Sample records for observed 2-m air

  1. Simultaneous assimilation of AIRS and GOSAT CO2 observations with Ensemble Kalman filter

    NASA Astrophysics Data System (ADS)

    Liu, J.; Kalnay, E.; Fung, I.; Kang, J.

    2012-12-01

    Lack of CO2 vertical information could lead to bias in the surface CO2 flux estimation (Stephens et al., 2007). Liu et al. (2012) showed that assimilating AIRS CO2 observations, which are sensitive to middle to upper troposphere CO2, improves CO2 concentration, especially in the middle to upper troposphere. GOSAT is sensitive to CO2 over the whole column, but the spatial coverage is sparser than AIRS. In this study, we assimilate AIRS and GOSAT CO2 observations simultaneously along with surface flask CO2 observations and meteorology observations with Ensemble Kalman filter (EnKF) to constrain CO2 vertical profiles simulated by NCAR carbon-climate model. We will show the impact of assimilating AIRS and GOSAT CO2 on the CO2 vertical gradient, seasonal cycle and spatial gradient by assimilating only GOSAT or AIRS and comparing to the control experiment. The quality of CO2 analysis will be examined by validating against independent CO2 aircraft observations, and analyzing the relationship between CO2 analysis fields and major circulation, such as Madden Julian Oscillation. We will also discuss the deficiencies of the observation network in understanding the carbon cycle.

  2. Simultaneous assimilation of AIRS Xco2 and meteorological observations in a carbon climate model with an ensemble Kalman filter

    NASA Astrophysics Data System (ADS)

    Liu, Junjie; Fung, Inez; Kalnay, Eugenia; Kang, Ji-Sun; Olsen, Edward T.; Chen, Luke

    2012-03-01

    This study is our first step toward the generation of 6 hourly 3-D CO2 fields that can be used to validate CO2 forecast models by combining CO2 observations from multiple sources using ensemble Kalman filtering. We discuss a procedure to assimilate Atmospheric Infrared Sounder (AIRS) column-averaged dry-air mole fraction of CO2 (Xco2) in conjunction with meteorological observations with the coupled Local Ensemble Transform Kalman Filter (LETKF)-Community Atmospheric Model version 3.5. We examine the impact of assimilating AIRS Xco2 observations on CO2 fields by comparing the results from the AIRS-run, which assimilates both AIRS Xco2 and meteorological observations, to those from the meteor-run, which only assimilates meteorological observations. We find that assimilating AIRS Xco2 results in a surface CO2 seasonal cycle and the N-S surface gradient closer to the observations. When taking account of the CO2 uncertainty estimation from the LETKF, the CO2 analysis brackets the observed seasonal cycle. Verification against independent aircraft observations shows that assimilating AIRS Xco2 improves the accuracy of the CO2 vertical profiles by about 0.5-2 ppm depending on location and altitude. The results show that the CO2 analysis ensemble spread at AIRS Xco2 space is between 0.5 and 2 ppm, and the CO2 analysis ensemble spread around the peak level of the averaging kernels is between 1 and 2 ppm. This uncertainty estimation is consistent with the magnitude of the CO2 analysis error verified against AIRS Xco2 observations and the independent aircraft CO2 vertical profiles.

  3. Clear-air radar observations of the atmospheric boundary layer

    NASA Astrophysics Data System (ADS)

    Ince, Turker

    2001-10-01

    This dissertation presents the design and operation of a high-resolution frequency-modulated continuous-wave (FM- CW) radar system to study the structure and dynamics of clear-air turbulence in the atmospheric boundary layer (ABL). This sensitive radar can image the vertical structure of the ABL with both high spatial and temporal resolutions, and provide both qualitative information about the morphology of clear-air structures and quantitative information on the intensity of fluctuations in refractive-index of air. The principles of operation and the hardware and data acquisition characteristics of the radar are described in the dissertation. In October 1999, the radar participated in the Cooperative Atmosphere-Surface Exchange Study (CASES'99) Experiment to characterize the temporal structure and evolution of the boundary-layer features in both convective and stable conditions. The observed structures include clear-air convection, boundary layer evolution, gravity waves, Kelvin-Helmholtz instabilities, stably stratified layers, and clear-air turbulence. Many of the S-band radar images also show high- reflectivity returns from Rayleigh scatterers such as insects. An adaptive median filtering technique based on local statistics has, therefore, been developed to discriminate between Bragg and Rayleigh scattering in clear-air radar observations. The filter is tested on radar observations of clear air convection with comparison to two commonly used image processing techniques. The dissertation also examines the statistical mean of the radar-measured C2n for clear-air convection, and compares it with the theoretical predictions. The study also shows that the inversion height, local thickness of the inversion layer, and the height of the elevated atmospheric layers can be estimated from the radar reflectivity measurements. In addition, comparisons to the radiosonde-based height estimates are made. To examine the temporal and spatial structure of C2n , the dissertation

  4. National review of ambient air toxics observations.

    PubMed

    Strum, Madeleine; Scheffe, Richard

    2016-02-01

    Ambient air observations of hazardous air pollutant (HAPs), also known as air toxics, derived from routine monitoring networks operated by states, local agencies, and tribes (SLTs), are analyzed to characterize national concentrations and risk across the nation for a representative subset of the 187 designated HAPs. Observations from the National Air Toxics Trend Sites (NATTS) network of 27 stations located in most major urban areas of the contiguous United States have provided a consistent record of HAPs that have been identified as posing the greatest risk since 2003 and have also captured similar concentration patterns of nearly 300 sites operated by SLTs. Relatively high concentration volatile organic compounds (VOCs) such as benzene, formaldehyde, and toluene exhibit the highest annual average concentration levels, typically ranging from 1 to 5 µg/m(3). Halogenated (except for methylene chloride) and semivolatile organic compounds (SVOCs) and metals exhibit concentrations typically 2-3 orders of magnitude lower. Formaldehyde is the highest national risk driver based on estimated cancer risk and, nationally, has not exhibited significant changes in concentration, likely associated with the large pool of natural isoprene and formaldehyde emissions. Benzene, toluene, ethylbenzene, and 1,3-butadiene are ubiquitous VOC HAPs with large mobile source contributions that continue to exhibit declining concentrations over the last decade. Common chlorinated organic compounds such as ethylene dichloride and methylene chloride exhibit increasing concentrations. The variety of physical and chemical attributes and measurement technologies across 187 HAPs result in a broad range of method detection limits (MDLs) and cancer risk thresholds that challenge confidence in risk results for low concentration HAPs with MDLs near or greater than risk thresholds. From a national monitoring network perspective, the ability of the HAPs observational database to characterize the multiple

  5. Comparing AIRS/AMSU-A Satellite and MERRA/MERRA-2 Reanalysis products with In-situ Station Observations at Summit, Greenland

    NASA Astrophysics Data System (ADS)

    Hearty, T. J., III; Vollmer, B.; Wei, J. C.; Huwe, P. M.; Albayrak, A.; Wu, D. L.; Cullather, R. I.; Meyer, D. L.; Lee, J. N.; Blaisdell, J. M.; Susskind, J.; Nowicki, S.

    2017-12-01

    The surface air and skin temperatures reported by the Atmospheric Infrared Sounder (AIRS), the Modern-Era Retrospective analysis for Research and Applications (MERRA), and MERRA-2 at Summit, Greenland are compared with near surface air temperatures measured at National Oceanic and Atmospheric Administration (NOAA) and Greenland Climate Network (GC-Net) weather stations. Therefore this investigation requires familiarity with a heterogeneous set of swath, grid, and point data in several different formats, different granularity, and different sampling. We discuss the current subsetting capabilities available at the GES DISC (Goddard Earth Sciences Data Information Services Center) to perform the inter-comparisons necessary to evaluate the quality and trustworthiness of these datasets. We also explore potential future services which may assist users with this type of intercomparison. We find the AIRS Surface Skin Temperature (TS) is best correlated with the NOAA 2 m air temperature (T2M) but it tends to be colder than the station measurements. The difference may be the result of the frequent near surface temperature inversions in the region. The AIRS Surface Air Temperature (SAT) is also well correlated with the NOAA T2M but it has a warm bias with respect to the NOAA T2M during the cold season and a larger standard error than surface temperature. This suggests that the extrapolation of the temperature profile to the surface is not valid for the strongest inversions. Comparing the temperature lapse rate derived from the 2 stations shows that the lapse rate can increase closer to the surface. We also find that the difference between the AIRS SAT and TS is sensitive to near surface inversions. The MERRA-2 surface and near surface temperatures show improvements over MERRA but little sensitivity to near surface temperature inversions.

  6. Mean Ages of Stratospheric Air Derived From in Situ Observations of CO2, CH4, and N2O

    NASA Technical Reports Server (NTRS)

    Andrews, A. E.; Boering, K. A.; Daube, B. C.; Wofsy, S. C.; Loewenstein, M.; Jost, H.; Podolske, J. R.; Webster, C. R.; Herman, R. L.; Scott, D. C.; hide

    2001-01-01

    Accurate mean ages for stratospheric air have been derived from a spatially and temporally comprehensive set of in situ observations of CO2, CH4, and N2O obtained from 1992 to 1998 from the NASA ER-2 aircraft and balloon flights. Errors associated with the tropospheric CO2 seasonal cycle and interannual variations in the CO2 growth rate are less than 0.5 year throughout the stratosphere and less than 0.3 year for air older than 2 years (N2O less than 275 ppbv), indicating that the age spectra are broad enough to attenuate these influences over the time period covered by these observations. The distribution of mean age with latitude and altitude provides detailed, quantitative information about the general circulation of the stratosphere. At 20 km, sharp meridional gradients in the mean age are observed across the subtropics. Between 20 and 30 km, the average difference in mean age between the tropics and midlatitudes is approximately 2 years, with slightly smaller differences at higher and lower altitudes. The mean age in the midlatitude middle stratosphere (approx. 25-32 km) is relatively constant with respect to altitude at 5 plus or minus 0.5 years. Comparison with earlier balloon observations of CO2 dating back to the 1970s indicates that the mean age of air in this region has remained within 11 year of its current value over the last 25 years. A climatology of mean age is derived from the observed compact relationship between mean age and N2O. These characteristics of the distribution of mean age in the stratosphere will serve as critically needed diagnostics for models of stratospheric transport.

  7. On the relationship between the Madden-Julian Oscillation and 2 m air temperature over central Asia in boreal winter

    NASA Astrophysics Data System (ADS)

    Zhou, Yang; Lu, Youyu; Yang, Ben; Jiang, Jing; Huang, Anning; Zhao, Yong; La, Mengke; Yang, Qing

    2016-11-01

    Linear regression is used to explore the relationship between the Madden-Julian oscillation (MJO) and 2 m air temperature (T2M) over central Asia in boreal winter during 1979-2012. During MJO phases 3 and 4 (7 and 8), T2M anomalies exhibit a significantly strong, negative (positive) response to the MJO from the Arabian Sea to northwestern China. The anomalies of T2M are essentially influenced by surface net downward long (Ldown) and shortwave radiations, which are caused by the changes in total cloud cover (TCC) and low-level tropospheric air temperature. The anomalies of Ldown that are caused by TCC account for 20-65% of total Ldown. The remaining anomalies of total Ldown are explained by low-level air temperature changes. The 850 hPa air temperature (T850) tendency is mainly affected by the vertical motion over central Asia during MJO phases 1, 2, 4-6, and 8, as well as over northern India during phases 3 and 7. Over Saudi Arabia, Afghanistan, Pakistan, Kazakhstan, and northwestern China, the anomalies of T850 tendency are mainly explained by the temperature advection during phases 3 and 7. TCC and vertical motion are affected by the evolution of the MJO event. The cyclonic (anticyclonic) circulation related to the MJO over central Asia during phases 3 and 4 (7 and 8) causes the transport of cold (warm) air over central Asia. The MJO can be a useful intraseasonal signal to predict winter T2M over central Asia, where temperatures would be colder (warmer) than normal during MJO phases 3 and 4 (7 and 8).

  8. Arrival time distributions of electrons in air showers with primary energies above 10 (18)eV observed at 900m above sea level

    NASA Technical Reports Server (NTRS)

    Kakimoto, F.; Tsuchimoto, I.; Enoki, T.; Suga, K.; Nishi, K.

    1985-01-01

    Detection of air showers with primary energies above 10 to the 19th power eV with sufficient statistics is extremely important in an astrophysical aspect related to the Greisen cut off and the origin of such high energy cosmic rays. Recently, a method is proposed to observe such giant air showers by measuring the arrival time distributions of air-shower particles at large core distances with a mini array. Experiments to measure the arrival time distributions of muons were started in 1981 and those of electrons in early 1983 in the Akeno air-shower array (930 gcm cm squared atmospheric depth, 900m above sea level). During the time of observation, the detection area of the Akeno array was expanded from 1 sq km to sq km in 1982 and to 20 sq km in 1984. Now the arrival time distribution of electrons and muons can be measured for showers with primary energies above 1019eV at large core distances.

  9. Feedbacks between Air Pollution and Weather, Part 2: Effects on Chemistry.

    EPA Science Inventory

    Fully-coupled air-quality models running in “feedback” and “no-feedback” configurations were compared against each other and observation network data as part of Phase 2 of the Air Quality Model Evaluation International Initiative. In the “no-feedback” mode, interactions between m...

  10. Evaluation of solid sorbents for the determination of fenhexamid, metalaxyl-M, pyrimethanil, malathion and myclobutanil residues in air samples: application to monitoring malathion and fenhexamid dissipation in greenhouse air using C-18 or Supelpak-2 for sampling.

    PubMed

    Tsiropoulos, Nikolaos G; Bakeas, Evangelos B; Raptis, Vasilios; Batistatou, Stavroula S

    2006-07-28

    A methodology is described for greenhouse air analysis by sampling fenhexamid, pyrimethanil, malathion, metalaxyl-M and myclobutanil in solid sorbents. Pesticides were determined by gas chromatography with NP Detector. The trapping efficiency of XAD-2, XAD-4, Supelpak-2, Florisil and C-18 at different sampling conditions (rate, time and air humidity) and pesticides concentration levels has been evaluated. No breakthrough was observed in the range of concentration studied (0.10-75 microg of each pesticide). In almost all the cases good stability results were obtained. Personal pumps have been used with selected sorbents (Supelpak-2 and C-18) in order to sample malathion and fenhexamid in air of experimental greenhouse after their application in a tomato crop. The dissipation process of the analytes in various time periods after application has been studied. Malathion concentrations varied between 20.1 microg m(-3) just after application and 1.06 microg m(-3) 3 days later. Fenhexamid concentrations, determined by high performance liquid chromatography with UV detection, fall rapidly; after 12 h post-application being below 0.50 microg m(-3).

  11. High-Resolution OH and CH2O Visualization in a Premixed Cavity-Anchored Ethylene-Air Flame in a M = 0.6 Flowfield

    NASA Technical Reports Server (NTRS)

    Geipel, Clayton M.; Rockwell, Robert D.; Chelliah, Harsha K.; Cutler, Andrew D.; Spelker, Christopher A.; Hashem, Zeid; Danehy, Paul M.

    2017-01-01

    OH and CH2O were imaged in a premixed, cavity-anchored, ethylene-air turbulent flame using a high resolution planar laser-induced fluorescence (PLIF) system. The electrically-heated, continuous flow facility (UVa Supersonic Combustion Facility, Configuration E) consisted of a Mach 2 nozzle, an isolator with fuel injectors, a test section with a cavity flame holder and optical access, and an extender. Standard test conditions comprised total temperature 1200 K, total pressure 300 kPa, local equivalence ratio near 0.4, and local Mach number near 0.6. OH PLIF data was also collected for a case with reduced total temperature and another with reduced equivalence ratio. OH and CH2O were excited in separate experiments with light sheets at 283.55 nm and 352.48 nm, respectively. A light sheet of approximate thickness 25 ?m illuminated the stream-wise midplane. This plane was imaged for 120 mm downstream of the backward-facing step. The intensified camera system imaged OH with magnification 1.97, a square 6.67 mm field of view, and in-plane resolution of 39 ?m. The smallest observed OH structures observed were approximately 100 ?m wide. The CH2O PLIF image signal was much weaker; the smallest observed structures were approximately 200 ?m wide. Composite fluorescence images were computed for the observed area.

  12. IUE observations of the 'Butterfly' Nebula M2-9

    NASA Technical Reports Server (NTRS)

    Feibelman, W. A.

    1984-01-01

    IUE observations of the peculiar 'Butterfy' nebula M2-9 indicate that it is not a normal planetary nebula. The ultraviolet spectrum is characterized by few emission lines and a weak continuum. Mg II 2800 A is the strongest emission line present and may be indicative of a binary nucleus. Lines of N v, Q I, N III, N IV, Si III, and C III are seen, but C IV and O III are conspicuous by their absence. T(e) = 10,250 + or - 400 K was determined for the core. Nitrogen in the core is found to be overabundant by about a factor of 5 over the solar value. M2-9 may be an object in the early stages of becoming a planetary nebula.

  13. Observational Analyses of Dramatic Developments of A Severe Air Pollution Event in the Beijing Area

    NASA Astrophysics Data System (ADS)

    Sun, J.; Li, J.; Zhou, M.; Cheng, Z.; Li, Q.; Cao, X.; Zhang, J.

    2017-12-01

    A rapid development of a severe air pollution event at the end of November, 2015 was investigated with in situ and remote sensing observations. The analyses indicate that the high PM2.5 air was transported over the urban area by the southwesterly flow above 500 m under the nighttime stable condition with its high concentration centered southeast of Beijing. As the daytime convective turbulent mixing developed over the Beijing urban area in the morning and it transported the upper polluted air downward, leading to the dramatic increase of the PM2.5 concentration in the urban area. Meanwhile, the convective turbulent mixing transported the highly polluted air upward upstream of Beijing, resulting in the horizontal transport of high PM2.5 air into Beijing especially in the afternoon when the stable boundary layer started to develop near the surface. As a result of both turbulent mixing and advection processes with possible aerosol growth from secondary aerosol formation under the low wind and high humidity condition, the PM2.5 concentration reached over 700 µg m-3 at Beijing by the end of the day.

  14. Use of Air Quality Observations by the National Air Quality Forecast Capability

    NASA Astrophysics Data System (ADS)

    Stajner, I.; McQueen, J.; Lee, P.; Stein, A. F.; Kondragunta, S.; Ruminski, M.; Tong, D.; Pan, L.; Huang, J. P.; Shafran, P.; Huang, H. C.; Dickerson, P.; Upadhayay, S.

    2015-12-01

    The National Air Quality Forecast Capability (NAQFC) operational predictions of ozone and wildfire smoke for the United States (U.S.) and predictions of airborne dust for continental U.S. are available at http://airquality.weather.gov/. NOAA National Centers for Environmental Prediction (NCEP) operational North American Mesoscale (NAM) weather predictions are combined with the Community Multiscale Air Quality (CMAQ) model to produce the ozone predictions and test fine particulate matter (PM2.5) predictions. The Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model provides smoke and dust predictions. Air quality observations constrain emissions used by NAQFC predictions. NAQFC NOx emissions from mobile sources were updated using National Emissions Inventory (NEI) projections for year 2012. These updates were evaluated over large U.S. cities by comparing observed changes in OMI NO2 observations and NOx measured by surface monitors. The rate of decrease in NOx emission projections from year 2005 to year 2012 is in good agreement with the observed changes over the same period. Smoke emissions rely on the fire locations detected from satellite observations obtained from NESDIS Hazard Mapping System (HMS). Dust emissions rely on a climatology of areas with a potential for dust emissions based on MODIS Deep Blue aerosol retrievals. Verification of NAQFC predictions uses AIRNow compilation of surface measurements for ozone and PM2.5. Retrievals of smoke from GOES satellites are used for verification of smoke predictions. Retrievals of dust from MODIS are used for verification of dust predictions. In summary, observations are the basis for the emissions inputs for NAQFC, they are critical for evaluation of performance of NAQFC predictions, and furthermore they are used in real-time testing of bias correction of PM2.5 predictions, as we continue to work on improving modeling and emissions important for representation of PM2.5.

  15. Intercomparison of AIRS and HIRDLS stratospheric gravity wave observations

    NASA Astrophysics Data System (ADS)

    Meyer, Catrin I.; Ern, Manfred; Hoffmann, Lars; Trinh, Quang Thai; Alexander, M. Joan

    2018-01-01

    We investigate stratospheric gravity wave observations by the Atmospheric InfraRed Sounder (AIRS) aboard NASA's Aqua satellite and the High Resolution Dynamics Limb Sounder (HIRDLS) aboard NASA's Aura satellite. AIRS operational temperature retrievals are typically not used for studies of gravity waves, because their vertical and horizontal resolution is rather limited. This study uses data of a high-resolution retrieval which provides stratospheric temperature profiles for each individual satellite footprint. Therefore the horizontal sampling of the high-resolution retrieval is 9 times better than that of the operational retrieval. HIRDLS provides 2-D spectral information of observed gravity waves in terms of along-track and vertical wavelengths. AIRS as a nadir sounder is more sensitive to short-horizontal-wavelength gravity waves, and HIRDLS as a limb sounder is more sensitive to short-vertical-wavelength gravity waves. Therefore HIRDLS is ideally suited to complement AIRS observations. A calculated momentum flux factor indicates that the waves seen by AIRS contribute significantly to momentum flux, even if the AIRS temperature variance may be small compared to HIRDLS. The stratospheric wave structures observed by AIRS and HIRDLS often agree very well. Case studies of a mountain wave event and a non-orographic wave event demonstrate that the observed phase structures of AIRS and HIRDLS are also similar. AIRS has a coarser vertical resolution, which results in an attenuation of the amplitude and coarser vertical wavelengths than for HIRDLS. However, AIRS has a much higher horizontal resolution, and the propagation direction of the waves can be clearly identified in geographical maps. The horizontal orientation of the phase fronts can be deduced from AIRS 3-D temperature fields. This is a restricting factor for gravity wave analyses of limb measurements. Additionally, temperature variances with respect to stratospheric gravity wave activity are compared on a

  16. Zn/gelled 6 M KOH/O 2 zinc-air battery

    NASA Astrophysics Data System (ADS)

    Mohamad, A. A.

    The gel electrolyte for the zinc-air cell was prepared by mixing hydroponics gel with a 6 M potassium hydroxide aqueous solution. The self-discharge of cells was characterized by measuring the open-circuit voltage. The effect of a discharge rate of 50 mA constant current on cell voltage and plateau hour, as well as the voltage-current and current density-power density were measured and analysed. The electrode degradation after discharge cycling was characterized by structural and surface methods. The oxidation of the electrode surface further blocked the utilization of the Zn anode and was identified as a cause for the failure of the cell.

  17. Observations of a bi-directional lightning leader producing an M-component

    NASA Astrophysics Data System (ADS)

    Kotovsky, D. A.; Uman, M. A.; Wilkes, R.; Carvalho, F. L.; Jordan, D. M.

    2017-12-01

    Lightning discharges to ground often exhibit millisecond-scale surges in the continuing currents following return strokes, called M-components. Relatively little is known regarding the source of M-component charge and the mechanisms by which that charge is transferred to ground. In this work, we seek to directly address these questions by presenting correlated high-speed video and Lightning Mapping Array (LMA) observations of a bi-directional leader that resulted in an M-component occurring in a rocket-and-wire triggered lightning flash. The observed leader initiated in the decayed remnants of a positive leader channel that had traversed virgin air approximately 90 msec prior. Three-dimensional locations and speeds of the photographed bi-directional leader and M-component processes are calculated by mapping video images to the observed LMA channel geometry. Both ends of the bi-directional leader exhibited speeds on the order of 2 x106 m sec-1 over 570 meters of the visible channel. Propagation of the luminosity wave from the in-cloud leader to ground ( 8.8 km channel length) exhibited appreciable dispersion, with rise-times (10-90%) increasing from 330 to 410 μsec and pulse-widths (half-maximum) increasing from 380 to 810 μsec - the M-component current pulse measured at ground-level exhibited a rise-time of 290 μsec and a pulse-width of 770 μsec. Group velocities of the luminosity wave have been calculated as a function of frequency, increasing from 2 x107 to 6 x107 m sec-1 over the dominant signal bandwidth (DC to 2 kHz). Additionally, multiple waves of luminosity are observed within the in-cloud channel, indicating nuanced wave phenomena possibly associated with reflection from the end of the leader channel and attachment with the main lightning channel carrying continuing current to ground.

  18. Analysis of air quality with numerical simulation (CMAQ), and observations of trace gases

    NASA Astrophysics Data System (ADS)

    Castellanos, Patricia

    carried out using aircraft observations taken for the Regional Atmospheric Measurement, Modeling and Prediction Program (RAMMPP) in the summer of 2002. Comparison of modeled and observed CO total columns were generally in agreement within 5-10%. There is little evidence that the CO emissions inventory is grossly overestimated. CMAQ predicts the same vertical profile shape for all of the observations, i.e. CO is well mixed throughout the boundary layer. However, the majority of observations have poorly mixed air below 500 m, and well mixed air above. CMAQ appears to be transporting CO away from the surface more quickly than what is observed. Turbulent mixing in the model is represented with K-theory. A minimum Kz that scales with fractional urban land use is imposed in order to account for subgrid scale obstacles in urban areas and the urban heat island effect. Micrometeorological observations suggest that the minimum Kz is somewhat high. A sensitivity case where the minimum K z was reduced from 0.5 m2/s to 0.1 m2/s was carried out. Model performance of surface ozone observations at night increased significantly. The model better captures the observed ozone minimum with slower mixing, and increases ozone concentrations in the residual layer. Model performance of CO and ozone morning vertical profiles improves, but the effect is not large enough to bring the model and measurements into agreement. Comparison of modeled CO and O3 vertical profiles shows that turbulent mixing (as represented by eddy diffusivity) appears to be too fast, while convective mixing may be too slow.

  19. Nitrogen fluorescence in air for observing extensive air showers

    NASA Astrophysics Data System (ADS)

    Keilhauer, B.; Bohacova, M.; Fraga, M.; Matthews, J.; Sakaki, N.; Tameda, Y.; Tsunesada, Y.; Ulrich, A.

    2013-06-01

    Extensive air showers initiate the fluorescence emissions from nitrogen molecules in air. The UV-light is emitted isotropically and can be used for observing the longitudinal development of extensive air showers in the atmosphere over tenth of kilometers. This measurement technique is well-established since it is exploited for many decades by several cosmic ray experiments. However, a fundamental aspect of the air shower analyses is the description of the fluorescence emission in dependence on varying atmospheric conditions. Different fluorescence yields affect directly the energy scaling of air shower reconstruction. In order to explore the various details of the nitrogen fluorescence emission in air, a few experimental groups have been performing dedicated measurements over the last decade. Most of the measurements are now finished. These experimental groups have been discussing their techniques and results in a series of Air Fluorescence Workshops commenced in 2002. At the 8th Air Fluorescence Workshop 2011, it was suggested to develop a common way of describing the nitrogen fluorescence for application to air shower observations. Here, first analyses for a common treatment of the major dependences of the emission procedure are presented. Aspects like the contributions at different wavelengths, the dependence on pressure as it is decreasing with increasing altitude in the atmosphere, the temperature dependence, in particular that of the collisional cross sections between molecules involved, and the collisional de-excitation by water vapor are discussed.

  20. Direct observation of the M2 phase with its Mott transition in a VO2 film

    NASA Astrophysics Data System (ADS)

    Kim, Hoon; Slusar, Tetiana V.; Wulferding, Dirk; Yang, Ilkyu; Cho, Jin-Cheol; Lee, Minkyung; Choi, Hee Cheul; Jeong, Yoon Hee; Kim, Hyun-Tak; Kim, Jeehoon

    2016-12-01

    In VO2, the explicit origin of the insulator-to-metal transition is still disputable between Peierls and Mott insulators. Along with the controversy, its second monoclinic (M2) phase has received considerable attention due to the presence of electron correlation in undimerized vanadium ions. However, the origin of the M2 phase is still obscure. Here, we study a granular VO2 film using conductive atomic force microscopy and Raman scattering. Upon the structural transition from monoclinic to rutile, we observe directly an intermediate state showing the coexistence of monoclinic M1 and M2 phases. The conductivity near the grain boundary in this regime is six times larger than that of the grain core, producing a donut-like landscape. Our results reveal an intra-grain percolation process, indicating that VO2 with the M2 phase is a Mott insulator.

  1. M2-F2 on ramp

    NASA Image and Video Library

    1966-02-24

    The M2-F2 Lifting Body is seen here on the ramp at the NASA Dryden Flight Research Center. The success of Dryden's M2-F1 program led to NASA's development and construction of two heavyweight lifting bodies based on studies at NASA's Ames and Langley research centers -- the M2-F2 and the HL-10, both built by the Northrop Corporation. The "M" refers to "manned" and "F" refers to "flight" version. "HL" comes from "horizontal landing" and 10 is for the tenth lifting body model to be investigated by Langley. The first flight of the M2-F2 -- which looked much like the "F1" -- was on July 12, 1966. Milt Thompson was the pilot. By then, the same B-52 used to air launch the famed X-15 rocket research aircraft was modified to also carry the lifting bodies. Thompson was dropped from the B-52's wing pylon mount at an altitude of 45,000 feet on that maiden glide flight. The M2-F2 weighed 4,620 pounds, was 22 feet long, and had a width of about 10 feet. On May 10, 1967, during the sixteenth glide flight leading up to powered flight, a landing accident severely damaged the vehicle and seriously injured the NASA pilot, Bruce Peterson. NASA pilots and researchers realized the M2-F2 had lateral control problems, even though it had a stability augmentation control system. When the M2-F2 was rebuilt at Dryden and redesignated the M2-F3, it was modified with an additional third vertical fin -- centered between the tip fins -- to improve control characteristics. The M2-F2/F3 was the first of the heavy-weight, entry-configuration lifting bodies. Its successful development as a research test vehicle answered many of the generic questions about these vehicles. NASA donated the M2-F3 vehicle to the Smithsonian Institute in December 1973. It is currently hanging in the Air and Space Museum along with the X-15 aircraft number 1, which was its hangar partner at Dryden from 1965 to 1969.

  2. Observation of Multi-TeV Gamma Rays from the Crab Nebula using the Tibet Air Shower Array.

    PubMed

    Amenomori; Ayabe; Cao; Danzengluobu; Ding; Feng; Fu; Guo; He; Hibino; Hotta; Huang; Huo; Izu; Jia; Kajino; Kasahara; Katayose; Labaciren; Li; Lu; Lu; Luo; Meng; Mizutani; Mu; Nanjo; Nishizawa; Ohnishi; Ohta; Ouchi; Ren; Saito; Sakata; Sasaki; Shi; Shibata; Shiomi; Shirai; Sugimoto; Taira; Tan; Tateyama; Torii; Utsugi; Wang; Wang; Xu; Yamamoto; Yu; Yuan; Yuda; Zhang; Zhang; Zhang; Zhang; Zhang; Zhaxisangzhu; Zhaxiciren; Zhou; Collaboration)

    1999-11-10

    The Tibet experiment, operating at Yangbajing (4300 m above sea level), is the lowest energy air shower array, and the new high-density array constructed in 1996 is sensitive to gamma-ray air showers at energies as low as 3 TeV. With this new array, the Crab Nebula was observed in multi-TeV gamma-rays and a signal was detected at the 5.5 sigma level. We also obtained the energy spectrum of gamma-rays in the energy region above 3 TeV which partially overlaps those observed with imaging atmospheric Cerenkov telescopes. The Crab spectrum observed in this energy region can be represented by the power-law fit dJ&parl0;E&parr0;&solm0;dE=&parl0;4.61+/-0.90&parr0;x10-12&parl0;E&solm0;3 TeV&parr0;-2.62+/-0.17 cm-2 s-1 TeV-1. This is the first observation of gamma-ray signals from point sources with a conventional air shower array using scintillation detectors.

  3. Traffic Impacts on PM2.5 Air Quality in Nairobi, Kenya

    PubMed Central

    Kinney, Patrick L.; Gichuru, Michael Gatari; Volavka-Close, Nicole; Ngo, Nicole; Ndiba, Peter K.; Law, Anna; Gachanja, Anthony; Gaita, Samuel Mwaniki; Chillrud, Steven N.; Sclar, Elliott

    2011-01-01

    Motor vehicle traffic is an important source of particulate pollution in cities of the developing world, where rapid growth, coupled with a lack of effective transport and land use planning, may result in harmful levels of fine particles (PM2.5) in the air. However, a lack of air monitoring data hinders health impact assessments and the development of transportation and land use policies that could reduce health burdens due to outdoor air pollution. To address this important need, a study of traffic-related PM2.5 was carried out in the city of Nairobi, Kenya, a model city for sub-Saharan Africa, in July 2009. Sampling was carried out using portable filter-based air samplers carried in backpacks by technicians on weekdays over two weeks at several sites in and around Nairobi ranging from high-traffic roadways to rural background. Mean daytime concentrations of PM2.5 ranged from 10.7 at the rural background site to 98.1 μg/m3 on a sidewalk in the central business district. Horizontal dispersion measurements demonstrated a decrease in PM2.5 concentration from 128.7 to 18.7 μg/m3 over 100 meters downwind of a major intersection in Nairobi. A vertical dispersion experiment revealed a decrease from 119.5 μg/m3 at street level to 42.8 μg/m3 on a third-floor rooftop in the central business district. Though not directly comparable to air quality guidelines, which are based on 24-hour or annual averages, the urban concentrations we observed raise concern with regard to public health and related policy. Taken together with survey data on commuting patterns within Nairobi, these results suggest that many Nairobi residents are exposed on a regular basis to elevated concentrations of fine particle air pollution, with potentially serious long-term implications for health. PMID:21779151

  4. Overview of NASA's Observations for Global Air Quality

    NASA Astrophysics Data System (ADS)

    Kaye, J. A.

    2015-12-01

    Observations of pollutants are central to the study of air quality. Much focus has been placed on local-scale observations that can help specific geographic areas document their air quality issues, plan abatement strategies, and understand potential impacts. In addition, long-range atmospheric transport of pollutants can cause downwind regions to not meet attainment standards. Satellite observations have shed significant light on air quality from local to regional to global scales, especially for pollutants such as ozone, aerosols, carbon monoxide, sulfur dioxide, and nitrogen dioxide. These observations have made use of multiple techniques and in some cases multiple satellite sensors. The satellite observations are complemented by surface observations, as well as atmospheric (in situ) observations typically made as part of focused airborne field campaigns. The synergy between satellite observations and field campaigns has been an important theme for recent and upcoming activities and plans. In this talk, a review of NASA's investments in observations relevant to global air quality will be presented, with examples given for a range of pollutants and measurement approaches covering the last twenty-five years. These investments have helped build national and international collaborations such that the global satellite community is now preparing to deploy a constellation of satellites that together will provide fundamental advances in global observations for air quality.

  5. Observed Screen (Air) and GCM Surface/Screen Temperatures: Implications for Outgoing Longwave Fluxes at the Surface.

    NASA Astrophysics Data System (ADS)

    Garratt, J. R.

    1995-05-01

    There is direct evidence that excess net radiation calculated in general circulation models at continental surfaces [of about 11-17 W m2 (20%-27%) on an annual ~1 is not only due to overestimates in annual incoming shortwave fluxes [of 9-18 W m2 (6%-9%)], but also to underestimates in outgoing longwave fluxes. The bias in the outgoing longwave flux is deduced from a comparison of screen-air temperature observations, available as a global climatology of mean monthly values, and model-calculated surface and screen-air temperatures. An underestimate in the screen temperature computed in general circulation models over continents, of about 3 K on an annual basis, implies an underestimate in the outgoing longwave flux, averaged in six models under study, of 11-15 W m2 (3%-4%). For a set of 22 inland stations studied previously, the residual bias on an annual basis (the residual is the net radiation minus incoming shortwave plus outgoing longwave) varies between 18 and 23 W m2 for the models considered. Additional biases in one or both of the reflected shortwave and incoming longwave components cannot be ruled out.

  6. M2-F2 cockpit instrument panels

    NASA Image and Video Library

    1966-03-27

    This photo shows the right side cockpit instrumentation panel of the M2-F2 Lifting Body. The success of Dryden's M2-F1 program led to NASA's development and construction of two heavyweight lifting bodies based on studies at NASA's Ames and Langley research centers -- the M2-F2 and the HL-10, both built by the Northrop Corporation. The "M" refers to "manned" and "F" refers to "flight" version. "HL" comes from "horizontal landing" and 10 is for the tenth lifting body model to be investigated by Langley. The first flight of the M2-F2 -- which looked much like the "F1" -- was on July 12, 1966. Milt Thompson was the pilot. By then, the same B-52 used to air launch the famed X-15 rocket research aircraft was modified to also carry the lifting bodies. Thompson was dropped from the B-52's wing pylon mount at an altitude of 45,000 feet on that maiden glide flight. The M2-F2 weighed 4,620 pounds, was 22 feet long, and had a width of about 10 feet. On May 10, 1967, during the sixteenth glide flight leading up to powered flight, a landing accident severely damaged the vehicle and seriously injured the NASA pilot, Bruce Peterson. NASA pilots and researchers realized the M2-F2 had lateral control problems, even though it had a stability augmentation control system. When the M2-F2 was rebuilt at Dryden and redesignated the M2-F3, it was modified with an additional third vertical fin -- centered between the tip fins -- to improve control characteristics. The M2-F2/F3 was the first of the heavy-weight, entry-configuration lifting bodies. Its successful development as a research test vehicle answered many of the generic questions about these vehicles. NASA donated the M2-F3 vehicle to the Smithsonian Institute in December 1973. It is currently hanging in the Air and Space Museum along with the X-15 aircraft number 1, which was its hangar partner at Dryden from 1965 to 1969.

  7. M2-F2 cockpit instrument panels

    NASA Image and Video Library

    1966-03-27

    This photo shows the left side cockpit instrumentation panel of the M2-F2 Lifting Body. The success of Dryden's M2-F1 program led to NASA's development and construction of two heavyweight lifting bodies based on studies at NASA's Ames and Langley research centers -- the M2-F2 and the HL-10, both built by the Northrop Corporation. The "M" refers to "manned" and "F" refers to "flight" version. "HL" comes from "horizontal landing" and 10 is for the tenth lifting body model to be investigated by Langley. The first flight of the M2-F2 -- which looked much like the "F1" -- was on July 12, 1966. Milt Thompson was the pilot. By then, the same B-52 used to air launch the famed X-15 rocket research aircraft was modified to also carry the lifting bodies. Thompson was dropped from the B-52's wing pylon mount at an altitude of 45,000 feet on that maiden glide flight. The M2-F2 weighed 4,620 pounds, was 22 feet long, and had a width of about 10 feet. On May 10, 1967, during the sixteenth glide flight leading up to powered flight, a landing accident severely damaged the vehicle and seriously injured the NASA pilot, Bruce Peterson. NASA pilots and researchers realized the M2-F2 had lateral control problems, even though it had a stability augmentation control system. When the M2-F2 was rebuilt at Dryden and redesignated the M2-F3, it was modified with an additional third vertical fin -- centered between the tip fins -- to improve control characteristics. The M2-F2/F3 was the first of the heavy-weight, entry-configuration lifting bodies. Its successful development as a research test vehicle answered many of the generic questions about these vehicles. NASA donated the M2-F3 vehicle to the Smithsonian Institute in December 1973. It is currently hanging in the Air and Space Museum along with the X-15 aircraft number 1, which was its hangar partner at Dryden from 1965 to 1969.

  8. Observation of regional air pollutant transport between the megacity Beijing and the North China Plain

    NASA Astrophysics Data System (ADS)

    Li, Yingruo; Ye, Chunxiang; Liu, Jun; Zhu, Yi; Wang, Junxia; Tan, Ziqiang; Lin, Weili; Zeng, Limin; Zhu, Tong

    2016-11-01

    Megacities have strong interactions with the surrounding regions through transport of air pollutants. It has been frequently addressed that the air quality of Beijing is influenced by the influx of air pollutants from the North China Plain (NCP). Estimations of air pollutant cross-boundary transport between Beijing and the NCP are important for air quality management. However, evaluation of cross-boundary transport using long-term observations is very limited. Using the observational results of the gaseous pollutants SO2, NO, NO2, O3, and CO from August 2006 to October 2008 at the Yufa site, a cross-boundary site between the megacity Beijing and the NCP, together with meteorological parameters, we explored a method for evaluating the transport flux intensities at Yufa, as part of the "Campaign of Air Quality Research in Beijing and Surrounding Region 2006-2008" (CAREBeijing 2006-2008). The hourly mean ± SD (median) concentration of SO2, NO, NO2, NOx, O3, Ox, and CO was 15 ± 16 (9) ppb, 12 ± 25 (3) ppb, 24 ± 19 (20) ppb, 36 ± 39 (23) ppb, 28 ± 27 (21) ppb, 52 ± 24 (45) ppb, and 1.6 ± 1.4 (1.2) ppm during the observation period, respectively. The bivariate polar plots showed the dependence of pollutant concentrations on both wind speed and wind direction, and thus inferred their dominant transport directions. Surface flux intensity calculations further demonstrated the regional transport influence of Beijing and the NCP on Yufa. The net surface transport flux intensity (mean ± SD) of SO2, NO, NO2, NOx, O3, Ox, and CO was 6.2 ± 89.5, -4.3 ± 29.5, -0.6 ± 72.3, -4.9 ± 93.0, 14.7 ± 187.8, 14.8 ± 234.9, and 70 ± 2830 µg s-1 m-2 during the observation period, respectively. For SO2, CO, O3, and Ox the surface flux intensities from the NCP to Yufa surpassed those from Beijing to Yufa in all seasons except winter, with the strongest net fluxes largely in summer, which were about 4-8 times those of other seasons. The surface transport flux intensity of NOx

  9. Intercomparison of Recent Anomaly Time-Series of OLR as Observed by CERES and Computed Using AIRS Products

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Molnar, Gyula; Iredell, Lena; Loeb, Norman G.

    2011-01-01

    This paper compares recent spatial and temporal anomaly time series of OLR as observed by CERES and computed based on AIRS retrieved surface and atmospheric geophysical parameters over the 7 year time period September 2002 through February 2010. This time period is marked by a substantial decrease of OLR, on the order of +/-0.1 W/sq m/yr, averaged over the globe, and very large spatial variations of changes in OLR in the tropics, with local values ranging from -2.8 W/sq m/yr to +3.1 W/sq m/yr. Global and Tropical OLR both began to decrease significantly at the onset of a strong La Ni a in mid-2007. Late 2009 is characterized by a strong El Ni o, with a corresponding change in sign of both Tropical and Global OLR anomalies. The spatial patterns of the 7 year short term changes in AIRS and CERES OLR have a spatial correlation of 0.97 and slopes of the linear least squares fits of anomaly time series averaged over different spatial regions agree on the order of +/-0.01 W/sq m/yr. This essentially perfect agreement of OLR anomaly time series derived from observations by two different instruments, determined in totally independent and different manners, implies that both sets of results must be highly stable. This agreement also validates the anomaly time series of the AIRS derived products used to compute OLR and furthermore indicates that anomaly time series of AIRS derived products can be used to explain the factors contributing to anomaly time series of OLR.

  10. Technology Needs Assessment of an Atmospheric Observation System for Multidisciplinary Air Quality/Meteorology Missions, Part 2

    NASA Technical Reports Server (NTRS)

    Alvarado, U. R.; Bortner, M. H.; Grenda, R. N.; Brehm, W. F.; Frippel, G. G.; Alyea, F.; Kraiman, H.; Folder, P.; Krowitz, L.

    1982-01-01

    The technology advancements that will be necessary to implement the atmospheric observation systems are considered. Upper and lower atmospheric air quality and meteorological parameters necessary to support the air quality investigations were included. The technology needs were found predominantly in areas related to sensors and measurements of air quality and meteorological measurements.

  11. Discovery of New Coronal Lines at 2.843 and 2.853 μm

    NASA Astrophysics Data System (ADS)

    Samra, Jenna E.; Judge, Philip G.; DeLuca, Edward E.; Hannigan, James W.

    2018-04-01

    Two new emission features were observed during the 2017 August 21 total solar eclipse by a novel spectrometer, the Airborne Infrared Spectrometer (AIR-Spec), flown at 14.3 km altitude aboard the NCAR Gulfstream-V aircraft. We derive wavelengths in air of 2.8427 ± 0.00009 μm and 2.8529 ± 0.00008 μm. One of these lines belongs to the 3{{{p}}}53{{d}}{}3{{{F}}}3^\\circ \\to 3{{{p}}}53{{d}}{}3{{{F}}}4^\\circ transition in Ar-like Fe IX. This appears to be the first detection of this transition from any source. Minimization of residual wavelength differences using both measured wavelengths, together with National Institute of Standards and Technology (NIST) extreme ultraviolet wavelengths, does not clearly favor assignment to Fe IX. However, the shorter wavelength line appears more consistent with other observed features formed at similar temperatures to Fe IX. The transition occurs between two levels within the excited 3{{{p}}}53{{d}} configuration, 429,000 cm‑1 above the ground level. The line is therefore absent in photo-ionized coronal-line astrophysical sources such as the Circinus Galaxy. Data from a Fourier transform interferometer (FTIR) deployed from Wyoming show that both lines are significantly attenuated by telluric H2O, even at dry sites. We have been unable to identify the longer wavelength transition.

  12. Validation of Mode-S Meteorological Routine Air Report aircraft observations

    NASA Astrophysics Data System (ADS)

    Strajnar, B.

    2012-12-01

    The success of mesoscale data assimilation depends on the availability of three-dimensional observations with high spatial and temporal resolution. This paper describes an example of such observations, available through Mode-S air traffic control system composed of ground radar and transponders on board the aircraft. The meteorological information is provided by interrogation of a dedicated meteorological data register, called Meteorological Routine Air Report (MRAR). MRAR provides direct measurements of temperature and wind, but is only returned by a small fraction of aircraft. The quality of Mode-S MRAR data, collected at the Ljubljana Airport, Slovenia, is assessed by its comparison with AMDAR and high-resolution radiosonde data sets, which enable high- and low-level validation, respectively. The need for temporal smoothing of raw Mode-S MRAR data is also studied. The standard deviation of differences between smoothed Mode-S MRAR and AMDAR is 0.35°C for temperature, 0.8 m/s for wind speed and below 10 degrees for wind direction. The differences with respect to radiosondes are larger, with standard deviations of approximately 1.7°C, 3 m/s and 25 degrees for temperature, wind speed and wind direction, respectively. It is concluded that both wind and temperature observations from Mode-S MRAR are accurate and therefore potentially very useful for data assimilation in numerical weather prediction models.

  13. Trend in Air Quality of Kathmandu Valley: A Satellite, Observation and Modelling Perspective

    NASA Astrophysics Data System (ADS)

    Mahapatra, P. S.; Praveen, P. S.; Adhikary, B.; Panday, A. K.; Putero, D.; Bonasoni, P.

    2016-12-01

    Kathmandu (floor area of 340 km2) in Nepal is considered to be a `hot spot' of urban air pollution in South Asia. Its structure as a flat basin surrounded by tall mountains provides a unique case study for analyzing pollution trapped by topography. Only a very small number of cities with similar features have been studied extensively including Mexico and Santiago-de-Chile. This study presents the trend in satellite derived Aerosol Optical Depth (AOD) from MODIS AQUA and TERRA (3x3km, Level 2) over Kathmandu from 2000 to 2015. Trend analysis of AOD shows 35% increase during the study period. Determination of the background pollution would reveal the contribution of only Kathmandu Valley for the observation period. For this, AOD at 1340m altitude outside Kathmandu, but nearby areas were considered as background. This analysis was further supported by investigating AOD at different heights around Kathmandu as well as determining AOD from CALIPSO vertical profiles. These analysis suggest that background AOD contributed 30% in winter and 60% in summer to Kathmandu Valley's observed AOD. Thereafter the background AOD was subtracted from total Kathmandu AOD to determine contribution of only Kathmandu Valley's AOD. Trend analysis of only Kathmandu Valley AOD (subtracting background AOD) suggested an increase of 50% during the study period. Further analysis of Kathmandu's visibility and AOD suggest profound role of background AOD on decreasing visibility. In-situ Black Carbon (BC) mass concentration measurements (BC being used as a proxy for surface observations) at two sites within Kathmandu valley have been analyzed. Kathmandu valley lacks long term trends of ambient air quality measurement data. Therefore, surface observations would be coupled with satellite measurements for understanding the urban air pollution scenario. Modelling studies to estimate the contribution of background pollution to Kathmandu's own pollution as well as the weekend effect on air quality will

  14. Air Modeling - Observational Meteorological Data

    EPA Pesticide Factsheets

    Observed meteorological data for use in air quality modeling consist of physical parameters that are measured directly by instrumentation, and include temperature, dew point, wind direction, wind speed, cloud cover, cloud layer(s), ceiling height,

  15. Spectroscopic Observation of Water-Mediated Deformation of the CARBOXYLATE-M2+ (M= Mg, Ca) Contact Ion Pair

    NASA Astrophysics Data System (ADS)

    Kelleher, Patrick J.; DePalma, Joseph W.; Johnson, Mark

    2016-06-01

    The binding of alkaline earth dications to the biologically relevant carboxylate ligand has previously been studied using vibrational sum frequency generation (VSFG) spectroscopy of the air-water interface, infrared multiple photon dissociation (IRMPD) spectroscopy of clusters, and DFT methods. These results suggest the presence of both monodentate and bidentate binding motifs of the M2+ ions to the cayboxyl head groups depending on the extent of solvation. We revisit these systems using vibrational predissociation spectroscopy to measure the gas-phase vibrational spectra of the D2-tagged microhydrated [MgOAc(H2O)n=1-5]+ and [CaOAc(H2O)n=1-6]+ clusters. The spectra show that [MgOAc(H2O)n]+ switches from bidentate to monodentate binding promptly at n = 5, while [CaOAc(H2O)n]+ retains its bidentate attachment such that the sixth water molecule initiates the second solvation shell. The difference in binding behavior between these two divalent metal ions is analyzed in the context of the local acidity of the solvent water molecules and the strength of the metal-carboxylate and metal-water interactions. This cluster study provides insight into the chemical physics underlying the unique and surprising impacts of Mg2+ and Ca2+ on the chemistry mediated by sea spray aerosols. Funding for this work was provided by the NSF's Center for Aerosol Impacts on Climate and the Environment.

  16. Evaluation of Observation-Fused Regional Air Quality Model Results for Population Air Pollution Exposure Estimation

    PubMed Central

    Chen, Gang; Li, Jingyi; Ying, Qi; Sherman, Seth; Perkins, Neil; Rajeshwari, Sundaram; Mendola, Pauline

    2014-01-01

    In this study, Community Multiscale Air Quality (CMAQ) model was applied to predict ambient gaseous and particulate concentrations during 2001 to 2010 in 15 hospital referral regions (HRRs) using a 36-km horizontal resolution domain. An inverse distance weighting based method was applied to produce exposure estimates based on observation-fused regional pollutant concentration fields using the differences between observations and predictions at grid cells where air quality monitors were located. Although the raw CMAQ model is capable of producing satisfying results for O3 and PM2.5 based on EPA guidelines, using the observation data fusing technique to correct CMAQ predictions leads to significant improvement of model performance for all gaseous and particulate pollutants. Regional average concentrations were calculated using five different methods: 1) inverse distance weighting of observation data alone, 2) raw CMAQ results, 3) observation-fused CMAQ results, 4) population-averaged raw CMAQ results and 5) population-averaged fused CMAQ results. It shows that while O3 (as well as NOx) monitoring networks in the HRR regions are dense enough to provide consistent regional average exposure estimation based on monitoring data alone, PM2.5 observation sites (as well as monitors for CO, SO2, PM10 and PM2.5 components) are usually sparse and the difference between the average concentrations estimated by the inverse distance interpolated observations, raw CMAQ and fused CMAQ results can be significantly different. Population-weighted average should be used to account spatial variation in pollutant concentration and population density. Using raw CMAQ results or observations alone might lead to significant biases in health outcome analyses. PMID:24747248

  17. AIRS Water Vapor and Cloud Products Validate and Explain Recent Negative Global and Tropical OLR Trends Observed by CERES

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Molnar, Gyula; Iredell, Lena

    2010-01-01

    This paper compares spatial and temporal anomalies and trends of OLR as observed by CERES and computed based on AIRS retrieved surface and atmospheric geophysical parameters over the time period September 2002 February 2010. This time period is marked by a substantial decreasing OLR trend on the order of -0.1 W/m2/yr averaged over the globe. There are very large spatial variations of these trends however, with local values ranging from -2.6 W/m2/yr to +3.0 W/m2/yr in the tropics. The spatial patterns of the AIRS and CERES trends are in essentially perfect agreement with each other, as are the anomaly time series averaged over different spatial regions. This essentially perfect agreement of OLR anomalies and trends derived from observations by two different instruments, in totally independent and different manners, implies that both sets of results must be highly accurate. The agreement of anomalies and trends of OLR as observed by CERES and computed from AIRS derived products also indirectly validates the anomalies and trends of the AIRS derived products as well. We used the anomalies and trends of AIRS derived water vapor and cloud products to explain why global OLR has had a large negative trend over the time period September 2002 through February 2010. Tropical OLR began to decrease significantly at the onset of a strong La Nina in mid-2007. AIRS products show that cloudiness and mid-tropospheric water vapor began to increase in the region 5degN - 20degS latitude extending eastward from 150degW - 30 E longitude at that time, with a corresponding very large drop in OLR in this region. Late 2009 is characterized by a strong El-Nino, with a corresponding change in sign of observed anomalies of mid-tropospheric water vapor, cloud cover, and OLR in this region, as we] l as that of OLR anomalies in the tropics and globally. Monthly mean anomalies of OLR, water vapor and cloud cover over this region are all shown to be highly correlated in time with those of an El Nino

  18. Improved Specification of Transboundary Air Pollution over the Gulf of Mexico Using Satellite Observations

    NASA Astrophysics Data System (ADS)

    Pour Biazar, A.; Khan, M. N.; Park, Y. H.; McNider, R. T.; Cameron, B.

    2010-12-01

    The assessment of potential environmental impact of oil and gas operations in the Gulf of Mexico (GoM) and in particular the onshore air quality impact of such operations is important to State and Federal regulatory agencies. In adapting sound policies for control strategies, it is crucial to assess the impact of local pollution versus transboundary air pollution, and in a region such as GoM with scarce monitoring capability over open waters such distinctions represents a challenge. Furthermore, GoM region can be impacted by the recirculation of pollution in the southeastern United States. The current study examines the efficacy of utilizing the newly available satellite observations of aerosols and trace gases in air quality impacts assessment for addressing these issues. In particular, ozone profiles from the Tropospheric Emission Spectrometer (TES) and Ozone Monitoring Instrument (OMI) onboard Aura and aerosol products from Moderate Resolution Imaging Spectroradiometer (MODIS) onboard Terra and Aqua satellites were utilized in a modeling study during August 2006. The satellite observations were used in the specification of the background and lateral boundary and also once daily for the re-adjustment of the concentration fields. The results were then evaluated against ozonesonde and surface observations. The utilization of OMI ozone profiles significantly improved model performance in the free troposphere and the use of MODIS aerosol products substantially enhanced model prediction of aerosols in the boundary layer. Neither OMI nor TES provide adequate information in the boundary layer with respect to O3 and as a result they can only marginally impact ozone predictions in the boundary layer. The utilization of the satellite data for lateral boundary condition (BC) was helpful in the realization of transboundary transport of pollution. The hypothesis that the recirculation of pollution from Northeast Corridor can play a role over the Gulf of Mexico was tested and

  19. EPA AirNow Satellite Data Processor (ASDP) for Improving Air Quality Information

    NASA Astrophysics Data System (ADS)

    White, J. E.; Dickerson, P.; Szykman, J.; Chu, D.; Kondragunta, S.; Zhang, H.; Martin, R. V.; van Donkelaar, A.; Pasch, A. N.; Dye, T. S.; Zahn, P. H.; Haderman, M. D.; DeWinter, J. L.

    2012-12-01

    The US Environmental Protection Agency (EPA) AirNow program provides Air Quality Index (AQI) information to the public, decision-makers, researchers and the media (data and forecasts) mainly for ozone and PM2.5 (particles smaller than 2.5 μm in median diameter). EPA wants to provide the best information available to the public and integrating NASA satellite-derived surface PM2.5 concentrations with ground-level PM2.5 observations has proved promising. The AirNow Satellite Data Processor (ASDP) uses daily PM2.5 estimates and uncertainties derived from average Aqua and Terra MODerate resolution Imaging Spectrometer (MODIS) AOD in near-real-time over the United States and fuses the results with observed PM2.5 measurements to create several air quality products for evaluation. In addition to the description of the AirNow program and the AirNow ASDP, several case studies will be presented to show the value that NASA satellite information adds to maps of air quality.

  20. M2-F2 with test pilot Bruce A. Peterson

    NASA Image and Video Library

    1966-09-22

    Bruce A. Peterson standing beside the M2-F2 lifting body on Rogers Dry Lake. Peterson became the NASA project pilot for the lifting body program after Milt Thompson retired from flying in late 1966. Peterson had flown the M2-F1, and made the first glide flight of the HL-10 heavy-weight lifting body in December 1966. On May 10, 1967, Peterson made his fourth glide flight in the M2-F2. This was also the M2-F2's 16th glide flight, scheduled to be the last one before the powered flights began. However, as pilot Bruce Peterson neared the lakebed, the M2-F2 suffered a pilot induced oscillation (PIO). The vehicle rolled from side to side in flight as he tried to bring it under control. Peterson recovered, but then observed a rescue helicopter that seemed to pose a collision threat. Distracted, Peterson drifted in a cross-wind to an unmarked area of the lakebed where it was very difficult to judge the height over the lakebed because of a lack of the guidance the markers provided on the lakebed runway. Peterson fired the landing rockets to provide additional lift, but he hit the lakebed before the landing gear was fully down and locked. The M2-F2 rolled over six times, coming to rest upside down. Pulled from the vehicle by Jay King and Joseph Huxman, Peterson was rushed to the base hospital, transferred to March Air Force Base and then the UCLA Hospital. He recovered but lost vision in his right eye due to a staph infection.

  1. Seasonal variation of air-sea CO2 fluxes in the Terra Nova Bay of the Ross Sea, Antarctica, based on year-round pCO2 observations

    NASA Astrophysics Data System (ADS)

    Zappa, C. J.; Rhee, T. S.; Kwon, Y. S.; Choi, T.; Yang, E. J.; Kim, J.

    2017-12-01

    The polar oceans are rapidly changing in response to climate variability. In particular, augmented inflow of glacial melt water and shrinking sea-ice extent impacts the polar coastal oceans, which may in turn shift the biogeochemistry into an unprecedented paradigm not experienced previously. Nonetheless, most research in the polar oceans is limited to the summer season. Here, we present the first direct observations of ocean and atmospheric pCO2 measured near the coast of Terra Nova Bay in the Ross Sea, Antarctica, ongoing since February, 2015 at Jang Bogo Station. The coastal area is covered by landfast sea-ice from spring to fall while continually exposed to the atmosphere during summer season only. The pCO2 in seawater swung from 120 matm in February to 425 matm in early October. Although sea-ice still covers the coastal area, pCO2 already started decreasing after reaching the peak in October. In November, the pCO2 suddenly dropped as much as 100 matm in a week. This decrease of pCO2 continued until late February when the sea-ice concentration was minimal. With growing sea ice, the pCO2 increased logarithmically reaching the atmospheric concentration in June/July, depending on the year, and continued to increase until October. Daily mean air-sea CO2 flux in the coastal area widely varied from -70 mmol m-2 d-1 to 20 mmol m-2 d-1. Based on these observations of pCO2 in Terra Nova Bay, the annual uptake of CO2 is 8 g C m-2, estimated using the fraction of sea-ice concentration estimated from AMSR2 microwave emission imagery. Extrapolating to all polynyas surrounding Antarctica, we expect the annual uptake of 8 Tg C in the atmosphere. This is comparable to the amount of CO2 degassed into the atmosphere south of the Antarctic Polar Front (62°S).

  2. Rate coefficient for H + O2 + M = HO2 + M evaluated from shock tube measurements of induction times

    NASA Technical Reports Server (NTRS)

    Slack, M. W.

    1977-01-01

    Shock tube experiments measured hydrogen-air induction times near the second explosion limit. By matching these experimental results with numerically predicted induction times, the rate coefficient for the reaction H + O2 + M = HO2 + M was evaluated as k-sub 4,N2 = 3.3 (plus or minus .6) x 10 to the 15 cm to the 6th/sq mole/s.

  3. Observational estimation of radiative feedback to surface air temperature over Northern High Latitudes

    NASA Astrophysics Data System (ADS)

    Hwang, Jiwon; Choi, Yong-Sang; Kim, WonMoo; Su, Hui; Jiang, Jonathan H.

    2018-01-01

    The high-latitude climate system contains complicated, but largely veiled physical feedback processes. Climate predictions remain uncertain, especially for the Northern High Latitudes (NHL; north of 60°N), and observational constraint on climate modeling is vital. This study estimates local radiative feedbacks for NHL based on the CERES/Terra satellite observations during March 2000-November 2014. The local shortwave (SW) and longwave (LW) radiative feedback parameters are calculated from linear regression of radiative fluxes at the top of the atmosphere on surface air temperatures. These parameters are estimated by the de-seasonalization and 12-month moving average of the radiative fluxes over NHL. The estimated magnitudes of the SW and the LW radiative feedbacks in NHL are 1.88 ± 0.73 and 2.38 ± 0.59 W m-2 K-1, respectively. The parameters are further decomposed into individual feedback components associated with surface albedo, water vapor, lapse rate, and clouds, as a product of the change in climate variables from ERA-Interim reanalysis estimates and their pre-calculated radiative kernels. The results reveal the significant role of clouds in reducing the surface albedo feedback (1.13 ± 0.44 W m-2 K-1 in the cloud-free condition, and 0.49 ± 0.30 W m-2 K-1 in the all-sky condition), while the lapse rate feedback is predominant in LW radiation (1.33 ± 0.18 W m-2 K-1). However, a large portion of the local SW and LW radiative feedbacks were not simply explained by the sum of these individual feedbacks.

  4. Observational analysis of air-sea fluxes and sea water temperature offshore South China Sea

    NASA Astrophysics Data System (ADS)

    Bi, X.; Huang, J.; Gao, Z.; Liu, Y.

    2017-12-01

    This paper investigates the air-sea fluxes (momentum flux, sensible heat flux and latent heat flux) from eddy covariance method based on data collected at an offshore observation tower in the South China Sea from January 2009 to December 2016 and sea water temperature (SWT) on six different levels based on data collected from November 2011 to June 2013. The depth of water at the tower over the sea averages about 15 m. This study presents the in-situ measurements of continuous air-sea fluxes and SWT at different depths. Seasonal and diurnal variations in air-sea fluxes and SWT on different depths are examined. Results show that air-sea fluxes and all SWT changed seasonally; sea-land breeze circulation appears all the year round. Unlike winters where SWT on different depths are fairly consistent, the difference between sea surface temperature (SST) and sea temperature at 10 m water depth fluctuates dramatically and the maximum value reaches 7 °C during summer.

  5. Observational Insights into N2O5 Heterogeneous Chemistry: Influencing Factors and Contribution to Wintertime Air Pollution

    NASA Astrophysics Data System (ADS)

    McDuffie, E. E.; Fibiger, D. L.; Womack, C.; Dube, W. P.; Lopez-Hilfiker, F.; Goldberger, L.; Thornton, J. A.; Shah, V.; Jaegle, L.; Guo, H.; Weber, R. J.; Schroder, J. C.; Campuzano Jost, P.; Jimenez, J. L.; Franchin, A.; Middlebrook, A. M.; Baasandorj, M.; Brown, S. S.

    2017-12-01

    Chemical mechanisms that underlie wintertime air pollution, including tropospheric ozone and aerosol nitrate, are poorly characterized. Due to colder temperatures and fewer hours of solar radiation, nocturnal heterogeneous uptake of N2O5 plays a relatively larger role during wintertime in controlling the oxidation of NOx (=NO+NO2) and its influence on ozone and soluble nitrate. After uptake to aerosol, N2O5 can act as both a nocturnal NOx reservoir and sink depending on the partitioning between its nitric acid and photo labile, ClNO2 reaction products. In addition, N2O5 itself can act as a NOx reservoir if the aerosol uptake coefficient is small. As a result, the nocturnal fate of N2O5 dictates the amount of NOx in an air parcel and the subsequent formation of aerosol nitrate and following-day ozone. Models of winter air pollution therefore require accurate parameterization of the N2O5 uptake coefficient, as well as factors that control its magnitude and N2O5 product partitioning. There are currently only a small number of ambient N2O5 and ClNO2 observations during the winter season concurrent with measurements of relevant variables such as aerosol size distributions and composition. The Wintertime INvestigation of Transport, Emissions, and Reactivity (WINTER) campaign conducted 10 nighttime research flights with the NCAR C-130 over the eastern U.S. during February and March, 2015. The more recent Utah Wintertime Fine Particulate Study (UWFPS) conducted over 20 research flights with the NOAA twin otter aircraft during January-February 2017 in three mountain basins near and including Salt Lake City, Utah. The two campaigns were similarly instrumented and have provided the first aircraft observations of N2O5, ClNO2, and aerosol composition in the wintertime boundary layer in these urban-influenced regions. Analysis of heterogeneous chemistry under a wide range of real environmental conditions provides insight into the factors controlling the N2O5 uptake coefficient

  6. Hydrostatic pressure study on high temperature superconductors: HgBa(2)Casb(m-1)Cu(m)O(2m+2+delta) (m = 1 to 6) and (Cu,C)Ba(2)Ca(m-1)Cu(m)O(2m+3) (m = 3 and 4)

    NASA Astrophysics Data System (ADS)

    Cao, Yong

    1998-12-01

    dependence is observed on other compounds without the Cu-O chain structure. Therefore, the Cu-O chain might be the main source of pressure-induced charge transfer. (3) The dTsb{c}/dP at nearly optimally doped state dTsb{c}sp{max}/dP, which are almost the same for the m = 1-3 members of Hg-12(m-1)m series, show a step-like drop to about one half of the original values as m = 4, and stay close to that value as m = 5 and 6. This observation is attributed to the inhomogeneous carrier distribution and pressure-induced redistribution of carriers between inner (planar) and outer (pyramidal) CuOsb2 layers. The compounds with m ≥ 4, unlike the first three members, have a large inhomogeneous carrier distribution, and this carrier inhomogeneity is enhanced under pressure. We believe these observations will provide useful information for the development of a microscopic theory on HTSy.

  7. IUE observations of RW Hydrae /gM2 + pec/

    NASA Astrophysics Data System (ADS)

    Kafatos, M.; Michalitsianos, A. G.; Hobbs, R. W.

    1980-08-01

    Analysis of the intense UV continuum observed between 1100 and 2000 A suggested that observations of the late type star RW Hya is a binary system in which the secondary is the central star of a planetary nebula. The UV spectrum is characterized by semiforbidden and allowed transition lines, of which the C IV doublet is particularly strong. Tidal interaction from the M giant is proposed as a method of forming a nebula with the characteristic densities inferred from the UV line analysis. RW Hya is suggested as a possible source of soft X-ray emission if material is accreting onto the surface of the secondary.

  8. IUE observations of RW Hydrae /gM2 + pec/

    NASA Technical Reports Server (NTRS)

    Kafatos, M.; Michalitsianos, A. G.; Hobbs, R. W.

    1980-01-01

    Analysis of the intense UV continuum observed between 1100 and 2000 A suggested that observations of the late type star RW Hya is a binary system in which the secondary is the central star of a planetary nebula. The UV spectrum is characterized by semiforbidden and allowed transition lines, of which the C IV doublet is particularly strong. Tidal interaction from the M giant is proposed as a method of forming a nebula with the characteristic densities inferred from the UV line analysis. RW Hya is suggested as a possible source of soft X-ray emission if material is accreting onto the surface of the secondary.

  9. AIRS Water Vapor and Cloud Products Validate and Explain Recent Negative Global and Tropical OLR Trends Observed by CERES

    NASA Astrophysics Data System (ADS)

    Susskind, J.; Molnar, G. I.; Iredell, L. F.; Sounder Research Team

    2010-12-01

    Joel Susskind, Gyula Molnar, and Lena Iredell NASA GSFC Sounder Research Team Abstract This paper compares spatial and temporal anomalies and trends of OLR as observed by CERES and computed based on AIRS retrieved surface and atmospheric geophysical parameters over the time period September 2002 - February 2010. This time period is marked by a substantial decreasing OLR trend on the order of -0.1 W/m2/yr averaged over the globe. There are very large spatial variations of these trends however, with local values ranging from -2.6 W/m2/yr to +3.0 W/m2/yr in the tropics. The spatial patterns of the AIRS and CERES trends are in essentially perfect agreement with each other, as are the anomaly time series averaged over different spatial regions. This essentially perfect agreement of OLR anomalies and trends derived from observations by two different instruments, in totally independent and different manners, implies that both sets of results must be highly accurate. The agreement of anomalies and trends of OLR as observed by CERES and computed from AIRS derived products also indirectly validates the anomalies and trends of the AIRS derived products as well. We used the anomalies and trends of AIRS derived water vapor and cloud products to explain why global OLR has had a large negative trend over the time period September 2002 through February 2010. Tropical OLR began to decrease significantly at the onset of a strong La Niña in mid-2007. AIRS products show that cloudiness and mid-tropospheric water vapor began to increase in the region 5°N - 20°S latitude extending eastward from 150°W - 30°E longitude at that time, with a corresponding very large drop in OLR in this region. Late 2009 is characterized by a strong El-Niño, with a corresponding change in sign of observed anomalies of mid-tropospheric water vapor, cloud cover, and OLR in this region, as well as that of OLR anomalies in the tropics and globally. Monthly mean anomalies of OLR, water vapor and cloud cover

  10. AIRS-only Product on Giovanni for Exploring Up-to-date AIRS Observation and Comparing with AIRS+AMSU Product

    NASA Astrophysics Data System (ADS)

    Ding, F.; Hearty, T. J., III; Theobald, M.; Vollmer, B.; Wei, J.

    2017-12-01

    The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has been the home of processing, archiving, and distribution services for the Atmospheric Infrared Sounder (AIRS) mission since its launch in 2002 for the global observations of the atmospheric state. Giovanni, a web-based application developed by the GES DISC, provides a simple and intuitive way to visualize, analyze, and access vast amounts of Earth science remote sensing data without having to download the data. Most important variables, including temperature and humidity profiles, outgoing longwave radiation, cloud properties, and trace gases, from version 6 AIRS product are available on Giovanni. The AIRS is an instrument suite comprised of a hyperspectral infrared instrument AIRS and two multichannel microwave instruments, the Advanced Microwave Sounding Unit (AMSU) and the Humidity Sounder for Brazil (HSB). As the HSB ceased operation in very early stage of AIRS mission, the AIRS project operates two parallel retrieval algorithms: one using both IR and MW measurements (AIRS+AMSU) and the other using only IR measurements (AIRS-only) for the most time of the mission. The AIRS+AMSU product is better and the variables on Giovanni are from it. However, the generation of AIRS+AMSU product has been suspended since the AMSU instrument anomaly occurred in late 2016. To continue exploring up-to-date AIRS observations, the same set of variables from the AIRS-only product are added on Giovanni by the GES DSIC. This will also support the comparison of AIRS-only with AIRS+AMSU retrievals. In the presentation, we will demonstrate the visualization of AIRS-only product and the plots/statistics of comparison with AIRS+AMSU product using Giovanni.

  11. AIRS-Only Product in Giovanni for Exploring Up-to-Date AIRS Observation and Comparing with AIRS+AMSU Product

    NASA Technical Reports Server (NTRS)

    Ding, Feng; Hearty, Thomas J.; Theobald, Michael; Vollmer, Bruce; Wei, Jennifer

    2017-01-01

    The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has been the home of processing, archiving, and distribution services for the Atmospheric Infrared Sounder (AIRS) mission since its launch in 2002 for global observations of the atmospheric state. Giovanni, a Web-based application developed by the GES DISC, provides a simple and intuitive way to visualize, analyze, and access vast amounts of Earth science remote sensing data without having to download the data. Most important AIRS variables, including temperature and humidity profiles, outgoing longwave radiation, cloud properties, and trace gases, are available in Giovanni. AIRS is an instrument suite comprised of a hyperspectral infrared instrument (AIRS) and two multichannel microwave instruments, the Advanced Microwave Sounding Unit (AMSU) and the Humidity Sounder for Brazil (HSB). As HSB ceased operation in the very early stages of the AIRS mission, the AIRS project operates two parallel retrieval algorithms: one using both IR and MW measurements (AIRS+AMSU) and the other using only IR measurements (AIRS-only), which covers most of the mission duration. The AIRS+AMSU product is better quality, and the variables in Giovanni are from this product. However, generation of the AIRS+AMSU product has been suspended since the AMSU instrument anomaly occurred in late September 2016. To continue exploring up-to-date AIRS observations, the same set of variables from the AIRS-only product have been added to Giovanni by the GES DSIC. This will also support comparison of AIRS-only with AIRS+AMSU retrievals. In this presentation, we demonstrate the visualization of the AIRS-only product and plots/statistics of comparison with AIRS+AMSU product using Giovanni.

  12. NASA Tropospheric Composition Program field campagins as prototypes to advance the Integrated Observing System for Air Quality

    NASA Astrophysics Data System (ADS)

    Lefer, B. L.; Crawford, J. H.; Pierce, R. B.; Berkoff, T.; Swap, R.; Janz, S. J.; Ahn, J.; Al-Saadi, J. A.

    2017-12-01

    With the launch over the virtual constellation of earth observing satellites for atmospheric composition (e.g., TROPOMI, GEMS, TEMPO, and Sentinel-4) over the next several years, we have a unique opportunity to develop an Integrated Observing System (IOS) for air quality in the northern hemisphere. Recently, NASA's Tropospheric Composition Program (TCP) has participated in several different air quality related field campaigns as an effort to explore various prototypes of the IOS for Air Quality. The IOS for air quality could be a system were space-based observations of air quality (generally, column abundances of NO2, HCHO, O3, SO2, and AOD) are given added "value" by being integrated with: a) long-term ground-based observations;b) regional and global air quality and chemical transport models; as well as c) measurements from targeted airborne field campaigns. The recent Korea-US Air Quality Study (KORUS-AQ), the Lake Michigan Ozone Study 2017 (LMOS), and the Ozone Water-Land Environmental Transition Study (OWLETS) field campaigns were held in different locations and made measurements over different scale. However, all of these provide an opportunity to learn about how a future integrated air quality observing system can be implemented to serve a variety of air quality related objectives. NASA TCP is also exploring enchancements to our routine observations to strengthen the IOS for air quality in the future.

  13. Effects of H2O, CO2, and N2 Air Contaminants on Critical Airside Strain Rates for Extinction of Hydrogen-Air Counterflow Diffusion Flames

    NASA Technical Reports Server (NTRS)

    Pellett, G. L.; Wilson, L. G.; Northam, G. B.; Guerra, Rosemary

    1989-01-01

    Coaxial tubular opposed jet burners (OJB) were used to form dish shaped counterflow diffusion flames (CFDF), centered by opposing laminar jets of H2, N2 and both clean and contaminated air (O2/N2 mixtures) in an argon bath at 1 atm. Jet velocities for flame extinction and restoration limits are shown versus wide ranges of contaminant and O2 concentrations in the air jet, and also input H2 concentration. Blowoff, a sudden breaking of CFDF to a stable ring shape, occurs in highly stretched stagnation flows and is generally believed to measure kinetically limited flame reactivity. Restore, a sudden restoration of central flame, is a relatively new phenomenon which exhibits a H2 dependent hysteresis from Blowoff. For 25 percent O2 air mixtures, mole for mole replacement of 25 percent N2 contaminant by steam increased U(air) or flame strength at Blowoff by about 5 percent. This result is consistent with laminar burning velocity results from analogous substitution of steam for N2 in a premixed stoichiometric H2-O2-N2 (or steam) flame, shown by Koroll and Mulpuru to promote a 10 percent increase in experimental and calculated laminar burning velocity, due to enhanced third body efficiency of water in: H + O2 + M yields HO2 + M. When the OJB results were compared with Liu and MacFarlane's experimental laminar burning velocity of premixed stoichiometric H2 + air + steam, a crossover occurred, i.e., steam enhanced OJB flame strength at extinction relative to laminar burning velocity.

  14. Investigating the Impact of Marine Ship Emissions on Regional Air Quality using OMI Satellite NO2 Observations and the CMAQ Model

    NASA Astrophysics Data System (ADS)

    Ring, A.; Canty, T. P.; He, H.; Vinciguerra, T.; Lamsal, L. N.; Dickerson, R. R.; Salawitch, R. J.; Cohen, M.; Montgomery, L. N.; Dreessen, J.

    2015-12-01

    Commercial marine vessels (CMVs) emit significant amounts of NOx, an ozone precursor, which may contribute to negative health consequences for people living in areas near shipping lanes. In coastal US states, many metropolitan areas such as Baltimore and New York City are located near ports with CMVs. Many studies estimate that ships account for ~15-30% of the global anthropogenic NOx emissions. EPA developed emissions inventories are widely used by states to construct model scenarios for testing air quality attainment strategies. Currently, CMV emissions are generated by simply applying growth factors to aggregated emissions data from much earlier years. Satellite retrievals from the Ozone Monitoring Instrument (OMI) have been successfully used to improve the veracity of marine emissions by incorporating observational data from the inventory year. In this study we use OMI NO2 observations and Community Multiscale Air Quality (CMAQ) model outputs to improve the EPA marine emission estimates for the Mid-Atlantic region. Back trajectories from the NOAA Air Resources Laboratory HYSPLIT model are used to identify days with minimal continental influence on OMI tropospheric column NO2 over shipping lanes. We perform sensitivity analyses to quantify the impact of marine emissions on air quality and suggest strategies to better meet the EPA mandated ozone standard.

  15. Observations of the convective plume of a lake under cold-air advective conditions

    NASA Technical Reports Server (NTRS)

    Bill, R. G., Jr.; Sutherland, R. A.; Bartholic, J. F.; Chen, E.

    1978-01-01

    Moderating effects of Lake Apopka, Florida, on downwind surface temperatures were evaluated under cold-air advective conditions. Point temperature measurements north and south of the lake and data obtained from a thermal scanner flown at 1.6 km indicate that surface temperatures directly downwind may be higher than surrounding surface temperatures by as much as 5 C under conditions of moderate winds (about 4 m/s). No substantial temperature effects were observed with surface wind speed less than 1 m/s. Fluxes of sensible and latent heat from Lake Apopka were calculated from measurements of lake temperature, net radiation, relative humidity, and air temperature above the lake. Bulk transfer coefficients and the Bowen ratio were calculated and found to be in agreement with reported data for nonadvective conditions.

  16. Using aircraft and satellite observations to improve regulatory air quality models

    NASA Astrophysics Data System (ADS)

    Canty, T. P.; Vinciguerra, T.; Anderson, D. C.; Carpenter, S. F.; Goldberg, D. L.; Hembeck, L.; Montgomery, L.; Liu, X.; Salawitch, R. J.; Dickerson, R. R.

    2014-12-01

    Federal and state agencies rely on EPA approved models to develop attainment strategies that will bring states into compliance with the National Ambient Air Quality Standards (NAAQS). We will describe modifications to the Community Multi-Scale Air Quality (CMAQ) model and Comprehensive Air Quality Model with Extensions (CAMx) frameworks motivated by analysis of NASA satellite and aircraft measurements. Observations of tropospheric column NO2 from OMI have already led to the identification of an important deficiency in the chemical mechanisms used by models; data collected during the DISCOVER-AQ field campaign has been instrumental in devising an improved representation of the chemistry of nitrogen species. Our recent work has focused on the use of: OMI observations of tropospheric O3 to assess and improve the representation of boundary conditions used by AQ models, OMI NO2 to derive a top down NOx emission inventory from commercial shipping vessels that affect air quality in the Eastern U.S., and OMI HCHO to assess the C5H8 emission inventories provided by bioegenic emissions models. We will describe how these OMI-driven model improvements are being incorporated into the State Implementation Plans (SIPs) being prepared for submission to EPA in summer 2015 and how future modeling efforts may be impacted by our findings.

  17. The Utility of the OMI HCHO/NO2 in Air Quality Decision-Making Activities

    NASA Technical Reports Server (NTRS)

    Duncan, Bryan

    2010-01-01

    I will discuss a novel and practical application of the OMI HCHU and NO2 data products to the "weight of evidence" in the air quality decision-making process (e.g., State Implementation Plan (SIP)) for a city, region, or state to demonstrate that it is making progress toward attainment of the National Ambient Air Quality Standard (NAAQS) for ozone. Any trend, or lack thereof, in the observed OMI HCHO/NO2 may support that an emission control strategy implemented to reduce ozone is or is not occurring for a metropolitan area. In addition, the observed OMI HCHO/NO2 may be used to define new emission control strategies as the photochemical environments of urban areas evolve over time. I will demonstrate the utility of the OMI HCHO/NO2 over the U.S. for air quality applications with support from simulations with both a regional model and a photochemical box model. These results support mission planning of an OMI-like instrument for the proposed GEO-CAPE satellite that has as one of its objectives to study air quality from space. However, I'm attending the meeting as the Aura Deputy Project Scientist, so I don't technically need to present anything to justify the travel.

  18. Ultraviolet Observations of M-Type Symbiotic Stars

    NASA Astrophysics Data System (ADS)

    Michalitsianos, Andrew G.

    The significant differences revealed in high dispersion short wavelength spectra of two M-type symbiotic stars RW Hya (gM2 + pec) and RX Pup (M5 + pec) observed previously with IUE emphasizes the need for high resolution observations of a wide range of similar objects. The anomalies observed in high excitation lines in RX Pup of He II, N III], N IV], O III], C III], C IV and Si III] that show split line profiles, multiple component Doppler displaced components, and broadened blue wing emission structure in N III] and N IV] suggest motion in circumstellar material. In contrast, high dispersion UV spectra of RW Hya reveal narrow high excitation emission lines that give no suggestion of macroscopic motions in the circumstellar gas. We wish to extend observations of a selected number of symbiotic stars observed previously but in low resolution, to high dispersion in order to determine if particular M-type symbiotic stars exhibit anomalies in their line profile. As such, symbiotic stars exhibiting velocity structure in emission lines may form a subset of objects that are characterized by mass motions in their circumstellar envelops that create high excitation emission. UV line and continuum emission from other M-type symbiotics may arise from mainly photo-excitation processes that results from the intense radiation field associated with the hot secondary companion.

  19. Air pollution and diabetes association: Modification by type 2 diabetes genetic risk score.

    PubMed

    Eze, Ikenna C; Imboden, Medea; Kumar, Ashish; von Eckardstein, Arnold; Stolz, Daiana; Gerbase, Margaret W; Künzli, Nino; Pons, Marco; Kronenberg, Florian; Schindler, Christian; Probst-Hensch, Nicole

    2016-09-01

    Exposure to ambient air pollution (AP) exposure has been linked to type 2 diabetes (T2D) risk. Evidence on the impact of T2D genetic variants on AP susceptibility is lacking. Compared to single variants, joint genetic variants contribute substantially to disease risk. We investigated the modification of AP and diabetes association by a genetic risk score (GRS) covering 63 T2D genes in 1524 first follow-up participants of the Swiss cohort study on air pollution and lung and heart diseases in adults. Genome-wide data and covariates were available from a nested asthma case-control study design. AP was estimated as 10-year mean residential particulate matter <10μm (PM10). We computed count-GRS and weighted-GRS, and applied PM10 interaction terms in mixed logistic regressions, on odds of diabetes. Analyses were stratified by pathways of diabetes pathology and by asthma status. Diabetes prevalence was 4.6% and mean exposure to PM10 was 22μg/m(3). Odds of diabetes increased by 8% (95% confidence interval: 2, 14%) per T2D risk allele and by 35% (-8, 97%) per 10μg/m(3) exposure to PM10. We observed a positive interaction between PM10 and count-GRS on diabetes [ORinteraction=1.10 (1.01, 1.20)], associations being strongest among participants at the highest quartile of count-GRS [OR: 1.97 (1.00, 3.87)]. Stronger interactions were observed with variants of the GRS involved in insulin resistance [(ORinteraction=1.22 (1.00, 1.50)] than with variants related to beta-cell function. Interactions with count-GRS were stronger among asthma cases. We observed similar results with weighted-GRS. Five single variants near GRB14, UBE2E2, PTPRD, VPS26A and KCNQ1 showed nominally significant interactions with PM10 (P<0.05). Our results suggest that genetic risk for T2D may modify susceptibility to air pollution through alterations in insulin sensitivity. These results need confirmation in diabetes cohort consortia. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights

  20. Assessment of air quality benefits from national air pollution control policies in China. Part II: Evaluation of air quality predictions and air quality benefits assessment

    NASA Astrophysics Data System (ADS)

    Wang, Litao; Jang, Carey; Zhang, Yang; Wang, Kai; Zhang, Qiang; Streets, David; Fu, Joshua; Lei, Yu; Schreifels, Jeremy; He, Kebin; Hao, Jiming; Lam, Yun-Fat; Lin, Jerry; Meskhidze, Nicholas; Voorhees, Scott; Evarts, Dale; Phillips, Sharon

    2010-09-01

    Following the meteorological evaluation in Part I, this Part II paper presents the statistical evaluation of air quality predictions by the U.S. Environmental Protection Agency (U.S. EPA)'s Community Multi-Scale Air Quality (Models-3/CMAQ) model for the four simulated months in the base year 2005. The surface predictions were evaluated using the Air Pollution Index (API) data published by the China Ministry of Environmental Protection (MEP) for 31 capital cities and daily fine particulate matter (PM 2.5, particles with aerodiameter less than or equal to 2.5 μm) observations of an individual site in Tsinghua University (THU). To overcome the shortage in surface observations, satellite data are used to assess the column predictions including tropospheric nitrogen dioxide (NO 2) column abundance and aerosol optical depth (AOD). The result shows that CMAQ gives reasonably good predictions for the air quality. The air quality improvement that would result from the targeted sulfur dioxide (SO 2) and nitrogen oxides (NO x) emission controls in China were assessed for the objective year 2010. The results show that the emission controls can lead to significant air quality benefits. SO 2 concentrations in highly polluted areas of East China in 2010 are estimated to be decreased by 30-60% compared to the levels in the 2010 Business-As-Usual (BAU) case. The annual PM 2.5 can also decline by 3-15 μg m -3 (4-25%) due to the lower SO 2 and sulfate concentrations. If similar controls are implemented for NO x emissions, NO x concentrations are estimated to decrease by 30-60% as compared with the 2010 BAU scenario. The annual mean PM 2.5 concentrations will also decline by 2-14 μg m -3 (3-12%). In addition, the number of ozone (O 3) non-attainment areas in the northern China is projected to be much lower, with the maximum 1-h average O 3 concentrations in the summer reduced by 8-30 ppb.

  1. Global and Regional Seasonal Variability of Mid-Tropospheric CO2 as Measured by the Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Olsen, Edward T.; Nguyen, Hai

    2012-01-01

    The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the Earth Observing System (EOS) Aqua Spacecraft, launched on May 4, 2002 into a near polar sun-synchronous orbit. AIRS has 2378 infrared channels ranging from 3.7 ?m to 15.4 ?m and a 13.5 km footprint at nadir. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy on a global scale, as well as water vapor profiles and trace gas amounts for CO2, CO, SO2, O3 and CH4. AIRS CO2 climatologies have been shown to be useful for identifying anomalies associated with geophysical events such as El Nino-Southern Oscillation or Madden-Julian oscillation. In this study, monthly representations of mid-tropospheric CO2 are constructed from 10 years of AIRS Version 5 monthly Level 3 data. We compare the AIRS mid-tropospheric CO2 representations to ground-based measurements from the Scripps and National Oceanic and Atmospheric Administration Climate Modeling and Diagnostics Laboratory (NOAA CMDL) ground networks to better understand the phase lag of the CO2 seasonal cycle between the surface and middle troposphere. Results show only a small phase lag in the tropics that grows to approximately two months in the northern latitudes.

  2. Accountability analysis of title IV phase 2 of the 1990 Clean Air Act Amendments.

    PubMed

    Morgenstern, Richard D; Harrington, Winston; Shih, Jhih-Shyang; Bell, Michelle L

    2012-11-01

    In this study, we sought to assess what portion, if any, of the reductions in ambient concentrations of particulate matter (PM*) < or = 2.5 microm in aerodynamic diameter (PM2.5) that occurred in the United States between the years 1999 and 2006 can be attributed to reductions in emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx) resulting from implementation of Phase 2 of Title IV of the 1990 Clean Air Act Amendments. To this end, a detailed statistical model linking sources and monitors over time and space was used to estimate associations between the observed emissions reductions and improvements in air quality. Overall, it turned out to be quite feasible to use relatively transparent statistical methods to assess these outcomes of the Phase 2 program, which was designed to reduce long-range transport of emissions. Associations between changes in emissions from individual power plants and monitor-specific estimates of changes in concentrations of PM2.5, our indicator pollutant, were highly significant and were mostly of the expected relative magnitudes with respect to distances and directions from sources. Originally estimated on monthly data for a set of 193 monitors between 1999 and 2005, our preferred model performed equally well using data for the same 193 monitors for 2006 as well as for an additional 217 monitors not in the original set in 2006. Although substantial model uncertainty was observed, we were able to estimate that the Title IV Phase 2 emissions reduction program implemented between 1999 and 2005 reduced PM2.5 concentrations in the eastern United States by an average of 1.07 microg/m3 (standard deviation [SD] = 0.11 microg/m3) compared with a counterfactual case defined as there having been no change in emission rates per unit of energy input (1 million British thermal units [BTUs]). On a population-weighted basis, the comparable reduction in PM2.5 was 0.89 microg/m3. Compared with the air quality fate and transport models used by the

  3. [Air pollution and mortality in twenty-five Italian cities: results of the EpiAir2 Project].

    PubMed

    Alessandrini, Ester Rita; Faustini, Annunziata; Chiusolo, Monica; Stafoggia, Massimo; Gandini, Martina; Demaria, Moreno; Antonelli, Antonello; Arena, Pasquale; Biggeri, Annibale; Canova, Cristina; Casale, Giovanna; Cernigliaro, Achille; Garrone, Elsa; Gherardi, Bianca; Gianicolo, Emilio Antonio Luca; Giannini, Simone; Iuzzolino, Claudia; Lauriola, Paolo; Mariottini, Mauro; Pasetto, Paolo; Randi, Giorgia; Ranzi, Andrea; Santoro, Michele; Selle, Vittorio; Serinelli, Maria; Stivanello, Elisa; Tominz, Riccardo; Vigotti, Maria Angela; Zauli-Sajani, Stefano; Forastiere, Francesco; Cadum, Ennio

    2013-01-01

    this study aims at presenting the results from the Italian EpiaAir2 Project on the short-term effects of air pollution on adult population (35+ years old) in 25 Italian cities. the short-term effects of air pollution on resident people died in their city were analysed adopting the time series approach. The association between increases in 10µg/m(3) in PM10, PM2.5, NO2 and O3 air concentration and natural, cardiac, cerebrovascular and respiratory mortality was studied. City-specific Poisson models were fitted to estimate the association of daily concentrations of pollutants with daily counts of deaths. The analysis took into account temporal and meteorological factors to control for potential confounding effect. Pooled estimates have been derived from random effects meta-analysis, evaluating the presence of heterogeneity in the city specific results. it was analysed 422,723 deaths in the 25 cities of the project among people aged 35 years or more, resident in each city during the period 2006-2010. daily counts of natural, cardiac, cerebrovascular, and respiratory mortality, obtained from the registries of each city. Demographic information were obtained by record linkage procedure with the civil registry of each city. mean number of deaths for natural causes ranged from 513 in Rovigo to 20,959 in Rome. About 25% of deaths are due to cardiac diseases, 10% to cerebrovascular diseases, and 7% to respiratory diseases. It was found an immediate effect of PM10 on natural mortality (0.51%; 95%CI 0.16-0.86; lag 0-1). More relevant and prolonged effects (lag 0-5) have been found for PM2.5 (0.78%; 95%CI 0.12-1.46) and NO2 (1.10%; 95%CI 0.63-1.58). Increases in cardiac mortality are associated with PM10 (0.93%; 95%CI 0.16-1.70) and PM2.5 (1.25%; 95%CI 0.17-2.34), while for respiratory mortality exposure to NO2 has an important role (1.67%; 95%CI 0.23-3.13; lag 2-5), as well as PM10 (1.41%; 95%CI - 0.23;+3.08). Results are strongly homogeneous among cities, except for

  4. Assessment of human health impact from exposure to multiple air pollutants in China based on satellite observations

    NASA Astrophysics Data System (ADS)

    Yu, Tao; Wang, Wen; Ciren, Pubu; Zhu, Yan

    2016-10-01

    Assessment of human health impact caused by air pollution is crucial for evaluating environmental hazards. In this paper, concentrations of six air pollutants (PM10, PM2.5, NO2, SO2, O3, and CO) were first derived from satellite observations, and then the overall human health risks in China caused by multiple air pollutants were assessed using an aggregated health risks index. Unlike traditional approach for human health risks assessment, which relied on the in-situ air pollution measurements, the spatial distribution of aggregated human health risks in China were obtained using satellite observations in this research. It was indicated that the remote sensing data have advantages over in-situ data in accessing human health impact caused by air pollution.

  5. Air-water CO2 Fluxes In Seasonal Hypoxia-influenced Green Bay, Lake Michigan

    NASA Astrophysics Data System (ADS)

    Lin, P.; Klump, J. V.; Guo, L.

    2016-02-01

    Increasing anthropogenic nutrient enrichment has led to seasonal hypoxia in Green Bay, the largest freshwater estuary in the Laurentian Great Lakes, but change in carbon dynamics associated with the development of hypoxia remains poorly understood. Variations in alkalinity, abundance of carbon species, and air-water CO2 fluxes were quantified under contrasting hypoxic conditions during summer 2014. Green Bay was characterized with high pH (average 8.62 ± 0.16 in August), high DIC concentrations (2113 - 3213 µmol/kg) and high pCO2 in the water column. pCO2 was mostly >700 µatm in June, resulting in a net CO2 source to the air, while pCO2 was mostly <650 µatm in August when hypoxic conditions occurred in Green Bay. In central Green Bay, pCO2 was the highest during both sampling months, accompanying by low dissolved oxygen (DO) and lower pH in the water column. In August, pCO2 was inversely correlated with DOC concentration and increased with DOC/DOP ratio, suggesting a control by organic matter on air-water CO2 dynamics and consumption of DO in Green Bay. Positive CO2 fluxes to the atmosphere during August were only observed in northern bay but a CO2 sink was found in southern Green Bay ( 40% of study area) with high biological production and terrestrial DOM. Daily CO2 flux ranged from 10.9 to 48.5 mmol-C m-2 d-1 in June with an average of 18.29 ± 7.44 mmol-C m-2 d-1, whereas it varied from 1.82 ± 1.18 mmol m-2 d-1 in the north to -2.05 ± 1.89 mmol m-2 d-1 in the south of Green Bay in August. Even though strong biological production reduced the CO2 emission, daily CO2 fluxes from Green Bay to the air were as high as 7.4 × 107 mole-C in June and 4.6 × 106 mole-C in August, suggesting a significant role of high-DIC lakes in global CO2 budget and cycling.

  6. Observations of emission lines in M supergiants

    NASA Technical Reports Server (NTRS)

    Lambert, D. L.

    1979-01-01

    Copernicus observations of Mg 2 h and k emission lines from M giants and supergiants are described. Supergiants with extensive circumstellar gas shells show an asymmetric k line. The asymmetry is ascribed to superimposed lines of Fe 1 and Mn 1. The Mg 2 line width fit the Wilson-Bappu relation derived from observations of G and K Stars. Results of correlated ground-based observations include (1) the discovery of K 1 fluorescent emission from the Betelgeuse shell; (2) extimates of the mass-loss rates; and (3) the proposal that silicate dust grains must account for the major fraction of the Si atoms in the Betelgeuse shell.

  7. M2-F2 flight preparation and launch

    NASA Technical Reports Server (NTRS)

    1969-01-01

    This movie clip runs about 27 seconds and shows the cockpit canopy close-out by the ground crew, the aircraft hanging from the NB-52B wing pylon, and the M2-F2 being dropped away from the mothership. A fleet of lifting bodies flown at the NASA Flight Research Center (FRC), Edwards, California, from 1963 to l975 demonstrated the ability of pilots to maneuver (in the atmosphere) and safely land a wingless vehicle. These lifting bodies were basically designed so they could fly back to Earth from space and be landed like an aircraft at a pre-determined site. They served as precursors of today's Space Shuttle, the X-33, and the X-38, providing technical and operational engineering data that shaped all three space vehicles. (In 1976 NASA renamed the FRC as the NASA Dryden Flight Research Center (DFRC) in honor of Hugh L. Dryden.) In 1962, FRC Director Paul Bikle approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1. Built by Gus Briegleb, a sailplane builder from El Mirage, California, it featured a plywood shell, placed over a tubular steel frame crafted at the FRC. Construction was completed in 1963. The success of Dryden's M2-F1 program led to NASA's development and construction of two heavyweight lifting bodies based on studies at NASA Ames Research Center and NASA and Langley Research Center -- the M2-F2 and the HL-10, both built by the Northrop Corporation, Los Angeles, California. The 'M' refers to 'manned' and 'F' refers to 'flight' version. 'HL' comes from 'horizontal landing' and '10' is for the tenth lifting body model to be investigated by Langley. The first flight of the M2-F2 -- which looked much like the M2-F1 -- occurred on July 12, 1966. Thompson was the pilot. By then, the same B-52 used to air launch the famed X-15 rocket research aircraft had been modified to also carry the lifting bodies into the air and Thompson was

  8. M2-F3 on lakebed

    NASA Image and Video Library

    1970-06-20

    The M2-F3 Lifting Body is seen here on the lakebed next to the NASA Flight Research Center (FRC--later Dryden Flight Research Center), Edwards, California. The May 1967 crash of the M2-F2 had torn off the left fin and landing gear. It had also damaged the external skin and internal structure. Flight Research Center engineers worked with Ames Research Center and the Air Force in redesigning the vehicle with a center fin to provide greater stability. Then Northrop Corporation cooperated with the FRC in rebuilding the vehicle. The entire process took three years.

  9. Transparent air filter for high-efficiency PM2.5 capture.

    PubMed

    Liu, Chong; Hsu, Po-Chun; Lee, Hyun-Wook; Ye, Meng; Zheng, Guangyuan; Liu, Nian; Li, Weiyang; Cui, Yi

    2015-02-16

    Particulate matter (PM) pollution has raised serious concerns for public health. Although outdoor individual protection could be achieved by facial masks, indoor air usually relies on expensive and energy-intensive air-filtering devices. Here, we introduce a transparent air filter for indoor air protection through windows that uses natural passive ventilation to effectively protect the indoor air quality. By controlling the surface chemistry to enable strong PM adhesion and also the microstructure of the air filters to increase the capture possibilities, we achieve transparent, high air flow and highly effective air filters of ~90% transparency with >95.00% removal of PM2.5 under extreme hazardous air-quality conditions (PM2.5 mass concentration >250 μg m(-3)). A field test in Beijing shows that the polyacrylonitrile transparent air filter has the best PM2.5 removal efficiency of 98.69% at high transmittance of ~77% during haze occurrence.

  10. Transparent air filter for high-efficiency PM2.5 capture

    NASA Astrophysics Data System (ADS)

    Liu, Chong; Hsu, Po-Chun; Lee, Hyun-Wook; Ye, Meng; Zheng, Guangyuan; Liu, Nian; Li, Weiyang; Cui, Yi

    2015-02-01

    Particulate matter (PM) pollution has raised serious concerns for public health. Although outdoor individual protection could be achieved by facial masks, indoor air usually relies on expensive and energy-intensive air-filtering devices. Here, we introduce a transparent air filter for indoor air protection through windows that uses natural passive ventilation to effectively protect the indoor air quality. By controlling the surface chemistry to enable strong PM adhesion and also the microstructure of the air filters to increase the capture possibilities, we achieve transparent, high air flow and highly effective air filters of ~90% transparency with >95.00% removal of PM2.5 under extreme hazardous air-quality conditions (PM2.5 mass concentration >250 μg m-3). A field test in Beijing shows that the polyacrylonitrile transparent air filter has the best PM2.5 removal efficiency of 98.69% at high transmittance of ~77% during haze occurrence.

  11. Field Observations of Coastal Air-Sea Interaction

    NASA Astrophysics Data System (ADS)

    Ortiz-Suslow, D. G.; Haus, B. K.; Williams, N. J.; Graber, H. C.

    2016-12-01

    In the nearshore zone wind, waves, and currents generated from different forcing mechanisms converge in shallow water. This can profoundly affect the physical nature of the ocean surface, which can significantly modulate the exchange of momentum, heat, and mass across the air-sea interface. For decades, the focus of air-sea interaction research has been on the open ocean while the shallow water regime has been relatively under-explored. This bears implications for efforts to understand and model various coastal processes, such as mixing, surface transport, and air-sea gas flux. The results from a recent study conducted at the New River Inlet in North Carolina showed that directly measured air-sea flux parameters, such as the atmospheric drag coefficient, are strong functions of space as well as the ambient conditions (i.e. wind speed and direction). The drag is typically used to parameterize the wind stress magnitude. It is generally assumed that the wind direction is the direction of the atmospheric forcing (i.e. wind stress), however significant wind stress steering off of the azimuthal wind direction was observed and was found to be related to the horizontal surface current shear. The authors have just returned from a field campaign carried out within Monterey Bay in California. Surface observations made from two research vessels were complimented by an array of beach and inland flux stations, high-resolution wind forecasts, and satellite image acquisitions. This is a rich data set and several case studies will be analyzed to highlight the importance of various processes for understanding the air-sea fluxes. Preliminary findings show that interactions between the local wind-sea and the shoaling, incident swell can have a profound effect on the wind stress magnitude. The Monterey Bay coastline contains a variety of topographical features and the importance of land-air-sea interactions will also be investigated.

  12. Recent Global Warming As Depicted by AIRS, GISSTEMP, and MERRA-2

    NASA Astrophysics Data System (ADS)

    Susskind, J.; Iredell, L. F.; Lee, J. N.

    2017-12-01

    We observed anomalously warm global mean surface temperatures since 2015. The year 2016 represents the warmest annual mean surface skin and surface air temperatures in the AIRS observational period, September 2002 through August 2017. Additionally, AIRS monthly mean surface skin temperature, from January 2016 through September 2016, and November 2016, were the warmest observed for each month of the year. Continuing this trend, the AIRS global surface temperatures of 2017 February and April show the second greatest positive anomalies from average. This recent warming is particularly significant over the Arctic where the snow and sea ice melt is closely tied to the spring and summer surface temperatures. In this paper, we show the global distribution of surface temperature anomalies as observed by AIRS over the period September 2002 through August 2017 and compare them with those from the GISSTEMP and MERRA-2 surface temperatures. The spatial patterns of warm and cold anomalies for a given month show reasonably good agreement in all three data set. AIRS anomalies, which do not have the benefit of in-situ measurements, are in almost perfect agreement with those of MERRA-2, which does use in-situ surface measurements. GISSTEMP anomaly patterns for the most part look similar to those of AIRS and MERRA-2, but are more spread out spatially, and consequently are also weaker.

  13. M2-F1 in flight over lakebed on tow line

    NASA Image and Video Library

    1963-08-30

    Following the first M2-F1 airtow flight on 16 August 1963, the Flight Research Center used the vehicle for both research flights and to check out new lifting-body pilots. These included Bruce Peterson, Don Mallick, Fred Haise, and Bill Dana from NASA. Air Force pilots who flew the M2-F1 included Chuck Yeager, Jerry Gentry, Joe Engle, Jim Wood, and Don Sorlie, although Wood, Haise, and Engle only flew on car tows. In the three years between the first and last flights of the M2-F1, it made about 400 car tows and 77 air tows.

  14. Observations of the microclimate of a lake under cold air advective conditions

    NASA Technical Reports Server (NTRS)

    Bill, R. G., Jr.; Sutherland, R. A.; Bartholic, J. F.

    1977-01-01

    The moderating effects of Lake Apopka, Florida, on downwind surface temperatures were evaluated under cold air advective conditions. Point temperature measurements north and south of the lake and data obtained from the NOAA satellite and a thermal scanner flown at 1.6 km, indicate that, under conditions of moderate winds (approximately 4m/sec), surface temperatures directly downwind may be higher than surrounding surface temperatures by as much as 5 C. With surface wind speed less than 1m/sec, no substantial temperature effects were observed. Results of this study are being used in land use planning, lake level control and in agriculture for selecting planting sites.

  15. An observation tool to study air traffic control and flightdeck collaboration.

    PubMed

    Cox, Gemma; Sharples, Sarah; Stedmon, Alex; Wilson, John

    2007-07-01

    The complex systems of the flightdeck (FD) and the Air Traffic Control Centre (ATC) are characterised by numerous concurrently operating and interacting communication channels between people and between people and machines/computer systems. This paper describes work in support of investigating the impact of changes to technologies and responsibilities within this system with respect to human factors. It focuses primarily on the introduction of datalink (text-based communication rather than traditional radio communication) and the move towards freeflight (pilot-mediated air traffic control). Air traffic management investigations have outlined these specific changes as strategies to enable further increases in the volume of air traffic. A systems approach was taken and field studies were conducted. Small numbers of domain experts such as air traffic controllers (ATCOs) were involved in the field-based observations of how people interact with systems and each other. This paper summarises the overall research approach taken and then specifically reports on the field-based observations including the justification, development, and findings of the observation tool used. The observation tool examined information propagation through the air traffic control-flightdeck (ATC-FD) system, and resulted in models of possible information trajectories through the system.

  16. Recent Global Warming as Observed by AIRS and Depicted in GISSTEMP and MERRA-2

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Lee, Jae; Iredell, Lena

    2017-01-01

    AIRS Version-6 monthly mean level-3 surface temperature products confirm the result, depicted in the GISSTEMP dataset, that the earth's surface temperature has been warming since early 2015, though not before that. AIRS is at a higher spatial resolution than GISSTEMP, and produces sharper spatial features which are otherwise in excellent agreement with those of GISSTEMP. Version-6 AO Ts anomalies are consistent with those of Version-6 AIRS/AMSU. Version-7 AO anomalies should be even more accurate, especially at high latitudes. ARCs of MERRA-2 Ts anomalies are spurious as a result of a discontinuity which occurred somewhere between 2007 and 2008. This decreases global mean trends.

  17. Transparency of the 2 μm window on Titan studied with observations made by VIMS

    NASA Astrophysics Data System (ADS)

    Rannou, P.; Lemouélic, S.; Sotin, C.; Brown, R. H.

    2012-09-01

    The study of Titan properties with remote sensing relies on a good knowledge of the atmosphere properties. The in-situ observations made by Huygens combined with recent advances in the definition of methane properties enable to model and interpret observations with a very good accuracy. However, intensity at some wavelengths are poorly modeled because additional opacities must be studied. We focus here on the case of the 2 μm window, which is essential to determined cloud and surface properties.

  18. EPA True NO2 ground site measurements ?? multiple sites, TCEQ ground site measurements of meteorological and air pollution parameters ?? multiple sites ,GeoTASO NO2 Vertical Column

    EPA Pesticide Factsheets

    EPA True NO2 ground site measurements ?? multiple sites - http://www-air.larc.nasa.gov/cgi-bin/ArcView/discover-aq.tx-2013; TCEQ ground site measurements of meteorological and air pollution parameters ?? multiple sites - http://www-air.larc.nasa.gov/cgi-bin/ArcView/discover-aq.tx-2013; GeoTASO NO2 Vertical Column - http://www-air.larc.nasa.gov/cgi-bin/ArcView/discover-aq.tx-2013?FALCON=1This dataset is associated with the following publication:Nowlan, C., X. Lu, J. Leitch, K. Chance, G. González Abad, C. Lu, P. Zoogman, J. Cole, T. Delker, W. Good, F. Murcray, L. Ruppert, D. Soo, M. Follette-Cook, S. Janz, M. Kowalewski, C. Loughner, K. Pickering, J. Herman, M. Beaver, R. Long, J. Szykman, L. Judd, P. Kelley, W. Luke, X. Ren, and J. Al-Saadi. Nitrogen dioxide observations from the Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument: Retrieval algorithm and measurements during DISCOVER-AQ Texas 2013. Atmospheric Measurement Techniques. Copernicus Publications, Katlenburg-Lindau, GERMANY, 9(6): 2647-2668, (2016).

  19. Improving UK Air Quality Modelling Through Exploitation of Satellite Observations

    NASA Astrophysics Data System (ADS)

    Pope, Richard; Chipperfield, Martyn; Savage, Nick

    2014-05-01

    In this work the applicability of satellite observations to evaluate the operational UK Met Office Air Quality in the Unified Model (AQUM) have been investigated. The main focus involved the AQUM validation against satellite observations, investigation of satellite retrieval error types and of synoptic meteorological-atmospheric chemistry relationships simulated/seen by the AQUM/satellite. The AQUM is a short range forecast model of atmospheric chemistry and aerosols up to 5 days. It has been designed to predict potentially hazardous air pollution events, e.g. high concentrations of surface ozone. The AQUM has only been validated against UK atmospheric chemistry recording surface stations. Therefore, satellite observations of atmospheric chemistry have been used to further validate the model, taking advantage of better satellite spatial coverage. Observations of summer and winter 2006 tropospheric column NO2 from both OMI and SCIAMACHY show that the AQUM generally compares well with the observations. However, in northern England positive biases (AQUM - satellite) suggest that the AQUM overestimates column NO2; we present results of sensitivity experiments on UK emissions datasets suspected to be the cause. In winter, the AQUM over predicts background column NO2 when compared to both satellite instruments. We hypothesise that the cause is the AQUM winter night-time chemistry, where the NO2 sinks are not substantially defined. Satellite data are prone to errors/uncertainty such as random, systematic and smoothing errors. We have investigated these error types and developed an algorithm to calculate and reduce the random error component of DOAS NO2 retrievals, giving more robust seasonal satellite composites. The Lamb Weather Types (LWT), an objective method of classifying the daily synoptic weather over the UK, were used to create composite satellite maps of column NO2 under different synoptic conditions. Under cyclonic conditions, satellite observed UK column NO2 is

  20. Ice Surface Temperature Variability in the Polar Regions and the Relationships to 2 Meter Air Temperatures

    NASA Astrophysics Data System (ADS)

    Hoyer, J.; Madsen, K. S.; Englyst, P. N.

    2017-12-01

    Determining the surface and near surface air temperature from models or observations in the Polar Regions is challenging due to the extreme conditions and the lack of in situ observations. The errors in near surface temperature products are typically larger than for other regions of the world, and the potential for using Earth Observations is large. As part of the EU project, EUSTACE, we have developed empirical models for the relationship between the satellite observed skin ice temperatures and 2m air temperatures. We use the Arctic and Antarctic Sea and sea ice Surface Temperatures from thermal Infrared satellite sensors (AASTI) reanalysis to estimate daily surface air temperature over land ice and sea ice for the Arctic and the Antarctic. Large efforts have been put into collecting and quality controlling in situ observations from various data portals and research projects. The reconstruction is independent of numerical weather prediction models and thus provides an important alternative to modelled air temperature estimates. The new surface air temperature data record has been validated against more than 58.000 independent in situ measurements for the four surface types: Arctic sea ice, Greenland ice sheet, Antarctic sea ice and Antarctic ice sheet. The average correlations are 92-97% and average root mean square errors are 3.1-3.6°C for the four surface types. The root mean square error includes the uncertainty of the in-situ measurement, which ranges from 0.5 to 2°C. A comparison with ERA-Interim shows a consistently better performance of the satellite based air temperatures than the ERA-Interim for the Greenland ice sheet, when compared against observations not used in any of the two estimates. This is encouraging and demonstrates the values of these products. In addition, the procedure presented here works on satellite observations that are available in near real time and this opens up for a near real time estimation of the surface air temperature over

  1. In-situ observations of Eyjafjallajökull ash particles by hot-air balloon

    NASA Astrophysics Data System (ADS)

    Petäjä, T.; Laakso, L.; Grönholm, T.; Launiainen, S.; Evele-Peltoniemi, I.; Virkkula, A.; Leskinen, A.; Backman, J.; Manninen, H. E.; Sipilä, M.; Haapanala, S.; Hämeri, K.; Vanhala, E.; Tuomi, T.; Paatero, J.; Aurela, M.; Hakola, H.; Makkonen, U.; Hellén, H.; Hillamo, R.; Vira, J.; Prank, M.; Sofiev, M.; Siitari-Kauppi, M.; Laaksonen, A.; lehtinen, K. E. J.; Kulmala, M.; Viisanen, Y.; Kerminen, V.-M.

    2012-03-01

    The volcanic ash cloud from Eyjafjallajökull volcanic eruption seriously distracted aviation in Europe. Due to the flight ban, there were only few in-situ measurements of the properties and dispersion of the ash cloud. In this study we show in-situ observations onboard a hot air balloon conducted in Central Finland together with regional dispersion modelling with SILAM-model during the eruption. The modeled and measured mass concentrations were in a qualitative agreement but the exact elevation of the layer was slightly distorted. Some of this discrepancy can be attributed to the uncertainty in the initial emission height and strength. The observed maximum mass concentration varied between 12 and 18 μg m -3 assuming a density of 2 g m -3, whereas the gravimetric analysis of the integrated column showed a maximum of 45 μg m -3 during the first two descents through the ash plume. Ion chromatography data indicated that a large fraction of the mass was insoluble to water, which is in qualitative agreement with single particle X-ray analysis. A majority of the super-micron particles contained Si, Al, Fe, K, Na, Ca, Ti, S, Zn and Cr, which are indicative for basalt-type rock material. The number concentration profiles indicated that there was secondary production of particles possibly from volcano-emitted sulfur dioxide oxidized to sulfuric acid during the transport.

  2. A Multiplatform Observations of Air Quality in Korea as the Pre-campaign of Korea and US Air Quality (KORUS-AQ) Study.

    NASA Astrophysics Data System (ADS)

    Park, J. H.; Hong, J.; Hong, Y.; Song, C. K.; Kim, S. K.; Chang, L. S.; Lim, J.; Ahn, J.; Kim, J. Y.; Han, Y. J.; Kim, J.; Park, R.; Lee, G.; Park, J.

    2015-12-01

    Despite the Korea government's efforts to regulate air pollutant emission for attaining the national air quality standard, current serious dust events and high ozone episodes in summer time remain important societal issues in Korea. In order to make effective policy for air quality attainment, it is contingent upon a thorough understanding of chemical production/loss mechanism of air pollutants and their precursors which drive air quality such as nitrogen oxides (NOX), volatile organic compounds (VOCs), and oxidants (e.g. OH, HO2, RO, RO2, etc.). At present, policy development is constrained by a lack of data for broad suite of chemical species which significantly affect on air quality.During 4 weeks between May and June 2013, the pre-campaign for the Korea and U.S. Air Quality (KORUS-AQ) study took place in multiplatform including fifteen ground sites, one mobile laboratory, and one small air crafts. An integrated research activity covering field observations, chemical transport models, and remote sensing has been intensively conducted. This study was focused on studying photochemistry and nighttime chemistry in urban area and transboundary transport of air pollutants from upwind. Scientific overview and outcomes from the campaign will be presented.

  3. Einstein X-ray observations of M101

    NASA Technical Reports Server (NTRS)

    Trinchieri, G.; Fabbiano, G.; Romaine, S.

    1990-01-01

    The Einstein X-ray observations of the face-on spiral galaxy M101 are presented. The global X-ray luminosity L(x) of M101 is about 1.2 x 10 to the 40th ergs/s for D = 7.2 Mpc, consistent with the expected X-ray luminosity of normal spiral galaxies of its optical magnitude. The X-ray emission is mostly due to very luminous individual sources, with L(x) greater than 10 to the 38th ergs/s each, most likely very massive accreting binary systems. The data suggest a deficiency of sources in the luminosity range of L(x) from about 10 to the 37th to about 10 to the 38th ergs/s, which would indicate that the luminosity distribution of the X-ray sources in M101 might be different from that of M31 or M33.

  4. Climate change impacts on sea-air fluxes of CO2 in three Arctic seas: a sensitivity study using Earth observation

    NASA Astrophysics Data System (ADS)

    Land, P. E.; Shutler, J. D.; Cowling, R. D.; Woolf, D. K.; Walker, P.; Findlay, H. S.; Upstill-Goddard, R. C.; Donlon, C. J.

    2013-12-01

    We applied coincident Earth observation data collected during 2008 and 2009 from multiple sensors (RA2, AATSR and MERIS, mounted on the European Space Agency satellite Envisat) to characterise environmental conditions and integrated sea-air fluxes of CO2 in three Arctic seas (Greenland, Barents, Kara). We assessed net CO2 sink sensitivity due to changes in temperature, salinity and sea ice duration arising from future climate scenarios. During the study period the Greenland and Barents seas were net sinks for atmospheric CO2, with integrated sea-air fluxes of -36 ± 14 and -11 ± 5 Tg C yr-1, respectively, and the Kara Sea was a weak net CO2 source with an integrated sea-air flux of +2.2 ± 1.4 Tg C yr-1. The combined integrated CO2 sea-air flux from all three was -45 ± 18 Tg C yr-1. In a sensitivity analysis we varied temperature, salinity and sea ice duration. Variations in temperature and salinity led to modification of the transfer velocity, solubility and partial pressure of CO2 taking into account the resultant variations in alkalinity and dissolved organic carbon (DOC). Our results showed that warming had a strong positive effect on the annual integrated sea-air flux of CO2 (i.e. reducing the sink), freshening had a strong negative effect and reduced sea ice duration had a small but measurable positive effect. In the climate change scenario examined, the effects of warming in just over a decade of climate change up to 2020 outweighed the combined effects of freshening and reduced sea ice duration. Collectively these effects gave an integrated sea-air flux change of +4.0 Tg C in the Greenland Sea, +6.0 Tg C in the Barents Sea and +1.7 Tg C in the Kara Sea, reducing the Greenland and Barents sinks by 11% and 53%, respectively, and increasing the weak Kara Sea source by 81%. Overall, the regional integrated flux changed by +11.7 Tg C, which is a 26% reduction in the regional sink. In terms of CO2 sink strength, we conclude that the Barents Sea is the most

  5. M2-F1 in flight over lakebed on tow line

    NASA Image and Video Library

    1963-08-16

    After initial ground-tow flights of the M2-F1 using the Pontiac as a tow vehicle, the way was clear to make air tows behind a C-47. The first air tow took place on 16 August 1963. Pilot Milt Thompson found that the M2-F1 flew well, with good control. This first flight lasted less than two minutes from tow-line release to touchdown. The descent rate was 4,000 feet per minute.

  6. Submillimeter observations of OH and CH in M42

    NASA Technical Reports Server (NTRS)

    Viscuso, P. J.; Stacy, G. J.; Fuller, C. E.; Kurtz, N. T.; Harwit, M.

    1985-01-01

    The (sup 2) pi sub 1/2 (J = 3/2 to 1/2) transitions of OH at 163.12 and 163.40 micro m have been detected and upper limits have been obtained for the (sup 2) pi sub 3/2 (J = 3/2 to 1/2) transitions of CH at 149.09 and 149.39 micro m, in observations of the Kleinmann-Low Nebula of Orion. All four flux levels lie between 1 and 1.2 x 10 to the 17th power/sq.cm. The OH lines are bright when compared to the lower, (sup 2) pi sub 3/2 (J = 5/2 to 3/2) fluxes reported and imply that the 119 micro m emission observed is partially self-absorbed. The combined results provide strong constraints. Taken together with existing data on molecular hydrogen and CO and recent data on other OH transition, they suggest OH emission from post-shock regions at temperatures T approx 1000 k, densities approx. 7 x 10 to the 6th powr/cu cm N sub OH approx 80/cu cm optically thick for the (sup 2) pi sub 3/2 (J = 5/2 to 3/2), 119 micro m but only partially self-absorbing in the (J = 7/2 to 3/2), 84 micro m transitions over a Doppler velocity bandwidth of 30 km/sec. The OH column density is N sub OH approx 4 x 10 to the 16th powr/sq cm. in the emitting regions which occupy a fraction of approx 0.1 of a 1' x 1' field of view centered on the Becklin-Neugebauer source. The CO (J = 31 to 30), 84 micro m transition appears to lie sufficiently close to one of the 84 micro m OH line components to be partially absorbed as well, through a Bowen-type mechanism.

  7. Improving Air Quality Forecasts with AURA Observations

    NASA Technical Reports Server (NTRS)

    Newchurch, M. J.; Biazer, A.; Khan, M.; Koshak, W. J.; Nair, U.; Fuller, K.; Wang, L.; Parker, Y.; Williams, R.; Liu, X.

    2008-01-01

    Past studies have identified model initial and boundary conditions as sources of reducible errors in air-quality simulations. In particular, improving the initial condition improves the accuracy of short-term forecasts as it allows for the impact of local emissions to be realized by the model and improving boundary conditions improves long range transport through the model domain, especially in recirculating anticyclones. During the August 2006 period, we use AURA/OMI ozone measurements along with MODIS and CALIPSO aerosol observations to improve the initial and boundary conditions of ozone and Particulate Matter. Assessment of the model by comparison of the control run and satellite assimilation run to the IONS06 network of ozonesonde observations, which comprise the densest ozone sounding campaign ever conducted in North America, to AURA/TES ozone profile measurements, and to the EPA ground network of ozone and PM measurements will show significant improvement in the CMAQ calculations that use AURA initial and boundary conditions. Further analyses of lightning occurrences from ground and satellite observations and AURA/OMI NO2 column abundances will identify the lightning NOx signal evident in OMI measurements and suggest pathways for incorporating the lightning and NO2 data into the CMAQ simulations.

  8. Different effects of long-term exposures to SO2 and NO2 air pollutants on asthma severity in young adults.

    PubMed

    Greenberg, Nili; Carel, Rafael S; Derazne, Estela; Bibi, Haim; Shpriz, Manor; Tzur, Dorit; Portnov, Boris A

    2016-01-01

    Numerous studies demonstrated that exposure to ambient air pollutants contributes to severity and frequency of asthma exacerbations. However, whether common air pollutants, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), exert differential effects on asthma occurrence and severity is unclear. The aim of this investigation was to determine whether exposure to NO2 and/or SO2 may initiate different long-term effects on prevalence and severity of asthma in young adults. Medical records of 137,040 males, 17 years old, who underwent standard premilitary service health examinations during 1999-2008 were examined. Air-pollution data for NO2 and SO2 were linked to the place of residence of each subject. The influence of specific air pollutants on asthma prevalence and severity was evaluated using bivariate logistic regression, controlling for individuals' sociodemographic attributes. For both ambient air pollutants, there was a significant dose-response effect on severity of asthma at ambient concentrations below the current National Ambient Air Quality Standards. However, in residential areas with high levels of SO2 (13.3-592.7µg/m(3)) and high levels of NO2 (27.2-43.2µg/m(3)) the risk of asthma occurrence was significantly higher than that in residential areas with high levels of NO2 (27.2-43.2 µg/m(3)) and intermediate levels (6.7-13.3 µg/m(3)) of SO2 pollution. The effects of exposure to SO2 and NO2 air pollutants on the respiratory airways system appear to differ, with possible implications regarding medical management, even in cases of exposure to mixtures of these pollutants.

  9. An upper limit of muon flux of energies above 100 TeV determined from horizontal air showers observed at Akeno

    NASA Technical Reports Server (NTRS)

    Nagano, M.; Yoshii, H.; Hara, T.; Kamata, K.; Kawaguchi, S.; Kifune, T.

    1985-01-01

    Muon energy spectrum above 100 TeV was determined by observing the extensive air showers (EAS) from the horizontal direction (HAS). No definite muon originated shower of sizes above 100,000 and zenith angles above 60 deg was observed. The upper limits of HAS intensity is 5x10/12 m/2 s/1 sn/1 above 100,000. It is indicated that the upper limit of muon flux above 100 TeV is about 1.3x10/8 m/2 s/1 sr/1 and is in agreement with that expected from the primary spectrum with a knee assuming scaling in the fragmentation region and 40% protons in the primary beam. The critical energy at which muon flux from prompt processes take over that from the conventional process is higher than 100 Tev at horizontal direction.

  10. Impact of atmospheric effects on the energy reconstruction of air showers observed by the surface detectors of the Pierre Auger Observatory

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Samarai, I. Al; Albuquerque, I. F. M.; Allekotte, I.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Anastasi, G. A.; Anchordoqui, L.; Andrada, B.; Andringa, S.; Aramo, C.; Arqueros, F.; Arsene, N.; Asorey, H.; Assis, P.; Aublin, J.; Avila, G.; Badescu, A. M.; Balaceanu, A.; Barreira Luz, R. J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; Berat, C.; Bertaina, M. E.; Bertou, X.; Biermann, P. L.; Billoir, P.; Biteau, J.; Blaess, S. G.; Blanco, A.; Blazek, J.; Bleve, C.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Borodai, N.; Botti, A. M.; Brack, J.; Brancus, I.; Bretz, T.; Bridgeman, A.; Briechle, F. L.; Buchholz, P.; Bueno, A.; Buitink, S.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, L.; Cancio, A.; Canfora, F.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Chavez, A. G.; Chinellato, J. A.; Chudoba, J.; Clay, R. W.; Colalillo, R.; Coleman, A.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; D'Amico, S.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; de Jong, S. J.; De Mauro, G.; de Mello Neto, J. R. T.; De Mitri, I.; de Oliveira, J.; de Souza, V.; Debatin, J.; Deligny, O.; Di Giulio, C.; Di Matteo, A.; Díaz Castro, M. L.; Diogo, F.; Dobrigkeit, C.; D'Olivo, J. C.; dos Anjos, R. C.; Dova, M. T.; Dundovic, A.; Ebr, J.; Engel, R.; Erdmann, M.; Erfani, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Falcke, H.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Fick, B.; Figueira, J. M.; Filipčič, A.; Fratu, O.; Freire, M. M.; Fujii, T.; Fuster, A.; Gaior, R.; García, B.; Garcia-Pinto, D.; Gaté, F.; Gemmeke, H.; Gherghel-Lascu, A.; Ghia, P. L.; Giaccari, U.; Giammarchi, M.; Giller, M.; Głas, D.; Glaser, C.; Glass, H.; Golup, G.; Gómez Berisso, M.; Gómez Vitale, P. F.; González, N.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grillo, A. F.; Grubb, T. D.; Guarino, F.; Guedes, G. P.; Hampel, M. R.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Hasankiadeh, Q.; Haungs, A.; Hebbeker, T.; Heck, D.; Heimann, P.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huege, T.; Hulsman, J.; Insolia, A.; Isar, P. G.; Jandt, I.; Jansen, S.; Johnsen, J. A.; Josebachuili, M.; Kääpä, A.; Kambeitz, O.; Kampert, K. H.; Kasper, P.; Katkov, I.; Keilhauer, B.; Kemp, E.; Kemp, J.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Krause, R.; Krohm, N.; Kuempel, D.; Kukec Mezek, G.; Kunka, N.; Kuotb Awad, A.; LaHurd, D.; Lauscher, M.; Lebrun, P.; Legumina, R.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; Lopes, L.; López, R.; López Casado, A.; Luce, Q.; Lucero, A.; Malacari, M.; Mallamaci, M.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Mariš, I. C.; Marsella, G.; Martello, D.; Martinez, H.; Martínez Bravo, O.; Masías Meza, J. J.; Mathes, H. J.; Mathys, S.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melo, D.; Menshikov, A.; Messina, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Mockler, D.; Mollerach, S.; Montanet, F.; Morello, C.; Mostafá, M.; Müller, A. L.; Müller, G.; Muller, M. A.; Müller, S.; Mussa, R.; Naranjo, I.; Nellen, L.; Neuser, J.; Nguyen, P. H.; Niculescu-Oglinzanu, M.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Novotny, V.; Nožka, H.; Núñez, L. A.; Ochilo, L.; Oikonomou, F.; Olinto, A.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Papenbreer, P.; Parente, G.; Parra, A.; Paul, T.; Pech, M.; Pedreira, F.; Pȩkala, J.; Pelayo, R.; Peña-Rodriguez, J.; Pereira, L. A. S.; Perlín, M.; Perrone, L.; Peters, C.; Petrera, S.; Phuntsok, J.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Porowski, C.; Prado, R. R.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Ramos-Pollan, R.; Rautenberg, J.; Ravignani, D.; Revenu, B.; Ridky, J.; Risse, M.; Ristori, P.; Rizi, V.; Rodrigues de Carvalho, W.; Rodriguez Fernandez, G.; Rodriguez Rojo, J.; Rogozin, D.; Roncoroni, M. J.; Roth, M.; Roulet, E.; Rovero, A. C.; Ruehl, P.; Saffi, S. J.; Saftoiu, A.; Salazar, H.; Saleh, A.; Salesa Greus, F.; Salina, G.; Sanabria Gomez, J. D.; Sánchez, F.; Sanchez-Lucas, P.; Santos, E. M.; Santos, E.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sarmiento, C. A.; Sato, R.; Schauer, M.; Scherini, V.; Schieler, H.; Schimp, M.; Schmidt, D.; Scholten, O.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Schumacher, J.; Sciutto, S. J.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sigl, G.; Silli, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sonntag, S.; Sorokin, J.; Squartini, R.; Stanca, D.; Stanič, S.; Stasielak, J.; Stassi, P.; Strafella, F.; Suarez, F.; Suarez Durán, M.; Sudholz, T.; Suomijärvi, T.; Supanitsky, A. D.; Swain, J.; Szadkowski, Z.; Taboada, A.; Taborda, O. A.; Tapia, A.; Theodoro, V. M.; Timmermans, C.; Todero Peixoto, C. J.; Tomankova, L.; Tomé, B.; Torralba Elipe, G.; Torres Machado, D.; Torri, M.; Travnicek, P.; Trini, M.; Ulrich, R.; Unger, M.; Urban, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van Bodegom, P.; van den Berg, A. M.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Vergara Quispe, I. D.; Verzi, V.; Vicha, J.; Villaseñor, L.; Vorobiov, S.; Wahlberg, H.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weindl, A.; Wiencke, L.; Wilczyński, H.; Winchen, T.; Wittkowski, D.; Wundheiler, B.; Yang, L.; Yelos, D.; Yushkov, A.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zepeda, A.; Zimmermann, B.; Ziolkowski, M.; Zong, Z.; Zuccarello, F.

    2017-02-01

    Atmospheric conditions, such as the pressure (P), temperature (T) or air density (ρ propto P/T), affect the development of extended air showers initiated by energetic cosmic rays. We study the impact of the atmospheric variations on the reconstruction of air showers with data from the arrays of surface detectors of the Pierre Auger Observatory, considering separately the one with detector spacings of 1500 m and the one with 750 m spacing. We observe modulations in the event rates that are due to the influence of the air density and pressure variations on the measured signals, from which the energy estimators are obtained. We show how the energy assignment can be corrected to account for such atmospheric effects.

  11. Evaluation of 11 terrestrial carbon–nitrogen cycle models against observations from two temperate Free-Air CO2 Enrichment studies

    PubMed Central

    Zaehle, Sönke; Medlyn, Belinda E; De Kauwe, Martin G; Walker, Anthony P; Dietze, Michael C; Hickler, Thomas; Luo, Yiqi; Wang, Ying-Ping; El-Masri, Bassil; Thornton, Peter; Jain, Atul; Wang, Shusen; Warlind, David; Weng, Ensheng; Parton, William; Iversen, Colleen M; Gallet-Budynek, Anne; McCarthy, Heather; Finzi, Adrien; Hanson, Paul J; Prentice, I Colin; Oren, Ram; Norby, Richard J

    2014-01-01

    We analysed the responses of 11 ecosystem models to elevated atmospheric [CO2] (eCO2) at two temperate forest ecosystems (Duke and Oak Ridge National Laboratory (ORNL) Free-Air CO2 Enrichment (FACE) experiments) to test alternative representations of carbon (C)–nitrogen (N) cycle processes. We decomposed the model responses into component processes affecting the response to eCO2 and confronted these with observations from the FACE experiments. Most of the models reproduced the observed initial enhancement of net primary production (NPP) at both sites, but none was able to simulate both the sustained 10-yr enhancement at Duke and the declining response at ORNL: models generally showed signs of progressive N limitation as a result of lower than observed plant N uptake. Nonetheless, many models showed qualitative agreement with observed component processes. The results suggest that improved representation of above-ground–below-ground interactions and better constraints on plant stoichiometry are important for a predictive understanding of eCO2 effects. Improved accuracy of soil organic matter inventories is pivotal to reduce uncertainty in the observed C–N budgets. The two FACE experiments are insufficient to fully constrain terrestrial responses to eCO2, given the complexity of factors leading to the observed diverging trends, and the consequential inability of the models to explain these trends. Nevertheless, the ecosystem models were able to capture important features of the experiments, lending some support to their projections. PMID:24467623

  12. Air pollution and clouds in southern China: preliminary results from the observations in spring 2009 at Mt. Heng

    NASA Astrophysics Data System (ADS)

    Wang, T.; Xue, L.; Gao, X.; Nie, W.; Wang, X.; Wang, Y.; Sun, M.; Ding, A.; Fan, S.; Zhang, Q.; Wang, W.

    2009-12-01

    Aerosols and clouds play a key role in climate change, and the interaction between them also affect the chemical transformation and removal of air pollutants. As a part of China's National Basic Research Project (National '973 Project) on acid deposition, trace gases, aerosols, and cloud water composition were measured in March-May 2009 at the summit of Mount Heng in southern China (Long: 112° 42’ E, Lat: 27 ° 18’ N, 1269 m a.s.l.). The preliminary results from this study are presented. Frequent clouds/fogs occurred at this site. Despite its southern location, the impact of a dust storm from northern China was observed in late April during which the PM10 concentration exceeded 800 ug/m3. Moderate levels of pollution were observed. Formation and growth of new particles frequently occurred on clear days as indicated from the measurement of particle number and size distributions. Cloud water was mostly acidic with a mean acidity of 3.75 (range: 2.51-6.91). The chemical data from this study are compared with those from Mt Tai to show the difference in southern and northern China. The sources of air pollution at this mountain site and the implications of the results will be discussed.

  13. Direct electrolytic dissolution of silicate minerals for air CO2 mitigation and carbon-negative H2 production

    PubMed Central

    Rau, Greg H.; Carroll, Susan A.; Bourcier, William L.; Singleton, Michael J.; Smith, Megan M.; Aines, Roger D.

    2013-01-01

    We experimentally demonstrate the direct coupling of silicate mineral dissolution with saline water electrolysis and H2 production to effect significant air CO2 absorption, chemical conversion, and storage in solution. In particular, we observed as much as a 105-fold increase in OH− concentration (pH increase of up to 5.3 units) relative to experimental controls following the electrolysis of 0.25 M Na2SO4 solutions when the anode was encased in powdered silicate mineral, either wollastonite or an ultramafic mineral. After electrolysis, full equilibration of the alkalized solution with air led to a significant pH reduction and as much as a 45-fold increase in dissolved inorganic carbon concentration. This demonstrated significant spontaneous air CO2 capture, chemical conversion, and storage as a bicarbonate, predominantly as NaHCO3. The excess OH− initially formed in these experiments apparently resulted via neutralization of the anolyte acid, H2SO4, by reaction with the base mineral silicate at the anode, producing mineral sulfate and silica. This allowed the NaOH, normally generated at the cathode, to go unneutralized and to accumulate in the bulk electrolyte, ultimately reacting with atmospheric CO2 to form dissolved bicarbonate. Using nongrid or nonpeak renewable electricity, optimized systems at large scale might allow relatively high-capacity, energy-efficient (<300 kJ/mol of CO2 captured), and inexpensive (<$100 per tonne of CO2 mitigated) removal of excess air CO2 with production of carbon-negative H2. Furthermore, when added to the ocean, the produced hydroxide and/or (bi)carbonate could be useful in reducing sea-to-air CO2 emissions and in neutralizing or offsetting the effects of ongoing ocean acidification. PMID:23729814

  14. Statistical analysis of PM2.5 observations from diplomatic facilities in China

    NASA Astrophysics Data System (ADS)

    San Martini, Federico M.; Hasenkopf, Christa A.; Roberts, David C.

    2015-06-01

    Systematic monitoring of air quality are lacking in many parts of the world, especially in cities where air quality is poor. Since 2008, the U.S. Embassy in Beijing has been collecting real-time air-quality data from a monitor on the Embassy's rooftop and sharing that data publicly through social media. Using this freely available data, as well as those from four other U.S. consulates in China that are also now collecting and sharing data publicly, we demonstrate that rooftop air-quality monitors installed at embassies and consulates can further our understanding of air quality and provide a rich, hourly-averaged, long-term data source for the academic community and decision-makers. For example, this is the first study to present an analysis of diurnal variability of PM2.5 in Chengdu, Guangzhou, Shanghai, and Shenyang. We analyzed the diurnal variability of PM2.5 over the entire period of measurement for those cities and Beijing, and found marked variation across seasons and between cities. This dataset allows comparison of the PM2.5 annual average concentrations in 2013, with Guangzhou reporting 56.3 μg/m3, Shanghai 61.6 μg/m3, Chengdu 96.1 μg/m3, Beijing 99.6 μg/m3, and Shenyang 76.3 μg/m3 (note the average in Shenyang is from August 2013-July 2014). This study demonstrates the potential uses of air quality data that is currently systematically being collected and made publicly accessible by U.S. embassies and consulates in polluted but under-studied locations.

  15. Kinetic and thermochemical studies of the ClO + ClO + M ↔ Cl2O2 + M reaction

    NASA Astrophysics Data System (ADS)

    Ferracci, V.; Rowley, D. M.

    2009-12-01

    Chlorine monoxide (ClO) radicals play a crucial role in polar ozone destruction events and the ClO dimer cycle has been identified as one of the most effective ozone-depleting catalytic cycles operating in the polar winter. A recent paper by von Hobe et al.1 highlighted significant inconsistencies between laboratory results, theoretical calculations and field observations concerning the ClO dimer ozone destruction cycle. This work has investigated the temperature dependence of the equilibrium constant of one of the key reactions in this cycle, ClO + ClO + M ↔ Cl2O2 + M (1, -1), by means of laser flash photolysis coupled with time-resolved UV absorption spectroscopy. ClO radicals were generated via laser flash photolysis of Cl2/Cl2O mixtures in synthetic air. The concentration of radicals was monitored via UV absorption spectroscopy: the use of a Charge Coupled Device (CCD) detector allowed time resolution over a broad range of wavelengths. The equilibrium constant Keq was determined as the ratio of the rate constants of the forward and reverse reaction (1, -1) over the T range 256 - 312 K. Second Law and Third Law analytical methods were employed to determine the standard enthalpy and entropy changes of reaction 1, ΔrH° and ΔrS°, from the measured equilibrium constants. The values obtained from the Second Law analysis (ΔrH° = - 80.8 ± 2.2 kJ mol-1; ΔrS° = - 168.4 ± 7.9 J K-1 mol-1) are in good agreement with previous work 2 but greater in magnitude than current NASA recommendations 3. It was also found that, under typical laboratory conditions employed in this work, [ClO] decay exhibits pure second order kinetics at T ≤ 250 K. A higher rate constant for the ClO recombination reaction (1) was also observed in this work (compared to the NASA evaluation 3), implying a higher Keq and a different partitioning between ClO and Cl2O2, shifting towards the dimer. 1. M. Von Hobe, R. J. Salawitch, T. Canty, H. Keller-Rudek, G. K. Moortgat, J.-U. Grooss, R. M

  16. Data Assimilation of AirSWOT and Synthetically Derived SWOT Observations of Water Surface Elevation in a Multichannel River

    NASA Astrophysics Data System (ADS)

    Altenau, E. H.; Pavelsky, T.; Andreadis, K.; Bates, P. D.; Neal, J. C.

    2017-12-01

    Multichannel rivers continue to be challenging features to quantify, especially at regional and global scales, which is problematic because accurate representations of such environments are needed to properly monitor the earth's water cycle as it adjusts to climate change. It has been demonstrated that higher-complexity, 2D models outperform lower-complexity, 1D models in simulating multichannel river hydraulics at regional scales due to the inclusion of the channel network's connectivity. However, new remote sensing measurements from the future Surface Water and Ocean Topography (SWOT) mission and it's airborne analog AirSWOT offer new observations that can be used to try and improve the lower-complexity, 1D models to achieve accuracies closer to the higher-complexity, 2D codes. Here, we use an Ensemble Kalman Filter (EnKF) to assimilate AirSWOT water surface elevation (WSE) measurements from a 2015 field campaign into a 1D hydrodynamic model along a 90 km reach of Tanana River, AK. This work is the first to test data assimilation methods using real SWOT-like data from AirSWOT. Additionally, synthetic SWOT observations of WSE are generated across the same study site using a fine-resolution 2D model and assimilated into the coarser-resolution 1D model. Lastly, we compare the abilities of AirSWOT and the synthetic-SWOT observations to improve spatial and temporal model outputs in WSEs. Results indicate 1D model outputs of spatially distributed WSEs improve as observational coverage increases, and improvements in temporal fluctuations in WSEs depend on the number of observations. Furthermore, results reveal that assimilation of AirSWOT observations produce greater error reductions in 1D model outputs compared to synthetic SWOT observations due to lower measurement errors. Both AirSWOT and the synthetic SWOT observations significantly lower spatial and temporal errors in 1D model outputs of WSEs.

  17. Air quality at outdoor community events: findings from fine particulate (PM2.5) sampling at festivals in Edmonton, Alberta.

    PubMed

    Collins, Damian; Parsons, Marc; Zinyemba, Chaka

    2014-01-01

    Exposure to fine particulate matter (PM2.5) is associated with a broad range of health risks. This study assessed the impacts of cooking smoke and environmental tobacco smoke on air quality at outdoor community events in Edmonton, Alberta (Canada). Data were collected at three festivals in July-August 2011 using a portable real-time airborne particle monitor. The pooled mean PM2.5 level was 12.41 μg/m(3). Peak readings varied from 52 to 1877 μg/m(3). Mean PM2.5 near food stalls was 35.42 μg/m(3), which exceeds the WHO limit for 24 h exposure. Mean PM2.5 levels with smokers present were 16.39 μg/m(3) (all points) and 9.64 μg/m(3) (excluding points near food stalls). Although some smokers withdrew from common spaces, on average 20 smokers/hour were observed within 3 m. Extending smoking bans would improve air quality and address related concerns. However, food preparation is a more pressing area for policy action to reduce PM2.5 exposure at these community events.

  18. [Contamination levels to room air arising from the use of 99mTc-gas and prevention from the contamination].

    PubMed

    Komatani, A; Akutsu, T; Yamaguchi, K; Onodera, Y; Manaka, Y; Takahashi, K

    1996-04-01

    99mTc-gas (TECHNEGAS) is a 99mTc-labeled micro-aerosol which is considered to have different behavior from 133Xe or 81mKr gas. In order to estimate contamination levels to room air arising from the use of 99mTc-gas, filtered expired air during administration and 1, 2, 3, 5, 10 min after the administration were collected in each polyethylene bag. Radioactivities of the polyethylene bags, used filter and the lung were measured with 3-head scintillation camera. The activity of the expired air diminished within 6-10 min and about 5% of whole discharged 99mTc-gas was released to room air. The activity of the used filter was two times of the lung. According to these results, it is recommended that the 99mTc-gas may be administrated in a exclusive room. The administrated patient and used filter must be remain in the exclusive room.

  19. Distribution of H2O and CO2 in the inner coma of 67P/CG as observed by VIRTIS-M onboard Rosetta

    NASA Astrophysics Data System (ADS)

    Capaccioni, F.

    2015-10-01

    VIRTIS (Visible, Infrared and Thermal Imaging Spectrometers) is a dual channel spectrometer; VIRTIS-M (M for Mapper) is a hyper-spectral imager covering a wide spectral range with two detectors: a CCD (VIS) ranging from 0.25 through 1.0 μm and an HgCdTe detector (IR) covering the 1.0 through 5.1 μm region. VIRTIS-M uses a slit and a scan mirror to generate images with spatial resolution of 250 μrad over a FOV of 64 mrad. The second channel is VIRTIS-H (H for High resolution), a point spectrometer with high spectral resolution (λ/Δλ=3000@3 μm) in the range 2-5 μm [1].The VIRTIS instrument has been used to investigate the molecular composition of the coma of 67P/CG by observing resonant fluorescent excitation in the 2 to 5 μm spectral region. The spectrum consists of emission bands superimposed on a background continuum. The strongest features are the bands of H2O at 2.7 μm and the CO2 band at 4.27 μm [1]. The high spectral resolution of VIRTIS-H obtains a detailed description of the fluorescent bands, while the mapping capability of VIRTIS-M extends the coverage in the spatial dimension to map and monitor the abundance of water and carbon dioxide in space and time. We have already reported [2,3,4] some preliminary observations by VIRTIS of H2O and CO2 in the coma. In the present work we perform a systematic mapping of the distribution and variability of these molecules using VIRTIS-M measurements of their band areas. All the spectra were carefully selected to avoid contamination due to nucleus radiance. A median filter is applied on the spatial dimensions of each data cube to minimise the pixel-to-pixel residual variability. This is at the expense of some reduction in the spatial resolution, which is still in the order of few tens of metres and thus adequate for the study of the spatial distribution of the volatiles. Typical spectra are shown in Figure 1

  20. Observational analyses of dramatic developments of a severe air pollution event in the Beijing area

    NASA Astrophysics Data System (ADS)

    Li, Ju; Sun, Jielun; Zhou, Mingyu; Cheng, Zhigang; Li, Qingchun; Cao, Xiaoyan; Zhang, Jingjiang

    2018-03-01

    A rapid development of a severe air pollution event in Beijing, China, at the end of November 2015 was investigated with unprecedented observations collected during the field campaign of the Study of Urban Rainfall and Fog/Haze (SURF-15). Different from previous statistical analyses of air pollution events and their correlations with meteorological environmental conditions in the area, the role of turbulent mixing in the pollutant transfer was investigated in detail. The analyses indicate that the major pollution source associated with high particulate matter of diameter 2.5 µm (PM2.5) was from south of Beijing. Before the day of the dramatic PM2.5 increase, the nighttime downslope flow from the mountains to the west and north of Beijing reduced the surface PM2.5 concentration northwest of Beijing. The nighttime surface stable boundary layer (SBL) not only kept the relatively less-polluted air near the surface, it also shielded the rough surface from the pollutant transfer by southwesterly winds above the SBL, leading to the fast transport of pollutants over the Beijing area at night. As the daytime convective turbulent mixing developed in the morning, turbulent mixing transported the elevated polluted air downward even though the weak surface wind was from northeast, leading to the dramatic increase of the surface PM2.5 concentration in the urban area. As a result of both turbulent mixing and advection processes with possible aerosol growth from secondary aerosol formation under the low-wind and high-humidity conditions, the PM2.5 concentration reached over 700 µg m-3 in the Beijing area by the end of the day. Contributions of the two transporting processes to the PM2.5 oscillations prior to this dramatic event were also analyzed. The study demonstrates the important role of large-eddy convective turbulent mixing in vertical transfer of pollutants and the role of the SBL in not only decoupling vertical transport of trace gases and aerosols but also in

  1. Impact of atmospheric effects on the energy reconstruction of air showers observed by the surface detectors of the Pierre Auger Observatory

    DOE PAGES

    Aab, A.; Abreu, P.; Aglietta, M.; ...

    2017-02-07

    Atmospheric conditions, such as the pressure (P), temperature (T) or air density (more » $$\\rho \\propto P/T$$), affect the development of extended air showers initiated by energetic cosmic rays. We study the impact of the atmospheric variations on the reconstruction of air showers with data from the arrays of surface detectors of the Pierre Auger Observatory, considering separately the one with detector spacings of 1500 m and the one with 750 m spacing. We observe modulations in the event rates that are due to the influence of the air density and pressure variations on the measured signals, from which the energy estimators are obtained. Lastly, we show how the energy assignment can be corrected to account for such atmospheric effects.« less

  2. Impact of atmospheric effects on the energy reconstruction of air showers observed by the surface detectors of the Pierre Auger Observatory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aab, A.; Abreu, P.; Aglietta, M.

    Atmospheric conditions, such as the pressure (P), temperature (T) or air density (more » $$\\rho \\propto P/T$$), affect the development of extended air showers initiated by energetic cosmic rays. We study the impact of the atmospheric variations on the reconstruction of air showers with data from the arrays of surface detectors of the Pierre Auger Observatory, considering separately the one with detector spacings of 1500 m and the one with 750 m spacing. We observe modulations in the event rates that are due to the influence of the air density and pressure variations on the measured signals, from which the energy estimators are obtained. Lastly, we show how the energy assignment can be corrected to account for such atmospheric effects.« less

  3. Multi-perspective observations of NO2 over the Denver area ...

    EPA Pesticide Factsheets

    The final deployment in the DISCOVER-AQ1 series of air quality field campaigns focused on the Northern Front Range of Colorado including the Denver Metropolitan Area in July-August 2014. The overarching goal of these campaigns was to improve the interpretation of satellite observations to diagnose near-surface air quality conditions. This called for observations to be combined from multiple perspectives that included ground-based as well as airborne in situ and remote sensing measurements. These observations were collected to demonstrate how future geostationary satellites could provide information of direct benefit to agencies responsible for monitoring and regulating air quality. This article focuses specifically on measurements of nitrogen dioxide (NO2), which are critical to understanding the photochemical production of ozone (O3). Published in the August issue of EM: AIR AND WASTE MANAGEMENT ASSOCIATIONS MAGAZINE FOR ENVIRONMENTAL MANAGERS

  4. Higher Capacity, Improved Conductive Matrix VB2/Air Batteries (Postprint)

    DTIC Science & Technology

    2016-02-18

    AFRL-RX-WP-JA-2016-0326 HIGHER CAPACITY, IMPROVED CONDUCTIVE MATRIX VB2/AIR BATTERIES (POSTPRINT) Matthew Lefler, Jessica...Interim 8 September 2014 – 20 September 2015 4. TITLE AND SUBTITLE HIGHER CAPACITY, IMPROVED CONDUCTIVE MATRIX VB2/AIR BATTERIES (POSTPRINT) 5a... batteries is that resistive oxide products impede the discharge depth, and only thin anode batteries (for example 10 mAh in a 1 cm diameter cell

  5. Air-stable hydrogen generation materials and enhanced hydrolysis performance of MgH2-LiNH2 composites

    NASA Astrophysics Data System (ADS)

    Ma, Miaolian; Ouyang, Liuzhang; Liu, Jiangwen; Wang, Hui; Shao, Huaiyu; Zhu, Min

    2017-08-01

    Hydrolysis of materials in water can be a promising solution of onsite hydrogen generation for realization of hydrogen economy. In this work, it was the first time that the MgH2-LiNH2 composites were explored as air-stable hydrolysis system for hydrogen generation. The MgH2-LiNH2 composites with different composition ratios were synthesized by ball milling with various durations and the hydrogen generation performances of the composite samples were investigated and compared. X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy techniques were adopted to elucidate the performance improvement mechanisms. The hydrolysis properties of MgH2 were found to be significantly enhanced by the introduction of LiNH2. The 4MgH2-LiNH2 composite ball milled for 5 h can generate 887.2 mL g-1 hydrogen in 1 min and 1016 mL g-1 in 50 min, one of the best results so far for Mg based hydrolysis materials. The LiOH·H2O and NH4OH phases of hydrolysis products from LiNH2 may prevent formation of Mg(OH)2 passivation layer on the surface and supply enough channels for hydrolysis of MgH2. The MgH2-LiNH2 composites appeared to be very stable in air and no obvious negative effect on kinetics and hydrogen generation yield was observed. These good performances demonstrate that the studied MgH2-LiNH2 composites can be a promising and practicable hydrogen generation system.

  6. M2-F1 cockpit

    NASA Technical Reports Server (NTRS)

    1963-01-01

    This photo shows the cockpit configuration of the M2-F1 wingless lifting body. With a top speed of about 120 knots, the M2-F1 had a simple instrument panel. Besides the panel itself, the ribs of the wooden shell (left) and the control stick (center) are also visible. The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and racing slicks, the Pontiac could tow the 1,000-pound M2-F1 110 miles per hour in 30 seconds. It proved adequate for the roughly 400 car tows that got the M2-F1 airborne to prove it could fly safely and to train pilots before they were towed behind a C-47

  7. Seasonal dynamics of coarse atmospheric particulate matter between 2.5 μm and 80 μm in Beijing and the impact of 2008 Olympic Games

    NASA Astrophysics Data System (ADS)

    Norra, Stefan; Yu, Yang; Dietze, Volker; Schleicher, Nina; Fricker, Mathieu; Kaminski, Uwe; Chen, Yuan; Stüben, Doris; Cen, Kuang

    2016-01-01

    Beijing is well known as a megacity facing severe atmospheric pollution problems. One very important kind of pollution is the high amount of particles in Beijing's atmosphere. Numerous studies investigated the dynamics of fine particles smaller 10 μm. Less information is available on the coarse particle fraction larger 10 μm, although geogenic dusts, which often are composed by those coarser particles, frequently affect the air quality in Beijing. Therefore, systematic sampling and analysis of size fractionated particulate matter between 2.5 and 80 μm was performed in Beijing from April 2005 till October 2009. Atmospheric particles were collected in the North-West of Beijing using a cost-effective passive sampling method called Sigma-2. Altogether, 200 weeks could be analysed and assessed. Concentrations and size distribution of atmospheric coarse particles were determined by automated microscopic single particle analysis. Seasonal variability of the total mass of different size fractions was identified as follows: spring > winter > autumn > summer. High concentrations of transparent mineral particles indicate the activity of geogenic sources in spring and winter time, due to asian dust events and resuspension of soil from local bare land during dry and windy periods. The percentage of opaque particle components differs seasonally with relatively high values in winter, confirming combustion of fossil fuels for heating purposes as a predominant pollution source in this season. The influence of meteorological conditions on concentrations and size distribution of atmospheric particulate matter between 2.5 and 80 μm is demonstrated for the whole sampling period. Lowest pollution by coarse aerosols occurred during the period of the 2008 Olympic Summer Games. A general trend of decreasing total coarse particle mass concentrations was observed. Due to frequently observed high total coarse particle mass concentrations of several 100 μg·m-³ it is strongly recommended

  8. 1.5 μm lidar anemometer for true air speed, angle of sideslip, and angle of attack measurements on-board Piaggio P180 aircraft

    NASA Astrophysics Data System (ADS)

    Augere, B.; Besson, B.; Fleury, D.; Goular, D.; Planchat, C.; Valla, M.

    2016-05-01

    Lidar (light detection and ranging) is a well-established measurement method for the prediction of atmospheric motions through velocity measurements. Recent advances in 1.5 μm Lidars show that the technology is mature, offers great ease of use, and is reliable and compact. A 1.5 μm airborne Lidar appears to be a good candidate for airborne in-flight measurement systems. It allows measurements remotely, outside aircraft aerodynamic disturbance, and absolute air speed (no need for calibration) with great precision in all aircraft flight domains. In the framework of the EU AIM2 project, the ONERA task has consisted of developing and testing a 1.5 μm anemometer sensor for in-flight airspeed measurements. The objective of this work is to demonstrate that the 1.5 μm Lidar sensor can increase the quality of the data acquisition procedure for aircraft flight test certification. This article presents the 1.5 μm anemometer sensor dedicated to in-flight airspeed measurements and describes the flight tests performed successfully on-board the Piaggio P180 aircraft. Lidar air data have been graphically compared to the air data provided by the aircraft flight test instrumentation (FTI) in the reference frame of the Lidar sensor head. Very good agreement of true air speed (TAS) by a fraction of ms-1, angle of sideslip (AOS), and angle of attack (AOA) by a fraction of degree were observed.

  9. Radical observations during the Clean air for London project

    NASA Astrophysics Data System (ADS)

    Whalley, L. K.; Stone, D.; Clancy, N.; Lee, J. D.; Laufs, S.; Kleffmann, J.; Heard, D. E.

    2012-12-01

    With greater than 50 % of the global population residing in urban conurbations, poor urban air quality has a demonstrable effect on human health. OH and HO2 radicals, (collectively termed HOx) together with RO2 radicals, mediate virtually all of the oxidative chemistry in the atmosphere, being responsible for the transformation of primary emissions into secondary pollutants such as NO2, O3 and particulates. Understanding the chemistry of free-radicals in the atmosphere is essential in improving predictions of the lifetimes of pollutants and spatial scales of their transport within urban areas. Results from earlier field campaigns in urban and polluted regions have demonstrated the significance of HONO photolysis and alkene ozonolysis in the production of HOx radicals. In many cases, however, measurements of HONO have not been made, reducing the ability to evaluate model successes for OH in these environments. Here we present measurements of OH, HO2, RO2 and OH reactivity taken during the wintertime (January - February, 2012) and summertime (July - August, 2012) as part of the Clean air for London (ClearfLo) project in London. RO2 was detected using a newly developed flow-reactor laser-induced fluorescence technique which is able to discriminate between HO2 and organic peroxy radicals [1]. Low concentrations of radicals were observed during the wintertime, midday [OH], [HO2] and [RO2] were ~ 0.04, 0.8 and 1.5 pptv respectively, comparable to observations of radicals at other urban locations in winter [2,3,4], and which displayed a negative correlation with NO concentrations. OH reactivity was high and largely tracked the diurnal profiles of NOx and CO, with the highest reactivity ~100 s-1 observed during the morning rush hour. Analysis of factors controlling OH concentrations during the wintertime suggests that the formation of OH from the photolysis of O3 and subsequent reaction of O(1D) with H2O is a minor contribution both under high and low NOx conditions owing

  10. Observations on persistent organic pollutants in indoor and outdoor air using passive polyurethane foam samplers

    NASA Astrophysics Data System (ADS)

    Bohlin, Pernilla; Jones, Kevin C.; Tovalin, Horacio; Strandberg, Bo

    Air quality data of persistent organic pollutants (POPs) indoors and outdoors are sparse or lacking in several parts of the world, often hampered by the cost and inconvenience of active sampling techniques. Cheap and easy passive air sampling techniques are therefore helpful for reconnaissance surveys. As a part of the Megacity Initiative: Local and Global Research Observations (MILAGRO) project in Mexico City Metropolitan Area in 2006, a range of POPs (polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ethers (PBDEs)) were analyzed in polyurethane foam (PUF) disks used as passive samplers in indoor and outdoor air. Results were compared to those from samplers deployed simultaneously in Gothenburg (Sweden) and Lancaster (United Kingdom). Using sampling rates suggested in the literature, the sums of 13 PAHs in the different sites were estimated to be 6.1-180 ng m -3, with phenanthrene as the predominant compound. Indoor PAH levels tended to be higher in Gothenburg and outdoor levels higher in Mexico City. The sum of PCBs ranged 59-2100 ng m -3, and seemed to be highest indoors in Gothenburg and Lancaster. PBDE levels (sum of seven) ranged 0.68-620 ng m -3, with the highest levels found in some indoor locations. OCPs (i.e. DDTs, HCHs, and chlordanes) were widely dispersed both outdoors and indoors at all three studied areas. In Gothenburg all POPs tended to be higher indoors than outdoors, while indoor and outdoor levels in Mexico City were similar. This could be due to the influence of indoor and outdoor sources, air exchange rates, and lifestyle factors. The study demonstrates how passive samplers can provide quick and cheap reconnaissance data simultaneously at many locations which can shed light on sources and other factors influencing POP levels in air, especially for the gaseous fractions.

  11. Strength of smoke-free air laws and indoor air quality

    PubMed Central

    Hahn, Ellen J.; Robertson, Heather E.; Vogel, Suzann L.; Travers, Mark J.

    2009-01-01

    Introduction: Smoke-free air laws have been implemented in many Kentucky communities to protect the public from the harmful effects of secondhand smoke exposure. The impact of different strengths of smoke-free air laws on indoor air quality was assessed. Methods: Indoor air quality in hospitality venues was assessed in seven communities before and after comprehensive smoke-free air laws and in two communities only after partial smoke-free air laws. One community was measured three times: before any smoke-free air law, after the initial partial law, and after the law was strengthened to cover all workplaces and public places with few exemptions. Real-time measurements of particulate matters with 2.5 μm aerodynamic diameter or smaller (PM2.5) were obtained. Results: When comprehensive smoke-free air laws were implemented, indoor PM2.5 concentrations decreased significantly from 161 to 20 μg/m3. In one community that implemented a comprehensive smoke-free law after initially passing a partial law, indoor PM2.5 concentrations were 304 μg/m3 before the law, 338 μg/m3 after the partial law, and 9 μg/m3 after the comprehensive law. Discussion: The study clearly demonstrated that partial smoke-free air laws do not improve indoor air quality. A significant linear trend indicated that PM2.5 levels in the establishments decreased with fewer numbers of burning cigarettes. Only comprehensive smoke-free air laws are effective in reducing indoor air pollution from secondhand tobacco smoke. PMID:19346510

  12. Stratospheric gravity waves at southern hemisphere orographic hotspots: 2003-2014 AIRS/Aqua observations

    NASA Astrophysics Data System (ADS)

    Hoffmann, Lars; Grimsdell, Alison W.; Alexander, M. Joan

    2017-04-01

    interesting case studies in the vast amount of AIRS data, which could then be further explored to study the specific characteristics of stratospheric gravity waves from orographic sources and to support model validation. Reference: Hoffmann, L., Grimsdell, A. W., and Alexander, M. J.: Stratospheric gravity waves at Southern Hemisphere orographic hotspots: 2003-2014 AIRS/Aqua observations, Atmos. Chem. Phys., 16, 9381-9397, doi:10.5194/acp-16-9381-2016, 2016.

  13. Application of High Resolution Air-Borne Remote Sensing Observations for Monitoring NOx Emissions

    NASA Astrophysics Data System (ADS)

    Souri, A.; Choi, Y.; Pan, S.; Curci, G.; Janz, S. J.; Kowalewski, M. G.; Liu, J.; Herman, J. R.; Weinheimer, A. J.

    2017-12-01

    Nitrogen oxides (NOx=NO+NO2) are one of the air pollutants, responsible for the formation of tropospheric ozone, acid rain and particulate nitrate. The anthropogenic NOx emissions are commonly estimated based on bottom-up inventories which are complicated by many potential sources of error. One way to improve the emission inventories is to use relevant observations to constrain them. Fortunately, Nitrogen dioxide (NO2) is one of the most successful detected species from remote sensing. Although many studies have shown the capability of using space-borne remote sensing observations for monitoring emissions, the insufficient sample number and footprint of current measurements have introduced a burden to constrain emissions at fine scales. Promisingly, there are several air-borne sensors collected for NASA's campaigns providing high spatial resolution of NO2 columns. Here, we use the well-characterized NO2 columns from the Airborne Compact Atmospheric Mapper (ACAM) onboard NASA's B200 aircraft into a 1×1 km regional model to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. Firstly, in order to incorporate the data, we convert the NO2 slant column densities to vertical ones using a joint of a radiative transfer model and the 1x1 km regional model constrained by P3-B aircraft measurements. After conducting an inverse modeling method using the Kalman filter, we find the ACAM observations are resourceful at mitigating the overprediction of model in reproducing NO2 on regular days. Moreover, the ACAM provides a unique opportunity to detect an anomaly in emissions leading to strong air quality degradation that is lacking in previous works. Our study provides convincing evidence that future geostationary satellites with high spatial and temporal resolutions will give us insights into uncertainties associated with the emissions at regional scales.

  14. Electron-Beam Produced Air Plasma: Optical Measurement of Beam Current

    NASA Astrophysics Data System (ADS)

    Vidmar, Robert; Stalder, Kenneth; Seeley, Megan

    2006-10-01

    Experiments to quantify the electron beam current and distribution of beam current in air plasma are discussed. The air plasma is produced by a 100-keV 10-mA electron beam source that traverses a transmission window into a chamber with air as a target gas. Air pressure is between 1 mTorr and 760 Torr. Strong optical emissions due to electron impact ionization are observed for the N2 2^nd positive line at 337.1 nm and the N2^+ 1^st negative line at 391.4 nm. Calibration of optical emissions using signals from the isolated transmission window and a Faraday plate are discussed. The calibrated optical system is then used to quantify the electron distribution in the air plasma.

  15. Carbonaceous aerosols in the air masses transported from Indochina to Taiwan: Long-term observation at Mt. Lulin

    NASA Astrophysics Data System (ADS)

    Chuang, Ming-Tung; Lee, Chung-Te; Chou, Charles C.-K.; Lin, Neng-Huei; Sheu, Guey-Rong; Wang, Jia-Lin; Chang, Shuenn-Chin; Wang, Sheng-Hsiang; Chi, Kai Hsien; Young, Chea-Yuan; Huang, Hill; Chen, Horng-Wen; Weng, Guo-Hau; Lai, Sin-Yu; Hsu, Shao-Peng; Chang, Yu-Jia; Chang, Jia-Hon; Wu, Xyue-Chang

    2014-06-01

    Eight carbonaceous fractions from aerosols were resolved using the Interagency Monitoring of Protected Visual Environments (IMPROVE) protocol (Chow et al., 1993). The aerosols were collected at the Mountain Lulin Atmospheric Background Station (Mt. Lulin, 2862 m a.s.l.) in Central Taiwan from April 2003 to April 2012. The monthly and yearly levels of organic carbon (OC) and elemental carbon (EC) varied consistently with PM2.5 mass concentrations during biomass burning (BB) period. The highest monthly carbonaceous content was observed in March and the highest yearly carbonaceous concentration was observed in 2007. This finding is consistent with the BB activity in Indochina and indicates that carbonaceous content is a major component of BB aerosols. Lee et al. (2011) classified four trajectory groups from the air masses transported to Mt. Lulin during the aerosol collection period. For the air masses transported from the BB area (the BB group) in Indochina, the carbonaceous content was greater than the water-soluble ions in PM2.5, and the OC/EC ratio (4.8 ± 1.5) was high. With EC as the indicator of primary emission sources, the air masses of the BB group were found to contain more primary than secondary OC. The Anthropogenic group (from the local and free troposphere below the 700-hPa pressure level over the Asian continent) probably contained more secondary than primary OC or the sources of OC and EC could be quite diverse. The average char-EC/soot-EC (low-temperature EC/high-temperature EC) ratios were 3.9 ± 3.5, 0.4 ± 0.4, 0.9 ± 0.8, and 0.3 ± 0.4 for the trajectory groups BB, SNBB (from BB source areas during the non-BB period), Anthropogenic, and FT (from the oceanic area and the free troposphere above the 700-hPa pressure level over the Asian continent), respectively. The presence of a high char-EC/soot-EC ratio confirmed the correct classification of the BB group, whereas the low ratios from the other groups indicated the strong influence of vehicle

  16. Studies of Muons in Extensive Air Showers from Ultra-High Energy Cosmic Rays Observed with the Telescope Array Surface Detector

    NASA Astrophysics Data System (ADS)

    Takeishi, R.; Sagawa, H.; Fukushima, M.; Takeda, M.; Nonaka, T.; Kawata, K.; Kido, E.; Sakurai, N.; Okuda, T.; Ogio, S.; Matthews, J. N.; Stokes, B.

    The number of muons in the air shower induced by ultra-high energy cosmic rays (UHECRs) has been measured with surface detector (SD) arrays of various experiments. Monte Carlo (MC) prediction of the number of muons in air showers depends on hadronic interaction models and the primary cosmic ray composition. By comparing the measured number of muons with the MC prediction, hadronic interaction models can be tested. The Pierre Auger Observatory reported that the number of muons measured by water Cherenkov type SD is about 1.8 times larger than the MC prediction for proton with QGSJET II-03 model. The number of muons in the Auger data is also larger than the MC prediction for iron. The Telescope Array experiment adopts plastic scintillator type SD, which is sensitive to the electromagnetic component that is the major part of secondary particles in the air shower. To search for the high muon purity condition in air showers observed by the TA, we divided air shower events into subsets by the zenith angle θ, the azimuth angle ϕ relative to the shower arrival direction projected onto the ground, and the distance R from shower axis. As a result, we found subsets with the high muon purity 65%, and compared the charge density between observed data and MC. The typical ratios of the charge density of the data to that of the MC are 1.71 ± 0.10 at 1870 m < R < 2150 m and 3.24 ± 0.40 at 2850 m < R < 3280 m. The difference in the charge density between the data and the MC is larger at the higher muon purity. These results imply that the excess of the charge density in the data is partly explained by the muon excess.

  17. Strength of smoke-free air laws and indoor air quality.

    PubMed

    Lee, Kiyoung; Hahn, Ellen J; Robertson, Heather E; Lee, Seongjik; Vogel, Suzann L; Travers, Mark J

    2009-04-01

    Smoke-free air laws have been implemented in many Kentucky communities to protect the public from the harmful effects of secondhand smoke exposure. The impact of different strengths of smoke-free air laws on indoor air quality was assessed. Indoor air quality in hospitality venues was assessed in seven communities before and after comprehensive smoke-free air laws and in two communities only after partial smoke-free air laws. One community was measured three times: before any smoke-free air law, after the initial partial law, and after the law was strengthened to cover all workplaces and public places with few exemptions. Real-time measurements of particulate matters with 2.5 mum aerodynamic diameter or smaller (PM(2.5)) were obtained. When comprehensive smoke-free air laws were implemented, indoor PM(2.5) concentrations decreased significantly from 161 to 20 microg/m3. In one community that implemented a comprehensive smoke-free law after initially passing a partial law, indoor PM(2.5) concentrations were 304 microg/m3 before the law, 338 microg/m3 after the partial law, and 9 microg/m3 after the comprehensive law. The study clearly demonstrated that partial smoke-free air laws do not improve indoor air quality. A significant linear trend indicated that PM(2.5) levels in the establishments decreased with fewer numbers of burning cigarettes. Only comprehensive smoke-free air laws are effective in reducing indoor air pollution from secondhand tobacco smoke.

  18. DISCOVER-AQ: An Overview and Initial Comparisons of NO2 with OMI Observations

    NASA Technical Reports Server (NTRS)

    Pickering, Kenneth; Crawford, James; Krotkov, Nickolay; Bucsela, Eric; Lamsal, Lok; Celarier, Edward; Herman, Jay; Janz, Scott; Cohen, Ron; Weinheimer, Andrew

    2011-01-01

    The first deployment of the Earth Venture -1 DISCOVER-AQ (Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality) project was conducted during July 2011 in the Baltimore-Washington region. Two aircraft (a P-3B for in-situ sampling and a King Air for remote sensing) were used along with an extensive array of surface-based in-situ and remote sensing instrumentation. Fourteen flight days were accomplished by both aircraft and over 250 profiles of trace gases and aerosols were performed by the P-3B over surface air quality monitoring stations, which were specially outfitted with sunphotometers and Pandora UV/Vis spectrometers. The King Air flew with the High Spectral Resolution Lidar for aerosols and the ACAM UV/Vis spectrometer for trace gases. This suite of observations allows linkage of surface air quality with the vertical distributions of gases and aerosols, with remotely-sensed column amounts observed from the surface and from the King Air, and with satellite observations from Aura (OMI and TES), GOME-2, MODIS and GOES. The DISCOVER-AQ data will allow determination of under what conditions satellite retrievals are indicative of surface air quality, and they will be useful in planning new satellites. In addition to an overview of the project, a preliminary comparison of tropospheric column NO2 densities from the integration of in-situ P-3B observations, from the Pandoras and ACAM, and from the new Goddard OMI NO2 algorithm will be presented.

  19. Surface Ocean pCO2 Seasonality and Sea-Air CO2 Flux Estimates for the North American East Coast

    NASA Technical Reports Server (NTRS)

    Signorini, Sergio; Mannino, Antonio; Najjar, Raymond G., Jr.; Friedrichs, Marjorie A. M.; Cai, Wei-Jun; Salisbury, Joe; Wang, Zhaohui Aleck; Thomas, Helmuth; Shadwick, Elizabeth

    2013-01-01

    Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between 3.4 and 5.4 Tg C/yr (areal average of 0.7 to 1.0 mol CO2 /sq m/yr) over the period 2003-2010.

  20. Assessment and application of AirMSPI high-resolution multiangle imaging photo-polarimetric observations for atmospheric correction

    NASA Astrophysics Data System (ADS)

    Kalashnikova, O. V.; Xu, F.; Garay, M. J.; Seidel, F. C.; Diner, D. J.

    2016-02-01

    Water-leaving radiance comprises less than 10% of the signal measured from space, making correction for absorption and scattering by the intervening atmosphere imperative. Modern improvements have been developed in ocean color retrieval algorithms to handle absorbing aerosols such as urban particulates in coastal areas and transported desert dust over the open ocean. In addition, imperfect knowledge of the absorbing aerosol optical properties or their height distribution results in well-documented sources of error in the retrieved water leaving radiance. Multi-angle spectro-polarimetric measurements have been advocated as an additional tool to better understand and retrieve the aerosol properties needed for atmospheric correction for ocean color retrievals. The Airborne Multiangle SpectroPolarimetric Imager-1 (AirMSPI-1) has been flying aboard the NASA ER-2 high altitude aircraft since October 2010. AirMSPI typically acquires observations of a target area at 9 view angles between ±67° at 10 m resolution. AirMSPI spectral channels are centered at 355, 380, 445, 470, 555, 660, and 865 nm, with 470, 660, and 865 reporting linear polarization. We have developed a retrieval code that employs a coupled Markov Chain (MC) and adding/doubling radiative transfer method for joint retrieval of aerosol properties and water leaving radiance from AirMSPI polarimetric observations. We tested prototype retrievals by comparing the retrieved aerosol concentration, size distribution, water-leaving radiance, and chlorophyll concentrations to values reported by the USC SeaPRISM AERONET-OC site off the coast of California. The retrieval then was applied to a variety of costal regions in California to evaluate variability in the water-leaving radiance under different atmospheric conditions. We will present results, and will discuss algorithm sensitivity and potential applications for future space-borne coastal monitoring.

  1. Determinants of perceived air pollution annoyance and association between annoyance scores and air pollution (PM 2.5, NO 2) concentrations in the European EXPOLIS study

    NASA Astrophysics Data System (ADS)

    Rotko, Tuulia; Oglesby, Lucy; Künzli, Nino; Carrer, Paolo; Nieuwenhuijsen, Mark J.; Jantunen, Matti

    Apart from its traditionally considered objective impacts on health, air pollution can also have perceived effects, such as annoyance. The psychological effects of air pollution may often be more important to well-being than the biophysical effects. Health effects of perceived annoyance from air pollution are so far unknown. More knowledge of air pollution annoyance levels, determinants and also associations with different air pollution components is needed. In the European air pollution exposure study, EXPOLIS, the air pollution annoyance as perceived at home, workplace and in traffic were surveyed among other study objectives. Overall 1736 randomly drawn 25-55-yr-old subjects participated in six cities (Athens, Basel, Milan, Oxford, Prague and Helsinki). Levels and predictors of individual perceived annoyances from air pollution were assessed. Instead of the usual air pollution concentrations at fixed monitoring sites, this paper compares the measured microenvironment concentrations and personal exposures of PM 2.5 and NO 2 to the perceived annoyance levels. A considerable proportion of the adults surveyed was annoyed by air pollution. Female gender, self-reported respiratory symptoms, downtown living and self-reported sensitivity to air pollution were directly associated with high air pollution annoyance score while in traffic, but smoking status, age or education level were not significantly associated. Population level annoyance averages correlated with the city average exposure levels of PM 2.5 and NO 2. A high correlation was observed between the personal 48-h PM 2.5 exposure and perceived annoyance at home as well as between the mean annoyance at work and both the average work indoor PM 2.5 and the personal work time PM 2.5 exposure. With the other significant determinants (gender, city code, home location) and home outdoor levels the model explained 14% (PM 2.5) and 19% (NO 2) of the variation in perceived air pollution annoyance in traffic. Compared to

  2. Eight Year Climatologies from Observational (AIRS) and Model (MERRA) Data

    NASA Technical Reports Server (NTRS)

    Hearty, Thomas; Savtchenko, Andrey; Won, Young-In; Theobalk, Mike; Vollmer, Bruce; Manning, Evan; Smith, Peter; Ostrenga, Dana; Leptoukh, Greg

    2010-01-01

    We examine climatologies derived from eight years of temperature, water vapor, cloud, and trace gas observations made by the Atmospheric Infrared Sounder (AIRS) instrument flying on the Aqua satellite and compare them to similar climatologies constructed with data from a global assimilation model, the Modern Era Retrospective-Analysis for Research and Applications (MERRA). We use the AIRS climatologies to examine anomalies and trends in the AIRS data record. Since sampling can be an issue for infrared satellites in low earth orbit, we also use the MERRA data to examine the AIRS sampling biases. By sampling the MERRA data at the AIRS space-time locations both with and without the AIRS quality control we estimate the sampling bias of the AIRS climatology and the atmospheric conditions where AIRS has a lower sampling rate. While the AIRS temperature and water vapor sampling biases are small at low latitudes, they can be more than a few degrees in temperature or 10 percent in water vapor at higher latitudes. The largest sampling biases are over desert. The AIRS and MERRA data are available from the Goddard Earth Sciences Data and Information Services Center (GES DISC). The AIRS climatologies we used are available for analysis with the GIOVANNI data exploration tool. (see, http://disc.gsfc.nasa.gov).

  3. Rapid establishment of the CO2 sink associated with Kerguelen's bloom observed during the KEOPS2/OISO20 cruise

    NASA Astrophysics Data System (ADS)

    Lo Monaco, C.; Metzl, N.; D'Ovidio, F.; Llort, J.; Ridame, C.

    2014-12-01

    Iron and light are the main factors limiting the biological pump of CO2 in the Southern Ocean. Iron fertilization experiments have demonstrated the potential for increased uptake of atmospheric CO2, but little is known about the evolution of fertilized environnements. This paper presents observations collected in one of the largest phytoplankton bloom of the Southern Ocean sustained by iron originating from the Kerguelen Plateau. We first complement previous studies by investigating the mechanisms that control air-sea CO2 fluxes over and downstream of the Kerguelen Plateau at the onset of the bloom based on measurements obtained in October-November 2011. These new observations show the rapid establishment of a strong CO2 sink in waters fertilized with iron as soon as vertical mixing is reduced. The magnitude of the CO2 sink was closely related to chlorophyll a and iron concentrations. Because iron concentration strongly depends on the distance from the iron source and the mode of delivery, we identified lateral advection as the main mechanism controlling air-sea CO2 fluxes downtream the Kerguelen Plateau during the growing season. In the southern part of the bloom, situated over the Plateau (iron source), the CO2 sink was stronger and spatially more homogeneous than in the plume offshore. However, we also witnessed a substantial reduction in the uptake of atmospheric CO2 over the Plateau following a strong winds event. Next, we used all the data available in this region in order to draw the seasonal evolution of air-sea CO2 fluxes. The CO2 sink is rapidly reduced during the course of the growing season, which we attribute to iron and silicic acid depletion. South of the Polar Front, where nutrients depletion is delayed, we suggest that the amplitude and duration of the CO2 sink is mainly controlled by vertical mixing. The impact of iron fertilization on air-sea CO2 fluxes is revealed by comparing the uptake of CO2 integrated over the productive season in the bloom

  4. Mapping urban air quality in near real-time using observations from low-cost sensors and model information.

    PubMed

    Schneider, Philipp; Castell, Nuria; Vogt, Matthias; Dauge, Franck R; Lahoz, William A; Bartonova, Alena

    2017-09-01

    The recent emergence of low-cost microsensors measuring various air pollutants has significant potential for carrying out high-resolution mapping of air quality in the urban environment. However, the data obtained by such sensors are generally less reliable than that from standard equipment and they are subject to significant data gaps in both space and time. In order to overcome this issue, we present here a data fusion method based on geostatistics that allows for merging observations of air quality from a network of low-cost sensors with spatial information from an urban-scale air quality model. The performance of the methodology is evaluated for nitrogen dioxide in Oslo, Norway, using both simulated datasets and real-world measurements from a low-cost sensor network for January 2016. The results indicate that the method is capable of producing realistic hourly concentration fields of urban nitrogen dioxide that inherit the spatial patterns from the model and adjust the prior values using the information from the sensor network. The accuracy of the data fusion method is dependent on various factors including the total number of observations, their spatial distribution, their uncertainty (both in terms of systematic biases and random errors), as well as the ability of the model to provide realistic spatial patterns of urban air pollution. A validation against official data from air quality monitoring stations equipped with reference instrumentation indicates that the data fusion method is capable of reproducing city-wide averaged official values with an R 2 of 0.89 and a root mean squared error of 14.3 μg m -3 . It is further capable of reproducing the typical daily cycles of nitrogen dioxide. Overall, the results indicate that the method provides a robust way of extracting useful information from uncertain sensor data using only a time-invariant model dataset and the knowledge contained within an entire sensor network. Copyright © 2017 The Authors. Published

  5. Effects of sea-ice and biogeochemical processes and storms on under-ice water fCO2 during the winter-spring transition in the high Arctic Ocean: Implications for sea-air CO2 fluxes

    NASA Astrophysics Data System (ADS)

    Fransson, Agneta; Chierici, Melissa; Skjelvan, Ingunn; Olsen, Are; Assmy, Philipp; Peterson, Algot K.; Spreen, Gunnar; Ward, Brian

    2017-07-01

    We performed measurements of carbon dioxide fugacity (fCO2) in the surface water under Arctic sea ice from January to June 2015 during the Norwegian young sea ICE (N-ICE2015) expedition. Over this period, the ship drifted with four different ice floes and covered the deep Nansen Basin, the slopes north of Svalbard, and the Yermak Plateau. This unique winter-to-spring data set includes the first winter-time under-ice water fCO2 observations in this region. The observed under-ice fCO2 ranged between 315 µatm in winter and 153 µatm in spring, hence was undersaturated relative to the atmospheric fCO2. Although the sea ice partly prevented direct CO2 exchange between ocean and atmosphere, frequently occurring leads and breakup of the ice sheet promoted sea-air CO2 fluxes. The CO2 sink varied between 0.3 and 86 mmol C m-2 d-1, depending strongly on the open-water fractions (OW) and storm events. The maximum sea-air CO2 fluxes occurred during storm events in February and June. In winter, the main drivers of the change in under-ice water fCO2 were dissolution of CaCO3 (ikaite) and vertical mixing. In June, in addition to these processes, primary production and sea-air CO2 fluxes were important. The cumulative loss due to CaCO3 dissolution of 0.7 mol C m-2 in the upper 10 m played a major role in sustaining the undersaturation of fCO2 during the entire study. The relative effects of the total fCO2 change due to CaCO3 dissolution was 38%, primary production 26%, vertical mixing 16%, sea-air CO2 fluxes 16%, and temperature and salinity insignificant.

  6. AirNow Information Management System - Global Earth Observation System of Systems Data Processor for Real-Time Air Quality Data Products

    NASA Astrophysics Data System (ADS)

    Haderman, M.; Dye, T. S.; White, J. E.; Dickerson, P.; Pasch, A. N.; Miller, D. S.; Chan, A. C.

    2012-12-01

    (ASDP) was recently developed to merge PM2.5 estimates from National Aeronautics and Space Administration (NASA) satellite data and AirNow observational data, creating more precise maps and gridded data products for under-monitored areas. The ASDP can easily incorporate other data feeds, including fire and smoke locations, to build enhanced real-time air quality data products. In this presentation, we provide an overview of the features and functions of IMS, an explanation of how data moves through IMS, the rationale of the system architecture, and highlights of the ASDP as an example of the modularity and scalability of IMS.

  7. Tailoring Mechanically Robust Poly(m-phenylene isophthalamide) Nanofiber/nets for Ultrathin High-Efficiency Air Filter

    NASA Astrophysics Data System (ADS)

    Zhang, Shichao; Liu, Hui; Yin, Xia; Li, Zhaoling; Yu, Jianyong; Ding, Bin

    2017-01-01

    Effective promotion of air filtration applications proposed for fibers requires their real nanoscale diameter, optimized pore structure, and high service strength; however, creating such filter medium has proved to be a tremendous challenge. This study first establishes a strategy to design and fabricate novel poly(m-phenylene isophthalamide) nanofiber/nets (PMIA NF/N) air filter via electrospinning/netting. Our strategy results in generation of a bimodal structure including a scaffold of nanofibers and abundant two-dimensional ultrathin (~20 nm) nanonets to synchronously construct PMIA filters by combining solution optimization, humidity regulation, and additive inspiration. Benefiting from the structural features including the true nanoscale diameter, small pore size, high porosity, and nets bonding contributed by the widely distributed nanonets, our PMIA NF/N filter exhibits the integrated properties of superlight weight (0.365 g m-2), ultrathin thickness (~0.5 μm), and high tensile strength (72.8 MPa) for effective air filtration, achieving the ultra-low penetration air filter level of 99.999% and low pressure drop of 92 Pa for 300-500 nm particles by sieving mechanism. The successful synthesis of PMIA NF/N would not only provide a promising medium for particle filtration, but also develop a versatile platform for exploring the application of nanonets in structural enhancement, separation and purification.

  8. NASA Earth Observation Systems and Applications for Health and Air Quality

    NASA Technical Reports Server (NTRS)

    Omar, Ali H.

    2015-01-01

    There is a growing body of evidence that the environment can affect human health in ways that are both complex and global in scope. To address some of these complexities, NASA maintains a diverse constellation of Earth observing research satellites, and sponsors research in developing satellite data applications across a wide spectrum of areas. These include environmental health; infectious disease; air quality standards, policies, and regulations; and the impact of climate change on health and air quality in a number of interrelated efforts. The Health and Air Quality Applications fosters the use of observations, modeling systems, forecast development, application integration, and the research to operations transition process to address environmental health effects. NASA has been a primary partner with Federal operational agencies over the past nine years in these areas. This talk presents the background of the Health and Air Quality Applications program, recent accomplishments, and a plan for the future.

  9. A proposed methodology for impact assessment of air quality traffic-related measures: The case of PM2.5 in Beijing.

    PubMed

    Fontes, Tânia; Li, Peilin; Barros, Nelson; Zhao, Pengjun

    2018-08-01

    Air quality traffic-related measures have been implemented worldwide to control the pollution levels of urban areas. Although some of those measures are claiming environmental improvements, few studies have checked their real impact. In fact, quantitative estimates are often focused on reducing emissions, rather than on evaluating the actual measures' effect on air quality. Even when air quality studies are conducted, results are frequently unclear. In order to properly assess the real impact on air quality of traffic-related measures, a statistical method is proposed. The method compares the pollutant concentration levels observed after the implementation of a measure with the concentration values of the previous year. Short- and long-term impact is assessed considering not only their influence on the average pollutant concentration, but also on its maximum level. To control the effect of the main confounding factors, only the days with similar environmental conditions are analysed. The changeability of the key meteorological variables that affect the transport and dispersion of the pollutant studied are used to identify and group the days categorized as similar. Resemblance of the pollutants' concentration of the previous day is also taken into account. The impact of the road traffic measures on the air pollutants' concentration is then checked for those similar days using specific statistical functions. To evaluate the proposed method, the impact on PM 2.5 concentrations of two air quality traffic-related measures (M1 and M2) implemented in the city of Beijing are taken into consideration: M1 was implemented in 2009, restricting the circulation of yellow-labelled vehicles, while M2 was implemented in 2014, restricting the circulation of heavy-duty vehicles. To compare the results of each measure, a time-period when these measures were not applied is used as case-control. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. Observation of the water cycle from space with the Atmospheric Infrared Sounder (AIRS)

    NASA Astrophysics Data System (ADS)

    Chahine, M. T.; Waliser, D. E.; Fetzer, E. J.; Olsen, E. T.

    2007-12-01

    AIRS is one of six instruments on board the Aqua satellite, part of NASA's Earth Observing System launched in a sun synchronous near polar orbit on May 4, 2002. AIRS and its partner microwave instrument, AMSU A, provide high quality data facilitating studies of the global water and energy cycles, climate variation and trends, and the response of the climate system to increased greenhouse gases. The exceptional stability of the AIRS instrument provides a climate record of thermal infrared radiance spectra spanning the 3.74 15.4 mm spectral band with 2378 channels at a nominal resolution of 1/1200. (Chahine et al, in BAMS, July 2006) Accurate knowledge of the vertical distribution of water vapor in the atmosphere is critically important to the determination of the warming the Earth will experience as a result of anthropogenic forcing. Comparison of the AIRS specific humidity product to state of the art climate models has shown most models exhibit a pattern of drier than observed (by 10 25%) in the tropics below 800 hPa and moister than observed (by 25 100%) between 300 and 600 hPa in the extra tropics (Pierce et al, GRL 2006). The AIRS water vapor measurements also reveal tropospheric moisture perturbations that are much larger than those depicted in previous NCAR/NCEP reanalysis and ECMWF analysis datasets, both of which have been widely used as observations to validate models. This suggests that the impact of convection induced downdrafts on the atmospheric boundary layer is significantly underestimated in both ECMWF and NCEP reanalysis (Fu et al., GRL 2006). AIRS data have led to the discovery of significant differences in the lower troposphere moisture and temperature fields during the spatial temporal evolution of the Madden Julian Oscillation (MJO). The anomalous lower troposphere temperature structure is observed in detail by AIRS for the Indian and western Pacific Oceans, while it remains much less well defined in the NCEP temperature fields (Tian et al

  11. Pediatric Conjunctivitis and Air Pollution Exposure: A Prospective Observational Study.

    PubMed

    Nucci, Paolo; Sacchi, Matteo; Pichi, Francesco; Allegri, Pia; Serafino, Massimiliano; Dello Strologo, Marika; De Cillà, Stefano; Villani, Edoardo

    2017-01-01

    To investigate, in pediatric patients, the rate and clinical features of unspecific conjunctivitis of unknown origin (UCUO) and to evaluate their relationship with air pollution. From January to December 2013, we consecutively screened all of the patients referred for symptomatic ocular surface inflammation. Inclusion criteria for this study were age<14, diagnosis of conjunctivitis, residence in the Lombardia region. UCUO was defined as conjunctivitis of unknown etiology, not clearly due to infection or allergy. Based on addresses of residence and sites of 73 automatic air pollution monitoring stations (locations and mean annual particulate matter (PM) 10 and 2.5 concentrations were provided by the Regional Environmental Protection Agency (ARPA) Lombardia), each patient was paired with a value of exposure to PM. Relationship between UCUO and PM exposure was investigated. A total of 132 of 251 screened children were included in this study. UCUO was diagnosed in 48/132 patients. The most common symptoms and signs in UCUO children were foreign body sensation (37/48) and conjunctival hyperemia (45/48), respectively. PM10 exposure value was significantly higher in UCUO (33.5±5.4µg/m3) compared to other groups (P<0.001, ANOVA). UCUO/total conjunctivitis ratio was significantly higher in residents in areas with more than 75 (Q3) days/year exceeding 50µg/m3 (EU legal limit) compared to areas with less than 45 (Q1) exceedances/year: 24/39: 61% vs 8/35: 23%; P>0.001, Chi-square test. Our data suggest a relationship between UCUO and air pollution. This form of conjunctivitis is not rare in pediatric patients and may be the most frequent in most polluted areas.

  12. Hurricane Alex as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    2004-01-01

    Carolina, traveling northeast at 6 mph.

    [figure removed for brevity, see original site] August 1, 2004, 1:30am ET Daylight snapshot from AIRS visible/near-infrared. At the time AIRS made this observation, Alex was still a tropical depression and just getting organized.

    Movies Slice down the atmosphere with the AIRS infrared sensor.

    [figure removed for brevity, see original site] August 3, 2004, 1:30am ET Alex becomes the first hurricane of the 2004 North Atlantic season with sustained winds at 75 mph.

    [figure removed for brevity, see original site] August 2, 2004, 1:30pm ET Alex is located about 120 miles southeast of Charleston, South Carolina. Alex has now begun to move to the northeast and a general northeastward track is expected the next couple of days with a gradual acceleration in forward speed as it begins to interact with stronger upper level winds.

    [figure removed for brevity, see original site] August 2, 2004, 1:30am ET Alex now has sustained winds of 35 knots.

    [figure removed for brevity, see original site] August 1, 2004, 1:30pm ET Alex is tropical depression and beginning to get organized.

    The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft and is managed by NASA's Jet Propulsion Laboratory, Pasadena, Calif., under contract to NASA. JPL is a division of the California Institute of Technology in Pasadena.

  13. Uncertainty in air quality observations using low-cost sensors

    NASA Astrophysics Data System (ADS)

    Castell, Nuria; Dauge, Franck R.; Dongol, Rozina; Vogt, Matthias; Schneider, Philipp

    2016-04-01

    Air pollution poses a threat to human health, and the WHO has classified air pollution as the world's largest single environmental health risk. In Europe, the majority of the population lives in areas where air quality levels frequently exceed WHO's ambient air quality guidelines. The emergence of low-cost, user-friendly and very compact air pollution platforms allowing observations at high spatial resolution in near real-time, provides us with new opportunities to simultaneously enhance existing monitoring systems as well as enable citizens to engage in more active environmental monitoring (citizen science). However the data sets generated by low-cost sensors show often questionable data quality. For many sensors, neither their error characteristics nor how their measurement capability holds up over time or through a range of environmental conditions, have been evaluated. We have conducted an exhaustive evaluation of the commercial low-cost platform AQMesh (measuring NO, NO2, CO, O3, PM10 and PM2.5) in laboratory and in real-world conditions in the city of Oslo (Norway). Co-locations in field of 24 platforms were conducted over a 6 month period (April to September 2015) allowing to characterize the temporal variability in the performance. Additionally, the field performance included the characterization on different monitoring urban monitoring sites characteristic of both traffic and background conditions. All the evaluations have been conducted against CEN reference method analyzers maintained according to the Norwegian National Reference Laboratory quality system. The results show clearly that a good performance in laboratory does not imply similar performance in real-world outdoor conditions. Moreover, laboratory calibration is not suitable for subsequent measurements in urban environments. In order to reduce the errors, sensors require on-site field calibration. Even after such field calibration, the platforms show a significant variability in the performance

  14. Temporal variability of air-sea CO2 exchange in a low-emission estuary

    NASA Astrophysics Data System (ADS)

    Mørk, Eva Thorborg; Sejr, Mikael Kristian; Stæhr, Peter Anton; Sørensen, Lise Lotte

    2016-07-01

    There is the need for further study of whether global estimates of air-sea CO2 exchange in estuarine systems capture the relevant temporal variability and, as such, the temporal variability of bulk parameterized and directly measured CO2 fluxes was investigated in the Danish estuary, Roskilde Fjord. The air-sea CO2 fluxes showed large temporal variability across seasons and between days and that more than 30% of the net CO2 emission in 2013 was a result of two large fall and winter storms. The diurnal variability of ΔpCO2 was up to 400 during summer changing the estuary from a source to a sink of CO2 within the day. Across seasons the system was suggested to change from a sink of atmospheric CO2 during spring to near neutral during summer and later to a source of atmospheric CO2 during fall. Results indicated that Roskilde Fjord was an annual low-emission estuary, with an estimated bulk parameterized release of 3.9 ± 8.7 mol CO2 m-2 y-1 during 2012-2013. It was suggested that the production-respiration balance leading to the low annual emission in Roskilde Fjord, was caused by the shallow depth, long residence time and high water quality in the estuary. In the data analysis the eddy covariance CO2 flux samples were filtered according to the H2Osbnd CO2 cross-sensitivity assessment suggested by Landwehr et al. (2014). This filtering reduced episodes of contradicting directions between measured and bulk parameterized air-sea CO2 exchanges and changed the net air-sea CO2 exchange from an uptake to a release. The CO2 gas transfer velocity was calculated from directly measured CO2 fluxes and ΔpCO2 and agreed to previous observations and parameterizations.

  15. Cardiorespiratory responses of air filtration: A randomized crossover intervention trial in seniors living in Beijing: Beijing Indoor Air Purifier StudY, BIAPSY.

    PubMed

    Shao, Danqing; Du, Yipeng; Liu, Shuo; Brunekreef, Bert; Meliefste, Kees; Zhao, Qian; Chen, Jie; Song, Xiaoming; Wang, Meng; Wang, Juan; Xu, Hongbing; Wu, Rongshan; Wang, Tong; Feng, Baihuan; Lung, Candice Shih-Chun; Wang, Xian; He, Bei; Huang, Wei

    2017-12-15

    In this Beijing Indoor Air Purifier StudY (BIAPSY), we conducted a randomized crossover intervention trial in a panel of 35 non-smoking senior participants with free-living, with and without chronic obstructive pulmonary disease (COPD). Portable air filtration units were randomly allocated to active-(filter in) for 2weeks and sham-mode (filter out) for 2weeks in the households. We examined the differences in indoor air pollutant concentrations in 20 study homes and a suite of cardio-respiratory biomarker levels in study participants between filtration modes, with and without adjustment for potential confounders. Following active filtration, we observed significant reductions from 60±45 to 24±15μg/m 3 in ten-day averages of indoor PM 2.5 and reductions from 3.87±1.65 to 1.81±1.19m -1 .10 -5 in ten-day averages of indoor BC, compared to sham-mode filtration. The major components of indoor PM 2.5 , including water soluble organics, NO 3 - , SO 4 2- , Zn 2+ , Pb 2+ and K + , were also reduced significantly by 42% to 63%. However, following active filtration, we only observed significant reductions on systemic inflammation measured as of IL-8 at 58.59% (95% CI: -76.31, -27.64) in the total group of participants and 70.04% (95% CI: -83.05, -47.05) in the subset of COPD patients, with adjustments. We were not able to detect improvements on lung function, blood pressure, and heart rate variability, following short-term intervention of two-week active air filtration. In conclusion, our results showed that indoor air filtration produced clear improvement on indoor air quality, but no demonstrable changes in the cardio-respiratory outcomes of study interest observed in the seniors living with real-world air pollution exposures. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Observational and research progress of the M51 galaxy

    NASA Astrophysics Data System (ADS)

    Chen, Zhu; Williams, Peter

    2006-12-01

    The M51 system consists of a grand-design spiral galaxy and a relatively large close companion, NGC 5195. Because M51 (=NGC 5194) is nearby and nearly face-on to us, its structure can be observed in great detail and with a minimum of obscuration from dust. As a result, this galaxy has been thoroughly observed at wavelengths from radio to X-ray. Due to the rich archive of observational data, its structure, dynamical process, star formation mechanism and some other important properties have been analyzed by many authors. In the center of M51, there is a Seyfert 2 or LINER type AGN which radius is 100 pc. The mass within 70 pc in the center is (4~7)×106 Msun, this indicates there may be a black hole there. The disk of M51 can be divided into two parts, the inner disk around the nucleus cuts off at 1350 pc, from this radius to 10 kpc is the outer disk. In contrast, the companion, NGC 5195 is small and faint, and heavy dust from the arm of M51 in the foreground obscures its optical radiation. M51 has many interesting properties different from other normal galaxies, such as the wide open spiral arm, the long HI tidal tail and the huge distorted gas ring around the outer disk, these may be related to the interaction effects. Actually, the dynamical modeling history of M51 is long, in the early stage of astronomical numerical simulation, Toomre & Toomre have given a simple simulation of M51 to study its tidal effect. In 1990, the discovery of M51's long HI tidal tail made the astrophysicists shift the preferred collision time of M51 and NGC 5195 to somewhat later times in order to give the tail more time to develop. More recently, Salo and Laurikainen suggested that a multiple-passage model might be more appropriate for the system, such a scenario appears to do a better job of explaining NGC 5194's HI velocity field, but the predicted structure of the HI tidal tail is more complex than its observation. In this paper, the authers review literature of multi

  17. Spectral Longwave Cloud Radiative Forcing as Observed by AIRS

    NASA Technical Reports Server (NTRS)

    Blaisdell, John M.; Susskind, Joel; Lee, Jae N.; Iredell, Lena

    2016-01-01

    AIRS V6 products contain the spectral contributions to Outgoing Longwave Radiation (OLR), clear-sky OLR (OLR(sub CLR)), and Longwave Cloud Radiative Forcing (LWCRF) in 16 bands from 100 cm(exp -1) to 3260 cm(exp -1). We show climatologies of selected spectrally resolved AIRS V6 products over the period of September 2002 through August 2016. Spectrally resolved LWCRF can better describe the response of the Earth system to cloud and cloud feedback processes. The spectral LWCRF enables us to estimate the fraction of each contributing factor to cloud forcing, i.e.: surface temperature, mid to upper tropospheric water vapor, and tropospheric temperature. This presentation also compares the spatial characteristics of LWCRF from AIRS, CERES_EBAF Edition-2.8, and MERRA-2. AIRS and CERES LWCRF products show good agreement. The OLR bias between AIRS and CERES is very close to that of OLR(sub CLR). This implies that both AIRS and CERES OLR products accurately account for the effect of clouds on OLR.

  18. Comparison of the impact of the Tobacco Heating System 2.2 and a cigarette on indoor air quality.

    PubMed

    Mitova, Maya I; Campelos, Pedro B; Goujon-Ginglinger, Catherine G; Maeder, Serge; Mottier, Nicolas; Rouget, Emmanuel G R; Tharin, Manuel; Tricker, Anthony R

    2016-10-01

    The impact of the Tobacco Heating System 2.2 (THS 2.2) on indoor air quality was evaluated in an environmentally controlled room using ventilation conditions recommended for simulating "Office", "Residential" and "Hospitality" environments and was compared with smoking a lit-end cigarette (Marlboro Gold) under identical experimental conditions. The concentrations of eighteen indoor air constituents (respirable suspended particles (RSP) < 2.5 μm in diameter), ultraviolet particulate matter (UVPM), fluorescent particulate matter (FPM), solanesol, 3-ethenylpyridine, nicotine, 1,3-butadiene, acrylonitrile, benzene, isoprene, toluene, acetaldehyde, acrolein, crotonaldehyde, formaldehyde, carbon monoxide, nitrogen oxide, and combined oxides of nitrogen) were measured. In simulations evaluating THS 2.2, the concentrations of most studied analytes did not exceed the background concentrations determined when non-smoking panelists were present in the environmentally controlled room under equivalent conditions. Only acetaldehyde and nicotine concentrations were increased above background concentrations in the "Office" (3.65 and 1.10 μg/m(3)), "Residential" (5.09 and 1.81 μg/m(3)) and "Hospitality" (1.40 and 0.66 μg/m(3)) simulations, respectively. Smoking Marlboro Gold resulted in greater increases in the concentrations of acetaldehyde (58.8, 83.8 and 33.1 μg/m(3)) and nicotine (34.7, 29.1 and 34.6 μg/m(3)) as well as all other measured indoor air constituents in the "Office", "Residential" and "Hospitality" simulations, respectively. Copyright © 2016 The Author(s). Published by Elsevier Inc. All rights reserved.

  19. Early-20th-century visual observations of M13 variable stars

    NASA Astrophysics Data System (ADS)

    Osborn, W.; Barnard, E. E.

    2016-08-01

    In 1900 E. E. Barnard published 37 visual observations of Variable 2 (V2) in the globular clustter M13 made in 1899 and 1900. A review of Barnard's notebooks revealed he made many additional brightness estimates up to 1911, and he had also recorded the variations of V1 starting in 1904. These data provide the earliest-epoch light curves for these stars and thus are useful for studying their period changes. This paper presents Barnard's observations of the M13 variables along with their derived heliocentric Julian Dates and approximate V magnitudes. These include 231 unpublished observations of V2 and 94 of V1. How these data will be of value for determing period changes by these stars is described.

  20. Spectrophotometric Determination of Nitrogen Oxides in the Air with 2-N-Ethyl-5-Naphthol-7-Sulfonic Acid

    NASA Astrophysics Data System (ADS)

    Huang, Y.; Shi, W.; Zhang, C.; Wen, H.

    2017-09-01

    For the determination of nitrogen oxides in the air, the structure of diazo and coupling compounds was studied and tested by experiments. The conditions and methods of diazo and coupling reactions were investigated. Furthermore, a spectrophotometric method using sulfanilamide as a diazo compound and 2-N-ethyl-5-naphthol-7-sulfonic acid (N-ethyl J acid) as a coupling compound was proposed. The maximum absorption wavelength of sulfanilamide-Nethyl J acid azo compound was at 478 nm. The molar absorptivity was 4.31 × 104 L/(mol × cm) with a recovery of 98.7-100.9% and RSD of 1.85%. For nitrogen oxides, the determinate limit of this measurement was 0.015 mg/m3 and the determinate range 0.024-2.0 mg/m3. Moreover, a high degree of correlation was observed between the results obtained by the proposed method and the standard methods. The proposed method can be easily applied to determine nitrogen oxides in the air.

  1. Effects of air velocity on photosynthesis of plant canopies under elevated CO2 levels in a plant culture system.

    PubMed

    Kitaya, Y; Shibuya, T; Yoshida, M; Kiyota, M

    2004-01-01

    To obtain basic data for adequate air circulation for promoting plant growth in closed plant production modules in bioregenerative life support systems in space, effects of air velocities ranging from 0.1 to 0.8 m s-1 on photosynthesis in tomato seedlings canopies were investigated under atmospheric CO2 concentrations of 0.4 and 0.8 mmol mol-1. The canopy of tomato seedlings on a plug tray (0.4 x 0.4 m2) was set in a wind-tunnel-type chamber (0.6 x 0.4 x 0.3 m3) installed in a semi-closed-type assimilation chamber (0.9 x 0.5 x 0.4 m3). The net photosynthetic rate in the plant canopy was determined with the differences in CO2 concentrations between the inlet and outlet of the assimilation chamber multiplied by the volumetric air exchange rate of the chamber. Photosynthetic photon flux (PPF) on the plant canopy was kept at 0.25 mmol m-2 s-1, air temperature at 23 degrees C and relative humidity at 55%. The leaf area indices (LAIs) of the plant canopies were 0.6-2.5 and plant heights were 0.05-0.2 m. The net photosynthetic rate of the plant canopy increased with increasing air velocities inside plant canopies and saturated at 0.2 m s-1. The net photosynthetic rate at the air velocity of 0.4 m s-1 was 1.3 times that at 0.1 m s-1 under CO2 concentrations of 0.4 and 0.8 mmol mol-1. The net photosynthetic rate under CO2 concentrations of 0.8 mmol mol-1 was 1.2 times that under 0.4 mmol mol-1 at the air velocity ranging from 0.1 to 0.8 m s-1. The results confirmed the importance of controlling air movement for enhancing the canopy photosynthesis under an elevated CO2 level as well as under a normal CO2 level in the closed plant production modules. c2004 COSPAR. Published by Elsevier Ltd. All rights reserved.

  2. Interannual Variability of OLR as Observed by AIRS and CERES

    NASA Technical Reports Server (NTRS)

    Susskind, Joel; Molnar, Gyula; Iredell, Lena; Loeb, Norman G.

    2012-01-01

    This paper compares spatial anomaly time series of OLR (Outgoing Longwave Radiation) and OLR(sub CLR) (Clear Sky OLR) as determined using observations from CERES Terra and AIRS over the time period September 2002 through June 2011. Both AIRS and CERES show a significant decrease in global mean and tropical mean OLR over this time period. We find excellent agreement of the anomaly time-series of the two OLR data sets in almost every detail, down to 1 deg X 1 deg spatial grid point level. The extremely close agreement of OLR anomaly time series derived from observations by two different instruments implies that both sets of results must be highly stable. This agreement also validates to some extent the anomaly time series of the AIRS derived products used in the computation of the AIRS OLR product. The paper also examines the correlations of anomaly time series of AIRS and CERES OLR, on different spatial scales, as well as those of other AIRS derived products, with that of the NOAA Sea Surface Temperature (SST) product averaged over the NOAA Nino-4 spatial region. We refer to these SST anomalies as the El Nino Index. Large spatially coherent positive and negative correlations of OLR anomaly time series with that of the El Nino Index are found in different spatial regions. Anomalies of global mean, and especially tropical mean, OLR are highly positively correlated with the El Nino Index. These correlations explain that the recent global and tropical mean decreases in OLR over the period September 2002 through June 2011, as observed by both AIRS and CERES, are primarily the result of a transition from an El Nino condition at the beginning of the data record to La Nina conditions toward the end of the data period. We show that the close correlation of global mean, and especially tropical mean, OLR anomalies with the El Nino Index can be well accounted for by temporal changes of OLR within two spatial regions which lie outside the NOAA Nino-4 region, in which anomalies

  3. M2-F1 simulator cockpit

    NASA Technical Reports Server (NTRS)

    1963-01-01

    This early simulator of the M2-F1 lifting body was used for pilot training, to test landing techniques before the first ground tow attempts, and to test new control configurations after the first tow attempts and wind-tunnel tests. The M2-F1 simulator was limited in some ways by its analog simulator. It had only limited visual display for the pilot, as well. The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and racing slicks, the Pontiac could tow the 1,000-pound M2-F1 110 miles per hour in 30 seconds. It proved adequate for the roughly 400 car tows that got the M2-F1 airborne

  4. Novel Markers to Delineate Murine M1 and M2 Macrophages

    PubMed Central

    Jablonski, Kyle A.; Amici, Stephanie A.; Webb, Lindsay M.; Ruiz-Rosado, Juan de Dios; Popovich, Phillip G.; Partida-Sanchez, Santiago; Guerau-de-Arellano, Mireia

    2015-01-01

    Classically (M1) and alternatively activated (M2) macrophages exhibit distinct phenotypes and functions. It has been difficult to dissect macrophage phenotypes in vivo, where a spectrum of macrophage phenotypes exists, and also in vitro, where low or non-selective M2 marker protein expression is observed. To provide a foundation for the complexity of in vivo macrophage phenotypes, we performed a comprehensive analysis of the transcriptional signature of murine M0, M1 and M2 macrophages and identified genes common or exclusive to either subset. We validated by real-time PCR an M1-exclusive pattern of expression for CD38, G-protein coupled receptor 18 (Gpr18) and Formyl peptide receptor 2 (Fpr2) whereas Early growth response protein 2 (Egr2) and c-Myc were M2-exclusive. We further confirmed these data by flow cytometry and show that M1 and M2 macrophages can be distinguished by their relative expression of CD38 and Egr2. Egr2 labeled more M2 macrophages (~70%) than the canonical M2 macrophage marker Arginase-1, which labels 24% of M2 macrophages. Conversely, CD38 labeled most (71%) in vitro M1 macrophages. In vivo, a similar CD38+ population greatly increased after LPS exposure. Overall, this work defines exclusive and common M1 and M2 signatures and provides novel and improved tools to distinguish M1 and M2 murine macrophages. PMID:26699615

  5. Assessment of filtration efficiency and physiological responses of selected plant species to indoor air pollutants (toluene and 2-ethylhexanol) under chamber conditions.

    PubMed

    Hörmann, Vanessa; Brenske, Klaus-Reinhard; Ulrichs, Christian

    2018-01-01

    Three common plant species (Dieffenbachia maculata, Spathiphyllum wallisii, and Asparagus densiflorus) were tested against their capacity to remove the air pollutants toluene (20.0 mg m -3 ) and 2-ethylhexanol (14.6 mg m -3 ) under light or under dark in chamber experiments of 48-h duration. Results revealed only limited pollutant filtration capabilities and indicate that aerial plant parts of the tested species are only of limited value for indoor air quality improvement. The removal rate constant ranged for toluene from 3.4 to 5.7 L h -1  m -2 leaf area with no significant differences between plant species or light conditions (light/dark). The values for 2-ethylhexanol were somewhat lower, fluctuating around 2 L h -1  m -2 leaf area for all plant species tested, whereas differences between light and dark were observed for two of the three species. In addition to pollutant removal, CO 2 fixation/respiration and transpiration as well as quantum yield were evaluated. These physiological characteristics seem to have no major impact on the VOC removal rate constant. Exposure to toluene or 2-ethylhexanol revealed no or only minor effects on D. maculata and S. wallisii. In contrast, a decrease in quantum yield and CO 2 fixation was observed for A. densiflorus when exposed to 2-ethylhexanol or toluene under light, indicating phytotoxic effects in this species.

  6. Silicon anode for rechargeable aqueous lithium-air batteries

    NASA Astrophysics Data System (ADS)

    Teranishi, R.; Si, Q.; Mizukoshi, F.; Kawakubo, M.; Matsui, M.; Takeda, Y.; Yamamoto, O.; Imanishi, N.

    2015-01-01

    A novel aqueous lithium-air rechargeable cell with the configuration of Si/1 M LiClO4 in ethylene carbonate-diethylene carbonate/Li1+x+yAlx(Ti,Ge)2-xP3-ySiyO12/5 M LiCl-1 M LiOH aqueous solution/carbon black, air is proposed. A silicon anode composed of mechanically milled silicon power with an average particle size of ca. 0.5 μm, vapor grown carbon fiber and a polyimide binder was examined. The open-circuit voltage at the charged state was 2.9 V at 25 °C. The discharge capacity of 700 mAh g-silicon-1 was retained for 40 cycles at 0.3 mA cm-2 with cut-off voltages of 3.5 and 1.5 V. Significant capacity fade was observed at deep charge and discharge cycling at 2000 mAh g-silicon-1.

  7. HIRDLS Observations and Simulation of a Lower Stratospheric Intrusion of Tropical Air to High Latitudes

    NASA Technical Reports Server (NTRS)

    Olsen, Mark A.; Douglass, Anne R.; Newman, Paul A.; Gille, John C.; Nardi, Bruno; Yudin, Valery A.; Kinnison, Douglas E.; Khosravi, Rashid

    2008-01-01

    On 26 January 2006, the High Resolution Dynamic Limb Sounder (HIRDLS) observed low mixing ratios of ozone and nitric acid in an approximately 2 km vertical layer near 100 hPa extending from the subtropics to 55 degrees N over North America. The subsequent evolution of the layer is simulated with the Global Modeling Initiative (GMI) model and substantiated with HIRDLS observations. Air with low mixing ratios of ozone is transported poleward to 80 degrees N. Although there is evidence of mixing with extratropical air and diabatic descent, much of the tropical intrusion returns to the subtropics. This study demonstrates that HIRDLS and the GMI model are capable of resolving thin intrusion events. The observations combined with simulation are a first step towards development of a quantitative understanding of the lower stratospheric ozone budget.

  8. Observational tests for stellar evolution and pulsation theory. I - The globular clusters M 4 and M 15

    NASA Astrophysics Data System (ADS)

    Caputo, F.

    1987-01-01

    It is shown that the pulsational properties of RR Lyrae variables in globular clusters can be used together with the Red Giant Branch location to derive reliable information on the cluster reddening and distance modulus. By demanding full agreement with some key observables, the reddening and distance modulus of the globular clusters M4 and M15 are derived as a function of the mass of the variables and of the adopted cluster metallicity. Thus, from the comparison between observations and theoretical isochrones, the cluster age can be evaluated. A best guess for the age of M4 and M15 can be presented: 16×109yr, with a total uncertainty of 2 billion years.

  9. Estimating Coastal Turbidity using MODIS 250 m Band Observations

    NASA Technical Reports Server (NTRS)

    Davies, James E.; Moeller, Christopher C.; Gunshor, Mathew M.; Menzel, W. Paul; Walker, Nan D.

    2004-01-01

    Terra MODIS 250 m observations are being applied to a Suspended Sediment Concentration (SSC) algorithm that is under development for coastal case 2 waters where reflectance is dominated by sediment entrained in major fluvial outflows. An atmospheric correction based on MODIS observations in the 500 m resolution 1.6 and 2.1 micron bands is used to isolate the remote sensing reflectance in the MODIS 25Om resolution 650 and 865 nanometer bands. SSC estimates from remote sensing reflectance are based on accepted inherent optical properties of sediment types known to be prevalent in the U.S. Gulf of Mexico coastal zone. We present our findings for the Atchafalaya Bay region of the Louisiana Coast, in the form of processed imagery over the annual cycle. We also apply our algorithm to selected sites worldwide with a goal of extending the utility of our approach to the global direct broadcast community.

  10. Diurnal variability of CO2 flux at coastal zone of Taiwan based on eddy covariance observation

    NASA Astrophysics Data System (ADS)

    Chien, Hwa; Zhong, Yao-Zhao; Yang, Kang-Hung; Cheng, Hao-Yuan

    2018-06-01

    In this study, we employed shore-based eddy covariance systems for a continuous measurement of the coastal CO2 flux near the northwestern coast of Taiwan from 2011 to 2015. To ensure the validity of the analysis, the data was selected and filtered with a footprint model and an empirical mode decomposition method. The results indicate that the nearshore air-sea and air-land CO2 fluxes exhibited a significant diurnal variability and a substantial day-night difference. The net air-sea CO2 flux was -1.75 ± 0.98 μmol-C m-2 s-1, whereas the net air-land CO2 flux was 0.54 ± 7.35 μmol-C m-2 s-1, which indicated that in northwestern Taiwan, the coastal water acts as a sink of atmospheric CO2 but the coastal land acts as a source. The Random Forest Method was applied to hierarchize the influence of Chl-a, SST, DO, pH and U10 on air-sea CO2 fluxes. The result suggests that the strength of the diurnal air-sea CO2 flux is strongly influenced by the local wind speed.

  11. Volcanic activity of Io observed in December 2001 with the Keck AO system: 2-5μ m sunlit and eclipse observations

    NASA Astrophysics Data System (ADS)

    Marchis, F.; de Pater, I.; Le Mignant, D.; Roe, H.; Fusco, T.; Graham, J. R.; Prange, R.; Macintosh, B.; Keck Science Team

    2002-09-01

    Volcanically active Io remains a mysterious and intriguing moon, despite numerous spacecraft flybys. Groundbased monitoring programs help characterize the time evolution of Io's volcanic activity, such as the frequency, spatial distribution and temperature of hot spots and outbursts. The satellite was observed intensively in December 2001 with the Keck II Adaptive Optics (AO) system and its recently installed near-infrared camera NIRC2. The spatial resolution after applying the MISTRAL myopic deconvolution method (130 km in K band and 200 km in L band) is better than that of the global images from the Galileo/NIMS instrument. A movie produced from 12 pictures taken every 30o in Ionian longitude provides a complete survey of Io's surface during one full rotation. A total of 26 active hot spots were detected in L band (3.8μ m), and approximatively three times more in M band (4.7μ m). One active hot spot is seen in K band (2.2μ m) in the Pele area. While Io is in Jupiter's shadow, it is invisible to the wavefront sensor, but its hot spots are easily visible in the near-infrared. We imaged Io during the 18 Dec. 2001 eclipse using Ganymede (30" from Io, moving relative to Io at 0.5"/min) as a reference source. Although isoplanatic effects limited AO performance, numerous spots are detected at both K' and L'. We will show the results of detailed studies (temperature, emission area, nature) for several of the hot spots. Keck Science team is composed of S. Kwok, P. Amico, R. Campbell, F. Chaffee, A. Conrad, A. Contos, B. Goodrich, G. Hill, D. Sprayberry, P. Stomski, P. Wizinowich (W.M. Keck Observatory). This work has been supported in part by the National Science Foundation Science and Technology Center for Adaptive Optics, managed by the University of California at Santa Cruz under cooperative agreement No. AST-9876783.

  12. Atmospheric fossil fuel CO2 traced by 14CO2 and air quality index pollutant observations in Beijing and Xiamen, China.

    PubMed

    Niu, Zhenchuan; Zhou, Weijian; Feng, Xue; Feng, Tian; Wu, Shugang; Cheng, Peng; Lu, Xuefeng; Du, Hua; Xiong, Xiaohu; Fu, Yunchong

    2018-06-01

    Radiocarbon ( 14 C) is the most accurate tracer available for quantifying atmospheric CO 2 derived from fossil fuel (CO 2ff ), but it is expensive and time-consuming to measure. Here, we used common hourly Air Quality Index (AQI) pollutants (AQI, PM 2.5 , PM 10 , and CO) to indirectly trace diurnal CO 2ff variations during certain days at the urban sites in Beijing and Xiamen, China, based on linear relationships between AQI pollutants and CO 2ff traced by 14 C ([Formula: see text]) for semimonthly samples obtained in 2014. We validated these indirectly traced CO 2ff (CO 2ff-in ) concentrations against [Formula: see text] concentrations traced by simultaneous diurnal 14 CO 2 observations. Significant (p < 0.05) strong correlations were observed between each of the separate AQI pollutants and [Formula: see text] for the semimonthly samples. Diurnal variations in CO 2ff traced by each of the AQI pollutants generally showed similar trends to those of [Formula: see text], with high agreement at the sampling site in Beijing and relatively poor agreement at the sampling site in Xiamen. AQI pollutant tracers showed high normalized root-mean-square (NRMS) errors for the summer diurnal samples due to low [Formula: see text] concentrations. After the removal of these summer samples, the NRMS errors for AQI pollutant tracers were in the range of 31.6-64.2%. CO generally showed a high agreement and low NRMS errors among these indirect tracers. Based on these linear relationships, monthly CO 2ff averages at the sampling sites in Beijing and Xiamen were traced using CO concentration as a tracer. The monthly CO 2ff averages at the Beijing site showed a shallow U-type variation. These results indicate that CO can be used to trace CO 2ff variations in Chinese cities with CO 2ff concentrations above 5 ppm.

  13. AIRS Obs4MIPs V2 data set

    NASA Astrophysics Data System (ADS)

    Tian, B.

    2017-12-01

    The Coupled Model Intercomparison Project (CMIP) has become a central element of national and international assessments of climate change. The CMIP Phase 6 (CMIP6) model experiments will be the foundation for the Intergovernmental Panel on Climate Change (IPCC) Sixth Assessment Report (AR6), scheduled for publication around 2021. To increase the fidelity of the IPCC AR6, the CMIP6 model experiments need rigorous evaluation. The "Observations for Model Intercomparison Projects" (Obs4MIPs) collects, organizes and publishes various well-established satellite data sets for CMIP model evaluation. The Atmospheric Infrared Sounder (AIRS) and Advanced Microwave Sounding Unit (AMSU), the NASA's temperature and humidity sounding system on the Aqua satellite, has provided over a decade-long high-quality tropospheric temperature and moisture sounding data. Under the current support of the NASA Data for Operation and Assessment (NDOA) program, we are generating and publishing the AIRS Obs4MIPs V2 data set including the monthly mean tropospheric air temperature, specific humidity, and relative humidity profiles from September 2002 to September 2016. This will provide the latest AIRS data in Obs4MIPs and assist the climate modeling community to better use the AIRS data for CMIP (including CMIP3, CMIP5, and CMIP6) model evaluation. In this presentation, we will discuss the AIRS Obs4MIPs V2 data set and their possible use for CMIP6 climate model evaluation.

  14. Global Positioning System: Observations on Quarterly Reports from the Air Force

    DTIC Science & Technology

    2016-10-17

    Positioning System : Observations on Quarterly Reports from the Air Force The satellite-based Global Positioning System (GPS) provides positioning, navigation...infrastructure, and transportation safety. The Department of Defense (DOD)—specifically, the Air Force—develops and operates the GPS system , which...programs, including the most recent detailed assessment of the next generation operational control system (OCX) and development of military GPS

  15. The composition of M-type asteroids: Synthesis of spectroscopic and radar observations

    NASA Astrophysics Data System (ADS)

    Ockert-Bell, M. E.; Clark, B. E.; Shepard, M. K.; Isaacs, R. A.; Cloutis, E. A.; Fornasier, S.; Bus, S. J.

    2010-12-01

    We have conducted a radar-driven observational campaign of 22 main-belt asteroids (MBAs) focused on Bus-DeMeo Xc- and Xk-type objects (Tholen X and M class asteroids) using the Arecibo radar and NASA Infrared Telescope Facilities (IRTF). Sixteen of our targets were near-simultaneously observed with radar and those observations are described in a companion paper (Shepard, M.K., and 19 colleagues [2010]. Icarus, in press). We find that most of the highest metal-content asteroids, as suggested by radar, tend to exhibit silicate absorption features at both 0.9 and 1.9 μm, and the lowest metal-content asteroids tend to exhibit either no bands or only the 0.9 μm band. Eleven of the asteroids were observed at several rotational longitudes in the near-infrared and significant variations in continuum slope were found for nine in the spectral regions 1.1-1.45 μm and 1.6-2.3 μm. We utilized visible wavelength data (Bus, S.J., Binzel, R.P. [2002b]. Icarus 158, 146-177; Fornasier, S., Clark, B.E., Dotto, E., Migliorini, A., Ockert-Bell, M., Barucci, M.A. [2010]. Icarus 210, 655-673.) for a more complete compositional analysis of our targets. Compositional evidence is derived from our target asteroid spectra using two different methods: (1) a χ2 search for spectral matches in the RELAB database, and (2) parametric comparisons with meteorites. This paper synthesizes the results of the RELAB search and the parametric comparisons with compositional suggestions based on radar observations. We find that for six of the seven asteroids with the highest iron abundances, our spectral results are consistent with the radar evidence (16 Psyche, 216 Kleopatra, 347 Pariana, 758 Mancunia, 779 Nina, and 785 Zwetana). Three of the seven asteroids with the lowest metal abundances, our spectral results are consistent with the radar evidence (21 Lutetia, 135 Hertha, 497 Iva). The remaining seven asteroids (22 Kalliope, 97 Klotho, 110 Lydia, 129 Antigone, 224 Oceana, 678 Fredegundis, and 771

  16. Review on recent progress in observations, source identifications and countermeasures of PM2.5.

    PubMed

    Liang, Chun-Sheng; Duan, Feng-Kui; He, Ke-Bin; Ma, Yong-Liang

    2016-01-01

    Recently, PM2.5 (atmospheric fine particulate matter with aerodynamic diameter ≤ 2.5 μm) have received so much attention that the observations, source appointment and countermeasures of it have been widely studied due to its harmful impacts on visibility, mood (mental health), physical health, traffic safety, construction, economy and nature, as well as its complex interaction with climate. A review on the PM2.5 related research is necessary. We start with summary of chemical composition and characteristics of PM2.5 that contains both macro and micro observation results and analysis, wherein the temporal variability of concentrations of PM2.5 and major components in many recent reports is embraced. This is closely followed by an overview of source appointment, including the composition and sources of PM2.5 in different countries in the six inhabitable continents based on the best available results. Besides summarizing PM2.5 pollution countermeasures by policy, planning, technology and ideology, the World Air Day is proposed to be established to inspire and promote the crucial social action in energy-saving and emission-reduction. Some updated knowledge of the important topics (such as formation and evolution mechanisms of hazes, secondary aerosols, aerosol mass spectrometer, organic tracers, radiocarbon, emissions, solutions for air pollution problems, etc.) is also included in the present review by logically synthesizing the studies. In addition, the key research challenges and future directions are put forward. Despite our efforts, our understanding of the recent reported observations, source identifications and countermeasures of PM2.5 is limited, and subsequent efforts both of the authors and readers are needed. Copyright © 2015 Elsevier Ltd. All rights reserved.

  17. Large Scale Variability of Mid-Tropospheric Carbon Dioxide as Observed by the Atmospheric Infrared Sounder (AIRS) on the NASA EOS Aqua Platform

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas S.; Olsen, Edward T.

    2012-01-01

    The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the EOS Aqua Spacecraft, launched on May 4, 2002. AIRS has 2378 infrared channels ranging from 3.7 microns to 15.4 microns and a 13.5 km footprint. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy, water vapor profiles (20%/2km), infrared cloud height and fraction, and trace gas amounts for CO2, CO, SO2, O3 and CH4 in the mid to upper troposphere. AIRS wide swath(cedilla) +/-49.5 deg , enables daily global daily coverage for over 95% of the Earth's surface. AIRS data are used for weather forecasting, validating climate model distribution and processes, and observing long-range transport of greenhouse gases. In this study, we examine the large scale and regional horizontal variability in the AIRS Mid-tropospheric Carbon Dioxide product as a function of season and associate the observed variability with known atmospheric transport processes, and sources and sinks of CO2.

  18. Retrievals of Sea Surface Emissivity and Skin Temperature from M-AERI Observations from the ACAPEX/CalWater2 Campaign

    NASA Astrophysics Data System (ADS)

    Gero, P. J.; Westphall, M.; Knuteson, R.; Knuteson, R. O.; Smith, W.

    2016-12-01

    The Atmospheric Emitted Radiance Interferometer (AERI) is a ground-based instrument developed at the University of Wisconsin-Madison that measures downwelling thermal infrared radiance from the atmosphere. Observations are made in the 520-3020 cm-1 (3.3-19 μm) spectral range with a resolution of 1 cm-1, with an accuracy better than 1% of ambient radiance. These observations can be used to obtain vertical profiles of tropospheric temperature and water vapor in the lowest 3 km of the troposphere, as well as measurements of the concentration of various trace gases and microphysical and optical properties of clouds and aerosols. The U.S Department of Energy's (DOE) Atmospheric Radiation Measurement (ARM) program currently operates about ten AERIs at various fixed and mobile sites worldwide, addressing a diverse range of scientific goals from process studies to long-term climate observations. One of the instruments is a marine version (M-AERI) that has the capability to view scenes ±45° from the horizon, and can be used to observe sea surface properties such as skin temperature and emissivity. The M-AERI was deployed on the NOAA Ship Ronald Brown in 2015 as part of the ACAPEX/CalWater2 campaign to study atmospheric rivers in the Pacific Ocean. We present results from the M-AERI from this campaign of retrievals of skin temperature and sea surface emissivity as a function of view angle and wind speed, as well as comparisons to various models.

  19. Observed Temporal Evolution of Global Mean Age of Stratospheric Air for the 2002 to 2010 Period

    NASA Astrophysics Data System (ADS)

    Stiller, G. P.; von Clarmann, T.; Haenel, F.; Funke, B.; Glatthor, N.; Grabowski, U.; Kellmann, S.; Kiefer, M.; Linden, A.; Lossow, S.; Lopez-Puertas, M.

    2011-12-01

    According to model calculations, the meridional circulation is expected to intensify as a result of climate change, and mean age of stratospheric air is expected to decrease. However, an observational data set presented recently (Engel et al., 2009) and consisting of 27 balloon samples of the age of air tracers carbon dioxide and sulfur hexafluoride covering the years 1975 to 2005 did not confirm the model predictions. As a contribution to the ongoing discussion, an extensive observational data set, consisting of more than 1 Million SF6 vertical profiles distributed globally is presented here. It has been derived from the MIPAS instrument covering the period 2002 to 2010 and has been converted into mean age of stratospheric air by referring to a combined data set of in-situ and flask global mean tropospheric SF6 measurements provided by NOAA/ESRL. During conversion into age of air, the non-linearity of tropospheric SF6 increase has been corrected for by convolution with the age spectrum within an iterative approach. Monthly zonal means of mean age of air, binned at 10 deg latitude and 1-2 km altitude, were analyzed with respect to their temporal variation by fitting a regression model consisting of a constant and a linear increase term, 2 proxies for the QBO variation, sinusoidal terms for the seasonal and semi-annual variation and overtones for the correction of the shapes to the observed data set. The impact of subsidence of mesospheric SF6-depleted air and in-mixing into non-polar latitudes on mid-latitudinal absolute age of air and the age-of-air linear increase was assessed and found to be small. The linear increase of mean age of stratospheric air was found to be positive and partly larger than the trend derived by Engel et al. (2009) for most of the Northern mid-latitudes, the middle stratosphere in the tropics, and parts of the Southern mid-latitudes, as well as for the Southern polar upper stratosphere. Multi-year decrease of age of air was found for the

  20. Short-wavelength infrared (1.3-2.6 μm) observations of the nucleus of Comet 19P/Borrelly

    USGS Publications Warehouse

    Soderblom, L.A.; Britt, D.T.; Brown, R.H.; Buratti, B.J.; Kirk, R.L.; Owen, T.C.; Yelle, R.V.

    2004-01-01

    During the last two minutes before closest approach of Deep Space 1 to Comet 19P/Borrelly, a long exposure was made with the short-wavelength infrared (SWIR) imaging spectrometer. The observation yielded 46 spectra covering 1.3–2.6 μm; the footprint of each spectrum was ∼160 m × width of the nucleus. Borrelly's highly variegated and extremely dark 8-km-long nucleus exhibits a strong red slope in its short-wavelength infrared reflection spectrum. This slope is equivalent to J–K and H–K colors of ∼0.82 and ∼0.43, respectively. Between 2.3–2.6 μm thermal emission is clearly detectable in most of the spectra. These data show the nucleus surface to be hot and dry; no trace of H2O ice was detected. The surface temperature ranged continuously across the nucleus from ⩽300 K near the terminator to a maximum of ∼340 K, the expected sub-solar equilibrium temperature for a slowly rotating body. A single absorption band at ∼2.39 μm is quite evident in all of the spectra and resembles features seen in nitrogen-bearing organic molecules that are reasonable candidates for compositional components of cometary nuclei. However as of yet the source of this band is unknown.

  1. 90 GHz Observations of M87 and Hydra A

    NASA Technical Reports Server (NTRS)

    Cotton, W. D.; Mason, B. S.; Dicker, S. R.; Korngut, P. M.; Devlin, M. J.; Aquirre, J.; Benford, D. J.; Moseley, S. H.; Staguhn, J. G.; Irwin, K. D.; hide

    2009-01-01

    This paper presents new observations of the active galactic nuclei M87 and Hydra A at 90 GHz made with the MUSTANG array on the Green Bank Telescope at 8"5 resolution. A spectral analysis is performed combining this new data and archival VLA 7 data on these objects at longer wavelengths. This analysis can detect variations in spectral index and curvature expected from energy losses in the radiating particles. M87 shows only weak evidence for steepening of the spectrum along the jet suggesting either re-acceleration of the relativistic particles in the jet or insufficient losses to affect the spectrum at 90 GHz. The jets in Hydra A show strong steepening as they move from the nucleus suggesting unbalanced losses of the higher energy relativistic particles. The difference between these two sources may be accounted for by the lengths over which the jets are observable, 2 kpc for M87 and 45 kpc for Hydra A.

  2. Characteristics of air quality and sources affecting fine particulate matter (PM2.5) levels in the City of Red Deer, Canada.

    PubMed

    Bari, Md Aynul; Kindzierski, Warren B

    2017-02-01

    With concern about levels and exceedances of Canadian and provincial standards and objectives for fine particulate matter (PM 2.5 ) in recent years, an investigation of air quality characteristics and potential local and long-range sources influencing PM 2.5 concentrations was undertaken in the City of Red Deer, Alberta. The study covered the period May 2009 to December 2015. Comparatively higher concentrations of PM 2.5 were observed in winter (mean: 11.6 μg/m 3 , median: 10 μg/m 3 ) than in summer (mean: 9.0 μg/m 3 , median: 7.0 μg/m 3 ). Exceedances of the 1 h Alberta Ambient Air Quality objective (3-31 times per year > 80 μg/m 3 ) and the 24 h Canada-Wide Standard (2-11 times per year > 30 μg/m 3 ) were found at the Red Deer Riverside air monitoring station, particularly in 2010, 2011 and 2015. Positive matrix factorization (PMF) followed by multiple linear regression (MLR) analysis identified a mixed industry/agriculture factor as the dominant contributor to PM 2.5 (39.3%), followed by an O 3 -rich (biogenic) factor (26.4%), traffic (19.3%), biomass burning (10.5%) and a mixed urban factor (4.4%). In addition to local traffic, the mixed industry/agriculture factor - inferred as mostly upstream oil and gas emission sources surrounding Red Deer - was identified as another potentially important source contributing to wintertime high PM 2.5 pollution days. These findings offer useful preliminary information about current PM 2.5 sources and their potential contributions in Red Deer; and this information can support policy makers in the development of particulate matter control strategies if required. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. New metal-organic polygons involving MM quadruple bonds: M8(O2CtBu)4(mu-SC4H2-3,4-{CO2}2)6 (M=Mo, W).

    PubMed

    Byrnes, Matthew J; Chisholm, Malcolm H; Patmore, Nathan J

    2005-12-12

    The reactions between M2(O2CtBu)4, where M=Mo or W, and thienyl-3,4-dicarboxylic acid (0.5-1.5 equiv) in toluene proceed via a series of detectable intermediates to the compounds M8(O2CtBu)4(mu-SC4H2-3,4-{CO2}2)6, which are isolated as air-sensitive yellow (M=Mo) or red (M=W) powders and show parent molecular ions in their mass spectra (MALDI). The structure of the molybdenum complex was determined by single-crystal X-ray crystallography and shown to contain an unusual M8 polygon involving four Mo2 quadruply bonded units linked via the agency of the six 3,4-thienylcarboxylate groups. The structure has crystallographically imposed S4 symmetry and may be described in terms of a highly distorted tetrahedron of Mo2 units or a bisphenoid in which two Mo2 units are linked by a thienyldicarboxylate such that intramolecular Mo2...O bonding is present, while the other thienylcarboxylate bridges merely serve to link these two [Mo2]...[Mo2] units together. The color of the compounds arises from intense M2 delta-to-thienyl pi transitions and, in THF, the complexes are redox-active and show four successive quasi-reversible oxidation waves. The [M8]+ radical cations, generated by one-electron oxidation with AgPF6, are shown to be valence-trapped (class II) by UV-vis-near-IR and electron paramagnetic resonance spectroscopy. These results are supported by the electronic structure calculations on model compounds M8(O2CH)4(mu-SC4H2-3,4-{CO}2)6 employing density functional theory that reveal only a small splitting of the M2 delta manifold via mixing with the 3,4-thienylcarboxylate pi system.

  4. VizieR Online Data Catalog: Sgr B2(N) and Sgr B2(M) IRAM 30m line survey (Belloche+, 2013)

    NASA Astrophysics Data System (ADS)

    Belloche, A.; Mueller, H. S. P.; Menten, K. M.; Schilke, P.; Comito, C.

    2013-08-01

    The list of line identifications corresponding to the blue labels in Figs. 2 to 7 where the labels are often too crowded to be easily readable are available in ASCII format. The lists are split into six files, three for Sgr B2(N) and three for Sgr B2(M). For each source, there is one file per atmospheric window (3, 2, and 1mm). Each file is ordered by increasing frequency. The observed and synthetic spectra of Sgr B2(N) and Sgr B2(M) between 80 and 116GHz are available both in ASCII and FITS formats. The synthetic spectra were resampled to the same frequency channels as the observed spectra. The blanking value is -1000K for the ASCII files. There is one ASCII file per source. There are two FITS files per source, one for the observed spectrum and one for the synthetic spectrum. The intensities are in main-beam temperature scale in K. The blanking value is 42.75234K for the observed spectrum of SgrB2(N) and 53.96533K for the observed spectrum of SgrB2(M). (9 data files).

  5. Public-health impact of outdoor air pollution for 2(nd) air pollution management policy in Seoul metropolitan area, Korea.

    PubMed

    Leem, Jong Han; Kim, Soon Tae; Kim, Hwan Cheol

    2015-01-01

    Air pollution contributes to mortality and morbidity. We estimated the impact of outdoor air pollution on public health in Seoul metropolitan area, Korea. Attributable cases of morbidity and mortality were estimated. Epidemiology-based exposure-response functions for a 10 μg/m3 increase in particulate matter (PM2.5 and PM10) were used to quantify the effects of air pollution. Cases attributable to air pollution were estimated for mortality (adults ≥ 30 years), respiratory and cardiovascular hospital admissions (all ages), chronic bronchitis (all ages), and acute bronchitis episodes (≤18 years). Environmental exposure (PM2.5 and PM10) was modeled for each 3 km × 3 km. In 2010, air pollution caused 15.9% of total mortality or approximately 15,346 attributable cases per year. Particulate air pollution also accounted for: 12,511 hospitalized cases of respiratory disease; 20,490 new cases of chronic bronchitis (adults); 278,346 episodes of acute bronchitis (children). After performing the 2(nd) Seoul metropolitan air pollution management plan, the reducible death number associated with air pollution is 14,915 cases per year in 2024. We can reduce 57.9% of death associated with air pollution. This assessment estimates the public-health impacts of current patterns of air pollution. Although individual health risks of air pollution are relatively small, the public-health consequences are remarkable. Particulate air pollution remains a key target for public-health action in the Seoul metropolitan area. Our results, which have also been used for economic valuation, should guide decisions on the assessment of environmental health-policy options.

  6. Indoor air quality in Virginia waterpipe cafés

    PubMed Central

    Cobb, Caroline Oates; Vansickel, Andrea Rae; Blank, Melissa D; Jentink, Kade; Travers, Mark J; Eissenberg, Thomas

    2014-01-01

    Introduction A revised indoor air quality law has been implemented in Virginia to protect the public from the harmful effects of secondhand smoke exposure. This legislation contains exemptions that include allowances for smoking in a room that is structurally separated and separately ventilated. The objective of the current study was to examine the impact of this law on air quality in waterpipe cafés, as well as to compare the air quality in these cafés to restaurants that allow cigarette smoking and those where no smoking is permitted. Methods Indoor air quality in 28 venues (17 waterpipe cafés, five cigarette smoking-permitted restaurants and six smoke-free restaurants (five with valid data)) in Virginia was assessed during 4 March to 27 May 2011. Real-time measurements of particulate matter (PM) with 2.5 µm aerodynamic diameter or smaller (PM2.5) were obtained and occupant behaviour/venue characteristics were assessed. Results The highest mean PM2.5 concentration was observed for waterpipe café smoking rooms (374 µg/m3, n=17) followed by waterpipe café non-smoking rooms (123 µg/m3, n=11), cigarette smoking-permitted restaurant smoking rooms (119 µg/m3, n=5), cigarette smoking-permitted restaurant non-smoking rooms (26 µg/m3, n=5) and smoke-free restaurants (9 µg/m3, n=5). Smoking density was positively correlated with PM2.5 across smoking rooms and the smoke-free restaurants. In addition, PM2.5 was positively correlated between smoking and non-smoking rooms of venues. Conclusions The PM2.5 concentrations observed among the waterpipe cafés sampled here indicated air quality in the waterpipe café smoking rooms was worse than restaurant rooms in which cigarette smoking was permitted, and state-required non-smoking rooms in waterpipe cafés may expose patrons and employees to PM2.5 concentrations above national and international air quality standards. Reducing the health risks of secondhand smoke may require smoke-free establishments in which tobacco

  7. M2-F1 in flight over lakebed on tow line

    NASA Technical Reports Server (NTRS)

    1963-01-01

    Following the first M2-F1 airtow flight on 16 August 1963, the Flight Research Center used the vehicle for both research flights and to check out new lifting-body pilots. These included Bruce Peterson, Don Mallick, Fred Haise, and Bill Dana from NASA. Air Force pilots who flew the M2-F1 included Chuck Yeager, Jerry Gentry, Joe Engle, Jim Wood, and Don Sorlie, although Wood, Haise, and Engle only flew on car tows. In the three years between the first and last flights of the M2-F1, it made about 400 car tows and 77 air tows. The wingless, lifting body aircraft design was initially concieved as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and

  8. Airborne aldehydes in cabin-air of commercial aircraft: Measurement by HPLC with UV absorbance detection of 2,4-dinitrophenylhydrazones.

    PubMed

    Rosenberger, Wolfgang; Beckmann, Bibiana; Wrbitzky, Renate

    2016-04-15

    This paper presents the strategy and results of in-flight measurements of airborne aldehydes during normal operation and reported "smell events" on commercial aircraft. The aldehyde-measurement is a part of a large-scale study on cabin-air quality. The aims of this study were to describe cabin-air quality in general and to detect chemical abnormalities during the so-called "smell-events". Adsorption and derivatization of airborne aldehydes on 2,4-dinitrophenylhydrazine coated silica gel (DNPH-cartridge) was applied using tailor-made sampling kits. Samples were collected with battery supplied personal air sampling pumps during different flight phases. Furthermore, the influence of ozone was investigated by simultaneous sampling with and without ozone absorption unit (ozone converter) assembled to the DNPH-cartridges and found to be negligible. The method was validated for 14 aldehydes and found to be precise (RSD, 5.5-10.6%) and accurate (recovery, 98-103 %), with LOD levels being 0.3-0.6 μg/m(3). According to occupational exposure limits (OEL) or indoor air guidelines no unusual or noticeable aldehyde pollution was observed. In total, 353 aldehyde samples were taken from two types of aircraft. Formaldehyde (overall average 5.7 μg/m(3), overall median 4.9 μg/m(3), range 0.4-44 μg/m(3)), acetaldehyde (overall average 6.5 μg/m(3), overall median 4.6, range 0.3-90 μg/m(3)) and mostly very low concentrations of other aldehydes were measured on 108 flights. Simultaneous adsorption and derivatization of airborne aldehydes on DNPH-cartridges to the Schiff bases and their HPLC analysis with UV absorbance detection is a useful method to measure aldehydes in cabin-air of commercial aircraft. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Nocturnal Air Seiches in the Arizona Meteor Crater

    NASA Astrophysics Data System (ADS)

    Muschinski, A.; Fritts, D. C.; Zhong, S.; Oncley, S. P.

    2011-12-01

    The Arizona Meteor Crater near Winslow, AZ is 170 m deep, has a diameter of 1.2 km, and it has a nearly circular shape. The motivation of the Meteor Crater Experiment (METCRAX), conducted in October 2006, was to use the Meteor Crater as a natural laboratory to study atmospheric phenomena that are typical for small basins. Among other observations, high-resolution wind, temperature and pressure measurements were collected with sonics and microbarometers, respectively, during the entire month. The sensors were mounted between 0.5 m and 8.5 m AGL on seven portable towers, five of which were located within the crater and two on the crater rim. Here we report observations of nocturnal air seiches, that is, standing gravity waves associated with the time-harmonic sloshing of the cold-air pool that forms at the bottom of the crater due to radiative cooling at night. We present time series, spectra, and spectrograms of temperature, wind and pressure fluctuations that characterize those air seiches. Typical seiche periods were 15 min. We compare the observations with the time-harmonic solutions of the shallow-water equation and with numerical simulations.

  10. Ground-Based Observing Campaign of Briz-M Debris

    NASA Technical Reports Server (NTRS)

    Lederer, S. M.; Buckalew, B.; Frith, J.; Cowardin, H. M.; Hickson, P.; Matney, M.; Anz-Meador, P.

    2017-01-01

    In 2015, NASA's Orbital Debris Program Office (ODPO) completed the installation of the Meter Class Autonomous Telescope (MCAT) on Ascension Island. MCAT is a 1.3m optical telescope designed with a fast tracking capability for observing orbital debris at all orbital regimes (Low-Erath orbits to Geosyncronous (GEO) orbits) from a low latitude site. This new asset is dedicated year-round for debris observations, and its location fills a geographical gap in the Ground-based Electro Optical Space Surveillance (GEODSS) network. A commercial off the shelf (COTS) research grade 0.4m telescope (named the Benbrook telescope) will also be installed on Ascension at the end of 2016. This smaller version is controlled by the same master software, designed by Euclid Research, and can be tasked to work independently or in concert with MCAT. Like MCAT, it has a the same suite of filters, a similar field of view, and a fast-tracking Astelco mount, and is also capable of tracking debris at all orbital regimes. These assets are well suited for targeted campagins or surveys of debris. Since 2013, NASA's ODPO has also had extensive access to the 3.8m infrared UKIRT telescope, located on Mauna Kea. At nearly 14,000-ft, this site affords excellent conditions for collecting both photometery and spectroscopy at near-IR (0.9 - 2.5 micrometers SWIR) and thermal-IR (8 - 25 micrometers; LWIR) regimes, ideal for investigating material properties as well as thermal characteristics and sizes of debris. For the purposes of understanding orbital debris, taking data in both survey mode as well as targeting individual objects for more in-depth characterizations are desired. With the recent break-ups of Briz-M rocket bodies, we have collected a suite of data in the optical, near-infrared, and mid-infrared of in-tact objects as well as those classified as debris. A break-up at GEO of a Briz-M rocket occurred in January, 2016, well timed for the first remote observing survey-campaign with MCAT. Access to

  11. Tailoring Mechanically Robust Poly(m-phenylene isophthalamide) Nanofiber/nets for Ultrathin High-Efficiency Air Filter

    PubMed Central

    Zhang, Shichao; Liu, Hui; Yin, Xia; Li, Zhaoling; Yu, Jianyong; Ding, Bin

    2017-01-01

    Effective promotion of air filtration applications proposed for fibers requires their real nanoscale diameter, optimized pore structure, and high service strength; however, creating such filter medium has proved to be a tremendous challenge. This study first establishes a strategy to design and fabricate novel poly(m-phenylene isophthalamide) nanofiber/nets (PMIA NF/N) air filter via electrospinning/netting. Our strategy results in generation of a bimodal structure including a scaffold of nanofibers and abundant two-dimensional ultrathin (~20 nm) nanonets to synchronously construct PMIA filters by combining solution optimization, humidity regulation, and additive inspiration. Benefiting from the structural features including the true nanoscale diameter, small pore size, high porosity, and nets bonding contributed by the widely distributed nanonets, our PMIA NF/N filter exhibits the integrated properties of superlight weight (0.365 g m−2), ultrathin thickness (~0.5 μm), and high tensile strength (72.8 MPa) for effective air filtration, achieving the ultra-low penetration air filter level of 99.999% and low pressure drop of 92 Pa for 300–500 nm particles by sieving mechanism. The successful synthesis of PMIA NF/N would not only provide a promising medium for particle filtration, but also develop a versatile platform for exploring the application of nanonets in structural enhancement, separation and purification. PMID:28074880

  12. Impacts of emission reduction and meteorological conditions on air quality improvement during the 2014 Youth Olympic Games in Nanjing, China

    NASA Astrophysics Data System (ADS)

    Huang, Qian; Wang, Tijian; Chen, Pulong; Huang, Xiaoxian; Zhu, Jialei; Zhuang, Bingliang

    2017-11-01

    As the holding city of the 2nd Youth Olympic Games (YOG), Nanjing is highly industrialized and urbanized, and faces several air pollution issues. In order to ensure better air quality during the event, the local government took great efforts to control the emissions from pollutant sources. However, air quality can still be affected by synoptic weather, not only emission. In this paper, the influences of meteorological factors and emission reductions were investigated using observational data and numerical simulations with WRF-CMAQ (Weather Research and Forecasting - Community Multiscale Air Quality). During the month in which the YOG were held (August 2014), the observed hourly mean concentrations of SO2, NO2, PM10, PM2.5, CO and O3 were 11.6 µg m-3, 34.0 µg m-3, 57.8 µg m-3, 39.4 µg m-3, 0.9 mg m-3 and 38.8 µg m-3, respectively, which were below China National Ambient Air Quality Standard (level 2). However, model simulation showed that the weather conditions, such as weaker winds during the YOG, were adverse for better air quality and could increase SO2, NO2, PM10, PM2.5 and CO by 17.5, 16.9, 18.5, 18.8, 7.8 and 0.8 %. Taking account of local emission abatement only, the simulated SO2, NO2, PM10, PM2.5 and CO decreased by 24.6, 12.1, 15.1, 8.1 and 7.2 %. Consequently, stringent emission control measures can reduce the concentrations of air pollutants in the short term, and emission reduction is very important for air quality improvement during the YOG. A good example has been set for air quality protection for important social events.

  13. Assessing changes in stratospheric mean age of air and fractional release using historical trace gas observations

    NASA Astrophysics Data System (ADS)

    Laube, Johannes; Bönisch, Harald; Engel, Andreas; Röckmann, Thomas; Sturges, William

    2014-05-01

    ., Sugawara, S., Moore, F., Hurst, D., Elkins, J., Schauffler, S., Andrews, A., and Boering, K.: Age of stratospheric air unchanged within uncertainties over the past 30 years, Nature Geoscience, 2, 28-31, 2009 Laube, J.C., Keil, A., Bönisch, H., Engel., A., Röckmann, T., Volk, C. M., and Sturges, W. T.: Observation-based assessment of stratospheric fractional release, lifetimes, and ozone depletion potentials of ten important source gases, Atmos. Chem. Phys., 13, 2779-2791, 2013 Newman, P. A., Daniel, J. S., Waugh, D. W., and Nash, E. R.: A new formulation of equivalent effective stratospheric chlorine (EESC), Atmos. Chem. Phys., 7, 4537-4552, 2007.

  14. Toxicological Assessment of ISS Air Quality: SpaceX-2 First Ingress

    NASA Technical Reports Server (NTRS)

    Meyers, Valerie

    2013-01-01

    One mini-grab sample container (M-GSC) was collected by crew members onboard ISS during first ingress into SpaceX-2 on March 3, 2013, three days after late cargo loading and a pre-launch clean air purge. Recoveries of the three surrogate standards from the m-GSC were: 13C-acetone, 97%; fluorobenzene, 95%; and chlorobenzene, 68%.

  15. Suitability Screening Test for Marine Corps Air Traffic Controllers Phase 2

    DTIC Science & Technology

    2013-06-10

    Karen M. Walker, Ph.D. William L. Farmer, Ph.D. Rebecca C. Roberts, MS Navy Personnel Research, Studies, and Technology NPRST-TR-13-2...June 2013 Suitability Screening Test for Marine Corps Air Traffic Controllers Phase II Karen M. Walker, Ph.D. William L. Farmer, Ph.D. Rebecca...C. Roberts, MS Navy Personnel Research, Studies, and Technology Reviewed by Tanja Blackstone , Ph.D. Approved and released by D. M. Cashbaugh

  16. Suitability Screening Test for Marine Corps Air Traffic Controllers. Phase 2

    DTIC Science & Technology

    2013-06-01

    Karen M. Walker, Ph.D. William L. Farmer, Ph.D. Rebecca C. Roberts, MS Navy Personnel Research, Studies, and Technology NPRST-TR-13-2...June 2013 Suitability Screening Test for Marine Corps Air Traffic Controllers Phase II Karen M. Walker, Ph.D. William L. Farmer, Ph.D. Rebecca...C. Roberts, MS Navy Personnel Research, Studies, and Technology Reviewed by Tanja Blackstone , Ph.D. Approved and released by D. M. Cashbaugh

  17. Comparison of three distinct clean air suits to decrease the bacterial load in the operating room: an observational study.

    PubMed

    Kasina, Piotr; Tammelin, Ann; Blomfeldt, Anne-Marie; Ljungqvist, Bengt; Reinmüller, Berit; Ottosson, Carin

    2016-01-01

    Lowering air-borne bacteria counts in the operating room is essential in prevention of surgical site infections in orthopaedic joint replacement surgery. This is mainly achieved by decreasing bacteria counts through dilution, with appropriate ventilation and by limiting the bacteria carrying skin particles, predominantly shed by the personnel. The aim of this study was to investigate if a single use polypropylene clothing system or a reusable polyester clothing system could offer similar air quality in the operating room as a mobile laminar airflow device-assisted reusable cotton/polyester clothing system. Prospective observational study design, comparing the performance of three Clean Air Suits by measuring Colony Forming Units (CFU)/m(3) of air during elective hip and knee arthroplasties, performed at a large university-affiliated hospital. The amount of CFU/m(3) of air was measured during 37 operations of which 13 were performed with staff dressed in scrub suits made of a reusable mixed material (69 % cotton, 30 % polyester, 1 % carbon fibre) accompanied by two mobile laminar airflow units. During 24 procedures no mobile laminar airflow units were used, 13 with staff using a reusable olefin fabric clothing (woven polypropylene) and 11 with staff dressed in single-use suits (non-woven spunbonded polypropylene). Air from the operating field was sampled through a filter, by a Sartorius MD8, and bacterial colonies were counted after incubation. There were 6-8 measurements from each procedure, in total 244 measurements. Statistical analysis was performed by Mann-Whitney U-test. The single-use polypropylene suit reduced the amount of CFU/m(3) to a significantly lower level than both other clothing systems. Single-use polypropylene clothing systems can replace mobile laminar airflow unit-assisted reusable mixed material-clothing systems. Measurements in standardized laboratory settings can only serve as guidelines as environments in real operation settings present a

  18. Observed temporal evolution of global mean age of stratospheric air for the 2002 to 2010 period

    NASA Astrophysics Data System (ADS)

    Stiller, G. P.; von Clarmann, T.; Haenel, F.; Funke, B.; Glatthor, N.; Grabowski, U.; Kellmann, S.; Kiefer, M.; Linden, A.; Lossow, S.; López-Puertas, M.

    2012-04-01

    An extensive observational data set from MIPAS measurements, consisting of more than one million SF6 vertical profiles distributed globally has been condensed into monthly zonal means of mean age of air for the period September 2002 to January 2010, binned at 10° latitude and 1-2 km altitude. The data were analysed with respect to their temporal variation by fitting a regression model consisting of: a constant and a linear increase term, 2 proxies for the QBO variation, sinusoidal terms for the seasonal and semi-annual variation and overtones for the correction of the shapes to the observed data set. The impact of subsidence of mesospheric SF6-depleted air and in-mixing into non-polar latitudes on mid-latitudinal age of air and its linear increase was assessed and found to be small. The linear increase of mean age of stratospheric air was found to be positive and partly larger than the trend derived by Engel et al. (2009) for most of the Northern mid-latitudes, the middle stratosphere in the tropics, and parts of the Southern mid-latitudes, as well as for the Southern polar upper stratosphere. Multi-year decrease of age of air was found for the lowermost and the upper stratospheric tropics, for parts of Southern mid-latitudes, and for the Northern polar regions. Analyses of the amplitudes and phases of the seasonal variation shed light on the coupling between different stratospheric regions. In particular, the Northern mid-latitude stratosphere is well coupled to the tropics, while the Northern lowermost mid-latitudinal stratosphere is decoupled, confirming the separation of the shallow branch of the Brewer-Dobson circulation from the deep branch. We suggest an overall increased tropical upwelling, together with a weakening of mixing barriers, especially in the Northern hemisphere, as possible explanations for the observed patterns. Reference: Engel, A., Möbius, T., Bönisch, H., Schmidt, U., Heinz, R., Levin, I., Atlas, E., Aoki, S., Nakazawa, T., Sugawara, S

  19. Fermi Large Area Telescope observations of Local Group galaxies: detection of M 31 and search for M 33

    DOE PAGES

    Abdo, A. A.

    2010-11-01

    Context. Cosmic rays (CRs) can be studied through the galaxy-wide gamma-ray emission that they generate when propagating in the interstellar medium. The comparison of the diffuse signals from different systems may inform us about the key parameters in CR acceleration and transport. Aims. We aim to determine and compare the properties of the cosmic-ray-induced gamma-ray emission of several Local Group galaxies. Methods. We use 2 years of nearly continuous sky-survey observations obtained with the Large Area Telescope aboard the Fermi Gamma-ray Space Telescope to search for gamma-ray emission from M 31 and M 33. We compare the results with thosemore » for the Large Magellanic Cloud, the Small Magellanic Cloud, the Milky Way, and the starburst galaxies M 82 and NGC 253. Results. We detect a gamma-ray signal at 5σ significance in the energy range 200 MeV–20 GeV that is consistent with originating from M 31. The integral photon flux above 100 MeV amounts to (9.1 ± 1.9stat ± 1.0sys) × 10 -9 ph cm-2 s -1. We find no evidence for emission from M 33 and derive an upper limit on the photon flux >100 MeV of 5.1 × 10 -9 ph cm -2 s -1 (2σ). Comparing these results to the properties of other Local Group galaxies, we find indications of a correlation between star formation rate and gamma-ray luminosity that also holds for the starburst galaxies. Conclusions. The gamma-ray luminosity of M 31 is about half that of the Milky Way, which implies that the ratio between the average CR densities in M 31 and the Milky Way amounts to ξ = 0.35 ± 0.25. The observed correlation between gamma-ray luminosity and star formation rate suggests that the flux of M 33 is not far below the current upper limit from the LAT observations.« less

  20. [Assessment of the air quality improment of cleaning and disinfection on central air-conditioning ventilation system].

    PubMed

    Liu, Hongliang; Zhang, Lei; Feng, Lihong; Wang, Fei; Xue, Zhiming

    2009-09-01

    To assess the effect of air quality of cleaning and disinfection on central air-conditioning ventilation systems. 102 air-conditioning ventilation systems in 46 public facilities were sampled and investigated based on Hygienic assessment criterion of cleaning and disinfection of public central air-conditioning systems. Median dust volume decreased from 41.8 g/m2 to 0.4 g/m2, and the percentage of pipes meeting the national standard for dust decreased from 17.3% (13/60) to 100% (62/62). In the dust, median aerobic bacterial count decreased from 14 cfu/cm2 to 1 cfu/cm2. Median aerobic fungus count decreased from 10 cfu/cm2 to 0 cfu/cm2. The percentage of pipes with bacterial and fungus counts meeting the national standard increased from 92.4% (171/185) and 82.2% (152/185) to 99.4% (165/166) and 100% (166/166), respectively. In the ventilation air, median aerobic bacterial count decreased from 756 cfu/m3 to 229 cfu/m3. Median aerobic fungus count decreased from 382 cfu/m3 to 120 cfu/m3. The percentage of pipes meeting the national standard for ventilation air increased from 33.3% (81/243) and 62.1% (151/243) to 79.8% (292/366) and 87.7% (242/276), respectively. But PM10 rose from 0.060 mg/m3 to 0.068 mg/m3, and the percentage of pipes meeting the national standard for PM10 increased from 74.2% (13/60) to 90.2% (46/51). The cleaning and disinfection of central air-conditioning ventilation systems could have a beneficial effect of air quality.

  1. M2-F1 in flight over lakebed on tow line

    NASA Technical Reports Server (NTRS)

    1963-01-01

    After initial ground-tow flights of the M2-F1 using the Pontiac as a tow vehicle, the way was clear to make air tows behind a C-47. The first air tow took place on 16 August 1963. Pilot Milt Thompson found that the M2-F1 flew well, with good control. This first flight lasted less than two minutes from tow-line release to touchdown. The descent rate was 4,000 feet per minute. The wingless, lifting body aircraft design was initially concieved as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and racing slicks, the Pontiac could tow the 1,000-pound M2-F1 110 miles per hour in 30 seconds. It proved adequate for the roughly 400 car tows that got

  2. Carbon-catalyzed oxidation of SO2 by NO2 and air

    NASA Technical Reports Server (NTRS)

    Rogowski, R. S.; Schryer, D. R.; Cofer, W. R., III; Edahl, R. A., Jr.; Munavalli, S.

    1982-01-01

    A series of experiments was performed using carbon particles (commercial furnace black) as a surrogate for soot particles. Carbon particles were suspended in water, and gas mixtures were bubbled into the suspensions to observe the effect of carbon particles on the oxidation of SO2 by air and NO2. Identical gas mixtures were bubbled into a blank containing only pure water. After exposure each solution was analyzed for pH and sulfate. It was found that NO2 greatly enhances the oxidation of SO2 to sulfate in the presence of carbon particles. The amount of sulfate found in the blanks was significantly less. Under the conditions of these experiments no saturation of the reaction was observed and SO2 was converted to sulfate even in a highly acid medium (pH or = 1.5).

  3. Hurricane Katrina as Observed by NASA's Spaceborne Atmospheric Infrared Sounder (AIRS)

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Figure 1: click on image for larger AIRS microwave image

    At 1:30 a.m. local time this morning, the remnants of (now Tropical Depression) Katrina were centered on the Mississippi-Tennessee border. This microwave image from the Atmospheric Infrared Sounder instrument on NASA's Aqua spacecrat shows that the area of most intense precipitation was concentrated to the north of the center of activity.

    The infrared image shows how the storms look through an AIRS Infrared window channel. Window channels measure the temperature of the cloud tops or the surface of the Earth in cloud-free regions. The lowest temperatures are associated with high, cold cloud tops that make up the top of the hurricane. The infrared signal does not penetrate through clouds, so the purple color indicates the cool cloud tops of the storm. In cloud-free areas, the infrared signal is retrieved at the Earth's surface, revealing warmer temperatures. Cooler areas are pushing to purple and warmer areas are pushing to red.

    The microwave image (figure 1) reveals where the heaviest precipitation in the hurricane is taking place. The blue areas within the storm show the location of this heavy precipitation. Blue areas outside of the storm where there are moderate or no clouds are where the cold (in the microwave sense) sea surface shines through.

    The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard

  4. Observed OH and HO2 concentrations in the upper troposphere inside and outside of Asian monsoon influenced air.

    NASA Astrophysics Data System (ADS)

    Marno, D. R.; Künstler, C.; Hens, K.; Tatum Ernest, C.; Broch, S.; Fuchs, H.; Martinez, M.; Bourtsoukidis, E.; Williams, J.; Holland, F.; Hofzumahaus, A.; Tomsche, L.; Fischer, H.; Klausner, T.; Schlager, H.; Eirenschmalz, L.; Stratmann, G.; Stock, P.; Ziereis, H.; Roiger, A.; Bohn, B.; Zahn, A.; Wahner, A.; Lelieveld, J.; Harder, H.

    2016-12-01

    The Asian monsoon convectively transports pollutants like volatile organic compounds (VOCs), NOx, and SO2 from the boundary layer over South Asia into the upper troposphere where they can potentially enter the stratosphere, or be dispersed globally. Therefore, it is crucial to understand the oxidizing capacity of this system regarding the rate of aerosol formation, and conversion of pollutants into compounds that have much shorter atmospheric lifetimes. OH plays a central role in this oxidation process. During the OMO-ASIA campaign in the summer of 2015, OH and HO2 were measured onboard the High Altitude Long-Range (HALO) Research Aircraft. Two laser-induced fluorescence instruments based on the fluorescence assay by gas expansion technique (LIF-FAGE) had been deployed, the AIR-LIF instrument from Forschungszentrum Jülich GmbH and the HORUS instrument from the Max Planck Institute for Chemistry, Mainz. To measure the chemical background of OH potentially produced inside the HORUS instrument from highly oxidized VOCs, atmospheric OH is scavenged by an Inlet Pre-injector (IPI) system. This was the first time an IPI system was implemented within an airborne LIF-FAGE instrument measuring OH and HO2. Throughout this campaign OH and HO2 were measured at 12 to 15km within the Asian monsoon anticyclone. These measurements have been contrasted by probing air outside the anticyclone in air masses influenced by North American emissions, and in very clean air masses originated from the southern hemisphere.

  5. Photochemical age of air pollutants, ozone, and secondary organic aerosol in transboundary air observed on Fukue Island, Nagasaki, Japan

    NASA Astrophysics Data System (ADS)

    Irei, Satoshi; Takami, Akinori; Sadanaga, Yasuhiro; Nozoe, Susumu; Yonemura, Seiichiro; Bandow, Hiroshi; Yokouchi, Yoko

    2016-04-01

    To better understand the secondary air pollution in transboundary air over westernmost Japan, ground-based field measurements of the chemical composition of fine particulate matter ( ≤ 1 µm), mixing ratios of trace gas species (CO, O3, NOx, NOy, i-pentane, toluene, and ethyne), and meteorological elements were conducted with a suite of instrumentation. The CO mixing ratio dependence on wind direction showed that there was no significant influence from primary emission sources near the monitoring site, indicating long- and/or mid-range transport of the measured chemical species. Despite the considerably different atmospheric lifetimes of NOy and CO, these mixing ratios were correlated (r2 = 0.67). The photochemical age of the pollutants, t[OH] (the reaction time × the mean concentration of OH radical during the atmospheric transport), was calculated from both the NOx / NOy concentration ratio (NOx / NOy clock) and the toluene / ethyne concentration ratio (hydrocarbon clock). It was found that the toluene / ethyne concentration ratio was significantly influenced by dilution with background air containing 0.16 ppbv of ethyne, causing significant bias in the estimation of t[OH]. In contrast, the influence of the reaction of NOx with O3, a potentially biasing reaction channel on [NOx] / [NOy], was small. The t[OH] values obtained with the NOx / NOy clock ranged from 2.9 × 105 to 1.3 × 108 h molecule cm-3 and were compared with the fractional contribution of the m/z 44 signal to the total signal in the organic aerosol mass spectra (f44, a quantitative oxidation indicator of carboxylic acids) and O3 mixing ratio. The comparison of t[OH] with f44 showed evidence for a systematic increase of f44 as t[OH] increased, an indication of secondary organic aerosol (SOA) formation. To a first approximation, the f44 increase rate was (1.05 ± 0.03) × 10-9 × [OH] h-1, which is comparable to the background-corrected increase rate observed during the New England Air Quality

  6. Spitzer Observations of M33 & M83 and the Hot Star, Hii Region Connection

    NASA Astrophysics Data System (ADS)

    Rubin, R.; Simpson, J.; Colgan, S.; Dufour, R.; Citron, R.; Ray, K.; Erickson, E.; Haas, M.; Pauldrach, A.

    2007-05-01

    H II regions play a crucial role in the measurement of current interstellar abundances. They also serve as laboratories for atomic physics and provide fundamental data about heavy element abundances that serve to constrain models of galactic chemical evolution. We observed emission lines of [S IV] 10.5, H (7-6) 12.4, [Ne II] 12.8, [Ne III] 15.6, & [S III] 18.7 micron cospatially with the Spitzer Space Telescope using the Infrared Spectrograph (IRS) in short-high mode (SH). Here we concentrate on the galaxy M33 and compare the results with our earlier similar study of M83. In each of these substantially face-on spirals, we observed ˜25 H II regions, covering a full range of galactocentric radii (RG). For most of the M33 H II regions, we were able to measure the H (7-6) line while none were detectable in M83. This limited our M83 study to a determination of the Ne++/Ne+, /, and S3+/S++ abundance ratios vs. RG. Angular brackets denote fractional ionizations. As well as having the addition of fluxes for the H(7-6) line, the M33 H II regions are generally of much higher ionization than those in M83, resulting in larger Ne++/Ne+ and S3+/ S++ abundance ratios. For M33, in addition to what we derived for those nebulae in M83, we are also able to derive Ne/H, S/H and Ne/S vs. RG. Important advantages compared with prior optical studies are: 1) the IR lines have a weak and similar electron temperature (Te) dependence while optical lines vary exponentially with Te and 2) the IR lines suffer far less from interstellar extinction. Additionally, these data may be used as constraints on the ionizing spectral energy distribution for the stars exciting these nebulae by comparing the above ionic ratios with predictions using stellar atmosphere models from several different non-LTE model sets. This work is based on observations made with the Spitzer Space Telescope, which is operated by the Jet Propulsion Laboratory, California Institute of Technology under NASA contract

  7. Operational trace gas column observations from GOME-2 on MetOp

    NASA Astrophysics Data System (ADS)

    Valks, Pieter; Hao, Nan; Pinardi, Gaia; Hedelt, Pascal; Liu, Song; Van Roozendael, Michel; De Smedt, Isabelle; Theys, Nicolas; Koukouli, MariLiza; Balis, Dimitris

    2017-04-01

    This contribution focuses on the operational GOME-2 trace gas column products developed in the framework of EUMETSAT's Satellite Application Facility on Atmospheric Composition Monitoring (AC-SAF). We present an overview of the retrieval algorithms for ozone, OClO, NO2, SO2 and formaldehyde, and we show examples of various applications such as air quality and climate monitoring, using observations from the GOME-2 instruments on MetOp-A and MetOp-B. Total ozone and the minor trace gas columns from GOME-2 are retrieved with the latest version 4.8 of the GOME Data Processor (GDP), which uses an optimized Differential Optical Absorption Spectroscopy (DOAS) algorithm, with air mass factor conversions based on the LIDORT model. Improved total and tropospheric NO2 columns are retrieved in the visible wavelength region between 425 and 497 nm. SO2 emissions from volcanic and anthropogenic sources can be measured by GOME-2 using the UV wavelength region around 320 nm. For formaldehyde, an optimal DOAS fitting window around 335 nm has been determined for GOME-2. The GOME-2 trace gas columns have reached the operational EUMETSAT product status, and are available to the users in near real time (within two hours after sensing by GOME-2). The use of trace gas observations from the GOME-2 instruments on MetOp-A and MetOp-B for air quality purposed will be illustrated, e.g. for South-East Asia and Europe. Furthermore, comparisons of the GOME-2 satellite observations with ground-based measurements will be shown. Finally, the use of GOME-2 trace-gas column data in the Copernicus Atmosphere Monitoring Service (CAMS) will be presented.

  8. Multi-year objective analyses of warm season ground-level ozone and PM2.5 over North America using real-time observations and Canadian operational air quality models

    NASA Astrophysics Data System (ADS)

    Robichaud, A.; Ménard, R.

    2013-05-01

    We present multi-year objective analyses (OA) on a high spatio-temporal resolution (15 or 21 km, every hour) for the warm season period (1 May-31 October) for ground-level ozone (2002-2012) and for fine particulate matter (diameter less than 2.5 microns (PM2.5)) (2004-2012). The OA used here combines the Canadian Air Quality forecast suite with US and Canadian surface air quality monitoring sites. The analysis is based on an optimal interpolation with capabilities for adaptive error statistics for ozone and PM2.5 and an explicit bias correction scheme for the PM2.5 analyses. The estimation of error statistics has been computed using a modified version of the Hollingsworth-Lönnberg's (H-L) method. Various quality controls (gross error check, sudden jump test and background check) have been applied to the observations to remove outliers. An additional quality control is applied to check the consistency of the error statistics estimation model at each observing station and for each hour. The error statistics are further tuned "on the fly" using a χ2 (chi-square) diagnostic, a procedure which verifies significantly better than without tuning. Successful cross-validation experiments were performed with an OA set-up using 90% of observations to build the objective analysis and with the remainder left out as an independent set of data for verification purposes. Furthermore, comparisons with other external sources of information (global models and PM2.5 satellite surface derived measurements) show reasonable agreement. The multi-year analyses obtained provide relatively high precision with an absolute yearly averaged systematic error of less than 0.6 ppbv (parts per billion by volume) and 0.7 μg m-3 (micrograms per cubic meter) for ozone and PM2.5 respectively and a random error generally less than 9 ppbv for ozone and under 12 μg m-3 for PM2.5. In this paper, we focus on two applications: (1) presenting long term averages of objective analysis and analysis increments

  9. M2-F1 in flight during low-speed car tow

    NASA Technical Reports Server (NTRS)

    1963-01-01

    The M2-F1 shown in flight during a low-speed car tow runs across the lakebed. Such tests allowed about two minutes to test the vehicle's handling in flight. NASA Flight Research Center (later redesignated the Dryden Flight Research Center) personnel conducted as many as 8 to 14 ground-tow flights in a single day either to test the vehicle in preparation for air tows or to train pilots to fly the vehicle before they undertook air tows. The wingless, lifting body aircraft design was initially concieved as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and racing slicks, the Pontiac could tow the 1,000-pound M2-F1 110 miles per hour in 30

  10. Planetary camera observations of the central parsec of M32

    NASA Technical Reports Server (NTRS)

    Lauer, Tod R.; Faber, S. M.; Currie, Douglas G.; Ewald, S. P.; Groth, Edward J.; Hester, J. J.; Holtzman, Jon A.; Light, Robert M.; O'Neil, Earl J., Jr.; Shaya, Edward J.

    1992-01-01

    New HST observations are reported which show that the M32 nucleus is extremely dense, with rho0 not less than 4 x 10 exp 6 solar masses/cu pc if M32 has a core with rc not greater than 0.37 pc, and rho0 greater than 3 x 10 exp 7 solar masses/cu pc if it instead has a central r exp -1/2 cusp. Limits on the M32 core radius are nearly three times smaller, and those on the central density at least four times greater, than values inferred from the best ground-based observations. A central relaxation that is almost an order of magnitude shorter than previous estimates is inferred from the new core parameters; a shorter stellar collision time is also inferred. It is argued that a starlight cusp surrounds the central black hole.

  11. Planetary camera observations of the central parsec of M32

    NASA Astrophysics Data System (ADS)

    Lauer, Tod R.; Faber, S. M.; Currie, Douglas G.; Ewald, S. P.; Groth, Edward J.; Hester, J. Jeff; Holtzman, Jon A.; Light, Robert M.; O'Neil, Earl J., Jr.; Shaya, Edward J.; Westphal, James A.

    1992-08-01

    New HST observations are reported which show that the M32 nucleus is extremely dense, with rho0 not less than 4 x 10 exp 6 solar masses/cu pc if M32 has a core with rc not greater than 0.37 pc, and rho0 greater than 3 x 10 exp 7 solar masses/cu pc if it instead has a central r exp -1/2 cusp. Limits on the M32 core radius are nearly three times smaller, and those on the central density at least four times greater, than values inferred from the best ground-based observations. A central relaxation that is almost an order of magnitude shorter than previous estimates is inferred from the new core parameters; a shorter stellar collision time is also inferred. It is argued that a starlight cusp surrounds the central black hole.

  12. Observational study on the concentration distributions of SO{sub 2} and NO{sub 2} in Dhaka, Bangladesh under severe air pollution condition in winter

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Azad, A.K.; Kitada, T.

    1996-12-31

    Dhaka is the capital and the biggest city of Bangladesh, and is expanding very rapidly. Emissions from heavy traffic and many small industries and commercial complexes, newly developed in and around the city, are polluting the air of Dhaka city. The air pollution is severe especially in winter due to adverse meteorological conditions such as low wind speed and dry, stably-stratified air, which restricts the mixing height to low levels and prevent dispersion of pollutants. But so far no study of air pollution of Dhaka city has been done. We have first measured SO{sub 2} and NO{sub 2} concentrations inmore » Dhaka city in a large scale and derived their spatial distributions over Dhaka. Molecular diffusion tubes, which do not require power sources and are produced at low cost, have been used to measure the concentration distributions of SO{sub 2} and NO{sub 2} at 64 sites in Dhaka city and its suburbs during the period of December-January of 1995-96. The diffusion tube samplers were calibrated using 6 automated air pollution monitoring stations in Aichi-prefecture, Japan. The calibration curve and the distribution of the concentration data acquired by automatic measurement instrument at each location showed that the error range of measurements with the molecular diffusion tube samplers was 2-27%. The samples were analyzed using ion-chromatography and spectrophotometer to determine the concentrations of SO{sub 2} and NO{sub 2} respectively. The contamination of unexposed tubes under field conditions was determined and the value of the blank test was subtracted from the measurements of the diffusion tube samplers. The effects of wind turbulence and temperature were reduced using polyflon filters.« less

  13. Y2K’s Impact on the U.S. Air Force

    DTIC Science & Technology

    1999-03-01

    AU/ACSC/169/1999-03 AIR COMMAND AND STAFF COLLEGE AIR UNIVERSITY Y2K’S IMPACT ON THE U.S. AIR FORCE by William M. Propst, Major, USAF A Research...doom and gloom for the world come 1 January 2000 and I wanted to determine if the predictions were accurate or simply the rantings of a group of...boys Glenn and Jonathan who kept me focused during this year and provided me something to look forward to when all of this over—going back to a loving

  14. Evaluation of Urban Air Quality By Passive Sampling Technique

    NASA Astrophysics Data System (ADS)

    Nunes, T. V.; Miranda, A. I.; Duarte, S.; Lima, M. J.

    Aveiro is a flat small city in the centre of Portugal, close to the Atlantic coast. In the last two decades an intensive development of demographic, traffic and industry growth in the region was observed which was reflected on the air quality degrada- tion. In order to evaluate the urban air quality in Aveiro, a field-monitoring network by passive sampling with high space resolution was implemented. Twenty-four field places were distributed in a area of 3x3 Km2 and ozone and NO2 concentrations were measured. The site distribution density was higher in the centre, 250x250 m2 than in periphery where a 500x500 m2 grid was used. The selection of field places took into consideration the choice criteria recommendation by United Kingdom environmental authorities, and three tubes and a blank tube for each pollutant were used at each site. The sampling system was mounted at 3m from the ground usually profiting the street lampposts. Concerning NO2 acrylic tubes were used with 85 mm of length and an in- ternal diameter of 12mm, where in one of the extremities three steel grids impregnated with a solution of TEA were placed and fixed with a polyethylene end cup (Heal et al., 1999); PFA Teflon tube with 53 mm of length and 9 mm of internal diameter and three impregnated glass filters impregnated with DPE solution fixed by a teflon end cup was used for ozone sampling (Monn and Hargartner, 1990). The passive sampling method for ozone and nitrogen dioxide was compared with continuous measurements, but the amount of measurements wasnSt enough for an accurate calibration and validation of the method. Although this constraint the field observations (June to August 2001) for these two pollutants assign interesting information about the air quality in the urban area. A krigger method of interpolation (Surfer- Golden Software-2000) was applied to field data to obtain isolines distribution of NO2 and ozone concentration for the studied area. Even the used passive sampling method has many

  15. Air Pollution Particulate Matter Alters Antimycobacterial Respiratory Epithelium Innate Immunity

    PubMed Central

    Rivas-Santiago, César E.; Sarkar, Srijata; Cantarella, Pasquale; Osornio-Vargas, Álvaro; Quintana-Belmares, Raúl; Meng, Qingyu; Kirn, Thomas J.; Ohman Strickland, Pamela; Chow, Judith C.; Watson, John G.; Torres, Martha

    2015-01-01

    Inhalation exposure to indoor air pollutants and cigarette smoke increases the risk of developing tuberculosis (TB). Whether exposure to ambient air pollution particulate matter (PM) alters protective human host immune responses against Mycobacterium tuberculosis has been little studied. Here, we examined the effect of PM from Iztapalapa, a municipality of Mexico City, with aerodynamic diameters below 2.5 μm (PM2.5) and 10 μm (PM10) on innate antimycobacterial immune responses in human alveolar type II epithelial cells of the A549 cell line. Exposure to PM2.5 or PM10 deregulated the ability of the A549 cells to express the antimicrobial peptides human β-defensin 2 (HBD-2) and HBD-3 upon infection with M. tuberculosis and increased intracellular M. tuberculosis growth (as measured by CFU count). The observed modulation of antibacterial responsiveness by PM exposure was associated with the induction of senescence in PM-exposed A549 cells and was unrelated to PM-mediated loss of cell viability. Thus, the induction of senescence and downregulation of HBD-2 and HBD-3 expression in respiratory PM-exposed epithelial cells leading to enhanced M. tuberculosis growth represent mechanisms by which exposure to air pollution PM may increase the risk of M. tuberculosis infection and the development of TB. PMID:25847963

  16. Hurricane Isabel, Amount of Atmospheric Water Vapor Observed By AIRS

    NASA Technical Reports Server (NTRS)

    2003-01-01

    [figure removed for brevity, see original site] Figure 1

    These false-color images show the amount of atmospheric water vapor observed by AIRS two weeks prior to the passage of Hurricane Isabel, and then when it was a Category 5 storm. The region shown includes parts of South America and the West Indies. Puerto Rico is the large island below the upper left corner.

    Total water vapor represents the depth of a layer if all the water vapor in the atmosphere were to condense and fall to the surface. The color bar on the right sides of the plots give the thickness of this layer in millimeters (mm). The first image, from August 28, shows typical tropical water vapor amounts over the ocean: between roughly 25 and 50 mm, or 1 to 2 inches. The highest values of roughly 80 mm, seen as a red blob over South America, corresponds to intense thunderstorms. Thunderstorms pull in water vapor from surrounding regions and concentrate it, with much of it then falling as rain.

    Figure 1 shows total water during the passage of Hurricane Isabel on September 13. The storm is apparent: the ring of moderate values surrounding a very strong maximum of 100 mm. Total water of more than 80 mm is unusual, and these values correspond to the intense thunderstorms contained within Isabel. The thunderstorms--and the large values of total water--are fed by evaporation from the ocean in the hurricane's high winds. The water vapor near the center of the storm does not remain there long, since hurricane rain rates as high 50 mm (2 inches) per hour imply rapid cycling of the water we observe. Away from the storm the amount of total water vapor is rather low, associated with fair weather where air that ascended near the storm's eye returns to earth, having dropped its moisture as rain. Also seen in the second images are two small regions of about 70 mm of total water over south America. These are yet more thunderstorms, though likely much more benign than those in Isabel.

    The

  17. M2-F1 in flight

    NASA Technical Reports Server (NTRS)

    1965-01-01

    -10, both built by the Northrop Corporation, and the U.S. Air Force's X-24 program. The Lifting Body program also heavily influenced the Space Shuttle program. The M2-F1 program demonstrated the feasibility of the lifting body concept for horizontal landings of atmospheric entry vehicles. It also demonstrated a procurement and management concept for prototype flight research vehicles that produced rapid results at very low cost (approximately $50,000, excluding salaries of government employees assigned to the project).

  18. Coccolithophore surface distributions in the North Atlantic and their modulation of the air-sea flux of CO2 from 10 years of satellite Earth observation data

    NASA Astrophysics Data System (ADS)

    Shutler, J. D.; Land, P. E.; Brown, C. W.; Findlay, H. S.; Donlon, C. J.; Medland, M.; Snooke, R.; Blackford, J. C.

    2013-04-01

    Coccolithophores are the primary oceanic phytoplankton responsible for the production of calcium carbonate (CaCO3). These climatically important plankton play a key role in the oceanic carbon cycle as a major contributor of carbon to the open ocean carbonate pump (~50%) and their calcification can affect the atmosphere-to-ocean (air-sea) uptake of carbon dioxide (CO2) through increasing the seawater partial pressure of CO2 (pCO2). Here we document variations in the areal extent of surface blooms of the globally important coccolithophore, Emiliania huxleyi, in the North Atlantic over a 10-year period (1998-2007), using Earth observation data from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS). We calculate the annual mean sea surface areal coverage of E. huxleyi in the North Atlantic to be 474 000 ± 104 000 km2, which results in a net CaCO3 carbon (CaCO3-C) production of 0.14-1.71 Tg CaCO3-C per year. However, this surface coverage (and, thus, net production) can fluctuate inter-annually by -54/+8% about the mean value and is strongly correlated with the El Niño/Southern Oscillation (ENSO) climate oscillation index (r=0.75, p<0.02). Our analysis evaluates the spatial extent over which the E. huxleyi blooms in the North Atlantic can increase the pCO2 and, thus, decrease the localised air-sea flux of atmospheric CO2. In regions where the blooms are prevalent, the average reduction in the monthly air-sea CO2 flux can reach 55%. The maximum reduction of the monthly air-sea CO2 flux in the time series is 155%. This work suggests that the high variability, frequency and distribution of these calcifying plankton and their impact on pCO2 should be considered if we are to fully understand the variability of the North Atlantic air-to-sea flux of CO2. We estimate that these blooms can reduce the annual N. Atlantic net sink atmospheric CO2 by between 3-28%.

  19. Assessment of COSMIC radio occultation and AIRS hyperspectral IR sounder temperature products in the stratosphere using observed radiances

    NASA Astrophysics Data System (ADS)

    Feltz, M. L.; Knuteson, R. O.; Revercomb, H. E.

    2017-08-01

    Upper air temperature is defined as an essential climate variable by the World Meteorological Organization. Two remote sensing technologies being promoted for monitoring stratospheric temperatures are GPS radio occultation (RO) and spectrally resolved IR radiances. This study assesses RO and hyperspectral IR sounder derived temperature products within the stratosphere by comparing IR spectra calculated from GPS RO and IR sounder products to coincident IR observed radiances, which are used as a reference standard. RO dry temperatures from the University Corporation for Atmospheric Research (UCAR) Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC) mission are compared to NASA Atmospheric Infrared Sounder (AIRS) retrievals using a previously developed profile-to-profile collocation method and vertical temperature averaging kernels. Brightness temperatures (BTs) are calculated for both COSMIC and AIRS temperature products and are then compared to coincident AIRS measurements. The COSMIC calculated minus AIRS measured BTs exceed the estimated 0.5 K measurement uncertainty for the winter time extratropics around 35 hPa. These differences are attributed to seasonal UCAR COSMIC biases. Unphysical vertical oscillations are seen in the AIRS L2 temperature product in austral winter Antarctic regions, and results imply a small AIRS tropical warm bias around 35 hPa in the middle stratosphere.

  20. Characterization of AIRS temperature and water vapor measurement capability using correlative observations

    NASA Technical Reports Server (NTRS)

    Fetzer, Eric J.; Eldering, Annmarie; Lee, Sung-Yung

    2005-01-01

    In this presentation we address several fundamental issues in the measurement of temperature and water vapor by AIRS: accuracy, precision, vertical resolution and biases as a function of cloud amount. We use two correlative data sources. First we compare AIRS total water vapor with that from the Advanced microwave Sounding Radiometer for EOS (AMSR-E) instrument, also onboard the Aqua spacecraft. AMSRE uses a mature methodology with a heritage including the operational Special Sensor Microwave Imager (SSM/I) instruments. AIRS and AMSR-E observations are collocated and simultaneous, providing a very large data set for comparison: about 200,000 over-ocean matches daily. We show small cloud-dependent biases between AIRS and AMSR-E total water vapor for several oceanic regions. Our second correlative data source is several hundred dedicated radiosondes launched during AIRS overpasses.

  1. Observation of a single-beam gradient-force optical trap for dielectric particles in air.

    PubMed

    Omori, R; Kobayashi, T; Suzuki, A

    1997-06-01

    A single-beam gradient-force optical trap for dielectric particles, which relies solely on the radiation pressure force of a TEM(00)-mode laser light, is demonstrated in air for what is believed to be the first time. It was observed that micrometer-sized glass spheres with a refractive index of n=1.45 remained trapped in the focus region for more than 30 min, and we could transfer them three dimensionally by moving the beam focus and the microscope stage. A laser power of ~40 mW was sufficient to trap a 5- microm -diameter glass sphere. The present method has several distinct advantages over the conventional optical levitation method.

  2. External CO2 and water supplies for enhancing electrical power generation of air-cathode microbial fuel cells.

    PubMed

    Ishizaki, So; Fujiki, Itto; Sano, Daisuke; Okabe, Satoshi

    2014-10-07

    Alkalization on the cathode electrode limits the electrical power generation of air-cathode microbial fuel cells (MFCs), and thus external proton supply to the cathode electrode is essential to enhance the electrical power generation. In this study, the effects of external CO2 and water supplies to the cathode electrode on the electrical power generation were investigated, and then the relative contributions of CO2 and water supplies to the total proton consumption were experimentally evaluated. The CO2 supply decreased the cathode pH and consequently increased the power generation. Carbonate dissolution was the main proton source under ambient air conditions, which provides about 67% of total protons consumed for the cathode reaction. It is also critical to adequately control the water content on the cathode electrode of air-cathode MFCs because the carbonate dissolution was highly dependent on water content. On the basis of these experimental results, the power density was increased by 400% (143.0 ± 3.5 mW/m(2) to 575.0 ± 36.0 mW/m(2)) by supplying a humid gas containing 50% CO2 to the cathode chamber. This study demonstrates that the simultaneous CO2 and water supplies to the cathode electrode were effective to increase the electrical power generation of air-cathode MFCs for the first time.

  3. The Earth Observation Data for Habitat Monitoring (EODHaM) system

    NASA Astrophysics Data System (ADS)

    Lucas, Richard; Blonda, Palma; Bunting, Peter; Jones, Gwawr; Inglada, Jordi; Arias, Marcela; Kosmidou, Vasiliki; Petrou, Zisis I.; Manakos, Ioannis; Adamo, Maria; Charnock, Rebecca; Tarantino, Cristina; Mücher, Caspar A.; Jongman, Rob H. G.; Kramer, Henk; Arvor, Damien; Honrado, Joāo Pradinho; Mairota, Paola

    2015-05-01

    To support decisions relating to the use and conservation of protected areas and surrounds, the EU-funded BIOdiversity multi-SOurce monitoring System: from Space TO Species (BIO_SOS) project has developed the Earth Observation Data for HAbitat Monitoring (EODHaM) system for consistent mapping and monitoring of biodiversity. The EODHaM approach has adopted the Food and Agriculture Organization Land Cover Classification System (LCCS) taxonomy and translates mapped classes to General Habitat Categories (GHCs) from which Annex I habitats (EU Habitats Directive) can be defined. The EODHaM system uses a combination of pixel and object-based procedures. The 1st and 2nd stages use earth observation (EO) data alone with expert knowledge to generate classes according to the LCCS taxonomy (Levels 1 to 3 and beyond). The 3rd stage translates the final LCCS classes into GHCs from which Annex I habitat type maps are derived. An additional module quantifies changes in the LCCS classes and their components, indices derived from earth observation, object sizes and dimensions and the translated habitat maps (i.e., GHCs or Annex I). Examples are provided of the application of EODHaM system elements to protected sites and their surrounds in Italy, Wales (UK), the Netherlands, Greece, Portugal and India.

  4. Air content and O2/N2 tuned chronologies on local insolation signatures in the Vostok ice core are similar

    NASA Astrophysics Data System (ADS)

    Lipenkov, V.; Raynaud, D.; Loutre, M.-F.; Duval, P.; Lemieux-Dudon, B.

    2009-04-01

    An accurate chronology of ice cores is needed for interpreting the paleoclimatic record and understanding the relation between insolation and climate. A new domain of research in this area has been initially stimulated by the work of M. Bender (2002) linking the record of O2/N2 ratio in the air trapped in the Vostok ice with the local insolation. More recently, it has been proposed that the long-term changes in air content, V, recorded in ice from the high Antarctic plateau is also dominantly imprinted by the local summer insolation (Raynaud et al., 2007). The present paper presents a new V record from Vostok, which is compared with the published Vostok O2/N2 record for the same period of time (150-400 ka BP) by using the same spectral analysis methods. The spectral differences between the two properties and the possible mechanisms linking them with insolation through the surface snow structure and the close-off processes are discussed. The main result of our study is that the two experimentally independent local insolation proxies lead to absolute (orbital) time scales, which agree together within a standard deviation of 0.6 ka. This result strongly adds credibility to the air content of ice and the O2 to N2 ratio of the air trapped in ice as equally reliable and complementary tools for accurate dating of existing and future deep ice cores. References: M. Bender, Orbital tuning chronology for the Vostok climate record supported by trapped gas composition, Earth and Planetary Science Letters 204(2002) 275-289. D. Raynaud, V. Lipenkov, B. Lemieux-Dudon, P. Duval, M.F. Loutre, N. Lhomme, The local insolation signature of air content in Antarctic ice: a new step toward an absolute dating of ice records, Earth and Planetary Science Letters 261(2007) 337-349.

  5. The Effect of Viscous Air Damping on an Optically Actuated Multilayer MoS2 Nanomechanical Resonator Using Fabry-Perot Interference

    PubMed Central

    She, Yumei; Li, Cheng; Lan, Tian; Peng, Xiaobin; Liu, Qianwen; Fan, Shangchun

    2016-01-01

    We demonstrated a multilayer molybdenum disulfide (MoS2) nanomechanical resonator by using optical Fabry-Perot (F-P) interferometric excitation and detection. The thin circular MoS2 nanomembrane with an approximate 8-nm thickness was transferred onto the endface of a ferrule with an inner diameter of 125 μm, which created a low finesse F-P interferometer with a cavity length of 39.92 μm. The effects of temperature and viscous air damping on resonance behavior of the resonator were investigated in the range of −10–80 °C. Along with the optomechanical behavior of the resonator in air, the measured resonance frequencies ranged from 36 kHz to 73 kHz with an extremely low inflection point at 20 °C, which conformed reasonably to those solved by previously obtained thermal expansion coefficients of MoS2. Further, a maximum quality (Q) factor of 1.35 for the resonator was observed at 0 °C due to viscous dissipation, in relation to the lower Knudsen number of 0.0025~0.0034 in the tested temperature range. Moreover, measurements of Q factor revealed little dependence of Q on resonance frequency and temperature. These measurements shed light on the mechanisms behind viscous air damping in MoS2, graphene, and other 2D resonators. PMID:28335290

  6. Dynamical Structure and Turbulence in Cirrus Clouds: Aircraft Observations during FIRE.

    NASA Astrophysics Data System (ADS)

    Gultepe, I.; Starr, D. O'c.

    1995-12-01

    Aircraft data collected during the First International Satellite Cloud Climatology Project Regional Experiment (FIRE)I are used to examine dynamical processes operating in cirrus cloud systems observed on 19 and 28 October 1986. Measurements from Lagrangian spiral soundings and constant-altitude flight legs are analyzed. Comparisons are made with observations in clear air. Each cirrus case contained a statically stable layer, a conditionally unstable or neutrally stratified layer (ice pseudoadiabatic) in which convection was prevalent, and a neutral layer in which convection was intermittent. The analysis indicates that a mixture of phenomena occurred including small-scale convective cells, gravity waves (2-9 km), quasi-two-dimensional waves (10-20 km), and larger two-dimensional mesoscale waves (100 km). The intermediate-scale waves, observed both in clear air and in the cloud systems, likely played an important role in the development of the cloud systems given the magnitude of the associated vertical air velocity. The spectra of perturbations of wind components for layers where convection was prevalent were characterized by a 5/3 power law dependence, while a 2/4 dependence was found at other levels in the cloud systems. A steeper spectral slope (3) was found in the more stable cloud-base layer on 19 October. Samples in clear air also showed a (2.4) dependence. Flight-leg-averaged eddy potential heat fluxes (H=±8 W m2) were comparable to observations in marine stratocumulus clouds. Calculated turbulence dissipation rates agree with previously published studies, which indicate a general enhancement within cloud systems (106 to 103 m2 s3 in cloud versus values less than 0.5×106 m2 s3 in clear air).

  7. Performance of the air2stream model that relates air and stream water temperatures depends on the calibration method

    NASA Astrophysics Data System (ADS)

    Piotrowski, Adam P.; Napiorkowski, Jaroslaw J.

    2018-06-01

    A number of physical or data-driven models have been proposed to evaluate stream water temperatures based on hydrological and meteorological observations. However, physical models require a large amount of information that is frequently unavailable, while data-based models ignore the physical processes. Recently the air2stream model has been proposed as an intermediate alternative that is based on physical heat budget processes, but it is so simplified that the model may be applied like data-driven ones. However, the price for simplicity is the need to calibrate eight parameters that, although have some physical meaning, cannot be measured or evaluated a priori. As a result, applicability and performance of the air2stream model for a particular stream relies on the efficiency of the calibration method. The original air2stream model uses an inefficient 20-year old approach called Particle Swarm Optimization with inertia weight. This study aims at finding an effective and robust calibration method for the air2stream model. Twelve different optimization algorithms are examined on six different streams from northern USA (states of Washington, Oregon and New York), Poland and Switzerland, located in both high mountains, hilly and lowland areas. It is found that the performance of the air2stream model depends significantly on the calibration method. Two algorithms lead to the best results for each considered stream. The air2stream model, calibrated with the chosen optimization methods, performs favorably against classical streamwater temperature models. The MATLAB code of the air2stream model and the chosen calibration procedure (CoBiDE) are available as Supplementary Material on the Journal of Hydrology web page.

  8. Air-Quality Impacts and Intake Fraction of PM2.5 during the 2013 Rim Megafire.

    PubMed

    Navarro, Kathleen M; Cisneros, Ricardo; O'Neill, Susan M; Schweizer, Don; Larkin, Narasimhan K; Balmes, John R

    2016-11-01

    The 2013 Rim Fire was the third largest wildfire in California history and burned 257 314 acres in the Sierra Nevada Mountains. We evaluated air-quality impacts of PM 2.5 from smoke from the Rim Fire on receptor areas in California and Nevada. We employed two approaches to examine the air-quality impacts: (1) an evaluation of PM 2.5 concentration data collected by temporary and permanent air-monitoring sites and (2) an estimation of intake fraction (iF) of PM 2.5 from smoke. The Rim Fire impacted locations in the central Sierra nearest to the fire and extended to the northern Sierra Nevada Mountains of California and Nevada monitoring sites. Daily 24-h average PM 2.5 concentrations measured at 22 air monitors had an average concentration of 20 μg/m 3 and ranged from 0 to 450 μg/m 3 . The iF for PM 2.5 from smoke during the active fire period was 7.4 per million, which is slightly higher than representative iF values for PM 2.5 in rural areas and much lower than for urban areas. This study is a unique application of intake fraction to examine emissions-to-exposure for wildfires and emphasizes that air-quality impacts are not only localized to communities near large fires but can extend long distances and affect larger urban areas.

  9. AirCore-HR: a high-resolution column sampling to enhance the vertical description of CH4 and CO2

    NASA Astrophysics Data System (ADS)

    Membrive, Olivier; Crevoisier, Cyril; Sweeney, Colm; Danis, François; Hertzog, Albert; Engel, Andreas; Bönisch, Harald; Picon, Laurence

    2017-06-01

    An original and innovative sampling system called AirCore was presented by NOAA in 2010 Karion et al.(2010). It consists of a long ( > 100 m) and narrow ( < 1 cm) stainless steel tube that can retain a profile of atmospheric air. The captured air sample has then to be analyzed with a gas analyzer for trace mole fraction. In this study, we introduce a new AirCore aiming to improve resolution along the vertical with the objectives to (i) better capture the vertical distribution of CO2 and CH4, (ii) provide a tool to compare AirCores and validate the estimated vertical resolution achieved by AirCores. This (high-resolution) AirCore-HR consists of a 300 m tube, combining 200 m of 0.125 in. (3.175 mm) tube and a 100 m of 0.25 in. (6.35 mm) tube. This new configuration allows us to achieve a vertical resolution of 300 m up to 15 km and better than 500 m up to 22 km (if analysis of the retained sample is performed within 3 h). The AirCore-HR was flown for the first time during the annual StratoScience campaign from CNES in August 2014 from Timmins (Ontario, Canada). High-resolution vertical profiles of CO2 and CH4 up to 25 km were successfully retrieved. These profiles revealed well-defined transport structures in the troposphere (also seen in CAMS-ECMWF high-resolution forecasts of CO2 and CH4 profiles) and captured the decrease of CO2 and CH4 in the stratosphere. The multi-instrument gondola also carried two other low-resolution AirCore-GUF that allowed us to perform direct comparisons and study the underlying processing method used to convert the sample of air to greenhouse gases vertical profiles. In particular, degrading the AirCore-HR derived profiles to the low resolution of AirCore-GUF yields an excellent match between both sets of CH4 profiles and shows a good consistency in terms of vertical structures. This fully validates the theoretical vertical resolution achievable by AirCores. Concerning CO2 although a good agreement is found in terms of vertical structure

  10. Emissions of CO2 and criteria air pollutants from mobile sources: Insights from integrating real-time traffic data into local air quality models

    NASA Astrophysics Data System (ADS)

    Gately, Conor; Hutyra, Lucy

    2016-04-01

    In 2013, on-road mobile sources were responsible for over 26% of U.S. fossil fuel carbon dioxide (ffCO2) emissions, and over 34% of both CO and NOx emissions. However, accurate representations of these emissions at the scale of urban areas remains a difficult challenge. Quantifying emissions at the scale of local streets and highways is critical to provide policymakers with the information needed to develop appropriate mitigation strategies and to guide research into the underlying process that drive mobile emissions. Quantification of vehicle ffCO2 emissions at high spatial and temporal resolutions requires a detailed synthesis of data on traffic activity, roadway attributes, fleet characteristics and vehicle speeds. To accurately characterize criteria air pollutant emissions, information on local meteorology is also critical, as the temperature and relative humidity can affect emissions rates of these pollutants by as much as 400%. As the health impacts of air pollutants are more severe for residents living in close proximity (<500m) to road sources, it is critical that inventories of these emissions rely on highly resolved source data to locate potential hot-spots of exposure. In this study we utilize real-time GPS estimates of vehicle speeds to estimate ffCO2 and criteria air pollutant emissions at multiple spatial and temporal scales across a large metropolitan area. We observe large variations in emissions associated with diurnal activity patterns, congestion, sporting and civic events, and weather anomalies. We discuss the advantages and challenges of using highly-resolved source data to quantify emissions at a roadway scale, and the potential of this methodology for forecasting the air quality impacts of changes in infrastructure, urban planning policies, and regional climate.

  11. Emissions of CO2 and criteria air pollutants from mobile sources: Insights from integrating real-time traffic data into local air quality models

    NASA Astrophysics Data System (ADS)

    Gately, C.; Hutyra, L.; Sue Wing, I.; Peterson, S.; Janetos, A.

    2015-12-01

    In 2013, on-road mobile sources were responsible for over 26% of U.S. fossil fuel carbon dioxide (ffCO2) emissions, and over 34% of both CO and NOx emissions. However, accurate representations of these emissions at the scale of urban areas remains a difficult challenge. Quantifying emissions at the scale of local streets and highways is critical to provide policymakers with the information needed to develop appropriate mitigation strategies and to guide research into the underlying process that drive mobile emissions. Quantification of vehicle ffCO2 emissions at high spatial and temporal resolutions requires a detailed synthesis of data on traffic activity, roadway attributes, fleet characteristics and vehicle speeds. To accurately characterize criteria air pollutant emissions, information on local meteorology is also critical, as the temperature and relative humidity can affect emissions rates of these pollutants by as much as 400%. As the health impacts of air pollutants are more severe for residents living in close proximity (<500m) to road sources, it is critical that inventories of these emissions rely on highly resolved source data to locate potential hot-spots of exposure. In this study we utilize real-time GPS estimates of vehicle speeds to estimate ffCO2 and criteria air pollutant emissions at multiple spatial and temporal scales across a large metropolitan area. We observe large variations in emissions associated with diurnal activity patterns, congestion, sporting and civic events, and weather anomalies. We discuss the advantages and challenges of using highly-resolved source data to quantify emissions at a roadway scale, and the potential of this methodology for forecasting the air quality impacts of changes in infrastructure, urban planning policies, and regional climate.

  12. VizieR Online Data Catalog: Early observations of M13 variables (Osborn,+, 2016)

    NASA Astrophysics Data System (ADS)

    Osborn, W.; Barnard, E. E.

    2018-05-01

    In 1900 E.E. Barnard published 37 visual observations of Variable 2 (V2) in the globular cluster M13 made in 1899 and 1900. A review of Barnard's notebooks revealed he made many additional brightness estimates up to 1911, and he had also recorded the variations of V1 starting in 1904. These data provide the earliest-epoch light curves for these stars and thus are useful for studying their period changes. This paper presents Barnard's observations of the M13 variables along with their derived heliocentric Julian dates and approximate V magnitudes. These include 231 unpublished observations of V2 and 94 of V1. How these data will be of value for determining period changes by these stars is described. (5 data files).

  13. Stratospheric Intrusion-Influenced Ozone Air Quality Exceedences Investigated in MERRA-2

    NASA Technical Reports Server (NTRS)

    Knowland, K. Emma; Ott, Lesley; Duncan, Bryan; Wargan, Krzysztof

    2017-01-01

    Ozone near the surface is harmful to human health and is a result of the photochemical reaction with both man-made and natural precursor pollutant sources. Therefore, in order to reduce near surface ozone concentrations, communities must reduce anthropogenic pollution sources. However, the injection of stratospheric ozone into the troposphere, known as a stratospheric intrusion, can also lead to concentrations of ground-level ozone exceeding air quality standards. Stratospheric intrusions are dynamical atmospheric features, however, these intrusions have been misrepresented in models and reanalyses until recently, as the features of a stratospheric intrusion are best identified in horizontal resolutions of approximately 50 km or smaller. NASA's Modern-Era Retrospective Analysis for Research and Applications Version-2 (MERRA-2) reanalysis is a publicly-available high-resolution dataset (50 km) with assimilated ozone that characterizes stratospheric ozone on the same spatiotemporal resolution as the meteorology. We show that stratospheric intrusions that impact surface air quality are well represented in the MERRA-2 reanalysis. This is demonstrated through a case study analysis of stratospheric intrusion events which were identified by the United States Environmental Protection Agency (EPA) to impact surface ozone air quality in spring 2012 in Colorado. The stratospheric intrusions are identified in MERRA-2 by the folding of the dynamical tropopause under the jet stream and subsequent isentropic descent of dry, O3-rich stratospheric air towards the surface where ozone air quality exceedences were observed. The MERRA-2 reanalysis can support air quality agencies for more rapid identification of the impact of stratospheric air on ground-level ozone.

  14. Characterization of criteria air pollutants in Beijing during 2014-2015.

    PubMed

    Guo, Hao; Wang, Yungang; Zhang, Hongliang

    2017-04-01

    One year-long criteria air pollutants data collected in Beijing were analyzed in this paper, which can support the research on formation, transport and human health effects of air pollutants. This is the first time to study the spatial and temporal variations of criteria pollutants in Beijing using hourly observational data from 12 sites between June 2014 and May 2015 released by the Ministry of Environmental Protection (MEP) of China. Beijing is facing tremendous air pollution as the daily averaged PM 2.5 (particulate matter with aerodynamic diameter less than 2.5µm) concentrations in all sites exceeding the Chinese Ambient Air Quality Standards (CAAQS) Grade I & II standards (15 and 35µg/m 3 ). Slightly differences in PM 2.5 and ozone (O 3 ) were observed between sites at the urban and rural areas. Pearson correlation coefficients show that most pollutants are temporally correlated in Beijing except for O 3 . The coefficients of divergence (COD) indicate that PM 2.5 is associated at most sites with only one rural site (Dingling) having observable difference and one site may be insufficient for monitoring surrounding area. The 8h peak O 3 (O 3 -8h) also correlates at different sites but with one urban site (Haidianquwanliu) different from others. In addition, an extreme PM 2.5 event (hourly average concentration exceeding 300μg/m 3 for ~40h) was examined with the consideration of meteorological conditions. Southerly wind with low speed and high relative humidity allow the accumulation of pollutants while northerly wind with high speed and low relative humidity result in good air quality. Copyright © 2017 Elsevier Inc. All rights reserved.

  15. Performance of MnO2 Crystallographic Phases in Rechargeable Lithium-Air Oxygen Cathode

    NASA Astrophysics Data System (ADS)

    Oloniyo, Olubukun; Kumar, Senthil; Scott, Keith

    2012-05-01

    Manganese dioxide (MnO2) has been shown to be effective for improving the efficiency of cathodes in lithium-air cells. Different crystallographic phases including α-, β-, and γ-MnO2 nanowires, α-MnO2 nanospheres, and α-MnO2 nanowires on carbon ( α-MnO2/C) were synthesized using the hydrothermal method. Their physical properties were examined using x-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area measurements, and scanning electron microscopy (SEM) and found to be in agreement with the literature. Electrochemical properties of the synthesized catalyst particles were investigated by fabricating cathodes and testing them in a lithium-air cell with lithium hexafluorophosphate in propylene carbonate (LiPF6/PC) and tetra(ethylene glycol)dimethyl ether (LiTFSi/TEGDME) electrolytes. α-MnO2 had the highest discharge capacity in the LiTFSi/TEGDME electrolyte (2500 mAh/g), whilst α-MnO2/C in LiPF6/PC showed a significantly higher discharge capacity of 11,000 mAh/g based on total mass of the catalytic cathode. However, the latter showed poor capacity retention compared with γ-MnO2 nanowires, which was stable for up to 30 cycles. The reported discharge capacity is higher than recorded in previous studies on lithium-air cells.

  16. Evaluating the Impacts of Transboundary Air pollution from China on Air Quality in the U.S. Using a Regression Framework

    NASA Astrophysics Data System (ADS)

    Ngo, N. S.; Bao, X.; Zhong, N.

    2014-12-01

    China is the largest emitter of anthropogenic air pollution in the world and previous work has shown the environmental impacts of the long-range transport (LRT) of air pollution from China to the U.S. via chemical transport models, in situ observations, isentropic back trajectories, and to a lesser extent statistical models. However, these studies generally focus on a narrow time period due to data constraints. In this study, we build upon the literature using econometric techniques to isolate the impacts on U.S. air quality from the LRT of air pollution from China. We use a unique daily data set of China's air pollution index (API) and PM10 concentrations at the city level and merge these information with daily monitor data in California (CA) between 2000 and 2013. We first employ a distributed lag model to examine daily patterns, and then exploit a "natural experiment." In the latter methodology, since air pollution is rarely randomly assigned, we examine the impacts of specific events that affect air quality in China, but are plausibly uncorrelated to factors affecting air pollution in CA. For example, Chinese New Year (CNY) is a major week-long holiday and we show pollution levels in China decrease during this time period, likely from reductions in industrial production. CNY varies each calendar year since it is based off the lunar new year, so the timing of this pollution reduction could be considered "as good as random" or exogenous to factors affecting air quality in CA. Using a regression framework including weather, seasonal and geographic controls, we can potentially isolate the impact of the LRT of air pollution to CA. First, results from the distributed lag model suggest that in the Spring, when LRT peaks, a 1 μg/m3 increase in daily PM10 from China between 10 and 14 days ago is associated with an increase in today's PM2.5 in CA of 0.022 μg/m3 (mean daily PM2.5 in CA is 12 μg/m3). Second, we find that if CNY occurred 5 to 9 days ago, today's PM2.5 in

  17. M2-F1 in flight

    NASA Technical Reports Server (NTRS)

    1964-01-01

    NASA's Ames and Langley research centers--the M2-F2 and the HL-10, both built by the Northrop Corporation, and the U.S. Air Force's X-24 program. The Lifting Body program also heavily influenced the Space Shuttle program. The M2-F1 program demonstrated the feasibility of the lifting-body concept for horizontal landings of atmospheric entry vehicles. It also demonstrated a procurement and management concept for prototype flight research vehicles that produced rapid results at very low cost (approximately $50,000, excluding salaries of government employees assigned to the project).

  18. High angular resolution mm- and submm-observations of dense molecular gas in M82

    NASA Technical Reports Server (NTRS)

    Wild, W.; Eckart, Andreas; Genzel, Reinhard; Harris, Andrew I.; Jackson, James M.; Jaffe, D. T.; Lugten, J. B.; Stutzki, J.

    1990-01-01

    Researchers observed CO(7-6), CO(3-2), HCN(3-2) and HCO+(3-2) line emission toward the starburst nucleus of M82 and have obtained an upper limit to H13CN(3-2). These are the first observations of the CO(7-6), HCN(3-2) and HCO+(3-2) lines in any extragalactic source. Researchers took the CO(7-6) spectrum in January 1988 at the Infrared Telescope Facility (IRTF) with the Max Planck Institute for Extraterrestrial Physics/Univ. of California, Berkeley 800 GHz Heterodyne Receiver. In March 1989 researchers used the Institute for Radio Astronomy in the Millimeter range (IRAM) 30 m telescope to observe the CO(3-2) line with the new MPE 350 GHz Superconductor Insulator Superconductor (SIS) receiver and the HCN(3-2) and HCO+(3-2) lines with the (IRAM) 230 GHz SIS receiver (beam 12" FWHM, Blundell et al. 1988). The observational parameters are summarized.

  19. Synthesis and characterization of different MnO2 morphologies for lithium-air batteries

    NASA Astrophysics Data System (ADS)

    Choi, Hyun-A.; Jang, Hyuk; Hwang, Hyein; Choi, Mincheol; Lim, Dongwook; Shim, Sang Eun; Baeck, Sung-Hyeon

    2014-09-01

    Manganese dioxide (MnO2) was synthesized in the forms of nanorods, nanoparticles, and mesoporous structures and the characteristics of these materials were investigated. Crystallinities were studied by x-ray diffraction and morphologies by scanning and transmission electron microscopy. Average pore sizes and specific surface areas were analyzed using the Barret-Joyner-Halenda and Brunauer-Emmett-Teller methods, respectively. Samples were also studied by cyclic voltammetry using 1M aqueous KOH solution saturated with either O2 or N2 as electrolytes to investigate their ORR (oxygen reduction reaction) and OER (oxygen evolution reaction) activities. Of the samples produced, mesoporous MnO2 exhibited the highest ORR and OER catalytic activities. Mesoporous MnO2 supported on a gas diffusion layer was also used as a catalyst on the air electrode (cathode) of a lithium-air battery in organic electrolyte. The charge-discharge behavior of mesoporous MnO2 was investigated at a current density 0.2 mAcm-2 in a pure oxygen environment. Mesoporous MnO2 electrodes showed stable cycleability up to 65 cycles at a cell capacity of 700 mAhg-1.

  20. EURAMET project No. 1225: intercomparsion of very low air speed standard facilities (0.05 m/s to 1 m/s)

    NASA Astrophysics Data System (ADS)

    Pachinger, Dietmar; De Huu, Marc; Mueller, Harald; Care, Isabelle; Frederiksen, John; Piccato, Aline; Bertasiene, Agne

    2017-01-01

    For the first time a EURAMET comparison of standard facilities in the field of low air speed is presented. The air velocities range from 0.05 m/s up to 1 m/s. Two different thermal anemometers are used as Transfer Standards (TS), namely a ball-type and a planar-type anemometer. Due to their construction it is possible to analyze different components of the flow vector. Orientation-dependent measurements which are investigated in addition might also deliver information concerning the components of the flow vector. A Comparison Reference Value (CRV) is calculated with the help of the chi-squared test according to the procedure A presented by Cox [1] [2] and the degree of equivalence of the laboratory data to the CRV is determined. Both TS show reasonable results and a high degree of equivalence. Furthermore the degree of equivalence of the laboratory data to each other is investigated in detail. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

  1. Plume splitting and rebounding in a high-intensity CO{sub 2} laser induced air plasma

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen Anmin; Jiang Yuanfei; Liu Hang

    2012-07-15

    The dynamics of plasma plume formed by high-intensity CO{sub 2} laser induced breakdown of air at atmospheric pressure is investigated. The laser wavelength is 10.6 {mu}m. Measurements were made using 3 ns gated fast photography as well as space and time resolved optical emission spectroscopy. The behavior of the plasma plume was studied with a laser energy of 3 J and 10 J. The results show that the evolution of the plasma plume is very complicated. The splitting and rebounding of the plasma plume is observed to occur early in the plumes history.

  2. Air-ice CO2 fluxes and pCO2 dynamics in the Arctic coastal area (Amundsen Gulf, Canada)

    NASA Astrophysics Data System (ADS)

    Geilfus, Nicolas-Xavier; Tison, Jean Louis; Carnat, Gauthier; Else, Brent; Borges, Alberto V.; Thomas, Helmuth; Shadwick, Elizabeth; Delille, Bruno

    2010-05-01

    Sea ice covers about 7% of the Earth surface at its maximum seasonal extent. For decades sea ice was assumed to be an impermeable and inert barrier for air - sea exchange of CO2 so that global climate models do not include CO2 exchange between the oceans and the atmosphere in the polar regions. However, uptake of atmospheric CO2 by sea ice cover was recently reported raising the need to further investigate pCO2 dynamics in the marine cryosphere realm and related air-ice CO2 fluxes. In addition, budget of CO2 fluxes are poorly constrained in high latitudes continental shelves [Borges et al., 2006]. We report measurements of air-ice CO2 fluxes above the Canadian continental shelf and compare them to previous measurements carried out in Antarctica. We carried out measurements of pCO2 within brines and bulk ice, and related air-ice CO2 fluxes (chamber method) in Antarctic first year pack ice ("Sea Ice Mass Balance in Antarctica -SIMBA" drifting station experiment September - October 2007) and in Arctic first year land fast ice ("Circumpolar Flaw Lead" - CFL, April - June 2008). These 2 experiments were carried out in contrasted sites. SIMBA was carried out on sea ice in early spring while CFL was carried out in from the middle of the winter to the late spring while sea ice was melting. Both in Arctic and Antarctic, no air-ice CO2 fluxes were detected when sea ice interface was below -10°C. Slightly above -10°C, fluxes toward the atmosphere were observed. In contrast, at -7°C fluxes from the atmosphere to the ice were significant. The pCO2 of the brine exhibits a same trend in both hemispheres with a strong decrease of the pCO2 anti-correlated with the increase of sea ice temperature. The pCO2 shifted from a large over-saturation at low temperature to a marked under-saturation at high temperature. These air-ice CO2 fluxes are partly controlled by the permeability of the air-ice interface, which depends of the temperature of this one. Moreover, air-ice CO2 fluxes are

  3. Multi-year objective analyses of warm season ground-level ozone and PM2.5 over North America using real-time observations and Canadian operational air quality models

    NASA Astrophysics Data System (ADS)

    Robichaud, A.; Ménard, R.

    2014-02-01

    Multi-year objective analyses (OA) on a high spatiotemporal resolution for the warm season period (1 May to 31 October) for ground-level ozone and for fine particulate matter (diameter less than 2.5 microns (PM2.5)) are presented. The OA used in this study combines model outputs from the Canadian air quality forecast suite with US and Canadian observations from various air quality surface monitoring networks. The analyses are based on an optimal interpolation (OI) with capabilities for adaptive error statistics for ozone and PM2.5 and an explicit bias correction scheme for the PM2.5 analyses. The estimation of error statistics has been computed using a modified version of the Hollingsworth-Lönnberg (H-L) method. The error statistics are "tuned" using a χ2 (chi-square) diagnostic, a semi-empirical procedure that provides significantly better verification than without tuning. Successful cross-validation experiments were performed with an OA setup using 90% of data observations to build the objective analyses and with the remainder left out as an independent set of data for verification purposes. Furthermore, comparisons with other external sources of information (global models and PM2.5 satellite surface-derived or ground-based measurements) show reasonable agreement. The multi-year analyses obtained provide relatively high precision with an absolute yearly averaged systematic error of less than 0.6 ppbv (parts per billion by volume) and 0.7 μg m-3 (micrograms per cubic meter) for ozone and PM2.5, respectively, and a random error generally less than 9 ppbv for ozone and under 12 μg m-3 for PM2.5. This paper focuses on two applications: (1) presenting long-term averages of OA and analysis increments as a form of summer climatology; and (2) analyzing long-term (decadal) trends and inter-annual fluctuations using OA outputs. The results show that high percentiles of ozone and PM2.5 were both following a general decreasing trend in North America, with the eastern

  4. Advanced buffer materials for indoor air CO2 control in commercial buildings.

    PubMed

    Rajan, P E; Krishnamurthy, A; Morrison, G; Rezaei, F

    2017-11-01

    In this study, we evaluated solid sorbents for their ability to passively control indoor CO 2 concentration in buildings or rooms with cyclic occupancy (eg, offices, bedrooms). Silica supported amines were identified as suitable candidates and systematically evaluated in the removal of CO 2 from indoor air by equilibrium and dynamic techniques. In particular, sorbents with various amine loadings were synthesized using tetraethylenepentamine (TEPA), poly(ethyleneimine) (PEI) and a silane coupling agent 3-aminopropyltriethoxysilane (APS). TGA analysis indicates that TEPA impregnated silica not only displays a relatively high adsorption capacity when exposed to ppm level CO 2 concentrations, but also is capable of desorbing the majority of CO 2 by air flow (eg, by concentration gradient). In 10 L flow-through chamber experiments, TEPA-based sorbents reduced outlet CO 2 by up to 5% at 50% RH and up to 93% of CO 2 adsorbed over 8 hours was desorbed within 16 hours. In 8 m 3 flow-through chamber experiments, 18 g of the sorbent powder spread over a 2 m 2 area removed approximately 8% of CO 2 injected. By extrapolating these results to real buildings, we estimate that meaningful reductions in the CO 2 can be achieved, which may help reduce energy requirements for ventilation and/or improve air quality. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  5. Air Twitter: Mashing Crowdsourced Air Quality Event Identification with Scientific Earth Observations (Invited)

    NASA Astrophysics Data System (ADS)

    Robinson, E. M.

    2010-12-01

    , which allows time series of the number of tweets hourly and daily. Monitoring the time series AQ events are identified from the background chatter about air quality. As the events are identified, collaborative, EventSpaces (Robinson, 2008) are created using the ESIP wiki to collect and merge social and scientific information about the event. The EventSpaces are monitored using Google Analytics. During the August California Fires the traffic increased five-fold to the ESIP wiki. Furthermore, the increase in traffic was entirely due to views of the SoCal FireEventSpace. A top driver to the site was through tweeting the link to the EventSpace and having that link re-tweeted by others like the LA Times. An interesting an unexpected observation, was that most of the increased traffic was coming from Southern California. So the right people were finding the right information at the right time. The overall benefit of using the online community as an AQ event indicator, allows specific effort to be made for initial documentation of air quality events and the result is a catalog of events with some sparse analysis that can be followed-up.

  6. Jupiter's para-H2 distribution from SOFIA/FORCAST and Voyager/IRIS 17-37 μm spectroscopy

    NASA Astrophysics Data System (ADS)

    Fletcher, Leigh N.; de Pater, I.; Reach, W. T.; Wong, M.; Orton, G. S.; Irwin, P. G. J.; Gehrz, R. D.

    2017-04-01

    Spatially resolved maps of Jupiter's far-infrared 17-37 μm hydrogen-helium collision-induced spectrum were acquired by the FORCAST instrument on the Stratospheric Observatory for Infrared Astronomy (SOFIA) in May 2014. Spectral scans in two grisms covered the broad S(0) and S(1) absorption lines, in addition to contextual imaging in eight broad-band filters (5-37 μm) with spatial resolutions of 2-4″. The spectra were inverted to map the zonal-mean temperature and para-H2 distribution (fp, the fraction of the para spin isomer with respect to the ortho spin isomer) in Jupiter's upper troposphere (the 100-700 mbar range). We compared these to a reanalysis of Voyager-1 and -2 IRIS spectra covering the same spectral range. Tropospheric temperature contrasts match those identified by Voyager in 1979, within the limits of temporal variability consistent with previous investigations. Para-H2 increases from equator to pole, with low-fp air at the equator representing sub-equilibrium conditions (i.e., less para-H2 than expected from thermal equilibration), and high-fp air and possible super-equilibrium at higher latitudes. In particular, we confirm the continued presence of a region of high-fp air at high northern latitudes discovered by Voyager/IRIS, and an asymmetry with generally higher fp in the north than in the south. Far-IR aerosol opacity is not required to fit the data, but cannot be completely ruled out. We note that existing collision-induced absorption databases lack opacity from (H2)2 dimers, leading to under-prediction of the absorption near the S(0) and S(1) peaks. There appears to be no spatial correlation between para-H2 and tropospheric ammonia, phosphine and cloud opacity derived from Voyager/IRIS at mid-infrared wavelengths (7-15 μm). We note, however, that para-H2 tracks the similar latitudinal distribution of aerosols within Jupiter's upper tropospheric and stratospheric hazes observed in reflected sunlight, suggesting that catalysis of hydrogen

  7. Morphological modification of alpha-MnO2 catalyst for use in Li/air batteries.

    PubMed

    Park, Min-Sik; Kim, Jae-Hun; Kim, Ki Jae; Jeong, Goojin; Kim, Young-Jun

    2013-05-01

    Single crystal alpha-MnO2 nanowires and nanopowders have been successfully synthesized in order to facilitate a comparison of their catalytic activity for use in Li-air batteries. The importance of the morphological modification of the alpha-MnO2 catalyst for facilitating electrochemical reactions between Li and O2 is addressed. Distinctive catalytic activity of alpha-MnO2 is observed, which is in line with its different morphologies. The catalytic activity significantly affects the reversible capacity of Li-air batteries. A high aspect ratio, large surface area and good dispersibility of alpha-MnO2 in the nanowire form are advantageous providing larger active surfaces for promoting the fundamental reactions in Li-air batteries. We also introduce a robustly designed air-electrode composed of highly porous carbon and nanostructured alpha-MnO2 catalysts, with employs a metal foam current collector to ensure sufficient air-permeability and to maximize electronic conduction during cycles. Our suggestions should prove helpful in forming a basis for further investigations in developing advanced Li-air batteries.

  8. M2 polarization of macrophages by Oncostatin M in hypoxic tumor microenvironment is mediated by mTORC2 and promotes tumor growth and metastasis.

    PubMed

    Shrivastava, Richa; Asif, Mohammad; Singh, Varsha; Dubey, Parul; Ahmad Malik, Showkat; Lone, Mehraj-U-Din; Tewari, Brij Nath; Baghel, Khemraj Singh; Pal, Subhashis; Nagar, Geet Kumar; Chattopadhyay, Naibedya; Bhadauria, Smrati

    2018-04-03

    Oncostatin M (OSM), an inflammatory cytokine belonging to the interleukin-6 (IL-6) superfamily, plays a vital role in multitude of physiological and pathological processes. Its role in breast tumor progression and metastasis to distant organs is well documented. Recent reports implicate OSM in macrophage M2 polarization, a key pro-tumoral phenomenon. M2 polarization of macrophages is believed to promote tumor progression by potentiating metastasis and angiogenesis. In the current study, we delineated the mechanism underlying OSM induced macrophage M2 polarization. The findings revealed that OSM skews macrophages towards an M2 polarized phenotype via mTOR signaling complex 2 (mTORC2). mTORC2 relays signals through two effector kinases i.e. PKC-α and Akt. Our results indicated that mTORC2 mediated M2 polarization of macrophages is not dependent on PKC-α and is primarily affected via Akt, particularly Akt1. In vivo studies conducted on 4T1/BALB/c mouse orthotropic model of breast cancer further corroborated these observations wherein i.v. reintroduction of mTORC2 abrogated monocytes into orthotropic mouse model resulted in diminished acquisition of M2 specific attributes by tumor associated macrophages. Metastasis to distant organs like lung, liver and bone was reduced as evident by decrease in formation of focal metastatic lesions in mTORC2 abrogated monocytes mice. Our study pinpoints key role of mTORC2-Akt1 axis in OSM induced macrophage polarization and suggests for possible usage of Oncostatin-M blockade and/or selective mTORC2 inhibition as a potential anti-cancer strategy particularly with reference to metastasis of breast cancer to distant organs such as lung, liver and bone. Copyright © 2018 Elsevier Ltd. All rights reserved.

  9. Akeno 20 km (2) air shower array (Akeno Branch)

    NASA Technical Reports Server (NTRS)

    Teshima, M.; Ohoka, H.; Matsubara, Y.; Hara, T.; Hatano, Y.; Hayashida, N.; He, C. X.; Honda, M.; Ishikawa, F.; Kamata, K.

    1985-01-01

    As the first stage of the future huge array, the Akeno air shower array was expanded to about 20 sq. km. by adding 19 scintillation detectors of 2.25 sq m area outside the present 1 sq. km. Akeno array with a new data collection system. These detectors are spaced about 1km from each other and connected by two optical fiber cables. This array has been in partial operation from 8th, Sep. 1984 and full operation from 20th, Dec. 1984. 20 sq m muon stations are planned to be set with 2km separation and one of them is now under construction. The origin of the highest energy cosmic rays is studied.

  10. Residues of 2, 4-D in air samples from Saskatchewan: 1966-1975.

    PubMed

    Grover, R; Kerr, L A; Wallace, K; Yoshida, K; Maybank, J

    1976-01-01

    Residues of 2,4-D (2,4-dichlorophenoxyacetic acid) in air samples from several sampling sites in central and southern Saskatchewan during the spraying seasons in the 1966-68 and 1970-75 periods were determined by gas-liquid chromatographic techniques. Initially, individual esters of 2,4-D were characterized by retention times and confirmed further by co-injection and dual column procedures. Since 1973, however, only total 2,4-D acid levels in air samples have been determined after esterification to the methyl ester and confirmed by gc/ms techniques whenever possible. Up to 50% of the daily samples collected during the spraying season at any of the locations and during any given year contained 2,4-D, with butyl esters being found most frequently. The daily 24-hr mean atmospheric concentrations of 2,4-D ranged from 0.01 to 1.22 mug/m3, 0.01 to 13.50 mug/m3, and 0.05 to 0.59 mug/m3 for the iso-propyl, mixed butyl and iso-octyl esters, respectively. Even when the samples were analysed for the total 2,4-D content, i.e. from 1973 onwards, the maximum level of the total acid reached only 23.14 mug/m3. In any given year and at any of the sampling sites, about 30% of the samples contained less than 0.01 mug/m3 of 2,4-D. In another 40% of the samples, the levels of 2,4-D ranged from 0.01 to 0.099 mug/m3. Only about 30% of the samples contained 2,4-D concentrations higher than 0.1 mug/m3, with only 10% or less exceeding 1 mug/m3. None of the samples, obtained with the high volume particulate sampler, showed any detectable levels of 2,4-D, indicating little or no transport of 2,4-D adsorbed on dust particles or as crystals of amine salts.

  11. Altus AFB, Oklahoma Revised Uniform Summary of Surface Weather Observations (RUSSWO). Parts A-F.

    DTIC Science & Technology

    1985-09-01

    4 _ 2; 4, InI Air Weather Service ( MAC) Aft 1 REVISED UNIFOCM SUMMAARY CW SC IL!8k 2 SURFACE WATHER OBE3RVATION$ 2b1l__ ALTUS m~F3 OK.MC 732 4 40 99...BRANCH PERCENIA6E FRECQUENCY OF OCCURRENCE OF CEILING VERSUS VISIBILIIV USAFTEAC FRON HOURLY OBSERVATIONS AIR WATHER SERVICE/HAC STATION NUMBER: 123520

  12. Modeling forest C and N allocation responses to free-air CO2 enrichment

    NASA Astrophysics Data System (ADS)

    Luus, Kristina; De Kauwe, Martin; Walker, Anthony; Werner, Christian; Iversen, Colleen; McCarthy, Heather; Medlyn, Belinda; Norby, Richard; Oren, Ram; Zak, Donald; Zaehle, Sönke

    2015-04-01

    models to more reliably capture responses of ecosystem C and N allocation to free-air CO2 enrichment because they were able to simulate the priming effect. Insights were therefore gained into between-site differences observed in forest FACE experiments, and the underlying physiological and biogeochemical mechanisms determining ecosystem C and N allocation responses to elevated CO2. References 1. De Kauwe, M. G., et al. (2014), Where does the carbon go? A model-data intercomparison of vegetation carbon allocation and turnover processes at two temperate forest free-air CO2 enrichment sites, New Phytologist, 203, 883-899. 2. Walker, A. P., et al. (2014), Comprehensive ecosystem model-data synthesis using multiple data sets at two temperate forest free-air CO2 enrichment experiments: Model performance at ambient CO2 concentration, Journal of Geophysical Research: Biogeosciences, 119, 937-964. 3. Zaehle, S., et al. (2014), Evaluation of 11 terrestrial carbon-nitrogen cycle models against observations from two temperate Free-Air CO2 Enrichment studies, New Phytologist, 202 (3), 803-822.

  13. M2-F1 in hangar with Pontiac tow vehicle

    NASA Technical Reports Server (NTRS)

    1963-01-01

    The M2-F1 Lifting Body is seen here in a hangar with its hotrod Pontiac convertible tow vehicle at the Flight Research Center (later the Dryden Flight Research Center), Edwards, California. The car was a 1963 Pontiac Catalina convertible, fitted with a 421-cubic-inch tripower engine like those being run at the Daytona 500 auto race. The vehicle also had a four-speed transmission and a heavy-duty suspension and cooling system. A roll bar was also added and the passenger seat turned around so an observer could watch the M2-F1 while it was being towed. The rear seat was removed and a second, side-facing seat installed. The lifting-body team used the Pontiac for all the ground-tow flights over the next three years. The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey

  14. Air pollution particulate matter alters antimycobacterial respiratory epithelium innate immunity.

    PubMed

    Rivas-Santiago, César E; Sarkar, Srijata; Cantarella, Pasquale; Osornio-Vargas, Álvaro; Quintana-Belmares, Raúl; Meng, Qingyu; Kirn, Thomas J; Ohman Strickland, Pamela; Chow, Judith C; Watson, John G; Torres, Martha; Schwander, Stephan

    2015-06-01

    Inhalation exposure to indoor air pollutants and cigarette smoke increases the risk of developing tuberculosis (TB). Whether exposure to ambient air pollution particulate matter (PM) alters protective human host immune responses against Mycobacterium tuberculosis has been little studied. Here, we examined the effect of PM from Iztapalapa, a municipality of Mexico City, with aerodynamic diameters below 2.5 μm (PM2.5) and 10 μm (PM10) on innate antimycobacterial immune responses in human alveolar type II epithelial cells of the A549 cell line. Exposure to PM2.5 or PM10 deregulated the ability of the A549 cells to express the antimicrobial peptides human β-defensin 2 (HBD-2) and HBD-3 upon infection with M. tuberculosis and increased intracellular M. tuberculosis growth (as measured by CFU count). The observed modulation of antibacterial responsiveness by PM exposure was associated with the induction of senescence in PM-exposed A549 cells and was unrelated to PM-mediated loss of cell viability. Thus, the induction of senescence and downregulation of HBD-2 and HBD-3 expression in respiratory PM-exposed epithelial cells leading to enhanced M. tuberculosis growth represent mechanisms by which exposure to air pollution PM may increase the risk of M. tuberculosis infection and the development of TB. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

  15. Photochemical removal of NO(2) by using 172-nm Xe(2) excimer lamp in N(2) or air at atmospheric pressure.

    PubMed

    Tsuji, Masaharu; Kawahara, Masashi; Noda, Kenji; Senda, Makoto; Sako, Hiroshi; Kamo, Naohiro; Kawahara, Takashi; Kamarudin, Khairul Sozana Nor

    2009-03-15

    Photochemical removal of NO(2) in N(2) or air (5-20% O(2)) mixtures was studied by using 172-nm Xe(2) excimer lamps to develop a new simple photochemical aftertreatment technique of NO(2) in air at atmospheric pressure without using any catalysts. When a high power lamp (300 mW/cm(2)) was used, the conversion of NO(2) (200-1000 ppm) to N(2) and O(2) in N(2) was >93% after 1 min irradiation, whereas that to N(2)O(5), HNO(3), N(2), and O(2) in air (10% O(2)) was 100% after 5s irradiation in a batch system. In a flow system, about 92% of NO(2) (200 ppm) in N(2) was converted to N(2) and O(2), whereas NO(2) (200-400 ppm) in air (20% O(2)) could be completely converted to N(2)O(5), HNO(3), N(2), and O(2) at a flow rate of 1l/min. It was found that NO could also be decomposed to N(2) and O(2) under 172-nm irradiation, though the removal rate is slower than that of NO(2) by a factor of 3.8. A simple model analysis assuming a consecutive reaction NO(2)-->NO-->N+O indicated that 86% of NO(2) is decomposed directly into N+O(2) and the rest is dissociated into NO+O under 172-nm irradiation. These results led us to conclude that the present technique is a new promising catalyst-free photochemical aftertreatment method of NO(2) in N(2) and air in a flow system.

  16. Impacts of South East Biomass Burning on local air quality in South China Sea

    NASA Astrophysics Data System (ADS)

    Wai-man Yeung, Irene; Fat Lam, Yun; Eniolu Morakinyo, Tobi

    2016-04-01

    Biomass burning is a significant source of carbon monoxide and particulate matter, which is not only contribute to the local air pollution, but also regional air pollution. This study investigated the impacts of biomass burning emissions from Southeast Asia (SEA) as well as its contribution to the local air pollution in East and South China Sea, including Hong Kong and Taiwan. Three years (2012 - 2014) of the Hybrid Single Particle Lagrangian-Integrated Trajectory (HYSPLIT) with particles dispersion analyses using NCEP (Final) Operational Global Analysis data (FNL) data (2012 - 2014) were analyzed to track down all possible long-range transport from SEA with a sinking motion that worsened the surface air quality (tropospheric downwash from the free troposphere). The major sources of SEA biomass burning emissions were first identified using high fire emissions from the Global Fire Emission Database (GFED), followed by the HYSPLIT backward trajectory dispersion modeling analysis. The analyses were compared with the local observation data from Tai Mo Shan (1,000 msl) and Tap Mun (60 msl) in Hong Kong, as well as the data from Lulin mountain (2,600 msl) in Taiwan, to assess the possible impacts of SEA biomass burning on local air quality. The correlation between long-range transport events from the particles dispersion results and locally observed air quality data indicated that the background concentrations of ozone, PM2.5 and PM10 at the surface stations were enhanced by 12 μg/m3, 4 μg/m3 and 7 μg/m3, respectively, while the long-range transport contributed to enhancements of 4 μg/m3, 4 μg/m3 and 8 μg/m3 for O3, PM2.5 and PM10, respectively at the lower free atmosphere.

  17. Operational prediction of air quality for the United States: applications of satellite observations

    NASA Astrophysics Data System (ADS)

    Stajner, Ivanka; Lee, Pius; Tong, Daniel; Pan, Li; McQueen, Jeff; Huang, Jianping; Huang, Ho-Chun; Draxler, Roland; Kondragunta, Shobha; Upadhayay, Sikchya

    2015-04-01

    Operational predictions of ozone and wildfire smoke over United States (U.S.) and predictions of airborne dust over the contiguous 48 states are provided by NOAA at http://airquality.weather.gov/. North American Mesoscale (NAM) weather predictions with inventory based emissions estimates from the U.S. Environmental Protection Agency (EPA) and chemical processes within the Community Multiscale Air Quality (CMAQ) model are combined together to produce ozone predictions. Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model is used to predict wildfire smoke and dust storm predictions. Routine verification of ozone predictions relies on AIRNow compilation of observations from surface monitors. Retrievals of smoke column integrals from GOES satellites and dust column integrals from MODIS satellite instruments are used for verification of smoke and dust predictions. Recent updates of NOAA's operational air quality predictions have focused on mobile emissions using the projections of mobile sources for 2012. Since emission inventories are complex and take years to assemble and evaluate causing a lag of information, we recently began combing inventory information with projections of mobile sources. In order to evaluate this emission update, these changes in projected NOx emissions from 2005-2012 were compared with observed changes in Ozone Monitoring Instrument (OMI) NO2 observations and NOx measured by surface monitors over large U.S. cities over the same period. Comparisons indicate that projected decreases in NOx emissions from 2005 to 2012 are similar, but not as strong as the decreases in the observed NOx concentrations and in OMI NO2 retrievals. Nevertheless, the use of projected mobile NOx emissions in the predictions reduced biases in predicted NOx concentrations, with the largest improvement in the urban areas. Ozone biases are reduced as well, with the largest improvement seen in rural areas. Recent testing of PM2.5 predictions is relying on

  18. Spectro-imaging observations of Jupiter's 2m auroral emission. I. H 3+ distribution and temperature

    NASA Astrophysics Data System (ADS)

    Raynaud, E.; Lellouch, E.; Maillard, J.-P.; Gladstone, G. R.; Waite, J. H.; Bézard, B.; Drossart, P.; Fouchet, T.

    2004-09-01

    We report on spectro-imaging infrared observations of Jupiter's auroral zones, acquired in October 1999 and October 2000 with the FTS/BEAR instrument at the Canada-France-Hawaii Telescope. The use of narrow-band filters at 2.09 and 2.12 μm, combined with high spectral resolution (0.2 cm -1), allowed us to map emission from the H 2S1(1) quadrupole line and from several H 3+ lines. The H 2 and H 3+ emission appears to be morphologically different, especially in the north, where the latter notably exhibits a "hot spot" near 150°-170° System III longitude. This hot spot coincides in position with the region of increased and variable hydrocarbon, FUV and X-ray emission, but is not seen in the more uniform H 2S1(1) emission. We also present the first images of the H 2 emission in the southern polar region. The spectra include a total of 14 H 3+ lines, including two hot lines from the 3 ν2- ν2 band, detected on Jupiter for the first time. They can be used to determine H 3+ column densities, rotational ( Trot) and vibrational ( Tvib) temperatures. We find the mean Tvib of the v2=3 state to be lower (960±50 K) than the mean Trot in v2=2 (1170±75 K), indicating an underpopulation of the v2=3 level with respect to local thermodynamical equilibrium. Rotational temperatures and associated column densities are generally higher and lower, respectively, than inferred previously from ν2 observations. This is a likely consequence of a large positive temperature gradient in the sub-microbar auroral atmosphere. While the signal-to-noise is not sufficient to take full advantage of the 2-D capabilities of the observations, the search for correlations between line intensities, Tvib and column densities, indicates that variations in line intensities are mostly due to correlated variations in the H 3+ column densities. The thermostatic role played by H 3+ at ionospheric levels may provide an explanation. The exception is the northern "hot spot," which exhibits a Tvib about 250 K

  19. An Observational and modeling strategy to investigate the impact of remote sources on local air quality: A Houston, Texas case study from the Second Texas Air Quality Study (TEXAQS II)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McMillan, W. W.; Pierce, R.; Sparling, L. C.

    2010-01-05

    Quantifying the impacts of remote sources on individual air quality exceedances remains a significant challenge for air quality forecasting. One goal of the 2006 Texas Air Quality Study (TEXAQS II) was to assess the impact of distant sources on air quality in east Texas. From 23-30 August 2006, retrievals of tropospheric carbon monoxide (CO) from NASA’s Atmospheric InfraRed Sounder (AIRS) reveal the transport of CO from fires in the United States Pacific Northwest to Houston, Texas. This transport occurred behind a cold front and contributed to the worst ozone exceedance period of the summer in the Houston area. We presentmore » supporting satellite observations from the NASA A-Train constellation of the vertical distribution of smoke aerosols and CO. Ground-based in situ CO measurements in Oklahoma and Texas track the CO plume as it moves south and indicate mixing of the aloft plume to the surface by turbulence in the nocturnal boundary layer and convection during the day. Ground-based aerosol speciation and lidar observations do not find appreciable smoke aerosol transport for this case. However, MODIS aerosol optical depths and model simulations indicate some smoke aerosols were transported from the Pacific Northwest through Texas to the Gulf of Mexico. Chemical transport and forward trajectory models confirm the three major observations: (1) the AIRS envisioned CO transport, (2) the satellite determined smoke plume height, and (3) the timing of the observed surface CO increases. Further, the forward trajectory simulations find two of the largest Pacific Northwest fires likely had the most significant impact.« less

  20. Spatio-temporal dynamics of biogeochemical processes and air-sea CO2 fluxes in the Western English Channel based on two years of FerryBox deployment

    NASA Astrophysics Data System (ADS)

    Marrec, P.; Cariou, T.; Latimier, M.; Macé, E.; Morin, P.; Vernet, M.; Bozec, Y.

    2014-12-01

    From January 2011 to January 2013, a FerryBox system was installed on a Voluntary Observing Ship (VOS), which crossed the Western English Channel (WEC) between Roscoff (France) and Plymouth (UK) up to 3 times a day. The FerryBox continuously measured sea surface temperature (SST), sea surface salinity (SSS), dissolved oxygen (DO), fluorescence and partial pressure of CO2 (from April 2012) along the ferry track. Sensors were calibrated based on 714 bimonthly surface samplings with precisions of 0.016 for SSS, 3.3 μM for DO, 0.40 μg L- 1 for Chlorophyll-a (Chl-a) (based on fluorescence measurements) and 5.2 μatm for pCO2. Over the 2 years of deployment (900 crossings), we reported 9% of data lost due to technical issues and quality checked data was obtained to allow investigation of the dynamics of biogeochemical processes related to air-sea CO2 fluxes in the WEC. Based on this unprecedented high-frequency dataset, the physical structure of the WEC was assessed using SST anomalies and the presence of a thermal front was observed around the latitude 49.5°N, which divided the WEC in two main provinces: the seasonally stratified northern WEC (nWEC) and the all-year well-mixed southern WEC (sWEC). These hydrographical properties strongly influenced the spatial and inter-annual distributions of phytoplankton blooms, which were mainly limited by nutrients and light availability in the nWEC and the sWEC, respectively. Air-sea CO2 fluxes were also highly related to hydrographical properties of the WEC between late April and early September 2012, with the sWEC a weak source of CO2 to the atmosphere of 0.9 mmol m- 2 d- 1, whereas the nWEC acted as a sink for atmospheric CO2 of 6.9 mmol m- 2 d- 1. The study of short time-scale dynamics of air-sea CO2 fluxes revealed that an intense and short (less than 10 days) summer bloom in the nWEC contributed to 29% of the CO2 sink during the productive period, highlighting the necessity for high frequency observations in coastal

  1. Changes in SO2 and NO2 Pollution over the Past Decade Observed by Aura OMI

    NASA Astrophysics Data System (ADS)

    Krotkov, N. A.; Li, C.; Lamsal, L. N.; Celarier, E. A.; Marchenko, S. V.; Swartz, W.; Bucsela, E. J.; Fioletov, V.; McLinden, C. A.; Joiner, J.; Bhartia, P. K.; Duncan, B. N.; Dickerson, R. R.

    2014-12-01

    The Ozone Monitoring Instrument (OMI), a NASA partnership with the Netherlands and Finland, flies on the EOS Aura satellite and uses reflected sunlight to measure two critical atmospheric trace gases, nitrogen dioxide (NO2) and sulfur dioxide (SO2), characterizing daily air quality. Both gases and the secondary pollutants they produce (particulate matter, PM2.5, and tropospheric ozone) are among USEPA designated criteria pollutants, posing serious threats to human health and the environment (e.g., acid rain, plant damage, and reduced visibility). A new generation of the OMI standard SO2 and NO2 products (based on critically improved DOAS spectral fitting for NO2 and innovative Principal Component Analysis method for SO2) provides a valuable dataset for studying anthropogenic pollution on local to global scales. Here we highlight some of the OMI observed long-term changes in air quality over several regions. Over the US, average NO2 and SO2 pollution levels have decreased dramatically as a result of both technological improvements (e.g., catalytic converters on cars) and stricter regulations of emissions. We see continued decline in NO2 and SO2 pollution over Europe. Over China OMI observed a ~ 60% increase in NO2 pollution between 2005 and 2013, despite a temporary reversal of the growing trend due to both 2008 Olympic Games and the economic recession in 2009. Chinese SO2 pollution seems to have stabilized since peaking in 2007, probably due to government efforts to curb SO2 emissions from the power sector. We have also observed large increases in both SO2 and NO2 pollution particularly in Eastern India where a number of new large coal power plants have been built in recent years. We expect that further improvements in the OMI NO2 and SO2 products will allow more robust quantification of long-term trends in local to global air quality.

  2. Internal steel structure of M2-F1

    NASA Technical Reports Server (NTRS)

    1963-01-01

    The internal steel structure for the M2-F1 was built at the Flight Research Center (predecessor of the Dryden Flight Research Center, Edwards, CA) in a section of the calibration hangar dubbed 'Wright Bicycle Shop.' Visible are the stick, rudder pedals, and ejection seat. The external wooden shell was attached to the steel structure. The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and racing slicks, the Pontiac could tow the 1,000-pound M2-F1 110 miles per hour in 30 seconds. It proved adequate for the roughly 400 car tows that got the M2-F1 airborne to prove it could fly

  3. Assessment of indoor air quality at an electronic cigarette (Vaping) convention.

    PubMed

    Chen, Rui; Aherrera, Angela; Isichei, Chineye; Olmedo, Pablo; Jarmul, Stephanie; Cohen, Joanna E; Navas-Acien, Ana; Rule, Ana M

    2017-12-29

    E-cigarette (vaping) conventions are public events promoting electronic cigarettes, in which indoor use of e-cigarettes is allowed. The large concentration of people using e-cigarettes and poor air ventilation can result in indoor air pollution. In order to estimate this worst-case exposure to e-cigarettes, we evaluated indoor air quality in a vaping convention in Maryland (MD), USA. Real-time concentrations of particulate matter (PM 10 ) and real-time total volatile organic compounds (TVOCs), CO 2 and NO 2 concentrations were measured. Integrated samples of air nicotine and PM 10 concentrations were also collected. The number of attendees was estimated to range from 75 to 600 at any single observation time. The estimated 24-h time-weighted average (TWA) PM 10 was 1800 μg/m 3 , 12-fold higher than the EPA 24-h regulation (150 μg/m 3 ). Median (range) indoor TVOCs concentration was 0.13 (0.04-0.3) ppm. PM 10 and TVOC concentrations were highly correlated with CO 2 concentrations, indicating the high number of people using e-cigarettes and poor indoor air quality. Air nicotine concentration was 125 μg/m 3 , equivalent to concentrations measured in bars and nightclubs. E-cigarette aerosol in a vaping convention that congregates many e-cigarette users is a major source of PM 10 , air nicotine and VOCs, impairing indoor air quality. These findings also raise occupational concerns for e-cigarette vendors and other venue staff workers.

  4. Observed characteristics of dust storm events over the western United States using meteorological, satellite, and air quality measurements

    NASA Astrophysics Data System (ADS)

    Lei, H.; Wang, J. X. L.

    2014-08-01

    To improve dust storm identification over the western United States, historical dust events measured by air quality and satellite observations are analyzed based on their characteristics in data sets of regular meteorology, satellite-based aerosol optical depth (AOD), and air quality measurements. Based on the prevailing weather conditions associated with dust emission, dust storm events are classified into the following four typical types: (1) The key feature of cold front-induced dust storms is their rapid process with strong dust emissions. (2) Events caused by meso- to small-scale weather systems have the highest levels of emissions. (3) Dust storms caused by tropical disturbances show a stronger air concentration of dust and last longer than those in (1) and (2). (4) Dust storms triggered by cyclogenesis last the longest. In this paper, sample events of each type are selected and examined to explore characteristics observed from in situ and remote-sensing measurements. These characteristics include the lasting period, surface wind speeds, areas affected, average loading on ground-based optical and/or air quality measurements, peak loading on ground-based optical and/or air quality measurements, and loading on satellite-based aerosol optical depth. Based on these analyses, we compare the characteristics of the same dust events captured in different data sets in order to define the dust identification criteria. The analyses show that the variability in mass concentrations captured by in situ measurements is consistent with the variability in AOD from stationary and satellite observations. Our analyses also find that different data sets are capable of identifying certain common characteristics, while each data set also provides specific information about a dust storm event. For example, the meteorological data are good at identifying the lasting period and area impacted by a dust event; the ground-based air quality and optical measurements can capture the peak

  5. VO2 attained during treadmill running: the influence of a specialist (400-m or 800-m) event.

    PubMed

    James, David V B; Sandals, Leigh E; Draper, Stephen B; Maldonado-Martin, Sara; Wood, Dan M

    2007-06-01

    Previously it has been observed that, in well-trained 800-m athletes, VO2max is not attained during middle-distance running events on a treadmill, even when a race-type pacing strategy is adopted. Therefore, the authors investigated whether specialization in a particular running distance (400-m or 800-m) influences the VO2 attained during running on a treadmill. Six 400-m and six 800-m running specialists participated in the study.A 400-m trial and a progressive test to determine VO2max were completed in a counterbalanced order. Oxygen uptakes attained during the 400-m trial were compared to examine the influence of specialist event. A VO2 plateau was observed in all participants for the progressive test, demonstrating the attainment of VO2max. The VO2max values were 56.2 +/- 4.7 and 69.3 +/- 4.5 mL x kg-1 x min-1 for the 400-m- and 800-m-event specialists, respectively (P = .0003). Durations for the 400-m trial were 55.1 +/- 4.2 s and 55.8 +/- 2.3 s for the 400-m- and 800-m-event specialists, respectively. The VO2 responses achieved were 93.1% +/- 2.0% and 85.7% +/- 3.0% VO2max for the 400-m- and 800-m-event specialists, respectively (P = .001). These results demonstrate that specialist running events do appear to influence the percentage of VO2max achieved in the 400-m trial, with the 800-m specialists attaining a lower percentage of VO2max than the 400-m specialists. The 400-m specialists appear to compensate for a lower VO2max by attaining a higher percentage VO2max during a 400-m trial.

  6. Temporal distribution of air quality related to meteorology and road traffic in Madrid.

    PubMed

    Perez-Martinez, Pedro J; Miranda, Regina M

    2015-04-01

    The impact of climatology--air temperature, precipitation and wind speed--and road traffic--volume, vehicle speed and percentage of heavy-duty vehicles (HDVs)--on air quality in Madrid was studied by estimating the effect for each explanatory variable using generalized linear regression models controlling for monthly variations, days of week and parameter levels. Every 1 m/s increase in wind speed produced a decrease in PM10 concentrations by 10.3% (95% CI 12.6-8.6) for all weekdays and by 12.4% (95% CI 14.9-9.8) for working days (up to the cut-off of 2.4 m/s). Increases of PM10 concentrations due to air temperature (7.2% (95% CI 6.2-8.3)) and traffic volume (3.3% (95% CI 2.9-3.8)) were observed at every 10 °C and 1 million vehicle-km increases for all weekdays; oppositely, slight decreases of PM10 concentrations due to percentage of HDVs (3.2% (95% CI 2.7-3.7)) and vehicle speed (0.7% (95% CI 0.6-0.8)) were observed at every 1% and 1 km/h increases. Stronger effects of climatology on air quality than traffic parameters were found.

  7. Aerosol properties associated with air masses arriving into the North East Atlantic during the 2008 Mace Head EUCAARI intensive observing period: an overview

    NASA Astrophysics Data System (ADS)

    Dall'Osto, M.; Ceburnis, D.; Martucci, G.; Bialek, J.; Dupuy, R.; Jennings, S. G.; Berresheim, H.; Wenger, J. C.; Sodeau, J. R.; Healy, R. M.; Facchini, M. C.; Rinaldi, M.; Giulianelli, L.; Finessi, E.; Worsnop, D.; O'Dowd, C. D.

    2009-12-01

    As part of the EUCAARI Intensive Observing Period, a 4-week campaign to measure aerosol physical, chemical and optical properties, atmospheric structure, and cloud microphysics was conducted from mid-May to mid-June 2008 at the Mace Head Atmospheric Research Station, located at the interface of Western Europe and the NE Atlantic and centered on the west Irish coastline. During the campaign, continental air masses comprising both young and aged continental plumes were encountered, along with polar, Arctic and tropical air masses. Polluted-continental aerosol concentrations were of the order of 3000 cm-3, while background marine air aerosol concentrations were between 400-600 cm-3. The highest marine air concentrations occurred in polar air masses in which a 15 nm nucleation mode, with concentration of 1100 cm-3, was observed and attributed to open ocean particle formation. Black carbon concentrations in polluted air were between 300-400 ng m-3, and in clean marine air were less than 50 ng m-3. Continental air submicron chemical composition (excluding refractory sea salt) was dominated by organic matter, closely followed by sulphate mass. Although the concentrations and size distribution spectral shape were almost identical for the young and aged continental cases, hygroscopic growth factors (GF) and cloud condensation nuclei (CCN) to total condensation nuclei (CN) concentration ratios were significantly less in the younger pollution plume, indicating a more oxidized organic component to the aged continental plume. The difference in chemical composition and hygroscopic growth factor appear to result in a 40-50% impact on aerosol scattering coefficients and Aerosol Optical Depth, despite almost identical aerosol microphysical properties in both cases, with the higher values been recorded for the more aged case. For the CCN/CN ratio, the highest ratios were seen in the more age plume. In marine air, sulphate mass dominated the sub-micron component, followed by water

  8. Chandra Observations of the M31

    NASA Technical Reports Server (NTRS)

    Garcia, Michael; Lavoie, Anthony R. (Technical Monitor)

    2000-01-01

    We report on Chandra observations of the nearest Spiral Galaxy, M3l, The nuclear source seen with previous X-ray observatories is resolved into five point sources. One of these sources is within 1 arc-sec of the M31 central super-massive black hole. As compared to the other point sources in M3l. this nuclear source has an unusually soft spectrum. Based on the spatial coincidence and the unusual spectrum. we identify this source with the central black hole. A bright transient is detected 26 arc-sec to the west of the nucleus, which may be associated with a stellar mass black hole. We will report on a comparison of the x-ray spectrum of the diffuse emission and point sources seen in the central few arcmin

  9. Carbachol induces Ca(2+)-dependent contraction via muscarinic M2 and M3 receptors in rat intestinal subepithelial myofibroblasts.

    PubMed

    Iwanaga, Koichi; Murata, Takahisa; Okada, Muneyoshi; Hori, Masatoshi; Ozaki, Hiroshi

    2009-07-01

    Intestinal myofibroblasts (IMFs) that exist adjacent to the basement membrane of intestines have contractility and contribute to physical barriers of the intestine. Nerve endings distribute adjacent to IMFs, suggesting neurotransmitters may influence IMFs motility; however, there is no direct evidence showing the interaction. Here, we isolated IMFs from rat colon and investigated the effect of acetylcholine on IMFs contractility. In the collagen gel contraction assay, carbachol (1 - 10 microM) and the muscarinic receptor agonist bethanechol (30 - 300 microM) dose-dependently induced IMFs contraction. Pretreatment with the muscarinic receptor antagonist atropine (1 - 10 nM) inhibited carbachol-induced contraction. In RT-PCR, mRNA expression of all muscarinic receptor subtypes (M(1) - M(5)) was detected in IMFs. Subsequently we found pretreatment with the muscarinic M(2) receptor antagonist 11-([2-[(diethylamino)methyl]-1-piperdinyl]acetyl)-5,11-dihydro-6H-pyrido[2,3-b][1,4]benzodiazepine-6-one (AF-DX116) (10 and 30 nM) or the muscarinic M(3) receptor antagonist 4-diphenylacetoxy-N-methyl-piperidine (4-DAMP) (3 and 10 nM) dose-dependently inhibited carbachol-induced contraction. In Ca(2+) measurement, 1 - 10 microM carbachol and 30 - 300 microM bethanechol elevated the intracellular Ca(2+) concentration ([Ca(2+)](i)) in IMFs. Atropine (10 nM) eliminated carbachol-induced [Ca(2+)](i) elevation. The Ca(2+)-channel blocker LaCl(3) (3 microM) abolished carbachol-induced [Ca(2+)](i) elevation and contraction. Furthermore, AF-DX116 and 4-DAMP dose-dependently inhibited the carbachol-induced [Ca(2+)](i) elevation. These observations suggest that acetylcholine elicits Ca(2+)-dependent IMF contraction through muscarinic M(2) and M(3) receptors.

  10. The BErkeley Atmospheric CO2 Observation Network: field calibration and evaluation of low-cost air quality sensors

    NASA Astrophysics Data System (ADS)

    Kim, Jinsol; Shusterman, Alexis A.; Lieschke, Kaitlyn J.; Newman, Catherine; Cohen, Ronald C.

    2018-04-01

    The newest generation of air quality sensors is small, low cost, and easy to deploy. These sensors are an attractive option for developing dense observation networks in support of regulatory activities and scientific research. They are also of interest for use by individuals to characterize their home environment and for citizen science. However, these sensors are difficult to interpret. Although some have an approximately linear response to the target analyte, that response may vary with time, temperature, and/or humidity, and the cross-sensitivity to non-target analytes can be large enough to be confounding. Standard approaches to calibration that are sufficient to account for these variations require a quantity of equipment and labor that negates the attractiveness of the sensors' low cost. Here we describe a novel calibration strategy for a set of sensors, including CO, NO, NO2, and O3, that makes use of (1) multiple co-located sensors, (2) a priori knowledge about the chemistry of NO, NO2, and O3, (3) an estimate of mean emission factors for CO, and (4) the global background of CO. The strategy requires one or more well calibrated anchor points within the network domain, but it does not require direct calibration of any of the individual low-cost sensors. The procedure nonetheless accounts for temperature and drift, in both the sensitivity and zero offset. We demonstrate this calibration on a subset of the sensors comprising BEACO2N, a distributed network of approximately 50 sensor nodes, each measuring CO2, CO, NO, NO2, O3 and particulate matter at 10 s time resolution and approximately 2 km spacing within the San Francisco Bay Area.

  11. Aura OMI Observations of Global SO2 and NO2 Pollution from 2005 to 2013

    NASA Technical Reports Server (NTRS)

    Krotkov, Nickolay; Li, Can; Lamsal, Lok; Celarier, Edward; Marchenko, Sergey; Swartz, William H.; Bucsela, Eric; Fioletov, Vitali; McLinden, Chris; Joiner, Joanna; hide

    2014-01-01

    The Ozone Monitoring Instrument (OMI), a NASA partnership with the Netherlands and Finland, flies on the NASA Aura satellite and uses reflected sunlight to measure the two critical atmospheric trace gases: nitrogen dioxide (NO2) and sulfur dioxide (SO2) characterizing daily air quality. Both gases and the secondary pollutants they produce (particulate matter, PM2.5, and tropospheric ozone) are USEPA designated criteria pollutants, posing serious threats to human health and the environment (e.g., acid rain, plant damage and reduced visibility). Our group at NASA GSFC has developed and maintained OMI standard SO2 and NO2 data products. We have recently released an updated version of the standard NO2 L2 and L3 products (SP v2.1) and continue improving the algorithm. We are currently in the process of releasing next generation pollution SO2 product, based on an innovative Principal Component Analysis (PCA) algorithm, which greatly reduces the noise and biases. These new standard products provide valuable datasets for studying anthropogenic pollution on local to global scales. Here we highlight some of the OMI observed changes in air quality over several regions. Over the US average NO2 and SO2 pollution levels had decreased dramatically as a result of both technological improvements (e.g., catalytic converters on cars) and stricter regulations of emissions. We see continued decline in pollution over Europe. Over China OMI observed an increase of about 60 percent in NO2 pollution between 2005 and 2013, despite a temporal reversal of the growing trend due to both 2008 Olympic Games and the economic recession in 2009. Chinese SO2 pollution seems to have stabilized since peaking in 2007, probably due to government efforts to curb SO2 emissions from the power sector. We have also observed large increases in both SO2 and NO2 pollution particularly in Eastern India where a number of large new coal power plants had been built in recent years. We expect that further

  12. Dynamics of air-sea CO2 fluxes based on FerryBox measurements and satellite-based prediction of pCO2 in the Western English Channel

    NASA Astrophysics Data System (ADS)

    Marrec, Pierre; Thierry, Cariou; Eric, Mace; Pascal, Morin; Marc, Vernet; Yann, Bozec

    2014-05-01

    Since April 2012, we installed an autonomous FerryBox system on a Voluntary Observing Ship (VOS), which crosses the Western English Channel (WEC) between Roscoff and Plymouth on a daily basis. High-frequency data of sea surface temperature (SST), salinity (SSS), fluorescence, dissolved oxygen (DO) and partial pressure of CO2 (pCO2) were recorded for two years across the all-year mixed southern WEC (sWEC) and the seasonally stratified northern WEC (nWEC). These contrasting hydrographical provinces strongly influenced the spatio-temporal distributions of pCO2 and air-sea CO2 fluxes. During the productive period (from May to September), the nWEC acted as a sink for atmospheric CO2 of -5.6 mmolC m-2 d-1 and -4.6 mmolC m-2 d-1, in 2012 and 2013, respectively. During the same period, the sWEC showed significant inter-annual variability degassing CO2 to the atmosphere in 2012 (1.4 mmolC m-2 d-1) and absorbing atmospheric CO2 in 2013 (-1.6 mmolC m-2 d-1). In 2012, high-frequency data revealed that an intense and short (less than 10 days) summer phytoplankton bloom in the nWEC contributed to 31% of the total CO2 drawdown during the productive period, highlighting the necessity of pCO2 high-frequency measurements in coastal ecosystems. Based on this multi-annual dataset, we developed pCO2 algorithms using multiple linear regression (MLR) based on SST, SSS, chlorophyll-a (Chl-a) concentration, time, latitude and mixed layer depth to predict pCO2 in the two hydrographical provinces of the WEC. MLR were performed based on more than 200,000 underway observations spanning the range from 150 to 480 µatm. The root mean square errors (RMSE) of the MLR fit to the data were 17.2 µatm and 21.5 µatm for the s WEC and the nWEC with correlation coefficient (r²) of 0.71 and 0.79, respectively. We applied these algorithms to satellite SST and Chl-a products and to modeled SSS estimates in the entire WEC. Based on these high-frequency and satellite approaches, we will discuss the main

  13. An Experiment with Air Purifiers in Delhi during Winter 2015-2016

    PubMed Central

    Vyas, Sangita

    2016-01-01

    Particulate pollution has important consequences for human health, and is an issue of global concern. Outdoor air pollution has become a cause for alarm in India in particular because recent data suggest that ambient pollution levels in Indian cities are some of the highest in the world. We study the number of particles between 0.5μm and 2.5μm indoors while using affordable air purifiers in the highly polluted city of Delhi. Though substantial reductions in indoor number concentrations are observed during air purifier use, indoor air quality while using an air purifier is frequently worse than in cities with moderate pollution, and often worse than levels observed even in polluted cities. When outdoor pollution levels are higher, on average, indoor pollution levels while using an air purifier are also higher. Moreover, the ratio of indoor air quality during air purifier use to two comparison measures of air quality without an air purifier are also positively correlated with outdoor pollution levels, suggesting that as ambient air quality worsens there are diminishing returns to improvements in indoor air quality during air purifier use. The findings of this study indicate that although the most affordable air purifiers currently available are associated with significant improvements in the indoor environment, they are not a replacement for public action in regions like Delhi. Although private solutions may serve as a stopgap, reducing ambient air pollution must be a public health and policy priority in any region where air pollution is as high as Delhi’s during the winter. PMID:27978542

  14. H2 Fluorescence in M Dwarf Systems: A Stellar Origin

    NASA Astrophysics Data System (ADS)

    Kruczek, Nicholas; France, Kevin; Evonosky, William; Loyd, R. O. Parke; Youngblood, Allison; Roberge, Aki; Wittenmyer, Robert A.; Stocke, John T.; Fleming, Brian; Hoadley, Keri

    2017-08-01

    Observations of molecular hydrogen (H2) fluorescence are a potentially useful tool for measuring the H2 abundance in exoplanet atmospheres. This emission was previously observed in {{M}} dwarfs with planetary systems. However, low signal-to-noise prevented a conclusive determination of its origin. Possible sources include exoplanetary atmospheres, circumstellar gas disks, and the stellar surface. We use observations from the “Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanet Host Stars” Treasury Survey to study H2 fluorescence in {{M}} dwarfs. We detect fluorescence in Hubble Space Telescope spectra of 8/9 planet-hosting and 5/6 non-planet-hosting {{M}} dwarfs. The detection statistics, velocity centroids, and line widths of the emission suggest a stellar origin. We calculate H2-to-stellar-ion flux ratios to compare flux levels between stars. For stars with planets, we find an average ratio of 1.7+/- 0.9, using the fluxes of the brightest H2 feature and two stellar C IV lines. This is compared to 0.9+/- 0.4 for stars without planets, showing that the planet-hosting {{M}} dwarfs do not have significant excess H2 emission. This claim is supported by the direct FUV imaging of GJ 832, where no fluorescence is observed at the expected star-planet separation. Additionally, the 3σ upper limit of 4.9 × 10-17 erg cm-2 s-1 from these observations is two orders of magnitude below the spectroscopically observed H2 flux. We constrain the location of the fluorescing H2 using 1D radiative transfer models, and find that it could reside in starspots or a ˜2500-3000 {{K}} region in the lower chromosphere. The presence of this emission could complicate efforts to quantify the atmospheric abundance of H2 in exoplanets orbiting {{M}} dwarfs.

  15. OCO-2 Observation and Validation Overview: Observations Data Modes and Target Observations, Taken During the First 15 Months of Operations

    NASA Astrophysics Data System (ADS)

    Osterman, G. B.; Fisher, B.; Wunch, D.; Eldering, A.; Wennberg, P. O.; Roehl, C. M.; Naylor, B. J.; Lee, R.; Pollock, R.; Gunson, M. R.

    2015-12-01

    The OCO-2 instrument was successfully launched on July 2, 2014 from Vandenberg Air Force Base in California. The instrument reached its observational orbit about three weeks later. The spacecraft is at the head of the A-train satellites and began collecting operational data on Sept 5, 2014. OCO-2 makes measurements in three modes: nadir, glint and target. Target observations are designed to provide large amounts of data in a small area near a ground validation site. The instruments of the Total Carbon Column Observing Network (TCCON) provide the ground validation data for the OCO-2 XCO2 observations and comparisons to TCCON form the basis of the OCO-2 validation plan. There are now 27 locations at which OCO-2 can perform target observations and CCON sites make up 23 of those possible target locations. For its first year in orbit, OCO-2 operated in nadir mode for 16 days and then in glint mode for 16 days. Each 16-day cycle spans 233 orbits. On July 1, 2015, OCO-2 changed to an observational mode of alternating nadir and glint measurements on an orbit-by-orbit basis. By December 2015, this operational mode may be modified such that orbits that measure only over ocean will always observed in glint mode. In this presentation we will provide information on the observations made by OCO-2 during its first 15 month in operations. We will show maps of the OCO-2 ground tracks and XCO2 data, calendars illustrating the observational schedule and statistics on the target observations taken. We will provide more information on what is involved in making target observations and how it affects the standard operational data acquisition patterns. Changes to the standard observational patterns of OCO-2 and to the list of locations for target observations will be discussed as well. We will provide an overview of some of the validation related analysis being done using nadir and glint mode OCO-2 data in addition to an overview on validation analyses that do not directly utilize TCCON

  16. M2-F2 Lifting Body being Carried Aloft by B-52 Mothership

    NASA Technical Reports Server (NTRS)

    1966-01-01

    The M2-F2 Lifting Body is shown here being carried aloft by the Air Force's B-52 (tail number 003) prior to a research launch. The success of Dryden's 'homebuilt' M2-F1 program led to NASA's development and construction of two heavyweight lifting bodies--the M2-F2 and the HL-10, both built by the Northrop Corporation. The 'M' refers to 'manned' and 'F' refers to 'flight' version. 'HL' comes from 'horizontal landing.' The first flight of the M2-F2--which looked much like the 'F1'--was on July 12, 1966. Milt Thompson was the pilot. NASA B-52, Tail Number 008, is an air launch carrier aircraft, 'mothership,' as well as a research aircraft platform that has been used on a variety of research projects. The aircraft, a 'B' model built in 1952 and first flown on June 11, 1955, is the oldest B-52 in flying status and has been used on some of the most significant research projects in aerospace history. Some of the significant projects supported by B-52 008 include the X-15, the lifting bodies, HiMAT (highly maneuverable aircraft technology), Pegasus, validation of parachute systems developed for the space shuttle program (solid-rocket-booster recovery system and the orbiter drag chute system), and the X-38. The B-52 served as the launch vehicle on 106 X-15 flights and flew a total of 159 captive-carry and launch missions in support of that program from June 1959 to October 1968. Information gained from the highly successful X-15 program contributed to the Mercury, Gemini, and Apollo human spaceflight programs as well as space shuttle development. Between 1966 and 1975, the B-52 served as the launch aircraft for 127 of the 144 wingless lifting body flights. In the 1970s and 1980s, the B-52 was the launch aircraft for several aircraft at what is now the Dryden Flight Research Center, Edwards, California, to study spin-stall, high-angle-of attack, and maneuvering characteristics. These included the 3/8-scale F-15/spin research vehicle (SRV), the HiMAT (Highly Maneuverable

  17. Comparison of three distinct surgical clothing systems for protection from air-borne bacteria: A prospective observational study

    PubMed Central

    2012-01-01

    Background To prevent surgical site infection it is desirable to keep bacterial counts low in the operating room air during orthopaedic surgery, especially prosthetic surgery. As the air-borne bacteria are mainly derived from the skin flora of the personnel present in the operating room a reduction could be achieved by using a clothing system for staff made from a material fulfilling the requirements in the standard EN 13795. The aim of this study was to compare the protective capacity between three clothing systems made of different materials – one mixed cotton/polyester and two polyesters - which all had passed the tests according to EN 13795. Methods Measuring of CFU/m3 air was performed during 21 orthopaedic procedures performed in four operating rooms with turbulent, mixing ventilation with air flows of 755 – 1,050 L/s. All staff in the operating room wore clothes made from the same material during each surgical procedure. Results The source strength (mean value of CFU emitted from one person per second) calculated for the three garments were 4.1, 2.4 and 0.6 respectively. In an operating room with an air flow of 755 L/s both clothing systems made of polyester reduced the amount of CFU/m3 significantly compared to the clothing system made from mixed material. In an operating room with air intake of 1,050 L/s a significant reduction was only achieved with the polyester that had the lowest source strength. Conclusions Polyester has a better protective capacity than cotton/polyester. There is need for more discriminating tests of the protective efficacy of textile materials intended to use for operating garment. PMID:23068884

  18. Effects of commercial air travel on patients with pulmonary hypertension air travel and pulmonary hypertension.

    PubMed

    Roubinian, Nareg; Elliott, C Gregory; Barnett, Christopher F; Blanc, Paul D; Chen, Joan; De Marco, Teresa; Chen, Hubert

    2012-10-01

    Limited data are available on the effects of air travel in patients with pulmonary hypertension (PH), despite their risk of physiologic compromise. We sought to quantify the incidence and severity of hypoxemia experienced by people with PH during commercial air travel. We recruited 34 participants for a prospective observational study during which cabin pressure, oxygen saturation (Sp O 2 ), heart rate, and symptoms were documented serially at multiple predefined time points throughout commercial flights. Oxygen desaturation was defined as SpO2, <85%. Median flight duration was 3.6 h (range, 1.0-7.3 h). Mean ± SD cabin pressure at cruising altitude was equivalent to the pressure 1,968 ± 371 m (6,456 ± 1,218 ft) above sea level (ASL)(maximum altitude 5 2,621 m [8,600 ft] ASL). Median change in Sp O 2 from sea level to cruising altitude was 2 4.9% (range, 2.0% to 2 15.8%). Nine subjects (26% [95% CI, 12%-38%]) experienced oxygen desaturation during flight (minimum Sp O 2 5 74%). Thirteen subjects (38%) reported symptoms during flight, of whom five also experienced desaturations. Oxygen desaturation was associated with cabin pressures equivalent to . 1,829 m (6,000 ft) ASL, ambulation, and flight duration(all P values , .05). Hypoxemia is common among people with PH traveling by air, occurring in one in four people studied. Hypoxemia was associated with lower cabin pressures, ambulation during flight, and longer flight duration. Patients with PH who will be traveling on flights of longer duration or who have a history of oxygen use, including nocturnal use only, should be evaluated for supplemental in-flight oxygen.

  19. Traffic-Related Air Pollution and Childhood Acute Leukemia in Oklahoma

    PubMed Central

    Janitz, Amanda E.; Campbell, Janis E.; Magzamen, Sheryl; Pate, Anne; Stoner, Julie A.; Peck, Jennifer D.

    2016-01-01

    Background While many studies have evaluated the association between acute childhood leukemia and environmental factors, knowledge is limited. Ambient air pollution has been classified as a Group 1 carcinogen, but studies have not established whether traffic-related air pollution is associated with leukemia. The goal of our study was to determine if children with acute leukemia had higher odds of exposure to traffic-related air pollution at birth compared to controls. Methods We conducted a case-control study using the Oklahoma Central Cancer Registry to identify cases of acute leukemia in children diagnosed before 20 years of age between 1997 and 2012 (n=307). Controls were selected from birth certificates and matched to cases on week of birth (n=1,013). Using a novel satellite-based land-use regression model of nitrogen dioxide (NO2) and estimating road density based on the 2010 US Census, we evaluated the association between traffic-related air pollution and childhood leukemia using conditional logistic regression. Results The odds of exposure to the fourth quartile of NO2 (11.19–19.89 ppb) were similar in cases compared to controls after adjustment for maternal education (OR: 1.08, 95% CI: 0.75, 1.55). These estimates were stronger among children with acute myeloid leukemia (AML) than acute lymphoid leukemia, with a positive association observed among urban children with AML (4th quartile odds ratio: 5.25, 95% confidence interval: 1.09, 25.26). While we observed no significant association with road density, male cases had an elevated odds of exposure to roads at 500 m from the birth residence compared to controls (OR: 1.39, 95% CI: 0.93, 2.10), which was slightly attenuated at 750 m. Conclusions Although we observed no association overall between NO2 or road density, this was the first study to observe an elevated odds of exposure to NO2 among children with AML compared to controls suggesting further exploration of traffic-related air pollution and AML is

  20. Observations and modeling of air quality trends over 1990-2010 across the Northern Hemisphere: China, the United States and Europe

    NASA Astrophysics Data System (ADS)

    Xing, J.; Mathur, R.; Pleim, J.; Hogrefe, C.; Gan, C.-M.; Wong, D. C.; Wei, C.; Gilliam, R.; Pouliot, G.

    2015-03-01

    Trends in air quality across the Northern Hemisphere over a 21-year period (1990-2010) were simulated using the Community Multiscale Air Quality (CMAQ) multiscale chemical transport model driven by meteorology from Weather Research and Forecasting (WRF) simulations and internally consistent historical emission inventories obtained from EDGAR. Thorough comparison with several ground observation networks mostly over Europe and North America was conducted to evaluate the model performance as well as the ability of CMAQ to reproduce the observed trends in air quality over the past 2 decades in three regions: eastern China, the continental United States and Europe. The model successfully reproduced the observed decreasing trends in SO2, NO2, 8 h O3 maxima, SO42- and elemental carbon (EC) in the US and Europe. However, the model fails to reproduce the decreasing trends in NO3- in the US, potentially pointing to uncertainties of NH3 emissions. The model failed to capture the 6-year trends of SO2 and NO2 in CN-API (China - Air Pollution Index) from 2005 to 2010, but reproduced the observed pattern of O3 trends shown in three World Data Centre for Greenhouse Gases (WDCGG) sites over eastern Asia. Due to the coarse spatial resolution employed in these calculations, predicted SO2 and NO2 concentrations are underestimated relative to all urban networks, i.e., US-AQS (US - Air Quality System; normalized mean bias (NMB) = -38% and -48%), EU-AIRBASE (European Air quality data Base; NMB = -18 and -54%) and CN-API (NMB = -36 and -68%). Conversely, at the rural network EU-EMEP (European Monitoring and Evaluation Programme), SO2 is overestimated (NMB from 4 to 150%) while NO2 is simulated well (NMB within ±15%) in all seasons. Correlations between simulated and observed O3 wintertime daily 8 h maxima (DM8) are poor compared to other seasons for all networks. Better correlation between simulated and observed SO42- was found compared to that for SO2. Underestimation of summer SO42- in

  1. Satellite-Derived NO2 as an Indicator of Urban Air Quality and Emissions

    NASA Astrophysics Data System (ADS)

    Holloway, T.; Penn, E.; Harkey, M.

    2016-12-01

    Nitrogen dioxide (NO2) is the satellite-derived constituent with the most direct connection to fossil fuel emissions. At present the Ozone Monitoring Instrument aboard the NASA Aura satellite offers the highest resolution NO2retrievals, and new missions under development (TropOMI, TEMPO, GEMS, Sentinel-4) offer the potential for improved data in coming years. We present results applying satellite-derived NO2data to characterize air quality and emissions in U.S. cities. We highlight research findings geared toward increasing the relevance of satellite data to evaluate urban-scale air quality issues. This work reflects activities under the NASA Air Quality Applied Sciences Team (AQAST), and emerging work under the NASA Health and Air Quality Applied Sciences Team (H-AQAST). Among our results is a characterization of the diurnal cycle of nitrogen oxides using ground-based observations and satellite data. In situ monitoring from the U.S. EPA Air Quality System (AQS) shows that most locations have two daily peaks in NO2 (morning and evening) and a single daily peak in NO (morning). Spaced-based observations from the ESA Global Ozone Monitoring Experiment-2 (GOME-2), with a mid-morning overpass, and the NASA OMI, with an early afternoon overpass, support a complementary analysis for characterizing diurnal variability in NO2. Both ground-based monitors and satellite data show a reduction in the amplitude of the diurnal NO2 cycle. In the Western U.S., satellite data showed evidence of higher NO2 in urban centers in the afternoon (OMI) and higher NO2 in suburban areas in the morning (GOME-2), consistent with diurnal traffic patterns associated with commuting. Some power plants in the Western U.S. showed an increase in NO2in the afternoon, consistent with peak power demand associated with building air conditioning use. We extend this city-focused analysis satellite-derived HCHO:NO2 ratios as an indicator of ozone production regime, comparing modeled and measured ratios

  2. Aerosol Optical Depth over Europe: Evaluation of the CALIOPE air quality modelling system with direct-sun AERONET observations

    NASA Astrophysics Data System (ADS)

    Basart, Sara; Pay, María. Teresa; Pérez, Carlos; Cuevas, Emilio; Jorba, Oriol; Piot, Matthias; María Baldasano, Jose

    2010-05-01

    probability of detection) of AOD when using CMAQ+DREAM8b compared to CMAQ-alone simulations. An accurate analysis of the relative contributions of anthropogenic aerosols and desert dust to AOD over Europe and their seasonality will be also presented. References: Baldasano J.M, P. Jiménez-Guerrero, O. Jorba, C. Pérez, E. López, P. Güereca, F. Martin, M. García-Vivanco, I. Palomino, X. Querol, M. Pandolfi, M.J. Sanz and J.J. Diéguez: "CALIOPE: An operational air quality forecasting system for the Iberian Peninsula, Balearic Islands and Canary Islands- First annual evaluation and ongoing developments", Adv. Sci. and Res., 2: 89-98, 2008. Baldasano J.M., L. P. Güereca, E. López, S. Gassó, P. Jimenez-Guerrero. "Development of a high resolution (1 km x 1 km, 1 h) emission model for Spain: the High-Elective Resolution Modelling Emission System (HERMES)". Atmospheric Environment, 42: 7215-7233 doi: 10.1016/j.atmosenv.2008.07.026, 2008. Basart, S., Pérez, C., Cuevas, E., Baldasano, J. M. and Gobbi, G. P. "Aerosol characterization in Northern Africa, Northeastern Atlantic, Mediterranean Basin and Middle East from direct-sun AERONET observations", Atmos. Chem. Phys.., 9, 7707-7745, 2009. Jiménez-Guerrero, P., Pérez, C., Jorba, O. and Baldasano, J. M. "Contribution of Saharan dust in an integrated air quality system and its on-line assessment", Geophys. Res. Lett., 35(3), 2008. O'Neill, N. T., Dubovik, O., and Eck, T. F.: A modified Angstrom coefficient for the characterization of sub-micron aerosols, App. Opt., 40(14), 2368-2375, 2001. Pérez, C., Nickovic, S., Pejanovic, G., Baldasano, J. M. and Ozsoy, E. "Interactive dust-radiation modeling: A step to improve weather forecasts", Geophys. Res., 11(D16206),doi:10.1029/2005JD006717, 2006. Rodríguez, S., Querol, X., Alastuey, A., Kallos, G. and Kakaliagou, O. "Saharan dust contributions to PM10 and TSP levels in Southern and Eastern Spain", Atmos. Environ., 35, 2433-2447, 2001.

  3. Direct Detection of C_2H_2 in Air and Human Breath by Cw-Crds

    NASA Astrophysics Data System (ADS)

    Schmidt, Florian M.; Vaittinen, Olavi; Metsälä, Markus; Halonen, Lauri

    2010-06-01

    Continuous wave cavity ring-down spectroscopy (cw-CRDS) is an established cavity-enhanced absorption technique that can provide the necessary sensitivity, selectivity and fast acquisition time for many applications involving the detection of trace species. We present a simple but highly sensitive cw-CRDS spectrometer based on an external cavity diode laser operating in the near-infrared region. This instrument allows us to directly detect acetylene (C_2H_2) mixing ratios in air with a detection limit of 120 parts per trillion by volume (pptv) measuring on a C_2H_2 absorption line at 6565.620 cm-1. Acetylene is a combustion product that is routinely used in environmental monitoring as a marker for anthropogenic emissions. In a recent work, the spectrometer was employed to measure the level of acetylene in indoor and outdoor air in Helsinki. Continuous flow measurements with high time resolution (one minute) revealed strong fluctuations in the acetylene mixing ratio in outdoor air during daytime. Due to its non-invasive nature and fast response time, the analysis of exhaled breath for medical diagnostics is an excellent and straightforward alternative to methods using urine or blood samples. In an ongoing study, the cw-CRDS instrument is used to establish the baseline level of acetylene in the breath of the healthy population. An elevated amount of acetylene in breath could indicate exposure to combustion exhausts or other volatile organic compound (VOC) rich sources. The latest results of this investigation will be presented. F. M. Schmidt, O. Vaittinen, M. Metsälä, P. Kraus and L. Halonen, submitted for publication in Appl. Phys. B.

  4. Present and Future of M2M

    NASA Astrophysics Data System (ADS)

    Ono, Satoru; Watanabe, Takashi

    In recent years, the rapid progress in the development of hardware and software technologies enables tiny and low cost information devices hereinafter referred to as Machine to be widely available. M2M (Machine to Machine) has been of much attention where many tiny machines are connected to each other through networks with minimal human intervention to provide smooth and intelligent management. M2M is a promising core technology providing timely, flexible, efficient and comprehensive service at low cost. M2M has wide variety of applications including energy management system, environmental monitoring system, intelligent transport system, industrial automation system and other applications. M2M consists of terminals and networks that connect them. In this paper, we mainly focus on M2M networking and mention the future direction of the technology.

  5. USAF Bioenvironmental Noise Data Handbook. Volume 167: MA-3M air conditioner

    NASA Astrophysics Data System (ADS)

    Rau, T. H.

    1982-06-01

    The MA-3M is an electric motor-driven air conditioner designed to cool electronic equipment on aircraft during ground maintenance. This report provides measured and extrapolated data defining the bioacoustic environments produced by this unit operating at a normal rated condition. Near-field data are reported for 37 locations in a wide variety of physical and psychoacoustic measures: overall and band sound pressure levels, C-weighted and A-weighted sound levels, preferred speech interference levels, perceived noise levels, and limiting times for total daily exposure of personnel with and without standard Air Force ear protectors.

  6. Photoelectron Spectroscopy of Doubly and Singly Charged Group VIB Dimetalate Anions: M2O72-, MM'072-, and M207- (M, M'=Cr, Mo, W)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhai, Hua Jin; Huang, Xin; Waters, Tom

    2005-11-24

    We produced both doubly and singly charged Group VIB dimetalate species-M2O7 2-, MM'O72-, and M2O7 - (M, M'=) Cr, Mo, W)susing two different experimental techniques (electrospray ionization for the doubly charged anions and laser vaporization for the singly charged anions) and investigated their electronic and geometric structures using photoelectron spectroscopy and density functional calculations. Distinct changes in the electronic and geometric structures were observed as a function of the metal and charge state. The electron binding energies of the heteronuclear dianions MM'O7 2- were observed to be roughly the average of those of their homonuclear counterparts (M2O7 2- and M'2O7more » 2-). Density functional calculations indicated that W2O7 2-, W2O7-, and W2O7 possess different ground-state structures: the dianion is highly symmetric (D3d,1A1g) with a single bridging oxo ligand, the monoanion is a doublet (C1, 2A) with two bridging oxo ligands and a radical terminal oxo ligand, whereas the neutral is a singlet (C1, 1A) with two bridging oxo ligands and a terminal peroxo ligand. The combined experimental and theoretical study provides insights into the evolution of geometric and electronic structures as a function of charge state. The clusters identified might provide insights into the possible structures of reactive species present in early transition-metal oxide catalysts that are relevant to their reactivity and catalytic function.« less

  7. Air Pollution and Ischemic Stroke Among Young Adults.

    PubMed

    Yitshak Sade, Maayan; Novack, Victor; Ifergane, Gal; Horev, Anat; Kloog, Itai

    2015-12-01

    Studies have demonstrated consistent associations between cardiovascular illness and particulate matter (PM) <10 and <2.5 μm in diameter, but stroke received less attention. We hypothesized that air pollution, an inflammation progenitor, can be associated with stroke incidence in young patients in whom the usual risk factors for stroke are less prevalent. We aimed to evaluate the association between stroke incidence and exposure to PM <10 and <2.5 μm, in a desert area characterized by a wide range of PM. We included all members of the largest health maintenance organization in Israel, who were admitted to a local hospital with stroke between 2005 and 2012. Exposure assessment was based on a hybrid model incorporating daily satellite remote sensing data at 1-km spatial resolution. We performed case-crossover analysis, stratified by personal characteristics and distance from main roads. We identified 4837 stroke cases (89.4% ischemic stroke). Interquartile range of PM <10 and <2.5 μm was 36.3 to 54.7 and 16.7 to 23.3 μg/m(3), respectively. The subjects' average age was 70 years; 53.4% were males. Associations between ischemic stroke and increases of interquartile range average concentrations of particulate matter <10 or <2.5 μm at the day of the event were observed among subjects <55 years (odds ratio [95% confidence interval], 1.11 [1.02-1.20] and 1.10 [1.00-1.21]). Stronger associations were observed in subjects living within 75 m from a main road (1.22 [1.03-1.43] and 1.26 [1.04-1.51]). We observed higher risk for ischemic stroke associated with PM among young adults. This finding can be explained by the inflammatory mechanism, linking air pollution and stroke. © 2015 American Heart Association, Inc.

  8. Observations of GEO Debris with the Magellan 6.5-m Telescopes

    NASA Technical Reports Server (NTRS)

    Seitzer, Patrick; Burkhardt, Andrew; Cardonna, Tommaso; Lederer, Susan M.; Cowardin, Heather; Barker, Edwin S.; Abercromby, Kira J.

    2012-01-01

    Optical observations of geosynchronous orbit (GEO) debris are important to address two questions: 1. What is the distribution function of objects at GEO as a function of brightness? With some assumptions, this can be used to infer a size distribution. 2. Can we determine what the likely composition of individual GEO debris pieces is from studies of the spectral reflectance of these objects? In this paper we report on optical observations with the 6.5-m Magellan telescopes at Las Campanas Observatory in Chile that attempt to answer both questions. Imaging observations over a 0.5 degree diameter field-of-view have detected a significant population of optically faint debris candidates with R > 19th magnitude, corresponding to a size smaller than 20 cm assuming an albedo of 0.175. Many of these objects show brightness variations larger than a factor of 2, suggesting either irregular shapes or albedo variations or both. The object detection rate (per square degree per hour) shows an increase over the rate measured in the 0.6-m MODEST observations, implying an increase in the population at optically fainter levels. Assuming that the albedo distribution is the same for both samples, this corresponds to an increase in the population of smaller size debris. To study the second issue, calibrated reflectance spectroscopy has been obtained of a sample of GEO and near GEO objects with orbits in the public U.S. Space Surveillance Network catalog. With a 6.5-m telescope, the exposures times are short (30 seconds or less), and provide simultaneous wavelength coverage from 4500 to 8000 Angstroms. If the observed objects are tumbling, then simultaneous coverage and short exposure times are essential for a realistic assessment of the object fs spectral signature. We will compare the calibrated spectra with lab-based measurements of simple spacecraft surfaces composed of a single material.

  9. The atmospheres of M dwarfs: Observations

    NASA Technical Reports Server (NTRS)

    Rodono, Marcello

    1987-01-01

    After presenting global properties of M dwarfs, the principal diagnostic of activity phenomena occurring in their atmosphere from the geometrical, energetic, and temporal points of view is stressed. Observations of sunspots, plages, flares, and activity cycles are presented. The major sources of activity are discussed with particular emphasis on the generation, intensification, and measurements of stellar magnetic fields.

  10. Characterising fifteen years of continuous atmospheric radon activity observations at Cape Point (South Africa)

    NASA Astrophysics Data System (ADS)

    Botha, R.; Labuschagne, C.; Williams, A. G.; Bosman, G.; Brunke, E.-G.; Rossouw, A.; Lindsay, R.

    2018-03-01

    This paper describes and discusses fifteen years (1999-2013) of continuous hourly atmospheric radon (222Rn) monitoring at the coastal low-altitude Southern Hemisphere Cape Point Station in South Africa. A strong seasonal cycle is evident in the observed radon concentrations, with maxima during the winter months, when air masses arriving at the Cape Point station from over the African continental surface are more frequently observed, and minima during the summer months, when an oceanic fetch is predominant. An atmospheric mean radon activity concentration of 676 ± 2 mBq/m3 is found over the 15-year record, having a strongly skewed distribution that exhibits a large number of events falling into a compact range of low values (corresponding to oceanic air masses), and a smaller number of events with high radon values spread over a wide range (corresponding to continental air masses). The mean radon concentration from continental air masses (1 004 ± 6 mBq/m3) is about two times higher compared to oceanic air masses (479 ± 3 mBq/m3). The number of atmospheric radon events observed is strongly dependent on the wind direction. A power spectral Fast Fourier Transform analysis of the 15-year radon time series reveals prominent peaks at semi-diurnal, diurnal and annual timescales. Two inter-annual radon periodicities have been established, the diurnal 0.98 ± 0.04 day-1 and half-diurnal 2.07 ± 0.15 day-1. The annual peak reflects major seasonal changes in the patterns of offshore versus onshore flow associated with regional/hemispheric circulation patterns, whereas the diurnal and semi-diurnal peaks together reflect the influence of local nocturnal radon build-up over land, and the interplay between mesoscale sea/land breezes. The winter-time diurnal radon concentration had a significant decrease of about 200 mBq/m3 (17%) while the summer-time diurnal radon concentration revealed nearly no changes. A slow decline in the higher radon percentiles (75th and 95th) for the

  11. SEARCH FOR GAMMA RAYS ABOVE 100 TeV FROM THE CRAB NEBULA WITH THE TIBET AIR SHOWER ARRAY AND THE 100 m{sup 2} MUON DETECTOR

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amenomori, M.; Bi, X. J.; Chen, W. Y.

    2015-11-10

    A 100 m{sup 2} muon detector (MD) was successfully constructed under the existing Tibet air shower (AS) array in the late fall of 2007. The sensitivity of the Tibet AS array to cosmic gamma rays can be improved by selecting muon-poor events with the MD. Our MC simulation of the MD response reasonably agrees with the experimental data in terms of the charge distribution for one-muon events and the background rejection power. Using the data collected by the Tibet AS array and the 100 m{sup 2} MD taken from 2008 March to 2010 February, we search for continuous gamma-ray emissionmore » from the Crab Nebula above ∼100 TeV. No significant excess is found, and the most stringent upper limit is obtained above 140 TeV.« less

  12. Temperature-dependent Raman and ultraviolet photoelectron spectroscopy studies on phase transition behavior of VO{sub 2} films with M1 and M2 phases

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Okimura, Kunio, E-mail: okifn@keyaki.cc.u-tokai.ac.jp; Hanis Azhan, Nurul; Hajiri, Tetsuya

    Structural and electronic phase transitions behavior of two polycrystalline VO{sub 2} films, one with pure M1 phase and the other with pure M2 phase at room temperature, were investigated by temperature-controlled Raman spectroscopy and ultraviolet photoelectron spectroscopy (UPS). We observed characteristic transient dynamics in which the Raman modes at 195 cm{sup −1} (V-V vibration) and 616 cm{sup −1} (V-O vibration) showed remarkable hardening along the temperature in M1 phase film, indicating the rearrangements of V-V pairs and VO{sub 6} octahedra. It was also shown that the M1 Raman mode frequency approached those of invariant M2 peaks before entering rutile phase. In UPSmore » spectra with high energy resolution of 0.03 eV for the M2 phase film, narrower V{sub 3d} band was observed together with smaller gap compared to those of M1 phase film, supporting the nature of Mott insulator of M2 phase even in the polycrystalline film. Cooperative behavior of lattice rearrangements and electronic phase transition was suggested for M1 phase film.« less

  13. Exposure of pregnant women to cookstove-related household air pollution in urban and periurban Trujillo, Peru.

    PubMed

    St Helen, Gideon; Aguilar-Villalobos, Manuel; Adetona, Olorunfemi; Cassidy, Brandon; Bayer, Charlene W; Hendry, Robert; Hall, Daniel B; Naeher, Luke P

    2015-01-01

    Although evidence suggests associations between maternal exposure to air pollution and adverse birth outcomes, pregnant women's exposure to household air pollution in developing countries is understudied. Personal exposures of pregnant women (N = 100) in Trujillo, Peru, to air pollutants and their indoor concentrations were measured. The effects of stove-use-related characteristics and ambient air pollution on exposure were determined using mixed-effects models. Significant differences in 48-hour kitchen concentrations of particulate matter (PM2.5), carbon monoxide (CO), and nitrogen dioxide (NO2) concentrations were observed across fuel types (p < 0.05). Geometric mean PM2.5 concentrations where 112 μg/m(3) (confidence limits [CLs]: 52, 242 μg/m(3)) and 42 μg/m(3) (21, 82 μg/m(3)) in homes where wood and gas were used, respectively. PM2.5 exposure was at levels that recent exposure-response analyses suggest may not result in substantial reduction in health risks even in homes where cleaner burning gas stoves were used.

  14. Observations and impacts of transported Canadian wildfire smoke on ozone and aerosol air quality in the Maryland region on June 9-12, 2015.

    PubMed

    Dreessen, Joel; Sullivan, John; Delgado, Ruben

    2016-09-01

    Canadian wildfire smoke impacted air quality across the northern Mid-Atlantic (MA) of the United States during June 9-12, 2015. A multiday exceedance of the new 2015 70-ppb National Ambient Air Quality Standard (NAAQS) for ozone (O3) followed, resulting in Maryland being incompliant with the Environmental Protection Agency's (EPA) revised 2015 O3 NAAQS. Surface in situ, balloon-borne, and remote sensing observations monitored the impact of the wildfire smoke at Maryland air quality monitoring sites. At peak smoke concentrations in Maryland, wildfire-attributable volatile organic compounds (VOCs) more than doubled, while non-NOx oxides of nitrogen (NOz) tripled, suggesting long range transport of NOx within the smoke plume. Peak daily average PM2.5 was 32.5 µg m(-3) with large fractions coming from black carbon (BC) and organic carbon (OC), with a synonymous increase in carbon monoxide (CO) concentrations. Measurements indicate that smoke tracers at the surface were spatially and temporally correlated with maximum 8-hr O3 concentrations in the MA, all which peaked on June 11. Despite initial smoke arrival late on June 9, 2015, O3 production was inhibited due to ultraviolet (UV) light attenuation, lower temperatures, and nonoptimal surface layer composition. Comparison of Community Multiscale Air Quality (CMAQ) model surface O3 forecasts to observations suggests 14 ppb additional O3 due to smoke influences in northern Maryland. Despite polluted conditions, observations of a nocturnal low-level jet (NLLJ) and Chesapeake Bay Breeze (BB) were associated with decreases in O3 in this case. While infrequent in the MA, wildfire smoke may be an increasing fractional contribution to high-O3 days, particularly in light of increased wildfire frequency in a changing climate, lower regional emissions, and tighter air quality standards. The presented event demonstrates how a single wildfire event associated with an ozone exceedance of the NAAQS can prevent the Baltimore region

  15. Isolation and characterization of rabbit anti-m3 2,2,7G antibodies.

    PubMed Central

    Luhrmann, R; Appel, B; Bringmann, P; Rinke, J; Reuter, R; Rothe, S; Bald, R

    1982-01-01

    Antibodies specific for intact 2,2,7-trimethylguanosine (m3 2,2,7G) were induced by immunization of rabbits with a nucleoside-human serum albumen (HSA) conjugate. Competition radioimmunoassay showed that the antibody distinguishes well between intact m3 2,2,7G and its alkali-hydrolysed form (m3 2,2,7G*). Antibody specificity is largely dependent on the presence of all three methyl groups in m3 2,2,7G: none of the less extensively methylated nucleosides m7G, m2G and m2 2,2G is able to compete efficiently with the homologous hapten. Little or no competition was observed with m1G, m1A, m6A, m5U and each of the four unmodified ribonucleosides. Binding studies with nucleoplasmic RNAs from Ehrlich ascites cells suggest that the antibody reacts specifically with the m3 2,2,7G-containing cap structure of the small nuclear U-RNAs (U-snRNAs). Thus the antibody should be a valuable tool for studying the role of the 5'-terminal regions of the U-snRNAs of eucaryotic cells. Images PMID:7155893

  16. Proposed Ames M2-F1, M1-L half-cone, and Langley lenticular bodies.

    NASA Technical Reports Server (NTRS)

    1962-01-01

    Dale Reed, who inaugurated the lifting-body flight research at NASA's Flight Research Center (later, Dryden Flight Research Center, Edwards, CA), originally proposed that three wooden outer shells be built. These would then be attached to the single internal steel structure. The three shapes were (viewer's left to right) the M2-F1, the M1-L, and a lenticular shape. Milt Thompson, who supported Reed's advocacy for a lifting-body research project, recommended that only the M2-F1 shell be built, believing that the M1-L shape was 'too radical,' while the lenticular one was 'too exotic.' Although the lenticular shape was often likened to that of a flying saucer, Reed's wife Donna called it the 'powder puff.' The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey

  17. VLBI observations of 23 hot spots in the starburst galaxy M82

    NASA Technical Reports Server (NTRS)

    Bartel, Norbert; Ratner, Michael I.; Shapiro, Irwin I.; Rogers, Alan E. E.; Preston, Robert A.

    1987-01-01

    The simultaneous 2.3 and 8.4 GHz VLBI observations of 23 hot spots in the nuclear region of M82 presented indicate the presence of six hot spots at 2.3 GHz, but only one at 8.4 GHz. Attention is given to a mapping of the brightest hot spot, 41.9+58, at 2.3 GHz, which exhibits a complex brightness distribution whose angular width in the NE-SW direction is 45 mas at the 10-percent contour. These data are consistent with the hot spots in M82 being powerful SNRs, with ages between about 10 and 300 yr.

  18. Long Duration Exposure Facility experiment M0003 deintegration observation data base

    NASA Technical Reports Server (NTRS)

    Gyetvay, S. R.; Coggi, J. M.; Meshishnek, M. J.

    1993-01-01

    The four trays (2 leading edge and 2 trailing edge) of the M0003 materials experiment on the Long Duration Exposure Facility (LDEF) contained 1274 samples from 20 subexperiments. The complete sample complement represented a broad range of materials, including thin film optical coatings, paints, polymer sheets and tapes, adhesives, and composites, for use in various spacecraft applications, including thermal control, structures, optics, and solar power. Most subexperiments contained sets of samples exposed on both the leading and trailing edge trays of LDEF. Each individual sample was examined by high resolution optical microscope during the deintegration of the subexperiments from the M0003 trays. Observations of the post-flight condition of the samples made during this examination were recorded in a computer data base. The deintegration observation data base is available to requesters on floppy disk in 4th Dimension for the Macintosh format. Over 3,000 color macrographs and photomicrographs were shot to complement the observation records and to document the condition of the individual samples and of the M0003 trays. The photographs provide a visual comparison of the response of materials in leading and trailing edge LDEF environments. The Aerospace Corporate Archives is distributing photographs of the samples and hard copies of the database records to the general public upon request. Information on obtaining copies of the data base disks and for ordering photographs and records of specific samples or materials are given.

  19. Einstein Observatory solid state spectrometer observations of M87 and the Virgo cluster

    NASA Technical Reports Server (NTRS)

    Lea, S. M.; Mushotzky, R. F.; Holt, S. S.

    1982-01-01

    X-ray observations of the galaxy M87 and of a region in the Virgo cluster displaced 7 minutes from the center of M87 are presented. X-ray spectra are obtained at these two locations with the slid state spectrometer onboard the Einstein Observatory. Emission lines were observed in both locations, indicating the presence of heavy elements at abundances approximately solar (to within a factor of 2). A temperature gradient, T increases from approximately 1.4 keV at the position of M87 to T approximately 3.35 keV 7' away, was detected. There is lower temperature thermal emission at the center of M87 with T approximately 0.6 keV, consistent with models for cooling flows in this cluster. In addition to the thermal emission, a power law component in the spectrum of M87, was detected consistent with that observed by HEAO-1, indicating that this component probably originates in the galaxy itself. The presence of intracluster gas having density approximately .001 cu cm and temperature approximately 30 million K is indicated.

  20. Retrieval of Raindrop Size Distribution, Vertical Air Velocity and Water Vapor Attenuation Using Dual-Wavelength Doppler Radar Observations

    NASA Technical Reports Server (NTRS)

    Heymsfield, Gerald M.; Tian, Lin; Li, Lihua; Srivastava, C.

    2005-01-01

    Two techniques for retrieving the slope and intercept parameters of an assumed exponential raindrop size distribution (RSD), vertical air velocity, and attenuation by precipitation and water vapor in light stratiform rain using observations by airborne, nadir looking dual-wavelength (X-band, 3.2 cm and W-band, 3.2 mm) radars are presented. In both techniques, the slope parameter of the RSD and the vertical air velocity are retrieved using only the mean Doppler velocities at the two wavelengths. In the first method, the intercept of the RSD is estimated from the observed reflectivity at the longer wavelength assuming no attenuation at that wavelength. The attenuation of the shorter wavelength radiation by precipitation and water vapor are retrieved using the observed reflectivity at the shorter wavelength. In the second technique, it is assumed that the longer wavelength suffers attenuation only in the melting band. Then, assuming a distribution of water vapor, the melting band attenuation at both wavelengths and the rain attenuation at the shorter wavelength are retrieved. Results of the retrievals are discussed and several physically meaningful results are presented.

  1. RXTE Observations M87: Investigating the Non-Thermal Continuum

    NASA Technical Reports Server (NTRS)

    Reynolds, Christopher S.

    2001-01-01

    This is the final report for NASA grant NAG5-7329, awarded for the RXTE Cycle 3 Guest Observer Program, "RXTE Observations of M87: Investigating the nonthermal continuum". This grant totaled $8000 and was spent over 3 years (4/1998-4/2001). It supported analysis of RXTE observations of the nearby giant elliptical galaxy M87 with the RXTE satellite. The main aim of these observations was to search for non-thermal emission from the core of M87 and the famous jet. This grant also partially funded supporting theoretical work. The observational campaign was performed in December 1997 and January 1998, and we were given the final data tape in April 1998. Sebastian Heinz (then a graduated student in our group) and I started to work on the data immediately. The results of our detailed analysis were submitted to the Astrophysical Journal in November 1998, and accepted for publication in March 1999. Tile paper was published in August, 1999. The journal reference is: A RXTE study of N187 and the core of the Virgo cluster, Reynolds C.S.,Heinx S., Fabian A.C., Begelman M.C., 1999, ApJ, 102, 1999. During this first year of the project, this grant supported Mr. Heinz's travel to the Paris Texas Symposium in December 1998, as well as providing funds for necessary maintenance of our computer system.

  2. Observations of M31 and M33 with the Fermi Large Area Telescope: A Galactic Center Excess in Andromeda?

    DOE PAGES

    Ackermann, M.; Ajello, M.; Albert, A.; ...

    2017-02-23

    We report the Fermi Large Area Telescope (LAT) has opened the way for comparative studies of cosmic rays (CRs) and high-energy objects in the Milky Way (MW) and in other, external, star-forming galaxies. Using 2 yr of observations with the Fermi LAT, Local Group galaxy M31 was detected as a marginally extended gamma-ray source, while only an upper limit has been derived for the other nearby galaxy M33. We revisited the gamma-ray emission in the direction of M31 and M33 using more than 7 yr of LAT Pass 8 data in the energy rangemore » $$0.1\\mbox{--}100\\,\\mathrm{GeV}$$, presenting detailed morphological and spectral analyses. M33 remains undetected, and we computed an upper limit of $$2.0\\times {10}^{-12}\\,\\mathrm{erg}\\,{\\mathrm{cm}}^{-2}\\,{{\\rm{s}}}^{-1}\\,$$ on the $$0.1\\mbox{--}100\\,\\mathrm{GeV}$$ energy flux (95% confidence level). This revised upper limit remains consistent with the observed correlation between gamma-ray luminosity and star formation rate tracers and implies an average CR density in M33 that is at most half of that of the MW. M31 is detected with a significance of nearly $$10\\sigma $$. Its spectrum is consistent with a power law with photon index $${\\rm{\\Gamma }}=2.4\\pm {0.1}_{\\mathrm{stat}+\\mathrm{syst}}$$ and a $$0.1\\mbox{--}100\\,\\mathrm{GeV}$$ energy flux of $$(5.6\\pm {0.6}_{\\mathrm{stat}+\\mathrm{syst}})\\times {10}^{-12}\\,\\mathrm{erg}\\,{\\mathrm{cm}}^{-2}\\,{{\\rm{s}}}^{-1}$$. M31 is detected to be extended with a $$4\\sigma $$ significance. The spatial distribution of the emission is consistent with a uniform-brightness disk with a radius of 0fdg4 and no offset from the center of the galaxy, but nonuniform intensity distributions cannot be excluded. The flux from M31 appears confined to the inner regions of the galaxy and does not fill the disk of the galaxy or extend far from it. The gamma-ray signal is not correlated with regions rich in gas or star formation activity, which suggests that the emission is not

  3. Observations of M31 and M33 with the Fermi Large Area Telescope: A Galactic Center Excess in Andromeda?

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ackermann, M.; Ajello, M.; Albert, A.

    We report the Fermi Large Area Telescope (LAT) has opened the way for comparative studies of cosmic rays (CRs) and high-energy objects in the Milky Way (MW) and in other, external, star-forming galaxies. Using 2 yr of observations with the Fermi LAT, Local Group galaxy M31 was detected as a marginally extended gamma-ray source, while only an upper limit has been derived for the other nearby galaxy M33. We revisited the gamma-ray emission in the direction of M31 and M33 using more than 7 yr of LAT Pass 8 data in the energy rangemore » $$0.1\\mbox{--}100\\,\\mathrm{GeV}$$, presenting detailed morphological and spectral analyses. M33 remains undetected, and we computed an upper limit of $$2.0\\times {10}^{-12}\\,\\mathrm{erg}\\,{\\mathrm{cm}}^{-2}\\,{{\\rm{s}}}^{-1}\\,$$ on the $$0.1\\mbox{--}100\\,\\mathrm{GeV}$$ energy flux (95% confidence level). This revised upper limit remains consistent with the observed correlation between gamma-ray luminosity and star formation rate tracers and implies an average CR density in M33 that is at most half of that of the MW. M31 is detected with a significance of nearly $$10\\sigma $$. Its spectrum is consistent with a power law with photon index $${\\rm{\\Gamma }}=2.4\\pm {0.1}_{\\mathrm{stat}+\\mathrm{syst}}$$ and a $$0.1\\mbox{--}100\\,\\mathrm{GeV}$$ energy flux of $$(5.6\\pm {0.6}_{\\mathrm{stat}+\\mathrm{syst}})\\times {10}^{-12}\\,\\mathrm{erg}\\,{\\mathrm{cm}}^{-2}\\,{{\\rm{s}}}^{-1}$$. M31 is detected to be extended with a $$4\\sigma $$ significance. The spatial distribution of the emission is consistent with a uniform-brightness disk with a radius of 0fdg4 and no offset from the center of the galaxy, but nonuniform intensity distributions cannot be excluded. The flux from M31 appears confined to the inner regions of the galaxy and does not fill the disk of the galaxy or extend far from it. The gamma-ray signal is not correlated with regions rich in gas or star formation activity, which suggests that the emission is not

  4. Lateral distribution of high energy hadrons and gamma ray in air shower cores observed with emulsion chambers

    NASA Technical Reports Server (NTRS)

    Matano, T.; Machida, M.; Kawasumi, N.; Tsushima, I.; Honda, K.; Hashimoto, K.; Navia, C. E.; Matinic, N.; Aquirre, C.

    1985-01-01

    A high energy event of a bundle of electrons, gamma rays and hadronic gamma rays in an air shower core were observed. The bundles were detected with an emulsion chamber with thickness of 15 cm lead. This air shower is estimated to be initiated with a proton with energy around 10 to the 17th power to 10 to the 18th power eV at an altitude of around 100 gmc/2. Lateral distributions of the electromagnetic component with energy above 2 TeV and also the hadronic component of energy above 6 TeV of this air shower core were determined. Particles in the bundle are produced with process of the development of the nuclear cascade, the primary energy of each interaction in the cascade which produces these particles is unknown. To know the primary energy dependence of transverse momentum, the average products of energy and distance for various average energies of secondary particles are studied.

  5. Assessment of air quality in and around a steel industry with direct reduction iron route.

    PubMed

    Jena, Pradip K; Behera, Dillip K; Mishra, C S K; Mohanty, Saswat K

    2011-10-01

    The coal based Direct Reduced Iron (DRI) route for secondary steel production is now a preferred choice in India. Steel making is invariably associated with emission of air pollutants into the environment. Air quality monitoring was carried out in Winter, Summer and Rainy seasons of 2008 in eight monitoring stations in the work zone and five stations in the residential zone of an Integrated Steel Industry located in Orissa state, India. Four air quality parameters i.e. SPM, RSPM, SO2 and NO2 were monitored. Mean SPM and RSPM values were found to be significantly high (p < 0.01) at stations nearer to source in both work zone and residential zone .The highest average SPM and RSPM values in the work zone recorded were 4869 microg/m3 and 1420 microg/m3 and in the residential zone 294 microg/m3 and 198 microg/m3 respectively. No significant difference in the SO2 and NO2 levels was observed between the work and residential zones. In general, the values of air pollutants were highest in Winter followed by Summer and Rainy season. SPM and RSPM values exceeded the National Air Quality Standards (NAAQS) in both the residential and work zones.

  6. The Coca-campaign: An Attempt To Derive The Carbon Exchange of A Forested Region Using Airborne Co2 and Co Observations

    NASA Astrophysics Data System (ADS)

    Schmitgen, S.; Ciais, P.; Geiß, H.; Kley, D.; Neininger, B.; Baeumle, M.; Fuchs, W.; Brunet, Y.

    As part of the project COCA an attempt was made to measure the daytime biogenic CO2 fluxes over a forest area (about 15 by 30 km). This campaign took place around the CARBOEUROFLUX site "Le Bray" (Pinus pinaster) close to Bordeaux in France end of June 2001. Based on continuous airborne CO2, H2O and CO flux and concen- tration measurements a Lagrangian budgeting approach was chosen for the determi- nation of the regional CO2 fluxes. The objective is to determine the CO2 uptake of the extended forest area from the CO2/CO gradients up- and downwind of the ecosystem, using CO as air mass tracer and such eliminating the influence of anthropogenic CO2 advected into the area. First results will be shown of a flight on June 23rd, where fair wind speeds (about 5 m/s) and a low CBL height led to the observation of a clear decrease in CO2 at the downwind flight stacks with basically constant CO concentrations. For other flights with very low wind speeds, local effects dominate the observa- tions leading to a larger variability in the observations. Both, correlations and anti- correlations of CO2 with the anthropogenic tracer CO have been observed. Positive correlations indicate fresh plumes of anthropogenic CO2. Negative correlations are indicative of entrainment of free tropospheric air, that was marked by relatively higher CO2 and lower CO concentrations than the average CBL concentrations.

  7. NASA Earth Observation Systems and Applications for Public Health and Air Quality Models and Decisions Support

    NASA Technical Reports Server (NTRS)

    Estes, Sue; Haynes, John; Omar, Ali

    2013-01-01

    Health and Air Quality providers and researchers need environmental data to study and understand the geographic, environmental, and meteorological differences in disease. Satellite remote sensing of the environment offers a unique vantage point that can fill in the gaps of environmental, spatial, and temporal data for tracking disease. This presentation will demonstrate the need for collaborations between multi-disciplinary research groups to develop the full potential of utilizing Earth Observations in studying health. Satellite earth observations present a unique vantage point of the earth's environment from space, which offers a wealth of health applications for the imaginative investigator. The presentation is directly related to Earth Observing systems and Global Health Surveillance and will present research results of the remote sensing environmental observations of earth and health applications, which can contribute to the public health and air quality research. As part of NASA approach and methodology they have used Earth Observation Systems and Applications for Public Health and Air Quality Models to provide a method for bridging gaps of environmental, spatial, and temporal data for tracking disease. This presentation will provide an overview of projects dealing with infectious diseases, water borne diseases and air quality and how many environmental variables effect human health. This presentation will provide a venue where the results of both research and practice using satellite earth observations to study weather and it's role in public health research.

  8. NASA Earth Observation Systems and Applications for Public Health and Air Quality Models and Decisions Support

    NASA Technical Reports Server (NTRS)

    Estes, Sue; Haynes, John; Omar, Ali

    2012-01-01

    Health and Air Quality providers and researchers need environmental data to study and understand the geographic, environmental, and meteorological differences in disease. Satellite remote sensing of the environment offers a unique vantage point that can fill in the gaps of environmental, spatial, and temporal data for tracking disease. This presentation will demonstrate the need for collaborations between multi-disciplinary research groups to develop the full potential of utilizing Earth Observations in studying health. Satellite earth observations present a unique vantage point of the earth's environment from space, which offers a wealth of health applications for the imaginative investigator. The presentation is directly related to Earth Observing systems and Global Health Surveillance and will present research results of the remote sensing environmental observations of earth and health applications, which can contribute to the public health and air quality research. As part of NASA approach and methodology they have used Earth Observation Systems and Applications for Public Health and Air Quality Models to provide a method for bridging gaps of environmental, spatial, and temporal data for tracking disease. This presentation will provide an overview of projects dealing with infectious diseases, water borne diseases and air quality and how many environmental variables effect human health. This presentation will provide a venue where the results of both research and practice using satellite earth observations to study weather and it's role in public health research.

  9. Yokota Air Base, Japan: Revised Uniform Summary of Surface Weather Observations (RUSSWO). Parts A-F

    DTIC Science & Technology

    1988-02-01

    8217... .. ... ... .. ... ... .. ... .. ... ... . m ... .. ... ... .. ... ... .. ... .. ... ... .. ... .. * GLOBAL CLIMAIOLOGY 6RANCH PLECENTAGE FREOUNCY OF...24 HOUR AMOUNTS IN INCHES - M -0-N-T-H-S- ALL YEAS I JAN...8217........................°...........°................°................ 24 HOUR AMUUNTS IN INCHFS - M -O-N-I-H-S- ALL YEA I JAN F E *’AIr AP4 MAY JUN

  10. Assessing polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in air across Latin American countries using polyurethane foam disk passive air samplers.

    PubMed

    Schuster, Jasmin K; Harner, Tom; Fillmann, Gilberto; Ahrens, Lutz; Altamirano, Jorgelina C; Aristizábal, Beatriz; Bastos, Wanderley; Castillo, Luisa Eugenia; Cortés, Johana; Fentanes, Oscar; Gusev, Alexey; Hernandez, Maricruz; Ibarra, Martín Villa; Lana, Nerina B; Lee, Sum Chi; Martínez, Ana Patricia; Miglioranza, Karina S B; Puerta, Andrea Padilla; Segovia, Federico; Siu, May; Tominaga, Maria Yumiko

    2015-03-17

    A passive air sampling network has been established to investigate polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) at Global Atmospheric Passive Sampling (GAPS) sites and six additional sites in the Group of Latin American and Caribbean Countries (GRULAC) region. The air sampling network covers background, agricultural, rural, and urban sites. Samples have been collected over four consecutive periods of 6 months, which started in January 2011 [period 1 (January to June 2011), period 2 (July to December 2011), period 3 (January to June 2012), and period 4 (July 2012 to January 2013)]. Results show that (i) the GAPS passive samplers (PUF disk type) and analytical methodology are adequate for measuring PCDD/F burdens in air and (ii) PCDD/F concentrations in air across the GRULAC region are widely variable by almost 2 orders of magnitude. The highest concentrations in air of Σ4-8PCDD/Fs were found at the urban site São Luis (Brazil, UR) (i.e., 2560 fg/m3) followed by the sites in São Paulo (Brazil, UR), Mendoza (Argentina, RU), and Sonora (Mexico, AG) with values of 1690, 1660, and 1610 fg/m3, respectively. Very low concentrations of PCDD/Fs in air were observed at the background site Tapanti (Costa Rica, BA), 10.8 fg/m3. This variability is attributed to differences in site characteristics and potential local/regional sources as well as meteorological influences. The measurements of PCDD/Fs in air agree well with model-predicted concentrations performed using the Global EMEP Multimedia Modeling System (GLEMOS) and emission scenario constructed on the basis of the UNEP Stockholm Convention inventory of dioxin and furan emissions.

  11. The Association between Ambient Fine Particulate Air Pollution and Lung Cancer Incidence: Results from the AHSMOG-2 Study.

    PubMed

    Gharibvand, Lida; Shavlik, David; Ghamsary, Mark; Beeson, W Lawrence; Soret, Samuel; Knutsen, Raymond; Knutsen, Synnove F

    2017-03-01

    There is a positive association between ambient fine particulate matter ≤ 2.5 μm in aerodynamic diameter (PM 2.5 ) and incidence and mortality of lung cancer (LC), but few studies have assessed the relationship between ambient PM 2.5 and LC among never smokers. We assessed the association between PM 2.5 and risk of LC using the Adventist Health and Smog Study-2 (AHSMOG-2), a cohort of health conscious nonsmokers where 81% have never smoked. A total of 80,285 AHSMOG-2 participants were followed for an average of 7.5 years with respect to incident LC identified through linkage with U.S. state cancer registries. Estimates of ambient air pollution levels at participants' residences were obtained for 2000 and 2001, the years immediately prior to the start of the study. A total of 250 incident LC cases occurred during 598,927 person-years of follow-up. For each 10-μg/m 3 increment in PM 2.5 , adjusted hazard ratio (HR) with 95% confidence interval (CI) for LC incidence was 1.43 (95% CI: 1.11, 1.84) in the two-pollutant multivariable model with ozone. Among those who spent > 1 hr/day outdoors or who had lived 5 or more years at their enrollment address, the HR was 1.68 (95% CI: 1.28, 2.22) and 1.54 (95% CI: 1.17, 2.04), respectively. Increased risk estimates of LC were observed for each 10-μg/m 3 increment in ambient PM 2.5 concentration. The estimate was higher among those with longer residence at enrollment address and those who spent > 1 hr/day outdoors. Citation: Gharibvand L, Shavlik D, Ghamsary M, Beeson WL, Soret S, Knutsen R, Knutsen SF. 2017. The association between ambient fine particulate air pollution and lung cancer incidence: results from the AHSMOG-2 study. Environ Health Perspect 125:378-384; http://dx.doi.org/10.1289/EHP124.

  12. Exploration of OMI Products for Air Quality Applications Through Comparisons with Models and Observations

    NASA Technical Reports Server (NTRS)

    Pickering, K. E.; Ziemke, J.; Bucsela, E.; Gleason, J.; Marufu, L.; Dickerson, R.; Mathur, R.; Davidson, P.; Duncan, B.; Bhartia, P. K.

    2006-01-01

    The Ozone Monitoring Instrument (OMI) on board NASA s Aura satellite was launched in July 2004, and is now providing daily global observations of total column ozone, NO2, and SO2, as well as aerosol information. Algorithms have also been developed to produce daily tropospheric ozone and NO2 products. The tropospheric ozone product reported here is a tropospheric residual computed through use of Aura Microwave Limb Sounder (MLS) ozone profile data to quantify stratospheric ozone. We are investigating the applicability of OMI products for use in air quality modeling, forecasting, and analysis. These investigations include comparison of the OMI tropospheric O3 and NO2 products with global and regional models and with lower tropospheric aircraft observations. Large-scale transport of pollution seen in the OM1 tropospheric O3 data is compared with output from NASA's Global Modeling Initiative global chemistry and transport model. On the regional scale we compare the OMI tropospheric O3 and NO2 with fields from the National Oceanic and Atmospheric Administration and Environmental Protection Agency (NOAA/EPA) operational Eta/CMAQ air quality forecasting model over the eastern United States. This 12-km horizontal resolution model output is roughly of equivalent resolution to the OMI pixel data. Correlation analysis between lower tropospheric aircraft O3 profile data taken by the University of Maryland over the Mid-Atlantic States and OMI tropospheric column mean volume mixing ratio for O3 will be presented. These aircraft data are representative of the lowest 3 kilometers of the atmosphere, the region in which much of the locally-generated and regionally-transported ozone exists.

  13. Magnetic and crystallographic properties of ZrM 2-δZn 20+δ (M=Cr–Cu)

    DOE PAGES

    Svanidze, E.; II, M. Kindy; Georgen, C.; ...

    2016-04-29

    Single crystals of the cubic Laves ternaries ZrM 2-δZn 20+δ (M=Mn, Fe, Co, Ni and Cu, 0 ≤ δ ≤ 1) have been synthesized in this paper using a self-flux method. The magnetic properties of these compounds were compared with structurally similar cubic binaries ZrM 2 (M=Mn, Fe, Co, Ni and Cu). A transition from local to itinerant moment magnetism was observed for M=Fe and M=Mn, while all other ternaries exhibit weakly para- or diamagnetic behavior. The local-to-itinerant crossover can be explained by a nearly two-fold increase of the M–M bond length d M–M in ZrM 2-δZn 20+δ compounds, asmore » compared with the ZrM 2 binaries. Additionally, we report two new compounds in this series ZrCrZn 21 and ZrCu 2Zn 20. Finally, analysis of crystallographic and magnetic trends in these materials will aid in understanding of magnetism in general and 3d intermetallics in particular.« less

  14. Utilization of satellite observation of ozone and aerosols in providing initial and boundary condition for regional air quality studies

    NASA Astrophysics Data System (ADS)

    Pour-Biazar, Arastoo; Khan, Maudood; Wang, Lihua; Park, Yun-Hee; Newchurch, Mike; McNider, Richard T.; Liu, Xiong; Byun, Daewon W.; Cameron, Robert

    2011-09-01

    To demonstrate the efficacy of satellite observations in the realization of the background and transboundary transport of pollution in regional air quality modeling practices, satellite observations of ozone and aerosol optical depth were incorporated in the EPA Models-3 Community Multiscale Air Quality (CMAQ) model (http://www.cmascenter.org). Observations from Ozone Monitoring Instrument (OMI) aboard NASA's Aura satellite and AOD products from the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard Terra (EOS AM) and Aqua (EOS PM) satellites were used to specify initial and lateral boundary conditions (IC/BC) for a simulation that spanned over August 2006. The tools and techniques using the satellite data were tested in the context of current regulatory air quality modeling practices. Daily satellite observations were remapped onto the modeling domain and used as IC/BC for daily segments of a month-long simulation and the results were evaluated against surface and ozonesonde observations. Compared to the standard application of CMAQ, OMI O3 profiles significantly improved model performance in the free troposphere and MODIS aerosol products substantially improved PM2.5 predictions in the boundary layer. The utilization of satellite data for BC helped in the realization of transboundary transport of pollution and was able to explain the recirculation of pollution from Northeast Corridor to the southeastern region. Ozone in the mid- to upper-troposphere was largely dominated by transport and thus benefited most from satellite provided BC. The ozone within the boundary layer was mostly affected by fast production/loss mechanisms that are impacted by surface emissions, chemistry and removal processes and was not impacted as much. A case study for August 18-22 demonstrated that model errors in the placement of a stationary front were the main reason for errors in PM2.5 predictions as the front acted as a boundary between high and low PM2.5 concentrations.

  15. Non-linear increase of respiratory diseases and their costs under severe air pollution.

    PubMed

    Shen, Ying; Wu, Yiyun; Chen, Guangdi; Van Grinsven, Hans J M; Wang, Xiaofeng; Gu, Baojing; Lou, Xiaoming

    2017-05-01

    China is experiencing severe and persistent air pollution, with concentrations of fine particulate matters (PM 2.5 ) reaching unprecedentedly high levels in many cities. Quantifying the detrimental effects on health and their costs derived from high PM 2.5 levels is crucial because of the unsolved challenges to mitigate air pollution in the following decades. Using the daily monitoring data on PM 2.5 concentrations and clinic visits, we found a non-linear increase of respiratory diseases, but not for other diseases (e.g., digestive diseases) under severe air pollution. We found an increase of respiratory diseases by 1% for each 10 μg m -3 increase in PM 2.5 when the annual average daily PM 2.5 concentration was less than 50 μg m -3 ; while this ratio was doubled (around 2%) with the daily PM 2.5 concentration larger than 50 μg m -3 . Under severe air pollution (PM 2.5 concentration >150 μg m -3 ), the respiratory diseases increased by over 50% compared to that in clean days. Children are more sensitive to the severe air pollution. The increase of clinic visits, especially for adults, was observed mainly in bigger (>500 beds) hospitals. Re-allocating medical resources (e.g., doctors) from big hospitals to community hospitals can benefit the respiratory patients due to air pollution. The total medical cost of clinic visits of respiratory diseases derived from PM 2.5 pollution was estimated at 17.2-57.0 billion Yuan in 2014 in China, accounting for 0.5-1.6% of national total health expenditure. Because these medical costs only represent a small part of total health cost derived from air pollution, the reduction of associated health costs would be an important co-benefit of implementation of air pollution preventive strategies. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Association between Short-Term Exposure to Air Pollution and Dyslipidemias among Type 2 Diabetic Patients in Northwest China: A Population-Based Study

    PubMed Central

    Wang, Minzhen; Zheng, Shan; Nie, Yonghong; Weng, Jun; Cheng, Ning; Hu, Xiaobin; Ren, Xiaowei; Pei, Hongbo; Bai, Yana

    2018-01-01

    Air pollution exposure may play an adverse role in diabetes. However, little data are available directly evaluating the effects of air pollution exposure in blood lipids of which dysfunction has been linked to diabetes or its complications. We aimed to evaluate the association between air pollution and lipids level among type 2 diabetic patients in Northwest China. We performed a population-based study of 3912 type 2 diabetes patients in an ongoing cohort study in China. Both spline and multiple linear regressions analysis were used to examine the association between short-term exposure to PM10, SO2, NO2 and total cholesterol (TC), triglycerides (TG), low-density lipoprotein cholesterol (LDL-C), and high-density lipoprotein cholesterol (HDL-C). By spline analyses, we observed that the relationship between SO2 and HDL-C and LDL-C was shown to be non-linear (p_non-lin-association = 0.0162 and 0.000). An inverted U-shaped non-linear relationship between NO2 and LDL-C was found (p_non-lin-association < 0.0001). A J-shaped non-linear relationship between PM10 and TC, HDL-C (p_non-lin-association = 0.0173, 0.0367) was also revealed. In linear regression analyses, a 10 μg/m3 increment in SO2 was associated with 1.31% (95% CI: 0.40–2.12%), 3.52% (95% CI: 1.07–6.03%) and 7.53% (95% CI: 5.98–9.09%) increase in TC, TG and LDL-C, respectively. A 10 μg/m3 increment in PM10 was associated with 0.45% (95% CI: 0.08–0.82%), 0.29% (95% CI: 0.10–0.49%) and 0.83% (95% CI: 0.21–1.45%) increase in TC, HDL-C and LDL-C, respectively. For NO2, an increment of 10 μg/m3 was statistically associated with −3.55% (95% CI: −6.40–0.61%) and 39.01% (95% CI: 31.43–47.03%) increase in HDL-C and LDL-C. The adverse effects of air pollutants on lipid levels were greater in female and elder people. Further, we found SO2 and NO2 played a more evident role in lipid levels in warm season, while PM10 appeared stronger in cold season. The findings suggest that exposure to air pollution

  17. Impact of Small Holder Dairy Farm on the Air Quality in Gunungpati District, Semarang Municipality

    NASA Astrophysics Data System (ADS)

    Widiastuti, E.; Kustono; Adiarto; Nurliyani; Sugiharto, S.

    2018-02-01

    The study aimed to investigate the impact of small holder dairy farm on the air quality in the farm and surrounding area. The study was conducted in three farmer groups in the District of Gunungpati, including the farmer groups in the villages of Nangkasawit, Plalangan and Sumurejo. Samplings of air quality were conducted in four points (locations), i.e., inside the barn, 100 m, 200 m and 300 m from the area of farm. Parameters observed were emission of NH3 CO2, H2S and CH4. Results showed that the levels of NH3 in the barn, 100 m, 200 m and 300 m from the farm area in Nangkasawit village were 0.211, 0.107, 0.104 and 0,035 ppm, respectively. The levels of NH3 in Plalangan village were 0.289, 0.231, 0.13 and 0.108 ppm, respectively, and in Sumurejo village were 0.109, 0.110, 0.082 and 0.046 ppm, respectively. The levels of H2S in Nangkasawit, Plalangan and Sumurejo villages at the entire points of observations were <0,002 ppm, with the acceptable standard level of H2S was 0.02 ppm. In four locations of observations, the levels of CH4 in Nangkasawit village were 809, 603, 599 and 521 ppb, in Plalangan village 999, 720, 645 and 582 ppb and in Sumurejo village 932, 824, 526 and 521 ppb. The levels of CO2 in Nangkasawit village were 26.55, 28.35, 28.44 and 30.05 ppm, in Plalangan village 24.65, 25.10, 23.44, 21.05 ppm and in Sumurejo village 28.50, 27.35, 30.68, 31.50 ppm, with the standard level of CO2 should be 30.000 ppm. In conclusion, the air quality was better (lower contamination) with the farther distance of locations from the barn.

  18. Development and Standardization of the Air Force Officer Qualifying Test Form M.

    ERIC Educational Resources Information Center

    Miller, Robert E.

    Air Force Officer Qualifying Test (AFOQT) Form M was constructed as a replacement for AFOQT Form L in Fiscal Year 1974. The new form serves the same purposes as its predecessor and possesses basically the same characteristics. It yields Pilot, Navigator-Technical, Officer Quality, Verbal, and Quantitative composite scores. Three sets of conversion…

  19. The LAAS network observation for studying time correlations in extensive air showers

    NASA Astrophysics Data System (ADS)

    Ochi, Nobuaki; Iyono, A.; Kimura, Hitoomi; Konishi, Takeharu; Nakamura, Toru; Nakatsuka, Takao; Ohara, Soji; Ohmori, Nobuharu; Saito, Katsuhiko; Takahashi, Nobusuke; Tsuji, Shuhei; Wada, Tomonori; Yamamoto, Isao; Yamashita, Yoshihiko; Yanagimoto, Yukio

    2003-02-01

    The Large Area Air Shower (LAAS) group has been performing a network observation of extensive air showers (EAS) since 1996 in Japan. Ten compact EAS arrays are operating simultaneously at distant stations (up to ≍1000 km) and detecting EAS with mean energy of ≍1015 eV. Each station has 4--12 scintillation counters and a Global Positioning System (GPS), which provides time stamps of EAS triggers with an accuracy of 1μs. As a consequence of the comparable time stamps, uniformly-adjusted detectors and a standardized data format among all stations, we can treat the independent observations as a gigantic EAS detector system as a whole. The primary purpose of the network observation is to study large-scale correlations in ultra-high-energy cosmic rays. On the other hand, three nearby stations within 1~km distance at Okayama area have a possibility to detect extremely-high-energy EAS (≍1019 eV) as coincident triggers of the three stations. The present status of the network and some results from computer simulations are reported here.

  20. The burden of COPD mortality due to ambient air pollution in Guangzhou, China

    NASA Astrophysics Data System (ADS)

    Li, Li; Yang, Jun; Song, Yun-Feng; Chen, Ping-Yan; Ou, Chun-Quan

    2016-05-01

    Few studies have investigated the chronic obstructive pulmonary disease (COPD) mortality fraction attributable to air pollution and modification by individual characteristics of air pollution effects. We applied distributed lag non-linear models to assess the associations between air pollution and COPD mortality in 2007-2011 in Guangzhou, China, and the total COPD mortality fraction attributable to air pollution was calculated as well. We found that an increase of 10 μg/m3 in particulate matter with an aerodynamic diameter of 10 μm or less (PM10), sulfur dioxide (SO2) and nitrogen dioxide (NO2) was associated with a 1.58% (95% confidence interval (CI): 0.12-3.06%), 3.45% (95% CI: 1.30-5.66%) and 2.35% (95% CI: 0.42-4.32%) increase of COPD mortality over a lag of 0-15 days, respectively. Greater air pollution effects were observed in the elderly, males and residents with low educational attainment. The results showed 10.91% (95% CI: 1.02-9.58%), 12.71% (95% CI: 5.03-19.85%) and 13.38% (95% CI: 2.67-22.84%) COPD mortality was attributable to current PM10, SO2 and NO2 exposure, respectively. In conclusion, the associations between air pollution and COPD mortality differed by individual characteristics. There were remarkable COPD mortality burdens attributable to air pollution in Guangzhou.

  1. MISR and AirMISR Simultaneously Observe African Grassland Fires

    NASA Technical Reports Server (NTRS)

    2000-01-01

    These images of northeastern South Africa, near Kruger National Park, were acquired on September 7, 2000. The left image shows an 85-kilometer wide x 200-kilometer long area captured by MISR's aftward-viewing 45-degree camera. At lower left are the Drakensberg Mountains; to the east of this range a large burn scar with thin smoke plumes from still-smoldering fires is visible. Near the top of the image another large burn scar with an open-pit mine at its western edge can be seen. Other burn scars are scattered throughout the image.

    Just above the center of the lefthand image is a polygonal burn scar with a set of smoke plumes from actively burning fires at its southwestern tip. The righthand image, which is a 'zoomed-in' view of the area, was acquired almost simultaneously by MISR's airborne counterpart, AirMISR, aboard a NASA ER-2 high-altitude aircraft. AirMISR contains a single camera that rotates to different view angles; when this image was acquired the camera was pointed straight downward. Because the ER-2 aircraft flies at an altitude of 20 kilometers, whereas the Terra spacecraft orbits the Earth 700 kilometers above the ground, the AirMISR image has 35 times finer spatial resolution. The AirMISR image covers about 9 kilometers x 9 kilometers. Unlike the MISR view, the AirMISR data are in 'raw' form and processing to remove radiometric and geometric distortions has not yet been performed.

    Fires such as those shown in the images are deliberately set to burn off dry vegetation, and constitute a widespread agricultural practice in many parts of Africa. These MISR and AirMISR images are part of an international field, aircraft, and satellite data collection and analysis campaign known as SAFARI-2000, the Southern Africa Regional Science Initiative. SAFARI-2000 is designed, in part, to study the effects of large-scale human activities on the regional climate, meteorology, and ecosystems.

    MISR was built and is managed by NASA's Jet Propulsion Laboratory

  2. Observation of Squeezed Light in the 2 μ m Region

    NASA Astrophysics Data System (ADS)

    Mansell, Georgia L.; McRae, Terry G.; Altin, Paul A.; Yap, Min Jet; Ward, Robert L.; Slagmolen, Bram J. J.; Shaddock, Daniel A.; McClelland, David E.

    2018-05-01

    We present the generation and detection of squeezed light in the 2 μ m wavelength region. This experiment is a crucial step in realizing the quantum noise reduction techniques that will be required for future generations of gravitational-wave detectors. Squeezed vacuum is generated via degenerate optical parametric oscillation from a periodically poled potassium titanyl phosphate crystal, in a dual resonant cavity. The experiment uses a frequency stabilized 1984 nm thulium fiber laser, and squeezing is detected using balanced homodyne detection with extended InGaAs photodiodes. We have measured 4.0 ±0.1 dB of squeezing and 10.5 ±0.5 dB of antisqueezing relative to the shot noise level in the audio frequency band, limited by photodiode quantum efficiency. The inferred squeezing level directly after the optical parametric oscillator, after accounting for known losses and phase noise, is 10.7 dB.

  3. Improvement of the GEOS-5 AGCM upon Updating the Air-Sea Roughness Parameterization

    NASA Technical Reports Server (NTRS)

    Garfinkel, C. I.; Molod, A.; Oman, L. D.; Song, I.-S.

    2011-01-01

    The impact of an air-sea roughness parameterization over the ocean that more closely matches recent observations of air-sea exchange is examined in the NASA Goddard Earth Observing System, version 5 (GEOS-5) atmospheric general circulation model. Surface wind biases in the GEOS-5 AGCM are decreased by up to 1.2m/s. The new parameterization also has implications aloft as improvements extend into the stratosphere. Many other GCMs (both for operational weather forecasting and climate) use a similar class of parameterization for their air-sea roughness scheme. We therefore expect that results from GEOS-5 are relevant to other models as well.

  4. Interrelationships among Grain Size, Surface Composition, Air Stability, and Interfacial Resistance of Al-Substituted Li7La3Zr2O12 Solid Electrolytes.

    PubMed

    Cheng, Lei; Wu, Cheng Hao; Jarry, Angelique; Chen, Wei; Ye, Yifan; Zhu, Junfa; Kostecki, Robert; Persson, Kristin; Guo, Jinghua; Salmeron, Miquel; Chen, Guoying; Doeff, Marca

    2015-08-19

    The interfacial resistances of symmetrical lithium cells containing Al-substituted Li7La3Zr2O12 (LLZO) solid electrolytes are sensitive to their microstructures and histories of exposure to air. Air exposure of LLZO samples with large grain sizes (∼150 μm) results in dramatically increased interfacial impedances in cells containing them, compared to those with pristine large-grained samples. In contrast, a much smaller difference is seen between cells with small-grained (∼20 μm) pristine and air-exposed LLZO samples. A combination of soft X-ray absorption (sXAS) and Raman spectroscopy, with probing depths ranging from nanometer to micrometer scales, revealed that the small-grained LLZO pellets are more air-stable than large-grained ones, forming far less surface Li2CO3 under both short- and long-term exposure conditions. Surface sensitive X-ray photoelectron spectroscopy (XPS) indicates that the better chemical stability of the small-grained LLZO is related to differences in the distribution of Al and Li at sample surfaces. Density functional theory calculations show that LLZO can react via two different pathways to form Li2CO3. The first, more rapid, pathway involves a reaction with moisture in air to form LiOH, which subsequently absorbs CO2 to form Li2CO3. The second, slower, pathway involves direct reaction with CO2 and is favored when surface lithium contents are lower, as with the small-grained samples. These observations have important implications for the operation of solid-state lithium batteries containing LLZO because the results suggest that the interfacial impedances of these devices is critically dependent upon specific characteristics of the solid electrolyte and how it is prepared.

  5. Investigation on the charging process of Li 2O 2-based air electrodes in Li-O 2 batteries with organic carbonate electrolytes

    NASA Astrophysics Data System (ADS)

    Xu, Wu; Viswanathan, Vilayanur V.; Wang, Deyu; Towne, Silas A.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Zhang, Ji-Guang

    The charging process of Li 2O 2-based air electrodes in Li-O 2 batteries with organic carbonate electrolytes was investigated using in situ gas chromatography/mass spectroscopy (GC/MS) to analyze gas evolution. A mixture of Li 2O 2/Fe 3O 4/Super P carbon/polyvinylidene fluoride (PVDF) was used as the starting air electrode material, and 1-M lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) in carbonate-based solvents was used as the electrolyte. We found that Li 2O 2 was actively reactive to 1-methyl-2-pyrrolidinone and PVDF that were used to prepare the electrode. During the first charging (up to 4.6 V), O 2 was the main component in the gases released. The amount of O 2 measured by GC/MS was consistent with the amount of Li 2O 2 that decomposed during the electrochemical process as measured by the charge capacity, which is indicative of the good chargeability of Li 2O 2. However, after the cell was discharged to 2.0 V in an O 2 atmosphere and then recharged to ∼4.6 V, CO 2 was dominant in the released gases. Further analysis of the discharged air electrodes by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy indicated that lithium-containing carbonate species (lithium alkyl carbonates and/or Li 2CO 3) were the main discharge products. Therefore, compatible electrolytes and electrodes, as well as the electrode-preparation procedures, need to be developed for rechargeable Li-air batteries for long term operation.

  6. Chandra and VLA Observations of Supermassive Black Hole Outbursts in M87

    NASA Astrophysics Data System (ADS)

    Forman, William; Jones, C.; Churazov, Eugene

    2013-07-01

    We discuss the effects of supermassive black hole (SMBH) outbursts on the hot atmospheres surrounding the central massive galaxies in groups and clusters, as observed with X-ray and radio observations. We focus on a detailed study of the supermassive black hole in M87 at the center of the Virgo cluster using Chandra and VLA observations. We summarize the outburst history and describe the clearly observed energy input from buoyant bubbles of relativistic plasma produced by the central SMBH, uplifted filaments of X-ray emitting gas, and the Mach 1.2 shock together balance the energy lost as gas radiatively cools.

  7. Analysis of air mass trajectories to explain observed variability of tritium in precipitation at the Southern Sierra Critical Zone Observatory, California, USA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Visser, Ate; Thaw, Melissa; Esser, Brad

    Understanding the behavior of tritium, a radioactive isotope of hydrogen, in the environment is important to evaluate the exposure risk of anthropogenic releases, and for its application as a tracer in hydrology and oceanography. To understand and predict the variability of tritium in precipitation, HYSPLIT air mass trajectories were analyzed for 16 aggregate precipitation samples collected over a 2 year period at irregular intervals at a research site located at 2000 m elevation in the southern Sierra Nevada (California, USA). Attributing the variation in tritium to specific source areas confirms the hypothesis that higher latitude or inland sources bring highermore » tritium levels in precipitation than precipitation originating in the lower latitude Pacific Ocean. In this case, the source of precipitation accounts for 79% of the variation observed in tritium concentrations. In conclusion, air mass trajectory analysis is a promising tool to improve the predictions of tritium in precipitation at unmonitored locations and thoroughly understand the processes controlling transport of tritium in the environment.« less

  8. Analysis of air mass trajectories to explain observed variability of tritium in precipitation at the Southern Sierra Critical Zone Observatory, California, USA

    DOE PAGES

    Visser, Ate; Thaw, Melissa; Esser, Brad

    2017-11-20

    Understanding the behavior of tritium, a radioactive isotope of hydrogen, in the environment is important to evaluate the exposure risk of anthropogenic releases, and for its application as a tracer in hydrology and oceanography. To understand and predict the variability of tritium in precipitation, HYSPLIT air mass trajectories were analyzed for 16 aggregate precipitation samples collected over a 2 year period at irregular intervals at a research site located at 2000 m elevation in the southern Sierra Nevada (California, USA). Attributing the variation in tritium to specific source areas confirms the hypothesis that higher latitude or inland sources bring highermore » tritium levels in precipitation than precipitation originating in the lower latitude Pacific Ocean. In this case, the source of precipitation accounts for 79% of the variation observed in tritium concentrations. In conclusion, air mass trajectory analysis is a promising tool to improve the predictions of tritium in precipitation at unmonitored locations and thoroughly understand the processes controlling transport of tritium in the environment.« less

  9. A UAV-based active AirCore system for measurements of greenhouse gases

    NASA Astrophysics Data System (ADS)

    Andersen, Truls; Scheeren, Bert; Peters, Wouter; Chen, Huilin

    2018-05-01

    We developed and field-tested an unmanned aerial vehicle (UAV)-based active AirCore for atmospheric mole fraction measurements of CO2, CH4, and CO. The system applies an alternative way of using the AirCore technique invented by NOAA. As opposed to the conventional concept of passively sampling air using the atmospheric pressure gradient during descent, the active AirCore collects atmospheric air samples using a pump to pull the air through the tube during flight, which opens up the possibility to spatially sample atmospheric air. The active AirCore system used for this study weighs ˜ 1.1 kg. It consists of a ˜ 50 m long stainless-steel tube, a small stainless-steel tube filled with magnesium perchlorate, a KNF micropump, and a 45 µm orifice working together to form a critical flow of dried atmospheric air through the active AirCore. A cavity ring-down spectrometer (CRDS) was used to analyze the air samples on site not more than 7 min after landing for mole fraction measurements of CO2, CH4, and CO. We flew the active AirCore system on a UAV near the atmospheric measurement station at Lutjewad, located in the northwest of the city of Groningen in the Netherlands. Five consecutive flights took place over a 5 h period on the same morning, from sunrise until noon. We validated the measurements of CO2 and CH4 from the active AirCore against those from the Lutjewad station at 60 m. The results show a good agreement between the measurements from the active AirCore and the atmospheric station (N = 146; R2CO2: 0.97 and R2CH4: 0.94; and mean differences: ΔCO2: 0.18 ppm and ΔCH4: 5.13 ppb). The vertical and horizontal resolution (for CH4) at typical UAV speeds of 1.5 and 2.5 m s-1 were determined to be ±24.7 to 29.3 and ±41.2 to 48.9 m, respectively, depending on the storage time. The collapse of the nocturnal boundary layer and the buildup of the mixed layer were clearly observed with three consecutive vertical profile measurements in the early morning hours. Besides

  10. Very Large Array Multiband Monitoring Observations of M31*

    NASA Astrophysics Data System (ADS)

    Yang, Yang; Li, Zhiyuan; Sjouwerman, Loránt O.; Yuan, Feng; Shen, Zhi-Qiang

    2017-08-01

    The Andromeda galaxy (M31) hosts one of the nearest and most quiescent supermassive black holes, which provides a rare, but promising opportunity for studying the physics of black hole accretion at the lowest state. We have conducted a multifrequency, multi-epoch observing campaign, using the Karl G. Jansky Very Large Array (VLA) in its extended configurations in 2011-2012, to advance our knowledge of the still poorly known radio properties of M31*. For the first time, we detect M31* at 10, 15, and 20 GHz and measure its spectral index, α ≈ -0.45 ± 0.08 (S ν ∝ ν α ), over the frequency range of 5-20 GHz. The relatively steep spectrum suggests that the observed radio flux is dominated by the optically thin part of a putative jet, which is located at no more than a few thousand Schwarzschild radii from the black hole. On the other hand, our sensitive radio images show little evidence for an extended component, perhaps except for several parsec-scale “plumes,” the nature of which remains unclear. Our data also reveal significant (a few tens of percent) flux variation of M31* at 6 GHz, on timescales of hours to days. Furthermore, a curious decrease of the mean flux density, by ˜50%, is found between VLA observations taken during 2002-2005 and our new observations, which might be associated with a substantial increase in the mean X-ray flux of M31* starting in 2006.

  11. Very Large Array Multiband Monitoring Observations of M31*

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Yang; Li, Zhiyuan; Sjouwerman, Loránt O.

    The Andromeda galaxy (M31) hosts one of the nearest and most quiescent supermassive black holes, which provides a rare, but promising opportunity for studying the physics of black hole accretion at the lowest state. We have conducted a multifrequency, multi-epoch observing campaign, using the Karl G. Jansky Very Large Array (VLA) in its extended configurations in 2011–2012, to advance our knowledge of the still poorly known radio properties of M31*. For the first time, we detect M31* at 10, 15, and 20 GHz and measure its spectral index, α ≈ −0.45 ± 0.08 (S{sub ν} ∝ ν {sup α}), overmore » the frequency range of 5–20 GHz. The relatively steep spectrum suggests that the observed radio flux is dominated by the optically thin part of a putative jet, which is located at no more than a few thousand Schwarzschild radii from the black hole. On the other hand, our sensitive radio images show little evidence for an extended component, perhaps except for several parsec-scale “plumes,” the nature of which remains unclear. Our data also reveal significant (a few tens of percent) flux variation of M31* at 6 GHz, on timescales of hours to days. Furthermore, a curious decrease of the mean flux density, by ∼50%, is found between VLA observations taken during 2002–2005 and our new observations, which might be associated with a substantial increase in the mean X-ray flux of M31* starting in 2006.« less

  12. Remediation of Chlorinated Solvent Plumes Using In-Situ Air Sparging—A 2-D Laboratory Study

    PubMed Central

    Adams, Jeffrey A.; Reddy, Krishna R.; Tekola, Lue

    2011-01-01

    In-situ air sparging has evolved as an innovative technique for soil and groundwater remediation impacted with volatile organic compounds (VOCs), including chlorinated solvents. These may exist as non-aqueous phase liquid (NAPL) or dissolved in groundwater. This study assessed: (1) how air injection rate affects the mass removal of dissolved phase contamination, (2) the effect of induced groundwater flow on mass removal and air distribution during air injection, and (3) the effect of initial contaminant concentration on mass removal. Dissolved-phase chlorinated solvents can be effectively removed through the use of air sparging; however, rapid initial rates of contaminant removal are followed by a protracted period of lower removal rates, or a tailing effect. As the air flow rate increases, the rate of contaminant removal also increases, especially during the initial stages of air injection. Increased air injection rates will increase the density of air channel formation, resulting in a larger interfacial mass transfer area through which the dissolved contaminant can partition into the vapor phase. In cases of groundwater flow, increased rates of air injection lessened observed downward contaminant migration effect. The air channel network and increased air saturation reduced relative hydraulic conductivity, resulting in reduced groundwater flow and subsequent downgradient contaminant migration. Finally, when a higher initial TCE concentration was present, a slightly higher mass removal rate was observed due to higher volatilization-induced concentration gradients and subsequent diffusive flux. Once concentrations are reduced, a similar tailing effect occurs. PMID:21776228

  13. Remediation of chlorinated solvent plumes using in-situ air sparging--a 2-D laboratory study.

    PubMed

    Adams, Jeffrey A; Reddy, Krishna R; Tekola, Lue

    2011-06-01

    In-situ air sparging has evolved as an innovative technique for soil and groundwater remediation impacted with volatile organic compounds (VOCs), including chlorinated solvents. These may exist as non-aqueous phase liquid (NAPL) or dissolved in groundwater. This study assessed: (1) how air injection rate affects the mass removal of dissolved phase contamination, (2) the effect of induced groundwater flow on mass removal and air distribution during air injection, and (3) the effect of initial contaminant concentration on mass removal. Dissolved-phase chlorinated solvents can be effectively removed through the use of air sparging; however, rapid initial rates of contaminant removal are followed by a protracted period of lower removal rates, or a tailing effect. As the air flow rate increases, the rate of contaminant removal also increases, especially during the initial stages of air injection. Increased air injection rates will increase the density of air channel formation, resulting in a larger interfacial mass transfer area through which the dissolved contaminant can partition into the vapor phase. In cases of groundwater flow, increased rates of air injection lessened observed downward contaminant migration effect. The air channel network and increased air saturation reduced relative hydraulic conductivity, resulting in reduced groundwater flow and subsequent downgradient contaminant migration. Finally, when a higher initial TCE concentration was present, a slightly higher mass removal rate was observed due to higher volatilization-induced concentration gradients and subsequent diffusive flux. Once concentrations are reduced, a similar tailing effect occurs.

  14. The Valley of Mexico: summary of observational studies on its air quality and effects on vegetation.

    PubMed

    de Bauer, L I; Krupa, S V

    1990-01-01

    Present day Mexico City was established on the banks of the now dead Lake Texcoco by Aztec Indians in a.d. 1325. Over time, increasing population growth, urbanization, vehicular traffic and the number of diverse stationary sources, coupled with its topography and the resultant frequency of prevalent stagnant air masses make Mexico City one of the most polluted areas in the world. Use of biological indicator plants since the early 1970s has shown the critical nature of phytotoxic photochemical oxidants in the region. More recent empirical studies with bean, soybean and pine species confirm these observations and raise concern regarding the geographic magnitude of the problem. Surface measurements of air quality in the region are inadequate and require much additional support. Ultimately, ambient air quality measurements must be coupled with the observations on responses of sensitive vegetation. While the results presented in this paper are primarily observational or qualitative, they hopefully serve the purpose of bringing attention to a critical air quality issue in a developing country.

  15. Association between air pollution and daily mortality and hospital admission due to ischaemic heart diseases in Hong Kong

    NASA Astrophysics Data System (ADS)

    Tam, Wilson Wai San; Wong, Tze Wai; Wong, Andromeda H. S.

    2015-11-01

    Ischaemic heart disease (IHD) is one of the leading causes of death worldwide. The effects of air pollution on IHD mortalities have been widely reported. Fewer studies focus on IHD morbidities and PM2.5, especially in Asia. To explore the associations between short-term exposure to air pollution and morbidities and mortalities from IHD, we conducted a time series study using a generalized additive model that regressed the daily numbers of IHD mortalities and hospital admissions on daily mean concentrations of the following air pollutants: nitrogen dioxide (NO2), particulate matter with an aerodynamic diameter less than 10 μm (PM10), particulate matter with an aerodynamic diameter less than 2.5 μm (PM2.5), ozone (O3), and sulfur dioxide (SO2). The relative risks (RR) of IHD deaths and hospital admissions per 10 μg/m3 increase in the concentration of each air pollutant were derived in single pollutant models. Multipollutant models were also constructed to estimate their RRs controlling for other pollutants. Significant RRs were observed for all five air pollutants, ranging from 1.008 to 1.032 per 10 μg/m3 increase in air pollutant concentrations for IHD mortality and from 1.006 to 1.021 per 10 μg/m3 for hospital admissions for IHD. In the multipollutant model, only NO2 remained significant for IHD mortality while SO2 and PM2.5 was significantly associated with hospital admissions. This study provides additional evidence that mortalities and hospital admissions for IHD are significantly associated with air pollution. However, we cannot attribute these health effects to a specific air pollutant, owing to high collinearity between some air pollutants.

  16. Graphene oxide electrocatalyst on MnO2 air cathode as an efficient electron pump for enhanced oxygen reduction in alkaline solution

    NASA Astrophysics Data System (ADS)

    Basirun, Wan Jeffrey; Sookhakian, Mehran; Baradaran, Saeid; Endut, Zulkarnain; Mahmoudian, Mohammad Reza; Ebadi, Mehdi; Yousefi, Ramin; Ghadimi, Hanieh; Ahmed, Sohail

    2015-03-01

    Graphene oxide (GO) was deposited on the surface of a MnO2 air cathode by thermal evaporation at 50°C from a GO colloidal suspension. Fourier transformed infrared spectroscopy and field emission scanning electron microscopy confirmed the presence of GO on the MnO2 air cathode (GO-MnO2). Voltammetry and chrono-amperometry showed increased currents for the oxygen reduction reaction (ORR) in 6 M KOH solution for GO-MnO2 compared to the MnO2 cathode. The GO-MnO2 was used as an air cathode in an alkaline tin-air cell and produced a maximum power density of 13 mW cm-2, in contrast to MnO2, which produced a maximum power density of 9.2 mW cm-2. The electrochemical impedance spectroscopy results suggest that the chemical step for the ORR is the rate determining step, as proposed earlier by different researchers. It is suggested that the presence of GO and electrochemically reduced graphene oxide (ERGO) on the MnO2 surface are responsible for the increased rate of this step, whereby GO and ERGO accelerate the process of electron donation to the MnO2 and to adsorbed oxygen atoms.

  17. The Relationships between Air Exposure, Negative Pressure and Hemolysis

    PubMed Central

    Pohlmann, Joshua R.; Toomasian, John M.; Hampton, Claire E.; Cook, Keith E.; Annich, Gail M.; Bartlett, Robert H.

    2013-01-01

    The purpose of this study was to describe the hemolytic effects of both negative pressure and an air-blood interface independently and in combination in an in-vitro static blood model. Samples of fresh ovine or human blood (5 mL) were subjected to a bubbling air interface (0–100 mL/min) or negative pressure (0–600 mmHg) separately, or in combination, for controlled periods of time, and analyzed for hemolysis. Neither negative pressure nor an air interface alone increased hemolysis. However, when air and negative pressure were combined, hemolysis increased as a function of negative pressure, the air interface, and time. Moreover, when blood samples were exposed to air prior to initiating the test, hemolysis was 4–5 times greater than samples not pre-exposed to air. When these experiments were repeated using freshly drawn human blood the same phenomena were observed, but the hemolysis was significantly higher than that observed in sheep blood. In this model, hemolysis is caused by combined air and negative pressure and is unrelated to either factor alone. PMID:19730004

  18. First observation of magnetoelectric effect in M-type hexaferrite thin films

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mohebbi, Marjan; Ebnabbasi, Khabat; Vittoria, Carmine

    2013-05-07

    The magnetoelectric (ME) effect in M-type hexaferrite thin films is reported. Prior to this work, the ME effect in hexaferrite materials was observed only in bulk polycrystalline materials. Thin films of SrCo{sub 2}Ti{sub 2}Fe{sub 8}O{sub 19} were grown on sapphire (0001) using pulsed laser deposition. The thin films were characterized by X-ray diffractometer, scanning electron microscope, energy-dispersive spectroscopy, vibrating sample magnetometer, and ferromagnetic resonance. We measured saturation magnetization of 1250 G, g-factor of 2.66, and coercive field of 20 Oe for these magnetoelectric M-type hexaferrite thin films. The magnetoelectric effect was confirmed by monitoring the change rate in remanence magnetizationmore » with the application of DC voltage at room temperature and it gave rise to changes in remanence in the order of 12.8% with the application of only 1 V (DC voltage). We deduced a magnetoelectric coupling, {alpha}, of 6.07 Multiplication-Sign 10{sup -9} s m{sup -1} in SrCo{sub 2}Ti{sub 2}Fe{sub 8}O{sub 19} thin films.« less

  19. Estimating Ground-Level PM2.5 by Fusing Satellite and Station Observations: A Geo-Intelligent Deep Learning Approach

    NASA Astrophysics Data System (ADS)

    Li, Tongwen; Shen, Huanfeng; Yuan, Qiangqiang; Zhang, Xuechen; Zhang, Liangpei

    2017-12-01

    Fusing satellite observations and station measurements to estimate ground-level PM2.5 is promising for monitoring PM2.5 pollution. A geo-intelligent approach, which incorporates geographical correlation into an intelligent deep learning architecture, is developed to estimate PM2.5. Specifically, it considers geographical distance and spatiotemporally correlated PM2.5 in a deep belief network (denoted as Geoi-DBN). Geoi-DBN can capture the essential features associated with PM2.5 from latent factors. It was trained and tested with data from China in 2015. The results show that Geoi-DBN performs significantly better than the traditional neural network. The out-of-sample cross-validation R2 increases from 0.42 to 0.88, and RMSE decreases from 29.96 to 13.03 μg/m3. On the basis of the derived PM2.5 distribution, it is predicted that over 80% of the Chinese population live in areas with an annual mean PM2.5 of greater than 35 μg/m3. This study provides a new perspective for air pollution monitoring in large geographic regions.

  20. Strain-induced extinction of hydrogen-air counterflow diffusion flames - Effects of steam, CO2, N2, and O2 additives to air

    NASA Technical Reports Server (NTRS)

    Pellett, G. L.; Northam, G. B.; Wilson, L. G.

    1992-01-01

    A fundamental study was performed using axisymmetric nozzle and tubular opposed jet burners to measure the effects of laminar plug flow and parabolic input velocity profiles on the extinction limits of H2-air counterflow diffusion flames. Extinction limits were quantified by 'flame strength', (average axial air jet velocity) at blowoff of the central flame. The effects of key air contaminants, on the extinction limits, are characterized and analyzed relative to utilization of combustion contaminated vitiated air in high enthalpy supersonic test facilities.

  1. Temperature autocontrol system for the coud%eacute; room of the 1.2 m telescope

    NASA Astrophysics Data System (ADS)

    Zhang, Jian-Hua

    The setting up of temperature autocontrol system for the coudé room of the 1.2 m telescope at Yunnan Observatory and realizing the airflow autocirculation, purified the air, keeping the temperature in the coudé room constantly by autocontrol the heater, and then keeping the optical system in the best condition are introduced in this paper. The autocontrol system is designed and developed at the basis of having only the air circulator and the heater controlled by hand.

  2. Comparison of Gravity Wave Temperature Variances from Ray-Based Spectral Parameterization of Convective Gravity Wave Drag with AIRS Observations

    NASA Technical Reports Server (NTRS)

    Choi, Hyun-Joo; Chun, Hye-Yeong; Gong, Jie; Wu, Dong L.

    2012-01-01

    The realism of ray-based spectral parameterization of convective gravity wave drag, which considers the updated moving speed of the convective source and multiple wave propagation directions, is tested against the Atmospheric Infrared Sounder (AIRS) onboard the Aqua satellite. Offline parameterization calculations are performed using the global reanalysis data for January and July 2005, and gravity wave temperature variances (GWTVs) are calculated at z = 2.5 hPa (unfiltered GWTV). AIRS-filtered GWTV, which is directly compared with AIRS, is calculated by applying the AIRS visibility function to the unfiltered GWTV. A comparison between the parameterization calculations and AIRS observations shows that the spatial distribution of the AIRS-filtered GWTV agrees well with that of the AIRS GWTV. However, the magnitude of the AIRS-filtered GWTV is smaller than that of the AIRS GWTV. When an additional cloud top gravity wave momentum flux spectrum with longer horizontal wavelength components that were obtained from the mesoscale simulations is included in the parameterization, both the magnitude and spatial distribution of the AIRS-filtered GWTVs from the parameterization are in good agreement with those of the AIRS GWTVs. The AIRS GWTV can be reproduced reasonably well by the parameterization not only with multiple wave propagation directions but also with two wave propagation directions of 45 degrees (northeast-southwest) and 135 degrees (northwest-southeast), which are optimally chosen for computational efficiency.

  3. Intra-observer and inter-observer agreements for the measurement of dual-input whole tumor computed tomography perfusion in patients with lung cancer: Influences of the size and inner-air density of tumors.

    PubMed

    Wang, Qingle; Zhang, Zhiyong; Shan, Fei; Shi, Yuxin; Xing, Wei; Shi, Liangrong; Zhang, Xingwei

    2017-09-01

    This study was conducted to assess intra-observer and inter-observer agreements for the measurement of dual-input whole tumor computed tomography perfusion (DCTP) in patients with lung cancer. A total of 88 patients who had undergone DCTP, which had proved a diagnosis of primary lung cancer, were divided into two groups: (i) nodules (diameter ≤3 cm) and masses (diameter >3 cm) by size, and (ii) tumors with and without air density. Pulmonary flow, bronchial flow, and pulmonary index were measured in each group. Intra-observer and inter-observer agreements for measurement were assessed using intraclass correlation coefficient, within-subject coefficient of variation, and Bland-Altman analysis. In all lung cancers, the reproducibility coefficient for intra-observer agreement (range 26.1-38.3%) was superior to inter-observer agreement (range 38.1-81.2%). Further analysis revealed lower agreements for nodules compared to masses. Additionally, inner-air density reduced both agreements for lung cancer. The intra-observer agreement for measuring lung cancer DCTP was satisfied, while the inter-observer agreement was limited. The effects of tumoral size and inner-air density to agreements, especially between two observers, should be emphasized. In future, an automatic computer-aided segment of perfusion value of the tumor should be developed. © 2017 The Authors. Thoracic Cancer published by China Lung Oncology Group and John Wiley & Sons Australia, Ltd.

  4. Nitrogen dioxide observations from the Geostationary Trace ...

    EPA Pesticide Factsheets

    The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument is a test bed for upcoming air quality satellite instruments that will measure backscattered ultraviolet, visible and near-infrared light from geostationary orbit. GeoTASO flew on the NASA Falcon aircraft in its first intensive field measurement campaign during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) Earth Venture Mission over Houston, Texas, in September 2013. Measurements of backscattered solar radiation between 420 and 465 nm collected on 4 days during the campaign are used to determine slant column amounts of NO2 at 250 m  ×  250 m spatial resolution with a fitting precision of 2.2 × 1015 moleculescm−2. These slant columns are converted to tropospheric NO2 vertical columns using a radiative transfer model and trace gas profiles from the Community Multiscale Air Quality (CMAQ) model. Total column NO2 from GeoTASO is well correlated with ground-based Pandora observations (r = 0.90 on the most polluted and cloud-free day of measurements and r = 0.74 overall), with GeoTASO NO2 slightly higher for the most polluted observations. Surface NO2 mixing ratios inferred from GeoTASO using the CMAQ model show good correlation with NO2 measured in situ at the surface during the campaign (r = 0.85). NO2 slant columns from GeoTASO also agree well with prelim

  5. [Detection of mite allergens in the dust of filter-net and air of air-conditioned room].

    PubMed

    Lian, Yu-yin; Liu, Zhi-gang; Wang, Hong-yu; Chai, Cheng-yu; Liu, Xiao-yu

    2007-08-01

    To detect mite allergens in the dust of air conditioner filter-net and floating air in room. Samples were collected from rooms of asthma patient and normal families with or without air conditioner. Der p1, Der f1 and Der 2 were determined by two monoclonal antibody-based ELISA. In asthma patient families, the concentration of airborne Der p1, Der f1 and Der 2 was (0.23 +/- 0.13), (2.62 +/- 1.08), (0.93 +/- 0.41) ng/m3, and (0.56 +/- 0.25), (4.74 +/- 1.22), (2.33 +/- 0.64) ng/m3 respectively before and after the air conditioner switched on, all showing a significant difference (P < 0.05). In families without asthma patient, the concentration of Der p1, Der f1 and Der 2 was (0.33 +/- 0.11), (11.50 +/- 3.08) and (2.10 +/- 0.80) ng/m3, and (0.63 +/- 0.23), (19.80 +/- 4.30) and (3.60 +/- 1.00) ng/m3 respectively before and after the air conditioner switched on, also showing a significant difference (P < 0.05). From the filter-net dust of air conditioner in family with allergic asthma patient, the concentration of Der p1, Der f1 and Der 2 was (0.52 +/- 0.19), (3.34 +/- 0.63), (2.53 +/- 0.65) microg/g dust, while that of normal families was (1.30 +/- 0.35), (5.16 +/- 0.92), (3.47 +/- 1.13) microg/g dust respectively. The concentration of Der f1 and Der 2 at both asthma families and normal families was higher than 2 microg/g, an allergen concentration threshold. Mite allergens exist in the filter-net dust of air conditioner, which may be an important source of indoor allergens and a cause of the increasing prevalence of allergic asthma.

  6. Air pollution during pregnancy and childhood cognitive and psychomotor development: six European birth cohorts.

    PubMed

    Guxens, Mònica; Garcia-Esteban, Raquel; Giorgis-Allemand, Lise; Forns, Joan; Badaloni, Chiara; Ballester, Ferran; Beelen, Rob; Cesaroni, Giulia; Chatzi, Leda; de Agostini, Maria; de Nazelle, Audrey; Eeftens, Marloes; Fernandez, Mariana F; Fernández-Somoano, Ana; Forastiere, Francesco; Gehring, Ulrike; Ghassabian, Akhgar; Heude, Barbara; Jaddoe, Vincent W V; Klümper, Claudia; Kogevinas, Manolis; Krämer, Ursula; Larroque, Béatrice; Lertxundi, Aitana; Lertxuni, Nerea; Murcia, Mario; Navel, Vladislav; Nieuwenhuijsen, Mark; Porta, Daniela; Ramos, Rosa; Roumeliotaki, Theano; Slama, Rémy; Sørensen, Mette; Stephanou, Euripides G; Sugiri, Dorothea; Tardón, Adonina; Tiemeier, Henning; Tiesler, Carla M T; Verhulst, Frank C; Vrijkotte, Tanja; Wilhelm, Michael; Brunekreef, Bert; Pershagen, Göran; Sunyer, Jordi

    2014-09-01

    Accumulating evidence from laboratory animal and human studies suggests that air pollution exposure during pregnancy affects cognitive and psychomotor development in childhood. We analyzed data from 6 European population-based birth cohorts-GENERATION R (The Netherlands), DUISBURG (Germany), EDEN (France), GASPII (Italy), RHEA (Greece), and INMA (Spain)-that recruited mother-infant pairs from 1997 to 2008. Air pollution levels-nitrogen oxides (NO2, NOx) in all regions and particulate matter (PM) with diameters of <2.5, <10, and 2.5-10 μm (PM2.5, PM10, and PMcoarse, respectively) and PM2.5 absorbance in a subgroup-at birth addresses were estimated by land-use regression models, based on monitoring campaigns performed primarily between 2008 and 2011. Levels were back-extrapolated to exact pregnancy periods using background monitoring sites. Cognitive and psychomotor development was assessed between 1 and 6 years of age. Adjusted region-specific effect estimates were combined using random-effects meta-analysis. A total of 9482 children were included. Air pollution exposure during pregnancy, particularly NO2, was associated with reduced psychomotor development (global psychomotor development score decreased by 0.68 points [95% confidence interval = -1.25 to -0.11] per increase of 10 μg/m in NO2). Similar trends were observed in most regions. No associations were found between any air pollutant and cognitive development. Air pollution exposure during pregnancy, particularly NO2 (for which motorized traffic is a major source), was associated with delayed psychomotor development during childhood. Due to the widespread nature of air pollution exposure, the public health impact of the small changes observed at an individual level could be considerable.

  7. Oxidation of SO2 by NO2 and air in an aqueous suspension of carbon

    NASA Technical Reports Server (NTRS)

    Rogowski, R. S.; Schryer, D. R.; Cofer, W. R., III; Edahl, R. A., Jr.; Munavalli, S.

    1982-01-01

    A series of experiments has been performed using carbon black as a surrogate for soot particles. Carbon black was suspended in water and gas mixtures were bubbled into the suspensions to observe the effect of carbon particles on the oxidation of SO2 by air and NO2. Identical gas mixtures were bubbled into a black containing only pure water. After exposure each solution was analyzed for pH and sulfate. It was found that NO2 greatly enhances the oxidation of SO2 to sulfate in the presence of carbon black. The amount of sulfate in the blanks was significantly less. Under the conditions of the experiments no saturation of the reaction was observed and SO2 was converted to sulfate even in a highly acid medium (pH not less than 1.5).

  8. Air Cushion Equipment Transporter (ACET) Testing. Volume 2.

    DTIC Science & Technology

    1986-10-01

    m: lllllhllllEEE 1.0. 1-2-5 w lw w w w w -- * e %. f~n4% AD-A188 369 AFWAL-TR-86-3088 VOLUME 11 AIR CUSHION EQ~UIPuMNT TRNSPO’jRTERi (ACET) TESTING T.D... E . COLCLOUGH, J Chief Vehicle E eupment Division .. If your address has changed, if you wish to be removed from our mailing list, or if the addressee...and ZIP CodeI 10. SOURCE OF FUNDING NOS. PROGRAM PROJECT TASK WORK UNIT ELEMENT NO. NO NO NO II TITLE (includ. Securito C f e ,,n 62201F 2402 01 34 12

  9. Operational performance of a low cost, air mass 2 solar simulator

    NASA Technical Reports Server (NTRS)

    Yass, K.; Curtis, H. B.

    1975-01-01

    Modifications and improvements on a low cost air mass 2 solar simulator are discussed. The performance characteristics of total irradiance, uniformity of irradiance, spectral distribution, and beam subtense angle are presented. The simulator consists of an array of tungsten halogen lamps hexagonally spaced in a plane. A corresponding array of plastic Fresnel lenses shapes the output beam such that the simulator irradiates a 1.2 m by 1.2 m area with uniform collimated irradiance. Details are given concerning individual lamp output measurements and placement of the lamps. Originally, only the direct component of solar irradiance was simulated. Since the diffuse component may affect the performance of some collectors, the capability to simulate it is being added. An approach to this diffuse addition is discussed.

  10. ALMA observation of the disruption of molecular gas in M87

    NASA Astrophysics Data System (ADS)

    Simionescu, A.; Tremblay, G.; Werner, N.; Canning, R. E. A.; Allen, S. W.; Oonk, J. B. R.

    2018-04-01

    We present the results from Atacama Large Millimeter Array (ALMA) observations centred 40 arcsec (3 kpc in projection) south-east of the nucleus of M87. We report the detection of extended CO (2-1) line emission with a total flux of (5.5 ± 0.6) × 10-18 erg s-1 cm-2 and corresponding molecular gas mass M_{H_2}=(4.7 ± 0.4) × 10^5 M_{⊙}, assuming a Galactic CO to H2 conversion factor. ALMA data indicate a line-of-sight velocity of -129 ± 3 km s-1, in good agreement with measurements based on the [C II] and H α+[N II] lines, and a velocity dispersion of σ = 27 ± 3 km s-1. The CO (2-1) emission originates only outside the radio lobe of the active galactic nucleus (AGN) seen in the 6 cm Very Large Array image, while the filament prolongs further inwards at other wavelengths. The molecular gas in M87 appears to be destroyed or excited by AGN activity, either by direct interaction with the radio plasma, or by the shock driven by the lobe into the X-ray emitting atmosphere. This is an important piece of the puzzle in understanding the impact of the central AGN on the amount of the coldest gas from which star formation can proceed.

  11. Experimental Air-Broadened Line Parameters in the nu2 Band of CH3D

    NASA Technical Reports Server (NTRS)

    Cross, Adriana Predoi; Brawley-Tremblay, Shannon; Povey, Chad; Smith, Mary Ann H.

    2007-01-01

    In this study we report the first experimental measurements of air-broadening and air-induced pressure-shift coefficients for approximately 378 transitions in the nu2 fundamental band of CH3D. These results were obtained from analysis of 17 room temperature laboratory absorption spectra recorded at 0.0056 cm(exp -1) resolution using the McMath-Pierce Fourier transform spectrometer located on Kitt Peak, Arizona. Three absorption cells with path lengths of 10.2, 25 and 150 cm were used to record the spectra. The total sample pressures ranged from 0.129x10(exp -2) to 52.855x10(exp -2) atm with CH3D volume mixing ratios of approximately 0.0109 in air. The spectra were analyzed using a multispectrum non-linear least-squares fitting technique. We report measurements for air pressure-broadening coefficients for transitions with quantum numbers as high as J" = 20 and K = 15, where K" = K' equivalent to K (for a parallel band). The measured air broadening coefficients range from 0.0205 to 0.0835 cm(exp -1) atm(exp -1) at 296 K. All the measured pressure-shift coefficients are negative and are found to vary from about -0.0005 to -0.0080 cm(exp -1) atm(exp -1) at the temperature of the spectra. We have examined the dependence of the measured broadening and shift parameters on the J" and K quantum numbers and also developed empirical expressions to describe the broadening coefficients in terms of m (m = -J", J" and J" + 1 in the (sup Q)P- (sup Q)Q-, and (sup Q)R-branch, respectively) and K. On average, the empirical expressions reproduce the measured broadening coefficients to within 4.4%.

  12. A Look at Hurricane Matthew from NASA AIRS

    NASA Image and Video Library

    2016-10-06

    Hurricane Matthew, currently an extremely dangerous Category 4 storm on the Saffir-Simpson Hurricane Wind Scale, continues to bear down on the southeastern United States. At 11:27 a.m. PDT (2:27 p.m. EDT and 18:23 UT) today, NASA's Atmospheric Infrared Sounder (AIRS) instrument aboard NASA's Aqua satellite observed the storm as its eye was passing over the Bahamas. An AIRS false-color infrared image shows that the northeast and southwest quadrants of the storm had the coldest cloud tops, denoting the regions of the storm where the strongest precipitation was occurring at the time. Data from the Advanced Microwave Sounding Unit (AMSU), another of AIRS' suite of instruments, indicate that the northeast quadrant, which appears smaller in the infrared image, likely had the most intense rain bands at the time. The AIRS infrared image shows that at the time of the image the storm had full circulation, with a small eye surrounded by a thick eye wall and can be seen at http://photojournal.jpl.nasa.gov/catalog/PIA21092.

  13. Trends and sources vs air mass origins in a major city in South-western Europe: Implications for air quality management.

    PubMed

    Fernández-Camacho, R; de la Rosa, J D; Sánchez de la Campa, A M

    2016-05-15

    This study presents a 17-years air quality database comprised of different parameters corresponding to the largest city in the south of Spain (Seville) where atmospheric pollution is frequently attributed to traffic emissions and is directly affected by Saharan dust outbreaks. We identify the PM10 contributions from both natural and anthropogenic sources in this area associated to different air mass origins. Hourly, daily and seasonal variation of PM10 and gaseous pollutant concentrations (CO, NO2 and SO2), all of them showing negative trends during the study period, point to the traffic as one of the main sources of air pollution in Seville. Mineral dust, secondary inorganic compounds (SIC) and trace elements showed higher concentrations under North African (NAF) air mass origins than under Atlantic. We observe a decreasing trend in all chemical components of PM10 under both types of air masses, NAF and Atlantic. Principal component analysis using more frequent air masses in the area allows the identification of five PM10 sources: crustal, regional, marine, traffic and industrial. Natural sources play a more relevant role during NAF events (20.6 μg · m(-3)) than in Atlantic episodes (13.8 μg · m(-3)). The contribution of the anthropogenic sources under NAF doubles the one under Atlantic conditions (33.6 μg · m(-3) and 15.8 μg · m(-3), respectively). During Saharan dust outbreaks the frequent accumulation of local anthropogenic pollutants in the lower atmosphere results in poor air quality and an increased risk of mortality. The results are relevant when analysing the impact of anthropogenic emissions on the exposed population in large cities. The increase in potentially toxic elements during Saharan dust outbreaks should also be taken into account when discounting the number of exceedances attributable to non-anthropogenic or natural origins. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. Detection and quantification of reactive oxygen species (ROS) in indoor air.

    PubMed

    Montesinos, V Nahuel; Sleiman, Mohamad; Cohn, Sebastian; Litter, Marta I; Destaillats, Hugo

    2015-06-01

    Reactive oxygen species (ROS), such as free radicals and peroxides, are environmental trace pollutants potentially associated with asthma and airways inflammation. These compounds are often not detected in indoor air due to sampling and analytical limitations. This study developed and validated an experimental method to sample, identify and quantify ROS in indoor air using fluorescent probes. Tests were carried out simultaneously using three different probes: 2',7'-dichlorofluorescin (DCFH) to detect a broad range of ROS, Amplex ultra Red® (AuR) to detect peroxides, and terephthalic acid (TPA) to detect hydroxyl radicals (HO(•)). For each test, air samples were collected using two impingers in series kept in an ice bath, containing each 10 mL of 50 mM phosphate buffer at pH 7.2. In tests with TPA, that probe was also added to the buffer prior to sampling; in the other two tests, probes and additional reactants were added immediately after sampling. The concentration of fluorescent byproducts was determined fluorometrically. Calibration curves were developed by reacting DCFH and AuR with known amounts of H2O2, and using known amounts of 2-hydroxyterephthalic acid (HTPA) for TPA. Low detection limits (9-13 nM) and quantification limits (18-22 nM) were determined for all three probes, which presented a linear response in the range 10-500 nM for AuR and TPA, and 100-2000 nM for DCFH. High collection efficiency (CE) and recovery efficiency (RE) were observed for DCFH (CE=RE=100%) and AuR (CE=100%; RE=73%) by sampling from a laboratory-developed gas phase H2O2 generator. Interference of co-occurring ozone was evaluated and quantified for the three probes by sampling from the outlet of an ozone generator. The method was demonstrated by sampling air emitted by two portable air cleaners: a strong ozone generator (AC1) and a plasma generator (AC2). High ozone levels emitted by AC1 did not allow for simultaneous determination of ROS levels due to high background levels

  15. Selective Metal Exsolution in BaFe 2-yMy(PO 4) 2 (M = Co 2+, Ni 2+) Solid Solutions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Alcover, Ignacio Blazquez; Daviero-Minaud, Sylvie; David, Rénald

    2015-08-19

    The 2D-Ising ferromagnetic phase BaFe 2+ 2(PO 4) 2 shows exsolution of up to one-third of its iron content (giving BaFe 3+ 1.33(PO 4) 2) under mild oxidation conditions, leading to nanosized Fe 2O 3 exsolved clusters. Here we have prepared BaFe 2–yMy(PO 4) 2 (M = Co 2+, Ni 2+; y = 0, 0.5, 1, 1.5) solid solutions to investigate the feasibility and selectivity of metal exsolution in these mixed metallic systems. For all the compounds, after 600 °C thermal treatment in air, a complete oxidation of Fe 2+ to Fe 3+ leaves stable M 2+ ions, as verifiedmore » by 57Fe Mössbauer spectroscopy, TGA, TEM, microprobe, and XANES. Furthermore, the size of the nanometric α-Fe 2O 3clusters coating the main phase strongly depends on the y M metal concentration. For M-rich phases the iron diffusion is hampered so that a significant fraction of superparamagnetic α-Fe2O3 particles (100% for BaFe 0.5–xCo 1.5(PO 4) 2) was detected even at 78 K. Although Ni 2+and Co 2+ ions tend to block Fe diffusion, the crystal structure of BaFe 0.67Co 1(PO 4) 2demonstrates a fully ordered rearrangement of Fe 3+ and Co 2+ ions after Fe exsolution. We found that the magnetic behaviors of the Fe-depleted materials are mostly dominated by antiferromagnetic exchange, while Co 2+-rich compounds show metamagnetic transitions reminiscent of the BaCo 2(PO 4) 2 soft helicoidal magnet.« less

  16. Attaining whole-ecosystem warming using air and deep-soil heating methods with an elevated CO2 atmosphere

    NASA Astrophysics Data System (ADS)

    Hanson, Paul J.; Riggs, Jeffery S.; Nettles, W. Robert; Phillips, Jana R.; Krassovski, Misha B.; Hook, Leslie A.; Gu, Lianhong; Richardson, Andrew D.; Aubrecht, Donald M.; Ricciuto, Daniel M.; Warren, Jeffrey M.; Barbier, Charlotte

    2017-02-01

    This paper describes the operational methods to achieve and measure both deep-soil heating (0-3 m) and whole-ecosystem warming (WEW) appropriate to the scale of tall-stature, high-carbon, boreal forest peatlands. The methods were developed to allow scientists to provide a plausible set of ecosystem-warming scenarios within which immediate and longer-term (1 decade) responses of organisms (microbes to trees) and ecosystem functions (carbon, water and nutrient cycles) could be measured. Elevated CO2 was also incorporated to test how temperature responses may be modified by atmospheric CO2 effects on carbon cycle processes. The WEW approach was successful in sustaining a wide range of aboveground and belowground temperature treatments (+0, +2.25, +4.5, +6.75 and +9 °C) in large 115 m2 open-topped enclosures with elevated CO2 treatments (+0 to +500 ppm). Air warming across the entire 10 enclosure study required ˜ 90 % of the total energy for WEW ranging from 64 283 mega Joules (MJ) d-1 during the warm season to 80 102 MJ d-1 during cold months. Soil warming across the study required only 1.3 to 1.9 % of the energy used ranging from 954 to 1782 MJ d-1 of energy in the warm and cold seasons, respectively. The residual energy was consumed by measurement and communication systems. Sustained temperature and elevated CO2 treatments were only constrained by occasional high external winds. This paper contrasts the in situ WEW method with closely related field-warming approaches using both aboveground (air or infrared heating) and belowground-warming methods. It also includes a full discussion of confounding factors that need to be considered carefully in the interpretation of experimental results. The WEW method combining aboveground and deep-soil heating approaches enables observations of future temperature conditions not available in the current observational record, and therefore provides a plausible glimpse of future environmental conditions.

  17. M2-F1 on lakebed with pilot Milt Thompson

    NASA Technical Reports Server (NTRS)

    1963-01-01

    NASA Flight Research Pilot Milt Thompson, shown here on the lakebed with the M2-F1 lifting body, was an early backer of R. Dale Reed's lifting-body proposal. He urged Flight Research Center director Paul Bikle to approve the M2-F1's construction. Thompson also made the first glide flights in both the M2-F1 and its successor, the heavyweight M2-F2. The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, NASA Flight Research Center (later Dryden Flight Research Center, Edwards, CA) management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with the largest engine available. He took the car to Bill Straup's renowned hot-rod shop near Long Beach for modification. With a special gearbox and racing slicks, the Pontiac could tow the 1,000-pound M2-F1 110 miles per hour in 30 seconds. It proved

  18. Improvements to the OMI Near-uv Aerosol Algorithm Using A-train CALIOP and AIRS Observations

    NASA Technical Reports Server (NTRS)

    Torres, O.; Ahn, C.; Zhong, C.

    2014-01-01

    The height of desert dust and carbonaceous aerosols layers and, to a lesser extent, the difficulty in assessing the predominant size mode of these absorbing aerosol types, are sources of uncertainty in the retrieval of aerosol properties from near UV satellite observations. The availability of independent, near-simultaneous measurements of aerosol layer height, and aerosol-type related parameters derived from observations by other A-train sensors, makes possible the direct use of these parameters as input to the OMI (Ozone Monitoring Instrument) near UV retrieval algorithm. A monthly climatology of aerosol layer height derived from observations by the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) sensor, and real-time AIRS (Atmospheric Infrared Sounder) CO observations are used in an upgraded version of the OMI near UV aerosol algorithm. AIRS CO measurements are used as a reliable tracer of carbonaceous aerosols, which allows the identification of smoke layers in areas and times of the year where the dust-smoke differentiation is difficult in the near-UV. The use of CO measurements also enables the identification of elevated levels of boundary layer pollution undetectable by near UV observations alone. In this paper we discuss the combined use of OMI, CALIOP and AIRS observations for the characterization of aerosol properties, and show a significant improvement in OMI aerosol retrieval capabilities.

  19. Summer outbursts in the coma of 67P/Churyumov-Gerasimenko as observed by VIRTIS-M

    NASA Astrophysics Data System (ADS)

    Rinaldi, G.; Bockelee-Morvan, D.; Ciarniello, M.; Tozzi, G. P.; Capaccioni, F.; Filacchione, G.; Fink, U.; Doose, L.; Raponi, A.; Capria, M. T.; Erard, S.; Leyrat, C.; Longobardo, A.; Taylor, F.

    2017-09-01

    In this work, we present an analysis of the outbursts observed by VIRTIS-M for the dates of August 10, September 13 and 14 2015, when the comet was at heliocentric distances of -1.2 AU (inbound) to 1.3 AU (outbound), 2 day before and one month after the perihelion passage respectively. They are characterized by a sudden and short increase of the dust emission, from localized areas with variable degree of collimation, followed by a sweet decrease of activity. The lifetime is between 5 and 15 minutes and the corresponding radiance at 0.55 μm is typically of the order of 10-2 - 1 Watt/m2/str/μm, i.e. 10-20 times larger than the surrounding coma. VIRTIS-M identified 2 main dust plumes morphologies associated to these events: a narrow jet and a broad plumes. We found clear evidence of different colour values in the ouburst with respect to the surrounding coma. This implies that we observed dust with different physical characteristics both in the structures and in the coma. The comparison between IR (VIRTIS-H) and VIS (VIRTISM) observations allows to derive the projected velocity of the small dust grain obtaining 23 -40 m/s. It is also possible to estimate the total mass loss in the outburst, by converting the radiance over an image to a dust cross section, and then to mass assuming a dust size distribution with a power law index of -3. For September 14 large event we estimated a total ejected dust mass of few tens tons as found by Vincent et al. 2016.

  20. Comparison of regional air dispersion simulation and ambient air monitoring data for the soil fumigant 1,3-dichloropropene.

    PubMed

    van Wesenbeeck, I J; Cryer, S A; de Cirugeda Helle, O; Li, C; Driver, J H

    2016-11-01

    SOFEA v2.0 is an air dispersion modeling tool used to predict acute and chronic pesticide concentrations in air for large air sheds resulting from agronomic practices. A 1,3-dichloropropene (1,3-D) air monitoring study in high use townships in Merced County, CA, logged 3-day average air concentrations at nine locations over a 14.5month period. SOFEA, using weather data measured at the site, and using a historical CDPR regulatory assumption of a constant 320m mixing height, predicted the general pattern and correct order of magnitude for 1,3-D air concentrations as a function of time, but failed to estimate the highest observed 1,3-D concentrations of the monitoring study. A time series and statistical comparison of the measured and modeled data indicated that the model underestimated 1,3-D concentrations during calm periods (wind speed <1m/s), such that the annual average concentration was under predicted by approximately 4.7-fold, and the variability was not representative of the measured data. Calm periods are associated with low mixing heights (MHs) and are more prevalent in the Central Valley of CA during the winter months, and thus the assumption of a constant 320m mixing height is not appropriate. An algorithm was developed to calculate the MH using the air temperature in the weather file when the wind speed was <1m/s. When the model was run using the revised MHs, the average of the modeled 1,3-D concentration Probability Distribution Function (PDF) was within 5% of the measured PDF, and the variability in modeled concentrations more closely matched the measured dataset. Use of the PCRAMMET processed weather data from the site (including PCRAMMET MH) resulted in the global annual average concentration within 2-fold of measured data. Receptor density was also found to have an effect on the modeled 1,3-D concentration PDF, and a 50×50 receptor grid in the nine township domain captured the measured 1,3-D concentration distribution much better than a 3×3

  1. 90-year-old firn air from Styx glacier, East Antarctica

    NASA Astrophysics Data System (ADS)

    Jang, Y.; Ahn, J.; Buizert, C.; Lee, H. G.; Hong, S.; Han, Y.; Jun, S. J.; Hur, S. D.

    2017-12-01

    Firn is the upper part of the glacier that has not yet been completely changed to the ice. In this layer, firn air can move through the open pores and be pumped for sampling. We obtained firn air and ice cores from Styx glacier (73°51'95″ S, 163°41'217″ E, 1623m asl.), East Antarctica during 2014-2015. The Styx glacier is located near coast, and has an accumulation rate of 0.13 Mgm-2y-1 with a mean annual temperature of -31.7 °. We found that the lock-in depth (depth where gas diffusion starts to stop, "LID") is 52.4 m and bubble close-off depth (the depth to the snow-ice transition perfectly, "COD") is 65.1 m. Therefore lock-in zone (between LID and COD, "LIZ") is 52.4 - 65.1 m. Concentrations of greenhouse gases (CO2, CH4, n=13) in the firn air were analyzed at US National Oceanic and Atmospheric Administration (NOAA) and 15N of N2 was measured at the Scripps Institution of Oceanography (SIO). We find that the firn air ages are up to about 90 years, the oldest firn air ages observed among coastal glaciers. In order to better understand physical properties and chemical composition, methane concentration and total air content of the closed bubbles in the LIZ (3 cm resolution, n=124) were analyzed by a wet extraction method at Seoul National University. The CH4 concentration and total air content show large variations in cm-scale depth intervals, and they are anti-correlated with each other. The CH4 concentration changes in a few cm corresponds to up to 40 years in CH4 age. We also applied Centre for Ice and Climate (CIC) 1-dimensional diffusion model and simulated greenhouse gas concentration profiles to quantitatively understand how the air moves in the Styx firn column. We hypothesize that density variations in the firn may increase thickness of LIZ and consequently increase of firn gas ages.

  2. Adult lung function and long-term air pollution exposure. ESCAPE: a multicentre cohort study and meta-analysis.

    PubMed

    Adam, Martin; Schikowski, Tamara; Carsin, Anne Elie; Cai, Yutong; Jacquemin, Benedicte; Sanchez, Margaux; Vierkötter, Andrea; Marcon, Alessandro; Keidel, Dirk; Sugiri, Dorothee; Al Kanani, Zaina; Nadif, Rachel; Siroux, Valérie; Hardy, Rebecca; Kuh, Diana; Rochat, Thierry; Bridevaux, Pierre-Olivier; Eeftens, Marloes; Tsai, Ming-Yi; Villani, Simona; Phuleria, Harish Chandra; Birk, Matthias; Cyrys, Josef; Cirach, Marta; de Nazelle, Audrey; Nieuwenhuijsen, Mark J; Forsberg, Bertil; de Hoogh, Kees; Declerq, Christophe; Bono, Roberto; Piccioni, Pavilio; Quass, Ulrich; Heinrich, Joachim; Jarvis, Deborah; Pin, Isabelle; Beelen, Rob; Hoek, Gerard; Brunekreef, Bert; Schindler, Christian; Sunyer, Jordi; Krämer, Ursula; Kauffmann, Francine; Hansell, Anna L; Künzli, Nino; Probst-Hensch, Nicole

    2015-01-01

    The chronic impact of ambient air pollutants on lung function in adults is not fully understood. The objective of this study was to investigate the association of long-term exposure to ambient air pollution with lung function in adult participants from five cohorts in the European Study of Cohorts for Air Pollution Effects (ESCAPE). Residential exposure to nitrogen oxides (NO₂, NOx) and particulate matter (PM) was modelled and traffic indicators were assessed in a standardised manner. The spirometric parameters forced expiratory volume in 1 s (FEV₁) and forced vital capacity (FVC) from 7613 subjects were considered as outcomes. Cohort-specific results were combined using meta-analysis. We did not observe an association of air pollution with longitudinal change in lung function, but we observed that a 10 μg·m(-3) increase in NO₂ exposure was associated with lower levels of FEV₁ (-14.0 mL, 95% CI -25.8 to -2.1) and FVC (-14.9 mL, 95% CI -28.7 to -1.1). An increase of 10 μg·m(-3) in PM10, but not other PM metrics (PM2.5, coarse fraction of PM, PM absorbance), was associated with a lower level of FEV₁ (-44.6 mL, 95% CI -85.4 to -3.8) and FVC (-59.0 mL, 95% CI -112.3 to -5.6). The associations were particularly strong in obese persons. This study adds to the evidence for an adverse association of ambient air pollution with lung function in adults at very low levels in Europe. Copyright ©ERS 2015.

  3. Observations and Modeling of Turbulent Air-Sea Coupling in Coastal and Strongly Forced Condition

    NASA Astrophysics Data System (ADS)

    Ortiz-Suslow, David G.

    The turbulent fluxes of momentum, mass, and energy across the ocean-atmosphere boundary are fundamental to our understanding of a myriad of geophysical processes, such as wind-wave generation, oceanic circulation, and air-sea gas transfer. In order to better understand these fluxes, empirical relationships were developed to quantify the interfacial exchange rates in terms of easily observed parameters (e.g., wind speed). However, mounting evidence suggests that these empirical formulae are only valid over the relatively narrow parametric space, i.e. open ocean conditions in light to moderate winds. Several near-surface processes have been observed to cause significant variance in the air-sea fluxes not predicted by the conventional functions, such as a heterogeneous surfaces, swell waves, and wave breaking. Further study is needed to fully characterize how these types of processes can modulate the interfacial exchange; in order to achieve this, a broad investigation into air-sea coupling was undertaken. The primary focus of this work was to use a combination of field and laboratory observations and numerical modeling, in regimes where conventional theories would be expected to breakdown, namely: the nearshore and in very high winds. These seemingly disparate environments represent the marine atmospheric boundary layer at its physical limit. In the nearshore, the convergence of land, air, and sea in a depth-limited domain marks the transition from a marine to a terrestrial boundary layer. Under extreme winds, the physical nature of the boundary layer remains unknown as an intermediate substrate layer, sea spray, develops between the atmosphere and ocean surface. At these ends of the MABL physical spectrum, direct measurements of the near-surface processes were made and directly related to local sources of variance. Our results suggest that the conventional treatment of air-sea fluxes in terms of empirical relationships developed from a relatively narrow set of

  4. Characteristics of vertical air motion in isolated convective clouds

    DOE PAGES

    Yang, Jing; Wang, Zhien; Heymsfield, Andrew J.; ...

    2016-08-11

    The vertical velocity and air mass flux in isolated convective clouds are statistically analyzed using aircraft in situ data collected from three field campaigns: High-Plains Cumulus (HiCu) conducted over the midlatitude High Plains, COnvective Precipitation Experiment (COPE) conducted in a midlatitude coastal area, and Ice in Clouds Experiment-Tropical (ICE-T) conducted over a tropical ocean. The results show that small-scale updrafts and downdrafts (<  500 m in diameter) are frequently observed in the three field campaigns, and they make important contributions to the total air mass flux. The probability density functions (PDFs) and profiles of the observed vertical velocity are provided. The PDFsmore » are exponentially distributed. The updrafts generally strengthen with height. Relatively strong updrafts (>  20 m s −1) were sampled in COPE and ICE-T. The observed downdrafts are stronger in HiCu and COPE than in ICE-T. The PDFs of the air mass flux are exponentially distributed as well. The observed maximum air mass flux in updrafts is of the order 10 4 kg m −1 s −1. The observed air mass flux in the downdrafts is typically a few times smaller in magnitude than that in the updrafts. Since this study only deals with isolated convective clouds, and there are many limitations and sampling issues in aircraft in situ measurements, more observations are needed to better explore the vertical air motion in convective clouds.« less

  5. Characterization of outdoor air particles as source of impurities in supply air

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pasanen, P.; Kalliokoski, P.; Tuomainen, A.

    1997-12-31

    Odor emission of supply air filters has proved to be a major source of stuffy odor of supply air. In this study, the odor emission characteristics of outdoor air particles and odor emissions of coarse prefilters and fine filters were studied. The outdoor air samples were collected by the aid of high volume impactor. Odor emissions of the size fractions, < 2.1 {micro}m , 2.1--10 {micro}m and >10 {micro}m were studied separately in laboratory with a trained olf panel: The odor emissions of the ventilation filters in real use were evaluated five times during the 14 month study period. Aftermore » the field evaluation the emissions of carbonyl compounds and other volatile organic compounds. The odor emissions of outdoor air particles were the highest during the heating season and lowest in the summer. The particles in the coarsest fraction had the most abundant emissions (1,200 olf/g) while the emissions from fine particles were lowest (100 olf/g). The odor emissions evaluated from the coarse and fine ventilation filters supported the finding that particles collected on coarse prefilter had the most abundant odor emission.« less

  6. Screen-level data assimilation of observations and pseudo-observations in COSMO-I2

    NASA Astrophysics Data System (ADS)

    Milelli, Dr.; Turco, Dr.; Cane, Dr.; Oberto, Dr.; Pelosini, Dr.

    2009-09-01

    general a positive impact during the assimilation cycle and below 1000-1500 m respectively and a neutral impact elsewhere, because the effect of the nudging vanishes a few hours after the end of the assimilation. As a second step, we introduced the assimilation of the 2 m temperature forecasts given by the Multimodel SuperEnsemble technique for all the available stations of the ARPA Piemonte network into the model, as if they were observations (we call them pseudo-observations), from +12h to +24h. The Multimodel SuperEnsemble technique is a powerful post-processing method for the estimation of weather forecast parameters. Several model outputs are combined, using weights calculated during a so-called training period. This technique has already been tested and implemented in many works on limited-area models in order to obtain reliable forecasts in complex orography regions. Also in this case we observe a positive impact mainly on the surface variables, but the effect lasts up to +24h.

  7. Observations of M87 and Hydra A at 90 GHz

    NASA Technical Reports Server (NTRS)

    Cotton, W. D.; Mason, B. S.; Dicker, S.; Korngut, P.; Devlin, M. J.; Aquirre, J.; Benford, D.; Moseley, H.; Staguhn, J.; Irwin, K.; hide

    2009-01-01

    This paper presents new observations of the AGNs M87 and Hydra A at 90 GHz made with the MUSTANG bolometer array on the Green Bank Telescope at 8.5" resolution. A spectral analysis is performed combining this new data and archival VLA data or1 these objects at longer wavelengths. This analysis can detect variations in spectral index and curvature expected from energy losses in the radiating particles. L187 shows only weak evidence for steepening of the spectrum along the jet suggesting either re-acceleration of the relativistic particles in the jet or insufficient losesto affect the spectrum at 90 GHz The jets in Hydra A show strong steepening as they move from the nucleus suggesting unbalanced losses of the higher energy relativistic particles The difference between these two sources may be accounted for by the different lengths over which the jets are observable, 2 kpc for 5187 and 45 kpc for Hydra A. Subject headings: galaxies: jets, galaxies: active, radio continuum, galaxies: individual (M87. Hydra A),

  8. A measurement of time-averaged aerosol optical depth using air-showers observed in stereo by HiRes

    NASA Astrophysics Data System (ADS)

    High Resolution Fly'S Eye Collaboration; Abbasi, R. U.; Abu-Zayyad, T.; Amann, J. F.; Archbold, G.; Atkins, R.; Belov, K.; Belz, J. W.; Benzvi, S.; Bergman, D. R.; Boyer, J. H.; Cannon, C. T.; Cao, Z.; Connolly, B. M.; Fedorova, Y.; Finley, C. B.; Hanlon, W. F.; Hoffman, C. M.; Holzscheiter, M. H.; Hughes, G. A.; Hüntemeyer, P.; Jui, C. C. H.; Kirn, M. A.; Knapp, B. C.; Loh, E. C.; Manago, N.; Mannel, E. J.; Martens, K.; Matthews, J. A. J.; Matthews, J. N.; O'Neill, A.; Reil, K.; Roberts, M. D.; Schnetzer, S. R.; Seman, M.; Sinnis, G.; Smith, J. D.; Sokolsky, P.; Song, C.; Springer, R. W.; Stokes, B. T.; Thomas, S. B.; Thomson, G. B.; Tupa, D.; Westerhoff, S.; Wiencke, L. R.; Zech, A.

    2006-03-01

    Air fluorescence measurements of cosmic ray energy must be corrected for attenuation of the atmosphere. In this paper, we show that the air-showers themselves can yield a measurement of the aerosol attenuation in terms of optical depth, time-averaged over extended periods. Although the technique lacks statistical power to make the critical hourly measurements that only specialized active instruments can achieve, we note the technique does not depend on absolute calibration of the detector hardware, and requires no additional equipment beyond the fluorescence detectors that observe the air showers. This paper describes the technique, and presents results based on analysis of 1258 air-showers observed in stereo by the High Resolution Fly’s Eye over a four year span.

  9. Observations of Tropospheric Carbon Monoxide From the Atmospheric InfraRed Sounder (AIRS): An Alternative Retrieval Scheme and Its Validation.

    NASA Astrophysics Data System (ADS)

    Douglass, D. H.; Kalnay, E.; Li, H.; Cai, M.

    2005-05-01

    Carbon monoxide (CO) is present in the troposphere as a product of fossil fuel combustion, biomass burning and the oxidation of volatile hydrocarbons. It is the principal sink of the hydroxyl radical (OH), thereby affecting the concentrations of greenhouse gases such as CH4 and O3. In addition, CO has a lifetime of 1-3 months, making it a good tracer for studying the long range transport of pollution. Satellite observations present a valuable tool in the investigation of tropospheric CO. The Atmospheric InfraRed Sounder (AIRS), onboard the Aqua satellite, is sensitive to tropospheric CO in a number of its 2378 channels. This sensitivity to CO, combined with the daily global coverage provided by AIRS, makes AIRS a potentially useful instrument for observing CO sources and transport. A maximum a posteriori (MAP) retrieval scheme (Rodgers 2000) has been developed for AIRS, to provide CO profiles from near-surface altitudes to around 150 hPa. An extensive validation data set, consisting of over 50 in-situ aircraft CO profiles, has been constructed. This data set combines CO data from a number of independent aircraft campaigns. Results from this validation study and comparisons with the AIRS level 2 CO product will be presented. Rodgers, C. D. (2000), Inverse Methods for Atmospheric Sounding : Theory and Practice, World Scientific, Singapore.

  10. A randomized trial of air cleaners and a health coach to improve indoor air quality for inner-city children with asthma and secondhand smoke exposure.

    PubMed

    Butz, Arlene M; Matsui, Elizabeth C; Breysse, Patrick; Curtin-Brosnan, Jean; Eggleston, Peyton; Diette, Gregory; Williams, D'Ann; Yuan, Jie; Bernert, John T; Rand, Cynthia

    2011-08-01

    To test an air cleaner and health coach intervention to reduce secondhand smoke exposure compared with air cleaners alone or no air cleaners in reducing particulate matter (PM), air nicotine, and urine cotinine concentrations and increasing symptom-free days in children with asthma residing with a smoker. Randomized controlled trial, with randomization embedded in study database. The Johns Hopkins Hospital Children's Center and homes of children. Children with asthma, residing with a smoker, randomly assigned to interventions consisting of air cleaners only (n = 41), air cleaners plus a health coach (n = 41), or delayed air cleaner (control) (n = 44). Changes in PM, air nicotine, and urine cotinine concentrations and symptom-free days during the 6-month study. The overall follow-up rate was high (91.3%). Changes in mean fine and coarse PM (PM(2.5) and PM(2.5-10)) concentrations (baseline to 6 months) were significantly lower in both air cleaner groups compared with the control group (mean differences for PM(2.5) concentrations: control, 3.5 μg/m(3); air cleaner only, -19.9 μg/m(3); and air cleaner plus health coach, -16.1 μg/m(3); P = .003; and PM(2.5-10) concentrations: control, 2.4 μg/m(3); air cleaner only, -8.7 μg/m(3); and air cleaner plus health coach, -10.6 μg/m(3); P = .02). No differences were noted in air nicotine or urine cotinine concentrations. The health coach provided no additional reduction in PM concentrations. Symptom-free days were significantly increased [corrected] in both air cleaner groups compared with the control group (P = .03). Although the use of air cleaners can result in a significant reduction in indoor PM concentrations and a significant increase in symptom-free days, it is not enough to prevent exposure to secondhand smoke.

  11. Long term observations of PM2.5-associated PAHs: Comparisons between normal and episode days

    NASA Astrophysics Data System (ADS)

    Wang, Jia; Li, Xiao; Jiang, Nan; Zhang, Wenkai; Zhang, Ruiqin; Tang, Xiaoyan

    2015-03-01

    The pollution characteristic of fine particular matter (PM2.5) and associated polycyclic aromatic hydrocarbons (PAHs) are currently drawing a great deal of interest because of their influence on environment and health. In this study, PM2.5 was collected from 2011 to 2013 (n = 188) in a suburban area of Zhengzhou, China. 16-PAHs were analyzed to determine the concentration, seasonal variation and potential sources during normal days and episode events. The total mass of 16 PAHs and PM2.5 were in the range of 7-961 ng m-3 and 55-697 μg m-3, with a 3-year average of 174 ng m-3 and 194 μg m-3 respectively. Winter is most polluted for both PM2.5 and PAHs. Average PAH and PM2.5 concentrations during three episode events are 454 ng m-3 and 453 μg m-3, respectively, much higher than values during normal days (299 ng m-3 and 180 μg m-3, respectively). Ratios of Σ16PAH/PM2.5 varied with seasons and concentrations of PM2.5, but showed a negative correlation with PM2.5 concentrations during episode events. The dominant components of PAHs are Benzo[b]fluoranthene, Chrysene, Fluoranthene, and Benzo[k]fluoranthene, Benz[a]anthracene, Pyrene, Indeno(1,2,3-cd)pyrene and their total concentrations vary from 27 to 342 ng m-3, accounting for 58-82% (average = 73%) of 16 PAHs. The Benzo[a]pyrene (Bap) concentration obtained was 9.4 ng m-3 (3-year average), exceeding nearly one order of magnitude of ambient air BaP standard (annual average: 1.0 ng m-3) in China. Diagnose ratios and Positive Matrix Factorization results show that coal combustion, vehicles, coking plant, and biomass burning are main sources for PAHs in this area. The high concentrations of PM2.5 and PAHs, especially during episode events, reflected a potential health problem for nearby public and the necessity of air pollution control for both stationary and mobile sources.

  12. Chandra Observations of M31 and their Implications for its ISM

    NASA Technical Reports Server (NTRS)

    Primini, F.; Garcia, M.; Murray, S.; Forman, W.; Jones, C.; McClintock, J.

    2000-01-01

    As part of the Chandra X-ray Observatory's Survey/Monitoring Program of M31, we have been regularly observing the bulge amd inner disk of M31 for nearly 1 year, using both the HRC and ACIS Instruments. We present results from our program th it are of interest to the study of the ISM in M31. In particular, spectral analysis of bright, unresolved x-ray sources in the bulge reveals the presence of significant local x-ray extinction (N(sub H) is about 2 x 10(exp 21)/square cm), and we will attempt to map out this extinction, Further, we find that diffuse emission accounts for a significant fraction of the overall x-ray flux from the bulge. Finally, our search for x-ray counterparts to supernova remnants in M31 yields surprisingly few candidates.

  13. OMI Satellite and Ground-Based Pandora Observations and Their Application to Surface NO2 Estimations at Terrestrial and Marine Sites

    NASA Astrophysics Data System (ADS)

    Kollonige, Debra E.; Thompson, Anne M.; Josipovic, Miroslav; Tzortziou, Maria; Beukes, Johan P.; Burger, Roelof; Martins, Douglas K.; van Zyl, Pieter G.; Vakkari, Ville; Laakso, Lauri

    2018-01-01

    The Pandora spectrometer that uses direct-Sun measurements to derive total column amounts of gases provides an approach for (1) validation of satellite instruments and (2) monitoring of total column (TC) ozone (O3) and nitrogen dioxide (NO2). We use for the first time Pandora and Ozone Monitoring Instrument (OMI) observations to estimate surface NO2 over marine and terrestrial sites downwind of urban pollution and compared with in situ measurements during campaigns in contrasting regions: (1) the South African Highveld (at Welgegund, 26°34'10″S, 26°56'21″E, 1,480 m asl, 120 km southwest of the Johannesburg-Pretoria megacity) and (2) shipboard U.S. mid-Atlantic coast during the 2014 Deposition of Atmospheric Nitrogen to Coastal Ecosystems (DANCE) cruise. In both cases, there were no local NOx sources but intermittent regional pollution influences. For TC NO2, OMI and Pandora difference is 20%, with Pandora higher most times. Surface NO2 values estimated from OMI and Pandora columns are compared to in situ NO2 for both locations. For Welgegund, the planetary boundary layer (PBL) height, used in converting column to surface NO2 value, has been estimated by three methods: co-located Atmospheric Infrared Sounder (AIRS) observations; a model simulation; and radiosonde data from Irene, 150 km northeast of the site. AIRS PBL heights agree within 10% of radiosonde-derived values. Absolute differences between Pandora- and OMI-estimated surface NO2 and the in situ data are better at the terrestrial site ( 0.5 ppbv and 1 ppbv or greater, respectively) than under clean marine air conditions, with differences usually >3 ppbv. Cloud cover and PBL variability influence these estimations.

  14. Multi-wave band SMM-VLA observations of an M2 flare and an associated coronal mass ejection

    NASA Technical Reports Server (NTRS)

    Willson, Robert F.; Lang, Kenneth R.; Schmelz, Joan T.; Gonzalez, Raymond D.; Smith, Kermit L.

    1991-01-01

    Results are presented of observations of an M2 flare and an associated coronal mass ejection CME by instruments on the SMM as well as by the VLA and other ground-based observatories on September 30, 1988. The multiwave band data show a gradual slowly changing event which lasted several hours. The microwave burst emission was found to originate in compact moderately circularly polarized sources located near the sites of bright H-alpha and soft X-ray emission. These data are combined with estimates of an electron temperature of 1.5 x 10 to the 7th K and an emission measure of about 2.0 x 10 to the 49th/cu cm obtained from Ca XIX and Fe XXV spectra to show that the microwave emission can be attributed to thermal gyrosynchrotron radiation in regions where the magnetic field strength is 425-650 G. The CME acceleration at low altitudes is measured on the basis of ground- and space-based coronagraphs.

  15. Impacts of ENSO on air-sea oxygen exchange: Observations and mechanisms

    NASA Astrophysics Data System (ADS)

    Eddebbar, Yassir A.; Long, Matthew C.; Resplandy, Laure; Rödenbeck, Christian; Rodgers, Keith B.; Manizza, Manfredi; Keeling, Ralph F.

    2017-05-01

    Models and observations of atmospheric potential oxygen (APO ≃ O2 + 1.1 * CO2) are used to investigate the influence of El Niño-Southern Oscillation (ENSO) on air-sea O2 exchange. An atmospheric transport inversion of APO data from the Scripps flask network shows significant interannual variability in tropical APO fluxes that is positively correlated with the Niño3.4 index, indicating anomalous ocean outgassing of APO during El Niño. Hindcast simulations of the Community Earth System Model (CESM) and the Institut Pierre-Simon Laplace model show similar APO sensitivity to ENSO, differing from the Geophysical Fluid Dynamics Laboratory model, which shows an opposite APO response. In all models, O2 accounts for most APO flux variations. Detailed analysis in CESM shows that the O2 response is driven primarily by ENSO modulation of the source and rate of equatorial upwelling, which moderates the intensity of O2 uptake due to vertical transport of low-O2 waters. These upwelling changes dominate over counteracting effects of biological productivity and thermally driven O2 exchange. During El Niño, shallower and weaker upwelling leads to anomalous O2 outgassing, whereas deeper and intensified upwelling during La Niña drives enhanced O2 uptake. This response is strongly localized along the central and eastern equatorial Pacific, leading to an equatorial zonal dipole in atmospheric anomalies of APO. This dipole is further intensified by ENSO-related changes in winds, reconciling apparently conflicting APO observations in the tropical Pacific. These findings suggest a substantial and complex response of the oceanic O2 cycle to climate variability that is significantly (>50%) underestimated in magnitude by ocean models.

  16. Installation Restoration Program. Phase 2. Confirmation/Quantification, Stage 2 for Seymour Johnson Air Force Base, North Carolina. Volume 2

    DTIC Science & Technology

    1988-11-01

    Biochem., 46, 200-208 (1972). Walter, R. L., Willis, R. D., Gutknecht, W. F., and Joyce, J. M. "An- alysis of Biological, Clinical and Environmental...Constituents (POHC) Measurements during Hazardous Waste Trial Burn Tests," Journal of the Air Pollution Control Association, 35(2), 143-147, rebruaryI 99...to June 1975. University of Virginia. Medical Technologist, Student Health Center. Performed various clinical laboratory tests, such as complete

  17. Radon in the soil air of Estonia.

    PubMed

    Petersell, Valter; Täht-Kok, Krista; Karimov, Mark; Milvek, Heli; Nirgi, Siim; Raha, Margus; Saarik, Krista

    2017-01-01

    Several investigations in Estonia during 1996¬-1999 have shown that permissible level (200 Bq/m 3 ) of radon (222Rn) in indoor air is exceeded in 33% of the inspected dwellings. This makes Estonia one of the five countries with highest radon risk in Europe (Fig 1). Due to correlation between the soil radon risk level and radon concentration in houses, small scale radon risk mapping of soil air was carried out (one study point per 70-100 km 2 ). It turned out that one-third of Estonian mainland has high radon risk potential, where radon concentration in soil air exceeds safe limit of 50 kBq/m 3 . In order to estimate radon content in soil air, two different methods developed in Sweden were used simultaneously. Besides measuring radon content from soil air at the depth of 80 cm with an emanometer (RnM), maximum potential content of radon in soil (RnG) was estimated based on the rate of eU (226Ra) concentration in soil, which was acquired by using gamma-ray spectrometer. Mapping and following studies revealed that simultaneously measured RnG and RnM in study points may often differ. To inspect the cause, several monitoring points were set up in places with different geological conditions. It appeared that unlike the RnG content, which remains close to average level in repeated measurements, the RnM content may differ more than three times periodically. After continuous observations it turned out that concentration of directly measured radon depended on various factors being mostly controlled by mineral composition of soil, properties of topsoil as well as different factors influencing aeration of soil. The results of Rn monitoring show that reliable level of radon risk in Estonian soils can only be acquired by using calculated Rn-concentration in soil air based on eU content and directly measured radon content of soil air in combination with interpreting specific geological and geochemical situations in the study points. Copyright © 2016 Elsevier Ltd. All rights

  18. Spatial Representativeness of PM2.5 Concentrations Obtained Using Observations From Network Stations

    NASA Astrophysics Data System (ADS)

    Shi, Xiaoqin; Zhao, Chuanfeng; Jiang, Jonathan H.; Wang, Chunying; Yang, Xin; Yung, Yuk L.

    2018-03-01

    Haze has been a focused air pollution phenomenon in China, and its characterization is highly desired. Aerosol properties obtained from a single station are frequently used to represent the haze condition over a large domain, such as tens of kilometers, which could result in high uncertainties due to their spatial variation. Using a high-resolution network observation over an urban city in North China from November 2015 to February 2016, this study examines the spatial representativeness of ground station observations of particulate matter with diameters less than 2.5 μm (PM2.5). We developed a new method to determine the representative area of PM2.5 measurements from limited stations. The key idea is to determine the PM2.5 spatial representative area using its spatial variability and temporal correlation. We also determine stations with large representative area using two grid networks with different resolutions. Based on the high spatial resolution measurements, the representative area of PM2.5 at one station can be determined from the grids with high correlations and small differences of PM2.5. The representative area for a single station in the study period ranges from 0.25 to 16.25 km2 but is less than 3 km2 for more than half of the stations. The representative area varies with locations, and observation at 10 optimal stations would have a good representativeness of those obtained from 169 stations for the 4 month time scale studied. Both evaluations with an empirical orthogonal function analysis and with independent data set corroborate the validity of the results found in this study.

  19. Thermal conditions and perceived air quality in an air-conditioned auditorium

    NASA Astrophysics Data System (ADS)

    Polednik, Bernard; Guz, Łukasz; Skwarczyński, Mariusz; Dudzińska, Marzenna R.

    2016-07-01

    The study reports measurements of indoor air temperature (T) and relative humidity (RH), perceived air quality (PAQ) and CO2, fine aerosol particle number (PN) and mass (PM1) concentrations in an air conditioned auditorium. The measurements of these air physical parameters have been carried out in the unoccupied auditorium with the air conditioning system switched off (AC off mode) and in the unoccupied and occupied auditorium with the air conditioning system switched off during the night and switched on during the day (AC on/off mode). The average indoor air thermal parameters, CO2 concentration and the PAQ value (in decipols) were elevated, while average PM1 concentration was lower in the AC on/off mode. A statistically significant (p < 0.001) positive correlation has been observed between T and PAQ values and CO2 concentrations (r = 0.66 and r = 0.59, respectively) in that AC mode. A significant negative correlation has been observed between T and PN and PM1 concentrations (r = -0.38 and r = -0.49, respectively). In the AC off mode the above relations between T and the particle concentrations were not that unequivocal. These findings may be of importance as they indicate that in certain AC operation modes the indoor air quality deteriorates along with the variation of the indoor air microclimate and room occupation. This, in turn, may adversely affect the comfort and productivity of the users of air conditioned premises.

  20. Retrieval of Mid-tropospheric CO2 Directly from AIRS Measurements

    NASA Technical Reports Server (NTRS)

    Olsen, Edward T.; Chahine, Moustafa T.; Chen, Luke L.; Pagano, Thomas S.

    2008-01-01

    We apply the method of Vanishing Partial Derivatives (VPD) to AIRS spectra to retrieve daily the global distribution of CO2 at a nadir geospatial resolution of 90 km x 90 km without requiring a first-guess input beyond the global average. Our retrievals utilize the 15 (micro)m band radiances, a complex spectral region. This method may be of value in other applications, in which spectral signatures of multiple species are not well isolated spectrally from one another.

  1. Effect of Sampling Depth on Air-Sea CO2 Flux Estimates in River-Stratified Arctic Coastal Waters

    NASA Astrophysics Data System (ADS)

    Miller, L. A.; Papakyriakou, T. N.

    2015-12-01

    In summer-time Arctic coastal waters that are strongly influenced by river run-off, extreme stratification severely limits wind mixing, making it difficult to effectively sample the surface 'mixed layer', which can be as shallow as 1 m, from a ship. During two expeditions in southwestern Hudson Bay, off the Nelson, Hayes, and Churchill River estuaries, we confirmed that sampling depth has a strong impact on estimates of 'surface' pCO2 and calculated air-sea CO2 fluxes. We determined pCO2 in samples collected from 5 m, using a typical underway system on the ship's seawater supply; from the 'surface' rosette bottle, which was generally between 1 and 3 m; and using a niskin bottle deployed at 1 m and just below the surface from a small boat away from the ship. Our samples confirmed that the error in pCO2 derived from typical ship-board versus small-boat sampling at a single station could be nearly 90 μatm, leading to errors in the calculated air-sea CO2 flux of more than 0.1 mmol/(m2s). Attempting to extrapolate such fluxes over the 6,000,000 km2 area of the Arctic shelves would generate an error approaching a gigamol CO2/s. Averaging the station data over a cruise still resulted in an error of nearly 50% in the total flux estimate. Our results have implications not only for the design and execution of expedition-based sampling, but also for placement of in-situ sensors. Particularly in polar waters, sensors are usually deployed on moorings, well below the surface, to avoid damage and destruction from drifting ice. However, to obtain accurate information on air-sea fluxes in these areas, it is necessary to deploy sensors on ice-capable buoys that can position the sensors in true 'surface' waters.

  2. Sensitivity of Fermi level position at Ga-polar, N-polar, and nonpolar m-plane GaN surfaces to vacuum and air ambient

    NASA Astrophysics Data System (ADS)

    Janicki, Łukasz; Ramírez-López, Manolo; Misiewicz, Jan; Cywiński, Grzegorz; Boćkowski, Michał; Muzioł, Grzegorz; Chèze, Caroline; Sawicka, Marta; Skierbiszewski, Czesław; Kudrawiec, Robert

    2016-05-01

    Ga-polar, N-polar, and nonpolar m-plane GaN UN+ structures have been examined in air and vacuum ambient by contactless electroreflectance (CER). This technique is very sensitive to the surface electric field that varies with the Fermi level position at the surface. For UN+ GaN structures [i.e., GaN (undoped)/GaN (n-type)/substrate], a homogeneous built-in electric field is expected in the undoped GaN layer that is manifested by Franz-Keldysh oscillation (FKO) in CER spectra. A clear change in FKO has been observed in CER spectra for N-polar and nonpolar m-plane structures when changing from air to vacuum ambient. This means that those surfaces are very sensitive to ambient atmosphere. In contrast to that, only a small change in FKO can be seen in the Ga-polar structure. This clearly shows that the ambient sensitivity of the Fermi level position at the GaN surface varies with the crystallographic orientation and is very high for N-polar and nonpolar m-plane surfaces. This feature of the N-polar and nonpolar m-plane surfaces can be very important for GaN-based devices grown on these crystallographic orientations and can be utilized in some of the devices, e.g., sensors.

  3. M2-F3 In-flight Launch from B-52

    NASA Technical Reports Server (NTRS)

    1971-01-01

    This photo shows the M2-F3 Lifting Body being launched from NASA's B-52 mothership at the NASA Flight Research Center (FRC--now the Dryden Flight Research Center), Edwards, California. A fleet of lifting bodies flown at the FRC from 1963 to l975 demonstrated the ability of pilots to maneuver and safely land a wingless vehicle designed to fly back to Earth from space and be landed like an aircraft at a pre-determined site. Early flight testing of the M2-F1 and M2-F2 lifting body reentry configurations had validated the concept of piloted lifting body reentry from space. When the M2-F2 crashed on May 10, 1967, valuable information had already been obtained and was contributing to new designs. NASA pilots said the M2-F2 had lateral control problems, so when the M2-F2 was rebuilt at Northrop and redesignated the M2-F3, it was modified with an additional third vertical fin -- centered between the tip fins -- to improve control characteristics. First flight of the M2-F3, with NASA pilot Bill Dana at the controls, was June 2, 1970. The modified vehicle exhibited much better lateral stability and control characteristics than before, and only three glide flights were necessary before the first powered flight on Nov. 25, 1970. Over the next 26 missions, the M2-F3 reached a top speed of l,064 mph (Mach 1.6). Highest altitude reached by vehicle was 7l,500 feet on Dec. 20, 1972, the date of its last flight, with NASA pilot John Manke at the controls. NASA donated The M2-F3 vehicle to the Smithsonian Institute in December 1973. It is currently hanging in the Air and Space Museum along with the X-15 aircraft number 1, which was its hangar partner from 1965 to 1969. NASA B-52, Tail Number 008, is an air launch carrier aircraft, 'mothership,' as well as a research aircraft platform that has been used on a variety of research projects. The aircraft, a 'B' model built in 1952 and first flown on June 11, 1955, is the oldest B-52 in flying status and has been used on some of the most

  4. Acute exposure to air pollution triggers atrial fibrillation.

    PubMed

    Link, Mark S; Luttmann-Gibson, Heike; Schwartz, Joel; Mittleman, Murray A; Wessler, Benjamin; Gold, Diane R; Dockery, Douglas W; Laden, Francine

    2013-08-27

    This study sought to evaluate the association of air pollution with the onset of atrial fibrillation (AF). Air pollution in general and more specifically particulate matter has been associated with cardiovascular events. Although ventricular arrhythmias are traditionally thought to convey the increased cardiovascular risk, AF may also contribute. Patients with dual chamber implantable cardioverter-defibrillators (ICDs) were enrolled and followed prospectively. The association of AF onset with air quality including ambient particulate matter <2.5 μm aerodynamic diameter (PM2.5), black carbon, sulfate, particle number, NO2, SO2, and O3 in the 24 h prior to the arrhythmia was examined utilizing a case-crossover analysis. In sensitivity analyses, associations with air pollution between 2 and 48 h prior to the AF were examined. Of 176 patients followed for an average of 1.9 years, 49 patients had 328 episodes of AF lasting ≥ 30 s. Positive but nonsignificant associations were found for PM2.5 in the prior 24 h, but stronger associations were found with shorter exposure windows. The odds of AF increased by 26% (95% confidence interval: 8% to 47%) for each 6.0 μg/m(3) increase in PM2.5 in the 2 h prior to the event (p = 0.004). The odds of AF were highest at the upper quartile of mean PM2.5. PM was associated with increased odds of AF onset within hours following exposure in patients with known cardiac disease. Air pollution is an acute trigger of AF, likely contributing to the pollution-associated adverse cardiac outcomes observed in epidemiological studies. Copyright © 2013 American College of Cardiology Foundation. Published by Elsevier Inc. All rights reserved.

  5. A high-resolution and observationally constrained OMI NO 2 satellite retrieval

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goldberg, Daniel L.; Lamsal, Lok N.; Loughner, Christopher P.

    Here, this work presents a new high-resolution NO 2 dataset derived from the NASA Ozone Monitoring Instrument (OMI) NO 2 version 3.0 retrieval that can be used to estimate surface-level concentrations. The standard NASA product uses NO 2 vertical profile shape factors from a 1.25° × 1° (~110 km × 110 km) resolution Global Model Initiative (GMI) model simulation to calculate air mass factors, a critical value used to determine observed tropospheric NO 2 vertical columns. To better estimate vertical profile shape factors, we use a high-resolution (1.33 km × 1.33 km) Community Multi-scale Air Quality (CMAQ) model simulation constrained by in situmore » aircraft observations to recalculate tropospheric air mass factors and tropospheric NO 2 vertical columns during summertime in the eastern US. In this new product, OMI NO 2 tropospheric columns increase by up to 160% in city centers and decrease by 20–50 % in the rural areas outside of urban areas when compared to the operational NASA product. Our new product shows much better agreement with the Pandora NO 2 and Airborne Compact Atmospheric Mapper (ACAM) NO 2 spectrometer measurements acquired during the DISCOVER-AQ Maryland field campaign. Furthermore, the correlation between our satellite product and EPA NO 2 monitors in urban areas has improved dramatically: r 2 = 0.60 in the new product vs. r 2 = 0.39 in the operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to recalculate satellite data in areas with large spatial heterogeneities in NO x emissions. Although the current work is focused on the eastern US, the methodology developed in this work can be applied to other world regions to produce high-quality region-specific NO 2 satellite retrievals.« less

  6. A high-resolution and observationally constrained OMI NO 2 satellite retrieval

    DOE PAGES

    Goldberg, Daniel L.; Lamsal, Lok N.; Loughner, Christopher P.; ...

    2017-09-26

    Here, this work presents a new high-resolution NO 2 dataset derived from the NASA Ozone Monitoring Instrument (OMI) NO 2 version 3.0 retrieval that can be used to estimate surface-level concentrations. The standard NASA product uses NO 2 vertical profile shape factors from a 1.25° × 1° (~110 km × 110 km) resolution Global Model Initiative (GMI) model simulation to calculate air mass factors, a critical value used to determine observed tropospheric NO 2 vertical columns. To better estimate vertical profile shape factors, we use a high-resolution (1.33 km × 1.33 km) Community Multi-scale Air Quality (CMAQ) model simulation constrained by in situmore » aircraft observations to recalculate tropospheric air mass factors and tropospheric NO 2 vertical columns during summertime in the eastern US. In this new product, OMI NO 2 tropospheric columns increase by up to 160% in city centers and decrease by 20–50 % in the rural areas outside of urban areas when compared to the operational NASA product. Our new product shows much better agreement with the Pandora NO 2 and Airborne Compact Atmospheric Mapper (ACAM) NO 2 spectrometer measurements acquired during the DISCOVER-AQ Maryland field campaign. Furthermore, the correlation between our satellite product and EPA NO 2 monitors in urban areas has improved dramatically: r 2 = 0.60 in the new product vs. r 2 = 0.39 in the operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to recalculate satellite data in areas with large spatial heterogeneities in NO x emissions. Although the current work is focused on the eastern US, the methodology developed in this work can be applied to other world regions to produce high-quality region-specific NO 2 satellite retrievals.« less

  7. A high-resolution and observationally constrained OMI NO2 satellite retrieval

    NASA Astrophysics Data System (ADS)

    Goldberg, Daniel L.; Lamsal, Lok N.; Loughner, Christopher P.; Swartz, William H.; Lu, Zifeng; Streets, David G.

    2017-09-01

    This work presents a new high-resolution NO2 dataset derived from the NASA Ozone Monitoring Instrument (OMI) NO2 version 3.0 retrieval that can be used to estimate surface-level concentrations. The standard NASA product uses NO2 vertical profile shape factors from a 1.25° × 1° (˜ 110 km × 110 km) resolution Global Model Initiative (GMI) model simulation to calculate air mass factors, a critical value used to determine observed tropospheric NO2 vertical columns. To better estimate vertical profile shape factors, we use a high-resolution (1.33 km × 1.33 km) Community Multi-scale Air Quality (CMAQ) model simulation constrained by in situ aircraft observations to recalculate tropospheric air mass factors and tropospheric NO2 vertical columns during summertime in the eastern US. In this new product, OMI NO2 tropospheric columns increase by up to 160 % in city centers and decrease by 20-50 % in the rural areas outside of urban areas when compared to the operational NASA product. Our new product shows much better agreement with the Pandora NO2 and Airborne Compact Atmospheric Mapper (ACAM) NO2 spectrometer measurements acquired during the DISCOVER-AQ Maryland field campaign. Furthermore, the correlation between our satellite product and EPA NO2 monitors in urban areas has improved dramatically: r2 = 0.60 in the new product vs. r2 = 0.39 in the operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to recalculate satellite data in areas with large spatial heterogeneities in NOx emissions. Although the current work is focused on the eastern US, the methodology developed in this work can be applied to other world regions to produce high-quality region-specific NO2 satellite retrievals.

  8. Observations of increased tropical rainfall preceded by air passage over forests.

    PubMed

    Spracklen, D V; Arnold, S R; Taylor, C M

    2012-09-13

    Vegetation affects precipitation patterns by mediating moisture, energy and trace-gas fluxes between the surface and atmosphere. When forests are replaced by pasture or crops, evapotranspiration of moisture from soil and vegetation is often diminished, leading to reduced atmospheric humidity and potentially suppressing precipitation. Climate models predict that large-scale tropical deforestation causes reduced regional precipitation, although the magnitude of the effect is model and resolution dependent. In contrast, observational studies have linked deforestation to increased precipitation locally but have been unable to explore the impact of large-scale deforestation. Here we use satellite remote-sensing data of tropical precipitation and vegetation, combined with simulated atmospheric transport patterns, to assess the pan-tropical effect of forests on tropical rainfall. We find that for more than 60 per cent of the tropical land surface (latitudes 30 degrees south to 30 degrees north), air that has passed over extensive vegetation in the preceding few days produces at least twice as much rain as air that has passed over little vegetation. We demonstrate that this empirical correlation is consistent with evapotranspiration maintaining atmospheric moisture in air that passes over extensive vegetation. We combine these empirical relationships with current trends of Amazonian deforestation to estimate reductions of 12 and 21 per cent in wet-season and dry-season precipitation respectively across the Amazon basin by 2050, due to less-efficient moisture recycling. Our observation-based results complement similar estimates from climate models, in which the physical mechanisms and feedbacks at work could be explored in more detail.

  9. The burden of COPD mortality due to ambient air pollution in Guangzhou, China

    PubMed Central

    Li, Li; Yang, Jun; Song, Yun-Feng; Chen, Ping-Yan; Ou, Chun-Quan

    2016-01-01

    Few studies have investigated the chronic obstructive pulmonary disease (COPD) mortality fraction attributable to air pollution and modification by individual characteristics of air pollution effects. We applied distributed lag non-linear models to assess the associations between air pollution and COPD mortality in 2007–2011 in Guangzhou, China, and the total COPD mortality fraction attributable to air pollution was calculated as well. We found that an increase of 10 μg/m3 in particulate matter with an aerodynamic diameter of 10 μm or less (PM10), sulfur dioxide (SO2) and nitrogen dioxide (NO2) was associated with a 1.58% (95% confidence interval (CI): 0.12–3.06%), 3.45% (95% CI: 1.30–5.66%) and 2.35% (95% CI: 0.42–4.32%) increase of COPD mortality over a lag of 0–15 days, respectively. Greater air pollution effects were observed in the elderly, males and residents with low educational attainment. The results showed 10.91% (95% CI: 1.02–9.58%), 12.71% (95% CI: 5.03–19.85%) and 13.38% (95% CI: 2.67–22.84%) COPD mortality was attributable to current PM10, SO2 and NO2 exposure, respectively. In conclusion, the associations between air pollution and COPD mortality differed by individual characteristics. There were remarkable COPD mortality burdens attributable to air pollution in Guangzhou. PMID:27195597

  10. Studying RR Lyrae Stars in M4 with K2

    NASA Astrophysics Data System (ADS)

    Kuehn, Charles A.; Drury, Jason; Moskalik, Pawel

    2017-01-01

    Observations by Kepler/K2 have revolutionized the study of RR Lyrae stars by allowing the detection of new phenomena, such as low amplitude additional modes and period doubling, which had not previously been seen from the ground. During its campaign 2, K2 observed the globular cluster M4, providing the first opportunity to study a sizeable group of RR Lyrae stars that belong to a single population; the other RR Lyrae stars that have been observed from space are field stars in the galactic halo and thus belong to an assortment of populations. We present the results of our study of the RR Lyrae variables in M4 from K2 photometry. We have identified additional, low amplitude pulsation modes in the two observed RRc stars. In three RRab stars we have found the Blazhko effect with periods of 16.6 days, 22.4 days, and 44.5 days.

  11. ALMA observation of the disruption of molecular gas in M87

    DOE PAGES

    Simionescu, A.; Tremblay, G.; Werner, N.; ...

    2018-01-09

    We present the results from Atacama Large Millimeter Array (ALMA) observations centred 40 arcsec (3 kpc in projection) south-east of the nucleus of M87. Here, we report the detection of extended CO (2–1) line emission with a total flux of (5.5 ± 0.6) × 10 -18 erg s -1 cm -2 and corresponding molecular gas mass M more » $$H{_2}$$=(4.7±0.4)×10 5M ⊙, assuming a Galactic CO to H 2 conversion factor. ALMA data indicate a line-of-sight velocity of -129 ± 3 km s -1, in good agreement with measurements based on the [C II] and H α+[N II] lines, and a velocity dispersion of σ = 27 ± 3 km s -1. The CO (2–1) emission originates only outside the radio lobe of the active galactic nucleus (AGN) seen in the 6 cm Very Large Array image, while the filament prolongs further inwards at other wavelengths. The molecular gas in M87 appears to be destroyed or excited by AGN activity, either by direct interaction with the radio plasma, or by the shock driven by the lobe into the X-ray emitting atmosphere. This is an important piece of the puzzle in understanding the impact of the central AGN on the amount of the coldest gas from which star formation can proceed.« less

  12. ALMA observation of the disruption of molecular gas in M87

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simionescu, A.; Tremblay, G.; Werner, N.

    We present the results from Atacama Large Millimeter Array (ALMA) observations centred 40 arcsec (3 kpc in projection) south-east of the nucleus of M87. Here, we report the detection of extended CO (2–1) line emission with a total flux of (5.5 ± 0.6) × 10 -18 erg s -1 cm -2 and corresponding molecular gas mass M more » $$H{_2}$$=(4.7±0.4)×10 5M ⊙, assuming a Galactic CO to H 2 conversion factor. ALMA data indicate a line-of-sight velocity of -129 ± 3 km s -1, in good agreement with measurements based on the [C II] and H α+[N II] lines, and a velocity dispersion of σ = 27 ± 3 km s -1. The CO (2–1) emission originates only outside the radio lobe of the active galactic nucleus (AGN) seen in the 6 cm Very Large Array image, while the filament prolongs further inwards at other wavelengths. The molecular gas in M87 appears to be destroyed or excited by AGN activity, either by direct interaction with the radio plasma, or by the shock driven by the lobe into the X-ray emitting atmosphere. This is an important piece of the puzzle in understanding the impact of the central AGN on the amount of the coldest gas from which star formation can proceed.« less

  13. [Biological contamination in office buildings related to ventilation/air conditioning system].

    PubMed

    Bródka, Karolina; Sowiak, Małgorzata; Kozajda, Anna; Cyprowski, Marcin; Irena, Szadkowska-Stańczyk

    2012-01-01

    Indoor air is contaminated with microorganisms coming from both the atmospheric air and sources present in premises. The aim of this study was to analyze the concentrations of biological agents in office buildings, dependending on ventilation/air conditioning system and season. The study covered office buildings (different in the system of ventila-tion/air conditioning). Air samples for assessing the levels of inhalable dust, endotoxins and (1-->3)-beta-D-glucans, were taken at the selected stationary points of each building during summer and winter. The air was sampled for 6 h, using portable sets consisting of the GilAir 5 pump and the head filled with a filter of fiber glass. The samples for the presence of airborne bacteria and fungi were collected twice during the day using the impaction method. Average concentrations of inhalable dust, bacteria, fungi, endotoxins and (1-->3)-beta-D-glucans in office premises were 0.09 mg/m3, 6.00 x 10(2) cfu/m3, 4.59 x 10(1) cfu/m3, 0.42 ng/m3 and 3.91 ng/m3, respectively. Higher concentrations of the investigated agents were found in summer. In premises with air conditioning concentrations of airborne fungi, (1-->3)-beta-D-glucans and inhalable dust were significantly lower in winter. In summer the trend was reverse except for (1-->3)-beta-D-glucans. Concentrations of biological agents were affected by the season and the presence of air conditioning. Concentrations of inhalable dust, bacteria, fungi, endotoxins and (1-->3)-beta-D-glucans, observed inside the office buildings, were significantly higher in summer than in winter. The presence of the air conditioning system modified in various ways the levels of biological agents. Its influence was greater on the concentration of fungi and (1-->3)-beta-D-glucans than on that of bacteria and endotoxins.

  14. Compliance with the annual NO 2 air quality standard in Athens. Required NO x levels and expected health implications

    NASA Astrophysics Data System (ADS)

    Chaloulakou, A.; Mavroidis, I.; Gavriil, I.

    Recent risk assessment studies have shown that high outdoor NO 2 levels observed in residential areas contribute to increased respiratory and cardiovascular diseases and mortality. Detailed information on present NO 2 levels as well as predictions of NO 2 concentrations corresponding to reduced NO x levels in urban areas are very useful to decision and policy makers in order to protect the public health. In the present paper, monitoring stations of the Athens network are initially classified into two main groups, traffic affected and urban background, using effectively a criterion based on the ratio of annual mean NO:NO 2 concentrations. Two empirical methodologies are then considered and compared for assessing the effect of different NO x levels on the attainment of the annual NO 2 air quality standard at urban-background locations in the Athens area. An interesting finding is that these two methodologies, one more general and one both year and site dependent, give similar results for the specific study area and can be applied alternatively based on the length of available concentration time series. The results show that in order to meet the EU annual mean NO 2 objective at all the urban-background locations of the Athens area, annual NO x concentrations should be reduced to approximately 60 μg m -3, requiring NO x emission reductions of up to 30%. An analysis of the health implications of the currently observed NO 2 levels is conducted, based on a dose-response relationship, and is coupled with available health-related data for the Athens area. This analysis suggests that if NO 2 concentrations were reduced to the levels of the annual EU air quality standard, then a decrease of hospital admissions of up to 2.6% would be observed, depending on the levels of NO 2 measured at different monitoring sites of the Athens conurbation.

  15. Polyfluorinated compounds in ambient air from ship- and land-based measurements in northern Germany

    NASA Astrophysics Data System (ADS)

    Dreyer, Annekatrin; Ebinghaus, Ralf

    Neutral volatile and semi-volatile polyfluorinated organic compounds (PFC) and ionic perfluorinated compounds were determined in air samples collected at two sites in the vicinity of Hamburg, Germany, and onboard the German research vessel Atair during a cruise in the German Bight, North Sea, in early November 2007. PUF/XAD-2/PUF cartridges and glass fiber filters as sampling media were applied to collect several fluorotelomer alcohols (FTOH), fluorotelomer acrylates (FTA), perfluoroalkyl sulfonamides (FASA), and perfluoroalkyl sulfonamido ethanols (FASE) in the gas- and particle-phase as well as a set of perfluorinated carboxylates (PFCA) and sulfonates (PFSA) in the particle-phase. This study presents the distribution of PFC in ambient air of the German North Sea and in the vicinity of Hamburg for the first time. Average total PFC concentrations in and around Hamburg (180 pg m -3) were higher than those observed in the German Bight (80 pg m -3). In the German Bight, minimum-maximum gas-phase concentrations of 17-82 pg m -3 for ΣFTOH, 2.6-10 pg m -3 for ΣFTA, 10-15 pg m -3 for ΣFASA, and 2-4.4 pg m -3 for ΣFASE were determined. In the vicinity of Hamburg, minimum-maximum gas-phase concentrations of 32-204 pg m -3 for ΣFTOH, 3-26 pg m -3 for ΣFTA, 3-18 pg m -3 for ΣFASA, and 2-15 pg m -3 for ΣFASE were detected. Concentrations of perfluorinated acids were in the range of 1-11 pg m -3. FTOH clearly dominated the substance spectrum; 8:2 FTOH occurred in maximum proportions. Air mass back trajectories, cluster, and correlation analyses revealed that the air mass origin and thus medium to long range atmospheric transport was the governing parameter for the amount of PFC in ambient air. Southwesterly located source regions seemed to be responsible for elevated PFC concentrations, local sources appeared to be of minor importance.

  16. Fabrication of VB2/Air Cells for Electrochemical Testing

    PubMed Central

    Stuart, Jessica; Lopez, Ruben; Lau, Jason; Li, Xuguang; Waje, Mahesh; Mullings, Matthew; Rhodes, Christopher; Licht, Stuart

    2013-01-01

    A technique to investigate the properties and performance of new multi-electron metal/air battery systems is proposed and presented. A method for synthesizing nanoscopic VB2 is presented as well as step-by-step procedure for applying a zirconium oxide coating to the VB2 particles for stabilization upon discharge. The process for disassembling existing zinc/air cells is shown, in addition construction of the new working electrode to replace the conventional zinc/air cell anode with a the nanoscopic VB2 anode. Finally, discharge of the completed VB2/air battery is reported. We show that using the zinc/air cell as a test bed is useful to provide a consistent configuration to study the performance of the high-energy high capacity nanoscopic VB2 anode. PMID:23962835

  17. H2MBH2 and M(μ-H)2BH2 Molecules Isolated in Solid Argon: Interelement M-B and M-H-B Bonds (M = Ge, Sn).

    PubMed

    Zhao, Jie; Beckers, Helmut; Huang, Tengfei; Wang, Xuefeng; Riedel, Sebastian

    2018-02-19

    Laser-ablated boron atoms react with GeH 4 molecules to form novel germylidene borane H 2 GeBH 2 , which undergoes a photochemical rearrangement to the germanium tetrahydroborate Ge(μ-H) 2 BH 2 upon irradiation with light of λ = 405 nm. For comparison, the boron atom reactions with SnH 4 only gave the tin tetrahydroborate Sn(μ-H) 2 BH 2 . Infrared matrix-isolation spectroscopy with deuterium substitution and the state-of-the-art quantum-chemical calculations are used to identify these species in solid argon. A planar structure of H 2 GeBH 2 with an electron-deficient B-Ge bond with a partial multiple bond character (bond order = 1.5) is predicted by quantum-chemical calculations. In the case of M(μ-H) 2 BH 2 (M = Ge, Sn) two 3c-2e B-H-M hydrogen bridged bonds are formed by donation of electrons from the B-H σ-bonds into empty p-orbitals of M.

  18. Linking Meteorology, Air Quality Models and Observations to ...

    EPA Pesticide Factsheets

    Epidemiologic studies are critical in establishing the association between exposure to air pollutants and adverse health effects. Results of epidemiologic studies are used by U.S. EPA in developing air quality standards to protect the public from the health effects of air pollutants. A major challenge in environmental epidemiology is adequate exposure characterization. Numerous health studies have used measurements from a few central-site ambient monitors to characterize air pollution exposures. Relying solely on central-site ambient monitors does not account for the spatial-heterogeneity of ambient air pollution patterns, the temporal variability in ambient concentrations, nor the influence of infiltration and indoor sources. Central-site monitoring becomes even more problematic for certain air pollutants that exhibit significant spatial heterogeneity. Statistical interpolation techniques and passive monitoring methods can provide additional spatial resolution in ambient concentration estimates. In addition, spatio-temporal models, which integrate GIS data and other factors, such as meteorology, have also been developed to produce more resolved estimates of ambient concentrations. Models, such as the Community Multi-Scale Air Quality (CMAQ) model, estimate ambient concentrations by combining information on meteorology, source emissions, and chemical-fate and transport. Hybrid modeling approaches, which integrate regional scale models with local scale dispersion

  19. Cot/tpl2-MKK1/2-Erk1/2 controls mTORC1-mediated mRNA translation in Toll-like receptor–activated macrophages

    PubMed Central

    López-Pelaéz, Marta; Fumagalli, Stefano; Sanz, Carlos; Herrero, Clara; Guerra, Susana; Fernandez, Margarita; Alemany, Susana

    2012-01-01

    Cot/tpl2 is the only MAP3K that activates MKK1/2-Erk1/2 in Toll-like receptor–activated macrophages. Here we show that Cot/tpl2 regulates RSK, S6 ribosomal protein, and 4E-BP phosphorylation after stimulation of bone marrow–derived macrophages with lipopolysaccharide (LPS), poly I:C, or zymosan. The dissociation of the 4E-BP–eIF4E complex, a key event in the cap-dependent mRNA translation initiation, is dramatically reduced in LPS-stimulated Cot/tpl2-knockout (KO) macrophages versus LPS-stimulated wild-type (Wt) macrophages. Accordingly, after LPS activation, increased cap-dependent translation is observed in Wt macrophages but not in Cot/tpl2 KO macrophages. In agreement with these data, Cot/tpl2 increases the polysomal recruitment of the 5´ TOP eEF1α and eEF2 mRNAs, as well as of inflammatory mediator gene–encoding mRNAs, such as tumor necrosis factor α (TNFα), interleukin-6 (IL-6), and KC in LPS-stimulated macrophages. In addition, Cot/tpl2 deficiency also reduces total TNFα, IL-6, and KC mRNA expression in LPS-stimulated macrophages, which is concomitant with a decrease in their mRNA half-lives. Macrophages require rapid fine control of translation to provide an accurate and not self-damaging response to host infection, and our data show that Cot/tpl2 controls inflammatory mediator gene–encoding mRNA translation in Toll-like receptor–activated macrophages. PMID:22675026

  20. Cot/tpl2-MKK1/2-Erk1/2 controls mTORC1-mediated mRNA translation in Toll-like receptor-activated macrophages.

    PubMed

    López-Pelaéz, Marta; Fumagalli, Stefano; Sanz, Carlos; Herrero, Clara; Guerra, Susana; Fernandez, Margarita; Alemany, Susana

    2012-08-01

    Cot/tpl2 is the only MAP3K that activates MKK1/2-Erk1/2 in Toll-like receptor-activated macrophages. Here we show that Cot/tpl2 regulates RSK, S6 ribosomal protein, and 4E-BP phosphorylation after stimulation of bone marrow-derived macrophages with lipopolysaccharide (LPS), poly I:C, or zymosan. The dissociation of the 4E-BP-eIF4E complex, a key event in the cap-dependent mRNA translation initiation, is dramatically reduced in LPS-stimulated Cot/tpl2-knockout (KO) macrophages versus LPS-stimulated wild-type (Wt) macrophages. Accordingly, after LPS activation, increased cap-dependent translation is observed in Wt macrophages but not in Cot/tpl2 KO macrophages. In agreement with these data, Cot/tpl2 increases the polysomal recruitment of the 5´ TOP eEF1α and eEF2 mRNAs, as well as of inflammatory mediator gene-encoding mRNAs, such as tumor necrosis factor α (TNFα), interleukin-6 (IL-6), and KC in LPS-stimulated macrophages. In addition, Cot/tpl2 deficiency also reduces total TNFα, IL-6, and KC mRNA expression in LPS-stimulated macrophages, which is concomitant with a decrease in their mRNA half-lives. Macrophages require rapid fine control of translation to provide an accurate and not self-damaging response to host infection, and our data show that Cot/tpl2 controls inflammatory mediator gene-encoding mRNA translation in Toll-like receptor-activated macrophages.

  1. Macrophage polarisation: an immunohistochemical approach for identifying M1 and M2 macrophages.

    PubMed

    Barros, Mário Henrique M; Hauck, Franziska; Dreyer, Johannes H; Kempkes, Bettina; Niedobitek, Gerald

    2013-01-01

    Macrophage polarization is increasingly recognised as an important pathogenetic factor in inflammatory and neoplastic diseases. Proinflammatory M1 macrophages promote T helper (Th) 1 responses and show tumoricidal activity. M2 macrophages contribute to tissue repair and promote Th2 responses. CD68 and CD163 are used to identify macrophages in tissue sections. However, characterisation of polarised macrophages in situ has remained difficult. Macrophage polarisation is regulated by transcription factors, pSTAT1 and RBP-J for M1, and CMAF for M2. We reasoned that double-labelling immunohistochemistry for the detection of macrophage markers together with transcription factors may be suitable to characterise macrophage polarisation in situ. To test this hypothesis, we have studied conditions associated with Th1- and Th2-predominant immune responses: infectious mononucleosis and Crohn's disease for Th1 and allergic nasal polyps, oxyuriasis, wound healing and foreign body granulomas for predominant Th2 response. In all situations, CD163+ cells usually outnumbered CD68+ cells. Moreover, CD163+ cells, usually considered as M2 macrophages, co-expressing pSTAT1 and RBP-J were found in all conditions examined. The numbers of putative M1 macrophages were higher in Th1- than in Th2-associated diseases, while more M2 macrophages were seen in Th2- than in Th1 related disorders. In most Th1-related diseases, the balance of M1 over M2 cells was shifted towards M1 cells, while the reverse was observed for Th2-related conditions. Hierarchical cluster analysis revealed two distinct clusters: cluster I included Th1 diseases together with cases with high numbers of CD163+pSTAT1+, CD68+pSTAT1+, CD163+RBP-J+ and CD68+RBP-J+ macrophages; cluster II comprised Th2 conditions together with cases displaying high numbers of CD163+CMAF+ and CD68+CMAF+ macrophages. These results suggest that the detection of pSTAT1, RBP-J, and CMAF in the context of CD68 or CD163 expression is a suitable tool for

  2. Characterising terrestrial influences on Antarctic air masses using Radon-222 measurements at King George Island

    NASA Astrophysics Data System (ADS)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-09-01

    We report on one year of high-precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late-summer to 44 mBq m-3 in late winter and early spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  3. Characterising terrestrial influences on Antarctic air masses using radon-222 measurements at King George Island

    NASA Astrophysics Data System (ADS)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-05-01

    We report on one year of high precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late summer to 44 mBq m-3 in late-winter and early-spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  4. Non-aqueous aluminium-air battery based on ionic liquid electrolyte

    NASA Astrophysics Data System (ADS)

    Revel, Renaud; Audichon, Thomas; Gonzalez, Serge

    2014-12-01

    A promising metal-air secondary battery based on aluminium-oxygen couple is described. In this paper, we observed that an aluminium-air battery employing EMImCl, AlCl3 room temperature ionic liquid (RTIL) as electrolyte and aluminium as negative electrode, has an exceptional reduced self-discharged rate. Due to its new and innovative type of electrolyte, this aluminium-air battery can support relatively high current densities (up to 0.6 mA cm-2) and an average voltage of 0.6-0.8 V. Such batteries may find immediate applications, as they can provide an internal, built-in autonomous and self-sustained energy source.

  5. Phytomonitoring of air pollution around a thermal power plant

    NASA Astrophysics Data System (ADS)

    Agrawal, M.; Agrawal, S. B.

    This study was undertaken in order to assess the impact of air pollutants on vegetation around Obra thermal power plant (1550 M W capacity) in the Mirzapur district of Uttar Pradesh. For this purpose, Mangifera indica, Citrus medico and Bouganvillaea spectabilis plants, most common at all sites, were selected as test plants. Five study sites were selected northeast (prevailing wind) of the thermal power plant. A control site was also selected at a distance of 30 km north of Obra. Responses of plants to pollutants in terms of presence of foliar injury symptoms and changes in chlorophyll, ascorbic acid and S content were measured. These changes were correlated with ambient SO 2 and suspended particulate matter (SPM) concentrations and the amount of dust settled on leaf surfaces. The SO 2 and SPM concentrations were quite high in the immediate vicinity of the power plant. There also exists a direct relationship between the concentration of SPM in air and amount of dust deposited on leaf surfaces. Maximum dust deposition was observed on M. indica plants. The levels of foliar injury, chlorophyll and ascorbic acid were found to decrease and that of S increase in plants around the power plant in comparison to those growing at a control site. The magnitude of such changes was maximum in M. indica and minimum in C. medica. A species specific direct relationship between the increase in the amount of S and decrease in chlorophyll content was observed. The study suggests that differential sensitivity of plants to SO 2 may be used in evaluating the air pollution impact around emission sources and M. indica plants can be used as an indicator plant for quantifying biological changes.

  6. Digital amateur observations of Venus at 0.9μm

    NASA Astrophysics Data System (ADS)

    Kardasis, E.

    2017-09-01

    Venus atmosphere is extremely dynamic, though it is very difficult to observe any features on it in the visible and even in the near-IR range. Digital observations with planetary cameras in recent years routinely produce high-quality images, especially in the near-infrared (0.7-1μm), since IR wavelengths are less influenced by Earth's atmosphere and Venus's atmosphere is partially transparent in this spectral region. Continuous observations over a few hours may track dark atmospheric features in the dayside and determine their motion. In this work we will present such observations and some dark-feature motion measurements at 0.9μm. Ground-based observations at this wavelength are rare and are complementary to in situ observations by JAXA's Akatsuki orbiter, that studies the atmospheric dynamics of Venus also in this band with the IR1 camera.

  7. Large inter annual variation in air quality during the annual festival 'Diwali' in an Indian megacity.

    PubMed

    Parkhi, Neha; Chate, Dilip; Ghude, Sachin D; Peshin, Sunil; Mahajan, Anoop; Srinivas, Reka; Surendran, Divya; Ali, Kaushar; Singh, Siddhartha; Trimbake, Hanumant; Beig, Gufran

    2016-05-01

    A network of air quality and weather monitoring stations was established under the System of Air Quality Forecasting and Research (SAFAR) project in Delhi. We report observations of ozone (O3), nitrogen oxides (NOx), carbon monoxide (CO) and particulate matter (PM2.5 and PM10) before, during and after the Diwali in two consecutive years, i.e., November 2010 and October 2011. The Diwali days are characterised by large firework displays throughout India. The observations show that the background concentrations of particulate matter are between 5 and 10 times the permissible limits in Europe and the United States. During the Diwali-2010, the highest observed PM10 and PM2.5 mass concentration is as high as 2070µg/m3 and 1620μg/m(3), respectively (24hr mean), which was about 20 and 27 times to National Ambient Air Quality Standards (NAAQS). For Diwali-2011, the increase in PM10 and PM2.5 mass concentrations was much less with their peaks of 600 and of 390μg/m(3) respectively, as compared to the background concentrations. Contrary to previous reports, firework display was not found to strongly influence the NOx, and O3 mixing ratios, with the increase within the observed variability in the background. CO mixing ratios showed an increase. We show that the large difference in 2010 and 2011 pollutant concentrations is controlled by weather parameters. Copyright © 2015. Published by Elsevier B.V.

  8. Adult lung function and long-term air pollution exposure. ESCAPE: a multicentre cohort study and meta-analysis

    PubMed Central

    Adam, Martin; Schikowski, Tamara; Carsin, Anne Elie; Cai, Yutong; Jacquemin, Benedicte; Sanchez, Margaux; Vierkötter, Andrea; Marcon, Alessandro; Keidel, Dirk; Sugiri, Dorothee; Al Kanani, Zaina; Nadif, Rachel; Siroux, Valérie; Hardy, Rebecca; Kuh, Diana; Rochat, Thierry; Bridevaux, Pierre-Olivier; Eeftens, Marloes; Tsai, Ming-Yi; Villani, Simona; Phuleria, Harish Chandra; Birk, Matthias; Cyrys, Josef; Cirach, Marta; de Nazelle, Audrey; Nieuwenhuijsen, Mark J.; Forsberg, Bertil; de Hoogh, Kees; Declerq, Christophe; Bono, Roberto; Piccioni, Pavilio; Quass, Ulrich; Heinrich, Joachim; Jarvis, Deborah; Pin, Isabelle; Beelen, Rob; Hoek, Gerard; Brunekreef, Bert; Schindler, Christian; Sunyer, Jordi; Krämer, Ursula; Kauffmann, Francine; Hansell, Anna L.; Künzli, Nino; Probst-Hensch, Nicole

    2015-01-01

    The chronic impact of ambient air pollutants on lung function in adults is not fully understood. The objective of this study was to investigate the association of long-term exposure to ambient air pollution with lung function in adult participants from five cohorts in the European Study of Cohorts for Air Pollution Effects (ESCAPE). Residential exposure to nitrogen oxides (NO2, NOx) and particulate matter (PM) was modelled and traffic indicators were assessed in a standardised manner. The spirometric parameters forced expiratory volume in 1 s (FEV1) and forced vital capacity (FVC) from 7613 subjects were considered as outcomes. Cohort-specific results were combined using meta-analysis. We did not observe an association of air pollution with longitudinal change in lung function, but we observed that a 10 μg·m−3 increase in NO2 exposure was associated with lower levels of FEV1 (−14.0 mL, 95% CI −25.8 to −2.1) and FVC (−14.9 mL, 95% CI −28.7 to −1.1). An increase of 10 μg·m−3 in PM10, but not other PM metrics (PM2.5, coarse fraction of PM, PM absorbance), was associated with a lower level of FEV1 (−44.6 mL, 95% CI −85.4 to −3.8) and FVC (−59.0 mL, 95% CI −112.3 to −5.6). The associations were particularly strong in obese persons. This study adds to the evidence for an adverse association of ambient air pollution with lung function in adults at very low levels in Europe. PMID:25193994

  9. Slip-Effect Functional Air Filter for Efficient Purification of PM2.5

    NASA Astrophysics Data System (ADS)

    Zhao, Xinglei; Wang, Shan; Yin, Xia; Yu, Jianyong; Ding, Bin

    2016-10-01

    Fabrication of air filtration materials (AFM) that allow air to easily flow through while retaining particles is a significant and urgent need due to the harmful airborne particulate matter pollution; however, this is still a challenging research area. Herein, we report novel slip-effect functional nanofibrous membranes with decreased air resistance (reduction rate of 40%) due to the slip flow of air molecules on the periphery of nanofibers. This was achieved through careful control over the diameters of electrospun polyacrylonitrile fibers and aperture size of fiber assembly. Fiber assembly with 86% of fiber diameters between 60-100 nm was found to be most effective for slip flow, as these diameters are close to the mean free path of air molecules (65.3 nm). Significantly, an equilibrium factor τ = df/d2 has been introduced to elucidate the effect of distance of adjacent fibers on the drag force of airflow. Furthermore, the most effective aperture size (>3.5 μm) for slip-effect has been determined. Ultimately, the new material displayed low air resistance of 29.5 Pa, high purification efficiency of 99.09%, good transmittance of 77%, and long service life. The successful fabrication of such materials can facilitate the development of high-performance AFMs for various applications.

  10. CCM.FF-K3.2011: Final report for the CIPM key comparison of air speed, 0.5 m/s to 40 m/s

    NASA Astrophysics Data System (ADS)

    Müller, Harald; Caré, Isabelle; Lucas, Peter; Pachinger, Dietmar; Kurihara, Noboru; Lishui, Cui; Su, Chun-Min; Shinder, Iosif; Spazzini, Pier Giorgio

    2017-01-01

    The CCM.FF-K3.2011 comparison was organized for the purpose of determination of the degree of equivalence of the national standards for air speed over the range 0.5 m/s to 40 m/s. An ultrasonic anemometer and a Laser Doppler anemometer were used as transfer standards. Nine laboratories from three RMOs participated between July 2013 and July 2015—EURAMET: PTB, Germany; LNE-CETIAT, France; INRIM, Italy; VSL, The Netherlands; E+E, Austria; SIM: NIST, USA; APMP: NMIJ/AIST, Japan; NIM, China; CMS/ITRI, Chinese Taipei. The measurements were provided at ambient conditions. All results of independent participants were used in the determination of the key comparison reference value (KCRV) and the uncertainty of the KCRV. The reference value was determined at each air speed separately following `procedure A' presented by M G Cox. The degree of equivalence with the KCRV was calculated for each air speed and laboratory. Almost all reported results were consistent with the KCRV. Main text To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

  11. Meteorological and urban landscape factors on severe air pollution in Beijing.

    PubMed

    Han, Lijian; Zhou, Weiqi; Li, Weifeng; Meshesha, Derege T; Li, Li; Zheng, Mingqing

    2015-07-01

    Air pollution gained special attention with the rapid development in Beijing. In January 2013, Beijing experienced extreme air pollution, which was not well examined. We thus examine the magnitude of air quality in the particular month by applying the air quality index (AQI), which is based on the newly upgraded Chinese environmental standard. Our finding revealed that (1) air quality has distinct spatial heterogeneity and relatively better air quality was observed in the northwest while worse quality happened in the southeast part of the city; (2) the wind speed is the main determinant of air quality in the city-when wind speed is greater than 4 m/sec, air quality can be significantly improved; and (3) urban impervious surface makes a contribution to the severity of air pollution-that is, with an increase in the fraction of impervious surface in a given area, air pollution is more severe. The results from our study demonstrated the severe pollution in Beijing and its meteorological and landscape factors. Also, the results of this work suggest that very strict air quality management should be conducted when wind speed less than 4 m/sec, especially at places with a large fraction of urban impervious surface. Prevention of air pollution is rare among methods with controls on meteorological and urban landscape conditions. We present research that utilizes the latest air quality index (AQI) to compare air pollution with meteorological and landscape conditions. We found that wind is the major meteorological factor that determines the air quality. For a given wind speed greater than 4 m/sec, the air quality improved significantly. Urban impervious surface also contributes to the severe air pollution: that is, when the fraction of impervious surface increases, there is more severe air pollution. These results suggest that air quality management should be conducted when wind speed is less than 4 m/sec, especially at places with a larger fraction of urban impervious surface.

  12. Polyfluorinated Compounds in Serum Linked to Indoor Air in Office Environments

    PubMed Central

    Fraser, Alicia J; Webster, Thomas F; Watkins, Deborah J; Nelson, Jessica W; Stapleton, Heather M; Calafat, Antonia M; Kato, Kayoko; Shoeib, Mahiba; Vieira, Verónica M; McClean, Michael D

    2011-01-01

    We aimed to investigate the role of indoor office air on exposure to polyfluorinated compounds (PFCs) among office workers. Week-long, active air sampling was conducted during the winter of 2009 in 31 offices in Boston, MA. Air samples were analyzed for fluorotelomer alcohols (FTOHs), sulfonamides (FOSAs), and sulfonamidoethanols (FOSEs). Serum was collected from each participant (n=31) and analyzed for twelve PFCs including PFOA and PFOS. In air, FTOHs were present in the highest concentrations, particularly 8:2-FTOH (GM=9,920 pg/m3). FTOHs varied significantly by building with the highest levels observed in a newly constructed building. PFOA in serum was significantly correlated with air levels of 6:2-FTOH (r=0.43), 8:2-FTOH (r=0.60), and 10:2-FTOH (r=0.62). Collectively, FTOHs in air significantly predicted PFOA in serum (p < 0.001) and explained approximately 36% of the variation in serum PFOA concentrations. PFOS in serum was not associated with air levels of FOSAs/FOSEs. In conclusion, FTOH concentrations in office air significantly predict serum PFOA concentrations in office workers. Variation in PFC air concentrations by building is likely due to differences in the number, type, and age of potential sources such as carpeting, furniture and/or paint. PMID:22148395

  13. Polyfluorinated compounds in serum linked to indoor air in office environments.

    PubMed

    Fraser, Alicia J; Webster, Thomas F; Watkins, Deborah J; Nelson, Jessica W; Stapleton, Heather M; Calafat, Antonia M; Kato, Kayoko; Shoeib, Mahiba; Vieira, Verónica M; McClean, Michael D

    2012-01-17

    We aimed to investigate the role of indoor office air on exposure to polyfluorinated compounds (PFCs) among office workers. Week-long, active air sampling was conducted during the winter of 2009 in 31 offices in Boston, MA. Air samples were analyzed for fluorotelomer alcohols (FTOHs), sulfonamides (FOSAs), and sulfonamidoethanols (FOSEs). Serum was collected from each participant (n = 31) and analyzed for 12 PFCs including PFOA and PFOS. In air, FTOHs were present in the highest concentrations, particularly 8:2-FTOH (GM = 9920 pg/m(3)). FTOHs varied significantly by building with the highest levels observed in a newly constructed building. PFOA in serum was significantly correlated with air levels of 6:2-FTOH (r = 0.43), 8:2-FTOH (r = 0.60), and 10:2-FTOH (r = 0.62). Collectively, FTOHs in air significantly predicted PFOA in serum (p < 0.001) and explained approximately 36% of the variation in serum PFOA concentrations. PFOS in serum was not associated with air levels of FOSAs/FOSEs. In conclusion, FTOH concentrations in office air significantly predict serum PFOA concentrations in office workers. Variation in PFC air concentrations by building is likely due to differences in the number, type, and age of potential sources such as carpeting, furniture, and/or paint.

  14. Inflammatory markers in relation to long-term air pollution.

    PubMed

    Mostafavi, Nahid; Vlaanderen, Jelle; Chadeau-Hyam, Marc; Beelen, Rob; Modig, Lars; Palli, Domenico; Bergdahl, Ingvar A; Vineis, Paolo; Hoek, Gerard; Kyrtopoulos, Soterios Α; Vermeulen, Roel

    2015-08-01

    Long-term exposure to ambient air pollution can lead to chronic health effects such as cancer, cardiovascular and respiratory disease. Systemic inflammation has been hypothesized as a putative biological mechanism contributing to these adverse health effects. We evaluated the effect of long-term exposure to air pollution on blood markers of systemic inflammation. We measured a panel of 28 inflammatory markers in peripheral blood samples from 587 individuals that were biobanked as part of a prospective study. Participants were from Varese and Turin (Italy) and Umea (Sweden). Long-term air pollution estimates of nitrogen oxides (NOx) were available from the European Study of Cohorts for Air Pollution Effects (ESCAPE). Linear mixed models adjusted for potential confounders were applied to assess the association between NOx and the markers of inflammation. Long-term exposure to NOx was associated with decreased levels of interleukin (IL)-2, IL-8, IL-10 and tumor necrosis factor-α in Italy, but not in Sweden. NOx exposure levels were considerably lower in Sweden than in Italy (Sweden: median (5th, 95th percentiles) 6.65 μg/m(3) (4.8, 19.7); Italy: median (5th, 95th percentiles) 94.2 μg/m(3) (7.8, 124.5)). Combining data from Italy and Sweden we only observed a significant association between long-term exposure to NOx and decreased levels of circulating IL-8. We observed some indication for perturbations in the inflammatory markers due to long-term exposure to NOx. Effects were stronger in Italy than in Sweden, potentially reflecting the difference in air pollution levels between the two cohorts. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Aura OMI observations of regional SO2 and NO2 pollution changes from 2005 to 2015

    NASA Technical Reports Server (NTRS)

    Krotkov, Nickolay A.; McLinden, Chris A; Li, Can; Lamsal, Lok N.; Celarier, Edward A.; Marchenko, Sergey V.; Swartz, William H.; Bucsela, Eric J.; Joiner, Joanna; Duncan, Bryan N.; hide

    2016-01-01

    The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2/ and sulfur dioxide (SO2/, since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80 %, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50% reduction in 2012- 2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50 %, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air quality over different

  16. Aura OMI Observations of Regional SO2 and NO2 Pollution Changes from 2005 to 2015

    NASA Technical Reports Server (NTRS)

    Krotkov, Nickolay A.; McLinden, Chris A.; Li, Can; Lamsal, Lok N.; Celarier, Edward A.; Marchenko, Sergey V.; Swartz, William H.; Bucsela, Eric J.; Joiner, Joanna; Duncan, Bryan N.; hide

    2016-01-01

    The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80 percent, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50 percent reduction in 2012-2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50 percent, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air

  17. Aura OMI observations of regional SO2 and NO2 pollution changes from 2005 to 2014

    NASA Astrophysics Data System (ADS)

    Krotkov, N. A.; McLinden, C. A.; Li, C.; Lamsal, L. N.; Celarier, E. A.; Marchenko, S. V.; Swartz, W. H.; Bucsela, E. J.; Joiner, J.; Duncan, B. N.; Boersma, K. F.; Veefkind, J. P.; Levelt, P. F.; Fioletov, V. E.; Dickerson, R. R.; He, H.; Lu, Z.; Streets, D. G.

    2015-10-01

    The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for the different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2014, by more than 40 and 80 %, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50 % reduction in 2012-2014, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50 %, respectively, from 2005 to 2014. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved to be very valuable in documenting rapid changes in air quality over

  18. Aura OMI observations of regional SO2 and NO2 pollution changes from 2005 to 2015

    NASA Astrophysics Data System (ADS)

    Krotkov, Nickolay A.; McLinden, Chris A.; Li, Can; Lamsal, Lok N.; Celarier, Edward A.; Marchenko, Sergey V.; Swartz, William H.; Bucsela, Eric J.; Joiner, Joanna; Duncan, Bryan N.; Folkert Boersma, K.; Pepijn Veefkind, J.; Levelt, Pieternel F.; Fioletov, Vitali E.; Dickerson, Russell R.; He, Hao; Lu, Zifeng; Streets, David G.

    2016-04-01

    The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80 %, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50 % reduction in 2012-2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50 %, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air quality over different

  19. Observation of Cosmic-Ray Anisotropy with the IceTop Air Shower Array

    NASA Astrophysics Data System (ADS)

    Aartsen, M. G.; Abbasi, R.; Abdou, Y.; Ackermann, M.; Adams, J.; Aguilar, J. A.; Ahlers, M.; Altmann, D.; Andeen, K.; Auffenberg, J.; Bai, X.; Baker, M.; Barwick, S. W.; Baum, V.; Bay, R.; Beattie, K.; Beatty, J. J.; Bechet, S.; Becker Tjus, J.; Becker, K.-H.; Bell, M.; Benabderrahmane, M. L.; BenZvi, S.; Berdermann, J.; Berghaus, P.; Berley, D.; Bernardini, E.; Bertrand, D.; Besson, D. Z.; Bindig, D.; Bissok, M.; Blaufuss, E.; Blumenthal, J.; Boersma, D. J.; Bohaichuk, S.; Bohm, C.; Bose, D.; Böser, S.; Botner, O.; Brayeur, L.; Brown, A. M.; Bruijn, R.; Brunner, J.; Carson, M.; Casey, J.; Casier, M.; Chirkin, D.; Christy, B.; Clark, K.; Clevermann, F.; Cohen, S.; Cowen, D. F.; Cruz Silva, A. H.; Danninger, M.; Daughhetee, J.; Davis, J. C.; De Clercq, C.; De Ridder, S.; Descamps, F.; Desiati, P.; de Vries-Uiterweerd, G.; DeYoung, T.; Díaz-Vélez, J. C.; Dreyer, J.; Dumm, J. P.; Dunkman, M.; Eagan, R.; Eisch, J.; Ellsworth, R. W.; Engdegård, O.; Euler, S.; Evenson, P. A.; Fadiran, O.; Fazely, A. R.; Fedynitch, A.; Feintzeig, J.; Feusels, T.; Filimonov, K.; Finley, C.; Fischer-Wasels, T.; Flis, S.; Franckowiak, A.; Franke, R.; Frantzen, K.; Fuchs, T.; Gaisser, T. K.; Gallagher, J.; Gerhardt, L.; Gladstone, L.; Glüsenkamp, T.; Goldschmidt, A.; Golup, G.; Goodman, J. A.; Góra, D.; Grant, D.; Gross, A.; Grullon, S.; Gurtner, M.; Ha, C.; Haj Ismail, A.; Hallgren, A.; Halzen, F.; Hanson, K.; Heereman, D.; Heimann, P.; Heinen, D.; Helbing, K.; Hellauer, R.; Hickford, S.; Hill, G. C.; Hoffman, K. D.; Hoffmann, R.; Homeier, A.; Hoshina, K.; Huelsnitz, W.; Hulth, P. O.; Hultqvist, K.; Hussain, S.; Ishihara, A.; Jacobi, E.; Jacobsen, J.; Japaridze, G. S.; Jlelati, O.; Kappes, A.; Karg, T.; Karle, A.; Kiryluk, J.; Kislat, F.; Kläs, J.; Klein, S. R.; Köhne, J.-H.; Kohnen, G.; Kolanoski, H.; Köpke, L.; Kopper, C.; Kopper, S.; Koskinen, D. J.; Kowalski, M.; Krasberg, M.; Kroll, G.; Kunnen, J.; Kurahashi, N.; Kuwabara, T.; Labare, M.; Landsman, H.; Larson, M. J.; Lauer, R.; Lesiak-Bzdak, M.; Lünemann, J.; Madsen, J.; Maruyama, R.; Mase, K.; Matis, H. S.; McNally, F.; Meagher, K.; Merck, M.; Mészáros, P.; Meures, T.; Miarecki, S.; Middell, E.; Milke, N.; Miller, J.; Mohrmann, L.; Montaruli, T.; Morse, R.; Nahnhauer, R.; Naumann, U.; Nowicki, S. C.; Nygren, D. R.; Obertacke, A.; Odrowski, S.; Olivas, A.; Olivo, M.; O'Murchadha, A.; Panknin, S.; Paul, L.; Pepper, J. A.; Pérez de los Heros, C.; Pieloth, D.; Pirk, N.; Posselt, J.; Price, P. B.; Przybylski, G. T.; Rädel, L.; Rawlins, K.; Redl, P.; Resconi, E.; Rhode, W.; Ribordy, M.; Richman, M.; Riedel, B.; Rodrigues, J. P.; Rothmaier, F.; Rott, C.; Ruhe, T.; Ruzybayev, B.; Ryckbosch, D.; Saba, S. M.; Salameh, T.; Sander, H.-G.; Santander, M.; Sarkar, S.; Schatto, K.; Scheel, M.; Scheriau, F.; Schmidt, T.; Schmitz, M.; Schoenen, S.; Schöneberg, S.; Schönherr, L.; Schönwald, A.; Schukraft, A.; Schulte, L.; Schulz, O.; Seckel, D.; Seo, S. H.; Sestayo, Y.; Seunarine, S.; Sheremata, C.; Smith, M. W. E.; Soiron, M.; Soldin, D.; Spiczak, G. M.; Spiering, C.; Stamatikos, M.; Stanev, T.; Stasik, A.; Stezelberger, T.; Stokstad, R. G.; Stössl, A.; Strahler, E. A.; Ström, R.; Sullivan, G. W.; Taavola, H.; Taboada, I.; Tamburro, A.; Ter-Antonyan, S.; Tilav, S.; Toale, P. A.; Toscano, S.; Usner, M.; van der Drift, D.; van Eijndhoven, N.; Van Overloop, A.; van Santen, J.; Vehring, M.; Voge, M.; Vraeghe, M.; Walck, C.; Waldenmaier, T.; Wallraff, M.; Walter, M.; Wasserman, R.; Weaver, Ch.; Wendt, C.; Westerhoff, S.; Whitehorn, N.; Wiebe, K.; Wiebusch, C. H.; Williams, D. R.; Wissing, H.; Wolf, M.; Wood, T. R.; Woschnagg, K.; Xu, C.; Xu, D. L.; Xu, X. W.; Yanez, J. P.; Yodh, G.; Yoshida, S.; Zarzhitsky, P.; Ziemann, J.; Zierke, S.; Zilles, A.; Zoll, M.; IceCube Collaboration

    2013-03-01

    We report on the observation of anisotropy in the arrival direction distribution of cosmic rays at PeV energies. The analysis is based on data taken between 2009 and 2012 with the IceTop air shower array at the south pole. IceTop, an integral part of the IceCube detector, is sensitive to cosmic rays between 100 TeV and 1 EeV. With the current size of the IceTop data set, searches for anisotropy at the 10-3 level can, for the first time, be extended to PeV energies. We divide the data set into two parts with median energies of 400 TeV and 2 PeV, respectively. In the low energy band, we observe a strong deficit with an angular size of about 30° and an amplitude of (- 1.58 ± 0.46stat ± 0.52sys) × 10-3 at a location consistent with previous observations of cosmic rays with the IceCube neutrino detector. The study of the high energy band shows that the anisotropy persists to PeV energies and increases in amplitude to (- 3.11 ± 0.38stat ± 0.96sys) × 10-3.

  20. M31N 2008-12a-The Remarkable Recurrent Nova in M31-Panchromatic Observations of the 2015 Eruption

    NASA Technical Reports Server (NTRS)

    Darnley, M. J.; Henze, M.; Bode, M. F.; Hachisu, I.; Hernanz, M.; Hornoch, K.; Hounsell, R.; Kato, M.; Ness, J.- U.; Osborne, J. P.; hide

    2016-01-01

    The Andromeda Galaxy recurrent nova M31N 2008-12a had been observed in eruption 10 times, including yearly eruptions from 2008 to 2014. With a measured recurrence period of Prec = 351+/-13 days (we believe the true value to be half of this) and a white dwarf very close to the Chandrasekhar limit, M31N 2008-12a has become the leading pre-explosion supernova type Ia progenitor candidate. Following multi-wavelength follow-up observations of the 2013 and 2014 eruptions, we initiated a campaign to ensure early detection of the predicted 2015 eruption, which triggered ambitious ground- and space-based follow-up programs. In this paper we present the 2015 detection, visible to near-infrared photometry and visible spectroscopy, and ultraviolet and X-ray observations from the Swift observatory. The LCOGT 2 m (Hawaii) discovered the 2015 eruption, estimated to have commenced at August 28.28 +/- 0.12 UT. The 2013-2015 eruptions are remarkably similar at all wavelengths. New early spectroscopic observations reveal short-lived emission from material with velocities approx. 13,000 km/s, possibly collimated outflows. Photometric and spectroscopic observations of the eruption provide strong evidence supporting a red giant donor. An apparently stochastic variability during the early supersoft X-ray phase was comparable in amplitude and duration to past eruptions, but the 2013 and 2015 eruptions show evidence of a brief flux dip during this phase. The multi-eruption Swift/XRT spectra show tentative evidence of high-ionization emission lines above a high-temperature continuum. Following Henze et al. (2015a), the updated recurrence period based on all known eruptions is Prec 174 +/- 10 days, and we expect the next eruption of M31N 2008-12a to occur around 2016 mid-September.

  1. The impact of draught related to air velocity, air temperature and workload.

    PubMed

    Griefahn, B; Künemund, C; Gehring, U

    2001-08-01

    This experimental study was designed to test the hypotheses that the effects of draught increase with higher air velocity, with lower air temperature, and with lower workload. Thirty healthy young males were exposed to horizontal draught during 55 min while they operated an arm ergometer in a standing posture. Air velocity, air temperature, and workload were varied in 3 steps each, between 11 and 23 degrees C, 0.1 and 0.3 m/s, and 104 to 156 W/m2, respectively. The 27 combinations were distributed over subjects in a fractional factorial 3(3)-design. The participants were clothed for thermal neutrality. Workload was measured at the end of the sessions by respirometry. Draught-induced annoyance was determined every 5 min, separately for 10 body sites. Corresponding skin temperature was also recorded. The hypotheses were verified for the influence of air velocity and air temperature. Regarding workload, local heat production is probably decisive, meaning that draft-induced local annoyance is inversely related to workload in active but independent from workload in non-active body areas. To improve the situation for the workers concerned it is suggested to apply protective gloves that cover an as great area of the forearms as possible and to limit airflows to mean velocities of less than 0.2 m/s (with turbulence intensities of 50%).

  2. Diversification of the vacAs1m1 and vacAs2m2 Strains of Helicobacter pylori in Meriones unguiculatus

    PubMed Central

    Mendoza-Elizalde, Sandra; Arteaga-Resendiz, Nancy K.; Valencia-Mayoral, Pedro; Luna, Raúl C.; Moreno-Espinosa, Sarbelio; Arenas-Huertero, Francisco; Zúñiga, Gerardo; Velázquez-Guadarrama, Norma

    2016-01-01

    The bacterium Helicobacter pylori exhibits great genetic diversity, and the pathogenic roles of its virulence factors have been widely studied. However, the evolutionary dynamics of H. pylori strains during stomach colonization are not well-characterized. Here, we analyzed the microevolutionary dynamics of the toxigenic strain vacAs1m1, the non-toxigenic strain vacAs2m2, and a combination of both strains in an animal model over time. Meriones unguiculatus were inoculated with the following bacteria: group 1-toxigenic strain vacAs1m1/cagA+/cagE+/babA2+; ST181, group 2-non-toxigenic strain vacAs2m2/cagA+/cagE+/babA2+; ST2901, and group 3-both strains. The gerbils were euthanized at different time points (3, 6, 12, and 18 months). In group 1, genetic alterations were observed at 6 and 12 months. With the combination of both strains, group 3 also exhibited genetic alterations at 3 and 18 months; moreover, a chimera, vacA m1-m2, was detected. Additionally, four new sequence types (STs) were reported in the PubMLST database for H. pylori. Synonymous and non-synonymous mutations were analyzed and associated with alterations in amino acids. Microevolutionary analysis of the STs (PHYLOViZ) identified in each group revealed many mutational changes in the toxigenic (vacAs1m1) and non-toxigenic (vacAs2m2) strains. Phylogenetic assessments (eBURST) did not reveal clonal complexes. Our findings indicate that the toxigenic strain, vacAs1m1, and a combination of toxigenic and non-toxigenic strains acquired genetic material by recombination. The allelic combination, vacAs2m1, displayed the best adaptation in the animal model over time, and a chimera, m1-m2, was also identified, which confirmed previous reports. PMID:27877163

  3. Diversification of the vacAs1m1 and vacAs2m2 Strains of Helicobacter pylori in Meriones unguiculatus.

    PubMed

    Mendoza-Elizalde, Sandra; Arteaga-Resendiz, Nancy K; Valencia-Mayoral, Pedro; Luna, Raúl C; Moreno-Espinosa, Sarbelio; Arenas-Huertero, Francisco; Zúñiga, Gerardo; Velázquez-Guadarrama, Norma

    2016-01-01

    The bacterium Helicobacter pylori exhibits great genetic diversity, and the pathogenic roles of its virulence factors have been widely studied. However, the evolutionary dynamics of H. pylori strains during stomach colonization are not well-characterized. Here, we analyzed the microevolutionary dynamics of the toxigenic strain vacAs1m1 , the non-toxigenic strain vacAs2m2 , and a combination of both strains in an animal model over time. Meriones unguiculatus were inoculated with the following bacteria: group 1-toxigenic strain vacAs1m1/cagA+/cagE+/babA2+ ; ST181, group 2-non-toxigenic strain vacAs2m2/cagA+/cagE+/babA2+ ; ST2901, and group 3-both strains. The gerbils were euthanized at different time points (3, 6, 12, and 18 months). In group 1, genetic alterations were observed at 6 and 12 months. With the combination of both strains, group 3 also exhibited genetic alterations at 3 and 18 months; moreover, a chimera, vacA m1-m2 , was detected. Additionally, four new sequence types (STs) were reported in the PubMLST database for H. pylori . Synonymous and non-synonymous mutations were analyzed and associated with alterations in amino acids. Microevolutionary analysis of the STs (PHYLOViZ) identified in each group revealed many mutational changes in the toxigenic ( vacAs1m1 ) and non-toxigenic ( vacAs2m2 ) strains. Phylogenetic assessments (eBURST) did not reveal clonal complexes. Our findings indicate that the toxigenic strain, vacAs1m1 , and a combination of toxigenic and non-toxigenic strains acquired genetic material by recombination. The allelic combination, vacAs2m1 , displayed the best adaptation in the animal model over time, and a chimera, m1-m2 , was also identified, which confirmed previous reports.

  4. Magnetic Field Topology in Low-Mass Stars: Spectropolarimetric Observations of M Dwarfs

    NASA Astrophysics Data System (ADS)

    Phan-Bao, Ngoc; Lim, Jeremy; Donati, Jean-François; Johns-Krull, Christopher M.; Martín, Eduardo L.

    2009-10-01

    The magnetic field topology plays an important role in the understanding of stellar magnetic activity. While it is widely accepted that the dynamo action present in low-mass partially convective stars (e.g., the Sun) results in predominantly toroidal magnetic flux, the field topology in fully convective stars (masses below ~0.35 M sun) is still under debate. We report here our mapping of the magnetic field topology of the M4 dwarf G 164-31 (or Gl 490B), which is expected to be fully convective, based on time series data collected from 20 hr of observations spread over three successive nights with the ESPaDOnS spectropolarimeter. Our tomographic imaging technique applied to time series of rotationally modulated circularly polarized profiles reveals an axisymmetric large-scale poloidal magnetic field on the M4 dwarf. We then apply a synthetic spectrum fitting technique for measuring the average magnetic flux on the star. The flux measured in G 164-31 is |Bf| = 3.2 ± 0.4 kG, which is significantly greater than the average value of 0.68 kG determined from the imaging technique. The difference indicates that a significant fraction of the stellar magnetic energy is stored in small-scale structures at the surface of G 164-31. Our Hα emission light curve shows evidence for rotational modulation suggesting the presence of localized structure in the chromosphere of this M dwarf. The radius of the M4 dwarf derived from the rotational period and the projected equatorial velocity is at least 30% larger than that predicted from theoretical models. We argue that this discrepancy is likely primarily due to the young nature of G 164-31 rather than primarily due to magnetic field effects, indicating that age is an important factor which should be considered in the interpretation of this observational result. We also report here our polarimetric observations of five other M dwarfs with spectral types from M0 to M4.5, three of them showing strong Zeeman signatures. Based on

  5. Impacts of fire smoke plumes on regional air quality, 2006-2013.

    PubMed

    Larsen, Alexandra E; Reich, Brian J; Ruminski, Mark; Rappold, Ana G

    2017-12-29

    Increases in the severity and frequency of large fires necessitate improved understanding of the influence of smoke on air quality and public health. The objective of this study is to estimate the effect of smoke from fires across the continental U.S. on regional air quality over an extended period of time. We use 2006-2013 data on ozone (O 3 ), fine particulate matter (PM 2.5 ), and PM 2.5 constituents from environmental monitoring sites to characterize regional air quality and satellite imagery data to identify plumes. Unhealthy levels of O 3 and PM 2.5 were, respectively, 3.3 and 2.5 times more likely to occur on plume days than on clear days. With a two-stage approach, we estimated the effect of plumes on pollutants, controlling for season, temperature, and within-site and between-site variability. Plumes were associated with an average increase of 2.6 p.p.b. (2.5, 2.7) in O 3 and 2.9 µg/m 3 (2.8, 3.0) in PM 2.5 nationwide, but the magnitude of effects varied by location. The largest impacts were observed across the southeast. High impacts on O 3 were also observed in densely populated urban areas at large distance from the fires throughout the southeast. Fire smoke substantially affects regional air quality and accounts for a disproportionate number of unhealthy days.

  6. Activation of mTORC1/mTORC2 signaling in pediatric low-grade glioma and pilocytic astrocytoma reveals mTOR as a therapeutic target

    PubMed Central

    Hütt-Cabezas, Marianne; Karajannis, Matthias A.; Zagzag, David; Shah, Smit; Horkayne-Szakaly, Iren; Rushing, Elisabeth J.; Cameron, J. Douglas; Jain, Deepali; Eberhart, Charles G.; Raabe, Eric H.; Rodriguez, Fausto J.

    2013-01-01

    Background Previous studies support a role for mitogen-activated protein kinase pathway signaling, and more recently Akt/mammalian target of rapamycin (mTOR), in pediatric low-grade glioma (PLGG), including pilocytic astrocytoma (PA). Here we further evaluate the role of the mTORC1/mTORC2 pathway in order to better direct pharmacologic blockade in these common childhood tumors. Methods We studied 177 PLGGs and PAs using immunohistochemistry and tested the effect of mTOR blockade on 2 PLGG cell lines (Res186 and Res259) in vitro. Results Moderate (2+) to strong (3+) immunostaining was observed for pS6 in 107/177 (59%) PAs and other PLGGs, while p4EBP1 was observed in 35/115 (30%), pElF4G in 66/112 (59%), mTOR (total) in 53/113 (47%), RAPTOR (mTORC1 component) in 64/102 (63%), RICTOR (mTORC2 component) in 48/101 (48%), and pAkt (S473) in 63/103 (61%). Complete phosphatase and tensin homolog protein loss was identified in only 7/101 (7%) of cases. In PA of the optic pathways, compared with other anatomic sites, there was increased immunoreactivity for pS6, pElF4G, mTOR (total), RICTOR, and pAkt (P < .05). We also observed increased pS6 (P = .01), p4EBP1 (P = .029), and RICTOR (P = .05) in neurofibromatosis type 1 compared with sporadic tumors. Treatment of the PLGG cell lines Res186 (PA derived) and Res259 (diffuse astrocytoma derived) with the rapalog MK8669 (ridaforolimus) led to decreased mTOR pathway activation and growth. Conclusions These findings suggest that the mTOR pathway is active in PLGG but varies by clinicopathologic subtype. Additionally, our data suggest that mTORC2 is differentially active in optic pathway and neurofibromatosis type 1–associated gliomas. MTOR represents a potential therapeutic target in PLGG that merits further investigation. PMID:24203892

  7. The influence of layering and barometric pumping on firn air transport in a 2-D model

    NASA Astrophysics Data System (ADS)

    Birner, Benjamin; Buizert, Christo; Wagner, Till J. W.; Severinghaus, Jeffrey P.

    2018-06-01

    Ancient air trapped in ice core bubbles has been paramount to developing our understanding of past climate and atmospheric composition. Before air bubbles become isolated in ice, the atmospheric signal is altered in the firn column by transport processes such as advection and diffusion. However, the influence of low-permeability layers and barometric pumping (driven by surface pressure variability) on firn air transport is not well understood and is not readily captured in conventional one-dimensional (1-D) firn air models. Here we present a two-dimensional (2-D) trace gas advection-diffusion-dispersion model that accounts for discontinuous horizontal layers of reduced permeability. We find that layering or barometric pumping individually yields too small a reduction in gravitational settling to match observations. In contrast, when both effects are active, the model's gravitational fractionation is suppressed as observed. Layering focuses airflows in certain regions in the 2-D model, which acts to amplify the dispersive mixing resulting from barometric pumping. Hence, the representation of both factors is needed to obtain a realistic emergence of the lock-in zone. In contrast to expectations, we find that the addition of barometric pumping in the layered 2-D model does not substantially change the differential kinetic fractionation of fast- and slow-diffusing trace gases. Like 1-D models, the 2-D model substantially underestimates the amount of differential kinetic fractionation seen in actual observations, suggesting that further subgrid-scale processes may be missing in the current generation of firn air transport models. However, we find robust scaling relationships between kinetic isotope fractionation of different noble gas isotope and elemental ratios. These relationships may be used to correct for kinetic fractionation in future high-precision ice core studies and can amount to a bias of up to 0.45 °C in noble-gas-based mean ocean temperature

  8. Air quality in Delhi during the Commonwealth Games

    NASA Astrophysics Data System (ADS)

    Marrapu, P.; Cheng, Y.; Beig, G.; Sahu, S.; Srinivas, R.; Carmichael, G. R.

    2014-10-01

    Air quality during the Commonwealth Games (CWG, held in Delhi in October 2010) is analyzed using a new air quality forecasting system established for the games. The CWG stimulated enhanced efforts to monitor and model air quality in the region. The air quality of Delhi during the CWG had high levels of particles with mean values of PM2.5 and PM10 at the venues of 111 and 238 μg m-3, respectively. Black carbon (BC) accounted for ~ 10% of the PM2.5 mass. It is shown that BC, PM2.5 and PM10 concentrations are well predicted, but with positive biases of ~ 25%. The diurnal variations are also well captured, with both the observations and the modeled values showing nighttime maxima and daytime minima. A new emissions inventory, developed as part of this air quality forecasting initiative, is evaluated by comparing the observed and predicted species-species correlations (i.e., BC : CO; BC : PM2.5; PM2.5 : PM10). Assuming that the observations at these sites are representative and that all the model errors are associated with the emissions, then the modeled concentrations and slopes can be made consistent by scaling the emissions by 0.6 for NOx, 2 for CO, and 0.7 for BC, PM2.5, and PM10. The emission estimates for particles are remarkably good considering the uncertainty in the estimates due to the diverse spread of activities and technologies that take place in Delhi and the rapid rates of change. The contribution of various emission sectors including transportation, power, domestic and industry to surface concentrations are also estimated. Transport, domestic and industrial sectors all make significant contributions to PM levels in Delhi, and the sectoral contributions vary spatially within the city. Ozone levels in Delhi are elevated, with hourly values sometimes exceeding 100 ppb. The continued growth of the transport sector is expected to make ozone pollution a more pressing air pollution problem in Delhi. The sector analysis provides useful inputs into the design of

  9. Sustained Observations of Air-Sea Fluxes and Air-Sea Interaction at the Stratus Ocean Reference Station

    NASA Astrophysics Data System (ADS)

    Weller, Robert

    2014-05-01

    Since October 2000, a well-instrumented surface mooring has been maintained some 1,500 km west of the coast of northern Chile, roughly in the location of the climatological maximum in marine stratus clouds. Statistically significant increases in wind stress and decreases in annual net air-sea heat flux and in latent heat flux have been observed. If the increased oceanic heat loss continues, the region will within the next decade change from one of net annual heat gain by the ocean to one of neat annual heat loss. Already, annual evaporation of about 1.5 m of sea water a year acts to make the warm, salty surface layer more dense. Of interest is examining whether or not increased oceanic heat loss has the potential to change the structure of the upper ocean and potentially remove the shallow warm, salty mixed layer that now buffers the atmosphere from the interior ocean. Insights into how that warm, shallow layer is formed and maintained come from looking at oceanic response to the atmosphere at diurnal tie scales. Restratification each spring and summer is found to depend upon the occurrence of events in which the trade winds decay, allowing diurnal warming in the near-surface ocean to occur, and when the winds return resulting in a net upward step in sea surface temperature. This process is proving hard to accurately model.

  10. Green Bank Telescope Observations of HI in the circumgalactic medium of M31

    NASA Astrophysics Data System (ADS)

    Denny, Lucas; Early, Laura; Berg, Michelle; Howk, Chris; Lehner, Nicolas; Lockman, Felix; wotta, Christopher

    2018-01-01

    The nearby spiral galaxy M31 contains an extensive gaseous circumgalactic medium (CGM) that is being studied in project AMIGA, a large HST program to obtain UV spectroscopy of the CGM in absorption against background AGN. As part of this project, sensitive HI 21cm emission observations were made using the Robert C. Byrd Green Bank Telescope (GBT) toward 48 AGN at impact parameters between 25 kpc and 340 kpc. No emission was detected to a 5-sigma limit on log(NHI) of 17.6 cm-2 (Howk et al 2017, ApJ, 846, 141). We now report on a search for HI emission in 1x1 degree fields around 8 of the AGN to 5-sigma limits on log(NHI) of 17.9 cm-2. The new observations cover ~10 times the area of the M31 CGM covered by the Howk et al pointings, though at somewhat reduced sensitivity. Again, no HI emission was detected with the exception of the "Davies Cloud", a high-velocity cloud of M31 that has been known for some time. We will discuss the absence of significant HI emission in the context of the COS-Halos study of 44 galaxies at z~0.2, and how this finding may relate to the existence of HI clouds between M31 and M33 (Wolfe et al. 2016, ApJ, 816, 81).The GBT is a facility of the National Science Foundation, operated under a cooperative agreement by Associated Universities, Inc.

  11. Air contamination for predicting wound contamination in clean surgery: A large multicenter study.

    PubMed

    Birgand, Gabriel; Toupet, Gaëlle; Rukly, Stephane; Antoniotti, Gilles; Deschamps, Marie-Noelle; Lepelletier, Didier; Pornet, Carole; Stern, Jean Baptiste; Vandamme, Yves-Marie; van der Mee-Marquet, Nathalie; Timsit, Jean-François; Lucet, Jean-Christophe

    2015-05-01

    The best method to quantify air contamination in the operating room (OR) is debated, and studies in the field are controversial. We assessed the correlation between 2 types of air sampling and wound contaminations before closing and the factors affecting air contamination. This multicenter observational study included 13 ORs of cardiac and orthopedic surgery in 10 health care facilities. For each surgical procedure, 3 microbiologic air counts, 3 particles counts of 0.3, 0.5, and 5 μm particles, and 1 bacteriologic sample of the wound before skin closure were performed. We collected data on surgical procedures and environmental characteristics. Of 180 particle counts during 60 procedures, the median log10 of 0.3, 0.5, and 5 μm particles was 7 (interquartile range [IQR], 6.2-7.9), 6.1 (IQR, 5.4-7), and 4.6 (IQR, 0-5.2), respectively. Of 180 air samples, 50 (28%) were sterile, 90 (50%) had 1-10 colony forming units (CFU)/m(3) and 40 (22%) >10 CFU/m(3). In orthopedic and cardiac surgery, wound cultures at closure were sterile for 24 and 9 patients, 10 and 11 had 1-10 CFU/100 cm(2), and 0 and 6 had >10 CFU/100 cm(2), respectively (P < .01). Particle sizes and a turbulent ventilation system were associated with an increased number of air microbial counts (P < .001), but they were not associated with wound contamination (P = .22). This study suggests that particle counting is a good surrogate of airborne microbiologic contamination in the OR. Copyright © 2015 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Elsevier Inc. All rights reserved.

  12. Oxygen-selective immobilized liquid membranes for operation of lithium-air batteries in ambient air

    NASA Astrophysics Data System (ADS)

    Zhang, Jian; Xu, Wu; Liu, Wei

    In this work, nonaqueous electrolyte-based Li-air batteries with an O 2-selective membrane have been developed for operation in ambient air of 20-30% relative humidity (RH). The O 2 gas is continuously supplied through a membrane barrier layer at the interface of the cathode and ambient air. The membrane allows O 2 to permeate through while blocking moisture. Such membranes can be prepared by loading O 2-selective silicone oils into porous supports such as porous metal sheets and Teflon (PTFE) films. It was found that the silicone oil of high viscosity shows better performance. The immobilized silicone oil membrane in the porous PTFE film enabled the Li-air batteries with carbon black air electrodes to operate in ambient air (at 20% RH) for 16.3 days with a specific capacity of 789 mAh g -1 carbon and a specific energy of 2182 Wh kg -1 carbon. Its performance is much better than a reference battery assembled with a commercial, porous PTFE diffusion membranes as the moisture barrier layer on the cathode, which only had a discharge time of 5.5 days corresponding to a specific capacity of 267 mAh g -1 carbon and a specific energy of 704 Wh kg -1 carbon. The Li-air battery with the present selective membrane barrier layer even showed better performance in ambient air operation (20% RH) than the reference battery tested in the dry air box (<1% RH).

  13. Indoor air pollution in slum neighbourhoods of Addis Ababa, Ethiopia

    NASA Astrophysics Data System (ADS)

    Sanbata, Habtamu; Asfaw, Araya; Kumie, Abera

    2014-06-01

    An estimated 95% of the population of Ethiopia uses traditional biomass fuels, such as wood, dung, charcoal, or crop residues, to meet household energy needs. As a result of the harmful smoke emitted from the combustion of biomass fuels, indoor air pollution is responsible for more than 50,000 deaths annually and causes nearly 5% of the burden of disease in Ethiopia. Very limited research on indoor air pollution and its health impacts exists in Ethiopia. This study was, therefore, undertaken to assess the magnitude of indoor air pollution from household fuel use in Addis Ababa, the capital city of Ethiopia. During January and February, 2012, the concentration of fine particulate matter (PM2.5) in 59 households was measured using the University of California at Berkeley Particle Monitor (UCB PM). The raw data was analysed using Statistical Package of Social Science (SPSS version 20.0) software to determine variance between groups and descriptive statistics. The geometric mean of 24-h indoor PM2.5 concentration is approximately 818 μg m-3 (Standard deviation (SD = 3.61)). The highest 24-h geometric mean of PM2.5 concentration observed were 1134 μg m-3 (SD = 3.36), 637 μg m-3 (SD = 4.44), and 335 μg m-3 (SD = 2.51), respectively, in households using predominantly solid fuel, kerosene, and clean fuel. Although 24-h mean PM2.5 concentration between fuel types differed statistically (P < 0.05), post hoc pairwise comparison indicated no significant difference in mean concentration of PM2.5 between improved biomass stoves and traditional stoves (P > 0.05). The study revealed indoor air pollution is a major environmental and health hazard from home using biomass fuel in Addis Ababa. The use of clean fuels and efficient cooking stoves is recommended.

  14. Airbreathing Laser Propulsion Experiments with 1 {mu}m Terawatt Pharos IIILaser: Part 2

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Myrabo, L. N.; Lyons, P. W.; Jones, R. A.

    This basic research study examines the physics of airbreathing laser propulsion at the extreme flux range of 1-2x10{sup 11} W/cm{sup 2}--within the air breakdown threshold for l {mu}m radiation--using the terawatt Pharos III neodymium-glass pulsed laser. Six different experimental setups were employed using a 34 mm line focus with 66 {mu}m focal waist, positioned near the flat impulse surface. The 2nd Campaign investigated impulse generation with the laser beam focused at grazing incidence across near horizontal target surfaces, with pulse energies ranging from 55 to 186 J, and pulse-widths of 2 to 30 ns FWHM. Laser generated impulse was measuredmore » with a horizontal Plexiglas registered ballistic pendulum equipped with either a steel target insert or 0.5 Tesla permanent magnet (NEIT-40), to quantify changes in the momentum coupling coefficient (C{sub M}). Part 2 of this 2-part paper covers Campaign no. 2 results including C{sub M} performance data, and long exposure color photos of LP plasma phenomena.« less

  15. Air pollution in China: Status and spatiotemporal variations.

    PubMed

    Song, Congbo; Wu, Lin; Xie, Yaochen; He, Jianjun; Chen, Xi; Wang, Ting; Lin, Yingchao; Jin, Taosheng; Wang, Anxu; Liu, Yan; Dai, Qili; Liu, Baoshuang; Wang, Ya-Nan; Mao, Hongjun

    2017-08-01

    In recent years, China has experienced severe and persistent air pollution associated with rapid urbanization and climate change. Three years' time series (January 2014 to December 2016) concentrations data of air pollutants including particulate matter (PM 2.5 and PM 10 ) and gaseous pollutants (SO 2 , NO 2 , CO, and O 3 ) from over 1300 national air quality monitoring sites were studied to understand the severity of China's air pollution. In 2014 (2015, 2016), annual population-weighted-average (PWA) values in China were 65.8 (55.0, 50.7) μg m -3 for PM 2.5 , 107.8 (91.1, 85.7) μg m -3 for PM 10 , 54.8 (56.2, 57.2) μg m -3 for O 3 _8 h, 39.6 (33.3, 33.4) μg m -3 for NO 2 , 34.1 (26, 21.9) μg m -3 for SO 2 , 1.2 (1.1, 1.1) mg m -3 for CO, and 0.60 (0.59, 0.58) for PM 2.5 /PM 10 , respectively. In 2014 (2015, 2016), 7% (14%, 19%), 17% (27%, 34%), 51% (67%, 70%) and 88% (97%, 98%) of the population in China lived in areas that meet the level of annual PM 2.5 , PM 10 , NO 2 , and SO 2 standard metrics from Chinese Ambient Air Quality Standards-Grade II. The annual PWA concentrations of PM 2.5 , PM 10 , O 3 _8 h, NO 2 , SO 2 , CO in the Northern China are about 40.4%, 58.9%, 5.9%, 24.6%, 96.7%, and 38.1% higher than those in Southern China, respectively. Though the air quality has been improving recent years, PM 2.5 pollution in wintertime is worsening, especially in the Northern China. The complex air pollution caused by PM and O 3 (the third frequent major pollutant) is an emerging problem that threatens the public health, especially in Chinese mega-city clusters. NOx controls were more beneficial than SO 2 controls for improvement of annual PM air quality in the northern China, central, and southwest regions. Future epidemiologic studies are urgently required to estimate the health impacts associated with multi-pollutants exposure, and revise more scientific air quality index standards. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. The University of Tokyo Atacama Observatory 6.5m Telescope: enclosure design and wind analysis

    NASA Astrophysics Data System (ADS)

    Konishi, Masahiro; Sako, Shigeyuki; Uchida, Takanori; Araya, Ryou; Kim, Koui; Yoshii, Yuzuru; Doi, Mamoru; Kohno, Kotaro; Miyata, Takashi; Motohara, Kentaro; Tanaka, Masuo; Minezaki, Takeo; Morokuma, Tomoki; Tamura, Yoichi; Tanabé, Toshihiko; Kato, Natsuko; Kamizuka, Takafumi; Takahashi, Hidenori; Aoki, Tsutomu; Soyano, Takao; Tarusawa, Ken'ichi

    2016-07-01

    We present results on the computational fluid dynamics (CFD) numerical simulations as well as the wind tunnel experiments for the observation facilities of the University of Tokyo Atacama Observatory 6.5m Telescope being constructed at the summit of Co. Chajnantor in northern Chile. Main purpose of this study starting with the baseline design reported in 2014 is to analyze topographic effect on the wind behavior, and to evaluate the wind pressure, the air turbulence, and the air change (ventilation) efficiency in the enclosure. The wind velocity is found to be accelerated by a factor of 1.2 to reach the summit (78 m sec-1 expected at a maximum), and the resulting wind pressure (3,750 N m-2) is used for the framework design of the facilities. The CFD data reveals that the open space below the floor of the facilities works efficiently to drift away the air turbulence near the ground level which could significantly affect the dome seeing. From comparisons of the wind velocity field obtained from the CFD simulation for three configurations of the ventilation windows, we find that the windows at a level of the telescope secondary mirror have less efficiency of the air change than those at lower levels. Considering the construction and maintenance costs, and operation procedures, we finally decide to allocate 13 windows at a level of the observing floor, 12 at a level of the primary mirror, and 2 at the level of the secondary mirror. The opening area by those windows accounts for about 14% of the total interior surface of the enclosure. Typical air change rate of 20-30 per hour is expected at the wind velocity of 1 m sec-1.

  17. Application of OMI NO2 for Regional Air Quality Model Evaluation

    NASA Astrophysics Data System (ADS)

    Holloway, T.; Bickford, E.; Oberman, J.; Scotty, E.; Clifton, O. E.

    2012-12-01

    To support the application of satellite data for air quality analysis, we examine how column NO2 measurements from the Ozone Monitoring Instrument (OMI) aboard the NASA Aura satellite relate to ground-based and model estimates of NO2 and related species. Daily variability, monthly mean values, and spatial gradients in OMI NO2 from the Netherlands Royal Meteorological Institute (KNMI) are compared to ground-based measurements of NO2 from the EPA Air Quality System (AQS) database. Satellite data is gridded to two resolutions typical of regional air quality models - 36 km x 36 km over the continental U.S., and 12 km x 12 km over the Upper Midwestern U.S. Gridding is performed using the Wisconsin Horizontal Interpolation Program for Satellites (WHIPS), a publicly available software to support gridding of satellite data to model grids. Comparing daily OMI retrievals (13:45 daytime local overpass time) with ground-based measurements (13:00), we find January and July 2007 correlation coefficients (r-values) generally positive, with values higher in the winter (January) than summer (July) for most sites. Incidences of anti-correlation or low-correlation are evaluated with model simulations from the U.S. EPA Community Multiscale Air Quality Model version 4.7 (CMAQ). OMI NO2 is also used to evaluate CMAQ output, and to compare performance metrics for CMAQ relative to AQS measurements. We compare simulated NO2 across both the U.S. and Midwest study domains with both OMI NO2 (total column CMAQ values, weighted with the averaging kernel) and with ground-based observations (lowest model layer CMAQ values). 2007 CMAQ simulations employ emissions from the Lake Michigan Air Directors Consortium (LADCO) and meteorology from the Weather Research and Forecasting (WRF) model. Over most of the U.S., CMAQ is too high in January relative to OMI NO2, but too low in January relative to AQS NO2. In contrast, CMAQ is too low in July relative to OMI NO2, but too high relative to AQS NO2. These

  18. Third harmonic generation in air ambient and laser ablated carbon plasma

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singh, Ravi Pratap, E-mail: ravips@iitk.ac.in; Gupta, Shyam L.; Thareja, Raj K.

    2015-12-15

    We report the third harmonic generation of a nanosecond laser pulse (1.06 μm) in air ambient and in the presence of nanoparticles from laser ablated carbon plasma. Significant decrease in the threshold of third harmonic generation and multi-fold increment in the intensity of generated third harmonic is observed in presence of carbon plasma. The third harmonic in air is due to the quasi-resonant four photon process involving vibrationally excited states of molecular ion of nitrogen due to electron impact ionization and laser pulse. Following optical emission spectroscopic observations we conclude that the presence of C{sub 2} and CN in the ablatedmore » plume play a vital role in the observed third harmonic signals.« less

  19. Atmospheric Ionizing Radiation (AIR) ER-2 Preflight Analysis

    NASA Technical Reports Server (NTRS)

    Tai, Hsiang; Wilson, John W.; Maiden, D. L.

    1998-01-01

    Atmospheric ionizing radiation (AIR) produces chemically active radicals in biological tissues that alter the cell function or result in cell death. The AIR ER-2 flight measurements will enable scientists to study the radiation risk associated with the high-altitude operation of a commercial supersonic transport. The ER-2 radiation measurement flights will follow predetermined, carefully chosen courses to provide an appropriate database matrix which will enable the evaluation of predictive modeling techniques. Explicit scientific results such as dose rate, dose equivalent rate, magnetic cutoff, neutron flux, and air ionization rate associated with those flights are predicted by using the AIR model. Through these flight experiments, we will further increase our knowledge and understanding of the AIR environment and our ability to assess the risk from the associated hazard.

  20. Polycyclic aromatic hydrocarbon (PAH) and oxygenated PAH (OPAH) air-water exchange during the deepwater horizon oil spill.

    PubMed

    Tidwell, Lane G; Allan, Sarah E; O'Connell, Steven G; Hobbie, Kevin A; Smith, Brian W; Anderson, Kim A

    2015-01-06

    Passive sampling devices were used to measure air vapor and water dissolved phase concentrations of 33 polycyclic aromatic hydrocarbons (PAHs) and 22 oxygenated PAHs (OPAHs) at four Gulf of Mexico coastal sites prior to, during, and after shoreline oiling from the Deepwater Horizon oil spill (DWH). Measurements were taken at each site over a 13 month period, and flux across the water-air boundary was determined. This is the first report of vapor phase and flux of both PAHs and OPAHs during the DWH. Vapor phase sum PAH and OPAH concentrations ranged between 1 and 24 ng/m(3) and 0.3 and 27 ng/m(3), respectively. PAH and OPAH concentrations in air exhibited different spatial and temporal trends than in water, and air-water flux of 13 individual PAHs were strongly associated with the DWH incident. The largest PAH volatilizations occurred at the sites in Alabama and Mississippi in the summer, each nominally 10,000 ng/m(2)/day. Acenaphthene was the PAH with the highest observed volatilization rate of 6800 ng/m(2)/day in September 2010. This work represents additional evidence of the DWH incident contributing to air contamination, and provides one of the first quantitative air-water chemical flux determinations with passive sampling technology.

  1. Mid infrared observations of Van Maanen 2: no substellar companion.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Farihi, J; Becklin, E; Macintosh, B

    2004-11-03

    The results of a comprehensive infrared imaging search for the putative 0.06 M{sub {circle_dot}} astrometric companion to the 4.4 pc white dwarf van Mannen 2 are reported. Adaptive optics images acquired at 3.8 {micro}m reveal a diffraction limited core of 0.09 inch and no direct evidence of a secondary. Models predict that at 5 Gyr, a 50 M{sub J} brown dwarf would be only 1 magnitude fainter than van Maanen 2 at this wavelength and the astrometric analysis suggested a separation of 0.2 inch. In the case of a chance alignment along the line of sight, a 0.4 mag excessmore » should be measured. An independent photometric observation at the same wavelength reveals no excess. In addition, there exist published ISO observations of van Maanen 2 at 6.8 {micro}m and 15.0 {micro}m which are consistent with photospheric flux of a 6750 K white dwarf. If recent brown dwarf models are correct, there is no substellar companion with T{sub eff} {approx}> 500 K.« less

  2. Search for tachyons associated with extensive air showers in the ground level cosmic radiation

    NASA Technical Reports Server (NTRS)

    Masjed, H. F.; Ashton, F.

    1985-01-01

    Events detected in a shielded plastic scintillation counter occurring in the 26 microsec preceding the arrival of an extensive air shower at ground level with local electron density or = 20 m to the -2 power and the 240 microsec after its arrival have been studied. No significant excess of events (tachyons) arriving in the early time domain have been observed in a sample of 11,585 air shower triggers.

  3. Quantifying the impact of traffic-related air pollution on the indoor air quality of a naturally ventilated building.

    PubMed

    Tong, Zheming; Chen, Yujiao; Malkawi, Ali; Adamkiewicz, Gary; Spengler, John D

    2016-01-01

    Improper natural ventilation practices may deteriorate indoor air quality when in close proximity to roadways, although the intention is often to reduce energy consumption. In this study, we employed a CFD-based air quality model to quantify the impact of traffic-related air pollution on the indoor air quality of a naturally ventilated building. Our study found that the building envelope restricts dispersion and dilution of particulate matter. The indoor concentration in the baseline condition located 10m away from the roadway is roughly 16-21% greater than that at the edge of the roadway. The indoor flow recirculation creates a well-mixed zone with little variation in fine particle concentration (i.e., 253nm). For ultrafine particles (<100nm), a noticeable decrease in particle concentrations indoors with increasing distance from the road is observed due to Brownian and turbulent diffusion. In addition, the indoor concentration strongly depends on the distance between the roadway and building, particle size, wind condition, and window size and location. A break-even point is observed at D'~2.1 (normalized distance from the roadway by the width of the road). The indoor particle concentration is greater than that at the highway where D'<2.1, and vice versa. For new building planning, the distance from the roadway and the ambient wind condition need to be considered at the early design stage whereas the size and location of the window openings, the interior layout, and the placement of fresh air intakes are important to the indoor air quality of existing buildings adjacent to roadways. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. AIRES: an Airborne Infra-Red Echelle Spectrometer for SOFIA

    NASA Astrophysics Data System (ADS)

    Erickson, E. F.; Haas, M. R.; Colgan, S. W. J.; Roellig, T.; Simpson, J. P.; Telesco, C. M.; Pina, R. K.; Young, E. T.; Wolf, J.

    1997-12-01

    The Stratospheric Observatory for Infrared Astronomy, SOFIA, is a 2.7 meter telescope which is scheduled to begin observations in a Boeing 747 in October 2001. Among other SOFIA science instruments recently selected for development is the facility spectrometer AIRES. AIRES is designed for studies of a broad range of phenomena occuring in the interstellar medium (ISM) which are uniquely enabled by SOFIA. Examples include accretion and outflow in protostars and young stellar objects, the morphology, dynamics, and excitation of neutral and ionized gas at the Galactic center, and the recycling of material to the ISM from evolved stars. Astronomers using AIRES will be able to select any wavelength from 17 to 210 mu m., with corresponding spectral resolving powers ranging from 60,000 to 4000 in less than a minute. This entire wavelength range is important because it contains spectral features, often widely separated in wavelength, which characterize fundamental ISM processes. AIRES will utilize two-dimensional detector arrays and a large echelle grating to achieve spectral imaging with excellent sensitivity and unparalleled angular resolution at these wavelengths. As a facility science instrument, AIRES will provide guest investigators frequent opportunities for far infrared spectroscopic observations when SOFIA begins operations.

  5. 36 CFR 2.17 - Aircraft and air delivery.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Aircraft and air delivery. 2.17 Section 2.17 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.17 Aircraft and air delivery. (a) The following are...

  6. 36 CFR 2.17 - Aircraft and air delivery.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 1 2010-07-01 2010-07-01 false Aircraft and air delivery. 2.17 Section 2.17 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.17 Aircraft and air delivery. (a) The following are...

  7. 36 CFR 2.17 - Aircraft and air delivery.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 1 2011-07-01 2011-07-01 false Aircraft and air delivery. 2.17 Section 2.17 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR RESOURCE PROTECTION, PUBLIC USE AND RECREATION § 2.17 Aircraft and air delivery. (a) The following are...

  8. Ambient Air Pollution and Preeclampsia: A Spatiotemporal Analysis

    PubMed Central

    Figueras, Francesc; Basagaña, Xavier; Beelen, Rob; Martinez, David; Cirach, Marta; Schembari, Anna; Hoek, Gerard; Brunekreef, Bert; Nieuwenhuijsen, Mark J

    2013-01-01

    Background: Available evidence concerning the association between air pollution and preeclampsia is limited, and specific associations with early- and late-onset preeclampsia have not been assessed. Objectives: We investigated the association, if any, between preeclampsia (all, early-, and late-onset) and exposure to nitrogen dioxide, nitrogen oxides, particulate matter with aerodynamic diameter ≤ 2.5 μm (PM2.5; fine particles), ≤ 10 μm, and 2.5–10 μm, and PM2.5 light absorption (a proxy for elemental carbon) during the entire pregnancy and during the first, second, and third trimesters. Methods: This study was based on 8,398 pregnancies (including 103 cases of preeclampsia) among women residing in Barcelona, Spain (2000–2005). We applied a spatiotemporal exposure assessment framework using land use regression models to predict ambient pollutant levels during each week of pregnancy at the geocoded residence address of each woman at the time of birth. Logistic and conditional logistic regression models were used to estimate unadjusted and adjusted associations. Results: We found positive associations for most of our evaluated outcome–exposure pairs, with the strongest associations observed for preeclampsia and late-onset preeclampsia in relation to the third-trimester exposure to fine particulate pollutants, and for early-onset preeclampsia in relation to the first-trimester exposure to fine particulate pollutants. Among our investigated associations, those of first- and third-trimester exposures to PM2.5 and third-trimester exposure to PM2.5 absorbance and all preeclampsia, and third-trimester PM2.5 exposure and late-onset preeclampsia attained statistical significance. Conclusion: We observed increased risk of preeclampsia associated with exposure to fine particulate air pollution. Our findings, in combination with previous evidence suggesting distinct pathogenic mechanisms for early- and late-onset preeclampsia, support additional research on this

  9. Impact of London's road traffic air and noise pollution on birth weight: retrospective population based cohort study

    PubMed Central

    Smith, Rachel B; Fecht, Daniela; Gulliver, John; Beevers, Sean D; Dajnak, David; Blangiardo, Marta; Ghosh, Rebecca E; Hansell, Anna L; Kelly, Frank J; Anderson, H Ross

    2017-01-01

    Abstract Objective To investigate the relation between exposure to both air and noise pollution from road traffic and birth weight outcomes. Design Retrospective population based cohort study. Setting Greater London and surrounding counties up to the M25 motorway (2317 km2), UK, from 2006 to 2010. Participants 540 365 singleton term live births. Main outcome measures Term low birth weight (LBW), small for gestational age (SGA) at term, and term birth weight. Results Average air pollutant exposures across pregnancy were 41 μg/m3 nitrogen dioxide (NO2), 73 μg/m3 nitrogen oxides (NOx), 14 μg/m3 particulate matter with aerodynamic diameter <2.5 μm (PM2.5), 23 μg/m3 particulate matter with aerodynamic diameter <10 μm (PM10), and 32 μg/m3 ozone (O3). Average daytime (LAeq,16hr) and night-time (Lnight) road traffic A-weighted noise levels were 58 dB and 53 dB respectively. Interquartile range increases in NO2, NOx, PM2.5, PM10, and source specific PM2.5 from traffic exhaust (PM2.5 traffic exhaust) and traffic non-exhaust (brake or tyre wear and resuspension) (PM2.5 traffic non-exhaust) were associated with 2% to 6% increased odds of term LBW, and 1% to 3% increased odds of term SGA. Air pollutant associations were robust to adjustment for road traffic noise. Trends of decreasing birth weight across increasing road traffic noise categories were observed, but were strongly attenuated when adjusted for primary traffic related air pollutants. Only PM2.5 traffic exhaust and PM2.5 were consistently associated with increased risk of term LBW after adjustment for each of the other air pollutants. It was estimated that 3% of term LBW cases in London are directly attributable to residential exposure to PM2.5>13.8 μg/m3during pregnancy. Conclusions The findings suggest that air pollution from road traffic in London is adversely affecting fetal growth. The results suggest little evidence for an independent exposure-response effect of traffic related noise on birth weight

  10. Nitrogen Chemistry in Sea Level Air Following Large Radiation Doses.

    DTIC Science & Technology

    1984-06-15

    majur reactions NO + 0 + M +N0 2 + M (9) ’.o, NO+0 3 +N 2 +0 2 (1) NO + HO2 + NO2 + OH (11) 0 + NO2 NO + U 2 (12) H + NO2 + No + OOH (13) NO + OH...8217 ’, ,-7- 0 DEPARTMENT OF THE NAVY DEPARTMENT OF THE AIR FORCE (Continued) 0 Joint Cruise Missiles Project...Ofc Air Force Space Technology Ctr ATTN: JCMG-707 ATTN: YH Naval Air Systems Command Air Force !-!ight Aeronautical Lab/AAAD ATTN: PMA 271 ATjN: W

  11. 40 CFR Appendix M to Part 50 - [Reserved

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 2 2011-07-01 2011-07-01 false [Reserved] M Appendix M to Part 50 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS NATIONAL PRIMARY AND SECONDARY AMBIENT AIR QUALITY STANDARDS Appendix M to Part 50 [Reserved] ...

  12. 40 CFR Appendix M to Part 50 - [Reserved

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 2 2010-07-01 2010-07-01 false [Reserved] M Appendix M to Part 50 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS NATIONAL PRIMARY AND SECONDARY AMBIENT AIR QUALITY STANDARDS Appendix M to Part 50 [Reserved] ...

  13. TASAR Flight Trial 2: Assessment of Air Traffic Controller Acceptability of TASAR Requests

    NASA Technical Reports Server (NTRS)

    Idris, Husni; Enea, Gabriele

    2016-01-01

    In support of the Flight Trial (FT-2) of NASA's prototype of the Traffic Aware Strategic Aircrew Requests (TASAR) concept, observations were conducted at the air traffic facilities to identify and assess the main factors that affect the acceptability of pilot requests by air traffic controllers. Two observers shadowed air traffic controllers at the Atlanta (ZTL) and Jacksonville (ZJX) air traffic control centers as the test flight pilot made pre-scripted requests to invoke acceptability issues and then they interviewed the observed and other controllers voluntarily. Fifty controllers were interviewed with experience ranging from one to thirty-five years. All interviewed controllers were enthusiastic about the technology and accounting for sector boundaries in pilot requests, particularly if pilots can be made aware of high workload situations. All interviewed controllers accept more than fifty percent of pilot requests; forty percent of them reject less than ten percent of requests. The most common reason for rejecting requests is conflicting with traffic followed by violating letters of agreement (LOAs) and negatively impacting neighboring sector workload, major arrival and departure flows and flow restrictions. Thirty-six requests were made during the test, eight of which were rejected due to: the aircraft already handed off to another sector, violating LOA, opposing traffic, intruding into an active special use airspace (SUA), intruding into another center, weather, and unfamiliarity with the requested waypoint. Nine requests were accepted with delay mostly because the controller needed to locate unfamiliar waypoints or to coordinate with other controllers.

  14. CNT Sheet Air Electrode for the Development of Ultra-High Cell Capacity in Lithium-Air Batteries

    PubMed Central

    Nomura, Akihiro; Ito, Kimihiko; Kubo, Yoshimi

    2017-01-01

    Lithium-air batteries (LABs) are expected to provide a cell with a much higher capacity than ever attained before, but their prototype cells present a limited areal cell capacity of no more than 10 mAh cm−2, mainly due to the limitation of their air electrodes. Here, we demonstrate the use of flexible carbon nanotube (CNT) sheets as a promising air electrode for developing ultra-high capacity in LAB cells, achieving areal cell capacities of up to 30 mAh cm−2, which is approximately 15 times higher than the capacity of cells with lithium-ion battery (LiB) technology (~2mAh cm−2). During discharge, the CNT sheet electrode experienced enormous swelling to a thickness of a few millimeters because of the discharge product deposition of lithium peroxide (Li2O2), but the sheet was fully recovered after being fully charged. This behavior results from the CNT sheet characteristics of the flexible and fibrous conductive network and suggests that the CNT sheet is an effective air electrode material for developing a commercially available LAB cell with an ultra-high cell capacity. PMID:28378746

  15. Mixing Heights and Three-Dimensional Ozone Structure Observed by Airborne Lidar During the 2006 Texas Air Quality Study

    NASA Astrophysics Data System (ADS)

    Hardesty, R. M.; Senff, C. J.; Alvarez, R. J.; Banta, R. M.; Sandberg, S. P.; Weickmann, A. M.; Darby, L. S.

    2007-12-01

    A new all solid state ozone lidar was deployed on a NOAA Twin Otter to study boundary layer ozone and aerosol, mostly around Houston, during the 2006 Texas Air Quality Study. The new instrument transmits high pulse-rate, low pulse-energy light at 3 wavelengths in the ultraviolet to obtain ozone profiles with 500 m horizontal resolution and 90 m vertical resolution. During the Texas field study, 20 research flights resulted in nearly 70 hours of ozone measurements during the period from August 1 to September 15. Science objectives included characterization of background ozone levels over rural areas near Houston and Dallas and variability and structure of the boundary layer over different surface types, including urban, wooded, and agricultural land surface areas as well as over Galveston Bay and the Gulf of Mexico. A histogram of all boundary layer ozone concentration measurements showed a bimodal distribution with modes at 45 ppb and 70 ppb. The lower mode correlated with southerly flow, when relatively clean air was transported onshore into the Houston area. Segmenting the observations during southerly flow by region, including the Gulf of Mexico, land within about 55 km from the coast, and further inland indicated that background levels increased by about 10 ppb as air was transported onshore. During the latter part of the experiment, as more pollution was imported into the Houston region, background levels rose to nearly 80 ppb in regions N of Houston. Two flights aimed at observing import of ozone into Texas from the east showed that ozone concentrations increased and boundary layer depths deepened upwind of Houston between September 4 and September 8. Background levels rose by more than 10 ppb over this period. In addition to ozone measurements, we also estimated boundary layer height based on maximum gradient in observed backscatter. The technique worked well when the layer topped by the strongest gradient extends down to the surface. Investigation of the

  16. Implications of RCP emissions on future PM2.5 air quality and direct radiative forcing over China

    NASA Astrophysics Data System (ADS)

    Li, Ke; Liao, Hong; Zhu, Jia; Moch, Jonathan M.

    2016-11-01

    Severe PM2.5 air pollution in China and the First Grand National Standard (FGNS), implemented in 2016 (annual PM2.5 concentration target of less than 35 µg m-3), necessitate urgent reduction strategies. This study applied the nested-grid version of the Goddard Earth Observing System (GEOS) chemical transport model (GEOS-Chem) to quantify 2000-2050 changes in PM2.5 air quality and related direct radiative forcing (DRF) in China, based on future emission changes under the representative concentration pathway (RCP) scenarios of RCP2.6, RCP4.5, RCP6.0, and RCP8.5. In the near term (2000-2030), a projected maximum increase in PM2.5 concentrations of 10-15 µg m-3 is found over east China under RCP6.0 and RCP8.5 and less than 5 µg m-3 under RCP2.6 and RCP4.5. In the long term (2000-2050), PM2.5 pollution clearly improves, and the largest decrease in PM2.5 concentrations of 15-30 µg m-3 is over east China under all RCPs except RCP6.0. Focusing particularly on highly polluted regions, we find that Beijing-Tianjin-Hebei (BTH) wintertime PM2.5 concentrations meeting the FGNS occur after 2040 under RCP2.6, RCP4.5, and RCP8.5, and summertime PM2.5 concentrations reach this goal by 2030 under RCP2.6 and RCP4.5. In Sichuan Basin (SCB), wintertime PM2.5 concentrations below the FGNS occur only in 2050 under RCP2.6 and RCP4.5, although future summertime PM2.5 will be well controlled. The difficulty in controlling future PM2.5 concentrations relates to unmitigated high levels of nitrate, although NOx and SO2 emissions show substantial reductions during 2020-2040. The changes in aerosol concentrations lead to positive aerosol DRF over east China (20°-45°N, 100°-125°E) by 1.22, 1.88, and 0.66 W m-2 in 2050 relative to 2000 under RCP2.6, RCP4.5, and RCP8.5, respectively. When considering both health and climate effects of PM2.5 over China, for example, PM2.5 concentrations averaged over east China under RCP4.5 (RCP2.6) decrease by 54% (43%) in 2050 relative to 2000, but at the

  17. Stewart Air National Guard Base, NY, C-5M Painting Refurbishment Assessment

    DTIC Science & Technology

    2012-12-06

    is asthma due to sensitization. After sensitization, any exposure , even to levels below the occupational exposure limit, can produce an asthmatic...Consultative Services Division provide a comprehensive exposure and risk assessment of the corrosion control process conducted on the C-5M in Building...101 at Stewart Air National Guard Base, NY. This facility was previously a fuels systems maintenance facility. At the time of this assessment, the

  18. Investigation into the dehydration of selenate doped Na2M(SO4)2·2H2O (M = Mn, Fe, Co and Ni): Stabilisation of the high Na content alluaudite phases Na3M1.5(SO4)3-1.5x(SeO4)1.5x (M = Mn, Co and Ni) through selenate incorporation

    NASA Astrophysics Data System (ADS)

    Driscoll, L. L.; Kendrick, E.; Knight, K. S.; Wright, A. J.; Slater, P. R.

    2018-02-01

    In this paper we report an investigation into the phases formed on dehydration of Na2M(SO4)2-x(SeO4)x·2H2O (0 ≤ x ≤ 1; M = Mn, Fe, Co and Ni). For the Fe series, all attempts to dehydrate the samples doped with selenate resulted in amorphous products, and it is suspected that a side redox reaction involving the Fe and selenate may be occurring leading to phase decomposition and hence the lack of a crystalline product on dehydration. For M = Mn, Co, Ni, the structure observed was shown to depend upon the transition metal cation and level of selenate doping. An alluaudite phase, Na3M1.5(SO4)3-1.5x(SeO4)1.5x, was observed for the selenate doped compositions, with this phase forming as a single phase for x ≥ 0.5 M = Co, and x = 1.0 M = Ni. For M = Mn, the alluaudite structure is obtained across the series, albeit with small impurities for lower selenate content samples. Although the alluaudite-type phases Na2+2y(Mn/Co)2-y(SO4)3 have recently been reported [1,2], doping with selenate appears to increase the maximum sodium content within the structure. Moreover, the selenate doped Ni based samples reported here are the first examples of a Ni sulfate/selenate containing system exhibiting the alluaudite structure.

  19. Temporal variability of air-pollutants over Abu Dhabi, UAE

    NASA Astrophysics Data System (ADS)

    Ghedira, H.; Ben Romdhane, H.; Beegum S, N.

    2013-12-01

    Air quality, the measure of the concentrations of gaseous pollutants and size or number of particulate matter, is one of the most important problems worldwide and has strong implications on human health, ecosystems, as well as regional and global climate. The levels of air pollutants such as sulphur dioxide (SO2), particulate matters (PM10, PM2.5), Ozone (O3), Nitrogen dioxide (NO2), Carbon monoxide (CO), etc. show an alarming increase in urban cities across the world and in many cases, the concentrations have grown well above the World Health Organization's guidelines for ambient air-quality standards. Here, we present the periodic fluctuations observed in the concentrations of air pollutants such as SO2, NO2, O3, CO, H2S, NMHC (Non methane Hydro Carbon) and VOC (volatile organic compounds) based on the measurements collected during the period 2008-2010 at Masdar City, Abu Dhabi (24.42oN, 54.61oE, 7m MSL). The measurements were carried out using an Air Quality Monitoring System (AQM60). All these pollutant species showed statistical periodic: diurnal, monthly, seasonal and annual variations. Diurnally, all the species, except ozone, depicted an afternoon low and nighttime/early morning high, attributed to the dynamics of the local atmospheric boundary layer. Whereas, an opposite pattern with daytime high and nighttime low was observed for O3, as the species is formed in the troposphere by catalytic photochemical reactions of NOx with CO, CH4 and other VOCs. Seasonally, the pollutants depicted higher values during summer and relatively lower values during winter, associated with changes in synoptic airmass types and/or removal processes. Concentrations of all the gaseous pollutants are within the National Ambient Air Quality Standards (NAAQS) throughout the year, whereas the PM10 often exceeded the limits, especially during dust storm episodes.

  20. Fγ: A new observable for photon-hadron discrimination in hybrid air shower events

    NASA Astrophysics Data System (ADS)

    Niechciol, M.; Risse, M.; Ruehl, P.; Settimo, M.; Younk, P. W.; Yushkov, A.

    2018-01-01

    To search for ultra-high-energy photons in primary cosmic rays, air shower observables are needed that allow a good separation between primary photons and primary hadrons. We present a new observable, Fγ, which can be extracted from ground-array data in hybrid events, where simultaneous measurements of the longitudinal and the lateral shower profile are performed. The observable is based on a template fit to the lateral distribution measured by the ground array with the template taking into account the complementary information from the measurement of the longitudinal profile, i.e. the primary energy and the geometry of the shower. Fγ shows a very good photon-hadron separation, which is even superior to the separation given by the well-known Xmax observable (the atmospheric depth of the shower maximum). At energies around 1 EeV (10 EeV), Fγ provides a background rejection better than 97.8 % (99.9 %) at a signal efficiency of 50 %. Advantages of the observable Fγ are its technical stability with respect to irregularities in the ground array (i.e. missing or temporarily non-operating stations) and that it can be applied over the full energy range accessible to the air shower detector, down to its threshold energy. Furthermore, Fγ complements nicely to Xmax such that both observables can well be combined to achieve an even better discrimination power, exploiting the rich information available in hybrid events.

  1. How Will Air Quality Change in South Asia by 2050?

    NASA Astrophysics Data System (ADS)

    Kumar, Rajesh; Barth, Mary C.; Pfister, G. G.; Delle Monache, L.; Lamarque, J. F.; Archer-Nicholls, S.; Tilmes, S.; Ghude, S. D.; Wiedinmyer, C.; Naja, M.; Walters, S.

    2018-02-01

    Exposure to unhealthy air causes millions of premature deaths and damages crops sufficient to feed a large portion of the South Asian population every year. However, little is known about how future air quality in South Asia will respond to changing human activities. Here we examine the combined effect of changes in climate and air pollutant emissions projected by the Representative Concentration Pathways (RCP) 8.5 and RCP6.0 on air quality of South Asia in 2050 using a state-of-the-science Nested Regional Climate model with Chemistry (NRCM-Chem). RCP8.5 and RCP6.0 are selected to represent scenarios of highest and lowest air pollution in South Asia by 2050. NRCM-Chem shows the ability to capture observed key features of variability in meteorological parameters, ozone and related gases, and aerosols. NRCM-Chem results show that surface ozone and particulate matter of less than 2.5 μm in diameter will increase significantly by midcentury in South Asia under the RCP8.5 but remain similar to present day under RCP6.0. No RCP suggest an improvement in air pollution in South Asia by midcentury. Under RCP8.5, the frequency of air pollution events is predicted to increase by 20-120 days per year in 2050 compared to the present-day conditions, with particulate matter of less than 2.5 μm in diameter predicted to breach the World Health Organization ambient air quality guidelines on an almost daily basis in many parts of South Asia. These results indicate that while the RCP scenarios project a global improvement in air quality, they generally result in degrading air quality in South Asia.

  2. M2-F1 ejection seat test at South Edwards

    NASA Technical Reports Server (NTRS)

    1963-01-01

    The M2-F1 was fitted with an ejection seat before the airtow flights began. The project selected the seat used in the T-37 as modified by the Weber Company to use a rocket rather than a ballistic charge for ejection. To test the ejection seat, the Flight Research Center's Dick Klein constructed a plywood mockup of the M2-F1's top deck and canopy. On the first firings, the test was unsuccessful, but on the final test the dummy in the seat landed safely. The M2-F1 ejection seat was later used in the two Lunar Landing Research Vehicles and the three Lunar Landing Training Vehicles. Three of them crashed, but in each case the pilot ejected from the vehicle successfully. The wingless, lifting body aircraft design was initially conceived as a means of landing an aircraft horizontally after atmospheric reentry. The absence of wings would make the extreme heat of re-entry less damaging to the vehicle. In 1962, Dryden management approved a program to build a lightweight, unpowered lifting body as a prototype to flight test the wingless concept. It would look like a 'flying bathtub,' and was designated the M2-F1, the 'M' referring to 'manned' and 'F' referring to 'flight' version. It featured a plywood shell placed over a tubular steel frame crafted at Dryden. Construction was completed in 1963. The first flight tests of the M2-F1 were over Rogers Dry Lake at the end of a tow rope attached to a hopped-up Pontiac convertible driven at speeds up to about 120 mph. This vehicle needed to be able to tow the M2-F1 on the Rogers Dry Lakebed adjacent to NASA's Flight Research Center (FRC) at a minimum speed of 100 miles per hour. To do that, it had to handle the 400-pound pull of the M2-F1. Walter 'Whitey' Whiteside, who was a retired Air Force maintenance officer working in the FRC's Flight Operations Division, was a dirt-bike rider and hot-rodder. Together with Boyden 'Bud' Bearce in the Procurement and Supply Branch of the FRC, Whitey acquired a Pontiac Catalina convertible with

  3. Airborne lidar wind detection at 2 μm

    NASA Astrophysics Data System (ADS)

    Targ, Russell; Hawley, James G.; Steakley, Bruce C.; Ames, Lawrence L.; Robinson, Paul A.

    1995-06-01

    NASA and the FAA have expressed interest in laser radar's capabilities to detect wind profiles at altitude. A number of programs have been addressing the technical feasibility and utility of laser radar atmospheric backscatter data to determine wind profiles and wind hazards for aircraft guidance and navigation. In addition, the U.S. Air Force is investigating the use of airborne lidar to achieve precision air drop capability, and to increase the accuracy of the AC- 130 gunship and the B-52 bomber by measuring the wind field from the aircraft to the ground. There are emerging capabilities of airborne laser radar to measure wind velocities and detect turbulence and other atmospheric disturbances out in front of an aircraft in real time. The measurement of these parameters can significantly increase fuel efficiency, flight safety, airframe lifetime, and terminal area capacity for new and existing aircraft. This is achieved through wind velocity detection, turbulence avoidance, active control utilization to alleviate gust loading, and detection of wingtip wake vortices produced by landing aircraft. This paper presents the first flight test results of an all solid-state 2-micrometers laser radar system measuring the wind field profile 1 to 2 km in front of an aircraft in real time. We find 0.7-m/s wind measurement accuracy for the system which is configured in a rugged, light weight, high- performance ARINC package.

  4. The Observational and Theoretical Tidal Radii of Globular Clusters in M87

    NASA Astrophysics Data System (ADS)

    Webb, Jeremy J.; Sills, Alison; Harris, William E.

    2012-02-01

    Globular clusters have linear sizes (tidal radii) which theory tells us are determined by their masses and by the gravitational potential of their host galaxy. To explore the relationship between observed and expected radii, we utilize the globular cluster population of the Virgo giant M87. Unusually deep, high signal-to-noise images of M87 are used to measure the effective and limiting radii of approximately 2000 globular clusters. To compare with these observations, we simulate a globular cluster population that has the same characteristics as the observed M87 cluster population. Placing these simulated clusters in the well-studied tidal field of M87, the orbit of each cluster is solved and the theoretical tidal radius of each cluster is determined. We compare the predicted relationship between cluster size and projected galactocentric distance to observations. We find that for an isotropic distribution of cluster velocities, theoretical tidal radii are approximately equal to observed limiting radii for R gc < 10 kpc. However, the isotropic simulation predicts a steep increase in cluster size at larger radii, which is not observed in large galaxies beyond the Milky Way. To minimize the discrepancy between theory and observations, we explore the effects of orbital anisotropy on cluster sizes, and suggest a possible orbital anisotropy profile for M87 which yields a better match between theory and observations. Finally, we suggest future studies which will establish a stronger link between theoretical tidal radii and observed radii.

  5. Coupling between Chemical and Meteorological Processes under Persistent Cold-Air Pool Conditions: Evolution of Wintertime PM2.5 Pollution Events and N2O5 Observations in Utah's Salt Lake Valley.

    PubMed

    Baasandorj, Munkhbayar; Hoch, Sebastian W; Bares, Ryan; Lin, John C; Brown, Steven S; Millet, Dylan B; Martin, Randal; Kelly, Kerry; Zarzana, Kyle J; Whiteman, C David; Dube, William P; Tonnesen, Gail; Jaramillo, Isabel Cristina; Sohl, John

    2017-06-06

    The Salt Lake Valley experiences severe fine particulate matter pollution episodes in winter during persistent cold-air pools (PCAPs). We employ measurements throughout an entire winter from different elevations to examine the chemical and dynamical processes driving these episodes. Whereas primary pollutants such as NO x and CO were enhanced twofold during PCAPs, O 3 concentrations were approximately threefold lower. Atmospheric composition varies strongly with altitude within a PCAP at night with lower NO x and higher oxidants (O 3 ) and oxidized reactive nitrogen (N 2 O 5 ) aloft. We present observations of N 2 O 5 during PCAPs that provide evidence for its role in cold-pool nitrate formation. Our observations suggest that nighttime and early morning chemistry in the upper levels of a PCAP plays an important role in aerosol nitrate formation. Subsequent daytime mixing enhances surface PM 2.5 by dispersing the aerosol throughout the PCAP. As pollutants accumulate and deplete oxidants, nitrate chemistry becomes less active during the later stages of the pollution episodes. This leads to distinct stages of PM 2.5 pollution episodes, starting with a period of PM 2.5 buildup and followed by a period with plateauing concentrations. We discuss the implications of these findings for mitigation strategies.

  6. Location of and landing on a source of human body odour by female Culex quinquefasciatus in still and moving air.

    PubMed

    Lacey, Emerson S; Cardé, Ring T

    2012-06-01

    The orientation to and landing on a source of human odour by female Culex quinquefasciatus Say (Diptera: Culicidae) is observed in a wind tunnel without an airflow or with a laminar airflow of 0.2 m s -1 . Odours from human feet are collected by 'wearing' clean glass beads inside a stocking and presenting beads in a Petri dish in a wind tunnel. Mosquitoes are activated by brief exposure to a 1 L min -1 jet of 4% CO 2 positioned 10 cm from the release cage. In moving air at 0.2 m s -1 , a mean of 3.45 ± 0.49 landings are observed in 10 min trials (5 mosquitoes per trial), whereas 6.50 ± 0.96 landings are recorded in still air. Furthermore, 1.45 ± 0.31mosquitoes are recorded on beads at any one time in moving air (a measure of individuals landing versus one landing multiple times) compared to 3.10 ± 0.31 in still air. Upwind flight to beads in moving air is demonstrated by angular headings of flight immediately prior to landing, whereas approaches to beads in still air are oriented randomly. The mean latency until first landing is 226.7 ± 17.98 s in moving air compared to 122.5 ± 24.18 in still air. Strategies used to locate a prospective host at close range in still air are considered.

  7. UAVSAR observations of triggered slip on the Imperial, Superstition Hills, and East Elmore Ranch Faults associated with the 2010 M 7.2 El Mayor-Cucapah earthquake

    NASA Astrophysics Data System (ADS)

    Donnellan, Andrea; Parker, Jay; Hensley, Scott; Pierce, Marlon; Wang, Jun; Rundle, John

    2014-03-01

    4 April 2010 M 7.2 El Mayor-Cucapah earthquake that occurred in Baja California, Mexico and terminated near the U.S. Mexican border caused slip on the Imperial, Superstition Hills, and East Elmore Ranch Faults. The pattern of slip was observed using radar interferometry from NASA's Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) instrument collected on 20-21 October 2009 and 12-13 April 2010. Right-lateral slip of 36 ± 9 and 14 ± 2 mm occurred on the Imperial and Superstition Hills Faults, respectively. Left-lateral slip of 9 ± 2 mm occurred on the East Elmore Ranch Fault. The widths of the zones of displacement increase northward suggesting successively more buried fault motion to the north. The observations show a decreasing pattern of slip northward on a series of faults in the Salton Trough stepping between the El Mayor-Cucapah rupture and San Andreas Fault. Most of the motion occurred at the time of the M 7.2 earthquake and the UAVSAR observations are consistent with field, creepmeter, GPS, and Envisat observations. An additional 28 ± 1 mm of slip at the southern end of the Imperial Fault over a <1 km wide zone was observed over a 1 day span a week after the earthquake suggesting that the fault continued to slip at depth following the mainshock. The total moment release on the three faults is 2.3 × 1023-1.2 × 1024 dyne cm equivalent to a moment magnitude release of 4.9-5.3, assuming shallow slip depths ranging from 1 to 5 km.

  8. H2 Fluorescence in M dwarf Systems: A Stellar Origin

    NASA Astrophysics Data System (ADS)

    Kruczek, Nicholas; France, Kevin; Evonosky, William; Youngblood, Allison; Loyd, R. O. Parke

    2017-01-01

    Observations of Lyα-driven H2 fluorescence can be a useful tool for measuring the abundance of H2 in exoplanet atmospheres. This emission has been previously observed in M dwarfs with planetary systems but at too low of a signal to determine its origin. It may have been originating in the atmospheres of planets, but conditions within these systems also mean that the H2 could be residing on the stellar surface or in a circumstellar disk. We use observations from the ``Measurements of the Ultraviolet Spectral Characteristics of Low-mass Exoplanet Host Stars" (MUSCLES) Hubble Space Telescope (HST) Treasury Survey to study H2 fluorescence in M dwarfs with and without confirmed planets to determine the origin of the emission. The results are further supported by the direct imaging of a candidate M dwarf system using the HST-Advanced Camera for Surveys/Solar Blind Channel. We constrain the location of the fluorescing H2 through analysis of the line profiles and determine that the emission is originating on the star. We verify that this interpretation is consistent with 1D radiative transfer models that are optimized using the spectra of the MUSCLES stars and find that the H2 likely resides in starspots or a cool region of the lower chromosphere.

  9. Satellite-observed NO2, SO2, and HCHO Vertical Column Densities in East Asia: Recent Changes and Comparisons with Regional Model

    NASA Astrophysics Data System (ADS)

    Kim, H. C.; Lee, P.; Kim, S.; Mok, J.; Yoo, H. L.; Bae, C.; Kim, B. U.; Lim, Y. K.; Woo, J. H.; Park, R.

    2015-12-01

    This study reports the recent changes in tropospheric NO2, SO2, and HCHO vertical column densities (VCD) in East Asia observed from multiple satellites, highlighting especially the annual trend changes of NO2 and SO2 over Beijing-Tianjin-Hebei (BTH) region of China since 2010. Tropospheric VCD data from Global Ozone Monitoring Experiment (GOME), SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY), Ozone Monitoring Instrument (OMI) and GOME-2, retrieved from the Royal Netherlands Meteorological Institute (KNMI) and OMI National Aeronautics and Space Administration (NASA) standard products, are utilized to investigate the annual trends of NO2, SO2, and HCHO VCDs from 2001 to 2015. They are also compared with simulations from Community Multi-scale Air Quality Model (CMAQ) based forecast system by the Integrated Multi-scale Air Quality System for Korea (IMAQS-K) of Ajou University. Until 2011, the changes in NO2 VCD over East Asian countries agree well with the findings of previous research, including the impact of the economic downturn during 2008-2009 and the subsequent quick recovery in China. After peaking in 2011, the NO2 VCD observations from active instruments (OMI and GOME-2) over China started to show a slower decreasing trend, mostly led by the rapid changes in the BTH region in northern China. On the other hand, SO2 started to decline earlier, from 2007, but inclined back from 2010 to 2012, and then back to declining trend since 2012. While satellite observations show dramatic recent changes, the model could not reproduce those changes mostly due to its use of fixed emission inventory. We conclude that rapid update of latest emission inventory is necessary for an accurate forecast of regional air quality in east Asia, especially for upcoming international sports events in PyeongChang (Korea), Tokyo (Japan) and Beijing (China) in 2018, 2020 and 2022, respectively.

  10. Acute and recent air pollution exposure and cardiovascular events at labour and delivery

    PubMed Central

    Männistö, Tuija; Mendola, Pauline; Grantz, Katherine Laughon; Leishear, Kira; Sundaram, Rajeshwari; Sherman, Seth; Ying, Qi; Liu, Danping

    2017-01-01

    Objective To study the relationship between acute air pollution exposure and cardiovascular events during labour/delivery. Methods The Consortium on Safe Labor (2002–2008), an observational US cohort with 223 502 singleton deliveries provided electronic medical records. Air pollution exposure was estimated by modified Community Multiscale Air Quality models. Cardiovascular events (cardiac failure/arrest, stroke, myocardial infarcts and other events) were recorded in the hospital discharge records for 687 pregnancies (0.3%). Logistic regression with generalised estimating equations estimated the relationship between cardiovascular events and daily air pollutant levels for delivery day and the 7 days preceding delivery. Results Increased odds of cardiovascular events were observed for each IQR increase in exposure to nitric oxides at 5 and 6 days prior to delivery (OR=1.17, 99% CI 1.04 to 1.30 and OR=1.15, 1.03 to 1.28, respectively). High exposure to toxic air pollution species such as ethylbenzene (OR=1.50, 1.08 to 2.09), m-xylene (OR=1.54, 1.11 to 2.13), o-xylene (OR=1.51, 1.09 to 2.09), p-xylene (OR=1.43, 1.03 to 1.99) and toluene (OR=1.42, 1.02 to 1.97) at 5 days prior to delivery were also associated with cardiovascular events. Decreased odds of events were observed with exposure to ozone. Conclusions Air pollution in the days prior to delivery, especially nitrogen oxides and some toxic air pollution species, was associated with increased risk of cardiovascular events during the labour/delivery admission. PMID:26105036

  11. Effect of air flow on tubular solar still efficiency

    PubMed Central

    2013-01-01

    Background An experimental work was reported to estimate the increase in distillate yield for a compound parabolic concentrator-concentric tubular solar still (CPC-CTSS). The CPC dramatically increases the heating of the saline water. A novel idea was proposed to study the characteristic features of CPC for desalination to produce a large quantity of distillate yield. A rectangular basin of dimension 2 m × 0.025 m × 0.02 m was fabricated of copper and was placed at the focus of the CPC. This basin is covered by two cylindrical glass tubes of length 2 m with two different diameters of 0.02 m and 0.03 m. The experimental study was operated with two modes: without and with air flow between inner and outer tubes. The rate of air flow was fixed throughout the experiment at 4.5 m/s. On the basis of performance results, the water collection rate was 1445 ml/day without air flow and 2020 ml/day with air flow and the efficiencies were 16.2% and 18.9%, respectively. Findings The experimental study was operated with two modes: without and with air flow between inner and outer tubes. The rate of air flow was fixed throughout the experiment at 4.5 m/s. Conclusions On the basis of performance results, the water collection rate was 1445 ml/day without air flow and 2020 ml/day with air flow and the efficiencies were 16.2% and 18.9%, respectively. PMID:23587020

  12. Effect of air flow on tubular solar still efficiency.

    PubMed

    Thirugnanasambantham, Arunkumar; Rajan, Jayaprakash; Ahsan, Amimul; Kandasamy, Vinothkumar

    2013-01-01

    An experimental work was reported to estimate the increase in distillate yield for a compound parabolic concentrator-concentric tubular solar still (CPC-CTSS). The CPC dramatically increases the heating of the saline water. A novel idea was proposed to study the characteristic features of CPC for desalination to produce a large quantity of distillate yield. A rectangular basin of dimension 2 m × 0.025 m × 0.02 m was fabricated of copper and was placed at the focus of the CPC. This basin is covered by two cylindrical glass tubes of length 2 m with two different diameters of 0.02 m and 0.03 m. The experimental study was operated with two modes: without and with air flow between inner and outer tubes. The rate of air flow was fixed throughout the experiment at 4.5 m/s. On the basis of performance results, the water collection rate was 1445 ml/day without air flow and 2020 ml/day with air flow and the efficiencies were 16.2% and 18.9%, respectively. THE EXPERIMENTAL STUDY WAS OPERATED WITH TWO MODES: without and with air flow between inner and outer tubes. The rate of air flow was fixed throughout the experiment at 4.5 m/s. On the basis of performance results, the water collection rate was 1445 ml/day without air flow and 2020 ml/day with air flow and the efficiencies were 16.2% and 18.9%, respectively.

  13. A-O Q-switching of 2.1-μm laser

    NASA Astrophysics Data System (ADS)

    Zheng, Jia; Liu, Jingjiao; Tang, Yi; Hu, Yongzhao

    2005-01-01

    2.1μm solid state laser operating at room temperature is a very useful laser source for optical communication, medical care, air pollution monitoring and Lidar, etc. It is eye-safe. It is also a very ideal pump source for optic parametric oscillator to get 3μm -5μm radiation. In order to further explore its potential applications, higher peak power and shorter pulse width are very desirable. Q-switching the laser is a most practical way to realize those goals. Among the most common used Q-switching techniques, mechanical Q-switching is not preferred due to that it involves use of a rotating motor, which has lower life time and causes undesirable vibration. E-O Q-switch material in this wavelength range is very expensive and quite susceptible to optical damage. On the other hand, low OH concentration quartz material exhibits very low absorption at the 2.1μm. The Cr:Tm:Ho:YAG 2.1μm laser has undesirable lower gain from the laser efficiency point of view, but offers a feasibility of using the A-O device for the Q-switching even the laser is pulse pumped. The Cr:Tm:Ho:YAG 2.1μm laser is a so called quasi-three level laser, which is characterized as having a higher threshold and lower gain. This study is focused on the optimization of the laser resonator design and the A-O Q-switch design for a higher laser peak power and shorter pulse width. Factors considered in the study include AO Q-switch"s RF frequency, modulation depth, active aperture, resonator length, resonator loss and pumping design, etc. Experiment results are compared with the Q-switched quasi-three level laser model. Final result of the Q-switched 2.1μm laser after preliminary optimization will be presented.

  14. Slip-Effect Functional Air Filter for Efficient Purification of PM2.5

    PubMed Central

    Zhao, Xinglei; Wang, Shan; Yin, Xia; Yu, Jianyong; Ding, Bin

    2016-01-01

    Fabrication of air filtration materials (AFM) that allow air to easily flow through while retaining particles is a significant and urgent need due to the harmful airborne particulate matter pollution; however, this is still a challenging research area. Herein, we report novel slip-effect functional nanofibrous membranes with decreased air resistance (reduction rate of 40%) due to the slip flow of air molecules on the periphery of nanofibers. This was achieved through careful control over the diameters of electrospun polyacrylonitrile fibers and aperture size of fiber assembly. Fiber assembly with 86% of fiber diameters between 60–100 nm was found to be most effective for slip flow, as these diameters are close to the mean free path of air molecules (65.3 nm). Significantly, an equilibrium factor τ = df/d2 has been introduced to elucidate the effect of distance of adjacent fibers on the drag force of airflow. Furthermore, the most effective aperture size (>3.5 μm) for slip-effect has been determined. Ultimately, the new material displayed low air resistance of 29.5 Pa, high purification efficiency of 99.09%, good transmittance of 77%, and long service life. The successful fabrication of such materials can facilitate the development of high-performance AFMs for various applications. PMID:27748419

  15. Structural and Magnetic Properties of M(mnt)(2) Salts (M = Ni, Pt, Cu) with a Ferrocene-Based Cation, [FcCH(2)N(CH(3))(3)](+). Interplay between M.M and M.S Intermolecular Interactions.

    PubMed

    Pullen, Anthony E.; Faulmann, Christophe; Pokhodnya, Konstantin I.; Cassoux, Patrick; Tokumoto, Madoka

    1998-12-28

    A series of metal bis-mnt complexes (mnt = 1,2-dithiolatomaleonitrile) with the trimethylammonium methylferrocene cation have been synthesized and characterized using X-ray diffraction, magnetic susceptibility, and differential scanning calorimetry measurements. The complexes have the formulas (FcCH(2)NMe(3))[Ni(mnt)(2)] (2), (FcCH(2)NMe(3))[Pt(mnt)(2)] (3), and (FcCH(2)NMe(3))(2)[Cu(mnt)(2)] (4) (where Fc = ferrocene). At 300 K, the crystal structures of 1:1 complexes 2 and 3 are very similar. They consist of pairs of [M(mnt)(2)](-) in a slipped configuration packed in stacks. Each [M(mnt)(2)](-) stack is separated from adjacent stacks by two columns of cations. Within the pairs, the [M(mnt)(2)](-) anions interact via short M.S contacts, while there are no short contacts between the pairs. Complex 4, which has a 2:1 stoichiometry, exhibits a markedly different packing arrangement of the anionic units. Due to the special position of the Cu atom in the asymmetric unit cell, [Cu(mnt)(2)](2)(-) dianions are completely isolated from each other. The magnetic susceptibility behavior of the nickel complex is consistent with the presence of magnetically isolated, antiferromagnetically (AF) coupled [Ni(mnt)(2)](-) pairs with the AF exchange parameter, J = -840 cm(-)(1). The platinum complex undergoes an endothermic structural phase transition (T(p)) at 247 K. Below T(p) its structure is characterized by the formation of magnetically isolated [Pt(mnt)(2)](2)(2)(-) dimers in an eclipsed configuration with short Pt.Pt and S.S contacts between monomers. In the magnetic properties, the structural changes reveal themselves as an abrupt susceptibility drop implying a substantial increase of the AF exchange parameter. A mechanism of the phase transition in the platinum compound is proposed. For compound 4, paramagnetic behavior is observed.

  16. OBSERVATION OF TeV GAMMA RAYS FROM THE FERMI BRIGHT GALACTIC SOURCES WITH THE TIBET AIR SHOWER ARRAY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amenomori, M.; Bi, X. J.; Ding, L. K.

    2010-01-20

    Using the Tibet-III air shower array, we search for TeV {gamma}-rays from 27 potential Galactic sources in the early list of bright sources obtained by the Fermi Large Area Telescope at energies above 100 MeV. Among them, we observe seven sources instead of the expected 0.61 sources at a significance of 2{sigma} or more excess. The chance probability from Poisson statistics would be estimated to be 3.8 x 10{sup -6}. If the excess distribution observed by the Tibet-III array has a density gradient toward the Galactic plane, the expected number of sources may be enhanced in chance association. Then, themore » chance probability rises slightly, to 1.2 x 10{sup -5}, based on a simple Monte Carlo simulation. These low chance probabilities clearly show that the Fermi bright Galactic sources have statistically significant correlations with TeV {gamma}-ray excesses. We also find that all seven sources are associated with pulsars, and six of them are coincident with sources detected by the Milagro experiment at a significance of 3{sigma} or more at the representative energy of 35 TeV. The significance maps observed by the Tibet-III air shower array around the Fermi sources, which are coincident with the Milagro {>=}3{sigma} sources, are consistent with the Milagro observations. This is the first result of the northern sky survey of the Fermi bright Galactic sources in the TeV region.« less

  17. Measurement of cytoplasmic Ca2+ concentration in Saccharomyces cerevisiae induced by air cold plasma

    NASA Astrophysics Data System (ADS)

    Xiaoyu, DONG

    2018-03-01

    In this study, a novel approach to measure the absolute cytoplasmic Ca2+ concentration ([Ca2+]cyt) using the Ca2+ indicator fluo-3 AM was established. The parameters associated with the probe fluo-3 AM were optimized to accurately determine fluorescence intensity from the Ca2+-bound probe. Using three optimized parameters (final concentration of 6 mM probe, incubation time of 135 min, loading probe before plasma treatment), the maximum fluorescence intensity (F max = 527.8 a.u.) and the minimum fluorescence intensity (F min = 63.8 a.u.) were obtained in a saturated Ca2+ solution or a solution of lacking Ca2+. Correspondingly, the maximum [Ca2+]cyt induced by cold plasma was 1232.5 nM. Therefore, the Ca2+ indicator fluo-3 AM was successfully applied to measure the absolute [Ca2+]cyt in Saccharomyces cerevisiae stimulated by cold plasma at atmospheric air pressure.

  18. Air pollution over the North China Plain and its implication of regional transport: A new sight from the observed evidences.

    PubMed

    Ge, Baozhu; Wang, Zifa; Lin, Weili; Xu, Xiaobin; Li, Jie; Ji, Dongshen; Ma, Zhiqiang

    2018-03-01

    High concentrations of the fine particles (PM 2.5 ) are frequently observed during all seasons over the North China Plain (NCP) region in recent years. In NCP, the contributions of regional transports to certain area, e.g. Beijing city, are often discussed and estimated by models when considering an effective air pollution controlling strategy. In this study, we selected three sites from southwest to northeast in NCP, in which the concentrations of air pollutants displayed a multi-step decreasing trend in space. An approach based on the measurement results at these sites has been developed to calculate the relative contributions of the minimal local emission (MinLEC) and the maximum regional transport (MaxRTC) to the air pollutants (e.g., SO 2 , NO 2 , CO, PM 2.5 ) in Beijing. The minimal influence of local emission is estimated by the difference of the air pollutants' concentrations between urban and rural areas under the assumption of a similar influence of regional transport. Therefore, it's convenient to estimate the contributions of local emission from regional transport based on the selective measurement results instead of the complex numerical model simulation. For the whole year of 2013, the averaged contributions of MinLEC (MaxRTC) for NO 2 , SO 2 , PM 2.5 and CO are 61.7% (30.7%), 46.6% (48%), 52.1% (40.2%) and 35.8% (45.5%), respectively. The diurnal variation of MaxRTC for SO 2 , PM 2.5 and CO shows an increased pattern during the afternoon and reached a peak (more than 50%) around 18:00, which indicates that the regional transport is the important role for the daytime air pollution in Beijing. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Revised Uniform Summary of Surface Weather Observations (RUSSWO) for Yucca Flat Air Strip, Mercury, Nevada. Parts A-F

    DTIC Science & Technology

    1979-09-28

    FREQUENCY OF WIND DIRECTION AND SPEED (FROM HOURLY OBSERVATIONS) 03133 YUCCA FLAT AIR STRIP NV 6-77 SEF STATION STATION KANE TSARS NONIN ALL WF&THEk 1200...92.8 92.8 929 92.# 92.2 92.! 92. 92*, 92.6T 9*81 93.,* ~ 9. 3 3 393.3. 93. 9393. 93.22 93 9 9393 93󈨡 93.2 93.21 93.4 93.5 W 94.9 95.09a 9590 9. 51 51

  20. Added value of stress related gene inductions in HepG2 cells as effect measurement in monitoring of air pollution

    NASA Astrophysics Data System (ADS)

    Nobels, Ingrid; Vanparys, Caroline; Van den Heuvel, Rosette; Vercauteren, Jordy; Blust, Ronny

    2012-08-01

    In this study we studied the effects of particulate matter samples (PM) through gene expression analysis in a routine air quality monitoring campaign by the Flemish Environment Agency (VMM, Belgium). We selected a human hepatoma (HepG2) multiple endpoint reporter assay for targeted stress related endpoint screening. Organic extracts of air samples (total suspended particles, TSP) were collected during one year in an industrial, urban and background location in Flanders, Belgium. Simultaneously, meteorological conditions (temperature, wind speed and precipitation) and particulate matter size ≤ 10 μM (PM10), organic (OC), elemental (EC) and total (TC) carbon were monitored and air samples were collected for chemical analysis (11 PAHs). Correlations between the induction of the different stress genes and the chemical pollutants were analysed. Exposure of HepG2 cells to daily air equivalents (20 m3) of organic TSP extracts revealed the dominant induction of the xenobiotic response element (Xre) and phase I (Cyp1A1) and phase II (GstYa) biotransformation enzymes. Additional effects were the induction of c-Fos, a proto-oncogen and Gadd45, a marker for cell cycle disturbance and responsive to genotoxic compounds. Inductions of other relevant pathways, such as sequestration of heavy metals, retinoids response, protein misfolding and increased cAMP levels were measured occasionally. A significant correlation was found between the genes Cyp1A1 (a typical marker for presence of PAHs and dioxin like compounds), c-Fos, Gadd45, (responsive to DNA damaging compounds) and the amount of PM10 and elemental carbon (EC) whereas no correlation was found between these genes and total PAHs content. This may suggest that the observed induction of Cyp1A1 and DNA damage related genes was provoked (partially) by other particle bound compounds (e.g. pesticides, PCBs, brominated flame retardants, dioxins, …), than PAHs. The contribution of particle bound compounds, other than PAHs might

  1. The air afterglow revisited

    NASA Technical Reports Server (NTRS)

    Kaufman, F.

    1972-01-01

    The air afterglow, 0 + NO2 chemiluminescence, is discussed in terms of fluorescence, photodissociation, and quantum theoretical calculations of NO2. The experimental results presented include pressure dependence, M-dependence, spectral dependence of P and M, temperature dependence, and infrared measurements. The NO2 energy transfer model is also discussed.

  2. Current Applications of OMI Tropospheric NO2 Data for Air Quality and a Look to the Future

    NASA Technical Reports Server (NTRS)

    Pickering, Kenneth E.; Bucsela, E.; Allen, D.; Prados, A.; Gleason, J.; Kondragunta, S.

    2010-01-01

    Ozone Monitoring Instrument (OMI) Tropospheric NO2 products are being used to enhance the ability to monitor changes in NO2 air quality, update emission inventories, and evaluate regional air quality models. Trends in tropospheric column NO2 have been examined over the eastern United States in relation to emissions changes mandated by regulatory actions. Decreases of 20 to 40 percent over the period 2005 to 2008 were noted, largely in response to major emission reductions at power plants. The OMI data have been used to identify regions in which the opposite trend has been found. We have also used OMI NO2 in efforts to improve emission inventories for NOx emissions from soil. Lightning NOx emissions have been added to CMAQ, the US Environmental Protection Agency's regional air quality model. Evaluation of the resulting NO2 columns in the model is being conducted using the OMI NO2 observations. Community Multiscale Air Quality (CMAQ) together with the OMI NO2 data comprise a valuable tool for monitoring and predicting air quality. Looking to the future, we expect that the combination of Global Ozone Monitoring Experiment-2 (GOME-2) (morning) and OMI (afternoon) data sets obtained through use of the same retrieval algorithms will substantially increase the possibility of successful integration of satellite information into regional air quality forecast models. Farther down the road, we anticipate the Geostationary Coastal and Air Pollution Events (GEO-CAPE) platform to supply data possibly on an hourly basis, allowing much more comprehensive analysis of air quality from space.

  3. Attaining whole-ecosystem warming using air and deep-soil heating methods with an elevated CO2 atmosphere

    DOE PAGES

    Hanson, Paul J.; Riggs, Jeffery S.; Nettles, IV, W. Robert; ...

    2017-02-24

    This paper describes the operational methods to achieve and measure both deep-soil heating (0–3 m) and whole-ecosystem warming (WEW) appropriate to the scale of tall-stature, high-carbon, boreal forest peatlands. The methods were developed to allow scientists to provide a plausible set of ecosystem-warming scenarios within which immediate and longer-term (1 decade) responses of organisms (microbes to trees) and ecosystem functions (carbon, water and nutrient cycles) could be measured. Elevated CO 2 was also incorporated to test how temperature responses may be modified by atmospheric CO 2 effects on carbon cycle processes. The WEW approach was successful in sustaining a widemore » range of aboveground and belowground temperature treatments (+0, +2.25, +4.5, +6.75 and +9 °C) in large 115 m 2 open-topped enclosures with elevated CO 2 treatments (+0 to +500 ppm). Air warming across the entire 10 enclosure study required ~90 % of the total energy for WEW ranging from 64 283 mega Joules (MJ) d –1 during the warm season to 80 102 MJ d –1 during cold months. Soil warming across the study required only 1.3 to 1.9 % of the energy used ranging from 954 to 1782 MJ d –1 of energy in the warm and cold seasons, respectively. The residual energy was consumed by measurement and communication systems. Sustained temperature and elevated CO 2 treatments were only constrained by occasional high external winds. This paper contrasts the in situ WEW method with closely related field-warming approaches using both aboveground (air or infrared heating) and belowground-warming methods. It also includes a full discussion of confounding factors that need to be considered carefully in the interpretation of experimental results. As a result, the WEW method combining aboveground and deep-soil heating approaches enables observations of future temperature conditions not available in the current observational record, and therefore provides a plausible glimpse of future environmental

  4. Attaining whole-ecosystem warming using air and deep-soil heating methods with an elevated CO2 atmosphere

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hanson, Paul J.; Riggs, Jeffery S.; Nettles, IV, W. Robert

    This paper describes the operational methods to achieve and measure both deep-soil heating (0–3 m) and whole-ecosystem warming (WEW) appropriate to the scale of tall-stature, high-carbon, boreal forest peatlands. The methods were developed to allow scientists to provide a plausible set of ecosystem-warming scenarios within which immediate and longer-term (1 decade) responses of organisms (microbes to trees) and ecosystem functions (carbon, water and nutrient cycles) could be measured. Elevated CO 2 was also incorporated to test how temperature responses may be modified by atmospheric CO 2 effects on carbon cycle processes. The WEW approach was successful in sustaining a widemore » range of aboveground and belowground temperature treatments (+0, +2.25, +4.5, +6.75 and +9 °C) in large 115 m 2 open-topped enclosures with elevated CO 2 treatments (+0 to +500 ppm). Air warming across the entire 10 enclosure study required ~90 % of the total energy for WEW ranging from 64 283 mega Joules (MJ) d –1 during the warm season to 80 102 MJ d –1 during cold months. Soil warming across the study required only 1.3 to 1.9 % of the energy used ranging from 954 to 1782 MJ d –1 of energy in the warm and cold seasons, respectively. The residual energy was consumed by measurement and communication systems. Sustained temperature and elevated CO 2 treatments were only constrained by occasional high external winds. This paper contrasts the in situ WEW method with closely related field-warming approaches using both aboveground (air or infrared heating) and belowground-warming methods. It also includes a full discussion of confounding factors that need to be considered carefully in the interpretation of experimental results. As a result, the WEW method combining aboveground and deep-soil heating approaches enables observations of future temperature conditions not available in the current observational record, and therefore provides a plausible glimpse of future environmental

  5. Using eddy covariance to measure the dependence of air-sea CO2 exchange rate on friction velocity

    NASA Astrophysics Data System (ADS)

    Landwehr, Sebastian; Miller, Scott D.; Smith, Murray J.; Bell, Thomas G.; Saltzman, Eric S.; Ward, Brian

    2018-03-01

    Parameterisation of the air-sea gas transfer velocity of CO2 and other trace gases under open-ocean conditions has been a focus of air-sea interaction research and is required for accurately determining ocean carbon uptake. Ships are the most widely used platform for air-sea flux measurements but the quality of the data can be compromised by airflow distortion and sensor cross-sensitivity effects. Recent improvements in the understanding of these effects have led to enhanced corrections to the shipboard eddy covariance (EC) measurements.Here, we present a revised analysis of eddy covariance measurements of air-sea CO2 and momentum fluxes from the Southern Ocean Surface Ocean Aerosol Production (SOAP) study. We show that it is possible to significantly reduce the scatter in the EC data and achieve consistency between measurements taken on station and with the ship underway. The gas transfer velocities from the EC measurements correlate better with the EC friction velocity (u*) than with mean wind speeds derived from shipboard measurements corrected with an airflow distortion model. For the observed range of wind speeds (u10 N = 3-23 m s-1), the transfer velocities can be parameterised with a linear fit to u*. The SOAP data are compared to previous gas transfer parameterisations using u10 N computed from the EC friction velocity with the drag coefficient from the Coupled Ocean-Atmosphere Response Experiment (COARE) model version 3.5. The SOAP results are consistent with previous gas transfer studies, but at high wind speeds they do not support the sharp increase in gas transfer associated with bubble-mediated transfer predicted by physically based models.

  6. Atmospheric Brown Clouds in the Himalayas: first two years of continuous observations at the Nepal-Climate Observatory at Pyramid (5079 m)

    NASA Astrophysics Data System (ADS)

    Bonasoni, P.; Laj, P.; Marinoni, A.; Sprenger, M.; Angelini, F.; Arduini, J.; Bonafè, U.; Calzolari, F.; Colombo, T.; Decesari, S.; di Biagio, C.; di Sarra, A. G.; Evangelisti, F.; Duchi, R.; Facchini, M. C.; Fuzzi, S.; Gobbi, G. P.; Maione, M.; Panday, A.; Roccato, F.; Sellegri, K.; Venzac, H.; Verza, G. P.; Villani, P.; Vuillermoz, E.; Cristofanelli, P.

    2010-02-01

    South Asia is strongly influenced by the so-called Atmospheric Brown Cloud (ABC), a wide polluted layer extending from the Indian Ocean to the Himalayas during the winter and pre-monsoon seasons (November to April). This thick, grey-brown haze blanket substantially interacts with the incoming solar radiation, causing a cooling of the Earth's surface and a warming of the atmosphere, thus influencing the monsoon system and climate. In this area, the Himalayan region, particularly sensitive to climate change, offers a unique opportunity to detect global change processes and to analyse the influence of anthropogenic pollution on background atmospheric conditions through continuous monitoring activities. This paper provides a detailed description of the atmospheric conditions characterizing the high Himalayas, thanks to continuous observations begun in March 2006 at the Nepal Climate Observatory - Pyramid (NCO-P) located at 5079 m a.s.l. on the southern foothills of Mt. Everest, in the framework of ABC-UNEP and SHARE-Ev-K2-CNR projects. Besides giving an overview of the measurement site and experimental activities, the work presents an in-depth characterization of meteorological conditions and air-mass circulation at NCO-P during the first two years of activity (March 2006-February 2008). The mean values of atmospheric pressure, temperature and wind speed recorded at the site were: 551 hPa, -3.0 °C, 4.7 m s-1, respectively. The highest seasonal values of temperature (1.7 °C) and relative humidity (94%) were registered during the monsoon season, which was also characterized by thick clouds present in about 80% of the afternoon hours and by a frequency of cloud-free sky less than 10%. The lowest temperature and relative humidity values were registered during winter, -6.3 °C and 22%, respectively, the season being characterised by mainly cloud-free sky conditions and rare thick clouds. The summer monsoon influenced the rain precipitation (seasonal mean 237 mm), while

  7. Aura OMI observations of changes in SO2 and NO2 emissions at local, regional and global scales

    NASA Astrophysics Data System (ADS)

    Krotkov, N. A.; McLinden, C. A.; Li, C.; Lamsal, L. N.; Celarier, E. A.; Marchenko, S. V.; Swartz, W.; Bucsela, E. J.; Joiner, J.; Duncan, B. N.; Boersma, K. F.; Veefkind, P.; Levelt, P.; Fioletov, V.; Dickerson, R. R.; He, H.; Lu, Z.; Streets, D. G.

    2015-12-01

    Space-based pollution monitoring from current and planned satellite UV-Vis spectrometers play an increasingly important role in studies of tropospheric chemistry and also air quality applications to help mitigate anthropogenic and natural impacts on sensitive ecosystems, and human health. We present long-term changes in tropospheric SO2 and NO2 over some of the most polluted industrialized regions of the world observed by the Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite. Using OMI data, we identified about 400 SO2 "hot spots" and estimated emissions from them. In many regions emissions and their ambient pollution levels have decreased significantly, such as over eastern US, Europe and China. OMI observed about 50% reduction in SO2 and NO2 pollution over the North China plain in 2012-2014 that can be attributed to both government efforts to restrain emissions from the power and industrial sectors and the economic slowdown. While much smaller, India's SO2 and NO2 emissions from coal power plants and smelters are growing at a fast pace, increasing by about 200% and 50% from 2005 to 2014. Over Europe and the US OMI-observed trends agree well with those from available in situ measurements of surface concentrations, deposition and emissions data. However, for some regions (e.g., Mexico, Middle East) the emission inventories may be incomplete and OMI can provide emission estimates for missing sources, such as SO2 sources observed over the Persian Gulf. It is essential to continue long-term overlapping satellite data records of air quality with increased spatial and temporal resolution to resolve point pollution sources using oversampling technique. We discuss how Aura OMI pollution measurements and emission estimates will be continued with the US JPSS and European Sentinel series for the next 20 years and further enhanced by the addition of three geostationary UV-VIS instruments.

  8. Processing AIRS Scientific Data Through Level 2

    NASA Technical Reports Server (NTRS)

    Oliphant, Robert; Lee, Sung-Yung; Chahine, Moustafa; Susskind, Joel; arnet, Christopher; McMillin, Larry; Goldberg, Mitchell; Blaisdell, John; Rosenkranz, Philip; Strow, Larrabee

    2007-01-01

    The Atmospheric Infrared Spectrometer (AIRS) Science Processing System (SPS) is a collection of computer programs, denoted product generation executives (PGEs), for processing the readings of the AIRS suite of infrared and microwave instruments orbiting the Earth aboard NASA s Aqua spacecraft. AIRS SPS at an earlier stage of development was described in "Initial Processing of Infrared Spectral Data' (NPO-35243), NASA Tech Briefs, Vol. 28, No. 11 (November 2004), page 39. To recapitulate: Starting from level 0 (representing raw AIRS data), the PGEs and their data products are denoted by alphanumeric labels (1A, 1B, and 2) that signify the successive stages of processing. The cited prior article described processing through level 1B (the level-2 PGEs were not yet operational). The level-2 PGEs, which are now operational, receive packages of level-1B geolocated radiance data products and produce such geolocated geophysical atmospheric data products such as temperature and humidity profiles. The process of computing these geophysical data products is denoted "retrieval" and is quite complex. The main steps of the process are denoted microwave-only retrieval, cloud detection and cloud clearing, regression, full retrieval, and rapid transmittance algorithm.

  9. Immunocytochemical localization of metabotropic (mGluR2/3 and mGluR4a) and ionotropic (GluR2/3) glutamate receptors in adrenal medullary ganglion cells.

    PubMed

    Sarría, R; Díez, J; Losada, J; Doñate-Oliver, F; Kuhn, R; Grandes, P

    2006-02-01

    The localization of metabotropic glutamate receptors of groups II (mGluR2/3) and III (mGluR4a) and the subunits 2 and 3 of alfa-amino-3-hydroxy-5-methyl-4-isoxazolepropionic acid (AMPA) ionotropic glutamate receptors (GluR2/3) was investigated with immunocytochemical methods in the rat adrenal gland. MGluR2/3, mGluR4a and GluR2/3 immunoreactivities were observed in large-sized, centrally located type I adrenal medullary ganglion neurons. Furthermore, the small-sized type II adrenal ganglion neurons identified by their immunoreactivity to brain nitric oxide synthase (bNOS), also expressed mGluR2/3, mGluR4a and GluR2/3. These cells were disposed in the peripheral portion of the adrenal medulla. None of the type I neurons were positively labeled for bNOS. These morphological observations suggest that activation of glutamate receptors in ganglion neurons may be instrumental in the control of adrenal endocrine systems as well as blood regulation.

  10. Impacts of Energy Sector Emissions on PM2.5 Air Quality in Northern India

    NASA Astrophysics Data System (ADS)

    Karambelas, A. N.; Kiesewetter, G.; Heyes, C.; Holloway, T.

    2015-12-01

    India experiences high concentrations of fine particulate matter (PM2.5), and several Indian cities currently rank among the world's most polluted cities. With ongoing urbanization and a growing economy, emissions from different energy sectors remain major contributors to air pollution in India. Emission sectors impact ambient air quality differently due to spatial distribution (typical urban vs. typical rural sources) as well as source height characteristics (low-level vs. high stack sources). This study aims to assess the impacts of emissions from three distinct energy sectors—transportation, domestic, and electricity—on ambient PM2.5­­ in northern India using an advanced air quality analysis framework based on the U.S. EPA Community Multi-Scale Air Quality (CMAQ) model. Present air quality conditions are simulated using 2010 emissions from the Greenhouse Gas-Air Pollution Interaction and Synergies (GAINS) model. Modeled PM2.5 concentrations are compared with satellite observations of aerosol optical depth (AOD) from the Moderate Imaging Spectroradiometer (MODIS) for 2010. Energy sector emissions impacts on future (2030) PM2.5 are evaluated with three sensitivity simulations, assuming maximum feasible reduction technologies for either transportation, domestic, or electricity sectors. These simulations are compared with a business as usual 2030 simulation to assess relative sectoral impacts spatially and temporally. CMAQ is modeled at 12km by 12km and include biogenic emissions from the Community Land Model coupled with the Model of Emissions of Gases and Aerosols in Nature (CLM-MEGAN), biomass burning emissions from the Global Fires Emissions Database (GFED), and ERA-Interim meteorology generated with the Weather Research and Forecasting (WRF) model for 2010 to quantify the impact of modified anthropogenic emissions on ambient PM2.5 concentrations. Energy sector emissions analysis supports decision-making to improve future air quality and public health in

  11. M2 Internal Tides and Their Observed Wavenumber Spectra from Satellite Altimetry*

    NASA Technical Reports Server (NTRS)

    Ray, R. D.; Zaron, E. D.

    2015-01-01

    A near-global chart of surface elevations associated with the stationary M2 internal tide is empirically constructed from multi-mission satellite altimeter data. An advantage of a strictly empirical mapping approach is that results are independent of assumptions about ocean wave dynamics and, in fact, can be used to test such assumptions. A disadvantage is that present-day altimeter coverage is only marginally adequate to support mapping such short-wavelength features. Moreover, predominantly north-south ground-track orientations and contamination from nontidal oceanographic variability can lead to deficiencies in mapped tides. Independent data from Cryosphere Satellite-2 (CryoSat-2) and other altimeters are used to test the solutions and show positive reduction in variance except in regions of large mesoscale variability. The tidal fields are subjected to two-dimensional wavenumber spectral analysis, which allows for the construction of an empirical map of modal wavelengths. Mode-1 wavelengths show good agreement with theoretical wavelengths calculated from the ocean's mean stratification, with a few localized exceptions (e.g., Tasman Sea). Mode-2 waves are detectable in much of the ocean, with wavelengths in reasonable agreement with theoretical expectations, but their spectral signatures grow too weak to map in some regions.

  12. Association between PM2.5 and primary care visits due to asthma attack in Japan: relation to Beijing's air pollution episode in January 2013.

    PubMed

    Yamazaki, Shin; Shima, Masayuki; Yoda, Yoshiko; Oka, Katsumi; Kurosaka, Fumitake; Shimizu, Shigeta; Takahashi, Hironobu; Nakatani, Yuji; Nishikawa, Jittoku; Fujiwara, Katsuhiko; Mizumori, Yasuyuki; Mogami, Akira; Yamada, Taku; Yamamoto, Nobuharu

    2014-03-01

    In January 2013, extremely high concentrations of fine particles (PM2.5) were observed around Beijing, China. In Japan, the health effects of transboundary air pollution have been a matter of concern. We examined the association between the levels of outdoor PM2.5 and other air pollutants with primary care visits (PCVs) at night due to asthma attack in Himeji City, western Japan. A case-crossover study was conducted in a primary care clinic in Himeji City, Japan, involving 112 subjects aged 0-80 years who visited the clinic due to an asthma attack between 9 p.m. and 6 a.m. during the period January-March, 2013. Daily concentrations of particulate matter, ozone, nitrogen dioxide, and some meteorological elements were measured, and a conditional logistic regression model was used to estimate the odds ratios (OR) of PCVs per unit increment in air pollutants or meteorological elements. Of the 112 subjects, 76 (68 %) were aged <15 years. We did not note any association between daily PM2.5 levels and PCVs due to asthma attack at night. A positive relation between ozone and PCVs due to asthma attack was detected. The OR per 10 ppb increment in daily mean ozone the day before the visit was 2.31 (95 % confidence interval 1.16-4.61). These findings do not support an association between daily mean concentration of PM2.5 and PCVs at night. However, we did find evidence suggesting that ozone is associated with PCVs.

  13. Potential impact of a US climate policy and air quality regulations on future air quality and climate change

    NASA Astrophysics Data System (ADS)

    Lee, Y. H.; Shindell, D. T.; Faluvegi, G.; Pinder, R. W.

    2015-11-01

    We have investigated how future air quality and climate change are influenced by the US air quality regulations that existed or were proposed in 2013 and a hypothetical climate mitigation policy that reduces 2050 CO2 emissions to be 50 % below 2005 emissions. Using NASA GISS ModelE2, we look at the impacts in year 2030 and 2055. The US energy-sector emissions are from the GLIMPSE project (GEOS-Chem LIDORT Integrated with MARKAL for the Purpose of Scenario Exploration), and other US emissions and the rest of the world emissions are based on the RCP4.5 scenario. The US air quality regulations are projected to have a strong beneficial impact on US air quality and public health in the future but result in positive radiative forcing. Surface PM2.5 is reduced by ~ 2 μg m-3 on average over the US, and surface ozone by ~ 8 ppbv. The improved air quality prevents about 91 400 premature deaths in the US, mainly due to the PM2.5 reduction (~ 74 200 lives saved). The air quality regulations reduces the light-reflecting aerosols (i.e., sulfate and organic matter) more than the light-absorbing species (i.e., black carbon and ozone), leading a strong positive radiative forcing (RF) by both aerosols direct and indirect forcing: total RF is ~ 0.04 W m-2 over the globe; ~ 0.8 W m-2 over the US. Under the hypothetical climate policy, future US energy relies less on coal and thus SO2 emissions are noticeably reduced. This provides air quality co-benefits, but it leads to climate dis-benefits over the US. In 2055, the US mean total RF is +0.22 W m-2 due to positive aerosol direct and indirect forcing, while the global mean total RF is -0.06 W m-2 due to the dominant negative CO2 RF (instantaneous RF). To achieve a regional-scale climate benefit via a climate policy, it is critical (1) to have multi-national efforts to reduce GHGs emissions and (2) to target emission reduction of light-absorbing species (e.g., BC and O3) on top of long-lived species. The latter is very desirable as the

  14. CHANDRA Observations of the Corona of AU Mic (dM1e)

    NASA Astrophysics Data System (ADS)

    Linsky, J. L.; Brown, A.; Osten, R. A.

    2002-05-01

    The dM1e flare star AU Mic (HD 197481, Gl 803) is the most luminous flare star in X-rays within 10 pc of the Sun. We observed the star in November 2000 for 60 ks using Chandra's High Energy Transmission Grating Spectrometer and ACIS-S detector. Since the X-ray flux was remarkably constant during this interval with only one small flare, the results we present refer to the quiescent state of the stellar corona. We have analyzed the Chandra spectra using the approach described by Osten et al (2002) for the analysis of similar observations of the active binary σ 2 CrB. We used CIAO2.0 "threads" and custom IDL procedures applied to the reprocessed Level 2 file. For the spectral line identification and atomic parameters, we used the APEC v1.10 line list. We derive the coronal emission measure distribution and abundances from the emission lines and continuum in the Chandra data set and the emission lines observed by EUVE during similar quiescent periods. The coronal model is compared with the fluxes of Fe XXI 1354A observed by STIS and Fe XVIII 975A observed by FUSE and with the lower temperature emission measure distribution obtained by Pagano et al (2000) from quiescent STIS observations. We acknowledge support by NASA through grant H-04630D to NIST and the University of Colorado.

  15. An analysis of spatial representativeness of air temperature monitoring stations

    NASA Astrophysics Data System (ADS)

    Liu, Suhua; Su, Hongbo; Tian, Jing; Wang, Weizhen

    2018-05-01

    Surface air temperature is an essential variable for monitoring the atmosphere, and it is generally acquired at meteorological stations that can provide information about only a small area within an r m radius ( r-neighborhood) of the station, which is called the representable radius. In studies on a local scale, ground-based observations of surface air temperatures obtained from scattered stations are usually interpolated using a variety of methods without ascertaining their effectiveness. Thus, it is necessary to evaluate the spatial representativeness of ground-based observations of surface air temperature before conducting studies on a local scale. The present study used remote sensing data to estimate the spatial distribution of surface air temperature using the advection-energy balance for air temperature (ADEBAT) model. Two target stations in the study area were selected to conduct an analysis of spatial representativeness. The results showed that one station (AWS 7) had a representable radius of about 400 m with a possible error of less than 1 K, while the other station (AWS 16) had the radius of about 250 m. The representable radius was large when the heterogeneity of land cover around the station was small.

  16. Constraining the subsoil carbon source to cave-air CO2 and speleothem calcite in central Texas

    NASA Astrophysics Data System (ADS)

    Bergel, Shelly J.; Carlson, Peter E.; Larson, Toti E.; Wood, Chris T.; Johnson, Kathleen R.; Banner, Jay L.; Breecker, Daniel O.

    2017-11-01

    Canonical models for speleothem formation and the subsurface carbon cycle invoke soil respiration as the dominant carbon source. However, evidence from some karst regions suggests that belowground CO2 originates from a deeper, older source. We therefore investigated the carbon sources to central Texas caves. Drip-water chemistry of two caves in central Texas implies equilibration with calcite at CO2 concentrations (PCO2_sat) higher than the maximum CO2 concentrations observed in overlying soils. This observation suggests that CO2 is added to waters after they percolate through the soils, which requires a subsoil carbon source. We directly evaluate the carbon isotope composition of the subsoil carbon source using δ13C measurements on cave-air CO2, which we independently demonstrate has little to no contribution from host rock carbon. We do so using the oxidative ratio, OR, defined as the number of moles of O2 consumed per mole of CO2 produced during respiration. However, additional belowground processes that affect O2 and CO2 concentrations, such as gas-water exchange and/or diffusion, may also influence the measured oxidative ratio, yielding an apparent OR (ORapparent). Cave air in Natural Bridge South Cavern has ORapparent values (1.09 ± 0.06) indistinguishable from those expected for respiration alone (1.08 ± 0.06). Pore space gases from soils above the cave have lower values (ORapparent = 0.67 ± 0.05) consistent with respiration and gas transport by diffusion. The simplest explanation for these observations is that cave air in NB South is influenced by respiration in open-system bedrock fractures such that neither diffusion nor exchange with water influence the composition of the cave air. The radiocarbon activities of NB South cave-air CO2 suggest the subsoil carbon source is hundreds of years old. The calculated δ13C values of the subsoil carbon source are consistent with tree-sourced carbon (perhaps decomposing root matter), the δ13C values of which

  17. A case study of air quality above an urban roof top vegetable farm.

    PubMed

    Tong, Zheming; Whitlow, Thomas H; Landers, Andrew; Flanner, Benjamin

    2016-01-01

    The effect of elevation and rooftop configuration on local air quality was investigated at the Brooklyn Grange rooftop farm during a short-term observational campaign. Using multiple particle counters and sonic anemometers deployed along vertical gradients, we found that PM2.5 concentration decayed with height above the street. Samples adjacent to the street had the highest average PM2.5 concentration and frequent stochastic spikes above background. Rooftop observations 26 m above ground showed 7-33% reductions in average PM2.5 concentration compared with the curbside and had far fewer spikes. A relationship between the vertical extinction rate of PM2.5 and atmospheric stability was found whereby less unstable atmosphere and greater wind shear led to greater PM2.5 extinction due to damped vertical motion of air. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Air quality in Delhi during the CommonWealth Games

    NASA Astrophysics Data System (ADS)

    Marrapu, P.; Cheng, Y.; Beig, G.; Sahu, S.; Srinivas, R.; Carmichael, G. R.

    2014-04-01

    Air quality during The CommonWealth Games (CWG, held in Delhi in October 2010) is analyzed using a new air quality forecasting system established for the Games. The CWG stimulated enhanced efforts to monitor and model air quality in the region. The air quality of Delhi during the CWG had high levels of particles with mean values of PM2.5 and PM10 at the venues of 111 and 238 μg m-3, respectively. Black carbon (BC) accounted for ∼10% of the PM2.5 mass. It is shown that BC, PM2.5 and PM10 concentrations are well predicted, but with positive biases of ∼25%. The diurnal variations are also well captured, with both the observations and the modeled values showing nighttime maxima and daytime minima. A new emissions inventory, developed as part of this air quality forecasting initiative, is evaluated by comparing the observed and predicted species-species correlations (i.e., BC : CO; BC : PM2.5; PM2.5 : PM10). Assuming that the observations at these sites are representative and that all the model errors are associated with the emissions, then the modeled concentrations and slopes can be made consistent by scaling the emissions by: 0.6 for NOx, 2 for CO, and 0.7 for BC, PM2.5 and PM10. The emission estimates for particles are remarkably good considering the uncertainty in the estimates due to the diverse spread of activities and technologies that take place in Delhi and the rapid rates of change. The contribution of various emission sectors including transportation, power, domestic and industry to surface concentrations are also estimated. Transport, domestic and industrial sectors all make significant contributions to PM levels in Delhi, and the sectoral contributions vary spatially within the city. Ozone levels in Delhi are elevated, with hourly values sometimes exceeding 100 ppb. The continued growth of the transport sector is expected to make ozone pollution a more pressing air pollution problem in Delhi. The sector analysis provides useful inputs into the

  19. Sulfate and nitrate in Asian dust particles observed in desert, coastal and marine air

    NASA Astrophysics Data System (ADS)

    Zhang, D.; Wu, F.; Junji, C.

    2016-12-01

    Sulfate and nitrate in dust particles are believed to be two key species which can largely alter the physical and chemical properties of the particles in the atmosphere, in particular under humid conditions. Their occurrence in the particles has usually been considered to be the consequence of particles' aging during their long-distance travel in the air although they are present in some crustal minerals. Our observations at two deserts in China during dust episodes revealed that there were soil-derived sulfate and background-like nitrate in atmospheric dust samples. Sulfate in dust samples was proportional to samples' mass and comprised at steady mass percentages in differently sized samples. In contrast, nitrate concentration was approximately stable and independent from dust loading. Our observations at inland and coastal areas of China during dust episodes revealed that sulfate and nitrate were hardly produced on the surface of dust particles that were originated from the deserts areas in northwestern China. This is because the dust particles were in the postfrontal air, where the temperature was low and the relative humidity was small due to the adiabatic properties of the air mass. There are a number studies reporting that sulfate and nitrate had been efficiently produced on mineral particles in inland areas of China. However, those mineral particles were more likely from the local areas rather than from the desert areas. Our observations in the coastal areas of Japan, which is located in the downstream areas of the Asian continent and surrounded by sea areas revealed that dust particles appearing there frequently contained sulfate and nitrate, indicating sulfate and nitrate had been efficiently produced on the surface of the particles when the particles traveled in the marine air between China and Japan.

  20. Air Pollution and Glucose Metabolism: An Analysis in Non-Diabetic Participants of the Heinz Nixdorf Recall Study.

    PubMed

    Lucht, Sarah A; Hennig, Frauke; Matthiessen, Clara; Ohlwein, Simone; Icks, Andrea; Moebus, Susanne; Jöckel, Karl-Heinz; Jakobs, Hermann; Hoffmann, Barbara

    2018-04-03

    Despite the importance of understanding the connection between air pollution exposure and diabetes, studies investigating links between air pollution and glucose metabolism in nondiabetic adults are limited. We aimed to estimate the association of medium-term air pollution exposures with blood glucose and glycated hemoglobin A1c (HbA1c) among nondiabetics. This study included observations from nondiabetic participants (n obs =7,108) of the population-based Heinz Nixdorf Recall study at baseline (2000–2003) and follow-up examination (2006–2008). Daily fine particulate matter (aerodynamic diameter≤2.5 μm, PM 2.5 ; aerodynamic diameter≤10 μm, PM 10 ), accumulation mode particle number (PN AM ), and nitrogen dioxide (NO 2 ) exposures were estimated at participants’ residences using the spatiotemporal European Air Pollution Dispersion (EURAD) chemistry transport model. We evaluated the associations between medium-term air pollution exposures (28- and 91-d means) and glucose metabolism measures using mixed linear regression and adjusting for season, meteorology, and personal characteristics. A range of other exposure windows (1-, 2-, 3-, 7-, 14-, 45-, 60-, 75-, 105-, 120-, and 182-d means) were also evaluated to identify potentially relevant biological windows. We observed positive associations between PM 2.5 and PN AM exposures and blood glucose levels [e.g., 28-d PM 2.5 : 0.91 mg/dL (95% CI: 0.38, 1.44) per 5.7 μg/m 3 ]. PM 2.5 , PM 10 , and PN AM exposures were positively associated with HbA1c [e.g., 91-d PM 2.5 : 0.07 p.p. (95% CI: 0.04, 0.10) per 4.0 μg/m 3 ]. Mean exposures during longer exposure windows (75- to 105-d) were most strongly associated with HbA1c, whereas 7- to 45-d exposures were most strongly associated with blood glucose. NO 2 exposure was not associated with blood glucose or with HbA1c. Medium-term PM and PN AM exposures were positively associated with glucose measures in nondiabetic adults. These findings indicate

  1. HAT-TR-318-007: A Double-lined M Dwarf Binary with Total Secondary Eclipses Discovered by HATNet and Observed by K2

    NASA Astrophysics Data System (ADS)

    Hartman, J. D.; Quinn, S. N.; Bakos, G. Á.; Torres, G.; Kovács, G.; Latham, D. W.; Noyes, R. W.; Shporer, A.; Fulton, B. J.; Esquerdo, G. A.; Everett, M. E.; Penev, K.; Bhatti, W.; Csubry, Z.

    2018-03-01

    We report the discovery by the HATNet survey of HAT-TR-318-007, a P=3.34395390+/- 0.00000020 day period detached double-lined M dwarf binary with total secondary eclipses. We combine radial velocity (RV) measurements from TRES/FLWO 1.5 m and time-series photometry from HATNet, FLWO 1.2 m, BOS 0.8 m, and NASA K2 Campaign 5, to determine the masses and radii of the component stars: MA=0.448+/-0.011 M⊙N, MB=0.2721-0.0042+0.0041 M⊙N, RA=0.4548-0.0036+0.0035 R⊙N, and RB=0.2913-0.0024+0.0023 R⊙N. We obtained a FIRE/Magellan near-infrared spectrum of the primary star during a total secondary eclipse, and we use this to obtain disentangled spectra of both components. We determine spectral types of STA=M 3.71+/- 0.69 and STB=M 5.01+/- 0.73 and effective temperatures of Teff, A= 3190+/-110 K and Teff, B=3100+/- 110 K for the primary and secondary star, respectively. We also measure a metallicity of [Fe/H] = +0.298+/- 0.080 for the system. We find that the system has a small, but significant, nonzero eccentricity of 0.0136+/- 0.0026. The K2 light curve shows a coherent variation at a period of 3.41315-0.00032+0.00030 days, which is slightly longer than the orbital period, and which we demonstrate comes from the primary star. We interpret this as the rotation period of the primary. We perform a quantitative comparison between the Dartmouth stellar evolution models and the seven systems, including HAT-TR-318-007, that contain M dwarfs with 0.2 M⊙N< M< 0.5 M⊙N, have metallicity measurements, and have masses and radii determined to better than 5% precision. Discrepancies between the predicted and observed masses and radii are found for three of the systems.

  2. [Verification of bacteriological safety of PCM 40 air conditioner].

    PubMed

    Dumas, J L; Ducel, G; Rouge, J C

    1991-01-01

    This study assessed the bacteriological safety of the bedside air conditioner PCM 40 (Howorth Airtech), used for prevention of intraoperative hypothermia, by blowing filtered warm air through a special mattress. The 3 microns bacterial filter of the device released 2,968 +/- 5,618 particles of diameter less than 3 microns per m3 of room air, containing 78,798 +/- 37,243 of such particles per m3. The amount of bacteries in the air pulsed from the mattress was 30 +/- 41 cfu/m3 vs 120 cfu/m3 in the ambient air and in the hot air supply tubing it reached 6 +/- 5 cfu/m3 vs 175 +/- 77 cfu/m3. It is concluded that bacteriological data do not contra-indicate the use of this air conditioner in the operating theater. The only limitations for use are the position (prone or lateral position) and type of surgery (neurosurgery).

  3. Stack air-breathing membraneless glucose microfluidic biofuel cell

    NASA Astrophysics Data System (ADS)

    Galindo-de-la-Rosa, J.; Moreno-Zuria, A.; Vallejo-Becerra, V.; Arjona, N.; Guerra-Balcázar, M.; Ledesma-García, J.; Arriaga, L. G.

    2016-11-01

    A novel stacked microfluidic fuel cell design comprising re-utilization of the anodic and cathodic solutions on the secondary cell is presented. This membraneless microfluidic fuel cell employs porous flow-through electrodes in a “V”-shape cell architecture. Enzymatic bioanodic arrays based on glucose oxidase were prepared by immobilizing the enzyme onto Toray carbon paper electrodes using tetrabutylammonium bromide, Nafion and glutaraldehyde. These electrodes were characterized through the scanning electrochemical microscope technique, evidencing a good electrochemical response due to the electronic transference observed with the presence of glucose over the entire of the electrode. Moreover, the evaluation of this microfluidic fuel cell with an air-breathing system in a double-cell mode showed a performance of 0.8951 mWcm-2 in a series connection (2.2822mAcm-2, 1.3607V), and 0.8427 mWcm-2 in a parallel connection (3.5786mAcm-2, 0.8164V).

  4. Poly(ethylenimine)-Functionalized Monolithic Alumina Honeycomb Adsorbents for CO2 Capture from Air.

    PubMed

    Sakwa-Novak, Miles A; Yoo, Chun-Jae; Tan, Shuai; Rashidi, Fereshteh; Jones, Christopher W

    2016-07-21

    The development of practical and effective gas-solid contactors is an important area in the development of CO2 capture technologies. Target CO2 capture applications, such as postcombustion carbon capture and sequestration (CCS) from power plant flue gases or CO2 extraction directly from ambient air (DAC), require high flow rates of gas to be processed at low cost. Extruded monolithic honeycomb structures, such as those employed in the catalytic converters of automobiles, have excellent potential as structured contactors for CO2 adsorption applications because of the low pressure drop imposed on fluid moving through the straight channels of such structures. Here, we report the impregnation of poly(ethylenimine) (PEI), an effective aminopolymer reported commonly for CO2 separation, into extruded monolithic alumina to form structured CO2 sorbents. These structured sorbents are first prepared on a small scale, characterized thoroughly, and compared with powder sorbents with a similar composition. Despite consistent differences observed in the filling of mesopores with PEI between the monolithic and powder sorbents, their performance in CO2 adsorption is similar across a range of PEI contents. A larger monolithic cylinder (1 inch diameter, 4 inch length) is evaluated under conditions closer to those that might be used in large-scale applications and shows a similar performance to the smaller monoliths and powders tested initially. This larger structure is evaluated over five cycles of CO2 adsorption and steam desorption and demonstrates a volumetric capacity of 350 molCO2m-3monolith and an equilibration time of 350 min under a 0.4 m s(-1) linear flow velocity through the monolith channels using 400 ppm CO2 in N2 as the adsorption gas at 30 °C. This volumetric capacity surpasses that of a similar technology considered previously, which suggested that CO2 could be removed from air at an operating cost as low as $100 per ton. © 2016 WILEY-VCH Verlag

  5. The influence of synoptic weather regimes on UK air quality: regional model studies of tropospheric column NO2

    NASA Astrophysics Data System (ADS)

    Pope, R. J.; Savage, N. H.; Chipperfield, M. P.; Ordóñez, C.; Neal, L. S.

    2015-07-01

    Synoptic meteorology can have a significant influence on UK air quality. Cyclonic (anticyclonic) conditions lead to the dispersion (accumulation) of air pollutants away from (over) source regions. Meteorology also modifies atmospheric chemistry processes such as photolysis and wet deposition. Previous studies have shown a relationship between observed satellite tropospheric column NO2 and synoptic meteorology in different seasons. Here, we test whether the UK Met Office Air Quality in the Unified Model (AQUM) can reproduce these observations and then use the model to determine the controlling factors. We show that AQUM successfully captures the observed relationships, when sampled under the Lamb Weather Types, an objective classification of midday UK circulation patterns. By using a range of idealised NOx-like tracers with different e-folding lifetimes, we show that under different synoptic regimes the NO2 lifetime in AQUM is approximately 6 h in summer and 12 h in winter. The longer lifetime can explain why synoptic spatial column NO2 variations are more significant in winter compared to summer, due to less NO2 photochemical loss. We also show that cyclonic conditions have more seasonality in column NO2 than anticyclonic conditions as they result in more extreme spatial departures from the wintertime seasonal average. Within a season (summer or winter) under different synoptic regimes, a large proportion of the spatial pattern in the UK column NO2 field can be explained by the idealised model tracers, showing that transport is an important factor in governing the variability of UK air quality on seasonal synoptic timescales.

  6. Ambient air quality status in Raniganj-Asansol area, India.

    PubMed

    Reddy, G S; Ruj, Biswajit

    2003-12-01

    This investigation presents the assessment of ambient air quality with respect to suspended particulate matter (SPM), sulphur dioxide (SO2) and oxides of nitrogen (NOx) at four sites (RGC, SRS, BBC and BCC) in the Raniganj-Asansol area in West Bengal, India. Ambient air was monitored with a sampling frequency of twenty four hours (3 x 8 hours) at each site on every alternate day (3 days a week) covering a period of one year. A total of 429 samples were collected from RGC, 429 from SRS and 435 each from the BBC and BCC sites. Meteorological parameters such as temperature, relative humidity, wind-speed and wind-direction were also recorded simultaneously during the sampling period. Monthly and seasonal variation of these pollutants have been observed and recorded. The annual average and range values have also been calculated. Results of the investigation indicates that the 95th percentile values of SPM levels exceed the limits (200 microg m(-3)) at RGC, SRS and BBC sites and is within the limit of 500 microg m(-3) at the BCC sites. The 95th percentile values of SO2 levels did not exceed the reference level at any of the monitoring stations. The 95th percentile values of NOx are found to be exceeding the limit (80 microg m(-3)) at RGC, SRS and BBC sites but is within the prescribed limit of 120 microg m(-3) at the BCC site. Further, it has been observed that the concentrations of the pollutants are high in winter in comparison to the summer or the monsoon seasons. Results of the investigation indicates that industrial activities, indiscriminate open air burning of coal by the local inhabitants for cooking as well as coking purposes, vehicular traffic, etc. are responsible for the high concentration of pollutants in this area.

  7. Hurricane Isabel, Amount of Atmospheric Water Vapor Observed By AIRS

    NASA Image and Video Library

    2003-09-20

    This false-color image shows the amount of atmospheric water vapor observed by AIRS two weeks prior to the passage of Hurricane Isabel, and then when it was a Category 5 storm. The region shown includes parts of South America and the West Indies. Puerto Rico is the large island below the upper left corner. Total water vapor represents the depth of a layer if all the water vapor in the atmosphere were to condense and fall to the surface. The color bar on the right sides of the plots give the thickness of this layer in millimeters (mm). The first image, from August 28, shows typical tropical water vapor amounts over the ocean: between roughly 25 and 50 mm, or 1 to 2 inches. The highest values of roughly 80 mm, seen as a red blob over South America, corresponds to intense thunderstorms. Thunderstorms pull in water vapor from surrounding regions and concentrate it, with much of it then falling as rain. http://photojournal.jpl.nasa.gov/catalog/PIA00430

  8. WRF modeling of PM2.5 remediation by SALSCS and its clean air flow over Beijing terrain.

    PubMed

    Cao, Qingfeng; Shen, Lian; Chen, Sheng-Chieh; Pui, David Y H

    2018-06-01

    Atmospheric simulations were carried out over the terrain of entire Beijing, China, to investigate the effectiveness of an air-pollution cleaning system named Solar-Assisted Large-Scale Cleaning System (SALSCS) for PM 2.5 mitigation by using the Weather Research and Forecasting (WRF) model. SALSCS was proposed to utilize solar energy to generate airflow therefrom the airborne particulate pollution of atmosphere was separated by filtration elements. Our model used a derived tendency term in the potential temperature equation to simulate the buoyancy effect of SALSCS created with solar radiation on its nearby atmosphere. PM 2.5 pollutant and SALSCS clean air were simulated in the model domain by passive tracer scalars. Simulation conditions with two system flow rates of 2.64 × 10 5  m 3 /s and 3.80 × 10 5  m 3 /s were tested for seven air pollution episodes of Beijing during the winters of 2015-2017. The numerical results showed that with eight SALSCSs installed along the 6 th Ring Road of the city, 11.2% and 14.6% of PM 2.5 concentrations were reduced under the two flow-rate simulation conditions, respectively. Copyright © 2018 Elsevier B.V. All rights reserved.

  9. Difficult colonoscopy: air, carbon dioxide, or water insufflation?

    PubMed

    Chaubal, Alisha; Pandey, Vikas; Patel, Ruchir; Poddar, Prateik; Phadke, Aniruddha; Ingle, Meghraj; Sawant, Prabha

    2018-04-01

    This study aimed to compare tolerance to air, carbon dioxide, or water insufflation in patients with anticipated difficult colonoscopy (young, thin, obese individuals, and patients with prior abdominal surgery or irradiation). Patients with body mass index (BMI) less than 18 kg/m 2 or more than 30 kg/m 2 , or who had undergone previous abdominal or pelvic surgeries were randomized to air, carbon dioxide, or water insufflation during colonoscopy. The primary endpoint was cecal intubation with mild pain (less than 5 on visual analogue scale [VAS]), without use of sedation. The primary end point was achieved in 32.7%, 43.8%, and 84.9% of cases with air, carbon dioxide and water insufflation ( P <0.001). The mean pain scores were 5.17, 4.72, and 3.93 on the VAS for air, carbon dioxide, and water insufflation ( P <0.001). The cecal intubation rate or procedure time did not differ significantly between the 3 groups. Water insufflation was superior to air or carbon dioxide for pain tolerance. This was seen in the subgroups with BMI <18 kg/m 2 and the post-surgical group, but not in the group with BMI >30 kg/m 2 .

  10. Air Quality Over the Canadian Oil Sands: A First Assessment Using Satellite Observations

    NASA Technical Reports Server (NTRS)

    McLinden, C. A.; Fioletov, V.; Boersma, K. F.; Krotkov, N.; Sioris, C. E.; Veefkind, J. P.; Yang, K.

    2012-01-01

    Results from the first assessment of air quality over the Canadian oil sands -- one ofthe largest industrial undertakings in human history -- using satellite remote sensing observations of two pollutants, nitrogen dioxide (N0O) and sulfur dioxide (SO2), are presented. High-resolution maps were created that revealed distinct enhancements in both species over an area (roughly 30 km x 50 km) of intensive surface mining at scales of a few kilometers. The magnitude of these enhancements, quantified in terms of total mass, are comparable to the largest seen in Canada from individual sources. The rate of increase in NO2 between 2005 and 2010 was assessed at 10.4 +/- 3.5%/year and resulted from increases both in local values as well as the spatial extent of the enhancement. This is broadly consistent with both surface-measurement trends and increases in annual bitumen production. An increase in SO2 was also found, but given larger uncertainties, it is not statistically significant.

  11. Observations of ozone-poor air in the tropical tropopause layer

    NASA Astrophysics Data System (ADS)

    Newton, Richard; Vaughan, Geraint; Hintsa, Eric; Filus, Michal T.; Pan, Laura L.; Honomichl, Shawn; Atlas, Elliot; Andrews, Stephen J.; Carpenter, Lucy J.

    2018-04-01

    Ozonesondes reaching the tropical tropopause layer (TTL) over the west Pacific have occasionally measured layers of very low ozone concentrations - less than 15 ppbv - raising the question of how prevalent such layers are and how they are formed. In this paper, we examine aircraft measurements from the Airborne Tropical Tropopause Experiment (ATTREX), the Coordinated Airborne Studies in the Tropics (CAST) and the Convective Transport of Active Species in the Tropics (CONTRAST) experiment campaigns based in Guam in January-March 2014 for evidence of very low ozone concentrations and their relation to deep convection. The study builds on results from the ozonesonde campaign conducted from Manus Island, Papua New Guinea, as part of CAST, where ozone concentrations as low as 12 ppbv were observed between 100 and 150 hPa downwind of a deep convective complex. TTL measurements from the Global Hawk unmanned aircraft show a marked contrast between the hemispheres, with mean ozone concentrations in profiles in the Southern Hemisphere between 100 and 150 hPa of between 10.7 and 15.2 ppbv. By contrast, the mean ozone concentrations in profiles in the Northern Hemisphere were always above 15.4 ppbv and normally above 20 ppbv at these altitudes. The CAST and CONTRAST aircraft sampled the atmosphere between the surface and 120 hPa, finding very low ozone concentrations only between the surface and 700 hPa; mixing ratios as low as 7 ppbv were regularly measured in the boundary layer, whereas in the free troposphere above 200 hPa concentrations were generally well in excess of 15 ppbv. These results are consistent with uplift of almost-unmixed boundary-layer air to the TTL in deep convection. An interhemispheric difference was found in the TTL ozone concentrations, with values < 15 ppbv measured extensively in the Southern Hemisphere but seldom in the Northern Hemisphere. This is consistent with a similar contrast in the low-level ozone between the two hemispheres found by

  12. Near-road air pollutant concentrations of CO and PM 2.5: A comparison of MOBILE6.2/CALINE4 and generalized additive models

    NASA Astrophysics Data System (ADS)

    Zhang, Kai; Batterman, Stuart

    2010-05-01

    The contribution of vehicular traffic to air pollutant concentrations is often difficult to establish. This paper utilizes both time-series and simulation models to estimate vehicle contributions to pollutant levels near roadways. The time-series model used generalized additive models (GAMs) and fitted pollutant observations to traffic counts and meteorological variables. A one year period (2004) was analyzed on a seasonal basis using hourly measurements of carbon monoxide (CO) and particulate matter less than 2.5 μm in diameter (PM 2.5) monitored near a major highway in Detroit, Michigan, along with hourly traffic counts and local meteorological data. Traffic counts showed statistically significant and approximately linear relationships with CO concentrations in fall, and piecewise linear relationships in spring, summer and winter. The same period was simulated using emission and dispersion models (Motor Vehicle Emissions Factor Model/MOBILE6.2; California Line Source Dispersion Model/CALINE4). CO emissions derived from the GAM were similar, on average, to those estimated by MOBILE6.2. The same analyses for PM 2.5 showed that GAM emission estimates were much higher (by 4-5 times) than the dispersion model results, and that the traffic-PM 2.5 relationship varied seasonally. This analysis suggests that the simulation model performed reasonably well for CO, but it significantly underestimated PM 2.5 concentrations, a likely result of underestimating PM 2.5 emission factors. Comparisons between statistical and simulation models can help identify model deficiencies and improve estimates of vehicle emissions and near-road air quality.

  13. Interaction between Air Bubbles and Superhydrophobic Surfaces in Aqueous Solutions.

    PubMed

    Shi, Chen; Cui, Xin; Zhang, Xurui; Tchoukov, Plamen; Liu, Qingxia; Encinas, Noemi; Paven, Maxime; Geyer, Florian; Vollmer, Doris; Xu, Zhenghe; Butt, Hans-Jürgen; Zeng, Hongbo

    2015-07-07

    Superhydrophobic surfaces are usually characterized by a high apparent contact angle of water drops in air. Here we analyze the inverse situation: Rather than focusing on water repellency in air, we measure the attractive interaction of air bubbles and superhydrophobic surfaces in water. Forces were measured between microbubbles with radii R of 40-90 μm attached to an atomic force microscope cantilever and submerged superhydrophobic surfaces. In addition, forces between macroscopic bubbles (R = 1.2 mm) at the end of capillaries and superhydrophobic surfaces were measured. As superhydrophobic surfaces we applied soot-templated surfaces, nanofilament surfaces, micropillar arrays with flat top faces, and decorated micropillars. Depending on the specific structure of the superhydrophobic surfaces and the presence and amount of entrapped air, different interactions were observed. Soot-templated surfaces in the Cassie state showed superaerophilic behavior: Once the electrostatic double-layer force and a hydrodynamic repulsion were overcome, bubbles jumped onto the surface and fully merged with the entrapped air. On nanofilaments and micropillar arrays we observed in addition the formation of sessile bubbles with finite contact angles below 90° or the attachment of bubbles, which retained their spherical shape.

  14. Surface-catalyzed air oxidation of hydrazines: Environmental chamber studies

    NASA Technical Reports Server (NTRS)

    Kilduff, Jan E.; Davis, Dennis D.; Koontz, Steven L.

    1988-01-01

    The surface-catalyzed air oxidation reactions of fuel hydrazines were studied in a 6500-liter fluorocarbon-film chamber at 80 to 100 ppm concentrations. First-order rate constants for the reactions catalyzed by aluminum, water-damaged aluminum (Al/Al2O3), stainless steel 304L, galvanized steel and titanium plates with surface areas of 2 to 24 sq m were determined. With 23.8 sq m of Al/Al2O3 the surface-catalyzed air oxidation of hydrazine had a half-life of 2 hours, diimide (N2H2) was observed as an intermediate and traces of ammonia were present in the final product mixture. The Al/Al2O3 catalyzed oxidation of monomethylhydrazine yielded methyldiazine (HN = NCH3) as an intermediate and traces of methanol. Unsymmetrical dimethylhydrazine gave no detectable products. The relative reactivities of hydrazine, MMH and UDMH were 130 : 7.3 : 1.0, respectively. The rate constants for Al/Al2O3-catalyzed oxidation of hydrazine and MMH were proportional to the square of the surface area of the plates. Mechanisms for the surface-catalyzed oxidation of hydrazine and diimide and the formation of ammonia are proposed.

  15. The impact of European measures to reduce air pollutants on air quality, human health and climate

    NASA Astrophysics Data System (ADS)

    Turnock, S.; Butt, E. W.; Richardson, T.; Mann, G.; Forster, P.; Haywood, J. M.; Crippa, M.; Janssens-Maenhout, G. G. A.; Johnson, C.; Bellouin, N.; Spracklen, D. V.; Carslaw, K. S.; Reddington, C.

    2015-12-01

    European air quality legislation has reduced emissions of air pollutants across Europe since the 1970s, resulting in improved air quality and benefits to human health but also an unintended impact on regional climate. Here we used a coupled chemistry-climate model and a new policy relevant emission scenario to determine the impact of air pollutant emission reductions over Europe. The emission scenario shows that a combination of technological improvements and end-of-pipe abatement measures in the energy, industrial and road transport sectors reduced European emissions of sulphur dioxide, black carbon and organic carbon by 53%, 59% and 32% respectively. We estimate that these emission reductions decreased European annual mean concentrations of fine particulate matter (PM2.5) by 35%, sulphate by 44%, black carbon (BC) by 56% and particulate organic matter (POM) by 23%. The reduction in PM2.5 concentrations is calculated to have prevented 107,000 (40,000-172,000, 5-95% confidence intervals) premature deaths annually from cardiopulmonary disease and lung cancer across the EU member states. The decrease in aerosol concentrations caused a positive all-sky aerosol radiative forcing at the top of atmosphere over Europe of 2.3±0.06 W m-2 and a positive clear-sky forcing of 1.7±0.05 W m-2. Additionally, the amount of solar radiation incident at the surface over Europe increased by 3.3±0.07 W m-2 under all-sky and by 2.7±0.05 W m-2 under clear-sky conditions. Reductions in BC concentrations caused a 1 Wm-2 reduction in atmospheric absorption. We use an energy budget approximation to show that the aerosol induced radiative changes caused both temperature and precipitation to increase globally and over Europe. Our results show that the implementation of European legislation to reduce the emission of air pollutants has improved air quality and human health over Europe, as well as altered the regional radiative balance and climate.

  16. Ceilometer observations of aerosol layer structure above the Petit Lubéron during ESCOMPTE's IOP 2

    NASA Astrophysics Data System (ADS)

    Zéphoris, Marcel; Holin, Hubert; Lavie, Franck; Cenac, Nadine; Cluzeau, Michel; Delas, Olivier; Eideliman, Françoise; Gagneux, Jacqueline; Gander, Alain; Thibord, Corinne

    2005-03-01

    A modified ceilometer has been used during the second Intensive Observation Period (IOP) of the "Expérience sur Site pour COntraindre les Modèles de Pollution atmosphériques et de Transport d'Émission" (ESCOMPTE) to perform continuous remote observations of aerosol accumulations in the first 3 km of the atmosphere. These observations encompassed an episode of intense particulate and photochemical pollution. The submicronic particles density, measured at an altitude of 600 m, went from a very low point of a few tens of particles per cubic centimeter (at the end of a Mistral episode in the free atmosphere) to a high point of more than 4500 particles per cubic centimeter (when pollutants were trapped by thermal inversions). The main result is that this instrument enables a fine documentation of the mixing layer height and of aerosol particles stratifications and circulation. Airborne aerosol measurements have been made above the mountainous region of Mérindol in order to validate in situ the remote sensing measurements. Ozone measurements near the summit of the mountains as well as in the valley were performed in order to correlate aerosol accumulation and ozone concentration. As a notable example, the two-layer aerosol stratification seen in the first 2 days of IOP 2b in that part of the ESCOMPTE domain confirms the results of another team which used backtrajectories. The low-altitude pollution for this timeframe had a local origin (the Fos industrial area), whereas above 500 m, the air masses had undergone regional-scale transport (from north-eastern Spain). The second major result is the highlighting of a pattern, in sea breeze conditions and in this part of the ESCOMPTE experiment zone, of nocturnal aerosol accumulation at an altitude of between 500 and 2000 m, followed by high ozone concentration the next day.

  17. A Unified Spatiotemporal Modeling Approach for Predicting Concentrations of Multiple Air Pollutants in the Multi-Ethnic Study of Atherosclerosis and Air Pollution

    PubMed Central

    Olives, Casey; Kim, Sun-Young; Sheppard, Lianne; Sampson, Paul D.; Szpiro, Adam A.; Oron, Assaf P.; Lindström, Johan; Vedal, Sverre; Kaufman, Joel D.

    2014-01-01

    Background: Cohort studies of the relationship between air pollution exposure and chronic health effects require predictions of exposure over long periods of time. Objectives: We developed a unified modeling approach for predicting fine particulate matter, nitrogen dioxide, oxides of nitrogen, and black carbon (as measured by light absorption coefficient) in six U.S. metropolitan regions from 1999 through early 2012 as part of the Multi-Ethnic Study of Atherosclerosis and Air Pollution (MESA Air). Methods: We obtained monitoring data from regulatory networks and supplemented those data with study-specific measurements collected from MESA Air community locations and participants’ homes. In each region, we applied a spatiotemporal model that included a long-term spatial mean, time trends with spatially varying coefficients, and a spatiotemporal residual. The mean structure was derived from a large set of geographic covariates that was reduced using partial least-squares regression. We estimated time trends from observed time series and used spatial smoothing methods to borrow strength between observations. Results: Prediction accuracy was high for most models, with cross-validation R2 (R2CV) > 0.80 at regulatory and fixed sites for most regions and pollutants. At home sites, overall R2CV ranged from 0.45 to 0.92, and temporally adjusted R2CV ranged from 0.23 to 0.92. Conclusions: This novel spatiotemporal modeling approach provides accurate fine-scale predictions in multiple regions for four pollutants. We have generated participant-specific predictions for MESA Air to investigate health effects of long-term air pollution exposures. These successes highlight modeling advances that can be adopted more widely in modern cohort studies. Citation: Keller JP, Olives C, Kim SY, Sheppard L, Sampson PD, Szpiro AA, Oron AP, Lindström J, Vedal S, Kaufman JD. 2015. A unified spatiotemporal modeling approach for predicting concentrations of multiple air pollutants in the Multi

  18. Observational Needs for Four-Dimensional Air Quality Characterization

    EPA Science Inventory

    Surface-based monitoring programs provide the foundation for associating air pollution and causal effects in human health studies, and they support the development of air quality standards and the preparation of emission reduction strategies. While surface oriented networks remai...

  19. First Observations of SO2 from the Satellite Suomi NPP OMPS: Widespread Air Pollution Events Over China

    NASA Technical Reports Server (NTRS)

    Yang, Kai; Dickerson, Russell R.; Carn, Simon A.; Ge, Cui; Wang, Jun

    2013-01-01

    Severe smog episodes over China in January 2013 received worldwide attention. This air pollution was distinguished by heavy loadings of fine particulate matter and SO2. To characterize these episodes, we employed the Ozone Mapping and Profiler Suite, Nadir Mapper (OMPS NM), an ultraviolet (UV) spectrometer flying on the Suomi National Polar-orbiting Partnership (SNPP) spacecraft since October 2011. We developed an advanced algorithm to quantify SO2 in the lower troposphere and achieved high-quality retrievals from OMPS NM, which are characterized by high precision, approx. 0.2 Dobson Units (DU; 1 DU = 2.69 x 10(exp 16) molecules/sq cm) for instantaneous field of view SO2 data and low biases (within +/-0.2 DU). Here we report SO2 retrievals and UV aerosol index data for these pollution events. The SO2 columns and the areas covered by high pollutant concentrations are quantified; the results reveal for the first time the full extent (an area of approx. 10(exp 6) sq km containing up to 60 kt of SO2) of these episodes.

  20. Hierarchically Designed 3D Holey C2N Aerogels as Bifunctional Oxygen Electrodes for Flexible and Rechargeable Zn-Air Batteries.

    PubMed

    Shinde, Sambhaji S; Lee, Chi Ho; Yu, Jin-Young; Kim, Dong-Hyung; Lee, Sang Uck; Lee, Jung-Ho

    2018-01-23

    The future of electrochemical energy storage spotlights on the designed formation of highly efficient and robust bifunctional oxygen electrocatalysts that facilitate advanced rechargeable metal-air batteries. We introduce a scalable facile strategy for the construction of a hierarchical three-dimensional sulfur-modulated holey C 2 N aerogels (S-C 2 NA) as bifunctional catalysts for Zn-air and Li-O 2 batteries. The S-C 2 NA exhibited ultrahigh surface area (∼1943 m 2 g -1 ) and superb electrocatalytic activities with lowest reversible oxygen electrode index ∼0.65 V, outperforms the highly active bifunctional and commercial (Pt/C and RuO 2 ) catalysts. Density functional theory and experimental results reveal that the favorable electronic structure and atomic coordination of holey C-N skeleton enable the reversible oxygen reactions. The resulting Zn-air batteries with liquid electrolytes and the solid-state batteries with S-C 2 NA air cathodes exhibit superb energy densities (958 and 862 Wh kg -1 ), low charge-discharge polarizations, excellent reversibility, and ultralong cycling lives (750 and 460 h) than the commercial Pt/C+RuO 2 catalysts, respectively. Notably, Li-O 2 batteries with S-C 2 NA demonstrated an outstanding specific capacity of ∼648.7 mA h g -1 and reversible charge-discharge potentials over 200 cycles, illustrating great potential for commercial next-generation rechargeable power sources of flexible electronics.