Sample records for observed frequency spectra

  1. Observations of explosion generated PcP spectra at near-normal incidence

    NASA Astrophysics Data System (ADS)

    Niazi, Mansour; McLaughlin, Keith L.

    1987-10-01

    Short period recordings of PcP at the SRO station ANTO have been observed at epicentral distance of 13.5° from presumed underground explosions in western Kazahk, USSR. The core reflections are narrow band (0.6 to 2.4 Hz), short duration (3 sec) signals. Comparison of these near normally incident reflections to P waveforms observed at greater distances reveals that the PcP spectra are peaked with respect to the more representative P-wave spectra. The 1.2 Hz spectral peak is also observed for PcP waves recorded at 50 degrees. Corrections for frequency independent mantle Q attnuation models only increase the high frequency deficiency of the PcP spectra at frequencies above 1.2 Hz. A plausible explanation calls for finer structural features of core-mantle boundary (CMB) than hitherto suggested. The influence of small scale lateral heterogeneities, however, cannot be completely ruled out. (Mantle-core boundary, near normal PcP reflection.)

  2. Generalized Doppler and aberration kernel for frequency-dependent cosmological observables

    NASA Astrophysics Data System (ADS)

    Yasini, Siavash; Pierpaoli, Elena

    2017-11-01

    We introduce a frequency-dependent Doppler and aberration transformation kernel for the harmonic multipoles of a general cosmological observable with spin weight s , Doppler weight d and arbitrary frequency spectrum. In the context of cosmic microwave background (CMB) studies, the frequency-dependent formalism allows to correct for the motion-induced aberration and Doppler effects on individual frequency maps with different masks. It also permits to deboost background radiations with non-blackbody frequency spectra, like extragalactic foregrounds and CMB spectra with primordial spectral distortions. The formalism can also be used to correct individual E and B polarization modes and account for motion-induced E/B mixing of polarized observables with d ≠1 at different frequencies. We apply the generalized aberration kernel on polarized and unpolarized specific intensity at 100 and 217 GHz and show that the motion-induced effects typically increase with the frequency of observation. In all-sky CMB experiments, the frequency-dependence of the motion-induced effects for a blackbody spectrum are overall negligible. However in a cut-sky analysis, ignoring the frequency dependence can lead to percent level error in the polarized and unpolarized power spectra over all angular scales. In the specific cut-sky used in our analysis (b >4 5 ° ,fsky≃14 % ), and for the dipole-inferred velocity β =0.00123 typically attributed to our peculiar motion, the Doppler and aberration effects can change polarized and unpolarized power spectra of specific intensity in the CMB rest frame by 1 - 2 % , but we find the polarization cross-leakage between E and B modes to be negligible.

  3. Doppler-shifting effects on frequency spectra of gravity waves observed near the summer mesopause at high latitude

    NASA Technical Reports Server (NTRS)

    Fritts, David C.; Wang, Ding-Yi

    1991-01-01

    Results are presented of radar observations of horizontal and vertical velocities near the summer mesopause at Poker Flat (Alaska), showing that the observed vertical velocity spectra were influenced strongly by Doppler-shifting effects. The horizontal velocity spectra, however, were relatively insensitive to horizontal wind speed. The observed spectra are compared with predicted spectra for various models of the intrinsic motion spectrum and degrees of Doppler shifting.

  4. Spatial-frequency spectra of printed characters and human visual perception.

    PubMed

    Põder, Endel

    2003-06-01

    It is well known that certain spatial frequency (SF) bands are more important than others for character recognition. Solomon and Pelli [Nature 369 (1994) 395-397] have concluded that human pattern recognition mechanism is able to use only a narrow band from available SF spectrum of letters. However, the SF spectra of letters themselves have not been studied carefully. Here I report the results of an analysis of SF spectra of printed characters and discuss their relationship to the observed band-pass nature of letter recognition.

  5. Automatic frequency and phase alignment of in vivo J-difference-edited MR spectra by frequency domain correlation.

    PubMed

    Wiegers, Evita C; Philips, Bart W J; Heerschap, Arend; van der Graaf, Marinette

    2017-12-01

    J-difference editing is often used to select resonances of compounds with coupled spins in 1 H-MR spectra. Accurate phase and frequency alignment prior to subtracting J-difference-edited MR spectra is important to avoid artefactual contributions to the edited resonance. In-vivo J-difference-edited MR spectra were aligned by maximizing the normalized scalar product between two spectra (i.e., the correlation over a spectral region). The performance of our correlation method was compared with alignment by spectral registration and by alignment of the highest point in two spectra. The correlation method was tested at different SNR levels and for a broad range of phase and frequency shifts. In-vivo application of the proposed correlation method showed reduced subtraction errors and increased fit reliability in difference spectra as compared with conventional peak alignment. The correlation method and the spectral registration method generally performed equally well. However, better alignment using the correlation method was obtained for spectra with a low SNR (down to ~2) and for relatively large frequency shifts. Our correlation method for simultaneously phase and frequency alignment is able to correct both small and large phase and frequency drifts and also performs well at low SNR levels.

  6. A model for gravity-wave spectra observed by Doppler sounding systems

    NASA Technical Reports Server (NTRS)

    Vanzandt, T. E.

    1986-01-01

    A model for Mesosphere - Stratosphere - Troposphere (MST) radar spectra is developed following the formalism presented by Pinkel (1981). Expressions for the one-dimensional spectra of radial velocity versus frequency and versus radial wave number are presented. Their dependence on the parameters of the gravity-wave spectrum and on the experimental parameters, radar zenith angle and averaging time are described and the conditions for critical tests of the gravity-wave hypothesis are discussed. The model spectra is compared with spectra observed in the Arctic summer mesosphere by the Poker Flat radar. This model applies to any monostatic Doppler sounding system, including MST radar, Doppler lidar and Doppler sonar in the atmosphere, and Doppler sonar in the ocean.

  7. Low frequency spectra of type III solar radio bursts

    NASA Technical Reports Server (NTRS)

    Weber, R. R.

    1978-01-01

    Flux density spectra have been determined for 91 simple type III solar bursts observed by the Goddard Space Flight Center radio astronomy experiment on the IMP-6 spacecraft during 1971 and 1972. Spectral peaks were found to occur at frequencies ranging from 44 kHz up to 2500 kHz. Half of the bursts peaked between 250 kHz and 900 kHz, corresponding to emission at solar distances of about 0.3 to 0.1 AU. Maximum burst flux density sometimes exceeds 10 to the -14th W/sq m/Hz. The primary factor controlling the spectral peak frequency of these bursts appears to be a variation in intrinsic power radiated by the source as the exciter moves outward from the sun, rather than radio propagation effects between the source and IMP-6. Thus, a burst spectrum strongly reflects the evolution of the properties of the exciting electron beam, and according to current theory, beam deceleration could help account for the observations.

  8. Theoretical aspects and the experience of studying spectra of low-frequency microseisms

    NASA Astrophysics Data System (ADS)

    Birialtsev, E.; Vildanov, A.; Eronina, E.; Rizhov, D.; Rizhov, V.; Sharapov, I.

    2009-04-01

    The appearance of low-frequency spectral anomalies in natural microseismic noise over oil and gas deposits is observed since 1989 in different oil and gas regions (S. Arutunov, S. Dangel, G. Goloshubin). Several methods of prospecting and exploration of oil and gas deposits based on this effect (NTK ANCHAR, Spectraseis AG). There are several points of view (S. Arutunov, E. Birialtsev, Y. Podladchikov) about the physical model of effect which are based on fundamentally different geophysical mechanisms. One of them is based on the hypothesis of generation of the microseismic noise in to an oil and gas reservoir. Another point of view is based on the mechanism of the filtering microseismic noise in the geological medium where oil and gas reservoir is the contrast layer. For the first hypothesis an adequate quantity physical-mathematical model is absent. Second hypothesis has a discrepancy of distribution energy on theoretical calculated frequencies of waveguides «ground surface - oil deposit» eigenmodes. The fundamental frequency (less than 1 Hz for most cases) should have a highest amplitude as opposed to the regular observation range is 1-10 Hz. During 2005-2008 years by specialists of «Gradient» JSC were processed microsesmic signals from more 50 geological objects. The parameters of low-frequency anomalies were compared with medium properties (porosity, saturation and viscosity) defined according to drilling, allowed to carry out a statistical analysis and to establish some correlation. This paper presents results of theoretical calculation of spectra of microseisms in the zone of oil and gas deposits by mathematical modeling of propagation of seismic waves and comparing spectra of model microseisms with actually observed. Mathematical modeling of microseismic vibrations spectra showed good correlation of theoretical spectra and observed in practice. This is proof the applicability of microseismic methods of exploration for oil and gas. Correlation between

  9. How to constrain snow particle scattering models? A novel approach using triple-frequency radar Doppler spectra.

    NASA Astrophysics Data System (ADS)

    Kneifel, S.; Battaglia, A.; Kollias, P.; Leinonen, J. S.; Maahn, M.; Kalesse, H.; Tridon, F.; Crewell, S.

    2016-12-01

    During the last years, an increasing number of microwave (MW) scattering databases and novel approximations for single particles, complex aggregates and even rimed and melting aggregates became available. While these developments are in general a great step forward, their evaluation with observations is a very necessary but also challenging task. Recently available multi-frequency radar observations which cover the Rayleigh up to the Mie scattering regime revealed characteristic signatures of rimed and unrimed aggregated particles. However, the observed signatures are still affected by both, the particle size distribution (PSD) and the single scattering properties of the particles which makes a clear evaluation of one or the other challenging. In this contribution we present a new approach which uses the radar Doppler spectra at three frequencies (X, Ka, and W-band) collected during a recent winter field campaign in Finland. We analyzed a snowfall event which includes rimed and unrimed snow aggregates. A large selection of spectra obtained from low-turbulence regions within the cloud reveals distinctly different signatures of the derived Doppler spectral ratios. Due to the third frequency, a characteristic curve can be derived which is almost independent of the underlying particle size distribution and velocity-size relation. The characteristics of the curves obtained for rimed and unrimed are distinctly different. The observed signatures were compared with scattering calculations obtained with discrete dipole approximation (DDA), self-similar Rayleigh-Gans approximation (SSRG), and with the classical soft spheroid (T-Matrix) method. While the DDA calculations of unrimed and rimed aggregates fit the observed signatures well, the T-Matrix results lie far outside the observed range. The SSRG approximations was found to be principally able to recover the main features but a better matching would need an adjustment of the published coefficients. Future campaigns, like

  10. A simple method for the computation of first neighbour frequencies of DNAs from CD spectra

    PubMed Central

    Marck, Christian; Guschlbauer, Wilhelm

    1978-01-01

    A procedure for the computation of the first neighbour frequencies of DNA's is presented. This procedure is based on the first neighbour approximation of Gray and Tinoco. We show that the knowledge of all the ten elementary CD signals attached to the ten double stranded first neighbour configurations is not necessary. One can obtain the ten frequencies of an unknown DNA with the use of eight elementary CD signals corresponding to eight linearly independent polymer sequences. These signals can be extracted very simply from any eight or more CD spectra of double stranded DNA's of known frequencies. The ten frequencies of a DNA are obtained by least square fit of its CD spectrum with these elementary signals. One advantage of this procedure is that it does not necessitate linear programming, it can be used with CD data digitalized using a large number of wavelengths, thus permitting an accurate resolution of the CD spectra. Under favorable case, the ten frequencies of a DNA (not used as input data) can be determined with an average absolute error < 2%. We have also observed that certain satellite DNA's, those of Drosophila virilis and Callinectes sapidus have CD spectra compatible with those of DNA's of quasi random sequence; these satellite DNA's should adopt also the B-form in solution. PMID:673843

  11. Comparison of the observed and calculated coherent forward scattering spectra of the 842.5 nm Ar I and 844.6 nm O I lines in a radio frequency glow discharge

    NASA Astrophysics Data System (ADS)

    Matsuta, Hideyuki

    2017-06-01

    The coherent forward scattering (CFS) spectra of O I 844.6 nm and Ar I 842.5 nm lines in a radio frequency (RF) glow discharge were measured using a CFS spectrometer that functions in the Faraday configuration with permanent double-ring magnets and a diode-laser source. A significant change in the CFS spectrum of the Ar I 842.5 nm line was observed when the partial pressures of argon in a Hesbnd Ar RF glow discharge were changed . Based on the theoretical calculations of the CFS spectra performed using Faraday functions, a comparison between the observed and calculated spectra was performed. The CFS line profile of O I 844.6 nm and changes in the Ar I 842.5 nm CFS spectrum are explained by theoretical calculations.

  12. Transformation of apparent ocean wave spectra observed from an aircraft sensor platform

    NASA Technical Reports Server (NTRS)

    Poole, L. R.

    1976-01-01

    The problem considered was transformation of a unidirectional apparent ocean wave spectrum observed from an aircraft sensor platform into the true spectrum that would be observed from a stationary platform. Spectral transformation equations were developed in terms of the linear wave dispersion relationship and the wave group speed. An iterative solution to the equations was outlined and used to transform reference theoretical apparent spectra for several assumed values of average water depth. Results show that changing the average water depth leads to a redistribution of energy density among the various frequency bands of the transformed spectrum. This redistribution is most severe when much of the energy density is expected, a priori, to reside at relatively low true frequencies.

  13. Observation of Pure Rotational Spectra of SiCCN by Fourier-Transform Microwave Spectroscopy

    NASA Astrophysics Data System (ADS)

    Umeki, Hiroya; Nakajima, Masakazu; Endo, Yasuki

    2014-06-01

    Pure rotational spectra of SiCCN ( ˜{X} 2Π3/2) have been observed using Fourier-transform microwave (FTMW) spectroscopy in the frequency region 13 to 35 GHz. The SiCCN radical was produced in a supersonic jet by discharging a mixture gas, 0.2% SiCl4 and 0.2% CH3CN diluted in Ar. The effective rotational constant Beff,3/2, the centrifugal distortion constant D, and the hyperfine coupling constants, a + (b + c)/2 and eQq0, were determined with a standard deviation of the fit to be 6 kHz. Determined B and eQq0 are consistent with those derived from ab initio calculations. Λ-type doublings were not resolved for the observed spectra.

  14. A comparison of the far-infrared and low-frequency Raman spectra of glass-forming liquids

    NASA Astrophysics Data System (ADS)

    Perova, T. S.; Vij, J. K.; Christensen, D. H.; Nielsen, O. F.

    1999-04-01

    Far-infrared and low-frequency Raman spectra in the wavenumber range from 15 to 500 cm -1 were recorded for glycerol, triacetin (glycerol triacetate) and o-terphenyl at temperatures from 253 to 355 K. The far-infrared spectra of glycerol appear complex compared with the spectra of triacetin owing to the presence of hydrogen bonding in glycerol. The experimental results obtained for o-terphenyl are in good agreement with normal mode analyses carried out for crystalline o-terphenyl (A. Criado, F.J. Bermejo, A. de Andres, Mol. Phys. 82 (1994) 787). The far-infrared results are compared with the low-frequency Raman spectra of these three glass-forming liquids. The difference in temperature dependences found from these spectra is explained on the basis of different temperature contributions of the relaxational and vibrational processes to the low-frequency vibrational spectra.

  15. Comparison between measured and predicted turbulence frequency spectra in ITG and TEM regimes

    NASA Astrophysics Data System (ADS)

    Citrin, J.; Arnichand, H.; Bernardo, J.; Bourdelle, C.; Garbet, X.; Jenko, F.; Hacquin, S.; Pueschel, M. J.; Sabot, R.

    2017-06-01

    The observation of distinct peaks in tokamak core reflectometry measurements—named quasi-coherent-modes (QCMs)—are identified as a signature of trapped-electron-mode (TEM) turbulence (Arnichand et al 2016 Plasma Phys. Control. Fusion 58 014037). This phenomenon is investigated with detailed linear and nonlinear gyrokinetic simulations using the Gene code. A Tore-Supra density scan is studied, which traverses through a linear (LOC) to saturated (SOC) ohmic confinement transition. The LOC and SOC phases are both simulated separately. In the LOC phase, where QCMs are observed, TEMs are robustly predicted unstable in linear studies. In the later SOC phase, where QCMs are no longer observed, ion-temperature-gradient (ITG) modes are identified. In nonlinear simulations, in the ITG (SOC) phase, a broadband spectrum is seen. In the TEM (LOC) phase, a clear emergence of a peak at the TEM frequencies is seen. This is due to reduced nonlinear frequency broadening of the underlying linear modes in the TEM regime compared with the ITG regime. A synthetic diagnostic of the nonlinearly simulated frequency spectra reproduces the features observed in the reflectometry measurements. These results support the identification of core QCMs as an experimental marker for TEM turbulence.

  16. The first observation of Carbon-13 spin noise spectra

    PubMed Central

    Schlagnitweit, Judith; Müller, Norbert

    2012-01-01

    We demonstrate the first 13C NMR spin noise spectra obtained without any pulse excitation by direct detection of the randomly fluctuating noise from samples in a cryogenically cooled probe. Noise power spectra were obtained from 13C enriched methanol and glycerol samples at 176 MHz without and with 1H decoupling, which increases the sensitivity without introducing radio frequency interference with the weak spin noise. The multiplet amplitude ratios in 1H coupled spectra indicate that, although pure spin noise prevails in these spectra, the influence of absorbed circuit noise is still significant at the high concentrations used. In accordance with the theory heteronuclear Overhauser enhancements are absent from the 1H-decoupled 13C spin noise spectra. PMID:23041799

  17. Power spectra at radio frequency of lightning return stroke waveforms

    NASA Technical Reports Server (NTRS)

    Lanzerotti, L. J.; Thomson, D. J.; Maclennan, C. G.; Rinnert, K.; Krider, E. P.

    1989-01-01

    The power spectra of the wideband (10 Hz to 100 kHz) magnetic field signals in a number of lightning return strokes (primarily first return strokes) measured during a lightning storm which occurred in Lindau, West Germany in August, 1984 have been calculated. The RF magnetic field data were obtained with the engineering unit of the Galileo Jupiter Probe lightning experiment. The spectra of the magnetic field data definitely show fine structure, with two or three distinct peaks appearing in the spectra of many of the waveforms. An enhancement of power at frequencies of about 60-70 kHz is often seen in the spectra of the waveform time segments preceding and following the rise-to-peak amplitude of the return stroke.

  18. Spectral analysis of temperature and Brunt-Vaisala frequency fluctuations observed by radiosondes

    NASA Technical Reports Server (NTRS)

    Tsuda, T.; Vanzandt, T. E.; Kato, S.; Fukao, S.; Sato, T.

    1989-01-01

    Recent studies have revealed that vertical wave number spectra of wind velocity and temperture fluctuations in the troposphere and the lower stratosphere are fairly well explained by a saturated gravity wave spectrum. But N(2) (N:Brunt-Vaisala (BV) frequency) spectra seem to be better for testing the scaling of the vertical wave number spectra in layers with different stratifications, beause its energy density is proportional only to the background value of N(2), while that for temperature depends on both the BV frequency and the potential temperature. From temperature profiles observed in June to August 1987 over the MU Observatory, Japan, by using a radiosonde with 30 m height resolution, N(2) spectra are determined in the 2 to 8.5 km (troposphere) and 18.5 to 25 km (lower stratosphere) ranges. Although individual spectra show fairly large day-by-day variability, the slope of the median of 34 spectra agrees reasonably with the theoretical value of -1 in the wave number range of 6 x 10(-4) similar to 3 x 10(-3) (c/m). The ratio of the spectral energy between these two height regions is about equal to the ratio of N(2), consistent with the prediction of saturated gravity wave theory.

  19. Drop-port study of microresonator frequency combs: power transfer, spectra and time-domain characterization.

    PubMed

    Wang, Pei-Hsun; Xuan, Yi; Fan, Li; Varghese, Leo Tom; Wang, Jian; Liu, Yang; Xue, Xiaoxiao; Leaird, Daniel E; Qi, Minghao; Weiner, Andrew M

    2013-09-23

    We use a drop-port geometry to characterize frequency combs generated from silicon nitride on-chip microresonators in the normal group velocity regime. In sharp contrast with the traditional transmission geometry, we observe smooth output spectra with comparable powers in the pump and adjacent comb lines. The power transfer into the comb may be explained to a large extent by the coupling parameters characterizing the linear operation of the resonances studied. Furthermore, comparison of thru- and drop-port spectra shows that much of the ASE noise is filtered out by transmission to the drop-port. Autocorrelation measurements are performed on the drop-port output, without the need to filter out or suppress the strong pump line as is necessary in thru-port experiments. Passively mode-locked pulses with low background are observed in a normal dispersion microcavity.

  20. Negative permittivity and permeability spectra of Cu/yttrium iron garnet hybrid granular composite materials in the microwave frequency range

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tsutaoka, Takanori, E-mail: tsutaok@hiroshima-u.ac.jp; Fukuyama, Koki; Kinoshita, Hideaki

    2013-12-23

    The relative complex permittivity and permeability spectra of the coagulated copper and yttrium iron garnet (Cu/YIG) hybrid granular composite materials have been studied in the microwave range. The insulator to metal transition was observed at the percolation threshold of Cu particle content (φ{sub Cu} = 16.0 vol. %) in the electrical conductivity. In the percolation threshold, the low frequency plasmonic state caused by the metallic Cu particle networks was observed. The percolated Cu/YIG granular composites show simultaneous negative permittivity and permeability spectra under external magnetic fields.

  1. On the frequency spectra of the core magnetic field Gauss coefficients

    NASA Astrophysics Data System (ADS)

    Lesur, Vincent; Wardinski, Ingo; Baerenzung, Julien; Holschneider, Matthias

    2018-03-01

    From monthly mean observatory data spanning 1957-2014, geomagnetic field secular variation values were calculated by annual differences. Estimates of the spherical harmonic Gauss coefficients of the core field secular variation were then derived by applying a correlation based modelling. Finally, a Fourier transform was applied to the time series of the Gauss coefficients. This process led to reliable temporal spectra of the Gauss coefficients up to spherical harmonic degree 5 or 6, and down to periods as short as 1 or 2 years depending on the coefficient. We observed that a k-2 slope, where k is the frequency, is an acceptable approximation for these spectra, with possibly an exception for the dipole field. The monthly estimates of the core field secular variation at the observatory sites also show that large and rapid variations of the latter happen. This is an indication that geomagnetic jerks are frequent phenomena and that significant secular variation signals at short time scales - i.e. less than 2 years, could still be extracted from data to reveal an unexplored part of the core dynamics.

  2. High Sensitive Scintillation Observations At Very Low Frequencies

    NASA Astrophysics Data System (ADS)

    Konovalenko, A. A.; Falkovich, I. S.; Kalinichenko, N. N.; Olyak, M. R.; Lecacheux, A.; Rosolen, C.; Bougeret, J.-L.; Rucker, H. O.; Tokarev, Yu.

    The observation of interplanetary scintillations of compact radio sources is powerful method of solar wind diagnostics. This method is developed mainly at decimeter- meter wavelengths. New possibilities are opened at extremely low frequencies (decameter waves) especially at large elongations. Now this approach is being actively developed using high effective decameter antennas UTR-2, URAN and Nancay Decameter Array. New class of back-end facility like high dynamic range, high resolution digital spectral processors, as well as dynamic spectra determination ideology give us new opportunities for distinguishing of the ionospheric and interplanetary scintillations and for observations of large number of radio sources, whith different angular sizes and elongations, even for the cases of rather weak objects.

  3. Observational and theoretical spectra of supernovae

    NASA Astrophysics Data System (ADS)

    Wheeler, J. Craig; Swartz, Douglas A.; Harkness, Robert P.

    1993-05-01

    Progress in nuclear astrophysics by means of quantitative supernova spectroscopy is discussed with special concentration on type Ia, Ib and Ic and on SN 1987A. Spectral calculations continue to support an exploding C/O white dwarf as the best model of a SN Ia. Deflagration model W7 produces good maximum light spectra of SN Ia and seems to have a better composition distribution compared to delayed detonation models, but proper treatment of opacity remains a problem and the physical basis of SN Ia explosions is still not completely understood. All models for SN Ia predict large quantities of 56Co in the ejecta, but it is not clear that observations confirm this. Although the evolutionary origin of SN Ia remains uncertain, there is recent evidence that transfer of hydrogen in a binary system may be involved, as long suspected. There has been progress in comparing dynamical models with the optical/IR spectra of SN 1987A. The evolution of the [OI] λλ6300, 6364 feature and the presence of strong persistent HeI λ10 830 indicate that both the envelope and core material contribute substantially to the formation of emission lines in the nebular phase and that neither the core nor the envelope can be neglected. Blending with nearby hydrogen lines may affect both of these spectral features, thereby complicating the analysis of the lines. The effects of continuum transfer and photoionization have been included and are under study. The discrepancies between theoretical and observed spectra are due primarily to the one-dimensional hydrodynamic models. The spectral data are not consistent with the high density ``spike'' (in radial coordinate) of the core material that is predicted by all such models. Analysis of the light curves of SN Ib and SN Ic supernovae implies that there are significant differences in their physical properties. Some SN Ib have considerably more ejecta mass than SN Ic events. SN Ib require He-rich atmospheres to produce the observed strong optical lines of

  4. Observational and theoretical spectra of supernovae

    NASA Astrophysics Data System (ADS)

    Craig Wheeler, J.; Swartz, Douglas A.; Harkness, Robert P.

    1993-05-01

    Progress in nuclear astrophysics by means of quantitative supernova spectroscopy is discussed with special concentration on type Ia, Ib and Ic and on SN 1987A. Spectral calculations continue to support an exploding C/O white dwarf as the best model of a SN Ia. Deflagration model W7 produces good maximum light spectra of SN Ia and seems to have a better composition distribution compared to delayed detonation models, but proper treatment of opacity remains a problem and the physical basis of SN Ia explosions is still not completely understood. All models for SN Ia predict large quantities of 56Co in the ejecta, but it is not clear that observations confirm this. Although the evolutionary origin of SN Ia remains uncertain, there is recent evidence that transfer of hydrogen in a binary system may be involved, as long suspected. There has been progress in comparing dynamical models with the optical/IR spectra of SN 1987A. The evolution of the [OI] λλ6300, 6364 feature and the presence of strong persistent HeI λ10 830 indicate that both the envelope and core material contribute substantially to the formation of emission lines in the nebular phase and that neither the core nor the envelope can be neglected. Blending with nearby hydrogen lines may affect both of these spectral features, thereby complicating the analysis of the lines. The effects of continuum transfer and photoionization have been included and are under study. The discrepancies between theoretical and observed spectra are due primarily to the one-dimensional hydrodynamic models. The spectral data are not consistent with the high density “spike” (in radial coordinate) of the core material that is predicted by all such models. Analysis of the light curves of SN Ib and SN Ic supernovae implies that there are significant differences in their physical properties. Some SN Ib have considerably more ejecta mass than SN Ic events. SN Ib require He-rich atmospheres to produce the observed strong optical lines

  5. Coherence Volume of an Optical Wave Field with Broad Frequency and Angular Spectra

    NASA Astrophysics Data System (ADS)

    Lyakin, D. V.; Mysina, N. Yu.; Ryabukho, V. P.

    2018-03-01

    We consider the sizes of a region in a three-dimensional space in which an optical wave field excites mutually coherent perturbations. We discuss the conditions under which the length of this region along the direction of propagation of the wave field and, correspondingly, its volume are determined either by the width of the frequency spectrum of the field or by the width of its angular spectrum, or by the parameters of these spectra simultaneously. We obtain expressions for estimating extremely small values of the coherence volume of the fields with a broad frequency spectrum and an extremely broad angular spectrum. Using the notion of instantaneous speckle-modulation of the wave field, we give a physical interpretation to the occurrence of a limited coherence volume of the field. The length of the spatiotemporal coherence region in which mutually coherent perturbations occur at different times is determined. The coherence volume of a wave field that illuminates an object in high-resolution microscopy with frequency broadband light is considered. The conditions for the dominant influence of the angular or frequency spectra on the longitudinal length of the coherence region are given, and the conditions for the influence of the frequency spectrum width on the transverse coherence of the wave field are examined. We show that, when using fields with broad and ultrabroad spectra in high-resolution microscopy, this influence should be taken into account.

  6. Fitting the low-frequency Raman spectra to boson peak models: glycerol, triacetin and polystyrene

    NASA Astrophysics Data System (ADS)

    Kirillov, S. A.; Perova, T. S.; Faurskov Nielsen, O.; Praestgaard, E.; Rasmussen, U.; Kolomiyets, T. M.; Voyiatzis, G. A.; Anastasiadis, S. H.

    1999-04-01

    A computational approach was elaborated to explicitly account for the Rayleigh line wing, the Boson peak and vibrational contributions to the low-frequency Raman spectra of amorphous solids and viscous liquids. It was shown that the low-frequency Raman spectra of glycerol and polystyrene consist of the Rayleigh contribution of Lorentzian form and the Boson peak which profile follows the predictions of the theory by Martin and Brenig in the version by Malinovsky and Sokolov. In the case of triacetin, the Boson peaks decay faster in their high-frequency side than the above theory predicts. Their form can be successfully modeled with a newly introduced empirical function intermediate between the Martin-Brenig and Malinovsky-Sokolov predictions.

  7. Directional Wave Spectra Observed During Intense Tropical Cyclones

    NASA Astrophysics Data System (ADS)

    Collins, C. O.; Potter, H.; Lund, B.; Tamura, H.; Graber, H. C.

    2018-02-01

    Two deep-sea moorings were deployed 780 km off the coast of southern Taiwan for 4-5 months during the 2010 typhoon season. Directional wave spectra, wind speed and direction, and momentum fluxes were recorded on two Extreme Air-Sea Interaction buoys during the close passage of Severe Tropical Storm Dianmu and three tropical cyclones (TCs): Typhoon Fanapi, Super Typhoon Megi, and Typhoon Chaba. Conditions sampled include significant wave heights up to 11 m and wind speeds up to 26 m s-1. Details varied for large-scale spectral structure in frequency and direction but were mostly bimodal. The modes were generally composed of a swell system emanating from the most intense storm region and local wind-seas. The peak systems were consistently young, meaning actively forced by winds, when the storms were close. During the peaks of the most intense passages—Chaba at the northern mooring and Megi at the southern—the bimodal seas coalesced. During Chaba, the swell and wind-sea coupling directed the high frequency waves and the wind stress away from the wind direction. A spectral wave model was able reproduce many of the macrofeatures of the directional spectra.

  8. BinMag: Widget for comparing stellar observed with theoretical spectra

    NASA Astrophysics Data System (ADS)

    Kochukhov, O.

    2018-05-01

    BinMag examines theoretical stellar spectra computed with Synth/SynthMag/Synmast/Synth3/SME spectrum synthesis codes and compare them to observations. An IDL widget program, BinMag applies radial velocity shift and broadening to the theoretical spectra to account for the effects of stellar rotation, radial-tangential macroturbulence, instrumental smearing. The code can also simulate spectra of spectroscopic binary stars by appropriate coaddition of two synthetic spectra. Additionally, BinMag can be used to measure equivalent width, fit line profile shapes with analytical functions, and to automatically determine radial velocity and broadening parameters. BinMag interfaces with the Synth3 (ascl:1212.010) and SME (ascl:1202.013) codes, allowing the user to determine chemical abundances and stellar atmospheric parameters from the observed spectra.

  9. Titan solar occultation observations reveal transit spectra of a hazy world.

    PubMed

    Robinson, Tyler D; Maltagliati, Luca; Marley, Mark S; Fortney, Jonathan J

    2014-06-24

    High-altitude clouds and hazes are integral to understanding exoplanet observations, and are proposed to explain observed featureless transit spectra. However, it is difficult to make inferences from these data because of the need to disentangle effects of gas absorption from haze extinction. Here, we turn to the quintessential hazy world, Titan, to clarify how high-altitude hazes influence transit spectra. We use solar occultation observations of Titan's atmosphere from the Visual and Infrared Mapping Spectrometer aboard National Aeronautics and Space Administration's (NASA) Cassini spacecraft to generate transit spectra. Data span 0.88-5 μm at a resolution of 12-18 nm, with uncertainties typically smaller than 1%. Our approach exploits symmetry between occultations and transits, producing transit radius spectra that inherently include the effects of haze multiple scattering, refraction, and gas absorption. We use a simple model of haze extinction to explore how Titan's haze affects its transit spectrum. Our spectra show strong methane-absorption features, and weaker features due to other gases. Most importantly, the data demonstrate that high-altitude hazes can severely limit the atmospheric depths probed by transit spectra, bounding observations to pressures smaller than 0.1-10 mbar, depending on wavelength. Unlike the usual assumption made when modeling and interpreting transit observations of potentially hazy worlds, the slope set by haze in our spectra is not flat, and creates a variation in transit height whose magnitude is comparable to those from the strongest gaseous-absorption features. These findings have important consequences for interpreting future exoplanet observations, including those from NASA's James Webb Space Telescope.

  10. High-resolution vertical velocities and their power spectrum observed with the MAARSY radar - Part 1: frequency spectrum

    NASA Astrophysics Data System (ADS)

    Li, Qiang; Rapp, Markus; Stober, Gunter; Latteck, Ralph

    2018-04-01

    The Middle Atmosphere Alomar Radar System (MAARSY) installed at the island of Andøya has been run for continuous probing of atmospheric winds in the upper troposphere and lower stratosphere (UTLS) region. In the current study, we present high-resolution wind measurements during the period between 2010 and 2013 with MAARSY. The spectral analysis applying the Lomb-Scargle periodogram method has been carried out to determine the frequency spectra of vertical wind velocity. From a total of 522 days of observations, the statistics of the spectral slope have been derived and show a dependence on the background wind conditions. It is a general feature that the observed spectra of vertical velocity during active periods (with wind velocity > 10 m s-1) are much steeper than during quiet periods (with wind velocity < 10 m s-1). The distribution of spectral slopes is roughly symmetric with a maximum at -5/3 during active periods, whereas a very asymmetric distribution with a maximum at around -1 is observed during quiet periods. The slope profiles along altitudes reveal a significant height dependence for both conditions, i.e., the spectra become shallower with increasing altitudes in the upper troposphere and maintain roughly a constant slope in the lower stratosphere. With both wind conditions considered together the general spectra are obtained and their slopes are compared with the background horizontal winds. The comparisons show that the observed spectra become steeper with increasing wind velocities under quiet conditions, approach a spectral slope of -5/3 at a wind velocity of 10 m s-1 and then roughly maintain this slope (-5/3) for even stronger winds. Our findings show an overall agreement with previous studies; furthermore, they provide a more complete climatology of frequency spectra of vertical wind velocities under different wind conditions.

  11. Titan solar occultation observations reveal transit spectra of a hazy world

    PubMed Central

    Robinson, Tyler D.; Maltagliati, Luca; Marley, Mark S.; Fortney, Jonathan J.

    2014-01-01

    High-altitude clouds and hazes are integral to understanding exoplanet observations, and are proposed to explain observed featureless transit spectra. However, it is difficult to make inferences from these data because of the need to disentangle effects of gas absorption from haze extinction. Here, we turn to the quintessential hazy world, Titan, to clarify how high-altitude hazes influence transit spectra. We use solar occultation observations of Titan’s atmosphere from the Visual and Infrared Mapping Spectrometer aboard National Aeronautics and Space Administration’s (NASA) Cassini spacecraft to generate transit spectra. Data span 0.88–5 μm at a resolution of 12–18 nm, with uncertainties typically smaller than 1%. Our approach exploits symmetry between occultations and transits, producing transit radius spectra that inherently include the effects of haze multiple scattering, refraction, and gas absorption. We use a simple model of haze extinction to explore how Titan’s haze affects its transit spectrum. Our spectra show strong methane-absorption features, and weaker features due to other gases. Most importantly, the data demonstrate that high-altitude hazes can severely limit the atmospheric depths probed by transit spectra, bounding observations to pressures smaller than 0.1–10 mbar, depending on wavelength. Unlike the usual assumption made when modeling and interpreting transit observations of potentially hazy worlds, the slope set by haze in our spectra is not flat, and creates a variation in transit height whose magnitude is comparable to those from the strongest gaseous-absorption features. These findings have important consequences for interpreting future exoplanet observations, including those from NASA’s James Webb Space Telescope. PMID:24876272

  12. First-Principles Framework to Compute Sum-Frequency Generation Vibrational Spectra of Semiconductors and Insulators.

    PubMed

    Wan, Quan; Galli, Giulia

    2015-12-11

    We present a first-principles framework to compute sum-frequency generation (SFG) vibrational spectra of semiconductors and insulators. The method is based on density functional theory and the use of maximally localized Wannier functions to compute the response to electric fields, and it includes the effect of electric field gradients at surfaces. In addition, it includes quadrupole contributions to SFG spectra, thus enabling the verification of the dipole approximation, whose validity determines the surface specificity of SFG spectroscopy. We compute the SFG spectra of ice I_{h} basal surfaces and identify which spectra components are affected by bulk contributions. Our results are in good agreement with experiments at low temperature.

  13. Short wind waves on the ocean: Wavenumber-frequency spectra

    NASA Astrophysics Data System (ADS)

    Plant, William J.

    2015-03-01

    Dominant surface waves on the ocean exhibit a dispersion relation that confines their energy to a curve in a wavenumber-frequency spectrum. Short wind waves on the ocean, on the other hand, are advected by these dominant waves so that they do not exhibit a well-defined dispersion relation over many realizations of the surface. Here we show that the short-wave analog to the dispersion relation is a distributed spectrum in the wavenumber-frequency plane that collapses to the standard dispersion relation in the absence of long waves. We compute probability distributions of short-wave wavenumber given a (frequency, direction) pair and of short-wave frequency given a (wavenumber, direction) pair. These two probability distributions must yield a single spectrum of surface displacements as a function of wavenumber and frequency, F(k,f). We show that the folded, azimuthally averaged version of this spectrum has a "butterfly" pattern in the wavenumber-frequency plane if significant long waves are present. Integration of this spectrum over frequency yields the well-known k-3 wavenumber spectrum. When integrated over wavenumber, the spectrum yields an f-4 form that agrees with measurement. We also show that a cut through the unfolded F(k,f) at constant k produces the well-known form of moderate-incidence-angle Doppler spectra for electromagnetic scattering from the sea. This development points out the dependence of the short-wave spectrum on the amplitude of the long waves.

  14. Complex inner core boundary from frequency characteristics of the reflection coefficients of PKiKP waves observed by Hi-net

    NASA Astrophysics Data System (ADS)

    Tanaka, Satoru; Tkalčić, Hrvoje

    2015-12-01

    Frequency-dependent reflection coefficients of P waves at the inner core boundary (ICB) are estimated from the spectral ratios of PKiKP and PcP waves observed by the high-sensitivity seismograph network (Hi-net) in Japan. The corresponding PKiKP reflection locations at the ICB are distributed beneath the western Pacific. At frequencies where noise levels are sufficiently low, spectra of reflection coefficients show four distinct sets of characteristics: a flat spectrum, a spectrum with a significant spectral hole at approximately 1 or 3 Hz, a spectrum with a strong peak at approximately 2 or 3 Hz, and a spectrum containing both a sharp peak and a significant hole. The variety in observed spectra suggests complex lateral variations in ICB properties. To explain the measured differences in frequency characteristics of ICB reflection coefficients, we conduct 2D finite difference simulations of seismic wavefields near the ICB. The models tested in our simulations include a liquid layer and a solid layer above the ICB, as well as sinusoidal and spike-shaped ICB topography with varying heights and scale lengths. We find that the existence of a layer above the ICB can be excluded as a possible explanation for the observed spectra. Furthermore, we find that an ICB topographic model with wavelengths and heights of several kilometers is too extreme to explain our measurements. However, restricting the ICB topography to wavelengths and heights of 1.0-1.5 km can explain the observed frequency-related phenomena. The existence of laterally varying topography may be a sign of lateral variations in inner core solidification.

  15. VUV Spectra observed in C-2 FRC plasma

    NASA Astrophysics Data System (ADS)

    Osin, Dmitry; Douglass, Jon; Tuszewski, Michel; TAE Team

    2014-10-01

    A grazing incidence flat-field spectrometer was installed for observation of vuv-spectra in C-2 FRC experiment. Wavelength calibration was done by observing spectra of six different gases produced by a hollow-cathode discharge lamp . In addition, in-situ calibration and alignment were performed utilizing neutral-beam heated gases. Wavelength regions between 16 nm and 170 nm was investigated with accuracy of about 0.02 nm. VUV-spectral lines of the most abundant impurity ions were identified both for Plasma Gun and C-2 plasmas. In addition to D spectrum, strong lines of O III-VI, N IV-V, C II-III, and Fe II ions were observed during the plasma lifetime. VUV radiative power losses within energy range from 7.3 eV to 81 eV were estimated based on the calculated FRC dimensions.

  16. Evolutionary Model and Oscillation Frequencies for α Ursae Majoris: A Comparison with Observations

    NASA Astrophysics Data System (ADS)

    Guenther, D. B.; Demarque, P.; Buzasi, D.; Catanzarite, J.; Laher, R.; Conrow, T.; Kreidl, T.

    2000-02-01

    Inspired by the observations of low-amplitude oscillations of α Ursae Majoris A by Buzasi et al. using the WIRE satellite, a grid of stellar evolutionary tracks has been constructed to derive physically consistent interior models for the nearby red giant. The pulsation properties of these models were then calculated and compared with the observations. It is found that, by adopting the correct metallicity and for a normal helium abundance, only models in the mass range of 4.0-4.5 Msolar fall within the observational error box for α UMa A. This mass range is compatible, within the uncertainties, with the mass derived from the astrometric mass function. Analysis of the pulsation spectra of the models indicates that the observed α UMa oscillations can be most simply interpreted as radial (i.e., l=0) p-mode oscillations of low radial order n. The lowest frequencies observed by Buzasi et al. are compatible, within the observational errors, with model frequencies of radial orders n=0, 1, and 2 for models in the mass range of 4.0-4.5 Msolar. The higher frequencies observed can also be tentatively interpreted as higher n-valued radial p-modes, if we allow that some n-values are not presently observed. The theoretical l=1, 2, and 3 modes in the observed frequency range are g-modes with a mixed mode character, that is, with p-mode-like characteristics near the surface and g-mode-like characteristics in the interior. The calculated radial p-mode frequencies are nearly equally spaced, separated by 2-3 μHz. The nonradial modes are very densely packed throughout the observed frequency range and, even if excited to significant amplitudes at the surface, are unlikely to be resolved by the present observations.

  17. Frequency Correction for MIRO Chirp Transformation Spectroscopy Spectrum

    NASA Technical Reports Server (NTRS)

    Lee, Seungwon

    2012-01-01

    This software processes the flyby spectra of the Chirp Transform Spectrometer (CTS) of the Microwave Instrument for Rosetta Orbiter (MIRO). The tool corrects the effect of Doppler shift and local-oscillator (LO) frequency shift during the flyby mode of MIRO operations. The frequency correction for CTS flyby spectra is performed and is integrated with multiple spectra into a high signal-to-noise averaged spectrum at the rest-frame RF frequency. This innovation also generates the 8 molecular line spectra by dividing continuous 4,096-channel CTS spectra. The 8 line spectra can then be readily used for scientific investigations. A spectral line that is at its rest frequency in the frame of the Earth or an asteroid will be observed with a time-varying Doppler shift as seen by MIRO. The frequency shift is toward the higher RF frequencies on approach, and toward lower RF frequencies on departure. The magnitude of the shift depends on the flyby velocity. The result of time-varying Doppler shift is that of an observed spectral line will be seen to move from channel to channel in the CTS spectrometer. The direction (higher or lower frequency) in the spectrometer depends on the spectral line frequency under consideration. In order to analyze the flyby spectra, two steps are required. First, individual spectra must be corrected for the Doppler shift so that individual spectra can be superimposed at the same rest frequency for integration purposes. Second, a correction needs to be applied to the CTS spectra to account for the LO frequency shifts that are applied to asteroid mode.

  18. Experimental observation and determination of the laser-induced frequency shift of hyperfine levels of ultracold polar molecules

    NASA Astrophysics Data System (ADS)

    Liu, Wenliang; Wang, Xiaofeng; Wu, Jizhou; Su, Xingliang; Wang, Shen; Sovkov, Vladimir B.; Ma, Jie; Xiao, Liantuan; Jia, Suotang

    2017-08-01

    We report on the experimental observation and quantitative determination of the laser-induced frequency shift (LIFS) of the ultracold polar molecules formed by photoassociation (PA). The experiments are performed by detecting a series of double PA spectra with a molecular hyperfine structure, which are induced by two PA lasers with a precise and adjustable frequency reference. We find that the LIFS of the molecular hyperfine levels shows a linear dependence on PA laser intensity.

  19. The variation in frequency locations in Doppler ultrasound spectra for maximum blood flow velocities in narrowed vessels.

    PubMed

    Zhang, Yingyun; Zhang, Yufeng; Gao, Lian; Deng, Li; Hu, Xiao; Zhang, Kexin; Li, Haiyan

    2017-11-01

    This study assessed the variation in the frequency locations in the Doppler ultrasound spectra for the maximum blood flow velocities of in vessels with different degrees of bilaterally axisymmetric stenosis. This was done by comparing the relationship between the velocity distributions and corresponding Doppler power spectra. First, a geometric vessel model with axisymmetric stenosis was established. This made it possible to obtain the blood flow velocity distributions for different degrees of stenosis from the solutions of the Navier-Stokes equations. Then, the Doppler spectra were calculated for the entire segment of the vessel that was covered by the sound field. Finally, the maximum frequency locations for the spectra were determined based on the intersections of the maximum values chosen from the calculated blood flow velocity distributions and their corresponding spectra. The computational analysis showed that the maximum frequencies, which corresponded to the maximum blood flow velocities for different degrees of stenosis, were located at different positions along the spectral falling edges. The location for a normal (stenosis free) vessel was in the middle of the falling edge. For vessels with increasing degrees of stenosis, this location shifted approximately linearly downward along the falling edge. For 40% stenosis, the location reached a position at the falling edge of 0.32. Results obtained using the Field II simulation tool demonstrated the validity of the theoretical analysis and calculations, and may help to improve the maximum velocity estimation accuracy for Doppler blood flow spectra in stenosed vessels. Copyright © 2017 IPEM. Published by Elsevier Ltd. All rights reserved.

  20. Characterization of radiation belt electron energy spectra from CRRES observations

    NASA Astrophysics Data System (ADS)

    Johnston, W. R.; Lindstrom, C. D.; Ginet, G. P.

    2010-12-01

    Energetic electrons in the outer radiation belt and the slot region exhibit a wide variety of energy spectral forms, more so than radiation belt protons. We characterize the spatial and temporal dependence of these forms using observations from the CRRES satellite Medium Electron Sensor A (MEA) and High-Energy Electron Fluxmeter (HEEF) instruments, together covering an energy range 0.15-8 MeV. Spectra were classified with two independent methods, data clustering and curve-fitting analyses, in each case defining categories represented by power law, exponential, and bump-on-tail (BOT) or other complex shapes. Both methods yielded similar results, with BOT, exponential, and power law spectra respectively dominating in the slot region, outer belt, and regions just beyond the outer belt. The transition from exponential to power law spectra occurs at higher L for lower magnetic latitude. The location of the transition from exponential to BOT spectra is highly correlated with the location of the plasmapause. In the slot region during the days following storm events, electron spectra were observed to evolve from exponential to BOT yielding differential flux minima at 350-650 keV and maxima at 1.5-2 MeV; such evolution has been attributed to energy-dependent losses from scattering by whistler hiss.

  1. X ray spectra of X Per. [oso-8 observations

    NASA Technical Reports Server (NTRS)

    Becker, R. H.; Boldt, E. A.; Holt, S. S.; Pravdo, S. H.; Robinson-Saba, J.; Serlemitsos, P. J.; Swank, J. H.

    1978-01-01

    The cosmic X-ray spectroscopy experiment on OSO-8 observed X Per for twenty days during two observations in Feb. 1976 and Feb. 1977. The spectrum of X Per varies in phase with its 13.9 min period, hardening significantly at X-ray minimum. Unlike other X-ray binary pulsar spectra, X Per's spectra do not exhibit iron line emission or strong absorption features. The data show no evidence for a 22 hour periodicity in the X-ray intensity of X Per. These results indicate that the X-ray emission from X Per may be originating from a neutron star in a low density region far from the optically identified Be star.

  2. Microearthquake spectra from the Anza, California, seismic network: site response and source scaling

    USGS Publications Warehouse

    Frankel, Arthur D.; Wennerberg, Leif

    1989-01-01

    We analyzed spectra of local microearthquakes recorded by the Anza, California, seismic network to isolate the effects of site response and to investigate the scaling of source parameters for small earthquakes. Spectra of microearthquakes (M < 2; Mo< 1019 dyne-cm) at Anza have shapes characteristic of the receiver sites and are generally independent of the source region. Thus, the site response is a major conditioner of the observed spectral shape. To remove the effects of site response from the spectra of a M ∼ 3 event and isolate its source spectrum, we divided by the spectra of an adjacent aftershock used as an empirical Green's function event. The spectral ratios indicate that the apparent corner frequencies of small earthquakes (Mo < 1019dyne-cm) observed at even the high-fmax stations on hard rock are much lower than the source corner frequencies. The spectral ratios are consistent with stress drop remaining constant with decreasing seismic moment, for events with moments as small as 1018 dyne-cm. The spectral ratios display remarkable agreement between sites which showed vast differences in their original spectra, indicating that the spectral division effectively removed the site response. The source spectrum of the M ∼ 3 event has a high-frequency spectral fall-off of about ω−2. An apparent dependence of high-frequency fall-off with seismic moment in the original spectra can also be explained by the effects of site response. The difference between the P- and S-wave corner frequencies and high-frequency roll-offs in the observed spectra for these events is the result of the site response and is not a source property. The shapes of the spectra of microearthquakes at Anza can largely be explained by attenuation at shallow depth with a frequency-independent Q. For some sites, near-surface resonances are also apparent in the spectra of microearthquakes. It is indicated by t* values determined for each site that Qp ∼ Qsfor the shallow

  3. Chandra Observations of Associates of η Carinae. II. Spectra

    NASA Astrophysics Data System (ADS)

    Evans, Nancy Remage; Schlegel, Eric M.; Waldron, Wayne L.; Seward, Frederick D.; Krauss, Miriam I.; Nichols, Joy; Wolk, Scott J.

    2004-09-01

    The low-resolution X-ray spectra around η Car covering Trumpler 16 and part of Trumpler 14 have been extracted from a Chandra CCD ACIS image. Various analysis techniques have been applied to the spectra based on their count rates. The spectra with the greatest number of counts (HD 93162 = WR 25, HD 93129 AB, and HD 93250) have been fitted with a wind model, which uses several components with different temperatures and depths in the wind. Weaker spectra have been fitted with Raymond-Smith models. The weakest spectra are simply intercompared with strong spectra. In general, fits produce reasonable parameters based on knowledge of the extinction from optical studies and on the range of temperatures for high- and low-mass stars. Direct comparisons of spectra confirm the consistency of the fitting results and also hardness ratios for cases of unusually large extinction in the clusters. The spectra of the low-mass stars are harder than the more massive stars. Stars in the sequence evolving from the main sequence (HD 93250) through the system containing the O supergiant (HD 93129 AB) and then through the Wolf-Rayet stage (HD 93162), presumably ending in the extreme example of η Car, share the property of being unusually luminous and hard in X-rays. For these X-ray-luminous stars, their high mass and evolutionary status (from the very last stages of the main sequence and beyond) is the common feature. Their binary status is mixed, and their magnetic status is still uncertain. Based on observations made with the Chandra X-Ray Observatory.

  4. Low-frequency dielectric spectra of low-resistivity GaSe crystals (in Ukrainian)

    NASA Astrophysics Data System (ADS)

    Stakhira, J.; Fl'Unt, O.; Fiyala, Ya.

    The low-frequency dielectric response of low-resistivity GaSe layered crystal along the c-axis has been investigated at liquid nitrogen temperatures. The normalized spectra (activation energies from frequency shift is 0.19 eV) have been treated analytically employing equivalent circuits. It is shown that experimental data cannot be obtained with the circuit containing only ideal capacitors and resistors. At the same time, the equivalent circuit containing dispersive capacitors characterized by the power law dependence on frequency C^*=B(jω)^{n-1}, where ω is radian frequency, 0< n< 1, gives a good agreement with experimental data. This means that measured response of low-resistivity GaSe crystals follows the ``universal" power law of dielectric response χ^*˜(jω)^{n-1}, but not the Debye one. The nature of the ``universal" power law is explained by many-body interactions between localized charge carriers.

  5. Cleaning HI Spectra Contaminated by GPS RFI

    NASA Astrophysics Data System (ADS)

    Sylvia, Kamin; Hallenbeck, Gregory L.; Undergraduate ALFALFA Team

    2016-01-01

    The NUDET systems aboard GPS satellites utilize radio waves to communicate information regarding surface nuclear events. The system tests appear in spectra as RFI (radio frequency interference) at 1381MHz, which contaminates observations of extragalactic HI (atomic hydrogen) signals at 50-150 Mpc. Test durations last roughly 20-120 seconds and can occur upwards of 30 times during a single night of observing. The disruption essentially renders the corresponding HI spectra useless.We present a method that automatically removes RFI in HI spectra caused by these tests. By capitalizing on the GPS system's short test durations and predictable frequency appearance we are able to devise a method of identifying times containing compromised data records. By reevaluating the remaining data, we are able to recover clean spectra while sacrificing little in terms of sensitivity to extragalactic signals. This method has been tested on 500+ spectra taken by the Undergraduate ALFALFA Team (UAT), in which it successfully identified and removed all sources of GPS RFI. It will also be used to eliminate RFI in the upcoming Arecibo Pisces-Perseus Supercluster Survey (APPSS).This work has been supported by NSF grant AST-1211005.

  6. Partitioning Ocean Wave Spectra Obtained from Radar Observations

    NASA Astrophysics Data System (ADS)

    Delaye, Lauriane; Vergely, Jean-Luc; Hauser, Daniele; Guitton, Gilles; Mouche, Alexis; Tison, Celine

    2016-08-01

    2D wave spectra of ocean waves can be partitioned into several wave components to better characterize the scene. We present here two methods of component detection: one based on watershed algorithm and the other based on a Bayesian approach. We tested both methods on a set of simulated SWIM data, the Ku-band real aperture radar embarked on the CFOSAT (China- France Oceanography Satellite) mission which launch is planned mid-2018. We present the results and the limits of both approaches and show that Bayesian method can also be applied to other kind of wave spectra observations as those obtained with the radar KuROS, an airborne radar wave spectrometer.

  7. Rabi-Bloch oscillations in spatially distributed systems: Temporal dynamics and frequency spectra

    NASA Astrophysics Data System (ADS)

    Levie, Ilay; Kastner, Raphael; Slepyan, Gregory

    2017-10-01

    We consider one-dimensional chains of two-level quantum systems coupled via tunneling. The chain is driven by the superposition of dc and ac fields in the strong coupling regime. Based on the fundamental principles of electrodynamics and quantum theory, we have developed a generalized model of quantum dynamics for such interactions, free of rotating-wave approximation. The system of equations of motion was studied numerically. We analyzed the dynamics and spectra of the inversion density, dipole current density, and tunneling current density. In the case of resonant interaction with the ac component, the particle dynamics exhibits itself in the oscillatory regime, which may be interpreted as a combination of Rabi and Bloch oscillations with their strong mutual influence. Such scenario for an obliquely incident ac field dramatically differs from the individual picture of both types of oscillations due to the interactions. This effect is counterintuitive because of the existence of markedly different frequency ranges for such two types of oscillations. These dynamics manifest themselves in multiline spectra in different combinations of Rabi and Bloch frequencies. The effect is promising as a framework of a new type of spectroscopy in nanoelectronics and electrical control of nanodevices.

  8. Comparison of remotely sensed continental-shelf wave spectra with spectra computed by using a wave refraction computer model

    NASA Technical Reports Server (NTRS)

    Poole, L. R.

    1976-01-01

    An initial attempt was made to verify the Langley Research Center and Virginia Institute of Marine Science mid-Atlantic continental-shelf wave refraction model. The model was used to simulate refraction occurring during a continental-shelf remote sensing experiment conducted on August 17, 1973. Simulated wave spectra compared favorably, in a qualitative sense, with the experimental spectra. However, it was observed that most of the wave energy resided at frequencies higher than those for which refraction and shoaling effects were predicted, In addition, variations among the experimental spectra were so small that they were not considered statistically significant. In order to verify the refraction model, simulation must be performed in conjunction with a set of significantly varying spectra in which a considerable portion of the total energy resides at frequencies for which refraction and shoaling effects are likely.

  9. Wetting effect on optical sum frequency generation (SFG) spectra of D-glucose, D-fructose, and sucrose

    NASA Astrophysics Data System (ADS)

    Hieu, Hoang Chi; Li, Hongyan; Miyauchi, Yoshihiro; Mizutani, Goro; Fujita, Naoko; Nakamura, Yasunori

    2015-03-01

    We report a sum frequency generation (SFG) spectroscopy study of D-glucose, D-fructose and sucrose in the Csbnd H stretching vibration regime. Wetting effect on the SFG spectra was investigated. The SFG spectrum of D-glucose changed from that of α-D-glucose into those of α-D-glucose monohydrate by wetting. The SFG spectra showed evidence of a small change of β-D-fructopyranose into other anomers by wetting. SFG spectra of sucrose did not change by wetting. Assignments of the vibrational peaks in the SFG spectra of the three sugars in the dry and wet states were performed in the Csbnd H stretching vibration region near 3000 cm-1.

  10. Wetting effect on optical sum frequency generation (SFG) spectra of d-glucose, d-fructose, and sucrose.

    PubMed

    Hieu, Hoang Chi; Li, Hongyan; Miyauchi, Yoshihiro; Mizutani, Goro; Fujita, Naoko; Nakamura, Yasunori

    2015-03-05

    We report a sum frequency generation (SFG) spectroscopy study of d-glucose, d-fructose and sucrose in the CH stretching vibration regime. Wetting effect on the SFG spectra was investigated. The SFG spectrum of d-glucose changed from that of α-d-glucose into those of α-d-glucose monohydrate by wetting. The SFG spectra showed evidence of a small change of β-d-fructopyranose into other anomers by wetting. SFG spectra of sucrose did not change by wetting. Assignments of the vibrational peaks in the SFG spectra of the three sugars in the dry and wet states were performed in the CH stretching vibration region near 3000cm(-1). Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Moment-Tensor Spectra of Source Physics Experiments (SPE) Explosions in Granite

    NASA Astrophysics Data System (ADS)

    Yang, X.; Cleveland, M.

    2016-12-01

    We perform frequency-domain moment tensor inversions of Source Physics Experiments (SPE) explosions conducted in granite during Phase I of the experiment. We test the sensitivity of source moment-tensor spectra to factors such as the velocity model, selected dataset and smoothing and damping parameters used in the inversion to constrain the error bound of inverted source spectra. Using source moments and corner frequencies measured from inverted source spectra of these explosions, we develop a new explosion P-wave source model that better describes observed source spectra of these small and over-buried chemical explosions detonated in granite than classical explosion source models derived mainly from nuclear-explosion data. In addition to source moment and corner frequency, we analyze other features in the source spectra to investigate their physical causes.

  12. Synchrotron Spectra of Short-Period Pulsars

    NASA Astrophysics Data System (ADS)

    Malov, I. F.

    2001-02-01

    A model with synchrotron radiation near the light cylinder is proposed to explain the observed spectra of short-period pulsars (P≤0.1 s). These spectra can be described if a power-law energy distribution of the emitting electrons with exponent γ=2 8 is assumed. For most pulsars, the peak frequency νm is below 10 MHz. The νm(γ) dependence is derived, and shows that the peak frequencies for pulsars with spectral indices α<1.5 may fall in the observable range. In particular, νm may be νm ˜ 100 MHz for PSR J0751 + 1807 and PSR J1640 + 2224. The observed radio spectrum of Geminga (PSR J0633 + 1746) can be described by a synchrotron model with a monoenergetic or Maxwellian distribution of relativistic electrons and a small angle β between the spin axis and magnetic moment (β ˜ 10°).

  13. Low-Resolution Near-infrared Stellar Spectra Observed by the Cosmic Infrared Background Experiment (CIBER)

    NASA Astrophysics Data System (ADS)

    Kim, Min Gyu; Lee, Hyung Mok; Arai, Toshiaki; Bock, James; Cooray, Asantha; Jeong, Woong-Seob; Kim, Seong Jin; Korngut, Phillip; Lanz, Alicia; Lee, Dae Hee; Lee, Myung Gyoon; Matsumoto, Toshio; Matsuura, Shuji; Nam, Uk Won; Onishi, Yosuke; Shirahata, Mai; Smidt, Joseph; Tsumura, Kohji; Yamamura, Issei; Zemcov, Michael

    2017-02-01

    We present near-infrared (0.8-1.8 μm) spectra of 105 bright ({m}J < 10) stars observed with the low-resolution spectrometer on the rocket-borne Cosmic Infrared Background Experiment. As our observations are performed above the Earth's atmosphere, our spectra are free from telluric contamination, which makes them a unique resource for near-infrared spectral calibration. Two-Micron All-Sky Survey photometry information is used to identify cross-matched stars after reduction and extraction of the spectra. We identify the spectral types of the observed stars by comparing them with spectral templates from the Infrared Telescope Facility library. All the observed spectra are consistent with late F to M stellar spectral types, and we identify various infrared absorption lines.

  14. Audible thunder characteristic and the relation between peak frequency and lightning parameters

    NASA Astrophysics Data System (ADS)

    Yuhua, Ouyang; Ping, Yuan

    2012-02-01

    In recent summers, some natural lightning optical spectra and audible thunder signals were observed. Twelve events on 15 August 2008 are selected as samples since some synchronizing information about them are obtained, such as lightning optical spectra, surface E-field changes, etc. By using digital filter and Fourier transform, thunder frequency spectra in observation location have been calculated. Then the two main propagation effects, finite amplitude propagation and attenuation by air, are calculated. Upon that we take the test thunder frequency spectra and work backward to recalculate the original frequency spectra near generation location. Thunder frequency spectra and the frequency distribution varying with distance are researched. According to the theories on plasma, the channel temperature and electron density are further calculated by transition parameters of lines in lightning optical spectra. Pressure and the average ionization degree of each discharge channel are obtained by using Saha equations, charge conservation equations and particle conservation equations. Moreover, the relationship between the peak frequency of each thunder and channel parameters of the lightning is studied.

  15. Very low H O H bending frequencies. IV. Fourier transform infrared spectra of synthetic dittmarite

    NASA Astrophysics Data System (ADS)

    Šoptrajanov, Bojan; Stefov, Viktor; Kuzmanovski, Igor; Jovanovski, Gligor; Lutz, H. Dieter; Engelen, Bernward

    2002-08-01

    The Fourier transform infrared spectra of MgNH 4PO 4·H 2O (the synthetic analogue of the mineral dittmarite) and of a series of its partially deuterated analogues have been studied as a part of our continuous work on compounds exhibiting very low water bending frequencies. Although, the presence of ammonium bands makes the assignments in this case more difficult than for the potassium analogues, the isomorphism between the compounds of the MNH 4PO 4·H 2O type (M=Mg, Co, Ni, Mn and one of the polymorphs of CdNH 4PO 4·H 2O) and those which contain potassium instead of ammonium as well as the careful analysis of the spectra warrant the conclusion that in the presently studied compound the water bending mode appears at a frequency which is far more than 100 cm -1 lower than in the gaseous water. The spectra clearly show that the ammonium ions in the structure are involved in quite strong hydrogen bonds, a characteristic which is a precondition for a material to behave as a protonic conductor.

  16. Solvent effect on the vibrational spectra of Carvedilol.

    PubMed

    Billes, Ferenc; Pataki, Hajnalka; Unsalan, Ozan; Mikosch, Hans; Vajna, Balázs; Marosi, György

    2012-09-01

    Carvedilol (CRV) is an important medicament for heart arrhythmia. The aim of this work was the interpretation of its vibrational spectra with consideration on the solvent effect. Infrared and Raman spectra were recorded in solid state as well in solution. The experimental spectra were evaluated using DFT quantum chemical calculations computing the optimized structure, atomic net charges, vibrational frequencies and force constants. The same calculations were done for the molecule in DMSO and aqueous solutions applying the PCM method. The calculated force constants were scaled to the experimentally observed solid state frequencies. The characters of the vibrational modes were determined by their potential energy distributions. Solvent effects on the molecular properties were interpreted. Based on these results vibrational spectra were simulated. Copyright © 2012 Elsevier B.V. All rights reserved.

  17. Acceleration spectra for subduction zone earthquakes

    USGS Publications Warehouse

    Boatwright, J.; Choy, G.L.

    1989-01-01

    We estimate the source spectra of shallow earthquakes from digital recordings of teleseismic P wave groups, that is, P+pP+sP, by making frequency dependent corrections for the attenuation and for the interference of the free surface. The correction for the interference of the free surface assumes that the earthquake radiates energy from a range of depths. We apply this spectral analysis to a set of 12 subduction zone earthquakes which range in size from Ms = 6.2 to 8.1, obtaining corrected P wave acceleration spectra on the frequency band from 0.01 to 2.0 Hz. Seismic moment estimates from surface waves and normal modes are used to extend these P wave spectra to the frequency band from 0.001 to 0.01 Hz. The acceleration spectra of large subduction zone earthquakes, that is, earthquakes whose seismic moments are greater than 1027 dyn cm, exhibit intermediate slopes where u(w)???w5/4 for frequencies from 0.005 to 0.05 Hz. For these earthquakes, spectral shape appears to be a discontinuous function of seismic moment. Using reasonable assumptions for the phase characteristics, we transform the spectral shape observed for large earthquakes into the time domain to fit Ekstrom's (1987) moment rate functions for the Ms=8.1 Michoacan earthquake of September 19, 1985, and the Ms=7.6 Michoacan aftershock of September 21, 1985. -from Authors

  18. Frequency spectra from current vs. magnetic flux density measurements for mobile phones and other electrical appliances.

    PubMed

    Straume, Aksel; Johnsson, Anders; Oftedal, Gunnhild; Wilén, Jonna

    2007-10-01

    The frequency spectra of electromagnetic fields have to be determined to evaluate human exposure in accordance to ICNIRP guidelines. In the literature, comparisons with magnetic field guidelines have been performed by using the frequency distribution of the current drawn from the battery. In the present study we compared the frequency spectrum in the range 217 Hz to 2.4 kHz of the magnetic flux density measured near the surface of a mobile phone with the frequency spectrum of the supply current. By using the multiple frequency rule, recommended in the ICNIRP guidelines, we estimated the magnetic field exposure in the two cases. Similar measurements and estimations were done for an electric drill, a hair dryer, and a fluorescent desk lamp. All the devices have a basic frequency of 50 Hz, and the frequency spectra were evaluated up to 550 Hz. We also mapped the magnetic field in 3D around three mobile phones. The frequency distributions obtained from the two measurement methods are not equal. The frequency content of the current leads to an overestimation of the magnetic field exposure by a factor up to 2.2 for the mobile phone. For the drill, the hair dryer, and the fluorescent lamp, the supply current signal underestimated the exposure by a factor up to 2.3. In conclusion, an accurate exposure evaluation requires the magnetic flux density spectrum of the device to be measured directly. There was no indication that the devices studied would exceed the reference levels at the working distances normally used.

  19. First Measurements of High Frequency Cross-Spectra from a Pair of Large Michelson Interferometers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chou, Aaron S.; Gustafson, Richard; Hogan, Craig

    Measurements are reported of high frequency cross-spectra of signals from the Fermilab Holometer, a pair of co-located 39 m, high power Michelson interferometers. The instrument obtains differential position sensitivity to cross-correlated signals far exceeding any previous measurement in a broad frequency band extending to the 3.8 MHz inverse light crossing time of the apparatus. A model of universal exotic spatial shear correlations that matches the Planck scale holographic information bound of space-time position states is excluded to 4.6{\\sigma} significance.

  20. Characteristics of magnetospheric radio noise spectra

    NASA Technical Reports Server (NTRS)

    Herman, J. R.

    1976-01-01

    Magnetospheric radio noise spectra (30 kHz to 10 MHz) taken by IMP-6 and RAE-2 exhibit time-varying characteristics which are related to spacecraft position and magnetospheric processes. In the mid-frequency range (100-1,000 kHz) intense noise peaks rise by a factor of 100 or more above background; 80% of the peak frequencies are within the band 125 kHz to 600 kHz, and the peak occurs most often (18% of the time) at 280 kHz. This intense mid-frequency noise has been detected at radial distances from 1.3 Re to 60 Re on all sides of the Earth during magnetically quiet as well as disturbed periods. Maximum occurrence of the mid-frequency noise is in the evening to midnight hours where splash-type energetic particle precipitation takes place. ""Magnetospheric lightning'' can be invoked to explain the spectral shape of the observed spectra.

  1. Wave-field decay rate estimate from the wavenumber-frequency spectra

    NASA Astrophysics Data System (ADS)

    Comisel, H.; Narita, Y.; Voros, Z.

    2017-12-01

    Observational data for wave or turbulent fields are conveniently analyzed and interpreted in the Fourier domain spanning the frequencies and the wavenumbers. If a wave field has not only oscillatory components (characterized by real parts of frequency) but also temporally decaying components (characterized by imaginary parts of frequency), the energy spectrum shows a frequency broadening around the peak due to the imaginary parts of frequency (or the decay rate). The mechanism of the frequency broadening is the same as that of the Breit-Wigner spectrum in nuclear resonance phenomena. We show that the decay rate can observationally and directly be estimated once multi-point data are available, and apply the method to Cluster four-point magnetometer data in the solar wind on a spatial scale of about 1000 km. The estimated decay rate is larger than the eddy turnover time, indicating that the decay profile of solar wind turbulence is more plasma physical such as excitation of whistler waves and other modes rather than hydrodynamic turbulence behavior.

  2. Analytic calculations of anharmonic infrared and Raman vibrational spectra

    PubMed Central

    Louant, Orian; Ruud, Kenneth

    2016-01-01

    Using a recently developed recursive scheme for the calculation of high-order geometric derivatives of frequency-dependent molecular properties [Ringholm et al., J. Comp. Chem., 2014, 35, 622], we present the first analytic calculations of anharmonic infrared (IR) and Raman spectra including anharmonicity both in the vibrational frequencies and in the IR and Raman intensities. In the case of anharmonic corrections to the Raman intensities, this involves the calculation of fifth-order energy derivatives—that is, the third-order geometric derivatives of the frequency-dependent polarizability. The approach is applicable to both Hartree–Fock and Kohn–Sham density functional theory. Using generalized vibrational perturbation theory to second order, we have calculated the anharmonic infrared and Raman spectra of the non- and partially deuterated isotopomers of nitromethane, where the inclusion of anharmonic effects introduces combination and overtone bands that are observed in the experimental spectra. For the major features of the spectra, the inclusion of anharmonicities in the calculation of the vibrational frequencies is more important than anharmonic effects in the calculated infrared and Raman intensities. Using methanimine as a trial system, we demonstrate that the analytic approach avoids errors in the calculated spectra that may arise if numerical differentiation schemes are used. PMID:26784673

  3. Retrieval of complex χ(2) parts for quantitative analysis of sum-frequency generation intensity spectra

    PubMed Central

    Hofmann, Matthias J.; Koelsch, Patrick

    2015-01-01

    Vibrational sum-frequency generation (SFG) spectroscopy has become an established technique for in situ surface analysis. While spectral recording procedures and hardware have been optimized, unique data analysis routines have yet to be established. The SFG intensity is related to probing geometries and properties of the system under investigation such as the absolute square of the second-order susceptibility χ(2)2. A conventional SFG intensity measurement does not grant access to the complex parts of χ(2) unless further assumptions have been made. It is therefore difficult, sometimes impossible, to establish a unique fitting solution for SFG intensity spectra. Recently, interferometric phase-sensitive SFG or heterodyne detection methods have been introduced to measure real and imaginary parts of χ(2) experimentally. Here, we demonstrate that iterative phase-matching between complex spectra retrieved from maximum entropy method analysis and fitting of intensity SFG spectra (iMEMfit) leads to a unique solution for the complex parts of χ(2) and enables quantitative analysis of SFG intensity spectra. A comparison between complex parts retrieved by iMEMfit applied to intensity spectra and phase sensitive experimental data shows excellent agreement between the two methods. PMID:26450297

  4. Vibrational spectroscopy of water in hydrated lipid multi-bilayers. I. Infrared spectra and ultrafast pump-probe observables.

    PubMed

    Gruenbaum, S M; Skinner, J L

    2011-08-21

    The vibrational spectroscopy of hydration water in dilauroylphosphatidylcholine lipid multi-bilayers is investigated using molecular dynamics simulations and a mixed quantum/classical model for the OD stretch spectroscopy of dilute HDO in H(2)O. FTIR absorption spectra, and isotropic and anisotropic pump-probe decay curves have been measured experimentally as a function of the hydration level of the lipid multi-bilayer, and our goal is to make connection with these experiments. To this end, we use third-order response functions, which allow us to include non-Gaussian frequency fluctuations, non-Condon effects, molecular rotations, and a fluctuating vibrational lifetime, all of which we believe are important for this system. We calculate the response functions using existing transition frequency and dipole maps. From the experiments it appears that there are two distinct vibrational lifetimes corresponding to HDO molecules in different molecular environments. In order to obtain these lifetimes, we consider a simple two-population model for hydration water hydrogen bonds. Assuming a different lifetime for each population, we then calculate the isotropic pump-probe decay, fitting to experiment to obtain the two lifetimes for each hydration level. With these lifetimes in hand, we then calculate FTIR spectra and pump-probe anisotropy decay as a function of hydration. This approach, therefore, permits a consistent calculation of all observables within a unified computational scheme. Our theoretical results are all in qualitative agreement with experiment. The vibrational lifetime of lipid-associated OD groups is found to be systematically shorter than that of the water-associated population, and the lifetimes of each population increase with decreasing hydration, in agreement with previous analysis. Our theoretical FTIR absorption spectra successfully reproduce the experimentally observed red-shift with decreasing lipid hydration, and we confirm a previous interpretation

  5. Vibrational spectroscopy of water in hydrated lipid multi-bilayers. I. Infrared spectra and ultrafast pump-probe observables

    PubMed Central

    Gruenbaum, S. M.; Skinner, J. L.

    2011-01-01

    The vibrational spectroscopy of hydration water in dilauroylphosphatidylcholine lipid multi-bilayers is investigated using molecular dynamics simulations and a mixed quantum∕classical model for the OD stretch spectroscopy of dilute HDO in H2O. FTIR absorption spectra, and isotropic and anisotropic pump-probe decay curves have been measured experimentally as a function of the hydration level of the lipid multi-bilayer, and our goal is to make connection with these experiments. To this end, we use third-order response functions, which allow us to include non-Gaussian frequency fluctuations, non-Condon effects, molecular rotations, and a fluctuating vibrational lifetime, all of which we believe are important for this system. We calculate the response functions using existing transition frequency and dipole maps. From the experiments it appears that there are two distinct vibrational lifetimes corresponding to HDO molecules in different molecular environments. In order to obtain these lifetimes, we consider a simple two-population model for hydration water hydrogen bonds. Assuming a different lifetime for each population, we then calculate the isotropic pump-probe decay, fitting to experiment to obtain the two lifetimes for each hydration level. With these lifetimes in hand, we then calculate FTIR spectra and pump-probe anisotropy decay as a function of hydration. This approach, therefore, permits a consistent calculation of all observables within a unified computational scheme. Our theoretical results are all in qualitative agreement with experiment. The vibrational lifetime of lipid-associated OD groups is found to be systematically shorter than that of the water-associated population, and the lifetimes of each population increase with decreasing hydration, in agreement with previous analysis. Our theoretical FTIR absorption spectra successfully reproduce the experimentally observed red-shift with decreasing lipid hydration, and we confirm a previous interpretation

  6. Structures, vibrational frequencies, and infrared spectra of the hexa-hydrated benzene clusters

    NASA Astrophysics Data System (ADS)

    Lee, Jin Yong; Kim, Jongseob; Lee, Han Myoung; Tarakeshwar, P.; Kim, Kwang S.

    2000-10-01

    The water hexamer is known to have a number of isoenergetic structures. The first experimental identification of the O-H stretching vibrational spectra of the water hexamer was done in the presence of benzene. It was followed by the identification of the pure water hexamer structure by vibration-rotational tunneling (VRT) spectroscopy. Although both experiments seem to have located only the Cage structure, the structure of the benzene-water hexamer complex is not clearly known, and the effect of benzene in the water hexamer is unclear. In particular, it is not obvious how the energy difference between nearly isoenergetic water hexamer conformers changes in the presence of benzene. Thus, we have compared the benzene complexes with four low-lying isoenergetic water hexamers, Ring, Book, Cage, and Prism structures, using ab initio calculations. We also investigated the effects of the presence of benzene on the structures, harmonic vibrational frequencies, and infrared (IR) intensities for the four low-lying energy conformers. There is little change in the structure of the water hexamer upon its interaction with the benzene molecule. Hence the deformation energies are very small. The dominant contribution to the benzene-water cluster interaction mainly comes from the π-H interactions between benzene and a single water molecule. As a result of this π-H interaction, O-Hπ bond length increases and the corresponding stretching vibrational frequencies are redshifted. The IR spectral features of both (H2O)6 and benzene-(H2O)6 are quite similar. From both the energetics and the comparison of calculated and experimental spectra of the benzene-(H2O)6, the water structure in these complexes is found to have the Cage form. In particular, among the four different Cage structures, only one conformer matches the experimental O-H vibrational frequencies.

  7. High-Frequency Observation of Water Spectrum and Its Application in Monitoring of Dynamic Variation of Suspended Materials in the Hangzhou Bay.

    PubMed

    Dai, Qian; Pan, De-lu; He, Xian-qiang; Zhu, Qian-kun; Gong, Fang; Huang, Hai-qing

    2015-11-01

    In situ measurement of water spectrum is the basis of the validation of the ocean color remote sensing. The traditional method to obtain the water spectrum is based on the shipboard measurement at limited stations, which is difficult to meet the requirement of validation of ocean color remote sensing in the highly dynamic coastal waters. To overcome this shortage, continuously observing systems of water spectrum have been developed in the world. However, so far, there are still few high-frequency observation systems of the water spectrum in coastal waters, especially in the highly turbid and high-dynamic waters. Here, we established a high-frequency water-spectrum observing system based on tower in the Hangzhou Bay. The system measures the water spectrum at a step of 3 minutes, which can fully match the satellite observation. In this paper, we primarily developed a data processing method for the tower-based high-frequency water spectrum data, to realize automatic judgment of clear sky, sun glint, platform shadow, and weak illumination, etc. , and verified the processing results. The results show that the normalized water-leaving radiance spectra obtained through tower observation have relatively high consistency with the shipboard measurement results, with correlation coefficient of more than 0. 99, and average relative error of 9.96%. In addition, the long-term observation capability of the tower-based high-frequency water-spectrum observing system was evaluated, and the results show that although the system has run for one year, the normalized water-leaving radiance obtained by this system have good consistency with the synchronously measurement by Portable spectrometer ASD in respect of spectral shape and value, with correlation coefficient of more than 0.90 and average relative error of 6.48%. Moreover, the water spectra from high-frequency observation by the system can be used to effectively monitor the rapid dynamic variation in concentration of suspended

  8. An improved dual-frequency technique for the remote sensing of ocean currents and wave spectra

    NASA Technical Reports Server (NTRS)

    Schuler, D. L.; Eng, W. P.

    1984-01-01

    A two frequency microwave radar technique for the remote sensing of directional ocean wave spectra and surface currents is investigated. This technique is conceptually attractive because its operational physical principle involves a spatial electromagnetic scattering resonance with a single, but selectable, long gravity wave. Multiplexing of signals having different spacing of the two transmitted frequencies allows measurements of the entire long wave ocean spectrum to be carried out. A new scatterometer is developed and experimentally tested which is capable of making measurements having much larger signal/background values than previously possible. This instrument couples the resonance technique with coherent, frequency agility radar capabilities. This scatterometer is presently configured for supporting a program of surface current measurements.

  9. Structures and vibrational spectra of pinacol.. 1. Infrared and matrix infrared spectra of monomeric pinacol. Ab initio calculations on conformers and vibrational frequencies

    NASA Astrophysics Data System (ADS)

    Dahlqvist, Martti; Hotokka, Matti; Räsänen, Markku

    1998-04-01

    The infrared spectra of monomeric pinacol molecules (2,3-dimethyl-2,3-butanediol; (CH 3) 2C(OH)C(OH)(CH 3) 2) have been recorded in the gas phase and dilute nonpolar solutions, and in an argon matrix. The vibrational data are consistent with the intramolecularly hydrogen-bonded G-type (gauche with respect to the central C-C bond) conformers and there is no evidence for the T-type (trans with respect to the central C-C bond) conformers, which have been observed in the condensed phases. This was confirmed by studying the infrared region 835-815 cm -1, which was found to be the most indicative to show spectral changes within the type of the conformers. In this region the band of the T-type conformers (assigned to the hybridized asymmetric vibration of the central CC and CO stretching modes) disappears when going from the condensed phases to phases, where pinacol molecules are monomeric. Ab initio HF/6-311G** (MP2/6-311G**) calculations support the experimental findings; the calculated relative energies for the tGg', gGg', g'Gg', tTt, and gTg' conformers are 0.0 (0.0), 3.4 (3.4), 5.1 (5.9), 7.9 (11.3), and 12.0 (14.0) kJ mol -1, respectively. Consequently, only the G-type conformers are sufficiently populated to give rise to observable spectral lines. Both experimental findings and theoretical calculations demonstrated that the bands in the argon matrix spectrum of pinacol are due to the most stable tGg' conformer. Although the ab initio calculations predict that also the gGg' and g'Gg' conformers are present in the gas phase and in dilute nonpolar solutions their existence could not be confirmed experimentally. Hence, we conclude that the conformation sensitive bands may coincide in the spectra. The HF/6-311G** ab initio calculations for vibrational frequencies of pinacol are consistent with this conclusion, suggesting only small differences between the wavenumbers of the G-type conformers. Pinacol does not show infrared-induced photorotamerization in the low

  10. Radial evolution of power spectra of interplanetary Alfvenic turbulence

    NASA Technical Reports Server (NTRS)

    Bavassano, B.; Dobrowolny, M.; Mariani, F.; Ness, N. F.

    1981-01-01

    The radial evolution of the power spectra of the MHD turbulence within the trailing edge of high speed streams in the solar wind was investigated with the magnetic field data of Helios 1 and 2 for heliocentric distance between 0.3 and 0.9 AU. In the analyzed frequency range (.00028 Hz to .0083 Hz) the computed spectra have, near the Earth, values of the spectral index close to that predicted for an incompressible hydromagnetic turbulence in a stationary state. Approaching the Sun the spectral slope remains unchanged for frequencies f or approximately .00 Hz, whereas at lower frequencies, a clear evolution toward a less steep fall off with frequency is found. The radial gradient of the power in Alfvenic fluctuations depends on frequency and it increases upon increasing frequency. For frequencies f or approximately .00 Hz, however, the radial gradient remains approximately the same. Possible theoretical implications of the observational features are discussed.

  11. Gigahertz-peaked Spectra Pulsars and Thermal Absorption Model

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kijak, J.; Basu, R.; Lewandowski, W.

    2017-05-10

    We present the results of our radio interferometric observations of pulsars at 325 and 610 MHz using the Giant Metrewave Radio Telescope. We used the imaging method to estimate the flux densities of several pulsars at these radio frequencies. The analysis of the shapes of the pulsar spectra allowed us to identify five new gigahertz-peaked spectra (GPS) pulsars. Using the hypothesis that the spectral turnovers are caused by thermal free–free absorption in the interstellar medium, we modeled the spectra of all known objects of this kind. Using the model, we were able to put some observational constraints on the physicalmore » parameters of the absorbing matter, which allows us to distinguish between the possible sources of absorption. We also discuss the possible effects of the existence of GPS pulsars on future search surveys, showing that the optimal frequency range for finding such objects would be from a few GHz (for regular GPS sources) to possibly 10 GHz for pulsars and radio magnetars exhibiting very strong absorption.« less

  12. First measurements of high frequency cross-spectra from a pair of large Michelson interferometers

    DOE PAGES

    Chou, Aaron S.; Gustafson, Richard; Hogan, Craig; ...

    2016-09-09

    Here, measurements are reported of the cross-correlation of spectra of differential position signals from the Fermilab Holometer, a pair of colocated 39 m long, high power Michelson interferometers with flat broadband frequency response in the MHz range. The instrument obtains sensitivity to high frequency correlated signals far exceeding any previous measurement in a broad frequency band extending beyond the 3.8 MHz inverse light-crossing time of the apparatus. The dominant but uncorrelated shot noise is averaged down over 2 × 10 8 independent spectral measurements with 381 Hz frequency resolution to obtain 2.1 × 10 -20m/ √Hz sensitivity to stationary signals. For signal bandwidthsmore » Δf > 11 kHz, the sensitivity to strain h or shear power spectral density of classical or exotic origin surpasses a milestone PSD δh < t p where t p = 5.39 × 10 -44/ Hz is the Planck time.« less

  13. First Measurements of High Frequency Cross-Spectra from a Pair of Large Michelson Interferometers.

    PubMed

    Chou, Aaron S; Gustafson, Richard; Hogan, Craig; Kamai, Brittany; Kwon, Ohkyung; Lanza, Robert; McCuller, Lee; Meyer, Stephan S; Richardson, Jonathan; Stoughton, Chris; Tomlin, Raymond; Waldman, Samuel; Weiss, Rainer

    2016-09-09

    Measurements are reported of the cross-correlation of spectra of differential position signals from the Fermilab Holometer, a pair of colocated 39 m long, high power Michelson interferometers with flat broadband frequency response in the MHz range. The instrument obtains sensitivity to high frequency correlated signals far exceeding any previous measurement in a broad frequency band extending beyond the 3.8 MHz inverse light-crossing time of the apparatus. The dominant but uncorrelated shot noise is averaged down over 2×10^{8} independent spectral measurements with 381 Hz frequency resolution to obtain 2.1×10^{-20}m/sqrt[Hz] sensitivity to stationary signals. For signal bandwidths Δf>11  kHz, the sensitivity to strain h or shear power spectral density of classical or exotic origin surpasses a milestone PSD_{δh}

  14. Directional spectra of hurricane-generated waves in the Gulf of Mexico

    NASA Astrophysics Data System (ADS)

    Hu, Kelin; Chen, Qin

    2011-10-01

    Hurricane-induced directional wave spectra in the Gulf of Mexico are investigated based on the measurements collected at 12 buoys during 7 hurricane events in recent years. Focusing on hurricane-generated wave spectra, we only consider the wave measurements at the buoys within eight times the radius of the hurricane maximum wind speed (Rmax) from the hurricane center. A series of numerical experiments using a third-generation spectral wave prediction model were carried out to gain insight into the mechanism controlling the directional and frequency distributions of hurricane wave energy. It is found that hurricane wave spectra are almost swell-dominated except for the right-rear quadrant of a hurricane with respect to the forward direction, where the local strong winds control the spectra. Despite the complexity of a hurricane wind field, most of the spectra are mono-modal, similar to those under fetch-limited, unidirectional winds. However, bi-modal spectra were also found in both measurements and model results. Four types of bi-modal spectra have been observed. Type I happens far away (>6 × Rmax) from a hurricane. Type II is bi-modal in frequency with significant differences in direction. It happens in the two left quadrants when the direction of hurricane winds deviates considerably from the swell direction. Type III is bi-modal in frequency in almost the same wave direction with two close peaks. It occurs when the energy of locally-generated wind-sea is only partially transferred to the swell energy by non-linear wave-wave interactions. Type IV was observed in shallow waters owing to coastal effects.

  15. Ultraviolet Spectra of Comets Observed with the International Ultraviolet Explorer Satellite Observatory.

    NASA Astrophysics Data System (ADS)

    Weaver, Harold Anthony, Jr.

    Ultraviolet spectra of seven comets observed with the International Ultraviolet Explorer (IUE) satellite are presented. Observations of comet Bradfield (1979 X) made in early 1980 allow a comprehensive study of the production of water by this comet. By comparing the observations to the predictions of two water models of the coma (Haser and vectorial), it is determined that these measurements support the idea of a comet composed principally of water ice. The vaporization of the water has a rather unexpected heliocentric variation, decreasing as r('-3.7) over the entire range of observations. Atomic carbon is relatively abundant in the coma of comet Bradfield; the production rate of carbon is roughly 5-10% of the water production rate. Analysis of the spatial brightness profiles of the strongest atomic carbon emission does not reveal the identity of the source of the observed carbon, but the data are apparently inconsistent with a photodissociation source that is either CO or CO(,2). A comparison of the ultraviolet spectrum of periodic comet Encke, recorded by the IUE between 1980 October 24 and November 5, with similar spectra of short and long period comets shows the gaseous composition of P/Encke to be virtually identical to that of the other comets. If P/Encke is indeed the remains of a once giant comet, this similarity implies a homogeneous structure for the cometary ice nucleus. The OH(0,0) band brightness distribution shows a spatial variation similar to the visible fan-shaped image of the comet. Comets P/Tuttle (1980h), P/Stephan-Oterma (1980g), and Meier (1980q) were observed during November-December 1980 with IUE, while comets P/Borrelly (1980i) and Panther (1980u) were observed with IUE on 6 March 1981. The spectra of these comets are compared with those of comets Bradfield (1979 X) and P/Encke, as well as with each other. In order to simplify the interpretation of the data and to minimize the dependence upon a specific model, the spectra are compared at

  16. Temperature Dependence of Low-Frequency Spectra in Molten Bis(trifluoromethylsulfonyl)amide Salts of Imidazolium Cations Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy.

    PubMed

    Shirota, Hideaki; Kakinuma, Shohei

    2015-07-30

    In this study, the temperature dependence of the low-frequency spectra of liquid bis(trifluoromethylsulfonyl)amide salts of the monocations 1-methyl-3-propylimidazolium and 1-hexyl-3-methylimidazolium and the dications 1,6-bis(3-methylimidazolium-1-yl)hexane and 1,12-bis(3-methylimidazolium-1-yl)dodecane has been investigated by means of femtosecond optical heterodyne-detected Raman-induced Kerr effect spectroscopy. The intensity in the low-frequency region below 20 cm(-1) in the spectra of the four ionic liquids increases with rising temperature. From a line-shape analysis of the broadened low-frequency spectra of the ionic liquids, it is clear that the lowest-frequency component, which peaks at approximately 5 cm(-1), contributes to the temperature dependence of the spectra. This implies that the activity of the intermolecular translational vibrational motion is increasing with rising temperature. It is also possible that decoupling in the crossover process between intermolecular vibrational motion and structural relaxation occurs as a result of a deterioration of the non-Markovian feature or the loss of memory caused by the higher temperature. The peak of the highest-frequency component, which is due mainly to the imidazolium ring libration, shifts to lower frequency with increasing temperature. This is attributed to weaker interactions of the ionic liquids at higher temperatures. Temperature-dependent viscosities from 293 to 353 K of the four ionic liquids have also been characterized.

  17. Difference optimization: Automatic correction of relative frequency and phase for mean non-edited and edited GABA 1H MEGA-PRESS spectra

    NASA Astrophysics Data System (ADS)

    Cleve, Marianne; Krämer, Martin; Gussew, Alexander; Reichenbach, Jürgen R.

    2017-06-01

    Phase and frequency corrections of magnetic resonance spectroscopic data are of major importance to obtain reliable and unambiguous metabolite estimates as validated in recent research for single-shot scans with the same spectral fingerprint. However, when using the J-difference editing technique 1H MEGA-PRESS, misalignment between mean edited (ON ‾) and non-edited (OFF ‾) spectra that may remain even after correction of the corresponding individual single-shot scans results in subtraction artefacts compromising reliable GABA quantitation. We present a fully automatic routine that iteratively optimizes simultaneously relative frequencies and phases between the mean ON ‾ and OFF ‾ 1H MEGA-PRESS spectra while minimizing the sum of the magnitude of the difference spectrum (L1 norm). The proposed method was applied to simulated spectra at different SNR levels with deliberately preset frequency and phase errors. Difference optimization proved to be more sensitive to small signal fluctuations, as e.g. arising from subtraction artefacts, and outperformed the alternative spectral registration approach, that, in contrast to our proposed linear approach, uses a nonlinear least squares minimization (L2 norm), at all investigated levels of SNR. Moreover, the proposed method was applied to 47 MEGA-PRESS datasets acquired in vivo at 3 T. The results of the alignment between the mean OFF ‾ and ON ‾ spectra were compared by applying (a) no correction, (b) difference optimization or (c) spectral registration. Since the true frequency and phase errors are not known for in vivo data, manually corrected spectra were used as the gold standard reference (d). Automatically corrected data applying both, method (b) or method (c), showed distinct improvements of spectra quality as revealed by the mean Pearson correlation coefficient between corresponding real part mean DIFF ‾ spectra of Rbd = 0.997 ± 0.003 (method (b) vs. (d)), compared to Rad = 0.764 ± 0.220 (method (a) vs

  18. Difference optimization: Automatic correction of relative frequency and phase for mean non-edited and edited GABA 1H MEGA-PRESS spectra.

    PubMed

    Cleve, Marianne; Krämer, Martin; Gussew, Alexander; Reichenbach, Jürgen R

    2017-06-01

    Phase and frequency corrections of magnetic resonance spectroscopic data are of major importance to obtain reliable and unambiguous metabolite estimates as validated in recent research for single-shot scans with the same spectral fingerprint. However, when using the J-difference editing technique 1 H MEGA-PRESS, misalignment between mean edited (ON‾) and non-edited (OFF‾) spectra that may remain even after correction of the corresponding individual single-shot scans results in subtraction artefacts compromising reliable GABA quantitation. We present a fully automatic routine that iteratively optimizes simultaneously relative frequencies and phases between the mean ON‾ and OFF‾ 1 H MEGA-PRESS spectra while minimizing the sum of the magnitude of the difference spectrum (L 1 norm). The proposed method was applied to simulated spectra at different SNR levels with deliberately preset frequency and phase errors. Difference optimization proved to be more sensitive to small signal fluctuations, as e.g. arising from subtraction artefacts, and outperformed the alternative spectral registration approach, that, in contrast to our proposed linear approach, uses a nonlinear least squares minimization (L 2 norm), at all investigated levels of SNR. Moreover, the proposed method was applied to 47 MEGA-PRESS datasets acquired in vivo at 3T. The results of the alignment between the mean OFF‾ and ON‾ spectra were compared by applying (a) no correction, (b) difference optimization or (c) spectral registration. Since the true frequency and phase errors are not known for in vivo data, manually corrected spectra were used as the gold standard reference (d). Automatically corrected data applying both, method (b) or method (c), showed distinct improvements of spectra quality as revealed by the mean Pearson correlation coefficient between corresponding real part mean DIFF‾ spectra of R bd =0.997±0.003 (method (b) vs. (d)), compared to R ad =0.764±0.220 (method (a) vs. (d

  19. Inductive phenomena at low frequencies in impedance spectra of proton exchange membrane fuel cells - A review

    NASA Astrophysics Data System (ADS)

    Pivac, Ivan; Barbir, Frano

    2016-09-01

    The results of electrochemical impedance spectroscopy of proton exchange membrane (PEM) fuel cells may exhibit inductive phenomena at low frequencies. The occurrence of inductive features at high frequencies is explained by the cables and wires of the test system. However, explanation of inductive loop at low frequencies requires a more detailed study. This review paper discusses several possible causes of such inductive behavior in PEM fuel cells, such as side reactions with intermediate species, carbon monoxide poisoning, and water transport, also as their equivalent circuit representations. It may be concluded that interpretation of impedance spectra at low frequencies is still ambiguous, and that better equivalent circuit models are needed with clearly defined physical meaning of each of the circuit elements.

  20. Observation of beat oscillation generation by coupled waves associated with parametric decay during radio frequency wave heating of a spherical tokamak plasma.

    PubMed

    Nagashima, Yoshihiko; Oosako, Takuya; Takase, Yuichi; Ejiri, Akira; Watanabe, Osamu; Kobayashi, Hiroaki; Adachi, Yuuki; Tojo, Hiroshi; Yamaguchi, Takashi; Kurashina, Hiroki; Yamada, Kotaro; An, Byung Il; Kasahara, Hiroshi; Shimpo, Fujio; Kumazawa, Ryuhei; Hayashi, Hiroyuki; Matsuzawa, Haduki; Hiratsuka, Junichi; Hanashima, Kentaro; Kakuda, Hidetoshi; Sakamoto, Takuya; Wakatsuki, Takuma

    2010-06-18

    We present an observation of beat oscillation generation by coupled modes associated with parametric decay instability (PDI) during radio frequency (rf) wave heating experiments on the Tokyo Spherical Tokamak-2. Nearly identical PDI spectra, which are characterized by the coexistence of the rf pump wave, the lower-sideband wave, and the low-frequency oscillation in the ion-cyclotron range of frequency, are observed at various locations in the edge plasma. A bispectral power analysis was used to experimentally discriminate beat oscillation from the resonant mode for the first time. The pump and lower-sideband waves have resonant mode components, while the low-frequency oscillation is exclusively excited by nonlinear coupling of the pump and lower-sideband waves. Newly discovered nonlocal transport channels in spectral space and in real space via PDI are described.

  1. Flat microwave spectra seen at X-class flares

    NASA Technical Reports Server (NTRS)

    Lee, Jeongwoo W.; Gary, Dale E.; Zirin, H.

    1994-01-01

    We report peculiar spectral activity of four large microwave bursts as obtained from the Solar Arrays at the Owens Valey Radio Observatory during observations of X-class flares on 24 May 1990 and 7, 8, 22 March 1991. Main observational points that we newly uncovered are: (1) flat flux spectra over 1-18 GHz in large amounts of flux ranging from 10(exp 2) to 10(exp 4) s.f.u. at the maximum phase, (2) a common evolutionary pattern in which the spectral region of dominant flux shifts from high frequencies at the initial rise to low frequencies at the decaying phase, and (3) unusual time profiles that are impulsive at high frequencies but more extended at lower frequencies. We carry out the model calculations of microwave spectra under assumptions of gyrosynchrotron mechanism and a dipole field configuration to reproduce the observational characteristics. Our results are summarized as follows. First, a flat microwave spectrum reaching up to 10(exp 2) - 10(exp 4) s.f.u. may occur in a case where a magnetic loop is extended to an angular size of approximately (0.7-7.0) x 10(exp -7) sterad and contains a huge number (N(E greater than 10 keV) approx. 10(exp 36) - 10(exp 38)) of nonthermal electrons with power-law index approx. 3-3.5 over the entire volume. Second, the observed spectral activity could adequately be accounted for by the shrinking of the region of nonthermal electrons to the loop top and by the softening of the power-law spectrum of electrons in a time scale ranging 3-45 min depending on the event. Third, the extended microwave activity at lower frequencies is probably due to electrons trapped in the loop top where magnetic fields are low. Finally, we clarify the physical distinction between these large, extended microwave bursts and the gradual/post-microwave bursts often seen in weak events, both of which are characterized by long-period activity and broadband spectra.

  2. Energy Spectra and High Frequency Oscillations in 4U 0614+091

    NASA Technical Reports Server (NTRS)

    Ford, E. C.; Kaaret, P.; Chen, K.; Tavani, M.; Barret, D.; Bloser, P.; Grindlay, J.; Harmon, B. A.; Paciesas, W. S.; Zhang, S. N.

    1997-01-01

    We investigate the behavior of the high frequency quasi-periodic oscillations (QPOs) in 4U 0614+091, combining timing and spectral analysis of RXTE (Rossi X-ray Timing Explorer) observations. The energy spectrum of the source can be described by a power law plus a blackbody component. The blackbody has a variable temperature (kT approximately 0.8 to 1.4 keV) and accounts for 10 to 25% of the total energy flux. The power law flux and photon index also vary (F approximately 0.8 to 1.6 x 10(exp -9) erg/sq cm.s and alpha approximately 2.0 to 2.8 respectively). We find a robust correlation of the frequency of the higher frequency QPO with the flux of the blackbody. The source follows the same relation even in observations separated by several months. The QPO frequency does not have a similarly unique correlation with the total flux or the flux of the power law component. The RMS amplitudes of the higher frequency QPO rise with energy but are consistent with a constant for the lower frequency QPO. These results may be interpreted in terms of a beat frequency model for the production of the high frequency QPOs.

  3. Distributions of solar drift-pair bursts in frequency from decameter radio observations

    NASA Astrophysics Data System (ADS)

    Stanislavsky, Aleksander; Volvach, Yaroslav

    2017-04-01

    Statement of the Problem: Solar drift-pair (DP) bursts are one of interesting manifestations of solar activity. Observed during the solar storms of type III bursts, they demonstrate a very simple form on dynamic radio spectra as two short components separated in time, often the second component being the full repetition of the first. As is well known, type III bursts are produced by the accelerated electrons propagating along open magnetic field lines in solar corona. However, no each storm of type III bursts leads to any DP. The role of electron beams in the generation of DPs remains unclear. Solar DPs are detected by ground-based instruments at decameter and meter wavelengths, but each individual DP occupies only a limited bandwidth in the frequency range. The bursts drift in frequency, and their frequency drift rate can be both negative and positive (so-called the forward and reverse DPs), from -2 MHz/s to 6 MHz/s [1]. Besides, there are cases of vertical DPs, which occur simultaneously in all the frequencies within their bandwidth. It is difficult to interpret them by means of a moving source, as any exciting agent responsible for such bursts would travel with velocities faster than velocity of light [2]. Methodology & Experimental Orientation: New features of modern low-frequency radio astronomy allow us to study the empirical properties of DPs more deeply than ever before. Our results are based on the recent radio data (during 10-12 July of 2015) obtained with help of the UTR-2 radio telescope at frequencies 9-33 MHz with the time resolution of 50 ms and the frequency resolution of 4 kHz. We have identified 301 DP bursts in which 209 events were forward (FDP), and the rest were reverse (RDP). Results & Significance: According to the data, the occurrence of FDPs decreased at high frequencies, whereas the number of RDPs had an opposite tendency, they rarely occured at lower frequencies. During the observational session, at 20-25 MHz almost the same amount of

  4. Two-frequency /Delta k/ microwave scatterometer measurements of ocean wave spectra from an aircraft

    NASA Technical Reports Server (NTRS)

    Johnson, J. W.; Jones, W. L.; Weissman, D. E.

    1981-01-01

    A technique for remotely sensing the large-scale gravity wave spectrum on the ocean surface using a two frequency (Delta k) microwave scatterometer has been demonstrated from stationary platforms and proposed from moving platforms. This measurement takes advantage of Bragg type resonance matching between the electromagnetic wavelength at the difference frequency and the length of the large-scale surface waves. A prominent resonance appears in the cross product power spectral density (PSD) of the two backscattered signals. Ku-Band aircraft scatterometer measurements were conducted by NASA in the North Sea during the 1979 Maritime Remote Sensing (MARSEN) experiment. Typical examples of cross product PSD's computed from the MARSEN data are presented. They demonstrate strong resonances whose frequency and bandwidth agree with the surface characteristics and the theory. Directional modulation spectra of the surface reflectivity are compared to the gravity wave spectrum derived from surface truth measurements.

  5. High-energy X-ray spectra of Cygnus XR-1 observed from OSO 8

    NASA Technical Reports Server (NTRS)

    Dolan, J. F.; Crannell, C. J.; Dennis, B. R.; Frost, K. J.; Orwig, L. E.

    1979-01-01

    X-ray spectra of Cygnus XR-1 were measured with the scintillation spectrometer aboard the OSO 8 satellite during a period of one-and-one-half to three weeks in each of the years from 1975 to 1977. Typical spectra of the source between 15 and 250 keV are presented and the spectra are found to be well represented by a single power-law expression whose photon number spectral index is different for the two intensity states that were considered. The observed pivoting effect is consistent with two-temperature accretion disk models of the X-ray emitting region.

  6. Event terms in the response spectra prediction equation and their deviation due to stress drop variations

    NASA Astrophysics Data System (ADS)

    Kawase, H.; Nakano, K.

    2015-12-01

    We investigated the characteristics of strong ground motions separated from acceleration Fourier spectra and acceleration response spectra of 5% damping calculated from weak and moderate ground motions observed by K-NET, KiK-net, and the JMA Shindokei Network in Japan using the generalized spectral inversion method. The separation method used the outcrop motions at YMGH01 as reference where we extracted site responses due to shallow weathered layers. We include events with JMA magnitude equal to or larger than 4.5 observed from 1996 to 2011. We find that our frequency-dependent Q values are comparable to those of previous studies. From the corner frequencies of Fourier source spectra, we calculate Brune's stress parameters and found a clear magnitude dependence, in which smaller events tend to spread over a wider range while maintaining the same maximum value. We confirm that this is exactly the case for several mainshock-aftershock sequences. The average stress parameters for crustal earthquakes are much smaller than those of subduction zone, which can be explained by their depth dependence. We then compared the strong motion characteristics based on the acceleration response spectra and found that the separated characteristics of strong ground motions are different, especially in the lower frequency range less than 1Hz. These differences comes from the difference between Fourier spectra and response spectra found in the observed data; that is, predominant components in high frequency range of Fourier spectra contribute to increase the response in lower frequency range with small Fourier amplitude because strong high frequency component acts as an impulse to a Single-Degree-of-Freedom system. After the separation of the source terms for 5% damping response spectra we can obtain regression coefficients with respect to the magnitude, which lead to a new GMPE as shown in Fig.1 on the left. Although stress drops for inland earthquakes are 1/7 of the subduction

  7. Hard X-ray and high-frequency decimetric radio observations of the 4 April 2002 solar flare

    NASA Astrophysics Data System (ADS)

    Kane, S. R.; Sawant, H. S.; Cecatto, J. R.; Andrade, M. C.; Fernandes, F. C. R.; Karlicky, M.; Meszarosova, H.

    Hard X-ray and high frequency decimetric type III radio bursts have been observed in association with the soft X-raysolar flare (GOES class M 6.1) on 4 April 2002 (˜1532 UT). The flare apparently occurred ˜ 6 degrees behind the east limb of the Sun in the active region NOAA 9898. Hard X-ray spectra and images were obtained by the X-ray imager on RHESSI during the impulsive phase of the flare. The Brazilian Solar Spectroscope and Ondrejov Radio Telescopes recorded type III bursts in 800-1400 MHz range in association with the flare. The images of the 3-6, 6-12, 12-25, and 25-50 keV X-ray sources, obtained simultaneously by RHESSI during the early impulsive phase of the flare, show that all the four X-ray sources were essentially at the same location well above the limb of the Sun. During the early impulsive phase, the X-ray spectrum over 8-30 keV range was consistent with a power law with a negative exponent of ˜ 6. The radio spectra show drifting radio structures with emission in a relatively narrow (Δf ≤ 200 MHz) frequency range indicating injection of energetic electrons into a plasmoid which is slowly drifting upwards in the corona.

  8. Simultaneous multi-frequency imaging observations of solar microwave bursts

    NASA Technical Reports Server (NTRS)

    Kundu, M. R.; White, S. M.; Schmahl, E. J.

    1989-01-01

    The results of simultaneous two-frequency imaging observations of solar microwave bursts with the Very Large Array are reviewed. Simultaneous 2 and 6 cm observations have been made of bursts which are optically thin at both frequencies, or optically thick at the lower frequency. In the latter case, the source structure may differ at the two frequencies, but the two sources usually seem to be related. However, this is not always true of simultaneous 6 and 20 cm observations. The results have implications for the analysis of nonimaging radio data of solar and stellar flares.

  9. Reference-free, high-resolution measurement method of timing jitter spectra of optical frequency combs

    PubMed Central

    Kwon, Dohyeon; Jeon, Chan-Gi; Shin, Junho; Heo, Myoung-Sun; Park, Sang Eon; Song, Youjian; Kim, Jungwon

    2017-01-01

    Timing jitter is one of the most important properties of femtosecond mode-locked lasers and optical frequency combs. Accurate measurement of timing jitter power spectral density (PSD) is a critical prerequisite for optimizing overall noise performance and further advancing comb applications both in the time and frequency domains. Commonly used jitter measurement methods require a reference mode-locked laser with timing jitter similar to or lower than that of the laser-under-test, which is a demanding requirement for many laser laboratories, and/or have limited measurement resolution. Here we show a high-resolution and reference-source-free measurement method of timing jitter spectra of optical frequency combs using an optical fibre delay line and optical carrier interference. The demonstrated method works well for both mode-locked oscillators and supercontinua, with 2 × 10−9 fs2/Hz (equivalent to −174 dBc/Hz at 10-GHz carrier frequency) measurement noise floor. The demonstrated method can serve as a simple and powerful characterization tool for timing jitter PSDs of various comb sources including mode-locked oscillators, supercontinua and recently emerging Kerr-frequency combs; the jitter measurement results enabled by our method will provide new insights for understanding and optimizing timing noise in such comb sources. PMID:28102352

  10. Theoretical Investigation of Anharmonic Effects Observed in the Infrared Spectra of the Formaldehyde Cation and its Hydroxymethylene Isomer

    NASA Astrophysics Data System (ADS)

    Madison, Lindsey R.; Mosley, Jonathan; Mauney, Daniel; Duncan, Michael A.; McCoy, Anne B.

    2016-06-01

    Formaldehyde is the smallest organic molecule and is a prime candidate for a thorough investigation regarding the anharmonic approximations made in computationally modeling its infrared spectrum. Mass-selected ion spectroscopy was used to detect mass 30 cations which include of HCOH^+ and CH_2O^+. In order to elucidate the differences between the structures of these isomers, infrared spectroscopy was performed on the mass 30 cations using Ar predissociation. Interestingly, several additional spectral features are observed that cannot be explained by the fundamental OH and CH stretch vibrations alone. By including anharmonic coupling between OH and CH stretching and various overtones and combination bands involving lower frequency vibrations, we are able to identify how specific modes couple and lead to the experimentally observed spectral features. We combine straight-forward, ab initio calculations of the anharmonic frequencies of the mass 30 cations with higher order, adiabatic approximations and Fermi resonance models. By including anharmonic effects we are able to confirm that the isomers of the CH_2O^+\\cdotAr system have substantially different, and thus distinguishable, IR spectra and that many of the features can only be explained with anharmonic treatments.

  11. Anomalies in the Spectra of the Uncorrelated Components of the Electric Field of the Earth at Frequencies that are Multiples of the Frequencies of Rotation of Relativistic Binary Star Systems

    NASA Astrophysics Data System (ADS)

    Grunskaya, L. V.; Isakevich, V. V.; Isakevich, D. V.

    2018-05-01

    A system is constructed, which, on the basis of extensive experimental material and the use of eigenoscopy, has allowed us to detect anomalies in the spectra of uncorrelated components localized near the rotation frequencies and twice the rotation frequencies of relativistic binary star systems with vanishingly low probability of false alarm, not exceeding 10-17.

  12. FTIR, FT-Raman spectra and ab initio, DFT vibrational analysis of 2,4-dinitrophenylhydrazine.

    PubMed

    Sundaraganesan, N; Ayyappan, S; Umamaheswari, H; Joshua, B Dominic

    2007-01-01

    The FTIR and FT-Raman spectra of 2,4-dinitrophenylhydrazine (2,4-DNPH) has been recorded in the region 4000-400 and 3500-50cm-1, respectively. The optimized geometry, frequency and intensity of the vibrational bands of 2,4-DNPH were obtained by the ab initio and density functional theory (DFT) levels of theory with complete relaxation in the potential energy surface using 6-31G(d,p) and 6-311G(d,p) basis sets. The harmonic vibrational frequencies were calculated and the scaled values have been compared with experimental FTIR and FT-Raman spectra. The observed and the calculated frequencies are found to be in good agreement. The experimental spectra also coincide satisfactorily with those of theoretically constructed bar type spectrograms.

  13. FTIR, FT-Raman spectra and ab initio, DFT vibrational analysis of 2,4-dinitrophenylhydrazine

    NASA Astrophysics Data System (ADS)

    Sundaraganesan, N.; Ayyappan, S.; Umamaheswari, H.; Dominic Joshua, B.

    2007-01-01

    The FTIR and FT-Raman spectra of 2,4-dinitrophenylhydrazine (2,4-DNPH) has been recorded in the region 4000-400 and 3500-50 cm -1, respectively. The optimized geometry, frequency and intensity of the vibrational bands of 2,4-DNPH were obtained by the ab initio and density functional theory (DFT) levels of theory with complete relaxation in the potential energy surface using 6-31G(d,p) and 6-311G(d,p) basis sets. The harmonic vibrational frequencies were calculated and the scaled values have been compared with experimental FTIR and FT-Raman spectra. The observed and the calculated frequencies are found to be in good agreement. The experimental spectra also coincide satisfactorily with those of theoretically constructed bar type spectrograms.

  14. Numerical investigation of frequency spectrum in the Hasegawa-Wakatani model

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kim, Juhyung; Terry, P. W.

    2013-10-15

    The wavenumber-frequency spectrum of the two-dimensional Hasegawa-Wakatani model is investigated in the hydrodynamic, intermediate, and adiabatic regimes. A nonlinear frequency and a line width related to energy transfer properties provide a measure of the average frequency and spectral broadening, respectively. In the adiabatic regime, narrow spectra, typical of wave turbulence, are observed with a nonlinear frequency shift in the electron drift direction. In the hydrodynamic regime, broad spectra with almost zero nonlinear frequencies are observed. Nonlinear frequency shifts are shown to be related to nonlinear energy transfer by vorticity advection through the high frequency region of the spectrum. In themore » intermediate regime, the nonlinear frequency shift for density fluctuations is observed to be weaker than that of electrostatic potential fluctuations. The weaker frequency shift of the density fluctuations is due to nonlinear density advection, which favors energy transfer in the low frequency range. Both the nonlinear frequency and the spectral width increase with poloidal wavenumber k{sub y}. In addition, in the adiabatic regime where the nonlinear interactions manifest themselves in the nonlinear frequency shift, the cross-phase between the density and potential fluctuations is observed to match a linear relation, but only if the linear response of the linearly stable eigenmode branch is included. Implications of these numerical observations are discussed.« less

  15. A sensitive continuum analysis method for gamma ray spectra

    NASA Technical Reports Server (NTRS)

    Thakur, Alakh N.; Arnold, James R.

    1993-01-01

    In this work we examine ways to improve the sensitivity of the analysis procedure for gamma ray spectra with respect to small differences in the continuum (Compton) spectra. The method developed is applied to analyze gamma ray spectra obtained from planetary mapping by the Mars Observer spacecraft launched in September 1992. Calculated Mars simulation spectra and actual thick target bombardment spectra have been taken as test cases. The principle of the method rests on the extraction of continuum information from Fourier transforms of the spectra. We study how a better estimate of the spectrum from larger regions of the Mars surface will improve the analysis for smaller regions with poorer statistics. Estimation of signal within the continuum is done in the frequency domain which enables efficient and sensitive discrimination of subtle differences between two spectra. The process is compared to other methods for the extraction of information from the continuum. Finally we explore briefly the possible uses of this technique in other applications of continuum spectra.

  16. MR Spectra of Normal Adult Testes and Variations with Age: Preliminary Observations.

    PubMed

    Tsili, Athina C; Astrakas, Loukas G; Ntorkou, Alexandra; Giannakis, Dimitrios; Stavrou, Sotirios; Maliakas, Vasilios; Sofikitis, Nikolaos; Argyropoulou, Maria I

    2016-07-01

    The aim was to determine the proton MR (1H-MR) spectra of normal adult testes and variations with age. Forty-one MR spectra of normal testes, including 16 testes from men aged 20-39 years (group I) and 25 testes from men aged 40-69 years (group II), were analyzed. A single-voxel point-resolved spectroscopy sequence (PRESS), with TR/TE: 2000/25 ms was used. The volume of interest was placed to include the majority of normal testicular parenchyma. Association between normalized metabolite concentrations, defined as ratios of the calculated metabolite concentrations relative to creatine concentration, and age was assessed. Quantified metabolites of the spectra were choline (Cho), creatine (Cr), myo-inositol (mI), scyllo-inositol, taurine, lactate, GLx compound, glucose, lipids, and macromolecules resonating at 0.9 ppm (LM09), around 20 ppm (LM20), and at 13 ppm (LM13). Most prominent peaks were Cho, Cr, mI, and lipids. A weak negative correlation between mI and age (P = 0.015) was observed. Higher normalized concentrations of Cho (P = 0.03), mI (P = 0.08), and LM13 (P = 0.05) were found in group I than in group II. 1H-MR spectra of a normal adult testis showed several metabolite peaks. A decrease of levels of Cho, mI, and LM13 was observed with advancing age. • Single-voxel PRESS MRS of a normal testis is feasible. • 1H-MR spectra of a normal testis showed several metabolite peaks. • Most prominent peaks were Cho, Cr, mI, and lipids. • A decrease of Cho, mI, and LM13 was seen with advancing age.

  17. Temperature effects on the pickup process of water group and hydrogen ions - Extensions of 'A theory for low-frequency waves observed at Comet Giacobini-Zinner' by M. L. Goldstein and H. K. Wong

    NASA Technical Reports Server (NTRS)

    Brinca, Armando L.; Tsurutani, Bruce T.

    1988-01-01

    Cometary heavy ions can resonantly excite hydromagnetic wave activity with spacecraft frequency spectra strongly deviating from the ion cyclotron frequency. The influence of the newborn particle temperature on this effect is assessed, its relevance to the interpretation of the observations is discussed, and an alternative, more efficient mechanism to generate spacecraft frequencies of the order of the proton cyclotron frequency is suggested.

  18. Very low frequency oscillations in the power spectra of heart rate variability during dry supine immersion and exposure to non-hypoxic hypobaria.

    PubMed

    Tripathi, K K

    2011-06-01

    The origin of very low frequency (VLF) oscillations in the power spectra of heart rate variability (HRV) is controversial with possible mechanisms involving thermoregulation and/or renin-angiotensin-aldosterone system. Recently, a major contribution from vagal influences has been suggested. The present study investigated the behaviour of VLF (0.004-0.040 Hz) components of HRV power spectra in a group of healthy male volunteers during their exposure to (1) dry, supine, immersion in thermo-neutral water for 6 h (n = 7) and (2) non-hypoxic hypobaria (breathing 40-60% oxygen at 15,000' simulated in a decompression chamber) for 5 h (n = 15). The two manoeuvres are established to increase vagal outflow. During both the manoeuvres, all the frequency domain indices of HRV exhibited a significant increase. Increase in HRV was much more than that in the R-R interval. At 6 h of immersion, the R-R interval increased by ∼ 15% but the total power increased ∼ fourfold. Similarly, at 5 h of exposure to hypobaria, total power increased ∼ twofold with a very modest increase in an R-R of ∼ 9%. Increase in spectral power was appreciable even after normalization with mean R-R(2). Increase in VLF during immersion was more than reported during enalaprilat blockade of angiotensin convertase enzyme. Plasma renin activity did not vary during hypobaria. There was a significant increase in pNN50, an established marker of cardiac vagal activity. Centre frequencies of the spectra and slope (β) of the relation between log(PSD) and log(frequency) did not change. Results were supportive of the notion that the parasympathetic system is pre-potent to influence slower (than respiratory) frequency components in HRV spectrum. Additionally, such an effect was without a change in the time constant of effector responses or pacemaker frequencies of VLF and LF periodicities and HRV was not a simple linear surrogate for cardiac vagal effects. An invariance of spectral exponent (β) ruled out

  19. Resonant Raman spectra of diindenoperylene thin films

    NASA Astrophysics Data System (ADS)

    Scholz, R.; Gisslén, L.; Schuster, B.-E.; Casu, M. B.; Chassé, T.; Heinemeyer, U.; Schreiber, F.

    2011-01-01

    Resonant and preresonant Raman spectra obtained on diindenoperylene (DIP) thin films are interpreted with calculations of the deformation of a relaxed excited molecule with density functional theory (DFT). The comparison of excited state geometries based on time-dependent DFT or on a constrained DFT scheme with observed absorption spectra of dissolved DIP reveals that the deformation pattern deduced from constrained DFT is more reliable. Most observed Raman peaks can be assigned to calculated A_g-symmetric breathing modes of DIP or their combinations. As the position of one of the laser lines used falls into a highly structured absorption band, we have carefully analyzed the Raman excitation profile arising from the frequency dependence of the dielectric tensor. This procedure gives Raman cross sections in good agreement with the observed relative intensities, both in the fully resonant and in the preresonant case.

  20. Resonant Raman spectra of diindenoperylene thin films.

    PubMed

    Scholz, R; Gisslén, L; Schuster, B-E; Casu, M B; Chassé, T; Heinemeyer, U; Schreiber, F

    2011-01-07

    Resonant and preresonant Raman spectra obtained on diindenoperylene (DIP) thin films are interpreted with calculations of the deformation of a relaxed excited molecule with density functional theory (DFT). The comparison of excited state geometries based on time-dependent DFT or on a constrained DFT scheme with observed absorption spectra of dissolved DIP reveals that the deformation pattern deduced from constrained DFT is more reliable. Most observed Raman peaks can be assigned to calculated A(g)-symmetric breathing modes of DIP or their combinations. As the position of one of the laser lines used falls into a highly structured absorption band, we have carefully analyzed the Raman excitation profile arising from the frequency dependence of the dielectric tensor. This procedure gives Raman cross sections in good agreement with the observed relative intensities, both in the fully resonant and in the preresonant case.

  1. Wavenumber-frequency Spectra of Pressure Fluctuations Measured via Fast Response Pressure Sensitive Paint

    NASA Technical Reports Server (NTRS)

    Panda, J.; Roozeboom, N. H.; Ross, J. C.

    2016-01-01

    The recent advancement in fast-response Pressure-Sensitive Paint (PSP) allows time-resolved measurements of unsteady pressure fluctuations from a dense grid of spatial points on a wind tunnel model. This capability allows for direct calculations of the wavenumber-frequency (k-?) spectrum of pressure fluctuations. Such data, useful for the vibro-acoustics analysis of aerospace vehicles, are difficult to obtain otherwise. For the present work, time histories of pressure fluctuations on a flat plate subjected to vortex shedding from a rectangular bluff-body were measured using PSP. The light intensity levels in the photographic images were then converted to instantaneous pressure histories by applying calibration constants, which were calculated from a few dynamic pressure sensors placed at selective points on the plate. Fourier transform of the time-histories from a large number of spatial points provided k-? spectra for pressure fluctuations. The data provides first glimpse into the possibility of creating detailed forcing functions for vibro-acoustics analysis of aerospace vehicles, albeit for a limited frequency range.

  2. Handling the satellite inter-frequency biases in triple-frequency observations

    NASA Astrophysics Data System (ADS)

    Zhao, Lewen; Ye, Shirong; Song, Jia

    2017-04-01

    The new generation of GNSS satellites, including BDS, Galileo, modernized GPS, and GLONASS, transmit navigation sdata at more frequencies. Multi-frequency signals open new prospects for precise positioning, but satellite code and phase inter-frequency biases (IFB) induced by the third frequency need to be handled. Satellite code IFB can be corrected using products estimated by different strategies, the theoretical and numerical compatibility of these methods need to be proved. Furthermore, a new type of phase IFB, which changes with the relative sun-spacecraft-earth geometry, has been observed. It is necessary to investigate the cause and possible impacts of phase Time-variant IFB (TIFB). Therefore, we present systematic analysis to illustrate the relevancy between satellite clocks and phase TIFB, and compare the handling strategies of the code and phase IFB in triple-frequency positioning. First, the un-differenced L1/L2 satellite clock corrections considering the hardware delays are derived. And IFB induced by the dual-frequency satellite clocks to triple-frequency PPP model is detailed. The analysis shows that estimated satellite clocks actually contain the time-variant phase hardware delays, which can be compensated in L1/L2 ionosphere-free combinations. However, the time-variant hardware delays will lead to TIFB if the third frequency is used. Then, the methods used to correct the code and phase IFB are discussed. Standard point positioning (SPP) and precise point positioning (PPP) using BDS observations are carried out to validate the improvement of different IFB correction strategies. Experiments show that code IFB derived from DCB or geometry-free and ionosphere-free combination show an agreement of 0.3 ns for all satellites. Positioning results and error distribution with two different code IFB correcting strategies achieve similar tendency, which shows their substitutability. The original and wavelet filtered phase TIFB long-term series show significant

  3. Visual adaptation and the amplitude spectra of radiological images.

    PubMed

    Kompaniez-Dunigan, Elysse; Abbey, Craig K; Boone, John M; Webster, Michael A

    2018-01-01

    We examined how visual sensitivity and perception are affected by adaptation to the characteristic amplitude spectra of X-ray mammography images. Because of the transmissive nature of X-ray photons, these images have relatively more low-frequency variability than natural images, a difference that is captured by a steeper slope of the amplitude spectrum (~ - 1.5) compared to the ~ 1/f (slope of - 1) spectra common to natural scenes. Radiologists inspecting these images are therefore exposed to a different balance of spectral components, and we measured how this exposure might alter spatial vision. Observers (who were not radiologists) were adapted to images of normal mammograms or the same images sharpened by filtering the amplitude spectra to shallower slopes. Prior adaptation to the original mammograms significantly biased judgments of image focus relative to the sharpened images, demonstrating that the images are sufficient to induce substantial after-effects. The adaptation also induced strong losses in threshold contrast sensitivity that were selective for lower spatial frequencies, though these losses were very similar to the threshold changes induced by the sharpened images. Visual search for targets (Gaussian blobs) added to the images was also not differentially affected by adaptation to the original or sharper images. These results complement our previous studies examining how observers adapt to the textural properties or phase spectra of mammograms. Like the phase spectrum, adaptation to the amplitude spectrum of mammograms alters spatial sensitivity and visual judgments about the images. However, unlike the phase spectrum, adaptation to the amplitude spectra did not confer a selective performance advantage relative to more natural spectra.

  4. Observing the Spectra of MEarth and TRAPPIST Planets with JWST

    NASA Astrophysics Data System (ADS)

    Morley, Caroline; Kreidberg, Laura; Rustamkulov, Zafar; Robinson, Tyler D.; Fortney, Jonathan J.

    2017-10-01

    During the past two years, nine planets close to Earth in radius have been discovered around nearby M dwarfs cooler than 3300 K. These planets include the 7 planets in the TRAPPIST-1 system and two planets discovered by the MEarth survey, GJ 1132b and LHS 1140b (Dittmann et al. 2017; Berta-Thompson et al. 2015; Gillon et al. 2017). These planets are the smallest planets discovered to date that will be amenable to atmospheric characterization with JWST. They span equilibrium temperatures from ˜130 K to >500 K, and radii from 0.7 to 1.43 Earth radii. Some of these planets orbit as distances potentially amenable to surface liquid water, though the actual surface temperatures will depend strongly on the albedo of the planet and the thickness and composition of its atmosphere. The stars they orbit also vary in activity levels, from the quiet LHS 1140b host star to the more active TRAPPIST-1 host star. This set of planets will form the testbed for our first chance to study the diversity of atmospheres around Earth-sized planets. Here, we will present model spectra of these 9 planets, varying the composition and the surface pressure of the atmosphere. We base our elemental compositions on three outcomes of planetary atmosphere evolution in our own solar system: Earth, Titan, and Venus. We calculate the molecular compositions in chemical equilibrium. We present both thermal emission spectra and transmission spectra for each of these objects, and make predictions for the observability of these spectra with different instrument modes with JWST.

  5. Monte Carlo turbulence simulation using rational approximations to von Karman spectra

    NASA Technical Reports Server (NTRS)

    Campbell, C. W.

    1986-01-01

    Turbulence simulation is computationally much simpler using rational spectra, but turbulence falls off as f exp -5/3 in frequency ranges of interest to aircraft response and as predicted by von Karman's model. Rational approximations to von Karman spectra should satisfy three requirements: (1) the rational spectra should provide a good approximation to the von Karman spectra in the frequency range of interest; (2) for stability, the resulting rational transfer function should have all its poles in the left half-plane; and (3) at high frequencies, the rational spectra must fall off as an integer power of frequency, and since the -2 power is closest to the -5/3 power, the rational approximation should roll off as the -2 power at high frequencies. Rational approximations to von Karman spectra that satisfy these three criteria are presented, along with spectra from simulated turbulence. Agreement between the spectra of the simulated turbulence and von Karman spectra is excellent.

  6. The Frequency-dependent Damping of Slow Magnetoacoustic Waves in a Sunspot Umbral Atmosphere

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Prasad, S. Krishna; Jess, D. B.; Doorsselaere, T. Van

    High spatial and temporal resolution images of a sunspot, obtained simultaneously in multiple optical and UV wavelengths, are employed to study the propagation and damping characteristics of slow magnetoacoustic waves up to transition region heights. Power spectra are generated from intensity oscillations in sunspot umbra, across multiple atmospheric heights, for frequencies up to a few hundred mHz. It is observed that the power spectra display a power-law dependence over the entire frequency range, with a significant enhancement around 5.5 mHz found for the chromospheric channels. The phase difference spectra reveal a cutoff frequency near 3 mHz, up to which themore » oscillations are evanescent, while those with higher frequencies propagate upward. The power-law index appears to increase with atmospheric height. Also, shorter damping lengths are observed for oscillations with higher frequencies suggesting frequency-dependent damping. Using the relative amplitudes of the 5.5 mHz (3 minute) oscillations, we estimate the energy flux at different heights, which seems to decay gradually from the photosphere, in agreement with recent numerical simulations. Furthermore, a comparison of power spectra across the umbral radius highlights an enhancement of high-frequency waves near the umbral center, which does not seem to be related to magnetic field inclination angle effects.« less

  7. Energy spectra variations of high energy electrons in magnetic storms observed by ARASE and HIMAWARI

    NASA Astrophysics Data System (ADS)

    Takashima, T.; Higashio, N.; Mitani, T.; Nagatsuma, T.; Yoshizumi, M.

    2017-12-01

    The ARASE spacecraft was launched in December 20, 2016 to investigate mechanisms for acceleration and loss of relativistic electrons in the radiation belts during space storms. The six particle instruments with wide energy range (a few eV to 10MeV) are onboard the ARASE spacecraft. Especially, two particle instruments, HEP and XEP observe high energy electron with energy range from 70keV to over 10Mev. Those instruments observed several geomagnetic storms caused by coronal hole high speed streams or coronal mass ejections from March in 2017. The relativistic electrons in the outer radiation belt were disappeared/increased and their energy spectra were changed dynamically in some storms observed by XEP/HEP onboard the ARASE spacecraft. In the same time, SEDA-e with energy range 200keV-4.5MeV for electron on board the HIMAWARI-8, Japanese weather satellite on GEO, observed increase of relativistic electron in different local time. We will report on energy spectra variations of high energy electrons including calibrations of differential flux between XEP and HEP and discuss comparisons with energy spectra between ARAE and HIMAWARI that observed each storm in different local time.

  8. Cosmological flux noise and measured noise power spectra in SQUIDs

    PubMed Central

    Beck, Christian

    2016-01-01

    The understanding of the origin of 1/f magnetic flux noise commonly observed in superconducting devices such as SQUIDs and qubits is still a major unsolved puzzle. Here we discuss the possibility that a significant part of the observed low-frequency flux noise measured in these devices is ultimately seeded by cosmological fluctuations. We consider a theory where a primordial flux noise field left over in unchanged form from an early inflationary or quantum gravity epoch of the universe intrinsically influences the phase difference in SQUIDs and qubits. The perturbation seeds generated by this field can explain in a quantitatively correct way the form and amplitude of measured low-frequency flux noise spectra in SQUID devices if one takes as a source of fluctuations the primordial power spectrum of curvature fluctuations as measured by the Planck collaboration. Our theoretical predictions are in excellent agreement with recent low-frequency flux noise measurements of various experimental groups. Magnetic flux noise, so far mainly considered as a nuisance for electronic devices, may thus contain valuable information about fluctuation spectra in the very early universe. PMID:27320418

  9. Cosmological flux noise and measured noise power spectra in SQUIDs.

    PubMed

    Beck, Christian

    2016-06-20

    The understanding of the origin of 1/f magnetic flux noise commonly observed in superconducting devices such as SQUIDs and qubits is still a major unsolved puzzle. Here we discuss the possibility that a significant part of the observed low-frequency flux noise measured in these devices is ultimately seeded by cosmological fluctuations. We consider a theory where a primordial flux noise field left over in unchanged form from an early inflationary or quantum gravity epoch of the universe intrinsically influences the phase difference in SQUIDs and qubits. The perturbation seeds generated by this field can explain in a quantitatively correct way the form and amplitude of measured low-frequency flux noise spectra in SQUID devices if one takes as a source of fluctuations the primordial power spectrum of curvature fluctuations as measured by the Planck collaboration. Our theoretical predictions are in excellent agreement with recent low-frequency flux noise measurements of various experimental groups. Magnetic flux noise, so far mainly considered as a nuisance for electronic devices, may thus contain valuable information about fluctuation spectra in the very early universe.

  10. Stratospheric Horizontal Wavenumber Spectra of Winds, Potential Temperature, and Atmospheric Tracers Observed by High-Altitude Aircraft

    NASA Technical Reports Server (NTRS)

    Bacmeister, Julio T.; Eckermann, Stephen D.; Newman, Paul A.; Lait, Leslie; Chan, K. R.; Loewenstein, Max; Proffitt, Michael H.; Gary, Bruce L.

    1996-01-01

    Horizontal wavenumber power spectra of vertical and horizontal wind velocities, potential temperatures, and ozone and N(2)O mixing ratios, as measured in the mid-stratosphere during 73 ER-2 flights (altitude approx. 20km) are presented. The velocity and potential temperature spectra in the 100 to 1-km wavelength range deviate significantly from the uniform -5/3 power law expected for the inverse energy-cascade regime of two-dimensional turbulence and also for inertial-range, three-dimensional turbulence. Instead, steeper spectra approximately consistent with a -3 power law are observed at horizontal scales smaller than 3 km for all velocity components as well as potential temperature. Shallower spectra are observed at scales longer than 6 km. For horizontal velocity and potential temperature the spectral indices at longer scales are between -1.5 and -2.0. For vertical velocity the spectrum at longer scales become flat. It is argued that the observed velocity and potential temperature spectra are consistent with gravity waves. At smaller scales, the shapes are also superficially consistent with a Lumley-Shur-Weinstock buoyant subrange of turbulence and/or nonlinear gravity waves. Contemporaneous spectra of ozone and N(sub 2)O mixing ratio in the 100 to 1-km wavelength range do conform to an approximately uniform -5/3 power law. It is argued that this may reflect interactions between gravity wave air-parcel displacements and laminar or filamentary structures in the trace gas mixing ratio field produced by enstropy-cascading two-dimensional turbulence.

  11. The effect of sampling rate and anti-aliasing filters on high-frequency response spectra

    USGS Publications Warehouse

    Boore, David M.; Goulet, Christine

    2013-01-01

    The most commonly used intensity measure in ground-motion prediction equations is the pseudo-absolute response spectral acceleration (PSA), for response periods from 0.01 to 10 s (or frequencies from 0.1 to 100 Hz). PSAs are often derived from recorded ground motions, and these motions are usually filtered to remove high and low frequencies before the PSAs are computed. In this article we are only concerned with the removal of high frequencies. In modern digital recordings, this filtering corresponds at least to an anti-aliasing filter applied before conversion to digital values. Additional high-cut filtering is sometimes applied both to digital and to analog records to reduce high-frequency noise. Potential errors on the short-period (high-frequency) response spectral values are expected if the true ground motion has significant energy at frequencies above that of the anti-aliasing filter. This is especially important for areas where the instrumental sample rate and the associated anti-aliasing filter corner frequency (above which significant energy in the time series is removed) are low relative to the frequencies contained in the true ground motions. A ground-motion simulation study was conducted to investigate these effects and to develop guidance for defining the usable bandwidth for high-frequency PSA. The primary conclusion is that if the ratio of the maximum Fourier acceleration spectrum (FAS) to the FAS at a frequency fsaa corresponding to the start of the anti-aliasing filter is more than about 10, then PSA for frequencies above fsaa should be little affected by the recording process, because the ground-motion frequencies that control the response spectra will be less than fsaa . A second topic of this article concerns the resampling of the digital acceleration time series to a higher sample rate often used in the computation of short-period PSA. We confirm previous findings that sinc-function interpolation is preferred to the standard practice of using

  12. Turn-over in pulsar spectra: From young pulsars to millisecond ones

    NASA Astrophysics Data System (ADS)

    Kijak, J.; Lewandowski, W.; Serylak, M.

    2008-02-01

    The evidence for turn-over in young pulsar radio spectra at high frequencies is presented. The frequency at which a spectrum shows the maximum flux density is called the peak frequency. This peak frequency appears to depend on pulsar age and dispersion measure. A possible relation with pulsar age is interesting. Millisecond pulsars, which are very old objects, may show no evidence for spectral turn-over down to 100 MHz. Some studied pulsars with turn-over at high frequencies have been shown to have very interesting interstellar environments. This could suggest that the turn-over phenomenon is associated with the enviromental conditions around the neutron stars, rahter than being related intrinsically with the radio emission mechanism. Although there are no earlier reports of such a connection, a more detailed study on larger sample of pulsars is needed to address this idea more quantitatively. In this context, future observations below 200 MHz using LOFAR will allow us to investigate turn-over in radio pulsar spectra.

  13. Observations of silicate reststrahlen bands in lunar infrared spectra

    NASA Technical Reports Server (NTRS)

    Potter, A. E., Jr.; Morgan, T. H.

    1982-01-01

    Thermal emission spectra of three lunar sites (Apollo 11, Descartes Formation, and Tycho central peak) are measured in the 8-14 micron spectral range. Transmission and instrument effects are accounted for by forming ratios of the Descartes and Tycho spectra to the Apollo 11 spectrum. The ratio spectra are compared with ratios of published laboratory spectra of returned lunar samples and also with ratio spectra calculated using the Aronson-Emslie (1975) model. The comparisons show pyroxene bands in the Descartes ratio spectrum and plagioclase bands in the Tycho ratio spectrum. The Tycho spectrum is found to be consistent with the existence of fine plagioclase dust (approximately 1 micron) at the rock surface and a higher-than-usual sodium content of the plagioclase.

  14. Fingerprints of a riming event on cloud radar Doppler spectra: observations and modeling

    DOE PAGES

    Kalesse, Heike; Szyrmer, Wanda; Kneifel, Stefan; ...

    2016-03-09

    In this paper, Radar Doppler spectra measurements are exploited to study a riming event when precipitating ice from a seeder cloud sediment through a supercooled liquid water (SLW) layer. The focus is on the "golden sample" case study for this type of analysis based on observations collected during the deployment of the Atmospheric Radiation Measurement Program's (ARM) mobile facility AMF2 at Hyytiälä, Finland, during the Biogenic Aerosols – Effects on Clouds and Climate (BAECC) field campaign. The presented analysis of the height evolution of the radar Doppler spectra is a state-of-the-art retrieval with profiling cloud radars in SLW layers beyondmore » the traditional use of spectral moments. Dynamical effects are considered by following the particle population evolution along slanted tracks that are caused by horizontal advection of the cloud under wind shear conditions. In the SLW layer, the identified liquid peak is used as an air motion tracer to correct the Doppler spectra for vertical air motion and the ice peak is used to study the radar profiles of rimed particles. A 1-D steady-state bin microphysical model is constrained using the SLW and air motion profiles and cloud top radar observations. The observed radar moment profiles of the rimed snow can be simulated reasonably well by the model, but not without making several assumptions about the ice particle concentration and the relative role of deposition and aggregation. In conclusion, this suggests that in situ observations of key ice properties are needed to complement the profiling radar observations before process-oriented studies can effectively evaluate ice microphysical parameterizations.« less

  15. Spectroscopy Made Easy: A New Tool for Fitting Observations with Synthetic Spectra

    NASA Technical Reports Server (NTRS)

    Valenti, J. A.; Piskunov, N.

    1996-01-01

    We describe a new software package that may be used to determine stellar and atomic parameters by matching observed spectra with synthetic spectra generated from parameterized atmospheres. A nonlinear least squares algorithm is used to solve for any subset of allowed parameters, which include atomic data (log gf and van der Waals damping constants), model atmosphere specifications (T(sub eff, log g), elemental abundances, and radial, turbulent, and rotational velocities. LTE synthesis software handles discontiguous spectral intervals and complex atomic blends. As a demonstration, we fit 26 Fe I lines in the NSO Solar Atlas (Kurucz et al.), determining various solar and atomic parameters.

  16. Comparisons of Spectra from 3D Kinetic Meteor PIC Simulations with Theory and Observations

    NASA Astrophysics Data System (ADS)

    Oppenheim, M. M.; Tarnecki, L. K.

    2017-12-01

    Meteoroids smaller than a grain of sand have significant impacts on the composition, chemistry, and dynamics of the atmosphere. The processes by which they turbulently diffuse can be studied using collisional kinetic particle-in-cell (PIC) simulations. Spectral analysis is a valuable tool for comparing such simulations of turbulent, non-specular meteor trails with observations. We present three types of spectral information: full spectra along the trail in k-ω space, spectral widths at common radar frequencies, and power as a function of angle with respect to B. These properties can be compared to previously published data. Zhou et al. (2004) use radar theory to predict the power observed by a radar as a function of the angle between the meteor trail and the radar beam and the size of field-aligned irregularities (FAI) within the trail. Close et al. (2008) present observations of meteor trails from the ALTAIR radar, including power returned as a function of angle off B for a small sample of meteors. Close et al. (2008) and Zhou et al. (2004) both suggest a power drop off of 2-3 dB per degree off perpendicular to B. We compare results from our simulations with both theory and observations for a range of conditions, including trail altitude and incident neutral wind speed. For 1m waves, power fell off by 1-3 dB per degree off perpendicular to B. These comparisons help determine if small-scale simulations accurately capture the behavior of real meteors.

  17. Investigation of Temperature Ratio Effect on the Low-Frequency Acoustic Spectra of Heated Jets

    NASA Astrophysics Data System (ADS)

    Karam, Sofia

    Jet noise remains one of the most important problems in the aviation industry, and its reduction is sought in the context of both commercial and military aircraft. In this thesis, an investigation of the jet noise is conducted in terms of the effect of temperature and Mach number on low frequency acoustic spectra. A low-order model derived from the generalized acoustic analogy method via a low-frequency asymptotic approach is utilized, where the mean flow and pertinent statistical quantities are obtained from RANS simulations. The study involves a combination of seven acoustic Mach numbers ranging from 0.3 to 1.5 and five temperature ratios (TR) ranging from 1 to 3. The model is calibrated with existing experimental measurements of a Mach 0.9 and TR = 1 jet. The results show that the sound pressure level increases with the increase in Mach number, and decreases with the decrease in temperature ratios.

  18. Planck intermediate results. XLV. Radio spectra of northern extragalactic radio sources

    NASA Astrophysics Data System (ADS)

    Planck Collaboration; Ade, P. A. R.; Aghanim, N.; Aller, H. D.; Aller, M. F.; Arnaud, M.; Aumont, J.; Baccigalupi, C.; Banday, A. J.; Barreiro, R. B.; Bartolo, N.; Battaner, E.; Benabed, K.; Benoit-Lévy, A.; Bernard, J.-P.; Bersanelli, M.; Bielewicz, P.; Bonaldi, A.; Bonavera, L.; Bond, J. R.; Borrill, J.; Bouchet, F. R.; Burigana, C.; Calabrese, E.; Catalano, A.; Chiang, H. C.; Christensen, P. R.; Clements, D. L.; Colombo, L. P. L.; Couchot, F.; Crill, B. P.; Curto, A.; Cuttaia, F.; Danese, L.; Davies, R. D.; Davis, R. J.; de Bernardis, P.; de Rosa, A.; de Zotti, G.; Delabrouille, J.; Dickinson, C.; Diego, J. M.; Dole, H.; Donzelli, S.; Doré, O.; Ducout, A.; Dupac, X.; Efstathiou, G.; Elsner, F.; Eriksen, H. K.; Finelli, F.; Forni, O.; Frailis, M.; Fraisse, A. A.; Franceschi, E.; Galeotta, S.; Galli, S.; Ganga, K.; Giard, M.; Giraud-Héraud, Y.; Gjerløw, E.; González-Nuevo, J.; Górski, K. M.; Gruppuso, A.; Gurwell, M. A.; Hansen, F. K.; Harrison, D. L.; Henrot-Versillé, S.; Hernández-Monteagudo, C.; Hildebrandt, S. R.; Hobson, M.; Hornstrup, A.; Hovatta, T.; Hovest, W.; Huffenberger, K. M.; Hurier, G.; Jaffe, A. H.; Jaffe, T. R.; Järvelä, E.; Keihänen, E.; Keskitalo, R.; Kisner, T. S.; Kneissl, R.; Knoche, J.; Kunz, M.; Kurki-Suonio, H.; Lähteenmäki, A.; Lamarre, J.-M.; Lasenby, A.; Lattanzi, M.; Lawrence, C. R.; Leonardi, R.; Levrier, F.; Liguori, M.; Lilje, P. B.; Linden-Vørnle, M.; López-Caniego, M.; Lubin, P. M.; Macías-Pérez, J. F.; Maffei, B.; Maino, D.; Mandolesi, N.; Maris, M.; Martin, P. G.; Martínez-González, E.; Masi, S.; Matarrese, S.; Max-Moerbeck, W.; Meinhold, P. R.; Melchiorri, A.; Mennella, A.; Migliaccio, M.; Mingaliev, M.; Miville-Deschênes, M.-A.; Moneti, A.; Montier, L.; Morgante, G.; Mortlock, D.; Munshi, D.; Murphy, J. A.; Nati, F.; Natoli, P.; Nieppola, E.; Noviello, F.; Novikov, D.; Novikov, I.; Pagano, L.; Pajot, F.; Paoletti, D.; Partridge, B.; Pasian, F.; Pearson, T. J.; Perdereau, O.; Perotto, L.; Pettorino, V.; Piacentini, F.; Piat, M.; Pierpaoli, E.; Plaszczynski, S.; Pointecouteau, E.; Polenta, G.; Pratt, G. W.; Ramakrishnan, V.; Rastorgueva-Foi, E. A.; S Readhead, A. C.; Reinecke, M.; Remazeilles, M.; Renault, C.; Renzi, A.; Richards, J. L.; Ristorcelli, I.; Rocha, G.; Rossetti, M.; Roudier, G.; Rubiño-Martín, J. A.; Rusholme, B.; Sandri, M.; Savelainen, M.; Savini, G.; Scott, D.; Sotnikova, Y.; Stolyarov, V.; Sunyaev, R.; Sutton, D.; Suur-Uski, A.-S.; Sygnet, J.-F.; Tammi, J.; Tauber, J. A.; Terenzi, L.; Toffolatti, L.; Tomasi, M.; Tornikoski, M.; Tristram, M.; Tucci, M.; Türler, M.; Valenziano, L.; Valiviita, J.; Valtaoja, E.; Van Tent, B.; Vielva, P.; Villa, F.; Wade, L. A.; Wehrle, A. E.; Wehus, I. K.; Yvon, D.; Zacchei, A.; Zonca, A.

    2016-12-01

    Continuum spectra covering centimetre to submillimetre wavelengths are presented for a northern sample of 104 extragalactic radio sources, mainly active galactic nuclei, based on four-epoch Planck data. The nine Planck frequencies, from 30 to 857 GHz, are complemented by a set of simultaneous ground-based radio observations between 1.1 and 37 GHz. The single-survey Planck data confirm that the flattest high-frequency radio spectral indices are close to zero, indicating that the original accelerated electron energy spectrum is much harder than commonly thought, with power-law index around 1.5 instead of the canonical 2.5. The radio spectra peak at high frequencies and exhibit a variety of shapes. For a small set of low-z sources, we find a spectral upturn at high frequencies, indicating the presence of intrinsic cold dust. Variability can generally be approximated by achromatic variations, while sources with clear signatures of evolving shocks appear to be limited to the strongest outbursts.

  19. Molecular structure and vibrational spectra of Irinotecan: a density functional theoretical study.

    PubMed

    Chinna Babu, P; Sundaraganesan, N; Sudha, S; Aroulmoji, V; Murano, E

    2012-12-01

    The solid phase FTIR and FT-Raman spectra of Irinotecan have been recorded in the regions 400-4000 and 50-4000 cm(-1), respectively. The spectra were interpreted in terms of fundamentals modes, combination and overtone bands. The structure of the molecule was optimized and the structural characteristics were determined by density functional theory (DFT) using B3LYP method with 6-31G(d) as basis set. The vibrational frequencies were calculated for Irinotecan by DFT method and were compared with the experimental frequencies, which yield good agreement between observed and calculated frequencies. The infrared spectrum was also simulated from the calculated intensities. Besides, molecular electrostatic potential (MEP), frontier molecular orbitals (FMO) analysis were investigated using theoretical calculations. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Signal Frequency Spectra with Audacity®

    ERIC Educational Resources Information Center

    Gailey, Alycia

    2015-01-01

    The primary objective of the activity presented here is to allow students to explore the frequency components of various simple signals, with the ultimate goal of teaching them how to remove unwanted noise from a voice signal. Analysis of the frequency components of a signal allows students to design filters that remove unwanted components of a…

  1. Kinetic energy and scalar spectra in high Rayleigh number axially homogeneous buoyancy driven turbulence

    NASA Astrophysics Data System (ADS)

    Pawar, Shashikant S.; Arakeri, Jaywant H.

    2016-06-01

    Kinetic energy and scalar spectra from the measurements in high Rayleigh number axially homogeneous buoyancy driven turbulent flow are presented. Kinetic energy and concentration (scalar) spectra are obtained from the experiments wherein density difference is created using brine and fresh water and temperature spectra are obtained from the experiments in which heat is used. Scaling of the frequency spectra of lateral and longitudinal velocity near the tube axis is closer to the Kolmogorov-Obukhov scaling, while the scalar spectra show some evidence of dual scaling, Bolgiano-Obukhov scaling followed by Obukhov-Corrsin scaling. These scalings are also observed in the corresponding second order spatial structure functions of velocity and concentration fluctuations.

  2. Polarized Power Spectra from HERA-19 Commissioning Data: Instrument Stability

    NASA Astrophysics Data System (ADS)

    Fox Fortino, Austin; Chichura, Paul; Igarashi, Amy; Kohn, Saul; Aguirre, James; HERA Collaboration

    2018-01-01

    The Epoch of Reionization (EoR) is a key period in the universe’s history, containing the formation of the first galaxies and large scale structures. Foreground emission is the limiting factor in detecting the 21 cm emission from the Epoch of Reionization (EoR). The HERA-19 low frequency radio interferometer aims to reduce the obfuscation from the foreground emission with its dish shaped antennae. We generate polarized 2D (cylindrically averaged) power spectra from seven days of observation from the HERA-19 2016 observation season in each of the four Stokes parameters I, Q, U, and V. These power spectra serve as a potent diagnostic tool that allow us to understand the instrument stability by comparison between nominally redundant baselines, and between observations of nominally the same astrophysical sky on successive days. The power spectra are expected to vary among nominally redundant measurements due to ionosphere fluctuations and thermal changes in the electronics and instrument beam patterns, as well as other factors. In this work we investigate the stability over time of these polarized power spectra, and use them to quantify the variation due to these effects.

  3. Highly Accurate Quantitative Analysis Of Enantiomeric Mixtures from Spatially Frequency Encoded 1H NMR Spectra.

    PubMed

    Plainchont, Bertrand; Pitoux, Daisy; Cyrille, Mathieu; Giraud, Nicolas

    2018-02-06

    We propose an original concept to measure accurately enantiomeric excesses on proton NMR spectra, which combines high-resolution techniques based on a spatial encoding of the sample, with the use of optically active weakly orienting solvents. We show that it is possible to simulate accurately dipolar edited spectra of enantiomers dissolved in a chiral liquid crystalline phase, and to use these simulations to calibrate integrations that can be measured on experimental data, in order to perform a quantitative chiral analysis. This approach is demonstrated on a chemical intermediate for which optical purity is an essential criterion. We find that there is a very good correlation between the experimental and calculated integration ratios extracted from G-SERF spectra, which paves the way to a general method of determination of enantiomeric excesses based on the observation of 1 H nuclei.

  4. The Copernicus observations - Interstellar or circumstellar material. [UV spectra of early stars

    NASA Technical Reports Server (NTRS)

    Steigman, G.; Strittmatter, P. A.; Williams, R. E.

    1975-01-01

    It is suggested that the sharp absorption lines observed in the ultraviolet spectra of early-type stars by the Copernicus satellite may be entirely accounted for by the circumstellar material in the H II regions and associated transition zones around the observed stars. If this interpretation is correct, the Copernicus results yield little information on the state of any interstellar (as opposed to circumstellar) gas and, in particular, shed little light on the degree of element depletion in interstellar space.

  5. Vibrational investigation on FT-IR and FT-Raman spectra, IR intensity, Raman activity, peak resemblance, ideal estimation, standard deviation of computed frequencies analyses and electronic structure on 3-methyl-1,2-butadiene using HF and DFT (LSDA/B3LYP/B3PW91) calculations.

    PubMed

    Ramalingam, S; Jayaprakash, A; Mohan, S; Karabacak, M

    2011-11-01

    FT-IR and FT-Raman (4000-100 cm(-1)) spectral measurements of 3-methyl-1,2-butadiene (3M12B) have been attempted in the present work. Ab-initio HF and DFT (LSDA/B3LYP/B3PW91) calculations have been performed giving energies, optimized structures, harmonic vibrational frequencies, IR intensities and Raman activities. Complete vibrational assignments on the observed spectra are made with vibrational frequencies obtained by HF and DFT (LSDA/B3LYP/B3PW91) at 6-31G(d,p) and 6-311G(d,p) basis sets. The results of the calculations have been used to simulate IR and Raman spectra for the molecule that showed good agreement with the observed spectra. The potential energy distribution (PED) corresponding to each of the observed frequencies are calculated which confirms the reliability and precision of the assignment and analysis of the vibrational fundamentals modes. The oscillation of vibrational frequencies of butadiene due to the couple of methyl group is also discussed. A study on the electronic properties such as HOMO and LUMO energies, were performed by time-dependent DFT (TD-DFT) approach. The calculated HOMO and LUMO energies show that charge transfer occurs within the molecule. The thermodynamic properties of the title compound at different temperatures reveal the correlations between standard heat capacities (C) standard entropies (S), and standard enthalpy changes (H). Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

  6. Observations of frequency shift associated with schooling fish

    NASA Astrophysics Data System (ADS)

    Diachok, Orest

    2003-04-01

    The number of sardines per school, N, is nominally 10000 and the separation between sardines in school, s, is nominally 1 fish length, L.s is much smaller than the wavelength at f (the resonance frequency of individuals), which suggests that schools may exhibit acoustic properties of bubble clouds. Long-term, broadband transmission loss measurements at a shallow-water site in the Gulf of Lion revealed absorption lines due to dispersed sardines at 1.3 kHz at 20 m at night and 2.7 kHz at 65 m at dawn. Temporal changes in observed values of f were consistent with concurrent echo sounder observations of the vertical migration of sardines, and theoretical computations based on laboratory measurements of swim bladder dimensions. The measured resonance frequency of sardines in schools during daytime, 1.7 kHz at 65 m, was 0.6f at the same depth at dawn. The observed frequency shift is consistent with a hybrid model of the fundamental resonance frequency of a bubble cloud, which is based on theories developed by Feuillade, Nero, and Love (1996) and dAgostino and Brennan (1988), and s=0.8 L and N=5000 fish per school. [Work supported by ONR.

  7. Low frequency vibrational spectra and the nature of metal-oxygen bond of alkaline earth metal acetylacetonates

    NASA Astrophysics Data System (ADS)

    Fakheri, Hamideh; Tayyari, Sayyed Faramarz; Heravi, Mohammad Momen; Morsali, Ali

    2017-12-01

    Theoretical quantum chemistry calculations were used to assign the observed vibrational band frequencies of Be, Mg, Ca, Sr, and Ba acetylacetonates complexes. Density functional theory (DFT) calculations have been carried out at the B3LYP level, using LanL2DZ, def2SVP, and mixed, GenECP, (def2SVP for metal ions and 6-311++G** for all other atoms) basis sets. The B3LYP level, with mixed basis sets, was utilized for calculations of vibrational frequencies, IR intensity, and Raman activity. Analysis of the vibrational spectra indicates that there are several bands which could almost be assigned mainly to the metal-oxygen vibrations. The strongest Raman band in this region could be used as a measure of the stability of the complex. The effects of central metal on the bond orders and charge distributions in alkaline earth metal acetylacetonates were studied by the Natural Bond Orbital (NBO) method for fully optimized compounds. Optimization were performed at the B3LYP/6-311++G** level for the lighter alkaline earth metal complexes (Be, Mg, and Ca acetylacetonates) while the B3LYP level, using LanL2DZ (extrabasis, d and f on oxygen and metal atoms), def2SVP and mixed (def2SVP on metal ions and 6-311++G** for all other atoms) basis sets for all understudy complexes. Calculations indicate that the covalence nature of metal-oxygen bonds considerably decreases from Be to Ba complexes. The nature of metal-oxygen bond was further studied by using Atoms In Molecules (AIM) analysis. The topological parameters, Wiberg bond orders, natural charges of O and metal ions, and also some vibrational band frequencies were correlated with the stability constants of understudy complexes.

  8. Theory of Parabolic Arcs in Interstellar Scintillation Spectra

    NASA Astrophysics Data System (ADS)

    Cordes, James M.; Rickett, Barney J.; Stinebring, Daniel R.; Coles, William A.

    2006-01-01

    Interstellar scintillation (ISS), observed as time variation in the intensity of a compact radio source, is caused by small-scale structure in the electron density of the interstellar plasma. Dynamic spectra of ISS show modulation in radio frequency and time. Here we relate the (two-dimensional) power spectrum of the dynamic spectrum-the secondary spectrum-to the scattered image of the source. Recent work has identified remarkable parabolic arcs in secondary spectra. Each point in a secondary spectrum corresponds to interference between points in the scattered image with a certain Doppler shift and a certain delay. The parabolic arc corresponds to the quadratic relation between differential Doppler shift and delay through their common dependence on scattering angle. We show that arcs will occur in all media that scatter significant power at angles larger than the rms angle. Thus, effects such as source diameter, steep spectra, and dissipation scales, which truncate high angle scattering, also truncate arcs. Arcs are equally visible in simulations of nondispersive scattering. They are enhanced by anisotropic scattering when the spatial structure is elongated perpendicular to the velocity. In weak scattering the secondary spectrum is directly mapped from the scattered image, and this mapping can be inverted. We discuss additional observed phenomena including multiple arcs and reverse arclets oriented oppositely to the main arc. These phenomena persist for many refractive scattering times, suggesting that they are due to large-scale density structures, rather than low-frequency components of Kolmogorov turbulence.

  9. Complex permeability and permittivity spectra of percolated Fe50Co50/Cu granular composites

    NASA Astrophysics Data System (ADS)

    Massango, Herieta; Tsutaoka, Takanori; Kasagi, Teruhiro; Yamamoto, Shinichiro; Hatakeyama, Kenichi

    2017-11-01

    Complex permeability and permittivity spectra of Fe50Co50/Cu hybrid granular composite materials have been studied in the RF to microwave frequency range. At low Cu particle content, the Fe50Co50/Cu hybrid sample shows a metallic percolative property with the electrical conductivity value about 0.1 S/cm. However, the low frequency plasmonic (LFP) state with negative permittivity (ENG) spectrum was not observed. An abrupt increase of electrical conductivity takes place at 14 to 16 vol% Cu content where the conductivity becomes above 1.0 S/cm; the Fe50Co50/Cu composite possesses the LFP state with negative permittivity spectrum below a characteristic frequency. The complex permittivity spectra in the LFP state can be described by the Drude model. Magnetic permeability spectrum in the LFP state showed a broad frequency dispersion above 10 MHz; a small negative permeability (MNG) dispersion was observed from 2 to 10 GHz. Consequently, the double negative (DNG) electromagnetic property with MNG and ENG was realized in the microwave range for the Cu content of 26 and 30 vol%.

  10. Low Frequency Oscillations in Assimilated Global Datasets Using TRMM Rainfall Observations

    NASA Technical Reports Server (NTRS)

    Tao, Li; Yang, Song; Zhang, Zhan; Hou, Arthur; Olson, William S.

    2004-01-01

    Global datasets for the period May-August 1998 from the Goddard Earth Observing System (GEOS) data assimilation system (DAS) with/without assimilated Tropical Rainfall Measuring Mission (TRMM) precipitation are analyzed against European Center for Medium-Range Weather Forecast (ECMWF) output, NOAA observed outgoing longwave radiation (OLR) data, and TRMM measured rainfall. The purpose of this study is to investigate the representation of the Madden-Julian Oscillation (MJO) in GEOS assimilated global datasets, noting the impact of TRMM observed rainfall on the MJO in GEOS data assimilations. A space-time analysis of the OLR data indicates that the observed OLR exhibits a spectral maximum for eastward-propagating wavenumber 1-3 disturbances with periods of 20-60 days in the 0deg-30degN latitude band. The assimilated OLR has a similar feature but with a smaller magnitude. However, OLR spectra from assimilations including TRMM rainfall data show better agreement with observed OLR spectra than spectra from assimilations without TRMM rainfall. Similar results are found for wavenumber 4-6 disturbances. There is a spectral peak for eastward-propagating wavenumber 4-6 disturbances with periods of 20-40 days near the equator, while for westward-moving disturbances, a spectral peak is noted for periods of 30-50 days near 25degN. To isolate the MJO, a 30-50 day band filter is selected for this study. It was found that the eastward-propagating waves from the band-filtered observed OLR between 10degs- 10degN are located in the eastern hemisphere. Similar patterns are evident in surface rainfall and the 850 hPa wind field. Assimilation of TRMM-observed rainfall reveals more distinct MJO features in the analysis than without rainfall assimilation. Similar analyses are also conducted over the Indian summer monsoon and East Asia summer monsoon regions, where the MJO is strongly related to the summer monsoon active-break patterns.

  11. Influence of molecular electronic properties on the IR spectra of dimeric hydrogen bond systems: polarized spectra of 2-hydroxybenzothiazole and 2-mercaptobenzothiazole crystals

    NASA Astrophysics Data System (ADS)

    Flakus, Henryk T.; Miros, Artur; Jones, Peter G.

    2002-01-01

    We have studied the polarized IR spectra of the hydrogen-bonded molecular crystals of 2-hydroxybenzothiazole (HBT) and 2-mercaptobenzothiazole (MBT). The crystal structure of 2-hydroxybenzothiazole was determined by X-ray diffraction. The polarized spectra of the crystals were measured, in the frequency ranges of the νN-H and νN-D bands, at room temperature, and at 77 K. In both systems an extremely strong H/D isotopic effect in the spectra was observed, involving reduction of the well-developed νN-H band fine structure to a single prominent νN-D line only. The two νN-H bands were also shown to exhibit almost identical properties, band shapes, temperature and dichroic properties included. The spectra were quantitatively reconstituted, along with the strong isotopic effect, when calculated using the 'strong-coupling' theory, assuming the centrosymmetric dimers of HBT or MBT to be the structural units responsible for the crystalline spectral properties. The similarity of the spectra of the two crystalline systems was considered to be a result of longer-distance couplings between the proton vibrations in the dimers, via the aromatic ring electrons. When investigating the 'residual' νN-H band shapes for crystals isotopically diluted by deuterium, we observed some 'self-organization' effects in the spectra, indicating the energetically favored presence of two identical hydrogen isotopes in each hydrogen bond dimer.

  12. Observed emotion frequency versus intensity as predictors of socioemotional maladjustment.

    PubMed

    Hernández, Maciel M; Eisenberg, Nancy; Valiente, Carlos; Spinrad, Tracy L; VanSchyndel, Sarah K; Diaz, Anjolii; Berger, Rebecca H; Silva, Kassondra M; Southworth, Jody; Piña, Armando A

    2015-12-01

    The purpose of this study was to assess whether observed emotional frequency (the proportion of instances an emotion was observed) and intensity (the strength of an emotion when it was observed) uniquely predicted kindergartners' (N = 301) internalizing and externalizing problems. Analyses were tested in a structural equation modeling (SEM) framework with data from multireporters (reports of problem behaviors from teachers and parents) and naturalistic observations of emotion in the fall semester. For observed positive emotion, both frequency and intensity negatively predicted parent- or teacher-reported internalizing symptoms. Anger frequency positively predicted parent- and teacher-reported externalizing symptoms, whereas anger intensity positively predicted parent- and teacher-reported externalizing and parent-reported internalizing symptoms. The findings support the importance of examining both aspects of emotion when predicting maladjustment. (c) 2015 APA, all rights reserved).

  13. Dielectric constant and low-frequency infrared spectra for liquid water and ice Ih within the E3B model

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shi, L.; Ni, Y.; Drews, S. E. P.

    2014-08-28

    Two intrinsic difficulties in modeling condensed-phase water with conventional rigid non-polarizable water models are: reproducing the static dielectric constants for liquid water and ice Ih, and generating the peak at about 200 cm{sup −1} in the low-frequency infrared spectrum for liquid water. The primary physical reason for these failures is believed to be the missing polarization effect in these models, and consequently various sophisticated polarizable water models have been developed. However, in this work we pursue a different strategy and propose a simple empirical scheme to include the polarization effect only on the dipole surface (without modifying a model's intermolecularmore » interaction potential). We implement this strategy for our explicit three-body (E3B) model. Our calculated static dielectric constants and low-frequency infrared spectra are in good agreement with experiment for both liquid water and ice Ih over wide temperature ranges, albeit with one fitting parameter for each phase. The success of our modeling also suggests that thermal fluctuations about local minima and the energy differences between different proton-disordered configurations play minor roles in the static dielectric constant of ice Ih. Our analysis shows that the polarization effect is important in resolving the two difficulties mentioned above and sheds some light on the origin of several features in the low-frequency infrared spectra for liquid water and ice Ih.« less

  14. Dielectric constant and low-frequency infrared spectra for liquid water and ice Ih within the E3B model.

    PubMed

    Shi, L; Ni, Y; Drews, S E P; Skinner, J L

    2014-08-28

    Two intrinsic difficulties in modeling condensed-phase water with conventional rigid non-polarizable water models are: reproducing the static dielectric constants for liquid water and ice Ih, and generating the peak at about 200 cm(-1) in the low-frequency infrared spectrum for liquid water. The primary physical reason for these failures is believed to be the missing polarization effect in these models, and consequently various sophisticated polarizable water models have been developed. However, in this work we pursue a different strategy and propose a simple empirical scheme to include the polarization effect only on the dipole surface (without modifying a model's intermolecular interaction potential). We implement this strategy for our explicit three-body (E3B) model. Our calculated static dielectric constants and low-frequency infrared spectra are in good agreement with experiment for both liquid water and ice Ih over wide temperature ranges, albeit with one fitting parameter for each phase. The success of our modeling also suggests that thermal fluctuations about local minima and the energy differences between different proton-disordered configurations play minor roles in the static dielectric constant of ice Ih. Our analysis shows that the polarization effect is important in resolving the two difficulties mentioned above and sheds some light on the origin of several features in the low-frequency infrared spectra for liquid water and ice Ih.

  15. Simulation of IR and Raman spectra of p-hydroxyanisole and p-nitroanisole based on scaled DFT force fields and their vibrational assignments.

    PubMed

    Krishnakumar, V; Prabavathi, N

    2009-09-15

    This work deals with the vibrational spectroscopy of p-hydroxyanisole (PHA) and p-nitroanisole (PNA) by means of quantum chemical calculations. The mid and far FT-IR and FT-Raman spectra were recorded in the condensed state. The fundamental vibrational frequencies and intensity of vibrational bands were evaluated using density functional theory (DFT) with the standard B3LYP/6-31G* method and basis set combination and were scaled using various scale factors which yield a good agreement between observed and calculated frequencies. The vibrational spectra were interpreted with the aid of normal coordinate analysis based on scaled density functional force field. The results of the calculations were applied to simulate infrared and Raman spectra of the title compounds, which showed excellent agreement with the observed spectra.

  16. Quantitative Interpretation of Polarization SFG Vibrational Spectra of Air/Methanol Interface

    NASA Astrophysics Data System (ADS)

    Wu, Hui; Zhang, Wen-kai; Gan, Wei; Cui, Zhi-feng; Wang, Hong-fei

    2006-06-01

    Even though in IR and Raman spectra of liquid methanol there is always an apparent feature for the asymmetric stretching mode of the CH3 group around 2970 cm-1, this feature has not been observed in the Sum Frequency Generation Vibrational Spectroscopy (SFG-VS) in any polarizations from the air/methanol interface. Here we present a treatment based on a corrected bond additivity model to quantitatively interpret the SFG-VS of the air/methanol interface from the IR and Raman spectra of liquid methanol.

  17. Nearby Supernova Factory Observations of SN 2006D: On SporadicCarbon Signatures in Early Type Ia Supernova Spectra

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Thomas, R.C.; Aldering, G.; Antilogus, P.

    2006-10-12

    We present four spectra of the Type Ia supernova SN Ia 2006Dextending from -7 to +13 days with respect to B-band maximum. The spectrainclude the strongest signature of unburned material at photosphericvelocities observed in a SN Ia to date. The earliest spectrum exhibits CII absorption features below 14,000 km/s, including a distinctive C IIlambda 6580 absorption feature. The carbon signatures dissipate as the SNapproaches peak brightness. In addition to discussing implications ofphotospheric-velocity carbon for white dwarf explosion models, we outlinesome factors that may influence the frequency of its detection before andaround peak brightness. Two effects are explored in this regard,includingmore » depopulation of the C II optical levels by non-LTE effects, andline-of-sight effects resulting from a clumpy distribution of unburnedmaterial with low volume-filling factor.« less

  18. Radio synchrotron spectra of star-forming galaxies

    NASA Astrophysics Data System (ADS)

    Klein, U.; Lisenfeld, U.; Verley, S.

    2018-03-01

    We investigated the radio continuum spectra of 14 star-forming galaxies by fitting nonthermal (synchrotron) and thermal (free-free) radiation laws. The underlying radio continuum measurements cover a frequency range of 325 MHz to 24.5 GHz (32 GHz in case of M 82). It turns out that most of these synchrotron spectra are not simple power-laws, but are best represented by a low-frequency spectrum with a mean slope αnth = 0.59 ± 0.20 (Sν ∝ ν-α), and by a break or an exponential decline in the frequency range of 1-12 GHz. Simple power-laws or mildly curved synchrotron spectra lead to unrealistically low thermal flux densities, and/or to strong deviations from the expected optically thin free-free spectra with slope αth = 0.10 in the fits. The break or cutoff energies are in the range of 1.5-7 GeV. We briefly discuss the possible origin of such a cutoff or break. If the low-frequency spectra obtained here reflect the injection spectrum of cosmic-ray electrons, they comply with the mean spectral index of Galactic supernova remnants. A comparison of the fitted thermal flux densities with the (foreground-corrected) Hα fluxes yields the extinction, which increases with metallicity. The fraction of thermal emission is higher than believed hitherto, especially at high frequencies, and is highest in the dwarf galaxies of our sample, which we interpret in terms of a lack of containment in these low-mass systems, or a time effect caused by a very young starburst.

  19. Experimental observation of multi-scale interactions among kink /tearing modes and high-frequency fluctuations in the HL-2A core NBI plasmas

    NASA Astrophysics Data System (ADS)

    Chen, W.; Jiang, M.; Xu, Y.; Shi, P. W.; Yu, L. M.; Ding, X. T.; Shi, Z. B.; Ji, X. Q.; Yu, D. L.; Li, Y. G.; Yang, Z. C.; Zhong, W. L.; Qiu, Z. Y.; Li, J. Q.; Dong, J. Q.; Yang, Q. W.; Liu, Yi.; Yan, L. W.; Xu, M.; Duan, X. R.

    2017-11-01

    Multi-scale interactions have been observed recently in the HL-2A core NBI plasmas, including the synchronous coupling between m/n=1/1 kink mode and m/n=2/1 tearing mode, nonlinear couplings of TAE/BAE and m/n=2/1 TM near q=2 surface, AITG/KBM/BAE and m/n=1/1 kink mode near q=1 surface, and between m/n=1/1 kink mode and high-frequency turbulence. Experimental results suggest that several couplings can exist simultaneously, Alfvenic fluctuations have an important contribution to the high-frequency turbulence spectra, and the couplings reveal the electromagnetic character. Multi-scale interactions via the nonlinear modulation process maybe enhance plasma transport and trigger sawtooth-crash onset.

  20. An analysis of short pulse and dual frequency radar techniques for measuring ocean wave spectra from satellites

    NASA Technical Reports Server (NTRS)

    Jackson, F. C.

    1980-01-01

    Scanning beam microwave radars were used to measure ocean wave directional spectra from satellites. In principle, surface wave spectral resolution in wave number can be obtained using either short pulse (SP) or dual frequency (DF) techniques; in either case, directional resolution obtains naturally as a consequence of a Bragg-like wave front matching. A four frequency moment characterization of backscatter from the near vertical using physical optics in the high frequency limit was applied to an analysis of the SP and DF measurement techniques. The intrinsic electromagnetic modulation spectrum was to the first order in wave steepness proportional to the large wave directional slope spectrum. Harmonic distortion was small and was a minimum near 10 deg incidence. NonGaussian wave statistics can have an effect comparable to that in the second order of scattering from a normally distributed sea surface. The SP technique is superior to the DF technique in terms of measurement signal to noise ratio and contrast ratio.

  1. LOW-FREQUENCY OBSERVATIONS OF THE MOON WITH THE MURCHISON WIDEFIELD ARRAY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McKinley, B.; Briggs, F.; Kaplan, D. L.

    2013-01-01

    A new generation of low-frequency radio telescopes is seeking to observe the redshifted 21 cm signal from the epoch of reionization (EoR), requiring innovative methods of calibration and imaging to overcome the difficulties of wide-field low-frequency radio interferometry. Precise calibration will be required to separate the expected small EoR signal from the strong foreground emission at the frequencies of interest between 80 and 300 MHz. The Moon may be useful as a calibration source for detection of the EoR signature, as it should have a smooth and predictable thermal spectrum across the frequency band of interest. Initial observations of themore » Moon with the Murchison Widefield Array 32 tile prototype show that the Moon does exhibit a similar trend to that expected for a cool thermally emitting body in the observed frequency range, but that the spectrum is corrupted by reflected radio emission from Earth. In particular, there is an abrupt increase in the observed flux density of the Moon within the internationally recognized frequency modulated (FM) radio band. The observations have implications for future low-frequency surveys and EoR detection experiments that will need to take this reflected emission from the Moon into account. The results also allow us to estimate the equivalent isotropic power emitted by the Earth in the FM band and to determine how bright the Earth might appear at meter wavelengths to an observer beyond our own solar system.« less

  2. Planck intermediate results: XLV. Radio spectra of northern extragalactic radio sources

    DOE PAGES

    Ade, P. A. R.; Aghanim, N.; Aller, H. D.; ...

    2016-12-12

    Continuum spectra covering centimetre to submillimetre wavelengths are presented in this paper for a northern sample of 104 extragalactic radio sources, mainly active galactic nuclei, based on four-epoch Planck data. The nine Planck frequencies, from 30 to 857 GHz, are complemented by a set of simultaneous ground-based radio observations between 1.1 and 37 GHz. The single-survey Planck data confirm that the flattest high-frequency radio spectral indices are close to zero, indicating that the original accelerated electron energy spectrum is much harder than commonly thought, with power-law index around 1.5 instead of the canonical 2.5. The radio spectra peak at highmore » frequencies and exhibit a variety of shapes. For a small set of low-z sources, we find a spectral upturn at high frequencies, indicating the presence of intrinsic cold dust. Finally, variability can generally be approximated by achromatic variations, while sources with clear signatures of evolving shocks appear to be limited to the strongest outbursts.« less

  3. Planck intermediate results: XLV. Radio spectra of northern extragalactic radio sources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ade, P. A. R.; Aghanim, N.; Aller, H. D.

    Continuum spectra covering centimetre to submillimetre wavelengths are presented in this paper for a northern sample of 104 extragalactic radio sources, mainly active galactic nuclei, based on four-epoch Planck data. The nine Planck frequencies, from 30 to 857 GHz, are complemented by a set of simultaneous ground-based radio observations between 1.1 and 37 GHz. The single-survey Planck data confirm that the flattest high-frequency radio spectral indices are close to zero, indicating that the original accelerated electron energy spectrum is much harder than commonly thought, with power-law index around 1.5 instead of the canonical 2.5. The radio spectra peak at highmore » frequencies and exhibit a variety of shapes. For a small set of low-z sources, we find a spectral upturn at high frequencies, indicating the presence of intrinsic cold dust. Finally, variability can generally be approximated by achromatic variations, while sources with clear signatures of evolving shocks appear to be limited to the strongest outbursts.« less

  4. Detection of changes of high-frequency activity by statistical time-frequency analysis in epileptic spikes

    PubMed Central

    Kobayashi, Katsuhiro; Jacobs, Julia; Gotman, Jean

    2013-01-01

    Objective A novel type of statistical time-frequency analysis was developed to elucidate changes of high-frequency EEG activity associated with epileptic spikes. Methods The method uses the Gabor Transform and detects changes of power in comparison to background activity using t-statistics that are controlled by the false discovery rate (FDR) to correct type I error of multiple testing. The analysis was applied to EEGs recorded at 2000 Hz from three patients with mesial temporal lobe epilepsy. Results Spike-related increase of high-frequency oscillations (HFOs) was clearly shown in the FDR-controlled t-spectra: it was most dramatic in spikes recorded from the hippocampus when the hippocampus was the seizure onset zone (SOZ). Depression of fast activity was observed immediately after the spikes, especially consistently in the discharges from the hippocampal SOZ. It corresponded to the slow wave part in case of spike-and-slow-wave complexes, but it was noted even in spikes without apparent slow waves. In one patient, a gradual increase of power above 200 Hz preceded spikes. Conclusions FDR-controlled t-spectra clearly detected the spike-related changes of HFOs that were unclear in standard power spectra. Significance We developed a promising tool to study the HFOs that may be closely linked to the pathophysiology of epileptogenesis. PMID:19394892

  5. Infrared Spectra of Polycyclic Aromatic Hydrocarbons: Nitrogen Substitution

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W.; Arnold, James O. (Technical Monitor)

    1998-01-01

    The B3LYP/4-31G approach is used to compute the harmonic frequencies of substituted naphthalene, anthracene, and their cations. The substitutions include cyano (CN), aminio (NH2), imino (NH), and replacement of a CH group by a nitrogen atom. All unique sites are considered, namely 1 and 2 for naphthalene and 1, 2, and 9 for an'tracene, except for the imino, where only 2-iminonaphthalene is studied. The IR spectra of these substituted species are compared with those of the unsubstituted molecules. The addition of a CN group does not significantly affect the spectra except to add the CN stretching frequency. Replacing a CH group by N has only a small effect on the IR spectra. The addition of the NH2 group dramatically affects the neutral spectra, giving it much of the character of the cation spectra. However, the neutral 2-irrinonaphthalene spectra looks more like that of naphthalene than like the 2-aminonaphthalene spectra.

  6. Identifying Broadband Rotational Spectra with Neural Networks

    NASA Astrophysics Data System (ADS)

    Zaleski, Daniel P.; Prozument, Kirill

    2017-06-01

    A typical broadband rotational spectrum may contain several thousand observable transitions, spanning many species. Identifying the individual spectra, particularly when the dynamic range reaches 1,000:1 or even 10,000:1, can be challenging. One approach is to apply automated fitting routines. In this approach, combinations of 3 transitions can be created to form a "triple", which allows fitting of the A, B, and C rotational constants in a Watson-type Hamiltonian. On a standard desktop computer, with a target molecule of interest, a typical AUTOFIT routine takes 2-12 hours depending on the spectral density. A new approach is to utilize machine learning to train a computer to recognize the patterns (frequency spacing and relative intensities) inherit in rotational spectra and to identify the individual spectra in a raw broadband rotational spectrum. Here, recurrent neural networks have been trained to identify different types of rotational spectra and classify them accordingly. Furthermore, early results in applying convolutional neural networks for spectral object recognition in broadband rotational spectra appear promising. Perez et al. "Broadband Fourier transform rotational spectroscopy for structure determination: The water heptamer." Chem. Phys. Lett., 2013, 571, 1-15. Seifert et al. "AUTOFIT, an Automated Fitting Tool for Broadband Rotational Spectra, and Applications to 1-Hexanal." J. Mol. Spectrosc., 2015, 312, 13-21. Bishop. "Neural networks for pattern recognition." Oxford university press, 1995.

  7. The ratio between corner frequencies of source spectra of P- and S-waves—a new discriminant between earthquakes and quarry blasts

    NASA Astrophysics Data System (ADS)

    Ataeva, G.; Gitterman, Y.; Shapira, A.

    2017-01-01

    This study analyzes and compares the P- and S-wave displacement spectra from local earthquakes and explosions of similar magnitudes. We propose a new approach to discrimination between low-magnitude shallow earthquakes and explosions by using ratios of P- to S-wave corner frequencies as a criterion. We have explored 2430 digital records of the Israeli Seismic Network (ISN) from 456 local events (226 earthquakes, 230 quarry blasts, and a few underwater explosions) of magnitudes Md = 1.4-3.4, which occurred at distances up to 250 km during 2001-2013 years. P-wave and S-wave displacement spectra were computed for all events following Brune's source model of earthquakes (1970, 1971) and applying the distance correction coefficients (Shapira and Hofstetter, Teconophysics 217:217-226, 1993; Ataeva G, Shapira A, Hofstetter A, J Seismol 19:389-401, 2015), The corner frequencies and moment magnitudes were determined using multiple stations for each event, and then the comparative analysis was performed.

  8. Turbulence in planetary occultations. IV - Power spectra of phase and intensity fluctuations

    NASA Technical Reports Server (NTRS)

    Haugstad, B. S.

    1979-01-01

    Power spectra of phase and intensity scintillations during occultation by turbulent planetary atmospheres are significantly affected by the inhomogeneous background upon which the turbulence is superimposed. Such coupling is particularly pronounced in the intensity, where there is also a marked difference in spectral shape between a central and grazing occultation. While the former has its structural features smoothed by coupling to the inhomogeneous background, such features are enhanced in the latter. Indeed, the latter power spectrum peaks around the characteristic frequency that is determined by the size of the free-space Fresnel zone and the ray velocity in the atmosphere; at higher frequencies strong fringes develop in the power spectrum. A confrontation between the theoretical scintillation spectra computed here and those calculated from the Mariner 5 Venus mission by Woo et al. (1974) is inconclusive, mainly because of insufficient statistical resolution. Phase and/or intensity power spectra computed from occultation data may be used to deduce characteristics of the turbulence and to distinguish turbulence from other perturbations in the refractive index. Such determinations are facilitated if observations are made at two or more frequencies (radio occultation) or in two or more colors (stellar occultation).

  9. Frequency spectrum of tantalum at temperatures of 293-2300 K

    NASA Astrophysics Data System (ADS)

    Semenov, V. A.; Kozlov, Zh. A.; Krachun, L.; Mateescu, G.; Morozov, V. M.; Oprea, A. I.; Oprea, K.; Puchkov, A. V.

    2010-05-01

    The temperature dependence of the frequency spectrum of tantalum in the temperature range from room temperature to 2300 K has been studied for the first time using inelastic slow-neutron scattering. The inelastic slow-neutron scattering spectra have been measured at different temperatures on a DIN-2PI time-of-flight spectrometer installed at the IBR-2 nuclear reactor (Joint Institute for Nuclear Research, Dubna, Russia) with the use of a TS3000K high-temperature thermostat. From the measured spectra, the frequency spectra of the tantalum crystal lattice have been determined at temperatures of 293, 1584, and 2300 K by the iteration method. As the temperature increases, the frequency spectrum, on the whole, is softened and the specific features manifested themselves at room temperature are smoothed. The variations observed have been explained by the increase in the role of the effects of vibration anharmonism at high temperatures.

  10. Linking snowflake microstructure to multi-frequency radar observations

    NASA Astrophysics Data System (ADS)

    Leinonen, J.; Moisseev, D.; Nousiainen, T.

    2013-04-01

    Spherical or spheroidal particle shape models are commonly used to calculate numerically the radar backscattering properties of aggregate snowflakes. A more complicated and computationally intensive approach is to use detailed models of snowflake structure together with numerical scattering models that can operate on arbitrary particle shapes. Recent studies have shown that there can be significant differences between the results of these approaches. In this paper, an analytical model, based on the Rayleigh-Gans scattering theory, is formulated to explain this discrepancy in terms of the effect of discrete ice crystals that constitute the snowflake. The ice crystals cause small-scale inhomogeneities whose effects can be understood through the density autocorrelation function of the particle mass, which the Rayleigh-Gans theory connects to the function that gives the radar reflectivity as a function of frequency. The derived model is a weighted sum of two Gaussian functions. A term that corresponds to the average shape of the particle, similar to that given by the spheroidal shape model, dominates at low frequencies. At high frequencies, that term vanishes and is gradually replaced by the effect of the ice crystal monomers. The autocorrelation-based description of snowflake microstructure appears to be sufficient for multi-frequency radar studies. The link between multi-frequency radar observations and the particle microstructure can thus be used to infer particle properties from the observations.

  11. Study of solar wind spectra by nonlinear waves interaction

    NASA Astrophysics Data System (ADS)

    Dwivedi, Navin; Sharma, Rampal; Narita, Yasuhito

    2014-05-01

    The nature of small-scale turbulent fluctuations in the solar wind (SW) turbulence is a topic that is being investigated extensively nowadays, both theoretically and observationally. Although recent observations predict the evidence of the dominance of kinetic Alfvén waves (KAW) at sub-ion scales with frequency below than ion cyclotron frequency, while other studies suggest that the KAW mode cannot carry the turbulence cascade down to electron scales and that the whistler mode is more relevant. In the present work, nonlinear interaction of kinetic Alfvén wave with whistler wave is considered as one of the possible cause responsible for the solar wind turbulence. A set of coupled dimensionless equations are derived for the intermediate beta plasmas and the nonlinear interaction between these two wave modes has been studied. As a consequence of ponderomotive nonlinearity, the pump KAW becomes filamented when its power exceeds the threshold for the filamentation instability. Whistler is considered to be weak and thus doesn't have enough intensity to initiate its own localization. It gets localized while propagating through the density channel created by KAW localization. In addition, spectral scales of power spectra of KAW and whistler are also calculated. The steeper spectra are found with scaling greater than -5/3. This type of nonlinear interaction between different wave modes and steeper spectra is one of the reasons for the solar wind turbulence and particles acceleration. This work is partially supported by DST (India) and FP7/STORM (313038)

  12. High Frequency Radio Observations of the Reactivated Magnetar PSR J1622-4950

    NASA Astrophysics Data System (ADS)

    Pearlman, Aaron B.; Majid, Walid A.; Prince, Thomas A.; Horiuchi, Shinji; Kocz, Jonathon; Lazio, T. J. W.; Naudet, Charles J.

    2017-07-01

    Radio emission from the magnetar PSR J1622-4950 was recently reported to have resumed (Camilo et al., ATel #10346). We have carried out Target of Opportunity (ToO) radio observations of PSR J1622-4950 at S-band (2.3 GHz) and X-band (8.4 GHz) using the 70-m diameter Deep Space Network (DSN) radio dish (DSS-43) in Canberra, Australia. We report on our single polarization mode observations of PSR J1622-4950 spanning 5 hours on 23 May 2017 starting at 16:03:32 UTC. Pulsations were detected at a period of 4.327308(1) s. We measure a mean flux density of 3.8(8)/0.41(8) mJy at S/X-band, from which we derive a spectral index of -1.7(2). We note that PSR J1622-4950's spectral behavior is now consistent with the majority of pulsars, which have a mean spectral index of -1.8(2) (Maron et al. (2000)). The result by Maron et al. (2000) is used here because they included more high frequency pulsar spectra than other studies to characterize the underlying spectral index distribution over a wide frequency range. The mean flux density at S-band has now increased by an order of magnitude compared to previous flux density measurements by Scholz et al. (2017) during the magnetar's quiescent state. Furthermore, the spectral index has steepened compared to a nearly flat spectral index from flux density measurements between 1.4 and 24 GHz prior to the disappearance of the radio emission (Levin et al. (2010); Keith et al. (2011); Levin et al. (2012); Anderson et al. (2012); Scholz et al. (2017)). We are continuing to monitor changes in PSR J1622-4950's radio spectrum at both S-band and X-band. We thank the DSN (Deep Space Network) and Canberra Deep Space Communication Complex (CDSCC) teams for scheduling these observations.

  13. Faraday rotation fluctutation spectra observed during solar occultation of the Helios spacecraft

    NASA Technical Reports Server (NTRS)

    Andreev, V.; Efimov, A. I.; Samoznaev, L.; Bird, M. K.

    1995-01-01

    Faraday rotation (FR) measurements using linearly polarized radio signals from the two Helios spacecraft were carried out during the period from 1975 to 1984. This paper presents the results of a spectral analysis of the Helios S-band FR fluctuations observed at heliocentric distances from 2.6 to 15 solar radii during the superior conjunctions 1975-1983. The mean intensity of the FR fluctuations does not exceed the noise level for solar offsets greater than ca. 15 solar radii. The rms FR fluctuation amplitude increases rapidly as the radio ray path approaches the Sun, varying according to a power law (exponent: 2.85 +/- 0.15) at solar distances 4-12 solar radii. At distances inside 4 solar radii the increase is even steeper (exponent: 5.6 +/- 0.2). The equivalent two-dimensional FR fluctuation spectrum is well modeled by a single power-law over the frequency range from 5 to 50 mHz. For heliocentric distances larger than 4 solar radii the spectral index varies between 1.1 and 1.6 with a mean value of 1.4 +/- 0.2, corresponding to a 3-D spectral index p = 2.4. FR fluctuations thus display a somwhat lower spectral index compared with phase and amplitude fluctuations. Surprisingly high values of the spectral index were found for measurements inside 4 solar radii (p = 2.9 +/- 0.2). This may arise from the increasingly dominant effect of the magnetic field on radio wave propagation at small solar offsets. Finally, a quasiperiodic component, believed to be associated with Alfven waves, was discovered in some (but not all!) fluctuation spectra observed simultaneously at two ground stations. Characteristic periods and bulk velocities of this component were 240 +/- 30 sec and 300 +/- 60 km/s, respectively.

  14. Non-Gaussian lineshapes and dynamics of time-resolved linear and nonlinear (correlation) spectra.

    PubMed

    Dinpajooh, Mohammadhasan; Matyushov, Dmitry V

    2014-07-17

    Signatures of nonlinear and non-Gaussian dynamics in time-resolved linear and nonlinear (correlation) 2D spectra are analyzed in a model considering a linear plus quadratic dependence of the spectroscopic transition frequency on a Gaussian nuclear coordinate of the thermal bath (quadratic coupling). This new model is contrasted to the commonly assumed linear dependence of the transition frequency on the medium nuclear coordinates (linear coupling). The linear coupling model predicts equality between the Stokes shift and equilibrium correlation functions of the transition frequency and time-independent spectral width. Both predictions are often violated, and we are asking here the question of whether a nonlinear solvent response and/or non-Gaussian dynamics are required to explain these observations. We find that correlation functions of spectroscopic observables calculated in the quadratic coupling model depend on the chromophore's electronic state and the spectral width gains time dependence, all in violation of the predictions of the linear coupling models. Lineshape functions of 2D spectra are derived assuming Ornstein-Uhlenbeck dynamics of the bath nuclear modes. The model predicts asymmetry of 2D correlation plots and bending of the center line. The latter is often used to extract two-point correlation functions from 2D spectra. The dynamics of the transition frequency are non-Gaussian. However, the effect of non-Gaussian dynamics is limited to the third-order (skewness) time correlation function, without affecting the time correlation functions of higher order. The theory is tested against molecular dynamics simulations of a model polar-polarizable chromophore dissolved in a force field water.

  15. Sampling theory for asynoptic satellite observations. I Space-time spectra, resolution, and aliasing. II - Fast Fourier synoptic mapping

    NASA Technical Reports Server (NTRS)

    Salby, M. L.

    1982-01-01

    An evaluation of the information content of asynoptic data taken in the form of nadir sonde and limb scan observations is presented, and a one-to-one correspondence is established between the alias-free data and twice-daily synoptic maps. Attention is given to space and time limitations of sampling and the orbital geometry is discussed. The sampling pattern is demonstrated to determine unique space-time spectra at all wavenumbers and frequencies. Spectral resolution and aliasing are explored, while restrictions on sampling and information content are defined. It is noted that irregular sampling at high latitudes produces spurious contamination effects. An Asynoptic Sampling Theorem is thereby formulated, as is a Synoptic Retrieval Theorem, in the second part of the article. In the latter, a procedure is developed for retrieving the unique correspondence between the asymptotic data and the synoptic maps. Applications examples are provided using data from the Nimbus-6 satellite.

  16. Laboratory mid-IR spectra of equilibrated and igneous meteorites. Searching for observables of planetesimal debris

    NASA Astrophysics Data System (ADS)

    de Vries, B. L.; Skogby, H.; Waters, L. B. F. M.; Min, M.

    2018-06-01

    Meteorites contain minerals from Solar System asteroids with different properties (like size, presence of water, core formation). We provide new mid-IR transmission spectra of powdered meteorites to obtain templates of how mid-IR spectra of asteroidal debris would look like. This is essential for interpreting mid-IR spectra of past and future space observatories, like the James Webb Space Telescope. First we present new transmission spectra of powdered ordinary chondrite, pallasite and HED meteorites and then we combine them with already available transmission spectra of chondrites in the literature, giving a total set of 64 transmission spectra. In detail we study the spectral features of minerals in these spectra to obtain measurables used to spectroscopically distinguish between meteorite groups. Being able to differentiate between dust from different meteorite types means we can probe properties of parent bodies, like their size, if they were wet or dry and if they are differentiated (core formation) or not. We show that the transmission spectra of wet and dry chondrites, carbonaceous and ordinary chondrites and achondrite and chondrite meteorites are distinctly different in a way one can distinguish in astronomical mid-IR spectra. Carbonaceous chondrites type < 3 (aqueously altered) show distinct features of hydrated silicates (hydrosilicates) compared to the olivine and pyroxene rich ordinary chondrites (dry and equilibrated meteorites). Also the iron concentration of the olivine in carbonaceous chondrites differs from ordinary chondrites, which can be probed by the wavelength peak position of the olivine spectral features. The transmission spectra of chondrites (not differentiated) are also strongly different from the achondrite HED meteorites (meteorites from differentiated bodies like 4 Vesta), where the latter show much stronger pyroxene signatures. The two observables that spectroscopically separate the different meteorites groups (and thus the different

  17. THERMAL ABSORPTION AS THE CAUSE OF GIGAHERTZ-PEAKED SPECTRA IN PULSARS AND MAGNETARS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lewandowski, Wojciech; Rożko, Karolina; Kijak, Jarosław

    2015-07-20

    We present a model that explains the observed deviation of the spectra of some pulsars and magnetars from the power-law spectra that are seen in the bulk of the pulsar population. Our model is based on the assumption that the observed variety of pulsar spectra can be naturally explained by the thermal free–free absorption that takes place in the surroundings of the pulsars. In this context, the variety of the pulsar spectra can be explained according to the shape, density, and temperature of the absorbing media and the optical path of the line of sight across it. We have putmore » specific emphasis on the case of the radio magnetar SGR J1745–2900 (also known as the Sgr A* magnetar), modeling the rapid variations of the pulsar spectrum after the outburst of 2013 April as due to the free–free absorption of the radio emission in the electron material ejected during the magnetar outburst. The ejecta expands with time and consequently the absorption rate decreases and the shape of the spectrum changes in such a way that the peak frequency shifts toward the lower radio frequencies. In the hypothesis of an absorbing medium, we also discuss the similarity between the spectral behavior of the binary pulsar B1259–63 and the spectral peculiarities of isolated pulsars.« less

  18. Time dependent features in tremor spectra

    NASA Astrophysics Data System (ADS)

    Powell, T. W.; Neuberg, J.

    2003-11-01

    Harmonic spectral peaks are observed in the tremor spectra of many different volcanoes, and in some cases these spectral lines have been seen to change with time. This has also been observed for the tremor at the Soufrière Hills volcano on Montserrat, West Indies, where the spectral lines are sometimes seen to glide apart before an explosion. We propose a model of repeated triggering of low-frequency earthquakes to explain these gliding lines using the relationship δt=1/ δν, where δt and δν are time and frequency spacing, respectively, and investigate factors which can affect the observation of these spectral peaks. Noise and amplitude variation are shown to have little effect on the spectral peaks; however the time gap between events must be nearly constant over several events. An error with a standard deviation of 2% or less is required for the spectral lines to be observed in the frequency range 0.5-10 Hz. We can reproduce the gliding spectral lines from a specific tremor episode preceding an explosion by changing δt from 1 to 0.31 s over a time period of 12 min. Using this relationship and an Automated Event Classification Analysis Program (AECAP), we can monitor δt over a long time period. The AECAP also extracts other seismic parameters such as energy, duration and spectral characteristics. An initial comparison between low-frequency seismic energy and cyclic tilt shows a correlation between the two, but this does not hold for later cycles.

  19. Far-infrared spectra of acetanilide revisited

    NASA Astrophysics Data System (ADS)

    Spire, A.; Barthes, M.; Kellouai, H.; De Nunzio, G.

    2000-03-01

    A new investigation of the temperature dependence of the far-infrared spectra of acetanilide and some isotopomers is presented. Four absorption bands are considered at 31, 42, 64, and 80 cm-1, and no significant change of their integrated intensity is observed when reducing the temperature. The temperature induced frequency shift values and other properties of these bands are consistent with an assignment as anharmonic lattice phonons. These results rule out the assignment of the 64, 80, and 106 cm-1 bands as normal modes of the polaronic excitation, as previously suggested.

  20. Observations of solar flare photon energy spectra from 20 keV to 7 MeV

    NASA Technical Reports Server (NTRS)

    Yoshimori, M.; Watanabe, H.; Nitta, N.

    1985-01-01

    Solar flare photon energy spectra in the 20 keV to 7 MeV range are derived from the Apr. 1, Apr. 4, apr. 27 and May 13, 1981 flares. The flares were observed with a hard X-ray and a gamma-ray spectrometers on board the Hinotori satellite. The results show that the spectral shape varies from flare to flare and the spectra harden in energies above about 400 keV. Effects of nuclear line emission on the continuum and of higher energy electron bremsstrahlung are considered to explain the spectral hardening.

  1. Observational constraints on relativistic electron dynamics: temporal evolution of electron spectra and flux isotropization

    NASA Astrophysics Data System (ADS)

    Kanekal, S. G.; Selesnick, R. S.; Baker, D. N.; Blake, J. B.

    2007-05-01

    Models of energization of electrons in the Earth's outer radiation belts invoke two classes of processes, radial transport and in-situ wave-particle interactions. Temporal evolution of electron spectra and flux isotropization during energization events provide useful observational constraints on models of electron energization. Events dominated by radial diffusion result in pancake type pitch angle distributions whereas some in-situ wave-particle energization mechanisms include pitch angle scattering leading to rapid flux isotropization. We present a survey of flux isotrpization time scales and electron spectra during relativstic electron enhancement events. We will use data collected by detectors onboard SAMPEX in low earth orbit and Polar which measures electron fluxes at higher altitude to measure flux isotropization. Electron spectra are obtained by pulse height analyzed data from the PET detector onboard SAMPEX.SAMPEX measurements cover the entire outer zone for more than a decade from mid 1992 to mid 2004 and Polar covers the time period from mid 1996 to the present.

  2. Vibrational spectra from atomic fluctuations in dynamics simulations. II. Solvent-induced frequency fluctuations at femtosecond time resolution

    NASA Astrophysics Data System (ADS)

    Schmitz, Matthias; Tavan, Paul

    2004-12-01

    The midinfrared (MIR) spectra of molecules in polar solvents exhibit inhomogeneously broadened bands whose spectral positions are shifted as compared to the gas phase. The shifts are caused by interactions with structured solvation shells and the broadenings by fluctuations of these interactions. The MIR spectra can be calculated from hybrid molecular dynamics (MD) simulations, which treat the solute molecule by density functional theory and the solvent by molecular mechanics by the so-called instantaneous normal mode analysis (INMA) or by Fourier transforming the time correlation function (FTTCF) of the molecular dipole moment. In Paper I of this work [M. Schmitz and P. Tavan, J. Chem. Phys. 121, 12233 (2004)] we explored an alternative method based on generalized virial (GV) frequencies noting, however, that GV systematically underestimates frequencies. As shown by us these artifacts are caused by solvent-induced fluctuations of the (i) equilibrium geometry, (ii) force constants, and (iii) normal mode directions as well as by (iv) diagonal and (v) off-diagonal anharmonicities. Here we now show, by analyzing the time scales of fluctuations and sample MD trajectories of formaldehyde in the gas phase and in water, that all these sources of computational artifacts can be made visible by a Fourier analysis of the normal coordinates. Correspondingly, the error sources (i) and (iii)-(v) can be removed by bandpass filtering, as long as the spectral signatures of the respective effects are well separated from the fundamental band. Furthermore, the artifacts arising from effect (ii) can be strongly diminished by a time-resolved version of the GV approach (TF-GV). The TF-GV method then yields for each mode j a trajectory of the vibrational frequency ωj(t|τ) at a time resolution τ>τj, which is only limited by the corresponding oscillation time τj=2π/ωj and, thus, is in the femtosecond range. A correlation analysis of these trajectories clearly separates the

  3. Millimeter and submillimeter wave spectra of mono-13C-acetaldehydes

    NASA Astrophysics Data System (ADS)

    Margulès, L.; Motiyenko, R. A.; Ilyushin, V. V.; Guillemin, J. C.

    2015-07-01

    Context. The acetaldehyde molecule is ubiquitous in the interstellar medium of our galaxy, and due to its dense and complex spectrum, large dipole moment, and several low-lying torsional states, acetaldehyde is considered to be a "weed" molecule for radio astronomy observations. Mono-13C acetaldehydes 13CH3CHO and CH313CHO are likely to be identified in astronomical surveys, such as those available with the very sensitive ALMA telescope. Laboratory measurements and analysis of the millimeter and submillimeter-wave spectra are the prerequisites for the successful radioastronomical search for the new interstellar molecular species, as well as for new isotopologs of already detected interstellar molecules. Aims: In this context, to provide reliable predictions of 13CH3CHO and CH313CHO spectra in millimeter and submillimeter wave ranges, we study rotational spectra of these species in the frequency range from 50 to 945 GHz. Methods: The spectra of mono-13C acetaldehydes were recorded using the spectrometer based on Schottky-diode frequencymultiplication chains in the Lille laboratory. The rotational spectra of 13CH3CHO and CH313CHO molecules were analyzed using the Rho axis method. Results: In the recorded spectra we have assigned 6884 for the 13CH3CHO species and 6458 for CH313CHO species new rotational transitions belonging to the ground, first, and second excited torsional states. These measurements were fitted together with previously published data to the Hamiltonian models that use 91 and 87 parameters to achieve overall weighted rms deviations 0.88 for the 13CH3CHO species and 0.95 for CH313CHO. On the basis of the new spectroscopic results, predictions of transition frequencies in the frequency range up to 1 THz with J ≤ 60 and Ka ≤ 20 are presented for both isotopologs. Full Tables 3-6 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/579/A46

  4. Precise Modelling of Telluric Features in Astronomical Spectra

    NASA Astrophysics Data System (ADS)

    Seifahrt, A.; Käufl, H. U.; Zängl, G.; Bean, J.; Richter, M.; Siebenmorgen, R.

    2010-12-01

    Ground-based astronomical observations suffer from the disturbing effects of the Earth's atmosphere. Oxygen, water vapour and a number of atmospheric trace gases absorb and emit light at discrete frequencies, shaping observing bands in the near- and mid-infrared and leaving their fingerprints - telluric absorption and emission lines - in astronomical spectra. The standard approach of removing the absorption lines is to observe a telluric standard star: a time-consuming and often imperfect solution. Alternatively, the spectral features of the Earth's atmosphere can be modelled using a radiative transfer code, often delivering a satisfying solution that removes these features without additional observations. In addition the model also provides a precise wavelength solution and an instrumental profile.

  5. The Importance of High Frequency Observations for the SKA

    NASA Astrophysics Data System (ADS)

    Welch, William J.

    2007-12-01

    The plan for the Square Kilometer Array (SKA) is one or more very large arrays operating in two or more contiguous frequency bands: roughly 15 - 90 MHz, 120 - 500 MHz, and 500 MHz - 25 GHz. The last band may be further divided into roughly 500 MHz - 1.5 GHz and 1.5 - 25 GHz. Construction costs may delay or forgo one or more of these bands. We argue that the entire high frequency band is of special importance for astronomy both in the local universe and at great distances and early times. One of the Key Science Projects, the Cradle of Life, requires high sensitivity and resolution at frequencies up to 20 GHz for the study of forming disks around new stars with disk opacities too great for millimeter wave observations. The larger issue of star formation, a poorly understood area, will also benefit from high sensitivity observations at short cm wavelengths. Magnetic field measurements through the Zeeman effect in the densest star forming gas are best done using tracers such as CCS at frequencies of 11 and 22 GHz. The wide frequency range of the SKA permits the observation of multiple rotational transitions of long chain molecules, providing accurate measures of both gas densities and temperatures. The wide field of view will permit large scale surveys of entire star forming clouds revealing, at high resolution, the formation of clusters of pre-protostellar stars and class 0-2 protostars in line radiation. The continuum cm wave radiation will reveal the growth of grains in disks. On the larger scale, observations of CO at high redshifts will trace the evolution of star formation and the formation of metals back to the Epic of Reionization.

  6. Theoretical Study of Infrared and Raman Spectra of Hydrated Magnesium Sulfate Salts

    NASA Technical Reports Server (NTRS)

    Chaban, Galina M.; Huo, Winifred M.; Lee, Timothy J.; Kwak, Dochan (Technical Monitor)

    2002-01-01

    Harmonic and anharmonic vibrational frequencies, as well as infrared and Raman intensities, are calculated for MgSO4.nH20 (n=1-3). Electronic structure theory at the second order Moller-Plesset perturbation theory (MP2) level with a triple-zeta + polarization (TZP) basis set is used to determine the geometry, properties, and vibrational spectra of pure and hydrated MgSO4 salts. The direct vibrational self-consistent field (VSCF) method and its correlation corrected (CC-VSCF) extension are used to determine anharmonic corrections to vibrational frequencies and intensities for the pure MgSO4 and its complex with one water molecule. Very significant differences are found between vibrational of water molecules in complexes with MgSO4 and pure water. Some of the O-H stretching frequencies are shifted to the red very significantly (by up to 1500-2000/cm) upon complexation with magnesium sulfate. They should be observed between 1700 and 3000/cm in a region very different from the corresponding O-H stretch frequency region of pure water (3700-3800/cm). In addition, the SO2 stretching vibrations are found at lower frequency regions than the water vibrations. They can serve as unique identifiers for the presence of sulfate salts. The predicted infrared and Raman spectra should be of valuable help in the design of future missions and analysis of observed data from the ice surface of Jupiter's moon Europa that possibly contains hydrated MgSO4 salts.

  7. Multi-Epoch Multiwavelength Spectra and Models for Blazar 3C 279

    NASA Technical Reports Server (NTRS)

    Hartman, R. C.; Boettcher, M.; Aldering, G.; Aller, H.; Aller, M.; Backman, D. E.; Balonek, T. J.; Bertsch, D. L.; Bloom, S. D.; Bock, H.; hide

    2001-01-01

    Of the blazars detected by EGRET in GeV gamma-rays, 3C 279 is not only the best-observed by EGRET, but also one of the best-monitored at lower frequencies. We have assembled eleven spectra, from GHz radio through GeV gamma-rays, from the time intervals of EGRET observations. Although some of the data have appeared in previous publications, most are new, including data taken during the high states in early 1999 and early 2000. All of the spectra show substantial gamma-ray contribution to the total luminosity of the object; in a high state, the gamma-ray luminosity dominates over that at all other frequencies by a factor of more than 10. There is no clear pattern of time correlation; different bands do not always rise and fall together, even in the optical, X-ray, and gamma-ray bands. The spectra are modeled using a leptonic jet, with combined synchrotron self-Compton + external Compton gamma-ray production. Spectral variability of 3C 279 is consistent with variations of the bulk Lorentz factor of the jet, accompanied by changes in the spectral shape of the electron distribution. Our modeling results are consistent with the UV spectrum of 3C 279 being dominated by accretion disk radiation during times of low gamma-ray intensity.

  8. Observation of frequency cutoff for self-excited dust acoustic waves

    NASA Astrophysics Data System (ADS)

    Nosenko, V.; Zhdanov, S. K.; Morfill, G. E.; Kim, S.-H.; Heinrich, J.; Merlino, R. L.

    2009-11-01

    Complex (dusty) plasmas consist of fine solid particles suspended in a weakly ionized gas. Complex plasmas are excellent model systems to study wave phenomena down to the level of individual ``atoms''. Spontaneously excited dust acoustic waves were observed with high temporal resolution in a suspension of micron-size kaolin particles in a dc discharge in argon. Wave activity was found at frequencies as high as 400 Hz. At high wave numbers, the wave dispersion relation was acoustic-like (frequency proportional to wave number). At low wave numbers, the wave frequency did not tend to zero, but reached a cutoff frequency fc instead. The value of fc declined with distance from the anode. We propose a simple model that explains the observed cutoff by particle confinement in plasma. The existence of a cutoff frequency is very important for the propagation of waves: the waves excited above fc are propagating, and those below fc are evanescent.

  9. Observed hierarchy of student proficiency with period, frequency, and angular frequency

    NASA Astrophysics Data System (ADS)

    Young, Nicholas T.; Heckler, Andrew F.

    2018-01-01

    In the context of a generic harmonic oscillator, we investigated students' accuracy in determining the period, frequency, and angular frequency from mathematical and graphical representations. In a series of studies including interviews, free response tests, and multiple choice tests developed in an iterative process, we assessed students in both algebra-based and calculus-based, traditionally instructed university-level introductory physics courses. Using the results, we categorized nine skills necessary for proficiency in determining period, frequency, and angular frequency. Overall results reveal that, postinstruction, proficiency is quite low: only about 20%-40% of students mastered most of the nine skills. Next, we used a semiquantitative, intuitive method to investigate the hierarchical structure of the nine skills. We also employed the more formal item tree analysis method to verify this structure and found that the skills form a multilevel, nonlinear hierarchy, with mastery of some skills being prerequisite for mastery in other skills. Finally, we implemented a targeted, 30-min group-work activity to improve proficiency in these skills and found a 1 standard deviation gain in accuracy. Overall, the results suggest that many students currently lack these essential skills, targeted practice may lead to required mastery, and that the observed hierarchical structure in the skills suggests that instruction should especially attend to the skills lower in the hierarchy.

  10. Simultaneous observations of electromagnetically induced transparency (EIT) and absorption (EIA) in a multi-level V-type system of 87Rb and theoretical simulation of the observed spectra using a multi-mode approach

    NASA Astrophysics Data System (ADS)

    Das, Bankim Chandra; Bhattacharyya, Dipankar; Das, Arpita; Chakrabarti, Shrabana; De, Sankar

    2016-12-01

    We report here simultaneous experimental observation of Electromagnetically Induced Transparency (EIT) and Electromagnetically Induced Absorption (EIA) in a multi-level V-type system in D2 transition of 87Rb, i.e., F =2 →F' with a strong pump and a weak probe beam. We studied the probe spectrum by locking the probe beam to the transition F =2 →F'=2 while the pump is scanned from F =2 →F' . EIA is observed for the open transition (F =2 →F'=2 ) whereas EIT is observed in the closed transition (F =2 →F'=3 ). Sub natural line-width is observed for the EIA. To simulate the observed spectra theoretically, Liouville equation for the three-level V-type system is solved analytically with a multi-mode approach for the density matrix elements. We assumed both the pump and the probe beams can couple the excited states. A multi-mode approach for the coherence terms facilitates the study of all the frequency contributions due to the pump and the probe fields. Since the terms contain higher harmonics of the pump and the probe frequencies, we expressed them in Fourier transformed forms. To simulate the probe spectrum, we have solved inhomogeneous difference equations for the coherence terms using the Green's function technique and continued fraction theory. The experimental line-widths of the EIT and the EIA are compared with our theoretical model. Our system can be useful in optical switching applications as it can be precisely tuned to render the medium opaque and transparent simultaneously.

  11. Simultaneous observations of electromagnetically induced transparency (EIT) and absorption (EIA) in a multi-level V-type system of 87Rb and theoretical simulation of the observed spectra using a multi-mode approach.

    PubMed

    Das, Bankim Chandra; Bhattacharyya, Dipankar; Das, Arpita; Chakrabarti, Shrabana; De, Sankar

    2016-12-14

    We report here simultaneous experimental observation of Electromagnetically Induced Transparency (EIT) and Electromagnetically Induced Absorption (EIA) in a multi-level V-type system in D 2 transition of Rb87, i.e., F=2→F ' with a strong pump and a weak probe beam. We studied the probe spectrum by locking the probe beam to the transition F=2→F ' =2 while the pump is scanned from F=2→F ' . EIA is observed for the open transition (F=2→F ' =2) whereas EIT is observed in the closed transition (F=2→F ' =3). Sub natural line-width is observed for the EIA. To simulate the observed spectra theoretically, Liouville equation for the three-level V-type system is solved analytically with a multi-mode approach for the density matrix elements. We assumed both the pump and the probe beams can couple the excited states. A multi-mode approach for the coherence terms facilitates the study of all the frequency contributions due to the pump and the probe fields. Since the terms contain higher harmonics of the pump and the probe frequencies, we expressed them in Fourier transformed forms. To simulate the probe spectrum, we have solved inhomogeneous difference equations for the coherence terms using the Green's function technique and continued fraction theory. The experimental line-widths of the EIT and the EIA are compared with our theoretical model. Our system can be useful in optical switching applications as it can be precisely tuned to render the medium opaque and transparent simultaneously.

  12. Evolution of spatial and temporal correlations in the solar wind - Observations and interpretation

    NASA Technical Reports Server (NTRS)

    Klein, L. W.; Matthaeus, W. H.; Roberts, D. A.; Goldstein, M. L.

    1992-01-01

    Observations of solar wind magnetic field spectra from 1-22 AU indicate a distinctive structure in frequency which evolves with increasing heliocentric distance. At 1 AU extremely low frequency correlations are associated with temporal variations at the solar period and its first few harmonics. For periods of l2-96 hours, a l/f distribution is observed, which we interpret as an aggregate of uncorrelated coronal structures which have not dynamically interacted by 1 AU. At higher frequencies the familiar Kolmogorov-like power law is seen. Farther from the sun the frequency break point between the shallow l/f and the steeper Kolmogorov spectrum evolves systematically towards lower frequencies. We suggest that the Kolmogorov-like spectra emerge due to in situ turbulence that generates spatial correlations associated with the turbulent cascade and that the background l/f noise is a largely temporal phenomenon, not associated with in situ dynamical processes. In this paper we discuss these ideas from the standpoint of observations from several interplanetary spacecraft.

  13. Adding a dimension to the infrared spectra of interfaces using heterodyne detected 2D sum-frequency generation (HD 2D SFG) spectroscopy.

    PubMed

    Xiong, Wei; Laaser, Jennifer E; Mehlenbacher, Randy D; Zanni, Martin T

    2011-12-27

    In the last ten years, two-dimensional infrared spectroscopy has become an important technique for studying molecular structures and dynamics. We report the implementation of heterodyne detected two-dimensional sum-frequency generation (HD 2D SFG) spectroscopy, which is the analog of 2D infrared (2D IR) spectroscopy, but is selective to noncentrosymmetric systems such as interfaces. We implement the technique using mid-IR pulse shaping, which enables rapid scanning, phase cycling, and automatic phasing. Absorptive spectra are obtained, that have the highest frequency resolution possible, from which we extract the rephasing and nonrephasing signals that are sometimes preferred. Using this technique, we measure the vibrational mode of CO adsorbed on a polycrystalline Pt surface. The 2D spectrum reveals a significant inhomogenous contribution to the spectral line shape, which is quantified by simulations. This observation indicates that the surface conformation and environment of CO molecules is more complicated than the simple "atop" configuration assumed in previous work. Our method can be straightforwardly incorporated into many existing SFG spectrometers. The technique enables one to quantify inhomogeneity, vibrational couplings, spectral diffusion, chemical exchange, and many other properties analogous to 2D IR spectroscopy, but specifically for interfaces.

  14. Separation of overlapping vibrational peaks in terahertz spectra using two-dimensional correlation spectroscopy

    NASA Astrophysics Data System (ADS)

    Hoshina, Hiromichi; Ishii, Shinya; Otani, Chiko

    2014-07-01

    In this study, the terahertz (THz) absorption spectra of poly(3-hydroxybutyrate) (PHB) were measured during isothermal crystallization at 90-120 °C. The temporal changes in the absorption spectra were analyzed using two-dimensional correlation spectroscopy (2DCOS). In the asynchronous plot, cross peaks were observed around 2.4 THz, suggesting that two vibrational modes overlap in the raw spectrum. By comparing this to the peak at 2.9 THz corresponding to the stretching mode of the helical structure of PHB and the assignment obtained using polarization spectroscopy, we concluded that the high-frequency band could be attributed to the vibration of the helical structure and the low-frequency band to the vibration between the helical structures. The exact frequencies of the overlapping vibrational bands and their assignments provide a new means to inspect the thermal behavior of the intermolecular vibrational modes. The large red-shift of the interhelix vibrational mode suggests a large anharmonicity in the vibrational potential.

  15. High Frequency Tail Characteristics in the Coastal Waters off Gopalpur, Northwest Bay of Bengal: A Nearshore Modelling Study

    NASA Astrophysics Data System (ADS)

    Umesh, P. A.; Bhaskaran, Prasad K.; Sandhya, K. G.; Nair, T. M. Balakrishnan

    2017-12-01

    Over the years, continued uncertainty amid - 4 and - 5 frequency exponent representation observed in the slope of the high-frequency tail of a wind-wave frequency spectrum is a major concern. To comprehend the nature of the high-frequency tail an effort has been made to assess the slope of the high-frequency tail with measured data recorded for 3 years off Gopalpur. The study demonstrates that the high-frequency slope of the spectra varied seasonally in the range of n = - 2.13 to - 3.48. The swell and wind sea parameters calculated by separation frequency method, shows that 64.6% of waves were dominant by swell and the rest 34.9% by sea annually. Single, double and multi-peaked spectra occur 12.23, 71.80 and 15.37% annually. To simulate wave spectra, the nested WAM-SWAN model is forced with ERA-Interim winds and 1D wave spectra comparisons, when performed, proved to be encouraging. From the comparisons of measured and theoretical spectra it is concluded that JONSWAP model could not describe the high-frequency tail of measured spectrum, as indicated by the very high Scatter Index ranging from 0.24 to 1.44. Whether there exists a correct slope for the high-frequency tail is still a question. Moreover, the philosophy of a unique slope at any coastal location remains uncertain for the wave modelling community.

  16. Tympanal spontaneous oscillations reveal mechanisms for the control of amplified frequency in tree crickets

    NASA Astrophysics Data System (ADS)

    Mhatre, Natasha; Robert, Daniel

    2018-05-01

    Tree cricket hearing shows all the features of an actively amplified auditory system, particularly spontaneous oscillations (SOs) of the tympanal membrane. As expected from an actively amplified auditory system, SO frequency and the peak frequency in evoked responses as observed in sensitivity spectra are correlated. Sensitivity spectra also show compressive non-linearity at this frequency, i.e. a reduction in peak height and sharpness with increasing stimulus amplitude. Both SO and amplified frequency also change with ambient temperature, allowing the auditory system to maintain a filter that is matched to song frequency. In tree crickets, remarkably, song frequency varies with ambient temperature. Interestingly, active amplification has been reported to be switched ON and OFF. The mechanism of this switch is as yet unknown. In order to gain insights into this switch, we recorded and analysed SOs as the auditory system transitioned from the passive (OFF) state to the active (ON) state. We found that while SO amplitude did not follow a fixed pattern, SO frequency changed during the ON-OFF transition. SOs were first detected above noise levels at low frequencies, sometimes well below the known song frequency range (0.5-1 kHz lower). SO frequency was observed to increase over the next ˜30 minutes, in the absence of any ambient temperature change, before settling at a frequency within the range of conspecific song. We examine the frequency shift in SO spectra with temperature and during the ON/OFF transition and discuss the mechanistic implications. To our knowledge, such modulation of active auditory amplification, and its dynamics are unique amongst auditory animals.

  17. Optical image and laser slope meter intercomparisons of high-frequency waves

    NASA Technical Reports Server (NTRS)

    Lubard, S. C.; Krimmel, J. E.; Thebaud, L. R.; Evans, D. D.; Shemdin, O. H.

    1980-01-01

    Spectral analyses of optical images of the ocean surface, obtained by a digital video system, are presented and compared with wave data measured simultaneously by the JPL Waverider-mounted laser slope meter. The image analyses, which incorporate several new ideas, provide two-dimensional wave number spectra of slope, covering wavelengths from 10 cm to 10 m. These slope spectra are converted to wave height spectra by a new technique which includes the effects of sky radiance gradients. Space-time spectra are also presented for waves whose frequencies are less than 2 Hz. The JPL slope frequency spectra are compared with image wave number spectra which have been converted to frequency spectra by use of the gravity wave dispersion relation. Results of comparisons between the frequency spectra obtained from the two different measurements show reasonable agreement for frequencies less than 3 Hz.

  18. Normal vibrational modes of phospholipid bilayers observed by low-frequency Raman scattering

    NASA Astrophysics Data System (ADS)

    Surovtsev, N. V.; Dmitriev, A. A.; Dzuba, S. A.

    2017-03-01

    Low-frequency Raman spectra of multilamellar vesicles made either of 1-palmitoyl-2-oleoyl-s n -glycero-3-phosphocholine (POPC) or 1,2-dipalmitoyl-s n -glycero-3-phosphocholine (DPPC) have been studied in a wide temperature range. Below 0 ∘C two peaks are found at frequencies around 8-9 and 14 -17 c m -1 and attributed to the normal vibrational modes of the phospholipid bilayer, which are determined by the bilayer thickness and stiffness (elastic modulus). The spectral positions of the peaks depend on the temperature and the bilayer composition. It is suggested that the ratio of the intensities of the first and second peaks can serve as a measure of the interleaflet elastic coupling. The addition of cholesterol to the phospholipid bilayer leads to peak shift and broadening, which may be assigned to the composition heterogeneities commonly attributed to the lipid raft formation.

  19. Solar observations with a low frequency radio telescope

    NASA Astrophysics Data System (ADS)

    Myserlis, I.; Seiradakis, J.; Dogramatzidis, M.

    2012-01-01

    We have set up a low frequency radio monitoring station for solar bursts at the Observatory of the Aristotle University in Thessaloniki. The station consists of a dual dipole phased array, a radio receiver and a dedicated computer with the necessary software installed. The constructed radio receiver is based on NASA's Radio Jove project. It operates continuously, since July 2010, at 20.1 MHz (close to the long-wavelength ionospheric cut-off of the radio window) with a narrow bandwidth (~5 kHz). The system is properly calibrated, so that the recorded data are expressed in antenna temperature. Despite the high interference level of an urban region like Thessaloniki (strong broadcasting shortwave radio stations, periodic experimental signals, CBs, etc), we have detected several low frequency solar radio bursts and correlated them with solar flares, X-ray events and other low frequency solar observations. The received signal is monitored in ordinary ASCII format and as audio signal, in order to investigate and exclude man-made radio interference. In order to exclude narrow band interference and calculate the spectral indices of the observed events, a second monitoring station, working at 36 MHz, is under construction at the village of Nikiforos near the town of Drama, about 130 km away of Thessaloniki. Finally, we plan to construct a third monitoring station at 58 MHz, in Thessaloniki. This frequency was revealed to be relatively free of interference, after a thorough investigation of the region.

  20. The spectra and periodograms of anti-correlated discrete fractional Gaussian noise.

    PubMed

    Raymond, G M; Percival, D B; Bassingthwaighte, J B

    2003-05-01

    Discrete fractional Gaussian noise (dFGN) has been proposed as a model for interpreting a wide variety of physiological data. The form of actual spectra of dFGN for frequencies near zero varies as f(1-2H), where 0 < H < 1 is the Hurst coefficient; however, this form for the spectra need not be a good approximation at other frequencies. When H approaches zero, dFGN spectra exhibit the 1 - 2H power-law behavior only over a range of low frequencies that is vanishingly small. When dealing with a time series of finite length drawn from a dFGN process with unknown H, practitioners must deal with estimated spectra in lieu of actual spectra. The most basic spectral estimator is the periodogram. The expected value of the periodogram for dFGN with small H also exhibits non-power-law behavior. At the lowest Fourier frequencies associated with a time series of N values sampled from a dFGN process, the expected value of the periodogram for H approaching zero varies as f(0) rather than f(1-2H). For finite N and small H, the expected value of the periodogram can in fact exhibit a local power-law behavior with a spectral exponent of 1 - 2H at only two distinct frequencies.

  1. Broadband turbulent spectra in gamma-ray burst light curves

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Van Putten, Maurice H. P. M.; Guidorzi, Cristiano; Frontera, Filippo, E-mail: mvp@sejong.ac.kr

    2014-05-10

    Broadband power density spectra offer a window to understanding turbulent behavior in the emission mechanism and, at the highest frequencies, in the putative inner engines powering long gamma-ray bursts (GRBs). We describe a chirp search method alongside Fourier analysis for signal detection in the Poisson noise-dominated, 2 kHz sampled, BeppoSAX light curves. An efficient numerical implementation is described in O(Nnlog n) operations, where N is the number of chirp templates and n is the length of the light-curve time series, suited for embarrassingly parallel processing. For the detection of individual chirps over a 1 s duration, the method is onemore » order of magnitude more sensitive in signal-to-noise ratio than Fourier analysis. The Fourier-chirp spectra of GRB 010408 and GRB 970816 show a continuation of the spectral slope with up to 1 kHz of turbulence identified in low-frequency Fourier analysis. The same continuation is observed in an average spectrum of 42 bright, long GRBs. An outlook on a similar analysis of upcoming gravitational wave data is included.« less

  2. MAGIC gamma-ray and multi-frequency observations of flat spectrum radio quasar PKS 1510-089 in early 2012

    DOE PAGES

    Aleksić, J.; Ansoldi, S.; Antonelli, L. A.; ...

    2014-09-17

    Aims. We report amongst more than fifty blazars detected in very high energy (VHE, E> 100 GeV) γ rays, only three belong to the subclass of flat spectrum radio quasars (FSRQs). The detection of FSRQs in the VHE range is challenging, mainly because of their soft spectra in the GeV-TeV regime. MAGIC observed PKS 1510-089 (z = 0.36) starting 2012 February 3 until April 3 during a high activity state in the high energy (HE, E> 100 MeV) γ-ray band observed by AGILE and Fermi. MAGIC observations result in the detection of a source with significance of 6.0 standard deviationsmore » (σ). We study the multi-frequency behaviour of the source at the epoch of MAGIC observation, collecting quasi-simultaneous data at radio and optical (GASP-WEBT and F-Gamma collaborations, REM, Steward, Perkins, Liverpool, OVRO, and VLBA telescopes), X-ray (Swift satellite), and HE γ-ray frequencies. Methods. We study the VHE γ-ray emission, together with the multi-frequency light curves, 43 GHz radio maps, and spectral energy distribution (SED) of the source. The quasi-simultaneous multi-frequency SED from the millimetre radio band to VHE γ rays is modelled with a one-zone inverse Compton model. We study two different origins of the seed photons for the inverse Compton scattering, namely the infrared torus and a slow sheath surrounding the jet around the Very Long Baseline Array (VLBA) core. Results. We find that the VHE γ-ray emission detected from PKS 1510-089 in 2012 February-April agrees with the previous VHE observations of the source from 2009 March-April. We find no statistically significant variability during the MAGIC observations on daily, weekly, or monthly time scales, while the other two known VHE FSRQs (3C 279 and PKS 1222+216) have shown daily scale to sub-hour variability. The γ-ray SED combining AGILE, Fermi and MAGIC data joins smoothly and shows no hint of a break. The multi-frequency light curves suggest a common origin for the millimetre radio and HE

  3. The anharmonic quartic force field infrared spectra of hydrogenated and methylated PAHs.

    PubMed

    Mackie, Cameron J; Candian, Alessandra; Huang, Xinchuan; Maltseva, Elena; Petrignani, Annemieke; Oomens, Jos; Buma, Wybren Jan; Lee, Timothy J; Tielens, Alexander G G M

    2018-01-03

    Polycyclic aromatic hydrocarbons (PAHs) have been shown to be ubiquitous in a large variety of distinct astrophysical environments and are therefore of great interest to astronomers. The majority of these findings are based on theoretically predicted spectra, which make use of scaled DFT harmonic frequencies for band positions and the double harmonic approximation for intensities. However, these approximations have been shown to fail at predicting high-resolution gas-phase infrared spectra accurately, especially in the CH-stretching region (2950-3150 cm -1 , 3 μm). This is particularly worrying for the subset of hydrogenated or methylated PAHs to which astronomers attribute the observed non-aromatic features that appear in the CH-stretching region of spectral observations of the interstellar medium (ISM). In our previous work, we presented the anharmonic theoretical spectra of three linear PAHs and five non-linear PAHs, demonstrating the importance of including anharmonicities into theoretical calculations. In this work we extend these techniques to two methylated PAHs (9-methylanthracene, and 9,10-dimethylanthracene) and four hydrogenated PAHs (9,10-dihydroanthracene, 9,10-dihydrophenanthrene, 1,2,3,4-tetrahydronaphthalene, and 1,2,3,6,7,8-hexahydropyrene) in order to better understand the aliphatic IR features of substituted PAHs. The theoretical spectra are compared with the spectra obtained under matrix isolation low-temperature conditions for the full vibrational fundamental range and under high-resolution, low-temperature gas-phase conditions for the CH-stretching region. Excellent agreement is observed between the theoretical and high-resolution experimental spectra with a deviation of 0.00% ± 0.17%, and changes to the spectra of PAHs upon methylation and hydrogenated are tracked accurately and explained.

  4. Raman spectra of thiolated arsenicals with biological importance.

    PubMed

    Yang, Mingwei; Sun, Yuzhen; Zhang, Xiaobin; McCord, Bruce; McGoron, Anthony J; Mebel, Alexander; Cai, Yong

    2018-03-01

    Surface enhanced Raman scattering (SERS) has great potential as an alternative tool for arsenic speciation in biological matrices. SERS measurements have advantages over other techniques due to its ability to maintain the integrity of arsenic species and its minimal requirements for sample preparation. Up to now, very few Raman spectra of arsenic compounds have been reported. This is particularly true for thiolated arsenicals, which have recently been found to be widely present in humans. The lack of data for Raman spectra in arsenic speciation hampers the development of new tools using SERS. Herein, we report the results of a study combining the analysis of experimental Raman spectra with that obtained from density functional calculations for some important arsenic metabolites. The results were obtained with a hybrid functional B3LYP approach using different basis sets to calculate Raman spectra of the selected arsenicals. By comparing experimental and calculated spectra of dimethylarsinic acid (DMA V ), the basis set 6-311++G** was found to provide computational efficiency and precision in vibrational frequency prediction. The Raman frequencies for the rest of organoarsenicals were studied using this basis set, including monomethylarsonous acid (MMA III ), dimethylarsinous acid (DMA III ), dimethylmonothioarinic acid (DMMTA V ), dimethyldithioarsinic acid (DMDTA V ), S-(Dimethylarsenic) cysteine (DMA III (Cys)) and dimethylarsinous glutathione (DMA III GS). The results were compared with fingerprint Raman frequencies from As─O, As─C, and As─S obtained under different chemical environments. These fingerprint vibrational frequencies should prove useful in future measurements of different species of arsenic using SERS. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. The Radio-optical Spectra of BL Lacs and Possible Relatives

    NASA Astrophysics Data System (ADS)

    Dennett-Thorpe, J.

    I consider the suggestion that, in a complete sample of flat-spectrum radio sources with available optical spectra (Marcha et al 1996), the strong emission line objects, or those with passive elliptical spectra are close relatives of the BL Lacs. New observations at four frequencies from 8 to 43GHz are presented, together with evidence for radio variability. Combined with other radio and optical data from the literature, we are able to construct the non-thermal SEDs and use these to address the questions: are the optically passive objects potentially `unrecognised' BL Lacs (either intrinsically weak and/or hidden by starlight)? What is the relationship between the surprising number of strong emission-line objects and the BL Lacs?

  6. High-frequency predictions for number counts and spectral properties of extragalactic radio sources. New evidence of a break at mm wavelengths in spectra of bright blazar sources

    NASA Astrophysics Data System (ADS)

    Tucci, M.; Toffolatti, L.; de Zotti, G.; Martínez-González, E.

    2011-09-01

    We present models to predict high-frequency counts of extragalactic radio sources using physically grounded recipes to describe the complex spectral behaviour of blazars that dominate the mm-wave counts at bright flux densities. We show that simple power-law spectra are ruled out by high-frequency (ν ≥ 100 GHz) data. These data also strongly constrain models featuring the spectral breaks predicted by classical physical models for the synchrotron emission produced in jets of blazars. A model dealing with blazars as a single population is, at best, only marginally consistent with data coming from current surveys at high radio frequencies. Our most successful model assumes different distributions of break frequencies, νM, for BL Lacs and flat-spectrum radio quasars (FSRQs). The former objects have substantially higher values of νM, implying that the synchrotron emission comes from more compact regions; therefore, a substantial increase of the BL Lac fraction at high radio frequencies and at bright flux densities is predicted. Remarkably, our best model is able to give a very good fit to all the observed data on number counts and on distributions of spectral indices of extragalactic radio sources at frequencies above 5 and up to 220 GHz. Predictions for the forthcoming sub-mm blazar counts from Planck, at the highest HFI frequencies, and from Herschel surveys are also presented. Appendices are available in electronic form at http://www.aanda.org

  7. Rotational Spectra in 29 Vibrationally Excited States of Interstellar Aminoacetonitrile

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kolesniková, L.; Alonso, E. R.; Mata, S.

    2017-04-01

    We report a detailed spectroscopic investigation of the interstellar aminoacetonitrile, a possible precursor molecule of glycine. Using a combination of Stark and frequency-modulation microwave and millimeter wave spectroscopies, we observed and analyzed the room-temperature rotational spectra of 29 excited states with energies up to 1000 cm{sup −1}. We also observed the {sup 13}C isotopologues in the ground vibrational state in natural abundance (1.1%). The extensive data set of more than 2000 new rotational transitions will support further identifications of aminoacetonitrile in the interstellar medium.

  8. Delta and theta power spectra of night sleep EEG are higher in breast-feeding mothers than in non-pregnant women.

    PubMed

    Nishihara, Kyoko; Horiuchi, Shigeko; Eto, Hiromi; Uchida, Sunao; Honda, Makoto

    2004-09-23

    The power spectra of night sleep EEGs of 12 breast-feeding 9-13 week postpartum mothers were analyzed and compared with those of 12 non-pregnant women. The power spectra in the delta and theta frequency range during NREM sleep for breast-feeding mothers were significantly higher than those for non-pregnant women. In addition, the all-night sleep patterns of the mothers were classified into two groups - interrupted sleep due to taking care of their infants and non-interrupted sleep - in order to observe the influence of partial sleep deprivation. The power spectra in the delta and theta frequency range were not significantly different between them. This result suggests that increased delta and theta power spectra during postpartum sleep do not result from partial sleep deprivation. The role of prolactin in breast-feeding mothers' sleep is also discussed.

  9. A devil in the detail: parameter cross-talk from the solar cycle and estimation of solar p-mode frequencies

    NASA Astrophysics Data System (ADS)

    Chaplin, W. J.; Jiménez-Reyes, S. J.; Eff-Darwich, A.; Elsworth, Y.; New, R.

    2008-04-01

    Frequencies, powers and damping rates of the solar p modes are all observed to vary over the 11-yr solar activity cycle. Here, we show that simultaneous variations in these parameters give rise to a subtle cross-talk effect, which we call the `devil in the detail', that biases p-mode frequencies estimated from analysis of long power frequency spectra. We also show that the resonant peaks observed in the power frequency spectra show small distortions due to the effect. Most of our paper is devoted to a study of the effect for Sun-as-a-star observations of the low-l p modes. We show that for these data the significance of the effect is marginal. We also touch briefly on the likely l dependence of the effect, and discuss the implications of these results for solar structure inversions.

  10. Do our reconstructions of ENSO have too much low-frequency variability?

    NASA Astrophysics Data System (ADS)

    Loope, G. R.; Overpeck, J. T.

    2017-12-01

    Reconstructing the spectrum of Pacific SST variability has proven to be difficult both because of complications with proxy systems such as tree rings and the relatively small number of records from the tropical Pacific. We show that the small number of long coral δ18O and Sr/Ca records has caused a bias towards having too much low-frequency variability in PCR, CPS, and RegEM reconstructions of Pacific variability. This occurs because the individual coral records used in the reconstructions have redder spectra than the shared signal (e.g. ENSO). This causes some of the unshared, low-frequency signal from local climate, salinity and possibly coral biology to bleed into the reconstruction. With enough chronologies in a reconstruction, this unshared noise cancels out but the problem is exacerbated in our longest reconstructions where fewer records are available. Coral proxies tend to have more low-frequency variability than SST observations so this problem is smaller but can still be seen in pseudoproxy experiments using observations and reanalysis data. The identification of this low-frequency bias in coral reconstructions helps bring the spectra of ENSO reconstructions back into line with both models and observations. Although our analysis is mostly constrained to the 20th century due to lack of sufficient data, we expect that as more long chronologies are developed, the low-frequency signal in ENSO reconstructions will be greatly reduced.

  11. Electromagnetic fluctuation spectra of collective oscillations in magnetized Maxwellian equal mass plasmas for low-frequency waves

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vafin, S.; Schlickeiser, R.; Yoon, P. H.

    Recently, the general electromagnetic fluctuation theory for magnetized plasmas has been used to study the steady-state fluctuation spectra and the total intensity of low-frequency collective weakly damped modes for parallel wave vectors in Maxwellian plasmas. Now, we address the same question with respect to an arbitrary direction of the wave-vector. Here, we analyze this problem for equal mass plasmas. These plasmas are a very good tool to study various plasma phenomena, as they considerably facilitate the theoretical consideration and at the same time provide with their clear physical picture. Finally, we compare our results in the limiting case of parallelmore » wave vectors with the previous study.« less

  12. The IR Absorption Spectra of Aqueous Solutions of Dimethylsulfoxide over the Frequency Range 50-300 cm-1 and the Mobility of Water Molecules

    NASA Astrophysics Data System (ADS)

    Klemenkova, Z. S.; Novskova, T. A.; Lyashchenko, A. K.

    2008-04-01

    The IR absorption spectra of aqueous solutions of dimethylsulfoxide (DMSO) with concentrations from 100% H2O to 100% DMSO were recorded over the frequency range 50-500 cm-1. The absorption spectra were described using the theoretical scheme of hindered rotators. A model was developed according to which orientation relaxation in solution was related to separate rotations of H2O and DMSO molecules through fixed small and (or) large angles in a unified network of H-bonds consisting of several subsystems ordered to various degrees. The calculated absorption spectra were in agreement with the experimental data in the far IR region. Elementary motions of molecules were found to slow down in the passage from pure dimethylsulfoxide to its aqueous solutions. The special features of the hydrophilic and hydrophobic hydration of DMSO polar and nonpolar groups were considered.

  13. Terrestrial FeO Continuum Emission Observed in Sky Spectra

    NASA Astrophysics Data System (ADS)

    Slanger, Tom G.; Melchiorri, R.; Saran, D. V.

    2011-01-01

    The terrestrial continuum emission in the visible spectral region has often been studied by both astronomers and aeronomers, in order to clarify backgrounds and the nature of the emissions. New observations from the ESI spectrograph on the Keck II telescope, as well as from the OSIRIS/Odin spectrograph and orbiter, have established that a major component of the emission originates with the FeO molecule [Evans et al., 2010]. This quasi-continuum peaks at 5950 A and extends from 5000 A well into the infrared. The identity has been demonstrated by comparison with meteor trains and laboratory measurements [Jenniskens et al., 2000]. Early studies of the continuum show consistency with the FeO emission as presently observed [Gadsden and Marovich, 1973]. Analysis of spectra from Kitt Peak [Neugent and Massey, 2010] demonstrates the great similarity between FeO emission in a clean atmosphere and high pressure sodium lamp emission in a polluted atmosphere. This research was supported by NSF Aeronomy under Grant ATM-0637433 . Evans, W.F.J., et al., Geophys. Res. Lett. [in press, 2010] Gadsden, M. and E. Marovich, J. Atm. Terr. Phys., 35, 1601-1614 [1973] Jenniskens, P., et al., Earth, Moon and Planets, 82-83, 429-434 [2000] Neugent, K.F. and P. Massey, PASP [in press, 2010

  14. Power Spectra, Power Law Exponents, and Anisotropy of Solar Wind Turbulence at Small Scales

    NASA Technical Reports Server (NTRS)

    Podesta, J. J.; Roberts, D. A.; Goldstein, M. L.

    2006-01-01

    The Wind spacecraft provides simultaneous solar wind velocity and magnetic field measurements with 3- second time resolution, roughly an order of magnitude faster than previous measurements, enabling the small scale features of solar wind turbulence to be studied in unprecedented detail. Almost the entire inertial range can now be explored (the inertial range extends from approximately 1 to 10(exp 3) seconds in the spacecraft frame) although the dissipation range of the velocity fluctuations is still out of reach. Improved measurements of solar wind turbulence spectra at 1 AU in the ecliptic plane are presented including spectra of the energy and cross-helicity, the magnetic and kinetic energies, the Alfven ratio, the normalized cross-helicity, and the Elsasser ratio. Some recent observations and theoretical challenges are discussed including the observation that the velocity and magnetic field spectra often show different power law exponents with values close to 3/2 and 5/3, respectively; the energy (kinetic plus magnetic) and cross-helicity often have approximately equal power law exponents with values intermediate between 3/2 and 5/3; and the Alfven ratio, the ratio of the kinetic to magnetic energy spectra, is often a slowly increasing function of frequency increasing from around 0.4 to 1 for frequencies in the inertial range. Differences between high- and low-speed wind are also discussed. Comparisons with phenomenological turbulence theories show that important aspects of the physics are yet unexplained.

  15. Track Structure Model for Radial Distributions of Electron Spectra and Event Spectra from High-Energy Ions

    NASA Technical Reports Server (NTRS)

    Cucinotta, F. A.; Katz, R.; Wilson, J. W.

    1998-01-01

    An analytic method is described for evaluating the average radial electron spectrum and the radial and total frequency-event spectrum for high-energy ions. For high-energy ions, indirect events make important contributions to frequency-event spectra. The method used for evaluating indirect events is to fold the radial electron spectrum with measured frequency-event spectrum for photons or electrons. The contribution from direct events is treated using a spatially restricted linear energy transfer (LET). We find that high-energy heavy ions have a significantly reduced frequency-averaged final energy (yF) compared to LET, while relativistic protons have a significantly increased yF and dose-averaged lineal energy (yD) for typical site sizes used in tissue equivalent proportional counters. Such differences represent important factors in evaluating event spectra with laboratory beams, in space- flight, or in atmospheric radiation studies and in validation of radiation transport codes. The inadequacy of LET as descriptor because of deviations in values of physical quantities, such as track width, secondary electron spectrum, and yD for ions of identical LET is also discussed.

  16. Anisotropic spectra of acoustic type turbulence

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuznetsov, E.; P.N. Lebedev Physical Institute, 53 Leninsky Ave., 119991 Moscow; Krasnoselskikh, V.

    2008-06-15

    The problem of spectra for acoustic type of turbulence generated by shocks being randomly distributed in space is considered. It is shown that for turbulence with a weak anisotropy, such spectra have the same dependence in k-space as the Kadomtsev-Petviashvili spectrum: E(k){approx}k{sup -2}. However, the frequency spectrum has always the falling {approx}{omega}{sup -2}, independent of anisotropy. In the strong anisotropic case the energy distribution relative to wave vectors takes anisotropic dependence, forming in the large-k region spectra of the jet type.

  17. Frequency and mode identification of γ Doradus from photometric and spectroscopic observations*

    NASA Astrophysics Data System (ADS)

    Brunsden, E.; Pollard, K. R.; Wright, D. J.; De Cat, P.; Cottrell, P. L.

    2018-04-01

    The prototype star for the γ Doradus class of pulsating variables was studied employing photometric and spectroscopic observations to determine the frequencies and modes of pulsation. The four frequencies found are self-consistent between the observation types and almost identical to those found in previous studies (1.3641 d-1, 1.8783 d-1, 1.4742 d-1, and 1.3209 d-1). Three of the frequencies are classified as l, m = (1, 1) pulsations and the other is ambiguous between l, m = (2, 0) and (2, -2) modes. Two frequencies are shown to be stable over 20 yr since their first identification. The agreement in ground-based work makes this star an excellent calibrator between high-precision photometry and spectroscopy with the upcoming TESS observations and a potential standard for continued asteroseismic modelling.

  18. Estimation of High-Frequency Earth-Space Radio Wave Signals via Ground-Based Polarimetric Radar Observations

    NASA Technical Reports Server (NTRS)

    Bolen, Steve; Chandrasekar, V.

    2002-01-01

    Expanding human presence in space, and enabling the commercialization of this frontier, is part of the strategic goals for NASA's Human Exploration and Development of Space (HEDS) enterprise. Future near-Earth and planetary missions will support the use of high-frequency Earth-space communication systems. Additionally, increased commercial demand on low-frequency Earth-space links in the S- and C-band spectra have led to increased interest in the use of higher frequencies in regions like Ku and Ka-band. Attenuation of high-frequency signals, due to a precipitating medium, can be quite severe and can cause considerable disruptions in a communications link that traverses such a medium. Previously, ground radar measurements were made along the Earth-space path and compared to satellite beacon data that was transmitted to a ground station. In this paper, quantitative estimation of the attenuation along the propagation path is made via inter-comparisons of radar data taken from the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR) and ground-based polarimetric radar observations. Theoretical relationships between the expected specific attenuation (k) of spaceborne measurements with ground-based measurements of reflectivity (Zh) and differential propagation phase shift (Kdp) are developed for various hydrometeors that could be present along the propagation path, which are used to estimate the two-way path-integrated attenuation (PIA) on the PR return echo. Resolution volume matching and alignment of the radar systems is performed, and a direct comparison of PR return echo with ground radar attenuation estimates is made directly on a beam-by-beam basis. The technique is validated using data collected from the TExas and Florida UNderflights (TEFLUN-B) experiment and the TRMM large Biosphere-Atmosphere experiment in Amazonia (LBA) campaign. Attenuation estimation derived from this method can be used for strategiC planning of communication systems for

  19. Statistical and observational research of solar flare for total spectra and geometrical features

    NASA Astrophysics Data System (ADS)

    Nishimoto, S.; Watanabe, K.; Imada, S.; Kawate, T.; Lee, K. S.

    2017-12-01

    Impulsive energy release phenomena such as solar flares, sometimes affect to the solar-terrestrial environment. Usually, we use soft X-ray flux (GOES class) as the index of flare scale. However, the magnitude of effect to the solar-terrestrial environment is not proportional to that scale. To identify the relationship between solar flare phenomena and influence to the solar-terrestrial environment, we need to understand the full spectrum of solar flares. There is the solar flare irradiance model named the Flare Irradiance Spectral Model (FISM) (Chamberlin et al., 2006, 2007, 2008). The FISM can estimate solar flare spectra with high wavelength resolution. However, this model can not express the time evolution of emitted plasma during the solar flare, and has low accuracy on short wavelength that strongly effects and/or controls the total flare spectra. For the purpose of obtaining the time evolution of total solar flare spectra, we are performing statistical analysis of the electromagnetic data of solar flares. In this study, we select solar flare events larger than M-class from the Hinode flare catalogue (Watanabe et al., 2012). First, we focus on the EUV emission observed by the SDO/EVE. We examined the intensities and time evolutions of five EUV lines of 55 flare events. As a result, we found positive correlation between the "soft X-ray flux" and the "EUV peak flux" for all EVU lines. Moreover, we found that hot lines peaked earlier than cool lines of the EUV light curves. We also examined the hard X-ray data obtained by RHESSI. When we analyzed 163 events, we found good correlation between the "hard X-ray intensity" and the "soft X-ray flux". Because it seems that the geometrical features of solar flares effect to those time evolutions, we also looked into flare ribbons observed by SDO/AIA. We examined 21 flare events, and found positive correlation between the "GOES duration" and the "ribbon length". We also found positive correlation between the "ribbon

  20. Variation of Static-PPP Positioning Accuracy Using GPS-Single Frequency Observations (Aswan, Egypt)

    NASA Astrophysics Data System (ADS)

    Farah, Ashraf

    2017-06-01

    Precise Point Positioning (PPP) is a technique used for position computation with a high accuracy using only one GNSS receiver. It depends on highly accurate satellite position and clock data rather than broadcast ephemeries. PPP precision varies based on positioning technique (static or kinematic), observations type (single or dual frequency) and the duration of collected observations. PPP-(dual frequency receivers) offers comparable accuracy to differential GPS. PPP-single frequency receivers has many applications such as infrastructure, hydrography and precision agriculture. PPP using low cost GPS single-frequency receivers is an area of great interest for millions of users in developing countries such as Egypt. This research presents a study for the variability of single frequency static GPS-PPP precision based on different observation durations.

  1. Recommended Rest Frequencies for Observed Interstellar Molecular Microwave Transitions - 2002 Revision

    National Institute of Standards and Technology Data Gateway

    SRD 116 NIST Recommended Rest Frequencies for Observed Interstellar Molecular Microwave Transitions - 2002 Revision (Web, free access)   Critically evaluated transition frequencies for the molecular transitions detected in interstellar and circumstellar clouds are presented.

  2. Interference effects in the sum frequency generation spectra of thin organic films. II: Applications to different thin-film systems.

    PubMed

    Tong, Yujin; Zhao, Yanbao; Li, Na; Ma, Yunsheng; Osawa, Masatoshi; Davies, Paul B; Ye, Shen

    2010-07-21

    In this paper, the results of the modeling calculations carried out for predicting the interference effects expected in the sum frequency generation (SFG) spectra of a specific thin-layer system, described in the accompanying paper, are tested by comparing them with the experimental spectra obtained for a real thin-layer film comprising an organic monolayer/variable thickness dielectric layer/gold substrate. In this system, two contributions to the SFG spectra arise, a resonant contribution from the organic film and a nonresonant contribution from the gold substrate. The modeling calculations are in excellent agreement with the experimental spectra over a wide range of thicknesses and for different polarization combinations. The introduction of another resonant monolayer adjacent to the gold substrate and with the molecules having a reverse orientation has a significant affect on the spectral shapes which is predicted. If a dielectric substrate such as CaF(2) is used instead of a gold substrate, only the spectral intensities vary with the film thickness but not the spectral shapes. The counterpropagating beam geometry will change both the thickness dependent spectral shapes and the intensity of different vibrational modes in comparison with a copropagating geometry. The influences of these experimental factors, i.e., the molecular orientational structure in the thin film, the nature of the substrate, and the selected incident beam geometry, on the experimental SFG spectra are quantitatively predicted by the calculations. The thickness effects on the signals from a SFG active monolayer contained in a thin liquid-layer cell of the type frequently used for in situ electrochemical measurements is also discussed. The modeling calculation is also valid for application to other thin-film systems comprising more than two resonant SFG active interfaces by appropriate choice of optical geometries and relevant optical properties.

  3. High-spectral resolution solar microwave observations

    NASA Technical Reports Server (NTRS)

    Hurford, G. J.

    1986-01-01

    The application of high-spectral resolution microwave observations to the study of solar activity is discussed with particular emphasis on the frequency dependence of microwave emission from solar active regions. A shell model of gyroresonance emission from active regions is described which suggest that high-spectral resolution, spatially-resolved observations can provide quantitative information about the magnetic field distribution at the base of the corona. Corresponding observations of a single sunspot with the Owens Valley frequency-agile interferometer at 56 frequencies between 1.2 and 14 Ghs are presented. The overall form of the observed size and brightness temperature spectra was consistent with expectations based on the shell model, although there were differences of potential physical significance. The merits and weaknesses of microwave spectroscopy as a technique for measuring magnetic fields in the solar corona are briefly discussed.

  4. Grading of cervical intraepithelial neoplasia using spatial frequency for optical histology

    NASA Astrophysics Data System (ADS)

    Pu, Yang; Jagtap, Jaidip; Pradhan, Asima; Alfano, Robert R.

    2014-03-01

    It is important to detect cervical dysplasia, Cervical Intraepithelial Neoplasia (CIN). CIN is the potentially premalignant and abnormal squamous cells on surface of cervix. In this study, the spatial frequency spectra of pre-cancer cervical tissues are used to detect differences among different grades of human cervical tissues. Seven sets of thick tissue sections of human cervix of normal, CIN 1, CIN 2, and CIN 3 tissues are studied. The confocal microscope images of the stromal region of normal and CIN human tissues were analyzed using Fast Fourier Transform (FFT) to generate the spatial spectra. It is observed that higher frequency components exist in CIN tissues than those in normal tissue, as well as those in higher grade CIN tissue than those in lower grade CIN tissue. The width of the spatial frequency of different types of tissues is used to create a criterion for CIN grading by training a support vector machine (SVM) classifier. The results show that the randomness of tissue structures from normal to different stages of precancer in cervical tissue can be recognized by fingerprints of the spatial frequency. The efficacy of spatial frequency analysis for CIN grading is evaluated as excellent since high AUC (area under the ROC curve), sensitivity and specificity are obtained by the statistics study. This works lays the foundation of using spatial frequency spectra for a histology evaluation.

  5. Adding a dimension to the infrared spectra of interfaces using heterodyne detected 2D sum-frequency generation (HD 2D SFG) spectroscopy

    PubMed Central

    Xiong, Wei; Laaser, Jennifer E.; Mehlenbacher, Randy D.; Zanni, Martin T.

    2011-01-01

    In the last ten years, two-dimensional infrared spectroscopy has become an important technique for studying molecular structures and dynamics. We report the implementation of heterodyne detected two-dimensional sum-frequency generation (HD 2D SFG) spectroscopy, which is the analog of 2D infrared (2D IR) spectroscopy, but is selective to noncentrosymmetric systems such as interfaces. We implement the technique using mid-IR pulse shaping, which enables rapid scanning, phase cycling, and automatic phasing. Absorptive spectra are obtained, that have the highest frequency resolution possible, from which we extract the rephasing and nonrephasing signals that are sometimes preferred. Using this technique, we measure the vibrational mode of CO adsorbed on a polycrystalline Pt surface. The 2D spectrum reveals a significant inhomogenous contribution to the spectral line shape, which is quantified by simulations. This observation indicates that the surface conformation and environment of CO molecules is more complicated than the simple “atop” configuration assumed in previous work. Our method can be straightforwardly incorporated into many existing SFG spectrometers. The technique enables one to quantify inhomogeneity, vibrational couplings, spectral diffusion, chemical exchange, and many other properties analogous to 2D IR spectroscopy, but specifically for interfaces. PMID:22143772

  6. Dual-frequency dielectrophoretic levitation of Canola protoplasts

    PubMed Central

    Kaler, Karan V. I. S.; Xie, Jing-Ping; Jones, Thomas B.; Paul, Reginald

    1992-01-01

    A novel dual-frequency excitation technique is introduced which permits investigation of the low-frequency dispersion of Canola plant protoplasts using feedback-controlled dielectrophoretic levitation. The upper and intermediate frequency spectra obtained using the new technique are generally consistent with previous work. However, below some cross-over frequency fOL, the protoplasts exhibit an apparent positive dielectrophoretic response that is not predicted by conventional theory. This cross-over frequency is linearly related to suspension conductivity, virtually independent of the suspension pH, and inversely proportional to the square of the cell radius. Examination of the complex Clausius-Mossotti polarization coefficient reveals that the observed positive dielectrophoretic response can not be accounted for in terms of Maxwell-Wagner polarization associated with a conventional layered model for the protoplast. The failure of straightforward enhancements to the protoplast model in explaining the low frequency behavior may indicate the presence of an electrophoretic contribution to the net observable force on the particle. To account for such fluid mechanical effects, it will be necessary to modify the existing dielectrophoretic force formulation. PMID:19431842

  7. Dual-frequency dielectrophoretic levitation of Canola protoplasts.

    PubMed

    Kaler, K V; Xie, J P; Jones, T B; Paul, R

    1992-07-01

    A novel dual-frequency excitation technique is introduced which permits investigation of the low-frequency dispersion of Canola plant protoplasts using feedback-controlled dielectrophoretic levitation. The upper and intermediate frequency spectra obtained using the new technique are generally consistent with previous work. However, below some cross-over frequency f(OL), the protoplasts exhibit an apparent positive dielectrophoretic response that is not predicted by conventional theory. This cross-over frequency is linearly related to suspension conductivity, virtually independent of the suspension pH, and inversely proportional to the square of the cell radius. Examination of the complex Clausius-Mossotti polarization coefficient reveals that the observed positive dielectrophoretic response can not be accounted for in terms of Maxwell-Wagner polarization associated with a conventional layered model for the protoplast. The failure of straightforward enhancements to the protoplast model in explaining the low frequency behavior may indicate the presence of an electrophoretic contribution to the net observable force on the particle. To account for such fluid mechanical effects, it will be necessary to modify the existing dielectrophoretic force formulation.

  8. Path spectra derived from inversion of source and site spectra for earthquakes in Southern California

    NASA Astrophysics Data System (ADS)

    Klimasewski, A.; Sahakian, V. J.; Baltay, A.; Boatwright, J.; Fletcher, J. B.; Baker, L. M.

    2017-12-01

    A large source of epistemic uncertainty in Ground Motion Prediction Equations (GMPEs) is derived from the path term, currently represented as a simple geometric spreading and intrinsic attenuation term. Including additional physical relationships between the path properties and predicted ground motions would produce more accurate and precise, region-specific GMPEs by reclassifying some of the random, aleatory uncertainty as epistemic. This study focuses on regions of Southern California, using data from the Anza network and Southern California Seismic network to create a catalog of events magnitude 2.5 and larger from 1998 to 2016. The catalog encompasses regions of varying geology and therefore varying path and site attenuation. Within this catalog of events, we investigate several collections of event region-to-station pairs, each of which share similar origin locations and stations so that all events have similar paths. Compared with a simple regional GMPE, these paths consistently have high or low residuals. By working with events that have the same path, we can isolate source and site effects, and focus on the remaining residual as path effects. We decompose the recordings into source and site spectra for each unique event and site in our greater Southern California regional database using the inversion method of Andrews (1986). This model represents each natural log record spectra as the sum of its natural log event and site spectra, while constraining each record to a reference site or Brune source spectrum. We estimate a regional, path-specific anelastic attenuation (Q) and site attenuation (t*) from the inversion site spectra and corner frequency from the inversion event spectra. We then compute the residuals between the observed record data, and the inversion model prediction (event*site spectra). This residual is representative of path effects, likely anelastic attenuation along the path that varies from the regional median attenuation. We examine the

  9. Automated Removal of Bad-Baseline Spectra from ACSIS/HARP Heterodyne Time Series

    NASA Astrophysics Data System (ADS)

    Currie, M. J.

    2013-10-01

    Heterodyne time-series spectral data often exhibit distorted or noisy baselines. These are either transient due to external interference or pickup; or affect a receptor throughout an observation or extended period, possibly due to a poor cable connection. While such spectra can be excluded manually, this is time consuming and prone to omission, especially for the high-frequency interference affecting just one or two spectra in typically several to twenty thousand, yet can produce undesirable artifacts in the reduced spectral cube. Further astronomers have tended to reject an entire receptor if any of its spectra are suspect; as a consequence the reduced products have lower signal-to-noise, and enhanced graticule patterns due to the variable coverage and detector relative sensitivities. This paper illustrates some of the types of aberrant spectra for ACSIS/HARP on the James Clerk Maxwell Telescope and the algorithms used to identify and remove them, applied within the ORAC-DR pipeline, and compares an integrated map with and without baseline filtering.

  10. Quantitative analysis of dinuclear manganese(II) EPR spectra

    NASA Astrophysics Data System (ADS)

    Golombek, Adina P.; Hendrich, Michael P.

    2003-11-01

    A quantitative method for the analysis of EPR spectra from dinuclear Mn(II) complexes is presented. The complex [(Me 3TACN) 2Mn(II) 2(μ-OAc) 3]BPh 4 ( 1) (Me 3TACN= N, N', N''-trimethyl-1,4,7-triazacyclononane; OAc=acetate 1-; BPh 4=tetraphenylborate 1-) was studied with EPR spectroscopy at X- and Q-band frequencies, for both perpendicular and parallel polarizations of the microwave field, and with variable temperature (2-50 K). Complex 1 is an antiferromagnetically coupled dimer which shows signals from all excited spin manifolds, S=1 to 5. The spectra were simulated with diagonalization of the full spin Hamiltonian which includes the Zeeman and zero-field splittings of the individual manganese sites within the dimer, the exchange and dipolar coupling between the two manganese sites of the dimer, and the nuclear hyperfine coupling for each manganese ion. All possible transitions for all spin manifolds were simulated, with the intensities determined from the calculated probability of each transition. In addition, the non-uniform broadening of all resonances was quantitatively predicted using a lineshape model based on D- and r-strain. As the temperature is increased from 2 K, an 11-line hyperfine pattern characteristic of dinuclear Mn(II) is first observed from the S=3 manifold. D- and r-strain are the dominate broadening effects that determine where the hyperfine pattern will be resolved. A single unique parameter set was found to simulate all spectra arising for all temperatures, microwave frequencies, and microwave modes. The simulations are quantitative, allowing for the first time the determination of species concentrations directly from EPR spectra. Thus, this work describes the first method for the quantitative characterization of EPR spectra of dinuclear manganese centers in model complexes and proteins. The exchange coupling parameter J for complex 1 was determined ( J=-1.5±0.3 cm-1; H ex=-2J S1· S2) and found to be in agreement with a previous

  11. A Comparison of the Raman Spectra and Crystal Chemistry of Norbergite and Clinohumite at High Pressure

    NASA Astrophysics Data System (ADS)

    Pease, A. M.; Gramsch, S. A.

    2017-12-01

    Humite group minerals n(Mg.Fe)2SiO4 - (Mg,Fe)(OH)2 have been suggested as possible candidates for water storage and transport in the mantle, and clinohumite in particular has been proposed as the source of ilmenite lamellae in Alpine ultrahigh pressure metamorphic terranes via its decomposition at high pressure and temperature. In this study, a comparison is made between the Raman spectra of norbergite (n = 1) and clinohumite (n = 4) up to 15 GPa to correlate the structural and vibrational properties of these two members of the group. All observed vibrational modes in the Raman spectra of both minerals increase in frequency with pressure, although the change in frequencies with pressure is much steeper in norbergite than for clinohumite. In norbergite, antisymmetric stretching modes of the SiO4 tetrahedra merge, but no such merging of modes occurs in clinohumite. In addition, the intensity of the antisymmetric stretching mode for clinohumite decreases dramatically in pressure compared to the intensity of the symmetric stretching mode. In the spectra of norbergite, these two modes retain their relative intensities with increasing pressure. The most striking difference between the spectra of norbergite and clinohumite is in the deformation modes of the brucite layer, which within the clinohumite structure retain their intensities with increasing pressure, while these modes are not observed in the spectra of norbergite. The nature of the Raman spectra and their evolution with pressure are correlated with the structural properties of the two minerals in terms of the interactions between olivine and brucite layers and the crystal chemistry of the humite group minerals.

  12. Vibrational spectra of ketamine hydrochloride and 3, 4-methylenedioxymethamphetamine in terahertz range

    NASA Astrophysics Data System (ADS)

    Wang, Guangqin; Shen, Jingling; Jia, Yan

    2007-07-01

    The terahertz spectrum of ketamine hydrochloride at room temperature, in the range of 0.2-2.6THz, has been measured by terahertz time-domain spectroscopy (TDS). Full-geometry optimizations and frequency calculations using the density functional theory (DFT) are also applied to predict the absorption spectra of ketamine hydrochloride and 3, 4-methylenedioxymethamphetamine (MDMA). The results of the simulation show qualitative agreement with the experimental data especially for MDMA, and the observed spectra features are assigned based on the DFT calculation. The results suggest that use of the terahertz TDS technique can be an effective method for the detection and inspection of illicit drugs.

  13. Experimental diagnostics and modeling of inductive phenomena at low frequencies in impedance spectra of proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Pivac, Ivan; Šimić, Boris; Barbir, Frano

    2017-10-01

    Representation of fuel cell processes by equivalent circuit models, involving resistance and capacitance elements representing activation losses on both anode and cathode in series with resistance representing ohmic losses, cannot capture and explain the inductive loop that may show up at low frequencies in Nyquist diagram representation of the electrochemical impedance spectra. In an attempt to explain the cause of the low-frequency inductive loop and correlate it with the processes within the fuel cell electrodes, a novel equivalent circuit model of a Proton Exchange Membrane (PEM) fuel cell has been proposed and experimentally verified here in detail. The model takes into account both the anode and the cathode, and has an additional resonant loop on each side, comprising of a resistance, capacitance and inductance in parallel representing the processes within the catalyst layer. Using these additional circuit elements, more accurate and better fits to experimental impedance data in the wide frequency range at different current densities, cell temperatures, humidity of gases, air flow stoichiometries and backpressures were obtained.

  14. The anharmonic quartic force field infrared spectra of three polycyclic aromatic hydrocarbons: Naphthalene, anthracene, and tetracene.

    PubMed

    Mackie, Cameron J; Candian, Alessandra; Huang, Xinchuan; Maltseva, Elena; Petrignani, Annemieke; Oomens, Jos; Buma, Wybren Jan; Lee, Timothy J; Tielens, Alexander G G M

    2015-12-14

    Current efforts to characterize and study interstellar polycyclic aromatic hydrocarbons (PAHs) rely heavily on theoretically predicted infrared (IR) spectra. Generally, such studies use the scaled harmonic frequencies for band positions and double harmonic approximation for intensities of species, and then compare these calculated spectra with experimental spectra obtained under matrix isolation conditions. High-resolution gas-phase experimental spectroscopic studies have recently revealed that the double harmonic approximation is not sufficient for reliable spectra prediction. In this paper, we present the anharmonic theoretical spectra of three PAHs: naphthalene, anthracene, and tetracene, computed with a locally modified version of the SPECTRO program using Cartesian derivatives transformed from Gaussian 09 normal coordinate force constants. Proper treatments of Fermi resonances lead to an impressive improvement on the agreement between the observed and theoretical spectra, especially in the C-H stretching region. All major IR absorption features in the full-scale matrix-isolated spectra, the high-temperature gas-phase spectra, and the most recent high-resolution gas-phase spectra obtained under supersonically cooled molecular beam conditions in the CH-stretching region are assigned.

  15. The anharmonic quartic force field infrared spectra of three polycyclic aromatic hydrocarbons: Naphthalene, anthracene, and tetracene

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mackie, Cameron J., E-mail: mackie@strw.leidenuniv.nl; Candian, Alessandra; Tielens, Alexander G. G. M.

    2015-12-14

    Current efforts to characterize and study interstellar polycyclic aromatic hydrocarbons (PAHs) rely heavily on theoretically predicted infrared (IR) spectra. Generally, such studies use the scaled harmonic frequencies for band positions and double harmonic approximation for intensities of species, and then compare these calculated spectra with experimental spectra obtained under matrix isolation conditions. High-resolution gas-phase experimental spectroscopic studies have recently revealed that the double harmonic approximation is not sufficient for reliable spectra prediction. In this paper, we present the anharmonic theoretical spectra of three PAHs: naphthalene, anthracene, and tetracene, computed with a locally modified version of the SPECTRO program using Cartesianmore » derivatives transformed from Gaussian 09 normal coordinate force constants. Proper treatments of Fermi resonances lead to an impressive improvement on the agreement between the observed and theoretical spectra, especially in the C–H stretching region. All major IR absorption features in the full-scale matrix-isolated spectra, the high-temperature gas-phase spectra, and the most recent high-resolution gas-phase spectra obtained under supersonically cooled molecular beam conditions in the CH-stretching region are assigned.« less

  16. Fine structure of the low-frequency spectra of heart rate and blood pressure.

    PubMed

    Kuusela, Tom A; Kaila, Timo J; Kähönen, Mika

    2003-10-13

    The aim of this study was to explore the principal frequency components of the heart rate and blood pressure variability in the low frequency (LF) and very low frequency (VLF) band. The spectral composition of the R-R interval (RRI) and systolic arterial blood pressure (SAP) in the frequency range below 0.15 Hz were carefully analyzed using three different spectral methods: Fast Fourier transform (FFT), Wigner-Ville distribution (WVD), and autoregression (AR). All spectral methods were used to create time-frequency plots to uncover the principal spectral components that are least dependent on time. The accurate frequencies of these components were calculated from the pole decomposition of the AR spectral density after determining the optimal model order--the most crucial factor when using this method--with the help of FFT and WVD methods. Spectral analysis of the RRI and SAP of 12 healthy subjects revealed that there are always at least three spectral components below 0.15 Hz. The three principal frequency components are 0.026 +/- 0.003 (mean +/- SD) Hz, 0.076 +/- 0.012 Hz, and 0.117 +/- 0.016 Hz. These principal components vary only slightly over time. FFT-based coherence and phase-function analysis suggests that the second and third components are related to the baroreflex control of blood pressure, since the phase difference between SAP and RRI was negative and almost constant, whereas the origin of the first component is different since no clear SAP-RRI phase relationship was found. The above data indicate that spontaneous fluctuations in heart rate and blood pressure within the standard low-frequency range of 0.04-0.15 Hz typically occur at two frequency components rather than only at one as widely believed, and these components are not harmonically related. This new observation in humans can help explain divergent results in the literature concerning spontaneous low-frequency oscillations. It also raises methodological and computational questions regarding

  17. Beat frequency interference pattern characteristics study

    NASA Technical Reports Server (NTRS)

    Ott, J. H.; Rice, J. S.

    1981-01-01

    The frequency spectra and corresponding beat frequencies created by the relative motions between multiple Solar Power Satellites due to solar wind, lunar gravity, etc. were analyzed. The results were derived mathematically and verified through computer simulation. Frequency spectra plots were computer generated. Detailed computations were made for the seven following locations in the continental US: Houston, Tx.; Seattle, Wa.; Miami, Fl.; Chicago, Il.; New York, NY; Los Angeles, Ca.; and Barberton, Oh.

  18. Can We Infer Ocean Dynamics from Altimeter Wavenumber Spectra?

    NASA Technical Reports Server (NTRS)

    Richman, James; Shriver, Jay; Arbic, Brian

    2012-01-01

    The wavenumber spectra of sea surface height (SSH) and kinetic energy (KE) have been used to infer the dynamics of the ocean. When quasi-geostrophic dynamics (QG) or surface quasi-geostrophic (SQG) turbulence dominate and an inertial subrange exists, a steep SSH wavenumber spectrum is expected with k-5 for QG turbulence and a flatter k-11/3 for SQG turbulence. However, inspection of the spectral slopes in the mesoscale band of 70 to 250 km shows that the altimeter wavenumber slopes typically are much flatter than the QG or SQG predictions over most of the ocean. Comparison of the altimeter wavenumber spectra with the spectra estimated from the output of an eddy resolving global ocean circulation model (the Hybrid Coordinate Ocean Model, HYCOM, at 1/25 resolution), which is forced by high frequency winds and includes the astronomical forcing of the sun and the moon, suggests that the flatter slopes of the altimeter may arise from three possible sources, the presence of internal waves, the lack of an inertial subrange in the 70 to 250 km band and noise or submesoscales at small scales. When the wavenumber spectra of SSH and KE are estimated near the internal tide generating regions, the resulting spectra are much flatter than the expectations of QG or SQG theory. If the height and velocity variability are separated into low frequency (periods greater than 2 days) and high frequency (periods less than a day), then a different pattern emerges with a relatively flat wavenumber spectrum at high frequency and a steeper wavenumber spectrum at low frequency. The stationary internal tides can be removed from the altimeter spectrum, which steepens the spectral slopes in the energetic internal wave regions. Away from generating regions where the internal waves

  19. iMARS--mutation analysis reporting software: an analysis of spontaneous cII mutation spectra.

    PubMed

    Morgan, Claire; Lewis, Paul D

    2006-01-31

    The sensitivity of any mutational assay is determined by the level at which spontaneous mutations occur in the corresponding untreated controls. Establishing the type and frequency at which mutations occur naturally within a test system is essential if one is to draw scientifically sound conclusions regarding chemically induced mutations. Currently, mutation-spectra analysis is laborious and time-consuming. Thus, we have developed iMARS, a comprehensive mutation-spectrum analysis package that utilises routinely used methodologies and visualisation tools. To demonstrate the use and capabilities of iMARS, we have analysed the distribution, types and sequence context of spontaneous base substitutions derived from the cII gene mutation assay in transgenic animals. Analysis of spontaneous mutation spectra revealed variation both within and between the transgenic rodent test systems Big Blue Mouse, MutaMouse and Big Blue Rat. The most common spontaneous base substitutions were G:C-->A:T transitions and G:C-->T:A transversions. All Big Blue Mouse spectra were significantly different from each other by distribution and nearly all by mutation type, whereas the converse was true for the other test systems. Twenty-eight mutation hotspots were observed across all spectra generally occurring in CG, GA/TC, GG and GC dinucleotides. A mutation hotspot at nucleotide 212 occurred at a higher frequency in MutaMouse and Big Blue Rat. In addition, CG dinucleotides were the most mutable in all spectra except two Big Blue Mouse spectra. Thus, spontaneous base-substitution spectra showed more variation in distribution, type and sequence context in Big Blue Mouse relative to spectra derived from MutaMouse and Big Blue Rat. The results of our analysis provide a baseline reference for mutation studies utilising the cII gene in transgenic rodent models. The potential differences in spontaneous base-substitution spectra should be considered when making comparisons between these test systems

  20. Gigahertz-peaked spectra pulsars in Pulsar Wind Nebulae

    NASA Astrophysics Data System (ADS)

    Basu, R.; RoŻko, K.; Kijak, J.; Lewandowski, W.

    2018-04-01

    We have carried out a detailed study of the spectral nature of six pulsars surrounded by pulsar wind nebulae (PWNe). The pulsar flux density was estimated using the interferometric imaging technique of the Giant Metrewave Radio Telescope at three frequencies 325, 610, and 1280 MHz. The spectra showed a turnover around gigahertz frequency in four out of six pulsars. It has been suggested that the gigahertz-peaked spectrum (GPS) in pulsars arises due to thermal absorption of the pulsar emission in surrounding medium like PWNe, H II regions, supernova remnants, etc. The relatively high incidence of GPS behaviour in pulsars surrounded by PWNe imparts further credence to this view. The pulsar J1747-2958 associated with the well-known Mouse nebula was also observed in our sample and exhibited GPS behaviour. The pulsar was detected as a point source in the high-resolution images. However, the pulsed emission was not seen in the phased-array mode. It is possible that the pulsed emission was affected by extreme scattering causing considerable smearing of the emission at low radio frequencies. The GPS spectra were modelled using the thermal free-free absorption and the estimated absorber properties were largely consistent with PWNe. The spatial resolution of the images made it unlikely that the point source associated with J1747-2958 was the compact head of the PWNe, but the synchrotron self-absorption seen in such sources was a better fit to the estimated spectral shape.

  1. Evaluation of burst-mode LDA spectra with implications

    NASA Astrophysics Data System (ADS)

    Velte, Clara; George, William

    2009-11-01

    Burst-mode LDA spectra, as described in [1], are compared to spectra obtained from corresponding HWA measurements using the FFT in a round jet and cylinder wake experiment. The phrase ``burst-mode LDA'' refers to an LDA which operates with at most one particle present in the measuring volume at a time. Due to the random sampling and velocity bias of the LDA signal, the Direct Fourier Transform with accompanying weighting by the measured residence times was applied to obtain a correct interpretation of the spectral estimate. Further, the self-noise was removed as described in [2]. In addition, resulting spectra from common interpolation and uniform resampling techniques are compared to the above mentioned estimates. The burst-mode LDA spectra are seen to concur well with the HWA spectra up to the emergence of the noise floor, caused mainly by the intermittency of the LDA signal. The interpolated and resampled counterparts yield unphysical spectra, which are buried in frequency dependent noise and step noise, except at very high LDA data rates where they perform well up to a limited frequency.[4pt] [1] Buchhave, P. PhD Thesis, SUNY/Buffalo, 1979.[0pt] [2] Velte, C.M. PhD Thesis, DTU/Copenhagen, 2009.

  2. Frequency-selective quantitation of short-echo time 1H magnetic resonance spectra

    NASA Astrophysics Data System (ADS)

    Poullet, Jean-Baptiste; Sima, Diana M.; Van Huffel, Sabine; Van Hecke, Paul

    2007-06-01

    Accurate and efficient filtering techniques are required to suppress large nuisance components present in short-echo time magnetic resonance (MR) spectra. This paper discusses two powerful filtering techniques used in long-echo time MR spectral quantitation, the maximum-phase FIR filter (MP-FIR) and the Hankel-Lanczos Singular Value Decomposition with Partial ReOrthogonalization (HLSVD-PRO), and shows that they can be applied to their more complex short-echo time spectral counterparts. Both filters are validated and compared through extensive simulations. Their properties are discussed. In particular, the capability of MP-FIR for dealing with macromolecular components is emphasized. Although this property does not make a large difference for long-echo time MR spectra, it can be important when quantifying short-echo time spectra.

  3. Comparing coastal ocean wavenumber spectra for surface currents and sea level from observations by HF-radar (CODAR) and CryoSat-2 satellite altimetry

    NASA Astrophysics Data System (ADS)

    Wilkin, J.; Hunter, E. J.

    2016-12-01

    An extensive CODAR HF-radar network has been acquiring observations of surface currents in the Mid Atlantic Bight (MAB) continental shelf ocean for several years. The fundamental CODAR observation is the component of velocity in the radial direction of view from a single antenna, geo-located by range and azimuth. Surface velocity vectors can be computed by combining radials observed by multiple sites. We exploit the concave geometry of the MAB coastline and the many possible radial views from numerous antennae to select transects that are substantially along or across isobaths, and compute wavenumber spectra for both along-shelf and across-shelf components of velocity. Comparing spectra computed from radial velocities to spectra for the same vector component extracted from the total vectors we find that the optimal interpolation combiner significantly damps energy for wavenumbers exceeding 0.03 km-1. This has ramifications for our error model in 4DVAR assimilation of CODAR total velocity. We further computed wavenumber spectra for altimeter SSHA from CryoSat-2 for ensembles of tracks in the same region of the MAB that were predominantly across- or along-shelf. Velocity spectra exhibit power law dependence close to k-5/3 down to the limit of resolution, while SSHA spectra are somewhat steeper. The constraint that bathymetry exerts on circulation on this broad, shallow shelf could influence the spectral characteristics of variability, as could winter well mixed versus summer strongly stratified conditions. Velocity and SSHA spectra are being compared to similar spectral estimates from model simulations as an assessment of convergence of the model resolution, and to explore theories of surface quasi-geostrophic turbulence that might explain the observed spectral characteristics.

  4. Temperature Dependence of Brillouin Light Scattering Spectra of Acoustic Phonons in Silicon

    NASA Astrophysics Data System (ADS)

    Somerville, Kevin; Klimovich, Nikita; An, Kyongmo; Sullivan, Sean; Weathers, Annie; Shi, Li; Li, Xiaoqin

    2015-03-01

    Thermal management represents an outstanding challenge in many areas of technology. Electrons, optical phonons, and acoustic phonons are often driven out of local equilibrium in electronic devices or during laser-material interaction processes. Interest in non-equilibrium transport processes has motivated the development of Raman spectroscopy as a local temperature sensor of optical phonons and intermediate frequency acoustic phonons, whereas Brillouin light scattering (BLS) has recently been explored as a temperature sensor of low-frequency acoustic phonons. Here, we report temperature dependent BLS spectra of silicon, with Raman spectra taken simultaneously for comparison. The origins of the observed temperature dependence of the BLS peak position, linewidth, and intensity are examined in order to evaluate their potential use as temperature sensors for acoustic phonons. We determine that the integrated BLS intensity can be used measure the temperature of specific acoustic phonon modes. This work is supported by National Science Foundation (NSF) Thermal Transport Processes Program under Grant CBET-1336968.

  5. Analysis of spatial and temporal spectra of liquid film surface in annular gas-liquid flow

    NASA Astrophysics Data System (ADS)

    Alekseenko, Sergey; Cherdantsev, Andrey; Heinz, Oksana; Kharlamov, Sergey; Markovich, Dmitriy

    2013-09-01

    Wavy structure of liquid film in annular gas-liquid flow without liquid entrainment consists of fast long-living primary waves and slow short-living secondary waves. In present paper, results of spectral analysis of this wavy structure are presented. Application of high-speed LIF technique allowed us to perform such analysis in both spatial and temporal domains. Power spectra in both domains are characterized by one-humped shape with long exponential tail. Influence of gas velocity, liquid Reynolds number, liquid viscosity and pipe diameter on frequency of the waves is investigated. When gravity effect is much lesser than the shear stress, similarity of power spectra at different gas velocities is observed. Using combination of spectral analysis and identification of characteristic lines of primary waves, frequency of generation of secondary waves by primary waves is measured.

  6. Frequency comb generation in a continuously pumped optical parametric oscillator

    NASA Astrophysics Data System (ADS)

    Mosca, S.; Parisi, M.; Ricciardi, I.; Leo, F.; Hansson, T.; Erkintalo, M.; Maddaloni, P.; De Natale, P.; Wabnitz, S.; De Rosa, M.

    2018-02-01

    We demonstrate optical frequency comb generation in a continuously pumped optical parametric oscillator, in the parametric region around half of the pump frequency. We also model the dynamics of such quadratic combs using a single time-domain mean-field equation, and obtain simulation results that are in good agreement with experimentally observed spectra. Moreover, we numerically investigate the coherence properties of simulated combs, showing the existence of correlated and phase-locked combs. Our work could pave the way for a new class of frequency comb sources, which may enable straightforward access to new spectral regions and stimulate novel applications of frequency combs.

  7. Meteor radar observations of vertically propagating low-frequency inertia-gravity waves near the southern polar mesopause region

    NASA Astrophysics Data System (ADS)

    Song, I.-S.; Lee, C.; Kim, J.-H.; Jee, G.; Kim, Y.-H.; Choi, H.-J.; Chun, H.-Y.; Kim, Y. H.

    2017-04-01

    Vertically propagating low-frequency inertia-gravity waves (IGWs) are retrieved from meteor radar winds observed at King Sejong Station (KSS: 62.22°S, 58.78°W), Antarctica. IGW horizontal winds extracted from temporal band-pass filtering in regular time-height bins show the frequent occurrence of IGWs with the downward phase progression and the counterclockwise rotation of their horizontal wind vectors with time (i.e., upward energy propagation) near the mesopause region throughout the whole year of 2014. The vertical wavelengths of the observed IGWs roughly range from 14 km to more than 20 km, which is consistent with previous observational studies on the mesospheric IGWs over Antarctica. Stokes parameters and rotary spectra computed from the hodographs of the IGW horizontal wind components reveal that the intrinsic frequencies of the upward propagating IGWs are |f|-3|f| with seasonal variations of the relative predominance between |f|-2|f| and 2|f|-3|f|, where f is the Coriolis parameter at KSS. The hodograph analysis also indicates that the N-S propagation is dominant in austral summer, while the NE-SW propagation is pronounced in austral winter. The propagation direction is discussed in relation to the generation of IGWs due to dynamical imbalances occurring in the tropospheric and stratospheric jet flow systems. Ray tracing results indicate that the N-S propagation in summer may be due to the jet flow systems roughly north of KSS and the NE-SW propagation in winter may be either the SW propagation from the jet flow systems northeast of KSS or the NE propagation (around the South Pole) from the south of Australia and Southern Indian and Pacific Oceans.

  8. Infrared Spectra of Polycyclic Aromatic Hydrocarbons: Methyl Substitution and Loss of H

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W.; Langhoff, Stephen R.; Arnold, James O. (Technical Monitor)

    1998-01-01

    The B3LYP approach, in conjunction with the 4-31G basis set, is used to compute the harmonic frequencies of 1- and 2-methylnaphthalene, 1-, 2-, and 9-methylanthracene, and their cations. The IR spectra of the methyl substituted species are very similar to the parent spectra, except for the addition of the methyl C-H stretch at lower frequency than the aromatic C-H stretch. The loss of a single hydrogen from naphthalene, anthracene, and their cations is shown to have a very small effect on the IR spectra. Loss of a methyl hydrogen from 1- or 2-methylnaphthalene, or their cations, is shown to shift the side group C-H frequencies from below aromatic hydrogen stretching frequencies to above them. The loss of IT from 2-methylenenaphthalene shows only a small shift in the side group C-H stretching frequency.

  9. Mid-Infrared Vibrational Spectra of Discrete Acetone-Ligated Cerium Hydroxide Cations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Groenewold, G. S.; Gianotto, Anita K.; Cossel, Kevin C.

    2007-02-15

    Cerium (III) hydroxy reactive sites are responsible for several important heterogeneous catalysis processes, and understanding the reaction chemistry of substrate molecules like CO, H2O, and CH3OH as they occur in heterogeneous media is a challenging task. We report here the first infrared spectra of model gas-phase cerium complexes and use the results as a benchmark to assist evaluation of the accuracy of ab initio calculations. Complexes containing [CeOH]2+ ligated by three- and four-acetone molecules were generated by electrospray ionization and characterized using wavelength-selective infrared multiple photon dissociation (IRMPD). The C=O stretching frequency for the [CeOH(acetone)4]2+ species appeared at 1650 cm-1more » and was red-shifted by 90 cm-1 compared to unligated acetone. The magnitude of this shift for the carbonyl frequency was even greater for the [CeOH(acetone)3]2+ complex: the IRMPD peak consisted of two dissociation channels, an initial elimination of acetone at 1635 cm-1, and elimination of acetone accompanied by a serial charge separation producing [CeO(acetone)]+ at 1599 cm-1, with the overall frequency centered at 1616 cm-1. The increasing red shift observed as the number of acetone ligands decreases from four to three is consistent with transfer of more electron density per ligand in the less coordinated complexes. The lower frequency measured for the elimination/charge separation process is likely due to anharmonicity resulting from population of higher vibrational states. The C-C stretching frequency in the complexes is also influenced by coordination to the metal: it is blue-shifted compared to bare acetone, indicating a slight strengthening of the C-C bond in the complex, with the intensity of the absorption decreasing with decreasing ligation. Density functional theory (DFT) calculations using three different functionals (LDA, B3LYP, and PBE0) are used to predict the infrared spectra of the complexes. Calculated frequencies for the

  10. Correlations Between Variations in Solar EUV and Soft X-Ray Irradiance and Photoelectron Energy Spectra Observed on Mars and Earth

    NASA Technical Reports Server (NTRS)

    Peterson, W. K.; Brain, D. A.; Mitchell, D. L.; Bailey, S. M.; Chamberlin, P. C.

    2013-01-01

    Solar extreme ultraviolet (EUV; 10-120 nm) and soft X-ray (XUV; 0-10 nm) radiation are major heat sources for the Mars thermosphere as well as the primary source of ionization that creates the ionosphere. In investigations of Mars thermospheric chemistry and dynamics, solar irradiance models are used to account for variations in this radiation. Because of limited proxies, irradiance models do a poor job of tracking the significant variations in irradiance intensity in the EUV and XUV ranges over solar rotation time scales when the Mars-Sun-Earth angle is large. Recent results from Earth observations show that variations in photoelectron energy spectra are useful monitors of EUV and XUV irradiance variability. Here we investigate photoelectron energy spectra observed by the Mars Global Surveyor (MGS) Electron Reflectometer (ER) and the FAST satellite during the interval in 2005 when Earth, Mars, and the Sun were aligned. The Earth photoelectron data in selected bands correlate well with calculations based on 1 nm resolution observations above 27 nm supplemented by broadband observations and a solar model in the 0-27 nm range. At Mars, we find that instrumental and orbital limitations to the identifications of photoelectron energy spectra in MGS/ER data preclude their use as a monitor of solar EUV and XUV variability. However, observations with higher temporal and energy resolution obtained at lower altitudes on Mars might allow the separation of the solar wind and ionospheric components of electron energy spectra so that they could be used as reliable monitors of variations in solar EUV and XUV irradiance than the time shifted, Earth-based, F(10.7) index currently used.

  11. Correlations between variations in solar EUV and soft X-ray irradiance and photoelectron energy spectra observed on Mars and Earth

    NASA Astrophysics Data System (ADS)

    Peterson, W. K.; Brain, D. A.; Mitchell, D. L.; Bailey, S. M.; Chamberlin, P. C.

    2013-11-01

    extreme ultraviolet (EUV; 10-120 nm) and soft X-ray (XUV; 0-10 nm) radiation are major heat sources for the Mars thermosphere as well as the primary source of ionization that creates the ionosphere. In investigations of Mars thermospheric chemistry and dynamics, solar irradiance models are used to account for variations in this radiation. Because of limited proxies, irradiance models do a poor job of tracking the significant variations in irradiance intensity in the EUV and XUV ranges over solar rotation time scales when the Mars-Sun-Earth angle is large. Recent results from Earth observations show that variations in photoelectron energy spectra are useful monitors of EUV and XUV irradiance variability. Here we investigate photoelectron energy spectra observed by the Mars Global Surveyor (MGS) Electron Reflectometer (ER) and the FAST satellite during the interval in 2005 when Earth, Mars, and the Sun were aligned. The Earth photoelectron data in selected bands correlate well with calculations based on 1 nm resolution observations above 27 nm supplemented by broadband observations and a solar model in the 0-27 nm range. At Mars, we find that instrumental and orbital limitations to the identifications of photoelectron energy spectra in MGS/ER data preclude their use as a monitor of solar EUV and XUV variability. However, observations with higher temporal and energy resolution obtained at lower altitudes on Mars might allow the separation of the solar wind and ionospheric components of electron energy spectra so that they could be used as reliable monitors of variations in solar EUV and XUV irradiance than the time shifted, Earth-based, F10.7 index currently used.

  12. A simple model for strong ground motions and response spectra

    USGS Publications Warehouse

    Safak, Erdal; Mueller, Charles; Boatwright, John

    1988-01-01

    A simple model for the description of strong ground motions is introduced. The model shows that response spectra can be estimated by using only four parameters of the ground motion, the RMS acceleration, effective duration and two corner frequencies that characterize the effective frequency band of the motion. The model is windowed band-limited white noise, and is developed by studying the properties of two functions, cumulative squared acceleration in the time domain, and cumulative squared amplitude spectrum in the frequency domain. Applying the methods of random vibration theory, the model leads to a simple analytical expression for the response spectra. The accuracy of the model is checked by using the ground motion recordings from the aftershock sequences of two different earthquakes and simulated accelerograms. The results show that the model gives a satisfactory estimate of the response spectra.

  13. The effects of conduit length and acoustic velocity on conduit resonance: Implications for low-frequency events

    NASA Astrophysics Data System (ADS)

    Sturton, Susan; Neuberg, Jürgen

    2006-03-01

    Low-frequency seismic events at volcanoes are modelled as the seismic wavefield from a magma-filled conduit embedded in a solid country rock using a finite difference method. The effects of varying the conduit length and the impedance contrast between the magma and the country rock are examined, generating a range of possible signals. Short-windowed spectrograms are used to look at the time-frequency relationships within the events in detail, and some of the possible variations are identified using a series of schematic spectrograms. The numerical results are compared to examples of observed seismic data from Soufrière Hills Volcano, Montserrat. While the spectra of the observed events are often different to the spectra of the numerical results, the spectrograms have similar features and show that the low-frequency events from Montserrat are composed of discrete subevents.

  14. Observations of neutral iron emission in twilight spectra

    NASA Technical Reports Server (NTRS)

    Tepley, C. A.; Meriwether, J. W., Jr.; Walker, J. C. G.; Mathews, J. D.

    1981-01-01

    A method is presented for the analysis of twilight airglow spectra that may be contaminated by atmospheric continuum emission of unknown brightness. The necessity of correcting for this continuum emission when measuring weak airglow features in twilight is illustrated by application of the method to the neutral iron line at 3860 A.

  15. Isotope effects on the optical spectra of semiconductors

    NASA Astrophysics Data System (ADS)

    Cardona, Manuel; Thewalt, M. L. W.

    2005-10-01

    Since the end of the cold war, macroscopic amounts of separated stable isotopes of most elements have been available “off the shelf” at affordable prices. Using these materials, single crystals of many semiconductors have been grown and the dependence of their physical properties on isotopic composition has been investigated. The most conspicuous effects observed have to do with the dependence of phonon frequencies and linewidths on isotopic composition. These affect the electronic properties of solids through the mechanism of electron-phonon interaction, in particular, in the corresponding optical excitation spectra and energy gaps. This review contains a brief introduction to the history, availability, and characterization of stable isotopes, including their many applications in science and technology. It is followed by a concise discussion of the effects of isotopic composition on the vibrational spectra, including the influence of average isotopic masses and isotopic disorder on the phonons. The final sections deal with the effects of electron-phonon interaction on energy gaps, the concomitant effects on the luminescence spectra of free and bound excitons, with particular emphasis on silicon, and the effects of isotopic composition of the host material on the optical transitions between the bound states of hydrogenic impurities.

  16. Low-frequency radio observations of poor clusters of galaxies

    NASA Technical Reports Server (NTRS)

    Hanisch, R. J.; White, R. A.

    1981-01-01

    Observations have been made at the Clark Lake Radio Observatory of 16 poor clusters of galaxies at 34.3 MHz. Four of the poor clusters were detected at flux densities greater than 20 Jy. The spectra of the four detected clusters are all rather steep. Two of the detected clusters, AWM 4 and AWM 5, are also known to be X-ray sources. The possibility that the X-ray-emitting gas is heated by Coulomb interactions with the relativistic electrons responsible for the radio emission is investigated, and it is found that the observed X-ray luminosities can be accounted for if the electron energy spectrum extends to very low energies (gamma approximately 1-10). Collective plasma effects may increase the heating efficiency and eliminate the need to extrapolate the electron energy spectrum to such low values.

  17. Fine structure of the low-frequency spectra of heart rate and blood pressure

    PubMed Central

    Kuusela, Tom A; Kaila, Timo J; Kähönen, Mika

    2003-01-01

    Background The aim of this study was to explore the principal frequency components of the heart rate and blood pressure variability in the low frequency (LF) and very low frequency (VLF) band. The spectral composition of the R–R interval (RRI) and systolic arterial blood pressure (SAP) in the frequency range below 0.15 Hz were carefully analyzed using three different spectral methods: Fast Fourier transform (FFT), Wigner-Ville distribution (WVD), and autoregression (AR). All spectral methods were used to create time–frequency plots to uncover the principal spectral components that are least dependent on time. The accurate frequencies of these components were calculated from the pole decomposition of the AR spectral density after determining the optimal model order – the most crucial factor when using this method – with the help of FFT and WVD methods. Results Spectral analysis of the RRI and SAP of 12 healthy subjects revealed that there are always at least three spectral components below 0.15 Hz. The three principal frequency components are 0.026 ± 0.003 (mean ± SD) Hz, 0.076 ± 0.012 Hz, and 0.117 ± 0.016 Hz. These principal components vary only slightly over time. FFT-based coherence and phase-function analysis suggests that the second and third components are related to the baroreflex control of blood pressure, since the phase difference between SAP and RRI was negative and almost constant, whereas the origin of the first component is different since no clear SAP–RRI phase relationship was found. Conclusion The above data indicate that spontaneous fluctuations in heart rate and blood pressure within the standard low-frequency range of 0.04–0.15 Hz typically occur at two frequency components rather than only at one as widely believed, and these components are not harmonically related. This new observation in humans can help explain divergent results in the literature concerning spontaneous low-frequency oscillations. It also raises methodological

  18. RM-CLEAN: RM spectra cleaner

    NASA Astrophysics Data System (ADS)

    Heald, George

    2017-08-01

    RM-CLEAN reads in dirty Q and U cubes, generates rmtf based on the frequencies given in an ASCII file, and cleans the RM spectra following the algorithm given by Brentjens (2007). The output cubes contain the clean model components and the CLEANed RM spectra. The input cubes must be reordered with mode=312, and the output cubes will have the same ordering and thus must be reordered after being written to disk. RM-CLEAN runs as a MIRIAD (ascl:1106.007) task and a Python wrapper is included with the code.

  19. Analysis of Earthquake Source Spectra in Salton Trough

    NASA Astrophysics Data System (ADS)

    Chen, X.; Shearer, P. M.

    2009-12-01

    Previous studies of the source spectra of small earthquakes in southern California show that average Brune-type stress drops vary among different regions, with particularly low stress drops observed in the Salton Trough (Shearer et al., 2006). The Salton Trough marks the southern end of the San Andreas Fault and is prone to earthquake swarms, some of which are driven by aseismic creep events (Lohman and McGuire, 2007). In order to learn the stress state and understand the physical mechanisms of swarms and slow slip events, we analyze the source spectra of earthquakes in this region. We obtain Southern California Seismic Network (SCSN) waveforms for earthquakes from 1977 to 2009 archived at the Southern California Earthquake Center (SCEC) data center, which includes over 17,000 events. After resampling the data to a uniform 100 Hz sample rate, we compute spectra for both signal and noise windows for each seismogram, and select traces with a P-wave signal-to-noise ratio greater than 5 between 5 Hz and 15 Hz. Using selected displacement spectra, we isolate the source spectra from station terms and path effects using an empirical Green’s function approach. From the corrected source spectra, we compute corner frequencies and estimate moments and stress drops. Finally we analyze spatial and temporal variations in stress drop in the Salton Trough and compare them with studies of swarms and creep events to assess the evolution of faulting and stress in the region. References: Lohman, R. B., and J. J. McGuire (2007), Earthquake swarms driven by aseismic creep in the Salton Trough, California, J. Geophys. Res., 112, B04405, doi:10.1029/2006JB004596 Shearer, P. M., G. A. Prieto, and E. Hauksson (2006), Comprehensive analysis of earthquake source spectra in southern California, J. Geophys. Res., 111, B06303, doi:10.1029/2005JB003979.

  20. FT-IR and FT-Raman spectra of cimetidine and its metallocomplexes

    NASA Astrophysics Data System (ADS)

    Barańska, M.; Proniewicz, L. M.

    1999-11-01

    We present vibrational spectra of three stable, well-reproducible, polymorphic forms of cimetidine ( cim), a drug which is a powerful histamine H 2-receptor antagonist used in the treatment of peptic ulcer and the Zollinger-Ellison syndrome. Assignments of Raman and IR bands are made using semiempirical methods: MNDO, AM1 and PM3. We also describe the synthesis of Me( cim) 2(ClO 4) 2, where Me=Cu(II), Cd(II), Co(II) and Ni(II), and present their vibrational data. We show that the obtained complexes are isostructural, however a metal ion that occupies a center of octahedral unit introduces some distortions that can be seen in the spectra. We also make tentative assignment of metal-ligand stretching modes observed in low frequency range.

  1. The Electronic Structure and Spectra of Triphenylamines Functionalized by Phenylethynyl Groups

    NASA Astrophysics Data System (ADS)

    Baryshnikov, G. V.; Minaeva, V. A.; Minaev, B. F.; Grigoras, M.

    2018-01-01

    We study the features of the electronic structure and the IR, UV, and visible spectra of a series of triphenylamines substituted with phenylethynyl groups. The analysis is performed at the level of the density functional theory (DFT) and its nonstationary version in comparison with the experimental data of IR and electron spectroscopy. It is shown that, in the excited state, there is a change in the alternation of single, double, and triple bonds in accordance with the character of bonding and antibonding in the lowest vacant molecular orbital. The gradual introduction of additional phenylethynyl groups does not cause frequency shifts in the IR spectra of the molecules under study, but significantly affects the intensity of the corresponding IR bands. A similar effect is also observed in the electronic-absorption spectra of these compounds. This can be used for optical tuning of triphenylamines as promising materials for organic light-emitting diodes and solar cells.

  2. Maven Observations of Electron-Induced Whistler Mode Waves in the Martian Magnetosphere

    NASA Technical Reports Server (NTRS)

    Harada, Y.; Andersson, L.; Fowler, C. M.; Mitchell, D. L.; Halekas, J. S.; Mazelle, C.; Espley, J.; DiBraccio, G. A.; McFadden, J. P.; Brian, D. A.; hide

    2016-01-01

    We report on narrowband electromagnetic waves at frequencies between the local electron cyclotron and lower hybrid frequencies observed by the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft in the Martian induced magnetosphere. The peaked electric field wave spectra below the electron cyclotron frequency were first observed by Phobos-2 in the Martian magnetosphere, but the lack of magnetic field wave data prevented definitive identification of the wave mode and their generation mechanisms remain unclear. Analysis of electric and magnetic field wave spectra obtained by MAVEN demonstrates that the observed narrowband waves have properties consistent with the whistler mode. Linear growth rates computed from the measured electron velocity distributions suggest that these whistler mode waves can be generated by cyclotron resonance with anisotropic electrons. Large electron anisotropy in the Martian magnetosphere is caused by absorption of parallel electrons by the collisional atmosphere. The narrowband whistler mode waves and anisotropic electrons are observed on both open and closed field lines and have similar spatial distributions in MSO and planetary coordinates. Some of the waves on closed field lines exhibit complex frequency-time structures such as discrete elements of rising tones and two bands above and below half the electron cyclotron frequency. These MAVEN observations indicate that whistler mode waves driven by anisotropic electrons, which are commonly observed in intrinsic magnetospheres and at unmagnetized airless bodies, are also present at Mars. The wave-induced electron precipitation into the Martian atmosphere should be evaluated in future studies.

  3. Vibrational spectra, UV and NMR, first order hyperpolarizability and HOMO-LUMO analysis of 2-amino-4-chloro-6-methylpyrimidine.

    PubMed

    Jayavarthanan, T; Sundaraganesan, N; Karabacak, M; Cinar, M; Kurt, M

    2012-11-01

    The solid phase FTIR and FT-Raman spectra of 2-amino-4-chloro-6-methylpyrimidine (2A4Cl6MP) have been recorded in the regions 400-4000 and 50-4,000 cm(-1), respectively. The spectra have been interpreted interms of fundamentals modes, combination and overtone bands. The structure of the molecule has been optimized and the structural characteristics have been determined by density functional theory (B3LYP) method with 6-311++G(d,p) as basis set. The vibrational frequencies were calculated and were compared with the experimental frequencies, which yield good agreement between observed and calculated frequencies. The infrared and Raman spectra have also been predicted from the calculated intensities. (1)H and (13)C NMR spectra were recorded and (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecule were calculated using the gauge independent atomic orbital (GIAO) method. UV-Vis spectrum of the compound was recorded in the region 200-400 nm and the electronic properties HOMO and LUMO energies were measured by time-dependent TD-DFT approach. Nonlinear optical and thermodynamic properties were interpreted. All the calculated results were compared with the available experimental data of the title molecule. Copyright © 2012 Elsevier B.V. All rights reserved.

  4. Extreme ultraviolet spectra of multiply charged tungsten ions

    NASA Astrophysics Data System (ADS)

    Mita, Momoe; Sakaue, Hiroyuki A.; Kato, Daiji; Murakami, Izumi; Nakamura, Nobuyuki

    2017-11-01

    We present extreme ultraviolet spectra of multiply charged tungsten ions observed with an electron beam ion trap. The observed spectra are compared with previous experimental results and theoretical spectra obtained with a collisional radiative model.

  5. Measurements of ocean wave spectra and modulation transfer function with the airborne two frequency scatterometer

    NASA Technical Reports Server (NTRS)

    Weissman, D. E.; Johnson, J. W.

    1984-01-01

    The directional spectrum and the microwave modulation transfer function of ocean waves can be measured with the airborne two frequency scatterometer technique. Similar to tower based observations, the aircraft measurements of the Modulation Transfer Function (MTF) show that it is strongly affected by both wind speed and sea state. Also detected are small differences in the magnitudes of the MTF between downwind and upwind radar look directions, and variations with ocean wavenumber. The MTF inferred from the two frequency radar is larger than that measured using single frequency, wave orbital velocity techniques such as tower based radars or ROWS measurements from low altitude aircraft. Possible reasons for this are discussed. The ability to measure the ocean directional spectrum with the two frequency scatterometer, with supporting MTF data, is demonstrated.

  6. Measurements of ocean wave spectra and modulation transfer function with the airborne two-frequency scatterometer

    NASA Technical Reports Server (NTRS)

    Weissman, D. E.; Johnson, J. W.

    1986-01-01

    The directional spectrum and the microwave modulation transfer function of ocean waves can be measured with the airborne two frequency scatterometer technique. Similar to tower based observations, the aircraft measurements of the Modulation Transfer Function (MTF) show that it is strongly affected by both wind speed and sea state. Also detected are small differences in the magnitudes of the MTF between downwind and upwind radar look directions, and variations with ocean wavenumber. The MTF inferred from the two frequency radar is larger than that measured using single frequency, wave orbital velocity techniques such as tower based radars or ROWS measurements from low altitude aircraft. Possible reasons for this are discussed. The ability to measure the ocean directional spectrum with the two frequency scatterometer, with supporting MTF data, is demonstrated.

  7. ALMACAL IV: A catalogue of ALMA calibrator continuum observations

    NASA Astrophysics Data System (ADS)

    Bonato, M.; Liuzzo, E.; Giannetti, A.; Massardi, M.; De Zotti, G.; Burkutean, S.; Galluzzi, V.; Negrello, M.; Baronchelli, I.; Brand, J.; Zwaan, M. A.; Rygl, K. L. J.; Marchili, N.; Klitsch, A.; Oteo, I.

    2018-05-01

    We present a catalogue of ALMA flux density measurements of 754 calibrators observed between August 2012 and September 2017, for a total of 16,263 observations in different bands and epochs. The flux densities were measured reprocessing the ALMA images generated in the framework of the ALMACAL project, with a new code developed by the Italian node of the European ALMA Regional Centre. A search in the online databases yielded redshift measurements for 589 sources (˜78 per cent of the total). Almost all sources are flat-spectrum, based on their low-frequency spectral index, and have properties consistent with being blazars of different types. To illustrate the properties of the sample we show the redshift and flux density distributions as well as the distributions of the number of observations of individual sources and of time spans in the source frame for sources observed in bands 3 (84-116 GHz) and 6 (211-275 GHz). As examples of the scientific investigations allowed by the catalogue we briefly discuss the variability properties of our sources in ALMA bands 3 and 6 and the frequency spectra between the effective frequencies of these bands. We find that the median variability index steadily increases with the source-frame time lag increasing from 100 to 800 days, and that the frequency spectra of BL Lacs are significantly flatter than those of flat-spectrum radio quasars. We also show the global spectral energy distributions of our sources over 17 orders of magnitude in frequency.

  8. Theoretical Model Images and Spectra for Comparison with HESSI and Microwave Observations of Solar Flares

    NASA Technical Reports Server (NTRS)

    Fisher, Richard R. (Technical Monitor); Holman, G. D.; Sui, L.; McTiernan, J. M.; Petrosian, V.

    2003-01-01

    We have computed bremsstrahlung and gyrosynchrotron images and spectra from a model flare loop. Electrons with a power-law energy distribution are continuously injected at the top of a semi-circular magnetic loop. The Fokker-Planck equation is integrated to obtain the steady-state electron distribution throughout the loop. Coulomb scattering and energy losses and magnetic mirroring are included in the model. The resulting electron distributions are used to compute the radiative emissions. Sample images and spectra are presented. We are developing these models for the interpretation of the High Energy Solar Spectroscopic Imager (HESSI) x-ray/gamma ray data and coordinated microwave observations. The Fokker-Planck and radiation codes are available on the Web at http://hesperia.gsfc.nasa.gov/hessi/modelware.htm This work is supported in part by the NASA Sun-Earth Connection Program.

  9. [The effect of electromagnetic waves of very high frequency of molecular spectra of radiation and absorption of nitric oxide on the functional activity of platelets].

    PubMed

    Kirichuk, V F; Maĭborodin, A V; Volin, M V; Krenitskiĭ, A P; Tupikin, V D

    2001-01-01

    A study was made of the effect of electromagnetic EMI MMD-fluctuation on the frequencies of molecular spectra of radiation, and nitric oxide absorption under in vitro conditions on the functional activity of platelets in patients with unstable angina pectoris, with the help of a specially created generator. At amplitude-modulated and continuous modes of EMI MMD-irradiation of platelet-rich plasma for 5, 15 and 30 min the platelet functional activity decreases, which was shown up in reduction of their activation and fall of aggregative ability. The degree, to which platelet functional activity was inhibited, depended on the mode of irradiation and on duration of EMI MMD effect. The most obvious changes in platelet activation and in their readiness to aggregative response were observed at a continuous mode of irradiation within a 15 min interval.

  10. Technologies for Low Frequency Radio Observations of the Cosmic Dawn

    NASA Technical Reports Server (NTRS)

    Jones, Dayton L.

    2014-01-01

    The Jet Propulsion Laboratory (JPL) is developing concepts and technologies for low frequency radio astronomy space missions aimed at observing highly redshifted neutral Hydrogen from the Dark Ages. This is the period of cosmic history between the recombination epoch when the microwave background radiation was produced and the re-ionization of the intergalactic medium by the first generation of stars (Cosmic Dawn). This period, at redshifts greater than about 20, is a critical epoch for the formation and evolution of large-scale structure in the universe. The 21-cm spectral line of Hydrogen provides the most promising method for directly studying the Dark Ages, but the corresponding frequencies at such large redshifts are only tens of MHz and thus require space-based observations to avoid terrestrial RFI and ionospheric absorption and refraction. This paper reports on the status of several low frequency technology development activities at JPL, including deployable bi-conical dipoles for a planned lunar-orbiting mission, and both rover-deployed and inflation-deployed long dipole antennas for use on the lunar surface.

  11. A comparison of field-line resonances observed at the Goose Bay and Wick radars

    NASA Astrophysics Data System (ADS)

    Provan, G.; Yeoman, T. K.

    1997-02-01

    Previous observations with the Goose Bay HF coherent-scatter radar have revealed structured spectral peaks at ultra-low frequencies. The frequencies of these spectral peaks have been demonstrated to be extremely consistent from day to day. The stability of these spectral peaks can be seen as evidence for the existence of global magnetospheric cavity modes whose resonant frequencies are independent of latitude. Field-line resonances occur when successive harmonics of the eigenfrequency of the magnetospheric cavity or waveguide match either the first harmonic eigenfrequency of the geomagnetic field lines or higher harmonics of this frequency. Power spectra observed at the SABRE VHF coherent-scatter radar at Wick, Scotland, during night and early morning are revealed to show similarly clearly structured spectral peaks. These spectral peaks are the result of local field-line resonances due to Alfvén waves standing on magnetospheric field lines. A comparison of the spectra observed by the Goose Bay and Wick radars demonstrate that the frequencies of the field-line resonances are, on average, almost identical, despite the different latitudinal ranges covered by the two radars. Possible explanations for the similarity of the signatures on the two radar systems are discussed.

  12. X-ray Spectra and Pulse Frequency Changes in SAX J2103.5+4545

    NASA Technical Reports Server (NTRS)

    Baykal, A.; Stark, M. J.; Swank, J. H.; White, Nicholas E. (Technical Monitor)

    2002-01-01

    The November 1999 outburst of the transient pulsar SAX J2103.5+4545 was monitored with the large area detectors of the Rossi X-Ray Timing Explorer until the pulsar faded after a year. The 358 s pulsar was spun up for 150 days, at which point the flux dropped quickly by a factor of approximately 7, the frequency saturated and, as the flux continued to decline, a weak spin-down began. The pulses remained strong during the decay and the spin-up/flux correlation can be fit to the Ghosh and Lamb derivations for the spin-up caused by accretion from a thin, pressure-dominated disk, for a distance approximately 3.2 kpc and a surface magnetic field approximately 1.2 x 10(exp 13) Gauss. During the bright spin-up part of the outburst, the flux was subject to strong orbital modulation, peaking approximately 3 days after periastron of the eccentric 12.68 day orbit, while during the faint part, there was little orbital modulation. The X-ray spectra were typical of accreting pulsars, describable by a cut-off power-law, with an emission line near the 6.4 keV of Kappa(sub alpha) fluorescence from cool iron. The equivalent width of this emission did not share the orbital modulation, but nearly doubled during the faint phase, despite little change in the column density. The outburst could have been caused by an episode of increased wind from a Be star, such that a small accretion disk is formed during each periastron passage. A change in the wind and disk structure apparently occurred after 5 months such that the accretion rate was no longer modulated or the diffusion time was longer. The distance estimate implies the X-ray luminosity observed was between 1 X 10(exp 36) ergs s(exp -1) and 6 x 10(exp 34) ergs s(exp -1), with a small but definite correlation of the intrinsic power-law spectral index.

  13. Characterization of the mutant spectra of a fish RNA virus within individual hosts during natural infections

    USGS Publications Warehouse

    Emmenegger, Eveline J.; Troyer, Ryan M.; Kurath, Gael

    2003-01-01

    Infectious hematopoietic necrosis virus (IHNV) is an RNA virus that causes significant mortalities of salmonids in the Pacific Northwest of North America. RNA virus populations typically contain genetic variants that form a heterogeneous virus pool, referred to as a quasispecies or mutant spectrum. This study characterized the mutant spectra of IHNV populations within individual fish reared in different environmental settings by RT–PCR of genomic viral RNA and determination of partial glycoprotein gene sequences of molecular clones. The diversity of the mutant spectra from ten in vivo populations was low and the average mutation frequencies of duplicate populations did not significantly exceed the background mutation level expected from the methodology. In contrast, two in vitro populations contained variants with an identical mutational hot spot. These results indicated that the mutant spectra of natural IHNV populations is very homogeneous, and does not explain the different magnitudes of genetic diversity observed between the different IHNV genogroups. Overall the mutant frequency of IHNV within its host is one of the lowest reported for RNA viruses.

  14. Hardware Demonstration: Frequency Spectra of Transients

    NASA Technical Reports Server (NTRS)

    McCloskey, John; Dimov, Jen

    2017-01-01

    Radiated emissions measurements as specified by MIL-STD-461 are performed in the frequency domain, which is best suited to continuous wave (CW) types of signals. However, many platforms implement signals that are single event pulses or transients. Such signals can potentially generate momentary radiated emissions that can cause interference in the system, but they may be missed with traditional measurement techniques. This demonstration provides measurement and analysis techniques that effectively evaluate the potential emissions from such signals in order to evaluate their potential impacts to system performance.

  15. Relationship between frequency power spectra and intermittent, large-amplitude bursts in the Alcator C-Mod scrape-off layer

    NASA Astrophysics Data System (ADS)

    Theodorsen, A.; Garcia, O. E.; Kube, R.; LaBombard, B.; Terry, J. L.

    2017-11-01

    Fluctuations in the boundary region of the Alcator C-Mod tokamak have been analyzed using gas puff imaging data from a set of Ohmically heated plasma density scan experiments. It is found that the relative fluctuation amplitudes are modest and close to normally distributed at the separatrix but become increasingly larger and skewed towards the main chamber wall. The frequency power spectra are nevertheless similar for all radial positions and line-averaged densities. Predictions of a stochastic model, describing the plasma fluctuations as a super-position of uncorrelated pulses, are shown to be in excellent agreement with the measurements. This implies that the pulse duration is the same, while the degree of pulse overlap decreases radially outwards in the scrape-off layer. The universal frequency power spectral density is thus determined by the shape and duration of the large-amplitude bursts associated with blob-like structures. The model also describes the rate of threshold level crossings, for which the exponential tails underline the intermittency of the fluctuations in the far scarpe-off layer.

  16. Similarity spectra analysis of high-performance jet aircraft noise.

    PubMed

    Neilsen, Tracianne B; Gee, Kent L; Wall, Alan T; James, Michael M

    2013-04-01

    Noise measured in the vicinity of an F-22A Raptor has been compared to similarity spectra found previously to represent mixing noise from large-scale and fine-scale turbulent structures in laboratory-scale jet plumes. Comparisons have been made for three engine conditions using ground-based sideline microphones, which covered a large angular aperture. Even though the nozzle geometry is complex and the jet is nonideally expanded, the similarity spectra do agree with large portions of the measured spectra. Toward the sideline, the fine-scale similarity spectrum is used, while the large-scale similarity spectrum provides a good fit to the area of maximum radiation. Combinations of the two similarity spectra are shown to match the data in between those regions. Surprisingly, a combination of the two is also shown to match the data at the farthest aft angle. However, at high frequencies the degree of congruity between the similarity and the measured spectra changes with engine condition and angle. At the higher engine conditions, there is a systematically shallower measured high-frequency slope, with the largest discrepancy occurring in the regions of maximum radiation.

  17. Study of hydrogen bond polarized IR spectra of cinnamic acid crystals

    NASA Astrophysics Data System (ADS)

    Flakus, Henryk T.; Jabłońska, Magdalena

    2004-11-01

    This paper presents the results of investigation of the polarized IR spectra of cinnamic acid and of its deuterium derivative crystals. The spectra were measured by a transmission method, using polarized light, at the room temperature and at 77 K, for two different crystalline faces. Theoretical analysis of the results concerned linear dichroic effects, H/D isotopic and temperature effects, observed in the spectra of the hydrogen and of the deuterium bonds in cinnamic acid crystals, at the frequency ranges of the νO-H and the νO-D bands. The basic crystal spectral properties could be satisfactorily interpreted in a quantitative way for a centrosymmetric cyclic hydrogen bond dimer model. Such a model explains not only a two-branch structure of the νO-H and νO-D bands in crystalline spectra, but also some essential linear dichroic effects in the band frequency ranges, measured for isotopically diluted crystals. Model calculations, performed within the limits of the 'strong-coupling' model, allowed for quantitative interpretation and for understanding of the basic properties of the hydrogen bond IR spectra of cinnamic acid crystals, H/D isotopic, temperature and dichroic effects included. In the scope of our studies the mechanism of H/D isotopic 'self-organization' processes, taking place in the crystal hydrogen bond lattices, was also recognized. It was proved that for isotopically diluted crystalline samples of cinnamic acid, a non-random distribution of protons and deuterons occurs exclusively in the hydrogen bond dimers. Nevertheless, these co-operative interactions between the hydrogen bonds do not involve the adjacent hydrogen bond dimers in each unit cell. The two-branch fine structure pattern of the νO-H and νO-D bands was ascribed to the vibronic mechanism of vibrational dipole selection rule breaking in centrosymmetric hydrogen bond dimers. The observed in the spectra very high intensity of the forbidden transition sub-band in the analyzed νO-H and

  18. Multi-angle Spectra Evolution of Langmuir Turbulence Excited by RF Ionospheric Interactions at HAARP

    NASA Astrophysics Data System (ADS)

    Sheerin, J. P.; Rayyan, N.; Watkins, B. J.; Bristow, W. A.; Spaleta, J.; Watanabe, N.; Golkowski, M.; Bernhardt, P. A.

    2013-12-01

    The high power HAARP HF transmitter is employed to generate and study strong Langmuir turbulence (SLT) in the interaction region of overdense ionospheric plasma. Diagnostics included the Modular UHF Ionospheric Radar (MUIR) sited at HAARP, the SuperDARN-Kodiak HF radar, and HF receivers to record stimulated electromagnetic emissions (SEE). Dependence of diagnostic signals on HAARP HF parameters, including pulselength, duty-cycle, aspect angle, and frequency were recorded. Short pulse, low duty cycle experiments demonstrate control of artificial field-aligned irregularities (AFAI) and isolation of ponderomotive effects. Among the effects observed and studied are: SLT spectra including cascade, collapse, and co-existence spectra and an outshifted plasma line under certain ionospheric conditions. High time resolution studies of the temporal evolution of the plasma line reveal the appearance of an overshoot effect on ponderomotive timescales. Bursty turbulence is observed in the collapse and cascade lines. For the first time, simultaneous multi-angle radar measurements of plasma line spectra are recorded demonstrating marked dependence on aspect angle with the strongest interaction region observed displaced southward of the HF zenith pointing angle. Numerous measurements of the outshifted plasma line are observed. Experimental results are compared to previous high latitude experiments and predictions from recent modeling efforts.

  19. Parity violation constraints using cosmic microwave background polarization spectra from 2006 and 2007 observations by the QUaD polarimeter.

    PubMed

    Wu, E Y S; Ade, P; Bock, J; Bowden, M; Brown, M L; Cahill, G; Castro, P G; Church, S; Culverhouse, T; Friedman, R B; Ganga, K; Gear, W K; Gupta, S; Hinderks, J; Kovac, J; Lange, A E; Leitch, E; Melhuish, S J; Memari, Y; Murphy, J A; Orlando, A; Piccirillo, L; Pryke, C; Rajguru, N; Rusholme, B; Schwarz, R; O'Sullivan, C; Taylor, A N; Thompson, K L; Turner, A H; Zemcov, M

    2009-04-24

    We constrain parity-violating interactions to the surface of last scattering using spectra from the QUaD experiment's second and third seasons of observations by searching for a possible systematic rotation of the polarization directions of cosmic microwave background photons. We measure the rotation angle due to such a possible "cosmological birefringence" to be 0.55 degrees +/-0.82 degrees (random) +/-0.5 degrees (systematic) using QUaD's 100 and 150 GHz temperature-curl and gradient-curl spectra over the spectra over the multipole range 200

  20. Identification of flexible structures by frequency-domain observability range context

    NASA Astrophysics Data System (ADS)

    Hopkins, M. A.

    2013-04-01

    The well known frequency-domain observability range space extraction (FORSE) algorithm provides a powerful multivariable system-identification tool with inherent flexibility, to create state-space models from frequency-response data (FRD). This paper presents a method of using FORSE to create "context models" of a lightly damped system, from which models of individual resonant modes can be extracted. Further, it shows how to combine the extracted models of many individual modes into one large state-space model. Using this method, the author has created very high-order state-space models that accurately match measured FRD over very broad bandwidths, i.e., resonant peaks spread across five orders-of-magnitude of frequency bandwidth.

  1. Van Allen Probes observations of unusually low frequency whistler mode waves observed in association with moderate magnetic storms: Statistical study.

    PubMed

    Cattell, C A; Breneman, A W; Thaller, S A; Wygant, J R; Kletzing, C A; Kurth, W S

    2015-09-28

    We show the first evidence for locally excited chorus at frequencies below 0.1  f ce (electron cyclotron frequency) in the outer radiation belt. A statistical study of chorus during geomagnetic storms observed by the Van Allen Probes found that frequencies are often dramatically lower than expected. The frequency at peak power suddenly stops tracking the equatorial 0.5  f ce and f / f ce decreases rapidly, often to frequencies well below 0.1  f ce (in situ and mapped to equator). These very low frequency waves are observed both when the satellites are close to the equatorial plane and at higher magnetic latitudes. Poynting flux is consistent with generation at the equator. Wave amplitudes can be up to 20 to 40 mV/m and 2 to 4 nT. We conclude that conditions during moderate to large storms can excite unusually low frequency chorus, which is resonant with more energetic electrons than typical chorus, with critical implications for understanding radiation belt evolution.

  2. FR II radio galaxies at low frequencies - I. Morphology, magnetic field strength and energetics.

    PubMed

    Harwood, Jeremy J; Croston, Judith H; Intema, Huib T; Stewart, Adam J; Ineson, Judith; Hardcastle, Martin J; Godfrey, Leith; Best, Philip; Brienza, Marisa; Heesen, Volker; Mahony, Elizabeth K; Morganti, Raffaella; Murgia, Matteo; Orrú, Emanuela; Röttgering, Huub; Shulevski, Aleksandar; Wise, Michael W

    2016-06-01

    Due to their steep spectra, low-frequency observations of Fanaroff-Riley type II (FR II) radio galaxies potentially provide key insights in to the morphology, energetics and spectrum of these powerful radio sources. However, limitations imposed by the previous generation of radio interferometers at metre wavelengths have meant that this region of parameter space remains largely unexplored. In this paper, the first in a series examining FR IIs at low frequencies, we use LOFAR (LOw Frequency ARray) observations between 50 and 160 MHz, along with complementary archival radio and X-ray data, to explore the properties of two FR II sources, 3C 452 and 3C 223. We find that the morphology of 3C 452 is that of a standard FR II rather than of a double-double radio galaxy as had previously been suggested, with no remnant emission being observed beyond the active lobes. We find that the low-frequency integrated spectra of both sources are much steeper than expected based on traditional assumptions and, using synchrotron/inverse-Compton model fitting, show that the total energy content of the lobes is greater than previous estimates by a factor of around 5 for 3C 452 and 2 for 3C 223. We go on to discuss possible causes of these steeper-than-expected spectra and provide revised estimates of the internal pressures and magnetic field strengths for the intrinsically steep case. We find that the ratio between the equipartition magnetic field strengths and those derived through synchrotron/inverse-Compton model fitting remains consistent with previous findings and show that the observed departure from equipartition may in some cases provide a solution to the spectral versus dynamical age disparity.

  3. Ion kinetic scale in the solar wind observed.

    PubMed

    Śafránková, Jana; Němeček, Zdeněk; Přech, Lubomír; Zastenker, Georgy N

    2013-01-11

    This Letter shows the first results from the solar wind monitor onboard the Spektr-R spacecraft which measures plasma moments with a time resolution of 31 ms. This high-time resolution allows us to make direct observations of solar wind turbulence below ion kinetic length scales. We present examples of the frequency spectra of the density, velocity, and thermal velocity. Our study reveals that although these parameters exhibit the same behavior at the magnetohydrodynamic scale, their spectra are remarkably different at the kinetic scale.

  4. Determination of thorium (IV) using isophthalaldehyde-tetrapyrrole as probe by resonance light scattering, second-order scattering and frequency-doubling scattering spectra

    NASA Astrophysics Data System (ADS)

    Wang, Jiao; Xue, Jinhua; Xiao, Xilin; Xu, Li; Jiang, Min; Peng, Pengcheng; Liao, Lifu

    2017-12-01

    The coordination reaction of thorium (IV) with a ditopic bidentate ligand to form supramolecular polymer was studied by resonance light scattering (RLS) spectra, second-order scattering (SOS) spectra and frequency-doubling scattering (FDS) spectra, respectively. The ditopic bidentate ligand is isophthalaldehyde-tetrapyrrole (IPTP). It was synthesized through a condensation reaction of isophthalaldehyde with pyrrole. The formation of supramolecular polymer results in remarkable intensity enhancements of the three light scattering signals. The maximum scattering wavelengths of RLS, FDS and SOS were 290, 568 and 340 nm, respectively. The reaction was used to establish new light scattering methods for the determination of thorium (IV) by using IPTP as probe. Under optimum conditions, the intensity enhancements of RLS, SOS and FDS were directly proportional to the concentration of thorium (IV) in the ranges of 0.01 to 1.2 μg mL- 1, 0.05 to 1.2 μg mL- 1 and 0.05 to 1.2 μg mL- 1, respectively. The detection limits were 0.003 μg mL- 1, 0.012 μg mL- 1 and 0.021 μg mL- 1, respectively. The methods were suitable for analyzing thorium (IV) in actual samples. The results show acceptable recoveries and precision compared with a reference method.

  5. On Theoretical Broadband Shock-Associated Noise Near-Field Cross-Spectra

    NASA Technical Reports Server (NTRS)

    Miller, Steven A. E.

    2015-01-01

    The cross-spectral acoustic analogy is used to predict auto-spectra and cross-spectra of broadband shock-associated noise in the near-field and far-field from a range of heated and unheated supersonic off-design jets. A single equivalent source model is proposed for the near-field, mid-field, and far-field terms, that contains flow-field statistics of the shock wave shear layer interactions. Flow-field statistics are modeled based upon experimental observation and computational fluid dynamics solutions. An axisymmetric assumption is used to reduce the model to a closed-form equation involving a double summation over the equivalent source at each shock wave shear layer interaction. Predictions are compared with a wide variety of measurements at numerous jet Mach numbers and temperature ratios from multiple facilities. Auto-spectral predictions of broadband shock-associated noise in the near-field and far-field capture trends observed in measurement and other prediction theories. Predictions of spatial coherence of broadband shock-associated noise accurately capture the peak coherent intensity, frequency, and spectral width.

  6. Spatial structure of directional wave spectra in hurricanes

    NASA Astrophysics Data System (ADS)

    Esquivel-Trava, Bernardo; Ocampo-Torres, Francisco J.; Osuna, Pedro

    2015-01-01

    The spatial structure of the wave field during hurricane conditions is studied using the National Data Buoy Center directional wave buoy data set from the Caribbean Sea and the Gulf of Mexico. The buoy information, comprising the directional wave spectra during the passage of several hurricanes, was referenced to the center of the hurricane using the path of the hurricane, the propagation velocity, and the radius of the maximum winds. The directional wave spectra were partitioned into their main components to quantify the energy corresponding to the observed wave systems and to distinguish between wind-sea and swell. The findings are consistent with those found using remote sensing data (e.g., Scanning Radar Altimeter data). Based on the previous work, the highest waves are found in the right forward quadrant of the hurricane, where the spectral shape tends to become uni-modal, in the vicinity of the region of maximum winds. More complex spectral shapes are observed in distant regions at the front of and in the rear quadrants of the hurricane, where there is a tendency of the spectra to become bi- and tri-modal. The dominant waves generally propagate at significant angles to the wind direction, except in the regions next to the maximum winds of the right quadrants. Evidence of waves generated by concentric eyewalls associated with secondary maximum winds was also found. The frequency spectra display some of the characteristics of the JONSWAP spectrum adjusted by Young (J Geophys Res 111:8020, 2006); however, at the spectral peak, the similarity with the Pierson-Moskowitz spectrum is clear. These results establish the basis for the use in assessing the ability of numerical models to simulate the wave field in hurricanes.

  7. Curved Radio Spectra of Weak Cluster Shocks

    NASA Astrophysics Data System (ADS)

    Kang, Hyesung; Ryu, Dongsu

    2015-08-01

    In order to understand certain observed features of arc-like giant radio relics such as the rareness, uniform surface brightness, and curved integrated spectra, we explore a diffusive shock acceleration (DSA) model for radio relics in which a spherical shock impinges on a magnetized cloud containing fossil relativistic electrons. Toward this end, we perform DSA simulations of spherical shocks with the parameters relevant for the Sausage radio relic in cluster CIZA J2242.8+5301, and calculate the ensuing radio synchrotron emission from re-accelerated electrons. Three types of fossil electron populations are considered: a delta-function like population with the shock injection momentum, a power-law distribution, and a power law with an exponential cutoff. The surface brightness profile of the radio-emitting postshock region and the volume-integrated radio spectrum are calculated and compared with observations. We find that the observed width of the Sausage relic can be explained reasonably well by shocks with speed {u}{{s}}˜ 3× {10}3 {km} {{{s}}}-1 and sonic Mach number {M}{{s}}˜ 3. These shocks produce curved radio spectra that steepen gradually over (0.1-10){ν }{br} with a break frequency {ν }{br}˜ 1 GHz if the duration of electron acceleration is ˜60-80 Myr. However, the abrupt increase in the spectral index above ˜1.5 GHz observed in the Sausage relic seems to indicate that additional physical processes, other than radiative losses, operate for electrons with {γ }{{e}}≳ {10}4.

  8. Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons - Effect of ionization

    NASA Technical Reports Server (NTRS)

    De Frees, D. J.; Miller, M. D.; Talbi, D.; Pauzat, F.; Ellinger, Y.

    1993-01-01

    In order to test the hypothesis of ionized PAHs as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.

  9. Ultraviolet Spectra of Subluminous Objects Found in the Kiso Schmidt Survey and Systematic Reanalysis of the Archived Ultraviolet Spectra of White Dwarfs Observed with the IUE Satellite Under the Astrophysics Data Program (ADP)

    NASA Technical Reports Server (NTRS)

    Wegner, Gary A.

    1988-01-01

    Recent research under NASA grant NAG5-971 consisted of the performance of two projects in conjunction with the International Ultraviolet Explorer (IUE) satellites. These are: (1) to look at the ultraviolet spectra of subluminous stars identified from visual wavelength spectroscopy that had been originally discovered from the Kiso Schmidt survey for ultraviolet excess stars and (2) to carry out a systematic reanalysis of the archived IUE spectra of white dwarfs. This report presents information on the progress of the re-reduction of over 600 IUE white dwarf spectra and their subsequent analysis employing model atmospheres and the observation of the Kiso ultraviolet excess stars.

  10. Origin of Non-Gaussian Spectra Observed via the Charge Exchange Recombination Spectroscopy Diagnostic in the DIII-D Tokamak

    NASA Astrophysics Data System (ADS)

    Sulyman, Alex; Chrystal, Colin; Haskey, Shaun; Burrell, Keith; Grierson, Brian

    2017-10-01

    The possible observation of non-Maxwellian ion distribution functions in the pedestal of DIII-D will be investigated with a synthetic diagnostic that accounts for the effect of finite neutral beam size. Ion distribution functions in tokamak plasmas are typically assumed to be Maxwellian, however non-Gaussian features observed in impurity charge exchange spectra have challenged this concept. Two possible explanations for these observations are spatial averaging over a finite beam size and a local ion distribution that is non-Maxwellian. Non-Maxwellian ion distribution functions could be driven by orbit loss effects in the edge of the plasma, and this has implications for momentum transport and intrinsic rotation. To investigate the potential effect of finite beam size on the observed spectra, a synthetic diagnostic has been created that uses FIDAsim to model beam and halo neutral density. Finite beam size effects are investigated for vertical and tangential views in the core and pedestal region with varying gradient scale lengths. Work supported in part by US DoE under the Science Undergraduate Laboratory Internship (SULI) program, DE-FC02-04ER54698, and DE-AC02-09CH11466.

  11. Studying the highly bent spectra of FR II-type radio galaxies with the KDA EXT model

    NASA Astrophysics Data System (ADS)

    Kuligowska, Elżbieta

    2018-04-01

    Context. The Kaiser, Dennett-Thorpe & Alexander (KDA, 1997, MNRAS, 292, 723) EXT model, that is, the extension of the KDA model of Fanaroff & Riley (FR) II-type source evolution, is applied and confronted with the observational data for selected FR II-type radio sources with significantly aged radio spectra. Aim. A sample of FR II-type radio galaxies with radio spectra strongly bent at their highest frequencies is used for testing the usefulness of the KDA EXT model. Methods: The dynamical evolution of FR II-type sources predicted with the KDA EXT model is briefly presented and discussed. The results are then compared to the ones obtained with the classical KDA approach, assuming the source's continuous injection and self-similarity. Results: The results and corresponding diagrams obtained for the eight sample sources indicate that the KDA EXT model predicts the observed radio spectra significantly better than the best spectral fit provided by the original KDA model.

  12. Technologies for low radio frequency observations of the Cosmic Dawn

    NASA Astrophysics Data System (ADS)

    Jones, D. L.

    2014-03-01

    The Jet Propulsion Laboratory (JPL) is developing concepts and technologies for low frequency radio astronomy space missions aimed at observing highly redshifted neutral Hydrogen from the Dark Ages. This is the period of cosmic history between the recombination epoch when the microwave background radiation was produced and the re-ionization of the intergalactic medium by the first generation of stars (Cosmic Dawn). This period, at redshifts z > ~20, is a critical epoch for the formation and evolution of large-scale structure in the universe. The 21-cm spectral line of Hydrogen provides the most promising method for directly studying the Dark Ages, but the corresponding frequencies at such large redshifts are only tens of MHz and thus require space-based observations to avoid terrestrial RFI and ionospheric absorption and refraction. This paper reports on the status of several low frequency technology development activities at JPL, including deployable bi-conical dipoles for a planned lunar-orbiting mission, and both rover-deployed and inflation-deployed long dipole antennas for use on the lunar surface. In addition, recent results from laboratory testing of low frequency receiver designs are presented. Finally, several concepts for space-based imaging interferometers utilizing deployable low frequency antennas are described. Some of these concepts involve large numbers of antennas and consequently a large digital cross-correlator will be needed. JPL has studied correlator architectures that greatly reduce the DC power required for this step, which can dominate the power consumption of real-time signal processing. Strengths and weaknesses of each mission concept are discussed in the context of the additional technology development required.

  13. Composition and energy spectra of low energy ions observed upstream of the earth's bow shock on ISEE-1

    NASA Technical Reports Server (NTRS)

    Ipavich, F. M.; Galvin, A. B.; Gloeckler, G.; Hovestadt, D.; Klecker, B.; Scholer, M.; Fan, C. Y.; Fisk, L. A.; Ogallagher, J. J.

    1980-01-01

    The characteristics of eleven locally accelerated particle events in the energy range from 30 to 125 keV/Q observed upstream of the earth's bow shock have been determined, including composition, energy spectra, and intensity versus time profiles. The measurements were made with the Ultra Low Energy Charge Analyzer sensor on ISEE-1. The composition in these events is similar to that of the solar wind, with a He to proton ratio of 8% and a CNO to He ratio of 6%. The composition is reasonably constant only when evaluated at equal energy per charge. The energy spectra cannot be adequately fit by a single power law in energy; an exponential or Maxwellian in energy per charge gives a satisfactory representation of the spectra. The time-intensity profiles of these upstream events show an inverse velocity dispersion, which may provide clues to the responsible acceleration mechanism.

  14. Noise power spectra of images from digital mammography detectors.

    PubMed

    Williams, M B; Mangiafico, P A; Simoni, P U

    1999-07-01

    Noise characterization through estimation of the noise power spectrum (NPS) is a central component of the evaluation of digital x-ray systems. We begin with a brief review of the fundamentals of NPS theory and measurement, derive explicit expressions for calculation of the one- and two-dimensional (1D and 2D) NPS, and discuss some of the considerations and tradeoffs when these concepts are applied to digital systems. Measurements of the NPS of two detectors for digital mammography are presented to illustrate some of the implications of the choices available. For both systems, two-dimensional noise power spectra obtained over a range of input fluence exhibit pronounced asymmetry between the orthogonal frequency dimensions. The 2D spectra of both systems also demonstrate dominant structures both on and off the primary frequency axes indicative of periodic noise components. Although the two systems share many common noise characteristics, there are significant differences, including markedly different dark-noise magnitudes, differences in NPS shape as a function of both spatial frequency and exposure, and differences in the natures of the residual fixed pattern noise following flat fielding corrections. For low x-ray exposures, quantum noise-limited operation may be possible only at low spatial frequency. Depending on the method of obtaining the 1D NPS (i.e., synthetic slit scanning or slice extraction from the 2D NPS), on-axis periodic structures can be misleadingly smoothed or missed entirely. Our measurements indicate that for these systems, 1D spectra useful for the purpose of detective quantum efficiency calculation may be obtained from thin cuts through the central portion of the calculated 2D NPS. On the other hand, low-frequency spectral values do not converge to an asymptotic value with increasing slit length when 1D spectra are generated using the scanned synthetic slit method. Aliasing can contribute significantly to the digital NPS, especially near the

  15. Instantaneous Frequency Analysis on Nonlinear EMIC Emissions: Arase Observation

    NASA Astrophysics Data System (ADS)

    Shoji, M.; Yoshizumi, M.; Omura, Y.; Kasaba, Y.; Ishisaka, K.; Matsuda, S.; Kasahara, Y.; Yagitani, S.; Matsuoka, A.; Teramoto, M.; Takashima, T.; Shinohara, I.

    2017-12-01

    In the inner magnetosphere, electromagnetic ion cyclotron (EMIC) waves cause nonlinear interactions with energetic protons. The waves drastically modify the proton distribution function, resulting in the particle loss in the radiation belt. Arase spacecraft, launched in late 2016, observed a nonlinear EMIC falling tone emission in the high magnetic latitude (MLAT) region of the inner magnetosphere. The wave growth with sub-packet structures of the falling tone emission is found by waveform data from PWE/EFD instrument. The evolution of the instantaneous frequency of the electric field of the EMIC falling tone emission is analyzed by Hilbert-Huang transform (HHT). We find several sub-packets with rising frequency in the falling tone wave. A self-consistent hybrid simulation suggested the complicate frequency evolution of the EMIC sub-packet emissions in the generation region. The intrinsic mode functions of Arase data derived from HHT are compared with the simulation data. The origin of the falling tone emission in the high MLAT region is also discussed.

  16. Observations of the Ultraviolet Spectra of Carbon White Dwarfs

    NASA Technical Reports Server (NTRS)

    Wagner, G. A.

    1982-01-01

    Strong ultraviolet carbon lines were detected in additional white DC (continuous visual spectra) dwarfs using the IUE. These lines are not seen in the ultraviolet spectrum of the cool DC star Stein 2051 B. The bright DA white dwarf LB 3303 has a strong unidentified absorption near lambda 1400.

  17. Quantitative analysis of Earth's field NMR spectra of strongly-coupled heteronuclear systems.

    PubMed

    Halse, Meghan E; Callaghan, Paul T; Feland, Brett C; Wasylishen, Roderick E

    2009-09-01

    In the Earth's magnetic field, it is possible to observe spin systems consisting of unlike spins that exhibit strongly coupled second-order NMR spectra. Such spectra result when the J-coupling between two unlike spins is of the same order of magnitude as the difference in their Larmor precession frequencies. Although the analysis of second-order spectra involving only spin-(1/2) nuclei has been discussed since the early days of NMR spectroscopy, NMR spectra involving spin-(1/2) nuclei and quadrupolar (I>(1/2)) nuclei have rarely been treated. Two examples are presented here, the tetrahydroborate anion, BH4-, and the ammonium cation, NH4+. For the tetrahydroborate anion, (1)J((11)B,(1)H)=80.9Hz, and in an Earth's field of 53.3microT, nu((1)H)=2269Hz and nu((11)B)=728Hz. The (1)H NMR spectra exhibit features that both first- and second-order perturbation theory are unable to reproduce. On the other hand, second-order perturbation theory adequately describes (1)H NMR spectra of the ammonium anion, (14)NH4+, where (1)J((14)N,(1)H)=52.75Hz when nu((1)H)=2269Hz and nu((14)N)=164Hz. Contrary to an early report, we find that the (1)H NMR spectra are independent of the sign of (1)J((14)N,(1)H). Exact analysis of two-spin systems consisting of quadrupolar nuclei and spin-(1/2) nuclei are also discussed.

  18. Circadian variation of EEG power spectra in NREM and REM sleep in humans: dissociation from body temperature

    NASA Technical Reports Server (NTRS)

    Dijk, D. J.

    1999-01-01

    In humans, EEG power spectra in REM and NREM sleep, as well as characteristics of sleep spindles such as their duration, amplitude, frequency and incidence, vary with circadian phase. Recently it has been hypothesized that circadian variations in EEG spectra in humans are caused by variations in brain or body temperature and may not represent phenomena relevant to sleep regulatory processes. To test this directly, a further analysis of EEG power spectra - collected in a forced desynchrony protocol in which sleep episodes were scheduled to a 28-h period while the rhythms of body temperature and plasma melatonin were oscillating at their near 24-h period - was carried out. EEG power spectra were computed for NREM and REM sleep occurring between 90-120 and 270-300 degrees of the circadian melatonin rhythm, i.e. just after the clearance of melatonin from plasma in the 'morning' and just after the 'evening' increase in melatonin secretion. Average body temperatures during scheduled sleep at these two circadian phases were identical (36.72 degrees C). Despite identical body temperatures, the power spectra in NREM sleep were very different at these two circadian phases. EEG activity in the low frequency spindle range was significantly and markedly enhanced after the evening increase in plasma melatonin as compared to the morning phase. For REM sleep, significant differences in power spectra during these two circadian phases, in particular in the alpha range, were also observed. The results confirm that EEG power spectra in NREM and REM sleep vary with circadian phase, suggesting that the direct contribution of temperature to the circadian variation in EEG power spectra is absent or only minor, and are at variance with the hypothesis that circadian variations in EEG power spectra are caused by variations in temperature.

  19. High-frequency Oscillations in the Atmosphere above a Sunspot Umbra

    NASA Astrophysics Data System (ADS)

    Wang, Feng; Deng, Hui; Li, Bo; Feng, Song; Bai, Xianyong; Deng, Linhua; Yang, Yunfei; Xue, Zhike; Wang, Rui

    2018-03-01

    We use high spatial and temporal resolution observations, simultaneously obtained with the New Vacuum Solar Telescope and Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory, to investigate the high-frequency oscillations above a sunspot umbra. A novel time–frequency analysis method, namely, the synchrosqueezing transform (SST), is employed to represent their power spectra and to reconstruct the high-frequency signals at different solar atmospheric layers. A validation study with synthetic signals demonstrates that SST is capable of resolving weak signals even when their strength is comparable to the high-frequency noise. The power spectra, obtained from both SST and the Fourier transform, of the entire umbral region indicate that there are significant enhancements between 10 and 14 mHz (labeled as 12 mHz) at different atmospheric layers. Analyzing the spectrum of a photospheric region far away from the umbra demonstrates that this 12 mHz component exists only inside the umbra. The animation based on the reconstructed 12 mHz component in AIA 171 Å illustrates that an intermittently propagating wave first emerges near the footpoints of coronal fan structures, and then propagates outward along the structures. A time–distance diagram, coupled with a subsonic wave speed (∼49 km s‑1), highlights the fact that these coronal perturbations are best described as upwardly propagating magnetoacoustic slow waves. Thus, we first reveal the high-frequency oscillations with a period around one minute in imaging observations at different height above an umbra, and these oscillations seem to be related to the umbral perturbations in the photosphere.

  20. Strong coupling effects in the polarized IR spectra of the chain hydrogen bond systems in imidazole crystals: H/D isotopic ?self-organization? effects in the IR spectra of isotopically diluted imidazole single crystals

    NASA Astrophysics Data System (ADS)

    Flakus, Henryk T.; Michta, Anna

    2004-11-01

    This paper presents the investigation results of the polarized IR spectra of H1245 imidazole crystals and of D1H245, D1245 and H1D245 imidazole deuterium derivative crystals. The spectra were measured using polarized light at the room temperature and at 77 K by a transmission method, for two different crystalline faces. Theoretical analysis of the results concerned linear dichroic effects, H/D isotopic and temperature effects, observed in the spectra of the hydrogen and of the deuterium bonds in imidazole crystals, at the frequency ranges of νN-H and νN-D bands. The basic crystal spectral properties can be satisfactorily interpreted in a quantitative way for a hydrogen bond linear dimer model. Such a model explains not only a two-branch structure of the νN-H and νN-D bands in crystalline spectra, but also some essential linear dichroic effects in the band frequency ranges, for isotopically diluted crystals. Model calculations, performed within the limits of the strong-coupling model, allowed for quantitative interpretation and for understanding of the basic properties of the hydrogen bond IR spectra of imidazole crystals, H/D isotopic, temperature and dichroic effects included. The results allowed verification of theoretical models proposed recently for the imidazole crystal spectra generation mechanisms. In the scope of our studies, the mechanism of H/D isotopic self-organization processes, taking place in the crystal hydrogen bond lattices, was also recognized. It was proved that for isotopically diluted crystalline samples of imidazole, a non-random distribution of protons and deuterons exclusively occurs in some restricted fragments (domains) of open chains of the hydrogen-bonded molecules. Nevertheless, these co-operative interactions between the hydrogen bonds do not concern adjacent fragments of neighboring hydrogen bond chains in the lattice. Analysis of the isotopic self-organization effects in the spectra of imidazole crystals delivered crucial

  1. A study of polarized spectra of magnetic CP stars: Predicted š. observed Stokes IQUV profiles for beta CrB and 53 Cam

    NASA Astrophysics Data System (ADS)

    Bagnulo, S.; Wade, G. A.; Donati, J.-F.; Landstreet, J. D.; Leone, F.; Monin, D. N.; Stift, M. J.

    2001-04-01

    We present a comparison of observed and calculated Stokes IQUV spectra of two well-known magnetic chemically peculiar stars, beta Coronae Borealis and 53 Camelopardalis. The observed Stokes spectra were recently described by Wade et al. (\\cite{wad00a}), and have been complemented with additional circularly polarized spectra obtained at the Special Astrophysical Observatory. The calculated spectra represent the predictions of new and previously published magnetic field models derived from the analysis of some surface averaged field estimates (e.g., longitudinal field, magnetic field modulus, etc.). We find that these magnetic models are not sufficient to account fully for the observed Stokes profiles - particularly remarkable is the disagreement between the predicted and observed Stokes Q and U profiles of 53 Cam. We suggest that this should be interpreted in terms of magnetic morphologies which are significantly more complex than the second-order multipolar expansions assumed in the models. However, it is clear that some of our inability to reproduce the detailed shapes of the Stokes IQUV profiles is unrelated to the magnetic models. For many metallic ions, for both stars, we found it impossible to account for the strengths and shapes of the observed spectral line profiles when we adopted a unique value for the individual ion abundance. We suggest that this results from strongly non-uniform distributions of these ions as a function of optical depth (i.e., chemical stratification), a hypothesis that is supported by comparison with simple chemically stratified models. Based on observations obtained with the 2 m Bernard Lyot telescope of the Pic-du-Midi Observatory, the 1 m telescope of the Special Astrophysical Observatory, and the 0.9 m telescope of the Osservatorio Astrofisico di Catania.

  2. FT-IR, FT-Raman spectra, density functional computations of the vibrational spectra and molecular conformational analysis of 2,5-di-tert-butyl-hydroquinone

    NASA Astrophysics Data System (ADS)

    Subramanian, N.; Sundaraganesan, N.; Dereli, Ö.; Türkkan, E.

    2011-12-01

    The purpose of finding conformer among six different possible conformers of 2,5-di-tert-butyl-hydroquinone (DTBHQ), its equilibrium geometry and harmonic wavenumbers were calculated by the B3LYP/6-31G(d,p) method. The infrared and Raman spectra of DTBHQ were recorded in the region 400-4000 cm -1 and 50-3500 cm -1, respectively. In addition, the IR spectra in CCl 4 at various concentrations of DTBHQ are also recorded. The computed vibrational wavenumbers were compared with the IR and Raman experimental data. Computational calculations at B3LYP level with two different basis sets 6-31G(d,p) and 6-311++G(d,p) are also employed in the study of the possible conformer of DTBHQ. The complete assignments were performed on the basis of the potential energy distribution (PED) of the vibrational modes, calculated using VEDA 4 program. The general agreement between the observed and calculated frequencies was established.

  3. Temperature dependence of Brillouin light scattering spectra of acoustic phonons in silicon

    NASA Astrophysics Data System (ADS)

    Olsson, Kevin S.; Klimovich, Nikita; An, Kyongmo; Sullivan, Sean; Weathers, Annie; Shi, Li; Li, Xiaoqin

    2015-02-01

    Electrons, optical phonons, and acoustic phonons are often driven out of local equilibrium in electronic devices or during laser-material interaction processes. The need for a better understanding of such non-equilibrium transport processes has motivated the development of Raman spectroscopy as a local temperature sensor of optical phonons and intermediate frequency acoustic phonons, whereas Brillouin light scattering (BLS) has recently been explored as a temperature sensor of low-frequency acoustic phonons. Here, we report the measured BLS spectra of silicon at different temperatures. The origins of the observed temperature dependence of the BLS peak position, linewidth, and intensity are examined in order to evaluate their potential use as temperature sensors for acoustic phonons.

  4. Temperature dependence of Brillouin light scattering spectra of acoustic phonons in silicon

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Olsson, Kevin S.; Klimovich, Nikita; An, Kyongmo

    2015-02-02

    Electrons, optical phonons, and acoustic phonons are often driven out of local equilibrium in electronic devices or during laser-material interaction processes. The need for a better understanding of such non-equilibrium transport processes has motivated the development of Raman spectroscopy as a local temperature sensor of optical phonons and intermediate frequency acoustic phonons, whereas Brillouin light scattering (BLS) has recently been explored as a temperature sensor of low-frequency acoustic phonons. Here, we report the measured BLS spectra of silicon at different temperatures. The origins of the observed temperature dependence of the BLS peak position, linewidth, and intensity are examined in ordermore » to evaluate their potential use as temperature sensors for acoustic phonons.« less

  5. New Observations of Soft X-ray (0.5-5 keV) Solar Spectra

    NASA Astrophysics Data System (ADS)

    Caspi, A.; Woods, T. N.; Mason, J. P.; Jones, A. R.; Warren, H. P.

    2013-12-01

    The solar corona is the brightest source of X-rays in the solar system, and the X-ray emission is highly variable on many time scales. However, the actual solar soft X-ray (SXR) (0.5-5 keV) spectrum is not well known, particularly during solar quiet periods, as, with few exceptions, this energy range has not been systematically studied in many years. Previous observations include high-resolution but very narrow-band spectra from crystal spectrometers (e.g., Yohkoh/BCS), or integrated broadband irradiances from photometers (e.g., GOES/XRS, TIMED/XPS, etc.) that lack detailed spectral information. In recent years, broadband measurements with moderate energy resolution (~0.5-0.7 keV FWHM) were made by SphinX on CORONAS-Photon and SAX on MESSENGER, although they did not extend to energies below ~1 keV. We present observations of solar SXR emission obtained using new instrumentation flown on recent SDO/EVE calibration rocket underflights. The photon-counting spectrometer, a commercial Amptek X123 with a silicon drift detector and an 8 μm Be window, measures the solar disk-integrated SXR emission from ~0.5 to >10 keV with ~0.15 keV FWHM resolution and 1 s cadence. A novel imager, a pinhole X-ray camera using a cooled frame-transfer CCD (15 μm pixel pitch), Ti/Al/C filter, and 5000 line/mm Au transmission grating, images the full Sun in multiple spectral orders from ~0.1 to ~5 nm with ~10 arcsec/pixel and ~0.01 nm/pixel spatial and spectral detector scales, respectively, and 10 s cadence. These instruments are prototypes for future CubeSat missions currently being developed. We present new results of solar observations on 04 October 2013 (NASA sounding rocket 36.290). We compare with previous results from 23 June 2012 (NASA sounding rocket 36.286), during which solar activity was low and no signal was observed above ~4 keV. We compare our spectral and imaging measurements with spectra and broadband irradiances from other instruments, including SDO/EVE, GOES/XRS, TIMED

  6. Studies of radio frequency interference at Parkes Observatory

    NASA Astrophysics Data System (ADS)

    Backus, Peter R.; Laroque, Sam; Tarter, Jill C.; Dreher, John; Gullers, Kent; Patrick, Alan; Heiligman, Gary

    1997-01-01

    From February through early June 1995, Project Phoenix conducted SETI observations of 209 stars over the frequency range from 1195 to 3005 MHz. A byproduct of this search is a unique data set suitable for studying the Radio Frequency Interference (RFI) environment at the Parkes 64-m telescope in New South Wales, Australia. RFI is an increasing problem for SETI and other radio astronomy observations conducted outside of the 'protected' frequency bands. The data analyzed for this paper were 'mean baseline' spectra in Left and Right Circular Polarization (LCP, RCP), integrated for either 138 or 276 s, covering a 10-MHz bandwidth with 15,552 channels at a resolution of 643 Hz. Channels were identified as contaminated by RFI when the power in the channel exceeded the mean noise by 3 percent. The 'spectral occupancy', the fraction of time RFI was seen, was determined for each channel. The RFI occupancy for LCP and RCP are distinctly different. Approximately 100 MHz of the spectrum was too heavily contaminated for SETI observations.

  7. FT-IR, FT-Raman spectra and DFT calculations of melaminium perchlorate monohydrate.

    PubMed

    Kanagathara, N; Marchewka, M K; Drozd, M; Renganathan, N G; Gunasekaran, S; Anbalagan, G

    2013-08-01

    Melaminium perchlorate monohydrate (MPM), an organic material has been synthesized by slow solvent evaporation method at room temperature. Powder X-ray diffraction analysis confirms that MPM crystal belongs to triclinic system with space group P-1. FTIR and FT Raman spectra are recorded at room temperature. Functional group assignment has been made for the melaminium cations and perchlorate anions. Vibrational spectra have also been discussed on the basis of quantum chemical density functional theory (DFT) calculations using Firefly (PC GAMESS) version 7.1 G. Vibrational frequencies are calculated and scaled values are compared with experimental values. The assignment of the bands has been made on the basis of the calculated PED. The Mulliken charges, HOMO-LUMO orbital energies are analyzed directly from Firefly program log files and graphically illustrated. HOMO-LUMO energy gap and other related molecular properties are also calculated. The theoretically constructed FT-IR and FT-Raman spectra of MPM coincide with the experimental one. The chemical structure of the compound has been established by (1)H and (13)C NMR spectra. No detectable signal was observed during powder test for second harmonic generation. Copyright © 2013 Elsevier B.V. All rights reserved.

  8. FT-IR, FT-Raman spectra and DFT calculations of melaminium perchlorate monohydrate

    NASA Astrophysics Data System (ADS)

    Kanagathara, N.; Marchewka, M. K.; Drozd, M.; Renganathan, N. G.; Gunasekaran, S.; Anbalagan, G.

    2013-08-01

    Melaminium perchlorate monohydrate (MPM), an organic material has been synthesized by slow solvent evaporation method at room temperature. Powder X-ray diffraction analysis confirms that MPM crystal belongs to triclinic system with space group P-1. FTIR and FT Raman spectra are recorded at room temperature. Functional group assignment has been made for the melaminium cations and perchlorate anions. Vibrational spectra have also been discussed on the basis of quantum chemical density functional theory (DFT) calculations using Firefly (PC GAMESS) version 7.1 G. Vibrational frequencies are calculated and scaled values are compared with experimental values. The assignment of the bands has been made on the basis of the calculated PED. The Mulliken charges, HOMO-LUMO orbital energies are analyzed directly from Firefly program log files and graphically illustrated. HOMO-LUMO energy gap and other related molecular properties are also calculated. The theoretically constructed FT-IR and FT-Raman spectra of MPM coincide with the experimental one. The chemical structure of the compound has been established by 1H and 13C NMR spectra. No detectable signal was observed during powder test for second harmonic generation.

  9. High frequency signal acquisition using a smartphone in an undergraduate teaching laboratory: Applications in ultrasonic resonance spectra.

    PubMed

    Sturtevant, Blake T; Pantea, Cristian; Sinha, Dipen N

    2016-10-01

    A simple and inexpensive approach to acquiring signals in the megahertz frequency range using a smartphone is described. The approach is general, applicable to electromagnetic as well as acoustic measurements, and makes available to undergraduate teaching laboratories experiments that are traditionally inaccessible due to the expensive equipment that are required. This paper focuses on megahertz range ultrasonic resonance spectra in liquids and solids, although there is virtually no upper limit on frequencies measurable using this technique. Acoustic resonance measurements in water and Fluorinert in a one dimensional (1D) resonant cavity were conducted and used to calculate sound speed. The technique is shown to have a precision and accuracy significantly better than one percent in liquid sound speed. Measurements of 3D resonances in an isotropic solid sphere were also made and used to determine the bulk and shear moduli of the sample. The elastic moduli determined from the solid resonance measurements agreed with those determined using a research grade vector network analyzer to better than 0.5%. The apparatus and measurement technique described can thus make research grade measurements using standardly available laboratory equipment for a cost that is two-to-three orders of magnitude less than the traditional measurement equipment used for these measurements.

  10. Observations of vertical velocities in the tropical upper troposphere and lower stratosphere using the Arecibo 430-MHz radar

    NASA Technical Reports Server (NTRS)

    Cornish, C. R.

    1988-01-01

    The first clear-air observations of vertical velocities in the tropical upper troposphere and lower stratosphere (8-22 km) using the Arecibo 430-MHz radar are presented. Oscillations in the vertical velocity near the Brunt-Vaisala period are observed in the lower stratosphere during the 12-hour observation period. Frequency power spectra from the vertical velocity time series show a slope between -0.5 and -1.0. Vertical wave number spectra computed from the height profiles of vertical velocities have slopes between -1.0 and -1.5. These observed slopes do not agree well with the slopes of +1/3 and -2.5 for frequency and vertical wave number spectra, respectively, predicted by a universal gravity-wave spectrum model. The spectral power of wave number spectra of a radial beam directed 15 deg off-zenith is enhanced by an order of magnitude over the spectral power levels of the vertical beam. This enhancement suggests that other geophysical processes besides gravity waves are present in the horizontal flow. The steepening of the wave number spectrum of the off-vertical beam in the lower stratosphere to near -2.0 is attributed to a quasi-inertial period wave, which was present in the horizontal flow during the observation period.

  11. Millimeter and submillimeter wave spectra of 13C methylamine

    NASA Astrophysics Data System (ADS)

    Motiyenko, R. A.; Margulès, L.; Ilyushin, V. V.; Smirnov, I. A.; Alekseev, E. A.; Halfen, D. T.; Ziurys, L. M.

    2016-03-01

    Context. Methylamine (CH3NH2) is a light molecule of astrophysical interest, which has an intensive rotational spectrum that extends in the submillimeter wave range and far beyond, even at temperatures characteristic for the interstellar medium. It is likely for 13C isotopologue of methylamine to be identified in astronomical surveys, but there is no information available for the 13CH3NH2 millimeter and submillimeter wave spectra. Aims: In this context, to provide reliable predictions of 13CH3NH2 spectrum in millimeter and submillimeter wave ranges, we have studied rotational spectra of the 13C methylamine isotopologue in the frequency range from 48 to 945 GHz. Methods: The spectrum of 13C methylamine was recorded using conventional absorption spectrometers. The analysis of the rotational spectrum of 13C methylamine in the ground vibrational state was performed on the basis of the group-theoretical high-barrier tunneling Hamiltonian that was developed for methylamine. The available multiple observations of the parent methylamine species toward Sgr B2(N) at 1, 2, and 3 mm using the Submillimeter Telescope and the 12 m antenna of the Arizona Radio Observatory were used to make a search for interstellar 13CH3NH2. Results: In the recorded spectra, we have assigned 2721 rotational transitions that belong to the ground vibrational state of the 13CH3NH2. These measurements were fitted to the Hamiltonian model that uses 75 parameters to achieve an overall weighted rms deviation of 0.73. On the basis of these spectroscopic results, predictions of transition frequencies in the frequency range up to 950 GHz with J ≤ 50 and Ka ≤ 20 are presented. The search for interstellar 13C methylamine in available observational data was not successful and therefore only an upper limit of 6.5 × 1014 cm-2 can be derived for the column density of 13CH3NH2 toward Sgr B2(N), assuming the same source size, temperature, linewidth, and systemic velocity as for parent methylamine isotopic

  12. Angular spectra of the intrinsic galaxy ellipticity field, their observability and their impact on lensing in tomographic surveys

    NASA Astrophysics Data System (ADS)

    Schäfer, Björn Malte; Merkel, Philipp M.

    2017-09-01

    This paper describes intrinsic ellipticity correlations between galaxies, their statistical properties, their observability with future surveys and their interference with weak gravitational lensing measurements. Using an angular-momentum-based, quadratic intrinsic alignment model we derive correlation functions of the ellipticity components and project them to yield the four non-zero angular ellipticity spectra C^ɛ _E(ℓ), C^ɛ _B(ℓ), C^ɛ _C(ℓ) and C^ɛ _S(ℓ) in their generalization to tomographic surveys. For a Euclid-like survey, these spectra would have amplitudes smaller than the weak lensing effect on non-linear structures, but would constitute an important systematics. Computing estimation biases for cosmological parameters derived from an alignment-contaminated survey suggests biases of +5σw for the dark energy equation of state parameter w, -20σ _{Ω _m} for the matter density Ωm and -12σ _{σ _8} for the spectrum normalization σ8. Intrinsic alignments yield a signal that is easily observable with a survey similar to Euclid: while not independent, significances for estimates of each of the four spectra reach values of tens of σ if weak lensing and shape noise are considered as noise sources, which suggests relative uncertainties on alignment parameters at the percent level, implying that galaxy alignment mechanisms can be investigated by future surveys.

  13. Dual-frequency sound-absorbing metasurface based on visco-thermal effects with frequency dependence

    NASA Astrophysics Data System (ADS)

    Ryoo, H.; Jeon, W.

    2018-03-01

    We investigate theoretically an acoustic metasurface with a high absorption coefficient at two frequencies and design it from subwavelength structures. We propose the use of a two-dimensional periodic array of four Helmholtz resonators in two types to obtain a metasurface with nearly perfect sound absorption at given target frequencies via interactions between waves emanating from different resonators. By considering how fluid viscosity affects acoustic energy dissipation in the narrow necks of the Helmholtz resonators, we obtain effective complex-valued material properties that depend on frequency and on the geometrical parameters of the resonators. We furthermore derive the effective acoustic impedance of the metasurface from the effective material properties and calculate the absorption spectra from the theoretical model, which we compare with the spectra obtained from a finite-element simulation. As a practical application of the theoretical model, we derive empirical formulas for the geometrical parameters of a metasurface which would yield perfect absorption at a given frequency. While previous works on metasurfaces based on Helmholtz resonators aimed to absorb sound at single frequencies, we use optimization to design a metasurface composed of four different Helmholtz resonators to absorb sound at two distinct frequencies.

  14. Spectra from pair-equilibrium plasmas

    NASA Technical Reports Server (NTRS)

    Zdziarski, A. A.

    1984-01-01

    A numerical model of relativistic nonmagnetized plasma with uniform temperature and electron density distributions is considered, and spectra from plasma in pair equilibrium are studied. A range of dimensionless temperature (T) greater than about 0.2 is considered. The spectra from low pair density plasmas in pair equilibrium vary from un-Comptonized bremsstrahlung spectra at Thomson cross section tau(N) much less than one to Comptonized bremsstrahlung spectra with tau(N) over one. For high pair density plasmas the spectra are flat for T greater than about one, and have broad intensity peaks at energy roughly equal to 3T for T less than one. In the latter region the total luminosity is approximately twice the annihilation luminosity. All spectra are flat in the X-ray region, in contradiction to observed AGN spectra. For dimensionless luminosity greater than about 100, the cooling time becomes shorter than the Thomson time.

  15. Analysis of high-frequency energy in long-term average spectra of singing, speech, and voiceless fricatives.

    PubMed

    Monson, Brian B; Lotto, Andrew J; Story, Brad H

    2012-09-01

    The human singing and speech spectrum includes energy above 5 kHz. To begin an in-depth exploration of this high-frequency energy (HFE), a database of anechoic high-fidelity recordings of singers and talkers was created and analyzed. Third-octave band analysis from the long-term average spectra showed that production level (soft vs normal vs loud), production mode (singing vs speech), and phoneme (for voiceless fricatives) all significantly affected HFE characteristics. Specifically, increased production level caused an increase in absolute HFE level, but a decrease in relative HFE level. Singing exhibited higher levels of HFE than speech in the soft and normal conditions, but not in the loud condition. Third-octave band levels distinguished phoneme class of voiceless fricatives. Female HFE levels were significantly greater than male levels only above 11 kHz. This information is pertinent to various areas of acoustics, including vocal tract modeling, voice synthesis, augmentative hearing technology (hearing aids and cochlear implants), and training/therapy for singing and speech.

  16. Toward ab initio molecular dynamics modeling for sum-frequency generation spectra; an efficient algorithm based on surface-specific velocity-velocity correlation function.

    PubMed

    Ohto, Tatsuhiko; Usui, Kota; Hasegawa, Taisuke; Bonn, Mischa; Nagata, Yuki

    2015-09-28

    Interfacial water structures have been studied intensively by probing the O-H stretch mode of water molecules using sum-frequency generation (SFG) spectroscopy. This surface-specific technique is finding increasingly widespread use, and accordingly, computational approaches to calculate SFG spectra using molecular dynamics (MD) trajectories of interfacial water molecules have been developed and employed to correlate specific spectral signatures with distinct interfacial water structures. Such simulations typically require relatively long (several nanoseconds) MD trajectories to allow reliable calculation of the SFG response functions through the dipole moment-polarizability time correlation function. These long trajectories limit the use of computationally expensive MD techniques such as ab initio MD and centroid MD simulations. Here, we present an efficient algorithm determining the SFG response from the surface-specific velocity-velocity correlation function (ssVVCF). This ssVVCF formalism allows us to calculate SFG spectra using a MD trajectory of only ∼100 ps, resulting in the substantial reduction of the computational costs, by almost an order of magnitude. We demonstrate that the O-H stretch SFG spectra at the water-air interface calculated by using the ssVVCF formalism well reproduce those calculated by using the dipole moment-polarizability time correlation function. Furthermore, we applied this ssVVCF technique for computing the SFG spectra from the ab initio MD trajectories with various density functionals. We report that the SFG responses computed from both ab initio MD simulations and MD simulations with an ab initio based force field model do not show a positive feature in its imaginary component at 3100 cm(-1).

  17. [Influence of electromagnetic emission at the frequencies of molecular absorption and emission spectra of oxygen and nitrogen oxide on the adhesion and formation of Pseudomonas aeruginosa biofilm].

    PubMed

    Pronina, E A; Shvidenko, I G; Shub, G M; Shapoval, O G

    2011-01-01

    Evaluate the influence of electromagnetic emission (EME) at the frequencies of molecular absorption and emission spectra of atmospheric oxygen and nitrogen oxide (MAES 02 and MAES NO respectively) on the adhesion, population progress and biofilm formation of Pseudomonas aeruginosa. Adhesive activity was evaluated by mean adhesion index (MAI) of bacteria on human erythrocytes. Population growth dynamic was assessed by optical density index of broth cultures; biofilm formation--by values of optical density of the cells attached to the surface of polystyrol wells. P.aeruginosa bacteria had high adhesive properties that have increased under the influence of MAES 02 frequency emission and have not changed under the influence of MAES NO frequency. Exposure of bacteria to MAES NO frequency did not influence the population progress; exposure to MAES 02 frequency stimulated the biofilm formation ability of the bacteria, and MAES NO--decreased this ability. EME at MAES NO frequency can be used to suppress bacterial biofilm formation by pseudomonas.

  18. Spectropolarimetric Observations of Solar Noise Storms at Low Frequencies

    NASA Astrophysics Data System (ADS)

    Mugundhan, V.; Ramesh, R.; Kathiravan, C.; Gireesh, G. V. S.; Hegde, Aathira

    2018-03-01

    A new high-resolution radio spectropolarimeter instrument operating in the frequency range of 15 - 85 MHz has recently been commissioned at the Radio Astronomy Field Station of the Indian Institute of Astrophysics at Gauribidanur, 100 km north of Bangalore, India. We describe the design and construction of this instrument. We present observations of a solar radio noise storm associated with Active Region (AR) 12567 in the frequency range of {≈} 15 - 85 MHz during 18 and 19 July 2016, observed using this instrument in the meridian-transit mode. This is the first report that we are aware of in which both the burst and continuum properties are derived simultaneously. Spectral indices and degree of polarization of both the continuum radiation and bursts are estimated. It is found that i) Type I storm bursts have a spectral index of {≈} {+}3.5, ii) the spectral index of the background continuum is ≈+2.9, iii) the transition frequency between Type I and Type III storms occurs at ≈55 MHz, iv) Type III bursts have an average spectral index of ≈-2.7, v) the spectral index of the Type III continuum is ≈-1.6, and vi) the degree of circular polarization of all Type I (Type III) bursts is ≈90% (30%). The results obtained here indicate that the continuum emission is due to bursts occurring in rapid succession. We find that the derived parameters for Type I bursts are consistent with suprathermal electron acceleration theory and those of Type III favor fundamental plasma emission.

  19. Correlations between spectra with different symmetries: any chance to be observed?

    NASA Astrophysics Data System (ADS)

    Braun, P.; Leyvraz, F.; Seligman, T. H.

    2011-06-01

    A standard assumption in quantum chaology is the absence of correlation between spectra pertaining to different symmetries. Doubts were raised about this statement for several reasons, in particular because in semiclassics the spectra of different symmetries are expressed in terms of the same set of periodic orbits. We re-examine this question and notice the absence of correlations in the universal regime. In the case of continuous symmetry, the problem is reduced to parametric correlation, and we expect correlations to be present up to a certain time which is essentially classical but larger than the ballistic time.

  20. Satellite observations of type III solar radio bursts at low frequencies

    NASA Technical Reports Server (NTRS)

    Fainberg, J.; Stone, R. G.

    1974-01-01

    Type III solar radio bursts have been observed from 10 MHz to 10 kHz by satellite experiments above the terrestrial plasmasphere. Solar radio emission in this frequency range results from excitation of the interplanetary plasma by energetic particles propagating outward along open field lines over distances from 5 earth radii to at least 1 AU from the sun. This review summarizes the morphology, characteristics, and analysis of individual as well as storms of bursts. Substantial evidence is available to show that the radio emission is observed at the second harmonic instead of the fundamental of the plasma frequency. This brings the density scale derived by radio observations into better agreement with direct solar wind density measurements at 1 AU and relaxes the requirement for type III propagation along large density-enhanced regions. This density scale with the measured direction of arrival of the radio burst allows the trajectory of the exciter path to be determined from 10 earth radii to 1 AU.

  1. Soft X-ray properties of Seyfert galaxies. I - Spectra

    NASA Technical Reports Server (NTRS)

    Kruper, J. S.; Canizares, C. R.; Urry, C. M.

    1990-01-01

    Results are presented from a study of soft X-ray spectra of 75 Seyfert galaxies observed by the Einstein Observatory IPC. The spectra in this sample (mostly high-luminosity Seyfert type 1s) are found to be consistent with a single power-law index alpha = 81. The AGN spectra observed with the IPC are compared with those from higher energy experiments, where AGN spectra have power law indices alpha = 0.7. It is found that the IPC spectra are systematically steeper than the HEAO 1 A-2 spectra of the same Seyfert galaxies, indicating a flattening toward higher energies.

  2. WIDE-BAND SPECTRA OF GIANT RADIO PULSES FROM THE CRAB PULSAR

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mikami, Ryo; Asano, Katsuaki; Tanaka, Shuta J.

    2016-12-01

    We present the results of the simultaneous observation of giant radio pulses (GRPs) from the Crab pulsar at 0.3, 1.6, 2.2, 6.7, and 8.4 GHz with four telescopes in Japan. We obtain 3194 and 272 GRPs occurring at the main pulse and the interpulse phases, respectively. A few GRPs detected at both 0.3 and 8.4 GHz are the most wide-band samples ever reported. In the frequency range from 0.3 to 2.2 GHz, we find that about 70% or more of the GRP spectra are consistent with single power laws and their spectral indices are distributed from −4 to −1. Wemore » also find that a significant number of GRPs have such a hard spectral index (approximately −1) that the fluence at 0.3 GHz is below the detection limit (“dim-hard” GRPs). Stacking light curves of such dim-hard GRPs at 0.3 GHz, we detect consistent enhancement compared to the off-GRP light curve. Our samples show apparent correlations between the fluences and the spectral hardness, which indicates that more energetic GRPs tend to show softer spectra. Our comprehensive studies on the GRP spectra are useful materials to verify the GRP model of fast radio bursts in future observations.« less

  3. Comparison of Frequencies and Rotational Splittings of Solar Acoustic Modes of Low Angular Degree from Simultaneous MDI and GOLF Observations

    NASA Astrophysics Data System (ADS)

    Bertello, L.; Henney, C. J.; Ulrich, R. K.; Varadi, F.; Kosovichev, A. G.; Scherrer, P. H.; Cortés, T. Roca; Thiery, S.; Boumier, P.; Gabriel, A. H.; Turck-Chièze, S.

    2000-06-01

    During the years 1996 through 1998 the Michelson Doppler Imager (MDI) and the Global Oscillations at Low Frequency (GOLF) experiments on the Solar and Heliospheric Observatory (SOHO) mission have provided unique and nearly uninterrupted sequences of helioseismic observations. This paper describes the analysis carried out on power spectra from 759 days of calibrated disk-averaged velocity signals provided by these two experiments. The period investigated in this work is from 1996 May 25 to 1998 June 22. We report the results of frequency determination of low-degree (l<=3) acoustic modes in the frequency range between 1.4 mHz and 3.7 mHz. Rotational splittings are also measured for nonradial modes up to 3.0 mHz. The power spectrum estimation of the signals is performed using classical Fourier analysis and the line-profile parameters of the modes are determined by means of a maximum likelihood method. All parameters have been estimated using both symmetrical and asymmetrical line profile-fitting formula. The line asymmetry parameter of all modes with frequency higher than 2.0 mHz is systematically negative and independent of l. This result is consistent with the fact that both MDI and GOLF data sets investigated in this paper are predominantly velocity signals, in agreement with previous results. A comparison of the results between the symmetric and asymmetric fits shows that there is a systematic shift in the frequencies for modes above 2.0 mHz. Below this frequency, the line width of the modes is very small and the time base of the data does not provide enough statistics to reveal an asymmetry. In general, the results show that frequency and rotational splitting values obtained from both the MDI and GOLF signals are in excellent agreement, and no significant differences exist between the two data sets within the accuracy of the measurements. Our results are consistent with a uniform rotation of the solar core at the rate of about 435 nHz and show only very small

  4. Theoretical Interpretation of the Fluorescence Spectra of Toluene and P- Cresol

    DTIC Science & Technology

    1994-07-01

    NUMBER OF PAGES Toluene Geometrica 25 p-Cresol Fluorescence Is. PRICE CODE Spectra 17. SECURITY CLASSIFICATION 13. SECURITY CLASSIFICATION 19...State Frequencies of Toluene ................ 19 6 Computed and exp" Ground State Frequencies of p-Cresol ............... 20 7 Correction Factors for...Computed Ground State Vibrational Frequencies ....... 21 8 Computed and Corrected Excited State Frequencies of Toluene ............. 22 9 Computed and

  5. In-Situ Wave Observations in the High Resolution Air-Sea Interaction DRI

    DTIC Science & Technology

    2008-09-30

    Program ( CDIP ) Harvest buoy located in 204 m depth off Point Conception. The initial sea surface is assumed Gaussian and homogeneous, with spectral...of simulated sea surface elevation. Right panels: corresponding observed frequency-directional wave spectra (source: CDIP ). Upper panels: Typical

  6. Laboratory spectra of C60 and related molecular structures

    NASA Technical Reports Server (NTRS)

    Janca, J.; Solc, M.; Vetesnik, M.

    1994-01-01

    The electronic spectra of fullerene structures in high frequency discharge are studied in the plasma chemistry laboratory of the Faculty of Science of Masaryk University in Brno. The ultraviolet and visual spectra are investigated in order to be compared with the diffuse interstellar bands and interpreted within the theory of quantum mechanics. The preliminary results of the study are presented here in the form of a poster.

  7. Temperature-dependent THz vibrational spectra of clenbuterol hydrochloride

    NASA Astrophysics Data System (ADS)

    Yang, YuPing; Lei, XiangYun; Yue, Ai; Zhang, Zhenwei

    2013-04-01

    Using the high-resolution Terahertz Time-domain spectroscopy (THz-TDS) and the standard sample pellet technique, the far-infrared vibrational spectra of clenbuterol hydrochloride (CH), a β 2-adrenergic agonist for decreasing fat deposition and enhancing protein accretion, were measured in temperature range of 77-295 K. Between 0.2 and 3.6 THz (6.6-120.0 cm-1), seven highly resolved spectral features, strong line-narrowing and a frequency blue-shift were observed with cooling. However, ractopamine hydrochloride, with some structural and pharmacological similarities to clenbuterol hydrochloride, showed no spectral features, indicating high sensitivity and strong specificity of THz-TDS. These results could be used for the rapid and nondestructive CH residual detection in food safety control.

  8. Two-dimensional sum-frequency generation (2D SFG) reveals structure and dynamics of a surface-bound peptide

    PubMed Central

    Laaser, Jennifer E.; Skoff, David R.; Ho, Jia-Jung; Joo, Yongho; Serrano, Arnaldo L.; Steinkruger, Jay D.; Gopalan, Padma; Gellman, Samuel H.; Zanni, Martin T.

    2014-01-01

    Surface-bound polypeptides and proteins are increasingly used to functionalize inorganic interfaces such as electrodes, but their structural characterization is exceedingly difficult with standard technologies. In this paper, we report the first two-dimensional sum-frequency generation (2D SFG) spectra of a peptide monolayer, which is collected by adding a mid-IR pulse shaper to a standard femtosecond SFG spectrometer. On a gold surface, standard FTIR spectroscopy is inconclusive about the peptide structure because of solvation-induced frequency shifts, but the 2D lineshapes, anharmonic shifts, and lifetimes obtained from 2D SFG reveal that the peptide is largely α-helical and upright. Random coil residues are also observed, which do not themselves appear in SFG spectra due to their isotropic structural distribution, but which still absorb infrared light and so can be detected by cross-peaks in 2D SFG spectra. We discuss these results in the context of peptide design. Because of the similar way in which the spectra are collected, these 2D SFG spectra can be directly compared to 2D IR spectra, thereby enabling structural interpretations of surface-bound peptides and biomolecules based on the well-studied structure/2D IR spectra relationships established from soluble proteins. PMID:24372101

  9. Noise spectra in balanced optical detectors based on transimpedance amplifiers.

    PubMed

    Masalov, A V; Kuzhamuratov, A; Lvovsky, A I

    2017-11-01

    We present a thorough theoretical analysis and experimental study of the shot and electronic noise spectra of a balanced optical detector based on an operational amplifier connected in a transimpedance scheme. We identify and quantify the primary parameters responsible for the limitations of the circuit, in particular, the bandwidth and shot-to-electronic noise clearance. We find that the shot noise spectrum can be made consistent with the second-order Butterworth filter, while the electronic noise grows linearly with the second power of the frequency. Good agreement between the theory and experiment is observed; however, the capacitances of the operational amplifier input and the photodiodes appear significantly higher than those specified in manufacturers' datasheets. This observation is confirmed by independent tests.

  10. Noise spectra in balanced optical detectors based on transimpedance amplifiers

    NASA Astrophysics Data System (ADS)

    Masalov, A. V.; Kuzhamuratov, A.; Lvovsky, A. I.

    2017-11-01

    We present a thorough theoretical analysis and experimental study of the shot and electronic noise spectra of a balanced optical detector based on an operational amplifier connected in a transimpedance scheme. We identify and quantify the primary parameters responsible for the limitations of the circuit, in particular, the bandwidth and shot-to-electronic noise clearance. We find that the shot noise spectrum can be made consistent with the second-order Butterworth filter, while the electronic noise grows linearly with the second power of the frequency. Good agreement between the theory and experiment is observed; however, the capacitances of the operational amplifier input and the photodiodes appear significantly higher than those specified in manufacturers' datasheets. This observation is confirmed by independent tests.

  11. Mid-Infrared Frequency-Agile Dual-Comb Spectroscopy

    NASA Astrophysics Data System (ADS)

    Luo, Pei-Ling; Yan, Ming; Iwakuni, Kana; Millot, Guy; Hänsch, Theodor W.; Picqué, Nathalie

    2016-06-01

    We demonstrate a new approach to mid-infrared dual-comb spectroscopy. It opens up new opportunities for accurate real-time spectroscopic diagnostics and it significantly simplifies the technique of dual-comb spectroscopy. Two mid-infrared frequency combs of slightly different repetition frequencies and moderate, but rapidly tunable, spectral span are generated in the 2800-3200 cm-1 region. The generators rely on electro-optic modulators, nonlinear fibers for spectral broadening and difference frequency generation and do not involve mode-locked lasers. Flat-top frequency combs span up to 10 cm-1 with a comb line spacing of 100 MHz (3×10-3 cm-1). The performance of the spectrometer without any phase-lock electronics or correction scheme is illustrated with spectra showing resolved comb lines and Doppler-limited spectra of methane. High precision on the spectroscopic parameter (line positions and intensities) determination is demonstrated for spectra measured on a millisecond time scale and it is validated with comparison with literature data. G. Millot, S. Pitois, M. Yan, T. Hovannysyan, A. Bendahmane, T.W. Hänsch, N. Picqué, Frequency-agile dual-comb spectroscopy, Nature Photonics 10, 27-30 (2016).

  12. Intensity and angle-of-arrival spectra of laser light propagating through axially homogeneous buoyancy-driven turbulence.

    PubMed

    Pawar, Shashikant S; Arakeri, Jaywant H

    2016-08-01

    Frequency spectra obtained from the measurements of light intensity and angle of arrival (AOA) of parallel laser light propagating through the axially homogeneous, axisymmetric buoyancy-driven turbulent flow at high Rayleigh numbers in a long (length-to-diameter ratio of about 10) vertical tube are reported. The flow is driven by an unstable density difference created across the tube ends using brine and fresh water. The highest Rayleigh number is about 8×109. The aim of the present work is to find whether the conventional Obukhov-Corrsin scaling or Bolgiano-Obukhov (BO) scaling is obtained for the intensity and AOA spectra in the case of light propagation in a buoyancy-driven turbulent medium. Theoretical relations for the frequency spectra of log amplitude and AOA fluctuations developed for homogeneous isotropic turbulent media are modified for the buoyancy-driven flow in the present case to obtain the asymptotic scalings for the high and low frequency ranges. For low frequencies, the spectra of intensity and vertical AOA fluctuations obtained from measurements follow BO scaling, while scaling for the spectra of horizontal AOA fluctuations shows a small departure from BO scaling.

  13. Power spectra comparison between GOLF and spatially masked MDI velocity signals

    NASA Astrophysics Data System (ADS)

    Henney, C. J.; Ulrich, R. K.; Bertello, L.; Bogart, R. S.; Bush, R. I.; Scherrer, P. H.; Cortés, T. Roca; Turck-Chièze, S.

    1999-08-01

    The Global Oscillations at Low Frequency (GOLF) and the Michelson Doppler Imager (MDI) instruments aboard the Solar and Heliospheric Observatory (SOHO) give an excellent opportunity to search for solar low frequency oscillation modes previously undetected from ground based experiments. Presented here is a comparison of the velocity power spectra between the two instruments. In addition, this paper outlines work towards creating a GOLF-simulated signal utilizing MDI velocity images. The simulation of the GOLF signal is achieved by integrating spatially weighted masks with MDI full-disk Doppler images. The GOLF-simulated signal and a selection of additional spatially masked MDI velocity signals are compared with the observed GOLF signal for a 759 day period from May 25, 1996 through June 22, 1998. Ultimately, a cross-analysis process between GOLF and MDI signals could lead to an enhancement of our ability to detect low frequency solar oscillations. For low degree (l<= 3) and low frequency acoustic modes, the signal-to-background ratio between GOLF and the spatially masked MDI velocity data is compared here.

  14. Discrete-time nonlinear damping backstepping control with observers for rejection of low and high frequency disturbances

    NASA Astrophysics Data System (ADS)

    Kim, Wonhee; Chen, Xu; Lee, Youngwoo; Chung, Chung Choo; Tomizuka, Masayoshi

    2018-05-01

    A discrete-time backstepping control algorithm is proposed for reference tracking of systems affected by both broadband disturbances at low frequencies and narrow band disturbances at high frequencies. A discrete time DOB, which is constructed based on infinite impulse response filters is applied to compensate for narrow band disturbances at high frequencies. A discrete-time nonlinear damping backstepping controller with an augmented observer is proposed to track the desired output and to compensate for low frequency broadband disturbances along with a disturbance observer, for rejecting narrow band high frequency disturbances. This combination has the merit of simultaneously compensating both broadband disturbances at low frequencies and narrow band disturbances at high frequencies. The performance of the proposed method is validated via experiments.

  15. Modelling the time-dependent frequency content of low-frequency volcanic earthquakes

    NASA Astrophysics Data System (ADS)

    Jousset, Philippe; Neuberg, Jürgen; Sturton, Susan

    2003-11-01

    Low-frequency volcanic earthquakes and tremor have been observed on seismic networks at a number of volcanoes, including Soufrière Hills volcano on Montserrat. Single events have well known characteristics, including a long duration (several seconds) and harmonic spectral peaks (0.2-5 Hz). They are commonly observed in swarms, and can be highly repetitive both in waveforms and amplitude spectra. As the time delay between them decreases, they merge into tremor, often preceding critical volcanic events like dome collapses or explosions. Observed amplitude spectrograms of long-period volcanic earthquake swarms may display gliding lines which reflect a time dependence in the frequency content. Using a magma-filled dyke embedded in a solid homogeneous half-space as a simplified volcanic structure, we employ a 2D finite-difference method to compute the propagation of seismic waves in the conduit and its vicinity. We successfully replicate the seismic wave field of a single low-frequency event, as well as the occurrence of events in swarms, their highly repetitive characteristics, and the time dependence of their spectral content. We use our model to demonstrate that there are two modes of conduit resonance, leading to two types of interface waves which are recorded at the free surface as surface waves. We also demonstrate that reflections from the top and the bottom of a conduit act as secondary sources that are recorded at the surface as repetitive low-frequency events with similar waveforms. We further expand our modelling to account for gradients in physical properties across the magma-solid interface. We also expand it to account for time dependence of magma properties, which we implement by changing physical properties within the conduit during numerical computation of wave propagation. We use our expanded model to investigate the amplitude and time scales required for modelling gliding lines, and show that changes in magma properties, particularly changes in the

  16. The structure elucidation of mequindox and 1,4-bisdesoxymequindox: NMR analyses, FT-IR spectra, DFT calculations and thermochemical studies

    NASA Astrophysics Data System (ADS)

    Zhang, Jiaheng; He, Xin; Gao, Haixiang

    2011-10-01

    In the current work, we report a combined experimental and theoretical study on the molecular conformation, vibrational spectra, and nuclear magnetic resonance (NMR) spectra of mequindox (MEQ) and 1,4-bisdesoxymequindox (1,4-BDM). The geometric structure and vibrational frequencies of MEQ and 1,4-BDM have been calculated by density functional theory employing the B3LYP functional and 6-311++G(d,p) basis set. The 1H and 13C NMR chemical shifts have been calculated by gauge-including atomic orbital method with B3LYP 6-311++G(2df,2pd) approach. The calculation results have been applied to simulate the infrared and NMR spectra of the compounds. The theoretical results agree well with the observed spectra. The bond dissociation enthalpy of MEQ and the heat of formation of MEQ and 1,4-BDM have also been computed.

  17. Early Pulsar Observations in Australia

    NASA Astrophysics Data System (ADS)

    Wielebinski, R.

    2012-12-01

    The news about the discovery of the pulsar CP1919 reached Australia soon after the Hewish et al. publication in Nature came out at the end of February 1968. Immediately the Parkes radio telescope was transferred from scheduled observations to observe this new exciting object. Since pulsars have steep spectra, low radio frequency receivers were needed that were not supported by the Radiophysics Division of the CSIRO. As a result I, a staff member of the School of Electrical Engineering, Sydney University, was asked to come with my low-frequency receivers to Parkes and join in the first observations. Later the Molonglo Mills Cross radio telescope showed its suitability to pulsar discoveries and became involved in a number of important discoveries. New additional equipment aimed for the reception of pulsating signals had to be constructed in a hurry. In my talk I will cover the period 1968 to 1970 when I left Sydney for the Max-Planck-Institute in Bonn with its 100-m radio telescope.

  18. Ground and space observations of medium frequency auroral radio emissions

    NASA Astrophysics Data System (ADS)

    Broughton, Matthew C.

    The auroral zone is a rich source of natural radio emissions that can be observed in space and at ground-level. By studying these waves, scientists can gain insight into the plasma processes that generate them and use the near-Earth space environment as a large-scale plasma physics laboratory. This thesis uses both ground-level and in situ observations to study two kinds of natural radio emissions. First, we report observations of a new kind of auroral radio emission. The waves have frequencies ranging from 1.3-2.2 MHz, bandwidths ranging from 90-272 kHz, and durations ranging from 16-355 s. Spectral analysis of the waveform data has revealed that the emission has a complex combination of at least three kinds of fine structures. For model auroral electron distributions, calculations indicate that Langmuir waves could be excited at frequencies consistent with observations. The remainder of the thesis discusses auroral medium frequency (MF) burst, an impulsive, broadband natural radio emission observed at ground-level within a few minutes of local substorm onset. LaBelle [2011] proposed that MF burst originates as Langmuir/Z-mode waves on the topside of the ionosphere that subsequently mode convert to L-mode waves and propagate to ground-level. Using continuous waveform measurements and combined observations with the Sondrestrom Incoherent Scatter Radar, we have performed two tests of this mechanism. The results of these tests are consistent with the mechanism described in LaBelle [2011]. A survey of 8,624 half-orbits of the DEMETER spacecraft has revealed 68 observations of bursty MF waves. We have compared the wave properties of these waves to those of MF burst and have found that although it is uncertain, the balance of the evidence suggests that the bursty MF waves observed with DEMETER are the same phenomenon as the ground-level MF burst. Finally, we have used numerical simulations to model both the fine structure of MF burst and to estimate the attenuation the

  19. Expanded Very Large Array Nova Project Observations of the Classical Nova V1723 Aquilae

    NASA Astrophysics Data System (ADS)

    Krauss, Miriam I.; Chomiuk, Laura; Rupen, Michael; Roy, Nirupam; Mioduszewski, Amy J.; Sokoloski, J. L.; Nelson, Thomas; Mukai, Koji; Bode, M. F.; Eyres, S. P. S.; O'Brien, T. J.

    2011-09-01

    We present radio light curves and spectra of the classical nova V1723 Aql obtained with the Expanded Very Large Array (EVLA). This is the first paper to showcase results from the EVLA Nova Project, which comprises a team of observers and theorists utilizing the greatly enhanced sensitivity and frequency coverage of EVLA radio observations, along with observations at other wavelengths, to reach a deeper understanding of the energetics, morphology, and temporal characteristics of nova explosions. Our observations of V1723 Aql span 1-37 GHz in frequency, and we report on data from 14 to 175 days following the time of the nova explosion. The broad frequency coverage and frequent monitoring show that the radio behavior of V1723 Aql does not follow the classic Hubble-flow model of homologous spherically expanding thermal ejecta. The spectra are always at least partially optically thin, and the flux rises on faster timescales than can be reproduced with linear expansion. Therefore, any description of the underlying physical processes must go beyond this simple picture. The unusual spectral properties and light curve evolution might be explained by multiple emitting regions or shocked material. Indeed, X-ray observations from Swift reveal that shocks are likely present.

  20. Expanded Very Large Array Nova Project Observations of the Classical NovaV1723 Aquilae

    NASA Technical Reports Server (NTRS)

    Krauss, Miriam I.; Chomiuk, Laura; Rupen, Michael; Roy, Nirupam; Mioduszewski, Amy J.; Sokoloski, J. L.; Nelson, Thomas; Mukai, Koji; Bode, M. F.; Eyres, S. P. S.; hide

    2011-01-01

    We present radio light curves and spectra of the classical nova VI723 Aql obtained with the Expanded Very Large Array (EVLA). This is the first paper to showcase results from the EVLA Nova Project, which comprises a team of observers and theorists utilizing the greatly enhanced sensitivity and frequency coverage of EVLA radio observations, along with observations at other wavelengths, to reach a deeper understanding of the energetics, morphology, and temporal characteristics of nova explosions. Our observations of VI723 Aql span 1-37 GHz in frequency, and we report on data from 14 to 175 days following the time of the nova explosion. The broad frequency coverage and frequent monitoring show that the radio behavior of VI723 Aql does not follow the classic Hubble-flow model of homologous spherically expanding thermal ejecta. The spectra are always at least partially optically thin, and the flux rises on faster timescales than can be reproduced with linear expansion. Therefore, any description of the underlying physical processes must go beyond this simple picture. The unusual spectral properties and light curve evolution might be explained by multiple emitting regions or shocked material. Indeed, X-ray observations from Swift reveal that shocks are likely present.

  1. Comparison of strong-motion spectra with teleseismic spectra for three magnitude 8 subduction-zone earthquakes

    NASA Astrophysics Data System (ADS)

    Houston, Heidi; Kanamori, Hiroo

    1990-08-01

    A comparison of strong-motion spectra and teleseismic spectra was made for three Mw 7.8 to 8.0 earthquakes: the 1985 Michoacan (Mexico) earthquake, the 1985 Valparaiso (Chile) earthquake, and the 1983 Akita-Oki (Japan) earthquake. The decay of spectral amplitude with the distance from the station was determined, considering different measures of distance from a finite fault, and it was found to be different for these three events. The results can be used to establish empirical relations between the observed spectra and the half-space responses depending on the distance and the site condition, making it possible to estimate strong motions from source spectra determined from teleseismic records.

  2. A New Ka-Band Scanning Radar Facility: Polarimetric and Doppler Spectra Measurements of Snow Events

    NASA Astrophysics Data System (ADS)

    Oue, M.; Kollias, P.; Luke, E. P.; Mead, J.

    2017-12-01

    radars were available. Larger DWR (>10 dB) suggested large, faster-falling, high-reflectivity particles, consistent with large aggregates (> 1 cm) observed at the ground. The presentation will show an advanced analysis using synergy between multi frequency, polarimetry, and Doppler spectra measurements.

  3. Improving Ambiguity Resolution for Medium Baselines Using Combined GPS and BDS Dual/Triple-Frequency Observations

    PubMed Central

    Gao, Wang; Gao, Chengfa; Pan, Shuguo; Wang, Denghui; Deng, Jiadong

    2015-01-01

    The regional constellation of the BeiDou navigation satellite system (BDS) has been providing continuous positioning, navigation and timing services since 27 December 2012, covering China and the surrounding area. Real-time kinematic (RTK) positioning with combined BDS and GPS observations is feasible. Besides, all satellites of BDS can transmit triple-frequency signals. Using the advantages of multi-pseudorange and carrier observations from multi-systems and multi-frequencies is expected to be of much benefit for ambiguity resolution (AR). We propose an integrated AR strategy for medium baselines by using the combined GPS and BDS dual/triple-frequency observations. In the method, firstly the extra-wide-lane (EWL) ambiguities of triple-frequency system, i.e., BDS, are determined first. Then the dual-frequency WL ambiguities of BDS and GPS were resolved with the geometry-based model by using the BDS ambiguity-fixed EWL observations. After that, basic (i.e., L1/L2 or B1/B2) ambiguities of BDS and GPS are estimated together with the so-called ionosphere-constrained model, where the ambiguity-fixed WL observations are added to enhance the model strength. During both of the WL and basic AR, a partial ambiguity fixing (PAF) strategy is adopted to weaken the negative influence of new-rising or low-elevation satellites. Experiments were conducted and presented, in which the GPS/BDS dual/triple-frequency data were collected in Nanjing and Zhengzhou of China, with the baseline distance varying from about 28.6 to 51.9 km. The results indicate that, compared to the single triple-frequency BDS system, the combined system can significantly enhance the AR model strength, and thus improve AR performance for medium baselines with a 75.7% reduction of initialization time on average. Besides, more accurate and stable positioning results can also be derived by using the combined GPS/BDS system. PMID:26528977

  4. Improving Ambiguity Resolution for Medium Baselines Using Combined GPS and BDS Dual/Triple-Frequency Observations.

    PubMed

    Gao, Wang; Gao, Chengfa; Pan, Shuguo; Wang, Denghui; Deng, Jiadong

    2015-10-30

    The regional constellation of the BeiDou navigation satellite system (BDS) has been providing continuous positioning, navigation and timing services since 27 December 2012, covering China and the surrounding area. Real-time kinematic (RTK) positioning with combined BDS and GPS observations is feasible. Besides, all satellites of BDS can transmit triple-frequency signals. Using the advantages of multi-pseudorange and carrier observations from multi-systems and multi-frequencies is expected to be of much benefit for ambiguity resolution (AR). We propose an integrated AR strategy for medium baselines by using the combined GPS and BDS dual/triple-frequency observations. In the method, firstly the extra-wide-lane (EWL) ambiguities of triple-frequency system, i.e., BDS, are determined first. Then the dual-frequency WL ambiguities of BDS and GPS were resolved with the geometry-based model by using the BDS ambiguity-fixed EWL observations. After that, basic (i.e., L1/L2 or B1/B2) ambiguities of BDS and GPS are estimated together with the so-called ionosphere-constrained model, where the ambiguity-fixed WL observations are added to enhance the model strength. During both of the WL and basic AR, a partial ambiguity fixing (PAF) strategy is adopted to weaken the negative influence of new-rising or low-elevation satellites. Experiments were conducted and presented, in which the GPS/BDS dual/triple-frequency data were collected in Nanjing and Zhengzhou of China, with the baseline distance varying from about 28.6 to 51.9 km. The results indicate that, compared to the single triple-frequency BDS system, the combined system can significantly enhance the AR model strength, and thus improve AR performance for medium baselines with a 75.7% reduction of initialization time on average. Besides, more accurate and stable positioning results can also be derived by using the combined GPS/BDS system.

  5. New structures of power density spectra for four Kepler active galactic nuclei

    NASA Astrophysics Data System (ADS)

    Dobrotka, A.; Antonuccio-Delogu, V.; Bajčičáková, I.

    2017-09-01

    Many nearby active galactic nuclei display a significant short-term variability. In this work, we reanalyse photometric data of four active galactic nuclei observed by Kepler in order to study the flickering activity, with our main goal to search for multiple components in the power density spectra. We find that all four objects have similar characteristics, with two break frequencies at approximately log( f /Hz) = -5.2 and -4.7. We consider some physical phenomena whose characteristic time-scales are consistent with those observed, in particular mass accretion fluctuations in the inner geometrically thick disc (hot X-ray corona) and unstable relativistic Rayleigh-Taylor modes. The former is supported by detection of the same break frequencies in the Swift X-ray data of ZW229-15. We also discuss rms-flux relations, and we detect a possible typical linear trend at lower flux levels. Our findings support the hypothesis of a multiplicative character of variability, in agreement with the propagating accretion fluctuation model.

  6. Estimation of snow in extratropical cyclones from multiple frequency airborne radar observations. An Expectation-Maximization approach

    NASA Astrophysics Data System (ADS)

    Grecu, M.; Tian, L.; Heymsfield, G. M.

    2017-12-01

    A major challenge in deriving accurate estimates of physical properties of falling snow particles from single frequency space- or airborne radar observations is that snow particles exhibit a large variety of shapes and their electromagnetic scattering characteristics are highly dependent on these shapes. Triple frequency (Ku-Ka-W) radar observations are expected to facilitate the derivation of more accurate snow estimates because specific snow particle shapes tend to have specific signatures in the associated two-dimensional dual-reflectivity-ratio (DFR) space. However, the derivation of accurate snow estimates from triple frequency radar observations is by no means a trivial task. This is because the radar observations can be subject to non-negligible attenuation (especially at W-band when super-cooled water is present), which may significantly impact the interpretation of the information in the DFR space. Moreover, the electromagnetic scattering properties of snow particles are computationally expensive to derive, which makes the derivation of reliable parameterizations usable in estimation methodologies challenging. In this study, we formulate an two-step Expectation Maximization (EM) methodology to derive accurate snow estimates in Extratropical Cyclones (ECTs) from triple frequency airborne radar observations. The Expectation (E) step consists of a least-squares triple frequency estimation procedure applied with given assumptions regarding the relationships between the density of snow particles and their sizes, while the Maximization (M) step consists of the optimization of the assumptions used in step E. The electromagnetic scattering properties of snow particles are derived using the Rayleigh-Gans approximation. The methodology is applied to triple frequency radar observations collected during the Olympic Mountains Experiment (OLYMPEX). Results show that snowfall estimates above the freezing level in ETCs consistent with the triple frequency radar

  7. EXPLORATION OF SOURCE FREQUENCY PHASE REFERENCING TECHNIQUES FOR ASTROMETRY AND OBSERVATIONS OF WEAK SOURCES WITH HIGH FREQUENCY SPACE VERY LONG BASELINE INTERFEROMETRY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rioja, M.; Dodson, R.; Malarecki, J.

    2011-11-15

    Space very long baseline interferometry (S-VLBI) observations at high frequencies hold the prospect of achieving the highest angular resolutions and astrometric accuracies, resulting from the long baselines between ground and satellite telescopes. Nevertheless, space-specific issues, such as limited accuracy in the satellite orbit reconstruction and constraints on the satellite antenna pointing operations, limit the application of conventional phase referencing. We investigate the feasibility of an alternative technique, source frequency phase referencing (SFPR), to the S-VLBI domain. With these investigations we aim to contribute to the design of the next generation of S-VLBI missions. We have used both analytical and simulationmore » studies to characterize the performance of SFPR in S-VLBI observations, applied to astrometry and increased coherence time, and compared these to results obtained using conventional phase referencing. The observing configurations use the specifications of the ASTRO-G mission for their starting point. Our results show that the SFPR technique enables astrometry at 43 GHz, using alternating observations with 22 GHz, regardless of the orbit errors, for most weathers and under a wide variety of conditions. The same applies to the increased coherence time for the detection of weak sources. Our studies show that the capability to carry out simultaneous dual frequency observations enables application to higher frequencies, and a general improvement of the performance in all cases, hence we recommend its consideration for S-VLBI programs.« less

  8. Electronic polarization effect on low-frequency infrared and Raman spectra of aprotic solvent: Molecular dynamics simulation study with charge response kernel by second order Møller-Plesset perturbation method

    NASA Astrophysics Data System (ADS)

    Isegawa, Miho; Kato, Shigeki

    2007-12-01

    Low-frequency infrared (IR) and depolarized Raman scattering (DRS) spectra of acetonitrile, methylene chloride, and acetone liquids are simulated via molecular dynamics calculations with the charge response kernel (CRK) model obtained at the second order Møller-Plesset perturbation (MP2) level. For this purpose, the analytical second derivative technique for the MP2 energy is employed to evaluate the CRK matrices. The calculated IR spectra reasonably agree with the experiments. In particular, the agreement is excellent for acetone because the present CRK model well reproduces the experimental polarizability in the gas phase. The importance of interaction induced dipole moments in characterizing the spectral shapes is stressed. The DRS spectrum of acetone is mainly discussed because the experimental spectrum is available only for this molecule. The calculated spectrum is close to the experiment. The comparison of the present results with those by the multiple random telegraph model is also made. By decomposing the polarizability anisotropy time correlation function to the contributions from the permanent, induced polarizability and their cross term, a discrepancy from the previous calculations is observed in the sign of permanent-induce cross term contribution. The origin of this discrepancy is discussed by analyzing the correlation functions for acetonitrile.

  9. IDEOS: Fitting Infrared Spectra from Dusty Galaxies

    NASA Astrophysics Data System (ADS)

    Viola, Vincent; Rupke, D.

    2014-01-01

    We fit models to heavily obscured infrared spectra taken by the Spitzer Space Telescope and prepare them for cataloguing in the Infrared Database of Extragalactic Observables from Spitzer (IDEOS). When completed, IDEOS will contain homogeneously measured mid-infrared spectroscopic observables of more than 4200 galaxies beyond the Local Group. The software we use, QUESTFit, models the spectra using up to three extincted blackbodies (including silicate, water ice, and hydrocarbon absorption) and PAH templates. We present results from a sample of the approximately 200 heavily obscured spectra that will be present in IDEOS.

  10. Natural frequency identification of smart washer by using adaptive observer

    NASA Astrophysics Data System (ADS)

    Ito, Hitoshi; Okugawa, Masayuki

    2014-04-01

    Bolted joints are used in many machines/structures and some of them have been loosened during long time use, and unluckily these bolt loosening may cause a great accident of machines/structures system. These bolted joint, especially in important places, are main object of maintenance inspection. Maintenance inspection with human- involvement is desired to be improved owing to time-consuming, labor-intensive and high-cost. By remote and full automation monitoring of the bolt loosening, constantly monitoring of bolted joint is achieved. In order to detect loosening of bolted joints without human-involvement, applying a structural health monitoring technique and smart structures/materials concept is the key objective. In this study, a new method of bolt loosening detection by adopting a smart washer has been proposed, and the basic detection principle was discussed with numerical analysis about frequency equation of the system, was confirmed experimentally. The smart washer used in this study is in cantilever type with piezoelectric material, which adds the washer the self-sensing and actuation function. The principle used to detect the loosening of the bolts is a method of a bolt loosening detection noted that the natural frequency of a smart washer system is decreasing by the change of the bolt tightening axial tension. The feature of this proposed method is achieving to identify the natural frequency at current condition on demand by adopting the self-sensing and actuation function and system identification algorithm for varying the natural frequency depending the bolt tightening axial tension. A novel bolt loosening detection method by adopting adaptive observer is proposed in this paper. The numerical simulations are performed to verify the possibility of the adaptive observer-based loosening detection. Improvement of the detection accuracy for a bolt loosening is confirmed by adopting initial parameter and variable adaptive gain by numerical simulation.

  11. Probing Buffer-Gas Cooled Molecules with Direct Frequency Comb Spectroscopy in the Mid-Infrrared

    NASA Astrophysics Data System (ADS)

    Spaun, Ben; Changala, Bryan; Bjork, Bryce J.; Heckl, Oliver H.; Patterson, David; Doyle, John M.; Ye, Jun

    2015-06-01

    We present the first demonstration of cavity-enhanced direct frequency comb spectroscopy on buffer-gas cooled molecules.By coupling a mid-infrared frequency comb to a high-finesse cavity surrounding a helium buffer-gas chamber, we can gather rotationally resolved absorption spectra with high sensitivity over a broad wavelength region. The measured ˜10 K rotational and translational temperatures of buffer-gas cooled molecules drastically simplify the observed spectra, compared to those of room temperature molecules, and allow for high spectral resolution limited only by Doppler broadening (10-100 MHz). Our system allows for the extension of high-resolution spectroscopy to larger molecules, enabling detailed analysis of molecular structure and dynamics, while taking full advantage of the powerful optical properties of frequency combs. A. Foltynowicz et al. Cavity-enhanced optical frequency comb spectroscopy in the mid-infrared application to trace detection of hydrogen peroxide. Applied Physics B, vol. 110, pp. 163-175, 2013. {D. Patterson and J. M. Doyle. Cooling molecules in a cell for FTMW spectroscopy. Molecular Physics 110, 1757-1766, 2012

  12. Theory and observations of high frequency Alfvén eigenmodes in low aspect ratio plasmas

    NASA Astrophysics Data System (ADS)

    Gorelenkov, N. N.; Fredrickson, E.; Belova, E.; Cheng, C. Z.; Gates, D.; Kaye, S.; White, R.

    2003-04-01

    New observations of sub-cyclotron frequency instability in low aspect ratio plasmas in national spherical torus experiments are reported. The frequencies of observed instabilities correlate with the characteristic Alfvén velocity of the plasma. A theory of localized compressional Alfvén eigenmodes (CAE) and global shear Alfvén eigenmodes (GAE) in low aspect ratio plasmas is presented to explain the observed high frequency instabilities. CAEs/GAEs are driven by the velocity space gradient of energetic super-Alfvénic beam ions via Doppler shifted cyclotron resonances. One of the main damping mechanisms of GAEs, the continuum damping, is treated perturbatively within the framework of ideal MHD. Properties of these cyclotron instability ions are presented.

  13. Important influence of respiration on human R-R interval power spectra is largely ignored

    NASA Technical Reports Server (NTRS)

    Brown, T. E.; Beightol, L. A.; Koh, J.; Eckberg, D. L.

    1993-01-01

    Frequency-domain analyses of R-R intervals are used widely to estimate levels of autonomic neural traffic to the human heart. Because respiration modulates autonomic activity, we determined for nine healthy subjects the influence of breathing frequency and tidal volume on R-R interval power spectra (fast-Fourier transform method). We also surveyed published literature to determine current practices in this burgeoning field of scientific inquiry. Supine subjects breathed at rates of 6, 7.5, 10, 15, 17.1, 20, and 24 breaths/min and with nominal tidal volumes of 1,000 and 1,500 ml. R-R interval power at respiratory and low (0.06-0.14 Hz) frequencies declined significantly as breathing frequency increased. R-R interval power at respiratory frequencies was significantly greater at a tidal volume of 1,500 than 1,000 ml. Neither breathing frequency nor tidal volume influenced average R-R intervals significantly. Our review of studies reporting human R-R interval power spectra showed that 51% of the studies controlled respiratory rate, 11% controlled tidal volume, and 11% controlled both respiratory rate and tidal volume. The major implications of our analyses are that breathing parameters strongly influence low-frequency as well as respiratory frequency R-R interval power spectra and that this influence is largely ignored in published research.

  14. Phase Acrobatics: The Influence of Excitonic Resonance and Gold Nonresonant Background on Heterodyne-Detected Vibrational Sum Frequency Generation Emission.

    PubMed

    Rich, Christopher C; Lindberg, Kathryn A; Krummel, Amber T

    2017-04-06

    We show how heterodyne-detected vibrational sum frequency generation (HD-VSFG) spectroscopy can discriminate between the excitonic and monomeric properties of a helical, nanotube molecular aggregate by monitoring the phase of the VSFG emission associated with different polarization configurations. By keeping track of the "phase acrobatics" associated with the added phase of the nonresonant SFG emission of gold as well as that of the double-resonance conditions achieved when the SF frequency is resonant with an electronic exciton transition, we discover that for aggregates of tetra(sulfonatophenyl)porphyrin (TSPP) the PPP-polarized spectra exhibit double-resonance conditions while SSP-polarized spectra exhibit resonance only with the ground-state vibration. Along with observed shifts in the vibrational frequency, intensity differences, and sign flips in the imaginary second-order susceptibility, χ s,Im (2) , we conclude that PPP-polarized HD-VSFG spectra reflect the delocalized, excitonic nature of the molecular aggregate, while the SSP-polarized HD-VSFG spectra measure the localized, monomeric nature of the molecular subunits. It is implied from this study that HD-VSFG spectroscopy can be uniquely utilized to measure the excitonic and monomeric properties associated with molecular assemblies for a single sample.

  15. Simultaneous Multi-angle Observations of Strong Langmuir Turbulence at HAARP

    NASA Astrophysics Data System (ADS)

    Watanabe, Naomi; Golkowski, Mark; Sheerin, James P.; Watkins, Brenton J.

    2015-10-01

    We report results from a recent series of experiments employing the HF transmitter of the High Frequency Active Auroral Research Program (HAARP) to generate and study strong Langmuir turbulence (SLT) in the interaction region of overdense ionospheric plasma. The Modular UHF Ionospheric Radar (MUIR) located at the HAARP facility is used as the primary diagnostic. Short pulse, low duty cycle experiments are used to avoid generation of artificial field-aligned irregularities and isolate ponderomotive plasma turbulence effects. The HF pump frequency is close to the 3rd gyro-harmonic frequency and the HF pointing angle and MUIR look angle are between the HF Spitze angle and Magnetic Zenith angle. Plasma line spectra measured simultaneously in different spots of the interaction region display differences dependent on the aspect angle of the HF pump beam in the boresight direction and the pointing angle of the MUIR diagnostic radar. Outshifted Plasma Lines, cascade, collapse, coexistence, spectra are observed in agreement with existing theory and simulation results of Strong Langmuir Turbulence in ionospheric interaction experiments. It is found that SLT at HAARP is most readily observed at a HF pointing angle of 11° and UHF observation angle of 15°, which is consistent with the magnetic zenith effect as documented in previous works and optimal orientation of the refracted HF electric field vector.

  16. Frequency regularities of acoustic modes and multi-colour mode identification in rapidly rotating stars

    NASA Astrophysics Data System (ADS)

    Reese, D. R.; Lignières, F.; Ballot, J.; Dupret, M.-A.; Barban, C.; van't Veer-Menneret, C.; MacGregor, K. B.

    2017-05-01

    Context. Mode identification has remained a major obstacle in the interpretation of pulsation spectra in rapidly rotating stars. This has motivated recent work on calculating realistic multi-colour mode visibilities in this type of star. Aims: We would like to test mode identification methods and seismic diagnostics in rapidly rotating stars, using oscillation spectra that are based on these new theoretical predictions. Methods: We investigate the auto-correlation function and Fourier transform of theoretically calculated frequency spectra, in which modes are selected according to their visibilities. Given that intrinsic mode amplitudes are determined by non-linear saturation and cannot currently be theoretically predicted, we experimented with various ad-hoc prescriptions for setting the mode amplitudes, including using random values. Furthermore, we analyse the ratios between mode amplitudes observed in different photometric bands to see up to what extent they can identify modes. Results: When non-random intrinsic mode amplitudes are used, our results show that it is possible to extract a mean value for the large frequency separation or half its value and, sometimes, twice the rotation rate, from the auto-correlation of the frequency spectra. Furthermore, the Fourier transforms are mostly sensitive to the large frequency separation or half its value. The combination of the two methods may therefore measure and distinguish the two types of separations. When the intrinsic mode amplitudes include random factors, which seems more representative of real stars, the results are far less favourable. It is only when the large separation or half its value coincides with twice the rotation rate, that it might be possible to detect the signature of a frequency regularity. We also find that amplitude ratios are a good way of grouping together modes with similar characteristics. By analysing the frequencies of these groups, it is possible to constrain mode identification, as

  17. Identification of Natural Frequency of Low Rise Building on Soft Ground Profile using Ambient Vibration Method

    NASA Astrophysics Data System (ADS)

    Kamarudin, A. F.; Zainal Abidin, M. H.; Mokhatar, S. N.; Daud, M. E.; Ibrahim, A.; Ibrahim, Z.; Noh, M. S. Md

    2018-04-01

    Natural frequency is the rate at which a body to vibrate or oscillate. Application of ambient vibration (AV) excitation is widely used nowadays as the input motion for building predominant frequency, fo, and ground fundamental frequency, Fo, prediction due to simple, fast, non-destructive, simple handling operation and reliable result. However, it must be emphasized and caution to isolate these frequencies (fo and Fo) from spurious frequencies of site-structure effects especially to low rise building on soft ground deposit. In this study, identification of fo and Fo by using AV measurements were performed on ground and 4-storey primary school reinforced concrete (RC) building at Sekolah Kebangsaan (SK) Sg. Tongkang, Rengit, Johor using 1 Hz of tri-axial seismometer sensor. Overlapping spectra between Fourier Amplitude Spectra (FAS) from and Horizontal to Vertical Spectra Ratio (HVSR) were used to distinguish respective frequencies of building and ground natural frequencies. Three dominant frequencies were identified from the FAS curves at 1.91 Hz, 1.98 Hz and 2.79 Hz in longitudinal (East West-EW), transverse (North South-NS) and vertical (UD) directions. It is expected the building has deformed in translational mode based on the first peak frequency by respective NS and EW components of FAS spectrum. Vertical frequency identified from the horizontal spectrums, might induces to the potential of rocking effect experienced by the school building. Meanwhile, single peak HVSR spectrum at low ground fundamental frequency concentrated at 0.93 Hz indicates to the existence deep contrast of soft deposit. Strong interaction between ground and building at similar frequency (0.93 Hz) observed from the FAS curves on the highest floor has shown the building to behave as a dependent unit against ground response as one rigid mass.

  18. Vibration and acoustic frequency spectra for industrial process modeling using selective fusion multi-condition samples and multi-source features

    NASA Astrophysics Data System (ADS)

    Tang, Jian; Qiao, Junfei; Wu, ZhiWei; Chai, Tianyou; Zhang, Jian; Yu, Wen

    2018-01-01

    Frequency spectral data of mechanical vibration and acoustic signals relate to difficult-to-measure production quality and quantity parameters of complex industrial processes. A selective ensemble (SEN) algorithm can be used to build a soft sensor model of these process parameters by fusing valued information selectively from different perspectives. However, a combination of several optimized ensemble sub-models with SEN cannot guarantee the best prediction model. In this study, we use several techniques to construct mechanical vibration and acoustic frequency spectra of a data-driven industrial process parameter model based on selective fusion multi-condition samples and multi-source features. Multi-layer SEN (MLSEN) strategy is used to simulate the domain expert cognitive process. Genetic algorithm and kernel partial least squares are used to construct the inside-layer SEN sub-model based on each mechanical vibration and acoustic frequency spectral feature subset. Branch-and-bound and adaptive weighted fusion algorithms are integrated to select and combine outputs of the inside-layer SEN sub-models. Then, the outside-layer SEN is constructed. Thus, "sub-sampling training examples"-based and "manipulating input features"-based ensemble construction methods are integrated, thereby realizing the selective information fusion process based on multi-condition history samples and multi-source input features. This novel approach is applied to a laboratory-scale ball mill grinding process. A comparison with other methods indicates that the proposed MLSEN approach effectively models mechanical vibration and acoustic signals.

  19. Mössbauer spectra linearity improvement by sine velocity waveform followed by linearization process

    NASA Astrophysics Data System (ADS)

    Kohout, Pavel; Frank, Tomas; Pechousek, Jiri; Kouril, Lukas

    2018-05-01

    This note reports the development of a new method for linearizing the Mössbauer spectra recorded with a sine drive velocity signal. Mössbauer spectra linearity is a critical parameter to determine Mössbauer spectrometer accuracy. Measuring spectra with a sine velocity axis and consecutive linearization increases the linearity of spectra in a wider frequency range of a drive signal, as generally harmonic movement is natural for velocity transducers. The obtained data demonstrate that linearized sine spectra have lower nonlinearity and line width parameters in comparison with those measured using a traditional triangle velocity signal.

  20. Three-frequency BDS precise point positioning ambiguity resolution based on raw observables

    NASA Astrophysics Data System (ADS)

    Li, Pan; Zhang, Xiaohong; Ge, Maorong; Schuh, Harald

    2018-02-01

    All BeiDou navigation satellite system (BDS) satellites are transmitting signals on three frequencies, which brings new opportunity and challenges for high-accuracy precise point positioning (PPP) with ambiguity resolution (AR). This paper proposes an effective uncalibrated phase delay (UPD) estimation and AR strategy which is based on a raw PPP model. First, triple-frequency raw PPP models are developed. The observation model and stochastic model are designed and extended to accommodate the third frequency. Then, the UPD is parameterized in raw frequency form while estimating with the high-precision and low-noise integer linear combination of float ambiguity which are derived by ambiguity decorrelation. Third, with UPD corrected, the LAMBDA method is used for resolving full or partial ambiguities which can be fixed. This method can be easily and flexibly extended for dual-, triple- or even more frequency. To verify the effectiveness and performance of triple-frequency PPP AR, tests with real BDS data from 90 stations lasting for 21 days were performed in static mode. Data were processed with three strategies: BDS triple-frequency ambiguity-float PPP, BDS triple-frequency PPP with dual-frequency (B1/B2) and three-frequency AR, respectively. Numerous experiment results showed that compared with the ambiguity-float solution, the performance in terms of convergence time and positioning biases can be significantly improved by AR. Among three groups of solutions, the triple-frequency PPP AR achieved the best performance. Compared with dual-frequency AR, additional the third frequency could apparently improve the position estimations during the initialization phase and under constraint environments when the dual-frequency PPP AR is limited by few satellite numbers.

  1. Quantum noise spectra for periodically driven cavity optomechanics

    NASA Astrophysics Data System (ADS)

    Aranas, E. B.; Akram, M. Javed; Malz, Daniel; Monteiro, T. S.

    2017-12-01

    A growing number of experimental setups in cavity optomechanics exploit periodically driven fields. However, such setups are not amenable to analysis by using simple, yet powerful, closed-form expressions of linearized optomechanics, which have provided so much of our present understanding of experimental optomechanics. In the present paper, we formulate a method to calculate quantum noise spectra in modulated optomechanical systems, which we analyze, compare, and discuss with two other recently proposed solutions: we term these (i) frequency-shifted operators, (ii) Floquet [Phys. Rev. A 94, 023803 (2016), 10.1103/PhysRevA.94.023803], and (iii) iterative analysis [New J. Phys. 18, 113021 (2016), 10.1088/1367-2630/18/11/113021]. We prove that (i) and (ii) yield equivalent noise spectra and find that (iii) is an analytical approximation to (i) for weak modulations. We calculate the noise spectra of a doubly modulated system describing experiments of levitated particles in hybrid electro-optical traps. We show excellent agreement with Langevin stochastic simulations in the thermal regime and predict squeezing in the quantum regime. Finally, we reveal how otherwise-inaccessible spectral components of a modulated system can be measured in heterodyne detection through an appropriate choice of modulation frequencies.

  2. Millimeter and submillimeter wave spectra of 13C-glycolaldehydes

    NASA Astrophysics Data System (ADS)

    Haykal, I.; Motiyenko, R. A.; Margulès, L.; Huet, T. R.

    2013-01-01

    Context. Glycolaldehyde (CH2OHCHO) is the simplest sugar and an important intermediate in the path toward forming more complex biologically relevant molecules. Astronomical surveys of interstellar molecules, such as those available with the very sensitive ALMA telescope, require preliminary laboratory investigations of the microwave and submillimeter-wave spectra of molecular species including new isotopologs - to identify these in the interstellar media. Aims: To achieve the detection of the 13C isotopologs of glycolaldehyde in the interstellar medium, their rotational spectra in the millimeter and submillimeter-wave regions were studied. Methods: The spectra of 13CH2OHCHO and CH2OH13CHO were recorded in the 150-945 GHz spectral range in the laboratory using a solid-state submillimeter-wave spectrometer in Lille. The observed line frequencies were measured with an accuracy of 30 kHz up to 700 GHz and of 50 kHz above 700 GHz. We analyzed the spectra with a standard Watson Hamiltonian. Results: About 10 000 new lines were identified for each isotopolog. The spectroscopic parameters were determined for the ground- and the three lowest vibrational states up to 945 and 630 GHz. Previous microwave assignments of 13CH2OHCHO were not confirmed. Conclusions: The provided line-lists and sets of molecular parameters meet the needs for a first astrophysical search of 13C-glycolaldehydes. Full Tables 3 and 4 are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/549/A96

  3. Analysis of high-frequency energy in long-term average spectra of singing, speech, and voiceless fricatives

    PubMed Central

    Monson, Brian B.; Lotto, Andrew J.; Story, Brad H.

    2012-01-01

    The human singing and speech spectrum includes energy above 5 kHz. To begin an in-depth exploration of this high-frequency energy (HFE), a database of anechoic high-fidelity recordings of singers and talkers was created and analyzed. Third-octave band analysis from the long-term average spectra showed that production level (soft vs normal vs loud), production mode (singing vs speech), and phoneme (for voiceless fricatives) all significantly affected HFE characteristics. Specifically, increased production level caused an increase in absolute HFE level, but a decrease in relative HFE level. Singing exhibited higher levels of HFE than speech in the soft and normal conditions, but not in the loud condition. Third-octave band levels distinguished phoneme class of voiceless fricatives. Female HFE levels were significantly greater than male levels only above 11 kHz. This information is pertinent to various areas of acoustics, including vocal tract modeling, voice synthesis, augmentative hearing technology (hearing aids and cochlear implants), and training/therapy for singing and speech. PMID:22978902

  4. Problems in abundance determination from UV spectra of hot supergiants

    NASA Astrophysics Data System (ADS)

    Deković, M. Sarta; Kotnik-Karuza, D.; Jurkić, T.; Dominis Prester, D.

    2010-03-01

    We present measurements of equivalent widths of the UV, presumably photospheric lines: C III 1247 Å, N III 1748 Å, N III 1752 Å, N IV 1718 Å and He II 1640 Å in high-resolution IUE spectra of 24 galactic OB supergiants. Equivalent widths measured from the observed spectra have been compared with their counterparts in the Tlusty NLTE synthetic spectra. We discuss possibilities of static plan-parallel model to reproduce observed UV spectra of hot massive stars and possible reasons why observations differ from the model so much.

  5. - and Frequency-Domain Signatures of Velocity Changing Collisions in Sub-Doppler Saturation Spectra and Pressure Broadening

    NASA Astrophysics Data System (ADS)

    Hall, Gregory; Xu, Hong; Forthomme, Damien; Dagdigian, Paul; Sears, Trevor

    2017-06-01

    We have combined experimental and theoretical approaches to the competition between elastic and inelastic collisions of CN radicals with Ar, and how this competition influences time-resolved saturation spectra. Experimentally, we have measured transient, two-color sub-Doppler saturation spectra of CN radicals with an amplitude chopped saturation laser tuned to selected Doppler offsets within rotational lines of the A-X (2-0) band, while scanning a frequency modulated probe laser across the hyperfine-resolved saturation features of corresponding rotational lines of the A-X (1-0) band. A steady-state depletion spectrum includes off-resonant contributions ascribed to velocity diffusion, and the saturation recovery rates depend on the sub-Doppler detuning. The experimental results are compared with Monte Carlo solutions to the Boltzmann equation for the collisional evolution of the velocity distributions of CN radicals, combined with a pressure-dependent and speed-dependent lifetime broadening. Velocity changing collisions are included by appropriately sampling the energy resolved differential cross sections for elastic scattering of selected rotational states of CN (X). The velocity space diffusion of Doppler tagged molecules proceeds through a series of small-angle scattering events, eventually terminating in an inelastic collision that removes the molecule from the coherently driven ensemble of interest. Collision energy-dependent total cross sections and differential cross sections for elastic scattering of selected CN rotational states with Ar were computed with Hibridon quantum scattering calculations, and used for sampling in the Monte Carlo modeling. Acknowledgments: Work at Brookhaven National Laboratory was carried out under Contract No. DE-SC0012704 with the U.S. Department of Energy, Office of Science, and supported by its Division of Chemical Sciences, Geosciences and Biosciences within the Office of Basic Energy Sciences.

  6. On signatures of clouds in exoplanetary transit spectra

    NASA Astrophysics Data System (ADS)

    Pinhas, Arazi; Madhusudhan, Nikku

    2017-11-01

    Transmission spectra of exoplanetary atmospheres have been used to infer the presence of clouds/hazes. Such inferences are typically based on spectral slopes in the optical deviant from gaseous Rayleigh scattering or low-amplitude spectral features in the infrared. We investigate three observable metrics that could allow constraints on cloud properties from transmission spectra, namely the optical slope, the uniformity of this slope and condensate features in the infrared. We derive these metrics using model transmission spectra considering Mie extinction from a wide range of condensate species, particle sizes and scaleheights. First, we investigate possible degeneracies among the cloud properties for an observed slope. We find, for example, that spectra with very steep optical slopes suggest sulphide clouds (e.g. MnS, ZnS, Na2S) in the atmospheres. Secondly, (non)uniformities in optical slopes provide additional constraints on cloud properties, e.g. MnS, ZnS, TiO2 and Fe2O3 have significantly non-uniform slopes. Thirdly, infrared spectra provide an additional powerful probe into cloud properties, with SiO2, Fe2O3, Mg2SiO4 and MgSiO3 bearing strong infrared features observable with James Webb Space Telescope. We investigate observed spectra of eight hot Jupiters and discuss their implications. In particular, no single or composite condensate species considered here conforms to the steep and non-uniform optical slope observed for HD 189733b. Our work highlights the importance of the three above metrics to investigate cloud properties in exoplanetary atmospheres using high-precision transmission spectra and detailed cloud models. We make our Mie scattering data for condensates publicly available to the community.

  7. AssignFit: a program for simultaneous assignment and structure refinement from solid-state NMR spectra

    PubMed Central

    Tian, Ye; Schwieters, Charles D.; Opella, Stanley J.; Marassi, Francesca M.

    2011-01-01

    AssignFit is a computer program developed within the XPLOR-NIH package for the assignment of dipolar coupling (DC) and chemical shift anisotropy (CSA) restraints derived from the solid-state NMR spectra of protein samples with uniaxial order. The method is based on minimizing the difference between experimentally observed solid-state NMR spectra and the frequencies back calculated from a structural model. Starting with a structural model and a set of DC and CSA restraints grouped only by amino acid type, as would be obtained by selective isotopic labeling, AssignFit generates all of the possible assignment permutations and calculates the corresponding atomic coordinates oriented in the alignment frame, together with the associated set of NMR frequencies, which are then compared with the experimental data for best fit. Incorporation of AssignFit in a simulated annealing refinement cycle provides an approach for simultaneous assignment and structure refinement (SASR) of proteins from solid-state NMR orientation restraints. The methods are demonstrated with data from two integral membrane proteins, one α-helical and one β-barrel, embedded in phospholipid bilayer membranes. PMID:22036904

  8. Artificial neural networks for retrieving absorption and reduced scattering spectra from frequency-domain diffuse reflectance spectroscopy at short source-detector separation

    PubMed Central

    Chen, Yu-Wen; Chen, Chien-Chih; Huang, Po-Jung; Tseng, Sheng-Hao

    2016-01-01

    Diffuse reflectance spectroscopy (DRS) based on the frequency-domain (FD) technique has been employed to investigate the optical properties of deep tissues such as breast and brain using source to detector separation up to 40 mm. Due to the modeling and system limitations, efficient and precise determination of turbid sample optical properties from the FD diffuse reflectance acquired at a source-detector separation (SDS) of around 1 mm has not been demonstrated. In this study, we revealed that at SDS of 1 mm, acquiring FD diffuse reflectance at multiple frequencies is necessary for alleviating the influence of inevitable measurement uncertainty on the optical property recovery accuracy. Furthermore, we developed artificial neural networks (ANNs) trained by Monte Carlo simulation generated databases that were capable of efficiently determining FD reflectance at multiple frequencies. The ANNs could work in conjunction with a least-square optimization algorithm to rapidly (within 1 second), accurately (within 10%) quantify the sample optical properties from FD reflectance measured at SDS of 1 mm. In addition, we demonstrated that incorporating the steady-state apparatus into the FD DRS system with 1 mm SDS would enable obtaining broadband absorption and reduced scattering spectra of turbid samples in the wavelength range from 650 to 1000 nm. PMID:27446671

  9. Characteristics of type III exciters derived from low frequency radio observations

    NASA Technical Reports Server (NTRS)

    Evans, L. G.; Fainberg, J.; Stone, R. G.

    1973-01-01

    Low-frequency radio observations (2.8 MHz to 67 kHz) from the RAE-1 and IMP-6 satellites allow the tracking of type III solar burst exciters out to large distances from the sun (of the order of 1 AU). A study of the interaction processes between the exciter and the interplanetary medium was made using the time-intensity profiles of the radio emission. The change in exciter length with distance from the sun, and the resulting exciter velocity dispersion which can be deduced from this change are investigated. From detailed measurements on 35 simple bursts it is found that the exciter length increases at a faster rate than a constant velocity dispersion would give. The damping of the radio emission is also investigated, and it is concluded that some current theories of the damping mechanism give results which are not consistent with the low-frequency observations.

  10. Normal Unenhanced Raman Spectra of CO and CH/sub 4/ adsorbed on cobalt(poly)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Marzouk, H.A.; Bradley, E.B.; Arunkumar, K.A.

    Normal Unenhanced Raman Spectra (NURS) of low-polarizability CO molecules were observed for the first time on cobalt at R.T. and residual gas pressure. We assign five bands observed between 2030--2130 cm/sup -1/ to linear chemisorbed CO species, while those observed between 1840--2010 cm/sup -1/ have been ascribed to the 2--fold chemisorbed species. The three bands observed between 1740--1830 cm/sup -1/ we believe are due to the 3--fold species. The corresponding fourteen Co-C stretches were observed and assigned. A model based upon electron backdonation is proposed for each of the three structures. NURS were also observed at R.T. for physisorbed CH/submore » 4/ and assignments are made to the four frequencies of CH/sub 4/.« less

  11. Low-Frequency Amplitudes Observed in a Set of the Strongest Recorded Ground Motions (Invited)

    NASA Astrophysics Data System (ADS)

    Anderson, J. G.; Koketsu, K.; Miyake, H.

    2010-12-01

    Anderson (2010) compiled a set of “exceptional” ground motion characterized by peak acceleration that exceeds 500 gal on at least one component or peak velocity that exceeds 50 cm/s on at least one component. With the addition of more recent data, there are now over 280 openly available records that meet these criteria. These data are examined to find to the empirical upper bound of observed pseudo-acceleration (PSA) response spectra and smoothed Fourier amplitude spectra. Statistics of amplitudes of PSA and of low-pass filtered acceleration and velocity have also been determined. Amplitudes recorded at the Kawaguchi-cho station (40 km) at 5-6 second period from the 1964 Niigata earthquake (Mw=8.3) are within ~20% of the current empirical limit of ground motions observed from all earthquakes in the data set including those from the near field. An even more impressive example is that amplitudes recorded at the SCT station (~300 km from the fault) with period of about 2 seconds, during the 1985 Michoacan, Mexico, earthquake (Mw=8.0), are about the same as the current empirical limit of ground motions observed from near field records. These examples support the idea that the hazard caused by long-period ground motions, amplified by basins and site conditions, is not sufficiently appreciated. Reference: Anderson, J. G. (2010), Bull. Seism. Soc. Am. 100, 1-36.

  12. Maturation of EEG Power Spectra in Early Adolescence: A Longitudinal Study

    ERIC Educational Resources Information Center

    Cragg, Lucy; Kovacevic, Natasa; McIntosh, Anthony Randal; Poulsen, Catherine; Martinu, Kristina; Leonard, Gabriel; Paus, Tomas

    2011-01-01

    This study investigated the fine-grained development of the EEG power spectra in early adolescence, and the extent to which it is reflected in changes in peak frequency. It also sought to determine whether sex differences in the EEG power spectra reflect differential patterns of maturation. A group of 56 adolescents were tested at age 10 years and…

  13. Planck Early Results. XV. Spectral Energy Distributions and Radio Continuum Spectra of Northern Extragalactic Radio Sources

    NASA Technical Reports Server (NTRS)

    Aatrokoski, J.; Ade, P. A. R.; Aghanim, N.; Aller, H. D.; Aller, M. F.; Angelakis, E.; Amaud, M.; Ashdown, M.; Aumont, J.; Baccigalupi, C.; hide

    2011-01-01

    Spectral energy distributions (SEDs) and radio continuum spectra are presented for a northern sample of 104 extragalactic radio sources. based on the Planck Early Release Compact Source Catalogue (ERCSC) and simultaneous multi frequency data. The nine Planck frequencies, from 30 to 857 GHz, are complemented by a set of simultaneous observations ranging from radio to gamma-rays. This is the first extensive frequency coverage in the radio and millimetre domains for an essentially complete sample of extragalactic radio sources, and it shows how the individual shocks, each in their own phase of development, shape the radio spectra as they move in the relativistic jet. The SEDs presented in this paper were fitted with second and third degree polynomials to estimate the frequencies of the synchrotron and inverse Compton (IC) peaks, and the spectral indices of low and high frequency radio data, including the Planck ERCSC data, were calculated. SED modelling methods are discussed, with an emphasis on proper. physical modelling of the synchrotron bump using multiple components. Planck ERCSC data also suggest that the original accelerated electron energy spectrum could be much harder than commonly thought, with power-law index around 1.5 instead of the canonical 2.5. The implications of this are discussed for the acceleration mechanisms effective in blazar shock. Furthermore in many cases the Planck data indicate that gamma-ray emission must originate in the same shocks that produce the radio emission.

  14. VizieR Online Data Catalog: Sgr B2 los molecular absorption line spectra (Corby+, 2018)

    NASA Astrophysics Data System (ADS)

    Corby, J. F.; McGuire, B. A.; Herbst, E.; Remijan, A. J.

    2017-11-01

    Spectra covering transitions of c-C3H2, c-H1 SO, CCS, H2CS, HCS+, OH, SiO, 29SiO, H2CO, H2(13C)O, l-C3H, and l-C3H+ with line-of-sight absorption observed in the 1-50 GHz data from the PRebiotic Interstellar MOlecular Survey (PRIMOS) taken with the Robert C. Byrd Green Bank Telescope (GBT). Data were observed between 2001 and 2014, with the majority of the data obtained in 2007 in GBT Key Science project ID GBT07A-051. Spectra have been baseline-subtracted using best fit polynomials as described in the paper, and normalized by the continuum, so that the y-axis represents (T/TC-1). Data are provided in the FITS format; each FITS file contains all lines of a single molecule that are observed to have foreground absorption. Please refer to Table 1 of the paper to obtain molecular transition rest frequencies, energies, GBT beam sizes, and transition quantum numbers. (2 data files).

  15. Observations of candidate oscillating eclipsing binaries and two newly discovered pulsating variables

    NASA Astrophysics Data System (ADS)

    Liakos, A.; Niarchos, P.

    2009-03-01

    CCD observations of 24 eclipsing binary systems with spectral types ranging between A0-F0, candidate for containing pulsating components, were obtained. Appropriate exposure times in one or more photometric filters were used so that short-periodic pulsations could be detected. Their light curves were analyzed using the Period04 software in order to search for pulsational behaviour. Two new variable stars, namely GSC 2673-1583 and GSC 3641-0359, were discov- ered as by-product during the observations of eclipsing variables. The Fourier analysis of the observations of each star, the dominant pulsation frequencies and the derived frequency spectra are also presented.

  16. Predicting lanthanide cluster properties: a comparison with the observed optical spectra of HO 2

    NASA Astrophysics Data System (ADS)

    Nemukhin, A. V.; Ermilov, A. Yu.; Petrukhina, M. A.; Klotzbücher, W. E.; Smets, J.

    1997-10-01

    Ab initio pseudopotential calculations for HO and HO 2 have been carried out in order to support an assignment of the bands observed in UV-visible spectra of matrix isolated holmium species. SCF, MCSCF and configuration interaction (CI) procedures have been used with quasirelativistic pseudopotentials to compute the ground and excited state energies of HO and HO 2, together with the dipole transition moments. For HO 2, using a Q = 11 pseudopotential (describing the holmium atom in the 4f 106s 25d 1 electronic state), two transitions from the ground state σg2σu2πu2 to the states with principal excitations σu → πg and π u → σ g∗ are predicted at 499 and 524 nm. These two lines, with predicted close intensities, correlate nicely with the observed features at 498/504 and 558/563nm in the spectrum of matrix-isolated HO 2.

  17. Ab initio and DFT studies of the structure and vibrational spectra of anhydrous caffeine

    NASA Astrophysics Data System (ADS)

    Srivastava, Santosh K.; Singh, Vipin B.

    2013-11-01

    Vibrational spectra and molecular structure of anhydrous caffeine have been systematically investigated by second order Moller-Plesset (MP2) perturbation theory and density functional theory (DFT) calculations. Vibrational assignments have been made and many previous ambiguous assignments in IR and Raman spectra are amended. The calculated DFT frequencies and intensities at B3LYP/6-311++G(2d,2p) level, were found to be in better agreement with the experimental values. It was found that DFT with B3LYP functional predicts harmonic vibrational wave numbers more close to experimentally observed value when it was performed on MP2 optimized geometry rather than DFT geometry. The calculated TD-DFT vertical excitation electronic energies of the valence excited states of anhydrous caffeine are found to be in consonance to the experimental absorption peaks.

  18. Observation of current reversal in the scanning tunneling spectra of fullerene-like WS2 nanoparticles.

    PubMed

    Azulay, Doron; Kopnov, Frieda; Tenne, Reshef; Balberg, Isaac; Millo, Oded

    2006-04-01

    Current-voltage characteristics measured using STM on fullerene-like WS2 nanoparticles show zero-bias current and contain segments in which the tunneling current flows opposite to the applied bias voltage. In addition, negative differential conductance peaks emerge in these reversed current segments, and the characteristics are hysteretic with respect to the change in the voltage sweep direction. Such unusual features resemble those appearing in cyclic voltammograms, but are uniquely observed here in tunneling spectra measured in vacuum, as well as in ambient and dry atmosphere conditions. This behavior is attributed to tunneling-driven electrochemical processes.

  19. Steep radio spectra in high-redshift radio galaxies

    NASA Technical Reports Server (NTRS)

    Krolik, Julian H.; Chen, Wan

    1991-01-01

    The generic spectrum of an optically thin synchrotron source steepens by 0.5 in spectral index from low frequencies to high whenever the source lifetime is greater than the energy-loss timescale for at least some of the radiating electrons. Three effects tend to decrease the frequency nu(b) of this spectral bend as the source redshift increases: (1) for fixed bend frequency nu* in the rest frame, nu(b) = nu*/(1 + z); (2) losses due to inverse Compton scattering the microwave background rise with redshift as (1 + z) exp 4, so that, for fixed residence time in the radiating region, the energy of the lowest energy electron that can cool falls rapidly with increasing redshift; and (3) if the magnetic field is proportional to the equipartition field and the emitting volume is fixed or slowly varying, flux-limited samples induce a selection effect favoring low nu* at high z because higher redshift sources require higher emissivity to be included in the sample, and hence have stronger implied fields and more rapid synchrotron losses. A combination of these effects may explain the trend observed in the 3CR sample for higher redshift radio galaxies to have steeper spectra, and the successful use of ultrasteep spectrum surveys to locate high-redshift galaxies.

  20. Galactic and extragalactic hydrogen in the X-ray spectra of Gamma Ray Bursts

    NASA Astrophysics Data System (ADS)

    Rácz, I. I.; Bagoly, Z.; Tóth, L. V.; Balázs, L. G.; Horváth, I.; Pintér, S.

    2017-07-01

    Two types of emission can be observed from gamma-ray bursts (GRBs): the prompt emission from the central engine which can be observed in gamma or X-ray (as a low energy tail) and the afterglow from the environment in X-ray and at shorter frequencies. We examined the Swift XRT spectra with the XSPEC software. The correct estimation of the galactic interstellar medium is very important because we observe the host emission together with the galactic hydrogen absorption. We found that the estimated intrinsic hydrogen column density and the X-ray flux depend heavily on the redshift and the galactic foreground hydrogen. We also found that the initial parameters of the iteration and the cosmological parameters did not have much effect on the fitting result.

  1. Long-Term Changes in Stratospheric Age Spectra in the 21st Century in the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM)

    NASA Technical Reports Server (NTRS)

    Li, Feng; Waugh, Darryn W.; Douglass, Anne R.; Newman, Paul A.; Strahan, Susan E.; Ma, Jun; Nielsen, J. Eric; Liang, Qing

    2012-01-01

    In this study we investigate the long-term variations in the stratospheric age spectra using simulations of the 21st century with the Goddard Earth Observing System Chemistry- Climate Model (GEOSCCM). Our purposes are to characterize the long-term changes in the age spectra and identify processes that cause the decrease of the mean age in a warming climate. Changes in the age spectra in the 21st century simulations are characterized by decreases in the modal age, the mean age, the spectral width, and the tail decay timescale. Our analyses show that the decrease in the mean age is caused by two processes: the acceleration of the residual circulation that increases the young air masses in the stratosphere, and the weakening of the recirculation that leads to the decrease of tail of the age spectra and the decrease of the old air masses. The weakening of the stratospheric recirculation is also strongly correlated with the increase of the residual circulation. One important result of this study is that the decrease of the tail of the age spectra makes an important contribution to the decrease of the main age. Long-term changes in the stratospheric isentropic mixing are investigated. Mixing increases in the subtropical lower stratosphere, but its impact on the age spectra is outweighed by the increase of the residual circulation. The impacts of the long-term changes in the age spectra on long-lived chemical traces are also investigated. 37 2

  2. OSO-8 X-ray spectra of clusters of galaxies. 1. Observations of twenty clusters: Physical correlations

    NASA Technical Reports Server (NTRS)

    Mushotzky, R. F.; Serlemitsos, P. J.; Smith, B. W.; Boldt, E. A.; Holt, S. S.

    1978-01-01

    OSO-8 X-ray spectra from 2 to 20 keV were analyzed for 26 clusters of galaxies. Temperature, emission integrals, iron abundances, and low energy absorption measurements are given. Eight clusters have positive iron emission line detections at the 90% confidence level, and all twenty cluster spectra are consistent with Fe/H=0.000014 by number with the possible exception of Virgo. Physical correlations between X-ray spectral parameters and other cluster properties are examined. It is found that: (1) the X-ray temperature is approximately proportional to the square of the velocity dispersion of the galaxies; (2) the emission integral and therefore the bolometric X-ray luminosity is a strong function of the X-ray temperature; (3) the X-ray temperature and emission integral are better correlated with cluster central galaxy density than with richness; (4) temperature and emission integral are separately correlated with Rood-Sastry type; and (5) the fraction of galaxies which are spirals is correlated with the observed ram pressure in the cluster core.

  3. Spectra of W19 +-W32 + observed in the EUV region between 15 and 55 Å with an electron-beam ion trap

    NASA Astrophysics Data System (ADS)

    Sakaue, H. A.; Kato, D.; Yamamoto, N.; Nakamura, N.; Murakami, I.

    2015-07-01

    We present extreme ultraviolet spectra of highly charged tungsten ions (W19 +-W32 + ) in the wavelength range of 15 -55 Å obtained with a compact electron-beam ion trap (CoBIT) and a grazing-incidence spectrometer at the National Institute for Fusion Science. The electron energy dependence of the spectra was investigated for electron energies from 490 to 1320 eV . Identification of the observed lines was aided by collisional-radiative (CR) modeling of CoBIT plasma. Good quantitative agreement was obtained between the CR-modeling results and the experimental observations. The ion charge dependence of the 6 g -4 f ,5 g -4 f ,5 f -4 d ,5 p -4 d , and 4 f -4 d transition wavelengths were measured.

  4. Terahertz spectra of l-phenylalanine and its monohydrate.

    PubMed

    Pan, Tingting; Li, Shaoping; Zou, Tao; Yu, Zheng; Zhang, Bo; Wang, Chenyang; Zhang, Jianbing; He, Mingxia; Zhao, Hongwei

    2017-05-05

    The low-frequency vibrational property of l-phenylalanine (l-Phe) and l-phenylalanine monohydrate (l-Phe·H 2 O) has been investigated by terahertz time-domain spectroscopy (THz-TDS) at room and low temperature ranging from 0.5 to 4.5THz. Distinctive THz absorption spectra of the two compounds were observed. Density functional theory (DFT) calculations based on the crystal structures have been performed to simulate the vibrational modes of l-Phe and l-Phe·H 2 O and the results agree well with the experimental observations. The study indicates that the characterized features of l-Phe mainly originate from the collective vibration of molecules. And the characterized features of l-Phe·H 2 O mainly come from hydrogen bond interactions between l-Phe and water molecules. l-Phe and l-Phe·H 2 O were also verified by differential scanning calorimetry and thermogravimetry (DSC-TG) and powder X-ray diffraction (PXRD) examinations. Copyright © 2017. Published by Elsevier B.V.

  5. Terahertz spectra of L-phenylalanine and its monohydrate

    NASA Astrophysics Data System (ADS)

    Pan, Tingting; Li, Shaoping; Zou, Tao; Yu, Zheng; Zhang, Bo; Wang, Chenyang; Zhang, Jianbing; He, Mingxia; Zhao, Hongwei

    2017-05-01

    The low-frequency vibrational property of L-phenylalanine (L-Phe) and L-phenylalanine monohydrate (L-Phe·H2O) has been investigated by terahertz time-domain spectroscopy (THz-TDS) at room and low temperature ranging from 0.5 to 4.5 THz. Distinctive THz absorption spectra of the two compounds were observed. Density functional theory (DFT) calculations based on the crystal structures have been performed to simulate the vibrational modes of L-Phe and L-Phe·H2O and the results agree well with the experimental observations. The study indicates that the characterized features of L-Phe mainly originate from the collective vibration of molecules. And the characterized features of L-Phe·H2O mainly come from hydrogen bond interactions between L-Phe and water molecules. L-Phe and L-Phe·H2O were also verified by differential scanning calorimetry and thermogravimetry (DSC-TG) and powder X-ray diffraction (PXRD) examinations.

  6. A comparison of in situ and airborne radar observations of ocean wave directionality

    NASA Technical Reports Server (NTRS)

    Jackson, F. C.; Walton, W. T.; Peng, C. Y.

    1985-01-01

    The directional spectrum of a fully arisen, about 3 m sea as measured by an experimental airborne radar, the NASA K(u)-band radar ocean wave spectrometer (ROWS), is compared to reference pitch-roll buoy data and to the classical SWOP (stereo wave observations project) spectrum for fully developed conditions. The ROWS spectrum, inferred indirectly from backscattered power measurements at 5-km altitude, is shown to be in excellent agreement with the buoy spectrum. Specifically, excellent agreement is found between the two nondirectional height spectra, and mean wave directions and directional spreads as functions of frequency. A comparison of the ROWS and SWOP spectra shows the two spectra to be very similar, in detailed shape as well as in terms of the gross spreading characteristics. Both spectra are seen to exhibit bimodal structures which accord with the Phillips' (1958) resonance mechanism. This observation is thus seen to support Phillips' contention that the SWOP modes were indeed resonance modes, not statistical artifacts.

  7. Raman spectra of solid benzene under high pressure

    NASA Technical Reports Server (NTRS)

    Thiery, M.-M.; Kobashi, K.; Spain, I. L.

    1985-01-01

    Raman spectra of solid benzene have been measured at room temperature up to about 140 kbar, using the diamond anvil cell. Effort has been focused upon the lattice vibration spectra at pressures above that of phase II. It is found that a change in slopes occurs in the frequency-pressure curves at about 40 kbar. Furthermore, a new band appears above 90 kbar. These features probably correspond respectively to the II-III phase transition, which has been reported previously, and a III-IV phase transition, reported here for the first time.

  8. Gravity-wave spectra in the atmosphere observed by MST radar, part 4.2B

    NASA Technical Reports Server (NTRS)

    Scheffler, A. O.; Liu, C. H.

    1984-01-01

    A universal spectrum of atmospheric buoyancy waves is proposed based on data from radiosonde, Doppler navigation, not-wire anemometer and Jimsphere balloon. The possible existence of such a universal spectrum clearly will have significant impact on several areas in the study of the middle atmosphere dynamics such as the parameterization of sub-grid scale gravity waves in global circulation models; the transport of trace constituents and heat in the middle atmosphere, etc. Therefore, it is important to examine more global wind data with temporal and spatial resolutions suitable for the investigation of the wave spectra. Mesosphere-stratosphere-troposphere (MST) radar observations offer an excellent opportunity for such studies. It is important to realize that radar measures the line-of-sight velocity which, in general, contains the combination of the vertical and horizontal components of the wave-associated particle velocity. Starting from a general oblique radar observation configuration, applying the dispersion relation for the gravity waves, the spectrum for the observed fluctuations in the line-of-sight gravity-wave spectrum is investigated through a filter function. The consequence of the filter function on data analysis is discussed.

  9. Observations of Turbulence in a Kelvin-Helmholtz Event on 8 September 2015 by the Magnetospheric Multiscale Mission

    NASA Technical Reports Server (NTRS)

    Stawarz, J. E.; Eriksson, S.; Wilder, F. D.; Ergun, R. E.; Schwartz, S. J.; Pouquet, A.; Burch, J. L.; Giles, B. L.; Khotyaintsev, Y.; Le Contel, O.; hide

    2016-01-01

    Spatial and high-time-resolution properties of the velocities, magnetic field, and 3-D electric field within plasma turbulence are examined observationally using data from the Magnetospheric Multiscale mission. Observations from a Kelvin-Helmholtz instability (KHI) on the Earth's magnetopause are examined, which both provides a series of repeatable intervals to analyze, giving better statistics, and provides a first look at the properties of turbulence in the KHI. For the first time direct observations of both the high-frequency ion and electron velocity spectra are examined, showing differing ion and electron behavior at kinetic scales. Temporal spectra exhibit power law behavior with changes in slope near the ion gyrofrequency and lower hybrid frequency. The work provides the first observational evidence for turbulent intermittency and anisotropy consistent with quasi two-dimensional turbulence in association with the KHI. The behavior of kinetic-scale intermittency is found to have differences from previous studies of solar wind turbulence, leading to novel insights on the turbulent dynamics in the KHI.

  10. The origin of high frequency radiation in earthquakes and the geometry of faulting

    NASA Astrophysics Data System (ADS)

    Madariaga, R.

    2004-12-01

    In a seminal paper of 1967 Kei Aki discovered the scaling law of earthquake spectra and showed that, among other things, the high frequency decay was of type omega-squared. This implies that high frequency displacement amplitudes are proportional to a characteristic length of the fault, and radiated energy scales with the cube of the fault dimension, just like seismic moment. Later in the seventies, it was found out that a simple explanation for this frequency dependence of spectra was that high frequencies were generated by stopping phases, waves emitted by changes in speed of the rupture front as it propagates along the fault, but this did not explain the scaling of high frequency waves with fault length. Earthquake energy balance is such that, ignoring attenuation, radiated energy is the change in strain energy minus energy released for overcoming friction. Until recently the latter was considered to be a material property that did not scale with fault size. Yet, in another classical paper Aki and Das estimated in the late 70s that energy release rate also scaled with earthquake size, because earthquakes were often stopped by barriers or changed rupture speed at them. This observation was independently confirmed in the late 90s by Ide and Takeo and Olsen et al who found that energy release rates for Kobe and Landers were in the order of a MJ/m2, implying that Gc necessarily scales with earthquake size, because if this was a material property, small earthquakes would never occur. Using both simple analytical and numerical models developed by Addia-Bedia and Aochi and Madariaga, we examine the consequence of these observations for the scaling of high frequency waves with fault size. We demonstrate using some classical results by Kostrov, Husseiny and Freund that high frequency energy flow measures energy release rate and is generated when ruptures change velocity (both direction and speed) at fault kinks or jogs. Our results explain why super shear ruptures are

  11. Search for and detection of pulsars inmonitoring observations at 111 MHz

    NASA Astrophysics Data System (ADS)

    Tyul'bashev, S. A.; Tyul'bashev, V. S.; Kitaeva, M. A.; Chernyshova, A. I.; Malofeev, V. M.; Chashei, I. V.; Shishov, V. I.; Dagkesamanskii, R. D.; Klimenko, S. V.; Nikitin, I. N.; Nikitina, L. D.

    2017-10-01

    In the course of monitoring interplanetary scintillations of a large number of sources using the Big Scanning Antenna of the Lebedev Physical Institute, a search for pulsars with periods ≥0.4 s at declinations -9◦ < δ < 42◦ and right ascensions 0h < α < 24h was simultaneously carried out. The search was conducted using four years of observations carried out at 110.25MHz in six frequency channels making up a 2.5 MHz band and having a time resolution of 100 ms. The initial identification of pulsar candidates was done using Fourier power spectra averaged over the entire observational period; the pulsar candidates were then verified using observations with higher frequency and time resolution: 32 frequency channels and a time resolution of 12.5 ms. Eighteen new pulsars were discovered in the studied area, whose main characteristics are presented.

  12. Rich magneto-absorption spectra of AAB-stacked trilayer graphene.

    PubMed

    Do, Thi-Nga; Shih, Po-Hsin; Chang, Cheng-Peng; Lin, Chiun-Yan; Lin, Ming-Fa

    2016-06-29

    A generalized tight-binding model is developed to investigate the feature-rich magneto-optical properties of AAB-stacked trilayer graphene. Three intragroup and six intergroup inter-Landau-level (inter-LL) optical excitations largely enrich magneto-absorption peaks. In general, the former are much higher than the latter, depending on the phases and amplitudes of LL wavefunctions. The absorption spectra exhibit single- or twin-peak structures which are determined by quantum modes, LL energy spectra and Fermion distribution. The splitting LLs, with different localization centers (2/6 and 4/6 positions in a unit cell), can generate very distinct absorption spectra. There exist extra single peaks because of LL anti-crossings. AAB, AAA, ABA, and ABC stackings considerably differ from one another in terms of the inter-LL category, frequency, intensity, and structure of absorption peaks. The main characteristics of LL wavefunctions and energy spectra and the Fermi-Dirac function are responsible for the configuration-enriched magneto-optical spectra.

  13. First light with Trident: multi-platform synthetic quasar spectra

    NASA Astrophysics Data System (ADS)

    Silvia, Devin W.; Hummels, Cameron B.; Smith, Britton

    2017-01-01

    Observational efforts to better understand the nature of the intergalactic and circumgalactic media have relied heavily on the information encoded in the absorption line systems of quasar spectra. Numerical simulations of large-scale structure and galaxy evolution are well-suited to explore the properties of those same media owing to the relative ease with which one can access physical quantities from complex, three-dimensional data. However, a difficulty arises when one tries to make direct “apple-to-apples” comparisons between observed spectra and simulated data. In an effort to provide a common language capable of linking theory and observation, we announce the release of Trident. Trident is a publicly available software tool that enables the creation of realistic synthetic absorption spectra from virtually all widely-used hydrodynamics simulation codes. Through user-controlled levels of spectral realism, direct comparisons between simulated and observed data become not only possible, but greatly simplified. We present the methods for extracting artificial quasar sightlines and generating spectra as well as early-stage applications of those spectra to intergalactic and circumgalactic absorption line studies.

  14. Computer-generated predictions of the structure and of the IR and Raman spectra of VX. Final report, May-August 1992

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hameka, H.F.; Jensen, J.O.

    1993-05-01

    This report presents the computed optimized geometry and vibrational IR and Raman frequencies of the V-agent VX. The computations are performed with the Gaussian 90 Program Package using 6-31G* basis sets. We assign the vibrational frequencies and correct each frequency by multiplying it with a previously derived 6-31G* correction factor. The result is a computer-generated prediction of the IR and Raman spectra of VX. This study was intended as a blind test of the utility of IR spectral prediction. Therefore, we intentionally did not look at experimental data on the IR and Raman spectra of VX.... IR Spectra, VX, Ramanmore » spectra, Computer predictions.« less

  15. Quantum Mechanical Calculations of Vibrational Sum-Frequency-Generation (SFG) Spectra of Cellulose: Dependence of the CH and OH Peak Intensity on the Polarity of Cellulose Chains within the SFG Coherence Domain.

    PubMed

    Lee, Christopher M; Chen, Xing; Weiss, Philip A; Jensen, Lasse; Kim, Seong H

    2017-01-05

    Vibrational sum-frequency-generation (SFG) spectroscopy is capable of selectively detecting crystalline biopolymers interspersed in amorphous polymer matrices. However, the spectral interpretation is difficult due to the lack of knowledge on how spatial arrangements of crystalline segments influence SFG spectra features. Here we report time-dependent density functional theory (TD-DFT) calculations of cellulose crystallites in intimate contact with two different polarities: parallel versus antiparallel. TD-DFT calculations reveal that the CH/OH intensity ratio is very sensitive to the polarity of the crystallite packing. Theoretical calculations of hyperpolarizability tensors (β abc ) clearly show the dependence of SFG intensities on the polarity of crystallite packing within the SFG coherence length, which provides the basis for interpretation of the empirically observed SFG features of native cellulose in biological systems.

  16. Substituent and solvent effects on electronic spectra of some substituted phenoxyacetic acids.

    PubMed

    Shanthi, M; Kabilan, S

    2007-06-01

    The effects of substituents and solvents have been studied through the absorption spectra of nearly 19 para- and ortho-substituted phenoxyacetic acids in the range of 200-400 nm. The effects of substituent on the absorption spectra of compounds under present investigation are interpreted by correlation of absorption frequencies with simple and extended Hammett equations. Effect of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of Kamlet equation and the results are discussed.

  17. Substituent and solvent effects on electronic spectra of some substituted phenoxyacetic acids

    NASA Astrophysics Data System (ADS)

    Shanthi, M.; Kabilan, S.

    2007-06-01

    The effects of substituents and solvents have been studied through the absorption spectra of nearly 19 para- and ortho-substituted phenoxyacetic acids in the range of 200-400 nm. The effects of substituent on the absorption spectra of compounds under present investigation are interpreted by correlation of absorption frequencies with simple and extended Hammett equations. Effect of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of Kamlet equation and the results are discussed.

  18. Observed Hierarchy of Student Proficiency with Period, Frequency, and Angular Frequency

    ERIC Educational Resources Information Center

    Young, Nicholas T.; Heckler, Andrew F.

    2018-01-01

    In the context of a generic harmonic oscillator, we investigated students' accuracy in determining the period, frequency, and angular frequency from mathematical and graphical representations. In a series of studies including interviews, free response tests, and multiple-choice tests developed in an iterative process, we assessed students in both…

  19. Spectra of Baroclinic Inertia-Gravity Wave Turbulence

    NASA Technical Reports Server (NTRS)

    Glazman, Roman E.

    1996-01-01

    Baroclinic inertia-gravity (IG) waves form a persistent background of thermocline depth and sea surface height oscillations. They also contribute to the kinetic energy of horizontal motions in the subsurface layer. Measured by the ratio of water particle velocity to wave phase speed, the wave nonlinearity may be rather high. Given a continuous supply of energy from external sources, nonlinear wave-wave interactions among IG waves would result in inertial cascades of energy, momentum, and wave action. Based on a recently developed theory of wave turbulence in scale-dependent systems, these cascades are investigated and IG wave spectra are derived for an arbitrary degree of wave nonlinearity. Comparisons with satellite-altimetry-based spectra of surface height variations and with energy spectra of horizontal velocity fluctuations show good agreement. The well-known spectral peak at the inertial frequency is thus explained as a result of the inverse cascade. Finally, we discuss a possibility of inferring the internal Rossby radius of deformation and other dynamical properties of the upper thermocline from the spectra of SSH (sea surface height) variations based on altimeter measurements.

  20. The RF spectra of first and subsequent lightning return strokes in the 1- to 200-km range

    NASA Technical Reports Server (NTRS)

    Serhan, G. I.; Uman, M. A.; Childers, D. G.; Lin, Y. T.

    1980-01-01

    An experimental characterization of the frequency spectra of first and subsequent stroke electric fields are presented over a distance range from about 1 km, where the fields are primarily electrostatic, to 200 km, where they are primarily radiation. Spectra are presented to about 700 kHz for lightning within 12 km and to about 300 kHz for lightning at 50 and 200 km. It is shown that the return stroke ground wave spectrum beyond 50 km has a peak near 4 kHz but that within 10 km the spectrum shows a steady increase with decreasing frequency to 1 kHz. Frequency spectra at all ranges fall off roughly as 1/f for frequencies between 5 and 100 kHz, while the falloff above 100 kHz is faster as the distance to the stroke increases. From this high-frequency attenuation an RF conductivity for central Florida of between 0.002 and 0.005/ohm/m was determined.

  1. Spectral Index and Quasi-Periodic Oscillation Frequency Correlation in Black Hole Sources: Observational Evidence of Two Phases and Phase Transition in Black Holes

    NASA Technical Reports Server (NTRS)

    Titarchuk, Lev; Fiorito, Ralph

    2004-01-01

    Recent studies have shown that strong correlations are observed between the low frequencies (1-10 Hz) of quasi-periodic oscillations (QPOs) and the spectral power law index of several black hole (BH) candidate sources, in low (hard) states, steep power law (soft) states, and transitions between these states. The observations indicate that the X-ray spectra of such state (phases) show the presence of a power-law component and are sometimes related to simultaneous radio emission, indicating the probable presence of a jet. Strong QPOs (>20% rms) are present in the power density spectrum in the spectral range where the power-law component is dominant (i.e., 60%90%). This evidence contradicts the dominant, long-standing interpretation of QPOs as a signature of the thermal accretion disk. We present the data from the literature and our own data to illustrate the dominance of power-law index-QPO frequency correlations. We provide a model that identifies and explains the origin of the QPOs and how they are imprinted on the properties of the power-law flux component. We argue for the existence of a bounded compact coronal region that is a natural consequence of the adjustment of the Keplerian disk flow to the innermost sub-Keplerian boundary conditions near the central object and that ultimately leads to the formation of a transition layer (TL) between the adjustment radius and the innermost boundary. The model predicts two phases or states dictated by the photon upscattering produced in the TL: (1) a hard state, in which the TL is optically thin and very hot (kT approximately greater than 50 keV), producing photon upscattering via thermal Comptonization (the photon spectrum index Gamma approximates 1.7 for this state is dictated by gravitational energy release and Compton cooling in an optically thin shock near the adjustment radius), and (2) a soft state that is optically thick and relatively cold (kT approximately less than 5 keV the index for this state, Gamma

  2. Microresonator Frequency Comb Optical Clock

    DTIC Science & Technology

    2014-07-22

    lithic construction with small size and power consumption. Microcomb development has included frequency control of their spectra [8–11...frequency f eo and amplified to a maximum of 140 mW. The first-order sideband powers are approximately 3 dB lower than the pump, and the piece of highly...resonator offers sufficient peak power for our experiments and is stable and repeatable even for different settings of pump frequency and power

  3. Geometry and Raman spectra of P.R. 255 and its furo-furanone analogue

    NASA Astrophysics Data System (ADS)

    Luňák, Stanislav, Jr.; Frumarová, Božena; Vyňuchal, Jan; Hrdina, Radim

    2009-05-01

    Fourier transform Raman spectra of two π-isoelectronic compounds 3,6-diphenyl-2,5-dihydro-pyrrolo-[3,4-c]pyrrole-1,4-dione (BPPB, C.I. Pigment Red 255) and 3,6-diphenyl-2,5-dihydro-furo-[3,4-c]furanone (BFFB) with the same 1,4-diphenyl-buta-1,3-diene (DPB) backbone were first time measured in polycrystalline phase. The ground state geometry and vibrational frequencies together with Raman intensities were computed by density functional theory (DFT: B3LYP/6-311G++(d,p)). All intensive observed Raman frequencies were identified as totally symmetric. The difference of carbon-carbon bond lengths of BPPB and BFFB compared to DPB, relating very well with the shifts of C dbnd C and C-C stretching modes frequencies, was explained by aromatization of central butadiene unit bounded in diketo-pyrrolo-pyrrole and furo-furanone heterocycles. A strong coupling of modes was observed for BFFB enhancing selectively the intensity of one peak 1593 cm -1 in C dbnd C stretching region and one peak 1372 cm -1 in C-C stretching region. C dbnd O stretching and N-H bending modes of BPPB are significantly affected by intermolecular hydrogen bonding.

  4. The mechanical spectra of β-relaxation and spontaneous densification effects in an amorphous polymer

    NASA Astrophysics Data System (ADS)

    Muzeau, Elisabeth; Johari, G. P.

    1990-12-01

    The dynamic mechanical spectra of shear modulus of poly(methyl methacrylate) have been measured at several temperatures over the frequency range 10 -4-1 Hz in order to study localized diffusion of chain segments which appears as β-relaxation. The shape of the spectra of both the real and imaginary components has been analyzed. It is described by a stretched exponential decay function with exponent of 0.18 and it shows nearly 50% change in the modulus over this frequency range. This exponent and the rate of relaxation are remarkably similar to those observed by dielectric methods. A procedure for obtaining the exponent of the decay function and the relaxation strength of the β-process has been outlined. The strength of the β-relaxation, or equivalently the number of molecular segments undergoing a thermally activated localized diffusion, decreases on structural relaxation during the isothermal ageing, and the magnitude of the modulus increases. Qualitatively speaking, these effects seem comparable to the effects of an increase in density that normally occurs with decrease in temperature or increase in pressure, and demonstrate that isothermal ageing causes collapse of "soft sites" in a rigid amorphous matrix.

  5. Chemical composition of matrix-embedded ternary II-VI nanocrystals derived from first- and second-order Raman spectra

    NASA Astrophysics Data System (ADS)

    Azhniuk, Yu. M.; Hutych, Yu. I.; Lopushansky, V. V.; Prymak, M. V.; Gomonnai, A. V.; Zahn, D. R. T.

    2016-12-01

    A one- and multiphonon Raman scattering study is performed for an extensive set of CdS1-xSex, Cd1-yZnyS, Cd1-yZnySe, and CdSe1-xTex nanocrystals to investigate the applicability of first- and second-order Raman spectra for the determination of the matrix-embedded ternary nanocrystal composition. For one-mode ternary systems both the LO and 2LO phonon frequencies in the Raman spectra are shown to be a good measure of the nanocrystal composition. For two-mode systems, the approaches based on the difference of the LO phonon frequencies (first-order Raman spectra) or double LO overtone and combination tone frequencies (second-order Raman spectra) as well as on the LO phonon band intensity ratios are analysed. The weak electron-phonon coupling in the II-VI nanocrystals and the polaron constant values for the nanocrystal sublattices are discussed.

  6. Electron energy-loss spectra in molecular fluorine

    NASA Technical Reports Server (NTRS)

    Nishimura, H.; Cartwright, D. C.; Trajmar, S.

    1979-01-01

    Electron energy-loss spectra in molecular fluorine, for energy losses from 0 to 17.0 eV, have been taken at incident electron energies of 30, 50, and 90 eV and scattering angles from 5 to 140 deg. Features in the spectra above 11.5 eV energy loss agree well with the assignments recently made from optical spectroscopy. Excitations of many of the eleven repulsive valence excited electronic states are observed and their location correlates reasonably well with recent theoretical results. Several of these excitations have been observed for the first time and four features, for which there are no identifications, appear in the spectra.

  7. Twin peak high-frequency quasi-periodic oscillations as a spectral imprint of dual oscillation modes of accretion tori

    NASA Astrophysics Data System (ADS)

    Bakala, P.; Goluchová, K.; Török, G.; Šrámková, E.; Abramowicz, M. A.; Vincent, F. H.; Mazur, G. P.

    2015-09-01

    Context. High-frequency (millisecond) quasi-periodic oscillations (HF QPOs) are observed in the X-ray power-density spectra of several microquasars and low-mass X-ray binaries. Two distinct QPO peaks, so-called twin peak QPOs, are often detected simultaneously exhibiting their frequency ratio close or equal to 3:2. A widely discussed class of proposed QPOs models is based on oscillations of accretion toroidal structures orbiting in the close vicinity of black holes or neutron stars. Aims: Following the analytic theory and previous studies of observable spectral signatures, we aim to model the twin peak QPOs as a spectral imprint of specific dual oscillation regime defined by a combination of the lowest radial and vertical oscillation mode of slender tori. We consider the model of an optically thick slender accretion torus with constant specific angular momentum. We examined power spectra and fluorescent Kα iron line profiles for two different simulation setups with the mode frequency relations corresponding to the epicyclic resonance HF QPOs model and modified relativistic precession QPOs model. Methods: We used relativistic ray-tracing implemented in the parallel simulation code LSDplus. In the background of the Kerr spacetime geometry, we analyzed the influence of the distant observer inclination and the spin of the central compact object. Relativistic optical projection of the oscillating slender torus is illustrated by images in false colours related to the frequency shift. Results: We show that performed simulations yield power spectra with the pair of dominant peaks that correspond to the frequencies of radial and vertical oscillation modes and with the peak frequency ratio equal to the proper value 3:2 on a wide range of inclinations and spin values. We also discuss exceptional cases of a very low and very high inclination, as well as unstable high spin relativistic precession-like configurations that predict a constant frequency ratio equal to 1:2. We

  8. Spectral-Temporal Evolution of Low-Frequency Pulsations in the Microwave Radiation of Solar Flares

    NASA Astrophysics Data System (ADS)

    Zaitsev, V. V.; Kislyakov, A. G.; Urpo, S.; Stepanov, A. V.; Shkelev, E. I.

    2003-10-01

    Low-frequency pulsations of 22 and 37 GHz microwave radiation detected during solar flares are analyzed. Several microwave bursts observed at the Metsähovi Radio Observatory are studied with time resolutions of 100 and 50 ms. A fast Fourier transformation with a sliding window and the Wigner-Ville method are used to obtain frequency-time diagrams for the low-frequency pulsations, which are interpreted as natural oscillations of coronal magnetic loops; the dynamical spectra of the pulsations are synthesized for the first time. Three types of low-frequency fluctuations modulating the flare microwave radiation can be distinguished in the observations. First, there are fast and slow magneto-acoustic oscillations with periods of 0.5 0.8 s and 200 280 s, respectively. The fast magneto-acoustic oscillations appear as trains of narrow-band signals with durations of 100 200 s, a positive frequency drift dν/dt=0.25 MHz/min, and frequency splitting δν=0.01 0.05 Hz. Second, there are natural oscillations of the coronal magnetic loops as equivalent electrical circuits. These oscillations have periods of 0.5 10 s and positive or negative frequency drift rates dν/dt=8×10-3 Hz/min or dν/dt=-1.3×10-2 Hz/min, depending on the phase of the radio outburst. Third, there are modulations of the microwave radiation by short periodic pulses with a period of 20 s. The dynamical spectra of the low-frequency pulsations supply important information about the parameters of the magnetic loops: the ratio of the loop radius to its length r/L≈0.1, the plasma parameter β≈10-3, the ratio of the plasma densities outside and inside the loop ρe/ρi≈10-2, and the electrical current flowing along the loop I≈1012 A.

  9. Energetic Proton Spectra Measured by the Van Allen Probes

    NASA Astrophysics Data System (ADS)

    Summers, Danny; Shi, Run; Engebretson, Mark J.; Oksavik, Kjellmar; Manweiler, Jerry W.; Mitchell, Donald G.

    2017-10-01

    We test the hypothesis that pitch angle scattering by electromagnetic ion cyclotron (EMIC) waves can limit ring current proton fluxes. For two chosen magnetic storms, during 17-20 March 2013 and 17-20 March 2015, we measure proton energy spectra in the region 3 ≤ L ≤ 6 using the RBSPICE-B instrument on the Van Allen Probes. The most intense proton spectra are observed to occur during the recovery periods of the respective storms. Using proton precipitation data from the POES (NOAA and MetOp) spacecraft, we deduce that EMIC wave action was prevalent at the times and L-shell locations of the most intense proton spectra. We calculate limiting ring current proton energy spectra from recently developed theory. Comparisons between the observed proton energy spectra and the theoretical limiting spectra show reasonable agreement. We conclude that the measurements of the most intense proton spectra are consistent with self-limiting by EMIC wave scattering.

  10. Amplification of anharmonicities in multiphoton vibrational action spectra.

    PubMed

    Calvo, F; Parneix, P

    2012-01-16

    The influence of one or several infrared laser pulses on the stability of bare and argon-tagged sodium chloride clusters is investigated theoretically by a combination of computational methods involving explicit molecular dynamics and properly calibrated unimolecular rate theories. The fragmentation spectra obtained by varying the laser frequency in the far-IR range is compared to the linear absorption spectrum resulting from the dipole moment autocorrelation function. Under appropriate laser field parameters, the action spectra are found to resemble the absorption spectra quite accurately in terms of positions, line widths, and even relative intensities. However, the action spectra exhibit residual and systematic redshifts of a few percent, which are partly due to the finite spectral bandwidth but are amplified by the progressive heating by the laser. A quantitative analysis suggests that these anharmonicity effects should generally arise upon multiple photon absorption. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. EMPCA and Cluster Analysis of Quasar Spectra: Construction and Application to Simulated Spectra

    NASA Astrophysics Data System (ADS)

    Marrs, Adam; Leighly, Karen; Wagner, Cassidy; Macinnis, Francis

    2017-01-01

    Quasars have complex spectra with emission lines influenced by many factors. Therefore, to fully describe the spectrum requires specification of a large number of parameters, such as line equivalent width, blueshift, and ratios. Principal Component Analysis (PCA) aims to construct eigenvectors-or principal components-from the data with the goal of finding a few key parameters that can be used to predict the rest of the spectrum fairly well. Analysis of simulated quasar spectra was used to verify and justify our modified application of PCA.We used a variant of PCA called Weighted Expectation Maximization PCA (EMPCA; Bailey 2012) along with k-means cluster analysis to analyze simulated quasar spectra. Our approach combines both analytical methods to address two known problems with classical PCA. EMPCA uses weights to account for uncertainty and missing points in the spectra. K-means groups similar spectra together to address the nonlinearity of quasar spectra, specifically variance in blueshifts and widths of the emission lines.In producing and analyzing simulations, we first tested the effects of varying equivalent widths and blueshifts on the derived principal components, and explored the differences between standard PCA and EMPCA. We also tested the effects of varying signal-to-noise ratio. Next we used the results of fits to composite quasar spectra (see accompanying poster by Wagner et al.) to construct a set of realistic simulated spectra, and subjected those spectra to the EMPCA /k-means analysis. We concluded that our approach was validated when we found that the mean spectra from our k-means clusters derived from PCA projection coefficients reproduced the trends observed in the composite spectra.Furthermore, our method needed only two eigenvectors to identify both sets of correlations used to construct the simulations, as well as indicating the linear and nonlinear segments. Comparing this to regular PCA, which can require a dozen or more components, or to

  12. Vibrational spectra of cyclopentadienyl chlorides of titanium, zirconium and hafnium. internal rotation and thermodynamic functions

    NASA Astrophysics Data System (ADS)

    Balducci, G.; Bencivenni, L.; De Rosa, G.; Gigli, R.; Martine, B.; Cesaro, S. Nunziante

    1980-05-01

    The infrared and Raman spectra of some cyclopentadienyl compounds of the transition metals, namely Ti(C 5H 5)Cl 3 and M(C 5H 5) 2Cl 2 (M = Ti, Zr and Hf), are reported and discussed. The infrared spectra of the gaseous species isolated in argon matrices at 10 K provide structural information about the single molecules. Particular attention has been paid to the low-frequency region in order to achieve more reliable assignments for the internal-rotation modes. The structural data and the fundamental frequencies derived from the spectra are employed in a calculation of the thermodynamic functions for these compounds in the ideal gas state.

  13. Study of polarized IR spectra of the hydrogen bond system in crystals of styrylacetic acid

    NASA Astrophysics Data System (ADS)

    Flakus, Henryk T.; Jabłońska, Magdalena; Jones, Peter G.

    2006-10-01

    We have investigated the polarized IR spectra of the hydrogen bond system in crystals of trans-styrylacetic acid C 6H 5sbnd CH dbnd CH sbnd CH 2sbnd COOH, and also in crystals of the following three deuterium isotopomers of the compound: C 6H 5sbnd CH dbnd CH sbnd CH 2sbnd COOD, C 6H 5sbnd CH dbnd CH sbnd CD 2sbnd COOH and C 6H 5sbnd CH dbnd CH sbnd CD 2sbnd COOD. The spectra were measured at room temperature and at 77 K by a transmission method. The spectral studies were preceded by determination of the X-ray crystal structure. Theoretical analysis of the results concerned linear dichroic effects, the H/D isotopic and temperature effects, observed in the solid-state IR spectra of the hydrogen and of the deuterium bond, at the frequency ranges of the νO sbnd H and the νO sbnd D bands, respectively. Basic spectral properties of the crystals can be interpreted satisfactorily in terms of the " strong-coupling" theory, when based on a hydrogen bond dimer model. This model sufficiently explained not only a two-branch structure of the νO sbnd H and the νO sbnd D bands, and temperature-induced evolution of the crystalline spectra, but also the linear dichroic effects observed in the band frequency ranges. A vibronic mechanism was analyzed, responsible for promotion of the symmetry-forbidden transition in the IR for the totally symmetric proton stretching vibrations in centrosymmetric hydrogen bond dimers. It was found to be of minor importance, when compared with analogous spectral properties of arylcarboxylic acid, or of cinnamic acid crystals. These effects were ascribed to a substantial weakening of electronic couplings between the hydrogen bonds of the associated carboxyl groups and the styryl radicals, associated with the separation of these groups in styrylacetic acid molecules by methylene groups in the molecules.

  14. Ab Initio Anharmonic Analysis of Vibrational Spectra of Uracil Using the Numerical-Analytic Implementation of Operator Van Vleck Perturbation Theory.

    PubMed

    Krasnoshchekov, Sergey V; Vogt, Natalja; Stepanov, Nikolay F

    2015-06-25

    The numerical-analytic implementation of the operator version of the canonical Van Vleck second-order vibrational perturbation theory (CVPT2) is employed for a purely ab initio prediction and interpretation of the infrared (IR) and Raman anharmonic spectra of a medium-size molecule of the diketo tautomer of uracil (2,4(1H,3H)-pyrimidinedione), which has high biological importance as one of the four RNA nucleobases. A nonempirical, semidiagonal quartic potential energy surface (PES) expressed in normal coordinates was evaluated at the MP2/cc-pVTZ level of theory. The quality of the PES was improved by replacing the harmonic frequencies with the "best" estimated CCSD(T)-based values taken from the literature. The theoretical method is enhanced by an accurate treatment of multiple Fermi and Darling-Dennison resonances with evaluation of the corresponding resonance constants W and K (CVPT2+WK method). A prediction of the anharmonic frequencies as well as IR and Raman intensities was used for a detailed interpretation of the experimental spectra of uracil. Very good agreement between predicted and observed vibrational frequencies has been achieved (RMSD ∼4.5 cm(-1)). The model employed gave a theoretically robust treatment of the multiple resonances in the 1680-1790 cm(-1) region. Our new analysis gives the most reliable reassignments of IR and Raman spectra of uracil available to date.

  15. Low-frequency waves at comet 67P/Churyumov-Gerasimenko. Observations compared to numerical simulations

    NASA Astrophysics Data System (ADS)

    Koenders, C.; Perschke, C.; Goetz, C.; Richter, I.; Motschmann, U.; Glassmeier, K. H.

    2016-10-01

    Context. A new type of low-frequency wave was detected by the magnetometer of the Rosetta Plasma Consortium at the comet during the initial months after the arrival of the Rosetta spacecraft at comet 67P/Churyumov-Gerasimenko. This large-amplitude, nearly continuous wave activity is observed in the frequency range from 30 mHz to 80 mHz where 40 mHz to 50 mHz is the dominant frequency. This type of low frequency is not closely related to the gyrofrequency of newborn cometary ions, which differs from previous wave activity observed in the interaction region of comets with the solar wind. Aims: This work aims to reveal a global view on the wave activity region using simulations of the comet-solar wind interaction region. Parameters, such as wavelength, propagation direction, and propagation patterns, are within the focus of this study. While the Rosetta observations only provide local information, numerical simulations provide further information on the global wave properties. Methods: Standard hybrid simulations were applied to the comet-solar wind interaction scenario. In the model, the ions were described as particles, which allows us to describe kinetic processes of the ions. The electrons were described as a fluid. Results: The simulations exhibit a threefold wave structure of the interaction region. A Mach cone and a Whistler wing are observed downstream of the comet. The third kind of wave activity found are low-frequency waves at 97 mHz, which corresponds to the waves observed by Richter et al. (2015, Ann. Geophys., 33, 1031). These waves are caused by the initial pick-up of the cometary ions that are perpendicular to the solar wind flow and in the interplanetary magnetic field direction. The associated electric current becomes unstable. The simulations show that wave activity is only detectable in the + E hemisphere and that the Mach cone and whistler wings need to be distinguished from the newly found instability driven wave activity. The movie associated to

  16. Spectra of M Asteroids V1.0

    NASA Astrophysics Data System (ADS)

    Fornasier, S.; Clark, B. E.; Migliorini, A.; Ockert-Bell, M.

    2011-08-01

    This data set contains reduced composite visual and near-infrared spectra of thirty M-type asteroids, observed over the years 2004-2008 and presented in Fornasier et al. (2010). The spectra were taken with the Dolores and NICS instruments at the Telescopio Nationale Galileo (TNG) in La Palma, with the EMMI and SOFI instruments at the ESO New Technology Telescope (NTT) in Chile, and with the SPeX instrument at the Infrared Telescope Facility (IRTF) in Hawaii. The individual spectra from the various instruments used to produce the composite spectra are also included.

  17. On the information content of natural frequency spectra associated with different angular numbers. [acoustic velocity in vibrating fluid sphere model of earth structure

    NASA Technical Reports Server (NTRS)

    Barcilon, V.

    1978-01-01

    The problem of inferring the speed of sound in a contained spherically symmetric fluid solely from its natural frequencies of vibration is considered. An investigation of the case in which the data consist of the two spectra associated with the angular numbers 0 and 1, suggests the possibility that a one-parameter family of slowness profiles can be constructed. These profiles are compatible with the data, up to first order in the non-uniformity of the fluid. It is conjectured that for other angular numbers, the loss of information increases as the difference between them increases.

  18. Blue spectra of Kalb-Ramond axions and fully anisotropic string cosmologies

    NASA Astrophysics Data System (ADS)

    Giovannini, Massimo

    1999-03-01

    The inhomogeneities associated with massless Kalb-Ramond axions can be amplified not only in isotropic (four-dimensional) string cosmological models but also in the fully anisotropic case. If the background geometry is isotropic, the axions (which are not part of the homogeneous background) develop outside the horizon, the growing modes leading, ultimately, to logarithmic energy spectra which are ``red'' in frequency and increase at large distance scales. We show that this conclusion can be avoided not only in the case of higher dimensional backgrounds with contracting internal dimensions but also in the case of string cosmological scenarios which are completely anisotropic in four dimensions. In this case the logarithmic energy spectra turn out to be ``blue'' in frequency and, consequently, decreasing at large distance scales. We elaborate on anisotropic dilaton-driven models and we argue that, incidentally, the background models leading to blue (or flat) logarithmic energy spectra for axionic fluctuations are likely to be isotropized by the effect of string tension corrections.

  19. Time-frequency analysis of transient signals - application to cardiovascular control

    NASA Astrophysics Data System (ADS)

    Keselbrener, Laurence; Akselrod, Solange

    A method for time-frequency decomposition (SDA) is presented for the analysis of cardiovascular signals, during steady state as well as under transient conditions. The SDA is applied to a simulated noisy non-stationary signal. It reliably discloses the time evolution of the different spectral components of the signal and does not present noise propagation as other time-frequency methods, such as Wigner-Ville distribution does. A comparison with the well-known short-time Fourier transform is also performed for non-stationary simulated signal showing that the SDA achieves a higher time-frequency resolution. Two physiological applications are then presented in which the SDA is used for the analysis of HR and BP variability, reflecting the activity of the autonomic nervous system. The power spectra of heart rate (HR) and blood pressure (BP) fluctuations during a change of posture from supine to standing are calculated. The decrease of vagal activity on standing is obvious and can be quantified from the spectrum of HR fluctuations. The increase in the LF fluctuations of both BP and HR spectra reflect the enhancement in sympathetic activity on standing. Finally, the power spectrum of fetal HR fluctuations is obtained by SDA. The respiratory peak is observed and can help in evaluating fetal well-being.

  20. A resonance phenomenon observed in a swept frequency experiment on a mother-daughter ionospheric rocket

    NASA Technical Reports Server (NTRS)

    Folkestad, K.; Troim, J.

    1974-01-01

    The report presents observations obtained in a swept frequency experiment conducted in a mother-daughter rocket flight at auroral latitudes. The discussion is essentially restricted to the possible interpretation of the experimental signal structures noted at and in the vicinity of a resonance frequency where signal components apparently are generated by nonlinear mechanisms. Various resonance frequencies have been considered in attempts to identify this multichannel response frequency. It is concluded that of all the possibilities invoked, the best consistency is provided by identifying the frequency concerned with the cone resonance frequency demonstrated experimentally in the case of a laboratory plasma by Fisher and Gould (1971).

  1. How Continuous Observations of Shortwave Reflectance Spectra Can Narrow the Range of Shortwave Climate Feedbacks

    NASA Astrophysics Data System (ADS)

    Feldman, D.; Collins, W. D.; Wielicki, B. A.; Shea, Y.; Mlynczak, M. G.; Kuo, C.; Nguyen, N.

    2017-12-01

    Shortwave feedbacks are a persistent source of uncertainty for climate models and a large contributor to the diagnosed range of equilibrium climate sensitivity (ECS) for the international multi-model ensemble. The processes that contribute to these feedbacks affect top-of-atmosphere energetics and produce spectral signatures that may be time-evolving. We explore the value of such spectral signatures for providing an observational constraint on model ECS by simulating top-of-atmosphere shortwave reflectance spectra across much of the energetically-relevant shortwave bandpass (300 to 2500 nm). We present centennial-length shortwave hyperspectral simulations from low, medium and high ECS models that reported to the CMIP5 archive as part of an Observing System Simulation Experiment (OSSE) in support of the CLimate Absolute Radiance and Refractivity Observatory (CLARREO). Our framework interfaces with CMIP5 archive results and is agnostic to the choice of model. We simulated spectra from the INM-CM4 model (ECS of 2.08 °K/2xCO2), the MIROC5 model (ECS of 2.70 °K/2xCO2), and the CSIRO Mk3-6-0 (ECS of 4.08 °K/2xCO2) based on those models' integrations of the RCP8.5 scenario for the 21st Century. This approach allows us to explore how perfect data records can exclude models of lower or higher climate sensitivity. We find that spectral channels covering visible and near-infrared water-vapor overtone bands can potentially exclude a low or high sensitivity model with under 15 years' of absolutely-calibrated data. These different spectral channels are sensitive to model cloud radiative effect and cloud height changes, respectively. These unprecedented calculations lay the groundwork for spectral simulations of perturbed-physics ensembles in order to identify those shortwave observations that can help narrow the range in shortwave model feedbacks and ultimately help reduce the stubbornly-large range in model ECS.

  2. Wave mode identification of electrostatic noise observed with ISEE 3 in the deep tail boundary layer

    NASA Technical Reports Server (NTRS)

    Tsutsui, M.; Matsumoto, H.; Strangeway, R. J.; Tsurutani, B. T.; Phillips, J. L.

    1991-01-01

    The characteristics of the VLF electrostatic noise observed with ISEE 3 in the low-latitude boundary layer of distant geomagnetic tail are examined using a display format for the wave dynamic spectra different from that used by Scarf et al. (1984). It is shown that the observed noise is composed of impulsive bursts. The results of the detailed analysis of the noise parameters are used to develop a model of plasma wave behavior in the plasma rest frame. A hypothesis is proposed that the wide frequency extent of the noise spectra is composed of Doppler effects of waves propagating nearly omnidirectionally within the plasma rest frame, which is moving with the electron bulk speed. On the basis of this hypothesis, the wavelength of the observed waves were determined from the width of the frequency extent and the measured electron bulk speed. It is shown that the wavelength ranges from 2 to 8 times the plasma Debye length.

  3. Mid-infrared frequency comb generation via cascaded quadratic nonlinearities in quasi-phase-matched waveguides

    NASA Astrophysics Data System (ADS)

    Kowligy, Abijith S.; Lind, Alex; Hickstein, Daniel D.; Carlson, David R.; Timmers, Henry; Nader, Nima; Cruz, Flavio C.; Ycas, Gabriel; Papp, Scott B.; Diddams, Scott A.

    2018-04-01

    We experimentally demonstrate a simple configuration for mid-infrared (MIR) frequency comb generation in quasi-phase-matched lithium niobate waveguides using the cascaded-$\\chi^{(2)}$ nonlinearity. With nanojoule-scale pulses from an Er:fiber laser, we observe octave-spanning supercontinuum in the near-infrared with dispersive-wave generation in the 2.5--3 $\\text{\\mu}$m region and intra-pulse difference-frequency generation in the 4--5 $\\text{\\mu}$m region. By engineering the quasi-phase-matched grating profiles, tunable, narrow-band MIR and broadband MIR spectra are both observed in this geometry. Finally, we perform numerical modeling using a nonlinear envelope equation, which shows good quantitative agreement with the experiment---and can be used to inform waveguide designs to tailor the MIR frequency combs. Our results identify a path to a simple single-branch approach to mid-infrared frequency comb generation in a compact platform using commercial Er:fiber technology.

  4. Mid-infrared frequency comb generation via cascaded quadratic nonlinearities in quasi-phase-matched waveguides.

    PubMed

    Kowligy, Abijith S; Lind, Alex; Hickstein, Daniel D; Carlson, David R; Timmers, Henry; Nader, Nima; Cruz, Flavio C; Ycas, Gabriel; Papp, Scott B; Diddams, Scott A

    2018-04-15

    We experimentally demonstrate a simple configuration for mid-infrared (MIR) frequency comb generation in quasi-phase-matched lithium niobate waveguides using the cascaded-χ (2) nonlinearity. With nanojoule-scale pulses from an Er:fiber laser, we observe octave-spanning supercontinuum in the near-infrared with dispersive wave generation in the 2.5-3 μm region and intrapulse difference frequency generation in the 4-5 μm region. By engineering the quasi-phase-matched grating profiles, tunable, narrowband MIR and broadband MIR spectra are both observed in this geometry. Finally, we perform numerical modeling using a nonlinear envelope equation, which shows good quantitative agreement with the experiment-and can be used to inform waveguide designs to tailor the MIR frequency combs. Our results identify a path to a simple single-branch approach to mid-infrared frequency comb generation in a compact platform using commercial Er:fiber technology.

  5. Ground Radar Polarimetric Observations of High-Frequency Earth-Space Communication Links

    NASA Technical Reports Server (NTRS)

    Bolen, Steve; Chandrasekar, V.; Benjamin, Andrew

    2002-01-01

    Strategic roadmaps for NASA's Human Exploration and Development of Space (REDS) enterprise support near-term high-frequency communication systems that provide moderate to high data rates with dependable service. Near-earth and human planetary exploration will baseline Ka-Band, but may ultimately require the use of even higher frequencies. Increased commercial demand on low-frequency earth-space bands has also led to increased interest in the use of higher frequencies in regions like K u - and K,- band. Data is taken from the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR), which operates at 13.8 GHz, and the true radar reflectivity profile is determined along the PR beam via low-frequency ground based polarimetric observations. The specific differential phase (Kdp) is measured along the beam and a theoretical model is used to determine the expected specific attenuation (k). This technique, called the k-Kdp method, uses a Fuzzy-Logic model to determine the hydrometeor type along the PR beam from which the appropriate k-Kdp relationship is used to determine k and, ultimately, the total path-integrated attenuation (PIA) on PR measurements. Measurements from PR and the NCAR S-POL radar were made during the TEFLUN-B experiment that took place near Melbourne, FL in 1998, and the TRMM-LBA campaign near Ji-Parana, Brazil in 1999.

  6. SCINTILLATION ARCS IN LOW-FREQUENCY OBSERVATIONS OF THE TIMING-ARRAY MILLISECOND PULSAR PSR J0437–4715

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bhat, N. D. R.; Ord, S. M.; Tremblay, S. E.

    2016-02-10

    Low-frequency observations of pulsars provide a powerful means for probing the microstructure in the turbulent interstellar medium (ISM). Here we report on high-resolution dynamic spectral analysis of our observations of the timing-array millisecond pulsar PSR J0437–4715 with the Murchison Widefield Array (MWA), enabled by our recently commissioned tied-array beam processing pipeline for voltage data recorded from the high time resolution mode of the MWA. A secondary spectral analysis reveals faint parabolic arcs akin to those seen in high-frequency observations of pulsars with the Green Bank and Arecibo telescopes. Data from Parkes observations at a higher frequency of 732 MHz revealmore » a similar parabolic feature with a curvature that scales approximately as the square of the observing wavelength (λ{sup 2}) to the MWA's frequency of 192 MHz. Our analysis suggests that scattering toward PSR J0437–4715 predominantly arises from a compact region about 115 pc from the Earth, which matches well with the expected location of the edge of the Local Bubble that envelopes the local Solar neighborhood. As well as demonstrating new and improved pulsar science capabilities of the MWA, our analysis underscores the potential of low-frequency pulsar observations for gaining valuable insights into the local ISM and for characterizing the ISM toward timing-array pulsars.« less

  7. On the modulation of low-frequency quasi-periodic oscillations in black hole transients

    NASA Astrophysics Data System (ADS)

    Pawar, Devraj D.; Motta, Sara; Shanthi, K.; Bhattacharya, Dipankar; Belloni, Tomaso

    2015-04-01

    We studied the properties of the low-frequency quasi-periodic oscillations detected in a sample of six black hole candidates (XTE J1550-564, H 1743-322, XTE J1859+226, 4U 1630-47, GX 339-4, XTE J1650-500) observed by the Rossi XTE satellite. We analysed the relation between the full width at half-maximum and the frequency of all the narrow peaks detected in power density spectra where a type-C QPO is observed. Our goal was to understand the nature of the modulation of the signal by comparing the properties of different harmonic peaks in the power density spectrum. We find that for the sources in our sample the width of the fundamental and of the first harmonic are compatible with a frequency modulation, while that of the sub-harmonic is independent of frequency, possibly indicating the presence of an additional modulation in amplitude. We compare our results with those obtained earlier from GRS 1915+105 and XTE J1550-564.

  8. Observations of volcanic tremor during January-February 2005 eruption of Mt. Veniaminof, Alaska

    USGS Publications Warehouse

    De Angelis, Slivio; McNutt, Stephen R.

    2007-01-01

    Mt. Veniaminof, Alaska Peninsula, is a stratovolcano with a summit ice-filled caldera containing a small intracaldera cone and active vent. From January 2 to February 21, 2005, Mt. Veniaminof erupted. The eruption was characterized by numerous small ash emissions (VEI 0 to 1) and accompanied by low-frequency earthquake activity and volcanic tremor. We have performed spectral analyses of the seismic signals in order to characterize them and to constrain their source. Continuous tremor has durations of minutes to hours with dominant energy in the band 0.5– 4.0 Hz, and spectra characterized by narrow peaks either irregularly (non-harmonic tremor) or regularly spaced (harmonic tremor). The spectra of non-harmonic tremor resemble those of low-frequency events recorded simultaneously with surface ash explosions, suggesting that the source mechanisms might be similar or related. We propose that non-harmonic tremor at Mt. Veniaminof results from the coalescence of gas bubbles while low-frequency events are related to the disruption of large gas pockets within the conduit. Harmonic tremor, characterized by regular and quasisinusoidal waveforms, has duration of hours. Spectra containing up to five harmonics suggest the presence of a resonating source volume that vibrates in a longitudinal acoustic mode. An interesting feature of harmonic tremor is that frequency is observed to change over time; spectral lines move towards higher or lower values while the harmonic nature of the spectra is maintained. Factors controlling the variable characteristics of harmonic tremor include changes in acoustic velocity at the source and variations of the effective size of the resonator.

  9. Multiple-Station Observation of Frequency Dependence and Polarization Characteristics of ELF/VLF waves generated via Ionospheric Modification

    NASA Astrophysics Data System (ADS)

    Maxworth, A. S.; Golkowski, M.; Cohen, M.; Moore, R. C.

    2014-12-01

    Generation of Extremely Low Frequency (ELF) and Very Low Frequency (VLF) signals through ionospheric modification has been practiced for many years. Heating the lower ionosphere with high power HF waves allows for modulation of natural current systems. Our experiments were carried out at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska, USA. In this experiment, the ionosphere was heated with a vertical amplitude modulating signal and the modulation frequency was changed sequentially within an array of 40 frequencies followed by a frequency ramp. The observed magnetic field amplitude and polarization of the generated ELF/VLF signals were analyzed for multiple sites and as a function of modulation frequency. Our three observation sites: Chistochina, Paxson and Paradise are located within 36km (azimuth 47.7°), 50.2km (azimuth -20°) and 99km (azimuth 80.3°) respectively. We show that the peak amplitudes observed as a function of frequency result from vertical resonance in the Earth-ionosphere waveguide and can be used to diagnose the D-region profile. Polarization analysis showed that out of the three sites Paxson shows the highest circularity in the magnetic field polarization, compared to Chistochina and Paradise which show highly linear polarizations. The experimental results were compared with a theoretical simulation model results and it was clear that in both cases, the modulated Hall current dominates the observed signals at Chistochina and Paradise sites and at Paxson there is an equal contribution from Hall and Pedersen currents. The Chistochina site shows the highest magnetic field amplitudes in both experimental and simulation environments. Depending upon the experimental and simulation observations at the three sites, a radiation pattern for the HAARP ionospheric heater can be mapped

  10. Fluctuation spectra in the NASA Lewis bumpy-torus plasma

    NASA Technical Reports Server (NTRS)

    Singh, C. M.; Krawczonek, W. M.; Roth, J. R.; Hong, J. Y.; Powers, E. J.

    1978-01-01

    The electrostatic potential fluctuation spectrum in the NASA Lewis bumpy-torus plasma was studied with capacitive probes in the low pressure (high impedance) mode and in the high pressure (low impedance) mode. Under different operating conditions, the plasma exhibited electrostatic potential fluctuations (1) at a set of discrete frequencies, (2) at a continuum of frequencies, and (3) as incoherent high-frequency turbulence. The frequencies and azimuthal wave numbers were determined from digitally implemented autopower and cross-power spectra. The azimuthal dispersion characteristics of the unstable waves were examined by varying the electrode voltage, the polarity of the voltage, and the neutral background density at a constant magnetic field strength.

  11. Cosmic ray proton spectra at low rigidities

    NASA Technical Reports Server (NTRS)

    Seo, E. S.; Ormes, J. F.; Streitmatter, R. E.; Lloyd-Evans, J.; Jones, W. V.

    1990-01-01

    The cosmic ray proton rigidity spectra have been investigated with data collected in the Low Energy Antiproton (LEAP) balloon flight experiment flown from Prince Albert, Canada in 1987. The LEAP apparatus was designed to measure antiprotons using a superconducting magnet spectrometer with ancillary scintillator, time-of-flight, and liquid Cherenkov detectors. After reaching float altitude the balloon drifted south and west to higher geomagnetic cutoffs. The effect of the changing geomagnetic cutoff on the observed spectra was observed during analysis of the proton data along the balloon trajectory. This is the first measurement of the primary and splash albedo spectra over a wide rigidity range (few hundred MV to about 100 GV) with a single instrument.

  12. Tissue specific resonance frequencies of water and metabolites within the human brain

    NASA Astrophysics Data System (ADS)

    Chadzynski, Grzegorz L.; Bender, Benjamin; Groeger, Adriane; Erb, Michael; Klose, Uwe

    2011-09-01

    Chemical shift imaging (CSI) without water suppression was used to examine tissue-specific resonance frequencies of water and metabolites within the human brain. The aim was to verify if there are any regional differences in those frequencies and to determine the influence of chemical shift displacement in slice-selection direction. Unsuppressed spectra were acquired at 3 T from nine subjects. Resonance frequencies of water and after water signal removal of total choline, total creatine and NAA were estimated. Furthermore, frequency distances between the water and those resonances were calculated. Results were corrected for chemical shift displacement. Frequency distances between water and metabolites were consistent and greater for GM than for WM. The highest value of WM to GM difference (14 ppb) was observed for water to NAA frequency distance. This study demonstrates that there are tissue-specific differences between frequency distances of water and metabolites. Moreover, the influence of chemical shift displacement in slice-selection direction is showed to be negligible.

  13. Regular frequency patterns in the young δ Scuti star HD 261711 observed by the CoRoT and MOST satellites

    NASA Astrophysics Data System (ADS)

    Zwintz, K.; Fossati, L.; Guenther, D. B.; Ryabchikova, T.; Baglin, A.; Themessl, N.; Barnes, T. G.; Matthews, J. M.; Auvergne, M.; Bohlender, D.; Chaintreuil, S.; Kuschnig, R.; Moffat, A. F. J.; Rowe, J. F.; Rucinski, S. M.; Sasselov, D.; Weiss, W. W.

    2013-04-01

    . Conclusions: Our asteroseismic models suggest that HD 261711 is a δ Scuti-type star close to the zero-age main sequence (ZAMS) with a mass of 1.8 to 1.9 M⊙. With an age of about 10 million years derived from asteroseismology, the star is either a young ZAMS star or a late PMS star just before the onset of hydrogen-core burning. The observed splittings about the l = 0 and 1 parent modes may be an artifact of the Fourier derived spectrum of frequencies with varying amplitudes. The CoRoT space mission was developed and is operated by the French space agency CNES, with participation of ESA's RSSD and Science Programmes, Austria, Belgium, Brazil, Germany, and Spain.Based on data from the MOST satellite, a Canadian Space Agency mission, jointly operated by Microsatellite Systems Canada Inc. (MSCI), formerly part of Dynacon, Inc., the University of Toronto Institute for Aerospace Studies and the University of British Columbia with the assistance of the University of Vienna.Reduced spectra are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/552/A68

  14. Low frequency noise peak near magnon emission energy in magnetic tunnel junctions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Liang; Xiang, Li; Guo, Huiqiang

    2014-12-15

    We report on the low frequency (LF) noise measurements in magnetic tunnel junctions (MTJs) below 4 K and at low bias, where the transport is strongly affected by scattering with magnons emitted by hot tunnelling electrons, as thermal activation of magnons from the environment is suppressed. For both CoFeB/MgO/CoFeB and CoFeB/AlO{sub x}/CoFeB MTJs, enhanced LF noise is observed at bias voltage around magnon emission energy, forming a peak in the bias dependence of noise power spectra density, independent of magnetic configurations. The noise peak is much higher and broader for unannealed AlO{sub x}-based MTJ, and besides Lorentzian shape noise spectramore » in the frequency domain, random telegraph noise (RTN) is visible in the time traces. During repeated measurements the noise peak reduces and the RTN becomes difficult to resolve, suggesting defects being annealed. The Lorentzian shape noise spectra can be fitted with bias-dependent activation of RTN, with the attempt frequency in the MHz range, consistent with magnon dynamics. These findings suggest magnon-assisted activation of defects as the origin of the enhanced LF noise.« less

  15. Natural Frequencies Evaluation on Partially Damaged Building using Ambient Vibration Technique

    NASA Astrophysics Data System (ADS)

    Kamarudin, A. F.; Zainal Abidin, M. H.; Daud, M. E.; Noh, M. S. Md; Madun, A.; Ibrahim, A.; Matarul, J.; Mokhatar, S. N.

    2018-04-01

    Severe damages observed on the school blocks, roads, retaining walls and drainage within the compound of SMK Kundasang Sabah possibly due to the ground movements triggered by the Ranau earthquake in 1991. Ambient vibration measurements were carried on the remaining demolished 3-storey building which partially damaged in order to measure the predominant building frequencies using tri-axial 1 Hz seismometer sensors. Popular methods of Horizontal-to-vertical spectral ratios (HVSR) and Fourier amplitude spectra (FAS) were used to compute the ambient vibration wave fields of each building axes (Transverse or North-South (NS), Longitudinal or East-West (EW) and vertical) into Fourier spectra. Two main modes of translation and torsion were observed from the peaks frequencies obtained at 2.99 to 3.10 Hz (1st mode), 4.85 Hz (2nd mode) and 5.63 to 5.85 Hz (3rd mode). The building experiencing translation modes of bending and shear in the NS and EW directions. It could be seen when the amplitudes tends to increase when the floor are increased. Meanwhile, the torsional bending mode is expected to occur when the deformation amplitudes are found to be increasing horizontally, when moving into partially structural damaged section located on the East wing of building.

  16. OSO 8 X-ray spectra of clusters of galaxies. I - Observations of twenty clusters: Physical correlations

    NASA Technical Reports Server (NTRS)

    Mushotzky, R. F.; Serlemitsos, P. J.; Boldt, E. A.; Holt, S. S.; Smith, B. W.

    1978-01-01

    OSO 8 X-ray spectra from 2 to 20 keV have been analyzed for 26 clusters of galaxies. For 20 clusters temperatures, emission integrals, iron abundances, and low-energy absorption measurements are presented. The data give, in general, better fits to thermal bremsstrahlung than to power-law models. Eight clusters have positive iron emission-line detections at the 90% confidence level, and all 20 cluster spectra are consistent with Fe/H = 0.000014 by number with the possible exception of Virgo. Thus it is confirmed that X-ray emission in this energy band is predominantly thermal radiation from hot intracluster gas rather than inverse Compton radiation. Physical correlations between X-ray spectral parameters and other cluster properties are examined. It is found that (1) the X-ray temperature is approximately proportional to the square of the velocity dispersion of the galaxies; (2) the emission integral is a strong function of the X-ray temperature; (3) the X-ray temperature and emission integral are better correlated with cluster central-galaxy density than with richness; and (4) the fraction of galaxies which are spirals is correlated with the observed ram pressure in the cluster core.

  17. The anharmonic quartic force field infrared spectra of five non-linear polycyclic aromatic hydrocarbons: Benz[a]anthracene, chrysene, phenanthrene, pyrene, and triphenylene

    NASA Astrophysics Data System (ADS)

    Mackie, Cameron J.; Candian, Alessandra; Huang, Xinchuan; Maltseva, Elena; Petrignani, Annemieke; Oomens, Jos; Mattioda, Andrew L.; Buma, Wybren Jan; Lee, Timothy J.; Tielens, Alexander G. G. M.

    2016-08-01

    The study of interstellar polycyclic aromatic hydrocarbons (PAHs) relies heavily on theoretically predicted infrared spectra. Most earlier studies use scaled harmonic frequencies for band positions and the double harmonic approximation for intensities. However, recent high-resolution gas-phase experimental spectroscopic studies have shown that the harmonic approximation is not sufficient to reproduce experimental results. In our previous work, we presented the anharmonic theoretical spectra of three linear PAHs, showing the importance of including anharmonicities into the theoretical calculations. In this paper, we continue this work by extending the study to include five non-linear PAHs (benz[a]anthracene, chrysene, phenanthrene, pyrene, and triphenylene), thereby allowing us to make a full assessment of how edge structure, symmetry, and size influence the effects of anharmonicities. The theoretical anharmonic spectra are compared to spectra obtained under matrix isolation low-temperature conditions, low-resolution, high-temperature gas-phase conditions, and high-resolution, low-temperature gas-phase conditions. Overall, excellent agreement is observed between the theoretical and experimental spectra although the experimental spectra show subtle but significant differences.

  18. The anharmonic quartic force field infrared spectra of five non-linear polycyclic aromatic hydrocarbons: Benz[a]anthracene, chrysene, phenanthrene, pyrene, and triphenylene.

    PubMed

    Mackie, Cameron J; Candian, Alessandra; Huang, Xinchuan; Maltseva, Elena; Petrignani, Annemieke; Oomens, Jos; Mattioda, Andrew L; Buma, Wybren Jan; Lee, Timothy J; Tielens, Alexander G G M

    2016-08-28

    The study of interstellar polycyclic aromatic hydrocarbons (PAHs) relies heavily on theoretically predicted infrared spectra. Most earlier studies use scaled harmonic frequencies for band positions and the double harmonic approximation for intensities. However, recent high-resolution gas-phase experimental spectroscopic studies have shown that the harmonic approximation is not sufficient to reproduce experimental results. In our previous work, we presented the anharmonic theoretical spectra of three linear PAHs, showing the importance of including anharmonicities into the theoretical calculations. In this paper, we continue this work by extending the study to include five non-linear PAHs (benz[a]anthracene, chrysene, phenanthrene, pyrene, and triphenylene), thereby allowing us to make a full assessment of how edge structure, symmetry, and size influence the effects of anharmonicities. The theoretical anharmonic spectra are compared to spectra obtained under matrix isolation low-temperature conditions, low-resolution, high-temperature gas-phase conditions, and high-resolution, low-temperature gas-phase conditions. Overall, excellent agreement is observed between the theoretical and experimental spectra although the experimental spectra show subtle but significant differences.

  19. Planck early results. XV. Spectral energy distributions and radio continuum spectra of northern extragalactic radio sources

    DOE PAGES

    Aatrokoski, J.

    2011-12-01

    Spectral energy distributions (SEDs) and radio continuum spectra are presented for a northern sample of 104 extragalactic radio sources, based on the Planck Early Release Compact Source Catalogue (ERCSC) and simultaneous multifrequency data. The nine Planck frequencies, from 30 to 857GHz, are complemented by a set of simultaneous observations ranging from radio to gamma-rays. This is the first extensive frequency coverage in the radio and millimetre domains for an essentially complete sample of extragalactic radio sources, and it shows how the individual shocks, each in their own phase of development, shape the radio spectra as they move in the relativisticmore » jet. The SEDs presented in this paper were fitted with second and third degree polynomials to estimate the frequencies of the synchrotron and inverse Compton (IC) peaks, and the spectral indices of low and high frequency radio data, including the Planck ERCSC data, were calculated. SED modelling methods are discussed, with an emphasis on proper, physical modelling of the synchrotron bump using multiple components. Planck ERCSC data also suggest that the original accelerated electron energy spectrum could be much harder than commonly thought, with power-law index around 1.5 instead of the canonical 2.5. The implications of this are discussed for the acceleration mechanisms effective in blazar shock. Furthermore in many cases the Planck data indicate that gamma-ray emission must originate in the same shocks that produce the radio emission.« less

  20. Experiments with Lasers and Frequency Doublers

    NASA Technical Reports Server (NTRS)

    Bachor, H.-A.; Taubman, M.; White, A. G.; Ralph, T.; McClelland, D. E.

    1996-01-01

    Solid state laser sources, such as diode-pumped Nd:YAG lasers, have given us CW laser light of high power with unprecedented stability and low noise performance. In these lasers most of the technical sources of noise can be eliminated allowing them to be operated close to the theoretical noise limit set by the quantum properties of light. The next step of reducing the noise below the standard limit is known as squeezing. We present experimental progress in generating reliably squeezed light using the process of frequency doubling. We emphasize the long term stability that makes this a truly practical source of squeezed light. Our experimental results match noise spectra calculated with our recently developed models of coupled systems which include the noise generated inside the laser and its interaction with the frequency doubler. We conclude with some observations on evaluating quadrature squeezed states of light.

  1. Infrared Spectra of Hydrated Magnesium Salts and their Role in the Search for Possible Life Conditions on Jupiter Moons

    NASA Technical Reports Server (NTRS)

    Chaban, Galina; Huo, Winifred M.; Lee, Timothy J.; Kwak, Dochan (Technical Monitor)

    2002-01-01

    Recent observations from the Galileo satellite indicate that three of the Jupiter moons, Europa, Ganymede, and Callisto, may have subsurface oceans. Possible existence of such ocean and the nature of its composition are of great interest to astrobiologists. Data from Galileo's NIMS spectrometer indicate the possibility of hydrated salts on Europa's surface. To aid in the design of future missions, we investigated infrared spectra of MgSO4-nH20, n=1-3 using ab initio calculations. Geometry, energetics, dipole moments, vibrational frequencies and infrared intensities of pure and hydrated MgSO4 salts were determined. Significant differences are found between vibrational spectra of water molecules in complexes with MgSO4 and pure water. Some of the O-H stretching frequencies in the complexes are shifted to the red by up to 1,500 - 2,000 per cm. In addition, the SO2 stretching vibrations are found at lower frequency regions than the water vibrations. The calculated bands of water and SO2 fragments can serve as markers for the existence of the salt-water complexes on the surface of Jupiter's moon.

  2. First Season QUIET Observations: Measurements of CMB Polarization Power Spectra at 43 GHz in the Multipole Range 25 <= ell <= 475

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bischoff, C.; /Chicago U., EFI /Harvard-Smithsonian Ctr. Astrophys.; Brizius, A.

    2010-12-01

    The Q/U Imaging ExperimenT (QUIET) employs coherent receivers at 43GHz and 95GHz, operating on the Chajnantor plateau in the Atacama Desert in Chile, to measure the anisotropy in the polarization of the CMB. QUIET primarily targets the B modes from primordial gravitational waves. The combination of these frequencies gives sensitivity to foreground contributions from diffuse Galactic synchrotron radiation. Between 2008 October and 2010 December, over 10,000 hours of data were collected, first with the 19-element 43-GHz array (3458 hours) and then with the 90-element 95-GHz array. Each array observes the same four fields, selected for low foregrounds, together covering {approx}more » 1000 square degrees. This paper reports initial results from the 43-GHz receiver which has an array sensitivity to CMB fluctuations of 69 {mu}K{radical}s. The data were extensively studied with a large suite of null tests before the power spectra, determined with two independent pipelines, were examined. Analysis choices, including data selection, were modified until the null tests passed. Cross correlating maps with different telescope pointings is used to eliminate a bias. This paper reports the EE, BB, and EB power spectra in the multipole range {ell} = 25-475. With the exception of the lowest multipole bin for one of the fields, where a polarized foreground, consistent with Galactic synchrotron radiation, is detected with 3-{sigma} significance, the E-mode spectrum is consistent with the {Lambda}CDM model, confirming the only previous detection of the first acoustic peak. The B-mode spectrum is consistent with zero, leading to a measurement of the tensor-to-scalar ratio of r = 0.35{sub -0.87}{sup +1.06}. The combination of a new time-stream 'double-demodulation' technique, Mizuguchi-Dragone optics, natural sky rotation, and frequent boresight rotation leads to the lowest level of systematic contamination in the B-mode power so far reported, below the level of r = 0.1.« less

  3. Spectra Handling from AIRS and IRIS for Climate Change Research

    NASA Astrophysics Data System (ADS)

    Jiang, Y.; Lau, M.; Aumann, H. H.; Yung, Y. L.

    2010-12-01

    Outgoing longwave radiation (OLR) measurements over a long period from satellites provide valuable information for the climate change research. Due to the different coverage, spectral resolution and instrument sensitivities, the data comparisons between different satellites could be problematic and possible artifacts could be easily introduced. In this paper, we have analyzed the data taken by IRIS in 1970 and by AIRS from 2002 to 2010. IRIS (Prabhakara, 1988) was a Fourier transform spectrometer (FTS) and it flew on the NASA Nimbus 4 satellite which was launched in April 1970 into an 1100km altitude sun-synchronous polar orbit. It collected data from the nadir track between 400cm-1 and 1600 cm-1 from April 1970 until January 1971. AIRS (Aumann, 2003) is a grating spectrometer launched on the EOS-Aqua satellite in May 2002 and it measures spectra from 650cm-1 to 2700cm-1. AIRS scans to ±49.5o cross track as the satellite moves forwards taking 90 spectra each with an instantaneous field of view of 1.1o in a row perpendicular to the direction of motion of the satellite. This results in a ground footprint of 13km diameter at nadir. In this paper, we analyzed the spectra between 650 cm-1 and 1350 cm-1 for nadir view footprints in order to match the IRIS’s measurements. Most of the possible sources of error or biases have been carefully handled, these include the errors from the data editing, spatial coverage, missing data (spatial gap), and spectral resolution, spectra frequency shift due to the fields of view, sea surface temperature fluctuations, clear sky determination, and spectra response function symmetry. It is extremely important when comparing spectra in the high slope spectra regions where possible large artifacts could be introduced. We have used a radiative model to simulate the spectra as observed in both IRIS and AIRS by using US Standard Atmospheric Profiles. The tropospheric warming and stratospheric warming are introduced in the model as well. The

  4. Moments, magnitudes, and radiated energies of non-volcanic tremor near Cholame, CA, from ground motion spectra at UPSAR

    USGS Publications Warehouse

    Fletcher, Joe B.; McGarr, A.

    2011-01-01

    By averaging the spectra of events within two episodes of tremor (on Jan. 21 and 24, 2005) across the 12 stations of UPSAR, we improved the S/N sufficiently to define source spectra. Analysis of eleven impulsive events revealed attenuation-corrected spectra of displacement similar to those of earthquakes, with a low-frequency plateau, a corner frequency, and a high frequency decay proportional to f−2. Seismic moments, M0, estimated from these spectra range from about 3 to 10 × 1011 N-m or moment magnitudes in the range 1.6 to 1.9. The corner frequencies range from 2.6 to 7.2 Hz and, if interpreted in the same way as for earthquakes, indicate low stress drops that vary from 0.001 to 0.04 MPa. Seismic energies, estimated from the ground motion spectra, vary from 0.2 × 105 to 4.4 × 105 J, or apparent stresses in the range 0.002 to 0.02 MPa. The low stress parameters are consistent with a weak fault zone in the lower crust at the depth of tremor. In contrast, the same analysis on a micro-earthquake, located near Cholame (depth = 10.3 km), revealed a stress drop of 0.5 MPa and an apparent stress of 0.02 MPa. Residual spectra from ω−2 model fits to the displacement spectra of the non-volcanic tremor events show peaks near 4 Hz that are not apparent in the spectra for the microearthquake nor for the spectrum of earth noise. These spectral peaks may indicate that tremor entails more than shear failure reminiscent of mechanisms, possibly entailing fluid flow, associated with volcanic tremor or deep volcanic earthquakes.

  5. Observation of Terahertz Radiation via the Two-Color Laser Scheme with Uncommon Frequency Ratios

    NASA Astrophysics Data System (ADS)

    Zhang, Liang-Liang; Wang, Wei-Min; Wu, Tong; Zhang, Rui; Zhang, Shi-Jing; Zhang, Cun-Lin; Zhang, Yan; Sheng, Zheng-Ming; Zhang, Xi-Cheng

    2017-12-01

    In the widely studied two-color laser scheme for terahertz (THz) radiation from a gas, the frequency ratio of the two lasers is usually fixed at ω2/ω1=1 :2 . We investigate THz generation with uncommon frequency ratios. Our experiments show, for the first time, efficient THz generation with new ratios of ω2/ω1=1 :4 and 2 ∶3 . We observe that the THz polarization can be adjusted by rotating the longer-wavelength laser polarization and the polarization adjustment becomes inefficient by rotating the other laser polarization; the THz energy shows similar scaling laws with different frequency ratios. These observations are inconsistent with multiwave mixing theory, but support the gas-ionization or plasma-current model. This study pushes the development of the two-color scheme and provides a new dimension to explore the long-standing problem of the THz generation mechanism.

  6. Observation of Terahertz Radiation via the Two-Color Laser Scheme with Uncommon Frequency Ratios.

    PubMed

    Zhang, Liang-Liang; Wang, Wei-Min; Wu, Tong; Zhang, Rui; Zhang, Shi-Jing; Zhang, Cun-Lin; Zhang, Yan; Sheng, Zheng-Ming; Zhang, Xi-Cheng

    2017-12-08

    In the widely studied two-color laser scheme for terahertz (THz) radiation from a gas, the frequency ratio of the two lasers is usually fixed at ω_{2}/ω_{1}=1:2. We investigate THz generation with uncommon frequency ratios. Our experiments show, for the first time, efficient THz generation with new ratios of ω_{2}/ω_{1}=1:4 and 2∶3. We observe that the THz polarization can be adjusted by rotating the longer-wavelength laser polarization and the polarization adjustment becomes inefficient by rotating the other laser polarization; the THz energy shows similar scaling laws with different frequency ratios. These observations are inconsistent with multiwave mixing theory, but support the gas-ionization or plasma-current model. This study pushes the development of the two-color scheme and provides a new dimension to explore the long-standing problem of the THz generation mechanism.

  7. Evidence for Abnormal H α Variability During Near-transit Observations of HD 189733 b

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cauley, P. Wilson; Redfield, Seth; Jensen, Adam G., E-mail: pcauley@wesleyan.edu

    2017-04-01

    Changes in levels of stellar activity can mimic absorption signatures in transmission spectra from circumplanetary material. Thus, it is critical to understand the frequency and magnitude of these changes in order to attribute any particular signal to the circumplanetary environment. We present short-cadence, high-resolution out-of-transit H α spectra for the hot Jupiter host HD 189733 in order to establish the frequency and magnitude of intrinsic stellar variations in the H α line core. We find that changes in the line core strength similar to those observed immediately pre- and post-transit in two independent data sets are uncommon. This suggests thatmore » the observed near-transit signatures are either due to absorption of circumplanetary material or they occur preferentially in time, very near planetary transits. In either case, the evidence for abnormal H α variability is strengthened, though the short-cadence out-of-transit data do not argue for circumplanetary absorption versus stellar activity caused by a star–planet interaction. Further out-of-transit monitoring at higher signal-to-noise would be useful to more strictly constrain the frequency of the near-transit changes in the H α line core.« less

  8. Observation of low-frequency acoustic surface waves in the nocturnal boundary layer.

    PubMed

    Talmadge, Carrick L; Waxler, Roger; Di, Xiao; Gilbert, Kenneth E; Kulichkov, Sergey

    2008-10-01

    A natural terrain surface, because of its porosity, can support an acoustic surface wave that is a mechanical analog of the familiar vertically polarized surface wave in AM radio transmission. At frequencies of several hundred hertz, the acoustic surface wave is attenuated over distances of a few hundred meters. At lower frequencies (e.g., below approximately 200 Hz) the attenuation is much less, allowing surface waves to propagate thousands of meters. At night, a low-frequency surface wave is generally present at long ranges even when downward refraction is weak. Thus, surface waves represent a ubiquitous nighttime transmission mode that exists even when other transmission modes are weak or absent. Data from recent nighttime field experiments and theoretical calculations are presented, demonstrating the persistence of the surface wave under different meteorological conditions. The low-frequency surface wave described here is the "quasiharmonical" tail observed previously in nighttime measurements but not identified by S. Kulichkov and his colleagues (Chunchuzov, I. P. et al. 1990. "On acoustical impulse propagation in a moving inhomogeneous atmospheric layer," J. Acoust. Soc. Am. 88, 455-461).

  9. LSD-based analysis of high-resolution stellar spectra

    NASA Astrophysics Data System (ADS)

    Tsymbal, V.; Tkachenko, A.; Van, Reeth T.

    2014-11-01

    We present a generalization of the method of least-squares deconvolution (LSD), a powerful tool for extracting high S/N average line profiles from stellar spectra. The generalization of the method is effected by extending it towards the multiprofile LSD and by introducing the possibility to correct the line strengths from the initial mask. We illustrate the new approach by two examples: (a) the detection of astroseismic signatures from low S/N spectra of single stars, and (b) disentangling spectra of multiple stellar objects. The analysis is applied to spectra obtained with 2-m class telescopes in the course of spectroscopic ground-based support for space missions such as CoRoT and Kepler. Usually, rather high S/N is required, so smaller telescopes can only compete successfully with more advanced ones when one can apply a technique that enables a remarkable increase in the S/N of the spectra which they observe. Since the LSD profiles have a potential for reconstruction what is common in all the spectral profiles, it should have a particular practical application to faint stars observed with 2-m class telescopes and whose spectra show remarkable LPVs.

  10. Unusually high frequency natural VLF radio emissions observed during daytime in Northern Finland

    NASA Astrophysics Data System (ADS)

    Manninen, Jyrki; Turunen, Tauno; Kleimenova, Natalia; Rycroft, Michael; Gromova, Liudmila; Sirviö, Iina

    2016-12-01

    Geomagnetic field variations and electromagnetic waves of different frequencies are ever present in the Earth’s environment in which the Earth’s fauna and flora have evolved and live. These waves are a very useful tool for studying and exploring the physics of plasma processes occurring in the magnetosphere and ionosphere. Here we present ground-based observations of natural electromagnetic emissions of magnetospheric origin at very low frequency (VLF, 3-30 kHz), which are neither heard nor seen in their spectrograms because they are hidden by strong impulsive signals (sferics) originating in lightning discharges. After filtering out the sferics, peculiar emissions are revealed in these digital recordings, made in Northern Finland, at unusually high frequencies in the VLF band. These recently revealed emissions, which are observed for several hours almost every day in winter, contain short (˜1-3 min) burst-like structures at frequencies above 4-6 kHz, even up to 15 kHz; fine structure on the 1 s time scale is also prevalent. It seems that these whistler mode emissions are generated deep inside the magnetosphere, but the detailed nature, generation region and propagation behaviour of these newly discovered high latitude VLF emissions remain unknown; however, further research on them may shed new light on wave-particle interactions occurring in the Earth’s radiation belts.

  11. Time-varying higher order spectra

    NASA Astrophysics Data System (ADS)

    Boashash, Boualem; O'Shea, Peter

    1991-12-01

    A general solution for the problem of time-frequency signal representation of nonlinear FM signals is provided, based on a generalization of the Wigner-Ville distribution. The Wigner- Ville distribution (WVD) is a second order time-frequency representation. That is, it is able to give ideal energy concentration for quadratic phase signals and its ensemble average is a second order time-varying spectrum. The same holds for Cohen's class of time-frequency distributions, which are smoothed versions of the WVD. The WVD may be extended so as to achieve ideal energy concentration for higher order phase laws, and such that the expectation is a time-varying higher order spectrum. The usefulness of these generalized Wigner-Ville distributions (GWVD) is twofold. Firstly, because they achieve ideal energy concentration for polynomial phase signals, they may be used for optimal instantaneous frequency estimation. Second, they are useful for discriminating between nonstationary processes of differing higher order moments. In the same way that the WVD is generalized, we generalize Cohen's class of TFDs by defining a class of generalized time-frequency distributions (GTFDs) obtained by a two dimensional smoothing of the GWVD. Another results derived from this approach is a method based on higher order spectra which allows the separation of cross-terms and auto- terms in the WVD.

  12. Smoothed Spectra, Ogives, and Error Estimates for Atmospheric Turbulence Data

    NASA Astrophysics Data System (ADS)

    Dias, Nelson Luís

    2018-01-01

    A systematic evaluation is conducted of the smoothed spectrum, which is a spectral estimate obtained by averaging over a window of contiguous frequencies. The technique is extended to the ogive, as well as to the cross-spectrum. It is shown that, combined with existing variance estimates for the periodogram, the variance—and therefore the random error—associated with these estimates can be calculated in a straightforward way. The smoothed spectra and ogives are biased estimates; with simple power-law analytical models, correction procedures are devised, as well as a global constraint that enforces Parseval's identity. Several new results are thus obtained: (1) The analytical variance estimates compare well with the sample variance calculated for the Bartlett spectrum and the variance of the inertial subrange of the cospectrum is shown to be relatively much larger than that of the spectrum. (2) Ogives and spectra estimates with reduced bias are calculated. (3) The bias of the smoothed spectrum and ogive is shown to be negligible at the higher frequencies. (4) The ogives and spectra thus calculated have better frequency resolution than the Bartlett spectrum, with (5) gradually increasing variance and relative error towards the low frequencies. (6) Power-law identification and extraction of the rate of dissipation of turbulence kinetic energy are possible directly from the ogive. (7) The smoothed cross-spectrum is a valid inner product and therefore an acceptable candidate for coherence and spectral correlation coefficient estimation by means of the Cauchy-Schwarz inequality. The quadrature, phase function, coherence function and spectral correlation function obtained from the smoothed spectral estimates compare well with the classical ones derived from the Bartlett spectrum.

  13. [Raman, FTIR spectra and normal mode analysis of acetanilide].

    PubMed

    Liang, Hui-Qin; Tao, Ya-Ping; Han, Li-Gang; Han, Yun-Xia; Mo, Yu-Jun

    2012-10-01

    The Raman and FTIR spectra of acetanilide (ACN) were measured experimentally in the regions of 3 500-50 and 3 500-600 cm(-1) respectively. The equilibrium geometry and vibration frequencies of ACN were calculated based on density functional theory (DFT) method (B3LYP/6-311G(d, p)). The results showed that the theoretical calculation of molecular structure parameters are in good agreement with previous report and better than the ones calculated based on 6-31G(d), and the calculated frequencies agree well with the experimental ones. Potential energy distribution of each frequency was worked out by normal mode analysis, and based on this, a detailed and accurate vibration frequency assignment of ACN was obtained.

  14. Mutational spectra of the lacI transgene isolated from Big Blue{reg_sign} mice exposed to three carcinogenic aromatic amines

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Staedtler, F.; Locher, F.; Sreenan, G.

    1997-10-01

    In order to evaluate the in vivo genotoxic potential of three putative genotoxic mouse liver carcinogens, high doses of 4-chloro-o-phenylenediamine, 2-nitro-p-phenylenediamine and 2, 4-diaminotoluene were tested short term in the Big Blue{reg_sign} transgenic mouse mutation assay. Small statistically significant increases in the lacI mutant frequencies in the liver by factors 1.7 to 2.0 were found. A representative number of 347 lacI mutants isolated from liver tissue of male and female animals were analyses by DNA sequencing. The mutational spectra were examined with the Adams-Skopek algorithm. The spontaneous mutational spectra from untreated male and female animals were similar and consistent withmore » spectral Big Blue{reg_sign} control data stored in the lacI database. Most of the background mutations were located in the 5{prime} portion of the coding region of the lacI gene. Single base substitutions were most prominent. G:C to A:T transitions and G:C to T:A transversions occurred predominatly and were preferentially located at CpG sites. Despite the increases observed in the mutant frequencies of the treated animals, the corresponding mutational spectra did not differ from the controls. However, it is possible that certain classes of point mutations were substantially increased but not detected due to the limited number of sequenced mutants. In two animals treated with 2, 4- diaminotoluene unusually high mutant frequencies and the multiple occurrence of certain mutations in the liver was observed. From one of these animals six lacI mutants isolated from colon tissue were all different. Since 2, 4-diaminotoluene was shown to induce liver cell proliferation these results may reflect clonal expansion of single mutated liver cells.« less

  15. Multi-scale roughness spectra of Mount St. Helens debris flows

    NASA Technical Reports Server (NTRS)

    Austin, Richard T.; England, Anthony W.

    1993-01-01

    A roughness spectrum allows surface structure to be interpreted as a sum of sinusoidal components with differing wavelengths. Knowledge of the roughness spectrum gives insight into the mechanisms responsible for electromagnetic scattering at a given wavelength. Measured spectra from 10-year-old primary debris flow surfaces at Mount St. Helens conform to a power-law spectral model, suggesting that these surfaces are scaling over the measured range of spatial frequencies. Measured spectra from water-deposited surfaces deviate from this model.

  16. AKARI observations of brown dwarfs. IV. Effect of elemental abundances on near-infrared spectra between 1.0 and 5.0 μm

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sorahana, S.; Yamamura, I.

    2014-09-20

    The detection of the CO{sub 2} absorption band at 4.2 μm in brown dwarf spectra by AKARI has made it possible to discuss CO{sub 2} molecular abundance in brown dwarf atmospheres. In our previous studies, we found an excess in the 4.2 μm CO{sub 2} absorption band of three brown dwarf spectra, and suggested that these deviations were caused by high C and O elemental abundances in their atmospheres. To validate this hypothesis, we have constructed a set of models of brown dwarf atmospheres with various elemental abundance patterns, and we investigate the variations of the molecular composition and themore » thermal structure, and how they affect the near-infrared spectra between 1.0 and 5.0 μm. The 4.2 μm CO{sub 2} absorption band in some late-L and T dwarfs taken by AKARI is stronger or weaker than predicted by corresponding models with solar abundance. By comparing the CO{sub 2} band in the model spectra to the observed near-infrared spectra, we confirm possible elemental abundance variations among brown dwarfs. We find that the band strength is especially sensitive to O abundance, but C is also needed to reproduce the entire near-infrared spectra. This result indicates that both the C and O abundances should increase and decrease simultaneously for brown dwarfs. We find that a weaker CO{sub 2} absorption band in a spectrum can also be explained by a model with lower 'C and O' abundances.« less

  17. Vortex dynamics and frequency splitting in vertically coupled nanomagnets

    DOE PAGES

    Stebliy, M. E.; Jain, S.; Kolesnikov, A. G.; ...

    2017-04-25

    Here, we explored the dynamic response of a vortex core in a circular nanomagnet by manipulating its dipole-dipole interaction with another vortex core confined locally on top of the nanomagnet. A clear frequency splitting is observed corresponding to the gyrofrequencies of the two vortex cores. The peak positions of the two resonance frequencies can be engineered by controlling the magnitude and direction of the external magnetic field. Both experimental and micromagnetic simulations show that the frequency spectra for the combined system is significantly dependent on the chirality of the circular nanomagnet and is asymmetric with respect to the external biasmore » field. We attribute this result to the strong dynamic dipole-dipole interaction between the two vortex cores, which varies with the distance between them. The possibility of having multiple states in a single nanomagnet with vertical coupling could be of interest for magnetoresistive memories.« less

  18. Modeling the Conformation-Specific Infrared Spectra of N-Alkylbenzenes

    NASA Astrophysics Data System (ADS)

    Tabor, Daniel P.; Sibert, Edwin; Hewett, Daniel M.; Korn, Joseph A.; Zwier, Timothy S.

    2016-06-01

    Conformation-specific UV-IR double resonance spectra are presented for n-alkylbenzenes. With the aid of a local mode Hamiltonian that includes the effects of stretch-bend Fermi coupling, the spectra of ethyl, n-propyl, and n-butylbenzene are assigned to individual conformers. These molecules allow for further development of the work on a first principles method for calculating alkyl stretch spectra. Due to the consistency of the anharmonic couplings from conformer to conformer, construction of the model Hamiltonian for a given conformer only requires a harmonic frequency calculation at the conformer's minimum geometry as an input. The model Hamiltonian can be parameterized with either density functional theory or MP2 electronic structure calculations. The relative strengths and weaknesses of these methods are evaluated, including their predictions of the relative energetics of the conformers. Finally, the IR spectra for conformers that have the alkyl chain bend back and interact with the π cloud of the benzene ring are modeled.

  19. Rain retrieval from dual-frequency radar Doppler spectra: validation and potential for a midlatitude precipitating case-study

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tridon, F.; Battaglia, A.; Luke, E.

    A recently developed technique retrieving the binned raindrop size distributions (DSDs) and air state parameters from ground-based K a and W-band radars Doppler spectra profiles is improved and applied to a typical midlatitude rain event. The retrievals are thoroughly validated against DSD observations of a 2D video disdrometer and independent X-band observations. Here for this case-study, profiles of rain rate, R, mean volume diameter and concentration parameter are retrieved, with low bias and standard deviations. In light rain (0.1 < R < 1 mm h -1), the radar reflectivities must be calibrated with a collocated disdrometer which introduces random errorsmore » due to sampling mismatch between the two instruments. The best performances are obtained in moderate rain (1 < R < 20 mm h -1) where the retrieval is providing self-consistent estimates of the absolute calibration and of the attenuation caused by antenna or radome wetness for both radars.« less

  20. Rain retrieval from dual-frequency radar Doppler spectra: validation and potential for a midlatitude precipitating case-study

    DOE PAGES

    Tridon, F.; Battaglia, A.; Luke, E.; ...

    2017-01-27

    A recently developed technique retrieving the binned raindrop size distributions (DSDs) and air state parameters from ground-based K a and W-band radars Doppler spectra profiles is improved and applied to a typical midlatitude rain event. The retrievals are thoroughly validated against DSD observations of a 2D video disdrometer and independent X-band observations. Here for this case-study, profiles of rain rate, R, mean volume diameter and concentration parameter are retrieved, with low bias and standard deviations. In light rain (0.1 < R < 1 mm h -1), the radar reflectivities must be calibrated with a collocated disdrometer which introduces random errorsmore » due to sampling mismatch between the two instruments. The best performances are obtained in moderate rain (1 < R < 20 mm h -1) where the retrieval is providing self-consistent estimates of the absolute calibration and of the attenuation caused by antenna or radome wetness for both radars.« less

  1. Theoretical Infrared Spectra for Polycyclic Aromatic Hydrocarbon Neutrals, Cations and Anions

    NASA Technical Reports Server (NTRS)

    Langhoff, Stephen R.

    1995-01-01

    Calculations are carried out using density functional theory (DFT) to determine the harmonic frequencies and intensities of the neutrals and cations of thirteen polycyclic aromatic hydrocarbons (PAHs) up to the size of ovalene. Calculations are also carried out for a few PAH anions. The DFT harmonic frequencies, when uniformly scaled by the factor of 0.958 to account primarily for anharmonicity, agree with the matrix isolation fundamentals to within an average error of about 10 per centimeter. Electron correlation is found to significantly reduce the intensities of many of the cation harmonics, bringing them into much better agreement with the available experimental data. While the theoretical infrared spectra agree well with the experimental data for the neutral systems and for many of the cations, there are notable discrepancies with the experimental matrix isolation data for some PAH cations that are difficult to explain in terms of limitations in the calculations. In agreement with previous theoretical work, the present calculations show that the relative intensities for the astronomical unidentified infrared (UIR) bands agree reasonably well with those for a distribution of polycyclic aromatic hydrocarbon (PAH) cations, but not with a distribution of PAH neutrals. We also observe that the infrared spectra of highly symmetrical cations such as coronene agree much better with astronomical observations than do those of, for example, the polyacenes such as tetracene and pentacene. The total integrated intensities for the neutral species are found to increase linearly with size, while the total integrated intensities are much larger for the cations and scale more nearly quadratically with size. We conclude that emission from moderate-sized highly symmetric PAH cations such as coronene and larger could account for the UIR bands.

  2. Accuracy of Single Frequency GPS Observations Processing In Near Real-time With Use of Code Predicted Products

    NASA Astrophysics Data System (ADS)

    Wielgosz, P. A.

    In this year, the system of active geodetic GPS permanent stations is going to be estab- lished in Poland. This system should provide GPS observations for a wide spectrum of users, especially it will be a great opportunity for surveyors. Many of surveyors still use cheaper, single frequency receivers. This paper focuses on processing of single frequency GPS observations only. During processing of such observations the iono- sphere plays an important role, so we concentrated on the influence of the ionosphere on the positional coordinates. Twenty consecutive days of GPS data from 2001 year were processed to analyze the accuracy of a derived three-dimensional relative vec- tor position between GPS stations. Observations from two Polish EPN/IGS stations: BOGO and JOZE were used. In addition to, a new test station - IGIK was created. In this paper, the results of single frequency GPS observations processing in near real- time are presented. Baselines of 15, 27 and 42 kilometers and sessions of 1, 2, 3, 4, and 6 hours long were processed. While processing we used CODE (Centre for Orbit De- termination in Europe, Bern, Switzerland) predicted products: orbits and ionosphere info. These products are available in real-time and enable near real-time processing. Software Bernese v. 4.2 for Linux and BPE (Bernese Processing Engine) mode were used. These results are shown with a reference to dual frequency weekly solution (the best solution). Obtained GPS positional time and GPS baseline length dependency accuracy is presented for single frequency GPS observations.

  3. Capturing molecular multimode relaxation processes in excitable gases based on decomposition of acoustic relaxation spectra

    NASA Astrophysics Data System (ADS)

    Zhu, Ming; Liu, Tingting; Wang, Shu; Zhang, Kesheng

    2017-08-01

    Existing two-frequency reconstructive methods can only capture primary (single) molecular relaxation processes in excitable gases. In this paper, we present a reconstructive method based on the novel decomposition of frequency-dependent acoustic relaxation spectra to capture the entire molecular multimode relaxation process. This decomposition of acoustic relaxation spectra is developed from the frequency-dependent effective specific heat, indicating that a multi-relaxation process is the sum of the interior single-relaxation processes. Based on this decomposition, we can reconstruct the entire multi-relaxation process by capturing the relaxation times and relaxation strengths of N interior single-relaxation processes, using the measurements of acoustic absorption and sound speed at 2N frequencies. Experimental data for the gas mixtures CO2-N2 and CO2-O2 validate our decomposition and reconstruction approach.

  4. Diffuse emission and pathological Seyfert spectra

    NASA Technical Reports Server (NTRS)

    Halpern, Jules P.

    1995-01-01

    In this annual ROSAT status report, the diffuse emission and spectra from Seyfert galaxies are examined. Three papers are presented and their contents include the soft x-ray properties and spectra of a binary millisecond pulsar, the PSPC and HRI observations of a Starburst/Seyfert 2 Galaxy, and an analysis of the possibility of x-ray luminous starbursts in the Einstein Medium Sensitivity Survey.

  5. VizieR Online Data Catalog: Absolute polarimetry observations of 33 pulsars (Force+, 2015)

    NASA Astrophysics Data System (ADS)

    Force, M. M.; Demorest, P.; Rankin, J. M.

    2017-11-01

    The observations were carried out in the summer of 2011 using the 100-m Robert C. Byrd GBT and the Green Bank Ultimate Pulsar Processing Instrument (GUPPI) in coherent filterbank mode. Full-Stokes spectra were acquired in an 800 MHz bandwidth centred at 1500 MHz radio frequency; the ~1200-1300 MHz airport radar analogue filter was used, resulting in a ~700 MHz effective bandwidth. The filterbank frequency resolution was 1.5 MHz, or 512 channels across the full band. (2 data files).

  6. Frequency-domain nonlinear regression algorithm for spectral analysis of broadband SFG spectroscopy.

    PubMed

    He, Yuhan; Wang, Ying; Wang, Jingjing; Guo, Wei; Wang, Zhaohui

    2016-03-01

    The resonant spectral bands of the broadband sum frequency generation (BB-SFG) spectra are often distorted by the nonresonant portion and the lineshapes of the laser pulses. Frequency domain nonlinear regression (FDNLR) algorithm was proposed to retrieve the first-order polarization induced by the infrared pulse and to improve the analysis of SFG spectra through simultaneous fitting of a series of time-resolved BB-SFG spectra. The principle of FDNLR was presented, and the validity and reliability were tested by the analysis of the virtual and measured SFG spectra. The relative phase, dephasing time, and lineshapes of the resonant vibrational SFG bands can be retrieved without any preset assumptions about the SFG bands and the incident laser pulses.

  7. Resonance Raman spectra of an O2-binding H-NOX domain reveal heme relaxation upon mutation.

    PubMed

    Tran, Rosalie; Boon, Elizabeth M; Marletta, Michael A; Mathies, Richard A

    2009-09-15

    Resonance Raman spectra were measured for the wild type Heme-Nitric oxide/OXygen binding domain from Thermoanaerobacter tengcongensis (Tt H-NOX WT) and three other Tt H-NOX proteins containing mutations at key conserved residues to determine the heme conformation in solution. The most dramatic changes in heme conformation occurred in the O2-bound forms, and the single Tt H-NOX P115A mutation was sufficient to generate a significant relaxation of the chromophore. Clear evidence of heme relaxation in the Tt H-NOX I5L, P115A, and I5L/P115A mutants in solution is demonstrated by the observation of reduced resonance Raman intensities for several out-of-plane low frequency modes (e.g., gamma11, gamma12, gamma13, and gamma15) in the 400-750 cm(-1) region known to be sensitive to ruffling and saddling deformations, as well as increased vibrational frequencies for the core heme skeletal stretching modes, nu3, nu2, and nu10. In addition, all three mutants exhibited some degree of heme conformational heterogeneity based on several broad skeletal markers (e.g., nu10) in the high frequency region. These results are comparable to those observed by Olea et al. for Tt H-NOX P115A in crystal form, where four different heme structures were determined from a single unit cell. On the basis of the resonance Raman spectra, it is clear that the actual heme conformation for Tt H-NOX P115A in solution is considerably more relaxed than that of the WT protein, with increased flexibility within the protein pocket, allowing for rapid sampling of alternate conformations.

  8. Vibrational dynamics of adsorbed molecules under conditions of photodesorption: Pump-probe SFG spectra of CO/Pt(111)

    NASA Astrophysics Data System (ADS)

    Fournier, Frédéric; Zheng, Wanquan; Carrez, Serge; Dubost, Henri; Bourguignon, Bernard

    2004-09-01

    Interaction of CO adsorbed on Pt(111) with electrons and phonons is studied experimentally by means of a pump-probe experiment where CO is probed by IR+visible sum frequency generation under a pump laser intensity that allows photodesorption. Vibrational spectra of CO internal stretch are obtained as a function of pump-probe delay. A two-temperature and anharmonic coupling model is used to extract from the spectra the real time variations of CO peak frequency and dephasing time. The main conclusions are the following: (i) The CO stretch is perturbed by two low-frequency modes, assigned to frustrated rotation and frustrated translation. (ii) The frustrated rotation is directly coupled to electrons photoexcited in Pt(111) by the pump laser. (iii) There is no evidence of Pt-CO stretch excitation in the spectra. The implications for the photodesorption dynamics are discussed.

  9. [The Study on the Far-FTIR and THz Spectra of Azitromycin Drugs with Different Physical Forms].

    PubMed

    Yang, Yu-ping; Fan, Li-jie; Cui, Bin; Chen, Gen-xiang; Zhang, Zhen-wei; Zhang, Cun-lin

    2015-11-01

    Far Fourier transform infrared spectroscopy (Far-FTIR) and terahertz time-domain spectroscopy (THz-TDS) were used to measure the fingerprint spectra of Azitromycin suspension, capsule, tablet and dispersible tablet under vacuum and nitrogen conditions, respectively. In the frequency range of 0.2-15 THz, highly resolved spectral features for Azitromycin suspension were measured and some minor differences were observed between domestic and exotic Azitromycin Suspension, such as linewidth broadening and additional peaks. As same time, for the domestic Azitromycin capsule, tablet and dispersible tablet, the absorption baselines in the range of 0.2-2.7 THz rise with the increase of frequency while absorption peaks become weaker due to the scattering of bigger particles and smaller amount of Azitromycin. Also, the additional peaks are caused by the absorption of filling materials. In parallel with the qualitative measurement, the THz absorption spectra for mixtures of polyethylene (PE) powders and exotic Azithomycin suspension with different concentrations were also measured. According to the linear correlation between the concentration and the absorption intensity, the concentration of effective component can be evaluated accurately. This means that THz-TDS method is suitable for the quality inspection and evaluation of the mixed Azithromycin system.

  10. Correlation of vapor phase infrared spectra and regioisomeric structure in synthetic cannabinoids

    NASA Astrophysics Data System (ADS)

    Smith, Lewis W.; Thaxton-Weissenfluh, Amber; Abiedalla, Younis; DeRuiter, Jack; Smith, Forrest; Clark, C. Randall

    2018-05-01

    The twelve 1-n-pentyl-2-, 3-, 4-, 5-, 6- and 7-(1- and 2-naphthoyl)-indoles each have the same substituents attached to the indole ring, identical elemental composition (C24H23NO) yielding identical nominal and accurate masses. These twelve isomers cover all possible positions of carbonyl bridge substitution for both indole (positons 2-7) and naphthalene rings (positions 1 and 2). Regioisomeric compounds can represent significant challenges for mass based analytical methods however, infrared spectroscopy is a powerful tool for the identification of positional isomers in organic compounds. The vapor phase infrared spectra of these twelve uniquely similar compounds were evaluated in GC-IR experiments. These spectra show the bridge position on the indole ring is a dominating influence over the carbonyl absorption frequency observed for these compounds. Substitution on the pyrrole moiety of the indole ring yields the lowest Cdbnd O frequency values for position 2 and 3 giving a narrow range from 1656 to 1654 cm-1. Carbonyl absorption frequencies are higher when the naphthoyl group is attached to the benzene portion of the indole ring yielding absorption values from 1674 to 1671 cm-1. The aliphatic stretching bands in the 2900 cm-1 region yield a consistent triplet pattern because the N-alkyl substituent tail group remains unchanged for all twelve regioisomers. The asymmetric CH2 stretch is the most intense of these three bands. Changes in positional bonding for both the indole and naphthalene ring systems results in unique patterns within the 700 wavenumber out-of-plane region and these absorption bands are different for all 12 regioisomers.

  11. Theoretical studies on absorption, emission, and resonance Raman spectra of Coumarin 343 isomers

    NASA Astrophysics Data System (ADS)

    Wu, Wenpeng; Cao, Zexing; Zhao, Yi

    2012-03-01

    The vibrationally resolved spectral method and quantum chemical calculations are employed to reveal the structural and spectral properties of Coumarin 343 (C343), an ideal candidate for organic dye photosensitizers, in vacuum and solution. The results manifest that the ground-state energies are dominantly determined by different placements of hydrogen atom in carboxylic group of C343 conformations. Compared to those in vacuum, the electronic absorption spectra in methanol solvent show a hyperchromic property together with the redshift and blueshift for the neutral C343 isomers and their deprotonated anions, respectively. From the absorption, emission, and resonance Raman spectra, it is found that the maximal absorption and emission come from low-frequency modes whereas the high-frequency modes have high Raman activities. The detailed spectra are further analyzed for the identification of the conformers and understanding the potential charge transfer mechanism in their photovoltaic applications.

  12. Mineralogy and chemistry of Ti-bearing lunar soils: Effects on reflectance spectra and remote sensing observations

    NASA Astrophysics Data System (ADS)

    Coman, Ecaterina O.; Jolliff, Bradley L.; Carpenter, Paul

    2018-05-01

    This paper presents results of coordinated ultraviolet and visible wavelength reflectance measurements, X-ray diffraction analyses of mineral components, and micro X-ray fluorescence analyses of Ti concentrations of 13 lunar soil samples (<210 μm) that span a range of maturity and TiO2 contents. Results of these analyses are used to determine the effects of soil maturity, TiO2 concentration, and specific mineralogical makeup, especially ilmenite content, on the ultraviolet/visible (UV/VIS) ratio for application to remote sensing observations of the Moon and other airless bodies. We find that measured ilmenite weight percent correlates highly with measured TiO2 concentrations. Thus, the ilmenite content is a good predictor of TiO2 concentration. Ilmenite is the main contributor of TiO2 for soils with greater than about 2 wt.% TiO2, so we take the effects of TiO2 on reflectance spectra to be essentially those of ilmenite. Constraining the data set to eight mature Apollo soils, we find that among the UV/VIS ratios from laboratory-measured spectra, the 321/415 nm ratio shows the best correlation with TiO2 and ilmenite. Moreover, for soils with similar maturity in the submature to mature range, those with higher TiO2 have higher 321/415 UV/VIS ratios. Finally, the correlation between TiO2 content and 321/415 ratio in samples measured in the lab appears weaker than for the same relationship using the Lunar Reconnaissance Orbiter (LRO) Wide Angle Camera (WAC) spectral data for the 321/415 ratio of Apollo ground-truth sites. The correlation between lab-derived 321/415 ratios and TiO2 content for measured samples improves when low-maturity samples are excluded from the dataset, implying that the LROC WAC spectra at 400 m/pix spatial resolution senses mostly mature soil.

  13. Substituent and solvent effects on electronic absorption spectra of some N-(substitutedphenyl)benzene sulphonamides

    NASA Astrophysics Data System (ADS)

    Suganya, Krishnasamy; Kabilan, Senthamaraikannan

    2004-04-01

    The effects of substituents and solvents have been studied through the absorption spectra of nearly 23 ortho- and para-N-(substitutedphenyl)benzene sulphonamides in the range of 200-400 nm. The effects of substituents on the absorption spectra of compounds under present investigation are interpreted by correlation of absorption frequencies with simple and extended Hammett equations. Effect of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of Kamlet equation and the results are discussed.

  14. Interannual and low-frequency variability of Upper Indus Basin winter/spring precipitation in observations and CMIP5 models

    NASA Astrophysics Data System (ADS)

    Greene, Arthur M.; Robertson, Andrew W.

    2017-12-01

    An assessment is made of the ability of general circulation models in the CMIP5 ensemble to reproduce observed modes of low-frequency winter/spring precipitation variability in the region of the Upper Indus basin (UIB) in south-central Asia. This season accounts for about two thirds of annual precipitation totals in the UIB and is characterized by "western disturbances" propagating along the eastward extension of the Mediterranean storm track. Observational data are utilized for for spatiotemporal characterization of the precipitation seasonal cycle, to compute seasonalized spectra and finally, to examine teleconnections, in terms of large-scale patterns in sea-surface temperature (SST) and atmospheric circulation. Annual and lowpassed variations are found to be associated primarily with SST modes in the tropical and extratropical Pacific. A more obscure link to North Atlantic SST, possibly related to the North Atlantic Oscillation, is also noted. An ensemble of 31 CMIP5 models is then similarly assessed, using unforced preindustrial multi-century control runs. Of these models, eight are found to reproduce well the two leading modes of the observed seasonal cycle. This model subset is then assessed in the spectral domain and with respect to teleconnection patterns, where a range of behaviors is noted. Two model families each account for three members of this subset. The degree of within-family similarity in behavior is shown to reflect underlying model differences. The results provide estimates of unforced regional hydroclimate variability over the UIB on interannual and decadal scales and the corresponding far-field influences, and are of potential relevance for the estimation of uncertainties in future water availability.

  15. Infrared Spectra of Substituted Polycyclic Aromatic Hydrocarbons

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Hudgins, Douglas M.; Sandford, Scott A.; Allamandola, Louis J.; Arnold, James O. (Technical Monitor)

    1997-01-01

    Calculations are carried out using density functional theory (DFT) to determine the harmonic frequencies and intensities of 1-methylanthracene, 9-methylanthracene, 9-cyanoanthracene, 2-aminoanthracene, acridine, and their positive ions. The theoretical data are compared with matrix-isolation spectra for these species also reported in this work. The theoretical and experimental frequencies and relative intensities for the neutral species are in generally good agreement, whereas the positive ion spectra are only in qualitative agreement. Relative to anthracene, we find that substitution of amethyl or CN for a hydrogen does not significantly affect the spectrum other than to add the characteristic methyl C-H stretch and C-N stretch (near 2200/cm), respectively. However, addition of NH2 dramatically affects the spectrum of the neutral. Not only are the NH2 modes themselves strong, but this electron withdrawing group induces sufficient partial charge on the ring to give the neutral molecule characteristics of the anthracene cation spectrum. The sum of the absolute intensities is about four times larger for 2-aminoanthracene than for 9-cyanoanthracene. Substituting nitrogen in the ring at the nine position (acridine) does not greatly alter the spectrum compared with anthracene.

  16. Room-Temperature Coherent Optical Phonon in 2D Electronic Spectra of CH 3NH 3PbI 3 Perovskite as a Possible Cooling Bottleneck

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Monahan, Daniele M.; Guo, Liang; Lin, Jia

    2017-06-29

    A hot phonon bottleneck may be responsible for slow hot carrier cooling in methylammonium lead iodide hybrid perovskite, creating the potential for more efficient hot carrier photovoltaics. In room-temperature 2D electronic spectra near the band edge, we observe in this paper amplitude oscillations due to a remarkably long lived 0.9 THz coherent phonon population at room temperature. This phonon (or set of phonons) is assigned to angular distortions of the Pb–I lattice, not coupled to cation rotations. The strong coupling between the electronic transition and the 0.9 THz mode(s), together with relative isolation from other phonon modes, makes it likelymore » to cause a phonon bottleneck. Finally, the pump frequency resolution of the 2D spectra also enables independent observation of photoinduced absorptions and bleaches independently and confirms that features due to band gap renormalization are longer-lived than in transient absorption spectra.« less

  17. Effects of multi-frequency power ultrasound on the enzymolysis and structural characteristics of corn gluten meal.

    PubMed

    Jin, Jian; Ma, Haile; Wang, Kai; Yagoub, Abu El-Gasim A; Owusu, John; Qu, Wenjuan; He, Ronghai; Zhou, Cunshan; Ye, Xiaofei

    2015-05-01

    The aim of this study was to investigate the effect of multi-frequency power ultrasound (sweeping frequency and pulsed ultrasound (SFPU) and sequential dual frequency ultrasound (SDFU)) on the enzymolysis of corn gluten meal (CGM) and on the structures of the major protein fractions (zein, glutelin) of CGM. The results showed that multi-frequency power ultrasound pretreatments improved significantly (P<0.05) the degree of hydrolysis and conversion rate of CGM. The changes in UV-Vis spectra, fluorescence emission spectra, surface hydrophobicity (H0), and the content of SH and SS groups indicated unfolding of zein and glutelin by ultrasound. The circular dichroism analysis showed that both pretreatments decreased α-helix and increased β-sheet of glutelin. The SFPU pretreatment had little impact on the secondary structure of zein, while the SDFU increased the α-helix and decreased the β-sheet remarkably. Scanning electron microscope indicated that both pretreatments destroyed the microstructures of glutelin and CGM, reduced the particle size of zein despite that the SDFU induced aggregation was observed. In conclusion, multi-frequency power ultrasound pretreatment is an efficient method in protein proteolysis due to its sonochemistry effect on the molecular conformation as well as on the microstructure of protein. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. Frequency domain measurement systems

    NASA Technical Reports Server (NTRS)

    Eischer, M. C.

    1978-01-01

    Stable frequency sources and signal processing blocks were characterized by their noise spectra, both discrete and random, in the frequency domain. Conventional measures are outlined, and systems for performing the measurements are described. Broad coverage of system configurations which were found useful is given. Their functioning and areas of application are discussed briefly. Particular attention is given to some of the potential error sources in the measurement procedures, system configurations, double-balanced-mixer-phase-detectors, and application of measuring instruments.

  19. Comparing Ultraviolet Spectra against Calculations: Year 2 Results

    NASA Technical Reports Server (NTRS)

    Peterson, Ruth C.

    2004-01-01

    The five-year goal of this effort is to calculate high fidelity mid-W spectra for individual stars and stellar systems for a wide range of ages, abundances, and abundance ratios. In this second year, the comparison of our calculations against observed high-resolution mid- W spectra was extended to stars as metal-rich as the Sun, and to hotter and cooler stars, further improving the list of atomic line parameters used in the calculations. We also published the application of our calculations based on the earlier list of line parameters to the observed mid-UV and optical spectra of a mildly metal-poor globular cluster in the nearby Andromeda galaxy, Messier 3 1.

  20. Doubly 15N-substituted diazenylium: THz laboratory spectra and fractionation models

    NASA Astrophysics Data System (ADS)

    Dore, L.; Bizzocchi, L.; Wirström, E. S.; Degli Esposti, C.; Tamassia, F.; Charnley, S. B.

    2017-07-01

    Context. Isotopic fractionation in dense molecular cores has been suggested as a possible origin of large 14N/15N ratio variations in solar system materials. While chemical models can explain some observed variations with different fractionation patterns for molecules with -NH or -CN functional groups, they fail to reproduce the observed ratios in diazenylium (N2H+). Aims: Observations of doubly 15N-substituted species could provide important constraints and insights for theoretical chemical models of isotopic fractionation. However, spectroscopic data are very scarce. Methods: The rotational spectra of the fully 15N-substituted isopologues of the diazenylium ion, 15N2H+ and 15N2D+, have been investigated in the laboratory well into the THz region by using a source-modulation microwave spectrometer equipped with a negative glow discharge cell. An extended chemical reaction network has been used to estimate what ranges of 15N fractionation in doubly 15N-substituted species could be expected in the interstellar medium (ISM). Results: For each isotopologue of the H- and D-containing pair, nine rotational transitions were accurately measured in the frequency region 88 GHz-1.2 THz. The analysis of the spectrum provided very precise rest frequencies at millimeter and sub-millimeter wavelengths, useful for the radioastronomical identification of the rotational lines of 15N2H+ and 15N2D+ in the ISM.

  1. Routes to spatiotemporal chaos in Kerr optical frequency combs.

    PubMed

    Coillet, Aurélien; Chembo, Yanne K

    2014-03-01

    We investigate the various routes to spatiotemporal chaos in Kerr optical frequency combs, obtained through pumping an ultra-high Q-factor whispering-gallery mode resonator with a continuous-wave laser. The Lugiato-Lefever model is used to build bifurcation diagrams with regards to the parameters that are externally controllable, namely, the frequency and the power of the pumping laser. We show that the spatiotemporal chaos emerging from Turing patterns and solitons display distinctive dynamical features. Experimental spectra of chaotic Kerr combs are also presented for both cases, in excellent agreement with theoretical spectra.

  2. Lightning electromagnetic radiation field spectra in the interval from 0. 2 to 20 MHz

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Willett, J.C.; Bailey, J.C.; Leteinturier, C.

    1990-11-20

    Average energy spectral densities are presented for the fast transitions in most of the components that produce large radiation field impulses from cloud-to-ground lightning; first and subsequent return strokes; stepped, dart-stepped, and 'chaotic' leaders; and 'characteristic' cloud pulses. A disagreement in the previous literature about the spectral energy radiated by return strokes at high frequencies is noted and explained. The authors show that the spectral amplitudes are not seriously distorted by propagation over less than 35 km of seawater, although as much as 45 km of such propagation does appear to produce significant attenuation above about 10 MHz. First andmore » subsequent return strokes produce identical spectra between 0.2 and 20 MHz. The spectra of stepped and dart-stepped leader steps are nearly identical and are very similar to that of characteristic pulses. The spectra of leader steps also match return stroke spectra above 2-3 MHz after the former are increased by about 7 dB. The shapes of individual spectra do not depend on their amplitude, so the shapes of the average spectra are probably not distorted by the trigger thresholds used in the data acquisition. Return strokes are the strongest sources of radiation from cloud-to-ground lightning in the 0.2- to 20-MHz frequency range, although certain intracloud processes are stronger radiators above 8 MHz.« less

  3. Sea level measurements using multi-frequency GPS and GLONASS observations

    NASA Astrophysics Data System (ADS)

    Löfgren, Johan S.; Haas, Rüdiger

    2014-12-01

    Global Positioning System (GPS) tide gauges have been realized in different configurations, e.g., with one zenith-looking antenna, using the multipath interference pattern for signal-to-noise ratio (SNR) analysis, or with one zenith- and one nadir-looking antenna, analyzing the difference in phase delay, to estimate the sea level height. In this study, for the first time, we use a true Global Navigation Satellite System (GNSS) tide gauge, installed at the Onsala Space Observatory. This GNSS tide gauge is recording both GPS and Globalnaya Navigatsionnaya Sputnikovaya Sistema (GLONASS) signals and makes it possible to use both the one- and two-antenna analysis approach. Both the SNR analysis and the phase delay analysis were evaluated using dual-frequency GPS and GLONASS signals, i.e., frequencies in the L-band, during a 1-month-long campaign. The GNSS-derived sea level results were compared to independent sea level observations from a co-located pressure tide gauge and show a high correlation for both systems and frequency bands, with correlation coefficients of 0.86 to 0.97. The phase delay results show a better agreement with the tide gauge sea level than the SNR results, with root-mean-square differences of 3.5 cm (GPS L1 and L2) and 3.3/3.2 cm (GLONASS L1/L2 bands) compared to 4.0/9.0 cm (GPS L1/L2) and 4.7/8.9 cm (GLONASS L1/L2 bands). GPS and GLONASS show similar performance in the comparison, and the results prove that for the phase delay analysis, it is possible to use both frequencies, whereas for the SNR analysis, the L2 band should be avoided if other signals are available. Note that standard geodetic receivers using code-based tracking, i.e., tracking the un-encrypted C/A-code on L1 and using the manufacturers' proprietary tracking method for L2, were used. Signals with the new C/A-code on L2, the so-called L2 C , were not tracked. Using wind speed as an indicator for sea surface roughness, we find that the SNR analysis performs better in rough sea

  4. Tissue specific resonance frequencies of water and metabolites within the human brain.

    PubMed

    Chadzynski, Grzegorz L; Bender, Benjamin; Groeger, Adriane; Erb, Michael; Klose, Uwe

    2011-09-01

    Chemical shift imaging (CSI) without water suppression was used to examine tissue-specific resonance frequencies of water and metabolites within the human brain. The aim was to verify if there are any regional differences in those frequencies and to determine the influence of chemical shift displacement in slice-selection direction. Unsuppressed spectra were acquired at 3T from nine subjects. Resonance frequencies of water and after water signal removal of total choline, total creatine and NAA were estimated. Furthermore, frequency distances between the water and those resonances were calculated. Results were corrected for chemical shift displacement. Frequency distances between water and metabolites were consistent and greater for GM than for WM. The highest value of WM to GM difference (14ppb) was observed for water to NAA frequency distance. This study demonstrates that there are tissue-specific differences between frequency distances of water and metabolites. Moreover, the influence of chemical shift displacement in slice-selection direction is showed to be negligible. Copyright © 2011 Elsevier Inc. All rights reserved.

  5. Frequency upconversion in Er3+ doped tungsten tellurite glass containing Ag nanoparticles

    NASA Astrophysics Data System (ADS)

    Mahajan, S. K.; Parashar, J.

    2018-05-01

    The frequency upconversion emission in Er3+ doped TeO2-WO3-Li2O containing Ag nanoparticle (TWLEOAG) glasses at 980nm excitation is reported. The absorption spectra reveal not only the peaks due to Er3+ ions, but also the surface plasmon resonance band of silver NPs located around 525nm and 650 nm. The spherical AgNPs with average size ˜38 nm in the glassy matrix is evidenced from the TEM measurement. Under 980nm laser excitation upconversion emission spectra show two major emission at 550nm and 638nm originating from 4S3/2 and 4F9/2 energy levels of the Er3+ ions, respectively was observed. Upconversion emission enhancement factor 7 fold has been measured for sample heat treated during 40h. However for 18h heat treated TWLEOAG sample under 980 nm flash lamp excitation produced Intense green compare to red emission. Since the 980nm frequency is far from the AgNPs surface plasmon resonance frequency, visible emission ehancement is attributed to local field increase in proximity of the Ag NPs and not energy tranfer from NPs to emitters. Possible energy transfer upconversion mechanism has been also discussed.

  6. On the analysis of photo-electron spectra

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gao, C.-Z., E-mail: gao@irsamc.ups-tlse.fr; CNRS, LPT; Dinh, P.M.

    2015-09-15

    We analyze Photo-Electron Spectra (PES) for a variety of excitation mechanisms from a simple mono-frequency laser pulse to involved combination of pulses as used, e.g., in attosecond experiments. In the case of simple pulses, the peaks in PES reflect the occupied single-particle levels in combination with the given laser frequency. This usual, simple rule may badly fail in the case of excitation pulses with mixed frequencies and if resonant modes of the system are significantly excited. We thus develop an extension of the usual rule to cover all possible excitation scenarios, including mixed frequencies in the attosecond regime. We find thatmore » the spectral distributions of dipole, monopole and quadrupole power for the given excitation taken together and properly shifted by the single-particle energies provide a pertinent picture of the PES in all situations. This leads to the derivation of a generalized relation allowing to understand photo-electron yields even in complex experimental setups.« less

  7. Experimental and theoretical study on the structure and vibrational spectra of β-2-aminopyridinium dihydrogenphosphate

    NASA Astrophysics Data System (ADS)

    Çırak, Çağrı; Demir, Selçuk; Ucun, Fatih; Çubuk, Osman

    2011-08-01

    Experimental and theoretical vibrational spectra of β-2-aminopyridinium dihydrogenphosphate (β-2APDP) have been investigated. The FT-IR spectrum of β-2APDP was recorded in the region 4000-400 cm -1. The optimized molecular structure and theoretical vibrational frequencies of β-2APDP have been investigated using ab initio Hartree-Fock (HF) and density functional B3LYP method with 6-311++G(d,p) basis set. The optimized geometric parameters (bond lengths and bond angles) and theoretical frequencies have been compared with the corresponding experimental data and it is found that they agree well with each other. All the assignments of the theoretical frequencies were performed by potential energy distributions using VEDA 4 program. Furthermore, the used scale factors were obtained from the ratio of the frequency values of the strongest peaks in the experimental and theoretical IR spectra. From the results it was concluded that the B3LYP method is superior to the HF method for the vibrational frequencies.

  8. Underdetermined blind separation of three-way fluorescence spectra of PAHs in water

    NASA Astrophysics Data System (ADS)

    Yang, Ruifang; Zhao, Nanjing; Xiao, Xue; Zhu, Wei; Chen, Yunan; Yin, Gaofang; Liu, Jianguo; Liu, Wenqing

    2018-06-01

    In this work, underdetermined blind decomposition method is developed to recognize individual components from the three-way fluorescent spectra of their mixtures by using sparse component analysis (SCA). The mixing matrix is estimated from the mixtures using fuzzy data clustering algorithm together with the scatters corresponding to local energy maximum value in the time-frequency domain, and the spectra of object components are recovered by pseudo inverse technique. As an example, using this method three and four pure components spectra can be blindly extracted from two samples of their mixture, with similarities between resolved and reference spectra all above 0.80. This work opens a new and effective path to realize monitoring PAHs in water by three-way fluorescence spectroscopy technique.

  9. Frequency band enlargement of the penetrator seismometer and its application to moonquake observation

    NASA Astrophysics Data System (ADS)

    Yamada, Ryuhei; Nébut, Tanguy; Shiraishi, Hiroaki; Lognonné, Philippe; Kobayashi, Naoki; Tanaka, Satoshi

    2015-07-01

    Seismic data obtained over a broad frequency range are very useful in investigation of the internal structures of the Earth and other planetary bodies. However, planetary seismic data acquired through the NASA Apollo and Viking programs were obtained only over a very limited frequency range. To obtain effective seismic data over a broader frequency range on planetary surfaces, broadband seismometers suitable for planetary seismology must be developed. In this study, we have designed a new broadband seismometer based on a short-period seismometer whose resonant frequency is 1 Hz for future geophysical missions. The seismometer is of an electromagnetic type, light weight, small size and has good shock-durability, making it suitable for being loaded onto a penetrator, which is a small, hard-landing probe developed in the LUNAR-A Project, a previous canceled mission. We modified the short-period seismometer so as to have a flat frequency response above about 0.1 Hz and the detection limit could be lowered to cover frequencies below the frequency. This enlargement of the frequency band will allow us to investigate moonquakes for lower frequency components in which waveforms are less distorted because strong scattering due to fractured structures near the lunar surface is likely to be suppressed. The modification was achieved simply by connecting a feedback circuit to the seismometer, without making any mechanical changes to the short-period sensor. We have confirmed that the broadband seismometer exhibits the frequency response as designed and allows us to observe long-period components of small ground motions. Methods to improve the performance of the broadband seismometer from the current design are also discussed. These developments should promise to increase the opportunity for application of this small and tough seismometer in various planetary seismological missions.

  10. Global distribution of vertical wavenumber spectra in the lower stratosphere observed using high-vertical-resolution temperature profiles from COSMIC GPS radio occultation

    NASA Astrophysics Data System (ADS)

    Noersomadi; Tsuda, T.

    2016-02-01

    We retrieved temperature (T) profiles with a high vertical resolution using the full spectrum inversion (FSI) method from the Constellation Observing System for Meteorology, Ionosphere and Climate (COSMIC) GPS radio occultation (GPS-RO) data from January 2007 to December 2009. We studied the characteristics of temperature perturbations in the stratosphere at 20-27 km altitude. This height range does not include a sharp jump in the background Brunt-Väisälä frequency squared (N2) near the tropopause, and it was reasonably stable regardless of season and latitude. We analyzed the vertical wavenumber spectra of gravity waves (GWs) with vertical wavelengths ranging from 0.5 to 3.5 km, and we integrated the (total) potential energy EpT. Another integration of the spectra from 0.5 to 1.75 km was defined as EpS for short vertical wavelength GWs, which was not studied with the conventional geometrical optics (GO) retrievals. We also estimated the logarithmic spectral slope (p) for the saturated portion of spectra with a linear regression fitting from 0.5 to 1.75 km.Latitude and time variations in the spectral parameters were investigated in two longitudinal regions: (a) 90-150° E, where the topography was more complicated, and (b) 170-230° E, which is dominated by oceans. We compared EpT, EpS, and p, with the mean zonal winds (U) and outgoing longwave radiation (OLR). We also show a ratio of EpS to EpT and discuss the generation source of EpS. EpT and p clearly showed an annual cycle, with their maximum values in winter at 30-50° N in region (a), and 50-70° N in region (b), which was related to the topography. At 30-50° N in region (b), EpT and p exhibited some irregular variations in addition to an annual cycle. In the Southern Hemisphere, we also found an annual oscillation in EpT and p, but it showed a time lag of about 2 months relative to U. Characteristics of EpTand p in the tropical region seem to be related to convective activity. The ratio of EpT to the

  11. Vibrational dynamics of adsorbed molecules under conditions of photodesorption: pump-probe SFG spectra of CO/Pt(111).

    PubMed

    Fournier, Frédéric; Zheng, Wanquan; Carrez, Serge; Dubost, Henri; Bourguignon, Bernard

    2004-09-08

    Interaction of CO adsorbed on Pt(111) with electrons and phonons is studied experimentally by means of a pump-probe experiment where CO is probed by IR + visible sum frequency generation under a pump laser intensity that allows photodesorption. Vibrational spectra of CO internal stretch are obtained as a function of pump-probe delay. A two-temperature and anharmonic coupling model is used to extract from the spectra the real time variations of CO peak frequency and dephasing time. The main conclusions are the following: (i) The CO stretch is perturbed by two low-frequency modes, assigned to frustrated rotation and frustrated translation. (ii) The frustrated rotation is directly coupled to electrons photoexcited in Pt(111) by the pump laser. (iii) There is no evidence of Pt-CO stretch excitation in the spectra. The implications for the photodesorption dynamics are discussed. Copyright 2004 American Institute of Physics

  12. Testing forward model against OCO-2 and TANSO-FTS/GOSAT observed spectra in near infrared range

    NASA Astrophysics Data System (ADS)

    Zadvornykh, Ilya V.; Gribanov, Konstantin G.

    2015-11-01

    An existing software package FIRE-ARMS (Fine InfraRed Explorer for Atmospheric Remote MeasurementS) was modified by embedding vector radiative transfer model VLIDORT. Thus the program tool includes both thermal (TIR) and near infrared (NIR) regions. We performed forward simulation of near infrared spectra on the top of the atmosphere for outgoing radiation accounting multiple scattering in cloudless atmosphere. Simulated spectra are compared with spectra measured by TANSO-FTS/GOSAT and OCO-2 in the condition of cloudless atmosphere over Western Siberia. NCEP/NCAR reanalysis data were used to complete model atmosphere.

  13. Multifrequency observations of a solar microwave burst with two-dimensional spatial resolution

    NASA Technical Reports Server (NTRS)

    Gary, Dale E.; Hurford, G. J.

    1990-01-01

    Frequency-agile interferometry observations using three baselines and the technique of frequency synthesis were used to obtain two-dimensional positions of multiple microwave sources at several frequency ranges in a solar flare. Source size and brightness temperature spectra were obtained near the peak of the burst. The size spectrum shows that the source size decreases rapidly with increasing frequency, but the brightness temperature spectrum can be well-fitted by gyrosynchrotron emission from a nonthermal distribution of electrons with power-law index of 4.8. The spatial structure of the burst showed several characteristics in common with primary/secondary bursts discussed by Nakajima et al. (1985). A source of coherent plasma emission at low frequencies is found near the secondary gyrosynchrotron source, associated with the leader spots of the active region.

  14. Theoretical and experimental studies of the structure and vibrational spectra of NTO

    NASA Astrophysics Data System (ADS)

    Sorescu, Dan C.; Sutton, Teressa R. L.; Thompson, Donald L.; Beardall, David; Wight, Charles A.

    1996-10-01

    The structure and vibrational spectra of the high explosive 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) have been determined by ab initio molecular orbital calculations at the Hartree-Fock and second-order Møller-Plesset levels and by density functional theory (B3LYP). Experimental frequencies for the molecule have been determined from infrared spectra of pure NTO films and NTO molecules isolated in an argon matrix at 21 K. A force field for gas phase NTO has been obtained based on calculated results at the MP2/6-311G∗∗ level. In addition, a force field for solid state NTO has been constructed using the experimental vibrational frequencies for NTO films and scaled ab initio vibrational frequencies. Differences between the solid state and gas phase results indicate that the environment and preparation procedure exert a marked influence on the spectral characteristics of the NTO molecule.

  15. Solar U- and J- Bursts at the Frequencies 10-30MHz

    NASA Astrophysics Data System (ADS)

    Dorovskyy, V. V.; Melnik, V. N.; Konovalenko, A. A.; Abranin, E. P.; Rucker, H. O.; Lecacheux, A.

    2006-08-01

    In the present report we discuss the results of observations of solar U- and J- bursts over the frequency range 10-30MHz, which have been obtained within the framework of an international observational campaign in June - August, 2004 at the radio telescope UTR-2 (Kharkov, Ukraine). We succeed to observe these types of bursts for the first time at such a low frequencies due to combination of large effective area of the radio telescope and high sensitivity of the new back-end. During June - August, 2004 about 30 U- and J- bursts were registered, and only 5 of them were confidently identified as U-bursts that may speak about the relative sparsity of the latter at mentioned frequencies. Both the isolated bursts and their sequences were observed. On average the turning frequencies lay in the range 10-22 MHz that corresponds to the arches heliocentric heights of 1.6-2.2 solar radii. In some sequences the bursts turning frequency was stable that may indicate the arch stability, while in others the turning frequency had tendency to vary from burst to burst. Durations of U- and J- bursts did not differ from those of usual Type III bursts (3-7s), while the drift rates of an ascending arm (on the average -1MHz/ s) was a little bit lower, than those of ordinary Type III bursts in this range. The harmonic structure of U- and J- bursts, and also Jb-J pairs (analogous to IIIb-III pairs) were registered. Also L-shaped bursts (Leblanc and Hoyos, 1985) were recorded. A specific feature of L-shaped bursts is prolonged zero-drift region on their dynamic spectra. The sizes and configurations of the arches were estimated on the base of obtained data. Possible explanations of the observed properties of U- and J- bursts are discussed.

  16. Observation of millimeter-wave oscillations from resonant tunneling diodes and some theoretical considerations of ultimate frequency limits

    NASA Technical Reports Server (NTRS)

    Sollner, T. C. L. G.; Brown, E. R.; Goodhue, W. D.; Le, H. Q.

    1987-01-01

    Recent observations of oscillation frequencies up to 56 GHz in resonant tunneling structures are discussed in relation to calculations by several authors of the ultimate frequency limits of these devices. It is found that calculations relying on the Wentzel-Kramers-Brillouin (WKB) approximation give limits well below the observed oscillation frequencies. Two other techniques for calculating the upper frequency limit were found to give more reasonable results. One method employs the solution of the time-dependent Schroedinger equation obtained by Kundrotas and Dargys (1986); the other uses the energy width of the transmission function for electrons through the double-barrier structure. This last technique is believed to be the most accurate since it is based on general results for the lifetime of any resonant state. It gives frequency limits on the order of 1 THz for two recently fabricated structures. It appears that the primary limitation of the oscillation frequency for double-barrier resonant-tunneling diodes is imposed by intrinsic device circuit parameters and by the transit time of the depletion layer rather than by time delays encountered in the double-barrier region.

  17. Low- and high-frequency Raman investigations on caffeine: polymorphism, disorder and phase transformation.

    PubMed

    Hédoux, Alain; Decroix, Anne-Amandine; Guinet, Yannick; Paccou, Laurent; Derollez, Patrick; Descamps, Marc

    2011-05-19

    Raman investigations are carried out both in crystalline forms of caffeine and during the isothermal transformation of the orientationally disordered form I into the stable form II at 363 K. The time dependence of the Raman spectrum exhibits no significant change in the intramolecular regime (above 100 cm(-1)), resembling the spectrum of the liquid state. By contrast, significant changes are observed below 100 cm(-1), and the low-frequency spectra of forms I and II are observed to be different from that of the liquid. The temperature dependence of the 5-600 cm(-1) spectrum gives information on the static disorder through the analysis of collective motions, while information on dynamic disorder are obtained from the study of the 555 cm(-1) band corresponding to internal vibrations in the pyrimidine ring. This analysis indubitably reveals that form II is also orientationally disordered with a local molecular arrangement that mimics that in form I and the liquid state. The comparison of the low-frequency spectra recorded in theophylline and form II of caffeine allows one to describe the stable form of caffeine from the packing arrangement of anhydrous theophylline with the consideration of reorientational molecular disorder. © 2011 American Chemical Society

  18. Simulations of the Fe K α Energy Spectra from Gravitationally Microlensed Quasars

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Krawczynski, H.; Chartas, G., E-mail: krawcz@wustl.edu

    The analysis of the Chandra X-ray observations of the gravitationally lensed quasar RX J1131−1231 revealed the detection of multiple and energy-variable spectral peaks. The spectral variability is thought to result from the microlensing of the Fe K α emission, selectively amplifying the emission from certain regions of the accretion disk with certain effective frequency shifts of the Fe K α line emission. In this paper, we combine detailed simulations of the emission of Fe K α photons from the accretion disk of a Kerr black hole with calculations of the effect of gravitational microlensing on the observed energy spectra. Themore » simulations show that microlensing can indeed produce multiply peaked energy spectra. We explore the dependence of the spectral characteristics on black hole spin, accretion disk inclination, corona height, and microlensing amplification factor and show that the measurements can be used to constrain these parameters. We find that the range of observed spectral peak energies of QSO RX J1131−1231 can only be reproduced for black hole inclinations exceeding 70° and for lamppost corona heights of less than 30 gravitational radii above the black hole. We conclude by emphasizing the scientific potential of studies of the microlensed Fe K α quasar emission and the need for more detailed modeling that explores how the results change for more realistic accretion disk and corona geometries and microlensing magnification patterns. A full analysis should furthermore model the signal-to-noise ratio of the observations and the resulting detection biases.« less

  19. The Effects of Low- and High-Energy Cutoffs on Solar Flare Microwave and Hard X-Ray Spectra

    NASA Technical Reports Server (NTRS)

    Holman, G. D.; Oegerle, William (Technical Monitor)

    2002-01-01

    Microwave and hard x-ray spectra provide crucial information about energetic electrons and their environment in solar flares. These spectra are becoming better determined with the Owens Valley Solar Array (OVSA) and the recent launch of the Ramaty High Energy Solar Spectroscopic Imager (RHESSI). The proposed Frequency Agile Solar Radiotelescope (FASR) promises even greater advances in radio observations of solar flares. Both microwave and hard x-ray spectra are sensitive to cutoffs in the electron distribution function. The determination of the high-energy cutoff from these spectra establishes the highest electron energies produced by the acceleration mechanism, while determination of the low-energy cutoff is crucial to establishing the total energy in accelerated electrons. This paper will show computations of the effects of both high- and low-energy cutoffs on microwave and hard x-ray spectra. The optically thick portion of a microwave spectrum is enhanced and smoothed by a low-energy cutoff, while a hard x-ray spectrum is flattened below the cutoff energy. A high-energy cutoff steepens the microwave spectrum and increases the wavelength at which the spectrum peaks, while the hard x-ray spectrum begins to steepen at photon energies roughly an order of magnitude below the electron cutoff energy. This work discusses how flare microwave and hard x-ray spectra can be analyzed together to determine these electron cutoff energies. This work is supported in part by the NASA Sun-Earth Connection Program.

  20. Capturing inhomogeneous broadening of the -CN stretch vibration in a Langmuir monolayer with high-resolution spectra and ultrafast vibrational dynamics in sum-frequency generation vibrational spectroscopy (SFG-VS)

    NASA Astrophysics Data System (ADS)

    Velarde, Luis; Wang, Hong-fei

    2013-08-01

    While in principle the frequency-domain and time-domain spectroscopic measurements should generate identical information for a given molecular system, the inhomogeneous character of surface vibrations in sum-frequency generation vibrational spectroscopy (SFG-VS) studies has only been studied with time-domain SFG-VS by mapping the decay of the vibrational polarization using ultrafast lasers, this due to the lack of SFG vibrational spectra with high enough spectral resolution and accurate enough lineshape. Here, with the recently developed high-resolution broadband SFG-VS (HR-BB-SFG-VS) technique, we show that the inhomogeneous lineshape can be obtained in the frequency-domain for the anchoring CN stretch of the 4-n-octyl-4'-cyanobiphenyl (8CB) Langmuir monolayer at the air-water interface, and that an excellent agreement with the time-domain SFG free-induction-decay can be established. We found that the 8CB CN stretch spectrum consists of a single peak centered at 2234.00 ± 0.01 cm-1 with a total linewidth of 10.9 ± 0.3 cm-1 at half maximum. The Lorentzian contribution accounts only for 4.7 ± 0.4 cm-1 to this width and the Gaussian (inhomogeneous) broadening for as much as 8.1 ± 0.2 cm-1. Polarization analysis of the -CN spectra showed that the -CN group is tilted 57° ± 2° from the surface normal. The large heterogeneity in the -CN spectrum is tentatively attributed to the -CN group interactions with the interfacial water molecules penetrated/accommodated into the 8CB monolayer, a unique phenomenon for the nCB Langmuir monolayers reported previously.

  1. Capturing inhomogeneous broadening of the -CN stretch vibration in a Langmuir monolayer with high-resolution spectra and ultrafast vibrational dynamics in sum-frequency generation vibrational spectroscopy (SFG-VS).

    PubMed

    Velarde, Luis; Wang, Hong-fei

    2013-08-28

    While in principle the frequency-domain and time-domain spectroscopic measurements should generate identical information for a given molecular system, the inhomogeneous character of surface vibrations in sum-frequency generation vibrational spectroscopy (SFG-VS) studies has only been studied with time-domain SFG-VS by mapping the decay of the vibrational polarization using ultrafast lasers, this due to the lack of SFG vibrational spectra with high enough spectral resolution and accurate enough lineshape. Here, with the recently developed high-resolution broadband SFG-VS (HR-BB-SFG-VS) technique, we show that the inhomogeneous lineshape can be obtained in the frequency-domain for the anchoring CN stretch of the 4-n-octyl-4'-cyanobiphenyl (8CB) Langmuir monolayer at the air-water interface, and that an excellent agreement with the time-domain SFG free-induction-decay can be established. We found that the 8CB CN stretch spectrum consists of a single peak centered at 2234.00 ± 0.01 cm(-1) with a total linewidth of 10.9 ± 0.3 cm(-1) at half maximum. The Lorentzian contribution accounts only for 4.7 ± 0.4 cm(-1) to this width and the Gaussian (inhomogeneous) broadening for as much as 8.1 ± 0.2 cm(-1). Polarization analysis of the -CN spectra showed that the -CN group is tilted 57° ± 2° from the surface normal. The large heterogeneity in the -CN spectrum is tentatively attributed to the -CN group interactions with the interfacial water molecules penetrated/accommodated into the 8CB monolayer, a unique phenomenon for the nCB Langmuir monolayers reported previously.

  2. Capturing inhomogeneous broadening of the -CN stretch vibration in a Langmuir monolayer with high-resolution spectra and ultrafast vibrational dynamics in sum-frequency generation vibrational spectroscopy (SFG-VS)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Velarde Ruiz Esparza, Luis A.; Wang, Hongfei

    2013-08-28

    Even though in principle the frequency-domain and time-domain spectroscopic measurement should generate identical information for a given molecular system, inhomogeneous character of surface vibrations in the sum-frequency generation vibrational spectroscopy (SFG-VS) studies has only been studied with the time-domain SFGVS by mapping the decay of the vibrational polarization using ultrafast lasers, due to the lack of SFG vibrational spectra with high enough spectral resolution and accurate enough line shape. Here with recently developed high-resolution broadband SFG-VS (HR-BB-SFG-VS) we show that the inhomogeneous line shape can be obtained in the frequency-domain, for the anchoring CN stretch of the 4-n-octyl-4'-cyanobiphenyl (8CB) Langmuirmore » monolayer at the air-water interface, and that an excellent agreement with the time-domain SFG free-induction-decay (FID) results can be established. We found that the 8CB CN stretch spectrum consists of a single peak centered at 2234.00 + * 0.01 cm-1 with a total line width of 10.9 + - 0.3 cm-1 at half maximum. The Lorentzian contribution accounts only for 4:7 + -0:4 cm-1 to this width and the Gaussian (inhomogeneous) broadening for as much as 8:1+*0:2 cm-1. Polarization analysis of the -CN spectra showed that the -CN group is tilted 57 + - 2 degrees from the surface normal. The large heterogeneity in the -CN spectrum is tentatively attributed to the -CN group interactions with the interfacial water molecules penetrated/accomodated into the 8CB monolayer, a unique phenomenon for the nCB Langmuir monolayers reported previously.« less

  3. A phase and frequency alignment protocol for 1H MRSI data of the prostate.

    PubMed

    Wright, Alan J; Buydens, Lutgarde M C; Heerschap, Arend

    2012-05-01

    (1)H MRSI of the prostate reveals relative metabolite levels that vary according to the presence or absence of tumour, providing a sensitive method for the identification of patients with cancer. Current interpretations of prostate data rely on quantification algorithms that fit model metabolite resonances to individual voxel spectra and calculate relative levels of metabolites, such as choline, creatine, citrate and polyamines. Statistical pattern recognition techniques can potentially improve the detection of prostate cancer, but these analyses are hampered by artefacts and sources of noise in the data, such as variations in phase and frequency of resonances. Phase and frequency variations may arise as a result of spatial field gradients or local physiological conditions affecting the frequency of resonances, in particular those of citrate. Thus, there are unique challenges in developing a peak alignment algorithm for these data. We have developed a frequency and phase correction algorithm for automatic alignment of the resonances in prostate MRSI spectra. We demonstrate, with a simulated dataset, that alignment can be achieved to a phase standard deviation of 0.095  rad and a frequency standard deviation of 0.68  Hz for the citrate resonances. Three parameters were used to assess the improvement in peak alignment in the MRSI data of five patients: the percentage of variance in all MRSI spectra explained by their first principal component; the signal-to-noise ratio of a spectrum formed by taking the median value of the entire set at each spectral point; and the mean cross-correlation between all pairs of spectra. These parameters showed a greater similarity between spectra in all five datasets and the simulated data, demonstrating improved alignment for phase and frequency in these spectra. This peak alignment program is expected to improve pattern recognition significantly, enabling accurate detection and localisation of prostate cancer with MRSI. Copyright

  4. Wind Speed Dependence of Acoustic Ambient Vertical Directional Spectra at High Frequency

    DTIC Science & Technology

    1989-05-26

    the measurements, which is 8 to 32 kHz, is sufficiently high that the propagation is adequately modeled using the Eikonal equation approximation. 4 TD...level spectra were calculated from the resulting time series. Spectral levels at 8, 16, and 32 kHz were recorded in a database along with the wind...indications of biological or industrial contaminations were removed. The resulting database seen here contained 215 samples. 10 * TD 8565 0z 00 a.I. cn

  5. Rotational spectra in the ν2 vibrationally excited states of MgNC

    NASA Astrophysics Data System (ADS)

    Kagi, E.; Kawaguchi, K.; Takano, S.; Hirano, T.

    1996-01-01

    The pure rotational spectra of MgNC in the ν2 (bending) vibrationally excited states were observed in the 310-380 GHz region to study the linearity of the molecule. The observed 90 spectral lines were assigned to the transitions in the v2=1-5 states and analyzed to determine a set of molecular constants in each state. The bending vibrational frequency was estimated to be 86 cm-1 from the l-type doubling constant of the v2=1 state. The interval of the Φ and Π states in v2=3 was determined to be 29.2280(24) cm-1, giving the anharmonicity constant xll=3.8611(9) cm-1 with one standard deviation in parentheses, which indicates that the molecule has a linear form. However, somewhat peculiar properties were recognized in dependence of the observed l-type resonance and vibration-rotation constants on the v2 vibrational quantum number, suggesting an effect of anharmonicity.

  6. Simple Emergent Power Spectra from Complex Inflationary Physics

    NASA Astrophysics Data System (ADS)

    Dias, Mafalda; Frazer, Jonathan; Marsh, M. C. David

    2016-09-01

    We construct ensembles of random scalar potentials for Nf-interacting scalar fields using nonequilibrium random matrix theory, and use these to study the generation of observables during small-field inflation. For Nf=O (few ), these heavily featured scalar potentials give rise to power spectra that are highly nonlinear, at odds with observations. For Nf≫1 , the superhorizon evolution of the perturbations is generically substantial, yet the power spectra simplify considerably and become more predictive, with most realizations being well approximated by a linear power spectrum. This provides proof of principle that complex inflationary physics can give rise to simple emergent power spectra. We explain how these results can be understood in terms of large Nf universality of random matrix theory.

  7. Simple Emergent Power Spectra from Complex Inflationary Physics.

    PubMed

    Dias, Mafalda; Frazer, Jonathan; Marsh, M C David

    2016-09-30

    We construct ensembles of random scalar potentials for N_{f}-interacting scalar fields using nonequilibrium random matrix theory, and use these to study the generation of observables during small-field inflation. For N_{f}=O(few), these heavily featured scalar potentials give rise to power spectra that are highly nonlinear, at odds with observations. For N_{f}≫1, the superhorizon evolution of the perturbations is generically substantial, yet the power spectra simplify considerably and become more predictive, with most realizations being well approximated by a linear power spectrum. This provides proof of principle that complex inflationary physics can give rise to simple emergent power spectra. We explain how these results can be understood in terms of large N_{f} universality of random matrix theory.

  8. Science highlights from high-sensitivity pulsar observations with the MWA

    NASA Astrophysics Data System (ADS)

    McSweeney, Samuel; Bhat, Ramesh; Tremblay, Steven; Ord, Stephen

    2016-01-01

    Pulsars are exquisite probes of the turbulent interstellar medium (ISM), capable of resolving structures down to tens of thousands of kilometres. Understanding the ISM is important for many areas of astrophysics, such as galactic dynamics, the chemical evolution of the galaxy, and the identification of timing noise in the search for gravitational waves using pulsar timing arrays. Low frequency observations of pulsars are key, because the strength of propagation effects scales strongly with frequency.We present the Murchison Widefield Array (MWA) as a key science tool for making high quality observations of pulsars at low frequencies (~80-300 MHz). Recently commissioned software for making tied-array beams and the MWA's high time resolution voltage capture system (VCS) allow an order of magnitude increase in sensitivity, vital for pulsar and other time-domain science. A pipeline has now been developed for observing the scintillation patterns of important pulsars at low frequencies, including a new computational technique for measuring the curvature of parabolic arcs in noisy secondary spectra. A program of MWA observations is being undertaken to sample a large number of millisecond pulsars. We present recent highlights including PSR J0437-4715, which yielded a new measurement of scattering screen distance of ~120 pc from Earth, consistent with a Parkes observation at ~730 MHz, and matching the predicted perimeter of the Local Bubble.

  9. Kinematic-PPP using Single/Dual Frequency Observations from (GPS, GLONASS and GPS/GLONASS) Constellations for Hydrography

    NASA Astrophysics Data System (ADS)

    Farah, Ashraf

    2018-03-01

    Global Positioning System (GPS) technology is ideally suited for inshore and offshore positioning because of its high accuracy and the short observation time required for a position fix. Precise point positioning (PPP) is a technique used for position computation with a high accuracy using a single GNSS receiver. It relies on highly accurate satellite position and clock data that can be acquired from different sources such as the International GNSS Service (IGS). PPP precision varies based on positioning technique (static or kinematic), observations type (single or dual frequency) and the duration of observations among other factors. PPP offers comparable accuracy to differential GPS with safe in cost and time. For many years, PPP users depended on GPS (American system) which considered the solely reliable system. GLONASS's contribution in PPP techniques was limited due to fail in maintaining full constellation. Yet, GLONASS limited observations could be integrated into GPS-based PPP to improve availability and precision. As GLONASS reached its full constellation early 2013, there is a wide interest in PPP systems based on GLONASS only and independent of GPS. This paper investigates the performance of kinematic PPP solution for the hydrographic applications in the Nile river (Aswan, Egypt) based on GPS, GLONASS and GPS/GLONASS constellations. The study investigates also the effect of using two different observation types; single-frequency and dual frequency observations from the tested constellations.

  10. Observation of magnetic fluctuations and rapid density decay of magnetospheric plasma in Ring Trap 1

    NASA Astrophysics Data System (ADS)

    Saitoh, H.; Yoshida, Z.; Morikawa, J.; Yano, Y.; Mikami, H.; Kasaoka, N.; Sakamoto, W.

    2012-06-01

    The Ring Trap 1 device, a magnetospheric configuration generated by a levitated dipole field magnet, has created high-β (local β ˜ 70%) plasma by using electron cyclotron resonance heating (ECH). When a large population of energetic electrons is generated at low neutral gas pressure operation, high frequency magnetic fluctuations are observed. When the fluctuations are strongly excited, rapid loss of plasma was simultaneously observed especially in a quiet decay phase after the ECH microwave power is turned off. Although the plasma is confined in a strongly inhomogeneous dipole field configuration, the frequency spectra of the fluctuations have sharp frequency peaks, implying spatially localized sources of the fluctuations. The fluctuations are stabilized by decreasing the hot electron component below approximately 40%, realizing stable high-β confinement.

  11. Observational Appearance and Spectrum of Black-Hole Winds

    NASA Astrophysics Data System (ADS)

    Fukue, Jun; Iino, Eriko

    2010-12-01

    We examine the observational appearance of an optically thick, spherically symmetric, relativistic wind (a black-hole wind), focusing our attention on the emerging spectrum. In a relativistic flow, the apparent optical depth becomes small (large) in the downstream (upstream) direction due to the Lorentz-Fitzgerald contraction. As a result, the location of the apparent photosphere of the wind is remarkably modified, and there appears a relativistic limb-darkening (center-brightening) effect, where the comoving temperature distribution of the apparent photosphere is enhanced (reduced) at the center (in the limb). In addition, due to the usual Doppler boost, the observed temperature distribution is greatly changed. These relativistic effects modify the expected spectrum. When the wind speed is subrelativistic, the observed temperature distribution is almost uniform, and the spectra of the black-hole wind are blackbody-like. When the wind speed becomes relativistic, on the other hand, the observed temperature distribution, Tobs, exhibits a power-law nature of Tobs ∝ r-1, where r is the distance from the disk center, and the observed spectra Sν become a modified blackbody, which has a power-law part of Sν ∝ ν, where ν is the frequency. We briefly examine the effects of the spatial variation of the wind speed and the mass-loss rate.

  12. Morphology of human sweat ducts observed by optical coherence tomography and their frequency of resonance in the terahertz frequency region

    NASA Astrophysics Data System (ADS)

    Tripathi, Saroj R.; Miyata, Eisuke; Ishai, Paul Ben; Kawase, Kodo

    2015-03-01

    It is crucial to understand the various biological effects induced by terahertz (THz) electromagnetic waves with the rapid development of electronic and photonic devices operating in the THz frequency region. The presence of sweat glands plays an important role in THz wave interactions with human skin. We investigated the morphological features of sweat ducts using optical coherence tomography (OCT) to further understand such phenomena. We observed remarkable features of the ducts, such as their clear helical structure. The intersubject and intrasubject variations in the diameter of sweat ducts were considerably smaller than the variations in other structural parameters, such as length and number of turns. Based on the sweat duct dimensions and THz dielectric properties of skin measured using terahertz time-domain spectroscopy (THz-TDS), we calculated the resonating frequency of the sweat duct under the assumption of it functioning as a helical antenna. Here, we show that the resonance frequency in the axial mode of operation lies in the THz wave region with a centre frequency of 0.44 +/- 0.07 THz. We expect that these findings will further our understanding of the various health consequences of the interaction of THz waves with human beings.

  13. Tunneling Spectra of a Quasifreestanding Graphene Monolayer

    NASA Astrophysics Data System (ADS)

    Li, Si-Yu; Bai, Ke-Ke; Zuo, Wei-Jie; Liu, Yi-Wen; Fu, Zhong-Qiu; Wang, Wen-Xiao; Zhang, Yu; Yin, Long-Jing; Qiao, Jia-Bin; He, Lin

    2018-05-01

    Considering the great success of scanning-tunneling-microscopy (STM) studies of graphene in the past ten years, it is quite surprising to notice that there is still a fundamental contradiction in the reported tunneling spectra of the quasifreestanding graphene monolayer. Many groups observed "V -shaped" spectra with linearly vanishing density of states at the Dirac point, whereas others reported spectra with a gap of ±60 meV pinned to the Fermi level in the quasifreestanding graphene monolayer. Here, we systematically study the two contradicting tunneling spectra of the quasifreestanding graphene monolayer on various substrates in the presence of different magnetic fields and demonstrate that both spectra are the "correct" spectra. However, the V -shaped spectrum exhibits only the contribution of the low-energy Dirac fermions, whereas the gapped spectrum is contributed by both the low-energy Dirac fermions and the high-energy nearly free-electron states due to the existence of the inelastic tunneling process. Our results indicate that interaction with substrates plays a vital role in affecting the spectra of graphene. We also show that it is possible to switch the tunneling spectra between the two distinct features at the nanoscale through voltage pulses applied to the STM tip.

  14. High-resolution 18 CM spectra of OH/IR stars

    NASA Astrophysics Data System (ADS)

    Fix, John D.

    1987-02-01

    High-velocity-resolution, high-signal-to-noise spectra have been obtained for the 18 cm maser emission lines from a number of optically visible OH/IR stars. The spectra have been interpreted in terms of a recent model by Alcock and Ross (1986), in which OH/IR stars lose mass in discrete elements rather than by a continuous wind. Comparison of the observed spectra with synthetic spectra shows that the lines are the composite emission from thousands or tens of thousands of individual elements.

  15. ESTIMATING THE RADIUS OF THE CONVECTIVE CORE OF MAIN-SEQUENCE STARS FROM OBSERVED OSCILLATION FREQUENCIES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yang, Wuming, E-mail: yangwuming@bnu.edu.cn, E-mail: yangwuming@ynao.ac.cn

    The determination of the size of the convective core of main-sequence stars is usually dependent on the construction of models of stars. Here we introduce a method to estimate the radius of the convective core of main-sequence stars with masses between about 1.1 and 1.5 M {sub ⊙} from observed frequencies of low-degree p -modes. A formula is proposed to achieve the estimation. The values of the radius of the convective core of four known stars are successfully estimated by the formula. The radius of the convective core of KIC 9812850 estimated by the formula is 0.140 ± 0.028 Rmore » {sub ⊙}. In order to confirm this prediction, a grid of evolutionary models was computed. The value of the convective-core radius of the best-fit model of KIC 9812850 is 0.149 R {sub ⊙}, which is in good agreement with that estimated by the formula from observed frequencies. The formula aids in understanding the interior structure of stars directly from observed frequencies. The understanding is not dependent on the construction of models.« less

  16. Vibrational spectra for uric acid and its D- and 15N-substituted analogues. Assignments for its normal modes from ab initio 3-21G force field.

    NASA Astrophysics Data System (ADS)

    Majoube, M.; Vergoten, G.

    1993-03-01

    FTR, Raman, FTIR spectra are obtained for polycrystalline uric acid and seven of its D-and 15N-substituted analogues. Assignments are given from a normal coordinate analysis carried out using a 3-21G ab initio force field. These are discussed by considering observed and calculated frequencies and D- and 15N-isotopic shifts.

  17. General properties of the radiation spectra from relativistic electrons moving in Langmuir turbulence

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Teraki, Yuto; Takahara, Fumio, E-mail: teraki@vega.ess.sci.osaka-u.ac.jp

    2014-05-20

    Using a numerical method, we examine the radiation spectra from relativistic electrons moving in Langmuir turbulence, which are expected to exist in high energy astrophysical objects. The spectral shape is characterized by the spatial scale λ, field strength σ, and frequency of the Langmuir waves, and in terms of frequency they are represented by ω{sub 0} = 2πc/λ, ω{sub st} = eσ/mc, and ω{sub p}, respectively. We normalize ω{sub st} and ω {sub p} by ω{sub 0} as a ≡ ω{sub st}/ω{sub 0} and b ≡ ω{sub p}/ω{sub 0}, and examine the spectral shape in the a–b plane. An earliermore » study based on the diffusive radiation in Langmuir turbulence (DRL) theory by Fleishman and Toptygin showed that the typical frequency is γ{sup 2}ω{sub p} and that the low frequency spectrum behaves as F {sub ω}∝ω{sup 1} for b > 1 irrespective of a. Here, we adopt the first principle numerical approach to obtain the radiation spectra in more detail. We generate Langmuir turbulence by superposing Fourier modes, injecting monoenergetic electrons, solving the equation of motion, and calculating the radiation spectra using a Lienard-Wiechert potential. We find different features from the DRL theory for a > b > 1. The peak frequency turns out to be γ{sup 2}ω{sub st}, which is higher than the γ{sup 2}ω{sub p} predicted by the DRL theory, and the spectral index of the low frequency region is not 1 but 1/3. This is because the typical deflection angle of electrons is larger than the angle of the beaming cone ∼1/γ. We call the radiation for this case 'wiggler radiation in Langmuir turbulence'.« less

  18. Substituent and solvent effects on electronic absorption spectra of some N-(substitutedphenyl)benzene sulphonamides.

    PubMed

    Suganya, Krishnasamy; Kabilan, Senthamaraikannan

    2004-04-01

    The effects of substituents and solvents have been studied through the absorption spectra of nearly 23 ortho- and para-N-(substitutedphenyl)benzene sulphonamides in the range of 200-400 nm. The effects of substituents on the absorption spectra of compounds under present investigation are interpreted by correlation of absorption frequencies with simple and extended Hammett equations. Effect of solvent polarity and hydrogen bonding on the absorption spectra are interpreted by means of Kamlet equation and the results are discussed. Copyright 2003 Elsevier B.V.

  19. Frequency domain kinetic of positron-electron annihilation in the MgO-Al2O3 spinel-type ceramics

    NASA Astrophysics Data System (ADS)

    Fl'unt, Orest; Klym, Halyna; Ingram, Adam

    2018-03-01

    In this work, the kinetic of positron-electron annihilation in the MgO-Al2O3 spinel-type ceramics sintered at different temperatures (1100, 1200 and 1400 °C) has been calculated and analyzed in a frequency domain. The spectra of real (in-phase) and imaginary (quadrature) components of positron-electron annihilation kinetic have been obtained numerically from usual temporal characteristics using integral Fourier transform. The numerical calculations were carried out using cubic spline interpolation of the pulse characteristics of MgO-Al2O3 ceramics in time domain with following analytical calculations of integrals. The obtained spectra as real so imaginary part of MgO-Al2O3 ceramics in frequency domain almost good obey a Debye law denying correlation between elementary positron annihilation processes. Complex diagrams of frequency domain responses of as-prepared samples have a shape of semicircles with close characteristic frequencies. Some deviation on low-frequency side of the semicircles is observed confirming an availability of longer time kinetic processes. Sintering temperature dependencies of the relaxation times and characteristic frequencies of positron-electron annihilation processes have been obtained. It is shown that position of large maxima on the frequency dependencies of imaginary part corresponds to fast average relaxation lifetime representing the most intensive interaction process of positrons with small cavity traps in solids.

  20. Modelling low-frequency volcanic earthquakes in a viscoelastic medium with topography

    NASA Astrophysics Data System (ADS)

    Jousset, Philippe; Neuberg, Jürgen; Jolly, Arthur

    2004-11-01

    Magma properties are fundamental to explain the volcanic eruption style as well as the generation and propagation of seismic waves. This study focusses on magma properties and rheology and their impact on low-frequency volcanic earthquakes. We investigate the effects of anelasticity and topography on the amplitudes and spectra of synthetic low-frequency earthquakes. Using a 2-D finite-difference scheme, we model the propagation of seismic energy initiated in a fluid-filled conduit embedded in a homogeneous viscoelastic medium with topography. We model intrinsic attenuation by linear viscoelastic theory and we show that volcanic media can be approximated by a standard linear solid (SLS) for seismic frequencies above 2 Hz. Results demonstrate that attenuation modifies both amplitudes and dispersive characteristics of low-frequency earthquakes. Low frequency volcanic earthquakes are dispersive by nature; however, if attenuation is introduced, their dispersion characteristics will be altered. The topography modifies the amplitudes, depending on the position of the seismographs at the surface. This study shows that we need to take into account attenuation and topography to interpret correctly observed low-frequency volcanic earthquakes. It also suggests that the rheological properties of magmas may be constrained by the analysis of low-frequency seismograms.