Sample records for observed light emission

  1. Global Night-Time Lights for Observing Human Activity

    NASA Technical Reports Server (NTRS)

    Hipskind, Stephen R.; Elvidge, Chris; Gurney, K.; Imhoff, Mark; Bounoua, Lahouari; Sheffner, Edwin; Nemani, Ramakrishna R.; Pettit, Donald R.; Fischer, Marc

    2011-01-01

    We present a concept for a small satellite mission to make systematic, global observations of night-time lights with spatial resolution suitable for discerning the extent, type and density of human settlements. The observations will also allow better understanding of fine scale fossil fuel CO2 emission distribution. The NASA Earth Science Decadal Survey recommends more focus on direct observations of human influence on the Earth system. The most dramatic and compelling observations of human presence on the Earth are the night light observations taken by the Defence Meteorological System Program (DMSP) Operational Linescan System (OLS). Beyond delineating the footprint of human presence, night light data, when assembled and evaluated with complementary data sets, can determine the fine scale spatial distribution of global fossil fuel CO2 emissions. Understanding fossil fuel carbon emissions is critical to understanding the entire carbon cycle, and especially the carbon exchange between terrestrial and oceanic systems.

  2. Experimental observation of polarized electroluminescence from edge-emission organic light emitting devices

    NASA Astrophysics Data System (ADS)

    Ran, G. Z.; Jiang, D. F.; Kan, Q.; Chen, H. D.

    2010-12-01

    We have observed a strongly polarized edge-emission from an organic light emitting device (OLED) with a silicon anode and a stacked Sm/Au (or Ag) cathode. For the OLED with a Sm/Au cathode, the transverse magnetic (TM) mode is stronger than the transverse electric (TE) mode by a factor of 2, while the polarization ratio of TM:TE is close to 300 for that with a Sm/Ag cathode. The polarization results from the scattering of surface plasmon polaritons at the device boundary. Such a silicon-based OLED is potentially an electrically excited SPP source in plasmonics.

  3. Prism-coupled light emission from tunnel junctions

    NASA Technical Reports Server (NTRS)

    Ushioda, S.; Rutledge, J. E.; Pierce, R. M.

    1985-01-01

    Completely p-polarized light emission has been observed from smooth Al-AlO(x)-Au tunnel junctions placed on a prism coupler. The angle and polarization dependence demonstrate unambiguously that the emitted light is radiated by the fast-mode surface plasmon polariton. The emission spectra suggest that the dominant process for the excitation of the fast mode is through conversion of the slow mode to the fast mode mediated by residual roughness on the junction surface.

  4. White-Light Emission from Layered Halide Perovskites.

    PubMed

    Smith, Matthew D; Karunadasa, Hemamala I

    2018-03-20

    With nearly 20% of global electricity consumed by lighting, more efficient illumination sources can enable massive energy savings. However, effectively creating the high-quality white light required for indoor illumination remains a challenge. To accurately represent color, the illumination source must provide photons with all the energies visible to our eye. Such a broad emission is difficult to achieve from a single material. In commercial white-light sources, one or more light-emitting diodes, coated by one or more phosphors, yield a combined emission that appears white. However, combining emitters leads to changes in the emission color over time due to the unequal degradation rates of the emitters and efficiency losses due to overlapping absorption and emission energies of the different components. A single material that emits broadband white light (a continuous emission spanning 400-700 nm) would obviate these problems. In 2014, we described broadband white-light emission upon near-UV excitation from three new layered perovskites. To date, nine white-light-emitting perovskites have been reported by us and others, making this a burgeoning field of study. This Account outlines our work on understanding how a bulk material, with no obvious emissive sites, can emit every color of the visible spectrum. Although the initial discoveries were fortuitous, our understanding of the emission mechanism and identification of structural parameters that correlate with the broad emission have now positioned us to design white-light emitters. Layered hybrid halide perovskites feature anionic layers of corner-sharing metal-halide octahedra partitioned by organic cations. The narrow, room-temperature photoluminescence of lead-halide perovskites has been studied for several decades, and attributed to the radiative recombination of free excitons (excited electron-hole pairs). We proposed that the broad white emission we observed primarily stems from exciton self-trapping. Here, the

  5. Light emission mechanism of mixed host organic light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Song, Wook; Lee, Jun Yeob

    2015-03-01

    Light emission mechanism of organic light-emitting diodes with a mixed host emitting layer was studied using an exciplex type mixed host and an exciplex free mixed host. Monitoring of the current density and luminance of the two type mixed host devices revealed that the light emission process of the exciplex type mixed host was dominated by energy transfer, while the light emission of the exciplex free mixed host was controlled by charge trapping. Mixed host composition was also critical to the light emission mechanism, and the contribution of the energy transfer process was maximized at 50:50 mixed host composition. Therefore, it was possible to manage the light emission process of the mixed host devices by managing the mixed host composition.

  6. A LIGHT CURVE ANALYSIS OF CLASSICAL NOVAE: FREE-FREE EMISSION VERSUS PHOTOSPHERIC EMISSION

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hachisu, Izumi; Kato, Mariko, E-mail: hachisu@ea.c.u-tokyo.ac.jp, E-mail: mariko@educ.cc.keio.ac.jp

    2015-01-10

    We analyzed light curves of seven relatively slower novae, PW Vul, V705 Cas, GQ Mus, RR Pic, V5558 Sgr, HR Del, and V723 Cas, based on an optically thick wind theory of nova outbursts. For fast novae, free-free emission dominates the spectrum in optical bands rather than photospheric emission, and nova optical light curves follow the universal decline law. Faster novae blow stronger winds with larger mass-loss rates. Because the brightness of free-free emission depends directly on the wind mass-loss rate, faster novae show brighter optical maxima. In slower novae, however, we must take into account photospheric emission because of theirmore » lower wind mass-loss rates. We calculated three model light curves of free-free emission, photospheric emission, and their sum for various white dwarf (WD) masses with various chemical compositions of their envelopes and fitted reasonably with observational data of optical, near-IR (NIR), and UV bands. From light curve fittings of the seven novae, we estimated their absolute magnitudes, distances, and WD masses. In PW Vul and V705 Cas, free-free emission still dominates the spectrum in the optical and NIR bands. In the very slow novae, RR Pic, V5558 Sgr, HR Del, and V723 Cas, photospheric emission dominates the spectrum rather than free-free emission, which makes a deviation from the universal decline law. We have confirmed that the absolute brightnesses of our model light curves are consistent with the distance moduli of four classical novae with known distances (GK Per, V603 Aql, RR Pic, and DQ Her). We also discussed the reason why the very slow novae are about ∼1 mag brighter than the proposed maximum magnitude versus rate of decline relation.« less

  7. Observations and models of emissions of volatile terpenoid compounds from needles of ponderosa pine trees growing in situ: control by light, temperature and stomatal conductance.

    PubMed

    Harley, Peter; Eller, Allyson; Guenther, Alex; Monson, Russell K

    2014-09-01

    Terpenoid emissions from ponderosa pine (Pinus ponderosa subsp. scopulorum) were measured in Colorado, USA over two growing seasons to evaluate the role of incident light, needle temperature, and stomatal conductance in controlling emissions of 2-methyl-3-buten-2-ol (MBO) and several monoterpenes. MBO was the dominant daylight terpenoid emission, comprising on average 87% of the total flux, and diurnal variations were largely determined by light and temperature. During daytime, oxygenated monoterpenes (especially linalool) comprised up to 75% of the total monoterpenoid flux from needles. A significant fraction of monoterpenoid emissions was dependent on light and 13CO2 labeling studies confirmed de novo production. Thus, modeling of monoterpenoid emissions required a hybrid model in which a significant fraction of emissions was dependent on both light and temperature, while the remainder was dependent on temperature alone. Experiments in which stomata were forced to close using abscisic acid demonstrated that MBO and a large fraction of the monoterpene flux, presumably linalool, could be limited at the scale of seconds to minutes by stomatal conductance. Using a previously published model of terpenoid emissions, which explicitly accounts for the physicochemical properties of emitted compounds, we were able to simulate these observed stomatal effects, whether induced experimentally or arising under naturally fluctuation conditions of temperature and light. This study shows unequivocally that, under naturally occurring field conditions, de novo light-dependent monoterpenes comprise a significant fraction of emissions in ponderosa pine. Differences between the monoterpene composition of ambient air and needle emissions imply a significant non-needle emission source enriched in Δ-3-carene.

  8. Light-dependent emission of hydrogen sulfide from plants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wilson, L.G.; Bressan, R.A.; Filner, P.

    1978-02-01

    With the aid of a sulfur-specific flame photometric detector, an emission of volatile sulfur was detected from leaves of cucumber (Cucumis sativus L.), squash and pumpkin (Cucurbita pepo L.), cantaloupe (Cucumis melo L.), corn (Zea mays L.), soybean (Glycine max (L.) Merr.) and cotton (Gossypium hirsutum L.). The emission was studied in detail in squash and pumpkin. It occurred following treatment of the roots of plants with sulfate and was markedly higher from either detached leaves treated via the cut petiole, or whole plants treated via mechanically injured roots. Bisulfite elicited higher rates of emission than sulfate. The emission wasmore » completely light-dependent and increased with light intensity. The rate of emission rose to a maximum and then declined steadily toward zero in the course of a few hours. However, emission resumed after reinjury of roots, an increase in light intensity, an increase in sulfur anion concentration, or a dark period of several hours. The emission was identified as H/sub 2/S by the following criteria: it had the odor of H/sub 2/S; it was not trapped by distilled H/sub 2/O, but was trapped by acidic CdCl/sub 2/ resulting in the formation of a yellow precipitate, CdS; it was also trapped by base and the contents of the trap formed methylene blue when reacted with N,N-dimethyl-p-phenylenediamine and Fe/sup 3 +/. H/sub 2/S emission is not the cause of leaf injury by SO/sub 2/, since bisulfite produced SO/sub 2/ injury symptoms in dim light when H/sub 2/S emission was low, while sulfate did not produce injury symptoms in bright light when H/sub 2/S emission was high. The maximum rates of emission observed, about 8 nmol min/sup -1/ g fresh weight/sup -1/, are about the activity that would be expected for the sulfur assimilation pathway of a normal leaf. H/sub 2/S emission may be a means by which the plant can rid itself of excess inorganic sulfur when HS/sup -/ acceptors are not available in sufficient quantity.« less

  9. In Situ Observation of Modulated Light Emission of Fiber Fuse Synchronized with Void Train over Hetero-Core Splice Point

    PubMed Central

    Todoroki, Shin-ichi

    2008-01-01

    Background Fiber fuse is a process of optical fiber destruction under the action of laser radiation, found 20 years ago. Once initiated, opical discharge runs along the fiber core region to the light source and leaves periodic voids whose shape looks like a bullet pointing the direction of laser beam. The relation between damage pattern and propagation mode of optical discharge is still unclear even after the first in situ observation three years ago. Methodology/Principal Findings Fiber fuse propagation over hetero-core splice point (Corning SMF-28e and HI 1060) was observed in situ. Sequential photographs obtained at intervals of 2.78 µs recorded a periodic emission at the tail of an optical discharge pumped by 1070 nm and 9 W light. The signal stopped when the discharge ran over the splice point. The corresponding damage pattern left in the fiber core region included a segment free of periodicity. Conclusions The spatial modulation pattern of the light emission agreed with the void train formed over the hetero-core splice point. Some segments included a bullet-shaped void pointing in the opposite direction to the laser beam propagation although the sequential photographs did not reveal any directional change in the optical discharge propagation. PMID:18815621

  10. HST observations of Europa's atmospheric UV emission

    NASA Astrophysics Data System (ADS)

    Saur, J. S.; Feldman, P. D.; Strobel, D. F.; Retherford, K. D.; Roth, L.; McGrath, M. A.; Gerard, J. M.; Grodent, D. C.; Schilling, N.

    2009-12-01

    The Advanced Camera for Surveys on the Hubble Space Telescope observed Europa on June 29, 2008 during five consecutive orbits. Europa was at eastern elongation and crossed the Jovian current sheet during the observing interval. The observations were performed with ACS/SBC with prism PR130L to separate the two prominent FUV oxygen lines OI 1304 A, OI 1356 A and to discriminate reflected solar light from Europa's surface. After addressing the strong red leak contained in the measurements, we find that Europa's atmospheric emission clearly depends on Europa's position in Jupiter's current sheet. We also see that the atmospheric emissions of Europa's leading side do not show pronounced asymmetries with respect to Europa's sub-Jovian and anti-Jovian side. Previous observations of the atmospheric emissions, in contrast, found a strong asymmetry on Europa's trailing side [McGrath et al. 2004].

  11. Transfer Printing Method to Obtain Polarized Light Emission in Organic Light-Emitting Device

    NASA Astrophysics Data System (ADS)

    Noh, Hee Yeon; Park, Chang-sub; Park, Ji-Sub; Kang, Shin-Won; Kim, Hak-Rin

    2012-06-01

    We demonstrate a transfer printing method to obtain polarized light emission in organic light-emitting devices (OLEDs). On a rubbed self-assembled monolayer (SAM), a spin-coated liquid crystalline light-emissive polymer is aligned along the rubbing direction because of the anisotropic interfacial intermolecular interaction. Owing to the low surface energy of the SAM surface, the light-emissive layer was easily transferred to a patterned poly(dimethylsiloxane) (PDMS) stamp surface without degrading the ordering. Finally, a polarized light-emissive OLED device was prepared by transferring the patterned light-emissive layer to the charge transport layer of the OLED structure.

  12. Observations and models of emissions of volatile terpenoid compounds from needles of ponderosa pine trees growing in situ: control by light, temperature and stomatal conductance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Harley, Peter; Eller, Allyson; Guenther, Alex

    Terpenoid emissions from ponderosa pine (Pinus ponderosa subsp. scopulorum) were measured in Colorado, USA over two growing seasons to evaluate the role of incident light, needle temperature and stomatal conductance in controlling emissions of 2-methyl-3-buten-2-ol (MBO) and several monoterpenes. MBO was the dominant daylight terpenoid emission, comprising on average 87% of the total flux, and diurnal variations were largely determined by light and temperature. During daytime, oxygenated monoterpenes (especially linalool) comprised up to 75% of the total monoterpenoid flux from needles. A significant fraction of monoterpenoid emissions was light dependent and 13CO2 labeling studies confirmed de novo production. Thus, modelingmore » of monoterpenoid emissions required a hybrid model in which a significant fraction of emissions was dependent on both light and temperature, while the remainder was dependent on temperature alone. Experiments in which stomata were forced to close using abscisic acid demonstrated that MBO and a large fraction of the monoterpene flux, presumably linalool, could be limited at the scale of seconds to minutes by stomatal conductance. Using a previously published model of terpenoid emissions which explicitly accounts for the physico-chemical properties of emitted compounds, we are able to simulate these observed stomatal effects, whether induced through experimentation or arising under naturally fluctuation conditions of temperature and light. This study shows unequivocally that, under naturally occurring field conditions, de novo light dependent monoterpenes can comprise a large fraction of emissions. Differences between the monoterpene composition of ambient air and needle emissions imply a significant non-needle emission source enriched in Δ-3-carene.« less

  13. Composite Supraparticles with Tunable Light Emission

    PubMed Central

    2017-01-01

    Robust luminophores emitting light with broadly tunable colors are desirable in many applications such as light-emitting diode (LED)-based lighting, displays, integrated optoelectronics and biology. Nanocrystalline quantum dots with multicolor emission, from core- and shell-localized excitons, as well as solid layers of mixed quantum dots that emit different colors have been proposed. Here, we report on colloidal supraparticles that are composed of three types of Cd(Se,ZnS) core/(Cd,Zn)S shell nanocrystals with emission in the red, green, and blue. The emission of the supraparticles can be varied from pure to composite colors over the entire visible region and fine-tuned into variable shades of white light by mixing the nanocrystals in controlled proportions. Our approach results in supraparticles with sizes spanning the colloidal domain and beyond that combine versatility and processability with a broad, stable, and tunable emission, promising applications in lighting devices and biological research. PMID:28787121

  14. Suppression of Hydrogen Emission in an X-Class White-Light Solar Flare

    NASA Technical Reports Server (NTRS)

    Prochazka, Ondrej; Milligan, Ryan O.; Allred, Joel C.; Kowalski, Adam F.; Kotrc, Pavel; Mathioudakis, Mihalis

    2017-01-01

    We present unique NUV observations of a well-observed X-class flare from NOAA 12087 obtained at the Ondrejov Observatory. The flare shows a strong white-light continuum but no detectable emission in the higher Balmer and Lyman lines. Reuven Ramaty High-Energy Solar Spectroscopic Imager and Fermi observations indicate an extremely hard X-ray spectrum and gamma-ray emission. We use the RADYN radiative hydrodynamic code to perform two types of simulations: one where an energy of 3 x 10(exp 11) erg/sq cm/s is deposited by an electron beam with a spectral index of approx. = 3, and a second where the same energy is applied directly to the photosphere. The combination of observations and simulations allows us to conclude that the white-light emission and the suppression or complete lack of hydrogen emission lines is best explained by a model where the dominant energy deposition layer is located in the lower layers of the solar atmosphere, rather than the chromosphere.

  15. Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites.

    PubMed

    Hu, Te; Smith, Matthew D; Dohner, Emma R; Sher, Meng-Ju; Wu, Xiaoxi; Trinh, M Tuan; Fisher, Alan; Corbett, Jeff; Zhu, X-Y; Karunadasa, Hemamala I; Lindenberg, Aaron M

    2016-06-16

    The recently discovered phenomenon of broadband white-light emission at room temperature in the (110) two-dimensional organic-inorganic perovskite (N-MEDA)[PbBr4] (N-MEDA = N(1)-methylethane-1,2-diammonium) is promising for applications in solid-state lighting. However, the spectral broadening mechanism and, in particular, the processes and dynamics associated with the emissive species are still unclear. Herein, we apply a suite of ultrafast spectroscopic probes to measure the primary events directly following photoexcitation, which allows us to resolve the evolution of light-induced emissive states associated with white-light emission at femtosecond resolution. Terahertz spectra show fast free carrier trapping and transient absorption spectra show the formation of self-trapped excitons on femtosecond time-scales. Emission-wavelength-dependent dynamics of the self-trapped exciton luminescence are observed, indicative of an energy distribution of photogenerated emissive states in the perovskite. Our results are consistent with photogenerated carriers self-trapped in a deformable lattice due to strong electron-phonon coupling, where permanent lattice defects and correlated self-trapped states lend further inhomogeneity to the excited-state potential energy surface.

  16. Suppression of Hydrogen Emission in an X-class White-light Solar Flare

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Procházka, Ondrej; Milligan, Ryan O.; Mathioudakis, Mihalis

    We present unique NUV observations of a well-observed X-class flare from NOAA 12087 obtained at the Ondřejov Observatory. The flare shows a strong white-light continuum but no detectable emission in the higher Balmer and Lyman lines. Reuven Ramaty High-Energy Solar Spectroscopic Imager and Fermi observations indicate an extremely hard X-ray spectrum and γ -ray emission. We use the RADYN radiative hydrodynamic code to perform two types of simulations: one where an energy of 3 × 10{sup 11} erg cm{sup −2} s{sup −1} is deposited by an electron beam with a spectral index of ≈3, and a second where the samemore » energy is applied directly to the photosphere. The combination of observations and simulations allows us to conclude that the white-light emission and the suppression or complete lack of hydrogen emission lines is best explained by a model where the dominant energy deposition layer is located in the lower layers of the solar atmosphere, rather than the chromosphere.« less

  17. Mapping Boron Dioxide (BO2) Light Emission During Ballistic Initiation of Boron

    DTIC Science & Technology

    2016-03-03

    Dreizin; unreferenced). Essentially, 2 light sensors (cameras), each filtered over a narrow wavelength region, observe an event over the same line of...background incandescence (subtraction gave a qualitatively similar result). For imaging BO2 emission, the light sensors were 2 Phantom V7.3 monochrome...A check of the temperature measurement technique using emission from an acetylene/air diffusion flame gave reasonable results (1,800 K outer soot

  18. Synthesis and White-Light Emission of ZnO/HfO2: Eu Nanocables

    PubMed Central

    2010-01-01

    ZnO/HfO2:Eu nanocables were prepared by radio frequency sputtering with electrospun ZnO nanofibers as cores. The well-crystallized ZnO/HfO2:Eu nanocables showed a uniform intact core–shell structure, which consisted of a hexagonal ZnO core and a monoclinic HfO2 shell. The photoluminescence properties of the samples were characterized. A white-light band emission consisted of blue, green, and red emissions was observed in the nanocables. The blue and green emissions can be attributed to the zinc vacancy and oxygen vacancy defects in ZnO/HfO2:Eu nanocables, and the yellow–red emissions are derived from the inner 4f-shell transitions of corresponding Eu3+ ions in HfO2:Eu shells. Enhanced white-light emission was observed in the nanocables. The enhancement of the emission is ascribed to the structural changes after coaxial synthesis. PMID:20730130

  19. On-road emissions of light-duty vehicles in europe.

    PubMed

    Weiss, Martin; Bonnel, Pierre; Hummel, Rudolf; Provenza, Alessio; Manfredi, Urbano

    2011-10-01

    For obtaining type approval in the European Union, light-duty vehicles have to comply with emission limits during standardized laboratory emissions testing. Although emission limits have become more stringent in past decades, light-duty vehicles remain an important source of nitrogen oxides and carbon monoxide emissions in Europe. Furthermore, persisting air quality problems in many urban areas suggest that laboratory emissions testing may not accurately capture the on-road emissions of light-duty vehicles. To address this issue, we conduct the first comprehensive on-road emissions test of light-duty vehicles with state-of-the-art Portable Emission Measurement Systems. We find that nitrogen oxides emissions of gasoline vehicles as well as carbon monoxide and total hydrocarbon emissions of both diesel and gasoline vehicles generally remain below the respective emission limits. By contrast, nitrogen oxides emissions of diesel vehicles (0.93 ± 0.39 grams per kilometer [g/km]), including modern Euro 5 diesel vehicles (0.62 ± 0.19 g/km), exceed emission limits by 320 ± 90%. On-road carbon dioxide emissions surpass laboratory emission levels by 21 ± 9%, suggesting that the current laboratory emissions testing fails to accurately capture the on-road emissions of light-duty vehicles. Our findings provide the empirical foundation for the European Commission to establish a complementary emissions test procedure for light-duty vehicles. This procedure could be implemented together with more stringent Euro 6 emission limits in 2014. The envisaged measures should improve urban air quality and provide incentive for innovation in the automotive industry.

  20. Fabrication of White Light-emitting Electrochemical Cells with Stable Emission from Exciplexes.

    PubMed

    Uchida, Soichi; Takizawa, Daisuke; Ikeda, Satoru; Takeuchi, Hironori; Nishimura, Suzushi; Nishide, Hiroyuki; Nishikitani, Yoshinori

    2016-11-15

    The authors present an approach for fabricating stable white light emission from polymer light-emitting electrochemical cells (PLECs) having an active layer which consists of blue-fluorescent poly(9,9-di-n-dodecylfluorenyl-2,7-diyl) (PFD) and π-conjugated triphenylamine molecules. This white light emission originates from exciplexes formed between PFD and amines in electronically excited states. A device containing PFD, 4,4',4''-tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA), Poly(ethylene oxide) and K2CF3SO3 showed white light emission with Commission internationale de l'éclairage (CIE) coordinates of (0.33, 0.43) and a Color Rendering Index (CRI) of Ra = 73 at an applied voltage of 3.5 V. Constant voltage measurements showed that the CIE coordinates of (0.27, 0.37), Ra of 67, and the emission color observed immediately after application of a voltage of 5 V were nearly unchanged and stable after 300 sec.

  1. A dual-emitting core-shell carbon dot-silica-phosphor composite for white light emission

    NASA Astrophysics Data System (ADS)

    Chen, Yonghao; Lei, Bingfu; Zheng, Mingtao; Zhang, Haoran; Zhuang, Jianle; Liu, Yingliang

    2015-11-01

    A unique dual-emitting core-shell carbon dot-silica-phosphor (CDSP) was constructed from carbon dots (CDs), tetraethoxysilane (TEOS) and Sr2Si5N8:Eu2+ phosphor through a one-pot sol-gel method. Blue emitting CDs uniformly disperse in the silica layer covering the orange emitting phosphor via a polymerization process, which makes CDSP achieve even white light emission. Tunable photoluminescence of CDSP is observed and the preferable white light emission is achieved through changing the excitation wavelength or controlling the mass ratio of the phosphor. When CDSP powders with a phosphor rate of 3.9% and 5.1% are excited at a wavelength of 400 nm, preferable white light emission is observed, with Commission Internationale de l'Eclairage (CIE) coordinates of (0.32, 0.32) and (0.34, 0.32), respectively. Furthermore, CDSP can mix well with epoxy resin to emit strong and even white light, and based on this, a CDSP-based white LED with a high colour rendering index (CRI) of 94 was fabricated.A unique dual-emitting core-shell carbon dot-silica-phosphor (CDSP) was constructed from carbon dots (CDs), tetraethoxysilane (TEOS) and Sr2Si5N8:Eu2+ phosphor through a one-pot sol-gel method. Blue emitting CDs uniformly disperse in the silica layer covering the orange emitting phosphor via a polymerization process, which makes CDSP achieve even white light emission. Tunable photoluminescence of CDSP is observed and the preferable white light emission is achieved through changing the excitation wavelength or controlling the mass ratio of the phosphor. When CDSP powders with a phosphor rate of 3.9% and 5.1% are excited at a wavelength of 400 nm, preferable white light emission is observed, with Commission Internationale de l'Eclairage (CIE) coordinates of (0.32, 0.32) and (0.34, 0.32), respectively. Furthermore, CDSP can mix well with epoxy resin to emit strong and even white light, and based on this, a CDSP-based white LED with a high colour rendering index (CRI) of 94 was fabricated

  2. Polarized electroluminescence from edge-emission organic light emitting devices

    NASA Astrophysics Data System (ADS)

    Ran, G. Z.; Jiang, D. F.

    2011-01-01

    We report the experimental observation and measurement of the polarized electroluminescence from an edge-emission Si based- organic light emitting device (OLED) with a Sm/Au or Sm/Ag cathode. Light collected from the OLED edge comes from the scattering of the surface plasmon polaritons (SPPs) at the device boundary. This experiment shows that such Si-OLED can be an electrically excited SPP source on a silicon chip for optical interconnect based on SPPs.

  3. Light collection device for flame emission detectors

    DOEpatents

    Woodruff, Stephen D.; Logan, Ronald G.; Pineault, Richard L.

    1990-01-01

    A light collection device for use in a flame emission detection system such as an on-line, real-time alkali concentration process stream monitor is disclosed which comprises a sphere coated on its interior with a highly diffuse reflective paint which is positioned over a flame emission source, and one or more fiber optic cables which transfer the light generated at the interior of the sphere to a detecting device. The diffuse scattering of the light emitted by the flame uniformly distributes the light in the sphere, and the collection efficiency of the device is greater than that obtainable in the prior art. The device of the present invention thus provides enhanced sensitivity and reduces the noise associated with flame emission detectors, and can achieve substantial improvements in alkali detection levels.

  4. Observation of Solar Wind Charge Exchange Emission from Exospheric Material in and Outside Earth's Magnetosheath

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Collier, M. R.; Cravens, T.; Kuntz, K. D.; Lepri, S. T.; Robertson, I.; Tomas, L.

    2008-01-01

    A long XMM-Newton exposure is used to observe solar wind charge exchange (SWCX) emission from exospheric material in and outside Earth s magnetosheath. The light curve of the O VII (0.5-0.62 keV) band is compared with a model for the expected emission, and while the emission is faint and the light curve has considerable scatter, the correlation is significant to better than 99.9%. This result demonstrates the validity of the geocoronal SWCX emission model for predicting a contribution to astrophysical observations to a scale factor of order unity (1.36). The results also demonstrate the potential utility of using X-ray observations to study global phenomena of the magnetosheath which currently are only investigated using in situ measurements.

  5. Electron emission from chemical vapor deposited diamond and amorphous carbon films observed with a simple field emission device

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Feng, Z.; Brown, I.G.; Ager, J.W. III

    Electron emission from chemical vapor deposited (CVD) diamond and amorphous carbon (a-C) films was observed with a simple field emission device (FED). Both diamond and a-C films were prepared with microwave plasma-enhanced CVD techniques. Electron emission in the field strength range +10 to {minus}10 MVm{sup {minus}1} was studied, and the field emission source was confirmed by a diode characteristic of the {ital I}-{ital V} curve, a straight line in the Fowler--Nordheim (F-N) plot, and direct observation of light emission from a fluorescent screen. The turn-on field strength was {similar_to}5 MVm{sup {minus}1}, which was similar for both kinds of carbon films.more » The highest current density for diamond films, observed at a field strength of 10 MVm{sup {minus}1}, was {similar_to}15 {mu}A cm{sup {minus}2}. Diamond films yielded a higher emission current than a-C films. The reasons for the observed field emission are discussed.« less

  6. Visible light emission measurements from a dense electrothermal launcher plasma

    NASA Astrophysics Data System (ADS)

    Hankins, O. E.; Bourham, M. A.; Earnhart, J.; Gilligan, J. G.

    1993-01-01

    Measurements of the visible light emission from dense, weakly non-ideal plasmas have been performed on the experimental electrothermal launcher device 'SIRENS'. The plasma is created by the ablation or a Lexan insulator in the source, which then flows through a cylindrical barrel which serves as the material sample. Visible light emission spectra have been observed both in-bore and from the muzzle flash or the barrel, and from the flash or the source. Due to high plasma opacity (the plasma emits as a near blackbody) and absorption by the molecular components of the vapor shield, the hotter core or the arc has been difficult to observe. Recent measurements along the axis or the device indicate time-averaged plasma temperatures in the barrel or about 1 eV for lower energy shots, which agree with experimental measurements of the average heat flux and plasma conductivity along the barrel. Measurements or visible emission from the source indicate time averaged temperatures of 1 to 2 eV which agree with the theoretical estimates derived from ablated mass measurements and calculated estimates derived from plasma conductivity measurements.

  7. Gamma-Ray Emission in Dissipative Pulsar Magnetospheres: from Theory to Fermi Observations

    NASA Technical Reports Server (NTRS)

    Kalapotharakos, Konstantinos; Harding, Alice K.; Kazanas, Demosthenes

    2014-01-01

    We compute the patterns of gamma-ray emission due to curvature radiation in dissipative pulsar magnetospheres. Our ultimate goal is to construct macrophysical models that are able to reproduce the observed gamma-ray light curve phenomenology recently published in the Second Fermi Pulsar Catalog. We apply specific forms of Ohm's law on the open field lines using a broad range for the macroscopic conductivity values that result in solutions ranging, from near-vacuum to near-force-free. Using these solutions, we generate model gamma-ray light curves by calculating realistic trajectories and Lorentz factors of radiating particles under the influence of both the accelerating electric fields and curvature radiation reaction. We further constrain our models using the observed dependence of the phase lags between the radio and gamma-ray emission on the gamma-ray peak separation. We perform a statistical comparison of our model radio-lag versus peak-separation diagram and the one obtained for the Fermi standard pulsars. We find that for models of uniform conductivity over the entire open magnetic field line region, agreement with observations favors higher values of this parameter. We find, however, significant improvement in fitting the data with models that employ a hybrid form of conductivity, specifically, infinite conductivity interior to the light cylinder and high but finite conductivity on the outside. In these models the gamma-ray emission is produced in regions near the equatorial current sheet but modulated by the local physical properties. These models have radio lags near the observed values and statistically best reproduce the observed light curve phenomenology. Additionally, they also produce GeV photon cut-off energies.

  8. Afterglow Observations Shed New Light on the Nature of X-ray Flashes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Granot, J

    X-ray flashes (XRFs) and X-ray rich gamma-ray bursts (XRGRBs) share many observational characteristics with long duration ({approx}> 2 s) GRBs, but the reason for which the spectral energy distribution of their prompt emission peaks at lower photon energies, E{sub p}, is still a subject of debate. Although many different models have been invoked in order to explain the lower values of E{sub p}, their implications for the afterglow emission were not considered in most cases, mainly because observations of XRF afterglows have become available only recently. Here we examine the predictions of the various XRF models for the afterglow emission,more » and test them against the observations of XRF 030723 and XRGRB 041006, the events with the best monitored afterglow light curves in their respective class. We show that most existing XRF models are hard to reconcile with the observed afterglow light curves, which are very flat at early times. Such light curves are, however, naturally produced by a roughly uniform jet with relatively sharp edges that is viewed off-axis (i.e. from outside of the jet aperture). This type of model self consistently accommodates both the observed prompt emission and the afterglow light curves of XRGRB 041006 and XRF 030723, implying viewing angles {theta}{sub obs} from the jet axis of ({theta}{sub obs}-{theta}{sub 0}) {approx} 0.15 {theta}{sub 0} and ({theta}{sub obs}-{theta}{sub 0}) {approx} {theta}{sub 0}, respectively, where {theta}{sub 0} {approx} 3{sup o} is the half-opening angle of the jet. This suggests that GRBs, XRGRBs and XRFs are intrinsically similar relativistic jets viewed from different angles. It is then natural to identify GRBs with {gamma}({theta}{sub obs} - {theta}{sub 0}) {approx}< 1, XRGRBs with 1 {approx}< ({theta}{sub obs} - {theta}{sub 0}) {approx}< a few, and XRFs with {gamma}({theta}{sub obs} - {theta}{sub 0}) {approx}> a few, where {gamma} is the Lorentz factor of the outflow near the edge of the jet from which most

  9. Light emission from organic single crystals operated by electrolyte doping

    NASA Astrophysics Data System (ADS)

    Matsuki, Keiichiro; Sakanoue, Tomo; Yomogida, Yohei; Hotta, Shu; Takenobu, Taishi

    2018-03-01

    Light-emitting devices based on electrolytes, such as light-emitting electrochemical cells (LECs) and electric double-layer transistors (EDLTs), are solution-processable devices with a very simple structure. Therefore, it is necessary to apply this device structure into highly fluorescent organic materials for future printed applications. However, owing to compatibility problems between electrolytes and organic crystals, electrolyte-based single-crystal light-emitting devices have not yet been demonstrated. Here, we report on light-emitting devices based on organic single crystals and electrolytes. As the fluorescent materials, α,ω-bis(biphenylyl)terthiophene (BP3T) and 5,6,11,12-tetraphenylnaphthacene (rubrene) single crystals were selected. Using ionic liquids as electrolytes, we observed clear light emission from BP3T LECs and rubrene EDLTs.

  10. Optical emission line monitor with background observation and cancellation

    DOEpatents

    Goff, D.R.; Notestein, J.E.

    1985-01-04

    A fiber optics based optical emission line monitoring system is provided in which selected spectral emission lines, such as the sodium D-line emission in coal combustion, may be detected in the presence of interferring background or blackbody radiation with emissions much greater in intensity than that of the emission line being detected. A bifurcated fiber optic light guide is adapted at the end of one branch to view the combustion light which is guided to a first bandpass filter, adapted to the common trunk end of the fiber. A portion of the light is reflected back through the common trunk portion of the fiber to a second bandpass filter adapted to the end of the other branch of the fiber. The first filter bandpass is centered at a wavelength corresponding to the emission line to be detected with a bandwidth of about three nanometers (nm). The second filter is centered at the same wavelength but having a width of about 10 nm. First and second light detectors are located to view the light passing through the first and second filters respectively. Thus, the second detector is blind to the light corresponding to the emission line of interest detected by the first detector and the difference between the two detector outputs is uniquely indicative of the intensity of only the combustion flame emission of interest. This instrument can reduce the effects of interfering blackbody radiation by greater than 20 dB.

  11. Optical emission line monitor with background observation and cancellation

    DOEpatents

    Goff, David R.; Notestein, John E.

    1986-01-01

    A fiber optics based optical emission line monitoring system is provided in which selected spectral emission lines, such as the sodium D-line emission in coal combustion, may be detected in the presence of interferring background or blackbody radiation with emissions much greater in intensity than that of the emission line being detected. A bifurcated fiber optic light guide is adapted at the end of one branch to view the combustion light which is guided to a first bandpass filter, adapted to the common trunk end of the fiber. A portion of the light is reflected back through the common trunk portion of the fiber to a second bandpass filter adapted to the end of the other branch of the fiber. The first filter bandpass is centered at a wavelength corresponding to the emission line to be detected with a bandwidth of about three nanometers (nm). The second filter is centered at the same wavelength but having a width of about 10 nm. First and second light detectors are located to view the light passing through the first and second filters respectively. Thus, the second detector is blind to the light corresponding to the emission line of interest detected by the first detector and the difference between the two detector outputs is uniquely indicative of the intensity of only the combustion flame emission of interest. This instrument can reduce the effects of interferring blackbody radiation by greater than 20 dB.

  12. Visible emission from bismuth-doped yttrium oxide thin films for lighting and display applications.

    PubMed

    Scarangella, Adriana; Fabbri, Filippo; Reitano, Riccardo; Rossi, Francesca; Priolo, Francesco; Miritello, Maria

    2017-12-11

    Due to the great development of light sources for several applications from displays to lighting, great efforts are devoted to find stable and efficient visible emitting materials. Moreover, the requirement of Si compatibility could enlarge the range of applications inside microelectronic chips. In this scenario, we have studied the emission properties of bismuth doped yttrium oxide thin films grown on crystalline silicon. Under optical pumping at room temperature a stable and strong visible luminescence has been observed. In particular, by the involvement of Bi ions in the two available lattice sites, the emission can be tuned from violet to green by changing the excitation wavelength. Moreover, under electron beam at low accelerating voltages (3 keV) a blue emission with high efficiency and excellent stability has been recorded. The color is generated by the involvement of Bi ions in both the lattice sites. These peculiarities make this material interesting as a luminescent medium for applications in light emitting devices and field emission displays by opening new perspectives for the realization of silicon-technology compatible light sources operating at room temperature.

  13. Simultaneous Observations of p-mode Light Walls and Magnetic Reconnection Ejections above Sunspot Light Bridges

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hou, Yijun; Zhang, Jun; Li, Ting

    Recent high-resolution observations from the Interface Region Imaging Spectrograph reveal bright wall-shaped structures in active regions (ARs), especially above sunspot light bridges. Their most prominent feature is the bright oscillating front in the 1400/1330 Å channel. These structures are named light walls and are often interpreted to be driven by p-mode waves. Above the light bridge of AR 12222 on 2014 December 06, we observed intermittent ejections superimposed on an oscillating light wall in the 1400 Å passband. At the base location of each ejection, the emission enhancement was detected in the Solar Dynamics Observatory 1600 Å channel. Thus, wemore » suggest that in wall bases (light bridges), in addition to the leaked p-mode waves consistently driving the oscillating light wall, magnetic reconnection could happen intermittently at some locations and eject the heated plasma upward. Similarly, in the second event occurring in AR 12371 on 2015 June 16, a jet was simultaneously detected in addition to the light wall with a wave-shaped bright front above the light bridge. At the footpoint of this jet, lasting brightening was observed, implying magnetic reconnection at the base. We propose that in these events, two mechanisms, p-mode waves and magnetic reconnection, simultaneously play roles in the light bridge, and lead to the distinct kinetic features of the light walls and the ejection-like activities, respectively. To illustrate the two mechanisms and their resulting activities above light bridges, in this study we present a cartoon model.« less

  14. Color stable white phosphorescent organic light emitting diodes with red emissive electron transport layer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wook Kim, Jin; Yoo, Seung Il; Sung Kang, Jin

    2015-06-28

    We analyzed the performance of multi-emissive white phosphorescent organic light-emitting diodes (PHOLEDs) in relation to various red emitting sites of hole and electron transport layers (HTL and ETL). The shift of the recombination zone producing stable white emission in PHOLEDs was utilized as luminance was increased with red emission in its electron transport layer. Multi-emissive white PHOLEDs including the red light emitting electron transport layer yielded maximum external quantum efficiency of 17.4% with CIE color coordinates (−0.030, +0.001) shifting only from 1000 to 10 000 cd/m{sup 2}. Additionally, we observed a reduction of energy loss in the white PHOLED via Ir(piq){submore » 3} as phosphorescent red dopant in electron transport layer.« less

  15. White Light Emission from Vegetable Extracts

    NASA Astrophysics Data System (ADS)

    Singh, Vikram; Mishra, Ashok K.

    2015-06-01

    A mixture of extracts from two common vegetables, red pomegranate and turmeric, when photoexcited at 380 nm, produced almost pure white light emission (WLE) with Commission Internationale d’Eclairage (CIE) chromaticity index (0.35, 0.33) in acidic ethanol. It was also possible to obtain WLE in polyvinyl alcohol film (0.32, 0.25), and in gelatin gel (0.26, 0.33) using the same extract mixture. The colour temperature of the WLE was conveniently tunable by simply adjusting the concentrations of the component emitters. The primary emitting pigments responsible for contributing to WLE were polyphenols and anthocyanins from pomegranate, and curcumin from turmeric. It was observed that a cascade of Forster resonance energy transfer involving polyphenolics, curcumin and anthocyanins played a crucial role in obtaining a CIE index close to pure white light. The optimized methods of extraction of the two primary emitting pigments from their corresponding plant sources are simple, cheap and fairly green.

  16. FAST TRACK COMMUNICATION: White light emission from chemically synthesized ZnO-porous silicon nanocomposite

    NASA Astrophysics Data System (ADS)

    Singh, R. G.; Singh, Fouran; Kanjilal, D.; Agarwal, V.; Mehra, R. M.

    2009-03-01

    White light emission across the extended visible region of the electromagnetic spectrum from the ZnO-porous silicon (PS) nanocomposite is reported. Nanocrystallites of ZnO were grown inside the spongy structures of PS by the chemical route of sol-gel spin coating. The property of the material arises from versatile interactions among the host structures of PS and ZnO. The origin of the observed extended white light emission from 1.4 to 3.3 eV is discussed by developing a flat band energy diagram.

  17. Determining the phonon energy of highly oriented pyrolytic graphite by scanning tunneling microscope light emission spectroscopy

    NASA Astrophysics Data System (ADS)

    Uehara, Yoichi; Michimata, Junichi; Watanabe, Shota; Katano, Satoshi; Inaoka, Takeshi

    2018-03-01

    We have investigated the scanning tunneling microscope (STM) light emission spectra of isolated single Ag nanoparticles lying on highly oriented pyrolytic graphite (HOPG). The STM light emission spectra exhibited two types of spectral structures (step-like and periodic). Comparisons of the observed structures and theoretical predictions indicate that the phonon energy of the ZO mode of HOPG [M. Mohr et al., Phys. Rev. B 76, 035439 (2007)] can be determined from the energy difference between the cutoff of STM light emission and the step in the former structure, and from the period of the latter structure. Since the role of the Ag nanoparticles does not depend on the substrate materials, this method will enable the phonon energies of various materials to be measured by STM light emission spectroscopy. The spatial resolution is comparable to the lateral size of the individual Ag nanoparticles (that is, a few nm).

  18. Observed Barium Emission Rates

    NASA Technical Reports Server (NTRS)

    Stenbaek-Nielsen, H. C.; Wescott, E. M.; Hallinan, T. J.

    1993-01-01

    The barium releases from the CRRES satellite have provided an opportunity for verifying theoretically calculated barium ion and neutral emission rates. Spectra of the five Caribbean releases in the summer of 1991 were taken with a spectrograph on board a U.S. Air Force jet aircraft. Because the line of sight release densities are not known, only relative rates could be obtained. The observed relative rates agree well with the theoretically calculated rates and, together with other observations, confirm the earlier detailed theoretical emission rates. The calculated emission rates can thus with good accuracy be used with photometric observations. It has been postulated that charge exchange between neutral barium and oxygen ions represents a significant source for ionization. If so. it should be associated with emissions at 4957.15 A and 5013.00 A, but these emissions were not detected.

  19. CARMA observations of Galactic cold cores: searching for spinning dust emission

    NASA Astrophysics Data System (ADS)

    Tibbs, C. T.; Paladini, R.; Cleary, K.; Muchovej, S. J. C.; Scaife, A. M. M.; Stevenson, M. A.; Laureijs, R. J.; Ysard, N.; Grainge, K. J. B.; Perrott, Y. C.; Rumsey, C.; Villadsen, J.

    2015-11-01

    We present the first search for spinning dust emission from a sample of 34 Galactic cold cores, performed using the CARMA interferometer. For each of our cores, we use photometric data from the Herschel Space Observatory to constrain bar{N}H, bar{T}d, bar{n}H, and bar{G}0. By computing the mass of the cores and comparing it to the Bonnor-Ebert mass, we determined that 29 of the 34 cores are gravitationally unstable and undergoing collapse. In fact, we found that six cores are associated with at least one young stellar object, suggestive of their protostellar nature. By investigating the physical conditions within each core, we can shed light on the cm emission revealed (or not) by our CARMA observations. Indeed, we find that only three of our cores have any significant detectable cm emission. Using a spinning dust model, we predict the expected level of spinning dust emission in each core and find that for all 34 cores, the predicted level of emission is larger than the observed cm emission constrained by the CARMA observations. Moreover, even in the cores for which we do detect cm emission, we cannot, at this stage, discriminate between free-free emission from young stellar objects and spinning dust emission. We emphasize that although the CARMA observations described in this analysis place important constraints on the presence of spinning dust in cold, dense environments, the source sample targeted by these observations is not statistically representative of the entire population of Galactic cores.

  20. Tuning the emission of ZnO nanorods based light emitting diodes using Ag doping

    NASA Astrophysics Data System (ADS)

    Echresh, Ahmad; Chey, Chan Oeurn; Shoushtari, Morteza Zargar; Nur, Omer; Willander, Magnus

    2014-11-01

    We have fabricated, characterized, and compared ZnO nanorods/p-GaN and n-Zn0.94Ag0.06O nanorods/p-GaN light emitting diodes (LEDs). Current-voltage measurement showed an obvious rectifying behaviour of both LEDs. A reduction of the optical band gap of the Zn0.94Ag0.06O nanorods compared to pure ZnO nanorods was observed. This reduction leads to decrease the valence band offset at n-Zn0.94Ag0.06O nanorods/p-GaN interface compared to n-ZnO nanorods/p-GaN heterojunction. Consequently, this reduction leads to increase the hole injection from the GaN to the ZnO. From electroluminescence measurement, white light was observed for the n-Zn0.94Ag0.06O nanorods/p-GaN heterojunction LEDs under forward bias, while for the reverse bias, blue light was observed. While for the n-ZnO nanorods/p-GaN blue light dominated the emission in both forward and reverse biases. Further, the LEDs exhibited a high sensitivity in responding to UV illumination. The results presented here indicate that doping ZnO nanorods might pave the way to tune the light emission from n-ZnO/p-GaN LEDs.

  1. Observation of Solar Wind Charge Exchange Emission From Exospheric Material in and Outside Earth's Magnetosheath 2008 September 25

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Collier, M. R.; Cravens, T.; Kuntz, K. D.; Lepri, S. T.; Robertson, I.; Tomas, L.

    2009-01-01

    A long XMM-Newton exposure is used to observe solar wind charge exchange (SWCX) emission from exospheric material in and outside Earth's magnetosheath. The light curve of the O vii (0.5-0.62 keV) band is compared with a model for the expected emission, and while the emission is faint and the light curve has considerable scatter, the correlation is significant to better than 99.9%. This result demonstrates the validity of the geocoronal SWCX emission model for predicting a contribution to astrophysical observations to a scale factor of order unity (1.5). In addition, an average value of the SWCX O vii emission from the magnetosheath over the observation of 2.6 +/- 0.5 LU is derived. The results also demonstrate the potential utility of using X-ray observations to study global phenomena of the magnetosheath which currently are only investigated using in situ measurements.

  2. Optical dosimetry of radiotherapy beams using Cherenkov radiation: the relationship between light emission and dose.

    PubMed

    Glaser, Adam K; Zhang, Rongxiao; Gladstone, David J; Pogue, Brian W

    2014-07-21

    Recent studies have proposed that light emitted by the Cherenkov effect may be used for a number of radiation therapy dosimetry applications. There is a correlation between the captured light and expected dose under certain conditions, yet discrepancies have also been observed and a complete examination of the theoretical differences has not been done. In this study, a fundamental comparison between the Cherenkov emission and absorbed dose was explored for x-ray photons, electrons, and protons using both a theoretical and Monte Carlo-based analysis. Based on the findings of where dose correlates with Cherenkov emission, it was concluded that for x-ray photons the light emission would be optimally suited for narrow beam stereotactic radiation therapy and surgery validation studies, for verification of dynamic intensity-modulated and volumetric modulated arc therapy treatment plans in water tanks, near monoenergetic sources (e.g., Co-60 and brachy therapy sources) and also for entrance and exit surface imaging dosimetry of both narrow and broad beams. For electron use, Cherenkov emission was found to be only suitable for surface dosimetry applications. Finally, for proton dosimetry, there exists a fundamental lack of Cherenkov emission at the Bragg peak, making the technique of little use, although post-irradiation detection of light emission from radioisotopes could prove to be useful.

  3. 75 FR 7426 - Tier 2 Light-Duty Vehicle and Light-Duty Truck Emission Standards and Gasoline Sulfur Control...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-02-19

    ... 2060-AI23; 2060-AQ12 Tier 2 Light-Duty Vehicle and Light-Duty Truck Emission Standards and Gasoline... February 10, 2000 (65 FR 6698), EPA published emission standards for light-duty vehicles and light-duty... new passenger cars and light trucks, including pickup trucks, vans, minivans, and sport-utility...

  4. Electron beam induced light emission

    NASA Astrophysics Data System (ADS)

    Ulrich, A.; Heindl, T.; Krücken, R.; Morozov, A.; Skrobol, C.; Wieser, J.

    2009-08-01

    Electron beams with a particle energy of typically 12keV are used for collisional excitation of dense gases. The electrons are sent through ceramic membranes of only 300nm thickness into gas targets. Excimer light emission from the pure rare gases and from gas mixtures are studied for the development of brilliant VUV and UV light sources. The application of the technology for gas kinetic studies is described and its potential for building very small electron beam pumped lasers is discussed.

  5. Real-time emission factor measurements of isocyanic acid from light duty gasoline vehicles.

    PubMed

    Brady, James M; Crisp, Timia A; Collier, Sonya; Kuwayama, Toshihiro; Forestieri, Sara D; Perraud, Véronique; Zhang, Qi; Kleeman, Michael J; Cappa, Christopher D; Bertram, Timothy H

    2014-10-07

    Exposure to gas-phase isocyanic acid (HNCO) has been previously shown to be associated with the development of atherosclerosis, cataracts and rheumatoid arthritis. As such, accurate emission inventories for HNCO are critical for modeling the spatial and temporal distribution of HNCO on a regional and global scale. To date, HNCO emission rates from light duty gasoline vehicles, operated under driving conditions, have not been determined. Here, we present the first measurements of real-time emission factors of isocyanic acid from a fleet of eight light duty gasoline-powered vehicles (LDGVs) tested on a chassis dynamometer using the Unified Driving Cycle (UC) at the California Air Resources Board (CARB) Haagen-Smit test facility, all of which were equipped with three-way catalytic converters. HNCO emissions were observed from all vehicles, in contrast to the idealized laboratory measurements. We report the tested fleet averaged HNCO emission factors, which depend strongly on the phase of the drive cycle; ranging from 0.46 ± 0.13 mg kg fuel(-1) during engine start to 1.70 ± 1.77 mg kg fuel(-1) during hard acceleration after the engine and catalytic converter were warm. The tested eight-car fleet average fuel based HNCO emission factor was 0.91 ± 0.58 mg kg fuel(-1), within the range previously estimated for light duty diesel-powered vehicles (0.21-3.96 mg kg fuel(-1)). Our results suggest that HNCO emissions from LDGVs represent a significant emission source in urban areas that should be accounted for in global and regional models.

  6. Direct observation of aqueous secondary organic aerosol from biomass-burning emissions

    PubMed Central

    Massoli, Paola; Paglione, Marco; Giulianelli, Lara; Carbone, Claudio; Rinaldi, Matteo; Decesari, Stefano; Sandrini, Silvia; Costabile, Francesca; Gobbi, Gian Paolo; Pietrogrande, Maria Chiara; Visentin, Marco; Scotto, Fabiana; Fuzzi, Sandro; Facchini, Maria Cristina

    2016-01-01

    The mechanisms leading to the formation of secondary organic aerosol (SOA) are an important subject of ongoing research for both air quality and climate. Recent laboratory experiments suggest that reactions taking place in the atmospheric liquid phase represent a potentially significant source of SOA mass. Here, we report direct ambient observations of SOA mass formation from processing of biomass-burning emissions in the aqueous phase. Aqueous SOA (aqSOA) formation is observed both in fog water and in wet aerosol. The aqSOA from biomass burning contributes to the “brown” carbon (BrC) budget and exhibits light absorption wavelength dependence close to the upper bound of the values observed in laboratory experiments for fresh and processed biomass-burning emissions. We estimate that the aqSOA from residential wood combustion can account for up to 0.1–0.5 Tg of organic aerosol (OA) per y in Europe, equivalent to 4–20% of the total OA emissions. Our findings highlight the importance of aqSOA from anthropogenic emissions on air quality and climate. PMID:27551086

  7. [Investigation of emission characteristics for light duty vehicles with a portable emission measurement system].

    PubMed

    Wang, Hai-Kun; Fu, Li-Xin; Zhou, Yu; Lin, Xin; Chen, Ai-Zhong; Ge, Wei-hu; Du, Xuan

    2008-10-01

    Emission from 7 typical light-duty vehicles under actual driving conditions was monitored using a portable emission measurement system to gather data for characterization of the real world vehicle emission in Shenzhen, including the effects of driving modes on vehicle emission, comparison of fuel consumption based emission factors (g x L(-1) with mileage based emission factors (g x km(-1)), and the average emission factors of the monitored vehicles. The acceleration and deceleration modes accounted for 66.7% of total travel time, 80.3% of traveling distance and 74.6%-79.2% of vehicle emission; the acceleration mode contributed more than other driving modes. The fuel based emission factors were less dependent on the driving speed; they may be utilized in building macro-scale vehicle emission inventory with smaller sensitivity to the vehicle driving conditions. The effect of vehicle technology on vehicle emission was significant; the emission factors of CO, HC and NO(x) of carbureted vehicles were 19.9-20.5, 5.6-26.1 and 1.8-2.0 times the more advanced vehicles of Euro II, respectively. Using the ECE + EUDC driving cycle would not produce the desired real-world emission rates of light duty vehicles in a typical Chinese city.

  8. Tailoring the chirality of light emission with spherical Si-based antennas.

    PubMed

    Zambrana-Puyalto, Xavier; Bonod, Nicolas

    2016-05-21

    Chirality of light is of fundamental importance in several enabling technologies with growing applications in life sciences, chemistry and photodetection. Recently, some attention has been focused on chiral quantum emitters. Consequently, optical antennas which are able to tailor the chirality of light emission are needed. Spherical nanoresonators such as colloids are of particular interest to design optical antennas since they can be synthesized at a large scale and they exhibit good optical properties. Here, we show that these colloids can be used to tailor the chirality of a chiral emitter. To this purpose, we derive an analytic formalism to model the interaction between a chiral emitter and a spherical resonator. We then compare the performances of metallic and dielectric spherical antennas to tailor the chirality of light emission. It is seen that, due to their strong electric dipolar response, metallic spherical nanoparticles spoil the chirality of light emission by yielding achiral fields. In contrast, thanks to the combined excitation of electric and magnetic modes, dielectric Si-based particles feature the ability to inhibit or to boost the chirality of light emission. Finally, it is shown that dual modes in dielectric antennas preserve the chirality of light emission.

  9. Laser Ablated Carbon Nanodots for Light Emission.

    PubMed

    Reyes, Delfino; Camacho, Marco; Camacho, Miguel; Mayorga, Miguel; Weathers, Duncan; Salamo, Greg; Wang, Zhiming; Neogi, Arup

    2016-12-01

    The synthesis of fluorescent carbon dots-like nanostructures (CNDs) obtained through the laser ablation of a carbon solid target in liquid environment is reported. The ablation process was induced in acetone with laser pulses of 1064, 532, and 355 nm under different irradiation times. Close-spherical amorphous CNDs with sizes between 5 and 20 nm, whose abundance strongly depends on the ablation parameters were investigated using electron microscopy and was confirmed using absorption and emission spectroscopies. The π- π* electronic transition at 3.76 eV dominates the absorption for all the CNDs species synthesized under different irradiation conditions. The light emission is most efficient due to excitation at 3.54 eV with the photoluminescence intensity centered at 3.23 eV. The light emission from the CNDs is most efficient due to ablation at 355 nm. The emission wavelength of the CNDs can be tuned from the near-UV to the green wavelength region by controlling the ablation time and modifying the ablation and excitation laser wavelength.

  10. Light-induced biophotonic emission from plant tissues.

    PubMed

    Bajpai, R P; Bajpai, P K

    1992-07-01

    The emission of biophotons in the visible range, following a delay time of 2-200 seconds after exposure to light, has been measured in germinating seeds, roots, flowers, leaves, and cells. It was found that the biophotonic signals are reproducible and light-induced. The observed signals from germinating seeds of Phaseolus aures and decaying leaves of Eucalyptus are presented to show that the signals have characteristic kinetics and intensity. The kinetics of the signal was found to be independent of the stage of growth or decay, though its intensity varied with biological factors. The kinetics in the first minute is characterized by a single exponential decay term while that in the region t less than or equal to 200 s is characterized by two exponentials. The variation in the intensity of the signal with mass, state of hydration, and growth, and the effect of inhibitors in various systems (e.g. leaves, lichen, Chlorella) are reported.

  11. The massive binary CPD - 41° 7742. II. Optical light curve and X-ray observations

    NASA Astrophysics Data System (ADS)

    Sana, H.; Antokhina, E.; Royer, P.; Manfroid, J.; Gosset, E.; Rauw, G.; Vreux, J.-M.

    2005-10-01

    In the first paper of this series, we presented a detailed high-resolution spectroscopic study of CPD - 41° 7742, deriving for the first time an orbital solution for both components of the system. In this second paper, we focus on the analysis of the optical light curve and on recent XMM-Newton X-ray observations. In the optical, the system presents two eclipses, yielding an inclination i˜77°. Combining the constraints from the photometry with the results of our previous work, we derive the absolute parameters of the system. We confirm that the two components of CPD - 41° 7742 are main sequence stars (O9 V + B1-1.5 V) with masses (M_1˜18 M⊙ and M_2˜10 M⊙) and respective radii (R_1˜7.5 R⊙ and R_2˜5.4 R⊙) close to the typical values expected for such stars. We also report an unprecedented set of X-ray observations that almost uniformly cover the 2.44-day orbital cycle. The X-ray emission from CPD - 41° 7742 is well described by a two-temperature thermal plasma model with energies close to 0.6 and 1.0 keV, thus slightly harder than typical early-type emission. The X-ray light curve shows clear signs of variability. The emission level is higher when the primary is in front of the secondary. During the high emission state, the system shows a drop of its X-ray emission that almost exactly matches the optical eclipse. We interpret the main features of the X-ray light curve as the signature of a wind-photosphere interaction, in which the overwhelming primary O9 star wind crashes into the secondary surface. Alternatively the light curve could result from a wind-wind interaction zone located near the secondary star surface. As a support to our interpretation, we provide a phenomenological geometric model that qualitatively reproduces the observed modulations of the X-ray emission.

  12. 40 CFR 86.1709-99 - Exhaust emission standards for 1999 and later light light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86.1709-99 Exhaust emission standards for... not exceed the standards in Tables R99-8 and R99-9 in rows designated with the applicable vehicle...

  13. A Modeling Framework for Inference of Surface Emissions Using Mobile Observations

    NASA Astrophysics Data System (ADS)

    Fasoli, B.; Mitchell, L.; Crosman, E.; Mendoza, D. L.; Lin, J. C.

    2016-12-01

    Our ability to quantify surface emissions depends on the precision of observations and the spatial density of measurement networks. Mobile measurement techniques offer a cost effective strategy for quantifying atmospheric conditions over space without requiring a dense network of in-situ sites. However, interpretation of these data and inversion of dispersed measurements to estimate surface emissions can be difficult. We introduce a framework using the Stochastic Time-Inverted Lagrangian Transport (STILT) model that assimilates both spatially resolved observations and an emissions inventory to better estimate surface fluxes. Salt Lake City is a unique laboratory for the study of urban carbon emissions. It is the only U.S. city that utilizes light-rail trains to continuously measure high frequency carbon dioxide (CO2) and methane (CH4); it is home to one of the longest and most spatially resolved high precision CO2 measurement networks (air.utah.edu); and it is one of four cities in the world for which the Hestia anthropogenic emissions inventory has been produced which characterizes CO2 emissions at the scale of individual buildings and roadways. Using these data and modeling resources, we evaluate spatially resolved CO2 measurements and transported CO2 emissions on hourly timescales at a dense spatial resolution across Salt Lake City.

  14. Organic light emitting device having multiple separate emissive layers

    DOEpatents

    Forrest, Stephen R [Ann Arbor, MI

    2012-03-27

    An organic light emitting device having multiple separate emissive layers is provided. Each emissive layer may define an exciton formation region, allowing exciton formation to occur across the entire emissive region. By aligning the energy levels of each emissive layer with the adjacent emissive layers, exciton formation in each layer may be improved. Devices incorporating multiple emissive layers with multiple exciton formation regions may exhibit improved performance, including internal quantum efficiencies of up to 100%.

  15. Two-dimensionally grown single-crystal silicon nanosheets with tunable visible-light emissions.

    PubMed

    Kim, Sung Wook; Lee, Jaejun; Sung, Ji Ho; Seo, Dong-jae; Kim, Ilsoo; Jo, Moon-Ho; Kwon, Byoung Wook; Choi, Won Kook; Choi, Heon-Jin

    2014-07-22

    Since the discovery of graphene, growth of two-dimensional (2D) nanomaterials has greatly attracted attention. However, spontaneous growth of atomic two-dimensional (2D) materials is limitedly permitted for several layered-structure crystals, such as graphene, MoS2, and h-BN, and otherwise it is notoriously difficult. Here we report the gas-phase 2D growth of silicon (Si), that is cubic in symmetry, via dendritic growth and an interdendritic filling mechanism and to form Si nanosheets (SiNSs) of 1 to 13 nm in thickness. Thin SiNSs show strong thickness-dependent photoluminescence in visible range including red, green, and blue (RGB) emissions with the associated band gap energies ranging from 1.6 to 3.2 eV; these emission energies were greater than those from Si quantum dots (SiQDs) of the similar sizes. We also demonstrated that electrically driven white, as well as blue, emission in a conventional organic light-emitting diode (OLED) geometry with the SiNS assembly as the active emitting layers. Tunable light emissions in visible range in our observations suggest practical implications for novel 2D Si nanophotonics.

  16. 40 CFR 86.1811-09 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-09 Section 86.1811-09 Protection of... Vehicles § 86.1811-09 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

  17. 40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of... Vehicles § 86.1811-10 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

  18. 40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of... Vehicles § 86.1811-10 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

  19. 40 CFR 86.1811-09 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-09 Section 86.1811-09 Protection of... Vehicles § 86.1811-09 Emission standards for light-duty vehicles, light-duty trucks and medium-duty...

  20. Light Emission by Nonequilibrium Bodies: Local Kirchhoff Law

    NASA Astrophysics Data System (ADS)

    Greffet, Jean-Jacques; Bouchon, Patrick; Brucoli, Giovanni; Marquier, François

    2018-04-01

    The goal of this paper is to introduce a local form of Kirchhoff law to model light emission by nonequilibrium bodies. While absorption by a finite-size body is usually described using the absorption cross section, we introduce a local absorption rate per unit volume and also a local thermal emission rate per unit volume. Their equality is a local form of Kirchhoff law. We revisit the derivation of this equality and extend it to situations with subsystems in local thermodynamic equilibrium but not in equilibrium between them, such as hot electrons in a metal or electrons with different Fermi levels in the conduction band and in the valence band of a semiconductor. This form of Kirchhoff law can be used to model (i) thermal emission by nonisothermal finite-size bodies, (ii) thermal emission by bodies with carriers at different temperatures, and (iii) spontaneous emission by semiconductors under optical (photoluminescence) or electrical pumping (electroluminescence). Finally, we show that the reciprocity relation connecting light-emitting diodes and photovoltaic cells derived by Rau is a particular case of the local Kirchhoff law.

  1. Mechanism of Prism-Coupled Scanning Tunneling Microscope Light Emission

    NASA Astrophysics Data System (ADS)

    Iida, Wataru; Ahamed, Jamal U.; Katano, Satoshi; Uehara, Yoichi

    2011-09-01

    We have investigated the mechanism of scanning tunneling microscope light emission (STM-LE) in a prism-coupled configuration using finite difference time domain analysis. In this configuration, the sample is a metallic thin film evaporated on the bottom surface of a hemispherical glass prism. STM light emitted into the prism (prism-side emission) through the metallic film is measured. Since both localized surface plasmons (LSP) and surface plasmon polaritons (SPP) contribute to prism-side emission, this emission is stronger than that in conventional STM-LE measured from the sample surface side, which is radiated by LSP alone. We show that the spatial resolution of prism-side emission is determined not by the propagation length of SPP, but by the lateral size of LSP, similarly to conventional (i.e., tip side) STM-LE. Thus, we conclude that, by using the prism-coupled configuration, the signal level of STM-LE improves without the loss of spatial resolution attained in tip side emission.

  2. Blue light emission from the heterostructured ZnO/InGaN/GaN

    PubMed Central

    2013-01-01

    ZnO/InGaN/GaN heterostructured light-emitting diodes (LEDs) were fabricated by molecular beam epitaxy and atomic layer deposition. InGaN films consisted of an Mg-doped InGaN layer, an undoped InGaN layer, and a Si-doped InGaN layer. Current-voltage characteristic of the heterojunction indicated a diode-like rectification behavior. The electroluminescence spectra under forward biases presented a blue emission accompanied by a broad peak centered at 600 nm. With appropriate emission intensity ratio, the heterostructured LEDs had potential application in white LEDs. Moreover, a UV emission and an emission peak centered at 560 nm were observed under reverse bias. PMID:23433236

  3. Observations of a White-light Flare Associated with a Filament Eruption

    NASA Astrophysics Data System (ADS)

    Song, Y. L.; Guo, Y.; Tian, H.; Zhu, X. S.; Zhang, M.; Zhu, Y. J.

    2018-02-01

    We present observations of an M5.7 white-light flare (WLF) associated with a small filament eruption in NOAA active region 11476 on 2012 May 10. During this flare, a circular flare ribbon appeared in the east and a remote brightening occurred in the northwest of the active region. Multi-wavelength data are employed to analyze the WLF, including white light (WL), ultraviolet, extreme ultraviolet, hard X-ray (HXR), and microwave. A close spatial and temporal relationship between the WL, HXR, and microwave emissions is found in this WLF. However, the peak time of the WL emission lagged that of the HXR and microwave emissions by about 1–2 minutes. Such a result tends to support the backwarming mechanism for the WL emission. Interestingly, the enhanced WL emission occurred at the two footpoints of the filament. Through forced and potential field extrapolations, we find that the 3D magnetic field in the flare region has a fan-spine feature and that a flux rope lies under the dome-like field structure. We describe the entire process of flare evolution into several steps, each one producing the sequent brightening below the filament, the circular flare ribbons, and the WL enhancement, respectively. We suggest that a reconnection between the magnetic field of the filament and the overlying magnetic field or reconnection within the flux rope leads to the WL enhancement.

  4. Multi-band Emission Light Curves of Jupiter: Insights on Brown Dwarfs and Directly Imaged Exoplanets

    NASA Astrophysics Data System (ADS)

    Zhang, Xi; Ge, Huazhi; Orton, Glenn S.; Fletcher, Leigh N.; Sinclair, James; Fernandes, Joshua; Momary, Thomas W.; Kasaba, Yasumasa; Sato, Takao M.; Fujiyoshi, Takuya

    2016-10-01

    Many brown dwarfs exhibit significant infrared flux variability (e.g., Artigau et al. 2009, ApJ, 701, 1534; Radigan et al. 2012, ApJ, 750, 105), ranging from several to twenty percent of the brightness. Current hypotheses include temperature variations, cloud holes and patchiness, and cloud height and thickness variations (e.g., Apai et al. 2013, ApJ, 768, 121; Robinson and Marley 2014, ApJ, 785, 158; Zhang and Showman 2014, ApJ, 788, L6). Some brown dwarfs show phase shifts in the light curves among different wavelengths (e.g., Buenzli et al. 2012, ApJ, 760, L31; Yang et al. 2016, arXiv:1605.02708), indicating vertical variations of the cloud distribution. The current observational technique can barely detect the brightness changes on the surfaces of nearby brown dwarfs (Crossfield et al. 2014, Nature, 505, 654) let alone resolve detailed weather patterns that cause the flux variability. The infrared emission maps of Jupiter might shed light on this problem. Using COMICS at Subaru Telescope, VISIR at Very Large Telescope (VLT) and NASA's Infrared Telescope Facility (IRTF), we obtained infrared images of Jupiter over several nights at multiple wavelengths that are sensitive to several pressure levels from the stratosphere to the deep troposphere below the ammonia clouds. The rotational maps and emission light curves are constructed. The individual pixel brightness varies up to a hundred percent level and the variation of the full-disk brightness is around several percent. Both the shape and amplitude of the light curves are significantly distinct at different wavelengths. Variation of light curves at different epochs and phase shift among different wavelengths are observed. We will present principle component analysis to identify dominant emission features such as stable vortices, cloud holes and eddies in the belts and zones and strong emissions in the aurora region. A radiative transfer model is used to simulate those features to get a more quantitative

  5. Real-time black carbon emission factor measurements from light duty vehicles.

    PubMed

    Forestieri, Sara D; Collier, Sonya; Kuwayama, Toshihiro; Zhang, Qi; Kleeman, Michael J; Cappa, Christopher D

    2013-11-19

    Eight light-duty gasoline low emission vehicles (LEV I) were tested on a Chassis dynamometer using the California Unified Cycle (UC) at the Haagen-Smit vehicle test facility at the California Air Resources Board in El Monte, CA during September 2011. The UC includes a cold start phase followed by a hot stabilized running phase. In addition, a light-duty gasoline LEV vehicle and ultralow emission vehicle (ULEV), and a light-duty diesel passenger vehicle and gasoline direct injection (GDI) vehicle were tested on a constant velocity driving cycle. A variety of instruments with response times ≥0.1 Hz were used to characterize how the emissions of the major particulate matter components varied for the LEVs during a typical driving cycle. This study focuses primarily on emissions of black carbon (BC). These measurements allowed for the determination of BC emission factors throughout the driving cycle, providing insights into the temporal variability of BC emission factors during different phases of a typical driving cycle.

  6. Effect of clustering on the emission of light charged particles

    NASA Astrophysics Data System (ADS)

    Kundu, Samir; Bhattacharya, C.; Rana, T. K.; Bhattacharya, S.; Pandey, R.; Banerjee, K.; Roy, Pratap; Meena, J. K.; Mukherjee, G.; Ghosh, T. K.; Mukhopadhyay, S.; Saha, A. K.; Sahoo, J. K.; Mandal Saha, R.; Srivastava, V.; Sinha, M.; Asgar, Md. A.

    2018-04-01

    Energy spectra of light charged particles emitted in the reaction p + {}^{27}Al → {}^{28}Si^{\\ast} have been studied and compared with statistical model calculation. Unlike 16O + 12C where a large deformation was observed in 28Si*, the energy spectra of α-particles were well explained by the statistical model calculation with standard "deformability parameters" obtained using the rotating liquid drop model. It seems that the α-clustering in the entrance channel causes extra deformation in 28Si* in the case of 16O + 12C, but the reanalysis of other published data shows that there are several cases where extra deformation was observed for composites produced via non-α-cluster entrance channels also. An empirical relation was found between mass-asymmetry in the entrance channel and deformation, which indicates that along with α-clustering, mass-asymmetry may also affect the emission of a light charged particle.

  7. EXHAUST EMISSION PATTERNS FROM TWO LIGHT-DUTY DIESEL AUTOMOBILES

    EPA Science Inventory

    Particulate and gaseous emissions from two light-duty diesel automobiles were examined over six operating cycles. Particulate characterizations included mass emission rate, soluble organic content, and trace element content determinations. The particulate matter was sampled using...

  8. Unique visible-light-assisted field emission of tetrapod-shaped ZnO/reduced graphene-oxide core/coating nanocomposites

    PubMed Central

    Wu, Chaoxing; Kim, Tae Whan; Guo, Tailiang; Li, Fushan

    2016-01-01

    The electronic and the optoelectronic properties of graphene-based nanocomposites are controllable, making them promising for applications in diverse electronic devices. In this work, tetrapod-shaped zinc oxide (T-ZnO)/reduced graphene oxide (rGO) core/coating nanocomposites were synthesized by using a hydrothermal-assisted self-assemble method, and their optical, photoelectric, and field-emission properties were investigated. The ZnO, an ideal ultraviolet-light-sensitive semiconductor, was observed to have high sensitivity to visible light due to the rGO coating, and the mechanism of that sensitivity was investigated. We demonstrated for the first time that the field-emission properties of the T-ZnO/rGO core/coating nanocomposites could be dramatically enhanced under visible light by decreasing the turn-on field from 1.54 to 1.41 V/μm and by increasing the current density from 5 to 12 mA/cm2 at an electric field of 3.5 V/μm. The visible-light excitation induces an electron jump from oxygen vacancies on the surface of ZnO to the rGO layer, resulting in a decrease in the work function of the rGO and an increase in the emission current. Furthermore, a field-emission light-emitting diode with a self-enhanced effect was fabricated making full use of the photo-assisted field-emission process. PMID:27941822

  9. Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

    NASA Astrophysics Data System (ADS)

    Hua, Wang; Du, Xiaogang; Su, Wenming; Lin, Wenjing; Zhang, Dongyu

    2014-02-01

    In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4'-N,N'-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N')iridium(III) (Ir(2-phq)3) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2']picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m2. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37) as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

  10. SPECIATED VOC EMISSIONS FROM MODERN GDI LIGHT DUTY VEHICLES

    EPA Science Inventory

    Chassis dynamometer emissions testing was conducted to characterize speciated volatile organic compounds (VOCs), including mobile source air toxics (MSATs) and ozone precursors, in exhaust emissions from three modern gasoline direct injection (GDI) light-duty vehicles. Each GDI v...

  11. Laboratory and field measurements of enantiomeric monoterpene emissions as a function of chemotype, light and temperature

    NASA Astrophysics Data System (ADS)

    Song, W.; Staudt, M.; Bourgeois, I.; Williams, J.

    2013-10-01

    Plants emit significant amounts of monoterpenes into the Earth's atmosphere where they react rapidly to form a multitude of gas phase species and particles. Many monoterpenes exist in mirror images forms or enantiomers. In this study the enantiomeric monoterpene profile for several representative plants (Quercus ilex L., Rosmarinus officinalis L., and Pinus halepensis Mill.) was investigated as a function of chemotype, light and temperature both in the laboratory and in the field. Analysis of enantiomeric monoterpenes from 19 Quercus ilex individuals from Southern France and Spain revealed four regiospecific chemotypes (genetically fixed emission patterns). In agreement with previous work, only Quercus ilex emissions increased strongly with light. However, for all three plant species no consistent enantiomeric variation was observed as a function of light, and the enantiomeric ratio of α-pinene was found vary by less than 20% from 100 and 1000 μmol m-2 s-1 PAR. The rate of monoterpene emission increased with temperature from all three plant species, but little variation in the enantiomeric distribution of α-pinene was observed with temperature. There was more enantiomeric variability between individuals of the same species than could be induced by either light or temperature. Field measurements of α-pinene enantiomer mixing ratios in the air taken at a Quercus ilex forest in Southern France, and several other previously reported field enantiomeric ratio diel cycle profiles are compared. All show smoothly varying diel cycles (some positive and some negative) even over changing wind directions. This is surprising in comparison with variations of enantiomeric emission patterns shown by individuals of the same species.

  12. [Real world instantaneous emission simulation for light-duty diesel vehicle].

    PubMed

    Huang, Cheng; Chen, Chang-Hong; Dai, Pu; Li, Li; Huang, Hai-Ying; Cheng, Zhen; Jia, Ji-Hong

    2008-10-01

    Core architecture and input parameters of CMEM model were introduced to simulation the second by second vehicle emission rate on real world by taking a light-duty diesel car as a case. On-board test data by a portable emission measurement system were then used to validate the simulation results. Test emission factors of CO, THC, NO(x) and CO2 were respectively 0.81, 0.61, 2.09, and 193 g x km(-1), while calculated emission factors were 0.75, 0.47, 2.47, and 212 g x km(-1). The correlation coefficients reached 0.69, 0.69, 0.75, and 0.72. Simulated instantaneous emissions of the light duty diesel vehicle by CMEM model were strongly coherent with the transient driving cycle. By analysis, CO, THC, NO(x), and CO2 emissions would be reduced by 50%, 47%, 45%, and 44% after improving the traffic situation at the intersection. The result indicated that it is necessary and feasible to simulate the instantaneous emissions of mixed vehicle fleet in some typical traffic areas by the micro-scale vehicle emission model.

  13. AMMONIA EMISSIONS FROM THE EPA'S LIGHT DUTY TEST VEHICLE

    EPA Science Inventory

    The paper discusses measurements of ammonia (NH3) emissions from EPA's light duty test vehicle while operated on a dynamometer. The vehicle's (1993 Chevrolet equipped with a three-way catalyst) emissions were measured for three transient (urban driving, highway fuel economy, and ...

  14. Light-absorbing organic carbon from prescribed and laboratory biomass burning and gasoline vehicle emissions.

    PubMed

    Xie, Mingjie; Hays, Michael D; Holder, Amara L

    2017-08-04

    Light-absorbing organic carbon (OC), also termed brown carbon (BrC), from laboratory-based biomass burning (BB) has been studied intensively to understand the contribution of BB to radiative forcing. However, relatively few measurements have been conducted on field-based BB and even fewer measurements have examined BrC from anthropogenic combustion sources like motor vehicle emissions. In this work, the light absorption of methanol-extractable OC from prescribed and laboratory BB and gasoline vehicle emissions was examined using spectrophotometry. The light absorption of methanol extracts showed a strong wavelength dependence for both BB and gasoline vehicle emissions. The mass absorption coefficients at 365 nm (MAC 365 , m 2 g -1 C) - used as a measurement proxy for BrC - were significantly correlated (p < 0.05) to the elemental carbon (EC)/OC ratios when examined by each BB fuel type. No significant correlation was observed when pooling fuels, indicating that both burn conditions and fuel types may impact BB BrC characteristics. The average MAC 365 of gasoline vehicle emission samples is 0.62 ± 0.76 m 2  g -1 C, which is similar in magnitude to the BB samples (1.27 ± 0.76 m 2  g -1 C). These results suggest that in addition to BB, gasoline vehicle emissions may also be an important BrC source in urban areas.

  15. Multiwavelength Observations of GRB 110731A: GeV Emission from Onset to Afterglow

    NASA Astrophysics Data System (ADS)

    Ackermann, M.; Ajello, M.; Asano, K.; Baldini, L.; Barbiellini, G.; Baring, M. G.; Bastieri, D.; Bellazzini, R.; Blandford, R. D.; Bonamente, E.; Borgland, A. W.; Bottacini, E.; Bregeon, J.; Brigida, M.; Bruel, P.; Buehler, R.; Buson, S.; Caliandro, G. A.; Cameron, R. A.; Caraveo, P. A.; Cecchi, C.; Charles, E.; Chaves, R. C. G.; Chekhtman, A.; Chiang, J.; Ciprini, S.; Claus, R.; Cohen-Tanugi, J.; Conrad, J.; Cutini, S.; D'Ammando, F.; de Angelis, A.; de Palma, F.; Dermer, C. D.; Silva, E. do Couto e.; Drell, P. S.; Drlica-Wagner, A.; Favuzzi, C.; Fegan, S. J.; Focke, W. B.; Franckowiak, A.; Fukazawa, Y.; Fusco, P.; Gargano, F.; Gasparrini, D.; Gehrels, N.; Giglietto, N.; Giordano, F.; Giroletti, M.; Glanzman, T.; Godfrey, G.; Granot, J.; Greiner, J.; Grenier, I. A.; Grove, J. E.; Guiriec, S.; Hadasch, D.; Hanabata, Y.; Hayashida, M.; Hays, E.; Hughes, R. E.; Jackson, M. S.; Jogler, T.; Jóhannesson, G.; Johnson, A. S.; Knödlseder, J.; Kocevski, D.; Kuss, M.; Lande, J.; Larsson, S.; Latronico, L.; Longo, F.; Loparco, F.; Lovellette, M. N.; Lubrano, P.; Mazziotta, M. N.; McEnery, J. E.; Mehault, J.; Mészáros, P.; Michelson, P. F.; Mitthumsiri, W.; Mizuno, T.; Monte, C.; Monzani, M. E.; Moretti, E.; Morselli, A.; Moskalenko, I. V.; Murgia, S.; Naumann-Godo, M.; Norris, J. P.; Nuss, E.; Nymark, T.; Ohno, M.; Ohsugi, T.; Omodei, N.; Orienti, M.; Orlando, E.; Paneque, D.; Perkins, J. S.; Pesce-Rollins, M.; Piron, F.; Pivato, G.; Racusin, J. L.; Rainò, S.; Rando, R.; Razzano, M.; Razzaque, S.; Reimer, A.; Reimer, O.; Romoli, C.; Roth, M.; Ryde, F.; Sanchez, D. A.; Sgrò, C.; Siskind, E. J.; Sonbas, E.; Spinelli, P.; Stamatikos, M.; Takahashi, H.; Tanaka, T.; Thayer, J. G.; Thayer, J. B.; Tibaldo, L.; Tinivella, M.; Tosti, G.; Troja, E.; Usher, T. L.; Vandenbroucke, J.; Vasileiou, V.; Vianello, G.; Vitale, V.; Waite, A. P.; Winer, B. L.; Wood, K. S.; Yang, Z.; Gruber, D.; Bhat, P. N.; Bissaldi, E.; Briggs, M. S.; Burgess, J. M.; Connaughton, V.; Foley, S.; Kippen, R. M.; Kouveliotou, C.; McBreen, S.; McGlynn, S.; Paciesas, W. S.; Pelassa, V.; Preece, R.; Rau, A.; van der Horst, A. J.; von Kienlin, A.; Kann, D. A.; Filgas, R.; Klose, S.; Krühler, T.; Fukui, A.; Sako, T.; Tristram, P. J.; Oates, S. R.; Ukwatta, T. N.; Littlejohns, O.

    2013-02-01

    We report on the multiwavelength observations of the bright, long gamma-ray burst GRB 110731A, by the Fermi and Swift observatories, and by the MOA and GROND optical telescopes. The analysis of the prompt phase reveals that GRB 110731A shares many features with bright Large Area Telescope bursts observed by Fermi during the first three years on-orbit: a light curve with short time variability across the whole energy range during the prompt phase, delayed onset of the emission above 100 MeV, extra power-law component and temporally extended high-energy emission. In addition, this is the first GRB for which simultaneous GeV, X-ray, and optical data are available over multiple epochs beginning just after the trigger time and extending for more than 800 s, allowing temporal and spectral analysis in different epochs that favor emission from the forward shock in a wind-type medium. The observed temporally extended GeV emission is most likely part of the high-energy end of the afterglow emission. Both the single-zone pair transparency constraint for the prompt signal and the spectral and temporal analysis of the forward-shock afterglow emission independently lead to an estimate of the bulk Lorentz factor of the jet Γ ~ 500-550.

  16. Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hua, Wang, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Du, Xiaogang; Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024

    2014-02-15

    In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4{sup ′}-N,N{sup ′}-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N{sup ′})iridium(III) (Ir(2-phq){sub 3}) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2{sup ′}]picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m{sup 2}. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37)more » as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.« less

  17. Gamma-Ray Burst Prompt Emission Light Curves and Power Density Spectra in the ICMART Model

    NASA Astrophysics Data System (ADS)

    Zhang, Bo; Zhang, Bing

    2014-02-01

    In this paper, we simulate the prompt emission light curves of gamma-ray bursts (GRBs) within the framework of the Internal-Collision-induced MAgnetic Reconnection and Turbulence (ICMART) model. This model applies to GRBs with a moderately high magnetization parameter σ in the emission region. We show that this model can produce highly variable light curves with both fast and slow components. The rapid variability is caused by many locally Doppler-boosted mini-emitters due to turbulent magnetic reconnection in a moderately high σ flow. The runaway growth and subsequent depletion of these mini-emitters as a function of time define a broad slow component for each ICMART event. A GRB light curve is usually composed of multiple ICMART events that are fundamentally driven by the erratic GRB central engine activity. Allowing variations of the model parameters, one is able to reproduce a variety of light curves and the power density spectra as observed.

  18. Monoterpene and sesquiterpene emissions from Quercus coccifera exhibit interacting responses to light and temperature

    NASA Astrophysics Data System (ADS)

    Staudt, M.; Lhoutellier, L.

    2011-09-01

    Light and temperature are known to be the most important environmental factors controlling biogenic volatile organic compound (BVOC) emissions from plants, but little is known about their interdependencies especially for BVOCs other than isoprene. We studied light responses at different temperatures and temperature responses at different light levels of foliar BVOC emissions, photosynthesis and chlorophyll fluorescence on Quercus coccifera, an evergreen oak widespread in Mediterranean shrublands. More than 50 BVOCs were detected in the emissions from Q. coccifera leaves most of them being isoprenoids plus a few green leaf volatiles (GLVs). Under standard conditions non-oxygenated monoterpenes (MT-hc) accounted for about 90% of the total BVOC release (mean ± SD: 738 ± 378 ng m-2 projected leaf area s-1 or 13.1 ± 6.9 μg g-1 leaf dry weight h-1) and oxygenated monoterpenes (MT-ox) and sesquiterpenes (SQTs) accounted for the rest in about equal proportions. Except GLVs, emissions of all BVOCs responded positively to light and temperature. The light responses of MT and SQT emissions resembled that of CO2-assimilation and were little influenced by the assay temperature: at high assay temperature, MT-hc emissions saturated at lower light levels than at standard assay temperature and tended even to decrease in the highest light range. The emission responses to temperature showed mostly Arrhenius-type response curves, whose shapes in the high temperature range were clearly affected by the assay light level and were markedly different between isoprenoid classes: at non-saturating light, all isoprenoids showed a similar temperature optimum (~43 °C), but, at higher temperatures, MT-hc emissions decreased faster than MT-ox and SQT emissions. At saturating light, MT-hc emissions peaked around 37 °C and rapidly dropped at higher temperatures, whereas MT-ox and SQT emissions strongly increased between 40 and 50 °C accompanied by a burst of GLVs. In all experiments

  19. Monoterpene and sesquiterpene emissions from Quercus coccifera exhibit interacting responses to light and temperature

    NASA Astrophysics Data System (ADS)

    Staudt, M.; Lhoutellier, L.

    2011-06-01

    Light and temperature are known to be the most important environmental factors controlling biogenic volatile organic compound (BVOC) emissions from plants, but little is known about their interdependencies especially for BVOCs other than isoprene. We studied light responses at different temperatures and temperature responses at different light levels of foliar BVOC emissions, photosynthesis and chlorophyll fluorescence on Quercus coccifera, an evergreen oak widespread in Mediterranean shrublands. More than 50 BVOCs were detected in the emissions from Q. coccifera leaves most of them being isoprenoids plus a few green leaf volatiles (GLVs). Under standard conditions non-oxygenated monoterpenes (MT-hc) accounted for about 90 % of the total BVOC release (mean ± SD: 738 ± 378 ng m-2 projected leaf area s-1 or 13.1 ± 6.9 μg g-1 leaf dry weight h-1) and oxygenated monoterpenes (MT-ox) and sesquiterpenes (SQTs) accounted for the rest in about equal proportions. Except GLVs, emissions of all BVOCs responded positively to light and temperature. The light responses of MT and SQT emissions resembled that of CO2-assimilation and were little influenced by the assay temperature: at high assay temperature, MT-hc emissions saturated at lower light levels than at standard assay temperature and tended even to decrease in the highest light range. The emission responses to temperature showed mostly Arrhenius-type response curves, whose shapes in the high temperature range were clearly affected by the assay light level and were markedly different between isoprenoid classes: at non-saturating light, all isoprenoids showed a similar temperature optimum (~43 °C), but, at higher temperatures, MT-hc emissions decreased faster than MT-ox and SQT emissions. At saturating light, MT-hc emissions peaked already around 37 °C and rapidly dropped at higher temperatures, whereas MT-ox and SQT emissions strongly increased between 40 and 50 °C accompanied by a burst of GLVs. In all experiments

  20. Relaxation dynamics of light-induced photon emission by mammalian cells and nuclei

    NASA Astrophysics Data System (ADS)

    Van Wijk, R.; Van Aken, J. M.; Laerdal, H. E.; Souren, J. E. M.

    1995-12-01

    Photon emission from mammalian cells has been the subject of study for many years. Throughout the history of this field of research the question of a functional biological role of the low intensity emission has been repeatedly raised. The discussion concerns the possible participation of biophotons in intra- and intercellular communication. In this paper we consider the significance of the studies on light-induced photon emission of isolated mammalian cells. Furthermore we report on the source of this light-induced photon emission.

  1. White light emission and optical gains from a Si nanocrystal thin film

    NASA Astrophysics Data System (ADS)

    Wang, Dong-Chen; Hao, Hong-Chen; Chen, Jia-Rong; Zhang, Chi; Zhou, Jing; Sun, Jian; Lu, Ming

    2015-11-01

    We report a Si nanocrystal thin film consisting of free-standing Si nanocrystals, which can emit white light and show positive optical gains for its red, green and blue (RGB) components under ultraviolet excitation. Si nanocrystals with ϕ = 2.31 ± 0.35 nm were prepared by chemical etching of Si powder, followed by filtering. After being mixed with SiO2 sol-gel and thermally annealed, a broadband photoluminescence (PL) from the thin film was observed. The RGB ratio of the PL can be tuned by changing the annealing temperature or atmosphere, which is 1.00/3.26/4.59 for the pure white light emission. The origins of the PL components could be due to differences in oxygen-passivation degree for Si nanocrystals. The results may find applications in white-light Si lasing and Si lighting.

  2. Laboratory and field measurements of enantiomeric monoterpene emissions as a function of chemotype, light and temperature

    NASA Astrophysics Data System (ADS)

    Song, W.; Staudt, M.; Bourgeois, I.; Williams, J.

    2014-03-01

    Plants emit significant amounts of monoterpenes into the earth's atmosphere, where they react rapidly to form a multitude of gas phase species and particles. Many monoterpenes exist in mirror-image forms or enantiomers. In this study the enantiomeric monoterpene profile for several representative plants (Quercus ilex L., Rosmarinus officinalis L., and Pinus halepensis Mill.) was investigated as a function of chemotype, light and temperature both in the laboratory and in the field. Analysis of enantiomeric monoterpenes from 19 Quercus ilex individuals from Southern France and Spain revealed four regiospecific chemotypes (genetically fixed emission patterns). In agreement with previous work, only Quercus ilex emissions increased strongly with light. However, for all three plant species no consistent enantiomeric variation was observed as a function of light, and the enantiomeric ratio of α-pinene was found to vary by less than 20% from 100 and 1000 μmol m-2 s-1 PAR (photosynthetically active radiation). The rate of monoterpene emission increased with temperature from all three plant species, but little variation in the enantiomeric distribution of α-pinene was observed with temperature. There was more enantiomeric variability between individuals of the same species than could be induced by either light or temperature. Field measurements of α-pinene enantiomer mixing ratios in the air, taken at a Quercus ilex forest in Southern France, and several other previously reported field enantiomeric ratio diel cycle profiles are compared. All show smoothly varying diel cycles (some positive and some negative) even over changing wind directions. This is surprising in comparison with variations of enantiomeric emission patterns shown by individuals of the same species.

  3. Fiber optic light collection system for scanning-tunneling-microscope-induced light emission.

    PubMed

    Watkins, Neil J; Long, James P; Kafafi, Zakya H; Mäkinen, Antti J

    2007-05-01

    We report a compact light collection scheme suitable for retrofitting a scanning tunneling microscope (STM) for STM-induced light emission experiments. The approach uses a pair of optical fibers with large core diameters and high numerical apertures to maximize light collection efficiency and to moderate the mechanical precision required for alignment. Bench tests indicate that efficiency reduction is almost entirely due to reflective losses at the fiber ends, while losses due to fiber misalignment have virtually been eliminated. Photon-map imaging with nanometer features is demonstrated on a stepped Au(111) surface with signal rates exceeding 10(4) counts/s.

  4. Tuning of the emission color of organic light emitting diodes via smartly designed aluminum plasmonics

    NASA Astrophysics Data System (ADS)

    Auer-Berger, Manuel; Tretnak, Veronika; Wenzl, Franz-Peter; Krenn, Joachim; List-Kratochvil, Emil J. W.

    2017-02-01

    With the invention of phosphorescent emitter material, organic light emitting diodes with internal quantum yields of up to 100% can be realized. Still, the extraction of the light from the OLED stack is a bottleneck, which hampers the availability of OLEDs with large external quantum efficiencies. In this contribution, we highlight the advantages of integrating aluminum nanodisc arrays into the OLED stack. By this, not only the out-coupling of light can be enhanced, but also the emission color can be tailored and controlled. By means of extinction- and fluorescence spectroscopy measurements we are able to show how the sharp features observed in the extinction measurements correlate with a very selective fluorescence enhancement of the organic emitter materials used in these studies. At the same time, localized surface plasmon resonances of the individual nanodiscs further modify the emission spectrum, e.g., by filtering the green emission tail. A combination of these factors leads to a modification of the emission color in between CIE1931 (x,y) chromaticity coordinates of (0.149, 0.225) and (0.152, 0.352). After accounting for the sensitivity of the human eye, we are able to demonstrate that this adjustment of the chromaticity coordinates goes is accompanied by an increase in device efficiency.

  5. Material system for tailorable white light emission and method for making thereof

    DOEpatents

    Smith, Christine A.; Lee, Howard W.

    2004-08-10

    A method of processing a composite material to tailor white light emission of the resulting composite during excitation. The composite material is irradiated with a predetermined power and for a predetermined time period to reduce the size of a plurality of nanocrystals and the number of a plurality of traps in the composite material. By this irradiation process, blue light contribution from the nanocrystals to the white light emission is intensified and red and green light contributions from the traps are decreased.

  6. Material system for tailorable white light emission and method for making thereof

    DOEpatents

    Smith, Christine A [Livermore, CA; Lee, Howard W. H. [Fremont, CA

    2009-05-19

    A method of processing a composite material to tailor white light emission of the resulting composite during excitation. The composite material is irradiated with a predetermined power and for a predetermined time period to reduce the size of a plurality of nanocrystals and the number of a plurality of traps in the composite material. By this irradiation process, blue light contribution from the nanocrystals to the white light emission is intensified and red and green light contributions from the traps are decreased.

  7. Weak light emission of soft tissues induced by heating

    NASA Astrophysics Data System (ADS)

    Spinelli, Antonello E.; Durando, Giovanni; Boschi, Federico

    2018-04-01

    The main goal of this work is to show that soft tissue interaction with high-intensity focused ultrasound (HIFU) or direct heating leads to a weak light emission detectable using a small animal optical imaging system. Our results show that the luminescence signal is detectable after 30 min of heating, resembling the time scale of delayed luminescence. The imaging of a soft tissue after heating it using an HIFU field shows that the luminescence pattern closely matches the shape of the cone typical of the HIFU beam. We conclude that heating a soft tissue using two different sources leads to the emission of a weak luminescence signal from the heated region with a decay half-life of a few minutes (4 to 6 min). The origin of such light emission needs to be further investigated.

  8. Tunneling-Electron-Induced Light Emission from Single Gold Nanoclusters.

    PubMed

    Yu, Arthur; Li, Shaowei; Czap, Gregory; Ho, W

    2016-09-14

    The coupling of tunneling electrons with the tip-nanocluster-substrate junction plasmon was investigated by monitoring light emission in a scanning tunneling microscope (STM). Gold atoms were evaporated onto the ∼5 Å thick Al2O3 thin film grown on the NiAl (110) surface where they formed nanoclusters 3-7 nm wide. Scanning tunneling spectroscopy (STS) of these nanoclusters revealed quantum-confined electronic states. Spatially resolved photon imaging showed localized emission hot spots. Size dependent study and light emission from nanocluster dimers further support the viewpoint that coupling of tunneling electrons to the junction plasmon is the main radiative mechanism. These results showed the potential of the STM to reveal the electronic and optical properties of nanoscale metallic systems in the confined geometry of the tunnel junction.

  9. Isoprenoid emission response to changing light conditions of English oak, European beech and Norway spruce

    NASA Astrophysics Data System (ADS)

    van Meeningen, Ylva; Schurgers, Guy; Rinnan, Riikka; Holst, Thomas

    2017-09-01

    Light is an important environmental factor controlling biogenic volatile organic compound (BVOC) emissions, but in natural conditions its impact is hard to separate from other influential factors such as temperature. We studied the light response of foliar BVOC emissions, photosynthesis and stomatal conductance on three common European tree species, namely English oak (Quercus robur), European beech (Fagus sylvatica) and two provenances of Norway spruce (Picea abies) in Taastrup, Denmark. Leaf scale measurements were performed on the lowest positioned branches of the tree in July 2015. Light intensity was increased in four steps (0, 500, 1000 and 1500 µmol m-2 s-1), whilst other chamber conditions such as temperature, humidity and CO2 levels were fixed. Whereas the emission rate differed between individuals of the same species, the relative contributions of compounds to the total isoprenoid emission remained similar. Whilst some compounds were species specific, the compounds α-pinene, camphene, 3-carene, limonene and eucalyptol were emitted by all of the measured tree species. Some compounds, like isoprene and sabinene, showed an increasing emission response with increasing light intensity, whereas other compounds, like camphene, had no significant emission response to light for most of the measured trees. English oak and European beech showed high light-dependent emission fractions from isoprene and sabinene, but other emitted compounds were light independent. For the two provenances of Norway spruce, the compounds α-pinene, 3-carene and eucalyptol showed high light-dependent fractions for many of the measured trees. This study highlights differences between compound emissions in their response to a change in light and a possible light independence for certain compounds, which might be valid for a wider range of tree species. This information could be of importance when improving emission models and to further emphasize the discussion regarding light or

  10. 40 CFR 86.097-9 - Emission standards for 1997 and later model year light-duty trucks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....097-9 Emission standards for 1997 and later model year light-duty trucks. (a)(1) Standards—(i) Light... standards. (ii) Heavy light-duty trucks. (A) Exhaust emissions from 1997 and later model year heavy light... model year light-duty trucks from compliance at low altitude with the emission standards set forth in...

  11. Space and time resolved representation of a vacuum arc light emission

    NASA Astrophysics Data System (ADS)

    Georgescu, N.; Sandolache, G.; Zoita, V.

    1999-04-01

    An optoelectronic multichannel detection system for the study of the visible light emission of a vacuum circuit breaker arc is described. The system consists of two multiple slit collimator assemblies coupled directly to the arc discharge chamber and an electronic detection part. The light emitted by the arc is collected by the two collimator assemblies and is transmitted through optical fibres to the electronic detection part. By using a new, simple computational method two-dimensional plots of the vacuum arc light emission at different times are obtained.

  12. 40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission...

  13. 40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission...

  14. The evolution of adult light emission color in North American fireflies

    PubMed Central

    Hall, David W.; Sander, Sarah E.; Pallansch, Jennifer C.; Stanger-Hall, Kathrin F.

    2016-01-01

    Firefly species (Lampyridae) vary in the color of their adult bioluminescence. It has been hypothesized that color is selected to enhance detection by conspecifics. One mechanism to improve visibility of the signal is to increase contrast against ambient light. High contrast implies that fireflies active early in the evening will emit yellower luminescence to contrast against ambient light reflected from green vegetation, especially in habitats with high vegetation cover. Another mechanism to improve visibility is to use reflection off the background to enhance the light signal. Reflectance predicts that sedentary females will produce greener light to maximize reflection off the green vegetation on which they signal. To test these predictions, we recorded over 7500 light emission spectra and determined peak emission wavelength for 675 males, representing 24 species, at 57 field sites across the Eastern United States. We found support for both hypotheses: males active early in more vegetated habitats produced yellower flashes in comparison to later-active males with greener flashes. Further, in 2 of the 8 species with female data, female light emissions were significantly greener as compared to males. PMID:27412777

  15. The evolution of adult light emission color in North American fireflies.

    PubMed

    Hall, David W; Sander, Sarah E; Pallansch, Jennifer C; Stanger-Hall, Kathrin F

    2016-09-01

    Firefly species (Lampyridae) vary in the color of their adult bioluminescence. It has been hypothesized that color is selected to enhance detection by conspecifics. One mechanism to improve visibility of the signal is to increase contrast against ambient light. High contrast implies that fireflies active early in the evening will emit yellower luminescence to contrast against ambient light reflected from green vegetation, especially in habitats with high vegetation cover. Another mechanism to improve visibility is to use reflection off the background to enhance the light signal. Reflectance predicts that sedentary females will produce greener light to maximize reflection off the green vegetation on which they signal. To test these predictions, we recorded over 7500 light emission spectra and determined peak emission wavelength for 675 males, representing 24 species, at 57 field sites across the Eastern United States. We found support for both hypotheses: males active early in more vegetated habitats produced yellower flashes in comparison to later-active males with greener flashes. Further, in two of the eight species with female data, female light emissions were significantly greener as compared to males. © 2016 The Author(s). Evolution © 2016 The Society for the Study of Evolution.

  16. Isoprene and monoterpene emissions in south-east Australia: comparison of a multi-layer canopy model with MEGAN and with atmospheric observations

    NASA Astrophysics Data System (ADS)

    Emmerson, Kathryn M.; Cope, Martin E.; Galbally, Ian E.; Lee, Sunhee; Nelson, Peter F.

    2018-05-01

    One of the key challenges in atmospheric chemistry is to reduce the uncertainty of biogenic volatile organic compound (BVOC) emission estimates from vegetation to the atmosphere. In Australia, eucalypt trees are a primary source of biogenic emissions, but their contribution to Australian air sheds is poorly quantified. The Model of Emissions of Gases and Aerosols from Nature (MEGAN) has performed poorly against Australian isoprene and monoterpene observations. Finding reasons for the MEGAN discrepancies and strengthening our understanding of biogenic emissions in this region is our focus. We compare MEGAN to the locally produced Australian Biogenic Canopy and Grass Emissions Model (ABCGEM), to identify the uncertainties associated with the emission estimates and the data requirements necessary to improve isoprene and monoterpene emissions estimates for the application of MEGAN in Australia. Previously unpublished, ABCGEM is applied as an online biogenic emissions inventory to model BVOCs in the air shed overlaying Sydney, Australia. The two models use the same meteorological inputs and chemical mechanism, but independent inputs of leaf area index (LAI), plant functional type (PFT) and emission factors. We find that LAI, a proxy for leaf biomass, has a small role in spatial, temporal and inter-model biogenic emission variability, particularly in urban areas for ABCGEM. After removing LAI as the source of the differences, we found large differences in the emission activity function for monoterpenes. In MEGAN monoterpenes are partially light dependent, reducing their dependence on temperature. In ABCGEM monoterpenes are not light dependent, meaning they continue to be emitted at high rates during hot summer days, and at night. When the light dependence of monoterpenes is switched off in MEGAN, night-time emissions increase by 90-100 % improving the comparison with observations, suggesting the possibility that monoterpenes emitted from Australian vegetation may not be

  17. Bright up-conversion white light emission from Er3+ doped lithium fluoro zinc borate glasses for photonic applications

    NASA Astrophysics Data System (ADS)

    Vijayalakshmi, L.; Naveen Kumar, K.; Rao, K. Srinivasa; Hwang, Pyung

    2018-03-01

    Various concentrations of Er3+ (0.3, 0.5, 1.0 and 1.5 mol %) doped lithium fluoro zinc borate glasses were synthesized by a traditional melt quenching method. XRD, FTIR and FESEM have been employed to analyze the structural, compositional and morphological analysis respectively. Judd-Ofelt theory has been employed to analyze the intensity parameters (Ωλ, λ = 2, 4 and 6) which can be used to estimate the radiative properties of fluorescent levels of Er3+. We have been observed a strong NIR emission peak at 1.53 μm (4I13/2 → 4I15/2) under the excitation of 980 nm from Er3+: LBZ glasses. Nevertheless, the NIR emission is remarkably enhanced by increasing the Er3+ ions concentration until the optimized concentration of 0.5 mol%. The lifetime of the excited level of 4I13/2 in the NIR emission transition is evaluated and it is found to be1.22 ms from the decay analysis of 0.5 mol% Er3+: LBZ glass. Apart from the NIR emission, a bright up-conversion green emission is observed at 544 nm (4S3/2 → 4I15/2) along with an intense red emission at 659 nm (4F9/2 → 4I15/2) and a weak blue emission (2H9/2 → 4I15/2) under the excitation of 980 nm. Up-conversion emission features were significantly enhanced with increasing the Er3+ concentration up to 1.0 mol%. The combination of the obtained up-conversion emission colors of green, red and blue could generate white light emission. The cool white-light emission from the optimized glass sample has been confirmed from the Commission International de I'Echairage (CIE) 1931 chromaticity diagram analysis and their correlated color temperature (CCT) values. Based on the NIR and up-conversion emission features, Er3+: LBZ glasses could be suggested as promising candidates for optical amplifiers, optical telecommunication windows and white light photonic applications.

  18. Intrinsic white-light emission from layered hybrid perovskites.

    PubMed

    Dohner, Emma R; Jaffe, Adam; Bradshaw, Liam R; Karunadasa, Hemamala I

    2014-09-24

    We report on the second family of layered perovskite white-light emitters with improved photoluminescence quantum efficiencies (PLQEs). Upon near-ultraviolet excitation, two new Pb-Cl and Pb-Br perovskites emit broadband "cold" and "warm" white light, respectively, with high color rendition. Emission from large, single crystals indicates an origin from the bulk material and not surface defect sites. The Pb-Br perovskite has a PLQE of 9%, which is undiminished after 3 months of continuous irradiation. Our mechanistic studies indicate that the emission has contributions from strong electron-phonon coupling in a deformable lattice and from a distribution of intrinsic trap states. These hybrids provide a tunable platform for combining the facile processability of organic materials with the structural definition of crystalline, inorganic solids.

  19. Multiwavelength Observations of GRB 110731A: GeV Emission From Onset to Afterglow

    DOE PAGES

    Ackermann, M.; Ajello, M.; Asano, K.; ...

    2013-01-09

    In this paper, we report on the multiwavelength observations of the bright, long gamma-ray burst GRB 110731A, by the Fermi and Swift observatories, and by the MOA and GROND optical telescopes. The analysis of the prompt phase reveals that GRB 110731A shares many features with bright Large Area Telescope bursts observed by Fermi during the first three years on-orbit: a light curve with short time variability across the whole energy range during the prompt phase, delayed onset of the emission above 100 MeV, extra power-law component and temporally extended high-energy emission. In addition, this is the first GRB for whichmore » simultaneous GeV, X-ray, and optical data are available over multiple epochs beginning just after the trigger time and extending for more than 800 s, allowing temporal and spectral analysis in different epochs that favor emission from the forward shock in a wind-type medium. Lastly, the observed temporally extended GeV emission is most likely part of the high-energy end of the afterglow emission. Both the single-zone pair transparency constraint for the prompt signal and the spectral and temporal analysis of the forward-shock afterglow emission independently lead to an estimate of the bulk Lorentz factor of the jet Γ ~ 500-550.« less

  20. Oscillations of absorption of a probe picosecond light pulse caused by its interaction with stimulated picosecond emission of GaAs

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ageeva, N. N.; Bronevoi, I. L., E-mail: bil@cplire.ru; Zabegaev, D. N.

    2015-04-15

    The self-modulation of absorption of a picosecond light pulse was observed earlier [1] in a thin (∼1-μm thick) GaAs layer pumped by a high-power picosecond pulse. Analysis of the characteristics of this self-modulation predicted [5] that the dependences of the probe pulse absorption on the pump pulse energy and picosecond delay between pump and probe pulses should be self-modulated by oscillations. Such self-modulation was experimentally observed in this work. Under certain conditions, absorption oscillations proved to be a function of part of the energy of picosecond stimulated emission of GaAs lying above a certain threshold in the region where themore » emission front overlapped the probe pulse front. Absorption oscillations are similar to self-modulation of the GaAs emission characteristics observed earlier [4]. This suggests that the self-modulation of absorption and emission is determined by the same type of interaction of light pulses in the active medium, the physical mechanism of which has yet to be determined.« less

  1. Observations of Pulsed Emission from Pulsars

    NASA Astrophysics Data System (ADS)

    Kramer, Michael

    2008-02-01

    This brief review summarises what we know observationally about the pulsed emission of pulsars across the electromagnetic spectrum. I describe the wide range of timescales observed in the properties of pulsed emission which cover about 18 orders of magnitude. Future advances in observations capabilities, most notably at gamma-ray and radio frequencies, are expected to significantly enhance our understanding of pulsars and their emission, as a large fraction of our discovery phase space is still unexplored. The first glimpse of the plethora of unknown phenomena yet to be found was given recently by the discovery of new classes of neutron stars such as Rotating Radio Transients (RRATs) and Intermittent Pulsars. We discuss these discoveries and demonstrate how they provide useful information for our understanding of pulsed emission in general.

  2. Influence of Light and Temperature on Monoterpene Emission Rates from Slash Pine

    PubMed Central

    Tingey, David T.; Manning, Marybeth; Grothaus, Louis C.; Burns, Walter F.

    1980-01-01

    There is a growing awareness of vegetation's role as a source of potentially reactive hydrocarbons that may serve as photochemical oxidant precursors. This study assessed the influence of light and temperature, independently, on monoterpene emissions from slash pine (Pinus elliottii Engelm.). Plants were preconditioned in a growth chamber, then transferred to an environmentally controlled gas exchange chamber. Samples of the chamber atmosphere were collected; the monoterpenes were concentrated cryogenically and measured by gas chromatography. Five monoterpenes (α-pinene, β-pinene, myrcene, limonene, and β-phellandrene) were present in the vapor phase surrounding the plants in sufficient quantity for reliable measurement. Light did not directly influence monoterpene emission rates since the emissions were similar in both the dark and at various light intensities. Monoterpene emission rates increased exponentially with temperature (i. e. emissions depend on temperature in a log-linear manner). The summed emissions of the five monoterpenes ranged from 3 to 21 micrograms C per gram dry weight per hour as temperature was increased from 20 to 46 C. Initially, emission rates from heat-stressed needles were similar to healthy needles, but rates decreased 11% per day. Daily carbon loss through monoterpene emissions accounted for approximately 0.4% of the carbon fixed during photosynthesis. PMID:16661285

  3. Influence of light and temperature on monoterpene emission rates from slash pine.

    PubMed

    Tingey, D T; Manning, M; Grothaus, L C; Burns, W F

    1980-05-01

    There is a growing awareness of vegetation's role as a source of potentially reactive hydrocarbons that may serve as photochemical oxidant precursors. This study assessed the influence of light and temperature, independently, on monoterpene emissions from slash pine (Pinus elliottii Engelm.). Plants were preconditioned in a growth chamber, then transferred to an environmentally controlled gas exchange chamber. Samples of the chamber atmosphere were collected; the monoterpenes were concentrated cryogenically and measured by gas chromatography. Five monoterpenes (alpha-pinene, beta-pinene, myrcene, limonene, and beta-phellandrene) were present in the vapor phase surrounding the plants in sufficient quantity for reliable measurement. Light did not directly influence monoterpene emission rates since the emissions were similar in both the dark and at various light intensities. Monoterpene emission rates increased exponentially with temperature (i. e. emissions depend on temperature in a log-linear manner). The summed emissions of the five monoterpenes ranged from 3 to 21 micrograms C per gram dry weight per hour as temperature was increased from 20 to 46 C. Initially, emission rates from heat-stressed needles were similar to healthy needles, but rates decreased 11% per day. Daily carbon loss through monoterpene emissions accounted for approximately 0.4% of the carbon fixed during photosynthesis.

  4. Inferring Sources in the Interplanetary Dust Cloud, from Observations and Simulations of Zodiacal Light and Thermal Emission

    NASA Technical Reports Server (NTRS)

    Levasseur-Regourd, A. C.; Lasue, J.

    2011-01-01

    Interplanetary dust particles physical properties may be approached through observations of the solar light they scatter, specially its polarization, and of their thermal emission. Results, at least near the ecliptic plane, on polarization phase curves and on the heliocentric dependence of the local spatial density, albedo, polarization and temperature are summarized. As far as interpretations through simulations are concerned, a very good fit of the polarization phase curve near 1.5 AU is obtained for a mixture of silicates and more absorbing organics material, with a significant amount of fluffy aggregates. In the 1.5-0.5 AU solar distance range, the temperature variation suggests the presence of a large amount of absorbing organic compounds, while the decrease of the polarization with decreasing solar distance is indeed compatible with a decrease of the organics towards the Sun. Such results are in favor of the predominance of dust of cometary origin in the interplanetary dust cloud, at least below 1.5 AU. The implication of these results on the delivery of complex organic molecules on Earth during the LHB epoch, when the spatial density of the interplanetary dust cloud was orders of magnitude greater than today, is discussed.

  5. Observation of low voltage driven green emission from erbium doped Ga{sub 2}O{sub 3} light-emitting devices

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, Zhengwei; Wang, Xu; Zhang, Fabi

    Erbium doped Ga{sub 2}O{sub 3} thin films were deposited on Si substrate by pulsed laser deposition method. Bright green emission (∼548 nm) can be observed by naked eye from Ga{sub 2}O{sub 3}:Er/Si light-emitting devices (LEDs). The driven voltage of this LEDs is 6.2 V which is lower than that of ZnO:Er/Si or GaN:Er/Si devices. Since the wide bandgap of Ga{sub 2}O{sub 3} contain more defect-related level which will enhance the effects of recombination between electrons in the defect-related level and the holes in the valence band, resulting in the improvement of the energy transfer to Er ions. We believe that this workmore » paves the way for the development of Si-based green LEDs by using wide bandgap Ga{sub 2}O{sub 3} as the host materials for Er{sup 3+} ions.« less

  6. Organic light-emitting device with a phosphor-sensitized fluorescent emission layer

    DOEpatents

    Forrest, Stephen [Ann Arbor, MI; Kanno, Hiroshi [Osaka, JP

    2009-08-25

    The present invention relates to organic light emitting devices (OLEDs), and more specifically to OLEDS that emit light using a combination of fluorescent emitters and phosphorescent emitters. The emissive region of the devices of the present invention comprise at least one phosphor-sensitized layer which has a combined emission from a phosphorescent emitter and a fluorescent emitter. In preferred embodiments, the invention relates to white-emitting OLEDS (WOLEDs).

  7. Applications of Cherenkov Light Emission for Dosimetry in Radiation Therapy

    NASA Astrophysics Data System (ADS)

    Glaser, Adam Kenneth

    Since its discovery in the 1930's, the Cherenkov effect has been paramount in the development of high-energy physics research. It results in light emission from charged particles traveling faster than the local speed of light in a dielectric medium. The ability of this emitted light to describe a charged particle's trajectory, energy, velocity, and mass has allowed scientists to study subatomic particles, detect neutrinos, and explore the properties of interstellar matter. However, only recently has the phenomenon been considered in the practical context of medical physics and radiation therapy dosimetry, where Cherenkov light is induced by clinical x-ray photon, electron, and proton beams. To investigate the relationship between this phenomenon and dose deposition, a Monte Carlo plug-in was developed within the Geant4 architecture for medically-oriented simulations (GAMOS) to simulate radiation-induced optical emission in biological media. Using this simulation framework, it was determined that Cherenkov light emission may be well suited for radiation dosimetry of clinically used x-ray photon beams. To advance this application, several novel techniques were implemented to realize the maximum potential of the signal, such as time-gating for maximizing the signal to noise ratio (SNR) and Cherenkov-excited fluorescence for generating isotropic light release in water. Proof of concept experiments were conducted in water tanks to demonstrate the feasibility of the proposed method for two-dimensional (2D) projection imaging, three-dimensional (3D) parallel beam tomography, large field of view 3D cone beam tomography, and video-rate dynamic imaging of treatment plans for a number of common radiotherapy applications. The proposed dosimetry method was found to have a number of unique advantages, including but not limited to its non-invasive nature, water-equivalence, speed, high-resolution, ability to provide full 3D data, and potential to yield data in-vivo. Based on

  8. 40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 20 2012-07-01 2012-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND...

  9. 40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission Standards for Clean-Fuel Vehicles § 88.10...

  10. 40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission Standards for Clean-Fuel Vehicles § 88.10...

  11. 40 CFR 86.1811-10 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 19 2014-07-01 2014-07-01 false Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-10 Section 86.1811-10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND...

  12. 40 CFR 88.104-94 - Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Clean-fuel vehicle tailpipe emission standards for light-duty vehicles and light-duty trucks. 88.104-94 Section 88.104-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CLEAN-FUEL VEHICLES Emission Standards for Clean-Fuel Vehicles § 88.104...

  13. Rapid-Response Low Infrared Emission Broadband Ultrathin Plasmonic Light Absorber

    PubMed Central

    Tagliabue, Giulia; Eghlidi, Hadi; Poulikakos, Dimos

    2014-01-01

    Plasmonic nanostructures can significantly advance broadband visible-light absorption, with absorber thicknesses in the sub-wavelength regime, much thinner than conventional broadband coatings. Such absorbers have inherently very small heat capacity, hence a very rapid response time, and high light power-to-temperature sensitivity. Additionally, their surface emissivity can be spectrally tuned to suppress infrared thermal radiation. These capabilities make plasmonic absorbers promising candidates for fast light-to-heat applications, such as radiation sensors. Here we investigate the light-to-heat conversion properties of a metal-insulator-metal broadband plasmonic absorber, fabricated as a free-standing membrane. Using a fast IR camera, we show that the transient response of the absorber has a characteristic time below 13 ms, nearly one order of magnitude lower than a similar membrane coated with a commercial black spray. Concurrently, despite the small thickness, due to the large absorption capability, the achieved absorbed light power-to-temperature sensitivity is maintained at the level of a standard black spray. Finally, we show that while black spray has emissivity similar to a black body, the plasmonic absorber features a very low infra-red emissivity of almost 0.16, demonstrating its capability as selective coating for applications with operating temperatures up to 400°C, above which the nano-structure starts to deform. PMID:25418040

  14. Temporal Evolution of the Gamma-ray Burst Afterglow Spectrum for an Observer: GeV-TeV Synchrotron Self-Compton Light Curve

    NASA Astrophysics Data System (ADS)

    Fukushima, Takuma; To, Sho; Asano, Katsuaki; Fujita, Yutaka

    2017-08-01

    We numerically simulate the gamma-ray burst (GRB) afterglow emission with a one-zone time-dependent code. The temporal evolutions of the decelerating shocked shell and energy distributions of electrons and photons are consistently calculated. The photon spectrum and light curves for an observer are obtained taking into account the relativistic propagation of the shocked shell and the curvature of the emission surface. We find that the onset time of the afterglow is significantly earlier than the previous analytical estimate. The analytical formulae of the shock propagation and light curve for the radiative case are also different from our results. Our results show that even if the emission mechanism is switching from synchrotron to synchrotron self-Compton, the gamma-ray light curves can be a smooth power law, which agrees with the observed light curve and the late detection of a 32 GeV photon in GRB 130427A. The uncertainty of the model parameters obtained with the analytical formula is discussed, especially in connection with the closure relation between spectral index and decay index.

  15. Temporal Evolution of the Gamma-ray Burst Afterglow Spectrum for an Observer: GeV–TeV Synchrotron Self-Compton Light Curve

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fukushima, Takuma; Fujita, Yutaka; To, Sho

    We numerically simulate the gamma-ray burst (GRB) afterglow emission with a one-zone time-dependent code. The temporal evolutions of the decelerating shocked shell and energy distributions of electrons and photons are consistently calculated. The photon spectrum and light curves for an observer are obtained taking into account the relativistic propagation of the shocked shell and the curvature of the emission surface. We find that the onset time of the afterglow is significantly earlier than the previous analytical estimate. The analytical formulae of the shock propagation and light curve for the radiative case are also different from our results. Our results showmore » that even if the emission mechanism is switching from synchrotron to synchrotron self-Compton, the gamma-ray light curves can be a smooth power law, which agrees with the observed light curve and the late detection of a 32 GeV photon in GRB 130427A. The uncertainty of the model parameters obtained with the analytical formula is discussed, especially in connection with the closure relation between spectral index and decay index.« less

  16. Effect of mid-term drought on Quercus pubescens BVOCs' emission seasonality and their dependency on light and/or temperature

    NASA Astrophysics Data System (ADS)

    Saunier, Amélie; Ormeño, Elena; Boissard, Christophe; Wortham, Henri; Temime-Roussel, Brice; Lecareux, Caroline; Armengaud, Alexandre; Fernandez, Catherine

    2017-06-01

    Biogenic volatile organic compounds (BVOCs) emitted by plants represent a large source of carbon compounds released into the atmosphere, where they account for precursors of tropospheric ozone and secondary organic aerosols. Being directly involved in air pollution and indirectly in climate change, understanding what factors drive BVOC emissions is a prerequisite for modeling their emissions and predict air pollution. The main algorithms currently used to model BVOC emissions are mainly light and/or temperature dependent. Additional factors such as seasonality and drought also influence isoprene emissions, especially in the Mediterranean region, which is characterized by a rather long drought period in summer. These factors are increasingly included in models but only for the principal studied BVOC, namely isoprene, but there are still some discrepancies in estimations of emissions. In this study, the main BVOCs emitted by Quercus pubescens - isoprene, methanol, acetone, acetaldehyde, formaldehyde, MACR, MVK and ISOPOOH (these three last compounds detected under the same m/z) - were monitored with a PTR-ToF-MS over an entire seasonal cycle during both in situ natural and amplified drought, which is expected with climate change. Amplified drought impacted all studied BVOCs by reducing emissions in spring and summer while increasing emissions in autumn. All six BVOCs monitored showed daytime light and temperature dependencies while three BVOCs (methanol, acetone and formaldehyde) also showed emissions during the night despite the absence of light under constant temperature. Moreover, methanol and acetaldehyde burst in the early morning and formaldehyde deposition and uptake were also punctually observed, which were not assessed by the classical temperature and light models.

  17. Microcontact printing of self-assembled monolayers to pattern the light-emission of polymeric light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Brondijk, J. J.; Li, X.; Akkerman, H. B.; Blom, P. W. M.; de Boer, B.

    2009-04-01

    By patterning a self-assembled monolayer (SAM) of thiolated molecules with opposing dipole moments on a gold anode of a polymer light-emitting diode (PLED), the charge injection and, therefore, the light-emission of the device can be controlled with a micrometer-scale resolution. Gold surfaces were modified with SAMs based on alkanethiols and perfluorinated alkanethiols, applied by microcontact printing, and their work functions have been measured. The molecules form a chemisorbed monolayer of only ˜1.5 nm on the gold surface, thereby locally changing the work function of the metal. Kelvin probe measurements show that the local work function can be tuned from 4.3 to 5.5 eV, which implies that this anode can be used as a hole blocking electrode or as a hole injecting electrode, respectively, in PLEDs based on poly( p-phenylene vinylene) (PPV) derivatives. By microcontact printing of SAMs with opposing dipole moments, the work function was locally modified and the charge injection in the PLED could be controlled down to the micrometer length scale. Consequently, the local light-emission exhibits a high contrast. Microcontact printing of SAMs is a simple and inexpensive method to pattern, with micrometer resolution, the light-emission for low-end applications like static displays.

  18. UV emissions from low energy artificial light sources.

    PubMed

    Fenton, Leona; Moseley, Harry

    2014-01-01

    Energy efficient light sources have been introduced across Europe and many other countries world wide. The most common of these is the Compact Fluorescent Lamp (CFL), which has been shown to emit ultraviolet (UV) radiation. Light Emitting Diodes (LEDs) are an alternative technology that has minimal UV emissions. This brief review summarises the different energy efficient light sources available on the market and compares the UV levels and the subsequent effects on the skin of normal individuals and those who suffer from photodermatoses. © 2013 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  19. XMM-Newton Observations of NGC 253: Resolving the Emission Components in the Disk and Nuclear Area

    NASA Technical Reports Server (NTRS)

    Pietsch, W.; Borozdin, K. N.; Branduardi-Raymont, G.; Cappi, M.; Ehle, M.; Ferrando, P.; Freyberg, M. J.; Kahn, S. M.; Ponman, T. J.; Ptak, A.

    2000-01-01

    We describe the first XMM-Newton observations of the starburst galaxy NGC 253. As known from previous X-ray observations, NGC 253 shows a mixture of extended (disk and halo) and point-source emission. The high XMM-Newton throughput allows for the first time a detailed investigation of the spatial, spectral and variability properties of these components simultaneously. We detect a bright X-ray transient approx. 70 sec SSW of the nucleus and show the spectrum and light curve of the brightest point source (approx. 30 sec S of the nucleus, most likely a black-hole X-ray binary, BHXRB). The unprecedented combination of RGS and EPIC also sheds new light on the emission of the complex nuclear region, the X-ray plume and the disk diffuse emission. In particular, EPIC images reveal that the limb-brightening of the plume is mostly seen in higher ionization emission lines, while in the lower ionization lines, and below 0.5 keV, the plume is more homo- geneously structured, pointing to new interpretations as to the make up of the starburst-driven outflow. Assuming that type IIa supernova remnants (SNRs) are mostly responsible for the E greater than 4 keV emission, the detection with EPIC of the 6.7 keV line allows us to estimate a supernova rate within the nuclear starburst of 0.2 /yr.

  20. MIRIS observation of near-infrared diffuse Galactic light

    NASA Astrophysics Data System (ADS)

    Onishi, Yosuke; Sano, Kei; Matsuura, Shuji; Jeong, Woong-Seob; Pyo, Jeonghyun; Kim, Il-Jong; Seo, Hyun Jong; Han, Wonyong; Lee, DaeHee; Moon, Bongkon; Park, Wonkee; Park, Younsik; Kim, MinGyu; Matsumoto, Toshio; Matsuhara, Hideo; Nakagawa, Takao; Tsumura, Kohji; Shirahata, Mai; Arai, Toshiaki; Ienaka, Nobuyuki

    2018-06-01

    We report near-infrared (IR) observations of high Galactic latitude clouds to investigate diffuse Galactic light (DGL), which is starlight scattered by interstellar dust grains. The observations were performed at 1.1 and 1.6 μm with a wide-field camera instrument, the Multi-purpose Infra-Red Imaging System (MIRIS) onboard the Korean satellite STSAT-3. The DGL brightness is measured by correlating the near-IR images with a far-IR 100 μm map of interstellar dust thermal emission. The wide-field observation of DGL provides the most accurate DGL measurement achieved to-date. We also find a linear correlation between optical and near-IR DGL in the MBM32 field. To study interstellar dust properties in MBM32, we adopt recent dust models with and without μm-sized very large grains and predict the DGL spectra, taking into account the reddening effect of the interstellar radiation field. The result shows that the observed color of the near-IR DGL is closer to the model spectra without very large grains. This may imply that dust growth in the observed MBM32 field is not active owing to the low density of its interstellar medium.

  1. Observations of a mode transition in a hydrogen hollow cathode discharge using phase resolved optical emission spectroscopy

    NASA Astrophysics Data System (ADS)

    Dixon, Sam; Charles, Christine; Dedrick, James; Gans, Timo; O'Connell, Deborah; Boswell, Rod

    2014-07-01

    Two distinct operational modes are observed in a radio frequency (rf) low pressure hydrogen hollow cathode discharge. The mode transition is characterised by a change in total light emission and differing expansion structures. An intensified CCD camera is used to make phase resolved images of Balmer α emission from the discharge. The low emission mode is consistent with a typical γ discharge, and appears to be driven by secondary electrons ejected from the cathode surface. The bright mode displays characteristics common to an inductive discharge, including increased optical emission, power factor, and temperature of the H2 gas. The bright mode precipitates the formation of a stationary shock in the expansion, observed as a dark region adjacent to the source-chamber interface.

  2. Energetic Neutral Atom Emissions From Venus: VEX Observations and Theoretical Modeling

    NASA Technical Reports Server (NTRS)

    Fok, M.-C.; Galli, A.; Tanaka, T.; Moore, T. E.; Wurz, P.; Holmstrom, M.

    2007-01-01

    Venus has almost no intrinsic magnetic field to shield itself from its surrounding environment. The solar wind thus directly interacts with the planetary ionosphere and atmosphere. One of the by-products of this close encounter is the production of energetic neutral atom (ENA) emissions. Theoretical studies have shown that significant amount of ENAs are emanated from the planet. The launch of the Venus Express (VEX) in 2005 provided the first light ever of the Venus ENA emissions. The observed ENA flux level and structure are in pretty good agreement with the theoretical studies. In this paper, we present VEX ENA data and the comparison with numerical simulations. We seek to understand the solar wind interaction with the planet and the impacts on its atmospheres.

  3. Study of white light emission from ZnS/PS composite system

    NASA Astrophysics Data System (ADS)

    Wang, Caifeng; Li, Qingshan; Lu, Lei; Zhang, Lichun; Qi, Hongxia

    2007-09-01

    ZnS films were deposited by pulsed laser deposition (PLD) on porous silicon (PS) substrates formed by electrochemical anodization of p-type (100) silicon wafer. The photoluminescence (PL) spectra of ZnS/PS composites were measured at room temperature. Under different excitation wavelengths, the relative integrated intensities of the red light emission from PS layers and the blue-green emission from ZnS films had different values. After samples were annealed in vacuum at different temperatures (200, 300, and 400 Celsius degree) for 30 min respectively, a new green emission located at around 550 nm appeared in the PL spectra of all ZnS/PS samples, and all of the ZnS/PS composites had a broad PL band (450-700 nm) in the visible region, exhibiting intensively white light emission.

  4. Hard X-ray Emission from Galaxy Clusters Observed with INTEGRAL and Prospects for Simbol-X

    NASA Astrophysics Data System (ADS)

    Eckert, D.; Paltani, S.; Courvoisier, T. J.-L.

    2009-05-01

    Some galaxy clusters are known to contain a large population of relativistic electrons, which produce radio emission through synchrotron radiation. Therefore, it is expected that inverse-Compton scattering of the relativistic electrons with the CMB produce non-thermal emission which should be observable in the hard X-ray domain. Here we focus on the recent results by INTEGRAL, which shed a new light on the non-thermal emission thanks to its angular resolution and sensitivity in the hard X-ray range. We also present the exciting prospects in this field for Simbol-X, which will allow us to detect the non-thermal emission in a number of clusters and map the magnetic field throughout the intra-cluster medium.

  5. Blackbody emission from light interacting with an effective moving dispersive medium.

    PubMed

    Petev, M; Westerberg, N; Moss, D; Rubino, E; Rimoldi, C; Cacciatori, S L; Belgiorno, F; Faccio, D

    2013-07-26

    Intense laser pulses excite a nonlinear polarization response that may create an effective flowing medium and, under appropriate conditions, a blocking horizon for light. Here, we analyze in detail the interaction of light with such laser-induced flowing media, fully accounting for the medium dispersion properties. An analytical model based on a first Born approximation is found to be in excellent agreement with numerical simulations based on Maxwell's equations and shows that when a blocking horizon is formed, the stimulated medium scatters light with a blackbody emission spectrum. Based on these results, diamond is proposed as a promising candidate medium for future studies of Hawking emission from artificial, dispersive horizons.

  6. ELECTROMAGNETIC EMISSION FROM LONG-LIVED BINARY NEUTRON STAR MERGER REMNANTS. II. LIGHT CURVES AND SPECTRA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Siegel, Daniel M.; Ciolfi, Riccardo, E-mail: daniel.siegel@aei.mpg.de, E-mail: riccardo.ciolfi@unitn.it

    2016-03-01

    Recent observations indicate that in a large fraction of binary neutron star (BNS) mergers a long-lived neutron star (NS) may be formed rather than a black hole. Unambiguous electromagnetic (EM) signatures of such a scenario would strongly impact our knowledge on how short gamma-ray bursts (SGRBs) and their afterglow radiation are generated. Furthermore, such EM signals would have profound implications for multimessenger astronomy with joint EM and gravitational-wave (GW) observations of BNS mergers, which will soon become reality thanks to the ground-based advanced LIGO/Virgo GW detector network. Here we explore such EM signatures based on the model presented in amore » companion paper, which provides a self-consistent evolution of the post-merger system and its EM emission up to ∼10{sup 7} s. Light curves and spectra are computed for a wide range of post-merger physical properties. We present X-ray afterglow light curves corresponding to the “standard” and the “time-reversal” scenario for SGRBs (prompt emission associated with the merger or with the collapse of the long-lived NS). The light curve morphologies include single and two-plateau features with timescales and luminosities that are in good agreement with Swift observations. Furthermore, we compute the X-ray signal that should precede the SGRB in the time-reversal scenario, the detection of which would represent smoking-gun evidence for this scenario. Finally, we find a bright, highly isotropic EM transient peaking in the X-ray band at ∼10{sup 2}–10{sup 4} s after the BNS merger with luminosities of L{sub X} ∼ 10{sup 46}–10{sup 48} erg s{sup −1}. This signal represents a very promising EM counterpart to the GW emission from BNS mergers.« less

  7. IUE observations of the Jovian dayglow emission

    NASA Technical Reports Server (NTRS)

    Mcgrath, M. A.; Feldman, P. D.; Ballester, G. E.; Moos, H. W.

    1989-01-01

    IUE spectra of Jupiter are examined in light of recent models put forward to explain the anomalously bright ultraviolet emissions seen from the upper atmospheres of the outer planets. Chi-squared fits of the IUE spectra with model spectra produced by two proposed excitation mechanisms, electron impact and fluorescence of solar radiation, result in consistently higher chi-squared values for the solar fluorescence model. No conclusive evidence is found in the IUE data for the dominance of solar fluorescence over electron excitation in producing the Jovian dayglow emission.

  8. STM-induced light emission enhanced by weakly coupled organic ad-layers

    NASA Astrophysics Data System (ADS)

    Cottin, M. C.; Ekici, E.; Bobisch, C. A.

    2018-03-01

    We analyze the light emission induced by the tunneling current flowing in a scanning tunneling microscopy experiment. In particular, we study the influence of organic ad-layers on the light emission on the initial monolayer of bismuth (Bi) on Cu(111) in comparison to the well-known case of organic ad-layers on Ag(111). On the Bi/Cu(111)-surface, we find that the scanning tunneling microscopy-induced light emission is considerably enhanced if an organic layer, e.g., the fullerene C60 or the perylene derivate perylene-tetracarboxylic-dianhydride, is introduced into the tip-sample junction. The enhancement can be correlated with a peculiarly weak interaction between the adsorbed molecules and the underlying Bi/Cu(111) substrate as compared to the Ag(111) substrate. This allows us to efficiently enhance and tune the coupling of the tunneling current to localized excitations of the tip-sample junction, which in turn couple to radiative decay channels.

  9. Chamber study of PCB emissions from caulking materials and light ballasts.

    PubMed

    Liu, Xiaoyu; Guo, Zhishi; Krebs, Kenneth A; Stinson, Rayford A; Nardin, Joshua A; Pope, Robert H; Roache, Nancy F

    2015-10-01

    The emissions of polychlorinated biphenyl (PCB) congeners from thirteen caulk samples were tested in a micro-chamber system. Twelve samples were from PCB-contaminated buildings and one was prepared in the laboratory. Nineteen light ballasts collected from buildings that represent 13 different models from five manufacturers were tested in 53-L environmental chambers. The rates of PCB congener emissions from caulking materials and light ballasts were determined. Several factors that may have affected the emission rates were evaluated. The experimentally determined emission factors showed that, for a given PCB congener, there is a linear correlation between the emission factor and the concentration of the PCB congener in the source. Furthermore, the test results showed that an excellent log-linear correlation exists between the normalized emission factor and the vapor pressure (coefficient of determination, r(2)⩾0.8846). The PCB congener emissions from ballasts at or near room temperature were relatively low with or without electrical load. However, the PCB congener emission rates increased significantly as the temperature increased. The results of this research provide new data and models for ranking the primary sources of PCBs and supports the development and refinement of exposure assessment models for PCBs. Published by Elsevier Ltd.

  10. Penning plasma based simultaneous light emission source of visible and VUV lights

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vyas, G. L., E-mail: glvyas27@gmail.com; Prakash, R.; Pal, U. N.

    In this paper, a laboratory-based penning plasma discharge source is reported which has been developed in two anode configurations and is able to produce visible and VUV lights simultaneously. The developed source has simultaneous diagnostics facility using Langmuir probe and optical emission spectroscopy. The two anode configurations, namely, double ring and rectangular configurations, have been studied and compared for optimum use of the geometry for efficient light emissions and recording. The plasma is produced using helium gas and admixture of three noble gases including helium, neon, and argon. The source is capable to produce eight spectral lines for pure heliummore » in the VUV range from 20 to 60 nm and total 24 spectral lines covering the wavelength range 20–106 nm for the admixture of gases. The large range of VUV lines is generated from gaseous admixture rather from the sputtered materials. The recorded spectrum shows that the plasma light radiations in both visible and VUV range are larger in double ring configuration than that of the rectangular configurations at the same discharge operating conditions. To clearly understand the difference, the imaging of the discharge using ICCD camera and particle-in-cell simulation using VORPAL have also been carried out. The effect of ion diffusion, metastable collision with the anode wall and the nonlinear effects are correlated to explain the results.« less

  11. White light upconversion emissions in Er3+/Tm3+/Yb3+ tridoped oxyfluoride glass

    NASA Astrophysics Data System (ADS)

    Guan, Xiaoping; Xu, Wei; Zhu, Shuang; Song, Qiutong; Wu, Xijun; Liu, Hailong

    2015-10-01

    Rare earth ions doped glasses producing visible upconversion emissions are of great interest due to their potential applications in the photonics filed. In fact, practical application of upconversion emissions has been used to obtain color image displays and white light sources. However, there are few reports on the thermal effect on tuning the emission color of the RE doped materials. In this work, the Er3+/Tm3+/Yb3+ tridoped oxyfluoride glasses were prepared through high temperature solid-state method. Under a 980 nm diode laser excitation, the upconversion emissions from the samples were studied. At room-temperature, bright white luminescence, whose CIE chromaticity coordinate was about (0.28, 0.31), can be obtained when the excitation power was 120 mW. The emission color was changed by varying the intensity ratios between RGB bands, which are strongly dependent on the rare earth ions concentration. The temperature dependent color emissions were also investigated. As temperature increased, the intensities for the emission bands presented different decay rates, finally resulting in the changing of the CIE coordinate. When the temperature was 573 K, white light with color coordinate of (0.31, 0.33) was achieved, which matches well with the white reference (0.33, 0.33). The color tunability, high quality of white light and intense emission intensity make the transparent oxyfluoride glasses excellent candidates for applications in solid-state lighting.

  12. High light-quality OLEDs with a wet-processed single emissive layer.

    PubMed

    Singh, Meenu; Jou, Jwo-Huei; Sahoo, Snehasis; S S, Sujith; He, Zhe-Kai; Krucaite, Gintare; Grigalevicius, Saulius; Wang, Ching-Wu

    2018-05-08

    High light-quality and low color temperature are crucial to justify a comfortable healthy illumination. Wet-process enables electronic devices cost-effective fabrication feasibility. We present herein low color temperature, blue-emission hazards free organic light emitting diodes (OLEDs) with very-high light-quality indices, that with a single emissive layer spin-coated with multiple blackbody-radiation complementary dyes, namely deep-red, yellow, green and sky-blue. Specifically, an OLED with a 1,854 K color temperature showed a color rendering index (CRI) of 90 and a spectrum resemblance index (SRI) of 88, whose melatonin suppression sensitivity is only 3% relative to a reference blue light of 480 nm. Its maximum retina permissible exposure limit is 3,454 seconds at 100 lx, 11, 10 and 6 times longer and safer than the counterparts of compact fluorescent lamp (5,920 K), light emitting diode (5,500 K) and OLED (5,000 K). By incorporating a co-host, tris(4-carbazoyl-9-ylphenyl)amine (TCTA), the resulting OLED showed a current efficiency of 24.9 cd/A and an external quantum efficiency of 24.5% at 100 cd/m 2 . It exhibited ultra-high light quality with a CRI of 93 and an SRI of 92. These prove blue-hazard free, high quality and healthy OLED to be fabrication feasible via the easy-to-apply wet-processed single emissive layer with multiple emitters.

  13. 40 CFR 86.1708-99 - Exhaust emission standards for 1999 and later light-duty vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... and later light-duty vehicles. 86.1708-99 Section 86.1708-99 Protection of Environment ENVIRONMENTAL... VEHICLES AND ENGINES (CONTINUED) General Provisions for the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86.1708-99 Exhaust emission standards for 1999 and...

  14. ZnO nanopowder induced light scattering for improved visualization of emission sites in carbon nanotube films and arrays

    NASA Astrophysics Data System (ADS)

    Meško, Marcel; Ou, Qiongrong; Matsuda, Takafumi; Ishikawa, Tomokazu; Veis, Martin; Antoš, Roman; Ogino, Akihisa; Nagatsu, Masaaki

    2009-06-01

    We report on ZnO nanopowder induced light scattering for improved visualization of emission sites in carbon nanotube films and arrays. We observed a significant reduction of the internal multiple light scattering phenomena, which are characteristic for ZnO micropowders. The microsized grains of the commercially available ZnO:Zn (P 15) were reduced to the nanometre scale by pulsed laser ablation at an oxygen ambient pressure of 10 kPa. Our investigations show no crystalline change and no shift of the broad green emission peak at 500 nm for the ZnO nanopowder. For the application in field emission displays, we demonstrate the possibility of achieving cathodoluminescence with a fine pitch size of 100 µm of the patterned pixels without requiring additional electron beam focusing and without a black matrix. Moreover, the presented results show the feasibility of employing ZnO nanopowder as a detection material for the phosphorus screen method, which is able to localize emission sites of carbon nanotube films and arrays with an accuracy comparable to scanning anode field emission microscopy.

  15. Light absorbing carbon emissions from commercial shipping

    NASA Astrophysics Data System (ADS)

    Lack, Daniel; Lerner, Brian; Granier, Claire; Baynard, Tahllee; Lovejoy, Edward; Massoli, Paola; Ravishankara, A. R.; Williams, Eric

    2008-07-01

    Extensive measurements of the emission of light absorbing carbon aerosol (LAC) from commercial shipping are presented. Vessel emissions were sampled using a photoacoustic spectrometer in the Gulf of Mexico region. The highest emitters (per unit fuel burnt) are tug boats, thus making significant contributions to local air quality in ports. Emission of LAC from cargo and non cargo vessels in this study appears to be independent of engine load. Shipping fuel consumption data (2001) was used to calculate a global LAC contribution of 133(+/-27) Ggyr-1, or ~1.7% of global LAC. This small fraction could have disproportionate effects on both air quality near port areas and climate in the Arctic if direct emissions of LAC occur in that region due to opening Arctic sea routes. The global contribution of this LAC burden was investigated using the MOZART model. Increases of 20-50 ng m-3 LAC (relative increases up to 40%) due to shipping occur in the tropical Atlantic, Indonesia, central America and the southern regions of South America and Africa.

  16. In Situ observation of dark current emission in a high gradient rf photocathode gun

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shao, Jiahang; Shi, Jiaru; Antipov, Sergey P.

    Undesirable electron field emission (also known as dark current) in high gradient rf photocathode guns deteriorates the quality of the photoemission current and limits the operational gradient. To improve the understanding of dark current emission, a high-resolution (~100 μm) dark current imaging experiment has been performed in an L-band photocathode gun operating at ~100 MV/m of surface gradient. Scattered strong emission areas with high current have been observed on the cathode. The field enhancement factor β of selected regions on the cathode has been measured. Finally, the postexaminations with scanning electron microscopy and white light interferometry reveal the origins ofmore » ~75% strong emission areas overlap with the spots where rf breakdown has occurred.« less

  17. In Situ observation of dark current emission in a high gradient rf photocathode gun

    DOE PAGES

    Shao, Jiahang; Shi, Jiaru; Antipov, Sergey P.; ...

    2016-08-15

    Undesirable electron field emission (also known as dark current) in high gradient rf photocathode guns deteriorates the quality of the photoemission current and limits the operational gradient. To improve the understanding of dark current emission, a high-resolution (~100 μm) dark current imaging experiment has been performed in an L-band photocathode gun operating at ~100 MV/m of surface gradient. Scattered strong emission areas with high current have been observed on the cathode. The field enhancement factor β of selected regions on the cathode has been measured. Finally, the postexaminations with scanning electron microscopy and white light interferometry reveal the origins ofmore » ~75% strong emission areas overlap with the spots where rf breakdown has occurred.« less

  18. Comparison of real-world and certification emission rates for light duty gasoline vehicles.

    PubMed

    Khan, Tanzila; Frey, H Christopher

    2018-05-01

    U.S. light duty vehicles are subject to the U.S. Environmental Protection Agency (EPA) emission standards. Emission compliance is determined by certification testing of selected emissions from representative vehicles on standard driving cycles using chassis dynamometers. Test results are also used in many emission inventories. The dynamometer based emission rates are adjusted to provide the certification levels (CL), which must be lower than the standards for compliance. Although standard driving cycles are based on specific observations of real-world driving, they are not necessarily real-world representative. A systematic comparison of the real-world emission rates of U.S. light duty gasoline vehicles (LDGVs) versus CL, and emission standards has not been previously reported. The purpose of this work is to compare regulatory limits (both CLs and emission standards) and the real-world emissions of LDGVs. The sensitivity of the comparisons to cold start emission was assessed. Portable Emission Measurement Systems (PEMS) were used to measure hot stabilized exhaust emissions of 122 LDGVs on a specified 110 mile test route. Cold start emissions were measured with PEMS for a selected vehicle sample of 32 vehicles. Emissions were measured for carbon dioxide (CO 2 ), carbon monoxide (CO), hydrocarbons (HC) and nitrogen oxides (NO x ). For each vehicle, a Vehicle Specific Power (VSP) modal emission rate model was developed. The VSP modal rates were weighted by the standard driving cycles and real-world driving cycles to estimate the respective cycle average emission rates (CAERs). Measured vehicles were matched with certification test vehicles for comparison. For systematic trends in comparison, vehicles were classified into four groups based on the Tier 1 and Tier 2 emission regulation, and the vehicle type such as passenger car and passenger truck. Depending on the cycle-pollutant and the vehicle groups, hot stabilized CAERs are on average either statistically

  19. Synoptic observations of Jupiter's radio emissions: Average Statistical properties observed by Voyager

    NASA Technical Reports Server (NTRS)

    Alexander, J. K.; Carr, T. D.; Thieman, J. R.; Schauble, J. J.; Riddle, A. C.

    1980-01-01

    Observations of Jupiter's low frequency radio emissions collected over one month intervals before and after each Voyager encounter were analyzed. Compilations of occurrence probability, average power flux density and average sense of circular polarization are presented as a function of central meridian longitude, phase of Io, and frequency. The results are compared with ground based observations. The necessary geometrical conditions are preferred polarization sense for Io-related decametric emission observed by Voyager from above both the dayside and nightside hemispheres are found to be essentially the same as are observed in Earth based studies. On the other hand, there is a clear local time dependence in the Io-independent decametric emission. Io appears to have an influence on average flux density of the emission down to below 2 MHz. The average power flux density spectrum of Jupiter's emission has a broad peak near 9MHz. Integration of the average spectrum over all frequencies gives a total radiated power for an isotropic source of 4 x 10 to the 11th power W.

  20. Angular Distribution of light emission in ELVES events

    NASA Astrophysics Data System (ADS)

    Mussa, Roberto

    2017-04-01

    The Pierre Auger Observatory, located in Malargüe (Argentina), is the largest facility (3000 kmq ) for the study of Ultra High Energy Cosmic Rays (E>0.3 EeV). The four sites of the Fluorescence Detector (FD) are continuously observing the night sky with moon fraction below 50% (13% duty cycle) with 100 ns time resolution and a space resolution below one degree. Since 2013, the Observatory has implemented a dedicated trigger for the study of ELVES events, produced by lightning activity in Northern Argentina during summer months. A network of ancillary devices (lidars, cloud cameras, weather stations, lightning sensors, E-field mills) complements the FD data to correct for the variation of atmospheric optical properties. This paper will report about the angular distribution of the light emission around the vertical above the lightning source and compare with existing models.

  1. Laser based imaging of time depending microscopic scenes with strong light emission

    NASA Astrophysics Data System (ADS)

    Hahlweg, Cornelius; Wilhelm, Eugen; Rothe, Hendrik

    2011-10-01

    Investigating volume scatterometry methods based on short range LIDAR devices for non-static objects we achieved interesting results aside the intended micro-LIDAR: the high speed camera recording of the illuminated scene of an exploding wire -intended for Doppler LIDAR tests - delivered a very effective method of observing details of objects with extremely strong light emission. As a side effect a schlieren movie is gathered without any special effort. The fact that microscopic features of short time processes with high emission and material flow might be imaged without endangering valuable equipment makes this technique at least as interesting as the intended one. So we decided to present our results - including latest video and photo material - instead of a more theoretical paper on our progress concerning the primary goal.

  2. Contribution of Lubricating Oil to Particulate Matter Emissions from Light-Duty Gasoline Vehicles in Kansas City

    EPA Science Inventory

    The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

  3. Contribution of Lubricating Oil to Particulate Matter Emissions from Light-duty Gasoline Vehicles in Kansas City

    EPA Science Inventory

    The contribution of lubricating oil to particulate matter (PM) emissions representative of the in-use 2004 light-duty gasoline vehicles fleet is estimated from the Kansas City Light-Duty Vehicle Emissions Study (KCVES). PM emissions are apportioned to lubricating oil and gasoline...

  4. FERMI Observations of Gamma -Ray Emission From the Moon

    NASA Technical Reports Server (NTRS)

    Abdo, A. A.; Ackermann, M.; Ajello, M.; Atwoo, W. B.; Baldini, I.; Ballet, J.; Barbiellini, G.; Bastieri, D.; Bechtol, K.; Bellazzini, R.; hide

    2012-01-01

    We report on the detection of high-energy ? -ray emission from the Moon during the first 24 months of observations by the Fermi Large Area Telescope (LAT). This emission comes from particle cascades produced by cosmicray (CR) nuclei and electrons interacting with the lunar surface. The differential spectrum of the Moon is soft and can be described as a log-parabolic function with an effective cutoff at 2-3 GeV, while the average integral flux measured with the LAT from the beginning of observations in 2008 August to the end of 2010 August is F(greater than100 MeV) = (1.04 plus or minus 0.01 [statistical error] plus or minus 0.1 [systematic error]) × 10(sup -6) cm(sup -2) s(sup -1). This flux is about a factor 2-3 higher than that observed between 1991 and 1994 by the EGRET experiment on board the Compton Gamma Ray Observatory, F(greater than100 MeV)˜5×10(sup -7) cm(sup -2) s(sup -1), when solar activity was relatively high. The higher gamma -ray flux measured by Fermi is consistent with the deep solar minimum conditions during the first 24 months of the mission, which reduced effects of heliospheric modulation, and thus increased the heliospheric flux of Galactic CRs. A detailed comparison of the light curve with McMurdo Neutron Monitor rates suggests a correlation of the trends. The Moon and the Sun are so far the only known bright emitters of gamma-rays with fast celestial motion. Their paths across the sky are projected onto the Galactic center and high Galactic latitudes as well as onto other areas crowded with high-energy gamma-ray sources. Analysis of the lunar and solar emission may thus be important for studies of weak and transient sources near the ecliptic.

  5. Fermi Observations of γ-Ray Emission from the Moon

    NASA Astrophysics Data System (ADS)

    Abdo, A. A.; Ackermann, M.; Ajello, M.; Atwoo, W. B.; Baldini, L.; Ballet, J.; Barbiellini, G.; Bastieri, D.; Bechtol, K.; Bellazzini, R.; Berenji, B.; Blandford, R. D.; Bonamente, E.; Borgland, A. W.; Bottacini, E.; Bouvier, A.; Bregeon, J.; Brigida, M.; Bruel, P.; Buehler, R.; Buson, S.; Caliandro, G. A.; Cameron, R. A.; Caraveo, P. A.; Casandjian, J. M.; Cecchi, C.; Charles, E.; Chekhtman, A.; Chiang, J.; Ciprini, S.; Claus, R.; Cohen-Tanugi, J.; Conrad, J.; Cutini, S.; D'Ammando, F.; de Angelis, A.; de Palma, F.; Dermer, C. D.; Digel, S. W.; Silva, E. do Couto e.; Drell, P. S.; Drlica-Wagner, A.; Dubois, R.; Favuzzi, C.; Fegan, S. J.; Focke, W. B.; Fortin, P.; Fukazawa, Y.; Funk, S.; Fusco, P.; Gargano, F.; Gehrels, N.; Germani, S.; Giglietto, N.; Giommi, P.; Giordano, F.; Giroletti, M.; Glanzman, T.; Godfrey, G.; Gomez-Vargas, G. A.; Grenier, I. A.; Grove, J. E.; Guiriec, S.; Hadasch, D.; Hays, E.; Hill, A. B.; Horan, D.; Hou, X.; Hughes, R. E.; Iafrate, G.; Jackson, M. S.; Jóhannesson, G.; Johnson, A. S.; Kamae, T.; Katagiri, H.; Kataoka, J.; Knödlseder, J.; Kuss, M.; Lande, J.; Larsson, S.; Latronico, L.; Lemoine-Goumard, M.; Longo, F.; Loparco, F.; Lott, B.; Lovellette, M. N.; Lubrano, P.; Mazziotta, M. N.; McEnery, J. E.; Mehault, J.; Michelson, P. F.; Mitthumsiri, W.; Mizuno, T.; Moiseev, A. A.; Monte, C.; Monzani, M. E.; Morselli, A.; Moskalenko, I. V.; Murgia, S.; Naumann-Godo, M.; Nolan, P. L.; Norris, J. P.; Nuss, E.; Ohno, M.; Ohsugi, T.; Okumura, A.; Omodei, N.; Orienti, M.; Orlando, E.; Ormes, J. F.; Ozaki, M.; Paneque, D.; Panetta, J. H.; Parent, D.; Pesce-Rollins, M.; Pierbattista, M.; Piron, F.; Pivato, G.; Poon, H.; Porter, T. A.; Prokhorov, D.; Rainò, S.; Rando, R.; Razzano, M.; Razzaque, S.; Reimer, A.; Reimer, O.; Reposeur, T.; Rochester, L. S.; Roth, M.; Sadrozinski, H. F.-W.; Sanchez, D. A.; Sbarra, C.; Schalk, T. L.; Sgrò, C.; Share, G. H.; Siskind, E. J.; Spandre, G.; Spinelli, P.; Stawarz, Ł.; Takahashi, H.; Tanaka, T.; Thayer, J. G.; Thayer, J. B.; Thompson, D. J.; Tibaldo, L.; Tinivella, M.; Torres, D. F.; Tosti, G.; Troja, E.; Uchiyama, Y.; Usher, T. L.; Vandenbroucke, J.; Vasileiou, V.; Vianello, G.; Vitale, V.; Waite, A. P.; Wang, P.; Winer, B. L.; Wood, D. L.; Wood, K. S.; Yang, Z.; Zimmer, S.

    2012-10-01

    We report on the detection of high-energy γ-ray emission from the Moon during the first 24 months of observations by the Fermi Large Area Telescope (LAT). This emission comes from particle cascades produced by cosmic-ray (CR) nuclei and electrons interacting with the lunar surface. The differential spectrum of the Moon is soft and can be described as a log-parabolic function with an effective cutoff at 2-3 GeV, while the average integral flux measured with the LAT from the beginning of observations in 2008 August to the end of 2010 August is F(>100\\ MeV) =(1.04+/- 0.01\\,{[statistical\\ error]}+/- 0.1\\,{[systematic\\ error]})\\times 10^{-6} cm-2 s-1. This flux is about a factor 2-3 higher than that observed between 1991 and 1994 by the EGRET experiment on board the Compton Gamma Ray Observatory, F(>100 MeV) ≈ 5 × 10-7 cm-2 s-1, when solar activity was relatively high. The higher γ-ray flux measured by Fermi is consistent with the deep solar minimum conditions during the first 24 months of the mission, which reduced effects of heliospheric modulation, and thus increased the heliospheric flux of Galactic CRs. A detailed comparison of the light curve with McMurdo Neutron Monitor rates suggests a correlation of the trends. The Moon and the Sun are so far the only known bright emitters of γ-rays with fast celestial motion. Their paths across the sky are projected onto the Galactic center and high Galactic latitudes as well as onto other areas crowded with high-energy γ-ray sources. Analysis of the lunar and solar emission may thus be important for studies of weak and transient sources near the ecliptic.

  6. Constraining CO emission estimates using atmospheric observations

    NASA Astrophysics Data System (ADS)

    Hooghiemstra, P. B.

    2012-06-01

    We apply a four-dimensional variational (4D-Var) data assimilation system to optimize carbon monoxide (CO) emissions and to reduce the uncertainty of emission estimates from individual sources using the chemistry transport model TM5. In the first study only a limited amount of surface network observations from the National Oceanic and Atmospheric Administration Earth System Research Laboratory (NOAA/ESRL) Global Monitoring Division (GMD) is used to test the 4D-Var system. Uncertainty reduction up to 60% in yearly emissions is observed over well-constrained regions and the inferred emissions compare well with recent studies for 2004. However, since the observations only constrain total CO emissions, the 4D-Var system has difficulties separating anthropogenic and biogenic sources in particular. The inferred emissions are validated with NOAA aircraft data over North America and the agreement is significantly improved from the prior to posterior simulation. Validation with the Measurements Of Pollution In The Troposphere (MOPITT) instrument shows a slight improved agreement over the well-constrained Northern Hemisphere and in the tropics (except for the African continent). However, the model simulation with posterior emissions underestimates MOPITT CO total columns on the remote Southern Hemisphere (SH) by about 10%. This is caused by a reduction in SH CO sources mainly due to surface stations on the high southern latitudes. In the second study, we compare two global inversions to estimate carbon monoxide (CO) emissions for 2004. Either surface flask observations from NOAA or CO total columns from the MOPITT instrument are assimilated in a 4D-Var framework. In the Southern Hemisphere (SH) three important findings are reported. First, due to their different vertical sensitivity, the stations-only inversion increases SH biomass burning emissions by 108 Tg CO/yr more than the MOPITT-only inversion. Conversely, the MOPITT-only inversion results in SH natural emissions

  7. First approach to exhaust emissions characterization of light vehicles in Montevideo, Uruguay.

    PubMed

    D'Angelo, Mauro; González, Alice Elizabeth; Rezzano Tizze, Nicolás

    2018-03-15

    According to Act No. 17283 of November 28th, 2000, air quality protection is a general concern in Uruguay. Road transport is the main emitter of nitrogen oxides (NO x ), as the National Inventory of Air Emissions 2006 stated. Actually, it is responsible for the emissions of 59.8% of NO x and 28% of carbon monoxide (CO). The number of households owning a car in Uruguay increased from 29% in 2005 to 39% in 2013, enhancing the importance of characterizing the vehicular emissions of the national fleet. In this paper, a first approach for this characterization is presented. It was carried out on a sample of 11 light vehicles currently in use in Montevideo city, Uruguay. On-road emissions measurements of nitrogen monoxide (NO), carbon monoxide (CO) and carbon dioxide (CO 2 ) were carried out for calculating the emission factors. The fitness of the set of calculated emission factors values to different probability distributions was tested. When possible, the 95% confidence intervals were obtained for the mean emission factors (CO: 2.0g/km±0.3g/km; NO: 0.05g/km±0.01g/km). This procedure was useful to obtaining accurate confidence intervals from a relatively small sample size. Finally, the link between atmospheric emissions and some other parameters of the tested vehicles was studied using a multivariate statistical tool, highlighting the strong increase in carbon monoxide emissions observed for low vehicles speeds and fuel efficiencies. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Controls of the quantum yield and saturation light of isoprene emission in different-aged aspen leaves

    PubMed Central

    Niinemets, Ülo; Sun, Zhihong; Talts, Eero

    2018-01-01

    Leaf age alters the balance between the use of end-product of plastidic isoprenoid synthesis pathway, dimethylallyl diphosphate (DMADP), in prenyltransferase reactions leading to synthesis of pigments of photosynthetic machinery and in isoprene synthesis, but the implications of such changes on environmental responses of isoprene emission have not been studied. Because under light-limited conditions, isoprene emission rate is controlled by DMADP pool size (SDMADP), shifts in the share of different processes are expected to particularly strongly alter the light dependency of isoprene emission. We examined light responses of isoprene emission in young fully-expanded, mature and old non-senescent leaves of hybrid aspen (Populus tremula x P. tremuloides) and estimated in vivo SDMADP and isoprene synthase activity from postillumination isoprene release. Isoprene emission capacity was 1.5-fold larger in mature than in young and old leaves. The initial quantum yield of isoprene emission (αI) increased by 2.5-fold with increasing leaf age primarily as the result of increasing SDMADP. The saturating light intensity (QI90) decreased by 2.3-fold with increasing leaf age, and this mainly reflected limited light-dependent increase of SDMADP possibly due to feedback inhibition by DMADP. These major age-dependent changes in the shape of the light response need consideration in modeling canopy isoprene emission. PMID:26037962

  9. Controls of the quantum yield and saturation light of isoprene emission in different-aged aspen leaves.

    PubMed

    Niinemets, Ülo; Sun, Zhihong; Talts, Eero

    2015-12-01

    Leaf age alters the balance between the use of end-product of plastidic isoprenoid synthesis pathway, dimethylallyl diphosphate (DMADP), in prenyltransferase reactions leading to synthesis of pigments of photosynthetic machinery and in isoprene synthesis, but the implications of such changes on environmental responses of isoprene emission have not been studied. Because under light-limited conditions, isoprene emission rate is controlled by DMADP pool size (SDMADP ), shifts in the share of different processes are expected to particularly strongly alter the light dependency of isoprene emission. We examined light responses of isoprene emission in young fully expanded, mature and old non-senescent leaves of hybrid aspen (Populus tremula x P. tremuloides) and estimated in vivo SDMADP and isoprene synthase activity from post-illumination isoprene release. Isoprene emission capacity was 1.5-fold larger in mature than in young and old leaves. The initial quantum yield of isoprene emission (αI ) increased by 2.5-fold with increasing leaf age primarily as the result of increasing SDMADP . The saturating light intensity (QI90 ) decreased by 2.3-fold with increasing leaf age, and this mainly reflected limited light-dependent increase of SDMADP possibly due to feedback inhibition by DMADP. These major age-dependent changes in the shape of the light response need consideration in modelling canopy isoprene emission. © 2015 John Wiley & Sons Ltd.

  10. Study of emissions from light-duty vehicles in Denver. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1981-08-31

    A sample of 300 light-duty vehicles normally operated in the Denver metropolitan area was tested for emissions and fuel economy. The vehicles were from the 1978 through 1982 model years and included both passenger cars and light-duty trucks. One purpose of the program was to gather information for calculations and projections of ambient air quality. Another purpose was to assemble data on current model year vehicles for use in the support of Inspection/Maintenance and other regulatory programs. The vehicles were tested for exhaust emissions utilizing the Federal Test Procedure, the Highway Fuel Economy Test (HFET), and four short mode tests.more » 125 vehicles from the 1980-82 model years received an evaporative emission test using the sealed housing evaporative determination (SHED) technique. Other actions were taken in relation to each vehicle tested. These included an engine and emission control system maladjustment/disablement and status inspection, driveability evaluations, and owner interviews to obtain vehicle maintenance and usage data.« less

  11. Light emission from compound eye with conformal fluorescent coating

    NASA Astrophysics Data System (ADS)

    Martín-Palma, Raúl J.; Miller, Amy E.; Pulsifer, Drew P.; Lakhtakia, Akhlesh

    2015-03-01

    Compound eyes of insects are attractive biological systems for engineered biomimicry as artificial sources of light, given their characteristic wide angular field of view. A blowfly eye was coated with a thin conformal fluorescent film, with the aim of achieving wide field-of-view emission. Experimental results showed that the coated eye emitted visible light and that the intensity showed a weaker angular dependence than a fluorescent thin film deposited on a flat surface.

  12. Vehicle, driver and atmospheric factors in light-duty vehicle particle number emissions.

    DOT National Transportation Integrated Search

    2014-06-01

    Made possible by the collection of on-board tailpipe emissions data, this research identifies road : and driver factors that are associated with a relatively understudied tailpipe pollutant from light-duty vehicles: ultrafine particle number emission...

  13. Mg+ and other metallic emissions observed in the thermosphere

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gardner, J.A.; Viereck, R.A.; Murad, E.

    1994-11-17

    Limb observations of UV dayglow emissions from 80 to 300 km tangent heights were made in December 1992, using the GLO instrument, which flew on STS-53 as a Hitchhiker-G experiment. STS-53 was at 330 km altitude and had an orbit inclination of 57 deg. The orbit placed the shuttle near the terminator for the entire mission, resulting in a unique set of observations. The GLO instrument consisted of 12 imagers and 9 spectrographs on an Az/El gimbal system. The data was obtained over 6 days of the mission. Emissions from Mg+ and Ca+ were observed, as were emissions from themore » neutral metallic species Mg and Na. The ultimate source of the metals is ablation of meteors; however, the spatial distribution of the emissions is controlled by upper mesospheric and thermospheric winds and, in the case of the ions, by the electromagnetic fields of the ionosphere. The observed Mg+ emission was the brightest of the metal emissions, and was observed near the poles and around the geomagnetic equator near sunset. The polar emissions were short-lived and intense, indicative of auroral activity. The equatorial emissions were more continuous, with several luminous patches propagation poleward over the period of several orbits. The instrumentation will be described, as will spatial and temporal variations of the metal emissions with emphasis on the metal ions. These observations will be compared to previous observations of thermospheric metallic species.« less

  14. Temperature effects on particulate matter emissions from light-duty, gasoline-powered motor vehicles

    EPA Science Inventory

    The Kansas City Light-Duty Vehicle Emissions study measured exhaust emissions of regulated and unregulated pollutants from over 500 vehicles randomly recruited in the Kansas City metropolitan area in 2004 and 2005. Vehicle emissions testing occurred during the summer and winter, ...

  15. Unusually high frequency natural VLF radio emissions observed during daytime in Northern Finland

    NASA Astrophysics Data System (ADS)

    Manninen, Jyrki; Turunen, Tauno; Kleimenova, Natalia; Rycroft, Michael; Gromova, Liudmila; Sirviö, Iina

    2016-12-01

    Geomagnetic field variations and electromagnetic waves of different frequencies are ever present in the Earth’s environment in which the Earth’s fauna and flora have evolved and live. These waves are a very useful tool for studying and exploring the physics of plasma processes occurring in the magnetosphere and ionosphere. Here we present ground-based observations of natural electromagnetic emissions of magnetospheric origin at very low frequency (VLF, 3-30 kHz), which are neither heard nor seen in their spectrograms because they are hidden by strong impulsive signals (sferics) originating in lightning discharges. After filtering out the sferics, peculiar emissions are revealed in these digital recordings, made in Northern Finland, at unusually high frequencies in the VLF band. These recently revealed emissions, which are observed for several hours almost every day in winter, contain short (˜1-3 min) burst-like structures at frequencies above 4-6 kHz, even up to 15 kHz; fine structure on the 1 s time scale is also prevalent. It seems that these whistler mode emissions are generated deep inside the magnetosphere, but the detailed nature, generation region and propagation behaviour of these newly discovered high latitude VLF emissions remain unknown; however, further research on them may shed new light on wave-particle interactions occurring in the Earth’s radiation belts.

  16. Fine particulate matter emissions inventories: comparisons of emissions estimates with observations from recent field programs.

    PubMed

    Simon, Heather; Allen, David T; Wittig, Ann E

    2008-02-01

    Emissions inventories of fine particulate matter (PM2.5) were compared with estimates of emissions based on data emerging from U.S. Environment Protection Agency Particulate Matter Supersites and other field programs. Six source categories for PM2.5 emissions were reviewed: on-road mobile sources, nonroad mobile sources, cooking, biomass combustion, fugitive dust, and stationary sources. Ammonia emissions from all of the source categories were also examined. Regional emissions inventories of PM in the exhaust from on-road and nonroad sources were generally consistent with ambient observations, though uncertainties in some emission factors were twice as large as the emission factors. In contrast, emissions inventories of road dust were up to an order of magnitude larger than ambient observations, and estimated brake wear and tire dust emissions were half as large as ambient observations in urban areas. Although comprehensive nationwide emissions inventories of PM2.5 from cooking sources and biomass burning are not yet available, observational data in urban areas suggest that cooking sources account for approximately 5-20% of total primary emissions (excluding dust), and biomass burning sources are highly dependent on region. Finally, relatively few observational data were available to assess the accuracy of emission estimates for stationary sources. Overall, the uncertainties in primary emissions for PM2.s are substantial. Similar uncertainties exist for ammonia emissions. Because of these uncertainties, the design of PM2.5 control strategies should be based on inventories that have been refined by a combination of bottom-up and top-down methods.

  17. Novel Strategy for Photopatterning Emissive Polymer Brushes for Organic Light Emitting Diode Applications

    PubMed Central

    2017-01-01

    A light-mediated methodology to grow patterned, emissive polymer brushes with micron feature resolution is reported and applied to organic light emitting diode (OLED) displays. Light is used for both initiator functionalization of indium tin oxide and subsequent atom transfer radical polymerization of methacrylate-based fluorescent and phosphorescent iridium monomers. The iridium centers play key roles in photocatalyzing and mediating polymer growth while also emitting light in the final OLED structure. The scope of the presented procedure enables the synthesis of a library of polymers with emissive colors spanning the visible spectrum where the dopant incorporation, position of brush growth, and brush thickness are readily controlled. The chain-ends of the polymer brushes remain intact, affording subsequent chain extension and formation of well-defined diblock architectures. This high level of structure and function control allows for the facile preparation of random ternary copolymers and red–green–blue arrays to yield white emission. PMID:28691078

  18. Novel Strategy for Photopatterning Emissive Polymer Brushes for Organic Light Emitting Diode Applications.

    PubMed

    Page, Zachariah A; Narupai, Benjaporn; Pester, Christian W; Bou Zerdan, Raghida; Sokolov, Anatoliy; Laitar, David S; Mukhopadhyay, Sukrit; Sprague, Scott; McGrath, Alaina J; Kramer, John W; Trefonas, Peter; Hawker, Craig J

    2017-06-28

    A light-mediated methodology to grow patterned, emissive polymer brushes with micron feature resolution is reported and applied to organic light emitting diode (OLED) displays. Light is used for both initiator functionalization of indium tin oxide and subsequent atom transfer radical polymerization of methacrylate-based fluorescent and phosphorescent iridium monomers. The iridium centers play key roles in photocatalyzing and mediating polymer growth while also emitting light in the final OLED structure. The scope of the presented procedure enables the synthesis of a library of polymers with emissive colors spanning the visible spectrum where the dopant incorporation, position of brush growth, and brush thickness are readily controlled. The chain-ends of the polymer brushes remain intact, affording subsequent chain extension and formation of well-defined diblock architectures. This high level of structure and function control allows for the facile preparation of random ternary copolymers and red-green-blue arrays to yield white emission.

  19. Gamma-ray emission from SN2014J near maximum optical light

    NASA Astrophysics Data System (ADS)

    Isern, J.; Jean, P.; Bravo, E.; Knödlseder, J.; Lebrun, F.; Churazov, E.; Sunyaev, R.; Domingo, A.; Badenes, C.; Hartmann, D. H.; Hoeflich, P.; Renaud, M.; Soldi, S.; Elias-Rosa, N.; Hernanz, M.; Domínguez, I.; García-Senz, D.; Lichti, G. G.; Vedrenne, G.; Von Ballmoos, P.

    2016-04-01

    Context. The optical light curve of Type Ia supernovae (SNIa) is powered by thermalized gamma-rays produced by the decay of 56Ni and 56Co, the main radioactive isotopes synthesized by the thermonuclear explosion of a C/O white dwarf. Aims: Gamma-rays escaping the ejecta can be used as a diagnostic tool for studying the characteristics of the explosion. In particular, it is expected that the analysis of the early gamma emission, near the maximum of the optical light curve, could provide information about the distribution of the radioactive elements in the debris. Methods: The gamma data obtained from SN2014J in M 82 by the instruments on board INTEGRAL were analysed paying special attention to the effect that the detailed spectral response has on the measurements of the intensity of the lines. Results: The 158 keV emission of 56Ni has been detected in SN2014J at ~5σ at low energy with both ISGRI and SPI around the maximum of the optical light curve. After correcting the spectral response of the detector, the fluxes in the lines suggest that, in addition to the bulk of radioactive elements buried in the central layers of the debris, there is a plume of 56Ni, with a significance of ~3σ, moving at high velocity and receding from the observer. The mass of the plume is in the range of ~0.03-0.08 M⊙. Conclusions: No SNIa explosion model has ever predicted the mass and geometrical distribution of 56Ni suggested here. According to its optical properties, SN2014J looks like a normal SNIa, so it is extremely important to discern whether it is also representative in the gamma-ray band. Based on observations with INTEGRAL, an ESA project with instruments and the science data centre funded by ESA member states (especially the PI countries: Denmark, France, Germany, Italy, Switzerland, and Spain), the Czech Republic, and Poland and with the participation of Russia and USA.

  20. Light-cone observables and gauge-invariance in the geodesic light-cone formalism

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Scaccabarozzi, Fulvio; Yoo, Jaiyul, E-mail: fulvio@physik.uzh.ch, E-mail: jyoo@physik.uzh.ch

    The remarkable properties of the geodesic light-cone (GLC) coordinates allow analytic expressions for the light-cone observables, providing a new non-perturbative way for calculating the effects of inhomogeneities in our Universe. However, the gauge-invariance of these expressions in the GLC formalism has not been shown explicitly. Here we provide this missing part of the GLC formalism by proving the gauge-invariance of the GLC expressions for the light-cone observables, such as the observed redshift, the luminosity distance, and the physical area and volume of the observed sources. Our study provides a new insight on the properties of the GLC coordinates and itmore » complements the previous work by the GLC collaboration, leading to a comprehensive description of light propagation in the GLC representation.« less

  1. Development of large volume double ring penning plasma discharge source for efficient light emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Prakash, Ram; Vyas, Gheesa Lal; Jain, Jalaj

    In this paper, the development of large volume double ring Penning plasma discharge source for efficient light emissions is reported. The developed Penning discharge source consists of two cylindrical end cathodes of stainless steel having radius 6 cm and a gap 5.5 cm between them, which are fitted in the top and bottom flanges of the vacuum chamber. Two stainless steel anode rings with thickness 0.4 cm and inner diameters 6.45 cm having separation 2 cm are kept at the discharge centre. Neodymium (Nd{sub 2}Fe{sub 14}B) permanent magnets are physically inserted behind the cathodes for producing nearly uniform magnetic fieldmore » of {approx}0.1 T at the center. Experiments and simulations have been performed for single and double anode ring configurations using helium gas discharge, which infer that double ring configuration gives better light emissions in the large volume Penning plasma discharge arrangement. The optical emission spectroscopy measurements are used to complement the observations. The spectral line-ratio technique is utilized to determine the electron plasma density. The estimated electron plasma density in double ring plasma configuration is {approx}2 Multiplication-Sign 10{sup 11} cm{sup -3}, which is around one order of magnitude larger than that of single ring arrangement.« less

  2. Development of large volume double ring penning plasma discharge source for efficient light emissions.

    PubMed

    Prakash, Ram; Vyas, Gheesa Lal; Jain, Jalaj; Prajapati, Jitendra; Pal, Udit Narayan; Chowdhuri, Malay Bikas; Manchanda, Ranjana

    2012-12-01

    In this paper, the development of large volume double ring Penning plasma discharge source for efficient light emissions is reported. The developed Penning discharge source consists of two cylindrical end cathodes of stainless steel having radius 6 cm and a gap 5.5 cm between them, which are fitted in the top and bottom flanges of the vacuum chamber. Two stainless steel anode rings with thickness 0.4 cm and inner diameters 6.45 cm having separation 2 cm are kept at the discharge centre. Neodymium (Nd(2)Fe(14)B) permanent magnets are physically inserted behind the cathodes for producing nearly uniform magnetic field of ~0.1 T at the center. Experiments and simulations have been performed for single and double anode ring configurations using helium gas discharge, which infer that double ring configuration gives better light emissions in the large volume Penning plasma discharge arrangement. The optical emission spectroscopy measurements are used to complement the observations. The spectral line-ratio technique is utilized to determine the electron plasma density. The estimated electron plasma density in double ring plasma configuration is ~2 × 10(11) cm(-3), which is around one order of magnitude larger than that of single ring arrangement.

  3. Light emission from silicon: Some perspectives and applications

    NASA Astrophysics Data System (ADS)

    Fiory, A. T.; Ravindra, N. M.

    2003-10-01

    Research on efficient light emission from silicon devices is moving toward leading-edge advances in components for nano-optoelectronics and related areas. A silicon laser is being eagerly sought and may be at hand soon. A key advantage is in the use of silicon-based materials and processing, thereby using high yield and low-cost fabrication techniques. Anticipated applications include an optical emitter for integrated optical circuits, logic, memory, and interconnects; electro-optic isolators; massively parallel optical interconnects and cross connects for integrated circuit chips; lightwave components; high-power discrete and array emitters; and optoelectronic nanocell arrays for detecting biological and chemical agents. The new technical approaches resolve a basic issue with native interband electro-optical emission from bulk Si, which competes with nonradiative phonon- and defect-mediated pathways for electron-hole recombination. Some of the new ways to enhance optical emission efficiency in Si diode devices rely on carrier confinement, including defect and strain engineering in the bulk material. Others use Si nanocrystallites, nanowires, and alloying with Ge and crystal strain methods to achieve the carrier confinement required to boost radiative recombination efficiency. Another approach draws on the considerable progress that has been made in high-efficiency, solar-cell design and uses the reciprocity between photo- and light-emitting diodes. Important advances are also being made with silicon-oxide materials containing optically active rare-earth impurities.

  4. White light emission of dysprosium doped lanthanum calcium phosphate oxide and oxyfluoride glasses

    NASA Astrophysics Data System (ADS)

    Luewarasirikul, N.; Kim, H. J.; Meejitpaisan, P.; Kaewkhao, J.

    2017-04-01

    Lanthanum calcium phosphate oxide and oxyfluoride glasses doped with dysprosium oxide were prepared by melt-quenching technique with chemical composition 20La2O3:10CaO:69P2O5:1Dy2O3 and 20La2O3:10CaF2:69P2O5:1Dy2O3. The physical, optical and luminescence properties of the glass samples were studied to evaluate their potential to using as luminescence materials for solid-state lighting applications. The density, molar volume and refractive index of the glass samples were carried out. The optical and luminescence properties were studied by investigating absorption, excitation, and emission spectra of the glass samples. The absorption spectra were investigated in the UV-Vis-NIR region from 300 to 2000 nm. The excitation spectra observed under 574 nm emission wavelength showed the highest peak centered at 349 nm (6H15/2 → 6P7/2). The emission spectra, excited with 349 nm excitation wavelength showed two major peaks corresponding to 482 nm blue emission (4F9/2 → 6H15/2) and 574 nm yellow emission (4F9/2 → 6H13/2). The experimental lifetime were found to be 0.539 and 0.540 for oxide and oxyfluoride glass sample, respectively. The x,y color coordinates under 349 nm excitation wavelength were (0.38, 0.43) for both glass samples, that be plotted in white region of CIE 1931 chromaticity diagram. The CCT values obtained from the glass samples are 4204 K for oxide glass and 4228 K for oxyfluoride glass corresponding to the commercial cool white light (3100-4500 K). Judd-Ofelt theory had also been employed to obtain the J-O parameters (Ω2, Ω4 and Ω6), oscillator strength, radiative transition possibility, stimulated emission cross section and branching ratio. The Ω2 > Ω4 > Ω6 trend of J-O parameters of both glass samples may indicate the good quality of a glass host for using as optical device application. Temperature dependence of emission spectra was studied from 300 K to 10 K and found that the intensity of the emission peak was found to be increased with

  5. 40 CFR 86.1717-99 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-99 Section 86.1717-99 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

  6. 40 CFR 86.1717-01 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-01 Section 86.1717-01 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

  7. 40 CFR 86.1717-99 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-99 Section 86.1717-99 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

  8. 40 CFR 86.1717-01 - Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission control diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. 86.1717-01 Section 86.1717-01 Protection of... diagnostic system for 1999 and later light-duty vehicles and light-duty trucks. (a) The provisions of § 86...

  9. The emission function of ground-based light sources: State of the art and research challenges

    NASA Astrophysics Data System (ADS)

    Solano Lamphar, Héctor Antonio

    2018-05-01

    To understand the night sky radiance generated by the light emissions of urbanised areas, different researchers are currently proposing various theoretical approaches. The distribution of the radiant intensity as a function of the zenith angle is one of the most unknown properties on modelling skyglow. This is due to the collective effects of the artificial radiation emitted from the ground-based light sources. The emission function is a key property in characterising the sky brightness under arbitrary conditions, therefore it is required by modellers, environmental engineers, urban planners, light pollution researchers, and experimentalists who study the diffuse light of the night sky. As a matter of course, the emission function considers the public lighting system, which is in fact the main generator of the skyglow. Still, another class of light-emitting devices are gaining importance since their overuse and the urban sprawl of recent years. This paper will address the importance of the emission function in modelling skyglow and the factors involved in its characterization. On this subject, the author's intention is to organise, integrate, and evaluate previously published research in order to state the progress of current research toward clarifying this topic.

  10. Fabrication, Light Emission, and Magnetism of Silica Nanoparticles Hybridized with AIE Luminogens and Inorganic Nanostructures

    NASA Astrophysics Data System (ADS)

    Faisal, Mahtab

    Much research efforts have been devoted in developing new synthetic approaches for fluorescent silica nanoparticles (FSNPs) due to their potential high-technological applications. However, light emissions from most of the FSNPs prepared so far have been rather weak. This is due to the emission quenching caused by the aggregation of fluorophores in the solid state. We have observed a novel phenomenon of aggregation-induced emission (AIE): a series of propeller-shaped molecules such as tetraphenylethene (TPE) and silole are induced to emit efficiently by aggregate formation. Thus, they are ideal fluorophors for the construction of FSNPs and my thesis work focuses on the synthesis of silica nanoparticles containing these luminogens and magnetic nanostructures. Highly emissive FSNPs with core-shell structures are fabricated by surfactant-free sol-gel reactions of tetraphenylethene- (TPE) and silole-functionalized siloxanes followed by the reactions with tetraethoxysilane. The FSNPs are uniformly sized, surface-charged and colloidally stable. The diameters of the FSNPs are tunable in the range of 45--295 nm by changing the reaction conditions. Whereas their TPE and silole precursors are non-emissive, the FSNPs emit strong visible lights, thanks to the novel aggregation-induced emission characteristics of the TPE and silole aggregates in the hybrid nanoparticles. The FSNPs pose no toxicity to living cells and can be utilized to selectively image cytoplasm of HeLa cells. Applying the same tool in the presence of citrate-coated magnetite nanoparticles, uniform magnetic fluorescent silica nanoparticles (MFSNPs) with smooth surfaces are fabricated. These particles exhibit appreciable surface charges and hence good colloidal stability. They are superparamagnetic, exhibiting no hysteresis at room temperature. UV irradiation of a suspension of MFSNPs in ethanol gives strong blue and green emissions. The MFSNPs can selectively stain the cytoplasmic regions of the living cells

  11. Panchromatic Observations of the Textbook GRB 110205A: Constraining Physical Mechanisms of Prompt Emission and Afterglow

    NASA Technical Reports Server (NTRS)

    Zheng, W.; Shen, R. F.; Sakamoto, T.; Beardmore, A. P.; De Pasquale, M.; Wu, X. F.; Gorosabel, J.; Urata, Y.; Sugita, S.; Zhang, B.; hide

    2011-01-01

    We present a comprehensive analysis of a bright, long duration (T(sub 90) approx. 257 s) GRB 110205A at redshift z = 2.22. The optical prompt emission was detected by Swift/UVOT, ROTSE-IIIb and BOOTES telescopes when the GRB was still radiating in the gamma-ray band. Thanks to its long duration, nearly 200 s of observations were obtained simultaneously from optical, X-ray to gamma-ray (1 eV - 5 MeV), which makes it one of the exceptional cases to study the broadband spectral energy distribution across 6 orders of magnitude in energy during the prompt emission phase. In particular, by fitting the time resolved prompt spectra, we clearly identify, for the first time, an interesting two-break energy spectrum, roughly consistent with the standard GRB synchrotron emission model in the fast cooling regime. Although the prompt optical emission is brighter than the extrapolation of the best fit X/ -ray spectra, it traces the -ray light curve shape, suggesting a relation to the prompt high energy emission. The synchrotron + synchrotron self-Compton (SSC) scenario is disfavored by the data, but the models invoking a pair of internal shocks or having two emission regions can interpret the data well. Shortly after prompt emission (approx. 1100 s), a bright (R = 14.0) optical emission hump with very steep rise ( alpha approx. 5.5) was observed which we interpret as the emission from the reverse shock. It is the first time that the rising phase of a reverse shock component has been closely observed.

  12. Time-resolved light emission of a, c, and r-cut sapphires shock-compressed to 65 GPa

    NASA Astrophysics Data System (ADS)

    Liu, Q. C.; Zhou, X. M.

    2018-04-01

    To investigate light emission and dynamic deformation behaviors, sapphire (single crystal Al2O3) samples with three crystallographic orientations (a, c, and r-cut) were shock-compressed by the planar impact method, with final stress ranges from 47 to 65 GPa. Emission radiance and velocity versus time profiles were simultaneously measured with a fast pyrometer and a Doppler pin system in each experiment. Wave profile results show anisotropic elastic-plastic transitions, which confirm the literature observations. Under final shock stress of about 52 GPa, lower emission intensity is observed in the r-cut sample, in agreement with the previous report in the literature. When final shock stress increases to 57 GPa and 65 GPa, spectral radiance histories of the r-cut show two stages of distinct features. In the first stage, the emission intensity of r-cut is lower than those of the other two, which agrees with the previous report in the literature. In the second stage, spectral radiance of r-cut increases with time at much higher rate and it finally peaks over those of the a and c-cut. These observations (conversion of intensified emission in the r-cut) may indicate activation of a second slip system and formation of shear bands which are discussed with the resolved shear stress calculations for the slip systems in each of the three cuts under shock compression.

  13. CORRELATION OF HARD X-RAY AND WHITE LIGHT EMISSION IN SOLAR FLARES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuhar, Matej; Krucker, Säm; Battaglia, Marina

    A statistical study of the correlation between hard X-ray and white light emission in solar flares is performed in order to search for a link between flare-accelerated electrons and white light formation. We analyze 43 flares spanning GOES classes M and X using observations from the Reuven Ramaty High Energy Solar Spectroscopic Imager and Helioseismic and Magnetic Imager. We calculate X-ray fluxes at 30 keV and white light fluxes at 6173 Å summed over the hard X-ray flare ribbons with an integration time of 45 s around the peak hard-X ray time. We find a good correlation between hard X-raymore » fluxes and excess white light fluxes, with a highest correlation coefficient of 0.68 for photons with energy of 30 keV. Assuming the thick target model, a similar correlation is found between the deposited power by flare-accelerated electrons and the white light fluxes. The correlation coefficient is found to be largest for energy deposition by electrons above ∼50 keV. At higher electron energies the correlation decreases gradually while a rapid decrease is seen if the energy provided by low-energy electrons is added. This suggests that flare-accelerated electrons of energy ∼50 keV are the main source for white light production.« less

  14. Blue light emission from trivalent cerium doped in sol-gel silica glass

    NASA Astrophysics Data System (ADS)

    Tokumitsu, Seika; Murakami, Yukon; Oda, Hisaya; Kawabe, Yutaka

    2017-02-01

    Rare earths in glass matrices are promising for active optical devices as amplifiers and lasers. Emission originating from d-f transitions in sol-gel glass has not been studied very often, while those based on f-f transitions were widely utilized. However, d-f emission in rare earths is very important because of their strong oscillator strength and broad emission widths suitable for the application to scintillators and solid-state lasers. Co-doping of aluminum in sol-gel synthesis was known to be effective for the emission enhancement of trivalent terbium and europium. Recently, we applied aluminum co-doping to cerium and europium systems in sol-gel glass to succeed in the observation of strong blue light emission originating from d-f transitions. Glass samples were prepared with conventional sol-gel process where tetramethylorthosilicate was hydrolyzed in the mixture of water, ethanol and dimethylformamide with nitric acid catalyst. After adding cerium nitrate and aluminum nitrate, the solution experienced drying followed by calcination at 1,050°C under air environment. When molar ratio of cerium to silicon was adjusted at 0.1% and Al concentration was varied in 0.1 2.0%, transparent glass products showed bright and broad blue photoluminescence under UV illumination. The fluorescence lifetimes were found to be about 50 90 ns, indicating that the emission was due to d-f transitions. Considering the simplicity of the process, blue phosphors based on sol-gel glass will be very promising for future applications.

  15. Enhancing Light Emission of ZnO-Nanofilm/Si-Micropillar Heterostructure Arrays by Piezo-Phototronic Effect.

    PubMed

    Li, Xiaoyi; Chen, Mengxiao; Yu, Ruomeng; Zhang, Taiping; Song, Dongsheng; Liang, Renrong; Zhang, Qinglin; Cheng, Shaobo; Dong, Lin; Pan, Anlian; Wang, Zhong Lin; Zhu, Jing; Pan, Caofeng

    2015-06-22

    n-ZnO nanofilm/p-Si micropillar heterostructure light-emitting diode (LED) arrays for white light emissions are achieved and the light emission intensity of LED array is enhanced by 120% under -0.05% compressive strains. These results indicate a promising approach to fabricate Si-based light-emitting components with high performances enhanced by piezo-phototronic effect, with potential applications in touchpad technology, personalized signatures, smart skin, and silicon-based photonic integrated circuits. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Room temperature synthesis of Mn2+ doped ZnS d-dots and observation of tunable dual emission: Effects of doping concentration, temperature, and ultraviolet light illumination

    NASA Astrophysics Data System (ADS)

    Kole, A. K.; Tiwary, C. S.; Kumbhakar, P.

    2013-03-01

    Mn2+ doped (0-50.0 molar %) ZnS d-dots have been synthesized in water medium by using an environment friendly low cost chemical technique. Tunable dual emission in UV and yellow-orange regions is achieved by tailoring the Mn2+ doping concentration in the host ZnS nanocrystal. The optimum doping concentration for achieving efficient photoluminescence (PL) emission is determined to be ˜1.10 (at. %) corresponding to 40.0 (molar %) of Mn2+ doping concentration used during synthesis. The mechanism of charge transfer from the host to the dopant leading to the intensity modulated tunable (594-610 nm) yellow-orange PL emission is straightforwardly understood as no capping agent is used. The temperature dependent PL emission measurements are carried out, viz., in 1.10 at. % Mn2+ doped sample and the experimental results are explained by using a theoretical PL emission model. It is found that the ratio of non-radiative to radiative recombination rates is temperature dependent and this phenomenon has not been reported, so far, in Mn2+ doped ZnS system. The colour tuning of the emitted light from the samples are evident from the calculated chromaticity coordinates. UV light irradiation for 150 min in 40.0 (molar %) Mn2+ doped sample shows an enhancement of 33% in PL emission intensity.

  17. Evaluation of NPP-VIIRS Nighttime Light Data for Mapping Global Fossil Fuel Combustion CO2 Emissions: A Comparison with DMSP-OLS Nighttime Light Data.

    PubMed

    Ou, Jinpei; Liu, Xiaoping; Li, Xia; Li, Meifang; Li, Wenkai

    2015-01-01

    Recently, the stable light products and radiance calibrated products from Defense Meteorological Satellite Program's (DMSP) Operational Linescan System (OLS) have been useful for mapping global fossil fuel carbon dioxide (CO2) emissions at fine spatial resolution. However, few studies on this subject were conducted with the new-generation nighttime light data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor on the Suomi National Polar-orbiting Partnership (NPP) Satellite, which has a higher spatial resolution and a wider radiometric detection range than the traditional DMSP-OLS nighttime light data. Therefore, this study performed the first evaluation of the potential of NPP-VIIRS data in estimating the spatial distributions of global CO2 emissions (excluding power plant emissions). Through a disaggregating model, three global emission maps were then derived from population counts and three different types of nighttime lights data (NPP-VIIRS, the stable light data and radiance calibrated data of DMSP-OLS) for a comparative analysis. The results compared with the reference data of land cover in Beijing, Shanghai and Guangzhou show that the emission areas of map from NPP-VIIRS data have higher spatial consistency of the artificial surfaces and exhibit a more reasonable distribution of CO2 emission than those of other two maps from DMSP-OLS data. Besides, in contrast to two maps from DMSP-OLS data, the emission map from NPP-VIIRS data is closer to the Vulcan inventory and exhibits a better agreement with the actual statistical data of CO2 emissions at the level of sub-administrative units of the United States. This study demonstrates that the NPP-VIIRS data can be a powerful tool for studying the spatial distributions of CO2 emissions, as well as the socioeconomic indicators at multiple scales.

  18. Evaluation of NPP-VIIRS Nighttime Light Data for Mapping Global Fossil Fuel Combustion CO2 Emissions: A Comparison with DMSP-OLS Nighttime Light Data

    PubMed Central

    Ou, Jinpei; Liu, Xiaoping; Li, Xia; Li, Meifang; Li, Wenkai

    2015-01-01

    Recently, the stable light products and radiance calibrated products from Defense Meteorological Satellite Program’s (DMSP) Operational Linescan System (OLS) have been useful for mapping global fossil fuel carbon dioxide (CO2) emissions at fine spatial resolution. However, few studies on this subject were conducted with the new-generation nighttime light data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensor on the Suomi National Polar-orbiting Partnership (NPP) Satellite, which has a higher spatial resolution and a wider radiometric detection range than the traditional DMSP-OLS nighttime light data. Therefore, this study performed the first evaluation of the potential of NPP-VIIRS data in estimating the spatial distributions of global CO2 emissions (excluding power plant emissions). Through a disaggregating model, three global emission maps were then derived from population counts and three different types of nighttime lights data (NPP-VIIRS, the stable light data and radiance calibrated data of DMSP-OLS) for a comparative analysis. The results compared with the reference data of land cover in Beijing, Shanghai and Guangzhou show that the emission areas of map from NPP-VIIRS data have higher spatial consistency of the artificial surfaces and exhibit a more reasonable distribution of CO2 emission than those of other two maps from DMSP-OLS data. Besides, in contrast to two maps from DMSP-OLS data, the emission map from NPP-VIIRS data is closer to the Vulcan inventory and exhibits a better agreement with the actual statistical data of CO2 emissions at the level of sub-administrative units of the United States. This study demonstrates that the NPP-VIIRS data can be a powerful tool for studying the spatial distributions of CO2 emissions, as well as the socioeconomic indicators at multiple scales. PMID:26390037

  19. 40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

  20. 40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

  1. 40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

  2. 40 CFR 86.708-94 - In-use emission standards for 1994 and later model year light-duty vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Later Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.708-94 In-use emission standards for... exhaust emissions from 1994 and later model year light-duty vehicles shall meet all standards in tables... applicable Tier 1I standards in table H94-3. (2) Particulates. For in-use exhaust emissions for model years...

  3. Beamed neutron emission driven by laser accelerated light ions

    NASA Astrophysics Data System (ADS)

    Kar, S.; Green, A.; Ahmed, H.; Alejo, A.; Robinson, A. P. L.; Cerchez, M.; Clarke, R.; Doria, D.; Dorkings, S.; Fernandez, J.; Mirfayzi, S. R.; McKenna, P.; Naughton, K.; Neely, D.; Norreys, P.; Peth, C.; Powell, H.; Ruiz, J. A.; Swain, J.; Willi, O.; Borghesi, M.

    2016-05-01

    Highly anisotropic, beam-like neutron emission with peak flux of the order of 109 n/sr was obtained from light nuclei reactions in a pitcher-catcher scenario, by employing MeV ions driven by a sub-petawatt laser. The spatial profile of the neutron beam, fully captured for the first time by employing a CR39 nuclear track detector, shows a FWHM divergence angle of ˜ 70^\\circ , with a peak flux nearly an order of magnitude higher than the isotropic component elsewhere. The observed beamed flux of neutrons is highly favourable for a wide range of applications, and indeed for further transport and moderation to thermal energies. A systematic study employing various combinations of pitcher-catcher materials indicates the dominant reactions being d(p, n+p)1H and d(d,n)3He. Albeit insufficient cross-section data are available for modelling, the observed anisotropy in the neutrons’ spatial and spectral profiles is most likely related to the directionality and high energy of the projectile ions.

  4. Broadband white light emission from Ce:AlN ceramics: High thermal conductivity down-converters for LED and laser-driven solid state lighting

    NASA Astrophysics Data System (ADS)

    Wieg, A. T.; Penilla, E. H.; Hardin, C. L.; Kodera, Y.; Garay, J. E.

    2016-12-01

    We introduce high thermal conductivity aluminum nitride (AlN) as a transparent ceramic host for Ce3+, a well-known active ion dopant. We show that the Ce:AlN ceramics have overlapping photoluminescent (PL) emission peaks that cover almost the entire visible range resulting in a white appearance under 375 nm excitation without the need for color mixing. The PL is due to a combination of intrinsic AlN defect complexes and Ce3+ electronic transitions. Importantly, the peak intensities can be tuned by varying the Ce concentration and processing parameters, causing different shades of white light without the need for multiple phosphors or light sources. The Commission Internationale de l'Eclairage coordinates calculated from the measured spectra confirm white light emission. In addition, we demonstrate the viability of laser driven white light emission by coupling the Ce:AlN to a readily available frequency tripled Nd-YAG laser emitting at 355 nm. The high thermal conductivity of these ceramic down-converters holds significant promise for producing higher power white light sources than those available today.

  5. SPECIATED VOC EMISSIONS FROM MODERN GDI LIGHT ...

    EPA Pesticide Factsheets

    Chassis dynamometer emissions testing was conducted to characterize speciated volatile organic compounds (VOCs), including mobile source air toxics (MSATs) and ozone precursors, in exhaust emissions from three modern gasoline direct injection (GDI) light-duty vehicles. Each GDI vehicle tested in this study utilized slightly different fuel injection technology: Vehicle 1 used a 2.4 liter, naturally aspirated, wall-guided GDI; Vehicle 2 used a 1.8 liter, turbocharged GDI engine; Vehicle 3 used a 1.5 liter, turbocharged, spray-guided GDI engine. Vehicle testing was conducted in a temperature controlled chassis dynamometer test cell at 22 °C over the EPA Federal Test Procedure (FTP) and a portion of the Supplemental FTP (SFTP). The FTP was conducted as a three phase cycle with a cold start, hot transient, and warm start phase (also known as the FTP-75 driving cycle). The SFTP consisted of the US06 driving cycle (conducted without the vehicle’s air conditioning on), which provides a more aggressive driving pattern than the FTP. The vehicles operated on 10 percent ethanol blended gasoline (E10). VOC emissions from diluted vehicle exhaust were sampled over each FTP phase and over the Supplemental FTP with SUMMA canisters for EPA Method TO-15 analysis and with DNPH cartridges for carbonyl analysis by EPA Method TO-11A. This presentation will report the impact of driving cycle and GDI technology on speciated MSAT emissions. MSAT emission rates will be compared

  6. Estimating global per-capita carbon emissions with VIIRS nighttime lights satellite data

    NASA Astrophysics Data System (ADS)

    Jasmin, T.; Desai, A. R.; Pierce, R. B.

    2015-12-01

    With the launch of the Suomi National Polar-orbiting Partnership (NPP) satellite in November 2011, we now have nighttime lights remote sensing capability vastly improved over the predecessor Defense Meteorological Satellite Program (DMSP), owing to improved spatial and radiometric resolution provided by the Visible Infrared Imaging Radiometer Suite (VIIRS) Day Night Band (DNB) along with technology improvements in data transfer, processing, and storage. This development opens doors for improving novel scientific applications utilizing remotely sensed low-level visible light, for purposes ranging from estimating population to inferring factors relating to economic development. For example, the success of future international agreements to reduce greenhouse gas emissions will be dependent on mechanisms to monitor remotely for compliance. Here, we discuss implementation and evaluation of the VRCE system (VIIRS Remote Carbon Estimates), developed at the University of Wisconsin-Madison, which provides monthly independent, unbiased estimates of per-capita carbon emissions. Cloud-free global composites of Earth nocturnal lighting are generated from VIIRS DNB at full spatial resolution (750 meter). A population equation is derived from a linear regression of DNB radiance sums at state level to U.S. Census data. CO2 emissions are derived from a linear regression of VIIRS DNB radiance sums to U.S. Department of Energy emission estimates. Regional coefficients for factors such as percentage of energy use from renewable sources are factored in, and together these equations are used to generate per-capita CO2 emission estimates at the country level.

  7. A tiered observational system for anthropogenic methane emissions

    NASA Astrophysics Data System (ADS)

    Duren, R. M.; Miller, C. E.; Hulley, G. C.; Hook, S. J.; Sander, S. P.

    2014-12-01

    Improved understanding of anthropogenic methane emissions is required for closing the global carbon budget and addressing priority challenges in climate policy. Several decades of top-down and bottom-up studies show that anthropogenic methane emissions are systematically underestimated in key regions and economic sectors. These uncertainties have been compounded by the dramatic rise of disruptive technologies (e.g., the transformation in the US energy system due to unconventional gas and oil production). Methane flux estimates derived from inverse analyses and aircraft-based mass balance approaches underscore the disagreement in nationally and regionally reported methane emissions as well as the possibility of a long-tail distribution in fugitive emissions spanning the US natural gas supply chain; i.e. a small number of super-emitters may be responsible for most of the observed anomalies. Other studies highlight the challenges of sectoral and spatial attribution of fugitive emissions - including the relative contributions of dairies vs oil and gas production or disentangling the contributions of natural gas transmission, distribution, and consumption or landfill emissions in complex urban environments. Limited observational data remains a foundational barrier to resolving these challenges. We present a tiered observing system strategy for persistent, high-frequency monitoring over large areas to provide remote detection, geolocation and quantification of significant anthropogenic methane emissions across cities, states, basins and continents. We describe how this would both improve confidence in methane emission estimates and expedite resolution of fugitive emissions and leaks. We summarize recent prototype field campaigns that employ multiple vantage points and measurement techniques (including NASA's CARVE and HyTES aircraft and PanFTS instrument on Mt Wilson). We share preliminary results of this tiered observational approach including examples of individual

  8. Colorado SIP: Reg 11, Motor Vehicle Emissions Inspection Program—Part F, Maximum Allowable Emissions Limits for Motor Vehicle Exhaust, Evaporative and Visible Emissions for Light-Duty and Heavy-Duty Vehicles

    EPA Pesticide Factsheets

    Colorado SIP: Reg 11, Motor Vehicle Emissions Inspection Program—Part F, Maximum Allowable Emissions Limits for Motor Vehicle Exhaust, Evaporative and Visible Emissions for Light-Duty and Heavy-Duty Vehicles

  9. Cluster observations and simulations of He+ EMIC triggered emissions

    NASA Astrophysics Data System (ADS)

    Grison, B.; Shoji, M.; Santolik, O.; Omura, Y.

    2012-12-01

    EMIC triggered emissions have been reported in the inner magnetosphere at the edge of the plasmapause nightside [Pickett et al., 2010]. The generation mechanism proposed by Omura et al. [2010] is very similar to the one of the whistler chorus emissions and simulation results agree with observations and theory [Shoji et Omura, 2011]. The main characteristics of these emissions generated in the magnetic equatorial plane region are a frequency with time dispersion and a high level of coherence. The start frequency of previously mentioned observations is above half of the proton gyrofrequency. It means that the emissions are generated on the proton branch. On the He+ branch, generation of triggered emissions, in the same region, requests more energetic protons and the triggering process starts below the He+ gyrofrequency. It makes their identification in Cluster data rather difficult. Recent simulation results confirm the possibility of EMIC triggered emission on the He+ branch. In the present contribution we propose to compare a Cluster event to simulation results in order to investigate the possibility to identify observations to a He+ triggered emission. The impact of the observed waves on particle precipitation is also investigated.

  10. White Light Emission and Enhanced Color Stability in a Single-Component Host.

    PubMed

    Li, Junhao; Liang, Qiongyun; Hong, Jun-Yu; Yan, Jing; Dolgov, Leonid; Meng, Yuying; Xu, Yiqin; Shi, Jianxin; Wu, Mingmei

    2018-05-30

    Eu 3+ ion can be effectively sensitized by Ce 3+ ion through an energy-transfer chain of Ce 3+ -(Tb 3+ ) n -Eu 3+ , which has contributed to the development of white light-emitting diodes (WLEDs) as it can favor more efficient red phosphors. However, simply serving for WLEDs as one of the multicomponents, the design of the Ce 3+ -(Tb 3+ ) n -Eu 3+ energy transfer is undoubtedly underused. Theoretically, white light can be achieved with extra blue and green emissions released from Ce 3+ and Tb 3+ . Herein, the design of the white light based on these three multicolor luminescence centers has been realized in GdBO 3 . It is the first time that white light is generated via accurate controls on the Ce 3+ -(Tb 3+ ) n -Eu 3+ energy transfer in such a widely studied host material. Because the thermal quenching rates of blue, green, and red emissions from Ce 3+ , Tb 3+ , and Eu 3+ , respectively, are well-matched in the host, this novel white light exhibits superior color stability and potential application prospect.

  11. Mg{sup +} and other metallic emissions observed in the thermosphere

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gardner, J.A.; Viereck, R.A.; Murad, E.

    1994-12-31

    Limb observations of UV dayglow emissions from 80 to 300 km tangent heights were made in December, 1992, using the GLO instrument, which flew on STS-53 as a Hitchhiker-G experiment. STS-53 was at 330 km altitude and had an orbit inclination of 57{degree}. The orbit placed the shuttle near the terminator for the entire mission, resulting in a unique set of observations. The GLO instrument consisted of 12 imagers and 9 spectrographs on an Az/El gimbal system. The data was obtained over 6 days of the mission. Emissions from Mg{sup +} and Ca{sup +} were observed, as were emissions frommore » the neutral metallic species Mg and Na. The ultimate source of the metals is ablation of meteors; however, the spatial distribution of the emissions is controlled by upper mesospheric and thermospheric winds and, in the case of the ions, by the electromagnetic fields of the ionosphere. The observed Mg{sup +} emission was the brightest of the metal emissions, and was observed near the poles and around the geomagnetic equator near sunset. The polar emissions were short-lived and intense, indicative of auroral activity. The equatorial emissions were more continuous, with several luminous patches propagating poleward over the period of several orbits. The instrumentation will be described, as will spatial and temporal variations of the metal emissions with emphasis on the metal ions. These observations will be compared to previous observations of thermospheric metallic species.« less

  12. Visualization of Nanoplasmonic Coupling to Molecular Orbital in Light Emission Induced by Tunneling Electrons.

    PubMed

    Yu, Arthur; Li, Shaowei; Wang, Hui; Chen, Siyu; Wu, Ruqian; Ho, W

    2018-05-09

    The coupling between localized plasmon and molecular orbital in the light emission from a metallic nanocavity has been directly detected and imaged with sub-0.1 nm resolution. The light emission intensity was enhanced when the energy difference between the tunneling electrons and the lowest unoccupied molecular orbital (LUMO) of an azulene molecule matches the energy of a plasmon mode of the nanocavity defined by the Ag-tip and Ag (110) substrate of a scanning tunneling microscope (STM). The spatially resolved image of the light emission intensity matches the spatial distribution of the LUMO obtained by scanning tunneling spectroscopy (STS) and density functional theory (DFT) calculations. Our results highlight the near-field coupling of a molecular orbital to the radiative decay of a plasmonic excitation in a confined nanoscale junction.

  13. An organic white light-emitting dye: very small molecular architecture displays panchromatic emission.

    PubMed

    Nandhikonda, Premchendar; Heagy, Michael D

    2010-11-14

    The synthesis and photophysical characterization of a new white-light fluorophore is described. The optimization of excitation wavelengths allows the naphthalimide (NI) dyes to display blue, green or white light emission depending on the excitation wavelength.

  14. Proteins involved in biophoton emission and flooding-stress responses in soybean under light and dark conditions.

    PubMed

    Kamal, Abu Hena Mostafa; Komatsu, Setsuko

    2016-02-01

    To know the molecular systems basically flooding conditions in soybean, biophoton emission measurements and proteomic analyses were carried out for flooding-stressed roots under light and dark conditions. Photon emission was analyzed using a photon counter. Gel-free quantitative proteomics were performed to identify significant changes proteins using the nano LC-MS along with SIEVE software. Biophoton emissions were significantly increased in both light and dark conditions after flooding stress, but gradually decreased with continued flooding exposure compared to the control plants. Among the 120 significantly identified proteins in the roots of soybean plants, 73 and 19 proteins were decreased and increased in the light condition, respectively, and 4 and 24 proteins were increased and decreased, respectively, in the dark condition. The proteins were mainly functionally grouped into cell organization, protein degradation/synthesis, and glycolysis. The highly abundant lactate/malate dehydrogenase proteins were decreased in flooding-stressed roots exposed to light, whereas the lysine ketoglutarate reductase/saccharopine dehydrogenase bifunctional enzyme was increased in both light and dark conditions. Notably, however, specific enzyme assays revealed that the activities of these enzymes and biophoton emission were sharply increased after 3 days of flooding stress. This finding suggests that the source of biophoton emission in roots might involve the chemical excitation of electron or proton through enzymatic or non-enzymatic oxidation and reduction reactions. Moreover, the lysine ketoglutarate reductase/saccharopine dehydrogenase bifunctional enzyme may play important roles in responses in flooding stress of soybean under the light condition and as a contributing factor to biophoton emission.

  15. Substrate dependence of TM-polarized light emission characteristics of BAlGaN/AlN quantum wells

    NASA Astrophysics Data System (ADS)

    Park, Seoung-Hwan; Ahn, Doyeol

    2018-06-01

    To study the substrate dependence of light emission characteristics of transverse-magnetic (TM)-polarized light emitted from BAlGaN/AlN quantum wells (QWs) grown on GaN and AlN substrates were investigated theoretically. It is found that the topmost valence subband for QW structures grown on AlN substrate, is heavy hole state (HH1) while that for QW structures grown on GaN substrate is crystal-field split off light hole state (CL1), irrespective of the boron content. Since TM-polarized light emission is associated with the light hole state, the TM-polarized emission peak of BAlGaN/AlN QW structures grown on GaN substrate is expected to be much larger than that of the QW structure grown on AlN substrate. Also, both QW structures show that the spontaneous emission peak of BAlGaN/AlN QW structures would be improved with the inclusion of the boron. However, it rapidly begins to decrease when the boron content exceeds a critical value.

  16. Blue light emission from ZnO-graphene hybrid quantum dot (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Choi, Won Kook; Kim, Hong Hee; Park, Cheolmin; Hwang, Do Kyung; Lee, Yeonju

    2017-03-01

    One of a wide-bandgap semiconductor, Zinc oxide (ZnO) has a near ultraviolet bandgap (3.37 eV) and an exciton binding energy of 60 meV at room temperature (RT), and has several favorable properties, such as high electron mobility, high oscillator strength, and good transparency. In the photoluminescence (PL) spectra of ZnO nanoparticles, the near band edge ultraviolet (UV) emission at 378 nm relevant to direct bandgap of ZnO, and blue light emissions centered at 410, 435, and 465 nm corresponding to Zn interstitial (Zni) to valence band maximum (VBM), and to Zn vacancies (VZn) and green light emission at 540 nm corresponding to conduction band maximum (CBM) to oxygen vacancy (Vo). Ultra-small size quasi consolidated ZnO-graphene nanoparticles was synthesized in which graphene outer layer was chemically attached with ZnO inner core. After attaching graphene to ZnO, green emission completely disappeared whereas the intensity of blue emission was greatly increased. Enhanced blue emission could be well described by both fast electron transfer from CBM of ZnO to graphene having similar molecular energy level with Zni and transition to VBM and Vzn. Glass/ITO/PEDOT:PSS/poly-TPD/ZnO-graphene/Cs2CO3/Al were fabricated and showed the blue emission centered at 435 nm with FWHM of about 90 nm.

  17. Light trapping for emission from a photovoltaic cell under normally incident monochromatic illumination

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Takeda, Yasuhiko, E-mail: takeda@mosk.tytlabs.co.jp; Iizuka, Hideo; Mizuno, Shintaro

    2014-09-28

    We have theoretically demonstrated a new light-trapping mechanism to reduce emission from a photovoltaic (PV) cell used for a monochromatic light source, which improves limiting conversion efficiency determined by the detailed balance. A multilayered bandpass filter formed on the surface of a PV cell has been found to prevent the light generated inside by radiative recombination from escaping the cell, resulting in a remarkable decrease of the effective solid angle for the emission. We have clarified a guide to design a suitable configuration of the bandpass filter and achieved significant reduction of the emission. The resultant gain in monochromatic conversionmore » efficiency in the radiative limit due to the optimally designed 18-layerd bandpass filters is as high as 6% under normally incident 1064 nm illumination of 10 mW/cm²~ 1 kW/cm², compared with the efficiency for the perfect anti-reflection treatment to the surface of a conventional solar cell.« less

  18. Comparisons of MOVES Light-duty Gasoline NOx Emission Rates with Real-world Measurements

    NASA Astrophysics Data System (ADS)

    Choi, D.; Sonntag, D.; Warila, J.

    2017-12-01

    Recent studies have shown differences between air quality model estimates and monitored values for nitrogen oxides. Several studies have suggested that the discrepancy between monitored and modeled values is due to an overestimation of NOx from mobile sources in EPA's emission inventory, particularly for light-duty gasoline vehicles. EPA's MOtor Vehicle Emission Simulator (MOVES) is an emission modeling system that estimates emissions for cars, trucks and other mobile sources at the national, county, and project level for criteria pollutants, greenhouse gases, and air toxics. Studies that directly measure vehicle emissions provide useful data for evaluating MOVES when the measurement conditions are properly accounted for in modeling. In this presentation, we show comparisons of MOVES2014 to thousands of real-world NOx emissions measurements from individual light-duty gasoline vehicles. The comparison studies include in-use vehicle emissions tests conducted on chassis dynamometer tests in support of Denver, Colorado's Vehicle Inspection & Maintenance Program and remote sensing data collected using road-side instruments in multiple locations and calendar years in the United States. In addition, we conduct comparisons of MOVES predictions to fleet-wide emissions measured from tunnels. We also present details on the methodology used to conduct the MOVES model runs in comparing to the independent data.

  19. Fracto-mechanoluminescent light emission of EuD4TEA-PDMS composites subjected to high strain-rate compressive loading

    NASA Astrophysics Data System (ADS)

    Ryu, Donghyeon; Castaño, Nicolas; Bhakta, Raj; Kimberley, Jamie

    2017-08-01

    The objective of this study is to understand light emission characteristics of fracto-mechanoluminescent (FML) europium tetrakis(dibenzoylmethide)-triethylammonium (EuD4TEA) crystals under high strain-rate compressive loading. As a sensing material that can play a pivotal role for the self-powered impact sensor technology, it is important to understand transformative light emission characteristics of the FML EuD4TEA crystals under high strain-rate compressive loading. First, EuD4TEA crystals were synthesized and embedded into polydimethylsiloxane (PDMS) elastomer to fabricate EuD4TEA-PDMS composite test specimens. Second, the prepared EuD4TEA-PDMS composites were tested using the modified Kolsky bar setup equipped with a high-speed camera. Third, FML light emission was captured to yield 12 bit grayscale video footage, which was processed to quantify the FML light emission. Finally, quantitative parameters were generated by taking into account pixel values and population of pixels of the 12 bit grayscale images to represent FML light intensity. The FML light intensity was correlated with high strain-rate compressive strain and strain rate to understand the FML light emission characteristics under high strain-rate compressive loading that can result from impact occurrences.

  20. Cold Temperature Effects on Speciated VOC Emissions from modern GDI Light Duty Truck

    EPA Science Inventory

    Although gasoline direct injection (GDI) vehicles represent nearly half of the light-duty vehicle market share, few studies have reported speciated volatile organic compounds (VOCs) in GDI vehicle exhaust emissions. In this study, speciated VOC emissions were characterized from t...

  1. Energetics and timing of the hard and soft X-ray emissions in white light flares

    NASA Technical Reports Server (NTRS)

    Neidig, Donald F.; Kane, Sharad R.

    1993-01-01

    By comparing the light curves in optical, hard X-ray, and soft X-ray wavelengths for eight well-observed flares, we confirm previous results indicating that the white light flare (WLF) is associated with the flare impulsive phase. The WLF emission peaks within seconds after the associated hard X-ray peak, and nearly two minutes before the 1-8 A soft X-ray peak. It is further shown that the peak power in nonthermal electrons above 50 keV is typically an order of magnitude larger, and the power in 1-8 A soft X-rays radiated over 2pi sr, at the time of the WLF peak, is an order of magnitude smaller than the peak WLF power.

  2. How light, temperature, and measurement and growth [CO2] interactively control isoprene emission in hybrid aspen

    PubMed Central

    Niinemets, Ülo; Sun, Zhihong

    2015-01-01

    Plant isoprene emissions have been modelled assuming independent controls by light, temperature and atmospheric [CO2]. However, the isoprene emission rate is ultimately controlled by the pool size of its immediate substrate, dimethylallyl diphosphate (DMADP), and isoprene synthase activity, implying that the environmental controls might interact. In addition, acclimation to growth [CO2] can shift the share of the control by DMADP pool size and isoprene synthase activity, and thereby alter the environmental sensitivity. Environmental controls of isoprene emission were studied in hybrid aspen (Populus tremula × Populus tremuloides) saplings acclimated either to ambient [CO2] of 380 μmol mol–1 or elevated [CO2] of 780 μmol mol–1. The data demonstrated strong interactive effects of environmental drivers and growth [CO2] on isoprene emissions. Light enhancement of isoprene emission was the greatest at intermediate temperatures and was greater in elevated-[CO2]-grown plants, indicating greater enhancement of the DMADP supply. The optimum temperature for isoprene emission was higher at lower light, suggesting activation of alternative DMADP sinks at higher light. In addition, [CO2] inhibition of isoprene emission was lost at a higher temperature with particularly strong effects in elevated-[CO2]-grown plants. Nevertheless, DMADP pool size was still predicted to more strongly control isoprene emission at higher temperatures in elevated-[CO2]-grown plants. We argue that interactive environmental controls and acclimation to growth [CO2] should be incorporated in future isoprene emission models at the level of DMADP pool size. PMID:25399006

  3. Carrier Conduction and Light Emission by Modification of Poly(alkylfluorene) Interface under Vacuum Ultraviolet Light Irradiation

    NASA Astrophysics Data System (ADS)

    Ohmori, Yutaka; Kajii, Hirotake; Terashima, Daiki; Kusumoto, Yusuke

    2013-03-01

    Organic field effect transistors (OFETs) have been extensively studied for flexible electronics. The characteristics of poly(9,9-dioctylfluorenyl-2,7-dyl) (F8) modified by thermal or light are strongly dependent on the carrier transport and optical characteristics. We investigate all solution-processed OFETs with Ag nano-ink as gate electrodes patterned by Vacuum Ultraviolet (VUV) (172 nm). Bi-layer gate insulators of amorphous fluoro-polymer CYTOP (Asahi Glass Corp.) and poly(methylmethacrylate) (PMMA) were used. Top-gate-type OFETs with ITO source/drain electrode utilizing F8 or poly(9,9-dioctylfluorene-co-benzothiadiazole) (F8BT) as an active layer were fabricated, and investigated the carrier conduction and emission characteristic. Without VUV irradiation, both OFETs showed the ambipolar and light-emitting characteristics. On the other hand, F8 devices with VUV exhibited only p-type conduction. The quenching centers were generated in F8 layer by VUV irradiation, which are related to the electron trap sites at the interface. OFETs with F8BT showed both p- and n-type conduction even after VUV. F8BT suffers less damage by VUV and maintain light emission. Light emitting transistors were realized utilizing F8BT patterned by VUV irradiation. This research was partially supported financially by MEXT. The authors thank Harima Chemicals Inc. for providing Ag nano-ink.

  4. Radio and white-light observations of coronal transients

    NASA Technical Reports Server (NTRS)

    Dulk, G. A.

    1980-01-01

    Optical, radio and X-ray evidence of violent mass motions in the corona has existed for some years but only recently have the form, nature, frequency and implication of the transients become obvious. In this paper the observed properties of coronal transients are reviewed, with concentration on the white-light and radio manifestations. The classification according to speeds seems to be meaningful, with the slow transients having thermal emissions at radio wavelengths and the fast ones nonthermal. The possible mechanisms involved in the radio bursts are then discussed and estimates of various forms of energy are reviewed. It appears that the magnetic energy transported from the sun by the transient exceeds that of any other form, and that magnetic forces dominate in the dynamics of the motions. The conversion of magnetic energy into mechanical energy, by expansion of the field, provides a possible driving force for the coronal and interplanetary shock waves.

  5. Jupiter emission observed near 1 MHz

    NASA Technical Reports Server (NTRS)

    Brown, L. W.

    1974-01-01

    Emission from Jupiter has been observed by the IMP-6 spacecraft at 19 frequencies between 600 and 9900 kHz covering the period from April 1971 to October 1972. The Jovian bursts were identified in the IMP-6 data through the phase of the observed modulated signal detected from the spinning dipole antenna. Initial data reduction has isolated 177 events over a span of 500 days. These events persisted over a period between 1 and 60 min. Of these events at least 48 occurred during times in which Jupiter emission was being observed at either 16.7 or 22.2 MHz by ground-based instruments of the Goddard Space Flight Center Jupiter monitoring system. Large bursts were detectable from 9900 kHz down to 600 kHz, while smaller bursts ranged down to 1030 kHz.-

  6. Multi-Wavelength Spectroscopic Observations of a White Light Flare Produced Directly by Non-thermal Electrons

    NASA Astrophysics Data System (ADS)

    Lee, Kyoung-Sun; Imada, Shinsuke; Watanabe, Kyoko; Bamba, Yumi; Brooks, David

    2017-08-01

    An X1.6 flare on 2014 October 22 was observed by multiple spectrometers in UV, EUV and X-ray (Hinode/EIS, IRIS, and RHESSI), and multi-wavelength imaging observations (SDO/AIA and HMI). We analyze a bright kernel that produces a white light (WL) flare with continuum enhancement and a hard X-ray (HXR) peak. Taking advantage of the spectroscopic observations of IRIS and Hinode/EIS, we measure the temporal variation of the plasma properties in the bright kernel in the chromosphere and corona. We find that explosive evaporation was observed when the WL emission occurred. The temporal correlation of the WL emission, HXR peak, and evaporation flows indicates that the WL emission was produced by accelerated electrons. We calculated the energy flux deposited by non-thermal electrons (observed by RHESSI) and compared it to the dissipated energy estimated from a chromospheric line (Mg II triplet) observed by IRIS. The deposited energy flux from the non-thermal electrons is about (3-7.7)x1010 erg cm-2 s-1 for a given low-energy cutoff of 30-40 keV, assuming the thick-target model. The energy flux estimated from the changes in temperature in the chromosphere measured using the Mg II subordinate line is about (4.6-6.7)×109 erg cm-2 s-1: ˜6%-22% of the deposited energy. This comparison of estimated energy fluxes implies that the continuum enhancement was directly produced by the non-thermal electrons.

  7. Observations of emission lines in M supergiants

    NASA Technical Reports Server (NTRS)

    Lambert, D. L.

    1979-01-01

    Copernicus observations of Mg 2 h and k emission lines from M giants and supergiants are described. Supergiants with extensive circumstellar gas shells show an asymmetric k line. The asymmetry is ascribed to superimposed lines of Fe 1 and Mn 1. The Mg 2 line width fit the Wilson-Bappu relation derived from observations of G and K Stars. Results of correlated ground-based observations include (1) the discovery of K 1 fluorescent emission from the Betelgeuse shell; (2) extimates of the mass-loss rates; and (3) the proposal that silicate dust grains must account for the major fraction of the Si atoms in the Betelgeuse shell.

  8. Pulsar Emission Geometry and Accelerating Field Strength

    NASA Technical Reports Server (NTRS)

    DeCesar, Megan E.; Harding, Alice K.; Miller, M. Coleman; Kalapotharakos, Constantinos; Parent, Damien

    2012-01-01

    The high-quality Fermi LAT observations of gamma-ray pulsars have opened a new window to understanding the generation mechanisms of high-energy emission from these systems, The high statistics allow for careful modeling of the light curve features as well as for phase resolved spectral modeling. We modeled the LAT light curves of the Vela and CTA I pulsars with simulated high-energy light curves generated from geometrical representations of the outer gap and slot gap emission models. within the vacuum retarded dipole and force-free fields. A Markov Chain Monte Carlo maximum likelihood method was used to explore the phase space of the magnetic inclination angle, viewing angle. maximum emission radius, and gap width. We also used the measured spectral cutoff energies to estimate the accelerating parallel electric field dependence on radius. under the assumptions that the high-energy emission is dominated by curvature radiation and the geometry (radius of emission and minimum radius of curvature of the magnetic field lines) is determined by the best fitting light curves for each model. We find that light curves from the vacuum field more closely match the observed light curves and multiwavelength constraints, and that the calculated parallel electric field can place additional constraints on the emission geometry

  9. Engineering light emission of two-dimensional materials in both the weak and strong coupling regimes

    NASA Astrophysics Data System (ADS)

    Brotons-Gisbert, Mauro; Martínez-Pastor, Juan P.; Ballesteros, Guillem C.; Gerardot, Brian D.; Sánchez-Royo, Juan F.

    2018-01-01

    Two-dimensional (2D) materials have promising applications in optoelectronics, photonics, and quantum technologies. However, their intrinsically low light absorption limits their performance, and potential devices must be accurately engineered for optimal operation. Here, we apply a transfer matrix-based source-term method to optimize light absorption and emission in 2D materials and related devices in weak and strong coupling regimes. The implemented analytical model accurately accounts for experimental results reported for representative 2D materials such as graphene and MoS2. The model has been extended to propose structures to optimize light emission by exciton recombination in MoS2 single layers, light extraction from arbitrarily oriented dipole monolayers, and single-photon emission in 2D materials. Also, it has been successfully applied to retrieve exciton-cavity interaction parameters from MoS2 microcavity experiments. The present model appears as a powerful and versatile tool for the design of new optoelectronic devices based on 2D semiconductors such as quantum light sources and polariton lasers.

  10. 40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

  11. 40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

  12. 40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

  13. 40 CFR 86.709-94 - In-use emission standards for 1994 and later model year light-duty trucks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Model Year Light-Duty Vehicles and Light-Duty Trucks § 86.709-94 In-use emission standards for 1994 and... exhaust emissions from 1994 and later model year light light-duty trucks shall meet all standards in... standards in tables H94-9 and H94-10. (ii) For model years 1996 and 1997, a minimum of the percentages shown...

  14. Radio Emission from Algol. I. Coronal Geometry and Emission Mechanisms Determined from VLBA and Green Bank Interferometer Observations

    NASA Astrophysics Data System (ADS)

    Mutel, R. L.; Molnar, L. A.; Waltman, E. B.; Ghigo, F. D.

    1998-11-01

    from optically thin emission regions containing mildly relativistic electrons in a dipolar magnetic field. There is no evidence for highly circularly polarized coherent flares at 8.3 GHz, although it is possible that such flares occasionally occur at 2.25 GHz. The lack of orbital phase dependence in the GBI light curves, combined with the significant inclination of the VLBA structure with respect to the orbital plane, is inconsistent with previous models in which the radio lobes are located in the equatorial plane. The individual lobes seen in the VLBI maps may be associated with the polar regions, with the strong circular polarization resulting from the opposed mean magnetic field vector component along the observer's line of sight in opposite hemispheres. Astrometric results from the VLBA observations are discussed in a companion paper.

  15. Ba2Mg(BO3)2:Bi3+ - A new phosphor with ultraviolet light emission

    NASA Astrophysics Data System (ADS)

    Lakshminarasimhan, N.; Jayakiruba, S.; Prabhavathi, K.

    2017-10-01

    Ultraviolet light emission was observed in a new Ba2Mg(BO3)2:Bi3+ phosphor. Bi3+ substitution for Ba2+ in the lattice was supplemented with K+ to maintain the charge neutrality. The samples of the formula Ba2-2xBixKxMg(BO3)2 [x = 0, 0.001, 0.01, 0.02, and 0.05] synthesized by solid state reaction were characterized using powder X-ray diffraction for their phase formation. Raman and diffuse reflectance UV-Vis spectroscopic techniques were used to obtain information on the vibrational modes and optical properties, respectively. The room temperature photoluminescence measurements revealed an ultraviolet emission at 370 nm when excited using 304 nm wavelength and the Stokes shift is 5868 cm-1.

  16. Potency of energy saving and emission reduction from lighting system in residential sector of Indonesia

    NASA Astrophysics Data System (ADS)

    Ambarita, H.

    2018-03-01

    The Government of Indonesia (GoI) has a strong commitment to the target of decreasing energy intensity and reducing Greenhouse gas emissions. One of the significant solutions to reach the target is increasing energy efficiency in the lighting system in the residential sector. The objective of this paper is twofold, to estimate the potency of energy saving and emission reduction from lighting in the residential sector. Literature related to the lighting system in Indonesia has been reviewed to provide sufficient data for the estimation of the energy saving and emission reduction. The results show that the in the year 2016, a total of 95.33 TWh of nationally produced electricity is used in the residential sector. This is equal to 44% of total produced electricity. The number of costumers is 64.78 million houses. The average number of lamps and average wattage of lamps used in Indonesia are 8.35 points and 13.8 W, respectively. The number of lighting and percentage of electricity used for lighting in the residential sector in Indonesia are 20.03 TWh (21.02 %) and 497 million lamps, respectively. The projection shows that in the year 2026 the total energy for lighting and number of lamps in the residential sector are 25.05 TWh and 619 million, respectively. By promoting the present technology of high efficient lamps (LED), the potency of energy saving and emission reduction in 2026 are 2.6 TWh and 2.1 million tons CO2eq, respectively.

  17. Cadmium-free quantum dot light emitting devices: energy-transfer realizing pure blue emission.

    PubMed

    Ji, Wenyu; Jing, Pengtao; Fan, Yi; Zhao, Jialong; Wang, Yunjun; Kong, Xianggui

    2013-01-01

    In this study, deep blue, pure electroluminescence (EL) at 441.5 nm from a ZnSe/ZnS quantum dot light-emitting device (QD-LED) is obtained by using poly (4-butylphenyl-diphenyl-amine) (poly-TPD) as the hole-transport layer (HTL) to open up the channel for energy transfer from poly-TPD to QDs. The emission originating from HTL is observed in the QD-LED with N,N'-bis (tolyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine functionalized with two styryl groups (2-TPD) as the HTL due to inefficient energy-transfer from 2-TPD to QDs. The poly-TPD based device exhibits color-saturated blue emission with a narrow spectral bandwidth of full width at half maximum (~17.2 nm). These results explore the operating mechanism of the QD EL and signify a remarkable progress in deep blue QD-LEDs based on environmental-friendly QD materials.

  18. Engineering photonic and plasmonic light emission enhancement

    NASA Astrophysics Data System (ADS)

    Lawrence, Nathaniel

    Semiconductor photonic devices are a rapidly maturing technology which currently occupy multi-billion dollar markets in the areas of LED lighting and optical data communication. LEDs currently demonstrate the highest luminous efficiency of any light source for general lighting. Long-haul optical data communication currently forms the backbone of the global communication network. Proper design of light management is required for photonic devices, which can increase the overall efficiency or add new device functionality. In this thesis, novel methods for the control of light propagation and confinement are developed for the use in integrated photonic devices. The first part of this work focuses on the engineering of field confinement within deep subwavelength plasmonic resonators for the enhancement of light-matter interaction. In this section, plasmonic ring nanocavities are shown to form gap plasmon modes confined to the dielectric region between two metal layers. The scattering properties, near-field enhancement and photonic density of states of nanocavity devices are studied using analytic theory and 3D finite difference time domain simulations. Plasmonic ring nanocavities are fabricated and characterized using photoluminescence intensity and decay rate measurements. A 25 times increase in the radiative decay rate of Er:Si02 is demonstrated in nanocavities where light is confined to volumes as small as 0.01( ln )3. The potential to achieve lasing, due to the enhancement of stimulated emission rate in ring nanocavities, is studied as a route to Si-compatible plasmon-enhanced nanolasers. The second part of this work focuses on the manipulation of light generated in planar semiconductor devices using arrays of dielectric nanopillars. In particular, aperiodic arrays of nanopillars are engineered for omnidirectional light extraction enhancement. Arrays of Er:SiNx, nanopillars are fabricated and a ten times increase in light extraction is experimentally demonstrated

  19. RATE OF ACCLIMATION OF THE CAPACITY FOR ISOPRENE EMISSION IN RESPONSE TO LIGHT AND TEMPERATURE

    EPA Science Inventory

    Isoprene emission from plants accounts for nearly half of all non-methane hydrocarbons entering the atmosphere. Light and temperature regulate the instantaneous rate of isoprene emission, but there is increasing evidence that they also affect the capacity for isoprene emission (i...

  20. Fast Emission Estimates in China Constrained by Satellite Observations (Invited)

    NASA Astrophysics Data System (ADS)

    Mijling, B.; van der A, R.

    2013-12-01

    Emission inventories of air pollutants are crucial information for policy makers and form important input data for air quality models. Unfortunately, bottom-up emission inventories, compiled from large quantities of statistical data, are easily outdated for an emerging economy such as China, where rapid economic growth changes emissions accordingly. Alternatively, top-down emission estimates from satellite observations of air constituents have important advantages of being spatial consistent, having high temporal resolution, and enabling emission updates shortly after the satellite data become available. Constraining emissions from concentration measurements is, however, computationally challenging. Within the GlobEmission project of the European Space Agency (ESA) a new algorithm has been developed, specifically designed for fast daily emission estimates of short-lived atmospheric species on a mesoscopic scale (0.25 × 0.25 degree) from satellite observations of column concentrations. The algorithm needs only one forward model run from a chemical transport model to calculate the sensitivity of concentration to emission, using trajectory analysis to account for transport away from the source. By using a Kalman filter in the inverse step, optimal use of the a priori knowledge and the newly observed data is made. We apply the algorithm for NOx emission estimates in East China, using the CHIMERE model together with tropospheric NO2 column retrievals of the OMI and GOME-2 satellite instruments. The observations are used to construct a monthly emission time series, which reveal important emission trends such as the emission reduction measures during the Beijing Olympic Games, and the impact and recovery from the global economic crisis. The algorithm is also able to detect emerging sources (e.g. new power plants) and improve emission information for areas where proxy data are not or badly known (e.g. shipping emissions). The new emission estimates result in a better

  1. The High Energy Photons Emission from Solar Flares Observed by SZ2-XD

    NASA Astrophysics Data System (ADS)

    Wang, Huanyu; Li, Xinqiao; Ma, Yuqian; Zhang, Chengmo; Xu, Yupeng; Wang, Jingzhou; Chen, Guoming

    The spectra and light curve of near a hundred Solar X-ray Flare events, which were observed by SZ2/XD in the energy band of 10-800 keV during 2001, have been investigated. The events covered from C to X-class flares, which are shown different characters of high energy photons emission. The results will be presented in this paper. The discussions will be made especially for 3 of the brightest X-class solar flares SF010402(X20),SF010406(X5.6) and SF010415 (X14.4, a GLE event).

  2. Low-Latitude ELF Emissions Below 100Hz Observed in Taiwan

    NASA Astrophysics Data System (ADS)

    Wang, K.; Wang, Y.; Su, H.; Hsu, R.

    2005-12-01

    ELF antennas have been mounted at the Lulin Observatory (23.47oN, 120.87oE; 2862m) and National Cheng Kung University (23.00oN, 120.22oE, 32m) in Taiwan for study of global lightning activities and ELF events. We have previously reported 10-month ELF-Whistlers observations from Aug. 26, 2003 to July 13, 2004. [Wang et al., 2005]. In addition to these events, other forms of ELF emissions were also detected. In this study, an Atlas of these observed ELF emissions below 100Hz for the same period of observation is presented. Total numbers of more than 100 detected events are categorized into six groups: discrete emissions, periodic emissions, quasi-periodic emissions, hiss, chorus, and triggered emissions, according to the system of classification for VLF emissions in [Helliwell, 1965]. Nevertheless, there are still some emissions hardly to be classified. Diurnal and seasonal variations of occurrences for these ELF emission events are analyzed. Correlation between these events and storm indices will also be discussed. References Helliwell, R. A., VLF Emission, in Whistlers and Related Ionospheric Phenomena, Stanford University Press, Stanford, California, 1965. Wang . Y. C., K. Wang, H. T. Su, R. R. Hsu, Low-Latitude ELF-Whistlers observed in Taiwan, Geophys. Res. Lett., 32, L08102, doi:10.1029/2005GL022412, 20

  3. Observational limitations of Bose-Einstein photon statistics and radiation noise in thermal emission

    NASA Astrophysics Data System (ADS)

    Lee, Y.-J.; Talghader, J. J.

    2018-01-01

    For many decades, theory has predicted that Bose-Einstein statistics are a fundamental feature of thermal emission into one or a few optical modes; however, the resulting Bose-Einstein-like photon noise has never been experimentally observed. There are at least two reasons for this: (1) Relationships to describe the thermal radiation noise for an arbitrary mode structure have yet to be set forth, and (2) the mode and detector constraints necessary for the detection of such light is extremely hard to fulfill. Herein, photon statistics and radiation noise relationships are developed for systems with any number of modes and couplings to an observing space. The results are shown to reproduce existing special cases of thermal emission and are then applied to resonator systems to discuss physically realizable conditions under which Bose-Einstein-like thermal statistics might be observed. Examples include a single isolated cavity and an emitter cavity coupled to a small detector space. Low-mode-number noise theory shows major deviations from solely Bose-Einstein or Poisson treatments and has particular significance because of recent advances in perfect absorption and subwavelength structures both in the long-wave infrared and terahertz regimes. These microresonator devices tend to utilize a small volume with few modes, a regime where the current theory of thermal emission fluctuations and background noise, which was developed decades ago for free-space or single-mode cavities, has no derived solutions.

  4. How light, temperature, and measurement and growth [CO2] interactively control isoprene emission in hybrid aspen.

    PubMed

    Niinemets, Ülo; Sun, Zhihong

    2015-02-01

    Plant isoprene emissions have been modelled assuming independent controls by light, temperature and atmospheric [CO2]. However, the isoprene emission rate is ultimately controlled by the pool size of its immediate substrate, dimethylallyl diphosphate (DMADP), and isoprene synthase activity, implying that the environmental controls might interact. In addition, acclimation to growth [CO2] can shift the share of the control by DMADP pool size and isoprene synthase activity, and thereby alter the environmental sensitivity. Environmental controls of isoprene emission were studied in hybrid aspen (Populus tremula × Populus tremuloides) saplings acclimated either to ambient [CO2] of 380 μmol mol(-1) or elevated [CO2] of 780 μmol mol(-1). The data demonstrated strong interactive effects of environmental drivers and growth [CO2] on isoprene emissions. Light enhancement of isoprene emission was the greatest at intermediate temperatures and was greater in elevated-[CO2]-grown plants, indicating greater enhancement of the DMADP supply. The optimum temperature for isoprene emission was higher at lower light, suggesting activation of alternative DMADP sinks at higher light. In addition, [CO2] inhibition of isoprene emission was lost at a higher temperature with particularly strong effects in elevated-[CO2]-grown plants. Nevertheless, DMADP pool size was still predicted to more strongly control isoprene emission at higher temperatures in elevated-[CO2]-grown plants. We argue that interactive environmental controls and acclimation to growth [CO2] should be incorporated in future isoprene emission models at the level of DMADP pool size. © The Author 2014. Published by Oxford University Press on behalf of the Society for Experimental Biology.

  5. 40 CFR 86.099-9 - Emission standards for 1999 and later model year light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....099-9 Emission standards for 1999 and later model year light-duty trucks. (a)(1)(i)-(iii) [Reserved... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Emission standards for 1999 and later model year light-duty trucks. 86.099-9 Section 86.099-9 Protection of Environment ENVIRONMENTAL...

  6. 40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

  7. 40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

  8. 40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

  9. 40 CFR 86.004-9 - Emission standards for 2004 and later model year light-duty trucks.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....004-9 Emission standards for 2004 and later model year light-duty trucks. Section 86.004-9 includes... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Emission standards for 2004 and later model year light-duty trucks. 86.004-9 Section 86.004-9 Protection of Environment ENVIRONMENTAL...

  10. 40 CFR 86.099-9 - Emission standards for 1999 and later model year light-duty trucks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ....099-9 Emission standards for 1999 and later model year light-duty trucks. (a)(1)(i)-(iii) [Reserved... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Emission standards for 1999 and later model year light-duty trucks. 86.099-9 Section 86.099-9 Protection of Environment ENVIRONMENTAL...

  11. Selective scanning tunneling microscope light emission from rutile phase of VO2.

    PubMed

    Sakai, Joe; Kuwahara, Masashi; Hotsuki, Masaki; Katano, Satoshi; Uehara, Yoichi

    2016-09-28

    We observed scanning tunneling microscope light emission (STM-LE) induced by a tunneling current at the gap between an Ag tip and a VO2 thin film, in parallel to scanning tunneling spectroscopy (STS) profiles. The 34 nm thick VO2 film grown on a rutile TiO2 (0 0 1) substrate consisted of both rutile (R)- and monoclinic (M)-structure phases of a few 10 nm-sized domains at room temperature. We found that STM-LE with a certain photon energy of 2.0 eV occurs selectively from R-phase domains of VO2, while no STM-LE was observed from M-phase. The mechanism of STM-LE from R-phase VO2 was determined to be an interband transition process rather than inverse photoemission or inelastic tunneling processes.

  12. Dual-Wavelength Interferometry and Light Emission Study for Experimental Support of Dual-Wire Ablation Experiments

    NASA Astrophysics Data System (ADS)

    Hamilton, Andrew; Caplinger, James; Sotnikov, Vladimir; Sarkisov, Gennady; Leland, John

    2017-10-01

    In the Plasma Physics and Sensors Laboratory, located at Wright Patterson Air Force Base, we utilize a pulsed power source to create plasma through a wire ablation process of metallic wires. With a parallel arrangement of wires the azimuthal magnetic fields generated around each wire, along with the Ohmic current dissipation and heating occurring upon wire evaporation, launch strong radial outflows of magnetized plasmas towards the centralized stagnation region. It is in this region that we investigate two phases of the wire ablation process. Observations in the first phase are collsionless and mostly comprised of light ions ejected from the initial corona. The second phase is observed when the wire core is ablated and heavy ions dominate collisions in the stagnation region. In this presentation we will show how dual-wavelength interferometric techniques can provide information about electron and atomic densities from experiments. Additionally, we expect white-light emission to provide a qualitative confirmation of the instabilities observed from our experiments. The material is based upon work supported by the Air Force Office of Scientific Research under Award Number 16RYCOR289.

  13. Silicon Mie resonators for highly directional light emission from monolayer MoS2

    NASA Astrophysics Data System (ADS)

    Cihan, Ahmet Fatih; Curto, Alberto G.; Raza, Søren; Kik, Pieter G.; Brongersma, Mark L.

    2018-05-01

    Controlling light emission from quantum emitters has important applications, ranging from solid-state lighting and displays to nanoscale single-photon sources. Optical antennas have emerged as promising tools to achieve such control right at the location of the emitter, without the need for bulky, external optics. Semiconductor nanoantennas are particularly practical for this purpose because simple geometries such as wires and spheres support multiple, degenerate optical resonances. Here, we start by modifying Mie scattering theory developed for plane wave illumination to describe scattering of dipole emission. We then use this theory and experiments to demonstrate several pathways to achieve control over the directionality, polarization state and spectral emission that rely on a coherent coupling of an emitting dipole to optical resonances of a silicon nanowire. A forward-to-backward ratio of 20 was demonstrated for the electric dipole emission at 680 nm from a monolayer MoS2 by optically coupling it to a silicon nanowire.

  14. 40 CFR 86.1818-12 - Greenhouse gas emission standards for light-duty vehicles, light-duty trucks, and medium-duty...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...-equivalent debits for a test group using an alternative N2O or CH4 standard; GWP = 25 if calculating CH4...) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty Vehicles, Light-Duty Trucks, and Complete Otto...

  15. Violet and blue light-induced green fluorescence emissions from dental caries.

    PubMed

    Shakibaie, F; Walsh, L J

    2016-12-01

    The objective of this laboratory study was to compare violet and visible blue LED light-elicited green fluorescence emissions from enamel and dentine in healthy or carious states. Microscopic digital photography was undertaken using violet and blue LED illumination (405 nm and 455 nm wavelengths) of tooth surfaces, which were photographed through a custom-made stack of green compensating filters which removed the excitation light and allowed green fluorescence emissions to pass. Green channel pixel data were analysed. Dry sound enamel and sound root surfaces showed strong green fluorescence when excited by violet or blue lights. Regions of cavitated dental caries gave lower green fluorescence, and this was similar whether the dentine in the lesions was the same colour as normal dentine or was darkly coloured. The presence of saliva on the surface did not significantly change the green fluorescence, while the presence of blood diluted in saliva depressed green fluorescence. Using violet or blue illumination in combination with green compensating filters could potentially aid in the assessment of areas of mineral loss. © 2016 Australian Dental Association.

  16. Resonant light emission from uniaxially tensile-strained Ge microbridges

    NASA Astrophysics Data System (ADS)

    Zhou, Peiji; Xu, Xuejun; Matsushita, Sho; Sawano, Kentarou; Maruizumi, Takuya

    2018-04-01

    A highly strained germanium microbridge is a promising platform for realizing monolithically integrated lasers on a silicon substrate. However, it remains challenging to combine it with optical resonators. Here, we have observed resonant light emission peaks with Q-factors of about 180 in room-temperature photoluminescence spectra from uniaxially tensile-strained germanium microbridges. These peaks are found to correspond to the resonance in Fabry–Perot (FP) cavities formed transversely to the uniaxial stress axis. On the basis of this phenomenon, we design a Fabry–Perot cavity by adding distributed Bragg reflectors (DBRs) laterally to the microbridge. With this design, the optical performance can be optimized without disturbing to the mechanical structure. A Q-factor as high as 1400 is obtained from numerical simulation. Moreover, we prove by theoretical analysis deduction and calculation that the lateral structure will not decrease the strain, unlike the on-pad DBR structure. The structure thus provides a promising solution for the realization of highly strained germanium lasers in the future.

  17. IRIS, Hinode, SDO, and RHESSI Observations of a White Light Flare Produced Directly by Nonthermal Electrons

    NASA Astrophysics Data System (ADS)

    Lee, Kyoung-Sun; Imada, Shinsuke; Watanabe, Kyoko; Bamba, Yumi; Brooks, David H.

    2017-02-01

    An X1.6 flare occurred in active region AR 12192 on 2014 October 22 at 14:02 UT and was observed by Hinode, IRIS, SDO, and RHESSI. We analyze a bright kernel that produces a white light (WL) flare with continuum enhancement and a hard X-ray (HXR) peak. Taking advantage of the spectroscopic observations of IRIS and Hinode/EIS, we measure the temporal variation of the plasma properties in the bright kernel in the chromosphere and corona. We find that explosive evaporation was observed when the WL emission occurred, even though the intensity enhancement in hotter lines is quite weak. The temporal correlation of the WL emission, HXR peak, and evaporation flows indicates that the WL emission was produced by accelerated electrons. To understand the WL emission process, we calculated the energy flux deposited by non-thermal electrons (observed by RHESSI) and compared it to the dissipated energy estimated from a chromospheric line (Mg II triplet) observed by IRIS. The deposited energy flux from the non-thermal electrons is about (3-7.7) × 1010 erg cm-2 s-1 for a given low-energy cutoff of 30-40 keV, assuming the thick-target model. The energy flux estimated from the changes in temperature in the chromosphere measured using the Mg II subordinate line is about (4.6-6.7) × 109 erg cm-2 s-1: ˜6%-22% of the deposited energy. This comparison of estimated energy fluxes implies that the continuum enhancement was directly produced by the non-thermal electrons.

  18. Surface slope characteristics from Thermal Emission Spectrometer emission phase function observations

    NASA Astrophysics Data System (ADS)

    Edwards, C. S.; Bandfield, J. L.; Christensen, P. R.

    2006-12-01

    It is possible to obtain surface roughness characteristics, by measuring a single surface from multiple emission angles and azimuths in the thermal infrared. Surfaces will have different temperatures depending on their orientation relative to the sun. A different proportion of sunlit versus shaded surfaces will be in the field of view based on the viewing orientation, resulting in apparent temperature differences. This difference in temperature can be utilized to calculate the slope characteristics for the observed area. This technique can be useful for determining surface slope characteristics not resolvable by orbital imagery. There are two main components to this model, a surface DEM, in this case a synthetic, two dimensional sine wave surface, and a thermal model (provided by H. Kieffer). Using albedo, solar longitude, slope, azimuth, along with several other parameters, the temperature for each cell of the DEM is calculated using the thermal model. A temperature is then predicted using the same observation geometries as the Thermal Emission Spectrometer (TES) observations. A temperature difference is calculated for the two complementary viewing azimuths and emission angles from the DEM. These values are then compared to the observed temperature difference to determine the surface slope. This method has been applied to TES Emission Phase Function (EPF) observations for both the spectrometer and bolometer data, with a footprint size of 10s of kilometers. These specialized types of TES observations measure nearly the same surface from several angles. Accurate surface kinetic temperatures are obtained after the application of an atmospheric correction for the TES bolometer and/or spectrometer. Initial results include an application to the northern circumpolar dunes. An average maximum slope of ~33 degrees has been obtained, which makes physical sense since this is near the angle of repose for sand sized particles. There is some scatter in the data from separate

  19. Energy transfer and colour tunability in UV light induced Tm3+/Tb3+/Eu3+: ZnB glasses generating white light emission.

    PubMed

    Naresh, V; Gupta, Kiran; Parthasaradhi Reddy, C; Ham, Byoung S

    2017-03-15

    A promising energy transfer (Tm 3+ →Tb 3+ →Eu 3+ ) approach is brought forward to generate white light emission under ultraviolet (UV) light excitation for solid state lightening. Tm 3+ /Tb 3+ /Eu 3+ ions are combinedly doped in zinc borate glass system in view of understanding energy transfer process resulting in white light emission. Zinc borate (host) glass displayed optical and luminescence properties due to formation of Zn(II) x -[O(-II)] y centres in the ZnB glass matrix. At 360nm (UV) excitation, triply doped Tm 3+ /Tb 3+ /Eu 3+ : ZnB glasses simultaneously shown their characteristic emission bands in blue (454nm: 1 D 2 → 3 F 4 ), green (547nm: 5 D 4 → 7 F 5 ) and red (616nm: 5 D 0 → 7 F 2 ) regions. In triple ions doped glasses, energy transfer dynamics is discussed in terms of Forster-Dexter theory, excitation & emission profiles, lifetime curves and from partial energy level diagram of three ions. The role of Tb 3+ in ET from Tm 3+ →Eu 3+ was discussed using branch model. From emission decay analysis, energy transfer probability (P) and efficiency (η) were evaluated. Colour tunability from blue to white on varying (Tb 3+ , Eu 3+ ) content is demonstrated from Commission Internationale de L'Eclairage (CIE) chromaticity coordinates. Based on chromaticity coordinates, other colour related parameters like correlated colour temperature (CCT) and colour purity are also computed for the studied glass samples. An appropriate blending of such combination of rare earth ions could show better suitability as potential candidates in achieving multi-colour and warm/cold white light emission for white LEDs application in the field of solid state lightening. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. Energy transfer and colour tunability in UV light induced Tm3 +/Tb3 +/Eu3 +: ZnB glasses generating white light emission

    NASA Astrophysics Data System (ADS)

    Naresh, V.; Gupta, Kiran; Parthasaradhi Reddy, C.; Ham, Byoung S.

    2017-03-01

    A promising energy transfer (Tm3 + → Tb3 + → Eu3 +) approach is brought forward to generate white light emission under ultraviolet (UV) light excitation for solid state lightening. Tm3 +/Tb3 +/Eu3 + ions are combinedly doped in zinc borate glass system in view of understanding energy transfer process resulting in white light emission. Zinc borate (host) glass displayed optical and luminescence properties due to formation of Zn(II)x-[O(- II)]y centres in the ZnB glass matrix. At 360 nm (UV) excitation, triply doped Tm3 +/Tb3 +/Eu3 +: ZnB glasses simultaneously shown their characteristic emission bands in blue (454 nm: 1D2 → 3F4), green (547 nm: 5D4 → 7F5) and red (616 nm: 5D0 → 7F2) regions. In triple ions doped glasses, energy transfer dynamics is discussed in terms of Forster-Dexter theory, excitation & emission profiles, lifetime curves and from partial energy level diagram of three ions. The role of Tb3 + in ET from Tm3 + → Eu3 + was discussed using branch model. From emission decay analysis, energy transfer probability (P) and efficiency (η) were evaluated. Colour tunability from blue to white on varying (Tb3 +, Eu3 +) content is demonstrated from Commission Internationale de L'Eclairage (CIE) chromaticity coordinates. Based on chromaticity coordinates, other colour related parameters like correlated colour temperature (CCT) and colour purity are also computed for the studied glass samples. An appropriate blending of such combination of rare earth ions could show better suitability as potential candidates in achieving multi-colour and warm/cold white light emission for white LEDs application in the field of solid state lightening.

  1. Nonlinear optical and light emission studies of special organic molecules and crystals

    NASA Astrophysics Data System (ADS)

    Bhowmik, Achintya K.

    The nonlinear optical properties and light emission characteristics of some special organic molecules and crystals have been studied in detail. The second-order nonlinear optical effects were measured in the single- crystal films of the materials. The crystallographic orientations of the films were determined using x-ray diffraction measurements. The second-order susceptibility tensor elements of 4-aminobenzophenone (ABP) and 8- (4'-acetylphenyl)-1,4-dioxa-8- azaspiro[4.5]decane (APDA) films were measured using polarization selective second-harmonic generation experiments. The d-coefficients of ABP are: d 23 = 7.3 +/- 0.4 pm/V and d22 = 0.73 +/- 0.04 pm/V, while those of APDA are: d33 = 54 +/- 6 pm/V and d15 = 18 +/- 3 pm/V at 1064 nm. Phase-matched propagation directions were identified on the films. The application of these films in measuring ultra-short laser pulse-width was demonstrated. Polarized optical absorption and photo- luminescence were measured in 4'- dimethylamino-N-methyl-4-stilbazolium tosylate (DAST). The electro-optic properties of single- crystal films of DAST and styryl pyridinium cyanine dye (SPCD) were studied over a broad range of wavelengths. The measured r-coefficients are the largest reported in any material. Thin-film electro-optic modulators were demonstrated using these films which have insignificant insertion and propagation losses compared to the traditional waveguide based devices. The response was observed to be flat over the measured frequency range (2 kHz-100 MHz), which indicates the origin of the electro-optic effect to be predominantly electronic. Thus these materials have significant potential for applications in high-speed optical signal processing. Spectral broadening of femtosecond laser pulses in poly- [2,4 hexadiyne-1,6 diol-bis-(p-toluene sulfonate)] (PTS) single-crystals due to self-phase modulation was studied. The magnitudes of the nonlinear refractive index were determined over the wavelength range of 720-1064 nm

  2. Evaluation of solid particle number and black carbon for very low particulate matter emissions standards in light-duty vehicles.

    PubMed

    Chang, M-C Oliver; Shields, J Erin

    2017-06-01

    To reliably measure at the low particulate matter (PM) levels needed to meet California's Low Emission Vehicle (LEV III) 3- and 1-mg/mile particulate matter (PM) standards, various approaches other than gravimetric measurement have been suggested for testing purposes. In this work, a feasibility study of solid particle number (SPN, d50 = 23 nm) and black carbon (BC) as alternatives to gravimetric PM mass was conducted, based on the relationship of these two metrics to gravimetric PM mass, as well as the variability of each of these metrics. More than 150 Federal Test Procedure (FTP-75) or Supplemental Federal Test Procedure (US06) tests were conducted on 46 light-duty vehicles, including port-fuel-injected and direct-injected gasoline vehicles, as well as several light-duty diesel vehicles equipped with diesel particle filters (LDD/DPF). For FTP tests, emission variability of gravimetric PM mass was found to be slightly less than that of either SPN or BC, whereas the opposite was observed for US06 tests. Emission variability of PM mass for LDD/DPF was higher than that of both SPN and BC, primarily because of higher PM mass measurement uncertainties (background and precision) near or below 0.1 mg/mile. While strong correlations were observed from both SPN and BC to PM mass, the slopes are dependent on engine technologies and driving cycles, and the proportionality between the metrics can vary over the course of the test. Replacement of the LEV III PM mass emission standard with one other measurement metric may imperil the effectiveness of emission reduction, as a correlation-based relationship may evolve over future technologies for meeting stringent greenhouse standards. Solid particle number and black carbon were suggested in place of PM mass for the California LEV III 1-mg/mile FTP standard. Their equivalence, proportionality, and emission variability in comparison to PM mass, based on a large light-duty vehicle fleet examined, are dependent on engine

  3. GOSAT Observations of Anthropogenic Emission of Carbon Dioxide and Methane

    NASA Astrophysics Data System (ADS)

    Janardanan Achari, R.; Maksyutov, S. S.; Oda, T.; Saito, M.; W Kaiser, J.; Ganshin, A.; Matsunaga, T.; Yoshida, Y.; Yokota, T.

    2016-12-01

    Carbon dioxide (CO2) and methane (CH4) are the most important greenhouse gases in terms of radiative forcing. Anthropogenic activities such as combustion of fossil fuel (for CO2) and gas leakage, animal agriculture, rice cultivation and landfill emissions (CH4), are considered to be major sources of those emissions. Still, emission data usually depend on national emission reports, which are seldom evaluated independently. Here we present a method for delineating anthropogenic contribution to global atmospheric CO2 (2009-2014) and CH4 (2009-2012) fields using GOSAT observations of column-average dry air mole fractions (XCO2 and XCH4) and atmospheric transport model simulations using high-resolution emission inventories. The CO2 and CH4 concentration enhancement due to anthropogenic activities, are estimated with the transport model at all GOSAT observation locations using high-resolution emission inventories (ODIAC for CO2 and EDGAR for CH4). Based on this estimate, using a threshold value, the observations are classified into two categories: data influenced by the anthropogenic sources and those not including them. To extract concentration enhancements due to the anthropogenic emissions, we define a clean background (the averaged values for the data free from contamination) in 10°×10° regions over the globe and are subtracted from the individual observational data including the anthropogenic contamination. Thus the anomalies contain contributions from anthropogenic sources. These anomalies are binned and analyzed for continental scale regions and countries. For CO2, we have found global and regional linear relationships between model and observed anomalies especially for Eurasia and North America. The analysis for East Asian region showed a systematic bias that is comparable in magnitude to the reported uncertainties in emission inventories in that region. In the case of CH4, we also found a good match between inventory-based estimates and GOSAT observations for

  4. Zero- and two-dimensional hybrid carbon phosphors for high colorimetric purity white light-emission.

    PubMed

    Ding, Yamei; Chang, Qing; Xiu, Fei; Chen, Yingying; Liu, Zhengdong; Ban, Chaoyi; Cheng, Shuai; Liu, Juqing; Huang, Wei

    2018-03-01

    Carbon nanomaterials are promising phosphors for white light emission. A facile single-step synthesis method has been developed to prepare zero- and two-dimensional hybrid carbon phosphors for the first time. Zero-dimensional carbon dots (C-dots) emit bright blue luminescence under 365 nm UV light and two-dimensional nanoplates improve the dispersity and film forming ability of C-dots. As a proof-of-concept application, the as-prepared hybrid carbon phosphors emit bright white luminescence in the solid state, and the phosphor-coated blue LEDs exhibit high colorimetric purity white light-emission with a color coordinate of (0.3308, 0.3312), potentially enabling the successful application of white emitting phosphors in the LED field.

  5. On-road assessment of light duty vehicles in Delhi city: Emission factors of CO, CO2 and NOX

    NASA Astrophysics Data System (ADS)

    Jaiprakash; Habib, Gazala

    2018-02-01

    This study presents the technology based emission factors of gaseous pollutants (CO, CO2, and NOX) measured during on-road operation of nine passenger cars of diesel, gasoline, and compressed natural gas (CNG). The emissions from two 3-wheelers, and three 2-wheelers were measured by putting the vehicles on jacks and operating them according to Modified Indian Driving Cycle (MIDC) at no load condition. The emission factors observed in the present work were significantly higher than values reported from dynamometer study by Automotive Research Association of India (ARAI). Low CO (0.34 ± 0.08 g km-1) and high NOX (1.0 ± 0.4 g km-1) emission factors were observed for diesel passenger cars, oppositely high CO (2.2 ± 2.6 g km-1) and low NOX (1.0 ± 1.6 g km-1) emission factors were seen for gasoline powered cars. The after-treatment technology in diesel vehicles was effective in CO reduction. While the use of turbocharger in diesel vehicles to generate high combustion temperature and pressure produces more NOx, probably which may not be effectively controlled by after-treatment device. The after-treatment devices in gasoline powered Post-2010, Post-2005 vehicles can be acclaimed for reduced CO emissions compared to Post-2000 vehicles. This work presents a limited data set of emission factors from on-road operations of light duty vehicles, this limitation can be improved by further measurements of emissions from similar vehicles.

  6. White light emission from an exciplex interface with a single emitting layer (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Bernal, Wilson; Perez-Gutierrez, Enrique; Agular, Andres; Barbosa G, J. Oracio C.; Maldonado, Jose L.; Meneses-Nava, Marco Antonio; Rodriguez Rivera, Mario A.; Rodriguez, Braulio

    2017-02-01

    Efficient solid state lighting devices based in inorganic emissive materials are now available in the market meanwhile for organic emissive materials still a lot of research work is in its way. [1,2] In this work a new organic emissive material based on carbazole, N-(4-Ethynylphenyl) carba-zole-d4 (6-d4), is used as electron-acceptor and commercial PEDOT:PSS as the electron-donor to obtain white emission. Besides the HOMO-LUMO levels of materials the white emission showed dependence on the films thicknesses and applied voltages. In here it is reported that by diminishing the thickness of the PEDOT:PSS layer, from 60 to 35 nm, and by keeping the derivative carbazole layer constant at 100 nm the electro-luminescence (EL) changed from emissive exciton states to the mixture of emissive exciton and exciplex states. [3] For the former thicknesses no white light was obtained meanwhile for the later the EL spectra broadened due to the emission of exciplex states. Under this condition, the best-achieved CIE coordinate was (0.31,0.33) with a driving voltage of 8 V. To lower the driving voltage of the devices a thin film of LiF was added between the derivative of carbazol and cathode but the CIE coordinates changed. The best CIE coordinates for this case were (0.29, 0.34) and (0.32, 0.37) with driving voltage of about 6.5 V. Acknowledgments: CeMie-Sol/27 (Mexico) 207450 References [1] Timothy L Dawson, Society of Dyers and Colourists, Color. Technol., 126, 1-10 (2010), doi: 10.1111/j.1478-4408.2010.00220.x [2] G. M. Farinola, R. Ragni, Journal of Solid State Lighting, 2:9 (2015), doi: 10.1186/s40539-015-0028-7. [3] E. Angioni, et al, J. Mater. Chem. C, 2016, 4, 3851, doi: 10.1039/c6tc00750c.

  7. Self-Assembly Driven Aggregation-Induced Emission of Copper Nanoclusters: A Novel Technology for Lighting.

    PubMed

    Liu, Yi; Yao, Dong; Zhang, Hao

    2018-04-18

    Because of the specific properties including HOMO-LUMO electronic transition, size-dependent fluorescent emission, and intense light absorption, metal nanoclusters (NCs) have been considered to be one of the most competitive color conversion materials in light-emitting diodes (LEDs). However, the monotonous emission color and the low emission stability and intensity of individual metal NCs strongly limit their universal application. Inspired by the concept of "aggregation-induced emission" (AIE), the utilization of highly ordered metal NC assemblies opens a door to resolve these problems. After self-assembly, the emission stability and intensity of metal NC assemblies are enhanced. At the same time, the emission color of metal NC assemblies become tunable. We termed this process as self-assembly driven AIE of metal NCs. In this review, we use Cu NCs as the example to convey the concept that the compact and ordered arrangement can efficiently improve the metal NCs' emission stability, tunability, and intensity. We first introduce the synthesis of 2D Cu NC self-assemblies and their emissions. We further summarize some of the factors that can affect the emissions of 2D Cu NC self-assemblies. We then discuss the utilization of 2D Cu NC self-assemblies as color conversion materials for LEDs. At last, we outline current challenges and our perspectives on the development of this area.

  8. Chandra ACIS Observations of Jovian X-Ray Emission

    NASA Technical Reports Server (NTRS)

    Garmire, Gordon; Elsner, Ronald; Feigelson, Eric; Ford, Peter; Gladstone, G. Randall; Hurley, Kevin; Metzger, Albert; Waite, J. Hunter, Jr.; Whitaker, Ann F. (Technical Monitor)

    2001-01-01

    On November 25 and 26, 1999, the Chandra X-ray spacecraft conducted a set of four 19,000 sec observations of Jupiter. The ACIS-S instrument configuration was used for its good low energy efficiency and spatial resolution. An anomalous response was obtained which was subsequently attributed to strong jovian infrared radiation penetrating the detector and piling up spurious events across the entire X-ray range. However, the pre-observation establishment of an offsetting bias field has allowed the recovery of data from that portion of Jupiter's disc which remained within the elevated portion of the bias field during the observation. This ranges from fewer than 3000 sec to the entire observing time for about 10% of the planet. Auroral emission is seen near both poles in each observation. The northern aurora ia overall more intense than the southern, consistent with prior Einstein and ROSAT Observatory results. The southern aurora shows more modulation with Jupiter's rotation than the northern. Spatial resolution has been improved by at least a factor of two over prior measurements but convincing evidence of structure has not been seen. Lower latitude emission, first observed by ROSAT, is confirmed with flux levels averaging more than a factor of five below peak auroral values. Pronounced variation in the observed emission has occurred over the observing period. The spectral response extends from 0.24 keV, below which noise dominates, to about 1.2 keV. For all four observations the spectrum is clearly enhanced between 0.45 and 0.85 keV. This is apparently unequivocal evidence that Jupiter's X-ray emission is the result of oxygen and perhaps sulfur ions precipitating into the planet's atmosphere, where they undergo charge exchange interactions. The identification of specific transitions lines in the spectrum is among the ongoing efforts. A bremsstrahlung component has not yet been identified.

  9. Canopy light cues affect emission of constitutive and methyl jasmonate-induced volatile organic compounds in Arabidopsis thaliana.

    PubMed

    Kegge, Wouter; Weldegergis, Berhane T; Soler, Roxina; Vergeer-Van Eijk, Marleen; Dicke, Marcel; Voesenek, Laurentius A C J; Pierik, Ronald

    2013-11-01

    The effects of plant competition for light on the emission of plant volatile organic compounds (VOCs) were studied by investigating how different light qualities that occur in dense vegetation affect the emission of constitutive and methyl-jasmonate-induced VOCs. Arabidopsis thaliana Columbia (Col-0) plants and Pieris brassicae caterpillars were used as a biological system to study the effects of light quality manipulations on VOC emissions and attraction of herbivores. VOCs were analysed using gas chromatography-mass spectrometry and the effects of light quality, notably the red : far red light ratio (R : FR), on expression of genes associated with VOC production were studied using reverse transcriptase-quantitative PCR. The emissions of both constitutive and methyl-jasmonate-induced green leaf volatiles and terpenoids were partially suppressed under low R : FR and severe shading conditions. Accordingly, the VOC-based preference of neonates of the specialist lepidopteran herbivore P. brassicae was significantly affected by the R : FR ratio. We conclude that VOC-mediated interactions among plants and between plants and organisms at higher trophic levels probably depend on light alterations caused by nearby vegetation. Studies on plant-plant and plant-insect interactions through VOCs should take into account the light quality within dense stands when extrapolating to natural and agricultural field conditions. © 2013 The Authors. New Phytologist © 2013 New Phytologist Trust.

  10. Light-Duty Automotive Technology, Carbon Dioxide Emissions, and Fuel Economy Trends Data

    EPA Pesticide Factsheets

    The Light-Duty Automotive Technology, Carbon Dioxide Emissions, and Fuel Economy Trends report is the authoritative reference for carbon dioxide (CO2) emissions, fuel economy, and powertrain technology trends for new personal vehicles in the United States. The ??Trends?? report has been published annually since 1975 and covers all passenger cars, sport utility vehicles, minivans, and all but the largest pickup trucks and vans. This report does not provide formal compliance values for EPA CO2 emissions standards and NHTSA CAFE standards. The downloadable data are available in PDF or spreadsheet (XLS) formats.

  11. Tuning Light Emission of a Pressure-Sensitive Silicon/ZnO Nanowires Heterostructure Matrix through Piezo-phototronic Effects.

    PubMed

    Chen, Mengxiao; Pan, Caofeng; Zhang, Taiping; Li, Xiaoyi; Liang, Renrong; Wang, Zhong Lin

    2016-06-28

    Based on white light emission at silicon (Si)/ZnO hetrerojunction, a pressure-sensitive Si/ZnO nanowires heterostructure matrix light emitting diode (LED) array is developed. The light emission intensity of a single heterostructure LED is tuned by external strain: when the applied stress keeps increasing, the emission intensity first increases and then decreases with a maximum value at a compressive strain of 0.15-0.2%. This result is attributed to the piezo-phototronic effect, which can efficiently modulate the LED emission intensity by utilizing the strain-induced piezo-polarization charges. It could tune the energy band diagrams at the junction area and regulate the optoelectronic processes such as charge carriers generation, separation, recombination, and transport. This study achieves tuning silicon based devices through piezo-phototronic effect.

  12. Evaluation of emission factors for light-duty gasoline vehicles based on chassis dynamometer and tunnel studies in Shanghai, China

    NASA Astrophysics Data System (ADS)

    Huang, Cheng; Tao, Shikang; Lou, Shengrong; Hu, Qingyao; Wang, Hongli; Wang, Qian; Li, Li; Wang, Hongyu; Liu, Jian'gang; Quan, Yifeng; Zhou, Lanlan

    2017-11-01

    CO, THC, NOx, and PM emission factors of 51 light-duty gasoline vehicles (LDGVs) spanning the emission standards from Euro 2 to Euro 5 were measured by a chassis dynamometer. High frequencies of high-emitting vehicles were observed in Euro 2 and Euro 3 LDGV fleet. 56% and 33% of high-emitting vehicles contributed 81%-92% and 82%-85% of the emissions in Euro 2 and Euro 3 test fleet, respectively. Malfunctions of catalytic convertors after high strength use are the main cause of the high emissions. Continuous monitoring of a gasoline vehicle dominated tunnel in Shanghai, China was conducted to evaluate the average emission factors of vehicles in real-world. The results indicated that the emission factors of LDGVs were considerably underestimated in EI guidebook in China. The overlook of high-emitting vehicles in older vehicle fleet is the main reason for this underestimation. Enhancing the supervision of high emission vehicles and strengthening the compliance tests of in-use vehicles are essential measures to control the emissions of in-use gasoline vehicles at the present stage in China.

  13. A stable Alq3@MOF composite for white-light emission.

    PubMed

    Xie, Wei; He, Wen-Wen; Du, Dong-Ying; Li, Shun-Li; Qin, Jun-Sheng; Su, Zhong-Min; Sun, Chun-Yi; Lan, Ya-Qian

    2016-02-25

    A stable mesoporous blue-emitting MOF NENU-521 was successfully constructed. NENU-521 can serve as a host for encapsulating Alq3 to obtain tunable and efficient white-light emission. The Alq3@NENU-521 composite possesses excellent stability and can be used as a promising white phosphor in WLEDs.

  14. Emission Characteristics of Organic Light-Emitting Diodes and Organic Thin-Films with Planar and Corrugated Structures

    PubMed Central

    Wei, Mao-Kuo; Lin, Chii-Wann; Yang, Chih-Chung; Kiang, Yean-Woei; Lee, Jiun-Haw; Lin, Hoang-Yan

    2010-01-01

    In this paper, we review the emission characteristics from organic light-emitting diodes (OLEDs) and organic molecular thin films with planar and corrugated structures. In a planar thin film structure, light emission from OLEDs was strongly influenced by the interference effect. With suitable design of microcavity structure and layer thicknesses adjustment, optical characteristics can be engineered to achieve high optical intensity, suitable emission wavelength, and broad viewing angles. To increase the extraction efficiency from OLEDs and organic thin-films, corrugated structure with micro- and nano-scale were applied. Microstructures can effectively redirects the waveguiding light in the substrate outside the device. For nanostructures, it is also possible to couple out the organic and plasmonic modes, not only the substrate mode. PMID:20480033

  15. White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites.

    PubMed

    Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C; Wasielewski, Michael R; Kanatzidis, Mercouri G

    2017-03-29

    Hybrid inorganic-organic perovskites are developing rapidly as high performance semiconductors. Recently, two-dimensional (2D) perovskites were found to have white-light, broadband emission in the visible range that was attributed mainly to the role of self-trapped excitons (STEs). Here, we describe three new 2D lead bromide perovskites incorporating a series of bifunctional ammonium dications as templates which also emit white light: (1) α-(DMEN)PbBr 4 (DMEN = 2-(dimethylamino)ethylamine), which adopts a unique corrugated layered structure in space group Pbca with unit cell a = 18.901(4) Å, b = 11.782(2) Å, and c = 23.680(5) Å; (2) (DMAPA)PbBr 4 (DMAPA = 3-(dimethylamino)-1-propylamine), which crystallizes in P2 1 /c with a = 10.717(2) Å, b = 11.735(2) Å, c = 12.127(2) Å, and β = 111.53(3)°; and (3) (DMABA)PbBr 4 (DMABA = 4-dimethylaminobutylamine), which adopts Aba2 with a = 41.685(8) Å, b = 23.962(5) Å, and c = 12.000(2) Å. Photoluminescence (PL) studies show a correlation between the distortion of the "PbBr 6 " octahedron in the 2D layer and the broadening of PL emission, with the most distorted structure having the broadest emission (183 nm full width at half-maximum) and longest lifetime (τ avg = 1.39 ns). The most distorted member α-(DMEN)PbBr 4 exhibits white-light emission with a color rendering index (CRI) of 73 which is similar to a fluorescent light source and correlated color temperature (CCT) of 7863 K, producing "cold" white light.

  16. Designing optically pumped InGaN quantum wells with long wavelength emission for a phosphor-free device with polarized white-light emission

    NASA Astrophysics Data System (ADS)

    Kowsz, Stacy J.; Pynn, Christopher D.; Wu, Feng; Farrell, Robert M.; Speck, James S.; DenBaars, Steven P.; Nakamura, Shuji

    2016-02-01

    We report a semipolar III-nitride device in which an electrically injected blue light emitting diode optically pumps monolithic long wavelength emitting quantum wells (QWs) to create polarized white light. We have demonstrated an initial device with emission peaks at 440 nm and 560 nm from the electrically injected and optically pumped QWs, respectively. By tuning the ratio of blue to yellow, white light was measured with a polarization ratio of 0.40. High indium content InGaN is required for long wavelength emission but is difficult to achieve because it requires low growth temperatures and has a large lattice mismatch with GaN. This device design incorporates optically pumped QWs for long wavelength emission because they offer advantages over using electrically injected QWs. Optically pumped QWs do not have to be confined within a p-n junction, and carrier transport is not a concern. Thus, thick GaN barriers can be incorporated between multiple InGaN QWs to manage stress. Optically pumping long wavelength emitting QWs also eliminates high temperature steps that degrade high indium content InGaN but are required when growing p-GaN for an LED structure. Additionally, by eliminating electrical injection, the doping profile can instead be engineered to affect the emission wavelength. We discuss ongoing work focused on improving polarized white light emission by optimizing the optically pumped QWs. We consider the effects of growth conditions, including: trimethylindium (TMI) flow rate, InGaN growth rate, and growth temperature. We also examine the effects of epitaxial design, including: QW width, number of QWs, and doping.

  17. GOSAT observations of anthropogenic emission of carbon dioxide and methane

    NASA Astrophysics Data System (ADS)

    Janardanan, Rajesh; Maksyutov, Shamil; Oda, Tomohiro; Saito, Makoto; Ito, Akihiko; Kaiser, Johannes W.; Ganshin, Alexander; Yoshida, Yukio; Yokota, Tatsuya; Matsunaga, Tsuneo

    2017-04-01

    Carbon dioxide (CO2) and methane (CH4) are the most important greenhouse gases in terms of radiative forcing. Human activities such as combustion of fossil fuel (for CO2), and gas leakage, animal agriculture, rice cultivation and landfill emissions (for CH4), are considered to be major sources of their emissions. Global emissions datasets usually depend on emission estimates reported by countries, which are seldom evaluated in an objective way. Here we present a method for delineating anthropogenic contributions to global atmospheric CO2 and CH4 (2009-2014) concentration fields using GOSAT observations of column-average dry air mole fractions (XCO2 and XCH4) and atmospheric transport model simulations using high-resolution emissions datasets (ODIAC for CO2 and EDGAR for CH4). The XCO2 and XCH4 concentration enhancements due to anthropogenic emissions are estimated at all GOSAT observation locations using the transport model simulation. We calculated threshold values to classify GOSAT observations into two categories: (1) data influenced by the anthropogenic sources and (2) those not influenced. We defined a clean background (averaged concentrations of GOSAT data that are free from contamination) in 10˚ ×10˚ regions over the globe and subtracted the background values from individual GOSAT observations. The anomalies (GOSAT observed values minus background values) were binned and compared to model-based anomalies over continental regions and selected countries. For CO2, we have found global and regional linear relationships between model and observed anomalies especially for Eurasia and North America. The analysis for East Asian region showed a systematic bias that is somewhat comparable in magnitude to the uncertainties in emission inventories in that region, which were reported by recent studies. In the case of CH4, we found a good match between inventory-based estimates and GOSAT observations for continental regions and large countries. The inventory

  18. The effects of emission control strategies on light-absorbing carbon emissions from a modern heavy-duty diesel engine.

    PubMed

    Robinson, Michael A; Olson, Michael R; Liu, Z Gerald; Schauer, James J

    2015-06-01

    Control of atmospheric black carbon (BC) and brown carbon (BrC) has been proposed as an important pathway to climate change mitigation, but sources of BC and BrC are still not well understood. In order to better identify the role of modern heavy-duty diesel engines on the production of BC and BrC, emissions from a heavy-duty diesel engine operating with different emission control strategies were examined using a source dilution sampling system. The effect of a diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) on light-absorbing carbon (LAC) was evaluated at three steady-state engine operation modes: idle, 50% speed and load, and 100% speed and load. LAC was measured with four different engine configurations: engine out, DOC out, DPF out, and engine out with an altered combustion calibration. BC and BrC emission rates were measured with the Aethalometer (AE-31). EC and BC emission rates normalized to the mass of CO₂emitted increased with increasing engine speed and load. Emission rates normalized to brake-specific work did not exhibit similar trends with speed and load, but rather the highest emission rate was measured at idle. EC and OC emissions were reduced by 99% when the DOC and DPF architecture was applied. The application of a DPF was equally effective at removing 99% of the BC fraction of PM, proving to be an important control strategy for both LAC and PM. BC emissions were unexpectedly increased across the DOC, seemingly due to a change aerosol optical properties. Removal of exhaust gas recirculation (EGR) flow due to simulated EGR cooler failure caused a large increase in OC and BrC emission rates at idle, but had limited influence during high load operation. LAC emissions proved to be sensitive to the same control strategies effective at controlling the total mass of diesel PM. In the context of black carbon emissions, very small emission rates of brown carbon were measured over a range of control technologies and engine operating

  19. Biogenic Volatile Organic Compound (BVOC) emissions from agricultural crop species: is guttation a possible source for methanol emissions following light/dark transition ?

    NASA Astrophysics Data System (ADS)

    Mozaffar, Ahsan; Amelynck, Crist; Bachy, Aurélie; Digrado, Anthony; Delaplace, Pierre; du Jardin, Patrick; Fauconnier, Marie-Laure; Schoon, Niels; Aubinet, Marc; Heinesch, Bernard

    2015-04-01

    In the framework of the CROSTVOC (CROp STress VOC) project, the exchange of biogenic volatile organic compounds (BVOCs) between two important agricultural crop species, maize and winter wheat, and the atmosphere has recently been measured during an entire growing season by using the eddy covariance technique. Because of the co-variation of BVOC emission drivers in field conditions, laboratory studies were initiated in an environmental chamber in order to disentangle the responses of the emissions to variations of the individual environmental parameters (such as PPFD and temperature) and to diverse abiotic stress factors. Young plants were enclosed in transparent all-Teflon dynamic enclosures (cuvettes) through which BVOC-free and RH-controlled air was sent. BVOC enriched air was subsequently sampled from the plant cuvettes and an empty cuvette (background) and analyzed for BVOCs in a high sensitivity Proton Transfer Reaction Mass Spectrometer (hs-PTR-MS) and for CO2 in a LI-7000 non-dispersive IR gas analyzer. Emissions were monitored at constant temperature (25 °C) and at a stepwise varying PPFD pattern (0-650 µmol m-2 s-1). For maize plants, sudden light/dark transitions at the end of the photoperiod were accompanied by prompt and considerable increases in methanol (m/z 33) and water vapor (m/z 39) emissions. Moreover, guttation droplets appeared on the sides and the tips of the leaves within a few minutes after light/dark transition. Therefore the assumption has been raised that methanol is also coming out with guttation fluid from the leaves. Consequently, guttation fluid was collected from young maize and wheat plants, injected in an empty enclosure and sampled by PTR-MS. Methanol and a large number of other compounds were observed from guttation fluid. Recent studies have shown that guttation from agricultural crops frequently occurs in field conditions. Further research is required to find out the source strength of methanol emissions by this guttation

  20. Light absorption properties and radiative effects of primary organic aerosol emissions

    DOE PAGES

    Lu, Zifeng; Streets, David G.; Winijkul, Ekbordin; ...

    2015-03-26

    Organic aerosols (OAs) in the atmosphere affect Earth’s energy budget by not only scattering but also absorbing solar radiation due to the presence of the so-called “brown carbon” (BrC) component. However, the absorptivities of OAs are not represented or are poorly represented in current climate and chemical transport models. In this study, we provide a method to constrain the BrC absorptivity at the emission inventory level using recent laboratory and field observations. We review available measurements of the light-absorbing primary OA (POA), and quantify the wavelength-dependent imaginary refractive indices (k OA, the fundamental optical parameter determining the particle’s absorptivity) andmore » their uncertainties for the bulk POA emitted from biomass/biofuel, lignite, propane, and oil combustion sources. In particular, we parametrize the k OA of biomass/biofuel combustion sources as a function of the black carbon (BC)-to-OA ratio, indicating that the absorptive properties of POA depend strongly on burning conditions. The derived fuel-type-based k OA profiles are incorporated into a global carbonaceous aerosol emission inventory, and the integrated k OA values of sectoral and total POA emissions are presented. The results of a simple radiative transfer model show that the POA absorptivity warms the atmosphere significantly and leads to ~27% reduction in the amount of the net global average POA cooling compared to results from the nonabsorbing assumption.« less

  1. Dual-Color Emission in Hybrid III-Nitride/ZnO Light Emitting Diodes

    NASA Astrophysics Data System (ADS)

    Namkoong, Gon; Trybus, Elaissa; Cheung, Maurice C.; Doolittle, W. Alan; Cartwright, Alexander N.; Ferguson, Ian; Seong, Tae-Yeon; Nause, Jeff

    2010-02-01

    We report dual-color production of the blue and green regions using hybrid nitride/ZnO light emitting diode (LED) structures grown on ZnO substrates. The blue emission is ascribed to the near-band edge transition in InGaN while green emission is related to Zn-related defect levels formed by the unintentional interdiffusion of Zn into the InGaN active layer from the ZnO substrates.

  2. Scientists Observe Light Fighting To Escape Black Hole's Pull

    NASA Astrophysics Data System (ADS)

    2002-06-01

    black hole in its core. (Black holes come in a variety of sizes; supermassive black holes are the heavyweights, weighing in at millions to billions of times the mass of the Sun.) Gas in this central region glows in X-ray radiation as it is heated to temperatures in the millions of degrees under the force of the black hole's extreme gravity. Spectral characteristics are features in a graph of light energy, called a spectrograph, which resembles a jagged line with peaks (emission lines) where light shines brightly at a specific energy. In a laboratory, iron gas bombarded with X rays emits them as a result, producing a spike at a specific energy in a spectrograph. In space, this spike is distorted, depending on the physical conditions in the emitting gas. Hot gas orbiting an object, for example, has a double-horned profile due to the Doppler effect. That is, some gas is moving towards us, slightly boosting the energy of its X-ray emission, and other gas is moving away, slightly reducing the energy of its X-rays. This results in a spectral line with two peaks, one for the boosted X-rays and one for the weakened ones. Seyfert Galaxy NGC 3516 Seyfert Galaxy NGC 3516 Credit: HST/UCLA/M.Malkan Turner and her colleagues observed a very complex profile for the iron K line in NGC 3516. This line showed narrow spikes, likely the Doppler peaks from hotspots in the accretion disk lit up by flaring at 35- and 175-times the black hole radius. These narrow features sit atop a broad line component from light across the entire accretion disk, a spectral feature broadened by gravity's pull. The combination of narrow and broad features supports Einstein's math, Turner said. Some scientists have suggested that the broad iron K line is due to Comptonization, a process in which light particles collide with electrons and lose energy. If Comptonization were afoot, even light emitted farther away from the black hole (at 35 and 175 radii away) would be broadened as this light interacts with

  3. Fuel savings and emissions reductions from light duty fuel cell vehicles

    NASA Astrophysics Data System (ADS)

    Mark, J.; Ohi, J. M.; Hudson, D. V., Jr.

    1994-04-01

    Fuel cell vehicles (FCV's) operate efficiently, emit few pollutants, and run on nonpetroleum fuels. Because of these characteristics, the large-scale deployment of FCV's has the potential to lessen U.S. dependence on foreign oil and improve air quality. This study characterizes the benefits of large-scale FCV deployment in the light duty vehicle market. Specifically, the study assesses the potential fuel savings and emissions reductions resulting from large-scale use of these FCV's and identifies the key parameters that affect the scope of the benefits from FCV use. The analysis scenario assumes that FCV's will compete with gasoline-powered light trucks and cars in the new vehicle market for replacement of retired vehicles and will compete for growth in the total market. Analysts concluded that the potential benefits from FCV's, measured in terms of consumer outlays for motor fuel and the value of reduced air emissions, are substantial.

  4. Green leaf volatiles and oxygenated metabolite emission bursts from mesquite branches following light-dark transitions.

    PubMed

    Jardine, K; Barron-Gafford, G A; Norman, J P; Abrell, L; Monson, R K; Meyers, K T; Pavao-Zuckerman, M; Dontsova, K; Kleist, E; Werner, C; Huxman, T E

    2012-09-01

    Green leaf volatiles (GLVs) are a diverse group of fatty acid-derived compounds emitted by all plants and are involved in a wide variety of developmental and stress-related biological functions. Recently, GLV emission bursts from leaves were reported following light-dark transitions and hypothesized to be related to the stress response while acetaldehyde bursts were hypothesized to be due to the 'pyruvate overflow' mechanism. In this study, branch emissions of GLVs and a group of oxygenated metabolites (acetaldehyde, ethanol, acetic acid, and acetone) derived from the pyruvate dehydrogenase (PDH) bypass pathway were quantified from mesquite plants following light-dark transitions using a coupled GC-MS, PTR-MS, and photosynthesis system. Within the first minute after darkening following a light period, large emission bursts of both C(5) and C(6) GLVs dominated by (Z)-3-hexen-1-yl acetate together with the PDH bypass metabolites are reported for the first time. We found that branches exposed to CO(2)-free air lacked significant GLV and PDH bypass bursts while O(2)-free atmospheres eliminated the GLV burst but stimulated the PDH bypass burst. A positive relationship was observed between photosynthetic activity prior to darkening and the magnitude of the GLV and PDH bursts. Photosynthesis under (13)CO(2) resulted in bursts with extensive labeling of acetaldehyde, ethanol, and the acetate but not the C(6)-alcohol moiety of (Z)-3-hexen-1-yl acetate. Our observations are consistent with (1) the "pyruvate overflow" mechanism with a fast turnover time (<1 h) as part of the PDH bypass pathway, which may contribute to the acetyl-CoA used for the acetate moiety of (Z)-3-hexen-1-yl acetate, and (2) a pool of fatty acids with a slow turnover time (>3 h) responsible for the C(6) alcohol moiety of (Z)-3-hexen-1-yl acetate via the 13-lipoxygenase pathway. We conclude that our non-invasive method may provide a new valuable in vivo tool for studies of acetyl-CoA and fatty acid

  5. Methanol emissions from maize: Ontogenetic dependence to varying light conditions and guttation as an additional factor constraining the flux

    NASA Astrophysics Data System (ADS)

    Mozaffar, A.; Schoon, N.; Digrado, A.; Bachy, A.; Delaplace, P.; du Jardin, P.; Fauconnier, M.-L.; Aubinet, M.; Heinesch, B.; Amelynck, C.

    2017-03-01

    Because of its high abundance and long lifetime compared to other volatile organic compounds in the atmosphere, methanol (CH3OH) plays an important role in atmospheric chemistry. Even though agricultural crops are believed to be a large source of methanol, emission inventories from those crop ecosystems are still scarce and little information is available concerning the driving mechanisms for methanol production and emission at different developmental stages of the plants/leaves. This study focuses on methanol emissions from Zea mays L. (maize), which is vastly cultivated throughout the world. Flux measurements have been performed on young plants, almost fully grown leaves and fully grown leaves, enclosed in dynamic flow-through enclosures in a temperature and light-controlled environmental chamber. Strong differences in the response of methanol emissions to variations in PPFD (Photosynthetic Photon Flux Density) were noticed between the young plants, almost fully grown and fully grown leaves. Moreover, young maize plants showed strong emission peaks following light/dark transitions, for which guttation can be put forward as a hypothetical pathway. Young plants' average daily methanol fluxes exceeded by a factor of 17 those of almost fully grown and fully grown leaves when expressed per leaf area. Absolute flux values were found to be smaller than those reported in the literature, but in fair agreement with recent ecosystem scale flux measurements above a maize field of the same variety as used in this study. The flux measurements in the current study were used to evaluate the dynamic biogenic volatile organic compound (BVOC) emission model of Niinemets and Reichstein. The modelled and measured fluxes from almost fully grown leaves were found to agree best when a temperature and light dependent methanol production function was applied. However, this production function turned out not to be suitable for modelling the observed emissions from the young plants

  6. Unique concurrent observations of whistler mode hiss, chorus, and triggered emissions

    NASA Astrophysics Data System (ADS)

    Hosseini, Poorya; Gołkowski, Mark; Turner, Drew L.

    2017-06-01

    We present a unique 2 h ground-based observation of concurrent magnetospheric hiss, chorus, VLF triggered emissions as well as ELF/VLF signals generated locally by the High Frequency Active Auroral Research Program (HAARP) facility. Eccentricity of observed wave polarization is used as a criteria to identify magnetospheric emissions and estimate their ionospheric exit points. The observations of hiss and chorus in the unique background of coherent HAARP ELF/VLF waves and triggered emissions allow for more accurate characterization of hiss and chorus properties than in typical ground-based observations. Eccentricity and azimuth results suggest a moving ionospheric exit point associated with a single ducted path at L 5. The emissions exhibit dynamics in time suggesting an evolution of a magnetospheric source from hiss generation to chorus generation or a moving plasmapause location. We introduce a frequency band-limited autocorrelation method to quantify the relative coherency of the emissions. A range of coherency was observed from high order of coherency in local HAARP transmissions and their echoes to lower coherency in natural chorus and hiss emissions.

  7. An assessment of the real-world driving gaseous emissions from a Euro 6 light-duty diesel vehicle using a portable emissions measurement system (PEMS)

    NASA Astrophysics Data System (ADS)

    Luján, José M.; Bermúdez, Vicente; Dolz, Vicente; Monsalve-Serrano, Javier

    2018-02-01

    Recent investigations demonstrated that real-world emissions usually exceed the levels achieved in the laboratory based type approval processes. By means of on-board emissions measurements, it has been shown that nitrogen oxides emitted by diesel engines substantially exceed the limit imposed by the Euro 6 regulation. Thus, with the aim of complementing the worldwide harmonized light vehicles test cycle, the real driving emissions cycle will be introduced after 1 September 2017 to regulate the vehicle emissions in real-world driving situations. This paper presents on-board gaseous emissions measurements from a Euro 6 light-duty diesel vehicle in a real-world driving route using a portable emissions measurement system. The test route characteristics follow the requirements imposed by the RDE regulation. The analysis of the raw emissions results suggests that the greatest amount of nitrogen oxides and nitrogen dioxide are emitted during the urban section of the test route, confirming that lower speeds with more accelerations and decelerations lead to higher nitrogen oxides emissions levels than constant high speeds. Moreover, the comparison of the two calculation methods proposed by the real driving emissions regulation has revealed emissions rates differences ranging from 10% to 45% depending on the pollutant emission and the trip section considered (urban or total). Thus, the nitrogen oxides emissions conformity factor slightly varies from one method to the other.

  8. Can Flare Loops Contribute to the White-light Emission of Stellar Superflares?

    NASA Astrophysics Data System (ADS)

    Heinzel, P.; Shibata, K.

    2018-06-01

    Since the discovery of stellar superflares by the Kepler satellite, these extremely energetic events have been studied in analogy to solar flares. Their white-light (WL) continuum emission has been interpreted as being produced by heated ribbons. In this paper, we compute the WL emission from overlying flare loops depending on their density and temperature and show that, under conditions expected during superflares, the continuum brightening due to extended loop arcades can significantly contribute to stellar flux detected by Kepler. This requires electron densities in the loops of 1012‑1013 cm‑3 or higher. We show that such densities, exceeding those typically present in solar-flare loops, can be reached on M-dwarf and solar-type superflare stars with large starspots and much stronger magnetic fields. Quite importantly, the WL radiation of loops is not very sensitive to their temperature and thus both cool as well as hot loops may contribute. We show that the WL intensity emergent from optically thin loops is lower than the blackbody radiation from flare ribbons, but the contribution of loops to total stellar flux can be quite important due to their significant emitting areas. This new scenario for interpreting superflare emission suggests that the observed WL flux is due to a mixture of the ribbon and loop radiation and can be even loop-dominated during the gradual phase of superflares.

  9. Tuning the emission of aqueous Cu:ZnSe quantum dots to yellow light window

    NASA Astrophysics Data System (ADS)

    Wang, Chunlei; Hu, Zhiyang; Xu, Shuhong; Wang, Yanbin; Zhao, Zengxia; Wang, Zhuyuan; Cui, Yiping

    2015-07-01

    Synthesis of internally doped Cu:ZnSe QDs in an aqueous solution still suffers from narrow tunable emissions from the blue to green light window. In this work, we extended the emission window of aqueous Cu:ZnSe QDs to the yellow light window. Our results show that high solution pH, multiple injections of Zn precursors, and nucleation doping strategy are three key factors for preparing yellow emitted Cu:ZnSe QDs. All these factors can depress the reactivity of CuSe nuclei and Zn monomers, promoting ZnSe growth outside CuSe nuclei rather than form ZnSe nuclei separately. With increased ZnSe QD size, the conduction band and nearby trap state energy levels shift to higher energy sites, causing Cu:ZnSe QDs to have a much longer emission.

  10. Selective area growth and characterization of InGaN nanocolumns for phosphor-free white light emission

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Albert, S.; Bengoechea-Encabo, A.; Sanchez-Garcia, M. A.

    This work reports on the morphology and light emission characteristics of ordered InGaN nanocolumns grown by plasma-assisted molecular beam epitaxy. Within the growth temperature range of 750 to 650 Degree-Sign C, the In incorporation can be modified either by the growth temperature, the In/Ga ratio, or the III/V ratio, following different mechanisms. Control of these factors allows the optimization of the InGaN nanocolumns light emission wavelength and line-shape. Furthermore, yellow-white emission is obtained at room temperature from nanostructures with a composition-graded active InGaN region obtained by temperature gradients during growth.

  11. Replacement policy of residential lighting optimized for cost, energy, and greenhouse gas emissions

    NASA Astrophysics Data System (ADS)

    Liu, Lixi; Keoleian, Gregory A.; Saitou, Kazuhiro

    2017-11-01

    Accounting for 10% of the electricity consumption in the US, artificial lighting represents one of the easiest ways to cut household energy bills and greenhouse gas (GHG) emissions by upgrading to energy-efficient technologies such as compact fluorescent lamps (CFL) and light emitting diodes (LED). However, given the high initial cost and rapidly improving trajectory of solid-state lighting today, estimating the right time to switch over to LEDs from a cost, primary energy, and GHG emissions perspective is not a straightforward problem. This is an optimal replacement problem that depends on many determinants, including how often the lamp is used, the state of the initial lamp, and the trajectories of lighting technology and of electricity generation. In this paper, multiple replacement scenarios of a 60 watt-equivalent A19 lamp are analyzed and for each scenario, a few replacement policies are recommended. For example, at an average use of 3 hr day-1 (US average), it may be optimal both economically and energetically to delay the adoption of LEDs until 2020 with the use of CFLs, whereas purchasing LEDs today may be optimal in terms of GHG emissions. In contrast, incandescent and halogen lamps should be replaced immediately. Based on expected LED improvement, upgrading LED lamps before the end of their rated lifetime may provide cost and environmental savings over time by taking advantage of the higher energy efficiency of newer models.

  12. Light beam shaping for collimated emission from white organic light-emitting diodes using customized lenticular microlens arrays structure

    NASA Astrophysics Data System (ADS)

    Zhou, Lei; Bai, Gui-Lin; Guo, Xin; Shen, Su; Ou, Qing-Dong; Fan, Yuan-Yuan

    2018-05-01

    We present a design approach to realizing a desired collimated planar incoherent light source (CPILS) by incorporating lenticular microlens arrays (LMLAs) onto the substrates of discrete white organic light-emitting diode (WOLED) light sources and demonstrate the effectiveness of this method in collimated light beam shaping and luminance enhancement simultaneously. The obtained collimated WOLED light source shows enhanced luminance by a factor of 2.7 compared with that of the flat conventional device at the normal polar angle and, more importantly, exhibits a narrowed angular emission with a full-width at half-maximum (FWHM) of ˜33.6°. We anticipate that the presented strategy could provide an alternative way for achieving the desired large scale CPILS, thereby opening the door to many potential applications, including LCD backlights, three-dimensional displays, car headlights, and so forth.

  13. Solar flare impulsive phase emission observed with SDO/EVE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kennedy, Michael B.; Milligan, Ryan O.; Mathioudakis, Mihalis

    2013-12-10

    Differential emission measures (DEMs) during the impulsive phase of solar flares were constructed using observations from the EUV Variability Experiment (EVE) and the Markov-Chain Monte Carlo method. Emission lines from ions formed over the temperature range log T{sub e} = 5.8-7.2 allow the evolution of the DEM to be studied over a wide temperature range at 10 s cadence. The technique was applied to several M- and X-class flares, where impulsive phase EUV emission is observable in the disk-integrated EVE spectra from emission lines formed up to 3-4 MK and we use spatially unresolved EVE observations to infer the thermalmore » structure of the emitting region. For the nine events studied, the DEMs exhibited a two-component distribution during the impulsive phase, a low-temperature component with peak temperature of 1-2 MK, and a broad high-temperature component from 7 to 30 MK. A bimodal high-temperature component is also found for several events, with peaks at 8 and 25 MK during the impulsive phase. The origin of the emission was verified using Atmospheric Imaging Assembly images to be the flare ribbons and footpoints, indicating that the constructed DEMs represent the spatially average thermal structure of the chromospheric flare emission during the impulsive phase.« less

  14. MMS Observations of Langmuir Collapse and Emission?

    NASA Astrophysics Data System (ADS)

    Boardsen, S. A.; Che, H.; Wilder, F. D.; Ergun, R.; Le Contel, O.; Gershman, D. J.; Giles, B. L.; Moore, T. E.; Paterson, W.

    2017-12-01

    Through the two stream instability, electron beams accelerated by solar flares and nanoflares are believed to be responsible for several types of solar radio bursts observed in the corona and interplanetary medium, including flare-associated coronal Type J, U, and Type III radio bursts, and nanoflare-associated weak coronal type III bursts. However the duration of these radio bursts is several orders of magnitude longer than the linear saturation time of the electron two-stream instability. This discrepancy has been a long-standing puzzle. Recently Che et al. [2017, doi: 10.1073/pnas.1614055114] proposed a mechanism in which the plasma coherent emission is maintained by the cyclic Langmuir collapse. Wave coupling between Langmuir waves and electrostatic whistler waves is the key process necessary to close the feedback loop. In the magnetosphere, electron beams are commonly produced by acceleration processes such as magnetic reconnection, during which both whistlers and Langmuir waves are observed and thus provide possible in-situ observations to test and study the emission process near the acceleration source region. The high spatial and time resolution MMS fields and particle data are used to test aspects of this mechanism. In this presentation, we will present some preliminary results from MMS observations of electron beams near a reconnection region. We investigate, in the regions where the electron beams are observed, the coupling between high frequency Langmuir waves and low frequency electrostatic whistler waves, and the associated electromagnetic emissions, along with other possible specific features predicted by this model.

  15. Characteristics of black carbon emissions from in-use light-duty passenger vehicles.

    PubMed

    Zheng, Xuan; Zhang, Shaojun; Wu, Ye; Zhang, K Max; Wu, Xian; Li, Zhenhua; Hao, Jiming

    2017-12-01

    Mitigating black carbon (BC) emissions from various combustion sources has been considered an urgent policy issue to address the challenges of climate change, air pollution and health risks. Vehicles contribute considerably to total anthropogenic BC emissions and urban BC concentrations. Compared with heavy-duty diesel vehicles, there is much larger uncertainty in BC emission factors for light-duty passenger vehicles (LDPVs), in particular for gasoline LDPVs, which warrants further studies. In this study, we employed the dynamometer and the Aethalometer (AE-51) to measure second-by-second BC emissions from eight LDPVs by engine technology and driving cycle. The average BC emission factors under transient cycles (e.g., ECE-15, New European Driving Cycle, NEDC, Worldwide Harmonized Light Vehicles Test Cycle, WLTC) are 3.6-91.5 mg/km, 7.6 mg/km and 0.13-0.58 mg/km, respectively, for diesel (N = 3), gasoline direct injection (GDI) (N = 1) and gasoline port-fuel injection (PFI) engine categories (N = 4). For gasoline PFI LDPVs, the instantaneous emission profiles show a strong association of peak BC emissions with cold-start and high-speed aggressive driving. Such impacts lead to considerable BC emission contributions in cold-start periods (e.g., the first 47 s-94 s) over the entire cycle (e.g., 18-76% of the NEDC and 13-36% of the WLTC) and increased BC emission factors by 80-440% under the WLTC compared to the NEDC. For diesel BC emissions, the size distribution exhibits a typical unimodal pattern with one single peak appearing approximately from 120 to 150 nm, which is largely consistent with previous studies. Nevertheless, the average mass ratios of BC to particle mass (PM) range from 0.38 to 0.54 for three diesel samples, representing substantial impacts from both driving and engine conditions. The significant discrepancy between gasoline BC emission factors obtained from tailpipe exhaust versus ambient conditions suggest that more comparative

  16. [Study on Hexagonal Super-Lattice Pattern with Light Spot and Dim Spot in Dielectric Barrier Discharge by Optical Emission Spectra].

    PubMed

    Liu, Ying; Dong, Li-fang; Niu, Xue-jiao; Zhang, Chao

    2016-02-01

    The hexagonal super-lattice pattern composed of the light spot and the dim spot is firstly observed and investigated in the discharge of gas mixture of air and argon by using the dielectric barrier discharge device with double water electrodes. It is found that the dim spot is located at the center of its surrounding three light spots by observing the discharge image. Obviously, the brightness of the light spot and the dim spot are different, which indicates that the plasma states of the light spot and the dim spot may be different. The optical emission spectrum method is used to further study the several plasma parameters of the light spot and the dim spot in different argon content. The emission spectra of the N₂ second positive band (C³IIu --> B³IIg) are measured, from which the molecule vibration temperatures of the light spot and the dim spot are calculated. Based on the relative intensity ratio of the line at 391.4 nm and the N₂ line at 394.1 nm, the average electron energies of the light spot and the dim spot are investigated. The broadening of spectral line 696.57 nm (2P₂-1S₅) is used to study the electron densities of the light spot and the dim spot. The experiment shows that the molecule vibration temperature, average electron energy and the electron density of the dim spot are higher than those of the light spot in the same argon content. The molecule vibration temperature and electron density of the light spot and dim spot increase with the argon content increasing from 70% to 95%, while average electron energies of the light spot and dim spot decrease gradually. The short-exposure image recorded by a high speed video camera shows that the dim spot results from the surface discharges (SDs). The surface discharge induced by the volume discharge (VD) has the decisive effect on the formation of the dim spot. The experiment above plays an important role in studying the formation mechanism of the hexagonal super-lattice pattern with light spot and

  17. 40 CFR 86.1811-01 - Emission standards for light-duty vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  18. 40 CFR 86.1811-01 - Emission standards for light-duty vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  19. 40 CFR 86.1811-01 - Emission standards for light-duty vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  20. 40 CFR 86.1811-01 - Emission standards for light-duty vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  1. Leaf wound induced ultraweak photon emission is suppressed under anoxic stress: Observations of Spathiphyllum under aerobic and anaerobic conditions using novel in vivo methodology.

    PubMed

    Oros, Carl L; Alves, Fabio

    2018-01-01

    Plants have evolved a variety of means to energetically sense and respond to abiotic and biotic environmental stress. Two typical photochemical signaling responses involve the emission of volatile organic compounds and light. The emission of certain leaf wound volatiles and light are mutually dependent upon oxygen which is subsequently required for the wound-induced lipoxygenase reactions that trigger the formation of fatty acids and hydroperoxides; ultimately leading to photon emission by chlorophyll molecules. A low noise photomultiplier with sensitivity in the visible spectrum (300-720 nm) is used to continuously measure long duration ultraweak photon emission of dark-adapting whole Spathiphyllum leaves (in vivo). Leaves were mechanically wounded after two hours of dark adaptation in aerobic and anaerobic conditions. It was found that (1) nitrogen incubation did not affect the pre-wound basal photocounts; (2) wound induced leaf biophoton emission was significantly suppressed when under anoxic stress; and (3) the aerobic wound induced emission spectra observed was > 650 nm, implicating chlorophyll as the likely emitter. Limitations of the PMT photocathode's radiant sensitivity, however, prevented accurate analysis from 700-720 nm. Further examination of leaf wounding profile photon counts revealed that the pre-wounding basal state (aerobic and anoxic), the anoxic wounding state, and the post-wounding aerobic state statistics all approximate a Poisson distribution. It is additionally observed that aerobic wounding induces two distinct exponential decay events. These observations contribute to the body of plant wound-induced luminescence research and provide a novel methodology to measure this phenomenon in vivo.

  2. Light up-conversion from near-infrared to blue using a photoresponsive organic light-emitting device

    NASA Astrophysics Data System (ADS)

    Chikamatsu, Masayuki; Ichino, Yoshiro; Takada, Noriyuki; Yoshida, Manabu; Kamata, Toshihide; Yase, Kiyoshi

    2002-07-01

    A photoresponsive organic light-emitting device combining blue-emitting organic electroluminescent (EL) diode with titanyl phthalocyanine as a near-infrared (IR) sensitive layer was fabricated. By irradiating near-IR light to the device, blue emission occurred in the lower drive voltage (between 5 and 12 V). The result indicates that the device acts as a light switch and/or an up-converter from near-IR light (1.6 eV) to blue (2.6 eV). The EL response times of rise and decay using a near-IR light trigger were 260 and 330 mus, respectively. At a higher voltage (above 12 V), enhancement of blue emission was observed with near-IR light irradiation. The ON/OFF ratio reached a maximum of 103.

  3. Space-based observations of nitrogen dioxide: Trends in anthropogenic emissions

    NASA Astrophysics Data System (ADS)

    Russell, Ashley Ray

    Space-based instruments provide routine global observations, offering a unique perspective on the spatial and temporal variation of atmospheric constituents. In this dissertation, trends in regional-scale anthropogenic nitrogen oxide emissions (NO + NO2 ≡ NOx) are investigated using high resolution observations from the Ozone Monitoring Instrument (OMI). By comparing trends in OMI observations with those from ground-based measurements and an emissions inventory, I show that satellite observations are well-suited for capturing changes in emissions over time. The high spatial and temporal resolutions of the observations provide a uniquely complete view of regional-scale changes in the spatial patterns of NO 2. I show that NOx concentrations have decreased significantly in urban regions of the United States between 2005 and 2011, with an average reduction of 32 ± 7%. By examining day-of-week and interannual trends, I show that these reductions can largely be attributed to improved emission control technology in the mobile source fleet; however, I also show that the economic downturn of the late 2000's has impacted emissions. Additionally, I describe the development of a high-resolution retrieval of NO2 from OMI observations known as the Berkeley High Resolution (BEHR) retrieval. The BEHR product uses higher spatial and temporal resolution terrain and profile parameters than the operational retrievals and is shown to provide a more quantitative measure of tropospheric NO2 column density. These results have important implications for future retrievals of NO2 from space-based observations.

  4. Fast emission estimates in China and South Africa constrained by satellite observations

    NASA Astrophysics Data System (ADS)

    Mijling, Bas; van der A, Ronald

    2013-04-01

    Emission inventories of air pollutants are crucial information for policy makers and form important input data for air quality models. Unfortunately, bottom-up emission inventories, compiled from large quantities of statistical data, are easily outdated for emerging economies such as China and South Africa, where rapid economic growth change emissions accordingly. Alternatively, top-down emission estimates from satellite observations of air constituents have important advantages of being spatial consistent, having high temporal resolution, and enabling emission updates shortly after the satellite data become available. However, constraining emissions from observations of concentrations is computationally challenging. Within the GlobEmission project (part of the Data User Element programme of ESA) a new algorithm has been developed, specifically designed for fast daily emission estimates of short-lived atmospheric species on a mesoscopic scale (0.25 × 0.25 degree) from satellite observations of column concentrations. The algorithm needs only one forward model run from a chemical transport model to calculate the sensitivity of concentration to emission, using trajectory analysis to account for transport away from the source. By using a Kalman filter in the inverse step, optimal use of the a priori knowledge and the newly observed data is made. We apply the algorithm for NOx emission estimates in East China and South Africa, using the CHIMERE chemical transport model together with tropospheric NO2 column retrievals of the OMI and GOME-2 satellite instruments. The observations are used to construct a monthly emission time series, which reveal important emission trends such as the emission reduction measures during the Beijing Olympic Games, and the impact and recovery from the global economic crisis. The algorithm is also able to detect emerging sources (e.g. new power plants) and improve emission information for areas where proxy data are not or badly known (e

  5. Diagnostics of pre-breakdown light emission in a helium coplanar barrier discharge: the presence of neutral bremsstrahlung

    NASA Astrophysics Data System (ADS)

    Navrátil, Zdeněk; Morávek, Tomáš; Ráheľ, Jozef; Čech, Jan; Lalinský, Ondřej; Trunec, David

    2017-05-01

    Weak light emission (˜10-3 of active discharge signal; average count rate ˜ 1 photon s-1 nm-1) associated with surface charge relaxation during the dark phase of a helium diffuse coplanar barrier discharge was studied by optical emission spectroscopy, using a technique of phase-resolved single photon counting. The optical emission spectra of the dark phase contained luminescent bands of the dielectrics used (Al2O3, AlN) and spectral lines from the gas constituents (OH*, {{{N}}}2* , {{{N}}}2+* , He*, He{}2* , O*). During the charge relaxation event, a broad continuum appeared in the optical emission spectra, consisting of bremsstrahlung radiation and amplified luminescence of the dielectric barrier. The analysis presented suggests that the bremsstrahlung radiation originated from slow electrons colliding with neutral helium atoms. The fitting procedure we developed reproduced well the observed shape of the continuum. Moreover, it provided a method for the determination of electric field strength in the discharge during this particular phase. The electric field reached 1 kV cm-1 during the charge relaxation event.

  6. On-vehicle emission measurement of a light-duty diesel van at various speeds at high altitude

    NASA Astrophysics Data System (ADS)

    Wang, Xin; Yin, Hang; Ge, Yunshan; Yu, Linxiao; Xu, Zhenxian; Yu, Chenglei; Shi, Xuejiao; Liu, Hongkun

    2013-12-01

    As part of the research on the relationship between the speed of a vehicle operating at high altitude and its contaminant emissions, an on-vehicle emission measurement of a light-duty diesel van at the altitudes of 1000 m, 2400 m and 3200 m was conducted. The test vehicle was a 2.8 L turbocharged diesel Ford Transit. Its settings were consistent in all experiments. Regulated gaseous emissions, including CO, HC and NOx, together with particulate matter was measured at nine speeds ranged from 10 km h-1 to 90 km h-1 with 10 km h-1 intervals settings. At each speed, measurement lasted for at least 120 s to ensure the sufficiency and reliability of the collected data. The results demonstrated that at all altitudes, CO and HC emissions decreased as the vehicle speed increased. However both NOx and PM increased with vehicle speed. In terms of the effects of altitude, an increase in CO, HC and PM was observed with the rising of altitude at each vehicle speed. NOx behaved different: emission of NOx initially increased as the vehicle was raised from 1000 m to 2400 m, but it decreased when the vehicle was further elevated to 3200 m.

  7. Quantitative estimation of the energy flux during an explosive chromospheric evaporation in a white light flare kernel observed by Hinode, IRIS, SDO, and RHESSI

    NASA Astrophysics Data System (ADS)

    Lee, Kyoung-Sun; Imada, Shinsuke; Kyoko, Watanabe; Bamba, Yumi; Brooks, David H.

    2016-10-01

    An X1.6 flare occurred at the AR 12192 on 2014 October 22 at14:02 UT was observed by Hinode, IRIS, SDO, and RHESSI. We analyze a bright kernel which produces a white light (WL) flare with continuum enhancement and a hard X-ray (HXR) peak. Taking advantage of the spectroscopic observations of IRIS and Hinode/EIS, we measure the temporal variation of the plasma properties in the bright kernel in the chromosphere and corona. We found that explosive evaporation was observed when the WL emission occurred, even though the intensity enhancement in hotter lines is quite weak. The temporal correlation of the WL emission, HXR peak, and evaporation flows indicate that the WL emission was produced by accelerated electrons. To understand the white light emission processes, we calculated the deposited energy flux from the non-thermal electrons observed by RHESSI and compared it to the dissipated energy estimated from the chromospheric line (Mg II triplet) observed by IRIS. The deposited energy flux from the non-thermal electrons is about 3.1 × 1010erg cm-2 s-1 when we consider a cut-off energy 20 keV. The estimated energy flux from the temperature changes in the chromosphere measured from the Mg II subordinate line is about 4.6-6.7×109erg cm-2 s-1, ˜ 15-22% of the deposited energy. By comparison of these estimated energy fluxes we conclude that the continuum enhancement was directly produced by the non-thermal electrons.

  8. Green light emitting curcumin dye in organic solvents

    NASA Astrophysics Data System (ADS)

    Mubeen, Mohammad; Deshmukh, Abhay D.; Dhoble, S. J.

    2018-05-01

    In this modern world, the demand for the white light emission has increased because of its wide applications in various display and lighting devices, sensors etc. This white light can be produced by mixing red, green and blue lights. Thus this green light can be produced from the plant extract i.e., Turmeric. Curcumin is the essential element present in turmeric to generate the green light. The Photoluminescence (PL) emission is observed at 540 nm at 380nm excitation. This method of generating green light is very simple, cost effective and efficient when compared to other methods.

  9. PM₂.₅ emissions from light-duty gasoline vehicles in Beijing, China.

    PubMed

    Shen, Xianbao; Yao, Zhiliang; Huo, Hong; He, Kebin; Zhang, Yingzhi; Liu, Huan; Ye, Yu

    2014-07-15

    As stricter standards for diesel vehicles are implemented in China, and the use of diesel trucks is forbidden in urban areas, determining the contribution of light-duty gasoline vehicles (LDGVs) to on-road PM2.5 emissions in cities is important. Additionally, in terms of particle number and size, particulates emitted from LDGVs have a greater health impact than particulates emitted from diesel vehicles. In this work, we measured PM2.5 emissions from 20 LDGVs in Beijing, using an improved combined on-board emission measurement system. We compared these measurements with those reported in previous studies, and estimated the contribution of LDGVs to on-road PM2.5 emissions in Beijing. The results show that the PM2.5 emission factors for LDGVs, complying with European Emission Standards Euro-0 through Euro-4 were: 117.4 ± 142, 24.1 ± 20.4, 4.85 ± 7.86, 0.99 ± 1.32, 0.17 ± 0.15 mg/km, respectively. Our results show a significant decline in emissions with improving vehicle technology. However, this trend is not reflected in recent emission inventory studies. The daytime contributions of LDGVs to PM2.5 emissions on highways, arterials, residential roads, and within urban areas of Beijing were 44%, 62%, 57%, and 57%, respectively. The contribution of LDGVs to PM2.5 emissions varied both for different road types and for different times. Copyright © 2014 Elsevier B.V. All rights reserved.

  10. IRIS , Hinode , SDO , and RHESSI Observations of a White Light Flare Produced Directly by Non-thermal Electrons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Kyoung-Sun; Imada, Shinsuke; Watanabe, Kyoko

    An X1.6 flare occurred in active region AR 12192 on 2014 October 22 at 14:02 UT and was observed by Hinode , IRIS , SDO , and RHESSI . We analyze a bright kernel that produces a white light (WL) flare with continuum enhancement and a hard X-ray (HXR) peak. Taking advantage of the spectroscopic observations of IRIS and Hinode /EIS, we measure the temporal variation of the plasma properties in the bright kernel in the chromosphere and corona. We find that explosive evaporation was observed when the WL emission occurred, even though the intensity enhancement in hotter lines ismore » quite weak. The temporal correlation of the WL emission, HXR peak, and evaporation flows indicates that the WL emission was produced by accelerated electrons. To understand the WL emission process, we calculated the energy flux deposited by non-thermal electrons (observed by RHESSI ) and compared it to the dissipated energy estimated from a chromospheric line (Mg ii triplet) observed by IRIS . The deposited energy flux from the non-thermal electrons is about (3–7.7) × 10{sup 10} erg cm{sup −2} s{sup −1} for a given low-energy cutoff of 30–40 keV, assuming the thick-target model. The energy flux estimated from the changes in temperature in the chromosphere measured using the Mg ii subordinate line is about (4.6–6.7) × 10{sup 9} erg cm{sup −2} s{sup −1}: ∼6%–22% of the deposited energy. This comparison of estimated energy fluxes implies that the continuum enhancement was directly produced by the non-thermal electrons.« less

  11. Transparent organic light-emitting diodes with balanced white emission by minimizing waveguide and surface plasmonic loss.

    PubMed

    Zhang, Yi-Bo; Ou, Qing-Dong; Li, Yan-Qing; Chen, Jing-De; Zhao, Xin-Dong; Wei, Jian; Xie, Zhong-Zhi; Tang, Jian-Xin

    2017-07-10

    It is challenging in realizing high-performance transparent organic light-emitting diodes (OLEDs) with symmetrical light emission to both sides. Herein, an efficient transparent OLED with highly balanced white emission to both sides is demonstrated by integrating quasi-periodic nanostructures into the organic emitter and the metal-dielectric composite top electrode, which can simultaneously suppressing waveguide and surface plasmonic loss. The power efficiency and external quantum efficiency are raised to 83.5 lm W -1 and 38.8%, respectively, along with a bi-directional luminance ratio of 1.26. The proposed scheme provides a facile route for extending application scope of transparent OLEDs for future transparent displays and lightings.

  12. Observations of EMIC Triggered Emissions off the Magnetic Equatorial Plane

    NASA Astrophysics Data System (ADS)

    Grison, B.; Breuillard, H.; Santolik, O.; Cornilleau-Wehrlin, N.

    2016-12-01

    On 19/08/2005 Cluster spacecraft had their perigee close to the dayside of the Earth magnetic equatorial plane, at about 14 hours Magnetic Local Time. The spacecraft crossed the equator from the southern hemisphere toward the northern hemisphere. In the Southern hemisphere, at about -23° magnetic latitude (MLAT) and at distance of 5.25 Earth Radii from Earth, Cluster 3 observes an EMIC triggered emission between the He+ and the proton local gyrofrequencies. The magnetic waveform (STAFF instrument data) is transformed into the Fourier space for a study based on single value decomposition (SVD) analysis. The emission lasts about 30s. The emission frequency rises from 1Hz up to 1.9Hz. The emission polarization is left-hand, its coherence value is high and the propagation angle is field aligned (lower than 30º). The Poynting flux orientation could not be established. Based on previous study results, these properties are indicative of an observation in vicinity of the source region of the triggered emission. From our knowledge this is the first time that EMIC triggered emission are observed off the magnetic equator. In order to identify the source region we study two possibilities: a source region at higher latitudes than the observations (and particles orbiting in "Shabansky" orbits) and a source region close to the magnetic equatorial plane, as reported in previous studies. We propose to identify the source region from ray tracing analysis and to compare the observed propagation angle in several frequency ranges to the ray tracing results.

  13. White light upconversion emission in Yb3+/ Er3+/ Tm3+ codoped oxy-fluoride lithium tungsten tellurite glass ceramics

    NASA Astrophysics Data System (ADS)

    Ansari, Ghizal F.; Mahajan, S. K.

    2012-02-01

    The bright white upconversion emission ( tri-colour UC) is generated in Er/Tm/Yb tri -doped oxy-fluoride lithium tungsten tellurite (TWLOF)glass ceramics containing crystalline phase LiYbF4 under the excitation of 980nm laser diode. The most appropriate combination of rare-earth ions (2mol% YbF3 1mol% ErF3 and 1mol%TmF3 )of glass ceramic sample has been determined to tune the primary colour (RGB and generate white light emission. By varying the pump power, intense and weak blue (487nm, 437nm), green (525nm and 545nm) and red (662nm) emission are simultaneously observed at room temperature. The dependence of upconversion emission intensity suggest that a theephoton process is responsible for the blue emission of Tm3+ ions and red emission due to both Tm3+ and Er3+ ions , while green emission originated from two photon processes in Er3+ ions. Also tri colour upconvesion and energy transfer in this glass ceramics sample were studied under 808nm laser diode excitation. The Upconversion mechanisms and Tm3+ ions plays role of both emitter and activator (transfer energy to Er) were discussed.

  14. Rear surface light emission measurements from laser-produced shock waves in clear and Al-coated polystyrene targets

    NASA Astrophysics Data System (ADS)

    McLean, E. A.; Deniz, A. V.; Schmitt, A. J.; Stamper, J. A.; Obenschain, S. P.; Lehecka, T.; Mostovych, A. N.; Seely, J.

    1999-08-01

    The Nike KrF laser, with its very uniform focal distributions, has been used at intensities near 10 14 W/cm 2 to launch shock waves in polystyrene targets. The rear surface visible light emission differed between clear polystyrene (CH) targets and targets with a thin (125 nm) Al coating on the rear side. The uncoated CH targets showed a relatively slowly rising emission followed by a sudden fall when the shock emerges, while the Al-coated targets showed a rapid rise in emission when the shock emerges followed by a slower fall, allowing an unambiguous determination of the time the shock arrived at the rear surface. A half-aluminized target allowed us to observe this difference in a single shot. The brightness temperature of both the aluminized targets and the non-aluminized targets was slightly below but close to rear surface temperature predictions of a hydrodynamic code. A discussion of preheat effects is given.

  15. XMM-Newton Observations of Solar Wind Charge Exchange Emission

    NASA Technical Reports Server (NTRS)

    Snowden, S. L.; Collier, M. R.; Kuntz, K. D.

    2004-01-01

    We present an XMM-Newton spectrum of diffuse X-ray emission from within the solar system. The spectrum is dominated by O VII and O VIII lines at 0.57 keV and 0.65 keV, O VIII (and possibly Fe XVII) lines at approximately 0.8 keV, Ne IX lines at approximately 0.92 keV, and Mg XI lines at approximately 1.35 keV. This spectrum is consistent with what is expected from charge exchange emission between the highly ionized solar wind and either interstellar neutrals in the heliosphere or material from Earth's exosphere. The emission is clearly seen as a low-energy ( E less than 1.5 keV) spectral enhancement in one of a series of observations of the Hubble Deep Field North. The X-ray enhancement is concurrent with an enhancement in the solar wind measured by the ACE satellite. The solar wind enhancement reaches a flux level an order of magnitude more intense than typical fluxes at 1 AU, and has ion ratios with significantly enhanced higher ionization states. Whereas observations of the solar wind plasma made at a single point reflect only local conditions which may only be representative of solar wind properties with spatial scales ranging from less than half of an Earth radii (approximately 10 s) to 100 Earth radii, X-ray observations of solar wind charge exchange are remote sensing measurements which may provide observations which are significantly more global in character. Besides being of interest in its own right for studies of the solar system, this emission can have significant consequences for observations of more cosmological objects. It can provide emission lines at zero redshift which are of particular interest (e.g., O VII and O VIII) in studies of diffuse thermal emission, and which can therefore act as contamination in objects which cover the entire detector field of view. We propose the use of solar wind monitoring data, such as from the ACE and Wind spacecraft, as a diagnostic to screen for such possibilities.

  16. OCO-2 and GOSAT observations of anthropogenic emissions of carbon dioxide.

    NASA Astrophysics Data System (ADS)

    Maksyutov, S. S.; Yadav, V.; Eldering, A.; Janardanan Achari, R.; Saito, M.; Oda, T.

    2017-12-01

    We apply high resolution transport modeling with Lagrangian transport model Flexpart to analyze CO2 emission signatures in the total column XCO2 observed by OCO-2 and GOSAT satellites in 2014-2016. To reduce computational load for transport modeling, the OCO-2 observations are aggregated into 1 second averages prepared separately for two groups (left and right) made of simultaneously measured eight OCO-2 observations (footprints). Each group has surface footprint size close to 0.1 degree. The spatial distribution of CO2 concentrations, resulting from anthropogenic emissions, are estimated with the transport model for all GOSAT and OCO-2 observation locations using high-resolution emission inventory (ODIAC) and biospheric exchange simulated with VISIT model at 0.1 degree resolution. Based on this estimate, using a threshold value of 0.1 ppm, the observations are classified into two categories: data contaminated by the anthropogenic sources and those not including this contamination. To extract concentration enhancements due to the anthropogenic emissions, we define a clean background (the averaged values for the data free from contamination by anthropogenic emissions) in 10° by 10° regions over the globe that are subtracted from the observational data including anthropogenic contamination. These anomalies are binned and analyzed to see a match between observed and simulated enhancements. For both OCO-2 and GOSAT, we found linear relations between model and observed anomalies. Similar to the earlier findings made with GOSAT; enhancements observed by OCO-2 match the simulated ones with a regression slope close to unity. Even after aggregation of OCO-2 data into groups of up to 12 individual soundings, the number of enhanced XCO2 observations by OCO-2 is 15 and 25 times larger than that of GOSAT in each 0.1 ppm bin, in the range of simulated enhancements between 0.1 and 2 ppm. The result confirms high potential of using OCO-2 observations for analyzing anthropogenic

  17. Possible Mg II emission in B stars observed from Copernicus

    NASA Technical Reports Server (NTRS)

    Kondo, Y.; Whaley, R. S.; Modisette, J. L.; Dufour, R. J.

    1976-01-01

    Four B stars, Alpha Vir, Beta Cen, Alpha Gru, and Beta Lib, were observed with the Copernicus spectrometer at a resolution of 0.1 A in order to investigate the presence of chromospheric emission. Emission was observed in Beta Cen and Alpha Gru, while the results for Alpha Vir and Beta Lib were inconclusive.

  18. High-Mileage Light-Duty Fleet Vehicle Emissions: Their Potentially Overlooked Importance.

    PubMed

    Bishop, Gary A; Stedman, Donald H; Burgard, Daniel A; Atkinson, Oscar

    2016-05-17

    State and local agencies in the United States use activity-based computer models to estimate mobile source emissions for inventories. These models generally assume that vehicle activity levels are uniform across all of the vehicle emission level classifications using the same age-adjusted travel fractions. Recent fuel-specific emission measurements from the SeaTac Airport, Los Angeles, and multi-year measurements in the Chicago area suggest that some high-mileage fleets are responsible for a disproportionate share of the fleet's emissions. Hybrid taxis at the airport show large increases in carbon monoxide, hydrocarbon, and oxide of nitrogen emissions in their fourth year when compared to similar vehicles from the general population. Ammonia emissions from the airport shuttle vans indicate that catalyst reduction capability begins to wane after 5-6 years, 3 times faster than is observed in the general population, indicating accelerated aging. In Chicago, the observed, on-road taxi fleet also had significantly higher emissions and an emissions share that was more than double their fleet representation. When compounded by their expected higher than average mileage accumulation, we estimate that these small fleets (<1% of total) may be overlooked as a significant emission source (>2-5% of fleet emissions).

  19. Light-induced protein nitration and degradation with HONO emission

    NASA Astrophysics Data System (ADS)

    Meusel, Hannah; Elshorbany, Yasin; Kuhn, Uwe; Bartels-Rausch, Thorsten; Reinmuth-Selzle, Kathrin; Kampf, Christopher J.; Li, Guo; Wang, Xiaoxiang; Lelieveld, Jos; Pöschl, Ulrich; Hoffmann, Thorsten; Su, Hang; Ammann, Markus; Cheng, Yafang

    2017-10-01

    Proteins can be nitrated by air pollutants (NO2), enhancing their allergenic potential. This work provides insight into protein nitration and subsequent decomposition in the presence of solar radiation. We also investigated light-induced formation of nitrous acid (HONO) from protein surfaces that were nitrated either online with instantaneous gas-phase exposure to NO2 or offline by an efficient nitration agent (tetranitromethane, TNM). Bovine serum albumin (BSA) and ovalbumin (OVA) were used as model substances for proteins. Nitration degrees of about 1 % were derived applying NO2 concentrations of 100 ppb under VIS/UV illuminated conditions, while simultaneous decomposition of (nitrated) proteins was also found during long-term (20 h) irradiation exposure. Measurements of gas exchange on TNM-nitrated proteins revealed that HONO can be formed and released even without contribution of instantaneous heterogeneous NO2 conversion. NO2 exposure was found to increase HONO emissions substantially. In particular, a strong dependence of HONO emissions on light intensity, relative humidity, NO2 concentrations and the applied coating thickness was found. The 20 h long-term studies revealed sustained HONO formation, even when concentrations of the intact (nitrated) proteins were too low to be detected after the gas exchange measurements. A reaction mechanism for the NO2 conversion based on the Langmuir-Hinshelwood kinetics is proposed.

  20. NuSTAR observations of the bullet cluster: constraints on inverse Compton emission

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wik, Daniel R.; Hornstrup, A.; Molendi, S.

    2014-08-13

    Here, the search for diffuse non-thermal inverse Compton (IC) emission from galaxy clusters at hard X-ray energies has been undertaken with many instruments, with most detections being either of low significance or controversial. Because all prior telescopes sensitive at E > 10 keV do not focus light and have degree-scale fields of view, their backgrounds are both high and difficult to characterize. The associated uncertainties result in lower sensitivity to IC emission and a greater chance of false detection. In this work, we present 266 ks NuSTAR observations of the Bullet cluster, which is detected in the energy range 3-30more » keV. NuSTAR's unprecedented hard X-ray focusing capability largely eliminates confusion between diffuse IC and point sources; however, at the highest energies, the background still dominates and must be well understood. To this end, we have developed a complete background model constructed of physically inspired components constrained by extragalactic survey field observations, the specific parameters of which are derived locally from data in non-source regions of target observations. Applying the background model to the Bullet cluster data, we find that the spectrum is well—but not perfectly—described as an isothermal plasma with kT = 14.2 ± 0.2 keV. To slightly improve the fit, a second temperature component is added, which appears to account for lower temperature emission from the cool core, pushing the primary component to kT ~ 15.3 keV. We see no convincing need to invoke an IC component to describe the spectrum of the Bullet cluster, and instead argue that it is dominated at all energies by emission from purely thermal gas. The conservatively derived 90% upper limit on the IC flux of 1.1 × 10 –12 erg s –1 cm –2 (50-100 keV), implying a lower limit on B ≳ 0.2 μG, is barely consistent with detected fluxes previously reported. In addition to discussing the possible origin of this discrepancy, we remark on the

  1. Low light CMOS contact imager with an integrated poly-acrylic emission filter for fluorescence detection.

    PubMed

    Dattner, Yonathan; Yadid-Pecht, Orly

    2010-01-01

    This study presents the fabrication of a low cost poly-acrylic acid (PAA) based emission filter integrated with a low light CMOS contact imager for fluorescence detection. The process involves the use of PAA as an adhesive for the emission filter. The poly-acrylic solution was chosen due its optical transparent properties, adhesive properties, miscibility with polar protic solvents and most importantly its bio-compatibility with a biological environment. The emission filter, also known as an absorption filter, involves dissolving an absorbing specimen in a polar protic solvent and mixing it with the PAA to uniformly bond the absorbing specimen and harden the filter. The PAA is optically transparent in solid form and therefore does not contribute to the absorbance of light in the visible spectrum. Many combinations of absorbing specimen and polar protic solvents can be derived, yielding different filter characteristics in different parts of the spectrum. We report a specific combination as a first example of implementation of our technology. The filter reported has excitation in the green spectrum and emission in the red spectrum, utilizing the increased quantum efficiency of the photo sensitive sensor array. The thickness of the filter (20 μm) was chosen by calculating the desired SNR using Beer-Lambert's law for liquids, Quantum Yield of the fluorophore and the Quantum Efficiency of the sensor array. The filters promising characteristics make it suitable for low light fluorescence detection. The filter was integrated with a fully functional low noise, low light CMOS contact imager and experimental results using fluorescence polystyrene micro-spheres are presented.

  2. HUBBLE SPACE TELESCOPE/ADVANCED CAMERA FOR SURVEYS OBSERVATIONS OF EUROPA'S ATMOSPHERIC ULTRAVIOLET EMISSION AT EASTERN ELONGATION

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Saur, Joachim; Roth, Lorenz; Schilling, Nico

    2011-09-10

    We report results of a Hubble Space Telescope (HST) campaign with the Advanced Camera for Surveys to observe Europa at eastern elongation, i.e., Europa's leading side, on 2008 June 29. With five consecutive HST orbits, we constrain Europa's atmospheric O I 1304 A and O I 1356 A emissions using the prism PR130L. The total emissions of both oxygen multiplets range between 132 {+-} 14 and 226 {+-} 14 Rayleigh. An additional systematic error with values on the same order as the statistical errors may be due to uncertainties in modeling the reflected light from Europa's surface. The total emissionmore » also shows a clear dependence of Europa's position with respect to Jupiter's magnetospheric plasma sheet. We derive a lower limit for the O{sub 2} column density of 6 x 10{sup 18} m{sup -2}. Previous observations of Europa's atmosphere with the Space Telescope Imaging Spectrograph in 1999 of Europa's trailing side show an enigmatic surplus of radiation on the anti-Jovian side within the disk of Europa. With emission from a radially symmetric atmosphere as a reference, we searched for an anti-Jovian versus sub-Jovian asymmetry with respect to the central meridian on the leading side and found none. Likewise, we searched for departures from a radially symmetric atmospheric emission and found an emission surplus centered around 90 deg. west longitude, for which plausible mechanisms exist. Previous work about the possibility of plumes on Europa due to tidally driven shear heating found longitudes with strongest local strain rates which might be consistent with the longitudes of maximum UV emissions. Alternatively, asymmetries in Europa's UV emission can also be caused by inhomogeneous surface properties, an optically thick atmospheric contribution of atomic oxygen, and/or by Europa's complex plasma interaction with Jupiter's magnetosphere.« less

  3. Evidence for Cocoon Emission from the Early Light Curve of SSS17a

    NASA Astrophysics Data System (ADS)

    Piro, Anthony L.; Kollmeier, Juna A.

    2018-03-01

    Swope Supernova Survey 2017a (SSS17a) was discovered as the first optical counterpart to the gravitational wave event GW170817. Although its light curve on the timescale of weeks roughly matches the expected luminosity and red color of an r-process powered transient, the explanation for the blue emission from high velocity material over the first few days is not as clear. Here we show that the power-law evolution of the luminosity, temperature, and photospheric radius during these early times can be explained by cooling of shock-heated material around the neutron star merger. This heating is likely from the interaction of the gamma-ray burst jet with merger debris, the so-called cocoon emission. We summarize the properties of this emission and provide formulae that can be used to study future detections of shock cooling from merging neutron stars. This argues that optical transient surveys should search for such early, blue light if they wish to find off-axis gamma-ray bursts and double neutron star gravitational wave events as soon as possible after the merger.

  4. Luminescence spectroscopic observation of singlet oxygen formation in extra virgin olive oil as affected by irradiation light wavelengths, 1,4-diazabicyclo[2.2.2]octane, irradiation time, and oxygen bubbling.

    PubMed

    Jung, Mun Y; Choi, Dong S; Park, Ki H; Lee, Bosoon; Min, David B

    2011-01-01

    A spectrofluorometer equipped with a highly sensitive near-IR InGaAs detector was used for the direct visualization of singlet oxygen emission at 1268 nm in olive oil during light irradiation with various different wavelengths. The virgin olive oil in methylene chloride (20% w/v, oxygen saturated) was irradiated at the 301, 417, 454, 483, and 668 nm, then the emission at 1268 nm, singlet oxygen dimole decaying was observed. The result showed the highest production of (1)O(2) with light irradiation at 417 nm, and followed by at 668 nm in virgin olive oil, indicating that pheophytin a and chlorophyll a were the most responsible components for the production of singlet oxygen. The UV light irradiations at the wavelength of 200, 250, and 300 nm did not induce any detectable luminescence emission at 1268 nm, but 350 nm produced weak emission at 1269 nm. The quantity of (1)O(2) produced with excitation at 350 nm was about 1/6 of that of irradiation at 417 nm. Addition of an efficient (1)O(2) quencher, 1,4-diazabicyclo[2.2.2]octane, in virgin olive oil in methylene chloride greatly decreased the luminescence emission at 1268 nm, confirming the singlet oxygen production in olive oil. Singlet oxygen production was more efficient in oxygen-purged virgin olive oil than in oxygen non-purged olive oil. This represents first report on the direct observation of singlet oxygen formation in olive oil as well as in real-food system after visible light illumination. Practical Application: The present results show the positive evidence of the singlet oxygen involvement in rapid oxidative deterioration of virgin olive oil under visible light. This paper also shows the effects of different wavelength of light irradiation on the formation of singlet oxygen in olive oil. The present results would provide important information for the understanding of the mechanism involved in rapid oxidative quality deterioration of virgin olive oil under light illumination and for searching the

  5. Einstein Observations of X-ray emission from A stars

    NASA Astrophysics Data System (ADS)

    Golub, L.; Harnden, F. R., Jr.; Maxson, C. W.; Rosner, R.; Vaiana, G. S.; Cash, W., Jr.; Snow, T. P., Jr.

    1983-08-01

    Results are reported from the combined CfA Stellar Survey of selected bright A stars and an Einstein Guest Observer program for Ap and Am stars. In an initial report of results from the CfA Stellar Surveys by Vaiana et al. (1981) it was noted that the spread in observed X-ray luminosities among the few A stars observed was quite large. The reasons for this large spread was studied by Pallavicini et al. (1981). It was found that the X-ray emission from normal stars is related very strongly to bolometric luminosity for early-type stars and to rotation rate for late-type stars. However, an exception to this rule has been the apparently anomalous behavior of A star X-ray emission, for which the large spread in luminosity showed no apparent correlation with either bolometric luminosity or stellar rotation rate. In the present study, it is shown that the level of emission from normal A stars agrees with the correlation observed for O and B stars.

  6. Correlation Analysis of Prompt Emission from Gamma Ray Bursts

    NASA Astrophysics Data System (ADS)

    Pothapragada, Sriharsha

    Prompt emission from gamma-ray bursts (GRBs) exhibits very rapid, complicated temporal and spectral evolution. This diverse variability in the light-curves reflects the complicated nature of the underlying physics, in which inter-penetrating relativistic shells in the outflow are believed to generate strong magnetic fields that vary over very small scales. We use the theory of jitter radiation to model the emission from such regions and the resulting overall prompt gamma ray emission from a series of relativistic collisionless shocks. We present simulated GRB light-curves developed as a series of "pulses" corresponding to instantaneously illuminated "thin-shell" regions emitting via the jitter radiation mechanism. The effects of various geometries, viewing angles, and bulk Lorentz factor profiles of the radiating outflow jets on the spectral features and evolution of these light-curves are explored. Our results demonstrate how an anisotropic jitter radiation pattern, in conjunction with relativistic shock kinematics, can produce certain features observed in the GRB prompt emission spectra, such as the occurrence of hard, synchrotron violating spectra, the "tracking" of observed flux with spectral parameters, and spectral softening below peak energy within individual episodes of the light curve. We highlight predictions in the light of recent advances in the observational sphere of GRBs.

  7. First Observations of 5fce Auroral Roar Emissions

    NASA Astrophysics Data System (ADS)

    Labelle, J. W.

    2012-12-01

    Auroral radio emissions reveal physics of beam-plasma interactions and provide possibilities to remotely sense ionospheric plasma processes. Sato et al. [2012] recently discovered that auroral roar emissions, long known to occur at two and three times the electron gyrofrequency (fce), also occur at 4fce. Using data from wave receivers in the British Antarctic Survey Automatic Geophysical Observatories (BAS AGOs), we confirm the existence of 4fce-roars and observe for the first time 5fce-roars. A search at higher frequencies did not find higher harmonics, however. Both 4fce- and 5fce-roars only occur in sunlit conditions near the summer soltices. The harmonic emissions scale as expected with the strength of the geomagnetic field, and combining data from four stations with a wide range of magnetic field strengths suggests that the source height of the 4fce may lie around 245 km, significantly lower than the ˜ 275 km estimated for 2fce-roars. These observations show that the auroral roar generation mechanism acts under a broader set of plasma densities than previously considered, highlight how ubiquitous and robust the mechanism must be in different plasma environments, and suggest a broader application for remote sensing methods exploiting auroral roar, such as those described by Weatherwax et al. [2002]. References: Sato, Y., T. Ono, N. Sato, and Y. Ogawa, First observations of 4fce auroral roar emissions, Geophys. Res. Lett., 39, L07101, doi:10.1029/2012GL051205, 2012. Weatherwax, A.T., P.H. Yoon, and J. LaBelle, Model results and interpretation related to topside observations of auroral roar, J. Geophys. Res., 107, 10.1029/2001JA000315, 2002.

  8. Terrestrial FeO Continuum Emission Observed in Sky Spectra

    NASA Astrophysics Data System (ADS)

    Slanger, Tom G.; Melchiorri, R.; Saran, D. V.

    2011-01-01

    The terrestrial continuum emission in the visible spectral region has often been studied by both astronomers and aeronomers, in order to clarify backgrounds and the nature of the emissions. New observations from the ESI spectrograph on the Keck II telescope, as well as from the OSIRIS/Odin spectrograph and orbiter, have established that a major component of the emission originates with the FeO molecule [Evans et al., 2010]. This quasi-continuum peaks at 5950 A and extends from 5000 A well into the infrared. The identity has been demonstrated by comparison with meteor trains and laboratory measurements [Jenniskens et al., 2000]. Early studies of the continuum show consistency with the FeO emission as presently observed [Gadsden and Marovich, 1973]. Analysis of spectra from Kitt Peak [Neugent and Massey, 2010] demonstrates the great similarity between FeO emission in a clean atmosphere and high pressure sodium lamp emission in a polluted atmosphere. This research was supported by NSF Aeronomy under Grant ATM-0637433 . Evans, W.F.J., et al., Geophys. Res. Lett. [in press, 2010] Gadsden, M. and E. Marovich, J. Atm. Terr. Phys., 35, 1601-1614 [1973] Jenniskens, P., et al., Earth, Moon and Planets, 82-83, 429-434 [2000] Neugent, K.F. and P. Massey, PASP [in press, 2010

  9. Quantum mechanical modeling the emission pattern and polarization of nanoscale light emitting diodes.

    PubMed

    Wang, Rulin; Zhang, Yu; Bi, Fuzhen; Frauenheim, Thomas; Chen, GuanHua; Yam, ChiYung

    2016-07-21

    Understanding of the electroluminescence (EL) mechanism in optoelectronic devices is imperative for further optimization of their efficiency and effectiveness. Here, a quantum mechanical approach is formulated for modeling the EL processes in nanoscale light emitting diodes (LED). Based on non-equilibrium Green's function quantum transport equations, interactions with the electromagnetic vacuum environment are included to describe electrically driven light emission in the devices. The presented framework is illustrated by numerical simulations of a silicon nanowire LED device. EL spectra of the nanowire device under different bias voltages are obtained and, more importantly, the radiation pattern and polarization of optical emission can be determined using the current approach. This work is an important step forward towards atomistic quantum mechanical modeling of the electrically induced optical response in nanoscale systems.

  10. Biogenic VOC Emissions from Tropical Landscapes

    NASA Astrophysics Data System (ADS)

    Guenther, A.; Greenberg, J.; Harley, P.; Otter, L.; Vanni Gatti, L.; Baker, B.

    2003-04-01

    Biogenic VOC have an important role in determining the chemical composition of atmosphere. As a result, these compounds are important for visibility, biogeochemical cycling, climate and radiative forcing, and the health of the biosphere. Tropical landscapes are estimated to release about 80% of total global biogenic VOC emissions but have been investigated to lesser extent than temperate regions. Tropical VOC emissions are particularly important due to the strong vertical transport and the rapid landuse change that is occurring there. This presentation will provide an overview of field measurements of biogenic VOC emissions from tropical landscapes in Amazonia (Large-scale Biosphere-atmosphere experiment in Amazonia, LBA) Central (EXPRESSO) and Southern (SAFARI 2000) Africa, Asia and Central America. Flux measurement methods include leaf-scale (enclosure measurements), canopy-scale (above canopy tower measurements), landscape-scale (tethered balloon), and regional-scale (aircraft measurements) observations. Typical midday isoprene emission rates for different landscapes vary by more than a factor of 20 with the lowest emissions observed from degraded forests. Emissions of alpha-pinene vary by a similar amount with the highest emissions associated with landscapes dominated by light dependent monoterpene emitting plants. Isoprene emissions tend to be higher for neotropical forests (Amazon and Costa Rica) in comparison to Africa and Asian tropical forests but considerable differences are observed within regions. Strong seasonal variations were observed in both the Congo and the Amazon rainforests with peak emissions during the dry seasons. Substantial emissions of light dependent monoterpenes, methanol and acetone are characteristic of at least some tropical landscapes.

  11. Constraining Swiss Methane Emissions from Atmospheric Observations: Sensitivities and Temporal Development

    NASA Astrophysics Data System (ADS)

    Henne, Stephan; Leuenberger, Markus; Steinbacher, Martin; Eugster, Werner; Meinhardt, Frank; Bergamaschi, Peter; Emmenegger, Lukas; Brunner, Dominik

    2017-04-01

    Similar to other Western European countries, agricultural sources dominate the methane (CH4) emission budget in Switzerland. 'Bottom-up' estimates of these emissions are still connected with relatively large uncertainties due to considerable variability and uncertainties in observed emission factors for the underlying processes (e.g., enteric fermentation, manure management). Here, we present a regional-scale (˜300 x 200 km2) atmospheric inversion study of CH4 emissions in Switzerland making use of the recently established CarboCount-CH network of four stations on the Swiss Plateau as well as the neighbouring mountain-top sites Jungfraujoch and Schauinsland (Germany). Continuous observations from all CarboCount-CH sites are available since 2013. We use a high-resolution (7 x 7 km2) Lagrangian particle dispersion model (FLEXPART-COSMO) in connection with two different inversion systems (Bayesian and extended Kalman filter) to estimate spatially and temporally resolved CH4 emissions for the Swiss domain in the period 2013 to 2016. An extensive set of sensitivity inversions is used to assess the overall uncertainty of our inverse approach. In general we find good agreement of the total Swiss CH4 emissions between our 'top-down' estimate and the national 'bottom-up' reporting. In addition, a robust emission seasonality, with reduced winter time values, can be seen in all years. No significant trend or year-to-year variability was observed for the analysed four-year period, again in agreement with a very small downward trend in the national 'bottom-up' reporting. Special attention is given to the influence of boundary conditions as taken from different global scale model simulations (TM5, FLEXPART) and remote observations. We find that uncertainties in the boundary conditions can induce large offsets in the national total emissions. However, spatial emission patterns are less sensitive to the choice of boundary condition. Furthermore and in order to demonstrate the

  12. Secondary organic aerosol formation exceeds primary particulate matter emissions for light-duty gasoline vehicles

    NASA Astrophysics Data System (ADS)

    Gordon, T. D.; Presto, A. A.; May, A. A.; Nguyen, N. T.; Lipsky, E. M.; Donahue, N. M.; Gutierrez, A.; Zhang, M.; Maddox, C.; Rieger, P.; Chattopadhyay, S.; Maldonado, H.; Maricq, M. M.; Robinson, A. L.

    2014-05-01

    The effects of photochemical aging on emissions from 15 light-duty gasoline vehicles were investigated using a smog chamber to probe the critical link between the tailpipe and ambient atmosphere. The vehicles were recruited from the California in-use fleet; they represent a wide range of model years (1987 to 2011), vehicle types and emission control technologies. Each vehicle was tested on a chassis dynamometer using the unified cycle. Dilute emissions were sampled into a portable smog chamber and then photochemically aged under urban-like conditions. For every vehicle, substantial secondary organic aerosol (SOA) formation occurred during cold-start tests, with the emissions from some vehicles generating as much as 6 times the amount of SOA as primary particulate matter (PM) after 3 h of oxidation inside the chamber at typical atmospheric oxidant levels (and 5 times the amount of SOA as primary PM after 5 × 106 molecules cm-3 h of OH exposure). Therefore, the contribution of light-duty gasoline vehicle exhaust to ambient PM levels is likely dominated by secondary PM production (SOA and nitrate). Emissions from hot-start tests formed about a factor of 3-7 less SOA than cold-start tests. Therefore, catalyst warm-up appears to be an important factor in controlling SOA precursor emissions. The mass of SOA generated by photooxidizing exhaust from newer (LEV2) vehicles was a factor of 3 lower than that formed from exhaust emitted by older (pre-LEV) vehicles, despite much larger reductions (a factor of 11-15) in nonmethane organic gas emissions. These data suggest that a complex and nonlinear relationship exists between organic gas emissions and SOA formation, which is not surprising since SOA precursors are only one component of the exhaust. Except for the oldest (pre-LEV) vehicles, the SOA production could not be fully explained by the measured oxidation of speciated (traditional) SOA precursors. Over the timescale of these experiments, the mixture of organic vapors

  13. Secondary organic aerosol formation exceeds primary particulate matter emissions for light-duty gasoline vehicles

    NASA Astrophysics Data System (ADS)

    Gordon, T. D.; Presto, A. A.; May, A. A.; Nguyen, N. T.; Lipsky, E. M.; Donahue, N. M.; Gutierrez, A.; Zhang, M.; Maddox, C.; Rieger, P.; Chattopadhyay, S.; Maldonado, H.; Maricq, M. M.; Robinson, A. L.

    2013-09-01

    The effects of photochemical aging on emissions from 15 light-duty gasoline vehicles were investigated using a smog chamber to probe the critical link between the tailpipe and ambient atmosphere. The vehicles were recruited from the California in-use fleet; they represent a wide range of model years (1987 to 2011), vehicle types and emission control technologies. Each vehicle was tested on a chassis dynamometer using the unified cycle. Dilute emissions were sampled into a portable smog chamber and then photochemically aged under urban-like conditions. For every vehicle, substantial secondary organic aerosol (SOA) formation occurred during cold-start tests, with the emissions from some vehicles generating as much as 6 times the amount of SOA as primary particulate matter after three hours of oxidation inside the chamber at typical atmospheric oxidant levels. Therefore, the contribution of light duty gasoline vehicle exhaust to ambient PM levels is likely dominated by secondary PM production (SOA and nitrate). Emissions from hot-start tests formed about a factor of 3-7 less SOA than cold-start tests. Therefore, catalyst warm-up appears to be an important factor in controlling SOA precursor emissions. The mass of SOA generated by photo-oxidizing exhaust from newer (LEV1 and LEV2) vehicles was only modestly lower (38%) than that formed from exhaust emitted by older (pre-LEV) vehicles, despite much larger reductions in non-methane organic gas emissions. These data suggest that a complex and non-linear relationship exists between organic gas emissions and SOA formation, which is not surprising since SOA precursors are only one component of the exhaust. Except for the oldest (pre-LEV) vehicles, the SOA production could not be fully explained by the measured oxidation of speciated (traditional) SOA precursors. Over the time scale of these experiments, the mixture of organic vapors emitted by newer vehicles appear to be more efficient (higher yielding) in producing SOA than

  14. Efficient light emission from inorganic and organic semiconductor hybrid structures by energy-level tuning

    PubMed Central

    Schlesinger, R.; Bianchi, F.; Blumstengel, S.; Christodoulou, C.; Ovsyannikov, R.; Kobin, B.; Moudgil, K.; Barlow, S.; Hecht, S.; Marder, S.R.; Henneberger, F.; Koch, N.

    2015-01-01

    The fundamental limits of inorganic semiconductors for light emitting applications, such as holographic displays, biomedical imaging and ultrafast data processing and communication, might be overcome by hybridization with their organic counterparts, which feature enhanced frequency response and colour range. Innovative hybrid inorganic/organic structures exploit efficient electrical injection and high excitation density of inorganic semiconductors and subsequent energy transfer to the organic semiconductor, provided that the radiative emission yield is high. An inherent obstacle to that end is the unfavourable energy level offset at hybrid inorganic/organic structures, which rather facilitates charge transfer that quenches light emission. Here, we introduce a technologically relevant method to optimize the hybrid structure's energy levels, here comprising ZnO and a tailored ladder-type oligophenylene. The ZnO work function is substantially lowered with an organometallic donor monolayer, aligning the frontier levels of the inorganic and organic semiconductors. This increases the hybrid structure's radiative emission yield sevenfold, validating the relevance of our approach. PMID:25872919

  15. Efficient light emission from inorganic and organic semiconductor hybrid structures by energy-level tuning.

    PubMed

    Schlesinger, R; Bianchi, F; Blumstengel, S; Christodoulou, C; Ovsyannikov, R; Kobin, B; Moudgil, K; Barlow, S; Hecht, S; Marder, S R; Henneberger, F; Koch, N

    2015-04-15

    The fundamental limits of inorganic semiconductors for light emitting applications, such as holographic displays, biomedical imaging and ultrafast data processing and communication, might be overcome by hybridization with their organic counterparts, which feature enhanced frequency response and colour range. Innovative hybrid inorganic/organic structures exploit efficient electrical injection and high excitation density of inorganic semiconductors and subsequent energy transfer to the organic semiconductor, provided that the radiative emission yield is high. An inherent obstacle to that end is the unfavourable energy level offset at hybrid inorganic/organic structures, which rather facilitates charge transfer that quenches light emission. Here, we introduce a technologically relevant method to optimize the hybrid structure's energy levels, here comprising ZnO and a tailored ladder-type oligophenylene. The ZnO work function is substantially lowered with an organometallic donor monolayer, aligning the frontier levels of the inorganic and organic semiconductors. This increases the hybrid structure's radiative emission yield sevenfold, validating the relevance of our approach.

  16. Generation of VLF saucer emissions observed by the Viking satellite

    NASA Astrophysics Data System (ADS)

    Lonnqvist, H.; Andre, M.; Matson, L.; Bahnsen, A.; Blomberg, L. G.; Erlandson, R. E.

    1993-08-01

    Simultaneous observations by the Viking satellite of electric and magnetic fields as well as charged particles have been used to investigate V-shaped wave phenomena. The intensity of these VLF and ELF emissions is V-shaped when shown in a frequency versus time plot. Simultaneous observations of V-shaped so-called VLF saucer emissions, particles and field-aligned currents strongly suggest, for the first time, that upgoing electrons with energies less than a few hundred electron volts can generate these waves. Broadband waves observed inside the saucer generation region, from frequencies much less than the ion cyclotron frequency up to the plasma frequency, may also be generated by these electrons. Viking observations of VLF saucers at altitudes between 4000 km and 13,500 km show that these emissions occur at higher altitudes than discussed in previous reports. The generation regions seem to be more extended at these higher altitudes than what has been reported at lower altitudes by other observers.

  17. Possible Mg ii emission in B stars observed from Copernicus

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kondo, Y.; Modisette, J.L.; Dufour, R.J.

    1976-05-15

    Four B stars, ..cap alpha.. Vir, ..beta.. Cen, ..cap alpha.. Gru, and ..beta.. Lib, were observed with the Copernicus Princeton Telescope Spectrometer at a resolution of 0.1 A in order to investigate the presence of chromospheric emission. Emission was observed in ..beta.. Cen and ..cap alpha.. Gru, while the results for ..cap alpha.. Vir and ..beta.. Lib were inconclusive. (AIP)

  18. Probing Millisecond Pulsar Emission Geometry Using Light Curves From the Fermi Large Area Telescope

    NASA Technical Reports Server (NTRS)

    Venter, Christo; Harding, Alice; Guillemot, L.

    2009-01-01

    An interesting new high-energy pulsar sub-population is emerging following early discoveries of gamma-ray millisecond pulsars (MSPs) by the Fermi Large Area Telescope (LAT). We present results from 3D emission modeling, including the Special Relativistic effects of aberration and time-of-flight delays and also rotational sweepback of 13-field lines, in the geometric context of polar cap (PC), slot gap (SG), outer gap (OG), and two-pole caustic (TPC) pulsar models. In contrast to the general belief that these very old, rapidly-rotating neutron stars (NSs) should have largely pair-starved magnetospheres due to the absence of significant pair production, we find that most of the light curves are best fit by SG and OG models, which indicates the presence of narrow accelerating gaps limited by robust pair production -- even in these pulsars with very low spin-down luminosities. The gamma-ray pulse shapes and relative phase lags with respect to the radio pulses point to high-altitude emission being dominant for all geometries. We also find exclusive differentiation of the current gamma-ray MSP population into two MSP sub-classes: light curve shapes and lags across wavebands impose either pair-starved PC (PSPC) or SG / OG-type geometries. In the first case, the radio pulse has a small lag with respect to the single gamma-ray pulse, while the (first) gamma-ray peak usually trails the radio by a large phase offset in the latter case. Finally, we find that the flux correction factor as a function of magnetic inclination and observer angles is typically of order unity for all models. Our calculation of light curves and flux correction factor f(_, _, P) for the case of MSPs is therefore complementary to the "ATLAS paper" of Watters et al. for younger pulsars.

  19. 40 CFR 86.1815-01 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  20. 40 CFR 86.1813-01 - Emission standards for light-duty trucks 2.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  1. 40 CFR 86.1812-01 - Emission standards for light-duty trucks 1.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  2. 40 CFR 86.1815-02 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  3. 40 CFR 86.1813-01 - Emission standards for light-duty trucks 2.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  4. 40 CFR 86.1814-01 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  5. 40 CFR 86.1814-02 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  6. 40 CFR 86.1812-01 - Emission standards for light-duty trucks 1.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  7. 40 CFR 86.1815-01 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  8. 40 CFR 86.1815-01 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  9. 40 CFR 86.1814-01 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  10. 40 CFR 86.1813-01 - Emission standards for light-duty trucks 2.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  11. 40 CFR 86.1814-01 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  12. 40 CFR 86.1814-02 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  13. 40 CFR 86.1812-01 - Emission standards for light-duty trucks 1.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  14. 40 CFR 86.1815-02 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  15. 40 CFR 86.1814-02 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  16. 40 CFR 86.1814-01 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  17. 40 CFR 86.1812-01 - Emission standards for light-duty trucks 1.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  18. 40 CFR 86.1813-01 - Emission standards for light-duty trucks 2.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  19. 40 CFR 86.1815-02 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  20. 40 CFR 86.1814-02 - Emission standards for light-duty trucks 3.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  1. 40 CFR 86.1815-02 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. This... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  2. 40 CFR 86.1815-01 - Emission standards for light-duty trucks 4.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... equivalents and references to non-methane hydrocarbons shall mean non-methane hydrocarbon equivalents. (a... (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air Pollution From New and In-Use Light-Duty...

  3. Tunable light emission by exciplex state formation between hybrid halide perovskite and core/shell quantum dots: Implications in advanced LEDs and photovoltaics.

    PubMed

    Sanchez, Rafael S; de la Fuente, Mauricio Solis; Suarez, Isaac; Muñoz-Matutano, Guillermo; Martinez-Pastor, Juan P; Mora-Sero, Ivan

    2016-01-01

    We report the first observation of exciplex state electroluminescence due to carrier injection between the hybrid lead halide perovskite (MAPbI3-xClx) and quantum dots (core/shell PbS/CdS). Single layers of perovskite (PS) and quantum dots (QDs) have been produced by solution processing methods, and their photoluminescent properties are compared to those of bilayer samples in both PS/QD and QD/PS configurations. Exciplex emission at lower energies than the band gap of both PS and QD has been detected. The exciplex emission wavelength of this mixed system can be simply tuned by controlling the QD size. Light-emitting diodes (LEDs) have been fabricated using those configurations, which provide light emission with considerably low turn-on potential. The "color" of the LED can also be tuned by controlling the applied bias. The presence of the exciplex state PS and QDs opens up a broad range of possibilities with important implications not only in tunable LEDs but also in the preparation of intermediate band gap photovoltaic devices with the potentiality of surpassing the Shockley-Queisser limit.

  4. Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions.

    PubMed

    Zhang, Yanxu; Jacob, Daniel J; Horowitz, Hannah M; Chen, Long; Amos, Helen M; Krabbenhoft, David P; Slemr, Franz; St Louis, Vincent L; Sunderland, Elsie M

    2016-01-19

    Observations of elemental mercury (Hg(0)) at sites in North America and Europe show large decreases (∼ 1-2% y(-1)) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (<1% y(-1)). These decreases are inconsistent with current global emission inventories indicating flat or increasing emissions over that period. However, the inventories have three major flaws: (i) they do not account for the decline in atmospheric release of Hg from commercial products; (ii) they are biased in their estimate of artisanal and small-scale gold mining emissions; and (iii) they do not properly account for the change in Hg(0)/Hg(II) speciation of emissions from coal-fired utilities after implementation of emission controls targeted at SO2 and NOx. We construct an improved global emission inventory for the period 1990 to 2010 accounting for the above factors and find a 20% decrease in total Hg emissions and a 30% decrease in anthropogenic Hg(0) emissions, with much larger decreases in North America and Europe offsetting the effect of increasing emissions in Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg(0) concentrations and in Hg(II) wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO2 and NOx emission controls on coal-fired utilities.

  5. Application of highly ordered carbon nanotubes templates to field-emission organic light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Li, Chi-Shing; Su, Shui-Hsiang; Chi, Hsiang-Yu; Yokoyama, Meiso

    2009-01-01

    An anodic aluminum oxide (AAO) template was formed by a two-step anodization process. Carbon nanotubes (CNTs) were successfully synthesized along with AAO pores and the diameters of CNTs equaled those of AAO pores. The lengths of CNTs during a chemical vapor deposition synthesized process on the AAO template were effectively controlled. These AAO-CNTs exhibit excellent field emission with a low turn-on field (0.7 V/μm) and a low threshold field (1.4 V/μm). The field enhancement factor, calculated from the non-saturated region of the Fowler-Nordheim (F-N) plot, is about 8237. A novel field-emission organic light-emitting diode (FEOLED) combining AAO-CNTs cathodes as electron source with organic electroluminescent (EL) light-emitting layers coated on indium-tin-oxide (ITO) is produced. The uniform and dense luminescence image is obtained in the FEOLEDs. Organic EL light-emitting materials have lower working voltage than inorganic phosphor-coated fluorescent screens.

  6. Reported emissions of organic gases are not consistent with observations

    PubMed Central

    Henry, Ronald C.; Spiegelman, Clifford H.; Collins, John F.; Park, EunSug

    1997-01-01

    Regulatory agencies and photochemical models of ozone rely on self-reported industrial emission rates of organic gases. Incorrect self-reported emissions can severely impact on air quality models and regulatory decisions. We compared self-reported emissions of organic gases in Houston, Texas, to measurements at a receptor site near the Houston ship channel, a major petrochemical complex. We analyzed hourly observations of total nonmethane organic carbon and 54 hydrocarbon compounds from C-2 to C-9 for the period June through November, 1993. We were able to demonstrate severe inconsistencies between reported emissions and major sources as derived from the data using a multivariate receptor model. The composition and the location of the sources as deduced from the data are not consistent with the reported industrial emissions. On the other hand, our observationally based methods did correctly identify the location and composition of a relatively small nearby chemical plant. This paper provides strong empirical evidence that regulatory agencies and photochemical models are making predictions based on inaccurate industrial emissions. PMID:11038551

  7. Study of extreme-ultraviolet emission and properties of a coronal streamer from PROBA2/SWAP, HINODE/EIS and Mauna Loa Mk4 observations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goryaev, F.; Slemzin, V.; Vainshtein, L.

    2014-02-01

    Wide-field extreme-ultraviolet (EUV) telescopes imaging in spectral bands sensitive to 1 MK plasma on the Sun often observe extended, ray-like coronal structures stretching radially from active regions to distances of 1.5-2 R {sub ☉}, which represent the EUV counterparts of white-light streamers. To explain this phenomenon, we investigated the properties of a streamer observed on 2010 October 20 and 21, by the PROBA2/SWAP EUV telescope together with the Hinode/EIS (HOP 165) and the Mauna Loa Mk4 white-light coronagraph. In the SWAP 174 Å band comprising the Fe IX-Fe XI lines, the streamer was detected to a distance of 2 Rmore » {sub ☉}. We assume that the EUV emission is dominated by collisional excitation and resonant scattering of monochromatic radiation coming from the underlying corona. Below 1.2 R {sub ☉}, the plasma density and temperature were derived from the Hinode/EIS data by a line-ratio method. Plasma conditions in the streamer and in the background corona above 1.2 R {sub ☉} from the disk center were determined by forward-modeling the emission that best fit the observational data in both EUV and white light. It was found that the plasma in the streamer above 1.2 R {sub ☉} is nearly isothermal, with a temperature of T = 1.43 ± 0.08 MK. The hydrostatic scale-height temperature determined from the evaluated density distribution was significantly higher (1.72 ± 0.08 MK), which suggests the existence of outward plasma flow along the streamer. We conclude that, inside the streamer, collisional excitation provided more than 90% of the observed EUV emission, whereas, in the background corona, the contribution of resonance scattering became comparable with that of collisions at R ≳ 2 R {sub ☉}.« less

  8. IRTF/SPEX OBSERVATIONS OF THE UNUSUAL KEPLER LIGHT CURVE SYSTEM KIC 8462852

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lisse, C. M.; Sitko, M. L.; Marengo, M., E-mail: carey.lisse@jhuapl.edu

    2015-12-20

    We have utilized the NASA/IRTF 3 m SpeX instrument’s high-resolution spectral mode to observe and characterize the near-infrared flux emanating from the unusual Kepler light curve system KIC 8462852. By comparing the resulting 0.8–4.2 μm spectrum to a mesh of model photospheric spectra, the 6 emission line analyses of the Rayner et al. catalog, and the 25 system collections of debris disks we have observed to date using SpeX under the Near InfraRed Debris disk Survey, we have been able to additionally characterize the system. Within the errors of our measurements, this star looks like a normal solar abundance main-sequencemore » F1V to F3V dwarf star without any obvious traces of significant circumstellar dust or gas. Using Connelley and Greene’s emission measures, we also see no evidence of significant ongoing accretion onto the star nor any stellar outflow away from it. Our results are inconsistent with large amounts of static close-in obscuring material or the unusual behavior of a YSO system, but are consistent with the favored episodic giant comet models of a Gyr old stellar system favored by Boyajian et al. We speculate that KIC 8462852, like the ∼1.4 Gyr old F2V system η Corvi, is undergoing a late heavy bombardment, but is only in its very early stages.« less

  9. First Observation of Lion Roar Emission in Saturn's Magnetosheath

    NASA Astrophysics Data System (ADS)

    Píša, D.; Sulaiman, A. H.; Santolík, O.; Hospodarsky, G. B.; Kurth, W. S.; Gurnett, D. A.

    2018-01-01

    We present an observation of intense emissions in Saturn's magnetosheath as detected by the Cassini spacecraft. The emissions are observed in the dawn sector (magnetic local time ˜06:45) of the magnetosheath over a time period of 11 h before the spacecraft crossed the bow shock and entered the unshocked solar wind. They are found to be narrow-banded with a peak frequency of about 0.16 fce, where fce is the local electron gyrofrequency. Using plane wave propagation analysis, we show that the waves are right hand circularly polarized in the spacecraft frame and propagate at small wave normal angles (<10∘) with respect to the ambient magnetic field. Electromagnetic waves with the same properties known as "lion roars" have been reported by numerous missions in the terrestrial magnetosheath. Here we show the first evidence such emission outside the terrestrial environment. Our observations suggest that lion roars are a solar-system-wide phenomenon and capable of existing in a broad range of parameter space. This also includes 1 order of magnitude difference in frequencies. We anticipate our result to provide new insight into such emissions in a new parameter regime characterized by a higher plasma beta (owing to the substantially higher Mach number bow shock) compared to Earth.

  10. 40 CFR 86.1811-09 - Emission standards for light-duty vehicles, light-duty trucks and medium-duty passenger vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., except as noted. Additionally, this section applies to hybrid electric vehicles (HEVs) and zero emission... vehicles, light-duty trucks and medium-duty passenger vehicles. 86.1811-09 Section 86.1811-09 Protection of... AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) General Compliance Provisions for Control of Air...

  11. Pump-probe STM light emission spectroscopy for detection of photo-induced semiconductor-metal phase transition of VO2

    NASA Astrophysics Data System (ADS)

    Sakai, Joe; Katano, Satoshi; Kuwahara, Masashi; Uehara, Yoichi

    2017-10-01

    We attempted to observe pump-probe scanning tunneling microscopy (STM)-light emission (LE) from a VO2 thin film grown on a rutile TiO2(0 0 1) substrate, with an Ag tip fixed over a semiconducting domain. Laser pulses from a Ti:sapphire laser (wavelength 920 nm pulse width less than 1.5 ps) irradiated the tip-sample gap as pump and probe light sources. With a photon energy of 2.7 eV, suggesting phase transition from semiconducting monoclinic (M) to metallic rutile (R) phases in relation to the electronic band structure, faint LE was observed roughly 30 ps after the irradiation of the pump pulse, followed by retention for roughly 20 ps. The incident energy fluence of the pump pulse at the gap was five orders of magnitude lower than the threshold value for reported photo-induced M-R phase transition. The mechanism that makes it possible to reduce the threshold fluence is discussed.

  12. Pump-probe STM light emission spectroscopy for detection of photo-induced semiconductor-metal phase transition of VO2.

    PubMed

    Sakai, Joe; Katano, Satoshi; Kuwahara, Masashi; Uehara, Yoichi

    2017-10-11

    We attempted to observe pump-probe scanning tunneling microscopy (STM)-light emission (LE) from a VO 2 thin film grown on a rutile TiO 2 (0 0 1) substrate, with an Ag tip fixed over a semiconducting domain. Laser pulses from a Ti:sapphire laser (wavelength 920 nm; pulse width less than 1.5 ps) irradiated the tip-sample gap as pump and probe light sources. With a photon energy of 2.7 eV, suggesting phase transition from semiconducting monoclinic (M) to metallic rutile (R) phases in relation to the electronic band structure, faint LE was observed roughly 30 ps after the irradiation of the pump pulse, followed by retention for roughly 20 ps. The incident energy fluence of the pump pulse at the gap was five orders of magnitude lower than the threshold value for reported photo-induced M-R phase transition. The mechanism that makes it possible to reduce the threshold fluence is discussed.

  13. A rapid excitation-emission matrix fluorometer utilizing supercontinuum white light and acousto-optic tunable filters

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Wenbo; Department of Dermatology and Skin Science, University of British Columbia, 835 West 10th Avenue, Vancouver, British Columbia V5Z 4E8; Department of Biomedical Engineering, University of British Columbia, KAIS 5500, 2332 Main Mall, Vancouver, British Columbia V6T 1Z4

    Scanning speed and coupling efficiency of excitation light to optic fibres are two major technical challenges that limit the potential of fluorescence excitation-emission matrix (EEM) spectrometer for on-line applications and in vivo studies. In this paper, a novel EEM system, utilizing a supercontinuum white light source and acousto-optic tunable filters (AOTFs), was introduced and evaluated. The supercontinuum white light, generated by pumping a nonlinear photonic crystal fiber with an 800 nm femtosecond laser, was efficiently coupled into a bifurcated optic fiber bundle. High speed EEM spectral scanning was achieved using AOTFs both for selecting excitation wavelength and scanning emission spectra.more » Using calibration lamps (neon and mercury argon), wavelength deviations were determined to vary from 0.18 nm to −0.70 nm within the spectral range of 500–850 nm. Spectral bandwidth for filtered excitation light broadened by twofold compared to that measured with monochromatic light between 650 nm and 750 nm. The EEM spectra for methanol solutions of laser dyes were successfully acquired with this rapid fluorometer using an integration time of 5 s.« less

  14. Thermal-infrared spectral observations of geologic materials in emission

    NASA Technical Reports Server (NTRS)

    Christensen, Philip R.; Luth, Sharon J.

    1987-01-01

    The thermal-infrared spectra of geologic materials in emission were studied using the prototype Thermal Emission Spectrometer (TES). A variety of of processes and surface modifications that may influence or alter the spectra of primary rock materials were studied. It was confirmed that thermal emission spectra contain the same absorption features as those observed in transmission and reflection spectra. It was confirmed that the TES instrument can be used to obtain relevant spectra for analysis of rock and mineral composition.

  15. Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

    PubMed Central

    Zhang, Yanxu; Jacob, Daniel J.; Horowitz, Hannah M.; Chen, Long; Amos, Helen M.; Krabbenhoft, David P.; Slemr, Franz; St. Louis, Vincent L.; Sunderland, Elsie M.

    2016-01-01

    Observations of elemental mercury (Hg0) at sites in North America and Europe show large decreases (∼1–2% y−1) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (<1% y−1). These decreases are inconsistent with current global emission inventories indicating flat or increasing emissions over that period. However, the inventories have three major flaws: (i) they do not account for the decline in atmospheric release of Hg from commercial products; (ii) they are biased in their estimate of artisanal and small-scale gold mining emissions; and (iii) they do not properly account for the change in Hg0/HgII speciation of emissions from coal-fired utilities after implementation of emission controls targeted at SO2 and NOx. We construct an improved global emission inventory for the period 1990 to 2010 accounting for the above factors and find a 20% decrease in total Hg emissions and a 30% decrease in anthropogenic Hg0 emissions, with much larger decreases in North America and Europe offsetting the effect of increasing emissions in Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg0 concentrations and in HgII wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO2 and NOx emission controls on coal-fired utilities. PMID:26729866

  16. Observation of the Rabi oscillation of light driven by an atomic spin wave.

    PubMed

    Chen, L Q; Zhang, Guo-Wan; Bian, Cheng-Ling; Yuan, Chun-Hua; Ou, Z Y; Zhang, Weiping

    2010-09-24

    Coherent conversion between a Raman pump field and its Stokes field is observed in a Raman process with a strong atomic spin wave initially prepared by another Raman process operated in the stimulated emission regime. The oscillatory behavior resembles the Rabi oscillation in atomic population in a two-level atomic system driven by a strong light field. The Rabi-like oscillation frequency is found to be related to the strength of the prebuilt atomic spin wave. High conversion efficiency of 40% from the Raman pump field to the Stokes field is recorded and it is independent of the input Raman pump field. This process can act as a photon frequency multiplexer and may find wide applications in quantum information science.

  17. NOx Emissions from Diesel Passenger Cars Worsen with Age.

    PubMed

    Chen, Yuche; Borken-Kleefeld, Jens

    2016-04-05

    Commonly, the NOx emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NOx unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NOx emissions from all cars and light commercial vehicles in European emission inventories increase by 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. We suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.

  18. Seasonal variations of isoprene emissions from deciduous trees

    NASA Astrophysics Data System (ADS)

    Xiaoshan, Zhang; Yujing, Mu; Wenzhi, Song; Yahui, Zhuang

    Isoprene emission fluxes were investigated for 12 tree species in and around Beijing city. Bag-enclosure method was used to collect the air sample and GC-PID was used to directly analyze isoprene. Ginkgo and Magnolia denudata had negligible isoprene emissions, while significant emissions were observed for Platanus orientalis, Pendula loud, Populus simonii, and Salix matsudana koidz, and other remaining trees showed no sign of isoprene emission. Variations in isoprene emission with changes in light, temperature and season were investigated for Platanus orientalis and Pendula loud. Isoprene emission rates strongly depended on light, temperature and leaf age. The maximum emission rates for the two trees were observed in summer with values of about 232 and 213 μg g -1 dw h -1, respectively. The measured emission fluxes were used to evaluate "Guenther" emission algorithm. The emission fluxes predicted by the algorithm were in relatively good agreement with field measurements. However, there were large differences for the calculated median emission factors during spring, summer and fall. The 25-75 percentiles span of the emission factor data sets ranged from -33 to +15% of the median values.

  19. Pulsar Emission: Is It All Relative?

    NASA Technical Reports Server (NTRS)

    Harding, Alice K.

    2004-01-01

    Thirty-five years after the discovery of pulsars, we still do not understand the fundamentals of their pulsed emission at any wavelength. The fact that even detailed pulse profiles cannot identlfy the origin of the emission in a magnetosphere that extends fiom the neutron star surface to plasma moving at relativistic speeds near the light cylinder compounds the problem. I will discuss the role of special and general relativistic effects on pulsar emission, fiom inertial frame-dragging near the stellar surface to aberration, time-of-flight and retardation of the magnetic field near the light cylinder. Understanding how these effects determine what we observe at different wavelengths is critical to unraveling the emission physics.

  20. Evaluating Urban Methane Emissions with a Light Rail Vehicle Platform in Salt Lake City, UT

    NASA Astrophysics Data System (ADS)

    Mitchell, L.; Fasoli, B.; Crosman, E.; Lin, J. C.; Bowling, D. R.; Ehleringer, J. R.

    2016-12-01

    Urban environments are characterized by both spatial complexity and temporal variability, each of which present challenges for measurement strategies aimed at constraining estimates of greenhouse gas emissions and air quality. To address these challenges we initiated a project in December 2014 to measure trace species (CO2, CH4, O3, and Particulate Matter) by way of a Utah Transit Authority (UTA) electricity-powered light rail vehicle whose route traverses the metropolitan Salt Lake Valley in Utah, USA on an hourly basis, retracing the same route through commercial, residential, suburban, and rural typologies. Light rail vehicles present advantages as a measurement platform, including the absence of in-situ fossil fuel emissions, regular repeated transects across an urban region that provide both spatial and temporal information, and relatively low operating costs. We will present initial results investigating methane point sources and evaluating the magnitude and temporal characteristics of these emissions.

  1. Characteristics of on-road NOx emissions from Euro 6 light-duty diesel vehicles using a portable emissions measurement system.

    PubMed

    Kwon, Sangil; Park, Yonghee; Park, Junhong; Kim, Jeongsoo; Choi, Kwang-Ho; Cha, Jun-Seok

    2017-01-15

    This paper presents the on-road nitrogen oxides (NO x ) emissions measurements from Euro 6 light-duty diesel vehicles using a portable emissions measurement system on the predesigned test routes in the metropolitan area of Seoul, Korea. Six diesel vehicles were tested and the NO x emissions results were analyzed according to the driving routes, driving conditions, data analysis methods, and ambient temperatures. Total NO x emissions for route 1, which has higher driving severity than route 2, differed by -4-60% from those for route 2. The NO x emissions when the air conditioner (AC) was used were higher by 68% and 85%, on average, for routes 1 and 2, respectively, compared to when the AC was not used. The analytical results for NO x emissions by the moving averaging window method were higher by 2-31% compared to the power binning method. NO x emissions at lower ambient temperatures (0-5°C) were higher by 82-192% compared to those at higher ambient temperatures (15-20°C). This result shows that performance improvements of exhaust gas recirculation and the NO x after-treatment system will be needed at lower ambient temperatures. Copyright © 2016 Elsevier B.V. All rights reserved.

  2. Evolution of chorus emissions into plasmaspheric hiss observed by Van Allen Probes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhou, Qinghua; Xiao, Fuliang; Yang, Chang

    The two classes of whistler mode waves (chorus and hiss) play different roles in the dynamics of radiation belt energetic electrons. Chorus can efficiently accelerate energetic electrons, and hiss is responsible for the loss of energetic electrons. Previous studies have proposed that chorus is the source of plasmaspheric hiss, but this still requires an observational confirmation because the previously observed chorus and hiss emissions were not in the same frequency range in the same time. In this paper, we report simultaneous observations form Van Allen Probes that chorus and hiss emissions occurred in the same range ~300–1500 Hz with themore » peak wave power density about 10 -5 nT 2/Hz during a weak storm on 3 July 2014. Chorus emissions propagate in a broad region outside the plasmapause. Meanwhile, hiss emissions are confined inside the plasmasphere, with a higher intensity and a broader area at a lower frequency. A sum of bi-Maxwellian distribution is used to model the observed anisotropic electron distributions and to evaluate the instability of waves. A three-dimensional ray tracing simulation shows that a portion of chorus emission outside the plasmasphere can propagate into the plasmasphere and evolve into plasmaspheric hiss. Moreover, hiss waves below 1 kHz are more intense and propagate over a broader area than those above 1 kHz, consistent with the observation. Finally, the current results can explain distributions of the observed hiss emission and provide a further support for the mechanism of evolution of chorus into hiss emissions.« less

  3. Evolution of chorus emissions into plasmaspheric hiss observed by Van Allen Probes

    DOE PAGES

    Zhou, Qinghua; Xiao, Fuliang; Yang, Chang; ...

    2016-05-09

    The two classes of whistler mode waves (chorus and hiss) play different roles in the dynamics of radiation belt energetic electrons. Chorus can efficiently accelerate energetic electrons, and hiss is responsible for the loss of energetic electrons. Previous studies have proposed that chorus is the source of plasmaspheric hiss, but this still requires an observational confirmation because the previously observed chorus and hiss emissions were not in the same frequency range in the same time. In this paper, we report simultaneous observations form Van Allen Probes that chorus and hiss emissions occurred in the same range ~300–1500 Hz with themore » peak wave power density about 10 -5 nT 2/Hz during a weak storm on 3 July 2014. Chorus emissions propagate in a broad region outside the plasmapause. Meanwhile, hiss emissions are confined inside the plasmasphere, with a higher intensity and a broader area at a lower frequency. A sum of bi-Maxwellian distribution is used to model the observed anisotropic electron distributions and to evaluate the instability of waves. A three-dimensional ray tracing simulation shows that a portion of chorus emission outside the plasmasphere can propagate into the plasmasphere and evolve into plasmaspheric hiss. Moreover, hiss waves below 1 kHz are more intense and propagate over a broader area than those above 1 kHz, consistent with the observation. Finally, the current results can explain distributions of the observed hiss emission and provide a further support for the mechanism of evolution of chorus into hiss emissions.« less

  4. Automatic detection of white-light flare kernels in SDO/HMI intensitygrams

    NASA Astrophysics Data System (ADS)

    Mravcová, Lucia; Švanda, Michal

    2017-11-01

    Solar flares with a broadband emission in the white-light range of the electromagnetic spectrum belong to most enigmatic phenomena on the Sun. The origin of the white-light emission is not entirely understood. We aim to systematically study the visible-light emission connected to solar flares in SDO/HMI observations. We developed a code for automatic detection of kernels of flares with HMI intensity brightenings and study properties of detected candidates. The code was tuned and tested and with a little effort, it could be applied to any suitable data set. By studying a few flare examples, we found indication that HMI intensity brightening might be an artefact of the simplified procedure used to compute HMI observables.

  5. Observing the Plasma-Physical Processes of Pulsar Radio Emission with Arecibo

    NASA Astrophysics Data System (ADS)

    Rankin, Joanna M.

    2017-01-01

    With their enormous densities and fields, neutron stars entail some of the most exotic physics in the cosmos. Similarly, the physical mechanisms of pulsar radio emission are no less exotic, and we are only now beginning to understand them. The talk will provide an introduction to the phenomenology of radio pulsar emission and focus on those aspects of the exquisite Arecibo observations that bear on their challenging emission physics.The commonalities of the radio beamforms of most slow pulsars (and some millisecond pulsars) argue strongly that their magnetic fields have a nearly dipolar structure at the height of their radio emission regions. These heights can often be determined by aberration/retardation analyses. Similarly, measurement of the orientation of the polarized radio emission with respect to the emitting magnetic field facilitates identification of the physical(X/O) emission modes and study of the plasma coupling to the electromagnetic radiation.While the physics of primary plasma generation above the pulsar polar cap is only beginning to be understood, it is clear that the radio pulsars we see are able to generate copious amounts of electron-positron plasma in their emission regions. Within the nearly dipolar field structure of these emission regions, the plasma density is near to that of the Goldreich-Julian model, and so the physical conditions in these regions can be accurately estimated.These conditions show that the plasma frequencies in the emission regions are much higher than the frequency of the emitted radiation, such that the plasma couples most easily to the extraordinary mode as observed. Therefore, the only surviving emission mechanism is curvature radiation from charged solitons, produced by the two-stream instability. Such soliton emission has probably been observed directly in the Crab pulsar; however, a physical theory of charged soliton radiation does not yet exist.

  6. The First Hours of the GW170817 Kilonova and the Importance of Early Optical and Ultraviolet Observations for Constraining Emission Models

    NASA Astrophysics Data System (ADS)

    Arcavi, Iair

    2018-03-01

    The kilonova associated with GW170817 displayed early blue emission, which has been interpreted as a signature of either radioactive decay in low-opacity ejecta, relativistic boosting of radioactive decay in high-velocity ejecta, the cooling of material heated by a wind or by a “cocoon” surrounding a jet, or a combination thereof. Distinguishing between these mechanisms is important for constraining the ejecta components and their parameters, which tie directly into the physics we can learn from these events. I compile published ultraviolet, optical, and infrared light curves of the GW170817 kilonova and examine whether the combined data set can be used to distinguish between early-emission models. The combined optical data show an early rise consistent with radioactive decay of low-opacity ejecta as the main emission source, but the subsequent decline is fit well by all models. A lack of constraints on the ultraviolet flux during the first few hours after discovery allows for both radioactive decay and other cooling mechanisms to explain the early bolometric light curve. This analysis demonstrates that early (few hours after merger) high-cadence optical and ultraviolet observations will be critical for determining the source of blue emission in future kilonovae.

  7. Plasmon effects in light scalar and pseudo-scalar emission from a supernova.

    NASA Astrophysics Data System (ADS)

    Altherr, T.

    1991-05-01

    The emission of light scalars and pseudo-scalars (axion-like particles) coupled to the chromo/electric field from a QCD/AED plasma at high temperature and very high density is studied in detail. The calculation is then applied to the SN 1987A event for which new bounds on the Peccei-Quinn symmetry breaking scale fa are derived, fa ⪆ 3×109GeV in presence of a quark-gluon core and fa ⪆ 107GeV, which is the same bound as the one obtained from red giant stars, by considering axion emission from the electron gas.

  8. New method for determining temperature and emission measure during solar flares from light curves of soft X-ray line fluxes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bornmann, P.L.

    I describe a new property of soft X-ray line fluxes observed during the decay phase of solar flares and a technique for using this property to determine the plasma temperature and emission measure as functions of time. The soft X-ray line fluxes analyzed in this paper were observed during the decay phase of the 1980 November 5 flare by the X-Ray Polychromator (XRP) instrument on board the Solar Maximum Mission (SMM). The resonance, intercombination, and forbidden lines of Ne IX, Mg XI, Si XIII, S XV, Ca XIX, and Fe XXV, as well as the Lyman-..cap alpha.. line of Omore » VIII and the resonance lines of Fe XIX, were observed. The rates at which the observed line fluxes decayed were not constant. For all but the highest temperature lines observed, the rate changed abruptly, causing the fluxes to fall at a more rapid rate later in the flare decay. These changes occurred at earlier times for lines formed at higher temperatures. This behavior is proposed to be due to the decreasing temperature of the flare plasma tracking the rise and subsequent fall of each line emissivity function. This explanation is used to empirically model the observed light curves and to estimate the temperature and the change in emission measure of the plasma as a function of time during the decay phase. Estimates are made of various plasma parameters based on the model results.« less

  9. Markovian and non-Markovian light-emission channels in strained quantum wires.

    PubMed

    Lopez-Richard, V; González, J C; Matinaga, F M; Trallero-Giner, C; Ribeiro, E; Sousa Dias, M Rebello; Villegas-Lelovsky, L; Marques, G E

    2009-09-01

    We have achieved conditions to obtain optical memory effects in semiconductor nanostructures. The system is based on strained InP quantum wires where the tuning of the heavy-light valence band splitting has allowed the existence of two independent optical channels with correlated and uncorrelated excitation and light-emission processes. The presence of an optical channel that preserves the excitation memory is unambiguously corroborated by photoluminescence measurements of free-standing quantum wires under different configurations of the incoming and outgoing light polarizations in various samples. High-resolution transmission electron microscopy and electron diffraction indicate the presence of strain effects in the optical response. By using this effect and under certain growth conditions, we have shown that the optical recombination is mediated by relaxation processes with different natures: one a Markov and another with a non-Markovian signature. Resonance intersubband light-heavy hole transitions assisted by optical phonons provide the desired mechanism for the correlated non-Markovian carrier relaxation process. A multiband calculation for strained InP quantum wires was developed to account for the description of the character of the valence band states and gives quantitative support for light hole-heavy hole transitions assisted by optical phonons.

  10. A white-light /Fe X/H-alpha coronal transient observation to 10 solar radii

    NASA Technical Reports Server (NTRS)

    Wagner, W. J.; Illing, R. M. E.; Sawyer, C. B.; House, L. L.; Sheeley, N. R., Jr.; Howard, R. A.; Koomen, M. J.; Michels, D. J.; Smartt, R. N.; Dryer, M.

    1983-01-01

    Multitelescope observations of the coronal transient of April 15-16, 1980 provide simultaneous data from the Solar Maximum Mission Coronagraph/Polarimeter, the Solwind Coronagraph, and the new Emission line Coronagraph of the Sacramento Peak Observatory. An eruptive prominence-associated white light transient is for the first time seen as an unusual wave or brightening in Fe X 6374 A (but not in Fe XIV 5303 A). Several interpretations of this fleeting enhancement are offered. The prominence shows a slowly increasing acceleration which peaks at the time of the Fe event. The white light loop transient surrounding the prominence expands at a well-documented constant speed to solar radii, with an extrapolated start time at zero height coincident with the surface activity. This loop transient exemplifies those seen above 1.7 solar radii, in that leading the disturbance is a bright N(e)-enhanced) loop rather than a dark one. This is consistent with a report of the behavior of another eruptive event observed by Fisher and Poland (1981) which began as a density depletion in the lower corona, with a bright loop forming at greater altitudes. The top of the bright loop ultimately fades in the outer corona while slow radial growth continues in the legs.

  11. In-situ stressing of rock: Observation of infrared emission prior to failure

    NASA Astrophysics Data System (ADS)

    Dahlgren, R.; Freund, F. T.; Momayez, M.; Bleier, T. E.; Dunson, C.; Joggerst, P.; Jones, K.; Wang, S.

    2009-12-01

    Blocks of igneous rocks such as anorthosite and granite subjected at one end to uniaxial stress have been shown to emit a small but distinct excess amount of infrared (IR) light (Freund, F. T., et al, JASTP, 71, 2009). This anomalous IR emission arises from the radiative de-excitation of electron vacancy defects, which, upon stress-activation, flow into the unstressed portion and recombine at the surface. This non-thermal IR emission occurs in the 8 μm to 14 μm wavelength region. Field experiments are performed by slowly stressing large boulders and monitoring the IR emission in situ with a Bruker EM27 Fourier Transform Infrared (FTIR) spectrometer. The boulders are prepared by drilling four blind holes into the rock, 50-100 cm deep, in an array roughly parallel to, and behind, the surface from where the IR emission is monitored. Any debris and water is blown out of the boreholes with compressed air, and the rock is given time to dry and relax from drilling-induced stresses. The holes are then filled with grout that expands upon curing, creating an increasing radial pressure of up to 5 × 103 t/m2. The experiments were carried out with two large granite boulders, one of about 30 t of hard (over 150 MPa) granite at the University of Arizona’s Henry "Hank" Grunstedt San Xavier Mining Laboratory, located in the copper mining district near Tucson, AZ and the other of about 7 t of weathered granite in the Sierra Nevada foothills near Oakhurst, CA. The Bruker EM27 FTIR spectrometer equipped with a 20 cm reflective telescope collects the IR emission from a safe distance at a rate of a full 4-16 µm spectrum every 30 sec. After recording baseline data, the grout was mixed with water and poured into the holes as IR emission was monitored continuously until the experiment was terminated after rock failure. The time of failure is noted whenever the first acoustic or visual cues are sensed from the boulder. The IR data shows that after a period of quiescence, pronounced

  12. Electronic Two-Transition-Induced Enhancement of Emission Efficiency in Polymer Light-Emitting Diodes

    PubMed Central

    Chen, Ren-Ai; Wang, Cong; Li, Sheng; George, Thomas F.

    2013-01-01

    With the development of experimental techniques, effective injection and transportation of electrons is proven as a way to obtain polymer light-emitting diodes (PLEDs) with high quantum efficiency. This paper reveals a valid mechanism for the enhancement of quantum efficiency in PLEDs. When an external electric field is applied, the interaction between a negative polaron and triplet exciton leads to an electronic two-transition process, which induces the exciton to emit light and thus improve the emission efficiency of PLEDs. PMID:28809346

  13. Observation of hectometric auroral radio emissions in Iceland

    NASA Astrophysics Data System (ADS)

    Sato, Y.; Ono, T.; Iizima, M.; Sato, N.

    2006-12-01

    The Earth's auroral region is an active radio source at frequencies from a few hertz to several megahertz. In the hectometric range, it was found that Terrestrial Hectometric Radiation (THR) is related to auroras by observations of the Ohzora satellite [Oya et al.(1985)]. In resent research, Shinbori et al. [2003] showed that occurrence of THR follows SC by several minutes using the Akebono satellite data. On the ground, auroral roar and MF burst were discovered by Kellogg and Monson [1979, 1984] and Weatherwax et al. [1994] in the northern Canada, respectively. Because there is not enough physical and geophysical characterization of these radio emissions, the physical mechanism of these phenomena in the auroral ionosphere has not been fully understood yet. We set up new observation system at Husafell station in Iceland in September, 2005 and have started to observe auroral radio emissions. Radio signals, which are received by the cross loop antennas, are converted into left- and right- handed polarized components within the frequency range from 1 MHz to 5 MHz. Based on the calibration of system, it was found that the possibility of occurence would be smaller than expected due to the low sensitivity because average power spectrum densities of auroral roar and MF burst are 50-100 nV/m/Hz^1/2. So, the system was planed to be upgraded in this September, which makes it possible to detect auroral roar and MF burst. It is expected that the detail physical process will be elucidated by clarifying the spectrum, polarization, dependence on the geomagnetic activity, and so on. In this presentation, we will show the improved points of the new system and preliminary observation results. There is a basic question whether auroral roar and MF burst observed on the ground are generated by the same process as THR observed by satellites. By comparing the results from the ground-based observation and the Akebono satellite observation of THR, it becomes possible to obtain a new

  14. Light-duty vehicle PM and VOC speciated emissions at differing ambient temperatues with ethanol blend gasoline

    EPA Science Inventory

    With the rise in the use of ethanol-blend gasoline in the U.S., interest is increasing in how these fuel blends affect PM and VOC emissions. EPA conducted a study characterizing emissions from two flex-fuel and one non-flex-fueled light-duty vehicles operated on a chassis dynamom...

  15. Short-term observations of double-peaked Na emission from Mercury's exosphere

    NASA Astrophysics Data System (ADS)

    Massetti, S.; Mangano, V.; Milillo, A.; Mura, A.; Orsini, S.; Plainaki, C.

    2017-04-01

    We report the analysis of short-term ground-based observations of the exospheric Na emission (D1 and D2 lines) from Mercury, which was characterized by two high-latitude peaks confined near the magnetospheric cusp footprints. During a series of scheduled observations from the Télescope Héliographique pour l'Etude du Magnétisme et des Instabilités Solaires (THEMIS) telescope, achieved by scanning the whole planet, we implemented a series of extra measurements by recording the Na emission from a narrow north-south strip only, centered above the two emission peaks. Our aim was to inspect the existence of short-term variations, which were never analyzed before from ground-based observations, and their possible correlation with interplanetary magnetic field variations. Though Mercury possesses a miniature magnetosphere, characterized by fast reconnection events that develop on a timescale of few minutes, ground-based observations show that the exospheric Na emission pattern can be globally stable for a prolonged period (some days) and also exhibits fluctuations in the time range of tens of minutes.

  16. The HST Frontier Field MACS 1159.5+2223: Flanking Observations for Intracluster Light

    NASA Astrophysics Data System (ADS)

    Gonzalez, Anthony

    2017-08-01

    We propose a 6 orbit WFC3/IR imaging program targeting the environs of the HST Frontier Field cluster MACS 1149.5+2223 to obtain a comprehensive view of the intracluster stellar population in a massive galaxy cluster. WFC3/IR enables a vast improvement over ground-based studies in mapping emission from diffuse stellar populations. Our proposed observations are designed to build upon the existing investment in the Frontier Fields to conduct a new, more complete census of the intracluster light (ICL) extending out to 750 kpc. The requested observations are constructed to span the gap between the primary and parallel HFF pointings, detecting ICL to a surface brightness of 29.5 mag per square arcsec in F160W (equivalent to 31.5 mag per square arcsec in V-band). This depth is sufficient to trace the radial ICL profile out to 750 kpc from the BCG. These data will also yield a high-fidelity calibration of the background sky level, enabling two-dimensional mapping of the distribution and color of intracluster light down to 27 mag per square arcsec in F160W. From these maps we will quantify spatial variation in the ratio of the stellar baryons to the ICM, establishing whether the observed low scatter in the global ratio masks underlying smaller scale inhomogeneities due to astrophysical processes in the cluster. The requested observations further serve as a pilot program, enabling future similar analyses with the full ensemble of HFF clusters, and developing techniques that will be required for such low surface brightness programs with upcoming facilities including Euclid and WFIRST.

  17. KVN observations reveal multiple γ-ray emission regions in 3C 84?

    NASA Astrophysics Data System (ADS)

    Hodgson, Jeffrey A.; Rani, Bindu; Lee, Sang-Sung; Algaba, Juan Carlos; Kino, Motoki; Trippe, Sascha; Park, Jong-Ho; Zhao, Guang-Yao; Byun, Do-Young; Kang, Sincheol; Kim, Jae-Young; Kim, Jeong-Sook; Kim, Soon-Wook; Miyazaki, Atsushi; Wajima, Kiyoaki; Oh, Junghwan; Kim, Dae-won; Gurwell, Mark

    2018-03-01

    3C 84 (NGC 1275) is a well-studied misaligned sctive galactic nucleus (AGN), which has been active in γ-rays since at least 2008. We have monitored the source at four wavelengths (14, 7, 3, and 2 mm) using the Korean VLBI network (KVN) since 2013 as part of the interferometric monitoring of γ-ray bright AGN (iMOGABA) programme, and it exhibits bright radio emission both near the central SMBH and in a slowly moving feature located to the south known as C3. Other facilities have also detected these short-term variations above a slowly rising trend at shorter wavelengths, such as in γ-ray and 1-mm total intensity light curves. We find that the variations in the γ-rays and 1-mm total intensity light curves are correlated, with the γ-ray leading and lagging the radio emission. Analysis of the 2-mm KVN data shows that both the γ-rays and 1-mm total intensity short-term variations are better correlated with the SMBH region than C3, likely placing the short-term variations in C1. We interpret the emission as being due to the random alignment of spatially separated emission regions. We place the slowly rising trend in C3, consistent with previous results. Spectral analysis of the γ-ray data shows that the γ-ray flaring is inconsistent with blazar-like γ-ray emission. Additionally, we report that since mid-2015, a large mm-wave radio flare has been occurring in C3, with a large γ-ray flare coincident with the onset of this flare at all radio wavelengths.

  18. Modeled and observed ozone sensitivity to mobile-source emissions in Mexico City

    NASA Astrophysics Data System (ADS)

    Zavala, M.; Lei, W.; Molina, M. J.; Molina, L. T.

    2009-01-01

    The emission characteristics of mobile sources in the Mexico City Metropolitan Area (MCMA) have changed significantly over the past few decades in response to emission control policies, advancements in vehicle technologies and improvements in fuel quality, among others. Along with these changes, concurrent non-linear changes in photochemical levels and criteria pollutants have been observed, providing a unique opportunity to understand the effects of perturbations of mobile emission levels on the photochemistry in the region using observational and modeling approaches. The observed historical trends of ozone (O3), carbon monoxide (CO) and nitrogen oxides (NOx) suggest that ozone production in the MCMA has changed from a low to a high VOC-sensitive regime over a period of 20 years. Comparison of the historical emission trends of CO, NOx and hydrocarbons derived from mobile-source emission studies in the MCMA from 1991 to 2006 with the trends of the concentrations of CO, NOx, and the CO/NOx ratio during peak traffic hours also indicates that fuel-based fleet average emission factors have significantly decreased for CO and VOCs during this period whereas NOx emission factors do not show any strong trend, effectively reducing the ambient VOC/NOx ratio. This study presents the results of model analyses on the sensitivity of the observed ozone levels to the estimated historical changes in its precursors. The model sensitivity analyses used a well-validated base case simulation of a high pollution episode in the MCMA with the mathematical Decoupled Direct Method (DDM) and the standard Brute Force Method (BFM) in the 3-D CAMx chemical transport model. The model reproduces adequately the observed historical trends and current photochemical levels. Comparison of the BFM and the DDM sensitivity techniques indicates that the model yields ozone values that increase linearly with NOx emission reductions and decrease linearly with VOC emission reductions only up to 30% from the

  19. Modeled and observed ozone sensitivity to mobile-source emissions in Mexico City

    NASA Astrophysics Data System (ADS)

    Zavala, M.; Lei, W. F.; Molina, M. J.; Molina, L. T.

    2008-08-01

    The emission characteristics of mobile sources in the Mexico City Metropolitan Area (MCMA) have changed significantly over the past few decades in response to emission control policies, advancements in vehicle technologies and improvements in fuel quality, among others. Along with these changes, concurrent non-linear changes in photochemical levels and criteria pollutants have been observed, providing a unique opportunity to understand the effects of perturbations of mobile emission levels on the photochemistry in the region using observational and modeling approaches. The observed historical trends of ozone (O3), carbon monoxide (CO) and nitrogen oxides (NOx) suggest that ozone production in the MCMA has changed from a low to a high VOC-sensitive regime over a period of 20 years. Comparison of the historical emission trends of CO, NOx and hydrocarbons derived from mobile-source emission studies in the MCMA from 1991 to 2006 with the trends of the concentrations of CO, NOx, and the CO/NOx ratio during peak traffic hours also indicates that fuel-based fleet average emission factors have significantly decreased for CO and VOCs during this period whereas NOx emission factors do not show any strong trend, effectively reducing the ambient VOC/NOx ratio. This study presents the results of model analyses on the sensitivity of the observed ozone levels to the estimated historical changes in its precursors. The model sensitivity analyses used a well-validated base case simulation of a high pollution episode in the MCMA with the mathematical Decoupled Direct Method (DDM) and the standard Brute Force Method (BFM) in the 3-D CAMx chemical transport model. The model reproduces adequately the observed historical trends and current photochemical levels. Comparison of the BFM and the DDM sensitivity techniques indicates that the model yields ozone values that increase linearly with NOx emission reductions and decrease linearly with VOC emission reductions only up to 30% from the

  20. Galactic water vapor emission: further observations of variability.

    PubMed

    Knowles, S H; Mayer, C H; Sullivan, W T; Cheung, A C

    1969-10-10

    Recent observations of the 1.35-centimeter line emission of water vapor from galactic sources show short-term variability in the spectra of several sources. Two additional sources, Cygnus 1 and NGC 6334N, have been observed, and the spectra of W49 and VY Canis Majoris were measured over a wider range of radial velocity.

  1. Electron Emission Observations from As-Grown and Vacuum-Coated Chemical Vapor Deposited Diamond

    NASA Technical Reports Server (NTRS)

    Lamouri, A.; Wang, Yaxin; Mearini, G. T.; Krainsky, I. L.; Dayton, J. A., Jr.; Mueller,W.

    1996-01-01

    Field emission has been observed from chemical vapor deposited diamond grown on Mo and Si substrates. Emission was observed at fields as low as 20 kV/cm. The samples were tested in the as-grown form, and after coating with thin films of Au, CsI, and Ni. The emission current was typically maximum at the onset of the applied field, but was unstable, and decreased rapidly with time from the as-grown films. Thin Au layers, approximately 15 nm thick, vacuum deposited onto the diamond samples significantly improved the stability of the emission current at values approximately equal to those from uncoated samples at the onset of the applied field. Thin layers of CsI, approximately 5 nm thick, were also observed to improve the stability of the emission current but at values less than those from the uncoated samples at the onset of the applied field. While Au and CsI improved the stability of the emission, Ni was observed to have no effect.

  2. LIGHT BRIDGE IN A DEVELOPING ACTIVE REGION. I. OBSERVATION OF LIGHT BRIDGE AND ITS DYNAMIC ACTIVITY PHENOMENA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Toriumi, Shin; Katsukawa, Yukio; Cheung, Mark C. M., E-mail: shin.toriumi@nao.ac.jp

    Light bridges, the bright structures that divide the umbra of sunspots and pores into smaller pieces, are known to produce a wide variety of activity events in solar active regions (ARs). It is also known that the light bridges appear in the assembling process of nascent sunspots. The ultimate goal of this series of papers is to reveal the nature of light bridges in developing ARs and the occurrence of activity events associated with the light bridge structures from both observational and numerical approaches. In this first paper, exploiting the observational data obtained by Hinode, the Interface Region Imaging Spectrograph, andmore » the Solar Dynamics Observatory, we investigate the detailed structure of the light bridge in NOAA AR 11974 and its dynamic activity phenomena. As a result, we find that the light bridge has a weak, horizontal magnetic field, which is transported from the interior by a large-scale convective upflow and is surrounded by strong, vertical fields of adjacent pores. In the chromosphere above the bridge, a transient brightening occurs repeatedly and intermittently, followed by a recurrent dark surge ejection into higher altitudes. Our analysis indicates that the brightening is the plasma heating due to magnetic reconnection at lower altitudes, while the dark surge is the cool, dense plasma ejected from the reconnection region. From the observational results, we conclude that the dynamic activity observed in a light bridge structure such as chromospheric brightenings and dark surge ejections are driven by magnetoconvective evolution within the light bridge and its interaction with the surrounding magnetic fields.« less

  3. First observation of lion roar-like emissions in Saturn's magnetosheath

    NASA Astrophysics Data System (ADS)

    Pisa, David; Sulaiman, Ali H.; Santolik, Ondrej; Hospodarsky, George B.; Kurth, William S.; Gurnett, Donald A.

    2017-04-01

    Electromagnetic whistler mode waves known as "lion roars" have been reported by many missions inside the terrestrial magnetosheath. We show the observation of similar intense emissions in Saturn's magnetosheath as detected by the Cassini spacecraft. The emissions were observed inside the dawn sector (MLT˜0730) of the magnetosheath over a time period of nine hours before the satellite crossed the bow shock and entered the solar wind. The emissions were narrow-banded with a typical frequency of about 15 Hz well below the local electron cyclotron frequency (fce ˜100 Hz). Using the minimum variance analysis method, we show that the waves are right hand circularly polarized and propagate at small wave normal angles with respect to the ambient magnetic field. Here, for the first time, we report the evidence of lion roar-like emissions in Saturn's magnetosheath which represents a new and unique parameter regime.

  4. Linearly polarized light emission from quantum dots with plasmonic nanoantenna arrays.

    PubMed

    Ren, Mengxin; Chen, Mo; Wu, Wei; Zhang, Lihui; Liu, Junku; Pi, Biao; Zhang, Xinzheng; Li, Qunqing; Fan, Shoushan; Xu, Jingjun

    2015-05-13

    Polarizers provide convenience in generating polarized light, meanwhile their adoption raises problems of extra weight, cost, and energy loss. Aiming to realize polarizer-free polarized light sources, herein, we present a plasmonic approach to achieve direct generation of linearly polarized optical waves at the nanometer scale. Periodic slot nanoantenna arrays are fabricated, which are driven by the transition dipole moments of luminescent semiconductor quantum dots. By harnessing interactions between quantum dots and scattered fields from the nanoantennas, spontaneous emission with a high degree of linear polarization is achieved from such hybrid antenna system with polarization perpendicular to antenna slot. We also demonstrate that the polarization is engineerable in aspects of both spectrum and magnitude by tailoring plasmonic resonance of the antenna arrays. Our findings will establish a basis for the development of innovative polarized light-emitting devices, which are useful in optical displays, spectroscopic techniques, optical telecommunications, and so forth.

  5. Recent evidence concerning higher NO x emissions from passenger cars and light duty vehicles

    NASA Astrophysics Data System (ADS)

    Carslaw, David C.; Beevers, Sean D.; Tate, James E.; Westmoreland, Emily J.; Williams, Martin L.

    2011-12-01

    Ambient trends in nitrogen oxides (NO x) and nitrogen dioxide (NO 2) for many air pollution monitoring sites in European cities have stabilised in recent years. The lack of a decrease in the concentration of NO x and in particular NO 2 is of concern given European air quality standards are set in law. The lack of decrease in the concentration of NO x and NO 2 is also in clear disagreement with emission inventory estimates and projections. This work undertakes a comprehensive analysis of recent vehicle emissions remote sensing data from seven urban locations across the UK. The large sample size of 84,269 vehicles was carefully cross-referenced to a detailed and comprehensive database of vehicle information. We find that there are significant discrepancies between current UK/European estimates of NO x emissions and those derived from the remote sensing data for several important classes of vehicle. In the case of light duty diesel vehicles it is found that NO x emissions have changed little over 20 years or so over a period when the proportion of directly emitted NO 2 has increased substantially. For diesel cars it is found that absolute emissions of NO x are higher across all legislative classes than suggested by UK and other European emission inventories. Moreover, the analysis shows that more recent technology diesel cars (Euro 3-5) have clear increasing NO x emissions as a function of Vehicle Specific Power, which is absent for older technology vehicles. Under higher engine loads, these newer model diesel cars have a NO x/CO 2 ratio twice that of older model cars, which may be related to the increased use of turbo-charging. Current emissions of NO x from early technology catalyst-equipped petrol cars (Euro 1/2) were also found to be higher than emission inventory estimates - and comparable with NO x emissions from diesel cars. For heavy duty vehicles, it is found that NO x emissions were relatively stable until the introduction of Euro IV technology when

  6. 40 CFR 86.1818-12 - Greenhouse gas emission standards for light-duty vehicles, light-duty trucks, and medium-duty...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., perfluorocarbons, and sulfur hexafluoride. This section applies to 2012 and later model year LDVs, LDTs and MDPVs... aftermarket conversion certifiers, as those terms are defined in 40 CFR 85.502, of all model year light-duty... business according to the requirements of § 86.1801-12(j) are exempt from the emission standards in this...

  7. Impact of surface morphology on the properties of light emission in InGaN epilayers

    NASA Astrophysics Data System (ADS)

    Kristijonas Uždavinys, Tomas; Marcinkevičius, Saulius; Mensi, Mounir; Lahourcade, Lise; Carlin, Jean-François; Martin, Denis; Butté, Raphaël; Grandjean, Nicolas

    2018-05-01

    Scanning near-field optical microscopy was used to study the influence of the surface morphology on the properties of light emission and alloy composition in InGaN epitaxial layers grown on GaN substrates. A strong correlation between the maps of the photoluminescence (PL) peak energy and the gradient of the surface morphology was observed. This correlation demonstrates that the In incorporation strongly depends on the geometry of the monolayer step edges that form during growth in the step-flow mode. The spatial distribution of nonradiative recombination centers — evaluated from PL intensity maps — was found to strongly anticorrelate with the local content of In atoms in the InGaN alloy.

  8. Radio emission of SN1993J: the complete picture. II. Simultaneous fit of expansion and radio light curves

    NASA Astrophysics Data System (ADS)

    Martí-Vidal, I.; Marcaide, J. M.; Alberdi, A.; Guirado, J. C.; Pérez-Torres, M. A.; Ros, E.

    2011-02-01

    We report on a simultaneous modelling of the expansion and radio light curves of the supernova SN1993J. We developed a simulation code capable of generating synthetic expansion and radio light curves of supernovae by taking into consideration the evolution of the expanding shock, magnetic fields, and relativistic electrons, as well as the finite sensitivity of the interferometric arrays used in the observations. Our software successfully fits all the available radio data of SN 1993J with a standard emission model for supernovae, which is extended with some physical considerations, such as an evolution in the opacity of the ejecta material, a radial decline in the magnetic fields within the radiating region, and a changing radial density profile for the circumstellar medium starting from day 3100 after the explosion.

  9. Emission enhancement, light extraction and carrier dynamics in InGaAs/GaAs nanowire arrays

    NASA Astrophysics Data System (ADS)

    Kivisaari, Pyry; Chen, Yang; Anttu, Nicklas

    2018-03-01

    Nanowires (NWs) have the potential for a wide range of new optoelectronic applications. For example, light-emitting diodes that span over the whole visible spectrum are currently being developed from NWs to overcome the well known green gap problem. However, due to their small size, NW devices exhibit special properties that complicate their analysis, characterization, and further development. In this paper, we develop a full optoelectronic simulation tool for NW array light emitters accounting for carrier transport and wave-optical emission enhancement (EE), and we use the model to simulate InGaAs/GaAs NW array light emitters with different geometries and temperatures. Our results show that NW arrays emit light preferentially to certain angles depending on the NW diameter and temperature, encouraging temperature- and angle-resolved measurements of NW array light emission. On the other hand, based on our results both the EE and light extraction efficiency can easily change by at least a factor of two between room temperature and 77 K, complicating the characterization of NW light emitters if conventional methods are used. Finally, simulations accounting for surface recombination emphasize its major effect on the device performance. For example, a surface recombination velocity of 104 cm s-1 reported earlier for bare InGaAs surfaces results in internal quantum efficiencies less than 30% for small-diameter NWs even at the temperature of 30 K. This highlights that core-shell structures or high-quality passivation techniques are eventually needed to achieve efficient NW-based light emitters.

  10. Airborne observations reveal elevational gradient in tropical forest isoprene emissions.

    PubMed

    Gu, Dasa; Guenther, Alex B; Shilling, John E; Yu, Haofei; Huang, Maoyi; Zhao, Chun; Yang, Qing; Martin, Scot T; Artaxo, Paulo; Kim, Saewung; Seco, Roger; Stavrakou, Trissevgeni; Longo, Karla M; Tóta, Julio; de Souza, Rodrigo Augusto Ferreira; Vega, Oscar; Liu, Ying; Shrivastava, Manish; Alves, Eliane G; Santos, Fernando C; Leng, Guoyong; Hu, Zhiyuan

    2017-05-23

    Isoprene dominates global non-methane volatile organic compound emissions, and impacts tropospheric chemistry by influencing oxidants and aerosols. Isoprene emission rates vary over several orders of magnitude for different plants, and characterizing this immense biological chemodiversity is a challenge for estimating isoprene emission from tropical forests. Here we present the isoprene emission estimates from aircraft eddy covariance measurements over the Amazonian forest. We report isoprene emission rates that are three times higher than satellite top-down estimates and 35% higher than model predictions. The results reveal strong correlations between observed isoprene emission rates and terrain elevations, which are confirmed by similar correlations between satellite-derived isoprene emissions and terrain elevations. We propose that the elevational gradient in the Amazonian forest isoprene emission capacity is determined by plant species distributions and can substantially explain isoprene emission variability in tropical forests, and use a model to demonstrate the resulting impacts on regional air quality.

  11. Strong enhancement of emission efficiency in GaN light-emitting diodes by plasmon-coupled light amplification of graphene

    NASA Astrophysics Data System (ADS)

    Kim, Jong Min; Kim, Sung; Hwang, Sung Won; Kim, Chang Oh; Shin, Dong Hee; Kim, Ju Hwan; Jang, Chan Wook; Kang, Soo Seok; Hwang, Euyheon; Choi, Suk-Ho; El-Gohary, Sherif H.; Byun, Kyung Min

    2018-02-01

    Recently, we have demonstrated that excitation of plasmon-polaritons in a mechanically-derived graphene sheet on the top of a ZnO semiconductor considerably enhances its light emission efficiency. If this scheme is also applied to device structures, it is then expected that the energy efficiency of light-emitting diodes (LEDs) increases substantially and the commercial potential will be enormous. Here, we report that the plasmon-induced light coupling amplifies emitted light by ˜1.6 times in doped large-area chemical-vapor-deposition-grown graphene, which is useful for practical applications. This coupling behavior also appears in GaN-based LEDs. With AuCl3-doped graphene on Ga-doped ZnO films that is used as transparent conducting electrodes for the LEDs, the average electroluminescence intensity is 1.2-1.7 times enhanced depending on the injection current. The chemical doping of graphene may produce the inhomogeneity in charge densities (i.e., electron/hole puddles) or roughness, which can play a role as grating couplers, resulting in such strong plasmon-enhanced light amplification. Based on theoretical calculations, the plasmon-coupled behavior is rigorously explained and a method of controlling its resonance condition is proposed.

  12. Maritime NOx Emissions Over Chinese Seas Derived From Satellite Observations

    NASA Astrophysics Data System (ADS)

    Ding, J.; van der A, R. J.; Mijling, B.; Jalkanen, J.-P.; Johansson, L.; Levelt, P. F.

    2018-02-01

    By applying an inversion algorithm to NOx satellite observations from Ozone Monitoring Instrument, monthly NOx emissions for a 10 year period (2007 to 2016) over Chinese seas are presented for the first time. No effective regulations on NOx emissions have been implemented for ships in China, which is reflected in the trend analysis of maritime emissions. The maritime emissions display a continuous increase rate of about 20% per year until 2012 and slow down to 3% after that. The seasonal cycle of shipping emissions has regional variations, but all regions show lower emissions during winter. Simulations by an atmospheric chemistry transport model show a notable influence of maritime emissions on air pollution over coastal areas, especially in summer. The satellite-derived spatial distribution and the magnitude of maritime emissions over Chinese seas are in good agreement with bottom-up studies based on the Automatic Identification System of ships.

  13. Mapping Isoprene Emissions over North America using Formaldehyde Column Observations from Space

    NASA Technical Reports Server (NTRS)

    Palmer, Paul I.; Jacob, Daniel J.; Fiore, Arlene M.; Martin, Randall V.; Chance, Kelly; Kurosu, Thomas P.

    2004-01-01

    I] We present a methodology for deriving emissions of volatile organic compounds (VOC) using space-based column observations of formaldehyde (HCHO) and apply it to data from the Global Ozone Monitoring Experiment (GOME) satellite instrument over North America during July 1996. The HCHO column is related to local VOC emissions, with a spatial smearing that increases with the VOC lifetime. lsoprene is the dominant HCHO precursor over North America in summer, and its lifetime (approx. = 1 hour) is sufficiently short that the smearing can be neglected. We use the Goddard Earth Observing System global 3-D model of tropospheric chemistry (GEOS-CHEM) to derive the relationship between isoprene emissions and HCHO columns over North America and use these relationships to convert the GOME HCHO columns to isoprene emissions. We also use the GEOS-CHEM model as an intermediary to validate the GOME HCHO column measurements by comparison with in situ observations. The GEOS-CHEM model including the Global Emissions Inventory Activity (GEIA) isoprene emission inventory provides a good simulation of both the GOME data (r(sup 2) = 0.69, n = 756, bias = +l1 %) and the in situ summertime HCHO measurements over North America (r(sup 2) = 0.47, n = 10, bias = -3%). The GOME observations show high values over regions of known high isoprene emissions and a day-to-day variability that is consistent with the temperature dependence of isoprene emission. Isoprene emissions inferred from the GOME data are 20% less than GEIA on average over North America and twice those from the U S . EPA Biogenic Emissions Inventory System (BEIS2) inventory. The GOME isoprene inventory when implemented in the GEOS-CHEM model provides a better simulation of the HCHO in situ measurements thaneitherGEIAorBEIS2 (r(sup 2) = 0.71,n= 10, bias = -10 %).

  14. Ca²⁺ signal contributing to the synthesis and emission of monoterpenes regulated by light intensity in Lilium 'siberia'.

    PubMed

    Hu, Zenghui; Li, Tianjiao; Zheng, Jian; Yang, Kai; He, Xiangfeng; Leng, Pingsheng

    2015-06-01

    The floral scent is an important part of plant volatile compounds, and is influenced by environmental factors. The emission of monoterpenes of Lilium 'siberia' is regulated by light intensity, but the mechanism is large unknown. In this study, the expression of Li-mTPS, a monoterpene synthase gene in the tepals of Lilium 'siberia', and net Ca(2+) flux were investigated after exposure to different levels of light intensity (0, 100, 300, 600, 1000, and 1500 μmol m(-2) s(-1)). Moreover the effect of LaCl3 and ethylene glycol-bis-(2-aminoethylether)-N,N,N',N'-tetraacetic acid (EGTA) on the Li-mTPS expression, monoterpene emission, and net Ca(2+) flux were examined at 600 μmol m(-2) s(-1). The results showed that along with the enhancement of light intensity, the expression level of Li-mTPS increased gradually, and the net Ca(2+) influx was also enhanced showing a similar pattern. It was found that LaCl3 and EGTA effectively inhibited the increase in expression of Li-mTPS and the net Ca(2+) influx induced by light treatment. Moreover, the release amounts of monoterpenes decreased significantly after treatment with LaCl3 and EGTA. So it can be concluded that Ca(2+) signal contributed to the biosynthesis and emission of monoterpenes regulated by light intensity in Lilium 'siberia' tepals. The increased light intensity firstly triggered the Ca(2+) influx to cytoplasm, and then the gene expression of monoterpene synthases downstream was activated to regulate the biosynthesis and emission of monoterpenes. But in the signaling pathway other mechanisms were thought to be involved in the emission of monoterpenes regulated by light intensity, which need to be investigated in future research. Copyright © 2015 Elsevier Masson SAS. All rights reserved.

  15. On the observations of unique low latitude whistler-triggered VLF/ELF emissions

    NASA Astrophysics Data System (ADS)

    Altaf, M.; Singh, K. K.; Singh, A. K.; Lalmani

    A detailed analysis of the VLF/ELF wave data obtained during a whistler campaign under All India Coordinated Program of Ionosphere Thermosphere Studies (AICPITS) at our low latitude Indian ground station Jammu (geomag. lat. = 22° 26‧ N, L = 1.17) has yielded two types of unusual and unique whistler-triggered VLF/ELF emissions. These include (1) whistler-triggered hook emissions and (2) whistler-triggered long enduring discrete chorus riser emissions in VLF/ELF frequency range during night time. Such types of whistler-triggered emissions have not been reported earlier from any of the ground observations at low latitudes. In the present study, the observed characteristics of these emissions are described and interpreted. Dispersion analysis of these emissions show that the whistlers as well as emissions have propagated along a higher geomagnetic field line path with L-values lying ∼L = 4, suggesting that these triggered emissions are to be regarded as mid-latitude emissions. These waves could have propagated along the geomagnetic field lines either in a ducted mode or in a pro-longitudinal (PL) mode. The measured intensity of the triggered emissions is almost equal to that of the source waves and does not vary throughout the period of observation on that day. It is speculated that these emissions may have been generated through a process of resonant interaction of the whistler waves with energetic electrons. Parameters related to this interaction are computed for different values of L and wave amplitude. The proposed mechanism explains some aspects of the dynamic spectra.

  16. Gamma-Ray Pulsar Light Curves as Probes of Magnetospheric Structure

    NASA Technical Reports Server (NTRS)

    Harding, A. K.

    2016-01-01

    The large number of gamma-ray pulsars discovered by the Fermi Gamma-Ray Space Telescope since its launch in 2008 dwarfs the handful that were previously known. The variety of observed light curves makes possible a tomography of both the ensemble-averaged field structure and the high-energy emission regions of a pulsar magnetosphere. Fitting the gamma-ray pulsar light curves with model magnetospheres and emission models has revealed that most of the high-energy emission, and the particles acceleration, takes place near or beyond the light cylinder, near the current sheet. As pulsar magnetosphere models become more sophisticated, it is possible to probe magnetic field structure and emission that are self-consistently determined. Light curve modeling will continue to be a powerful tool for constraining the pulsar magnetosphere physics.

  17. Tunable light emission by exciplex state formation between hybrid halide perovskite and core/shell quantum dots: Implications in advanced LEDs and photovoltaics

    PubMed Central

    Sanchez, Rafael S.; de la Fuente, Mauricio Solis; Suarez, Isaac; Muñoz-Matutano, Guillermo; Martinez-Pastor, Juan P.; Mora-Sero, Ivan

    2016-01-01

    We report the first observation of exciplex state electroluminescence due to carrier injection between the hybrid lead halide perovskite (MAPbI3–xClx) and quantum dots (core/shell PbS/CdS). Single layers of perovskite (PS) and quantum dots (QDs) have been produced by solution processing methods, and their photoluminescent properties are compared to those of bilayer samples in both PS/QD and QD/PS configurations. Exciplex emission at lower energies than the band gap of both PS and QD has been detected. The exciplex emission wavelength of this mixed system can be simply tuned by controlling the QD size. Light-emitting diodes (LEDs) have been fabricated using those configurations, which provide light emission with considerably low turn-on potential. The “color” of the LED can also be tuned by controlling the applied bias. The presence of the exciplex state PS and QDs opens up a broad range of possibilities with important implications not only in tunable LEDs but also in the preparation of intermediate band gap photovoltaic devices with the potentiality of surpassing the Shockley-Queisser limit. PMID:26844299

  18. Toxicological assessment of particulate emissions from the exhaust of old and new model heavy- and light-duty vehicles.

    DOT National Transportation Integrated Search

    2011-06-01

    The primary objective of this project is to develop an improved understanding of the factors affecting the toxicology of particulate exhaust emissions. Diesel particulate matter is a known carcinogen, and particulate exhaust emissions from both light...

  19. White light emission from Mn2 + doped ZnS nanocrystals through the surface chelating of 8-hydroxyquinoline-5-sulfonic acid

    NASA Astrophysics Data System (ADS)

    Lü, Xiaodan; Yang, Jing; Fu, Yuqin; Liu, Qianqian; Qi, Bin; Lü, Changli; Su, Zhongmin

    2010-03-01

    White light emitting semiconductor nanocrystals (NCs) have been successfully synthesized from 8-hydroxyquinoline-5-sulfonic acid (HQS) decorated manganese doped ZnS NCs through fine tuning the surface-coordination emission and dopant emission of the NC host. The HQS functionalized manganese doped ZnS NCs (QS-ZnS:Mn), with a cubic crystal structure, have the same diameter of about 4.0 nm as ZnS:Mn NCs without HQS. The intensity of the surface-coordination emission peak increased with increasing HQS content or augmenting excited wavelength. The emission of white light was achieved by carefully controlling the dosage of HQS in NCs and appropriately tuning the excited wavelength. The color coordinates (0.35, 0.34) for the efficient white light emitting NCs were very close to the ideal Commission Internationale de l'Eclairage (CIE) chromaticity coordinates for pure white light (0.33, 0.33). The photoluminescence (PL) decay study revealed that the white light emitting NCs exhibited maximum lifetime values at different emission peaks for different NC samples. The study results also indicated that the HQS molecules were attached to the surface of ZnS:Mn NCs in a single coordination fashion due to the steric hindrance effect of the special spherical surface of NCs, which made the QS-ZnS:Mn NCs possess stable and high fluorescent properties in different organic solvents as compared with the conventional small molecule complexes.

  20. Near white light emission of silicon nanocrystals

    NASA Astrophysics Data System (ADS)

    Lee, Soojin; Han, Il-Ki; Cho, Woon-Jo

    2003-11-01

    Silicon nanoparticles in the range from 2 nm to 5 nm was prepared from Zintl salt, soldium silicide (NaSi) by sonochemical method. This synthesis permits the reaction completed as fast as in a few hours and the easy alkyl-modification of nanocrystals surface at room temperature and ambient pressure. The average size of nanoparticles measured by the dynamic light scattering analysis was 2.7 nm. The high-resolution transmission electron micrograph cofirmed the material identity of nanoparticles as crystalline silicon. FT-IR spectra are consistent with the surface states of nanocrystals that is chlorine- or butyl-capped. The emission peak center moved to longer wavelength (up to 430 nm) with the reaction time, under a 325 nm excitation. The luminescence of silicon colloids looks bright bluish-white under excitation using a commercial low-intensity UV lamp.

  1. 40 CFR 86.099-8 - Emission standards for 1999 and later model year light-duty vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....099-8 Emission standards for 1999 and later model year light-duty vehicles. (a)(1)(i)-(ii) [Reserved... schedule of table A99-08 of this section for model year 1999. For small volume manufacturers, the standards... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Emission standards for 1999 and later...

  2. 40 CFR 86.001-9 - Emission standards for 2001 and later model year light-duty trucks

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ....001-9 Emission standards for 2001 and later model year light-duty trucks Section 86.001-9 includes... for 2001 and later model years, and shall not exceed the standards described in paragraph (d)(1) of... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Emission standards for 2001 and later...

  3. 40 CFR 86.001-9 - Emission standards for 2001 and later model year light-duty trucks

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....001-9 Emission standards for 2001 and later model year light-duty trucks Section 86.001-9 includes... for 2001 and later model years, and shall not exceed the standards described in paragraph (d)(1) of... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Emission standards for 2001 and later...

  4. 40 CFR 86.001-9 - Emission standards for 2001 and later model year light-duty trucks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....001-9 Emission standards for 2001 and later model year light-duty trucks. Section 86.001-9 includes... for 2001 and later model years, and shall not exceed the standards described in paragraph (d)(1) of... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Emission standards for 2001 and later...

  5. 40 CFR 86.099-8 - Emission standards for 1999 and later model year light-duty vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....099-8 Emission standards for 1999 and later model year light-duty vehicles. (a)(1)(i)-(ii) [Reserved... schedule of table A99-08 of this section for model year 1999. For small volume manufacturers, the standards... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Emission standards for 1999 and later...

  6. 40 CFR 86.001-9 - Emission standards for 2001 and later model year light-duty trucks

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....001-9 Emission standards for 2001 and later model year light-duty trucks Section 86.001-9 includes... for 2001 and later model years, and shall not exceed the standards described in paragraph (d)(1) of... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Emission standards for 2001 and later...

  7. 40 CFR 86.099-8 - Emission standards for 1999 and later model year light-duty vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....099-8 Emission standards for 1999 and later model year light-duty vehicles. (a)(1)(i)-(ii) [Reserved... schedule of table A99-08 of this section for model year 1999. For small volume manufacturers, the standards... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Emission standards for 1999 and later...

  8. 40 CFR 86.099-8 - Emission standards for 1999 and later model year light-duty vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ....099-8 Emission standards for 1999 and later model year light-duty vehicles. (a)(1)(i)-(ii) [Reserved... schedule of table A99-08 of this section for model year 1999. For small volume manufacturers, the standards... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Emission standards for 1999 and later...

  9. [The spectrogram characteristics of organic blue-emissive light-emitting excitated YAG : Ce phosphor].

    PubMed

    Xi, Jian-Fei; Zhang, Fang-Hui; Mu, Qiang; Zhang, Mai-Li

    2011-09-01

    It is demonstrated that the panchromatic luminescence devices with organic blue-emissive light-emitting was fabricated. This technique used down conversion, which was already popular in inorganic power LEDs to obtain white light emission. A blue OLED device with a configuration of ITO/2T-NATA (30 nm)/AND : TBPe (50 Wt%, 40 nm)/Alq3 (100 nm)/LiF(1 nm)/Al(100 nm) was prepared via vacuum deposition process, and then coated with YAG : Ce phosphor layers of different thicknesses to obtain a controllable and uniform shape while the CIE coordinates were fine tuned. This development not only decreased steps of technics and degree of difficulty, but also applied the mature technology of phosphor. The results showed that steady spectrogram was obtained in the devices with phosphor, with a best performance of a maximum luminance of 13 840 cd x m(-2) which was about 2 times of that of the devices without phosphor; a maximum current efficiency of 17.3 cd x A(-1) was increased more two times more than the devices without phosphor. The emission spectrum could be adjusted by varying the concentration and thickness of the phosphor layers. Absoulte spectrogram of devices was in direct proportion with different driving current corresponding.

  10. 76 FR 48758 - 2017-2025 Model Year Light-Duty Vehicle GHG Emissions and CAFE Standards: Supplemental Notice of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-09

    ... Presidential Memorandum on May 21, 2010, concerning the development of a new generation of clean cars and... cars, light-duty trucks, and medium-duty passenger vehicles (light-duty vehicles) built in those model... and to reduce greenhouse gas emissions of passenger cars and light-duty trucks of model years 2017...

  11. Enhancing UV-emissions through optical and electronic dual-function tuning of Ag nanoparticles hybridized with n-ZnO nanorods/p-GaN heterojunction light-emitting diodes.

    PubMed

    Yao, Yung-Chi; Yang, Zu-Po; Hwang, Jung-Min; Chuang, Yi-Lun; Lin, Chia-Ching; Haung, Jing-Yu; Chou, Chun-Yang; Sheu, Jinn-Kong; Tsai, Meng-Tsan; Lee, Ya-Ju

    2016-02-28

    ZnO nanorods (NRs) and Ag nanoparticles (NPs) are known to enhance the luminescence of light-emitting diodes (LEDs) through the high directionality of waveguide mode transmission and efficient energy transfer of localized surface plasmon (LSP) resonances, respectively. In this work, we have demonstrated Ag NP-incorporated n-ZnO NRs/p-GaN heterojunctions by facilely hydrothermally growing ZnO NRs on Ag NP-covered GaN, in which the Ag NPs were introduced and randomly distributed on the p-GaN surface to excite the LSP resonances. Compared with the reference LED, the light-output power of the near-band-edge (NBE) emission (ZnO, λ = 380 nm) of our hybridized structure is increased almost 1.5-2 times and can be further modified in a controlled manner by varying the surface morphology of the surrounding medium of the Ag NPs. The improved light-output power is mainly attributed to the LSP resonance between the NBE emission of ZnO NRs and LSPs in Ag NPs. We also observed different behaviors in the electroluminescence (EL) spectra as the injection current increases for the treatment and reference LEDs. This observation might be attributed to the modification of the energy band diagram for introducing Ag NPs at the interface between n-ZnO NRs and p-GaN. Our results pave the way for developing advanced nanostructured LED devices with high luminescence efficiency in the UV emission regime.

  12. Contrasting trends in light pollution across Europe based on satellite observed night time lights.

    PubMed

    Bennie, Jonathan; Davies, Thomas W; Duffy, James P; Inger, Richard; Gaston, Kevin J

    2014-01-21

    Since the 1970s nighttime satellite images of the Earth from space have provided a striking illustration of the extent of artificial light. Meanwhile, growing awareness of adverse impacts of artificial light at night on scientific astronomy, human health, ecological processes and aesthetic enjoyment of the night sky has led to recognition of light pollution as a significant global environmental issue. Links between economic activity, population growth and artificial light are well documented in rapidly developing regions. Applying a novel method to analysis of satellite images of European nighttime lights over 15 years, we show that while the continental trend is towards increasing brightness, some economically developed regions show more complex patterns with large areas decreasing in observed brightness over this period. This highlights that opportunities exist to constrain and even reduce the environmental impact of artificial light pollution while delivering cost and energy-saving benefits.

  13. Simulating Electron Cyclotron Maser Emission for Low Mass Stars

    NASA Astrophysics Data System (ADS)

    Llama, Joe; Jardine, Moira

    2018-01-01

    Zeeman-Doppler Imaging (ZDI) is a powerful technique that enables us to map the large-scale magnetic fields of stars spanning the pre- and main-sequence. Coupling these magnetic maps with field extrapolation methods allow us to investigate the topology of the closed, X-ray bright corona, and the cooler, open stellar wind.Using ZDI maps of young M dwarfs with simultaneous radio light curves obtained from the VLA, we present the results of modeling the Electron-Cyclotron Maser (ECM) emission from these systems. We determine the X-ray luminosity and ECM emission that is produced using the ZDI maps and our field extrapolation model. We compare these findings with the observed radio light curves of these stars. This allows us to predict the relative phasing and amplitude of the stellar X-ray and radio light curves.This benchmarking of our model using these systems allows us to predict the ECM emission for all stars that have a ZDI map and an observed X-ray luminosity. Our model allows us to understand the origin of transient radio emission observations and is crucial for disentangling stellar and exoplanetary radio signals.

  14. Characteristics that Produce White-light Enhancements in Solar Flares Observed by Hinode/SOT

    NASA Astrophysics Data System (ADS)

    Watanabe, Kyoko; Kitagawa, Jun; Masuda, Satoshi

    2017-12-01

    To understand the conditions that produce white-light (WL) enhancements in solar flares, a statistical analysis of visible continuum data as observed by Hinode/Solar Optical Telescope (SOT) was performed. In this study, approximately 100 flare events from M- and X-class flares were selected. The time period during which the data were recorded spans from 2011 January to 2016 February. Of these events, approximately half are classified as white-light flares (WLFs), whereas the remaining events do not show any enhancements of the visible continuum (non-WLF; NWL). To determine the existence of WL emission, running difference images of not only the Hinode/SOT WL (G-band, blue, green, and red filter) data, but also the Solar Dynamics Observatory/Helioseismic and Magnetic Imager continuum data are used. A comparison between these two groups of WL data in terms of duration, temperature, emission measure of GOES soft X-rays, distance between EUV flare ribbons, strength of hard X-rays, and photospheric magnetic field strength was undertaken. In this statistical study, WLF events are characterized by a shorter timescale and shorter ribbon distance compared with NWL events. From the scatter plots of the duration of soft X-rays and the energy of non-thermal electrons, a clear distinction between WLF and NWL events can be made. It is found that the precipitation of large amounts of accelerated electrons within a short time period plays a key role in generating WL enhancements. Finally, it was demonstrated that the coronal magnetic field strength in the flare region is one of the most important factors that allow the individual identification of WLF events from NWL events.

  15. Updated SO2 emission estimates over China using OMI/Aura observations

    NASA Astrophysics Data System (ADS)

    Elissavet Koukouli, Maria; Theys, Nicolas; Ding, Jieying; Zyrichidou, Irene; Mijling, Bas; Balis, Dimitrios; van der A, Ronald Johannes

    2018-03-01

    The main aim of this paper is to update existing sulfur dioxide (SO2) emission inventories over China using modern inversion techniques, state-of-the-art chemistry transport modelling (CTM) and satellite observations of SO2. Within the framework of the EU Seventh Framework Programme (FP7) MarcoPolo (Monitoring and Assessment of Regional air quality in China using space Observations) project, a new SO2 emission inventory over China was calculated using the CHIMERE v2013b CTM simulations, 10 years of Ozone Monitoring Instrument (OMI)/Aura total SO2 columns and the pre-existing Multi-resolution Emission Inventory for China (MEIC v1.2). It is shown that including satellite observations in the calculations increases the current bottom-up MEIC inventory emissions for the entire domain studied (15-55° N, 102-132° E) from 26.30 to 32.60 Tg annum-1, with positive updates which are stronger in winter ( ˜ 36 % increase). New source areas were identified in the southwest (25-35° N, 100-110° E) as well as in the northeast (40-50° N, 120-130° E) of the domain studied as high SO2 levels were observed by OMI, resulting in increased emissions in the a posteriori inventory that do not appear in the original MEIC v1.2 dataset. Comparisons with the independent Emissions Database for Global Atmospheric Research, EDGAR v4.3.1, show a satisfying agreement since the EDGAR 2010 bottom-up database provides 33.30 Tg annum-1 of SO2 emissions. When studying the entire OMI/Aura time period (2005 to 2015), it was shown that the SO2 emissions remain nearly constant before the year 2010, with a drift of -0.51 ± 0.38 Tg annum-1, and show a statistically significant decline after the year 2010 of -1.64 ± 0.37 Tg annum-1 for the entire domain. Similar findings were obtained when focusing on the greater Beijing area (30-40° N, 110-120° E) with pre-2010 drifts of -0.17 ± 0.14 and post-2010 drifts of -0.47 ± 0.12 Tg annum-1. The new SO2 emission inventory is publicly available and forms

  16. Light Converting Inorganic Phosphors for White Light-Emitting Diodes

    PubMed Central

    Chen, Lei; Lin, Chun-Che; Yeh, Chiao-Wen; Liu, Ru-Shi

    2010-01-01

    White light-emitting diodes (WLEDs) have matched the emission efficiency of florescent lights and will rapidly spread as light source for homes and offices in the next 5 to 10 years. WLEDs provide a light element having a semiconductor light emitting layer (blue or near-ultraviolet (nUV) LEDs) and photoluminescence phosphors. These solid-state LED lamps, rather than organic light emitting diode (OLED) or polymer light-emitting diode (PLED), have a number of advantages over conventional incandescent bulbs and halogen lamps, such as high efficiency to convert electrical energy into light, reliability and long operating lifetime. To meet with the further requirement of high color rendering index, warm light with low color temperature, high thermal stability and higher energy efficiency for WLEDs, new phosphors that can absorb excitation energy from blue or nUV LEDs and generate visible emissions efficiently are desired. The criteria of choosing the best phosphors, for blue (450−480 nm) and nUV (380−400 nm) LEDs, strongly depends on the absorption and emission of the phosphors. Moreover, the balance of light between the emission from blue-nUV LEDs and the emissions from phosphors (such as yellow from Y3Al5O12:Ce3+) is important to obtain white light with proper color rendering index and color temperature. Here, we will review the status of phosphors for LEDs and prospect the future development.

  17. Observations of O VI Emission from the Diffuse Interstellar Medium

    NASA Technical Reports Server (NTRS)

    Shelton, R. L.; Kruk, J. W.; Murphy, E. M.; Andersson, B. G.; Blair, W. P.; Dixon, W. V.; Edelstein, J.; Fullerton, A. W.; Gry, C.; Howk, J. C.; hide

    2001-01-01

    We report the first Far Ultraviolet Spectroscopic Explorer (FUSE) measurements of diffuse O(VI) (lambda lambda 1032,1038) emission from the general diffuse interstellar medium outside of supernova remnants or superbubbles. We observed a 30 arcsec x 30 arcsec region of the sky centered at l = 315.0 deg and b = -41.3 deg. From the observed intensities (2930 +/- 290 (random) +/- 410 (systematic) and 1790 +/- 260 (random) +/- 250 (systematic) photons/sq cm/s/sr in the 1032 and 1038 angstrom emission lines, respectively), derived equations, and assumptions about the source location, we calculate the intrinsic intensity, electron density, thermal pressure, and emitting depth. The intensities are too large for the emission to originate solely in the Local Bubble. Thus, we conclude that the Galactic thick disk and lower halo also contribute. High velocity clouds are ruled out because there are none near the pointing direction. The calculated emitting depth is small, indicating that the O(VI)-bearing gas fills a small volume. The observations can also be used to estimate the cooling rate of the hot interstellar medium and constrain models. The data also yield the first intensity measurement of the C(II) 3s 2S(1/2) to 2p 2P(3/2) emission line at 1037 angstrom and place upper limits on the intensities of ultraviolet line emission from C(I), C(III), Si(II), S(III), S(IV), S(VI), and Fe(III).

  18. Observed angles and geodesic light-cone coordinates

    NASA Astrophysics Data System (ADS)

    Mitsou, Ermis; Scaccabarozzi, Fulvio; Fanizza, Giuseppe

    2018-05-01

    We discuss the interpretation of the angles in the geodesic light-cone (GLC) coordinates. In particular, we clarify the way in which these angles can be identified with the observed ones. We show that, although this identification is always possible in principle, one cannot implement it in the usual gauge-fixing way, i.e. through a set of conditions on the GLC metric. Rather, one needs to invoke a tetrad at the observer and a Cartesian-like coordinate system in order to obtain the desired map globally on the observed sky.

  19. 40 CFR 86.096-8 - Emission standards for 1996 and later model year light-duty vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....096-8 Emission standards for 1996 and later model year light-duty vehicles. (a)(1) Standards. (i... tested with the procedures in subpart B indicated for 1996 model year, and shall not exceed the standards... subpart B of this part for 1995 model year light-duty vehicles and be subject to the standards described...

  20. 40 CFR 86.096-8 - Emission standards for 1996 and later model year light-duty vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....096-8 Emission standards for 1996 and later model year light-duty vehicles. (a)(1) Standards. (i... tested with the procedures in subpart B indicated for 1996 model year, and shall not exceed the standards... subpart B of this part for 1995 model year light-duty vehicles and be subject to the standards described...

  1. Land Surface Microwave Emissivity Dynamics: Observations, Analysis and Modeling

    NASA Technical Reports Server (NTRS)

    Tian, Yudong; Peters-Lidard, Christa D.; Harrison, Kenneth W.; Kumar, Sujay; Ringerud, Sarah

    2014-01-01

    Land surface microwave emissivity affects remote sensing of both the atmosphere and the land surface. The dynamical behavior of microwave emissivity over a very diverse sample of land surface types is studied. With seven years of satellite measurements from AMSR-E, we identified various dynamical regimes of the land surface emission. In addition, we used two radiative transfer models (RTMs), the Community Radiative Transfer Model (CRTM) and the Community Microwave Emission Modeling Platform (CMEM), to simulate land surface emissivity dynamics. With both CRTM and CMEM coupled to NASA's Land Information System, global-scale land surface microwave emissivities were simulated for five years, and evaluated against AMSR-E observations. It is found that both models have successes and failures over various types of land surfaces. Among them, the desert shows the most consistent underestimates (by approx. 70-80%), due to limitations of the physical models used, and requires a revision in both systems. Other snow-free surface types exhibit various degrees of success and it is expected that parameter tuning can improve their performances.

  2. On-road measurements of NMVOCs and NOx: Determination of light-duty vehicles emission factors from tunnel studies in Brussels city center

    NASA Astrophysics Data System (ADS)

    Ait-Helal, W.; Beeldens, A.; Boonen, E.; Borbon, A.; Boréave, A.; Cazaunau, M.; Chen, H.; Daële, V.; Dupart, Y.; Gaimoz, C.; Gallus, M.; George, C.; Grand, N.; Grosselin, B.; Herrmann, H.; Ifang, S.; Kurtenbach, R.; Maille, M.; Marjanovic, I.; Mellouki, A.; Miet, K.; Mothes, F.; Poulain, L.; Rabe, R.; Zapf, P.; Kleffmann, J.; Doussin, J.-F.

    2015-12-01

    Emission factors (EFs) of pollutants emitted by light-duty vehicles (LDV) were investigated in the Leopold II tunnel in Brussels city center (Belgium), in September 2011 and in January 2013, respectively. Two sampling sites were housing the instruments for the measurements of a large range of air pollutants, including non-methane volatile organic compounds (NMVOCs), nitrogen oxides (NOx) and carbon dioxide (CO2). The NMVOCs and NOx traffic EFs for LDV were determined from their correlation with CO2 using a single point analysis method. The emission factor of NOx is (544 ± 199) mg vehicle-1 km-1; NMVOCs emission factors vary from (0.26 ± 0.09) mg vehicle-1 km-1 for cis-but-2-ene to (8.11 ± 2.71) mg vehicle-1 km-1 for toluene. Good agreement is observed between the EFs determined in the Leopold II tunnel and the most recent EFs determined in another European roadway tunnel in 2004, with only a slight decrease of the EFs during the last decade. An historical perspective is provided and the observed trend in the NMVOCs emission factors reflect changes in the car fleet composition, the fuels and/or the engine technology that have occurred within the last three decades in Europe.

  3. Light sources and output couplers for a backlight with switchable emission angles

    NASA Astrophysics Data System (ADS)

    Fujieda, Ichiro; Imai, Keita; Takagi, Yoshihiko

    2007-09-01

    For switching viewing angles of a liquid crystal display, we proposed to place a liquid crystal device between an LED and a light-guide of a backlight. The first key component for this configuration is a light source with electronically-controlled emission angles. Here, we construct such a device by stacking an optical film and a polymer-network liquid crystal (PNLC) cell on top of a chip-type LED. The optical film contains opaque parallel plates that limit the LED output in a narrow angular range. The PNLC cell either transmits or scatters the light emerging from the optical film. Experiment using a 15μm-thick PNLC cell shows that the angular distribution becomes 2.3 times wider by turning off the PNLC cell. We place this light source at one end of a light-guide so that the angular distribution of the light propagating inside is controlled. The second key component is some types of micro-strucrures built on the light-guide to out-couple the propagating light. We first attached various optical films on a light-guide surface. Although the angular distribution of the extracted light was switched successfully, light was mostly emitted into an oblique direction, approximately 60° from the plane normal. Next, we used a half-cylinder in place of the optical films. The curved surface of the cylinder was attached to the light-guide with a small amount of matching oil, which constituted an optical window. We measured that the angular distribution of the extracted light decreased to 35° FWHM from 62° FWHM by turning on the PNLC cell.

  4. NO x emissions from diesel passenger cars worsen with age

    DOE PAGES

    Chen, Yuche; Borken-Kleefeld, Jens

    2016-02-17

    Commonly, the NO x emissions rates of diesel vehicles have been assumed to remain stable over the vehicle's lifetime. However, there have been hardly any representative long-term emission measurements. Here we present real-driving emissions of diesel cars and light commercial vehicles sampled on-road over 15 years in Zurich/Switzerland. Results suggest deterioration of NO x unit emissions for Euro 2 and Euro 3 diesel technologies, while Euro 1 and Euro 4 technologies seem to be stable. We can exclude a significant influence of high-emitting vehicles. NO x emissions from all cars and light commercial vehicles in European emission inventories increase bymore » 5-10% accounting for the observed deterioration, depending on the country and its share of diesel cars. Finally, we suggest monitoring the stability of emission controls particularly for high-mileage light commercial as well as heavy-duty vehicles.« less

  5. Progress in Emission Efficiency of Organic Light-Emitting Diodes: Basic Understanding and Its Technical Application

    NASA Astrophysics Data System (ADS)

    Tsutsui, Tetsuo; Takada, Noriyuki

    2013-11-01

    The technical history of when and how the basic understanding of the emission efficiency of organic light-emitting diodes (OLEDs) was established over the last 50 years is described. At first, our understanding of emission efficiency in single-crystal and thin-film electroluminescence (EL) devices in the early stages before the Eastman-Kodak breakthrough, that is, the introduction of the concept of multilayer structures, is examined. Then our contemplation travels from the Eastman-Kodak breakthrough towards the presently widely accepted concept of emission efficiency. The essential issues concerning the emission efficiency of OLEDs are summarized to help readers to obtain a common understanding of OLED efficiency problems, and detailed discussions on the primary factors that determine emission efficiency are given. Finally, some comments on remaining issues are presented.

  6. Instantaneous Frequency Analysis on Nonlinear EMIC Emissions: Arase Observation

    NASA Astrophysics Data System (ADS)

    Shoji, M.; Yoshizumi, M.; Omura, Y.; Kasaba, Y.; Ishisaka, K.; Matsuda, S.; Kasahara, Y.; Yagitani, S.; Matsuoka, A.; Teramoto, M.; Takashima, T.; Shinohara, I.

    2017-12-01

    In the inner magnetosphere, electromagnetic ion cyclotron (EMIC) waves cause nonlinear interactions with energetic protons. The waves drastically modify the proton distribution function, resulting in the particle loss in the radiation belt. Arase spacecraft, launched in late 2016, observed a nonlinear EMIC falling tone emission in the high magnetic latitude (MLAT) region of the inner magnetosphere. The wave growth with sub-packet structures of the falling tone emission is found by waveform data from PWE/EFD instrument. The evolution of the instantaneous frequency of the electric field of the EMIC falling tone emission is analyzed by Hilbert-Huang transform (HHT). We find several sub-packets with rising frequency in the falling tone wave. A self-consistent hybrid simulation suggested the complicate frequency evolution of the EMIC sub-packet emissions in the generation region. The intrinsic mode functions of Arase data derived from HHT are compared with the simulation data. The origin of the falling tone emission in the high MLAT region is also discussed.

  7. Assessing Greenhouse Gas emissions in the Greater Toronto Area using atmospheric observations (Invited)

    NASA Astrophysics Data System (ADS)

    Vogel, F. R.; Chan, E.; Huang, L.; Levin, I.; Worthy, D.

    2013-12-01

    Urban areas are said to be responsible for approximately 75% of anthropogenic Greenhouse Gases (GHGs) emissions while comprising only two percent of the land area [1]. This limited spatial expansion should facilitate a monitoring of anthropogenic GHGs from atmospheric observations. As major sources of emissions, cities also have a huge potential to drive emissions reductions. To effectively manage emissions, cities must however, first measure and report these publicly [2]. Modelling studies and measurements of CO2 from fossil fuel burning (FFCO2) in densely populated areas does, however, pose several challenges: Besides continuous in-situ observations, i.e. finding an adequate atmospheric transport model, a sufficiently fine-grained FFCO2 emission model and the proper background reference observations to distinguish the large-scale from the local/urban contributions to the observed FFCO2 concentration offsets ( ΔFFCO2) are required. Pilot studies which include the data from two 'sister sites*' in the vicinity of Toronto, Canada helped to derive flux estimates for Non-CO2 GHGs [3] and improve our understanding of urban FFCO2 emissions. Our 13CO2 observations reveal that the contribution of natural gas burning (mostly due to domestic heating) account for 80%×7% of FFCO2 emissions in the Greater Toronto Area (GTA) during winter. Our 14CO2 observations in the GTA, furthermore, show that the local offset of CO2 (ΔCO2) between our two sister sites can be largely attributed to urban FFCO2 emissions. The seasonal cycle of the observed ΔFFCO2 in Toronto, combined with high-resolution atmospheric modeling, helps to independently assess the contribution from different emission sectors (transportation, primary energy and industry, domestic heating) as predicted by a dedicated city-scale emission inventory, which deviates from a UNFCCC-based inventory. [1] D. Dodman. 2009. Blaming cities for climate change? An analysis of urban greenhouse gas emissions inventories

  8. 40 CFR 86.000-9 - Emission standards for 2000 and later model year light-duty trucks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....000-9 Emission standards for 2000 and later model year light-duty trucks. Section 86.000-9 includes...) and CO Model year Percentage 2002 40 2003 80 2004 100 Table A00-6—Useful Life Standards (G/MI) for... applicable model year's heavy light-duty trucks shall not exceed the applicable SFTP standards in table A00-6...

  9. 40 CFR 86.000-9 - Emission standards for 2000 and later model year light-duty trucks.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....000-9 Emission standards for 2000 and later model year light-duty trucks. Section 86.000-9 includes...) and CO Model year Percentage 2002 40 2003 80 2004 100 Table A00-6—Useful Life Standards (G/MI) for... applicable model year's heavy light-duty trucks shall not exceed the applicable SFTP standards in table A00-6...

  10. 40 CFR 86.000-8 - Emission standards for 2000 and later model year light-duty vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....000-8 Emission standards for 2000 and later model year light-duty vehicles. Section 86.000-8 includes... later model year light-duty vehicles shall meet the additional SFTP standards of table A00-2 (defined by...=NOX) and CO Model year Percentage 2000 40 2001 80 2002 100 Table A00-2—Useful Life Standards (G/MI...

  11. 40 CFR 86.000-8 - Emission standards for 2000 and later model year light-duty vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....000-8 Emission standards for 2000 and later model year light-duty vehicles. Section 86.000-8 includes... later model year light-duty vehicles shall meet the additional SFTP standards of table A00-2 (defined by...=NOX) and CO Model year Percentage 2000 40 2001 80 2002 100 Table A00-2—Useful Life Standards (G/MI...

  12. Fabrication of ZnO Thin Films by Sol-Gel Spin Coating and Their UV and White-Light Emission Properties

    NASA Astrophysics Data System (ADS)

    Kumar, Mirgender; Dubey, Sarvesh; Rajendar, Vanga; Park, Si-Hyun

    2017-10-01

    ZnO thin films have been fabricated by the sol-gel spin-coating technique and annealed under different conditions, and their ultraviolet (UV) and white-light emission properties investigated. Different ambient conditions including oxygen, nitrogen, zinc-rich nitrogen, and vacuum were used to tune the main properties of the ZnO thin films. The resistivity varied from the conductive to semi-insulating regime, and the luminescence emission from fairly intense UV to polychromatic. The emission intensity was also found to be a function of the annealing conditions. Possible routes to compensate the loss of emission characteristics are discussed. X-ray photoelectron spectroscopy (XPS) analysis was carried out to detect the chemical states of the zinc/oxygen species. The changes in the electrical and emission properties are explained based on annihilation/formation of inherent donor/acceptor-type defects. Such ZnO thin films could have potential applications in solid-state lighting.

  13. Suzaku Observations of Charge Exchange Emission from Solar System Objects

    NASA Technical Reports Server (NTRS)

    Ezoe, Y.; Fujimoto, R.; Yamasaki, N. Y.; Mitsuda, K.; Ohashi, T.; Ishikawa, K.; Oishi, S.; Miyoshi, Y; Terada, N.; Futaana, Y.; hide

    2012-01-01

    Recent results of charge exchange emission from solar system objects observed with the Japanese Suzaku satellite are reviewed. Suzaku is of great importance to investigate diffuse X-ray emission like the charge exchange from planetary exospheres and comets. The Suzaku studies of Earth's exosphere, Martian exosphere, Jupiter's aurorae, and comets are overviewed.

  14. Numerical simulation of whistler-triggered VLF emissions observed in Antartica

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nunn, D.; Smith, A.J.

    1996-03-01

    The authors have extracted from VLF databases from British Antarctica Survey data taken at Halley and Faraday stations, examples of whistler-triggered emissions (WTE). The WTE are relatively narrow band emissions triggered by natural background whistlers undergoing nonlinear wave particle interactions generally in the equatorial regions. They occur with either rising or falling frequency relative to the triggering waves. Using a Vlasov type code the authors are able to simulate the types of emissions which are observed. 24 refs., 8 figs., 3 tabs.

  15. Can acoustic emission detect the initiation of fatigue cracks: Application to high-strength light alloys used in aeronautics

    NASA Technical Reports Server (NTRS)

    Bathias, C.; Brinet, B.; Sertour, G.

    1978-01-01

    Acoustic emission was used for the detection of fatigue cracking in a number of high-strength light alloys used in aeronautical structures. Among the features studied were: the influence of emission frequency, the effect of surface oxidation, and the influence of grains. It was concluded that acoustic emission is an effective nondestructive technique for evaluating the initiation of fatigue cracking in such materials.

  16. Dynamic Control of Light Emission Faster than the Lifetime Limit Using VO2 Phase-Change

    DTIC Science & Technology

    2015-10-22

    ARTICLE Received 1 Jun 2015 | Accepted 14 Sep 2015 | Published 22 Oct 2015 Dynamic control of light emission faster than the lifetime limit using VO2...excited state lifetime . This proof-of-concept demonstration shows how integration with phase-change materials can transform wide- spread phosphorescent...faster than their radiative lifetime . The concept is based on the dynamic manipulation of light through tailoring the local density of optical states

  17. Airborne observations reveal elevational gradient in tropical forest isoprene emissions

    DOE PAGES

    Gu, Dasa; Guenther, Alex B.; Shilling, John E.; ...

    2017-05-23

    Terrestrial vegetation emits vast quantities of volatile organic compounds (VOCs) to he atmosphere1-3, which influence oxidants and aerosols leading to complex feedbacks on air quality and climate4-6. Isoprene dominates global non-methane VOC emissions with tropical regions contributing ~80% of global isoprene emissions2. Isoprene emission rates vary over several orders of magnitude for different plant species, and characterizing this immense biological chemodiversity is a challenge for estimating isoprene emission from tropical forests. Here we present the isoprene emission estimates from aircraft direct eddy covariance measurements over the pristine Amazon forest. We report isoprene emission rates that are 3 times higher thanmore » satellite top-down estimates and 35% higher than model predictions based on satellite land cover and vegetation specific emission factors (EFs). The results reveal strong correlations between observed isoprene emission rates and terrain elevations which are confirmed by similar correlations between satellite-derived isoprene emissions and terrain elevations. We propose that the elevational gradient in the Amazonian forest isoprene emission capacity is determined by plant species distributions and can explain a substantial degree of isoprene emission variability in tropical forests. Finally, we apply this approach over the central Amazon and use a model to demonstrate the impacts on regional air quality.« less

  18. Lattice-matched double dip-shaped BAlGaN/AlN quantum well structures for ultraviolet light emission devices

    NASA Astrophysics Data System (ADS)

    Park, Seoung-Hwan; Ahn, Doyeol

    2018-05-01

    Ultraviolet light emission characteristics of lattice-matched BxAlyGa1-x-y N/AlN quantum well (QW) structures with double AlGaN delta layers were investigated theoretically. In contrast to conventional single dip-shaped QW structure where the reduction effect of the spatial separation between electron and hole wave functions is negligible, proposed double dip-shaped QW shows significant enhancement of the ultraviolet light emission intensity from a BAlGaN/AlN QW structure due to the reduced spatial separation between electron and hole wave functions. The emission peak of the double dip-shaped QW structure is expected to be about three times larger than that of the conventional rectangular AlGaN/AlN QW structure.

  19. Simultaneous light emission and detection of InGaN/GaN multiple quantum well diodes for in-plane visible light communication

    NASA Astrophysics Data System (ADS)

    Wang, Yongjin; Xu, Yin; Yang, Yongchao; Gao, Xumin; Zhu, Bingcheng; Cai, Wei; Yuan, Jialei; Zhang, Rong; Zhu, Hongbo

    2017-03-01

    This paper presents the design, fabrication, and experimental characterization of monolithically integrated p-n junction InGaN/GaN multiple quantum well diodes (MQWDs) and suspended waveguides. Suspended MQWDs can be used as transmitters and receivers simultaneously, and suspended waveguides are used for light coupling to create an in-plane visible light communication system. Compared to the waveguide with separation trench, the calculated total light efficiency is increased from 18% to 22% for the continuous waveguide. The MQWDs are characterized by their typical current-voltage performance, and the pulse excitation measurements confirm that the InGaN/GaN MQWDs can achieve the light emission and photodetection at the same time. The photocurrent measurements indicate that the photocurrent is modulated by a bias voltage and that the photons are being supplied from another transmitter. An experimental demonstration is presented showing that the proposed device works well for in-plane full-duplex communication using visible light.

  20. NOx emission trends over Chinese cities estimated from OMI observations during 2005 to 2015.

    PubMed

    Liu, Fei; Beirle, Steffen; Zhang, Qiang; van der A, Ronald J; Zheng, Bo; Tong, Dan; He, Kebin

    2017-01-01

    Satellite NO 2 observations have been widely used to evaluate emission changes. To determine trends in NO x emission over China, we used a method independent of chemical transport models to quantify the NO x emissions from 48 cities and 7 power plants over China, on the basis of Ozone Monitoring Instrument (OMI) NO 2 observations during 2005 to 2015. We found that NO x emissions over 48 Chinese cities increased by 52% from 2005 to 2011 and decreased by 21% from 2011 to 2015. The decrease since 2011 could be mainly attributed to emission control measures in power sector; while cities with different dominant emission sources (i.e. power, industrial and transportation sectors) showed variable emission decline timelines that corresponded to the schedules for emission control in different sectors. The time series of the derived NO x emissions was consistent with the bottom-up emission inventories for all power plants (r=0.8 on average), but not for some cities (r=0.4 on average). The lack of consistency observed for cities was most probably due to the high uncertainty of bottom-up urban emissions used in this study, which were derived from downscaling the regional-based emission data to cities by using spatial distribution proxies.

  1. NOx emission trends over Chinese cities estimated from OMI observations during 2005 to 2015

    NASA Astrophysics Data System (ADS)

    Liu, Fei; Beirle, Steffen; Zhang, Qiang; van der A, Ronald J.; Zheng, Bo; Tong, Dan; He, Kebin

    2017-08-01

    Satellite nitrogen dioxide (NO2) observations have been widely used to evaluate emission changes. To determine trends in nitrogen oxides (NOx) emission over China, we used a method independent of chemical transport models to quantify the NOx emissions from 48 cities and seven power plants over China, on the basis of Ozone Monitoring Instrument (OMI) NO2 observations from 2005 to 2015. We found that NOx emissions over 48 Chinese cities increased by 52 % from 2005 to 2011 and decreased by 21 % from 2011 to 2015. The decrease since 2011 could be mainly attributed to emission control measures in power sector; while cities with different dominant emission sources (i.e., power, industrial, and transportation sectors) showed variable emission decline timelines that corresponded to the schedules for emission control in different sectors. The time series of the derived NOx emissions was consistent with the bottom-up emission inventories for all power plants (r = 0. 8 on average), but not for some cities (r = 0. 4 on average). The lack of consistency observed for cities was most probably due to the high uncertainty of bottom-up urban emissions used in this study, which were derived from downscaling the regional-based emission data to city level by using spatial distribution proxies.

  2. Si III OV Bright Line of Scattering Polarized Light That Has Been Observed in the CLASP and Its Center-to-Limb Variation

    NASA Technical Reports Server (NTRS)

    Katsukawa, Yukio; Ishikawa, Ryoko; Kano, Ryohei; Kubo, Masahito; Noriyuki, Narukage; Kisei, Bando; Hara, Hirohisa; Yoshiho, Suematsu; Goto, Motouji; Ishikawa, Shinnosuke; hide

    2017-01-01

    The CLASP (Chromospheric Lyman-Alpha Spectro- Polarimeter) rocket experiment, in addition to the ultraviolet region of the Ly alpha emission line (121.57 nm), emission lines of Si III (120.65 nm) and OV (121.83 nm) is can be observed. These are optically thin line compared to a Ly alpha line, if Rarere captured its polarization, there is a possibility that dripping even a new physical diagnosis chromosphere-transition layer. In particular, OV bright light is a release from the transition layer, further, three P one to one S(sub 0) is a forbidden line (cross-triplet transition between lines), it was not quite know whether to polarization.

  3. Groundbased Observations of [C I] 9850A Emission from Comet Hale-Bopp

    NASA Astrophysics Data System (ADS)

    Doane, N. E.; Oliversen, R. J.; Scherb, F.; Morgenthaler, J. P.; Roesler, F. L.; Woodward, R. C.; Harris, W. M.; Hilton, G. M.

    1999-05-01

    High spectral resolution observations of Comet Hale-Bopp [C I] 9850A emission were obtained at the NSO McMath-Pierce main telescope on 13 nights during 1997 March 9 to 10 and April 7 to 19. Spectra with good signal-to-noise were obtained using a dual- etalon 50mm Fabry-Perot spectrometer (R 40,000) with a 6 arcmin field of view. The comet was observed over a 0.92-1.00 AU range of heliocentric distances. Most observations were centered on the comet nucleus where the surface brightness ranged from about 70 to 170 Rayleighs. Several observations were also centered approximately 5 arcmin sunward and tailward of the comet nucleus. The sunward [C I] emission was fainter than the tailward emission. Assuming that CO photodissociation is the source of cometary C(1D) (and neglecting quenching), for a surface brightness of 120 Rayleighs, we estimate a (lower limit) CO production rate of about 2x10(30) per sec. These [C I] observationsare the first extensive set reported for this cometary emission line.

  4. White organic light emitting diodes with enhanced internal and external outcoupling for ultra-efficient light extraction and Lambertian emission.

    PubMed

    Bocksrocker, Tobias; Preinfalk, Jan Benedikt; Asche-Tauscher, Julian; Pargner, Andreas; Eschenbaum, Carsten; Maier-Flaig, Florian; Lemme, Uli

    2012-11-05

    White organic light emitting diodes (WOLEDs) suffer from poor outcoupling efficiencies. The use of Bragg-gratings to enhance the outcoupling efficiency is very promising for light extraction in OLEDs, but such periodic structures can lead to angular or spectral dependencies in the devices. Here we present a method which combines highly efficient outcoupling by a TiO(2)-Bragg-grating leading to a 104% efficiency enhancement and an additional high quality microlens diffusor at the substrate/air interface. With the addition of this diffusor, we achieved not only a uniform white emission, but also further increased the already improved device efficiency by another 94% leading to an overall enhancement factor of about 4.

  5. Time- and space-resolved light emission and spectroscopic research of the flashover plasma

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gleizer, J. Z.; Krasik, Ya. E.; Leopold, J.

    2015-02-21

    The results of an experimental study of the evolution of surface flashover across the surface of an insulator in vacuum subject to a high-voltage pulse and the parameters of the flashover plasma are reported. For the system studied, flashover is always initiated at the cathode triple junctions. Using time-resolved framing photography of the plasma light emission the velocity of the light emission propagation along the surface of the insulator was found to be ∼2.5·10{sup 8} cm/s. Spectroscopic measurements show that the flashover is characterized by a plasma density of 2–4 × 10{sup 14} cm{sup −3} and neutral and electron temperatures of 2–4 eV and 1–3 eV,more » respectively, corresponding to a plasma conductivity of ∼0.2 Ω{sup −1} cm{sup −1} and a discharge current density of up to ∼10 kA/cm{sup 2}.« less

  6. Role of nuclear stars in the light flashes observed on Skylab 4.

    PubMed

    McNulty, P J; Filz, R C; Rothwell, P L

    1977-01-01

    The astronauts on Skylab 4 observed bursts of intense visual light-flash activity when their spacecraft passed through the portion of the earth's inner trapped radiation belt known as the South Atlantic Anomaly (SAA). Two experimental sessions were carried out on board Skylab 4 under the auspices of Pinsky et al. who compare the flash rates with the measured flux of Z > or = 1 particles that would pass through the astronaut's eyes. They concluded that the flash rates, which became as great as 20/min, were anomalously high. We explored a number of alternative explanations for the anomalous flash rates that would be consistent with the accepted SAA flux values and the laboratory data on particle induced visual sensations and found that when one includes the effect of nuclear interactions in and near the retina which result in star formation (the emission of slow protons, neutrons and alpha particles form the nucleus in an evaporation-like process) the apparent anomaly is removed.

  7. Spontaneous light emission in complex nanostructures

    NASA Astrophysics Data System (ADS)

    Blanco, L. A.; García de Abajo, F. J.

    2004-05-01

    The spontaneous emission of an excited atom surrounded by different materials is studied in the framework of a semiclassical approach, where the transition dipole moment acts as the source of the emission field. The emission in the presence of semiinfinite media, metallic nanorings, spheres, gratings, and other complex geometries is investigated. Strong emission enhancement effects are obtained in some of these geometries associated to the excitation of plasmons (e.g., in nanorings or spheres). Furthermore, the emission is shown to take place only along narrow angular distributions when the atom is located inside a low-index dielectric and near its planar surface, or when metallic nanogratings are employed at certain resonant wave lengths. In particular, axially symmetric gratings made of real silver metal are considered, and both emission rate enhancement and focused far-field emission are achieved simultaneously when the grating is decorated with further nanostructures.

  8. Hot electron light emission in gallium arsenide/aluminium(x) gallium(1-x) arsenic heterostructures

    NASA Astrophysics Data System (ADS)

    Teke, Ali

    In this thesis we have demonstrated the operation of a novel tunable wavelength surface light emitting device. The device is based on a p-GaAs, and n-Ga1- xAlxAs heterojunction containing an inversion layer on the p- side, and GaAs quantum wells on the n- side, and, is referred to as HELLISH-2 (Hot Electron Light Emitting and Lasing in Semiconductor Heterostructure-Type 2). The devices utilise hot electron longitudinal transport and, therefore, light emission is independent of the polarity of the applied voltage. The wavelength of the emitted light can be tuned with the applied bias from GaAs band-to-band transition in the inversion layer to e1-hh1 transition in the quantum wells. In this work tunable means that the device can be operated at either single or multiple wavelength emission. The operation of the device requires only two diffused in point contacts. In this project four HELLISH-2 samples coded as ES1, ES2, ES6 and QT919 have been studied. First three samples were grown by MBE and the last one was grown by MOVPE techniques. ES1 was designed for single and double wavelength operation. ES2 was a control sample used to compare our results with previous work on HELLISH-2 and ES6 was designed for single, double and triple wavelength operation. Theoretical modelling of the device operation was carried out and compared with the experimental results. HELLISH-2 structure was optimised for low threshold and high efficiency operation as based on our model calculations. The last sample QT919 has been designed as an optimised device for single and double wavelength operation like ES1. HELLISH-2 has a number of advantages over the conventional light emitters, resulting in some possible applications, such as light logic gates and wavelength division multiplexing in optoelectronic.

  9. The National Emissions Inventory Significantly Overestimates NOx Emissions: Analysis of CMAQ and in situ observations from DISCOVER-AQ

    NASA Astrophysics Data System (ADS)

    Anderson, D. C.; Dickerson, R. R.; Loughner, C.

    2013-12-01

    NOx and CO not only adversely impact human health, but they, along with associated VOCs, are also important precursors for O3 formation. While ambient NOx and CO concentrations have decreased dramatically over the past 10-20 years, O3 has remained a more recalcitrant problem, particularly in the Baltimore/Washington region. Reduction of O3 production requires that emissions inventories, such as the National Emissions Inventory (NEI), accurately capture total emissions of CO and NOx while also correctly apportioning them among different sectors. Previous evaluations of the NEI paint different pictures of its accuracy, with assertions that it overestimates either one or both of CO and NOx from anywhere between 25 percent to a factor of 2. These conflicting claims warrant further investigation. In this study, measurements of NOx and CO taken aboard the NOAA P3B airplane during the 2011 DISCOVER-AQ field campaign were used to determine the NOx/CO emissions ratio at 6 locations in the Washington/Baltimore region. An average molar emissions ratio of 12.8 × 1.2 CO/NOx was found by calculating the change in CO over the change in NOx from vertical concentration profiles in the planetary boundary layer. Ratios showed little variation with location. Observed values were approximately a factor of 1.35 - 1.75 times greater than that predicted by the annual, countywide emissions ratio from the 2008 NEI. When compared to a temporalized, gridded version of the inventory processed by SMOKE, ratio observations were greater than that predicted by inventories by up to a factor of 2. Comparison of the in situ measurements and remotely sensed observations from MOPITT of CO to the Community Multiscale Air Quality (CMAQ) model agree within 10-35 percent, with the model higher on average. Measurements of NOy by two separate analytical techniques, on the other hand, show that CMAQ consistently and significantly overestimates NOy concentrations. Combined with the CO observations, this

  10. Cold Temperature Effects on Speciated VOC Emissions from Modern GDI Light-Duty Vehicles 1

    EPA Science Inventory

    In this study, speciated VOC emissions were characterized from three modern GDI light-duty vehicles. The vehicles were tested on a chassis dynamometer housed in a climate-controlled chamber at two temperatures (20 and 72 °F) using the EPA Federal Test Procedure (FTP) and a portio...

  11. DRIVE CYCLE EFFICIENCY AND EMISSIONS ESTIMATES FOR REACTIVITY CONTROLLED COMPRESSION IGNITION IN A MULTI-CYLINDER LIGHT-DUTY DIESEL ENGINE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Curran, Scott; Briggs, Thomas E; Cho, Kukwon

    2011-01-01

    In-cylinder blending of gasoline and diesel to achieve Reactivity Controlled Compression Ignition (RCCI) has been shown to reduce NOx and PM emissions while maintaining or improving brake thermal efficiency as compared to conventional diesel combustion (CDC). The RCCI concept has an advantage over many advanced combustion strategies in that by varying both the percent of premixed gasoline and EGR rate, stable combustion can be extended over more of the light-duty drive cycle load range. Changing the percent premixed gasoline changes the fuel reactivity stratification in the cylinder providing further control of combustion phasing and pressure rise rate than the usemore » of EGR alone. This paper examines the combustion and emissions performance of light-duty diesel engine using direct injected diesel fuel and port injected gasoline to carry out RCCI for steady-state engine conditions which are consistent with a light-duty drive cycle. A GM 1.9L four-cylinder engine with the stock compression ratio of 17.5:1, common rail diesel injection system, high-pressure EGR system and variable geometry turbocharger was modified to allow for port fuel injection with gasoline. Engine-out emissions, engine performance and combustion behavior for RCCI operation is compared against both CDC and a premixed charge compression ignition (PCCI) strategy which relies on high levels of EGR dilution. The effect of percent of premixed gasoline, EGR rate, boost level, intake mixture temperature, combustion phasing and pressure rise rate is investigated for RCCI combustion for the light-duty modal points. Engine-out emissions of NOx and PM were found to be considerably lower for RCCI operation as compared to CDC and PCCI, while HC and CO emissions were higher. Brake thermal efficiency was similar or higher for many of the modal conditions for RCCI operation. The emissions results are used to estimate hot-start FTP-75 emissions levels with RCCI and are compared against CDC and PCCI modes.« less

  12. Gamma-Ray Light Curves from Pulsar Magnetospheres with Finite Conductivity

    NASA Technical Reports Server (NTRS)

    Harding, A. K.; Kalapotharakos, C.; Kazanas, D.; Contopoulos, I.

    2012-01-01

    The Fermi Large Area Telescope has provided an unprecedented database for pulsar emission studies that includes gamma-ray light curves for over 100 pulsars. Modeling these light curves can reveal and constrain the geometry of the particle accelerator, as well as the pulsar magnetic field structure. We have constructed 3D magnetosphere models with finite conductivity, that bridge the extreme vacuum and force-free solutions used in previous light curves modeling. We are investigating the shapes of pulsar gamma-ray light curves using these dissipative solutions with two different approaches: (l) assuming geometric emission patterns of the slot gap and outer gap, and (2) using the parallel electric field provided by the resistive models to compute the trajectories and . emission of the radiating particles. The light curves using geometric emission patterns show a systematic increase in gamma-ray peak phase with increasing conductivity, introducing a new diagnostic of these solutions. The light curves using the model electric fields are very sensitive to the conductivity but do not resemble the observed Fermi light curves, suggesting that some screening of the parallel electric field, by pair cascades not included in the models, is necessary

  13. Polycyclic aromatic hydrocarbons in biomass-burning emissions and their contribution to light absorption and aerosol toxicity.

    PubMed

    Samburova, Vera; Connolly, Jessica; Gyawali, Madhu; Yatavelli, Reddy L N; Watts, Adam C; Chakrabarty, Rajan K; Zielinska, Barbara; Moosmüller, Hans; Khlystov, Andrey

    2016-10-15

    In recent years, brown carbon (BrC) has been shown to be an important contributor to light absorption by biomass-burning atmospheric aerosols in the blue and near-ultraviolet (UV) part of the solar spectrum. Emission factors and optical properties of 113 polycyclic aromatic hydrocarbons (PAHs) were determined for combustion of five globally important fuels: Alaskan, Siberian, and Florida swamp peat, cheatgrass (Bromus tectorum), and ponderosa pine (Pinus ponderosa) needles. The emission factors of total analyzed PAHs were between 1.9±0.43.0±0.6 and 9.6±1.2-42.2±5.4mgPAHkg(-1)fuel for particle- and gas phase, respectively. Spectrophotometric analysis of the identified PAHs showed that perinaphthenone, methylpyrenes, and pyrene contributed the most to the total PAH light absorption with 17.2%, 3.3 to 10.5%, and 7.6% of the total particle-phase PAH absorptivity averaged over analyzed emissions from the fuels. In the gas phase, the top three PAH contributors to BrC were acenaphthylene (32.6%), anthracene (8.2%), and 2,4,5-trimethylnaphthalene (8.0%). Overall, the identified PAHs were responsible for 0.087-0.16% (0.13% on average) and 0.033-0.15% (0.11% on average) of the total light absorption by dichloromethane-acetone extracts of particle and gas emissions, respectively. Toxic equivalency factor (TEF) analysis of 16 PAHs prioritized by the United States Environmental Protection Agency (EPA) showed that benzo(a)pyrene contributed the most to the PAH carcinogenic potency of particle phase emissions (61.8-67.4% to the total carcinogenic potency of Σ16EPA PAHs), while naphthalene played the major role in carcinogenicity of the gas phase PAHs in the biomass-burning emission analyzed here (35.4-46.0% to the total carcinogenic potency of Σ16EPA PAHs). The 16 EPA-prioritized PAHs contributed only 22.1±6.2% to total particle and 23.4±11% to total gas phase PAH mass, thus toxic properties of biomass-burning PAH emissions are most likely underestimated. Copyright

  14. Light-duty vehicle greenhouse gas emission standards and corporate average fuel economy standards : final rule

    DOT National Transportation Integrated Search

    2010-05-07

    Final Rule to establish a National Program consisting of new standards for light-duty vehicles that will reduce greenhouse gas emissions and improve fuel economy. This joint : Final Rule is consistent with the National Fuel Efficiency Policy announce...

  15. Aggregation-induced emission: phenomenon, mechanism and applications.

    PubMed

    Hong, Yuning; Lam, Jacky W Y; Tang, Ben Zhong

    2009-08-07

    It is textbook knowledge that chromophore aggregation generally quenches light emission. In this feature article, we give an account on how we observed an opposite phenomenon termed aggregation-induced emission (AIE) and identified the restriction of intramolecular rotation as a main cause for the AIE effect. Based on the mechanistic understanding, we developed a series of new fluorescent and phosphorescent AIE systems with emission colours covering the entire visible spectral region and luminescence quantum yields up to unity. We explored high-tech applications of the AIE luminogens as, for example, fluorescence sensors (for explosive, ion, pH, temperature, viscosity, pressure, etc.), biological probes (for protein, DNA, RNA, sugar, phospholipid, etc.), immunoassay markers, PAGE visualization agents, polarized light emitters, monitors for layer-by-layer assembly, reporters for micelle formation, multistimuli-responsive nanomaterials, and active layers in the fabrication of organic light-emitting diodes.

  16. Ground and space observations of medium frequency auroral radio emissions

    NASA Astrophysics Data System (ADS)

    Broughton, Matthew C.

    The auroral zone is a rich source of natural radio emissions that can be observed in space and at ground-level. By studying these waves, scientists can gain insight into the plasma processes that generate them and use the near-Earth space environment as a large-scale plasma physics laboratory. This thesis uses both ground-level and in situ observations to study two kinds of natural radio emissions. First, we report observations of a new kind of auroral radio emission. The waves have frequencies ranging from 1.3-2.2 MHz, bandwidths ranging from 90-272 kHz, and durations ranging from 16-355 s. Spectral analysis of the waveform data has revealed that the emission has a complex combination of at least three kinds of fine structures. For model auroral electron distributions, calculations indicate that Langmuir waves could be excited at frequencies consistent with observations. The remainder of the thesis discusses auroral medium frequency (MF) burst, an impulsive, broadband natural radio emission observed at ground-level within a few minutes of local substorm onset. LaBelle [2011] proposed that MF burst originates as Langmuir/Z-mode waves on the topside of the ionosphere that subsequently mode convert to L-mode waves and propagate to ground-level. Using continuous waveform measurements and combined observations with the Sondrestrom Incoherent Scatter Radar, we have performed two tests of this mechanism. The results of these tests are consistent with the mechanism described in LaBelle [2011]. A survey of 8,624 half-orbits of the DEMETER spacecraft has revealed 68 observations of bursty MF waves. We have compared the wave properties of these waves to those of MF burst and have found that although it is uncertain, the balance of the evidence suggests that the bursty MF waves observed with DEMETER are the same phenomenon as the ground-level MF burst. Finally, we have used numerical simulations to model both the fine structure of MF burst and to estimate the attenuation the

  17. Effect of Carrier Thermalization Dynamics on Light Emission and Amplification in Organometal Halide Perovskites.

    PubMed

    Chen, Kai; Barker, Alex J; Morgan, Francis L C; Halpert, Jonathan E; Hodgkiss, Justin M

    2015-01-02

    The remarkable rise of organometal halide perovskites as solar photovoltaic materials has been followed by promising developments in light-emitting devices, including lasers. Here we present unique insights into the processes leading to photon emission in these materials. We employ ultrafast broadband photoluminescence (PL) and transient absorption spectroscopies to directly link density dependent ultrafast charge dynamics to PL. We find that exceptionally strong PL at the band edge is preceded by thermalization of free charge carriers. Short-lived PL above the band gap is clear evidence of nonexcitonic emission from hot carriers, and ultrafast PL depolarization confirms that uncorrelated charge pairs are precursors to photon emission. Carrier thermalization has a profound effect on amplified stimulated emission at high fluence; the delayed onset of optical gain we resolve within the first 10 ps and the unusual oscillatory behavior are both consequences of the kinetic interplay between carrier thermalization and optical gain.

  18. IUE observations of longitudinal and temporal variations in the Jovian auroral emission

    NASA Technical Reports Server (NTRS)

    Skinner, T. E.; Durrance, S. T.; Feldman, P. D.; Moos, H. W.

    1984-01-01

    The IUE's short wavelength spectrograph has been used to monitor the auroral emissions from Jupiter's northern hemisphere, yielding eight observations between January 1981 and January 1982 of H I Lyman-alpha and the H2 Lyman and Werner bands. Attention is given to an apparent periodic emission flux fluctuation, through detailed modeling of the emission geometry. Two possible auroral zones are defined at the north pole by mapping the magnetic field lines from the Io torus and the magnetotail onto the planet's atmosphere. The observed variation in flux with central meridian longitude is not consistent with a uniform brightness as a function of magnetic longitude in either auroral zone. The data can be fitted by confining the emissions to the region of the northern torus auroral zone, in qualitative agreement with the magnetic anomaly model. A similar emission from the magnetotail auroral zone cannot be ruled out.

  19. Ho3+-doped strontium-aluminium-bismuth-borate glasses for green light emission.

    PubMed

    Rajesh, D; Dhamodhara Naidu, M; Ratnakaram, Y C; Balakrishna, A

    2014-11-01

    Strontium-aluminium-bismuth-borate glasses (SAlBiB) doped with different concentrations of Ho(3+) were prepared using conventional melt quenching technique and their structural and optical properties investigated. X-ray diffraction and scanning electron microscopy analysis were used to study the structural properties. Optical properties were studied by measuring the optical absorption and visible luminescence spectra. The Judd-Ofelt (J-O) theory was applied to evaluate J-O intensity parameters, Ω(λ) (λ = 2, 4 and 6). Using J-O intensity parameters, radiative properties such as spontaneous transition probabilities (A(R)), branching ratios (β(R)) and radiative lifetimes (τ(R)) were determined. From the emission spectra, a strong green emission nearly at 549 nm corresponding to the transition, (5)S2 ((5)F4)→(5)I(8) was observed. Emission peak positions (λ(P)), effective bandwidths (Δλ(eff)) and stimulated emission cross-sections (σ(p)) were calculated for the observed emission transitions, (5)F3 →(5)I(8), (5)S2((5)F4)→(5)I(8) and (5)F5 →(5)I(8) of Ho(3+) in all the glass matrices. Chromaticity color coordinates were calculated using the emission spectra. The experimental results suggest that SAlBiB glass matrix with 1.5 mol% of Ho(3+) has better emission properties. Copyright © 2014 John Wiley & Sons, Ltd.

  20. Formation of Long-Lived Color Centers for Broadband Visible Light Emission in Low-Dimensional Layered Perovskites.

    PubMed

    Booker, Edward P; Thomas, Tudor H; Quarti, Claudio; Stanton, Michael R; Dashwood, Cameron D; Gillett, Alexander J; Richter, Johannes M; Pearson, Andrew J; Davis, Nathaniel J L K; Sirringhaus, Henning; Price, Michael B; Greenham, Neil C; Beljonne, David; Dutton, Siân E; Deschler, Felix

    2017-12-27

    We investigate the origin of the broadband visible emission in layered hybrid lead-halide perovskites and its connection with structural and photophysical properties. We study ⟨001⟩ oriented thin films of hexylammonium (HA) lead iodide, (C 6 H 16 N) 2 PbI 4 , and dodecylammonium (DA) lead iodide, (C 12 H 28 N) 2 PbI 4 , by combining first-principles simulations with time-resolved photoluminescence, steady-state absorption and X-ray diffraction measurements on cooling from 300 to 4 K. Ultrafast transient absorption and photoluminescence measurements are used to track the formation and recombination of emissive states. In addition to the excitonic photoluminescence near the absorption edge, we find a red-shifted, broadband (full-width at half-maximum of about 0.4 eV), emission band below 200 K, similar to emission from ⟨110⟩ oriented bromide 2D perovskites at room temperature. The lifetime of this sub-band-gap emission exceeds that of the excitonic transition by orders of magnitude. We use X-ray diffraction measurements to study the changes in crystal lattice with temperature. We report changes in the octahedral tilt and lattice spacing in both materials, together with a phase change around 200 K in DA 2 PbI 4 . DFT simulations of the HA 2 PbI 4 crystal structure indicate that the low-energy emission is due to interstitial iodide and related Frenkel defects. Our results demonstrate that white-light emission is not limited to ⟨110⟩ oriented bromide 2D perovskites but a general property of this class of system, and highlight the importance of defect control for the formation of low-energy emissive sites, which can provide a pathway to design tailored white-light emitters.

  1. Energy-dependent intensity variation of the persistent X-ray emission of magnetars observed with Suzaku

    NASA Astrophysics Data System (ADS)

    Nakagawa, Yujin; Ebisawa, Ken; Enoto, Teruaki

    2018-03-01

    The emission mechanism of magnetars is still controversial even though various observational and theoretical studies have been made. In order to investigate mechanisms of both the persistent X-ray emission and the burst emission of the magnetars, we propose a model in which the persistent X-ray emission consists of numerous micro-bursts of various sizes. If this model is correct, root mean square (rms) intensity variations of the persistent emission would exceed the values expected from the Poisson distribution. Using Suzaku archive data of 11 magnetars (22 observations), the rms intensity variations were calculated from 0.2 keV to 70 keV. As a result, we found significant excess rms intensity variations from all 11 magnetars. We suppose that numerous micro-bursts constituting the persistent X-ray emission cause the observed variations, suggesting that the persistent X-ray emission and the burst emission have identical emission mechanisms. In addition, we found that the rms intensity variations clearly increase toward higher energy bands for four magnetars (six observations). The energy-dependent rms intensity variations imply that the soft thermal component and the hard X-ray component are emitted from different regions far apart from each other.

  2. Mechanically flexible organic electroluminescent device with directional light emission

    DOEpatents

    Duggal, Anil Raj; Shiang, Joseph John; Schaepkens, Marc

    2005-05-10

    A mechanically flexible and environmentally stable organic electroluminescent ("EL") device with directional light emission comprises an organic EL member disposed on a flexible substrate, a surface of which is coated with a multilayer barrier coating which includes at least one sublayer of a substantially transparent organic polymer and at least one sublayer of a substantially transparent inorganic material. The device includes a reflective metal layer disposed on the organic EL member opposite to the substrate. The reflective metal layer provides an increased external quantum efficiency of the device. The reflective metal layer and the multilayer barrier coating form a seal around the organic EL member to reduce the degradation of the device due to environmental elements.

  3. The evolution of the X-ray afterglow emission of GW 170817/ GRB 170817A in XMM-Newton observations

    NASA Astrophysics Data System (ADS)

    D'Avanzo, P.; Campana, S.; Salafia, O. S.; Ghirlanda, G.; Ghisellini, G.; Melandri, A.; Bernardini, M. G.; Branchesi, M.; Chassande-Mottin, E.; Covino, S.; D'Elia, V.; Nava, L.; Salvaterra, R.; Tagliaferri, G.; Vergani, S. D.

    2018-05-01

    We report our observation of the short gamma-ray burst (GRB) GRB 170817A, associated to the binary neutron star merger gravitational wave (GW) event GW 170817, performed in the X-ray band with XMM-Newton 135 d after the event (on 29 December, 2017). We find evidence for a flattening of the X-ray light curve with respect to the previously observed brightening. This is also supported by a nearly simultaneous optical Hubble Space Telescope observation and successive X-ray Chandra and low-frequency radio observations recently reported in the literature. Since the optical-to-X-ray spectral slope did not change with respect to previous observations, we exclude that the change in the temporal evolution of the light curve is due to the passage of the cooling frequency: its origin must be geometric or dynamical. We interpret all the existing afterglow data with two models: i) a structured jet and ii) a jet-less isotropic fireball with some stratification in its radial velocity structure. Both models fit the data and predict that the radio flux must decrease simultaneously with the optical and X-ray emission, making it difficult to distinguish between them at the present stage. Polarimetric measurements and the rate of short GRB-GW associations in future LIGO/Virgo runs will be key to disentangle these two geometrically different scenarios.

  4. Organic light-emitting diodes with a spacer enhanced exciplex emission

    NASA Astrophysics Data System (ADS)

    Yan, Fei; Chen, Rui; Sun, Handong; Wei Sun, Xiao

    2014-04-01

    By introducing a spacer molecule into the blended exciplex emissive layer, the performance of the bulk heterojunction exciplex organic light-emitting diodes (OLEDs) was improved dramatically; the maximum luminous efficiency was enhanced by about 22% from 7.9 cd/A to 9.7 cd/A, and the luminous efficiency drop was reduced by 28% at 400 mA/cm2. Besides the suppressed annihilation of exciton, the time-resolved photoluminescence measurements indicated that the spacer enhanced the delayed fluorescence through increasing the backward intersystem crossing rate from the triplet to singlet exciplex state. This method is useful for developing high performance exciplex OLEDs.

  5. Quantifying VOC emissions from East Asia using 10 years of satellite observations

    NASA Astrophysics Data System (ADS)

    Stavrakou, T.; Muller, J. F.; Bauwens, M.; De Smedt, I.; Van Roozendael, M.; Boersma, F.; van der A, R. J.; Pierre-Francois, C.; Clerbaux, C.

    2016-12-01

    China's emissions are in the spotlight of efforts to mitigate climate change and improve regional and city-scale air quality. Despite growing efforts to better quantify China's emissions, the current estimates are often poor or inadequate. Complementary to bottom-up inventories, inverse modeling of fluxes has the potential to improve those estimates through the use of atmospheric observations of trace gas compounds. As formaldehyde (HCHO) is a high-yield product in the oxidation of most volatile organic compounds (VOCs) emitted by anthropogenic and natural sources, satellite observations of HCHO hold the potential to inform us on the spatial and temporal variability of the underlying VOC sources. The 10-year record of space-based HCHO column observations from the OMI instrument is used to constrain VOC emission fluxes in East Asia in a source inversion framework built on the IMAGES chemistry-transport model and its adjoint. The interannual and seasonal variability, spatial distribution and potential trends of the top-down VOC fluxes (anthropogenic, pyrogenic and biogenic) are presented and confronted to existing emission inventories, satellite observations of other species (e.g. glyoxal and nitrogen oxides), and past studies.

  6. FERMI Observations of GRB 090902B: A Distinct Spectral Component in the Prompt and Delayed Emission

    DOE PAGES

    Abdo, A. A.; Ackermann, M.; Ajello, M.; ...

    2009-11-03

    Here, we report on the observation of the bright, long gamma-ray burst (GRB), GRB 090902B, by the Gamma-ray Burst Monitor (GBM) and Large Area Telescope (LAT) instruments on-board the Fermi observatory. This was one of the brightest GRBs to have been observed by the LAT, which detected several hundred photons during the prompt phase. With a redshift of z = 1.822, this burst is among the most luminous detected by Fermi. Time-resolved spectral analysis reveals a significant power-law component in the LAT data that is distinct from the usual Band model emission that is seen in the sub-MeV energy range.more » This power-law component appears to extrapolate from the GeV range to the lowest energies and is more intense than the Band component, both below ~50 keV and above 100 MeV. The Band component undergoes substantial spectral evolution over the entire course of the burst, while the photon index of the power-law component remains constant for most of the prompt phase, then hardens significantly toward the end. After the prompt phase, power-law emission persists in the LAT data as late as 1 ks post-trigger, with its flux declining as t –1.5. The LAT detected a photon with the highest energy so far measured from a GRB, 33.4 +2.7 –3.5 GeV. This event arrived 82 s after the GBM trigger and ~50 s after the prompt phase emission had ended in the GBM band. In conclusion, we discuss the implications of these results for models of GRB emission and for constraints on models of the extragalactic background light.« less

  7. Light emitting diode excitation emission matrix fluorescence spectroscopy.

    PubMed

    Hart, Sean J; JiJi, Renée D

    2002-12-01

    An excitation emission matrix (EEM) fluorescence instrument has been developed using a linear array of light emitting diodes (LED). The wavelengths covered extend from the upper UV through the visible spectrum: 370-640 nm. Using an LED array to excite fluorescence emission at multiple excitation wavelengths is a low-cost alternative to an expensive high power lamp and imaging spectrograph. The LED-EEM system is a departure from other EEM spectroscopy systems in that LEDs often have broad excitation ranges which may overlap with neighboring channels. The LED array can be considered a hybrid between a spectroscopic and sensor system, as the broad LED excitation range produces a partially selective optical measurement. The instrument has been tested and characterized using fluorescent dyes: limits of detection (LOD) for 9,10-bis(phenylethynyl)-anthracene and rhodamine B were in the mid parts-per-trillion range; detection limits for the other compounds were in the low parts-per-billion range (< 5 ppb). The LED-EEMs were analyzed using parallel factor analysis (PARAFAC), which allowed the mathematical resolution of the individual contributions of the mono- and dianion fluorescein tautomers a priori. Correct identification and quantitation of six fluorescent dyes in two to six component mixtures (concentrations between 12.5 and 500 ppb) has been achieved with root mean squared errors of prediction (RMSEP) of less than 4.0 ppb for all components.

  8. EVLA Observation of Centimeter Continuum Emission from Protostars in Serpens South

    NASA Astrophysics Data System (ADS)

    Kern, Nicholas S.; Tobin, John J.; Keown, Jared A.; Gutermuth, Robert A.

    2015-01-01

    Serpens South is a protocluster with an unusually high abundance of Class 0 and I protostars, suggesting it is in a very early phase of star formation and may eventually form a star cluster. Following its discovery in 2008 with the Spitzer space telescope, infrared and millimeter observations and analysis quickly followed, however, Serpens South has yet to be fully explored in the radio. Radio observations at centimeter wavelengths have long been used as a tool to probe the dynamical processes of young protostars that are still heavily shrouded in their protostellar envelopes and thus cannot be seen at longer wavelengths. Radio observations then become an important tool in understanding Serpens South due to its young age. To this end, we have conducted EVLA C band continuum observations of the central region of the Serpens South protostellar cluster in order to map the centimeter continuum emission in a region of high Class 0 / I protostellar surface density. We report the detection of centimeter emission corresponding to protostars identified by Spitzer, and to protostars identified but blended by Herschel. We characterize their centimeter emission, and put them in context with previous Spitzer and Herschel infrared and far-infrared observations, as well as IRAM millimeter observations. Additionally, we make an assessment of the protostars' bolometric luminosity, and compare them to the known protostellar 3.6 cm to 6.0 cm luminosity vs. bolometric luminosity relation. With the EVLA, we present a mid-resolution map of centimeter emission from the central region of Serpens South with the highest sensitivity to date, with a beam size of ~5 arcseconds and rms on the order of 15 microJansky.

  9. Enhancing light emission in flexible AC electroluminescent devices by tetrapod-like zinc oxide whiskers.

    PubMed

    Wen, Li; Liu, Nishuang; Wang, Siliang; Zhang, Hui; Zhao, Wanqiu; Yang, Zhichun; Wang, Yumei; Su, Jun; Li, Luying; Long, Fei; Zou, Zhengguang; Gao, Yihua

    2016-10-03

    Flexible alternating current electroluminescent devices (ACEL) are more and more popular and widely used in liquid-crystal display back-lighting, large-scale architectural and decorative lighting due to their uniform light emission, low power consumption and high resolution. However, presently how to acquire high brightness under a certain voltage are confronted with challenges. Here, we demonstrate an electroluminescence (EL) enhancing strategy that tetrapod-like ZnO whiskers (T-ZnOw) are added into the bottom electrode of carbon nanotubes (CNTs) instead of phosphor layer in flexible ACEL devices emitting blue, green and orange lights, and the brightness is greatly enhanced due to the coupling between the T-ZnOw and ZnS phosphor dispersed in the flexible polydimethylsiloxane (PDMS) layer. This strategy provides a new routine for the development of high performance, flexible and large-area ACEL devices.

  10. A Climatology of Dust-Emission Events over North Africa Based on 27 Years of Surface Observations

    NASA Astrophysics Data System (ADS)

    Cowie, S.; Knippertz, P.; Schepanski, K.

    2012-04-01

    The huge quantity of mineral dust emitted annually from North Africa makes this area crucial to the global dust cycle. Once in the atmosphere, dust aerosols have a significant impact on the global radiation budget, clouds, the carbon cycle and can even act as a fertilizer to rain forests in South America. Current model estimates of dust production from North Africa are uncertain. At the heart of this problem is insufficient understanding of key dust emitting processes such as haboobs (cold pools generated through evaporation of convective precipitation), low-level jets (LLJs), and dry convection (dust devils and dust plumes). Scarce observations in this region, in particular in the Sahara, make model evaluation difficult. This work uses long-term surface observations from the MIDAS data set (~120 stations in the arid part of North Africa) to explore the diurnal, seasonal, decadal and geographical variations in dust emission events and their associated wind thresholds. The threshold values are determined from probability density functions of observed 10-minute anemomenter wind speeds. Emission events are defined using the present weather codes (WW) of SYNOP reports. These codes represent events of smaller intensity such as "Dust or sand raised by wind" to severe dust storms. During the 27-year study period (1984-2011) stations are required to have a minimum of 1000 dust observations to be included in the analysis. Dust emission frequency (DEF) is calculated for different time intervals (e.g. monthly, 3-hourly) taking into account the different number of measurements available at each station. North of 25°N a maximum during March-May is evident and relatively consistent over the whole North African region. Wind-speed thresholds for dust emission north of 25°N are higher than south of 25°N in the Sahel, where station-to-station variability is larger, and enhanced DEF activity during February-March is observed. The variability in this region is closely linked to the

  11. Effects of surface contamination on the infrared emissivity and visible-light scattering of highly reflective surfaces at cryogenic temperatures

    NASA Technical Reports Server (NTRS)

    Viehmann, W.; Eubanks, A. G.

    1972-01-01

    A technique is described for the simultaneous in situ measurement of film thickness, refractive index, total normal emissivity, visible-light scattering, and reflectance of contaminant films on a highly reflective liquid-nitrogen cooled, stainless steel substrate. Emissivities and scattering data are obtained for films of water, carbon dioxide, silicone oil, and a number of aromatic and aliphatic hydrocarbons as a function of film thickness between zero and 20 microns. Of the contaminants investigated, water has by far the greatest effect on emissivity, followed by silicone oil, aliphatic hydrocarbons, aromatic hydrocarbons, and carbon dioxide. The emissivity increases more rapidly with film thickness between zero and 2.5 microns than at thicknesses greater than 2.5 microns. Scattering of visible light changes very little below 2 microns thickness but increases rapidly with thickness beyond 2 to 3 microns. The effect of contaminant films on passive radiation coolers is discussed.

  12. Understanding NOx emission trends in China based on OMI observations

    NASA Astrophysics Data System (ADS)

    Wang, Y.; Ga, D.; Smeltzer, C. D.; Yi, R.; Liu, Z.

    2012-12-01

    We analyze OMI observations of NO2 columns over China from 2005 to 2010. Simulations using a regional 3-D chemical transport model (REAM) are used to derive the top-down anthropogenic NOx emissions. The Kendall method is then applied to derive the emission trend. The emission trend is affected by the economic slowdown in 2009. After removing the effect of one year abnormal data, the overall emission trend is 4.35±1.42% per year, which is slower than the linear-regression trend of 5.8-10.8% per year reported for previous years. We find large regional, seasonal, and urban-rural variations in emission trend. The annual emission trends of Northeast China, Central China Plain, Yangtze River Delta and Pearl River Delta are 44.98±1.39%, 5.24±1.63%, 3.31±1.02% and -4.02±1.87%, respectively. The annual emission trends of four megacities, Beijing, Shanghai, Guangzhou and Shenzhen are 0.7±0.27%, -0.75±0.31%, -4.08±1.21% and -6.22±2.85%,, considerably lower than the regional averages. These results appear to suggest that a number of factors, including migration of high-emission industries, vehicle emission regulations, emission control measures of thermal power plants, increased hydro-power usage, have reduced or reversed the increasing trend of NOx emissions in more economically developed megacities and southern coastal regions.

  13. The effects of deterioration and technological levels on pollutant emission factors for gasoline light-duty trucks.

    PubMed

    Zhang, Qingyu; Fan, Juwang; Yang, Weidong; Chen, Bixin; Zhang, Lijuan; Liu, Jiaoyu; Wang, Jingling; Zhou, Chunyao; Chen, Xuan

    2017-07-01

    Vehicle deterioration and technological change influence emission factors (EFs). In this study, the impacts of vehicle deterioration and emission standards on EFs of regulated pollutants (carbon monoxide [CO], hydrocarbon [HC], and nitrogen oxides [NO x ]) for gasoline light-duty trucks (LDTs) were investigated according to the inspection and maintenance (I/M) data using a chassis dynamometer method. Pollutant EFs for LDTs markedly varied with accumulated mileages and emission standards, and the trends of EFs are associated with accumulated mileages. In addition, the study also found that in most cases, the median EFs of CO, HC, and NO x are higher than those of basic EFs in the International Vehicle Emissions (IVE) model; therefore, the present study provides correction factors for the IVE model relative to the corresponding emission standards and mileages. Currently, vehicle emissions are great contributors to air pollution in cities, especially in developing countries. Emission factors play a key role in creating emission inventory and estimating emissions. Deterioration represented by vehicle age and accumulated mileage and changes of emission standards markedly influence emission factors. In addition, the results provide collection factors for implication in the IVE model in the region levels.

  14. A study of 173 nm light emission from discharge cells in plasma display panel

    NASA Astrophysics Data System (ADS)

    Uhm, Han S.; Choi, Eun H.; Jung, Kyu B.

    2005-03-01

    Emission properties of the 173nm lights from the electrical discharge cells of the plasma display panel are investigated. The dimer formation and a theoretical model of 173nm emission are presented. It is shown that the diffusion loss of the excited xenon atoms in the metastable level is one of the most important population depreciation factor of excited xenon atoms. The decay time τd of excited atom number increases from zero, reaches its peak, and then decreases to zero, as the gas pressure p increases from zero, agreeing well with experimental data. A simple analytical expression Y of the total emission intensity is described in terms of the diffusion loss df, the three-body collision η, the gas pressure p, and the xenon mole fraction χ. The emission intensity Y of 173nm photon decreases with an increasing value of parameter df. Moreover, the emission intensity Y increases drastically with an increasing value of the gas pressure p and the xenon mole fraction χ. Results from the theoretical model agree remarkably well with experimental data.

  15. Light-Dependent Aerobic Methane Oxidation Reduces Methane Emissions from Seasonally Stratified Lakes

    PubMed Central

    Oswald, Kirsten; Milucka, Jana; Brand, Andreas; Littmann, Sten; Wehrli, Bernhard; Kuypers, Marcel M. M.; Schubert, Carsten J.

    2015-01-01

    Lakes are a natural source of methane to the atmosphere and contribute significantly to total emissions compared to the oceans. Controls on methane emissions from lake surfaces, particularly biotic processes within anoxic hypolimnia, are only partially understood. Here we investigated biological methane oxidation in the water column of the seasonally stratified Lake Rotsee. A zone of methane oxidation extending from the oxic/anoxic interface into anoxic waters was identified by chemical profiling of oxygen, methane and δ13C of methane. Incubation experiments with 13C-methane yielded highest oxidation rates within the oxycline, and comparable rates were measured in anoxic waters. Despite predominantly anoxic conditions within the zone of methane oxidation, known groups of anaerobic methanotrophic archaea were conspicuously absent. Instead, aerobic gammaproteobacterial methanotrophs were identified as the active methane oxidizers. In addition, continuous oxidation and maximum rates always occurred under light conditions. These findings, along with the detection of chlorophyll a, suggest that aerobic methane oxidation is tightly coupled to light-dependent photosynthetic oxygen production both at the oxycline and in the anoxic bottom layer. It is likely that this interaction between oxygenic phototrophs and aerobic methanotrophs represents a widespread mechanism by which methane is oxidized in lake water, thus diminishing its release into the atmosphere. PMID:26193458

  16. The Story of Ever Diminishing Vehicle Tailpipe Emissions as Observed in the Chicago, Illinois Area.

    PubMed

    Bishop, Gary A; Haugen, Molly J

    2018-05-15

    The University of Denver has collected on-road fuel specific vehicle emissions measurements in the Chicago area since 1989. This nearly 30 year record illustrates the large reductions in light-duty vehicle tailpipe emissions and the remarkable improvements in emissions control durability to maintain low emissions over increasing periods of time. Since 1989 fuel specific carbon monoxide (CO) emissions have been reduced by an order of magnitude and hydrocarbon (HC) emissions by more than a factor of 20. Nitric oxide (NO) emissions have only been collected since 1997 but have seen reductions of 79%. This has increased the skewness of the emissions distribution where the 2016 fleet's 99th percentile contributes ∼3 times more of the 1990 total for CO and HC emissions. There are signs that these reductions may be leveling out as the emissions durability of Tier 2 vehicles in use today has almost eliminated the emissions reduction benefit of fleet turnover. Since 1997, the average age of the Chicago on-road fleet has increased 2 model years and the percentage of passenger vehicles has dropped from 71 to 52% of the fleet. Emissions are now so well controlled that the influence of driving mode has been completely eliminated as a factor for fuel specific CO and NO emissions.

  17. Optical Properties of Hybrid Inorganic/Organic Thin Film Encapsulation Layers for Flexible Top-Emission Organic Light-Emitting Diodes.

    PubMed

    An, Jae Seok; Jang, Ha Jun; Park, Cheol Young; Youn, Hongseok; Lee, Jong Ho; Heo, Gi-Seok; Choi, Bum Ho; Lee, Choong Hun

    2015-10-01

    Inorganic/organic hybrid thin film encapsulation layers consist of a thin Al2O3 layer together with polymer material. We have investigated optical properties of thin film encapsulation layers for top-emission flexible organic light-emitting diodes. The transmittance of hybrid thin film encapsulation layers and the electroluminescent spectrum of organic light-emitting diodes that were passivated by hybrid organic/inorganic thin film encapsulation layers were also examined as a function of the thickness of inorganic Al203 and monomer layers. The number of interference peaks, their intensity, and their positions in the visible range can be controlled by varying the thickness of inorganic Al2O3 layer. On the other hand, changing the thickness of monomer layer had a negligible effect on the optical properties. We also verified that there is a trade-off between transparency in the visible range and the permeation of water vapor in hybrid thin film encapsulation layers. As the number of dyads decreased, optical transparency improved while the water vapor permeation barrier was degraded. Our study suggests that, in top-emission organic light-emitting diodes, the thickness of each thin film encapsulation layer, in particular that of the inorganic layer, and the number of dyads should be controlled for highly efficient top-emission flexible organic light-emitting diodes.

  18. An Overview of Saturn Narrowband Radio Emissions Observed by Cassini RPWS

    NASA Astrophysics Data System (ADS)

    Ye, S.-Y.; Fischer, G.; Menietti, J. D.; Wang, Z.; Gurnett, D. A.; Kurth, W. S.

    Saturn narrowband (NB) radio emissions are detected between 3 and 70 kHz, with occurrence probability and wave intensity peaking around 5 kHz and 20 kHz. The emissions usually occur periodically for several days after intensification of Saturn kilometric radiation (SKR). Originally detected by the Voyagers, the extended duration of the Cassini mission and the improved capabilities of the Radio and Plasma Wave Science (RPWS) instrument have significantly advanced our knowledge about them. For example, RPWS measurements of the magnetic component have validated the electromagnetic nature of Saturn NB emissions. Evidences show that the 20 kHz NB emissions are generated by mode conversion of electrostatic upper hybrid waves on the boundary of the plasma torus, whereas direction-finding results point to a source in the auroral zone for the 5 kHz component. Similar to SKR, the 5 kHz NB emissions have a clock-like modulation and display two distinct modulation periods identical to the northern and southern hemisphere periods of SKR. Polarization measurements confirm that most NB emissions are propagating in the L-O mode, with the exception of second harmonic NB emissions. At high latitudes closer to the planet, RPWS detected right hand polarized Z-mode NB emissions below the local electron cyclotron frequency (f_ce), which are believed to be the source of the L-O mode NB emissions detected above the local f_ce. Although the energy source for the generation of the Z-mode waves is still unclear, linear growth rate calculations indicate that the observed plasma distributions are unstable to the growth of electrostatic cyclotron harmonic emission. Alternatively, electromagnetic Z-mode might be directly generated by the cyclotron maser instability. The source Z-mode waves, upon reflection, propagate to the opposite hemisphere before escaping through mode conversion, which could explain the fact that both rotational modulation periods of NB emissions are observable in each

  19. Tropospheric Emission Spectrometer for the Earth Observing System

    NASA Technical Reports Server (NTRS)

    Glavich, Thomas A.; Beer, Reinhard

    1991-01-01

    A Tropospheric Emission Spectrometer (TES) for the Earth Observing System (EOS) series of polar-orbiting platforms is described. TES is aimed at studying tropospheric chemistry, in particular, the exchange of gases between the surface and the atmosphere, urban and regional pollution, acid rain precursors, sources and sinks of greenhouse gases, and the interchange of gases between the troposphere and the stratosphere. TES is a high-resolution (0.025/cm) infrared Fourier transform spectrometer operating in the passive thermal-emission mode in a very wide spectral range (600 to 4350/cm; 2.3 to 16.7 microns). TES has 32 spatial pixels in each of four optically conjugated linear detector arrays, each optimized for a different spectral region.

  20. Photoluminescence studies of a perceived white light emission from a monolithic InGaN/GaN quantum well structure

    PubMed Central

    Ben Sedrine, N.; Esteves, T. C.; Rodrigues, J.; Rino, L.; Correia, M. R.; Sequeira, M. C.; Neves, A. J.; Alves, E.; Bockowski, M.; Edwards, P. R.; O’Donnell, K. P.; Lorenz, K.; Monteiro, T.

    2015-01-01

    In this work we demonstrate by photoluminescence studies white light emission from a monolithic InGaN/GaN single quantum well structure grown by metal organic chemical vapour deposition. As-grown and thermally annealed samples at high temperature (1000 °C, 1100 °C and 1200 °C) and high pressure (1.1 GPa) were analysed by spectroscopic techniques, and the annealing effect on the photoluminescence is deeply explored. Under laser excitation of 3.8 eV at room temperature, the as-grown structure exhibits two main emission bands: a yellow band peaked at 2.14 eV and a blue band peaked at 2.8 eV resulting in white light perception. Interestingly, the stability of the white light is preserved after annealing at the lowest temperature (1000 °C), but suppressed for higher temperatures due to a deterioration of the blue quantum well emission. Moreover, the control of the yellow/blue bands intensity ratio, responsible for the white colour coordinate temperatures, could be achieved after annealing at 1000 °C. The room temperature white emission is studied as a function of incident power density, and the correlated colour temperature values are found to be in the warm white range: 3260–4000 K. PMID:26336921

  1. 75 FR 25323 - Light-Duty Vehicle Greenhouse Gas Emission Standards and Corporate Average Fuel Economy Standards...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-05-07

    ...EPA and NHTSA are issuing this joint Final Rule to establish a National Program consisting of new standards for light-duty vehicles that will reduce greenhouse gas emissions and improve fuel economy. This joint Final Rule is consistent with the National Fuel Efficiency Policy announced by President Obama on May 19, 2009, responding to the country's critical need to address global climate change and to reduce oil consumption. EPA is finalizing greenhouse gas emissions standards under the Clean Air Act, and NHTSA is finalizing Corporate Average Fuel Economy standards under the Energy Policy and Conservation Act, as amended. These standards apply to passenger cars, light-duty trucks, and medium-duty passenger vehicles, covering model years 2012 through 2016, and represent a harmonized and consistent National Program. Under the National Program, automobile manufacturers will be able to build a single light-duty national fleet that satisfies all requirements under both programs while ensuring that consumers still have a full range of vehicle choices. NHTSA's final rule also constitutes the agency's Record of Decision for purposes of its National Environmental Policy Act (NEPA) analysis.

  2. New insights into the parametrization of temperature and light responses of mono - and sesquiterpene emissions from Aleppo pine and rosemary

    NASA Astrophysics Data System (ADS)

    Staudt, M.; Bourgeois, I.; Al Halabi, R.; Song, W.; Williams, J.

    2017-03-01

    Phytogenic emission of large volatile organic compounds (VOCs) such as monoterpenes (MTs) and sesquiterpenes (SQTs) are key precursors to the formation and growth of atmospheric particles. However, controlled environment studies to elucidate emission responses to temperature and light are still sparse. In this study, the volatile contents and emission responses of Aleppo pine and Rosemary have been investigated. These two common Mediterranean species store semivolatiles inside (resin ducts) and outside (trichomes) their foliage tissues respectively. Both species emitted mainly MTs with basal emission rates of around 5 (Rosemary) and 10 (pine) μg g-1 h-1 and SQTs about one order of magnitude lower. In Aleppo pine, two volatile sources could be clearly distinguished: 1) de-novo synthesized emission of (E)-β-ocimene and linalool, which accounted for about 70% of the total VOC release, were not found in foliar VOC extracts and expressed light dependency (LD) and temperature responses typical for enzyme driven emissions; and 2) storage-derived emissions of various MTs and SQTs whose emissions increased exponentially with temperature, showed no light dependency and were all present in leaf extracts. In Rosemary, all emitted MTs and SQTs including many oxygenated compounds, showed responses typical for stored volatiles and were all found in leaf extracts. The emissions of individual volatiles or volatile classes could be well described with the commonly applied empirical algorithms developed for LD or non LD emissions. However, the shapes of the temperature responses, and hence the deduced coefficient values, were significantly different between oxygenated and non-oxygenated compounds. They also differed between the storage-derived emissions of the two plant species, for individual VOCs or VOC classes. We address the possible reasons for this variation in temperature responses and argue that they are mostly due to molecular interactions along the species specific leaf

  3. Photopolarimetric Observations of CI(1657 Angstroms) and Dust Continuum Emissions from Comet Hale-Bopp with the WISP Sounding Rocket

    NASA Astrophysics Data System (ADS)

    Harris, W. M.; Nordsieck, K. H.; Scherb, F.; Mierkiewicz, E. J.

    1997-07-01

    We report on photopolarimetric observations of resonant emission from Carbon [CI(1657 Angstroms)] and scattered solar continuum from dust at 2800 Angstroms using the Wisconsin Imaging Survey Polarimeter (WISP). The WISP is a wide field (1.5deg x 4.8deg ) sounding rocket telescope originally designed for polarimetric observations of diffuse galactic light at a 1% photometric level. We will describe the initial results of our launch on 8 April, 1997 from the White Sands Missile range, including a discussion of the images obtained, and the results from supporting visible/near-infrared measurements of gas and dust from the Burrell Schmidt telescope, and spectroscopic observations of the CI(9850 Angstroms) metastable line from the McMath Pierce Solar Telescope. This research was supported by NASA grant NAG5-5091 and NSF grant AST-9615625.

  4. On Shocks Driven by High-mass Planets in Radiatively Inefficient Disks. III. Observational Signatures in Thermal Emission and Scattered Light

    NASA Astrophysics Data System (ADS)

    Hord, Blake; Lyra, Wladimir; Flock, Mario; Turner, Neal J.; Mac Low, Mordecai-Mark

    2017-11-01

    Recent observations of the protoplanetary disk around the Herbig Be star HD 100546 show two bright features in infrared (H and {L}{\\prime } bands) at about 50 au,with one so far unexplained. We explore the observational signatures of a high-mass planet causing shock heating in order to determine if it could be the source of the unexplained infrared feature in HD 100546. More fundamentally, we identify and characterize planetary shocks as an extra, hitherto ignored, source of luminosity in transition disks. The RADMC-3D code is used to perform dust radiative transfer calculations on the hydrodynamical disk models, including volumetric heating. A stronger shock heating rate by a factor of 20 would be necessary to qualitatively reproduce the morphology of the second infrared source. Instead, we find that the outer edge of the gap carved by the planet heats up by about 50% relative to the initial reference temperature, which leads to an increase in the scale height. The bulge is illuminated by the central star, producing a lopsided feature in scattered light, as the outer gap edge shows an asymmetry in density and temperature attributable to a secondary spiral arm launched not from the Lindblad resonances but from the 2:1 resonance. We conclude that high-mass planets lead to shocks in disks that may be directly observed, particularly at wavelengths of 10 μm or longer, but that they are more likely to reveal their presence in scattered light by puffing up their outer gap edges and exciting multiple spiral arms.

  5. SU-F-T-166: On the Nature of the Background Visible Light Observed in Fiber Optic Dosimetry of Proton Beams

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Darafsheh, A; Kassaee, A; Finlay, J

    Purpose: The nature of the background visible light observed during fiber optic dosimetry of proton beams, whether it is due to Cherenkov radiation or not, has been debated in the literature recently. In this work, experimentally and by means of Monte Carlo simulations, we shed light on this problem and investigated the nature of the background visible light observed in fiber optics irradiated with proton beams. Methods: A bare silica fiber optics was embedded in tissue-mimicking phantoms and irradiated with clinical proton beams with energies of 100–225 MeV at Roberts Proton Therapy Center. Luminescence spectroscopy was performed by a CCD-coupledmore » spectrograph to analyze in detail the emission spectrum of the fiber tip across the visible range of 400–700 nm. Monte Carlo simulation was performed by using FLUKA Monte Carlo code to simulate Cherenkov light and ionizing radiation dose deposition in the fiber. Results: The experimental spectra of the irradiated silica fiber shows two distinct peaks at 450 and 650 nm, whose spectral shape is different from that of Cherenkov radiation. We believe that the nature of these peaks are connected to the point defects of silica including oxygen-deficiency center (ODC) and non-bridging oxygen hole center (NBOHC). Monte Carlo simulations confirmed the experimental observations that Cherenkov radiation cannot be solely responsible for such a signal. Conclusion: We showed that Cherenkov radiation is not the dominant visible signal observed in bare fiber optics irradiated with proton beams. We observed two distinct peaks at 450 and 650 nm whose nature is connected with the point defects of silica fiber including oxygen-deficiency center and non-bridging oxygen hole center.« less

  6. Infrared observations of RS CVn stars

    NASA Technical Reports Server (NTRS)

    Berriman, G.; De Campli, W. M.; Werner, M. W.; Hatchett, S. P.

    1983-01-01

    The paper presents infrared photometry of the RS CVn binary stars AR Lac (1.2-10 microns) and MM Her (1.2-3.5 microns) as they egressed from their primary and secondary eclipses; of the eclipsing systems RS CVn and Z Her at maximum light (1.2-10 microns) and of the non-eclipsing systems UX Ari and HR 1099 (1.2-10 microns). An analysis of these and published V data based on flux ratio diagrams (linear analogues of color-color diagrams) shows that G and K stars supply the infrared light of these systems. In AR Lac, the combined light of a G5-K0 subgiant and either a late F dwarf or an early F subgiant can account for the observed visual and infrared light curves. None of these systems shows infrared emission from circumstellar matter. This result is simply understood: dust grains would not be expected to form in the physical conditions surrounding the subgiant, and the corona and chromosphere (whose properties have been deduced from spectroscopic X-ray observations) should not produce appreciable infrared emission.

  7. Comparison of BRDF-Predicted and Observed Light Curves of GEO Satellites

    NASA Astrophysics Data System (ADS)

    Ceniceros, A.; Dao, P.; Gaylor, D.; Rast, R.; Anderson, J.; Pinon, E., III

    Although the amount of light received by sensors on the ground from Resident Space Objects (RSOs) in geostationary orbit (GEO) is small, information can still be extracted in the form of light curves (temporal brightness or apparent magnitude). Previous research has shown promising results in determining RSO characteristics such as shape, size, reflectivity, and attitude by processing simulated light curve data with various estimation algorithms. These simulated light curves have been produced using one of several existing analytic Bidirectional Reflectance Distribution Function (BRDF) models. These BRDF models have generally come from researchers in computer graphics and machine vision and have not been shown to be realistic for telescope observations of RSOs in GEO. While BRDFs have been used for SSA analysis and characterization, there is a lack of research on the validation of BRDFs with regards to real data. In this paper, we compared telescope data provided by the Air Force Research Laboratory (AFRL) with predicted light curves from the Ashikhmin-Premoze BRDF and two additional popular illumination models, Ashikhmin-Shirley and Cook-Torrance. We computed predicted light curves based on two line mean elements (TLEs), shape model, attitude profile, observing ground station location, observation time and BRDF. The predicted light curves were then compared with AFRL telescope data. The selected BRDFS provided accurate apparent magnitude trends and behavior, but uncertainties due to lack of attitude information and deficiencies in our satellite model prevented us from obtaining a better match to the real data. The current findings present a foundation for ample future research.

  8. Effects of cold temperature and ethanol content on VOC emissions from light-duty gasoline vehicles

    EPA Science Inventory

    Emissions of speciated volatile organic compounds (VOCs), including mobile source air toxics (MSATs), were measured in vehicle exhaust from three light-duty spark ignition vehicles operating on summer and winter grade gasoline (E0) and ethanol blended (E10 and E85) fuels. Vehicle...

  9. Real-time black carbon emission factors of light-duty vehicles tested on a chassis dynamometer

    NASA Astrophysics Data System (ADS)

    Forestieri, S. D.; Cappa, C. D.; Kuwayama, T.; Collier, S.; Zhang, Q.; Kleeman, M. J.

    2012-12-01

    Eight light-duty gasoline vehicles were tested on a Chassis dynamometer using the California Unified Driving Cycle (UDC) at the Haagen-Smit vehicle test facility at the California Air Resources Board (CARB) in El Monte, CA during September 2011. In addition, one light-duty gasoline vehicle, one ultra low-emission vehicle, one diesel passenger vehicle, and one gasoline direct injection vehicle were tested on a constant velocity driving cycle. Vehicle exhaust was diluted through CARB's CVS tunnel and a secondary dilution system in order to examine particulate matter (PM) emissions at atmospherically relevant concentrations (5-30 μg-m3). A variety of real-time instrumentation was used to characterize how the major PM components vary during a typical driving cycle, which includes a cold start phase followed by a hot stabilized running phase. Aerosol absorption coefficients were obtained at 532 nm and 405 nm with a time resolution of 2 seconds from a photo-acoustic spectrometer. These absorption coefficients were then converted to black carbon (BC) concentrations via a mass absorption coefficient. Non-refractory organic and inorganic PM and CO2 concentrations were quantified with a time resolution of 10 seconds using a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS). Real-time BC and CO2 concentrations allowed for the determination of BC emission factors (EFs), providing insights into the variability of BC EFs during different phases of a typical driving cycle and aiding in the modeling BC emissions.

  10. Coronal mass ejection kinematics deduced from white light (Solar Mass Ejection Imager) and radio (Wind/WAVES) observations

    NASA Astrophysics Data System (ADS)

    Reiner, M. J.; Jackson, B. V.; Webb, D. F.; Mizuno, D. R.; Kaiser, M. L.; Bougeret, J.-L.

    2005-09-01

    White-light and radio observations are combined to deduce the coronal and interplanetary kinematics of a fast coronal mass ejection (CME) that was ejected from the Sun at about 1700 UT on 2 November 2003. The CME, which was associated with an X8.3 solar flare from W56°, was observed by the Mauna Loa and Solar and Heliospheric Observatory (SOHO) Large-Angle Spectrometric Coronograph (LASCO) coronagraphs to 14 R⊙. The measured plane-of-sky speed of the LASCO CME was 2600 km s-1. To deduce the kinematics of this CME, we use the plane-of-sky white light observations from both the Solar Mass Ejection Imager (SMEI) all-sky camera on board the Coriolis spacecraft and the SOHO/LASCO coronagraph, as well as the frequency drift rate of the low-frequency radio data and the results of the radio direction-finding analysis from the WAVES experiment on the Wind spacecraft. In agreement with the in situ observations for this event, we find that both the white light and radio observations indicate that the CME must have decelerated significantly beginning near the Sun and continuing well into the interplanetary medium. More specifically, by requiring self-consistency of all the available remote and in situ data, together with a simple, but not unreasonable, assumption about the general characteristic of the CME deceleration, we were able to deduce the radial speed and distance time profiles for this CME as it propagated from the Sun to 1 AU. The technique presented here, which is applicable to mutual SMEI/WAVES CME events, is expected to provide a more complete description and better quantitative understanding of how CMEs propagate through interplanetary space, as well as how the radio emissions, generated by propagating CME/shocks, relate to the shock and CME. This understanding can potentially lead to more accurate predictions for the onset times of space weather events, such as those that were observed during this unique period of intense solar activity.

  11. Observations of the auroral hectometric radio emission onboard the INTERBALL-1 satellite

    NASA Astrophysics Data System (ADS)

    Kuril'Chik, V. N.

    2007-06-01

    The results of five-year (1995 2000) continuous observations of the auroral radio emission (ARE) in the hectometric wavelength range on the high-apogee INTERBALL-1 satellite are presented. Short intense bursts of the auroral hectometric radio emission (AHR) were observed at frequencies of 1463 and 1501 kHz. The bursts were observed predominantly at times when the terrestrial magnetosphere was undisturbed (in the quiet Sun period), and their number decreased rapidly with increasing solar activity. The bursts demonstrated seasonal dependence in the Northern and Southern hemispheres (dominating in the autumn-winter period). Their appearance probably depends on the observation time (UT). A qualitative explanation of the AHR peculiarities is given.

  12. On-board emission measurement of high-loaded light-duty vehicles in Algeria.

    PubMed

    Boughedaoui, Ménouèr; Kerbachi, Rabah; Joumard, Robert

    2008-01-01

    A sample of eight private gasoline and diesel conventional light-duty vehicles (LDVs) in use with various ages, carrying a load of 460 kg, were tested on a representative trip in the traffic flow of the city of Blida to obtain emission factors representing the actual use conditions of Algerian LDVs. The gas sampling system (mini-constant volume sampling) as well as the analyzers are carried on-board the vehicle. Around 55 tests were conducted during 3 months covering more than 480 km under various real driving conditions. The mean speed downtown is about 16.1 km/hr with a rather low acceleration, an average of 0.60 m/sec2. For each test, kinematics are recorded as well as the analysis of the four emitted pollutants carbon dioxide, carbon monoxide, oxides of nitrogen, and total hydrocarbons. Emission factors were evaluated according to speed for each category of gasoline and diesel engines. The influence of some parameters such as cold/hot start, age of vehicle and its state of maintenance are discussed. Results are compared with the European database ARTEMIS for comparable vehicles. These measurements contribute to the development of unit emission of the vehicles used in Algeria, which are necessary for the calculation of emission inventory of pollutants and greenhouse gases from the road transportation sector. The unit emissions constitute a tool of decisionmaking aid regarding the conception of new regulations of vehicle control and inspection in Algeria and even in similar developing countries.

  13. Tunable blue organic light emitting diode based on aluminum calixarene supramolecular complex

    NASA Astrophysics Data System (ADS)

    Legnani, C.; Reyes, R.; Cremona, M.; Bagatin, I. A.; Toma, H. E.

    2004-07-01

    In this letter, the results of supramolecular organic light emitting diodes using a calix[4] arene complex thin film as emitter and electron transporting layer are presented. The devices were grown onto glass substrates coated with indium-tin-oxide layer and aluminum thick (150nm) cathode. By applying a dc voltage between the device electrodes in forward bias condition, a blue light emission in the active area of the device was observed. It was found that the electroluminescent emission peak can be tuned between 470 and 510nm changing the applied voltage bias from 4.3 to 5.4V. The observed tunable emission can be associated with an energy transfer from the calixarene compound.

  14. Experimental investigation on NOx and green house gas emissions from a marine auxiliary diesel engine using ultralow sulfur light fuel.

    PubMed

    Geng, Peng; Tan, Qinming; Zhang, Chunhui; Wei, Lijiang; He, Xianzhong; Cao, Erming; Jiang, Kai

    2016-12-01

    In recent years, marine auxiliary diesel engine has been widely used to produce electricity in the large ocean-going ship. One of the main technical challenges for ocean-going ship is to reduce pollutant emissions from marine auxiliary diesel engine and to meet the criteria of disposal on ships pollutants of IMO (International Maritime Organization). Different technical changes have been introduced in marine auxiliary diesel engine to apply clean fuels to reduce pollutant emissions. The ultralow sulfur light fuel will be applied in diesel engine for emission reductions in China. This study is aimed to investigate the impact of fuel (ultralow sulfur light fuel) on the combustion characteristic, NOx and green house gas emissions in a marine auxiliary diesel engine, under the 50%-90% engine speeds and the 25%-100% engine torques. The experimental results show that, in the marine auxiliary diesel engine, the cylinder pressure and peak heat release rate increase slightly with the increase of engine torques, while the ignition advances and combustion duration become longer. With the increases of the engine speed and torque, the fuel consumption decreases significantly, while the temperature of the exhaust manifold increases. The NOx emissions increase significantly with the increases of the engine speed and torque. The NO emission increases with the increases of the engine speed and torque, while the NO 2 emission decreases. Meanwhile, the ratio of NO 2 and NO is about 1:1 when the diesel engine operated in the low speed and load, while the ratio increases significantly with the increases of engine speed and torque, due to the increase of the cylinder temperature in the diffusive combustion mode. Moreover, the CO 2 emission increases with the increases of engine speed and torque by the use of ultralow sulfur light fuel. Copyright © 2016. Published by Elsevier B.V.

  15. Biogenic nonmethane hydrocarbon emissions estimated from tethered balloon observations

    NASA Technical Reports Server (NTRS)

    Davis, K. J.; Lenschow, D. H.; Zimmerman, P. R.

    1994-01-01

    A new technique for estimating surface fluxes of trace gases, the mixed-layer gradient technique, is used to calculate isoprene and terpene emissions from forests. The technique is applied to tethered balloon measurements made over the Amazon forest and a pine-oak forest in Alabama at altitudes up to 300 m. The observations were made during the dry season Amazon Boundary Layer Experiment (ABLE 2A) and the Rural Oxidants in the Southern Environment 1990 experiment (ROSE I). Results from large eddy simulations of scalar transport in the clear convective boundary layer are used to infer fluxes from the balloon profiles. Profiles from the Amazon give a mean daytime emission of 3630 +/- 1400 micrograms isoprene sq m/h, where the uncertainty represents the standard deviation of the mean of eight flux estimates. Twenty profiles from Alabama give emissions of 4470 +/- 3300 micrograms isoprene sq m/h, 1740 +/- 1060 micrograms alpha-pinene sq m/h, and 790 +/- 560 micrograms beta-pinene sq m/h, respectively. These results are in agreement with emissions derived from chemical budgets. The emissions may be overestimated because of uncertainty about how to incorporate the effects of the canopy on the mixed-layer gradients. The large variability in these emission estimates is probably due to the relatively short sampling times of the balloon profiles, though spatially heterogeneous emissions may also play a role. Fluxes derived using this technique are representative of an upwind footprint of several kilometers and are independent of hydrocarbon oxidation rate and mean advection.

  16. Kinetics of ultraweak light emission from human erythroleukemia K562 cells upon electroporation.

    PubMed

    Maccarrone, M; Fantini, C; Agrò, A F; Rosato, N

    1998-11-11

    Electroporation involves the application of an electric pulse that creates transient aqueous channels (electropores) across the lipid bilayer membranes. Here, we describe an instrument set up suitable to record ultraweak light emission from human erythroleukemia K562 cells during and immediately after delivery of electric pulses. Most of light was emitted in the first seconds after each pulse, following a complex decay which can be fitted by a double exponential equation characterized by two different time constants (T1 and T2), both in the order of seconds. T1 was approximately 10-fold shorter than T2 and both time constants were dependent on field strength of the electric pulse. The effect of various antioxidants on the amount of emitted photons and on T1 and T2 values was investigated, in order to shed some light on the chemical species responsible for cellular luminescence.

  17. Prompt optical emission from gamma-ray bursts with multiple timescale variability of central engine activities

    NASA Astrophysics Data System (ADS)

    Xu, Si-Yao; Li, Zhuo

    2014-04-01

    Complete high-resolution light curves of GRB 080319B observed by Swift present an opportunity for detailed temporal analysis of prompt optical emission. With a two-component distribution of initial Lorentz factors, we simulate the dynamical process of shells being ejected from the central engine in the framework of the internal shock model. The emitted radiations are decomposed into different frequency ranges for a temporal correlation analysis between the light curves in different energy bands. The resulting prompt optical and gamma-ray emissions show similar temporal profiles, with both showing a superposition of a component with slow variability and a component with fast variability, except that the gamma-ray light curve is much more variable than its optical counterpart. The variability in the simulated light curves and the strong correlation with a time lag between the optical and gamma-ray emissions are in good agreement with observations of GRB 080319B. Our simulations suggest that the variations seen in the light curves stem from the temporal structure of the shells injected from the central engine of gamma-ray bursts. Future observations with high temporal resolution of prompt optical emission from GRBs, e.g., by UFFO-Pathfinder and SVOM-GWAC, will provide a useful tool for investigating the central engine activity.

  18. Global oceanic emission of ammonia: Constraints from seawater and atmospheric observations

    NASA Astrophysics Data System (ADS)

    Paulot, F.; Jacob, D. J.; Johnson, M. T.; Bell, T. G.; Baker, A. R.; Keene, W. C.; Lima, I. D.; Doney, S. C.; Stock, C. A.

    2015-08-01

    Current global inventories of ammonia emissions identify the ocean as the largest natural source. This source depends on seawater pH, temperature, and the concentration of total seawater ammonia (NHx(sw)), which reflects a balance between remineralization of organic matter, uptake by plankton, and nitrification. Here we compare [NHx(sw)] from two global ocean biogeochemical models (BEC and COBALT) against extensive ocean observations. Simulated [NHx(sw)] are generally biased high. Improved simulation can be achieved in COBALT by increasing the plankton affinity for NHx within observed ranges. The resulting global ocean emissions is 2.5 TgN a-1, much lower than current literature values (7-23 TgN a-1), including the widely used Global Emissions InitiAtive (GEIA) inventory (8 TgN a-1). Such a weak ocean source implies that continental sources contribute more than half of atmospheric NHx over most of the ocean in the Northern Hemisphere. Ammonia emitted from oceanic sources is insufficient to neutralize sulfate aerosol acidity, consistent with observations. There is evidence over the Equatorial Pacific for a missing source of atmospheric ammonia that could be due to photolysis of marine organic nitrogen at the ocean surface or in the atmosphere. Accommodating this possible missing source yields a global ocean emission of ammonia in the range 2-5 TgN a-1, comparable in magnitude to other natural sources from open fires and soils.

  19. Study of Sequential Dexter Energy Transfer in High Efficient Phosphorescent White Organic Light-Emitting Diodes with Single Emissive Layer

    NASA Astrophysics Data System (ADS)

    Kim, Jin Wook; You, Seung Il; Kim, Nam Ho; Yoon, Ju-An; Cheah, Kok Wai; Zhu, Fu Rong; Kim, Woo Young

    2014-11-01

    In this study, we report our effort to realize high performance single emissive layer three color white phosphorescent organic light emitting diodes (PHOLEDs) through sequential Dexter energy transfer of blue, green and red dopants. The PHOLEDs had a structure of; ITO(1500 Å)/NPB(700 Å)/mCP:Firpic-x%:Ir(ppy)3-0.5%:Ir(piq)3-y%(300 Å)/TPBi(300 Å)/Liq(20 Å)/Al(1200 Å). The dopant concentrations of FIrpic, Ir(ppy)3 and Ir(piq)3 were adjusted and optimized to facilitate the preferred energy transfer processes attaining both the best luminous efficiency and CIE color coordinates. The presence of a deep trapping center for charge carriers in the emissive layer was confirmed by the observed red shift in electroluminescent spectra. White PHOLEDs, with phosphorescent dopant concentrations of FIrpic-8.0%:Ir(ppy)3-0.5%:Ir(piq)3-0.5% in the mCP host of the single emissive layer, had a maximum luminescence of 37,810 cd/m2 at 11 V and a luminous efficiency of 48.10 cd/A at 5 V with CIE color coordinates of (0.35, 0.41).

  20. A time dependent approach to model X-ray and γ-ray light curves of Mrk 421 observed during the flare in February 2010

    NASA Astrophysics Data System (ADS)

    Singh, K. K.; Sahayanathan, S.; Sinha, A.; Bhatt, N.; Tickoo, A. K.; Yadav, K. K.; Rannot, R. C.; Chandra, P.; Venugopal, K.; Marandi, P.; Kumar, N.; Goyal, H. C.; Goyal, A.; Agarwal, N. K.; Kothari, M.; Chanchalani, K.; Dhar, V. K.; Chouhan, N.; Bhat, C. K.; Koul, M. K.; Koul, R.

    2017-07-01

    Strong X-ray and γ-ray flares have been detected in February 2010 from the high synchrotron peaked blazar Mrk 421 (z = 0.031). With the motivation of understanding the physics involved in this flaring activity, we study the variability of the source in X-ray and γ-ray energy bands during the period February 10-23, 2010 (MJD 55237-55250). We use near simultaneous X-ray data collected by MAXI, Swift-XRT and γ-ray data collected by Fermi-LAT and TACTIC along with the optical V-band observations by SPOLat Steward Observatory. We observe that the variation in the one day averaged flux from the source during the flare is characterized by fast rise and slow decay. Besides, the TeV γ-ray flux shows a strong correlation with the X-ray flux, suggesting the former to be an outcome of synchrotron self Compton emission process. To model the observed X-ray and γ-ray light curves, we numerically solve the kinetic equation describing the evolution of particle distribution in the emission region. The injection of particle distribution into the emission region, from the putative acceleration region, is assumed to be a time dependent power law. The synchrotron and synchrotron self Compton emission from the evolving particle distribution in the emission region are used to reproduce the X-ray and γ-ray flares successfully. Our study suggests that the flaring activity of Mrk 421 can be an outcome of an efficient acceleration process associated with the increase in underlying non-thermal particle distribution.