Impact of pecan nut shell aqueous extract on the oxidative properties of margarines during storage.

PubMed

Engler Ribeiro, Paula Cristina; de Britto Policarpi, Priscila; Dal Bo, Andrea; Barbetta, Pedro Alberto; Block, Jane Mara

2017-07-01

The oxidative properties of margarines supplemented with pecan nut shell extract, rosemary extract and butylated hydroxytoluene (BHT) were investigated. The extracts of pecan nut shell and rosemary showed a high content of total phenolics and condensed tannins (93 and 102.9 mg GAE g -1 and 46 and 38.9 mg CE g -1 respectively) as well as a high antioxidant activity (1257 and 2306 µmol TEAC g -1 and 293 and 856 mg TEAC g -1 by ABTS and DPPH methods respectively). Gallic acid, chlorogenic acid, p-hydroxybenzoic acid, epicatechin and epicatechin gallate were identified in the pecan nut shell extract. Peroxide and p-anisidine values of 3.75-4.43 meq kg -1 and 1.22-2.73 respectively, Totox values of 9.88-10.8 and specific extinction values of 4.38-4.59 and 0.92-0.94 at 232 and 268 nm respectively were observed after 8 months of storage in the studied samples. Margarines supplemented with pecan nut shell extract, rosemary extract or BHT during prolonged storage were found to be of equal quality within the degree of confidence limits. The extract of pecan nut shell may be considered as a natural product replacement for the synthetic antioxidant BHT. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

Nezara viridula (Hemiptera: Pentatomidae) feeding patterns in macadamia nut in Hawaii: nut maturity and cultivar effects.

PubMed

Follett, Peter A; Wright, Mark G; Golden, Mary

2009-08-01

Nezara viridula L. (Hemiptera: Pentatomidae) is a serious pest of macadamia nuts, Macadamia integrifolia, in Hawaii. Using ruthenium red dye to stain stink bug feeding probes, feeding activity was determined for nuts of various maturity levels harvested from the tree and off the ground throughout the growing season in five commercial cultivars. Damage occurred in the tree and on the ground during all nut growth stages. Damage on the ground was often higher than in the tree. Cultivar 246 was more susceptible to attack than cultivars 333 and 800. It was previously thought that cultivar susceptibility was related to husk and shell thickness, but cultivar 246 showed higher damage than other cultivars even during early nut development when the nuts are small and before the shell has formed. This suggests that shell and husk thickness may play a secondary role in susceptibility to feeding by N. viridula. Monitoring N. viridula feeding activity during early nut development may help alert growers to potential problems later in the season, but early-season probing activity in immature nuts was not a good predictor of damage levels in mature nuts later in the season in our study.

7 CFR 51.2547 - Definitions.

Code of Federal Regulations, 2013 CFR

2013-01-01

... shells, shells not split on suture, adhering hull material, light stained, or dark stained. (1) Damage by... shell surface or, on dyed nuts, when readily noticeable. (v) Dark stained on raw or roasted nuts, means an aggregate amount of dark brown, dark gray or black discoloration affects more than one-eighth of...

7 CFR 51.2547 - Definitions.

Code of Federal Regulations, 2014 CFR

2014-01-01

... shells, shells not split on suture, adhering hull material, light stained, or dark stained. (1) Damage by... shell surface or, on dyed nuts, when readily noticeable. (v) Dark stained on raw or roasted nuts, means an aggregate amount of dark brown, dark gray or black discoloration affects more than one-eighth of...

Maintaining high moisture content of macadamia nuts-in-shell during storage induces brown centres in raw kernels.

PubMed

Walton, David A; Randall, Bruce W; Le Lagadec, Marie D; Wallace, Helen M

2013-09-01

Kernel brown centres in macadamia are a defect causing internal discolouration of kernels. This study investigates the effect on the incidence of brown centres in raw kernel after maintaining high moisture content in macadamia nuts-in-shell stored at temperatures of 30°C, 35°C, 40°C and 45°C. Brown centres of raw kernel increased with nuts-in-shell storage time and temperature when high moisture content was maintained by sealing in polyethylene bags. Almost all kernels developed the defect when kept at high moisture content for 5 days at 45°C, and 44% developed brown centres after only 2 days of storage at high moisture content at 45°C. This contrasted with only 0.76% when stored for 2 days at 45°C but allowed to dry in open-mesh bags. At storage temperatures below 45°C, there were fewer brown centres, but there were still significant differences between those stored at high moisture content and those allowed to dry (P < 0.05). Maintenance of high moisture content during macadamia nuts-in-shell storage increases the incidence of brown centres in raw kernels and the defect increases with time and temperature. On-farm nuts-in-shell drying and storage practices should rapidly remove moisture to reduce losses. Ideally, nuts-in-shell should not be stored at high moisture content on-farm at temperatures over 30°C. © 2013 Society of Chemical Industry.

Effect of bone on the pyrolysis product distribution and composition in a fixed bed reactor

NASA Astrophysics Data System (ADS)

Alhassan, M.; Andresen, J. M.

2012-04-01

Co-pyrolysis of Biomass including Pistachio shell (PS), Pine wood (PW) and Wheat Straw (WS) with Bone matter (BM) have been investigated to determine the effect of bone on the quality of bio-char and bio-oil produced. The aim of this study is to generate stable and nitrogen enriched bio-char that can act as fertilizer while at the same time optimizes the chemical stability of the char to act as a Carbon Capture and Storage system (CCS) and co-produce high quality oils for renewable energy generation. To achieve this, the present study has focused on the influence of bone matter addition from 0wt% to 25wt% to the biomasses in a fixed bed pyrolysis reactor at 3000C. The analysis of the char products shows that the addition of bone to the biomass increased their char yields up to 10wt% addition. Higher addition was found to reduce the overall char yield from the biomass. At 10wt% bone addition, the carbon, hydrogen, and nitrogen content, and the gross calorific value of the chars were increased by 7wt%, 29wt%, 163wt% and 19Mj/kg, for Wheat straw, 62wt%, 46wt%, 135wt%, 110Mj/kg for Pine wood and 7wt%, 76wt%, 42wt% and 33Mj/kg for Pistachio shells. The oxygen content of the Wheat straw, Pistachio shells and pine wood mixed with 10wt% BM decreased by 28wt%, 21wt%, and 93wt%, respectively. The bio-oil yield increased for the bone addition up to 5%wt% for all the samples, its energy value and concentration of its major chemical components was improved for fuel and pharmaceutical use. Port experiment has shown that plant grown on soil amended with the bio-char produced gave higher yield as compared to that from un-amended soil. Comparison between the three biomasses investigated showed similar pattern of change. Hence it can be concluded that at optimum addition of bone to the biomass, bio-chars and oil yield could be optimized for soil amendment, energy production, while retaining carbon for sequestration.

7 CFR 51.2542 - U.S. Artificially Opened.

Code of Federal Regulations, 2010 CFR

2010-01-01

... STANDARDS) United States Standards for Grades of Pistachio Nuts in the Shell § 51.2542 U.S. Artificially Opened. “U.S. Artificially Opened” consists of artificially opened pistachio nuts in the shell which meet...

7 CFR 51.2540 - General.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Standards for Grades of Pistachio Nuts in the Shell § 51.2540 General. (a) Compliance with the provisions of.... (b) These standards are applicable to pistachio nuts in the shell which may be in a natural, dyed...

Characterization of Liquid Volatile Matter (LVM) of Cashew Nut Shell using Pyrolysis and Gas Chomatroghaphy

NASA Astrophysics Data System (ADS)

Mashuni; Jahiding, Muhammad; Sitti Ilmawati, Waode; Kurniasih, Ita; Wati, Wa; Muzirah; Burhan, Muniati

2017-05-01

Cashew nut areexcellent products in Southeast Sulawesi. Cashew nut is one part of the cashew plant untapped waste. Cashew nut shell potential as a producer of liquidvolatile matter (LVM) and charcoal because it contains lignocellulos. LVM is the smoke condensation products obtained from the pyrolysis reactor can used foradhesive of briquettes hybridapplication. The aim of this reseach is to produce LVM of cashew nut shellby pyrolysisand analyze the content byGas Chromatography(GC). The research procedure begin with drying the cashew nut, the sample inserting into the pyrolysis reactor then heating with three variations of temperature respectively is 400°C, 500°C and 600°C. Cashew nutshell have been heating by pyrolisis processwith high temperatures resulting chorcoal and LVM separately. Volume LVM measured,then identify is components using GC. LVM obtained respectively 200ml kg-1, 340 ml kg-1, and 340 ml kg-1. Chromatogram of the GC from LVM of cashew nut shell has ammonia, hexane, acetic acid, propanone and phenol. Phenol compounds can be used as a adhesive for hybrid briquettes applications.

Thermogravimetric characterization and gasification of pecan nut shells.

PubMed

Aldana, Hugo; Lozano, Francisco J; Acevedo, Joaquín; Mendoza, Alberto

2015-12-01

This study focuses on the evaluation of pecan nut shells as an alternative source of energy through pyrolysis and gasification. The physicochemical characteristics of the selected biomass that can influence the process efficiency, consumption rates, and the product yield, as well as create operational problems, were determined. In addition, the thermal decomposition kinetics necessary for prediction of consumption rates and yields were determined. Finally, the performance of a downdraft gasifier fed with pecan nut shells was analyzed in terms of process efficiency and exit gas characteristics. It was found that the pyrolytic decomposition of the nut shells can be modeled adequately using a single equation considering two independent parallel reactions. The performance of the gasification process can be influenced by the particle size and air flow rate, requiring a proper combination of these parameters for reliable operation and production of a valuable syngas. Copyright © 2015 Elsevier Ltd. All rights reserved.

Quality changes in macadamia kernel between harvest and farm-gate.

PubMed

Walton, David A; Wallace, Helen M

2011-02-01

Macadamia integrifolia, Macadamia tetraphylla and their hybrids are cultivated for their edible kernels. After harvest, nuts-in-shell are partially dried on-farm and sorted to eliminate poor-quality kernels before consignment to a processor. During these operations, kernel quality may be lost. In this study, macadamia nuts-in-shell were sampled at five points of an on-farm postharvest handling chain from dehusking to the final storage silo to assess quality loss prior to consignment. Shoulder damage, weight of pieces and unsound kernel were assessed for raw kernels, and colour, mottled colour and surface damage for roasted kernels. Shoulder damage, weight of pieces and unsound kernel for raw kernels increased significantly between the dehusker and the final silo. Roasted kernels displayed a significant increase in dark colour, mottled colour and surface damage during on-farm handling. Significant loss of macadamia kernel quality occurred on a commercial farm during sorting and storage of nuts-in-shell before nuts were consigned to a processor. Nuts-in-shell should be dried as quickly as possible and on-farm handling minimised to maintain optimum kernel quality. 2010 Society of Chemical Industry.

7 CFR 51.2543 - U.S. Non-Split.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Standards for Grades of Pistachio Nuts in the Shell § 51.2543 U.S. Non-Split. “U.S. Non-Split” consists of non-split pistachio nuts in the shell which meet the following requirements: (a) Basic requirements...

Sensing of moisture content in in-shell peanuts by NIR (Near Infra Red) reflectance spectroscopy

USDA-ARS?s Scientific Manuscript database

It was found earlier that moisture content (MC) of intact kernels of grain and nuts could be determined by Near Infra Red (NIR) reflectance spectrometry. However, if the MC values can be determined while the nuts are in their shells, it would save lot of labor and money spent in shelling and cleanin...

Co-gasification of tire and biomass for enhancement of tire-char reactivity in CO2 gasification process.

PubMed

Lahijani, Pooya; Zainal, Zainal Alimuddin; Mohamed, Abdul Rahman; Mohammadi, Maedeh

2013-06-01

In this investigation, palm empty fruit bunch (EFB) and almond shell (AS) were implemented as two natural catalysts rich in alkali metals, especially potassium, to enhance the reactivity of tire-char through co-gasification process. Co-gasification experiments were conducted at several blending ratios using isothermal Thermogravimetric analysis (TGA) under CO2. The pronounced effect of inherent alkali content of biomass-chars on promoting the reactivity of tire-char was proven when acid-treated biomass-chars did not exert any catalytic effect on improving the reactivity of tire-char in co-gasification experiments. In kinetic studies of the co-gasified samples in chemically-controlled regime, modified random pore model (M-RPM) was adopted to describe the reactive behavior of the tire-char/biomass-char blends. By virtue of the catalytic effect of biomass, the activation energy for tire-char gasification was lowered from 250 kJ/mol in pure form 203 to 187 kJ/mol for AS-char and EFB-char co-gasified samples, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

Pyrolysis conditions and ozone oxidation effects on ammonia adsorption in biomass generated chars.

PubMed

Kastner, James R; Miller, Joby; Das, K C

2009-05-30

Ammonia adsorbents were generated via pyrolysis of biomass (peanut hulls and palm oil shells) over a range of temperatures and compared to a commercially available activated carbon (AC) and solid biomass residuals (wood and poultry litter fly ash). Dynamic ammonia adsorption studies (i.e., breakthrough curves) were performed using these adsorbents at 23 degrees C from 6 to 17 ppmv NH(3). Of the biomass chars, palm oil char generated at 500 degrees C had the highest NH(3) adsorption capacity (0.70 mg/g, 6 ppmv, 10% relative humidity (RH)), was similar to the AC, and contrasted to the other adsorbents (including the AC), the NH(3) adsorption capacity significantly increased if the relative humidity was increased (4 mg/g, 7 ppmv, 73% RH). Room temperature ozone treatment of the chars and activated carbon significantly increased the NH(3) adsorption capacity (10% RH); resultant adsorption capacity, q (mg/g) increased by approximately 2, 6, and 10 times for palm oil char, peanut hull char (pyrolysis only), and activated carbon, respectively. However, water vapor (73% RH at 23 degrees C) significantly reduced NH(3) adsorption capacity in the steam and ozone treated biomass, yet had no effect on the palm shell char generated at 500 degrees C. These results indicate the feasibility of using a low temperature (and thus low energy input) pyrolysis and activation process for the generation of NH(3) adsorbents from biomass residuals.

High-Temperature Captive Nut Assembly

NASA Technical Reports Server (NTRS)

Marke, M. L.; Charles, J. F.

1982-01-01

High-temperature captive-nut assembly consists of removable nut element that snaps into loose-fitting recesses in shell. Replacement of nut element is easily accomplished with simple handtools. Old nut is pried out and new one pushed into position. Removal is easily accomplished with help of U-shaped tool.

Evaluation of sanitizers for inactivating Salmonella on in-shell pecans and pecan nutmeats.

PubMed

Beuchat, Larry R; Mann, David A; Alali, Walid Q

2012-11-01

Chlorine, organic acids, and water extracts of inedible pecan components were tested for effectiveness in killing Salmonella on pecans. In-shell pecans and nutmeats (U.S. Department of Agriculture medium pieces) were immersion inoculated with a mixture of five Salmonella serotypes, dried to 3.7% moisture, and stored at 4°C for 3 to 6 weeks. In-shell nuts were immersed in chlorinated water (200, 400, and 1,000 μg/ml), lactic acid (0.5, 1, and 2%), and levulinic acid (0.5, 1, and 2%) with and without 0.05% sodium dodecyl sulfate (SDS), and a mixed peroxyacid sanitizer (Tsunami 200, 40 μg/ml) for up to 20 min at 21°C. The rate of reduction of free chlorine in conditioning water decreased as the ratio of in-shell nuts/water was increased. The rate of reduction was more rapid when nuts were not precleaned before treatment. The initial population of Salmonella on in-shell nuts (5.9 to 6.3 log CFU/g) was reduced by 2.8 log CFU/g after treating with chlorinated water (1,000 μg/ml). Treatment with 2% lactic acid plus SDS or 2% levulinic acid plus SDS reduced the pathogen by 3.7 and 3.4 log CFU/g, respectively. Lactic and levulinic acids (2%) without SDS were less effective (3.3- and 2.1-log CFU/g reductions, respectively) than acids with SDS. Treatment with Tsunami 200 resulted in a 2.4-log CFU/g reduction. In-shell nuts and nutmeats were immersed in water extracts of ground pecan shucks (hulls), shells, a mixture of shells and pith, and pith. The general order of lethality of extracts to Salmonella was shuck < shell-pith ≤ shell ≤ pith < chlorine (400 μg/ml) and shuck < shell ≤ pith = shell-pith < chlorine (400 μg/ml). Results emphasize the importance of removing soil and dust on in-shell pecans before conditioning in chlorinated water and the need for sanitizers with increased effectiveness in killing Salmonella on pecans.

Aqueous extract from pecan nut [Carya illinoinensis (Wangenh) C. Koch] shell show activity against breast cancer cell line MCF-7 and Ehrlich ascites tumor in Balb-C mice.

PubMed

Hilbig, Josiane; Policarpi, Priscila de Britto; Grinevicius, Valdelúcia Maria Alves de Souza; Mota, Nádia Sandrine Ramos Santos; Toaldo, Isabela Maia; Luiz, Marilde Terezinha Bordignon; Pedrosa, Rozangela Curi; Block, Jane Mara

2018-01-30

In Brazil many health disorders are treated with the consumption of different varieties of tea. Shell extracts of pecan nut (Carya illinoinensis), which have significant amounts of phenolic compounds in their composition, are popularly taken as tea to prevent diverse pathologies. Phenolic compounds from pecan nut shell extract have been associated with diverse biological effects but the effect on tumor cells has not been reported yet. The aim of the current work was to evaluate the relationship between DNA fragmentation, cell cycle arrest and apoptosis induced by pecan nut shell extract and its antitumor activity. Cytotoxicity, proliferation, cell death and cell cycle were evaluated in MCF-7 cells by MTT, colony assay, differential coloring and flow cytometry assays, respectively. DNA damage effects were evaluated through intercalation into CT-DNA and plasmid DNA cleavage. Tumor growth inhibition, survival time increase, apoptosis and cell cycle arrest were assessed in Ehrlich ascites tumor in Balb/C mice. The cytotoxic effect of pecan nut shell extracts, the induction of cell death by apoptosis and also the cell cycle arrest in MCF-7 cells have been demonstrated. The survival time in mice with Ehrlich ascites tumor increased by 67%. DNA damage was observed in the CT-DNA, plasmid DNA and comet assays. The mechanism involved in the antitumor effect of pecan nut shell extracts may be related to the activation of key proteins involved in apoptosis cell death (Bcl-XL, Bax and p53) and on the cell cycle regulation (cyclin A, cyclin B and CDK2). These results were attributed to the phenolic profile of the extract, which presented compounds such as gallic, 4-hydroxybenzoic, chlorogenic, vanillic, caffeic and ellagic acid, and catechin, epicatechin, epigallocatechin and epicatechin gallate. The results indicated that pecan nut shell extracts are effective against tumor cells growth and may be considered as an alternative to the treatment of cancer. Copyright © 2017 Elsevier Ireland Ltd. All rights reserved.

Machine vision system for automated detection of stained pistachio nuts

NASA Astrophysics Data System (ADS)

Pearson, Tom C.

1995-01-01

A machine vision system was developed to separate stained pistachio nuts, which comprise of about 5% of the California crop, from unstained nuts. The system may be used to reduce labor involved with manual grading or to remove aflatoxin contaminated product from low grade process streams. The system was tested on two different pistachio process streams: the bi- chromatic color sorter reject stream and the small nut shelling stock stream. The system had a minimum overall error rate of 14% for the bi-chromatic sorter reject stream and 15% for the small shelling stock stream.

Hyposensitization to poison ivy after working in a cashew nut shell oil processing factory.

PubMed

Reginella, R F; Fairfield, J C; Marks, J G

1989-04-01

19 adults were patch tested to urushiol, the allergen in poison ivy/oak, to determine their sensitivity to this allergen after working in a cashew nut shell oil (CNSO) processing plant. The cashew nut tree and poison ivy/oak are in the same botanical family. Anacardiaceae, and they share similar chemicals which cause allergic contact dermatitis. 13 of the 19 workers had a preemployment history of poison ivy sensitivity, with 10 developing CNSO dermatitis. After working in this factory for several months, 9 of the 13 noticed a decreased sensitivity or no sensitivity to poison ivy/oak. When tested to urushiol extract, only 3 reacted positively, 2 minimally. These results imply that hyposensitization to poison ivy/oak occurred in these employees after development of hardening to cashew nut shell oil.

Botanical pesticides effect from shells of bean’s cashew nut on biological agents of trichoderma sp. and gliocladium sp.

NASA Astrophysics Data System (ADS)

Bande, L. O. S.; Mariadi; Gusnawaty, HS; Nuriadi; Trisulpa, L.; Rahmania

2018-02-01

A shell of cashew nut (Anacardium occidentanle) has contained Cashew Nut Shell Liquid (CNSL) that is used as botanical pesticides. CNSL oil consists of active substance such as anacardat acid, cardol and cardanol. Utilization of the pesticides from shells of cashew nut to control pests and diseases of plants would be affected on biological agents. The objective of this research was to investigate pesticides inhibition on the increase of mycelium Trichoderma sp. and Gliocladium sp. by in vitro method. The tested concentration sample consisted of 0.0% (control), 2.5%, 7.5% and 10.0% in PDA media. The results of this research showed that 2.5% botanical pesticides concentration could minimize mycelium of Trichoderma sp. and Gliocladium sp. 22.73% and 21.04% respectively and also the increase shells of cashew extract could be affected the increase of mycelium inhibition. The extract with 2.5% concentration was the recommended concentration to control of fruit rot diseases and if concentration was 10.0% then its inhibition become 54.98% and 49.35%, respectively. The results proved that uncontrolled utilization of the pesticides could be affected on decrease of Trichoderma sp. and Gliocladium sp. growth.

Synthesis of carbon-encapsulated metal nanoparticles from wood char

Treesearch

Yicheng Du; Chuji Wang; Hossein Toghiani; Zhiyong Cai; Xiaojian Liu; Jilei Zhang; Qiangu Yan

2010-01-01

Carbon-encapsulated metal nanoparticles were synthesized by thermal treatment of wood char, with or without transition metal ions pre-impregnated, at 900ºC to 1,100ºC. Nanoparticles with concentric multilayer shells were observed. The nanoparticles were analyzed by scanning electron microscopy, transmission electron microscopy (TEM), X-ray diffraction...

Developing hot air assisted radio frequency drying for in-shell Macadamia nuts

USDA-ARS?s Scientific Manuscript database

Dehydration offers a means of preserving foods in a stable and safe condition as it reduces water activity and extends shelf-life of perishable agricultural products. The purpose of this study was to develop radio frequency (RF) drying protocols for in-shell macadamia nuts based on conventional hot ...

The ultrastructure of shelled and unshelled cashew nuts.

PubMed

Muniz, Celli R; Freire, Francisco C O; Soares, Arlete Aparecida; Cooke, Peter H; Guedes, Maria I F

2013-01-01

Cashew nuts have many attributes, including sensory, nutritional and health appeal, which contribute to their worldwide acceptance. We demonstrate details of the microstructure of shelled and unshelled cashew kernels with regard to pericarp and cotyledon organization. This study also provides evidence of the colonization of these kernels by filamentous fungi. Nuts were examined by scanning electron and confocal scanning laser microscopy. Staining with acridine orange was performed. A tight lignified palisade layer adjacent to the exocarp surface explains the hardness of the shell's pericarp. The mesocarp contains large secretory cavities that confer a spongy property to this tissue. Papillose cells, which are responsible for secreting CNSL (cashew nutshell liquid), were observed to cover the inner wall of these cavities. Lipid components are readily released from the parenchyma and appear as oil droplets. The outer surface of the shelled samples exhibited a dense Aspergillus infestation. Copyright © 2013 Elsevier Ltd. All rights reserved.

Chromatographic techniques for the determination of alkyl-phenols, tocopherols and other minor polar compounds in raw and roasted cold pressed cashew nut oils.

PubMed

Gómez-Caravaca, Ana María; Verardo, Vito; Caboni, Maria Fiorenza

2010-11-19

Anacardium occidentale belongs to the family Anacardiaceae and is principally grown in tropical America (Mexico, Peru, Brazil, etc.) and India. Cashew nuts contain low amounts of hydroxy alkyl phenols that come from an oily liquid present in their shell and that is known as cashew-nut shell liquid. This paper reports the alkyl phenols composition of cold pressed raw and roasted cashew nut oil. First of all, cashew nut shell liquid was used for a basic fractionation of the alkyl phenol classes by preparative TLC and definitively identified by GC-MS and GC-FID. Anacardic acids were the major alkylphenols contained in both oils followed by cardol, cardanol and 2-methylcardol compounds, respectively. Raw and roasted oils did not show different compositions except for cardanols. The oil produced from roasted cashew nut reported a higher concentration of cardanols. Furthermore, tocopherols and other minor polar compounds were determined by HPLC-FLD and HPLC-DAD-MS, respectively. Tocopherol content varied in a range of 171.48-29.56mg/100g from raw to roasted cashew nut oil, being β-tocopherol the one which presented a higher decrease (93.68%). Also minor polar compounds in cashew oil decreased after roasting from 346.52 to 262.83mg/kg. Copyright © 2010 Elsevier B.V. All rights reserved.

Nutrient composition of raw, dry-roasted, and skin-on cashews

USDA-ARS?s Scientific Manuscript database

Cashew nuts are the second most popular tree nut and sales are growing at a rate of 7% per annum. The highest quality cashew nuts are traditionally whole, oil-roasted, and devoid of skins. The recent development of a technique to remove the caustic cashew nut shell liquid from cashews and leave th...

Thermal Cyclic Resistance Polyester Resin Composites Reinforce Fiber Nut Shell

NASA Astrophysics Data System (ADS)

Fahmi, Hendriwan

2017-12-01

The purpose of study is to determine the effect of fiber length and thermal cyclic of the bending strength of polyester resin composite reinforced by fibers nut shell. The materials used in this study is a nut shell fibers with fiber length of 1 cm, 2 cm and 3 cm and polyester resin with composition 70-30%wt. Fiber nut shell treated soaking in NaOH 30% for 30 minutes, then rinse with clean water so that the fiber free of alkali and then dried. Furthermore, the composite is heated in an oven to a temperature of 100°C for 1 hour and then cooled in the open with a variety of thermal cyclic 30, 40, and 50 times. Bending properties of composites known through the testing process using a three-point bending test equipment universal testing machine. The test results show that the bending strength bending highest in fiber length of 3 cm with 30 treatment cycles of thermal to the value of 53.325 MPa, while the lowest occurred in bending strength fiber length of 1 cm with no cycles of thermal treatment to the value of 30.675 MPa.

Modulation of antioxidant potential in liver of mice by kernel oil of cashew nut (Anacardium occidentale) and its lack of tumour promoting ability in DMBA induced skin papillomagenesis.

PubMed

Singh, Bimala; Kale, R K; Rao, A R

2004-04-01

Cashew nut shell oil has been reported to possess tumour promoting property. Therefore an attempt has been made to study the modulatory effect of cashew nut (Anlacardium occidentale) kernel oil on antioxidant potential in liver of Swiss albino mice and also to see whether it has tumour promoting ability like the shell oil. The animals were treated orally with two doses (50 and 100 microl/animal/day) of kernel oil of cashew nut for 10 days. The kernel oil was found to enhance the specific activities of SOD, catalase, GST, methylglyoxalase I and levels of GSH. These results suggested that cashew nut kernel oil had an ability to increase the antioxidant status of animals. The decreased level of lipid peroxidation supported this possibility. The tumour promoting property of the kernel oil was also examined and found that cashew nut kernel oil did not exhibit any solitary carcinogenic activity.

Evaluation of Toxic, Cytotoxic, Mutagenic, and Antimutagenic Activities of Natural and Technical Cashew Nut Shell Liquids Using the Allium cepa and Artemia salina Bioassays

PubMed Central

Leite, Aracelli de Sousa; Oliveira, George Laylson da Silva; Gomes Júnior, Antonio L.; de Lima, Sidney Gonçalo; Citó, Antônia Maria das Graças Lopes; de Freitas, Rivelilson M.; Melo-Cavalcante, Ana Amélia de C.; Dantas Lopes, José Arimateia

2015-01-01

The cashew nut releases a substance that is known as cashew nut shell liquid (CNSL). There are both natural (iCNSL) and technical (tCNSL) cashew nut shell liquids. This study used an Artemia salina bioassay to evaluate the toxic effects of iCNSL and tCNSL cashew nut shell liquids. It also evaluated the toxicity, cytotoxicity, and mutagenicity of CNSL and its effects on the damage induced by copper sulfate (CuSO4·5H2O) on the meristems' root of Allium cepa. Effects of the damage induced by CuSO4·5H2O were evaluated before (pre-), during (co-), and after (post-) treatments. The iCNSL contained 94.5% anacardic acid, and the tCNSL contained 91.3% cardanol. The liquids were toxic to A. salina. Toxicity, cytotoxicity, and mutagenicity were observed with iCNSL compared with the negative control. Similarly, iCNSL failed to inhibit the toxicity and cytotoxicity of CuSO4·5H2O. The tCNSL was not toxic, cytotoxic, or mutagenic in any of the concentrations. However, the lowest iCNSL concentrations and all of the tCNSL concentrations had preventive, antimutagenic, and reparative effects on micronuclei and on chromosomal aberrations in the A. cepa. Therefore, protective, modulating, and reparative effects may be observed in the A. cepa, depending on the concentration and type of CNSL used. PMID:25861638

Evaluation of toxic, cytotoxic, mutagenic, and antimutagenic activities of natural and technical cashew nut shell liquids using the Allium cepa and Artemia salina bioassays.

PubMed

Leite, Aracelli de Sousa; Dantas, Alisson Ferreira; Oliveira, George Laylson da Silva; Gomes Júnior, Antonio L; de Lima, Sidney Gonçalo; Citó, Antônia Maria das Graças Lopes; de Freitas, Rivelilson M; Melo-Cavalcante, Ana Amélia de C; Dantas Lopes, José Arimateia

2015-01-01

The cashew nut releases a substance that is known as cashew nut shell liquid (CNSL). There are both natural (iCNSL) and technical (tCNSL) cashew nut shell liquids. This study used an Artemia salina bioassay to evaluate the toxic effects of iCNSL and tCNSL cashew nut shell liquids. It also evaluated the toxicity, cytotoxicity, and mutagenicity of CNSL and its effects on the damage induced by copper sulfate (CuSO4·5H2O) on the meristems' root of Allium cepa. Effects of the damage induced by CuSO4·5H2O were evaluated before (pre-), during (co-), and after (post-) treatments. The iCNSL contained 94.5% anacardic acid, and the tCNSL contained 91.3% cardanol. The liquids were toxic to A. salina. Toxicity, cytotoxicity, and mutagenicity were observed with iCNSL compared with the negative control. Similarly, iCNSL failed to inhibit the toxicity and cytotoxicity of CuSO4·5H2O. The tCNSL was not toxic, cytotoxic, or mutagenic in any of the concentrations. However, the lowest iCNSL concentrations and all of the tCNSL concentrations had preventive, antimutagenic, and reparative effects on micronuclei and on chromosomal aberrations in the A. cepa. Therefore, protective, modulating, and reparative effects may be observed in the A. cepa, depending on the concentration and type of CNSL used.

Chemical and nutritional characterization of the wrapped cashew

USDA-ARS?s Scientific Manuscript database

Cashews of the highest quality are traditionally whole, oil-roasted, and devoid of skins, although nut skins have been reported to have high concentrations of bioactive compounds. New techniques to clean the nut skins of harmful cashew nut shell liquid (CNSL) have been developed and production of n...

High-Quality Hollow Closed-Pore Silica Antireflection Coatings Based on Styrene-Acrylate Emulsion @ Organic-Inorganic Silica Precursor.

PubMed

Guo, Zhaolong; Zhao, Haixin; Zhao, Wei; Wang, Tao; Kong, Depeng; Chen, Taojing; Zhang, Xiaoyan

2016-05-11

Making use of a facile and low-cost way for the preparation of a hierarchically organized novel hollow closed-pore silica antireflective coating (CHAR) with tailored optical properties and a mechanical reliability is of great interest in the field of solar photovoltaic technology. The process mainly contains two aspects: (1) a styrene-acrylate emulsion @ organic-inorganic silica precursor (SA@OISP) core/shell hierarchical nanostructure, consisting of a sacrificial styrene-acrylate (SA) primary template, was fabricated using a sol-gel method; (2) the self-assembly of the nanostructures leads to SA@OISP nanospheres forming the high-quality hollow closed-pore silica antireflection coating (CHAR) by a dip-coating process and a subsequent calcination treatment. The resulting SA@OISP nanospheres have a mean diameter of 65.2 nm and contained a SA soft core with a mean diameter of approximately 54.8 nm and an organic-inorganic silica precursor (OISP) shell with a thickness of approximately 6-10 nm. Furthermore, the prepared CHAR film exhibited a high transmittance and good ruggedness. An average transmittance (TAV) of 97.64% was obtained, and the value is close to the ideal single-layered antireflection coating (98.09%) over a broad range of wavelengths (from 380 to 1100 nm). The CHAR film showed a stable TAV, with attenuation values of less than 0.8% and 0.43% after the abrasion test and the damp heat test, respectively. The conversion efficiency of the CHAR coating cover solar modules tends to be increased by 3.75%. The promising results obtained in this study suggest that the CHAR film was considered as an essential component of the solar module and were expected to provide additional solar energy harvest under extreme outdoor climates.

7 CFR 983.29 - Shelled pistachios.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 8 2010-01-01 2010-01-01 false Shelled pistachios. 983.29 Section 983.29 Agriculture... and Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE PISTACHIOS GROWN IN CALIFORNIA, ARIZONA, AND NEW MEXICO Definitions § 983.29 Shelled pistachios. Shelled pistachios means pistachio...

Bioactive compounds in cashew nut (Anacardium occidentale L.) kernels: effect of different shelling methods.

PubMed

Trox, Jennifer; Vadivel, Vellingiri; Vetter, Walter; Stuetz, Wolfgang; Scherbaum, Veronika; Gola, Ute; Nohr, Donatus; Biesalski, Hans Konrad

2010-05-12

In the present study, the effects of various conventional shelling methods (oil-bath roasting, direct steam roasting, drying, and open pan roasting) as well as a novel "Flores" hand-cracking method on the levels of bioactive compounds of cashew nut kernels were investigated. The raw cashew nut kernels were found to possess appreciable levels of certain bioactive compounds such as beta-carotene (9.57 microg/100 g of DM), lutein (30.29 microg/100 g of DM), zeaxanthin (0.56 microg/100 g of DM), alpha-tocopherol (0.29 mg/100 g of DM), gamma-tocopherol (1.10 mg/100 g of DM), thiamin (1.08 mg/100 g of DM), stearic acid (4.96 g/100 g of DM), oleic acid (21.87 g/100 g of DM), and linoleic acid (5.55 g/100 g of DM). All of the conventional shelling methods including oil-bath roasting, steam roasting, drying, and open pan roasting revealed a significant reduction, whereas the Flores hand-cracking method exhibited similar levels of carotenoids, thiamin, and unsaturated fatty acids in cashew nuts when compared to raw unprocessed samples.

Effects of Moisture and Other Contaminants in Friction Composites

DTIC Science & Technology

1993-01-30

NC 126, (Cardolite Corporation, Newark, NJ), a cashew nut shell liquid modified phenolic resin. NC126 is different from a straight phenolic resin in...that there is an alkyl chain substituent in the meta position of the phenol. The resin is derived from cashew nut shell liquid and is a solid...crosslinked cashew resin and is often referred to as cashew particles. The friction materials were processed by compression molding at 160 °C and 1000 psi

Looking for scaling laws, or physics with nuts and shells

NASA Astrophysics Data System (ADS)

Sheets, H. David; Lauffenburger, James C.

1999-09-01

Scaling laws relating the volume of a class of objects to a characteristic dimension of the object appear commonly in physics, chemistry, and biology. In this laboratory exercise for an introductory physics course scaling laws are derived for machine nuts and clam shells. In addition to covering a standard problem in physics, determining volume of the object by measuring the buoyant force on it, the biologically interesting idea of scaling laws are incorporated into the same lab.

Toward new benchmark adsorbents: preparation and characterization of activated carbon from argan nut shell for bisphenol A removal.

PubMed

Zbair, Mohamed; Ainassaari, Kaisu; Drif, Asmaa; Ojala, Satu; Bottlinger, Michael; Pirilä, Minna; Keiski, Riitta L; Bensitel, Mohammed; Brahmi, Rachid

2018-01-01

The use of argan nut shell as a precursor for producing activated carbon was investigated in this work. Two activated carbons AC-HP and AC-Na were prepared from argan nut shell by chemical activation method using phosphoric acid (H 3 PO 4 ) and sodium hydroxide (NaOH), respectively. Textural, morphological, and surface chemistry characteristics were studied by nitrogen physisorption, TGA, SEM, TXRF, FTIR, XRD, and by determining the pH PZC of the AC-HP. The adsorption experiments revealed that AC-HP was more efficient in adsorption of BPA due to high specific surface area (1372 m 2 /g) compared to AC-Na (798 m 2 /g). The obtained adsorption data of BPA on AC-HP correlated well with the pseudo-second-order model and the Langmuir isotherm (Qmax = 1250 mg/g at 293 K). The thermodynamic parameters (ΔG° < 0, ΔH° < 0, and ΔS° < 0) indicate that adsorption of BPA on AC-HP was spontaneous and exothermic in nature. The regeneration of AC-HP showed excellent results after 5 cycles (95-93%). This work does not only provide a potential way to use argan nut shell but also represents a sustainable approach to synthesize AC-HP, which might be an ideal material for various applications (energy storage, catalysis, and environmental remediation).

Nutritional potential, chemical profile and antioxidant activity of Chichá (Sterculia striata) nuts and its by-products.

PubMed

de Britto Policarpi, Priscila; Turcatto, Leticia; Demoliner, Fernanda; Ferrari, Roseli Aparecida; Bascuñan, Vera Lúcia Azzolin Frescura; Ramos, Juliano Carvalho; Jachmanián, Iván; Vitali, Luciano; Micke, Gustavo Amadeu; Block, Jane Mara

2018-04-01

The Sterculia striata nut commonly known as chichá is consumed raw or toasted inBrazil but information on its chemical composition and antioxidant activity are scarce in the literature. In this work, the nutritional composition, minerals profile, lipid composition and phenolic compounds profile of chichá nuts and its by-products (pellicle and shell) were determined. The results showed that the nuts and the cake contain considerable amount of fibers and proteins and are rich in minerals (Fe, Mn and Cu). Oleic acid was the main fatty acid (37.8%), and PPO (36.0%) and POP (15.6%) were the main triacylglycerides present in the chichá oil. The phytosterols β-sitosterol, stigmasteroland campesterol (1848.5μgg -1 , 542.2μgg -1 and 186.3μgg -1 , respectively), and the γ-, δ-, α- and β-tocopherol (8.85; 2.10; 1.64, and 0.11mg100g -1 , respectively) were identified in the oil. The antioxidant activity (ABTS and FRAP assays) followed the order pellicle>shell>nuts (13.25 and 84.65; 8.71 and 64.3; 5.85 and 36.79μmolTEACg -1 , respectively). The main phenolic compounds identified in the extracts were ellagic and ferulic acids; ellagic and protocatechuic acids; and protocatechuic, ellagic and methoxyphenylacetic acids for the nuts, shells and pellicle, respectively. A strong positive correlation was observed between total phenolic content and antioxidant activity determined by ABTS and FRAP assays (r=0.9067, p<0.01; and r=0.9584, p<0.01; respectively). Collectively, the results showed that the chichá is a nut of high nutritional value, rich in bioactive compounds. Copyright © 2018 Elsevier Ltd. All rights reserved.

Shell cracking strength in almond (Prunus dulcis [Mill.] D.A. Webb.) and its implication in uses as a value-added product.

PubMed

Ledbetter, C A

2008-09-01

Researchers are currently developing new value-added uses for almond shells, an abundant agricultural by-product. Almond varieties are distinguished by processors as being either hard or soft shelled, but these two broad classes of almond also exhibit varietal diversity in shell morphology and physical characters. By defining more precisely the physical and chemical characteristics of almond shells from different varieties, researchers will better understand which specific shell types are best suited for specific industrial processes. Eight diverse almond accessions were evaluated in two consecutive harvest seasons for nut and kernel weight, kernel percentage and shell cracking strength. Shell bulk density was evaluated in a separate year. Harvest year by almond accession interactions were highly significant (p0.01) for each of the analyzed variables. Significant (p0.01) correlations were noted for average nut weight with kernel weight, kernel percentage and shell cracking strength. A significant (p0.01) negative correlation for shell cracking strength with kernel percentage was noted. In some cases shell cracking strength was independent of the kernel percentage which suggests that either variety compositional differences or shell morphology affect the shell cracking strength. The varietal characterization of almond shell materials will assist in determining the best value-added uses for this abundant agricultural by-product.

Effect of Oxygen-Reducing Atmospheres on the Safety of Packaged Shelled Brazil Nuts during Storage

PubMed Central

Scussel, Vildes Maria; Giordano, Barbara Nantua; Simao, Vanessa; Manfio, Daniel; Galvao, Simone; Rodrigues, Manuel Nazaré Ferreira

2011-01-01

This work reports the application of oxygen-(O2-) reducing atmosphere methods on stored shelled Brazil nut (Bertholletia excelsa H.B.K.) packs aiming to evaluate the degree of aflatoxin degradation, nuts lipid oxidative stability, fungi control, and hygienic conditions improvement. The methods applied were (a) ozone: O3, (b) carbon dioxide: CO2, and (c) O2 absorber pads with and without vacuum. From all modified atmospheres evaluated, the best performance was obtained with O3, either with or without vacuum. It was the only nut treatment that was able to degrade aflatoxins. None of the spiked (AFLs: 15 μg·kg−1) nut samples O3- treated had aflatoxins detected up to the LC-MS/MS method LOQ (0.36 μg·kg−1 for total AFLs), thus producing safer nuts. Also it kept the fatty acid oxidation indicator—malondialdehyde stable and improved the sensory attributes for consumer acceptance. In addition, the destruction of fungi and yeast was observed since the O3 application (from 1.8 × 104 cfu/g to NG = no growth). All other treatments stabilized and/or inhibited microorganisms' growth only. By adding CO2 gas also played an important role in the nut quality. Regarding cost, gaseous O3 showed to be of low cost for application in the nut packs. PMID:21760791

Beyond the wild nut: moving toward profitable black walnut nut crops

Treesearch

Brian Hammons; Felix, Jr. Ponder; John Rickman

2004-01-01

Currently, about 2 million pounds of black walnut nutmeats are consumed annually, requiring about 26 million pounds of wild in-shell nuts (hulled, wet weight). Walnuts from wild trees are variable in quality, yield, and moisture, reducing the amount of good, salable nutmeats produced. Consequently, the price that can be paid to the harvester/producer is limited....

Prevalence of Salmonella in Cashews, Hazelnuts, Macadamia Nuts, Pecans, Pine Nuts, and Walnuts in the United States.

PubMed

Zhang, Guodong; Hu, Lijun; Melka, David; Wang, Hua; Laasri, Anna; Brown, Eric W; Strain, Errol; Allard, Marc; Bunning, Vincent K; Musser, Steven M; Johnson, Rhoma; Santillana Farakos, Sofia; Scott, Virginia N; Pouillot, Régis; Doren, Jane M Van; Hammack, Thomas S

2017-03-01

Nuts have been identified as a vector for salmonellosis. The objective of this project was to estimate the prevalence and contamination level of Salmonella in raw tree nuts (cashews, pecans, hazelnuts, macadamia nuts, pine nuts, and walnuts) at retail markets in the United States. A total of 3,656 samples of six types of tree nuts were collected from different types of retail stores and markets nationwide between October 2014 and October 2015. These samples were analyzed using a modified version of the Salmonella culture method from the U.S. Food and Drug Administration's Bacteriological Analytical Manual. Of the 3,656 samples collected and tested, 32 were culturally confirmed as containing Salmonella. These isolates represented 25 serotypes. Salmonella was not detected in pecans and in-shell hazelnuts. Salmonella prevalence estimates (and 95% confidence intervals) in cashews, shelled hazelnuts, pine nuts, walnuts, and macadamia nuts were 0.55% [0.15, 1.40], 0.35% [0.04, 1.20], 0.48% [0.10, 1.40], 1.20% [0.53, 2.40], and 4.20% [2.40, 6.90], respectively. The rates of Salmonella isolation from major or big chain supermarkets, small chain supermarkets, discount, variety, or drug stores, and online were 0.64% [0.38, 1.00], 1.60% [0.80, 2.90], 0.00% [0.00, 2.40], and 13.64% [2.90, 35.00], respectively (Cochran-Mantel-Haenszel test: P = 0.02). The rates of Salmonella isolation for conventional and organic nuts were not significantly different. Of the samples containing Salmonella, 60.7% had levels less than 0.003 most probable number (MPN)/g. The highest contamination level observed was 0.092 MPN/g. The prevalence and levels of Salmonella in these tree nut samples were comparable to those previously reported for similar foods.

Chemical Characterization and Release of Polyphenols from Pecan Nut Shell [Carya illinoinensis (Wangenh) C. Koch] in Zein Microparticles for Bioactive Applications.

PubMed

Kureck, Itamara; Policarpi, Priscila de Brito; Toaldo, Isabela Maia; Maciel, Matheus Vinícius de Oliveira Brisola; Bordignon-Luiz, Marilde T; Barreto, Pedro Luiz Manique; Block, Jane Mara

2018-05-03

The pecan nut [Carya illinoinensis (Wangenh) C. Koch] is a natural source of polyphenols with antioxidant properties. In this study, the encapsulation of aqueous and hydroalcoholic extracts of pecan nut shell were evaluated for the release of bioactive compounds and antioxidant potential in order to explore food applications using zein as encapsulating agent. The extracts showed high contents of total phenolics, condensed tannins and high antioxidant activity. Concentrations of proanthocyanidins were 9-fold higher in hydroalcoholic extracts. The LC-DAD analysis showed that catechins were the major phenolic compounds in samples, with epigallocatechin levels up to 138.62 mg mL -1 . Zein microparticles loaded with aqueous extract released 2.3 times more phenolic compounds than the hydroalcoholic extracts and the DSC thermograms showed that extracts of pecan nut shell remained thermally stable up to 240 °C. The zein microcapsules obtained in this study were efficiently encapsulated and represent an interesting additive due its high antioxidant capacity, physicochemical characteristics and morphology. The use of zein microparticles combined with natural extracts constitute a step forward in the improvement of current technology for delivering phenolic compounds with applications in functional foods and nutraceuticals.

Wild capuchin monkeys (Cebus libidinosus) use anvils and stone pounding tools.

PubMed

Fragaszy, Dorothy; Izar, Patrícia; Visalberghi, Elisabetta; Ottoni, Eduardo B; de Oliveira, Marino Gomes

2004-12-01

We conducted an exploratory investigation in an area where nut-cracking by wild capuchin monkeys is common knowledge among local residents. In addition to observing male and female capuchin monkeys using stones to pound open nuts on stone "anvils," we surveyed the surrounding area and found physical evidence that monkeys cracked nuts on rock outcrops, boulders, and logs (collectively termed anvils). Anvils, which were identified by numerous shallow depressions on the upper surface, the presence of palm shells and debris, and the presence of loose stones of an appropriate size to pound nuts, were present even on the tops of mesas. The stones used to crack nuts can weigh >1 kg, and are remarkably heavy for monkeys that weigh <4 kg. The abundance of shell remains and depressions in the anvil surface at numerous anvil sites indicate that nut-cracking activity is common and long-enduring. Many of the stones found on anvils (presumably used to pound nuts) are river pebbles that are not present in the local area we surveyed (except on or near the anvils); therefore, we surmise that they were transported to the anvil sites. Ecologically and behaviorally, nut-cracking by capuchins appears to have strong parallels to nut-cracking by wild chimpanzees. The presence of abundant anvil sites, limited alternative food resources, abundance of palms, and the habit of the palms in this region to produce fruit at ground level all likely contribute to the monkeys' routine exploitation of palm nuts via cracking them with stones. This discovery provides a new reference point for discussions regarding the evolution of tool use and material culture in primates. Routine tool use to exploit keystone food resources is not restricted to living great apes and ancestral hominids. Copyright 2004 Wiley-Liss, Inc.

Inhibition of soybean and potato lipoxygenases by bhilawanols from bhilawan (Semecarpus anacardium) nut shell liquid and some synthetic salicylic acid analogues.

PubMed

Nagabhushana, Kyatanahalli S; Umamaheshwari, S; Tocoli, Felismino E; Prabhu, Sandeep K; Green, Ivan R; Ramadoss, Candadai S

2002-08-01

Bhilawanol diene (3) isolated from bhilawan nut shell liquid was found to be a potent inhibitor of both soybean and potato lipoxygenases with IC50 values of 0.85 microM and 1.1 microM, respectively. However, the monoene (2) and saturated (1) bhilawanols exhibited relatively lower inhibitory activity. In addition, inhibition studies with synthetic analogues of salicylic acid (4-8) suggested that the unsaturated lipophilic side chain may be an absolute requirement for inhibitory activity.

Results of tests of MTA-2 TPS on the SRB hold-down bolt blast container

NASA Technical Reports Server (NTRS)

Dean, W. G.

1982-01-01

The four solid rocket booster (SRB) hold-down posts are fastened to the mobile launch platform (MLP) with four large nuts. At liftoff the nuts are split with explosive changes to release the SRB/Shuttle. A blast container is placed over the nuts to protect the vehicle from flying debris. The blast container is a reusable part and has to be protected from aerodynamic heating during flight. The thermal protection system (TPS) used to protect these blast containers is cork. Fitting the flat cork sheet to this hemispherical shaped blast container is both time consuming and expensive. Another problem is removing the charred cork and epoxy glue from the blast containers. Replacements of this cork with another TPS material such as MTA-2 was examined. Heating rates along the centerline of the forward facing areas of the blast container were determined. The feasibility of using 1/2 in. MTA-2 on the SRB blast containers for protection from ascent, plume impingement and reentry heating is demonstrated.

Exploring application of cardanol from natural resource: Chemistry and products

USDA-ARS?s Scientific Manuscript database

Cardanol (cashew nut shell liquid, CNSL) is a renewable raw material derived from a byproduct of the cashew nut processing industry. First, two natural plasticizers derived from cardanol, cardanol acetate (CA) and epoxidated cardanol acetate (ECA), have been synthesized and characterized by 1HNMR an...

Dissolution and fractionation of nut shells in ionic liquids.

PubMed

Carneiro, Aristides P; Rodríguez, Oscar; Macedo, Eugénia A

2017-03-01

The aim of this work was to study the dissolution of raw peanut and chestnut shells in ionic liquids. Dissolution of raw biomass up to 7wt% was achieved under optimized operatory conditions. Quantification of polysaccharides dissolved through quantitative 13 Cq NMR revealed extractions of the cellulosic material to ionic liquids as high as 87%. Regeneration experiments using an antisolvent mixture allowed to recover the cellulosic material and the ionic liquid. The overall mass balance presented very low loss rates (<8%), recoveries of 75% and 95% of cellulosic material from peanut and chestnut shells, respectively, and the recovery of more than 95% of the ionic liquid in both cases. These results show the high potential of using nut shells and ionic liquids for biorefining purposes. Moreover, high recovery of ionic liquids favors the process from an economical point of view. Copyright © 2016 Elsevier Ltd. All rights reserved.

Analysis of Hydrogen Generation through Thermochemical Gasification of Coconut Shell Using Thermodynamic Equilibrium Model Considering Char and Tar

PubMed Central

Rupesh, Shanmughom; Muraleedharan, Chandrasekharan; Arun, Palatel

2014-01-01

This work investigates the potential of coconut shell for air-steam gasification using thermodynamic equilibrium model. A thermodynamic equilibrium model considering tar and realistic char conversion was developed using MATLAB software to predict the product gas composition. After comparing it with experimental results the prediction capability of the model is enhanced by multiplying equilibrium constants with suitable coefficients. The modified model is used to study the effect of key process parameters like temperature, steam to biomass ratio, and equivalence ratio on product gas yield, composition, and heating value of syngas along with gasification efficiency. For a steam to biomass ratio of unity, the maximum mole fraction of hydrogen in the product gas is found to be 36.14% with a lower heating value of 7.49 MJ/Nm3 at a gasification temperature of 1500 K and equivalence ratio of 0.15. PMID:27433487

Analysis of Hydrogen Generation through Thermochemical Gasification of Coconut Shell Using Thermodynamic Equilibrium Model Considering Char and Tar.

PubMed

Rupesh, Shanmughom; Muraleedharan, Chandrasekharan; Arun, Palatel

2014-01-01

This work investigates the potential of coconut shell for air-steam gasification using thermodynamic equilibrium model. A thermodynamic equilibrium model considering tar and realistic char conversion was developed using MATLAB software to predict the product gas composition. After comparing it with experimental results the prediction capability of the model is enhanced by multiplying equilibrium constants with suitable coefficients. The modified model is used to study the effect of key process parameters like temperature, steam to biomass ratio, and equivalence ratio on product gas yield, composition, and heating value of syngas along with gasification efficiency. For a steam to biomass ratio of unity, the maximum mole fraction of hydrogen in the product gas is found to be 36.14% with a lower heating value of 7.49 MJ/Nm(3) at a gasification temperature of 1500 K and equivalence ratio of 0.15.

Cleaning oil refining drainage waters out of emulsified oil products with thermic treated cedar nut shell

NASA Astrophysics Data System (ADS)

Pyatanova, P. A.; Adeeva, L. N.

2017-08-01

It was elaborated the ability of the sorbent produced by thermic treatment of cedar nut shell to destruct model and real first kind (direct) emulsions in static and dynamic conditions. In static conditions optimal ratio sorbent-emulsion with the original concentration of oil products 800 mg/l was in the range of 2.0 g per 100 ml of emulsion which corresponds to the level of treatment 94.9%. The time of emulsion destruction was 40 minutes. This sorbent is highly active in dynamic processes of oil-contaminated water treatment, the level of treatment 96.0% is being achieved. Full dynamic sorptive capacity of the sorbent is 0.85 g/g. Sorbent based on the thermic treated cedar nut shell can be elaborated as sorptive filter element of local treatment facilities of oil refining and petrochemical processes. After the treatment with this sorbent of drainage waters of oil refinery in dynamic conditions the concentration of oil products became less than mpc on oil products for waste waters coming to biological treatment.

Derivatives of cardanol through the ene reaction with diethyl azodicarboxylate

USDA-ARS?s Scientific Manuscript database

Cardanol is an alkyl/alkenyl phenolic material obtained from cashew nut shell liquid (CNSL), which is a byproduct of cashew nut processing. In an effort to develop new uses, cardanol was derivatized for the first time with diethyl azodicarboxylate (DEAD) through the ene reaction. The reaction was fa...

Sorting in-shell walnuts using near infrared spectroscopy for improved drying efficiency and product quality

USDA-ARS?s Scientific Manuscript database

In the current walnut drying practice, dryers comingle nuts with varying moisture contents (MC) which results in over drying of nuts with low MC and thereby decrease product quality. The objectives of this research were to investigate correlations among near infrared (NIR) spectral data and MC of fr...

Impact resistance of spar-shell composite fan blades

NASA Technical Reports Server (NTRS)

Graff, J.; Stoltze, L.; Varholak, E. M.

1973-01-01

Composite spar-shell fan blades for a 1.83 meter (6 feet) diameter fan stage were fabricated and tested in a whirling arm facility to evaluate foreign object damage (FOD) resistance. The blades were made by adhesively bonding boron-epoxy shells on titanium spars and then adhesively bonding an Inconel 625 sheath on the leading edge. The rotating blades were individually tested at a tip speed of 800 feet per second. Impacting media used were gravel, rivets, bolt, nut, ice balls, simulated birds, and a real bird. Incidence angles were typical of those which might be experienced by STOL aircraft. The tests showed that blades of the design tested in this program have satisfactory impact resistance to small objects such as gravel, rivets, nuts, bolts, and two inch diameter ice balls. The blades suffered nominal damage when impacted with one-pound birds (9 to 10 ounce slice size). However, the shell was removed from the spar for a larger slice size.

Influence of biomass pretreatment on upgrading of bio-oil: Comparison of dry and hydrothermal torrefaction.

PubMed

Xu, Xiwei; Tu, Ren; Sun, Yan; Li, Zhiyu; Jiang, Enchen

2018-08-01

The dry and hydrothermal torrefacation of on Camellia Shell (CS) was carried on three different devices- batch autoclave, quartz tube, and auger reactor. The torrefied bio-char products were investigated via TGA, elemental analysis and industrial analysis. Moreover, the pyrolysis and catalytic pyrolysis properties of torrefied bio-char were investigated. The results showed torrefaction significantly influenced the content of hemicellulose in CS. And hydrothermal torrefaction via batch autoclave and dry torrefaction via auger reactors promoted the hemicellulose to strip from the CS. Quartz tube and auger reactor were beneficial for devolatilization and improving heat value of torrefied bio-char. The result showed that the main products were phenols and acids. And hydrothermal torrefaction pretreatment effectively reduced the acids content from 34.5% to 13.2% and enriched the content of phenols (from 27.23% to 60.05%) in bio-oil due to the decreasing of hemicellulos in torrefied bio-char. And the catalyst had slight influence on the bio-oil distribution. Copyright © 2018 Elsevier Ltd. All rights reserved.

7 CFR 51.2547 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-01-01

... hull material, light stained, or dark stained. (1) Damage by external (shell) defects means any... noticeable. (v) Dark stained on raw or roasted nuts, means an aggregate amount of dark brown, dark gray or... than three-fourths, but not less than one-half the shell cavity. (ii) Kernel spotting refers to dark...

7 CFR 51.2547 - Definitions.

Code of Federal Regulations, 2012 CFR

2012-01-01

... hull material, light stained, or dark stained. (1) Damage by external (shell) defects means any... noticeable. (v) Dark stained on raw or roasted nuts, means an aggregate amount of dark brown, dark gray or... than three-fourths, but not less than one-half the shell cavity. (ii) Kernel spotting refers to dark...

7 CFR 51.2547 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-01-01

... hull material, light stained, or dark stained. (1) Damage by external (shell) defects means any... noticeable. (v) Dark stained on raw or roasted nuts, means an aggregate amount of dark brown, dark gray or... than three-fourths, but not less than one-half the shell cavity. (ii) Kernel spotting refers to dark...

Escherichia coli Field Contamination of Pecan Nuts

PubMed Central

Marcus, Karen A.; Amling, H. J.

1973-01-01

More pecan samples collected from grazed orchards were contaminated with Escherichia coli than were samples from nongrazed orchards. No differences in frequency of contamination between mechanically and manually harvested nuts occurred. Nutmeats from whole uncracked pecans that were soaked for 24 h in a lactose broth solution containing E. coli did not become contaminated. Twentyfour percent of the whole pecans soaked in water for 48 h to simulate standing in a rain puddle developed openings along shell suture lines which did not completely close when the nuts were redried. PMID:4584575

Nanoparticles of wurtzite aluminum nitride from the nut shells

NASA Astrophysics Data System (ADS)

Qadri, S. B.; Gorzkowski, E. P.; Rath, B. B.; Feng, C. R.; Amarasinghe, R.

2016-11-01

Nanoparticles of aluminum nitride were produced from a thermal treatment of a mixture of aluminum oxide (Al2O3) and shells of almond, cashew, coconuts, pistachio, and walnuts in a nitrogen atmosphere at temperatures in excess of 1450 °C. By selecting the appropriate ratios of each nut powder to Al2O3, it is shown that stoichiometric aluminum nitride can be produced by carbo-thermal reduction in nitrogen atmosphere. Using x-ray diffraction analysis, Raman scattering and Fourier Transform Infrared spectroscopy, it is demonstrated that aluminum nitride consists of pure wurtzite phase. Transmission electron microscopy showed the formation of nanoparticles and in some cases nanotubes of AlN.

Oxidative stress and anxiety-like symptoms related to withdrawal of passive cigarette smoke in mice: beneficial effects of pecan nut shells extract, a by-product of the nut industry.

PubMed

Reckziegel, P; Boufleur, N; Barcelos, R C S; Benvegnú, D M; Pase, C S; Muller, L G; Teixeira, A M; Zanella, R; Prado, A C P; Fett, R; Block, J M; Burger, M E

2011-09-01

The present study evaluated the role of pecan nut (Carya illinoensis) shells aqueous extract (AE) against oxidative damage induced by cigarette smoke exposure (CSE) and behavioral parameters of smoking withdrawal. Mice were passively exposed to cigarette smoke for 3 weeks (6, 10, and 14 cigarettes/day) and orally treated with AE (25 g/L). CSE induced lipid peroxidation in brain and red blood cells (RBC), increased catalase (CAT) activity in RBC, and decreased plasma ascorbic acid levels. AE prevented oxidative damage and increased antioxidant defenses of mice exposed to cigarette smoke. In addition, AE reduced the locomotor activity and anxiety symptoms induced by smoking withdrawal, and these behavioral parameters showed a positive correlation with RBC lipid peroxidation. Our results showed the beneficial effects of this by-product of the pecan industry, indicating its usefulness in smoking cessation. Copyright © 2011 Elsevier Inc. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ejiofor, J.U.; Reddy, R.G.

The influence of microporous particulate carbon char on the mechanical, thermal, and tribological properties of wear-resistant Al-13.5Si-2.5Mg alloy composites was studied. Large increases in surface area due to the formation of micropores in coconut shell chars were achieved by high-temperature activation under CO{sub 2} gas flow. Activated char particles at 0.02 V{sub f} were used to reinforce the alloy. The composites were fabricated via a double-compaction reaction sintering technique under vacuum at a compaction pressure of 250 MPa and sintering temperature of 600 C. At more than 35% burn-off of the carbon chars at the temperature of activation, 915 C,more » the total surface area remained virtually unaffected. The ultimate tensile strength and hardness decreased by 23% and 6%, respectively; with increasing surface area of the reinforcement from 123 to 821 m{sup 2} g{sup {minus}1}. The yield strength and the percentage of elongation decreased by a factor of 2 and 5, respectively. No significant change in sliding wear rate was observed but the coefficient of friction increased by 13% (0.61 to 0.69). The coefficient of linear thermal expansion was reduced by 16% (11.7 {times} 10{sup {minus}6} to 9.8 {times} 10{sup {minus}6} C{sup {minus}1}), and remained unaffected at more than 35% burn-off. Energy-dispersive spectrometry of the particles of the activated chars showed that oxides of potassium and copper coated the open surfaces. Failure at the matrix-char interface was observed, and this was attributed to localized presence of oxides at the interfaces as identified by electron probe microanalysis. Poor wetting of the oxides by magnesium at the sintering conditions resulted in formation of weak matrix-char interface bonds.« less

7 CFR 51.2949 - U.S. No. 2.

Code of Federal Regulations, 2010 CFR

2010-01-01

... broken shells, perforated shells, adhering hulls, discoloration or other means. The kernels are well..., insects or other means. (See § 51.2954.) (a) At least 60 percent, by count, of the walnuts have kernels... percentages of nuts with kernels not darker than “light amber” which are free from grade defects, and/or...

7 CFR 457.167 - Pecan revenue crop insurance provisions.

Code of Federal Regulations, 2010 CFR

2010-01-01

... include selling through an on-farm or roadside stand, or a farmer's market, or permitting the general... of in-shell pecans grown during a crop year. Harvest—Collecting mature pecans from the orchard. Hedge...—Pecans as they are removed from the orchard with the nut-meats in the shell. Interplanted—Acreage on...

Activated carbons from end-products of tree nut and tree fruit production as sorbents for removing methyl bromide in ventilation effluent from postharvest chamber fumigation

USDA-ARS?s Scientific Manuscript database

End-products of tree nuts and tree fruits grown in California, USA were evaluated for the ability to remove methyl bromide from the ventilation effluent of postharvest chamber fumigations. Activated carbon sorbents from walnut and almond shells as well as peach and prune pits were prepared using dif...

Feasibility of dibromochloropropane (DBCP) and trichloroethylene (TCE) adsorption onto activated carbons made from nut shells of different almond varieties

USDA-ARS?s Scientific Manuscript database

Steam-activated carbons were made from shells from five different almond varieties (‘Nonpareil,’ ‘Padre,’ Tuono,’ ‘23-122,’ and ‘Y120-74’) and from a mix of almond types. The purpose of the work was to evaluate if the composition of shells had any effect on the performance of the final product. The ...

Identification of peanuts and tree nuts: are allergists smarter than their patients?

PubMed

Kao, Leon; Bhangoo, Parmbir S; Roy, Lonnie; Bird, J Andrew

2013-10-01

It has been reported that peanut- or tree nut-allergic individuals and their guardians are poorly capable of differentiating various tree nuts and peanuts. No information exists on the ability of allergists to differentiate peanuts and tree nuts. To measure the ability of allergists and other specialists within the allergy and immunology field to identify various types of tree nuts and peanuts. A nut box with a clear cover was constructed and contained various tree nuts and peanuts in shelled and unshelled forms. Attendees at the 2012 national meeting of the American Academy of Allergy, Asthma, and Immunology were offered participation by viewing the nut box and filling in their responses to a questionnaire. A similar procedure was conducted in the Food Allergy Center at Children's Medical Center (Dallas, TX) for guardians of children with and without peanut or tree nut allergies. Allergists were better able to identify and differentiate tree nuts and peanuts than guardians of peanut- or tree nut-allergic children, guardians of children without food allergies, and allergy and immunology fellows in training. It is important for allergists to educate peanut- and tree nut-allergic individuals and their guardians on the proper avoidance of peanuts and tree nuts. This includes education in the ability to identify peanuts and tree nuts. In addition, allergy and immunology fellows in training may benefit from education in proper peanut and tree nut identification. Copyright © 2013 American College of Allergy, Asthma & Immunology. Published by Elsevier Inc. All rights reserved.

78 FR 7266 - Alpha-Cypermethrin; Pesticide Tolerances

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-01

... confidential pursuant to 40 CFR part 2 may be disclosed publicly by EPA without prior notice. Submit the non...- cypermethrin in or on tree nuts, Group 14; dried shelled pea and bean, except soybean, subgroup 6C; corn, grain... shelled pea and bean, subgroup 6B; and root and tuber vegetables, Group 1 at 0.1 ppm; cucurbit vegetables...

Capacitance Sensor For Nondestructive Determination Of Total Oil Content In Nuts

USDA-ARS?s Scientific Manuscript database

Earlier a simple, low cost instrument was designed and assembled in our laboratory, that could estimate the moisture content (MC) of in-shell peanuts (MC range 9% to 20%) and yellow-dent field corn (MC range 7% to 18%). In this method a sample of of in-shell peanuts or corn was placed between a set...

7 CFR 457.167 - Pecan revenue crop insurance provisions.

Code of Federal Regulations, 2013 CFR

2013-01-01

...,000. Approved average revenue per acre. The total of your average gross sales per acre based on at... trees. In-shell pecans. Pecans as they are removed from the orchard with the nut-meats in the shell... average revenue upon which the amount of insurance per acre is based and the number of affected acres; (2...

7 CFR 457.167 - Pecan revenue crop insurance provisions.

Code of Federal Regulations, 2012 CFR

2012-01-01

...,000. Approved average revenue per acre. The total of your average gross sales per acre based on at... trees. In-shell pecans. Pecans as they are removed from the orchard with the nut-meats in the shell... average revenue upon which the amount of insurance per acre is based and the number of affected acres; (2...

Early Indian People.

ERIC Educational Resources Information Center

Doermann, Elisabeth

1979-01-01

Using bits and pieces of the past such as charred bits of wood from campfires, broken pieces of clay pots, stone spearpoints and arrowheads, and shell or copper ornaments, the archaeologist tries to put together the story of early Indian people in the Minnesota region. A short story, one of eight articles, re-creates the kill of an Itasca bison…

Characterization of Aspergillus species on Brazil nut from the Brazilian Amazonian region and development of a PCR assay for identification at the genus level

PubMed Central

2014-01-01

Background Brazil nut is a protein-rich extractivist tree crop in the Amazon region. Fungal contamination of shells and kernel material frequently includes the presence of aflatoxigenic Aspergillus species from the section Flavi. Aflatoxins are polyketide secondary metabolites, which are hepatotoxic carcinogens in mammals. The objectives of this study were to identify Aspergillus species occurring on Brazil nut grown in different states in the Brazilian Amazon region and develop a specific PCR method for collective identification of member species of the genus Aspergillus. Results Polyphasic identification of 137 Aspergillus strains isolated from Brazil nut shell material from cooperatives across the Brazilian Amazon states of Acre, Amapá and Amazonas revealed five species, with Aspergillus section Flavi species A. nomius and A. flavus the most abundant. PCR primers ASP_GEN_MTSSU_F1 and ASP_GEN_MTSSU_R1 were designed for the genus Aspergillus, targeting a portion of the mitochondrial small subunit ribosomal RNA gene. Primer specificity was validated through both electronic PCR against target gene sequences at Genbank and in PCR reactions against DNA from Aspergillus species and other fungal genera common on Brazil nut. Collective differentiation of the observed section Flavi species A. flavus, A. nomius and A. tamarii from other Aspergillus species was possible on the basis of RFLP polymorphism. Conclusions Given the abundance of Aspergillus section Flavi species A. nomius and A. flavus observed on Brazil nut, and associated risk of mycotoxin accumulation, simple identification methods for such mycotoxigenic species are of importance for Hazard Analysis Critical Control Point system implementation. The assay for the genus Aspergillus represents progress towards specific PCR identification and detection of mycotoxigenic species. PMID:24885088

Biodiversity of mycobiota throughout the Brazil nut supply chain: From rainforest to consumer.

PubMed

Taniwaki, Marta H; Frisvad, Jens C; Ferranti, Larissa S; de Souza Lopes, Aline; Larsen, Thomas O; Fungaro, Maria Helena P; Iamanaka, Beatriz T

2017-02-01

A total of 172 Brazil nut samples (114 in shell and 58 shelled) from the Amazon rainforest region and São Paulo state, Brazil was collected at different stages of the Brazil nut production chain: rainforest, street markets, processing plants and supermarkets. The mycobiota of the Brazil nut samples were evaluated and also compared in relation to water activity. A huge diversity of Aspergillus and Penicillium species were found, besides Eurotium spp., Zygomycetes and dematiaceous fungi. A polyphasic approach using morphological and physiological characteristics, as well as molecular and extrolite profiles, were studied to distinguish species among the more important toxigenic ones in Aspergillus section Flavi and A. section Nigri. Several metabolites and toxins were found in these two sections. Ochratoxin A (OTA) was found in 3% of A. niger and 100% of A. carbonarius. Production of aflatoxins B and G were found in all isolates of A. arachidicola, A. bombycis, A. nomius, A. pseudocaelatus and A. pseudonomius, while aflatoxin B was found in 38% of A. flavus and all isolates of A. pseudotamarii. Cyclopiazonic acid (CPA) was found in A. bertholletius (94%), A. tamarii (100%), A. caelatus (54%) and A. flavus (41%). Tenuazonic acid, a toxin commonly found in Alternaria species was produced by A. bertholletius (47%), A. caelatus (77%), A. nomius (55%), A. pseudonomius (75%), A. arachidicola (50%) and A. bombycis (100%). This work shows the changes of Brazil nut mycobiota and the potential of mycotoxin production from rainforest to consumer, considering the different environments which exist until the nuts are consumed. Copyright © 2016 Elsevier Ltd. All rights reserved.

Antinociceptive and antiedematogenic effect of pecan (Carya illinoensis) nut shell extract in mice: a possible beneficial use for a by-product of the nut industry.

PubMed

Trevisan, Gabriela; Rossato, Mateus F; Hoffmeister, Carin; Müller, Liz G; Pase, Camila; Córdova, Marina M; Rosa, Fernanda; Tonello, Raquel; Hausen, Bruna S; Boligon, Aline A; Moresco, Rafael N; Athayde, Margareth L; Burguer, Marilise E; Santos, Adair R; Ferreira, Juliano

2014-01-27

Abstract Background: Interest in pecan (Carya illinoensis) nut shells, a by-product of the nut industry, has increased due to its anti-inflammatory and antioxidant activities. The goal of this study was to evaluate the antinociceptive and antiedematogenic activity and the mechanisms of the pecan shell aqueous extract (AE). Methods: First, we performed fingerprinting of C. illinoensis AE. The antinociceptive and antiedematogenic effects of AE intragastric (i.g.) administration in mice (male Swiss mice 20-30 g) were evaluated using the acetic acid test or after subcutaneous (s.c.) paw injection of diverse transient receptor potential ankyrin 1 (TRPA1) agonists, including hydrogen peroxide (H2O2), allyl isothiocyanate, or cinnamaldehyde. We also observed AE antinociceptive and antiedematogenic effects after carrageenan s.c. paw injection and measured H2O2 production. Moreover, we observed the development of adverse effects after AE i.g. treatment. Results: The high-performance liquid chromatography fingerprinting of AE showed the presence of rutin. AE or rutin i.g. treatment produced antinociception in the acetic acid test and reduced the nociception and edema mediated by H2O2 s.c. hind paw injection or nociception induced by other TRPA1 agonists. Moreover, AE or rutin reduced the hyperalgesia, edema, and H2O2 production induced by carrageenan s.c. paw injection. No motor, gastric, or toxicological alterations were observed after AE administration. Conclusions: Collectively, the present results show that AE and its constituent rutin produced antinociceptive and antiedematogenic action in models of acute and persistent inflammatory nociception and it seems to be related to the inhibition of TRPA1 receptor activation.

Penicillium excelsum sp. nov from the Brazil Nut Tree Ecosystem in the Amazon Basin'.

PubMed

Taniwaki, Marta Hiromi; Pitt, John I; Iamanaka, Beatriz T; Massi, Fernanda P; Fungaro, Maria Helena P; Frisvad, Jens C

2015-01-01

A new Penicillium species, P. excelsum, is described here using morphological characters, extrolite and partial sequence data from the ITS, β-tubulin and calmodulin genes. It was isolated repeatedly using samples of nut shells and flowers from the brazil nut tree, Bertolletia excelsa, as well as bees and ants from the tree ecosystem in the Amazon rainforest. The species produces andrastin A, curvulic acid, penicillic acid and xanthoepocin, and has unique partial β-tubulin and calmodulin gene sequences. The holotype of P. excelsum is CCT 7772, while ITAL 7572 and IBT 31516 are cultures derived from the holotype.

Penicillium excelsum sp. nov from the Brazil Nut Tree Ecosystem in the Amazon Basin’

PubMed Central

Taniwaki, Marta Hiromi; Pitt, John I.; Iamanaka, Beatriz T.; Massi, Fernanda P.; Fungaro, Maria Helena P.; Frisvad, Jens C.

2015-01-01

A new Penicillium species, P. excelsum, is described here using morphological characters, extrolite and partial sequence data from the ITS, β-tubulin and calmodulin genes. It was isolated repeatedly using samples of nut shells and flowers from the brazil nut tree, Bertolletia excelsa, as well as bees and ants from the tree ecosystem in the Amazon rainforest. The species produces andrastin A, curvulic acid, penicillic acid and xanthoepocin, and has unique partial β-tubulin and calmodulin gene sequences. The holotype of P. excelsum is CCT 7772, while ITAL 7572 and IBT 31516 are cultures derived from the holotype. PMID:26717519

Removal of Volatile Organics from Humidified Air Streams by Absorption.

DTIC Science & Technology

1987-12-01

Type Comments Activated Carbons: SK-4 nut shell LCL coconut shell WV-B coal base CT coconut shell Specialty Carbons: Graphpac graphitized carbon area...Capacity, g/g Percentage Sorbent ( virgin ) (treated)D Change SK-4 0.114 0.117 +2.6 Carbosieve S-11 0.195 0.180 -7.7 Spherocarb 0.149 0.151 +1.3 CT...and WV-B with respect to their adsorption capacities. CT and SK-4 are both coconut -derived carbons produced by the same manufacturer. Differences

Cashew Nut Positioning during Stone Tool Use by Wild Bearded Capuchin Monkeys (Sapajus libidinosus).

PubMed

Falótico, Tiago; Luncz, Lydia V; Svensson, Magdalena S; Haslam, Michael

2016-01-01

Wild capuchin monkeys (Sapajus libidinosus) at Serra da Capivara National Park, Brazil, regularly use stone tools to break open cashew nuts (Anacardium spp.). Here we examine 2 approaches used by the capuchins to position the kidney-shaped cashew nuts on an anvil before striking with a stone tool. Lateral positioning involves placing the nut on its flatter, more stable side, therefore requiring less attention from the monkey during placement. However, the less stable and never previously described arched position, in which the nut is balanced with its curved side uppermost, requires less force to crack the outer shell. We observed cashew nut cracking in a field experimental setting. Only 6 of 20 adults, of both sexes, were observed to deliberately place cashew nuts in an arched position, which may indicate that the technique requires time and experience to learn. We also found that use of the arched position with dry nuts, but not fresh, required, in 63% of the time, an initial processing to remove one of the cashew nut lobes, creating a more stable base for the arch. This relatively rare behaviour appears to have a complex ontogeny, but further studies are required to establish the extent to which social learning is involved. © 2017 S. Karger AG, Basel.

Aqueous extract of pecan nut shell (Carya illinoensis [Wangenh.] K. Koch) exerts protection against oxidative damage induced by cyclophosphamide in rat testis.

PubMed

Benvegnu, Dalila M; Barcelos, Raquel C S; Roversi, Katiane; Boufleur, Nardelli; Pase, Camila S; Trevizol, Fabiola; Segat, Hecson J; Dias, Verônica T; Dolci, Geisa S; Antoniazzi, Caren T D; Reckziegel, Patricia; Lima, Fernanda; de Lima, Luiz A R; de Carvalho, Leandro M; da Silva Junior, Valdemiro A; Burger, Marilise E

2013-01-01

This study investigated the protective effect of pecan nut (Carya illinoensis) shell aqueous extract (AE) on the oxidative and morphological status of rat testis treated with cyclophosphamide (CP). Wistar rats received water or AE (5%) ad libitum for 37 days. On day 30, half of each group received a single intraperitoneal administration of vehicle or CP 200 mg/kg. After 7 days, the animals were killed and their testis removed. Rats treated with CP presented reduced levels of lactate dehydrogenase, vitamin C, and gluthatione, as well as decreased catalase activity, increased lipid peroxidation levels and superoxide dismutase activity, no alteration in carbonyl protein levels, and a loss of morphological testicular integrity. In contrast, cotreatment with pecan shell AE totally prevented the decrease of lactate dehydrogenase and vitamin C levels and catalase activity and partially prevented the depletion of gluthatione levels. Moreover, it totally prevented the increase in superoxide dismutase activity and lipid peroxidation levels and maintained testicular integrity. These findings show the protective role of pecan shell AE in CP-induced testicular toxicity. The use of this phytotherapy may be considered to minimize deleterious effects related to this chemotherapy.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dai, X.; Antal, M.J. Jr.

Macadamia nut shell charcoal was heated in an inert environment to temperatures above 1000 K (carbonized), reacted with oxygen (Po{sub 2} = 2.68--11.3 kPa) at temperatures between 525 and 586 K (oxygenated), and heated again in an inert environment to temperatures above 1000 K (activated) to produce an activated carbon. Carbons produced by this process possess surface areas and iodine numbers in the range of 400--550. Overall yields of these carbons (based on the dry, raw macadamia nut shell feed) ranged from 24 to 30 wt %. Under the conditions employed in this work, the rates of chemisorption and gasificationmore » were not mass transfer limited. Initially, the gasification reaction was first-order with respect to oxygen concentration but became independent of oxygen concentration as the surface sites of the carbon became saturated with oxygen.« less

7 CFR 51.2555 - General.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Standards for Grades of Shelled Pistachio Nuts § 51.2555 General. (a) Compliance with the provisions of.... (b) These standards are applicable to raw, roasted, salted or salted/roasted pistachio kernels. [55...

Evaluation of Toxicological Effects of an Aqueous Extract of Shells from the Pecan Nut Carya illinoinensis (Wangenh.) K. Koch and the Possible Association with Its Inorganic Constituents and Major Phenolic Compounds.

PubMed

Porto, Luiz Carlos S; da Silva, Juliana; Sousa, Karen; Ambrozio, Mariana L; de Almeida, Aline; Dos Santos, Carla Eliete I; Dias, Johnny F; Allgayer, Mariangela C; Dos Santos, Marcela S; Pereira, Patrícia; Ferraz, Alexandre B F; Picada, Jaqueline N

2016-01-01

Background. Industrial processing of the pecan nut Carya illinoinensis K. Koch generated a large amount of shells, which have been used to prepare nutritional supplements and medicinal products; however, the safe use of shells requires assessment. This study evaluated the toxic, genotoxic, and mutagenic effects of pecan shell aqueous extract (PSAE) and the possible contribution of phenolic compounds, ellagic and gallic acids, and inorganic elements present in PSAE to induce toxicity. Results. Levels of inorganic elements like K, P, Cl, and Rb quantified using the Particle-Induced X-Ray Emission method were higher in PSAE than in pecan shells, while Mg and Mn levels were higher in shells. Mice showed neurobehavioral toxicity when given high PSAE doses (200-2,000 mg kg(-1)). The LD50 was 1,166.3 mg kg(-1). However, PSAE (50-200 mg·kg(-1)) and the phenolic compounds (10-100 mg·kg(-1)) did not induce DNA damage or mutagenicity evaluated using the comet assay and micronucleus test. Treatment with ellagic acid (10-100 mg·kg(-1)) decreased triglyceride and glucose levels, while treatments with PSAE and gallic acid had no effect. Conclusion. Pecan shell toxicity might be associated with high concentrations of inorganic elements such as Mn, Al, Cu, and Fe acting on the central nervous system, besides phytochemical components, suggesting that the definition of the safe dose should take into account the consumption of micronutrients.

Evaluation of Toxicological Effects of an Aqueous Extract of Shells from the Pecan Nut Carya illinoinensis (Wangenh.) K. Koch and the Possible Association with Its Inorganic Constituents and Major Phenolic Compounds

PubMed Central

Porto, Luiz Carlos S.; Sousa, Karen; Ambrozio, Mariana L.; de Almeida, Aline; dos Santos, Carla Eliete I.; Dias, Johnny F.; Allgayer, Mariangela C.; dos Santos, Marcela S.; Pereira, Patrícia; Picada, Jaqueline N.

2016-01-01

Background. Industrial processing of the pecan nut Carya illinoinensis K. Koch generated a large amount of shells, which have been used to prepare nutritional supplements and medicinal products; however, the safe use of shells requires assessment. This study evaluated the toxic, genotoxic, and mutagenic effects of pecan shell aqueous extract (PSAE) and the possible contribution of phenolic compounds, ellagic and gallic acids, and inorganic elements present in PSAE to induce toxicity. Results. Levels of inorganic elements like K, P, Cl, and Rb quantified using the Particle-Induced X-Ray Emission method were higher in PSAE than in pecan shells, while Mg and Mn levels were higher in shells. Mice showed neurobehavioral toxicity when given high PSAE doses (200–2,000 mg kg−1). The LD50 was 1,166.3 mg kg−1. However, PSAE (50–200 mg·kg−1) and the phenolic compounds (10–100 mg·kg−1) did not induce DNA damage or mutagenicity evaluated using the comet assay and micronucleus test. Treatment with ellagic acid (10–100 mg·kg−1) decreased triglyceride and glucose levels, while treatments with PSAE and gallic acid had no effect. Conclusion. Pecan shell toxicity might be associated with high concentrations of inorganic elements such as Mn, Al, Cu, and Fe acting on the central nervous system, besides phytochemical components, suggesting that the definition of the safe dose should take into account the consumption of micronutrients. PMID:27525021

40 CFR 180.649 - Saflufenacil; tolerances for residues.

Code of Federal Regulations, 2012 CFR

2012-07-01

....10 Banana 1 0.03 Coffee, green bean 1 0.03 Cotton, gin byproducts 0.45 Cottonseed subgroup 20C 0.20... Mango 1 0.03 Nut, tree, group 14 0.03 Pea and bean, dried shelled, except soybean, subgroup 6C 0.30 Pea and bean, succulent shelled, subgroup 6B 0.03 Pea, hay 17 Pistachio 0.03 Rapeseed subgroup 20A 0.45...

40 CFR 180.649 - Saflufenacil; tolerances for residues.

Code of Federal Regulations, 2014 CFR

2014-07-01

....10 Banana 1 0.03 Coffee, green bean 1 0.03 Cotton, gin byproducts 0.45 Cottonseed subgroup 20C 0.20... Mango 1 0.03 Nut, tree, group 14 0.03 Pea and bean, dried shelled, except soybean, subgroup 6C 0.30 Pea and bean, succulent shelled, subgroup 6B 0.03 Pea, hay 17 Pistachio 0.03 Rapeseed subgroup 20A 0.45...

40 CFR 180.649 - Saflufenacil; tolerances for residues.

Code of Federal Regulations, 2013 CFR

2013-07-01

....10 Banana 1 0.03 Coffee, green bean 1 0.03 Cotton, gin byproducts 0.45 Cottonseed subgroup 20C 0.20... Mango 1 0.03 Nut, tree, group 14 0.03 Pea and bean, dried shelled, except soybean, subgroup 6C 0.30 Pea and bean, succulent shelled, subgroup 6B 0.03 Pea, hay 17 Pistachio 0.03 Rapeseed subgroup 20A 0.45...

7 CFR 51.2540 - General.

Code of Federal Regulations, 2011 CFR

2011-01-01

... these standards shall not excuse failure to comply with provisions of applicable Federal or State laws. (b) These standards are applicable to pistachio nuts in the shell which may be in a natural, dyed...

Potential of Aqueous Ozone to Control Aflatoxigenic Fungi in Brazil Nuts

PubMed Central

Morales-Valle, Héctor; Venâncio, Armando

2013-01-01

This study aimed to verify the use of aqueous ozone as alternative technology for fungal control. Brazil nuts sterilized were inoculated with either 1 × 106 or 1 × 107 conidia mL−1 of Aspergillus flavus (MUM 9201) to determine optimal treatment parameters and different aqueous ozone contact times. These assays showed that the effect of ozone is almost immediate against A. flavus, and the optimum ozone concentration depended on the number of initial viable spores on the shell. The remaining viable spores in the ozone solution were recorded, and the rate of inactivation for each treatment was determined by assessing the ratio between the cfu of each treatment and the control. The ozonized nuts were also cultured to recover the fungal population. Aqueous ozone was effective in reducing the conidia of A. flavus and the natural fungal population associated with Brazil nuts. Aqueous ozone presented a great potential to reduce microorganisms counts in Brazil nuts with a great potential use in packing houses for decontamination step. PMID:25937982

Effects of industrial cashew nut processing on anacardic acid content and allergen recognition by IgE.

PubMed

Mattison, Christopher P; Malveira Cavalcante, Jéfferson; Izabel Gallão, Maria; Sousa de Brito, Edy

2018-02-01

Cashew nuts are important both nutritionally and industrially, but can also cause food allergies in some individuals. The present study aimed to assess the effect(s) of industrial processing on anacardic acids and allergens present in cashew nuts. Sample analyses were performed using liquid chromatography coupled with mass spectrometry, SDS-PAGE and immunoassay. The anacardic acid concentration ranged from 6.2 to 82.6mg/g during processing, and this variation was attributed to cashew nut shell liquid incorporation during storage and humidification. Dehydrated and selected samples did not significantly differ in anacardic acid content, having values similar to the raw sample. SDS-PAGE and immunoassay analysis with rabbit polyclonal sera and human IgE indicated only minor differences in protein solubility and antibody binding following processing steps. The findings indicate that appreciable amounts of anacardic acid remain in processed nuts, and that changes to cashew allergens during industrial processing may only mildly affect antibody recognition. Published by Elsevier Ltd.

7 CFR 51.2559 - Size classifications.

Code of Federal Regulations, 2010 CFR

2010-01-01

... STANDARDS) United States Standards for Grades of Shelled Pistachio Nuts § 51.2559 Size classifications. (a) The size of pistachio kernels may be specified in connection with the grade in accordance with one of...

7 CFR 93.10 - General.

Code of Federal Regulations, 2010 CFR

2010-01-01

... FRUITS AND VEGETABLES Peanuts, Tree Nuts, Corn and Other Oilseeds § 93.10 General. Chemical analyses are performed to detect the presence of aflatoxin in lots of shelled peanuts and peanut products, as well as in...

7 CFR 93.10 - General.

Code of Federal Regulations, 2011 CFR

2011-01-01

... FRUITS AND VEGETABLES Peanuts, Tree Nuts, Corn and Other Oilseeds § 93.10 General. Chemical analyses are performed to detect the presence of aflatoxin in lots of shelled peanuts and peanut products, as well as in...

7 CFR 51.2540 - General.

Code of Federal Regulations, 2013 CFR

2013-01-01

... provisions of applicable Federal or State laws. (b) These standards are applicable to pistachio nuts in the shell which may be in a natural, dyed, raw, roasted, or salted state; or in any combination thereof...

7 CFR 51.2956 - Practically clean.

Code of Federal Regulations, 2010 CFR

2010-01-01

... dirt or other foreign matter, and that individual walnuts are not damaged by such means. A slightly chalky deposit on the shell is characteristic of many bleached nuts and shall not be considered as dirt...

Antioxidant, larvicidal and antiacetylcholinesterase activities of cashew nut shell liquid constituents.

PubMed

Oliveira, Micheline Soares Costa; Morais, Selene Maia de; Magalhães, Davi Varela; Batista, Williams Pereira; Vieira, Icaro Gusmão Pinto; Craveiro, Afrânio Aragão; de Manezes, Jane Eire Silva Alencar; Carvalho, Ana Fontenelle Urano; de Lima, Glauber Pacelli Gomes

2011-03-01

Anacardic acid, cardanol and cardol, the main constituents of natural cashew nut shell liquid (CNSL), were obtained by solvent extraction and assayed for antioxidant, larvicidal and antiacetylcholinesterase activity. Their relative percent composition was obtained by HPLC analysis. Antioxidant activity was assessed using the DPPH and ABTS(+) tests, which showed cardanol as the most active, followed by cardol and anacardic acid. The three CNSL components demonstrated good larvicidal activity against Aedes aegypti (LC(50)=12.40 for anacardic acid, 10.22 for cardol and 14.45 for cardanol) and exhibited inhibition zones for acetylcholinesterase enzymes in the TLC test similar to carbachol, which was used as standard. Based on the results, these multipotent compounds represent promising agents in the control of Ae. aegypti, the main dengue vector in Brazil. Copyright © 2011. Published by Elsevier B.V.

Assessment of the microbiological safety of edible roasted nut kernels on retail sale in England, with a focus on Salmonella.

PubMed

Little, C L; Jemmott, W; Surman-Lee, S; Hucklesby, L; de Pinnal, E

2009-04-01

There is little published information on the prevalence of Salmonella in edible nut kernels. A study in early 2008 of edible roasted nut kernels on retail sale in England was undertaken to assess the microbiological safety of this product. A total of 727 nut kernel samples of different varieties were examined. Overall, Salmonella and Escherichia coli were detected from 0.2 and 0.4% of edible roasted nut kernels. Of the nut varieties examined, Salmonella Havana was detected from 1 (4.0%) sample of pistachio nuts, indicating a risk to health. The United Kingdom Food Standards Agency was immediately informed, and full investigations were undertaken. Further examination established the contamination to be associated with the pistachio kernels and not the partly opened shells. Salmonella was not detected in other varieties tested (almonds, Brazils, cashews, hazelnuts, macadamia, peanuts, pecans, pine nuts, and walnuts). E. coli was found at low levels (range of 3.6 to 4/g) in walnuts (1.4%), almonds (1.2%), and Brazils (0.5%). The presence of Salmonella is unacceptable in edible nut kernels. Prevention of microbial contamination in these products lies in the application of good agricultural, manufacturing, and storage practices together with a hazard analysis and critical control points system that encompass all stages of production, processing, and distribution.

Biochar potential evaluation of palm oil wastes through slow pyrolysis: Thermochemical characterization and pyrolytic kinetic studies.

PubMed

Lee, Xin Jiat; Lee, Lai Yee; Gan, Suyin; Thangalazhy-Gopakumar, Suchithra; Ng, Hoon Kiat

2017-07-01

This research investigated the potential of palm kernel shell (PKS), empty fruit bunch (EFB) and palm oil sludge (POS), abundantly available agricultural wastes, as feedstock for biochar production by slow pyrolysis (50mLmin -1 N 2 at 500°C). Various characterization tests were performed to establish the thermochemical properties of the feedstocks and obtained biochars. PKS and EFB had higher lignin, volatiles, carbon and HHV, and lower ash than POS. The thermochemical conversion had enhanced the biofuel quality of PKS-char and EFB-char exhibiting increased HHV (26.18-27.50MJkg -1 ) and fixed carbon (53.78-59.92%), and decreased moisture (1.03-2.26%). The kinetics of pyrolysis were evaluated by thermogravimetry at different heating rates (10-40°C). The activation energies determined by Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa models were similar, and comparable with literature data. The findings implied that PKS and EFB are very promising sources for biochars synthesis, and the obtained chars possessed significant biofuel potential. Copyright © 2017 Elsevier Ltd. All rights reserved.

40 CFR 180.479 - Halosulfuron-methyl; tolerances for residues.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Alfalfa, forage 1.0 Alfalfa, hay 2.0 Almond, hulls 0.2 Apple 0.05 Asparagus 0.8 Bean, dry, seed 0.05... subgroup 9A 0.1 Nut, tree, group 14 0.05 Okra 0.05 Pea and bean, succulent shelled, subgroup 6 0.05 Pea and bean, succulent shelled, subgroup 6B 0.05 Pistachio 0.05 Rhubarb 0.05 Rice, grain 0.05 Rice, straw 0.2...

40 CFR 180.479 - Halosulfuron-methyl; tolerances for residues.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Alfalfa, forage 1.0 Alfalfa, hay 2.0 Almond, hulls 0.2 Apple 0.05 Asparagus 0.8 Bean, dry, seed 0.05... subgroup 9A 0.1 Nut, tree, group 14 0.05 Okra 0.05 Pea and bean, succulent shelled, subgroup 6 0.05 Pea and bean, succulent shelled, subgroup 6B 0.05 Pistachio 0.05 Rhubarb 0.05 Rice, grain 0.05 Rice, straw 0.2...

40 CFR 180.479 - Halosulfuron-methyl; tolerances for residues.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Bean, dry, seed 0.05 Bushberry, subgroup 13-07B 0.05 Corn, field, forage 0.2 Corn, field, grain 0.05..., hay 0.01 Millet, proso, straw 0.01 Nut, tree, group 14 0.05 Okra 0.05 Pea and bean, succulent shelled, subgroup 6 0.05 Pea and bean, succulent shelled, subgroup 6B 0.05 Pistachio 0.05 Rhubarb 0.05 Rice, grain 0...

Protective effects of a by-product of the pecan nut industry (Carya illinoensis) on the toxicity induced by cyclophosphamide in rats Carya illinoensis protects against cyclophosphamide-induced toxicity.

PubMed

Benvegnú, D; Barcelos, R C S; Boufleur, N; Reckziegel, P; Pase, C S; Müller, L G; Martins, N M B; Vareli, C; Bürger, M E

2010-01-01

This study investigated the antioxidant effects of pecan nut (Carya illinoensis) shell aqueous extract (AE) on toxicity induced by cyclophosphamide (CP) in the heart, kidney, liver, bladder, plasma and erythrocytes of rats. Rats were treated with water or pecan shell AE (5%) ad libitum, replacing drinking water for 37 days up to the end of the experiment. On day 30, half of each group received a single administration of vehicle or CP 200 mg/kg-ip. After 7 days, the organs were removed. Rats treated with CP showed an increase in lipid peroxidation (LP) and decrease in reduced glutathione (GSH) levels in all structures. Catalase (CAT) activity was increased in the heart and decreased in liver and kidney. Besides, CP treatment decreased plasmatic vitamin C (VIT C) levels and induced bladder macroscopical and microscopical damages. In contrast, co-treatment with pecan shell AE prevented the LP development and the GSH depletion in all structures, except in the heart and plasma, respectively. CAT activity in the heart and liver as well as the plasmatic VIT C levels remained unchanged. Finally, AE prevented CP-induced bladder injury. These findings revealed the protective role of pecan shell AE in CP-induced multiple organ toxicity.

Crustacean derived calcium phosphate systems: Application in defluoridation of drinking water in East African rift valley.

PubMed

Wagutu, Agatha W; Machunda, Revocatus; Jande, Yusufu Abeid Chande

2018-04-05

Calcium phosphate adsorbents, derived from prawns and crabs shell biomass wastes have been developed using wet chemistry and low temperature treatment. The adsorbents were characterized by X-ray diffractometry and Fourier transform infrared spectroscopy. Batch adsorption test were carried out to investigate their effectiveness in adsorption of fluoride from ground and surface waters. Adsorption capacities were compared with bone char and synthetic hydroxyapatite (CCHA). Results indicate that prawns derived adsorbent (PHA) formed hexagonal structure with phases identifiable with hydroxyapatite while crabs based adsorbent (CHA) formed predominantly monoclinic structure with crystalline phase characteristic of brushite. Vibrational analysis and kinetic studies predicted defluoridation occurred mainly by ion exchange and ion adsorption mechanisms. Defluoridation capacity of the adsorbents was found to be superior compared to bone char and CCHA. CHA was the most effective with efficiencies above 92% and highest capacity of 13.6 mg/g in field water with fluoride concentration of 5-70 mg/L. PHA had highest capacity of 8.5 mg/g which was still better than 2.6 mg/g recorded by CCHA and bone char. Adsorption was best described by pseudo 2nd order kinetics. The findings indicate that crustacean derived calcium phosphate systems have better potential for defluoridation than traditional bone char and synthetic systems. Copyright © 2017 The Author(s). Published by Elsevier B.V. All rights reserved.

Hepatoprotective effects of pecan nut shells on ethanol-induced liver damage.

PubMed

Müller, Liz Girardi; Pase, Camila Simonetti; Reckziegel, Patrícia; Barcelos, Raquel C S; Boufleur, Nardeli; Prado, Ana Cristina P; Fett, Roseane; Block, Jane Mara; Pavanato, Maria Amália; Bauermann, Liliane F; da Rocha, João Batista Teixeira; Burger, Marilise Escobar

2013-01-01

The hepatoprotective activity of the aqueous extract of the shells of pecan nut was investigated against ethanol-induced liver damage. This by-product of the food industry is popularly used to treat toxicological diseases. We evaluated the phytochemical properties of pecan shell aqueous extract (AE) and its in vitro and ex vivo antioxidant activity. The AE was found to have a high content of total polyphenols (192.4±1.9 mg GAE/g), condensed tannins (58.4±2.2 mg CE/g), and antioxidant capacity, and it inhibited Fe(2+)-induced lipid peroxidation (LP) in vitro. Rats chronically treated with ethanol (Et) had increased plasmatic transaminases (ALT, AST) and gamma glutamyl transpeptidase (GGT) levels (96%, 59.13% and 465.9%, respectively), which were effectively prevented (87; 41 and 383%) by the extract (1:40, w/v). In liver, ethanol consumption increased the LP (121%) and decreased such antioxidant defenses as glutathione (GSH) (33%) and superoxide dismutase (SOD) (47%) levels, causing genotoxicity in erythrocytes. Treatment with pecan shell AE prevented the development of LP (43%), GSH and SOD depletion (33% and 109%, respectively) and ethanol-induced erythrocyte genotoxicity. Catalase activity in the liver was unchanged by ethanol but was increased by the extract (47% and 73% in AE and AE+Et, respectively). Therefore, pecan shells may be an economic agent to treat liver diseases related to ethanol consumption. Copyright © 2011 Elsevier GmbH. All rights reserved.

When and where to practice: social influences on the development of nut-cracking in bearded capuchins (Sapajus libidinosus).

PubMed

Eshchar, Y; Izar, P; Visalberghi, E; Resende, B; Fragaszy, D

2016-05-01

The habitual use of tools by wild capuchin monkeys presents a unique opportunity to study the maintenance and transmission of traditions. Young capuchins spend several years interacting with nuts before cracking them efficiently with stone tools. Using a two-observer method, we quantified the magnitude of the social influences that sustain this long period of practice. During five collection periods (over 26 months), one observer recorded the behavior of 16 immature monkeys, and another observer concurrently recorded behavior of group members in the focal monkey's vicinity. The two-observer method provides a means to quantify distinct social influences. Data show that immatures match the behavior of the adults in time and especially in space. The rate of manipulation of nuts by the immatures quadrupled when others in the group cracked and ate nuts, and immatures were ten times more likely to handle nuts and 40 times more likely to strike a nut with a stone when they themselves were near the anvils. Moreover, immature monkeys were three times more likely to be near an anvil when others were cracking. We suggest a model for social influence on nut-cracking development, based on two related processes: (1) social facilitation from observing group members engaged in nut-cracking, and (2) opportunity for practice provided by the anvils, hammer stones and nut shells available on and around the anvils. Nut-cracking activities by others support learning by drawing immatures to the anvils, where extended practice can take place, and by providing materials for practice at these places.

7 CFR 983.14 - Handle.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE PISTACHIOS GROWN IN CALIFORNIA, ARIZONA, AND NEW MEXICO Definitions § 983.14 Handle. Handle means to engage in: (a) Receiving pistachios; (b) Hulling and drying pistachios; (c) Further preparing pistachios by sorting, sizing, shelling, roasting...

Biochar, Tool for Climate Change Mitigation and Soil Management

NASA Astrophysics Data System (ADS)

Shackley, Simon; Sohi, Saran; Ibarrola, Rodrigo; Hammond, Jim; Mašek, Ondřej; Brownsort, Peter; Cross, Andrew; Prendergast-Miller, Miranda; Haszeldine, Stuart

Biochar is the solid remains of any organic material that has been heated to at least 350oC in a zero-oxygen or oxygen-limited environment, which is intended to be mixed with soils. If the solid remains are not suitable for addition to soils, or will be burned as a fuel or used as an aggregate in construction, it is defined as char not biochar. There is a very wide range of potential biochar feedstocks, e.g., wood waste, timber, agricultural residues and wastes (straws, bagasse, manure, husks, shells, fibers, etc.), leaves, food wastes, paper and sewage sludge, green waste, distiller's grain, and many others. Pyrolysis is usually the technology of choice for producing biochar, though biomass gasification also produces smaller char yields. Syngas and pyrolytic bio-liquids, which have a potential use as energy carriers, are produced alongside biochar.

Radio frequency heating: a potential method for post-harvest pest control in nuts and dry products

PubMed Central

Wang, Shao-jin; Tang, Ju-ming

2004-01-01

The multi-billion dollar US tree nut industries rely heavily on methyl bromide fumigation for postharvest insect control and are facing a major challenge with the mandated cessation by 2005 of its use for most applications. There is an urgent need to develop effective and economically viable alternative treatments to replace current phytosanitary and quarantine practices in order to maintain the competitiveness of US agriculture in domestic and international markets. With the reliable heating block system, the thermal death kinetics for fifth-instar codling moth, Indianmeal moth, and navel orangeworm were determined at a heating rate of 18 °C/min. A practical process protocol was developed to control the most heat resistant insect pest, fifth-instar navel orangeworm, in in-shell walnuts using a 27 MHz pilot scale radio frequency (RF) system. RF heating to 55 °C and holding in hot air for at least 5 min resulted in 100% mortality of the fifth-instar navel orangeworm. Rancidity, sensory qualities and shell characteristics were not affected by the treatments. If this method can be economically integrated into the handling process, it should have excellent potential as a disinfestation method for in-shell walnuts. PMID:15362185

7 CFR 51.2556 - Grades.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Standards for Grades of Shelled Pistachio Nuts § 51.2556 Grades. (a) “U.S. Fancy,” “U.S. Extra No. 1,” and “U.S. No. 1” consist of pistachio kernels which meet the following requirements: (1) Well dried, or...

Survival and growth of salmonella in high-moisture pecan nutmeats, in-shell pecans, inedible nut components, and orchard soil.

PubMed

Beuchat, Larry R; Mann, David A

2010-11-01

Outbreaks of salmonellosis associated with almonds have raised interest in better understanding the behavior of Salmonella on other tree nuts. We undertook a study to determine the survival and growth characteristics of Salmonella on high-moisture (water activity of 0.96 to 0.99) pecan nutmeats, in-shell pecans, and inedible components (shuck, shell, and middle septum tissue) of in-shell pecans. Salmonella did not grow on high-moisture nutmeat halves, pieces, or granules stored at 4°C for up to 48 h. Growth did occur, however, at 21, 30, and 37°C. Increases of 1.77 to 5.87 log CFU/g of nutmeats occurred within 48 h at 37°C; the order in which nutmeats supported growth was granules > pieces > halves. Populations of Salmonella on and in high-moisture in-shell pecans (kernel water activity of 0.94) stored at 4, 21, 30, and 37°C for 8 days decreased by 0.52 to 1.19 log CFU/g. The pathogen grew on the surface of high-moisture (water activity of 0.99) pecan shucks and shells but died on middle septum tissue stored at 21, 30, and 37°C for up to 6 days. Salmonella died in water extracts of shucks and in pecan orchard soil saturated with water or shuck extract, but survived well for at least 18 weeks in dry soil. The ability of the pathogen to grow on high-moisture nutmeats and some of the inedible components of pecans emphasizes the importance of controlling or limiting the time pecans are exposed to water in preharvest and postharvest environments.

Experimental characterization of fire-induced response of rigid polyurethane foam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chu, T.Y.; Gill, W.; Moore, J.W.

1995-12-31

Reported is the result of an experimental investigation of fire-induced response of a 96 kg/m{sup 3} closed cell rigid polyurethane foam. The specimen is 0.37 m in diameter, and 152 mm thick, placed in a cylindrical test vessel. The fire condition is simulated by heating the bottom of the test vessel to 1283 K using a radiant heat source. Real-time x-ray shows that the degradation process involves the progression of a charring front into the virgin material. The charred region has a regular and graded structure consisting of a packed bubble outer layer and successive layers of thin shells. Themore » layer-to-layer permeability appears to be poor. There are indications that gas vents laterally. The shell-like structure might be the result of lateral venting. Although the foam degradation process is quite complicated, the in-depth temperature responses in the uncharted foam appear to be consistent with steady state ablation. The measured temperature responses are well represented by the exponential distribution for steady state ablation. An estimate of the thermal diffusivity of the foam is obtained from the ablation model. The experiment is part of a more comprehensive program to develop material response models of foams and encapsulants.« less

Response of postharvest tree nut lepidopteran pests to vacuum treatments.

PubMed

Johnson, J A; Zettler, J L

2009-10-01

Industry concerns over insect resistance, regulatory action, and the needs of organic processors have renewed interest in nonchemical alternative postharvest treatments to fumigants used for California tree nuts. The development of inexpensive polyvinyl chloride containers capable of holding low pressures has increased the practicality of vacuum treatments for durable commodities such as tree nuts. To develop vacuum treatment protocols, we determined the relative tolerance to vacuum (50 mmHg) at 25 and 30 degrees C of different life stages of three postharvest pests of tree nuts: codling moth, Cydia pomonella (L.), navel orangeworm, Amyelois transitella (Walker), and Indianmeal moth, Plodia interpunctella (Hübner). At both temperatures, nondiapausing codling moth larvae were the least tolerant stage tested. LT95 values for diapausing Indianmeal moth larvae were similar to Indianmeal moth eggs at both temperatures. Indianmeal moth diapausing larvae and eggs were the most tolerant at 25 degrees C, whereas navel orangeworm eggs were most tolerant at 30 degrees C. Field tests using GrainPro Cocoons (GrainPro, Inc., Concord, MA) to treat shelled almonds, Prunus dulcis (Mill.) D. A. Webb, in bins at vacuum levels of 18-43 mmHg at average winter temperatures (6-10 degrees C) showed that diapausing codling moth larvae were the most tolerant under these conditions and that exposures of 7-13 d provided incomplete control. Summer field tests treating in-shell almonds in bags at average temperatures of 25-30 degrees C provided complete control with 48 h exposure to average vacuum levels of 50 mmHg, and navel orangeworm eggs were the most tolerant stage.

Detection and segmentation of multiple touching product inspection items

NASA Astrophysics Data System (ADS)

Casasent, David P.; Talukder, Ashit; Cox, Westley; Chang, Hsuan-Ting; Weber, David

1996-12-01

X-ray images of pistachio nuts on conveyor trays for product inspection are considered. The first step in such a processor is to locate each individual item and place it in a separate file for input to a classifier to determine the quality of each nut. This paper considers new techniques to: detect each item (each nut can be in any orientation, we employ new rotation-invariant filters to locate each item independent of its orientation), produce separate image files for each item [a new blob coloring algorithm provides this for isolated (non-touching) input items], segmentation to provide separate image files for touching or overlapping input items (we use a morphological watershed transform to achieve this), and morphological processing to remove the shell and produce an image of only the nutmeat. Each of these operations and algorithms are detailed and quantitative data for each are presented for the x-ray image nut inspection problem noted. These techniques are of general use in many different product inspection problems in agriculture and other areas.

40 CFR 180.568 - Flumioxazin; tolerances for residues.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Grain, aspirated fractions 100 Grape 0.02 Hop, dried cones 0.05 Leaf petioles subgroup 4B 0.02 Nut, tree, group 14 0.02 Okra 0.02 Olive 0.02 Onion, bulb 0.02 Pea and bean, dried shelled, except soybean...

40 CFR 180.568 - Flumioxazin; tolerances for residues.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Grain, aspirated fractions 100 Grape 0.02 Hop, dried cones 0.05 Leaf petioles subgroup 4B 0.02 Nut, tree, group 14 0.02 Okra 0.02 Olive 0.02 Onion, bulb 0.02 Pea and bean, dried shelled, except soybean...

Levels of inorganic constituents in raw nuts and seeds on the Swedish market.

PubMed

Rodushkin, I; Engström, E; Sörlin, D; Baxter, D

2008-03-25

The levels of approximately 70 elements were determined in different culinary nuts (hazelnuts, walnuts, almonds, bitter almonds, pecans, cashews, Brazil nuts, pistachios, pine nuts, peanuts and coconuts) and seeds (pumpkin and sunflower) available on the Swedish market. The study was limited to raw, virtually unprocessed nuts and seeds (both shelled and unshelled) excluding mixed, roasted or salted products. In total, 44 products from different suppliers were analyzed, with the number of samples per nut/seed variety reflecting the availability of unprocessed products in retail outlets, varying from two for bitter almonds and pistachios to six for hazelnuts and walnuts. This selection includes samples from at least 11 different countries of origin. The optimized analytical procedure consists of microwave-assisted sample digestion using a HNO3/HF mixture, followed by multi-elemental analysis by double focusing, sector field inductively coupled plasma mass spectrometry. The analyses were accompanied by rigorous quality control measures including thorough control of potential sample contamination at all analytical stages, participation in inter-laboratory performance assessment schemes, and the analysis of certified reference materials of plant origin. Concentrations thus obtained were compared with data from product labels (where available), food composition tables and other relevant surveys, demonstrating, depending on the elements in question, close agreement as well as considerable differences.

7 CFR 981.473 - Redetermination reports.

Code of Federal Regulations, 2010 CFR

2010-01-01

... Agreements and Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE ALMONDS GROWN IN CALIFORNIA... Board in redetermination of the kernel weight of almonds received for his own account and for marketing... carryover. Report the weight of all almonds, whether unshelled or shelled, wherever located, held by the...

Use of nut shells as fillers in polymer composites

USDA-ARS?s Scientific Manuscript database

The three nutshell fillers including walnut, almond and pistachio nutshell were added to PLA. All the physical properties of samples deteriorated relative to PLA. When subjected to heat pre-treatment, although the physical properties of PLA-filler samples still deteriorated, the extent of deteriorat...

Bleaching augments lipid peroxidation products in pistachio oil and its cytotoxicity

USDA-ARS?s Scientific Manuscript database

Pistachio consumption is associated with reductions in serum cholesterol and oxidative stress due to their constituents of unsaturated fats, phytosterols, fiber, and antioxidants. Bleaching has been applied to whiten nut shells for antifungal and cosmetic purposes. However, the impact of bleaching o...

Natural Product Anacardic Acid from Cashew Nut Shells Stimulates Neutrophil Extracellular Trap Production and Bactericidal Activity.

PubMed

Hollands, Andrew; Corriden, Ross; Gysler, Gabriela; Dahesh, Samira; Olson, Joshua; Raza Ali, Syed; Kunkel, Maya T; Lin, Ann E; Forli, Stefano; Newton, Alexandra C; Kumar, Geetha B; Nair, Bipin G; Perry, J Jefferson P; Nizet, Victor

2016-07-01

Emerging antibiotic resistance among pathogenic bacteria is an issue of great clinical importance, and new approaches to therapy are urgently needed. Anacardic acid, the primary active component of cashew nut shell extract, is a natural product used in the treatment of a variety of medical conditions, including infectious abscesses. Here, we investigate the effects of this natural product on the function of human neutrophils. We find that anacardic acid stimulates the production of reactive oxygen species and neutrophil extracellular traps, two mechanisms utilized by neutrophils to kill invading bacteria. Molecular modeling and pharmacological inhibitor studies suggest anacardic acid stimulation of neutrophils occurs in a PI3K-dependent manner through activation of surface-expressed G protein-coupled sphingosine-1-phosphate receptors. Neutrophil extracellular traps produced in response to anacardic acid are bactericidal and complement select direct antimicrobial activities of the compound. © 2016 by The American Society for Biochemistry and Molecular Biology, Inc.

7 CFR 51.2559 - Size classifications.

Code of Federal Regulations, 2012 CFR

2012-01-01

... 7 Agriculture 2 2012-01-01 2012-01-01 false Size classifications. 51.2559 Section 51.2559... STANDARDS) United States Standards for Grades of Shelled Pistachio Nuts § 51.2559 Size classifications. (a... the following size classifications. (1) Jumbo Whole Kernels: 80 percent or more by weight shall be...

7 CFR 51.2559 - Size classifications.

Code of Federal Regulations, 2011 CFR

2011-01-01

... 7 Agriculture 2 2011-01-01 2011-01-01 false Size classifications. 51.2559 Section 51.2559... STANDARDS) United States Standards for Grades of Shelled Pistachio Nuts § 51.2559 Size classifications. (a... the following size classifications. (1) Jumbo Whole Kernels: 80 percent or more by weight shall be...

Molecular-scale characterization of uranium sorption by bone apatite materials for a permeable reactive barrier demonstration

USGS Publications Warehouse

Fuller, C.C.; Bargar, J.R.; Davis, J.A.

2003-01-01

Uranium binding to bone charcoal and bone meal apatite materials was investigated using U LIII-edge EXAFS spectroscopy and synchrotron source XRD measurements of laboratory batch preparations in the absence and presence of dissolved carbonate. Pelletized bone char apatite recovered from a permeable reactive barrier (PRB) at Fry Canyon, UT, was also studied. EXAFS analyses indicate that U(VI) sorption in the absence of dissolved carbonate occurred by surface complexation of U(VI) for sorbed concentrations ??? 5500 ??g U(VI)/g for all materials with the exception of crushed bone char pellets. Either a split or a disordered equatorial oxygen shell was observed, consistent with complexation of uranyl by the apatite surface. A second shell of atoms at a distance of 2.9 A?? was required to fit the spectra of samples prepared in the presence of dissolved carbonate (4.8 mM total) and is interpreted as formation of ternary carbonate complexes with sorbed U(VI). A U-P distance at 3.5-3.6 A?? was found for most samples under conditions where uranyl phosphate phases did not form, which is consistent with monodentate coordination of uranyl by phosphate groups in the apatite surface. At sorbed concentrations ??? 5500 ??g U(VI)/g in the absence of dissolved carbonate, formation of the uranyl phosphate solid phase, chernikovite, was observed. The presence of dissolved carbonate (4.8 mM total) suppressed the formation of chernikovite, which was not detected even with sorbed U(VI) up to 12 300 ??g U(VI)/g in batch samples of bone meal, bone charcoal, and reagent-grade hydroxyapatite. EXAFS spectra of bone char samples recovered from the Fry Canyon PRB were comparable to laboratory samples in the presence of dissolved carbonate where U(VI) sorption occurred by surface complexation. Our findings demonstrate that uranium uptake by bone apatite will probably occur by surface complexation instead of precipitation of uranyl phosphate phases under the groundwater conditions found at many U-contaminated sites.

Synthesis of a cardanol-amine derivative using an ionic liquid catalyst

USDA-ARS?s Scientific Manuscript database

Cardanol is a biobased raw material derived from cashew nut shell liquid. In order to extend its utility, new derivatives and additional applications are useful. In this work cardanol was first epoxidized, and a novel aniline derivative prepared from it under mild reaction conditions with the help o...

7 CFR 51.2561 - Average moisture content.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Average moisture content. 51.2561 Section 51.2561... STANDARDS) United States Standards for Grades of Shelled Pistachio Nuts § 51.2561 Average moisture content. (a) Determining average moisture content of the lot is not a requirement of the grades, except when...

Sapucaia nut (Lecythis pisonis Cambess) and its by-products: A promising and underutilized source of bioactive compounds. Part I: Nutritional composition and lipid profile.

PubMed

Demoliner, Fernanda; de Britto Policarpi, Priscila; Ramos, Juliano Carvalho; Bascuñan, Vera Lúcia Azzolin Frescura; Ferrari, Roseli Aparecida; Jachmanián, Iván; de Francisco de Casas, Alicia; Vasconcelos, Lúcio Flavo Lopes; Block, Jane Mara

2018-06-01

The nutritional composition of the sapucaia nut, cake and shell, the nut and cake minerals content and the lipid profile of the nut oil (fatty acids, tocopherols, phytosterols and triacylglycerols) were determined. The nuts and cake exhibited a high content of lipid (47.9 to 60.8 mg 100 g -1 ), protein (15.8 to 19.5 mg 100 g -1 ), dietary fiber (16.5 to 22.6 mg 100 g -1 ) and provided an excellent source of selenium (26.4 to 46.94 μg g -1 ). The oil contained a high amount of unsaturated fatty acids (39.7 to 45.4% of oleic and 32.2 to 46.6% of linoleic acids) and presented a high Oxidative Stability Index (8.57-12.95 h) indicating the presence of antioxidant compounds in the oil. The major triacylglycerols in the sapucaia oil were LLO, PLO, LOO, POO, OOO, PLL and LLL. The main bioactive lipids identified in the oil were γ-tocopherol (19.2 to 28.5 mg 100 g -1 ) and β-sitosterol (92.8 to 194 mg 100 g -1 ). The results showed that the sapucaia nut and its by-products are a promising natural source of bioactive and nutritional compounds and when present in the diet can contribute to the maintenance of human health. In addition, the nut and by-product represents a promising raw material for the food industry. Copyright © 2018 Elsevier Ltd. All rights reserved.

7 CFR 51.2541 - U.S. Fancy, U.S. Extra No. 1, U.S. No. 1 And U.S. Select Grades.

Code of Federal Regulations, 2010 CFR

2010-01-01

... PRODUCTS 1,2 (INSPECTION, CERTIFICATION, AND STANDARDS) United States Standards for Grades of Pistachio.... Fancy,” “U.S. Extra No. 1,” “U.S. No. 1,” and “U.S. Select” consists of pistachio nuts in the shell...

Synthesis and characterization of TiO2 loaded cashew nut shell activated carbon and photocatalytic activity on BG and MB dyes under sunlight radiation

NASA Astrophysics Data System (ADS)

Ragupathy, S.; Raghu, K.; Prabu, P.

2015-03-01

Synthesis of titanium dioxide (TiO2) nanoparticles and TiO2 loaded cashew nut shell activated carbon (TiO2/CNSAC) had been undertaken using sol-gel method and their application in BG and MB dyes removal under sunlight radiation has been investigated. The synthesized photocatalysts were characterized by X-ray diffraction analysis (XRD), Fourier infra-red spectroscopy (FT-IR), UV-Vis-diffuse reflectance spectroscopy (DRS) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The various experimental parameters like amount of catalyst, contact time for efficient dyes degradation of BG and MB were concerned in this study. Activity measurements performed under solar irradiation has shown good results for the photodegradation of BG and MB in aqueous solution. It was concluded that the higher photocatalytic activity in TiO2/CNSAC was due to parameters like band-gap, number of hydroxyl groups, surface area and porosity of the catalyst. The kinetic data were also described by the pseudo-first-order and pseudo-second-order kinetic models.

Establishing axenic cultures from mature pecan embryo explants on media with low water availability.

PubMed

Obeidy, A A; Smith, M A

1990-12-01

Endophytic fungi associated with mature pecan (Carya illinoensis (Wangenh.) C. Koch) nuts prevented successful, contaminant-free in vitro culture of embryo expiants, even after rigorous surface disinfestation of the nuts and careful aseptic shelling. Disinfestation with sodium hypochlorite after shell removal was also unsuccessful, because even dilute concentrations which were ineffective against the fungal contaminants prevented subsequent growth from the embryo. Explanting media with low water availability which would not sustain growth of fungal contaminants, but supported growth from mature pecan embryos, were developed as an alternative disinfestation method. The explanting media were supplemented with 0.9-1.5% agar, and other media components were selectively omitted to test their influence on water availability and fungal growth. Disinfestation of up to 65% of the cultures was accomplished, depending on the medium formulation, compared to 100% loss to contamination on control medium (0.5% agar). A complete medium (containing sucrose, salts, vitamins, 18 μM BAP, and 5 μM IBA) with 1.5% agar provided control of contamination, and encouraged subsequent regeneration from the embryo expiants, which remained free of contaminant growth through subsequent subcultures.

Ultrasonic-assisted extraction combined with sample preparation and analysis using LC-ESI-MS/MS allowed the identification of 24 new phenolic compounds in pecan nut shell [Carya illinoinensis (Wangenh) C. Koch] extracts.

PubMed

Hilbig, Josiane; Alves, Victor Rodrigues; Müller, Carmen Maria Olivera; Micke, Gustavo Amadeu; Vitali, Luciano; Pedrosa, Rozangela Curi; Block, Jane Mara

2018-04-01

Ultrasonic-assisted extraction combined with statistical tools (factorial design, response surface methodology and kinetics) were used to evaluate the effects of the experimental conditions of temperature, solid-to-solvent ratio, ethanol concentration and time for the extraction of the total phenolic content from pecan nut shells. The optimal conditions for the aqueous and hydroalcoholic extract (with 20% v/v of ethanol) were 60 and 80 °C; solid to solvent ratio of 30 mL·g -1 (for both) and extraction time of 35 and 25 min, respectively. Using these optimize extraction conditions, 426 and 582 mg GAE·g -1 of phenolic compounds, from the aqueous and hydroalcoholic phases respectively, were obtained. In addition, the analysis of the phenolic compounds using the LC-ESI-MS/MS system allowed the identification of 29 phenolic compounds, 24 of which had not been reported in literature for this raw material yet. Copyright © 2018. Published by Elsevier Ltd.

Speciation of arsenic in different types of nuts by ion chromatography-inductively coupled plasma mass spectrometry.

PubMed

Kannamkumarath, Sasi S; Wróbel, Kazimierz; Wróbel, Katarzyna; Caruso, Joseph A

2004-03-24

In this work the quantitative determination and analytical speciation of arsenic were undertaken in different types of nuts, randomly purchased from local markets. The hardness of the whole nuts and high lipid content made the preparation of this material difficult for analysis. The lack of sample homogeneity caused irreproducible results. To improve the precision of analysis, arsenic was determined separately in nut oil and in the defatted sample. The lipids were extracted from the ground sample with the two portions of a mixture of chloroform and methanol (2:1). The defatted material was dried and ground again, yielding a fine powder. The nut oil was obtained by combining the two organic extracts and by evaporating the solvents. The two nut fractions were microwave digested, and total arsenic was determined by inductively coupled plasma mass spectrometry (ICP-MS). The results obtained for oils from different types of nuts showed element concentration in the range 2.9-16.9 ng g(-)(1). Lower levels of arsenic were found in defatted material (<0.1 ng g(-)(1) with the exception of Brazil nuts purchased with and without shells, 3.0 and 2.8 ng g(-)(1) respectively). For speciation analysis of arsenic in nut oils, elemental species were extracted from 2 g of oil with 12 mL of chloroform/methanol (2:1) and 8 mL of deionized water. The aqueous layer, containing polar arsenic species, was evaporated and the residue dissolved and analyzed by ion chromatography-ICP-MS. The anion exchange chromatography enabled separation of As(III), dimethylarsinic acid (DMAs(V)), monomethylarsonic acid (MMAs(V)), and As(V) within 8 min. Several types of nuts were analyzed, including walnuts, Brazil nuts, almonds, cashews, pine nuts, peanuts, pistachio nuts, and sunflower seeds. The recovery for the speciation procedure was in the range 72.7-90.6%. The primary species found in the oil extracts were As(III) and As(V). The arsenic concentration levels in these two species were 0.7-12.7 and 0.5-4.3 ng g(-)(1), respectively. The contribution of As in DMAs(V) ranged from 0.1 +/- 0.1 ng g(-)(1) in walnuts to 1.3 +/- 0.3 ng g(-)(1) in pine nuts. MMAs(V) was not detected in almonds, peanuts, pine nuts, sunflower seeds, or walnuts, and the highest concentration was found in pistachio nuts (0.5 +/- 0.2 ng g(-)(1)).

The Design of Mechanically Compatible Fasteners for Human Mandible Reconstruction

NASA Technical Reports Server (NTRS)

Roberts, Jack C.; Ecker, John A.; Biermann, Paul J.

1993-01-01

Mechanically compatible fasteners for use with thin or weakened bone sections in the human mandible are being developed to help reduce large strain discontinuities across the bone/implant interface. Materials being considered for these fasteners are a polyetherertherketone (PEEK) resin with continuous quartz or carbon fiber for the screw. The screws were designed to have a shear strength equivalent to that of compact/trabecular bone and to be used with a conventional nut, nut plate, or an expandable shank/blind nut made of a ceramic filled polymer. Physical and finite element models of the mandible were developed in order to help select the best material fastener design. The models replicate the softer inner core of trabecular bone and the hard outer shell of compact bone. The inner core of the physical model consisted of an expanding foam and the hard outer shell consisted of ceramic particles in an epoxy matrix. This model has some of the cutting and drilling attributes of bone and may be appropriate as an educational tool for surgeons and medical students. The finite element model was exercised to establish boundary conditions consistent with the stress profiles associated with mandible bite forces and muscle loads. Work is continuing to compare stress/strain profiles of a reconstructed mandible with the results from the finite element model. When optimized, these design and fastening techniques may be applicable, not only to other skeletal structures, but to any composite structure.

A Comparative study of microwave-induced pyrolysis of lignocellulosic and algal biomass.

PubMed

Wang, Nan; Tahmasebi, Arash; Yu, Jianglong; Xu, Jing; Huang, Feng; Mamaeva, Alisa

2015-08-01

Microwave (MW) pyrolysis of algal and lignocellulosic biomass samples were studied using a modified domestic oven. The pyrolysis temperature was recorded continuously by inserting a thermocouple into the samples. Temperatures as high as 1170 and 1015°C were achieved for peanut shell and Chlorella vulgaris. The activation energy for MW pyrolysis was calculated by Coats-Redfern method and the values were 221.96 and 214.27kJ/mol for peanut shell and C. vulgaris, respectively. Bio-oil yields reached to 27.7wt.% and 11.0wt.% during pyrolysis of C. vulgaris and peanut shell, respectively. The bio-oil samples from pyrolysis were analyzed by a gas chromatography-mass spectrometry (GC-MS). Bio-oil from lignocellulosic biomass pyrolysis contained more phenolic compounds while that from microalgae pyrolysis contained more nitrogen-containing species. Fourier transform infrared spectroscopy (FTIR) analysis results showed that concentration of OH, CH, CO, OCH3, and CO functional groups in char samples decreased significantly after pyrolysis. Copyright © 2015 Elsevier Ltd. All rights reserved.

Effect of γ-Al2O3/water nanofluid on the thermal performance of shell and coil heat exchanger with different coil torsions

NASA Astrophysics Data System (ADS)

Elshazly, K. M.; Sakr, R. Y.; Ali, R. K.; Salem, M. R.

2017-06-01

This work investigated experimentally the thermal performance of shell and coil heat exchanger with different coil torsions (λ) for γ-Al2O3/water nanofluid flow. Five helically coiled tube (HCT) with 0.0442 ≤ λ ≤ 0.1348 were tested within turbulent flow regime. The average size of γ-Al2O3 particles is 40 nm and volume concentration (φ) is varied from 0 to 2%. Results showed that reducing coil torsion enhances the heat transfer rate and increases HCT-friction factor (fc). Also, it is noticed that HCT average Nusselt number (Nut) and fc of nanofluids increase with increasing γ-Al2O3 volume concentration. The thermal performance index, TPI = (ht,nf/ht,bf)/(ΔPc,nf/ΔPc,bf). increases with increasing nanoparticles concentration, coil torsion, HCT-side inlet temperature and nanofluid flow rate. Over the studied range of HCT-Reynolds number, the average value of TPI is of 1.34 and 2.24 at φ = 0.5% and φ = 2%, respectively. The average value of TPI is of 1.64 at λ = 0.0442 while its average value at λ = 0.1348 is of 2.01. One of the main contributions is to provide heat equipments designers with Nut and fc correlations for practical configurations shell and coil heat exchangers with a wide range of nanofluid concentration.

Effects of Post-Pyrolysis Air Oxidation of Biomass Chars on Adsorption of Neutral and Ionizable Compounds.

PubMed

Xiao, Feng; Pignatello, Joseph J

2016-06-21

This study was conducted to understand the effects of thermal air oxidation of biomass chars experienced during formation or production on their adsorptive properties toward various compounds, including five neutral nonpolar and polar compounds and seven weak acids and bases (pKa = 3-5.2) selected from among industrial chemicals and the triazine and phenoxyacetic acid herbicide classes. Post-pyrolysis air oxidation (PPAO) at 400 °C of anoxically prepared wood and pecan shell chars for up to 40 min enhanced the mass-normalized adsorption at pH ∼ 7.4 of all test compounds, especially the weak acids and bases, by up to 100-fold. Both general and specific effects were identified. The general effect results from "reaming" of pores by the oxidative removal of pore wall matter and/or tarry deposits generated during the pyrolysis step. Reaming creates new surface area and enlarges nanopores, which helps relieve steric hindrance to adsorption. The specific effect results from creation of new acidic functionality that provides sites for the formation of very strong, charge-assisted hydrogen bonds (CAHB) with solutes having comparable pKa. The CAHB hypothesis was supported by competition experiments and the finding that weak acid anion adsorption increased with surface carboxyl content, despite electrostatic repulsion from the growing negative charge. The results provide insight into the effects of air oxidation on pollutant retention.

Moisture Determination of Nuts and Dry Fruits using a Capacitance Sensor

USDA-ARS?s Scientific Manuscript database

Impedance (Z), and phase angle (') of a cylindrical parallel-plate capacitor with in-shell peanuts between the plates was measured earlier, using a CI meter (Chari’s Impedance meter), at 1 and 5 MHz . Capacitance C, was derived from Z and ', and using the C, ', and Z values of a set of peanuts whos...

7 CFR 457.167 - Pecan revenue crop insurance provisions.

Code of Federal Regulations, 2011 CFR

2011-01-01

...,000. Approved average revenue per acre—The total of your average gross sales per acre based on at...—Pecans as they are removed from the orchard with the nut-meats in the shell. Interplanted—Acreage on... insurance per acre is based and the number of affected acres; (2) The number of bearing trees on insurable...

7 CFR 457.167 - Pecan revenue crop insurance provisions.

Code of Federal Regulations, 2014 CFR

2014-01-01

... average revenue per acre. The total of your average gross sales per acre based on the most recent... overcrowding of pecan trees. In-shell pecans. Pecans as they are removed from the orchard with the nut-meats in... per acre is based and the number of affected acres; (2) The number of bearing trees on insurable and...

Anacardic Acid Constituents from Cashew Nut Shell Liquid: NMR Characterization and the Effect of Unsaturation on Its Biological Activities

PubMed Central

Morais, Selene M.; Silva, Katherine A.; Araujo, Halisson; Vieira, Icaro G.P.; Alves, Daniela R.; Fontenelle, Raquel O.S.; Silva, Artur M.S.

2017-01-01

Anacardic acids are the main constituents of natural cashew nut shell liquid (CNSL), obtained via the extraction of cashew shells with hexane at room temperature. This raw material presents high technological potential due to its various biological properties. The main components of CNSL are the anacardic acids, salicylic acid derivatives presenting a side chain of fifteen carbon atoms with different degrees of unsaturation (monoene–15:1, diene–15:2, and triene–15:3). Each constituent was isolated by column chromatography using silica gel impregnated with silver nitrate. The structures of the compounds were characterized by nuclear magnetic resonance through complete and unequivocal proton and carbon assignments. The effect of the side chain unsaturation was also evaluated in relation to antioxidant, antifungal and anticholinesterase activities, and toxicity against Artemia salina. The triene anacardic acid provided better results in antioxidant activity assessed by the inhibition of the free radical 1,1-diphenyl-2-picrylhydrazyl (DPPH), higher cytotoxicity against A. salina, and acetylcholinesterase (AChE) inhibition. Thus, increasing the unsaturation of the side chain of anacardic acid increases its action against free radicals, AChE enzyme, and A. salina nauplii. In relation to antifungal activity, an inverse result was obtained, and the linearity of the molecule plays an important role, with monoene being the most active. In conclusion, the changes in structure of anacardic acids, which cause differences in polarity, contribute to the increase or decrease in the biological activity assessed. PMID:28300791

NMR studies on the conformation of polyflavanoids and their association with proteins

Treesearch

Richard W. Hemingway; Petrus J. Steynberg; Jan P. Steynberg; Tsutomu Hatano

1999-01-01

Polyflavanoids (also named condensed tannins or proanthocyanidins) make up approximately half of the dry weight of most commercial tree barks, are often found in even higher concentrations in nut shells, and are important constituents of the leaves of plants. The polyflavanoids rank second in abundance after lignin as a source of renewable phenolic materials. Most of...

Synthesis and characterization of TiO2 loaded cashew nut shell activated carbon and photocatalytic activity on BG and MB dyes under sunlight radiation.

PubMed

Ragupathy, S; Raghu, K; Prabu, P

2015-03-05

Synthesis of titanium dioxide (TiO2) nanoparticles and TiO2 loaded cashew nut shell activated carbon (TiO2/CNSAC) had been undertaken using sol-gel method and their application in BG and MB dyes removal under sunlight radiation has been investigated. The synthesized photocatalysts were characterized by X-ray diffraction analysis (XRD), Fourier infra-red spectroscopy (FT-IR), UV-Vis-diffuse reflectance spectroscopy (DRS) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The various experimental parameters like amount of catalyst, contact time for efficient dyes degradation of BG and MB were concerned in this study. Activity measurements performed under solar irradiation has shown good results for the photodegradation of BG and MB in aqueous solution. It was concluded that the higher photocatalytic activity in TiO2/CNSAC was due to parameters like band-gap, number of hydroxyl groups, surface area and porosity of the catalyst. The kinetic data were also described by the pseudo-first-order and pseudo-second-order kinetic models. Copyright © 2014 Elsevier B.V. All rights reserved.

Effect of biochar on bio-electrochemical dye degradation and energy production.

PubMed

Sophia Ayyappan, Carmalin; Bhalambaal, V M; Kumar, Sunil

2018-03-01

The effect of coconut shell biochar on dye degradation in a microbial fuel cell (MFC) was investigated in the present study. Two different doses of biochar (0.5 g and 1 g) and one control without bio-char were studied. The highest COD removal efficiency was about 77.7% (0.5 g biochar), maximum current (1.07 mA) and voltage (722 mV) were obtained with 1 g biochar. Biofilm optical microscopy characterization revealed the micro colonies intricate plate-like structures. High adsorbent dosage might provide a high surface area for biofilm to generate electricity. BET results of coconut shell biochar showed the maximum surface area of 0.9669 m 2 /g and macroporosity (0.0032 cm 3 /g). The overall results highlighted the possibility of using biochar as an additive in MFC for efficient dye degradation. Copyright © 2017 Elsevier Ltd. All rights reserved.

The carbon dioxide gasification characteristics of biomass char samples and their effect on coal gasification reactivity during co-gasification.

PubMed

Mafu, Lihle D; Neomagus, Hein W J P; Everson, Raymond C; Okolo, Gregory N; Strydom, Christien A; Bunt, John R

2018-06-01

The carbon dioxide gasification characteristics of three biomass char samples and bituminous coal char were investigated in a thermogravimetric analyser in the temperature range of 850-950 °C. Char SB exhibited higher reactivities (R i , R s , R f ) than chars SW and HW. Coal char gasification reactivities were observed to be lower than those of the three biomass chars. Correlations between the char reactivities and char characteristics were highlighted. The addition of 10% biomass had no significant impact on the coal char gasification reactivity. However, 20 and 30% biomass additions resulted in increased coal char gasification rate. During co-gasification, chars HW and SW caused increased coal char gasification reactivity at lower conversions, while char SB resulted in increased gasification rates throughout the entire conversion range. Experimental data from biomass char gasification and biomass-coal char co-gasification were well described by the MRPM, while coal char gasification was better described by the RPM. Copyright © 2018 Elsevier Ltd. All rights reserved.

Analysis of total oil and fatty acids composition by near infrared reflectance spectroscopy in edible nuts

NASA Astrophysics Data System (ADS)

Kandala, Chari V.; Sundaram, Jaya

2014-10-01

Near Infrared (NIR) Reflectance spectroscopy has established itself as an important tool in quantifying water and oil present in various food materials. It is rapid and nondestructive, easier to use, and does not require processing the samples with corrosive chemicals that would render them non-edible. Earlier, the samples had to be ground into powder form before making any measurements. With the development of new soft ware packages, NIR techniques could now be used in the analysis of intact grain and nuts. While most of the commercial instruments presently available work well with small grain size materials such as wheat and corn, the method present here is suitable for large kernel size products such as shelled or in-shell peanuts. Absorbance spectra were collected from 400 nm to 2500 nm using a NIR instrument. Average values of total oil contents (TOC) of peanut samples were determined by standard extraction methods, and fatty acids were determined using gas chromatography. Partial least square (PLS) analysis was performed on the calibration set of absorption spectra, and models were developed for prediction of total oil and fatty acids. The best model was selected based on the coefficient of determination (R2), Standard error of prediction (SEP) and residual percent deviation (RPD) values. Peanut samples analyzed showed RPD values greater than 5.0 for both absorbance and reflectance models and thus could be used for quality control and analysis. Ability to rapidly and nondestructively measure the TOC, and analyze the fatty acid composition, will be immensely useful in peanut varietal improvement as well as in the grading process of grain and nuts.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sai, P.M.S.; Ahmed, J.; Krishnaiah, K.

Activated carbon is produced from coconut shell char using steam or carbon dioxide as the reacting gas in a 100 mm diameter fluidized bed reactor. The effect of process parameters such as reaction time, fluidizing velocity, particle size, static bed height, temperature of activation, fluidizing medium, and solid raw material on activation is studied. The product is characterized by determination of iodine number and BET surface area. The product obtained in the fluidized bed reactor is much superior in quality to the activated carbons produced by conventional processes. Based on the experimental observations, the optimum values of process parameters aremore » identified.« less

Interaction and its induced inhibiting or synergistic effects during co-gasification of coal char and biomass char.

PubMed

Ding, Liang; Zhang, Yongqi; Wang, Zhiqing; Huang, Jiejie; Fang, Yitian

2014-12-01

Co-gasification of coal char and biomass char was conducted to investigate the interactions between them. And random pore model (RPM) and modified random pore model (MRPM) were applied to describe the gasification behaviors of the samples. The results show that inhibiting effect was observed during co-gasification of corn stalk char with Hulunbeier lignite coal char, while synergistic effects were observed during co-gasification of corn stalk char with Shenmu bituminous coal char and Jincheng anthracite coal char. The inhibiting effect was attributed to the intimate contact and comparable gasification rate between biomass char and coal char, and the loss of the active form of potassium caused by the formation of KAlSiO4, which was proved to be inactive during gasification. While the synergistic effect was caused by the high potassium content of biomass char and the significant difference of reaction rate between coal char and biomass char during gasification. Copyright © 2014 Elsevier Ltd. All rights reserved.

Prehistory of the Little Blue River Valley, Western Missouri: Archaeological Investigations at Blue Springs Lake.

DTIC Science & Technology

1989-01-01

amaranths, chenopods and purslane , along with mast resources, such as acorns and hickory nuts. The restricted periods of availability of these plant...Polygonum pensylvanicum (Pensylvania smartweed) fall Portulaca mundula ( purslane ) fall Portulaca oleracea (common purslane ) fall Rorippa palustris...and Bright 1968) and the oxygen-isotope ratios of mollusk shells (Stuiver 1970), which all indicate increased salinity at the time of maximum prairie

Corrigendum to “Feasibility of dibromochloropropane (DBCP) and trichloroethylene (TCE) adsorption onto activated carbons made from nut shells of different almond varieties” [Ind. Crops Prod. 31 (2) (2010) 261-265

USDA-ARS?s Scientific Manuscript database

The authors would like to make the following correction in the above mentioned published article. In the Experimental Methods section, the original manuscript described an activation strategy for the pyrolyzed materials that was not accurate. The correct condition for activation was 800C for 45 m...

A PC Program to Calculate the One-Sided Lower Tolerance Limit for Total Ionizing Dose Radiation Data

DTIC Science & Technology

1991-08-01

include <graphics .h> #define VEDIO OxlO #define ESC 27 1* Decelerations * FILE *pfile; FILE *outf; FILE *inf; mnt n; mnt un; float max scale...regs.h.ah=2; regs .h.dh=y; regs .h.dl=x; regs .h.bh=O; int86( VEDIO , ®s, ®s); char attribute(char blink, char back-color,char intensity, char...set lint mode) union REGS regs; regs.h.ah=O; regs h a l-mode; int86( VEDIO , ®s, ®s); void str-color (char x, char y, char *str, char blink, char

Development of Refined Natural Resin based Cashew Nut Shell Oil Liquid (CNSL) for Brake Pads Composite

NASA Astrophysics Data System (ADS)

Wahyuningsih, S.; Ramelan, A. H.; Rahmawati, P.; Tamtama, B. P. N.; Sari, P. P.; Sari, P. L.; Ichsan, S.; Kristiawan, Y. R.; Aini, F. N.

2017-02-01

Brake is one of the most important components in the vehicle. One type of brake that widely used is brake-based composites. One of the manufacture of composite material is resin. Cashew Nut Shell Liquid (CNSL) is a natural material which has chemical structure similar to synthetic phenol so it can be an alternative as a resin. Brake pads manufacture using CNSL as resin composites made to obtain the brake which is strong, wear-resistant, and environmentally friendly. The composite made using powder metallurgy techniques by mixing ingredients such as rubber, fibre glass, carbon, mineral sands and phenolic resin. Two formulas were composed by varying the resin and iron mineral sands in 5 grams. Composites were tested using Universal Testing Machine (UTM). The tensile strength result of those formulas are 600 N and 900 N and the elongations are 1.98 mm and 2.59 mm respectively. Formula 2 has a better tensile strength due to the addition of more resin is 15%. Since the better properties, formula 2 was derivated to 4 extended formulas and showed excellent pressure strength reached 20.000 N. It indicates that the addition of the resin can improve the mechanical properties of a composite.

Reduction of silver (I) using defatted cashew nut shell starch and its structural comparison with commercial product.

PubMed

Velmurugan, Palanivel; Park, Jung-Hee; Lee, Sang-Myeong; Jang, Jum-Suk; Yi, Young-Joo; Han, Sang-Sub; Lee, Sang-Hyun; Cho, Kwang-Min; Cho, Min; Oh, Byung-Taek

2015-11-20

In this current study, we report on the reduction of noble metal silver into silver nanoparticles using defatted cashew nut shell (CNS) starch as both the reducing and capping agents. Furthermore, it was compared with commercially available silver nanopowder for the first time. Color changes, ultraviolet-visible spectra (433.76nm), X-ray diffraction peaks (2θ=37.8, 46.3, 66.2, and 77.92) revealed the face-centered cubic (fcc) geometry of silver nanoparticles, scanning electron microscopy-energy dispersive spectroscopy confirmed the presence of elemental silver nanoparticles and the defatted CNS starch silver nanoparticle structures was in accordance to commercial silver nanopowder. The size of both the nanoparticles was found to be similar in the range of 10-50nm as analyzed using high resolution-transmission electron micrographs. The FT-IR spectroscopy revealed the shifting of NH and OH of defatted CNS starch, starch based silver nanoparticle and commercial silver nanopowder has parallel functional groups. The use of environmentally benign and renewable materials like defatted CNS starch offers an alternative to large scale synthesis of silver nanoparticle and includes numerous benefits like eco-friendly and compatibility for pharmaceutical and biomedical applications. Copyright © 2015 Elsevier Ltd. All rights reserved.

Mitochondria-Associated Apoptosis in Human Melanoma Cells Induced by Cardanol Monoene from Cashew Nut Shell Liquid.

PubMed

Su, Wei-Chao; Lin, Yu-Feng; Yu, Xiang-Ping; Wang, Yu-Xia; Lin, Xiao-Dong; Su, Qiao-Zhen; Shen, Dong-Yan; Chen, Qing-Xi

2017-07-19

Cardanol monoene (CM) is the major phenolic component extracted from cashew nut shell liquid (CNSL), which has been relevant to wide range of biological effects. In this study, we found that CM could inhibit the M14 human melanoma cells proliferation in a dose dependent and time dependent manner, and the IC 50 values were determined to be 23.15 ± 2.42 μM and 12.30 ± 1.67 μM after 24 and 48 h treatment, respectively. The flow cytometric analysis demonstrated that CM induced M14 cell cycle arrest at the S phase, along with the collapse of mitochondrial membrane potential (ΔΨm) and the accumulation of reactive oxygen species (ROS) level in cells, but the apoptotic cells reduced when treated with Z-VAD-FMK (pan-caspase inhibitor). Western blotting showed that the expressions of p53, cytosol cytochrome C, cleaved-caspase-3, and cleaved-PARP were up-regulated, and the expression level of Bax/Bcl-2 ratio increased significantly. The 2527 significant differentially expressed genes were obtained by RNA-seq, which were assigned to 270 KEGG pathways. These results indicated that CM induced M14 cells apoptosis via the ROS triggered mitochondrial-associated pathways, which supports the potential application of CM for the therapy of melanoma cancer.

Production of activated carbon from TCR char

NASA Astrophysics Data System (ADS)

Stenzel, Fabian; Heberlein, Markus; Klinner, Tobias; Hornung, Andreas

2016-04-01

The utilization of char for adsorptive purposes is known since the 18th century. At that time the char was made of wood or bones and used for decoloration of fluids. In the 20th century the production of activated carbon in an industrial scale was started. The today's raw materials for activated carbon production are hard coal, peat, wood or coconut shells. All these materials entail costs especially the latter. Thus, the utilization of carbon rich residues (biomass) is an interesting economic opportunity because it is available for no costs or even can create income. The char is produced by thermo-catalytic reforming (TCR®). This process is a combination of an intermediate pyrolysis and subsequently a reforming step. During the pyrolysis step the material is decomposed in a vapor and a solid carbon enriched phase. In the second step the vapor and the solid phase get in an intensive contact and the quality of both materials is improved via the reforming process. Subsequently, the condensables are precipitated from the vapor phase and a permanent gas as well as oil is obtained. Both are suitable for heat and power production which is a clear advantage of the TCR® process. The obtained biochar from the TCR® process has special properties. This material has a very low hydrogen and oxygen content. Its stability is comparable to hard coal or anthracite. Therefore it consists almost only of carbon and ash. The latter depends from input material. Furthermore the surface structure and area can be influenced during the reforming step. Depending from temperature and residence time the number of micro pores and the surface area can be increased. Preliminary investigations with methylene blue solution have shown that a TCR® char made of digestate from anaerobic digestion has adsorptive properties. The decoloration of the solution was achieved. A further influencing factor of the adsorption performance is the particle size. Based on the results of the preliminary tests a systematically investigation was started. For this a muffle furnace with a maximum temperature up to 1300 ° C is used. Furthermore the gaseous atmosphere can be controlled. So it is possible to carry out the trials with the absence of oxygen by purging with nitrogen, carbon oxide and/ or steam for example. With the addition of steam the number of mesopores is increased. These pores are responsible for the adsorption performance in liquid phases. The trials for the TCR® chars made from beech wood (reference) and digestate are currently carried out. Additionally the reduction of the ash content of the char by using hydrochloric and acetic acid is investigated, too. These leaching tests are carried out in a lab scale test rig at an operating temperature of 60 ° C and a residence time up to 4 hours. The main objective is to adapt the TCR® process with regard to an optimized activated carbon production from biogenic residues to obtain an economic sustainable concept.

Century scale char and non-char C co-stabilization in soil free C fractions

NASA Astrophysics Data System (ADS)

Vasilyeva, N. A.; Chenu, C.

2012-04-01

Fate of char particles and reasons of char C stabilization in soils is not well understood especially due to difficulties of its quantification. In this study we showed how char C content could be estimated from elemental analysis along with its size redistribution and co-stabilization with non-char C in long-term. We studied C dynamics in the size and density fractons of soil samples from a historical collection of 80 years bare fallow (no plant input plus tillage) experiment in Versailles, France (1929, 1939, 1949, 1962, 1972, 1991, 2008 years). Coarse char particles were observed in the soil substantially contributing to total organic C. Thus, char C study in this soil was carried out as a nessessary step for estimation of non-char C dynamics. Physical fraction allowed us to follow separately the dynamics of mineral-associated and free C. We analyzed bulk soils, fractions and picked out char particles for C, N and 13C contents. Total organic carbon concentrations in fractions pointed to char C input during 1939-1949 years. After that patterns of C and C/N and δ 13C changes in all fractions suggested redistribution of char C from coarse to finer fractions. Evolution of C/N and δ 13C suggested that all free C fractions, although enriched in char, still contained non-char C in the end of the 80 years C depletion chronosequence. Especially high proportion of non-char C was observed in the silt-size free C fraction. Linear combinations of contrasting char and non-char C C/N values allowed estimation of their proportions from the C/N evolution in the fractions. No substantial admixture of char C was observed for mineral-associated C fractions. Stable C pool in 2008 comprised of 4.6 g C kg-1 soil and was composed of mineral-associated C (3.5 g C kg-1 soil) and char-associated C (1.1 g C kg-1 soil). In both cases organic matter could be stabilized through adsorption and/or occlusion with solid particles (mineral or char). Stabilization capacities of different size class minerals reflected in C concentrations of fractions were 1.2 g C kg-1 for silt-size minerals and 19.4 g C kg-1 for clay-size minerals, contrastingly three orders of magnitude more C was associated with char particles or about 1.2 kg non-char C kg-1 sand-size char and about 1.4 to 3.5 kg non-char C kg-1 silt-size char. Such a high capacity of stabilization by char particles could not be explained by adorbtion alone. In conclusion, combination of C/N and δ13C signature allowed estimation of char content in this soil. Total char C content (sum up of redistributed char C in free fractions) remained not significantly different in the C depletion experiment during five decades after char input. Century scale char and non-char C co-stabilization in this soil could be explained by combination of adsorption and physical protection in microaggregates constructed of mineral and char particles.

Multiple lead seal assembly for a liquid-metal-cooled fast-breeder nuclear reactor

DOEpatents

Hutter, Ernest; Pardini, John A.

1977-03-15

A reusable multiple lead seal assembly provides leak-free passage of stainless-steel-clad instrument leads through the cover on the primary tank of a liquid-metal-cooled fast-breeder nuclear reactor. The seal isolates radioactive argon cover gas and sodium vapor within the primary tank from the exterior atmosphere and permits reuse of the assembly and the stainless-steel-clad instrument leads. Leads are placed in flutes in a seal body, and a seal shell is then placed around the seal body. Circumferential channels in the body and inner surface of the shell are contiguous and together form a conduit which intersects each of the flutes, placing them in communication with a port through the wall of the seal shell. Liquid silicone rubber sealant is injected into the flutes through the port and conduit; the sealant fills the space in the flutes not occupied by the leads themselves and dries to a rubbery hardness. A nut, threaded onto a portion of the seal body not covered by the seal shell, jacks the body out of the shell and shears the sealant without damage to the body, shell, or leads. The leads may then be removed from the body. The sheared sealant is cleaned from the body, leads, and shell and the assembly may then be reused with the same or different leads.

Aflatoxin and sterigmatocystin contamination of pistachio nuts in orchards.

PubMed Central

Sommer, N F; Buchanan, J R; Fortlage, R J

1976-01-01

Aspergillus flavus and A. versicolor were both shown to be weak pathogens of developing pistachio fruits, producing aflatoxin and sterigmatocystin, respectively. Aflatoxin concentrations approached those reported in cereal and legume seeds. Fungus lesions on the first hulls were followed by invasion of seeds despite the sclerified shell. Infections and mycotoxins present before harvest would presumably lead to further build-up after harvest if drying was slow or storage was under high humidity. PMID:823868

Evaluation of current techniques for isolation of chars as natural adsorbents

USGS Publications Warehouse

Chun, Y.; Sheng, G.; Chiou, C.T.

2004-01-01

Chars in soils or sediments may potentially influence the soil/sediment sorption behavior. Current techniques for the isolation of black carbon including chars rely often on acid demineralization, base extraction, and chemical oxidation to remove salts and minerals, humic acid, and refractory kerogen, respectively. Little is known about the potential effects of these chemical processes on the char surface and adsorptive properties. This study examined the effects of acid demineralization, base extraction, and acidic Cr2O72- oxidation on the surface areas, surface acidity, and benzene adsorption characteristics of laboratory-produced pinewood and wheat-residue chars, pure or mixed with soils, and a commercial activated carbon. Demineralization resulted in a small reduction in the char surface area, whereas base extraction showed no obvious effect. Neither demineralization nor base extraction caused an appreciable variation in benzene adsorption and presumably the char surface properties. By contrast, the Cr2O 72- oxidation caused a >31% reduction in char surface area. The Boehm titration, supplemented by FTIR spectra, indicated that the surface acidity of oxidized chars increased by a factor between 2.3 and 12 compared to nonoxidized chars. Benzene adsorption with the oxidized chars was lower than that with the non-oxidized chars by a factor of >8.9; both the decrease in char surface area and the increase in char surface acidity contributed to the reduction in char adsorptive power. Although the Cr 2O72- oxidation effectively removes resistant kerogen, it is not well suited for the isolation of chars as contaminant adsorbents because of its destructive nature. Alternative nondestructive techniques that preserve the char surface properties and effectively remove kerogen must be sought.

Thermochemical and trace element behavior of coal gangue, agricultural biomass and their blends during co-combustion.

PubMed

Zhou, Chuncai; Liu, Guijian; Cheng, Siwei; Fang, Ting; Lam, Paul Kwan Sing

2014-08-01

The thermal decomposition behavior of coal gangue, peanut shell, wheat straw and their blends during combustion were determined via thermogravimetric analysis. The coal gangue/agricultural biomass blends were prepared in four weight ratios and oxidized under dynamic conditions from room temperature to 1000 °C by various heating rates. Kinetic models were carried out to evaluate the thermal reactivity. The overall mass balance was performed to assess the partition behavior of coal gangue, peanut shell and their blends during combustion in a fixed bed reactor. The decomposition processes of agricultural biomass included evaporation, release of volatile matter and combustion as well as char oxidation. The thermal reactivity of coal gangue could be improved through the addition of agricultural biomass in suitable proportion and subsequent appropriate heating rate during combustion. In combination with the heating value and base/acid ratio limitations, a blending ratio of 30% agricultural biomass is conservatively selected as optimum blending. Copyright © 2014 Elsevier Ltd. All rights reserved.

Study on CO2 gasification reactivity and physical characteristics of biomass, petroleum coke and coal chars.

PubMed

Huo, Wei; Zhou, Zhijie; Chen, Xueli; Dai, Zhenghua; Yu, Guangsuo

2014-05-01

Gasification reactivities of six different carbonaceous material chars with CO2 were determined by a Thermogravimetric Analyzer (TGA). Gasification reactivities of biomass chars are higher than those of coke and coal chars. In addition, physical structures and chemical components of these chars were systematically tested. It is found that the crystalline structure is an important factor to evaluate gasification reactivities of different chars and the crystalline structures of biomass chars are less order than those of coke and coal chars. Moreover, initial gasification rates of these chars were measured at high temperatures and with relatively large particle sizes. The method of calculating the effectiveness factor η was used to quantify the effect of pore diffusion on gasification. The results show that differences in pore diffusion effects among gasification with various chars are prominent and can be attributed to different intrinsic gasification reactivities and physical characteristics of different chars. Copyright © 2014 Elsevier Ltd. All rights reserved.

Isolation of anacardic acid from natural cashew nut shell liquid (CNSL) using supercritical carbon dioxide.

PubMed

Philip, Joseph Y N; Da Cruz Francisco, José; Dey, Estera S; Buchweishaija, Joseph; Mkayula, Lupituko L; Ye, Lei

2008-10-22

Solvent extracted cashew nut shell liquid (CNSL), conventionally known as natural CNSL, is a mixture of several alkenyl phenols. One of these alkenyl phenols is anacardic acid, which is present at the highest concentration. In view of anticipated industrial applications of anacardic acid, the objective of this work was to isolate anacardic acid from natural CNSL by supercritical carbon dioxide (scCO 2). In this study, the solubility data for natural CNSL in scCO 2 under a range of operating conditions of pressure (100, 200, and 300 bar), temperature (40 and 50 degrees C), and CO 2 flow rate (5, 10, and 15 g min (-1)) were established. The best scCO 2 working conditions were found to be 50 degrees C and 300 bar at a flow rate of 5 g min (-1) CO 2. Using 3 g of sample (CNSL/solid adsorbent = 1/2) under these scCO 2 conditions, it was possible to quantitatively isolate high purity anacardic acid from crude natural CNSL (82% of total anacardic acid) within 150 min. The anacardic acid isolated by scCO 2 was analyzed by different spectroscopic techniques (UV-vis, FT-IR, and (1)H NMR) and HPLC analysis, indicating that the anacardic acid isolated by scCO 2 has better quality than that obtained through a conventional method involving several chemical conversion steps.

Soap production: A green prospective.

PubMed

Félix, Sandra; Araújo, Joana; Pires, Ana Maria; Sousa, Ana Cláudia

2017-08-01

A green prospective based on the reuse of waste materials such as almond shells, orange peel and used cooking oil to manufacture soap is presented. In Portugal, thousands of tons of waste are generated from used cooking oil and production of nut shells' residues is growing every year. In addition, the high consumption of citrus fruits, oranges in particular, generates large amounts of citrus peel. Therefore, it is necessary to diversify reuse mechanisms of these wastes, in order to make them back into raw materials. Complying with this trend, this work was carried out by processing and grinding almond shells, treating used oil, processing orange peels and extracting limonene, formulating and producing soap, and performing an acceptance study of the final product. Results validated a high potential of the idea in the field of environmental education, so it can be replicated in practical classes. It can also be useful for waste management, and it can support the development of community projects on an ecological approach. Copyright © 2017 Elsevier Ltd. All rights reserved.

Preparation of porous bio-char and activated carbon from rice husk by leaching ash and chemical activation.

PubMed

Ahiduzzaman, Md; Sadrul Islam, A K M

2016-01-01

Preparation porous bio-char and activated carbon from rice husk char study has been conducted in this study. Rice husk char contains high amount silica that retards the porousness of bio-char. Porousness of rice husk char could be enhanced by removing the silica from char and applying heat at high temperature. Furthermore, the char is activated by using chemical activation under high temperature. In this study no inert media is used. The study is conducted at low oxygen environment by applying biomass for consuming oxygen inside reactor and double crucible method (one crucible inside another) is applied to prevent intrusion of oxygen into the char. The study results shows that porous carbon is prepared successfully without using any inert media. The adsorption capacity of material increased due to removal of silica and due to the activation with zinc chloride compared to using raw rice husk char. The surface area of porous carbon and activated carbon are found to be 28, 331 and 645 m(2) g(-1) for raw rice husk char, silica removed rice husk char and zinc chloride activated rice husk char, respectively. It is concluded from this study that porous bio-char and activated carbon could be prepared in normal environmental conditions instead of inert media. This study shows a method and possibility of activated carbon from agro-waste, and it could be scaled up for commercial production.

The effect of char structure on burnout during pulverized coal combustion at pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, G.; Wu, H.; Benfell, K.E.

An Australian bituminous coal sample was burnt in a drop tube furnace (DTF) at 1 atm and a pressurized drop tube furnace (PDTF) at 15 atm. The char samples were collected at different burnout levels, and a scanning electron microscope was used to examine the structures of chars. A model was developed to predict the burnout of char particles with different structures. The model accounts for combustion of the thin-walled structure of cenospheric char and its fragmentation during burnout. The effect of pressure on reaction rate was also considered in the model. As a result, approximately 40% and 70% cenosphericmore » char particles were observed in the char samples collected after coal pyrolysis in the DTF and PDTF respectively. A large number of fine particles (< 30 mm) were observed in the 1 atm char samples at burnout levels between 30% and 50%, which suggests that significant fragmentation occurred during early combustion. Ash particle size distributions show that a large number of small ash particles formed during burnout at high pressure. The time needed for 70% char burnout at 15 atm is approximately 1.6 times that at 1 atm under the same temperature and gas environment conditions, which is attributed to the different pressures as well as char structures. The overall reaction rate for cenospheric char was predicted to be approximately 2 times that of the dense chars, which is consistent with previous experimental results. The predicted char burnout including char structures agrees reasonably well with the experimental measurements that were obtained at 1 atm and 15 atm pressures.« less

The Effect of Polymer Char on Nitridation Kinetics of Silicon

NASA Technical Reports Server (NTRS)

Chan, Rickmond C.; Bhatt, Ramakrishna T.

1994-01-01

Effects of polymer char on nitridation kinetics of attrition milled silicon powder have been investigated from 1200 to 1350 C. Results indicate that at and above 1250 C, the silicon compacts containing 3.5 wt percent polymer char were fully converted to Si3N4 after 24 hr exposure in nitrogen. In contrast, the silicon compacts without polymer char could not be fully converted to Si3N4 at 1350 C under similar exposure conditions. At 1250 and 1350 C, the silicon compacts with polymer char showed faster nitridation kinetics than those without the polymer char. As the polymer char content is increased, the amount of SiC in the nitrided material is also increased. By adding small amounts (approx. 2.5 wt percent) of NiO, the silicon compacts containing polymer char can be completely nitrided at 1200 C. The probable mechanism for the accelerated nitridation of silicon containing polymer char is discussed.

Role of oxygen-containing functional groups in forest fire-generated and pyrolytic chars for immobilization of copper and nickel.

PubMed

Esfandbod, Maryam; Merritt, Christopher R; Rashti, Mehran Rezaei; Singh, Balwant; Boyd, Sue E; Srivastava, Prashant; Brown, Christopher L; Butler, Orpheus M; Kookana, Rai S; Chen, Chengrong

2017-01-01

Char as a carbon-rich material, can be produced under pyrolytic conditions, wildfires or prescribed burn offs for fire management. The objective of this study was to elucidate mechanistic interactions of copper (Cu 2+ ) and nickel (Ni 2+ ) with different chars produced by pyrolysis (green waste, GW; blue-Mallee, BM) and forest fires (fresh-burnt by prescribed fire, FC; aged char produced by wild fire, AC). The pyrolytic chars were more effective sorbents of Cu 2+ (∼11 times) and Ni 2+ (∼5 times) compared with the forest fire chars. Both cross-polarization (CPMAS-NMR) and Bloch decay (BDMAS-NMR) 13 C NMR spectroscopies showed that forest fire chars have higher woody components (aromatic functional groups) and lower polar groups (e.g. O-alkyl C) compared with the pyrolytic chars. The polarity index was greater in the pyrolytic chars (0.99-1.34) than in the fire-generated chars (0.98-1.15), while aromaticity was lower in the former than in the latter. Fourier transform infrared (FTIR) and Raman spectroscopies indicated the binding of carbonate and phosphate with both Cu 2+ and Ni 2+ in all chars, but with a greater extent in pyrolytic than forest fire-generated chars. These findings have demonstrated the key role of char's oxygen-containing functional groups in determining their sorption capacity for the Cu 2+ and Ni 2+ in contaminated lands. Copyright © 2016 Elsevier Ltd. All rights reserved.

Development of Acid Functional Groups and Lactones During the Thermal Degradation of Wood and Wood Components

USGS Publications Warehouse

Rutherford, David W.; Wershaw, Robert L.; Reeves, James B.

2008-01-01

Black carbon (pyrogenic materials including chars) in soils has been recognized as a substantial portion of soil organic matter, and has been shown to play a vital role in nutrient cycling; however, little is known concerning the properties of this material. Previous studies have largely been concerned with the creation of high-surface-area materials for use as sorbents. These materials have been manufactured at high temperature and have often been activated. Chars occurring in the environment can be formed over a wide range of temperature. Because it is extremely difficult to isolate black carbon once it has been incorporated in soils, chars produced in the laboratory under controlled conditions can be used to investigate the range of properties possible for natural chars. This report shows that charring conditions (temperature and time) have substantial impact on the acid functional group and lactone content of chars. Low temperatures (250?C) and long charring times (greater than 72 hours) produce chars with the highest acid functional group and lactone content. The charring of cellulose appears to be responsible for the creation of the acid functional group and lactones. The significance of this study is that low-temperature chars can have acid functional group contents comparable to humic materials (as high as 8.8 milliequivalents per gram). Acid functional group and lactone content decreases as charring temperature increases. The variation in formation conditions expected under natural fire conditions will result in a wide range of sorption properties for natural chars which are an important component of soil organic matter. By controlling the temperature and duration of charring, it is possible to tailor the sorption properties of chars, which may be used as soil amendments.

Constitution of Drop-Tube-Generated Coal Chars from Vitrinite- and Inertinite-Rich South African Coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Louw, Enette B.; Mitchell, Gareth D.; Wang, Juan

The structural transformations of coal and the resultant char morphologies are strongly dependent on the initial structure and degree of thermoplasticity achieved during coal-to-char transition. These are a function of petrographic composition, rank, particle size, and heating rate and strongly affect combustion behavior. This study compares the devolatilization and subsequent combustion behavior of an inertinite-rich (87.7% dmmf) and a vitrinite-rich (91.8% dmmf) South African coal, wet-screened to a narrow particle size distribution of 200 x 400 mesh. Pyrolysis chars were generated under rapid-heating conditions (104-105 °C/s) in a drop-tube reactor to closely resemble chars generated in pulverized combustion conditions. Themore » inertinite-rich coal took ~ 400 ms to devolatilize in the drop-tube, compared to only ~ 240 ms for the vitrinite-rich sample. The chemical and physical structure (the constitution) of the chars were investigated through a range of chemical, physical, and optical characteristics including the maceral differences, and high ash yields. To evaluate the combustion reactivity non-isothermal burn-out profiles were obtained through thermogravimetrical analyses (TGA) in air. The vitrinite-rich char had on average 20% higher reaction rates than the inertinite-rich char under the various combustion conditions. The char samples were de-ashed with HCl and HF acid which resulted in an increase in combustion reactivity. The maximum reaction rate of the high-ash (36% ash yield) inertinite-rich char increased with 80% after de-ashing. While the vitrinite-rich char with an ash yield of 15%, had a 20% increase in reactivity after de-ashing. The ash acted as a barrier, and the removal of ash most likely increased the access to reactive surface area. The chemical and physical structures of the chars were characterized through a range of different analytical techniques to quantify the factors contributing to reactivity differences. The morphologies of the chars were characterized with SEM and optical microscopy, while quantitative information on the ordered nature of chars was obtained through XRD on de-ashed chars. The inertinite-rich coal experienced limited fluidity during heat-treatment, resulting in slower devolatilization, limited growth in crystallite height (11.8 to 12.6Å), only rounding of particle edges, and producing > 40% of mixed-dense type chars. The vitrinite-char showed more significant structural transformations; producing mostly (80%) extensively swollen crassisphere, tenuisphere, and network-type chars, and XRD showed a large increase in crystallite height (4.3 to 11.7Å). Nitrogen adsorption and small-angle X-ray scattering (SAXS) were utilized to compare the nitrogen surface areas and pore size distributions. Both chars were mostly mesoporous but the inertinite-rich char had double the average pore size, which also resulted in a larger nitrogen surface area since nitrogen can only access surface areas in larger pores. The BET surface area was 3.9 and 2.7 m2/g for the inertinite- and vitrinite-rich chars respectively. SAXS data showed that the vitrinite-rich char had 60% higher frequencies of pores in the micropore range. Helium porosimetry indicated that the inertinite-rich coal and resultant char had higher densities than the vitrinite coal and char; 1.6 and 2.0 g/cm3, compared to 1.3 and 1.9 g/cm3 (dry basis). Non-isothermal TGA burnout profiles showed the inertinite-rich char had a burnout temperature of 680°C, slightly higher than the vitrinite-rich char’s 650 °C. This, along with the peak shape and position in the burnout profiles indicate that the vitrinite-rich char has a higher reactivity. The higher reactivity is due to a combination of factors likely including less organization, grater porosity and access to the reactive site, less ash blocking, and char morphology differences.« less

Effects of pressure on morphology and structure of bio-char from pressurized entrained-flow pyrolysis of microalgae.

PubMed

Maliutina, Kristina; Tahmasebi, Arash; Yu, Jianglong

2018-06-01

The present dataset describes the entrained-flow pyrolysis of Microalgae Chlorella vulgaris and the results obtained during bio-char characterization. The dataset includes a brief explanation of the experimental procedure, experimental conditions and the influence of pyrolysis conditions on bio-chars morphology and carbon structure. The data show an increase in sphericity and surface smoothness of bio-chars at higher pressures and temperatures. Data confirmed that the swelling ratio of bio-chars increased with pressure up to 2.0 MPa. Consequently, changes in carbon structure of bio-chars were investigated using Raman spectroscopy. The data showed the increase in carbon order of chars at elevated pressures. Changes in the chemical structure of bio-char as a function of pyrolysis conditions were investigated using FTIR analysis.

Anacardic Acids from Cashew Nuts Ameliorate Lung Damage Induced by Exposure to Diesel Exhaust Particles in Mice

PubMed Central

Carvalho, Ana Laura Nicoletti; Annoni, Raquel; Torres, Larissa Helena Lobo; Durão, Ana Carolina Cardoso Santos; Shimada, Ana Lucia Borges; Almeida, Francine Maria; Hebeda, Cristina Bichels; Lopes, Fernanda Degobbi Tenorio Quirino Santos; Dolhnikoff, Marisa; Martins, Milton Arruda; Silva, Luiz Fernando Ferraz; Farsky, Sandra Helena Poliselli; Saldiva, Paulo Hilário Nascimento; Ulrich, Cornelia M.; Owen, Robert W.; Marcourakis, Tania; Trevisan, Maria Teresa Salles; Mauad, Thais

2013-01-01

Anacardic acids from cashew nut shell liquid, a Brazilian natural substance, have antimicrobial and antioxidant activities and modulate immune responses and angiogenesis. As inflammatory lung diseases have been correlated to environmental pollutants exposure and no reports addressing the effects of dietary supplementation with anacardic acids on lung inflammation in vivo have been evidenced, we investigated the effects of supplementation with anacardic acids in a model of diesel exhaust particle- (DEP-) induced lung inflammation. BALB/c mice received an intranasal instillation of 50 μg of DEP for 20 days. Ten days prior to DEP instillation, animals were pretreated orally with 50, 150, or 250 mg/kg of anacardic acids or vehicle (100 μL of cashew nut oil) for 30 days. The biomarkers of inflammatory and antioxidant responses in the alveolar parenchyma, bronchoalveolar lavage fluid (BALF), and pulmonary vessels were investigated. All doses of anacardic acids ameliorated antioxidant enzyme activities and decreased vascular adhesion molecule in vessels. Animals that received 50 mg/kg of anacardic acids showed decreased levels of neutrophils and tumor necrosis factor in the lungs and BALF, respectively. In summary, we demonstrated that AAs supplementation has a potential protective role on oxidative and inflammatory mechanisms in the lungs. PMID:23533495

Assessment of Feeding Acceptance and Injury of Kerman Pistachios, Pistacia vera, by Brown Marmorated Stink Bug (Hemiptera: Pentatomidae)

PubMed Central

Kamiyama, Matthew T; Hernandez, Gabriel; Nay, Justin; Hoddle, Mark S

2017-01-01

Abstract In the United States, California (CA) is the primary commercial producer of pistachio nuts, Pistacia vera L. (Anacardiaceae). The brown marmorated stink bug (BMSB), Halyomorpha halys (Stål) (Hemiptera: Pentatomidae), an invasive and polyphagous insect pest from Asia, has established in urban areas in several pistachio-growing counties in CA. Breeding BMSB populations have not been detected in commercial pistachio acreage. However, the detection of BMSB in Kern and Fresno counties, major Kerman pistachio producing areas in CA, underscored key knowledge gaps on BMSB ecology in CA and motivated investigations on the susceptibility of pistachio nuts to BMSB feeding. Laboratory feeding trials conducted in quarantine under permit indicated that adult BMSB stylets can penetrate developing pistachio shells and associated feeding was correlated with kernel necrosis for nuts collected mid to late season (June to August 2016). Feeding damage estimates indicated that higher levels of kernel injury were associated with female BMSB when compared to feeding by male BMSB. These results suggest that there is probable risk of feeding damage to field grown pistachios from BMSB. The implications of this study for BMSB pest management in the CA pistachio system and future research directions are discussed. PMID:29117381

Assessment of Feeding Acceptance and Injury of Kerman Pistachios, Pistacia vera, by Brown Marmorated Stink Bug (Hemiptera: Pentatomidae).

PubMed

Lara, Jesús R; Kamiyama, Matthew T; Hernandez, Gabriel; Nay, Justin; Hoddle, Mark S; Gao, Yulin

2017-09-01

In the United States, California (CA) is the primary commercial producer of pistachio nuts, Pistacia vera L. (Anacardiaceae). The brown marmorated stink bug (BMSB), Halyomorpha halys (Stål) (Hemiptera: Pentatomidae), an invasive and polyphagous insect pest from Asia, has established in urban areas in several pistachio-growing counties in CA. Breeding BMSB populations have not been detected in commercial pistachio acreage. However, the detection of BMSB in Kern and Fresno counties, major Kerman pistachio producing areas in CA, underscored key knowledge gaps on BMSB ecology in CA and motivated investigations on the susceptibility of pistachio nuts to BMSB feeding. Laboratory feeding trials conducted in quarantine under permit indicated that adult BMSB stylets can penetrate developing pistachio shells and associated feeding was correlated with kernel necrosis for nuts collected mid to late season (June to August 2016). Feeding damage estimates indicated that higher levels of kernel injury were associated with female BMSB when compared to feeding by male BMSB. These results suggest that there is probable risk of feeding damage to field grown pistachios from BMSB. The implications of this study for BMSB pest management in the CA pistachio system and future research directions are discussed. © The Authors 2017. Published by Oxford University Press on behalf of Entomological Society of America.

Method and apparatus for acoustically monitoring the flow of suspended solid particulate matter. [Patent application; monitoring char flow in coal gasifier

DOEpatents

Roach, P.D.; Raptis, A.C.

1980-11-24

A method and apparatus for monitoring char flow in a coal gasifier system includes flow monitor circuits which measure acoustic attenuation caused by the presence of char in a char line and provides a char flow/no flow indication and an indication of relative char density. The flow monitor circuits compute the ratio of signals in two frequency bands, a first frequency band representative of background noise, and a second higher frequency band in which background noise is attenuated by the presence of char. Since the second frequency band contains higher frequencies, the ratio can be used to provide a flow/no flow indication. The second band can also be selected so that attenuation is monotonically related to particle concentration, providing a quantitative measure of char concentration.

Subcellular distribution of trace elements and liver histology of landlocked Arctic char (Salvelinus alpinus) sampled along a mercury contamination gradient.

PubMed

Barst, Benjamin D; Rosabal, Maikel; Campbell, Peter G C; Muir, Derek G C; Wang, Xioawa; Köck, Günter; Drevnick, Paul E

2016-05-01

We sampled landlocked Arctic char (Salvelinus alpinus) from four lakes (Small, 9-Mile, North, Amituk) in the Canadian High Arctic that span a gradient of mercury contamination. Metals (Hg, Se, Tl, and Fe) were measured in char tissues to determine their relationships with health indices (relative condition factor and hepatosomatic index), stable nitrogen isotope ratios, and liver histology. A subcellular partitioning procedure was employed to determine how metals were distributed between potentially sensitive and detoxified compartments of Arctic char livers from a low- and high-mercury lake (Small Lake and Amituk Lake, respectively). Differences in health indices and metal concentrations among char populations were likely related to differences in feeding ecology. Concentrations of Hg, Se, and Tl were highest in the livers of Amituk char, whereas concentrations of Fe were highest in Small and 9-Mile char. At the subcellular level we found that although Amituk char had higher concentrations of Tl in whole liver than Small Lake char, they maintained a greater proportion of this metal in detoxified fractions, suggesting an attempt at detoxification. Mercury was found mainly in potentially sensitive fractions of both Small and Amituk Lake char, indicating that Arctic char are not effectively detoxifying this metal. Histological changes in char livers, mainly in the form of melano-macrophage aggregates and hepatic fibrosis, could be linked to the concentrations and subcellular distributions of essential or non-essential metals. Copyright © 2016 Elsevier Ltd. All rights reserved.

The biodiversity of Aspergillus section Flavi in brazil nuts: from rainforest to consumer.

PubMed

Calderari, Thaiane O; Iamanaka, Beatriz T; Frisvad, Jens C; Pitt, John I; Sartori, Daniele; Pereira, Jose Luiz; Fungaro, Maria Helena P; Taniwaki, Marta H

2013-01-01

A total of 288 brazil nut samples (173 kernel and 115 shell) from the Amazon rainforest region and São Paulo State, Brazil were collected at different stages of brazil nut production. Samples were analysed for: percentages of aflatoxigenic fungal species and potential for aflatoxin production and presence of aflatoxins. Aspergillus nomius was the most common species found (1235 isolates) which amounted to 30% of the total species with potential to produce aflatoxins. This species is of concern since 100% of all isolates produced aflatoxins B(1), B(2), G(1) and G(2). Aspergillus flavus was almost equally common (1212 isolates) although only 46% produced aflatoxins under laboratory conditions, and only aflatoxins B(1) and B(2). Low number of other species with the potential to produce aflatoxins was isolated: Aspergillus arachidicola and Aspergillus bombycis produced B and G aflatoxins whilst Aspergillus pseudotamarii produced only aflatoxin B(1). The total aflatoxin levels found in samples taken from the rainforests was 0.7 μg/kg, from processing plants before and after sorting 8.0 and 0.1 μg/kg respectively, from street markets in the Amazon region 6.3 μg/kg and from supermarkets in São Paulo State 0.2 μg/kg. Processing, which included manual or mechanical sorting and drying at 60°C for 30 to 36 h, eliminated on average more than 98% of total aflatoxins. These results showed that sorting is a very effective way to decrease aflatoxin content in brazil nuts. Copyright © 2012 Elsevier B.V. All rights reserved.

Peanut and tree nut allergic reactions in restaurants and other food establishments.

PubMed

Furlong, T J; DeSimone, J; Sicherer, S H

2001-11-01

The clinical features of food-allergic reactions in restaurants and other food establishments have not been studied. Of the registrants in the United States Peanut and Tree Nut Allergy Registry (PAR), 13.7% have reported reactions associated with such establishments. The purpose of this study was to determine the features of allergic reactions to peanut and tree nut in restaurant foods and foods purchased at other private establishments (eg, ice cream shops and bakeries). Telephone interviews were conducted through use of a structured questionnaire. Subjects/parental surrogates were randomly selected from among the 706 PAR registrants who reported a reaction in a restaurant or other food establishment. Details were obtained for 156 episodes (29 first-time reactions) from 129 subjects/parental surrogates. Most reactions were caused by peanut (67%) or tree nut (24%); for some reactions (9%), the cause was a combination of peanut and another nut or was unknown. Symptoms began at a median of 5 minutes after exposure and were severe in 27% of reactions. Overall, 86% of reactions were treated (antihistamines, 86%; epinephrine, 40%). Establishments commonly cited were Asian food restaurants (19%), ice cream shops (14%), and bakeries/doughnut shops (13%). Among meal courses, desserts were a common cause (43%). Of 106 registrants with previously diagnosed allergy who ordered food specifically for ingestion by the allergic individual, only 45% gave prior notification about the allergy to the establishment. For 83 (78%) of these 106 reactions, someone in the establishment knew that the food contained peanut or tree nut as an ingredient; in 50% of these incidents, the food item was "hidden" (in sauces, dressings, egg rolls, etc), visual identification being prevented. In 23 (22%) of the 106 cases, exposures were reported from contamination caused primarily by shared cooking/serving supplies. In the remaining 21 subjects with previously diagnosed allergy, reactions resulted from ingestion of food not intended for them, ingestion of food selected from buffet/food bars, or skin contact/inhalation (residual food on tables, 2; peanut shells covering floors, 2; being within 2 feet of the cooking of the food, 1). Restaurants and other food establishments pose a number of dangers for peanut- and tree nut-allergic individuals, particularly with respect to cross-contamination and unexpected ingredients in desserts and Asian food. Failure to establish a clear line of communication between patron and establishment is a frequent cause of errors.

Molecular aspects of aromatic C additions to soils: Implications of char quality for ecosystem functionality

NASA Astrophysics Data System (ADS)

Keiluweit, M.; Nico, P. S.; Johnson, M. G.; Kleber, M.

2009-12-01

Solid residues of incomplete combustion (biochar or char) are continuously being added to soils due to natural vegetation fires in many ecosystems. However, new strategies for carbon sequestration in soils are likely to include the active addition of biochar to soils. Since biochar is a highly aromatic organic material such additions will modify the native molecular structure of soil organic matter and thus alter interactions with the global atmosphere and hydrosphere. Here we present a molecular level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. Differences among wood and grass charred at temperatures from 100 to 700°C are investigated. BET-N2 surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS) and Fourier transform infrared (FT-IR) spectroscopy results demonstrate how the two plant precursor materials undergo analogous, but quantitatively different physical-chemical transitions as charring intensity increases. These changes suggest the existence of four distinct physical and chemical categories of char. We find that each category of char consists of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by turbostratic (disordered) graphitic crystallites. There is wide variation in both the chemical and the physical nature of aromatic carbon among these char categories. In this presentation we will point out how molecular variations among the aromatic components of the different char categories translate into differences in their ability to: (i) persist in the environment, (ii) function as environmental sorbents, and (iii) to enable the soil to provide environmental services.

Spatial and temporal trends of mercury and other metals in landlocked char from lakes in the Canadian Arctic archipelago.

PubMed

Muir, Derek; Wang, Xiaowa; Bright, Doug; Lockhart, Lyle; Köck, Günter

2005-12-01

Spatial and temporal trends of mercury (Hg) and 22 other elements were examined in landlocked Arctic char (Salvelinus alpinus) from six lakes in the Canadian Arctic (Char, Resolute and North Lakes, and Amituk Lake on Cornwallis Island, Sapphire Lake on Devon Island and Boomerang Lake on Somerset Island). The objectives of the study were to compare recent concentrations of Hg and other metals in char with older data from Amituk, Resolute and Char Lakes, in order to examine temporal trends as well as to investigate factors influencing spatial trends in contaminant levels such as lake characteristics, trophic position, size and age of the fish. Geometric mean Hg concentrations in dorsal muscle ranged from 0.147 microg/g wet weight (ww) in Resolute Lake to 1.52 microg/g ww in Amituk Lake for samples collected over the period 1999-2003. Char from Amituk Lake also had significantly higher selenium (Se). Mercury in char from Resolute Lake was strongly correlated with fish length, weight, and age, as well as with thallium, lead and Se. In 5 of 6 lakes, Hg concentrations were correlated with stable nitrogen isotope ratios (delta15N) and larger char were feeding at a higher trophic level presumably due to feeding on smaller char. Weight adjusted mean Hg concentrations in char from Amituk Lake, and unadjusted geometric means in Char Lake and Resolute Lakes, did not show any statistically significant increase from the early 1990s to 2003. However, small sample sizes from 1999-2003 for fish <1000 g limited the power of this comparison in Char and Amituk Lakes. In Resolute Lake char, manganese, strontium and zinc showed consistent decreases from 1997 or 1999 to 2003 while nickel generally increased over the 6 year period. Differences in char trophic level inferred from delta15N values best explained the higher concentrations of Hg in Amituk Lake compared to the other lakes.

Evaluating phenanthrene sorption on various wood chars

USGS Publications Warehouse

James, G.; Sabatini, D.A.; Chiou, C.T.; Rutherford, D.; Scott, A.C.; Karapanagioti, H.K.

2005-01-01

A certain amount of wood char or soot in a soil or sediment sample may cause the sorption of organic compounds to deviate significantly from the linear partitioning commonly observed with soil organic matter (SOM). Laboratory produced and field wood chars have been obtained and analyzed for their sorption isotherms of a model solute (phenanthrene) from water solution. The uptake capacities and nonlinear sorption effects with the laboratory wood chars are similar to those with the field wood chars. For phenanthrene aqueous concentrations of 1 ??gl-1, the organic carbon-normalized sorption coefficients (log Koc) ranging from 5.0 to 6.4 for field chars and 5.4-7.3 for laboratory wood chars, which is consistent with literature values (5.6-7.1). Data with artificial chars suggest that the variation in sorption potential can be attributed to heating temperature and starting material, and both the quantity and heterogeneity of surface-area impacts the sorption capacity. These results thus help to corroborate and explain the range of log Koc values reported in previous research for aquifer materials containing wood chars. ?? 2004 Elsevier Ltd. All rights reserved.

Fast pyrolysis of palm kernel shells: influence of operation parameters on the bio-oil yield and the yield of phenol and phenolic compounds.

PubMed

Kim, Seon-Jin; Jung, Su-Hwa; Kim, Joo-Sik

2010-12-01

Palm kernel shells were pyrolyzed in a pyrolysis plant equipped with a fluidized-bed reactor and a char-separation system. The influence of reaction temperature, feed size and feed rate on the product spectrum was also investigated. In addition, the effect of reaction temperature on the yields of phenol and phenolic compounds in the bio-oil was examined. The maximum bio-oil yield was 48.7 wt.% of the product at 490 degrees C. The maximum yield of phenol plus phenolic compounds amounted to about 70 area percentage at 475 degrees C. The yield of pyrolytic lignin after its isolation from the bio-oil was approximately 46 wt.% based on the water and ash free oil. The pyrolytic lignin was mainly composed of phenol, phenolic compounds and oligomers of coniferyl, sinapyl and p-coumaryl alcohols. From the result of a GPC analysis, the number average molecular weight and the weight average molecular weight were 325 and 463 g/mol, respectively. 2010 Elsevier Ltd. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vyas, S.N.; Patwardhan, S.R.; Vijayalakshmi, S.

Adsorption on carbon molecular sieves (CMS) prepared by coke deposition has become an interesting area of adsorption due to its microporous nature and favorable separation factor on size and shape selectivity basis for many gaseous systems. In the present work CMS was synthesized from coconut shell through three major steps, namely, carbonization, activation, and coke deposition by hydrocarbon cracking. The crushed, washed, and sieved granules of coconut shell (particle size 2--3 mm) were pretreated with sodium silicate solution and oven-dried at 150 C to create the inorganic sites necessary for coke deposition. Carbonization and activation of the dried granules weremore » carried out at 800 C, for 30 min each. The activated char thus produced was subjected to hydrocarbon cracking at 600 C for periods varying from 30 to 180 min. The product samples were characterized in terms of adsorption isotherm, kinetic adsorption curve, surface area, pore volume, pore size distribution, and characteristic energy for adsorption by using O[sub 2], N[sub 2], C[sub 2]H[sub 2], CO[sub 2], C[sub 3]H[sub 6], and CH[sub 4].« less

Process for reducing sulfur in coal char

DOEpatents

Gasior, Stanley J.; Forney, Albert J.; Haynes, William P.; Kenny, Richard F.

1976-07-20

Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.

Dynamic molecular structure of plant biomass-derived black carbon (biochar)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keiluweit, M.; Nico, P.S.; Johnson, M.G.

2009-11-15

Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration ('biochar'). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. BET-N{sub 2} surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous, but quantitatively different physical-chemical transitions as charring temperature increases frommore » 100 to 700 C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by disordered graphitic crystallites. The molecular variations among the different char categories translate into differences in their ability to persist in the environment and function as environmental sorbents.« less

Determination of cannabinoids in hemp nut products in Taiwan by HPLC-MS/MS coupled with chemometric analysis: quality evaluation and a pilot human study.

PubMed

Chang, Chih-Wei; Tung, Chun-Wei; Tsai, Chin-Chuan; Wu, Yu-Tse; Hsu, Mei-Chich

2017-06-01

Hemp nuts are mature cannabis seeds obtained after shelling and that are commonly used in traditional Chinese medicine for treating functional constipation. In this work, we screened hemp nut products, classified them, and verified the legality of consuming them. A total of 18 products were purchased from Taiwan, China, and Canada. Validated high-performance liquid chromatography with tandem mass spectrometry methods were developed for analyzing the cannabinoid (i.e., Δ 9 -tetrahydrocannabinol (THC), cannabidiol (CBD), and cannabinol) content of the products and the concentration of urinary 11-nor-9-carboxy-THC. Chemometric techniques, namely hierarchical clustering analysis (HCA) and principal component analysis (PCA), were applied for rapidly classifying 11 concentrated powder products in Taiwan. A pilot human study comprising single and multiple administrations of a product with 1.5 µg/g of THC was conducted to examine the urinary 11-nor-9-carboxy-THC concentration. Through optimization of 3 2 full factorial design, using 60% isopropanol as the extraction solvent exhibited the highest yield of cannabinoids and was applied as the optimal condition in further analysis. The results of HCA and PCA on quality evaluation were in good agreement; however, the tested products possessed distinct CBD-to-THC ratios which ranged widely from 0.1:1 to 46.8:1. Particularly, the products with CBD-to-THC ratios higher than 1:1 were the majority in Taiwan. Our data suggested that all the tested hemp nut products met the Taiwan restriction criterion of 10 µg/g of THC. We propose a usual consumption amount of hemp nut products in Taiwan would unlikely to violate the cut-off point of 15 ng/mL of urinary 11-nor-9-carboxy-THC. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Ferns and fires: Experimental charring of ferns compared to wood and implications for paleobiology, paleoecology, coal petrology, and isotope geochemistry

DOE Office of Scientific and Technical Information (OSTI.GOV)

McParland, L.C.; Collinson, M.E.; Scott, A.C.

We report the effects of charring on the ferns Osmunda, Pteridium, and Matteucia with coniferous wood (Sequoia) for comparison. Like charred wood, charred ferns shrink, become black and brittle with a silky sheen, and retain three-dimensional cellular structure. Ferns yield recognizable charcoal (up to 800{sup o}C) that could potentially survive in the fossil record enabling reconstruction of ancient fire-prone vegetation containing ferns. Charred fossils of herbaceous ferns would indicate surface fires. Like charred wood, cell-wall layers of charred ferns homogenize, and their reflectance values increase with rising temperature. Charcoalified fragments of thick-walled cells from conifer wood or fern tissues aremore » indistinguishable and so cannot be used to infer the nature of source vegetation. Charred conifer wood and charred fern tissues show a relationship between mean random reflectance and temperature of formation and can be used to determine minimum ancient fire temperatures. Charred fern tissues consistently have significantly more depleted {delta}{sup 13}C values ({le} 4 parts per thousand) than charred wood. Therefore, if an analysis of {delta} {sup 13}C through time included fern charcoal among a succession of wood charcoals, any related shifts in {delta} {sup 13}C could be misinterpreted as atmospheric changes or misused as isotope stratigraphic markers. Thus, charcoals of comparable botanical origin and temperatures of formation should be used in order to avoid misinterpretations of shifts in {delta}{sup 13}C values.« less

Design of a Decentralized Asynchronous Membership Protocol and an Implementation of Its Communications Layer

DTIC Science & Technology

1993-03-01

sstm[MAXFD], stpm [MAXFD]; u-short fport,bport; char sfport[MLAXPORTI, sbport[MAXPORTII; int childpid; char my~name[MAXHOSTNAME+ 1 ], *ip~add&, char my...34, "tpm", stpm , (char*) NULL); printf ("Error executing tpm\

Method and apparatus for acoustically monitoring the flow of suspended solid particulate matter

DOEpatents

Roach, Paul D.; Raptis, Apostolos C.

1982-01-01

A method and apparatus for monitoring char flow in a coal gasifier system cludes flow monitor circuits which measure acoustic attenuation caused by the presence of char in a char line and provide a char flow/no flow indication and an indication of relative char density. The flow monitor circuits compute the ratio of signals in two frequency bands, a first frequency band representative of background noise, and a second higher frequency band in which background noise is attenuated by the presence of char. Since the second frequency band contains higher frequencies, the ratio can be used to provide a flow/no flow indication. The second band can also be selected so that attenuation is monotonically related to particle concentration, providing a quantitative measure of char concentration.

Effect of reactivity loss on apparent reaction order of burning char particles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murphy, Jeffrey J.; Shaddix, Christopher R.

Considerable debate still exists in the char combustion community over the expected and observed reaction orders of carbon reacting with oxygen. In particular, very low values of the reaction order (approaching zero) are commonly observed in char combustion experiments. These observations appear to conflict with porous catalyst theory as first expressed by Thiele, which suggests that the apparent reaction order must be greater than 0.5. In this work, we propose that this conflict may be resolved by considering the decrease in char reactivity with burnout due to ash effects, thermal annealing, or other phenomena. Specifically, the influence of ash dilutionmore » of the available surface area on the apparent reaction order is explored. Equations describing the ash dilution effect are combined with a model for particle burnout based on single-film nth-order Arrhenius char combustion and yield an analytical expression for the effective reaction order. When this expression is applied for experimental conditions reflecting combustion of individual pulverized coal particles in an entrained flow reactor, the apparent reaction order is shown to be lower than the inherent char matrix reaction order, even for negligible extents of char conversion. As char conversion proceeds and approaches completion, the apparent reaction order drops precipitously past zero to negative values. Conversely, the inclusion of the ash dilution model has little effect on the char conversion profile or char particle temperature until significant burnout has occurred. Taken together, these results suggest that the common experimental observation of low apparent reaction orders during char combustion is a consequence of the lack of explicit modeling of the decrease in char reactivity with burnout. (author)« less

Comparison of the combustion reactivity of TGA and drop tube furnace chars from a bituminous coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katherine Le Manquais; Colin Snape; Ian McRobbie

This paper compares the reactivity of chars generated in a drop tube furnace (DTF) to those from TGA. The implications of devolatilization temperature, heating rate and residence time are considered. For the smaller particle size ranges of the bituminous coal investigated (ATC), optimized devolatilization procedures were used to generate corresponding TGA burnout rates between the two char types. However, with fractions of >75 {mu}m, the DTF chars showed an increased burnout propensity when moving from combustion regime II to combustion regime III. Scanning electron microscope (SEM) images and internal surface areas indicate that this is because of incompatible char morphologies.more » Thus, while chars produced under the conditions of TGA pyrolysis strongly resemble raw coal and display an undeveloped pore network; the DTF chars are highly porous, extensively swollen and possess considerably larger internal surface areas. Subsequently, char burnout variability was quantified, with the reactivity distribution for the DTF samples found to be up to an order of magnitude more significant than for the TGA chars. This is attributed to a fluctuating devolatilization environment on the DTF. Finally, a TGA study observed a robust particle size based compensation effect for the TGA chars, with the relative reaction rates and activation energies demonstrating the presence of internal diffusion control. However this phenomenon was partly alleviated for the DTF chars, since their higher porosities reduce mass transfer restrictions. Moreover, it should be realized that DTF char fractions of <38 {mu}m, including those required to ensure true intrinsic control under the investigated burnout conditions, cannot be produced directly. This is because of bridging and sloughing in the DTF's screw-feeder. Instead, such samples must be created by grinding larger particles, which destroys the char's existing porosity. 60 refs., 9 figs., 5 tabs.« less

OXIDATION AND DEVOLATILIZATION OF NITROGEN IN COAL CHAR

EPA Science Inventory

The reactions of organically-bound nitrogen in coal char during combustion have been studied in a laboratory furnace using size-graded char particles prepared by the pyrolysis of a Montana lignite. The time-resolved variations of nitrogen-to-carbon ratio during char oxidation hav...

Mechanical properties of acacia and eucalyptus wood chars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, M.; Verma, B.B.; Gupta, R.C.

1999-10-01

In the present investigation the effects of carbonization conditions (temperature and heating rate) on the mechanical properties (such as crushing and impact strengths and shatter index) of acacia and eucalyptus wood chars have been determined. The crushing and impact strengths of both the acacia and eucalyptus wood chars (made by slow carbonization) decreased with increase of preparation temperature up to 600 C, followed by an increase thereafter. These wood chars showed a continuous increase in shatter index values with carbonization temperature. In contrast to slow carbonization (heating rate 4 C min{sup {minus}1}), rapid carbonization (heating rate 30 C min{sup {minus}1})more » yielded chars of lower crushing strengths. Slowly carbonized eucalyptus wood gave chars of superior crushing and impact strengths than those produced from acacia wood under the same carbonization conditions. The crushing and impact strengths of these wood chars, in general, have shown an increase with increase in their apparent density. The crushing strength of cubic-shaped wood char decreased with increase in size.« less

Properties of gasification-derived char and its utilization for catalytic tar reforming

NASA Astrophysics Data System (ADS)

Qian, Kezhen

Char is a low-value byproduct of biomass gasification and pyrolysis with many potential applications, such as soil amendment and the synthesis of activated carbon. The overall goal of the proposed research was to develop novel methods to use char derived from gasification for high-value applications in syngas conditioning. The first objective was to investigate effects of gasification condition and feedstock on properties of char derived from fluidized bed gasification. Results show that the surface areas of most of the char were 1--10 m 2/g and increased as the equivalence ratio increased. Char moisture and fixed carbon contents decreased while ash content increased as equivalence ratio increased. The next objective was to study the properties of sorghum and red cedar char derived from downdraft gasifier. Red cedar char contained more aliphatic carbon and o-alkyl carbon than sorghum char. Char derived from downdraft gasification had higher heating values and lower ash contents than char derived from fluidized bed gasification. The gasification reactivity of red cedar char was higher than that of sorghum char. Then, red cedar char based catalysts were developed with different preparation method to reform toluene and naphthalene as model tars. The catalyst prepared with nickel nitrate was found to be better than that with nickel acetate. The nickel particle size of catalyst impregnated with nickel nitrate was smaller than that of catalyst impregnated with nickel acetate. The particle size of catalyst impregnated with nickel acetate decreased by hydrazine reduction. The catalyst impregnated with nickel nitrate had the highest toluene removal efficiency, which was 70%--100% at 600--800 °C. The presence of naphthalene in tar reduced the catalyst efficiency. The toluene conversion was 36--99% and the naphthalene conversion was 37%--93% at 700--900 °C. Finally, effects of atmosphere and pressure on catalytic reforming of lignin-derived tars over the developed catalyst were investigated. An increase in reaction temperature led to an increase in removal of most tar components except naphthalene. High pressure promoted the catalytic conditioning of lignin tar. Hydrogen promoted the conversion of lignin into non-condensable gas.

Overview of the CHarring Ablator Response (CHAR) Code

NASA Technical Reports Server (NTRS)

Amar, Adam J.; Oliver, A. Brandon; Kirk, Benjamin S.; Salazar, Giovanni; Droba, Justin

2016-01-01

An overview of the capabilities of the CHarring Ablator Response (CHAR) code is presented. CHAR is a one-, two-, and three-dimensional unstructured continuous Galerkin finite-element heat conduction and ablation solver with both direct and inverse modes. Additionally, CHAR includes a coupled linear thermoelastic solver for determination of internal stresses induced from the temperature field and surface loading. Background on the development process, governing equations, material models, discretization techniques, and numerical methods is provided. Special focus is put on the available boundary conditions including thermochemical ablation and contact interfaces, and example simulations are included. Finally, a discussion of ongoing development efforts is presented.

Overview of the CHarring Ablator Response (CHAR) Code

NASA Technical Reports Server (NTRS)

Amar, Adam J.; Oliver, A. Brandon; Kirk, Benjamin S.; Salazar, Giovanni; Droba, Justin

2016-01-01

An overview of the capabilities of the CHarring Ablator Response (CHAR) code is presented. CHAR is a one-, two-, and three-dimensional unstructured continuous Galerkin finite-element heat conduction and ablation solver with both direct and inverse modes. Additionally, CHAR includes a coupled linear thermoelastic solver for determination of internal stresses induced from the temperature field and surface loading. Background on the development process, governing equations, material models, discretization techniques, and numerical methods is provided. Special focus is put on the available boundary conditions including thermochemical ablation, surface-to-surface radiation exchange, and flowfield coupling. Finally, a discussion of ongoing development efforts is presented.

Mercury adsorption of modified mulberry twig chars in a simulated flue gas.

PubMed

Shu, Tong; Lu, Ping; He, Nan

2013-05-01

Mulberry twig chars were prepared by pyrolysis, steam activation and impregnation with H2O2, ZnCl2 and NaCl. Textural characteristics and surface functional groups were performed using nitrogen adsorption and FTIR, respectively. Mercury adsorption of different modified MT chars was investigated in a quartz fixed-bed absorber. The results indicated that steam activation and H2O2-impregnation can improve pore structure significantly and H2O2-impregnation and chloride-impregnation promote surface functional groups. However, chloride-impregnation has adverse effect on pore structure. Mercury adsorption capacities of impregnated MT chars with 10% or 30% H2O2 are 2.02 and 1.77 times of steam activated MT char, respectively. Mercury adsorption capacity of ZnCl2-impregnated MT char increase with increasing ZnCl2 content and is better than that of NaCl-impregnated MT char at the same chloride content. The modified MT char (MT873-A-Z5) prepared by steam activation following impregnation with 5% ZnCl2 exhibits a higher mercury adsorption capacity (29.55 μg g(-1)) than any other MT chars. Copyright © 2013 Elsevier Ltd. All rights reserved.

The combustion of large particles of char in bubbling fluidized beds: The dependence of Sherwood number and the rate of burning on particle diameter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dennis, J.S.; Hayhurst, A.N.; Scott, S.A.

Particles of char derived from a variety of fuels (e.g., biomass, sewage sludge, coal, or graphite), with diameters in excess of {approx}1.5mm, burn in fluidized bed combustors containing smaller particles of, e.g., sand, such that the rate is controlled by the diffusion both of O{sub 2} to the burning solid and of the products CO and CO{sub 2} away from it into the particulate phase. It is therefore important to characterize these mass transfer processes accurately. Measurements of the burning rate of char particles made from sewage sludge suggest that the Sherwood number, Sh, increases linearly with the diameter ofmore » the fuel particle, d{sub char} (for d{sub char}>{approx}1.5mm). This linear dependence of Sh on d{sub char} is expected from the basic equation Sh=2{epsilon}{sub mf}(1+d{sub char}/2{delta}{sub diff})/{tau}, provided the thickness of the boundary layer for mass transfer, {delta}{sub diff}, is constant in the region of interest (d{sub char}>{approx}1.5mm). Such a dependence is not seen in the empirical equations currently used and based on the Frossling expression. It is found here that for chars made from sewage sludge (for d{sub char}>{approx}1.5mm), the thickness of the boundary layer for mass transfer in a fluidized bed, {delta}{sub diff}, is less than that predicted by empirical correlations based on the Frossling expression. In fact, {delta}{sub diff} is not more than the diameter of the fluidized sand particles. Finally, the experiments in this study indicate that models based on surface renewal theory should be rejected for a fluidized bed, because they give unrealistically short contact times for packets of fluidized particles at the surface of a burning sphere. The result is the new correlation Sh = 2{epsilon}{sub mf}/{tau} + (A{sub cush}/A{sub char})(d{sub char}/ {delta}{sub diff}) for the dependence of Sh on d{sub char}, the diameter of a burning char particle. This equation is based on there being a gas-cushion of fluidizing gas underneath a burning char particle; the implication of this correlation is that a completely new picture emerges for the combustion of a char particle in a hot fluidized bed. (author)« less

Compositions and sorptive properties of crop residue-derived chars

USGS Publications Warehouse

Chun, Y.; Sheng, G.; Chiou, G.T.; Xing, B.

2004-01-01

Chars originating from the burning or pyrolysis of vegetation may significantly sorb neutral organic contaminants (NOCs). To evaluate the relationship between the char composition and NOC sorption, a series of char samples were generated by pyrolyzing a wheat residue (Triticum aestivum L) for 6 h at temperatures between 300 ??C and 700 ??C and analyzed for their elemental compositions, surface areas, and surface functional groups. The samples were then studied for their abilities to sorb benzene and nitrobenzene from water. A commercial activated carbon was used as a reference carbonaceous sample. The char samples produced at high pyrolytic temperatures (500-700 ??C) were well carbonized and exhibited a relatively high surface area (>300 m2/g), little organic matter (20% oxygen). The char samples exhibited a significant range of surface acidity/basicity because of their different surface polar-group contents, as characterized by the Boehm titration data and the NMR and FTIR spectra. The NOC sorption by high-temperature chars occurred almost exclusively by surface adsorption on carbonized surfaces, whereas the sorption by low-temperature chars resulted from the surface adsorption and the concurrent smaller partition into the residual organic-matter phase. The chars appeared to have a higher surface affinity for a polar solute (nitrobenzene) than for a nonpolar solute (benzene), the difference being related to the surface acidity/basicity of the char samples.

Production of activated char from Illinois coal for flue gas cleanup

USGS Publications Warehouse

Lizzio, A.A.; DeBarr, J.A.; Kruse, C.W.

1997-01-01

Activated chars were produced from Illinois coal and tested in several flue gas cleanup applications. High-activity chars that showed excellent potential for both SO2 and NOx removal were prepared from an Illinois No. 2 bituminous coal. The SO2 (120 ??C) and NOx (25 ??C) removal performance of one char compared favorably with that of a commercial activated carbon (Calgon Centaur). The NOx removal performance of the same char at 120 ??C exceeded that of the Centaur carbon by more than 1 order of magnitude. Novel char preparation methods were developed including oxidation/thermal desorption and hydrogen treatments, which increased and preserved, respectively, the active sites for SO2 and NOx adsorption. The results of combined SO2/NOx removal tests, however, suggest that SO2 and NOx compete for similar adsorption sites and SO2 seems to be more strongly adsorbed than NO. A low-activity, low-cost char was also developed for cleanup of incinerator flue gas. A three-step method involving coal preoxidation, pyrolysis, and CO2 activation was used to produce the char from Illinois coal. Five hundred pounds of the char was tested on a slipstream of flue gas from a commercial incinerator in Germany. The char was effective in removing >97% of the dioxins and furans present in the flue gas; mercury levels were below detectable limits.

A Modular Approach to Endurance Loading of Subsistence Stores in Naval Vessels.

DTIC Science & Technology

1980-09-01

Navy ships. Dehydrated foods like instant potatoes, powdered eggs and dry synthetic vinegar allow more endurance per package with less storage weight...Coffee, frees, dried, instant lb Coffee. roaed, ground Lb 3.oo 0.2W ga mix. dehydrated £1 cyl co Basa, trash, In-shell ai 3.460 0.2ŝ I" Witmes, tose... NOODLES , egg lb 8 F92 RICE, parboiled lb 60 G13 SPAGHETTI lb 68 G19 F82 STARCH, Corn lb 15 G21 SUGAR, CONFECTIONERY, AND NUTS COCONUT, prepared cn 4

Solid-State NMR Investigation of Bio-chars Produced from Biomass Components and Whole Biomasses

DOE PAGES

Ben, Haoxi; Hao, Naijia; Liu, Qian; ...

2017-08-24

Bio-char is a by-product from thermochemical treatment of biomass and has been identified as an energy condensed product with a comparable heating value as commercial coal. However, the combustion of such solid product as an energy resource is only a preliminary application. It is highly possible to convert bio-char, which always has a condensed aromatic and porous structure to various high-value products. The investigations of the structures and formation pathways for the bio-char are very important to any future applications. In this study, six different biomass components, including cellulose, lignin, and tannin, and three whole biomasses—pine wood, pine residue, andmore » pine bark—have been used to produce bio-char at 400, 500, and 600 °C. Solid-state NMR and FT-IR have been employed in this study to characterize the structures for the bio-chars. The results indicated that the bio-chars produced from lignin contained some methoxyl groups, and the bio-chars produced from tannin contained significantly higher amount of phenolic hydroxyl groups. Compared to the bio-chars produced from pine wood and residue, the bio-chars produced from pine bark contained more aromatic C–O bonds, and aliphatic C–O and C–C bonds, which may be due to the significantly higher amount of lignin and tannin in the pine bark. Furthermore, the elevated amounts of aromatic C–O and aliphatic C–O and C–C bonds in the bio-chars from pine bark appeared to be completely decomposed at 600 °C.« less

High temperature gasification of high heating-rate chars using a flat-flame reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Tian; Niu, Yanqing; Wang, Liang

The increasing interest in gasification and oxy-fuel combustion of biomass has heightened the need for a detailed understanding of char gasification in industrially relevant environments (i.e., high temperature and high-heating rate). Despite innumerable studies previously conducted on gasification of biomass, very few have focused on such conditions. Consequently, in this study the high-temperature gasification behaviors of biomass-derived chars were investigated using non-intrusive techniques. Two biomass chars produced at a heating rate of approximately 10 4 K/s were subjected to two gasification environments and one oxidation environment in an entrained flow reactor equipped with an optical particle-sizing pyrometer. A coal charmore » produced from a common U.S. low sulfur subbituminous coal was also studied for comparison. Both char and surrounding gas temperatures were precisely measured along the centerline of the furnace. Despite differences in the physical and chemical properties of the biomass chars, they exhibited rather similar reaction temperatures under all investigated conditions. On the other hand, a slightly lower particle temperature was observed in the case of coal char gasification, suggesting a higher gasification reactivity for the coal char. A comprehensive numerical model was applied to aid the understanding of the conversion of the investigated chars under gasification atmospheres. In addition, a sensitivity analysis was performed on the influence of four parameters (gas temperature, char diameter, char density, and steam concentration) on the carbon conversion rate. Here, the results demonstrate that the gas temperature is the most important single variable influencing the gasification rate.« less

Solid-State NMR Investigation of Bio-chars Produced from Biomass Components and Whole Biomasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ben, Haoxi; Hao, Naijia; Liu, Qian

Bio-char is a by-product from thermochemical treatment of biomass and has been identified as an energy condensed product with a comparable heating value as commercial coal. However, the combustion of such solid product as an energy resource is only a preliminary application. It is highly possible to convert bio-char, which always has a condensed aromatic and porous structure to various high-value products. The investigations of the structures and formation pathways for the bio-char are very important to any future applications. In this study, six different biomass components, including cellulose, lignin, and tannin, and three whole biomasses—pine wood, pine residue, andmore » pine bark—have been used to produce bio-char at 400, 500, and 600 °C. Solid-state NMR and FT-IR have been employed in this study to characterize the structures for the bio-chars. The results indicated that the bio-chars produced from lignin contained some methoxyl groups, and the bio-chars produced from tannin contained significantly higher amount of phenolic hydroxyl groups. Compared to the bio-chars produced from pine wood and residue, the bio-chars produced from pine bark contained more aromatic C–O bonds, and aliphatic C–O and C–C bonds, which may be due to the significantly higher amount of lignin and tannin in the pine bark. Furthermore, the elevated amounts of aromatic C–O and aliphatic C–O and C–C bonds in the bio-chars from pine bark appeared to be completely decomposed at 600 °C.« less

High temperature gasification of high heating-rate chars using a flat-flame reactor

DOE PAGES

Li, Tian; Niu, Yanqing; Wang, Liang; ...

2017-08-25

The increasing interest in gasification and oxy-fuel combustion of biomass has heightened the need for a detailed understanding of char gasification in industrially relevant environments (i.e., high temperature and high-heating rate). Despite innumerable studies previously conducted on gasification of biomass, very few have focused on such conditions. Consequently, in this study the high-temperature gasification behaviors of biomass-derived chars were investigated using non-intrusive techniques. Two biomass chars produced at a heating rate of approximately 10 4 K/s were subjected to two gasification environments and one oxidation environment in an entrained flow reactor equipped with an optical particle-sizing pyrometer. A coal charmore » produced from a common U.S. low sulfur subbituminous coal was also studied for comparison. Both char and surrounding gas temperatures were precisely measured along the centerline of the furnace. Despite differences in the physical and chemical properties of the biomass chars, they exhibited rather similar reaction temperatures under all investigated conditions. On the other hand, a slightly lower particle temperature was observed in the case of coal char gasification, suggesting a higher gasification reactivity for the coal char. A comprehensive numerical model was applied to aid the understanding of the conversion of the investigated chars under gasification atmospheres. In addition, a sensitivity analysis was performed on the influence of four parameters (gas temperature, char diameter, char density, and steam concentration) on the carbon conversion rate. Here, the results demonstrate that the gas temperature is the most important single variable influencing the gasification rate.« less

Simulation of Oil Palm Shell Pyrolysis to Produce Bio-Oil with Self-Pyrolysis Reactor

NASA Astrophysics Data System (ADS)

Fika, R.; Nelwan, L. O.; Yulianto, M.

2018-05-01

A new self-pyrolysis reactor was designed to reduce the utilization of electric heater due to the energy saving for the production of bio-oil from oil palm shell. The yield of the bio- oil was then evaluated with the developed mathematical model by Sharma [1] with the characteristic of oil palm shell [2]. During the simulation, the temperature on the combustion chamber on the release of the bio-oil was utilized to determine the volatile composition from the combustion of the oil palm shell as fuel. The mass flow was assumed constant for three experiments. The model resulted in a significant difference between the simulated bio-oil and experiments. The bio-oil yields from the simulation were 22.01, 16.36, and 21.89 % (d.b.) meanwhile the experimental yields were 10.23, 9.82, and 8.41% (d.b.). The char yield varied from 30.7 % (d.b.) from the simulation to 40.9 % (d.b.) from the experiment. This phenomenon was due to the development of process temperature over time which was not considered as one of the influential factors in producing volatile matters on the simulation model. Meanwhile the real experiments highly relied on the process conditions (reactor type, temperature over time, gas flow). There was also possibilities of the occurrence of the gasification inside the reactor which caused the liquid yield was not as high as simulated. Further simulation model research on producing the bio-oil yield will be needed to predict the optimum condition and temperature development on the newly self-pyrolysis reactor.

47 CFR 15.122 - Closed caption decoder requirements for digital television receivers and converter boxes.

Code of Federal Regulations, 2011 CFR

2011-10-01

... code 0×2D Lower-left border (⌊), G2 char code 0×7C G0 dash (-), char code 0×2D Horizontal border... (-), char code 0×2D Upper-left border (⌈), G2 char code 0×7F G0 dash (-), char code 0×2D (4) Support for..., if the character to the left of the embedded return is a hyphen, the embedded return should be...

47 CFR 15.122 - Closed caption decoder requirements for digital television receivers and converter boxes.

Code of Federal Regulations, 2010 CFR

2010-10-01

... code 0×2D Lower-left border (⌊), G2 char code 0×7C G0 dash (-), char code 0×2D Horizontal border... (-), char code 0×2D Upper-left border (⌈), G2 char code 0×7F G0 dash (-), char code 0×2D (4) Support for..., if the character to the left of the embedded return is a hyphen, the embedded return should be...

The effect of 150μm expandable graphite on char expansion of intumescent fire retardant coating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ullah, Sami, E-mail: samichemist1@gmail.com; Shariff, A. M., E-mail: azmish@petronas.com.my, E-mail: azmibustam@petronas.com.my; Bustam, M. A., E-mail: azmish@petronas.com.my, E-mail: azmibustam@petronas.com.my

2014-10-24

Intumescent is defined as the swelling of certain substances to insulate the underlying substrate when they are heated. In this research work the effect of 150μm expandable graphite (EG) was studied on char expansion, char morphology and char composition of intumescent coating formulations (ICFs). To study the expansion and thermal properties of the coating, nine different formulations were prepared. The coatings were tested at 500 °C for one hour and physically were found very stable and well bound with the steel substrate. The morphology was studied by Scanning Electron Microscopy (SEM). The char composition was analysed by X-ray Diffraction (XRD)more » and Fourier transform infrared spectroscopy (FTIR) techniques. EG above than 10.8wt% expands the char abruptly with uniform network structure and affect the outer surface of the char.« less

Physico-chemical properties and gasification reactivity of co-pyrolysis char from different rank of coal blended with lignocellulosic biomass: Effects of the cellulose.

PubMed

Wu, Zhiqiang; Wang, Shuzhong; Luo, Zhengyuan; Chen, Lin; Meng, Haiyu; Zhao, Jun

2017-07-01

In this paper, the influence of cellulose on the physicochemical properties and the gasification reactivity of co-pyrolysis char was investigated. A specific surface area analyzer and an X-ray diffraction system were used to characterize the pore structure and the micro-crystalline structure of char. Fractal theory and deconvolution method were applied to quantitatively investigate the influence of cellulose on the structure of co-pyrolysis char. The results indicate that the improvements in the pore structure due to the presence of cellulose are more pronounced in the case of anthracite char with respect to bituminous char. Cellulose promotes the ordering of micro-scale structure and the uniformity of both anthracite and bituminous char, while the negative synergetic effect was observed during gasification of co-pyrolysis char. The exponential relationships between fractal dimension and specific surface area were determined, along with the relations between the gasification reactivity index and the microcrystalline structure parameter. Copyright © 2017 Elsevier Ltd. All rights reserved.

A volumetric ablation model of EPDM considering complex physicochemical process in porous structure of char layer

NASA Astrophysics Data System (ADS)

Yang, Liu; Xiao-Jing, Yu; Jian-Ming, Ma; Yi-Wen, Guan; Jiang, Li; Qiang, Li; Sa, Yang

2017-06-01

A volumetric ablation model for EPDM (ethylene- propylene-diene monomer) is established in this paper. This model considers the complex physicochemical process in the porous structure of a char layer. An ablation physics model based on a porous structure of a char layer and another model of heterogeneous volumetric ablation char layer physics are then built. In the model, porosity is used to describe the porous structure of a char layer. Gas diffusion and chemical reactions are introduced to the entire porous structure. Through detailed formation analysis, the causes of the compact or loose structure in the char layer and chemical vapor deposition (CVD) reaction between pyrolysis gas and char layer skeleton are introduced. The Arrhenius formula is adopted to determine the methods for calculating carbon deposition rate C which is the consumption rate caused by thermochemical reactions in the char layer, and porosity evolution. The critical porosity value is used as a criterion for char layer porous structure failure under gas flow and particle erosion. This critical porosity value is obtained by fitting experimental parameters and surface porosity of the char layer. Linear ablation and mass ablation rates are confirmed with the critical porosity value. Results of linear ablation and mass ablation rate calculations generally coincide with experimental results, suggesting that the ablation analysis proposed in this paper can accurately reflect practical situations and that the physics and mathematics models built are accurate and reasonable.

Hormesis is induced in the red flour beetle Tribolium castaneum through ingestion of charred toast.

PubMed

Grünwald, Stefanie; Niedermeier, Janine; Wenzel, Uwe

2015-06-01

Charred foods are generally suspected to exert health threats by providing toxicants, such as acrylamide or polycyclic aromatic hydrocarbons. Using the red flour beetle Tribolium castaneum as a model organism, we tested its survival under heat stress in response to feeding charred toast. Survival of beetles was measured at 42 °C after a pre-feeding phase with flour enriched with increasing concentrations of charred toast. In order to assess the influence of key transcription factors for phase-I and phase-II xenobiotic metabolism, gene homologs for ahr and nrf-2, respectively, were knocked down by the use of RNA interference (RNAi). Beetles fed only charred toast died off much earlier than control beetles fed on flour, whereas beetles fed flour enriched with 5% charred toast survived significantly longer than the control. Both, ahr and nrf-2 proved essential in order to enable the increase in survival by the feeding of 5% charred toast. Moreover, functional loss of ahr and nrf-2 made the beetles hypersensitive versus the feeding of 100% charred toast. Finally, at the transcriptional level, it was shown that RNAi for ahr blocked the inducing activities of charred toast on nrf-2. Our studies suggest a hormetic response of the red flour beetle to feeding of charred toast that causes an increased stress resistance through the activation of ahr and nrf-2. Those adaptations, however, are saturable and accordingly the hormetic effects at increasing concentrations of the toxicants become expended.

Degradation of p-Nitrophenol by Lignin and Cellulose Chars: H2O2-Mediated Reaction and Direct Reaction with the Char.

PubMed

Yang, Jing; Pignatello, Joseph J; Pan, Bo; Xing, Baoshan

2017-08-15

Chars and other black carbons are reactive toward certain compounds. Such reactivity has been attributed to reduction of O 2 by persistent free radicals in the solid to H 2 O 2 , which then back-reacts with the solid to generate reactive oxygen species (ROS; especially HO • ). We studied the decomposition of p-nitrophenol (PNP) by pure lignin and cellulose chars aged in moist air or a vacuum at room temperature for up to a month. In air, the chars chemisorbed oxygen, a portion of which was liberated as H 2 O 2 when the char was submerged in water. The evolved H 2 O 2 was simultaneously decomposed by the char. PNP reacted predominantly in the sorbed state and only reduction products (phenol, catechol) were identified. Aging the char in air sharply (within hours) reduced H 2 O 2 -producing capacity and free radical concentration, but more gradually reduced PNP decay rate over the month-long period. PNP decay was only modestly suppressed (12-30%) by H 2 O 2 removal (catalase), and had little effect on the free radical signal (<6 radicals annihilated per 1000 PNP reacted). Contrasting with previous studies, the results show that direct reaction of PNP with char predominates over H 2 O 2 -dependent reactions, and the vast majority of direct-reacting sites are nonradical in character. Nonradical sites are also responsible in part for H 2 O 2 decomposition; in fact, H 2 O 2 pretreatment depleted PNP reactive sites. Lignin char was generally more reactive than cellulose char. The Fe impurity in lignin played no role. The results are relevant to the fate of pollutants in black carbon-rich environments and the use of carbons in remediation.

Integration of behavioral tests and biochemical biomarkers of terrestrial isopod Porcellio scaber (Isopoda, Crustacea) is a promising methodology for testing environmental safety of chars.

PubMed

Madžarić, Suzana; Kos, Monika; Drobne, Damjana; Hočevar, Matej; Jemec Kokalj, Anita

2018-03-01

We investigated how different carbonized materials, or chars (olive mill pomace biochar (BC) and urban greens pruning residues hydrochar (HC)) affect an important member of soil fauna, the terrestrial isopod Porcellio scaber. The selection behavior of isopods towards chars after a 48 h exposure was studied in (i) soil-char amended tests with single and multiple choices, and (ii) tests with chars offered as pure material. Finally, we exposed the isopods to char-amended soils for a period of 14 days to follow the effect on food consumption, body mass and activities of enzymes that are commonly altered upon stressor exposure (acetylcholinesterase, AChE, and glutathione S-transferase, GST). We showed that isopods are able to select between char amended and un-amended soil and different forms of char amendments: a clear preference for BC, and avoidance of HC were evidenced. The preferences remained the same when the chars were sterilized leading to the conclusion that initial microorganism composition was not the reason for selection, but selection was governed by other chars' physico-chemical properties. It remains to be elucidated which of these properties were the dominant reason for the selection. We also showed that isopods intentionally use BC as food at a similar rate to alder leaves. Medium-term exposure to HC resulted in adverse effects on isopods because it led to reduced feeding and growth, in addition to increasing GST activity, although no alterations in AChE activity were found. We suggest that behavioral tests with P. scaber could be used as a fast, reliable and economically feasible screening method for determining the safety of chars for the soil environment. Results represent significant contribution in the field of char toxicity testing, highlighting the importance of tests with isopods as important members of soil meso fauna, with the aim of influencing environmental policies and quality standards. Copyright © 2017 Elsevier Ltd. All rights reserved.

Production of carbon molecular sieves from Illinois coal

USGS Publications Warehouse

Lizzio, A.A.; Rostam-Abadi, M.

1993-01-01

Carbon molecular sieves (CMS) have become an increasingly important class of adsorbents for application in the separation of gas molecules that vary in size and shape. A study is in progress at the Illinois State Geological Survey to determine whether Illinois basin coals are suitable feedstocks for the production of CMS and to evaluate their potential application in gas separation processes of commercial importance. Chars were prepared from Illinois coal in a fixed-bed reactor under a wide range of heat treatment and activation conditions. The effects of various coal/char pretreatments, including coal demineralization, preoxidation, char activation, and carbon deposition, on the molecular sieve properties of the chars were also investigated. Chars with commercially significant BET surface areas of 1500 m2/g were produced by chemical activation using potassium hydroxide as the activant. These high-surface-area (HSA) chars had more than twice the adsorption capacity of commercial carbon and zeolite molecular sieves. The kinetics of adsorption of various gases, e.g., N2, O2, CO2, CH4, CO and H2, on these chars at 25??C was measured. The O2/N2 molecular sieve properties of one char prepared without chemical activation were similar to those of a commercial CMS. On the other hand, the O2/N2 selectivity of the HSA char was comparable to that of a commercial activated carbon, i.e., essentially unity. Carbon deposition, using methane as the cracking gas, increased the O2/N2 selectivity of the HSA char, but significantly decreased its adsorption capacity. Several chars showed good potential for efficient CO2/CH4 separation; both a relatively high CO2 adsorption capacity and CO2/CH4 selectivity were achieved. The micropore size distribution of selected chars was estimated by equilibrium adsorption of carbon dioxide, n-butane and iso-butane at O??C. The extent of adsorption of each gas corresponded to the effective surface area contained in pores with diameters greater than 3.3, 4.3 and 5.0 A??, respectively. Kinetic and equilibrium adsorption data provided complementary information on the molecular sieving capabilities and microstructure of the prepared chars. ?? 1993.

Effect of technical cashew nut shell liquid on rumen methane emission and lactation performance of dairy cows.

PubMed

Branco, A F; Giallongo, F; Frederick, T; Weeks, H; Oh, J; Hristov, A N

2015-06-01

Technical-grade cashew nut shell liquid (TCNSL) is a by-product of the cashew nut industry in tropical countries, and is known to exhibit a wide range of biological activities, including inhibitory effect against gram-positive bacteria. This study was conducted to investigate the effects of TCNSL (73.3% cardanol, 16.4% cardol, and 3.0% methylcardol) on rumen methane emission, nutrient digestibility, dry matter intake, and milk yield and composition in dairy cows. Eight multiparous Holstein cows were used in a crossover design trial with two 21-d experimental periods. The diet was based on corn silage and alfalfa haylage and was formulated to meet or exceed the energy and metabolizable protein requirements of the cows. Treatments were control (no TCNSL supplementation) or 30 g/cow per day of TCNSL. Rumen carbon dioxide emission was not affected by TCNSL. Treatment had no effect on methane emission (542 vs. 511±35.3 g/cow per day, respectively) and methane emission intensity (15.0 vs. 13.9±0.58 g/kg of energy-corrected milk, respectively) and tended to decrease methane emission per kilogram of dry matter intake (20.2 vs. 18.6±1.04 g/kg, respectively). Dry matter intake (average 26.9±1.00 kg/d), milk yield (40.0±1.73 kg/d), and milk composition were not different between treatments. The TCNSL had no effect on N losses in urine and feces and total-tract apparent digestibility of nutrients, except digestibility of neutral detergent fiber tended to be increased compared with the control. Plasma urea and glucose concentrations were not affected by TCNSL. Concentration of milk C18:0 tended to be decreased (17%) by TCNSL compared with the control. In this study, TCNSL did not alter absolute methane emission in the rumen, but tended to decrease it by 8% per kilogram of dry matter intake. The TCNSL had no effect on milk yield and composition in dairy cows. Copyright © 2015 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Development and Validation of a Reversed Phase HPLC Method for Determination of Anacardic Acids in Cashew (Anacardium occidentale) Nut Shell Liquid.

PubMed

Oiram Filho, Francisco; Alcântra, Daniel Barbosa; Rodrigues, Tigressa Helena Soares; Alexandre E Silva, Lorena Mara; de Oliveira Silva, Ebenezer; Zocolo, Guilherme Julião; de Brito, Edy Sousa

2018-04-01

Cashew nut shell liquid (CNSL) contains phenolic lipids with aliphatic chains that are of commercial interest. In this work, a chromatographic method was developed to monitor and quantify anacardic acids (AnAc) in CNSL. Samples containing AnAc were analyzed on a high-performance liquid chromatograph coupled to a diode array detector, equipped with a reversed phase C18 (150 × 4.6 mm × 5 μm) column using acetonitrile and water as the mobile phase both acidified with acetic acid to pH 3.0 in an isocratic mode (80:20:1). The chromatographic method showed adequate selectivity, as it could clearly separate the different AnAc. To validate this method, AnAc triene was used as an external standard at seven different concentrations varying from 50 to 1,000 μg mL-1. The Student's t-test and F-test were applied to ensure high confidence for the obtained data from the analytical calibration curve. The results were satisfactory with respect to intra-day (relative standard deviation (RSD) = 0.60%) and inter-day (RSD = 0.67%) precision, linearity (y = 2,670.8x - 26,949, r2 > 0.9998), system suitability for retention time (RSD = 1.02%), area under the curve (RSD = 0.24%), selectivity and limits of detection (19.8 μg mg-1) and quantification (60.2 μg mg-1). The developed chromatographic method was applied for the analysis of different CNSL samples, and it was deemed suitable for the quantification of AnAc.

SEM-EDX and isotope characterization of the organic sulfur in macerals and chars in Illinois Basin coals

USGS Publications Warehouse

Demir, I.; Harvey, R.D.; Hackley, Keith C.

1993-01-01

Two samples of the Herrin (Illinois No. 6) Coal and one sample of the Colchester (Illinois No. 2) Coal from the Illinois Basin were studied to evaluate the spatial distribution of organic sulfur within macerals occurring next to pyrite grains, both in the raw coal and their chars. The chars were produced by pyrolysing the coal at 250-550??C in a nitrogen atmosphere. Representative splits of the coals and their chars were mounted in epoxy and polished for optical microscopy and scanning electron microscopy-energy dispersive x-ray spectroscopy (SEM-EDX). Determinations of organic sulfur concentrations were made at 996 locations within macerals, mostly vitrinite, around 115 grains of pyrite and at 50 locations around 5 pores in chars. The pyrite considered here is restricted to the disseminated type within macerals. On the average, the organic sulfur content increased near pyrite grains after the coals were charred at 550??C, indicating that some of the pyritic sulfur released during charring was retained within the organic matrix rather than being emitted to the atmosphere. One of the coal samples and its chars were isotopically characterized by chemically separating the pyritic and organic sulfur fractions, followed by analyzing the isotopes of the sulfur forms with a Nuclide 6-60 ratio mass spectrometer. The sulfur isotope (??34S) data confirmed the movement of pyritic sulfur into the macerals after charring to 550??C. About 18% of the organic sulfur that remained in the 550??C char had originally been pyritic sulfur in the untreated coal. ?? 1993.

The effect of chars and their water extractable organic carbon (WEOC) fractions on atrazine adsorption-desorption processes

NASA Astrophysics Data System (ADS)

Cavoski, I.; Jablonowski, N.; Burauel, P.; Miano, T.

2012-04-01

Chars are carbonaceous material produced from different type of biomass by pyrolysis. They are known as highly effective adsorbents for atrazine therefore limiting its degradation and its diffusion into the aqueous phase. The aim of the present work is to study the effects of different chars and char's derived WEOC on atrazine sorption-desorption processes. The five chars been used in this study derived from: 1) fast pyrolysis from hard wood (FP1); 2) flash pyrolysis from soft wood (FP2); 3) slow pyrolysis from deciduous wood (CC); 4) gasification from deciduous wood (GC) and 5) the market, purchased as activated charcoal standard (AC). Short-term batch equilibration tests were conducted to assess the sorption-desorption behavior of 14C-labeled atrazine on the chars, with a special focus on the desorption behavior using successive dilution method with six consecutive desorption step. Chars and their WEOC were physically and chemically characterized. Results demonstrate that biomass and pyrolysis process used to produce chars affect their physical and chemical properties, and atrazine adsorption-desorption behavior. Atrazine desorption resulted from the positive and competitive interactions between WEOC and chars surfaces. WEOC pool play important role in atrazine adsorption-desorption behavior. FP1 and FP2 with higher concentration of WEOC showed higher desorption rates, whereas GC, CC and AC with insignificant WEOC concentration strongly adsorb atrazine with low desorption rates. According to our results, when high WEOC pools chars are concerned, an increase in atrazine desorption can be observed but further studies would help in confirming the present results.

Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils

USGS Publications Warehouse

Reeves, J. B.; McCarty, G.W.; Rutherford, D.W.; Wershaw, R. L.

2007-01-01

The objective of this research was to investigate the effect of charring on near infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred carbon in soils. Four materials (cellulose, lignin, pine bark and pine wood) and char from these materials created by charring for various durations (1 to 168 h) and at various temperatures (200 to 450??C) were studied. Near infrared spectra and measures of acidity (total acids, carboxylic acids, lactones and phenols as determined by titration) were available for 56 different samples (Not all samples charred at all temperatures/durations). Results showed spectral changes that varied with the material, temperature and duration of charring. Examination of spectra and correlation plots indicated that changes in the constituents of the materials in question, such as loss of OH groups in carbohydrates, rather than direct determination of typical products produced by charring, such as carboxylic acids, lactones and phenols, were the basis for the spectral changes. Finally, while the spectral changes resulting from charring appeared to be relatively unique to each material, PLS calibrations for total acids, carboxylic acids, lactones and phenols were successfully created (with R2 of 0.991, 0.943, 0.931 and 0.944, respectively) indicating that there is a sufficient commonality in the changes to develop calibrations without the need for unique calibrations for each specific set of charring conditions (i.e. material, temperature and time of heating). ?? IM Publications 2007.

Physicochemical properties and gasification reactivity of the ultrafine semi-char derived from a bench-scale fluidized bed gasifier

NASA Astrophysics Data System (ADS)

Zhang, Yukui; Zhang, Haixia; Zhu, Zhiping; Na, Yongjie; Lu, Qinggang

2017-08-01

Zhundong coalfield is the largest intact coalfield worldwide and fluidized bed gasification has been considered as a promising way to achieve its clean and efficient utilization. The purpose of this study is to investigate the physicochemical properties and gasification reactivity of the ultrafine semi-char, derived from a bench-scale fluidized bed gasifier, using Zhundong coal as fuel. The results obtained are as follows. In comparison to the raw coal, the carbon and ash content of the semi-char increase after partial gasification, but the ash fusion temperatures of them show no significant difference. Particularly, 76.53% of the sodium in the feed coal has released to the gas phase after fluidized bed gasification. The chemical compositions of the semi-char are closely related to its particle size, attributable to the distinctly different natures of diverse elements. The semi-char exhibits a higher graphitization degree, higher BET surface area, and richer meso- and macropores, which results in superior gasification reactivity than the coal char. The chemical reactivity of the semi-char is significantly improved by an increased gasification temperature, which suggests the necessity of regasification of the semi-char at a higher temperature. Consequently, it will be considered feasible that these carbons in the semi-char from fluidized bed gasifiers are reclaimed and reused for the gasification process.

Removal of lead (Pb2+) from aqueous medium by using chars from co-pyrolysis.

PubMed

Bernardo, Maria; Mendes, Sandra; Lapa, Nuno; Gonçalves, Margarida; Mendes, Benilde; Pinto, Filomena; Lopes, Helena; Fonseca, Isabel

2013-11-01

The effectiveness of chars from the co-pyrolysis of pine, used tires and plastic wastes for the removal of lead (Pb(2+)) from aqueous medium, was investigated. The chars were predominantly of macroporous nature, but the introduction of tires in the pyrolysis feedstock enhanced their mesoporous content as well as surface area. Pb(2+) sorption with the chars was a slow and unstable process in which sorption-desorption seems to be competing. The highest Pb(2+) removal (88%) was attained by the char resulting from the pyrolysis of a mixture composed by equal mass ratios of used tires and plastics, at 48 h of contact time. This char was also the one with the overall better performance for Pb(2+) sorption, achieving almost 100% of Pb(2+) removal on the study of the effect of adsorbent dose. Mixing the three raw materials for pyrolysis had no advantage for the resulting char concerning the removal efficiency of Pb(2+). The sorption mechanisms varied according to the pyrolysis feedstock: in chars from feedstock with pine, chemisorption involving complexation with oxygenated surface functional groups followed by cation exchange was the presumable mechanism. In tire rubber derived chars, cation exchange with Ca(2+), K(+), and Zn(2+) played the major role on Pb(2+) sorption. Copyright © 2013 Elsevier Inc. All rights reserved.

An evaluation of the efficacy of various coal combustion models for predicting char burnout

DOE Office of Scientific and Technical Information (OSTI.GOV)

McConnell, Josh; Goshayeshi, Babak; Sutherland, James C.

Coal combustion is comprised of several subprocesses including devolatilization and heterogeneous reactions of the coal char with O 2, CO 2, H 2O and potentially several other species. Much effort has been put forth to develop models for these processes which vary widely in both complexity and computational cost. This work investigates the efficacy of models for devolatilization and char reactions at either end of the complexity and cost spectrums for a range of particle sizes and furnace temperatures and across coal types. The overlap of simulated devolatilization and char consumption is also examined. In the gas phase, a detailedmore » kinetics model based on a reduced version of the GRI 3.0 mechanism is used. The Char Conversion Kinetics and an n th-order Langmuir-Hinshelwood models are considered for char oxidation. The Chemical Percolation and Devolatilization and a two-step model are considered for devolatilization. Results indicate that high-fidelity models perform better at representing particle temperature and mass data across a wide range of O 2 concentrations as well as coal types. A significant overlap in devolatilization and char consumption is observed for both char chemistry and devolatilization models.« less

A burnout prediction model based around char morphology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tao Wu; Edward Lester; Michael Cloke

Several combustion models have been developed that can make predictions about coal burnout and burnout potential. Most of these kinetic models require standard parameters such as volatile content and particle size to make a burnout prediction. This article presents a new model called the char burnout (ChB) model, which also uses detailed information about char morphology in its prediction. The input data to the model is based on information derived from two different image analysis techniques. One technique generates characterization data from real char samples, and the other predicts char types based on characterization data from image analysis of coalmore » particles. The pyrolyzed chars in this study were created in a drop tube furnace operating at 1300{sup o}C, 200 ms, and 1% oxygen. Modeling results were compared with a different carbon burnout kinetic model as well as the actual burnout data from refiring the same chars in a drop tube furnace operating at 1300{sup o}C, 5% oxygen, and residence times of 200, 400, and 600 ms. A good agreement between ChB model and experimental data indicates that the inclusion of char morphology in combustion models could well improve model predictions. 38 refs., 5 figs., 6 tabs.« less

An evaluation of the efficacy of various coal combustion models for predicting char burnout

DOE PAGES

McConnell, Josh; Goshayeshi, Babak; Sutherland, James C.

2016-11-22

Coal combustion is comprised of several subprocesses including devolatilization and heterogeneous reactions of the coal char with O 2, CO 2, H 2O and potentially several other species. Much effort has been put forth to develop models for these processes which vary widely in both complexity and computational cost. This work investigates the efficacy of models for devolatilization and char reactions at either end of the complexity and cost spectrums for a range of particle sizes and furnace temperatures and across coal types. The overlap of simulated devolatilization and char consumption is also examined. In the gas phase, a detailedmore » kinetics model based on a reduced version of the GRI 3.0 mechanism is used. The Char Conversion Kinetics and an n th-order Langmuir-Hinshelwood models are considered for char oxidation. The Chemical Percolation and Devolatilization and a two-step model are considered for devolatilization. Results indicate that high-fidelity models perform better at representing particle temperature and mass data across a wide range of O 2 concentrations as well as coal types. A significant overlap in devolatilization and char consumption is observed for both char chemistry and devolatilization models.« less

Comparative Performance of Three Magnesium Compounds on Thermal Degradation Behavior of Red Gum Wood.

PubMed

Wu, Yiqiang; Yao, Chunhua; Hu, Yunchu; Zhu, Xiaodan; Qing, Yan; Wu, Qinglin

2014-01-24

The effect of basic magnesium carbonate (BMC), magnesium hydroxide (MH), and magnesium chloride hydrate (MCH) on thermal degradation of red gum wood was studied using cone calorimetry, Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis, and X-ray diffraction (XRD) characterization. The results showed common fire retardation actions of the three compounds by releasing incombustible gas and/or water vapor to dilute combustible gas in the flaming zone, and by converting to MgO, which had a satisfactory protective wall effect on the wood. Individually, BMC absorbed heat from the wood at the pre-decomposition stage and, thus, slowed down wood pyrolysis process. It slightly increased the char yield by charring in both the charring stage and the char calcination stage. MH lost water at about 270 °C, close to the temperature at which wood thermally degraded. MH rendered wood char quickly, and the compact char layer impeded further carbonization and burning of inner wood. MCH promoted charring with Mg 2+ as a Lewis acid, and increased wood char yield. MCH also released Cl· free radical and HCl at 167 °C, which easily coordinated with combustion reaction radical, and slowed down, even inhibited, the combustion chain reaction.

Comparative Performance of Three Magnesium Compounds on Thermal Degradation Behavior of Red Gum Wood

PubMed Central

Wu, Yiqiang; Yao, Chunhua; Hu, Yunchu; Zhu, Xiaodan; Qing, Yan; Wu, Qinglin

2014-01-01

The effect of basic magnesium carbonate (BMC), magnesium hydroxide (MH), and magnesium chloride hydrate (MCH) on thermal degradation of red gum wood was studied using cone calorimetry, Thermogravimetric-differential scanning calorimetry (TG-DSC) analysis, and X-ray diffraction (XRD) characterization. The results showed common fire retardation actions of the three compounds by releasing incombustible gas and/or water vapor to dilute combustible gas in the flaming zone, and by converting to MgO, which had a satisfactory protective wall effect on the wood. Individually, BMC absorbed heat from the wood at the pre-decomposition stage and, thus, slowed down wood pyrolysis process. It slightly increased the char yield by charring in both the charring stage and the char calcination stage. MH lost water at about 270°C, close to the temperature at which wood thermally degraded. MH rendered wood char quickly, and the compact char layer impeded further carbonization and burning of inner wood. MCH promoted charring with Mg2+ as a Lewis acid, and increased wood char yield. MCH also released Cl· free radical and HCl at 167°C, which easily coordinated with combustion reaction radical, and slowed down, even inhibited, the combustion chain reaction. PMID:28788480

Improved lignin pyrolysis for phenolics production in a bubbling bed reactor--Effect of bed materials.

PubMed

Li, Dongbing; Briens, Cedric; Berruti, Franco

2015-01-01

Lignin pyrolysis was studied in a bubbling fluidized bed reactor equipped with a fractional condensation train, using nitrogen as the fluidization gas. The effect of different bed materials (silica sand, lignin char, activated lignin char, birch bark char, and foamed glass beads) on bio-oil yield and quality was investigated for a pyrolysis temperature of 550 °C. Results how that a bed of activated lignin char is preferable to the commonly used silica sand: pyrolysis of Kraft lignin with a bed of activated lignin char not only provides a pure char product, but also a higher dry bio-oil yield (with a relative increase of 43%), lower pyrolytic water production, and better bio-oil quality. The bio-oil obtained from Kraft lignin pyrolysis with a bed of activated lignin char has a lower average molecular weight, less tar, more phenolics, and less acidity than when sand is used as bed material. Copyright © 2015 Elsevier Ltd. All rights reserved.

Microbial oxidation of pyrrhotites in coal chars

USGS Publications Warehouse

Miller, K.W.; Risatti, J.B.

1988-01-01

The ability of Thiobacillus ferrooxidans to oxidize pyrrhotite minerals occurring in coal chars was investigated, to evaluate the feasibility of microbial char desulphurization. Bio-oxidation of pyrrhotites in chars produced by two different processes was demonstrated conclusively. Microbial removal of sulphur from a char and its parent coal proceeded at the rate of 3.5% and 12% day-1, respectively with a total of 48% and 81% removal after 27 days. The pH of shake flask cultures containing the coal dropped naturally to a final value of 2.2, while the pH of cultures containing the corresponding char rose and had to be lowered artificially with additional acid. Amending char cultures with elemental sulphur to increase acidity upon bio-oxidation and prevent precipitation of ferric iron was successful; however, the extent of pyrrhotite removal, as demonstated by X-ray diffraction analysis, was not improved. As yet, there is no explanation for the failure of microbial removal of pyrrhotitic sulphur to go to completion. ?? 1988.

The thermal and mechanical properties of a low density elastomeric ablation material

NASA Technical Reports Server (NTRS)

Engelke, W. T.; Robertson, R. W.; Bush, A. L.; Pears, C. D.

1973-01-01

Thermal and mechanical properties data were obtained for a low density elastomeric resin based ablation material with phenolic-glass honeycomb reinforcement. Data were obtained for the material in the charred and uncharred state. Ablation material specimens were charred in a laboratory furnace at temperatures in the range from 600 K to 1700 K to obtain char specimens representative of the ablation char layer formed during reentry. These specimens were then used to obtain effective thermal conductivity, heat capacity, porosity, and permeability data at the char formation temperature. This provided a boxing of the data which enables the prediction of the transient response of the material during ablation. Limited comparisons were made between the furnace charred specimens and specimens which had been exposed to simulated reentry conditions.

Influence of carbonization conditions on the pyrolytic carbon deposition in acacia and eucalyptus wood chars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, M.; Gupta, R.C.

1997-04-01

The amount of deposited pyrolytic carbon (resulting from the cracking of volatile matter) was found to depend on wood species and carbonization conditions, such as temperature and heating rate. Maximum pyrolytic carbon deposition in both the acacia and eucalyptus wood chars has been observed at a carbonization temperature of 800 C. Rapid carbonization (higher heating rate) of wood significantly reduces the amount of deposited pyrolytic carbon in resulting chars. Results also indicate that the amount of deposited pyrolytic carbon in acacia wood char is less than that in eucalyptus wood char.

Using environmental chemistry technologies for the removal of arsenic from drinking water, and fat and oil based phase change materials for thermal energy storage

NASA Astrophysics Data System (ADS)

Sutterlin, William R.

The first four chapters of this dissertation involve the removal of arsenic from drinking water. Various forms of a macroporous char prepared by partial gasification of subbituminous coal were studied for removal of arsenic(V) and arsenic(III) from water. In increasing order of effectiveness for arsenic(V) removal were untreated char < acid-washed char < char impregnated with iron(III) and gasified < char impregnated with FeS < char impregnated with iron(III) hydroxide < char coated with zerovalent iron < char impregnated with iron(III) oxide. A mass of 10 g of iron(III) oxide char removed arsenic(V) and arsenic(III) from 10,000 mL of water containing 500 micrograms/L of arsenic to levels below 10 micrograms/L. The capacity of the solid to remove arsenic was significantly diminished in water containing 4 mg/L of phosphate. An electrical current passed over 4 g of iron(III) oxide char in a column enabled removal of arsenic(III) from 14,000 mL of 500 micrograms/L arsenic(III) to below 10 micrograms/liter and at significantly higher flow rates than could be employed without electrolysis. The fifth chapter in this dissertation focused on the retention of organics onto a char/concrete pellet. A mixture of naphthalene, pentachlorophenol, biphenyl, toluene, tetrachloroethane, and chlorobenzene were impregnated into a loose granular char, a char/concrete pellet and a sand/concrete pellet. The results showed that the char/concrete pellet had significant advantages over the other forms. Chapters 6--9 focus on phase change materials (PCMs). These PCMs are made from fats and oils. PCMs are perhaps the only proven method that can provide near 100% thermal energy storage. In chapter 7 a novel HPLC method was developed that could provide quantification and qualification of the resulting products formed after PCM synthesis. In chapter 8 thermal cycling studies were conducted on the fat and oil based PCMs. These thermal cycle demonstrated that these PCMs were capable of going through a multitude of freeze and melt processes with little to no degradation if the appropriate preservative is used. Finally in chapter 9 the PCM is incorporated into a simulated 100 th scale house. A traditional freon based evaporator is used to freeze the PCM at night during electrical-off-peak hours. During the peak-load of the day the evaporator is turned off and the PCM provides the cooling for the house.

Life-Cycle Analysis of Greenhouse Gas Emissions and Water Consumption – Effects of Coal and Biomass Conversion to Liquid Fuels as Analyzed with the GREET Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Qianfeng; Cai, Hao; Han, Jeongwoo

The vast reserves of coal in the U.S. provide a significant incentive for the development of processes for coal conversion to liquid fuels (CTL). Also, CTL using domestic coal can help move the U.S. toward greater energy independence and security. However, current conversion technologies are less economically competitive and generate greater greenhouse gas (GHG) emissions than production of petroleum fuels. Altex Technologies Corporation (Altex, hereinafter) and Pennsylvania State University have developed a hybrid technology to produce jet fuel from a feedstock blend of coal and biomass. Collaborating with Altex, Argonne National Laboratory has expanded and used the Greenhouse gases, Regulatedmore » Emissions, and Energy use in Transportation (GREET®) model to assess the life-cycle GHG emissions and water consumption of this hybrid technology. Biomass feedstocks include corn stover, switchgrass, and wheat straw. The option of biomass densification (bales to pellets) is also evaluated in this study. The results show that the densification process generates additional GHG emissions as a result of additional biomass process energy demand. This process coproduces a large amount of char, and this study investigates two scenarios to treat char: landfill disposal (Char-LF) and combustion for combined heat and power (CHP). Since the CHP scenarios export excess heat and electricity as coproducts, two coproduct handling methods are used for well-to-wake (WTWa) analysis: displacement (Char-CHP-Disp) and energy allocation (Char-CHP-EnAllo). When the feedstock contains 15 wt% densified wheat straw and 85 wt% lignite coal, WTWa GHG emissions of the coal-and-biomass-to-liquid pathways are 116, 97, and 137 gCO2e per megajoule (MJ) under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively, as compared to conventional jet fuel production at 84 gCO2e/MJ. WTWa water consumption values are 0.072, -0.046, and 0.044 gal/MJ for Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo, respectively, as compared to conventional jet fuel production at 0.028 gal/MJ. To reach the break-even point of 84 gCO2e/MJ, under the assumptions of constant product yields and energy demands regardless of the share of biomass and coal feedstocks, 31 wt%, 23 wt%, and 53 wt% of the feedstock blend need to be biomass under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively.« less

The effects of the conditions of char formation on the physical properties of charred phenolic-nylon

NASA Technical Reports Server (NTRS)

Smyly, E. D.; Pears, C. D.

1972-01-01

A study was made of the effects of the conditions of char formation on the physical properties of charred phenolic nylon of 0.577 gm/cu cm density. It was found that the thermal conductivity and several of the monitors correlate well with degradation conditions. The monitors included electrical resistivity, sonic velocity, porosity, lattice spacing and crystallite size.

How do molecular marker patterns of BC change at increasing age of chars?

NASA Astrophysics Data System (ADS)

Schneider, M. P. W.; Hilf, M.; Schmidt, M. W. I.

2009-04-01

Black carbon (BC) is considered to be a relatively stable form of organic carbon. However, previous results have shown that the physical and chemical properties of BC can vary considerably with formation temperature. Thus, to understand the long-term carbon sink potential of BC there is increasing interest to gain more information about i) the conditions under which BC was formed, and ii) the resulting degradability of BC under natural conditions. In a first step, we synthesised chars from two different sources of biomass (chestnut wood, rice straw) under well-defined conditions as model substances to analyse the changes in their molecular structure at increasing formation temperature. Results are presented obtained from a set of laboratory produced char samples pyrolysed at increasing temperatures with a high resolution between 200 and 1000 °C. The chars were characterized by a molecular marker method for pyrogenic carbon quantification, which additionally provides information about the degree of condensation of chars. At temperatures between 275 and 500°C, which typically are observed during wildfires and thus are relevant for natural char formation, the molecular marker pattern of the chars remains almost constant. In a next step, we analysed changes in the molecular marker patterns of chars from a chronosequence, with BC deposited between 0 and 100 years ago. Based on the data obtained from the laboratory char series, we compare changes in the molecular marker patterns of the chars from the chronosequence over time. These results show if less condensed forms of BC are degraded preferentially and more condensed, aromatic backbone of BC becomes enriched in the soils with time of degradation. Our results provide information about the fate of BC in the environment, which has important implications in the context of carbon sequestration strategies.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tam, M.S.; Antal, M.J. Jr.

A novel, three-step process for the production of high-quality activated carbons from macadamia nut shell and coconut shell charcoals is described. In this process the charcoal is (1) heated to a high temperature (carbonized), (2) oxidized in air following a stepwise heating program from low (ca. 450 K) to high (ca. 660 K) temperatures (oxygenated), and (3) heated again in an inert environment to a high temperature (activated). By use of this procedure, activated carbons with surface areas greater than 1,000 m{sub 2}/g are manufactured with an overall yield of 15% (based on the dry shell feed). Removal of carbonmore » mass by the development of mesopores and macropores is largely responsible for increases in the surface area of the carbons above 600 m{sub 2}/g. Thus, the surface area per gram of activated carbon can be represented by an inverse function of the yield for burnoffs between 15 and 60%. These findings are supported by mass-transfer calculations and pore-size distribution measurements. A kinetic model for gasification of carbon by oxygen, which provides for an Eley-Rideal type reaction of a surface oxide with oxygen in air, fits the measured gasification rates reasonably well over the temperature range of 550--660 K.« less

[Dynamics of the parasite fauna of various forms of chars, salvelinus alpinus L., of the Lake Azabach'e basin].

PubMed

Butorina, T E

1975-01-01

The paper deals with age changes in the parasite fauna of different intraspecific forms of chars. It is shown that this year brood and yearlings of predatory, benthofagous, stream and anadromous chars up to 10 cm in length have a similar parasite fauna. During the second year of life the chars come to different feeding; correspondingly changes their parasite fauna which differs considerably in the above forms of chars. Two groups of parasites are distinguished the infection with which increases and decreases with the age of fishes. Observations were carried out on the life cycles, developmental and maturation periods of some parasites of chars. Biological peculiarities of some mixosporidia are studied. A shift in the developmental periods of helminths is noted as compared to those from the European part of the USSR.

Evaluation of char combustion models: measurement and analysis of variability in char particle size and density

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maloney, Daniel J; Monazam, Esmail R; Casleton, Kent H

Char samples representing a range of combustion conditions and extents of burnout were obtained from a well-characterized laminar flow combustion experiment. Individual particles from the parent coal and char samples were characterized to determine distributions in particle volume, mass, and density at different extent of burnout. The data were then compared with predictions from a comprehensive char combustion model referred to as the char burnout kinetics model (CBK). The data clearly reflect the particle- to-particle heterogeneity of the parent coal and show a significant broadening in the size and density distributions of the chars resulting from both devolatilization and combustion.more » Data for chars prepared in a lower oxygen content environment (6% oxygen by vol.) are consistent with zone II type combustion behavior where most of the combustion is occurring near the particle surface. At higher oxygen contents (12% by vol.), the data show indications of more burning occurring in the particle interior. The CBK model does a good job of predicting the general nature of the development of size and density distributions during burning but the input distribution of particle size and density is critical to obtaining good predictions. A significant reduction in particle size was observed to occur as a result of devolatilization. For comprehensive combustion models to provide accurate predictions, this size reduction phenomenon needs to be included in devolatilization models so that representative char distributions are carried through the calculations.« less

NMR studies on the chemical alteration of soil organic matter precursors during controlled charring

NASA Astrophysics Data System (ADS)

Knicker, Heike

2010-05-01

Beside the production of volatiles, vegetation fire transforms various amounts of labile organic components into recalcitrant dark colored and highly aromatic structures. They are incorporated into soils and are assumed to represent an important sink within the global carbon cycle. In order to elucidate the real importance of PyOM as a C-sink, a good understanding of its chemistry is crucial. Although several 'Black Carbon' (BC) models are reported, a commonly accepted view of the chemistry involved in its formation is still missing. Its biogeochemical recalcitrance is commonly associated with a highly condensed aromatic structure. However, recent studies indicated that this view may be oversimplified for PyOM derived from vegetation fire. In order to bring some more light on the structural properties of PyOM produced during vegetation fire, charred plant residues and model chars derived from typical plant macromolecules (casein, cellulose, lignin and condensed tannins) were subjected to controlled charring under oxic conditions (350°C and 450°C) and then characterized by nuclear magnetic resonance (NMR) spectroscopy and elemental analysis. Subsequently, the chemical features of the PyOM were related to its chemical recalcitrance as determined by chemical oxidation with acid potassium dichromate. Charring cellulose (350°C, 8 min) yielded in a low C-recovery (11%). Treating casein in the same way resulted in a survival of 62% of its C and 46% of its N. Comparable high C-recoveries are reported for lignin. After charring Lolium perenne, 34% of its N and C were recovered. NMR-spectroscopic studies revealed that for this sample most of the charred N and C occurred in pyrrole-type structures. Our studies further indicate that the aromatic skeleton of char accumulating after a vegetation fire must contain remains of the lignin backbone and considerable contributions of furans and anhydrosugars from thermally altered cellulose. Enhancing the temperature during the charring of casein to 450°C decreased the C and N recovery to 30% and 23%, respectively. Comparably the C, O and H recovery were also reduced in the cellulose char, but to a considerably higher extent. These changes went along with a further augmentation of the relative contribution of aromatic C. Increased C, H and O losses were also observed for charring of lignin at higher temperature, although they were smaller than those observed for casein and cellulose. The higher temperature considerably altered the chemistry of the lignin char. The atomic H/C ratio, however, remained above 0.5 showing that in average at least every second C is protonated. Subjecting the produced chars to chemical oxidation with acid potassium dichromate clearly demonstrated that the resistance of the casein chars against heat is not necessarily related to chemical recalcitrance. For the char produced at 350°C, only 13% of the C and N remained in the oxidation residues, whereas for that produced at 450°C this value increased to 80%. In contrast, both cellulose chars showed high chemical resistance with a C-survival of more than 80%. Comparatively, the C and N recalcitrance in the grass chars increased with temperature, whereas, the burned wood residues (350°C) suffered an almost complete oxidation. The chars from condensed tannins, on the other hand showed a high chemical resistance independently from the production temperature. In summary, this study confirmed that the thermal, chemical and biological recalcitrance of biochars is related to their chemical structures and N-contents, which on the other hand depend on the source and the respective charring conditions. The resulting high chemical variability of biochars is in accordance with the concept of BC as a continuum and explains the high discrepancy among BC quantifications obtained with common approaches assuming BC as a highly condensed polyaromatic network.

Manganese phytate dotted polyaniline shell enwrapped carbon nanotube: Towards the reinforcements in fire safety and mechanical property of polymer.

PubMed

Wang, Junling; Zhan, Jing; Mu, Xiaowei; Jin, Xin; Chu, Fukai; Kan, Yongchun; Xing, Weiyi

2018-06-19

High fire hazard of epoxy resin (EP) has been an unavoidable obstruction on its wide application. Here, a manganese phytate dotted polyaniline shell enwrapped carbon nanotube (MPCNT) is facilely constructed and employed as flame retardant for EP. By adding 4.0 wt% MPCNT, the peak heat release rate, total heat release values, peak CO yields and total CO yields are decreased by 27.2, 12.3, 44.8, and 23.3%, respectively. The decreased absorbance intensity of toxic aromatic volatiles is also observed. Then, a tripartite cooperative flame retardant mechanism (a continuous barrier network, catalytic charring function of phytate, and catalytic activity of MnP/C system) is proposed. Furthermore, the storage modulus of EP composites with 2.0 and 4.0 wt% MPCNT are increased by 23.0 and 25.8% at 40 °C, respectively. Thus, the simultaneous reinforcements in fire safety and mechanical performance of EP are successfully achieved. This work may represent a significant step forward in the facile construction of functionalized carbon materials for achieving their whole potentials in polymer-matrix composite. Copyright © 2018. Published by Elsevier Inc.

Effects of retorting factors on combustion properties of shale char. 3. Distribution of residual organic matters.

PubMed

Han, Xiangxin; Jiang, Xiumin; Cui, Zhigang; Liu, Jianguo; Yan, Junwei

2010-03-15

Shale char, formed in retort furnaces of oil shale, is classified as a dangerous waste containing several toxic compounds. In order to retort oil shale to produce shale oil as well as treat shale char efficiently and in an environmentally friendly way, a novel kind of comprehensive utilization system was developed to use oil shale for shale oil production, electricity generation (shale char fired) and the extensive application of oil shale ash. For exploring the combustion properties of shale char further, in this paper organic matters within shale chars obtained under different retorting conditions were extracted and identified using a gas chromatography-mass spectrometry (GC-MS) method. Subsequently, the effects of retorting factors, including retorting temperature, residence time, particle size and heating rate, were analyzed in detail. As a result, a retorting condition with a retorting temperature of 460-490 degrees C, residence time of <40 min and a middle particle size was recommended for both keeping nitrogenous organic matters and aromatic hydrocarbons in shale char and improving the yield and quality of shale oil. In addition, shale char obtained under such retorting condition can also be treated efficiently using a circulating fluidized bed technology with fractional combustion. (c) 2009 Elsevier B.V. All rights reserved.

Feasibility of mercury removal from simulated flue gas by activated chars made from poultry manures.

PubMed

Klasson, K Thomas; Lima, Isabel M; Boihem, Larry L; Wartelle, Lynda H

2010-12-01

Increased emphasis on reduction of mercury emissions from coal fired electric power plants has resulted in environmental regulations that may in the future require application of activated carbons as mercury sorbents for mercury removal. At the same time, the quantity of poultry manure generated each year is large and technologies that take advantage of the material should be explored. The purpose of the work was to obtain preliminary data to investigate if activated chars made from different poultry manures could adsorb mercury from simulated flue gas. In laboratory experiments, activated chars made from chicken cake and litter removed mercury from the gas as well as a commercial alternative. It was also found that acid-washing these chars after activation may improve pore structure but does not influence the mercury removal efficiency. Activated chars were also made from turkey cake and litter. These raw materials produced activated chars with similar pore structure as those made from chicken manure, but they did not adsorb mercury as well. Acid-washing the turkey manure-based chars improved their performance, but this step would add to the cost of production. Preliminary evaluations suggest that unwashed activated chars may cost as little as $0.95/kg to produce. Published by Elsevier Ltd.

Combustion of char from plastic wastes pyrolysis

NASA Astrophysics Data System (ADS)

Saptoadi, Harwin; Rohmat, Tri Agung; Sutoyo

2016-06-01

A popular method to recycle plastic wastes is pyrolysis, where oil, gas and char can be produced. These products can be utilized as fuels because they are basically hydrocarbons. The research investigates char properties, including their performance as fuel briquettes. There are 13 char samples from PE (Polyethylene) pyrolyzed at temperatures of around 450 °C, with and without a catalyst. Some of the samples were obtained from PE mixed with other types, such as Polystyrene (PS), Polypropylene (PP), Polyethylene Terephthalate (PET), and Others. Char properties, such as moisture, ash, volatile matter, and fixed carbon contents, are revealed from the proximate analysis, whereas calorific values were measured with a bomb calorimeter. Briquettes are made by mixing 4 g of char with 0.5 - 1 g binder. Briquettes are hollow cylinders with an outer and inner diameter of around 1.75 cm and 0.25 cm, respectively. Combustion is carried out in a furnace with wall temperatures of about 230°C and a constant air velocity of 0.7 m/s. Five out of 13 char briquettes are not feasible because they melt during combustion. Briquettes made from 100% PE wastes burn in substantially shorter duration than those from mixed plastic wastes. Char #1 and #5 are excellent due to their highest energy release, whereas #10 show the worst performance.

Combustion and gasification characteristics of chars from four commercially significant coals of different rank. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nsakala, N.Y.; Patel, R.L.; Lao, T.C.

1982-09-01

The combustion and gasification kinetics of four size graded coal chars were investigated experimentally in Combustion Engineering's Drop Tube Furnace System (DTFS). The chars were prepared in the DTFS from commercially significant coals representing a wide range of rank; these included a Pittsburgh No. 8 Seam hvAb coal, an Illinois No. 6 Seam hvCb coal, a Wyoming Sub C, and a Texas Lignite A. Additionally, a number of standard ASTM and special bench scale tests were performed on the coals and chars to characterize their physicochemical properties. Results showed that the lower rank coal chars were more reactive than themore » higher rank coal chars and that combustion reactions of chars were much faster than the corresponding gasification reactions. Fuel properties, temperature, and reactant gas partial pressure had a significant influence on both combustion and gasification, and particle size had a mild but discernible influence on gasification. Fuel reactivities were closely related to pore structure. Computer simulation of the combustion and gasification performances of the subject samples in the DTFS supported the experimental findings.« less

Co-gasification of coal and biomass: Synergy, characterization and reactivity of the residual char.

PubMed

Hu, Junhao; Shao, Jingai; Yang, Haiping; Lin, Guiying; Chen, Yingquan; Wang, Xianhua; Zhang, Wennan; Chen, Hanping

2017-11-01

The synergy effect between coal and biomass in their co-gasification was studied in a vertical fixed bed reactor, and the physic-chemical structural characteristics and gasification reactivity of the residual char obtained from co-gasification were also investigated. The results shows that, conversion of the residual char and tar into gas is enhanced due to the synergy effect between coal and biomass. The physical structure of residual char shows more pore on coal char when more biomass is added in the co-gasification. The migration of inorganic elements between coal and biomass was found, the formation and competitive role of K 2 SiO 3 , KAlSiO 4 , and Ca 3 Al 2 (SiO 4 ) 3 is a mechanism behind the synergy. The graphization degree is enhanced but size of graphite crystallite in the residual char decreases with biomass blending ratio increasing. TGA results strongly suggest the big difference in the reactivity of chars derived from coal and biomass in spite of influence from co-gasification. Copyright © 2017 Elsevier Ltd. All rights reserved.

Studies on biomass char gasification and dynamics

NASA Astrophysics Data System (ADS)

You, Zhanping; You, Shijun; Ma, Xiaoyan

2018-01-01

The gasification performances of two kinds of biomass char by experiment methods are studied, including conversion rate and gasification gas component with temperature and time. Experimental results show that gasification temperature has important effects on the conversion rate and gas component. In the range of experimental temperature, char conversion rates are no more than 30.0%. The apparent activation energies and apparent reaction frequency factors of two biomass chars are obtained through kinetic studies.

Characteristics of coking coal burnout

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakamura, M.; Bailey, J.G.

An attempt was made to clarify the characteristics of coking coal burnout by the morphological analysis of char and fly ash samples. Laboratory-scale combustion testing, simulating an ignition process, was carried out for three kinds of coal (two coking coals and one non-coking coal for reference), and sampled chars were analyzed for size, shape and type by image analysis. The full combustion process was examined in industrial-scale combustion testing for the same kinds of coal. Char sampled at the burner outlet and fly ash at the furnace exit were also analyzed. The difference between the char type, swelling properties, agglomeration,more » anisotropy and carbon burnout were compared at laboratory scale and at industrial scale. As a result, it was found that coking coals produced chars with relatively thicker walls, which mainly impeded char burnout, especially for low volatile coals.« less

Adsorption mechanism for xanthene dyes to cellulose granules.

PubMed

Tabara, Aya; Yamane, Chihiro; Seguchi, Masaharu

2012-01-01

The xanthene dyes, erythrosine, phloxine, and rose bengal, were adsorbed to charred cellulose granules. The charred cellulose granules were preliminarily steeped in ionic (NaOH, NaCl, KOH, KCl, and sodium dodecyl sulfate (SDS)), nonionic (glucose, sucrose, and ethanol), and amphipathic sucrose fatty acid ester (SFAE) solutions, and adsorption tests on the dye to the steeped and charred cellulose granules were conducted. Almost none of the dye was adsorbed when the solutions of ionic and amphipathic molecules were used, but were adsorbed in the case of steeping in the nonionic molecule solutions. Thin-layer chromatography (TLC) and the Fourier transform infra-red (FT-IR) profiles of SFAE which was adsorbed to the charred cellulose granules and extracted by ethyl ether suggested the presence of hydrophobic sites on the surface of the charred cellulose granules. We confirmed that the xanthene dyes could bind to the charred cellulose granules by ionic and hydrophobic bonds.

Tyre char preparation from waste tyre rubber for dye removal from effluents.

PubMed

Mui, Edward L K; Cheung, W H; McKay, Gordon

2010-03-15

A number of chars from waste tyre rubber were prepared by carbonisation at 673-1173 K. The effects of holding time, heating rate and particle size on the textural characteristics and elemental composition of the resultant chars were investigated. It was demonstrated that temperatures over 773 K did not have a significant improvement on the total surface area but resulted in lower char yields following increased aromatisation. Modelling of dye adsorption isotherms showed that the Redlich-Peterson expression yields the best-fit between experimental and predicted data. Furthermore, for a larger sized dye like Acid Yellow 117 (MW=848 g/mol), the amount adsorbed by the tyre char is not directly proportional to the total surface area when compared with a commercial carbon, revealing that factors other than total surface area are involved in the adsorption potential of the tyre chars. (c) 2009 Elsevier B.V. All rights reserved.

Low-calorie bread baked with charred cellulose granules and wheat flour to eliminate toxic xanthene food dye in the alimentary canal.

PubMed

Tabara, Aya; Yamane, Chihiro; Seguchi, Masaharu

2012-01-01

We baked low-calorie bread by mixing charred cellulose granules with wheat flour, using the charred cellulose granules to eliminate toxic xanthene food dyes contained in processed foods from the alimentary canal. The size of the charred cellulose granules played an important role in determining good breadmaking properties in respect of the bread height (mm) and specific volume (SV, cm3/g). Charred cellulose granules with a diameter above 270 μm were blended with wheat flour at 10% to obtain bread with a lower caloric content (1020 kcal/gram of bread) than the control bread (1126 kcal) made solely from wheat flour. The charred cellulose granules taken out from the bread adsorbed toxic xanthene food dyes at around pH 6.5, such that toxic food dyes taken into the alimentary canal were excreted in the feces with the non-digestible cellulose granules.

Influence of pressure on pyrolysis of black liquor: 2. Char yields and component release.

PubMed

Whitty, Kevin; Kullberg, Mika; Sorvari, Vesa; Backman, Rainer; Hupa, Mikko

2008-02-01

This is the second in a series of papers concerning the behavior of black liquor during pyrolysis at elevated pressures. Two industrial black liquors were pyrolyzed under pressurized conditions in two laboratory-scale devices, a pressurized single-particle reactor and a pressurized grid heater. Temperatures ranging between 650 and 1100 degrees C and pressures in the range 1-20 bar were studied. Char yields were calculated and based on analysis of some of the chars the fate of carbon, sodium, potassium and sulfur was determined as a function of pyrolysis pressure. At temperatures below 800 degrees C little variation in char yield was observed at different pressures. At higher temperatures char yield increased with pressure due to slower decomposition of sodium carbonate. For the same reason, sodium release decreased with pressure. Sulfur release, however, increased with pressure primarily because there was less opportunity for its capture in the less-swollen chars.

Structural evolution of maize stalk/char particles during pyrolysis.

PubMed

Fu, Peng; Hu, Song; Sun, Lushi; Xiang, Jun; Yang, Tao; Zhang, Anchao; Zhang, Junying

2009-10-01

The structural evolution characteristics of maize stalk/char particles during pyrolysis were investigated. The char was prepared by pyrolyzing at temperatures ranging from 200 to 900 degrees C. Maize stalk and chars were characterized by thermogravimetric analysis, ultimate analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), helium density measurement and N(2) adsorption/desorption method. The char yield decreased rapidly with increasing temperature until 400 degrees C. As temperature increased, the char became progressively more aromatic and carbonaceous. The hydroxyl, aliphatic C-H, carbonyl and olefinic C=C groups were lost at high temperatures. Below 500 degrees C, the removal of volatile matter made pore opening. High temperatures led to the occurrence of softening, melting, fusing and carbon structural ordering. The aromatization process started at approximately 350 degrees C and continued to higher temperatures. The shrinkage of carbon structure occurred above 500 degrees C, which was concurrent with the aromatization process.

Mid-infrared diffuse reflectance spectroscopic examination of charred pine wood, bark, cellulose, and lignin: Implications for the quantitative determination of charcoal in soils

USGS Publications Warehouse

Reeves, J. B.; McCarty, G.W.; Rutherford, D.W.; Wershaw, R. L.

2008-01-01

Fires in terrestrial ecosystems produce large amounts of charcoal that persist in the environment and represent a substantial pool of sequestered carbon in soil. The objective of this research was to investigate the effect of charring on mid-infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred organic matter in soils. Four materials (cellulose, lignin, pine bark, and pine wood) and char from these materials, created by charring for various durations (1 to 168 h) and at various temperatures (200 to 450 ??C), were studied. Mid-infrared spectra and measures of acidity (total acids, carboxylic acids, lactones, and phenols as determined by titration) were determined for 56 different samples (not all samples were charred at all temperatures/durations). Results showed spectral changes that varied with the material, temperature, and duration of charring. Despite the wide range of spectral changes seen with the differing materials and length/temperature of charring, partial least squares calibrations for total acids, carboxylic acids, lactones, and phenols were successfully created (coefficient of determination and root mean squared deviation of 0.970 and 0.380; 0.933 and 0.227; 0.976 and 0.120; and 0.982 and 0.101 meq/g, respectively), indicating that there is a sufficient commonality in the changes to develop calibrations without the need for unique calibrations for each specific material or condition of char formation. ?? 2008 Society for Applied Spectroscopy.

Pyrolysis of flax straw: Characterization of char, liquid, and gas as fuel

NASA Astrophysics Data System (ADS)

Tushar, Mohammad Shahed Hasan Khan

The demand for energy continues to outstrip its supply and necessitates the development of renewable energy options. Biomass has been recognized as a major renewable energy source to supplement the declining fossil fuel source of energy. It is the most popular form of renewable energy and, currently, biofuel production is becoming more promising. Being carbon neutral, readily available, and low in sulphur content makes biomass a very promising source of renewable energy. In the present research, both the isothermal and non-isothermal pressurized pyrolysis of flax straw is studied for the first time. In case of isothermal pyrolysis, the influence of pyrolysis temperature and reaction time on char yield and morphology was investigated. The applied pyrolysis temperature was varied between 300 and 500°C. The reaction time was varied from 15 to 60 min. The char yield was found to decrease as pyrolysis temperature and reaction time increased. The char structure and surface morphology were thoroughly investigated by means of x-ray diffraction (XRD), temperature-programmed oxidation (TPO), and scanning electron microscopy (SEM). The degree of porosity and graphitization increased as pyrolysis temperature and time increased. In fact, the experiment performed at 500°C for 1h duration did not yield any char; only residual ash could be obtained. The TPO studies on the char samples corroborated the XRD findings and showed the presence of two types of carbon, namely, amorphous filamentous carbon and graphitic carbon. A thermogravimetric analysis (TGA) of the char was performed to gain an understanding of combustion kinetics and reactivity. It implied that the reactivity of the char decreases as temperature increases, and this finding is well supported by the TPO, TGA, SEM, and XRD characterization data. Furthermore, an empirical global model was devised based on the power law to estimate activation energy and other kinetic parameters. For the non-isothermal pressurized pyrolysis of flax straw, the experiments were carried out at different pressures, ranging from 10 to 40 psig. The three types of products thus obtained (gas, liquid, char) were thoroughly quantified and analyzed. The yields of the products were found to be dependent on the experimental conditions. It was observed that 10 psig of pressure gave the maximum yield of bio-oil, while 20 psig pressure lead to maximum char yield. The gaseous products were analyzed using an online GC, while the bio-oils were characterized using an offline GC/MS. SEM studies were performed to study the char morphology and porosity. The main gaseous products observed were CO, H2, CO2, CH 4, and C3. The bio-oils were mainly composed of phenolic compounds, carboxylic acids, and furfural. The pH and density of the bio-oils was found to increase as pyrolysis pressure increased. SEM investigation gave insights into the porosity of chars; as pressure increased, an increase in the porosity of char was noted. XRD studies showed that amorphous hydrocarbon and graphitic carbons are the major constituents of char, which was supported by TPO experiments. A TGA study showed two reaction zones for char oxidation. The kinetic parameters of oxidation were estimated using a power law model, which was also used for isothermal pyrolysis and isothermal char oxidation kinetics. Based on the data generated, the pressure of 10 psig was found to be optimum for bio-oil production, while a pressure of 20 psig was optimum for char production. With the increase in pressure, the production of individual gas components increased within the pressure range studied. Finally, with the increase in reaction pressure, temperature and time, the produced chars became less reactive.

Preparation and characterization of activated carbon from the char produced in the thermolysis of granulated scrap tyres.

PubMed

López, F A; Centeno, T A; Rodríguez, O; Alguacil, E J

2013-05-01

The char produced in the thermolysis of granulated scrap tyres has few market outlets, reducing the economic viability of the thermolytic process. This paper reports the potential of this char as a low-cost precursor of porous carbons. The tyre-derived char was demineralized in either alkaline or acidic media to reduce its ash, zinc, sulfur, and silica contents. The lowest impurity content was achieved with an HNO3/H2O treatment. The resulting demineralized char was then subjected to activation by KOH or CO2. The Brunauer-Emmett-Teller (BET)-specific surface area of the activated carbon produced by the KOH treatment was 242 m2/g, whereas that of the CO2-activated carbon was 720 m2/g. The textural properties of the latter product were similar to those of some commercial activated carbons. The use of tyre-derived char as a precursor of porous carbons could render the thermolytic treatment of scrap tyres more economically attractive. Char produced in thermolysis of granulated scrap tyres has a few market outlets; in this paper an alternative for its use is presented. The char was converted into activated carbon with textural properties similar to those of some commercial activated carbons. This process could render the thermolytic treatment of scrap tyres more economically attractive.

Proximate analyses and predicting HHV of chars obtained from cocracking of petroleum vacuum residue with coal, plastics and biomass.

PubMed

Ahmaruzzaman, M

2008-07-01

Higher heating value (HHV) and analysis of chars obtained from cocracking of petroleum vacuum residue (XVR) with coal (SC), biomass (BG, CL) and plastics (PP, PS, BL) are important which define the energy content and determine the clean and efficient use of these chars. The main aim of the present study is to analyze the char obtained from cocracking in terms of their proximate analysis data and determination of the HHV of the chars. The char obtained from XVR+PP cocracking showed a HHV of 32.84 MJ/kg, whereas that from CL cracking showed a HHV of 18.52 MJ/kg. The experimentally determined heating values of the char samples obtained from cocracking have been correlated with the theoretical equation based on proximate analysis data. There exists a variety of correlations for predicting HHV from proximate analysis of fuels. Based upon proximate analysis data, the models were tested. The best results show coefficient of determination (R2) of 0.965 and average absolute and bias error of 3.07% and 0.41%, respectively. The heating values obtained from the model were in good agreement with that obtained by experiment. Proximate analysis of the chars obtained from the cocracking of XVR with coal, biomass and plastics showed that there exists a definite interaction of the reactive species, when they were cocracked together.

Landform position and charring conditions control decomposition of soil organic matter and pyrogenic carbon

NASA Astrophysics Data System (ADS)

Abney, R.; Jin, L.; Berhe, A. A.

2017-12-01

Wildfire is a significant global control on both ecosystem properties and biogeochemical cycling, and wildfires are projected to increase in both size and severity with continued climate change. Post-fire, charred biomass, or pyrogenic carbon, is left behind as a significant, relatively slow-cycling component of the soil organic matter pool. Pyrogenic carbon has a turnover time on the centennial scale, and previous research has demonstrated that it is highly susceptible to erosion. However, the interaction of the roles of landform position and combustion temperature remains unexplored. We collected live Pinus jeffreyi bark and charred it under combustion conditions at three temperatures (200°C, 350°C, and 500°C). The charred bark was mixed with soil collected from both eroding and depositional landform positions and incubated for six months. Throughout this incubation, microbial respiration was monitored via collection of CO2, and cumulative respiration was fitted using both single- and multi-pool exponential models. Overall, respiration was highest in soil and char mixtures in the depositional landform positions. Pyrogenic carbon concentrations, as determined by the Kurth Mackenzie Deluca method, declined only slightly in the 200°C char mixed with the depositional soil. Scanning electron microscopy images of the chars before and after incubation illustrate some incorporation of soil organic matter into the structures of the char, and some breakdown of the physical structures of the char. Altogether, the lower temperature chars mixed with the soil from the depositional landform position had the highest decomposition rates, which suggests the role that landform position may play on the stability of pyrogenic carbon at the landscape scale. Furthermore, this implies that the post-fire erosional re-distribution of pyrogenic carbon may act as a significant control of its long-term stabilization in soil and landscape-scale soil carbon stocks.

Effect of surface area and chemisorbed oxygen on the SO2 adsorption capacity of activated char

USGS Publications Warehouse

Lizzio, A.A.; DeBarr, J.A.

1996-01-01

The objective of this study was to determine whether activated char produced from Illinois coal could be used effectively to remove sulfur dioxide from coal combustion flue gas. Chars were prepared from a high-volatile Illinois bituminous coal under a wide range of pyrolysis and activation conditions. A novel char preparation technique was developed to prepare chars with SO2 adsorption capacities significantly greater than that of a commercial activated carbon. In general, there was no correlation between SO2 adsorption capacity and surface area. Temperature-programmed desorption (TPD) was used to determine the nature and extent of carbon-oxygen (C-O) complexes formed on the char surface. TPD data revealed that SO2 adsorption was inversely proportional to the amount of C-O complex. The formation of a stable C-O complex during char preparation may have served only to occupy carbon sites that were otherwise reactive towards SO2 adsorption. A fleeting C(O) complex formed during SO2 adsorption is postulated to be the reaction intermediate necessary for conversion of SO2 to H2SO4. Copyright ?? 1996 Elsevier Science Ltd.

Ultrasonically assisted extraction of calcium and ash from char

NASA Astrophysics Data System (ADS)

Mathumba, E. E.; Mbaya, R. K. K.; Kolesnikov, A.

2018-03-01

This study characterized and removed calcium and ash content from char to improve the chemical quality of char as reductant for titanium smelting application. Calcium in char can be classified in two parts: mineral matter and cationic metals associated with organic matrix. Virgin and chemically treated char was characterized by using ISO 1171, wet chemistry methods, ISO 19579, XRF, and B.E.T. methods. In this present work, demineralization of char with mild chemical leachants such as acetic acid, citric acid, gluconic acid and Ethylene Diamine Tetra Acetic acid with three different ultrasonic power input (150 W, 270 W and 300 W) and semi-dual frequency of 40 kHz tank was investigated. Actual power dissipated into the system was calculated from the calorimetric measurement. An optimum set of process parameters are identified and validated. The ultrasound technology was compared with soaking technology to determine the efficiency of ultrasound system for the removal of calcium. The removal of calcium was exponentially higher with ultrasonic treatment than without it. Results revealed that mild chemical reagents do not harm the carbon content of char. It is evident from the results that amongst the leachants used; acetic and citric acid has caused significant removal of mineral phases.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures ofmore » the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.« less

Characterization of a Neochlamydia-like Bacterium Associated with Epitheliocystis in Cultured Artic Char Salvelinus alpinus

USDA-ARS?s Scientific Manuscript database

Infections of branchial epithelium by intracellular gram-negative bacteria, termed epitheliocystis, have limited culture of Arctic char (Salvelinus alpinus). To characterize a bacterium associated with epitheliocystis in cultured char, gills were sampled for histopathologic examination, conventional...

An Integrated Hydrogen Production-CO2 Capture Process from Fossil Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhicheng Wang

The new technology concept integrates two significant complementary hydrogen production and CO{sub 2}-sequestration approaches that have been developed at Oak Ridge National Laboratory (ORNL) and Clark Atlanta University. The process can convert biomass into hydrogen and char. Hydrogen can be efficiently used for stationary power and mobile applications, or it can be synthesized into Ammonia which can be used for CO{sub 2}-sequestration, while char can be used for making time-release fertilizers (NH{sub 4}HCO{sub 3}) by absorption of CO{sub 2} and other acid gases from exhaust flows. Fertilizers are then used for the growth of biomass back to fields. This projectmore » includes bench scale experiments and pilot scale tests. The Combustion and Emission Lab at Clark Atlanta University has conducted the bench scale experiments. The facility used for pilot scale tests was built in Athens, GA. The overall yield from this process is 7 wt% hydrogen and 32 wt% charcoal/activated carbon of feedstock (peanut shell). The value of co-product activated carbon is about $1.1/GJ and this coproduct reduced the selling price of hydrogen. And the selling price of hydrogen is estimated to be $6.95/GJ. The green house experimental results show that the samples added carbon-fertilizers have effectively growth increase of three different types of plants and improvement ability of keeping fertilizer in soil to avoid the fertilizer leaching with water.« less

A kinetic study on microwave-assisted conversion of cellulose and lignocellulosic waste into hydroxymethylfurfural/furfural.

PubMed

da Silva Lacerda, Viviane; López-Sotelo, Juan Benito; Correa-Guimarães, Adriana; Hernández-Navarro, Salvador; Sánchez-Bascones, Mercedes; Navas-Gracia, Luis M; Martín-Ramos, Pablo; Pérez-Lebeña, Eduardo; Martín-Gil, Jesús

2015-03-01

Native cellulose, lignocellulosic materials from Brazil (carnauba palm leaves and macauba pulp and shell) and pine nut shell from Spain have been studied as substrates for the production of HMF and furfural in a conventional microwave oven. In order to promote the dissolution of native cellulose, several ionic liquids, catalysts, organic solvents and water doses have been assessed. The most suitable mixture (5mL of choline chloride/oxalic acid, 2mL of sulfolane, 2mL of water, 0.02g of TiO2 and 0.1g of substrate) has been chosen to conduct kinetic studies at different reaction times (5-60min) and various temperatures (120-200°C) and to evaluate the best conditions for HMF+furfural production according to Seaman's model. The best production yields of HMF+furfural have been attained for native cellulose, with a yield of 53.24% when an ultrasonic pretreatment was used prior to a microwave treatment with stirring. Copyright © 2014 Elsevier Ltd. All rights reserved.

Evaluation of the energy transfer in the char zone during ablation. Part 2: In-depth response of ablative composites, volume 1. Ph.D. Thesis, 1975. Final Report

NASA Technical Reports Server (NTRS)

Pike, R. W.; Delvalle, E. G.

1974-01-01

The decomposition of ablative composites is described along with the transport phenomena of pyrolysis gases which result from the decomposition of these plastics as they flow through the porous char of char-forming ablators. The pyrolysis products are those formed by the thermal degradation of nylon-phenolic resin and silicone elastomer composites. Emphasis is placed on the nature and extent of chemical reactions of the pyrolysis products and the char, along with the energy absorbed by the combined pyrolysis and char zone. Chemical reactions with thermodynamically consistent kinetic data are determined in order to develop a realistic analysis for predicting the thermal performance of ablative heat shields.

Nitric Oxide Reduction over Sewage Sludge and Coal Chars at Conditions Relevant to Staged Fluidized Bed Combustion

NASA Astrophysics Data System (ADS)

Salatino, P.; Solimene, R.; Chirone, R.

The de-NOx potential of coal and of dried and pelletized sewage sludge, a waste-derived fuel candidate for cofiring with coal, is assessed. The experimental procedure is based on operation of a bench scale fluidized bed reactor where NO-doped nitrogen is contacted with batches of the fuel. A second type of experiment has been purposely designed to assess the loss of reactivity of chars toward gasification by NOx as char is heat-treated for pre-set times at temperatures typical of fluidized bed combustion. A simple phenomenological model is developed to shed light on the basic features of the interaction between heterogeneous char-NOx reaction and thermal annealing of the char.

Attrition-free pyrolysis to produce bio-oil and char.

PubMed

Mauviel, Guillain; Guillain, Mauviel; Kies, Fairouz; Fairouz, Kies; René, Mar Sans; Mar, Sans Rene; Ferrer, Monique; Monique, Ferrer; Lédé, Jacques; Jacques, Lédé

2009-12-01

Experiments are performed on a laboratory scale setup where beech wood chips are heated by gas convection and walls radiation. This study shows that it is possible to obtain high bio-oil and char yields with relatively low external heat transfer coefficients. The main advantage of this convection/radiation heat transfer mode compared to solid-solid collisions, applied in fluidized bed or twin screw reactors, is the reduction of solid attrition (char and sand). Thus tricky gas-solid separation through hot cyclones and/or hot filters could be avoided or reduced. It should be possible to recover directly bio-oil with less char particles and char free of sand dust. These qualities would allow easier use of these bio-products in different applications.

Method and apparatus for removing coarse unentrained char particles from the second stage of a two-stage coal gasifier

DOEpatents

Donath, Ernest E.

1976-01-01

A method and apparatus for removing oversized, unentrained char particles from a two-stage coal gasification process so as to prevent clogging or plugging of the communicating passage between the two gasification stages. In the first stage of the process, recycled process char passes upwardly while reacting with steam and oxygen to yield a first stage synthesis gas containing hydrogen and oxides of carbon. In the second stage, the synthesis gas passes upwardly with coal and steam which react to yield partially gasified char entrained in a second stage product gas containing methane, hydrogen, and oxides of carbon. Agglomerated char particles, which result from caking coal particles in the second stage and are too heavy to be entrained in the second stage product gas, are removed through an outlet in the bottom of the second stage, the particles being separated from smaller char particles by a counter-current of steam injected into the outlet.

Kinetic modeling of the formation and growth of inorganic nano-particles during pulverized coal char combustion in O 2/N 2 and O 2/CO 2 atmospheres

DOE PAGES

Shaddix, Christopher R.; Niu, Yanqing; Hui, Shi'en; ...

2016-08-01

In this formation of nano-particles during coal char combustion, the vaporization of inorganic components in char and the subsequent homogeneous particle nucleation, heterogeneous condensation, coagulation, and coalescence play decisive roles. Furthermore, conventional measurements cannot provide detailed information on the dynamics of nano-particle formation and evolution, In this study, a sophisticated intrinsic char kinetics model that considers ash effects (including ash film formation, ash dilution, and ash vaporization acting in tandem), both oxidation and gasification by CO 2 and H 2O, homogeneous particle nucleation, heterogeneous vapor condensation, coagulation, and and coalescence mechanisms is developed and used to compare the temporal evolutionmore » of the number and size of nano-particles during coal char particle combustion as a function of char particle size, ash content, and oxygen content in O 2/N 2 and O 2/CO 2 atmospheres .« less

Kinetic modeling of the formation and growth of inorganic nano-particles during pulverized coal char combustion in O 2/N 2 and O 2/CO 2 atmospheres

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shaddix, Christopher R.; Niu, Yanqing; Hui, Shi'en

In this formation of nano-particles during coal char combustion, the vaporization of inorganic components in char and the subsequent homogeneous particle nucleation, heterogeneous condensation, coagulation, and coalescence play decisive roles. Furthermore, conventional measurements cannot provide detailed information on the dynamics of nano-particle formation and evolution, In this study, a sophisticated intrinsic char kinetics model that considers ash effects (including ash film formation, ash dilution, and ash vaporization acting in tandem), both oxidation and gasification by CO 2 and H 2O, homogeneous particle nucleation, heterogeneous vapor condensation, coagulation, and and coalescence mechanisms is developed and used to compare the temporal evolutionmore » of the number and size of nano-particles during coal char particle combustion as a function of char particle size, ash content, and oxygen content in O 2/N 2 and O 2/CO 2 atmospheres .« less

Structural features of resorcinol-formaldehyde resin chars and interfacial behavior of water co-adsorbed with low-molecular weight organics

NASA Astrophysics Data System (ADS)

Gun'ko, Vladimir M.; Bogatyrov, Viktor M.; Turov, Vladimir V.; Leboda, Roman; Skubiszewska-Zięba, Jadwiga; Urubkov, Iliya V.

2013-10-01

Products of resorcinol-formaldehyde resin carbonization (chars) are characterized by different morphology (particle shape and sizes) and texture (specific surface area, pore volume and pore size distribution) depending on water content during resin polymerization. At a low amount of water (Cw = 37.8 wt.%) during synthesis resulting in strongly cross-linked polymers, carbonization gives nonporous particles. An increase in the water content to 62.7 wt.% results in a nano/mesoporous char, but if Cw = 73.3 wt.%, a char is purely nanoporous. Despite these textural differences, the Raman spectra of all the chars are similar because of the similarity in the structure of their carbon sheets with a significant contribution of sp3 C atoms. However, the difference in the spatial organization of the carbon sheet stacks in the particles results in the significant differences in the textural and morphological characteristics and in the adsorption properties of chars with respect to water, methane, benzene, hydrogen, methylene chloride, and dimethylsulfoxide.

Coal char oxidation kinetics in air medium

NASA Astrophysics Data System (ADS)

Slyusarskiy, K. V.; Jankovskiy, S. A.; Korotkikh, A. G.; Sorokin, I. V.

2017-01-01

Research on oxidation in air medium process of three different coal chars with various carbon content was presented. The anthracite, T-grade bituminous coal and 2B-grade lignite char powders with particle size less than 80 µm were studied. The coal char oxidation was studied by isothermal method using coupled TG-DSC analyzer Netzsch STA 449 Jupiter F3 in the temperature range 1000-1200 °C. Experiments were carried out at ambient pressure. Volumetric flow rate of oxidation medium into analyzer chamber was 250 ml/min and consisted of oxygen and argon with volumetric ratio 24:1. Based on experimental data, the average rate of carbon oxidation reaction values were defined at each temperature. Kinetic constants (frequency factor and activation energy) of reaction were defined as well via 1st order Arrhenius equation. Activation energy values are in good agreement with the data presented in the literature. Activation energy values for anthracite char are 1.6-1.7 times higher than those for bituminous coal and lignite chars, respectively.

Investigation on the fast co-pyrolysis of sewage sludge with biomass and the combustion reactivity of residual char.

PubMed

Deng, Shuanghui; Tan, Houzhang; Wang, Xuebin; Yang, Fuxin; Cao, Ruijie; Wang, Zhao; Ruan, Renhui

2017-09-01

Gaining the valuable fuels from sewage sludge is a promising method. In this work, the fast pyrolysis characteristics of sewage sludge (SS), wheat straw (WS) and their mixtures in different proportions were carried out in a drop-tube reactor. The combustion reactivity of the residual char obtained was investigated in a thermogravimetric analyzer (TGA). Results indicate that SS and WS at different pyrolysis temperatures yielded different characteristic gas compositions and product distributions. The co-pyrolysis of SS with WS showed that there existed a synergistic effect in terms of higher gas and bio-oil yields and lower char yield, especially at the WS adding percentage of 80wt%. The addition of WS to SS increased the carbon content in the SS char and improved char porous structures, resulting in an improvement in the combustion reactivity of the SS char. The research results can be used to promote co-utilization of sewage sludge and biomass. Copyright © 2017. Published by Elsevier Ltd.

Pyrolytic characteristics of biomass acid hydrolysis residue rich in lignin.

PubMed

Huang, Yanqin; Wei, Zhiguo; Yin, Xiuli; Wu, Chuangzhi

2012-01-01

Pyrolytic characteristics of acid hydrolysis residue (AHR) of corncob and pinewood (CAHR, WAHR) were investigated using a thermo-gravimetric analyzer (TGA) and a self-designed pyrolysis apparatus. Gasification reactivity of CAHR char was then examined using TGA and X-ray diffractometer. Result of TGA showed that thermal degradation curves of AHR descended smoothly along with temperature increasing from 150 °C to 850 °C, while a "sharp mass loss stage" for original biomass feedstock (OBF) was observed. Char yield from AHR (42.64-30.35 wt.%) was found to be much greater than that from OBF (26.4-19.15 wt.%). In addition, gasification reactivity of CAHR char was lower than that of corncob char, and there was big difference in micro-crystallite structure. It was also found that CAHR char reactivity decreased with pyrolysis temperature, but increased with pyrolysis heating rate and gasification temperature at 850-950 °C. Furthermore, CAHR char reactivity performed better under steam atmosphere than under CO2 atmosphere. Copyright © 2011 Elsevier Ltd. All rights reserved.

Pulsed Laser Annealing of Carbon

NASA Astrophysics Data System (ADS)

Abrahamson, Joseph P.

This dissertation investigates laser heating of carbon materials. The carbon industry has been annealing carbon via traditional furnace heating since at least 1800, when Sir Humphry Davy produced an electric arc with carbon electrodes made from carbonized wood. Much knowledge has been accumulated about carbon since then and carbon materials have become instrumental both scientifically and technologically. However, to this day the kinetics of annealing are not known due to the slow heating and cooling rates of furnaces. Additionally, consensus has yet to be reached on the cause of nongraphitizability. Annealing trajectories with respect to time at temperature are observed from a commercial carbon black (R250), model graphitizable carbon (anthracene coke) and a model nongraphitizable carbon (sucrose char) via rapid laser heating. Materials were heated with 1064 nm and 10.6 im laser radiation from a Q-switched Nd:YAG laser and a continuous wave CO2 laser, respectively. A pulse generator was used reduce the CO2 laser pulse width and provide high temporal control. Time-temperature-histories with nanosecond temporal resolution and temperature reproducibility within tens of degrees Celsius were determined by spectrally resolving the laser induced incandescence signal and applying multiwavelength pyrometry. The Nd:YAG laser fluences include: 25, 50, 100, 200, 300, and 550 mJ/cm2. The maximum observed temperature ranged from 2,400 °C to the C2 sublimation temperature of 4,180 °C. The CO2 laser was used to collect a series of isothermal (1,200 and 2,600 °C) heat treatments versus time (100 milliseconds to 30 seconds). Laser heated samples are compared to furnace annealing at 1,200 and 2,600 °C for 1 hour. The material transformation trajectory of Nd:YAG laser heated carbon is different than traditional furnace heating. The traditional furnace annealing pathway is followed for CO2 laser heating as based upon equivalent end structures. The nanostructure of sucrose char after 5 seconds of isothermal annealing at 2,600 °C is comprised almost entirely of quasi-spherical closed shell particles that are free of sp3 and oxygen content. With additional time at temperature the particles unravel and propagative particle opening occurs throughout the material. The irregular pore structure found in the end product is a result of particle unraveling. The structures found in heat treated sucrose char believed to contain odd membered rings are not manufactured during the annealing process due to impinging growth of stacks. Thus, odd membered rings are likely present in the starting non-graphitizable char. Furnace annealing of cokes and chars produced from: oxygen containing compounds (polyfurfuryl alcohol and anthanthrone), from a five membered ring containing polyaromatic hydrocarbon (fluorene), and from sulfur containing decant oil and a blend of anthracene-dibenzothiophene were compared to furnace annealed anthracene coke and sucrose char. The majority of initial oxygen content evolved out during low temperature carbonization. The intermediate species formed after oxygen evolution dictated the resulting carbon skeleton and thus the graphitizability. Carbonization of anthanthrone resulted in a graphitizable coke. It is proposed that carbon monoxide loss from anthanthrone results in the formation of perylene. An obvious resemblance was observed in structure between heat treated sucrose and polyfurfuryl alcohol char as compared to heated treated char embedded with 5 membered rings via carbonization of fluorene. Thus, providing evidence that 5 membered rings are present in the virgin chars and are the cause of non-graphitizability. The heteroatom sulfur effects carbon structure in a different way as compared to oxygen. Sulfur is thermally stable in carbon up to ˜ 1,000 °C and thus plays little role in the initial low temperature (500 °C) carbonization. As such it imparts a relatively unobservable impact on nanostructure, but rather acts to cause micro-cracks upon rapid evolution in the form of H2S and CS2, upon subsequent heat treatment. Laboratory generated synthetic soot from benzene and benzene-thiophene were Nd:YAG laser and furnace annealed. Furnace annealing of sulfur doped synthetic soot results in cracks and rupturing due to the high pressures caused by explosive sulfur evolution at elevated temperature. Whereas Nd:YAG laser heating of the sulfur doped sample acted to induce curvature. The observed curvature is owed to annealing occurring simultaneously with sulfur evolution. The unset lamellae are strongly influenced by the defect formed upon sulfur evolution. Coke and char samples were prepared via carbonization in sealed tubing reactors. The extent of mesophase development was assessed by measuring the materials optical anisotropy with a polarized light microscope. Physical and chemical transformations from annealing were measured with electron microscopy, energy dispersive X-ray spectroscopy, selected area electron diffraction, and electron energy loss spectroscopy. Virgin samples and traditional furnace annealed samples available in bulk were analyzed with X-ray diffraction. The potential technological importance of laser annealing carbon is demonstrated as annealing can be performed continuously and rapidly. Examples of material processing and synthesis not possible via traditional furnace annealing are provided.

Compositional and thermal evaluation of lignocellulosic and poultry litter chars via high and low temperature pyrolysis

USDA-ARS?s Scientific Manuscript database

Inorganic elements in biomass feedstocks can influence thermochemical reactions as well as the resultant chars elemental, compositional, and thermal characteristics. Chars were produced using slow pyrolysis at less than 400 and at higher than 500 degree Celsius from sugarcane bagasse, peanut hulls,...

Multiscale Architectures and Parallel Algorithms for Video Object Tracking

DTIC Science & Technology

2011-10-01

0 4 : if FIFO1 contains nDt frames then 5: Partition data into blocks. 6: Put SPE control block information...char buf 4 = FF; vec to r unsigned char buf 5 = FF; vec to r unsigned char buf 6 = FF; vec to r unsigned char buf 7 = FF; for ( j = 0 ; j < s i z e ; j...Public Release; Distribution Unlimited 8 7 u 6 ill :J (;) 5 E -;::; c 0 4 ~ u Q) X 3 Q) 8 7 6 u Q) Ul 5 :J (;) E :;::; 4 c 0

Study on coal char ignition by radiant heat flux.

NASA Astrophysics Data System (ADS)

Korotkikh, A. G.; Slyusarskiy, K. V.

2017-11-01

The study on coal char ignition by CO2-continuous laser was carried out. The coal char samples of T-grade bituminous coal and 2B-grade lignite were studied via CO2-laser ignition setup. Ignition delay times were determined at ambient condition in heat flux density range 90-200 W/cm2. The average ignition delay time value for lignite samples were 2 times lower while this difference is larger in high heat flux region and lower in low heat flux region. The kinetic constants for overall oxidation reaction were determined using analytic solution of simplified one-dimensional heat transfer equation with radiant heat transfer boundary condition. The activation energy for lignite char was found to be less than it is for bituminous coal char by approximately 20 %.

Conversion of microwave pyrolysed ASR's char using high temperature agents.

PubMed

Donaj, Pawel; Blasiak, Wlodzimierz; Yang, Weihong; Forsgren, Christer

2011-01-15

Pyrolysis enables to recover metals and organic feedstock from waste conglomerates such as: automotive shredder residue (ASR). ASR as well as its pyrolysis solid products, is a morphologically and chemically varied mixture, containing mineral materials, including hazardous heavy metals. The aim of the work is to generate fundamental knowledge on the conversion of the organic residues of the solid products after ASR's microwave pyrolysis, treated at various temperatures and with two different types of gasifying agent: pure steam or 3% (v/v) of oxygen. The research is conducted using a lab-scale, plug-flow gasifier, with an integrated scale for analysing mass loss changes over time of experiment, serving as macro TG at 950, 850 and 760 °C. The reaction rate of char decomposition was investigated, based on carbon conversion during gasification and pyrolysis stage. It was found in both fractions that char conversion rate decreases with the rise of external gas temperature, regardless of the gasifying agent. No significant differences between the reaction rates undergoing with steam and oxygen for char decomposition has been observed. This abnormal char behaviour might have been caused by the inhibiting effects of ash, especially alkali metals on char activity or due to deformation of char structure during microwave heating. Copyright © 2010 Elsevier B.V. All rights reserved.

Anadromous char as an alternate food choice to marine animals: a synthesis of Hg concentrations, population features and other influencing factors.

PubMed

Evans, Marlene S; Muir, Derek C G; Keating, Jonathan; Wang, Xiaowa

2015-03-15

This study was conducted to confirm sporadic measurements made over the late 1970s to the early 1990 s which determined that mercury (Hg) concentrations were low in anadromous char across Arctic and subarctic Canada including northern Québec and Labrador. Over 2004-2013, anadromous char populations across northern Canada were investigated at 20 sites for Hg concentrations and life history characteristics. Hg concentrations were extremely low in anadromous char muscle, typically <0.05 μg/g (wet weight) and, at each location, generally increased with fish length, age and nitrogen isotope (δ(15)N) ratio and decreased with condition factor and %lipid; correlations with carbon isotope (δ(13)C) ratio were inconsistent. Location and year were significant variables influencing Hg concentrations over the study area; longitude and latitude also were significant influencing variables. Char length, weight, age, condition factor and lipid content explained additional variance. A tendency towards higher Hg concentrations with increasing latitude may be partially related to decreasing growth of char towards the north. However, Hg concentrations in char were positively correlated with growth rates suggesting that Hg concentrations in char also were higher in the more productive study areas, including to the west where mainland riverine inputs of terrestrial carbon, nutrients, and Hg were greater. The data base for assessing time trends in char was limited by the small number of years investigated at most locations, variable fish size across years, small sample size, etc. Where temporal trends were detected, they were of increase on the long term (1970s, 1980s or early 1990 s to the present) but of decrease on the short term (early 2000s to present) with Nain (Labrador) showing the converse pattern. Higher Hg concentrations were also related to lower condition factor and cooler springs. Hg concentrations in anadromous char are compared with other terrestrial, aquatic and marine vertebrates in traditional diets. The known information on anadromous char is reviewed including population features, habitat, and harvests. Future Hg trend monitoring should focus on specific locations and harvest areas within these areas to better assess trends and influencing factors. Crown Copyright © 2014. Published by Elsevier B.V. All rights reserved.

Using BPCA and pyrolysis-GC/MS patterns as a measure of charring intensity

NASA Astrophysics Data System (ADS)

Kaal, Joeri; Schneider, Maximilian P. W.; Schmidt, Michael W. I.

2010-05-01

Many questions remain on the molecular properties of Black C (organic fire residues such as charcoal and soot). Here we compare parameters from two methods that have recently shown to be related to the degree of thermal modification ("charring intensity") of charcoal-Black C: i) the proportion of mellitic acid (B6CA) among benzenepolycarboxylic acids in the BPCA method [1,2,3] and ii) the relative proportions and degree of alkylation of pyrolysis products from Black C in pyrolysis-GC/MS [4]. For that purpose we used laboratory chars from rice straw (grass) and chestnut wood (wood) produced at 200-1000 °C under N2 flow. The chars obtained at 450 °C are reference materials of the Black Carbon Ring Trial [5]. Positive correlations between the charring temperature and BPCA and pyrolysis patterns confirm that these methods can be used to study the degree of thermal impact of charred remains. Pyrolysis-GC/MS allowed us to track the thermal degradation of the major biocomponents lignin, polysaccharides, tannin, aliphatic chain lipids, triterpenoids, chlorophyll and proteins, mostly between 250 and 450 °C. The proportions of the pyrolysis products of Black C (benzene, toluene, benzonitrile, PAHs, etc.) and also the ratios that reflect the abundance of aliphatic cross-linkages between aromatic moieties (benzene/toluene, naphthalene/alkylnaphthalenes, benzofuran/alkylbenzofurans), increase with charring intensity. Nonetheless, chars obtained at T > 600 °C (especially for wood) gave low quality pyrograms and poor reproducibility because of high thermal stability. The relative contributions of B6CA, one of the molecular markers used for the BPCA method, are indicative for the degree of condensation of the chars. The BPCA approach showed a clear increase in the relative contribution of B6CA from ca. 5 % at 200 °C to ca. 95 % at 1000 °C, confirming the ability of this parameter to assess charring intensity. The relative contribution of B6CA remains almost constant at ca. 30 % between 250 and 450 °C. Thus, with regard to estimating the charring intensity of Black C, the BPCA method is more suitable for high T chars (> 450 °C) while pyrolysis-GC/MS seems more appropriate in the lower T range (< 500 °C). This is not surprising as larger clusters of polyaromatic domains (high T) can be assessed by the BPCA method but are resistant against pyrolysis. On the other hand, smaller clusters and non-polycondensed portions of Black C (low T) are amenable to pyrolysis-GC/MS but escape the analytical window of the BPCA method. The two methods may therefore be considered complementary, with BPCA giving reliable quantitative data on Black C content and charring degree of high T chars while pyrolysis-GC/MS is quantitatively weak but provides highly detailed information on the molecular properties of especially lower T chars. References [1] Brodowski, S., Rodionov, A., Haumeier L., Glaser, B., Amelung, W. (2005) Org. Geochem. 36, 1299-1310. [2] Glaser, B., Haumeier, L., Guggenberger, G., Zech, W. (1998) Org. Geochem. 29, 811-819. [3] Schneider, M.P.W., Hilf, M., Vogt, U.F., Schmidt, M.W.I., Org. Geochem. (submitted) [4] Kaal, J., Rumpel, C. (2009) Org. Geochem. 40, 1179-1187. [5] Hammes, K., Schmidt, M.W.I., Smernik, R.J. et al. (2007) Global Biogeochemical Cycles 21, 1-18.

Development of an Electric Motor Powered Low Cost Coconut Deshelling Machine

NASA Astrophysics Data System (ADS)

Mondal, Imdadul Hoque; Prasanna Kumar, G. V.

2016-06-01

An electric motor powered coconut deshelling machine was developed in line with the commercially available unit, but with slight modifications. The machine worked on the principle that the coconut shell can be caused to fail in shear and compressive forces. It consisted of a toothed wheel, a deshelling rod, an electric motor, and a compound chain drive. A bevelled 16 teeth sprocket with 18 mm pitch was used as the toothed wheel. Mild steel round bar of 18 mm diameter was used as the deshelling rod. The sharp edge tip of the deshelling rod was inserted below the shell to apply shear force on the shell, and the fruit was tilted toward the rotary toothed wheel to apply the compressive force on the shell. The speed of rotation of the toothed wheel was set at 34 ± 2 rpm. The output capacity of the machine was found to be 24 coconuts/h with 95 % of the total time effectively used for deshelling. The labour requirement was found to be 43 man-h/1000 nuts. About 13 % of the kernels got scraped and about 7 % got sliced during the operation. The developed coconut deshelling machine was recommended for the minimum annual use of 200 h or deshelling of 4700 coconuts per year. The cost of operation for 200 h of annual use was found to be about ` 47/h. The developed machine was found to be simple, easy to operate, energy efficient, safe and reduce drudgery involved in deshelling by conventional methods.

Distinct oxidative stabilities of char versus soot black carbon: Implications for quantification and environmental recalcitrance

NASA Astrophysics Data System (ADS)

Elmquist, Marie; Cornelissen, Gerard; Kukulska, Zofia; Gustafsson, Örjan

2006-06-01

Sequestration in sediments of black carbon (BC) from vegetation fires and fuel combustion may constitute a significant sink of otherwise rapidly cycling carbon from the atmosphere-biosphere cycle. It also has the potential to provide a historical record of atmospheric BC loadings. Previous treatments of BC as one homogeneous entity are being replaced with the growing awareness of a BC combustion continuum, a range spanning from slightly charred biomass to soot and graphite. Here the relative recalcitrance of different BC forms is evaluated, and implications for both BC quantification and environmental stability are considered. The stabilities of four BC reference materials against thermal oxidation in air were quite distinct with T50%BC values (i.e., the temperature where 50% BC remained in the residue) of 444°C (diesel soot-BC), 388°C (n-hexane soot-BC), 338°C (wood char-BC), and 266°C (grass char-BC). The implications for BC quantification have been illustrated for a thermal oxidation (the CTO-375) method commonly applied to study BC in sediments. This technique measured BC:TOC ratios of 78.3 ± 1.3% for the diesel soot-BC and 45.3 ± 6.1% for n-hexane soot-BC, whereas no CTO375-BC was detected for the two analyzed char-BC materials. The greater lability of char-BC compared to soot-BC likely reflects higher accessibility to internal microporosity in char-BC, facilitating internal O2 transfer. Decreasing the temperature cutoff below 375°C to also include char-BC is not possible as thermograms of nonpyrogenic reference materials indicated that such material would then be artifactually quantified as BC. The presence of mineral oxides in the sediment matrix may lead to a catalytically mediated lowering of the activation energy for soot-BC oxidation but not for char-BC or nonpyrogenic organic material. Several recent studies combine to challenge the proposition of complete recalcitrance of BC. Particularly, the thermal lability of char-BC from grassland fires deserves further attention in order to improve the understanding of BC in the global carbon cycle.

Lead sorption characteristics of various chicken bone part-derived chars.

PubMed

Park, Jong-Hwan; Wang, Jim J; Kim, Seong-Heon; Kang, Se-Won; Cho, Ju-Sik; Delaune, Ronald D; Ok, Yong Sik; Seo, Dong-Cheol

2018-01-18

Recycling food waste for beneficial use is becoming increasingly important in resource-limited economy. In this study, waste chicken bones of different parts from restaurant industry were pyrolyzed at 600 °C and evaluated for char physicochemical properties and Pb sorption characteristics. Lead adsorption isotherms by different chicken bone chars were carried out with initial Pb concentration range of 1-1000 mg L -1 at pH 5. The Pb adsorption data were better described by the Langmuir model (R 2  = 0.9289-0.9937; ARE = 22.7-29.3%) than the Freundlich model (R 2  = 0.8684-0.9544; ARE = 35.4-72.0%). Among the chars derived from different chicken bone parts, the tibia bone char exhibited the highest maximum Pb adsorption capacity of 263 mg g -1 followed by the pelvis (222 mg g -1 ), ribs (208 mg g -1 ), clavicle (179 mg g -1 ), vertebrae (159 mg g -1 ), and humerus (135 mg g -1 ). The Pb adsorption capacities were significantly and positively correlated with the surface area, phosphate release amount, and total phosphorus content of chicken bone chars (r ≥ 0.9711). On the other hand, approximately 75-88% of the adsorbed Pb on the chicken bone chars was desorbable with 0.1 M HCl, indicating their recyclability for reuse. Results demonstrated that chicken bone char could be used as an effective adsorbent for Pb removal in wastewater.

Etude de production et de caracterisation de biocharbons de panic erige (Panicum virgatum L.) obtenus par pyrolyse

NASA Astrophysics Data System (ADS)

Pilon, Guillaume

This research aimed at the production of biomass char under pyrolytic conditions, targeting biochar as soil amendment, while also considering its application as biocoal, either for bioenergy or subsequent upgrading. The production of biomass char was performed using two bench-scale, batch-type, fixed-bed reactors, each with an operating capacity of 1 and 25 gw.b. /batch, respectively. Switchgrass (Panicum virgatum) has been used for the tests. Production conditions studied implied temperatures of 300, 400 and 500 °C with short residence times (2.5 and 5 min). As well, the effect of using CO2 as vector gas has been compared to a common inert environment of N2. The effects of the previously mentioned parameters were correlated with some important physicochemical characteristics of biomass char. Analyses were also performed on complementary pyrolytic products (bio-oil and gas). The biomass char extraction was performed using a Soxhlet and dichloromethane was used as extracting solvent. The extracts were then characterized by GC-MS thus allowing the identification of several compounds. Specific pyrolysis conditions used at 300 °C - N2 with the 1 g/batch reactor, such as high heating rates as well as high convection conditions, presented advantegeous biomass char yields and properties, and, possible torrefaction process productivity improvement (in comparison to reported literature, such as Gilbert et al. [2009]). The char extracts as well as the bio-oils analysis (also performed using GC-MS), all generated from the 25 g/batch reactor, showed major differences among the compounds obtained from the CO2 and N2 environments, respectively. Several compounds observed in the char extracts appeared less concentrated in the CO2 environment vs N2, for the same reaction temperatures. As an example, at 400 °C, furfural was found only in char extracts from N2 environment as compared to the CO2 environment. Among all studied conditions (for both reactors), only naphthalene and naphthalene derivatives constituted the PAHs content, which was only detected for the chars produced at 500 °C. The use of CO2 as pyrolysis vector gas led to a significant difference for every temperature conditions studied for the biomass char as well as for the liquid and gas products. At 300 °C, in CO 2 environment, it is possible to observe a bio-oil production significantly lower than within a N2 environment (18.0 vs 24.6 %; CO2 vs N2 for P<0.002), a result consistent with the biomass char volatile content that was shown to be significantly higher under the same conditions (0.29 vs 0.35 gchar volatiles content/graw biomass; P=0.1). In addition, at 500 °C, the char ash content was observed to be significantly lower in CO 2 than in N2 (P<0.06). Keywords: Pyrolysis, torrefaction, char, biochar, biocoal, CO 2, Soxhlet extractions, characterization.

Removal of hexavalent Cr by coconut coir and derived chars--the effect of surface functionality.

PubMed

Shen, Ying-Shuian; Wang, Shan-Li; Tzou, Yu-Min; Yan, Ya-Yi; Kuan, Wen-Hui

2012-01-01

The Cr(VI) removal by coconut coir (CC) and chars obtained at various pyrolysis temperatures were evaluated. Increasing the pyrolysis temperature resulted in an increased surface area of the chars, while the corresponding content of oxygen-containing functional groups of the chars decreased. The Cr(VI) removal by CC and CC-derived chars was primarily attributed to the reduction of Cr(VI) to Cr(III) by the materials and the extent and rate of the Cr(VI) reduction were determined by the oxygen-containing functional groups in the materials. The contribution of pure Cr(VI) adsorption to the overall Cr(VI) removal became relatively significant for the chars obtained at higher temperatures. Accordingly, to develop a cost-effective method for removing Cr(VI) from water, the original CC is more advantageous than the carbonaceous counterparts because no pyrolysis is required for the application and CC has a higher content of functional groups for reducing Cr(VI) to less toxic Cr(III). Copyright © 2011 Elsevier Ltd. All rights reserved.

Mechanistic understanding of tetracycline sorption on waste tire powder and its chars as affected by Cu(2+) and pH.

PubMed

Lian, Fei; Song, Zhengguo; Liu, Zhongqi; Zhu, Lingyan; Xing, Baoshan

2013-07-01

The sorption characteristics of tetracycline (TC) by waste tire powder and its chars were investigated to explore the potential of using waste tires as effective sorbents for removal of TC from aqueous solution. Naphthalene (NAPH), a typical hydrophobic organic compound, was selected as asorbate for comparison. TC displayed much lower sorption affinity to tire powder than NAPH. However, it exhibited similar adsorption affinity as NAPH on the pyrolyzed tire chars, which was mainly attributed to π-π electron-donor-acceptor interactions of TC with the graphite surface of chars. TC and Cu(2+) could mutually facilitate the sorption of each other on both tire powder and pyrolyzed chars in a wide pH range. This could be explained by the metallic complexation and/or surface-bridging mechanisms (i.e., Cu- or TC-bridging). However, Cu(2+) and NAPH depressed the sorption of each other on tire powder and displayed negligible impact to each other on the highly pyrolyzed chars. Copyright © 2013 Elsevier Ltd. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zia-ul-Mustafa, M., E-mail: engr.ziamustafa@gmail.com; Ahmad, Faiz; Megat-Yusoff, Puteri S. M.

In this study, intumescent fire retardant coatings (IFRC) were developed to investigate the synergistic effects of reinforced mica and wollastonite fillers based IFRC towards heat shielding, char expansion, char composition and char morphology. Ammonium poly-phosphate (APP) was used as acid source, expandable graphite (EG) as carbon source, melamine as blowing agent, boric acid as additive and Hardener H-2310 polyamide amine in bisphenol A epoxy resin BE-188(BPA) was used as curing agent. Bunsen burner fire test was used for thermal performance according to UL-94 for 1 h. Field Emission Scanning Electron Microscopy (FESEM) was used to observe char microstructure. X-Ray Diffraction (XRD)more » and Fourier transform infrared spectroscopy (FTIR) were used to analyse char composition. The results showed that addition of clay filler in IFRC enhanced the fire protection performance of intumescent coating. X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) results showed the presence of boron phosphate, silicon phosphate oxide, aluminium borate in the char that improved the thermal performance of intumescent fire retardant coating (IFRC). Resultantly, the presence of these developed compounds enhanced the Integrity of structural steel upto 500°C.« less

Prevalence, Level, and Types of Salmonella Isolated from North American In-Shell Pecans over Four Harvest Years.

PubMed

Brar, Pardeepinder K; Strawn, Laura K; Danyluk, Michelle D

2016-03-01

In-shell pecan samples (500 g) were collected over four harvest seasons (2010 to 2014) from seven pecan shelling facilities located in five U.S. states. Four varieties of pecans were analyzed: Mexican Improved, Native Seedlings, Southern Improved, and Western Improved. Pecan samples (100 g) were sent to a third party laboratory for initial Salmonella screening. When a sample was positive for Salmonella, the pathogen level was determined by the most-probable-number (MPN) method (25, 2.5, and 0.25 g). Two sample preparation strategies were used for the MPN analysis, and both strategies were combined for the reported MPN values. Forty-four (0.95%) of 4,641 in-shell pecan samples were positive for Salmonella during initial screening; prevalence by year was 0.47 to 1.4%. Prevalence was not significantly different between varieties: Mexican Improved, 1.2%; Native/Seedling, 0.99%; Southern Improved, 0.97%; and Western Improved, 0.75%. Salmonella was not isolated from 31 of 44 samples upon retesting during MPN analysis (<0.47 MPN/100 g). When Salmonella was detected, the levels were 0.47 to 39 MPN/100 g, with a mean of 2.4 MPN/100 g. Thirty-one Salmonella serotypes were obtained from 42 Salmonella-positive pecan samples; Enteritidis was the most common (12% of samples) followed by Javiana (9%) and Braenderup (7%). All Salmonella Enteritidis isolates were phage type 8. Pulsed-field gel electrophoresis analysis (XbaI) revealed within-serotype diversity, indicating introduction of contamination from a variety of sources. Most (64%) of the isolates were resistant to streptomycin or tetracycline, and 13% were resistant to three or more antibiotics. Salmonella prevalence and level on in-shell pecans is comparable to that on other nuts.

Modeling and evaluation of chromium remediation from water using low cost bio-char, a green adsorbent.

PubMed

Mohan, Dinesh; Rajput, Shalini; Singh, Vinod K; Steele, Philip H; Pittman, Charles U

2011-04-15

Oak wood and oak bark chars were obtained from fast pyrolysis in an auger reactor at 400-450 °C. These chars were characterized and utilized for Cr(VI) remediation from water. Batch sorption studies were performed at different temperatures, pH values and solid to liquid ratios. Maximum chromium was removed at pH 2.0. A kinetic study yielded an optimum equilibrium time of 48 h with an adsorbent dose of 10 g/L. Sorption studies were conducted over a concentration range of 1-100mg/L. Cr(VI) removal increased with an increase in temperature (Q(Oak wood)(°): 25 °C = 3.03 mg/g; 35 °C = 4.08 mg/g; 45 °C = 4.93 mg/g and Q(Oakbark)(°): 25 °C = 4.62 mg/g; 35 °C = 7.43 mg/g; 45 °C = 7.51 mg/g). More chromium was removed with oak bark than oak wood. The char performances were evaluated using the Freundlich, Langmuir, Redlich-Peterson, Toth, Radke and Sips adsorption isotherm models. The Sips adsorption isotherm model best fits the experimental data [high regression (R(2)) coefficients]. The overall kinetic data was satisfactorily explained by a pseudo second order rate expression. Water penetrated into the char walls exposing Cr(VI) to additional adsorption sites that were not on the surfaces of dry char pores. It is remarkable that oak chars (S(BET): 1-3m(2)g(-1)) can remove similar amounts of Cr(VI) as activated carbon (S(BET): ∼ 1000 m(2)g(-1)). Thus, byproduct chars from bio-oil production might be used as inexpensive adsorbents for water purification. Char samples were successfully used for chromium remediation from contaminated surface water with dissolved interfering ions. Copyright © 2011 Elsevier B.V. All rights reserved.

Influence of post-treatment strategies on the properties of activated chars from broiler manure.

PubMed

Lima, Isabel M; Boykin, Debbie L; Thomas Klasson, K; Uchimiya, Minori

2014-01-01

There are a myriad of carbonaceous precursors that can be used advantageously to produce activated carbons or chars, due to their low cost, availability and intrinsic properties. Because of the nature of the raw material, production of granular activated chars from broiler manure results in a significant ash fraction. This study was conducted to determine the influence of several pre- and post-treatment strategies in various physicochemical and adsorptive properties of the resulting activated chars. Pelletized samples of broiler litter and cake were pyrolyzed at 700 °C for 1h followed by a 45 min steam activation at 800 °C at different water flow rates from 1 to 5 mL min(-1). For each activation strategy, samples were either water-rinsed or acid-washed and rinsed or used as is (no acid wash/rinse). Activated char's physicochemical and adsorptive properties towards copper ions were selectively affected by both pre- and post-treatments. Percent ash reduction after either rinsing or acid washing ranged from 1.1 to 15.1% but washed activated chars were still alkaline with pH ranging from 8.4 to 9.1. Acid washing or water rinsing had no significant effect in the ability of the activated char to adsorb copper ions, however it significantly affected surface area, pH, ash content and carbon content. Instead, manure type (litter versus cake) and the activation water flow rate were determining factors in copper ion adsorption which ranged from 38 mg g(-1) to 104 mg g(-1) of activated char. Moreover, strong positive correlations were found between copper uptake and concentration of certain elements in the activated char such as phosphorous, sulfur, calcium and sodium. Rinsing could suffice as a post treatment strategy for ash reduction since no significant differences in the carbon properties were observed between rinsed and acid wash treatments. Published by Elsevier Ltd.

Controls upon biomass losses and char production from prescribed burning on UK moorland.

PubMed

Worrall, Fred; Clay, Gareth D; May, Richard

2013-05-15

Prescribed burning is a common management technique used across many areas of the UK uplands. However, there are few data sets that assess the loss of biomass during burning and even fewer data on the effect of burning on above-ground carbon stocks and production of char. During fire the production of char occurs which represents a transfer of carbon from the short term bio-atmospheric cycle to the longer term geological cycle. However, biomass is consumed leading to the reduction in litter formation which is the principal mechanism for peat formation. This study aims to solve the problem of whether loss of biomass during a fire is ever outweighed by the production of refractory forms of carbon during the fire. This study combines both a laboratory study of char production with an assessment of biomass loss from a series of field burns from moorland in the Peak District, UK. The laboratory results show that there are significant effects due to ambient temperature but the most important control on dry mass loss is the maximum burn temperature. Burn temperature was also found to be linearly related to the production of char in the burn products. Optimisation of dry mass loss, char production and carbon content shows that the production of char from certain fires could store more carbon in the ecosystem than if there had been no fire. Field results show that approximately 75% of the biomass and carbon were lost through combustion, a figure comparable to other studies of prescribed fire in other settings. Char-C production was approximately 2.6% of the carbon consumed during the fire. This study has shown that there are conditions (fast burns at high temperatures) under which prescribed fire may increase C sequestration through char production and that these conditions are within existing management options available to practitioners. Copyright © 2013 Elsevier Ltd. All rights reserved.

Effects of fresh and aged chars from pyrolysis and hydrothermal carbonization on nutrient sorption in agricultural soils

NASA Astrophysics Data System (ADS)

Gronwald, M.; Don, A.; Tiemeyer, B.; Helfrich, M.

2015-06-01

Leaching of nutrients from agricultural soils causes major environmental problems that may be reduced with amendments of chars derived from pyrolysis (pyrochars) or hydrothermal carbonization (hydrochars). Chars are characterized by a high adsorption capacity - i.e. they may retain nutrients such as nitrate and ammonium. However, the physicochemical properties of the chars and hence their sorption capacity likely depend on feedstock and the production process. We investigated the nutrient retention capacity of pyrochars and hydrochars from three different feedstocks (digestates, Miscanthus, woodchips) mixed into different soil substrates (sandy loam and silty loam). Moreover, we investigated the influence of char degradation on its nutrient retention capacity using a 7-month in situ field incubation of pyrochar and hydrochar mixed into soils at three different field sites. Pyrochars showed the highest ability to retain nitrate, ammonium and phosphate, with pyrochar from woodchips being particularly efficient in nitrate adsorption. Ammonium adsorption of pyrochars was controlled by the soil type of the soil-char mixture. We found some ammonium retention on sandy soils, but no pyrochar effect or even ammonium leaching from the loamy soil. The phosphate retention capacity of pyrochars strongly depended on the pyrochar feedstock with large phosphate leaching from digestate-derived pyrochar and some adsorption capacity from woodchip-derived pyrochar. Application of hydrochars to agricultural soils caused small, and often not significant, effects on nutrient retention. In contrast, some hydrochars did increase the leaching of nutrients compared to the non-amended control soil. We found a surprisingly rapid loss of the chars' adsorption capacity after field application of the chars. For all sites and for hydrochar and pyrochar, the adsorption capacity was reduced by 60-80 % to less or no nitrate and ammonium adsorption. Thus, our results cast doubt on the efficiency of char applications to temperate zone soils to minimize nutrient losses via leaching.

Development, Verification and Validation of Enclosure Radiation Capabilities in the CHarring Ablator Response (CHAR) Code

NASA Technical Reports Server (NTRS)

Salazar, Giovanni; Droba, Justin C.; Oliver, Brandon; Amar, Adam J.

2016-01-01

With the recent development of multi-dimensional thermal protection system (TPS) material response codes including the capabilities to account for radiative heating is a requirement. This paper presents the recent efforts to implement such capabilities in the CHarring Ablator Response (CHAR) code developed at NASA's Johnson Space Center. This work also describes the different numerical methods implemented in the code to compute view factors for radiation problems involving multiple surfaces. Furthermore, verification and validation of the code's radiation capabilities are demonstrated by comparing solutions to analytical results, to other codes, and to radiant test data.

Thermochemical tests on resins: Char resistance of selected phenolic cured epoxides

NASA Technical Reports Server (NTRS)

Keck, F. L.

1982-01-01

Curing epoxy resins with novalac phenolic resins is a feasible approach for increasing intact char of the resin system. Char yields above 40% at 700 C were achieved with epoxy novalac (DEN 438)/novalac phenolic (BRWE 5833) resin systems with or without catalyst such as ethyl tri-phenyl phosphonium iodide. These char yields are comparable to commercially used epoxy resin systems like MY-720/DDS/BF3. Stable prepregs are easily made from a solvent solution of the epoxy/phenolic system and this provides a feasible process for fabrication of same into commercial laminates.

Kinetic Modelling of the Pyrolysis of Biomass for the Development of Charcoal Briquette

NASA Astrophysics Data System (ADS)

Idris, Y. R.; Bayu, H. T.; Wintoko, J.; Murachman, B.; Yuliansyah, A. T.; Purwono, S.

2017-06-01

Waste of biomass can be utilized as an energy alternative such as a charcoal briquette. In the waste of biomass, there is carbon element bonded in the cellulose which can be utilized as an energy source of solid fuel. Charcoal briquette from waste of biomass can be developed via pyrolysis process. Terminalia Catappa L. and Myristica fragrans (nutmeg seeds shells) shells were used as raw material for the manufacture of charcoal briquettes. Pyrolysis process took place under isothermal conditions at a temperature of 350°C, 400°C, 450°C, 500°C, and 550°C with variation of times were 30 minutes, 60 minutes and 90 minutes. During the pyrolysis process, there were three main components observed, namely liquid (bio oil), gases and solids (char). Data obtained for measuring the kinetics of liquids and gases were taken in interval of 5 minutes. The results showed that the rise in temperature will increase the rate of pyrolysis process and increase the yield of gases and liquids as well as lowering the yield for solid. The best fitted kinetic model is the representation of biomass pyrolysis process involving secondary decomposition of the liquid. The results of briquette development showed that these two biomasses can be used as raw material of energy alternative.

Effect of basalt fibres reinforcement and aluminum trihydrate on the thermal properties of intumescent fire retardant coatings

NASA Astrophysics Data System (ADS)

Yasir, Muhammad; Amir, Norlaili Binti; Ahmad, Faiz; Syahirah Rodzhan, N.

2017-08-01

This research is carried out in order to study the synergistic effect of aluminium trihydrate and basalt fibres on the properties of fire resistant intumescent coatings. Intumescent fire retardant coatings were developed using different flame retardants such as ammonium polyphosphate, expandable graphite, melamine and boric acid. These flame retardants were bound together with the help of epoxy binder along with curing agent. Furthermore, individual and combinations of aluminium trihydrate and basalt fibres was incorporated in the formulations to analyse mechanical and chemical properties of the coatings. Char expansion was observed using furnace test, thermogravimetric analysis was used to determine residual weight, X-Ray Diffraction was performed to investigate compounds present in the char, shear test was conducted to determine char strength and scanning electron microscopy analysis was performed to observe morphology of the burnt char. From the microscopic investigation it was concluded that the dense structure of the char increased the char integrity by adding basalt and aluminium trihydrate as fillers. X-Ray Diffraction results shows the presence boron phosphate, and boric acid which enhanced the thermal performance of the coating up to 800°C. From the Thermogravimetric analysis it was concluded that the residual weight of the char was increased up to 34.9 % for IC-B2A4 which enhanced thermal performance of intumescent coating.

Combustion and Gasification Properties of Plastics Particles.

PubMed

Zevenhoven, Ron; Karlsson, Magnus; Hupa, Mikko; Frankenhaeuser, Martin

1997-08-01

The combustion and gasification behavior of the most common plastics is studied and compared with conventional fuels such as coal, peat, and wood. The aim is to give background data for finding the optimum conditions for co-combustion or co-gasification of a conventional fuel with a certain amount of plastic-derived fuel. Atmospheric or pressurized fluidized bed co-combustion of conventional fuels and plastics are considered to be promising future options. The plastics investigated were poly(ethylene) (PE), poly(propylene) (PP), poly(styrene) (PS), and poly(vinyl chloride) (PVC). Some of the samples had a print or color. The reference fuels were Polish bituminous coal, Finnish peat, and Finnish pine wood. PE, PP, and PS were found to burn like oil. The particles shrank to a droplet and burned completely during the pyrolysis stage, leaving no char. Printing and coloring left a small portion of ash. PVC was the only plastic that produced a carbonaceous residue, and its timescales for heating, devolatilization, and char burning were of the same order as those for peat and wood, and much shorter for the other plastics studied. An important result is that char from PVC contains less than 1% chlorine,99% hydrocarbon. The gasification rate of PVC char (at 1 bar and 25 bar) was of the same order as that of char from coal. Peat-char and wood-char were gasified an order of magnitude faster.

Apparatus for mixing char-ash into coal stream

DOEpatents

Blaskowski, Henry J.

1982-03-16

Apparatus for obtaining complete mixing of char with coal prior to the introduction of the mixture into the combustor (30) of a coal gasifier (10). The coal is carried in one air stream (22), and the char in another air stream (54), to a riffle plate arrangement (26), where the streams of solid are intimately mixed or blended.

Char syndrome: an additional family with polythelia, a new finding.

PubMed

Zannolli, R; Mostardini, R; Matera, M; Pucci, L; Gelb, B D; Morgese, G

2000-11-27

This report describes a father and daughter with Char syndrome, a rare autosomal dominant disorder. Both affected individuals had typical face, strabismus, and foot anomalies. The girl also had a patent ductus arteriosus. In addition, both patients had polythelia (supernumerary nipples), a finding not described before in the Char syndrome. Copyright 2000 Wiley-Liss, Inc.

Formation of nanocarbon spheres by thermal treatment of woody char from fast pyrolysis process

Treesearch

Qiangu Yan; Hossein Toghiani; Zhiyong Cai; Jilei Zhang

2014-01-01

Influences of thermal treatment conditions of temperature, reaction cycle and time, and purge gas type on nanocarbon formation over bio-chars from fast pyrolysis and effects of thermal reaction cycle and purge gas type on bio-char surface functional groups were investigated by temperature-programmed desorption (TPD) and temperature programmed reduction methods....

Near-extinction and final burnout in coal combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hurt, R.H.; Davis, K.A.

The late stages of char combustion have a special technological significance, as carbon conversions of 99% or greater are typically required for the economic operation of pulverized coal fired boilers. In the present article, two independent optical techniques are used to investigate near-extinction and final burnout phenomenas. Captive particle image sequences, combined with in situ optical measurements on entrained particles, provide dramatic illustration of the asymptotic nature of the char burnout process. Single particle combustion to complete burnout is seen to comprise two distinct stages: (1) a rapid high-temperature combustion stage, consuming about 70% of the char carbon and endingmore » with near-extinction of the heterogeneous reactions due to a loss of global particle reactivity, and (2) a final burnout stage occurring slowly at lower temperatures. For particles containing mineral matter, the second stage can be further subdivided into: (2a) late char combustion, which begins after the near-extinction event, and converts carbon-rich particles to mixed particle types at a lower temperature and a slower rate; and (2b) decarburization of ash -- the removal of residual carbon inclusions from inorganic (ash) frameworks in the very late stages of combustion. This latter process can be extremely slow, requiring over an order of magnitude more time than the primary rapid combustion stage. For particles with very little ash, the loss of global reactivity leading to early near-extinction is clearly related to changes in the carbonaceous char matrix, which evolves over the course of combustion. Current global kinetic models used for the prediction of char combustion rates and carbon burnout in boilers do not predict the asymptotic nature of char combustion. More realistic models accounting for the evolution of char structure are needed to make accurate predictions in the range of industrial interest.« less

Computational investigations of low-emission burner facilities for char gas burning in a power boiler

NASA Astrophysics Data System (ADS)

Roslyakov, P. V.; Morozov, I. V.; Zaychenko, M. N.; Sidorkin, V. T.

2016-04-01

Various variants for the structure of low-emission burner facilities, which are meant for char gas burning in an operating TP-101 boiler of the Estonia power plant, are considered. The planned increase in volumes of shale reprocessing and, correspondingly, a rise in char gas volumes cause the necessity in their cocombustion. In this connection, there was a need to develop a burner facility with a given capacity, which yields effective char gas burning with the fulfillment of reliability and environmental requirements. For this purpose, the burner structure base was based on the staging burning of fuel with the gas recirculation. As a result of the preliminary analysis of possible structure variants, three types of early well-operated burner facilities were chosen: vortex burner with the supply of recirculation gases into the secondary air, vortex burner with the baffle supply of recirculation gases between flows of the primary and secondary air, and burner facility with the vortex pilot burner. Optimum structural characteristics and operation parameters were determined using numerical experiments. These experiments using ANSYS CFX bundled software of computational hydrodynamics were carried out with simulation of mixing, ignition, and burning of char gas. Numerical experiments determined the structural and operation parameters, which gave effective char gas burning and corresponded to required environmental standard on nitrogen oxide emission, for every type of the burner facility. The burner facility for char gas burning with the pilot diffusion burner in the central part was developed and made subject to computation results. Preliminary verification nature tests on the TP-101 boiler showed that the actual content of nitrogen oxides in burner flames of char gas did not exceed a claimed concentration of 150 ppm (200 mg/m3).

Leaching of major and trace elements from paper-plastic gasification chars: an experimental and modelling study.

PubMed

Fuente-Cuesta, A; Lopez-Anton, M A; Diaz-Somoano, M; Zomeren, A van; Cieplik, M; Martínez-Tarazona, M R

2013-01-15

The control of soluble metal species in the sub-product leachate generated in electricity production processes is of great concern from an environmental and health point of view. Unlike fly ash, the leaching behaviour of char materials has received little attention. Yet, these solids are captured together with fly ashes in the particle control devices of power plants and are emitted in the same way as by-products. The present study was carried out using two char samples: (i) a raw char and (ii) the same type of char employed in a previous study so that it could serve as a sorbent for mercury species in gas phase. The char samples were by-products (residues) that had been generated during the gasification of plastic and paper waste. The leachates were analyzed for the following elements: Al, Ca, Si, Mg, Ba, Cu, Ni, Pb, Zn, Mo and Hg. In addition, geochemical modelling of the leaching test results was employed to identify the underlying chemical processes that led to the release of toxic elements. The results showed that at alkaline pH values, sorption on the solid surfaces of the char was negligible due to the inorganic complexation of cations in the solution. When the char was used as mercury sorbent slight changes occurred on the reactive surface resulting in the modification of the binding of some elements. As the pH increased, complexation with dissolved organic matter played a more important role in the case of some elements such as Cu because of the greater concentration of dissolved organic matter in solution. Copyright © 2012 Elsevier B.V. All rights reserved.

The application of carbon isotope discrimination of charred wheat grains to reconstruct Late Holocene climate change and identify water management strategy in northwest China

NASA Astrophysics Data System (ADS)

Wang, W.; An, C.; Duan, F.; Zhao, Y.; Cao, Z.

2017-12-01

The AMS 14C dating and corresponding carbon stable isotope datum of charred wheat grains from archaeological sites in northwest China especially Hexi Corridor and Xinjiang have been collected widely to study its potential roles in reconstructing past climate change and identifying water management strategies through comparison with integrated regional humidity index, carbon isotope data of wheat grown under modern irrigation environment from study area and Mediterranean charred wheat carbon isotope data. The results suggest (1) carbon isotope discrimination values of charred wheat both in Hexi corridor and Xinjiang could respond well to regional moisture change, and there are also good positive correlation relationship between them (2) in contrast to consistent relationship between decreased carbon isotope discrimination values of charred wheat and dry climate condition, increased carbon isotope discrimination values does not represent wetter regional climate completely and may also reveal effects of human irrigation activities. The higher carbon isotope discrimination value of charred wheat which occurred in the Hexi Corridor from 4000 to 3850 a BP, 2100 a BP and 550 a BP and in Tianshan area of Xinjiang from 3730 a BP could be likely to be related with human activities (3) the carbon isotope discrimination value of charred wheat may have a certain limit which is generally not beyond 19‰. And this upper limit could influence its availability in reflecting abrupt change of precipitation/humidity especially rapid wetter trend. We conclude that carbon isotope analysis of charred wheat grains could be a good tool for reconstructing past climate change and identifying ancient irrigation practices.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Calo, J.M.; Suuberg, E.M.; Hradil, G.

This project is concerned with the study of the nature and behavior of ''active sites'' in char gasification. The research strategy involves use of model chars produced from the phenol-formaldehyde family of resins. These materials have been chosen since they have structural features similar to those in coals, but are much ''cleaner'' in that the concentration of potentially catalytic impurities can be maintained at low levels. It should be borne in mind that the objective of this work is to study non-catalytic gasification processes. In the previous quarterly report, we presented evidence that low temperature oxygen chemisorption does not providemore » a site-specific titration of active sites in chars; the uptake of oxygen by a cleaned char surface was unquestionably shown to be a function of temperature and oxygen partial pressure, and the importance of these variables differs from char to char. The fact that ''active surface area'' (ASA) determined by various arbitrary methods does seem to generally correlate with reactivity, seems to suggest that reactivities under various gasification and chemisorption conditions are correlated but that mechanisitic inferences cannot necessarily be drawn from such data. In the present report, we have extended the study of low temperature oxidation of chars, considering mass loss as well as oxygen uptake, since the two processes are essentially inseparable under a wide range of conditions. This work represents more than a simple attempt at trying to learn more about the oxygen chemisorption technique; rather it offers the opportunity to study the mechanism of oxygen attack on char under conditions that allow for better understanding of the fundamental processes. For these reasons, this work was performed in the pyrogasifier reactor (developed for CO/sub 2/ gasification reactivity studies), and complements the ongoing work in the TGA apparatus. 6 refs., 9 figs., 1 tab.« less

Experimental performance of an ablative material as an external insulator for a hypersonic research aircraft

NASA Technical Reports Server (NTRS)

Puster, R. L.; Chapman, A. J.

1977-01-01

An ablative material composed of silica-filled elastomeric silicone was tested to evaluate its thermal and structural performance as an external insulator, or heat shield, for a hypersonic research aircraft. The material was also tested to determine whether it would form a durable char layer when initially heated and thereafter function primarily as an insulator with little further pyrolysis or char removal. Aerothermal tests were representative of nominal Mach 6 cruise conditions of the aircraft, and additional tests were representative of Mach 8 cruise and interference heating conditions. Radiant heating tests were used to simulate the complete nominal Mach 6 surface-temperature history. The silica char that formed during aerothermal tests was not durable. The char experienced a general and preferential surface recession, with the primary mechanism for char removal being erosion. Tests revealed that radiant heating is not a valid technique for simulating aerodynamic heating of the material.

Experimental Study of Hydrogasification of Lignite and Subbituminous Coal Chars

PubMed Central

Gil, Stanisław

2015-01-01

The experimental facility for pressure hydrogasification research was adapted to the pressure of 10 MPa and temperature of 1300 K, which ensured repeatability of results and hydrogen heating to the process temperature. A hydrogasification reaction of chars produced from two rank coals was investigated at temperatures up to 1173 K, pressures up to 8 MPa, and the gas flow rates of 0.5–5 dmn 3/min. Reactivity of the “Szczerców” lignite char was found to be slightly higher than that of the subbituminous “Janina” coal char produced under the same conditions. A high value of the char reactivity was observed to a certain carbon conversion degree, above which a sharp drop took place. It was shown that, to achieve proper carbon conversion, the hydrogasification reaction must proceed at a temperature above 1200 K. PMID:26065028

[Dynamics of parasite fauna of different forms of salmon Salvelinus alpinus L. from the basin of the Lake Azabach'e].

PubMed

Butorina, T E

1975-01-01

The paper deals with age changes in the parasite fauna of different intraspecific forms of chars. It is shown that this year brood and yearlings of predatory, benthofagous, stream and anadromous chars up to 10 cm in length have a similar parasite fauna. During the second year of life the chars come to different feeding; correspondingly changes their parasite fauna which differs considerably in the above forms of chars. Two groups of parasites are distinguished the infection with which increases and decreases with the age of fishes. Observations were carried out on the life cycles, developmental and maturation periods of some parasites of chars. Biological peculiarities of some mixosporidia are studied. A shift in the developmental periods of helminths is noted as compared to those from the European part of the USSR.

The influence of wildfire severity on soil char composition and nitrogen dynamics

NASA Astrophysics Data System (ADS)

Rhoades, Charles; Fegel, Timothy; Chow, Alex; Tsai, Kuo-Pei; Norman, John, III; Kelly, Eugene

2017-04-01

Forest fires cause lasting ecological changes and alter the biogeochemical processes that control stream water quality. Decreased plant nutrient uptake is the mechanism often held responsible for lasting post-fire shifts in nutrient supply and demand, though other upland and in-stream factors also likely contribute to elevated stream nutrient losses. Soil heating, for example, creates pyrogenic carbon (C) and char layers that influence C and nitrogen (N) cycling. Char layer composition and persistence vary across burned landscapes and are influenced first by fire behavior through the temperature and duration of combustion and then by post-fire erosion. To evaluate the link between soil char and stream C and N export we studied areas burned by the 2002 Hayman Fire, the largest wildfire in Colorado, USA history. We compared soil C and N pools and processes across ecotones that included 1) unburned forests, 2) areas with moderate and 3) high wildfire severity. We analyzed 1-2 cm thick charred organic layers that remain visible 15 years after the fire, underlying mineral soils, and soluble leachate from both layers. Unburned soils released more dissolved organic C and N (DOC and DON) from organic and mineral soil layers than burned soils. The composition of DOC leachate characterized by UV-fluorescence, emission-excitation matrices (EEMs) and Fluorescence Regional Integration (FRI) found similarity between burned and unburned soils, underscoring a common organic matter source. Humic and fulvic acid-like fractions, contained in regions V and III of the FRI model, comprised the majority of the fluorescing DOM in both unburned and char layers. Similarity between two EEMs indices (Fluorescence and Freshness), further denote that unburned soils and char layers originate from the same source and are consistent with visual evidence char layers contain significant amounts of unaltered OM. However, the EEMs humification index (HIX) and compositional analysis with pyrolysis GCMS both indicate that C contained or leached from severely-burned char layers has higher aromaticity and thus chemical stability compared to C in unburned soils. Mineral soil (0-5 cm depth) beneath char layers in high severity portions of the Hayman Fire had significantly more soil N and C and lower pH. Potential net mineralization - an index of the supply of plant-available nitrogen - differed between the severely-burned areas and both unburned and moderately-burn areas. Negative net mineralization in unburned and moderately burned soils indicates immobilization or retention of inorganic N by soil microbes. In contrast, soils burned at high severity produced inorganic N sources available to plants, leaching and gas losses. Water soluble nitrate comprised a larger proportion of inorganic N leached from the char layer of high severity burns. Mineral soil in those areas had both higher water soluble nitrate and total inorganic N in leachate. Char layers that have persisted for fifteen years influence soil N turnover within the Hayman Fire affected area and may contribute to elevated N losses in streams burned at high severity. The chemical stability of soil char layers perpetuates their importance for C sequestration and N dynamics in burned landscapes.

Using bark char codes to predict post-fire cambium mortality

Treesearch

Sharon M. Hood; Danny R. Cluck; Sheri L. Smith; Kevin C. Ryan

2008-01-01

Cambium injury is an important factor in post-fire tree survival. Measurements that quantify the degree of bark charring on tree stems after fire are often used as surrogates for direct cambium injury because they are relatively easy to assign and are non-destructive. However, bark char codes based on these measurements have been inadequately tested to determine how...

Magnetic separation of carbon-encapsulated Fe nanoparticles from thermally-treated wood char

Treesearch

Sung Phil Mun; Zhiyong Cai; Jilei Zhang

2013-01-01

Wood char,a by-product from the fast-pyrolysis process of southern yellow pine wood for bio-oil production, was carbonized with Fenano particles (FeNPs) as a catalyst to prepare carbon-encapsulated Fe nanoparticles. A magnetic separation method was tested to isolate carbon-encapsulated Fe nano particles from the carbonized char. X-ray diffraction pattern clearly shows...

Graphite fiber surface treatment to improve char retention and increase fiber clumping

NASA Technical Reports Server (NTRS)

Paul, J. T., Jr.; Weldy, W. E.

1980-01-01

Composites containing carbon and graphite fibers can release fibers into the atmosphere during a fire. This release can potentially cause failure in some types of electrical equipment. Reduced fiber dispersion during and after combustion will reduce risks. Epoxidized char forming systems were synthesized which will react with commercially available surface treated carbon fiber. Fibers modified with these char formers retained adhesion in a specific epoxy matrix resin. Small scale combustion testing indicates that using these char former modified fibers in laminates will help to reduce the dispersement of fibers resulting from exposure to fire without sacrificing resin to fiber adhesion.

Synergistic effects of mica and wollastonite fillers on thermal performance of intumescent fire retardant coating

NASA Astrophysics Data System (ADS)

Zia-ul-Mustafa, M.; Ahmad, Faiz; Megat-Yusoff, Puteri S. M.; Aziz, Hammad

2015-07-01

In this study, intumescent fire retardant coatings (IFRC) were developed to investigate the synergistic effects of reinforced mica and wollastonite fillers based IFRC towards heat shielding, char expansion, char composition and char morphology. Ammonium poly-phosphate (APP) was used as acid source, expandable graphite (EG) as carbon source, melamine as blowing agent, boric acid as additive and Hardener H-2310 polyamide amine in bisphenol A epoxy resin BE-188(BPA) was used as curing agent. Bunsen burner fire test was used for thermal performance according to UL-94 for 1 h. Field Emission Scanning Electron Microscopy (FESEM) was used to observe char microstructure. X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) were used to analyse char composition. The results showed that addition of clay filler in IFRC enhanced the fire protection performance of intumescent coating. X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) results showed the presence of boron phosphate, silicon phosphate oxide, aluminium borate in the char that improved the thermal performance of intumescent fire retardant coating (IFRC). Resultantly, the presence of these developed compounds enhanced the Integrity of structural steel upto 500°C.

Recent studies on activated carbons and fly ashes from Turkish resources

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ayhan Demirbas; Gulsin Arslan; Erol Pehlivan

2006-05-15

This article deals with adsorptive properties of activated carbons (ACs) and fly ashes from Turkish coal and biomass resources. ACs because of their high surface area, microporous character and the chemical nature of their surface have been considered potential adsorbents for the removal of heavy metals from industrial wastewater. Pyrolysis is an established process method for preparation of activated carbon from biomass. The bio-char is can be used as AC. The adsorption properties of ACs were strictly defined by the physicochemical nature of their surface and their texture, i.e., pore volume, pore size distribution, surface area. It is well knownmore » that the pH of the solution-adsorbant mixture is an important variable in the adsorption process. Fly ash has the highest adsorption capacity (198.2 mg/g for Cd(II)). Almond shell AC has the lowest adsorption capacity (2.7 mg/g).« less

The potential applications of using compost chars for removing the hydrophobic herbicide atrazine from solution.

PubMed

Tsui, Lo; Roy, William R

2008-09-01

One commercial compost sample was pyrolyzed to produce chars as a sorbent for removing the herbicide atrazine from solution. The sorption behavior of compost-based char was compared with that of an activated carbon derived from corn stillage. When compost was pyrolyzed, the char yield was greater than 45% when heated under air, and 52% when heated under N(2). In contrast, when the corn stillage was pyrolyzed under N(2), the yield was only 22%. The N(2)-BET surface area of corn stillage activated carbon was 439 m(2)/g, which was much greater than the maximum compost char surface area of 72 m(2)/g. However, the sorption affinity of the compost char for dissolved atrazine was comparable to that of the corn stillage activated carbon. This similarity could have resulted from the initial organic waste being subjected to a relatively long period of thermal processes during composting, and thus, the compost was more thermally stable when compared with the raw materials. In addition, microorganisms transformed the organic wastes into amorphous humic substances, and thus, it was likely that the microporisity was enhanced. Although this micropore structure could not be detected by the N(2)-BET method, it was apparent in the atrazine sorption experiment. Overall, the experimental results suggested that the compost sample in current study was a relatively stable material thermally for producing char, and that it has the potential as a feed stock for making high-quality activated carbon.

Charring rate of wood exposed to a constant heat flux

Treesearch

R. H. White; H. C. Tran

1996-01-01

A critical factor in the fire endurance of a wood member is its rate of charring. Most available charring rate data have been obtained using the time-temperature curves of the standard fire resistance tests (ASTM E 119 and ISO 834) to define the fire exposure. The increased use of heat release calorimeters using exposures of constant heat flux levels has broadened the...

Gasification Characteristics of Coal/Biomass Mixed Fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitchell, Reginald

2014-09-01

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co-produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomassmore » and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures.« less

Recovery of solid fuel from municipal solid waste by hydrothermal treatment using subcritical water

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hwang, In-Hee, E-mail: hwang@eng.hokudai.ac.jp; Aoyama, Hiroya; Matsuto, Toshihiko

2012-03-15

Highlights: Black-Right-Pointing-Pointer Hydrothermal treatment using subcritical water was studied to recover solid fuel from MSW. Black-Right-Pointing-Pointer More than 75% of carbon in MSW was recovered as char. Black-Right-Pointing-Pointer Heating value of char was comparable to that of brown coal and lignite. Black-Right-Pointing-Pointer Polyvinyl chloride was decomposed at 295 Degree-Sign C and 8 MPa and was removed by washing. - Abstract: Hydrothermal treatments using subcritical water (HTSW) such as that at 234 Degree-Sign C and 3 MPa (LT condition) and 295 Degree-Sign C and 8 MPa (HT condition) were investigated to recover solid fuel from municipal solid waste (MSW). Printing paper,more » dog food (DF), wooden chopsticks, and mixed plastic film and sheets of polyethylene, polypropylene, and polystyrene were prepared as model MSW components, in which polyvinylchloride (PVC) powder and sodium chloride were used to simulate Cl sources. While more than 75% of carbon in paper, DF, and wood was recovered as char under both LT and HT conditions, plastics did not degrade under either LT or HT conditions. The heating value (HV) of obtained char was 13,886-27,544 kJ/kg and was comparable to that of brown coal and lignite. Higher formation of fixed carbon and greater oxygen dissociation during HTSW were thought to improve the HV of char. Cl atoms added as PVC powder and sodium chloride to raw material remained in char after HTSW. However, most Cl originating from PVC was found to converse into soluble Cl compounds during HTSW under the HT condition and could be removed by washing. From these results, the merit of HTSW as a method of recovering solid fuel from MSW is considered to produce char with minimal carbon loss without a drying process prior to HTSW. In addition, Cl originating from PVC decomposes into soluble Cl compound under the HT condition. The combination of HTSW under the HT condition and char washing might improve the quality of char as alternative fuel.« less

Development and Verification of Enclosure Radiation Capabilities in the CHarring Ablator Response (CHAR) Code

NASA Technical Reports Server (NTRS)

Salazar, Giovanni; Droba, Justin C.; Oliver, Brandon; Amar, Adam J.

2016-01-01

With the recent development of multi-dimensional thermal protection system (TPS) material response codes, the capability to account for surface-to-surface radiation exchange in complex geometries is critical. This paper presents recent efforts to implement such capabilities in the CHarring Ablator Response (CHAR) code developed at NASA's Johnson Space Center. This work also describes the different numerical methods implemented in the code to compute geometric view factors for radiation problems involving multiple surfaces. Verification of the code's radiation capabilities and results of a code-to-code comparison are presented. Finally, a demonstration case of a two-dimensional ablating cavity with enclosure radiation accounting for a changing geometry is shown.

Charring Rate for Fire Exposed X-Lam

NASA Astrophysics Data System (ADS)

Wong, Bernice VY; Fah Tee, Kong

2017-06-01

Design of timber structures has been outlined in Eurocode 5. Notional charring rate for softwood and hardwood timber is given. For the performance of X-LAM panels in fire, only little information on charring is available and whether the fire behaviour of X-LAM is similar to homogenous timber panels has not yet been systematically analysed. This paper presents an overview of fire performance of X-LAM and evaluation of its resistance to elevated temperature as an element of structure in comparison to homogeneous timber panels. Numerical study has been carried out based on available experimental results. Charring rates for X-LAM panels obtained from experimental results are compared with those obtained from Eurocode 5 and proposed simplified model.

The thermal and mechanical properties of a low-density glass-fiber-reinforced elastomeric ablation material

NASA Technical Reports Server (NTRS)

Engelke, W. T.; Robertson, R. W.; Bush, A. L.; Pears, C. D.

1974-01-01

An evaluation of the thermal and mechanical properties was performed on a molded low-density elastomeric ablation material designated as Material B. Both the virgin and charred states were examined to provide meaningful inputs to the design of a thermal protection system. Chars representative of the flight chars formed during ablation were prepared in a laboratory furnace from 600 K to 1700 K and properties of effective thermal conductivity, heat capacity, porosity and permeability were determined on the furnace chars formed at various temperature levels within the range. This provided a boxing of the data which will enable the prediction of the transient response of the material during flight ablation.

Erosion characteristics of ethylene propylene diene monomer composite insulation by high-temperature dense particles

NASA Astrophysics Data System (ADS)

Li, Jiang; Guo, Meng-fei; Lv, Xiang; Liu, Yang; Xi, Kun; Guan, Yi-wen

2018-04-01

In this study, a dense particles erosion test motor which can simulate the erosion state of a solid rocket motor under high acceleration was developed. Subsequently, erosion experiments were carried out for the ethylene propylene diene monomer composite insulation and the microstructure of the char layer analysed. A turning point effect was found from the influence of the particle impact velocity on the ablation rate, and three erosion modes were determined according to the micro-morphology of the char layer. A reasonable explanation for the different structures of the char layer in the three modes was presented based on the formation mechanism of the compact/loose structure of the char layer.

Dwarf char, a new form of chars (the genus Salvelinus) in Lake Kronotskoe

USGS Publications Warehouse

Pavlov, S.D.; Pivovarov, E.A.; Ostberg, C.O.

2012-01-01

Lake Kronotskoe is situated in the Kronotskii State Nature Reserve and is a unique natural heritage of Kamchatka. The lake–river system of the reserve includes numerous springs and small streams and three large inflowing rivers, Listvennichnaya, Unana, and Uzon, which form the main bays of Lake Kronotskoe; one river (Kronotskaya) flows from the lake. This river is characterized by several rapids, which are assumed to be unsurmountable barriers for fish migration. The ichthyofauna of the lake has been isolated for a long time, and some endemic fishes appeared, including char of the genus Salvelinus and the residential form of red salmon Oncorhynchus nerka (the local name is kokanee). These species are perfect model objects to study microevolution processes. Char of Lake Kronotskoe are characterized by significant polymorphism and plasticity [1–3]; therefore, they are extremely valuable for studying the processes of speciation and form development. That is why the populations of char in Lake Kronotskoe are unique and attract special attention of researchers. 

Short-term effects of triiodothyronine on the bowfin, Amia calva (Holostei), and the lake char, Salvelinus namaycush (Teleostei).

PubMed

Ballantyne, J S; John, T M; Singer, T D; Oommen, O V

1992-01-01

To assess the role of triiodothyronine (T3) in mediating short-term changes in metabolism, such as those occurring in circadian patterns, we examined the effects of intraperitoneal injection of T3 on the oxidation of substrates by isolated mitochondria from liver of the bowfin, Amia calva, and red muscle and liver of the lake char, Salvelinus namaycush. Selected enzymes were measured in red muscle and liver of the lake char. Three hours after intraperitoneal injection of T3, oxidation of some substrates by mitochondria isolated from the liver of the bowfin was reduced. Similar treatment had no effect on substrate oxidation in liver mitochondria isolated from lake char. Oxidation of substrates by lake char red muscle mitochondria was stimulated by T3 injection. Citrate synthase levels were increased in red muscle suggesting that changes in enzyme activity may be in part responsible for the short-term mitochondrial responses to T3 injection.

CO2 gasification of char from lignocellulosic garden waste: Experimental and kinetic study.

PubMed

Gupta, Ankita; Thengane, Sonal K; Mahajani, Sanjay

2018-04-25

In this study, the dry leaves litter from jackfruit, raintree, mango and eucalyptus trees, lignin, and cellulose were characterized, pyrolysed, and evaluated for their char reactivity towards CO 2 gasification using TGA. The differences in char reactivity were attributed to the difference in char morphology and the varying inorganic contents. The mineral analysis of biomass ash showed the presence of alkali minerals some of which could act as catalysts. The adverse effect of high silica content was also evident through the experimental results. The kinetic parameters for gasification reaction were determined using three different reaction models. A modified random pore model was investigated to account for the influence of inorganic content. The effect of external catalyst on CO 2 gasification was also studied by adding potassium carbonate to biomass char and pellets. The results obtained from this study can be conveniently used in the design of a gasifier for lignocellulosic garden waste. Copyright © 2018 Elsevier Ltd. All rights reserved.

Behaviors of Char Gasification Based on Two-stage Gasifier of Biomass

NASA Astrophysics Data System (ADS)

Taniguchi, Miki; Sasauchi, Kenichi; Ahn, Chulju; Ito, Yusuke; Hayashi, Toshiaki; Akamatsu, Fumiteru

In order to develop a small-scale gasifier in which biomass can be converted to energy with high efficiency, we planed a gasification process that consists of two parts: pyrolysis part (rotary kiln) and gasification part (downdraft gasifier). We performed fundamental experiments on gasification part and discussed the apropriate conditions such as air supply location, air ratio, air temperature and hearth load. The following results was found: 1) the air supply into the char bed is more effective than that into the gas phase, 2) we can have the maximum cold gas efficiency of 80% on the following conditions: air supply location: char layer, air temperature: 20°C, air ratio: 0.2. 3) As air temperature is higher, the cold gas efficiency is larger. As for the hearth load, the cold gas efficiency becomes higher and reaches the constant level. It is expected from the results that high temperature in the char layer is effective on the char gasification.

Effect of torrefaction on the properties of rice straw high temperature pyrolysis char: Pore structure, aromaticity and gasification activity.

PubMed

Chen, Handing; Chen, Xueli; Qin, Yueqiang; Wei, Juntao; Liu, Haifeng

2017-03-01

The influence of torrefaction on the physicochemical characteristics of char during raw and water washed rice straw pyrolysis at 800-1200°C is investigated. Pore structure, aromaticity and gasification activity of pyrolysis chars are compared between raw and torrefied samples. For raw straw, BET specific surface area decreases with the increased torrefaction temperature at the same pyrolysis temperature and it approximately increases linearly with weight loss during pyrolysis. The different pore structure evolutions relate to the different volatile matters and pore structures between raw and torrefied straw. Torrefaction at higher temperature would bring about a lower graphitization degree of char during pyrolysis of raw straw. Pore structure and carbon crystalline structure evolutions of raw and torrefied water washed straw are different from these of raw straw during pyrolysis. For both raw and water washed straw, CO 2 gasification activities of pyrolysis chars are different between raw and torrefied samples. Copyright © 2016 Elsevier Ltd. All rights reserved.

Low levels of hybridization between sympatric Arctic char (Salvelinus alpinus) and Dolly Varden char (Salvelinus malma) highlights their genetic distinctiveness and ecological segregation.

PubMed

May-McNally, Shannan L; Quinn, Thomas P; Taylor, Eric B

2015-08-01

Understanding the extent of interspecific hybridization and how ecological segregation may influence hybridization requires comprehensively sampling different habitats over a range of life history stages. Arctic char (Salvelinus alpinus) and Dolly Varden (S. malma) are recently diverged salmonid fishes that come into contact in several areas of the North Pacific where they occasionally hybridize. To better quantify the degree of hybridization and ecological segregation between these taxa, we sampled over 700 fish from multiple lake (littoral and profundal) and stream sites in two large, interconnected southwestern Alaskan lakes. Individuals were genotyped at 12 microsatellite markers, and genetic admixture (Q) values generated through Bayesian-based clustering revealed hybridization levels generally lower than reported in a previous study (<0.6% to 5% of samples classified as late-generation hybrids). Dolly Varden and Arctic char tended to make different use of stream habitats with the latter apparently abandoning streams for lake habitats after 2-3 years of age. Our results support the distinct biological species status of Dolly Varden and Arctic char and suggest that ecological segregation may be an important factor limiting opportunities for hybridization and/or the ecological performance of hybrid char.

Low levels of hybridization between sympatric Arctic char (Salvelinus alpinus) and Dolly Varden char (Salvelinus malma) highlights their genetic distinctiveness and ecological segregation

PubMed Central

May-McNally, Shannan L; Quinn, Thomas P; Taylor, Eric B

2015-01-01

Understanding the extent of interspecific hybridization and how ecological segregation may influence hybridization requires comprehensively sampling different habitats over a range of life history stages. Arctic char (Salvelinus alpinus) and Dolly Varden (S. malma) are recently diverged salmonid fishes that come into contact in several areas of the North Pacific where they occasionally hybridize. To better quantify the degree of hybridization and ecological segregation between these taxa, we sampled over 700 fish from multiple lake (littoral and profundal) and stream sites in two large, interconnected southwestern Alaskan lakes. Individuals were genotyped at 12 microsatellite markers, and genetic admixture (Q) values generated through Bayesian-based clustering revealed hybridization levels generally lower than reported in a previous study (<0.6% to 5% of samples classified as late-generation hybrids). Dolly Varden and Arctic char tended to make different use of stream habitats with the latter apparently abandoning streams for lake habitats after 2–3 years of age. Our results support the distinct biological species status of Dolly Varden and Arctic char and suggest that ecological segregation may be an important factor limiting opportunities for hybridization and/or the ecological performance of hybrid char. PMID:26356310

Basic study of charring detection at the laser catheter-tip using back scattering light measurement during therapeutic laser irradiation in blood.

PubMed

Takahashi, Mei; Ito, Arisa; Kajihara, Takuro; Matsuo, Hiroki; Arai, Tsunenori

2010-01-01

The purpose of this study is to investigate transient process of the charring at the laser catheter-tip in blood during therapeutic laser irradiation by the back scattering light measurement to detect precursor state of the charring. We took account of using photodynamic therapy for arrhythmia in blood through the laser catheter. We observed the influence of the red laser irradiation (λ=663 nm) upon the shape of red blood cells (RBCs). The RBCs aggregation, round formation, and hemolysis were took place sequentially before charring. With a model blood sandwiched between glass plates simulated as a catheter-tip boundary, we measured diffuse-reflected-light power and transmitted-light power simultaneously and continuously by a microscopic optics during the laser irradiation. We found that measured light power changes were originated with RBCs shape change induced by temperature rise due to the laser irradiation. A gentle peak following a slow descending was observed in the diffuse-reflected-light power history. This history might indicate the precursor state of the charring, in which the hemolysis might be considered to advance rapidly. We think that the measurement of diffuse-reflected-light power history might be able to detect precursor state of charring at the catheter-tip in blood.

Temperature influence on the fast pyrolysis of manure samples: char, bio-oil and gases production

NASA Astrophysics Data System (ADS)

Fernandez-Lopez, Maria; Anastasakis, Kostas; De Jong, Wiebren; Valverde, Jose Luis; Sanchez-Silva, Luz

2017-11-01

Fast pyrolysis characterization of three dry manure samples was studied using a pyrolyzer. A heating rate of 600°C/s and a holding time of 10 s were selected to reproduce industrial conditions. The effect of the peak pyrolysis temperature (600, 800 and 1000°C) on the pyrolysis product yield and composition was evaluated. Char and bio-oil were gravimetrically quantified. Scanning electron microscopy (SEM) was used to analyse the char structure. H2, CH4, CO and CO2 were measured by means of gas chromatography (GC). A decrease in the char yield and an increase of the gas yield were observed when temperature increased. From 800°C on, it was observed that the char yield of samples Dig R and SW were constant, which indicated that the primary devolatilization reactions stopped. This fact was also corroborated by GC analysis. The bio-oil yield slightly increased with temperature, showing a maximum of 20.7 and 27.8 wt.% for samples Pre and SW, respectively, whereas sample Dig R showed a maximum yield of 16.5 wt.% at 800°C. CO2 and CO were the main released gases whereas H2 and CH4 production increased with temperature. Finally, an increase of char porosity was observed with temperature.

Preliminary study on quality evaluation of pecans with terahertz time-domain spectroscopy

NASA Astrophysics Data System (ADS)

Li, Bin; Cao, Wei; Mathanker, Sunil; Zhang, Weili; Wang, Ning

2010-11-01

This paper reports a preliminary work on a feasibility study of applying terahertz (THz) technology for pecan quality evaluation. A set of native pecan nuts collected in 2009 were used during the experiment. Each pecan nutmeat was manually sliced at a thickness of about 1mm, 2mm, and 3mm and a size of about 2cm (length) ×1cm (width). Pecan shell and inner separator were also cut into the same size. The absorption spectra for the nutmeat slices, shell, and inner separator were collected using a THz time-domain spectroscopy (THz-TDS) developed by a group of researchers at Oklahoma State University. The test results show that nutmeat, shell, and inner separator had different absorption characteristics within the bandwidth of 0.2-2.0 THz. To study the capability of insect damage detection of the THz spectroscopy, the absorption spectra of insects (living manduca sexta and dry pecan weevil) were also collected. Due to high water contents in the insects, very obvious spectral characteristics were found. The results from the preliminary study show a potential of THz technology applied for quality detection of bio-products. However, since bio-products mostly have high water content and are handled under an environment with certain levels of water content, practical issues needs to be further investigated to make the THz technology a feasible tool for quality evaluation.

Mutagenicity assessment of aerosols in emissions from domestic combustion processes.

PubMed

Canha, Nuno; Lopes, Isabel; Vicente, Estela Domingos; Vicente, Ana M; Bandowe, Benjamin A Musa; Almeida, Susana Marta; Alves, Célia A

2016-06-01

Domestic biofuel combustion is one of the major sources of regional and local air pollution, mainly regarding particulate matter and organic compounds, during winter periods. Mutagenic and carcinogenic activity potentials of the ambient particulate matter have been associated with the fraction of polycyclic aromatic hydrocarbons (PAH) and their oxygenated (OPAH) and nitrogenated (NPAH) derivatives. This study aimed at assessing the mutagenicity potential of the fraction of this polycyclic aromatic compound in particles (PM10) from domestic combustion by using the Ames assays with Salmonella typhimurium TA98 and TA100. Seven biofuels, including four types of pellets and three agro-fuels (olive pit, almond shell and shell of pine nuts), were tested in an automatic pellet stove, and two types of wood (Pinus pinaster, maritime pine, and Eucalyptus globulus, eucalypt) were burned in a traditional wood stove. For this latter appliance, two combustion phases-devolatilisation and flaming/smouldering-were characterised separately. A direct-acting mutagenic effect for the devolatilisation phase of pine combustion and for both phases of eucalypt combustion was found. Almond shell revealed a weak direct-acting mutagenic effect, while one type of pellets, made of recycled wastes, and pine (devolatilisation) presented a cytotoxic effect towards strain TA100. Compared to the manually fired appliance, the automatic pellet stove promoted lower polyaromatic mutagenic emissions. For this device, only two of the studied biofuels presented a weak mutagenic or cytotoxic potential.

Effects of water, sodium hypochlorite, peroxyacetic acid, and acidified sodium chlorite on in-shell hazelnuts inoculated with Salmonella enterica serovar Panama.

PubMed

Weller, Lisa D; Daeschel, Mark A; Durham, Catherine A; Morrissey, Michael T

2013-12-01

Recent foodborne disease outbreaks involving minimally processed tree nuts have generated a need for improved sanitation procedures. Chemical sprays and dips have shown promise for reducing pathogens on fresh produce, but little research has been conducted for in-shell hazelnuts. This study analyzed the effectiveness of 3 chemical sanitizers for reducing Salmonella on in-shell hazelnuts. Treatments of water, sodium hypochlorite (NaOCl; 25 and 50 ppm), peroxyacetic acid (PAA; 80 and 120 ppm), and acidified sodium chlorite (ASC; 450, 830, and 1013 ppm) were sprayed onto hazelnut samples inoculated with Salmonella enterica serovar Panama. Hazelnut samples were immersed in liquid cultures of S. Panama for 24 h, air-dried, and then sprayed with water and chemical treatments. Inoculation achieved S. Panama populations of approximately 8.04 log CFU/hazelnut. Surviving S. panama populations were evaluated using a nonselective medium (tryptic soy agar), incubated 3 h, and then overlaid with selective media (xylose lysine deoxycholate agar). All of the chemical treatments significantly reduced S. Panama populations (P ≤ 0.0001). The most effective concentrations of ASC, PAA, and NaOCl treatments reduced populations by 2.65, 1.46, and 0.66 log units, respectively. ASC showed the greatest potential for use as a postharvest sanitation treatment. © 2013 Institute of Food Technologists®

The effect of model fidelity on prediction of char burnout for single-particle coal combustion

DOE PAGES

McConnell, Josh; Sutherland, James C.

2016-07-09

In this study, practical simulation of industrial-scale coal combustion relies on the ability to accurately capture the dynamics of coal subprocesses while also ensuring the computational cost remains reasonable. The majority of the residence time occurs post-devolatilization, so it is of great importance that a balance between the computational efficiency and accuracy of char combustion models is carefully considered. In this work, we consider the importance of model fidelity during char combustion by comparing combinations of simple and complex gas and particle-phase chemistry models. Detailed kinetics based on the GRI 3.0 mechanism and infinitely-fast chemistry are considered in the gas-phase.more » The Char Conversion Kinetics model and nth-Order Langmuir–Hinshelwood model are considered for char consumption. For devolatilization, the Chemical Percolation and Devolatilization and Kobayashi-Sarofim models are employed. The relative importance of gasification versus oxidation reactions in air and oxyfuel environments is also examined for various coal types. Results are compared to previously published experimental data collected under laminar, single-particle conditions. Calculated particle temperature histories are strongly dependent on the choice of gas phase and char chemistry models, but only weakly dependent on the chosen devolatilization model. Particle mass calculations were found to be very sensitive to the choice of devolatilization model, but only somewhat sensitive to the choice of gas chemistry and char chemistry models. High-fidelity models for devolatilization generally resulted in particle temperature and mass calculations that were closer to experimentally observed values.« less

The effect of model fidelity on prediction of char burnout for single-particle coal combustion

DOE Office of Scientific and Technical Information (OSTI.GOV)

McConnell, Josh; Sutherland, James C.

In this study, practical simulation of industrial-scale coal combustion relies on the ability to accurately capture the dynamics of coal subprocesses while also ensuring the computational cost remains reasonable. The majority of the residence time occurs post-devolatilization, so it is of great importance that a balance between the computational efficiency and accuracy of char combustion models is carefully considered. In this work, we consider the importance of model fidelity during char combustion by comparing combinations of simple and complex gas and particle-phase chemistry models. Detailed kinetics based on the GRI 3.0 mechanism and infinitely-fast chemistry are considered in the gas-phase.more » The Char Conversion Kinetics model and nth-Order Langmuir–Hinshelwood model are considered for char consumption. For devolatilization, the Chemical Percolation and Devolatilization and Kobayashi-Sarofim models are employed. The relative importance of gasification versus oxidation reactions in air and oxyfuel environments is also examined for various coal types. Results are compared to previously published experimental data collected under laminar, single-particle conditions. Calculated particle temperature histories are strongly dependent on the choice of gas phase and char chemistry models, but only weakly dependent on the chosen devolatilization model. Particle mass calculations were found to be very sensitive to the choice of devolatilization model, but only somewhat sensitive to the choice of gas chemistry and char chemistry models. High-fidelity models for devolatilization generally resulted in particle temperature and mass calculations that were closer to experimentally observed values.« less

Studying the specific features pertinent to combustion of chars obtained from coals having different degrees of metamorphism and biomass chars

NASA Astrophysics Data System (ADS)

Bestsennyi, I. V.; Shchudlo, T. S.; Dunaevskaya, N. I.; Topal, A. I.

2013-12-01

Better conditions for igniting low-reaction coal (anthracite) can be obtained, higher fuel burnout ratio can be achieved, and the problem of shortage of a certain grade of coal can be solved by firing coal mixtures and by combusting coal jointly with solid biomass in coal-fired boilers. Results from studying the synergetic effect that had been revealed previously during the combustion of coal mixtures in flames are presented. A similar effect was also obtained during joint combustion of coal and wood in a flame. The kinetics pertinent to combustion of char mixtures obtained from coals characterized by different degrees of metamorphism and the kinetics pertinent to combustion of wood chars were studied on the RSK-1D laboratory setup. It was found from the experiments that the combustion rate of char mixtures obtained from coals having close degrees of metamorphism is equal to the value determined as a weighted mean rate with respect to the content of carbon. The combustion rate of char mixtures obtained from coals having essentially different degrees of metamorphism is close to the combustion rate of more reactive coal initially in the process and to the combustion rate of less reactive coal at the end of the process. A dependence of the specific burnout rate of carbon contained in the char of two wood fractions on reciprocal temperature in the range 663—833 K is obtained. The combustion mode of an experimental sample is determined together with the reaction rate constant and activation energy.

The potential applications of using compost chars for removing the hydrophobic herbicide atrazine from solution

USGS Publications Warehouse

Tsui, L.; Roy, W.R.

2008-01-01

One commercial compost sample was pyrolyzed to produce chars as a sorbent for removing the herbicide atrazine from solution. The sorption behavior of compost-based char was compared with that of an activated carbon derived from corn stillage. When compost was pyrolyzed, the char yield was greater than 45% when heated under air, and 52% when heated under N2. In contrast, when the corn stillage was pyrolyzed under N2, the yield was only 22%. The N2-BET surface area of corn stillage activated carbon was 439 m2/g, which was much greater than the maximum compost char surface area of 72 m2/g. However, the sorption affinity of the compost char for dissolved atrazine was comparable to that of the corn stillage activated carbon. This similarity could have resulted from the initial organic waste being subjected to a relatively long period of thermal processes during composting, and thus, the compost was more thermally stable when compared with the raw materials. In addition, microorganisms transformed the organic wastes into amorphous humic substances, and thus, it was likely that the microporisity was enhanced. Although this micropore structure could not be detected by the N2-BET method, it was apparent in the atrazine sorption experiment. Overall, the experimental results suggested that the compost sample in current study was a relatively stable material thermally for producing char, and that it has the potential as a feed stock for making high-quality activated carbon. ?? 2007 Elsevier Ltd. All rights reserved.

Gasification of the char derived from distillation of granulated scrap tyres.

PubMed

López, Félix A; Centeno, Teresa A; Alguacil, Francisco José; Lobato, Belén; López-Delgado, Aurora; Fermoso, Javier

2012-04-01

This work reports the effect of pressure on the steam/oxygen gasification at 1000°C of the char derived from low temperature-pressure distillation of granulated scrap tyres (GST). The study was based on the analysis of gas production, carbon conversion, cold gas efficiency and the high heating value (HHV) of the product. For comparison, similar analyses were carried out for the gasification of coals with different rank. In spite of the relatively high ash (≈12 wt.%) and sulphur (≈3 wt.%) contents, the char produced in GST distillation can be regarded as a reasonable solid fuel with a calorific value of 34MJkg(-1). The combustion properties of the char (E(A)≈50 kJ mol(-1)), its temperature of self-heating (≈264°C), ignition temperature (≈459°C) and burn-out temperature (≈676°C) were found to be similar to those of a semi-anthracite. It is observed that the yield, H(2) and CO contents and HHV of the syngas produced from char gasification increase with pressure. At 0.1 MPa, 4.6 Nm(3)kg(char)(-1) of syngas was produced, containing 28%v/v of H(2) and CO and with a HHV around 3.7 MJ Nm(-3). At 1.5 MPa, the syngas yield achieved 4.9N m(3)kg(char)(-1) with 30%v/v of H(2)-CO and HHV of 4.1 MJ Nm(-3). Carbon conversion significantly increased from 87% at 0.1 MPa to 98% at 1.5 MPa. It is shown that the char derived from distillation of granulated scrap tyres can be further gasified to render a gas of considerable heating value, especially when gasification proceeds at high pressure. Copyright © 2011 Elsevier Ltd. All rights reserved.

Cow bones char as a green sorbent for fluorides removal from aqueous solutions: batch and fixed-bed studies.

PubMed

Nigri, Elbert M; Cechinel, Maria Alice P; Mayer, Diego A; Mazur, Luciana P; Loureiro, José M; Rocha, Sônia D F; Vilar, Vítor J P

2017-01-01

Cow bone char was investigated as sorbent for the defluoridation of aqueous solutions. The cow bone char was characterized in terms of its morphology, chemical composition, and functional groups present on the bone char surface using different analytical techniques: SEM, EDS, N 2 -BET method, and FTIR. Batch equilibrium studies were performed for the bone chars prepared using different procedures. The highest sorption capacities for fluoride were obtained for the acid washed (q = 6.2 ± 0.5 mg/g) and Al-doped (q = 6.4 ± 0.3 mg/g) bone chars. Langmuir and Freundlich models fitted well the equilibrium sorption data. Fluoride removal rate in batch system is fast in the first 5 h, decreasing after this time until achieving equilibrium due to pore diffusion. The presence of carbonate and bicarbonate ions in the aqueous solution contributes to a decrease of the fluoride sorption capacity of the bone char by 79 and 31 %, respectively. Regeneration of the F-loaded bone char using 0.5 M NaOH solution leads to a sorption capacity for fluoride of 3.1 mg/g in the second loading cycle. Fluoride breakthrough curve obtained in a fixed-bed column presents an asymmetrical S-shaped form, with a slow approach of C/C 0  → 1.0 due to pore diffusion phenomena. Considering the guideline value for drinking water of 1.5 mg F - /L, as recommended by World Health Organization, the service cycle for fluoride removal was of 71.0 h ([F - ] feed  ∼ 9 mg/L; flow rate = 1 mL/min; m sorbent  = 12.6 g). A mass transfer model considering the pore diffusion was able to satisfactorily describe the experimental data obtained in batch and continuous systems.

[Etiology and prognosis of the eye traumas by war weapons in the Senegalese army].

PubMed

Seck, S M; Diakhaté, M; Ndiaye Sow, M N; Dieng, M; Agboton, G; Guèye, N N

2017-02-01

The aim of this work is to identify the main weapons causing eye injuries during the campaigns of the Senegalese army in the south of the country, as well as the prognosis of these traumas. This study is retrospective and concerns soldiers wounded by the weapons of war during the exercise of their mission within the Senegalese armed forces of 1991 in 2005. They are mainly soldiers affected in the south of the country during a war, clashes with the rebels or in Guinea-Bissau during operation Gabou in 1998. And they were evacuated to the ophthalmology department of the Principal Hospital in Dakar, which is a level 3. Thirty-seven military all male, with an average age of 30.5 years. Forty-six eyes including 9 bilateral cases. The trauma agent is a burst of RPG7 shells in 62% of cases, mine explosion in 13.5%, offensive grenade 10.8%, assault rifle 5.7% and flame lance-roquette anti-char (LRAC) accounts for 8%. We noted a phthisis of the globe for 14 eyes (30.43%) and for 15 eyes (32.60%) a functional loss of the affected globe. Inability to fight was decided by 29 wounded soldiers (78.37% of the cases), sedentary employment in 27 cases (72.97%) and 10 cases (27.03%) of reformed soldiers. In the conflict in southern Senegal, the RPG7 shell burst causes 62% of eye injuries. This RPG7 shell called "rebel weapon" is frequently used in conflicts in Africa. The prognosis of trauma with these types of weapons is severe. The combat goggles systematically integrated in the equipment of the Senegalese combatant, would be an invaluable contribution on the prevention of the traumatisms of the eye. Copyright © 2016 Elsevier Masson SAS. All rights reserved.

User Interface to an ICAI System That Teaches Discrete Math

DTIC Science & Technology

1990-06-01

lesson; otherwise, returns the user to the lesson. */ if (!frornlsn) menudeino); else exit((); 90 FUNCTION . flashcards CALLED BY: tools CALLS...char opchar[5j; /* OR, AND, IMPLIES or 1FF * char anchar[5J: /* User’s response: Either TRUE or FALSE * char outputch[ 15]; /* Flashcard that is...y values for the user’s screen. */ maxx = getmaxxo ; maxy = getmaxyo ; /* Sets the coordinates for the flashcard . */ left = maxx/6 right = maxx* 5/6

A new mathematical solution for predicting char activation reactions

USGS Publications Warehouse

Rafsanjani, H.H.; Jamshidi, E.; Rostam-Abadi, M.

2002-01-01

The differential conservation equations that describe typical gas-solid reactions, such as activation of coal chars, yield a set of coupled second-order partial differential equations. The solution of these coupled equations by exact analytical methods is impossible. In addition, an approximate or exact solution only provides predictions for either reaction- or diffusion-controlling cases. A new mathematical solution, the quantize method (QM), was applied to predict the gasification rates of coal char when both chemical reaction and diffusion through the porous char are present. Carbon conversion rates predicted by the QM were in closer agreement with the experimental data than those predicted by the random pore model and the simple particle model. ?? 2002 Elsevier Science Ltd. All rights reserved.

The mixture of cashew nut shell liquid and castor oil results in an efficient larvicide against Aedes aegypti that does not alter embryo-fetal development, reproductive performance or DNA integrity

PubMed Central

Vani, Juliana Miron; Monreal, Maria Tereza Ferreira Duenhas; Auharek, Sarah Alves; Cunha-Laura, Andréa Luiza; de Arruda, Eduardo José; Lima, Alessandra Ramos; da Silva, Cicera Maria; Antoniolli-Silva, Andréia Conceição Milan Brochado; de Lima, Dênis Pires; Beatriz, Adilson

2018-01-01

Dengue fever, chikungunya fever and Zika virus are epidemics in Brazil that are transmitted by mosquitoes, such as Aedes aegypti or Aedes albopictus. The liquid from shells of cashew nuts is attractive for its important biological and therapeutic activities, which include toxicity to mosquitoes of the genus Aedes. The present study evaluated the effects of a mixture of surfactants from natural cashew nutshell liquid and castor oil (named TaLCC-20) on the mortality of larvae and on the reproductive performance, embryonic and fetal development and genetic stability of Swiss mice. A total of 400 Ae. aegypti larvae (third larval stage) were treated with TaLCC-20 concentrations of 0.05 mg/L, 0.5 mg/L, or 5 mg/L (ppm). Twenty pregnant female mice were also orally administered TaLCC-20 at doses of 5 mg/kg and 50 mg/kg body weight (b.w.), and 10 animals were given only drinking water at 0.1 mL/10 g b.w. (orally). The results of a larvicide test demonstrated that 5 mg/mL TaLCC-20 killed 100% of larvae within three hours, which is comparable to the gold standard indicated by the Ministry of Health. Overall, these results show that TaLCC-20 is an efficient larvicide that does not induce genetic damage. In addition, changes in reproductive performance and embryo-fetal development appear positive, and the formulation is cost effective. Therefore, TaLCC-20 is an important product in the exploration of natural larvicides and can assist in fighting mosquitos as vectors for dengue fever, chikungunya fever and Zika virus, which are emerging/re-emerging and require proper management to ensure minimal harm to the human population. Therefore, TaLCC-20 can be considered a key alternative to commercial products, which are effective yet toxigenic. PMID:29554095

The mixture of cashew nut shell liquid and castor oil results in an efficient larvicide against Aedes aegypti that does not alter embryo-fetal development, reproductive performance or DNA integrity.

PubMed

Vani, Juliana Miron; Monreal, Maria Tereza Ferreira Duenhas; Auharek, Sarah Alves; Cunha-Laura, Andréa Luiza; de Arruda, Eduardo José; Lima, Alessandra Ramos; da Silva, Cicera Maria; Antoniolli-Silva, Andréia Conceição Milan Brochado; de Lima, Dênis Pires; Beatriz, Adilson; Oliveira, Rodrigo Juliano

2018-01-01

Dengue fever, chikungunya fever and Zika virus are epidemics in Brazil that are transmitted by mosquitoes, such as Aedes aegypti or Aedes albopictus. The liquid from shells of cashew nuts is attractive for its important biological and therapeutic activities, which include toxicity to mosquitoes of the genus Aedes. The present study evaluated the effects of a mixture of surfactants from natural cashew nutshell liquid and castor oil (named TaLCC-20) on the mortality of larvae and on the reproductive performance, embryonic and fetal development and genetic stability of Swiss mice. A total of 400 Ae. aegypti larvae (third larval stage) were treated with TaLCC-20 concentrations of 0.05 mg/L, 0.5 mg/L, or 5 mg/L (ppm). Twenty pregnant female mice were also orally administered TaLCC-20 at doses of 5 mg/kg and 50 mg/kg body weight (b.w.), and 10 animals were given only drinking water at 0.1 mL/10 g b.w. (orally). The results of a larvicide test demonstrated that 5 mg/mL TaLCC-20 killed 100% of larvae within three hours, which is comparable to the gold standard indicated by the Ministry of Health. Overall, these results show that TaLCC-20 is an efficient larvicide that does not induce genetic damage. In addition, changes in reproductive performance and embryo-fetal development appear positive, and the formulation is cost effective. Therefore, TaLCC-20 is an important product in the exploration of natural larvicides and can assist in fighting mosquitos as vectors for dengue fever, chikungunya fever and Zika virus, which are emerging/re-emerging and require proper management to ensure minimal harm to the human population. Therefore, TaLCC-20 can be considered a key alternative to commercial products, which are effective yet toxigenic.

Removal of Cd(II), Pb(II) and Cr(III) from water using modified residues of Anacardium occidentale L.

NASA Astrophysics Data System (ADS)

Coelho, Gustavo Ferreira; Gonçalves, Affonso Celso; Schwantes, Daniel; Rodríguez, Esperanza Álvarez; Tarley, César Ricardo Teixeira; Dragunski, Douglas; Conradi Junior, Élio

2018-06-01

The pollution of water has been one of the greatest problems faced by the modern society, due to industrialization and urban growth. Rivers, lakes and seas have been continually suffering from the rising concentration of various pollutants, especially toxic elements. This study aimed to evaluate the use of cashew nut shell ( Anacardium occidentale) (CNS), after chemical modification with H2O2, H2SO4 and NaOH, as an new and renewable adsorbent material, for the removal of metals Cd2+, Pb2+ and Cr3+ in aqueous medium. The adsorbents were characterized by its chemical constitution, structure, infrared spectroscopy, morphology, by means of scanning electron microscopy, determination of the point of zero charge, thermogravimetrical analysis and porosimetry assessments. Tests were conducted to determine the optimal conditions (pH vs. adsorbent mass) for adsorption, by means of multivariate analysis using a central composite design. The adsorption kinetics was evaluated by models of pseudo-first order, pseudo-second order, Elovich and intraparticle diffusion, while adsorption isotherms were linearized by Langmuir, Freundlich and Dubinin-Radushkevich. The effect of initial concentration, temperature and desorption was also performed. The adsorbents exhibited irregular, spongy and heterogeneous structure. FTIR analysis confirms the presence of hydroxyl, aliphatic, phenolic and carboxylic acid groups, which are favorable adsorption characteristics. The pHPZC of adsorbent is 4.35, 2.50 e 6.92, respectively, for CNS H2O2, H2SO4 and NaOH. The optimum adsorption conditions were as follows: pH 5.0; relation of adsorbent mass/volume of water: 4 g L-1; 40 min of contact time for reaching the equilibration. Results suggest the predominance of chemisorption of Cd2+ and Cr3+. Most of biosorbents exhibited good fit by Langmuir and Freundlich, suggesting the occurrence of adsorption on mono- and multilayers. The adsorbents of cashew nut shell exhibited high removal efficiency of Cd, Pb and Cr from waters.

Tree nut oils

USDA-ARS?s Scientific Manuscript database

The major tree nuts include almonds, Brazil nuts, cashew nuts, hazelnuts, macadamia nuts, pecans, pine nuts, pistachio nuts, and walnuts. Tree nut oils are appreciated in food applications because of their flavors and are generally more expensive than other gourmet oils. Research during the last de...

Biochemical stability of sewage sludge chars and their impact on soil organic matter of a Mediterranean Cambisol

NASA Astrophysics Data System (ADS)

Paneque, Marina; María De la Rosa, José; Aragón, Carlos; Kern, Jürgen; Knicker, Heike

2016-04-01

Transformation of sewage sludge (SS) into char achieves sludge hygienisation, which is necessary prior its application into agricultural soils. The pyrolysis of SS increases its stability in a degree which depends on the thermal treatment used. Thus, chars produced by using hydrothermal carbonization are typically more stable than normal soil organic matter (SOM), but less stable than chars from dry pyrolysis (Libra et al., 2011). Addition of highly-recalcitrant SS-chars to soil will likely increase its carbon sequestration potential; however the fertilizing properties of SS may be compromised due to its alteration during the pyrolysis. The main goal of this work was to investigate the biochemical recalcitrance of two 13C-enriched SS-chars once applied in a Mediterranean Cambisol as well as to evaluate their impact on the SOM quality and carbon stability. Thus, we studied the distribution of 13C between plants and soil after the addition of the 13C-enriched chars (2 atm%) to the soil. Therefore, we performed a greenhouse incubation experiment, using a Mediterranean Cambisol as matrix and tested the following treatments: control (soil alone), raw SS, SS-hydrochar, SS-pyrochar. The SS was produced in a pilot-scale waste-water plant and enriched with 13C by the addition of 13C-glucose during the treatment. The amendment was only applied to the upper 2 cm of the soil matrix where it accounted for 5% of its dry weight. Per pot, 25 seeds of Lolium perenne were sowed and incubated under controlled conditions. The biomass production as well as the concentration of 13C in leaves and roots was determined after 1, 2 and 5 months. The partitioning of the 13C between soil and plant and its transformation into bioavailable forms were monitored by stable isotopic mass spectrometry. The 13C-enrichment of the chars allowed the use of solid-state 13C NMR spectroscopy as a means for the detection of chemical alterations of the chars during their aging. Libra J., Ro K., Kammann C., Funke A., Berge N., Neubauer Y., Titirici M., Fuhner C., Bens O., Kern J., Emmerich K. (2011) Hydrothermal carbonization of biomass residuals: a comparative review of the chemistry, processes and applications of wet and dry pyrolysis. Biofuels, 2 (1), 89-124.

Acidification with nitric acid improves chemical characteristics and reduces phytotoxicity of alkaline chars.

PubMed

Fornes, Fernando; Belda, Rosa Maria

2017-04-15

Charred organic matter is recently receiving attention for its potential use as soilless growth medium. However, depending on its origin and on the manufacturing technology, it can result toxic for plants. This fact implies that a detoxifying treatment ought to be devised in order to reclaim char in this way. We have studied three materials which combine these factors: two pyrolyzed biochars, one from forest waste (BCH-FW) and another from olive mill waste (BCH-OMW), and one hydrothermally carbonized hydrochar from forest waste (HYD-FW). These materials are suspicious of phytotoxicity due to their high pH, high salinity, or presence of organic toxics. For these new materials, it is mandatory to select fast and reliable bioassays to predict their potential phytotoxicity. In order to achieve this goal water extracts of the three chars were subjected to bioassays of seed germination and bioassays of seedling growth in hydroponic conditions. The biochar from olive mill waste and the hydrochar, but not the biochar from forest waste, showed considerable phytotoxicity as seed germination and plant growth were negatively affected (e.g. BCH-OMW reduced seed germination by 80% and caused early seedling death). In order to adjust pH and electrical conductivity for plant growth, treatments of acidification and salt leaching with optimal diluted HNO 3 solutions (0.3 N, 0.2 N, and 0.75 N for BCH-OMW, BCH-FW, and HYD-FW, respectively) as calculated from titration curves, were conducted. The acid treatment reduced electrical conductivity in BCH-OMW (from 9.2 to 4.5 dS m -1 ), pH (maximum in BCH-FW from 9.6 to 6.2) and water soluble carbonaceous compounds (maximum in HYD-FW from 5969 to 2145 mg kg -1 ) in the three chars, and increased N content (maximum in BCH-OMW from 50 to 6342 mg kg -1 ) in the three chars. Bioassays on acid-treated chars demonstrated the absence of phytotoxicity and even stimulation of seedling growth over the control (increase of 86% and 56% for BCH-FW and HYD-FW, respectively). We conclude that acidification of chars with diluted HNO 3 is a viable technique to conform chars to standards for plant growth purposes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Tree Nut Allergies

MedlinePlus

... Blog Vision Awards Common Allergens Tree Nut Allergy Tree Nut Allergy Learn about tree nut allergy, how ... a Tree Nut Label card . Allergic Reactions to Tree Nuts Tree nuts can cause a severe and ...

Simultaneous sonosynthesis and sonofabrication of N-doped ZnO/TiO2 core-shell nanocomposite on wool fabric: Introducing various properties specially nano photo bleaching.

PubMed

Behzadnia, Amir; Montazer, Majid; Rad, Mahnaz Mahmoudi

2015-11-01

In this study, N-doped ZnO/TiO2 core-shell nanocomposite was successfully sonosynthesized and sonofabricated on wool fabric through a facile one-step method under ambient pressure and low temperature (75-80°C) as a novel photo-catalyst nanocomposite on textile material. The differences between crystalline phase transformation of conventional and ultrasound synthesized N-ZnO/TiO2 has been compared. The influence of different zinc acetate and titanium isopropoxide precursors in the formation of nanocomposite was studied and optimized through response surface methodology. The photocatalytic activity of the sonofabricated catalyst on the wool fabric surface was evaluated through decomposition of Methylene Blue as a model compound under sunlight irradiation. Also, N-doped ZnO/TiO2 nanocomposite sonosynthesized on wool fabric led to photo bleaching of wool fabric due to decomposition of the naturally occurred pigments under daylight irradiation. Further, yellowness index, antibacterial and antifungal activity against Escherichia coli, Staphylococcus aureus and Candida albicans, cell viability, char residual, alkali solubility, mechanical properties and water drop absorption time on the treated wool fabrics were evaluated. Also, the acid solubility of the synthesized nanopowder obtained from sonobath after treatment was characterized in acetic acid indicating higher acid resistance on N-doped ZnO/TiO2 nanocomposite. Copyright © 2015 Elsevier B.V. All rights reserved.

Understanding how lake populations of arctic char are structured and function with special consideration of the potential effects of climate change: a multi-faceted approach.

PubMed

Budy, Phaedra; Luecke, Chris

2014-09-01

Size dimorphism in fish populations, both its causes and consequences, has been an area of considerable focus; however, uncertainty remains whether size dimorphism is dynamic or stabilizing and about the role of exogenous factors. Here, we explored patterns among empirical vital rates, population structure, abundance and trend, and predicted the effects of climate change on populations of arctic char (Salvelinus alpinus) in two lakes. Both populations cycle dramatically between dominance by small (≤300 mm) and large (>300 mm) char. Apparent survival (Φ) and specific growth rates (SGR) were relatively high (40-96%; SGR range 0.03-1.5%) and comparable to those of conspecifics at lower latitudes. Climate change scenarios mimicked observed patterns of warming and resulted in temperatures closer to optimal for char growth (15.15 °C) and a longer growing season. An increase in consumption rates (28-34%) under climate change scenarios led to much greater growth rates (23-34%). Higher growth rates predicted under climate change resulted in an even greater predicted amplitude of cycles in population structure as well as an increase in reproductive output (Ro) and decrease in generation time (Go). Collectively, these results indicate arctic char populations (not just individuals) are extremely sensitive to small changes in the number of ice-free days. We hypothesize years with a longer growing season, predicted to occur more often under climate change, produce elevated growth rates of small char and act in a manner similar to a "resource pulse," allowing a sub-set of small char to "break through," thus setting the cycle in population structure.

Understanding how lake populations of arctic char are structured and function with special consideration of the potential effects of climate change: A multi-faceted approach.

USGS Publications Warehouse

Budy, Phaedra; Luecke, Chris

2014-01-01

Size dimorphism in fish populations, both its causes and consequences, has been an area of considerable focus; however, uncertainty remains whether size dimorphism is dynamic or stabilizing and about the role of exogenous factors. Here, we explored patterns among empirical vital rates, population structure, abundance and trend, and predicted the effects of climate change on populations of arctic char (Salvelinus alpinus) in two lakes. Both populations cycle dramatically between dominance by small (≤300 mm) and large (>300 mm) char. Apparent survival (Φ) and specific growth rates (SGR) were relatively high (40–96 %; SGR range 0.03–1.5 %) and comparable to those of conspecifics at lower latitudes. Climate change scenarios mimicked observed patterns of warming and resulted in temperatures closer to optimal for char growth (15.15 °C) and a longer growing season. An increase in consumption rates (28–34 %) under climate change scenarios led to much greater growth rates (23–34 %). Higher growth rates predicted under climate change resulted in an even greater predicted amplitude of cycles in population structure as well as an increase in reproductive output (Ro) and decrease in generation time (Go). Collectively, these results indicate arctic char populations (not just individuals) are extremely sensitive to small changes in the number of ice-free days. We hypothesize years with a longer growing season, predicted to occur more often under climate change, produce elevated growth rates of small char and act in a manner similar to a “resource pulse,” allowing a sub-set of small char to “break through,” thus setting the cycle in population structure.

Stronger association of polycyclic aromatic hydrocarbons with soot than with char in soils and sediments

PubMed Central

Han, Y.M.; Bandowe, B.A.M.; Wei, C.; Cao, J.J.; Wilcke, W.; Wang, G.H.; Ni, H.Y.; Jin, Z.D.; An, Z.S.; Yan, B.Z.

2016-01-01

The knowledge of the association of polycyclic aromatic hydrocarbons (PAHs) with organic matter and carbonaceous materials is critical for a better understanding of their environmental transport, fate, and toxicological effects. Extensive studies have been done with regard to the relationship of PAHs with total organic carbon (TOC) and elemental carbon (EC) in different environmental matrices. The relationship between PAHs and the two subtypes of EC, char (combustion residues) and soot (produced via gas-to-particle conversion) also has been tested in field and laboratory experiments using reference materials. However, a direct comparison of associations of PAHs between with char and with soot in real environmental matrices has to our knowledge not yet been reported because of a lack of methodology to differentiate them. In this study, char and soot were measured using the IMPROVE method to test their associations with 12 EPA priority PAHs measured in topsoil samples (N = 22, top 10 cm) collected from the Guanzhong Plain and in surface sediment samples (N = 32, top 5 cm) from the Wei River (central China). In both soils and sediments, Σ12PAHs were more strongly associated with soot than with char, mainly due to the fact that soot and PAHs were produced in the same gas phase during combustion, had a strong affinity for each other, and were transported and deposited together, while char, the combustion residue, was transported differently to PAHs due to its large particle size. Stronger correlations between PAHs and the different carbon fractions (TOC, soot, and char) in sediments than in soils were observed, which is associated with the redistribution of PAHs among the organic matter pools in water because of the processes during soil erosion and sedimentation in the river. PMID:24656973

Preference for cannibalism and ontogenetic constraints in competitive ability of piscivorous top predators.

PubMed

Byström, Pär; Ask, Per; Andersson, Jens; Persson, Lennart

2013-01-01

Occurrence of cannibalism and inferior competitive ability of predators compared to their prey have been suggested to promote coexistence in size-structured intraguild predation (IGP) systems. The intrinsic size-structure of fish provides the necessary prerequisites to test whether the above mechanisms are general features of species interactions in fish communities where IGP is common. We first experimentally tested whether Arctic char (Salvelinus alpinus) were more efficient as a cannibal than as an interspecific predator on the prey fish ninespine stickleback (Pungitius pungitius) and whether ninespine stickleback were a more efficient competitor on the shared zooplankton prey than its predator, Arctic char. Secondly, we performed a literature survey to evaluate if piscivores in general are more efficient as cannibals than as interspecific predators and whether piscivores are inferior competitors on shared resources compared to their prey fish species. Both controlled pool experiments and outdoor pond experiments showed that char imposed a higher mortality on YOY char than on ninespine sticklebacks, suggesting that piscivorous char is a more efficient cannibal than interspecific predator. Estimates of size dependent attack rates on zooplankton further showed a consistently higher attack rate of ninespine sticklebacks compared to similar sized char on zooplankton, suggesting that ninespine stickleback is a more efficient competitor than char on zooplankton resources. The literature survey showed that piscivorous top consumers generally selected conspecifics over interspecific prey, and that prey species are competitively superior compared to juvenile piscivorous species in the zooplankton niche. We suggest that the observed selectivity for cannibal prey over interspecific prey and the competitive advantage of prey species over juvenile piscivores are common features in fish communities and that the observed selectivity for cannibalism over interspecific prey has the potential to mediate coexistence in size structured intraguild predation systems.

Preference for Cannibalism and Ontogenetic Constraints in Competitive Ability of Piscivorous Top Predators

PubMed Central

Byström, Pär; Ask, Per; Andersson, Jens; Persson, Lennart

2013-01-01

Occurrence of cannibalism and inferior competitive ability of predators compared to their prey have been suggested to promote coexistence in size-structured intraguild predation (IGP) systems. The intrinsic size-structure of fish provides the necessary prerequisites to test whether the above mechanisms are general features of species interactions in fish communities where IGP is common. We first experimentally tested whether Arctic char (Salvelinus alpinus) were more efficient as a cannibal than as an interspecific predator on the prey fish ninespine stickleback (Pungitius pungitius) and whether ninespine stickleback were a more efficient competitor on the shared zooplankton prey than its predator, Arctic char. Secondly, we performed a literature survey to evaluate if piscivores in general are more efficient as cannibals than as interspecific predators and whether piscivores are inferior competitors on shared resources compared to their prey fish species. Both controlled pool experiments and outdoor pond experiments showed that char imposed a higher mortality on YOY char than on ninespine sticklebacks, suggesting that piscivorous char is a more efficient cannibal than interspecific predator. Estimates of size dependent attack rates on zooplankton further showed a consistently higher attack rate of ninespine sticklebacks compared to similar sized char on zooplankton, suggesting that ninespine stickleback is a more efficient competitor than char on zooplankton resources. The literature survey showed that piscivorous top consumers generally selected conspecifics over interspecific prey, and that prey species are competitively superior compared to juvenile piscivorous species in the zooplankton niche. We suggest that the observed selectivity for cannibal prey over interspecific prey and the competitive advantage of prey species over juvenile piscivores are common features in fish communities and that the observed selectivity for cannibalism over interspecific prey has the potential to mediate coexistence in size structured intraguild predation systems. PMID:23894650

Recovery of solid fuel from municipal solid waste by hydrothermal treatment using subcritical water.

PubMed

Hwang, In-Hee; Aoyama, Hiroya; Matsuto, Toshihiko; Nakagishi, Tatsuhiro; Matsuo, Takayuki

2012-03-01

Hydrothermal treatments using subcritical water (HTSW) such as that at 234°C and 3MPa (LT condition) and 295°C and 8MPa (HT condition) were investigated to recover solid fuel from municipal solid waste (MSW). Printing paper, dog food (DF), wooden chopsticks, and mixed plastic film and sheets of polyethylene, polypropylene, and polystyrene were prepared as model MSW components, in which polyvinylchloride (PVC) powder and sodium chloride were used to simulate Cl sources. While more than 75% of carbon in paper, DF, and wood was recovered as char under both LT and HT conditions, plastics did not degrade under either LT or HT conditions. The heating value (HV) of obtained char was 13,886-27,544 kJ/kg and was comparable to that of brown coal and lignite. Higher formation of fixed carbon and greater oxygen dissociation during HTSW were thought to improve the HV of char. Cl atoms added as PVC powder and sodium chloride to raw material remained in char after HTSW. However, most Cl originating from PVC was found to converse into soluble Cl compounds during HTSW under the HT condition and could be removed by washing. From these results, the merit of HTSW as a method of recovering solid fuel from MSW is considered to produce char with minimal carbon loss without a drying process prior to HTSW. In addition, Cl originating from PVC decomposes into soluble Cl compound under the HT condition. The combination of HTSW under the HT condition and char washing might improve the quality of char as alternative fuel. Copyright © 2011 Elsevier Ltd. All rights reserved.

The effectiveness of spent coffee grounds and its biochar on the amelioration of heavy metals-contaminated water and soil using chemical and biological assessments.

PubMed

Kim, Min-Suk; Min, Hyun-Gi; Koo, Namin; Park, Jeongsik; Lee, Sang-Hwan; Bak, Gwan-In; Kim, Jeong-Gyu

2014-12-15

Spent coffee grounds (SCG) and charred spent coffee grounds (SCG-char) have been widely used to adsorb or to amend heavy metals that contaminate water or soil and their success is usually assessed by chemical analysis. In this work, the effects of SCG and SCG-char on metal-contaminated water and soil were evaluated using chemical and biological assessments; a phytotoxicity test using bok choy (Brassica campestris L. ssp. chinensis Jusl.) was conducted for the biological assessment. When SCG and SCG-char were applied to acid mine drainage, the heavy metal concentrations were decreased and the pH was increased. However, for SCG, the phytotoxicity increased because a massive amount of dissolved organic carbon was released from SCG. In contrast, SCG-char did not exhibit this phenomenon because any easily released organic matter was removed during pyrolysis. While the bioavailable heavy metal content decreased in soils treated with SCG or SCG-char, the phytotoxicity only rose after SCG treatment. According to our statistical methodology, bioavailable Pb, Cu and As, as well as the electrical conductivity representing an increase in organic content, affected the phytotoxicity of soil. Therefore, applying SCG during environment remediation requires careful biological assessments and evaluations of the efficiency of this remediation technology. Copyright © 2014 Elsevier Ltd. All rights reserved.

Evaluation of a Technology-Based Adaptive Learning and Prevention Program for Stress Response-A Randomized Controlled Trial.

PubMed

Wesemann, Ulrich; Kowalski, Jens T; Jacobsen, Thomas; Beudt, Susan; Jacobs, Herbert; Fehr, Julia; Büchler, Jana; Zimmermann, Peter L

2016-08-01

To prevent deployment-related disorders, Chaos Driven Situations Management Retrieval System (CHARLY), a computer-aided training platform with a biofeedback interface has been developed. It simulates critical situations photorealistic for certain target and occupational groups. CHARLY was evaluated as a 1.5 days predeployment training method comparing it with the routine training. The evaluation was carried out for a matched random sample of N = 67 soldiers deployed in Afghanistan (International Security Assistance Force). Data collection took place before and after the prevention program and 4 to 6 weeks after deployment, which included mental state, post-traumatic stress disorder (PTSD) symptoms, knowledge of and attitude toward PTSD, and deployment-specific stressors. CHARLY has been significantly superior to the control group in terms of psychoeducation and attitude change. As to the mental state, both groups showed a significant increase in stress after deployment with significant lower increase in CHARLY. For PTSD-specific symptoms, CHARLY achieved a significant superiority. The fact that PTSD-specific scales showed significant differences at the end of deployment substantiates the validity of a specifically preventive effect of CHARLY. The study results tentatively indicate that highly standardized, computer-based primary prevention of mental disorders in soldiers on deployment might be superior to other more personal and less standardized forms of prevention. Reprint & Copyright © 2016 Association of Military Surgeons of the U.S.

Changes of chromium speciation and organic matter during low-temperature pyrolysis of tannery sludge.

PubMed

Zhou, Jianjun; Ma, Hongrui; Gao, Mao; Sun, Wenyue; Zhu, Chao; Chen, Xiangping

2018-01-01

The application or disposal of char derived from tannery sludge is directly influenced by the mobility and bioavailability of Cr during pyrolysis process. This study focused on the changes of Cr speciation and organic matter in tannery sludge during low-temperature pyrolysis (100-400 °C) to evaluate the toxicity of char in terms of the leaching possibility of Cr. The results showed that (1) lower char yield and more porous structure were observed after pyrolysis. (2) Higher pyrolysis temperature increased Cr content in the char; however, Cr in this case was converted into the residual fraction which minimized its bioavailability therefore lowers its potential risk to the environment. (3) Organic matters in the acid and alkali leachates were mainly humic acid-like substance, and condensed organic matter might appear at 200 °C and then destruct. (4) Despite the comparatively high content of Cr in the char, the leaching toxicity of char was within the security range according to the national standard of China. The Cr content in the acid and alkali leachates decreased to the range of 16.5-35.3 and 0.2-6.8 mg/L, respectively. It was suggested that the potential toxicity of tannery sludge from Cr could be reduced before utilization or disposal by pyrolysis, especially under 400 °C.

Pyrolysis of Lantana camara and Mimosa pigra: Influences of temperature, other process parameters and incondensable gas evolution on char yield and higher heating value.

PubMed

Mundike, Jhonnah; Collard, François-Xavier; Görgens, Johann F

2017-11-01

Pyrolysis of invasive non-indigenous plants, Lantana camara (LC) and Mimosa pigra (MP) was conducted at milligram-scale for optimisation of temperature, heating rate and hold time on char yield and higher heating value (HHV). The impact of scaling-up to gram-scale was also studied, with chromatography used to correlate gas composition with HHV evolution. Statistically significant effects of temperature on char yield and HHV were obtained, while heating rate and hold time effects were insignificant. Milligram-scale maximised HHVs were 30.03MJkg -1 (525°C) and 31.01MJkg -1 (580°C) for LC and MP, respectively. Higher char yields and HHVs for MP were attributed to increased lignin content. Scaling-up promoted secondary char formation thereby increasing HHVs, 30.82MJkg -1 for LC and 31.61MJkg -1 for MP. Incondensable gas analysis showed that temperature increase beyond preferred values caused dehydrogenation that decreased HHV. Similarly, CO evolution profile explained differences in optimal HHV temperatures. Copyright © 2017 Elsevier Ltd. All rights reserved.

Pyrolysis of polyethylene mixed with paper and wood: Interaction effects on tar, char and gas yields.

PubMed

Grieco, E M; Baldi, G

2012-05-01

In the present study the interactions between the main constituents of the refuse derived fuel (plastics, paper, and wood) during pyrolysis were studied. Binary mixtures of polyethylene-paper and polyethylene/sawdust have been transformed into pellets and pyrolyzed. Various mixtures with different composition were analyzed and pyrolysis products (tar, gas, and char) were collected. The mixtures of wood/PE and paper/PE have a different behavior. The wood/PE mixtures showed a much reduced interaction of the various compounds because the yields of pyrolysis products of the mixture can be predicted as linear combination of those of the pure components. On the contrary, a strong char yield increase was found at a low heating rate for paper/PE mixtures. In order to explain the results, the ability of wood and paper char to adsorb and convert the products of PE pyrolysis into was studied. Adsorption and desorption tests were performed on the char obtained by paper and wood by using n-hexadecane as a model compound for the heavy products of PE pyrolysis. Copyright © 2011 Elsevier Ltd. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only overmore » the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.« less

Study on demetalization of sewage sludge by sequential extraction before liquefaction for the production of cleaner bio-oil and bio-char.

PubMed

Leng, Lijian; Yuan, Xingzhong; Shao, Jianguang; Huang, Huajun; Wang, Hou; Li, Hui; Chen, Xiaohong; Zeng, Guangming

2016-01-01

Demetalization of sewage sludge (SS) by sequential extraction before liquefaction was implemented to produce cleaner bio-char and bio-oil. Demetalization steps 1 and 2 did not cause much organic matter loss on SS, and thus the bio-oil and bio-char yields and the compositions of bio-oils were also not affected significantly. However, the demetalization procedures resulted in the production of cleaner bio-chars and bio-oils. The total concentrations and the acid soluble/exchangeable fraction (F1 fraction, the most toxic heavy metal fraction) of heavy metals (Cu, Cr, Pb, Zn, and Cd) in these products were significantly reduced and the environmental risks of these products were also relived considerably compared with those produced from raw SS, respectively. Additionally, these bio-oils had less heavy fractions. Demetalization processes with removal of F1 and F2 fractions of heavy metals would benefit the production of cleaner bio-char and bio-oil by liquefaction of heavy metal abundant biomass like SS. Copyright © 2015 Elsevier Ltd. All rights reserved.

Pyrolysis for exploitation of biomasses selected for soil phytoremediation: Characterization of gaseous and solid products.

PubMed

Giudicianni, Paola; Pindozzi, Stefania; Grottola, Corinna Maria; Stanzione, Fernando; Faugno, Salvatore; Fagnano, Massimo; Fiorentino, Nunzio; Ragucci, Raffaele

2017-03-01

Biomasses to be used in the phytoremediation process are generally selected to match agronomic parameters and heavy metals uptake ability. A proper selection can be made greatly effective if knowledge of the properties of the residual char from pyrolysis is available to identify possible valorization routes. In this study a comparative analysis of the yields and characteristics of char obtained from slow pyrolysis of five uncontaminated biomasses (Populus nigra, Salix alba, Fraxinus oxyphylla, Eucalyptus occidentalis and Arundo donax) was carried out under steam atmosphere to better develop char porosity. Moreover, the dependence of the properties of solid residue on the process final temperature was studied for E. occidentalis in the temperature range of 688-967K. The results demonstrate that, among the studied biomasses, chars from P. nigra and E. occidentalis have to be preferred for applications regulated by surface phenomena given their highest surface area (270-300m 2 /g), whereas char from E. occidentalis is the best choice when the goal is to maximize energy recovery. Copyright © 2017 Elsevier Ltd. All rights reserved.

Thermal characteristics and surface morphology of char during co-pyrolysis of low-rank coal blended with microalgal biomass: Effects of Nannochloropsis and Chlorella.

PubMed

Wu, Zhiqiang; Yang, Wangcai; Yang, Bolun

2018-02-01

In this work, the influence of Nannochloropsis and Chlorella on the thermal behavior and surface morphology of char during the co-pyrolysis process were explored. Thermogravimetric and iso-conversional methods were applied to analyzing the pyrolytic and kinetic characteristics for different mass ratios of microalgae and low-rank coal (0, 3:1, 1:1, 1:3 and 1). Fractal theory was used to quantitatively determine the effect of microalgae on the morphological texture of co-pyrolysis char. The result indicated that both the Nannochloropsis and Chlorella promoted the release of volatile from low-rank coal. Different synergistic effects on the thermal parameters and yield of volatile were observed, which could be attributed to the different compositions in the Nannochloropsis and Chlorella and operating condition. The distribution of activation energies shows nonadditive characteristics. Fractal dimensions of the co-pyrolysis char were higher than the individual char, indicating the promotion of disordered degree due to the addition of microalgae. Copyright © 2017 Elsevier Ltd. All rights reserved.

Co-pyrolysis behaviors of saw dust and Shenfu coal in drop tube furnace and fixed bed reactor.

PubMed

Li, Shuaidan; Chen, Xueli; Wang, Li; Liu, Aibin; Yu, Guangsuo

2013-11-01

Co-pyrolysis behaviors of saw dust (SD) and Shenfu bituminous coal (SF) were studied in a drop tube furnace and a fixed bed reactor at different temperatures respectively. Six different biomass/coal ratios (B:C) were used. Compared the results with the calculated value obtained by the additional behavior, CO volume yields were lower while H2, CH4, CO2, volume yields were higher. Blend char yields had a good agreement with the calculated values, and their structures remained similar with SD and SF char's. Synergy effect occurred in gaseous phase, which was mainly caused by the secondary reactions. Compared the blend char yields in the drop tube furnace with those in the fixed bed reactor, the results showed the contacting way of biomass and coal particles had little influence on char yield in co-pyrolysis process. The reactivity index of blend char achieved the minimum at B:C=40:60 and the maximum at B:C=80:20. Copyright © 2013 Elsevier Ltd. All rights reserved.

Rapid co-pyrolysis of rice straw and a bituminous coal in a high-frequency furnace and gasification of the residual char.

PubMed

Yuan, Shuai; Dai, Zheng-hua; Zhou, Zhi-jie; Chen, Xue-li; Yu, Guang-suo; Wang, Fu-chen

2012-04-01

Rapid pyrolysis of rice straw (RS) and Shenfu bituminous coal (SB) separately, and rapid co-pyrolysis of RS/SB blends (mass ratio 1:4, 1:4, and 4:1), were carried out in a high-frequency furnace which can ensure both high heating rate and satisfying contact of fuel particles. Synergies between RS and SB during rapid co-pyrolysis were investigated. Intrinsic and morphological structures of residual char from co-pyrolysis, and their effects on gasification characteristics were also studied. Synergies occurred during rapid co-pyrolysis of RS and SB (RS/SB=1:4) resulting in decreasing char yields and increasing volatile yields. Synergies also happened during gasification of the char derived from co-pyrolysis of RS and SB with mass ratio of 1:4. The increased mass ratio of RS to SB did not only weaken synergies during co-pyrolysis, but significantly reduced the gasification rates of the co-pyrolysis char compared to the calculated values. Results can help to optimize co-conversion process of biomass/coal. Copyright © 2012 Elsevier Ltd. All rights reserved.

Intumescent coatings with improved properties for high-rise construction

NASA Astrophysics Data System (ADS)

Ustinov, Andrey; Zybina, Olga; Tanklevsky, Leonid; Lebedev, Vasily; Andreev, Andrey

2018-03-01

The paper overviews the way of creating intumescent fire-protective compositions with improved properties by adding nano-and micro-sized supplements into them. Intumescent paints are inert at low temperatures, and at higher temperatures they expand and degrade to provide a charred layer of low conductivity materials. The modified intumescent paints are able to form a more stable charred layer than the classical paints. The stability of a charred layer is crucial if the fire safety in high-rise construction must be secured, because a weak charred layer will not provide a required fire endurance for steel bearing structures and they will break down in case of fire. The fire-protective properties of modified intumescent paints were estimated using an electrical furnace. Also the way of thermal decomposition of the paints was studied with thermogravimetric analysis. Results show that modified intumescent paints form a charred layer with improved fire-protective properties; it can serve as a thermal barrier for a longer period of time. Thermogravimetric analysis confirms this fact showing that the temperatures of full thermal decay in case of modified paints are higher than those of non-modified paints.

Combustion of Coal Char Particles under Fluidized Bed Oxyfiring Conditions

NASA Astrophysics Data System (ADS)

Scala, Fabrizio; Chirone, Riccardo

In this work combustion of single coal char particles was studied at 850°C in a lab-scale fluidized bed under simulated oxyfiring conditions. The burning rate of the particles was followed as a function of time by continuously measuring the outlet CO and O2 concentrations. Some preliminary evaluations on the significance of homogeneous CO oxidation in the reactor and of carbon gasification by CO2 in the char were also carried out. Results showed that the carbon burning rate increases with oxygen concentration and char particle size. The particle temperature is approximately equal to the bed one up to an oxygen concentration of 2%, but it is considerably higher for larger oxygen concentrations. Both CO2 gasification of char and homogeneous CO oxidation are not negligible. The gasification reaction rate is slow and it is likely to be controlled by intrinsic kinetics. During purely gasification conditions the extent of carbon loss due to particle attrition by abrasion (estimated from the carbon mass balance) appears to be more important than under combustion conditions.

Promotion of hydrogen-rich gas and phenolic-rich bio-oil production from green macroalgae Cladophora glomerata via pyrolysis over its bio-char.

PubMed

Norouzi, Omid; Jafarian, Sajedeh; Safari, Farid; Tavasoli, Ahmad; Nejati, Behnam

2016-11-01

Conversion of Cladophora glomerata (C. glomerata) as a Caspian Sea's green macroalgae into gaseous, liquid and solid products was carried out via pyrolysis at different temperatures to determine its potential for bio-oil and hydrogen-rich gas production for further industrial utilization. Non-catalytic tests were performed to determine the optimum condition for bio-oil production. The highest portion of bio-oil was retrieved at 500°C. The catalytic test was performed using the bio-char derived at 500°C as a catalyst. Effect of the addition of the algal bio-char on the composition of the bio-oil and also gaseous products was investigated. Pyrolysis derived bio-char was characterized by BET, FESEM and ICP method to show its surface area, porosity, and presence of inorganic metals on its surface, respectively. Phenols were increased from 8.5 to 20.76area% by the addition of bio-char. Moreover, the hydrogen concentration and hydrogen selectivity were also enhanced by the factors of 1.37, 1.59 respectively. Copyright © 2016 Elsevier Ltd. All rights reserved.

Development and Verification of the Charring Ablating Thermal Protection Implicit System Solver

NASA Technical Reports Server (NTRS)

Amar, Adam J.; Calvert, Nathan D.; Kirk, Benjamin S.

2010-01-01

The development and verification of the Charring Ablating Thermal Protection Implicit System Solver is presented. This work concentrates on the derivation and verification of the stationary grid terms in the equations that govern three-dimensional heat and mass transfer for charring thermal protection systems including pyrolysis gas flow through the porous char layer. The governing equations are discretized according to the Galerkin finite element method with first and second order implicit time integrators. The governing equations are fully coupled and are solved in parallel via Newton's method, while the fully implicit linear system is solved with the Generalized Minimal Residual method. Verification results from exact solutions and the Method of Manufactured Solutions are presented to show spatial and temporal orders of accuracy as well as nonlinear convergence rates.

Development and Verification of the Charring, Ablating Thermal Protection Implicit System Simulator

NASA Technical Reports Server (NTRS)

Amar, Adam J.; Calvert, Nathan; Kirk, Benjamin S.

2011-01-01

The development and verification of the Charring Ablating Thermal Protection Implicit System Solver (CATPISS) is presented. This work concentrates on the derivation and verification of the stationary grid terms in the equations that govern three-dimensional heat and mass transfer for charring thermal protection systems including pyrolysis gas flow through the porous char layer. The governing equations are discretized according to the Galerkin finite element method (FEM) with first and second order fully implicit time integrators. The governing equations are fully coupled and are solved in parallel via Newton s method, while the linear system is solved via the Generalized Minimum Residual method (GMRES). Verification results from exact solutions and Method of Manufactured Solutions (MMS) are presented to show spatial and temporal orders of accuracy as well as nonlinear convergence rates.

Synthesis of improved phenolic and polyester resins

NASA Technical Reports Server (NTRS)

Delano, C. B.

1980-01-01

Thirty-seven cured phenolic resin compositions were prepared and tested for their ability to provide improved char residues and moisture resistance over state of the art epoxy resin composite matrices. Cyanate, epoxy novolac and vinyl ester resins were investigated. Char promoter additives were found to increase the anaerobic char yield at 800 C of epoxy novolacs and vinyl esters. Moisture resistant cyanate and vinyl ester compositions were investigated as composite matrices with Thornel 300 graphite fiber. A cyanate composite matrix provided state of the art composite mechanical properties before and after humidity exposure and an anaerobic char yield of 46 percent at 800 C. The outstanding moisture resistance of the matrix was not completely realized in the composite. Vinyl ester resins showed promise as candidates for improved composite matrix systems.

Low percentage of clinically relevant pistachio nut and mango co-sensitisation in cashew nut sensitised children.

PubMed

van der Valk, J P M; Bouche, R El; Gerth van Wijk, R; de Groot, H; Wichers, H J; Dubois, A E J; de Jong, N W

2017-01-01

Cashew nut, pistachio nut and mango belong to the Anacardiaceae family and are botanically related. Therefore, cashew nut sensitised children are frequently advised to eliminate cashew nuts and pistachio nuts from their diet. The 'Improvement of Diagnostic mEthods for ALlergy assessment (IDEAL trial number NTR3572) study showed that cashew nut sensitised children were co-sensitised to pistachio nut in 98% of cases and to mango in 21% of cases. The aim of this follow-up study to IDEAL is to assess the clinical relevance of co-sensitisation to pistachio nut and mango in cashew nut sensitised children. Children were recruited from the study: 'Improvement of Diagnostic mEthods for ALlergy assessment (IDEAL trial number NTR3572). Inclusion criterion for the IDEAL study was sensitization to cashew nut as demonstrated by either SPT or sIgE, and a clinical history of reactions to cashew nuts or no previous (known) exposure. Sensitized children who were tolerant to cashew nuts were excluded. Inclusion criterion for this IDEAL follow-up study was co-sensitization to pistachio nut, regardless the result of the DBPCFC with cashew nut. In this follow-up study a double-blind placebo-controlled food challenge with pistachio nut and an open food challenge with mango were performed. Twenty-nine children (mean age of 11.6 years, 62% male) were included. Pistachio nut sensitisation was clinically relevant in only 34% of cashew-sensitised children and only 31% of cashew challenge positive children. None of the children was challenge positive to mango. Although co-sensitisation between cashew nut and pistachio nut was observed in 98%, pistachio nut sensitisation was only clinically relevant in 34% of the children. Therefore, a challenge test with pistachio nut is recommended in children with cashew nut and pistachio nut sensitisation. Trial registration The study was registered in the Dutch trial register (registration number 3572) on 10 August 2012 (retrospectively registered).

Electronic structure calculations toward new potentially AChE inhibitors

NASA Astrophysics Data System (ADS)

de Paula, A. A. N.; Martins, J. B. L.; Gargano, R.; dos Santos, M. L.; Romeiro, L. A. S.

2007-10-01

The main purpose of this study was the use of natural non-isoprenoid phenolic lipid of cashew nut shell liquid from Anacardium occidentale as lead material for generating new potentially candidates of acetylcholinesterase inhibitors. Therefore, we studied the electronic structure of 15 molecules derivatives from the cardanol using the following groups: methyl, acetyl, N, N-dimethylcarbamoyl, N, N-dimethylamine, N, N-diethylamine, piperidine, pyrrolidine, and N-benzylamine. The calculations were performed at RHF level using 6-31G, 6-31G(d), 6-31+G(d) and 6-311G(d,p) basis functions. Among the proposed compounds we found that the structures with substitution by acetyl, N, N-dimethylcarbamoyl, N, N-dimethylamine, and pyrrolidine groups were better correlated to rivastigmine indicating possible activity.

Evaluation of tensile strength of hybrid fiber (jute/gongura) reinforced hybrid polymer matrix composites

NASA Astrophysics Data System (ADS)

Venkatachalam, G.; Gautham Shankar, A.; Vijay, Kumar V.; Chandan, Byral R.; Prabaharan, G. P.; Raghav, Dasarath

2015-07-01

The polymer matrix composites attract many industrial applications due to its light weight, less cost and easy for manufacturing. In this paper, an attempt is made to prepare and study of the tensile strength of hybrid (two natural) fibers reinforced hybrid (Natural + Synthetic) polymer matrix composites. The samples were prepared with hybrid reinforcement consists of two different fibers such as jute and Gongura and hybrid polymer consists of polyester and cashew nut shell resins. The hybrid composites tensile strength is evaluated to study the influence of various fiber parameters on mechanical strength. The parameters considered here are the duration of fiber treatment, the concentration of alkali in fiber treatment and nature of fiber content in the composites.

Optoelectronic and photoacoustic studies of an organic dye synthesized through green route

NASA Astrophysics Data System (ADS)

Vijayakumar, S.; Sreelatha, S.; Hatamimoslehabadi, M.; Yelleswarappu, C. S.

2017-10-01

An azo dye was prepared through an environmentally benign and economically feasible synthesis route with cardanol as a starting material. Cardanol is a cost-effective and renewable natural source obtained from Cashew Nut Shell Liquid, a by-product of the cashew industry. The dye was spectrally characterized by IR, UV-Vis, NMR and fluorescence studies. UV-Vis absorption showed a bathochromic shift between solvents of lower and higher polarities. Nonlinear optical and photoacoustic properties were studied using a frequency doubled Nd:YAG laser producing 532 nm laser pulses of 3 ns pulse width. Results show that the nonlinear absorption coefficient decreases with the increase of on-axis intensity, suggesting excited state absorption as the principal mechanism. The observed nonlinearity has applications in optoelectronics.

Separation of variables in Maxwell equations in Plebański-Demiański spacetime

NASA Astrophysics Data System (ADS)

Frolov, Valeri P.; Krtouš, Pavel; KubizÅák, David

2018-05-01

A new method for separating variables in the Maxwell equations in four- and higher-dimensional Kerr-(A)dS spacetimes proposed recently by Lunin is generalized to any off-shell metric that admits a principal Killing-Yano tensor. The key observation is that Lunin's ansatz for the vector potential can be formulated in a covariant form—in terms of the principal tensor. In particular, focusing on the four-dimensional case we demonstrate separability of Maxwell's equations in the Kerr-NUT-(A)dS and the Plebański-Demiański family of spacetimes. The new method of separation of variables is quite different from the standard approach based on the Newman-Penrose formalism.

Combustion and NOx emissions in deep-air-staging combustion of char in a circulating fluidized bed

NASA Astrophysics Data System (ADS)

Gong, Zhiqiang; Wang, Zhentong; Wang, Lei; Du, Aixun

2017-10-01

Combustion and NOx emissions in deep-air-staging (with higher level secondary air (SA) injection) combustion of char have been investigated in a CFB test rig. A good fluidized condition and uniform temperature distribution can be achieved with injection of higher level SA. NOx emission decreases with injection of higher level SA and the reduction effect is more obvious at higher temperature. NOx emission decreases with combustion temperature increasing for char combustion.

The Effect of Soil Warming on Decomposition of Biochar, Wood, and Bulk Soil Organic Carbon in Contrasting Temperate and Tropical Soils

NASA Astrophysics Data System (ADS)

Torn, Margaret; Tas, Neslihan; Reichl, Ken; Castanha, Cristina; Fischer, Marc; Abiven, Samuel; Schmidt, Michael; Brodie, Eoin; Jansson, Janet

2013-04-01

Biochar and wood are known to decay at different rates in soil, but the longterm effect of char versus unaltered wood inputs on soil carbon dynamics may vary by soil ecosystem and by their sensitivity to warming. We conducted an incubation experiment to explore three questions: (1) How do decomposition rates of char and wood vary with soil type and depth? (2) How vulnerable to warming are these slowly decomposing inputs? And (3) Do char or wood additions increase loss of native soil organic carbon (priming)? Soils from a Mediterranean grassland (Hopland Experimental Research Station, California) and a moist tropical forest (Tabunoco Forest, Puerto Rico) were collected from two soil depths and incubated at ambient temperature (14°C, 20°C for Hopland and Tabonuco respectively) and ambient +6°C. We added 13C-labeled wood and char (made from the wood at 450oC) to the soils and quantified CO2 and 13CO2 fluxes with continuous online carbon isotope measurements using a Cavity Ringdown Spectrometer (Picarro, Inc) for one year. As expected, in all treatments the wood decomposed much (about 50 times) more quickly than did the char amendment. With few exceptions, amendments placed in the surface soil decomposed more quickly than those in deeper soil, and in forest soil faster than that placed in grassland soil, at the same temperature. The two substrates were not very temperature sensitive. Both had Q10 less than 2 and char decomposition in particular was relatively insensitive to warming. Finally, the addition of wood caused a significant increase of roughly 30% in decomposition losses of the native soil organic carbon in the grassland and slightly less in forest. Char had only a slight positive priming effect but had a significant effect on microbial community. These results show that conversion of wood inputs to char through wildfire or intentional management will alter not only the persistence of the carbon in soil but also its temperature response and effect on microbial communities.

Does providing written dietary advice improve the ingestion of non-allergic nuts in children with existing nut allergies? - A randomized controlled trial.

PubMed

Norman, M; South, C; Quinn, P; Chan, D; Palmer, S; Netting, M; Gold, M

2016-05-01

Allergy to one or more nuts is common in children and often complete nut avoidance is advised. More recently, introduction of non-allergic nuts into the diet is advised by some allergists. This study aims to determine whether the provision of additional written dietary advice increases the ingestion of non-allergic nuts by children with nut allergy. Secondary aims include determining which factors facilitate or prevent successful inclusion of non-allergic nuts in the diet, and how inclusion influences quality of life, sensitization and the rate of nut reactions. This is a randomized, double-blinded, controlled trial of children with nut allergy who were asked to ingest one or more non-allergic nuts. Participants were 75 children aged 2-16 years (Intervention=36, Control=39), recruited in Adelaide, Australia. Randomized participants were supplied with the intervention (recipe booklet and monthly reminder text messages) or provided standard verbal dietary advice. After 6 months participants were assessed by a blinded investigator with regard to nut ingestion, quality of life, sensitization and nut reactions. The intervention did not increase the ingestion of non-allergic nuts. A negative hospital challenge was a predictor of successful introduction. Parental report of child concern about a reaction was the greatest barrier. Ingestion of non-allergic nuts did not improve quality of life or change nut sensitization. Few nut reactions occurred during the study. Ingestion of non-allergic nuts by children with nut allergy was not improved by additional dietary intervention. Selective introduction of non-allergic nuts is difficult to achieve when the child is anxious about introduction and challenges cannot be done in a medically supervised setting. This dietary intervention did not improve non-allergic nut ingestion by nut allergic children. Hospital challenge increased introduction rates, whilst parentally reported child concern about a reaction reduced success. Non-allergic nut ingestion did not change quality of life or sensitization. © 2016 John Wiley & Sons Ltd.

A concept of technology for freight wagons modernization

NASA Astrophysics Data System (ADS)

Pɫaczek, M.; Wróbel, A.; Buchacz, A.

2016-11-01

Rail transport is a very important part of the modern economy, one of the components determining its dynamic development. It is therefore important to conduct research and taking action aimed at the development and refinement of this branch of industry. Such actions directly translate into an increase in its effectiveness, safety, reduction of burden on the environment and society. Nowadays numerous studies are conducted, aimed at introducing new technologies and solutions, both in terms of railway infrastructure and logistics management systems, as well as in traction vehicles themselves. Introduction of modern technology helps eliminate or reduce nuisance problems associated with the implementation of any kind of transport or the operation of the used technical means. Presented paper concerns an issue of freight wagon modernization using composite materials. It presents a part of a research project that aim is to develop a technology of freight wagons modernization during their periodic repair. The main problem during exploitation of concerned types of freight wagons designed for coal transport is corrosion of the wagon's body shell. The goal of the project is to elongate the period between periodic repairs (by better corrosion protection) and improve conditions of exploitation of modernized freight wagons (for example easier unloading during winter conditions - no freezes of the charge to the freight wagon body shell). One of elements of the project is also to develop a system for diagnosing the technical condition of the modernized shell of wagon body during operation. For this purpose the use of non-destructive testing methods of technical state of constructions will be used, including methods that use the analysis of dynamic response of the object. Application of the composite panels to the freight wagon's body shell was proposed as the solution that can solve mentioned problems during exploitation of freight wagons. The composite panels composed of fiberglass and epoxy resin were proposed. They will be mounted on the body shell using blind rivet nuts. What is more the body shell of the modernized freight wagon will be painted using an anticorrosion agent. The research project is realized by a consortium composed by research units and industry and supported by the Polish National Centre for Research and Development.

Synergistic Effect of Co-utilization of Coal and Biomass Char: An Overview

NASA Astrophysics Data System (ADS)

Paiman, M. E. S.; Hamzah, N. S.; Idris, S. S.; Rahman, N. A.; Ismail, K.

2018-05-01

Global concerns on impact of greenhouse gases emission, mostly released from coal-fired power plant, and the depletion of fossil fuel particularly coal, has led the production of electricity from alternatives resources such as co-utilization technologies. Previous studies proved that the co-utilization of coal and biomass/biomass chars has significantly reduced the emission of greenhouse gases either during the pyrolysis, combustion or gasification process in laboratories, pilots as well as in the industrial scales. Interestingly, most of the studies reported the presence of synergistic effect during the co-utilization processes particularly between coal and biomass char while some are not. Biomass chars were found to have porous and highly disorder carbon structure and belong to the class of most reactive carbon material, resulting to be more reactive than those hard coal and lignite. Up to date, microwave assisted pyrolysis is one of the best and latest techniques employed to produce better quality of biomass chars and it is also reduce the processing cost. Lot of works has been done regarding on the existence of synergistic effects during its co-utilization. However, the knowledge is limited to thermal and product characteristics so far. Even so, the specific reasons behind its existence are yet to understand well. Therefore, in this paper, the emphasis will be given on the synergistic effects on emission characteristics of co-utilization of coal and biomass chars so that it can be apply in energy-based industries to help in reduction of the greenhouse gases emission.

Synthesis and characterization of poly (dihydroxybiphenyl borate) with high char yield for high-performance thermosetting resins

NASA Astrophysics Data System (ADS)

Wang, Shujuan; Xing, Xiaolong; Li, Jian; Jing, Xinli

2018-01-01

The objective of the current work is to synthesize novel boron-containing polymers with excellent thermal resistance, and reveal the structure and the reason for the high char yield. Thus, poly (dihydroxybiphenyl borate) (PDDB) with a more rigid molecular chain, was successfully synthesized using 4,4‧-dihydroxybiphenyl and boric acid. Structural characterizations of the prepared PDDB were performed via NMR, FTIR, XPS, and XRD analyses. The results reveal that PDDB consists of aromatic, Phsbnd Osbnd B and Bsbnd Osbnd B structures as well as a small number of boron hydroxyl and phenolic hydroxyl groups. PDDB shows good solubility in strong polar solvents, which is of great importance for the modification of thermosetting resins. TGA combined with DSC were employed to evaluate the thermal properties of PDDB, and increases in the glass transition temperature (Tg) and char yield were observed with increased boron content. Tg and char yield of PDDB (800 °C, nitrogen atmosphere) reached up to 219 °C and 66.5%, respectively. PDDB was extensively characterized during pyrolysis to reveal the high char yield of PDDB. As briefly discussed, the boron oxide and boron carbide that formed during pyrolysis play a crucial role in the high char yield of PDDB, which reduces the release of volatile carbon dioxide and carbon. This research suggests that PDDB has great potential as a novel modified agent for the improvement of the comprehensive performance of thermosetting resins to broaden their applicability in the field of advanced composites.

Pyrolysis of waste animal fats in a fixed-bed reactor: Production and characterization of bio-oil and bio-char

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ben Hassen-Trabelsi, A., E-mail: aidabenhassen@yahoo.fr; Kraiem, T.; Département de Géologie, Université de Tunis, 2092, Tunis

Highlights: • Produced bio-fuels (bio-oil and bio-char) from some animal fatty wastes. • Investigated the effects of main parameters on pyrolysis products distribution. • Determined the suitable conditions for the production of the maximum of bio-oil. • Characterized bio-oils and bio-chars obtained from several animal fatty wastes. - Abstract: Several animal (lamb, poultry and swine) fatty wastes were pyrolyzed under nitrogen, in a laboratory scale fixed-bed reactor and the main products (liquid bio-oil, solid bio-char and syngas) were obtained. The purpose of this study is to produce and characterize bio-oil and bio-char obtained from pyrolysis of animal fatty wastes. Themore » maximum production of bio-oil was achieved at a pyrolysis temperature of 500 °C and a heating rate of 5 °C/min. The chemical (GC–MS analyses) and spectroscopic analyses (FTIR analyses) of bio-oil showed that it is a complex mixture consisting of different classes of organic compounds, i.e., hydrocarbons (alkanes, alkenes, cyclic compounds…etc.), carboxylic acids, aldehydes, ketones, esters,…etc. According to fuel properties, produced bio-oils showed good properties, suitable for its use as an engine fuel or as a potential source for synthetic fuels and chemical feedstock. Obtained bio-chars had low carbon content and high ash content which make them unattractive for as renewable source energy.« less

Bio-char from treated and untreated oil palm fronds

NASA Astrophysics Data System (ADS)

Sulaiman, Fauziah; Abdullah, Nurhayati; Rahman, Aizuddin Abdul

2013-05-01

The palm oil industry generates almost 94% of biomass in Malaysia, while other agricultural and forestry by-products contribute the remaining of 6%. Oil palm fronds (OPF) are estimated to be the highest available biomass amounting to 44.84 million tonnes in Malaysia. However, studies on OPF for thermochemical conversion technology which has good potential for energy conversion are still lacking. In this work, pyrolysis of OPF is conducted by using a fixed bed reactor. Samples were carbonized at slow pyrolysis temperature of around 300 to 500°C with heating rate of 10°C min-1. In addition, samples were treated for 20 min with distilled water at ambient temperature to reduce the ash content. Effectiveness of pre-treatment can be determined by observing the percentage of ash content reduction of each sample after undergoing washing pre-treatment. At 300°C, the char yields of the untreated OPF were slightly higher at 50.95% compared to the treated sample at 49.77%. Approximately all bio-char from the treated samples have better high heating value (HHV) of around 18-20 MJ kg-1 compared to the untreated samples. Besides that, all treated OPF char is more carbon rich and considered to be environmental friendly due to its low nitrogen content compared to the untreated OPF char. In this work, microscopic analysis of OPF bio-char were also studied by observing and evaluating their structure surface and morphology.

Cookery method and endpoint temperature can affect the Warner-Bratzler shear force, cooking loss, and internal cooked color of beef semimembranosus and infraspinatus steaks.

PubMed

Yancey, J W S; Apple, J K; Wharton, M D

2016-10-01

Steaks from USDA Select inside rounds (Exp. 1) and shoulder clods (Exp. 2) were used to test the interactive effect of cookery method and endpoint temperature on Warner-Bratzler shear force (WBSF) and internal cooked color. Pairs of 2.5-cm-thick semimembranosus (SM) or infraspinatus (INF) steaks ( = 360/muscle) were cut from each subprimal, labeled, vacuum packaged, and frozen at -30°C in the dark for approximately 60 d before being cooked to 65.5, 71.1, or 76.6°C using 1) a forced-air convection oven (FAC); 2) a forced-air impingement oven (IMP); 3) a gas-fired, open-hearth charbroiler (CHAR); 4) an electric countertop griddle (GRID); or 5) a clam-shell grill (CLAM). Thawed steaks were cooked to their assigned endpoint temperature × cookery method combination, and, after a 5-min cooling period, steaks were weighed to calculate cooking loss percentage and subsequently sliced perpendicular to the cut surface to measure instrumental cooked color. Then, 6 cores were removed for measurement of WBSF. Cooking losses of SM steaks increased ( < 0.05) with each increase in endpoint temperature, whereas INF steaks cooked on a CHAR had the greatest ( < 0.05) cooking losses and cooking INF steaks with the GRID and the CLAM resulted in lesser ( < 0.05) cooking losses than cooking with the FAC and the IMP. Cooking SM steaks on the CHAR resulted in greater ( < 0.05) WBSF values than all other cookery methods when cooked to 65.5 and 76.6°C and greater ( < 0.05) WBSF values than those cooked on the FAC, GRID, and CLAM when cooked to 71.1°C. Shear force values were greater ( < 0.05) for INF steaks cooked to 71.1 and 76.6°C than those cooked to 65.5°C, but INF WBSF values were similar ( = 0.55) among cookery methods. At 65.5°C, FAC-cooked SM steaks were redder ( < 0.05) than those cooked with the GRID and the IMP and, at 71.1°C, CLAM-cooked SM steaks were redder ( < 0.05) than FAC- and IMP-cooked SM steaks; however, a* values were similar ( > 0.05) among cookery methods when cooked to 76.6°C. Redness did not ( > 0.05) differ among INF steaks cooked to 65.5 and 71.1°C with the FAC and the CHAR, whereas internal color of INF steaks cooked in the IMP and the FAC was redder ( < 0.05) than that of INF steaks cooked with the CLAM and the GRID to 76.6°C. Results suggest that endpoint temperature has a greater impact on cooking properties of SM and INF steaks than cookery method, yet it is apparent that internal cooked color of INF and SM steaks react differently to some cookery method-endpoint temperature combinations.

Power and Limitations of Anhydrosugars to Trace Historical Natural and Anthropogenic Inputs of charcoal BC to Aquatic Systems

NASA Astrophysics Data System (ADS)

Louchouarn, P.; Kuo, L.; Brandenberger, J. M.; Andresen, C. S.; Kjaer, K. H.; Dalton, M.

2011-12-01

Plant-derived chars are the solid residues from incomplete combustion of plant materials. They are an important constituent in the black carbon (BC) continuum, an array of diverse pyrogenic organic materials ranging from slightly charred biomass (low temperature) to highly condensed refractory soot (high temperature). The characterization and quantification of plant-derived chars in environmental samples is a challenging process due to the heterogeneous nature of these substances. Most of the BC methods using oxidative approaches that seek to remove non-BC materials are limited in their potential to identify and quantify plant-derived chars because of their relative labilities compared to the condensed BC forms such as soot. Anhydrosugars, such as levoglucosan and its isomers (mannosan and galactosan), have generated considerable interest in recent years in BC research because they are exclusive thermal degradation products of cellulose/hemicellulose and are produced in different proportions in chars and smokes from low temperature combustion of different plant species permitting some source discrimination in environmental samples (e.g. softwoods vs. hardwoods; gymnosperms vs. angiosperms). We show here a synthesis of several years of work using levoglucosan in diverse environments to reconstruct local to large-scale environmental change from climate-driven wildfires to human and accidental fires. For example, in the Hood Canal (WA), the striking consistency between the fluxes of levoglucosan, the Pacific Decadal Oscillation (PDO) Index, and the Palmer Drought Severity Index (PDSI), suggests that climate oscillations may play a role in the historical wildfire activities and thus influence the inputs of char-BC to the Puget Sound. Similarly, peaks in anhydrosugars in a sediment core from Lake Copenhagen record large-scale accidental fires in the city of Copenhagen during the early and late 18th Century, and help constrain the geochronology of the core beyond the limit of the 210Pb dating potential (late 19th Century). Despite these "successes" in sedimentary systems, the application of anhydrosugars to reconstruct historical char-BC inputs to aquatic systems is fraught with both methodological and conceptual issues. For one, anhydrosugars analysis in sediments suffers from more interferences than similar analyses in atmospheric particles. Secondly, and most significantly, the rapid turnover of anhydrosugars in aquatic systems mean that only a small fraction of the original tracers encapsulated in the inner pores of char particles is preserved in sedimentary systems, thus complicating the potential for a direct transfer function between the presence of anhydrosugars and original fluxes of char-BC to aquatic environments.

Textural, Rheological and Sensory Properties and Oxidative Stability of Nut Spreads—A Review

PubMed Central

Shakerardekani, Ahmad; Karim, Roselina; Ghazali, Hasanah Mohd; Chin, Nyuk Ling

2013-01-01

Tree nuts are rich in macro and micronutrients, phytochemicals, tocopherols and phenolic compounds. The development of nut spreads would potentially increase the food uses of nuts and introduce consumers with a healthier, non-animal breakfast snack food. Nut spreads are spreadable products made from nuts that are ground into paste. Roasting and milling (particle size reduction) are two important stages for the production of nut spreads that affected the textural, rheological characteristic and overall quality of the nut spread. Textural, color, and flavor properties of nut spreads play a major role in consumer appeal, buying decisions and eventual consumption. Stability of nut spreads is influenced by its particle size. Proper combination of ingredients (nut paste, sweetener, vegetable oil and protein sources) is also required to ensure a stable nut spread product is produced. Most of the nut spreads behaved like a non-Newtonian pseudo-plastic fluid under yield stress which help the producers how to start pumping and stirring of the nut spreads. Similar to other high oil content products, nut spreads are susceptible to autoxidation. Their oxidation can be controlled by application of antioxidants, using processing techniques that minimize tocopherol and other natural antioxidant losses. PMID:23429239

Solar coal gasification reactor with pyrolysis gas recycle

DOEpatents

Aiman, William R.; Gregg, David W.

1983-01-01

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

2,4-D adsorption to biochars: effect of preparation conditions on equilibrium adsorption capacity and comparison with commercial activated carbon literature data.

PubMed

Kearns, J P; Wellborn, L S; Summers, R S; Knappe, D R U

2014-10-01

Batch isotherm experiments were conducted with chars to study adsorption of the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D). Chars generated from corncobs, bamboo and wood chips in a laboratory pyrolyzer at 400-700 °C were compared with traditional kiln charcoals collected from villages in S/SE Asia and with activated carbons (ACs). 2,4-D uptake by laboratory chars obtained from bamboo and wood chips after 14 h of pyrolysis at 700 °C, from wood chips after 96 h of pyrolysis at 600 °C, and one of the field-collected chars (basudha) was comparable to ACs. H:C and O:C ratios declined with pyrolysis temperature and duration while surface area increased to >500 m(2)/g. Increasing pyrolysis intensity by increasing temperature and/or duration of heating was found to positively influence adsorption capacity yield (mg(2,4-D/g(feedstock))) over the range of conditions studied. Economic analysis showed that high temperature chars can be a cost-effective alternative to ACs for water treatment applications. Copyright © 2014 Elsevier Ltd. All rights reserved.

Valorization of algal waste via pyrolysis in a fixed-bed reactor: Production and characterization of bio-oil and bio-char.

PubMed

Aboulkas, A; Hammani, H; El Achaby, M; Bilal, E; Barakat, A; El Harfi, K

2017-11-01

The aim of the present work is to develop processes for the production of bio-oil and bio-char from algae waste using the pyrolysis at controlled conditions. The pyrolysis was carried out at different temperatures 400-600°C and different heating rates 5-50°C/min. The algal waste, bio-oil and bio-char were successfully characterized using Elemental analysis, Chemical composition, TGA, FTIR, 1 H NMR, GC-MS and SEM. At a temperature of 500°C and a heating rate of 10°C/min, the maximum yield of bio-oil and bio-char was found to be 24.10 and 44.01wt%, respectively, which was found to be strongly influenced by the temperature variation, and weakly affected by the heating rate variation. Results show that the bio-oil cannot be used as bio-fuel, but can be used as a source of value-added chemicals. On the other hand, the bio-char is a promising candidate for solid fuel applications and for the production of carbon materials. Copyright © 2017 Elsevier Ltd. All rights reserved.

Removal of copper by oxygenated pyrolytic tire char: kinetics and mechanistic insights.

PubMed

Quek, Augustine; Balasubramanian, Rajashekhar

2011-04-01

The kinetics of copper ion (Cu(II)) removal from aqueous solution by pyrolytic tire char was modeled using five different conventional models. A modification to these models was also developed through a modified equation that accounts for precipitation. Conventional first- and second-order reaction models did not fit the copper sorption kinetics well, indicating a lack of simple rate-order dependency on solute concentration. Instead, a reversible first-order rate reaction showed the best fit to the data, indicating a dependence on surface functional groups. Due to the varying solution pH during the sorption process, modified external and internal mass transfer models were employed. Results showed that the sorption of copper onto oxygenated chars was limited by external mass transfer and internal resistance with and without the modification. However, the modification of the sorption process produced very different results for unoxygenated chars, which showed neither internal nor external limitation to sorption. Instead, its slow sorption rate indicates a lack of surface functional groups. The sorption of Cu(II) by oxygenated and unoxygenated chars was also found to occur via three and two distinct stages, respectively. Copyright © 2010 Elsevier Inc. All rights reserved.

Effects of temperature, pressure, and carrier gas on the cracking of coal tar over a char-dolomite mixtures and calcined dolomite in a fixed-bed reactor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seshadri, K.; Shamsi, A.

1998-10-01

A distillation fraction of a coal-derived liquid (tar) was cracked over a char-dolomite mixture, calcined dolomite, and silicon carbide in a fixed-bed reactor. The char-dolomite mixture (FWC) was produced from Pittsburgh No. 8 coal and dolomite in a Foster Wheeler carbonizer. The experiments were conducted under nitrogen and simulated coal gas (SCG), which was a mixture of CO, CO{sub 2}, H{sub 2}S, CH{sub 4}, N{sub 2}, and steam, at 1 and 17 atm. The conversion over these materials under nitrogen was much higher at 17 atm than at 1 atm. At higher pressures, tar molecules were trapped in the poresmore » of the bed material and underwent secondary reactions, resulting in the formation of excess char. However, when nitrogen was replaced by SCG, the reactions that induce char formation were suppressed, thus increasing the yield of gaseous products. The analysis of the gaseous products and the spent bed materials for organic and inorganic carbons suggested that the product distribution can be altered by changing the carrier gas, temperature, and pressure.« less

Simulation of fluidized bed coal combustors

NASA Technical Reports Server (NTRS)

Rajan, R.

1979-01-01

The many deficiencies of previous work on simulation of fluidized bed combustion (FBC) processes are presented. An attempt is made to reduce these deficiencies, and to formulate a comprehensive FBC model taking into account the following elements: (1) devolatilization of coal and the subsequent combustion of volatiles and residual char; (2) sulfur dioxide capture by limestone; (3) NOx release and reduction of NOx by char; (4) attrition and elutriation of char and limestone; (5) bubble hydrodynamics; (6) solids mixing; (7) heat transfer between gas and solid, and solid and heat exchange surfaces; and (8) freeboard reactions.

Size distribution of carbon layer planes in biochar from different plant type of feedstock with different heating temperatures.

PubMed

Lu, Guan-Yang; Ikeya, Kosuke; Watanabe, Akira

2016-11-01

Biochar application to soil is a strategy to decelerate the increase in the atmospheric carbon concentration. The composition of condensed aromatic clusters appears to be an important determinant of the degradation rate of char in soil. The objective of the present study was to determine the size distribution of carbon layer planes in biochars produced from different types of feedstock (a broadleaf and a coniferous tree and two herbs) using different heating treatment temperatures (HTT; 400 °C-800 °C) using X-ray diffraction 11 band profile analysis. (13)C nuclear magnetic resonance with the phase-adjusted spinning side bands of the chars indicated different spectral features depending on the HTT and similar carbon composition among the plant types at each HTT. Both the content and composition of carbon layer planes in biochar produced using the same HTT were also similar among the plant types. The carbon layer plane size in the 400 °C and 600 °C chars was distributed from 0.24 to 1.68 or 1.92 nm (corresponding to 37 or 52 rings) with the mean size of 0.79-0.92 and 0.80-1.14 nm, respectively. The carbon layer planes in the 800 °C chars ranged from 0.72-0.96 nm (7-14 rings) to 2.64-3.60 nm (91-169 rings) and the mean values were 1.47-1.89 nm. The relative carbon layer plane content in the 600 °C and 800 °C chars was typically 2 and 3 times that in the 400 °C chars. These results indicate the progression of the formation and/or the size development of graphite-like structures, suggesting that a char produced at a higher HTT would have better carbon sequestrating characteristics. Copyright © 2016 Elsevier Ltd. All rights reserved.

Carbon Sequestration and Nitrogen Mineralization in Soil Cooperated with Organic Composts and Bio-char During Corn (Zea mays) Cultivation

NASA Astrophysics Data System (ADS)

Shin, Joung-Du; Lee, Sun-Ill; Park, Wu-Gyun; Choi, Yong-Su; Hong, Seong-Gil; Park, Sang-Won

2014-05-01

Objectives of this study were to estimate the carbon sequestration and to evaluate nitrogen mineralization and nitrification in soils cooperated with organic composts and bio-char during corn cultivation. For the experiment, the soil used in this study was clay loam types, and application rates of chemical fertilizer and bio-char were recommended amount after soil test and 2 % to soil weight, respectively. The soil samples were periodically taken at every 15 day intervals during the experimental periods. The treatments were consisted of non-application, cow manure compost, pig manure compost, swine digestate from aerobic digestion system, their bio-char cooperation. For the experimental results, residual amount of inorganic carbon was ranged from 51 to 208kg 10a-1 in soil only cooperated with different organic composts. However it was estimated to be highest at 208kg 10a-1 in the application plot of pig manure compost. In addition to bio-char application, it was ranged from 187.8 to 286kg 10a-1, but was greatest accumulated at 160.3kg 10a-1 in the application plot of cow manure compost. For nitrogen mineralization and nitrification rates, it was shown that there were generally low in the soil cooperated with bio-char compared to the only application plots of different organic composts except for 71 days after sowing. Also, they were observed to be highest in the application plot of swine digestate from aerobic digestion system. For the loss of total inorganic carbon (TIC) by run-off water, it was ranged from 0.18 to 0.36 kg 10a-1 in the different treatment plots. Also, with application of bio-char, total nitrogen was estimated to be reduced at 0.42(15.1%) and 0.38(11.8%) kg 10a-1 in application plots of the pig manure compost and aerobic digestate, respectively.

Fıxed bed slow pyrolysıs of bıomass solıd waste for bıo-char

NASA Astrophysics Data System (ADS)

Islam, M. N.; Ali, M. H.; Ahmad, I.

2017-06-01

Biomass solid waste in the form of rice husk particle is pyrolyzed in a fixed bed pyrolysis reactor. The reactor is made of stainless steel with dimensions of 76 mm in diameter and 90 cm in length. Rice husk is collected locally from Brunei-Muara district of Brunei Darussalam which is processed for pyrolysis. The particles are selected in the millimeter range. It is oven-dried at 105°C for 6 hours after being air-dried prior to pyrolysis. The reactor bed is heated by means of saw-dust in a biomass source heater. A temperature range of 390-410°C is maintained with an apperent vapor residence time of 30 min. Nitrogen gas is passed through the reactor system to make the atmosphere inert. A water-cooled condenser is used to derive bio-oil from the condensable vapors. The system is subjected to pyrolysis for a running time of 60 min. The products obtained are solid bio-char, liquid bio-oil and pyrolytic bio-gases. The solid char yield is found to be 45 by weight of solid biomass feedstock and the liquid product yield is found to be 29 by weight of solid biomass feedstock. The rest is gas flared into the atmosphere. The bio-char is retained in the reactor and collected at the end of the experimental run. The bio-char is found to be black in color retaining its original shape. The bio-char product is subjected to energy analysis for its higher heating value (HHV) by means of an oxygen bomb calorimeter. It is found to be 20.3 MJ/kg. The density of the bio-char is found to be 238.5 kg/m3 with an energy density of 4.85 GJ/m3.

Co-pyrolysis behaviour and kinetic of two typical solid wastes in China and characterisation of activated carbon prepared from pyrolytic char.

PubMed

Ma, Yuhui; Niu, Ruxuan; Wang, Xiaona; Wang, Qunhui; Wang, Xiaoqiang; Sun, Xiaohong

2014-11-01

This is the first study on the co-pyrolysis of spent substrate of Pleurotus ostreatus and coal tar pitch, and the activated carbon prepared from the pyrolytic char. Thermogravimetry (TG) analysis was carried out taking spent substrate, coal tar pitch and spent substrate-coal tar pitch mixture. The activation energies of pyrolysis reactions were obtained via the Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose methods. The kinetic models were determined by the master-plots method. The activated carbons were characterised by N2-adsorption, Fourier transform infrared spectroscopy and X-ray diffraction. Experimental results demonstrated a synergistic effect happened during co-pyrolysis, which was characterised by a decreased maximum decomposition rate and an enhanced char yield. The average activation energies of the pyrolysis reactions of spent substrate, coal tar pitch and the mixture were 115.94, 72.92 and 94.38 kJ mol(-1) for the Flynn-Wall-Ozawa method, and 112.17, 65.62 and 89.91 kJ mol(-1) for the Kissinger-Akahira-Sunose method. The reaction model functions were f(α) = (1-α)(3.42), (1-α)(1.72) and (1-α)(3.07) for spent substrate, coal tar pitch and the mixture, respectively. The mixture char-derived activated carbon had a Brunauer-Emmett-Teller surface area up to 1337 m(2) g(-1) and a total pore volume of 0.680 cm(3) g(-1). Mixing spent substrate with coal tar pitch led to the creation of more micropores and a higher surface area compared with the single spent substrate and coal tar pitch char. Also, the mixture char-derived activated carbon had a higher proportion of aromatic stacking. This study provides a reference for the utilisation of spent substrate and coal tar pitch via co-pyrolysis, and their pyrolytic char as a promising precursor of activated carbon. © The Author(s) 2014.

Characterization of fuels for second-generation PFBC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zevenhoven, C.A.P.; Hupa, M.

1997-12-31

In second-generation PFBC technology a solid fuel is partly converted in a devolatilization step (in a carbonizer) to produce a char and a pressurized fuel gas, followed by PFB combustion of the char. The fuel gas is led to the combustion chamber of a gas turbine after it is mixed with the PFBC off-gas, thus increasing the temperature at the inlet of the expansion turbine. Clearly, the optimization of the carbonizer design and operation is essential to the process. Detailed information on the behavior of solid fuels under pressurized conditions is, however, largely limited to steam and/or carbon dioxide gasificationmore » reactivities, obtained at a different combination of process parameters, such as temperature, pressure, heating rate, particle size and gas atmosphere. In the present work, the effect of temperature, pressure and heating rates on the yields of volatiles and char residue reactivity has been measured for a set of fuels ranging from bituminous coal to wood. Laboratory conditions were typical for the carbonizer and combustion reactors in a second-generation PFBC system. A pressurized thermogravimetric reactor (PTGR) operated at heating rates of around 250 K/s and a pressurized grid heater (PGH) operated at heating rates up to 3,000 K/s were used to analyze fuel devolatilization and char reactivity against carbon dioxide or steam at temperatures between 800 and 1,100 C, and 1, 10 or 25 bar total pressure. For comparison, a few experiments were repeated without a separate devolatilization step. The behavior of the various fuels were compared and related to proximate and ultimate fuel analysis. Several empirical, engineering equations are given. A simple 2-parameter model which separates intrinsic surface reactivity and physical, structure effects, very well describes the time-conversion data of the char. It was found that the fuel O/C molar ratio is a very good index for char reactivity, when the char O/C ratio itself is unknown.« less

Charring temperatures are driven by the fuel types burned in a peatland wildfire

PubMed Central

Hudspith, Victoria A.; Belcher, Claire M.; Yearsley, Jonathan M.

2014-01-01

Peatlands represent a globally important carbon store; however, the human exploitation of this ecosystem is increasing both the frequency and severity of fires on drained peatlands. Yet, the interactions between the hydrological conditions (ecotopes), the fuel types being burned, the burn severity, and the charring temperatures (pyrolysis intensity) remain poorly understood. Here we present a post-burn assessment of a fire on a lowland raised bog in Co. Offaly, Ireland (All Saints Bog). Three burn severities were identified in the field (light, moderate, and deeply burned), and surface charcoals were taken from 17 sites across all burn severities. Charcoals were classified into two fuel type categories (either ground or aboveground fuel) and the reflectance of each charcoal particle was measured under oil using reflectance microscopy. Charcoal reflectance shows a positive relationship with charring temperature and as such can be used as a temperature proxy to reconstruct minimum charring temperatures after a fire event. Resulting median reflectance values for ground fuels are 1.09 ± 0.32%Romedian, corresponding to estimated minimum charring temperatures of 447°C ± 49°C. In contrast, the median charring temperatures of aboveground fuels were found to be considerably higher, 646°C ± 73°C (3.58 ± 0.77%Romedian). A mixed-effects modeling approach was used to demonstrate that the interaction effects of burn severity, as well as ecotope classes, on the charcoal reflectance is small compared to the main effect of fuel type. Our findings reveal that the different fuel types on raised bogs are capable of charring at different temperatures within the same fire, and that the pyrolysis intensity of the fire on All Saints Bog was primarily driven by the fuel types burning, with only a weak association to the burn severity or ecotope classes. PMID:25566288

Combustion characteristics of Malaysian oil palm biomass, sub-bituminous coal and their respective blends via thermogravimetric analysis (TGA).

PubMed

Idris, Siti Shawalliah; Rahman, Norazah Abd; Ismail, Khudzir

2012-11-01

The combustion characteristics of Malaysia oil palm biomass (palm kernel shell (PKS), palm mesocarp fibre (PMF) and empty fruit bunches (EFB)), sub-bituminous coal (Mukah Balingian) and coal/biomass blends via thermogravimetric analysis (TGA) were investigated. Six weight ratios of coal/biomass blends were prepared and oxidised under dynamic conditions from temperature 25 to 1100°C at four heating rates. The thermogravimetric analysis demonstrated that the EFB and PKS evolved additional peak besides drying, devolatilisation and char oxidation steps during combustion. Ignition and burn out temperatures of blends were improved in comparison to coal. No interactions were observed between the coal and biomass during combustion. The apparent activation energy during this process was evaluated using iso-conversional model free kinetics which resulted in highest activation energy during combustion of PKS followed by PMF, EFB and MB coal. Blending oil palm biomass with coal reduces the apparent activation energy value. Copyright © 2012 Elsevier Ltd. All rights reserved.

Removal of Cu(II) from acidic electroplating effluent by biochars generated from crop straws.

PubMed

Tong, Xuejiao; Xu, Renkou

2013-04-01

The removal efficiency of copper (Cu(II)) from an actual acidic electroplating effluent by biochars generated from canola, rice, soybean and peanut straws was investigated. The biochars simultaneously removed Cu(II) from the effluent, mainly through the mechanisms of adsorption and precipitation, and neutralized its acidity. The removal efficiency of Cu(II) by the biochars followed the order: peanut straw char > soybean straw char > canola straw char > rice straw char > a commercial activated carbonaceous material, which is consistent with the alkalinity of the biochars. The pH of the effluent was a key factor determining the removal efficiency of Cu(II) by biochars. Raising the initial pH of the effluent enhanced the removal of Cu(II) from it. The optimum pyrolysis temperature was 400 degrees C for producing biochar from crop straws for acidic wastewater treatment, and the optimum reaction time was 8 hr.

Reactivity of young chars via energetic distribution measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Calo, J.M.; Lilly, W.D.

1991-01-01

The current project is directed at developing related techniques for the characterization and prediction/correlation of the reactivity of young'' chars to steam and oxygen. Of particular interest is mapping of the reactivity behavior of the resultant chars, as revealed by the energetic heterogeneity of the complexes with char preparation conditions; i.e., heating rate and ultimate temperature. In this first quarterly technical progress report we present the background of the project and the research program for the proposed investigations. The following work was accomplished on the experimental apparatus: a new set of electronics for the UTi quadrupole mass spectrometer head wasmore » purchased and delivered. The Temperature Programmed Desorption (TPD) System was moved to another laboratory and interfaced with the mass spectrometer system. A Polycold{trademark} freon refrigeration system was repaired and interfaced with the vacuum system for the TPD apparatus. It will be used to cool the diffusion pump trap. 60 refs.« less

Online LC-GC-based analysis of minor lipids in various tree nuts and peanuts.

PubMed

Esche, Rebecca; Müller, Luisa; Engel, Karl-Heinz

2013-11-27

As information on free sterols/stanols and steryl/stanyl esters in nuts is lacking, the compositions and contents of these lipid constituents in ten different nut types were analyzed. The applied approach was based on online liquid chromatography-gas chromatography and enabled the simultaneous analysis of free sterols/stanols and individual steryl/stanyl fatty acid esters, and additionally of tocopherols and squalene. Total contents of free sterols/stanols ranged from 0.62 mg/g nut in hazelnuts to 1.61 mg/g nut in pistachios, with sitosterol as the predominant compound. Total contents of steryl/stanyl fatty acid esters were in the range of 0.11-1.26 mg/g nut, being lowest in Brazil nuts and highest in pistachios. There were considerable differences between the various nut types not only regarding the contents, but also the compositions of both classes. The levels of tocopherols were highest in pine nuts (0.33 mg/g nut); those of squalene were remarkably high in Brazil nuts (1.11 mg/g nut).

Characterization of bio char derived from tapioca skin

NASA Astrophysics Data System (ADS)

Hasnan, F. I.; Iamail, K. N.; Musa, M.; Jaapar, J.; Alwi, H.; Hamid, K. K. K.

2018-03-01

Pyrolysis of tapioca skin was conducted to produce bio chars in the range between 500°C–800°C. Surface modification treatment were performed on bio chars by using chemicals within 24 hours at 30°C and hot water within 1 hour to enhance the bio char’s adsorption properties according to surface area, pore volume, pore size, crystallinity structure and functional groups. The samples were characterized by using BET, XRD, FTIR and Methylene Blue adsorption. Based on BET result, it showed the surface area increased as the pyrolysis temperature increased followed by pore volume and pore size for S0. The optimum temperature for SNaOH, SHW and SMeOH was at 600°C, 700°C and 800°C with the surface area of 75.9874, 274.5066 and 351.5531 m2/g respectively compared to S0 while SP3HO4 has the worst result since it felt on macroporous structure. The percentage of MB adsorption was followed the size of bio chars surface area. Based on FTIR result, at temperature 500°C to 700°C, the bio chars still have functional groups while at 800°C, many functional groups were diminished due to high temperature struck on them. XRD result showed all the bio chars were amorphous. In conclusion, the best surface modification treatment was by Methanol followed by hot water and Sodium Hydroxide at temperature of 700°C and 800°C while Ortho-Phosphoric acid was the worst one and was not suitable for bio char’s surface modification for adsorption purpose.

Nitric oxide reduction in coal combustion: role of char surface complexes in heterogeneous reactions.

PubMed

Arenillas, Ana; Rubiera, Fernando; Pis, José J

2002-12-15

Nitrogen oxides are one of the major environmental problems arising from fossil fuel combustion. Coal char is relatively rich in nitrogen, and so this is an important source of nitrogen oxides during coal combustion. However, due to its carbonaceous nature, char can also reduce NO through heterogeneous reduction. The objectives of this work were on one hand to compare NO emissions from coal combustion in two different types of equipment and on the other hand to study the influence of char surface chemistry on NO reduction. A series of combustion tests were carried out in two different scale devices: a thermogravimetric analyzer coupled to a mass spectrometer and an FTIR (TG-MS-FTIR) and a fluidized bed reactor with an on line battery of analyzers. The TG-MS-FTIR system was also used to perform a specific study on NO heterogeneous reduction reactions using chars with different surface chemistry. According to the results obtained, it can be said that the TG-MS-FTIR system provides valuable information about NO heterogeneous reduction and it can give good trends of the behavior in other combustion equipments (i.e., fluidized bed combustors). It has been also pointed out that NO-char interaction depends to a large extent on temperature. In the low-temperature range (<800 degrees C), NO heterogeneous reduction seems to be controlled by the evolution of surface complexes. In the high-temperature range (>800 degrees C), a different mechanism is involved in NO heterogeneous reduction, the nature of the carbon matrix being a key factor.

[Oral allergy syndrome due to cashew nuts in the patient without pollinosis].

PubMed

Inomata, Naoko; Osuna, Hiroyuki; Ikezawa, Zenro

2006-01-01

A 26-year-old woman felt tingling on her tongue and itching both in the throat and on the face immediately after she put a cashew nut on her tongue. She had a history of atopic dermatitis and bronchial asthma, but not of pollinosis. CAP-FEIA and skin prick test (SPT) were positive for cashew nuts. The results showed negative for peanuts and other tree nuts than cashew nuts. Consequently, she was diagnosed with oral allergy syndrome due to cashew nuts. In addition, the result of skin prick test with cashew nuts normalized one year after she began avoiding cashew nuts, indicating that cashew nuts allergy would be due to sensitization by itself rather than to cross-reactivity between cashew nuts and pollens in this case.

Resin char oxidation retardant for composites

NASA Technical Reports Server (NTRS)

Bowles, K. J.; Gluyas, R. E.

1981-01-01

Boron powder stabilizes char, so burned substances are shiny, smooth, and free of loose graphite fibers. Resin weight loss of laminates during burning in air is identical for the first three minutes for unfilled and boron-filled samples, then boron samples stabilize.

Char from sugarcane bagasse

USDA-ARS?s Scientific Manuscript database

Unused sugarcane bagasse represents an underutilized resource in sugarcane growing regions of the world. This is a renewable resource that can be used in a thermochemical process to create chars, which could be incorporated back into agricultural activities. The practice is likely to improve soil ...

Effects of catalysts on combustion characteristics and kinetics of coal-char blends

NASA Astrophysics Data System (ADS)

Hu, Yingjie; Wang, Zhiqiang; Cheng, Xingxing; Liu, Ming; Ma, Chunyuan

2018-04-01

The effects of Fe2O3, CaO, and MnO2 on the combustion characteristics and kinetics of coal-char blends were investigated using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicated that catalysts exhibited positive effects on the combustion characteristics of coal-char blends, especially in the initial period of coal-char blends combustion. With catalysts addition (mass 1.5%), it could improves volatile matter release, and reduces ignition point, promotes char to begin burning under lower temperature. The ignition index (C) was increased, respectively, by 27% for Fe2O3, 6% for CaO, 11.3% for MnO2, and the combustion characteristic index ( S ) was increased respectively, by 29% for Fe2O3, 5% for CaO, 8.3% for MnO2. In addition, two kinetic models (R2 and F1) were adopted to calculate the kinetic parameters in different stage of combustion processes. The results showed that with Fe2O3 or CaO addition, the activation energy at second stage decreases from 86.0 KJ/mol to 76.92 KJ/mol and 75.12 KJ/mol, respectively. There are no obvious decreases at the third stage of samples combustion process.

Solidifying process and flame retardancy of epoxy resin cured with boron-containing phenolic resin

NASA Astrophysics Data System (ADS)

Deng, Peng; Shi, Yan; Liu, Yuansen; Liu, Yuan; Wang, Qi

2018-01-01

For the sake of improving the charring performance and flame retardancy of epoxy resin (EP), boron-containing phenolic resin (BPR) instead of a conventional curing agent, linear phenolic resin (LPR) was employed to cure EP. Of several possible chemical structures for BPR, the existence of benzyl hydroxy groups in BPR chains has been confirmed using 1H nuclear magnetic resonance spectroscopy. The resonance of these groups may reasonably explain the higher curing reactivity of BPR-cured EP than that of LPR-cured EP. Thermogravimetric analysis, observation of the morphologies of the char residues and X-ray photoelectron spectroscopic were performed to characterize the charring process. Due to the presence of B2O3 produced on the char surface from decomposition of phenyl borates and the facile high self-crosslinking reaction of BPR, a more continuous and stronger char barrier was formed for BPR-cured EP compared to that for the LPR-cured EP system. Therefore the former exhibited much better flame retardancy. In addition, BPR-cured EP also displayed better dynamic mechanical properties, than those observed for LPR-cured EP. It is not subject to the significant lowering the glass transition temperature of the polymer which accompanies curing with LPR. This suggests that BPR cured resin may meet the requirement for utilization at high temperature.

Recovery of a Charred Painting Using Atomic Oxygen Treatment

NASA Technical Reports Server (NTRS)

Rutledge, Sharon K.; Banks, Bruce A.; Chichernea, Virgil A.

1999-01-01

A noncontact method is described which uses atomic oxygen to remove soot and char from the surface of a painting. The atomic oxygen was generated by the dissociation of oxygen in low pressure air using radio frequency energy. The treatment, which is an oxidation process, allows control of the amount of material to be removed. The effectiveness of char removal from half of a fire-damaged oil painting was studied using reflected light measurements from selected areas of the painting and by visual and photographic observation. The atomic oxygen was able to effectively remove char and soot from the treated half of the painting. The remaining loosely bound pigment was lightly sprayed with a mist to replace the binder and then varnish was reapplied. Caution should he used when treating an untested paint medium using atomic oxygen. A representative edge or corner should he tested first in order to determine if the process would be safe for the pigments present. As more testing occurs, a greater knowledge base will be developed as to what types of paints and varnishes can or cannot be treated using this technique. With the proper precautions, atomic oxygen treatment does appear to be a technique with great potential for allowing very charred, previously unrestorable art to be salvaged.

Production and characterization of chars from cherry pulp via pyrolysis.

PubMed

Pehlivan, E; Özbay, N; Yargıç, A S; Şahin, R Z

2017-12-01

Pyrolysis is an eco-friendly process to achieve valuable products like bio-oil, char and gases. In the last decades, biochar production from pyrolysis of a wide variety of industrial and agricultural wastes become popular, which can be utilized as adsorbent instead of the expensive activated carbons. In this study, cherry pulp was pyrolyzed in a fixed bed tubular reactor at five different temperatures (400, 500,550, 600 and 700 °C) and three different heating rates (10, 100 and 200 °C/min) to obtain biochar. Proximate, ultimate, nitrogen adsorption/desorption isotherms, scanning electron microscopy, thermogravimetric analysis, x-ray fluorescence, x-ray diffraction, and Fourier transform infrared spectroscopy were performed on cherry pulp and its chars to examine the chemical alterations after the pyrolysis process. Biochar yields were decreased with increasing pyrolysis temperature and heating rate, based on experimental results. Porous biochars are carbon rich and includes high potassium content. The aromaticity of biochars increased and O/C mass ratio reduced with an increase in the pyrolysis temperature as a result of the development of compact aromatic structure in char. Pyrolysis provides a promising conversion procedure for the production of high energy density char which has promising applications in existing coal-fired boilers without any upgrading. Copyright © 2017 Elsevier Ltd. All rights reserved.

Graphite and ablative material response to CO2 laser, carbon-arc, and xenon-arc radiation

NASA Technical Reports Server (NTRS)

Brewer, W. D.

1976-01-01

The behavior was investigated of graphite and several charring ablators in a variety of high-radiative heat-flux environments. A commercial-grade graphite and nine state-of-the-art charring ablators were subjected to various radiative environments produced by a CO2 laser and a carbon arc. Graphite was also tested in xenon-arc radiation. Heat-flux levels ranged from 10 to 47 MW/sq m. Tests were conducted in air, nitrogen, helium, and a CO2-N2 mixture which simulated the Venus atmosphere. The experimental results were compared with theoretical results obtained with a one-dimensional charring-ablator analysis and a two-dimensional subliming-ablator analysis. Neither the graphite nor the charring ablators showed significant differences in appearance or microstructure after testing in the different radiative environments. The performance of phenolic nylon and graphite was predicted satisfactorily with existing analyses and published material property data. Good agreement between experimental and analytical results was obtained by using sublimation parameters from a chemical nonequilibrium analysis of graphite sublimation. Some charring ablators performed reasonably well and could withstand radiative fluxes of the level encountered in certain planetary entries. Other materials showed excessive surface recession and/or large amounts of cracking and spalling, and appear to be unsuitable for severe radiative environments.

Role of charred wood, heat-shock and light in germination of postfire phrygana species from the eastern Mediterranean Basin

USGS Publications Warehouse

Keeley, Jon E.; Babr-Keeley, Melanie

1999-01-01

Seeds of 22 species collected from recently burned phrygana were tested for their response to fire-type cues of charred wood and heat-shock. All Cistus species were stimulated by brief heat-shock, as shown in previous studies; however, none responded to charred wood. Only one of the 22 species was stimulated by charred wood, and only in dark-inhibited seeds, and this response did not occur in the light. The lack of charred-wood-induced germination is in contrast to the substantial proportion of species with this germination response reported for mediterranean-type vegetation in California, the Cape region of South Africa, and Western Australia. Phrygana has many species with heat-shock-stimulated germination, primarily in the Fabaceae and Cistaceae. This germination cue is widespread in these two families, thus, the presence of heat-shock-stimulated germination is a result of homologous, rather than covergent, adaptations in mediterranean-climate ecosystems. Germination response to light was not randomly distributed with respect to fire-type response. Heat-shock-stimulated species were almost uniformly light neutral, in contrast to more opportunistic colonizing species with non-refractory seeds, in which half of the species responded positively or negatively to light.

Longitudinal Analysis of Nut-Inclusive Diets and Body Mass Index Among Overweight and Obese African American Women Living in Rural Alabama and Mississippi, 2011-2013.

PubMed

Sterling, Samara R; Bertrand, Brenda; Judd, Suzanne; Carson, Tiffany L; Chandler-Laney, Paula; Baskin, Monica L

2017-09-21

Nuts, when eaten alongside other nutritionally rich foods, may decrease obesity and related chronic disease risks, which are high among African American women in the rural South. We monitored changes in nut intake, other obesity-related foods (fruits, vegetables, red or processed meats, added sugars), and body mass index (BMI) over a 2-year weight loss intervention among 383 overweight and obese African American women in rural Alabama and Mississippi. Two dietary recalls were administered at 4 points over 24 months. Mann-Whitney tests compared differences in median food group intake between nut consumers and non-nut consumers, and t tests identified BMI differences between groups. Mixed linear models tested the relationship between nut intake and intake of the select food groups, and between nut intake and BMI over time. Overall nut consumers ate more fruits and vegetables and less red meat than non-nut consumers. Nut consumers had lower BMI values than non-nut consumers. Weight loss by the end of the intervention was significant for nut consumers but not for non-nut consumers, even after accounting for kilocalorie consumption and physical activity engagement. Nut consumption is associated with consumption of other nutritionally rich foods and lower BMI among African American women in rural Alabama and Mississippi. Future interventions should target increasing daily nut intake, decreasing added sugar intake, and identifying strategies to encourage positive dietary changes to continue after an intervention.

Perceptions and Knowledge of Nuts amongst Health  Professionals in New Zealand.

PubMed

Brown, Rachel C; Yong, Lee Ching; Gray, Andrew R; Tey, Siew Ling; Chisholm, Alexandra; Leong, Sook Ling

2017-03-01

Despite their nutritional value, population-level nut consumption remains low. Studies suggest that individuals would eat more nuts on their doctor's advice, making health professionals potentially important for promoting nut consumption. This cross-sectional study aimed to examine the perceptions and knowledge of nuts and the predictors of nut promotion among health professionals in New Zealand. Dietitians, general practitioners (GPs), and practice nurses were identified from the Electoral Roll and invited to complete a questionnaire (n = 318, 292, and 149 respondents respectively). Over one-fifth of GPs and practice nurses believed that eating nuts could increase blood cholesterol concentrations and cause weight gain. The most common perceptions overall were that nuts are healthy; high in protein, fat, and calories; and are satiating. Nut consumption was recommended for reasons relating to these perceptions and because of nuts' selenium content. Conversely, reasons for suggesting the consumption of fewer nuts included that they were high in calories and fat, would cause weight gain, and concerns regarding allergies and cost. All groups of health professionals were more likely to promote nut consumption if they perceived nuts to reduce the risk of diabetes (all p ≤ 0.034). Education could improve health professionals' knowledge regarding the effects of nut consumption on blood cholesterol and body weight, alongside other health benefits, which should improve the advice given to patients and may thereby increase nut consumption.

Nuts in the prevention and treatment of metabolic syndrome.

PubMed

Salas-Salvadó, Jordi; Guasch-Ferré, Marta; Bulló, Mònica; Sabaté, Joan

2014-07-01

Nuts are rich in many bioactive compounds that can exert beneficial effects on cardiovascular health. We reviewed the evidence relating nut consumption and the metabolic syndrome (MetS) and its components. Nuts reduce the postprandial glycemic response; however, long-term trials of nuts on insulin resistance and glycemic control in diabetic individuals are inconsistent. Epidemiologic studies have shown that nuts may lower the risk of diabetes incidence in women. Few studies have assessed the association between nuts and abdominal obesity, although an inverse association with body mass index and general obesity has been observed. Limited evidence suggests that nuts have a protective effect on blood pressure and endothelial function. Nuts have a cholesterol-lowering effect, but the relation between nuts and hypertriglyceridemia and high-density lipoprotein cholesterol is not well established. A recent pooled analysis of clinical trials showed that nuts are inversely related to triglyceride concentrations only in subjects with hypertriglyceridemia. An inverse association was found between the frequency of nut consumption and the prevalence and the incidence of MetS. Several trials evaluated the effect of nuts on subjects with MetS and found that they may have benefits in some components. Compared with a low-fat diet, a Mediterranean diet enriched with nuts could be beneficial for MetS management. The protective effects on metabolism could be explained by the modulation of inflammation and oxidation. Further trials are needed to clarify the role of nuts in MetS prevention and treatment. © 2014 American Society for Nutrition.

The two NUT-like solutions of Ernst equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu Yabo; Dong Peng; Deng Xuemei

By applying Ehlers transformation to Schwarzschild and Kerr solutions of Ernst equation and choosing the suitable coordinate transformations, the two NUT-like solutions, i.e., the so called NUT-Taub-like and the Kerr-NUT-like solutions are obtained which not only can, respectively, reduce to Schwarzschild and Kerr solutions when the parameter l{sup '}=0, but also can also reduce to the NUT-Taub metric and Kerr-NUT metric, respectively, when l{sup '} satisfies the some approximation. Meanwhile it is shown that in the NUT-Taub and Kerr-NUT solutions the range of value for the parameter l interpreted as the gravomagnetic monopole cannot be arbitrary and should be confinedmore » by mass of the source to vertical bar l vertical bar<

Perceptions and Knowledge of Nuts amongst Health Professionals in New Zealand

PubMed Central

Brown, Rachel C.; Yong, Lee Ching; Gray, Andrew R.; Tey, Siew Ling; Chisholm, Alexandra; Leong, Sook Ling

2017-01-01

Despite their nutritional value, population-level nut consumption remains low. Studies suggest that individuals would eat more nuts on their doctor’s advice, making health professionals potentially important for promoting nut consumption. This cross-sectional study aimed to examine the perceptions and knowledge of nuts and the predictors of nut promotion among health professionals in New Zealand. Dietitians, general practitioners (GPs), and practice nurses were identified from the Electoral Roll and invited to complete a questionnaire (n = 318, 292, and 149 respondents respectively). Over one-fifth of GPs and practice nurses believed that eating nuts could increase blood cholesterol concentrations and cause weight gain. The most common perceptions overall were that nuts are healthy; high in protein, fat, and calories; and are satiating. Nut consumption was recommended for reasons relating to these perceptions and because of nuts’ selenium content. Conversely, reasons for suggesting the consumption of fewer nuts included that they were high in calories and fat, would cause weight gain, and concerns regarding allergies and cost. All groups of health professionals were more likely to promote nut consumption if they perceived nuts to reduce the risk of diabetes (all p ≤ 0.034). Education could improve health professionals’ knowledge regarding the effects of nut consumption on blood cholesterol and body weight, alongside other health benefits, which should improve the advice given to patients and may thereby increase nut consumption. PMID:28257045

Blind-Anchor-Nut-Installation Fixture (BANIF)

NASA Technical Reports Server (NTRS)

Willey, Norman F., Jr.; Linker, James F.

1994-01-01

Blind-anchor-nut-installation fixture, BANIF, developed for replacing or installing anchor nuts in blind holes or other inaccessible places. Attachment of anchor nut to BANIF enables placement of anchor nut on blind side of component.

Tree nut consumption improves nutrient intake and diet quality in US adults: an analysis of National Health and Nutrition Examination Survey (NHANES) 1999-2004

USDA-ARS?s Scientific Manuscript database

Recent epidemiologic studies assessing tree nut (almonds, Brazil nuts, cashews, hazelnuts, macadamia nuts, pecans, pine nuts, pistachios, and walnuts) consumption and the association with nutrient intake and diet quality are lacking. This study determined the association of tree nut consumption and ...

Time domain-nuclear magnetic resonance study of chars from southern hardwoods

Treesearch

Thomas Elder; Nicole Labbe; David Harper; Timothy Rials

2006-01-01

Chars from the thermal degradation of silver maple (Acer saccharinum), red maple (Acer rubrum), sugar maple (Acer saccharum), and white oak (Quercus spp.), performed at temperatures from 250 to 350 oC, were examined using time domain-nuclear magnetic resonance...

iQOS: evidence of pyrolysis and release of a toxicant from plastic.

PubMed

Davis, Barbara; Williams, Monique; Talbot, Prue

2018-03-13

To evaluate performance of the I quit original smoking (iQOS) heat-not-burn system as a function of cleaning and puffing topography, investigate the validity of manufacturer's claims that this device does not burn tobacco and determine if the polymer-film filter is potentially harmful. iQOS performance was evaluated using five running conditions incorporating two different cleaning protocols. Heatsticks were visually and stereomicroscopically inspected preuse and postuse to determine the extent of tobacco plug charring (from pyrolysis) and polymer-film filter melting, and to elucidate the effects of cleaning on charring. Gas chromatography-mass spectrometry headspace analysis was conducted on unused polymer-film filters to determine if potentially toxic chemicals are emitted from the filter during heating. For all testing protocols, pressure drop decreased as puff number increased. Changes in testing protocols did not affect aerosol density. Charring due to pyrolysis (a form of organic matter thermochemical decomposition) was observed in the tobacco plug after use. When the manufacturer's cleaning instructions were followed, both charring of the tobacco plug and melting of the polymer-film filter increased. Headspace analysis of the polymer-film filter revealed the release of formaldehyde cyanohydrin at 90°C, which is well below the maximum temperature reached during normal usage. Device usage limitations may contribute to decreases in interpuff intervals, potentially increasing user's intake of nicotine and other harmful chemicals. This study found that the tobacco plug does char and that charring increases when the device is not cleaned between heatsticks. Release of formaldehyde cyanohydrin is a concern as it is highly toxic at very low concentrations. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

Devolatilization of coal particles in a flat flame -- Experimental and modeling study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Therssen, E.; Gourichon, L.; Delfosse, L.

1995-10-01

Pulverized coals have been tested under the conditions of industrial flames, with high heating rate and high temperatures. The chars were collected after different pyrolysis times. For eight coals, the devolatilized fraction of coal has been measured, as well as those of carbon, hydrogen and nitrogen. During pyrolysis, the evolution of the texture of the grains has been studied by measurement of their microporous surface area, which undergoes a large increase, depending on coal rank. The composition of the volatiles, as deduced from the ultimate and proximate analysis of chars, showed high volatile bituminous coals to essentially produce tars withmore » an aromatic structure. Low and medium volatile bituminous coals produced light hydrocarbons on devolatilization and the char`s surface area continued increasing slowly during the whole of devolatilization, according to the slow increase of the fraction of hydrogen devolatilized. The char`s reactivity with oxygen was followed by measurements of Active Surface Area (ASA). It was shown that the ASA continuously decreases during devolatilization. Five models of devolatilization in the literature were tested and compared to the experimental results, assuming first-order reactions with respect to the remaining volatile matter. Badzioch`s model correctly fitted the experimental results and values of the rate constant obtained by computer trial and error adjustment were higher for lower ranks of the four bituminous coals. Anthony`s model also fits the measurements, provided an adjustment of the preexponential factor of activation energy for which it is shown that an infinite number of such pairs is suitable. If the model is run isothermally at the flame`s peak temperature, it also correctly fits the experimental results.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Suuberg, E.M.; Lilly, W.D.; Aarna, I.

This project is concerned with the mechanism of reduction of both NO and N{sub 2}O by carbons. It was recognized some years ago that NO formed during fluidized bed coal combustion can be heterogeneously reduced in-situ by the carbonaceous solid intermediates of combustion. This has been recently supplemented by the knowledge that heterogeneous reaction with carbon can also play an important role in reducing emissions of N{sub 2}, but that the NO-carbon reactions might also contribute to formation of N{sub 2}. The precise role of carbon in N{sub 2} reduction and formation has yet to be established. Interest in themore » N{sub 2} and N{sub 2}O-char reactions has been significant in connection with both combustor modeling, as well as in design of post-combustion NO{sub x} control strategies. In our studies, a DuPont thermogravimetric analyzer (TGA) is used for the char reactivity studies. The temperature and mass are recorded as function of time, using a Macintosh computer and software for simultaneous apparatus control and data acquisition. Specific surface areas of char samples were determined by the N{sub 2} BET method at 77 K. A standard flow-type adsorption device (Quantasorb) was used for the measurements. Prior to surface area analysis, all samples were outgassed in a flow of nitrogen at 573 K for 3 hours. The carbonaceous solids used were resin char, graphite, coconut char and a Wyodak coal char. As was noted in the last report, carbons derived from different original materials show quite similar behaviors, in terms of the trends, but there are significant differences in actual reaction rates. It was shown that the spread of the reaction rate data from different studies, when expressed on a mass of carbon reactant- or surface area-basis, was almost the same.« less

Towards User-Friendly Spelling with an Auditory Brain-Computer Interface: The CharStreamer Paradigm

PubMed Central

Höhne, Johannes; Tangermann, Michael

2014-01-01

Realizing the decoding of brain signals into control commands, brain-computer interfaces (BCI) aim to establish an alternative communication pathway for locked-in patients. In contrast to most visual BCI approaches which use event-related potentials (ERP) of the electroencephalogram, auditory BCI systems are challenged with ERP responses, which are less class-discriminant between attended and unattended stimuli. Furthermore, these auditory approaches have more complex interfaces which imposes a substantial workload on their users. Aiming for a maximally user-friendly spelling interface, this study introduces a novel auditory paradigm: “CharStreamer”. The speller can be used with an instruction as simple as “please attend to what you want to spell”. The stimuli of CharStreamer comprise 30 spoken sounds of letters and actions. As each of them is represented by the sound of itself and not by an artificial substitute, it can be selected in a one-step procedure. The mental mapping effort (sound stimuli to actions) is thus minimized. Usability is further accounted for by an alphabetical stimulus presentation: contrary to random presentation orders, the user can foresee the presentation time of the target letter sound. Healthy, normal hearing users (n = 10) of the CharStreamer paradigm displayed ERP responses that systematically differed between target and non-target sounds. Class-discriminant features, however, varied individually from the typical N1-P2 complex and P3 ERP components found in control conditions with random sequences. To fully exploit the sequential presentation structure of CharStreamer, novel data analysis approaches and classification methods were introduced. The results of online spelling tests showed that a competitive spelling speed can be achieved with CharStreamer. With respect to user rating, it clearly outperforms a control setup with random presentation sequences. PMID:24886978

Nuts, especially walnuts, have both antioxidant quantity and efficacy and exhibit significant potential health benefits.

PubMed

Vinson, Joe A; Cai, Yuxing

2012-02-01

Free and total (after basic hydrolysis) polyphenols in nine types of raw and roasted nuts and two types of peanut butter (54 commercial samples) were analyzed after methanol extraction by a single step Folin-Ciocalteu reagent using catechin as standard. Walnuts had the highest free and total polyphenols in both the combined raw and roasted samples. Total polyphenols in the nuts were significantly higher than free polyphenols. Roasting had little effect on either free or total polyphenols in nuts. Raw and roasted walnuts had the highest total polyphenols. The efficacy of raw and roasted nut antioxidants was assessed by measuring the ability of the free polyphenol nut extracts to inhibit the oxidation of lower density lipoproteins (LDL + VLDL). A nut polyphenol, catechin, was measured after binding of three nut extracts to lower density lipoproteins. Walnut polyphenols had the best efficacy among the nuts and also the highest lipoprotein-bound antioxidant activity. Based on USDA availability data, the per capita total polyphenols was 162 mg from nuts per day in 2008. This corresponds to 19% of the total polyphenols from fruits and vegetables, nuts, grains, oils and spices in the US diet. Nuts provided 158 mg of polyphenols per day to the European Union diet. Nuts are high in polyphenol antioxidants which by binding to lipoproteins would inhibit oxidative processes that lead to atherosclerosis in vivo. In human supplementation studies nuts have been shown to improve the lipid profile, increase endothelial function and reduce inflammation, all without causing weight gain. These qualities make nuts a nutritious healthy snack and food additive.

Taking actions to quit chewing betel nuts and starting a new life: taxi drivers' successful experiences of quitting betel nut chewing.

PubMed

Yang, Tsui-Yun; Lin, Hung-Ru

2017-04-01

To understand taxi drivers' successful experiences of quitting betel nut chewing. Previous studies verified that betel nut chewing significantly increases the risk of oral cancer. In Taiwan, taxi drivers work for approximately 10-13 hours per day, and 31·7-80% of them choose to chew betel nuts for their invigorating qualities, which enable them to work more hours and receive more income. A qualitative research design was used. This study used the grounded theory method with purposive sampling to perform in-depth interviews with male taxi drivers who had successfully quit betel nut chewing for more than six months. The interviewed participants were 25 taxi drivers aged 45-67 who had chewed betel nuts for an average of 30·9 years. A constant comparative analysis of the 25 interviews revealed six categories, namely the first experience of chewing betel nuts, a part of work and life, perceiving the impact of betel nuts, trying to change, acting to quit betel nut chewing and starting a new life. During the cessation process, taxi drivers tended to be affected by their addiction to chewing betel nuts and the temptation of friends' invitations to chew betel nuts. However, their recognition of the physical effects of betel nut chewing and their sense of responsibility and commitment to family were the critical factors affecting their determination to quit betel nut chewing. Their willpower to not to chew betel nuts and the source of their motivation to exercise self-control also contributed to their success. Healthcare personnel should understand the experiences and perceptions of betel nut chewers, strengthen their understanding of the effects of betel nut chewing on physical health during the cessation period and support their self-efficacy and quitting behaviours with the assistance of significant others. © 2016 John Wiley & Sons Ltd.

ON-SITE PRODUCTION OF ACTIVATED CARBON FROM KRAFT BLACK LIQUOR

EPA Science Inventory

A pilot plant was designed and constructed to produce char via the St. Regis hydropyrolysis kraft chemical recovery process and to produce activated carbon from the char. This report includes discussion of laboratory and prepilot work, the pilot plant, and presents operating resu...

Co-hydrothermal treatment of fallen leaves with iron sludge to prepare magnetic iron product and solid fuel.

PubMed

Gu, Lin; Li, Binglian; Wen, Haifeng; Zhang, Xin; Wang, Liang; Ye, Jianfeng

2018-06-01

The hydrothermal carbonization (HTC) was performed on Metasequoia Leaves (ML) in the presence of iron sludge, both of which were generated as solid residuals. The relations between sludge, char's properties and operating conditions were systemically investigated. Iron sludge primarily catalyzed the efficient formation of char with higher heating value (HHV) becoming 1.15-1.65 times of ML (18.21 MJ/kg) and was meanwhile reduced to magnetite. The hydrated Fe ions in octahedron crystals acted as nucleophiles facilitating the dehydration and decarboxylation reactions. The increased HHV is found strong temperature dependent while prolonging the residence time is more preferable for low organic acids generation. Thermogravimetric analysis confirmed the iron sludge enhanced conversion of volatile to fixed carbon. The as-prepared solid char showed better stability after catalytic HTC treatment, having ignition temperature increased from 253 to 426 °C as compared to the char prepared without iron sludge addition. Copyright © 2018 Elsevier Ltd. All rights reserved.

An analysis of a charring ablator with thermal nonequilibrium, chemical kinetics, and mass transfer

NASA Technical Reports Server (NTRS)

Clark, R. K.

1973-01-01

The differential equations governing the transient response of a one-dimensional ablative thermal protection system are presented for thermal nonequilibrium between the pyrolysis gases and the char layer and with finite rate chemical reactions occurring. The system consists of three layers (the char layer, the uncharred layer, and an optical insulation layer) with concentrated heat sinks at the back surface and between the second and third layers. The equations are solved numerically by using a modified implicit finite difference scheme to obtain solutions for the thickness of the charred and uncharred layers, surface recession and pyrolysis rates, solid temperatures, porosity profiles, and profiles of pyrolysis-gas temperature, pressure, composition, and flow rate. Good agreement is obtained between numerical results and exact solutions for a number of simplified cases. The complete numerical analysis is used to obtain solutions for an ablative system subjected to a constant heating environment. Effects of thermal, chemical, and mass transfer processes are shown.

Torrefaction of agriculture straws and its application on biomass pyrolysis poly-generation.

PubMed

Chen, Yingquan; Yang, Haiping; Yang, Qing; Hao, Hongmeng; Zhu, Bo; Chen, Hanping

2014-03-01

This study investigated the properties of corn stalk and cotton stalk after torrefaction, and the effects of torrefaction on product properties obtained under the optimal condition of biomass pyrolysis polygeneration. The color of the torrefied biomass chars darkened, and the grindability was upgraded, with finer particles formed and grinding energy consumption reduced. The moisture and oxygen content significantly decreased whereas the carbon content increased considerably. It was found that torrefaction had different effects on the char, liquid oil and biogas from biomass pyrolysis polygeneration. Compared to raw straws, the output of chars from pyrolysis of torrefied straws increased and the quality of chars as a solid fuel had no significant change, while the output of liquid oil and biogas decreased. The liquid oil contained more concentrated phenols with less water content below 40wt.%, and the biogas contained more concentrated H2 and CH4 with higher LHV up to 15MJ/nm(3). Copyright © 2014 Elsevier Ltd. All rights reserved.

Physicochemical evolution during rice straw and coal co-pyrolysis and its effect on co-gasification reactivity.

PubMed

Wei, Juntao; Gong, Yan; Guo, Qinghua; Ding, Lu; Wang, Fuchen; Yu, Guangsuo

2017-03-01

Physicochemical evolution (i.e. pore structure variation, carbon structure change and active AAEM transformation) during rice straw (RS) and Shenfu bituminous coal (SF) co-pyrolysis was quantitatively determined in this work. Moreover, the corresponding char gasification was conducted using a thermogravimetric analyzer (TGA) and relative reactivity was proposed to quantify the co-pyrolysis impact on co-gasification reactivity. The results showed that the development of pore structure in co-pyrolyzed chars was first inhibited and then enhanced with the decrease of SF proportion. The promotion effect of co-pyrolysis on order degree of co-pyrolyzed chars gradually weakened with increasing RS proportion. Co-pyrolysis mainly enhanced active K transformation in co-pyrolyzed chars and the promotion effect was alleviated with increasing RS proportion. The inhibition effect of co-pyrolysis on co-gasification reactivity weakened with increasing RS proportion and gasification temperature, which was mainly attributed to the combination of carbon structure evolution and active AAEM transformation in co-pyrolysis. Copyright © 2016 Elsevier Ltd. All rights reserved.

Strategy for Passivating Char Efficiently at the Pilot Scale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dunning, Timothy C

Fast pyrolysis is a promising pathway for the commercialization of liquid transportation fuels from biomass. Fast pyrolysis is performed at moderate heat (450-600 degrees Celcius) in an oxygen-deficient environment. One of the products of fast pyrolysis is biochar, which is often used as a heat source or as a soil amendment. Biochar is a partially reacted solid that is created in the production of bio-oil during fast pyrolysis. Biochar produced at these conditions contains significant quantities of carbon that adsorb oxygen when exposed to air. Biochar adsorption of oxygen is an exothermic process that may generate sufficient heat for combustionmore » in ambient air. Biochar is also a self-insulating material which compounds the effects of heat generated internally. These factors lead to safety concerns and material handling difficulties. The Thermochemical Process Development Unit at the National Renewable Energy Laboratory operates a pilot plant that may be configured for fast pyrolysis, gasification, and will be introducing catalytic fast pyrolysis capabilities in 2018. The TCPDU designed and installed a system to introduce oxygen to collected biochar systematically for a controlled passivation. Biochar is collected and cooled in an oxygen deficient environment during fast pyrolysis. Oxygen is then introduced to the biochar on a mass flow basis. A sparger imbedded within the biochar sample near the bottom of the bed flows air diluted with nitrogen into the char bed, and excess gasses are removed from the top of the collection drum, above the char bed. Pressure within the collection drum is measured indicating adequate flow through filters. Sample weight is recorded before and after passivation. During passivation, temperature is measured at 18 points within the char bed. Oxygen content and temperature are measured leaving the char bed. Maximum temperature parameters were established to ensure operator safety during biochar passivation. Extensive passivation data was collected on pine and blended feedstocks and has been analyzed to characterize the exotherm of char samples. Observations and data collected while passivating char will be discussed.« less

Mitigation of methane production from cattle by feeding cashew nut shell liquid.

PubMed

Shinkai, T; Enishi, O; Mitsumori, M; Higuchi, K; Kobayashi, Y; Takenaka, A; Nagashima, K; Mochizuki, M; Kobayashi, Y

2012-09-01

The effects of cashew nut shell liquid (CNSL) feeding on methane production and rumen fermentation were investigated by repeatedly using 3 Holstein nonlactating cows with rumen fistulas. The cows were fed a concentrate and hay diet (6:4 ratio) for 4 wk (control period) followed by the same diet with a CNSL-containing pellet for the next 3 wk (CNSL period). Two trials were conducted using CNSL pellets blended with only silica (trial 1) or with several other ingredients (trial 2). Each pellet type was fed to cows to allow CNSL intake at 4 g/100 kg of body weight per day. Methane production was measured in a respiration chamber system, and energy balance, nutrient digestibility, and rumen microbial changes were monitored. Methane production per unit of dry matter intake decreased by 38.3 and 19.3% in CNSL feeding trials 1 and 2, respectively. Energy loss as methane emission decreased from 9.7 to 6.1% (trial 1) and from 8.4 to 7.0% (trial 2) with CNSL feeding, whereas the loss to feces (trial 1) and heat production (trial 2) increased. Retained energy did not differ between the control and CNSL periods. Digestibility of dry matter and gross energy decreased with CNSL feeding in trial 1, but did not differ in trial 2. Feeding CNSL caused a decrease in acetate and total short-chain fatty acid levels and an increase in propionate proportion in both trials. Relative copy number of methyl coenzyme-M reductase subunit A gene and its expression decreased with CNSL feeding. The relative abundance of fibrolytic or formate-producing species such as Ruminococcus flavefaciens, Butyrivibrio fibrisolvens, and Treponema bryantii decreased, but species related to propionate production, including Prevotella ruminicolla, Selenomonas ruminantium, Anaerovibrio lipolytica, and Succinivibrio dextrinosolvens, increased. If used in a suitable formulation, CNSL acts as a potent methane-inhibiting and propionate-enhancing agent through the alteration of rumen microbiota without adversely affecting feed digestibility. Copyright © 2012 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Particle-Sizing System for Scanning Electron Microscope Images of Solid- Propellant Combustion Exhaust

DTIC Science & Technology

1991-03-01

bl2[3]; 1* ditto */ char b13(61, b1413]; /* unused at the moment ~ char bl5(3], b16 (3], b17[31, b18[3]; /* YIN input buffers * char bl9[3], b20[3...gbool(SET,frm,13,wn.10, 1, ’ALL: Enable HELP screens (Y,N] fatrib,’ - ,&HELPLVL,bl5,NSTR,NSTR); bool2YN(DOSEQ, b16 ); wngbool(SET,frm,14,wn,ll, l,’SEMEX...CLIP, TAG and SIZE without asking[Y.N): fatrib,’ ’ ,&DOSEQ, bl6 ,NSTR.NSTR): bool2YN(DFINVERT,b17); wngbool(SET,frm,15,wn,12, 1, ACQUIRE: Complement

Considerations Based on Reaction Rate on Char Gasification Behavior in Two-stage Gasifier for Biomass

NASA Astrophysics Data System (ADS)

Taniguchi, Miki; Nishiyama, Akio; Sasauchi, Kenichi; Ito, Yusuke; Akamatsu, Fumiteru

In order to develop a small-scale gasifier in which biomass can be converted to energy with high efficiency, we planned a gasification process that consists of two parts: pyrolysis part (rotary kiln) and gasification part (downdraft gasifier). We performed fundamental experiments on gasification part and discussed the appropriate conditions such as air supply location, air ratio, air temperature and hearth load. We considered the results by calculating reaction rates of representative reactions on char gasification part and found that water gas reaction is dominant in the reduction area and its behavior gives important information to decide the adequate length of the char layer.

Numerical analysis of the transient response of an axisymmetric ablative char layer considering internal flow effects

NASA Technical Reports Server (NTRS)

Pittman, C. M.; Howser, L. M.

1972-01-01

The differential equations governing the transient response of the char layer of an ablating axisymmetric body, internal pyrolysis gas flow effects being considered, have been derived. These equations have been expanded into finite difference form and programed for numerical solution on a digital computer. Numerical results compare favorably with simplified exact solutions. The complete numerical analysis was used to obtain solutions for two representative body shapes subjected to a typical entry heating environment. Pronounced effects of the lateral flow of pyrolysis gases on the mass flow field within the char layer and the associated surface and pyrolysis interface recession rates are shown.

Decision Support Functions for the Retail Operations Management System.

DTIC Science & Technology

1984-09-01

0003 NUTS , PLANTERS PEANUTS CN 1 .10 Al 053200-0006 NUTS , PLANTERS MIXED CN 1.05 Al 053200-001 1 NUTS , PLANTERS CASHEWS CN 2.55 Al 053200-0052 NUTS ...PLANTERS SPANISH PEA CN 1.10 Al 053200-4877 NUTS , SMOKE HOUSE ALMONDS EA .25 A2 101120-0002 CIO, CAMEL REG PK .40 A2 101120-0004 CIO, VANTAGE REG PK .40...CANDY, TOOTSIE POP DROP EA .1450 112 033200-0006 NUTS , PLANTERS MIXED CN 1.0910 72 053200-4877 NUTS , SMOKE HOUSE ALMONDS EA .1456 44 101120-0003 CIG

Nuts and Human Health Outcomes: A Systematic Review

PubMed Central

de Souza, Rávila Graziany Machado; Schincaglia, Raquel Machado; Pimentel, Gustavo Duarte

2017-01-01

There has been increasing interest in nuts and their outcome regarding human health. The consumption of nuts is frequently associated with reduction in risk factors for chronic diseases. Although nuts are high calorie foods, several studies have reported beneficial effects after nut consumption, due to fatty acid profiles, vegetable proteins, fibers, vitamins, minerals, carotenoids, and phytosterols with potential antioxidant action. However, the current findings about the benefits of nut consumption on human health have not yet been clearly discussed. This review highlights the effects of nut consumption on the context of human health. PMID:29207471

Comparative study between two animal models of extrapyramidal movement disorders: prevention and reversion by pecan nut shell aqueous extract.

PubMed

Trevizol, Fabiola; Benvegnú, Dalila M; Barcelos, Raquel C S; Pase, Camila S; Segat, Hecson J; Dias, Verônica Tironi; Dolci, Geisa S; Boufleur, Nardeli; Reckziegel, Patrícia; Bürger, Marilise E

2011-08-01

Acute reserpine and subchronic haloperidol are animal models of extrapyramidal disorders often used to study parkinsonism, akinesia and tardive dyskinesia. In humans, these usually irreversible and disabling extrapyramidal disorders are developed by typical antipsychotic treatment, whose pathophysiology has been related to oxidative damages development. So far, there is no treatment to prevent these problems of the psychiatric clinic, and therefore further studies are needed. Here we used the animal models of extrapyramidal disorders cited above, which were performed in two distinct experiments: orofacial dyskinesia (OD)/catalepsy induced by acute reserpine and subchronic haloperidol after (experiment 1) and before (experiment 2) oral treatment with pecan shell aqueous extract (AE), a natural and promissory antioxidant. When administered previously (exp.1), the AE prevented OD and catalepsy induced by both reserpine and haloperidol. When reserpine and haloperidol were administered before the extract (exp.2), the animals developed OD and catalepsy all the same. However, the orofacial parameter (but not catalepsy) in both animal models was reversed after 7 and 14 days of AE treatment. These results indicate that, acute reserpine and subchronic haloperidol administrations induced similar motor disorders, although through different mechanisms, and therefore are important animal models to study the physiopathology of extrapyramidal disorders. Comparatively, the pecan shell AE was able to both prevent and reverse OD but only to prevent catalepsy. These results reinforce the role of oxidative stress and validate the two animal models used here. Our findings also favor the idea of prevention of extrapyramidal disorders, rather than their reversal. Copyright © 2011 Elsevier B.V. All rights reserved.

Microanalysis of vitrous char and associated polymers: reference and ancient assemblages

NASA Astrophysics Data System (ADS)

Allue, E.; Bonnamy, S.; Courty, M. M.; Gispert I Guirado, F.

2012-12-01

Formation of vitrous char that occur in ancient charcoal assemblages have remained unsolved. Laboratory experiments refuted vitrification to resulting from high temperature charring of green or resinous wood. This puzzling problem has been refreshed by showing the association to the charcoal and vitrous char of plastics that were originally supposed to only be produced by petroleum industry. Extraction of similar polymers within geological glassy products from cosmic airbursts has suggested impact processes to possibly forming the carbonaceous polymorphs. The pulverisation at the ground in the Angles village (French Eastern Pyrenees) following the 2011 August 2nd high altitude meteor explosion of exotic debris with vitrous char and polymers, just alike the puzzling ones of the geological and archaeological records, has provided potential reference materials. We present here their microanalysis by Environmental SEM with EDS, Raman micro-spectrometry and FTIR, XRD, TEM, ICP-MS and isotope analyses. The characterization helps elucidating how the carbonaceous polymorphs formed by transient heating and transient high pressure of atmospheric aerosols. Under TEM the vesicular, dense, vitrous char show high structural organization with a dense pattern of nano-sized graphitized domains, metals and mineral inclusions. The coupled Raman-ESEM has allowed identifying a complex pattern at micro scales of ordered "D" peak at 1320-1350 cm-1 and the graphitic, ordered peak at 1576-1590 cm-1, in association to amorphous and poorly graphitic ordered carbon. The later occurs within plant cells that have been extracted from the dense vitrous char by performing controlled combustion under nitrogen up to 1000°C. In contrast, the brittle, vesicular vitrous char and the polymers encountered at the rear of the pulverised airburst debris reveal to be formed of agglutinated micro spherules of amorphous carbon with rare crystallized carbon nano-domains and scattered mineral inclusions. They completely vaporised at 300°C under stepped-heating without leaving extractable residues. The link established between the structure of these exceptional carbon polymorphs and their forming processes provide diagnostic keys for interpreting vitrous carbon in ancient charcoal assemblage. The hardest ones offer reliable impact markers with their distinctive nanostructure produced by the transient high pressure and heating of carbonaceous aerosols by cosmic airbursts. In contrast, the weakly graphitised ones with distinctive plant structures would possibly express moderate effects of the airburst shock wave on vegetation at the ground. Thus micro-structural characterization of charcoal in archaeological assemblages would help tracing possible exploitation of blasted wood forest and related fossil fuel produced by ancient cosmic airbursts.

Internally Wrenching Nut

NASA Technical Reports Server (NTRS)

Cortes, R. G.

1986-01-01

Less space needed for installation and removal. Nut for use with short bolts torqued with allen wrench. In contrast with standard hexagonal nuts, new nut requires no external wrench clearance on installation surface. Nut has many uses in assemblies where space is limited, especially in automotive and aircraft industries.

Quick application/release nut with engagement indicator

NASA Technical Reports Server (NTRS)

Wright, Jay M. (Inventor)

1992-01-01

A composite nut is shown which permits a fastener to be inserted or removed from either side with an indicator of fastener engagement. The nut has a plurality of segments, preferably at least three segments, which are internally threaded, spring loaded apart by an internal spring, and has detents on opposite sides which force the nut segments into operative engagements with a threaded member when pushed in and release the segments for quick insertion or removal of the nut when moved out. When the nut is installed, end pressure on one of the detents presses the nut segments into operative engagement with a threaded member where continued rotation locks the structure together with the detents depressed to indicate positive locking engagement of the nut. On removal, counterclockwise rotation of the nut relieves the endwise pressure on the detents, permitting internal springs to force the detents outward and allowing the nut segments to move outward and separate to permit quick removal of the fastener.

Production and analysis of recombinant tree nut allergens.

PubMed

Willison, Leanna N; Sathe, Shridhar K; Roux, Kenneth H

2014-03-01

Allergic reactions to tree nuts are a growing global concern as the number of affected individuals continues to rise. Unlike some food allergies, tree nuts can cause severe reactions that persist throughout life. The tree nuts discussed in this review include those most commonly responsible for allergic reactions: cashew, almond, hazelnut, walnut, pecan, Brazil nut, pistachio, and chestnut. The native allergenic proteins derived from tree nuts are frequently difficult to isolate and purify and may not be adequately represented in aqueous nut protein extracts. Consequently, defined recombinant allergens have become useful reagents in a variety of immunoassays aimed at the diagnosis of tree nut allergy, assessing cross-reactivity between various nuts and other seeds, mapping of IgE binding epitopes, and analyzing the effects of the food matrix, food processing, and gastric digestion on allergenicity. This review describes the approaches that can be used for the production of recombinant tree nut allergens and addresses key issues associated with their production and downstream applications. Copyright © 2013 Elsevier Inc. All rights reserved.

Microwave-assisted pyrolysis of Mississippi coal: A comparative study with conventional pyrolysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abdelsayed, Victor; Shekhawat, Dushyant; Smith, Mark W.

Pyrolysis conditions greatly affect the structure-reactivity relationship of char during coal gasification. Here, this work investigated the effect of temperature and microwave heating on the structural properties of the chars generated during pyrolysis, as well as gaseous and tar products. Results showed that microwave pyrolysis of Mississippi coal produced more gaseous products and less tars compared to conventional pyrolysis. Higher CO/CO 2 ratio (>1) was observed under microwave pyrolysis compared to conventional pyrolysis (CO/CO2 < 1), which may be explained by a greater extent of gasification between solid carbon and the CO 2 formed during microwave pyrolysis. Additionally, in microwavemore » pyrolysis, the oil tars generated exhibited lower concentrations of polar oxygenates, while the wax tars showed higher concentrations of non-polar alkanes, as observed from the intensity of CH vibrations in FTIR. The product compositions and FTIR analysis of the tars (oils and waxes) suggest that the microwave interacted preferentially with these polar species, which have relatively higher dielectric properties compared to alkanes. The structure–reactivity relationship of the chars produced was also investigated using a variety of characterization tools such as XRD, BET, SEM, EDS, and FTIR. Finally, the char reactivity towards combustion suggested that microwave-produced chars have a higher thermal stability, likely due to lower O/C ratios, and could be utilized in the metallurgical industry.« less

Microwave-assisted pyrolysis of Mississippi coal: A comparative study with conventional pyrolysis

DOE PAGES

Abdelsayed, Victor; Shekhawat, Dushyant; Smith, Mark W.; ...

2018-01-13

Pyrolysis conditions greatly affect the structure-reactivity relationship of char during coal gasification. Here, this work investigated the effect of temperature and microwave heating on the structural properties of the chars generated during pyrolysis, as well as gaseous and tar products. Results showed that microwave pyrolysis of Mississippi coal produced more gaseous products and less tars compared to conventional pyrolysis. Higher CO/CO 2 ratio (>1) was observed under microwave pyrolysis compared to conventional pyrolysis (CO/CO2 < 1), which may be explained by a greater extent of gasification between solid carbon and the CO 2 formed during microwave pyrolysis. Additionally, in microwavemore » pyrolysis, the oil tars generated exhibited lower concentrations of polar oxygenates, while the wax tars showed higher concentrations of non-polar alkanes, as observed from the intensity of CH vibrations in FTIR. The product compositions and FTIR analysis of the tars (oils and waxes) suggest that the microwave interacted preferentially with these polar species, which have relatively higher dielectric properties compared to alkanes. The structure–reactivity relationship of the chars produced was also investigated using a variety of characterization tools such as XRD, BET, SEM, EDS, and FTIR. Finally, the char reactivity towards combustion suggested that microwave-produced chars have a higher thermal stability, likely due to lower O/C ratios, and could be utilized in the metallurgical industry.« less

Biochar Treatment Resulted in a Combined Effect on Soybean Growth Promotion and a Shift in Plant Growth Promoting Rhizobacteria

PubMed Central

Egamberdieva, Dilfuza; Wirth, Stephan; Behrendt, Undine; Abd_Allah, Elsayed F.; Berg, Gabriele

2016-01-01

The application of biochar to soil is considered to have the potential for long-term soil carbon sequestration, as well as for improving plant growth and suppressing soil pathogens. In our study we evaluated the effect of biochar on the plant growth of soybeans, as well as on the community composition of root-associated bacteria with plant growth promoting traits. Two types of biochar, namely, maize biochar (MBC), wood biochar (WBC), and hydrochar (HTC) were used for pot experiments to monitor plant growth. Soybean plants grown in soil amended with HTC char (2%) showed the best performance and were collected for isolation and further characterization of root-associated bacteria for multiple plant growth promoting traits. Only HTC char amendment resulted in a statistically significant increase in the root and shoot dry weight of soybeans. Interestingly, rhizosphere isolates from HTC char amended soil showed higher diversity than the rhizosphere isolates from the control soil. In addition, a higher proportion of isolates from HTC char amended soil compared with control soil was found to express plant growth promoting properties and showed antagonistic activity against one or more phytopathogenic fungi. Our study provided evidence that improved plant growth by biochar incorporation into soil results from the combination of a direct effect that is dependent on the type of char and a microbiome shift in root-associated beneficial bacteria. PMID:26941730

Systematic review on cashew nut allergy.

PubMed

van der Valk, J P M; Dubois, A E J; Gerth van Wijk, R; Wichers, H J; de Jong, N W

2014-06-01

Recent studies on cashew nut allergy suggest that the prevalence of cashew nut allergy is increasing. Cashew nut consumption by allergic patients can cause severe reactions, including anaphylaxis. This review summarizes current knowledge on cashew nut allergy to facilitate timely clinical recognition and to promote awareness of this emerging food allergy amongst clinicians. The goal of this study is to present a systematic review focused on the clinical aspects of allergy to cashew nut including the characteristics of cashew nut, the prevalence, allergenic components, cross-reactivity, diagnosis and management of cashew nut allergy. The literature search yielded 255 articles of which 40 met our selection criteria and were considered to be relevant for this review. The 40 articles included one prospective study, six retrospective studies and seven case reports. The remaining 26 papers were not directly related to cashew nut allergy. The literature suggests that the prevalence of cashew nut allergy is increasing, although the level of evidence for this is low. A minimal amount of cashew nut allergen may cause a severe allergic reaction, suggesting high potency comparable with other tree nuts and peanuts. Cashew allergy is clearly an underestimated important healthcare problem, especially in children. © 2014 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Factors affecting cashew processing by wild bearded capuchin monkeys (Sapajus libidinosus, Kerr 1792).

PubMed

Visalberghi, Elisabetta; Albani, Alessandro; Ventricelli, Marialba; Izar, Patricia; Schino, Gabriele; Fragazsy, Dorothy

2016-08-01

Cashew nuts are very nutritious but so well defended by caustic chemicals that very few species eat them. We investigated how wild bearded capuchin monkeys (Sapajus libidinosus) living at Fazenda Boa Vista (FBV; Piauí, Brazil) process cashew nuts (Anacardium spp.) to avoid the caustic chemicals contained in the seed mesocarp. We recorded the behavior of 23 individuals toward fresh (N = 1282) and dry (N = 477) cashew nuts. Adult capuchins used different sets of behaviors to process nuts: rubbing for fresh nuts and tool use for dry nuts. Moreover, adults succeed to open dry nuts both by using teeth and tools. Age and body mass significantly affected success. Signs of discomfort (e.g., chemical burns, drooling) were rare. Young capuchins do not frequently closely observe adults processing cashew nuts, nor eat bits of nut processed by others. Thus, observing the behavior of skillful group members does not seem important for learning how to process cashew nuts, although being together with group members eating cashews is likely to facilitate interest toward nuts and their inclusion into the diet. These findings differ from those obtained when capuchins crack palm nuts, where observations of others cracking nuts and encounters with the artifacts of cracking produced by others are common and support young individuals' persistent practice at cracking. Cashew nut processing by capuchins in FBV appears to differ from that observed in a conspecific population living 320 km apart, where capuchins use tools to open both fresh and dry nuts. Moreover, in the latter population, chemical burns due to cashew caustic compounds appear to be common. The sources of these differences across populations deserve investigation, especially given that social influences on young monkeys learning to open cashew nuts at FBV seem to be nonspecific. Am. J. Primatol. 78:799-815, 2016. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

What happens with the nitrogen in sewage sludge once this material is pyrolyzed?

NASA Astrophysics Data System (ADS)

Paneque, Marina; María De la Rosa, José; Kern, Jürgen; Knicker, Heike

2017-04-01

The transformation of sewage sludge (SS) into char by pyrolysis achieves sludge hygienization, a necessary step prior to a possible application on agricultural soils. Former studies indicated that during this process part of the organic nitrogen (No) of this material is incorporated into the aromatic network of the charred product and forms the so called black N (BN). De la Rosa and Knicker (2011) showed further that at least some of the BN is bioavailable. However, neither the pathways of BN formation nor its chemical structure is well understood. Therefore, we studied the production of inorganic N (Ni) and the forms of No after subjecting two types of SS to hydrothermal carbonization (HTC) and dry pyrolysis (Dry-Py). The samples were collected at two different stages of the wastewater treatment (hereafter A_SS and T_SS) at the Experimental Wastewater Treatment plant CENTA, located in Carrion de los Céspedes (Southern Spain). Four chars were produced by HTC at 200°C and 260°C, and with residence times of 30 min and 3 hours. Dry pyrolysis char was obtained after heating at 600°C for 1 hour. The organic N forms were revealed by solid-state 15N nuclear magnetic resonance (NMR) spectroscopy. All pyrolysis conditions resulted in a decrease of the amount of total N (Nt). Whereas HTC preserved between 83-59% of original N, only 2% were recovered in the char after Dry-Py. With respect to Ni, the amounts of ammonium and nitrite increased between 2 and 4 times compared to the non-treated SS after HTC. After Dry-Py no Ni was detected in the solid residue. The solid-state 15N NMR spectra of the non-treated SS are dominated by the signals assignable to amide-N. With increasing temperature and residence time applied during HTC, a shift of the signal intensity toward the region of pyrrole-N was evidenced. The largest contribution of pyrrole-N was identified in the sample obtained after heating at 260°C for 3h although the 15N-intensity in the chemical shift region of amide/carbazole N dominated the spectrum. In contrast, Dry-Py resulted in a dominance of pyrrole-N. In conclusion, our study demonstrated the impact of the pyrolysis conditions on the quantity and quality of N-forms in chars of SS. Considering the N fertilization potential, HTC chars may be more suitable than chars produced by Dry-Py if fast fertilization is needed due to the presence of Ni. On the other hand, the binding of N in heterocyclic structures retards its bioavailability. Thus Dry-Py chars will be a better choise, if slow N-release is wanted. However, deeper and specific researchers are necessary to confirm this hypothesis. De la Rosa JM, Knicker H (2011) Bioavailability of N released from N-rich pyrogenic organic matter: An incubation study. Soil Biology and Biogeochemistry 43: 2368-2373

40 CFR 454.10 - Applicability; description of the manufacture of char and charcoal briquets subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 30 2014-07-01 2014-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) GUM AND WOOD CHEMICALS...

EVALUATION OF TRADITIONAL CHARCOALS AND GASIFIER BIOCHARS AS SUSTAINABLE LOW-COST ADSORBENTS FOR WATER TREATMENT SERVING DEVELOPING COMMUNITIES

EPA Science Inventory

This research will break new ground in elucidating connections between principal char manufacture variables and the development of enhanced sorption characteristics in the char product. These variables include feedstock identity (biomass precursor) and form (i.e., whole log...

40 CFR 454.10 - Applicability; description of the manufacture of char and charcoal briquets subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 31 2012-07-01 2012-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) GUM AND WOOD CHEMICALS...

40 CFR 454.10 - Applicability; description of the manufacture of char and charcoal briquets subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 31 2013-07-01 2013-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS (CONTINUED) GUM AND WOOD CHEMICALS...

40 CFR 454.10 - Applicability; description of the manufacture of char and charcoal briquets subcategory.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GUM AND WOOD CHEMICALS...

MOLECULAR TRACERS FOR SMOKE FROM CHARRING/BURNING OF CHITIN BIOPOLYMER. (R823990)

EPA Science Inventory

Abstract

Monosaccharide derivatives from the breakdown of cellulose are the major organic components of smoke particles emitted to the atmosphere from biomass burning. In urban areas a related biopolymer, chitin, may contribute markers to smoke from grilling/charring o...

Comparison of biochar formation from various agricultural by-products using FTIR spectroscopy

USDA-ARS?s Scientific Manuscript database

Biochar is charred material produced by the pyrolysis of organic biomass. In this work, Fourier transform infrared (FTIR) spectra of different agricultural by-products feedstock and their derived biochars were collected to explore the potential of FTIR technique as a simple and rapid method for char...

Chemical characterization of chars developed from thermochemical treatment of Kentucky bluegrass seed screenings

USDA-ARS?s Scientific Manuscript database

Char produced from the gasification of post-seed harvest Kentucky bluegrass residues could be recycled to a cropping system as a soil amendment if chemical characterization determined that the gasification process had not produced or concentrated deleterious chemical or physical factors that might h...

Kim Magrini | NREL

Science.gov Websites

Developing char-based soil amendments Soil carbon and char analysis via molecular beam mass spectrometry depth profiling, Fourier transform infrared [FTIR]) Rapid soil carbon analysis using analytical DRIFTS, 13C NMR, and py-MBMS to Characterize the Effects of Soil Science Oxidation Assays on Soil Organic

USE OF BONE CHAR FOR THE REMOVAL OF ARSENIC AND URANIUM FROM GROUNDWATER ATTHE PINE RIDGE RESERVATION

EPA Science Inventory

Using bench scale U removal capacity data with bone char, a preliminary point-of-use filter was developed using theoretical calculations. The design specifications were completed for the filter, and the manufacturing of the preliminary filter is currently underway. Through ...

40 CFR 454.10 - Applicability; description of the manufacture of char and charcoal briquets subcategory.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Applicability; description of the manufacture of char and charcoal briquets subcategory. 454.10 Section 454.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS GUM AND WOOD CHEMICALS...

21 CFR 164.110 - Mixed nuts.

Code of Federal Regulations, 2011 CFR

2011-04-01

... to in paragraph (a) of this section are: (1) Almonds, black walnuts, Brazil nuts, cashews, English... 21 Food and Drugs 2 2011-04-01 2011-04-01 false Mixed nuts. 164.110 Section 164.110 Food and Drugs... CONSUMPTION TREE NUT AND PEANUT PRODUCTS Requirements for Specific Standardized Tree Nut and Peanut Products...

21 CFR 164.110 - Mixed nuts.

Code of Federal Regulations, 2012 CFR

2012-04-01

... to in paragraph (a) of this section are: (1) Almonds, black walnuts, Brazil nuts, cashews, English... 21 Food and Drugs 2 2012-04-01 2012-04-01 false Mixed nuts. 164.110 Section 164.110 Food and Drugs... CONSUMPTION TREE NUT AND PEANUT PRODUCTS Requirements for Specific Standardized Tree Nut and Peanut Products...

21 CFR 164.110 - Mixed nuts.

Code of Federal Regulations, 2014 CFR

2014-04-01

... to in paragraph (a) of this section are: (1) Almonds, black walnuts, Brazil nuts, cashews, English... 21 Food and Drugs 2 2014-04-01 2014-04-01 false Mixed nuts. 164.110 Section 164.110 Food and Drugs... CONSUMPTION TREE NUT AND PEANUT PRODUCTS Requirements for Specific Standardized Tree Nut and Peanut Products...

21 CFR 164.110 - Mixed nuts.

Code of Federal Regulations, 2013 CFR

2013-04-01

... to in paragraph (a) of this section are: (1) Almonds, black walnuts, Brazil nuts, cashews, English... 21 Food and Drugs 2 2013-04-01 2013-04-01 false Mixed nuts. 164.110 Section 164.110 Food and Drugs... CONSUMPTION TREE NUT AND PEANUT PRODUCTS Requirements for Specific Standardized Tree Nut and Peanut Products...

Reversible Nut With Engagement Indication

NASA Technical Reports Server (NTRS)

Wright, Jay M.

1995-01-01

Document describes nut allowing fastener inserted or removed from either side by simply sliding fastener in or out. Detents on each face of nut, when pushed in, ensure positive engagement of threads. Followed by conventional clockwise turning to lock and counterclockwise turning to unlock nut. Detents, when viewed, show whether nut in positive lock.

Oecophylla longinoda (Hymenoptera: Formicidae) Lead to Increased Cashew Kernel Size and Kernel Quality.

PubMed

Anato, F M; Sinzogan, A A C; Offenberg, J; Adandonon, A; Wargui, R B; Deguenon, J M; Ayelo, P M; Vayssières, J-F; Kossou, D K

2017-06-01

Weaver ants, Oecophylla spp., are known to positively affect cashew, Anacardium occidentale L., raw nut yield, but their effects on the kernels have not been reported. We compared nut size and the proportion of marketable kernels between raw nuts collected from trees with and without ants. Raw nuts collected from trees with weaver ants were 2.9% larger than nuts from control trees (i.e., without weaver ants), leading to 14% higher proportion of marketable kernels. On trees with ants, the kernel: raw nut ratio from nuts damaged by formic acid was 4.8% lower compared with nondamaged nuts from the same trees. Weaver ants provided three benefits to cashew production by increasing yields, yielding larger nuts, and by producing greater proportions of marketable kernel mass. © The Authors 2017. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Mediterranean nuts: origins, ancient medicinal benefits and symbolism.

PubMed

Casas-Agustench, Patricia; Salas-Huetos, Albert; Salas-Salvadó, Jordi

2011-12-01

To consider historical aspects of nuts in relation to origin and distribution, attributed medicinal benefits, symbolism, legends and superstitions. Review of historical aspects of nuts. Mediterranean region. The varieties reviewed include almonds, walnuts, hazelnuts, pine nuts and pistachios. Like other foods, nuts have a wide variety of cultural connections to the areas where they grow and to the people who live there or eat them. History, symbolism and legends reveal the ancient tradition of nuts and how they are related to the lives of our ancestors. Archaeological excavations in eastern Turkey have uncovered the existence of a non-migratory society whose economy centred on harvesting nuts. This shows that nuts have been a staple in the human diet since the beginnings of history. Moreover, since ancient times nuts have been used for their medicinal properties. They also play a role in many old legends and traditions.

Health Benefits of Nut Consumption

PubMed Central

Ros, Emilio

2010-01-01

Nuts (tree nuts and peanuts) are nutrient dense foods with complex matrices rich in unsaturated fatty and other bioactive compounds: high-quality vegetable protein, fiber, minerals, tocopherols, phytosterols, and phenolic compounds. By virtue of their unique composition, nuts are likely to beneficially impact health outcomes. Epidemiologic studies have associated nut consumption with a reduced incidence of coronary heart disease and gallstones in both genders and diabetes in women. Limited evidence also suggests beneficial effects on hypertension, cancer, and inflammation. Interventional studies consistently show that nut intake has a cholesterol-lowering effect, even in the context of healthy diets, and there is emerging evidence of beneficial effects on oxidative stress, inflammation, and vascular reactivity. Blood pressure, visceral adiposity and the metabolic syndrome also appear to be positively influenced by nut consumption. Thus it is clear that nuts have a beneficial impact on many cardiovascular risk factors. Contrary to expectations, epidemiologic studies and clinical trials suggest that regular nut consumption is unlikely to contribute to obesity and may even help in weight loss. Safety concerns are limited to the infrequent occurrence of nut allergy in children. In conclusion, nuts are nutrient rich foods with wide-ranging cardiovascular and metabolic benefits, which can be readily incorporated into healthy diets. PMID:22254047

[Epidemiological investigation of chewing fresh or dried betel nut and oral mucosal disease].

PubMed

Yongxiu, Du; Dongye, Sun; Xinchun, Jian; Qiuhua, Mao; Yanan, Cheng; Pu, Xu

2016-08-01

This study was conducted to investigate the effect of chewing fresh or dried betel nut on the inci-dence and canceration of oral mucosa disease in Haikou City in Hainan Province. Through a survey questionnaire, clinical examination, and regular follow-up, we collected clinical data from 1 722 cases and divided them into two groups, among which 704 of the afflicted people chew dried betel nut, whereas the other 1 018 chew fresh betel nut. The data were 
statistically analyzed using different variables which included age, number, time of onset of the disease, and the cancerous condition associated with common oral mucosa disease, including oral submucous fibrosis (OSF), oral leukoplakia (OLK), and oral Lichen planus (OLP). 1) The study found no significant difference in the prevalence of oral mucosa diseases between the dried betel nut group (n=704) and fresh betel nut group (n=1 018) among the 1 722 cases (P>0.05), but the peak age of oral mucosal disease was more advanced in the dried betel nut group (P<0.01). 2) The incidence within 5 years of OSF, OLK, OLP, and oral mucosa diseases in the dried betel nut group was significantly higher than that in the fresh betel nut group (P<0.01). 3) The incidence of cancer for oral mucosa disease in patients included in the dried betel nut group was significantly higher than that in the fresh betel nut group (P<0.01). Chewing dried betel nut is more pathogenic and carcinogenic than chewing fresh betel nut. The extremely harmful components of the dried betel nut synergistically play a vital role in the occurrence and carcinogenesis of oral mucosal diseases.

Role of an RNase III Binding Site in Transcription Termination at λ nutL by HK022 Nun Protein

PubMed Central

Washburn, Robert S.; Court, Donald L.; Gottesman, Max E.

2006-01-01

The phage HK022 Nun protein excludes phage λ by binding nascent λ pL and pR transcripts at nutL and nutR, respectively, and inducing transcription termination just downstream of these sites. Termination is more efficient at nutL than at nutR. One difference between nutL and nutR is the presence of RNase III processing sites (rIII) located immediately promoter distal to λ nutL. We found that deletion of rIII dramatically reduced Nun transcription arrest in vitro but had little effect on termination in vivo. However, consistent with the in vitro results, overexpression of a transcript carrying nutL and rIII efficiently titrated Nun, allowing λ to grow on a strain that expressed Nun, whereas a transcript carrying only nutL or nutL-rIII with nucleotides 97 to 141 deleted was ineffective. Rnc70, an RNase III mutant that binds but does not cleave rIII, also prevented Nun-mediated λ exclusion. We propose that rIII enhances the on-rate of Nun at nutL, stimulating Nun-mediated arrest in vitro. We have shown that a specific element in rIII, i.e., box C (G89GUGUGUG), strongly enhances arrest on rIII+ templates. Nun-rIII interactions do not stimulate Nun termination in vivo, presumably because formation of the Nun-nutL complex is normally not rate-limiting in the cell. In contrast to Nun, N is not occluded by Rnc70 and is not efficiently titrated by a nutL-rIII transcript. PMID:16980485

Machine recognition of navel orange worm damage in x-ray images of pistachio nuts

NASA Astrophysics Data System (ADS)

Keagy, Pamela M.; Parvin, Bahram; Schatzki, Thomas F.

1995-01-01

Insect infestation increases the probability of aflatoxin contamination in pistachio nuts. A non- destructive test is currently not available to determine the insect content of pistachio nuts. This paper uses film X-ray images of various types of pistachio nuts to assess the possibility of machine recognition of insect infested nuts. Histogram parameters of four derived images are used in discriminant functions to select insect infested nuts from specific processing streams.

Effect of tiger nut-derived products in gluten-free batter and bread.

PubMed

Aguilar, Núria; Albanell, Elena; Miñarro, Begoña; Guamis, Buenaventura; Capellas, Marta

2015-07-01

Tiger nut is a tuber used to produce tiger nut milk that yields a high quantity of solid waste, which can be dried and used as fiber source. The objective of this paper was to evaluate the quality of gluten-free bread formulated with different tiger nut-derived products in order to substitute soya flour (which is an allergen ingredient) and, at the same time, increase the use of tiger nut-derived products. Four gluten-free formulations based on corn starch and containing tiger nut milk, tiger nut milk by-product, tiger nut flour, or soya flour (as reference formulation) were studied. Tiger nut milk increased G' of gluten-free batter and rendered breads with the softest crumb (502.46 g ± 102.05), the highest loaf-specific volume (3.35 cm(3)/g ± 0.25), and it was mostly preferred by consumers (61.02%). Breads elaborated with tiger nut flour had similar characteristics than soya flour breads (except in color and crumb structure). The addition of tiger nut milk by-product resulted in a hard (1047.64 g ± 145.74) and dark (L(*)  = 70.02 ± 3.38) crumb bread, which was the least preferred by consumers. Results showed that tiger nut is a promising ingredient to formulate gluten-free baked products. © The Author(s) 2014.

Determination of Trace Elements in Edible Nuts in the Beijing Market by ICP-M.

PubMed

Yin, Liang Liang; Tian, Qing; Shao, Xian Zhang; Kong, Xiang Yin; Ji, Yan Qin

2015-06-01

Nuts have received increased attention from the public in recent years as important sources of some essential elements, and information on the levels of elements in edible nuts is useful to consumers. Determination of the elemental distributions in nuts is not only necessary in evaluating the total dietary intake of the essential elements, but also useful in detecting heavy metal contamination in food. The aim of this study was to determine the mineral contents in edible nuts, and to assess the food safety of nuts in the Beijing market. Levels of Li, Cr, Mn, Co, Cu, Zn, As, Se, Rb, Sr, Mo, Cd, Cs, Ba, Pb, Th, and U in 11 types of edible nuts and seeds (macadamia nuts, lotus nuts, pistachios, sunflower seeds, pine nuts, almonds, walnuts, chestnuts, hazelnuts, cashews, and ginkgo nuts) as well as raisins were determined by inductively coupled plasma mass spectrometry (ICP-MS). The accuracy of the method was validated using standard reference materials GBW10014 (cabbage) and GBW10016 (tea). Our results provide useful information for evaluating the levels of trace elements in edible nuts in the Beijing market, will be helpful for improving food safety, and will aid in better protecting consumer interests. Copyright © 2015 The Editorial Board of Biomedical and Environmental Sciences. Published by China CDC. All rights reserved.

Wild capuchin monkeys adjust stone tools according to changing nut properties.

PubMed

Luncz, Lydia V; Falótico, Tiago; Pascual-Garrido, Alejandra; Corat, Clara; Mosley, Hannah; Haslam, Michael

2016-09-14

Animals foraging in their natural environments need to be proficient at recognizing and responding to changes in food targets that affect accessibility or pose a risk. Wild bearded capuchin monkeys (Sapajus libidinosus) use stone tools to access a variety of nut species, including otherwise inaccessible foods. This study tests whether wild capuchins from Serra da Capivara National Park in Brazil adjust their tool selection when processing cashew (Anacardium spp.) nuts. During the ripening process of cashew nuts, the amount of caustic defensive substance in the nut mesocarp decreases. We conducted field experiments to test whether capuchins adapt their stone hammer selection to changing properties of the target nut, using stones of different weights and two maturation stages of cashew nuts. The results show that although fresh nuts are easier to crack, capuchin monkeys used larger stone tools to open them, which may help the monkeys avoid contact with the caustic hazard in fresh nuts. We demonstrate that capuchin monkeys are actively able to distinguish between the maturation stages within one nut species, and to adapt their foraging behaviour accordingly.

Wild capuchin monkeys adjust stone tools according to changing nut properties

PubMed Central

Luncz, Lydia V.; Falótico, Tiago; Pascual-Garrido, Alejandra; Corat, Clara; Mosley, Hannah; Haslam, Michael

2016-01-01

Animals foraging in their natural environments need to be proficient at recognizing and responding to changes in food targets that affect accessibility or pose a risk. Wild bearded capuchin monkeys (Sapajus libidinosus) use stone tools to access a variety of nut species, including otherwise inaccessible foods. This study tests whether wild capuchins from Serra da Capivara National Park in Brazil adjust their tool selection when processing cashew (Anacardium spp.) nuts. During the ripening process of cashew nuts, the amount of caustic defensive substance in the nut mesocarp decreases. We conducted field experiments to test whether capuchins adapt their stone hammer selection to changing properties of the target nut, using stones of different weights and two maturation stages of cashew nuts. The results show that although fresh nuts are easier to crack, capuchin monkeys used larger stone tools to open them, which may help the monkeys avoid contact with the caustic hazard in fresh nuts. We demonstrate that capuchin monkeys are actively able to distinguish between the maturation stages within one nut species, and to adapt their foraging behaviour accordingly. PMID:27624672

Study of CNSL Processing Plants Located in Cuddalore District of Tamil Nadu, India

NASA Astrophysics Data System (ADS)

Bhaskaran, E.

2017-06-01

Basic chemicals and their related products like petrochemicals, fertilisers, paints, varnishes, glass, perfumes, toiletries, pharmaceuticals, etc. form a very significant part of the Indian economy and account for about 3% of India's GDP. Among the most diversified industrial sectors, it covers an array of more than 70,000 commercial products. The chemicals sector accounts for about 14% in overall index of industrial production, 11% of total exports and about 7.2% of total imports. The total Foreign Direct Investment in Chemicals (excluding fertilizers) was US 7252 million from April 2011 to March 2012. For inclusive growth and sustainable development most of the Chemical manufacturers should adopt the Cluster Development Approach. The objective is to Study the Occupational Hazards in Cashew Nut Shell Liquid (CNSL) Oil Processing Industries in Panruti Block of Cuddalore District. The methodology adopted is collection of primary processing data during November 2012 from 14 CNSL Processing Industries in Panruti Block of Cuddalore District. Majority of Industries has not processed the CNSL oil as per standards and there is much scope for occupational hazards. In two processes the CNSL oil is let out in the tank constructed equal to ground height where there is possibility of workers getting trapped inside the high temperature CNSL oil. The electric motor is also placed in the ground so that there is possibility of current passing in the ground which leads to occupational hazards for the workers. To conclude, Cashew Shell Oil Processing Industries in Panruti Block of Cuddalore District needs is re-engineering in design and operation starting from Cashew Shell storage, extraction of shell oil from expeller, processing and packaging of CNSL in barrels for better safety from occupational hazards and Cyclones. Moreover for sustainable development, they should adopt cluster development approach, so that infrastructure interrelationships, technology interrelationships, procurement interrelationships, production interrelationships and marketing interrelationships will take place among CNSL manufacturers to decrease cost, increase quality, productivity and efficiency to compete in the world market.

Porphyrin synthesized from cashew nut shell liquid as part of a novel superparamagnetic fluorescence nanosystem

NASA Astrophysics Data System (ADS)

Clemente, C. S.; Ribeiro, V. G. P.; Sousa, J. E. A.; Maia, F. J. N.; Barreto, A. C. H.; Andrade, N. F.; Denardin, J. C.; Mele, G.; Carbone, L.; Mazzetto, S. E.; Fechine, P. B. A.

2013-06-01

Magnetic Fe3O4 nanoparticles with average size approximately 11 nm were first oleic acid coated to interact with the meso-porphyrin derivative from CNSL. This procedure produced a novel superparamagnetic fluorescent nanosystem (SFN) linked by van der Waals interactions. This system was characterized by transmission electron microscope, infrared spectroscopy, thermogravimetric analysis, magnetic measurements, UV-Vis absorption, and fluorescence emission measurements. These results showed that SFN has good thermal stability, excellent magnetization, and nanosized dimensions ( 13 nm). It exhibited emission peaks at 668 and 725 nm with a maximum emission at 467 nm of excitation wavelength. The type of interaction between porphyrin and magnetic nanoparticles allowed to obtain a material with interesting optical properties which might be used as an imaging agent for contrast in cells as well as heterogeneous photocatalysis.

Flexural analysis of palm fiber reinforced hybrid polymer matrix composite

NASA Astrophysics Data System (ADS)

Venkatachalam, G.; Gautham Shankar, A.; Raghav, Dasarath; Santhosh Kiran, R.; Mahesh, Bhargav; Kumar, Krishna

2015-07-01

Uncertainty in availability of fossil fuels in the future and global warming increased the need for more environment friendly materials. In this work, an attempt is made to fabricate a hybrid polymer matrix composite. The blend is a mixture of General Purpose Resin and Cashew Nut Shell Liquid, a natural resin extracted from cashew plant. Palm fiber, which has high strength, is used as reinforcement material. The fiber is treated with alkali (NaOH) solution to increase its strength and adhesiveness. Parametric study of flexure strength is carried out by varying alkali concentration, duration of alkali treatment and fiber volume. Taguchi L9 Orthogonal array is followed in the design of experiments procedure for simplification. With the help of ANOVA technique, regression equations are obtained which gives the level of influence of each parameter on the flexure strength of the composite.