o-x-b double mode: Topics by Science.gov

Sample records for o-x-b double mode

Searching for O-X-B mode-conversion window with monitoring of stray microwave radiation in LHD

NASA Astrophysics Data System (ADS)

Igami, H.; Kubo, S.; Laqua, H. P.; Nagasaki, K.; Inagaki, S.; Notake, T.; Shimozuma, T.; Yoshimura, Y.; Mutoh, T.; LHD Experimental Group

2006-10-01

In the Large Helical Device, the stray microwave radiation is monitored by using so-called sniffer probes during electron cyclotron heating. In monitoring the stray radiation, we changed the microwave beam injection angle and search the O-X-B mode-conversion window to excite electron Bernstein waves (EBWs). When the microwave beam is injected toward the vicinity of the predicted O-X-B mode-conversion window, the electron temperature rises in the central part of overdense plasmas. In that case, the stray radiation level near the injection antenna becomes low. These results indicate that monitoring the stray radiation near the injection antenna is helpful in confirming the effectiveness of excitation of EBWs simply without precise analysis.
Kinetic simulations of X-B and O-X-B mode conversion and its deterioration at high input power

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arefiev, A. V.; Dodin, I. Y.; Kohn, A.

Spherical tokamak plasmas are typically overdense and thus inaccessible to externally-injected microwaves in the electron cyclotron range. The electrostatic electron Bernstein wave (EBW), however, provides a method to access the plasma core for heating and diagnostic purposes. Understanding the details of the coupling process to electromagnetic waves is thus important both for the interpretation of microwave diagnostic data and for assessing the feasibility of EBW heating and current drive. While the coupling is reasonably well–understood in the linear regime, nonlinear physics arising from high input power has not been previously quantified. To tackle this problem, we have performed one- andmore » two-dimensional fully kinetic particle-in-cell simulations of the two possible coupling mechanisms, namely X-B and O-X-B mode conversion. We find that the ion dynamics has a profound effect on the field structure in the nonlinear regime, as high amplitude short-scale oscillations of the longitudinal electric field are excited in the region below the high-density cut-off prior to the arrival of the EBW. We identify this effect as the instability of the X wave with respect to resonant scattering into an EBW and a lower-hybrid wave. Finally, we calculate the instability rate analytically and find this basic theory to be in reasonable agreement with our simulation results.« less
Kinetic simulations of X-B and O-X-B mode conversion and its deterioration at high input power

DOE PAGES

Arefiev, A. V.; Dodin, I. Y.; Kohn, A.; ...

2017-08-09

Spherical tokamak plasmas are typically overdense and thus inaccessible to externally-injected microwaves in the electron cyclotron range. The electrostatic electron Bernstein wave (EBW), however, provides a method to access the plasma core for heating and diagnostic purposes. Understanding the details of the coupling process to electromagnetic waves is thus important both for the interpretation of microwave diagnostic data and for assessing the feasibility of EBW heating and current drive. While the coupling is reasonably well–understood in the linear regime, nonlinear physics arising from high input power has not been previously quantified. To tackle this problem, we have performed one- andmore » two-dimensional fully kinetic particle-in-cell simulations of the two possible coupling mechanisms, namely X-B and O-X-B mode conversion. We find that the ion dynamics has a profound effect on the field structure in the nonlinear regime, as high amplitude short-scale oscillations of the longitudinal electric field are excited in the region below the high-density cut-off prior to the arrival of the EBW. We identify this effect as the instability of the X wave with respect to resonant scattering into an EBW and a lower-hybrid wave. Finally, we calculate the instability rate analytically and find this basic theory to be in reasonable agreement with our simulation results.« less
Characterization of Y1-xCaxBa2Cu4O8 (x=0.0˜ 0.1) with Double Cu-O Chains by Raman Spectra

NASA Astrophysics Data System (ADS)

Kodama, Yasuharu; Tanemura, Sakae; Ikeda, Teruki

1991-08-01

Raman spectra of Y1-xCaxBa2Cu4O8 (x=0.0, 0.02, 0.05 and 0.1) ceramic samples synthesized under high oxygen pressure were investigated. Seven clear peaks assigned to Ag modes were observed for the sample with x=0. With increasing x, the peaks at 238 cm-1, 332 cm-1, 430 cm-1 and 590 cm-1 were broadened. The origin of the broadening of the peaks at 238 cm-1 and 590 cm-1 is considered to be the destruction of the double Cu-O chains due to the substitution of Ca for Y.
Stabilized antiferroelectricity in xBiScO3-(1-x)NaNbO3 lead-free ceramics with established double hysteresis loops

NASA Astrophysics Data System (ADS)

Gao, Lisheng; Guo, Hanzheng; Zhang, Shujun; Randall, Clive A.

2018-02-01

We previously reported various solid solution systems that demonstrated the stabilized antiferroelectric (P) phases in NaNbO3 through lowering the tolerance factor. However, all those reported modifications were achieved by adding A2+B4+O3 type solid solutions. A lead-free antiferroelectric (AFE) solid solution xBiScO3-(1-x)NaNbO3 was rationalized by adopting the tolerance factor design rule. Specifically, adding BiScO3 was found to effectively stabilize the AFE phase without changing the crystal symmetry of NaNbO3. Microstructure and electron zone axis diffraction patterns from transmission electron microscopy revealed the stabilized AFE (P) phase in this solid solution. Besides, the electric-field-induced polarization with a double-hysteresis loop was observed. The present results pointed out that the strategy could also be applied while adding A3+B3+O3 type solid solutions. In addition, it expanded the compositional design that can be applied to antiferroelectric materials.
The luminosity of the double-mode Cepheid Y Carinae

NASA Technical Reports Server (NTRS)

Evans, Nancy R.

1992-01-01

IUE spectra of the double-mode Cepheid Y Carinae have been used to determine the spectral type of the binary companion. From the companion spectral type (B9.O V), the absolute magnitude of the Cepheid is found to be -2.94 mag, with an estimated uncertainty of +/-0.3. This luminosity is in good agreement with that from the period-luminosity-color relation of Feast and Walker for the fundamental mode. This agreement, together with the large magnitude difference between the B9.0 V star and the Cepheid, confirm that the Cepheid is a normal classical Cepheid with a mass much larger than that inferred from the ratio of the two periods (beat mass). The two double-mode Cepheids with independently determined luminosities (Y Car and V 367 Sct) both fall on the blue edge of the instability strip.
Crystal structures and high-temperature phase-transitions in SrNdMRuO{sub 6} (M=Zn,Co,Mg,Ni) new double perovskites studied by symmetry-mode analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Iturbe-Zabalo, E., E-mail: iturbe@ill.fr; Fisika Aplikatua II Saila, Zientzia eta Teknologia Fakultatea, UPV/EHU, P.O. Box 644, 48080 Bilbao; Igartua, J.M.

2013-02-15

Crystal structures of SrNdZnRuO{sub 6}, SrNdCoRuO{sub 6}, SrNdMgRuO{sub 6} and SrNdNiRuO{sub 6} double perovskites have been studied by X-ray, synchrotron radiation and neutron powder diffraction method, at different temperatures, and using the symmetry-mode analysis. All compounds adopt the monoclinic space group P2{sub 1}/n at room-temperature, and contain a completely ordered array of the tilted MO{sub 6} and RuO{sub 6} octahedra, whereas Sr/Nd cations are completely disordered. The analysis of the structures in terms of symmetry-adapted modes of the parent phase allows the identification of the modes responsible for the phase-transition. The high-temperature study (300-1250 K) has shown that the compoundsmore » present a temperature induced structural phase-transition: P2{sub 1}/n{yields}P4{sub 2}/n{yields}Fm3{sup Macron }m. - Graphical abstract: Representation of the dominant distortion modes of the symmetry mode decomposition of the room-temperature (P2{sub 1}/n), intermediate (P4{sub 2}/n) and cubic (Fm-3m) phase SrNdMRuO{sub 6} (M=Zn,Co,Mg,Ni), with respect to the parent phase Fm-3m. The dominant distortion modes are: in the monoclinic phase-GM{sub 4}{sup +} (blue arrow), X{sub 3}{sup +} (green arrow) and X{sub 5}{sup +} acting on A-site cations (red arrow); in the tetragonal phase-GM{sub 4}{sup +} (pink arrow), X{sub 3}{sup +} (light blue arrow) and X{sub 5}{sup +} acting on A-site cations (brown arrow). Highlights: Black-Right-Pointing-Pointer Structural study of four ruthenate double perovskites. Black-Right-Pointing-Pointer Room-temperature structural determination using symmetry-mode procedure. Black-Right-Pointing-Pointer Determination of temperature induced structural phase-transitions. Black-Right-Pointing-Pointer Symmetry adapted-mode analysis.« less
Boson mode, Medium Range Structure and Intermediate Phase (IP) in (Na2O)x(B2O3)1-x glasses

NASA Astrophysics Data System (ADS)

Vignarooban, K.; Boolchand, P.; Micoulaut, M.; Malki, M.

2012-02-01

Raman scattering of titled glasses are examined using a T64000 Dispersive system. Scattering strengths of the Boson mode (40 cm-1, 70 cm-1) and the Boroxyl ring (BR) mode (808 cm-1) are found to decrease with increasing x at the same rate in the 0 < x < 20% soda range. Apparently, the 2D character of BRs embedded in a 3D network gives rise to the Boson mode.ootnotetextM. Flores-Ruiz and G. Naumis, PRB, 2011. 83: p. 184204 The triad of modes (705, 740, 770 cm-1) near the 808 cm-1 mode are found to display a maximum in scattering strength near x = 37% (705 cm-1), 33% (740 cm-1) and 25% (770 cm-1), suggesting that these are also ring modes of Na-tripentaborate (STPB), Na-diborate (SDB) and Na-triborate (STB) super-structures. Variations in Raman scattering strengths also suggest that STB percolate near x = 20%, the stress transition, while the STPB and SDTB percolate near x = 40%, the rigidity transition. These transitions were inferred from m-DSC experiments that show an intermediate phase in the 20% < x < 40% range in dry and homogeneous glasses.
Advanced light-scattering materials: Double-textured ZnO:B films grown by LP-MOCVD

NASA Astrophysics Data System (ADS)

Addonizio, M. L.; Spadoni, A.; Antonaia, A.

2013-12-01

Double-textured ZnO:B layers with enhanced optical scattering in both short and long wavelength regions have been successfully fabricated using MOCVD technique through a three step process. Growth of double-textured structures has been induced by wet etching on polycrystalline ZnO surface. Our double-layer structure consists of a first ZnO:B layer wet etched and subsequently used as substrate for a second ZnO:B layer deposition. Polycrystalline ZnO:B layers were etched by utilizing diluted solutions of fluoridic acid (HF), chloridric acid (HCl) and phosphoric acid (H3PO4) and their effect on surface morphology modification was systematically investigated. The morphology of the second deposited ZnO layer strongly depended on the surface properties of the etched ZnO first layer. Growth of cauliflower-like texture was induced by protrusions presence on the HCl etched surface. Optimized double-layer structure shows a cauliflower-like double texture with higher RMS roughness and increased spectral haze values in both short and long wavelength regions, compared to conventional pyramidal-like single texture. Furthermore, this highly scattering structure preserves excellent optical and electrical properties.
Anomalous double-mode RR Lyrae stars in the Magellanic Clouds

NASA Astrophysics Data System (ADS)

Soszyński, I.; Smolec, R.; Dziembowski, W. A.; Udalski, A.; Szymański, M. K.; Wyrzykowski, Ł.; Ulaczyk, K.; Poleski, R.; Pietrukowicz, P.; Kozłowski, S.; Skowron, D.; Skowron, J.; Mróz, P.; Pawlak, M.

2016-12-01

We report the discovery of a new subclass of double-mode RR Lyrae stars in the Large and Small Magellanic Clouds. The sample of 22 pulsating stars has been extracted from the latest edition of the Optical Gravitational Lensing Experiment collection of RR Lyrae variables in the Magellanic System. The stars pulsating simultaneously in the fundamental (F) and first-overtone (1O) modes have distinctly different properties than regular double-mode RR Lyrae variables (RRd stars). The P1O/PF period ratios of our anomalous RRd stars are within a range of 0.725-0.738, while `classical' double-mode RR Lyrae variables have period ratios in the range of 0.742-0.748. In contrast to the typical RRd stars, in the majority of the anomalous pulsators, the F-mode amplitudes are higher than the 1O-mode amplitudes. The light curves associated with the F-mode in the anomalous RRd stars show different morphology than the light curves of, both, regular RRd stars and single-mode RRab stars. Most of the anomalous double-mode stars show long-term modulations of the amplitudes (Blazhko-like effect). Translating the period ratios into the abundance parameter, Z, we find for our stars Z ∈ (0.002, 0.005) - an order of magnitude higher values than typical for RR Lyrae stars. The mass range of the RRd stars inferred from the WI versus PF diagram is (0.55-0.75) M⊙. These parameters cannot be accounted for with single star evolution assuming a Reimers-like mass-loss. Much greater mass-loss caused by interaction with other stars is postulated. We blame the peculiar pulsation properties of our stars to the parametric resonance instability of the 1O-mode to excitation of the F- and 2O-modes as with the inferred parameters of the stars 2ω1O ≈ ωF + ω2O.
Local vibrational modes of the formic acid dimer - the strength of the double hydrogen bond

NASA Astrophysics Data System (ADS)

Kalescky, R.; Kraka, E.; Cremer, D.

2013-07-01

The 24 normal and 24 local vibrational modes of the formic acid dimer formed by two trans formic acid monomers to a ring (TT1) are analysed utilising preferentially experimental frequencies, but also CCSD(T)/CBS and ωB97X-D harmonic vibrational frequencies. The local hydrogen bond (HB) stretching frequencies are at 676 cm-1 and by this 482 and 412 cm-1 higher compared to the measured symmetric and asymmetric HB stretching frequencies at 264 and 194 cm-1. The adiabatic connection scheme between local and normal vibrational modes reveals that the lowering is due to the topology of dimer TT1, mass coupling, and avoided crossings involving the HṡṡṡOC bending modes. The HB local mode stretching force constant is related to the strength of the HB whereas the normal mode stretching force constant and frequency lead to an erroneous underestimation of the HB strength. The HB in TT1 is stabilised by electron delocalisation in the O=C-O units fostered by forming a ring via double HBs. This implies that the CO apart from the OH local stretching frequencies reflect the strength of the HB via their red or blue shifts relative to their corresponding values in trans formic acid.
Demonstration of β-(AlxGa1-x)2O3/Ga2O3 double heterostructure field effect transistors

NASA Astrophysics Data System (ADS)

Zhang, Yuewei; Joishi, Chandan; Xia, Zhanbo; Brenner, Mark; Lodha, Saurabh; Rajan, Siddharth

2018-06-01

In this work, we demonstrate modulation-doped β-(AlxGa1-x)2O3/Ga2O3 double heterostructure field effect transistors. The maximum sheet carrier density for a two-dimensional electron gas (2DEG) in a β-(AlxGa1-x)2O3/Ga2O3 heterostructure is limited by the conduction band offset and parasitic channel formation in the barrier layer. We demonstrate a double heterostructure to realize a β-(AlxGa1-x)2O3/Ga2O3/(AlxGa1-x)2O3 quantum well, where electrons can be transferred from below and above the β-Ga2O3 quantum well. The confined 2DEG charge density of 3.85 × 1012 cm-2 was estimated from the low-temperature Hall measurement, which is higher than that achievable in a single heterostructure. Hall mobilities of 1775 cm2/V.s at 40 K and 123 cm2/V.s at room temperature were measured. Modulation-doped double heterostructure field effect transistors showed a maximum drain current of IDS = 257 mA/mm, a peak transconductance (gm) of 39 mS/mm, and a pinch-off voltage of -7.0 V at room temperature. The three-terminal off-state breakdown measurement on the device with a gate-drain spacing (LGD) of 1.55 μm showed a breakdown voltage of 428 V, corresponding to an average breakdown field of 2.8 MV/cm. The breakdown measurement on the device with a scaled gate-drain spacing of 196 nm indicated an average breakdown field of 3.2 MV/cm. The demonstrated modulation-doped β-(AlxGa1-x)2O3/Ga2O3 double heterostructure field effect transistor could act as a promising candidate for high power and high frequency device applications.
Effect of crystal structure and cationic order on phonon modes across ferroelectric phase transformation in Pb(Fe{sub 0.5-x}Sc{sub x}Nb{sub 0.5})O{sub 3} bulk ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mallesham, B.; Ranjith, R., E-mail: ranjith@iith.ac.in; Viswanath, B.

Pb(Fe{sub 0.5-x}Sc{sub x}Nb{sub 0.5})O{sub 3} [(PFSN) (0 ≤ x ≤ 0.5)] multiferroic relaxors were synthesized and the temperature dependence of phonon modes across ferroelectric to paraelectric transition was studied. With varying Sc content from x = 0 to 0.25 the structure remains monoclinic and with further addition (x = 0.3 - 0.5) the structure transforms into rhombohedral symmetry. Structural refinement studies showed that the change in crystal structure from monoclinic to rhombohedral symmetry involves a volume increment of 34-36%. Associated changes in the tolerance factor (1.024 ≤ t ≤ 0.976) and bond angles were observed. Structure assisted B′-B″ cation orderingmore » was confirmed through the superlattice reflections in selected area electron diffraction (SAED) pattern of Pb(Sc{sub 0.5}Nb{sub 0.5})O{sub 3} (x = 0.5). Cation ordering is also evident from the evolution of Pb-O phonon mode in Raman spectra of compositions with rhombohedral symmetry (x ≥ 0.3). The high temperature Raman scattering studies show that the B-localized mode [F{sub 1u}, ∼250 cm{sup −1}] and BO{sub 6} octahedral rotational mode [F{sub 1g}, ∼200 cm{sup −1}], both originating from polar nano regions (PNRs) behave like coupled phonon modes in rhombohedral symmetry. However, in monoclinic symmetry they behave independently across the transition. Softening of B localized mode across the transition followed by the hardening for all compositions confirms the diffusive nature of the ferroelectric transformation. The presence of correlation between the B localized and BO{sub 6} rotational modes introduces a weak relaxor feature for systems with rhombohedral symmetry in PFSN ceramics, which was confirmed from the macroscopic dielectric studies.« less
Optically stimulated luminescence in x-ray irradiated xSnO-(25-x)SrO-75B2O3 glass

NASA Astrophysics Data System (ADS)

Nanto, H.; Nakagawa, R.; Takei, Y.; Hirasawa, K.; Miyamoto, Y.; Masai, H.; Kurobori, T.; Yanagida, T.; Fujimoto, Y.

2015-06-01

An intense optically stimulated luminescence (OSL) was observed, for the first time, in x-ray irradiated xSnO-(25-x)SrO-75B2O3 glass. It was found that the peak wavelength of OSL emission spectrum and its stimulation spectrum is about 400 nm and 600 nm, respectively. The OSL intensity is depended on the SnO contents (x=0.05-1.5) and the most intense OSL was observed in 1.0 mol% SnO doped glass. It was found that the OSL intensity is increased with increasing x-ray absorbed dose. Fairly good fading characteristics were observed in the x-ray irradiated glass, showing that this glass is useful as a candidate for OSL sensor materials for ionizing radiation monitoring.
The translational, rotational, and vibrational energy effects on the chemical reactivity of water cation H2O+(X 2B1) in the collision with deuterium molecule D2

NASA Astrophysics Data System (ADS)

Xu, Yuntao; Xiong, Bo; Chang, Yih Chung; Ng, C. Y.

2013-07-01

By employing the newly established vacuum ultraviolet (VUV) laser pulsed field ionization-photoion (PFI-PI) double quadrupole-double octopole ion guide apparatus, we have examined the translational, rotational, and vibrational energy effects on the chemical reactivity of water cation H2O+(X2B1) in the collision with deuterium molecule D2. The application of a novel electric-field pulsing scheme to the VUV laser PFI-PI ion source has enabled the preparation of a rovibrationally selected H2O+(X2B1; v_1^ + v_2^ + v_3^ +; N+Ka+Kc+) ion beam with not only high internal-state selectivity and high intensity but also high translational energy resolution. Despite the unfavorable Franck-Condon factors, we are able to prepare the excited vibrational states (v_1^ + v_2^ + v_3^ +) = (100) and (020) along with the (000) ground vibrational state, for collisional studies, where v_1^ +, v_2^ +, and v_3^ + represent the symmetric stretching, bending, and asymmetric stretching modes of H2O+(X2B1). We show that a range of rotational levels from N+Ka+Kc+ = 000 to 322, covering a rotational energy range of 0-200 cm-1 of these vibrational states, can also be generated for absolute integral cross section (σ) measurements at center-of-mass collision energies (Ecms) from thermal energies to 10.00 eV. The Ecm dependences of the σ values are consistent with the prediction of the orbiting model, indicating that translational energy significantly hinders the chemical reactivity of H2O+(X2B1). Rotational enhancements are observed at Ecm < 0.30 eV for all the three vibrational states, (000), (100), and (020). While the σ values for (100) are found to be only slightly below those for (000), the σ values for (020) are lower than those for (000) and (100) by up to 20% at Ecm ≤ 0.20 eV, indicative of vibrational inhibition at low Ecm by excitation of the (020) mode. Rationalizations are proposed for the observed rotational enhancements and the bending vibrational inhibition. Rigorous
CD22 x Siglec-G double-deficient mice have massively increased B1 cell numbers and develop systemic autoimmunity.

PubMed

Jellusova, Julia; Wellmann, Ute; Amann, Kerstin; Winkler, Thomas H; Nitschke, Lars

2010-04-01

CD22 and Siglec-G are inhibitory coreceptors for BCR-mediated signaling. Although CD22-deficient mice show increased calcium signaling in their conventional B2 cells and a quite normal B cell maturation, Siglec-G-deficient mice have increased calcium mobilization just in B1 cells and show a large expansion of the B1 cell population. Neither CD22-deficient, nor Siglec-G-deficient mice on a pure C57BL/6 or BALB/c background, respectively, develop autoimmunity. Using Siglec-G x CD22 double-deficient mice, we addressed whether Siglec-G and CD22 have redundant functions. Siglec-G x CD22 double-deficient mice show elevated calcium responses in both B1 cells and B2 cells, increased serum IgM levels and an enlarged population of B1 cells. The enlargement of B1 cell numbers is even higher than in Siglecg(-/-) mice. This expansion seems to happen at the expense of B2 cells, which are reduced in absolute cell numbers, but show an activated phenotype. Furthermore, Siglec-G x CD22 double-deficient mice show a diminished immune response to both thymus-dependent and thymus-independent type II Ags. In contrast, B cells from Siglec-G x CD22 double-deficient mice exhibit a hyperproliferative response to stimulation with several TLR ligands. Aged Siglec-G x CD22 double-deficient mice spontaneously develop anti-DNA and antinuclear autoantibodies. These resulted in a moderate form of immune complex glomerulonephritis. These results show that Siglec-G and CD22 have partly compensatory functions and together are crucial in maintaining the B cell tolerance.
Separation of O/X Polarization Modes on Oblique Ionospheric Soundings

NASA Astrophysics Data System (ADS)

Harris, T. J.; Cervera, M. A.; Pederick, L. H.; Quinn, A. D.

2017-12-01

The oblique-incidence sounder (OIS) is a well-established instrument for determining the state of the ionosphere, with several advantages over vertical-incidence sounders (VIS). However, the processing and interpretation of OIS ionograms is more complicated than that of VIS ionograms. Due to the Earth's magnetic field, the ionosphere is birefringent at radio frequencies and a VIS or OIS will typically see two distinct ionospheric returns, known as the O and X modes. The separation of these two modes on a VIS, using a polarimetric receive antenna, is a well-established technique. However, this process is more complicated on an OIS due to a variable separation in the phase difference between the two modes, as measured between the two arms of a polarimetric antenna. Using a polarimetric antenna that can be rotated and tilted, we show that this variation in phase separation within an ionogram is caused by the variation in incidence angle, with some configurations leading to greater variation in phase separation. We then develop an algorithm for separating O and X modes in oblique ionograms that can account for the variation in phase separation, and we demonstrate successful separation even in relatively difficult cases. The variation in phase separation can also be exploited to estimate the incident elevation, a technique which may be useful for other applications of HF radio.
Simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822-09

NASA Astrophysics Data System (ADS)

Hermsen, W.; Kuiper, L.; Hessels, J. W. T.; Mitra, D.; Rankin, J. M.; Stappers, B. W.; Wright, G. A. E.; Basu, R.; Szary, A.; van Leeuwen, J.

2017-04-01

We report on simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822-09 with ESA's XMM-Newton and the Westerbork Synthesis Radio Telescope, Giant Metrewave Radio Telescope and Lovell radio telescopes. PSR B1822-09 switches between a radio-bright and radio-quiet mode, and we discovered a relationship between the durations of its modes and a known underlying radio-modulation time-scale within the modes. We discovered X-ray (energies 0.2-1.4 keV) pulsations with a broad sinusoidal pulse, slightly lagging the radio main pulse in phase by 0.094 ± 0.017, with an energy-dependent pulsed fraction varying from ˜0.15 at 0.3 keV to ˜0.6 at 1 keV. No evidence is found for simultaneous X-ray and radio mode switching. The total X-ray spectrum consists of a cool component (T ˜0.96 × 106 K, hotspot radius R ˜2.0 km) and a hot component (T ˜2.2 × 106 K, R ˜100 m). The hot component can be ascribed to the pulsed emission and the cool component to the unpulsed emission. The high-energy characteristics of PSR B1822-09 resemble those of middle-aged pulsars such as PSR B0656+14, PSR B1055-52 and Geminga, including an indication for pulsed high-energy gamma-ray emission in Fermi Large Area Telescope data. Explanations for the high pulsed fraction seem to require different temperatures at the two poles of this orthogonal rotator, or magnetic anisotropic beaming effects in its strong magnetic field. In our X-ray skymap, we found a harder source at only 5.1 ± 0.5 arcsec from PSR B1822-09, which might be a pulsar wind nebula.
Simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822$-$09

DOE PAGES

Hermsen, W.; Kuiper, L.; Hessels, J. W. T.; ...

2016-12-05

Here, we report on simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822–09 with ESA's XMM–Newton and the Westerbork Synthesis Radio Telescope, Giant Metrewave Radio Telescope and Lovell radio telescopes. PSR B1822–09 switches between a radio-bright and radio-quiet mode, and we discovered a relationship between the durations of its modes and a known underlying radio-modulation time-scale within the modes. We discovered X-ray (energies 0.2–1.4 keV) pulsations with a broad sinusoidal pulse, slightly lagging the radio main pulse in phase by 0.094 ± 0.017, with an energy-dependent pulsed fraction varying from ~0.15 at 0.3 keV to ~0.6 at 1more » keV. No evidence is found for simultaneous X-ray and radio mode switching. The total X-ray spectrum consists of a cool component (T ~0.96 × 10 6 K, hotspot radius R ~2.0 km) and a hot component (T ~2.2 × 10 6 K, R ~100 m). The hot component can be ascribed to the pulsed emission and the cool component to the unpulsed emission. The high-energy characteristics of PSR B1822–09 resemble those of middle-aged pulsars such as PSR B0656+14, PSR B1055–52 and Geminga, including an indication for pulsed high-energy gamma-ray emission in Fermi Large Area Telescope data. Explanations for the high pulsed fraction seem to require different temperatures at the two poles of this orthogonal rotator, or magnetic anisotropic beaming effects in its strong magnetic field. In our X-ray skymap, we found a harder source at only 5.1 ± 0.5 arcsec from PSR B1822–09, which might be a pulsar wind nebula.« less
Simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822$-$09

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hermsen, W.; Kuiper, L.; Hessels, J. W. T.

Here, we report on simultaneous X-ray and radio observations of the radio-mode-switching pulsar PSR B1822–09 with ESA's XMM–Newton and the Westerbork Synthesis Radio Telescope, Giant Metrewave Radio Telescope and Lovell radio telescopes. PSR B1822–09 switches between a radio-bright and radio-quiet mode, and we discovered a relationship between the durations of its modes and a known underlying radio-modulation time-scale within the modes. We discovered X-ray (energies 0.2–1.4 keV) pulsations with a broad sinusoidal pulse, slightly lagging the radio main pulse in phase by 0.094 ± 0.017, with an energy-dependent pulsed fraction varying from ~0.15 at 0.3 keV to ~0.6 at 1more » keV. No evidence is found for simultaneous X-ray and radio mode switching. The total X-ray spectrum consists of a cool component (T ~0.96 × 10 6 K, hotspot radius R ~2.0 km) and a hot component (T ~2.2 × 10 6 K, R ~100 m). The hot component can be ascribed to the pulsed emission and the cool component to the unpulsed emission. The high-energy characteristics of PSR B1822–09 resemble those of middle-aged pulsars such as PSR B0656+14, PSR B1055–52 and Geminga, including an indication for pulsed high-energy gamma-ray emission in Fermi Large Area Telescope data. Explanations for the high pulsed fraction seem to require different temperatures at the two poles of this orthogonal rotator, or magnetic anisotropic beaming effects in its strong magnetic field. In our X-ray skymap, we found a harder source at only 5.1 ± 0.5 arcsec from PSR B1822–09, which might be a pulsar wind nebula.« less

Optical Emissions Enhanced by O and X Mode Ionosphere HF Pumping: Similarities and Differences

NASA Astrophysics Data System (ADS)

Sergienko, T.; Brandstrom, U.; Gustavsson, B.; Blagoveshchenskaya, N. F.

2013-12-01

Strong enhancement of the optical emissions with excitation thresholds from 1.96 eV up to 18.75 eV have been observed during experiments of ionosphere modification by high power HF radio waves since the early 1970s. Up to now all these emissions were observed only during the interaction of the O-mode HF radio wave with the ionospheric plasma. On 19 October 2012, during an EISCAT heating experiment, strong optical emissions were observed by ALIS, in first time, for X-mode ionosphere pumping. While for O-mode heating the optical emission enhancements can be explained by the ionospheric electron heating and acceleration due to the nonlinear interaction of the powerful radio wave with ionosphere, the mechanism responsible for the emission enhancements during the X-mode heating is not known. In the experiment optical emissions have been measured in three different wave-lengths simultaneously from four ALIS stations. The emission intensity ratios as well as the characteristics of the spatial distribution of the enhanced optical emissions provide important information on the possible mechanisms of the radio wave - ionosphere interaction. In this report we present the results of comparison of the characteristics of the optical emissions caused by X-mode heating with the characteristics of the emissions enhanced by O-mode measured during same experiment.
Mapping chemical/structural order in double perovskite Sr2-xGdxMnTiO6 by atomic resolution electron microscopy

NASA Astrophysics Data System (ADS)

Alvarez, Inmaculada; Biskup, Neven; Lopez, Maria; Garcia-Hernandez, Mar; Veiga, Luisa; Varela, Maria; UCM Collaboration; ORNL Collaboration; CSIC Collaboration

2013-03-01

We report on visualizing the chemical and structural order of double perovskite Sr2-xGdxMnTiO6. The antisite disorder of Mn and Ti is detected even at atomic scale at all x, resulting in Mn-rich and Ti-rich regions. For x ?0.75, the majority of manganese ions are in Mn3+ state and are centered in Jahn-Teller distorted MnO6octahedra. The Fourier transformation of atomic resolution images along the [110] zone axis reveals a superstructure that corresponds to the tilting of oxygen octahedra and that doubles the unit cell along [001]c. This superstructure is spatially inhomogeneous and coincides with the regions where B-site ion (Mn/Ti) is displaced along the [110] direction. We discuss these findings in the frame of possible local ferroelectricity and in the light of strong electroresistance observed in Sr1.25Gd0.75MnTiO6. Research at ORNL supported by the U.S. DOE-BES, Materials Sciences and Engineering Division, and also by ORNL's ShaRE User Program (sponsored by DOE-BES). Research at UCM supported by the ERC Starting Investigator Award and MAT2010-20117.
Structural evolution of the double perovskites Sr{sub 2}B'UO{sub 6} (B' = Mn, Fe, Co, Ni, Zn) upon reduction: Magnetic behavior of the uranium cations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pinacca, R.M., E-mail: rmp@unsl.edu.ar; Viola, M.C.; Pedregosa, J.C.

2011-11-15

Highlights: {yields} Evolution of the double perovskites Sr{sub 2}B'UO{sub 6} upon reduction were studied by XRPD. {yields} Orthorhombic (Pnma) disordered perovskites SrB'{sub 0.5-x}U{sub 0.5+x}O{sub 3} were obtained at 900 {sup o}C. {yields} U{sup 5+/4+} and Zn{sup 2+} cations are distributed at random over the octahedral positions. {yields} AFM ordering for the perovskite with B' = Zn appears below 30 K. -- Abstract: We describe the preparation of five perovskite oxides obtained upon reduction of Sr{sub 2}B'UO{sub 6} (B' = Mn, Fe, Co, Ni, Zn) with H{sub 2}/N{sub 2} (5%/95%) at 900 {sup o}C during 8 h, and their structural characterizationmore » by X-ray powder diffraction (XRPD). During the reduction process there is a partial segregation of the elemental metal when B' = Co, Ni, Fe, and the corresponding B'O oxide when B' = Mn, Zn. Whereas the parent, oxygen stoichiometric double perovskites Sr{sub 2}B'UO{sub 6} are long-range ordered concerning B' and U cations. The crystal structures of the reduced phases, SrB'{sub 0.5-x}U{sub 0.5+x}O{sub 3} with 0.37 < x < 0.27, correspond to simple, disordered perovskites; they are orthorhombic, space group Pnma (No. 62), with a full cationic disorder at the B site. Magnetic measurements performed on the phase with B' = Zn, indicate uncompensated antiferromagnetic ordering of the U{sup 5+}/U{sup 4+} sublattice below 30 K.« less
Searching for Dual AGNs in Galaxy Mergers: Understanding Double-Peaked [O III] and Ultra Hard X-rays as Selection Method

NASA Astrophysics Data System (ADS)

McGurk, Rosalie C.; Max, Claire E.; Medling, Anne; Shields, Gregory A.

2015-01-01

When galaxies merge, gas accretes onto both central supermassive black holes. Thus, one expects to see close pairs of active galactic nuclei (AGNs), or dual AGNs, in a fraction of galaxy mergers. However, finding them remains a challenge. The presence of double-peaked [O III] or of ultra hard X-rays have been proposed as techniques to select dual AGNs efficiently. We studied a sample of double-peaked narrow [O III] emitting AGNs from SDSS DR7. By obtaining new and archival high spatial resolution images taken with the Keck 2 Laser Guide Star Adaptive Optics system and the near-infrared (IR) camera NIRC2, we showed that 30% of double-peaked [O III] emission line SDSS AGNs have two spatial components within a 3' radius. However, spatially resolved spectroscopy or X-ray observations are needed to confirm these galaxy pairs as systems containing two AGNs. We followed up these spatially-double candidate dual AGNs with integral field spectroscopy from Keck OSIRIS and Gemini GMOS and with long-slit spectroscopy from Keck NIRSPEC and Shane Kast Double Spectrograph. We find double-peaked emitters are caused sometimes by dual AGN and sometimes by outflows or narrow line kinematics. We also performed Chandra X-ray ACIS-S observations on 12 double-peaked candidate dual AGNs. Using our observations and 8 archival observations, we compare the distribution of X-ray photons to our spatially double near-IR images, measure X-ray luminosities and hardness ratios, and estimate column densities. By assessing what fraction of double-peaked emission line SDSS AGNs are true dual AGNs, we can better determine whether double-peaked [O III] is an efficient dual AGN indicator and constrain the statistics of dual AGNs. A second technique to find dual AGN is the detection of ultra hard X-rays by the Swift Burst Alert Telescope. We use CARMA observations to measure and map the CO(1-0) present in nearby ultra-hard X-ray Active Galactic Nuclei (AGNs) merging with either a quiescent companion
Full-wave feasibility study of anti-radar diagnostic of magnetic field based on O-X mode conversion and oblique reflectometry imaging

DOE PAGES

Meneghini, Orso; Volpe, Francesco A.

2016-08-19

An innovative millimeter wave diagnostic is proposed to measure the local magnetic field and edge current as a function of the minor radius in the tokamak pedestal region. The idea is to identify the direction of minimum reflectivity at the O-mode cutoff layer. Correspondingly, the transmissivity due to O-X mode conversion is maximum. That direction, and the angular map of reflectivity around it, contain information on the magnetic field vector B at the cutoff layer. By probing the plasma with different wave frequencies it provides the radial profile of B. Full-wave finite-element simulations are presented here in 2D slab geometry.more » Modeling confirms the existence of a minimum in reflectivity that depends on the magnetic field at the cutoff, as expected from mode conversion physics, giving confidence in the feasibility of the diagnostic. We proposed an reflectometric approach in order to yield superior signal-to-noise ratio and to access wider ranges of density and magnetic field, compared with related radiometric techniques that require the plasma to emit Electron Bernstein Waves. Due to computational limitations, frequencies of 10-20 GHz were considered in this initial study. Furthermore, frequencies above the edge electron-cyclotron frequency (f >28 GHz here) would be preferable for the experiment, because the upper hybrid resonance and right cutoff would lie in the plasma, and would help separate the O-mode of interest from spurious X-waves.« less
Full-wave feasibility study of anti-radar diagnostic of magnetic field based on O-X mode conversion and oblique reflectometry imaging

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meneghini, Orso; Volpe, Francesco A., E-mail: fvolpe@columbia.edu

An innovative millimeter wave diagnostic is proposed to measure the local magnetic field and edge current as a function of the minor radius in the tokamak pedestal region. The idea is to identify the direction of minimum reflectivity at the O-mode cutoff layer. Correspondingly, the transmissivity due to O-X mode conversion is maximum. That direction, and the angular map of reflectivity around it, contains information on the magnetic field vector B at the cutoff layer. Probing the plasma with different wave frequencies provides the radial profile of B. Full-wave finite-element simulations are presented here in 2D slab geometry. Modeling confirmsmore » the existence of a minimum in reflectivity that depends on the magnetic field at the cutoff, as expected from mode conversion physics, giving confidence in the feasibility of the diagnostic. The proposed reflectometric approach is expected to yield superior signal-to-noise ratio and to access wider ranges of density and magnetic field, compared with related radiometric techniques that require the plasma to emit electron Bernstein waves. Due to computational limitations, frequencies of 10-20 GHz were considered in this initial study. Frequencies above the edge electron-cyclotron frequency (f > 28 GHz here) would be preferable for the experiment, because the upper hybrid resonance and right cutoff would lie in the plasma, and would help separate the O-mode of interest from spurious X-waves.« less
Synchronous x-ray and radio mode switches: a rapid global transformation of the pulsar magnetosphere.

PubMed

Hermsen, W; Hessels, J W T; Kuiper, L; van Leeuwen, J; Mitra, D; de Plaa, J; Rankin, J M; Stappers, B W; Wright, G A E; Basu, R; Alexov, A; Coenen, T; Grießmeier, J-M; Hassall, T E; Karastergiou, A; Keane, E; Kondratiev, V I; Kramer, M; Kuniyoshi, M; Noutsos, A; Serylak, M; Pilia, M; Sobey, C; Weltevrede, P; Zagkouris, K; Asgekar, A; Avruch, I M; Batejat, F; Bell, M E; Bell, M R; Bentum, M J; Bernardi, G; Best, P; Bîrzan, L; Bonafede, A; Breitling, F; Broderick, J; Brüggen, M; Butcher, H R; Ciardi, B; Duscha, S; Eislöffel, J; Falcke, H; Fender, R; Ferrari, C; Frieswijk, W; Garrett, M A; de Gasperin, F; de Geus, E; Gunst, A W; Heald, G; Hoeft, M; Horneffer, A; Iacobelli, M; Kuper, G; Maat, P; Macario, G; Markoff, S; McKean, J P; Mevius, M; Miller-Jones, J C A; Morganti, R; Munk, H; Orrú, E; Paas, H; Pandey-Pommier, M; Pandey, V N; Pizzo, R; Polatidis, A G; Rawlings, S; Reich, W; Röttgering, H; Scaife, A M M; Schoenmakers, A; Shulevski, A; Sluman, J; Steinmetz, M; Tagger, M; Tang, Y; Tasse, C; ter Veen, S; Vermeulen, R; van de Brink, R H; van Weeren, R J; Wijers, R A M J; Wise, M W; Wucknitz, O; Yatawatta, S; Zarka, P

2013-01-25

Pulsars emit from low-frequency radio waves up to high-energy gamma-rays, generated anywhere from the stellar surface out to the edge of the magnetosphere. Detecting correlated mode changes across the electromagnetic spectrum is therefore key to understanding the physical relationship among the emission sites. Through simultaneous observations, we detected synchronous switching in the radio and x-ray emission properties of PSR B0943+10. When the pulsar is in a sustained radio-"bright" mode, the x-rays show only an unpulsed, nonthermal component. Conversely, when the pulsar is in a radio-"quiet" mode, the x-ray luminosity more than doubles and a 100% pulsed thermal component is observed along with the nonthermal component. This indicates rapid, global changes to the conditions in the magnetosphere, which challenge all proposed pulsar emission theories.
Raman and infrared spectroscopic investigations of a ferroelastic phase transition in B a2ZnTe O6 double perovskite

NASA Astrophysics Data System (ADS)

Moreira, Roberto L.; Lobo, Ricardo P. S. M.; Ramos, Sérgio L. L. M.; Sebastian, Mailadil T.; Matinaga, Franklin M.; Righi, Ariete; Dias, Anderson

2018-05-01

The low-temperature vibrational properties of B a2ZnTe O6 double-perovskite ceramics obtained by the solid-state route were investigated by Raman scattering and Fourier-transform infrared reflectivity. We found that this material undergoes a reversible ferroelastic phase transition at around 140 K, well compatible with a recently proposed rhombohedral-to-monoclinic structural change that would occur below 165 K. Complementary calorimetric measurements showed that the phase transition has a first-order character, with an entropy jump compatible with a displacive mechanism. The vibrational spectra show clearly the splitting of the doubly degenerate E modes into nondegenerate representations of the low-symmetry phase. In particular, the lowest-frequency Raman mode presents soft-mode behavior and splits below the critical temperature, confirming the in-plane ferroelastic deformation in the low-temperature phase.
Phase transitions in heated Sr{sub 2}MgTeO{sub 6} double perovskite oxide probed by X-ray diffraction and Raman spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manoun, Bouchaib, E-mail: manounb@gmail.com; Tamraoui, Y.; Lazor, P.

2013-12-23

Double-perovskite oxide Sr{sub 2}MgTeO{sub 6} has been synthetized, and its crystal structure was probed by the technique of X-ray diffraction at room temperature. The structure is monoclinic, space group I2/m. Temperature-induced phase transitions in this compound were investigated by Raman spectroscopy up to 550 °C. Two low-wavenumber modes corresponding to external lattice vibrations merge at temperature of around 100 °C, indicating a phase transition from the monoclinic (I2/m) to the tetragonal (I4/m) structure. At 300 °C, changes in the slopes of temperature dependencies of external and O–Te–O bending modes are detected and interpreted as a second phase transition from the tetragonal (I4/m) tomore » the cubic (Fm-3m) structure.« less
Ferromagnetic resonance study of the non-stoichiometric double perovskite Sr2Fe1+xMo1-xO6

NASA Astrophysics Data System (ADS)

Medina, J. De La Torre; Piraux, L.; Soto, T. E.; Morales, R.; Navarro, O.

2018-02-01

In this work we report a ferromagnetic resonance study on the magnetic properties of double perovskite compounds fab-ricated by solid state reaction. Based on a mean field approach, along with morphological considerations, we accurately determined the saturation magnetization of the non-stoichiometric double perovskite Sr2Fe1+xMo1-xO6. Our approach has revealed a direct in-fluence of composition on the overall magnetic behavior of these materials, providing complementary experimental evidence that corroborates previous theoretical findings. The understanding of the influence of composition is of paramount importance for the design of ferromagnetic oxides with tunable magnetic and magneto-transport behavior.
Formation, stability and crystal structure of mullite-type Al{sub 6−x}B{sub x}O{sub 9}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoffmann, K., E-mail: Kristin.Hoffmann@uni-bremen.de; Institut für Anorganische Chemie und Kristallographie, FB02, Leobener Straße/NW2, Universität Bremen, D-28359 Bremen; Hooper, T.J.N.

2016-11-15

Mullite-type Al{sub 6−x}B{sub x}O{sub 9} compounds were studied by means of powder diffraction and spectroscopic methods. The backbones of this structure are chains of edge-connected AlO{sub 6} octahedra crosslinked by AlO- and BO-polyhedra. Rietveld refinements show that the a and b lattice parameters can be well resolved, thus representing an orthorhombic metric. A continuous decrease of the lattice parameters most pronounced in c-direction indicates a solid solution for Al{sub 6−x}B{sub x}O{sub 9} with 1.09≤x≤2. A preference of boron in 3-fold coordination is confirmed by {sup 11}B MAS NMR spectroscopy and Fourier calculations based on neutron diffraction data collected at 4more » K. Distance Least Squares modeling was performed to simulate a local geometry avoiding long B-O distances linking two octahedral chains by planar BO{sub 3} groups yielding split positions for the oxygen atoms and a strong distortion in the octahedral chains. The lattice thermal expansion was calculated using the Grüneisen first-order equation of state Debye-Einstein-Anharmonicity model. - Graphical abstract: Local distortion induced by boron linking the octahedral chains. - Highlights: • Decreasing lattice parameters indicate a solid solution for Al{sub 6−x}B{sub x}O{sub 9} (1.09≤x≤2). • B-atoms induce a local distortion of neighboring AlO{sub 6} octahedra. • A preference of boron in BO{sub 3} coordination is confirmed by {sup 11}B MAS NMR spectroscopy. • An optimized structural model for Al{sub 6−x}B{sub x}O{sub 9} is presented.« less
Composition dependence of the in-plane Cu-O bond-stretching LO phonon mode in YBa2Cu3O6+x

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stercil, F.; Egami, T.; Mook Jr, Herbert A

An inelastic pulsed neutron scattering study was performed on the dependence of the dispersion and spectral intensity of the in-plane Cu-O bond-stretching LO phonon mode on doped charge density. The measurements were made in the time-of-flight mode with the multiangle position sensitive spectrometer of the ISIS facility on single crystals of YBa{sub 2}Cu{sub 3}O{sub 6+x} (x=0.15, 0.35, 0.6, 0.7, and 0.95). The focus of the study is the in-plane Cu-O bond-stretching LO phonon mode, which is known for strong electron-phonon coupling and unusual dependence on composition and temperature. It is shown that the dispersions for the samples with x=0.35, 0.6,more » and 0.7 are similar to the superposition of those for x=0.15 and 0.95 samples, and cannot be explained in terms of the structural anisotropy. It is suggested that the results are consistent with the model of nanoscale electronic phase separation, with the fraction of the phases being dependent on the doped charge density.« less
Structure, magnetism and electronic properties in 3d-5d based double perovskite ({Sr_{1-x}} Y x )2FeIrO6

NASA Astrophysics Data System (ADS)

Kharkwal, K. C.; Pramanik, A. K.

2017-12-01

The 3d-5d based double perovskites are of current interest as they provide model systems to study the interplay between electronic correlation (U) and spin-orbit coupling (SOC). Here, we report detailed structural, magnetic and transport properties of doped double perovskite material (Sr1-x Y x )2FeIrO6 with x ≤slant 0.2 . With substitution of Y, the system retains its original crystal structure but structural parameters change with x in nonmonotonic fashion. The magnetization data for Sr2FeIrO6 show antiferromagnetic type magnetic transition around 45 K however, a close inspection of the data indicates a weak magnetic phase transition around 120 K. No change of structural symmetry has been observed down to low temperature, although the lattice parameters show sudden changes around the magnetic transitions. Sr2FeIrO6 shows an insulating behavior over the whole temperature range, which nevertheless does not change with Y substitution. The nature of charge conduction is found to follow thermally activated Mott’s variable range hopping and power law behavior for parent and doped samples, respectively. Interestingly, evolution of structural, magnetic and transport behavior in (Sr1-x Y x )2FeIrO6 is observed to reverse with x > 0.1 , which is believed to arise due to a change in the transition metal ionic state.
Customized binary and multi-level HfO2-x-based memristors tuned by oxidation conditions.

PubMed

He, Weifan; Sun, Huajun; Zhou, Yaxiong; Lu, Ke; Xue, Kanhao; Miao, Xiangshui

2017-08-30

The memristor is a promising candidate for the next generation non-volatile memory, especially based on HfO 2-x , given its compatibility with advanced CMOS technologies. Although various resistive transitions were reported independently, customized binary and multi-level memristors in unified HfO 2-x material have not been studied. Here we report Pt/HfO 2-x /Ti memristors with double memristive modes, forming-free and low operation voltage, which were tuned by oxidation conditions of HfO 2-x films. As O/Hf ratios of HfO 2-x films increase, the forming voltages, SET voltages, and R off /R on windows increase regularly while their resistive transitions undergo from gradually to sharply in I/V sweep. Two memristors with typical resistive transitions were studied to customize binary and multi-level memristive modes, respectively. For binary mode, high-speed switching with 10 3 pulses (10 ns) and retention test at 85 °C (>10 4 s) were achieved. For multi-level mode, the 12-levels stable resistance states were confirmed by ongoing multi-window switching (ranging from 10 ns to 1 μs and completing 10 cycles of each pulse). Our customized binary and multi-level HfO 2-x -based memristors show high-speed switching, multi-level storage and excellent stability, which can be separately applied to logic computing and neuromorphic computing, further suitable for in-memory computing chip when deposition atmosphere may be fine-tuned.
Pulse intensity characterization of the LCLS nanosecond double-bunch mode of operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Yanwen; Decker, Franz-Josef; Turner, James

The recent demonstration of the 'nanosecond double-bunch' operation mode,i.e.two X-ray pulses separated in time between 0.35 and hundreds of nanoseconds and by increments of 0.35 ns, offers new opportunities to investigate ultrafast dynamics in diverse systems of interest. However, in order to reach its full potential, this mode of operation requires the precise characterization of the intensity of each X-ray pulse within each pulse pair for any time separation. Here, a transmissive single-shot diagnostic that achieves this goal for time separations larger than 0.7 ns with a precision better than 5% is presented. Lastly, it also provides real-time monitoring feedbackmore » to help tune the accelerator parameters to deliver double pulse intensity distributions optimized for specific experimental goals.« less
Pulse intensity characterization of the LCLS nanosecond double-bunch mode of operation

DOE PAGES

Sun, Yanwen; Decker, Franz-Josef; Turner, James; ...

2018-03-27

The recent demonstration of the 'nanosecond double-bunch' operation mode,i.e.two X-ray pulses separated in time between 0.35 and hundreds of nanoseconds and by increments of 0.35 ns, offers new opportunities to investigate ultrafast dynamics in diverse systems of interest. However, in order to reach its full potential, this mode of operation requires the precise characterization of the intensity of each X-ray pulse within each pulse pair for any time separation. Here, a transmissive single-shot diagnostic that achieves this goal for time separations larger than 0.7 ns with a precision better than 5% is presented. Lastly, it also provides real-time monitoring feedbackmore » to help tune the accelerator parameters to deliver double pulse intensity distributions optimized for specific experimental goals.« less
Canted ferrimagnetism and giant coercivity in the nonstoichiometric double perovskite L a2N i1.19O s0.81O6

NASA Astrophysics Data System (ADS)

Feng, Hai L.; Reehuis, Manfred; Adler, Peter; Hu, Zhiwei; Nicklas, Michael; Hoser, Andreas; Weng, Shih-Chang; Felser, Claudia; Jansen, Martin

2018-05-01

The nonstoichiometric double perovskite oxide L a2N i1.19O s0.81O6 was synthesized by solid-state reaction and its crystal and magnetic structures were investigated by powder x-ray and neutron diffraction. L a2N i1.19O s0.81O6 crystallizes in the monoclinic double perovskite structure (general formula A2B B'O6 ) with space group P 21/n , where the B site is fully occupied by Ni and the B ' site by 19% Ni and 81% Os atoms. Using x-ray absorption spectroscopy an O s4.5 + oxidation state was established, suggesting the presence of about 50% paramagnetic O s5 + (5 d3 , S =3 /2 ) and 50% nonmagnetic O s4 + (5 d4 , Jeff=0 ) ions at the B ' sites. Magnetization and neutron diffraction measurements on L a2N i1.19O s0.81O6 provide evidence for a ferrimagnetic transition at 125 K. The analysis of the neutron data suggests a canted ferrimagnetic spin structure with collinear N i2 + -spin chains extending along the c axis but a noncollinear spin alignment within the a b plane. The magnetization curve of L a2N i1.19O s0.81O6 features a hysteresis with a very high coercive field, HC=41 kOe , at T =5 K , which is explained in terms of large magnetocrystalline anisotropy due to the presence of Os ions together with atomic disorder. Our results are encouraging to search for rare-earth-free hard magnets in the class of double perovskite oxides.
Improved opto-electronic properties of silicon heterojunction solar cells with SiO x /Tungsten-doped indium oxide double anti-reflective coatings

NASA Astrophysics Data System (ADS)

Yu, Jian; Zhou, Jie; Bian, Jiantao; Zhang, Liping; Liu, Yucheng; Shi, Jianhua; Meng, Fanying; Liu, Jinning; Liu, Zhengxin

2017-08-01

Amorphous SiO x was prepared by plasma enhanced chemical vapor deposition (PECVD) to form SiO x /tungsten-doped indium oxide (IWO) double anti-reflective coatings for silicon heterojunction (SHJ) solar cell. The sheet resistance of SiO x /IWO stacks decreases due to plasma treatment during deposition process, which means thinner IWO film would be deposited for better optical response. However, the comparisons of three anti-reflective coating (ARC) structures reveal that SiO x film limits carier transport and the path of IWO-SiO x -Ag structure is non-conductive. The decrease of sheet resistance is defined as pseudo conductivity. IWO film capping with SiO x allows observably reduced reflectance and better response in 300-400 and 600-1200 nm wavelength ranges. Compared with IWO single ARC, the average reflection is reduced by 1.65% with 70 nm SiO x /80 nm IWO double anti-reflective coatings (DARCs) in 500-1200 nm wavelength range, leading to growing external quantum efficiency response, short circuit current density (J sc), and efficiency. After well optimization of SiO x /IWO stacks, an impressive efficiency of 23.08% is obtained with high J sc and without compromising open circuit voltage (V oc) and fill factor. SiO x /IWO DARCs provide better anti-reflective properties over a broad range of wavelength, showing promising application for SHJ solar cells.
Syntheses and luminescence study for La{sub 1−x}Eu{sub x}[B{sub 5}O{sub 8}(OH){sub 2}]·1.5H{sub 2}O (0≤x≤0.40) and the dehydrated products β-La{sub 1−x}Eu{sub x}B{sub 5}O{sub 9} (0≤x≤0.15)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Xiaorui; Zhou, Zhengyang; Yang, Haixia

La{sub 1−x}Eu{sub x}[B{sub 5}O{sub 8}(OH){sub 2}]·1.5H{sub 2}O with the Eu{sup 3+}-doping upper limit of 40 atom% were synthesized hydrothermally. Thereafter, thermal treatments at 710 °C were applied to obtain β-La{sub 1−x}Eu{sub x}B{sub 5}O{sub 9}. The solid solution range is even narrower, i.e. 0≤x≤0.15, due to the mismatch between La{sup 3+} and Eu{sup 3+}. The host borate system shows a typical concentration quenching effect at x=0.20 under CT excitation, and this is postponed to x=0.30 under the f−f excitation. β-La{sub 1−x}Eu{sub x}B{sub 5}O{sub 9} shows a very intense absorption of charge transfer, and gives strong red emissions at 615 nm withmore » large R/O ratios (1.9–2.4). The saturation effect appears at x=0.11, which is probably due to the lattice distortion. Eu{sup 3+} luminescence was applied as the structural probe to study the local coordination environment change during the dehydration and re-crystallization processes of La{sub 0.93}Eu{sub 0.07}[B{sub 5}O{sub 8}(OH){sub 2}]·1.5H{sub 2}O. - Highlights: • La{sub 1−x}Eu{sub x}[B{sub 5}O{sub 8}(OH){sub 2}]·1.5H{sub 2}O (0≤x≤0.40) were prepared by hydrothermal method. • The Eu{sup 3+}-doping limit in β-La{sub 1−x}Eu{sub x}B{sub 5}O{sub 9} is 15 atom% proved by powder XRD. • La{sub 1−x}Eu{sub x}[B{sub 5}O{sub 8}(OH){sub 2}]·1.5H{sub 2}O show relatively weaker red emissions. • β-La{sub 1−x}Eu{sub x}B{sub 5}O{sub 9} shows an intense CT absorption together with strong red emissions. • Eu{sup 3+} luminescence was studied when annealing La{sub 0.93}Eu{sub 0.07}[B{sub 5}O{sub 8}(OH){sub 2}]·1.5H{sub 2}O.« less
Double perovskite Sr2FeMoO6-xNx (x=0.3, 1.0) oxynitrides with anionic ordering

NASA Astrophysics Data System (ADS)

Retuerto, M.; de la Calle, C.; Martínez-Lope, M. J.; Porcher, F.; Krezhov, K.; Menéndez, N.; Alonso, J. A.

2012-01-01

Two new oxynitride double perovskites of composition Sr2FeMoO6-xNx (x=0.3, 1.0) have been synthesized by annealing precursor powders obtained by citrate techniques in flowing ammonia at 750 °C and 650 °C, respectively. The polycrystalline samples have been characterized by chemical analysis, x-ray and neutron diffraction (NPD), Mössbauer spectroscopy and magnetic measurements. They exhibit a tetragonal structure with a=5.5959(1) Å, c=7.9024(2) Å, V=247.46(2) Å3 for Sr2FeMoO5.7N0.3; and a=5.6202(2) Å, c=7.9102(4) Å, V=249.85(2) Å3 for Sr2FeMoO5N; space group I4/m, Z=2. The nitridation process seems to extraordinarily improve the long-range Fe/Mo ordering, achieving 95% at moderate temperatures of 750 °C. The analysis of high resolution NPD data, based on the contrast existing between the scattering lengths of O and N, shows that both atoms are located at (O,N)2 anion substructure corresponding to the basal ab plane of the perovskite structure, whereas the O1 site is fully occupied by oxygen atoms. The evolution of the O> and O> distances suggests a shift towards a configuration close to Fe4+(3d4, S=2):Mo5+(4d1, S=1/2). The magnetic susceptibility shows a ferrimagnetic transition with a reduced saturation magnetization compared to Sr2FeMoO6, due to the different nature of the magnetic double exchange interactions through Fe-N-Mo-N-Fe paths in contrast to the stronger Fe-O-Mo-O-Fe interactions. Also, the effect observed by low-temperature NPD seems to reduce the ordered Fe moments and enhance the Mo moments, in agreement with the evolution of the oxidation states, thus decreasing the saturation magnetization.

Ultrafast X-ray diffraction probe of terahertz field-driven soft mode dynamics in SrTiO 3

DOE PAGES

Kozina, M.; van Driel, T.; Chollet, M.; ...

2017-05-03

We use ultrafast x-ray pulses to characterize the lattice response of SrTiO 3 when driven by strong terahertz (THz) fields. We observe transient changes in the diffraction intensity with a delayed onset with respect to the driving field. Fourier analysis reveals two frequency components corresponding to the two lowest energy zone-center optical modes in SrTiO 3. Lastly, the lower frequency mode exhibits clear softening as the temperature is decreased while the higher frequency mode shows slight temperature dependence.
Ultrafast X-ray diffraction probe of terahertz field-driven soft mode dynamics in SrTiO 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kozina, M.; van Driel, T.; Chollet, M.

We use ultrafast x-ray pulses to characterize the lattice response of SrTiO 3 when driven by strong terahertz (THz) fields. We observe transient changes in the diffraction intensity with a delayed onset with respect to the driving field. Fourier analysis reveals two frequency components corresponding to the two lowest energy zone-center optical modes in SrTiO 3. Lastly, the lower frequency mode exhibits clear softening as the temperature is decreased while the higher frequency mode shows slight temperature dependence.
CzeV293 and CzeV581-Two new high-amplitude double-mode delta Scuti stars

NASA Astrophysics Data System (ADS)

Skarka, M.; Cagaš, P.

2016-07-01

We report on the discovery of two high-amplitude double-mode delta Scuti stars in constellations of Hercules and Auriga. The stars were observed photometrically in five and two seasons, respectively. Frequency analysis revealed that both stars show complex pulsation behaviour with two independent modes and several combination peaks. Placing the stars into the Petersen diagram allowed us to identify the pulsation modes as the fundamental and the first overtone. Both stars follow the general trend for F/1O pulsators in the short-period part of the Petersen diagram and turned out to be classical members of HADS group of variables. Using empirical formulae we roughly estimate visual absolute magnitude, intrinsic (B - V) 0 colour index and temperature of the target stars.
Status of the LIA-2. Double-pulse mode

NASA Astrophysics Data System (ADS)

Starostenko, D. A.; Akimov, A. V.; Bak, P. A.; Batazova, M. A.; Batrakov, A. M.; Boimelshtein, Yu. M.; Bolkhovityanov, D. Yu.; Eliseev, A. A.; Korepanov, A. A.; Kuznetsov, G. I.; Kulenko, Ya. V.; Logatchev, P. V.; Ottmar, A. V.; Pavlenko, A. V.; Pavlov, O. A.; Panov, A. N.; Pachkov, A. A.; Fatkin, G. A.; Akhmetov, A. R.; Kolesnikov, P. A.; Nikitin, O. A.; Petrov, D. V.

2016-12-01

The LIA-2 linear induction accelerator has been designed in the Budker Institute of Nuclear Physics as an electron-beam injector for a promising 20-MeV induction accelerator intended for tomography. Owing to the results of the first tests, it was decided to use the injector as an independent X-ray installation [1]. In 2014, the high-voltage power supply system of the LIA-2 was upgraded and tuned. The accelerator operates stably in the one-pulse mode at energies of up to 1.7 MeV; in the double-pulse mode it operates at energies of up to 1.5 MeV. The inhomogeneity in energy in each pulse does not exceed ±0.5%.
X-RAY EMISSION FROM THE DOUBLE-BINARY OB-STAR SYSTEM QZ CAR (HD 93206)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parkin, E. R.; Naze, Y.; Rauw, G.

X-ray observations of the double-binary OB-star system QZ Car (HD 93206) obtained with the Chandra X-ray Observatory over a period of roughly 2 years are presented. The respective orbits of systems A (O9.7 I+b2 v, P{sub A} = 21 days) and B (O8 III+o9 v, P{sub B} = 6 days) are reasonably well sampled by the observations, allowing the origin of the X-ray emission to be examined in detail. The X-ray spectra can be well fitted by an attenuated three-temperature thermal plasma model, characterized by cool, moderate, and hot plasma components at kT {approx_equal} 0.2, 0.7, and 2 keV, respectively,more » and a circumstellar absorption of {approx_equal}0.2 x 10{sup 22} cm{sup -2}. Although the hot plasma component could be indicating the presence of wind-wind collision shocks in the system, the model fluxes calculated from spectral fits, with an average value of {approx_equal}7 x 10{sup -13} erg s{sup -1} cm{sup -2}, do not show a clear correlation with the orbits of the two constituent binaries. A semi-analytical model of QZ Car reveals that a stable momentum balance may not be established in either system A or B. Yet, despite this, system B is expected to produce an observed X-ray flux well in excess of the observations. If one considers the wind of the O8 III star to be disrupted by mass transfer, the model and observations are in far better agreement, which lends support to the previous suggestion of mass transfer in the O8 III + o9 v binary. We conclude that the X-ray emission from QZ Car can be reasonably well accounted for by a combination of contributions mainly from the single stars and the mutual wind-wind collision between systems A and B.« less
Enhanced thermoelectric figure-of-merit in environmentally benign BaxSr2-xTiCoO6 double perovskites

NASA Astrophysics Data System (ADS)

Saxena, Mandvi; Roy, Pinku; Acharya, Megha; Bose, Imon; Tanwar, Khagesh; Maiti, Tanmoy

2016-12-01

Environmental friendly, non-toxic double perovskite BaxSr2-xTiCoO6 compositions with 0 ≤ x ≤ 0.2 were synthesized using solid-state reaction route for high temperature thermoelectric (TE) applications. XRD and SEM studies confirmed the presence of single-phase solid solution with highly dense microstructure for all the oxide compositions. Temperature dependent electrical conductivity measurement showed semiconductor to metal (M-S) transition in these double perovskites. Incorporation of barium in Sr2TiCoO6 pushed M-S transition to higher temperature making it a potential candidate for high temperature TE applications. Conductivity behaviors of these oxides were explained by small polaron model. Furthermore, these oxides exhibit a glass like behavior resulting in low thermal conductivity. Low temperature dielectric measurement revealed relaxor ferroelectric behavior in these oxides below room temperature. Transition of these relaxors into a glassy state beyond Burns temperature (TD) was found responsible for having low thermal conductivity in these oxides. Maximum dimensionless TE figure-of-merit ZT = 0.29 at 1223 K was achieved for BaxSr2-xTiCoO6 composition with x = 0.2.
The crystal structures of BiTeO 3I, NdTeO 3X (X=Cl, Br) and Bi 5TeO 8.5I 2: some crystal chemistry peculiarities of layered Bi(Ln)Te oxyhalides

NASA Astrophysics Data System (ADS)

Berdonosov, Peter S.; Charkin, Dmitry O.; Kusainova, Ardak M.; Hervoches, Charles H.; Dolgikh, Valeriy A.; Lightfoot, Philip

2000-09-01

Four new layered oxyhalides related to the Sillen family have been prepared and characterized by Rietveld refinement of powder X-ray and neutron diffraction data. BiTeO 3I and NdTeO 3Br both adopt tetragonal symmetry, space group P4/ nmm (for BiTeO 3I, a=4.10811(8), c=27.988(1) Å; NdTeO 3Br, a=4.06603(7), c=26.922(1) Å, at 25°C). The structures are composed of triple and double fluorite-related mixed metal oxide layers separated by single and double halogen layers, in the sequence MTe 2O 5XXMTe 2O 5XM 2O 2X, which may be represented by the symbol X 13X 13X 22, where the subscript signifies the number of halogen layers and the superscript the number of metal sublayers within the fluorite block, by analogy with Sillen's notation. The double fluorite layers are occupied exclusively by Bi, whereas there is an ordered arrangement of Bi/Te within the triple fluorite layers, with Te exclusively occupying the outer sublayers of the block. NdTeO 3Cl adopts an orthorhombically distorted form of this structure type, space group Pmmn, a=4.08096(8), b=4.03441(8), c=25.7582(7) Å at 25°C. Bi 5TeO 8.5I 2 adopts a distorted, non-centrosymmetric version of the simpler X 13 structure type, space group Cmm2, a=5.6878(3), b=5.7230(3), c=9.7260(6) Å, consisting of single halogen layers sandwiched between triple fluorite layers, in which there is partial ordering of the Bi/Te cations.
Ultrafast Three-Dimensional X-ray Imaging of Deformation Modes in ZnO Nanocrystals.

PubMed

Cherukara, Mathew J; Sasikumar, Kiran; Cha, Wonsuk; Narayanan, Badri; Leake, Steven J; Dufresne, Eric M; Peterka, Tom; McNulty, Ian; Wen, Haidan; Sankaranarayanan, Subramanian K R S; Harder, Ross J

2017-02-08

Imaging the dynamical response of materials following ultrafast excitation can reveal energy transduction mechanisms and their dissipation pathways, as well as material stability under conditions far from equilibrium. Such dynamical behavior is challenging to characterize, especially operando at nanoscopic spatiotemporal scales. In this letter, we use X-ray coherent diffractive imaging to show that ultrafast laser excitation of a ZnO nanocrystal induces a rich set of deformation dynamics including characteristic "hard" or inhomogeneous and "soft" or homogeneous modes at different time scales, corresponding respectively to the propagation of acoustic phonons and resonant oscillation of the crystal. By integrating the 3D nanocrystal structure obtained from the ultrafast X-ray measurements with a continuum thermo-electro-mechanical finite element model, we elucidate the deformation mechanisms following laser excitation, in particular, a torsional mode that generates a 50% greater electric potential gradient than that resulting from the flexural mode. Understanding of the time-dependence of these mechanisms on ultrafast scales has significant implications for development of new materials for nanoscale power generation.
Ultrafast Three-Dimensional X-ray Imaging of Deformation Modes in ZnO Nanocrystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cherukara, Mathew J.; Sasikumar, Kiran; Cha, Wonsuk

Imaging the dynamical response of materials following ultrafast excitation can reveal energy transduction mechanisms and their dissipation pathways, as well as material stability under conditions far from equilibrium. Such dynamical behaviour is challenging to characterize, especially operando at nanoscopic spatiotemporal scales. In this letter, we use x-ray coherent diffractive imaging to show that ultrafast laser excitation of a ZnO nanocrystal induces a rich set of deformation dynamics including characteristic ‘hard’ or inhomogeneous and ‘soft’ or homogeneous modes at different time scales, corresponding respectively to the propagation of acoustic phonons and resonant oscillation of the crystal. By integrating the 3D nanocrystalmore » structure obtained from the ultrafast x-ray measurements with a continuum thermo-electro-mechanical finite element model, we elucidate the deformation mechanisms following laser excitation, in particular, a torsional mode that generates a 50% greater electric potential gradient than that resulting from the flexural mode. Furthermore, understanding of the time-dependence of these mechanisms on ultrafast scales has significant implications for development of new materials for nanoscale power generation.« less
Ultrafast Three-Dimensional X-ray Imaging of Deformation Modes in ZnO Nanocrystals

DOE PAGES

Cherukara, Mathew J.; Sasikumar, Kiran; Cha, Wonsuk; ...

2016-12-27

Imaging the dynamical response of materials following ultrafast excitation can reveal energy transduction mechanisms and their dissipation pathways, as well as material stability under conditions far from equilibrium. Such dynamical behaviour is challenging to characterize, especially operando at nanoscopic spatiotemporal scales. In this letter, we use x-ray coherent diffractive imaging to show that ultrafast laser excitation of a ZnO nanocrystal induces a rich set of deformation dynamics including characteristic ‘hard’ or inhomogeneous and ‘soft’ or homogeneous modes at different time scales, corresponding respectively to the propagation of acoustic phonons and resonant oscillation of the crystal. By integrating the 3D nanocrystalmore » structure obtained from the ultrafast x-ray measurements with a continuum thermo-electro-mechanical finite element model, we elucidate the deformation mechanisms following laser excitation, in particular, a torsional mode that generates a 50% greater electric potential gradient than that resulting from the flexural mode. Furthermore, understanding of the time-dependence of these mechanisms on ultrafast scales has significant implications for development of new materials for nanoscale power generation.« less
Constraining primordial vector mode from B-mode polarization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saga, Shohei; Ichiki, Kiyotomo; Shiraishi, Maresuke, E-mail: saga.shohei@nagoya-u.jp, E-mail: maresuke.shiraishi@pd.infn.it, E-mail: ichiki@a.phys.nagoya-u.ac.jp

The B-mode polarization spectrum of the Cosmic Microwave Background (CMB) may be the smoking gun of not only the primordial tensor mode but also of the primordial vector mode. If there exist nonzero vector-mode metric perturbations in the early Universe, they are known to be supported by anisotropic stress fluctuations of free-streaming particles such as neutrinos, and to create characteristic signatures on both the CMB temperature, E-mode, and B-mode polarization anisotropies. We place constraints on the properties of the primordial vector mode characterized by the vector-to-scalar ratio r{sub v} and the spectral index n{sub v} of the vector-shear power spectrum,more » from the Planck and BICEP2 B-mode data. We find that, for scale-invariant initial spectra, the ΛCDM model including the vector mode fits the data better than the model including the tensor mode. The difference in χ{sup 2} between the vector and tensor models is Δχ{sup 2} = 3.294, because, on large scales the vector mode generates smaller temperature fluctuations than the tensor mode, which is preferred for the data. In contrast, the tensor mode can fit the data set equally well if we allow a significantly blue-tilted spectrum. We find that the best-fitting tensor mode has a large blue tilt and leads to an indistinct reionization bump on larger angular scales. The slightly red-tilted vector mode supported by the current data set can also create O(10{sup -22})-Gauss magnetic fields at cosmological recombination. Our constraints should motivate research that considers models of the early Universe that involve the vector mode.« less
EPR spectroscopic investigations in 15BaO-25Li2O-(60-x) B2O3-xFe2O3 glass system

NASA Astrophysics Data System (ADS)

Bhogi, Ashok; Kumar, R. Vijaya; Kistaiah, P.

2018-05-01

Glasses with composition 15BaO-25Li2O-(60-x) B2O3 -xFe2O3 (x = 0, 0.2, 0.4, 0.6, 0.8 and 1 mol %) were prepared by the conventional melt quenching technique. These glasses were characterized using X-ray diffraction (XRD). Electron paramagnetic resonance (EPR) investigations have been carried out as a function of iron ion concentration. The observed EPR spectra of Fe3+ ion exhibits resonance signals at g= 2.0, 4.3 and 8.0. The resonance signal at g= 4.3 is due to isolated Fe3+ ions in site with rhombic symmetry where as the g= 2.0 resonance signal is attributed to the Fe3+ ions coupled by exchange interaction in a distorted octahedral environment and the signal at g= 8.0 arises from axially distorted sites. The number of spins participating in resonance (N) and its paramagnetic susceptibilities (χ) have also been evaluated. The peak-to-peak line width ΔB for the resonance lines at g ≈ 4.3 and at g ≈ 2.0 is increasing as function of the iron ion content. The line intensity of the resonance centered at g ≈ 4.3 and at g ≈ 2.0 increases up to 0.8 mol% of Fe2O3 and for 1 mol% of Fe2O3 its value is found to decrease. The analysis of these results indicated that the conversion some of Fe3+ cations to Fe2+ ions beyond 0.8 mol%.
Multiferroic Double Perovskites ScFe1-xCrxO3 (1 /6 ≤x ≤5 /6 ) for Highly Efficient Photovoltaics and Spintronics

NASA Astrophysics Data System (ADS)

Cai, Tian-Yi; Liu, Shi-Chen; Ju, Sheng; Liu, Cheng-You; Guo, Guang-Yu

2017-09-01

Ferroelectric oxides are attractive materials for constructing efficient solar cells. Nevertheless, a wide band gap of nearly 3.0 eV in these ferroelectric oxides would result in poor overall sunlight absorption and, hence, low energy conversion efficiency. Here, by systematic first-principles density-functional calculations, we demonstrate that double-perovskite semiconductors ScFe1-xCrxO3 (1 /6 ≤x ≤5 /6 ) with a narrow band gap of approximately 1.8 eV would simultaneously exhibit large ferroelectric polarization (100 μ C /cm2 ) and ferrimagnetic magnetization (170 emu/cm3 ). Within a Schottky-based model for a typical sandwich solar-cell structure, a power-conversion efficiency of 9.0% can be reached by neglecting all other sources of photovoltaicity in ferroelectric materials. This value is larger than the largest value of 8.1% observed in ferroelectric oxides. Furthermore, these double perovskites are found to be single-spin semiconductors, and the obtained photocurrent is fully spin polarized over almost the entire Sun spectrum. These fascinating advantages would make ScFex Cr1 -xO3 (1 /6 ≤x ≤5 /6 ) semiconductors promising candidates for highly efficient solar cells and spin photovoltaic devices.
Colossal change in thermopower with temperature-driven p-n-type conduction switching in La x Sr2-x TiFeO6 double perovskites

NASA Astrophysics Data System (ADS)

Roy, Pinku; Maiti, Tanmoy

2018-02-01

Double perovskite materials have been studied in detail by many researchers, as their magnetic and electronic properties can be controlled by the substitution of alkaline earth metals or lanthanides in the A site and transition metals in the B site. Here we report the temperature-driven, p-n-type conduction switching assisted, large change in thermopower in La3+-doped Sr2TiFeO6-based double perovskites. Stoichiometric compositions of La x Sr2-x TiFeO6 (LSTF) with 0 ⩽ x ⩽ 0.25 were synthesized by the solid-state reaction method. Rietveld refinement of room-temperature XRD data confirmed a single-phase solid solution with cubic crystal structure and Pm\\bar{3}m space group. From temperature-dependent electrical conductivity and Seebeck coefficient (S) studies it is evident that all the compositions underwent an intermediate semiconductor-to-metal transition before the semiconductor phase reappeared at higher temperature. In the process of semiconductor-metal-semiconductor transition, LSTF compositions demonstrated temperature-driven p-n-type conduction switching behavior. The electronic restructuring which occurs due to the intermediate metallic phase between semiconductor phases leads to the colossal change in S for LSTF oxides. The maximum drop in thermopower (ΔS ~ 2516 µV K-1) was observed for LSTF with x = 0.1 composition. Owing to their enormous change in thermopower of the order of millivolts per kelvin, integrated with p-n-type resistance switching, these double perovskites can be used for various high-temperature multifunctional device applications such as diodes, sensors, switches, thermistors, thyristors, thermal runaway monitors etc. Furthermore, the conduction mechanisms of these oxides were explained by the small polaron hopping model.
Fragility Index variation in (Li2O)x(B2O3) 100-x melts

NASA Astrophysics Data System (ADS)

Skipper, Charles; Chbeir, Ralph; Mohanty, Chandi; Boolchand, Punit

We have measured the fragility index (m) of titled melts as a function of Li2O content in the 0<x<35% range using Modulated DSC. In this approach, one measures the real and imaginary part of the complex specific heat as a function of modulation frequency (ν) , and deduces an activation energy by plotting the log of the enthalpy relaxation time as a function of inverse Temperature obtained at various ν. For pure B2O3 glass with a Tg = 308°C, we obtain m = 28 (1). With increasing x, m is found to monotonically increase to 38(1) as x increased to 15%, but then to plateau at a value of m = 42(2) in the range 18%<x<25%. These values in m are significantly lower than those reported earlier. In particular, the range of x where we observe a plateau in m, authors of ref. 1 observed a linear increase in the 41x across which a plateau is observed also happens to coincide where the isostatically rigid Intermediate Phase reported recently.
Influence of nonmagnetic Al ions on magnetoresistance of double-perovskite Sr2Fe1-xAlxMoO6 (0<=x<=0.30)

NASA Astrophysics Data System (ADS)

Sui, Yu; Wang, Xianjie; Cheng, Jinguang; Liu, Zhiguo; Miao, Jipeng; Huang, Xiqiang; Lu, Zhe; Qian, Zhengnan; Su, Wenhui; Tang, Jinke; Ong, C. K.

2005-09-01

The structural, magnetic, and magnetoresistance properties of the double-perovskite series Sr2Fe1-xAlxMoO6 (0<=x<=0.30) were systematically investigated in order to clarify the influence of nonmagnetic Al ions on the magnetoresistance. The structural refinements of these samples show that the degree of cationic order increases gradually from 88.5% for x=0 to 92% for x=0.30 without any change in the crystal structure. The magnetization measurements reveal that the substitution of nonmagnetic Al ion for Fe ion enhances the magnetic moment per Fe ion significantly. In addition, the magnetic-field dependence of magnetization and magnetoresistance of these Sr2Fe1-xAlxMoO6 samples were all fitted excellently by taking into account the contributions from ferromagnetic-coupled Fe-O-Mo region and nonferromagnetic-coupled regions. The fitting results indicate that the low-field magnetoresistance can be greatly enhanced due to the separation of the cationic-ordered Fe-O-Mo regions by the paramagnetic Mo-O-Al-O-Mo chains introduced through Al doping. Furthermore, doping nonmagnetic Al ions also suppress the formation of antiferromagnetic Fe-O-Fe antiphase boundaries, and then lead to the improvement of cation ordering and the reduction of magnetoresistance under high field.
High-pressure behavior of A 2 B 2 O 7 pyrochlore (A=Eu, Dy; B=Ti, Zr)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rittman, Dylan R.; Turner, Katlyn M.; Park, Sulgiye

2017-01-28

In situ high-pressure X-ray diffraction and Raman spectroscopy were used to determine the influence of composition on the high-pressure behavior of A 2B 2O 7 pyrochlore (A=Eu, Dy; B=Ti, Zr) up to ~50GPa. Based on X-ray diffraction results, all compositions transformed to the high-pressure cotunnite structure. The B-site cation species had a larger effect on the transition pressure than the A-site cation species, with the onset of the phase transformation occurring at ~41 GPa for B=Ti and ~16 GPa B=Zr. However, the A-site cation affected the kinetics of the phase transformation, with the transformation for compositions with the smaller ionicmore » radii, i.e., A=Dy, proceeding faster than those with a larger ionic radii, i.e., A=Eu. These results were consistent with previous work in which the radius-ratio of the A- and B-site cations determined the energetics of disordering, and compositions with more similarly sized A- and B-site cations had a lower defect formation energy. Raman spectra revealed differences in the degree of short-range order of the different compositions. Due to the large phase fraction of cotunnite at high pressure for B=Zr compositions, Raman modes for cotunnite could be observed, with more modes recorded for A=Eu than A=Dy. These additional modes are attributed to increased short-to-medium range ordering in the initially pyrochlore structured Eu 2Zr 2O 7 as compared with the initially defect-fluorite structured Dy 2Zr 2O 7.« less
Current-induced spin-orbit torque switching of perpendicularly magnetized Hf|CoFeB|MgO and Hf|CoFeB|TaO{sub x} structures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akyol, Mustafa; Department of Physics, University of Çukurova, Adana 01330; Yu, Guoqiang

2015-04-20

We study the effect of the oxide layer on current-induced perpendicular magnetization switching properties in Hf|CoFeB|MgO and Hf|CoFeB|TaO{sub x} tri-layers. The studied structures exhibit broken in-plane inversion symmetry due to a wedged CoFeB layer, resulting in a field-like spin-orbit torque (SOT), which can be quantified by a perpendicular (out-of-plane) effective magnetic field. A clear difference in the magnitude of this effective magnetic field (H{sub z}{sup FL}) was observed between these two structures. In particular, while the current-driven deterministic perpendicular magnetic switching was observed at zero magnetic bias field in Hf|CoFeB|MgO, an external magnetic field is necessary to switch the CoFeBmore » layer deterministically in Hf|CoFeB|TaO{sub x}. Based on the experimental results, the SOT magnitude (H{sub z}{sup FL} per current density) in Hf|CoFeB|MgO (−14.12 Oe/10{sup 7} A cm{sup −2}) was found to be almost 13× larger than that in Hf|CoFeB|TaO{sub x} (−1.05 Oe/10{sup 7} A cm{sup −2}). The CoFeB thickness dependence of the magnetic switching behavior, and the resulting H{sub z}{sup FL} generated by in-plane currents are also investigated in this work.« less
Strain-induced changes of the electronic properties of B -site ordered double-perovskite Sr2CoIrO6 thin films

NASA Astrophysics Data System (ADS)

Esser, S.; Chang, C. F.; Kuo, C.-Y.; Merten, S.; Roddatis, V.; Ha, T. D.; Jesche, A.; Moshnyaga, V.; Lin, H.-J.; Tanaka, A.; Chen, C. T.; Tjeng, L. H.; Gegenwart, P.

2018-05-01

B -site ordered thin films of double perovskite Sr2CoIrO6 were epitaxially grown by a metalorganic aerosol deposition technique on various substrates, actuating different strain states. X-ray diffraction, transmission electron microscopy, and polarized far-field Raman spectroscopy confirm the strained epitaxial growth on all used substrates. Polarization-dependent Co L2 ,3 x-ray absorption spectroscopy reveals a change of the magnetic easy axis of the antiferromagnetically ordered (high-spin) Co3 + sublattice within the strain series. By reversing the applied strain direction from tensile to compressive, the easy axis changes abruptly from in-plane to out-of-plane orientation. The low-temperature magnetoresistance changes its sign respectively and is described by a combination of weak antilocalization and anisotropic magnetoresistance effects.
Raman scattering studies of strain effects in (100) and (311)B GaAs1-xBix epitaxial layers

NASA Astrophysics Data System (ADS)

Steele, J. A.; Lewis, R. A.; Henini, M.; Lemine, O. M.; Alkaoud, A.

2013-11-01

We report room-temperature Raman studies of strained (100) and (311)B GaAs1-xBix epitaxial layers for x ≤ 0.039. The Raman spectra exhibit a two-mode behavior, as well as disorder-activated GaAs-like phonons. The experimental results show that the GaAs-like LO(Γ) mode experiences a strong composition-dependent redshift as a result of alloying. The peak frequency decreases linearly from the value for pure GaAs (˜293 cm-1) with the alloyed Bi fraction x and the introduced in-plane lattice strain ɛ∥, by ΔωLO=Δωalloy-Δωstrain. X-ray diffraction measurements are used to determine x and ɛ∥ allowing Δωalloy to be decoupled and is estimated to be -12(±4) cm-1/x for (100) GaAs1-xBix. ΔωLO is measured to be roughly double for samples grown on (311)B-oriented substrates to that of (100) GaAs. This large difference in redshift is accounted for by examining the Bi induced strain, effects from alloying, and defects formed during high-index (311)B crystal growth.

High-pressure behavior of A 2 B 2 O 7 pyrochlore (A=Eu, Dy; B=Ti, Zr)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rittman, Dylan R.; Turner, Katlyn M.; Park, Sulgiye

2017-01-24

In situ high-pressure X-ray diffraction and Raman spectroscopy were used to determine the influence of composition on the high-pressure behavior of A 2B 2O 7 pyrochlore (A = Eu, Dy; B = Ti, Zr) up to ~50 GPa. Based on X-ray diffraction results, all compositions transformed to the high-pressure cotunnite structure. The B-site cation species had a larger effect on the transition pressure than the A-site cation species, with the onset of the phase transformation occurring at ~41 GPa for B = Ti and ~16 GPa B = Zr. But, the A-site cation affected the kinetics of the phase transformation,more » with the transformation for compositions with the smaller ionic radii, i.e., A = Dy, proceeding faster than those with a larger ionic radii, i.e., A = Eu. Our results were consistent with previous work in which the radius-ratio of the A- and B-site cations determined the energetics of disordering, and compositions with more similarly sized A- and B-site cations had a lower defect formation energy. Raman spectra revealed differences in the degree of short-range order of the different compositions. Due to the large phase fraction of cotunnite at high pressure for B = Zr compositions, Raman modes for cotunnite could be observed, with more modes recorded for A = Eu than A = Dy. These additional modes are attributed to increased short-to-medium range ordering in the initially pyrochlore structured Eu 2Zr 2O 7 as compared with the initially defect-fluorite structured Dy 2Zr 2O 7.« less
Boron Substituted Na 3 V 2 (P 1 -x B x O 4 ) 3 Cathode Materials with Enhanced Performance for Sodium-Ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Pu; Wang, Xiaofang; Wang, Tianshi

The development of excellent performance of Na-ion batteries remains great challenge owing to the poor stability and sluggish kinetics of cathode materials. Herein, B substituted Na 3V 2P 3–xB xO 12 (0 ≤ x ≤ 1) as stable cathode materials for Na-ion battery is presented. A combined experimental and theoretical investigations on Na 3V 2P 3–xB xO 12 (0 ≤ x ≤ 1) are undertaken to reveal the evolution of crystal and electronic structures and Na storage properties associated with various concentration of B. X-ray diffraction results indicate that the crystal structure of Na 3V 2P 3–xB xO 12 (0more » ≤ x ≤ 1/3) consisted of rhombohedral Na 3V 2(PO 4) 3 with tiny shrinkage of crystal lattice. X-ray absorption spectra and the calculated crystal structures all suggest that the detailed local structural distortion of substituted materials originates from the slight reduction of V–O distances. Na 3V 2P 3-1/6B 1/6O 12 significantly enhances the structural stability and electrochemical performance, giving remarkable enhanced capacity of 100 and 70 mAh g -1 when the C-rate increases to 5 C and 10 C. Spin-polarized density functional theory (DFT) calculation reveals that, as compared with the pristine Na 3V 2(PO 4) 3, the superior electrochemical performance of the substituted materials can be attributed to the emergence of new boundary states near the band gap, lower Na + diffusion energy barriers, and higher structure stability.« less
Nano sized La2Co2O6 double perovskite synthesized by sol gel method

NASA Astrophysics Data System (ADS)

Solanki, Neha; Lodhi, Pavitra Devi; Choudhary, K. K.; Kaurav, Netram

2018-05-01

We report here the synthesis of double perovskite La2Co2O6 (LCO) compound by a sol gel route method. The double perovskite structure of LCO system was confirmed via X-ray diffraction (XRD) analysis. Further, the lattice parameter, unit cell volume and bond length were refined by means of rietveld analysis using the full proof software. Debye Scherer formula was used to determine the particle size. The compound crystallized in triclinic structure with space group P-1 in ambient condition. We also obtained Raman modes from XRD spectra of poly-crystalline LCO sample. These results were interpreted for the observation of phonon excitations in this compound.
Comment on "Parametric Instability Induced by X-Mode Wave Heating at EISCAT" by Wang et al. (2016)

NASA Astrophysics Data System (ADS)

Blagoveshchenskaya, N. F.; Borisova, T. D.; Yeoman, T. K.

2017-12-01

In their recent article Wang et al. (2016) analyzed observations from EISCAT (European Incoherent Scatter) Scientific Association Russian X-mode heating experiments and claimed to explain the potential mechanisms for the parametric decay instability (PDI) and oscillating two-stream instability (OTSI). Wang et al. (2016) claim that they cannot separate the HF-enhanced plasma and ion lines excited by O or X mode in the EISCAT UHF radar spectra. Because of this they distinguished the parametric instability excited by O-/X-mode heating waves according to their different excitation heights. Their reflection heights were determined from ionosonde records, which provide a rough measure of excitation altitudes and cannot be used for the separation of the O- and X-mode effects. The serious limitation in their analysis is the use of a 30 s integration time of the UHF radar data. There are also serious disagreements between their analysis and the real observational facts. The fact is that it is the radical difference in the behavior of the X- and O-mode plasma and ion line spectra derived with a 5 s resolution, which provides the correct separation of the X- and O-mode effects. It is not discussed and explained how the parallel component of the electric field under X-mode heating is generated. Apart from the leakage to the O mode, results by Wang et al. (2016) do not explain the potential mechanisms for PDI and OTSI and add nothing to understanding the physical factors accounting for the parametric instability generated by an X-mode HF pump wave.
Forming short-period Wolf-Rayet X-ray binaries and double black holes through stable mass transfer

NASA Astrophysics Data System (ADS)

van den Heuvel, E. P. J.; Portegies Zwart, S. F.; de Mink, S. E.

2017-11-01

We show that black hole high-mass X-ray binaries (HMXBs) with O- or B-type donor stars and relatively short orbital periods, of order one week to several months may survive spiral-in, to then form Wolf-Rayet (WR) X-ray binaries with orbital periods of order a day to a few days; while in systems where the compact star is a neutron star, HMXBs with these orbital periods never survive spiral-in. We therefore predict that WR X-ray binaries can only harbour black holes. The reason why black hole HMXBs with these orbital periods may survive spiral-in is: the combination of a radiative envelope of the donor star and a high mass of the compact star. In this case, when the donor begins to overflow its Roche lobe, the systems are able to spiral in slowly with stable Roche lobe overflow, as is shown by the system SS433. In this case, the transferred mass is ejected from the vicinity of the compact star (so-called isotropic re-emission mass-loss mode, or SS433-like mass-loss), leading to gradual spiral-in. If the mass ratio of donor and black hole is ≳3.5, these systems will go into common-envelope evolution and are less likely to survive. If they survive, they produce WR X-ray binaries with orbital periods of a few hours to one day. Several of the well-known WR+O binaries in our Galaxy and the Magellanic Clouds, with orbital periods in the range between a week and several months, are expected to evolve into close WR-black hole binaries, which may later produce close double black holes. The galactic formation rate of double black holes resulting from such systems is still uncertain, as it depends on several poorly known factors in this evolutionary picture. It might possibly be as high as ˜10-5 yr-1.
Electron density distribution in BaPb{sub 1-x}Sb{sub x}O{sub 3} superconducting oxides studied by double nuclear magnetic resonance methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Piskunov, Yu. V., E-mail: piskunov@imp.uran.ru; Ogloblichev, V. V.; Arapova, I. Yu.

2011-11-15

The effect of charge disorder on the formation of an inhomogeneous state of the electron system in the conduction band in BaPb{sub 1-x}Sb{sub x}O{sub 3} superconducting oxides is investigated experimentally by NMR methods. The NMR spectra of {sup 17}O are measured systematically, and the contributions from {sup 17}O atoms with different cation nearest surroundings are identified. It is found that microscopic regions with an elevated spin density of charge carriers are formed within two coordination spheres near antimony ions. Nuclei of the superconducting phase of the oxide (regions with an elevated antimony concentration) microscopically distributed over the sample are detectedmore » in compounds with x = 0.25 and 0.33. Experiments in which a double resonance signal of the spin echo of {sup 17}O-{sup 207}Pb and {sup 17}O-{sup 121}Sb are measured in the metal phase of BaPb{sub 1-x}Sb{sub x}O{sub 3} oxides are carried out for the first time. The constants of indirect heteronuclear spin-spin {sup 17}O-{sup 207}Pb interaction are determined as functions of the local Knight shift {sub 207}Ks. The estimates of the constants of the indirect interaction between the nuclei of the nearest neighbors (O-Pb and Pb-Pb atoms) and analysis of evolution of the NMR spectra of {sup 17}O upon a change in the antimony concentration are convincing evidence in favor of the development of a microscopically inhomogeneous state of the electron system in the metal phase of BaPb{sub 1-x}Sb{sub x}O{sub 3} oxides.« less
Effects of electron cyclotron current drive on the evolution of double tearing mode

NASA Astrophysics Data System (ADS)

Sun, Guanglan; Dong, Chunying; Duan, Longfang

2015-09-01

The effects of electron cyclotron current drive (ECCD) on the double tearing mode (DTM) in slab geometry are investigated by using two-dimensional compressible magnetohydrodynamics equations. It is found that, mainly, the double tearing mode is suppressed by the emergence of the secondary island, due to the deposition of driven current on the X-point of magnetic island at one rational surface, which forms a new non-complete symmetric magnetic topology structure (defined as a non-complete symmetric structure, NSS). The effects of driven current with different parameters (magnitude, initial time of deposition, duration time, and location of deposition) on the evolution of DTM are analyzed elaborately. The optimal magnitude or optimal deposition duration of driven current is the one which makes the duration of NSS the longest, which depends on the mutual effect between ECCD and the background plasma. Moreover, driven current introduced at the early Sweet-Parker phase has the best suppression effect; and the optimal moment also exists, depending on the duration of the NSS. Finally, the effects varied by the driven current disposition location are studied. It is verified that the favorable location of driven current is the X-point which is completely different from the result of single tearing mode.
Crystal structures of the double perovskites Ba{sub 2}Sr{sub 1-} {sub x} Ca {sub x} WO{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fu, W.T.; Akerboom, S.; IJdo, D.J.W.

2007-05-15

Structures of the double perovskites Ba{sub 2}Sr{sub 1-} {sub x} Ca {sub x} WO{sub 6} have been studied by the profile analysis of X-ray diffraction data. The end members, Ba{sub 2}SrWO{sub 6} and Ba{sub 2}CaWO{sub 6}, have the space group I2/m (tilt system a {sup 0} b {sup -} b {sup -}) and Fm3-barm (tilt system a {sup 0} a {sup 0} a {sup 0}), respectively. By increasing the Ca concentration, the monoclinic structure transforms to the cubic one via the rhombohedral R3-bar phase (tilt system a {sup -} a {sup -} a {sup -}) instead of the tetragonal I4/mmore » phase (tilt system a {sup 0} a {sup 0} c {sup -}). This observation supports the idea that the rhombohedral structure is favoured by increasing the covalency of the octahedral cations in Ba{sub 2} MM'O{sub 6}-type double perovskites, and disagrees with a recent proposal that the formation of the {pi}-bonding, e.g., d {sup 0}-ion, determines the tetragonal symmetry in preference to the rhombohedral one. - Graphical abstract: Enlarged sections showing the evolution of the basic (222) and (400) reflections in Ba{sub 2}Sr{sub 1-} {sub x} Ca {sub x} WO{sub 6}. Tick marks below are the positions of Bragg's reflections calculated using the space groups I2/m (x=0), R3-bar (x=0.25, 0.5 and 0.75) and Fm3-barm (x=1), respectively.« less
Thermoelectric properties of n-type double substituted SrTiO3 bulk materials.

PubMed

Cui, Yanjie; He, Jian; Amow, Gisele; Kleinke, Holger

2010-01-28

A series of La, Ta double substituted Sr(1-x)La(x)Ti(1-x)Ta(x)O(3), with x = 0.01, 0.05 and 0.10, and La, Nb double substituted Sr(0.90)La(0.10)Ti(0.90)Nb(0.10)O(3) for comparison were investigated in this project. Rietveld refinements were performed to check for purity and symmetry reduction. Electronic structure calculations indicate n-type conduction with steep and flat bands in the vicinity of the Fermi level for x = 0.125. Seebeck coefficient, electrical conductivity, and thermal conductivity measurements on hot-pressed and spark-plasma-sintered samples were performed over a wide range of temperatures. Best results were obtained by spark-plasma-sintering of double substituted Sr(0.99)La(0.01)Ti(0.99)Ta(0.01)O(3) with a thermoelectric figure-of-merit of 0.13 at 660 K.
Single-Arm Double-Mode Double-Order Planar Waveguide Interferometric Sensor

NASA Technical Reports Server (NTRS)

Sarkisov, Sergey S.

2000-01-01

We have met the goals stated in section one for the project. We have demonstrated the feasibility of a single-arm double-mode double-order waveguide interferometer as a cost efficient alternative to an optical chemical sensor. Experimental prototype was built as a dye-doped polymer waveguide with propagating modes of orders <<0>> and <<1>> of the same TM polarization. The prototype demonstrated sensitivity to ammonia of the order of 200 ppm per one full oscillation of the signal. Sensor based on polyimide doped with BCP can operate at elevated temperature up to 150 C. Upon the future funding, we are planning to optimize the light source, material and the design in order to achieve sensitivity of the order of 1 ppm per full oscillations.
A hybrid electro-optic polymer and TiO2 double-slot waveguide modulator

PubMed Central

Qiu, Feng; Spring, Andrew M.; Maeda, Daisuke; Ozawa, Masa-aki; Odoi, Keisuke; Otomo, Akira; Aoki, Isao; Yokoyama, Shiyoshi

2015-01-01

An electro-optic (EO) modulator using a TiO2 slot hybrid waveguide has been designed and fabricated. Optical mode calculations revealed that the mode was primarily confined within the slots when using a double-slot configuration, thus achieving a high EO activity experimentally. The TiO2 slots also acted as an important barrier to induce an enhanced DC field during the poling of the EO polymer and the driving of the EO modulator. The hybrid phase modulator exhibited a driving voltage (Vπ) of 1.6 V at 1550 nm, which can be further reduced to 0.8 V in a 1 cm-long push-pull Mach–Zehnder interferometer (MZI) structure. The modulator demonstrated a low propagation loss of 5 dB/cm and a relatively high end-fire coupling efficiency. PMID:25708425
Comparison of the effects induced by the ordinary (O-mode) and extraordinary (X-mode) polarized powerful HF radio waves in the high-latitude ionospheric F region

NASA Astrophysics Data System (ADS)

Blagoveshchenskaya, N. F.; Borisova, T. D.; Kalishin, A. S.; Kayatkin, V. N.; Yeoman, T. K.; Häggström, I.

2018-01-01

Using the results of coordinated experiments on the modification of the high-latitude ionosphere by powerful HF radio emission of the EISCAT/Heating facility, effects of the impact of powerful HF radio waves of the ordinary (O-mode) and extraordinary (X-mode) polarization on the high-latitude ionospheric F region have been compared. During the experiments, a powerful HF radio wave was emitted in the magnetic zenith direction at frequencies within the 4.5-7.9 MHz range. The effective power of the emission was 150-650 MW. The behavior and characteristics of small-scale artificial ionospheric irregularities (SAIIs) during O- and X-heating at low and high frequencies are considered in detail. A principal difference has been found in the development of the Langmuir and ion-acoustic turbulence (intensified by the heating of the plasma and ion-acoustic lines in the spectrum of the EISCAT radar of incoherent scatter of radio waves) in the O- and X-heating cycles after switching on the heating facility. It has been shown that, under the influence on the ionospheric plasma of a powerful HF radio wave of the X-polarization, intense spectral components in the spectrum of the narrow-band artificial ionospheric radio emission (ARI) were registered at distances on the order of 1200 km from the heating facility.
X-Ray Absorption Measured in the Resonant Auger Scattering Mode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hikosaka, Y.; Shigemasa, E.; Kaneyasu, T.

2008-08-15

We report both experimental and theoretical studies on x-ray absorption measured in the resonant Auger scattering mode of gas phase carbon monoxide near the O1s{yields}2{pi} region. Both experiment and theory display a crucial difference between the x-ray absorption profiles obtained in the conventional and resonant scattering modes. Lifetime vibrational interference is the main source of the difference. It is demonstrated that such interference, which arises from a coherent excitation to overlapping intermediate levels, ruins the idea for obtaining x-ray absorption spectra in a lifetime broadening free regime.
Structure evolution upon chemical and physical pressure in (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tiittanen, T.; Karppinen, M., E-mail: maarit.karppinen@aalto.fi

Here we demonstrate the gradual structural transformation from the monoclinic I2/m to tetragonal I4/m, cubic Fm-3m and hexagonal P6{sub 3}/mmc structure upon the isovalent larger-for-smaller A-site cation substitution in the B-site ordered double-perovskite system (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6}. This is the same transformation sequence previously observed up to Fm-3m upon heating the parent Sr{sub 2}FeSbO{sub 6} phase to high temperatures. High-pressure treatment, on the other hand, transforms the hexagonal P6{sub 3}/mmc structure of the other end member Ba{sub 2}FeSbO{sub 6} back to the cubic Fm-3m structure. Hence we may conclude that chemical pressure, physical pressure and decreasing temperature allmore » work towards the same direction in the (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6} system. Also shown is that with increasing Ba-for-Sr substitution level, i.e. with decreasing chemical pressure effect, the degree-of-order among the B-site cations, Fe and Sb, decreases. - Graphical abstract: In the (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6} double-perovskite system the gradual structural transformation from the monoclinic I2/m to tetragonal I4/m, cubic Fm-3m and hexagonal P6{sub 3}/mmc structure is seen upon the isovalent larger-for-smaller A-site cation substitution. High-pressure treatment under 4 GPa extends stability of the cubic Fm-3m structure within a wider substitution range of x. - Highlights: • Gradual structural transitions upon A-cation substitution in (Sr{sub 1−x}Ba{sub x}){sub 2}FeSbO{sub 6.} • With increasing x structure changes from I2/m to I4/m, Fm-3m and P6{sub 3}/mmc. • Degree of B-site order decreases with increasing x and A-site cation radius. • High-pressure treatment extends cubic Fm-3m phase stability for wider x range. • High-pressure treatment affects bond lengths mostly around the A-cation.« less
Investigations on the local structures of Cu2+ at various BaO concentrations in 59B2O3-10K2O-(30-x)ZnO-xBaO-1CuO glasses

NASA Astrophysics Data System (ADS)

Jin, Jia-Rui; Wu, Shao-Yi; Hong, Jian; Liu, Shi-Nan; Song, Min-Xian; Teng, Bao-Hua; Wu, Ming-He

2017-11-01

The local structures and electron paramagnetic resonance (EPR) parameters for Cu2+ in 59B2O3-10K2O-(30-x)ZnO-xBaO-1CuO (BKZBC) glasses are theoretically investigated with distinct modifier BaO concentrations x (= 0, 6, 12, 18, 24 and 30 mol %). The ? clusters are found to undergo the relative tetragonal elongations of about 13.5 and 5.0% at zero and higher BaO concentrations. The concentration dependences of the measured d-d transition bands, g factors and A// are suitably reproduced from the Fourier type functions or sign functions of the relevant quantities with x by using only six adjustable parameters. The features of the EPR parameters and the local structures of Cu2+ are analysed in a consistent way by considering the differences in the local ligand field strength and electronic cloud admixtures around Cu2+ under addition of Ba2+ with the highest ionicity and polarisability. The present theoretical studies would be helpful to the researches on the structures, optical and EPR properties for the similar potassium barium zinc borate glasses containing copper with variation concentration of modifier BaO.
Transport, Magnetic, and Memristive Properties of a Nanogranular (CoFeB) x (LiNbO y )100- x Composite Material

NASA Astrophysics Data System (ADS)

Rylkov, V. V.; Nikolaev, S. N.; Demin, V. A.; Emelyanov, A. V.; Sitnikov, A. V.; Nikiruy, K. E.; Levanov, V. A.; Presnyakov, M. Yu.; Taldenkov, A. N.; Vasiliev, A. L.; Chernoglazov, K. Yu.; Vedeneev, A. S.; Kalinin, Yu. E.; Granovsky, A. B.; Tugushev, V. V.; Bugaev, A. S.

2018-03-01

The properties of (CoFeB) x (LiNbO y )100- x nanocomposite films with a ferromagnetic alloy content x = 6-48 at % are comprehensively studied. The films are shown to consist of ensembles of CoFe granules 2-4 nm in size, which are strongly elongated (up to 10-15 nm) in the nanocomposite growth direction and are located in an LiNbO y matrix with a high content of Fe2+ and Co2+ magnetic ions (up to 3 × 1022 cm-3). At T ≤ 25 K, a paramagnetic component of the magnetization of nanocomposites is detected along with a ferromagnetic component, and the contribution of the former component is threefold that of the latter. A hysteresis of the magnetization is observed below the percolation threshold up to x ≈ 33 at %, which indicates the appearance of a superferromagnetic order in the nanocomposites. The temperature dependence of the electrical conductivity of the nanocomposites in the range T ≈ 10-200 K on the metallic side of the metal-insulator transition (44 at % < x < 48 at %) is described by a logarithmic law σ( T) ∝ ln T. This law changes into the law of "1/2" at x ≤ 40 at %. The tunneling anomalous Hall effect is strongly suppressed and the longitudinal conductivity turns out to be lower than in a (CoFeB) x (AlO y )100- x composite material by an order of magnitude. The capacitor structures based on (CoFeB) x (LiNbO y )100- x films exhibit resistive switching effects. They are related to (i) the formation of isolated chains of elongated granules and an anomalously strong decrease in the resistance in fields E > 104 V/cm because of the suppression of Coulomb blockage effects and the generation of oxygen vacancies V O and (ii) the injection (or extraction) of V O vacancies (depending on the sign of voltage) into a strongly oxidized layer in the nanocomposites, which is located near an electrode of the structure and controls its resistance. The number of stable resistive switchings exceeds 105 at a resistance ratio R off/ R on 50.
High-temperature thermoelectric properties of the double-perovskite ruthenium oxide (Sr1-xLax)2ErRuO6

NASA Astrophysics Data System (ADS)

Takahashi, Ryohei; Okazaki, Ryuji; Yasui, Yukio; Terasaki, Ichiro; Sudayama, Takaaki; Nakao, Hironori; Yamasaki, Yuichi; Okamoto, Jun; Murakami, Youichi; Kitajima, Yoshinori

2012-10-01

We have prepared polycrystalline samples of (Sr1-xLax)2ErRuO6 and (Sr1-xLax)2YRuO6, and have measured the resistivity, Seebeck coefficient, thermal conductivity, susceptibility, and x-ray absorption in order to evaluate the electronic states and thermoelectric properties of the doped double-perovskite ruthenates. We have observed a large Seebeck coefficient of -160 μV/K and a low thermal conductivity of 7 mW/cmK for x = 0.1 at 800 K in air. These two values are suitable for efficient oxide thermoelectrics, although the resistivity is still as high as 1 Ω cm. From the susceptibility and x-ray absorption measurements, we find that the doped electrons exist as Ru4+ in the low spin state. On the basis of the measured results, the electronic states and the conduction mechanism are discussed.
Optimized effective potential model for the double perovskites Sr2 - xYxVMoO6 and Sr2 - xYxVTcO6

NASA Astrophysics Data System (ADS)

Solovyev, I. V.

2011-08-01

In an attempt to explore half-metallic properties of the double perovskites Sr2 - xYxVMoO6 and Sr2 - xYxVTcO6, we construct an effective low-energy model, which describes the behavior of the t2g states of these compounds. All parameters of such a model are derived rigorously on the basis of first-principles electronic structure calculations. In order to solve this model, we employ the optimized effective potential method and treat the correlation interactions in the random phase approximation. Although correlation interactions considerably reduce the intraatomic exchange splitting in comparison with the Hartree-Fock approach, this splitting still substantially exceeds the typical values obtained in the local-spin-density approximation (LSDA), which alters many predictions based on the LSDA. Our main results are summarized as follows. (i) All ferromagnetic states are expected to be half-metallic. However, their energies are generally higher than those of the ferrimagnetic ordering between V and Mo/Tc sites (except Sr2VMoO6). (ii) All ferrimagnetic states are metallic (except fully insulating Y2VTcO6) and no half-metallic antiferromagnetism has been found. (iii) Moreover, many of the ferrimagnetic structures appear to be unstable with respect to the spin-spiral alignment. Thus, the true magnetic ground state of these systems is expected to be more complex. In addition, we discuss several methodological issues related to nonuniqueness of the effective potential for the half-metallic and magnetic insulating states.
Tribological Properties of TiO2/SiO2 Double Layer Coatings Deposited on CP-Ti

NASA Astrophysics Data System (ADS)

Çomakli, O.; Yazici, M.; Yetim, T.; Yetim, A. F.; Çelik, A.

In the present paper, the influences of different double layer on wear and scratch performances of commercially pure Titanium (CP-Ti) were investigated. TiO2/SiO2 and SiO2/TiO2 double layer coatings were deposited on CP-Ti by sol-gel dip coating process and calcined at 750∘C. The phase structure, cross-sectional morphology, composition, wear track morphologies, adhesion properties, hardness and roughness of uncoated and coated samples were characterized with X-ray diffraction, scanning electron microscopy (SEM), nano-indentation technique, scratch tester and 3D profilometer. Also, the tribological performances of all samples were investigated by a pin-on-disc tribo-tester against Al2O3 ball. Results showed that hardness, elastic modulus and adhesion resistance of double layer coated samples were higher than untreated CP-Ti. It was found that these properties of TiO2/SiO2 double layer coatings have higher than SiO2/TiO2 double layer coating. Additionally, the lowest friction coefficient and wear rates were obtained from TiO2/SiO2 double layer coatings. Therefore, it was seen that phase structure, hardness and film adhesion are important factors on the tribological properties of double layer coatings.
Structural transformations in (1 -x ) Na0.5Bi0.5TiO3-x BaTiO3 single crystals studied by Raman spectroscopy

NASA Astrophysics Data System (ADS)

de la Flor, G.; Malcherek, T.; Gorfman, S.; Mihailova, B.

2017-12-01

Hard-mode Raman spectroscopy was applied to analyze the temperature-induced transformation processes in perovskite-type (ABO3) single crystals of (1 -x ) Na0.5Bi0.5TiO3-x BaTiO3 (NBT-x BT ) in a wide temperature range between 100 and 1010 K and a composition range of x =0 -0.074 across the morphotropic phase boundary (MPB). The results show abundant uncoupled ferroic structural distortions even at 1010 K and coexistence of two types of mesoscopic-scale ferroic order at lower temperatures. Octahedral BO6 tilting is typical of pure NBT, while the incorporation of A-site Ba2 + suppresses the tilting and promotes the off centering of BO6 octahedra. The temperature evolution of the phonon modes clearly reveals the two macroscopically observed critical temperatures Tm and Td as well as, in the case of x ≠0 , two characteristic temperatures T' and T'' preceding the Tm and Td, respectively, which are attributed to mesoscopic-scale antiferroelectric and ferroelectric coupling processes within the A-site-cation subsystem. At x <xMPB the two sublattices, off-centered A-site cations and off-centered B-site cations, remain incoherent in the entire temperature range. Only when the amount of Ba reaches xMPB the two subsystems couple dynamically, which can explain the enhancement of properties at the MPB. The overall ferroic distortion, however, has a minimum at the MPB, probably because at xMPB the ferroelectric coupling between B-site Ti4 + cations is reduced to a greater extent than the enhancement of ferroelectric coupling between A-site Bi3 + cations.

High-resolution 17O double-rotation NMR characterization of ring and non-ring oxygen in vitreous B2O3.

PubMed

Wong, Alan; Howes, Andy P; Parkinson, Ben; Anupõld, Tiit; Samoson, Ago; Holland, Diane; Dupree, Ray

2009-08-28

The application of double rotation (DOR) NMR to crystalline materials (both inorganic and organic) has made tremendous strides in providing site-specific information about materials in recent years. However (17)O DOR has yet to demonstrate its potential in disordered materials such as glasses. In the present study, we have successfully recorded high resolution (17)O DOR spectra of vitreous B(2)O(3) (v-B(2)O(3)), a highly effective glass-forming oxide of considerable technological importance. Two distinct oxygen sites are resolved and a complete set of (17)O NMR parameters were determined from the DOR spectra. These were assigned to oxygen atoms in the planar boroxol ring [B(3)O(6)] and in the non-boroxol [BO(3)] groups which share oxygen with the ring boron atoms. This assignment was based on the similarity of all of their (17)O parameters with those found by DFT calculation for caesium enneaborate, Cs(2)O.9B(2)O(3), which has two boroxol rings in its structure. The boroxol ring oxygens have a more positive chemical shift, a larger shift anisotropy and a smaller electric field gradient than non ring oxygens (O(R): delta(iso) = 100 +/- 1 ppm, span = 180 +/- 20 ppm, skew = -0.4 +/- 0.1, P(q) = 5.0 +/- 0.2 MHz; O(NR): delta(iso) = 86 +/- 1 ppm, span = 100 +/- 20 ppm, skew = 0.1 +/- 0.1, P(q) = 5.7 +/- 0.2 MHz). The relative proportions of the two sites in v-B(2)O(3) are approximately 1 : 1, as expected if all three boron atoms in the boroxol ring are each connected to one oxygen in a linking [BO(3)] group and there are very few [BO(3)]-[BO(3)] linkages. We see no evidence for a third oxygen site such as has been reported in an earlier study of v-B(2)O(3). This work demonstrates the potential of (17)O DOR to provide site-specific information in disordered materials.
Direct evidence for double-exchange coupling in Ru- substituted La0.7Pb0.3Mn 1 - x Ru x O3, 0.0 <= x <= 0.4

NASA Astrophysics Data System (ADS)

Sundar Manoharan, S.; Sahu, R. K.; Rao, M. L.; Elefant, D.; Schneider, C. M.

2002-08-01

The La0.7Pb0.3Mn 1 - x Ru x O3 (0.0 <= x <= 0.4) system shows an innate relationship between Mn and Ru ions by a unique double-exchange mediated transport behavior. This is exonerated by the coexistence of Tp and Tc (range 330 K 245 K for 0.0 <= x <= 0.4). For Ru > 30%, the hole carrier mass influences the transport property. X-ray absorption spectra suggest that the Tc-Tp match is due to the transport mediated by the Mn3+/Mn4+ leftrightarrow Ru4+/Ru5+ redox pair and also due to the broad low-spin Ru:4d conduction band. For x > 0.2, T < 0.5Tc obeys a modified variable-range hopping model, where kT0 propto (M/Ms)2, suggesting a random magnetic potential which localizes the charge carriers.
Large effects of A-site average cation size on the properties of the double perovskites Ba2-xSrxMnReO6: A d5-d1 system

NASA Astrophysics Data System (ADS)

Popov, Guerman; Greenblatt, Martha; Croft, Mark

2003-01-01

Ba2-xSrxMnReO6 (x=0, 0.5, 1, 2) phases with a double-perovskite structure were prepared by solid-state techniques in evacuated sealed silica tubes. Mn2+ and Re6+ are virtually completely ordered on the B sites. The compounds are ferrimagnetic below 120 K. The maximum saturation moment was obtained for a compound with x=0.5 whose tolerance factor is closest to 1. The whole series of compounds, 0.0⩽x⩽2.0, exhibits semiconducting behavior with variable-range hopping type of conduction. Sr2MnReO6 has an unusually high coercive field (2.6 T at 5 K) and two transitions in the M-H loop. Ba2MnReO6 shows large positive magnetoresistance (14% at 80 K, 5 T) below 140 K, while the other compositions studied exhibit negative magnetoresistance in the temperature range measured.
Investigating the local structure of B-site cations in (1-x)BaTiO3-xBiScO3 and (1-x)PbTiO3-xBiScO3 using X-ray absorption spectroscopy

NASA Astrophysics Data System (ADS)

Blanchard, Peter E. R.; Grosvenor, Andrew P.

2018-05-01

The structural properties of (1-x)BaTiO3-xBiScO3 and (1-x)PbTiO3-xBiScO3 were investigated using powder X-ray diffraction and X-ray absorption spectroscopy. Diffraction measurements confirmed that substituting small amounts of BiScO3 into BaTiO3 initially stabilizes a cubic phase at x = 0.2 before impurity phases begin to form at x = 0.5. BiScO3 substitution also resulted in noticeable changes in the local coordination environment of Ti4+. X-ray absorption near-edge spectroscopy (XANES) analysis showed that replacing Ti4+ with Sc3+ results in an increase in the off-centre displacement of Ti4+ cations. Surprisingly, BiScO3 substitution has no effect on the displacement of the Ti4+ cation in the (1-x)PbTiO3-xBiScO3 solid solution.
Structural, electronic and magnetic properties of the series of double perovskites (Ca , Sr) 2 - xLaxFeIrO6

NASA Astrophysics Data System (ADS)

Bufaiçal, L.; Adriano, C.; Lora-Serrano, R.; Duque, J. G. S.; Mendonça-Ferreira, L.; Rojas-Ayala, C.; Baggio-Saitovitch, E.; Bittar, E. M.; Pagliuso, P. G.

2014-04-01

Polycrystalline samples of the series of double perovskites Sr2-xLaxFeIrO6 were synthesized. Their structural, electronic and magnetic properties were investigated by X-ray powder diffraction, Mössbauer spectroscopy, magnetic susceptibility, heat capacity and electrical resistivity experiments. The compounds crystallize in a monoclinic structure and were fitted in space group P21 / n, with a significant degree of Fe/Ir cationic disorder. As in Ca2-xLaxFeIrO6 the Sr-based system seems to evolve from an antiferromagnetic ground state for the end members (x=0.0 and x=2.0) to a ferrimagnetic order in the intermediate regions (x ~ 1). Since Mössbauer spectra indicate that Fe valence remains 3+ with doping, this tendency of change in the nature of the microscopic interaction could be attributed to Ir valence changes, induced by La3+ electrical doping. Upon comparing both Ca and Sr series, Sr2-xLaxFeIrO6 is more structurally homogenous and presents higher magnetization and transition temperatures. Magnetic susceptibility measurements at high temperatures on Sr1.2La0.8FeIrO6 indicate a very high ferrimagnetic Curie temperature TC ~ 700 K. For the Sr2FeIrO6 compound, electrical resistivity experiments under applied pressure suggest that this material might be a Mott insulator.
Structural and semiconductor-to-metal transitions of double-perovskite cobalt oxide Sr2-xLaxCoTiO6-δ with enhanced thermoelectric capability

NASA Astrophysics Data System (ADS)

Sugahara, Tohru; Ohtaki, Michitaka

2011-08-01

The thermoelectric properties of double-perovskite oxide Sr2-xLaxCoTiO6-δ were revealed to vary anomalously with the La concentration, plausibly due to a structural transition found in this study. Although the temperature dependence of the resistivity and thermopower of the present oxide showed a semiconductor-to-metal transition similar to those observed for other perovskite-related Co oxides such as Sr1-xYxCoO3-δ, the transition temperature was more than 350 K higher, implying considerable stabilization of the low-spin state of Co ions in the double-perovskite oxide. Consequently, the operating temperature range of the oxide for potential thermoelectric applications was significantly expanded toward higher temperatures.
Superconducting antennas for telecommunication applications based on dual mode cross slotted patches

NASA Astrophysics Data System (ADS)

Cassinese, A.; Barra, M.; Fragalà, I.; Kusunoki, M.; Malandrino, G.; Nakagawa, T.; Perdicaro, L. M. S.; Sato, K.; Ohshima, S.; Vaglio, R.

2002-08-01

Dual mode devices based on high temperature superconducting films represent an interesting class for telecommunication applications since they combine a miniaturized size with a good power handling. Here we report on a novel compact antenna obtained by crossing a square patch with two or more slots. The proposed design has an antenna size reduction of about 40% as compared to the conventional square patch microstrip antennas. Single patch antenna both with linear (LP) and circular (CP) polarization operating in the X-band have been designed and tested at prototype level. They are realized by using double sided (YBa 2Cu 3O 7- x) YBCO and Tl 2Ba 2Ca 1Cu 2O 8 (Tl-2212) superconducting films grown on MgO substrates and tested with a portable cryocooler. They showed at T=77 K a return loss <25 dB and a power handling of 23 dBm. Exemplary 16 elements arrays LP antennas operating in the X band have been also realized by using YBCO film grown on 2 ″ diameter MgO substrate.
Legendre polynomial modeling for vibrations of guided Lamb waves modes in [001]c, [011]c and [111]c polarized (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (x = 0.29 and 0.33) piezoelectric plates: Physical phenomenon of multiple intertwining of An and Sn modes

NASA Astrophysics Data System (ADS)

Othmani, Cherif; Takali, Farid; Njeh, Anouar

2017-12-01

Guided wave devices have recently become one of the most important applications in the industry because such waves are directly related to applications in sensor technology, chemical sensing, agricultural science, fields of bio-sensing and surface acoustic wave (SAW) devices that are used in electronic filters and signal processing. On that account, this numerical investigation aims to study the propagation behavior of guided Lamb waves in a (1-x)Pb(Mg1/3Nb2/3)O3- x PbTiO3 [PMN- x PT] ( x=0.29 or 0.33) piezoelectric single crystal plate. In fact, the PMN- xPT ( x=0.29 or 0.33) piezoelectric crystals are being polarized along [001]c, [011]c and [111]c of the cubic reference directions so that the macroscopic symmetries are tetragonal 4 mm, orthogonal mm2 and rhombohedral 3 m, respectively. Both open- and short-circuit conditions are considered. Here, the Legendre polynomial method is proposed to solve the guided Lamb waves equations. The validity of the proposed method is illustrated by comparison with the ordinary differential equation (ODE). The convergence of this method is discussed. Consequently, the converged results are obtained with very low truncation order M . This constitutes a major advantage of the present method when compared with the other matrix methods. There is cross-crossings among multiple modes for both symmetric ( Sn) and the anti-symmetric ( An) guided Lamb waves propagation. A displacement field has been illustrated to judge whether Sn and An modes cross with each other. Moreover, electric displacement, stress field and electric potential for the open-circuit case were presented for both S0 and A0 Lamb modes.
Spectral analysis of Cu 2+: B 2O 3-ZnO-PbO glasses

NASA Astrophysics Data System (ADS)

Lakshminarayana, G.; Buddhudu, S.

2005-11-01

A new series of heavy metal oxide (PbO) based zinc borate glasses in the chemical composition of (95 - x)B 2O 3-5ZnO- xPbO ( x = 10, 15, 20, 25, 30, 35, 40, 45 and 50 mol%) have been prepared to verify their UV filtering performance. Both direct and indirect optical band gaps ( Eopt) have been evaluated for these glasses. For a reference glass of 45B 2O 3-5ZnO-50PbO, refractive indices at different wavelengths are measured and found the results satisfactorily correlated with the theoretical data upon the computation of Cauchy's constants of A = 1.766029949, B = 159531.024 nm 2 and C = -1.078 × 10 10 nm 4. Measurements concerning X-ray diffraction (XRD), FT-IR, differential scanning colorimeter (DSC) profiles have been carried out for this glass. The FT-IR profile has revealed that the glass has both BO 3 and BO 4 units. From DSC thermogram, glass transition temperature ( Tg), crystallization temperature ( Tc) and melting temperature ( Tm) have been located and from them, other related parameters of the glass have also been calculated. Visible absorption spectra of 45B 2O 3-5ZnO-(50 - x)PbO- xCuO ( x = 0. 1, 0.2, 0.5 and 1.0 mol%) have revealed two absorption bands at around 400 nm ( 2B 1g → 2E g) and 780 nm ( 2B 1g → 2B 2g) of Cu 2+ ions, respectively. Emission bands at 422 and 512 nm are found for the 1 mol% CuO doped glass with excitations at 306 and 332 nm.
A Robust Automatic Ionospheric O/X Mode Separation Technique for Vertical Incidence Sounders

NASA Astrophysics Data System (ADS)

Harris, T. J.; Pederick, L. H.

2017-12-01

The sounding of the ionosphere by a vertical incidence sounder (VIS) is the oldest and most common technique for determining the state of the ionosphere. The automatic extraction of relevant ionospheric parameters from the ionogram image, referred to as scaling, is important for the effective utilization of data from large ionospheric sounder networks. Due to the Earth's magnetic field, the ionosphere is birefringent at radio frequencies, so a VIS will typically see two distinct returns for each frequency. For the automatic scaling of ionograms, it is highly desirable to be able to separate the two modes. Defence Science and Technology Group has developed a new VIS solution which is based on direct digital receiver technology and includes an algorithm to separate the O and X modes. This algorithm can provide high-quality separation even in difficult ionospheric conditions. In this paper we describe the algorithm and demonstrate its consistency and reliability in successfully separating 99.4% of the ionograms during a 27 day experimental campaign under sometimes demanding ionospheric conditions.
Single-longitudinal-mode, narrow bandwidth double-ring fiber laser stabilized by an efficiently taper-coupled high roundness microsphere resonator

NASA Astrophysics Data System (ADS)

Wan, Hongdan; Liu, Linqian; Ding, Zuoqin; Wang, Jie; Xiao, Yu; Zhang, Zuxing

2018-06-01

This paper proposes and demonstrates a single-longitudinal-mode, narrow bandwidth fiber laser, using an ultra-high roundness microsphere resonator (MSR) with a stabilized package as the single-longitudinal-mode selector inside a double-ring fiber cavity. By improving the heating technology and surface cleaning process, MSR with high Q factor are obtained. With the optimized coupling condition, light polarization state and fiber taper diameter, we achieve whispering gallery mode (WGM) spectra with a high extinction ratio of 23 dB, coupling efficiency of 99.5%, a 3 dB bandwidth of 1 pm and a side-mode-suppression-ratio of 14.5 dB. The proposed fiber laser produces single-longitudinal-mode laser output with a 20-dB frequency linewidth of about 340 kHz, a signal-to-background ratio of 54 dB and a high long-term stability without mode-hopping, which is potential for optical communication and sensing applications.
Effects of substitution, pressure, and temperature on the phonon mode in layered-rocksalt-type Li{sub (1−x)/2}Ga{sub (1−x)/2}Zn{sub x}O (x = 0.036–0.515) alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tan, Lijie; Hu, Qiwei; Lei, Li, E-mail: lei@scu.edu.cn

2015-11-14

ZnO-based semiconductor alloys, Li{sub (1−x)/2}Ga{sub (1−x)/2}Zn{sub x}O (x = 0.036–0.515) with a layered-rocksalt-type structure, have been prepared under high pressure. The composition, pressure, and temperature dependence of phonons have been studied by Raman spectroscopy. We observe two disorder-activated Raman (DAR) modes when the Zn composition x increases: a broad Raman peak at ca. 400 cm{sup −1} and a left-shoulder peak at ca. 530 cm{sup −1} on the low-frequency side of A{sub 1g} mode at ca. 580 cm{sup −1}, which can be explained by reference to the phonon density of states for rocksalt-type ZnO. With the increase of the pressure and temperature, the left-shoulder DAR modemore » induced by substitution does not change at the same pace with the A{sub 1g} mode at Brillouin-zone center. We find that ion substitution can be seen as a kind of chemical pressure, and the chemical pressure caused by internal substitution and the physical pressure caused by external compression have equivalent effects on the shortening of correlation length, the distortion of crystal lattice, and the change of atomic occupation.« less
Surface modification study of borate materials from B K-edge X-ray absorption spectroscopy

NASA Astrophysics Data System (ADS)

Kasrai, Masoud; Fleet, Michael E.; Muthupari, Swaminathan; Li, D.; Bancroft, G. M.

The B K-edge X-ray absorption near-edge structure (XANES) spectra of two borates with tetrahedrally-coordinated B [[4]B; natural danburite (CaB2Si2O8) and synthetic boron phosphate (BPO4)] have been recorded in total electron yield (TEY) and fluorescence yield (FY) modes to investigate the surface and bulk structure of these materials. The TEY XANES measurement shows that danburite is susceptible to surface damage involving conversion of [4]B sites to [3]B sites by reaction with moisture and/or mechanical abrasion (grinding, polishing, etc.). The bulk of the mineral is essentially unaffected. Commercial boron phosphate powder exhibits more extensive surface and bulk damage, which increases with air exposure but is recovered on heating at 650°C. In contrast to ELNES, the XANES technique is not affected by beam damage and when collected in the FY mode is capable of yielding meaningful information on the coordination and intermediate-range structure of B in borate and borosilicate materials.
Structure, magnetism and electronic properties in 3d-5d based double perovskite ([Formula: see text]Y x )2FeIrO6.

PubMed

Kharkwal, K C; Pramanik, A K

2017-11-13

The 3d-5d based double perovskites are of current interest as they provide model systems to study the interplay between electronic correlation (U) and spin-orbit coupling (SOC). Here, we report detailed structural, magnetic and transport properties of doped double perovskite material ([Formula: see text]Y x ) 2 FeIrO 6 with [Formula: see text]. With substitution of Y, the system retains its original crystal structure but structural parameters change with x in nonmonotonic fashion. The magnetization data for Sr 2 FeIrO 6 show antiferromagnetic type magnetic transition around 45 K; however, a close inspection of the data indicates a weak magnetic phase transition around 120 K. No change of structural symmetry has been observed down to low temperature, although the lattice parameters show sudden changes around the magnetic transitions. Sr 2 FeIrO 6 shows an insulating behavior over the whole temperature range, which nevertheless does not change with Y substitution. The nature of charge conduction is found to follow thermally activated Mott's variable range hopping and power law behavior for parent and doped samples, respectively. Interestingly, evolution of structural, magnetic and transport behavior in ([Formula: see text]Y x ) 2 FeIrO 6 is observed to reverse with [Formula: see text], which is believed to arise due to a change in the transition metal ionic state.
Band offsets and growth mode of molecular beam epitaxy grown MgO (111) on GaN (0002) by x-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Craft, H. S.; Collazo, R.; Losego, M. D.; Mita, S.; Sitar, Z.; Maria, J.-P.

2007-10-01

MgO is a proposed dielectric for use as a tunneling barrier in devices integrating GaN and ferroelectric oxides. In this study, we present data regarding the growth mode and band offsets of MgO grown epitaxially on GaN (0002) surfaces using molecular beam epitaxy. Using in situ x-ray photoelectron spectroscopy (XPS) and molecular beam epitaxy, we determine, from sequential growth experiments, that the growth of MgO proceeds via the Volmer-Weber (three-dimensional) mode, and full coalescence of the film does not occur until approximately 12nm of MgO has been deposited. The observation of a three-dimensional growth mode is in agreement with previously published data. For the valence band offset, we find a value of 1.2±0.2eV, which corresponds to a 3.2eV conduction band offset. XPS measurements suggest a chemically abrupt interface and no effect on band lineup due to the slow coalescence behavior.
Investigations of the local distortions and EPR parameters for Cu2+ in xNa2 O-(30-x)K2 O-70B2 O3 (5 ≤ x ≤ 25 mol%) glasses.

PubMed

Zhang, Zhen-Ya; Wu, Shao-Yi; Zhang, Fu; Zhang, Cheng-Xi; Qin, Rui-Jie; Gao, Han

2018-03-01

The local distortions and electron paramagnetic resonance parameters for Cu 2+ in the mixed alkali borate glasses xNa 2 O-(30-x)K 2 O-70B 2 O 3 (5 ≤ x ≤ 25 mol%) are theoretically studied with distinct modifier Na 2 O compositions x. Owing to the Jahn-Teller effect, the octahedral [CuO 6 ] 10- clusters show significant tetragonal elongation ratios p ~19% along the C 4 axis. With the increase of composition x, the cubic field parameter Dq and the orbital reduction factor k exhibit linearly and quasi-linearly decreasing tendencies, respectively, whereas the relative tetragonal elongation ratio p has quasi-linearly increasing rule with some fluctuations, leading to the minima of g factors at x = 10 mol%. The composition dependences of the optical spectra and the electron paramagnetic resonance parameters are suitably reproduced by the linear or quasi-linear relationships of the relevant quantities (i.e., Dq, k, and p) with x. The above composition dependences are analyzed from mixed alkali effect, which brings forward the modifications of the local crystal-fields and the electronic cloud distribution around Cu 2+ with the variation of the composition of Na 2 O. Copyright © 2017 John Wiley & Sons, Ltd.
Strain-induced tetragonal distortions and multiferroic properties in polycrystalline Sr1 -xB axMn O3 (x =0.43 -0.45 ) perovskites

NASA Astrophysics Data System (ADS)

Somaily, H.; Kolesnik, S.; Mais, J.; Brown, D.; Chapagain, K.; Dabrowski, B.; Chmaissem, O.

2018-05-01

We report the structure-property phase diagram of unique single-ion type-1 multiferroic pseudocubic Sr1 -xB axMn O3 perovskites. Employing a specially designed multistep reduction-oxidation synthesis technique, we have synthesized Sr1 -xB axMn O3 compositions in their polycrystalline form with a significantly extended Ba solubility limit that is only rivaled by a very limited number of crystals and thin films grown under nonequilibrium conditions. Understanding the multiferroic interplay with structure in Sr1 -xB axMn O3 is of great importance as it opens the door wide to the development of newer materials from the parent (A A' ) (B B' ) O3 system with enhanced properties. To this end, using a combination of time-of-flight neutron and synchrotron x-ray scattering techniques, we determined the exact structures and quantified the Mn and oxygen polar distortions above and below the ferroelectric Curie temperature TC and the Néel temperature TN. In its ferroelectric state, the system crystalizes in the noncentrosymmetric tetragonal P 4 m m space group, which gives rise to a large electric dipole moment Ps, in the z direction, of 18.4 and 29.5 μ C /c m2 for x =0.43 and 0.45, respectively. The two independently driven ferroelectric and magnetic order parameters are single-handedly accommodated by the Mn sublattice leading to a novel strain-assisted multiferroic behavior in agreement with many theoretical predictions. Our neutron diffraction results demonstrate the large and tunable suppression of the ferroelectric order at the onset of AFM ordering and confirm the coexistence and strong coupling of the two ferroic orders below TN. The refined magnetic moments confirm the strong covalent bonding between Mn and the oxygen anions, which is necessary for stabilizing the ferroelectric phase.
Phase transformation in (0.90- x)Pb(Mg 1/3Nb 2/3)O 3- xPbTiO 3-0.10PbZrO 3 piezoelectric ceramic: X-ray diffraction and Raman investigation

NASA Astrophysics Data System (ADS)

Xia, Zhiguo; Li, Qiang

2007-05-01

Piezoelectric ceramics with compositions of (0.90- x)Pb(Mg 1/3Nb 2/3)O 3- xPbTiO 3-0.10PbZrO 3, x=0.28, 0.31, 0.34, 0.37, 0.40 and 0.43, were prepared using the conventional columbite precursor method, and their structural phase transformation and piezoelectric behaviors near the morphotropic phase boundary (MPB) have been systematically investigated as a function of PbTiO 3 content. X-ray diffraction (XRD) results demonstrate that the structure of the ceramics experiences a gradual transition process from rhombohedral phase to tetragonal phase with the increasing of PbTiO 3 content, and that compositions with x=0.34-0.40 lie in the MPB region of this ternary system. A Raman spectra investigation of the ceramic samples testified to the transformation process of rhombohedral phase to tetragonal phase by comparing the relative intensities of tetragonal E(2TO 1) mode and rhombohedral phase R h mode. The structure information was also correlated to the parabola change of the piezoelectric constant; the maximum piezoelectric constants were obtained near the MPB region.
Comparison of symmetric and asymmetric double quantum well extended-cavity diode lasers for broadband passive mode-locking at 780 nm.

PubMed

Christopher, Heike; Kovalchuk, Evgeny V; Wenzel, Hans; Bugge, Frank; Weyers, Markus; Wicht, Andreas; Peters, Achim; Tränkle, Günther

2017-07-01

We present a compact, mode-locked diode laser system designed to emit a frequency comb in the wavelength range around 780 nm. We compare the mode-locking performance of symmetric and asymmetric double quantum well ridge-waveguide diode laser chips in an extended-cavity diode laser configuration. By reverse biasing a short section of the diode laser chip, passive mode-locking at 3.4 GHz is achieved. Employing an asymmetric double quantum well allows for generation of a mode-locked optical spectrum spanning more than 15 nm (full width at -20 dB) while the symmetric double quantum well device only provides a bandwidth of ∼2.7 nm (full width at -20 dB). Analysis of the RF noise characteristics of the pulse repetition rate shows an RF linewidth of about 7 kHz (full width at half-maximum) and of at most 530 Hz (full width at half-maximum) for the asymmetric and symmetric double quantum well devices, respectively. Investigation of the frequency noise power spectral density at the pulse repetition rate shows a white noise floor of approximately 2100 Hz 2 /Hz and of at most 170 Hz 2 /Hz for the diode laser employing the asymmetric and symmetric double quantum well structures, respectively. The pulse width is less than 10 ps for both devices.
V473 Lyr, a modulated, period-doubled Cepheid, and U TrA, a double-mode Cepheid, observed by MOST

NASA Astrophysics Data System (ADS)

Molnár, L.; Derekas, A.; Szabó, R.; Matthews, J. M.; Cameron, C.; Moffat, A. F. J.; Richardson, N. D.; Csák, B.; Dózsa, Á.; Reed, P.; Szabados, L.; Heathcote, B.; Bohlsen, T.; Cacella, P.; Luckas, P.; Sódor, Á.; Skarka, M.; Szabó, Gy. M.; Plachy, E.; Kovács, J.; Evans, N. R.; Kolenberg, K.; Collins, K. A.; Pepper, J.; Stassun, K. G.; Rodriguez, J. E.; Siverd, R. J.; Henden, A.; Mankiewicz, L.; Żarnecki, A. F.; Cwiek, A.; Sokolowski, M.; Pál, A.; Guenther, D. B.; Kuschnig, R.; Rowe, J.; Rucinski, S. M.; Sasselov, D.; Weiss, W. W.

2017-04-01

Space-based photometric measurements first revealed low-amplitude irregularities in the pulsations of Cepheid stars, but their origins and how commonly they occur remain uncertain. To investigate this phenomenon, we present MOST space telescope photometry of two Cepheids. V473 Lyrae is a second-overtone, strongly modulated Cepheid, while U Trianguli Australis is a Cepheid pulsating simultaneously in the fundamental mode and first overtone. The nearly continuous, high-precision photometry reveals alternations in the amplitudes of cycles in V473 Lyr, the first case of period doubling detected in a classical Cepheid. In U TrA, we tentatively identify one peak as the fX or 0.61-type mode often seen in conjunction with the first radial overtone in Cepheids, but given the short length of the data, we cannot rule out that it is a combination peak instead. Ground-based photometry and spectroscopy were obtained to follow two modulation cycles in V473 Lyr and to better specify its physical parameters. The simultaneous data yield the phase lag parameter (the phase difference between maxima in luminosity and radial velocity) of a second-overtone Cepheid for the first time. We find no evidence for a period change in U TrA or an energy exchange between the fundamental mode and the first overtone during the last 50 yr, contrary to earlier indications. Period doubling in V473 Lyr provides a strong argument that mode interactions do occur in some Cepheids and we may hypothesize that it could be behind the amplitude modulation, as recently proposed for Blazhko RR Lyrae stars.

The A2Πi˜X2Σ+ interaction in CO +: Deperturbation analyses of B- A and A- X bands of 12C 16O +, 13C 16O + and 14C 16O +

NASA Astrophysics Data System (ADS)

Coxon, John A.; Kępa, Ryszard; Piotrowska, Izabela

2010-08-01

The 1-0, 6-0 and 6-1 bands of the A2Πi→X2Σ+ system of 13C 16O + and the 2-0 and 2-1 bands of the A2Πi→X2Σ+ system of 14C 16O + have been recorded at high resolution for the first time. The 0-2 and 5-0 bands of the A → X system of 12C 16O + have also been recorded at higher resolution than in previous work. The spectra were excited in an air-cooled hollow cathode discharge and photographed using a 2-m plane grating spectrograph. The spectral resolution and the Doppler-broadened line widths are both ˜0.12 cm -1, and the experimental measurement precision of resolved lines is ˜0.02 cm -1. The measured line positions, sometimes in combination with literature data on the B2Σ+→A2Πi transition, have been employed in deperturbation analyses of level crossings in the near-degenerate A(0)˜ X(10) and A(5)˜ X(14) interactions in 12C 16O +, the A(1)˜ X(11) and A(6)˜ X(15) interactions in 13C 16O +, and the A(2)˜ X(12) interaction in 14C 16O +. No radial dependence of the electronic perturbation matrix elements HSO( r) and HRE( r) could be detected over the narrow range of r-centroids (1.477-1.501 Å), and the mean values of these parameters are HSO = -49.06(15) cm -1 and HRE = 0.211(2). Using iteratively improved RKR potentials and FC-overlap integrals, the mean HSO and HRE were employed in least-squares analyses of A → X literature data involving A( υ) levels of the three isotopologues that are affected by interactions with one or two distant X( υ∗) levels. The fitted parameters of the A2Πi state ( B υ, A υ, A Dυ, p υ, q υ) exhibit υ-dependences that are much smoother than those employing perturbed parameters determined in previous investigations. In addition, a significant electronic isotope effect has been characterized. The separations Te( A)- Te( X) of the minima of the A and X states of 13C 16O + and 14C 16O + are less than that of 12C 16O + by 0.39 and 0.73 cm -1, respectively. Although Born-Oppenheimer breakdown of this magnitude is
Higgs Mode in the d -Wave Superconductor Bi2Sr2CaCu2O8 +x Driven by an Intense Terahertz Pulse

NASA Astrophysics Data System (ADS)

Katsumi, Kota; Tsuji, Naoto; Hamada, Yuki I.; Matsunaga, Ryusuke; Schneeloch, John; Zhong, Ruidan D.; Gu, Genda D.; Aoki, Hideo; Gallais, Yann; Shimano, Ryo

2018-03-01

We investigate the terahertz (THz)-pulse-driven nonlinear response in the d -wave cuprate superconductor Bi2Sr2CaCu2O8 +x (Bi2212) using a THz pump near-infrared probe scheme in the time domain. We observe an oscillatory behavior of the optical reflectivity that follows the THz electric field squared and is markedly enhanced below Tc . The corresponding third-order nonlinear effect exhibits both A1 g and B1 g symmetry components, which are decomposed from polarization-resolved measurements. A comparison with a BCS calculation of the nonlinear susceptibility indicates that the A1 g component is associated with the Higgs mode of the d -wave order parameter.
Higgs Mode in the d -Wave Superconductor Bi 2 Sr 2 CaCu 2 O 8 + x Driven by an Intense Terahertz Pulse

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katsumi, Kota; Tsuji, Naoto; Hamada, Yuki I.

We investigated the terahertz (THz)-pulse driven nonlinear response in the d-wave cuprate superconductor Bi 2Sr 2CaCu 2O 8+x (Bi2212) using a THz pump near-infrared probe scheme in the time domain. We have observed an oscillatory behavior of the optical reflectivity that follows the THz electric field squared and is strongly enhanced below Tc. The corresponding third-order nonlinear effect exhibits both A 1g and B 1g symmetry components, which are decomposed from polarization-resolved measurements. Comparison with a BCS calculation of the nonlinear susceptibility indicates that the A 1g component is associated with the Higgs mode of the d-wave order parameter.
Higgs Mode in the d -Wave Superconductor Bi 2 Sr 2 CaCu 2 O 8 + x Driven by an Intense Terahertz Pulse

DOE PAGES

Katsumi, Kota; Tsuji, Naoto; Hamada, Yuki I.; ...

2018-03-14

We investigated the terahertz (THz)-pulse driven nonlinear response in the d-wave cuprate superconductor Bi 2Sr 2CaCu 2O 8+x (Bi2212) using a THz pump near-infrared probe scheme in the time domain. We have observed an oscillatory behavior of the optical reflectivity that follows the THz electric field squared and is strongly enhanced below Tc. The corresponding third-order nonlinear effect exhibits both A 1g and B 1g symmetry components, which are decomposed from polarization-resolved measurements. Comparison with a BCS calculation of the nonlinear susceptibility indicates that the A 1g component is associated with the Higgs mode of the d-wave order parameter.
Selection by current compliance of negative and positive bipolar resistive switching behaviour in ZrO2-x /ZrO2 bilayer memory

NASA Astrophysics Data System (ADS)

Huang, Ruomeng; Yan, Xingzhao; Morgan, Katrina A.; Charlton, Martin D. B.; (Kees de Groot, C. H.

2017-05-01

We report here a ZrO2-x /ZrO2-based bilayer resistive switching memory with unique properties that enables the selection of the switching mode by applying different electroforming current compliances. Two opposite polarity modes, positive bipolar and negative bipolar, correspond to the switching in the ZrO2 and ZrO2-x layer, respectively. The ZrO2 layer is proved to be responsible for the negative bipolar mode which is also observed in a ZrO2 single layer device. The oxygen deficient ZrO2-x layer plays the dominant role in the positive bipolar mode, which is exclusive to the bilayer memory. A systematic investigation of the ZrO2-x composition in the bilayer memory suggests that ZrO1.8 layer demonstrates optimum switching performance with low switching voltage, narrow switching voltage distribution and good cycling endurance. An excess of oxygen vacancies, beyond this composition, leads to a deterioration of switching properties. The formation and dissolution of the oxygen vacancy filament model has been proposed to explain both polarity switching behaviours and the improved properties in the bilayer positive bipolar mode are attributed to the confined oxygen vacancy filament size within the ZrO2-x layer.
Effects of B{sub 18}H{sub x}{sup +} and B{sub 18}H{sub x} dimer ion implantations on crystallinity and retained B dose in silicon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawasaki, Yoji; Shibahara, Kentaro; Research Institute for Nanodevice and Bio Systems, Hiroshima University, 1-4-2 Kagamiyama, Higashihiroshima, Hiroshima 739-8527

2012-01-15

The effects of B{sub 18}H{sub x}{sup +} and B{sub 18}H{sub x} dimer ion (B{sub 36}H{sub y}{sup +}) implantations on Si crystallinity and the retained B dose in Si were investigated using B{sub 18}H{sub x} bombardment and compared with the effects of B{sup +} implantation. Crystallinity was estimated for the implantation dose using molecular dynamic simulations (MDSs) and was quantified using the optical thickness obtained from spectroscopic ellipsometry. The authors focused on the crystallinity at a low B dose and compared the amorphized zones predicted by MDS for B{sub 18}H{sub x}{sup +} implantation with those measured using transmission electron microscopy; themore » predicted and measured results were in reasonable agreement. The authors then used their understanding of B{sub 18}H{sub x} bombardment to discuss the process for the generation of larger amorphized zones and thicker amorphized layers, as observed in B{sub 36}H{sub y}{sup +} implantation. The retained B dose and the sputtering were examined with secondary ion mass spectroscopy, focusing on a comparison of the retained B and the sputtering of Si and SiO{sub 2} surfaces. The retained B dose was lower for B{sub 18}H{sub x}{sup +} and B{sub 36}H{sub y}{sup +} implantations, with and without surface SiO{sub 2}, than for B{sup +} implantation, although no sputtering was observed. The reduction of the retained B dose was more severe in the samples with SiO{sub 2}. The origin of the differences between Si and SiO{sub 2} surfaces was considered to be Si melting; this was predicted by the MDSs, and observed indirectly as flat B profiles in the Si region. To examine the effects of both crystallinity and retained B dose on the electrical characteristics, the sheet resistance (R{sub S}) was measured. The R{sub S} for B{sub 18}H{sub x}{sup +} implantation was lower than that for B{sup +} implantation at both B doses studied. Additionally, the B{sub 36}H{sub y}{sup +} implantation under conditions that produced
Topology-optimized silicon photonic wire mode (de)multiplexer

NASA Astrophysics Data System (ADS)

Frellsen, Louise F.; Frandsen, Lars H.; Ding, Yunhong; Elesin, Yuriy; Sigmund, Ole; Yvind, Kresten

2015-02-01

We have designed and for the first time experimentally verified a topology optimized mode (de)multiplexer, which demultiplexes the fundamental and the first order mode of a double mode photonic wire to two separate single mode waveguides (and multiplexes vice versa). The device has a footprint of ~4.4 μm x ~2.8 μm and was fabricated for different design resolutions and design threshold values to verify the robustness of the structure to fabrication tolerances. The multiplexing functionality was confirmed by recording mode profiles using an infrared camera and vertical grating couplers. All structures were experimentally found to maintain functionality throughout a 100 nm wavelength range limited by available laser sources and insertion losses were generally lower than 1.3 dB. The cross talk was around -12 dB and the extinction ratio was measured to be better than 8 dB.
Infrared spectrum of NH4+(H2O): Evidence for mode specific fragmentation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pankewitz, Tobias; Lagutschenkov, Anita; Niedner-schatteburg, Gereon

2007-02-21

The gas phase infrared spectrum (3250 to 3810 cm1) of the singly hydrated ammonium ion, NH4+(H2O), has been recorded by consequence spectroscopy of mass selected and isolated ions. The obtained four bands are assigned to N-H stretching modes and O-H stretching modes, respectively. The observed N-H stretching modes are blueshifted with respect to the corresponding modes of the free NH4+ ion, whereas a redshift is observed with respect to the modes of the free NH3 molecule. The observed O-H stretching modes are redshifted when compared to the free H2O molecule. The asymmetric stretching modes give rise to rotationally resolved perpendicularmore » transitions. The K-type equidistant rotational spacings of 11.1(2) cm1 (NH4+) and 29(3) cm1 (H2O) deviate systematically from the corresponding values of the free molecules, a fact which is rationalized in terms of a symmetric top analysis. The recorded relative band intensities compare favorably with predictions of high level ab initio calculations except for the 3(H2O) band for which the observed value is about 20 times weaker than the calculated one. This long standing puzzle motivated us to examine the a 3(H2O)/1(H2O) intensity ratios from other published action spectra in other cationic complexes. These suggest that the 3(H2O) intensities become smaller the stronger the complexes are bound. The recorded ratios vary, in particular among the data collected from action spectra that were recorded with and without rare gas tagging. The calculated anharmonic coupling constants in NH4+(H2O) further suggested that the coupling of the 3(H2O) and 1(H2O) modes to other cluster modes indeed varies by orders of magnitude. These findings altogether render the picture of a mode specific fragmentation dynamic that modulates band intensities in action spectra with respect to absorption spectra. Additional high-level electronic structure calculations at the coupled-cluster single and double with perturbative treatment of triple
Photoluminescence of A- and B-site Eu{sup 3+}-substituted (Sr{sub x}Ba{sub 1−x}){sub 2}CaW{sub y}Mo{sub 1−y}O{sub 6} phosphors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sletnes, M.; Lindgren, M.; Valmalette, J.C.

The photoluminescence of two series of A- and B-site Eu{sup 3+} substituted (Sr{sub x}Ba{sub 1−x}){sub 2}CaW{sub y}Mo{sub 1−y}O{sub 6} double perovskite phosphor materials, (Sr{sub x}Ba{sub 1−x}){sub 1.96}Eu{sub 0.02}K{sub 0.02}CaW{sub y}Mo{sub 1−y}O{sub 6} and (Sr{sub x}Ba{sub 1−x}){sub 2}Ca{sub 0.96}Eu{sub 0.02}Li{sub 0.02}W{sub y}Mo{sub 1−y}O{sub 6} (x and y=0, 0.25, 0.50, 0.75, and 1), were studied systematically as a function of stoichiometry and crystal structure. The Eu{sup 3+} lattice sites controlled by co-doping with either K or Li were confirmed by Raman spectroscopy. The variation in integrated emission intensity and emission colour over the experimental matrix was examined using statistical tools, and themore » observed trends were rationalized based on the physical and electronic structure of the phosphors. Phosphors with Eu on B-site with maximum Sr content had remarkably higher emission intensities than all other materials, but the emission was more orange than red due to domination of the {sup 5}D{sub 0}–{sup 7}F{sub 1} (595 nm) transition of Eu{sup 3+}. The relative intensities of the {sup 5}D{sub 0}–{sup 7}F{sub 2} (615 nm) and {sup 5}D{sub 0}–{sup 7}F{sub 1} transitions of Eu{sup 3+}, and thus the red-shift of the emission, decreased linearly with increasing Sr content in the A-site Eu-substituted phosphors, and reached a maximum for Sr{sub 1.96}Eu{sub 0.02}K{sub 0.02}CaW{sub 0.25}Mo{sub 0.75}O{sub 6}. A maximum external quantum efficiency of 17% was obtained for the phosphor Sr{sub 2}Ca{sub 0.7}Eu{sub 0.15}Li{sub 0.15}W{sub 0.5}Mo{sub 0.5}O{sub 6} with Eu on B-site. - Highlights: • Systematic study of the photoluminescence of Eu{sup 3+}-doped (Sr{sub x}Ba{sub 1−x}){sub 2}CaW{sub y}Mo{sub 1−y}O{sub 6}. • The Eu{sup 3+} lattice sites were confirmed by Raman spectroscopy. • A large parameter space was investigated using statistical tools. • A maximum external QE of 17% was obtained for Sr{sub 2}Ca{sub 0.7}Eu{sub 0
Magnetic order and electronic structure of 5d 3 double perovskite Sr 2ScOsO 6

DOE PAGES

Taylor, A. E.; Morrow, R.; Singh, D. J.; ...

2015-03-01

The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr 2ScOsO 6 are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from 3.5 to 300 K. Magnetization measurements indicate an antiferromagnetic transition at TN=92 K, one of the highest transition temperatures of any double perovskite hosting only one magnetic ion. Type I antiferromagnetic order is determined by neutron powder diffraction, with an Os moment of only 1.6(1) muB, close to half the spin-only value for a crystal field split 5d electron state with t2g^3 ground state. Densitymore » functional calculations show that this reduction is largely the result of strong Os-O hybridization, with spin-orbit coupling responsible for only a ~0.1 muB reduction in the moment.« less
Strategy for stabilization of the antiferroelectric phase (Pbma) over the metastable ferroelectric phase (P2{sub 1}ma) to establish double loop hysteresis in lead-free (1−x)NaNbO{sub 3}-xSrZrO{sub 3} solid solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, Hanzheng, E-mail: hug17@psu.edu; Randall, Clive A.; Shimizu, Hiroyuki

A new lead-free antiferroelectric solid solution system, (1−x)NaNbO{sub 3}-xSrZrO{sub 3}, was rationalized through noting the crystal chemistry trend, of decreasing the tolerance factor and an increase in the average electronegativity of the system. The SrZrO{sub 3} doping was found to effectively stabilize the antiferroelectric (P) phase in NaNbO{sub 3} without changing its crystal symmetry. Preliminary electron diffraction and polarization measurements were presented which verified the enhanced antiferroelectricity. In view of our recent report of another lead-free antiferroelectric system (1−x)NaNbO{sub 3}-xCaZrO{sub 3} [H. Shimizu et al. “Lead-free antiferroelectric: xCaZrO{sub 3} - (1−x)NaNbO{sub 3} system (0 ≤ x ≤ 0.10),” Dalton Trans.more » (published online)], the present results point to a general strategy of utilizing tolerance factor to develop a broad family of new lead-free antiferroelectrics with double polarization hysteresis loops. We also speculate on a broad family of possible solid solutions that could be identified and tested for this important type of dielectric.« less
Synthesis and morphology of Ba1-xRE2x/3Nb2O6 nanocrystals with tungsten bronze structure in RE2O3-BaO-Nb2O5-B2O3 glasses (RE: Sm, Eu, Gd, Dy, Er)

NASA Astrophysics Data System (ADS)

Ida, H.; Shinozaki, K.; Honma, T.; Oh-ishi, K.; Komatsu, T.

2012-12-01

Ba1-xRE2x/3Nb2O6 nanocrystals with a tetragonal tungsten bronze (TTB) structure are synthesized using a conventional glass crystallization technique in 2.3RE2O3-27.4BaO-34.3Nb2O5-36B2O3 (mol%) (RE=Sm, Eu, Gd, Dy, and Er) glasses. One sharp crystallization peak is observed at ∼670 °C in both powdered and bulk glasses, and the formation of Ba1-xRE2x/3Nb2O6 nanocrystals with unit cell parameters of a∼1.24 nm and c∼0.39 nm was confirmed. It is found from high resolution transmission electron microscope observations that the morphology of Ba1-xRE2x/3Nb2O6 nanocrystals is ellipsoidal. Their average particle size is in the range of 15-60 nm and decreases with decreasing ionic radius of RE3+ being present in the precursor glasses. The optical transparent crystallized glass (bulk) shows the total photoluminescence (PL) quantum yield of 53% in the visible region of Eu3+ ions, suggesting a high potential of Ba1-xRE2x/3Nb2O6 nanocrystals as PL materials.
Atmospheric dayglow diagnostics involving the O2(b-X) Atmospheric band emission: Global Oxygen and Temperature (GOAT) mapping

NASA Astrophysics Data System (ADS)

Slanger, T. G.; Pejaković, D. A.; Kostko, O.; Matsiev, D.; Kalogerakis, K. S.

2017-03-01

The terrestrial dayglow displays prominent emission features from the 0-0 and 1-1 bands of the O2 Atmospheric band system in the 760-780 nm region. We present an analysis of observations in this wavelength region recorded by the Space Shuttle during the Arizona Airglow Experiment. A major conclusion is that the dominant product of O(1D) + O2 energy transfer is O2(b, v = 1), a result that corroborates our previous laboratory studies. Moreover, critical to the interpretation of dayglow is the possible interference by N2 and N2+ bands in the 760-780 nm region, where the single-most important component is the N2 1PG 3-1 band that overlaps with the O2(b-X) 0-0 band. When present, this background must be accounted for to reveal the O2(b-X) 0-0 and 1-1 bands for altitudes at which the O2 and N2/N2+ emissions coincide. Finally, we exploit the very different collisional behavior of the two lowest O2(b) vibrational levels to outline a remote sensing technique that provides information on Atmospheric composition and temperature from space-based observations of the 0-0 and 1-1 O2 atmospheric bands.
New Defective Brannerite-Type Vanadates. I. Synthesis and Study of Mn 1- x- yφ xNa yV 2-2 x-yMo 2 x+yO 6 Solid Solutions

NASA Astrophysics Data System (ADS)

Masłowska, Bogna; Ziółkowski, Jacek

1994-05-01

MnV 2O 6 of the brannerite-type structure (below 540°C) doped with MoO 3 and Na 2O forms isomorphous solid solutions MnNaφ = Mn 1- x-yφ xNa yV 2-2 x-yMo 2 x+ yO 6 (φ cation vacancy in the original Mn position), belonging to the pseudoternary MnV 2O 6-NaVMoO 6-MoO 3 system. Particular cases are MnNa = Mn 1- yNa y V 2- yMo yO 6 ( x = 0), Mnφ = Mn 1- xφ xV 2-2 xMo 2 xO 6 ( y = 0), and Naφ = Na 1- xφ xV 1- xMo 1+ xO 6 ( x + y = 1). MnV 2O 6 and NaVMoO 6 show miscibility in the entire composition range (MnNa). The opposite boundary of MnNaφ passes through the (100 x, 100 y) points (45, 0), (33, 30), and (30, 70). The phase diagram of the pseudobinary MnV 2O 6-NaVMoO 6 system (determined with DTA) shows (i) a narrow double-lens-type solidus-liquidus gap at high values of y , (ii) two peritectic meltings at lower y (yielding the high temperature β-MnNa and Mn 2V 2O 7), and (iii) little area of β-MnNa. Lattice parameters of MnNa (determined with X-ray diffraction) reveal small deviations from Vegard's law. As the ionic radii of both dopants (Na + and Mo 6+) are, respectively, larger than those of mother ions (Mn 2+ and V 5+), the unit cell increases in all directions with rising y along the MnNa series of solid solutions. However, due to the anisotropy of the structure, parameter c is strongly sensitive to Na/Mn substitution, b is ruled by Mo/V, and a is weakly influenced by Mo/V. Close analogy to the behavior of the previously studied MnV 2O 6-LiVMoO 6-MoO 6 system is discussed.
Suppression of the cooperative Jahn-Teller distortion and its effect on the Raman octahedra-rotation modes of TbM n1 -xF exO3

NASA Astrophysics Data System (ADS)

Vilarinho, R.; Passos, D. J.; Queirós, E. C.; Tavares, P. B.; Almeida, A.; Weber, M. C.; Guennou, M.; Kreisel, J.; Moreira, J. Agostinho

2018-04-01

This work reports the changes in structure and lattice dynamics induced by substituting the Jahn-Teller-active M n3 + ion by the Jahn-Teller-inactive F e3 + in TbM n1 -xF exO3 over the full composition range. The structural analysis reveals that the amplitude of the cooperative Jahn-Teller distortion decreases linearly from x =0 (pure TbMn O3 ) to x =0.5 , where it is completely suppressed. We then correlate this evolution with the behavior of the Raman modes across the solid solution. In particular, we show that the Raman modes associated with the rotation of octahedra, whose wave number is commonly considered to scale linearly with the tilt angles in orthorhombic Pnma perovskites, are also sensitive to the amplitude of the Jahn-Teller distortion.
Double-Mode Miniature Cantilever-Type Ultrasonic Motor Using Lead-Free Array-Type Multilayer Piezoelectric Ceramics

NASA Astrophysics Data System (ADS)

Doshida, Yutaka; Kishimoto, Sumiaki; Irieda, Taisei; Tamura, Hideki; Tomikawa, Yoshiro; Hirose, Seiji

2008-05-01

We studied the following to improve the characteristics of the lead-free ultrasonic micromotor. A double-mode miniature cantilever-type ultrasonic motor was fabricated using array-type multilayer piezoelectric ceramics (A-MLPC) of (Sr,Ca)2NaNb5O15 (SCNN) such as lead-free piezoelectric materials, and the electrical driving properties were investigated. The A-MLPC integrated multilayer piezoelectric ceramics (MLPC) arrayed in a 2 ×2 matrix. By using A-MLPC, double-mode bending vibration of the stator vibrator can be realized easily, and the quality factor of the vibrator increased. Furthermore, with the improvement of the piezoelectric properties of the SCNN, the electromechanical coupling coefficient of the vibrator increased. As a result, we succeeded in improving the driving properties of the motor. In particular, the driving voltage of SCNN motor decreased to 1/10 of the previous study, and this motor is similar to Pb(Zr,Ti)O3-Pb(Ni,Nb)O3-Pb(Zn,Nb)O3 (PZT) one in terms of properties by applying 3 times higher voltage than that required for the PZT one. The SCNN motor started to rotate at 0.3 Vp-p and showed such characteristics as revolution speed of 730 rpm, torque of 0.7 µN m, and efficiency of 3.5% at 1.6 Vp-p. It appeared that the SCNN motor was able to rotate by a lithium-ion cell used in the mobile equipment without an amplifier circuit.
Hard X-ray photoelectron spectroscopy of Li{sub x}Ni{sub 1−x}O epitaxial thin films with a high lithium content

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumara, L. S. R., E-mail: KUMARA.Rosantha@nims.go.jp; Yang, Anli; Sakata, Osami, E-mail: SAKATA.Osami@nims.go.jp

2014-07-28

The core-level and valence-band electronic structures of Li{sub x}Ni{sub 1−x}O epitaxial thin films with x = 0, 0.27, and 0.48 were studied by hard X-ray photoelectron spectroscopy. A double peak structure, consisting of a main peak and a shoulder peak, and a satellite structure were observed in the Ni 2p{sub 3/2} core-level spectra. The intensity ratio of the shoulder to main peak in this double peak structure increased with increasing lithium content in Li{sub x}Ni{sub 1−x}O. This lithium doping dependence of the Ni 2p{sub 3/2} core-level spectra was investigated using an extended cluster model, which included the Zhang–Rice (ZR) doubletmore » bound states arising from a competition between O 2p – Ni 3d hybridization and the Ni on-site Coulomb interaction. The results indicated that the change in the intensity ratio in the main peak is because of a reduction in the ZR doublet bound states from lithium substitutions. This strongly suggests that holes compensating Li doping in Li{sub x}Ni{sub 1−x}O are of primarily ZR character.« less
Structural and ferroelectric phase evolution in [KNbO3]1-x[BaNi1/2Nb1/2O3 -δ] x (x =0 ,0.1 )

NASA Astrophysics Data System (ADS)

Hawley, Christopher J.; Wu, Liyan; Xiao, Geoffrey; Grinberg, Ilya; Rappe, Andrew M.; Davies, Peter K.; Spanier, Jonathan E.

2017-08-01

The phase transition evolution for [KNbO3]1-x[BaNi1/2Nb1/2O3 -δ] x(x =0 ,0.1 ) is determined via complementary dielectric permittivity and Raman-scattering measurements. Raman scattering by optical phonons over the range of 100-1000 cm-1 for 83 K modes. Mode behaviors are observed through structural and ferroelectric phases in the solid solution x =0.1 and compared with those for end member x =0 and with the results of temperature-dependent dielectric permittivity. Rigorous peak fitting analyses of spectra collected from the solid solution and end member indicate structural and ferroelectric phase transition temperatures that are close to those for the KNbO3 end member despite the inclusion of 5 atomic % of ferroelectrically inactive Ni cations. Density functional theory calculations were performed in the solid solution and end member using both cation displacement and Berry phase-based methods. Differences in the electronic and polar properties between the solid solution and the end member highlights local and nonlocal characteristics, which are discussed in relation to the experimental data.
The two-photon absorptivity of rotational transitions in the A2 Sigma hyperon + (v prime = O) - X-2 pion (v prime prime = O) gamma band of nitric oxide

NASA Technical Reports Server (NTRS)

Gross, K. P.; Mckenzie, R. L.

1982-01-01

A predominantly single-mode pulsed dye laser system giving a well characterized spatial and temporal output suitable for absolute two-photon absorptivity measurements was used to study the NO gamma(0,0) S11 + R21 (J double prime = 7-1/2) transition. Using a calibrated induced-fluorescence technique, an absorptivity parameter of 2.8 + or - 1.4 x 10 to the minus 51st power cm to the 6th power was obtained. Relative strengths of other rotational transitions in the gamma(0,0) band were also measured and shown to compare well with predicted values in all cases except the O12 (J double prime = 10-1/2) transition.
Frequency-doubled green picosecond laser based on K3B6O10Br nonlinear optical crystal

NASA Astrophysics Data System (ADS)

Meng, Luping; Zhang, Ling; Hou, Zhanyu; Wang, Lirong; Xu, Hui; Shi, Meng; Wang, Lingwu; Yang, Yingying; Qi, Yaoyao; He, Chaojian; Yu, Haijuan; Lin, Xuechun; Su, Fufang; Xia, Mingjun; Li, Rukang

2018-05-01

We report a frequency-doubled green picosecond (ps) laser based on K3B6O10Br (KBB) nonlinear optical crystal with cutting angle of θ = 34.7° and φ = 30°. Through intracavity frequency doubling using a type I phase-matched KBB crystal with dimensions of 4 mm × 4 mm × 13.2 mm, the average output power of 185.00 mW green ps laser was obtained with a repetition rate of 80 MHz and pulse width of 25.0 ps. In addition, we present external frequency doubling using KBB crystal. The average output power of 3.00 W green ps laser was generated with a repetition rate of 10 kHz and pulse width of 38.1 ps, which corresponds to a pulse energy of 0.30 mJ and a peak power 7.89 MW, respectively. The experimental results show that KBB crystal is a promising nonlinear optical material.

Ethanol Sensitivity of Cu1-xSnxO (x = 0.00, 0.03, and 0.05) Nanoflakes

NASA Astrophysics Data System (ADS)

Mariammal, R. N.; Ramachandran, K.

2011-07-01

Cu1-xSnxO (x = 0.00, 0.03, and 0.05) nanoflakes were synthesized by a simple wet chemical method and X-Ray diffraction (XRD) result confirms the monoclinic structure of CuO with no secondary phases due to Sn doping. The scanning electron microscopic images indicate the formation of nanoflakes. The fundamental Raman modes were observed at 273, 318, 610, and 1084 cm-1 for undoped CuO sample and theses modes were slightly shifted towards lower frequency side for Sn-doped samples, which indicates the inclusion of Sn in CuO. In addition, XRD and Raman studies infer the decrease of crystallinity in doped samples, which is reflected in the sensitivity towards ethanol. The ethanol sensitivity (resistivity measurement) increases with ethanol gas concentration and decreases with Sn-doping in CuO nanoflakes.
Two-mode PLC-based mode multi/demultiplexer for mode and wavelength division multiplexed transmission.

PubMed

Hanzawa, Nobutomo; Saitoh, Kuimasa; Sakamoto, Taiji; Matsui, Takashi; Tsujikawa, Kyozo; Koshiba, Masanori; Yamamoto, Fumihiko

2013-11-04

We proposed a PLC-based mode multi/demultiplexer (MUX/DEMUX) with an asymmetric parallel waveguide for mode division multiplexed (MDM) transmission. The mode MUX/DEMUX including a mode conversion function with an asymmetric parallel waveguide can be realized by matching the effective indices of the LP(01) and LP(11) modes of two waveguides. We report the design of a mode MUX/DEMUX that can support C-band WDM-MDM transmission. The fabricated mode MUX/DEMUX realized a low insertion loss of less than 1.3 dB and high a mode extinction ratio that exceeded 15 dB. We used the fabricated mode MUX/DEMUX to achieve a successful 2 mode x 4 wavelength x 10 Gbps transmission over a 9 km two-mode fiber with a penalty of less than 1 dB.
Correlates of mammographic density in B-mode ultrasound and real time elastography.

PubMed

Jud, Sebastian Michael; Häberle, Lothar; Fasching, Peter A; Heusinger, Katharina; Hack, Carolin; Faschingbauer, Florian; Uder, Michael; Wittenberg, Thomas; Wagner, Florian; Meier-Meitinger, Martina; Schulz-Wendtland, Rüdiger; Beckmann, Matthias W; Adamietz, Boris R

2012-07-01

The aim of our study involved the assessment of B-mode imaging and elastography with regard to their ability to predict mammographic density (MD) without X-rays. Women, who underwent routine mammography, were prospectively examined with additional B-mode ultrasound and elastography. MD was assessed quantitatively with a computer-assisted method (Madena). The B-mode and elastography images were assessed by histograms with equally sized gray-level intervals. Regression models were built and cross validated to examine the ability to predict MD. The results of this study showed that B-mode imaging and elastography were able to predict MD. B-mode seemed to give a more accurate prediction. R for B-mode image and elastography were 0.67 and 0.44, respectively. Areas in the B-mode images that correlated with mammographic dense areas were either dark gray or of intermediate gray levels. Concerning elastography only the gray levels that represent extremely stiff tissue correlated positively with MD. In conclusion, ultrasound seems to be able to predict MD. Easy and cheap utilization of regular breast ultrasound machines encourages the use of ultrasound in larger case-control studies to validate this method as a breast cancer risk predictor. Furthermore, the application of ultrasound for breast tissue characterization could enable comprehensive research concerning breast cancer risk and breast density in young and pregnant women.
Axisymmetric oscillation modes of a double droplet system

DOE PAGES

Ramalingam, Santhosh K.; Basaran, Osman A.

2010-11-15

A double droplet system (DDS) consists of a sessile and a pendant drop that are coupled through a liquid filled cylindrical hole in a plate of thickness d. For a small hole radius R, equilibrium shapes of both drops are sections of spheres. While DDSs have a number of applications in microfluidics, a DDS oscillating about its equilibrium state can be used as a fast focusing liquid lens. Here, a DDS consisting of an isothermal, incompressible Newtonian fluid of constant density p and constant viscosity u that is surrounded by a gas is excited by oscillating in time (a) themore » pressure in the gas surrounding either drop (pressure excitation), (b) the plate perpendicular to its plane (axial excitation), and (c) the hole radius (radial excitation). In contrast to previous works that assumed transient drop shapes are spherical, they are determined here by simulation and used to identify the natural modes of axisymmetric oscillations from resonances observed during frequency sweeps with DDSs for which the combined volume V of the two drops is less than (4/3)πR 3. Pressure and axial excitations are found to have identical responses but axial and radial excitations are shown to excite different modes. These modes are compared to those exhibited by single pendant (sessile) drop systems. Specifically, while a single pendant (sessile) drop has one additional oscillation mode compared to a free drop, a DDS is found to exhibit roughly twice as many oscillation modes as a pendant (sessile) drop. The effects of dimensionless volume V/R 3, dimensionless plate thickness d/R, and Ohnesorge number Oh =μ/√ρRσ , where σ is the surface tension of the DDS-gas interface, on the resonance frequencies are also investigated.« less
Structure and properties of CdO-B2O3 and CdO-MnO-B2O3 glasses; Criteria of getting the fraction of four coordinated boron atoms from infrared spectra

NASA Astrophysics Data System (ADS)

Doweidar, H.; El-Damrawi, G.; El-Stohy, Sh.

2017-11-01

IR spectra of CdO-B2O3 and xCdO·(50 - x)MnO·50B2O3 glasses (0 ≤ x ≤ 50 mol%) have been analyzed. The fraction N4 of four coordinated boron atoms obtained from the integrated area under the IR spectra of CdO-B2O3 glasses is markedly higher than the reported NMR values. In both cases, N4 does not change with CdO content. The difference between N4 values of both techniques has been correlated with the relative absorption coefficient of BO4 unit with respect to BO3 unit, as suggested by Chryssikos et al. N4 data of xCdO·(50 - x)MnO·50B2O3 glasses could be used to calculate the fraction of modifier and former CdO and MnO in the borate matrix, as a function of composition. There is a linear increase in both the density and molar volume with increasing CdO content. The change has been correlated with the contribution of CdO and MnO. Electric conduction is assumed to take place via hopping of small polarons. There is a decrease in conductivity with increasing CdO concentration, which suggests that the electrons related to Cd sites are more localized than those at Mn sites.
Monoclinic distortion and magnetic coupling in the double perovskite Sr{sub 2−x}Ca{sub x}YRuO{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernardo, P.L.; Ghivelder, L.; Eslava, G.G.

2014-12-15

Abstracts: This work investigates in the insulating double perovskites Sr{sub 2−x}Ca{sub x}YRuO{sub 6}. We address the angular dependence of the strength of the magnetic coupling due to the deviation from planarity of the basal layers of the monoclinic structure, characterized by the in-plane angle α<180°, in order to probe the impact of the structural distortions in the magnetic properties of the compounds. High resolution x-ray powder diffraction, susceptibility, and specific heat measurements were performed. The deviation from planarity significantly increases (α=144° for x=1) while the bond distances vary in a complex way as a consequence of the strong monoclinic distortion.more » We found that the magnetic transition temperature, T{sub M}, shows a linear dependence on cos [(π−α)/2]. This result is discussed in terms of t{sub 2g}(π)–e{sub g}(σ) mixing of the magnetic orbitals of the Ru{sup 5+} ions and unbalanced competitive super-exchange interactions. The deleterious effect of Ca doping for the magnetic coupling is confirmed by the reduction in the short-range antiferromagnetic correlations characteristic of the parent compound at T>>T{sub M} and the enhancement of magnetic frustration for T« less
The Crystal Structure and Magnetic Behavior of Quinary Osmate and Ruthenate Double Perovskites La ABB'O 6 ( A = Ca, Sr; B = Co, Ni; B' = Ru, Os)

DOE PAGES

Morrow, Ryan; McGuire, Michael A.; Yan, Jiaqiang; ...

2018-02-23

In this work, six LaABB'O 6 (A = Ca, Sr; B = Co, Ni; B' = Ru, Os) double perovskites were synthesized, several for the first time, and their crystal structures and magnetic behavior were characterized with neutron powder diffraction and direct-current and alternating-current magnetometry. All six compounds crystallize with P2 1/n space group symmetry, resulting from a –a –c + octahedral tilting and complete rock salt ordering of transition-metal ions. Despite the electronic configurations of the transition-metal ions, either d 8–d 3 or d 7–d 3, not one of the six compounds shows ferromagnetism as predicted by the Goodenough–Kanamorimore » rules. LaSrNiOsO 6, LaSrNiRuO 6, and LaCaNiRuO 6 display long-range antiferromagnetic order, while LaCaNiOsO 6, LaCaCoOsO 6, and LaSrCoOsO 6 exhibit spin-glass behavior. These compounds are compared to the previously studied LaCaCoRuO 6 and LaSrCoRuO 6, both of which order antiferromagnetically. Lastly, the observed variations in magnetic properties can be attributed largely to the response of competing superexchange pathways due to changes in B–O–B' bond angles, differences in the radial extent of the 4d (B' = Ru) and 5d (B' = Os) orbitals, and filling of the t 2g orbitals of the 3d ion.« less
The Crystal Structure and Magnetic Behavior of Quinary Osmate and Ruthenate Double Perovskites La ABB'O 6 ( A = Ca, Sr; B = Co, Ni; B' = Ru, Os)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morrow, Ryan; McGuire, Michael A.; Yan, Jiaqiang

In this work, six LaABB'O 6 (A = Ca, Sr; B = Co, Ni; B' = Ru, Os) double perovskites were synthesized, several for the first time, and their crystal structures and magnetic behavior were characterized with neutron powder diffraction and direct-current and alternating-current magnetometry. All six compounds crystallize with P2 1/n space group symmetry, resulting from a –a –c + octahedral tilting and complete rock salt ordering of transition-metal ions. Despite the electronic configurations of the transition-metal ions, either d 8–d 3 or d 7–d 3, not one of the six compounds shows ferromagnetism as predicted by the Goodenough–Kanamorimore » rules. LaSrNiOsO 6, LaSrNiRuO 6, and LaCaNiRuO 6 display long-range antiferromagnetic order, while LaCaNiOsO 6, LaCaCoOsO 6, and LaSrCoOsO 6 exhibit spin-glass behavior. These compounds are compared to the previously studied LaCaCoRuO 6 and LaSrCoRuO 6, both of which order antiferromagnetically. Lastly, the observed variations in magnetic properties can be attributed largely to the response of competing superexchange pathways due to changes in B–O–B' bond angles, differences in the radial extent of the 4d (B' = Ru) and 5d (B' = Os) orbitals, and filling of the t 2g orbitals of the 3d ion.« less
Effects of resonant magnetic perturbation on the triggering and the evolution of double-tearing mode

NASA Astrophysics Data System (ADS)

Wang, L.; Lin, W. B.; Wang, X. Q.

2018-02-01

The effects of resonant magnetic perturbation on the triggering and the evolution of the double-tearing mode are investigated by using nonlinear magnetohydrodynamics simulations in a slab geometry. It is found that the double-tearing mode can be destabilized by boundary magnetic perturbation. Moreover, the mode has three typical development stages before it reaches saturation: the linear stable stage, the linear-growth stage, and the exponential-growth stage. The onset and growth of the double-tearing mode significantly depend on the boundary magnetic perturbations, particularly in the early development stage of the mode. The influences of the magnetic perturbation amplitude on the mode for different separations of the two rational surfaces are also discussed.
High-Pressure, High-Temperature Equations of State Using Fabricated Controlled-Geometry Ni/SiO2 Double Hot-Plate Samples

NASA Astrophysics Data System (ADS)

Pigott, J. S.; Ditmer, D. A.; Fischer, R. A.; Reaman, D. M.; Davis, R. J.; Panero, W. R.

2014-12-01

To model and predict the structure, dynamics, and composition of Earth's deep interior, accurate and precise measurements of thermal expansion and compressibility are required. The laser-heated diamond-anvil cell (LHDAC) coupled with synchrotron-based x-ray diffraction (XRD) is a powerful tool to determine pressure-volume-temperature (P-V-T) relationships. However, LHDAC experiments may be hampered by non-uniform heating caused by the mixing of transparent materials with opaque laser absorbers. Additionally, radial temperature gradients are exacerbated by small misalignments (1-3 µm) of the x-ray beam with respect to the center of the laser-heated hotspot. We have fabricated three-dimensional, controlled-geometry, double hot-plate samples. In this double hot-plate arrangement, a transparent oxide layer (SiO2) is sandwiched between two laser absorbing layers (Ni) in a single, cohesive sample. These samples were mass manufactured (>105 samples) using a combination of physical vapor deposition, photolithography, wet etching, and plasma etching. The double hot-plate arrangement coupled with the chemical and spatial homogeneity of the laser absorbing layers addresses problems caused by mixtures of transparent and opaque samples. The controlled-geometry samples have dimensions of 50 μm x 50 μm x 1.4 μm. The dimensions of the samples are much larger than the synchrotron x-ray beam. With a heating laser FWHM of ~50 μm, the radial temperature gradients within the volume probed by the x-ray are reduced. We conducted XRD experiments to P > 50 GPa and T > 2200 K at beamline 16-ID-B (HPCAT) of the Advanced Photon Source. Here we present relevant thermal modeling of the LHDAC environment along with Ni and SiO2 P-V-T equations of state. Our photolithography method of sample fabrication can be extended to different materials including but not limited to Fe and MgO.
Theoretical Study of the Statistical Properties of Single- and Double-Pass M-Mode Er3+-Ti:LiNbO3 Straight Waveguide Amplifiers

NASA Astrophysics Data System (ADS)

Puscas, Liliana A.; Galatus, Ramona V.; Puscas, Niculae N.

In this article, we report a theoretical study concerning some statistical parameters which characterize the single- and double-pass Er3+-doped Ti:LiNbO3 M-mode straight waveguides. For the derivation and the evaluation of the Fano factor, the statistical fluctuation and the spontaneous emission factor we used a quasi two-level model in the small gain approximation and the unsaturated regime. The simulation results show the evolution of these parameters under various pump regimes and waveguide lengths. The obtained results can be used for the design of complex rare earth-doped integrated circuits.
An evaluation of the rate of absorption of solar radiation in the O2(X3Sigma-g - b1Sigma-g) transition

NASA Technical Reports Server (NTRS)

Mlynczak, Martin G.

1993-01-01

The rate at which molecular oxygen absorbs radiation in the O2(X3Sigma-g - b1Sigma-g) transition is calculated using a line-by-line radiative transfer model. This rate is critical to the determination of the population of the O2(b1Sigma-g) state required for studies of the O2(b1Sigma-g - X3Sigma-g) dayglow, the O2(a1Delta-g - X3Sigma-g) dayglow, and possibly the rates of oxidation of H2 and N2O. Previous evaluations of this rate (which is sometimes called the g-factor) have significantly overestimated its value. The rate is tabulated as a function of altitude, pressure, and solar zenith angle.
Lead-free piezoelectric (K,Na)NbO3-based ceramic with planar-mode coupling coefficient comparable to that of conventional lead zirconate titanate

NASA Astrophysics Data System (ADS)

Ohbayashi, Kazushige; Matsuoka, Takayuki; Kitamura, Kazuaki; Yamada, Hideto; Hishida, Tomoko; Yamazaki, Masato

2017-06-01

We developed a (K,Na)NbO3-based lead-free piezoelectric ceramic with a KTiNbO5 system, (K1- x Na x )0.86Ca0.04Li0.02Nb0.85O3-δ-K0.85Ti0.85Nb1.15O5-BaZrO3-Fe2O3-MgO (K1- x N x N-NTK-FM). K1- x N x N-NTK-FM ceramic exhibits a very dense microstructure and a coupling coefficient of k p = 0.59, which is almost comparable to that of conventional lead zirconate titanate (PZT). The (K,Na)NbO3-based ceramic has the Γ15 mode for a wide x range. The nanodomains of orthorhombic (K,Na)NbO3 with the M3 mode coexist within the tetragonal Γ15 mode (K,Na)NbO3 matrix. Successive phase transition cannot occur with increasing x. The maximum k p is observed at approximately the minimum x required to generate the M3 mode phase. Unlike the behavior at the morphotropic phase boundary (MPB) in PZT, the characteristics of K1- x N x N-NTK-FM ceramic in this region changed moderately. This gentle phase transition seems to be a relaxor, although the diffuseness degree is not in line with this hypothesis. Furthermore, piezoelectric properties change from “soft” to “hard” upon the M3 mode phase aggregation.
Sliding Mode Control of the X-33 Vehicle in Launch Mode

NASA Technical Reports Server (NTRS)

Shtessel, Yuri; Jackson, Mark; Hall, Charles; Krupp, Don; Hendrix, N. Douglas

1998-01-01

The "nested" structure of the control system for the X33 vehicle in launch mode is developed. Employing backstopping concepts, the outer loop (guidance) and the Inner loop (rates) continuous sliding mode controllers are designed. Simulations of the 3-DOF model of the X33 launch vehicle showed an accurate, robust, de-coupled tracking performance.
Ion irradiation-induced easy-cone anisotropy in double-MgO free layers for perpendicular magnetic tunnel junctions

NASA Astrophysics Data System (ADS)

Teixeira, B. M. S.; Timopheev, A. A.; Caçoilo, N. F. F.; Auffret, S.; Sousa, R. C.; Dieny, B.; Alves, E.; Sobolev, N. A.

2018-05-01

We have used the ferromagnetic resonance in the X-band (9.37 GHz) to investigate the effect of 400 keV Ar+ irradiation on the perpendicular magnetic anisotropy (PMA) and Gilbert damping parameter, α, of double-MgO free layers designed for application in perpendicular magnetic tunnel junctions. The samples comprised a MgO/Fe72Co8B20/X(0.2 nm)/Fe72Co8B20/MgO layer stack, where X stands for an ultrathin Ta or W spacer. Samples with two different total FeCoB layer thicknesses, tFCB = 3.0 nm and tFCB = 2.6 nm, were irradiated with ion fluences ranging from 1012 cm-2 to 1016 cm-2. The effective first-order PMA field, BK1, decreased nearly linearly with the logarithm of the fluence for both FeCoB thicknesses and spacer elements. The decrease in BK1, which is likely caused by an ion-induced intermixing at the FeCoB/MgO interfaces, resulted in a reorientation of the magnetization of the free layers with tFCB = 2.6 nm, initially exhibiting a perpendicular easy-axis anisotropy. For intermediate fluences, 1013 cm-2 and 1014 cm-2, easy-cone states with different cone angles could be induced in the free layer with a W spacer. Importantly, no corresponding increase in the Gilbert damping was observed. This study shows that ion irradiation can be used to tune the easy-cone anisotropy in perpendicular magnetic tunnel junctions, which is interesting for spintronic applications such as spin-torque magnetic memory devices, oscillators, and sensors.
A double B1-mode 4-layer laminated piezoelectric linear motor.

PubMed

Li, Xiaotian; Chen, Zhijiang; Dong, Shuxiang

2012-12-01

We report a miniature piezoelectric ultrasonic linear motor that is made of four Pb(Zr,Ti)O(3) (PZT) piezoelectric ceramic layers for low-voltage work. The 4-layer piezoelectric laminate works in two orthogonal first-bending modes for producing elliptical oscillations, which are then used to drive a contacting slider into continuous linear motion. Experimental results show that the miniature linear motor (size: 4 × 4 × 12 mm, weight: 1.7 g) can generate a large driving force of 0.48 N and a linear motion speed of up to 160 mm/s, using a 40 V(pp)/mm voltage drive at its resonance frequency of 64.5 kHz. The maximum efficiency of the linear motor is 30%.
Study of dynamics of X-14B VTOL aircraft

NASA Technical Reports Server (NTRS)

Loscutoff, W. V.; Mitchiner, J. L.; Roesener, R. A.; Seevers, J. A.

1973-01-01

Research was initiated to investigate certain facets of modern control theory and their integration with a digital computer to provide a tractable flight control system for a VTOL aircraft. Since the hover mode is the most demanding phase in the operation of a VTOL aircraft, the research efforts were concentrated in this mode of aircraft operation. Research work on three different aspects of the operation of the X-14B VTOL aircraft is discussed. A general theory for optimal, prespecified, closed-loop control is developed. The ultimate goal was optimal decoupling of the modes of the VTOL aircraft to simplify the pilot's task of handling the aircraft. Modern control theory is used to design deterministic state estimators which provide state variables not measured directly, but which are needed for state variable feedback control. The effect of atmospheric turbulence on the X-14B is investigated. A maximum magnitude gust envelope within which the aircraft could operate stably with the available control power is determined.
Analysis of SAW properties in ZnO/AlxGa1-xN/c-Al2O3 structures.

PubMed

Chen, Ying; Emanetoglu, Nuri William; Saraf, Gaurav; Wu, Pan; Lu, Yicheng; Parekh, Aniruddh; Merai, Vinod; Udovich, Eric; Lu, Dong; Lee, Dong S; Armour, Eric A; Pophristic, Milan

2005-07-01

Piezoelectric thin films on high acoustic velocity nonpiezoelectric substrates, such as ZnO, AlN, or GaN deposited on diamond or sapphire substrates, are attractive for high frequency and low-loss surface acoustic wave devices. In this work, ZnO films are deposited on AlxGa1-xN/c-Al2O3 (0 < or = chi < or = 1) substrates using the radio frequency (RF) sputtering technique. In comparison with a single AlxGa1-xN layer deposited on c-Al2O3 with the same total film thickness, a ZnO/AlxGa1-xN/c-Al2O3 multilayer structure provides several advantages, including higher order wave modes with higher velocity and larger electromechanical coupling coefficient (K2). The surface acoustic wave (SAW) velocities and coupling coefficients of the ZnO/AlxGa1-xN/c-Al2O3 structure are tailored as a function of the Al mole percentage in AlxGa1-xN films, and as a function of the ZnO (h1) to AlxGa1-xN (h2) thickness ratio. It is found that a wide thickness-frequency product (hf) region in which coupling is close to its maximum value, K(2)max, can be obtained. The K(2)max of the second order wave mode (h1 = h2) is estimated to be 4.3% for ZnO/GaN/c-Al2O3, and 3.8% for ZnO/AlN/c-Al2O3. The bandwidth of second and third order wave modes, in which the coupling coefficient is within +/- 0.3% of K(2)max, is calculated to be 820 hf for ZnO/GaN/c-Al2O3, and 3620 hf for ZnO/AlN/c-Al2O3. Thus, the hf region in which the coupling coefficient is close to the maximum value broadens with increasing Al content, while K(2)max decreases slightly. When the thickness ratio of AlN to ZnO increases, the K(2)max and hf bandwidth of the second and third higher wave modes increases. The SAW test devices are fabricated and tested. The theoretical and experimental results of velocity dispersion in the ZnO/AlxGa1-xN/c-Al2O3 structures are found to be well matched.
Synthesis and morphology of Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals with tungsten bronze structure in RE{sub 2}O{sub 3}-BaO-Nb{sub 2}O{sub 5}-B{sub 2}O{sub 3} glasses (RE: Sm, Eu, Gd, Dy, Er)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ida, H.; Shinozaki, K.; Honma, T.

2012-12-15

Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals with a tetragonal tungsten bronze (TTB) structure are synthesized using a conventional glass crystallization technique in 2.3RE{sub 2}O{sub 3}-27.4BaO-34.3Nb{sub 2}O{sub 5}-36B{sub 2}O{sub 3} (mol%) (RE=Sm, Eu, Gd, Dy, and Er) glasses. One sharp crystallization peak is observed at {approx}670 Degree-Sign C in both powdered and bulk glasses, and the formation of Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals with unit cell parameters of a{approx}1.24 nm and c{approx}0.39 nm was confirmed. It is found from high resolution transmission electron microscope observations that the morphology of Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals is ellipsoidal. Their average particlemore » size is in the range of 15-60 nm and decreases with decreasing ionic radius of RE{sup 3+} being present in the precursor glasses. The optical transparent crystallized glass (bulk) shows the total photoluminescence (PL) quantum yield of 53% in the visible region of Eu{sup 3+} ions, suggesting a high potential of Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals as PL materials. - Graphical abstract: This figure shows a TEM photograph for the heat-treated (667 Degree-Sign C, 3 h) sample of 2.3Dy{sub 2}O{sub 3}-27.4BaO-34.3Nb{sub 2}O{sub 5}-36B{sub 2}O{sub 3}. An ellipsoidal-shaped Ba{sub 1-x}Dy{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystal with diameters of 17 and 28 nm is observed. The ellipsoidal morphology is a common feature in Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals synthesized by the crystallization of 2.3RE{sub 2}O{sub 3}-27.4BaO-34.3Nb{sub 2}O{sub 5}-36B{sub 2}O{sub 3} glasses. Highlights: Black-Right-Pointing-Pointer Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals with a tetragonal tungsten bronze structure are synthesized. Black-Right-Pointing-Pointer A glass crystallization technique was applied. Black-Right-Pointing-Pointer The morphology of Ba{sub 1-x}RE{sub 2x/3}Nb{sub 2}O{sub 6} nanocrystals
Magnetic ground states in the three O s6 + (5 d2 ) double perovskites B a2M Os O6 (M =Mg ,Zn,and Cd) from Néel order to its suppression

NASA Astrophysics Data System (ADS)

Marjerrison, C. A.; Thompson, C. M.; Sharma, A. Z.; Hallas, A. M.; Wilson, M. N.; Munsie, T. J. S.; Flacau, R.; Wiebe, C. R.; Gaulin, B. D.; Luke, G. M.; Greedan, J. E.

2016-10-01

Three closely related double perovskites (DP) based on the 5 d2 ion, O s6 +,B a2M Os O6 , with M =Mg , Zn, and Cd have been prepared and characterized using x-ray (XRD) and neutron diffraction (ND), dc magnetization, heat capacity, and muon spin relaxation (μ SR ) techniques. All three are cubic, Fm-3 m , at ambient temperature from XRD with Δ d /d ˜5 ×10-4 resolution. For both M =Mg and Zn, ND data at 3.5 K and lower, Δ d /d =2 ×10-3 , resolution show no signs of a distortion. The results are compared with the known DP material, B a2CaOs O6 , which shows antiferromagnetic (AF) order below TN=49 K and a moderate frustration index, f ˜4 , (f =| θCW|/ TN ), where θCW is the Curie-Weiss temperature. B a2MgOs O6 with a unit cell constant a0=8.0757 (1 ) Å , 3% smaller than for B a2CaOs O6 , also shows Néel order below TN=51 K with f ˜2 . However, B a2ZnOs O6,a0=8.0975 (1 ) Å , 0.27% larger than B a2MgOs O6 , does not show Néel order from either heat capacity or μ SR data. A zero field cooled/field cooled (ZFC/FC) irreversibility occurs near 30 K and a broad heat capacity anomaly is detected at a similar temperature. The μ SR data are consistent with a weak spin ordering with an onset below 28 K but with a coexisting dynamic component. B a2CdOs O6 with a0=8.3190 (1 ) Å , 0.5% smaller than B a2CaOs O6 , shows no evidence for any type of order/spin freezing to 0.47 K from any of the measurement techniques applied. The results for M =Zn and Cd appear to lie outside of the mean field theory of Chen and Balents [Phys. Rev. B 84, 094420 (2011), 10.1103/PhysRevB.84.094420] for cubic d2 DP with strong spin orbit coupling, but B a2MgOs O6 , along with B a2CaOs O6 , is likely one of the three predicted AF phases. The remarkable contrast between the doppelgänger pairs M =Mg /Zn and M =Ca /Cd may be traceable to differences in electronic structure of the diamagnetic M ions. All of the super-super exchange pathways in these DP materials involve Os-O-M -O-Os linkages.

Enhanced ferromagnetism, metal-insulator transition, and large magnetoresistance in La1-xCaxMn1-xRuxO3 free of eg-orbital double-exchange

NASA Astrophysics Data System (ADS)

Liu, M. F.; Du, Z. Z.; Liu, H. M.; Li, X.; Yan, Z. B.; Dong, S.; Liu, J.-M.

2014-03-01

The structure, ionic valences, magnetism, and magneto-transport behaviors of mixed valence oxides La1-xCaxMn1-xRuxO3 are systematically investigated. The simultaneous substitutions of La3+ and Mn3+ ions by Ca2+ and Ru4+, respectively, are confirmed by the structural and ionic valence characterizations, excluding the presence of Mn4+ and Ru3+ ions. The enhanced ferromagnetism, induced metal-insulator transition, and remarkable magnetoresistance effect are demonstrated when the substitution level x is lower than ˜0.6, in spite of the absence of the Mn3+-Ru4+ eg-orbital double-exchange. These anomalous magnetotransport effects are discussed based on the competing multifold interactions associated with the Mn3+-Ru4+ super-exchange and strong Ru4+-Ru4+ hopping, while the origins for the metal-insulator transition and magnetoresistance effect remain to be clarified.
Resonant Raman scattering study of BexZn1-xO thin films grown on sapphire by molecular beam epitaxy

NASA Astrophysics Data System (ADS)

Wang, Yu-Chao; Su, Long-Xing; Zhao, Yu; Liu, Jian-Feng; Shen, Zheng-Chuan; Feng, Yu-Hua; Wu, Tian-Zhun; Tang, Zi-Kang

2017-07-01

Resonance Raman spectra of BexZn1-xO alloy materials were studied using 325 nm Laser. The research showed that the Raman spectra of BexZn1-xO alloys presents a dual-mode vibration. Compare BexZn1-xO alloy with ZnO single crystal, the A1 (LO) phonon vibration mode of BexZn1-xO alloy moved to the larger wave number direction. The position of A1 (LO) phonon vibration modes of Be0.08Zn0.92O and Be0.12Zn0.88O was 580 cm-1 and 582 cm-1, respectively. In addition, the temperature-dependent Raman spectroscopy was employed for Be0.12Zn0.88O, and the phonon mode frequency shift with temperature was studied in detail. Finally, the stability of the polar and nonpolar BexZn1-xO alloy materials was studied using resonance Raman spectroscopy. The results showed that the A1 (LO) phonon mode frequency of polar BexZn1-xO alloy remained in the same position, while the nonpolar BexZn1-xO alloys moved nearly 3.5 cm-1 to larger direction after being placed in the air for two years. The reason may be that the stability of the nonpolar BexZn1-xO alloy is relatively poor upon interaction with molecule such as H2O, O2 in the air.
Double-slit interference in H2^, subjected to ultrashort x-ray radiation

NASA Astrophysics Data System (ADS)

Secor, Ethan; Guan, Xiaoxu; Bartschat, Klaus; Schneider, Barry I.

2012-06-01

Extending our earlier work [1], we consider the double-slit interference effect [2,3] in the H2^, ion irradiated by intense short x-ray laser pulses with central photon energies from 200-500 eV. The time-dependent Schr"odinger equation in prolate spheroidal coordinates is solved to extract the angle-differential cross section of the photo-electron. The spatical coordinates are discretized by means of a finite-element discrete-variable representation. We discuss the confinement effect [3] in the parallel geometry, in which the emission mode of the photoelectron along the laser polarization direction is dynamically forbidden. This confinement appears periodically, with the details depending on both the momentum of the electron and the internuclear separation. On the other hand, the effect disappears in the perpendicular geometry. We compare our results to those obtained from a simple plane-wave model based on time-independent perturbation theory.[4pt] [1] X. Guan, E. Secor, K. Bartschat, and B. I. Schneider, Phys. Rev. A 84 (2011) 032420.[0pt] [2] I. G. Kaplan and A. P. Markin, Sov. Phys. Dokl. 14 (1969) 36.[0pt] [3] J. Fern'andez, F. L. Yip, T. N. Rescigno, C. W. McCurdy, and F. Mart'in, Phys. Rev. A 79 (2009) 043409.
Which hadronic decay modes are good for {eta}{sub b} searching: Double J/{psi} or something else?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia Yu

2008-09-01

It has been controversial whether {eta}{sub b} can be discovered in Tevatron Run 2 through the decay {eta}{sub b}{yields}J/{psi}J/{psi} followed by J/{psi}{yields}{mu}{sup +}{mu}{sup -}. I clear this controversy by an explicit calculation which predicts Br[{eta}{sub b}{yields}J/{psi}J/{psi}] to be of order 10{sup -8}. It is concluded that observing {eta}{sub b} through this decay mode in Tevatron Run 2 may be rather unrealistic. The {eta}{sub b} may be observed in the forthcoming CERN LHC experiments through the 4-lepton channel, if the background events can be significantly reduced by imposing some kinematical cuts. By some rough but plausible considerations, I find that themore » analogous decay processes {eta}{sub b}{yields}VV, D*D* also have very suppressed branching ratios; nevertheless it may be worth looking for {eta}{sub b} at LHC and Super B factory through the decay modes {eta}{sub b}{yields}K{sub S}K{sup {+-}}{pi}{sup {+-}}, D*D.« less
Comparison and characterization of efficient frequency doubling at 397.5 nm with PPKTP, LBO and BiBO crystals

NASA Astrophysics Data System (ADS)

Wen, Xin; Han, Yashuai; Wang, Junmin

2016-04-01

A continuous-wave Ti:sapphire laser at 795 nm is frequency doubled in a bow-tie type enhancement four-mirror ring cavity with LiB3O5 (LBO), BiB3O6 (BiBO), and periodically polled KTiOPO4 (PPKTP) crystals, respectively. The properties of 397.5 nm ultra-violet (UV) output power, beam quality, stability for these different nonlinear crystals are investigated and compared. For PPKTP crystal, the highest doubling efficiency of 58.1% is achieved from 191 mW of 795 nm mode-matched fundamental power to 111 mW of 397.5 nm UV output. For LBO crystal, with 1.34 W of mode-matched 795 nm power, 770 mW of 397.5 nm UV output is achieved, implying a doubling efficiency of 57.4%. For BiBO crystal, with 323 mW of mode-matched 795 nm power, 116 mW of 397.5 nm UV output is achieved, leading to a doubling efficiency of 35.9%. The generated UV radiation has potential applications in the fields of quantum physics.
Isotope effects in liquid water probed by transmission mode x-ray absorption spectroscopy at the oxygen K-edge.

PubMed

Schreck, Simon; Wernet, Philippe

2016-09-14

The effects of isotope substitution in liquid water are probed by x-ray absorption spectroscopy at the O K-edge as measured in transmission mode. Confirming earlier x-ray Raman scattering experiments, the D2O spectrum is found to be blue shifted with respect to H2O, and the D2O spectrum to be less broadened. Following the earlier interpretations of UV and x-ray Raman spectra, the shift is related to the difference in ground-state zero-point energies between D2O and H2O, while the difference in broadening is related to the difference in ground-state vibrational zero-point distributions. We demonstrate that the transmission-mode measurements allow for determining the spectral shapes with unprecedented accuracy. Owing in addition to the increased spectral resolution and signal to noise ratio compared to the earlier measurements, the new data enable the stringent determination of blue shift and broadening in the O K-edge x-ray absorption spectrum of liquid water upon isotope substitution. The results are compared to UV absorption data, and it is discussed to which extent they reflect the differences in zero-point energies and vibrational zero-point distributions in the ground-states of the liquids. The influence of the shape of the final-state potential, inclusion of the Franck-Condon structure, and differences between liquid H2O and D2O resulting from different hydrogen-bond environments in the liquids are addressed. The differences between the O K-edge absorption spectra of water from our transmission-mode measurements and from the state-of-the-art x-ray Raman scattering experiments are discussed in addition. The experimentally extracted values of blue shift and broadening are proposed to serve as a test for calculations of ground-state zero-point energies and vibrational zero-point distributions in liquid H2O and D2O. This clearly motivates the need for new calculations of the O K-edge x-ray absorption spectrum of liquid water.
A study of Na(x)Pt3O4 as an O2 electrode bifunctional electrocatalyst

NASA Technical Reports Server (NTRS)

Fielder, William L.; Singer, Joseph

1991-01-01

The present study suggests that polytetrafluoroethylene (PTFE) bonded Na(X)Pt3O4 gas porous diffusion electrodes may be a viable candidate for bifunctional O2 reduction and evolution activity. The electrodes exhibited Tafel slopes of about 0.06 V/decade for both O2 reduction an evolution. For O2 reduction, the 0.06 slope doubled to 0.12 V/decade at larger current densities. Preliminary stability testing at 24 C suggest that the Na(x)Pt3O4 electrodes were relatively stable at reducing and oxidizing potentials typically encountered at the O2 electrodes in a regenerative fuel cell.
Novel Nd 2WO 6-type Sm 2- xA xM 1- yB yO 6- δ (A = Ca, Sr; M = Mo, W; B = Ce, Ni) mixed conductors

NASA Astrophysics Data System (ADS)

Li, Qin; Thangadurai, Venkataraman

In the present work, we have explored novel Nd 2WO 6-type structure Sm 2- xA xM 1- yB yO 6- δ (A = Ca, Sr; M = Mo, W; B = Ce, Ni) as precursor for the development of solid oxide fuel cells (SOFCs) anodes. The formation of single-phase monoclinic structure was confirmed by powder X-ray diffraction (PXRD) for the A- and B-doped Sm 2MO 6 (SMO). Samples after AC measurements under wet H 2 up to 850 °C changed from Nd 2WO 6-type structure into Sm 2MoO 5 due to the reduction of Mo VI that was confirmed by PXRD and is consistent with literature. The electrical conductivity was determined using 2-probe AC impedance and DC method and was compared with 4-probe DC method. The total electrical conductivity obtained from these two different techniques was found to vary within the experimental error over the investigated temperature of 350-650 °C. Ionic and electronic conductivity were studied using electron-blocking electrodes technique. Among the samples studied, Sm 1.8Ca 0.2MoO 6- δ exhibits total conductivity of 0.12 S cm -1 at 550 °C in wet H 2 with an activation energy of 0.06 eV. Ca-doped SMO appears to be chemically stable against reaction with YSZ electrolyte at 800 °C for 24 h in wet H 2. The ionic transference number (t i) of Sm 1.9Ca 0.1MoO 6- δ in wet H 2 at 550 °C (pO 2 = 10 -25.5 atm) was found to be about 0.012 after subtraction of electrical lead resistance from the 2-probe AC data and showed predominate electronic conductors.
Synthesis and crystal structures of new oxyapatites BiCa{sub 4-x}La{sub x}(VO{sub 4}){sub 3-x}(GeO{sub 4}){sub x}O, x=1-3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhuravlev, V.D., E-mail: zhvd@ihim.uran.ru; Tyutyunnik, A.P.; Zubkov, V.G.

2012-10-15

New germanate-vanadates with the general formula BiCa{sub 4-x}La{sub x}(VO{sub 4}){sub 3-x}(GeO{sub 4}){sub x}O, x=1-3, have been synthesized by the nitrate-citrate method and characterized. Structural refinement based on X-ray powder diffraction data showed that these compounds are isostructural with BiCa{sub 4}(VO{sub 4}){sub 3}O (space group P6{sub 3}/m (N 176), Z=2, a=9.8327-9.8755(3), and c=7.1203-7.2133(2) ). They may be viewed as continuous series of solid solutions where Ca{sup 2+} and V{sup 5+} cations in the crystal lattice of vanadate BiCa{sub 4}(VO{sub 4}){sub 3}O are replaced by La{sup 3+} and Ge{sup 4+} cations. In the process of substitution, the La{sup 3+} cations occupy mainlymore » the 4f lattice sites of the germanate-vanadate oxyapatites, but the filling of the 4f and 6h lattice sites in the germanate BiCaLa{sub 3}(GeO{sub 4}){sub 3} is equivalent. IR and Raman spectra were studied. The Raman spectra clearly show a two-mode behavior: the lines of GeO{sub 4} and VO{sub 4} are separated from each other, and the (V/Ge)O{sub 4} tetrahedra exhibit a quasi-independent behavior. - Graphical abstract: Schematic drawing of the BiCa{sub 3}La(VO{sub 4}){sub 2}(GeO{sub 4})O structure in projection on the ac plane. Green-V and Ge, red-Ca(1) and La(1), yellow-Ca(2), La(2) and Bi, dark-blue-O(1)-O(4), blue-O(5). Highlights: Black-Right-Pointing-Pointer The citrate synthesis of germanate-vanadate oxyapatites. Black-Right-Pointing-Pointer The synthesized compounds crystallize in the hexagonal symmetry. Black-Right-Pointing-Pointer A single series of solid solutions BiCa{sub 4-x}La{sub x}(VO{sub 4}){sub 3-x}(GeO{sub 4}){sub x}O, (x=0-3). Black-Right-Pointing-Pointer IR an Raman spectra of mixed crystals.« less
Explorations on TiOsX (X=B, C, N, O and Si) alloys for potential superhard materials from first-principle calculation

NASA Astrophysics Data System (ADS)

Wu, Junyan; Zhang, Bo; Zhan, Yongzhong

2017-05-01

Using the first-principle calculations, we gained a deep insight of the structural, mechanical, electronic and thermal properties of the TiOs and TiOs-X (X=B, C, N, O and Si) compounds. The calculated results of formation enthalpy Hform and ternary transfer energy EXOs → Ti illustrate that O element exhibits strong Os site preference and all the compounds here are structurally stable. The results of mechanical properties confirm that there is no superhard character in those intermetallics which are mechanically stable. It is noted that the Ti7Os8Si possesses the best mechanical properties. All the compounds here show elastic anisotropy, and the Ti8Os7O exhibits the strongest elastic anisotropy, while the Ti8Os7Si strongly tends to be isotropic. There exists a mixture of covalent, ionic and metallic characters in these compounds. The covalent bond strength of Ti7Os8X is supposed to be better than that of the corresponding Ti8Os7X. Moreover, the minimum thermal conductivity kmin of these compounds are comparatively small and show dependence of directions, and they have potential thermal-insulating application in engineering.
Studies of single-mode injection lasers and of quaternary materials. Volume 1: Single-mode constricted double-heterojunction AlGaAs diode lasers

NASA Technical Reports Server (NTRS)

Botez, D.

1982-01-01

Constricted double-heterojunction (CDH) lasers are presented as the class of single-mode nonplanar-substrate devices for which the lasing cavity is on the least resistive electrical path between the contact and the substrate. Various types of CDH structures are considered under three general topics: liquid-phase epitaxy over channeled substrates, lateral mode control, and current control in nonplanar-substrate devices. Ridge-guide CDH lasers have positive-index lateral-mode confinement and provide: single-mode CW operation to 7 mW/facet at room temperature and to 3 mW/facet at 150 C; light-current characteristics with second-harmonic distortion as low as -57 dB below the fundamental level; threshold-current temperature coefficients, as high as 375 C (pulsed) and 310 C (CW); constant external differential quantum efficiency to 100 C; and lasing operation to 170 C CW and 280 C pulsed. Semileakyguide CDH lasers have an asymmetric leaky cavity for lateral-mode confinement and provide single-mode operation to 15 to 20 mW/facet CW and to 50 mW/facet at 50% duty cycle. Modulation characteristics and preliminary reliability data are discussed.
Oxygen K- and Mn L-Edges of La_xMn_yO_3-d Films

NASA Astrophysics Data System (ADS)

Deleon, Michael; Tyson, Trevor; Qian, Q.; Dubourdieu, C.; Senateur, J. P.; Bosak, A.; Arena, D. A.

2003-03-01

The La_xMn_yO_3-d system holds much interest due to it's wide range of magnetic and transport properties with varying compositions. Oxygen defects and lanthanum deficiencies in the parent compound LaMnO3 induce a mixture of valences at the Mn site which enables transitions to a ferromagnetic metallic state through double exchange [1-5]. We have measured the oxygen K-edges and Mn L-edges for La_xMn_yO_3-d films of varying x deposited on (100) SrTiO3 and x=0.8 on varying thickness deposited on (001) LaAlO_3. These results are interpreted by multiplet structure computations. In addition, band structure results will be used to track changes in unoccupied levels on the Mn and O sites. This work is supported by NSF Career Grant DMR-9733862 and DMR-0209243. [1]A. Gupta, T.R. McGuire, P.R. Duncombe, M. Rupp, J. Z. Sun, W. J. Gallagher, G. Xiao. Appl. Phys. Let. 67, 3494 (1995) [2]P. S. I. P. N. de Silva, F.M. Richards, L. F. Cohen, J. A. Alonso, M. J. Martinez-Lope, M. T. Casais, K. A. Thomas, J. L. MacManus-Driscoll. J. A. Phys. 83, 3394(1998) [3] C. Chen, A. de Lozanne. A. Phys. Let. 73, 3950(1998) [4] S. J. Kim, C. S. Kim, S. Park, B. W. Lee. J. A. Phys. 89, 7416 (2001) [5] J. Topfer, J. B. Goodenough. Sol. St. Ionics 101, 1215 (1997)
Transfer matrix approach to electron transport in monolayer MoS2/MoO x heterostructures

NASA Astrophysics Data System (ADS)

Li, Gen

2018-05-01

Oxygen plasma treatment can introduce oxidation into monolayer MoS2 to transfer MoS2 into MoO x , causing the formation of MoS2/MoO x heterostructures. We find the MoS2/MoO x heterostructures have the similar geometry compared with GaAs/Ga1‑x Al x As semiconductor superlattice. Thus, We employ the established transfer matrix method to analyse the electron transport in the MoS2/MoO x heterostructures with double-well and step-well geometries. We also considere the coupling between transverse and longitudinal kinetic energy because the electron effective mass changes spatially in the MoS2/MoO x heterostructures. We find the resonant peaks show red shift with the increasing of transverse momentum, which is similar to the previous work studying the transverse-momentum-dependent transmission in GaAs/Ga1‑x Al x As double-barrier structure. We find electric field can enhance the magnitude of peaks and intensify the coupling between longitudinal and transverse momentums. Moreover, higher bias is applied to optimize resonant tunnelling condition to show negative differential effect can be observed in the MoS2/MoO x system.
Mode characteristics of nonplanar double-heterojunction and large-optical-cavity laser structures

NASA Technical Reports Server (NTRS)

Butler, J. K.; Botez, D.

1982-01-01

Mode behavior of nonplanar double-heterojunction (DH) and large-optical-cavity (LOC) lasers is investigated using the effective index method to model the lateral field distribution. The thickness variations of various layers for the devices discussed are correlated with the growth characteristics of liquid-phase epitaxy over topographical features (channels, mesas) etched into the substrate. The effective dielectric profiles of constricted double-heterojunction (CDH)-LOC lasers show a strong influence on transverse mode operation: the fundamental transverse mode (i.e., in the plane perpendicular to the junction) may be laterally index-guided, while the first (high)-order mode is laterally index-antiguided. The analytical model developed uses a smoothly varying hyperbolic cosine distribution to characterize lateral index variations. The waveguide model is applied to several lasers to illustrate conditions necessary to convert leaky modes to trapped ones via the active-region gain distribution. Theoretical radiation patterns are calculated using model parameters, and matched to an experimental far-field pattern.
Robust sliding mode control applied to double Inverted pendulum system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mahjoub, Sonia; Derbel, Nabil; Mnif, Faical

A three hierarchical sliding mode control is presented for a class of an underactuated system which can overcome the mismatched perturbations. The considered underactuated system is a double inverted pendulum (DIP), can be modeled by three subsystems. Such structure allows the construction of several designs of hierarchies for the controller. For all hierarchical designs, the asymptotic stability of every layer sliding mode surface and the sliding mode surface of subsystems are proved theoretically by Barbalat's lemma. Simulation results show the validity of these methods.
Spin reorientation and magnetoelastic properties of ferromagnetic T b1 -xN dxC o2 systems with a morphotropic phase boundary

NASA Astrophysics Data System (ADS)

Murtaza, Adil; Yang, Sen; Chang, Tieyan; Ghani, Awais; Khan, Muhammad Tahir; Zhang, Rui; Zhou, Chao; Song, Xiaoping; Suchomel, Matthew; Ren, Yang

2018-03-01

The spin reorientation (SR) and magnetoelastic properties of pseudobinary ferromagnetic T b1 -xN dxC o2 (0 ≤x ≤1.0 ) systems involving a morphotropic phase boundary (MPB) were studied by high-resolution synchrotron x-ray diffraction (XRD), magnetization, and magnetostriction measurements. The easy magnetization direction of the Laves phase lies along the 〈111 〉 axis with x <0.65 , whereas it lies along the 〈100 〉 axis for x >0.65 below Curie temperature (TC). The temperature-dependent magnetization curves showed SR; this can be explained by a two-sublattice model. Based on the synchrotron (XRD) and magnetization measurements, the SR phase diagram for a MPB composition of T b0.35N d0.65C o2 was obtained. Contrary to previously reported ferromagnetic systems involving MPB, the MPB composition of T b0.35N d0.65C o2 exhibits a low saturation magnetization (MS), indicating a compensation of the Tb and Nd magnetic moments at MPB. The anisotropic magnetostriction (λS) first decreased until x =0.8 and then continuously increased in the negative direction with further increase of Nd concentration. The decrease in magnetostriction can be attributed to the decrease of spontaneous magnetostriction λ111 and increase of λ100 with opposite sign to λ111. This paper indicates an anomalous type of MPB in the ferromagnetic T b1 -xN dxC o2 system and provides an active way to design novel functional materials with exotic properties.
Synthesis, characterization and ferromagnetic properties of Zn1-xMnxO (x ≤ 0.05) nanoparticles

NASA Astrophysics Data System (ADS)

Phuruangrat, Anukorn; Thongtem, Titipun; Thongtem, Somchai

2018-06-01

Zn1-xMnxO (x ≤ 0.05) nanoparticles were synthesized by a combination of room temperature precipitation and high temperature calcination. Pure hexagonal wurtzite ZnO nanoparticles with the size of ≤100 nm and a dominant vibrational peak at 437 cm-1 of E2H non-polar optical phonon mode were detected. The present research was succeeded in doping of ZnO lattice by Mn2+ ions, including the detection of an additional peak at 528 cm-1 associated with lattice defects. Magnetic properties of Zn1-xMnxO (x ≤ 0.05) nanoparticles were controlled by correlated spin of Mn-O-Mn exchange couple and lattice disorder. The saturation magnetization of ferromagnetic Zn0.97Mn0.03O was the highest at 51.49 × 10-3 emu/g.
Concurrent ionic migration and electronic effects at the memristive TiO x /La1/3Ca2/3MnO3-x interface

NASA Astrophysics Data System (ADS)

Román Acevedo, W.; Ferreyra, C.; Sánchez, M. J.; Acha, C.; Gay, R.; Rubi, D.

2018-03-01

The development of reliable redox-based resistive random-access memory devices requires understanding and disentangling concurrent effects present at memristive interfaces. We report on the fabrication and electrical characterization of TiO x /La1/3Ca2/3MnO3-x microstructured interfaces and on the modeling of their memristive behavior. We show that a careful tuning of the applied external electrical stimuli allows controlling the redox process between both layers, obtaining multilevel non-volatile resistance states. We simulate the oxygen vacancies dynamics at the interface between both oxides, and successfully reproduce the experimental electrical behavior after the inclusion of an electronic effect, related to the presence of an n-p diode at the interface. The formation of the diode is due to the n- and p-character of TiO x and La1/3Ca2/3MnO3-x , respectively. Our analysis indicates that oxygen vacancies migration between both layers is triggered after the diode is polarized either in forward mode or in reverse mode above breakdown. Electrical measurements at different temperatures suggest that the diode can be characterized as Zener-type. The advantages of our junctions for their implementation in RRAM devices are finally discussed.
Defect-Tolerant Diffusion Channels for Mg 2+ Ions in Ribbon-Type Borates: Structural Insights into Potential Battery Cathodes MgVBO 4 and Mg x Fe 2–xB 2O 5

DOE PAGES

Bo, Shou-Hang; Grey, Clare P.; Khalifah, Peter G.

2015-06-10

The reversible room temperature intercalation of Mg 2+ ions is difficult to achieve, but may offer substantial advantages in the design of next-generation batteries if this electrochemical process can be successfully realized. Two types of quadruple ribbon-type transition metal borates (Mg xFe 2-xB 2O 5 and MgVBO 4) with high theoretical capacities (186 mAh/g and 360 mAh/g) have been synthesized and structurally characterized through the combined Rietveld refinement of synchrotron and time-of-flight neutron diffraction data. Neither MgVBO 4 nor Mg xFe 2-xB 2O 5 can be chemically oxidized at room temperature, though Mg can be dynamically removed from themore » latter phase at elevated temperatures (approximately 200 - 500 °C). Findings show that Mg diffusion in the Mg xFe 2-xB 2O 5 structure is more facile for the inner two octahedral sites than for the two outer octahedral sites in the ribbons, a result supported by both the refined site occupancies after Mg removal and by bond valence sum difference map calculations of diffusion paths in the pristine material. Mg diffusion in this pyroborate Mg xFe 2-xB 2O 5 framework is also found to be tolerant to the presence of Mg/Fe disorder since Mg ions can diffuse through interstitial channels which bypass Fe-containing sites.« less
The Effects of Gravity on the Combustion Synthesis of B2O3-Al2O3-MgO Glass Ceramic Composites

NASA Technical Reports Server (NTRS)

Manerbino, A. R.; Yi, H. C.; Guigne, J. Y.; Moore, J. J.; Schowengerdt, F. D.

2000-01-01

Glass ceramic composites based on B2O3-Al2O3-MgO have been produced by combustion synthesis in a Self-propagating mode. The gravitational effects on the combustion characteristics such as combustion wave velocity (V), and combustion temperature (T(sub c)) were studied. The results showed that the gravitational effects on these parameters were inconclusive. The microstructure of this system has also been analyzed with X-ray Diffraction and light microscopy. These results showed a higher amount of divitrification occurs under both reduced gravity and high gravity conditions. The gravitational effects on formation of pores, overall porosity and apparent porosity for this family of glass-ceramics also shows to be inconclusive. Possible reasons for these results are discussed.

X-Ray diffraction and mu-Raman investigation of the monoclinic-orthorhombic phase transition in Th(1-x)U(x)(C(2)O(4))(2).2H(2)O solid solutions.

PubMed

Clavier, Nicolas; Hingant, Nina; Rivenet, Murielle; Obbade, Saïd; Dacheux, Nicolas; Barré, Nicole; Abraham, Francis

2010-02-15

A complete Th(1-x)U(x)(C(2)O(4))(2).2H(2)O solid solution was prepared by mild hydrothermal synthesis from a mixture of hydrochloric solutions containing cations and oxalic acid. The crystal structure has been solved from twinned single crystals for x = 0, 0.5, and 1 with monoclinic symmetry, space group C2/c, leading to unit cell parameters of a approximately 10.5 A, b approximately 8.5 A, and c approximately 9.6 A. The crystal structure consists of a two-dimensional arrangement of actinide centers connected through bis-bidentate oxalate ions forming squares. The actinide metal is coordinated by eight oxygen atoms from four oxalate entities and two water oxygen atoms forming a bicapped square antiprism. The connection between the layers is assumed by hydrogen bonds between the water molecules and the oxygen of oxalate of an adjacent layer. Under these conditions, the unit cell contains two independent oxalate ions. From high-temperature mu-Raman and X-ray diffraction studies, the compounds were found to undergo a transition to an orthorhombic form (space group Ccca). The major differences in the structural arrangement concern the symmetry of uranium, which decreases from C2 to D2, leading to a unique oxalate group. Consequently, the nu(s)(C-O) double band observed in the Raman spectra recorded at room temperature turned into a singlet. This transformation was then used to make the phase transition temperature more precise as a function of the uranium content of the sample.
Efficient pre-ionization by direct X-B mode conversion in VEST

NASA Astrophysics Data System (ADS)

Jo, JongGab; Lee, H. Y.; Kim, S. C.; Kim, S. H.; An, Y. H.; Hwang, Y. S.

2017-01-01

Pre-ionization experiments with pure toroidal field have been carried out in VEST (Versatile Experiment Spherical Torus) to investigate the feasibility of direct XB mode conversion from perpendicular LFS (Low Field Side) injection for efficient pre-ionization. Pre-ionization plasmas are studied by measuring the electron density and temperature profiles with respect to microwave power and toroidal field strength, and 2D full wave cold plasma simulation using the COMSOL Multiphysics is performed for the comparison. It is experimentally figured out that exceeding the threshold microwave power (>3 kW), the parametric decay and localized collisional heating is observed near the UHR (Upper Hybrid Resonance), and the efficient XB mode conversion can be achieved in both short density scale length (Ln) and magnetic scale length (LB) region positioned at outboard and inboard sides, respectively. From the 2D full wave simulations, the reflection and tunneling of X-wave near the R-cutoff layer according to the measured electron density profiles are analyzed with electric field polarization and power flow. Threshold electric field and wave power density for parametric decay are evaluated at least more than 4.8 × 104 V/m and 100 W/cm2, respectively. This study shows that efficient pre-ionization schemes using direct XB mode conversion can be realized by considering the key factors such as Ln, LB, and transmitted wave power at the UHR. Application to Ohmic start-up experiment is carried out to confirm the effect of the pre-ionization schemes on tokamak plasma start-up in VEST.
Unified Description of the Optical Phonon Modes inN-Layer MoTe2

NASA Astrophysics Data System (ADS)

Froehlicher, Guillaume; Lorchat, Etienne; Fernique, François; Joshi, Chaitanya; Molina-Sánchez, Alejandro; Wirtz, Ludger; Berciaud, Stéphane

2015-10-01

$N$-layer transition metal dichalcogenides provide a unique platform to investigate the evolution of the physical properties between the bulk (three dimensional) and monolayer (quasi two-dimensional) limits. Here, using high-resolution micro-Raman spectroscopy, we report a unified experimental description of the $\\Gamma$-point optical phonons in $N$-layer $2H$-molybdenum ditelluride (MoTe$_2$). We observe a series of $N$-dependent low-frequency interlayer shear and breathing modes (below $40~\\rm cm^{-1}$, denoted LSM and LBM) and well-defined Davydov splittings of the mid-frequency modes (in the range $100-200~\\rm cm^{-1}$, denoted iX and oX), which solely involve displacements of the chalcogen atoms. In contrast, the high-frequency modes (in the range $200-300~\\rm cm^{-1}$, denoted iMX and oMX), arising from displacements of both the metal and chalcogen atoms, exhibit considerably reduced splittings. The manifold of phonon modes associated with the in-plane and out-of-plane displacements are quantitatively described by a force constant model, including interactions up to the second nearest neighbor and surface effects as fitting parameters. The splittings for the iX and oX modes observed in $N$-layer crystals are directly correlated to the corresponding bulk Davydov splittings between the $E_{2u}/E_{1g}$ and $B_{1u}/A_{1g}$ modes, respectively, and provide a measurement of the frequencies of the bulk silent $E_{2u}$ and $B_{1u}$ optical phonon modes. Our analysis could readily be generalized to other layered crystals.
Multiple secondary islands formation in nonlinear evolution of double tearing mode simulations

NASA Astrophysics Data System (ADS)

Guo, W.; Ma, J.; Yu, Z.

2017-03-01

A new numerical code solving the conservative perturbed resistive magnetohydrodynamic (MHD) model is developed. Numerical tests of the ideal Kelvin-Helmholtz instability and the resistive double tearing mode (DTM) show its capability in solving linear and nonlinear MHD instabilities. The nonlinear DTM evolution in 2D geometry is numerically investigated with low guiding field B z 0 , short half-distance y 0 between the equilibrium current sheets, and small resistivity η. The interaction of islands on the two initial current sheets may generate an unstable flow driven current sheet with a high length-to-thickness aspect ratio (α), and multiple secondary islands can form. In general, the length-to-thickness aspect ratio α and the number of secondary islands increase with decreasing guide field B z 0 , decreasing half-distance y 0 , and increasing Lundquist number of the flow driven current sheet S L although the dependence may be non-monotonic. The reconnection rate dependence on S L , B z 0 , and y 0 is also investigated.
Dynamic Confinement of ITER Plasma by O-Mode Driver at Electron Cyclotron Frequency Range

NASA Astrophysics Data System (ADS)

Stefan, V. Alexander

2009-05-01

A low B-field side launched electron cyclotron O-Mode driver leads to the dynamic rf confinement, in addition to rf turbulent heating, of ITER plasma. The scaling law for the local energy confinement time τE is evaluated (τE ˜ 3neTe/2Q, where (3/2) neTe is the local plasma thermal energy density and Q is the local rf turbulent heating rate). The dynamics of unstable dissipative trapped particle modes (DTPM) strongly coupled to Trivelpiece-Gould (T-G) modes is studied for gyrotron frequency 170GHz; power˜24 MW CW; and on-axis B-field ˜ 10T. In the case of dynamic stabilization of DTPM turbulence and for the heavily damped T-G modes, the energy confinement time scales as τE˜(I0)-2, whereby I0(W/m^2) is the O-Mode driver irradiance. R. Prater et. al., Nucl. Fusion 48, No 3 (March 2008). E. P. Velikhov, History of the Russian Tokamak and the Tokamak Thermonuclear Fusion Research Worldwide That Led to ITER (Documentary movie; Stefan Studios Int'l, La Jolla, CA, 2008; E. P. Velikhov, V. Stefan.) M N Rosenbluth, Phys. Scr. T2A 104-109 1982 B. B. Kadomtsev and O. P. Pogutse, Nucl. Fusion 11, 67 (1971).
The influence of the concentration of Sr ions on the crystal and magnetic structures of Ba{sub 2} –{sub x}Sr{sub x}FeMoO{sub 6} double perovskites (x = 0–1.6)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Turchenko, V. A., E-mail: turchenko@jinr.ru; Kalanda, N. A.; Kovalev, L. V.

2017-01-15

The crystal and magnetic structures of a solid solution of double perovskite Ba{sub 2–} {sub x}Sr{sub x}FeMoO{sub 6} (x = 0–1.6) have been investigated by neutron diffraction. The high-resolution diffraction patterns have provided precise information about the changes in the crystal and magnetic structures with an increase in the strontium content and data on the behavior of the sample microstructure. Replacement of barium with strontium leads to a change in the lattice symmetry from cubic (x = 0, sp. gr. Fm3̄m)) to tetragonal (x = 0.4, sp. gr. I4/m). At x = 1.0, the symmetry is either tetragonal (sp. gr.more » I4/m) or orthorhombic (sp. gr. Fmmm), and at x = 1.6 the symmetry becomes again tetragonal (sp. gr. I4/m). The values of the Curie temperature and microstrain increase with an increase in the strontium content.« less
Physical and thermal behaviour of Sr-La-Al-B-Si based SOFC glass sealants as function of SrO content and B2O3/SiO2 ratio in the matrix

NASA Astrophysics Data System (ADS)

Ojha, Prasanta Kumar; Rath, S. K.; Chongdar, T. K.; Gokhale, N. M.; Kulkarni, A. R.

2011-05-01

A series of SOFC glass sealants with composition SrO (x), La2O3 (15), Al2O3 (15), B2O3 (40 - x), and SiO2 (30) [x = 10, 15, 20, 25 and 30] (wt.%) [SLABS] are investigated for their structure property correlations at different compositions. Quantitative Fourier transform infrared spectroscopy shows structural rigidity with increasing SrO content, as demonstrate by an increase in the Si-O-Si/O-Si-O bending and B-O-B stretching frequencies. The role of SrO as a modifier dominates the control of the structure and behaviour of glasses compared with the effect of network formers, i.e., the B2O3/SiO2 ratio. Consequent to the structural changes, increasing substitution of B2O3 by SrO the glasses causes increases in the density, glass transition temperature and dilatometric softening point. On the other hand, the crystallization temperatures show a decreasing trend and the coefficient of thermal expansion increases with increase in substitution.
Neutron and x-ray scattering study of phonon dispersion and diffuse scattering in (Na ,Bi ) Ti O3-x BaTi O3 single crystals near the morphotropic phase boundary

NASA Astrophysics Data System (ADS)

Luo, Chengtao; Bansal, Dipanshu; Li, Jiefang; Viehland, Dwight; Winn, Barry; Ren, Yang; Li, Xiaobing; Luo, Haosu; Delaire, Olivier

2017-11-01

Neutron and x-ray scattering measurements were performed on (N a1 /2B i1 /2 ) Ti O3-x at %BaTi O3 (NBT-x BT ) single crystals (x =4 , 5, 6.5, and 7.5) across the morphotropic phase boundary (MPB), as a function of both composition and temperature, and probing both structural and dynamical aspects. In addition to the known diffuse scattering pattern near the Γ points, our measurements revealed new, faint superlattice peaks, as well as an extensive diffuse scattering network, revealing a short-range ordering of polar nanoregions (PNR) with a static stacking morphology. In samples with compositions closest to the MPB, our inelastic neutron scattering investigations of the phonon dynamics showed two unusual features in the acoustic phonon branches, between the superlattice points, and between the superlattice points and Γ points, respectively. These critical elements are not present in the other compositions away from the MPB, which suggests that these features may be related to the tilt modes coupling behavior near the MPB.
Retrieving atmospheric turbulence information from regular commercial aircraft using Mode-S and ADS-B

NASA Astrophysics Data System (ADS)

Kopeć, Jacek M.; Kwiatkowski, Kamil; de Haan, Siebren; Malinowski, Szymon P.

2016-05-01

Navigational information broadcast by commercial aircraft in the form of Mode-S EHS (Mode-S Enhanced Surveillance) and ADS-B (Automatic Dependent Surveillance-Broadcast) messages can be considered a new source of upper tropospheric and lower stratospheric turbulence estimates. A set of three processing methods is proposed and analysed using a quality record of turbulence encounters made by a research aircraft.The proposed methods are based on processing the vertical acceleration or the background wind into the eddy dissipation rate. Turbulence intensity can be estimated using the standard content of the Mode-S EHS/ADS-B.The results are based on a Mode-S EHS/ADS-B data set generated synthetically based on the transmissions from the research aircraft. This data set was validated using the overlapping record of the Mode-S EHS/ADS-B received from the same research aircraft. The turbulence intensity, meaning the eddy dissipation rate, obtained from the proposed methods based on the Mode-S EHS/ADS-B is compared with the value obtained using on-board accelerometer. The results of the comparison indicate the potential of the methods. The advantages and limitation of the presented approaches are discussed.
Chromium substitution in mullite type bismuth aluminate: Bi{sub 2}Cr{sub x}Al{sub 4−x}O{sub 9} with 0≤x≤2.0

DOE Office of Scientific and Technical Information (OSTI.GOV)

Debnath, Tapas, E-mail: debnath@du.ac.bd; Ullah, Ahamed; Rüscher, Claus H.

2014-12-15

Nominal compositions Bi{sub 2}Cr{sub x}Al{sub 4−x}O{sub 9} with 0.0≤x≤2.0 (Δx=0.2) were prepared using appropriate amounts of nitrates dissolved in glycerine and heated at 800 °C for 24 h as we previously used for the preparation of solid solution series Bi{sub 2}M{sub x}/M′{sub 4−x}O{sub 9} (M/M′=Fe/Al, Ga/Al and Fe/Ga). The samples were characterized using XRD, FTIR and optical microscopic techniques. Analyses of XRD data show mullite type single phase can be prepared up to x=1.2. The lattice parameters (a, b and c) increases with increasing Cr content. Further increase in x (i.e., x≥1.4) show the presence of some additional phases indicatingmore » a limiting value for Cr doping is in the range of 1.2≤x<1.4. The effect of Cr incorporation could also be observed in the infrared absorption spectra via systematic hard mode shifts of certain lattice modes, e.g. the Bi–O related vibration changes from 96 cm{sup −1} to 93 cm{sup −1} with increasing x up to 1.2 and certain intensity changes together with shift in peak positions. Interestingly, the absence of any splitting and shift of the high energy IR absorption peak at 821 cm{sup −1} as assigned to the characteristic tetrahedral type dimer, Al{sub 2}O{sub 7}, indicate that the Cr thus partially substitutes only the octahedrally coordinated Al. This is confirmed by Rietveld structure refinements, too. - Graphical abstract: Structural model of Cr doped bismuth aluminate, Bi{sub 2}Cr{sub x}Al{sub 4−x}O{sub 9}. - Highlights: • Chromium doped bismuth aluminate, Bi{sub 2}Cr{sub x}Al{sub 4−x}O{sub 9} with mullite type structure are synthesized. • The samples are characterized by XRD and FTIR techniques. • Cr can replace only certain amount of octahedrally coordinated Al in Bi{sub 2}Al{sub 4}O{sub 9} under present experimental conditions.« less
Effect of Mixed Glass Former on Ionic Conductivity of Silver Boro Tungstate glass system x[0.75AgI:0.25AgCl]: (1-x) [Ag2O-{B2O3:WO3}

NASA Astrophysics Data System (ADS)

Dehariya, Harsha; Kumar, R.; Polu, A. R.

2012-05-01

The idea to explore new 'Superionic Electrolytes', "Fast ionic conductors" is due to their tremendous potential applications in solid state electrochemical devices viz. solid state batteries, fuel cells, sensors, super capacitors. Superionic glasses have attracted great deal of attention due to their several advantageous over their crystalline counterparts such as high ionic conductivity, easy preparation, wide selection of compositions, isotropic properties and high stability etc [4-7]. Large numbers of silver ion based glasses have been reported in the literature for the glassy system of AgI:Ag2O: MxOy (MxOy = B2O3, SiO2, P2O5, GeO2, V2O5, As2O5, CrO3, SeO2, MoO3 & TeO3 etc many of them shows high silver ion conductivity [8]. Ion transport behavior of Silver Boro Tungstate glass system x[0.75AgI:0.25AgCl]: (1-x) [Ag2O{B2O3:WO3}], where 0 <= x <= 1 in molar wt% prepared by melt quench technique were reported. The new host [0.75AgI:0.25AgCl] was used as a better alternate in place of conventional host salt AgI. Conductivity measurement were carried out on this glass system as a function of frequency from 50 Hz to 5 MHz, over a temperature range of 27°C to 200°C, for different compositions by Impedance spectroscopy. The composition 0.7[0.75AgI:0.25AgCl]: 0.3[Ag2O{B2O3:WO3}] shows the highest conductivity of the order of σrt ~ 2.76 × 10-2 S/cm, referred to as the Optimum Conducting Composition (OCC). The enhancement in the conductivity has been obtained by mixed former effect. XRD result shows that the system is completely amorphous. Temperature dependence of conductivity of all compositions were studied & reported. Activation energies (Ea) were also evaluated from the slope of .Log(σ) vs 1000/T, Arrhenius plots.
Synthesis, structure and reactivity of rare-earth metallacarborane alkyls [η(1):η(5)-O(CH2)2C2B9H9]Ln(σ:η(1)-CH2C6H4-o-NMe2)(THF)2.

PubMed

Yang, Jingying; Xie, Zuowei

2015-04-14

Rare-earth metallacarborane alkyls can be stabilized by the incorporation of a functional sidearm into both π and σ ligands. Reaction of [Me3NH][7,8-O(CH2)2-7,8-C2B9H10] with one equiv. of Ln(CH2C6H4-o-NMe2)3 gave metallacarborane alkyls [η(1):η(5)-O(CH2)2C2B9H9]Ln(σ:η(1)-CH2C6H4-o-NMe2)(THF)2 (Ln = Y (), Gd (), Er ()) via alkane elimination. They represent the first examples of rare-earth metallacarborane alkyls. Treatment of with RN[double bond, length as m-dash]C[double bond, length as m-dash]NR (R = Cy, (i)Pr) or 2-benzoylpyridine afforded the corresponding mono-insertion products [η(1):η(5)-O(CH2)2C2B9H9]Y[η(2)-(RN)2C(CH2C6H4-o-NMe2)](DME) (R = Cy (), (i)Pr ()) or [η(1):η(5)-O(CH2)2C2B9H9]Y[C5H4NC(Ph)(CH2C6H4-o-NMe2)O](THF)2 (), respectively. Complex also reacted with ArNCO or ArNC (Ar = 2,6-diisopropylphenyl, 2,6-dimethylphenyl) to give di-insertion products [η(1):η(5)-O(CH2)2C2B9H9]Y[OC([double bond, length as m-dash]NC6H3Me2)N(C6H3Me2)C(CH2C6H4-o-NMe2)O](THF)2 () or [η(1):η(5)-O(CH2)2C2B9H9]Y[C([double bond, length as m-dash]NC6H3(i)Pr2)C([double bond, length as m-dash]NC6H3(i)Pr2)(CH2C6H4-o-NMe2)](DME) (). These results showed that the reactivity pattern of the Ln-C σ bond in rare-earth metallacarborane alkyls was dependent on the nature of the unsaturated organic molecules. New complexes were characterized by various spectroscopic techniques and elemental analysis. Some were further confirmed by single-crystal X-ray analysis.
Optical evidence for the spin-state disorder in LaCo1-x Rh x O3

NASA Astrophysics Data System (ADS)

Terasaki, Ichiro; Asai, Shinichiro; Taniguchi, Hiroki; Okazaki, Ryuji; Yasui, Yukio; Ikemoto, Yuka; Moriwaki, Taro

2017-06-01

We have measured the infrared reflectivity of single-crystalline samples of LaCo1-x Rh x O3 (x = 0, 0.05 and 0.10) from 10 to 300 K from 0.05 to 0.15 eV. We find that the optical phonons of the Co-O stretching mode depend on temperature and the Rh content. Analysis with three Lorentz oscillators reveals that the spin state of Co3+ in LaCo1-x Rh x O3 can be understood in terms of a solid solution of low-spin- and high-spin-state Co3+ ions, and the substituted Rh ion retains some fraction of the high-spin Co3+ ions down to low temperature.
Parametric instability induced by X-mode wave heating at EISCAT

NASA Astrophysics Data System (ADS)

Wang, Xiang; Zhou, Chen; Liu, Moran; Honary, Farideh; Ni, Binbin; Zhao, Zhengyu

2016-10-01

In this paper, we present results of parametric instability induced by X-mode wave heating observed by EISCAT (European Incoherent Scatter Scientific Association) radar at Tromsø, Norway. Three typical X-mode ionospheric heating experiments on 22 October 2013, 19 October 2012, and 21 February 2013 are investigated in details. Both parametric decay instability (PDI) and oscillating two-stream instability are observed during the X-mode heating period. We suggest that the full dispersion relationship of the Langmuir wave can be employed to analyze the X-mode parametric instability excitation. A modified kinetic electron distribution is proposed and analyzed, which is able to satisfy the matching condition of parametric instability excitation. Parallel electric field component of X-mode heating wave can also exceed the parametric instability excitation threshold under certain conditions.
Ultralow-threshold Kerr-lens mode-locked Ti:Al(2)O(3) laser.

PubMed

Kowalevicz, A M; Schibli, T R; Kärtner, F X; Fujimoto, J G

2002-11-15

An ultralow-threshold Kerr-lens mode-locked Ti:Al(2)O(3) laser achieved by use of an extended cavity design is demonstrated. Mode-locking thresholds as low as 156 mW are achieved. Pulses with durations as short as 14 fs and bandwidths of >100 nm with output powers of ~15 mW at 50-MHz repetition rates are generated by only 200 mW of pump power. Reducing the pump power requirements to a factor of 10x less than required by most conventional Kerr-lens mode-locked lasers permits inexpensive, low-power pump lasers to be used. This will facilitate the development of low-cost, high-performance femtosecond Ti:Al(2)O(3) laser technology.
Recovering the negative mode for type B Coleman-de Luccia instantons

NASA Astrophysics Data System (ADS)

Yang, I.-Sheng

2013-04-01

The usual (type A) thin-wall Coleman—de Luccia instanton is made by a bigger-than-half sphere of the false vacuum and a smaller-than-half sphere of the true vacuum. It has the standard O(4) symmetric negative mode associated with changing the size of the true vacuum region. On the other hand, the type B instanton, made by two smaller-than-half spheres, was believed to have lost this negative mode. We argue that such a belief is misguided due to an overrestriction on the Euclidean path integral. We introduce the idea of a “purely geometric junction” to visualize why such a restriction could be removed, and then we explicitly construct this negative mode. We also show that type B and type A instantons have the same thermal interpretation for mediating tunnelings.
First-principles study of electronic and optical properties of lead-free double perovskites Cs2NaBX6 (B = Sb, Bi; X = Cl, Br, I)

NASA Astrophysics Data System (ADS)

Zhao, Shuai; Yamamoto, Kumiko; Iikubo, Satoshi; Hayase, Shuzi; Ma, Tingli

2018-06-01

Organolead halide perovskite is regarded as the most promising light-harvesting material for next-generation solar cells; however, the intrinsic instability and toxicity of lead are still of great concern. Bismuth is ecofriendly and has electronic properties similar to those of lead, which has gradually attracted interest for optoelectronic applications. However, the valence state of bismuth is different from that of lead, eliminating the possibility of replacing lead by bismuth in organolead halide perovskites. To address this matter, one feasible strategy is to construct B-site double perovskites by the combination of Bi3+ and B+ in 1:1 ratio. In this work, lead-free halide double perovskites of the form Cs2NaBX6 (B = Sb, Bi; X = Cl, Br, I) were investigated by first-principles calculations. The electronic properties, optical absorption coefficients, and thermodynamic stability of these compounds were investigated to ascertain their potential application in solar energy conversion. The results provide theoretical support for the exploration of lead-free perovskite materials in potential optoelectronic applications.
The role of nonmagnetic d{sup 0} vs. d{sup 10}B-type cations on the magnetic exchange interactions in osmium double perovskites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feng, Hai L., E-mail: Hai.Feng@cpfs.mpg.de; Yamaura, Kazunari; Tjeng, Liu Hao

Polycrystalline samples of double perovskites Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) were synthesized by solid state reactions. They adopt the cubic double perovskite structures (space group, Fm-3m) with ordered B and Os arrangements. Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) show antiferromagnetic transitions at 93 K, 69 K, and 28 K, respectively. The Weiss-temperatures are −590 K for Ba{sub 2}ScOsO{sub 6}, −571 K for Ba{sub 2}YOsO{sub 6}, and −155 K for Ba{sub 2}InOsO{sub 6}. Sc{sup 3+} and Y{sup 3+} have the open-shell d{sup 0} electronic configuration, while In{sup 3+} has the closed-shell d{sup 10}. This indicates that a d{sup 0} B-typemore » cation induces stronger overall magnetic exchange interactions in comparison to a d{sup 10}. Comparison of Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) to their Sr and Ca analogues shows that the structural distortions weaken the overall magnetic exchange interactions. - Graphical abstract: Magnetic properties of osmium double perovskites Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) were studied. Comparison of Ba{sub 2}BOsO{sub 6}indicates that a d{sup 0} B-type cation induces stronger overall magnetic exchange interactions in comparison to a d{sup 10}. - Highlights: • Magnetic properties of double perovskites Ba{sub 2}BOsO{sub 6} (B=Sc, Y, In) were studied. • A d{sup 0}B-type cation induces stronger magnetic interactions than a d{sup 10}. • Structural distortions weaken the overall Os{sup 5+}-Os{sup 5+} magnetic interactions.« less
CMB delensing beyond the B modes

NASA Astrophysics Data System (ADS)

Green, Daniel; Meyers, Joel; van Engelen, Alexander

2017-12-01

Gravitational lensing by large-scale structure significantly impacts observations of the cosmic microwave background (CMB): it smooths the acoustic peaks in temperature and E-mode polarization power spectra, correlating previously uncorrelated modes; and it converts E-mode polarization into B-mode polarization. The act of measuring and removing the effect of lensing from CMB maps, or delensing, has been well studied in the context of B modes, but little attention has been given to the delensing of the temperature and E modes. In this paper, we model the expected delensed T and E power spectra to all orders in the lensing potential, demonstrating the sharpening of the acoustic peaks and a significant reduction in lens-induced power spectrum covariances. We then perform cosmological forecasts, demonstrating that delensing will yield improved sensitivity to parameters with upcoming surveys. We highlight the breaking of the degeneracy between the effective number of neutrino species and primordial helium fraction as a concrete application. We also show that delensing increases cosmological information as long as the measured lensing reconstruction is included in the analysis. We conclude that with future data, delensing will be crucial not only for primordial B-mode science but for a range of other observables as well.
Structural and ferroelectric phase evolution in [KNbO3]1-x[BaNi1/2Nb1/2O3-δ]x (x = 0, 0.1)

NASA Astrophysics Data System (ADS)

Hawley, Christopher; Wu, Liyan; Xiao, Geoffrey; Grinberg, Ilya; Rappe, Andrew; Davies, Peter; Spanier, Jonathan

The phase transition evolution for [KNbO3]1-x[BaNi1/2Nb1/2O3-δ]x (x=0, 0.1) is determined via complementary dielectric constant and Raman scattering measurements. Raman scattering by optical phonons over the range of 100-1000 cm-1 for -190°C < T < 600°C reveals six discernible zone-center optical phonon modes. They are assigned to structural and ferroelectric phases in the solid solution x = 0.1 and compared with those for end member x = 0 and with the results of temperature-dependent dielectric permittivity. Rigorous peak fitting analyses of spectra collected from the solid solution and end member indicate structural and ferroelectric phase transition temperatures that are quite close to those for the KNbO3 end member. Remarkably, despite the inclusion of 5 atomic Work supported by US ARO under W911NF-14-1-0500, NSF 1123696, and DoE BES under DE-FG02-07ER46431. Equipment acquisitions and computational support under DURIP and DoE NERSCC.

Coexistence of bipolar and unipolar resistive switching behaviors in the double-layer Ag/ZnS-Ag/CuAlO2/Pt memory device

NASA Astrophysics Data System (ADS)

Zhang, Lei; Xu, Haiyang; Wang, Zhongqiang; Yu, Hao; Ma, Jiangang; Liu, Yichun

2016-01-01

The coexistence of uniform bipolar and unipolar resistive-switching (RS) characteristics was demonstrated in a double-layer Ag/ZnS-Ag/CuAlO2/Pt memory device. By changing the compliance current (CC) from 1 mA to 10 mA, the RS behavior can be converted from the bipolar mode (BRS) to the unipolar mode (URS). The temperature dependence of low resistance states further indicates that the CFs are composed of the Ag atoms and Cu vacancies for the BRS mode and URS mode, respectively. For this double-layer structure device, the thicker conducting filaments (CFs) will be formed in the ZnS-Ag layer, and it can act as tip electrodes. Thus, the formation and rupture of these two different CFs are located in the CuAlO2 layer, realizing the uniform and stable BRS and URS.
Acousto-optic interaction in alpha-BaB(2)O(4)and Li(2)B(4)O(7) crystals.

PubMed

Martynyuk-Lototska, Irina; Mys, Oksana; Dudok, Taras; Adamiv, Volodymyr; Smirnov, Yevgen; Vlokh, Rostyslav

2008-07-01

Experimental studies and analysis of acousto-optic diffraction in alpha-BaB(2)O(4) and Li(2)B(4)O(7) crystals are given. Ultrasonic wave velocity, elastic compliance and stiffness coefficients, and piezo-optic and photoelastic coefficients of alpha-BaB(2)O(4) and Li(2)B(4)O(7) crystals are determined. The acousto-optic figure of merit has been estimated for different possible geometries of acousto-optic interaction. It is shown that the acousto-optic figures of merit for alpha-BaB(2)O(4) crystals reach the value M(2)=(270 +/- 70) x 10(-15) s(3)/kg for the case of interaction with the slowest ultrasonic wave. The directions of propagation and polarization of those acoustic waves are obtained on the basis of construction of acoustic slowness surfaces. The acousto-optic diffraction is experimentally studied for alpha-BaB(2)O(4) and Li(2)B(4)O(7) crystals.
Tunable Optical Properties and Increased Thermal Quenching in the Blue-Emitting Phosphor Series: Ba 2 (Y 1–x Lu x ) 5 B 5 O 17 :Ce 3+ ( x = 0–1)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hermus, Martin; Phan, Phu-Cuong; Duke, Anna C.

The preparation of cerium-substituted barium lutetium borate, Ba2Lu5B5O17:Ce3+, is achieved using high temperature solid state synthesis. This compound crystallizes in the Ba2Y5B5O17-type structure and shows an efficient blue emission (λmax = 447 nm) when excited by UV-light (λex = 340 nm) with a photoluminescent quantum yield near 90%, a fast luminescence decay time (<40 ns), and a thermal quenching temperature of 452 K. Further, preparing a solid solution following Ba2(Y1–xLux)5B5O17:Ce3+ (x = 0, 0.25, 0.50, 0.75, 1) confirms that all compounds are isostructural and follow Vegard’s law. Substituting Y3+ for Lu3+ yields a nearly constant emission spectrum that blue-shifts bymore » only 9 nm and has a consistent luminescence lifetime across the range prepared. The photoluminescent quantum yield (PLQY) and thermal quenching (T50) of the solid solution, however, are dramatically impacted by the composition, with the PLQY decreasing to ≈70% and the T50 dropping 49 K going from x = 1 to x = 0. These significant changes in the optical properties likely stem from enhanced structural rigidity as the larger, more polarizable Y3+ is substituted for the smaller, harder Lu3+ cation. These results highlight the importance of optimizing chemical bonding to improve a phosphor’s optical properties.« less
Synthesis, characterization of double perovskite Ca{sub 2}MSbO{sub 6} (M = Dy, Fe, Cr, Al) materials via sol–gel auto-combustion and their catalytic properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Feraru, S.; Samoila, P.; Borhan, A.I.

2013-10-15

Double perovskite-type oxide Ca{sub 2}MSbO{sub 6} materials, where M = Dy, Fe, Cr, and Al, were prepared by using the sol–gel auto-combustion method. The role of different B-site cations on their synthesis, structures, morphologies and catalytic properties was investigated. The progress of double-perovskite type structure formation and the disappearance of the organic phases were monitored by infrared absorption spectroscopy (FTIR). Double perovskite oxide structures were evaluated using X-ray diffraction (XRD), while the microstructure of obtained compounds was studied using scanning electron microscopy (SEM). Also, BET surface areas were measured at the liquid nitrogen temperature by nitrogen adsorption. Catalytic properties ofmore » the obtained compounds were evaluated by test reaction of hydrogen peroxide decomposition. - Highlights: • Ca{sub 2}MSbO{sub 6} double perovskites were obtained by sol–gel auto-combustion method. • Ca{sub 2}MSbO{sub 6} (M = Dy, Fe, Cr and Al) as catalysts in H{sub 2}O{sub 2} decomposition • Strong relationship between particles' shape, BET area and catalytic performance • Ca{sub 2}FeSbO{sub 6} spherical grains show superior catalytic activity.« less
Synthesis, structure and magnetic properties of Sr{sub 2}Fe{sub 1-x}Ga{sub x}MoO{sub 6} (0 {<=} x {<=} 0.6) double perovskites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Azad, Abul K., E-mail: aka7@st-andrews.ac.uk; Khan, Abdullah; Eriksson, Sten-G.

2009-12-15

Polycrystalline Sr{sub 2}Fe{sub 1-x}Ga{sub x}MoO{sub 6} (0 {<=} x {<=} 0.6) materials have been synthesized by solid state reaction method and studied by neutron powder diffraction (NPD) and magnetization measurements. Rietveld analysis of the temperature dependent NPD data shows that the compounds crystallize in the tetragonal symmetry in the space group I4/m. The anti-site (AS) defects concentration increases with Ga doping, giving rise to highly B-site disordered materials. Ga doping at the Fe-site decreases the cell volume. The evolution of bond lengths and the cation oxidation states was determined from the Rietveld refinement data. The saturation magnetization and Curie temperaturemore » decreased with the increasing Ga content in the samples. Low temperature neutron diffraction data analysis and magnetization measurements confirm the magnetic interaction as ferrimagnetic in the sample.« less
Down-top nanofabrication of binary (CdO)x (ZnO)1-x nanoparticles and their antibacterial activity.

PubMed

Al-Hada, Naif Mohammed; Mohamed Kamari, Halimah; Abdullah, Che Azurahanim Che; Saion, Elias; Shaari, Abdul H; Talib, Zainal Abidin; Matori, Khamirul Amin

2017-01-01

In the present study, binary oxide (cadmium oxide [CdO]) x (zinc oxide [ZnO]) 1-x nanoparticles (NPs) at different concentrations of precursor in calcination temperature were prepared using thermal treatment technique. Cadmium and zinc nitrates (source of cadmium and zinc) with polyvinylpyrrolidone (capping agent) have been used to prepare (CdO) x (ZnO) 1-x NPs samples. The sample was characterized by X-ray diffraction (XRD), scanning electron microscopy, energy-dispersive X-ray (EDX), transmission electron microscopy (TEM), and Fourier transform infrared (FTIR) spectroscopy. XRD patterns analysis revealed that NPs were formed after calcination, which showed a cubic and hexagonal crystalline structure of (CdO) x (ZnO) 1-x NPs. The phase analysis using EDX spectroscopy and FTIR spectroscopy confirmed the presence of Cd and Zn as the original compounds of prepared (CdO) x (ZnO) 1-x NP samples. The average particle size of the samples increased from 14 to 33 nm as the concentration of precursor increased from x=0.20 to x=0.80, as observed by TEM results. The surface composition and valance state of the prepared product NPs were determined by X-ray photoelectron spectroscopy (XPS) analyses. Diffuse UV-visible reflectance spectra were used to determine the optical band gap through the Kubelka-Munk equation; the energy band gap was found to decrease for CdO from 2.92 to 2.82 eV and for ZnO from 3.22 to 3.11 eV with increasing x value. Additionally, photoluminescence (PL) spectra revealed that the intensity in PL increased with an increase in particle size. In addition, the antibacterial activity of binary oxide NP was carried out in vitro against Escherichia coli ATCC 25922 Gram (-ve), Salmonella choleraesuis ATCC 10708, and Bacillus subtilis UPMC 1175 Gram (+ve). This study indicated that the zone of inhibition of 21 mm has good antibacterial activity toward the Gram-positive B. subtilis UPMC 1175.
Vibrational spectra of Mg2KH(XO4)2·15H2O (X=P, As) containing dimer units [H(XO4)2].

PubMed

Stefov, V; Koleva, V; Najdoski, M; Abdija, Z; Cahil, A; Šoptrajanov, B

2017-08-05

Infrared and Raman spectra of Mg 2 KH(PO 4 ) 2 ·15H 2 O and Mg 2 KH(AsO 4 ) 2 ·15H 2 O and a series of their partially deuterated analogues were recorded and analyzed. Compounds of the type Mg 2 KH(XO 4 ) 2 ·15H 2 O (X=P, As) are little-known and a rare case of phosphate and arsenate salts containing dimer units [H(XO 4 ) 2 ] in the crystal structure. The analysis of their IR spectra (recorded at room and liquid nitrogen temperature) and Raman spectra showed that the spectral characteristics of the XO 4 groups connected in a dimer through a proton are not consistent with the presence of X-O-H covalent linkage and C 1 crystallographic symmetry of the XO 4 groups. The observation of a singlet Raman band for the ν 1 (XO 4 ) mode as well as the absence of substantial splitting of the ν 3 (XO 4 ) modes and IR activation of the ν 1 (XO 4 ) mode suggest that the dimer units [H(XO 4 ) 2 ] are most probably symmetric rather than non-symmetric ones. It was found that, in the vibrational spectra of Mg 2 KH(AsO 4 ) 2 ·15H 2 O, both ν 1 (AsО 4 ) and ν 3 (AsО 4 ) modes have practically the same wavenumber around 830cm -1 . It was also established that the ν 4 (PО 4 ) modes in the deuterated hydrogendiphosphate compound are strongly coupled, most probably with HDO and/or D 2 O librations. As a whole, the spectral picture of Mg 2 KH(XO 4 ) 2 ·15H 2 O (X=P, As) very much resembles that observed for the struvite type compounds with the formula KMgXO 4 ·6H 2 O (X=P, As) which do not contain X-OH groups. This means that vibrations of the dimers [H(XO 4 ) 2 ] play a relatively small part in the general spectral appearance. Copyright © 2017 Elsevier B.V. All rights reserved.
Anomalous double-stripe charge ordering in β -NaFe2O3 with double triangular layers consisting of almost perfect regular Fe4 tetrahedra

NASA Astrophysics Data System (ADS)

Kobayashi, Shintaro; Ueda, Hiroaki; Michioka, Chishiro; Yoshimura, Kazuyoshi; Nakamura, Shin; Katsufuji, Takuro; Sawa, Hiroshi

2018-05-01

The physical properties of the mixed-valent iron oxide β -NaFe2O3 were investigated by means of synchrotron radiation x-ray diffraction, magnetization, electrical resistivity, differential scanning calorimetry, 23Na NMR, and 57FeM o ̈ssbauer measurements. This compound has double triangular layers consisting of almost perfect regular Fe4 tetrahedra, which suggests geometrical frustration. We found that this compound exhibits an electrostatically unstable double-stripe-type charge ordering, which is stabilized by the cooperative compression of Fe3 +O6 octahedra, owing to a valence change and Fe2 +O6 octahedra due to Jahn-Teller distortion. Our results indicate the importance of electron-phonon coupling for charge ordering in the region of strong charge frustration.
Upper hybrid wave excitation due to O-mode interaction with density gradient in the ionosphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Antani, S.N.; Kaup, D.J.; Rao, N.N.

1995-12-31

It has been well recognized that upper hybrid (UH) waves play a key role in various wave processes occurring in the upper hybrid resonance (UHR) region of the ionosphere leading to the observed stimulated electromagnetic emissions (SEE) during artificial heating by ordinary mode (O-mode) electromagnetic waves. Hence it is important to investigate how the UH waves get excited from the incident O-mode. It has been generally suggested that the UH waves are excited by O-mode interaction with nonuniform ionospheric plasma. For instance, direct conversion of the O-mode into UH waves due to pre-existing short scale irregularities was reported earlier. Heremore » the authors consider the role of large-scale, smooth density gradient in exciting the UH waves from the O-mode. The model used is that of a driven harmonic oscillator in which the source term arises from the O-mode interaction with local density gradient. For a slab model with density gradient in the x-direction, and the geomagnetic field in the z-direction, they obtain an inhomogeneous fourth order ordinary differential equation governing the UH wave excitation. This equation has been analyzed in the vicinity of the UHR. The pertinent solutions will be presented and discussed for the typical parameters of heating experiments.« less
Surface Modification of Solution-Processed ZrO2 Films through Double Coating for Pentacene Thin-Film Transistors

NASA Astrophysics Data System (ADS)

Kwon, Jin-Hyuk; Bae, Jin-Hyuk; Lee, Hyeonju; Park, Jaehoon

2018-03-01

We report the modification of surface properties of solution-processed zirconium oxide (ZrO2) dielectric films achieved by using double-coating process. It is proven that the surface properties of the ZrO2 film are modified through the double-coating process; the surface roughness decreases and the surface energy increases. The present surface modification of the ZrO2 film contributes to an increase in grain size of the pentacene film, thereby increasing the field-effect mobility and decreasing the threshold voltage of the pentacene thin-film transistors (TFTs) having the ZrO2 gate dielectric. Herein, the molecular orientation of pentacene film is also studied based on the results of contact angle and X-ray diffraction measurements. Pentacene molecules on the double-coated ZrO2 film are found to be more tilted than those on the single-coated ZrO2 film, which is attributed to the surface modification of the ZrO2 film. However, no significant differences are observed in insulating properties between the single-and the double-coated ZrO2 dielectric films. Consequently, the characteristic improvements of the pentacene TFTs with the double-coated ZrO2 gate dielectric film can be understood through the increase in pentacene grain size and the reduction in grain boundary density.
X-ray-induced catalytic active-site reduction of a multicopper oxidase: structural insights into the proton-relay mechanism and O 2 -reduction states

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serrano-Posada, Hugo; Centeno-Leija, Sara; Rojas-Trejo, Sonia Patricia

2015-11-26

During X-ray data collection from a multicopper oxidase (MCO) crystal, electrons and protons are mainly released into the system by the radiolysis of water molecules, leading to the X-ray-induced reduction of O 2 to 2H 2O at the trinuclear copper cluster (TNC) of the enzyme. In this work, 12 crystallographic structures of Thermus thermophilus HB27 multicopper oxidase (Tth-MCO) in holo, apo and Hg-bound forms and with different X-ray absorbed doses have been determined. In holo Tth -MCO structures with four Cu atoms, the proton-donor residue Glu451 involved in O 2 reduction was found in a double conformation: Glu451a (~7 Åmore » from the TNC) and Glu451b (~4.5 Å from the TNC). A positive peak of electron density above 3.5σ in anF o-F c map for Glu451a O ε2 indicates the presence of a carboxyl functional group at the side chain, while its significant absence in Glu451b strongly suggests a carboxylate functional group. In contrast, for apo Tth -MCO and in Hg-bound structures neither the positive peak nor double conformations were observed. Together, these observations provide the first structural evidence for a proton-relay mechanism in the MCO family and also support previous studies indicating that Asp106 does not provide protons for this mechanism. In addition, eight composite structures (Tth -MCO-C1–8) with different X-ray-absorbed doses allowed the observation of different O 2-reduction states, and a total depletion of T2Cu at doses higher than 0.2 MGy showed the high susceptibility of this Cu atom to radiation damage, highlighting the importance of taking radiation effects into account in biochemical interpretations of an MCO structure.« less
Spectroscopic Properties of B2O3-PbO-Nd2O3 Glasses

NASA Astrophysics Data System (ADS)

Simon, V.; Ardelean, I.; Milea, I.; Peteanu, M.; Simon, S.

Samples belonging to xNd2O3(100-x) [2B2O3·PbO] glass system, with 0≤ x≤ 40 mol%, are investigated by IR and UV-VIS spectroscopies in order to obtain evidence for the influence of Nd2O3 on the local order from 2B2O3·PbO glass matrix. Besides the IR absorption bands characteristic to lead and boron arrangements, typical absorption lines of Nd3+ ions around 4000 cm-1 and 6000 cm-1 are recorded. The 6000 cm-1 band appears only for the samples with x≥25 mol% Nd2O3. The split of some UV-VIS absorption bands arising from transitions of neodymium ions in doublet lines as well as the shift of the absorption bands as the Nd2O3 content increases denote the influence of the lead-borate matrix on the radiative transitions of the lanthanide ion.
Electron paramagnetic resonance analysis of La(1-x)M(x)MnO(3+δ) (M = Ce, Sr) perovskite-like nanostructured catalysts.

PubMed

Oliva, Cesare; Allieta, Mattia; Scavini, Marco; Biffi, Cesare; Rossetti, Ilenia; Forni, Lucio

2012-08-06

The physical-chemical properties of some nanostructured perovskite-like catalysts of general formula La(1-x)M(x)MnO(3+δ) (M = Ce, Sr) have been investigated, in particular by using the electron paramagnetic resonance (EPR) technique. We show that the interplay between the -O-Mn(3+)-O-Mn(4+)-O- electron double-exchange and the electron mobility is strictly dependent on the dopant nature and the annealing conditions in air. A relationship between the observed properties of these samples and their activity in the methane flameless catalytic combustion is proposed.
First-principles study on ferromagnetism in double perovskite Sr2AlTaO6 doped with Cu or Zn at B sites

NASA Astrophysics Data System (ADS)

Li, Y. D.; Wang, C. C.; Guo, Y. M.; Yu, Y.; Lu, Q. L.; Huang, S. G.; Li, Q. J.; Wang, H.; Cheng, R. L.; Liu, C. S.

2018-05-01

The possibilities of ferromagnetism induced by nonmagnetic dopants (Cu, Zn) in double perovskite Sr2AlTaO6 at B sites are investigated by density functional theory. Calculations reveal that substitutions at Ta-site tend to form high spin electronic configurations and could induce ferromagnetism which can be attributed to the hole-mediated p- d hybridization between Cu (or Zn) eg states and the neighboring O 2p states. The dopants preferably substitute at Al-site and adopt low spin electronic structures. Due to the smaller hole concentration and weaker covalent intensity, Sr2AlTaO6 with dopants at Al-site exhibits p-type metallic semiconductors without spin polarization.
Structural characterization of Mg substituted on A/B sites in NiFe_2O_4 nanoparticles using autocombustion method

NASA Astrophysics Data System (ADS)

De, Manojit; Tewari, H. S.

2017-07-01

In the present paper, we are reporting the synthesis of pure nickel and magnesium ferrite [NiFe_2O_4, MgFe_2O_4] and magnesium-substituted nickel ferrite (Ni_{1-x}Mg_{x/y}Fe_{2-y}O_4; x=y=0.60) on A/B sites with particles size in nanometer range using autocombustion technique. In this study, it has been observed that with increase in sintering temperature, the estimated bulk density of the materials increases. The XRD patterns of the samples show the formation of single-phase materials and the lattice parameters are estimated from XRD patterns. From Raman spectra, the Raman shift of pure NiFe_2O_4 and MgFe_2O_4 are comparable with the experimental values reported in literature. The Raman spectra give five Raman active modes (A_{{1g}} + Eg + 3F_{2g}) which are expected in the spinel structure.
Synthesis and crystal structure of a novel pentaborate, Na{sub 3}ZnB{sub 5}O{sub 10}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Xuean; Li Ming; Chang Xinan

A novel ternary borate, trisodium zinc pentaborate, Na{sub 3}ZnB{sub 5}O{sub 10}, has been prepared by solid-state reaction at temperature below 750deg. C. The single-crystal X-ray structural analysis showed that Na{sub 3}ZnB{sub 5}O{sub 10} crystallizes in the monoclinic space group P2{sub 1}/n with a=6.6725(7)A, b=18.1730(10)A, c=7.8656(9)A, {beta}=114.604(6){sup o}, Z=4. It represents a new structure type in which double ring [B{sub 5}O{sub 10}]{sup 5-} building units are bridged by ZnO{sub 4} tetrahedra through common O atoms to form a two-dimensional {sub {approx}}{sup 2}[ZnB{sub 5}O{sub 10}]{sup 3-}-layer that affords one-dimensional channels running parallel to the [101] direction. Symmetry-center related {sub {approx}}{sup 2}[ZnB{sub 5}O{submore » 10}]{sup 3-} layers are stacked along the b-axis, with the interlayer void spaces and intralayer open channels filled by Na{sup +} cations to balance charge. The IR spectrum further confirms the presence of both BO{sub 3} and BO{sub 4} groups and UV-vis diffuse reflectance spectrum shows a band gap of about 3.2eV.« less
ITER Plasma at Electron Cyclotron Frequency Domain: Stimulated Raman Scattering off Gould-Trivelpiece Modes and Generation of Suprathermal Electrons and Energetic Ions

NASA Astrophysics Data System (ADS)

Stefan, V. Alexander

2011-04-01

Stimulated Raman scattering in the electron cyclotron frequency range of the X-Mode and O-Mode driver with the ITER plasma leads to the ``tail heating'' via the generation of suprathermal electrons and energetic ions. The scattering off Trivelpiece-Gould (T-G) modes is studied for the gyrotron frequency of 170GHz; X-Mode and O-Mode power of 24 MW CW; on-axis B-field of 10T. The synergy between the two-plasmon decay and Raman scattering is analyzed in reference to the bulk plasma heating. Supported in part by Nikola TESLA Labs, La Jolla, CA
Structural characteristics of Mg-doped (1-x)(K0.5Na0.5)NbO3-xLiSbO3 lead-free ceramics as revealed by Raman spectroscopy

NASA Astrophysics Data System (ADS)

Zhu, W. L.; Zhu, J. L.; Meng, Y.; Wang, M. S.; Zhu, B.; Zhu, X. H.; Zhu, J. G.; Xiao, D. Q.; Pezzotti, G.

2011-12-01

This paper presents a Raman spectroscopic study of compositional-change-induced structure variation and of the related mechanism of Mg doping in LiSbO3 (LS)-modified (K0.5Na0.5)NbO3 (KNN) ceramics. With increasing LS content from 0 to 0.06, a discontinuous shift towards higher wavenumbers was found for the band position of the A1g(v1) stretching mode of KNN, accompanied by a clearly nonlinear broadening of this band and a decrease in its intensity. Such morphological changes in the Raman spectrum result from two factors: (i) changes in polarizability/binding strength of the O-Nb-O vibration upon incorporation of Li ions in the KNN perovskitic structure and (ii) a polymorphic phase transition (PPT) from orthorhombic to tetragonal (O → T) phase at x > 0.04. Upon increasing the amount, w, of Mg dopant incorporated into the (1-x)KNN-xLS ceramic structure, the intensity of the Raman bands are enhanced, while the peak position and the full width at half maximum of the A1g(v1) mode was found to experience a clear dependence on both w and x. Raman characterization revealed that the mechanism of Mg doping is strongly correlated with the concentration of Li in the perovskite structure: Mg2+ ions will preferentially replace Li+ ions for low Mg doping while replace K/Na ions for higher doping of Mg. The PPT O → T was also found to be altered by the introduction of Mg and the critical value of LS concentration, xO-T, for incipient O → T transition in the KNN-xLS-wMT system was strongly dependent on Mg content, with xO → T being roughly equal to 0.04 + 2w, for the case of dilute Mg alloying.
Lattice and magnetic dynamics in perovskite Y1 -xLaxTiO3

NASA Astrophysics Data System (ADS)

Li, Bing; Louca, Despina; Niedziela, Jennifer; Li, Zongyao; Zhang, Libin; Zhou, Jianshi; Goodenough, John B.

2016-12-01

Inelastic neutron scattering combined with the dynamic pair density function (DPDF) analysis were used to investigate the magnetic and lattice dynamics in the orbitally active Y1 -xLaxTiO3 as it crosses the antiferromagnetic (AFM) to ferromagnetic (FM) phase boundary. Upon doping, the FM state present in YTiO3 is suppressed on approaching a critical concentration of xc˜0.3 in which TC≃0 , and is replaced by the AFM phase of LaTiO3. Below xc, magnetic scattering from spin waves is dominant at low energies. At xc with a TC≃0 , magnetic scattering is also observed and is most likely due to AFM fluctuations. At the same time, local atomic fluctuations extending to 50 meV are observed above and below the magnetic transitions from 0 ≤x ≤1 that show distinct characteristics with x . From Y to La, a clear difference is observed in the phonon density of states as a function of doping as well. At x =0.15 and 0.3, low-energy modes involving predominantly the rare-earth ion become suppressed with increasing temperature, while in x =1 , strong suppression of phonon modes across a wide range in energy is observed above TN. It is likely that in the Y heavy samples, phonon modes below 20 meV have a stronger influence on the orbital excitations, while in LaTiO3, a strong phonon dependence is observed upon cooling up to TN.
Investigation by Monte Carlo simulation of substitution doping in the Double Perovskite Sr2CrRe1-xWxO6

NASA Astrophysics Data System (ADS)

El Rhazouani, O.; Benyoussef, A.

2018-01-01

Re-substitution doping by W has been investigated in the Double Perovskite (DP) Sr2CrRe1-xWxO6 for x ranging from 10 to 90% by using a Monte Carlo Simulation (MCS) in the framework of Ising model. Exchange couplings used in the simulation have been approximated in previous work for experimental Curie temperatures (TC). Doping effect on: partial and total magnetization, magnetic susceptibility, internal energy, specific heat, and Curie temperature has been studied. A sharp drop of partial magnetizations at 40% of W-concentration has been noticed at the magnetic transition. Apparition of a non-monotonic behavior of the total magnetization at 20% of W-concentration. Effect of doping on the stability of the compound has been emphasized. A quasilinear decrease of TC has been observed by increasing the concentration percentage of substitution doping by W.

Down-top nanofabrication of binary (CdO)x (ZnO)1–x nanoparticles and their antibacterial activity

PubMed Central

Al-Hada, Naif Mohammed; Mohamed Kamari, Halimah; Abdullah, Che Azurahanim Che; Saion, Elias; Shaari, Abdul H; Talib, Zainal Abidin; Matori, Khamirul Amin

2017-01-01

In the present study, binary oxide (cadmium oxide [CdO])x (zinc oxide [ZnO])1–x nanoparticles (NPs) at different concentrations of precursor in calcination temperature were prepared using thermal treatment technique. Cadmium and zinc nitrates (source of cadmium and zinc) with polyvinylpyrrolidone (capping agent) have been used to prepare (CdO)x (ZnO)1–x NPs samples. The sample was characterized by X-ray diffraction (XRD), scanning electron microscopy, energy-dispersive X-ray (EDX), transmission electron microscopy (TEM), and Fourier transform infrared (FTIR) spectroscopy. XRD patterns analysis revealed that NPs were formed after calcination, which showed a cubic and hexagonal crystalline structure of (CdO)x (ZnO)1–x NPs. The phase analysis using EDX spectroscopy and FTIR spectroscopy confirmed the presence of Cd and Zn as the original compounds of prepared (CdO)x (ZnO)1–x NP samples. The average particle size of the samples increased from 14 to 33 nm as the concentration of precursor increased from x=0.20 to x=0.80, as observed by TEM results. The surface composition and valance state of the prepared product NPs were determined by X-ray photoelectron spectroscopy (XPS) analyses. Diffuse UV–visible reflectance spectra were used to determine the optical band gap through the Kubelka–Munk equation; the energy band gap was found to decrease for CdO from 2.92 to 2.82 eV and for ZnO from 3.22 to 3.11 eV with increasing x value. Additionally, photoluminescence (PL) spectra revealed that the intensity in PL increased with an increase in particle size. In addition, the antibacterial activity of binary oxide NP was carried out in vitro against Escherichia coli ATCC 25922 Gram (−ve), Salmonella choleraesuis ATCC 10708, and Bacillus subtilis UPMC 1175 Gram (+ve). This study indicated that the zone of inhibition of 21 mm has good antibacterial activity toward the Gram-positive B. subtilis UPMC 1175. PMID:29200844
Y2O3:Yb,Er@mSiO2-CuxS double-shelled hollow spheres for enhanced chemo-/photothermal anti-cancer therapy and dual-modal imaging

NASA Astrophysics Data System (ADS)

Yang, Dan; Yang, Guixin; Wang, Xingmei; Lv, Ruichan; Gai, Shili; He, Fei; Gulzar, Arif; Yang, Piaoping

2015-07-01

Multifunctional composites have gained significant interest due to their unique properties which show potential in biological imaging and therapeutics. However, the design of an efficient combination of multiple diagnostic and therapeutic modes is still a challenge. In this contribution, Y2O3:Yb,Er@mSiO2 double-shelled hollow spheres (DSHSs) with up-conversion fluorescence have been successfully prepared through a facile integrated sacrifice template method, followed by a calcination process. It is found that the double-shelled structure with large specific surface area and uniform shape is composed of an inner shell of luminescent Y2O3:Yb,Er and an outer mesoporous silica shell. Ultra small CuxS nanoparticles (about 2.5 nm) served as photothermal agents, and a chemotherapeutic agent (doxorubicin, DOX) was then attached onto the surface of mesoporous silica, forming a DOX-DSHS-CuxS composite. The composite exhibits high anti-cancer efficacy due to the synergistic photothermal therapy (PTT) induced by the attached CuxS nanoparticles and the enhanced chemotherapy promoted by the heat from the CuxS-based PTT when irradiated by 980 nm near-infrared (NIR) light. Moreover, the composite shows excellent in vitro and in vivo X-ray computed tomography (CT) and up-conversion fluorescence (UCL) imaging properties owing to the doped rare earth ions, thus making it possible to achieve the target of imaging-guided synergistic therapy.Multifunctional composites have gained significant interest due to their unique properties which show potential in biological imaging and therapeutics. However, the design of an efficient combination of multiple diagnostic and therapeutic modes is still a challenge. In this contribution, Y2O3:Yb,Er@mSiO2 double-shelled hollow spheres (DSHSs) with up-conversion fluorescence have been successfully prepared through a facile integrated sacrifice template method, followed by a calcination process. It is found that the double-shelled structure with large
Electron doping effect on structural and magnetic phase transitions in Sr{sub 2-x}Nd{sub x}FeMoO{sub 6} double perovskites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Azad, A.K.; Eriksson, S.-G.; Khan, Abdullah

2006-05-15

Polycrystalline Sr{sub 2-x}Nd{sub x}FeMoO{sub 6} (x=0.0, 0.1, 0.2, 0.4) materials have been synthesized by a citrate co-precipitation method and studied by neutron powder diffraction (NPD) and magnetization measurements. Rietveld analysis of the temperature-dependent NPD data shows that the compounds (x=0.0, 0.1, 0.2) crystallize in the tetragonal symmetry in the range 10-400K and converts to cubic symmetry above 450K. The unit cell volume increases with increasing Nd{sup 3+} concentration, which is an electronic effect in order to change the valence state of the B-site cations. Antisite defects at the Fe-Mo sublattice increases with the Nd{sup 3+} doping. The Curie temperature wasmore » increased from 430K for x=0 to 443K for x=0.4. The magnetic moment of the Fe-site decreases while the Mo-site moment increases with electron doping. The antiferromagnetic arrangement causes the system to show a net ferrimagnetic moment.« less
Reexamining X-mode suppression and fine structure in artificial E region field-aligned plasma density irregularities

NASA Astrophysics Data System (ADS)

Miceli, R. J.; Hysell, D. L.; Munk, J.; McCarrick, M.; Huba, J. D.

2013-09-01

Artificial field-aligned plasma density irregularities (FAIs) were generated in the E region of the ionosphere above the High Frequency Active Auroral Research Program facility during campaigns in May and August of 2012 and observed using a 30 MHz coherent scatter radar imager in Homer, Alaska. The purpose of this ionospheric modification experiment was to measure the threshold pump power required to excite thermal parametric instabilities by O-mode heating and to investigate the suppression of the FAIs by simultaneous X-mode heating. We find that the threshold pump power for irregularity excitation was consistent with theoretical predictions and increased by approximately a factor of 2 when X-mode heating was present. A modified version of the Another Model of the Ionosphere (SAMI2) ionospheric model was used to simulate the threshold experiments and suggested that the increase was entirely due to enhanced D region absorption associated with X-mode heating. Additionally, a remarkable degree of fine structure possibly caused by natural gradient drift instability in the heater-modified volume was observed in experiments performed during geomagnetically active conditions.
Coexistence of superconductivity and short-range double-stripe spin correlations in Te-vapor annealed FeTe 1–xSe x with x ≤ 0.2

DOE PAGES

Xu, Zhijun; Tranquada, John M.; Schneeloch, J. A.; ...

2018-06-30

In as-grown bulk crystals of Fe 1+yTe 1–xSe x with x ≲ 0.3, excess Fe (y > 0) is inevitable and correlates with a suppression of superconductivity. At the same time, t here remains the question as to whether the character of the antiferromagnetic correlations associated wi th the enhanced anion height above the Fe planes in Te-rich samples is compatible with superconductivity. To t est this, we have annealed as-grown crystals with x = 0.1 and 0.2 in Te vapor, effectively reducing the excess Fe and in ducing bulk superconductivity. Inelastic neutron scattering measurements reveal low-energy magnet ic excitationsmore » consistent with short-range correlations of the double-stripe type; nevertheless, cooling int o the superconducting state results in a spin gap and a spin resonance, with the extra signal in the resonance being short-range with a mixed single-stripe/double-stripe character, which is different than other iron-based superconductors. In conclusion, the mixed magnetic character of these superconducting samples does not appear to be trivially explainable by inhomogeneity.« less
Coexistence of superconductivity and short-range double-stripe spin correlations in Te-vapor annealed FeTe 1–xSe x with x ≤ 0.2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Zhijun; Tranquada, John M.; Schneeloch, J. A.

In as-grown bulk crystals of Fe 1+yTe 1–xSe x with x ≲ 0.3, excess Fe (y > 0) is inevitable and correlates with a suppression of superconductivity. At the same time, t here remains the question as to whether the character of the antiferromagnetic correlations associated wi th the enhanced anion height above the Fe planes in Te-rich samples is compatible with superconductivity. To t est this, we have annealed as-grown crystals with x = 0.1 and 0.2 in Te vapor, effectively reducing the excess Fe and in ducing bulk superconductivity. Inelastic neutron scattering measurements reveal low-energy magnet ic excitationsmore » consistent with short-range correlations of the double-stripe type; nevertheless, cooling int o the superconducting state results in a spin gap and a spin resonance, with the extra signal in the resonance being short-range with a mixed single-stripe/double-stripe character, which is different than other iron-based superconductors. In conclusion, the mixed magnetic character of these superconducting samples does not appear to be trivially explainable by inhomogeneity.« less
Explosive Magnetic Reconnection in Double-current Sheet Systems: Ideal versus Resistive Tearing Mode

NASA Astrophysics Data System (ADS)

Baty, Hubert

2017-03-01

Magnetic reconnection associated with the tearing instability occurring in double-current sheet systems is investigated within the framework of resistive magnetohydrodynamics (MHD) in a two-dimensional Cartesian geometry. A special emphasis on the existence of fast and explosive phases is taken. First, we extend the recent theory on the ideal tearing mode of a single-current sheet to a double-current layer configuration. A linear stability analysis shows that, in long and thin systems with (length to shear layer thickness) aspect ratios scaling as {S}L9/29 (S L being the Lundquist number based on the length scale L), tearing modes can develop on a fast Alfvénic timescale in the asymptotic limit {S}L\\to ∞ . The linear results are confirmed by means of compressible resistive MHD simulations at relatively high S L values (up to 3× {10}6) for different current sheet separations. Moreover, the nonlinear evolution of the ideal double tearing mode (IDTM) exhibits a richer dynamical behavior than its single-tearing counterpart, as a nonlinear explosive growth violently ends up with a disruption when the two current layers interact trough the merging of plasmoids. The final outcome of the system is a relaxation toward a new state, free of magnetic field reversal. The IDTM dynamics is also compared to the resistive double tearing mode dynamics, which develops in similar systems with smaller aspect ratios, ≳ 2π , and exhibits an explosive secondary reconnection, following an initial slow resistive growth phase. Finally, our results are used to discuss the flaring activity in astrophysical magnetically dominated plasmas, with a particular emphasis on pulsar systems.
Normal Mode Analysis of Polytheonamide B

NASA Astrophysics Data System (ADS)

Mori, Takaharu; Kokubo, Hironori; Shimizu, Hirofumi; Iwamoto, Masayuki; Oiki, Shigetoshi; Okamoto, Yuko

2007-09-01

Polytheonamide B is a linear 48-residue peptide which forms a single β-helix structure with alternating d- and l-amino acids and contains methylated and hydroxy variants of proteinogenic amino acids. To investigate the dynamical properties of polytheonamide B we perform the normal mode analysis. Root-mean-square displacements of all backbone atoms, root-mean-square fluctuations of the backbone dihedral angles (φ,\\psi), and correlation factors for the Cα atom fluctuations and for the dihedral angle fluctuations are calculated. The normal mode analysis reveals that polytheonamide B shows the elastic rod behavior in the very low-frequency regions and that librational motions of backbone amide planes have the modes with relatively low frequencies, which is relevant to the function of polytheonamide B. In addition, these librational motions occur almost independently and weakly anticorrelate with those of the hydrogen-bonded neighboring amide planes. Calculations of the backbone fluctuations show that the flexibility of polytheonamide B is roughly uniform over the entire helix. We compare our results with those of gramicidin A, the analogue of polytheonamide B, to discuss the structures and functions, and obtain some common features in the flexibilities and dynamics of the backbone atoms. These results present important clues for clarifying the function of polytheonamide B at the atomic level.
Magnetisation studies of phase co-existence in Gd{sub 1-x}Ca{sub x}BaCo{sub 2}O{sub 5.5}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thirumurugan, N.; Bharathi, A., E-mail: bharathi@igcar.gov.in; Arulraj, A.

2012-04-15

Highlights: Black-Right-Pointing-Pointer The series Gd{sub 1-x}Ca{sub x}BaCo{sub 2}O{sub 5.5} was synthesised by solid state reaction. Black-Right-Pointing-Pointer Magnetisation studies were carried out in the 4-300 K temperature range in magnetic fields upto 16 Tesla. Black-Right-Pointing-Pointer Results were used to formulate the T versus Ca fraction, phase diagram. Black-Right-Pointing-Pointer Evidence for Magnet-electronic phase separation is shown for the first time in the compound. -- Abstract: Magnetic properties of hole doped, oxygen deficient double perovskite compounds, Gd{sub 1-x}Ca{sub x}BaCo{sub 2}O{sub 5.5}, have been investigated. Ferromagnetic transition temperatures increase and the anti-ferromagnetic transition temperatures decrease with Ca substitution leading to stabilisation of ferromagnetisim formore » x {>=} 0.05. A detailed study of the ferromagnetic phase indicates the presence of double hysterisis loops for Ca fractions, 0.05 {<=} x {<=} 0.2 in the 50-200 K temperature range, suggestive of the co-existence of two ferromagnetic phases with different co-ercivities. Based on the magnetisation and transport measurements a phase diagram is proposed for Ca doped GdBaCo{sub 2}O{sub 5.5}.« less
Non-Gaussian structure of B-mode polarization after delensing

NASA Astrophysics Data System (ADS)

Namikawa, Toshiya; Nagata, Ryo

2015-10-01

The B-mode polarization of the cosmic microwave background on large scales has been considered as a probe of gravitational waves from the cosmic inflation. Ongoing and future experiments will, however, suffer from contamination due to the B-modes of non-primordial origins, one of which is the lensing induced B-mode polarization. Subtraction of the lensing B-modes, usually referred to as delensing, will be required for further improvement of detection sensitivity of the gravitational waves. In such experiments, knowledge of statistical properties of the B-modes after delensing is indispensable to likelihood analysis particularly because the lensing B-modes are known to be non-Gaussian. In this paper, we study non-Gaussian structure of the delensed B-modes on large scales, comparing it with that of the lensing B-modes. In particular, we investigate the power spectrum correlation matrix and the probability distribution function (PDF) of the power spectrum amplitude. Assuming an experiment in which the quadratic delensing is an almost optimal method, we find that delensing reduces correlations of the lensing B-mode power spectra between different multipoles, and that the PDF of the power spectrum amplitude is well described as a normal distribution function with a variance larger than that in the case of a Gaussian field. These features are well captured by an analytic model based on the 4th order Edgeworth expansion. As a consequence of the non-Gaussianity, the constraint on the tensor-to-scalar ratio after delensing is degraded within approximately a few percent, which depends on the multipole range included in the analysis.
Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ∞} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4−x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1−x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, J. Palmer; Sulejmanovic, Dino; Becht, Gregory

2013-10-15

Crystals of Sr{sub 4−x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x∼0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x∼0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ∞} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{submore » 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4−x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1−x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4−x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1−x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1−x
Double-inversion mechanisms of the X⁻ + CH₃Y [X,Y = F, Cl, Br, I] SN2 reactions.

PubMed

Szabó, István; Czakó, Gábor

2015-03-26

The double-inversion and front-side attack transition states as well as the proton-abstraction channels of the X(-) + CH3Y [X,Y = F, Cl, Br, I] reactions are characterized by the explicitly correlated CCSD(T)-F12b/aug-cc-pVTZ(-PP) level of theory using small-core relativistic effective core potentials and the corresponding aug-cc-pVTZ-PP bases for Br and I. In the X = F case the double-inversion classical(adiabatic) barrier heights are 28.7(25.6), 15.8(13.4), 13.2(11.0), and 8.6(6.6) kcal mol(-1) for Y = F, Cl, Br, and I, respectively, whereas the barrier heights are in the 40-90 kcal mol(-1) range for the other 12 reactions. The abstraction channels are always above the double-inversion saddle points. For X = F, the front-side attack classical(adiabatic) barrier heights, 45.8(44.8), 31.0(30.3), 24.7(24.2), and 19.5(19.3) kcal mol(-1) for Y = F, Cl, Br, and I, respectively, are higher than the corresponding double-inversion ones, whereas for the other systems the front-side attack saddle points are in the 35-70 kcal mol(-1) range. The double-inversion transition states have XH···CH2Y(-) structures with Cs point-group symmetry, and the front-side attack saddle points have either Cs (X = F or X = Y) or C1 symmetry with XCY angles in the 78-88° range. On the basis of the previous reaction dynamics simulations and the minimum energy path computations along the inversion coordinate of selected XH···CH2Y(-) systems, we suggest that the double inversion may be a general mechanism for SN2 reactions.
FIBER AND INTEGRATED OPTICS: Bandgap modes in a coupled waveguide array

NASA Astrophysics Data System (ADS)

Usievich, B. A.; Nurligareev, D. Kh; Svetikov, V. V.; Sychugov, V. A.

2009-08-01

This work examines a waveguide array that consists of ten Nb2O5/SiO2 double layers and supports a 0.63-μm surface wave. The deposition of a Nb2O5 capping layer on top of the waveguide array enables a marked increase in the wave field intensity on its surface. The efficiency of surface-wave excitation in the Kretschmann configuration can be optimised by adjusting the number of double layers. We analyse the behaviour of the Bragg mode in relation to the thickness of the layer exposed to air and the transition of this mode from the second allowed band to the first through the bandgap of the system. In addition, the conventional leaky mode converts to a surface mode and then to a guided mode.
Probing structural changes in Ca(1-x)Nd2x/3TiO3 ceramics by Raman spectroscopy

NASA Astrophysics Data System (ADS)

Lowndes, Robert; Deluca, Marco; Azough, Feridoon; Freer, Robert

2013-01-01

Ceramics in the system Ca(1-x)Nd2x/3TiO3, intended for mobile communication applications, exhibit grossly non-linear variations in microwave dielectric properties with composition. There is evidence of a structural transition and the formation of vacancies on the A-site of the perovskite structure. High density, single phase perovskite Ca(1-x)Nd2x/3TiO3 ceramics have been prepared by the mixed oxide route. Raman spectroscopy was used to investigate the structural variations, which impact on dielectric properties. The Raman spectra show that with increasing Nd content, there is a transition from an ordered structure, to a disordered arrangement of cations and vacancies, and back to an ordered arrangement in Ca0.1Nd0.6TiO3. A structural phase transition from orthorhombic Pbnm to monoclinic C2/m coincides with the order-disorder transition at Ca0.1Nd0.6TiO3. Polarized Raman spectroscopy facilitated the assignment of the Raman modes and investigation of the role of importance of domain structures. Large variation in the plane angles was attributed to differences in domain structures. Differences in the angular dependence of the Raman modes with Nd content reflect changes in the preferred orientation of the domains from lamellar twins, to wedge shaped and back to lamellar twins.
Double Alfvén waves

NASA Astrophysics Data System (ADS)

Webb, G. M.; Hu, Q.; Dasgupta, B.; Zank, G. P.

2012-02-01

Double Alfvén wave solutions of the magnetohydrodynamic equations in which the physical variables (the gas density ρ, fluid velocity u, gas pressure p, and magnetic field induction B) depend only on two independent wave phases ϕ1(x,t) and ϕ2(x,t) are obtained. The integrals for the double Alfvén wave are the same as for simple waves, namely, the gas pressure, magnetic pressure, and group velocity of the wave are constant. Compatibility conditions on the evolution of the magnetic field B due to changes in ϕ1 and ϕ2, as well as constraints due to Gauss's law ∇ · B = 0 are discussed. The magnetic field lines and hodographs of B in which the tip of the magnetic field B moves on the sphere |B| = B = const. are used to delineate the physical characteristics of the wave. Hamilton's equations for the simple Alfvén wave with wave normal n(ϕ), and with magnetic induction B(ϕ) in which ϕ is the wave phase, are obtained by using the Frenet-Serret equations for curves x=X(ϕ) in differential geometry. The use of differential geometry of 2D surfaces in a 3D Euclidean space to describe double Alfvén waves is briefly discussed.
Non-Gaussian structure of B-mode polarization after delensing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Namikawa, Toshiya; Nagata, Ryo, E-mail: namikawa@slac.stanford.edu, E-mail: rnagata@post.kek.jp

2015-10-01

The B-mode polarization of the cosmic microwave background on large scales has been considered as a probe of gravitational waves from the cosmic inflation. Ongoing and future experiments will, however, suffer from contamination due to the B-modes of non-primordial origins, one of which is the lensing induced B-mode polarization. Subtraction of the lensing B-modes, usually referred to as delensing, will be required for further improvement of detection sensitivity of the gravitational waves. In such experiments, knowledge of statistical properties of the B-modes after delensing is indispensable to likelihood analysis particularly because the lensing B-modes are known to be non-Gaussian. Inmore » this paper, we study non-Gaussian structure of the delensed B-modes on large scales, comparing it with that of the lensing B-modes. In particular, we investigate the power spectrum correlation matrix and the probability distribution function (PDF) of the power spectrum amplitude. Assuming an experiment in which the quadratic delensing is an almost optimal method, we find that delensing reduces correlations of the lensing B-mode power spectra between different multipoles, and that the PDF of the power spectrum amplitude is well described as a normal distribution function with a variance larger than that in the case of a Gaussian field. These features are well captured by an analytic model based on the 4th order Edgeworth expansion. As a consequence of the non-Gaussianity, the constraint on the tensor-to-scalar ratio after delensing is degraded within approximately a few percent, which depends on the multipole range included in the analysis.« less
Non-Gaussian structure of B-mode polarization after delensing

DOE PAGES

Namikawa, Toshiya; Nagata, Ryo

2015-10-01

The B-mode polarization of the cosmic microwave background on large scales has been considered as a probe of gravitational waves from the cosmic inflation. Ongoing and future experiments will, however, suffer from contamination due to the B-modes of non-primordial origins, one of which is the lensing induced B-mode polarization. Subtraction of the lensing B-modes, usually referred to as delensing, will be required for further improvement of detection sensitivity of the gravitational waves. In such experiments, knowledge of statistical properties of the B-modes after delensing is indispensable to likelihood analysis particularly because the lensing B-modes are known to be non-Gaussian. Inmore » this paper, we study non-Gaussian structure of the delensed B-modes on large scales, comparing it with that of the lensing B-modes. In particular, we investigate the power spectrum correlation matrix and the probability distribution function (PDF) of the power spectrum amplitude. Assuming an experiment in which the quadratic delensing is an almost optimal method, we find that delensing reduces correlations of the lensing B-mode power spectra between different multipoles, and that the PDF of the power spectrum amplitude is well described as a normal distribution function with a variance larger than that in the case of a Gaussian field. These features are well captured by an analytic model based on the 4th order Edgeworth expansion. Furthermore, as a consequence of the non-Gaussianity, the constraint on the tensor-to-scalar ratio after delensing is degraded within approximately a few percent, which depends on the multipole range included in the analysis.« less
Exploring anti-correlated radio/X-ray modes in transitional millisecond pulsars

NASA Astrophysics Data System (ADS)

Jaodand, Amruta

2017-09-01

Recently, using coordinated VLA+Chandra observations, Bogdanov et al.(2017) have uncovered a stunning anti-correlation in the LMXB state of the tMSP PSR J1023+0038. They see that radio luminosity consistently peaks during the X-ray `low' luminosity modes. Also, we have found a promising candidate tMSP, 3FGL J1544-1125(J1544) (Bogdanov and Halpern 2015; currently only tMSP candidate apart from J1023 in a persistent LMXB state). Using VLA and simultaneous Swift observations we see that it lies on the proposed tMSP track in radio vs. X-ray luminosity (L_ R/L_X) diagram. This finding strengthens its classification as a tMSP and provides an excellent opportunity to a)determine universality of radio/X-ray brightness anti-correlatio and b)understand jet/outflow formation in tMSPs.
Physical and optical studies of BaO-TeO2-TiO2-B2O3 glasses containing Cu2+ transition metal ion

NASA Astrophysics Data System (ADS)

Srinivas, B.; Kumar, R. Vijaya; Hameed, Abdul; Sagar, D. Karuna; Chary, M. Narasimha; Shareefuddin, Md.

2018-05-01

Glasses with the composition xBaO-(30-x) TeO2-10TiO2-59B2O3-1CuO (where x = 10, 15, 20 and 25 mole %) were prepared by melt quenching technique. The XRD studies were made on these glass samples at room temperature. The amorphous nature of the glass samples was confirmed from the XRD patterns. The physical parameters such as density (ρ), molar volume (Vm), average boron-boron separation (dB-B) and oxygen packing density (OPD) were calculated. The change in density and molar volume has been investigated in terms of the variation of BaO in the glass composition. The optical absorption spectra have been recorded at room temperature. The values of optical band gap have been estimated from the ASF and Tauc's methods. Both Tauc's and ASF methods have been showing progressively increasing indirect optical band gap values with the increase of BaO concentrations.
Effect of double layer thickness on magnetoelectric coupling in multiferroic BaTiO3-Bi0.95Gd0.05FeO3 multilayers

NASA Astrophysics Data System (ADS)

Hohenberger, S.; Lazenka, V.; Temst, K.; Selle, S.; Patzig, C.; Höche, T.; Grundmann, M.; Lorenz, M.

2018-05-01

The effect of double-layer thickness and partial substitution of Bi3+ by Gd3+ is demonstrated for multiferroic BaTiO3–BiFeO3 2–2 heterostructures. Multilayers of 15 double layers of BaTiO3 and Bi0.95Gd0.05FeO3 were deposited onto (0 0 1) oriented SrTiO3 substrates by pulsed laser deposition with various double layer thicknesses. X-ray diffraction and high resolution transmission electron microscopy investigations revealed a systematic strain tuning with layer thickness via coherently strained interfaces. The multilayers show increasingly enhanced magnetoelectric coupling with reduced double layer thickness. The maximum magnetoelectric coupling coefficient was measured to be as high as 50.8 V cm‑1 Oe‑1 in 0 T DC bias magnetic field at room temperature, and 54.9 V cm‑1 Oe‑1 above 3 T for the sample with the thinnest double layer thickness of 22.5 nm. This enhancement is accompanied by progressively increasing perpendicular magnetic anisotropy and compressive out-of-plane strain. To understand the origin of the enhanced magnetoelectric coupling in such multilayers, the temperature and magnetic field dependency of is discussed. The magnetoelectric performance of the Gd3+ substituted samples is found to be slightly enhanced when compared to unsubstituted BaTiO3–BiFeO3 multilayers of comparable double-layer thickness.

Antisite-disorder, magnetic and thermoelectric properties of Mo-rich Sr2Fe1-yMo1+yO6 (0 ≤y≤ 0.2) double perovskites.

PubMed

Popuri, Srinivasa R; Redpath, Debbie; Chan, Gavin; Smith, Ronald I; Cespedes, Oscar; Bos, Jan-Willem G

2015-06-21

Structure analysis using X-ray and neutron powder diffraction and elemental mapping has been used to demonstrate that nominal A-site deficient Sr(2-x)FeMoO(6-δ) (0 ≤x≤ 0.5) compositions form as Mo-rich Sr(2)Fe(1-y)Mo(1+y)O(6) (0 ≤y≤ 0.2) perovskites at high temperatures and under reducing atmospheres. These materials show a gradual transition from the Fe and Mo rock salt ordered double perovskite structure to a B-site disordered arrangement. Analysis of the fractions of B-O-B' linkages revealed a gradual increase in the number of Mo-O-Mo linkages at the expense of the ferrimagnetic (FIM) Fe-O-Mo linkages that dominate the y = 0 material. All samples contain about 10-15% antiferromagnetic (AF) Fe-O-Fe linkages, independent of the degree of B-site ordering. The magnetic susceptibility of the y = 0.2 sample is characteristic of a small domain ferrimagnet (T(c)∼ 250 K), while room temperature neutron powder diffraction demonstrated the presence of G-type AF ordering linked to the Fe-O-Fe linkages (m(Fe) = 1.25(7)μ(B)). The high temperature thermoelectric properties are characteristic of a metal with a linear temperature dependence of the Seebeck coefficient, S (for all y) and electrical resistivity ρ (y≥ 0.1). The largest thermoelectric power factor S(2)/ρ = 0.12 mW m(-1) K(-1) is observed for Sr(2)FeMoO(6) at 1000 K.
Magnetic properties of Zn1-xNixO

NASA Astrophysics Data System (ADS)

Mondal, A.; Giri, N.; Sarkar, S.; Ray, Ruma

2018-05-01

Ni doped ZnO (Zn1-xNixO for 0.01 ≤ x ≤ 0.11) have been prepared by chemical precipitation method. X-ray diffraction corroborates a hexagonal wurzite structure without any impurity phases upto 11% Ni doping. Morphology of the particles is investigated by FE-SEM which exhibits either rod or tube like structure depending on the dopant concentration. Magnetization of Zn1-xNixO for 0.03 ≤ x ≤ 0.11 measured at room temperature infers the paramagnetic behavior. Zero field cooled and field cooled magnetization for x = 0.11 follows Curie-Weiss behavior above 122 K with effective paramagnetic moment 3.9μB. The non-linear magnetic hysteresis loop at 2 K with a small coercivity (300 Oe) indicates signature of ferromagnetic ordering.
Clinical Significance of "Double-hit" and "Double-protein" expression in Primary Gastric B-cell Lymphomas.

PubMed

He, Miaoxia; Chen, Keting; Li, Suhong; Zhang, Shimin; Zheng, Jianming; Hu, Xiaoxia; Gao, Lei; Chen, Jie; Song, Xianmin; Zhang, Weiping; Wang, Jianmin; Yang, Jianmin

2016-01-01

Primary gastric B-cell lymphoma is the second most common malignancy of the stomach. There are many controversial issues about its diagnosis, treatment and clinical management. "Double-hit" and "double-protein" involving gene rearrangement and protein expression of c-Myc and bcl2/bcl6 are the most used terms to describe DLBCL poor prognostic factors in recent years. However, very little is known about the role of these prognostic factors in primary gastric B-cell lymphomas. This study aims to obtain a molecular pathology prognostic model of gastric B-cell lymphoma for clinical stratified management by evaluating how the "double-hit" and "double-protein" in tumor cells as well as microenvironmental reaction of tumor stromal tissue affect clinical outcome in primary gastric B-cell lymphomas. Data and tissues of 188 cases diagnosed with gastric B-cell lymphomas were used in this study. Tumor tissue microarray (TMA) of formalin fixed and paraffin embedded (FFPE) tissues was constructed for fluorescence in situ hybridization (FISH) and immunohistochemistry (IHC) analysis with a serial of biomarkers containing MYC, BCL2, BCL6, CD31, SPARC, CD10, MUM1 and Ki-67. Modeled period analysis was used to estimate 3-year and 5-year overall survival (OS) and disease-free survival (DFS) distributions. There was no definite "double-hit" case though the gene rearrangement of c-Myc (5.9%), bcl2 (0.1%) and bcl6 (7.4%) was found in gastric B-cell lymphomas. The gene amplification or copy gains of c-Myc (10.1%), bcl-2 (17.0%) and bcl-6 (0.9%) were present in these lymphomas. There were 12 cases of the lymphomas with the "double-protein" expression of MYC and BCL2/BCL6. All patients with "double-protein" gastric B-cell lymphomas had poor outcome compared with those without. More importantly, "MYC-BCL2-BCL6" negative group of gastric B-cell lymphoma patients had favorable clinical outcome regardless clinical stage, pathological types and therapeutic modalities. And the similar better
High-Resolution Laser Spectroscopy of the tilde{B} ← tilde{X} Transition of 14NO3 Radical: Vibrationally Excited States of the tilde{B} State

NASA Astrophysics Data System (ADS)

Kasahara, Shunji; Tada, Kohei; Hirata, Michihiro; Ishiwata, Takashi; Hirota, Eizi

2016-06-01

Rotationally-resolved high-resolution fluorescence excitation spectra of the tilde{B} 2E' ← tilde{X} 2A2' electronic transition of 14NO3 radical have been observed for 15860-15920 cm-1 region. Sub-Doppler excitation spectra were measured by crossing a single-mode laser beam perpendicular to a collimated radical beam, which was formed by the heat decomposition of 14N2O5; 14N2O5 → 14NO3 + 14NO2. We have also measured the high-resolution fluorescence excitation spectra of the 14NO2 tilde{A} 2B{2} ← tilde{X} 2A1 transition to distinguish the 14NO3 signals from the 14NO2 signals in the observed region. The typical linewidth was 30 MHz and the absolute wavenumber was calibrated with accuracy 0.0001 cm-1 by measurement of the Doppler-free saturation spectrum of iodine molecule and fringe pattern of the stabilized etalon. The observed rotational lines were too complicated to find any rotational series. In the observed spectra, only the rotational line pairs from the tilde{X} 2A2'(v''=0, K''=0, N''=1, F1 and F2) levels are assigned unambiguously by using the combination differences of the tilde{X} 2A2' state and measurement of the Zeeman splittings similar to the analysis of the 0-0 band at around 15100 cm-1 region. The observed results suggest the observed vibrationally excited states of the tilde{B} 2E' state are also interacts with the other vibronic levels similar to the tilde{B} 2E'(v'=0) level. K. Tada, W. Kashihara, M. Baba, T. Ishiwata, E. Hirota, and S. Kasahara, J. Chem. Physc. 141, 184307 (2014). K. Tada, T. Ishiwata, E. Hirota, and S. Kasahara, J. Mol. Spectrosc., 321, 23 (2016)
Deposition and characterization of B4C/CeO2 multilayers at 6.x nm extreme ultraviolet wavelengths

NASA Astrophysics Data System (ADS)

Sertsu, M. G.; Giglia, A.; Brose, S.; Park, D.; Wang, Z. S.; Mayer, J.; Juschkin, L.; Nicolosi, P.

2016-03-01

New multilayers of boron carbide/cerium dioxide (B4C/CeO2) combination on silicon (Si) substrate are manufactured to represent reflective-optics candidates for future lithography at 6.x nm wavelength. This is one of only a few attempts to make multilayers of this kind. Combination of several innovative experiments enables detailed study of optical properties, structural properties, and interface profiles of the multilayers in order to open up a room for further optimization of the manufacturing process. The interface profile is visualized by high-angle annular dark-field imaging which provides highly sensitive contrast to atomic number. Synchrotron based at-wavelength extreme ultraviolet (EUV) reflectance measurements near the boron (B) absorption edge allow derivation of optical parameters with high sensitivity to local atom interactions. X-ray reflectivity measurements at Cu-Kalpha (8 keV ) determine the period of multilayers with high in-depth resolution. By combining these measurements and choosing robust nonlinear curve fitting algorithms, accuracy of the results has been significantly improved. It also enables a comprehensive characterization of multilayers. Interface diffusion is determined to be a major cause for the low reflectivity performance. Optical constants of B4C and CeO2 layers are derived in EUV wavelengths. Besides, optical properties and asymmetric thicknesses of inter-diffusion layers (interlayers) in EUV wavelengths near the boron edge are determined. Finally, ideal reflectivity of the B4C/CeO2 combination is calculated by using optical constants derived from the proposed measurements in order to evaluate the potentiality of the design.
Phase transformation, improved ferroelectric and magnetic properties of (1 − x) BiFeO{sub 3}–xPb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} solid solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Subhash, E-mail: rk.dwivedi@jiit.ac.in, E-mail: subhash1jiit@gmail.com; Singh, Vikash; Dwivedi, R. K., E-mail: rk.dwivedi@jiit.ac.in, E-mail: subhash1jiit@gmail.com

2014-06-14

The authors prepared (1 − x)BiFeO{sub 3} – (x)Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} for x ≤ 0.30 by sol-gel method and investigated the material's structures, magnetic and electrical properties. Detailed Rietveld analysis of X-ray diffraction data revealed that the system retains distorted rhombohedral R3c structure for x ≤ 0.10 but transforms to monoclinic (Cc) structure for x > 0.10. Disappearance of some Raman modes corresponding to A1 modes and the decrease in the intensities of the remaining A1 modes with increasing x in the Raman spectra, which is a clear indication of structural modification and symmetry changes brought about by PZT doping. Enhanced magnetization with PZT doping content maymore » be attributed to the gradual change and destruction in the spin cycloid structure of BiFeO{sub 3.} The leakage current density at 3.5 kV/cm was reduced by approximately three orders of magnitude by doping PZT (x = 0.30), compared with BFO ceramics.« less
Reactions of the linear tetranuclear complex Ru sub 4 (CO) sub 10 (CH sub 3 C double bond C(H)C(H) double bond N-i-Pr) sub 2 with oxidizing reagents. Syntheses of halide-bridged (Ru(CO) sub 2 X(CH sub 3 C double bond C(H)C(H) double bond N-i-Pr)) sub 2 and fac-Ru(CO) sub 3 X(CH sub 3 C double bond C(H)C(H) double bond N-i-Pr)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mul, W.P.; Elsevier, C.J.; van Leijen, M.

1991-01-01

The linear tetranuclear complex Ru{sub 4}(CO){sub 10}(CH{sub 3}C{double bond}C(H)C(H){double bond}N-i-Pr){sub 2} (1), containing two {eta}{sup 5}-azaruthenacyclopentadienyl systems, reacts with oxidizing reagents (I{sub 2}, Br{sub 2}, NBS, CCl{sub 4}) at elevated temperatures (40-90C) in heptane or benzene to give the new dimeric halide-bridged organoruthenium(II) complexes (Ru(CO){sub 2}X(CH{sub 3}C{double bond}C(H)C(H){double bond}N-i-Pr)){sub 2} (X = I (3a), X = Br (3b), Cl (3c); yield 30-80%) together with (Ru(CO){sub 3}X{sub 2}){sub 2}. The reactions of 1 with CX{sub 4} (X = I, Br, Cl) are accelerated by CO, probably because Ru{sub 4}(CO){sub 12}(CH{sub 3}C{double bond}C(H)C(H){double bond}N-i-Pr){sub 2} (5), which contains two unbridged metal-metal bonds,more » is formed prior to oxidation. The halide-bridged dimers 3a-c are obtained as mixtures of four isomers, the configurations of which are discussed. Splitting of the halide bridges takes place when a solution of 3a-c is saturated with CO, whereby mononuclear fac-Ru(CO){sub 3}X(CH{sub 3}C{double bond}C(H)C(H){double bond}N-i-Pr) (4a-c) is obtained. This process is reversible; ie., passing a stream of nitrogen through a solution of 4a-c or removal of the solvent under vacuum causes the reverse reaction with reformation of 3a-c. Compounds 3a-c and 4a-c have been characterized by IR (3, 4), FD mass (3), {sup 1}H (3, 4), and {sup 13}C{l brace}H{r brace} NMR (4) spectroscopy and satisfactory elemental analyses have been obtained for 3a-c. Compounds 3 and 4 are suitable precursors for the preparation of new homo- and heteronuclear transition-metal complexes.« less
Structural, optical, physical and electrical properties of V2O5.SrO.B2O3 glasses.

PubMed

Sindhu, S; Sanghi, S; Agarwal, A; Seth, V P; Kishore, N

2006-05-01

The present work aims to study the structure and variation of optical band gap, density and dc electrical conductivity in vanadium strontium borate glasses. The glass systems xV2O5.(40-x)SrO.60B2O3 and xV2O5.(60-x)B2O3.40SrO with x varying from 0 to 20 mol% were prepared by normal melt quench technique. Structural studies were made by recording IR transmission spectra. The fundamental absorption edge for all the glasses was analyzed in terms of the theory proposed by Davis and Mott. The position of absorption edge and hence the value of the optical band gap was found to depend on the semiconducting glass composition. The absorption in these glasses is believed to be associated with indirect transitions. The origin of Urbach energy is associated with the phonon-assisted indirect transitions. The change in both density and molar volume was discussed in terms of the structural modifications that take place in the glass matrix on addition of V2O5. dc conductivity of the glass systems is also reported. The change of conductivity and activation energy with composition indicates that the conduction process varies from ionic to polaronic one.
Magnetic properties of x(Fe2O3).(100-x)[P2O5.Li2O] and x(Fe2O3).(100-x)[P2O5.CaO] glass systems

NASA Astrophysics Data System (ADS)

Andronache, Constantin; Racolta, Dania; Ardelean, Gheorghe

2017-12-01

Magnetic properties of x(Fe2O3).(100-x)[P2O5 .Li2O] and x(Fe2O3).(100-x)[P2O5 .CaO] with 0 < x ≤ 50 mol % were investigated using magnetic susceptibility measurements. The both glass systems were prepared in the same condition. The valence states and the distribution of iron ions in the glass matrix depend on the Fe2O3 content. For the P2O5.CaO glass matrix with x≤35mol%, the data revealed iron ions as isolated or participating in dipole-dipole interaction. For x > 35 mol% an antiferromagnetic coupling is observed. For the P2O5.Li2O glass matrix, the iron ions behave magnetically similarly as in other oxide glasses, but concentration of Fe2O3 over which magnetic superexchange interactions occur is lower. The absolute magnitude of θp values increases when content of Fe2O3 are increased. If the content of the magnetic ions is increased in the glass, the exchange integral increased and as a result the magnitude of the θP increases.
Frustration by competing interactions in the highly-distorted double perovskites La2NaRuO6 and La2NaOsO6

NASA Astrophysics Data System (ADS)

Aczel, A. A.; Bugaris, D. E.; Li, L.; Yan, J.-Q.; de La Cruz, C.; Zur Loye, H.-C.; Nagler, S. E.

2013-03-01

The usual classical behavior of S = 3/2, B-site ordered double perovskites results in simple, commensurate magnetic ground states. In contrast, heat capacity and neutron powder diffraction measurements for the S = 3/2 systems La2NaB'O6 (B' = Ru, Os) reveal an incommensurate magnetic ground state for La2NaRuO6 and a drastically suppressed ordered moment for La2NaOsO6. This behavior is attributed to the large monoclinic structural distortions of these double perovskites. The distortions have the effect of weakening the nearest neighbor superexchange interactions, presumably to an energy scale that is comparable to the next nearest neighbor superexchange. The exotic ground states in these materials can then arise from a competition between these two types of antiferromagnetic interactions, providing a novel mechanism for achieving frustration in the double perovskite family. Work at ORNL is supported by the Division of Scientific User Facilities and the Materials Science and Engineering Division, DOE Basic Energy Sciences. Work at the University of South Carolina is supported by the Heterogeneous Functional Materials Research Center, funded by DOE under award number de-sc0001061.
Effects of configurational disorder on the elastic properties of icosahedral boron-rich alloys based on B6O, B13C2, and B4C, and their mixing thermodynamics

NASA Astrophysics Data System (ADS)

Ektarawong, A.; Simak, S. I.; Hultman, L.; Birch, J.; Tasnádi, F.; Wang, F.; Alling, B.

2016-04-01

The elastic properties of alloys between boron suboxide (B6O) and boron carbide (B13C2), denoted by (B6O)1-x(B13C2)x, as well as boron carbide with variable carbon content, ranging from B13C2 to B4C are calculated from first-principles. Furthermore, the mixing thermodynamics of (B6O)1-x(B13C2)x is studied. A superatom-special quasirandom structure approach is used for modeling different atomic configurations, in which effects of configurational disorder between the carbide and suboxide structural units, as well as between boron and carbon atoms within the units, are taken into account. Elastic properties calculations demonstrate that configurational disorder in B13C2, where a part of the C atoms in the CBC chains substitute for B atoms in the B12 icosahedra, drastically increase the Young's and shear modulus, as compared to an atomically ordered state, B12(CBC). These calculated elastic moduli of the disordered state are in excellent agreement with experiments. Configurational disorder between boron and carbon can also explain the experimentally observed almost constant elastic moduli of boron carbide as the carbon content is changed from B4C to B13C2. The elastic moduli of the (B6O)1-x(B13C2)x system are also practically unchanged with composition if boron-carbon disorder is taken into account. By investigating the mixing thermodynamics of the alloys, in which the Gibbs free energy is determined within the mean-field approximation for the configurational entropy, we outline the pseudo-binary phase diagram of (B6O)1-x(B13C2)x. The phase diagram reveals the existence of a miscibility gap at all temperatures up to the melting point. Also, the coexistence of B6O-rich as well as ordered or disordered B13C2-rich domains in the material prepared through equilibrium routes is predicted.
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Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-20

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Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study.

PubMed

Xiao, Zewen; Du, Ke-Zhao; Meng, Weiwei; Wang, Jianbo; Mitzi, David B; Yan, Yanfa

2017-05-03

Recently, there has been substantial interest in developing double-B-cation halide perovskites, which hold the potential to overcome the toxicity and instability issues inherent within emerging lead halide-based solar absorber materials. Among all double perovskites investigated, In(I)-based Cs 2 InBiCl 6 and Cs 2 InSbCl 6 have been proposed as promising thin-film photovoltaic absorber candidates, with computational examination predicting suitable materials properties, including direct bandgap and small effective masses for both electrons and holes. In this study, we report the intrinsic instability of Cs 2 In(I)M(III)X 6 (M = Bi, Sb; X = halogen) double perovskites by a combination of density functional theory and experimental study. Our results suggest that the In(I)-based double perovskites are unstable against oxidation into In(III)-based compounds. Further, the results show the need to consider reduction-oxidation (redox) chemistry when predicting stability of new prospective electronic materials, especially when less common oxidation states are involved.
Synthesis, crystal structure and magnetic properties of a new B-site ordered double perovskite Sr{sub 2}CuIrO{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vasala, Sami; Yamauchi, Hisao; Karppinen, Maarit, E-mail: maarit.karppinen@aalto.fi

2014-12-15

Here we synthesize and characterize a new double-perovskite oxide Sr{sub 2}CuIrO{sub 6}. The synthesis requires the use of high oxygen pressure to stabilize the VI oxidation state of iridium. The compound has a tetragonally-distorted crystal structure due to the Jahn–Teller active Cu{sup II} ion, and a high degree of B-site cation order. Magnetic transition is apparent at 15 K, but the zero-field-cooled and field-cooled susceptibilities diverge below this temperature. The high degree of cation order would exclude the possibility of a typical spin-glass, indicating that the divergence is probably due to a frustration of the magnetic interactions between Cu andmore » Ir, with a high frustration factor of f≈25. - Graphical abstract: A new member of the A{sub 2}B′B″O{sub 6} double-perovskite family with JT-active Cu{sup II} at the B′ site and Ir{sup VI} at the B″ site is synthesized through high pressure synthesis and characterized for the structural and magnetic properties. - Highlights: • New member of the A{sub 2}CuB″O{sub 6} double-perovskite family is synthesized with B″=Ir. • Stabilization of Ir{sup VI} requires the use of high oxygen pressure synthesis. • Crystal structure is tetragonally distorted due to JT-active Cu{sup II}. • Divergence of ZFC and FC curves is seen below the T{sub N} of 15 K. • This is presumably due to a frustration effect.« less
Spin and orbital disordering by hole doping in P r1 -xC axV O3

NASA Astrophysics Data System (ADS)

Reehuis, M.; Ulrich, C.; Abdala, P. M.; Pattison, P.; Khaliullin, G.; Fujioka, J.; Miyasaka, S.; Tokura, Y.; Keimer, B.

2016-09-01

High-resolution powder x-ray diffraction and single-crystal neutron diffraction were used to investigate the crystal structure and magnetic ordering of the compound P r1 -xC axV O3 (0 ≤x ≤0.3 ), which undergoes an insulator-to-metal transition for x ˜0.23 . Since the ionic radii of P r3 + and C a2 + are almost identical and structural disorder is minimal, P r1 -xC axV O3 is a good model system for the influence of hole doping on the spin and orbital correlations in transition metal oxides. The end member PrV O3 is a Mott-Hubbard insulator, which exhibits a structural phase transition at TS=180 K from an orthorhombic to a monoclinic structure with space groups Pbnm and P 21/b , respectively. This transition is associated with the onset of orbital ordering and strong Jahn-Teller distortions of the V O6 octahedra. Antiferromagnetic C -type order with vanadium moments oriented in the a b plane is observed below TN=140 K . Upon cooling, the vanadium moments induce a progressive magnetic polarization of the praseodymium sublattice, resulting in a ferrimagnetic structure with coexisting modes (Cx, Fy) and (Fx, Cy). In the insulating range of the P r1 -xC axV O3 phase diagram, Ca doping reduces both the orbital and magnetic transition temperatures so that TS=108 K and TN=95 K for x =0.20 . The Jahn-Teller distortions and ordered vanadium moments also decrease upon doping. In a metallic sample with x =0.30 , Jahn-Teller distortions and long-range orbital ordering are no longer observable, and the average crystal structure remains orthorhombic down to low temperature. However, broadening of some lattice Bragg reflections indicate a significant increase in lattice strain. Antiferromagnetic short-range order with a weak ordered moment of 0.14(3) μB per vanadium atom could still be observed on the vanadium site below T ˜60 K . We discuss these observations in terms of doping-induced spin-orbital polaron formation.
The effect of A-site substitution on the structure and magnetism of Sr2-xPrxFeCoO6 (x = 0, 1, 2)

NASA Astrophysics Data System (ADS)

Haripriya, G. R.; Chakraborty, Debamitra; Pradheesh, R.; Sankaranarayanan, V.; Sethupathi, K.

2018-05-01

The paper presents the variation of structure and magnetism observed with the A-site composition of the double perovskite oxide Sr2-xPrxFeCoO6 (x = 0, 1, 2). The lattice symmetry was found to be lowered from tetragonal (x = 0) to orthorhombic (x = 2). With a ratio 1:1 of Sr and Pr, a highly asymmetric monoclinic structure is observed. The magnetic behavior of the middle member (x = 1) shows resemblance with that of Sr2FeCoO6, indicating the effect of Sr in the dilution of rare earth magnetism.
The photocatalytic properties of hollow (GaN)1-x(ZnO)x composite nanofibers synthesized by electrospinning

NASA Astrophysics Data System (ADS)

Wang, Ding; Zhang, Minglu; Zhuang, Huaijuan; Chen, Xu; Wang, Xianying; Zheng, Xuejun; Yang, Junhe

2017-02-01

(GaN)1-x(ZnO)x composite nanofibers with hollow structure were prepared by initial electrospinning, and the subsequent calcination and nitridation. The structure and morphology characteristics of samples were investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS) and transmission electron microscopy (TEM). The characterization results showed the phase transition from ZnGa2O4 to (GaN)1-x(ZnO)x solid-solution under ammonia atmosphere. The preparation conditions were explored and the optimum nitridation temperature and holding time are 750 °C and 2 h, respectively. The photocatalytic properties of (GaN)1-x(ZnO)x with different Ga:Zn atomic ratios were investigated by degrading Rhodamine B under the visible light irradiation. The photocatalytic activity sequence is (GaN)1-x(ZnO)x (Ga:Zn = 1:2) > (GaN)1-x(ZnO)x (Ga:Zn = 1:3) > ZnO nanofibers > (GaN)1-x(ZnO)x (Ga:Zn = 1:4) > (GaN)1-x(ZnO)x (Ga:Zn = 1:1). The photocatalytic mechanism of the (GaN)1-x(ZnO)x hollow nanofibers was further studied by UV-vis diffuse reflectance spectra. The excellent photocatalytic performance of (GaN)1-x(ZnO)x hollow nanofibers was attributed to the narrow band gap and high surface area of porous nanofibers with hollow structure.
Characterization of the Atacama B-mode Search

NASA Astrophysics Data System (ADS)

Simon, S. M.; Raghunathan, S.; Appel, J. W.; Becker, D. T.; Campusano, L. E.; Cho, H. M.; Essinger-Hileman, T.; Ho, S. P.; Irwin, K. D.; Jarosik, N.; Kusaka, A.; Niemack, M. D.; Nixon, G. W.; Nolta, M. R.; Page, L. A.; Palma, G. A.; Parker, L. P.; Sievers, J. L.; Staggs, S. T.; Visnjic, K.

2014-07-01

The Atacama B-mode Search (ABS), which began observations in February of 2012, is a crossed-Dragone telescope located at an elevation of 5190 m in the Atacama Desert in Chile. ABS is searching for the B-mode polarization spectrum of the cosmic microwave background (CMB) at large angular scales from multipole moments of ` ~ 50 ~ 500, a range that includes the primor- dial B-mode peak from inflationary gravity waves at ~ 100. The ABS focal plane consists of 240 pixels sensitive to 145 GHz, each containing two transition-edge sensor bolometers coupled to orthogonal polarizations with a planar ortho-mode transducer. An ambient-temperature con- tinuously rotating half-wave plate and 4 K optics make the ABS instrument unique. We discuss the characterization of the detector spectral responses with a Fourier transform spectrometer and demonstrate that the pointing model is adequate. We also present measurements of the beam from point sources and compare them with simulations.
Did BICEP2 see vector modes? First B-mode constraints on cosmic defects.

PubMed

Moss, Adam; Pogosian, Levon

2014-05-02

Scaling networks of cosmic defects, such as strings and textures, actively generate scalar, vector, and tensor metric perturbations throughout the history of the Universe. In particular, vector modes sourced by defects are an efficient source of the cosmic microwave background B-mode polarization. We use the recently released BICEP2 and POLARBEAR B-mode polarization spectra to constrain properties of a wide range of different types of cosmic strings networks. We find that in order for strings to provide a satisfactory fit on their own, the effective interstring distance needs to be extremely large--spectra that fit the data best are more representative of global strings and textures. When a local string contribution is considered together with the inflationary B-mode spectrum, the fit is improved. We discuss implications of these results for theories that predict cosmic defects.
Modelling the thermal conductivity of (U xTh 1-x)O 2 and (U xPu 1-x)O 2

DOE PAGES

Cooper, M. W. D.; Middleburgh, S. C.; Grimes, R. W.

2015-07-15

The degradation of thermal conductivity due to the non-uniform cation lattice of (U xTh 1-x)O 2 and (U xPu 1-x)O 2 solid solutions has been investigated by molecular dynamics, using the non-equilibrium method, from 300 to 2000 K. Degradation of thermal conductivity is predicted in (U xTh 1-x)O 2 and (U xPu 1-x)O 2 as compositions deviate from the pure end members: UO 2, PuO 2 and ThO 2. The reduction in thermal conductivity is most apparent at low temperatures where phonon-defect scattering dominates over phonon-phonon interactions. The effect is greater for (U xTh 1-x)O 2 than U xPu 1-x)Omore » 2 due to the greater mismatch in cation size. Parameters for an analytical expressions have been developed that describe the predicted thermal conductivities over the full temperature and compositional ranges. Finally, these expressions may be used in higher level fuel performance codes.« less

DSC and optical studies on BaO-Li{sub 2}O-B{sub 2}O{sub 3}-CuO glass system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhogi, Ashok, E-mail: ashokbhogi@gmail.com; Kumar, R. Vijaya; Ahmmad, Shaik Kareem

2016-05-06

Glasses with composition 15BaO-25Li{sub 2}O-(60-x)B{sub 2}O{sub 3} -xCuO (x= 0, 0.2, 0.4, 0.6, 0.8 and 1 mol%) were prepared by the conventional melt quenching technique. These glasses were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and density measurements. Optical absorption studies were carried out as a function of copper ion concentration. The optical absorption spectra of studied glasses containing copper oxide exhibit a single broad band around 761nm which has been assigned to the 2B{sub 1g}→2B{sub 2g} transition. From these studies, the variations in the values of glass transition temperature (T{sub g}) have been observed. The fundamental absorption edgemore » has been determined from the optical absorption spectra. The values of optical band gap and Urbach energy were determined with increase in concentration of CuO. The variations in density, glass transition temperature, optical band gap and Urbach energy with CuO content have been discussed in terms of changes in the glass structure. The analysis of these results indicated that copper ions mostly exist in Cu{sup 2+} state in these glasses when the concentration of CuO ≤ 0.8 mol% and above this concentration copper ions seem to subsist in Cu{sup 1+} state.« less
Mode-Locked Multichromatic X-Rays in a Seeded Free-Electron Laser for Single-Shot X-Ray Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiang, Dao; Ding, Yuantao; Raubenheimer, Tor

2012-05-10

We present the promise of generating gigawatt mode-locked multichromatic x rays in a seeded free-electron laser (FEL). We show that, by using a laser to imprint periodic modulation in electron beam phase space, a single-frequency coherent seed can be amplified and further translated to a mode-locked multichromatic output in an FEL. With this configuration the FEL output consists of a train of mode-locked ultrashort pulses which span a wide frequency gap with a series of equally spaced sharp lines. These gigawatt multichromatic x rays may potentially allow one to explore the structure and dynamics of a large number of atomicmore » states simultaneously. The feasibility of generating mode-locked x rays ranging from carbon K edge ({approx}284 eV) to copper L{sub 3} edge ({approx}931 eV) is confirmed with numerical simulation using the realistic parameters of the linac coherent light source (LCLS) and LCLS-II. We anticipate that the mode-locked multichromatic x rays in FELs may open up new opportunities in x-ray spectroscopy (i.e. resonant inelastic x-ray scattering, time-resolved scattering and spectroscopy, etc.).« less
Synthetic ANaB(Na x Li1 - x Mg1)CMg5Si8O22(OH)2 (with x = 0.6, 0.2 and 0) P21/ m amphiboles at high pressure: a synchrotron infrared study

NASA Astrophysics Data System (ADS)

Iezzi, Gianluca; Liu, Zhenxian; Della Ventura, Giancarlo

2009-06-01

The high-pressure behavior of three synthetic amphiboles crystallized with space group P21/ m at room conditions in the system Li2O-Na2O-MgO-SiO2-H2O has been studied by in situ synchrotron infrared absorption spectroscopy. The amphiboles have compositions ANa B(Na x Li1 - x Mg1) CMg5 Si8 O22(OH)2 with x = 0.6, 0.2 and 0.0, respectively. The high- P experiments up to 32 GPa were carried out on the U2A beamline at Brookhaven National Laboratory (NY, USA) using a diamond anvil cell under non-hydrostatic or quasi-hydrostatic conditions. The two most intense absorption bands in the OH-stretching infrared spectra can be assigned to two non-equivalent O-H dipoles in the P21/ m structure, bonded to the same local environment M1M3Mg3-OH-ANa, and pointing toward two differently kinked tetrahedral rings. In all samples these bands progressively merge to give a unique symmetrical absorption with increasing pressure, suggesting a change in symmetry from P21/ m to C2/ m. The pressure at which the transition occurs appears to be linearly correlated to the aggregate B-site dimension. The infrared spectra collected for amphibole B(Na0.2Li0.8Mg1) in the frequency range 50 to 1,400 cm-1 also show a series of changes with increasing pressure. The data reported here support the inference of Iezzi et al. (Am Miner 91:479-482, 2006a) regarding a new high-pressure amphibole polymorph.
Ethanol Sensor of CdO/Al2O3/CeO2 Obtained from Ce-DOPED Layered Double Hydroxides with High Response and Selectivity

NASA Astrophysics Data System (ADS)

Xu, Dongmei; Guan, Meiyu; Xu, Qinghong; Guo, Ying; Wang, Yao

2013-04-01

In this paper, Ce-doped CdAl layered double hydroxide (LDH) was first synthesized and the derivative CdO/Al2O3/CeO2 composite oxide was prepared by calcining Ce-doped CdAl LDH. The structure, morphology and chemical state of the Ce doped CdAl LDH and CdO/Al2O3/CeO2 were also investigated by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), solid state nuclear magnetic resonance (SSNMR), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). The gas sensing properties of CdO/Al2O3/CeO2 to ethanol were further studied and compared with CdO/Al2O3 prepared from CdAl LDH, CeO2 powder as well as the calcined Ce salt. It turns out that CdO/Al2O3/CeO2 sensor shows best performance in ethanol response. Besides, CdO/Al2O3/CeO2 possesses short response/recovery time (12/72 s) as well as remarkable selectivity in ethanol sensing, which means composite oxides prepared from LDH are very promising in gas sensing application.
Structural and magnetic properties of the 5d 2 double perovskites Sr 2 BReO 6 ( B = Y, In)

DOE PAGES

Aczel, A. A.; Zhao, Z.; Calder, S.; ...

2016-06-01

With this study, we have performed magnetic susceptibility, heat capacity, neutron powder diffraction, and muon spin relaxation experiments to investigate the magnetic ground states of the 5more » $d^2$ double perovskites Sr$$_2$$YReO$$_6$$ and Sr$$_2$$InReO$$_6$$. We find that Sr$$_2$$YReO$$_6$$ is a spin glass, while Sr$$_2$$InReO$$_6$$ hosts a non-magnetic singlet state. By making detailed comparisons with other 5$d^2$ double perovskites, we argue that a delicate interplay between spin-orbit coupling, non-cubic crystal fields, and exchange interactions plays a key role in the great variation of magnetic ground states observed for this family of materials.« less
Structural variations and dielectric properties of (Bi1-xL ax ) 2Si O5 (0 ≤x ≤0.1 ): Polycrystallines synthesized by crystallization of Bi-Si-O and Bi-La-Si-O glasses

NASA Astrophysics Data System (ADS)

Taniguchi, Hiroki; Tatewaki, Shingo; Yasui, Shintaro; Fujii, Yasuhiro; Yamaura, Jun-ichi; Terasaki, Ichiro

2018-04-01

This paper focuses on effects of isovalent La substitution on the crystal structure and dielectric properties of ferroelectric B i2Si O5 . Polycrystalline samples of (Bi1-xL ax ) 2Si O5 are synthesized by crystallization of Bi-Si-O and Bi-La-Si-O glasses with a composition range of 0 ≤x ≤0.1 . The crystal structure changes from monoclinic to tetragonal with increasing La-substitution rate x at room temperature. This structural variation stems from the change in orientation of Si O4 tetrahedra that form one-dimensional chains when they are in the ordered configuration, thus suggesting that lone-pair electrons play an important role in sustaining one-dimensional chains of Si O4 tetrahedra. Synchronizing with the disordering of Si O4 chains, ferroelectric phase transition temperature of (Bi1-xL ax ) 2Si O5 sharply decreases as x increases, and ferroelectricity finally vanishes at around x =0.03 . The present results demonstrate that lone-pair electrons of Bi play an important role in the ferroelectricity of B i2Si O5 through propping the ordered structure of one-dimensional Si O4 chains with stereochemical activity. Furthermore, an additional phase transition has been first discovered in the low-temperature region of (Bi1-xL ax ) 2Si O5 with x ≤0.01 , where the ordered one-dimensional Si O4 chains remain.
Planck intermediate results. XLI. A map of lensing-induced B-modes

NASA Astrophysics Data System (ADS)

Planck Collaboration; Ade, P. A. R.; Aghanim, N.; Ashdown, M.; Aumont, J.; Baccigalupi, C.; Banday, A. J.; Barreiro, R. B.; Bartolo, N.; Basak, S.; Battaner, E.; Benabed, K.; Benoit-Lévy, A.; Bernard, J.-P.; Bersanelli, M.; Bielewicz, P.; Bock, J. J.; Bonaldi, A.; Bonavera, L.; Bond, J. R.; Borrill, J.; Bouchet, F. R.; Boulanger, F.; Burigana, C.; Butler, R. C.; Calabrese, E.; Cardoso, J.-F.; Catalano, A.; Chiang, H. C.; Christensen, P. R.; Clements, D. L.; Colombi, S.; Colombo, L. P. L.; Combet, C.; Crill, B. P.; Curto, A.; Cuttaia, F.; Danese, L.; Davis, R. J.; de Bernardis, P.; de Zotti, G.; Delabrouille, J.; Dickinson, C.; Diego, J. M.; Doré, O.; Ducout, A.; Dupac, X.; Elsner, F.; Enßlin, T. A.; Eriksen, H. K.; Finelli, F.; Forni, O.; Frailis, M.; Fraisse, A. A.; Franceschi, E.; Galeotta, S.; Galli, S.; Ganga, K.; Ghosh, T.; Giard, M.; Giraud-Héraud, Y.; Gjerløw, E.; González-Nuevo, J.; Górski, K. M.; Gruppuso, A.; Gudmundsson, J. E.; Harrison, D. L.; Hernández-Monteagudo, C.; Herranz, D.; Hildebrandt, S. R.; Hornstrup, A.; Hovest, W.; Hurier, G.; Jaffe, A. H.; Jones, W. C.; Keihänen, E.; Keskitalo, R.; Kisner, T. S.; Knoche, J.; Knox, L.; Kunz, M.; Kurki-Suonio, H.; Lagache, G.; Lähteenmäki, A.; Lamarre, J.-M.; Lasenby, A.; Lattanzi, M.; Leonardi, R.; Levrier, F.; Lilje, P. B.; Linden-Vørnle, M.; López-Caniego, M.; Lubin, P. M.; Macías-Pérez, J. F.; Maffei, B.; Maggio, G.; Maino, D.; Mandolesi, N.; Mangilli, A.; Maris, M.; Martin, P. G.; Martínez-González, E.; Masi, S.; Matarrese, S.; Meinhold, P. R.; Melchiorri, A.; Mennella, A.; Migliaccio, M.; Mitra, S.; Miville-Deschênes, M.-A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Moss, A.; Munshi, D.; Murphy, J. A.; Naselsky, P.; Nati, F.; Natoli, P.; Netterfield, C. B.; Nørgaard-Nielsen, H. U.; Novikov, D.; Novikov, I.; Pagano, L.; Pajot, F.; Paoletti, D.; Pasian, F.; Patanchon, G.; Perdereau, O.; Perotto, L.; Pettorino, V.; Piacentini, F.; Piat, M.; Pierpaoli, E.; Pointecouteau, E.; Polenta, G.; Pratt, G. W.; Rachen, J. P.; Reinecke, M.; Remazeilles, M.; Renault, C.; Renzi, A.; Ristorcelli, I.; Rocha, G.; Rosset, C.; Rossetti, M.; Roudier, G.; Rubiño-Martín, J. A.; Rusholme, B.; Sandri, M.; Santos, D.; Savelainen, M.; Savini, G.; Scott, D.; Spencer, L. D.; Stolyarov, V.; Stompor, R.; Sudiwala, R.; Sunyaev, R.; Sutton, D.; Suur-Uski, A.-S.; Sygnet, J.-F.; Tauber, J. A.; Terenzi, L.; Toffolatti, L.; Tomasi, M.; Tristram, M.; Tucci, M.; Tuovinen, J.; Valenziano, L.; Valiviita, J.; Van Tent, B.; Vielva, P.; Villa, F.; Wade, L. A.; Wandelt, B. D.; Wehus, I. K.; Yvon, D.; Zacchei, A.; Zonca, A.

2016-12-01

The secondary cosmic microwave background (CMB) B-modes stem from the post-decoupling distortion of the polarization E-modes due to the gravitational lensing effect of large-scale structures. These lensing-induced B-modes constitute both a valuable probe of the dark matter distribution and an important contaminant for the extraction of the primary CMB B-modes from inflation. Planck provides accurate nearly all-sky measurements of both the polarization E-modes and the integrated mass distribution via the reconstruction of the CMB lensing potential. By combining these two data products, we have produced an all-sky template map of the lensing-induced B-modes using a real-space algorithm that minimizes the impact of sky masks. The cross-correlation of this template with an observed (primordial and secondary) B-mode map can be used to measure the lensing B-mode power spectrum at multipoles up to 2000. In particular, when cross-correlating with the B-mode contribution directly derived from the Planck polarization maps, we obtain lensing-induced B-mode power spectrum measurement at a significance level of 12σ, which agrees with the theoretical expectation derived from the Planck best-fit Λ cold dark matter model. This unique nearly all-sky secondary B-mode template, which includes the lensing-induced information from intermediate to small (10 ≲ ℓ ≲ 1000) angular scales, is delivered as part of the Planck 2015 public data release. It will be particularly useful for experiments searching for primordial B-modes, such as BICEP2/Keck Array or LiteBIRD, since it will enable an estimate to be made of the lensing-induced contribution to the measured total CMB B-modes.
Study of B to X \\gamma Decays and Determination of |V_{td}/V_{ts}|

DOE Office of Scientific and Technical Information (OSTI.GOV)

del Amo Sanchez, P.; Lees, J.P.; Poireau, V.

2011-08-22

Using a sample of 471 million B{bar B} events collected with the BABAR detector, we study the sum of seven exclusive final states B {yields} X{sub s(d){gamma}}, where X{sub s(d)} is a strange (non-strange) hadronic system with a mass of up to 2.0 GeV/c{sup 2}. After correcting for unobserved decay modes, we obtain a branching fraction for b {yields} d{gamma} of (9.2 {+-} 2.0(stat.) {+-} 2.3(syst.)) x 10{sup -6} in this mass range, and a branching fraction for b {yields} s{gamma} of (23.0 {+-} 0.8(stat.) {+-} 3.0(syst.)) x 10{sup -5} in the same mass range. We find {Beta}(b{yields}d{gamma})/{Beta}(b{yields}s{gamma}) = 0.040more » {+-} 0.009(stat.) {+-} 0.010(syst.), from which we determine |V{sub td}/V{sub ts}| = 0.199 {+-} 0.022(stat.) {+-} 0.024(syst.) {+-} 0.002(th.).« less
Effect of Composition on the Voltage Fade Phenomenon in Lithium-, Manganese-Rich xLiMnO 3•(1-x)LiNi aMn bCo cO 2: A Combinatorial Synthesis Approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vu, Anh; Qin, Yan; Bareno, Javier

2015-10-30

The effect of composition on the voltage fade phenomenon was probed using combinatorial synthesis methods. In compositions that have the general formula, (Li 2MnO 3) a(LiNiO 2) b(LiMnO 2) c(LiCoO 2) d, where 0 ≤ a≤0.83, 0.15 ≤ b ≤ 0.42, 0 ≤ c ≤ 0.85, and 0 ≤ d ≤ 0.30 (a + b + c + d = 1), the dependence of features in the x-ray diffraction pattern and of voltage fade on composition were identified and mapped. The observed values of voltage fade indicated that it displayed some sensitivity to composition, but that the sensitivity was notmore » large. The values of voltage fade were found to be amenable to statistical modeling. The model indicated that it may be possible to lower the value of voltage fade below 0.01% by adjusting the composition of the system; however, the composition is not expected to have the layered–layered structure.« less
CMB Polarization B-mode Delensing with SPTpol and Herschel

NASA Astrophysics Data System (ADS)

Manzotti, A.; Story, K. T.; Wu, W. L. K.; Austermann, J. E.; Beall, J. A.; Bender, A. N.; Benson, B. A.; Bleem, L. E.; Bock, J. J.; Carlstrom, J. E.; Chang, C. L.; Chiang, H. C.; Cho, H.-M.; Citron, R.; Conley, A.; Crawford, T. M.; Crites, A. T.; de Haan, T.; Dobbs, M. A.; Dodelson, S.; Everett, W.; Gallicchio, J.; George, E. M.; Gilbert, A.; Halverson, N. W.; Harrington, N.; Henning, J. W.; Hilton, G. C.; Holder, G. P.; Holzapfel, W. L.; Hoover, S.; Hou, Z.; Hrubes, J. D.; Huang, N.; Hubmayr, J.; Irwin, K. D.; Keisler, R.; Knox, L.; Lee, A. T.; Leitch, E. M.; Li, D.; McMahon, J. J.; Meyer, S. S.; Mocanu, L. M.; Natoli, T.; Nibarger, J. P.; Novosad, V.; Padin, S.; Pryke, C.; Reichardt, C. L.; Ruhl, J. E.; Saliwanchik, B. R.; Sayre, J. T.; Schaffer, K. K.; Smecher, G.; Stark, A. A.; Vanderlinde, K.; Vieira, J. D.; Viero, M. P.; Wang, G.; Whitehorn, N.; Yefremenko, V.; Zemcov, M.

2017-09-01

We present a demonstration of delensing the observed cosmic microwave background (CMB) B-mode polarization anisotropy. This process of reducing the gravitational-lensing-generated B-mode component will become increasingly important for improving searches for the B modes produced by primordial gravitational waves. In this work, we delens B-mode maps constructed from multi-frequency SPTpol observations of a 90 deg2 patch of sky by subtracting a B-mode template constructed from two inputs: SPTpol E-mode maps and a lensing potential map estimated from the Herschel 500 μm map of the cosmic infrared background. We find that our delensing procedure reduces the measured B-mode power spectrum by 28% in the multipole range 300< {\\ell }< 2300; this is shown to be consistent with expectations from simulations and to be robust against systematics. The null hypothesis of no delensing is rejected at 6.9σ . Furthermore, we build and use a suite of realistic simulations to study the general properties of the delensing process and find that the delensing efficiency achieved in this work is limited primarily by the noise in the lensing potential map. We demonstrate the importance of including realistic experimental non-idealities in the delensing forecasts used to inform instrument and survey-strategy planning of upcoming lower-noise experiments, such as CMB-S4.
CMB Polarization B-mode Delensing with SPTpol and Herschel

DOE PAGES

Manzotti, A.; et al.

2017-08-30

We present a demonstration of delensing the observed cosmic microwave background (CMB) B-mode polarization anisotropy. This process of reducing the gravitational-lensing-generated B-mode component will become increasingly important for improving searches for the B modes produced by primordial gravitational waves. In this work, we delens B-mode maps constructed from multi-frequency SPTpol observations of a 90 deg(2) patch of sky by subtracting a B-mode template constructed from two inputs: SPTpol E-mode maps and a lensing potential map estimated from the Herschel 500 μm map of the cosmic infrared background. We find that our delensing procedure reduces the measured B-mode power spectrum bymore » $28$% in the multipole range $$300\\lt {\\ell }\\lt 2300,$$ this is shown to be consistent with expectations from simulations and to be robust against systematics. The null hypothesis of no delensing is rejected at $$6.9\\sigma $$. Furthermore, we build and use a suite of realistic simulations to study the general properties of the delensing process and find that the delensing efficiency achieved in this work is limited primarily by the noise in the lensing potential map. We demonstrate the importance of including realistic experimental non-idealities in the delensing forecasts used to inform instrument and survey-strategy planning of upcoming lower-noise experiments, such as CMB-S4.« less
Growth of ultrathin twin-free b-oriented YBa{sub 2}Cu{sub 3}O{sub 7} {sub –} {sub x} films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stepantsov, E. A., E-mail: stepantsov@ns.crys.ras.ru; Arpaia, R.; Lombardi, F.

2017-01-15

Twin-free b-oriented YBa{sub 2}Cu{sub 3}O{sub 7–x} films with a thickness less than 40 nm have been epitaxially grown on (100)SrLaGaO{sub 4} crystals. Based on the temperature dependence of resistance, the onset temperature of the transition to the superconducting state is found to be 90 K; the transition width is 4 K. The film growth has been performed in two stages. A (100)PrBa{sub 2}Cu{sub 3}O{sub 7–x} buffer layer was previously grown on a (100)SrLaGaO{sub 4} substrate by rf magnetron sputtering in an Ar–O{sub 2} gas mixture at a continuous and monotonic increase in temperature from 660 to 830°C. The main YBa{submore » 2}Cu{sub 3}O{sub 7–x} film was grown on the buffer layer surface by pulsed laser deposition in an oxygen medium at a fixed temperature (800°C). The above processes were implemented in different chambers, which were connected by a vacuum channel for transporting samples. Both films were grown in situ, without contacting atmosphere in all growth stages. An X-ray diffraction study has shown that the YBa{sub 2}Cu{sub 3}O{sub 7–x} films are single-crystal and free of precipitates of other phases and domains of other orientations.« less
Investigation on gamma and neutron radiation shielding parameters for BaO/SrO‒Bi2O3‒B2O3 glasses

NASA Astrophysics Data System (ADS)

Sayyed, M. I.; Lakshminarayana, G.; Dong, M. G.; Ersundu, M. Çelikbilek; Ersundu, A. E.; Kityk, I. V.

2018-04-01

In this work, mass attenuation coefficients (μ/ρ), effective atomic number (Zeff), electron density (Ne), mean free path (MFP), and half-value layer (HVL) of 20 BaO/SrO‒(x) Bi2O3‒(80‒x) B2O3 glasses (where x=10, 20, 30, 40, 50 and 60 mol%) were calculated using WinXCom program and MCNP5 code. The obtained (μ/ρ) results using both MCNP5 code and WinXCom program were in good agreement. It is found that the addition of Bi2O3 leads to increase the Zeff values in both BaO/SrO‒Bi2O3‒B2O3 glass systems. However, the Zeff values of the BaO‒Bi2O3‒B2O3 glass system are higher than those of the SrO‒Bi2O3‒B2O3 glasses. The fast neutrons effective removal cross sections (ΣR) for 20 SrO‒40 Bi2O3‒40 B2O3 glass is the highest among all studied glasses. The calculated half-value layer values were compared with different glass systems and it was found that the shielding properties of the selected glasses are comparable or even better than other glass systems such as phosphate glasses.
The Atacama B-mode Search: Status and Prospect

NASA Astrophysics Data System (ADS)

Kusaka, Akito

2013-04-01

The Atacama B-mode Search (ABS) experiment is a 145 GHz polarimeter designed to measure the B-mode polarization of the Cosmic Microwave Background (CMB) at degre angular scales. In January 2012, ABS has deployed 240 polarimeters employing transition-edge sensor (TES) bolometers. ABS has unique advantages for the measurement of B modes. This includes a continuously rotating half-wave plate that provides fast and clean modulation, as well as systematically clean optics that consist of a cryogenic side-fed Dragone telescope and feedhorn coupled TES polarimeters. In this talk, we will present the status and prospect of ABS.
Sol-gel preparation of self-cleaning SiO2-TiO2/SiO2-TiO2 double-layer antireflective coating for solar glass

NASA Astrophysics Data System (ADS)

Lin, Wensheng; Zheng, Jiaxian; Yan, Lianghong; Zhang, Xinxiang

2018-03-01

Self-cleaning SiO2-TiO2/SiO2-TiO2 double-layer antireflective (AR) coating is prepared by sol-gel process. SiO2 sol is prepared by using tetraethyl orthosilicate (TEOS) as precursor and ammonia as catalyst, while TiO2 sol was prepared by using tetrabutyl orthotitanate (TBOT) as precursor and hydrochloric acid as catalyst. The effect of TiO2 content on refractive index, abrasion-resistance and photo-catalytic activity of SiO2-TiO2 hybrid thin films or powders is systematically investigated. It is found that the refractive index of SiO2-TiO2 hybrid thin films increases gradually from 1.18 to 1.53 as the weight ratio of TiO2 to SiO2 increased from 0 to 1.0. The SiO2-TiO2 hybrid thin film and powder possesses good abrasion-resistance and photo-catalytic activity, respectively, as the weight ratio of TiO2 to SiO2 is 0.4. The degradation degree of Rhodamine B by SiO2-TiO2 hybrid powder is 88.3%. Finally, SiO2-TiO2/SiO2-TiO2 double-layer AR coating with high transmittance, abrasion-resistance and self-cleaning property is realized.
Enhanced photocatalytic performance and degradation pathway of Rhodamine B over hierarchical double-shelled zinc nickel oxide hollow sphere heterojunction

NASA Astrophysics Data System (ADS)

Zhang, Ying; Zhou, Jiabin; Cai, Weiquan; Zhou, Jun; Li, Zhen

2018-02-01

In this study, hierarchical double-shelled NiO/ZnO hollow spheres heterojunction were prepared by calcination of the metallic organic frameworks (MOFs) as a sacrificial template in air via a one-step solvothermal method. Additionally, the photocatalytic activity of the as-prepared samples for the degradation of Rhodamine B (RhB) under UV-vis light irradiation were also investigated. NiO/ZnO microsphere comprised a core and a shell with unique hierarchically porous structure. The photocatalytic results showed that NiO/ZnO hollow spheres exhibited excellent catalytic activity for RhB degradation, causing complete decomposition of RhB (200 mL of 10 g/L) under UV-vis light irradiation within 3 h. Furthermore, the degradation pathway was proposed on the basis of the intermediates during the photodegradation process using liquid chromatography analysis coupled with mass spectroscopy (LC-MS). The improvement in photocatalytic performance could be attributed to the p-n heterojunction in the NiO/ZnO hollow spheres with hierarchically porous structure and the strong double-shell binding interaction, which enhances adsorption of the dye molecules on the catalyst surface and facilitates the electron/hole transfer within the framework. The degradation mechanism of pollutant is ascribed to the hydroxyl radicals (rad OH), which is the main oxidative species for the photocatalytic degradation of RhB. This work provides a facile and effective approach for the fabrication of porous metal oxides heterojunction with high photocatalytic activity and thus can be potentially used in the environmental purification.
Theory of dynamic spin susceptibility in terms of the t-J-V model: Comparison with neutron scattering data for Pr0.88LaCe0.12CuO4 - x and La2 - x Sr x CuO4

NASA Astrophysics Data System (ADS)

Andreev, A. I.; Eremin, I. M.; Eremin, M. V.

2009-01-01

A formula for the dynamic spin susceptibility is derived in terms of the t-J-V model. This formula makes it possible to explain the main features of recent experiments on neutron scattering in the electron-doped superconductor Pr0.88LaCe0.12CuO4 - x . In particular, the proposed theory reproduces well a V-shaped relief in the frequency behavior of the imaginary part χ″( Q, ω) of the susceptibility of the Pr0.88LaCe0.12CuO4 - x compound in the vicinity of the wave vector Q = (π,π) and the scaling behavior of the position of the maxima in the dependence of the function χ″( Q, ω) T on the quantity ω/ T. The magnetism of the high-temperature superconductors is dual. These materials contain charge carriers, on the one hand, and localized spins in the copper ion sublattice, on the other hand. Both these systems are strongly coupled to each other. The mode of collective oscillations is common. The magnetism of localized spins “freezes” with the appearance of the superconducting gap. The recently revealed double-peak structure of the imaginary part χ″( Q, ω) of the susceptibility in superconductors of the La1.84Sr0.16CuO4 type is explained. The low-frequency absorption peak is located within the superconducting gap and interpreted as a manifestation of the branch of spin excitons, and the high-frequency absorption peak predominantly corresponds to renormalized collective oscillations of localized spins.
Planck intermediate results: XLI. A map of lensing-induced B-modes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ade, P. A. R.; Aghanim, N.; Ashdown, M.

The secondary cosmic microwave background (CMB) B-modes stem from the post-decoupling distortion of the polarization E-modes due to the gravitational lensing effect of large-scale structures. These lensing-induced B-modes constitute both a valuable probe of the dark matter distribution and an important contaminant for the extraction of the primary CMB B-modes from inflation. Planck provides accurate nearly all-sky measurements of both the polarization E-modes and the integrated mass distribution via the reconstruction of the CMB lensing potential. By combining these two data products, we have produced in this paper an all-sky template map of the lensing-induced B-modes using a real-space algorithmmore » that minimizes the impact of sky masks. The cross-correlation of this template with an observed (primordial and secondary) B-mode map can be used to measure the lensing B-mode power spectrum at multipoles up to 2000. In particular, when cross-correlating with the B-mode contribution directly derived from the Planck polarization maps, we obtain lensing-induced B-mode power spectrum measurement at a significance level of 12σ, which agrees with the theoretical expectation derived from the Planck best-fit Λ cold dark matter model. This unique nearly all-sky secondary B-mode template, which includes the lensing-induced information from intermediate to small (10 ≲ ℓ ≲ 1000) angular scales, is delivered as part of the Planck 2015 public data release. Finally, it will be particularly useful for experiments searching for primordial B-modes, such as BICEP2/Keck Array or LiteBIRD, since it will enable an estimate to be made of the lensing-induced contribution to the measured total CMB B-modes.« less
Planck intermediate results: XLI. A map of lensing-induced B-modes

DOE PAGES

Ade, P. A. R.; Aghanim, N.; Ashdown, M.; ...

2016-12-12

The secondary cosmic microwave background (CMB) B-modes stem from the post-decoupling distortion of the polarization E-modes due to the gravitational lensing effect of large-scale structures. These lensing-induced B-modes constitute both a valuable probe of the dark matter distribution and an important contaminant for the extraction of the primary CMB B-modes from inflation. Planck provides accurate nearly all-sky measurements of both the polarization E-modes and the integrated mass distribution via the reconstruction of the CMB lensing potential. By combining these two data products, we have produced in this paper an all-sky template map of the lensing-induced B-modes using a real-space algorithmmore » that minimizes the impact of sky masks. The cross-correlation of this template with an observed (primordial and secondary) B-mode map can be used to measure the lensing B-mode power spectrum at multipoles up to 2000. In particular, when cross-correlating with the B-mode contribution directly derived from the Planck polarization maps, we obtain lensing-induced B-mode power spectrum measurement at a significance level of 12σ, which agrees with the theoretical expectation derived from the Planck best-fit Λ cold dark matter model. This unique nearly all-sky secondary B-mode template, which includes the lensing-induced information from intermediate to small (10 ≲ ℓ ≲ 1000) angular scales, is delivered as part of the Planck 2015 public data release. Finally, it will be particularly useful for experiments searching for primordial B-modes, such as BICEP2/Keck Array or LiteBIRD, since it will enable an estimate to be made of the lensing-induced contribution to the measured total CMB B-modes.« less
(3+1)D superspace structural determination of two new modulated composite phases: Sr 1+ x(Cu xMn 1- x)O 3; x=3/11 and x=0.3244

NASA Astrophysics Data System (ADS)

El Abed, Ahmed; Gaudin, Etienne; zur Loye, Hans-Conrad; Darriet, Jacques

2003-01-01

We report the structure determination of two new phases belonging to the A 1+ x(A' xB 1- x)O 3 family of oxides with A=Sr, A'=Cu, and B=Mn, where x=3/11 and x=0.3244, corresponding to a commensurate and incommensurate composite structure, respectively. These two compounds are the first examples of oxides belonging to the Sr 1+ x(Cu xMn 1- x)O 3 family. Their structures were solved in the (3+1) dimensional superspace formalism as modulated composite structures with two subsystems [(Cu,Mn)O 3] and [Sr]. The superspace group used to solve the structures is R 3¯m(00γ)0s . The first phase ( x=3/11), corresponding to the chemical formula Sr 14Cu 3Mn 8O 33, was obtained as a single crystal with unit cell parameters of a=9.6025(3) Å and c1=2.5660(8) Å ( q=7/11 c1∗, Z=3), where c1 is the lattice parameter corresponding to the c-axis of the trigonal subsystem [(Cu,Mn)O 3]. The second phase ( x=0.3244(1)), is a polycrystalline sample with unit cell parameters of a=9.5933(7) and c1=2.5933(3) ( q=0.6622 c1∗, Z=3). In both structures, one dimensional chains run along the c-axis which contain octahedra and trigonal prisms occupied by manganese and copper atoms, respectively. The refinement results show that in both cases copper occupies the rectangular faces of the trigonal prism while manganese occupies the octahedral sites. The magnetic measurements of the polycrystalline phase (Sr 1+ x(Cu xMn 1- x)O 3, x=0.3244(2)) and the Curie constant obtained from the high temperature susceptibility are in agreement with a spin state configuration of S=3/2 for Mn 4+ and S=1/2 for Cu 2+.

Ferroelectricity of Sn-doped SrTiO3 perovskites with tin at both A and B sites

NASA Astrophysics Data System (ADS)

Suzuki, Shoichiro; Honda, Atsushi; Iwaji, Naoki; Higai, Shin'ichi; Ando, Akira; Takagi, Hiroshi; Kasatani, Hirofumi; Deguchi, Kiyoshi

2012-08-01

We successfully obtained Sn-doped SrTiO3 (SSTO) perovskites, and clarified their ferroelectricity and structural properties by using first-principles theoretical calculations. The ferroelectricity of SSTO was confirmed by the appearance of a dielectric permittivity maximum and a clear hysteresis loop of the relationship between the external electric field and the electric flux density below 180 K. X-ray diffraction and Raman spectra revealed the structural phase transition of SSTO at approximately 200 K. We directly observed by spherical aberration corrected scanning transmission electron microscopy with energy-dispersive x-ray spectroscopy that Sn ions are doped into both Sr and Ti sites (SnA and SnB), and that SnA is located at an off-centered position. We also performed theoretical analyses of SSTO and related perovskites, and found that SnA is preferentially located in an off-centered position and that SnA and the O6 octahedron, which includes SnB in its center, oscillate along the antiphase direction in the soft mode. Thus, we propose that the ferroelectricity of SSTO originates from the antiphase off-centering, which induces ferroelectric nanoregions in paraelectric SrTiO3.
Enhanced room temperature multiferroic characteristics in hexagonal LuFe1-xNixO3 (x = 0 - 0.3) nanoparticles

NASA Astrophysics Data System (ADS)

Suresh, Pittala; Vijaya Laxmi, K.; Anil Kumar, P. S.

2018-02-01

Single phase polycrystalline LuFe1-xNixO3 (x = 0 - 0.3) (LFNO) nanoparticles are synthesized using the sol-gel method. X-ray diffraction measurements revealed that the crystal structure of Ni-doped samples is isomorphic to hexagonal LuFeO3 (LFO). The phase pure hexagonal P63cm symmetry exists for 0 ≤ x ≤ 0.3, and the secondary phases appear for x ≥ 0.4. Raman spectra show a shift in the mode frequency corresponding to the changes in Lu-O and Fe-O bond lengths with Ni doping. An enhancement in the magnetization is observed for LFNO throughout the temperature range (400-5 K) compared to LFO. The antiferromagnetic state of LFO becomes ferrimagnetic at low temperatures, and a net magnetization is observed at room temperature with Ni doping. As Ni concentration increases, a systematic increment in the ferroelectric polarization is observed. This enhancement in polarization is believed to be due to the distortion in FeO5 cage, while the improvement in magnetic properties is due to the induced magnetic interactions, caused by the Fe-Ni interactions on the triangular lattice with Ni doping in LuFeO3.
Sub-femtosecond quantum dynamics of the strong-field ionization of water to the X ̃(2)B1 and Ã(2)A1 states of the cation.

PubMed

Jayachander Rao, B; Varandas, A J C

2015-03-07

Motivated by recent efforts to achieve sub-femtosecond structural resolution in various molecular systems, we have performed a femtosecond quantum dynamics study of the water cation in the X ̃(2)B1 and Ã(2)A1 electronic states. Autocorrelation functions for H2O(+) and D2O(+) are calculated for such electronic states by solving numerically the time-dependent Schrödinger equation. From the ratio of the squared autocorrelation functions of D2O(+) and H2O(+), the high-order harmonic generation signals are calculated. Substantial vibrational dynamics is found in the Ã(2)A1 state as compared to the one in X ̃(2)B1, which supports recent experimental findings of Farrell et al., Phys. Rev. Lett., 2011, 107, 083001. Maxima in the above ratio are also predicted at ∼1.1 fs and ∼1.6 fs for the X ̃(2)B1 and Ã(2)A1 states, respectively. The expectation values of the positions of the atoms in H2O(+) as a function of time reveal a strong excitation of the bending mode in the Ã(2)A1 state, which explains the observed vibrational dynamics. The peaks in the ratios of the squared autocorrelation functions are also explained in terms of the evolving geometries of the water cation.
Direct visualization of soliton stripes in the Cu O2 plane and oxygen interstitials in B i2(S r2 -xL ax) Cu O6 +δ superconductors

NASA Astrophysics Data System (ADS)

Guo, C.; Tian, H. F.; Yang, H. X.; Zhang, B.; Sun, K.; Sun, X.; Peng, Y. Y.; Zhou, X. J.; Li, J. Q.

2017-11-01

Microstructure features in correlation with the incommensurate modulation and oxygen interstitials in B i2(S r2 -xL ax) Cu O6 +δ superconducting materials were studied by Cs-corrected scanning transmission electron microscopy. Atomic displacements following the modulation wave were well characterized by a sinusoidal wave for each atomic layer, which highlighted clear changes resulting from increases in the La concentration. Careful investigations of the alterations in the local atomic structure revealed that remarkable microstructural features, i.e., notable soliton lines, which arise from the prominent interplay between incommensurate modulation and the basic lattice, appear at the Cu O2 sheets yielding visible structural anomalies for x ranging from 0.40 to 0.85. The interstitial oxygen atoms between the SrO-BiO layers became clearly visible for X ≥0.73 and showed well-defined ordered states in the x =1.10 sample. These structural features, in particular the strong structural effects of the soliton lines on the Cu O2 sheets, could evidently affect the physical properties of layered La-Bi2201 systems.
Retention Model of TaO/HfO x and TaO/AlO x RRAM with Self-Rectifying Switch Characteristics.

PubMed

Lin, Yu-De; Chen, Pang-Shiu; Lee, Heng-Yuan; Chen, Yu-Sheng; Rahaman, Sk Ziaur; Tsai, Kan-Hsueh; Hsu, Chien-Hua; Chen, Wei-Su; Wang, Pei-Hua; King, Ya-Chin; Lin, Chrong Jung

2017-12-01

A retention behavior model for self-rectifying TaO/HfO x - and TaO/AlO x -based resistive random-access memory (RRAM) is proposed. Trapping-type RRAM can have a high resistance state (HRS) and a low resistance state (LRS); the degradation in a LRS is usually more severe than that in a HRS, because the LRS during the SET process is limited by the internal resistor layer. However, if TaO/AlO x elements are stacked in layers, the LRS retention can be improved. The LRS retention time estimated by extrapolation method is more than 5 years at room temperature. Both TaO/HfO x - and TaO/AlO x -based RRAM structures have the same capping layer of TaO, and the activation energy levels of both types of structures are 0.38 eV. Moreover, the additional AlO x switching layer of a TaO/AlO x structure creates a higher O diffusion barrier that can substantially enhance retention, and the TaO/AlO x structure also shows a quite stable LRS under biased conditions.
Structural, vibrational and dielectric studies of (0.95)Pb(Zr{sub x}Ti{sub 1−x})O{sub 3}-(0.05)BiFeO{sub 3} nanoceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Subhash, E-mail: rk.dwivedi@jiit.ac.in; Singh, Vikash, E-mail: rk.dwivedi@jiit.ac.in; Dwivedi, R. K., E-mail: rk.dwivedi@jiit.ac.in

2014-04-24

(0.95)Pb(Zr{sub x}Ti{sub 1−x})O{sub 3}-(0.05)BiFeO{sub 3} nanoceramics with x=0.51, 0.53 and 0.55 were synthesized by sol-gel route. Rietveld refined X-ray powder diffraction pattern of the samples confirm the single phase formation of compounds with tetragonal structure (P4mm). FT-IR studies revealed that slight shift of phonon modes towards the lower wave number and increase in the bond length with increasing Zr{sup 4+} concentration. Room temperature dielectric properties of system revealed that relaxor characteristics of these samples. Ferroelectric hysteresis curve shows the decrease in polarization values with Zr concentration.
Observation of 67 keV x-rays with a scintillation detector using proportional-mode silicon avalanche photodiode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Inoue, Keisuke; Kishimoto, Shunji, E-mail: syunji.kishimoto@kek.jp; Inst. of Materials Structure Science, KEK, 1-1 Oho, Tsukuba, Ibaraki 305-0801

2016-07-27

We developed a scintillation X-ray detector using a proportional-mode silicon avalanche photodiode (Si-APD). We report a prototype detector using a lead-loaded plastic scintillator mounted on a proportional-mode Si-APD (active area size: 3 mm in diameter), which is operated at a low temperature. Using 67.41 keV X-rays, we could measure pulse-height spectra of scintillation light with a charge-sensitive preamplifier at 20, 0, and −35°C. Time spectra of the X-ray bunch structure were successfully recorded using a wideband and 60-dB-gain amplifier in hybrid-mode operation of the Photon Factory ring. We obtained a better time resolution of 0.51 ns (full width at half-maximum)more » for the single-bunch X-ray peak at −35°C. We were also able to observe a linear response of the scintillation pulses up to 8 Mcps for input photon rates up to 1.4 × 10{sup 8} photons/s.« less
Near-Zero Thermal Expansion and Phase Transitions in HfMg1−xZnxMo3O12

PubMed Central

Li, Sailei; Ge, Xianghong; Yuan, Huanli; Chen, Dongxia; Guo, Juan; Shen, Ruofan; Chao, Mingju; Liang, Erjun

2018-01-01

The effects of Zn2+ incorporation on the phase formation, thermal expansion, phase transition, and vibrational properties of HfMg1−xZnxMo3O12 are investigated by XRD, dilatometry, and Raman spectroscopy. The results show that (i) single phase formation is only possible for x ≤ 0.5, otherwise, additional phases of HfMo2O8 and ZnMoO4 appear; (ii) The phase transition temperature from monoclinic to orthorhombic structure of the single phase HfMg1−xZnxMo3O12 can be well-tailored, which increases with the content of Zn2+; (iii) The incorporation of Zn2+ leads to an pronounced reduction in the positive expansion of the b-axis and an enhanced negative thermal expansion (NTE) in the c-axes, leading to a near-zero thermal expansion (ZTE) property with lower anisotropy over a wide temperature range; (iv) Replacement of Mg2+ by Zn2+ weakens the Mo–O bonds as revealed by obvious red shifts of all the Mo–O stretching modes with increasing the content of Zn2+ and improves the sintering performance of the samples which is observed by SEM. The mechanisms of the negative and near-ZTE are discussed. PMID:29719819
Raman effect, structural and dielectric properties of sol-gel synthesized polycrystalline GaFe{sub 1-x}Zr{sub x}O{sub 3} (0≤x≤0.15)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, Rajeev, E-mail: rajeevgiitk@gmail.com; Mall, Ashish Kumar; Gupta, Rajeev

2016-05-23

Polycrystalline ceramic samples of Zirconium (Zr)-doped GaFeO{sub 3} (GaFe{sub 1-x}Zr{sub x}O{sub 3}) were studied using powder X-ray diffraction, complex impedance spectroscopy and Raman spectroscopic measurements to understand the effect of Zr doping on the structural and dielectric properties. The samples with varying Zr content were prepared by Sol-Gel method. X-ray data analysis confirmed the formation of single phase material without formation of any secondary phases and all are crystallized in Pc2{sub 1}n orthorhombic symmetry. Rietveld refinement of the X-ray data suggested an increase in the lattice constants due to size effect and decreases on x = 0.15 due to themore » effect of change in interplanner spacing. Impedance studies on the samples showed that the dielectric constant increases while loss tangent decrease as the Zr content increases. Raman scattering on GaFe{sub 1-x}Zr{sub x}O{sub 3} (x = 0, 0.05, 0.10, & 0.15) used to understand the composition dependence on phonon modes at room temperature. On Zr doping, Raman modes frequencies shifts to lower energies consistent with the X-ray data.« less
Structure symmetry determination and magnetic evolution in Sr 2Ir 1–xRh xO 4

DOE PAGES

Ye, Feng; Wang, Xiaoping; Hoffmann, Christina; ...

2015-11-23

We use single-crystal neutron diffraction to determine the crystal structure symmetry and to study the magnetic evolution in the rhodium doped iridates Sr 2Ir 1–xRh xO 4 (0 ≤ x ≤ 0.16). Throughout this doping range, the crystal structure retains a tetragonal symmetry (space group I4 1/a) with two distinct magnetic Ir sites in the unit cell forming staggered IrO 6 rotation. Upon Rh doping, the magnetic order is suppressed and the magnetic moment of Ir4+ is reduced from 0.21 μ B/Ir for x = 0 to 0.18 μ B/Ir for x = 0.12. As a result, the magnetic structuremore » at x = 0.12 is different from that of the parent compound while the moments remain in the basal plane.« less
Evidence of Multiple Sorption Modes in Layered Double Hydroxides Using Mo As Structural Probe.

PubMed

Ma, Bin; Fernandez-Martinez, Alejandro; Grangeon, Sylvain; Tournassat, Christophe; Findling, Nathaniel; Claret, Francis; Koishi, Ayumi; Marty, Nicolas C M; Tisserand, Delphine; Bureau, Sarah; Salas-Colera, Eduardo; Elkaïm, Erik; Marini, Carlo; Charlet, Laurent

2017-05-16

Layered double hydroxides (LDHs) have been considered as effective phases for the remediation of aquatic environments, to remove anionic contaminants mainly through anion exchange mechanisms. Here, a combination of batch isotherm experiments and X-ray techniques was used to examine molybdate (MoO 4 2- ) sorption mechanisms on CaAl LDHs with increasing loadings of molybdate. Advanced modeling of aqueous data shows that the sorption isotherm can be interpreted by three retention mechanisms, including two types of edge sites complexes, interlayer anion exchange, and CaMoO 4 precipitation. Meanwhile, Mo geometry evolves from tetrahedral to octahedral on the edge, and back to tetrahedral coordination at higher Mo loadings, indicated by Mo K-edge X-ray absorption spectra. Moreover, an anion exchange process on both CaAl LDHs was followed by in situ time-resolved synchrotron-based X-ray diffraction, remarkably agreeing with the sorption isotherm. This detailed molecular view shows that different uptake mechanisms-edge sorption, interfacial dissolution-reprecipitation-are at play and control anion uptake under environmentally relevant conditions, which is contrast to the classical view of anion exchange as the primary retention mechanism. This work puts all these mechanisms in perspective, offering a new insight into the complex interplay of anion uptake mechanisms by LDH phases, by using changes in Mo geometry as powerful molecular-scale probe.
Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB{sub 5}O{sub 9}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Min; Graduate University of Chinese Academy of Sciences, Beijing 100049; Pan, Shilie, E-mail: slpan@ms.xjb.ac.c

A novel sodium lead pentaborate, NaPbB{sub 5}O{sub 9}, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB{sub 5}O{sub 9} crystallizes in the monoclinic space group P2{sub 1}/c with a=6.5324(10) A, b=13.0234(2) A, c=8.5838(10) A, {beta}=104.971(10){sup o}, and Z=4. The crystal structure is composed of double ring [B{sub 5}O{sub 9}]{sup 3-} units, [PbO{sub 7}] and [NaO{sub 7}] polyhedra. [B{sub 5}O{sub 9}]{sup 3-} groups connect with each other forming two-dimensional infinite {sub {infinity}}[B{sub 5}O{sub 9}]{sup 3-} layers, while [PbO{sub 7}] and [NaO{sub 7}] polyhedra are located between the layers. [PbO{sub 7}] polyhedra linked together viamore » corner-sharing O atom forming novel infinite {sub {infinity}}[PbO{sub 6}] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB{sub 5}O{sub 9} were reported. -- Graphical abstract: A new phase, NaPbB{sub 5}O{sub 9}, has been discovered in the ternary M{sub 2}O-PbO-B{sub 2}O{sub 3} (M=alkali-metal) system. The crystal structure consists of a novel infinite {sub {infinity}}[PbO{sub 6}] chains. Display Omitted Research highlights: NaPbB{sub 5}O{sub 9} is the first borate discovered in the ternary M{sub 2}O-PbO-B{sub 2}O{sub 3} (M=alkali-metal) system. NaPbB{sub 5}O{sub 9} crystal structure includes a two-dimensional infinite {sub {infinity}}[B{sub 5}O{sub 9}]{sup 3-} layers and a novel one-dimensional infinite {sub {infinity}}[PbO{sub 6}] chains. [PbO{sub 7}] polyhedron has a highly asymmetric bonding configuration.« less
Applying the Post-Modern Double ABC-X Model to Family Food Insecurity

ERIC Educational Resources Information Center

Hutson, Samantha; Anderson, Melinda; Swafford, Melinda

2015-01-01

This paper develops the argument that using the Double ABC-X model in family and consumer sciences (FCS) curricula is a way to educate nutrition and dietetics students regarding a family's perceptions of food insecurity. The Double ABC-X model incorporates ecological theory as a basis to explain family stress and the resulting adjustment and…
Self-consistent Formulation of EBW Excitation by Mode Conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bers, Abraham; Decker, Joan

2005-09-26

Based upon a FLR-hydrodynamic formulation for high frequency waves in a collisionless plasma, we formulate the self-consistent, coupled set of ordinary differential equations whose solution gives the mode conversion of O- and/or X-waves at an angle to B0 to electron Bernstein waves (EBW) at the upper-hybrid resonance UHR layer occurring at the edge of an ST plasma.
Direct spectroscopic evidence for isolated silanols in SiO x/Al 2O 3 and their formation mechanism

DOE PAGES

Mouat, Aidan R.; Kobayashi, Takeshi; Pruski, Marek; ...

2017-02-27

Here, the preparation and unambiguous characterization of isolated Brønsted-acidic silanol species on silica–alumina catalysts presents a key challenge in the rational design of solid acid catalysts. In this report, atomic layer deposition (ALD) and liquid-phase preparation (chemical liquid deposition, CLD) are used to install the SiO x sites on Al 2O 3 catalysts using the same Si source (tetraethylorthosilicate, TEOS). The ALD-derived and CLD-derived SiO x sites are probed with dynamic nuclear polarization (DNP)-enhanced 29Si– 29Si double-quantum/single-quantum (DQ/SQ) correlation NMR spectroscopy. The investigation reveals conclusively that the SiO x/Al 2O 3 material prepared by ALD and CLD, followed by calcinationmore » under an O 2 stream, contains fully spatially isolated Si species, in contrast with those resulting from the calcination under static air, which is widely accepted as a postgrafting treatment for CLD. Insight into the formation mechanism of these sites is obtained via in situ monitoring of the TEOS + γ-Al 2O 3 reaction in an environmental diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) cell. Upon calcination, the DRIFTS spectra of SiO x/Al 2O 3 reveal a signature unambiguously assignable to isolated Brønsted-acidic silanol species. Surprisingly, the results of this study indicate that the method of preparing SiO x/Al 2O 3 catalysts is less important to the final structure of the silanol sites than the post-treatment conditions. This finding should greatly simplify the methods for synthesizing site-isolated, Brønsted-acidic SiO x/Al 2O 3 catalysts.« less
Structure, spectra and thermal, mechanical, Faraday rotation properties of novel diamagnetic SeO2-PbO-Bi2O3-B2O3 glasses

NASA Astrophysics Data System (ADS)

Chen, Qiuling; Su, Kai; Li, Yantao; Zhao, Zhiwei

2018-06-01

Faraday rotation diamagnetic glass has attracted research attentions in photonics, sensing and magneto optical devices due to their high refractive index, wide transmittance in UV and Fourier transform infrared (FT-IR) range and temperature independent Faraday rotation. Selenite modified heavy metal oxides glasses with composition of xSeO2-(10-x) B2O3-45PbO-45Bi2O3 (x = 0, 1, 5 and 10mol%) and 15%SeO2-40%PbO-45%Bi2O3 have been fabricated by melt-quenching method in present study. The influence of SeO2 on glass forming ability, thermal, mechanical properties and Faraday rotation were evaluated through X-ray Diffraction (XRD), Fourier transforms infrared spectra (FT-IR), Raman, X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC), Vicker's hardness and Verdet constant measurements. XRD spectra reveal that the good vitrification was achieved for glass with SeO2 amounts ≤10% even without B2O3. FT-IR, Raman and XPS spectra ascertain the existence of characteristic vibration of SeO4, SeO3, PbO4, BiO3 and BO3 units. The incorporation of SeO2 increases the connectivity of glassy network by increasing the Tg, thermal stability and mechanical hardness. The small band gap, high polarizable Se4+ ions and isolated SeO3 units contribute to Faraday rotation improvement.
Study of B{yields}X{gamma} decays and determination of |V{sub td}/V{sub ts}|

DOE Office of Scientific and Technical Information (OSTI.GOV)

del Amo Sanchez, P.; Lees, J. P.; Poireau, V.

2010-09-01

Using a sample of 471x10{sup 6} BB events collected with the BABAR detector, we study the sum of seven exclusive final states B{yields}X{sub s(d){gamma}}, where X{sub s(d)} is a strange (nonstrange) hadronic system with a mass of up to 2.0 GeV/c{sup 2}. After correcting for unobserved decay modes, we obtain a branching fraction for b{yields}d{gamma} of (9.2{+-}2.0(stat){+-}2.3(syst))x10{sup -6} in this mass range, and a branching fraction for b{yields}s{gamma} of (23.0{+-}0.8(stat){+-}3.0(syst))x10{sup -5} in the same mass range. We find (B(b{yields}d{gamma})/B(b{yields}s{gamma}))=0.040{+-}0.009(stat){+-}0.010(syst), from which we determine |V{sub td}/V{sub ts}|=0.199{+-}0.022(stat){+-}0.024(syst){+-}0.002(th).
Capturing reflected cladding modes from a fiber Bragg grating with a double-clad fiber coupler.

PubMed

Baiad, Mohamad Diaa; Gagné, Mathieu; Lemire-Renaud, Simon; De Montigny, Etienne; Madore, Wendy-Julie; Godbout, Nicolas; Boudoux, Caroline; Kashyap, Raman

2013-03-25

We present a novel measurement scheme using a double-clad fiber coupler (DCFC) and a fiber Bragg grating (FBG) to resolve cladding modes. Direct measurement of the optical spectra and power in the cladding modes is obtained through the use of a specially designed DCFC spliced to a highly reflective FBG written into slightly etched standard photosensitive single mode fiber to match the inner cladding diameter of the DCFC. The DCFC is made by tapering and fusing two double-clad fibers (DCF) together. The device is capable of capturing backward propagating low and high order cladding modes simply and efficiently. Also, we demonstrate the capability of such a device to measure the surrounding refractive index (SRI) with an extremely high sensitivity of 69.769 ± 0.035 μW/RIU and a resolution of 1.433 × 10(-5) ± 8 × 10(-9) RIU between 1.37 and 1.45 RIU. The device provides a large SRI operating range from 1.30 to 1.45 RIU with sufficient discrimination for all individual captured cladding modes. The proposed scheme can be adapted to many different types of bend, temperature, refractive index and other evanescent wave based sensors.
Hybrid density functional study of band alignment in ZnO-GaN and ZnO-(Ga(1-x)Zn(x))(N(1-x)O(x))-GaN heterostructures.

PubMed

Wang, Zhenhai; Zhao, Mingwen; Wang, Xiaopeng; Xi, Yan; He, Xiujie; Liu, Xiangdong; Yan, Shishen

2012-12-05

The band alignment in ZnO-GaN and related heterostructures is crucial for uses in solar harvesting technology. Here, we report our density functional calculations of the band alignment and optical properties of ZnO-GaN and ZnO-(Ga(1-x)Zn(x))(N(1-x)O(x))-GaN heterostructures using a Heyd-Scuseria-Ernzerhof (HSE) hybrid functional. We found that the conventional GGA functionals underestimate not only the band gap but also the band offset of these heterostructures. Using the hybrid functional calculations, we show that the (Ga(1-x)Zn(x))(N(1-x)O(x)) solid solution has a direct band gap of about 2.608 eV, in good agreement with the experimental data. More importantly, this solid solution forms type-II band alignment with the host materials. A GaN-(Ga(1-x)Zn(x))(N(1-x)O(x))-ZnO core-shell solar cell model is presented to improve the visible light absorption ability and carrier collection efficiency.
Exploring X-ray Emission from Winds in Two Early B-type Binary Systems

NASA Astrophysics Data System (ADS)

Rotter, John P.; Hole, Tabetha; Ignace, Richard; Oskinova, Lida

2017-01-01

The winds of the most massive (O-type) stars have been well studied, but less is known about the winds of early-type B stars, especially in binaries. Extending O-star wind theory to these smaller stars, we would expect them to emit X-rays, and when in a B-star binary system, the wind collision should emit additional X-rays. This combined X-ray flux from nearby B-star binary systems should be detectable with current telescopes. Yet X-ray observations of two such systems with the Chandra Observatory not only show far less emission than predicted, but also vary significantly from each other despite having very similar observed characteristics. We will present these observations, and our work applying the classic Castor, Abbott, and Klein (CAK) wind theory, combined with more recent analytical wind-shock models, attempting to reproduce this unexpected range of observations.

Enhancement of the nonreciprocal magneto-optic effect of TM modes using iron garnet double layers with opposite Faraday rotation

NASA Astrophysics Data System (ADS)

Wallenhorst, M.; Niemöller, M.; Dötsch, H.; Hertel, P.; Gerhardt, R.; Gather, B.

1995-04-01

Garnet films of composition Lu3-xBixFe5-yGayO12 are grown by liquid-phase epitaxy on [111]-oriented substrates of gadolinium gallium garnet. Faraday rotation and saturation magnetization are measured as a function of substitution levels, which range up to x=1.4 and y=1.8, respectively. Nonreciprocal propagation of the TM0 is studied at a wavelength of 1.3 μm. It is shown that the difference between forward and backward propagation constants can be optimized using double layers with opposite sign of the Faraday rotation. Agreement between experiments and calculations is excellent.
A long XMM-Newton campaign on the mode-switching radio pulsar PSR B0943+10

NASA Astrophysics Data System (ADS)

Mereghetti, S.

2017-10-01

Observations obtained in the last years challenged the widespread notion that rotation-powered neutron stars are steady X-ray emitters. Besides the few pulsars showing "magnetar-like" activity, in at least one remarkable object, PSR B0943+10, significant variations, correlated to radio-mode switching have been discovered. Their study opens a new window to investigate the processes responsible for the pulsar radio and high-energy emission. An XMM-Newton Large Program, with simultaneous radio observations with LOFAR, LWA and Arecibo, allowed us to detect X-ray pulsations also during the fainter state and to better constrain the spectral and variability properties of PSR B0943+10. In both radio states the pulsed emission can be described by a thermal blackbody with temperature of a few 10^6 K and the unpulsed emission by a power-law. We discuss a scenario in which both unpulsed non-thermal emission, likely of magnetospheric origin, and pulsed thermal emission from a small polar cap (˜1500 m^2) with a strong non-dipolar field (˜10^{14} G), are present during both modes and vary in intensity in a correlated way. This is broadly consistent with the predictions of the partially screened gap model and does not necessarily imply global magnetospheric rearrangements to explain the mode switching.
Effect of Manganese Addition on the Structure, Magnetic Properties and Microwave Absorption of La0.8Ba0.2MnxFe½(1-x)Ti½(1-x)O3

NASA Astrophysics Data System (ADS)

Adi, W. A.; Indro, M. N.; Kusumastuti, A. A.

2017-03-01

We have carried out modification of La0.8Ba0.2MnxFe½(1-x)Ti½(1-x)O3 (x = 0.1 - 0.8) magnetic materials by wet milling method. Raw materials of La2O3, BaCO3, Fe2O3, TiO2 and MnCO3 were mixed according to stoichiometry calculation for each composition. The mixture was milled for 5 hours and then sintered at 1000 °C for 5 hours. The refinement results by X-ray diffraction pattern shows that the increasing Mn composition enhances the mass fraction of La0.8Ba0.2MnxFe½(1-x)Ti½(1-x)O3 phase which has the same structure as LaMnO3. For x = 0.8 a single phase of LaMnO3 was formed. The single phase has a crystal monoclinic crystal structure with space group of I 1 2 / a 1, with lattice parameters given by a = 5.519(5) Å, b = 5.5537(5) Å and c = 7.8176(9) Å, α = γ = 90o and β = 90.345(6)o, V = 239.64(3) Å3, ρ = 6.463 gr.cm-3, wRp = 5.96, and χ2 (chi-squared) = 1.17. The hysteresis curve shows that the sample with composition x = 0.8 produces ferromagnetic behaviour at room temperature. The ferromagnetic properties arise due to the mixed valence of Mn3+ and Mn4+ ions through a double exchange mechanism. The results of the microwave absorption indicated that there was a broadening of absorption peak frequency at 9.9 GHz. The reflection loss (RL) increases with the increasing of LaMnO3 phase. For x = 0.8 we have the best of RL where the microwave absorption was calculated reaching 95% at the highest peak frequency with a thickness of 1.5 mm. Thus we have been successful in creating a single phase of La0.8Ba0.2MnxFe½(1-x)Ti½(1-x)O3 with application as a microwave absorber.
CMB Polarization B -mode Delensing with SPTpol and Herschel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manzotti, A.; Story, K. T.; Wu, W. L. K.

2017-08-30

Here, we present a demonstration of delensing the observed cosmic microwave background (CMB) Bmode polarization anisotropy. This process of reducing the gravitational-lensing generated B-mode component will become increasingly important for improving searches for the B modes produced by primordial gravitational waves. In this work, we delens B-mode maps constructed from multi-frequency SPTpol observations of a 90 deg 2 patch of sky by subtracting a B-mode template constructed from two inputs: SPTpol E-mode maps and a lensing potential map estimated from the Herschel 500 µm map of the CIB. We find that our delensing procedure reduces the measured B-mode power spectrummore » by 28% in the multipole range 300 < ℓ< 2300; this is shown to be consistent with expectations from theory and simulations and to be robust against systematics. Furthermore, the null hypothesis of no delensing is rejected at 6.9σ. Furthermore, we build and use a suite of realistic simulations to study the general properties of the delensing process and find that the delensing efficiency achieved in this work is limited primarily by the noise in the lensing potential map. We also demonstrate the importance of including realistic experimental non-idealities in the delensing forecasts used to inform instrument and survey-strategy planning of upcoming lower-noise experiments, such as CMB-S4.« less
Structural crossover from nonmodulated to long-period modulated tetragonal phase and anomalous change in ferroelectric properties in the lead-free piezoelectric N a1 /2B i1 /2Ti O3-BaTi O3

NASA Astrophysics Data System (ADS)

Rao, Badari Narayana; Khatua, Dipak Kumar; Garg, Rohini; Senyshyn, Anatoliy; Ranjan, Rajeev

2015-06-01

The highly complex structure-property interrelationship in the lead-free piezoelectric (x )N a1 /2B i1 /2Ti O3- (1 -x ) BaTi O3 is a subject of considerable contemporary debate. Using comprehensive x-ray, neutron diffraction, dielectric, and ferroelectric studies, we have shown the existence of a new criticality in this system at x =0.80 , i.e., well within the conventional tetragonal phase field. This criticality manifests as a nonmonotonic variation of the tetragonality and coercivity and is shown to be associated with a crossover from a nonmodulated tetragonal phase (for x <0.8 ) to a long-period modulated tetragonal phase (for x >0.80 ). It is shown that the stabilization of long-period modulation introduces a characteristic depolarization temperature in the system. While differing qualitatively from the two-phase model often suggested for the critical compositions of this system, our results support the view with regard to the tendency in perovskites to stabilize long-period modulated structures as a result of complex interplay of antiferrodistortive modes [Bellaiche and Iniguez, Phys. Rev. B 88, 014104 (2013), 10.1103/PhysRevB.88.014104; Prosandeev, Wang, Ren, Iniguez, ands Bellaiche, Adv. Funct. Mater. 23, 234 (2013), 10.1002/adfm.201201467].
Thermal behaviour of GdCo1-xMnxO3 cobaltates

NASA Astrophysics Data System (ADS)

Thakur, Rasna; Thakur, Rajesh K.; Gaur, N. K.

2018-05-01

With the objective of exploring the unknown thermodynamic behavior of GdCo1-xMnxO3 family, we present here an investigation of the temperature-dependent (10K≤T≤1000K) thermodynamic properties of GdCo1-xMnxO3 (x=0.1 to 0.8). The specific heat of GdCoO3 with Mn doping in the perovskite structure at B-site has been studied by means of a Modified Rigid Ion Model (MRIM). The cohesive energy, specific heat (C), volume thermal expansion (α) and Gruneisen parameter (γ) of GdCo1-xMnxO3 compounds are also discussed.
A-DNA and B-DNA: Comparing Their Historical X-Ray Fiber Diffraction Images

ERIC Educational Resources Information Center

Lucas, Amand A.

2008-01-01

A-DNA and B-DNA are two secondary molecular conformations (among other allomorphs) that double-stranded DNA drawn into a fiber can assume, depending on the relative water content and other chemical parameters of the fiber. They were the first two forms to be observed by X-ray fiber diffraction in the early 1950s, respectively by Wilkins and…
NMR study of spin fluctuations and superconductivity in LaFeAsO1-xHx

NASA Astrophysics Data System (ADS)

Fujiwara, Naoki; Sakurai, Ryosuke; Iimura, Soushi; Matsuishi, Satoru; Hosono, Hideo; Yamakawa, Yoichi; Kontani, Hiroshi

2013-03-01

We have performed NMR measurements in LaFeAsO1-xHx, an isomorphic compound of LaFeAsO1-xFx. LaFeAsO1-xHx is most recently known for having double superconducting (SC) domes on H doping. LaFeAsO1-xHx is an electron- doped system, and protons act as H-1 as well as F-1. The first SC dome is very similar between F and H doping, suggesting that H doping supplies the same amount of electrons as F doping. Interestingly, an excess amount of H up to x=0.5 can be replaced with O2-. In the H-overdoped regime (x > 0 . 2), LaFeAsO1-xHx undergoes the second superconducting state. We measured the relaxation rate of LaFeAsO1-xHx for x=0.2 and 0.4, and fond an anomalous electronic state; spin fluctuations measured from 1 /T1 T is enhanced with increasing the doping level from x = 0 . 2 to 0.4. The enhancement of spin fluctuations with increasing carrier doping is a new phenomenon that has not observed in LaFeAsO1-xFx in which the upper limit of the doping level is at most x = 0 . 2 . We will discuss the phenomenon in relation to superconductivity. Grant (KAKENHI 23340101) from the Ministry of Education, Sports and Science, Japan
Effects of chemical pressure on the magnetic ground states of the osmate double perovskites SrCaCoOs 6 and Ca 2CoOsO 6

DOE PAGES

Morrow, Ryan; Yan, Jiaqiang; McGuire, Michael A.; ...

2015-09-21

The magnetic ground state in the double perovskite system Sr 2-xCa xCoOsO 6 changes from an antiferromagnet (x=0), to a spin glass (x=1), to a ferrimagnet (x=2) as the Ca content increases. Moreover, this crossover is driven by chemical pressure effects that control the relative strength of magnetic exchange interactions. The synthesis, crystal structure, and magnetism of SrCaCoOsO 6 and Ca 2CoOsO 6 are investigated and compared with Sr 2CoOsO 6. Both compounds adopt a monoclinic crystal structure with rock-salt ordering of Co 2+ and Os 6+ and a -a -b + octahedral tilting, but the average Co–O–Os bond anglemore » evolves from 158.0(3) in SrCaCoOsO 6 to 150.54(9)° in Ca 2CoOsO 6 as the smaller Ca 2+ ion replaces Sr 2+. And while this change may seem minor, it has a profound effect on the magnetism, changing the magnetic ground state from antiferromagnetic in Sr 2CoOsO 6 (TN1=108K, T N2=70K), to a spin glass in SrCaCoOsO 6 (T f1=32K, T f2=13K), to ferrimagnetic in Ca 2CoOsO 6 (T C=145K). Finally, in the first two compounds the observation of two transitions is consistent with weak coupling between the Co and Os sublattices.« less
Favorable Concurrence of Static and Dynamic Phenomena at the Morphotropic Phase Boundary of x BiNi0.5Zr0.5O3-(1 -x )PbTiO3

NASA Astrophysics Data System (ADS)

Datta, K.; Neder, R. B.; Chen, J.; Neuefeind, J. C.; Mihailova, B.

2017-11-01

We reveal that concurrent events of inherent entropy boosting and increased synchronization between A - and B -site cation vibrations of an A B O3 -type perovskite structure give rise to a larger piezoelectric response in a ferroelectric system at its morphotropic phase boundary (MPB). It is further evident that the superior piezoelectric properties of x BiNi0.5Zr0.5O3-(1 -x )PbTiO3 in comparison to x BiNi0.5Ti0.5O3-(1 -x )PbTiO3 are due to the absolute flattening of the local potentials for all ferroelectrically active cations with a higher spontaneous polarization at the MPB. These distinctive features are discovered from the analyses of neutron pair distribution functions and Raman scattering data at ambient conditions, which are particularly sensitive to mesoscopic-scale structural correlations. Altogether this uncovers more fundamental structure-property connections for ferroelectric systems exhibiting a MPB, and thereby has a critical impact in contriving efficient novel materials.
Two-dimensional numerical simulation of O-mode to Z-mode conversion in the ionosphere

NASA Astrophysics Data System (ADS)

Cannon, P. D.; Honary, F.; Borisov, N.

2016-03-01

Experiments in the illumination of the F region of the ionosphere via radio frequency waves polarized in the ordinary mode (O-mode) have revealed that the magnitude of artificial heating-induced effects depends strongly on the inclination angle of the pump beam, with a greater modification to the plasma observed when the heating beam is directed close to or along the magnetic zenith direction. Numerical simulations performed using a recently developed finite-difference time-domain (FDTD) code are used to investigate the contribution of the O-mode to Z-mode conversion process to this effect. The aspect angle dependence and angular size of the radio window for which conversion of an O-mode pump wave to the Z-mode occurs is simulated for a variety of plasma density profiles including 2-D linear gradients representative of large-scale plasma depletions, density-depleted plasma ducts, and periodic field-aligned irregularities. The angular shape of the conversion window is found to be strongly influenced by the background plasma profile. If the Z-mode wave is reflected, it can propagate back toward the O-mode reflection region leading to resonant enhancement of the electric field in this region. Simulation results presented in this paper demonstrate that this process can make a significant contribution to the magnitude of electron density depletion and temperature enhancement around the resonance height and contributes to a strong dependence of the magnitude of plasma perturbation with the direction of the pump wave.
Temperature Dependence of the Tunneling Conductance in Ba_1-xK_xBiO_3

NASA Astrophysics Data System (ADS)

Miyakawa, N.; Ozyuzer, L.; Zasadzinski, J. F.

1997-03-01

Tunneling measurements have been made on high-density polycrystalline pellets of Ba_1-xK_xBiO3 using a point contact method. The temperature dependence (up to 30 K) and magnetic field dependence (up to 6T) of the tunneling conductance has been measured. It is found that at temperatures less than 4.2 K the gap region conductance can be fit with a BCS density of states (dos) and thermal smearing only. However, as the temperature is increased a quasiparticle recombination rate, Γ, which increases as T^n (n ~ 3) must be included in the dos to fit the data. The behavior of Γ (T) does not follow the strong-coupling theory of Kaplan et al. (S.B. Kaplan et al. Phys. Rev. B 14), 4854 (1976) We investigate whether this anomalous power law dependence can come out of Eliashberg theory using the electron-phonon spectral function, a^2F(ω) for Ba_1-xK_xBiO_3.
Morphological and Electrochemical Characterization of Nanostructured Li 4Ti 5O 12 Electrodes Using Multiple Imaging Mode Synchrotron X-ray Computed Tomography

DOE PAGES

Kashkooli, Ali Ghorbani; Foreman, Evan; Farhad, Siamak; ...

2017-09-21

In this study, synchrotron X-ray computed tomography has been utilized using two different imaging modes, absorption and Zernike phase contrast, to reconstruct the real three-dimensional (3D) morphology of nanostructured Li 4Ti 5O 12 (LTO) electrodes. The morphology of the high atomic number active material has been obtained using the absorption contrast mode, whereas the percolated solid network composed of active material and carbon-doped polymer binder domain (CBD) has been obtained using the Zernike phase contrast mode. The 3D absorption contrast image revealed that some LTO nano-particles tend to agglomerate and form secondary micro-sized particles with varying degrees of sphericity. Themore » tortuosity of electrode’s pore and solid phases were found to have directional dependence, different from Bruggeman’s tortuosity commonly used in macro-homogeneous models. The electrode’s heterogeneous structure was investigated by developing a numerical model to simulate galvanostatic discharge process using the Zernike phase contrast mode. The inclusion of CBD in the Zernike phase contrast results in an integrated percolated network of active material and CBD that is highly suited for continuum modeling. As a result, the simulation results highlight the importance of using the real 3D geometry since the spatial distribution of physical and electrochemical properties have a strong non-uniformity due to microstructural heterogeneities.« less
New Phases of YBaCuGeO Superconductors Identified from X-ray Diffraction and Infra-red Absorption Measurements

NASA Astrophysics Data System (ADS)

Abo-Arais, Ahmed; Dawoud, Mohamad Ahmad Taher

2005-01-01

X-ray powder diffraction patterns and infra-red absorption spectra have been evaluated and analysed for the Y1 Ba2 Cu3 O7-d - Gex compound samples prepared by the solid state reaction with x values ranging from 0.0 to 1.13. All samples show bulk superconductivity above liquid nitrogen temperature using the levitation test (Meissner effect). Samples with Ge content up to x = 0.2 have offset Tc between 83K and 92K while the sample with x = 1.13 shows semiconducting behavior above 100K. As a result of the solid state interaction between YBCO and Ge, new phases are observed and determined, mainly three phases are concluded from X-ray powder diffraction analysis: (i) Ba2GeO4 (ii) Y2BaCuO5 (iii) BaCO3. The unit cell parameters a, b and c of the orthorhombic superconducting phase are calculated for all the prepared samples. The anisotropy factor is evaluated and related to the new structural phases in YBCO-Ge composite system. The I-R absorption spectra for the samples with orthorhombic symmetry have been determined. The phonon modes between ~ 400 cm-1 and 630 cm-1 are attributed to the Cu - O octahedron and pyramid vibrations for the CuO2 -planes and CuO-chains, while the peaks in the range from ~ 700 cm-1 to ~ 860 cm-1 may be due to defects such as the new phase Ba2GeO4 and the green phase Y2BaCuO5. The obtained results are discussed according to the superconductor - semi-conductor composite model and with the phonon-mediated charge transfer between CuO2 -planes and CuO- chains through apex oxygen (BaO).
Band Structure Engineering by Substitutional Doping in Solid-State Solutions of [5-Me-PLY(O,O)]2B(1-x)Be(x) Radical Crystals.

PubMed

Bag, Pradip; Itkis, Mikhail E; Stekovic, Dejan; Pal, Sushanta K; Tham, Fook S; Haddon, Robert C

2015-08-12

We report the substitutional doping of solid-state spiro-bis(5-methyl-1,9-oxido-phenalenyl)boron radical ([2]2B) by co-crystallization of this radical with the corresponding spiro-bis(5-methyl-1,9-oxido-phenalenyl)beryllium compound ([2]2Be). The pure compounds crystallize in different space groups ([2]2B, P1̅, Z = 2; [2]2Be, P2₁/c, Z = 4) with distinct packing arrangements, yet we are able to isolate crystals of composition [2]2B(1-x)Be(x), where x = 0-0.59. The phase transition from the P1̅ to the P2₁/c space group occurs at x = 0.1, but the conductivities of the solid solutions are enhanced and the activation energies reduced for values of x = 0-0.25. The molecular packing is driven by the relative concentration of the spin-bearing ([2]2B) and spin-free ([2]2Be) molecules in the crystals, and the extended Hückel theory band structures show that the progressive incorporation of spin-free [2]2Be in the lattice of the [2]2B radical (overall bandwidth, W = 1.4 eV, in the pure compound) leads to very strong narrowing of the bandwidth, which reaches a minimum at [2]2Be (W = 0.3 eV). The results provide a graphic picture of the structural transformations undergone by the lattice, and at certain compositions we are able to identify distinct structures for the [2]2B and [2]2Be molecules in a single crystalline phase.
High-Temperature Thermoelectric Properties of (1 - x) SrTiO3 - ( x) La1/3NbO3 Ceramic Solid Solution

NASA Astrophysics Data System (ADS)

Srivastava, Deepanshu; Azough, F.; Molinari, M.; Parker, S. C.; Freer, R.

2015-06-01

Ceramics based on SrTiO3 are of growing interest as thermoelectric materials because of their high-temperature stability and non-toxicity. Substitution of La and Nb into the perovskite structure provides opportunities to control both the microstructure and properties. Ceramic solid solutions of (1 - x) SrTiO3 - ( x) La1/3NbO3 were prepared by the mixed oxide route, using compositional steps of x = 0.1. Pressed pellets were sintered at temperatures of 1573 K to 1723 K in air. Addition of aliovalent ions (La3+, Nb5+) on the A/B sites (Sr2+, Ti4+) led to A-Site cation deficiency in the stoichiometric compositions and other defect structures which increased carrier concentration. A maximum ZT of 0.004 was obtained for the x = 0.2 stoichiometric sample, although much higher ZT values are possible by sample reduction.
Structure, glass transition temperature and spectroscopic properties of 10Li2O-xP2O5-(89-x)TeO2-1CuO (5≤x≤25 mol%) glass system.

PubMed

Upender, G; Babu, J Chinna; Mouli, V Chandra

2012-04-01

X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), energy dispersive X-ray spectrometry (EDS), differential scanning calorimetry (DSC), infrared (IR), Raman, electron paramagnetic resonance (EPR) and optical absorption studies on 10Li2O-xP2O5-(89-x)TeO2-1CuO glasses (where x=5, 10, 15, 20 and 25 mol%) have been carried out. The amorphous nature of the glasses was confirmed using XRD and FESEM measurements. The glass transition temperature (Tg) of glass samples have been estimated from DSC traces and found that the Tg increases with increasing P2O5 content. Both the IR and Raman studies have been showed that the present glass system consists of [TeO3], [TeO4], [PO3] and [PO4] units. The spin-Hamiltonian parameters such as g∥, g⊥, and A∥ have been determined from EPR spectra and it was found that the Cu2+ ion is present in tetragonal distorted octahedral site with [Formula: see text] as the ground state. Bonding parameters and bonding symmetry of Cu2+ ions have been calculated by correlating EPR and optical data and were found to be composition dependent. Copyright © 2012 Elsevier B.V. All rights reserved.
Effect of Zn doping on structural and dielectric properties of tetragonal Ni{sub 1-x}Zn{sub x}Fe{sub 2}O{sub 4} (0.0 ≤ x ≤ 0.5)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lone, S. A.; Dar, M. A.; Kumar, A.

2015-06-24

A series of Ni-Zn ferrite with compositional formula Ni{sub 1-x}Zn{sub x}Fe{sub 2}O{sub 4} (0.0 ≤ x ≤ 0.5) were prepared by solid-state reaction route. The influence of the Zn content on the structural and dielectric properties of NiFe{sub 2}O{sub 4} was investigated using X-ray powder diffraction (XRD), Raman spectroscopy and dielectric measurements. XRD analysis reveals that the samples are polycrystalline single-phase cubic spinel in structure excluding the presence of any secondary phase corresponding to any structure. Slight variation in the lattice parameter of Zn doped NiFe{sub 2}O{sub 4} has been observed due to difference in ionic radii of cations. Ramanmore » analysis reveals the doublet like nature of A{sub 1g} mode for all synthesized samples. Small shift in Raman modes and increment in the line width has been observed with the doping ions. Furthermore, room temperature dielectric properties of all the prepared samples have been reported. It is observed that for each sample the dielectric constant decreases with an increase of frequency and becomes constant at higher frequencies.« less
Gamma ray shielding properties of PbO-Li2O-B2O3 glasses

NASA Astrophysics Data System (ADS)

Kumar, Ashok

2017-07-01

The mass attenuation coefficients have been measured in (0.6-x) PbO-x Li2O-0.40 B2O3 (where 0≤ x≤0.25 mol%) glasses for photon energies of 356, 662, 1173 and 1332 keV in a narrow beam geometry with an overall scatter acceptance angle of 2.31°. The experimental results are found to be within 3% of their theoretical values. These coefficients were then used to obtain the values of mean free path, effective atomic number and electron density. The shielding properties of these glasses have also been compared among themselves in terms of their mean free path and radiation protection efficiency. The shielding properties prepared glasses have also been compared with standard concretes as well as with the standard shielding glasses. It is found that the prepared glasses are the better shielding substitute to the conventional concretes as well as other standard shielding glasses. The Pb3B4O9 has been found to be the most effective shield.
Nano-crystalline phase evolution and structural modification in Co/V substituted Li2O-Bi2O3-B2O3 glasses

NASA Astrophysics Data System (ADS)

Yadav, Arti; Dahiya, M. S.; Hooda, A.; Agarwal, A.; Khasa, S.

2018-05-01

Co/V substituted Li2O-Bi2O3-B2O3 glasses having composition 7CoO•23Li2O•20Bi2O3•50B2O3(CLBB) and xCoO•(30-x)Li2O•20Bi2O3•50B2O3(x = 0.0, 2.0, 5.0, 7.0 and 10.0 mol%, CVLBB1-5 respectively) developed via melt- quench route. The effect of annealing on structural properties of prepared samples was investigated by using XRD patterns and FTIR spectroscopy. Glasses annealed at 400˚C remained amorphous whereas glasses annealed at 500˚C changes from glasses to glass ceramics. The different crystalline phases i.e. Bi2(V0.9Co0.1)O5.25, LiCoVO4, V2O5 & Bi2(VO5) evolve on annealing at 500°C for 6 hours confirmed from the corresponding XRD patterns. The crystallite size of prepared samples were found to vary as 38-60nm This indicated that CoO and V2O5 introduced in matrix act as crystallizing agents and cause structural modification as studied by the FTIR spectra for all heat treated compositions.

Polarizability, optical basicity and optical properties of SiO2B2O3Bi2O3TeO2 glass system

NASA Astrophysics Data System (ADS)

Kashif, I.; Ratep, A.; Adel, Gh.

2018-07-01

Glasses having a composition xSiO2 xB2O3 (95-2 x) Bi2O35TeO2 where x = (5, 10, 15, 20, 25) prepared by the melt-quenching technique. Thermal stability, density, optical transmittance, and the refractive index of these glasses investigated. Glass samples were transparent in the visible to near-infrared (NIR) region and had a high refractive index. A number of glass samples have high glass-forming ability. This indicates that the quarterly glasses are suitable for optical applications in the visible to the NIR region. Bi2O3 substituted by B2O3 and SiO2 on optical properties discussed. It suggested that the substitution of Bi2O3 increased the density, molar volume, the molar polarizability, optical basicity and refractive index in addition to, the oxygen packing density, the optical energy gap, and metallization decrease. These results are helpful for designing new optical glasses controlled to have a higher refractive index. All studied glass presented high nonlinearities, and the addition of network modifiers made a little contribution. Results clarified the bandgap energy reduction, which associated with the growth within the non-bridging oxygen content with the addition of the network modifier. An increase in the refractive index nonlinearity explained by the optical basicity and the high electronic polarizability of the modifier ions.
FTIR characterization of Bi2Sr2Can-1(Cu1-xFex)3O10+δ with (n=3, x = 0.01) ceramic superconductor

NASA Astrophysics Data System (ADS)

Kumar, Rohitash; Singh, H. S.; Singh, Yadunath

2018-05-01

We synthesized a ceramic superconductor Bi2Sr2Can-1(Cu1-xFex)3O10+δ with (n = 3, x = 0.01) by usual method of oxides superconductor. In this paper, we report the characterization of the said sample by Fourier Transform Infrared Spectroscopic (FTIR) method. This method provides information about structural and compound bonding formation for the studied sample in powder form. The sharper peaks in the recorded spectra are reflecting with a functional group in the high-frequency stretching and low frequency bending modes. In this study, the interaction between Cu-O and Fe-O bond occupies octahedral and tetrahedral positions due to occupancy of cations and anions. The increasing amount of (Fe) is showing the transmittance (T%) behavior with different bonding vibration modes.
Inclusive χbJ(nP) decays to D0X

NASA Astrophysics Data System (ADS)

Briere, R. A.; Ferguson, T.; Tatishvili, G.; Vogel, H.; Watkins, M. E.; Rosner, J. L.; Alexander, J. P.; Cassel, D. G.; Duboscq, J. E.; Ehrlich, R.; Fields, L.; Galik, R. S.; Gibbons, L.; Gray, R.; Gray, S. W.; Hartill, D. L.; Heltsley, B. K.; Hertz, D.; Kandaswamy, J.; Kreinick, D. L.; Kuznetsov, V. E.; Mahlke-Krüger, H.; Mohapatra, D.; Onyisi, P. U. E.; Patterson, J. R.; Peterson, D.; Riley, D.; Ryd, A.; Sadoff, A. J.; Shi, X.; Stroiney, S.; Sun, W. M.; Wilksen, T.; Athar, S. B.; Patel, R.; Yelton, J.; Rubin, P.; Eisenstein, B. I.; Karliner, I.; Mehrabyan, S.; Lowrey, N.; Selen, M.; White, E. J.; Wiss, J.; Mitchell, R. E.; Shepherd, M. R.; Besson, D.; Pedlar, T. K.; Cronin-Hennessy, D.; Gao, K. Y.; Hietala, J.; Kubota, Y.; Klein, T.; Lang, B. W.; Poling, R.; Scott, A. W.; Zweber, P.; Dobbs, S.; Metreveli, Z.; Seth, K. K.; Tomaradze, A.; Libby, J.; Powell, A.; Wilkinson, G.; Ecklund, K. M.; Love, W.; Savinov, V.; Lopez, A.; Mendez, H.; Ramirez, J.; Ge, J. Y.; Miller, D. H.; Shipsey, I. P. J.; Xin, B.; Adams, G. S.; Anderson, M.; Cummings, J. P.; Danko, I.; Hu, D.; Moziak, B.; Napolitano, J.; He, Q.; Insler, J.; Muramatsu, H.; Park, C. S.; Thorndike, E. H.; Yang, F.; Artuso, M.; Blusk, S.; Khalil, S.; Li, J.; Mountain, R.; Nisar, S.; Randrianarivony, K.; Sultana, N.; Skwarnicki, T.; Stone, S.; Wang, J. C.; Zhang, L. M.; Bonvicini, G.; Cinabro, D.; Dubrovin, M.; Lincoln, A.; Naik, P.; Rademacker, J.; Asner, D. M.; Edwards, K. W.; Reed, J.

2008-11-01

Using Υ(2S) and Υ(3S) data collected with the CLEO III detector we have searched for decays of χbJ to final states with open charm. We fully reconstruct D0 mesons with pD0>2.5GeV/c in three decay modes (K-π+, K-π+π0, and K-π-π+π+) in coincidence with radiative transition photons that tag the production of one of the χbJ(nP) states. Significant signals are obtained for the two J=1 states. Recent nonrelativistic QCD (NRQCD) calculations of χbJ(nP)→c cmacr X depend on one nonperturbative parameter per χbJ triplet. The extrapolation from the observed D0X rate over a limited momentum range to a full c cmacr X rate also depends on these same parameters. Using our data to fit for these parameters, we extract results which agree well with NRQCD predictions, confirming the expectation that charm production is largest for the J=1 states. In particular, for J=1, our results are consistent with c cmacr g accounting for about one-quarter of all hadronic decays.
Axial interface optical phonon modes in a double-nanoshell system.

PubMed

Kanyinda-Malu, C; Clares, F J; de la Cruz, R M

2008-07-16

Within the framework of the dielectric continuum (DC) model, we analyze the axial interface optical phonon modes in a double system of nanoshells. This system is constituted by two identical equidistant nanoshells which are embedded in an insulating medium. To illustrate our results, typical II-VI semiconductors are used as constitutive polar materials of the nanoshells. Resolution of Laplace's equation in bispherical coordinates for the potentials derived from the interface vibration modes is made. By imposing the usual electrostatic boundary conditions at the surfaces of the two-nanoshell system, recursion relations for the coefficients appearing in the potentials are obtained, which entails infinite matrices. The problem of deriving the interface frequencies is reduced to the eigenvalue problem on infinite matrices. A truncating method for these matrices is used to obtain the interface phonon branches. Dependences of the interface frequencies on the ratio of inter-nanoshell separation to core size are obtained for different systems with several values of nanoshell interdistance. Effects due to the change of shell and embedding materials are also investigated in interface phonon modes.
Effects of configurational disorder on the elastic properties of icosahedral boron-rich alloys based on B{sub 6}O, B{sub 13}C{sub 2}, and B{sub 4}C, and their mixing thermodynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ektarawong, A., E-mail: anekt@ifm.liu.se; Hultman, L.; Birch, J.

The elastic properties of alloys between boron suboxide (B{sub 6}O) and boron carbide (B{sub 13}C{sub 2}), denoted by (B{sub 6}O){sub 1−x}(B{sub 13}C{sub 2}){sub x}, as well as boron carbide with variable carbon content, ranging from B{sub 13}C{sub 2} to B{sub 4}C are calculated from first-principles. Furthermore, the mixing thermodynamics of (B{sub 6}O){sub 1−x}(B{sub 13}C{sub 2}){sub x} is studied. A superatom-special quasirandom structure approach is used for modeling different atomic configurations, in which effects of configurational disorder between the carbide and suboxide structural units, as well as between boron and carbon atoms within the units, are taken into account. Elastic propertiesmore » calculations demonstrate that configurational disorder in B{sub 13}C{sub 2}, where a part of the C atoms in the CBC chains substitute for B atoms in the B{sub 12} icosahedra, drastically increase the Young’s and shear modulus, as compared to an atomically ordered state, B{sub 12}(CBC). These calculated elastic moduli of the disordered state are in excellent agreement with experiments. Configurational disorder between boron and carbon can also explain the experimentally observed almost constant elastic moduli of boron carbide as the carbon content is changed from B{sub 4}C to B{sub 13}C{sub 2}. The elastic moduli of the (B{sub 6}O){sub 1−x}(B{sub 13}C{sub 2}){sub x} system are also practically unchanged with composition if boron-carbon disorder is taken into account. By investigating the mixing thermodynamics of the alloys, in which the Gibbs free energy is determined within the mean-field approximation for the configurational entropy, we outline the pseudo-binary phase diagram of (B{sub 6}O){sub 1−x}(B{sub 13}C{sub 2}){sub x}. The phase diagram reveals the existence of a miscibility gap at all temperatures up to the melting point. Also, the coexistence of B{sub 6}O-rich as well as ordered or disordered B{sub 13}C{sub 2}-rich domains in the material
Lattice parameter functions of (AmyU1-y)O2-x based on XRD and XANES measurements

NASA Astrophysics Data System (ADS)

Nishi, Tsuyoshi; Nakada, Masami; Hirata, Masaru

2017-12-01

The lattice parameters of (Am0.50U0.50)O2.0, (Am0.37U0.63)O2.0, and (Am0.50U0.50)O2-x were determined by powder X-ray diffraction with Cu Kα radiation. In addition, the lattice parameter functions of (AmyU1-y)O2-x (0.00<x<0.25, 0.00O2 and (Am3+yU4+1-y)O2-y/2 based on the results of X-ray diffraction and the ionic radii of Am3+, U4+, and U5+. In order to confirm the valence state of Am and U in (AmyU1-y)O2-x, the X-ray absorption near-edge structure measurements were performed in the transmission mode at the Am-LIII and U-LIII absorption edges of (Am0.50U0.50)O2.0, (Am0.50U0.50)O2-x, and UO2.0.
Analysis of the hot-cavity mode composition of an X-band overmoded relativistic backward wave oscillators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan, Yuzhang; Zhang, Jun; Zhong, Huihuang

Overmoded RBWO (Relativistic Backward Wave Oscillators) is utilized more and more often for its high power capacity. However, both sides of SWS (Slow Wave Structure) of overmoded RBWO consist multi TM{sub 0n} modes; in order to achieve the design of reflector, it is essential to make clear of the mode composition of TM{sub 0n}. NUDT (National University of Defence Technology) had done research of the output mode composition in overmoded O-type Cerenkov HPM (High Power Microwave) Oscillators in detail, but in the area where the electron beam exists, the influence of electron beam must be taken into account. Hot-cavity dispersionmore » equation is figured out in this article first, and then analyzes the hot-cavity mode composition of an X-band overmoded RBWO tentatively. The results show that in collimating hole, the hot-cavity mode analysis is more accurate.« less
The Vaporization of B2O3(l) to B2O3(g) and B2O2(g)

NASA Technical Reports Server (NTRS)

Jacobson, Nathan S.; Myers, Dwight L.

2011-01-01

The vaporization of B2O3 in a reducing environment leads to formation of both B2O3(g) and B2O2(g). While formation of B2O3(g) is well understood, many questions about the formation of B2O2(g) remain. Previous studies using B(s) + B2O3(l) have led to inconsistent thermodynamic data. In this study, it was found that after heating, B(s) and B2O3(l) appear to separate and variations in contact area likely led to the inconsistent vapor pressures of B2O2(g). To circumvent this problem, an activity of boron is fixed with a two-phase mixture of FeB and Fe2B. Both second and third law enthalpies of formation were measured for B2O2(g) and B2O3(g). From these the enthalpies of formation at 298.15 K are calculated to be -479.9 +/- 41.5 kJ/mol for B2O2(g) and -833.4 +/- 13.1 kJ/mol for B2O3(g). Ab initio calculations to determine the enthalpies of formation of B2O2(g) and B2O3(g) were conducted using the W1BD composite method and show good agreement with the experimental values.
X-24B on Lakebed Showing Upper Body Shape

NASA Technical Reports Server (NTRS)

1972-01-01

The sleek, futuristic shape of the X-24B lifting body research vehicle can be clearly seen in this look-down view of the aircraft on Rogers Dry Lake, adjacent to the NASA Flight Research Center, Edwards, California. The X-24 was one of a group of lifting bodies flown by the NASA Flight Research Center (now Dryden Flight Research Center), Edwards, California, in a joint program with the U.S. Air Force at Edwards Air Force Base from 1963 to 1975. The lifting bodies were used to demonstrate the ability of pilots to maneuver and safely land wingless vehicles designed to fly back to Earth from space and be landed like an airplane at a predetermined site. Lifting bodies' aerodynamic lift, essential to flight in the atmosphere, was obtained from their shape. The addition of fins and control surfaces allowed the pilots to stabilize and control the vehicles and regulate their flight paths. Built by Martin Aircraft Company, Maryland, for the U.S. Air Force, the X-24A was a bulbous vehicle shaped like a teardrop with three vertical fins at the rear for directional control. It weighed 6,270 pounds, was 24.5 feet long and 11.5 feet wide (measuring just the fuselage, not the distance between the tips of the outboard fins). Its first unpowered glide flight was on April 17, 1969, with Air Force Maj. Jerauld Gentry at the controls. Gentry also piloted its first powered flight on March 19, 1970. The X-24A was flown 28 times in the program that, like the HL-10, validated the concept that a Space Shuttle vehicle could be landed unpowered. The fastest speed achieved by the X-24A was 1,036 miles per hour (mph-Mach 1.6). Its maximum altitude was 71,400 feet. It was powered by an XLR-11 rocket engine with a maximum theoretical vacuum thrust of 8,480 pounds. The X-24A was later modified into the X-24B. The bulbous shape of the X-24A was converted into a 'flying flatiron' shape with a rounded top, flat bottom, and double delta platform that ended in a pointed nose. The X-24B demonstrated
Low-temperature sequential pulsed chemical vapor deposition of ternary B{sub x}Ga{sub 1-x}N and B{sub x}In{sub 1-x}N thin film alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haider, Ali, E-mail: ali.haider@bilkent.edu.tr, E-mail: biyikli@unam.bilkent.edu.tr; Kizir, Seda; Ozgit-Akgun, Cagla

In this work, the authors have performed sequential pulsed chemical vapor deposition of ternary B{sub x}Ga{sub 1-x}N and B{sub x}In{sub 1-x}N alloys at a growth temperature of 450 °C. Triethylboron, triethylgallium, trimethylindium, and N{sub 2} or N{sub 2}/H{sub 2} plasma have been utilized as boron, gallium, indium, and nitrogen precursors, respectively. The authors have studied the compositional dependence of structural, optical, and morphological properties of B{sub x}Ga{sub 1-x}N and B{sub x}In{sub 1-x}N ternary thin film alloys. Grazing incidence X-ray diffraction measurements showed that boron incorporation in wurtzite lattice of GaN and InN diminishes the crystallinity of B{sub x}Ga{sub 1-x}N and B{submore » x}In{sub 1-x}N sample. Refractive index decreased from 2.24 to 1.65 as the B concentration of B{sub x}Ga{sub 1-x}N increased from 35% to 88%. Similarly, refractive index of B{sub x}In{sub 1-x}N changed from 1.98 to 1.74 for increase in B concentration value from 32% to 87%, respectively. Optical transmission band edge values of the B{sub x}Ga{sub 1-x}N and B{sub x}In{sub 1-x}N films shifted to lower wavelengths with increasing boron content, indicating the tunability of energy band gap with alloy composition. Atomic force microscopy measurements revealed an increase in surface roughness with boron concentration of B{sub x}Ga{sub 1-x}N, while an opposite trend was observed for B{sub x}In{sub 1-x}N thin films.« less
Pixelated transmission-mode diamond X-ray detector.

PubMed

Zhou, Tianyi; Ding, Wenxiang; Gaowei, Mengjia; De Geronimo, Gianluigi; Bohon, Jen; Smedley, John; Muller, Erik

2015-11-01

Fabrication and testing of a prototype transmission-mode pixelated diamond X-ray detector (pitch size 60-100 µm), designed to simultaneously measure the flux, position and morphology of an X-ray beam in real time, are described. The pixel density is achieved by lithographically patterning vertical stripes on the front and horizontal stripes on the back of an electronic-grade chemical vapor deposition single-crystal diamond. The bias is rotated through the back horizontal stripes and the current is read out on the front vertical stripes at a rate of ∼ 1 kHz, which leads to an image sampling rate of ∼ 30 Hz. This novel signal readout scheme was tested at beamline X28C at the National Synchrotron Light Source (white beam, 5-15 keV) and at beamline G3 at the Cornell High Energy Synchrotron Source (monochromatic beam, 11.3 keV) with incident beam flux ranges from 1.8 × 10(-2) to 90 W mm(-2). Test results show that the novel detector provides precise beam position (positional noise within 1%) and morphology information (error within 2%), with an additional software-controlled single channel mode providing accurate flux measurement (fluctuation within 1%).
X-24B with Test Pilot Michael V. Love

NASA Technical Reports Server (NTRS)

1973-01-01

Force Maj. Jerauld Gentry at the controls. Gentry also piloted its first powered flight on March 19, 1970. The X-24A was flown 28 times in the program that, like the HL-10, validated the concept that a Space Shuttle vehicle could be landed unpowered. The fastest speed achieved by the X-24A was 1,036 miles per hour (mph--Mach 1.6). Its maximum altitude was 71,400 feet. It was powered by an XLR-11 rocket engine with a maximum theoretical vacuum thrust of 8,480 pounds. The X-24A was later modified into the X-24B. The bulbous shape of the X-24A was converted into a 'flying flatiron' shape with a rounded top, flat bottom, and double delta platform that ended in a pointed nose. The X-24B demonstrated that accurate unpowered reentry vehicle landings were operationally feasible. Top speed achieved by the X-24B was 1,164 mph and the highest altitude it reached was 74,130 feet. The vehicle is on display at the Air Force Museum, Wright-Patterson Air Force Base, Ohio. The pilot on the last powered flight of the X-24B was Bill Dana, who also flew the last X-15 flight about seven years earlier. The X-24A shape was later borrowed for the X-38 Crew Return Vehicle (CRV) technology demonstrator for the International Space Station. The X-24B is on public display at the Air Force Museum, Wright-Patterson AFB, Ohio.
Phase coexistence and high electrical properties in (KxNa0.96-xLi0.04)(Nb0.85Ta0.15)O3 piezoelectric ceramics

NASA Astrophysics Data System (ADS)

Chang, Yunfei; Yang, Zupei; Ma, Difei; Liu, Zonghuai; Wang, Zenglin

2009-03-01

(KxNa0.96-xLi0.04)(Nb0.85Ta0.15)O3 lead-free piezoelectric ceramics were produced by conventional solid-state reaction method. The effects of K/Na ratio on the phase transitional behavior, Raman spectrum, microstructure, and dielectric, piezoelectric, and ferroelectric properties of the ceramics have been investigated. The phase structure of the ceramics undergoes a transition from orthorhombic to tetragonal phase with increasing x. A double-degenerate symmetric O-Nb-O stretching vibration v1 and a triply degenerate symmetric O-Nb-O bending vibration v5 are detected as relatively strong scattering in the Raman spectra. The peak shifts of v5 and v1 modes all have a discontinuity with x between 0.42 and 0.46, which may suggest the coexistence of orthorhombic and tetragonal phases in this range. Properly modifying x reduces the sintering temperature, promotes the grain growth behavior, and improves the density of the ceramics. The polymorphic phase transition (at To -t) is shifted to near room temperature by increasing x to 0.44 (K/Na ratio of about 0.85:1), and the coexistence of orthorhombic and tetragonal phases in the ceramics at x =0.44 results in the optimized electrical properties (d33=291 pC/N, kp=0.54, ɛr=1167, tan δ=0.018, To -t=35 °C, TC=351 °C, Pr=27.65 μC/cm2, and Ec=8.63 kV/cm). The results show that the equal K/Na ratio is not an essential condition in obtaining optimized electrical properties in (KxNa0.96-xLi0.04)(Nb0.85Ta0.15)O3 ceramics.
Near-zero thermal expansion and phase transitions in HfMg1-xZnxMo3O12

NASA Astrophysics Data System (ADS)

Li, Sailei; Ge, Xianghong; Yuan, Huanli; Chen, Dongxia; Guo, Juan; Shen, Ruofan; Chao, Mingju; Liang, Erjun

2018-04-01

The effects of Zn2+ incorporation on the phase formation, thermal expansion, phase transition and vibrational properties ofHfMg1-xZnxMo3O12 are investigated by XRD, dilatometry and Raman spectroscopy. The results show that (i) single phase formation is only possible for x≤0.5, otherwise, additional phases ofHfMo2O8 and ZnMoO4 appear; (ii) The phase transition temperature from monoclinic to orthorhombic structure of the single phase HfMg1-xZnxMo3O12 can be well tailored, which increases with the content of Zn2+; (iii) The incorporation of Zn2+ leads to an pronounced reduction in the positive expansion of the b-axis and a enhanced negative thermal expansion in the c-axes, leading to a near-zero thermal expansion property with lower anisotropy over a wide temperature range; (iv) Replacement of Mg2+ by Zn2+ weakens the Mo-O bonds as revealed by obvious red shifts of all the Mo-O stretching modes with increasing the content of Zn2+ and improves the sintering performance of the samples which is observed by SEM. The mechanisms of the negative and near-zero thermal expansion are discussed.
Effect of Sr doping on structural and magnetic behavior of SmBa1-xSrxCo2O5+δ (x = 0 and 1)

NASA Astrophysics Data System (ADS)

Kumari, Archana; Dhanasekhar, C.; Das, A. K.

2018-05-01

Layered double perovskite, SmBa1-xSrxCo2O5+δ (x = 0, δ = 0.5 and x = 1, δ = 1) samples were prepared by solid state reaction method. X-ray diffraction studies show that the SmBaCo2O5.5 sample crystallizes in the orthorhombic crystal structure with Pmmm space group, whereas SmSrCo2O6 sample crystallizes in the orthorhombic crystal structure with Pnma space group. The temperature dependent magnetization of the SmBaCo2O5.5 sample shows a paramagnetic (PM)-ferromagnetic (FM) and a FM-antiferromagnetic (AFM) transitions at TC = 267 K and TN = 221 K, respectively. In contrast, the SmSrCo2O6 sample shows a PM-FM transition at TC = 175 K. According to Goodenough-Kanamori-Anderson rules, the ferromagnetic behavior in SmSrCo2O6 can be understood from the super exchange interaction between the intermediate spin Co3+ and low spin Co4+ via O2- (IS Co3+ -O2- - LS Co4+). The change in magnetic entropy (ΔSMmax) is found to be maximum for the SmSrCo2O6 sample.
Development of AlN and TiB2 Composites with Nb2O5, Y2O3 and ZrO2 as Sintering Aids

PubMed Central

González, José C.; Rodríguez, Miguel Á.; Figueroa, Ignacio A.; Villafuerte-Castrejón, María-Elena; Díaz, Gerardo C.

2017-01-01

The synthesis of AlN and TiB2 by spark plasma sintering (SPS) and the effect of Nb2O5, Y2O3 and ZrO2 additions on the mechanical properties and densification of the produced composites is reported and discussed. After the SPS process, dense AlN and TiB2 composites with Nb2O5, Y2O3 and ZrO2 were successfully prepared. X-ray diffraction analysis showed that in the AlN composites, the addition of Nb2O5 gives rise to Nb4N3 during sintering. The compound Y3Al5O12 (YAG) was observed as precipitate in the sample with Y2O3. X-ray diffraction analysis of the TiB2 composites showed TiB2 as a single phase in these materials. The maximum Vickers and toughness values were 14.19 ± 1.43 GPa and 27.52 ± 1.75 GPa for the AlN and TiB2 composites, respectively. PMID:28772681
Sol-gel syntheses, luminescence, and energy transfer properties of α-GdB5O9:Ce(3+)/Tb(3+) phosphors.

PubMed

Sun, Xiaorui; Gao, Wenliang; Yang, Tao; Cong, Rihong

2015-02-07

Sol-gel method was applied to prepare homogenous and highly crystalline phosphors with the formulas α-GdB5O9:xTb(3+) (0 ≤ x ≤ 1), α-Gd1-xCexB5O9 (0 ≤ x ≤ 0.40), α-GdB5O9:xCe(3+), 0.30Tb(3+) (0 ≤ x ≤ 0.15) and α-GdB5O9:0.20Ce(3+), xTb(3+) (0 ≤ x ≤ 0.10). The success of the syntheses was proved by the linear shrinkage or expansion of the cell volumes against the substitution contents. In α-GdB5O9:xTb(3+), an efficient energy transfer from Gd(3+) to Tb(3+) was observed and there was no luminescence quenching. The exceptionally high efficiency of the f-f excitations of Tb(3+) implies that these phosphors may be good green-emitting UV-LED phosphors. For α-Gd1-xCexB5O9, Ce(3+) absorbs the majority of the energy and transfers it to Gd(3+). Therefore, the co-doping of Ce(3+) and Tb(3+) leads to a significant enhancement in the green emission of Tb(3+). Our current results together with the study on α-GdB5O9:xEu(3+) in the literature indicate that α-GdB5O9 is a good phosphor host with advantages including controllable preparation, diverse cationic doping, the absence of concentration quenching, and effective energy transfer.
Manganese-induced magnetic symmetry breaking and its correlation with the metal-insulator transition in bilayered S r 3 ( R u 1 - x M n x ) 2 O 7

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Qiang; Ye, Feng; Tian, Wei

Bilayered Sr 3Ru 2O 7 is an unusual metamagnetic metal with inherently antiferromagnetic (AFM) and ferromagnetic (FM) fluctuations. Partial substitution of Ru by Mn results in the establishment of a metal-insulator transition (MIT) at TMIT and AFM ordering at TM in Sr 3(Ru 1-xMn x) 2O 7. Using elastic neutron scattering, we investigated the effect of Mn doping on the magnetic structure, in-plane magnetic correlation lengths and their correlation to the MIT in Sr 3(Ru 1-xMn x) 2O 7 (x=0.06 and 0.12). With the increase of Mn doping (x) from 0.06 to 0.12 or the decrease of temperatures for x=0.12,more » an evolution from an in-plane short-range to long-range antiferromagnetic (AFM) ground state occurs. For both compounds, the magnetic ordering has a double-stripe configuration, and the onset of magnetic correlation with an anisotropic behavior coincides with the sharp rise in electrical resistivity and specific heat. Since it does not induce a measurable lattice distortion, the double-stripe antiferromagnetic order with anisotropic spin texture breaks symmetry from a C 4v crystal lattice to a C 2v magnetic sublattice. These observations shed light on an age-old question regarding the Slater versus Mott-type MIT.« less
Manganese-induced magnetic symmetry breaking and its correlation with the metal-insulator transition in bilayered S r 3 ( R u 1 - x M n x ) 2 O 7

DOE PAGES

Zhang, Qiang; Ye, Feng; Tian, Wei; ...

2017-06-12

Bilayered Sr 3Ru 2O 7 is an unusual metamagnetic metal with inherently antiferromagnetic (AFM) and ferromagnetic (FM) fluctuations. Partial substitution of Ru by Mn results in the establishment of a metal-insulator transition (MIT) at TMIT and AFM ordering at TM in Sr 3(Ru 1-xMn x) 2O 7. Using elastic neutron scattering, we investigated the effect of Mn doping on the magnetic structure, in-plane magnetic correlation lengths and their correlation to the MIT in Sr 3(Ru 1-xMn x) 2O 7 (x=0.06 and 0.12). With the increase of Mn doping (x) from 0.06 to 0.12 or the decrease of temperatures for x=0.12,more » an evolution from an in-plane short-range to long-range antiferromagnetic (AFM) ground state occurs. For both compounds, the magnetic ordering has a double-stripe configuration, and the onset of magnetic correlation with an anisotropic behavior coincides with the sharp rise in electrical resistivity and specific heat. Since it does not induce a measurable lattice distortion, the double-stripe antiferromagnetic order with anisotropic spin texture breaks symmetry from a C 4v crystal lattice to a C 2v magnetic sublattice. These observations shed light on an age-old question regarding the Slater versus Mott-type MIT.« less
E × B flow shear drive of the linear low- n modes of EHO in the QH-mode regime [ E × B flow shear drive of EHO in the QH-mode regime

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, G. S.; Wan, B. N.; Wang, Y. F.

A new mechanism is identified for driving the edge harmonic oscillations (EHOs) in the quiescent H-mode (QH-mode) regime, where a strong E × B flow shear destabilizes low-n kink/peeling modes, separately from the previously found Kelvin-Helmholtz drive. We find that the differential advection of mode vorticity by sheared E × B flows modifies the two-dimensional pattern of mode electrostatic potential perpendicular to the magnetic field lines, which in turn causes a radial expansion of the mode structure, an increase of field line bending away from the mode rational surface, and a reduction of inertial stabilization. This enhances the kink drivemore » as the parallel wavenumber increases significantly away from the rational surface where the magnetic shear is also strong. A newly developed model reproduces the observations that at high E × B flow shear only a few low-n modes remain unstable, consistent with the EHO behavior, while at low E × B flow shear the unstable mode spectrum is significantly broadened, consistent with the low-n broadband electromagnetic turbulence behavior observed recently in the DIII-D tokamak. This destabilization is also shown to be independent of the sign of the flow shear, as observed experimentally, and has not been taken into 2 / 46 account in previous pedestal linear stability analyses. Verification of the veracity of this EHO mechanism will require analysis of the nonlinear evolution of low-n kink/peeling modes so destabilized in the linear regime.« less

E × B flow shear drive of the linear low- n modes of EHO in the QH-mode regime [ E × B flow shear drive of EHO in the QH-mode regime

DOE PAGES

Xu, G. S.; Wan, B. N.; Wang, Y. F.; ...

2017-07-18

A new mechanism is identified for driving the edge harmonic oscillations (EHOs) in the quiescent H-mode (QH-mode) regime, where a strong E × B flow shear destabilizes low-n kink/peeling modes, separately from the previously found Kelvin-Helmholtz drive. We find that the differential advection of mode vorticity by sheared E × B flows modifies the two-dimensional pattern of mode electrostatic potential perpendicular to the magnetic field lines, which in turn causes a radial expansion of the mode structure, an increase of field line bending away from the mode rational surface, and a reduction of inertial stabilization. This enhances the kink drivemore » as the parallel wavenumber increases significantly away from the rational surface where the magnetic shear is also strong. A newly developed model reproduces the observations that at high E × B flow shear only a few low-n modes remain unstable, consistent with the EHO behavior, while at low E × B flow shear the unstable mode spectrum is significantly broadened, consistent with the low-n broadband electromagnetic turbulence behavior observed recently in the DIII-D tokamak. This destabilization is also shown to be independent of the sign of the flow shear, as observed experimentally, and has not been taken into 2 / 46 account in previous pedestal linear stability analyses. Verification of the veracity of this EHO mechanism will require analysis of the nonlinear evolution of low-n kink/peeling modes so destabilized in the linear regime.« less
Strain-induced tetragonal distortions and multiferroic properties in polycrystalline Sr 1 - x B a x Mn O 3 ( x = 0.43 - 0.45 ) perovskites

DOE Office of Scientific and Technical Information (OSTI.GOV)

Somaily, H.; Kolesnik, S.; Mais, J.

Here, we report a comprehensive structure-property phase diagram of unique single-ion type-1 multiferroic pseudocubic Sr 1-xBa xMnO 3 perovskites. Employing a specially designed multi-step reduction-oxidation synthesis technique, we describe the successful synthesis of previously unknown Sr 1-xBa xMnO 3 compositions in their polycrystalline form with a significantly extended Ba solubility limit that is only rivaled by a very limited number of crystals and thin films grown under non-equilibrium conditions. Understanding the multiferroic interplay with structure in Sr 1-xBa xMnO 3 is of great importance as it opens the door wide to the development of newer materials from the parent (AA’)(BB’)more » O 3 system with enhanced properties. To this end, using a combination of time-of-flight neutron and synchrotron x-ray scattering techniques, we determined the exact structures and quantified the Mn and oxygen polar distortions above and below T C and T N. In its ferroelectric state, the system crystalizes in the noncentrosymmetric tetragonal P4mm space group which gives rise to a large electric dipole moment P s, in the z-direction, of 18.4 and 29.5 µC/cm 2 for x = 0.43 and 0.45, respectively. The two independently driven ferroelectric and magnetic order parameters are single-handedly accommodated by the Mn sublattice leading to a novel strain-assisted multiferroic behavior in agreement with many theoretical predictions. Our neutron diffraction results demonstrate the large and tunable suppression of the ferroelectric order at the onset of AFM ordering and confirm the coexistence and strong coupling of the two ferroic orders below T N. The refined magnetic moments confirm the strong covalent bonding between Mn and the oxygen anions which is necessary for stabilizing the ferroelectric phase.« less
Strain-induced tetragonal distortions and multiferroic properties in polycrystalline Sr 1 - x B a x Mn O 3 ( x = 0.43 - 0.45 ) perovskites

DOE PAGES

Somaily, H.; Kolesnik, S.; Mais, J.; ...

2018-05-17

Here, we report a comprehensive structure-property phase diagram of unique single-ion type-1 multiferroic pseudocubic Sr 1-xBa xMnO 3 perovskites. Employing a specially designed multi-step reduction-oxidation synthesis technique, we describe the successful synthesis of previously unknown Sr 1-xBa xMnO 3 compositions in their polycrystalline form with a significantly extended Ba solubility limit that is only rivaled by a very limited number of crystals and thin films grown under non-equilibrium conditions. Understanding the multiferroic interplay with structure in Sr 1-xBa xMnO 3 is of great importance as it opens the door wide to the development of newer materials from the parent (AA’)(BB’)more » O 3 system with enhanced properties. To this end, using a combination of time-of-flight neutron and synchrotron x-ray scattering techniques, we determined the exact structures and quantified the Mn and oxygen polar distortions above and below T C and T N. In its ferroelectric state, the system crystalizes in the noncentrosymmetric tetragonal P4mm space group which gives rise to a large electric dipole moment P s, in the z-direction, of 18.4 and 29.5 µC/cm 2 for x = 0.43 and 0.45, respectively. The two independently driven ferroelectric and magnetic order parameters are single-handedly accommodated by the Mn sublattice leading to a novel strain-assisted multiferroic behavior in agreement with many theoretical predictions. Our neutron diffraction results demonstrate the large and tunable suppression of the ferroelectric order at the onset of AFM ordering and confirm the coexistence and strong coupling of the two ferroic orders below T N. The refined magnetic moments confirm the strong covalent bonding between Mn and the oxygen anions which is necessary for stabilizing the ferroelectric phase.« less
Fragile morphotropic phase boundary and phase stability in the near-surface region of the relaxor ferroelectric (1 -x ) Pb (Z n1 /3N b2 /3) O3-x PbTi O3 : [001] field-cooled phase diagrams

NASA Astrophysics Data System (ADS)

Wang, Yaojin; Wang, Ding; Yuan, Guoliang; Ma, He; Xu, Feng; Li, Jiefang; Viehland, D.; Gehring, Peter M.

2016-11-01

We have examined the effects of field cooling on the phase diagram of the relaxor system (1 -x ) Pb (Z n1 /3N b2 /3) O3-x PbTi O3 (PZN-x PT ) for compositions near the morphotropic phase boundary (MPB). High-resolution diffraction measurements using Cu Kα x rays, which probe ≈3 μ m below the crystal surface, were made on field-cooled (FC) single-crystal specimens of PZN-4.5 %PT and PZN-6.5 %PT under electric fields of 1 and 2 kV/cm applied along [001] and combined with previous neutron diffraction data, which probe the entire crystal volume, for FC PZN-8 %PT [Ohwada et al., Phys. Rev. B 67, 094111 (2003), 10.1103/PhysRevB.67.094111]. A comparison to the zero-field-cooled (ZFC) PZN-x PT phase diagram reveals several interesting features: (1) The short-range monoclinic phase observed in the ZFC state on the low-PT side of the MPB is replaced by a monoclinic MA phase; (2) field cooling extends the tetragonal phase to higher temperatures and lower-PT concentrations; (3) the orthorhombic phase near the MPB is replaced by a monoclinic MC phase; (4) the vertical MPB in the ZFC phase diagram bends significantly towards the low-PT side in the FC state. These results demonstrate that both the phase stability and the nature of the MPB in PZN-PT within the near-surface regions are fragile in the presence of electric fields.
Crystal structure characteristics, dielectric loss, and vibrational spectra of Zn-rich non-stoichiometric Ba[(Zn1/3Nb2/3)1-x Zn x ]O3 ceramics

NASA Astrophysics Data System (ADS)

Li, Jianzhu; Xing, Chao; Qiao, Hengyang; Chen, Huiling; Yang, Jun; Dong, Helei; Shi, Feng

2017-07-01

Zn-Rich non-stoichiometric Ba(Zn1/3Nb2/3)1-x Zn x O3 (BZNZ) (x = 0.01, 0.02, 0.03, 0.04) ceramics were prepared by the solid-state reaction method at 1500 °C for 2 h. The crystal structures and morphologies were analyzed by x-ray diffraction (XRD) and scanning electron microscopy. The vibration modes were obtained by Raman scattering spectroscopy and Fourier transform far-infrared (FTIR) reflectance spectroscopy. Rietveld refinement was performed for the XRD data. The relationship between crystal structures, dielectric properties, and phonon modes was analyzed in detail. XRD results show that the main phase is Ba(Zn1/3Nb2/3)O3. The Raman results displayed that the ordering structure of BZNZ transformed from 1:2 to 1:1 when x changed from 0.02 to 0.04, and the dielectric losses have a positive correlation with the full width at half maximum values of the A 1g(O) and E g(O) modes. The FTIR spectra were analyzed by the Kramers-Krönig method to obtain the real parts (ɛ‧) and the imaginary parts (ɛ″) of the dielectric constant. When x = 0.02, the sample possesses uniform grains with clear boundaries and the lowest dielectric loss value (tanδ = 5.5 × 10‒4) due to the largest packing fraction.
Development of BaO-ZnO-B2O3 glasses as a radiation shielding material

NASA Astrophysics Data System (ADS)

Chanthima, N.; Kaewkhao, J.; Limkitjaroenporn, P.; Tuscharoen, S.; Kothan, S.; Tungjai, M.; Kaewjaeng, S.; Sarachai, S.; Limsuwan, P.

2017-08-01

The effects of the BaO on the optical, physical and radiation shielding properties of the xBaO: 20ZnO: (80-x)B2O3, where x=5, 10, 15, 20 and 25 mol%, were investigated. The glasses were developed by the conventional melt-quenching technique at 1400 °C with high purity chemicals of H3BO3, ZnO, and BaSO4. The optical transparency of the glasses indicated that the glasses samples were high, as observed by visual inspections. The mass attenuation coefficients (μm), the effective atomic numbers (Zeff), and the effective electron densities (Ne) were increased with the increase of BaO concentrations, and the decrease of gamma-ray energy. The developed glass samples were investigated and compared with the shielding concretes and glasses in terms of half value layer (HVL). The overall results demonstrated that the developed glasses had good shielding properties, and highly practical potentials in the environmental friendly radiation shielding materials without an additional of Pb.
Detectors for the Atacama B-mode Search experiment

NASA Astrophysics Data System (ADS)

Appel, John William

Inflation is the leading theory for explaining the initial conditions that brought about our homogeneous and isotropic Universe. It predicts the presence of gravitational waves in the early Universe, which implant a characteristic B-mode polarization pattern on the Cosmic Microwave Background (CMB). The Atacama B-mode Search (ABS) experiment is a polarimeter observing from Cerro Toco (located in the Atacama desert of Chile at an altitude of 5190 m), searching for the yet undetected B-mode signal. ABS carries 480 superconducting Transition Edge Sensor (TES) Bolometers that couple 150 GHz radiation via planar Ortho-Mode Transducers (OMTs) mounted at the output of corrugated feedhorns. The feedhorn beam is projected onto the sky through crossed Dragonian reflectors, a set of reflective and absorptive filters, and a rotating Half Wave Plate (HWP) that modulates any polarized sky signal at 10.2 Hz. The bolometers are cooled to 300 mK by a He3-He4 adsorption fridge system backed by pulse tubes. The reflectors are located within the 4 K cavity of the cryostat, while the HWP is mounted on frictionless air bearings above the cryostat window. This thesis discusses the development and construction of the ABS detector focal plane, and presents results of its performance in the field through August 2012. The ABS detector array sensitivity of 31 μKs 1/2, together with the experiment's unique set of systematic controls, and expected multi-year integration time, could detect a B-mode signal with tensor to scalar ratio r ˜ 0.1.
Searching for primordial magnetic fields with CMB B-modes

NASA Astrophysics Data System (ADS)

Pogosian, Levon; Zucca, Alex

2018-06-01

Was the primordial universe magnetized? The answer to this question would help explain the origin of micro-Gauss strength magnetic fields observed in galaxies. It is also of fundamental importance in developing a complete theory of the early universe. While there can be other signatures of cosmological magnetic fields, a signature in the cosmic microwave background (CMB) would prove their primordial origin. The B-mode polarization of CMB is particularly promising in this regard because there are relatively few other sources of B-modes, and because the vortical modes sourced by the primordial magnetic field (PMF) survive diffusion damping up to a small fraction of the Silk length. At present, the Planck temperature and polarization spectra combined with the B-mode spectrum measured by the South Pole Telescope (SPT) constrain the PMF strength to be no more than ∼1 nano-Gauss (nG). Because of the quartic scaling of the CMB anisotropy spectra with the PMF strength, this bound will not change by much even with the significantly better measurements of the B-mode spectrum by the Stage III and Stage IV CMB experiments. On the other hand, tightening the bound well below the 1 nG threshold would rule out the purely primordial origin (requiring no dynamo action) of galactic fields. Considering Faraday rotation, which converts some of the E-modes into B-modes and scales linearly with the field strength, will help to achieve this goal. As we demonstrate, the upcoming experiments, such as SPT-3G and the Simons Observatory, will be sensitive to fields of ∼0.5 nG strength thanks to the mode-coupling signature induced by Faraday rotation. A future Stage IV ground based experiment or a space probe will be capable of probing fields below 0.1 nG, and would detect a scale-invariant PMF of 0.2 nG strength without de-lensing or subtracting the galactic rotation measure.
Oxygen vacancy induced structural evolution of SrFeO3 -x epitaxial thin film from brownmillerite to perovskite

NASA Astrophysics Data System (ADS)

Roh, Seulki; Lee, Seokbae; Lee, Myounghoon; Seo, Yu-Seong; Khare, Amit; Yoo, Taesup; Woo, Sungmin; Choi, Woo Seok; Hwang, Jungseek; Glamazda, A.; Choi, K.-Y.

2018-02-01

We investigated SrFeO3 -x thin films on a SrTiO3 (001) substrate prepared via pulsed laser epitaxy using an optical spectroscopy technique. The oxygen vacancy level (x ) was controlled by post-annealing processes at different oxygen partial pressures. We achieved a brownmillerite (BM) structure at x =0.5 and observed the evolution of the crystal structure from BM into perovskite (PV) as the oxygen concentration increased. We observed the evolution of infrared-active phonons with respect to the oxygen concentration, which was closely related to the structural evolution observed via x-ray diffraction. We identified the phonons using the shell-model calculation. Furthermore, we studied temperature-dependent behaviors of the phonon modes of three representative samples: PV and two BMs (BMoop and BMip) with different orientations of the oxygen vacancy channel. In the BMoop sample, we observed a phonon mode, which exhibited an unusual redshift with decreasing temperature; this behavior may have been due to the apical oxygen instability in the FeO6 octahedron. Our results provide important information regarding the ionic conduction mechanism in SrFeO3 -x material systems.
Harmonic mode-locking using the double interval technique in quantum dot lasers.

PubMed

Li, Yan; Chiragh, Furqan L; Xin, Yong-Chun; Lin, Chang-Yi; Kim, Junghoon; Christodoulou, Christos G; Lester, Luke F

2010-07-05

Passive harmonic mode-locking in a quantum dot laser is realized using the double interval technique, which uses two separate absorbers to stimulate a specific higher-order repetition rate compared to the fundamental. Operating alone these absorbers would otherwise reinforce lower harmonic frequencies, but by operating together they produce the harmonic corresponding to their least common multiple. Mode-locking at a nominal 60 GHz repetition rate, which is the 10(th) harmonic of the fundamental frequency of the device, is achieved unambiguously despite the constraint of a uniformly-segmented, multi-section device layout. The diversity of repetition rates available with this method is also discussed.
O2(b1Σg+, v = 0, 1) Relative Yield in O(1D) + O2 Energy Transfer

NASA Astrophysics Data System (ADS)

Kostko, O.; Raj, S.; Campbell, K. M.; Pejakovic, D. A.; Slanger, T. G.; Kalogerakis, K. S.

2012-04-01

Energy transfer from excited O(1D) atoms to ground-state O2(X3Σg-) leads to production of O2 in the first two vibrational levels of the O2(b1Σg+) state: O(1D) + O2 → O(3P ) + O2(b1Σg+, v = 0, 1). Subsequent radiative decay of O2(b1Σg+, v = 0, 1) to the ground state results in the Atmospheric Band emission, a prominent feature of the terrestrial airglow. The relative yield for production of O2(b1Σg+, v = 0, 1) in the above process, k1/k0, is an important parameter in modeling of the observed O2 Atmospheric Band emission intensities. In the laboratory experiments, the output of a pulsed fluorine laser at 157 nm is used to photodissociate molecular oxygen in an O2/N2 mixture flowing through a heated gas cell. Photodissociation of O2 produces a ground-state O(3P ) atom and an excited O(1D) atom. O(1D) rapidly transfers energy to the remaining O2 to produce O2(b1Σg+, v = 0, 1). The populations of O2(b1Σg+, v = 0, 1) are monitored by observing emissions in the O2(b-X) 0-0 and 1-0 bands at 762 and 688 nm, respectively. The value of k1/k0 is extracted from the time-dependent O2(b1Σg+, v = 0, 1) fluorescence signals using computer simulations. We find that production of v = 1 is substantially larger than that of v = 0. We will present measurements on k1/k0 and its temperature dependence, and discuss the significance of these and other relevant laboratory measurements on the interpretation of the O2 Atmospheric Band emission. This work was supported by the US National Science Foundation (NSF) Aeronomy Program under grant AGS-0937317. The fluorine laser was purchased under grant ATM-0216583 from the NSF Major Research Instrumentation Program. The participation of Sumana Raj and Kendrick M. Campbell was supported by a Research Experiences for Undergraduates (REU) site, co-funded by the Division of Physics of the NSF and the Department of Defense in partnership with the NSF REU program (PHY-1002892).
Reply to Comment on Axial oxygen-centered lattice instabilities in YBa[sub 2]Cu[sub 3]O[sub 7]: An application of the analysis of extended x-ray-absorption fine structure in anharmonic systems' ''

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mustre de Leon, J.; Batistic, I.; Bishop, A.R.

1993-05-01

We assert that the one-site Cu(1)-O(4) model, suggested in the Comment by Thomsen and Cardona [Phys. Rev. B 47, 12 320 (1993)] is inconsistent with polarized x-ray-absorption fine-structure and diffraction results. We also show that the two-site Cu(1)-O(4) distribution is not inconsistent with optical measurements, although a rigid double-well modeling of this distribution is [Phys. Rev. Lett. 68, 3236 (1992)].
Structural, magnetic and transport properties of Pb{sub 2}Cr{sub 1+x}Mo{sub 1−x}O{sub 6} (−1≤x≤1/3)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, H.F.; School of Mathematics and Physics, University of Science and Technology, Beijing 100083; Cao, L.P.

Pb{sub 2}Cr{sub 1+x}Mo{sub 1-x}O{sub 6} (−1≤x≤1/3) samples were synthesized via a high pressure and high temperature route. X-ray diffraction results suggest the samples crystallize in a disordered double perovskite structure (Pm-3m). X-ray photoemission spectroscopy results confirm the presence of Mo{sup 4+} for x=−1 and Mo{sup 6+} for x=1/3. The measured magnetic and electrical properties exhibit systematic change with increasing x. - Highlights: • A series of Pb{sub 2}Cr{sub 1+x}Mo{sub 1−x}O{sub 6} samples were synthesized under high pressure. • Magnetic and electrical properties of the series samples were investigated. • Valence states of Cr and Mo were determined through the analysesmore » of XRD and XPS results. • Ground state of PbMoO{sub 3} were determined through the transport study and first-principles calculations.« less
Mutual conversion between B-mode image and acoustic impedance image

NASA Astrophysics Data System (ADS)

Chean, Tan Wei; Hozumi, Naohiro; Yoshida, Sachiko; Kobayashi, Kazuto; Ogura, Yuki

2017-07-01

To study the acoustic properties of a B-mode image, two ways of analysis methods were proposed in this report. The first method is the conversion of an acoustic impedance image into a B-mode image (Z to B). The time domain reflectometry theory and transmission line model were used as reference in the calculation. The second method is the direct a conversion of B-mode image into an acoustic impedance image (B to Z). The theoretical background of the second method is similar to that of the first method; however, the calculation is in the opposite direction. Significant scatter, refraction, and attenuation were assumed not to take place during the propagation of an ultrasonic wave. Hence, they were ignored in both calculations. In this study, rat cerebellar tissue and human cheek skin were used to determine the feasibility of the first and second methods respectively. Some good results are obtained and hence both methods showed their possible applications in the study of acoustic properties of B-mode images.
Enhanced performance of inverted organic photovoltaic cells using CNTs-TiO(X) nanocomposites as electron injection layer.

PubMed

Zhang, Hong; Xu, Meifeng; Cui, Rongli; Guo, Xihong; Yang, Shangyuan; Liao, Liangsheng; Jia, Quanjie; Chen, Yu; Dong, Jinquan; Sun, Baoyun

2013-09-06

In this study, we fabricated inverted organic photovoltaic cells with the structure ITO/carbon nanotubes (CNTs)-TiO(X)/P3HT:PCBM/MoO₃/Al by spin casting CNTs-TiO(X) nanocomposite (CNTs-TiO(X)) as the electron injection layer onto ITO/glass substrates. The power conversion efficiency (PCE) of the 0.1 wt% single-walled nanotubes (SWNTs)-TiO(X) nanocomposite device was almost doubled compared with the TiO(X) device, but with increasing concentration of the incorporated SWNTs in the TiO(X) film, the performance of the devices appeared to decrease rapidly. Devices with multi-walled NTs in the TiO(X) film have a similar trend. This phenomenon mainly depends on the inherent physical and chemical characteristics of CNTs such as their high surface area, their electron-accepting properties and their excellent carrier mobility. However, with increasing concentration of CNTs, CNTs-TiO(X) current leakage pathways emerged and also a recombination of charges at the interfaces. In addition, there was a significant discovery. The incorporated CNTs were highly conducive to enhancing the degree of crystallinity and the ordered arrangement of the P3HT in the active layers, due to the intermolecular π-π stacking interactions between CNTs and P3HT.
La{sup 3+} doping of the Sr{sub 2}CoWO{sub 6} double perovskite: A structural and magnetic study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lopez, C.A.; Viola, M.C.; Pedregosa, J.C.

2008-11-15

La-doped Sr{sub 2}CoWO{sub 6} double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, {lambda}=1.594 A). At room temperature, the replacement of Sr{sup 2+} by La{sup 3+} induces a change of the tetragonal structure, space group I4/m of the undoped Sr{sub 2}CoWO{sub 6} into the distorted monoclinic crystal structure, space group P2{sub 1}/n, Z=2. The structure of La-doped phases contains alternating CoO{sub 6} and (Co/W)O{sub 6} octahedra,more » almost fully ordered. On the other hand, the replacement of Sr{sup 2+} by La{sup 3+} induces a partial replacement of W{sup 6+} by Co{sup 2+} into the B sites, i.e. Sr{sub 2-x}La{sub x}CoW{sub 1-y}Co{sub y}O{sub 6} (y=x/4) with segregation of SrWO{sub 4}. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below T{sub N}=24 K independently of the La-substitution. - Graphical abstract: La-doped Sr{sub 2}CoWO{sub 6} double perovskites have been prepared in polycrystalline form by solid-state reaction. The general formula of these compounds is Sr{sub 2-x}La{sub x}CoW{sub 1-y}Co{sub y}O{sub 6} (y=x/4). XRPD, NPD and magnetic susceptibility studies were performed. The structure of monoclinic La-doped phases contains alternating CoO{sub 6} and (Co/W)O{sub 6} octahedra, almost fully ordered. NPD and magnetic measurements indicate an antiferromagnetic ordering at low temperature.« less
The crystal structure of galgenbergite-(Ce), CaCe2(CO3)4•H2O

NASA Astrophysics Data System (ADS)

Walter, Franz; Bojar, Hans-Peter; Hollerer, Christine E.; Mereiter, Kurt

2013-04-01

Galgenbergite-(Ce) from the type locality, the railroad tunnel Galgenberg between Leoben and St. Michael, Styria, Austria, was investigated. There it occurs in small fissures of an albite-chlorite schist as very thin tabular crystals building rosette-shaped aggregates associated with siderite, ancylite-(Ce), pyrite and calcite. Electron microprobe analyses gave CaO 9.49, Ce2O3 28.95, La2O3 11.70, Nd2O3 11.86, Pr2O3 3.48, CO2 30.00, H2O 3.07, total 98.55 wt.%. CO2 and H2O calculated by stoichiometry. The empirical formula (based on Ca + REE ∑3.0) is C{{a}_{1.00 }}{{( {C{{e}_{1.04 }}L{{a}_{0.42 }}N{{d}_{0.42 }}P{{r}_{0.12 }}} )}_{2.00 }}{{( {C{{O}_3}} )}_4}\\cdot {{H}_2}O , and the simplified formula is CaC{{e}_2}{{( {C{{O}_3}} )}_4}\\cdot {{H}_2}O . According to X-ray single crystal diffraction galgenbergite-(Ce) is triclinic, space group Poverline{1},a=6.3916(5) , b = 6.4005(4), c = 12.3898(9) Å, α = 100.884(4), β = 96.525(4), γ = 100.492(4)°, V = 483.64(6) Å3, Z = 2. The eight strongest lines in the powder X-ray diffraction pattern are [ d calc in Å/( I)/ hkl]: 5.052/(100)/011; 3.011/(70)/0-22; 3.006/(66)/004; 5.899/(59)/-101; 3.900/(51)/1-12; 3.125/(46)/-201; 2.526/(42)/022; 4.694/(38)/-102. The infrared absorption spectrum reveals H2O (OH-stretching mode at 3,489 cm-1, HOH bending mode at 1,607 cm-1) and indicates the presence of distinctly non-equivalent CO3-groups by double and quadruple peaks of their ν1, ν2, ν3 and ν4 modes. The crystal structure of galgenbergite-(Ce) was refined with X-ray single crystal data to R1 = 0.019 for 2,448 unique reflections ( I > 2 σ( I)) and 193 parameters. The three cation sites of the structure Ca(1), Ce(2) and Ce(3) have a modest mixed site occupation by Ca and small amount of REE (Ce, La, Pr, Nd) and vice versa. The structure is based on double layers parallel to (001), which are composed of Ca(1)Ce(2)(CO3)2 single layers with an ordered chessboard like arrangement of Ca and Ce, and with a roof tile
Evolution of Fermi Surface Properties in CexLa1-xB6 and PrxLa1-xB6

NASA Astrophysics Data System (ADS)

Endo, Motoki; Nakamura, Shintaro; Isshiki, Toshiyuki; Kimura, Noriaki; Nojima, Tsutomu; Aoki, Haruyoshi; Harima, Hisatomo; Kunii, Satoru

2006-11-01

We report the de Haas-van Alphen (dHvA) effect measurements of the Fermi surface properties in LaB6, CexLa1-xB6 (x = 0.1, 0.25, 0.5, 0.75, 1.0) and PrxLa1-xB6 (x = 0.25, 0.5, 0.75, 1.0) with particular attention to the spin dependence of the Fermi surface properties. The Fermi surface shape and dimension of CexLa1-xB6 change considerably with Ce concentration, while those of PrxLa1-xB6 change very slightly up to x = 0.75, and in PrB6 the Fermi surface splits into the up and down spin Fermi surfaces. The effective mass of CexLa1-xB6 increases considerably with Ce concentration and is nearly proportional to the number of Ce ions, whereas that of PrxLa1-xB6 increases slightly with Pr concentration. In CexLa1-xB6 the effective mass depends very strongly on field and increases divergently with decreasing field, while that of PrxLa1-xB6 increases slightly with decreasing field. The contribution to the dHvA signal from the conduction electrons of one spin direction diminishes with Ce concentration and appears to disappear somewhere around x = 0.25--0.5. A weak spin dependence is also found in PrxLa1-xB6. The behaviors of CexLa1-xB6 and PrxLa1-xB6 are compared to discuss the origin of the spin dependence of the Fermi surface properties.
Pixelated transmission-mode diamond X-ray detector

PubMed Central

Zhou, Tianyi; Ding, Wenxiang; Gaowei, Mengjia; De Geronimo, Gianluigi; Bohon, Jen; Smedley, John; Muller, Erik

2015-01-01

Fabrication and testing of a prototype transmission-mode pixelated diamond X-ray detector (pitch size 60–100 µm), designed to simultaneously measure the flux, position and morphology of an X-ray beam in real time, are described. The pixel density is achieved by lithographically patterning vertical stripes on the front and horizontal stripes on the back of an electronic-grade chemical vapor deposition single-crystal diamond. The bias is rotated through the back horizontal stripes and the current is read out on the front vertical stripes at a rate of ∼1 kHz, which leads to an image sampling rate of ∼30 Hz. This novel signal readout scheme was tested at beamline X28C at the National Synchrotron Light Source (white beam, 5–15 keV) and at beamline G3 at the Cornell High Energy Synchrotron Source (monochromatic beam, 11.3 keV) with incident beam flux ranges from 1.8 × 10−2 to 90 W mm−2. Test results show that the novel detector provides precise beam position (positional noise within 1%) and morphology information (error within 2%), with an additional software-controlled single channel mode providing accurate flux measurement (fluctuation within 1%). PMID:26524304
Interplay of 3 d - and 5 d -sublattice magnetism in the double perovskite substitution series La2Zn1 -xCoxIrO6

NASA Astrophysics Data System (ADS)

Vogl, M.; Corredor, L. T.; Dey, T.; Morrow, R.; Scaravaggi, F.; Wolter, A. U. B.; Aswartham, S.; Wurmehl, S.; Büchner, B.

2018-01-01

We report on the interplay of 3 d - and 5 d -sublattice magnetism in polycrystalline samples of the double perovskite substitution series La2Zn1 -xCoxIrO6 . Powder x-ray diffraction reveals no major structural changes within the series. In magnetization measurements, a gradual shift of the transition temperature from TN ≈91 K for the Co parent compound to TN ≈8.7 K for the Zn parent compound is observed. The data on the Zn-rich members of the substitution series indicate that this is accompanied by changing roles of the 3 d sublattice of Co2 + and the strongly spin-orbit coupled 5 d -sublattice of Ir4 + with its jeff=1 /2 ground state, as a function of the Co/Zn ratio. Temperature-dependent specific-heat studies revealed a reduced magnetic entropy, pointing towards a large spin-orbit coupling and orbital contribution in the system.

Evolution of the magnetic and structural properties of Fe 1 - x Co x V 2 O 4

DOE PAGES

Sinclair, R.; Ma, Jie; Cao, H. B.; ...

2015-10-12

The magnetic and structural properties of single-crystal Fe 1-xCo xV 2O 4 samples have been investigated by performing specific heat, susceptibility, neutron diffraction, and x-ray diffraction measurements. As the orbital-active Fe 2+ ions with larger ionic size are gradually substituted by the orbital-inactive Co 2+ ions with smaller ionic size, the system approaches the itinerant electron limit with decreasing V-V distance. Then, various factors such as the Jahn-Teller distortion and the spin-orbital coupling of the Fe 2+ ions on the A sites and the orbital ordering and electronic itinerancy of the V 3+ ions on the B sites compete withmore » each other to produce a complex magnetic and structural phase diagram. Finally, this phase diagram is compared to those of Fe 1-xMn xV 2O 4 and Mn 1-xCo xV 2O 4 to emphasize several distinct features.« less
A 9.61-W, b-cut Tm,Ho:YAP laser in Q-switched mode operation

NASA Astrophysics Data System (ADS)

Li, Guoxing; Yang, Xining; Zhang, Ziqiu; Zhang, Hongda; Zhang, Liang

2018-02-01

A high energy of b-cut Tm, Ho:YAlO3 laser is reported in the paper. The laser operated in acousto-optical Qswitched mode at 2.12 μm. The output average power of 9.61 W was achieved at the pulse repetition frequency of 10 kHz ,and the power of 11.6 W was acquired in continuous wave mode. Moreover, the energy per pulse of 0.961 mJ in 64.4 ns was acquired at 10 kHz with a 14.92-kW peak power.
Structural, thermal, optical and dielectric studies of Dy3+: B2O3-ZnO-PbO-Na2O-CaO glasses for white LEDs application

NASA Astrophysics Data System (ADS)

Mohammed, Al-B. F. A.; Lakshminarayana, G.; Baki, S. O.; Halimah, M. K.; Kityk, I. V.; Mahdi, M. A.

2017-11-01

Dy3+-doped borate glasses with nominal composition (60-x) B2O3-10 ZnO-10 PbO-10 Na2O-10 CaO-(x) Dy2O3 (x = 0, 0.1, 0.2, 0.5, 0.75, 1.0, 1.5 and 2.0 mol%) were prepared by the melt quenching technique. The XRD and SEM confirm the amorphous nature of the glasses and through EDAX, all the related elements were found in the synthesized glasses. The vibrations of metal cations such as Pb2+ and Zn2+, B-O-B bond bending vibrations from pentaborate groups, bending vibrations of BO3 triangles, and stretching vibrations of tetrahedral BO4- units etc. are identified from the respective FTIR and Raman spectra including the non-hygroscopic nature of the synthesized glasses. The TGA and DSC measurements were performed to study thermal properties, where ΔT >100 °C (ΔT = Tx - Tg) for all the glasses. Among all the Dy3+-doped glasses, the 0.75 mol% Dy3+-doped glass shows the highest PL intensity with four emissions, where the two transitions corresponding to 4F9/2 → 6H15/2 (blue) and 4F9/2 → 6H13/2 (yellow) are observed more intense than the others. The CIE chromaticity (x,y) coordinates for BZPNCDy 0.1 mol% glass are (0.398, 0.430), close to the white light region in the CIE 1931 chromaticity diagram. The dielectric properties of the 0.75 mol% Dy3+-doped glass such as dielectric constant, dielectric loss and AC conductivity were studied in the various frequencies and temperature.
Degradation of azo dye active brilliant red X-3B by composite ferrate solution.

PubMed

Xu, G R; Zhang, Y P; Li, G B

2009-01-30

Composite ferrate(VI) solution (CFS) with improved stability was successfully prepared in this study. The stability of Fe(VI) increased from hours for potassium ferrate at pH 9-10 to 16d for 1 mmol L(-1) Fe(VI) in CFS at 25 degrees C, decomposing 24%. The Fe(VI) was more stable at low concentration (1 mmol L(-1)) than that at high concentration (10 mmol L(-1)). The degradation of the azo dye reactive brilliant red X-3B (X-3B) by CFS was investigated. The results showed that pH, initial dye concentration and CFS dosage affected the degradation efficiency. For 0.08 mmol L(-1) X-3B simulate wastewater, the optimal pH and CFS dosage were 8.4 and 25 mg L(-1) (as K(2)FeO(4)), and about 99% X-3B was decolorized after 20 min under this conditions. The color decay was considerably faster than the decrease in COD and TOC, which was attributed to the ease of chromophore destruction. Compared with the decolorization, the removal percentage of COD and TOC were 42% and 9% after 60 min, respectively. The Fe(VI) and ClO(-) were contained in CFS, which have synergetic effect for the degradation of X-3B. Additionally, phthalic acid and muconic acid were identified as intermediates by GC/MS, which was in accordance with the lowered pH with the reaction time. The complete mineralization of X-3B cannot be achieved under the oxidation by CFS. And a tentative pathway for the oxidative degradation of X-3B was postulated.
Production and characterization of femtosecond laser-written double line waveguides in heavy metal oxide glasses

NASA Astrophysics Data System (ADS)

da Silva, Diego Silvério; Wetter, Niklaus Ursus; de Rossi, Wagner; Kassab, Luciana Reyes Pires; Samad, Ricardo Elgul

2018-01-01

We report the fabrication and characterization of double line waveguides directly written in tellurite and germanate glasses using a femtosecond laser delivering 30 μJ, 80 fs pulses at 4 kHz repetition rate. The double line waveguides produced presented internal losses inferior to 2.0 dB/cm. The output mode profile and the M2 measurements indicate multimodal guiding behavior. A better beam quality for the GeO2 - PbO waveguide was observed when compared with TeO2 - ZnO glass. Raman spectroscopy of the waveguides showed structural modification of the glassy network and indicates that a negative refractive index modification occurs at the focus of the laser beam, therefore allowing for light guiding in between two closely spaced laser written lines. The refractive index change at 632 nm is around 10-4, and the structural changes in the laser focal region of the writing, evaluated by Raman spectroscopy, corroborated our findings that these materials are potential candidates for optical waveguides and passive components. To the best of our knowledge, the two double line configuration demonstrated in the present work was not reported before for germanate or tellurite glasses.
Fe{sub 2}O{sub 3}-Bi{sub 2}O{sub 3}-B{sub 2}O{sub 3} glasses as lithium-free nonsilicate pH responsive glasses – Compatibility between pH responsivity and hydrophobicity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hashimoto, Tadanori, E-mail: hasimoto@chem.mie-u.ac.jp; Hamajima, Mitsuaki; Ohta, Honami

Highlights: • Fe{sub 2}O{sub 3}-rich FeBiB glasses show high pH sensitivity and short pH response time. • Bi{sub 2}O{sub 3}-rich FeBiB glasses show relatively high contact angle for water. • FeBiB glasses are lithium-free nonsilicate pH responsive ones. • pH responsivity and hydrophobicity are obtained for optimum glass compositions. - Abstract: Lithium silicate-based glasses have widely been used as commercially available pH glass electrodes. It was revealed that Ti{sup 3+}-containing titanophosphate (TiO{sub 2}-P{sub 2}O{sub 5}, TP) glasses are pH responsive as lithium-free nonsilicate glasses for the first time. TP glasses with the compatibility between pH responsivity and self-cleaning property weremore » obtained by the sequential post-annealing (oxidation and reduction) of as-prepared glasses. Bi{sub 2}O{sub 3}-B{sub 2}O{sub 3} (BiB) glasses are relatively hydrophobic and are expected to show anti-fouling effect. They are unsuitable for pH responsive glasses, because they have high electrical resistivity. In the present study, xFe{sub 2}O{sub 3}·yBi{sub 2}O{sub 3}·(100 − x − y)B{sub 2}O{sub 3} glasses (xFeyBiB, x = 0–20 mol%, y = 20–80 mol%) glasses were selected as new pH responsive glasses with hydrophobicity, because Fe{sub 2}O{sub 3} is a representative component for causing hopping conduction to the glasses. BiB glass did not show pH responsivity, whereas xFeyBiB glasses showed good pH responsivity. xFeyBiB glasses are lithium-free nonsilicate pH responsive ones as well as TP glasses. The electrical resistivity and pH response time decreased with increasing Fe{sub 2}O{sub 3} content. The pH repeatability for standard solutions increased with increasing Bi{sub 2}O{sub 3} content. Silicate glass (20Fe70BiSi) showed better pH responsivity but lower contact angle than those of borate glass (20Fe70BiB). pH sensitivity increased in order of TP glasses (about 80%), xFeyBiB glasses (about 90%) and commercial pH responsive glass (about 100
Binding mode and thermodynamic studies on the interaction of the anticancer drug dacarbazine and dacarbazine-Cu(II) complex with single and double stranded DNA.

PubMed

Temerk, Yassien; Ibrahim, Hossieny

2014-07-01

The binding mode and thermodynamic characteristics of the anticancer drug dacarbazine (Dac) with double and single stranded DNA were investigated in the absence and presence of Cu(II) using cyclic voltammetry, square wave voltammetry and fluorescence spectroscopy. The interaction of Dac and Dac-Cu(II) complex with dsDNA indicated their intercalation into the base stacking domain of dsDNA double helix and the strength of interaction is independent on the ionic strength. The interaction of Dac with dsDNA in the presence of Cu(II) leads to a much stronger intercalation. The interaction mode of Dac molecules with ssDNA is electrostatic attraction via negative phosphate on the exterior of the ssDNA with Dac. The binding constants, stoichiometric coefficients and thermodynamic parameters of Dac and Dac-Cu(II) complex with dsDNA and ssDNA were evaluated. Comparison of the mode interaction of Dac with dsDNA and ssDNA was discussed. The decrease of peak current of Dac was proportional to DNA concentration, which was applied for determination of dsDNA and ssDNA concentration. Copyright © 2014 Elsevier B.V. All rights reserved.
A microlens-array based pupil slicer and double scrambler for MAROON-X

NASA Astrophysics Data System (ADS)

Seifahrt, Andreas; Stürmer, Julian; Bean, Jacob L.

2016-07-01

We report on the design and construction of a microlens-array (MLA)-based pupil slicer and double scrambler for MAROON-X, a new fiber-fed, red-optical, high-precision radial-velocity spectrograph for one of the twin 6.5m Magellan Telescopes in Chile. We have constructed a 3X slicer based on a single cylindrical MLA and show that geometric efficiencies of >=85% can be achieved, limited by the fill factor and optical surface quality of the MLA. We present here the final design of the 3x pupil slicer and double scrambler for MAROON-X, based on a dual MLA design with (a)spherical lenslets. We also discuss the techniques used to create a pseudo-slit of rectangular core fibers with low FRD levels.
Double-shell Fe2O3 hollow box-like structure for enhanced photo-Fenton degradation of malachite green dye

NASA Astrophysics Data System (ADS)

Jiang, De Bin; Liu, Xiaoying; Xu, Xuan; Zhang, Yu Xin

2018-01-01

In this work we demonstrate the synthesis of novel Fe2O3 nanosheets with double-shell hollow morphology by replica molding from diatomite framework. The nanostructures of Fe2O3 nanosheets were examined by focused-ion-beam scanning electron microscopy (FIB/SEM), X-ray diffraction spectroscopy (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurements and Fourier transform infrared (FT-IR) spectroscopy. The results reveal that (1) Pure Fe2O3 nanosheets were successfully obtained; (2) The double-shell Fe2O3 hollow structure achieved via the NaOH etching silica method was observed; (3) Fe2O3 nanosheets possessed uniformly distributed porous nanosheets. Such structural features enlarged the specific surface area of Fe2O3 nanosheets and led to more catalytic active sites. In the heterogeneous photo-Fenton reaction, the double-shell Fe2O3 hollow morphology exhibited excellent catalytic capability for the degradation of malachite green (MG) at circumneutral pH condition. Under optimum condition, MG solution was almost completely decolorized in 60 min (99.9%). The Fe2O3 nanosheets also showed good stability and recyclability, demonstrating great potential as a promising photo-Fenton catalyst for the effective degradation of MG dye in wastewater.
Tunable double-clad ytterbium-doped fiber laser based on a double-pass Mach-Zehnder interferometer

NASA Astrophysics Data System (ADS)

Meng, Yichang; Zhang, Shumin; Wang, Xinzhan; Du, Juan; Li, Hongfei; Hao, Yanping; Li, Xingliang

2012-03-01

We have demonstrated an adjustable double-clad Yb 3+-doped fiber laser using a double-pass Mach-Zehnder interferometer. The laser is adjustable over a range of 40 nm from 1064 nm to 1104 nm. By adjusting the state of the polarization controller, which is placed in the double-pass Mach-Zehnder interferometer, we obtained central lasing wavelengths that can be accurately tuned with controllable spacing between different tunable wavelengths. The laser has a side mode suppression ratio of 42 dB, the 3 dB spectral width is less than 0.2 nm, and the slope efficiencies at 1068 nm, 1082 nm and 1098 nm are 23%, 32% and 26%, respectively. In addition, we have experimentally observed tunable multi-wavelengths lasing output.
Fabrication of multilayered Ge nanocrystals embedded in SiO xGeN y films

NASA Astrophysics Data System (ADS)

Gao, Fei; Green, Martin A.; Conibeer, Gavin; Cho, Eun-Chel; Huang, Yidan; Perez-Wurfl, Ivan; Flynn, Chris

2008-09-01

Multilayered Ge nanocrystals embedded in SiO xGeN y films have been fabricated on Si substrate by a (Ge + SiO 2)/SiO xGeN y superlattice approach, using a rf magnetron sputtering technique with a Ge + SiO 2 composite target and subsequent thermal annealing in N 2 ambient at 750 °C for 30 min. X-ray diffraction (XRD) measurement indicated the formation of Ge nanocrystals with an average size estimated to be 5.4 nm. Raman scattering spectra showed a peak of the Ge-Ge vibrational mode downward shifted to 299.4 cm -1, which was caused by quantum confinement of phonons in the Ge nanocrystals. Transmission electron microscopy (TEM) revealed that Ge nanocrystals were confined in (Ge + SiO 2) layers. This superlattice approach significantly improved both the size uniformity of Ge nanocrystals and their uniformity of spacing on the 'Z' growth direction.
Scale dependence of open c{\\bar{c}} and b{\\bar{b}} production in the low x region

NASA Astrophysics Data System (ADS)

Oliveira, E. G. de; Martin, A. D.; Ryskin, M. G.

2017-03-01

The `optimal' factorization scale μ _0 is calculated for open heavy quark production. We find that the optimal value is μ _F=μ _0˜eq 0.85√{p^2_T+m_Q^2} ; a choice which allows us to resum the double-logarithmic, (α _s ln μ ^2_F ln (1/x))^n corrections (enhanced at LHC energies by large values of ln (1/x)) and to move them into the incoming parton distributions, PDF(x,μ _0^2). Besides this result for the single inclusive cross section (corresponding to an observed heavy quark of transverse momentum p_T), we also determined the scale for processes where the acoplanarity can be measured; that is, events where the azimuthal angle between the quark and the antiquark may be determined experimentally. Moreover, we discuss the important role played by the 2→ 2 subprocesses, gg→ Q\\bar{Q} at NLO and higher orders. In summary, we achieve a better stability of the QCD calculations, so that the data on c{\\bar{c}} and b{\\bar{b}} production can be used to further constrain the gluons in the small x, relatively low scale, domain, where the uncertainties of the global analyses are large at present.
Does the Addition of M-Mode to B-Mode Ultrasound Increase the Accuracy of Identification of Lung Sliding in Traumatic Pneumothoraces?

PubMed

Avila, Jacob; Smith, Ben; Mead, Therese; Jurma, Duane; Dawson, Matthew; Mallin, Michael; Dugan, Adam

2018-04-24

It is unknown whether the addition of M-mode to B-mode ultrasound (US) has any effect on the overall accuracy of interpretation of lung sliding in the evaluation of a pneumothorax by emergency physicians. This study aimed to determine what effect, if any, this addition has on US interpretation by emergency physicians of varying training levels. One hundred forty emergency physicians were randomized via online software to receive a quiz with B-mode clips alone or B-mode with corresponding M-mode images and asked to identify the presence or absence of lung sliding. The sensitivity, specificity, and accuracy of the diagnosis of lung sliding with and without M-mode US were compared. Overall, the sensitivities, specificities, and accuracies of B-mode + M-mode US versus B-mode US alone were 93.1% and 93.2% (P = .8), 96.0% and 89.8% (P < .0001), and 91.5% and 94.5% (P = .0091), respectively. A subgroup analysis showed that in those providers with fewer than 250 total US scans done previously, M-mode US increased accuracy from 88.2% (95% confidence interval, 86.2%-90.2%) to 94.4% (92.8%-96.0%; P = .001) and increased the specificity from 87.0% (84.5%-89.5%) to 97.2% (95.4%-99.0%; P < .0001) compared with B-mode US alone. There was no statistically significant difference observed in the sensitivity, specificity, and accuracy of B-mode + M-mode US compared with B-mode US alone in those with more than 250 scans. The addition of M-mode images to B-mode clips aids in the accurate diagnosis of lung sliding by emergency physicians. The subgroup analysis showed that the benefit of M-mode US disappears after emergency physicians have performed more than 250 US examinations. © 2018 by the American Institute of Ultrasound in Medicine.
Fesbnd X (X = B, N) binary compounds: First-principles calculations of electronic structures, theoretic hardness and magnetic properties

NASA Astrophysics Data System (ADS)

Hui, Liangliang; Xie, Zhongjing; Li, Chunmei; Chen, Zhi-Qian

2018-04-01

The first-principles calculations are implemented to investigate the electronic structures, theoretic hardness and magnetic properties of iron borides and nitrides with four different crystal systems containing hexagonal (FeB2, ε-Fe3N), tetragonal (Fe2B, α″-Fe16N2), orthorhombic (α-FeB, θ-Fe3B, ζ-Fe2N), and cubic (zb-FeN, rs-FeN, γ‧-Fe4N, γ-Fe23B6) phase. The calculated lattice parameters using RPBE meet well with the experimental results. The cohesive energy and formation enthalpy values indicate the Fesbnd X (X = B, N) binary compounds are thermodynamically stable. Meanwhile, the h-FeB2 is most difficult phase for experimental synthesis among these interstitial compounds. Moreover, magnetic properties are discussed and show that the mean magnetic moments of o-Fe3B and c-Fe23B6 with the values of 2.227 μB and 2.256 μB per iron atom are approaching to that of pure iron (2.32 μB) while the c-Fe4N and t-Fe16N2 with the values of 2.51 and 2.48 μB are beyond that of pure α-Fe. The c-FeN phase shows nonmagnetic in zb-style while rs-type shows antiferromagnetic with a value of 2.52 μB. Furthermore, the average bonding length and Mulliken population combined with electronic structures are also analysed in this paper which provide that strong Fesbnd X and Xsbnd X covalent bonds are responsible for high hardness. Finally, the theoretic hardness of Xsbnd X, Fesbnd X and Fesbnd Fe bonds is predicted by semi empirical hardness theory.
Metal-insulator transition in Ba3Fe1 -xRu2 +xO9 : Interplay between site disorder, chemical percolation, and electronic structure

NASA Astrophysics Data System (ADS)

Middey, S.; Aich, Payel; Meneghini, C.; Mukherjee, K.; Sampathkumaran, E. V.; Siruguri, V.; Mahadevan, P.; Ray, Sugata

2016-11-01

Perovskites containing barium metal at the A site often take up unusual hexagonal structures having more than one type of possible sites for the B cation to occupy. This opens up various different B -B - or B -O-B -type connectivities and consequent physical properties which are naturally missing in cubic perovskites. BaRuO3 is one such system where doping of Ru (4 d4 ) by other transition metals (Mn +) creates similar conditions, giving rise to various M -Ru interactions. Interestingly, the 6 H hexagonal structure of doped barium ruthenate triple perovskite (Ba3M Ru2O9 ) seems to possess some internal checks because within the structure M ion always occupies the 2 a site and Ru goes to the 4 f site, allowing only M -O-Ru 180∘ and Ru-O-Ru 90∘ interactions to occur. The only exception is observed in the case of the Fe dopant, which allows us to study almost the full Ba3Fe1 -xRu2 +xO9 series of compounds with wide ranges of x because here Fe ions have the ability to freely go to the 4 f sites and Ru readily takes up the 2 a positions. Therefore, here one has the opportunity to probe the evolution of electronic and magnetic properties as a function of doping by going from BaRuO3 (paramagnetic metal) to BaFeO3 (ferromagnetic insulator). Our detailed experimental and theoretical results show that the series does exhibit a percolative metal-insulator transition with an accompanying but not coincidental magnetic transition as a function of x .
Enhancement of magnetic ordering temperature in iron substituted ytterbium manganate (YbMn{sub 1-x}Fe{sub x}O{sub 3})

DOE Office of Scientific and Technical Information (OSTI.GOV)

Samal, S.L.; Magdaleno, T.; Ramanujachary, K.V.

Oxides of the type YbMn{sub 1-x}Fe{sub x}O{sub 3}; x<=0.3 showing multiferroic behavior have been synthesized by the solid state route. These oxides crystallize in the hexagonal structure known for the parent YbMnO{sub 3} with the c/a ratio increasing with Fe substitution. The distortion of the MnO{sub 5} polyhedra (tbp) decreases and the Mn-O-Mn bonds in the a-b plane become shorter with Fe-substitution. Magnetic ordering is observed from the low temperature neutron diffraction study. The compounds were found to be antiferromagnetic and the ordering temperature T{sub N} increased from 82 K for pure YbMnO{sub 3} to 95 K for YbMn{sub 0.7}Fe{submore » 0.3}O{sub 3}. Variable temperature dielectric measurements (15-110 K) show an anomaly in the dielectric constant at temperatures close to the antiferromagnetic ordering temperature for all the compositions, showing a unique correlation between the magnetic and electric field. The increase in the ordering temperature in YbMn{sub 1-x}Fe{sub x}O{sub 3} is explained on the basis of increase in covalence of Mn/Fe-O-Mn/Fe bonds (shorter) with iron substitution. - Graphical abstract: Hexagonal manganites of the type YbMn{sub 1-x}Fe{sub x}O{sub 3}; x<=0.3 have been synthesized by the solid state route. The distortion of the MnO{sub 5} polyhedra (tbp) decreases and the Mn-O-Mn bonds in the a-b plane become shorter with Fe-substitution. The compounds were found to be antiferromagnetic and the ordering temperature T{sub N} increased from 82 K for pure YbMnO{sub 3} to 95 K for YbMn{sub 0.7}Fe{sub 0.3}O{sub 3}. The increase in the ordering temperature in YbMn{sub 1-x}Fe{sub x}O{sub 3} is explained on the basis of increase in covalence of Mn/Fe-O-Mn/Fe bonds with iron substitution. Low temperature dielectric measurements show a unique correlation between the magnetic and electric fields for all compositions.« less
Effect of heavy Ag doping on the physical properties of ZnO

NASA Astrophysics Data System (ADS)

Hou, Qingyu; Zhao, Chunwang; Jia, Xiaofang; Xu, Zhenchao

2018-04-01

The band structure, density of state and absorption spectrum of Zn1‑xAgxO (x = 0.02778, 0.04167) were calculated. Results indicated that a higher doping content of Ag led to a higher total energy, lower stability, higher formation energy, narrower bandgap, more significant red shift of the absorption spectrum, higher relative concentration of free hole, smaller hole effective mass, lower mobility and better conductivity. Furthermore, four types of model with the same doping content of double Ag-doped Zn1‑xAgxO (x = 0.125) but different manners of doping were established. Two types of models with different doping contents of double Ag-doped Zn1‑xAgxO (x = 0.0626, 0.0833) but the same manner of doping, were also established. Under the same doping content and different ordering occupations in Ag double doping, the doped system almost caused magnetic quenching upon the nearest neighbor -Ag-O-Ag- bonding at the direction partial to the a- or b-axis. Upon the next-nearest neighbor of -Ag-O-Zn-O-Ag- bonding at the direction partial to the c-axis, the total magnetic moment of the doped system increased, and the doped system reached a Curie temperature above the room-temperature. All these results indicated that the magnetic moments of Ag double-doped ZnO systems decreased with increased Ag doping content. Within the range of the mole number of the doping content of 0.02778-0.04167, a greater Ag doping content led to a narrower bandgap of the doped system and a more significant red shift in the absorption spectrum. The absorption spectrum of the doped ZnO system with interstitial Ag also shows a red shift.
Structural, magnetic and magnetoreactance studies in NiFe2-xRxO4 (x = 0, 0.05; R = Y, Yb and Lu)

NASA Astrophysics Data System (ADS)

Ugendar, Kodam; Chunchu, Venkatrao; Rani, G. Neeraja; Markaneyulu, G.

2018-04-01

Structural, magnetic and magnetoreactance (mr) properties of NiFe2-xRxO4 (x = 0, 0.05; R = Y, Yb and Lu) compounds were investigated and the results are discussed and presented in this paper. Rietveld refined X-ray diffraction (XRD) patterns and Raman spectroscopy revealed the cubic inverse spinel phase for all the compounds investigated. The former also identified small amounts of RFeO3 as the secondary phase. Lattice constant values were increased upon partial substitution of Fe3+ by R3+ (R = Y, Yb and Lu). Magnetization measurements revealed that the magnetic moment of R3+ (R = Y, Yb and Lu) substituted compounds decreased compared with NiFe2O4. mr was measured at 3 kHz and 3 MHz both longitudinal (LT) and transverse (TR) configuration. A maximum mr of 54 % was observed in Y3+ substituted NiFe2O4 in TR mode.
(O8 , O8 ) contribution to B ¯→Xsγ γ at O (αs)

NASA Astrophysics Data System (ADS)

Asatrian, H. M.; Greub, C.; Kokulu, A.

2016-01-01

In this analysis, we present the contribution associated with the chromomagnetic dipole operator O8 to the double differential decay width d Γ /(d s1d s2) for the inclusive process B ¯→Xsγ γ . The kinematical variables s1 and s2 are defined as si=(pb-qi)2/mb2, where pb, q1, q2 are the momenta of b quark and two photons. This contribution (taken at tree level) is of order αs, like the recently calculated QCD corrections to the contribution of the operator O7. In order to regulate possible collinear singularities of one of the photons with the strange quark, we introduce a nonzero mass ms for the strange quark. Our results are obtained for exact ms, which we interpret as a constituent mass being varied between 400 and 600 MeV. Numerically it turns out that the effect of the (O8 , O8 ) contribution to the branching ratio of B ¯→Xsγ γ does not exceed +0.1 % for any kinematically allowed value of our physical cutoff parameter c , confirming the expected suppression of this contribution relative to the QCD corrections to d Γ77/(d s1d s2).
Double-clad photonic crystal fiber coupler for compact nonlinear optical microscopy imaging.

PubMed

Fu, Ling; Gu, Min

2006-05-15

A 1 x 2 double-clad photonic crystal fiber coupler is fabricated by the fused tapered method, showing a low excess loss of 1.1 dB and a splitting ratio of 97/3 over the entire visible and near-infrared wavelength range. In addition to the property of splitting the laser power, the double-clad feature of the coupler facilitates the separation of a near-infrared single-mode beam from a visible multimode beam, which is ideal for nonlinear optical microscopy imaging. In conjunction with a gradient-index lens, this coupler is used to construct a miniaturized microscope based on two-photon fluorescence and second-harmonic generation. Three-dimensional nonlinear optical images demonstrate potential applications of the coupler to compact all-fiber and nonlinear optical microscopy and endoscopy.

Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO{sub 3})X (X=Cl, OH)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Bing-Ping, E-mail: ybp@fjirsm.ac.cn; Mao, Jiang-Gao

Systematic explorations of new compounds in the cadmium iodate system by hydrothermal reactions led to two layered iodates, namely, Cd(IO{sub 3})X (X=Cl, OH). Cd(IO{sub 3})Cl crystallizes in the orthorhombic space group Cmca (No. 64) whereas Cd(IO{sub 3})(OH) crystallizes in the orthorhombic space group Pnma (No. 62). Cd(IO{sub 3})Cl displays a unique double layered structure composed of {sup 1}{sub ∞}[Cd−O{sub 3}Cl]{sub n} chains. Cadmium octahedrons form a 1D chain along the a-axis through edge sharing, and such chains are further interconnected via IO{sub 3} groups to form a special double layer on (020) plane. Cd(IO{sub 3})(OH) also exhibits a layered structuremore » that is composed of cadmium cations, IO{sub 3} groups and hydroxyl ions. Within a layer, chains of CdO{sub 6} edge-shared octahedra are observed along the b-axis. And these chains are connected by IO{sub 3} groups into a layer parallel to the bc plane. Spectroscopic characterizations, elemental analysis, and thermogravimetric analysis for the reported two compounds are also presented. - Graphical abstract: Two new layered cadmium iodates Cd(IO{sub 3})X (X=Cl, OH) are reported. Cd(IO{sub 3})Cl features a unique double layered structure whereas Cd(IO{sub 3})(OH) displays an ordinary layered structure. - Highlights: • Two new layered cadmium iodates Cd(IO{sub 3})X (X=Cl, OH) are reported. • Cd(IO{sub 3})Cl features a unique double layered structure. • Cd(IO{sub 3})(OH) displays an ordinary layered structure. • The spectroscopic and thermal properties have been studied in detail.« less
Determination of O2(a1 delta g) and O2(b1 sigma+ g) yields in the reaction O + ClO --> Cl + O2: implications for photochemistry in the atmosphere of Venus

NASA Technical Reports Server (NTRS)

Leu, M. T.; Yung, Y. L.

1987-01-01

A discharge flow apparatus with chemiluminescence detector has been used to study the reaction O + ClO --> Cl + O2, where O2 = O2(a1 delta g) or O2(b1 sigma+ g). The measured quantum yields for producing O2(a1 delta g) and O2(b1 sigma+ g) in the above reaction are less than 2.5 x 10(-2) and equal to (4.4 +/- 1.1) x 10(-4), respectively. The observed O2(a1 delta g) airglow of Venus cannot be explained in the context of standard photochemistry using our experimental results and those reported in recent literature. The possibility of an alternative source of O atoms derived from SO2 photolysis in the mesosphere of Venus is suggested.
Vibrational spectra of Mg2KH(XO4)2·15H2O (X = P, As) containing dimer units [H(XO4)2

NASA Astrophysics Data System (ADS)

Stefov, V.; Koleva, V.; Najdoski, M.; Abdija, Z.; Cahil, A.; Šoptrajanov, B.

2017-08-01

Infrared and Raman spectra of Mg2KH(PO4)2·15H2O and Mg2KH(AsO4)2·15H2O and a series of their partially deuterated analogues were recorded and analyzed. Compounds of the type Mg2KH(XO4)2·15H2O (X = P, As) are little-known and a rare case of phosphate and arsenate salts containing dimer units [H(XO4)2] in the crystal structure. The analysis of their IR spectra (recorded at room and liquid nitrogen temperature) and Raman spectra showed that the spectral characteristics of the XO4 groups connected in a dimer through a proton are not consistent with the presence of X-O-H covalent linkage and C1 crystallographic symmetry of the XO4 groups. The observation of a singlet Raman band for the ν1(XO4) mode as well as the absence of substantial splitting of the ν3(XO4) modes and IR activation of the ν1(XO4) mode suggest that the dimer units [H(XO4)2] are most probably symmetric rather than non-symmetric ones. It was found that, in the vibrational spectra of Mg2KH(AsO4)2·15H2O, both ν1(AsО4) and ν3(AsО4) modes have practically the same wavenumber around 830 cm- 1. It was also established that the ν4(PО4) modes in the deuterated hydrogendiphosphate compound are strongly coupled, most probably with HDO and/or D2O librations. As a whole, the spectral picture of Mg2KH(XO4)2·15H2O (X = P, As) very much resembles that observed for the struvite type compounds with the formula KMgXO4·6H2O (X = P, As) which do not contain X-OH groups. This means that vibrations of the dimers [H(XO4)2] play a relatively small part in the general spectral appearance.
Interfacial RhO{sub x}/CeO{sub 2} sites as locations for low temperature N{sub 2}O dissociation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cunningham, J.; Hickey, J.N.; Soria, J.

Temperatures required for extensive N{sub 2}O dissociation to N{sub 2}, or to N{sub 2} plus O{sub 2}, over 0.5% RhO{sub x}/CeO{sub 2} materials, and over polycrystalline Rh{sub 2}O{sub 3} or CeO{sub 2}, are compared for preoxidised and for prereduced samples on the basis of conversions achieved in pulsed-reactant, continuous-flow and recirculatory microcatalytic reactors. Influences of sample prereduction or preoxidation upon those measurements and upon results from parallel ESR and FTIR studies of N{sub 2}O interactions with such materials are presented and compared. Over partially reduced 0.5% RhO{sub x}/CeO{sub 2} materials complete dissociation of N{sub 2}O pulses to N{sub 2} plusmore » O{sub 2} is obtained at temperatures 50-100{degrees} lower than those required for extensive dissociation over prereduced Rh{sub 2}O{sub 3}. Furthermore, N{sub 2} was the sole product from the latter. Higher ongoing N{sub 2}O conversions to N{sub 2} plus O{sub 2} at 623 K over 0.5% Rh/CeO{sub 2} in pulsed-reactant than in continuous-flow mode point to regeneration of active sites under helium flushing between pulses. The TPD profile for dioxygen release from Rhodia containing samples at temperatures 350-550 K is presented. ESR measurements reveal complementary effects of outgassings at temperatures, T{sub v}, {ge} 573 K upon the availability at RhO{sub x}/CeO{sub 2} surfaces of electron-excess sites reactive towards N{sub 2}O. Differences from observations over Rh{sub 2}O{sub 3} and CeO{sub 2} can be understood by attributing the low-temperature activity of RhO{sub x}/CeO{sub 2} to electron excess sites at microinterfaces between the dispersed Rhodia component and the Ceria support.« less
LiNixCo1-xO2 Cell Grown by Pulsed Laser Deposition

NASA Astrophysics Data System (ADS)

Rao, M. C.; Ravindranadh, K.; Begum, Sk. Muntaz; Nirmala, G.

2011-07-01

Thin films of LiNixCo1-xO2 were prepared by pulsed laser deposition technique. Two important deposition parameters such as substrate temperature and oxygen partial pressure during the thin film deposition were controlled. The electrochemical measurements were carried out on Li//LiNixCo1-xO2 cells with a lithium metal foil as anode and LiNixCo1-xO2 film as cathode of 1.5 cm2 active area using a Teflon home-made cell hardware. Electrochemical titration was made by charging and discharging the cells using the galvanostatic mode of a Mac-Pile single 608 electrochemical analyzer system in the potential range between 2.0 and 4.1 V. Specific capacity as high as 220 mC/cm2 μm was measured for the film grown at 700 °C.
Syntheses and crystal structures of two new hydrated borates, Zn{sub 8}[(BO{sub 3}){sub 3}O{sub 2}(OH){sub 3}] and Pb[B{sub 5}O{sub 8}(OH)].1.5H{sub 2}O

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen Xuean; Zhao Yinghua; Chang Xinan

Two new hydrated borates, Zn{sub 8}[(BO{sub 3}){sub 3}O{sub 2}(OH){sub 3}] and Pb[B{sub 5}O{sub 8}(OH)].1.5H{sub 2}O, have been prepared by hydrothermal reactions at 170 {sup o}C. Single-crystal X-ray structural analyses showed that Zn{sub 8}[(BO{sub 3}){sub 3}O{sub 2}(OH){sub 3}] crystallizes in a non-centrosymmetric space group R32 with a=8.006(2) A, c=17.751(2) A, Z=3 and Pb[B{sub 5}O{sub 8}(OH)].1.5H{sub 2}O in a triclinic space group P1-bar with a=6.656(2) A, b=6.714(2) A, c=10.701(2) A, {alpha}=99.07(2){sup o}, {beta}=93.67(2){sup o}, {gamma}=118.87(1){sup o}, Z=2. Zn{sub 8}[(BO{sub 3}){sub 3}O{sub 2}(OH){sub 3}] represents a new structure type in which Zn-centered tetrahedra are connected via common vertices leading to helical ribbons {submore » {infinity}} {sup 1}[Zn{sub 8}O{sub 15}(OH){sub 3}]{sup 17-} that pack side by side and are further condensed through sharing oxygen atoms to form a three-dimensional {sub {infinity}} {sup 3}[Zn{sub 8}O{sub 11}(OH){sub 3}]{sup 9-} framework. The boron atoms are incorporated into the channels in the framework to complete the final structure. Pb[B{sub 5}O{sub 8}(OH)].1.5H{sub 2}O is a layered compound containing double ring [B{sub 5}O{sub 8}(OH)]{sup 2-} building units that share exocyclic oxygen atoms to form a two-dimensional layer. Symmetry-center-related layers are stacked along the c-axis and held together by interlayer Pb{sup 2+} ions and water molecules via electrostatic and hydrogen bonding interactions. The IR spectra further confirmed the existence of both triangular BO{sub 3} and OH groups in Zn{sub 8}[(BO{sub 3}){sub 3}O{sub 2}(OH){sub 3}], and BO{sub 3}, BO{sub 4}, OH groups as well as guest water molecules in Pb[B{sub 5}O{sub 8}(OH)].1.5H{sub 2}O. -- Zn{sub 8}[(BO{sub 3}){sub 3}O{sub 2}(OH){sub 3}] represents a new structure type in which Zn-centered tetrahedra are connected via common vertices to form a three-dimensional framework. The boron atoms are incorporated into the channels in the framework to
Sr{sub 2}CaW{sub x}Mo{sub 1−x}O{sub 6}:Eu{sup 3+}, Li{sup +}: An emission tunable phosphor through site symmetry and excitation wavelength

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, Ning; Shen, Jun; Xiao, Tengjiao

2015-10-15

The emission of Eu{sup 3+} doped Sr{sub 2}CaW{sub x}Mo{sub 1−x}O{sub 6} phosphors could be tunable by the site symmetry of the activators and the excitation wavelengths. - Highlights: • The emission of Eu{sup 3+} depends on site symmetry and excitation wavelengths. • The color of the samples was tunable by structure and excitation wavelength. • The effect of W and Eu content on the properties of the samples was investigated. - Abstract: A series of Eu{sup 3+} substituted double-perovskite Sr{sub 2}CaW{sub x}Mo{sub 1−x}O{sub 6} phosphors were prepared by solid state reactions. The phase, photoluminescence and energy transfer of the phosphorsmore » were investigated by X-ray diffraction (XRD), photoluminescence (PL) and luminescence decay respectively. It is found that the emission of the Eu{sup 3+} substituted double perovskites depends on both the site symmetry of the activators and the excitation wavelengths. Based on the decay analysis of Sr{sub 2}CaW{sub x}Mo{sub 1−x}O{sub 6} matrix and Eu{sup 3+} doped samples, the energy transfer efficiencies between the host and activators Eu{sup 3+} were investigated. The results of the emission tunable phosphors indicate their potential applications in LEDs.« less
Topology-energy relationships and lowest energy configurations for pentagonal dodecahedral (H2O)20X clusters, X=empty, H2O, NH3, H3O+: The importance of O-topology

NASA Astrophysics Data System (ADS)

Anick, David J.

2010-04-01

For (H2O)20X water clusters consisting of X enclosed by the 512 dodecahedral cage, X=empty, H2O, NH3, and H3O+, databases are made consisting of 55-82 isomers optimized via B3LYP/6-311++G∗∗. Correlations are explored between ground state electronic energy (Ee) or electronic energy plus zero point energy (Ee+ZPE) and the clusters' topology, defined as the set of directed H-bonds. Linear regression is done to identify topological features that correlate with cluster energy. For each X, variables are found that account for 99% of the variance in Ee and predict it with a rms error under 0.2 kcal/mol. The method of analysis emphasizes the importance of an intermediate level of structure, the "O-topology," consisting of O-types and a list of O pairs that are bonded but omitting H-bond directions, as a device to organize the databases and reduce the number of structures one needs to consider. Relevant variables include three parameters, which count the number of H-bonds having particular donor and acceptor types; |M|2, where M is the cluster's vector dipole moment; and the projection of M onto the symmetry axis of X. Scatter diagrams for Ee or Ee+ZPE versus |M| show that clusters fall naturally into "families" defined by the values of certain discrete parameters, the "major parameters," for each X. Combining "family" analysis and O-topologies, a small group of clusters is identified for each X that are candidates to be the global minimum, and the minimum is determined. For X=H3O+, one cluster with central hydronium lies just 2.08 kcal/mol above the lowest isomer with surface hydronium. Implications of the methodology for dodecahedral (H2O)20(NH4+) and (H2O)20(NH4+)(OH-) are discussed, and new lower energy isomers are found. For MP2/TZVP, the lowest-energy (H2O)20(NH4+) isomer features a trifurcated H-bond. The results suggest a much more efficient and comprehensive way of seeking low-energy water cluster geometries that may have wide applicability.
Topology-energy relationships and lowest energy configurations for pentagonal dodecahedral (H2O)20X clusters, X = empty, H2O, NH3, H3O+: the importance of O-topology.

PubMed

Anick, David J

2010-04-28

For (H(2)O)(20)X water clusters consisting of X enclosed by the 5(12) dodecahedral cage, X = empty, H(2)O, NH(3), and H(3)O(+), databases are made consisting of 55-82 isomers optimized via B3LYP/6-311++G(**). Correlations are explored between ground state electronic energy (Ee) or electronic energy plus zero point energy (Ee+ZPE) and the clusters' topology, defined as the set of directed H-bonds. Linear regression is done to identify topological features that correlate with cluster energy. For each X, variables are found that account for 99% of the variance in Ee and predict it with a rms error under 0.2 kcal/mol. The method of analysis emphasizes the importance of an intermediate level of structure, the "O-topology," consisting of O-types and a list of O pairs that are bonded but omitting H-bond directions, as a device to organize the databases and reduce the number of structures one needs to consider. Relevant variables include three parameters, which count the number of H-bonds having particular donor and acceptor types; absolute value(M)(2), where M is the cluster's vector dipole moment; and the projection of M onto the symmetry axis of X. Scatter diagrams for Ee or Ee+ZPE versus absolute value(M) show that clusters fall naturally into "families" defined by the values of certain discrete parameters, the "major parameters," for each X. Combining "family" analysis and O-topologies, a small group of clusters is identified for each X that are candidates to be the global minimum, and the minimum is determined. For X = H(3)O(+), one cluster with central hydronium lies just 2.08 kcal/mol above the lowest isomer with surface hydronium. Implications of the methodology for dodecahedral (H(2)O)(20)(NH(4)(+)) and (H(2)O)(20)(NH(4)(+))(OH(-)) are discussed, and new lower energy isomers are found. For MP2/TZVP, the lowest-energy (H(2)O)(20)(NH(4)(+)) isomer features a trifurcated H-bond. The results suggest a much more efficient and comprehensive way of seeking low
Photocatalytic self-cleaning transparent 2Bi2O3-B2O3 glass ceramics

NASA Astrophysics Data System (ADS)

Sharma, Sumeet Kumar; Singh, V. P.; Chauhan, Vishal S.; Kushwaha, H. S.; Vaish, Rahul

2017-09-01

Photocatalytic response of as-quenched and heat-treated 2Bi2O3-B2O3 glasses was studied. X ray diffraction reveals that the controlled heat treatment of glasses at 380 °C for 1 h, 2 h, and 3 h shows the formation of Bi4B2O9 crystals embedded in 2Bi2O3-B2O3 the host glass matrix. Scanning electron microscopic images reveal the presence of nanocrystallization in as-quenched glass. Significant photocatalytic activities were observed in as-quenched transparent glass. Photocatalytic activities were studied using the degradation of Resazurin as well as pharmaceutical 17 β-Estradiol under UV irradiation. Measurement of contact angle shows enhanced hydrophilicity with the increase in crystallization of the samples. Further, for as quenched 2Bi2O3-B2O3 glass ceramic, under UV irradiation, the water contact angle decreased from 92.7° to 39.5° and the sample surface transformed from hydrophobic to hydrophilic. Effective photocatalytic performance along with photoinduced hydrophilicity promotes 2Bi2O3-B2O3 glass ceramics in self-cleaning applications.
Influences of Ru-doping on the magnetic properties of Ca0.85Pr0.15Mn1- x Ru x O3

NASA Astrophysics Data System (ADS)

Phan, T. L.; Zhang, Y. D.; Yu, S. C.; Thanh, P. Q.; Yen, P. D. H.

2012-11-01

CaMnO3 is an antiferromagnet, in which the super-exchange interaction taking place between Mn4+ ions plays an important role. The doping of a small amount of 15% Pr into the Ca site, Ca0.85Pr0.15MnO3, leads to the appearance of Mn3+ ions, and introduces the ferromagnetic (FM) double-exchange interaction between Mn3+ and Mn4+ ions, which is dominant in a narrow temperature range of 90 ˜ 115 K. The FM interaction becomes strong for Ca0.85Pr0.15MnO3 doped with 4 and 8% Ru into the Mn site ( i.e., Ca0.85Pr0.15Mn1- x Ru x O3 with x = 0.04 and 0.08). The Curie temperature obtained for x = 0.04 and 0.08 are about 135 and 180 K, respectively. While the FM interaction in the former is dominant due to Mn3+-Mn4+ exchange pairs, the latter has the contribution of Ru ions. This results in remarkable differences in the features of their FM-paramagnetic phase transitions and their coercive fields H c .
A comparative study between different approaches to improve the RCS of a compact double-layer absorber

NASA Astrophysics Data System (ADS)

El-Hakim, H. A.; Mahmoud, K. R.

2017-10-01

In this paper, straightforward and efficient techniques have been addressed into double-layer structure to enlarge the operating bandwidth to include the X, Ku and K bands, in addition to increase the electromagnetic wave absorption for wide varieties of incident angles and both polarization types. To increase the band-stop resonating frequency up to 26 GHz, an additional layer of meta-surface, circuit analog radar absorber material (CAR), or a thin radar absorber material (RAM) layer is engineered. The synthesized layers are designed based on optimization process with genetic algorithm (GA) through numerical technique (Ansoft design software HFSS) for both transmission line (T.L) and the free space method to get optimal material properties suitable for the design. For different approaches, the designed structures achieved a reflectivity value less than -16 dB on average in the desired bandwidth from 8 to 26 GHz for TE/TM modes with incidence angle up to 50o.
Influence of oxygen vacancies in ALD HfO2-x thin films on non-volatile resistive switching phenomena with a Ti/HfO2-x/Pt structure

NASA Astrophysics Data System (ADS)

Sokolov, Andrey Sergeevich; Jeon, Yu-Rim; Kim, Sohyeon; Ku, Boncheol; Lim, Donghwan; Han, Hoonhee; Chae, Myeong Gyoon; Lee, Jaeho; Ha, Beom Gil; Choi, Changhwan

2018-03-01

We report a modulation of oxygen vacancies profile in atomic layer deposition (ALD) HfO2-x thin films by reducing oxidant pulse time (0.7 s-0.1 s) and study its effect on resistive switching behavior with a Ti/HfO2-x/Pt structure. Hf 4f spectra of x-ray photoelectron microscopy (XPS) and depth profile confirm varied oxygen vacancies profiles by shifts of binding energies of Hf 4f5/2 and Hf 4f7/2 main peaks and its according HfO2-x sub-oxides for each device. The ultraviolet photoelectron spectroscopy (UPS) confirms different electron affinity (χ) of HfO2 and HfO2-x thin films, implying that barrier height at Ti/oxide interface is reduced. Current transport mechanism is dictated by Ohmic conduction in fully oxidized HfO2 thin films - Device A (0.7 s) and by Trap Filled Space Charge Limited Conduction (TF-SCLC) in less oxidized HfO2-x thin films - Device B (0.3 s) and Device C (0.1 s). A switching mechanism related to the oxygen vacancies modulation in Ti/HfO2-x/Pt based resistive random access memory (RRAM) devices is used to explain carefully notified current transport mechanism variations from device-to-device. A proper endurance and long-time retention characteristics of the devices are also obtained.
Structure Evolution and Reactivity of the Sc(2- x)V xO3+δ (0 ≤ x ≤ 2.0) System.

PubMed

Lussier, Joey A; Simon, Fabian J; Whitfield, Pamela S; Singh, Kalpana; Thangadurai, Venkataraman; Bieringer, Mario

2018-05-07

Solid oxide fuel cells (SOFCs) are solid-state electrochemical devices that directly convert chemical energy of fuels into electricity with high efficiency. Because of their fuel flexibility, low emissions, high conversion efficiency, no moving parts, and quiet operation, they are considered as a promising energy conversion technology for low carbon future needs. Solid-state oxide and proton conducting electrolytes play a crucial role in improving the performance and market acceptability of SOFCs. Defect fluorite phases are some of the most promising fast oxide ion conductors for use as electrolytes in SOFCs. We report the synthesis, structure, phase diagram, and high-temperature reactivity of the Sc (2- x) V x O 3+δ (0 ≤ x ≤ 2.00) oxide defect model system. For all Sc (2- x) V x O 3.0 phases with x ≤ 1.08 phase-pure bixbyite-type structures are found, whereas for x ≥ 1.68 phase-pure corundum structures are reported, with a miscibility gap found for 1.08 < x < 1.68. Structural details obtained from the simultaneous Rietveld refinements using powder neutron and X-ray diffraction data are reported for the bixbyite phases, demonstrating a slight V 3+ preference toward the 8b site. In situ X-ray diffraction experiments were used to explore the oxidation of the Sc (2- x) V x O 3.0 phases. In all cases ScVO 4 was found as a final product, accompanied by Sc 2 O 3 for x < 1.0 and V 2 O 5 when x > 1.0; however, the oxidative pathway varied greatly throughout the series. Comments are made on different synthesis strategies, including the effect on crystallinity, reaction times, rate-limiting steps, and reaction pathways. This work provides insight into the mechanisms of solid-state reactions and strategic guidelines for targeted materials synthesis.
Type-I non-critically phase-matched second-harmonic generation in Gd1-xYxCa4O(BO3)3

NASA Astrophysics Data System (ADS)

Burmester, P. B. W.; Kellner, T.; Petermann, K.; Huber, G.; Uecker, R.; Reiche, P.

Second-harmonic generation was z-cut observed Gd1-xYxCa4O(BO3)3 (Gd1-xYxCOB) and the dependence of the phase-matching wavelength on the mixing ratio x has been investigated. The dependence on both temperature and angle tuning was examined as well. We found the suitable composition for noncritical frequency doubling at 930 nm, which is the lasing wavelength of Nd:YAlO3 on the 4F3/2?4I9/2 transition.
Magnetic interactions in rhenium-containing rare earth double perovskites Sr{sub 2}LnReO{sub 6} (Ln=rare earths)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishiyama, Atsuhide; Doi, Yoshihiro; Hinatsu, Yukio, E-mail: hinatsu@sci.hokudai.ac.jp

The perovskite-type compounds containing both rare earth and rhenium Sr{sub 2}LnReO{sub 6} (Ln=Y, Tb-Lu) have been prepared. Powder X-ray diffraction measurements and Rietveld analysis show that Ln{sup 3+} and Re{sup 5+} ions are structurally ordered at the B site of the perovskite SrBO{sub 3}. Magnetic anomalies are found in their magnetic susceptibility and specific heat measurements at 2.6–20 K for Ln=Y, Tb, Dy, Yb, Lu compounds. They are due to magnetic interactions between Re{sup 5+} ions. The results of the magnetic hysteresis and remnant magnetization measurements for Sr{sub 2}YReO{sub 6} and Sr{sub 2}LuReO{sub 6} indicate that the antiferromagnetic interactions betweenmore » Re{sup 5+} ions below transition temperatures have a weak ferromagnetic component. The analysis of the magnetic specific heat data for Sr{sub 2}YbReO{sub 6} shows that both the Yb{sup 3+} and Re{sup 5+} ions magnetically order at 20 K. For the case of Sr{sub 2}DyReO{sub 6}, magnetic ordering of the Re{sup 5+} moments occurs at 93 K, and with decreasing temperature, the moments of Dy{sup 3+} ferromagnetically order at 5 K from the measurements of magnetic susceptibility and specific heat. - Graphical abstract: Crystal structure of double perovskite Sr{sub 2}LnReO{sub 6}. Red and black lines show cubic and monoclinic unit cells, respectively. - Highlights: • Double perovskites Sr{sub 2}LnReO{sub 6} (Ln=rare earths) were prepared. • They show an antiferromagnetic transition at 2.6–20 K. • In Sr{sub 2}DyReO{sub 6}, Dy and Re moments magnetically order at 5 and 93 K, respectively.« less
Fused-fiber-based 3-dB mode insensitive power splitters for few-mode optical fiber networks

NASA Astrophysics Data System (ADS)

Ren, Fang; Huang, Xiaoshan; Wang, Jianping

2017-11-01

We propose a 3-dB mode insensitive power splitter (MIPS) capable of broadcasting and combining optical signals. It is fabricated with two identical few-mode fibers (FMFs) by a heating and pulling technique. The mode-dependent power transfer characteristic as a function of pulling length is investigated. For exploiting its application, we experimentally demonstrate both FMF-based transmissive and reflective star couplers consisting of multiple 3-dB mode insensitive power splitters, which perform broadcasting and routing signals in few-mode optical fiber networks such as mode-division multiplexing (MDM) local area networks using star topology. For experimental demonstration, optical on-off keying signals at 10 Gb/s carried on three spatial modes are successfully processed with open and clear eye diagrams. Measured bit error ratio results show reasonable power penalties. It is found that a reflective star coupler in MDM networks can reduce half of the total amount of required fibers comparing to that of a transmissive star coupler. This MIPS is more efficient, more reliable, more flexible, and more cost-effective for future expansion and application in few-mode optical fiber networks.
Unanticipated spin gap measured in the frustrated quasi-FCC d3 double perovskites La2 LiXO6 (X = Ru, Os)

NASA Astrophysics Data System (ADS)

Maharaj, Dalini D.; Sala, Gabriele; Marjerrison, Casey A.; Greedan, John; Gaulin, Bruce; Stone, Matthew

There is much current interest in the influence of strong spin-orbit (SO) interactions on exotic ground state selection in new 4d and 5d magnets, particularly involving 4d5 Ir. Here we consider double perovskites of the form A2 BB'O6 which are based on heavy 4d or 5d magnetic ions, where the SO interaction is expected to be significant as it increases as ~Z4 . The double perovskite structure can accommodate a variety of magnetic ions on the B' site, providing a playground for systematic studies of the exotic ground states stabilized by strong SO coupling. Here, we report inelastic neutron scattering (INS) measurements conducted on the frustrated monoclinic magnets, La2LiXO6 (X = Ru, Os), wherein the magnetic moments decorate a quasi face-centered-cubic lattice. Our results show the development of a spin gap in the spin excitation spectrum of size ΔOs = 8 meV and ΔRu = 2.5meV concomitant with TN, which is unexpected for orbitally quenched d3 systems. We liken these results to INS results obtained for Ba2YXO6 and La2NaXO6, which were also shown to exhibit spin gaps that correlate with TN. We shall discuss trends observed in these three d3 double perovskite families which correlate strong SO coupling, spin gap and TN.
Energy of auroral electrons and Z mode generation

NASA Technical Reports Server (NTRS)

Krauss-Varban, D.; Wong, H. K.

1990-01-01

The present consideration of Z-mode radiation generation, in light of observational results indicating that the O mode and second-harmonic X-mode emissions can prevail over the X-mode fundamental radiation when suprathermal electron energy is low, gives attention to whether the thermal effect on the Z-mode dispersion can be equally important, and whether the Z-mode can compete for the available free-energy source. It is found that, under suitable circumstances, the growth rate of the Z-mode can be substantial even for low suprathermal auroral electron energies. Growth is generally maximized for propagation perpendicular to the magnetic field.
Experimental and theoretical comparison of the O K-edge nonresonant inelastic X-ray scattering and X-ray absorption spectra of NaReO4.

PubMed

Bradley, Joseph A; Yang, Ping; Batista, Enrique R; Boland, Kevin S; Burns, Carol J; Clark, David L; Conradson, Steven D; Kozimor, Stosh A; Martin, Richard L; Seidler, Gerald T; Scott, Brian L; Shuh, David K; Tyliszczak, Tolek; Wilkerson, Marianne P; Wolfsberg, Laura E

2010-10-06

Accurate X-ray absorption spectra (XAS) of first row atoms, e.g., O, are notoriously difficult to obtain due to the extreme sensitivity of the measurement to surface contamination, self-absorption, and saturation affects. Herein, we describe a comprehensive approach for determining reliable O K-edge XAS data for ReO(4)(1-) and provide methodology for obtaining trustworthy and quantitative data on nonconducting molecular systems, even in the presence of surface contamination. This involves comparing spectra measured by nonresonant inelastic X-ray scattering (NRIXS), a bulk-sensitive technique that is not prone to X-ray self-absorption and provides exact peak intensities, with XAS spectra obtained by three different detection modes, namely total electron yield (TEY), fluorescence yield (FY), and scanning transmission X-ray microscopy (STXM). For ReO(4)(1-), TEY measurements were heavily influenced by surface contamination, while the FY and STXM data agree well with the bulk NRIXS analysis. These spectra all showed two intense pre-edge features indicative of the covalent interaction between the Re 5d and O 2p orbitals. Density functional theory calculations were used to assign these two peaks as O 1s excitations to the e and t(2) molecular orbitals that result from Re 5d and O 2p covalent mixing in T(d) symmetry. Electronic structure calculations were used to determine the amount of O 2p character (%) in these molecular orbitals. Time dependent-density functional theory (TD-DFT) was also used to calculate the energies and intensities of the pre-edge transitions. Overall, under these experimental conditions, this analysis suggests that NRIXS, STXM, and FY operate cooperatively, providing a sound basis for validation of bulk-like excitation spectra and, in combination with electronic structure calculations, suggest that NaReO(4) may serve as a well-defined O K-edge energy and intensity standard for future O K-edge XAS studies.

Double valley Dirac fermions for 3D and 2D Hg1-x Cd x Te with strong asymmetry

NASA Astrophysics Data System (ADS)

Marchewka, M.

2017-04-01

In this paper the possibility to bring about the double-valley Dirac fermions in some quantum structures is predicted. These quantum structures are: strained 3D Hg1-x Cd x Te topological insulator (TI) with strong interface inversion asymmetry and the asymmetric Hg1-x Cd x Te double quantum wells (DQW). The numerical analysis of the dispersion relation for 3D TI Hg1-x Cd x Te for the proper Cd (x)-content of the Hg1-x Cd x Te compound clearly shows that the inversion symmetry breaking together with the unaxial tensile strain causes the splitting of each of the Dirac nodes (two belonging to two interfaces) into two in the proximity of the Γ-point. Similar effects can be obtained for asymmetric Hg1-x Cd x Te DQW with the proper content of Cd and proper width of the quantum wells. The aim of this work is to explore the inversion symmetry breaking in 3D TI and 2D DQW mixed HgCdTe systems. It is shown that this symmetry breaking leads to the dependence of carriers energy on quasi-momentum similar to that of Weyl fermions.
Double MITs and magnetoresistance: an intrinsic feature of Ru substituted La0.67Ca0.33MnO3

NASA Astrophysics Data System (ADS)

Seetha Lakshmi, L.; Sridharan, V.; Sukumar, A. A.; Kamruddin, M.; Sastry, V. S.; Raju, V. S.

2006-05-01

In this paper, we examine the possible influence of extrinsic factors on the electrical and magnetotransport of La0.67Ca0.33Mn1-xRuxO3 (x<=0.10). Ru substitution results in double metal-insulator transitions (MITs) at TMI1 and TMI2, both exhibiting magnetoresistance (MR). No additional magnetic signal corresponding to a second low-temperature maximum (LTM) at TMI2 could be observed, either in ac susceptibility (χ') or in specific heat (Cp). Typical grain sizes of ~18 000-20 000 nm, as estimated from the scanning electron microscope (SEM) micrographs, are not so small as to warrant an LTM. The absence of additional peaks in the high statistics powder x-ray diffraction (XRD), a linear systematic increase of the unit cell parameters, close matching of the transition temperatures in resistivity, χ' and Cp and their linear systematic decrease with x, and an homogeneous distribution of Mn, Ru and O at arbitrarily selected regions within and across the grains exclude chemical inhomogeneity in the samples. The insensitivity of grain boundary MR at 5 K to Ru composition indicates that the grain boundary is not altered to result in an LTM. Oxygen stoichiometry of all the compounds is close to the nominal value of 3. These results not only exclude the extrinsic factors, but also establish that double MITs, both exhibiting MR, are intrinsic to Ru substituted La0.67Ca0.33MnO3.
Nb K-edge x-ray absorption investigation of the pressure induced amorphization in A-site deficient double perovskite La1/3NbO3.

PubMed

Marini, C; Noked, O; Kantor, I; Joseph, B; Mathon, O; Shuker, R; Kennedy, B J; Pascarelli, S; Sterer, E

2016-02-03

Nb K-edge x-ray absorption spectroscopy is utilized to investigate the changes in the local structure of the A-site deficient double perovskite La1/3NbO3 which undergoes a pressure induced irreversible amorphization. EXAFS results show that with increasing pressure up to 7.5 GPa, the average Nb-O bond distance decreases in agreement with the expected compression and tilting of the NbO6 octahedra. On the contrary, above 7.5 GPa, the average Nb-O bond distance show a tendency to increase. Significant changes in the Nb K-edge XANES spectrum with evident low energy shift of the pre-peak and the absorption edge is found to happen in La1/3NbO3 above 6.3 GPa. These changes evidence a gradual reduction of the Nb cations from Nb(5+) towards Nb(4+) above 6.3 GPa. Such a valence change accompanied by the elongation of the average Nb-O bond distances in the octahedra, introduces repulsion forces between non-bonding adjacent oxygen anions in the unoccupied A-sites. Above a critical pressure, the Nb reduction mechanism can no longer be sustained by the changing local structure and amorphization occurs, apparently due to the build-up of local strain. EXAFS and XANES results indicate two distinct pressure regimes having different local and electronic response in the La1/3NbO3 system before the occurence of the pressure induced amorphization at ∼14.5 GPa.
High-pressure X-ray diffraction and Raman spectroscopy of CaFe2O4-type β-CaCr2O4

NASA Astrophysics Data System (ADS)

Zhai, Shuangmeng; Yin, Yuan; Shieh, Sean R.; Shan, Shuangming; Xue, Weihong; Wang, Ching-Pao; Yang, Ke; Higo, Yuji

2016-04-01

In situ high-pressure synchrotron X-ray diffraction and Raman spectroscopic studies of orthorhombic CaFe2O4-type β-CaCr2O4 chromite were carried out up to 16.2 and 32.0 GPa at room temperature using multi-anvil apparatus and diamond anvil cell, respectively. No phase transition was observed in this study. Fitting a third-order Birch-Murnaghan equation of state to the P-V data yields a zero-pressure volume of V 0 = 286.8(1) Å3, an isothermal bulk modulus of K 0 = 183(5) GPa and the first pressure derivative of isothermal bulk modulus K 0' = 4.1(8). Analyses of axial compressibilities show anisotropic elasticity for β-CaCr2O4 since the a-axis is more compressible than the b- and c-axis. Based on the obtained and previous results, the compressibility of several CaFe2O4-type phases was compared. The high-pressure Raman spectra of β-CaCr2O4 were analyzed to determine the pressure dependences and mode Grüneisen parameters of Raman-active bands. The thermal Grüneisen parameter of β-CaCr2O4 is determined to be 0.93(2), which is smaller than those of CaFe2O4-type CaAl2O4 and MgAl2O4.
Observation of the electron density fluctuations by using the O-mode Microwave Imaging Reflectometry in LHD

NASA Astrophysics Data System (ADS)

Nagayama, Yoshio; Yamaguchi, Soichiro; Tsuchiya, Hayato; Kuwahara, Daisuke; LHD Experimental Team

2016-10-01

Visualization of local electron density fluctuations will be very useful to study the physics of confinement and instabilities in fusion plasma. In the Large Helical Device (LHD), the O-mode microwave imaging reflectometry (O-MIR) has been intensively developed in order to visualize the electron density fluctuations. The frequency is 26 - 34 GHz. This corresponds to the electron density of 0.8 - 1.5 × 1019 m-3. The plasma is illuminated by the Gaussian beam with four frequencies. The imaging optics make a plasma image onto the newly developed 2D (8 × 8) Horn-antenna Millimeter-wave Imaging Device (HMID). In HMID, the signal wave that is accumulated by the horn antenna is transduced to the micro-strip line by using the finline transducer. The signal wave is mixed by the double balanced mixer with the local wave that is delivered by cables. By using O-MIR, electron density fluctuations are measured at the H-mode edge and the ITB layer in LHD. This work is supported by NIFS/NINS under the project of Formation of International Scientific Base and Network, by the NIFS LHD project, by KAKENHI, and by IMS.
Stabilization and tracking control of X-Z inverted pendulum with sliding-mode control.

PubMed

Wang, Jia-Jun

2012-11-01

X-Z inverted pendulum is a new kind of inverted pendulum which can move with the combination of the vertical and horizontal forces. Through a new transformation, the X-Z inverted pendulum is decomposed into three simple models. Based on the simple models, sliding-mode control is applied to stabilization and tracking control of the inverted pendulum. The performance of the sliding mode control is compared with that of the PID control. Simulation results show that the design scheme of sliding-mode control is effective for the stabilization and tracking control of the X-Z inverted pendulum. Copyright © 2012 ISA. Published by Elsevier Ltd. All rights reserved.
Cosmic bandits: Exploration versus exploitation in CMB B-mode experiments

NASA Astrophysics Data System (ADS)

Kovetz, Ely D.; Kamionkowski, Marc

2016-02-01

A preferred method to detect the curl-component, or B-mode, signature of inflationary gravitational waves (IGWs) in the cosmic microwave background (CMB) polarization, in the absence of foregrounds and lensing, is a prolonged integration over a single patch of sky of a few square degrees. In practice, however, foregrounds abound and the sensitivity to B modes can be improved considerably by finding the region of sky cleanest of foregrounds. The best strategy to detect B modes thus involves a tradeoff between exploration (to find lower-foreground patches) and exploitation (through prolonged integration). This problem is akin to the multi-armed bandit (MAB) problem in probability theory, wherein a gambler faces a series of slot machines with unknown winning odds and must develop a strategy to maximize his/her winnings with some finite number of pulls. While the optimal MAB strategy remains to be determined, a number of algorithms have been developed in an effort to maximize the winnings. Here, based on this resemblance, we tackle the search for IGW B modes with single frequency experiments in the presence of spatially varying foregrounds by developing adaptive survey strategies to optimize the sensitivity to IGW B modes. We demonstrate, using realistic foreground models and taking lensing-induced B modes into account, that adaptive experiments can substantially improve the upper bound on the tensor-to-scalar ratio (by factors of 2 and 3 in single frequency experiments, and possibly even more). Similar techniques can be applied to other surveys, including 21-cm measurements of signatures of the epoch of reionization, searches for a stochastic primordial gravitational wave background, deep-field imaging by the James Webb Space Telescope or various radio interferometers, and transient follow-up searches.
High-pressure synthesis and structural, physical properties of CaIr1-xPtxO3 and CaIr1-xRhxO3

NASA Astrophysics Data System (ADS)

Hirai, S.; Bromiley, G. D.; Klemme, S.; Irifune, T.; Ohfuji, H.; Attfield, P.; Nishiyama, N.

2010-12-01

in terms of materials science applications. To our knowledge, this will be the first report on structural, magnetic and charge-transport properties of B-site substituted solid solutions of post-perovskite oxides with 4d/5d transition metals. High-quality polycrystalline samples of CaIr1-xPtxO3 and CaIr1-xRhxO3 have been obtained at high pressures, and structural, magnetic and charge-transport properties of the compounds will be reported. ODF analysis reveals that solutions of CaIrO3, CaPtO3 and CaRhO3 exhibit similar grain growth features to the mother compound, although growth in [0 1 0] plays a more dominant role than the growth in [0 0 1] for the solid solutions. CaIrO3 is a characteristic hard magnet suitable for applications such as magnetic recording, with TN = 108K. A new phase of CaIr1-xPtxO3 synthesized at a high P/T condition has Raman modes which resemble those of CaIrO3 perovskite, suggesting this phase has a perovskite structure.The instability of the perovskite phase of CaIr1-xPtxO3 reveals why the post-perovskite to peovskite phase transition has not been observed for CaPtO3 unlike the case for CaIrO3, CaRhO3 and CaRuO3.
Multi-wavelength generation based on cascaded Raman scattering and self-frequency-doubling in KTA

NASA Astrophysics Data System (ADS)

Zhong, K.; Li, J. S.; Xu, D. G.; Ding, X.; Zhou, R.; Wen, W. Q.; Li, Z. Y.; Xu, X. Y.; Wang, P.; Yao, J. Q.

2010-04-01

A multi-wavelength laser is developed based on cascaded stimulated Raman scattering (SRS) and self-frequency-doubling in an x-cut KTA crystal pumped by an A-O Q-switched Nd:YAG laser. The generation of 1178 nm from cascaded SRS of 234 and 671 cm-1 Raman modes is observed. The six wavelengths, including the fundamental 1064 nm, four Stokes waves at 1091, 1120, 1146, 1178 nm, and the second harmonic generation (SHG) of 1146 nm, are tens to hundreds of millwatts for each at 10 kHz, corresponding to a total conversion efficiency of 8.72%.
Edge Stability and Performance of the ELM-Free Quiescent H-Mode and the Quiescent Double Barrier Mode on DIII-D

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, W P; Burrell, K H; Casper, T A

2004-12-03

The quiescent H (QH) mode, an edge localized mode (ELM)-free, high-confinement mode, combines well with an internal transport barrier to form quiescent double barrier (QDB) stationary state, high performance plasmas. The QH-mode edge pedestal pressure is similar to that seen in ELMing phases of the same discharge, with similar global energy confinement. The pedestal density in early ELMing phases of strongly pumped counter injection discharges drops and a transition to QH-mode occurs, leading to lower calculated edge bootstrap current. Plasmas current ramp experiment and ELITE code modeling of edge stability suggest that QH-modes lie near an edge current stability boundary.more » At high triangularity, QH-mode discharges operate at higher pedestal density and pressure, and have achieved ITER level values of {beta}{sub PED} and {nu}*. The QDB achieves performance of {alpha}{sub N}H{sub 89} {approx} 7 in quasi-stationary conditions for a duration of 10 tE, limited by hardware. Recently we demonstrated stationary state QDB discharges with little change in kinetic and q profiles (q{sub 0} > 1) for 2 s, comparable to ELMing ''hybrid scenarios'', yet without the debilitating effects of ELMs. Plasma profile control tools, including electron cyclotron heating and current drive and neutral beam heating, have been demonstrated to control simultaneously the q profile development, the density peaking, impurity accumulation and plasma beta.« less
Perovskite-Type Oxides. I. Structural, Magnetic, and Morphological Properties of LaMn 1- xCu xO 3 and LaCo 1- xCu xO 3 Solid Solutions with Large Surface Area

NASA Astrophysics Data System (ADS)

Porta, Piero; De Rossi, Sergio; Faticanti, Marco; Minelli, Giuliano; Pettiti, Ida; Lisi, Luciana; Turco, Maria

1999-09-01

Perovskite-type compounds of general formula LaMn1-xCuxO3 and LaCo1-xCuxO3 (x=0.0, 0.2, 0.4, 0.6, 0.8, 1.0) were prepared by calcining the citrate gel precursors at 823, 923, and 1073 K. The decomposition of the precursors was followed by thermal analysis and the oxides were investigated by means of elemental analysis (atomic absorption and redox titration), X-ray powder diffraction, BET surface area, X-ray absorption (EXAFS and XANES), electron microscopy (SEM and TEM), and magnetic susceptibility. LaMn1-xCuxO3 samples are perovskite-like single phases up to x=0.6. At x=0.8 CuO and La2CuO4 phases are present in addition to perovskite. For x=1.0 the material is formed by CuO and La2CuO4. Mn(IV) was found by redox titration in all Mn-based perovskite samples, its fraction increasing with the increase in copper content. EXAFS and XANES analyses confirmed the presence of Mn(IV). Cation vacancies in equal amounts in the 12-coordinated A and octahedral B sites are suggested in the samples with x=0.0 and x=0.2, while for x=0.6 anionic vacancies are present. Materials with sufficiently high surface area (22-36 m2 g-1 for samples fired at 923 K and 14-22 m2 g-1 for those fired at 1073 K) were obtained. Crystallite sizes in the ranges 390-500 and 590-940 Å for samples calcined at 923 and 1073 K, respectively, were determined from the FWHM of the (102) X-ray diffraction peak. TEM patterns of LaMnO3 showed almost regular hexagonal prismatic crystals with sizes of the same order of magnitude (800 Å) of those drawn from X-ray diffraction, while no evidence of defect clustering was drawn out from TEM and electron diffraction images. For the sample with x=0.6, TEM and electron diffraction patterns revealed perturbation of the structure. Magnetic susceptibility studies show a ferromagnetic behavior that decreases with increase in x. LaCo1-xCuxO3 samples are perovskite-like single phases up to x=0.2. For x=0.4 a small amount of La2CuO4, in addition to perovskite, is detected. For
Analyzing x-ray hotspot images with Ince-Gaussian modes

NASA Astrophysics Data System (ADS)

Kruse, Michael; Field, John; Nora, Ryan; Benedetti, Robin; Khan, Shahab; Ma, Tammy; Peterson, Luc; Spears, Brian

2017-10-01

X-ray images at the National Ignition Facility (NIF) provide important metrics regarding the shape of the hotspot along a given line-of-sight. The 17% contour from peak brightness is usually used to infer the size of the hotspot as well as determine shape perturbations quantified through the Legendre coefficients P2 and P4. Unfortunately features that lie inside the contour such as those that could arise from tent or fill-tube perturbations are not easily captured. An analysis that takes into account the two-dimensional nature of the x-ray image is desirable. Ince-Gaussian modes (for short: Ince) offer such an analysis and could provide a new way to encode and understand the images recorded at NIF. The Ince modes are the solutions to the paraxial wave equation expressed in elliptical coordinates and thus form an orthonormal basis. Due to their elliptical nature they are suitable for decomposing images that have a non-zero P2 or P4 coefficient. We show that the Ince modes can be used to uncover structure that is missed by the contour analysis and how the modes aid in compressing images produced in large ensemble calculations. Finally a comparison is made to the Zernike modes which form an orthonormal basis on a circular disk. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-734741.
Study of the X ± ( 5568 ) state with semileptonic decays of the B s 0 meson

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abazov, V. M.; Abbott, B.; Acharya, B. S.

Here, we present a study of the X ±(5568) using semileptonic decays of the B s 0 meson using the full run II integrated luminosity of 10.4 fb -1 in proton-antiproton collisions at a center of mass energy of 1.96 TeV collected with the D0 detector at the Fermilab Tevatron Collider. We report evidence for a narrow structure, X ±(5568), in the decay sequence X ±(5568) → B s 0π ± where B s 0 → μ ∓D s ±X, D s ± → Φπ ± which is consistent with the previous measurement by the D0 Collaboration in the hadronic decaymore » mode, X ±(5568) → B s 0π ± where B s 0 → J/ψΦ. The mass and width of this state are measured using a combined fit of the hadronic and semileptonic data, yielding m = 5566.9 -3.1 +3.2(stat) -1.2 +0.6(syst) MeV/c 2, Γ = 18.6 -6.1 +7.9(stat) -3.8 +3.5(syst) MeV/c 2 with a significance of 6.7σ.« less
Study of the X ± ( 5568 ) state with semileptonic decays of the B s 0 meson

DOE PAGES

Abazov, V. M.; Abbott, B.; Acharya, B. S.; ...

2018-05-18

Here, we present a study of the X ±(5568) using semileptonic decays of the B s 0 meson using the full run II integrated luminosity of 10.4 fb -1 in proton-antiproton collisions at a center of mass energy of 1.96 TeV collected with the D0 detector at the Fermilab Tevatron Collider. We report evidence for a narrow structure, X ±(5568), in the decay sequence X ±(5568) → B s 0π ± where B s 0 → μ ∓D s ±X, D s ± → Φπ ± which is consistent with the previous measurement by the D0 Collaboration in the hadronic decaymore » mode, X ±(5568) → B s 0π ± where B s 0 → J/ψΦ. The mass and width of this state are measured using a combined fit of the hadronic and semileptonic data, yielding m = 5566.9 -3.1 +3.2(stat) -1.2 +0.6(syst) MeV/c 2, Γ = 18.6 -6.1 +7.9(stat) -3.8 +3.5(syst) MeV/c 2 with a significance of 6.7σ.« less
X-24B launch - air drop from mothership

NASA Technical Reports Server (NTRS)

1974-01-01

A fleet of lifting bodies flown at the NASA Flight Research Center, Edwards, California, from 1963 to l975 demonstrated the ability of pilots to maneuver (in the atmosphere) and safely land a wingless vehicle. These lifting bodies were basically designed so they could fly back to Earth from space and be landed like an aircraft at a pre-determined site. (In 1976 NASA renamed the FRC as the NASA Dryden Flight Research Center in honor of Hugh L. Dryden.) In 1962, FRC Director Paul Bikle approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1. It featured a plywood shell, built by Gus Briegleb (a sailplane builder from El Mirage, California) placed over a tubular steel frame crafted at the FRC. Construction was completed in 1963. The success of the Flight Research Center M2-F1 program led to NASA development and construction of two heavyweight lifting bodies based on studies at the NASA Ames and Langley research centers--the M2-F2 and the HL-10, both built by the Northrop Corporation, Hawthorne, California. The Air Force also became interested in lifting body research and had a third design concept built, the X-24A, built by the Martin Company, Denver, Colorado. It was later modified into the X-24B and both configurations were flown in the joint NASA-Air Force lifting body program located at Dryden. The X-24B design evolved from a family of potential reentry shapes, each with higher lift-to-drag ratios, proposed by the Air Force Flight Dynamics Laboratory. To reduce the costs of constructing a research vehicle, the Air Force returned the X-24A to Martin for modifications that converted its bulbous shape into one resembling a 'flying flatiron' -- rounded top, flat bottom, and a double-delta planform that ended in a pointed nose. First to fly the X-24B was John A. Manke, a glide flight on August 1, 1973. He was also the pilot on the first
Effects of (NH4)2S x treatment on the surface properties of SiO2 as a gate dielectric for pentacene thin-film transistor applications

NASA Astrophysics Data System (ADS)

Hung, Cheng-Chun; Lin, Yow-Jon

2018-01-01

The effect of (NH4)2S x treatment on the surface properties of SiO2 is studied. (NH4)2S x treatment leads to the formation of S-Si bonds on the SiO2 surface that serves to reduce the number of donor-like trap states, inducing the shift of the Fermi level toward the conduction band minimum. A finding in this case is the noticeably reduced value of the SiO2 capacitance as the sulfurated layer is formed at the SiO2 surface. The effect of SiO2 layers with (NH4)2S x treatment on the carrier transport behaviors for the pentacene/SiO2-based organic thin-film transistor (OTFT) is also studied. The pentacene/as-cleaned SiO2-based OTFT shows depletion-mode behavior, whereas the pentacene/(NH4)2S x -treated SiO2-based OTFT exhibits enhancement-mode behavior. Experimental identification confirms that the depletion-/enhancement-mode conversion is due to the dominance competition between donor-like trap states in SiO2 near the pentacene/SiO2 interface and acceptor-like trap states in the pentacene channel. A sulfurated layer between pentacene and SiO2 is expected to give significant contributions to carrier transport for pentacene/SiO2-based OTFTs.
Anomalous behavior of B{sub 1g} mode in highly transparent anatase nano-crystalline Nb-doped Titanium Dioxide (NTO) thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gautam, Subodh K., E-mail: subodhkgtm@gmail.com, E-mail: fouran@gmail.com; Ojha, S.; Singh, Fouran, E-mail: subodhkgtm@gmail.com, E-mail: fouran@gmail.com

2015-12-15

The effect of Niobium doping and size of crystallites on highly transparent nano-crystalline Niobium doped Titanium Dioxide (NTO) thin films with stable anatase phase are reported. The Nb doping concentration is varied within the solubility limit in TiO{sub 2} lattice. Films were annealed in controlled environment for improving the crystallinity and size of crystallites. Elemental and thickness analysis were carried out using Rutherford backscattering spectrometry and cross sectional field emission scanning electron microscopy. Structural characteristics reveal a substitutional incorporation of Nb{sup +5} in the TiO{sub 2} lattice which inhibits the anatase crystallites growth with increasing the doping percentage. The micro-Ramanmore » (MR) spectra of films with small size crystallites shows stiffening of about 4 cm{sup −1} for the E{sub g(1)} mode and is ascribed to phonon confinement and non-stoichiometry. In contrast, B{sub 1g} mode exhibits a large anomalous softening of 20 cm{sup −1} with asymmetrical broadening; which was not reported for the case of pure TiO{sub 2} crystallites. This anomalous behaviour is explained by contraction of the apical Ti-O bonds at the surface upon substitutional Nb{sup 5+} doping induced reduction of Ti{sup 4+} ions also known as hetero-coordination effect. The proposed hypotheses is manifested through studying the electronic structure and phonon dynamics by performing the near edge x-ray absorption fine structure (NEXAFS) and temperature dependent MR down to liquid nitrogen temperature on pure and 2.5 at.% doped NTO films, respectively.« less
Scintillation and optical properties of TiO2-ZnO-Al2O3-B2O3 glasses and glass-ceramics

NASA Astrophysics Data System (ADS)

Usui, Yuki; Okada, Go; Kawaguchi, Noriaki; Masai, Hirokazu; Yanagida, Takayuki

2018-04-01

13TiO2-xZnO-17Al2O3-(70 - x)B2O3 (x = 17, 26, and 35) glasses were prepared by a melt-quenching method, and the obtained glass samples were heated at temperatures 30 °C above the glass transition temperature of corresponding glass in order to obtain glass-ceramics. The obtained glass-ceramic samples were confirmed to have anatase (x = 17) and rutile (x = 26 and 35) phases from X-ray diffraction analysis. Then, the scintillation and optical properties were evaluated and discussed the difference between the glass-ceramic and glass samples. In the scintillation spectra under X-ray irradiation, a broad emission peak was observed around 450 nm in all the samples, and the new peak around 500 nm appeared in the anatase-precipitated glass-ceramic. The intensities of the glass-ceramic samples were enhanced in comparison with the corresponding glasses because the glass-ceramics includes TiO2 crystallites with defect centers which act as effective emission centers. The scintillation decay curves of the glass and glass-ceramic samples were approximated by one and a sum of two exponential decay functions, respectively. The faster component of glass and glass-ceramic samples would be caused by the host emission, and the slower component of glass-ceramic sample would be ascribed to the emission of Ti3+.
Electronic structure and spectroscopic properties of mononuclear manganese(III) Schiff base complexes: a systematic study on [Mn(acen)X] complexes by EPR, UV/vis, and MCD spectroscopy (X = Hal, NCS).

PubMed

Westphal, Anne; Klinkebiel, Arne; Berends, Hans-Martin; Broda, Henning; Kurz, Philipp; Tuczek, Felix

2013-03-04

The manganese(III) Schiff base complexes [Mn(acen)X] (H2acen: N,N'-ethylenebis(acetylacetone)imine, X: I(-), Br(-), Cl(-), NCS(-)) are considered as model systems for a combined study of the electronic structure using vibrational, UV/vis absorption, parallel-mode electron paramagnetic resonance (EPR) and low-temperature magnetic circular dichroism (MCD) spectroscopy. By variation of the co-ligand X, the influence of the axial ligand field within a given square-pyramidal coordination geometry on the UV/vis, EPR, and MCD spectra of the title compounds is investigated. Between 25000 and 35000 cm(-1), the low-temperature MCD spectra are dominated by two very intense, oppositely signed pseudo-A terms, referred to as "double pseudo-A terms", which change their signs within the [Mn(acen)X] series dependent on the axial ligand X. Based on molecular orbital (MO) and symmetry considerations, these features are assigned to π(n.b.)(s, a) → yz, z(2) ligand-to-metal charge transfer transitions. The individual MCD signs are directly determined from the calculated MOs of the [Mn(acen)X] complexes. The observed sign change is explained by an inversion of symmetry among the π(n.b.)(s, a) donor orbitals which leads to an interchange of the positive and negative pseudo-A terms constituting the "double pseudo-A term".
Vibrational mode frequencies of silica species in SiO2-H2O liquids and glasses from ab initio molecular dynamics.

PubMed

Spiekermann, Georg; Steele-MacInnis, Matthew; Schmidt, Christian; Jahn, Sandro

2012-04-21

Vibrational spectroscopy techniques are commonly used to probe the atomic-scale structure of silica species in aqueous solution and hydrous silica glasses. However, unequivocal assignment of individual spectroscopic features to specific vibrational modes is challenging. In this contribution, we establish a connection between experimentally observed vibrational bands and ab initio molecular dynamics (MD) of silica species in solution and in hydrous silica glass. Using the mode-projection approach, we decompose the vibrations of silica species into subspectra resulting from several fundamental structural subunits: The SiO(4) tetrahedron of symmetry T(d), the bridging oxygen (BO) Si-O-Si of symmetry C(2v), the geminal oxygen O-Si-O of symmetry C(2v), the individual Si-OH stretching, and the specific ethane-like symmetric stretching contribution of the H(6)Si(2)O(7) dimer. This allows us to study relevant vibrations of these subunits in any degree of polymerization, from the Q(0) monomer up to the fully polymerized Q(4) tetrahedra. Demonstrating the potential of this approach for supplementing the interpretation of experimental spectra, we compare the calculated frequencies to those extracted from experimental Raman spectra of hydrous silica glasses and silica species in aqueous solution. We discuss observed features such as the double-peaked contribution of the Q(2) tetrahedral symmetric stretch, the individual Si-OH stretching vibrations, the origin of the experimentally observed band at 970 cm(-1) and the ethane-like vibrational contribution of the H(6)Si(2)O(7) dimer at 870 cm(-1).

Evaluation and comparision of dc resistivity of NiZr x Co x Fe2-2x O4, Ni0.5Sn0.5Co x Mn x Fe2-2x O4, Mg1-x Ca x Ni y Fe2-y O4 and Mg1-x Ni x Co y Fe2-y O4 nanocrytalline materials

NASA Astrophysics Data System (ADS)

Ali, Rajjab; Gilani, Zaheer Abbas; Shahzad Shifa, Muhammad; Asghar, H. M. Noor Ul Huda Khan; Azhar Khan, Muhammad; Naeem Anjum, Muhammad; Nauman Usmani, Muhammad; Farooq Warsi, Muhammad; Khawaja, Imtiaz U.

2017-11-01

Four series nanocrystalline ferrites with nominal composition, NiZr x Co x Fe2-2x O4 (x = 0.0, 0.2, 0.4, 0.6, 0.8) Ni0.5Sn0.5Co x Mn x Fe2-2x O4 (x = 0.0, 0.2, 0.4, 0.6, 0.8), Mg1-x Ca x Ni y Fe2-y O4 (x = 0.0, 0.2, 0.4, 0.6, 0.8; y = 0, 04, 0.8, 1.2, 1.6) and Mg1-x Ni x Co y Fe2-y O4 (x,y = 0.0, 0.2, 0.4, 0.6, 0.8) have been fabricated using the microemulsion synthesis route. The synthesized materials are investigated for dc electrical resistivity measurements. The variation of dc electrical resistivity of these materials has been explainedon the basis of hopping mechanism of both holes and electrons.
Thermal and fragility studies on microwave synthesized K2O-B2O3-V2O5 glasses

NASA Astrophysics Data System (ADS)

Harikamalasree, Reddy, M. Sudhakara; Viswanatha, R.; Reddy, C. Narayana

2016-05-01

Glasses with composition xK2O-60B2O3-(40-x) V2O5 (15 ≤ x ≤ 39 mol %) was prepared by an energy efficient microwave method. The heat capacity change (ΔCp) at glass transition (Tg), width of glass transition (ΔTg), heat capacities in the glassy (Cpg) and liquid (Cpl) state for the investigated glasses were extracted from Modulated Differential Scanning Calorimetry (MDSC) thermograms. The width of glass transition is less than 30°C, indicating that these glasses belongs to fragile category. Fragility functions [NBO]/(Vm3Tg) and (ΔCp/Cpl)increases with increasing modifier oxide concentration. Increase in fragility is attributed to the increasing coordination of boron. Further, addition of K2O creates NBOs and the flow mechanism involves bond switching between BOs and NBOs. Physical properties exhibit compositional dependence and these properties increase with increasing K2O concentration. The observed variations are qualitatively analyzed.
New double molybdate Na9Fe(MoO4)6: Synthesis, structure, properties

NASA Astrophysics Data System (ADS)

Savina, Aleksandra A.; Solodovnikov, Sergey F.; Basovich, Olga M.; Solodovnikova, Zoya A.; Belov, Dmitry A.; Pokholok, Konstantin V.; Gudkova, Irina A.; Stefanovich, Sergey Yu.; Lazoryak, Bogdan I.; Khaikina, Elena G.

2013-09-01

A new double molybdate Na9Fe(MoO4)6 was synthesized using solid state reactions and studied with X-ray powder diffraction, second harmonic generation (SHG) technique, differential scanning calorimetry, X-ray fluorescence analysis, Mössbauer and dielectric impedance spectroscopy. Single crystals of Na9Fe(MoO4)6 were obtained and its structure was solved (the space group R3¯, a=14.8264(2), c=19.2402(3) Å, V=3662.79(9) Å3, Z=6, R=0.0132). The structure is related to that of sodium ion conductor II-Na3Fe2(AsO4)3. The basic structure units are polyhedral clusters composed of central FeО6 octahedron sharing edges with three Na(1)О6 octahedra. The clusters share common vertices with bridging МоО4 tetrahedra to form an open 3D framework where the cavities are occupied by Na(2) and Na(3) atoms. The compound melts incongruently at 904.7±0.2 K. Arrhenius type temperature dependence of electric conductivity σ has been registered in solid state (σ=6.8×10-2 S сm-1 at 800 K), thus allowing considering Na9Fe(MoO4)6 as a new sodium ion conductor.
Toward a synthesis of hirsutellone B by the concept of double cyclization

PubMed Central

Reber, Keith P.; Tilley, S. David; Carson, Cheryl A.; Sorensen, Erik J.

2014-01-01

This account describes a strategy for directly forming three of the six rings found in the polyketide natural product hirsutellone B via a novel cyclization cascade. The key step in our approach comprises two transformations: a large-ring forming, nucleophilic capture of a transient acyl ketene and an intramolecular Diels–Alder reaction, both of which occur in tandem through thermolyses of appropriately functionalized, polyunsaturated dioxinones. These thermally induced “double cyclization” cascades generate three new bonds, four contiguous stereocenters, and a significant fraction of the polycyclic architecture of hirsutellone B. The advanced macrolactam and macrolactone intermediates that were synthesized by this process possess key features of the hirsutellone framework, including the stereochemically dense decahydrofluorene core and the strained para-cyclophane ring. However, attempts to complete the carbon skeleton of hirsutellone B via transannular carbon-carbon bond formation were undermined by competitive O-alkylation reactions. This account also documents how we adapted to this undesired outcome through an evaluation of several distinct strategies for synthesis, as well as our eventual achievement of a formal total synthesis of hirsutellone B. PMID:24032341
ZnO:Ag nanorods as efficient photocatalysts: Sunlight driven photocatalytic degradation of sulforhodamine B

NASA Astrophysics Data System (ADS)

Raji, R.; K. S., Sibi; K. G., Gopchandran

2018-01-01

Visible light responsive highly photocatalytic ZnO:Ag nanorods with varying Ag concentration were synthesized via co-precipitation method. X-ray diffraction analysis and high resolution transmission electron microscopy investigations confirmed the hexagonal wurtzite phase for these ZnO:Ag nanorods with preferential growth along the (101) plane. Raman shift and luminescence measurements indicated that the incorporation of Ag influences the lattice vibrational modes; there by causing distortion in lattice, inducing silent vibrational modes and emission behavior by quenching of both the band edge and visible emissions respectively. The photocatalytic performance of these nanorods as catalysts was tested by observing the photodegradation of a representative dye pollutant, viz., sulforhodamine B under sunlight irradiation. Photocatalytic performance was evaluated by determining the rate of reaction kinetics, photodegradation efficiency and mineralization efficiency. A high rate constant of 0.552 min-1, chemical oxygen demand value of 5.8 ppm and a mineralization efficiency of 94% were obtained when ZnO: Ag nanorods with an Ag content of 1.5 at.% were used as catalysts. The observed increase in photocatalytic efficiency with Ag content in ZnO:Ag nanorods is attributed to the electron scavenging action of silver, Schottky barrier between the Ag and ZnO interface and the better utilization of sunlight due to enhanced absorption due to plasmons in the visible region. BET analysis indicated that silver doping causes effective surface area of nanorods to increase, which in turn increases the photocatalytic efficiency. The possible mechanism for degradation of dye under sunlight irradiation is described with a schematic and the photostability of the ZnO:Ag nanorods were also tested through five repetitive cycles. This work suggests that the prepared ZnO:Ag nanorods are excellent reusable photocatalysts for the degradation of toxic organic waste in water, which causes severe
Comparison of structural and magnetic properties of Zn{sub x}Mg{sub 1.5-x}Mn{sub 0.5}FeO{sub 4} and MgAl{sub x}Cr{sub x}Fe{sub 2-2x}O{sub 4} spinel oxides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thummer, K. P., E-mail: kpthummer@yahoo.co.in; Tanna, A. R., E-mail: ashish.tanna@rku.ac.in; Joshi, H. H.

2016-05-23

The spinel oxides Zn{sub x}Mg{sub 1.5-x}Mn{sub 0.5}FeO{sub 4} (x = 0.0 to 0.6) and MgAl{sub x}Cr{sub x}Fe{sub 2-2x}O{sub 4} (x = 0.0 to 0.6) abbreviated as ZMMFO and MACFO respectively, were synthesized by standard ceramic processing. The compositional purity of all the specimens was checked by EDAX technique. The X-ray diffractometry was employed to determine the lattice constants and distribution of cations in the interstitial voids. The initial decrease of cell edge parameter (a) for ZMMFO up to x = 0.2 and thereafter expected rise in the ‘a’ and the initial slower rate of reduction in the lattice constant formore » MACFO are explained as basic of cation occupancy. The magnetic ordering in both systems is explained by invoking statistical canting models. The compositional variation of magneton number (n{sub B}) for ZMMFO could be very well explained by Localized canting of spin (LCS) model while Random canting of spin (RCS) model was used for MACFO system.« less
Crystal structures and magnetic properties of two-dimensional antiferromagnets Co{sub 1-x}Zn{sub x}TeMoO{sub 6}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doi, Yoshihiro, E-mail: doi@sci.hokudai.ac.j; Suzuki, Ryo; Hinatsu, Yukio

2009-12-15

Crystal structures and magnetic properties of metal telluromolybdates Co{sub 1-x}Zn{sub x}TeMoO{sub 6} (x=0.0, 0.1,...,0.9) are reported. All the compounds have an orthorhombic structure with space group P2{sub 1}2{sub 1}2 and a charge configuration of M{sup 2+}Te{sup 4+}Mo{sup 6+}O{sub 6}. In this structure, M ions form a pseudo-two-dimensional lattice in the ab plane. Their magnetic susceptibility measurements have been performed in the temperature range between 1.8 and 300 K. The end member CoTeMoO{sub 6} shows a magnetic transition at 24.4 K. The transition temperature for solid solutions rapidly decreases with increasing x and this transition disappears between x=0.4 and 0.5, whichmore » is corresponding to the percolation limit for the square-planer lattice. From the magnetization, specific heat, and powder neutron diffraction measurements, it is found that the magnetic transition observed in the CoTeMoO{sub 6} is a canted antiferromagnetic ordering of Co{sup 2+} ions. The antiferromagnetic component of the ordered magnetic moment (3.12(3)mu{sub B} at 10 K) is along the b-axis. In addition, there exists a small ferromagnetic component (0.28(3)mu{sub B}) along the a-axis. - Graphical abstract: The metal telluromolybdates Co{sub 1-x}Zn{sub x}TeMoO{sub 6} have an orthorhombic structure with space group P2{sub 1}2{sub 1}2. In this structure, M ions form a pseudo-square-planer lattice in the ab plane. These compounds show a low-dimensional magnetism reflecting this structural feature. The magnetic transition observed in the CoTeMoO{sub 6} is a canted antiferromagnetic ordering of Co{sup 2+} ions, and the figure is the magnetic structure.« less
Crystallographic site swapping of La3+ ion in BaA'LaTeO6 (A' = Na, K, Rb) double perovskite type compounds: diffraction and photoluminescence evidence for the site swapping.

PubMed

Phatak, R; Gupta, S K; Krishnan, K; Sali, S K; Godbole, S V; Das, A

2014-02-28

Double perovskite type compounds of the formula BaA'LaTeO6 (A' = Na, K, Rb) were synthesized by solid state route and their crystal structures were determined by Rietveld analysis using powder X-ray diffraction and neutron diffraction data. Na compound crystallizes in the monoclinic system with P2₁/n space group whereas, K and Rb compounds crystallize in Fm3m space group. All the three compounds show rock salt type ordering at B site. Crystal structure analysis shows that La ion occupies A site in Na compound whereas, it occupies B site in K and Rb compounds according to the general formula of AA'BB'O6 for a double perovskite type compound. Effect of this crystallographic site swapping of the La ion was also observed in the photoluminescence study by doping Eu(3+) in La(3+) site. The large decrease in the intensity of the electric dipole ((5)D0-(7)F2) transition in the Rb compound compared to the Na compound indicates that Eu(3+) ion resides in the centrosymmetric octahedral environment in the Rb compound.
Quantum interference effects on the intensity of the G modes in double-walled carbon nanotubes

NASA Astrophysics Data System (ADS)

Tran, H. N.; Blancon, J.-C.; Arenal, R.; Parret, R.; Zahab, A. A.; Ayari, A.; Vallée, F.; Del Fatti, N.; Sauvajol, J.-L.; Paillet, M.

2017-05-01

The effects of quantum interferences on the excitation dependence of the intensity of G modes have been investigated on single-walled carbon nanotubes [Duque et al., Phys. Rev. Lett. 108, 117404 (2012), 10.1103/PhysRevLett.108.117404]. In this work, by combining optical absorption spectroscopy and Raman scattering on individual index identified double-walled carbon nanotubes, we examine the experimental excitation dependence of the intensity of longitudinal optical and transverse optical G modes of the constituent inner and outer single-walled carbon nanotubes. The observed striking dependencies are understood in terms of quantum interference effects. Considering such effects, the excitation dependence of the different components of the G modes permits us to unambiguously assign each of them as originating from the longitudinal or transverse G modes of inner and outer tubes.
Tautomerism of monochalcogenosilanoic acids CH3Si(＝O)XH (X D S, Se, Te) in the gas phase and in the polar and aprotic solution: An ab initio computational investigation

NASA Astrophysics Data System (ADS)

Li, Qiang-Gen; Deng, Chao; Ren, Yi; Wong, Ning-Bew; Chu, San-Yan; Wang, Xin

Computational investigations by an ab initio molecular orbital method (HF and MP2) with the 6-311+G(d,p) and 6-311++G(2df, 2pd) basis sets on the tautomerism of three monochalcogenosilanoic acids CH3Si(＝O)XH (X D S, Se, and Te) in the gas phase and a polar and aprotic solution tetrahydrofuran (THF) was undertaken. Calculated results show that the silanol forms CH3Si(＝X)OH are much more stable than the silanone forms CH3Si(＝O)XH in the gas-phase, which is different from the monochalcogenocarboxylic acids, where the keto forms CH3C(＝O)XH are dominant. This situation may be attributed to the fact that the Si＝O and O＝H single bonds in the silanol forms are stronger than the Si＝X and X＝H single bonds in the silanone forms, respectively, even though the Si＝X (X D S, Se, and Te) double bonds are much weaker than the Si＝O double bondE These results indicate that the stability of the monochalcogenosilanoic acid tautomers is not determined by the double bond energies, contrary to the earlier explanation based on the incorrect assumption that the Si＝S double bond is stronger than the S＝O double bond for the tautomeric equilibrium of RSi(＝O)SH (R＝H, F, Cl, CH3, OH, NH2) to shift towards the thione forms [RSi(＝S)OH]. The binding with CH3OCH3 enhances the preference of the silanol form in the tautomeric equilibrium, and meanwhile significantly lowers the tautomeric barriers by more than 34 kJ/mol in THF solution.0
O2(b1∑+g) relaxation in active medium of oxygen-iodine laser

NASA Astrophysics Data System (ADS)

Tolstov, G. I.; Zagidullin, M. V.; Khvatov, N. A.; Medvedkov, I. A.; Mikheyev, P. A.

2018-04-01

Rate constants for the removal of O2 b1∑+g by collisions with O2, N2, CO2 and H2O have been determined at temperature 297 K. O2(b1 ∑+g) was excited by pulses from a tunable dye laser, and the deactivation kinetics were followed by observing the temporal behavior of the b1∑+g - X3∑-g fluorescence. The removal rate constants for CO2, N2 and H2O were not strongly dependent on temperature, and could be represented by the expressions kCO2=(1.8+/-0.05)×10-16 kN2=(2.2 +/- 0.2)×10-15, and kH2O=(6.12+/-0.67)×10-12 cm3 molecule-1 s-1. Rate constant for O2(b1∑+ ) removal by O2(X), being orders of magnitude lower, represented by the fitted expression kO2=(3.67 +/- 0.06)×10-17 cm3 molecule-1 s-1. All of the rate constants measured at room temperature were found to be in good agreement with previously reported values.
Influence of asymmetric magnetic perturbation on the nonlinear evolution of double tearing modes

NASA Astrophysics Data System (ADS)

Xiong, G. Z.; Wang, L.; Li, X. Q.; Liu, H. F.; Tang, C. J.; Huang, J.; Zhang, X.; Wang, X. Q.

2017-06-01

The effects of asymmetric magnetic perturbation on the triggering and evolution of double tearing modes (DTMs) are investigated using nonlinear magnetohydrodynamics simulations in a slab geometry. We find that for reversed magnetic shear plasmas the resistive reconnection process induced by the initial perturbation at one rational surface can drive a new island at the other rational surface with the same mode number. The four typical states of the mode for the time evolution are found, and include: (i) a linear growth stage; (ii) a linear/nonlinear stable stage; (iii) an interactively driving stage; and (iv) a symmetric DTM stage. These differ from previous simulation results. Moreover, nonlinear DTM growth is found to strongly depend on the asymmetric magnetic perturbation, particularly in the early nonlinear phase. The initial perturbation strength scale of island width suggests that the left island enters into a Sweet-Parker growth process when the right island is sufficiently large to effectively drive the other. These results predict that although externally applied magnetic perturbations can suppress the neoclassical tearing mode they can also trigger new instabilities such as asymmetric DTMs.
First-Principles Calculations of Lattice Dynamics in La_2CuO_4

NASA Astrophysics Data System (ADS)

Wang, C.-Z.; Yu, Rici; Krakauer, Henry

1998-03-01

To investigate wavevector-dependent lattice vibrational properties of the high-temperature cuprate superconductor La_2-xSr_xCuO_4, we have performed first principles calculations for tetragonal I4/mmm La_2CuO_4, using the linear response LAPW method(R. Yu and H. Krakauer, Phys. Rev. B 49), 4467 (1994). Phonon frequencies and polarization vectors are obtained throughout the Brillouin zone. Generally good agreement is obtained with experiment, but we underestimate the frequencies of the low lying modes, which involve either motions of the apical oxygen atoms parallel to the CuO2 planes or motions of the plane O atoms along the c-axis. The discrepancy may be due to anharmonic coupling of these modes(R. Cohen, W. Pickett, and H. Krakauer, Phys. Rev. Lett. 62), 831 (1989)^,(D. J. Singh, Solid State Commun. 98), 575 (1996). The X point tilt phonon mode is found to be the most unstable mode, consistent with previous frozen phonon calculations^3 and the observed phase transition to the orthorhombic structure at low temperature. The results will be discussed in comparison with previous calculations^3,4 and experiment.
Microwave Absorption Properties of La0.8Ca0.2-xAgxMnO3 (x=0.05; x=0.15) Synthesized by Sol-Gel Method

NASA Astrophysics Data System (ADS)

Kurniawan, B.; Laksmi, W.; Sahara, N. A.

2018-04-01

Microwave absorption properties of La0.8Ca0.2-xAgxMnO3 (x= 0.05; 0.15) is reported in this paper. Lanthanum manganite materials was reported as a potential absorber material [1][2][3]. In this paper, the material was synthesized by sol-gel method, calcined at 550°C, and sintered at 900°C. The material was characterized by X-Ray Diffractometer (XRD), and we found that the materials were single phased. Through SEM-EDS characterization it is found that the materials have compositional purity. The resistivity of the materials is obtained by four point probe method, and it is shown that Ag doped decreases the resistivity of the materials. Reflection loss of La0.8Ca0.15Ag0.05MnO3 reaches -4.470 dB and La0.8Ca0.05Ag0.15MnO3 reaches - 7.953 dB.
Room-Temperature Quantum Cascade Laser: ZnO/Zn1- x Mg x O Versus GaN/Al x Ga1- x N

NASA Astrophysics Data System (ADS)

Chou, Hung Chi; Mazady, Anas; Zeller, John; Manzur, Tariq; Anwar, Mehdi

2013-05-01

A ZnO/Zn1- x Mg x O-based quantum cascade laser (QCL) is proposed as a candidate for generation of THz radiation at room temperature. The structural and material properties, field dependence of the THz lasing frequency, and generated power are reported for a resonant phonon ZnO/Zn0.95Mg0.05O QCL emitting at 5.27 THz. The theoretical results are compared with those from GaN/Al x Ga1- x N QCLs of similar geometry. Higher calculated optical output powers [ {P}_{{ZnMgO}} = 2.89 mW (nonpolar) at 5.27 THz and 2.75 mW (polar) at 4.93 THz] are obtained with the ZnO/Zn0.95Mg0.05O structure as compared with GaN/Al0.05Ga0.95N QCLs [ {P}_{{AlGaN}} = 2.37 mW (nonpolar) at 4.67 THz and 2.29 mW (polar) at 4.52 THz]. Furthermore, a higher wall-plug efficiency (WPE) is obtained for ZnO/ZnMgO QCLs [24.61% (nonpolar) and 23.12% (polar)] when compared with GaN/AlGaN structures [14.11% (nonpolar) and 13.87% (polar)]. These results show that ZnO/ZnMgO material is optimally suited for THz QCLs.
Hybridized orbital states in spin-orbit coupled 3 d -5 d double perovskites studied by x-ray absorption spectroscopy

NASA Astrophysics Data System (ADS)

Lee, Min-Cheol; Lee, Sanghyun; Won, C. J.; Lee, K. D.; Hur, N.; Chen, Jeng-Lung; Cho, Deok-Yong; Noh, T. W.

2018-03-01

We investigated the orbital hybridization mechanism in 3 d -5 d double perovskites (DPs) of La2CoIrO6 and La2CoPtO6 using x-ray absorption spectroscopy. It is clearly evidenced by O K -edge and Co K -edge x-ray absorption spectra that the Co 3 d orbitals hybridize not only with the half-filled Ir/Pt jeff states but also with the fully empty (unpolarized) Ir/Pt eg states in both DPs. The Co 3 d eg-Ir 5 d eg hybridization cannot contribute to the ferrimagnetic long-range order in La2CoIrO6 established by spin-selective Co 3 d t2 g-Ir 5 d jeff hybridization through the intermediate oxygen p state but could serve as an origin of paramagnetism. The strengths of such orbital hybridizations were found to be almost invariant to temperature, even far above the Curie temperature, implying persistent paramagnetism against the antiferromagnetic ordering in the spin-orbit entangled 3 d -5 d DPs.
Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Asakura, Daisuke; Hosono, Eiji; Nanba, Yusuke

2016-03-07

Here, we evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathodematerials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi 0.5Mn 1.5O 4, the line shape of the Mn L 3-edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L 3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathodematerials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are usefulmore » enough for the Ni L edge which is far from the O K edge.« less
Alloy composition effects on oxidation products of VIA, B-1900, 713C, and 738X: A high temperature diffractometer study

NASA Technical Reports Server (NTRS)

Garlick, R. G.; Lowell, C.

1973-01-01

High temperature X-ray diffraction studies were performed to investigate isothermal and cyclic oxidation at 1000 and 1100 C of the nickel-base superalloys VIA, B-1900, 713C, and 738X. Oxidation was complex. The major oxides, Al2O3, Cr2O3, and the spinels, formed in amounts consistent with alloy chemistry. The alloys VIA and B-1900 (high Al, low Cr alloys) tended to form Al2O3 and NiAl2O4; 738X (high Cr, low Al) formed Cr2O3 and NiCr2O4. A NiTa2O6 type of oxide formed in amounts approximately proportional to the refractory metal content of the alloy. One of the effects of cycling was to increase the amount of spinels formed.
X-24B with Test Pilot Lt. Col. Michael V. Love

NASA Technical Reports Server (NTRS)

1976-01-01

glide flight was on April 17, 1969, with Air Force Maj. Jerauld Gentry at the controls. Gentry also piloted its first powered flight on March 19, 1970. The X-24A was flown 28 times in the program that, like the HL-10, validated the concept that a Space Shuttle vehicle could be landed unpowered. The fastest speed achieved by the X-24A was 1,036 miles per hour (mph--Mach 1.6). Its maximum altitude was 71,400 feet. It was powered by an XLR-11 rocket engine with a maximum theoretical vacuum thrust of 8,480 pounds. The X-24A was later modified into the X-24B. The bulbous shape of the X-24A was converted into a 'flying flatiron' shape with a rounded top, flat bottom, and double delta platform that ended in a pointed nose. The X-24B demonstrated that accurate unpowered reentry vehicle landings were operationally feasible. Top speed achieved by the X-24B was 1,164 mph and the highest altitude it reached was 74,130 feet. The vehicle is on display at the Air Force Museum, Wright-Patterson Air Force Base, Ohio. The pilot on the last powered flight of the X-24B was Bill Dana, who also flew the last X-15 flight about seven years earlier. The X-24A shape was later borrowed for the X-38 Crew Return Vehicle (CRV) technology demonstrator for the International Space Station. The X-24B is on public display at the Air Force Museum, Wright-Patterson AFB, Ohio.
OPTICAL AND SPECTROSCOPIC STUDIES OF Fe2O3-Bi2O3-B2O3:V2O5 GLASSES

NASA Astrophysics Data System (ADS)

Sanjay; Kishore, N.; Agarwal, A.; Dahiya, S.; Pal, Inder; Kumar, Navin

2013-11-01

The glasses of compositions xFe2O3ṡ (40 - x)Bi2O3ṡ60B2O3ṡ2V2O5 have been prepared by the standard melt-quenching technique. Amorphous nature of these samples is ascertained by XRD patterns. The presence of BO3 and BO4 units is identified by IR spectra of glass samples. The absorption edge (λcut-off) shifts toward longer wavelengths with an increase in Fe2O3 content in the glass matrix. The values of optical band gap energy for indirect allowed and forbidden transitions have been determined and it is found to decrease with increase in transition metal ions. The Urbach's energy is used to characterize the degree of disorder in amorphous solids.

Electronic structure of α-SrB4O7: experiment and theory

NASA Astrophysics Data System (ADS)

Atuchin, V. V.; Kesler, V. G.; Zaitsev, A. I.; Molokeev, M. S.; Aleksandrovsky, A. S.; Kuzubov, A. A.; Ignatova, N. Y.

2013-02-01

The investigation of valence band structure and electronic parameters of constituent element core levels of α-SrB4O7 has been carried out with x-ray photoemission spectroscopy. Optical-quality crystal α-SrB4O7 has been grown by the Czochralski method. Detailed photoemission spectra of the element core levels have been recorded from the powder sample under excitation by nonmonochromatic Al Kα radiation (1486.6 eV). The band structure of α-SrB4O7 has been calculated by ab initio methods and compared to XPS measurements. It has been found that the band structure of α-SrB4O7 is weakly dependent on the Sr-related states.
Thermal characteristics, Raman spectra, optical and structural properties of TiO2-Bi2O3-B2O3-TeO2 glasses

NASA Astrophysics Data System (ADS)

Gupta, Nupur; Khanna, Atul; Gonzàlez, Fernando; Iordanova, Reni

2017-05-01

Tellurite and borotellurite glasses containing Bi2O3 and TiO2 were prepared and structure-property correlations were carried out by density measurements, X-ray Diffraction (XRD), Differential Scanning Calorimetry (DSC), Raman and UV-visible spectroscopy. Titanium tellurite glasses require high melt-cooling rates and were fabricated by splat quenching. On adding B2O3, the glass forming ability (GFA) enhances, and glasses could be synthesized at lower quenching rates. The density of glasses shows a direct correlation with molecular mass of the constituents. UV-visible studies were used to determine the optical band gap and refractive index. Raman studies found that the co-ordination number of tellurium ions with oxygen (NTe-O) decreases with the increase in B2O3 as well as Bi2O3 content while, TiO2 produce only a small decrease in NTe-O, which explains the lower GFA of titanium tellurite glasses that do not contain Bi2O3 and B2O3. DSC studies show that the glass transition temperature (Tg) increases with B2O3 and TiO2 concentrations and that Tg correlates well with bond enthalpy of the metal oxides.
Atomistic study on the site preference and lattice vibration of Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} (T=Al and Ge)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Hai-Xia; Wang, Xiao-Xu; Department of Materials Engineering, National Ping Tung University of Technology and Science, Ping-Tung 91201, Taiwan

The effects of the Y substitution for Gd on the structural stability and the site preference of intermetallics Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} (T=Al and Ge) are studied by using a series of interatomic pair potentials. The calculated results show Y can stabilize Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} with the tetragonal structure, and Y substitute for Gd with a strong preference for the 2b sites. The calculated lattice parameters are in good agreement with the experimental data. Furthermore, the total and partial phonon densities of states are evaluated for the Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} compounds withmore » the tetragonal structure. A qualitative analysis is carried out with the relevant potentials for the vibrational modes, which makes it possible to predict some properties related to lattice vibration. - Graphical abstract: The lattice cell of Gd{sub 3}Co{sub 29}T{sub 4}B{sub 10} consists of 92 atoms, or two Gd{sub 3}Co{sub 29}T{sub 4}B{sub 10} formula units, with fourteen distinct kinds of site. Rare-earth atoms occupy 2b and 4d sites, Co atoms occupy the Co1(2c), Co2(8i1), Co3(8i2), Co4(8i3), Co5(8j1), Co6(8j2) and Co7(16k), T atoms occupy the T(8i) sites, and B atoms occupy the B1(2c1), B2(2c2), B3(8i) and B4(8j) sites. - Highlights: • The application of the pair potentials obtained from lattice-inversion method. • The lattice vibrations for Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} (T=Ge and Al) are first evaluated. • The Y atoms should prefer the 2b site of Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} compounds. • The total and partial phonon densities of states are evaluated for the Gd{sub 3−x}Y{sub x}Co{sub 29}T{sub 4}B{sub 10} compounds with the tetragonal structure. • A qualitative analysis is carried out with the relevant potentials for the vibrational modes.« less
Inflation, symmetry, and B-modes

DOE PAGES

Hertzberg, Mark P.

2015-04-20

Here, we examine the role of using symmetry and effective field theory in inflationary model building. We describe the standard formulation of starting with an approximate shift symmetry for a scalar field, and then introducing corrections systematically in order to maintain control over the inflationary potential. We find that this leads to models in good agreement with recent data. On the other hand, there are attempts in the literature to deviate from this paradigm by envoking other symmetries and corrections. In particular: in a suite of recent papers, several authors have made the claim that standard Einstein gravity with amore » cosmological constant and a massless scalar carries conformal symmetry. They claim this conformal symmetry is hidden when the action is written in the Einstein frame, and so has not been fully appreciated in the literature. They further claim that such a theory carries another hidden symmetry; a global SO(1,1) symmetry. By deforming around the global SO(1,1) symmetry, they are able to produce a range of inflationary models with asymptotically flat potentials, whose flatness is claimed to be protected by these symmetries. These models tend to give rise to B-modes with small amplitude. Here we explain that standard Einstein gravity does not in fact possess conformal symmetry. Instead these authors are merely introducing a redundancy into the description, not an actual conformal symmetry. Furthermore, we explain that the only real (global) symmetry in these models is not at all hidden, but is completely manifest when expressed in the Einstein frame; it is in fact the shift symmetry of a scalar field. When analyzed systematically as an effective field theory, deformations do not generally produce asymptotically flat potentials and small B-modes as suggested in these recent papers. Instead, deforming around the shift symmetry systematically, tends to produce models of inflation with B-modes of appreciable amplitude. Such simple models
Hydrothermal synthesis and structural analysis of new mixed oxyanion borates: Ba11B26O44(PO4)2(OH)6, Li9BaB15O27(CO3) and Ba3Si2B6O16

NASA Astrophysics Data System (ADS)

Heyward, Carla; McMillen, Colin D.; Kolis, Joseph

2013-07-01

Several new borate compounds, Ba11B26O44(PO4)2(OH)6 (1), Li9BaB15O27(CO3) (2), and Ba3Si2B6O16 (3) were synthesized containing other hetero-oxyanion building blocks in addition to the borate frameworks. They were all prepared under hydrothermal conditions and characterized by single crystal and powder X-ray diffraction, and IR spectroscopy. Crystal data: For 1; space group P21/c, a=6.8909 (14) Å, b=13.629 (3) Å, c=25.851 (5) Å, β=90.04 (3)°; For 2; space group P-31c, a=8.8599 (13) Å, c=15.148 (3) Å; For 3; space group P-1, a=5.0414 (10) Å, b=7.5602 (15) Å, c=8.5374 (17) Å, α=77.15 (3)°, β=77.84 (3)°, γ=87.41 (3)° for 3. Compounds 1 and 2 contain isolated oxyanions [PO4]3- and [CO3]2- respectively, sitting in channels created by the borate framework, while structure 3 has the [SiO4]4- groups directly bonded to the borate groups creating a B-O-Si framework.
B-mode Ultrasound Versus Color Doppler Twinkling Artifact in Detecting Kidney Stones

PubMed Central

Harper, Jonathan D.; Hsi, Ryan S.; Shah, Anup R.; Dighe, Manjiri K.; Carter, Stephen J.; Moshiri, Mariam; Paun, Marla; Lu, Wei; Bailey, Michael R.

2013-01-01

Abstract Purpose To compare color Doppler twinkling artifact and B-mode ultrasonography in detecting kidney stones. Patients and Methods Nine patients with recent CT scans prospectively underwent B-mode and twinkling artifact color Doppler ultrasonography on a commercial ultrasound machine. Video segments of the upper pole, interpolar area, and lower pole were created, randomized, and independently reviewed by three radiologists. Receiver operator characteristics were determined. Results There were 32 stones in 18 kidneys with a mean stone size of 8.9±7.5 mm. B-mode ultrasonography had 71% sensitivity, 48% specificity, 52% positive predictive value, and 68% negative predictive value, while twinkling artifact Doppler ultrasonography had 56% sensitivity, 74% specificity, 62% positive predictive value, and 68% negative predictive value. Conclusions When used alone, B-mode is more sensitive, but twinkling artifact is more specific in detecting kidney stones. This information may help users employ twinkling and B-mode to identify stones and developers to improve signal processing to harness the fundamental acoustic differences to ultimately improve stone detection. PMID:23067207
Double MITs and magnetoresistance: an intrinsic feature of Ru substituted La(0.67)Ca(0.33)MnO(3).

PubMed

Seetha Lakshmi, L; Sridharan, V; Sukumar, A A; Kamruddin, M; Sastry, V S; Raju, V S

2006-05-03

In this paper, we examine the possible influence of extrinsic factors on the electrical and magnetotransport of La(0.67)Ca(0.33)Mn(1-x)Ru(x)O(3) (x≤0.10). Ru substitution results in double metal-insulator transitions (MITs) at T(MI1) and T(MI2), both exhibiting magnetoresistance (MR). No additional magnetic signal corresponding to a second low-temperature maximum (LTM) at T(MI2) could be observed, either in ac susceptibility (χ(')) or in specific heat (C(p)). Typical grain sizes of ∼18 000-20 000 nm, as estimated from the scanning electron microscope (SEM) micrographs, are not so small as to warrant an LTM. The absence of additional peaks in the high statistics powder x-ray diffraction (XRD), a linear systematic increase of the unit cell parameters, close matching of the transition temperatures in resistivity, χ(') and C(p) and their linear systematic decrease with x, and an homogeneous distribution of Mn, Ru and O at arbitrarily selected regions within and across the grains exclude chemical inhomogeneity in the samples. The insensitivity of grain boundary MR at 5 K to Ru composition indicates that the grain boundary is not altered to result in an LTM. Oxygen stoichiometry of all the compounds is close to the nominal value of 3. These results not only exclude the extrinsic factors, but also establish that double MITs, both exhibiting MR, are intrinsic to Ru substituted La(0.67)Ca(0.33)MnO(3).
Electronic Warfare Systems Career Ladder, AFSC 456X1A/B.

DTIC Science & Technology

1991-04-01

En .. 𔃾- (AS L o t.. 4 - 0 L. 0 IXtC SL U41 .004- -C . W a 3 2 ) P- C XL x1. C4’ X O b .4 -J L. 0...2 Im 1m 1 AL/HRD/ID 1 1M lm/lh1 ARMY OCCUPATIONAL SURVEY BRANCH 1 CCAF/AYX 1 DEFENSE TECHNICAL INFORMATION CENTER 2 DE1 3 , USAFOMS (KEESLER AFB MS) 1...1 i HQ AFISC/DAP 2 HQ AFLC/DPMAE 3 HQ AFSC/DPAL 3 3 HQ AFSC/TTA 1 1 HQ ATC/DPAE 3 3 HQ ATC/TTOA 2 1 HQ ESC/DPTE 3 3 HQ ESC/TTA 1 1 HQ MAC/DPAT 3 3
Synthesis of layered perovskite oxides, ACa[sub 2-x]La[sub x]Nb[sub 3-x]Ti[sub x]O[sub 10] (A = K, Rb, Cs), and characterization of new solid acids, HCa[sub 2-x]La[sub x]Nb[sub 3-x]Ti[sub x]O[sub 10] (O < x [le] 2), exhibiting variable Bronsted acidity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gopalakrishnan, J.; Uma, S.; Bhat, V.

1993-01-01

Layered perovskite oxides of the formula ACa[sub 2-x]La[sub x]Nb[sub 3-x]Ti[sub x]O[sub 10] (A = K, Rb, Cs and 0 , x [le] 2) have been prepared. The members adopt the structures of the parent ACa[sub 2]Nb[sub 3]O[sub 10]. Interlayer alkali cations in the niobium-titanium oxide series can be ion-exchanged with Li[sup +], Na[sup +], NG[sub 4][sup +], of H[sup +] to give new derivatives. Intercalation of the protonated derivatives with organic bases reveals that the Bronsted acidity of the solid solution series, HCa[sub 2-x]La[sub x]Nb[sub 3-x]Ti[sub x]O[sub 10], depends on the titanium content. While the x = 1 member (HCaLaNb[submore » 2]TiO[sub 10]) is nearly as acidic as the parent HCa[sub 2]Nb[sub 3]O[sub 10], the x = 2 member (HLA[sub 2]NbTi[sub 2]O[sub 10]) is a weak acid hardly intercalating organic bases with pK[sub a] [approximately] 11.3. The variation of acidity is probably due to an ordering of Nb/Ti atoms in the triple octahedral perovskite slabs, [Ca[sub 2-x]La[sub x]Nb[sub 3-x]Ti[sub x]O[sub 10
MOF-derived hierarchical double-shelled NiO/ZnO hollow spheres for high-performance supercapacitors.

PubMed

Li, Guo-Chang; Liu, Peng-Fei; Liu, Rui; Liu, Minmin; Tao, Kai; Zhu, Shuai-Ru; Wu, Meng-Ke; Yi, Fei-Yan; Han, Lei

2016-09-14

Nanorods-composed yolk-shell bimetallic-organic frameworks microspheres are successfully synthesized by a one-step solvothermal method in the absence of any template or surfactant. Furthermore, hierarchical double-shelled NiO/ZnO hollow spheres are obtained by calcination of the bimetallic organic frameworks in air. The NiO/ZnO hollow spheres, as supercapacitor electrodes, exhibit high capacitance of 497 F g(-1) at the current density of 1.3 A g(-1) and present a superior cycling stability. The superior electrochemical performance is believed to come from the unique double-shelled NiO/ZnO hollow structures, which offer free space to accommodate the volume change during the ion insertion and desertion processes, as well as provide rich electroactive sites for the electrochemical reactions.
Mechanical and thermal properties of SrO/BaO modified Y2O3-Al2O3-B2O3-SiO2 glasses and their compatibility with solid oxide fuel cell components

NASA Astrophysics Data System (ADS)

Kaur, Navdeep; Kaur, Gurbinder; Kumar, Devender; Singh, K.

2018-07-01

In this study, various compositions of (30-x) SrO-xBaO-10Al2O3-45SiO2-5B2O3-10Y2O3 (mol%) (5 ≤ x ≤ 25) were synthesized using the melt-quench technique. The as-prepared glasses were characterized by X-ray diffraction, micro-hardness testing, dilatometry, and scanning electron microscopy to determine their thermal and mechanical properties. Powders of the glasses were used to make diffusion couples with Crofer 22 APU (interconnect) and yttria stabilized zirconia (YSZ) for the interfacial study. Diffusion couples of the pre-oxidized Crofer 22 APU/glasses and YSZ/glasses were tested for 500 h at 850 °C. The coefficients of thermal expansion obtained for all the glasses were in the required range for applications in solid oxide fuel cells. The highest hardness and fracture toughness were obtained for the glass with x = 10 mol% due to the mixed modifier effect. However, the glass with x = 15 mol% exhibited better adhesion with YSZ and Crofer 22 APU.
Study of the $${X^\\pm(5568)}$$ state with semileptonic decays of the $${B_s^0}$$ meson

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abazov, Victor Mukhamedovich; et al.

2017-12-29

We present a study of themore » $$X^\\pm(5568)$$ using semileptonic decays of the $$B_s^0$$ meson using the full Run II integrated luminosity of 10.4 fb$$^{-1}$$ in proton-antiproton collisions at a center of mass energy of 1.96\\,TeV collected with the D0 detector at the Fermilab Tevatron Collider. We report evidence for a narrow structure, $$X^\\pm(5568)$$, in the decay sequence $$X^\\pm(5568) \\to B_s^0 \\pi^\\pm$$ where $$B_s^0 \\rightarrow \\mu^\\mp D_s^\\pm \\, \\mathrm{X}$$, $$D_s^\\pm \\rightarrow \\phi \\pi^{\\pm}$$ which is consistent with the previous measurement by the D0 collaboration in the hadronic decay mode, $$X^\\pm(5568) \\to B^0_s \\pi^\\pm$$ where $$B^0_s \\to J/\\psi\\phi$$. The mass and width of this state are measured using a combined fit of the hadronic and semileptonic data, yielding $$m = 5566.9 ^{+3.2}_{-3.1} \\thinspace {\\rm (stat)} ^{+0.6}_{-1.2} {\\rm \\thinspace (syst)}$$\\,MeV/$c^2$, $$\\Gamma = 18.6 ^{+7.9}_{-6.1} {\\rm \\thinspace (stat)} ^{+3.5}_{-3.8} {\\rm \\thinspace (syst)} $$\\,MeV/$c^2$ with a significance of 6.7$$\\,\\sigma$$.« less
Spectroscopic properties of Er(3+)/Yb(3+) co-doped Bi(2)O(3)-B(2)O(3)-GeO(2) glasses.

PubMed

Zhang, Xudong; Xu, Tiefeng; Nie, Qiuhua; Dai, Shixun; Shen, Xiang; Zhang, Xianghua

2007-05-01

Er(3+)/Yb(3+) co-doped 60Bi(2)O(3)-(40 - x)B(2)O(3)-xGeO(2) (BBG; x=0, 5, 10, 15 mol%) glasses that are suitable for fiber lasers, amplifiers have been fabricated and characterized. The absorption spectra, emission spectra, and lifetime of the (4)I(13/2) level and quantum efficiency of Er(3+):(4)I(13/2) --> (4)I(15/2) transition were measured and calculated. With the substitution of GeO(2) for B(2)O(3), both Delta lambda(eff) and sigma(e) decrease from 75 to 71 nm and 9.88 to 8.12 x 10(-21) cm(2), respectively. The measured lifetime of the (4)I(13/2) level and quantum efficiency of Er(3+):(4)I(13/2) --> (4)I(15/2) transition increase from 1.18 to 1.5 ms and 36.2% to 43.2%, respectively. The emission spectra of Er(3+):(4)I(13/2) --> (4)I(15/2) transition was also analyzed using a peak-fit routine, and an equivalent four-level system was proposed to estimate the stark splitting for the (4)I(15/2) and (4)I(13/2) levels of Er(3+) in the BBG glasses. The results indicate that the (4)I(13/2) --> (4)I(15/2) emission of Er(3+) can be exhibit a considerable broadening due to a significant enhance the peak A, and D emission.
Modifying a numerical algorithm for solving the matrix equation X + AX T B = C

NASA Astrophysics Data System (ADS)

Vorontsov, Yu. O.

2013-06-01

Certain modifications are proposed for a numerical algorithm solving the matrix equation X + AX T B = C. By keeping the intermediate results in storage and repeatedly using them, it is possible to reduce the total complexity of the algorithm from O( n 4) to O( n 3) arithmetic operations.
Long-range ordering in the Bi 1-xAe xFeO 3-x/2 perovskites: Bi 1/3Sr 2/3FeO 2.67 and Bi 1/2Ca 1/2FeO 2.75

NASA Astrophysics Data System (ADS)

Lepoittevin, C.; Malo, S.; Barrier, N.; Nguyen, N.; Van Tendeloo, G.; Hervieu, M.

2008-10-01

Two-ordered perovskites, Bi 1/3Sr 2/3FeO 2.67 and Bi 1/2Ca 1/2FeO 2.75, have been stabilized and characterized by transmission electron microscopy, Mössbauer spectroscopy and X-ray powder diffraction techniques. They both exhibit orthorhombic superstructures, one with a≈ b≈2 ap and c≈3 ap (S.G.: Pb2 n or Pbmn) for the Sr-based compound and one with a≈ b≈2 ap and c≈8 ap (S.G.: B222, Bmm2, B2 mm or Bmmm) for the Ca-based one. The high-resolution transmission electron microscopy (HRTEM) images evidence the existence of one deficient [FeO x] ∞ layer, suggesting that Bi 1/3Sr 2/3FeO 2.67 and Bi 1/2Ca 1/2FeO 2.75 behave differently compared to their Ln-based homolog. The HAADF-STEM images allow to propose a model of cation ordering on the A sites of the perovskite. The Mössbauer analyses confirm the trivalent state of iron and its complex environment with three types of coordination. Both compounds exhibit a high value of resistivity and the inverse molar susceptibility versus temperature curves evidence a magnetic transition at about 730 K for the Bi 1/3Sr 2/3FeO 2.67 and a smooth reversible transition between 590 and 650 K for Bi 1/2Ca 1/2FeO 2.75.
Survival of the most transferable at the top of Jacob's ladder: Defining and testing the ωB97M(2) double hybrid density functional

NASA Astrophysics Data System (ADS)

Mardirossian, Narbe; Head-Gordon, Martin

2018-06-01

A meta-generalized gradient approximation, range-separated double hybrid (DH) density functional with VV10 non-local correlation is presented. The final 14-parameter functional form is determined by screening trillions of candidate fits through a combination of best subset selection, forward stepwise selection, and random sample consensus (RANSAC) outlier detection. The MGCDB84 database of 4986 data points is employed in this work, containing a training set of 870 data points, a validation set of 2964 data points, and a test set of 1152 data points. Following an xDH approach, orbitals from the ωB97M-V density functional are used to compute the second-order perturbation theory correction. The resulting functional, ωB97M(2), is benchmarked against a variety of leading double hybrid density functionals, including B2PLYP-D3(BJ), B2GPPLYP-D3(BJ), ωB97X-2(TQZ), XYG3, PTPSS-D3(0), XYGJ-OS, DSD-PBEP86-D3(BJ), and DSD-PBEPBE-D3(BJ). Encouragingly, the overall performance of ωB97M(2) on nearly 5000 data points clearly surpasses that of all of the tested density functionals. As a Rung 5 density functional, ωB97M(2) completes our family of combinatorially optimized functionals, complementing B97M-V on Rung 3, and ωB97X-V and ωB97M-V on Rung 4. The results suggest that ωB97M(2) has the potential to serve as a powerful predictive tool for accurate and efficient electronic structure calculations of main-group chemistry.
La 3+ doping of the Sr 2CoWO 6 double perovskite: A structural and magnetic study

NASA Astrophysics Data System (ADS)

López, C. A.; Viola, M. C.; Pedregosa, J. C.; Carbonio, R. E.; Sánchez, R. D.; Fernández-Díaz, M. T.

2008-11-01

La-doped Sr 2CoWO 6 double perovskites have been prepared in air in polycrystalline form by solid-state reaction. These materials have been studied by X-ray powder diffraction (XRPD), neutron powder diffraction (NPD) and magnetic susceptibility. The structural refinement was performed from combined XRPD and NPD data (D2B instrument, λ=1.594 Å). At room temperature, the replacement of Sr 2+ by La 3+ induces a change of the tetragonal structure, space group I4/ m of the undoped Sr 2CoWO 6 into the distorted monoclinic crystal structure, space group P2 1/ n, Z=2. The structure of La-doped phases contains alternating CoO 6 and (Co/W)O 6 octahedra, almost fully ordered. On the other hand, the replacement of Sr 2+ by La 3+ induces a partial replacement of W 6+ by Co 2+ into the B sites, i.e. Sr 2-xLa xCoW 1-yCo yO 6 ( y= x/4) with segregation of SrWO 4. Magnetic and neutron diffraction measurements indicate an antiferromagnetic ordering below TN=24 K independently of the La-substitution.
Flux Pinning Enhancement in YBa2Cu3O7-x Films for Coated Conductor Applications (Postprint)

DTIC Science & Technology

2010-01-01

YBa2Cu3O7–x Films for Coated Conductor Applications Maiorov , B. , Civale , L. , Lin , Y. , Hawley , M.E. , Maley , M.P. , and Peterson , D.E...L. , Maiorov , B. , Hawley , M.E. , Maley , M.P. , and Peterson , D.E. ( 2004 ) Nat. Mater. , 3 , 439 . 30 Kang , S. , Goyal...1864 . 47 Civale , L. , Maiorov , B. , Serquis , A. , Willis , J.O. , Coulter , J.Y. , Wang , H. , Jia , Q.X. , Arendt , P.N
Synthesis, structural and optical properties of (ALa)(FeMn)O6 (A = Ba and Sr) double perovskites

NASA Astrophysics Data System (ADS)

Kumar, Dinesh; Sudarshan, V.; Singh, Akhilesh Kumar

2018-05-01

Here, we report structural and optical properties of ALaFeMnO6 (A = Ba and Sr) double perovskite synthesized via auto-combustion followed by calcinations process. Rietveld refinement of structure using x-ray diffraction data reveals that BaLaFeMnO6 crystallizes into cubic crystal structure with space group Pm-3m while SrLaFeMnO6 crystallizes into rhombohedral crystal structure having space group R-3c. The absorption spectrum measurement using UV-Vis spectroscopy reveals that these samples are prefect insulator having energy band gap between conduction and valence band of the order of 6 eV.
DNA double-strand breaks and Aurora B mislocalization induced by exposure of early mitotic cells to H2O2 appear to increase chromatin bridges and resultant cytokinesis failure.

PubMed

Cho, Min-Guk; Ahn, Ju-Hyun; Choi, Hee-Song; Lee, Jae-Ho

2017-07-01

Aneuploidy, an abnormal number of chromosomes that is a hallmark of cancer cells, can arise from tetraploid/binucleated cells through a failure of cytokinesis. Reactive oxygen species (ROS) have been implicated in various diseases, including cancer. However, the nature and role of ROS in cytokinesis progression and related mechanisms has not been clearly elucidated. Here, using time-lapse analysis of asynchronously growing cells and immunocytochemical analyses of synchronized cells, we found that hydrogen peroxide (H 2 O 2 ) treatment at early mitosis (primarily prometaphase) significantly induced cytokinesis failure. Cytokinesis failure and the resultant formation of binucleated cells containing nucleoplasmic bridges (NPBs) seemed to be caused by increases in DNA double-strand breaks (DSBs) and subsequent unresolved chromatin bridges. We further found that H 2 O 2 induced mislocalization of Aurora B during mitosis. All of these effects were attenuated by pretreatment with N-acetyl-L-cysteine (NAC) or overexpression of Catalase. Surprisingly, the PARP inhibitor PJ34 also reduced H 2 O 2 -induced Aurora B mislocalization and binucleated cell formation. Results of parallel experiments with etoposide, a topoisomerase IIα inhibitor that triggers DNA DSBs, suggested that both DNA DSBs and Aurora B mislocalization contribute to chromatin bridge formation. Aurora B mislocalization also appeared to weaken the "abscission checkpoint". Finally, we showed that KRAS-induced binucleated cell formation appeared to be also H 2 O 2 -dependent. In conclusion, we propose that a ROS, mainly H 2 O 2 increases binucleation through unresolved chromatin bridges caused by DNA damage and mislocalization of Aurora B, the latter of which appears to augment the effect of DNA damage on chromatin bridge formation. Copyright © 2017 Elsevier Inc. All rights reserved.

Comparison of light and x-ray sensitometric responses of double-emulsion films for different processing conditions.

PubMed

Blendl, C; Buhr, E

2001-12-01

The effects of different film processing conditions on light and x-ray sensitometric responses were compared for a variety of double-emulsion x-ray films. The processing conditions were altered by changes of the developer temperature. Three different exposure variants were applied: x-ray sensitometry using two stepped neutral density attenuators between film and screens, simultaneous double-sided light sensitometry, and single-sided light sensitometry. 13 different types of double-emulsion x-ray films were investigated, among them three asymmetric films. In the special case of exposing the asymmetric films with the single-sided light sensitometer, a method was investigated where each side of the film is exposed at different locations and the sum effect is analyzed. From each sensitometric curve shape two parameters, the logarithmic speed (logS) and the average gradient (G), were evaluated. The results of this study can be summarized as follows: (1) Single-sided and double-sided light sensitometers revealed almost equal changes of logS when the processing conditions are altered. Thus, single-sided light sensitometers can serve as a substitute for double-sided light sensitometers provided that suited exposure methods are used and appropriate sensitometric parameters are evaluated. (2) Light sensitometry quantitatively indicated changes of the film processing that affect the x-ray speed. Hence, light sensitometry is a useful method to monitor changes in film processing.
The double peaks and symmetric path phenomena in the catalytic activity of Pd/Al2O3-TiO2 catalysts with different TiO2 contents

NASA Astrophysics Data System (ADS)

Zhang, Shen; Guo, Yuyu; Li, Xingying; Wu, Xu; Li, Zhe

2018-06-01

Physicochemical properties of Pd/Al2O3-TiO2 catalysts with different amounts of TiO2 contents were investigated by XRD, nitrogen adsorption-desorption, FTIR, NH3-TPD, H2-TPR and XPS techniques. Catalysts of different compositions were tested in the ethanol oxidation reaction to study the effects of TiO2 contents. Double peaks and symmetric path phenomena were observed at certain temperatures with the increase in TiO2 contents. The symmetric peak phenomena and the diverse activity fluctuations have been ascribed to the controlling factors such as temperature and compositions. With the increase in TiO2 content, the surface area, adsorbed oxygen contents and surface acid quantity decreased gradually. The large surface area and adsorbed oxygen contents were conducive to the performance, while increased acid amounts were not beneficial for ethanol oxidation. At 150 and 175 °C, Pd/AT(X1
Intermittent bursts induced by double tearing mode reconnection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wei, Lai; Wang, Zheng-Xiong, E-mail: zxwang@dlut.edu.cn

Reversed magnetic shear (RMS) configuration is assumed to be the steady-state operation scenario for the future advanced tokamaks like International Thermonuclear Experimental Reactor. In this work, we numerically discover a phenomenon of violent intermittent bursts induced by self-organized double tearing mode (DTM) reconnection in the RMS configuration during the very long evolution, which may continuously lead to annular sawtooth crashes and thus badly impact the desired steady-state operation of the future advanced RMS tokamaks. The key process of the intermittent bursts in the off-axis region is similar to that of the typical sawtooth relaxation oscillation in the positive magnetic shearmore » configuration. It is interestingly found that in the decay phase of the DTM reconnection, the zonal field significantly counteracts equilibrium field to make the magnetic shear between the two rational surfaces so weak that the residual self-generated vortices of the previous DTM burst are able to trigger a reverse DTM reconnection by curling the field lines.« less
Intermittent bursts induced by double tearing mode reconnection

NASA Astrophysics Data System (ADS)

Wei, Lai; Wang, Zheng-Xiong

2014-06-01

Reversed magnetic shear (RMS) configuration is assumed to be the steady-state operation scenario for the future advanced tokamaks like International Thermonuclear Experimental Reactor. In this work, we numerically discover a phenomenon of violent intermittent bursts induced by self-organized double tearing mode (DTM) reconnection in the RMS configuration during the very long evolution, which may continuously lead to annular sawtooth crashes and thus badly impact the desired steady-state operation of the future advanced RMS tokamaks. The key process of the intermittent bursts in the off-axis region is similar to that of the typical sawtooth relaxation oscillation in the positive magnetic shear configuration. It is interestingly found that in the decay phase of the DTM reconnection, the zonal field significantly counteracts equilibrium field to make the magnetic shear between the two rational surfaces so weak that the residual self-generated vortices of the previous DTM burst are able to trigger a reverse DTM reconnection by curling the field lines.
Quenched crystal-field disorder and magnetic liquid ground states in Tb 2 Sn 2 - x Ti x O 7 [Crystal field disorder in the quantum spin ice ground state of Tb2Sn2-xTixO7

DOE PAGES

Gaulin, B. D.; Kermarrec, E.; Dahlberg, M. L.; ...

2015-06-01

Solid-solutions of the "soft" quantum spin ice pyrochlore magnets Tb 2B 2O 7 with B=Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac-susceptibility and muSR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb 3+ crystal field levels appropriate to at high B-site mixing (0.5 < x < 1.5 in Tb 2Sn 2-xTi xO 7) reveal that the doublet ground andmore » first excited states present as continua in energy, while transitions to singlet excited states at higher energies simply interpolate between those of the end members of the solid solution. The resulting ground state suggests an extreme version of a random-anisotropy magnet, with many local moments and anisotropies, depending on the precise local configuration of the six B sites neighboring each magnetic Tb 3+ ion.« less
Bismuth-induced Raman modes in GaP 1– xBi x

DOE PAGES

Christian, Theresa M.; Fluegel, Brian; Beaton, Daniel A.; ...

2016-09-02

Here, dilute bismide semiconductor alloys are a promising material platform for optoelectronic devices due to drastic impacts of bismuth on the electronic structure of the alloy. At the same time, the details of bismuth incorporation in the lattice are not fully understood. In this work, we conduct Raman scattering spectroscopy on GaP 1- xBi x epilayers grown by molecular beam epitaxy (MBE) and identify several bismuth-related Raman features including gap vibration modes at 296, 303, and 314 cm -1. This study paves the way for more detailed analysis of the local symmetry at bismuth incorporation sites in the dilute bismidemore » alloy regime.« less
Structure and Cancer Immunotherapy of the B7 Family Member B7x

PubMed Central

Jeon, Hyungjun; Vigdorovich, Vladimir; Garrett-Thomson, Sarah C.; Janakiram, Murali; Ramagopal, Udupi A.; Abadi, Yael M.; Lee, Jun Sik; Scandiuzzi, Lisa; Ohaegbulam, Kim C; Chinai, Jordan M; Zhao, Ruihua; Yao, Yu; Mao, Ying; Sparano, Joseph A.; Almo, Steven C.; Zang, Xingxing

2014-01-01

SUMMARY B7x (B7-H4 or B7S1) is a member of the B7 family that can inhibit T cell function. B7x protein is absent in most normal human tissues and immune cells, but is overexpressed in human cancers and often correlates with negative clinical outcome. The expression pattern and function of B7x suggest that it may be a potent immunosuppressive pathway in human cancers. Here we determined the crystal structure of human B7x IgV domain at 1.59Å resolution and mapped the epitopes recognized by monoclonal antibodies. We developed a new in vivo system to screen therapeutic monoclonal antibodies against B7x, and found that the clone 1H3 significantly inhibited growth of B7x-expressing tumor in vivo via multiple mechanisms. Furthermore, the surviving mice given 1H3 treatment were resistant to tumor re-challenge. Our data suggest that targeting B7x on tumors is a promising cancer immunotherapy and humanized 1H3 may be efficacious for immunotherapy of human cancers. PMID:25437562
Double axis, two-crystal x-ray spectrometer.

PubMed

Erez, G; Kimhi, D; Livnat, A

1978-05-01

A two-crystal double axis x-ray spectrometer, capable of goniometric accuracy on the order of 0.1", has been developed. Some of its unique design features are presented. These include (1) a modified commercial thrust bearing which furnishes a precise, full circle theta:2theta coupling, (2) a new tangent drive system design in which a considerable reduction of the lead screw effective pitch is achieved, and (3) an automatic step scanning control which eliminates most of the mechanical deficiencies of the tangent drive by directly reading the tangent arm displacement.
Retrieving clear-air turbulence information from regular commercial aircraft using Mode-S and ADS-B broadcast

NASA Astrophysics Data System (ADS)

Kopeć, J. M.; Kwiatkowski, K.; de Haan, S.; Malinowski, S. P.

2015-11-01

Navigational information broadcast by commercial aircraft in the form of Mode-S and ADS-B messages can be considered a new and valid source of upper air turbulence measurements. A set of three processing methods is proposed and analysed using a quality record of turbulence encounters made by a research aircraft. The proposed methods are based on processing the vertical acceleration or the background wind into the eddy dissipation rate. All the necessary parameters are conveyed in the Mode-S/ADS-B messages. The comparison of the results of application of the processing against a reference eddy dissipation rate obtained using on-board accelerometer indicate a significant potential of those methods. The advantages and limitation of the presented approaches are discussed.
Floating Double Deck Pier Fenders

DTIC Science & Technology

2011-07-01

Center FDDP Floating Double Deck Pier FEM Finite Element Model MHP Modular Hybrid Pier NAVFAC Naval Facilities RDT&E Research, Development, Testing...4. FEM Performance of MV1000x900B Elements ........................................................ 14 Figure 4-5. Biaxial UE1200x1200E3.1 Fender...Deflection .......................................................... 15 Figure 4-6. FEM Performance of Biaxial UE Fender
Phase relations in the pseudo ternary system In2O3-TiO2-BO (B: Zn, Co and Ni) at 1200 °C in air

NASA Astrophysics Data System (ADS)

Brown, Francisco; Jacobo-Herrera, Ivan Edmundo; Alvarez-Montaño, Victor Emmanuel; Kimizuka, Noboru; Hirano, Tomonosuke; Sekine, Ryotaro; Denholme, Saleem J.; Miyakawa, Nobuaki; Kudo, Akihiko; Iwase, Akihide; Michiue, Yuichi

2018-02-01

Phase relations in the pseudo ternary systems In2O3-TiO2-ZnO, In2O3-TiO2-CoO and In2O3-TiO2-NiO at 1200 °C in air were determined by means of a classic quenching method. In6Ti6BO22 (B: Zn, Co and Ni) which has the monoclinic In(Fe1/4Ti3/4)O27/8-type of structure with a 4-dimensional super space group exists in a stable form. There exist homologous phases In1+x(Ti1/2Zn1/2)1-xO3(ZnO)m (m: natural number, 0<x ≤ 1) having the InGaO3(ZnO)m-type of the layered crystal structures such as In1+x(Ti1/2Zn1/2)1-xO3(ZnO) (0.12 ≤ x ≤ 0.29), In1+x(Ti1/2Zn1/2)1-x(ZnO)2 (0.12 ≤ x ≤ 0.50), In1+x(Ti1/2Zn1/2)1-xO3(ZnO)3 (0.15 ≤ x ≤ 0.84), In1+x(Ti1/2Zn1/2)1-x(ZnO)4 (0.15 ≤ x ≤ 1), In1+x(Ti1/2Zn1/2)1-xO3(ZnO)5 (0.15 ≤ x ≤ 1), In1+x(Ti1/2Zn1/2)1-x(ZnO)6 (0.15 ≤ x ≤ 1), In1+x(Ti1/2Zn1/2)1-xO3(ZnO)7 (0.15 ≤ x ≤ 1), In1+x(Ti1/2Zn1/2)1-x(ZnO)8 (?<x ≤ 1), In1+x(Ti1/2Zn1/2)1-xO3(ZnO)9 (0.15 ≤ x ≤ 1), In1+x(Ti1/2Zn1/2)1-x(ZnO)10 (?<x ≤ 1), and In1+x(Ti1/2Zn1/2)1-xO3(ZnO)11 (0.15 ≤ x ≤ 1)… without an upper limit of m in the pseudo ternary system In2O3-TiO2-ZnO. All the ions are on the trigonal lattice points, the In(III) is in the octahedral coordination with the oxygen and the {Inx(Ti1/2Zn1/2)1-xZnm} is in the trigonalbipyramidal coordination with oxygen in the crystal structures of each homologous compound. They have R 3 bar m (No. 166) for m = odd or P63/mmc (No. 194) for m = even in space group. Lattice constants for each of the homologous compounds as a hexagonal setting and In6Ti6BO22 as the monoclinic system were determined by means of the powder X-ray diffraction method at room temperature. The temperature dependence of resistivity for In1+x(Ti1/2Zn1/2)1-x(ZnO)4 (0.15 ≤ x ≤ 1) showed semiconducting-like behavior for all samples examined at T(K) = 2-300. The resistivity increased systematically with decreasing x (0.7 ≤ x ≤ 1), and it was found that samples where x ≤ 0.7 became insulators. The optical band gap Eg (eV) of In1+x(Ti1/2Zn
Temperature Dependence of O2(b1Σ ^+g, v = 0 and 1) Relative Yield in O(1D) + O2 Energy Transfer

NASA Astrophysics Data System (ADS)

Kostko, O.; Raj, S.; Campbell, K.; Pejakovic, D. A.; Kalogerakis, K.

2011-12-01

Energy transfer from excited O(1D) atoms to ground-state O2(X3Σ ^-g) leads to production of O2 in the first two vibrational levels of the O2 (b1Σ ^+g) state: O(1D) + O2 -> O(3P) + O2(b1Σ ^+g, v = 0, 1). Subsequent radiative decay of O2(b1Σ ^+g, v = 0, 1) to the ground state results in the Atmospheric Band emission, a prominent feature of the terrestrial airglow. The relative yield for production of O2(b1Σ ^+g, v = 0 and 1) in the above process, k1/k0, is an important parameter in modeling of the observed Atmospheric Band emission intensities. Recent measurements at room temperature have shown that production of O2(b1Σ ^+g, v = 1) dominates that of O2(b1Σ ^+g, v = 0), with k1/k0 having a value of approximately 3.5 [1]. In the laboratory experiments, the output of a pulsed fluorine laser at 157 nm is used to photodissociate molecular oxygen in an O2/N2 mixture flowing through a heated gas cell. Photodissociation of O2 produces a ground-state O(3P) atom and an excited O(1D) atom. O(1D) rapidly transfers energy to the remaining O2 to produce O2(b1Σ ^+g, v = 0, 1). The populations of O2(b1Σ ^+g, v = 0 and 1) are monitored by observing emissions in the O2(b--X) 0--0 and 1--0 bands at 762 and 688 nm, respectively. The value of k1/k0 is extracted from the time-dependent O2(b1Σ ^+g, v = 0 and 1) fluorescence signals using computer simulations. We will present measurements on the temperature dependence of k1/k0 and discuss their atmospheric significance. This work was supported by the US National Science Foundation (NSF) Aeronomy Program under grant AGS-0937317. The fluorine laser was purchased under grant ATM-0216583 from the NSF Major Research Instrumentation Program. S. Raj and K. M. Campbell participated in a Research Experiences for Undergraduates (REU) site, co-funded by the Division of Physics of the NSF and the Department of Defense in partnership with the NSF REU program under grant PHY-1002892. [1] K. S. Kalogerakis, D. A. Pejaković, R. A. Copeland, T. G
Elasticity, shear-mode softening and high-pressure polymorphism of wüstite (Fe1-xO)

NASA Astrophysics Data System (ADS)

Jackson, Ian; Khanna, S. K.; Revcolevschi, A.; Berthon, J.

1990-12-01

Elastic wave travel times have been determined as functions of hydrostatic pressure to 3 GPa for five modes of propagation in synthetic single-crystal wüstite Feo.943O by ultrasonic phase comparison. The measured travel times, corrected for transducer-bond phase shifts, constrain very accurately the zero-pressure elastic moduli (GPa) and, for the first time, their first pressure derivatives (dimensionless) as follows: C11∶218.4, dC11/dP∶9.65, C12∶123.0, dC12/dP∶2.77, C44∶45.5, dC44/dP∶-1.03. The zero-pressure moduli are in good agreement with the results of previous determinations by ultrasonic wave propagation but not with all of the moduli determined by resonance techniques. The variation of bulk modulus with pressure calculated from the Cij (P) is extrapolated to much higher pressures via third-order Eulerian isotherms and isentropes based on K0S = 154.9 GPa and (dKs/dP)0T = 4.90. The resulting isothermal and shock compression curves satisfactorily reproduce the experimental data to ˜70 GPa, thereby providing a unified description of essentially all data bearing on the compressibility of wüstite. At higher pressures, published shock compression studies provide clear evidence for the existence of a different phase of much greater density and incompressibility. Metallic values of electrical conductivity have been reported for pressures >70 GPa under conditions of shock and high-temperature static loading. Polyhedral face-sharing in either the B8(NiAs) or B2(CsCl) (or derivative) structures would result in shorter Fe-Fe distances, allowing greater 3d orbital overlap conducive to metallic conductivity. However, none of these possibilities satisfactorily accounts for the large inferred increase (14-20%) in zero-pressure density unless the Fe-O distance is also reduced by 3-5% by electron delocalization or spin-pairing. The marked violation of the Cauchy condition associated with the very low value of C44 and its unusual temperature and pressure
Electric field dependent local structure of (KxNa1-x) 0.5B i0.5Ti O3

NASA Astrophysics Data System (ADS)

Goetzee-Barral, A. J.; Usher, T.-M.; Stevenson, T. J.; Jones, J. L.; Levin, I.; Brown, A. P.; Bell, A. J.

2017-07-01

The in situ x-ray pair-distribution function (PDF) characterization technique has been used to study the behavior of (KxNa1-x) 0.5B i0.5Ti O3 , as a function of electric field. As opposed to conventional x-ray Bragg diffraction techniques, PDF is sensitive to local atomic displacements, detecting local structural changes at the angstrom to nanometer scale. Several field-dependent ordering mechanisms can be observed in x =0.15 , 0.18 and at the morphotropic phase boundary composition x =0.20 . X-ray total scattering shows suppression of diffuse scattering with increasing electric-field amplitude, indicative of an increase in structural ordering. Analysis of PDF peaks in the 3-4-Å range shows ordering of Bi-Ti distances parallel to the applied electric field, illustrated by peak amplitude redistribution parallel and perpendicular to the electric-field vector. A transition from <110 > to <112 > -type off-center displacements of Bi relative to the neighboring Ti atoms is observable with increasing x . Analysis of PDF peak shift with electric field shows the effects of Bi-Ti redistribution and onset of piezoelectric lattice strain. The combination of these field-induced ordering mechanisms is consistent with local redistribution of Bi-Ti distances associated with domain reorientation and an overall increase in order of atomic displacements.
Electrical conduction mechanism of LaNi{sub x}Me{sub 1−x}O{sub 3−δ} (Me = Fe, Mn)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Niwa, Eiki, E-mail: e-niwa@phys.chs.nihon-u.ac.jp; Department of Integrated Sciences in Physics and Biology, College of Humanities and Sciences, Nihon University, Setagaya-ku, Tokyo 156-8550; Maeda, Hiroki

Graphical abstract: Compositional dependence of (a) electrical conductivity and (b) E{sub a} for hopping conduction of LaNi{sub x}Me{sub 1−x}O{sub 3} (Me = Fe, Mn). - Highlights: • Electrical conduction mechanism of LaNi{sub x}Me{sub 1−x}O{sub 3} (Me = Fe, Mn) was investigated. • Hopping conduction model could be applied for conductivity of both specimens. • The difference of E{sub a} due to that of energy level of Fe and Mn was observed. • Hole concentration estimated by iodimetry increases with increasing Ni content. - Abstract: Electrical conduction mechanism of LaNi{sub x}Fe{sub 1−x}O{sub 3−δ} and LaNi{sub x}Mn{sub 1−x}O{sub 3+δ} expected as Sr-freemore » new cathode material for solid oxide fuel cells was analyzed. Electrical conduction behaviors of both specimens could be well fitted by small polaron hopping conduction model. The electrical conductivity of LaNi{sub x}Fe{sub 1−x}O{sub 3−δ} increased with increasing Ni content, showing agreement with decrease of activation energy for hopping conduction. The decrease of electrical conductivity and increase of activation energy of LaNi{sub x}Mn{sub 1−x}O{sub 3+δ} were observed with increasing Ni content for 0.0 ≤ x ≤ 0.4. Further Ni substitution increased electrical conductivity and decreased activation energy for 0.4 ≤ x ≤ 0.6. It was revealed using iodometry that the difference of hole carrier density between LaNi{sub x}Fe{sub 1−x}O{sub 3−δ} and LaNi{sub x}Mn{sub 1−x}O{sub 3+δ} was small. It was suspected that the origin of the difference of electrical conduction behavior of LaNi{sub x}Fe{sub 1−x}O{sub 3−δ} and LaNi{sub x}Mn{sub 1-x}O{sub 3+δ} was difference of energy level of e{sub g} band composed of Fe 3d or Mn 3d orbitals and their overlapping quantity with O 2p and Ni 3d band.« less
Specific heat of new perovskite-type cobaltates Pr{sub 1-x}Nd{sub x}CoO{sub 3}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thakur, Rasna, E-mail: rasnarishu@gmail.com; Thakur, Rajesh K.; Gaur, N. K.

2016-05-23

Specific heat and Bulk modulus (B) of new perovskite-type cobaltates Pr{sub 1-x}Nd{sub x}CoO{sub 3} has been studied by means of a Modified Rigid Ion Model (MRIM) and Atoms in Molecules (AIM) theory in a wide temperature range (1 K ≤ T ≤1000 K). The effect of Nd doping on the elastic, cohesive and thermal properties of PrCoO{sub 3} have been studied probably for the first time by an atomistic approach. The computed results are in good agreement with the available experimental data.
O2(b1Σg+) Quenching by O2, CO2, H2O, and N2 at Temperatures of 300-800 K.

PubMed

Zagidullin, M V; Khvatov, N A; Medvedkov, I A; Tolstov, G I; Mebel, A M; Heaven, M C; Azyazov, V N

2017-10-05

Rate constants for the removal of O 2 (b 1 Σ g + ) by collisions with O 2 , N 2 , CO 2 , and H 2 O have been determined over the temperature range from 297 to 800 K. O 2 (b 1 Σ g + ) was excited by pulses from a tunable dye laser, and the deactivation kinetics were followed by observing the temporal behavior of the b 1 Σ g + -X 3 Σ g - fluorescence. The removal rate constants for CO 2 , N 2 , and H 2 O were not strongly dependent on temperature and could be represented by the expressions k CO2 = (1.18 ± 0.05) × 10 -17 × T 1.5 × exp[Formula: see text], k N2 = (8 ± 0.3) × 10 -20 × T 1.5 × exp[Formula: see text], and k H2O = (1.27 ± 0.08) × 10 -16 × T 1.5 × exp[Formula: see text] cm 3 molecule -1 s -1 . Rate constants for O 2 (b 1 Σ g + ) removal by O 2 (X), being orders of magnitude lower, demonstrated a sharp increase with temperature, represented by the fitted expression k O2 = (7.4 ± 0.8) × 10 -17 × T 0.5 × exp[Formula: see text] cm 3 molecule -1 s -1 . All of the rate constants measured at room temperature were found to be in good agreement with previously reported values.
Spin-split fermi surfaces in CexLa1-xB6 and PrxLa1-xB6

NASA Astrophysics Data System (ADS)

Isshiki, T.; Endo, M.; Sugi, M.; Kimura, N.; Nakamura, S.; Nojima, T.; Aoki, H.; Kunii, S.

2006-05-01

We have performed the dHvA measurements on CexLa1-xB6 and PrxLa1-xB6 compounds to study spin splitting of the Fermi surfaces. In PrB 6 we have found new frequency branches to confirm that the Fermi surface splits into up and down spin Fermi surfaces, whereas no spin splitting has been found for x=0.25,0.5,0.75. We have also found several new frequency branches in CeB6. The new frequency branches imply that the Fermi surfaces of up and down spin conduction electrons are significantly different in CeB6 as well as in PrB6.
Microwave absorption enhancement, magnetic coupling and ab initio electronic structure of monodispersed (Mn1-xCox)3O4 nanoparticles

NASA Astrophysics Data System (ADS)

Zhao, Pengfei; Liang, Chongyun; Gong, Xiwen; Gao, Ran; Liu, Jiwei; Wang, Min; Che, Renchao

2013-08-01

Monodispersed manganese oxide (Mn1-xCox)3O4 (0 <= x <= 0.5) nanoparticles, less than 10 nm size, are respectively synthesized via a facile thermolysis method at a rather low temperature, ranging from 90 to 100 °C, without any inertia gas for protection. The influences of the Co dopant content on the critical reaction temperature required for the nanoparticle formation, electronic band structures, magnetic properties, and the microwave absorption capability of (Mn1-xCox)3O4 are comprehensively investigated by means of both experimental and theoretical approaches including powder X-ray diffraction (XRD), electron energy loss spectroscopy (EELS), super conductivity quantum interference device (SQUID) examination, and first-principle simulations. Co is successfully doped into the Mn atomic sites of the (Mn1-xCox)3O4 lattice, which is further confirmed by EELS data acquired from one individual nanoparticle. Therefore, continuous solid solutions of well-crystallized (Mn1-xCox)3O4 products are achieved without any impurity phase or phase separation. With increases in the Co dopant concentration x from 0 to 0.5, the lattice parameters change systemically, where the overall saturation magnetization at 30 K increases due to the more intense coupling of the 3d electrons between Mn and Co, as revealed by simulations. The microwave absorption properties of the (Mn1-xCox)3O4 nanoparticles are examined between 2 and 18 GHz. The maximum absorption peak -11.0 dB of the x = 0 sample is enhanced to -11.5 dB for x = 0.2, -12.7 dB for x = 0.25, -15.6 dB for x = 0.33, and -24.0 dB for x = 0.5 respectively, suggesting the Co doping effects. Our results might provide novel insights into the understanding of the influences of metallic ion doping on the electromagnetic properties of metallic oxide nanomaterials.Monodispersed manganese oxide (Mn1-xCox)3O4 (0 <= x <= 0.5) nanoparticles, less than 10 nm size, are respectively synthesized via a facile thermolysis method at a rather low
Prediction of radial breathing-like modes of double-walled carbon nanotubes with arbitrary chirality

NASA Astrophysics Data System (ADS)

Ghavanloo, Esmaeal; Fazelzadeh, S. Ahmad

2014-10-01

The radial breathing-like modes (RBLMs) of double-walled carbon nanotubes (DWCNTs) with arbitrary chirality are investigated by a simple analytical model. For this purpose, DWCNT is considered as double concentric elastic thin cylindrical shells, which are coupled through van der Waals (vdW) forces between two adjacent tubes. Lennard-Jones potential and a molecular mechanics model are used to calculate the vdW forces and to predict the mechanical properties, respectively. The validity of these theoretical results is confirmed through the comparison of the experimental results. Finally, a new approach is proposed to determine the diameters and the chiral indices of the inner and outer tubes of the DWCNTs with high precision.

Synthesis, growth and characterization of ZnO microtubes using a traveling-wave mode microwave system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Naser, Qusay A.H.; Zhou, Jian, E-mail: jianzhou@whut.edu.cn; Wang, Han

Highlights: • ZnO microtubes were successfully synthesized within 15 min. • Introducing a design of a traveling-wave mode microwave system. • Growth temperature of ZnO microtubes becomes predominant between 1350 °C and 1400 °C. • ZnO microtube showed a strong ultraviolet and a weak and broad green emission. • ZnO microtube is composed only of ZnO with high crystallinity. - Abstract: Field emission scanning electron microscopy (FESEM) investigation reveals that zinc oxide (ZnO) microtubes have been successfully synthesized via a traveling-wave mode microwave system. These products are hexagonal tubular crystals with an average diameter of 60 μm and 250 μmmore » in length, having a well faceted end and side surfaces. The wall thickness of the ZnO tubes is about 3–5 μm. The influence of reaction temperature on the formation of crystalline ZnO hexagonal tubes is studied. Room temperature photoluminescence (PL) spectra have also been examined to explore the optical property which exhibits strong ultraviolet emission at 377.422 nm and a weak and broad green emission band at 587.548 nm. X-ray diffraction (XRD) and energy dispersive spectrometer (EDS) show that the product is composed only of ZnO with high crystallinity. The presented synthesis method possesses several advantages, which would be significant to the deeper study and wide applications of ZnO tubes in the future.« less
Evaluation of Freehand B-Mode and Power-Mode 3D Ultrasound for Visualisation and Grading of Internal Carotid Artery Stenosis.

PubMed

Pelz, Johann Otto; Weinreich, Anna; Karlas, Thomas; Saur, Dorothee

2017-01-01

Currently, colour-coded duplex sonography (2D-CDS) is clinical standard for detection and grading of internal carotid artery stenosis (ICAS). However, unlike angiographic imaging modalities, 2D-CDS assesses ICAS by its hemodynamic effects rather than luminal changes. Aim of this study was to evaluate freehand 3D ultrasound (3DUS) for direct visualisation and quantification of ICAS. Thirty-seven patients with 43 ICAS were examined with 2D-CDS as reference standard and with freehand B-mode respectively power-mode 3DUS. Stenotic value of 3D reconstructed ICAS was calculated as distal diameter respectively distal cross-sectional area (CSA) reduction percentage and compared with 2D-CDS. There was a trend but no significant difference in successful 3D reconstruction of ICAS between B-mode and power mode (examiner 1 {Ex1} 81% versus 93%, examiner 2 {Ex2} 84% versus 88%). Inter-rater agreement was best for power-mode 3DUS and assessment of stenotic value as distal CSA reduction percentage (intraclass correlation coefficient {ICC} 0.90) followed by power-mode 3DUS and distal diameter reduction percentage (ICC 0.81). Inter-rater agreement was poor for B-mode 3DUS (ICC, distal CSA reduction 0.36, distal diameter reduction 0.51). Intra-rater agreement for power-mode 3DUS was good for both measuring methods (ICC, distal CSA reduction 0.88 {Ex1} and 0.78 {Ex2}; ICC, distal diameter reduction 0.83 {Ex1} and 0.76 {Ex2}). In comparison to 2D-CDS inter-method agreement was good and clearly better for power-mode 3DUS (ICC, distal diameter reduction percentage: Ex1 0.85, Ex2 0.78; distal CSA reduction percentage: Ex1 0.63, Ex2 0.57) than for B-mode 3DUS (ICC, distal diameter reduction percentage: Ex1 0.40, Ex2 0.52; distal CSA reduction percentage: Ex1 0.15, Ex2 0.51). Non-invasive power-mode 3DUS is superior to B-mode 3DUS for imaging and quantification of ICAS. Thereby, further studies are warranted which should now compare power-mode 3DUS with the angiographic gold standard imaging
Influence of Content of Al2O3 on Structure and Properties of Nanocomposite Nb-B-Al-O films

NASA Astrophysics Data System (ADS)

Liu, Na; Dong, Lei; Dong, Lei; Yu, Jiangang; Pan, Yupeng; Wan, Rongxin; Gu, Hanqing; Li, Dejun

2015-11-01

Nb-B-Al-O nanocomposite films with different power of Al2O3 were successfully deposited on the Si substrate via multi-target magnetron co-sputtering method. The influences of Al2O3's content on structure and properties of obtained nanocomposite films through controlling Al2O3's power were investigated. Increasing the power of Al2O3 can influence the bombarding energy and cause the momentum transfer of NbB2. This can lead to the decreasing content of Al2O3. Furthermore, the whole films showed monocrystalline NbB2's (100) phase, and Al2O3 shaded from amorphous to weak cubic-crystalline when decreasing content of Al2O3. This structure and content changes were proof by X-ray diffraction (XRD) and high-resolution transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). When NbB2 grains were far from each other in lower power of Al2O3, the whole films showed a typical nanocomposite microstructure with crystalline NbB2 grains embedded in a matrix of an amorphous Al2O3 phase. Continuing increasing the power of Al2O3, the less content of Al2O3 tended to cause crystalline of cubic-Al2O3 between the close distances of different crystalline NbB2 grains. The appearance of cubic-crystallization Al2O3 can help to raise the nanocomposite films' mechanical properties to some extent. The maximum hardness and elastic modulus were up to 21.60 and 332.78 GPa, which were higher than the NbB2 and amorphous Al2O3 monolithic films. Furthermore, this structure change made the chemistry bond of O atom change from the existence of O-Nb, O-B, and O-Al bonds to single O-Al bond and increased the specific value of Al and O. It also influenced the hardness in higher temperature, which made the hardness variation of different Al2O3 content reduced. These results revealed that it can enhance the films' oxidation resistance properties and keep the mechanical properties at high temperature. The study highlighted the importance of controlling the Al2O3's content to prepare
Enhancement of tetragonal anisotropy and stabilisation of the tetragonal phase by Bi/Mn-double-doping in BaTiO3 ferroelectric ceramics

PubMed Central

Yabuta, Hisato; Tanaka, Hidenori; Furuta, Tatsuo; Watanabe, Takayuki; Kubota, Makoto; Matsuda, Takanori; Ifuku, Toshihiro; Yoneda, Yasuhiro

2017-01-01

To stabilise ferroelectric-tetragonal phase of BaTiO3, the double-doping of Bi and Mn up to 0.5 mol% was studied. Upon increasing the Bi content in BaTiO3:Mn:Bi, the tetragonal crystal-lattice-constants a and c shrank and elongated, respectively, resulting in an enhancement of tetragonal anisotropy, and the temperature-range of the ferroelectric tetragonal phase expanded. X-ray absorption fine structure measurements confirmed that Bi and Mn were located at the A(Ba)-site and B(Ti)-site, respectively, and Bi was markedly displaced from the centrosymmetric position in the BiO12 cluster. This A-site substitution of Bi also caused fluctuations of B-site atoms. Magnetic susceptibility measurements revealed a change in the Mn valence from +4 to +3 upon addition of the same molar amount of Bi as Mn, probably resulting from a compensating behaviour of the Mn at Ti4+ sites for donor doping of Bi3+ into the Ba2+ site. Because addition of La3+ instead of Bi3+ showed neither the enhancement of the tetragonal anisotropy nor the stabilisation of the tetragonal phase, these phenomena in BaTiO3:Mn:Bi were not caused by the Jahn-Teller effect of Mn3+ in the MnO6 octahedron, but caused by the Bi-displacement, probably resulting from the effect of the 6 s lone-pair electrons in Bi3+. PMID:28367973
Investigation of gamma ray shielding, structural and dissolution rate properties of Bi2O3-BaO-B2O3-Na2O glass system

NASA Astrophysics Data System (ADS)

Dogra, Mridula; Singh, K. J.; Kaur, Kulwinder; Anand, Vikas; Kaur, Parminder; Singh, Prabhjot; Bajwa, B. S.

2018-03-01

In the present study, quaternary system of the composition (0.45 + x) Bi2O3-(0.25 - x) BaO-0.15 B2O3-0.15 Na2O (where 0 ≤ x ≤ 0.2 mol fraction) has been prepared by using melt-quenching technique for investigation of gamma ray shielding properties. Mass attenuation coefficients and half value layer parameters have been determined experimentally at 662 keV by using 137Cs source. It has been found that experimental results of these parameters hold good agreement with theoretical values. The density, molar volume, XRD, FTIR, Raman and UV-visible studies have been used to determine structural properties of the prepared glass samples. Dissolution rate of the samples has also been measured to check their utility as long term durable glasses.
Determination of intrinsic mode and linear mode coupling in solar microwave bursts

NASA Astrophysics Data System (ADS)

Huang, Guangli; Song, Qiwu; Li, Jianping

2013-05-01

in another FP was always smaller than 90∘ where the mode coupling did not happen. Moreover, the right-circular sense at 17 GHz was always observed in both two FPs during the event, which supports that the transition frequency should be larger than 17 GHz in the first FP together with strong magnetic field of over 2000 Gauses in photosphere, where the weakly coupled case should happen. Moreover, there are two possibilities of the intrinsic mode in the two FPs due to the 180-degree ambiguity. (1) The emission of extraordinary (X) mode from the first FP turns to the ordinary (O) mode in the two time intervals of the maximum phase, while, the X-mode is always emitted from the second FP. (2) The inversion from O-mode to X-mode takes place in the first FP, while the O-mode keeps in the second FP. If the magnetic polarities in photosphere and corona are coincident in this event, the intrinsic mode belongs to the second case.
Pseudo Jahn-Teller coupling in trioxides XO3(0,1,-1) with 22 and 23 valence electrons

NASA Astrophysics Data System (ADS)

Grein, Friedrich

2013-05-01

D3h and C2v geometries and energies, vertical excitation energies, as well as minimal energy paths as function of the O1(z)-X-O2 angle α were obtained for XO3(0,1,-1) (X = B, Al, Ga; C, Si, Ge; N, P, As; S, Se) molecules and ions with 22 and 23 valence electrons (VE), using density functional theory (DFT), coupled cluster with single and double substitutions with noniterative triple excitations (CCSD(T)), equation of motion (EOM)-CCSD, time-dependent DFT, and multi-reference configuration interaction methods. It is shown that pseudo Jahn-Teller (PJT) coupling increases as the central atom X becomes heavier, due to decreases in excitation energies. As is well known for CO3, the excited 1E' states of the 22 VE systems SiO3, GeO3; NO_3 ^ +, PO3+, AsO3+; BO3-, AlO3-, GaO3- have strong vibronic coupling with the 1A1' ground state via the e' vibrational modes, leading to a C2v minimum around α = 145°. For first and second row X atoms, there is an additional D3h minimum (α = 120°). Interacting excited states have minima around 135°. In the 23 VE systems CO3-, SiO3-; NO3, PO3; SO3+, coupling of the excited 2E' with the 2A2' ground state via the e' mode does not generate a C2v state. Minima of interacting excited states are close to 120°. However, due to very strong PJT coupling, a double-well potential is predicted for GeO3-, AsO3, and SeO3+, with a saddle point at D3h symmetry. Interaction of the b2 highest occupied molecular orbital with the b2 lowest unoccupied molecular orbital, both oxygen lone pair molecular orbitals, is seen as the reason for the C2v stabilization of 22 VE molecules.
Crystal structures of K2[XSi5O12] (X = Fe2+, Co, Zn) and Rb2[XSi5O12] (X = Mn) leucites: comparison of monoclinic P21/c and Ia{\\overline 3}d polymorph structures and inverse relationship between tetrahedral cation (T = Si and X)-O bond distances and intertetrahedral T-O-T angles.

PubMed

Bell, Anthony M T; Henderson, C Michael B

2018-06-01

The leucite tectosilicate mineral analogues K 2 X 2+ Si 5 O 12 (X = Fe 2+ , Co, Zn) and Rb 2 X 2+ Si 5 O 12 (X = Mn) have been synthesized at elevated temperatures both dry at atmospheric pressure and at controlled water vapour pressure; for X = Co and Zn both dry and hydrothermally synthesized samples are available. Rietveld refinement of X-ray data for hydrothermal K 2 X 2+ Si 5 O 12 (X = Fe 2+ , Co, Zn) samples shows that they crystallize in the monoclinic space group P2 1 /c and have tetrahedral cations (Si and X) ordered onto distinct framework sites [cf. hydrothermal K 2 MgSi 5 O 12 ; Bell et al. (1994a), Acta Cryst. B50, 560-566]. Dry-synthesized K 2 X 2+ Si 5 O 12 (X = Co, Zn) and Rb 2 X 2+ Si 5 O 12 (X = Mn) samples crystallize in the cubic space group Ia{\\overline 3}d and with Si and X cations disordered in the tetrahedral framework sites as typified by dry K 2 MgSi 5 O 12 . Both structure types have tetrahedrally coordinated SiO 4 and XO 4 sharing corners to form a partially substituted silicate framework. Extraframework K + and Rb + cations occupy large channels in the framework. Structural data for the ordered samples show that mean tetrahedral Si-O and X-O bond lengths cover the ranges 1.60 Å (Si-O) to 2.24 Å (Fe 2+ -O) and show an inverse relationship with the intertetrahedral angles (T-O-T) which range from 144.7° (Si-O-Si) to 124.6° (Si-O-Fe 2+ ). For the compositions with both disordered and ordered tetrahedral cation structures (K 2 MgSi 5 O 12 , K 2 CoSi 5 O 12 , K 2 ZnSi 5 O 12 , Rb 2 MnSi 5 O 12 and Cs 2 CuSi 5 O 12 leucites) the disordered polymorphs always have larger unit-cell volumes, larger intertetrahedral T-O-T angles and smaller mean T-O distances than their isochemical ordered polymorphs. The ordered samples clearly have more flexible frameworks than the disordered structures which allow the former to undergo a greater degree of tetrahedral collapse around the interframework cavity cations. Multivariant linear regression has
Crystal growth, crystal structure of new polymorphic modification, β-Bi 2B 8O 15 and thermal expansion of α-Bi 2B 8O 15

NASA Astrophysics Data System (ADS)

Bubnova, R. S.; Alexandrova, J. V.; Krivovichev, S. V.; Filatov, S. K.; Egorysheva, A. V.

2010-02-01

Single crystals of α- and β-polymorphs of Bi 2B 8O 15 were grown by Czochralski method from a charge of the stoichiometric composition. The crystal structure of β-Bi 2B 8O 15 was solved by direct methods from a twinned crystal and refined to R1=0.081 (w R=0.198) on the basis of 1584 unique observed reflections ( I>2 σ( I)). The compound is triclinic, space group P1¯, a=4.3159(8), b=6. 4604(12), c=22.485(4) Å, α=87.094(15)°, β=86.538(15)°, γ=74.420(14)°, V=602.40(19) Å 3, Z=2. The B-O layered anion of β-Bi 2B 8O 15 is topologically identical to the anion of α-Bi 2B 8O 15 but the orientation of neighboring layers is different. Thermal expansion of α-Bi 2B 8O 15 has been investigated by X-ray powder diffraction in air in temperature range from 20 to 700 °C. It is strongly anisotropic, which can be explained by the hinge mechanism applied to chains of Bi-O polyhedra. While the anisotropy of thermal expansion is rather high, the volume thermal expansion coefficient α V=40×10 6 °C -1 for α-Bi 2B 8O 15 is close to those of other bismuth borates.
Numerical analysis of lasing characteristics in highly bend-compensated large-mode-area ytterbium-doped double-clad leakage channel fibers.

PubMed

Thavasi Raja, G; Halder, Raktim; Varshney, S K

2015-12-10

The bend-induced mode-area reduction and thermal effects are vital factors that affect the power scaling of fiber lasers. Recently, bend-compensated large-mode-area double-clad modified hybrid leakage channel fiber (M-HLCF) has been reported with a mode area greater than 1000 μm, while sustaining the single-mode behavior at 1064 nm for high-temperature environments. In this work, the lasing characteristics of a newly designed ytterbium-doped double-clad M-HLCF (YDMHLCF) have been numerically investigated for strongly pumped conditions. The doped region size is optimally found through simulations, equivalent to the size of core diameter ∼38 μm in order to achieve maximum conversion efficiency for the bent and straight cases. Numerical simulations further confirm that a 2 m long YDMHLCF exhibits slope efficiency of 78% and conversion efficiency of 79% for the straight case and also almost the same for the practical bending radius of 7.5 cm when pumped with a 975 nm laser source.
The characteristics of Kerr-lens mode-locked self-Raman Nd:YVO4 1176 nm laser

NASA Astrophysics Data System (ADS)

Li, Zuohan; Peng, Jiying; Yao, Jianquan; Han, Ming

2017-03-01

In this paper we report on a compact and feasible dual-concave cavity CW Kerr-lens mode-locked self-Raman Nd:YVO4 laser. A self-starting diode-pumped picosecond Nd:YVO4 1176 nm laser is demonstrated without any additional components, where the stimulated Stokes Raman scattering and Kerr-lens-induced mode locking are operated in the same crystal. With an incident pump power of 12 W, the average output power at 1176 nm is up to 643 mW. Meanwhile, the repetition rate and the pulse width of the fundamental laser are measured to be 1.53 GHz and 8.6 ps, respectively. In addition, the yellow laser output at 588 nm is realized by frequency doubling with a LiB3O5 crystal.
Ti1-xSnxO2 nanofilms: Layer-by-layer deposition with extended Sn solubility and characterization

NASA Astrophysics Data System (ADS)

Yong, Zhihua; Linghu, Jiajun; Xi, Shibo; Tan, Hui Ru; Shen, Lei; Yang, Ping; Hui, Hui Kim; Cao, Jian Qing; Leek, Meng Lee; Yin, Xinmao; Feng, Yuan Ping; Pan, Jisheng

2018-01-01

High quality rutile Ti1-xSnxO2 nanofilms were successfully grown in a layer-by-layer mode at a moderately low temperature of 400 °C using pulsed laser deposition (PLD). High solid solubility of up to x = 0.216 has been achieved in the Ti1-xSnxO2 films despite theoretical prediction by Density functional theory (DFT) of large formation energy (∼5.64 eV) required for the substitutional alloy to exist at such high Sn concentration. The resultant films have smooth interfaces and step-terraced surfaces with well controlled stoichiometry and are optically transparent. Sn L3-edge Extended X-ray absorption fine structure (EXAFS) reveals the substitution of Sn4+ in the Ti4+ lattice sites of TiO2. The lattice spacing along [110] increases linearly with increment in x due to substitution of Sn4+ ions in the Ti lattice sites of the Ti1-xSnxO2 films. X-ray photoelectron spectroscopy (XPS) and Rutherford backscattering (RBS) show that Sn is uniformly distributed on the surface and in the bulk of the films. These results are crucial when considering Ti1-xSnxO2 with suitable composition for making TiO2 based quantum structures in advanced optoelectronic devices and solar energy materials, where high-quality crystalline thin film-substrates are important.
Analysis on the mechanism of pulse-shortening in an X-band triaxial klystron amplifier due to the asymmetric mode competition

NASA Astrophysics Data System (ADS)

Qi, Zumin; Zhang, Jun; Xie, Yongjie; Zhang, Yi; Wang, Zehua; Zhou, Xiaofeng; Zhu, Jianhui; Zi, Yanyong; Zhong, Huihuang

2016-12-01

Asymmetric mode competitions are observed in the design of an X-band triaxial klystron amplifier with an asymmetric input cavity, and the generation mechanism of the asymmetric mode competition is analyzed in the paper. The results indicate that the asymmetric modes are excited in the buncher cavity. The asymmetric mode (coaxial TM612 mode) in the buncher cavity with the highest shunt impedance can start up first among the asymmetric modes with negative beam loading conductance. The coupling of the corresponding coaxial TE mode between the buncher and input cavity exacerbates the start oscillation of the asymmetric mode competition. The rationality of the analysis is demonstrated by cutting off the propagation of the corresponding coaxial TE modes between the buncher cavity and the input cavity, and the asymmetric mode competitions are thoroughly suppressed by specially designed reflectors and lossy material. In simulation, a microwave with a power of 1.28 GW and a frequency of 9.375 GHz is generated, and the extraction efficiency and the gain are 34.5% and 41.5 dB, respectively.
Investigation on the formation process of single-crystalline GaO x barrier in Fe/GaO x /MgO/Fe magnetic tunnel junctions

NASA Astrophysics Data System (ADS)

Krishna, N. S.; Doko, N.; Matsuo, N.; Saito, H.; Yuasa, S.

2017-11-01

We have grown Fe(0 0 1)/GaO x (0 0 1)/MgO(0 0 1)/Fe(0 0 1) magnetic tunnel junctions (MTJs) with or without in situ annealing after the deposition of GaO x layer and performed structural characterizations by focusing on the formation process of the single-crystalline GaO x . It was found that, even without the in situ annealing, the as-grown GaO x grown on the MgO was mostly single-crystalline except near the surface region (amorphous). The crystallization temperature of the amorphous region was reduced from 500 °C down to 250 °C by depositing the Fe upper electrode (poly-crystalline). It was clarified that the crystallization of the amorphous region near the Fe/GaO x interface caused the realignments of the crystal grains in the poly-crystalline Fe upper electrode, and, as a result, the fully epitaxial Fe/GaO x /MgO/Fe structure is eventually formed. All the MTJs showed high tunneling magnetoresistance ratios (about 100%) at room temperature, which was almost independent of the formation temperature of the single-crystalline GaO x .
Anomalous atomic displacement parameters and local dynamics in the Curie range of a Pb-free relaxor ferroelectric system (Bi1-xBax)(Fe1-xTix)O3(0.36 ≤ x ≤ 0.50)

NASA Astrophysics Data System (ADS)

Singh, Anar; Moriyoshi, Chikako; Kuroiwa, Yoshihiro; Pandey, Dhananjai

2018-04-01

We report here the relaxor ferroelectric (RFE) behaviour in a multiferroic solid solution system, (Bi1-xBax)(Fe1-xTix)O3, at a critical disorder level of xC ˜ 0.35 in BiFeO3 and 0.65 (i.e., 1-xC = 0.35) in BaTiO3 similar to the 1:2 ratio of Mg2+ and Nb5+ in the canonical RFE Pb(Mg1/3Nb2/3)O3. This Pb-free system, like canonical Pb-based RFEs, does not exhibit macroscopic symmetry breaking and shows only the signatures of ergodicity breaking at Vogel-Fulcher freezing temperature (TVF). The atomic displacement parameters (ADPs) of Fe3+/Ti4+ and O2-, obtained using high wave vector (Q) and high-resolution synchrotron x-ray diffraction data as a function of temperature, show anomalous diffuse peaks in the Curie range. It is shown that the diffuse peak in ADPs is due to softening of the vibrational frequencies of the B-O chain (B = Fe3+/Ti4+ and O = O2-) below the Burns temperature (TB) followed by hardening below the characteristic temperature (T'm), which corresponds to a peak in the dielectric permittivity (ɛ').
Towards weakly constrained double field theory

NASA Astrophysics Data System (ADS)

Lee, Kanghoon

2016-08-01

We show that it is possible to construct a well-defined effective field theory incorporating string winding modes without using strong constraint in double field theory. We show that X-ray (Radon) transform on a torus is well-suited for describing weakly constrained double fields, and any weakly constrained fields are represented as a sum of strongly constrained fields. Using inverse X-ray transform we define a novel binary operation which is compatible with the level matching constraint. Based on this formalism, we construct a consistent gauge transform and gauge invariant action without using strong constraint. We then discuss the relation of our result to the closed string field theory. Our construction suggests that there exists an effective field theory description for massless sector of closed string field theory on a torus in an associative truncation.
Interaction of phenazinium dyes with double-stranded poly(A): Spectroscopy and isothermal titration calorimetry studies

NASA Astrophysics Data System (ADS)

Khan, Asma Yasmeen; Saha, Baishakhi; Kumar, Gopinatha Suresh

2014-10-01

A comprehensive study on the binding of phenazinium dyes viz. janus green B, indoine blue, safranine O and phenosafranine with double stranded poly(A) using various spectroscopic and calorimetric techniques is presented. A higher binding of janus green B and indoine blue over safranine O and phenosafranine to poly(A) was observed from all experiments. Intercalative mode of binding of the dyes was inferred from fluorescence polarization anisotropy, iodide quenching and viscosity experiments. Circular dichroism study revealed significant perturbation of the secondary structure of poly(A) on binding of these dyes. Results from isothermal titration calorimetry experiments suggested that the binding was predominantly entropy driven with a minor contribution of enthalpy to the standard molar Gibbs energy. The results presented here may open new opportunities in the application of these dyes as RNA targeted therapeutic agents.
Double-parton scattering effects in D0B+ and B+B+ meson-meson pair production in proton-proton collisions at the LHC

NASA Astrophysics Data System (ADS)

Maciuła, Rafał; Szczurek, Antoni

2018-05-01

We extend our previous studies of double-parton scattering (DPS) to simultaneous production of c c ¯ and b b ¯ and production of two pairs of b b ¯. The calculation is performed within a factorized ansatz. Each parton scattering is calculated within the kT-factorization approach. The hadronization is done with the help of fragmentation functions. Production of D mesons in our framework was tested in our previous works. Here, we present our predictions for B mesons. A good agreement is achieved with the LHCb data. We present our results for c c ¯b b ¯ and b b ¯b b ¯ final states. For completeness, we compare results for double- and single-parton scattering (SPS). As for the c c ¯c c ¯ final state, the DPS dominates over the SPS, especially for small transverse momenta. We present several distributions and integrated cross sections with realistic cuts for simultaneous production of D0B+ and B+B+, suggesting future experimental studies at the LHC.
Optical properties of (50-X)BaO-X(YF2)-50P2O5 glasses

NASA Astrophysics Data System (ADS)

Narayanan, Manoj Kumar; Shashikala, H. D.

2018-05-01

Glasses with composition (50-X)BaO-X(YF2)-50P2O5 (Y - Ca, Ba, X = 0, 10, 20 mol%) were prepared using conventional melt-quenching technique. Optical parameters of prepared samples such as optical band gap energy increased, while Urbach energy and refractive index decreased with partial substitution of BaO with CaF2 or BaF2 in the glass batch.
Band alignment of SiO2/(AlxGa1-x)2O3 (0 ≤ x ≤ 0.49) determined by X-ray photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Feng, Zhaoqing; Feng, Qian; Zhang, Jincheng; Li, Xiang; Li, Fuguo; Huang, Lu; Chen, Hong-Yan; Lu, Hong-Liang; Hao, Yue

2018-03-01

In this work, we report the investigation of the band alignment of SiO2/(AlxGa1-x)2O3 (0 ≤ x ≤ 0.49) utilizing the high resolution X-ray photoelectron spectroscopy (XPS) measurements. The single crystallinity and orientation of β-(AlxGa1-x)2O3 films grown on sapphire by pulsed laser deposition were studied with the high resolution X-ray diffraction. The Ga 2p3/2 and Si 2p core-level spectra as well as valence band spectra were used in the analysis of band alignment. As the mole fraction x of Al increases from 0 to 0.49, the bandgap and conduction band offset values of SiO2/(AlxGa1-x)2O3 increases from 4.9 to 5.6 eV and from 1.5 to 2.1 eV, respectively, while that of valence band offset decreases from 2.2 to 0.9 eV. From the results obtained, the energy band diagram of the studied SiO2/(AlxGa1-x)2O3 (0 ≤ x ≤ 0.49) interfaces is found to be of type I. Energy band lineups of SiO2/(AlxGa1-x)2O3 were thus determined which can be used as for Ga2O3 based power device technology.

Study of working principle and thermal balance process of a double longitudinal-mode He-Ne laser

NASA Astrophysics Data System (ADS)

Wang, Li-qiang

2009-07-01

A double longitudinal mode He-Ne laser with frequency stabilization is proposed. Compared with general methods, such as Lamb dip, Zeeman splitting and molecule saturation absorption method, this design has some advantages, such as no piezocrystal or magnetic field, a short frequency-stabilized time, lower cost, and higher frequency stability and reproducibility. The metal wire is uniformly wrapped on the discharge tube of the laser. When the metal wire is heated up, the resonant cavity changes with the temperature field around the discharge tube to make the frequency of the laser to be tuned. The polarizations of the two longitudinal modes from the laser must be orthogonal. The parallelly polarized light and the vertically polarized light compete with each other, i. e., the parallelly polarized light generates a larger output power, while, the vertically polarized light correspondingly generates a smaller one, but an equal value is found at the reference frequencies by automatically adjusting the length of the resonant cavity, due to change of the temperature in the discharge tube. Consequently the frequencies of the laser are stabilized. In my experiment, an intracavity He-Ne laser whose length of the resonant cavity is larger than 50mm and smaller than 300mm is selected for the double longitudinal-mode laser. Influence factors of frequency stability of this laser is only change of the length of the resonant cavity. The laser includes three stages: mode hopping, transition stage, and modes stability from startup to laser stability. When this laser is in modes stability, the waveform of heating metal wire is observed to a pulse whose duty is almost 50%, and thermal balances of the resonant cavity mainly rely on discharge tube.
Positron annihilation studies of Bi 2CaSr 2Cu 2O x and Bi 1.6Pb 0.4Ca 2Sr 2Cu 3O y in the region of the superconducting transition

NASA Astrophysics Data System (ADS)

Pujari, P. K.; Datta, T.; Manohar, S. B.; Prakash, Satya; Sastry, P. V. P. S. S.; Yakhmi, J. V.; Iyer, R. M.

1990-03-01

Doppler broadened annihilation radiation (DBAR) spectral parameters have been reported- for the first time- between 77 K and 300 K, for several Bi-based oxide superconductors, viz. A: single phase (2122) Bi 2CaSr 2Cu 2O x with Tc=85 K (R=0), B: a mixed phase lead doped sample containing both 2122 and 2223 with a nominal composition Bi 1.6Pb 0.4Ca 2Sr 2Cu 3O y, and, C: another 2122+2223 sample with same nominal composition as that of B but synthesised under a different heat-treatment schedule so as to yield a Tc=85 K (R=0). Analyses of these spectra using PAACFIT program yielded two components, of which the intensity of the narrow component, I N, and, the width of the broad component, T B, were seen to be the only temperature dependent parameters. At the onset of superconducting transition both T B and I N were seen to increase to a maximum value and decrease on further cooling. A double peak structure in T B vs temperature profile were observed in sample B and C, similar to one reported by us in Tl-Ca-Ba-Cu-O systems. In addition, presence of a magnetic field (1 KG) yielded no significant change in the DBAR spectral parameters. The results are discussed.
Luminescence and energy transfer of Tb3+-doped BaO-Gd2O3-Al2O3-B2O3-SiO2 glasses.

PubMed

Zuo, Chenggang; Huang, Jinze; Liu, Shaoyou; Xiao, Anguo; Shen, Youming; Zhang, Xiangyang; Zhou, Zhihua; Zhu, Ligang

2017-12-05

Transparent Tb 3+ -doped BaO-Gd 2 O 3 -Al 2 O 3 -B 2 O 3 -SiO 2 glasses with the greater than 4g/cm 3 were prepared by high temperature melting method and its luminescent properties have been investigated by measured UV-vis transmission, excitation, emission and luminescence decay spectra. The transmission spectrum shows there are three weak absorption bands locate at about 312, 378 and 484nm in the glasses and it has good transmittance in the visible spectrum region. Intense green emission can be observed under UV excitation. The effective energy transfer from Gd 3+ ion to Tb 3+ ion could occur and sensitize the luminescence of Tb 3+ ion. The green emission intensity of Tb 3+ ion could change with the increasing SiO 2 /B 2 O 3 ratio in the borosilicate glass matrix. With the increasing concentration of Tb 3+ ion, 5 D 4 → 7 F J transitions could be enhanced through the cross relaxation between the two nearby Tb 3+ ions. Luminescence decay time of 2.12ms from 546nm emission is obtained. The results indicate that Tb 3+ -doped BaO-Gd 2 O 3 -Al 2 O 3 -B 2 O 3 -SiO 2 glasses would be potential scintillating material for applications in X-ray imaging. Copyright © 2017 Elsevier B.V. All rights reserved.
Effects of complexing agents on electrochemical deposition of FeS x O y in ZnO/FeS x O y heterostructures

NASA Astrophysics Data System (ADS)

Supee, A.; Ichimura, M.

2017-12-01

Heterostructures which consist of ZnO and FeS x O y were deposited via electrochemical deposition (ECD) for application to solar cells. Galvanostatic ECD was used in FeS x O y deposition with a solution containing 100 mM Na2S2O3 and 30 mM FeSO4. To alter the film properties, L(+)-tartaric acid (C4H6O6) and lactic acid [CH3CH(OH)COOH] were introduced as the complexing agents into the FeS x O y deposition solution. Larger film thickness and smaller oxygen content were obtained for the films deposited with the complexing agents. ZnO was deposited on FeS x O y by two-step pulse ECD from a solution containing Zn(NO3)2. For the ZnO/FeS x O y heterostructures fabricated with/without complexing agents, rectifying properties were confirmed in the current density-voltage ( J- V) characteristics. However, photovoltaic properties were not improved with addition of both complexing agents.
Impact of a primordial magnetic field on cosmic microwave background B modes with weak lensing

NASA Astrophysics Data System (ADS)

Yamazaki, Dai G.

2018-05-01

We discuss the manner in which the primordial magnetic field (PMF) suppresses the cosmic microwave background (CMB) B mode due to the weak-lensing (WL) effect. The WL effect depends on the lensing potential (LP) caused by matter perturbations, the distribution of which at cosmological scales is given by the matter power spectrum (MPS). Therefore, the WL effect on the CMB B mode is affected by the MPS. Considering the effect of the ensemble average energy density of the PMF, which we call "the background PMF," on the MPS, the amplitude of MPS is suppressed in the wave number range of k >0.01 h Mpc-1 . The MPS affects the LP and the WL effect in the CMB B mode; however, the PMF can damp this effect. Previous studies of the CMB B mode with the PMF have only considered the vector and tensor modes. These modes boost the CMB B mode in the multipole range of ℓ>1000 , whereas the background PMF damps the CMB B mode owing to the WL effect in the entire multipole range. The matter density in the Universe controls the WL effect. Therefore, when we constrain the PMF and the matter density parameters from cosmological observational data sets, including the CMB B mode, we expect degeneracy between these parameters. The CMB B mode also provides important information on the background gravitational waves, inflation theory, matter density fluctuations, and the structure formations at the cosmological scale through the cosmological parameter search. If we study these topics and correctly constrain the cosmological parameters from cosmological observations, including the CMB B mode, we need to correctly consider the background PMF.
Titanium Dioxide (TiO2) film as a new saturable absorber for generating mode-locked Thulium-Holmium doped all-fiber laser

NASA Astrophysics Data System (ADS)

Mohd Rusdi, Muhammad Farid; Latiff, Anas Abdul; Paul, Mukul Chandra; Das, Shyamal; Dhar, Anirban; Ahmad, Harith; Harun, Sulaiman Wadi

2017-03-01

We report the generation of mode-locked thulium-holmium doped fiber laser (THDFL) at 1979 nm. This is a first demonstration of mode-locked by using Titanium Dioxide (TiO2) film as a saturable absorber (SA). A piece of 1 mm×1 mm TiO2 film was sandwiched in between two fiber ferrule in the cavity. Fabrication process of TiO2 film incorporated a TiO2 and a polyvinyl alcohol (PVA). The stable 9 MHz repetition rate of mode-locked mode operation with 58 dB SNR was generated under pump power of 902-1062 mW. At maximum pump power, the mode-locked THDFL has output power and pulse energy of 15 mW and 1.66 nJ, respectively. Our results demonstrate the TiO2 can be used promisingly in ultrafast photonics applications.
Characterizing Atacama B-mode Search Detectors with a Half-Wave Plate

NASA Astrophysics Data System (ADS)

Simon, S. M.; Appel, J. W.; Campusano, L. E.; Choi, S. K.; Crowley, K. T.; Essinger-Hileman, T.; Gallardo, P.; Ho, S. P.; Kusaka, A.; Nati, F.; Palma, G. A.; Page, L. A.; Raghunathan, S.; Staggs, S. T.

2016-08-01

The Atacama B-Mode Search (ABS) instrument is a cryogenic (˜ 10 K) crossed-Dragone telescope located at an elevation of 5190 m in the Atacama Desert in Chile that observed for three seasons between February 2012 and October 2014. ABS observed the cosmic microwave background (CMB) at large angular scales (40<ℓ <500) to limit the B-mode polarization spectrum around the primordial B-mode peak from inflationary gravity waves at ℓ ˜ 100. The ABS focal plane consists of 480 transition-edge sensor (TES) bolometers. They are coupled to orthogonal polarizations from a planar ortho-mode transducer and observe at 145 GHz. ABS employs an ambient-temperature, rapidly rotating half-wave plate (HWP) to mitigate systematic effects and move the signal band away from atmospheric 1 / f noise, allowing for the recovery of large angular scales. We discuss how the signal at the second harmonic of the HWP rotation frequency can be used for data selection and for monitoring the detector responsivities.
The incommensurately modulated(1 - x)Ta 2O 5· xWO 3, 0 ≤ x ≤ 0.267 solid solution

NASA Astrophysics Data System (ADS)

Schmid, Siegbert; Withers, Ray L.; Thompson, John G.

1992-08-01

The phase(1 - x)Ta 2O 5 · WO 3, 0 ≤ x ≤ 0.267 has been studied by X-ray powder diffraction and transmission electron microscopy. It was previously described as an infinite series of anion-deficient, α-UO 3-type "line phases," with compositions resulting from intergrowths of different blocks made up by small numbers of α-UO 3-type cells. More correctly(1 - x)Ta 2O 5· xWO 3, 0 ≤ x ≤ 0.267 is described as an incommensurately modulated structure with a linearly composition-dependent primary modulation wave-vector qprim. = qb*. The underlying orthorhombically distorted α-UO 3-type parent structure has space group symmetry Cmmm ( a ≈ 6.20-6.14, b ≈ 3.66, c ≈ 3.89-3.85Å). Characteristic extinction conditions imply a superspace group symmetry of P : Cmmmm : s, -1,1. The four previously reported crystal structures in the solid solution field are examined by means of apparent valence calculations. Crystal chemical reasons are proposed for the width of the composition range,0 ≤ x ≤ 0.267, observed for the title phase.
Effects of Eu3+ concentration on structural, optical and vibrational properties of multifunctional Ce(1-x)Eu(x)O2-delta) nanoparticles synthesized by thermolysis of 2,4-pentanedione complexes.

PubMed

Kremenovic, A; Bozanic, D K; Welsch, A M; Jancar, B; Nikolic, A S; Boskovic, M; Colomban, Ph; Fabian, Martin; Antic, B

2012-12-01

The 5-10 nm Ce(1-x)Eu(x)O(2-delta) (0 < or = x < or = 0.30) nanoparticles with fluorite structure were synthesized by thermal decomposition of Eu- and Ce-2,4-pentanedione complexes mixtures. X-ray line broadening analysis of mixed samples Ce(1-x)Eu(x)O(2-delta) (0.05 < or = x < or = 0.30) showed that the crystallite size was lower and root mean square strain higher than in pure ceria. However, within mixed samples Ce(1-x)Eu(x)O(2-delta) (0.05 < or = x < or = 0.30) crystallite size and root mean square strain were independent of Eu3+ concentration. Raman spectroscopy results indicated that europium ions yield disorder by breaking the phonon propagation and therefore making the non-centre Brillouin zone modes Raman active. The absorption bands in the spectra of mixed oxides were blue-shifted in comparison to pure CeO(2-delta) nanopowder. The samples show red emission typical for Eu ions. The biggest photoluminescent intensity was observed for the highest Eu3+ concentration (x = 0.30) and further enhanced with the increase in crystallinity.
Polarization-Dependent Raman Spectroscopy of Epitaxial TiO 2 (B) Thin Films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jokisaari, Jacob R.; Bayerl, Dylan; Zhang, Kui

2015-12-08

The bronze polymorph of titanium dioxide, known as TiO 2(B), has promising photochemical and electronic properties for potential applications in Li-ion batteries, photocatalysis, chemical sensing, and solar cells. In contrast to previous studies performed with powder samples, which often suffer from impurities and lattice water, here we report Raman spectra from highly crystalline TiO 2(B) films epitaxially grown on Si substrates with a thin SrTiO 3 buffer layer. The reduced background from the Si substrate significantly benefits acquisition of polarization-dependent Raman spectra collected from the high-quality thin films, which are compared to nanopowder results reported in the literature. The experimentalmore » spectra were compared with density functional theory calculations to analyze the atomic displacements associated with each Raman-active vibrational mode. These results provide a standard reference for further investigation of the crystallinity, structure, composition, and properties of TiO 2(B) materials with Raman spectroscopy.« less
Strong composition-dependent variation of MCs + calibration factors in TiO x and GeO x ( x ≤ 2) films

NASA Astrophysics Data System (ADS)

Gnaser, Hubert; Le, Yongkang; Su, Weifeng

2006-07-01

The emission of MCs + secondary ions (M designates the analyte species) from TiO x (0.2 ≤ x ≤ 2) and GeO x (0.001 ≤ x ≤ 0.8) films under Cs + bombardment was examined. The relative calibration factors of OCs +/TiCs + and OCs +/GeCs + were determined and were found to depend pronouncedly on the O/Ti and O/Ge atomic concentration ratios. Specifically, with increasing oxygen content OCs + ions form much more efficiently (as compared to TiCs + or GeCs + ions), an enhancement amounting to more than a factor of 10 for the highest oxygen concentrations. Concurrently, the formation of TiOCs + or GeOCs + ions increases drastically. For both oxide systems, an empirical relation for the oxygen-concentration dependence of the relative calibration factors could be established.
Pinning in high performance MgB2 thin films and bulks: Role of Mg-B-O nano-scale inhomogeneities

NASA Astrophysics Data System (ADS)

Prikhna, Tatiana; Shapovalov, Andrey; Eisterer, Michael; Shaternik, Vladimir; Goldacker, Wilfried; Weber, Harald W.; Moshchil, Viktor; Kozyrev, Artem; Sverdun, Vladimir; Boutko, Viktor; Grechnev, Gennadiy; Gusev, Alexandr; Kovylaev, Valeriy; Shaternik, Anton

2017-02-01

The comparison of nano-crystalline MgB2 oxygen-containing thin film (140 nm) and highly dense bulk materials showed that the critical current density, Jc, depends on the distribution of Mg-B-O nano-scale inhomogeneities. It has been shown that MgB2 bulks with high Jc in low (∼106 A/cm2 in 0-1 T at 10 K) and medium magnetic fields contain MgB0.6-0.8O0.8-0.9 nano-inclusions, where δTc or a combined δTc (dominant) / δl pinning mechanism prevails, while in bulk MgB2 with high Jc in high magnetic fields (Birr(18.5 K) = 15 T, Bc2(0 K) = 42.1 T) MgB1.2-2.7O1.8-2.5 nano-layers are present and δl pinning prevails. The structure of oxygen-containing films with high Jc in low and high magnetic fields (Jc (0 Т) = 1.8 × 107 А/сm2 and Jc (5 Т) = 2 × 106 А/сm2 at 10 К) contains very fine oxygen-enriched Mg-B-O inhomogeneities and δl pinning is realized. The results of DOS calculations in MgB2-xOx cells for x = 0, 0.125, 0.25, 0.5, 1 demonstrate that all compounds are conductors with metal-like behaviour. In the case of ordered oxygen substitution for boron the binding energy, Eb, does not increase sufficiently as compared with that for MgB2, while when oxygen atoms form zigzag chains the calculated Eb is even lower (Eb = -1.15712 Ry).
Interferon induction by two 2'-modified double-helical RNAs, poly(2'-fluoro-2'-deoxyinosinic acid) x poly(cytidylic acid) and poly(2'-chloro-2'-deoxyinosinic acid) x poly(cytidylic acid).

PubMed

De Clercq, E; Stollar, B D; Hobbs, J; Fukui, T; Kakiuchi, N; Ikehara, M

1980-01-01

In addition to the 2'-azido analogue of (I)n x (C)n, (dIn3)n x (C)n, we have found two other (I)n x (C)n analogues, (dIfl)n x (C)n and (dIcl)n x (C)n, in which the 2'-hydroxyls of the (I)n strand are replaced by either fluorine or chlorine, to be highly effective in inducing interferon. This contrasted with the lack of interferon-inducing activity noted for various other 2'-halogeno analogues of (I)n x (C)n and (A)n x (U)n, i.e. (I)n x (dCcl)n, (dAfl)n x (U)n, (dAcl)n x (U)n, (A)n x (dUfl)n and (A)n x (dUcl)n. In most assay systems, viz. primary rabbit kidney cells, human diploid fibroblasts, HeLa cells, interferon-primed mouse L-929 cells, and intact rabbits, (dIfl)n x (C)n and (dIcl)n x (C)n induced interferon levels that were comparable to those induced by (I)n x (C)n. There was one particular system (L-929 cells treated with DEAE-dextran), however, in which (dIfl)n x (C)n and (dIcl)n x (C)n, unlike (I)n x (C)n, failed to stimulate interferon production. As monitored by both radiochemical and biological means, (dIfl)n x (C)n and, to a lesser extent, (dIcl)n x (C)n were more resistant to degradation by ribonuclease A, T1 and human serum nucleases than was (I)n x (C)n. In their reactivity towards antibodies to double-stranded RNA (dIfl)n x (C)n and (dIcl)n x (C)n conformed more closely to (I)n x (C)n than did other 2'-substituted (e.g. 2'-O-methyl or 2'-O-ethyl) analogues of (I)n x (C)n. The high interferon-inducing potency of (dIfl)n x (C)n and (dIcl)n x (C)n has both theoretical and practical implications. While our findings suggest that (dIfl)n x (C)n and (dIcl)n x (C)n should be further explored for their therapeutic potentials, they also strengthen the notion that the interferon-inducing capacity, and possibly other biological functions of double-stranded RNAs is dependent on the recognition of the overall conformation of the polynucleotide rather than on the binding of specific functional groups such as the 2'-hydroxyl group.
Self-assembly preparation of SiO2@Ni-Al layered double hydroxide composites and their enhanced electrorheological characteristics

PubMed Central

Ji, Xuqiang; Zhang, Wenling; Shan, Lei; Tian, Yu; Liu, Jingquan

2015-01-01

The core-shell structured SiO2@Ni-Al layered double hydroxide (LDH) composites were prepared via self-assembly of Ni-Al LDH on the surface of SiO2 spheres. Only coating a layer of ultrathin Ni-Al LDH sheet, the resulting SiO2@Ni-Al LDH composites exhibit significantly enhanced electrorheological (ER) characteristics compared to conventional bare SiO2 spheres. The monodispersed SiO2 spheres with average diameters of 260 nm were synthesized by the hydrolysis of tetraethyl orthosilicate (TEOS), while the shell part, Ni-Al LDH sheet was prepared by the hydrothermal procedure. The morphology of the samples was investigated via scanning transmission electron microscopy (STEM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structure of the samples was characterized by X-ray diffraction (XRD). The species and distribution of elements in samples were confirmed by X-ray photoelectron spectroscopy (XPS), Energy dispersive analysis of X-ray (EDX) and elemental mapping in STEM. Subsequently, the ER characteristics of the composites dispersed in insulating oil were characterized by a rotational rheometer. The electric field-stimulated rheological performances (yield stress, viscosity, modulus, etc.) were observed under an external electric field, which is different from the Newtonian state in the free electric field. PMID:26670467
Self-assembly preparation of SiO2@Ni-Al layered double hydroxide composites and their enhanced electrorheological characteristics

NASA Astrophysics Data System (ADS)

Ji, Xuqiang; Zhang, Wenling; Shan, Lei; Tian, Yu; Liu, Jingquan

2015-12-01

The core-shell structured SiO2@Ni-Al layered double hydroxide (LDH) composites were prepared via self-assembly of Ni-Al LDH on the surface of SiO2 spheres. Only coating a layer of ultrathin Ni-Al LDH sheet, the resulting SiO2@Ni-Al LDH composites exhibit significantly enhanced electrorheological (ER) characteristics compared to conventional bare SiO2 spheres. The monodispersed SiO2 spheres with average diameters of 260 nm were synthesized by the hydrolysis of tetraethyl orthosilicate (TEOS), while the shell part, Ni-Al LDH sheet was prepared by the hydrothermal procedure. The morphology of the samples was investigated via scanning transmission electron microscopy (STEM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structure of the samples was characterized by X-ray diffraction (XRD). The species and distribution of elements in samples were confirmed by X-ray photoelectron spectroscopy (XPS), Energy dispersive analysis of X-ray (EDX) and elemental mapping in STEM. Subsequently, the ER characteristics of the composites dispersed in insulating oil were characterized by a rotational rheometer. The electric field-stimulated rheological performances (yield stress, viscosity, modulus, etc.) were observed under an external electric field, which is different from the Newtonian state in the free electric field.
Quantum interference effects on the intensity of the G modes in double-walled carbon nanotubes

DOE PAGES

Tran, Huy Nam; Blancon, Jean-Christophe Robert; Arenal, Raul; ...

2017-05-08

The effects of quantum interferences on the excitation dependence of the intensity of G modes have been investigated on single-walled carbon nanotubes [Duque et al., Phys. Rev. Lett.108, 117404 (2012)]. In this work, by combining optical absorption spectroscopy and Raman scattering on individual index identified double-walled carbon nanotubes, we examine the experimental excitation dependence of the intensity of longitudinal optical and transverse optical G modes of the constituent inner and outer single-walled carbon nanotubes. The observed striking dependencies are understood in terms of quantum interference effects. Considering such effects, the excitation dependence of the different components of the G modesmore » permit to unambiguously assign each of them as originating from the longitudinal or transverse G modes of inner and outer tubes.« less
Quantum interference effects on the intensity of the G modes in double-walled carbon nanotubes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tran, Huy Nam; Blancon, Jean-Christophe Robert; Arenal, Raul

The effects of quantum interferences on the excitation dependence of the intensity of G modes have been investigated on single-walled carbon nanotubes [Duque et al., Phys. Rev. Lett.108, 117404 (2012)]. In this work, by combining optical absorption spectroscopy and Raman scattering on individual index identified double-walled carbon nanotubes, we examine the experimental excitation dependence of the intensity of longitudinal optical and transverse optical G modes of the constituent inner and outer single-walled carbon nanotubes. The observed striking dependencies are understood in terms of quantum interference effects. Considering such effects, the excitation dependence of the different components of the G modesmore » permit to unambiguously assign each of them as originating from the longitudinal or transverse G modes of inner and outer tubes.« less
X-24A in Powered Flight after Drop from B-52 Mothership

NASA Technical Reports Server (NTRS)

1970-01-01

The X-24A lights its XLR-11 rocket engine and begins its powered flight after being drop launched from its B-52 mothership, seen here with high-altitude contrails streaming from its wings against a piercingly dark blue sky. The X-24 was one of a group of lifting bodies flown by the NASA Flight Research Center (now Dryden Flight Research Center), Edwards, California, in a joint program with the U.S. Air Force at Edwards Air Force Base from 1963 to 1975. The lifting bodies were used to demonstrate the ability of pilots to maneuver and safely land wingless vehicles designed to fly back to Earth from space and be landed like an airplane at a predetermined site. Lifting bodies' aerodynamic lift, essential to flight in the atmosphere, was obtained from their shape. The addition of fins and control surfaces allowed the pilots to stabilize and control the vehicles and regulate their flight paths. Built by Martin Aircraft Company, Maryland, for the U.S. Air Force, the X-24A was a bulbous vehicle shaped like a teardrop with three vertical fins at the rear for directional control. It weighed 6,270 pounds, was 24.5 feet long and 11.5 feet wide (measuring just the fuselage, not the distance between the tips of the outboard fins). Its first unpowered glide flight was on April 17, 1969, with Air Force Maj. Jerauld Gentry at the controls. Gentry also piloted its first powered flight on March 19, 1970. The X-24A was flown 28 times in the program that, like the HL-10, validated the concept that a Space Shuttle vehicle could be landed unpowered. The fastest speed achieved by the X-24A was 1,036 miles per hour (mph-Mach 1.6). Its maximum altitude was 71,400 feet. It was powered by an XLR-11 rocket engine with a maximum theoretical vacuum thrust of 8,480 pounds. The X-24A was later modified into the X-24B. The bulbous shape of the X-24A was converted into a 'flying flatiron' shape with a rounded top, flat bottom, and double delta platform that ended in a pointed nose. The X-24B
Ionic configuration of copper ferrimanganites Cu 0.5Mn xFe 2.5- xO 4

NASA Astrophysics Data System (ADS)

Lenglet, M.; Kasperek, J.; Hannoyer, B.; Lopitaux, J.; d'Huysser, A.; Tellier, J. C.

1992-06-01

Mössbauer spectrometry, neutron diffraction, XANES, and XPS have led to the determination of the cation distributions of the system Cu 0.5Mn xFe 2.5- xO 4 (0≤ x≤1.5). The three cations are present in both tetrahedral and octahedral sites, and the relative number of Fe ions on A- and B-sites remains nearly constant in the whole range of x. It appears that for x≤0.5 manganese is divalent and copper is in its two oxidation states. For x>0.5 copper and iron are respectively divalent and trivalent; the manganese is in +2 and +3 oxydation states.
Understanding the role of A-site and B-site cations on piezoelectric instability in lead--free (1-x) BaTiO3 -- xA(Cu1/3Nb2/3)O3 (A = Sr, Ca, Ba) solid solutions

NASA Astrophysics Data System (ADS)

Maurya, Deepam; Zhou, Yuan; Priya, Shashank

2013-03-01

This study provides fundamental understanding of the enhanced piezoelectric instability in lead-free piezoelectric (1-x) BaTiO3-xA(Cu1/3Nb2/3) O3(A: Sr, Ba and Ca and x = 0.0-0.03) solid solutions. These compositions were found to exhibit large longitudinal piezoelectric constant (d33) of ~330 pC/N and electromechanical planar coupling constant (kp) ~ 46% at room temperature. The X-ray diffraction coupled with atomic pair distribution functions (PDF)s indicated increase in local polarization. Raman scattering and electron paramagnetic resonance (EPR) analysis revealed that substitutions on A and B-site both substantially perturbed the local octahedral dynamics and resulted in localized nano polar regions with lower symmetry. The presence of nano domains and local structural distortions smears the Curie peak resulting in diffuse order-disorder type phase transitions. The effect of these distortions on the variations in physical property was modeled and analyzed within the context of nanodomains and phase transitions. *spriya@vt.edu The financial support from National Science Foundation and Office of Basic Energy Science, Department of Energy (Microscopy analysis) is gratefully acknowledged. The authors would also like to acknowledge the support from KIMS (new piezoelectric)

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