Kinetic study of olive oil degradation monitored by fourier transform infrared spectrometry. Application to oil characterization.

PubMed

Román Falcó, Iván P; Grané Teruel, Nuria; Prats Moya, Soledad; Martín Carratalá, M Luisa

2012-11-28

A new approach for the determination of kinetic parameters of the cis/trans isomerization during the oxidation process of 24 virgin olive oils belonging to 8 different varieties is presented. The accelerated process of degradation at 100 °C was monitored by recording the Fourier transform infrared spectra. The parameters obtained confirm pseudo-first-order kinetics for the degradation of cis and the appearance of trans double bonds. The kinetic approach affords the induction time and the rate coefficient; these parameters are related to the fatty acid profile of the fresh olive oils. The data obtained were used to compare the oil stability of the samples with the help of multivariate statistical techniques. Fatty acid allowed a classification of the samples in five groups, one of them constituted by the cultivars with higher stability. Meanwhile, the kinetic parameters showed greater ability for the characterization of olive oils, allowing the classification in seven groups.

Low-Cost Oil Quality Sensor Based on Changes in Complex Permittivity

PubMed Central

Pérez, Angel Torres; Hadfield, Mark

2011-01-01

Real time oil quality monitoring techniques help to protect important industry assets, minimize downtime and reduce maintenance costs. The measurement of a lubricant’s complex permittivity is an effective indicator of the oil degradation process and it can be useful in condition based maintenance (CBM) to select the most adequate oil replacement maintenance schedules. A discussion of the working principles of an oil quality sensor based on a marginal oscillator to monitor the losses of the dielectric at high frequencies (>1 MHz) is presented. An electronic design procedure is covered which results in a low cost, effective and ruggedized sensor implementation suitable for use in harsh environments. PMID:22346666

Satellite Monitoring of the Northern Territories Disturbed by Oil Production

NASA Astrophysics Data System (ADS)

Bondur, V. G.; Vorobyev, V. E.; Lukin, A. A.

2017-12-01

The results of satellite monitoring of the state of northern territories disturbed by oil production are presented by the example of the Usinsk oil field in the Komi Republic. The sets of vegetation indices formed by the results of processing long-term series of multispectral satellite images for the period from 1988 to 2014 are analyzed. They are used to assess long-term environmental changes, to reveal the most disturbed zones, and to estimate the dynamics of changes in the vegetation cover area caused by the extraction and transportation of hydrocarbons.

InSAR Monitoring of Surface Deformation in Alberta's Oil Sands

NASA Astrophysics Data System (ADS)

Pearse, J.; Singhroy, V.; Li, J.; Samsonov, S. V.; Shipman, T.; Froese, C. R.

2013-05-01

Alberta's oil sands are among the world's largest deposits of crude oil, and more than 80% of it is too deep to mine, so unconventional in-situ methods are used for extraction. Most in situ extraction techniques, such as Steam-Assisted Gravity Drainage (SAGD), use steam injection to reduce the viscosity of the bitumen, allowing it to flow into wells to be pumped to the surface. As part of the oil sands safety and environmental monitoring program, the energy regulator uses satellite radar to monitor surface deformation associated with in-situ oil extraction. The dense vegetation and sparse infrastructure in the boreal forest of northern Alberta make InSAR monitoring a challenge; however, we have found that surface heave associated with steam injection can be detected using traditional differential InSAR. Infrastructure and installed corner reflectors also allow us to use persistent scatterer methods to obtain time histories of deformation at individual sites. We have collected and processed several tracks of RADARSAT-2 data over a broad area of the oil sands, and have detected surface deformation signals of approximately 2-3 cm per year, with time series that correlate strongly with monthly SAGD steam injection volumes.

Real-time oil-saturation monitoring in rock cores with low-field NMR.

PubMed

Mitchell, J; Howe, A M; Clarke, A

2015-07-01

Nuclear magnetic resonance (NMR) provides a powerful suite of tools for studying oil in reservoir core plugs at the laboratory scale. Low-field magnets are preferred for well-log calibration and to minimize magnetic-susceptibility-induced internal gradients in the porous medium. We demonstrate that careful data processing, combined with prior knowledge of the sample properties, enables real-time acquisition and interpretation of saturation state (relative amount of oil and water in the pores of a rock). Robust discrimination of oil and brine is achieved with diffusion weighting. We use this real-time analysis to monitor the forced displacement of oil from porous materials (sintered glass beads and sandstones) and to generate capillary desaturation curves. The real-time output enables in situ modification of the flood protocol and accurate control of the saturation state prior to the acquisition of standard NMR core analysis data, such as diffusion-relaxation correlations. Although applications to oil recovery and core analysis are demonstrated, the implementation highlights the general practicality of low-field NMR as an inline sensor for real-time industrial process control. Copyright © 2015 Elsevier Inc. All rights reserved.

Monitoring automotive oil degradation: analytical tools and onboard sensing technologies.

PubMed

Mujahid, Adnan; Dickert, Franz L

2012-09-01

Engine oil experiences a number of thermal and oxidative phases that yield acidic products in the matrix consequently leading to degradation of the base oil. Generally, oil oxidation is a complex process and difficult to elucidate; however, the degradation pathways can be defined for almost every type of oil because they mainly depend on the mechanical status and operating conditions. The exact time of oil change is nonetheless difficult to predict, but it is of great interest from an economic and ecological point of view. In order to make a quick and accurate decision about oil changes, onboard assessment of oil quality is highly desirable. For this purpose, a variety of physical and chemical sensors have been proposed along with spectroscopic strategies. We present a critical review of all these approaches and of recent developments to analyze the exact lifetime of automotive engine oil. Apart from their potential for degradation monitoring, their limitations and future perspectives have also been investigated.

Oil-shale program

NASA Astrophysics Data System (ADS)

Bader, B. E.

1981-10-01

The principal activities of the Sandia National Laboratories in the Department of Energy Oil shale program during the period April 1 to June 30, 1981 are discussed. Currently, Sandia's activities are focused upon: the development and use of analytical and experimental modeling techniques to describe and predict the retort properties and retorting process parameters that are important to the preparation, operation, and stability of in situ retorts, and the development, deployment, and field use of instrumentation, data acquisition, and process monitoring systems to characterize and evaluate in site up shale oil recovery operations. In-house activities and field activities (at the Geokinetics Oil Shale Project and the Occidental Oil Shale Project) are described under the headings: bed preparation, bed characterization, retorting process, and structural stability.

Remote Sensing Application in Oil and Gas Industry

NASA Astrophysics Data System (ADS)

Sizov, Oleg; Aloltsov, Alexander; Rubtsova, Natalia

2014-05-01

The main environmental problems of the Khanty-Mansi Autonomous Okrug (a federal subject of Russia) related to the activities of oil and gas industry (82 active companies which hold 77,000 oil wells). As on the 1st of January 2013 the subject produces more than 50% of all oil in Russia. The principle of environmental responsibility makes it necessary to minimize human impact and ecological impact. One of the most effective tools for environmental monitoring is remote sensing. The main advantages of such approach are: wide coverage of areas of interest, high temporal resolution, precise location, automatic processing, large set of extracted parameters, etc. Authorities of KhMAO are interested in regular detection of the impact on the environment by processing satellite data and plan to increase the coverage from 434.9 to 659.9 square kilometers with resolution not less than 10 m/pixel. Years of experience of our company shows the significant potential to expand the use of such remote sensing data in the solution of environmental problems. The main directions are: monitoring of rational use of associated petroleum gas (detection of all gas flares and volumes of burned gas), monitoring of soil pollution (detection of areas of oil pollution, assess of the extent of pollution, planning of reclamation activities and assessment of their efficiency, detection of potential areas of pipelines corrosion), monitoring of status of sludge pits (inventory of all sludge pits, assessment of their liquidation), monitoring of technogenic impact (detection of changes), upgrading of a geospatial database (topographic map of not less than 1:50000 scale). Implementation of modeling, extrapolation and remote analysis techniques based on satellite images will help to reduce unnecessary costs for instrumental methods. Thus, the introduction of effective remote monitoring technology to the activity of oil and gas companies promotes environmental responsibility of these companies.

On-Line Analyzer For Monitoring Trace Amounts Of Oil In Turbid Waters

NASA Astrophysics Data System (ADS)

Niemela, P.; Jaatinen, J.

1986-05-01

This report presents an automated analyzer which continuously monitors oil content of a sample water stream that flows through the analyzer. The measuring principle is based on the absorption of infrared radiation by oil molecules contained in the sample water. The wavelength band that is used in the measurement is at 3.4 μm, where different types of oils show nearly equal absorption. Another wavelength band of 3.6 μm, where oil has no absorption, is used to compensate the effect of turbidity, which is due to solid particles and oil droplets contained in the sample water. Before entering the analyzer the sample water flow is properly homogenized. To compensate the strong absorption by water molecules in these wavelength bands the sample water is compared with reference water. This is done by directing them alternately through the same measuring cell. The reference water is obtained from the sample water by ultrafiltration and it determines the base line for the contaminated sample water. To ensure the stability of the base line, temperature and pressure differences of the two waters are kept within adequate ranges. Areas of application of the analyzer are wide ranging i.a. from ships' discharge waters to waste waters of industrial processes. The first application of the analyzer is on board oil tankers to control the discharge process of bilge and ballast waters. The analyzer is the first that fully corresponds to the stringent regulations for oil content monitors by the International Maritime Organization (IMO). Pilot installations of the analyzer are made on industrial plants.

An on-line monitoring system for oil-film, pressure and temperature distributions in large-scale hydro-generator bearings

NASA Astrophysics Data System (ADS)

Höbel, M.; Haffner, K.

1999-05-01

Instrumentation that allows the behaviour of a hydro-generator thrust bearing to be monitored during operation is described. The measurement system was developed at the Asea Brown Boveri corporate research centre in Switzerland and was tested under realistic operating conditions at the Harbin Electric Machinery Company bearing-testing facility in the People's Republic of China. Newly developed fibre-optical proximity probes were used for the on-line monitoring of the thin oil film between the static and rotating parts of the bearing. These sensors are based on a back-reflection technique and can be used for various target materials such as Babbitt and Teflon. The monitoring system comprises about 120 temperature sensors, four pressure sensors and five optical oil-film thickness sensors. Temperature sensors are installed at specific static locations, whereas pressure and oil-film sensors are positioned in the runner and generate data during rotation. A special feature of the monitoring equipment is its on-line processing capability. Digital signal processors operating in parallel handle pressure and oil-film thickness data. Important measurement parameters such as the maximum pressure, maximum temperature and minimum oil-film thickness are displayed on-line. Detailed three-dimensional temperature information on one of the load segments can be obtained from subsequent off-line data analysis. The system also calculates two-dimensional plots of the oil-film thickness and pressure for most of the 12 load segments.

Long Term Geoelectrical Monitoring of Deep-water Horizon Oil Spill in the Gulf Coast

NASA Astrophysics Data System (ADS)

Heenan, J. W.; Ntarlagiannis, D.; Slater, L. D.; Atekwana, E. A.; Ross, C.; Nolan, J. T.; Atekwana, E. A.

2011-12-01

In the aftermath of the catastrophic Deep-water Horizon (DWH) spill in the Gulf Coast, opportunities exist to study the evolution of fresh crude oil contamination in beach sediments and marshes. Grand Terre 1 Island, off the coast of Grand Isle in southern Louisiana, is an uninhabited barrier island, heavily impacted by the DWH spill, and ideal for undisturbed long term monitoring of crude oil degradation processes. A 10 channel Syscal-Pro resistivity / IP instrument (IRIS Instruments, France) is the heart of the fully autonomous geoelectrical monitoring system; the system, which is housed in a weatherproof container, relies solely on solar power, is controlled by an energy efficient PC and can be accessed remotely via web tools. The monitoring scheme involves collecting bi-daily resistivity measurements from surface and shallow boreholes, ranging from January 2011 to the present; environmental parameters, such as T, are continuously recorded at several depths. During regular field trips we perform larger scale geophysical surveys, and geochemical measurements (pH, DO, T, fluid C) to support the continuous geophysical monitoring. The contaminated layer on site is a visually distinctive layer of crude oil, isolated by cleaner sands above and below which is identified by a clear and obvious resistive anomaly in preliminary surveys. Early results show a decrease in average of the resistance values of each dataset over time. Further processing of the data yields a linearly shaped resistive anomaly, which coincides with the location of the oil layer. The changes in subsurface resistivity appear to be focused within this anomaly. Time filtering of the data by the time that they were collected, morning or evening, reveals a diurnal variation. While both time frames follow the same overall trend, the measurements in the morning are slightly more resistive than those in the evening. This indicates that there are environmental factors, such as temperature, that need to be accounted for when analyzing the data for evidence of biological processes. These preliminary findings indicate changes in the subsurface properties of the contaminated area and suggest that geoelectrical methods are sensitive to contamination evolution processes. Such geophysical data, constrained by geochemical and microbiological information, have the potential to be used as a long term monitoring tool for biological and geochemical processes in the subsurface.

OPTICAL FIBER SENSOR TECHNOLOGIES FOR EFFICIENT AND ECONOMICAL OIL RECOVERY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anbo Wang; Kristie L. Cooper; Gary R. Pickrell

2003-06-01

Efficient recovery of petroleum reserves from existing oil wells has been proven to be difficult due to the lack of robust instrumentation that can accurately and reliably monitor processes in the downhole environment. Commercially available sensors for measurement of pressure, temperature, and fluid flow exhibit shortened lifetimes in the harsh downhole conditions, which are characterized by high pressures (up to 20 kpsi), temperatures up to 250 C, and exposure to chemically reactive fluids. Development of robust sensors that deliver continuous, real-time data on reservoir performance and petroleum flow pathways will facilitate application of advanced recovery technologies, including horizontal and multilateralmore » wells. This is the final report for the four-year program ''Optical Fiber Sensor Technologies for Efficient and Economical Oil Recovery'', funded by the National Petroleum Technology Office of the U.S. Department of Energy, and performed by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering at Virginia Tech from October 1, 1999 to March 31, 2003. The main objective of this research program was to develop cost-effective, reliable optical fiber sensor instrumentation for real-time monitoring of various key parameters crucial to efficient and economical oil production. During the program, optical fiber sensors were demonstrated for the measurement of temperature, pressure, flow, and acoustic waves, including three successful field tests in the Chevron/Texaco oil fields in Coalinga, California, and at the world-class oil flow simulation facilities in Tulsa, Oklahoma. Research efforts included the design and fabrication of sensor probes, development of signal processing algorithms, construction of test systems, development and testing of strategies for the protection of optical fibers and sensors in the downhole environment, development of remote monitoring capabilities allowing real-time monitoring of the field test data from virtually anywhere in the world, and development of novel data processing techniques. Comprehensive testing was performed to systematically evaluate the performance of the fiber optic sensor systems in both lab and field environments.« less

Quality monitoring of extra-virgin olive oil using an optical sensor

NASA Astrophysics Data System (ADS)

Mignani, A. G.; Ciaccheri, L.; Mencaglia, A. A.; Paolesse, R.; Di Natale, C.; Del Nobile, A.; Benedetto, A.; Mentana, A.

2006-04-01

An optical sensor for the detection of olive oil aroma is presented. It is capable of distinguishing different ageing levels of extra-virgin olive oils, and shows effective potential for achieving a non destructive olfactory perception of oil ageing. The sensor is an optical scanner, fitted with an array of metalloporphyrin-based sensors. The scanner provides exposure of the sensors to the flow of the oil vapor being tested, and their sequential spectral interrogation. Spectral data are then processed using chemometric methodologies.

Microfluidic Assessment of Frying Oil Degradation

PubMed Central

Liu, Mei; Xie, Shaorong; Ge, Ji; Xu, Zhensong; Wu, Zhizheng; Ru, Changhai; Luo, Jun; Sun, Yu

2016-01-01

Monitoring the quality of frying oil is important for the health of consumers. This paper reports a microfluidic technique for rapidly quantifying the degradation of frying oil. The microfluidic device generates monodispersed water-in-oil droplets and exploits viscosity and interfacial tension changes of frying oil samples over their frying/degradation process. The measured parameters were correlated to the total polar material percentage that is widely used in the food industry. The results reveal that the steady-state length of droplets can be used for unambiguously assessing frying oil quality degradation. PMID:27312884

Comprehensive near infrared study of Jatropha oil esterification with ethanol for biodiesel production

NASA Astrophysics Data System (ADS)

Oliveira, Alianda Dantas de; Sá, Ananda Franco de; Pimentel, Maria Fernanda; Pacheco, José Geraldo A.; Pereira, Claudete Fernandes; Larrechi, Maria Soledad

2017-01-01

This work presents a comprehensive near infrared study for in-line monitoring of the esterification reaction of high acid oils, such as Jatropha curcas oil, using ethanol. Parallel reactions involved in the process were carried out to select a spectral region that characterizes the evolution of the esterification reaction. Using absorbance intensities at 5176 cm- 1, the conversion and kinetic behaviors of the esterification reaction were estimated. This method was applied to evaluate the influence of temperature and catalyst concentration on the estimates of initial reaction rate and ester conversion as responses to a 22 factorial experimental design. Employment of an alcohol/oil ratio of 16:1, catalyst concentration of 1.5% w/w, and temperatures at 65 °C or 75 °C, made it possible to reduce the initial acidity from 18% to 1.3% w/w, which is suitable for transesterification of high free fatty acid oils for biodiesel production. Using the proposed analytical method in the esterification reaction of raw materials with high free fatty acid content for biodiesel makes the monitoring process inexpensive, fast, simple, and practical.

Isotopic insights into microbial sulfur cycling in oil reservoirs

PubMed Central

Hubbard, Christopher G.; Cheng, Yiwei; Engelbrekston, Anna; Druhan, Jennifer L.; Li, Li; Ajo-Franklin, Jonathan B.; Coates, John D.; Conrad, Mark E.

2014-01-01

Microbial sulfate reduction in oil reservoirs (biosouring) is often associated with secondary oil production where seawater containing high sulfate concentrations (~28 mM) is injected into a reservoir to maintain pressure and displace oil. The sulfide generated from biosouring can cause corrosion of infrastructure, health exposure risks, and higher production costs. Isotope monitoring is a promising approach for understanding microbial sulfur cycling in reservoirs, enabling early detection of biosouring, and understanding the impact of souring. Microbial sulfate reduction is known to result in large shifts in the sulfur and oxygen isotope compositions of the residual sulfate, which can be distinguished from other processes that may be occurring in oil reservoirs, such as precipitation of sulfate and sulfide minerals. Key to the success of this method is using the appropriate isotopic fractionation factors for the conditions and processes being monitored. For a set of batch incubation experiments using a mixed microbial culture with crude oil as the electron donor, we measured a sulfur fractionation factor for sulfate reduction of −30‰. We have incorporated this result into a simplified 1D reservoir reactive transport model to highlight how isotopes can help discriminate between biotic and abiotic processes affecting sulfate and sulfide concentrations. Modeling results suggest that monitoring sulfate isotopes can provide an early indication of souring for reservoirs with reactive iron minerals that can remove the produced sulfide, especially when sulfate reduction occurs in the mixing zone between formation waters (FW) containing elevated concentrations of volatile fatty acids (VFAs) and injection water (IW) containing elevated sulfate. In addition, we examine the role of reservoir thermal, geochemical, hydrological, operational and microbiological conditions in determining microbial souring dynamics and hence the anticipated isotopic signatures. PMID:25285094

33 CFR 157.12 - Oil discharge monitoring and control system.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Oil discharge monitoring and... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12 Oil discharge monitoring and control system. (a) Each vessel must have an oil discharge monitoring and control system (monitoring system) that...

33 CFR 157.12 - Oil discharge monitoring and control system.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Oil discharge monitoring and... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12 Oil discharge monitoring and control system. (a) Each vessel must have an oil discharge monitoring and control system (monitoring system) that...

33 CFR 157.12 - Oil discharge monitoring and control system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Oil discharge monitoring and... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12 Oil discharge monitoring and control system. (a) Each vessel must have an oil discharge monitoring and control system (monitoring system) that...

33 CFR 157.12 - Oil discharge monitoring and control system.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Oil discharge monitoring and... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12 Oil discharge monitoring and control system. (a) Each vessel must have an oil discharge monitoring and control system (monitoring system) that...

33 CFR 157.12 - Oil discharge monitoring and control system.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Oil discharge monitoring and... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12 Oil discharge monitoring and control system. (a) Each vessel must have an oil discharge monitoring and control system (monitoring system) that...

Blowout Monitor

NASA Technical Reports Server (NTRS)

1994-01-01

C Language Integrated Production System (CLIPS), a NASA-developed software shell for developing expert systems, has been embedded in a PC-based expert system for training oil rig personnel in monitoring oil drilling. Oil drilling rigs if not properly maintained for possible blowouts pose hazards to human life, property and the environment may be destroyed. CLIPS is designed to permit the delivery of artificial intelligence on computer. A collection of rules is set up and, as facts become known, these rules are applied. In the Well Site Advisor, CLIPS provides the capability to accurately process, predict and interpret well data in a real time mode. CLIPS was provided to INTEQ by COSMIC.

Automatic Measuring System for Oil Stream Paraffin Deposits Parameters

NASA Astrophysics Data System (ADS)

Kopteva, A. V.; Koptev, V. Yu

2018-03-01

This paper describes a new method for monitoring oil pipelines, as well as a highly efficient and automated paraffin deposit monitoring method. When operating oil pipelines, there is an issue of paraffin, resin and salt deposits on the pipeline walls that come with the oil stream. It ultimately results in frequent transportation suspension to clean or even replace pipes and other equipment, thus shortening operation periods between repairs, creating emergency situations and increasing production expenses, badly affecting environment, damaging ecology and spoil underground water, killing animals, birds etc. Oil spills contaminate rivers, lakes, and ground waters. Oil transportation monitoring issues are still subject for further studying. Thus, there is the need to invent a radically new automated process control and management system, together with measurement means intellectualization. The measurement principle is based on the Lambert-Beer law that describes the dependence between the gamma-radiation frequency and the density together with the linear attenuation coefficient for a substance. Using the measuring system with high accuracy (± 0,2%), one can measure the thickness of paraffin deposits with an absolute accuracy of ± 5 mm, which is sufficient to ensure reliable operation of the pipeline system. Safety is a key advantage, when using the proposed control system.

Monitoring of high refractive index edible oils using coated long period fiber grating sensors

NASA Astrophysics Data System (ADS)

Coelho, Luís.; Viegas, Diana; Santos, José Luís.; de Almeida, Jose Manuel M. M.

2015-05-01

Monitoring the quality of high refractive index edible oils is of great importance for the human health. Uncooked edible oils in general are healthy foodstuff, olive oil in particular, however, they are frequently used for baking and cooking. High quality edible oils are made from seeds, nuts or fruits by mechanical processes. Nevertheless, once the mechanical extraction is complete, up to 15% of the oil remains in oil pomace and in the mill wastewater, which can be extracted using organic solvents, often hexane. Optical fiber sensors based on long period fiber gratings (LPFG) have very low wavelength sensitivity when the surround refractive index is higher than the refractive index of the cladding. Titanium dioxide (TiO2) coated LPFG could lead to the realization of high sensitivity chemical sensor for the food industry. In this work LPFG coated with a TiO2 thin film were successfully used for to detect small levels of hexane diluted in edible oils and for real time monitoring the thermal deterioration of edible oils. For a TiO2 coating of 30 nm a wavelength sensitivity of 1361.7 nm/RIU (or 0.97 nm / % V/V) in the 1.4610-1.4670 refractive index range was achieved, corresponding to 0 to 12 % V/V of hexane in olive oil. A sensitivity higher than 638 nm/RIU at 225 ºC was calculated, in the 1.4670-1.4735 refractive index range with a detection limit of thermal deterioration of about 1 minute.

Microbial community dynamics during assays of harbour oil spill bioremediation: a microscale simulation study.

PubMed

Cappello, S; Caruso, G; Zampino, D; Monticelli, L S; Maimone, G; Denaro, R; Tripodo, B; Troussellier, M; Yakimov, M; Giuliano, L

2007-01-01

Microcosm experiments simulating an oil spill event were performed to evaluate the response of the natural microbial community structure of Messina harbour seawater following the accidental load of petroleum. An experimental harbour seawater microcosm, supplemented with nutrients and crude oil, was monitored above 15 days in comparison with unpolluted ones (control microcosms). Bacterial cells were counted with a Live/Dead BacLight viability kit; leucine aminopeptidase, beta-glucosidase, alkaline phosphatase, lipase and esterase enzymes were measured using fluorogenic substrates. The microbial community dynamic was monitored by isolation of total RNA, RT-PCR amplification of 16S rRNA, cloning and sequencing. Oil addition stimulated an increase of the total bacterial abundance, leucine aminopeptidase and phosphatase activity rates, as well as a change in the community structure. This suggested a prompt response of micro-organisms to the load of petroleum hydrocarbons. The present study on the viability, specific composition and metabolic characteristics of the microbial community allows a more precise assessment of oil pollution. Both structural and functional parameters offer interesting perspectives as indicators to monitor changes caused by petroleum hydrocarbons. A better knowledge of microbial structural successions at oil-polluted sites is essential for environmental bioremediation. Data obtained in microcosm studies improve our understanding of natural processes occurring during oil spills.

Geophysical monitoring technology for CO2 sequestration

NASA Astrophysics Data System (ADS)

Ma, Jin-Feng; Li, Lin; Wang, Hao-Fan; Tan, Ming-You; Cui, Shi-Ling; Zhang, Yun-Yin; Qu, Zhi-Peng; Jia, Ling-Yun; Zhang, Shu-Hai

2016-06-01

Geophysical techniques play key roles in the measuring, monitoring, and verifying the safety of CO2 sequestration and in identifying the efficiency of CO2-enhanced oil recovery. Although geophysical monitoring techniques for CO2 sequestration have grown out of conventional oil and gas geophysical exploration techniques, it takes a long time to conduct geophysical monitoring, and there are many barriers and challenges. In this paper, with the initial objective of performing CO2 sequestration, we studied the geophysical tasks associated with evaluating geological storage sites and monitoring CO2 sequestration. Based on our review of the scope of geophysical monitoring techniques and our experience in domestic and international carbon capture and sequestration projects, we analyzed the inherent difficulties and our experiences in geophysical monitoring techniques, especially, with respect to 4D seismic acquisition, processing, and interpretation.

Structural health monitoring of localized internal corrosion in high temperature piping for oil industry

NASA Astrophysics Data System (ADS)

Eason, Thomas J.; Bond, Leonard J.; Lozev, Mark G.

2015-03-01

Crude oil is becoming more corrosive with higher sulfur concentration, chloride concentration, and acidity. The increasing presence of naphthenic acids in oils with various environmental conditions at temperatures between 150°C and 400°C can lead to different internal degradation morphologies in refineries that are uniform, non-uniform, or localized pitting. Improved corrosion measurement technology is needed to better quantify the integrity risk associated with refining crude oils of higher acid concentration. This paper first reports a consolidated review of corrosion inspection technology to establish the foundation for structural health monitoring of localized internal corrosion in high temperature piping. An approach under investigation is to employ flexible ultrasonic thin-film piezoelectric transducer arrays fabricated by the sol-gel manufacturing process for monitoring localized internal corrosion at temperatures up to 400°C. A statistical analysis of sol-gel transducer measurement accuracy using various time of flight thickness calculation algorithms on a flat calibration block is demonstrated.

Interdisciplinary study of atmospheric processes and constituents of the mid-Atlantic coastal region. Attachment 3: Data set for Craney Island oil refinery installation experiment. [air pollution monitoring

NASA Technical Reports Server (NTRS)

Kindle, E. C.; Bandy, A.; Copeland, G.; Blais, R.; Levy, G.; Sonenshine, D.; Adams, D.; Maier, G.

1975-01-01

Data tables and maps are presented which include background information and experimental data on the Craney Island oil refinery installation experiment. The experiment was to investigate air pollution effects.

Application of remote sensing data to monitoring of oil pollution as part of the environmental expert system

NASA Astrophysics Data System (ADS)

Shagarova, Lyudmila; Muratova, Mira; Abuova, Sholpan

2016-07-01

The impact of oil-producing facilities on the environment is caused by toxicity of hydrocarbons and by-products, a variety of chemicals used in industrial processes, as well as specificity of production, treatment, transportation and storage of oil and oil products. To predict the state of the geological environment, scientists carry out investigations, which help to choose the optimal strategy for creation of the expert system taking into account simulations and to provide efficient use of available environmentally relevant information related to the current state of the geological environment. The expert system is a complex of interconnected blocks, one of which is the information on the presence of oil pollution, which can be identified using satellite imagery. The satellite imagery has practical application in monitoring of oil pollution, as it allows specialists to identify oil spills remotely and to determine their characteristics based on the differentiation of the surface reflectance spectra. Snapshots are used to estimate the area of oil-contamination and location of spills. To detect contaminants it is necessary to perform the following steps in processing of the remote sensing data: - Identify and isolate all the dark deformations in the satellite images, as a result of processing of segmentation and threshold processing; - Calculate statistical parameters of dark deformations, i.e., signs similar to areas prone to contamination. These signs are related to the geometry of formation, their physical changes (backscattering value) and the image context; - Classify the selected spectral anomalies as oil pollution and oil sludge. On the basis of classification of satellite imagery, the objects of oil pollution are detected and deciphering signs are analyzed in order to refer classified objects to implicit or explicit contaminations. To detect oil pollution, pixels are classified into categories with learning on the given areas with creation of the corresponding signature for each of them, i.e. the area with a given class, which is used to determine centers of classes in further supervised classification. The classification process compares the luminance of pixels with the training sample, as a result, each pixel is referred to the most appropriate class of objects. The development of an expert system using digital space information will extend the circle of problems solved in the environmental protection, creation of complex schemes of intensive development of hydrocarbon production regions in view of environmental risks.

Documentation of time-scales for onset of natural attenuation in an aquifer treated by a crude-oil recovery system.

PubMed

Ponsin, Violaine; Maier, Joachim; Guelorget, Yves; Hunkeler, Daniel; Bouchard, Daniel; Villavicencio, Hakeline; Höhener, Patrick

2015-04-15

A pipeline transporting crude-oil broke in a nature reserve in 2009 and spilled 5100 m(3) of oil that partly reached the aquifer and formed progressively a floating oil lens. Groundwater monitoring started immediately after the spill and crude-oil recovery by dual pump-and-skim technology was operated after oil lens formation. This study aimed at documenting the implementation of redox-specific natural attenuation processes in the saturated zone and at assessing whether dissolved compounds were degraded. Seven targeted water sampling campaigns were done during four years in addition to a routine monitoring of hydrocarbon concentrations. Liquid oil reached the aquifer within 2.5 months, and anaerobic processes, from denitrification to reduction of sulfate, were observable after 8 months. Methanogenesis appeared on site after 28 months. Stable carbon isotope analyses after 16 months showed maximum shifts in δ(13)C of +4.9±0.22‰ for toluene, +2.4±0.19‰ for benzene and +0.9±0.51‰ for ethylbenzene, suggesting anaerobic degradation of these compounds in the source zone. Estimations of fluxes of inorganic carbon produced by biodegradation revealed that, in average, 60% of inorganic carbon production was attributable to sulfate reduction. This percentage tended to decrease with time while the production of carbon attributable to methanogenesis was increasing. Within the investigation time frame, mass balance estimations showed that biodegradation is a more efficient process for control of dissolved concentrations compared to pumping and filtration on an activated charcoal filter. Copyright © 2015 Elsevier B.V. All rights reserved.

Study of jojoba oil aging by FTIR.

PubMed

Le Dréau, Y; Dupuy, N; Gaydou, V; Joachim, J; Kister, J

2009-05-29

As the jojoba oil was used in cosmetic, pharmaceutical, dietetic food, animal feeding, lubrication, polishing and bio-diesel fields, it was important to study its aging at high temperature by oxidative process. In this work a FT-MIR methodology was developed for monitoring accelerate oxidative degradation of jojoba oils. Principal component analysis (PCA) was used to differentiate various samples according to their origin and obtaining process, and to differentiate oxidative conditions applied on oils. Two spectroscopic indices were calculated to report simply the oxidation phenomenon. Results were confirmed and deepened by multivariate curve resolution-alternative least square method (MCR-ALS). It allowed identifying chemical species produced or degraded during the thermal treatment according to a SIMPLISMA pretreatment.

Balanced program plan: analysis for biomedical and environmental research. Volume 5. Oil shale technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1976-06-01

Oil shale technology has been divided into two sub-technologies: surfaceprocessing and in-situ processing. Definition of the research programs is essentially an amplification of the five King-Muir categories: (A) pollutants: characterization, measurement, and monitoring; (B) physical and chemical processes and effects; (C) health effects; (D) ecological processes and effects; and (E) integrated assessment. Twenty-three biomedical and environmental research projects are described as to program title, scope, milestones, technology time frame, program unit priority, and estimated program unit cost.

BER balanced program plan: oil shale technology. [23 suggested biomedical and environmental research projects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schulte, H.F.; Stoker, A.K.; Campbell, E.E.

1976-06-01

Oil shale technology has been divided into two sub-technologies: surface processing and in-situ processing. Definition of the research programs is essentially an amplification of the five King-Muir categories: (A) pollutants: characterization, measurement, and monitoring; (B) physical and chemical processes and effects; (C) health effects; (D) ecological processes and effects; and (E) integrated assessment. Twenty-three biomedical and environmental research projects are described as to program title, scope, milestones, technolgy time frame, program unit priority, and estimated program unit cost.

Photonic crystal fiber modal interferometer with Pd/WO3 coating for real-time monitoring of dissolved hydrogen concentration in transformer oil

NASA Astrophysics Data System (ADS)

Zhang, Ya-nan; Wu, Qilu; Peng, Huijie; Zhao, Yong

2016-12-01

A highly-sensitive and temperature-robust photonic crystal fiber (PCF) modal interferometer coated with Pd/WO3 film was fabricated and studied, aiming for real-time monitoring of dissolved hydrogen concentration in transformer oil. The sensor probe was fabricated by splicing two segments of a single mode fiber (SMF) with both ends of the PCF. Since the collapse of air holes in the PCF in the interfaces between SMF and PCF, a SMF-PCF-SMF interferometer structure was formed. The Pd/WO3 film was fabricated by sol-gel method and coated on the surface of the PCF by dip-coating method. When the Pd/WO3 film is exposed to hydrogen, both the length and cladding refractive index of the PCF would be changed, resulting in the resonant wavelength shift of the interferometer. Experimental results showed that the hydrogen measurement sensitivity of the proposed sensor can reach 0.109 pm/(μl/l) in the transformer oil, with the measurement range of 0-10 000 μl/l and response time less than 33 min. Besides, the proposed sensor was temperature-insensitive without any compensation process, easy to fabricate without any tapering, polishing, or etching process, low cost and quickly response without any oil-gas separation device. All these performances satisfy the actual need of real-time monitoring of dissolved hydrogen concentration in the transformer oil.

Photonic crystal fiber modal interferometer with Pd/WO3 coating for real-time monitoring of dissolved hydrogen concentration in transformer oil.

PubMed

Zhang, Ya-Nan; Wu, Qilu; Peng, Huijie; Zhao, Yong

2016-12-01

A highly-sensitive and temperature-robust photonic crystal fiber (PCF) modal interferometer coated with Pd/WO 3 film was fabricated and studied, aiming for real-time monitoring of dissolved hydrogen concentration in transformer oil. The sensor probe was fabricated by splicing two segments of a single mode fiber (SMF) with both ends of the PCF. Since the collapse of air holes in the PCF in the interfaces between SMF and PCF, a SMF-PCF-SMF interferometer structure was formed. The Pd/WO 3 film was fabricated by sol-gel method and coated on the surface of the PCF by dip-coating method. When the Pd/WO 3 film is exposed to hydrogen, both the length and cladding refractive index of the PCF would be changed, resulting in the resonant wavelength shift of the interferometer. Experimental results showed that the hydrogen measurement sensitivity of the proposed sensor can reach 0.109 pm/(μl/l) in the transformer oil, with the measurement range of 0-10 000 μl/l and response time less than 33 min. Besides, the proposed sensor was temperature-insensitive without any compensation process, easy to fabricate without any tapering, polishing, or etching process, low cost and quickly response without any oil-gas separation device. All these performances satisfy the actual need of real-time monitoring of dissolved hydrogen concentration in the transformer oil.

Highly oil-producing microalgae selected through directed-evolution on a microfludic chip

NASA Astrophysics Data System (ADS)

Mestler, Troy; Estevez-Torres, Andre; Lambert, Guillaume; Austin, Robert H.

2009-03-01

Some species of photosynthetic microalgae produce signi?cant amounts of oil which can be easily converted to diesel fuel. However, as it stands today, biodiesel is signi?cantly more expensive than fossil fuels. We wish to improve the oil yield and production rate of a single species of microalgae through directed evolution. We propose to utilize our microfabication technology to create microhabitats to control the nutrient environment of the species, monitor oil production through Raman Spectroscopy, and punish colonies of algae which have low oil yield. We believe this process will produce a mutant species with a high oil yield.

Study on diesel vertical migration characteristics and mechanism in water-bearing sand stratum using an automated resistivity monitoring system.

PubMed

Pan, Yuying; Jia, Yonggang; Wang, Yuhua; Xia, Xin; Guo, Lei

2018-02-01

Oil spills frequently occur on both land and sea. Petroleum in mobile phase will cause serious pollution in the sediment and can form a secondary pollution source. Therefore, it is very important to study the migration of petroleum in sediments ideally in a rapid and simplified approach. The release of diesel was simulated using fine beach sand to construct a model aquifer, and dynamic monitoring was carried out using an automated monitoring system including a resistivity probe originally developed by our research group. The mobile phase migration fronts were determined accurately using wavelet analysis method combined with resistivity curve method. Then, a relationship between resistivity and the joint oil-water content was established. The main conclusions were as follows. The seepage velocity of the diesel with high mobility at the initial stage of infiltration was faster, followed by a period when gravity seepage was dominant, and finally a redistribution period at the later stage, which was mainly an oil-water displacement process. The resistivity trends for diesel infiltration in different water-saturated soil layers varied with depth. The resistivity in the vadose zone fluctuated significantly, increasing initially and later decreasing. The resistivity change in the capillary zone was relatively small and constant in the initial stage; then, it increased and subsequently decreased. The resistivity in the saturated zone was basically unchanged with depth, and the value became slightly larger than the background value over time. Overall, for a large volume of mobile phase diesel leakage, the arrival migration fronts can be detected by wavelet analysis combined with resistivity curves. The thickness of the oil slick in the capillary zone can be estimated by resistivity changes. The relationships between resistivity and both the moisture content and oil-water joint saturation are in agreement with the linear models. The research results provide basic data and a new data processing method for monitoring of contaminated sites following major oil spills using the resistivity method.

Hyperspectral and Radar Airborne Imagery over Controlled Release of Oil at Sea.

PubMed

Angelliaume, Sébastien; Ceamanos, Xavier; Viallefont-Robinet, Françoise; Baqué, Rémi; Déliot, Philippe; Miegebielle, Véronique

2017-08-02

Remote sensing techniques are commonly used by Oil and Gas companies to monitor hydrocarbon on the ocean surface. The interest lies not only in exploration but also in the monitoring of the maritime environment. Occurrence of natural seeps on the sea surface is a key indicator of the presence of mature source rock in the subsurface. These natural seeps, as well as the oil slicks, are commonly detected using radar sensors but the addition of optical imagery can deliver extra information such as thickness and composition of the detected oil, which is critical for both exploration purposes and efficient cleanup operations. Today, state-of-the-art approaches combine multiple data collected by optical and radar sensors embedded on-board different airborne and spaceborne platforms, to ensure wide spatial coverage and high frequency revisit time. Multi-wavelength imaging system may create a breakthrough in remote sensing applications, but it requires adapted processing techniques that need to be developed. To explore performances offered by multi-wavelength radar and optical sensors for oil slick monitoring, remote sensing data have been collected by SETHI (Système Expérimental de Télédection Hyperfréquence Imageur), the airborne system developed by ONERA (the French Aerospace Lab), during an oil spill cleanup exercise carried out in 2015 in the North Sea, Europe. The uniqueness of this dataset lies in its high spatial resolution, low noise level and quasi-simultaneous acquisitions of different part of the EM spectrum. Specific processing techniques have been developed to extract meaningful information associated with oil-covered sea surface. Analysis of this unique and rich dataset demonstrates that remote sensing imagery, collected in both optical and microwave domains, allows estimating slick surface properties such as the age of the emulsion released at sea, the spatial abundance of oil and the relative concentration of hydrocarbons remaining on the sea surface.

Hyperspectral and Radar Airborne Imagery over Controlled Release of Oil at Sea

PubMed Central

Angelliaume, Sébastien; Ceamanos, Xavier; Viallefont-Robinet, Françoise; Baqué, Rémi; Déliot, Philippe

2017-01-01

Remote sensing techniques are commonly used by Oil and Gas companies to monitor hydrocarbon on the ocean surface. The interest lies not only in exploration but also in the monitoring of the maritime environment. Occurrence of natural seeps on the sea surface is a key indicator of the presence of mature source rock in the subsurface. These natural seeps, as well as the oil slicks, are commonly detected using radar sensors but the addition of optical imagery can deliver extra information such as thickness and composition of the detected oil, which is critical for both exploration purposes and efficient cleanup operations. Today, state-of-the-art approaches combine multiple data collected by optical and radar sensors embedded on-board different airborne and spaceborne platforms, to ensure wide spatial coverage and high frequency revisit time. Multi-wavelength imaging system may create a breakthrough in remote sensing applications, but it requires adapted processing techniques that need to be developed. To explore performances offered by multi-wavelength radar and optical sensors for oil slick monitoring, remote sensing data have been collected by SETHI (Système Expérimental de Télédection Hyperfréquence Imageur), the airborne system developed by ONERA (the French Aerospace Lab), during an oil spill cleanup exercise carried out in 2015 in the North Sea, Europe. The uniqueness of this dataset lies in its high spatial resolution, low noise level and quasi-simultaneous acquisitions of different part of the EM spectrum. Specific processing techniques have been developed to extract meaningful information associated with oil-covered sea surface. Analysis of this unique and rich dataset demonstrates that remote sensing imagery, collected in both optical and microwave domains, allows estimating slick surface properties such as the age of the emulsion released at sea, the spatial abundance of oil and the relative concentration of hydrocarbons remaining on the sea surface. PMID:28767059

Reflection of processes of non-equilibrium two-phase filtration in oil-saturated hierarchical medium in data of active wave geophysical monitoring

NASA Astrophysics Data System (ADS)

Hachay, Olga; Khachay, Andrey; Khachay, Oleg

2016-04-01

The processes of oil extraction from deposit are linked with the movement of multi-phase multi-component media, which are characterized by non-equilibrium and non-linear rheological features. The real behavior of layered systems is defined by the complexity of the rheology of moving fluids and the morphology structure of the porous medium, and also by the great variety of interactions between the fluid and the porous medium [Hasanov and Bulgakova, 2003]. It is necessary to take into account these features in order to informatively describe the filtration processes due to the non-linearity, non-equilibrium and heterogeneity that are features of real systems. In this way, new synergetic events can be revealed (namely, a loss of stability when oscillations occur, and the formation of ordered structures). This allows us to suggest new methods for the control and management of complicated natural systems that are constructed on account of these phenomena. Thus the layered system, from which it is necessary to extract the oil, is a complicated dynamical hierarchical system. A comparison is provided of non-equilibrium effects of the influence of independent hydrodynamic and electromagnetic induction on an oil layer and the medium which it surrounds. It is known that by drainage and steeping the hysteresis effect on curves of the relative phase permeability in dependence on the porous medium's water saturation in some cycles of influence (drainage-steep-drainage) is observed. Using the earlier developed 3D method of induction electromagnetic frequency geometric monitoring, we showed the possibility of defining the physical and structural features of a hierarchical oil layer structure and estimating the water saturation from crack inclusions. This effect allows managing the process of drainage and steeping the oil out of the layer by water displacement. An algorithm was constructed for 2D modeling of sound diffraction on a porous fluid-saturated intrusion of a hierarchical structure located in layer number J of an N-layered elastic medium. The algorithm developed for modeling, and the method of mapping and monitoring of heterogenic highly complicated two-phase medium can be used for managing viscous oil extraction in mining conditions and light oil in sub-horizontal boreholes. The demand for effective economic parameters and fuller extraction of oil and gas from deposits dictates the necessity of developing new geotechnology based on the fundamental achievements in the area of geophysics and geomechanics

Biosensors for monitoring the isothermal breakdown kinetics of peanut oil heated at 180°C. Comparison with results obtained for extra virgin olive oil.

PubMed

Tomassetti, M; Vecchio, S; Campanella, L; Dragone, R

2013-10-15

The present research was devoted to studying the kinetics of the artificial rancidification of peanut oil (PO) when a sample of this oil was isothermally heated at 180°C in an air stream. The formation of radical species due to heating was evaluated using a radical index whose value was determined using a biosensor method based on a superoxide dismutase (SOD), while the increasing toxicity was monitored using a suitable toxicity measuring probe based on the Clark electrode and immobilized yeast cells. An extra virgin olive oil was isothermally rancidified under the same experimental conditions and the corresponding data were used for the purpose of comparison. Both the so-called "model-fitting" and the classical kinetic methods were applied to the isothermal process biosensor data in order to obtain the kinetic constant rate value at 180°C. Copyright © 2012 Elsevier Ltd. All rights reserved.

Detection and Monitoring of Oil Spills Using Moderate/High-Resolution Remote Sensing Images.

PubMed

Li, Ying; Cui, Can; Liu, Zexi; Liu, Bingxin; Xu, Jin; Zhu, Xueyuan; Hou, Yongchao

2017-07-01

Current marine oil spill detection and monitoring methods using high-resolution remote sensing imagery are quite limited. This study presented a new bottom-up and top-down visual saliency model. We used Landsat 8, GF-1, MAMS, HJ-1 oil spill imagery as dataset. A simplified, graph-based visual saliency model was used to extract bottom-up saliency. It could identify the regions with high visual saliency object in the ocean. A spectral similarity match model was used to obtain top-down saliency. It could distinguish oil regions and exclude the other salient interference by spectrums. The regions of interest containing oil spills were integrated using these complementary saliency detection steps. Then, the genetic neural network was used to complete the image classification. These steps increased the speed of analysis. For the test dataset, the average running time of the entire process to detect regions of interest was 204.56 s. During image segmentation, the oil spill was extracted using a genetic neural network. The classification results showed that the method had a low false-alarm rate (high accuracy of 91.42%) and was able to increase the speed of the detection process (fast runtime of 19.88 s). The test image dataset was composed of different types of features over large areas in complicated imaging conditions. The proposed model was proved to be robust in complex sea conditions.

Fuel properties and engine performance of biodiesel from waste cooking oil collected in Dhaka city

NASA Astrophysics Data System (ADS)

Islam, R. B.; Islam, R.; Uddin, M. N.; Ehsan, Md.

2016-07-01

Waste cooking oil can be a potential source of biodiesel that has least effect on the edible oil consumption. Increasing number of hotel-restaurants and more active monitoring by health authorities have increased the generation of waste cooking oil significantly in densely populated cities like Dhaka. If not used or disposed properly, waste cooking oil itself may generate lot of environmental issues. In this work, waste cooking oils from different restaurants within Dhaka City were collected and some relevant properties of these waste oils were measured. Based on the samples studied one with the highest potential as biodiesel feed was identified and processed for engine performance. Standard trans-esterification process was used to produce biodiesel from the selected waste cooking oil. Biodiesel blends of B20 and B40 category were made and tested on a single cylinder direct injection diesel engine. Engine performance parameters included - bhp, bsfc and exhaust emission for rated and part load conditions. Results give a quantitative assessment of the potential of using biodiesel from waste cooking oil as fuel for diesel engines in Bangladesh.

Image processing analysis of geospatial uav orthophotos for palm oil plantation monitoring

NASA Astrophysics Data System (ADS)

Fahmi, F.; Trianda, D.; Andayani, U.; Siregar, B.

2018-03-01

Unmanned Aerial Vehicle (UAV) is one of the tools that can be used to monitor palm oil plantation remotely. With the geospatial orthophotos, it is possible to identify which part of the plantation land is fertile for planted crops, means to grow perfectly. It is also possible furthermore to identify less fertile in terms of growth but not perfect, and also part of plantation field that is not growing at all. This information can be easily known quickly with the use of UAV photos. In this study, we utilized image processing algorithm to process the orthophotos for more accurate and faster analysis. The resulting orthophotos image were processed using Matlab including classification of fertile, infertile, and dead palm oil plants by using Gray Level Co-Occurrence Matrix (GLCM) method. The GLCM method was developed based on four direction parameters with specific degrees 0°, 45°, 90°, and 135°. From the results of research conducted with 30 image samples, it was found that the accuracy of the system can be reached by using the features extracted from the matrix as parameters Contras, Correlation, Energy, and Homogeneity.

Application of thin layer activation technique for monitoring corrosion of carbon steel in hydrocarbon processing environment.

PubMed

Saxena, R C; Biswal, Jayashree; Pant, H J; Samantray, J S; Sharma, S C; Gupta, A K; Ray, S S

2018-05-01

Acidic crude oil transportation and processing in petroleum refining and petrochemical operations cause corrosion in the pipelines and associated components. Corrosion monitoring is invariably required to test and prove operational reliability. Thin Layer Activation (TLA) technique is a nuclear technique used for measurement of corrosion and erosion of materials. The technique involves irradiation of material with high energy ion beam from an accelerator and measurement of loss of radioactivity after the material is subjected to corrosive environment. In the present study, TLA technique has been used to monitor corrosion of carbon steel (CS) in crude oil environment at high temperature. Different CS coupons were irradiated with a 13 MeV proton beam to produce Cobalt-56 radioisotope on the surface of the coupons. The corrosion studies were carried out by subjecting the irradiated coupons to a corrosive environment, i.e, uninhibited straight run gas oil (SRGO) containing known amount of naphthenic acid (NA) at high temperature. The effects of different parameters, such as, concentration of NA, temperature and fluid velocity (rpm) on corrosion behaviour of CS were studied. Copyright © 2018 Elsevier Ltd. All rights reserved.

Modern Processes of Hydrocarbon Migration and Re-Formation of Oil and Gas Fields (Based on the Results of Monitoring and Geochemical Studies)

NASA Astrophysics Data System (ADS)

Plotnikova, Irina; Salakhidinova, Gulmira; Nosova, Fidania; Pronin, Nikita; Ostroukhov, Sergey

2015-04-01

Special geochemical studies of oils allowed to allocate a movable migration component of oils in the industrial oil deposits. In the field the migration component of oils varies in different parts of the field. The largest percentage of the light migration component (gas condensate of the oil) was detected in the central part of the Kama-Kinel troughs system. Monitoring of the composition of water, oil and gas (condensate light oil component) in the sedimentary cover and ni crystalline basement led to the conclusion of modern migration of hydrocarbons in sedimentary cover. This proves the existence of the modern processes of formation and reformation of oil and gas fields. This presentation is dedicated to the problem of definition of geochemical criteria of selection of hydrocarbons deposit reformation zone in the sample wells of Minibaevskaya area of Romashkinskoye field. While carrying out this work we examined 11 samples of oil from the Upper Devonian Pashiysky horizon. Four oil samples were collected from wells reckoned among the "anomalous" zones that were marked out according to the results of geophysical, oil field and geological research. Geochemical studies of oils were conducted in the laboratory of geochemistry of the Kazan (Volga-region) Federal University. The wells where the signs of hydrocarbons influx from the deep zones of the crust were recorded are considered to be "anomalous". A number of scientists connect this fact to the hypothesis about periodic influx of deep hydrocarbons to the oil deposits of Romashkinskoye field. Other researchers believe that the source rocks of the adjacent valleys sedimentary cover generate gases when entering the main zone of gas formation, which then migrate up the section and passing through the previously formed deposits of oil, change and "lighten" their composition. Regardless of the point of view on the source of the hydrocarbons, the study of the process of deposits refilling with light hydrocarbons is an important fundamental task of exceptional practical importance. The reservoir water monitoring has been conducted in five wells that have penetrated the water-saturated, loosely aggregated zones of the South Tatarstan Arch's basement. The long-term testing resulted in the production of reservoir water from the basement. The sedimentary cover in these wells is blocked by the column, which prevents water cross-flowing from the sedimentary cover. The observations have shown that the levels, gas saturation, mineralisation, density, and composition of reservoir waters from the loosely aggregated zones of the basement change with time. The varying characteristics of the water include its component composition, redox potential, and amount of chlorine and some other components and trace elements. Compositional changes in gases of the loosely aggregated zones of the basement, variations in the gas saturation of reservoir waters and of their composition, the decreasing density of oil in the sedimentary cover, - all result from one cause. This cause is the movement of fluids (solutions and gases dissolved in them) through the loosely aggregated zones and faults of the Earth's crust and the sedimentary cover. The fluids mainly move vertically in an upward direction, although their migration through subhorizontal, loosely aggregated zones of the crystalline basement is also possible. Fluid migration still takes place in the Earth's crust of ancient platforms. This phenomenon indicates that some portions of the platforms - primarily, their margins - periodically resume tectonic activities. The fluid dynamic activity of the crust define the processes in the sedimentary cover. It affects the development of the sedimentary basin during the sedimentation period, and the formation of mineral deposits. The monitoring of the present-day movement of fluid systems in the loosely aggregated zones of the basement will permit the more detailed study of the present-day fluid regime in the upper portion of the Earth's crust and the sedimentary cover.

40 CFR 468.03 - Monitoring and reporting requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... monitoring procedure for TTO, indirect dischargers may monitor for oil and grease and meet the alternate monitoring standards for oil and grease established for PSES and PSNS. Any indirect discharger meeting the alternate monitoring oil and grease standards shall be considered to meet the TTO standard. ...

40 CFR 468.03 - Monitoring and reporting requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... monitoring procedure for TTO, indirect dischargers may monitor for oil and grease and meet the alternate monitoring standards for oil and grease established for PSES and PSNS. Any indirect discharger meeting the alternate monitoring oil and grease standards shall be considered to meet the TTO standard. ...

40 CFR 468.03 - Monitoring and reporting requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... monitoring procedure for TTO, indirect dischargers may monitor for oil and grease and meet the alternate monitoring standards for oil and grease established for PSES and PSNS. Any indirect discharger meeting the alternate monitoring oil and grease standards shall be considered to meet the TTO standard. ...

40 CFR 468.03 - Monitoring and reporting requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitoring procedure for TTO, indirect dischargers may monitor for oil and grease and meet the alternate monitoring standards for oil and grease established for PSES and PSNS. Any indirect discharger meeting the alternate monitoring oil and grease standards shall be considered to meet the TTO standard. ...

Novel technologies for monitoring the in-line quality of virgin olive oil during manufacturing and storage.

PubMed

Beltrán Ortega, Julio; Martínez Gila, Diego M; Aguilera Puerto, Daniel; Gámez García, Javier; Gómez Ortega, Juan

2016-11-01

The quality of virgin olive oil is related to the agronomic conditions of the olive fruits and the process variables of the production process. Nowadays, food markets demand better products in terms of safety, health and organoleptic properties with competitive prices. Innovative techniques for process control, inspection and classification have been developed in order to to achieve these requirements. This paper presents a review of the most significant sensing technologies which are increasingly used in the olive oil industry to supervise and control the virgin olive oil production process. Throughout the present work, the main research studies in the literature that employ non-invasive technologies such as infrared spectroscopy, computer vision, machine olfaction technology, electronic tongues and dielectric spectroscopy are analysed and their main results and conclusions are presented. These technologies are used on olive fruit, olive slurry and olive oil to determine parameters such as acidity, peroxide indexes, ripening indexes, organoleptic properties and minor components, among others. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

Final report on development and testing of the microwave oil-water monitor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swanson, C.

1991-06-15

The oil-water monitor is a device invented by Dr. Claude Swanson of Applied Physics Technology to respond to the petroleum-loss problem in crude oil transfers. It is a device which measures water content in crude oil and other petroleum products, in a flowing pipe such as a pipeline or tanker manifold. It is capable of accurately measuring the water contamination levels in crude oil shipments, in real time as the crude oil flows through the loading manifold into the tanker, or at the receiving point as the oil is off-loaded. The oil-water monitor has application in the verification of oilmore » volumes and concentration of contaminants at petroleum transfer points. The industry-estimated level of water loss at transfer points due to inadequate monitoring technology amounts to several billion dollars per year, so there is a definite perceived need within the petroleum community for this type of accurate water monitoring technology. News articles indicating the importance of this problem are shown. The microwave oil-water monitor measures the water content in the oil, whether in the form of small droplets or large globules. Therefore it can be applied to the crude oil as it flows through crude oil pipes into the ship, or at transfer points in a crude oil distribution system. 4 refs., 18 figs.« less

Oil spill environmental forensics: the Hebei Spirit oil spill case.

PubMed

Yim, Un Hyuk; Kim, Moonkoo; Ha, Sung Yong; Kim, Sunghwan; Shim, Won Joon

2012-06-19

After the Hebei Spirit oil spill (HSOS) in December 2007, mixtures of three types of Middle East crude oil (total 12,547 kL) were stranded along 375 km of coastline in Western Korea. Emergency responses together with 1.3 million volunteers' activity rapidly removed ca. 20% of spilled oil but the lingering oils have been found along the heavily impacted shorelines for more than 4 years. The HSOS was the worst oil spill case in Republic of Korea, and there were many issues and lessons to be shared. In this study, we summarized some of the oil spill environmental forensic issues that were raised after the HSOS. Rapid screening using on-site measurement, long-term monitoring of multimedia, fingerprinting challenges and evaluation of the extent of the submerged oil were introduced, which supported decision making process of oil spill cleanup, mitigation of debates among stakeholders and provided scientific backgrounds for reasonable compensation.

Microseismic monitoring of CO2 injection at the Penn West Enhanced Oil Recovery pilot project, Canada: implications for detection of wellbore leakage.

PubMed

Martínez-Garzón, Patricia; Bohnhoff, Marco; Kwiatek, Grzegorz; Zambrano-Narváez, Gonzalo; Chalaturnyk, Rick

2013-09-02

A passive seismic monitoring campaign was carried out in the frame of a CO2-Enhanced Oil Recovery (EOR) pilot project in Alberta, Canada. Our analysis focuses on a two-week period during which prominent downhole pressure fluctuations in the reservoir were accompanied by a leakage of CO2 and CH4 along the monitoring well equipped with an array of short-period borehole geophones. We applied state of the art seismological processing schemes to the continuous seismic waveform recordings. During the analyzed time period we did not find evidence of induced micro-seismicity associated with CO2 injection. Instead, we identified signals related to the leakage of CO2 and CH4, in that seven out of the eight geophones show a clearly elevated noise level framing the onset time of leakage along the monitoring well. Our results confirm that micro-seismic monitoring of reservoir treatment can contribute towards improved reservoir monitoring and leakage detection.

Microseismic Monitoring of CO2 Injection at the Penn West Enhanced Oil Recovery Pilot Project, Canada: Implications for Detection of Wellbore Leakage

PubMed Central

Martínez-Garzón, Patricia; Bohnhoff, Marco; Kwiatek, Grzegorz; Zambrano-Narváez, Gonzalo; Chalaturnyk, Rick

2013-01-01

A passive seismic monitoring campaign was carried out in the frame of a CO2-Enhanced Oil Recovery (EOR) pilot project in Alberta, Canada. Our analysis focuses on a two-week period during which prominent downhole pressure fluctuations in the reservoir were accompanied by a leakage of CO2 and CH4 along the monitoring well equipped with an array of short-period borehole geophones. We applied state of the art seismological processing schemes to the continuous seismic waveform recordings. During the analyzed time period we did not find evidence of induced micro-seismicity associated with CO2 injection. Instead, we identified signals related to the leakage of CO2 and CH4, in that seven out of the eight geophones show a clearly elevated noise level framing the onset time of leakage along the monitoring well. Our results confirm that micro-seismic monitoring of reservoir treatment can contribute towards improved reservoir monitoring and leakage detection. PMID:24002229

Bacterial community shift for monitoring the co-composting of oil palm empty fruit bunch and palm oil mill effluent anaerobic sludge.

PubMed

Zainudin, Mohd Huzairi Mohd; Ramli, Norhayati; Hassan, Mohd Ali; Shirai, Yoshihito; Tashiro, Kosuke; Sakai, Kenji; Tashiro, Yukihiro

2017-06-01

A recently developed rapid co-composting of oil palm empty fruit bunch (OPEFB) and palm oil mill effluent (POME) anaerobic sludge is beginning to attract attention from the palm oil industry in managing the disposal of these wastes. However, a deeper understanding of microbial diversity is required for the sustainable practice of the co-compositing process. In this study, an in-depth assessment of bacterial community succession at different stages of the pilot scale co-composting of OPEFB-POME anaerobic sludge was performed using 454-pyrosequencing, which was then correlated with the changes of physicochemical properties including temperature, oxygen level and moisture content. Approximately 58,122 of 16S rRNA gene amplicons with more than 500 operational taxonomy units (OTUs) were obtained. Alpha diversity and principal component analysis (PCoA) indicated that bacterial diversity and distributions were most influenced by the physicochemical properties of the co-composting stages, which showed remarkable shifts of dominant species throughout the process. Species related to Devosia yakushimensis and Desemzia incerta are shown to emerge as dominant bacteria in the thermophilic stage, while Planococcus rifietoensis correlated best with the later stage of co-composting. This study proved the bacterial community shifts in the co-composting stages corresponded with the changes of the physicochemical properties, and may, therefore, be useful in monitoring the progress of co-composting and compost maturity.

Chemical fingerprinting of naphthenic acids at an oil sands end pit lake by comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry (GC×GC/TOFMS)

NASA Astrophysics Data System (ADS)

Bowman, D. T.; Arriaga, D.; Morris, P.; Risacher, F.; Warren, L. A.; McCarry, B. E.; Slater, G.

2016-12-01

Naphthenic acids (NAs) are naturally occurring in Athabasca oil sands and accumulate in tailings as a result of water-based extraction processes. NAs contribute to the toxicity of tailings and oil sands process-affected water (OSPW). NAs exist as a complex mixture, so the development of an analytical technique to characterize them has been an on-going challenge. The monitoring of individual NAs and their associated isomers through multidimensional chromatography has the potential to provide greater insight into the behavior of NAs in the environment. For NAs whose proportions do not change during environmental processing, NA ratios may provide a means to develop fingerprints characteristic of specific sources. Alternatively, relative changes in the proportions of NAs may provide a tracer of their occurrence and extent of removal. As yet, only a few studies have begun to explore these possibilities. In this study, comprehensive two dimensional gas chromatography/time-of-flight mass spectrometry was used to monitor individual naphthenic acids in an end pit lake in Alberta, Canada. NA profiles from different depths and sampling locations were compared to evaluate the spatial variations at the site.

The research of new type stratified water injection process intelligent measurement technology

NASA Astrophysics Data System (ADS)

Zhao, Xin

2017-10-01

To meet the needs of injection and development of Daqing Oilfield, the injection of oil from the early stage of general water injection to the subdivision of water is the purpose of improving the utilization degree and the qualified rate of water injection, improving the performance of water injection column and the matching process. Sets of suitable for high water content of the effective water injection technology supporting technology. New layered water injection technology intelligent measurement technology will be more information testing and flow control combined into a unified whole, long-term automatic monitoring of the work of the various sections, in the custom The process has the characteristics of "multi-layer synchronous measurement, continuous monitoring of process parameters, centralized admission data", which can meet the requirement of subdivision water injection, but also realize the automatic synchronization measurement of each interval, greatly improve the efficiency of tiered injection wells to provide a new means for the remaining oil potential.

In situ control of industrial processes using laser light scattering and optical rotation

NASA Astrophysics Data System (ADS)

Mendoza Sanchez, Patricia Judith; López Echevarria, Daniel; Huerta Ruelas, Jorge Adalberto

2006-02-01

We present results of optical measurements in products or processes usually found in industrial processes, which can be used to control them. Laser light scattering was employed during semiconductor epitaxial growth by molecular beam epitaxy. With this technique, it was possible to determine growth rate, roughness and critical temperatures related to substrate degradation. With the same scattering technique, oil degradation as function of temperature was monitored for different automotive lubricants. Clear differences can be studied between monograde and multigrade oils. Optical rotation measurements as function of temperature were performed in apple juice in a pasteurization process like. Average variations related to optical rotation dependence of sugars were measured and monitored during heating and cooling process, finding a reversible behavior. As opposite behavior, sugar-protein solution was measured in a similar heating and cooling process. Final result showed a non-reversible behavior related to protein denaturation. Potential applications are discussed for metal-mechanic, electronic, food, and pharmaceutical industry. Future improvements in optical systems to make them more portable and easily implemented under typical industry conditions are mentioned.

33 CFR 157.02 - Incorporation by reference: Where can I get a copy of the publications mentioned in this part?

Code of Federal Regulations, 2014 CFR

2014-07-01

... Item 11, Guidelines and Specifications for Oil Discharge Monitoring and Control Systems for Oil Tankers... Monitoring and Control Systems for Oil Tankers (“A.586(14)”), incorporation by reference approved for § 157... 1983, Guidelines for Plan Approval and Installation Survey of Oil Discharge Monitoring and Control...

33 CFR 157.02 - Incorporation by reference: Where can I get a copy of the publications mentioned in this part?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Item 11, Guidelines and Specifications for Oil Discharge Monitoring and Control Systems for Oil Tankers... Monitoring and Control Systems for Oil Tankers (“A.586(14)”), incorporation by reference approved for § 157... 1983, Guidelines for Plan Approval and Installation Survey of Oil Discharge Monitoring and Control...

33 CFR 157.02 - Incorporation by reference: Where can I get a copy of the publications mentioned in this part?

Code of Federal Regulations, 2012 CFR

2012-07-01

... Item 11, Guidelines and Specifications for Oil Discharge Monitoring and Control Systems for Oil Tankers... Monitoring and Control Systems for Oil Tankers (“A.586(14)”), incorporation by reference approved for § 157... 1983, Guidelines for Plan Approval and Installation Survey of Oil Discharge Monitoring and Control...

33 CFR 157.02 - Incorporation by reference: Where can I get a copy of the publications mentioned in this part?

Code of Federal Regulations, 2013 CFR

2013-07-01

... Item 11, Guidelines and Specifications for Oil Discharge Monitoring and Control Systems for Oil Tankers... Monitoring and Control Systems for Oil Tankers (“A.586(14)”), incorporation by reference approved for § 157... 1983, Guidelines for Plan Approval and Installation Survey of Oil Discharge Monitoring and Control...

Wind Turbine Gearbox Oil Filtration and Condition Monitoring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sheng, Shuangwen

This is an invited presentation for a pre-conference workshop, titled advances and opportunities in lubrication: wind turbine, at the 2015 Society of Tribologists and Lubrication Engineers (STLE) Tribology Frontiers Conference held in Denver, CO. It gives a brief overview of wind turbine gearbox oil filtration and condition monitoring by highlighting typical industry practices and challenges. The presentation starts with an introduction by covering recent growth of global wind industry, reliability challenges, benefits of oil filtration and condition monitoring, and financial incentives to conduct wind operation and maintenance research, which includes gearbox oil filtration and condition monitoring work presented herein. Then,more » the presentation moves on to oil filtration by stressing the benefits of filtration, discussing typical main- and offline-loop practices, highlighting important factors considered when specifying a filtration system, and illustrating real-world application challenges through a cold-start example. In the next section on oil condition monitoring, a discussion on oil sample analysis, oil debris monitoring, oil cleanliness measurements and filter analysis is given based on testing results mostly obtained by and at NREL, and by pointing out a few challenges with oil sample analysis. The presentation concludes with a brief touch on future research and development (R and D) opportunities. It is hoping that the information presented can inform the STLE community to start or redirect their R and D work to help the wind industry advance.« less

Radar and optical remote sensing in offshore domain to detect, characterize, and quantify ocean surface oil slicks

NASA Astrophysics Data System (ADS)

Angelliaume, S.; Ceamanos, X.; Viallefont-Robinet, F.; Baqué, R.; Déliot, Ph.; Miegebielle, V.

2017-10-01

Radar and optical sensors are operationally used by authorities or petroleum companies for detecting and characterizing maritime pollution. The interest lies not only in exploration but also in the monitoring of the maritime environment. Occurrence of natural seeps on the sea surface is a key indicator of the presence of mature source rock in the subsurface. These natural seeps, as well as the oil slicks, are commonly detected using radar sensors but the addition of optical imagery can deliver extra information such as the oil real fraction, which is critical for both exploration purposes and efficient cleanup operations. Today state-of-the-art approaches combine multiple data collected by optical and radar sensors embedded on-board different airborne and spaceborne platforms, to ensure wide spatial coverage and high frequency revisit time. Multi-wavelength imaging system may create a breakthrough in remote sensing applications, but it requires adapted processing techniques that need to be developed. To explore performances offered by multi-wavelength radar and optical sensors for oil slick monitoring, remote sensing data have been collected by SETHI, the airborne system developed by ONERA, during an oil spill cleanup exercise carried out in 2015 in the North Sea, Europe. The uniqueness of this data set lies in its high spatial resolution, low noise level and quasi-simultaneous acquisitions of different part of the electromagnetic spectrum. Specific processing techniques have been developed in order to extract meaningful information associated with oil-covered sea surface. Analysis of this unique and rich dataset demonstrates that remote sensing imagery, collected in both optical and microwave domains, allows to estimate slick surface properties such as the spatial abundance of oil and the relative concentration of hydrocarbons on the sea surface.

Estimation of the Heat Balance of the Liquid Hydrocarbons Evaporation Process from the Open Surface During Geotechnical Monitoring

NASA Astrophysics Data System (ADS)

Zemenkova, M. Yu; Zemenkov, Yu D.

2016-10-01

Researchers in Tyumen State Oil and Gas University (TSOGU) have conducted a complex research of the heat and mass transfer processes and thermophysical properties of hydrocarbons, taking into account their impact on the reliability and safety of the hydrocarbon transport and storage processes. It has been shown that the thermodynamic conditions on the surface and the color of oil influence the degree of temperature rise in the upper layers of oil when exposed to direct solar radiation. In order to establish the nature of solar radiation impact on the surface temperature the experimental studies were conducted in TSOGU on the hydrocarbon evaporation and the temperature change of various petroleum and petroleum products on the free surface with varying degrees of thermal insulation of the side walls and bottom of the vessel.

Engineering design and prototype development of a full scale ultrasound system for virgin olive oil by means of numerical and experimental analysis.

PubMed

Clodoveo, Maria Lisa; Moramarco, Vito; Paduano, Antonello; Sacchi, Raffaele; Di Palmo, Tiziana; Crupi, Pasquale; Corbo, Filomena; Pesce, Vito; Distaso, Elia; Tamburrano, Paolo; Amirante, Riccardo

2017-07-01

The aim of the virgin olive oil extraction process is mainly to obtain the best quality oil from fruits, by only applying mechanical actions while guaranteeing the highest overall efficiency. Currently, the mechanical methods used to extract virgin oils from olives are basically of two types: the discontinuous system (obsolete) and the continuous one. Anyway the system defined as "continuous" is composed of several steps which are not all completely continuous, due to the presence of the malaxer, a device that works in batch. The aim of the paper was to design, realize and test the first full scale sono-exchanger for the virgin olive oil industry, to be placed immediately after the crusher and before the malaxer. The innovative device is mainly composed of a triple concentric pipe heat exchanger combined with three ultrasound probes. This mechanical solution allows both the cell walls (which release the oil droplets) along with the minor compounds to be destroyed more effectively and the heat exchange between the olive paste and the process water to be accelerated. This strategy represents the first step towards the transformation of the malaxing step from a batch operation into a real continuous process, thus improving the working capacity of the industrial plants. Considering the heterogeneity of the olive paste, which is composed of different tissues, the design of the sono-exchanger required a thorough fluid dynamic analysis. The thermal effects of the sono-exchanger were monitored by measuring the temperature of the product at the inlet and the outlet of the device; in addition, the measurement of the pigments concentration in the product allowed monitoring the mechanical effects of the sono-exchanger. The effects of the innovative process were also evaluated in terms of extra virgin olive oil yields and quality, evaluating the main legal parameters, the polyphenol and tocopherol content. Moreover, the activity of the polyphenol oxidase enzyme in the olive paste was measured. Copyright © 2017 Elsevier B.V. All rights reserved.

Monitoring of pipeline oil spill fire events using Geographical Information System and Remote Sensing

NASA Astrophysics Data System (ADS)

Ogungbuyi, M. G.; Eckardt, F. D.; Martinez, P.

2016-12-01

Nigeria, the largest producer of crude oil in Africa occupies sixth position in the world. Despite such huge oil revenue potentials, its pipeline network system is consistently susceptible to leaks causing oil spills. We investigate ground based spill events which are caused by operational error, equipment failure and most importantly by deliberate attacks along the major pipeline transport system. Sometimes, these spills are accompanied with fire explosion caused by accidental discharge, natural or illegal refineries in the creeds, etc. MODIS satellites fires data corresponding to the times and spill events (i.e. ground based data) of the Area of Interest (AOI) show significant correlation. The open source Quantum Geographical Information System (QGIS) was used to validate the dataset and the spatiotemporal analyses of the oil spill fires were expressed. We demonstrate that through QGIS and Google Earth (using the time sliders), we can identify and monitor oil spills when they are attended with fire events along the pipeline transport system accordingly. This is shown through the spatiotemporal images of the fires. Evidence of such fire cases resulting from bunt vegetation as different from industrial and domestic fire is also presented. Detecting oil spill fires in the study location may not require an enormous terabyte of image processing: we can however rely on a near-real-time (NRT) MODIS data that is readily available twice daily to detect oil spill fire as early warning signal for those hotspots areas where cases of oil seepage is significant in Nigeria.

Performance Analysis of Retrofitted Tribo-Corrosion Test Rig for Monitoring In Situ Oil Conditions.

PubMed

Siddaiah, Arpith; Khan, Zulfiqar Ahmad; Ramachandran, Rahul; Menezes, Pradeep L

2017-09-28

Oils and lubricants, once extracted after use from a mechanical system, can hardly be reused, and should be refurbished or replaced in most applications. New methods of in situ oil and lubricant efficiency monitoring systems have been introduced for a wide variety of mechanical systems, such as automobiles, aerospace aircrafts, ships, offshore wind turbines, and deep sea oil drilling rigs. These methods utilize electronic sensors to monitor the "byproduct effects" in a mechanical system that are not indicative of the actual remaining lifecycle and reliability of the oils. A reliable oil monitoring system should be able to monitor the wear rate and the corrosion rate of the tribo-pairs due to the inclusion of contaminants. The current study addresses this technological gap, and presents a novel design of a tribo-corrosion test rig for oils used in a dynamic system. A pin-on-disk tribometer test rig retrofitted with a three electrode-potentiostat corrosion monitoring system was used to analyze the corrosion and wear rate of a steel tribo-pair in industrial grade transmission oil. The effectiveness of the retrofitted test rig was analyzed by introducing various concentrations of contaminants in an oil medium that usually leads to a corrosive working environment. The results indicate that the retrofitted test rig can effectively monitor the in situ tribological performance of the oil in a controlled dynamic corrosive environment. It is a useful method to understand the wear-corrosion synergies for further experimental work, and to develop accurate predictive lifecycle assessment and prognostic models. The application of this system is expected to have economic benefits and help reduce the ecological oil waste footprint.

Performance Analysis of Retrofitted Tribo-Corrosion Test Rig for Monitoring In Situ Oil Conditions

PubMed Central

Ramachandran, Rahul; Menezes, Pradeep L.

2017-01-01

Oils and lubricants, once extracted after use from a mechanical system, can hardly be reused, and should be refurbished or replaced in most applications. New methods of in situ oil and lubricant efficiency monitoring systems have been introduced for a wide variety of mechanical systems, such as automobiles, aerospace aircrafts, ships, offshore wind turbines, and deep sea oil drilling rigs. These methods utilize electronic sensors to monitor the “byproduct effects” in a mechanical system that are not indicative of the actual remaining lifecycle and reliability of the oils. A reliable oil monitoring system should be able to monitor the wear rate and the corrosion rate of the tribo-pairs due to the inclusion of contaminants. The current study addresses this technological gap, and presents a novel design of a tribo-corrosion test rig for oils used in a dynamic system. A pin-on-disk tribometer test rig retrofitted with a three electrode-potentiostat corrosion monitoring system was used to analyze the corrosion and wear rate of a steel tribo-pair in industrial grade transmission oil. The effectiveness of the retrofitted test rig was analyzed by introducing various concentrations of contaminants in an oil medium that usually leads to a corrosive working environment. The results indicate that the retrofitted test rig can effectively monitor the in situ tribological performance of the oil in a controlled dynamic corrosive environment. It is a useful method to understand the wear–corrosion synergies for further experimental work, and to develop accurate predictive lifecycle assessment and prognostic models. The application of this system is expected to have economic benefits and help reduce the ecological oil waste footprint. PMID:28956819

Study of ultrasonic cavitation during extraction of the peanut oil at varying frequencies.

PubMed

Zhang, Lei; Zhou, Cunshan; Wang, Bei; Yagoub, Abu El-Gasim A; Ma, Haile; Zhang, Xiao; Wu, Mian

2017-07-01

The ultrasonic extraction of oils is a typical physical processing technology. The extraction process was monitored from the standpoint of the oil quality and efficiency of oil extraction. In this study, the ultrasonic cavitation fields were measured by polyvinylidene fluoride (PVDF) sensor. Waveform of ultrasonic cavitation fields was gained and analyzed. The extraction yield and oxidation properties were compared. The relationship between the fields and cavitation oxidation was established. Numerical calculation of oscillation cycle was done for the cavitation bubbles. Results showed that the resonance frequency, f r , of the oil extraction was 40kHz. At f r , the voltage amplitude was the highest; the time was the shortest as reaching the amplitude of the waveform. Accordingly, the cavitation effect worked most rapidly, resulting in the strongest cavitation intensity. The extraction yield and oxidation properties were closely related to the cavitation effect. It controlled the cavitation oxidation effectively from the viewpoint of chemical and physical aspects. Copyright © 2017 Elsevier B.V. All rights reserved.

Early warning indicators for process failure due to organic overloading by rapeseed oil in one-stage continuously stirred tank reactor, sewage sludge and waste digesters.

PubMed

Kleyböcker, A; Liebrich, M; Verstraete, W; Kraume, M; Würdemann, H

2012-11-01

Early warning indicators for process failures were investigated to develop a reliable method to increase the production efficiency of biogas plants. Organic overloads by the excessive addition of rapeseed oil were used to provoke the decrease in the gas production rate. Besides typical monitoring parameters, as pH, methane and hydrogen contents, biogas production rate and concentrations of fatty acids; carbon dioxide content, concentrations of calcium and phosphate were monitored. The concentration ratio of volatile fatty acids to calcium acted as an early warning indicator (EWI-VFA/Ca). The EWI-VFA/Ca always clearly and reliably indicated a process imbalance by exhibiting a 2- to 3-fold increase 3-7days before the process failure occurred. At this time, it was still possible to take countermeasures successfully. Furthermore, increases in phosphate concentration and in the concentration ratio of phosphate to calcium also indicated a process failure, in some cases, even earlier than the EWI-VFA/Ca. Copyright © 2012 Elsevier Ltd. All rights reserved.

Olive oil quality and ripening in super-high-density Arbequina orchard.

PubMed

Benito, Marta; Lasa, José Manuel; Gracia, Pilar; Oria, Rosa; Abenoza, María; Varona, Luis; Sánchez-Gimeno, Ana Cristina

2013-07-01

The aim of this work was to evaluate the evolution of the quality of extra virgin olive oil obtained from a super-high-density Arbequina orchard, under a drip irrigation system, throughout the ripening process. For this objective, physicochemical, nutritional and sensory parameters were studied. In addition, the oxidative stability, pigment content and colour evolution of olive oil were analysed during the ripening process. Free acidity increased slightly throughout the ripening process, while peroxide value and extinction coefficient decreased. Total phenol content and oxidative stability showed a similar trend, increasing at the beginning of ripening up to a maximum and thereafter decreasing. α-Tocopherol and pigment contents decreased with ripening, leading to changes in colour coordinates. Sensory parameters were correlated with total phenol content, following a similar trend throughout the maturation process. By sampling and monitoring the ripeness index weekly, it would be possible to determine an optimal harvesting time for olives according to the industrial yield and the physicochemical, nutritional and sensory properties of the olive oil. © 2012 Society of Chemical Industry.

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2014 CFR

2014-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2012 CFR

2012-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2013 CFR

2013-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

40 CFR 125.137 - As an owner or operator of a new offshore oil and gas extraction facility, must I perform...

Code of Federal Regulations, 2011 CFR

2011-07-01

... offshore oil and gas extraction facility, must I perform monitoring? 125.137 Section 125.137 Protection of... operator of a new offshore oil and gas extraction facility, must I perform monitoring? As an owner or operator of a new offshore oil and gas extraction facility, you will be required to perform monitoring to...

Application of distributed optical fiber sensing technologies to the monitoring of leakage and abnormal disturbance of oil pipeline

NASA Astrophysics Data System (ADS)

Yang, Xiaojun; Zhu, Xiaofei; Deng, Chi; Li, Junyi; Liu, Cheng; Yu, Wenpeng; Luo, Hui

2017-10-01

To improve the level of management and monitoring of leakage and abnormal disturbance of long distance oil pipeline, the distributed optical fiber temperature and vibration sensing system is employed to test the feasibility for the healthy monitoring of a domestic oil pipeline. The simulating leakage and abnormal disturbance affairs of oil pipeline are performed in the experiment. It is demonstrated that the leakage and abnormal disturbance affairs of oil pipeline can be monitored and located accurately with the distributed optical fiber sensing system, which exhibits good performance in the sensitivity, reliability, operation and maintenance etc., and shows good market application prospect.

Long Term, Operational Monitoring Of Enhanced Oil Recovery In Harsh Environments With INSAR

NASA Astrophysics Data System (ADS)

Sato, S.; Henschel, M. D.

2012-01-01

Since 2004, MDA GSI has provided ground deformation measurements for an oil field in northern Alberta, Canada using InSAR technology. During this period, the monitoring has reliably shown the slow rise of the oil field due to enhanced oil recovery operations. The InSAR monitoring solution is essentially based on the observation of point and point-like targets in the field. Ground conditions in the area are almost continuously changing (in their reflectivity characteristics) making it difficult to ob- serve coherent patterns from the ground. The extended duration of the oil operations has allowed us to continue InSAR monitoring and transition from RADARSAT-1 to RADARSAT-2. With RADARSAT-2 and the enhancement of the satellite resolution capability has provided more targets of opportunity as identified by a differential coherence method. This poster provides an overview of the long term monitoring of the oil field in northern Alberta, Canada.

Synergistic use of an oil drift model and remote sensing observations for oil spill monitoring.

PubMed

De Padova, Diana; Mossa, Michele; Adamo, Maria; De Carolis, Giacomo; Pasquariello, Guido

2017-02-01

In case of oil spills due to disasters, one of the environmental concerns is the oil trajectories and spatial distribution. To meet these new challenges, spill response plans need to be upgraded. An important component of such a plan would be models able to simulate the behaviour of oil in terms of trajectories and spatial distribution, if accidentally released, in deep water. All these models need to be calibrated with independent observations. The aim of the present paper is to demonstrate that significant support to oil slick monitoring can be obtained by the synergistic use of oil drift models and remote sensing observations. Based on transport properties and weathering processes, oil drift models can indeed predict the fate of spilled oil under the action of water current velocity and wind in terms of oil position, concentration and thickness distribution. The oil spill event that occurred on 31 May 2003 in the Baltic Sea offshore the Swedish and Danish coasts is considered a case study with the aim of producing three-dimensional models of sea circulation and oil contaminant transport. The High-Resolution Limited Area Model (HIRLAM) is used for atmospheric forcing. The results of the numerical modelling of current speed and water surface elevation data are validated by measurements carried out in Kalmarsund, Simrishamn and Kungsholmsfort stations over a period of 18 days and 17 h. The oil spill model uses the current field obtained from a circulation model. Near-infrared (NIR) satellite images were compared with numerical simulations. The simulation was able to predict both the oil spill trajectories of the observed slick and thickness distribution. Therefore, this work shows how oil drift modelling and remotely sensed data can provide the right synergy to reproduce the timing and transport of the oil and to get reliable estimates of thicknesses of spilled oil to prepare an emergency plan and to assess the magnitude of risk involved in case of oil spills due to disaster.

Remote Oil Spill Detection and Monitoring Beneath Sea Ice

NASA Astrophysics Data System (ADS)

Polak, Adam; Marshall, Stephen; Ren, Jinchang; Hwang, Byongjun (Phil); Hagan, Bernard; Stothard, David J. M.

2016-08-01

The spillage of oil in Polar Regions is particularly serious due to the threat to the environment and the difficulties in detecting and tracking the full extent of the oil seepage beneath the sea ice. Development of fast and reliable sensing techniques is highly desirable. In this paper hyperspectral imaging combined with signal processing and classification techniques are proposed as a potential tool to detect the presence of oil beneath the sea ice. A small sample, lab based experiment, serving as a proof of concept, resulted in the successful identification of oil presence beneath the thin ice layer as opposed to the other sample with ice only. The paper demonstrates the results of this experiment that granted a financial support to execute full feasibility study of this technology for oil spill detection beneath the sea ice.

Monitoring toxicity of polycyclic aromatic hydrocarbons in intertidal sediments for five years after the Hebei Spirit oil spill in Taean, Republic of Korea.

PubMed

Lee, Chang-Hoon; Lee, Jong-Hyeon; Sung, Chan-Gyoung; Moon, Seong-Dae; Kang, Sin-Kil; Lee, Ji-Hye; Yim, Un Hyuk; Shim, Won Joon; Ha, Sung Yong

2013-11-15

Ecotoxicological monitoring of intertidal sediments was performed for 5 years after the Hebei Spirit oil spill in Taean, Korea. Sediment toxicity was observed on most of the beaches 4 months after the spill and later decreased rapidly to nontoxic levels 8 months after the spill. The concentrations of total polycyclic aromatic hydrocarbons (TPAHs) in the sediments ranged from 2 to 530,000 ng/g during the monitoring. More than half of the samples exhibited significant toxicity 5 years after the Hebei Spirit oil spill. Using a logistic regression model, the median lethal concentration of TPAHs to amphipod Monocorophium uenoi was estimated to be 36,000 ng/g. From the 63 chemistry and toxicity data, the effect range-low, effect range median, threshold effect level, and probable effect level were derived to be 3190, 54,100, 2480, and 29,000 ng/g, respectively. The relative compositions of the PAH groups indicated that the weathering process is still ongoing. Copyright © 2013 Elsevier Ltd. All rights reserved.

Dissolution and degradation of crude oil droplets by different bacterial species and consortia by microcosm microfluidics

NASA Astrophysics Data System (ADS)

Jalali, Maryam; Sheng, Jian

2017-11-01

Bacteria are involved in cleanup and degradation of crude oil in polluted marine and soil environments. A number of bacterial species have been identified for consuming petroleum hydrocarbons with diverse metabolic capabilities. We conducted laboratory experiments to investigate bacterial consumption by monitoring the volume change to oil droplets as well as effects of oil droplet size on this process. To conduct our study, we developed a micro-bioassay containing an enclosed chamber with bottom substrate printed with stationary oil microdroplets and a digital holographic interferometer (DHI). The morphology of microdroplets was monitored in real time over 100 hours and instantaneous flow field was also measured by digital holographic microscope. The substrates with printed oil droplets were further evaluated with atomic force microscopy (AFM) at the end of each experiment. Three different bacteria species, Pseudomonas sp, Alcanivorax borkumensis, and Marinobacter hydrocarbonoclasticus, as well as six bacterial consortia were used in this study. The results show that droplets smaller than 20µm in diameter are not subject to bacterial degradation and the volume of droplet did not change beyond dissolution. Substantial species-specific behaviors have been observed in isolates. The experiments of consortia and various flow shears on biodegradation and dissolution are ongoing and will be reported.

40 CFR 467.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Oil and grease (alternate monitoring parameter) 20.37 20.37 Subpart A Cleaning or Etching Bath....124 Oil and grease (alternate monitoring parameter) 1.79 1.79 Subpart A Cleaning or Etching Rinse... Oil and grease (alternate monitoring parameter) 13.91 13.91 Subpart A Cleaning or Etching Scrubber...

40 CFR 467.55 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 1.41 Oil and grease (alternate monitoring parameter) 110 53 Subpart E Cleaning or Etching Bath....124 Oil and grease (alternate monitoring parameter) 9.3 4.7 Subpart E Cleaning or Etching Rinse... Oil and grease (alternate monitoring parameter) 73 36 Subpart E Cleaning or Etching Scrubber Liquor...

40 CFR 467.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Oil and grease (alternate monitoring parameter) 20.37 20.37 Subpart A Cleaning or Etching Bath....124 Oil and grease (alternate monitoring parameter) 1.79 1.79 Subpart A Cleaning or Etching Rinse... Oil and grease (alternate monitoring parameter) 13.91 13.91 Subpart A Cleaning or Etching Scrubber...

40 CFR 467.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Oil and grease (alternate monitoring parameter) 20.37 20.37 Subpart A Cleaning or Etching Bath....124 Oil and grease (alternate monitoring parameter) 1.79 1.79 Subpart A Cleaning or Etching Rinse... Oil and grease (alternate monitoring parameter) 13.91 13.91 Subpart A Cleaning or Etching Scrubber...

40 CFR 467.55 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 1.41 Oil and grease (alternate monitoring parameter) 110 53 Subpart E Cleaning or Etching Bath....124 Oil and grease (alternate monitoring parameter) 9.3 4.7 Subpart E Cleaning or Etching Rinse... Oil and grease (alternate monitoring parameter) 73 36 Subpart E Cleaning or Etching Scrubber Liquor...

40 CFR 467.55 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 1.41 Oil and grease (alternate monitoring parameter) 110 53 Subpart E Cleaning or Etching Bath....124 Oil and grease (alternate monitoring parameter) 9.3 4.7 Subpart E Cleaning or Etching Rinse... Oil and grease (alternate monitoring parameter) 73 36 Subpart E Cleaning or Etching Scrubber Liquor...

Non-intrusive telemetry applications in the oilsands: from visible light and x-ray video to acoustic imaging and spectroscopy

NASA Astrophysics Data System (ADS)

Shaw, John M.

2013-06-01

While the production, transport and refining of oils from the oilsands of Alberta, and comparable resources elsewhere is performed at industrial scales, numerous technical and technological challenges and opportunities persist due to the ill defined nature of the resource. For example, bitumen and heavy oil comprise multiple bulk phases, self-organizing constituents at the microscale (liquid crystals) and the nano scale. There are no quantitative measures available at the molecular level. Non-intrusive telemetry is providing promising paths toward solutions, be they enabling technologies targeting process design, development or optimization, or more prosaic process control or process monitoring applications. Operation examples include automated large object and poor quality ore during mining, and monitoring the thickness and location of oil water interfacial zones within separation vessels. These applications involve real-time video image processing. X-ray transmission video imaging is used to enumerate organic phases present within a vessel, and to detect individual phase volumes, densities and elemental compositions. This is an enabling technology that provides phase equilibrium and phase composition data for production and refining process development, and fluid property myth debunking. A high-resolution two-dimensional acoustic mapping technique now at the proof of concept stage is expected to provide simultaneous fluid flow and fluid composition data within porous inorganic media. Again this is an enabling technology targeting visualization of diverse oil production process fundamentals at the pore scale. Far infrared spectroscopy coupled with detailed quantum mechanical calculations, may provide characteristic molecular motifs and intermolecular association data required for fluid characterization and process modeling. X-ray scattering (SAXS/WAXS/USAXS) provides characteristic supramolecular structure information that impacts fluid rheology and process fouling. The intent of this contribution is to present some of the challenges and to provide an introduction grounded in current work on non-intrusive telemetry applications - from a mine or reservoir to a refinery!

Refining of Military Jet Fuels from Shale Oil. Part II. Volume III. Above Ground Shale Oil Process Data.

DTIC Science & Technology

1982-03-01

system. Regenerator flue gas composi- tion, spent catalyst carbon content and regenerated cata- lyst content are monitored for material balance purposes...and good material balance closures obtained. During each run pro- duct gas samples, regenerator flue gas samples, spent and -85- regenerated...TEMPERATURE DEPENDENCE OF DENITROGENATION AT 2 LHSV ON CO/MO ......................... 26 111-2 TEMPERATURE DEPENDENCE OF DESULFURIZATION AT 2 LHSV ON

Impact of hydrocarbon type, concentration and weathering on its biodegradability in soil.

PubMed

Maletić, Snežana P; Dalmacija, Božo D; Rončević, Srđan D; Agbaba, Jasmina R; Perović, Svetlana D Ugarčina

2011-01-01

The objective of this research was to investigate the impact of the hydrocarbon type and concentration, as well as the total effect of the natural weathering process to hydrocarbon biodegradability in sandy soil and the environment. In this experiment, sandy soil was separately contaminated with 0.5%, 1.0%, 2.0% and 3.5% of diesel and crude oils. Oil contaminated soil was taken from the Oil Refinery dumping sites after 9 years of weathering, and its concentration was adjusted to the above-mentioned levels. The biodegradation process was monitored by measuring CO(2), evolution rate, hydrocarbon degradation rate and dehydrogenase activity. The favourable concentration ranges for the soil contaminated with diesel oil were 1.0%, with concentrations at about 2.0% causing slightly adverse effects to CO(2) production which was overcome after 2 weeks, and with 3.5% diesel oil causing significant toxicity. For soil contaminated with crude oil, 2.0% was found to be optimum for effective biodegradation, with 3.5% crude oil also causing adverse effects to CO(2) production, although less so than the same concentration of diesel oil. No adverse effect was obtained for any concentration of the weathered oil, as after the weathering process, the remaining contaminants in the soil were mostly poorly degradable constituents like asphaltenes, resins etc. It has been proposed that such residual material from oil degradation is analogous to, and can even be regarded as, humic material. Due to its inert characteristics, insolubility and similarity to humic materials it is unlikely to be environmentally hazardous.

The perspective of the permanent monitoring with an FBG sensor network in oil and gas production in China

NASA Astrophysics Data System (ADS)

Zhang, Yuanzhong; Xiao, Lizhi; Fu, Jianwei; Chen, Haifeng; Zhao, Xiaoliang

2005-12-01

Most of the onshore oilfields in China are in the middle and late development stages, and great deals of residual oil are waiting for exploitation. Downhole permanent sensor monitoring technology is an effective means to enhance oil and gas recovery. The concept of the downhole permanent sensor network is introduced, and the research status was reviewed. The measurement principle, application and some issues of the Distribute Temperature System (DTS) and Fiber Bragg Grating (FBG) sensor are discussed. Some potential applications of permanent monitoring with FBG sensors in oil and gas production, including enhancing oil and gas recovery and realtime monitoring of casing damaging were reviewed.

Well casing-based geophysical sensor apparatus, system and method

DOEpatents

Daily, William D.

2010-03-09

A geophysical sensor apparatus, system, and method for use in, for example, oil well operations, and in particular using a network of sensors emplaced along and outside oil well casings to monitor critical parameters in an oil reservoir and provide geophysical data remote from the wells. Centralizers are affixed to the well casings and the sensors are located in the protective spheres afforded by the centralizers to keep from being damaged during casing emplacement. In this manner, geophysical data may be detected of a sub-surface volume, e.g. an oil reservoir, and transmitted for analysis. Preferably, data from multiple sensor types, such as ERT and seismic data are combined to provide real time knowledge of the reservoir and processes such as primary and secondary oil recovery.

BMP UNIT PROCESS DESIGN, MONITORING, AND PERFORMANCE

EPA Science Inventory

Urbanization results in more impervious areas that cause larger quantities of stormwater runoff. This runoff can contribute significant amounts of pollutants (e.g., litter, oils, microorganisms, sediments, nutrients, organic matter, and heavy metals) to receiving waters. To impro...

Methods of Oil Detection in Response to the Deepwater ...

EPA Pesticide Factsheets

Detecting oil in the northern Gulf of Mexico following the Deepwater Horizon oil spill presented unique challenges due to the spatial and temporal extent of the spill and the subsequent dilution of oil in the environment. Over time, physical, chemical, and biological processes altered the composition of the oil, further complicating its detection. Reservoir fluid, containing gas and oil, released from the Macondo well was detected in surface and subsurface environments. Oil monitoring during and after the spill required a variety of technologies, including nimble adaptation of techniques developed for non-oil-related applications. The oil detection technologies employed varied in sensitivity, selectivity, strategy, cost, usability, expertise of user, and reliability. Innovative technologies ranging from remote sensing to laboratory analytical techniques were employed and produced new information relevant to oil spill detection, including the chemical characterization, the dispersion effectiveness, and the detection limits of oil. The challenge remains to transfer these new technologies to oil spill responders so that detection of oil following a spill can be improved. To publish a perspective paper on oil detection technologies during the Deepwater Horizon Oil Spill. This is for a special issue book/journal.

Development of the oil-water monitor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swanson, C.

1990-04-02

The oil-water monitor is a device invented by Dr. Claude Swanson of Applied Physics Technology to respond to the petroleum-loss problem in crude oil transfers. It is a device which measures water content in crude oil and other petroleum products, in a flowing pipe such as a pipeline or tanker manifold. It is capable of accurately measuring the water contamination levels in crude oil shipments, in real time as the crude oil flows through the loading manifold into the tanker, or at the receiving point as the oil is off-loaded It has application in the verification of oil volumes andmore » concentration of contaminants at petroleum transfer points. The industry-estimated level of water loss at transfer points due to inadequate monitoring technology amounts to several billion dollars per year, so there is a definite perceived need within the petroleum community for this type of accurate water monitoring technology. The device has been patented, and initial feasibility experiments have been conducted. The present research is directed toward developing and demonstrating a bench model prototype of the oil-water monitor, complete with the computer software and automated microwave equipment and electronics which will demonstrate the performance of the invention, for implementation in full-scale fielded systems. 3 figs.« less

40 CFR 467.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

....021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0.50 0.50 Subpart D Forging Scrubber... 0.065 Oil and grease (alternate monitoring parameter) 0.95 0.95 Subpart D Solution Heat Treatment... 0.86 TTO 1.41 Oil and grease (alternate monitoring parameter) 20.37 20.37 Subpart D Cleaning or...

40 CFR 467.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

....021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0.50 0.50 Subpart D Forging Scrubber... 0.065 Oil and grease (alternate monitoring parameter) 0.95 0.95 Subpart D Solution Heat Treatment... 0.86 TTO 1.41 Oil and grease (alternate monitoring parameter) 20.37 20.37 Subpart D Cleaning or...

40 CFR 467.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

....021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0.50 0.50 Subpart D Forging Scrubber... 0.065 Oil and grease (alternate monitoring parameter) 0.95 0.95 Subpart D Solution Heat Treatment... 0.86 TTO 1.41 Oil and grease (alternate monitoring parameter) 20.37 20.37 Subpart D Cleaning or...

Settling of virgin olive oil from horizontal screw solid bowl in static conditions.

PubMed

Gila, Abraham M; Bejaoui, Mohamed A; Beltrán, Gabriel; Jiménez, Antonio

2017-08-01

This work was aimed to study the clarification efficiency of natural decantation in settling tank on virgin olive oil obtained from a two-ways continuous process. For this purpose, the impurities content of the virgin olive oil were monitored during settling process in settling tank at two different depths. Efficiency of purging system was determined for two days. The experiments were performed at industrial scale during three crop years. During the first minutes of settling was observed an ascent of the smaller organic particles of the oil. Then, most of the virgin olive oil impurities were settled at 300 min, independently of the initial content of virgin olive oil. Finally, oil decantation showed slower rate. Higher clarification values were obtained for those decanter oils with higher impurities content, achieving clarification percentages between of 62.69 and 95.91% at 48 h of settling. The highest settling efficiency was observed for those decanter oils with initial higher impurities content. The purging system used in the settling tanks was not able to remove the most of settled impurities since a considerable amount of the impurities remained in the tank after 48 h, between 13.6 and 71.41% for the studied oils. In the tank purges was observed important oil losses. Therefore, decantation was not an efficient system for oil clarification since its settling capacity varied depending on the initial impurities content and due to the settled impurities can not be removed fully by purging system.

Polycyclic Aromatic Hydrocarbons (PAHs) and Hopanes in Plastic Resin Pellets as Markers of Oil Pollution via International Pellet Watch Monitoring.

PubMed

Yeo, Bee Geok; Takada, Hideshige; Hosoda, Junki; Kondo, Atsuko; Yamashita, Rei; Saha, Mahua; Maes, Thomas

2017-08-01

Oil pollution in the marine environment is an unavoidable problem due to chronic input from local sources, particularly in urban areas and oil spills. Oil pollution not only causes immediate physical damages to surrounding wildlife but also some components, including higher molecular weight PAHs, can persist in the environment for many years and pose insidious threats to the ecosystem. Long-term and nontargeted monitoring of oil pollution is important. This paper examines the ability of International Pellet Watch (IPW) for initial identification and monitoring of oil pollution by analysing PAHs and hopanes in plastic pellet samples collected globally by volunteers. PAH concentrations with the sum of 28 parent and methyl PAHs vary geographically, ranging from 0.035 to 24.4 µg/g-pellet, in line with the presence or absence of local oil pollution sources, such as oil refineries or oil spill sites. This suggests that PAHs can be used to monitor petroleum pollution in IPW. A colour-coded categorization for PAH concentrations within IPW monitoring also is established to facilitate data presentation and understanding. PAH concentrations are generally higher in Western Europe, especially around the North Sea shorelines, moderate in East Asia and North America, and lower in South East Asia, Oceania, South America, and Africa. Hopane concentrations, with a smaller spatial variation (1.7-101 µg/g-pellet), showed no spatial pattern. This result and the poor correlation between hopanes and PAHs suggest that hopane concentrations alone are unsuited to identify petroleum pollution. However, hopane compositions can be used for fingerprinting sources of oil pollution. Thus, both PAHs and hopanes in IPW allow for low cost, remote monitoring of global oil pollution.

33 CFR 157.12b - Implementation requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... OIL IN BULK Design, Equipment, and Installation § 157.12b Implementation requirements. Oil discharge monitoring and control systems must be fitted to oil tankers to which this subpart applies. A monitoring and...

33 CFR 157.12b - Implementation requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... OIL IN BULK Design, Equipment, and Installation § 157.12b Implementation requirements. Oil discharge monitoring and control systems must be fitted to oil tankers to which this subpart applies. A monitoring and...

33 CFR 157.12b - Implementation requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... OIL IN BULK Design, Equipment, and Installation § 157.12b Implementation requirements. Oil discharge monitoring and control systems must be fitted to oil tankers to which this subpart applies. A monitoring and...

33 CFR 157.12b - Implementation requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... OIL IN BULK Design, Equipment, and Installation § 157.12b Implementation requirements. Oil discharge monitoring and control systems must be fitted to oil tankers to which this subpart applies. A monitoring and...

33 CFR 157.12b - Implementation requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... OIL IN BULK Design, Equipment, and Installation § 157.12b Implementation requirements. Oil discharge monitoring and control systems must be fitted to oil tankers to which this subpart applies. A monitoring and...

Modeling of oil mist and oil vapor concentration in the shale shaker area on offshore drilling installations.

PubMed

Bråtveit, Magne; Steinsvåg, Kjersti; Lie, Stein Atle; Moen, Bente E

2009-11-01

The objective of this study was to develop regression models to predict concentrations of oil mist and oil vapor in the workplace atmosphere in the shale shaker area of offshore drilling installations. Collection of monitoring reports of oil mist and oil vapor in the mud handling areas of offshore drilling installations was done during visits to eight oil companies and five drilling contractors. A questionnaire was sent to the rig owners requesting information about technical design of the shaker area. Linear mixed-effects models were developed using concentration of oil mist or oil vapor measured by stationary sampling as dependent variables, drilling installation as random effect, and potential determinants related to process technical parameters and technical design of the shale shaker area as fixed effects. The dataset comprised stationary measurements of oil mist (n = 464) and oil vapor (n = 462) from the period 1998 to 2004. The arithmetic mean concentrations of oil mist and oil vapor were 3.89 mg/m(3) and 39.7 mg/m(3), respectively. The air concentration models including significant determinants such as viscosity of base oil, mud temperature, well section, type of rig, localization of shaker, mechanical air supply, air grids in outer wall, air curtain in front of shakers, and season explained 35% and 17% of the total variance in oil vapor and oil mist, respectively. The developed models could be used to indicate what impact differences in technical design and changes in process parameters have on air concentrations of oil mist and oil vapor. Thus, the models will be helpful in planning control measures to reduce the potential for occupational exposure.

Tracking buoys research for oil spilling with the wireless charging equipment

NASA Astrophysics Data System (ADS)

Cui, Di; Zhao, Ping

2018-03-01

This paper describes thewirelesscharging equipment for achieving oil spill tracking buoys detection in satellite images acquired after tanker accidents or ship oil spill accidents. This information could allow the evolution of residues dumped at sea to be tracked. The validity of this process is demonstrated using several experiment acquired over several regions (Dalian and Tianjin coasts in China), in which a tanker accident has occurred and as a consequence oil spillage has taken place. Thus, this purpose of paper is developed for the active surveillance and rapid response to marine oil spills tracking buoys with wirelesscharging equipmentis important and essential to environment protection. It may appears of leak places for the Wire Charging Equipment for marine oil spills tracking buoys monitoring needs, and achieved instant alarm technology and equipment, guarantees leak occurred timely obtained alarm information. In order toproviding oil spill accidents emergency quickly reaction time and prepared. The maximum degree reduce oil leak and accidents caused influences are ensured.

Formation of Glycidyl Fatty Acid Esters Both in Real Edible Oils during Laboratory-Scale Refining and in Chemical Model during High Temperature Exposure.

PubMed

Cheng, Weiwei; Liu, Guoqin; Liu, Xinqi

2016-07-27

In the present study, the formation mechanisms of glycidyl fatty acid esters (GEs) were investigated both in real edible oils (soybean oil, camellia oil, and palm oil) during laboratory-scale preparation and refining and in chemical model (1,2-dipalmitin (DPG) and 1-monopalmitin (MPG)) during high temperature exposure (160-260 °C under nitrogen). The formation process of GEs in the chemical model was monitored using attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy. The results showed that the roasting and pressing process could produce certain amounts of GEs that were much lower than that produced in the deodorization process. GE contents in edible oils increased continuously and significantly with increasing deodorization time below 200 °C. However, when the temperature exceeded 200 °C, GE contents sharply increased in 1-2 h followed by a gradual decrease, which could verify a simultaneous formation and degradation of GEs at high temperature. In addition, it was also found that the presence of acylglycerol (DAGs and MAGs) could significantly increase the formation yield of GEs both in real edible oils and in chemical model. Compared with DAGs, moreover, MAGs displayed a higher formation capacity but substantially lower contribution to GE formation due to their low contents in edible oils. In situ ATR-FTIR spectroscopic evidence showed that cyclic acyloxonium ion intermediate was formed during GE formation derived from DPG and MPG in chemical model heated at 200 °C.

High Resolution Rapid Revisits Insar Monitoring of Surface Deformation

NASA Astrophysics Data System (ADS)

Singhroy, V.; Li, J.; Charbonneau, F.

2014-12-01

Monitoring surface deformation on strategic energy and transportation corridors requires high resolution spatial and temporal InSAR images for mitigation and safety purposes. High resolution air photos, lidar and other satellite images are very useful in areas where the landslides can be fatal. Recently, radar interferometry (InSAR) techniques using more rapid revisit images from several radar satellites are increasingly being used in active deformation monitoring. The Canadian RADARSAT Constellation (RCM) is a three-satellite mission that will provide rapid revisits of four days interferometric (InSAR) capabilities that will be very useful for complex deformation monitoring. For instance, the monitoring of surface deformation due to permafrost activity, complex rock slide motion and steam assisted oil extraction will benefit from this new rapid revisit capability. This paper provide examples of how the high resolution (1-3 m) rapid revisit InSAR capabilities will improve our monitoring of surface deformation and provide insights in understanding triggering mechanisms. We analysed over a hundred high resolution InSAR images over a two year period on three geologically different sites with various configurations of topography, geomorphology, and geology conditions. We show from our analysis that the more frequent InSAR acquisitions are providing more information in understanding the rates of movement and failure process of permafrost triggered retrogressive thaw flows; the complex motion of an asymmetrical wedge failure of an active rock slide and the identification of over pressure zones related to oil extraction using steam injection. Keywords: High resolution, InSAR, rapid revisits, triggering mechanisms, oil extraction.

43 CFR 2881.5 - What acronyms and terms are used in the regulations in this part?

Code of Federal Regulations, 2012 CFR

2012-10-01

... of 1920, as amended (30 U.S.C. 185). TAPS means the Trans-Alaska Oil Pipeline System. TUP means a... Federal government expends or uses in processing a right-of-way application or in monitoring the... authorizations issued under FLPMA (43 U.S.C. 1761 et seq.). Monitoring means those actions, subject to § 2886.11...

43 CFR 2881.5 - What acronyms and terms are used in the regulations in this part?

Code of Federal Regulations, 2014 CFR

2014-10-01

... of 1920, as amended (30 U.S.C. 185). TAPS means the Trans-Alaska Oil Pipeline System. TUP means a... Federal government expends or uses in processing a right-of-way application or in monitoring the... authorizations issued under FLPMA (43 U.S.C. 1761 et seq.). Monitoring means those actions, subject to § 2886.11...

43 CFR 2881.5 - What acronyms and terms are used in the regulations in this part?

Code of Federal Regulations, 2013 CFR

2013-10-01

... of 1920, as amended (30 U.S.C. 185). TAPS means the Trans-Alaska Oil Pipeline System. TUP means a... Federal government expends or uses in processing a right-of-way application or in monitoring the... authorizations issued under FLPMA (43 U.S.C. 1761 et seq.). Monitoring means those actions, subject to § 2886.11...

43 CFR 2881.5 - What acronyms and terms are used in the regulations in this part?

Code of Federal Regulations, 2011 CFR

2011-10-01

... of 1920, as amended (30 U.S.C. 185). TAPS means the Trans-Alaska Oil Pipeline System. TUP means a... Federal government expends or uses in processing a right-of-way application or in monitoring the... authorizations issued under FLPMA (43 U.S.C. 1761 et seq.). Monitoring means those actions, subject to § 2886.11...

Research on crude oil storage and transportation based on optimization algorithm

NASA Astrophysics Data System (ADS)

Yuan, Xuhua

2018-04-01

At present, the optimization theory and method have been widely used in the optimization scheduling and optimal operation scheme of complex production systems. Based on C++Builder 6 program development platform, the theoretical research results are implemented by computer. The simulation and intelligent decision system of crude oil storage and transportation inventory scheduling are designed. The system includes modules of project management, data management, graphics processing, simulation of oil depot operation scheme. It can realize the optimization of the scheduling scheme of crude oil storage and transportation system. A multi-point temperature measuring system for monitoring the temperature field of floating roof oil storage tank is developed. The results show that by optimizing operating parameters such as tank operating mode and temperature, the total transportation scheduling costs of the storage and transportation system can be reduced by 9.1%. Therefore, this method can realize safe and stable operation of crude oil storage and transportation system.

Satellite monitoring of sea surface pollution

NASA Technical Reports Server (NTRS)

Fielder, G.; Telfer, D. J. (Principal Investigator)

1979-01-01

The author has identified the following significant results. Image processing techniques developed are well adapted to the exploration and isolation of local areas which exhibit small temperature differences between themselves and their surroundings. In the worst case of imagery of small areal extent of sea surface having no coastal boundary in the area, there is yet no method of distinguishing unambiguously an oil spill from fog, cloud, the effect produced by shallow sediments, or the effects of naturally occuring thermal fronts. In the case of uniform slicks of liquid North Sea oil in still air, laboratory simulation experiments show that, for oil thicknesses in excess of 1 or 2 mm, there is, under equilibrium conditions, little dependence of oil surface temperature on the thickness of the oil layer. The surface temperature of oil is consistently higher than that of water, the difference being about 1 K at low values of relative humidity, but tending to increase as the relative humidity increases.

Management and control of microbiologically influenced corrosion (MIC) in the oil and gas industry-Overview and a North Sea case study.

PubMed

Skovhus, Torben Lund; Eckert, Richard B; Rodrigues, Edgar

2017-08-20

Microbiologically influenced corrosion (MIC) is the terminology applied where the actions of microorganisms influence the corrosion process. In literature, terms such as microbial corrosion, biocorrosion, microbially influenced/induced corrosion, and biodegradation are often applied. MIC research in the oil and gas industry has seen a revolution over the past decade, with the introduction of molecular microbiological methods: (MMM) as well as new industry standards and procedures of sampling biofilm and corrosion products from the process system. This review aims to capture the most important trends the oil and gas industry has seen regarding MIC research over the past decade. The paper starts out with an overview of where in the process stream MIC occurs - from the oil reservoir to the consumer. Both biotic and abiotic corrosion mechanisms are explained in the context of managing MIC using a structured corrosion management (CM) approach. The corrosion management approach employs the elements of a management system to ensure that essential corrosion control activities are carried out in an effective, sustainable, well-planned and properly executed manner. The 3-phase corrosion management approach covering of both biotic and abiotic internal corrosion mechanisms consists of 1) corrosion assessment, 2) corrosion mitigation and 3) corrosion monitoring. Each of the three phases are described in detail with links to recent field cases, methods, industry standards and sampling protocols. In order to manage the corrosion threat, operators commonly use models to support decision making. The models use qualitative, semi-quantitative or quantitative measures to help assess the rate of degradation caused by MIC. The paper reviews four existing models for MIC Threat Assessment and describe a new model that links the threat of MIC in the oil processing system located on an offshore platform with a Risk Based Inspection (RBI) approach. A recent field case highlights and explains the conflicting historic results obtained through serial dilution of culture media using the most probable number (MPN) method as compared to data obtained from corrosion monitoring and the quantitative polymerase chain reaction (qPCR) method. Results from qPCR application in the field case have changed the way MIC is monitored on the oil production facility in the North Sea. A number of high quality resources have been published as technical conference papers, books, educational videos and peer-reviewed scientific papers, and thus we end the review with an updated list of state-of-the-art resources for anyone desiring to become more familiar with the topic of MIC in the upstream oil and gas sector. Copyright © 2017 Elsevier B.V. All rights reserved.

40 CFR 464.36 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 0.0257 0.00838 Oil and Grease (for alternate monitoring) 1.43 0.476 (2) Applicable to plants that... Oil and Grease (for alternate monitoring) 1.43 0.476 (c) Dust Collection Scrubber Operations. (1... TTO 2.04 0.664 Oil and Grease (for alternate monitoring) 22.5 7.51 (2) Applicable to plants that are...

40 CFR 464.36 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 0.0257 0.00838 Oil and Grease (for alternate monitoring) 1.43 0.476 (2) Applicable to plants that... Oil and Grease (for alternate monitoring) 1.43 0.476 (c) Dust Collection Scrubber Operations. (1... TTO 2.04 0.664 Oil and Grease (for alternate monitoring) 22.5 7.51 (2) Applicable to plants that are...

Air concentrations of volatile compounds near oil and gas production: a community-based exploratory study.

PubMed

Macey, Gregg P; Breech, Ruth; Chernaik, Mark; Cox, Caroline; Larson, Denny; Thomas, Deb; Carpenter, David O

2014-10-30

Horizontal drilling, hydraulic fracturing, and other drilling and well stimulation technologies are now used widely in the United States and increasingly in other countries. They enable increases in oil and gas production, but there has been inadequate attention to human health impacts. Air quality near oil and gas operations is an underexplored human health concern for five reasons: (1) prior focus on threats to water quality; (2) an evolving understanding of contributions of certain oil and gas production processes to air quality; (3) limited state air quality monitoring networks; (4) significant variability in air emissions and concentrations; and (5) air quality research that misses impacts important to residents. Preliminary research suggests that volatile compounds, including hazardous air pollutants, are of potential concern. This study differs from prior research in its use of a community-based process to identify sampling locations. Through this approach, we determine concentrations of volatile compounds in air near operations that reflect community concerns and point to the need for more fine-grained and frequent monitoring at points along the production life cycle. Grab and passive air samples were collected by trained volunteers at locations identified through systematic observation of industrial operations and air impacts over the course of resident daily routines. A total of 75 volatile organics were measured using EPA Method TO-15 or TO-3 by gas chromatography/mass spectrometry. Formaldehyde levels were determined using UMEx 100 Passive Samplers. Levels of eight volatile chemicals exceeded federal guidelines under several operational circumstances. Benzene, formaldehyde, and hydrogen sulfide were the most common compounds to exceed acute and other health-based risk levels. Air concentrations of potentially dangerous compounds and chemical mixtures are frequently present near oil and gas production sites. Community-based research can provide an important supplement to state air quality monitoring programs.

Prooxidant effect of α-tocopherol on soybean oil. Global monitoring of its oxidation process under accelerated storage conditions by 1H nuclear magnetic resonance.

PubMed

Martin-Rubio, A S; Sopelana, P; Ibargoitia, M L; Guillén, María D

2018-04-15

The effect of adding α-tocopherol in proportions ranging from 0.002 to 5% in weight on the oxidative stability of soybean oil was studied. For the first time, the oxidation process under accelerated storage conditions including evolution of the molar percentages of the several types of oil acyl groups, and formation and evolution of various kinds of oxidation products comprising hydroperoxides, hydroxy-dienes and other alcohols, epoxides, aldehydes and keto-dienes, was followed by 1 H nuclear magnetic resonance. It is proved that, except in the lowest proportion, α-tocopherol not only exerts a prooxidant effect on soybean oil but also modifies its oxidation pathway, affecting the oxidation products generation rate, their nature, relative proportions and concentrations. It is noticeable that the highest α-tocopherol concentrations induce the generation of some toxic compounds at earlier stages of the thermoxidation process and sometimes in higher concentration, such as certain oxygenated α,β-unsaturated aldehydes and monoepoxides derived from linoleic groups. Copyright © 2017 Elsevier Ltd. All rights reserved.

Large-scale oil-in-ice experiment in the Barents Sea: monitoring of oil in water and MetOcean interactions.

PubMed

Faksness, Liv-Guri; Brandvik, Per Johan; Daae, Ragnhild L; Leirvik, Frode; Børseth, Jan Fredrik

2011-05-01

A large-scale field experiment took place in the marginal ice zone in the Barents Sea in May 2009. Fresh oil (7000 L) was released uncontained between the ice floes to study oil weathering and spreading in ice and surface water. A detailed monitoring of oil-in-water and ice interactions was performed throughout the six-day experiment. In addition, meteorological and oceanographic data were recorded for monitoring of the wind speed and direction, air temperature, currents and ice floe movements. The monitoring showed low concentrations of dissolved hydrocarbons and the predicted acute toxicity indicated that the acute toxicity was low. The ice field drifted nearly 80 km during the experimental period, and although the oil drifted with the ice, it remained contained between the ice floes. Copyright © 2011 Elsevier Ltd. All rights reserved.

Production and characterization of refined oils obtained from Indian oil sardine (Sardinella longiceps).

PubMed

Chakraborty, Kajal; Joseph, Deepu

2015-01-28

Crude Sardinella longiceps oil was refined in different stages such as degumming, neutralization, bleaching, and deodorization. The efficiency of these processes was evaluated on the basis of free fatty acid (FFA), peroxide (PV), p-anisidine (pAV), total oxidation (TOTOX), thiobarbituric acid reactive species (TBARS) values, Lovibond CIE-L*a*b* color analyses, and (1)H NMR or GC-MS experiments. The utilities of NMR-based proton signal characteristics as new analytical tools to understand the signature peaks and relative abundance of different fatty acids and monitoring the refining process of fish oil have been demonstrated. Phosphoric acid (1%) was found to be an effective degumming reagent to obtain oil with the lowest FFA, PV, pAV, TOTOX, and TBARS values and highest color reduction. Significant reduction in the contents of hydrocarbon functionalities as shown by the decrease in proton integral in the characteristic (1)H NMR region was demonstrated by using 1% H3PO4 during the course of the degumming process. A combination (1.25:3.75%) of activated charcoal and Fuller's earth at 3% concentration for a stirring time of 40 min was found to be effective in bleaching the sardine oil. This study demonstrated that unfavorable odor-causing components, particularly low molecular weight carbonyl compounds, could successfully be removed by the refining process. The alkane-dienals/alkanes, which cause unfavorable fishy odors, were successfully removed by distillation (100 °C) under vacuum with aqueous acetic acid solution (0.25 N) to obtain greater quality of refined sardine oil, a rich source of essential fatty acids and improved oxidative stability. The present study demonstrated that the four-stage refinement process of sardine oil resulted in a significant improvement in quality characteristics and nutritional values, particularly n-3 PUFAs, with improved fish oil characteristics for use in the pharmaceutical and functional food industries.

Comparison of electrical capacitance tomography & gamma densitometer measurement in viscous oil-gas flows

NASA Astrophysics Data System (ADS)

Archibong Eso, A.; Zhao, Yabin; Yeung, Hoi

2014-04-01

Multiphase flow is a common occurrence in industries such as nuclear, process, oil & gas, food and chemical. A prior knowledge of its features and characteristics is essential in the design, control and management of such processes due to its complex nature. Electrical Capacitance Tomography (ECT) and Gamma Densitometer (Gamma) are two promising approaches for multiphase visualization and characterization in process industries. In two phase oil & gas flow, ECT and Gamma are used in multiphase flow monitoring techniques due to their inherent simplicity, robustness, and an ability to withstand wide range of operational temperatures and pressures. High viscous oil (viscosity > 100 cP) is of interest because of its huge reserves, technological advances in its production and unlike conventional oil (oil viscosity < 100 cP) and gas flows where ECT and Gamma have been previously used, high viscous oil and gas flows comes with certain associated concerns which include; increased entrainment of gas bubbles dispersed in oil, shorter and more frequent slugs as well as oil film coatings on the walls of flowing conduits. This study aims to determine the suitability of both devices in the visualization and characterization of high-viscous oil and gas flow. Static tests are performed with both devices and liquid holdup measurements are obtained. Dynamic experiments were also conducted in a 1 & 3 inch facility at Cranfield University with a range of nominal viscosities (1000, 3000 & 7500 cP). Plug, slug and wavy annular flow patterns were identified by means of Probability Mass Function and time series analysis of the data acquired from Gamma and ECT devices with high speed camera used to validate the results. Measured Liquid holdups for both devices were also compared.

Petroleum mineral oil refining and evaluation of cancer hazard.

PubMed

Mackerer, Carl R; Griffis, Larry C; Grabowski, John S; Reitman, Fred A

2003-11-01

Petroleum base oils (petroleum mineral oils) are manufactured from crude oils by vacuum distillation to produce several distillates and a residual oil that are then further refined. Aromatics including alkylated polycyclic aromatic compounds (PAC) are undesirable constituents of base oils because they are deleterious to product performance and are potentially carcinogenic. In modern base oil refining, aromatics are reduced by solvent extraction, catalytic hydrotreating, or hydrocracking. Chronic exposure to poorly refined base oils has the potential to cause skin cancer. A chronic mouse dermal bioassay has been the standard test for estimating carcinogenic potential of mineral oils. The level of alkylated 3-7-ring PAC in raw streams from the vacuum tower must be greatly reduced to render the base oil noncarcinogenic. The processes that can reduce PAC levels are known, but the operating conditions for the processing units (e.g., temperature, pressure, catalyst type, residence time in the unit, unit engineering design, etc.) needed to achieve adequate PAC reduction are refinery specific. Chronic dermal bioassays provide information about whether conditions applied can make a noncarcinogenic oil, but cannot be used to monitor current production for quality control or for conducting research or developing new processes since this test takes at least 78 weeks to conduct. Three short-term, non-animal assays all involving extraction of oil with dimethylsulfoxide (DMSO) have been validated for predicting potential carcinogenic activity of petroleum base oils: a modified Ames assay of a DMSO extract, a gravimetric assay (IP 346) for wt. percent of oil extracted into DMSO, and a GC-FID assay measuring 3-7-ring PAC content in a DMSO extract of oil, expressed as percent of the oil. Extraction with DMSO concentrates PAC in a manner that mimics the extraction method used in the solvent refining of noncarcinogenic oils. The three assays are described, data demonstrating the validation of the assays are shown, and test results of currently manufactured base oils are summarized to illustrate the general lack of cancer hazard for the base oils now being manufactured.

40 CFR 464.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

....0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d) Dust Collection Scrubber...) 0.343 0.129 Total Phenols 0.258 0.09 TTO 0.613 0.2 Oil and grease (for alternate monitoring) 9.01 3...) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring) 330 110 (g) Melting Furnace...

40 CFR 464.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

....0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d) Dust Collection Scrubber...) 0.343 0.129 Total Phenols 0.258 0.09 TTO 0.613 0.2 Oil and grease (for alternate monitoring) 9.01 3...) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring) 330 110 (g) Melting Furnace...

40 CFR 464.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

....0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d) Dust Collection Scrubber...) 0.343 0.129 Total Phenols 0.258 0.09 TTO 0.613 0.2 Oil and grease (for alternate monitoring) 9.01 3...) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring) 330 110 (g) Melting Furnace...

40 CFR 467.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... TTO 0.057 Oil and grease (alternate monitoring parameter) 4.3 2.1 Subpart A Core Without an Annealing... Zinc 0.081 0.034 TTO 0.038 Oil and grease (alternate monitoring parameter) 2.9 1.5 Subpart A Continuous... Zinc 0.0029 0.0012 TTO 0.0014 Oil and grease (alternate monitoring parameter) 0.10 0.052 Subpart A...

40 CFR 467.56 - Pretreatment standards for new sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Zinc 0.051 0.021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0.50 0.50 Subpart E... 0.0002 Zinc 0.0020 0.0008 TTO 0.0014 Oil and grease (alternate monitoring parameter) 0.020 0.020....072 0.029 Cyanide 0.039 0.016 Zinc 0.198 0.134 TTO 0.082 Oil and grease (alternate monitoring...

40 CFR 464.16 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

....0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d) Dust Collection Scrubber...) 0.343 0.129 Total Phenols 0.258 0.09 TTO 0.613 0.2 Oil and grease (for alternate monitoring) 9.01 3...) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring) 330 110 (g) Melting Furnace...

40 CFR 467.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... TTO 0.057 Oil and grease (alternate monitoring parameter) 4.3 2.1 Subpart A Core Without an Annealing... Zinc 0.081 0.034 TTO 0.038 Oil and grease (alternate monitoring parameter) 2.9 1.5 Subpart A Continuous... Zinc 0.0029 0.0012 TTO 0.0014 Oil and grease (alternate monitoring parameter) 0.10 0.052 Subpart A...

40 CFR 467.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... TTO 0.057 Oil and grease (alternate monitoring parameter) 4.3 2.1 Subpart A Core Without an Annealing... Zinc 0.081 0.034 TTO 0.038 Oil and grease (alternate monitoring parameter) 2.9 1.5 Subpart A Continuous... Zinc 0.0029 0.0012 TTO 0.0014 Oil and grease (alternate monitoring parameter) 0.10 0.052 Subpart A...

Bioluminescent bioreporter integrated circuit

DOEpatents

Simpson, Michael L.; Sayler, Gary S.; Paulus, Michael J.

2000-01-01

Disclosed are monolithic bioelectronic devices comprising a bioreporter and an OASIC. These bioluminescent bioreporter integrated circuit are useful in detecting substances such as pollutants, explosives, and heavy-metals residing in inhospitable areas such as groundwater, industrial process vessels, and battlefields. Also disclosed are methods and apparatus for environmental pollutant detection, oil exploration, drug discovery, industrial process control, and hazardous chemical monitoring.

Monitoring of oil pollution at Gemsa Bay and bioremediation capacity of bacterial isolates with biosurfactants and nanoparticles.

PubMed

El-Sheshtawy, H S; Khalil, N M; Ahmed, W; Abdallah, R I

2014-10-15

Fifteen crude oil-degrading bacterial isolates were isolated from an oil-polluted area in Gemsa Bay, Red Sea, Egypt. Two bacterial species showed the highest growth rate on crude oil hydrocarbons. From an analysis of 16S rRNA sequences, these isolates were identified as Pseudomonas xanthomarina KMM 1447 and Pseudomonas stutzeri ATCC 17588. Gas Chromatographic (GC) analysis of the crude oil remaining in the culture medium after one week at 30°C showed that the optimum biodegradation of crude petroleum oil was demonstrated at 50% in medium containing biosurfactant with two types of nanoparticles separately and two bacterial species. The complete degradation of some different members of polyaromatics and the percentage biodegradation of other polyaromatics increased in microcosm containing two different types of nanoparticles with biosurfactant after 7 days. In conclusion, these bacterial strains may be useful for the bioremediation process in the Gemsa Bay, Red Sea decreasing oil pollution in this marine ecosystem. Copyright © 2014 Elsevier Ltd. All rights reserved.

Synthesis of fatty acid methyl ester from used vegetable cooking oil by solid reusable Mg 1-x Zn 1+x O2 catalyst.

PubMed

Olutoye, M A; Hameed, B H

2011-02-01

Fatty acid methyl ester was produced from used vegetable cooking oil using Mg(1-)(x) Zn(1+)(x)O(2) solid catalyst and the performance monitored in terms of ester content obtained. Used vegetable cooking oil was employed to reduce operation cost of biodiesel. The significant operating parameters which affect the overall yield of the process were studied. The highest ester content, 80%, was achieved with the catalyst during 4h 15 min reaction at 188°C with methanol to oil ratio of 9:1 and catalyst loading of 2.55 wt% oil. Also, transesterification of virgin oil gave higher yield with the heterogeneous catalyst and showed high selectivity towards ester production. The used vegetable cooking oil did not require any rigorous pretreatment. Catalyst stability was examined and there was no leaching of the active components, and its performance was as good at the fourth as at the first cycle. Copyright © 2010 Elsevier Ltd. All rights reserved.

Optical transmission measurements for in-line monitoring of turbid oil-water emulsions

NASA Astrophysics Data System (ADS)

Metz, Philipp; Dopf, Katja; Aichholz, Markus; Riedel, Boris; Lemmer, Uli; Freudig, Barbara; Zimmermann, Clifton; Gerken, Martina

2014-05-01

For absorbing media the concentration may be calculated directly from the optical transmission following the logarithmic dependence given in the Lambert-Beer law. Due to multiple scattering events in oil-water emulsions (e.g. milk, cream, etc.), these exhibit a nonlinear relationship between the attenuation and the oil concentration. We demonstrate that for increasing oil content in oil-water emulsions the attenuation first increases, then levels out, and finally even decreases for a fat content of 60%. Single-wavelength optical transmission measurements are found to be well suited for the in-line monitoring of oil-water emulsions of fat contents below 20%, e.g., for the in-line fat content monitoring of milk. Using experiments and ray-tracing simulations we evaluate system optimization.

Fingerprinting Deepwater Horizon Oil in the northern Gulf of Mexico using biomarkers and Gas Chromatography-Triple Quadrupole Mass Spectrometry (GC/MS/MS)

NASA Astrophysics Data System (ADS)

Adhikari, P. L.; Overton, E. B.; Maiti, K.; Wong, R. L.

2016-02-01

Petroleum biomarkers such as hopanes, steranes, and triaromatic steroids are more persistent than alkanes and aromatic compounds. Thus, they are often used to track spilled oil in the environments and as a proxy for weathering processes. The present study utilizes water samples, suspended and sinking particles, and seafloor sediments collected during 2011-2013 from various locations of the northern Gulf of Mexico with wide range of contaminated oil for Deepwater Horizon (DWH) oil fingerprinting. The MC252 source oil along with the samples collected in this study were analyzed using a gas chromatography coupled with a triple quadrupole mass spectrometry (GC/MS/MS) in Multiple Reaction Monitoring (MRM) mode and the results were compared with results from commonly used GC/MS selective ion monitoring (SIM) method. The results indicate that the MRM method separates interfering ions from interfering compounds and can be a powerful analytical strategy for a reliable identification and determination of trace levels of biomarkers in complex matrices. Source indicators such as the MRM fragment ion chromatograms of the biomarkers and their diagnostic ratios in samples were compared with the MC252 source oil. The preliminary results show that the biomarkers were below detection limits in dissolved samples. However, in few particulate and seafloor sediment samples, primarily from the immediate vicinity of the Macondo wellhead, contained their patterns. The results also illustrate that these biomarker compounds have been weathered within 1-3 years following the oil spill, and their DWH oil signature in some of these samples reflects this weathering.

Application of denaturing high-performance liquid chromatography for monitoring sulfate-reducing bacteria in oil fields.

PubMed

Priha, Outi; Nyyssönen, Mari; Bomberg, Malin; Laitila, Arja; Simell, Jaakko; Kapanen, Anu; Juvonen, Riikka

2013-09-01

Sulfate-reducing bacteria (SRB) participate in microbially induced corrosion (MIC) of equipment and H2S-driven reservoir souring in oil field sites. Successful management of industrial processes requires methods that allow robust monitoring of microbial communities. This study investigated the applicability of denaturing high-performance liquid chromatography (DHPLC) targeting the dissimilatory sulfite reductase ß-subunit (dsrB) gene for monitoring SRB communities in oil field samples from the North Sea, the United States, and Brazil. Fifteen of the 28 screened samples gave a positive result in real-time PCR assays, containing 9 × 10(1) to 6 × 10(5) dsrB gene copies ml(-1). DHPLC and denaturing gradient gel electrophoresis (DGGE) community profiles of the PCR-positive samples shared an overall similarity; both methods revealed the same samples to have the lowest and highest diversity. The SRB communities were diverse, and different dsrB compositions were detected at different geographical locations. The identified dsrB gene sequences belonged to several phylogenetic groups, such as Desulfovibrio, Desulfococcus, Desulfomicrobium, Desulfobulbus, Desulfotignum, Desulfonatronovibrio, and Desulfonauticus. DHPLC showed an advantage over DGGE in that the community profiles were very reproducible from run to run, and the resolved gene fragments could be collected using an automated fraction collector and sequenced without a further purification step. DGGE, on the other hand, included casting of gradient gels, and several rounds of rerunning, excising, and reamplification of bands were needed for successful sequencing. In summary, DHPLC proved to be a suitable tool for routine monitoring of the diversity of SRB communities in oil field samples.

40 CFR 467.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 0.009 Cyanide 0.015 0.006 Zinc 0.073 0.031 TTO 0.035 Oil and grease (alternate monitoring parameter... 0.028 0.011 Zinc 0.14 0.058 TTO 0.065 Oil and grease (alternate monitoring parameter) 4.9 2.5....897 0.37 Cyanide 0.591 0.25 Zinc 2.98 1.24 TTO 1.41 Oil and grease (alternate monitoring parameter...

40 CFR 464.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

....0095 Oil and grease (for alternate monitoring) 0.363 0.121 (c) Die Casting Operations. PSES Pollutant... Total phenols 0.0074 0.0026 TTO 0.0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d...) 8.48 4.63 Lead (T) 8.7 4.3 Zinc (T) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring...

40 CFR 467.56 - Pretreatment standards for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

....008 Cyanide 0.010 0.004 Zinc 0.051 0.021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0....0007 0.0003 Cyanide 0.0004 0.0002 Zinc 0.0020 0.0008 TTO 0.0014 Oil and grease (alternate monitoring... etched Chromium 0.52 0.21 Cyanide 0.28 0.11 Zinc 1.42 0.59 TTO 0.96 Oil and grease (alternate monitoring...

40 CFR 464.26 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

....0104 Zinc (T) 0.0303 0.0116 TTO 0.0335 0.0109 Oil and grease (for alternate monitoring) 1.2 0.399 (b... TTO 1.65 0.54 Oil and Grease (for alternate monitoring 21.5 7.18 (d) Grinding Scrubber Operations. No... TTO 5.41 1.77 Oil and Grease (for alternate monitoring 70.6 23.5 (g) Mold Cooling Operations. PSNS...

40 CFR 467.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 0.009 Cyanide 0.015 0.006 Zinc 0.073 0.031 TTO 0.035 Oil and grease (alternate monitoring parameter... 0.028 0.011 Zinc 0.14 0.058 TTO 0.065 Oil and grease (alternate monitoring parameter) 4.9 2.5....897 0.37 Cyanide 0.591 0.25 Zinc 2.98 1.24 TTO 1.41 Oil and grease (alternate monitoring parameter...

40 CFR 467.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 0.009 Cyanide 0.015 0.006 Zinc 0.073 0.031 TTO 0.035 Oil and grease (alternate monitoring parameter... 0.028 0.011 Zinc 0.14 0.058 TTO 0.065 Oil and grease (alternate monitoring parameter) 4.9 2.5....897 0.37 Cyanide 0.591 0.25 Zinc 2.98 1.24 TTO 1.41 Oil and grease (alternate monitoring parameter...

40 CFR 467.56 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

....008 Cyanide 0.010 0.004 Zinc 0.051 0.021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0....0007 0.0003 Cyanide 0.0004 0.0002 Zinc 0.0020 0.0008 TTO 0.0014 Oil and grease (alternate monitoring... etched Chromium 0.52 0.21 Cyanide 0.28 0.11 Zinc 1.42 0.59 TTO 0.96 Oil and grease (alternate monitoring...

40 CFR 467.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2011 CFR

2011-07-01

....015 0.006 Zinc 0.073 0.031 TTO 0.035 Oil and grease (alternate monitoring parameter) 2.6 1.3 Subpart D....14 0.058 TTO 0.065 Oil and grease (alternate monitoring parameter) 4.9 2.5 Subpart D Solution Heat... Zinc 2.98 1.24 TTO 1.41 Oil and grease (alternate monitoring parameter) 110 53 Subpart D Cleaning or...

40 CFR 464.26 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

....0104 Zinc (T) 0.0303 0.0116 TTO 0.0335 0.0109 Oil and grease (for alternate monitoring) 1.2 0.399 (b... TTO 1.65 0.54 Oil and Grease (for alternate monitoring 21.5 7.18 (d) Grinding Scrubber Operations. No... TTO 5.41 1.77 Oil and Grease (for alternate monitoring 70.6 23.5 (g) Mold Cooling Operations. PSNS...

40 CFR 467.56 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

....008 Cyanide 0.010 0.004 Zinc 0.051 0.021 TTO 0.035 Oil and grease (alternate monitoring parameter) 0....0007 0.0003 Cyanide 0.0004 0.0002 Zinc 0.0020 0.0008 TTO 0.0014 Oil and grease (alternate monitoring... etched Chromium 0.52 0.21 Cyanide 0.28 0.11 Zinc 1.42 0.59 TTO 0.96 Oil and grease (alternate monitoring...

Use of ultrasound to monitor physical properties of soybean oil

NASA Astrophysics Data System (ADS)

Baêsso, R. M.; Oliveira, P. A.; Morais, G. C.; Alvarenga, A. V.; Costa-Félix, R. P. B.

2016-07-01

The study of the monitoring physical properties of soybean oil was performed. The pulse-echo method allowed measuring the density and viscosity of the oil in real time and accurately. The physical property values were related to the acoustic time of flight ratio, dimensionless parameter that can be obtained from any reference. In our case, we used the time of flight at 20°C as reference and a fixed distance between the transducer and the reflector. Ultrasonic monitoring technique employed here has shown promising in the analysis of edible oils.

Integrating Oil Debris and Vibration Measurements for Intelligent Machine Health Monitoring. Degree awarded by Toledo Univ., May 2002

NASA Technical Reports Server (NTRS)

Dempsey, Paula J.

2003-01-01

A diagnostic tool for detecting damage to gears was developed. Two different measurement technologies, oil debris analysis and vibration were integrated into a health monitoring system for detecting surface fatigue pitting damage on gears. This integrated system showed improved detection and decision-making capabilities as compared to using individual measurement technologies. This diagnostic tool was developed and evaluated experimentally by collecting vibration and oil debris data from fatigue tests performed in the NASA Glenn Spur Gear Fatigue Rig. An oil debris sensor and the two vibration algorithms were adapted as the diagnostic tools. An inductance type oil debris sensor was selected for the oil analysis measurement technology. Gear damage data for this type of sensor was limited to data collected in the NASA Glenn test rigs. For this reason, this analysis included development of a parameter for detecting gear pitting damage using this type of sensor. The vibration data was used to calculate two previously available gear vibration diagnostic algorithms. The two vibration algorithms were selected based on their maturity and published success in detecting damage to gears. Oil debris and vibration features were then developed using fuzzy logic analysis techniques, then input into a multi sensor data fusion process. Results show combining the vibration and oil debris measurement technologies improves the detection of pitting damage on spur gears. As a result of this research, this new diagnostic tool has significantly improved detection of gear damage in the NASA Glenn Spur Gear Fatigue Rigs. This research also resulted in several other findings that will improve the development of future health monitoring systems. Oil debris analysis was found to be more reliable than vibration analysis for detecting pitting fatigue failure of gears and is capable of indicating damage progression. Also, some vibration algorithms are as sensitive to operational effects as they are to damage. Another finding was that clear threshold limits must be established for diagnostic tools. Based on additional experimental data obtained from the NASA Glenn Spiral Bevel Gear Fatigue Rig, the methodology developed in this study can be successfully implemented on other geared systems.

SAR processing in the cloud for oil detection in the Arctic

NASA Astrophysics Data System (ADS)

Garron, J.; Stoner, C.; Meyer, F. J.

2016-12-01

A new world of opportunity is being thawed from the ice of the Arctic, driven by decreased persistent Arctic sea-ice cover, increases in shipping, tourism, natural resource development. Tools that can automatically monitor key sea ice characteristics and potential oil spills are essential for safe passage in these changing waters. Synthetic aperture radar (SAR) data can be used to discriminate sea ice types and oil on the ocean surface and also for feature tracking. Additionally, SAR can image the earth through the night and most weather conditions. SAR data is volumetrically large and requires significant computing power to manipulate. Algorithms designed to identify key environmental features, like oil spills, in SAR imagery require secondary processing, and are computationally intensive, which can functionally limit their application in a real-time setting. Cloud processing is designed to manage big data and big data processing jobs by means of small cycles of off-site computations, eliminating up-front hardware costs. Pairing SAR data with cloud processing has allowed us to create and solidify a processing pipeline for SAR data products in the cloud to compare operational algorithms efficiency and effectiveness when run using an Alaska Satellite Facility (ASF) defined Amazon Machine Image (AMI). The products created from this secondary processing, were compared to determine which algorithm was most accurate in Arctic feature identification, and what operational conditions were required to produce the results on the ASF defined AMI. Results will be used to inform a series of recommendations to oil-spill response data managers and SAR users interested in expanding their analytical computing power.

33 CFR 157.43 - Discharges of clean and segregated ballast: Seagoing tank vessels of 150 gross tons or more.

Code of Federal Regulations, 2014 CFR

2014-07-01

... an approved oil discharge monitoring and control system or, if discharged before the required oil... mixture in the ballast. Use of an oil discharge monitoring and control system is not required. This... OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Vessel Operation § 157.43...

33 CFR 157.43 - Discharges of clean and segregated ballast: Seagoing tank vessels of 150 gross tons or more.

Code of Federal Regulations, 2013 CFR

2013-07-01

... an approved oil discharge monitoring and control system or, if discharged before the required oil... mixture in the ballast. Use of an oil discharge monitoring and control system is not required. This... OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Vessel Operation § 157.43...

33 CFR 157.43 - Discharges of clean and segregated ballast: Seagoing tank vessels of 150 gross tons or more.

Code of Federal Regulations, 2010 CFR

2010-07-01

... an approved oil discharge monitoring and control system or, if discharged before the required oil... mixture in the ballast. Use of an oil discharge monitoring and control system is not required. This... OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Vessel Operation § 157.43...

33 CFR 157.43 - Discharges of clean and segregated ballast: Seagoing tank vessels of 150 gross tons or more.

Code of Federal Regulations, 2012 CFR

2012-07-01

... an approved oil discharge monitoring and control system or, if discharged before the required oil... mixture in the ballast. Use of an oil discharge monitoring and control system is not required. This... OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Vessel Operation § 157.43...

33 CFR 157.43 - Discharges of clean and segregated ballast: Seagoing tank vessels of 150 gross tons or more.

Code of Federal Regulations, 2011 CFR

2011-07-01

... an approved oil discharge monitoring and control system or, if discharged before the required oil... mixture in the ballast. Use of an oil discharge monitoring and control system is not required. This... OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Vessel Operation § 157.43...

Carbon Disulfide (CS2) Interference in Glucose Metabolism from Unconventional Oil and Gas Extraction and Processing Emissions.

PubMed

Rich, Alisa L; Patel, Jay T; Al-Angari, Samiah S

2016-01-01

Carbon disulfide (CS2) has been historically associated with the manufacturing of rayon, cellophane, and carbon tetrachloride production. This study is one of the first to identify elevated atmospheric levels of CS2 above national background levels and its mechanisms to dysregulate normal glucose metabolism. Interference in glucose metabolism can indirectly cause other complications (diabetes, neurodegenerative disease, and retinopathy), which may be preventable if proper precautions are taken. Rich et al found CS2 and 12 associated sulfide compounds present in the atmosphere in residential areas where unconventional shale oil and gas extraction and processing operations were occurring. Ambient atmospheric concentrations of CS2 ranged from 0.7 parts per billion by volume (ppbv) to 103 ppbv over a continuous 24-hour monitoring period. One-hour ambient atmospheric concentrations ranged from 3.4 ppbv to 504.6 ppbv. Using the U.S. Environmental Protection Agency Urban Air Toxic Monitoring Program study as a baseline comparison for atmospheric CS2 concentrations found in this study, it was determined that CS2 atmospheric levels were consistently elevated in areas where unconventional oil and gas extraction and processing occurred. The mechanisms by which CS2 interferes in normal glucose metabolism by dysregulation of the tryptophan metabolism pathway are presented in this study. The literature review found an increased potential for alteration of normal glucose metabolism in viscose rayon occupational workers exposed to CS2. Occupational workers in the energy extraction industry exposed to CS2 and other sulfide compounds may have an increased potential for glucose metabolism interference, which has been an indicator for diabetogenic effect and other related health impacts. The recommendation of this study is for implementation of regular monitoring of blood glucose levels in CS2-exposed populations as a preventative health measure.

A new twist to a traditional approach to environmental monitoring: differentiation of oil sands process-affected waters and natural systems by comparison of individual organic acids

NASA Astrophysics Data System (ADS)

Scarlett, A.; Lengger, S.; West, C.; Rowland, S.

2013-12-01

Review panels of both the Canadian Federal and Alberta Provincial governments have recommended a complete overhaul of existing monitoring programs of the Athabasca oil sands industry and have called for a greater understanding of the potential impacts of mining activities to allow for future sustainable development. Due to the no release policy, it is critical that leakages of oil sands process-affected waters (OSPW) from tailings ponds can be differentiated from natural waters flowing through the McMurray formation into the Athabasca river system. Environmental monitoring of oil contamination usually entails profiling of known compounds, e.g. the US EPA list of priority Polycyclic Aromatic Hydrocarbons, but until now a similar approach has not been possible for OSPW due to its extreme complexity. It has been estimated that the number of carboxylic acids, historically referred to as ';naphthenic acids' (NA) in OSPW, to be in excess of 10000 compounds. Until recently, individual structures of these NA were unknown but analyses by tandem gas chromatography mass spectrometry (GCxGC-MS) have now begun to reveal the individual structures of alicyclic, aromatic and sulphur-containing acids within OSPWs stored in tailings ponds. Now that some individual structures present in OSPW are known and standards are available, a methodological approach similar to traditional oil monitoring can be developed using individual diamondoid NA and recently discovered diacids and applied to tailings pond OSPW and environmental waters. One obstacle to understanding whether the NA present in environmental groundwater samples are associated with particular tailings ponds is the lack of knowledge of the variability of OSPW within and between ponds. In the current study, GCxGC-MS analyses have been applied to statistically compare OSPWs of two industries, both temporally and spatially, using specific, known compounds as well as associated isomers. Although variation within individual ponds was observed, there was a significant difference (P < 0.05) between the ponds of the two industries. Having determined the variability in the ponds, further statistical analysis was applied to compare ratios of individual NAs in the ponds with those in groundwaters, near and distant from the ponds, thereby providing a measure of the probability that a particular groundwater sample is associated with a specific tailings pond. We have previously shown that the ability to identify individual chemical structures within these highly complex samples facilitates relevant toxicological testing and modelling. Here, we show it to be of crucial importance for differentiating tailings ponds and natural groundwaters and thus provides a relatively simple and robust means of monitoring anthropogenic impacts on natural systems arising from oil sands mining activities.

Comparison of electrical capacitance tomography and gamma densitometer measurement in viscous oil-gas flows

DOE Office of Scientific and Technical Information (OSTI.GOV)

Archibong Eso, A.; Zhao, Yabin; Yeung, Hoi

2014-04-11

Multiphase flow is a common occurrence in industries such as nuclear, process, oil and gas, food and chemical. A prior knowledge of its features and characteristics is essential in the design, control and management of such processes due to its complex nature. Electrical Capacitance Tomography (ECT) and Gamma Densitometer (Gamma) are two promising approaches for multiphase visualization and characterization in process industries. In two phase oil and gas flow, ECT and Gamma are used in multiphase flow monitoring techniques due to their inherent simplicity, robustness, and an ability to withstand wide range of operational temperatures and pressures. High viscous oilmore » (viscosity > 100 cP) is of interest because of its huge reserves, technological advances in its production and unlike conventional oil (oil viscosity < 100 cP) and gas flows where ECT and Gamma have been previously used, high viscous oil and gas flows comes with certain associated concerns which include; increased entrainment of gas bubbles dispersed in oil, shorter and more frequent slugs as well as oil film coatings on the walls of flowing conduits. This study aims to determine the suitability of both devices in the visualization and characterization of high-viscous oil and gas flow. Static tests are performed with both devices and liquid holdup measurements are obtained. Dynamic experiments were also conducted in a 1 and 3 inch facility at Cranfield University with a range of nominal viscosities (1000, 3000 and 7500 cP). Plug, slug and wavy annular flow patterns were identified by means of Probability Mass Function and time series analysis of the data acquired from Gamma and ECT devices with high speed camera used to validate the results. Measured Liquid holdups for both devices were also compared.« less

A New Meteo-oceanographic and Environmental Monitoring Laboratory in Brazil

NASA Astrophysics Data System (ADS)

Fontes, Roberto F. C.; Dottori, Marcelo; Silveira, Ilson C. A.; Castro, Belmiro M.

2013-04-01

The newer oil provinces in the pre-salt regions off the Brazilian Coast have raised the necessity of the creation of monitoring and observational centers, regarding the best comprehension on the ocean and atmosphere dynamics. The relation between industry and university is a concept based on collaboration, and it is an innovative social experiment in Brazil. The sustainability of that collaboration depends on the balance of mutual interests on private business and public academic institutions. The entrepreneur needs continuous accesses to the new academic researches, and the greatest benefit, for the academy, are funding complementation and personnel qualification. We need to establish a thread of new challenges, some of them based on disruption of paradigms in the Brazilian academic culture, and removal of obstructive clauses from the entrepreneur. Questioning and methods revalidation, in the oceanic environment areas, also requires a collaborative and interdisciplinary effort, congregating the physical aspects along with others compartments of the environmental monitoring. We proposed the creation of a Meteo-oceanographic and Environmental Monitoring Laboratory - LAMMOA (Portuguese acronym), which will be installed in a new facility funded by PETROBRAS (the Brazilian leading oil company) and ruled by USP, UNESP and UNICAMP, the state public universities in Santos (São Paulo State, Brazil). The new facility will be a research center in oil and gas activities, named CENPEG-BS (Portuguese acronym for Research Center of Oil and Gas in the Bay of Santos). Several laboratories and groups will work together, in a highly collaborative environment and so, capable of quickly respond to sudden demands on offshore activities and logistic operations, as well as in contingency situations. LAMMOA will continuous monitor oceanic regions where the pre-salt activities of oil exploitation occur. It will monitor meteo-oceanographic parameters like winds, waves and currents, providing suitable data for offshore and transportation activities. For such, LAMMOA will operate a system of moored acoustic current meters and others environmental sensors, applying analytical and numerical methods for improving comprehension of the oceanic environment. Oceanographic gliders, satellite measurements and newer observational technics should replace expensive hydrographic surveys, and enhance the efforts on the knowledge of oceanographic processes as those that occur in the Brazil Current. We hope these actions create a new culture on continuous monitoring the ocean, along and offshore the 8,000-km Brazilian coast, including its continental shelf and coastal regions.

Enhancement of the Wear Particle Monitoring Capability of Oil Debris Sensors Using a Maximal Overlap Discrete Wavelet Transform with Optimal Decomposition Depth

PubMed Central

Li, Chuan; Peng, Juan; Liang, Ming

2014-01-01

Oil debris sensors are effective tools to monitor wear particles in lubricants. For in situ applications, surrounding noise and vibration interferences often distort the oil debris signature of the sensor. Hence extracting oil debris signatures from sensor signals is a challenging task for wear particle monitoring. In this paper we employ the maximal overlap discrete wavelet transform (MODWT) with optimal decomposition depth to enhance the wear particle monitoring capability. The sensor signal is decomposed by the MODWT into different depths for detecting the wear particle existence. To extract the authentic particle signature with minimal distortion, the root mean square deviation of kurtosis value of the segmented signal residue is adopted as a criterion to obtain the optimal decomposition depth for the MODWT. The proposed approach is evaluated using both simulated and experimental wear particles. The results show that the present method can improve the oil debris monitoring capability without structural upgrade requirements. PMID:24686730

Enhancement of the wear particle monitoring capability of oil debris sensors using a maximal overlap discrete wavelet transform with optimal decomposition depth.

PubMed

Li, Chuan; Peng, Juan; Liang, Ming

2014-03-28

Oil debris sensors are effective tools to monitor wear particles in lubricants. For in situ applications, surrounding noise and vibration interferences often distort the oil debris signature of the sensor. Hence extracting oil debris signatures from sensor signals is a challenging task for wear particle monitoring. In this paper we employ the maximal overlap discrete wavelet transform (MODWT) with optimal decomposition depth to enhance the wear particle monitoring capability. The sensor signal is decomposed by the MODWT into different depths for detecting the wear particle existence. To extract the authentic particle signature with minimal distortion, the root mean square deviation of kurtosis value of the segmented signal residue is adopted as a criterion to obtain the optimal decomposition depth for the MODWT. The proposed approach is evaluated using both simulated and experimental wear particles. The results show that the present method can improve the oil debris monitoring capability without structural upgrade requirements.

Simultaneous monitoring the real and imaginary parts of the analyte refractive index using liquid-core photonic bandgap Bragg fibers.

PubMed

Li, Jingwen; Qu, Hang; Skorobogatiy, Maksim

2015-09-07

We demonstrate simultaneous monitoring of the real and imaginary parts of the liquid analyte refractive index by using a hollow-core Bragg fiber. We apply this two-channel fiber sensor to monitor concentrations of various commercial cooling oils. The sensor operates using spectral monitoring of the fiber bandgap center wavelength, as well as monitoring of the fiber transmission amplitude at mid-bandgap position. The sensitivity of the fiber sensor to changes in the real part of the core refractive index is found to be 1460nm/Refractive index unit (RIU). By using spectral modality and effective medium theory, we determine the concentrations of the two commercial fluids from the measured refractive indices with an accuracy of ~0.57% for both low- and high-loss oils. Moreover, using an amplitude-based detection modality allows determination of the oil concentration with accuracy of ~1.64% for low-loss oils and ~2.81% for the high-loss oils.

40 CFR 464.35 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

....84 2.86 Zinc (T) 10.8 4.07 TTO 13.2 4.3 Oil and Grease (for alternate monitoring) 330 110 (2....0576 Zinc (T) 0.217 0.0827 TTO 0.0797 0.026 Oil and grease (for alternate monitoring) 4.43 1.48 (h... Zinc (T) 0.178 0.0673 TTO 0.0257 0.00838 Oil and grease (for alternate monitoring) 5.46 1.82 (2...

40 CFR 464.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 0.029 0.0095 Oil and grease (for alternate monitoring) 0.363 0.121 (c) Die Casting Operations. PSES... Total phenols 0.0074 0.0026 TTO 0.0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d...) 8.48 4.63 Lead (T) 8.7 4.3 Zinc (T) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring...

40 CFR 464.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 0.029 0.0095 Oil and grease (for alternate monitoring) 0.363 0.121 (c) Die Casting Operations. PSES... Total phenols 0.0074 0.0026 TTO 0.0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d...) 8.48 4.63 Lead (T) 8.7 4.3 Zinc (T) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring...

40 CFR 464.35 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

....84 2.86 Zinc (T) 10.8 4.07 TTO 13.2 4.3 Oil and Grease (for alternate monitoring) 330 110 (2....0576 Zinc (T) 0.217 0.0827 TTO 0.0797 0.026 Oil and grease (for alternate monitoring) 4.43 1.48 (h... Zinc (T) 0.178 0.0673 TTO 0.0257 0.00838 Oil and grease (for alternate monitoring) 5.46 1.82 (2...

40 CFR 464.15 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 0.029 0.0095 Oil and grease (for alternate monitoring) 0.363 0.121 (c) Die Casting Operations. PSES... Total phenols 0.0074 0.0026 TTO 0.0308 0.01 Oil and grease (for alternate monitoring) 0.259 0.0864 (d...) 8.48 4.63 Lead (T) 8.7 4.3 Zinc (T) 12.6 4.74 TTO 18.1 5.91 Oil and grease (for alternate monitoring...

Effect of Opuntia ficus-indica flowers maceration on quality and on heat stability of olive oil.

PubMed

Ammar, Imène; BenAmira, Amal; Khemakem, Ibtihel; Attia, Hamadi; Ennouri, Monia

2017-05-01

This study was focused on the evaluation of the quality and the oxidative stability of olive oil added with Opuntia ficus - indica flowers. Two different amounts of O. ficus - indica flowers were considered 5 and 15% (w/w). The olive oils were evaluated towards their quality, fatty acids profile, total phenol contents and thermal properties by differential scanning calorimetry. The oxidative stability was also monitored by employing the Rancimat and the oven test based on accelerating the oxidation process during storage. The addition of O. ficus - indica flowers induced an increase in free acidity values and a variation in fatty acids profile of olive oils but values remained under the limits required for an extra-virgin olive oil. The obtained olive oils were nutritionally enriched due to the increase in their phenols content. The oxidative stability was generally improved, mainly in olive oil enriched with 5% Opuntia ficus - indica flowers. These findings proved that this enriched olive oil could be considered as a product with a greater added value.

Terahertz time-domain spectroscopy of edible oils

PubMed Central

Valchev, Dimitar G.

2017-01-01

Chemical degradation of edible oils has been studied using conventional spectroscopic methods spanning the spectrum from ultraviolet to mid-IR. However, the possibility of morphological changes of oil molecules that can be detected at terahertz frequencies is beginning to receive some attention. Furthermore, the rapidly decreasing cost of this technology and its capability for convenient, in situ measurement of material properties, raises the possibility of monitoring oil during cooking and processing at production facilities, and more generally within the food industry. In this paper, we test the hypothesis that oil undergoes chemical and physical changes when heated above the smoke point, which can be detected in the 0.05–2 THz spectral range, measured using the conventional terahertz time-domain spectroscopy technique. The measurements demonstrate a null result in that there is no significant change in the spectra of terahertz optical parameters after heating above the smoke point for 5 min. PMID:28680681

Terahertz time-domain spectroscopy of edible oils

NASA Astrophysics Data System (ADS)

Dinovitser, Alex; Valchev, Dimitar G.; Abbott, Derek

2017-06-01

Chemical degradation of edible oils has been studied using conventional spectroscopic methods spanning the spectrum from ultraviolet to mid-IR. However, the possibility of morphological changes of oil molecules that can be detected at terahertz frequencies is beginning to receive some attention. Furthermore, the rapidly decreasing cost of this technology and its capability for convenient, in situ measurement of material properties, raises the possibility of monitoring oil during cooking and processing at production facilities, and more generally within the food industry. In this paper, we test the hypothesis that oil undergoes chemical and physical changes when heated above the smoke point, which can be detected in the 0.05-2 THz spectral range, measured using the conventional terahertz time-domain spectroscopy technique. The measurements demonstrate a null result in that there is no significant change in the spectra of terahertz optical parameters after heating above the smoke point for 5 min.

Terahertz time-domain spectroscopy of edible oils.

PubMed

Dinovitser, Alex; Valchev, Dimitar G; Abbott, Derek

2017-06-01

Chemical degradation of edible oils has been studied using conventional spectroscopic methods spanning the spectrum from ultraviolet to mid-IR. However, the possibility of morphological changes of oil molecules that can be detected at terahertz frequencies is beginning to receive some attention. Furthermore, the rapidly decreasing cost of this technology and its capability for convenient, in situ measurement of material properties, raises the possibility of monitoring oil during cooking and processing at production facilities, and more generally within the food industry. In this paper, we test the hypothesis that oil undergoes chemical and physical changes when heated above the smoke point, which can be detected in the 0.05-2 THz spectral range, measured using the conventional terahertz time-domain spectroscopy technique. The measurements demonstrate a null result in that there is no significant change in the spectra of terahertz optical parameters after heating above the smoke point for 5 min.

Asphaltene dispersants as demulsification aids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manek, M.B.

1995-11-01

Destabilization of petroleum asphaltenes may cause a multitude of problems in crude oil recovery and production. One major problem is their agglomeration at the water-oil interface of crude oil emulsions. Once agglomeration occurs, destabilized asphaltenes can form a thick pad in the dehydration equipment, which significantly reduces the demulsification rate. Certain polymeric dispersants increase asphaltene solubilization in hydrocarbon media, and when used in conjunction with emulsion breakers, facilitate the demulsification process. Two case studies are presented that demonstrate how asphaltene dispersants can efficiently inhibit pad formation and help reduce demulsifier dosage. Criteria for dispersant application and selection are discussed, whichmore » include the application of a novel laboratory technique to assess asphaltene stabilization in the crude oil. The technique monitors asphaltene agglomeration while undergoing titration with an incompatible solvent (precipitant). The method was used to evaluate stabilization of asphaltenes in the crude oil and to screen asphaltene dispersants.« less

Monitoring of bisphenols in canned tuna from Italian markets.

PubMed

Fattore, Margherita; Russo, Giacomo; Barbato, Francesco; Grumetto, Lucia; Albrizio, Stefania

2015-09-01

Monitoring of food contamination from bisphenols is a necessary process for the consumers' risk assessment. A method for the quali-quantitative analysis of Bisphenol A (BPA), Bisphenol B (BPB), Bisphenol A Diglycidyl Ether (BADGE), and Bisphenol F Diglycidyl Ether (BFDGE), by liquid chromatography with fluorescence detection (LC-FD), was performed and validated for their determination in 33 samples of tuna fish, canned in either oil or aqueous medium. Samples were collected in Italian markets. Tuna and the correspondent preservation medium were analyzed separately. Detected levels of bisphenols ranged from 19.1 to 187.0 ng/g in tuna matrix and from 6.3 to 66.9 ng/mL in oil medium. No bisphenols were found in aqueous medium. At least one of the analytes was found in 83% of the tuna samples in oil medium, whereas tuna samples in aqueous medium showed BPA alone in 67% of samples. 21% of the oil medium samples resulted positive for at least one bisphenol. On the basis of measured concentrations and general daily ingestion rate of canned tuna fish, the probable daily intake of BPA for Italian population was calculated. Copyright © 2015 Elsevier Ltd. All rights reserved.

Satellite passive remote sensing of off-shore pollutants, volume 2

NASA Technical Reports Server (NTRS)

1979-01-01

Satellite detection and monitoring of off-shore dumped pollutants, other than oil, are discussed. Summaries of satellite sensor performance in three spectral bands (visible, infrared, and microwave) are presented. The bulk of the report gives all the calculations, trade-offs and limitations of the three sensor systems. It is asserted that the problem of pollution monitoring is not a sensor problem but a problem of mathematical modeling and data processing.

Microwave/Sonic Apparatus Measures Flow and Density in Pipe

NASA Technical Reports Server (NTRS)

Arndt, G. D.; Ngo, Phong; Carl, J. R.; Byerly, Kent A.

2004-01-01

An apparatus for measuring the rate of flow and the mass density of a liquid or slurry includes a special section of pipe instrumented with microwave and sonic sensors, and a computer that processes digitized readings taken by the sensors. The apparatus was conceived specifically for monitoring a flow of oil-well-drilling mud, but the basic principles of its design and operation are also applicable to monitoring flows of other liquids and slurries.

New problems and opportunities of oil spill monitoring systems

NASA Astrophysics Data System (ADS)

Barenboim, G. M.; Borisov, V. M.; Golosov, V. N.; Saveca, A. Yu.

2015-04-01

Emergency oil and oil products spills represent a great danger to the environment, including ecosystems, and to the population. New problems of such dangerous spills and methods of early detection are discussed in this paper. It is proposed to conduct assessment of biological hazards of such spills on the basis of data on the distribution of individual oil hydrocarbons within the column of the water body and computer predictions of their toxicity. Oil radioactivity, which is associated with uranium and thorium, is seen as the important aspect of the oil spill danger, especially in watercourses. The need for an automated monitoring system for the early detection of oil spills in water bodies is analysed. The proposed system consists of three subsystems. The first remote sensing subsystem is based on powerful fluorescent lidars; experimental results on lidar registration of oil pollution of water are reported. The second subsystem uses a network of automatic monitoring stations with contact detectors. The third subsystem is the combined sensor system based on remote and contact technologies.

Evaluation for Bearing Wear States Based on Online Oil Multi-Parameters Monitoring

PubMed Central

Hu, Hai-Feng

2018-01-01

As bearings are critical components of a mechanical system, it is important to characterize their wear states and evaluate health conditions. In this paper, a novel approach for analyzing the relationship between online oil multi-parameter monitoring samples and bearing wear states has been proposed based on an improved gray k-means clustering model (G-KCM). First, an online monitoring system with multiple sensors for bearings is established, obtaining oil multi-parameter data and vibration signals for bearings through the whole lifetime. Secondly, a gray correlation degree distance matrix is generated using a gray correlation model (GCM) to express the relationship of oil monitoring samples at different times and then a KCM is applied to cluster the matrix. Analysis and experimental results show that there is an obvious correspondence that state changing coincides basically in time between the lubricants’ multi-parameters and the bearings’ wear states. It also has shown that online oil samples with multi-parameters have early wear failure prediction ability for bearings superior to vibration signals. It is expected to realize online oil monitoring and evaluation for bearing health condition and to provide a novel approach for early identification of bearing-related failure modes. PMID:29621175

Evaluation for Bearing Wear States Based on Online Oil Multi-Parameters Monitoring.

PubMed

Wang, Si-Yuan; Yang, Ding-Xin; Hu, Hai-Feng

2018-04-05

As bearings are critical components of a mechanical system, it is important to characterize their wear states and evaluate health conditions. In this paper, a novel approach for analyzing the relationship between online oil multi-parameter monitoring samples and bearing wear states has been proposed based on an improved gray k-means clustering model (G-KCM). First, an online monitoring system with multiple sensors for bearings is established, obtaining oil multi-parameter data and vibration signals for bearings through the whole lifetime. Secondly, a gray correlation degree distance matrix is generated using a gray correlation model (GCM) to express the relationship of oil monitoring samples at different times and then a KCM is applied to cluster the matrix. Analysis and experimental results show that there is an obvious correspondence that state changing coincides basically in time between the lubricants' multi-parameters and the bearings' wear states. It also has shown that online oil samples with multi-parameters have early wear failure prediction ability for bearings superior to vibration signals. It is expected to realize online oil monitoring and evaluation for bearing health condition and to provide a novel approach for early identification of bearing-related failure modes.

Characterization and determination of naphthenic acids species in oil sands process-affected water and groundwater from oil sands development area of Alberta, Canada.

PubMed

Huang, Rongfu; Chen, Yuan; Meshref, Mohamed N A; Chelme-Ayala, Pamela; Dong, Shimiao; Ibrahim, Mohamed D; Wang, Chengjin; Klamerth, Nikolaus; Hughes, Sarah A; Headley, John V; Peru, Kerry M; Brown, Christine; Mahaffey, Ashley; Gamal El-Din, Mohamed

2018-01-01

This work reports the monitoring and assessment of naphthenic acids (NAs) in oil sands process-affected water (OSPW), Pleistocene channel aquifer groundwater (PLCA), and oil sands basal aquifer groundwater (OSBA) from an active oil sands development in Alberta, Canada, using ultra performance liquid chromatography time-of-flight mass spectrometry (UPLC-TOF-MS) analysis with internal standard (ISTD) and external standard (ESTD) calibration methods and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) for compositional analysis. PLCA was collected at 45-51 m depth and OSBA was collected at 67-144 m depth. Results of O x -NA concentrations follow an order as OSPW > OSBA > PLCA, indicating that occurrences of NAs in OSBA were likely related to natural bitumen deposits instead of OSPW. Liquid-liquid extraction (LLE) was applied to avoid the matrix effect for the ESTD method. Reduced LLE efficiency accounted for the divergence of the ISTD and ESTD calibrated results for oxidized NAs. Principle component analysis results of O 2 and O 4 species could be employed for differentiation of water types, while classical NAs with C13-15 and Z (-4)-(-6) and aromatic O 2 -NAs with C16-18 and Z (-14)-(-16) could be measured as marker compounds to characterize water sources and potential temporal variations of samples, respectively. FTICR-MS results revealed that compositions of NA species varied greatly among OSPW, PLCA, and OSBA, because of NA transfer and transformation processes. This work contributed to the understanding of the concentration and composition of NAs in various types of water, and provided a useful combination of analytical and statistical tools for monitoring studies, in support of future safe discharge of treated OSPW. Copyright © 2017 Elsevier Ltd. All rights reserved.

Superhydrophobic silica wool—a facile route to separating oil and hydrophobic solvents from water

NASA Astrophysics Data System (ADS)

Crick, Colin R.; Bhachu, Davinder S.; Parkin, Ivan P.

2014-12-01

Silica microfiber wool was systematically functionalized in order to provide an extremely water repellent and oleophilic material. This was carried out using a two-step functionalization that was shown to be a highly effective method for generating an intense water repulsion and attraction for oil. A demonstration of the silica wools application is shown through the highly efficient separation of oils and hydrophobic solvents from water. Water is confined to the extremities of the material, while oil is absorbed into the voids within the wool. The effect of surface functionalization is monitored though observing the interaction of the material with both oils and water, in addition to scanning electron microscope images, x-ray photoelectron spectroscopy and energy dispersive x-ray analysis. The material can be readily utilized in many applications, including the cleaning of oil spills and filtering during industrial processes, as well as further water purification tasks—while not suffering the losses of efficiency observed in current leading polymeric materials.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brian Toelle

This project, 'Application of Time-Lapse Seismic Monitoring for the Control and Optimization of CO{sub 2} Enhanced Oil Recovery Operations', investigated the potential for monitoring CO{sub 2} floods in carbonate reservoirs through the use of standard p-wave seismic data. This primarily involved the use of 4D seismic (time lapse seismic) in an attempt to observe and map the movement of the injected CO{sub 2} through a carbonate reservoir. The differences between certain seismic attributes, such as amplitude, were used for this purpose. This technique has recently been shown to be effective in CO{sub 2} monitoring in Enhanced Oil Recovery (EOR) projects,more » such as Weyborne. This study was conducted in the Charlton 30/31 field in the northern Michigan Basin, which is a Silurian pinnacle reef that completed its primary production in 1997 and was scheduled for enhanced oil recovery using injected CO{sub 2}. Prior to injection an initial 'Base' 3D survey was obtained over the field and was then processed and interpreted. CO{sub 2} injection within the main portion of the reef was conducted intermittently during 13 months starting in August 2005. During this time, 29,000 tons of CO{sub 2} was injected into the Guelph formation, historically known as the Niagaran Brown formation. By September 2006, the reservoir pressure within the reef had risen to approximately 2000 lbs and oil and water production from the one producing well within the field had increased significantly. The determination of the reservoir's porosity distribution, a critical aspect of reservoir characterization and simulation, proved to be a significant portion of this project. In order to relate the differences observed between the seismic attributes seen on the multiple 3D seismic surveys and the actual location of the CO{sub 2}, a predictive reservoir simulation model was developed based on seismic attributes obtained from the base 3D seismic survey and available well data. This simulation predicted that the CO{sub 2} injected into the reef would remain in the northern portion of the field. Two new wells, the State Charlton 4-30 and the Larsen 3-31, were drilled into the field in 2006 and 2008 respectively and supported this assessment. A second (or 'Monitor') 3D seismic survey was acquired during September 2007 over most of the field and duplicated the first (Base) survey, as much as possible. However, as the simulation and new well data available at that time indicated that the CO{sub 2} was concentrated in the northern portion of the field, the second seismic survey was not acquired over the extreme southern end of the area covered by the original (or Base) 3D survey. Basic processing was performed on the second 3D seismic survey and, finally, 4D processing methods were applied to both the Base and the Monitor surveys. In addition to this 3D data, a shear wave seismic data set was obtained at the same time. Interpretation of the 4D seismic data indicated that a significant amplitude change, not attributable to differences in acquisition or processing, existed at the locations within the reef predicted by the reservoir simulation. The reservoir simulation was based on the porosity distribution obtained from seismic attributes from the Base 3D survey. Using this validated reservoir simulation the location of oil within the reef at the time the Monitor survey was obtained and recommendations made for the drilling of additional EOR wells. The economic impact of this project has been estimated in terms of both enhanced oil recovery and CO{sub 2} sequestration potential. In the northern Michigan Basin alone, the Niagaran reef play is comprised of over 700 Niagaran reefs with reservoirs already depleted by primary production. Potentially there is over 1 billion bbls of oil (original oil in place minus primary recovery) remains in the reefs in Michigan, much of which could be more efficiently mobilized utilizing techniques similar to those employed in this study.« less

Oil-in-water monitoring using membrane inlet mass spectrometry.

PubMed

Brkić, Boris; France, Neil; Taylor, Stephen

2011-08-15

A membrane inlet mass spectrometry (MIMS) system has been used for detection and analysis of two types of North Sea crude oil. The system was installed on-field on the Flotta Oil Terminal (Orkney, UK). It consisted of a quadrupole mass spectrometer (QMS) connected to the capillary probe with a silicone-based membrane. The produced mass spectra and calibration plots from the MIMS instrument showed the capability to measure levels of individual hydrocarbons within crude oil in seawater. The generated mass spectra from the field tests also showed the ability to distinguish between different types of oil and to determine concentrations of toxic hydrocarbons in oil (e.g., benzene, toluene, and xylene (BTX)). The performance of the instrument at different temperatures of seawater and oil droplet sizes was also investigated. The results showed that the QMS-based MIMS system has a potential to complement existing oil-in-water (OiW) monitors by being able to detect different oil types and specific hydrocarbon concentrations with high accuracy, which are currently not supported in commercially available OiW monitors.

Online monitoring of P(3HB) produced from used cooking oil with near-infrared spectroscopy.

PubMed

Cruz, Madalena V; Sarraguça, Mafalda Cruz; Freitas, Filomena; Lopes, João Almeida; Reis, Maria A M

2015-01-20

Online monitoring process for the production of polyhydroxyalkanoates (PHA), using cooking oil (UCO) as the sole carbon source and Cupriavidus necator, was developed. A batch reactor was operated and hydroxybutyrate homopolymer was obtained. The biomass reached a maximum concentration of 11.6±1.7gL(-1) with a polymer content of 63±10.7% (w/w). The yield of product on substrate was 0.77±0.04gg(-1). Near-infrared (NIR) spectroscopy was used for online monitoring of the fermentation, using a transflectance probe. Partial least squares regression was applied to relate NIR spectra with biomass, UCO and PHA concentrations in the broth. The NIR predictions were compared with values obtained by offline reference methods. Prediction errors to these parameters were 1.18, 2.37 and 1.58gL(-1) for biomass, UCO and PHA, respectively, which indicate the suitability of the NIR spectroscopy method for online monitoring and as a method to assist bioreactor control. Copyright © 2014 Elsevier B.V. All rights reserved.

Regional Analysis of the Effects of Oil and Gas Development on Groundwater Resources in California

NASA Astrophysics Data System (ADS)

Landon, M. K.; McMahon, P. B.; Kulongoski, J. T.; Ball, L. B.; Gillespie, J. M.; Shimabukuro, D.; Taylor, K. A.

2016-12-01

The California State Water Resources Control Board is collaborating with the U.S. Geological Survey to implement a Regional Monitoring Program (RMP) to assess potential interactions between oil/gas stimulation treatment and groundwater resources. The effects of stimulation on groundwater resources will be difficult to distinguish from the effects of other past or present components of oil and gas development. As a result, the RMP is designed to provide an overall assessment of the effects of oil and gas development on groundwater quality. During 2016-17, the study is focused on selected priority oilfields in the eastern and western portions of the San Joaquin Valley in Kern County to: (1) produce three-dimensional (3D) salinity maps, (2) characterize the chemical composition of groundwater and produced water, and (3) identify the extent to which fluids from oil and gas development may be moving into protected (total dissolved solids less than 10,000 milligrams per liter) groundwater at regional scales. Analysis of available salinity data near oil/gas fields indicates there are regional patterns to salinity depth profiles; however, data gaps between the depths of water and oil/gas wells are common. These results provide a foundation for more detailed oilfield-scale salinity mapping, which includes geophysical methods (borehole, surface, and airborne) to fill data gaps. The RMP sampling-well networks are designed to evaluate groundwater quality along transects from oil/gas fields into adjacent aquifers and consist of existing wells supplemented by monitoring-well installation in priority locations identified by using 3D visualization of hydrogeologic data. The analytes include constituents with different transport characteristics such as dissolved gases, inorganic components (brines), and petroleum compounds. Analytes were selected because of their potential usefulness for understanding processes and pathways by which fluids from oilfield sources reach groundwater.

Applications of remote-sensing technology to environmental problems of Delaware and Delaware Bay

NASA Technical Reports Server (NTRS)

Bartlett, D.; Klemas, V.; Philpot, W.; Rogers, R.

1975-01-01

Digital processing of multispectral LANDSAT data was used to develop a computerized model for predicting oil slick movement within the Delaware Bay. LANDSAT imagery was also used to monitor offshore waste disposal sites for mapping of wetlands, and charting of tidal currents.

A literature review of portable fluorescence-based oil-in-water monitors.

PubMed

Lambert, P

2003-08-15

The results of a literature search on fluorescence-based portable detectors to measure the real-time concentration of oil are reported. For more than two decades, fluorometers have been commonly employed to monitor dispersed oil levels at oil spills on water. The focus of this paper has been to extract specific information from references about how the instruments were used, including set up and calibration procedures, the oil and dispersant measured, the approximate concentration range of the oil in the water column, and how the real-time data compared to traditional laboratory techniques.

Characteristics Study of In-Situ Capacitive Sensor for Monitoring Lubrication Oil Debris.

PubMed

Han, Zhibin; Wang, Yishou; Qing, Xinlin

2017-12-08

As an essential part of engine health monitoring (EHM), online lubrication oil debris monitoring has recently received great attention for the assessment of rotating and reciprocating parts in aero-engines, due to its high integration, low cost and safe characteristics. However, it is be a challenge to find a suitable sensor operating in such a complex environment. We present an unconventional novel approach, in which a cylinder capacitive sensor is designed and integrated with the pipeline of an engine lubrication system, so that the capacitive sensor can effectively detect changes in the lubrication oil condition. In this paper, an attempt to illustrate the performance characteristics of the developed cylinder capacitive sensor is made, through an experiment system that simulates a real scenario of a lubrication oil system. The main aim of the research was to qualitatively describe the relationship between the sensor parameter and the lubrication oil debris. In addition, the effect of the temperature and flow rate of the lubrication oil on capacitance change was performed by several experiments and we figured out a compensation method. The experimental results demonstrated that the cylinder capacitive sensor can potentially be used for lubrication oil debris monitoring of the health condition of an aero-engine.

Oil Sands Characteristics and Time-Lapse and P-SV Seismic Steam Monitoring, Athabasca, Canada

NASA Astrophysics Data System (ADS)

Takahashi, A.; Nakayama, T.; Kashihara, K.; Skinner, L.; Kato, A.

2008-12-01

A vast amount of oil sands exists in the Athabasca area, Alberta, Canada. These oil sands consist of bitumen (extra-heavy oil) and unconsolidated sand distributed from surface to a depth of 750 meters. Including conventional crude oil, the total number of proved remaining oil reserves in Canada ranks second place in the world after Saudi Arabia. For the production of bitumen from the reservoir 200 to 500 meters in depth, the Steam Assisted Gravity Drainage (SAGD) method (Steam Injection EOR) has been adopted as bitumen is not movable at original temperatures. It is essential to understand the detailed reservoir distribution and steam chamber development extent for optimizing the field development. Oil sands reservoir characterization is conducted using 3D seismic data acquired in February 2002. Conducting acoustic impedance inversion to improve resolution and subsequent multi-attribute analysis integrating seismic data with well data facilitates an understanding of the detailed reservoir distribution. These analyses enable the basement shale to be imaged, and enables identification to a certain degree of thin shale within the reservoir. Top and bottom depths of the reservoir are estimated in the range of 2.0 meters near the existing wells even in such a complex channel sands environment characterized by abrupt lateral sedimentary facies changes. In March 2006, monitoring 3D seismic data was acquired to delineate steam-affected areas. The 2002 baseline data is used as a reference data and the 2006 monitoring data is calibrated to the 2002 seismic data. Apparent differences in the two 3D seismic data sets with the exception of production related response changes are removed during the calibration process. P-wave and S-wave velocities of oil sands core samples are also measured with various pressures and temperatures, and the laboratory measurement results are then combined to construct a rock physics model used to predict velocity changes induced by steam-injection. The differences of the seismic responses between the time-lapse seismic volumes can be quantitatively explained by P-wave velocity decrease of the oil sands layers due to steam-injection. In addition, the data suggests that a larger area would be influenced by pressure than temperature. We calculate several seismic attributes such as RMS values of amplitude difference, maximum cross correlations, and interval velocity differences. These attributes are integrated by using self-organization maps (SOM) and K-means methods. By this analysis, we are able to distinguish areas of steam chamber growth from transitional and non-affected areas. In addition, 3D P-SV converted-wave processing and analysis are applied on the second 3D data set (recorded with three-component digital sensor). Low Vp/Vs values in the P-SV volume show areas of steam chamber development, and high Vp/Vs values indicate transitional zones. Our analysis of both time-lapse 3D seismic and 3D P-SV data along with the rock physics model can be used to monitor qualitatively and quantitatively the rock property changes of the inter-well reservoir sands in the field.

Literature Review of the State of the Art for Graphical User Interfaces (GUI) for a Series of Oil Quality Monitoring Sensors for Shipboard Equipment

DTIC Science & Technology

2011-03-01

sensors, the hardware may impose amplification and filtering on the input signal prior to the A/D conversion process. The third component in the...Assessment by FTIR – A Case Study on HEMM in Indian Mines”, Industrial Lubrication and Tribology , Vol. 152, pp. 61-66, 2000. [7] KarisAllen, K.J...and Engine Oil Condition”, Industrial Lubrication and Tribology , April 2005. [16] Jakoby, B., Eisenschmid, H., Schatz, O., “On-Board Evaluation of

Detection of genetically modified soybean in crude soybean oil.

PubMed

Nikolić, Zorica; Vasiljević, Ivana; Zdjelar, Gordana; Ðorđević, Vuk; Ignjatov, Maja; Jovičić, Dušica; Milošević, Dragana

2014-02-15

In order to detect presence and quantity of Roundup Ready (RR) soybean in crude oil extracted from soybean seed with a different percentage of GMO seed two extraction methods were used, CTAB and DNeasy Plant Mini Kit. The amplifications of lectin gene, used to check the presence of soybean DNA, were not achieved in all CTAB extracts of DNA, while commercial kit gave satisfactory results. Comparing actual and estimated GMO content between two extraction methods, root mean square deviation for kit is 0.208 and for CTAB is 2.127, clearly demonstrated superiority of kit over CTAB extraction. The results of quantification evidently showed that if the oil samples originate from soybean seed with varying percentage of RR, it is possible to monitor the GMO content at the first stage of processing crude oil. Copyright © 2013 Elsevier Ltd. All rights reserved.

Occidental vertical modified in situ process for the recovery of oil from oil shale. Phase II. Quarterly progress report, September 1, 1980-November 30, 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-01-01

The major activities at OOSI's Logan Wash site during the quarter were: mining the voids at all levels for Retorts 7 and 8; blasthole drilling; tracer testing MR4; conducting the start-up and burner tests on MR3; continuing the surface facility construction; and conducting Retorts 7 and 8 related Rock Fragmentation tests. Environmental monitoring continued during the quarter, and the data and analyses are discussed. Sandia National Laboratory and Laramie Energy Technology Center (LETC) personnel were active in the DOE support of the MR3 burner and start-up tests. In the last section of this report the final oil inventory for Retortmore » 6 production is detailed. The total oil produced by Retort 6 was 55,696 barrels.« less

Remote down-hole well telemetry

DOEpatents

Briles, Scott D [Los Alamos, NM; Neagley, Daniel L [Albuquerque, NM; Coates, Don M [Santa Fe, NM; Freund, Samuel M [Los Alamos, NM

2004-07-20

The present invention includes an apparatus and method for telemetry communication with oil-well monitoring and recording instruments located in the vicinity of the bottom of gas or oil recovery pipes. Such instruments are currently monitored using electrical cabling that is inserted into the pipes; cabling has a short life in this environment, and requires periodic replacement with the concomitant, costly shutdown of the well. Modulated reflectance, a wireless communication method that does not require signal transmission power from the telemetry package will provide a long-lived and reliable way to monitor down-hole conditions. Normal wireless technology is not practical since batteries and capacitors have to frequently be replaced or recharged, again with the well being removed from service. RF energy generated above ground can also be received, converted and stored down-hole without the use of wires, for actuating down-hole valves, as one example. Although modulated reflectance reduces or eliminates the loss of energy at the sensor package because energy is not consumed, during the transmission process, additional stored extra energy down-hole is needed.

Monitoring of volatile organic compounds (VOCs) from an oil and gas station in northwest China for 1 year

NASA Astrophysics Data System (ADS)

Zheng, Huang; Kong, Shaofei; Xing, Xinli; Mao, Yao; Hu, Tianpeng; Ding, Yang; Li, Gang; Liu, Dantong; Li, Shuanglin; Qi, Shihua

2018-04-01

Oil and natural gas are important for energy supply around the world. The exploring, drilling, transportation and processing in oil and gas regions can release a lot of volatile organic compounds (VOCs). To understand the VOC levels, compositions and sources in such regions, an oil and gas station in northwest China was chosen as the research site and 57 VOCs designated as the photochemical precursors were continuously measured for an entire year (September 2014-August 2015) using an online monitoring system. The average concentration of total VOCs was 297 ± 372 ppbv and the main contributor was alkanes, accounting for 87.5 % of the total VOCs. According to the propylene-equivalent concentration and maximum incremental reactivity methods, alkanes were identified as the most important VOC groups for the ozone formation potential. Positive matrix factorization (PMF) analysis showed that the annual average contributions from natural gas, fuel evaporation, combustion sources, oil refining processes and asphalt (anthropogenic and natural sources) to the total VOCs were 62.6 ± 3.04, 21.5 ± .99, 10.9 ± 1.57, 3.8 ± 0.50 and 1.3 ± 0.69 %, respectively. The five identified VOC sources exhibited various diurnal patterns due to their different emission patterns and the impact of meteorological parameters. Potential source contribution function (PSCF) and concentration-weighted trajectory (CWT) models based on backward trajectory analysis indicated that the five identified sources had similar geographic origins. Raster analysis based on CWT analysis indicated that the local emissions contributed 48.4-74.6 % to the total VOCs. Based on the high-resolution observation data, this study clearly described and analyzed the temporal variation in VOC emission characteristics at a typical oil and gas field, which exhibited different VOC levels, compositions and origins compared with those in urban and industrial areas.

Design and validation of wireless system for oil monitoring base on optical sensing unit

NASA Astrophysics Data System (ADS)

Niu, Liqun; Wang, Weiming; Zhang, Shuaishuai; Li, Zhirui; Yu, Yan; Huang, Hui

2017-04-01

According to the situation of oil leakage and the development of oil detection technology, a wireless monitoring system, combining with the sensor technology, optical measurement technology, and wireless technology, is designed. In this paper, the architecture of a wireless system is designed. In the hardware, the collected data, acquired by photoelectric conversion and analog to digital conversion equipment, will be sent to the upper machine where they are saved and analyzed. The experimental results reveals that the wireless system has the characteristics of higher precision, more real-time and more convenient installation, it can reflect the condition of the measuring object truly and implement the dynamic monitoring for a long time on-site, stability—thus it has a good application prospect in the oil monitoring filed.

Use of FBG sensors for health monitoring of pipelines

NASA Astrophysics Data System (ADS)

Felli, Ferdinando; Paolozzi, Antonio; Vendittozzi, Cristian; Paris, Claudio; Asanuma, Hiroshi

2016-04-01

The infrastructures for oil and gas production and distribution need reliable monitoring systems. The risks for pipelines, in particular, are not only limited to natural disasters (landslides, earthquakes, extreme environmental conditions) and accidents, but involve also the damages related to criminal activities, such as oil theft. The existing monitoring systems are not adequate for detecting damages from oil theft, and in several occasion the illegal activities resulted in leakage of oil and catastrophic environmental pollution. Systems based on fiber optic FBG (Fiber Bragg Grating) sensors present a number of advantages for pipeline monitoring. FBG sensors can withstand harsh environment, are immune to interferences, and can be used to develop a smart system for monitoring at the same time several physical characteristics, such as strain, temperature, acceleration, pressure, and vibrations. The monitoring station can be positioned tens of kilometers away from the measuring points, lowering the costs and the complexity of the system. This paper describes tests on a sensor, based on FBG technology, developed specifically for detecting damages of pipeline due to illegal activities (drilling of the pipes), that can be integrated into a smart monitoring chain.

Radar monitoring of oil pollution

NASA Technical Reports Server (NTRS)

Guinard, N. W.

1970-01-01

Radar is currently used for detecting and monitoring oil slicks on the sea surface. The four-frequency radar system is used to acquire synthetic aperature imagery of the sea surface on which the oil slicks appear as a nonreflecting area on the surface surrounded by the usual sea return. The value of this technique was demonstrated, when the four-frequency radar system was used to image the oil spill of tanker which has wrecked. Imagery was acquired on both linear polarization (horizontal, vertical) for frequencies of 428, 1228, and 8910 megahertz. Vertical returns strongly indicated the presence of oil while horizontal returns failed to detect the slicks. Such a result is characteristic of the return from the sea and cannot presently be interpreted as characteristics of oil spills. Because an airborne imaging radar is capable of providing a wide-swath coverage under almost all weather conditions, it offers promise in the development of a pollution-monitoring system that can provide a coastal watch for oil slicks.

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2013 CFR

2013-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2011 CFR

2011-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2014 CFR

2014-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2012 CFR

2012-07-01

... monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Monitoring devices. 154.525...) POLLUTION FACILITIES TRANSFERRING OIL OR HAZARDOUS MATERIAL IN BULK Equipment Requirements § 154.525...

Geochemistry of radioactive elements in bituminous sands and sandstones of Permian bitumen deposits of Tatarstan (east of the Russian plate)

NASA Astrophysics Data System (ADS)

Mullakaev, A. I.; Khasanov, R. R.; Badrutdinov, O. R.; Kamaletdinov, I. R.

2018-05-01

The article investigates geochemical features of Permian (Cisuralian, Ufimian Stage and Biarmian, Kazanian Stage of the General Stratigraphic Scale of Russia) bituminous sands and sandstones located on the territory of the Volga-Ural oil and gas province (Republic of Tatarstan). Natural bitumens are extracted using thermal methods as deposits of high-viscosity oils. In the samples studied, the specific activity of natural radionuclides from the 238U (226Ra), 232Th, and 40K series was measured using gamma spectrometry. As a result of the precipitation of uranium and thorium and their subsequent decay, the accumulation of radium (226Ra and 228Ra) has been shown to occur in the bituminous substance. In the process of exploitation of bitumen-bearing rock deposits (as an oil fields) radium in the composition of a water-oil mixture can be extracted to the surface or deposited on sulfate barriers, while being concentrated on the walls of pipes and other equipment. This process requires increased attention to monitoring and inspection the environmental safety of the exploitation procedure.

NORM management in the oil and gas industry.

PubMed

Cowie, M; Mously, K; Fageeha, O; Nassar, R

2012-01-01

It has been established that naturally occurring radioactive material (NORM) may accumulate at various locations along the oil and gas production process. Components such as wellheads, separation vessels, pumps, and other processing equipment can become contaminated with NORM, and NORM can accumulate in the form of sludge, scale, scrapings, and other waste media. This can create a potential radiation hazard to workers, the general public, and the environment if certain controls are not established. Saudi Aramco has developed NORM management guidelines, and is implementing a comprehensive strategy to address all aspects of NORM management that aim to enhance NORM monitoring; control of NORM-contaminated equipment; control of NORM waste handling and disposal; and protection, awareness, and training of workers. The benefits of shared knowledge, best practice, and experience across the oil and gas industry are seen as key to the establishment of common guidance. This paper outlines Saudi Aramco's experience in the development of a NORM management strategy, and its goals of establishing common guidance throughout the oil and gas industry. Copyright © 2012. Published by Elsevier Ltd.

In Situ Monitoring of Dispersion in the Water Column, Final Product for the Detection and Mitigation of Oil within the Water Column Project

DTIC Science & Technology

2018-01-31

properties in the presence of oil, such as conductivity, temperature , and turbidity (Battelle, 2014). The National Response Team (NRT) divides subsea...monitoring of oil and conditions (conductivity, temperature , salinity) in the water column, and discrete sampling and analysis (Battelle, 2014). Sensors

Fingerprint and weathering characteristics of stranded oils after the Hebei Spirit oil spill.

PubMed

Yim, Un Hyuk; Ha, Sung Yong; An, Joon Geon; Won, Jong Ho; Han, Gi Myung; Hong, Sang Hee; Kim, Moonkoo; Jung, Jee-Hyun; Shim, Won Joon

2011-12-15

After the Hebei Spirit oil spill in December 2007, mixtures of three types of Middle East crude oil were stranded along 375 km of coastline in Western Korea. Stranded oils were monitored for their identity and weathering status in 19 stations in three provinces. The results obtained using a weathering model indicated that evaporation would be a dominant weathering process immediately after the spill and the sequential changes of chemical composition in the field verified this prediction positively. In the early stages of weathering, the half-life of spilled oil was calculated to be 2.6 months. Tiered fingerprinting approaches identified background contamination and confirmed the identity of the stranded oils with the spill source. Double ratios using alkylated phenanthrenes and dibenzothiophenes in samples after the spill clearly reveal the impact of weathering on oil. However, to derive defensible fingerprinting for source identification and allocation, recalcitrant biomarkers are extremely useful. Weathering status of the stranded oils was evaluated using composition profiles of saturated hydrocarbons, polycyclic aromatic hydrocarbons and various weathering indices. Most samples collected 8 months after the spill were categorized in either the advanced or extreme weathering states. Gradual increase in toxic components in the residual oil through weathering emphasizes the need for adaptive ecotoxicological approaches. Copyright © 2011 Elsevier B.V. All rights reserved.

Monitoring of oil pollution in the Arabian Gulf based on medium resolution satellite imagery

NASA Astrophysics Data System (ADS)

Zhao, J.; Ghedira, H.

2013-12-01

A large number of inland and offshore oil fields are located in the Arabian Gulf where about 25% of the world's oil is produced by the countries surrounding the Arabian Gulf region. Almost all of this oil production is shipped by sea worldwide through the Strait of Hormuz making the region vulnerable to environmental and ecological threats that might arise from accidental or intentional oil spills. Remote sensing technologies have the unique capability to detect and monitor oil pollutions over large temporal and spatial scales. Synoptic satellite imaging can date back to 1972 when Landsat-1 was launched. Landsat satellite missions provide long time series of imagery with a spatial resolution of 30 m. MODIS sensors onboard NASA's Terra and Aqua satellites provide a wide and frequent coverage at medium spatial resolution, i.e. 250 m and 500, twice a day. In this study, the capability of medium resolution MODIS and Landsat data in detecting and monitoring oil pollutions in the Arabian Gulf was tested. Oil spills and slicks show negative or positive contrasts in satellite derived RGB images compared with surrounding clean waters depending on the solar/viewing geometry, oil thickness and evolution, etc. Oil-contaminated areas show different spectral characteristics compared with surrounding waters. Rayleigh-corrected reflectance at the seven medium resolution bands of MODIS is lower in oil affected areas. This is caused by high light absorption of oil slicks. 30-m Landsat image indicated the occurrence of oil spill on May 26 2000 in the Arabian Gulf. The oil spill showed positive contrast and lower temperature than surrounding areas. Floating algae index (FAI) images are also used to detect oil pollution. Oil-contaminated areas were found to have lower FAI values. To track the movement of oil slicks found on October 21 2007, ocean circulations from a HYCOM model were examined and demonstrated that the oil slicks were advected toward the coastal areas of United Arab Emirates (UAE). This can help to enable an early alarm for oil pollution and minimize the potential adverse effects. Remote sensing provides an effective tool for monitoring oil pollution. Medium resolution MODIS and Landsat data have shown to be effective in detecting oil pollution over small areas. Combined with remote sensing imagery, ocean circulation models demonstrate their unique value for developing a warning and forecasting system for oil pollution management.

Characteristics Study of In-Situ Capacitive Sensor for Monitoring Lubrication Oil Debris

PubMed Central

Han, Zhibin; Wang, Yishou; Qing, Xinlin

2017-01-01

As an essential part of engine health monitoring (EHM), online lubrication oil debris monitoring has recently received great attention for the assessment of rotating and reciprocating parts in aero-engines, due to its high integration, low cost and safe characteristics. However, it is be a challenge to find a suitable sensor operating in such a complex environment. We present an unconventional novel approach, in which a cylinder capacitive sensor is designed and integrated with the pipeline of an engine lubrication system, so that the capacitive sensor can effectively detect changes in the lubrication oil condition. In this paper, an attempt to illustrate the performance characteristics of the developed cylinder capacitive sensor is made, through an experiment system that simulates a real scenario of a lubrication oil system. The main aim of the research was to qualitatively describe the relationship between the sensor parameter and the lubrication oil debris. In addition, the effect of the temperature and flow rate of the lubrication oil on capacitance change was performed by several experiments and we figured out a compensation method. The experimental results demonstrated that the cylinder capacitive sensor can potentially be used for lubrication oil debris monitoring of the health condition of an aero-engine. PMID:29292748

Effects of high-pressure process on kinetics of leaching oil from soybean powder using hexane in batch systems.

PubMed

Uhm, Joo Tae; Yoon, Won Byong

2011-08-01

Mass transfer models of leaching oil from soybean (Glycine max) flour with hexane after high-pressure process (HPP) treatment were developed. High pressure (450 MPa) was applied to the soybean flour (mean diameter of flour particle: 365 μm) for 30 min before leaching the oil components in the solvent. The ratio of solvent (volume, mL) to soybean flour (mass, g), such as 1:10 and 1:20, was employed to characterize the effect of solvent ratio on the leaching rate in the batch type of extraction process. Ultraviolet absorbance at 300 nm was used to monitor the extraction rate. Saturation solubility (C(AS)) was determined to be 21.73 kg/m³. The mass transfer coefficients (k) were determined based on the 1st- and 2nd-order kinetic models. The 2nd kinetic model showed better fit. The HPP treatment showed a higher extraction rate and yield compared to the control, while the amount of solvent did not affect the extraction rate and yield. The scanning electron microscope showed that HPP-treated soybean particles included more pores than the untreated. The pores observed in the HPP-treated soybean flours might help increase the mass transfer rate of solvent and solute in the solid matrix. High-pressure processing can help increase the extraction rate of oil from the soybean flour operated in batch systems. The conventional solid to solvent ratio (1:20) used to extract oil composition from the plant seed did not help increase the amount of oil extracted from the soybean flour. © 2011 Institute of Food Technologists®

Photonic Low Cost Micro-Sensor for in-Line Wear Particle Detection in Flowing Lube Oils.

PubMed

Mabe, Jon; Zubia, Joseba; Gorritxategi, Eneko

2017-03-14

The presence of microscopic particles in suspension in industrial fluids is often an early warning of latent or imminent failures in the equipment or processes where they are being used. This manuscript describes work undertaken to integrate different photonic principles with a micro- mechanical fluidic structure and an embedded processor to develop a fully autonomous wear debris sensor for in-line monitoring of industrial fluids. Lens-less microscopy, stroboscopic illumination, a CMOS imager and embedded machine vision technologies have been merged to develop a sensor solution that is able to detect and quantify the number and size of micrometric particles suspended in a continuous flow of a fluid. A laboratory test-bench has been arranged for setting up the configuration of the optical components targeting a static oil sample and then a sensor prototype has been developed for migrating the measurement principles to real conditions in terms of operating pressure and flow rate of the oil. Imaging performance is quantified using micro calibrated samples, as well as by measuring real used lubricated oils. Sampling a large fluid volume with a decent 2D spatial resolution, this photonic micro sensor offers a powerful tool at very low cost and compacted size for in-line wear debris monitoring.

Photonic Low Cost Micro-Sensor for in-Line Wear Particle Detection in Flowing Lube Oils

PubMed Central

Mabe, Jon; Zubia, Joseba; Gorritxategi, Eneko

2017-01-01

The presence of microscopic particles in suspension in industrial fluids is often an early warning of latent or imminent failures in the equipment or processes where they are being used. This manuscript describes work undertaken to integrate different photonic principles with a micro- mechanical fluidic structure and an embedded processor to develop a fully autonomous wear debris sensor for in-line monitoring of industrial fluids. Lens-less microscopy, stroboscopic illumination, a CMOS imager and embedded machine vision technologies have been merged to develop a sensor solution that is able to detect and quantify the number and size of micrometric particles suspended in a continuous flow of a fluid. A laboratory test-bench has been arranged for setting up the configuration of the optical components targeting a static oil sample and then a sensor prototype has been developed for migrating the measurement principles to real conditions in terms of operating pressure and flow rate of the oil. Imaging performance is quantified using micro calibrated samples, as well as by measuring real used lubricated oils. Sampling a large fluid volume with a decent 2D spatial resolution, this photonic micro sensor offers a powerful tool at very low cost and compacted size for in-line wear debris monitoring. PMID:28335436

Detecting gas hydrate behavior in crude oil using NMR.

PubMed

Gao, Shuqiang; House, Waylon; Chapman, Walter G

2006-04-06

Because of the associated experimental difficulties, natural gas hydrate behavior in black oil is poorly understood despite its grave importance in deep-water flow assurance. Since the hydrate cannot be visually observed in black oil, traditional methods often rely on gas pressure changes to monitor hydrate formation and dissociation. Because gases have to diffuse through the liquid phase for hydrate behavior to create pressure responses, the complication of gas mass transfer is involved and hydrate behavior is only indirectly observed. This pressure monitoring technique encounters difficulties when the oil phase is too viscous, the amount of water is too small, or the gas phase is absent. In this work we employ proton nuclear magnetic resonance (NMR) spectroscopy to observe directly the liquid-to-solid conversion of the water component in black oil emulsions. The technique relies on two facts. The first, well-known, is that water becomes essentially invisible to liquid state NMR as it becomes immobile, as in hydrate or ice formation. The second, our recent finding, is that in high magnetic fields of sufficient homogeneity, it is possible to distinguish water from black oil spectrally by their chemical shifts. By following changes in the area of the water peak, the process of hydrate conversion can be measured, and, at lower temperatures, the formation of ice. Taking only seconds to accomplish, this measurement is nearly direct in contrast to conventional techniques that measure the pressure changes of the whole system and assume these changes represent formation or dissociation of hydrates - rather than simply changes in solubility. This new technique clearly can provide accurate hydrate thermodynamic data in black oils. Because the technique measures the total mobile water with rapidity, extensions should prove valuable in studying the dynamics of phase transitions in emulsions.

Challenges to oil spill assessment for seabirds in the deep ocean

USGS Publications Warehouse

Haney, J. Christopher; Jodice, Patrick G. R.; Montevecchi, William; Evers, David C.

2017-01-01

We synthesize impediments for evaluating effects to seabirds from open ocean hydrocarbon releases. Effects on seabirds from ship discharges, spills, and well blowouts often are poorly detected and monitored far from land. Regulatory regimes for ocean spills can result in monitoring efforts that are not entirely transparent. We illustrate how interdisciplinary technologies address deficits that hamper individual or population level assessments for seabirds, and we demonstrate where emerging technologies might be engaged to bridge gaps in oil spill monitoring. Although acute mortality from direct oil exposure poses the greatest risk to seabirds, other hazards from light-attraction, flaring, collisions, chronic pollution, and hydrocarbon inhalation around oil infrastructure also may induce bird mortality in the deep ocean.

On the SAR derived alert in the detection of oil spills according to the analysis of the EGEMP.

PubMed

Ferraro, Guido; Baschek, Björn; de Montpellier, Geraldine; Njoten, Ove; Perkovic, Marko; Vespe, Michele

2010-01-01

Satellite services that deliver information about possible oil spills at sea currently use different labels of "confidence" to describe the detections based on radar image processing. A common approach is to use a classification differentiating between low, medium and high levels of confidence. There is an ongoing discussion on the suitability of the existing classification systems of possible oil spills detected by radar satellite images with regard to the relevant significance and correspondence to user requirements. This paper contains a basic analysis of user requirements, current technical possibilities of satellite services as well as proposals for a redesign of the classification system as an evolution towards a more structured alert system. This research work offers a first review of implemented methodologies for the categorisation of detected oil spills, together with the proposal of explorative ideas evaluated by the European Group of Experts on satellite Monitoring of sea-based oil Pollution (EGEMP). Copyright 2009 Elsevier Ltd. All rights reserved.

30 CFR 250.457 - What equipment is required to monitor drilling fluids?

Code of Federal Regulations, 2010 CFR

2010-07-01

... OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations Drilling Fluid Requirements § 250.457 What equipment is required to monitor drilling fluids? Once you... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What equipment is required to monitor drilling...

30 CFR 250.457 - What equipment is required to monitor drilling fluids?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 2 2014-07-01 2014-07-01 false What equipment is required to monitor drilling..., DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations Drilling Fluid Requirements § 250.457 What equipment is required to monitor...

30 CFR 250.457 - What equipment is required to monitor drilling fluids?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 2 2012-07-01 2012-07-01 false What equipment is required to monitor drilling..., DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations Drilling Fluid Requirements § 250.457 What equipment is required to monitor...

30 CFR 250.457 - What equipment is required to monitor drilling fluids?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 2 2013-07-01 2013-07-01 false What equipment is required to monitor drilling..., DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations Drilling Fluid Requirements § 250.457 What equipment is required to monitor...

An airborne laser fluorosensor for the detection of oil on water

NASA Technical Reports Server (NTRS)

Kim, H. H.; Hickman, G. D.

1975-01-01

An airborne laser fluorosensor for the detection of oil derivatives on water has been tested. The system transmits 337 nm UV radiation at the rate of 100 pulses per second and monitors fluorescent emission at 540 nm. Daylight flight tests were made over the areas of controlled oil spills and additional reconnaissance flights were made over a 50 km stretch of the Delaware River to establish ambient oil baseline in the river. The results show that the device is capable of monitoring and mapping out extremely low level oil on water which cannot be identified by ordinary photographic method.

Oil Spill Detection and Monitoring of Abu Dhabi Coastal Zone Using KOMPSAT-5 SAR Imagery

NASA Astrophysics Data System (ADS)

Harahsheh, H. A.

2016-06-01

Abu Dhabi Government endorsed vision for its Maritime Strategy `A safe, secure and sustainable maritime domain for Abu Dhabi'. This research study share this vision using the concept of monitoring as tool for marine protection against any possible oil pollution. The best technology to detect and monitor oil pollution and in particularly oil spill is SAR imagery In this case study we chose KOMPSAT-5 SAR. KOMPSAT-5 carries X-band SAR for earth observation, and is capable of day-and-night imaging under all weather condition. It provides three operation modes: High Resolution Mode to provide 1 m resolution, Standard Mode to provide 3 m resolution and Wide Swath Mode to provide 20 m resolution with 100 km swath at 550 km altitude, with four modes of polarization. KOMPSAT-5 provides products for various applications; security and defense, mapping, and natural resource management, environmental monitoring, disaster monitoring and more. For our case study we chose to work with Wide Swath mode (WS) with Vertical polarization (VV) to cover a wide area of interest located to the north west of Abu Dhabi including some important islands like "Zirku Island", and areas with oil production activities. The results of data acquired on 4th May 2015 show some spot of oil spill with length estimated about 3 KM, and the daily satellite data acquisition over the period July 24 through July 31 shows serious and many oil spill events some are small, but many others are considered to be big with area size around 20 km2. In the context of oil spill pollution in the seas, we have to consider the development and increase of overseas transportation, which is an important factor for both social and economic sectors. The harmful effects of marine pollution are numerous, from the damage of marine life to the damage of the aquatic ecosystem as whole. As such, the need for oil slick detection is crucial, for the location of polluted areas and to evaluate slick drift to protect the coastline. Satellite-based oil spill monitoring system now can be used to take precautions and even to determine the possible polluter; it has a vital importance on the detection and protection of national and international waters from the possible damages of petroleum hazard. Finally, and as we suggested in previous studies, we recommend to the national authorities to establish a national near-real time oil spill monitoring system based on SAR satellite imagery, with the support of other tools like AIS and navigation radars

Microfluidic acoustophoretic force based low-concentration oil separation and detection from the environment.

PubMed

Wang, Han; Liu, Zhongzheng; Kim, Sungman; Koo, Chiwan; Cho, Younghak; Jang, Dong-Young; Kim, Yong-Joe; Han, Arum

2014-03-07

Detecting and quantifying extremely low concentrations of oil from the environment have broad applications in oil spill monitoring in ocean and coastal areas as well as in oil leakage monitoring on land. Currently available methods for low-concentration oil detection are bulky or costly with limited sensitivities. Thus they are difficult to be used as portable and field-deployable detectors in the case of oil spills or for monitoring the long-term effects of dispersed oil on marine and coastal ecosystems. Here, we present a low-concentration oil droplet trapping and detection microfluidic system based on the acoustophoresis phenomenon where oil droplets in water having a negative acoustic contrast factor move towards acoustic pressure anti-nodes. By trapping oil droplets from water samples flowing through a microfluidic channel, even very low concentrations of oil droplets can be concentrated to a detectable level for further analyses, which is a significant improvement over currently available oil detection systems. Oil droplets in water were successfully trapped and accumulated in a circular acoustophoretic trapping chamber of the microfluidic device and detected using a custom-built compact fluorescent detector based on the natural fluorescence of the trapped crude oil droplets. After the on-line detection, crude oil droplets released from the trapping chamber were successfully separated into a collection outlet by acoustophoretic force for further off-chip analyses. The developed microfluidic system provides a new way of trapping, detecting, and separating low-concentration crude oil from environmental water samples and holds promise as a low-cost field-deployable oil detector with extremely high sensitivity. The microfluidic system and operation principle are expected to be utilized in a wide range of applications where separating, concentrating, and detecting small particles having a negative acoustic contrast factor are required.

Identification of Critical Operation Conditions of Industrial Gearboxes by 24/7 Monitoring of Oil Quality, Oil Aging, and Additive Consumption

NASA Astrophysics Data System (ADS)

Mauntz, M.; Peuser, J.

2017-05-01

The demand for wind energy grows at exponential rates. At the same time improving reliability, reduced operation and maintenance costs are the key priorities in wind tur-bine maintenance strategies [1]. This paper provides information about a novel online oil condition monitoring system to give a solution to the mentioned priorities. The presented sensor system enables damage prevention of the wind turbine gear-box by an advanced warning time of critical operation conditions and an enhanced oil exchange interval realized by a precise measurement of the electrical conductivity, the relative permittivity and the oil temperature. A new parameter, the WearSens® Index (WSi) is introduced. The mathematical model of the WSi combines all measured values and its gradients in one single parameter for a comprehensive monitoring to prevent wind turbines from damage. Furthermore, the WSi enables a long-term prognosis on the next oil change by 24/7 server data logging. Corrective procedures and/or maintenance can be carried out before actual damage occurs. First WSi results of an onshore wind turbine installation compared to traditional vibration monitoring are shown.

Raman spectroscopy for the characterization of different fractions of hemp essential oil extracted at 130 °C using steam distillation method

NASA Astrophysics Data System (ADS)

Hanif, Muhammad Asif; Nawaz, Haq; Naz, Saima; Mukhtar, Rubina; Rashid, Nosheen; Bhatti, Ijaz Ahmad; Saleem, Muhammad

2017-07-01

In this study, Raman spectroscopy along with Principal Component Analysis (PCA) is used for the characterization of pure essential oil (pure EO) isolated from the leaves of the Hemp (Cannabis sativa L.,) as well as its different fractions obtained by fractional distillation process. Raman spectra of pure Hemp essential oil and its different fractions show characteristic key bands of main volatile terpenes and terpenoids, which significantly differentiate them from each other. These bands provide information about the chemical composition of sample under investigation and hence can be used as Raman spectral markers for the qualitative monitoring of the pure EO and different fractions containing different active compounds. PCA differentiates the Raman spectral data into different clusters and loadings of the PCA further confirm the biological origin of the different fractions of the essential oil.

NPDES permit compliance and enforcement: A resource guide for oil and gas operators

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-12-01

During the fall of 1996, the Interstate Oil and Gas Compact Commission sponsored sessions for government and industry representatives to discuss concerns about the National Pollution Discharge Elimination System (NPDES) program under the Clean Water Act. In January 1997, the NPDES Education/Communication/Training Workgroup (ECT Workgroup) was established with co-leaders from the Environmental Protection Agency (EPA) and industry. The ECT Workgroup`s purpose was to develop ideas that would improve communication between NPDES regulators and the oil and gas industry regarding NPDES compliance issues. The Workgroup focused on several areas, including permit compliance monitoring and reporting, enforcement activity and options, and treatmentmore » technology. The ECT Workgroup also discussed the need for materials and information to help NPDES regulatory agency personnel understand more about oil and gas industry exploration and extraction operations and treatment processes. This report represents a compendium of the ECT Workgroup`s efforts.« less

Changes in extra-virgin olive oil added with Lycium barbarum L. carotenoids during frying: Chemical analyses and metabolomic approach.

PubMed

Blasi, F; Rocchetti, G; Montesano, D; Lucini, L; Chiodelli, G; Ghisoni, S; Baccolo, G; Simonetti, M S; Cossignani, L

2018-03-01

In this work, an Italian extra-virgin olive oil (EVOO) sample and the same sample added with a carotenoid-rich nutraceutical extract from Lycium barbarum L. (EVOOCar) were subjected to a frying process to comparatively assess chemical and physical changes and heat stability. Oxidation progress was monitored by measuring oil quality changes such as peroxide value, free acidity, K232, K268, and fatty acid composition as well as minor compound content, phenols, α-tocopherol, and carotenoids. An UHPLC/QTOF-MS metabolomics approach discriminated the two oil samples based on their chemical changes during frying, identifying also the phenolic classes most exposed to statistically significant variations. Partial least square discriminant analysis and volcano analysis were applied together to identify the most significant markers allowing group separation. The decrease in total phenolic content was lower in EVOOCar than in EVOO during frying. Monounsaturated and polyunsaturated fatty acids showed a significant percentage loss, 3.7% and 17.2%, respectively, in EVOO after 180min frying at 180°C, while they remained constant or slightly changed in EVOOCar. Zeaxanthin added to the oil rapidly decreased during the frying process. These findings showed that the addition of a carotenoid extract from L. barbarum can help to improve the oxidative stability of extra-virgin olive oil. Copyright © 2017 Elsevier Ltd. All rights reserved.

Complete Moment Tensor Determination of Induced Seismicity in Unconventional and Conventional Oil/Gas Fields

NASA Astrophysics Data System (ADS)

Gu, C.; Li, J.; Toksoz, M. N.

2013-12-01

Induced seismicity occurs both in conventional oil/gas fields due to production and water injection and in unconventional oil/gas fields due to hydraulic fracturing. Source mechanisms of these induced earthquakes are of great importance for understanding their causes and the physics of the seismic processes in reservoirs. Previous research on the analysis of induced seismic events in conventional oil/gas fields assumed a double couple (DC) source mechanism. However, recent studies have shown a non-negligible percentage of a non-double-couple (non-DC) component of source moment tensor in hydraulic fracturing events (Šílený et al., 2009; Warpinski and Du, 2010; Song and Toksöz, 2011). In this study, we determine the full moment tensor of the induced seismicity data in a conventional oil/gas field and for hydrofrac events in an unconventional oil/gas field. Song and Toksöz (2011) developed a full waveform based complete moment tensor inversion method to investigate a non-DC source mechanism. We apply this approach to the induced seismicity data from a conventional gas field in Oman. In addition, this approach is also applied to hydrofrac microseismicity data monitored by downhole geophones in four wells in US. We compare the source mechanisms of induced seismicity in the two different types of gas fields and explain the differences in terms of physical processes.

An Optical Interferometric Triaxial Displacement Sensor for Structural Health Monitoring: Characterization of Sliding and Debonding for a Delamination Process

PubMed Central

Chen, Yizheng; Zhuang, Yiyang; Du, Yang; Gerald, Rex E.; Tang, Yan

2017-01-01

This paper presents an extrinsic Fabry–Perot interferometer-based optical fiber sensor (EFPI) for measuring three-dimensional (3D) displacements, including interfacial sliding and debonding during delamination. The idea employs three spatially arranged EFPIs as the sensing elements. In our sensor, the three EFPIs are formed by three endfaces of three optical fibers and their corresponding inclined mirrors. Two coincident roof-like metallic structures are used to support the three fibers and the three mirrors, respectively. Our sensor was calibrated and then used to monitor interfacial sliding and debonding between a long square brick of mortar and its support structure (i.e., a steel base plate) during the drying/curing process. This robust and easy-to-manufacture triaxial EFPI-based 3D displacement sensor has great potential in structural health monitoring, the construction industry, oil well monitoring, and geotechnology. PMID:29165351

An Optical Interferometric Triaxial Displacement Sensor for Structural Health Monitoring: Characterization of Sliding and Debonding for a Delamination Process.

PubMed

Zhu, Chen; Chen, Yizheng; Zhuang, Yiyang; Du, Yang; Gerald, Rex E; Tang, Yan; Huang, Jie

2017-11-22

This paper presents an extrinsic Fabry-Perot interferometer-based optical fiber sensor (EFPI) for measuring three-dimensional (3D) displacements, including interfacial sliding and debonding during delamination. The idea employs three spatially arranged EFPIs as the sensing elements. In our sensor, the three EFPIs are formed by three endfaces of three optical fibers and their corresponding inclined mirrors. Two coincident roof-like metallic structures are used to support the three fibers and the three mirrors, respectively. Our sensor was calibrated and then used to monitor interfacial sliding and debonding between a long square brick of mortar and its support structure (i.e., a steel base plate) during the drying/curing process. This robust and easy-to-manufacture triaxial EFPI-based 3D displacement sensor has great potential in structural health monitoring, the construction industry, oil well monitoring, and geotechnology.

Monitoring reactive microencapsulation dynamics using microfluidics

PubMed Central

Brosseau, Quentin; Baret, Jean-Christophe

2015-01-01

We use microfluidic polydimethylsiloxane (PDMS) devices to measure the kinetics of reactive encapsulations occurring at the interface of emulsion droplets. The formation of the polymeric shell is inferred from the droplet deformability measured in a series of expansion–constriction chambers along the microfluidic chip. With this tool we quantify the kinetic processes governing the encapsulation at the very early stage of shell formation with a time resolution of the order of the millisecond for overall reactions occurring in less than 0.5 s. We perform a comparison of monomer reactivities used for the encapsulation. We study the formation of polyurea microcapsules (PUMCs); the shell formation proceeds at the water–oil interface by an immediate reaction of amines dissolved in the aqueous phase and isocyanates dissolved in the oil phase. We observe that both monomers contribute differently to the encapsulation kinetics. The kinetics of the shell formation process at the oil-in-water (O/W) experiments significantly differs from the water-in-oil (W/O) systems; the component dissolved in the continuous phase has the largest impact on the kinetics. In addition, we quantified the retarding effect on the encapsulation kinetics by the interface stabilizing agent (surfactant). Our approach is valuable for quantifying in situ reactive encapsulation processes and provides guidelines to generate microcapsules with soft interfaces of tailored and controllable interfacial properties. PMID:25705975

Electrobioremediation of oil spills.

PubMed

Daghio, Matteo; Aulenta, Federico; Vaiopoulou, Eleni; Franzetti, Andrea; Arends, Jan B A; Sherry, Angela; Suárez-Suárez, Ana; Head, Ian M; Bestetti, Giuseppina; Rabaey, Korneel

2017-05-01

Annually, thousands of oil spills occur across the globe. As a result, petroleum substances and petrochemical compounds are widespread contaminants causing concern due to their toxicity and recalcitrance. Many remediation strategies have been developed using both physicochemical and biological approaches. Biological strategies are most benign, aiming to enhance microbial metabolic activities by supplying limiting inorganic nutrients, electron acceptors or donors, thus stimulating oxidation or reduction of contaminants. A key issue is controlling the supply of electron donors/acceptors. Bioelectrochemical systems (BES) have emerged, in which an electrical current serves as either electron donor or acceptor for oil spill bioremediation. BES are highly controllable and can possibly also serve as biosensors for real time monitoring of the degradation process. Despite being promising, multiple aspects need to be considered to make BES suitable for field applications including system design, electrode materials, operational parameters, mode of action and radius of influence. The microbiological processes, involved in bioelectrochemical contaminant degradation, are currently not fully understood, particularly in relation to electron transfer mechanisms. Especially in sulfate rich environments, the sulfur cycle appears pivotal during hydrocarbon oxidation. This review provides a comprehensive analysis of the research on bioelectrochemical remediation of oil spills and of the key parameters involved in the process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Integrating technologies for oil spill response in the SW Iberian coast

NASA Astrophysics Data System (ADS)

Janeiro, J.; Neves, A.; Martins, F.; Relvas, P.

2017-09-01

An operational oil spill modelling system developed for the SW Iberia Coast is used to investigate the relative importance of the different components and technologies integrating an oil spill monitoring and response structure. A backtrack of a CleanSeaNet oil detection in the region is used to demonstrate the concept. Taking advantage of regional operational products available, the system provides the necessary resolution to go from regional to coastal scales using a downscalling approach, while a multi-grid methodology allows the based oil spill model to span across model domains taking full advantage of the increasing resolution between the model grids. An extensive validation procedure using a multiplicity of sensors, with good spatial and temporal coverage, strengthens the operational system ability to accurately solve coastal scale processes. The model is validated using available trajectories from satellite-tracked drifters. Finally, a methodology is proposed to identifying potential origins for the CleanSeaNet oil detection, by combining model backtrack results with ship trajectories supplied by AIS was developed, including the error estimations found in the backtrack validation.

The impact of oil burning on kraft recovery furnace SO sub 2 emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Someshwar, A.V.; Pinkerton, J.E.; Caron, A.L.

1991-04-01

Auxiliary fossil fuel, either natural gas or fuel oil, is burned in kraft recovery furnaces during furnace startups and shutdowns, furnace upsets, and periods of substantially reduced rates of black liquor firing. The efficiency of sulfur capture and retention during normal operation of a kraft recovery furnace is inherently high. Consequently, not all the SO{sub 2} from occasional burning of sulfur-containing fuel oil in the furnace would be expected to end up in the stack gases. However, the extent to which such SO{sub 2} is captured by the alkali fume generation processes has not been well documented. In this paper,more » the authors examines the impact that burning oil in kraft recovery furnaces has on the SO{sub 2} emissions. The work included analyses of long-term SO{sub 2} data from a continuous emission monitoring system (CEMS) obtained for four furnaces that burned medium sulfur fuel oil as auxiliary fuel. It also included tests conducted on four furnaces in which varying amounts of oil were co-fired with black liquor.« less

Destabilization of mayonnaise induced by lipid crystallization upon freezing.

PubMed

Miyagawa, Yayoi; Ogawa, Takenobu; Nakagawa, Kyuya; Adachi, Shuji

2016-01-01

The thermal and rheological history of mayonnaise during freezing and its dispersion stability after the freeze-thaw process were investigated. Mayonnaise was cooled to freeze and stored at -20 to -40 °C while monitoring the temperature; penetration tests were conducted on the mayonnaise, which was sampled at selected times during isothermal storage at -20 °C. Significant increases in the temperature and stress values due to water-phase crystallization and subsequent oil-phase crystallization were observed. The water phase crystallized during the cooling step in all the tested mayonnaise samples. The oil phases of the prepared mayonnaise (with rapeseed oil) and commercial mayonnaise crystallized during isothermal storage after 6 and 4 h, respectively, at -20 °C. The dispersion stability was evaluated from the separation ratio, which was defined as the weight ratio of separated oil after centrifuging to the total amount of oil in the commercial mayonnaise. The separation ratio rapidly increased after 4 h of freezing. This result suggests that crystallization of the oil phase is strongly related to the dispersion stability of mayonnaise.

Wave Velocities in Hydrocarbons and Hydrocarbon Saturated - Applications to Eor Monitoring.

NASA Astrophysics Data System (ADS)

Wang, Zhijing

In order to effectively utilize many new seismic technologies and interpret the results, acoustic properties of both reservoir fluids and rocks must be well understood. It is the main purpose of this dissertation to investigate acoustic wave velocities in different hydrocarbons and hydrocarbon saturated rocks under various reservoir conditions. The investigation consists of six laboratory experiments, followed by a series of theoretical and application analyses. All the experiments involve acoustic velocity measurements in hydrocarbons and rocks with different hydrocarbons, using the ultrasonic pulse-transmission methods, at elevated temperatures and pressures. In the experiments, wave velocities are measured versus both temperature and pressure in 50 hydrocarbons. The relations among the acoustic velocity, temperature, pressure, API gravity, and the molecular weight of the hydrocarbons are studied, and empirical equations are established which allow one to calculate the acoustic velocities in hydrocarbons with known API gravities. Wave velocities in hydrocarbon mixtures are related to the composition and the velocities in the components. The experimental results are also analyzed in terms of various existing theories and models of the liquid state. Wave velocities are also measured in various rocks saturated with different hydrocarbons. The compressional wave velocities in rocks saturated with pure hydrocarbons increase with increasing the carbon number of the hydrocarbons. They decrease markedly in all the heavy hydrocarbon saturated rocks as temperature increases. Such velocity decreases set the petrophysical basis for in-situ seismic monitoring thermal enhanced oil recovery processes. The effects of carbon dioxide flooding and different pore fluids on wave velocities in rocks are also investigated. It is highly possible that there exist reflections of seismic waves at the light-heavy oil saturation interfaces in-situ. It is also possible to use seismic methods to monitor carbon dioxide flooding processes. Velocity dispersions are analyzed theoretically in rocks saturated with different pore fluids. The results are discussed in terms of the Biot theory and the "local flow" mechanism. Applications of the results and the applicability of using seismic methods to monitor various enhanced oil recovery and production processes are also discussed.

Final report on Weeks Island Monitoring Phase : 1999 through 2004.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ehgartner, Brian L.; Munson, Darrell Eugene

2005-05-01

This Final Report on the Monitoring Phase of the former Weeks Island Strategic Petroleum Reserve crude oil storage facility details the results of five years of monitoring of various surface accessible quantities at the decommissioned facility. The Weeks Island mine was authorized by the State of Louisiana as a Strategic Petroleum Reserve oil storage facility from 1979 until decommissioning of the facility in 1999. Discovery of a sinkhole over the facility in 1992 with freshwater inflow to the facility threatened the integrity of the oil storage and led to the decision to remove the oil, fill the chambers with brine,more » and decommission the facility. Thereafter, a monitoring phase, by agreement between the Department of Energy and the State, addressed facility stability and environmental concerns. Monitoring of the surface ground water and the brine of the underground chambers from the East Fill Hole produced no evidence of hydrocarbon contamination, which suggests that any unrecovered oil remaining in the underground chambers has been contained. Ever diminishing progression of the initial major sinkhole, and a subsequent minor sinkhole, with time was verification of the response of sinkholes to filling of the facility with brine. Brine filling of the facility ostensively eliminates any further growth or new formation from freshwater inflow. Continued monitoring of sinkhole response, together with continued surface surveillance for environmental problems, confirmed the intended results of brine pressurization. Surface subsidence measurements over the mine continued throughout the monitoring phase. And finally, the outward flow of brine was monitored as a measure of the creep closure of the mine chambers. Results of each of these monitoring activities are presented, with their correlation toward assuring the stability and environmental security of the decommissioned facility. The results suggest that the decommissioning was successful and no contamination of the surface environment by crude oil has been found.« less

46 CFR 162.050-5 - Contents of application.

Code of Federal Regulations, 2014 CFR

2014-10-01

... control procedures, in-process and final inspections and tests followed in manufacturing the item, and..., and maintenance of the item. (7) For each monitor and bilge alarm and each control on a separator, the vibration test report described in § 162.050-37. (8) For each oil content meter, a statement of whether it...

46 CFR 162.050-5 - Contents of application.

Code of Federal Regulations, 2011 CFR

2011-10-01

... control procedures, in-process and final inspections and tests followed in manufacturing the item, and..., and maintenance of the item. (7) For each monitor and bilge alarm and each control on a separator, the vibration test report described in § 162.050-37. (8) For each oil content meter, a statement of whether it...

46 CFR 162.050-5 - Contents of application.

Code of Federal Regulations, 2013 CFR

2013-10-01

... control procedures, in-process and final inspections and tests followed in manufacturing the item, and..., and maintenance of the item. (7) For each monitor and bilge alarm and each control on a separator, the vibration test report described in § 162.050-37. (8) For each oil content meter, a statement of whether it...

Future Issues and Approaches to Health Monitoring and Failure Prevention for Oil-Free Gas Turbines

NASA Technical Reports Server (NTRS)

DellaCorte, Christopher

2004-01-01

Recent technology advances in foil air bearings, high temperature solid lubricants and computer based modeling has enabled the development of small Oil-Free gas turbines. These turbomachines are currently commercialized as small (<100 kW) microturbine generators and larger machines are being developed. Based upon these successes and the high potential payoffs offered by Oil-Free systems, NASA, industry, and other government entities are anticipating Oil-Free gas turbine propulsion systems to proliferate future markets. Since an Oil-Free engine has no oil system, traditional approaches to health monitoring and diagnostics, such as chip detection, oil analysis, and possibly vibration signature analyses (e.g., ball pass frequency) will be unavailable. As such, new approaches will need to be considered. These could include shaft orbit analyses, foil bearing temperature measurements, embedded wear sensors and start-up/coast down speed analysis. In addition, novel, as yet undeveloped techniques may emerge based upon concurrent developments in MEMS technology. This paper introduces Oil-Free technology, reviews the current state of the art and potential for future turbomachinery applications and discusses possible approaches to health monitoring, diagnostics and failure prevention.

Space Telemetry for the Energy Industry

NASA Technical Reports Server (NTRS)

1983-01-01

Space telemetry is the process whereby information acquired in orbit is relayed to Earth. In 1981, Bill Sheen, President of Nu-Tech Industries, Inc., saw a need for a better way of monitoring flow, due to high costs of oil and gas, increasing oil field theft and a mounting requirement for more timely information to speed up accounting procedures. Sheen turned to NASA for assistance which was provided by Kerr Industrial Applications Center (KIAC). The system that emerged from two years of research, now in production at Nu-Tech's Fort Worth Texas facility, is known as the Remote Measurement and Control Network.

33 CFR 157.12a - Definitions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... recordings of data as specified in § 157.12d(h)(2). Oil discharge monitoring and control system or monitoring... RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Design... means a unit in a monitoring system composed of the items specified in § 157.12d(a)(4)(viii). Control...

33 CFR 157.12a - Definitions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... recordings of data as specified in § 157.12d(h)(2). Oil discharge monitoring and control system or monitoring... RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Design... means a unit in a monitoring system composed of the items specified in § 157.12d(a)(4)(viii). Control...

33 CFR 157.12a - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... recordings of data as specified in § 157.12d(h)(2). Oil discharge monitoring and control system or monitoring... RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Design... means a unit in a monitoring system composed of the items specified in § 157.12d(a)(4)(viii). Control...

33 CFR 157.12a - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... recordings of data as specified in § 157.12d(h)(2). Oil discharge monitoring and control system or monitoring... RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Design... means a unit in a monitoring system composed of the items specified in § 157.12d(a)(4)(viii). Control...

33 CFR 157.12a - Definitions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... recordings of data as specified in § 157.12d(h)(2). Oil discharge monitoring and control system or monitoring... RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Design... means a unit in a monitoring system composed of the items specified in § 157.12d(a)(4)(viii). Control...

40 CFR 464.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (T) 0.0339 0.0129 TTO 0.093 0.0304 Oil and grease (for alternate monitoring) 1.34 0.446 (b) Die....29 Oil and grease (for alternate monitoring) 60.8 20.3 (d) Mold Cooling Operations. PSNS Pollutant or....0022 Zinc (T) 0.0066 0.0025 Total phenols 0.0074 0.0026 TTO 0.0196 0.0064 Oil and grease (for alternate...

40 CFR 464.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (T) 0.0339 0.0129 TTO 0.093 0.0304 Oil and grease (for alternate monitoring) 1.34 0.446 (b) Die....29 Oil and grease (for alternate monitoring) 60.8 20.3 (d) Mold Cooling Operations. PSNS Pollutant or....0022 Zinc (T) 0.0066 0.0025 Total phenols 0.0074 0.0026 TTO 0.0196 0.0064 Oil and grease (for alternate...

40 CFR 464.46 - Pretreatment standards for new sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (T) 0.0339 0.0129 TTO 0.093 0.0304 Oil and grease (for alternate monitoring) 1.34 0.446 (b) Die....29 Oil and grease (for alternate monitoring) 60.8 20.3 (d) Mold Cooling Operations. PSNS Pollutant or....0022 Zinc (T) 0.0066 0.0025 Total phenols 0.0074 0.0026 TTO 0.0196 0.0064 Oil and grease (for alternate...

Multiclass mycotoxin analysis in edible oils using a simple solvent extraction method and liquid chromatography with tandem mass spectrometry.

PubMed

Eom, Taeyong; Cho, Hyun-Deok; Kim, Junghyun; Park, Mihee; An, Jinyoung; Kim, Moosung; Kim, Sheen-Hee; Han, Sang Beom

2017-11-01

A simple and rapid method for the simultaneous determination of 11 mycotoxins - aflatoxins B 1 , B 2 , G 1 and G 2 ; fumonisins B 1 , B 2 and B 3 ; ochratoxin A; zearalenone; deoxynivalenol; and T-2 toxin - in edible oils was established using liquid chromatography tandem mass spectrometry (LC-MS/MS). In this study, QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe), QuEChERS with dispersive liquid-liquid microextraction, and solvent extraction were examined for sample preparation. Among these methods, solvent extraction with a mixture of formic acid/acetonitrile (5/95, v/v) successfully extracted all target mycotoxins. Subsequently, a defatting process using n-hexane was employed to remove the fats present in the edible oil samples. Mass spectrometry was carried out using electrospray ionisation in polarity switching mode with multiple reaction monitoring. The developed LC-MS/MS method was validated by assessing the specificity, linearity, recovery, limit of quantification (LOQ), accuracy and precision with reference to Commission Regulation (EC) 401/2006. Mycotoxin recoveries of 51.6-82.8% were achieved in addition to LOQs ranging from 0.025 ng/g to 1 ng/g. The edible oils proved to be relatively uncomplicated matrices and the developed method was applied to 9 edible oil samples, including soybean oil, corn oil and rice bran oil, to evaluate potential mycotoxin contamination. The levels of detection were significantly lower than the international regulatory standards. Therefore, we expect that our developed method, based on simple, two-step sample preparation process, will be suitable for the large-scale screening of mycotoxin contamination in edible oils.

Impacts of a fuel oil spill on seagrass meadows in a subtropical port, Gladstone, Australia--the value of long-term marine habitat monitoring in high risk areas.

PubMed

Taylor, Helen A; Rasheed, Michael A

2011-01-01

We used an established seagrass monitoring programme to examine the short and longer-term impacts of an oil spill event on intertidal seagrass meadows. Results for potentially impacted seagrass areas were compared with existing monitoring data and with control seagrass meadows located outside of the oil spill area. Seagrass meadows were not significantly affected by the oil spill. Declines in seagrass biomass and area 1month post-spill were consistent between control and impact meadows. Eight months post-spill, seagrass density and area increased to be within historical ranges. The declines in seagrass meadows were likely attributable to natural seasonal variation and a combination of climatic and anthropogenic impacts. The lack of impact from the oil spill was due to several mitigating factors rather than a lack of toxic effects to seagrasses. The study demonstrates the value of long-term monitoring of critical habitats in high risk areas to effectively assess impacts. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved.

1997 annual report : environmental monitoring program Louisiana offshore oil port pipeline.

DOT National Transportation Integrated Search

1998-06-01

The Louisiana Offshore Oil Port (LOOP) Environmental Monitoring Program includes an onshore pipeline vegetation and wildlife survey as a continuing study designed to measure the immediate and long-term impacts of LOOP-related pipeline construction an...

Ecological impacts of the Deepwater Horizon oil spill: implications for immunotoxicity

EPA Science Inventory

Summary of major Federal and multi-stake holder research efforts in response to the DWH spill, including laboratory oil dispersant testing, estimation of oil release rates and oil fate calculations, subsea monitoring, and post-spill assessments. Impacts from shoreline oiling, wil...

Failure Prevention of Hydraulic System Based on Oil Contamination

NASA Astrophysics Data System (ADS)

Singh, M.; Lathkar, G. S.; Basu, S. K.

2012-07-01

Oil contamination is the major source of failure and wear of hydraulic system components. As per literature survey, approximately 70 % of hydraulic system failures are caused by oil contamination. Hence, to operate the hydraulic system reliably, the hydraulic oil should be of perfect condition. This requires a proper `Contamination Management System' which involves monitoring of various parameters like oil viscosity, oil temperature, contamination level etc. A study has been carried out on vehicle mounted hydraulically operated system used for articulation of heavy article, after making the platform levelled with outrigger cylinders. It is observed that by proper monitoring of contamination level, there is considerably increase in reliability, economy in operation and long service life. This also prevents the frequent failure of hydraulic system.

Proceedings of the symposium on assessing the industrial hygiene monitoring needs for the coal conversion and oil shale industries

DOE Office of Scientific and Technical Information (OSTI.GOV)

White, O. Jr.

1979-03-01

This work was supported by the United States Department of Energy, Division of Biomedical and Environmental Research, Analysis and Assessment Program, through the Safety and Environmental Protection Division at Brookhaven National Laboratory. The symposium program included presentations centering around the themes: Recognition of Occupational Health Monitoring Requirements for the Coal Conversion and Oil Shale Industries and Status of Dosimetry Technology for Occupational Health Monitoring for the Coal Conversion and Oil Shale Industries. Sixteen papers have been entered individually into EDB and ERA; six had been entered previously from other sources. (LTN)

Fluorescence excitation-emission matrix spectroscopy for degradation monitoring of machinery lubricants

NASA Astrophysics Data System (ADS)

Sosnovski, Oleg; Suresh, Pooja; Dudelzak, Alexander E.; Green, Benjamin

2018-02-01

Lubrication oil is a vital component of heavy rotating machinery defining the machine's health, operational safety and effectiveness. Recently, the focus has been on developing sensors that provide real-time/online monitoring of oil condition/lubricity. Industrial practices and standards for assessing oil condition involve various analytical methods. Most these techniques are unsuitable for online applications. The paper presents the results of studying degradation of antioxidant additives in machinery lubricants using Fluorescence Excitation-Emission Matrix (EEM) Spectroscopy and Machine Learning techniques. EEM Spectroscopy is capable of rapid and even standoff sensing; it is potentially applicable to real-time online monitoring.

A high sensitivity wear debris sensor using ferrite cores for online oil condition monitoring

NASA Astrophysics Data System (ADS)

Zhu, Xiaoliang; Zhong, Chong; Zhe, Jiang

2017-07-01

Detecting wear debris and measuring the increasing number of wear debris in lubrication oil can indicate abnormal machine wear well ahead of machine failure, and thus are indispensable for online machine health monitoring. A portable wear debris sensor with ferrite cores for online monitoring is presented. The sensor detects wear debris by measuring the inductance change of two planar coils wound around a pair of ferrite cores that make the magnetic flux denser and more uniform in the sensing channel, thereby improving the sensitivity of the sensor. Static testing results showed this wear debris sensor is capable of detecting 11 µm and 50 µm ferrous debris in 1 mm and 7 mm diameter fluidic pipes, respectively; such a high sensitivity has not been achieved before. Furthermore, a synchronized sampling method was also applied to reduce the data size and realize real-time data processing. Dynamic testing results demonstrated that the sensor is capable of detecting wear debris in real time with a high throughput of 750 ml min-1 the measured debris concentration is in good agreement with the actual concentration.

A Comparison of Vibration and Oil Debris Gear Damage Detection Methods Applied to Pitting Damage

NASA Technical Reports Server (NTRS)

Dempsey, Paula J.

2000-01-01

Helicopter Health Usage Monitoring Systems (HUMS) must provide reliable, real-time performance monitoring of helicopter operating parameters to prevent damage of flight critical components. Helicopter transmission diagnostics are an important part of a helicopter HUMS. In order to improve the reliability of transmission diagnostics, many researchers propose combining two technologies, vibration and oil monitoring, using data fusion and intelligent systems. Some benefits of combining multiple sensors to make decisions include improved detection capabilities and increased probability the event is detected. However, if the sensors are inaccurate, or the features extracted from the sensors are poor predictors of transmission health, integration of these sensors will decrease the accuracy of damage prediction. For this reason, one must verify the individual integrity of vibration and oil analysis methods prior to integrating the two technologies. This research focuses on comparing the capability of two vibration algorithms, FM4 and NA4, and a commercially available on-line oil debris monitor to detect pitting damage on spur gears in the NASA Glenn Research Center Spur Gear Fatigue Test Rig. Results from this research indicate that the rate of change of debris mass measured by the oil debris monitor is comparable to the vibration algorithms in detecting gear pitting damage.

Changes in microbial populations and enzyme activities during the bioremediation of oil-contaminated soil.

PubMed

Lin, Xin; Li, Xiaojun; Sun, Tieheng; Li, Peijun; Zhou, Qixing; Sun, Lina; Hu, Xiaojun

2009-10-01

In the process of bioremediation in the soil contaminated by different oil concentrations, the changes in the microbial numbers (bacteria and fungi) and the enzyme (catalase (CAT), polyphenol oxidase (PPO) and lipase) activities were evaluated over a 2-year period. The results showed that the microbial numbers after 2-year bioremediation were one to ten times higher than those in the initial. The changes in the bacterial and the fungal populations were different during the bioremediation, and the highest microbial numbers for bacteria and fungi were 5.51 x 10(9) CFU g(-1) dry soil in treatment 3 (10,000 mg kg(-1)) in the initial and 5.54 x 10(5) CFU g(-1) dry soil in treatment 5 (50,000 mg kg(-1)) after the 2-year bioremediation period, respectively. The CAT and PPO activities in the contaminated soil decreased with increasing oil concentration, while the lipase activity increased. The activities of CAT and PPO improved after the bioremediation, but lipase activity was on the contrary. The CAT activity was more sensible to the oil than others, and could be alternative to monitor the bioremediation process.

40 CFR 464.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Total phenols 1.74 0.608 TTO 3.95 1.29 Oil and grease for alternate monitoring) 60.8 20.3 (d) Mold... Zinc (T) 0.3 0.114 TTO 0.821 0.268 Oil and grease for alternate monitoring) 11.8 3.94 ....0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 TTO 0.093 0.0304 Oil and grease (for alternate...

40 CFR 464.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Total phenols 1.74 0.608 TTO 3.95 1.29 Oil and grease for alternate monitoring) 60.8 20.3 (d) Mold... Zinc (T) 0.3 0.114 TTO 0.821 0.268 Oil and grease for alternate monitoring) 11.8 3.94 ....0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 TTO 0.093 0.0304 Oil and grease (for alternate...

40 CFR 464.45 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Total phenols 1.74 0.608 TTO 3.95 1.29 Oil and grease for alternate monitoring) 60.8 20.3 (d) Mold... Zinc (T) 0.3 0.114 TTO 0.821 0.268 Oil and grease for alternate monitoring) 11.8 3.94 ....0187 Lead (T) 0.0237 0.0116 Zinc (T) 0.0339 0.0129 TTO 0.093 0.0304 Oil and grease (for alternate...

The application of pulse field gradient (PFG) NMR methods to characterize the efficiency of separation of water-in-crude oil emulsions.

PubMed

Marques, Debora Salomon; Sørland, Geir; Less, Simone; Vilagines, Regis

2018-02-15

Demulsification of water-in-crude oil emulsions is an essential and sometimes challenging procedure for crude oil processing facilities. Pulse field gradient (PFG) NMR techniques are known to monitor the dynamics of emulsion separation. This method has limitations that restrict its application to some crude oils. A comprehensive methodology applicable to all types of crude oil regardless of its viscosity, without assumptions, and providing a large number of data with fast measurements, is proposed in this paper. The coalescence and sedimentation of unstable emulsions was observed through simultaneous measurements of the evolution of the brine profile and droplet size distribution (DSD). Measurements of emulsions after stabilization, with and without the contribution of the free water layer, revealed the residual emulsified water quantity and location in the sample. A new, faster approach to separate the oil and water overlapping T 2 relaxation signals was demonstrated on real water-in-crude oil emulsions, using the root mean square displacement (RMSD) measured with the spoiler recovery and a loop of 13-interval pulsed field gradient stimulated echo (PFGSTE) oneshot sequences. The residual water within the crude oils after separation was determined and used to quantify the efficiency of the demulsifier used. Copyright © 2017 Elsevier Inc. All rights reserved.

Changes in oil content, fatty acid composition, and functional lipid profiles during dry grind ethanol production from corn.

USDA-ARS?s Scientific Manuscript database

Demand for alternatives to fossil fuels has resulted in a dramatic increase in ethanol production from corn. The dry grind method has been the major process, resulting in a large volume of dried distiller grains with solubles (DDGS) as a co-product. This presentation reports our study to monitor ...

30 CFR 250.233 - What decisions will MMS make on the EP and within what timeframe?

Code of Federal Regulations, 2011 CFR

2011-07-01

..., REGULATION, AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Plans and Information Review and Decision Process for the Ep § 250.233 What..., including those to provide monitoring information. (2) Require you to modify your proposed EP The Regional...

United States Military Posture for FY 1987

DTIC Science & Technology

1987-01-01

monitor, plan, and execute mobilization, deployment, employment, and sustainment during peace, crisis, and war. JOPES requirements are being developed ...positioning 68 Deployment Management 69 VI Sustainability 69 Ammunition 69 Petroleum, Oils, and Lubricants 69 Military Construction 69...Commanders in Chiefs 73 Joint Doctrine 73 Combined Doctrine 74 Joint Force Development Process 74 Joint Resource Assessment 75 Joint Program

Distributed acoustic sensing technique and its field trial in SAGD well

NASA Astrophysics Data System (ADS)

Han, Li; He, Xiangge; Pan, Yong; Liu, Fei; Yi, Duo; Hu, Chengjun; Zhang, Min; Gu, Lijuan

2017-10-01

Steam assisted gravity drainage (SAGD) is a very promising way for the development of heavy oil, extra heavy oil and tight oil reservoirs. Proper monitoring of the SAGD operations is essential to avoid operational issues and improve efficiency. Among all the monitoring techniques, micro-seismic monitoring and related interpretation method can give useful information about the steam chamber development and has been extensively studied. Distributed acoustic sensor (DAS) based on Rayleigh backscattering is a newly developed technique that can measure acoustic signal at all points along the sensing fiber. In this paper, we demonstrate a DAS system based on dual-pulse heterodyne demodulation technique and did field trial in SAGD well located in Xinjiang Oilfield, China. The field trail results validated the performance of the DAS system and indicated its applicability in steam-chamber monitoring and hydraulic monitoring.

Satellite Monitoring Over the Canadian Oil Sands: Highlights from Aura OMI and TES

NASA Technical Reports Server (NTRS)

Shephard, Mark W.; McLinden, Chris; Fioletov, Vitali; Cady-Pereira, Karen E.; Krotkov, Nick A.; Boersma, Folkert; Li, Can; Luo, Ming; Bhartia, P. K.; Joiner, Joanna

2014-01-01

Satellite remote sensing provides a unique perspective for air quality monitoring in and around the Canadian Oil Sands as a result of its spatial and temporal coverage. Presented are Aura satellite observations of key pollutants including nitrogen dioxide (NO2), sulfur dioxide (SO2), carbon monoxide (CO), ammonia (NH3), methanol (CH3OH), and formic acid (HCOOH) over the Canadian Oil Sands. Some of the highlights include: (i) the evolution of NO2 and SO2 from the Ozone Monitoring Instrument (OMI), including comparisons with other nearby sources, (ii) two years of ammonia, carbon monoxide, methanol, and formic acid observations from 240 km North-South Tropospheric Emission Spectrometer (TES) transects through the oils sands, and (iii) preliminary insights into emissions derived from these observations.

Characterization of oscillator circuits for monitoring the density-viscosity of liquids by means of piezoelectric MEMS microresonators

NASA Astrophysics Data System (ADS)

Toledo, J.; Ruiz-Díez, V.; Pfusterschmied, G.; Schmid, U.; Sánchez-Rojas, J. L.

2017-06-01

Real-time monitoring of the physical properties of liquids, such as lubricants, is a very important issue for the automotive industry. For example, contamination of lubricating oil by diesel soot has a significant impact on engine wear. Resonant microstructures are regarded as a precise and compact solution for tracking the viscosity and density of lubricant oils. In this work, we report a piezoelectric resonator, designed to resonate with the 4th order out-of-plane modal vibration, 15-mode, and the interface circuit and calibration process for the monitoring of oil dilution with diesel fuel. In order to determine the resonance parameters of interest, i.e. resonant frequency and quality factor, an interface circuit was implemented and included within a closed-loop scheme. Two types of oscillator circuits were tested, a Phase-Locked Loop based on instrumentation, and a more compact version based on discrete electronics, showing similar resolution. Another objective of this work is the assessment of a calibration method for piezoelectric MEMS resonators in simultaneous density and viscosity sensing. An advanced calibration model, based on a Taylor series of the hydrodynamic function, was established as a suitable method for determining the density and viscosity with the lowest calibration error. Our results demonstrate the performance of the resonator in different oil samples with viscosities up to 90 mPa•s. At the highest value, the quality factor measured at 25°C was around 22. The best resolution obtained was 2.4•10-6 g/ml for the density and 2.7•10-3 mPa•s for the viscosity, in pure lubricant oil SAE 0W30 at 90°C. Furthermore, the estimated density and viscosity values with the MEMS resonator were compared to those obtained with a commercial density-viscosity meter, reaching a mean calibration error in the best scenario of around 0.08% for the density and 3.8% for the viscosity.

Application of Fenton process to remove organic matter and PCBs from waste (fuller's earth) contaminated with insulating oil.

PubMed

da Silva, Milady Renata Apolinário; Rodrigues, Eduardo de Oliveira; Espanhol-Soares, Melina; Silva, Flavio Soares; Kondo, Márcia Matiko; Gimenes, Rossano

2018-01-09

Polychlorinated biphenyls (PCBs) are carcinogenic to humans and can be found in fuller's earth used for the treatment of used transformer oil. This work describes an optimization of the Fenton process for the removal of contaminants from fuller's earth. The effects of pH (2.5 and 4.0), [H 2 O 2 ] (1.47 and 2.07 mol L -1 ), and [Fe 2+ ] (1.7 and 40 mmol L -1 ) were studied. The Fenton process efficiency was monitored using the decreases in the chemical oxygen demand (COD) and the concentrations of oil and grease, total carbon (TC), PCBs, and H 2 O 2 . The fuller's earth contaminated with insulating oil presented 35% (w/w) of TC, 34% (w/w) of oil and grease, 297.0 g L -1 COD, and 64 mg of PCBs per kg. The material could therefore be considered a dangerous waste. After Fenton treatment, using a slurry mode, there was a removal of 55% of COD, 20% of oil and grease, and 20% of TC, achieved at pH 2.5 using 2.07 mol L -1 of H 2 O 2 and 40.0 mmol L -1 of Fe 2+ . No PCBs were detected in the samples after the Fenton treatment, even using smaller amounts of Fenton reagents (1.47 mol L -1 of H 2 O 2 , 1.7 mmol L -1 of Fe 2+ , pH 2.5). The results indicated that the treated fuller's earth was free from PCB residues and could be disposed of in a simple landfill, in accordance with Brazilian PCB regulations.

Ruthenium oxide ion selective thin-film electrodes for engine oil acidity monitoring

NASA Astrophysics Data System (ADS)

Maurya, D. K.; Sardarinejad, A.; Alameh, K.

2015-06-01

We demonstrate the concept of a low-cost, rugged, miniaturized ion selective electrode (ISE) comprising a thin film RuO2 on platinum sensing electrode deposited using RF magnetron sputtered in conjunction with an integrated Ag/AgCl and Ag reference electrodes for engine oil acidity monitoring. Model oil samples are produced by adding nitric acid into fresh fully synthetic engine oil and used for sensor evaluation. Experimental results show a linear potential-versus-acid-concentration response for nitric acid concentration between 0 (fresh oil) to 400 ppm, which demonstrate the accuracy of the RuO2 sensor in real-time operation, making it attractive for use in cars and industrial engines.

Interpreting isotopic analyses of microbial sulfate reduction in oil reservoirs

NASA Astrophysics Data System (ADS)

Hubbard, C. G.; Engelbrektson, A. L.; Druhan, J. L.; Cheng, Y.; Li, L.; Ajo Franklin, J. B.; Coates, J. D.; Conrad, M. E.

2013-12-01

Microbial sulfate reduction in oil reservoirs is often associated with secondary production of oil where seawater (28 mM sulfate) is commonly injected to maintain reservoir pressure and displace oil. The hydrogen sulfide produced can cause a suite of operating problems including corrosion of infrastructure, health exposure risks and additional processing costs. We propose that monitoring of the sulfur and oxygen isotopes of sulfate can be used as early indicators that microbial sulfate reduction is occurring, as this process is well known to cause substantial isotopic fractionation. This approach relies on the idea that reactions with reservoir (iron) minerals can remove dissolved sulfide, thereby delaying the transport of the sulfide through the reservoir relative to the sulfate in the injected water. Changes in the sulfate isotopes due to microbial sulfate reduction may therefore be measurable in the produced water before sulfide is detected. However, turning this approach into a predictive tool requires (i) an understanding of appropriate fractionation factors for oil reservoirs, (ii) incorporation of isotopic data into reservoir flow and reactive transport models. We present here the results of preliminary batch experiments aimed at determining fractionation factors using relevant electron donors (e.g. crude oil and volatile fatty acids), reservoir microbial communities and reservoir environmental conditions (pressure, temperature). We further explore modeling options for integrating isotope data and discuss whether single fractionation factors are appropriate to model complex environments with dynamic hydrology, geochemistry, temperature and microbiology gradients.

40 CFR 464.25 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2014 CFR

2014-07-01

....84 2.86 Zinc (T) 8.37 3.19 TTO 25.4 8.29 Oil and grease for alternate monitoring) 330 110 (f) Melting....214 Lead (T) 0.27 0.132 Zinc (T) 0.387 0.148 TTO 0.428 0.14 Oil and grease (for alternate monitoring... Copper (T) 0.0307 0.0168 Lead (T) 0.0211 0.0104 Zinc (T) 0.0303 0.0116 TTO 0.0335 0.0109 Oil and grease...

40 CFR 464.25 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2013 CFR

2013-07-01

....84 2.86 Zinc (T) 8.37 3.19 TTO 25.4 8.29 Oil and grease for alternate monitoring) 330 110 (f) Melting....214 Lead (T) 0.27 0.132 Zinc (T) 0.387 0.148 TTO 0.428 0.14 Oil and grease (for alternate monitoring... Copper (T) 0.0307 0.0168 Lead (T) 0.0211 0.0104 Zinc (T) 0.0303 0.0116 TTO 0.0335 0.0109 Oil and grease...

40 CFR 464.25 - Pretreatment standards for existing sources.

Code of Federal Regulations, 2012 CFR

2012-07-01

....84 2.86 Zinc (T) 8.37 3.19 TTO 25.4 8.29 Oil and grease for alternate monitoring) 330 110 (f) Melting....214 Lead (T) 0.27 0.132 Zinc (T) 0.387 0.148 TTO 0.428 0.14 Oil and grease (for alternate monitoring... Copper (T) 0.0307 0.0168 Lead (T) 0.0211 0.0104 Zinc (T) 0.0303 0.0116 TTO 0.0335 0.0109 Oil and grease...

Prognostic Fusion for Uncertainty Reduction

DTIC Science & Technology

2007-02-01

Damage estimates are arrived at using sensor information such as oil debris monitoring data as well as vibration data. The method detects the onset of...NAME OF RESPONSIBLE PERSON ( Monitor ) a. REPORT Unclassified b. ABSTRACT Unclassified c . THIS PAGE Unclassified 17. LIMITATION OF ABSTRACT...estimates are arrived at using sensor information such as oil debris monitoring data as well as vibration data. The method detects the onset of

Evolution of oil/water interface in the presence of SDBS detected by dual polarization interferometry

NASA Astrophysics Data System (ADS)

Duan, Ming; Ding, Ziling; Wang, Hu; Xiong, Yan; Fang, Shenwen; Shi, Peng; Liu, Shuai

2018-01-01

In this work, the technique of dual polarization interferometry (DPI) was applied to establish a new method to monitor the real-time evolution of oil/water interface in the presence of sodium dodecyl benzene sulfonate (SDBS) at molecular level. A three-stage model of adsorption-desorption-detachment had been proposed and was systematically discussed upon the addition of different SDBS concentrations based on the variation of the interfacial mass with time. The results demonstrated two patterns of adsorption morphology at the oil/water interface, SDBS mono-molecules and SDBS hemi-micelles at SDBS concentrations below and above cmc respectively according to the relaxation time obtained by theoretical model and the reaction order calculated by integral method in the analysis of adsorbed dynamics. The capability of oil detachment with the aid of SDBS as well as the properties of the outlet fluid were investigated under two patterns of adsorption morphologies, which showed different effects of oil detachment with the aid of SDBS molecules. The speed of oil detachment and the fluorescence intensity of the outlet fluid during the detachment process indicated the fact that the oil detachment capability was significantly promoted by the morphology of the absorbed hemi-micelles. The findings in the present study are crucial for fully understanding the interfacial behavior of surfactants applied in oil/water interface, which is of great significance in enhanced oil recovery and pollution industry.

Open-Path Hydrocarbon Laser Sensor for Oil and Gas Facility Monitoring

EPA Science Inventory

This poster reports on an experimental prototype open-path laser absorption sensor for measurement of unspeciated hydrocarbons for oil and gas production facility fence-line monitoring. Such measurements may be useful to meet certain state regulations, and enable advanced leak d...

Determination of thermodynamic and transport parameters of naphthenic acids and organic process chemicals in oil sand tailings pond water.

PubMed

Wang, Xiaomeng; Robinson, Lisa; Wen, Qing; Kasperski, Kim L

2013-07-01

Oil sand tailings pond water contains naphthenic acids and process chemicals (e.g., alkyl sulphates, quaternary ammonium compounds, and alkylphenol ethoxylates). These chemicals are toxic and can seep through the foundation of the tailings pond to the subsurface, potentially affecting the quality of groundwater. As a result, it is important to measure the thermodynamic and transport parameters of these chemicals in order to study the transport behavior of contaminants through the foundation as well as underground. In this study, batch adsorption studies and column experiments were performed. It was found that the transport parameters of these chemicals are related to their molecular structures and other properties. The computer program (CXTFIT) was used to further evaluate the transport process in the column experiments. The results from this study show that the transport of naphthenic acids in a glass column is an equilibrium process while the transport of process chemicals seems to be a non-equilibrium process. At the end of this paper we present a real-world case study in which the transport of the contaminants through the foundation of an external tailings pond is calculated using the lab-measured data. The results show that long-term groundwater monitoring of contaminant transport at the oil sand mining site may be necessary to avoid chemicals from reaching any nearby receptors.

Downhole Measurements of Electrokinetic Potential to Monitor Flow in Oilfields

NASA Astrophysics Data System (ADS)

Saunders, J.; Jackson, M.; Pain, C.; Addiego-Guevara, E.

2005-12-01

Oil companies currently produce an average of three barrels of water for each barrel of oil, which is expensive and environmentally unfriendly: the produced water is contaminated and must be treated and disposed of carefully. Ideally, water production would be prevented or minimised by monitoring its movement within the reservoir and responding appropriately. We suggest that measurements of electrokinetic (or ' streaming') potential during oil production, using permanently installed downhole electrodes, could be used to monitor water encroachment towards a well before water breakthrough occurs. Electrokinetic potentials are generated when fluids flow through rock, and although they are increasingly being used in other areas of earth science to monitor subsurface flows, there has been little investigation of their utility in hydrocarbon reservoirs. We have used a new numerical model to simulate the electrokinetic potential measured at a well during oil production, with reservoir pressure maintained by water injection or aquifer influx. Our results suggest that encroaching water causes changes in the electrokinetic potential at the well which could be resolved above background electrical noise; indeed, water approaching the well could be monitored several 10s to 100s of metres away. Our results differ from those obtained previously, because we include the results of recent laboratory experiments which provide new insight into the nature of the coupling between fluid and electrokinetic potentials as the oil saturation changes. Moreover, we investigate a range of production rates which are more appropriate for modern offshore developments, and simulate the potential measured at electrodes installed at the producing well rather than at a nearby monitoring well or at the surface. Electrodes mounted downhole on insulated casing have been successfully applied in subsurface resistivity surveys during oil production, and similar technology could be used to measure electrokinetic potential. If the producing well is equipped with downhole inflow control valves (so called ' intelligent' well technology), then oil production can be significantly enhanced if encroaching water is detected before it arrives and flow into the wellbore properly controlled. These findings raise the prospect of an oil field in which the wells can monitor the approach of water and respond appropriately. Such wells offer enormous potential economic and environmental benefits, particularly in fields which are difficult to access or dangerous to operate.

Size distributions and exposure concentrations of nanoparticles associated with the emissions of oil mists from fastener manufacturing processes.

PubMed

Wang, Ying-Fang; Tsai, Perng-Jy; Chen, Chun-Wan; Chen, Da-Ren; Dai, Yu-Tung

2011-12-30

The aims of the present study were set out to measure size distributions and estimate workers' exposure concentrations of oil mist nanoparticles in three selected workplaces of the forming, threading, and heat treating areas in a fastener manufacturing plant by using a modified electrical aerosol detector (MEAD). The results were further compared with those simultaneously obtained from a nanoparticle surface area monitor (NSAM) and a scanning mobility particle sizer (SMPS) for the validation purpose. Results show that oil mist nanoparticles in the three selected process areas were formed mainly through the evaporation and condensation processes. The measured size distributions of nanoparticles were consistently in the form of uni-modal. The estimated fraction of nanoparticles deposited on the alveolar (AV) region was consistently much higher than that on the head airway (HD) and tracheobronchial (TB) regions in both number and surface area concentration bases. However, a significant difference was found in the estimated fraction of nanoparticles deposited on each individual region while different exposure metrics were used. Comparable results were found between results obtained from both NSAM and MEAD. After normalization, no significant difference can be found between the results obtained from SMPS and MEAD. It is concluded that the obtained MEAD results are suitable for assessing oil mist nanoparticle exposures. Copyright © 2011 Elsevier B.V. All rights reserved.

Online monitoring of oil film using electrical capacitance tomography and level set method.

PubMed

Xue, Q; Sun, B Y; Cui, Z Q; Ma, M; Wang, H X

2015-08-01

In the application of oil-air lubrication system, electrical capacitance tomography (ECT) provides a promising way for monitoring oil film in the pipelines by reconstructing cross sectional oil distributions in real time. While in the case of small diameter pipe and thin oil film, the thickness of the oil film is hard to be observed visually since the interface of oil and air is not obvious in the reconstructed images. And the existence of artifacts in the reconstructions has seriously influenced the effectiveness of image segmentation techniques such as level set method. Besides, level set method is also unavailable for online monitoring due to its low computation speed. To address these problems, a modified level set method is developed: a distance regularized level set evolution formulation is extended to image two-phase flow online using an ECT system, a narrowband image filter is defined to eliminate the influence of artifacts, and considering the continuity of the oil distribution variation, the detected oil-air interface of a former image can be used as the initial contour for the detection of the subsequent frame; thus, the propagation from the initial contour to the boundary can be greatly accelerated, making it possible for real time tracking. To testify the feasibility of the proposed method, an oil-air lubrication facility with 4 mm inner diameter pipe is measured in normal operation using an 8-electrode ECT system. Both simulation and experiment results indicate that the modified level set method is capable of visualizing the oil-air interface accurately online.

Online monitoring of oil film using electrical capacitance tomography and level set method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xue, Q., E-mail: xueqian@tju.edu.cn; Ma, M.; Sun, B. Y.

2015-08-15

In the application of oil-air lubrication system, electrical capacitance tomography (ECT) provides a promising way for monitoring oil film in the pipelines by reconstructing cross sectional oil distributions in real time. While in the case of small diameter pipe and thin oil film, the thickness of the oil film is hard to be observed visually since the interface of oil and air is not obvious in the reconstructed images. And the existence of artifacts in the reconstructions has seriously influenced the effectiveness of image segmentation techniques such as level set method. Besides, level set method is also unavailable for onlinemore » monitoring due to its low computation speed. To address these problems, a modified level set method is developed: a distance regularized level set evolution formulation is extended to image two-phase flow online using an ECT system, a narrowband image filter is defined to eliminate the influence of artifacts, and considering the continuity of the oil distribution variation, the detected oil-air interface of a former image can be used as the initial contour for the detection of the subsequent frame; thus, the propagation from the initial contour to the boundary can be greatly accelerated, making it possible for real time tracking. To testify the feasibility of the proposed method, an oil-air lubrication facility with 4 mm inner diameter pipe is measured in normal operation using an 8-electrode ECT system. Both simulation and experiment results indicate that the modified level set method is capable of visualizing the oil-air interface accurately online.« less

Rapid screening of fatty acid alkyl esters in olive oils by time domain reflectometry.

PubMed

Berardinelli, Annachiara; Ragni, Luigi; Bendini, Alessandra; Valli, Enrico; Conte, Lanfranco; Guarnieri, Adriano; Toschi, Tullia Gallina

2013-11-20

The main aim of the present research is to assess the possibility of quickly screening fatty acid alkyl esters (FAAE) in olive oils using time domain reflectometry (TDR) and partial least-squares (PLS) multivariate statistical analysis. Eighteen virgin olive oil samples with fatty acid alkyl ester contents and fatty acid ethyl ester/methyl ester ratios (FAEE/FAME) ranging from 3 to 100 mg kg(-1) and from 0.3 to 2.6, respectively, were submitted to tests with time domain resolution of 1 ps. The results obtained in test set validation demonstrated that this new and fast analytical approach is able to predict FAME, FAEE, and FAME + FAEE contents with R(2) values of 0.905, 0.923, and 0.927, respectively. Further measurements on mixtures between olive oil and FAAE standards confirmed that the prediction is based on a direct influence of fatty acid alkyl esters on the TDR signal. The suggested technique appeared potentially suitable for monitoring one of the most important quality attribute of the olive oil in the extraction process.

Potential oil spill risk from shipping and the implications for management in the Caribbean Sea.

PubMed

Singh, Asha; Asmath, Hamish; Chee, Candice Leung; Darsan, Junior

2015-04-15

The semi enclosed Caribbean Sea is ranked as having one of the most intense maritime traffic in the world. These maritime activities have led to significant oil pollution. Simultaneously, this sea supports many critical habitats functioning as a Large Marine Ecosystem (LME). While the impacts of oil pollution are recognised, a number of management challenges remain. This study applies spatial modelling to identify critical areas potentially at risk from oil spills in the form of a potential oil spill risk (POSR) model. The model indicates that approximately 83% of the sea could be potentially impacted by oil spills due to shipping. The results from this study collectively support a management framework for minimising ship generated oil pollution in the Caribbean Sea. Among the recommended components are a common policy, surveillance and monitoring controls, standards, monitoring programmes, data collection and greater rates of convention ratifications. Copyright © 2015 Elsevier Ltd. All rights reserved.

Direct technique for monitoring lipid oxidation in water-in-oil emulsions based on micro-calorimetry.

PubMed

Dridi, Wafa; Toutain, Jean; Sommier, Alain; Essafi, Wafa; Leal-Calderon, Fernando; Cansell, Maud

2017-09-01

An experimental device based on the measurement of the heat flux dissipated during chemical reactions, previously validated for monitoring lipid oxidation in plant oils, was extended to follow lipid oxidation in water-in-oil emulsions. Firstly, validation of the approach was performed by correlating conjugated diene concentrations measured by spectrophotometry and the heat flux dissipated by oxidation reactions and measured directly in water-in-oil emulsions, in isothermal conditions at 60°C. Secondly, several emulsions based on plant oils differing in their n-3 fatty acid content were compared. The oxidability parameter derived from the enthalpy curves reflected the α-linolenic acid proportion in the oils. On the whole, the micro-calorimetry technique provides a sensitive method to assess lipid oxidation in water-in-oil emulsions without requiring any phase extraction. Copyright © 2017 Elsevier Ltd. All rights reserved.

A Multispectral Look at Oil Pollution Detection, Monitoring, and Law Enforcement

NASA Technical Reports Server (NTRS)

Catoe, C. E.; Mclean, J. T.

1979-01-01

The problems of detecting oil films on water, mapping the areal extent of slicks, measuring the slick thickness, and identifying oil types are discussed. The signature properties of oil in the ultraviolet, visible, infrared, microwave, and radar regions are analyzed.

Feasibility of the Scalable, Automated, Semipermanent Seismic Array (SASSA) to Monitor Possible Carbon Dioxide Migration

NASA Astrophysics Data System (ADS)

Livers, A. J.; Burnison, S. A.; Salako, O.; Barajas-Olalde, C.; Hamling, J. A.; Gorecki, C. D.

2016-12-01

The feasibility of monitoring potential carbon dioxide (CO2) migration in a reservoir using a sparse seismic array is being evaluated by the Energy & Environmental Research Center (EERC) at the Denbury Onshore LLC-operated Bell Creek oil field in Montana, which is undergoing commercial CO2 enhanced oil recovery (EOR). This new method may provide an economical means of continuously monitoring the CO2 plume edge and the CO2 reservoir boundaries and/or to interpret vertical or lateral out-of-reservoir CO2 migration. A 96-station scalable, automated, semipermanent seismic array (SASSA) was deployed in October 2015 to detect and track CO2 plume migration not by imaging, but by monitoring discrete source-receiver midpoints. Midpoints were strategically located within and around four injector-producer patterns covering approximately one square mile. Three-dimensional (3-D) geophysical ray tracing was used to determine surface receiver locations. Receivers used were FairfieldNodal Zland three-component, autonomous, battery-powered nodes. A GISCO ESS850 accelerated weight drop source located in a secure structure was remotely fired on a weekly basis for one calendar year, including a two-month period prior to initiation of CO2 injection to establish a baseline. Fifty shots were fired one day each week to facilitate increased signal-to-noise through novel receiver domain processing and vertical stacking. Receiver domain processing allowed for individualization of processing parameters to maximize signal enhancement and noise attenuation. Reflection events in the processed SASSA data correlate well to 3-D surface survey data collected in the field. Preliminary time-lapse data results for several individual SASSA receivers show a phase shift in the reflection events below the reservoir after injection, suggesting possible migration of the CO2 in the reservoir to the corresponding midpoint locations. This work is supported by the U.S. Department of Energy National Energy Technology Laboratory under Award No. FE0012665.

Design and Implementation of a Coastal-Mounted Sensor for Oil Film Detection on Seawater

PubMed Central

Hou, Yongchao; Li, Ying; Liu, Yu; Wang, Tong

2017-01-01

The routine surveillance of oil spills in major ports is important. However, existing techniques and sensors are unable to trace oil and micron-thin oil films on the surface of seawater. Therefore, we designed and studied a coastal-mounted sensor, using ultraviolet-induced fluorescence and fluorescence-filter systems (FFSs), to monitor oil spills and overcome the disadvantages of traditional surveillance systems. Using seawater from the port of Lingshui (Yellow Sea, China) and six oil samples of different types, we found that diesel oil’s relative fluorescence intensity (RFI) was significantly higher than those of heavy fuel and crude oils in the 180–300 nm range—in the 300–400 nm range, the RFI value of diesel is far lower. The heavy fuel and crude oils exhibited an opposite trend in their fluorescence spectra. A photomultiplier tube, employed as the fluorescence detection unit, efficiently monitored different oils on seawater in field experiments. On-site tests indicated that this sensor system could be used as a coastal-mounted early-warning detection system for oil spills. PMID:29283412

75 FR 24822 - Fisheries of the Caribbean, Gulf of Mexico, and South Atlantic; Emergency Fisheries Closure in...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-06

... conditions allow NMFS to terminate it sooner. NMFS will continue to monitor and evaluate the oil spill and... of NOAA chart 11360. NMFS will continue to monitor and evaluate the oil spill and its impacts to Gulf...

Oil palm mapping for Malaysia using PALSAR-2 dataset

NASA Astrophysics Data System (ADS)

Gong, P.; Qi, C. Y.; Yu, L.; Cracknell, A.

2016-12-01

Oil palm is one of the most productive vegetable oil crops in the world. The main oil palm producing areas are distributed in humid tropical areas such as Malaysia, Indonesia, Thailand, western and central Africa, northern South America, and central America. Increasing market demands, high yields and low production costs of palm oil are the primary factors driving large-scale commercial cultivation of oil palm, especially in Malaysia and Indonesia. Global demand for palm oil has grown exponentially during the last 50 years, and the expansion of oil palm plantations is linked directly to the deforestation of natural forests. Satellite remote sensing plays an important role in monitoring expansion of oil palm. However, optical remote sensing images are difficult to acquire in the Tropics because of the frequent occurrence of thick cloud cover. This problem has led to the use of data obtained by synthetic aperture radar (SAR), which is a sensor capable of all-day/all-weather observation for studies in the Tropics. In this study, the ALOS-2 (Advanced Land Observing Satellite) PALSAR-2 (Phased Array type L-band SAR) datasets for year 2015 were used as an input to a support vector machine (SVM) based machine learning algorithm. Oil palm/non-oil palm samples were collected using a hexagonal equal-area sampling design. High-resolution images in Google Earth and PALSAR-2 imagery were used in human photo-interpretation to separate oil palm from others (i.e. cropland, forest, grassland, shrubland, water, hard surface and bareland). The characteristics of oil palms from various aspects, including PALSAR-2 backscattering coefficients (HH, HV), terrain and climate by using this sample set were further explored to post-process the SVM output. The average accuracy of oil palm type is better than 80% in the final oil palm map for Malaysia.

Modernization of Special Monitoring of Applied Response Technologies (SMART) Technology and Methods - 2014

DTIC Science & Technology

2014-10-01

recommendations that came out of the DWH experience.  The USCG BP Deepwater Horizon Oil Spill Incident Specific Preparedness Review Final Report, January...look at the EPA air monitoring data that was posted the ERMA situation map. The BP Deepwater Horizon Oil Spill Incident Specific Preparedness Review...incidents:  M/V New Carissa Grounding, 1999 (in-situ burning)  Eugene Island Pipeline Spill , 2009 (dispersant)  T/V Krymsk Oil Spill , 2009

Comparing the Potential of Multispectral and Hyperspectral Data for Monitoring Oil Spill Impact.

PubMed

Khanna, Shruti; Santos, Maria J; Ustin, Susan L; Shapiro, Kristen; Haverkamp, Paul J; Lay, Mui

2018-02-12

Oil spills from offshore drilling and coastal refineries often cause significant degradation of coastal environments. Early oil detection may prevent losses and speed up recovery if monitoring of the initial oil extent, oil impact, and recovery are in place. Satellite imagery data can provide a cost-effective alternative to expensive airborne imagery or labor intensive field campaigns for monitoring effects of oil spills on wetlands. However, these satellite data may be restricted in their ability to detect and map ecosystem recovery post-spill given their spectral measurement properties and temporal frequency. In this study, we assessed whether spatial and spectral resolution, and other sensor characteristics influence the ability to detect and map vegetation stress and mortality due to oil. We compared how well three satellite multispectral sensors: WorldView2, RapidEye and Landsat EMT+, match the ability of the airborne hyperspectral AVIRIS sensor to map oil-induced vegetation stress, recovery, and mortality after the DeepWater Horizon oil spill in the Gulf of Mexico in 2010. We found that finer spatial resolution (3.5 m) provided better delineation of the oil-impacted wetlands and better detection of vegetation stress along oiled shorelines in saltmarsh wetland ecosystems. As spatial resolution become coarser (3.5 m to 30 m) the ability to accurately detect and map stressed vegetation decreased. Spectral resolution did improve the detection and mapping of oil-impacted wetlands but less strongly than spatial resolution, suggesting that broad-band data may be sufficient to detect and map oil-impacted wetlands. AVIRIS narrow-band data performs better detecting vegetation stress, followed by WorldView2, RapidEye and then Landsat 15 m (pan sharpened) data. Higher quality sensor optics and higher signal-to-noise ratio (SNR) may also improve detection and mapping of oil-impacted wetlands; we found that resampled coarser resolution AVIRIS data with higher SNR performed better than either of the three satellite sensors. The ability to acquire imagery during certain times (midday, low tide, etc.) or a certain date (cloud-free, etc.) is also important in these tidal wetlands; WorldView2 imagery captured at high-tide detected a narrower band of shoreline affected by oil likely because some of the impacted wetland was below the tideline. These results suggest that while multispectral data may be sufficient for detecting the extent of oil-impacted wetlands, high spectral and spatial resolution, high-quality sensor characteristics, and the ability to control time of image acquisition may improve assessment and monitoring of vegetation stress and recovery post oil spills.

Comparing the Potential of Multispectral and Hyperspectral Data for Monitoring Oil Spill Impact

PubMed Central

Santos, Maria J.; Ustin, Susan L.; Haverkamp, Paul J.; Lay, Mui

2018-01-01

Oil spills from offshore drilling and coastal refineries often cause significant degradation of coastal environments. Early oil detection may prevent losses and speed up recovery if monitoring of the initial oil extent, oil impact, and recovery are in place. Satellite imagery data can provide a cost-effective alternative to expensive airborne imagery or labor intensive field campaigns for monitoring effects of oil spills on wetlands. However, these satellite data may be restricted in their ability to detect and map ecosystem recovery post-spill given their spectral measurement properties and temporal frequency. In this study, we assessed whether spatial and spectral resolution, and other sensor characteristics influence the ability to detect and map vegetation stress and mortality due to oil. We compared how well three satellite multispectral sensors: WorldView2, RapidEye and Landsat EMT+, match the ability of the airborne hyperspectral AVIRIS sensor to map oil-induced vegetation stress, recovery, and mortality after the DeepWater Horizon oil spill in the Gulf of Mexico in 2010. We found that finer spatial resolution (3.5 m) provided better delineation of the oil-impacted wetlands and better detection of vegetation stress along oiled shorelines in saltmarsh wetland ecosystems. As spatial resolution become coarser (3.5 m to 30 m) the ability to accurately detect and map stressed vegetation decreased. Spectral resolution did improve the detection and mapping of oil-impacted wetlands but less strongly than spatial resolution, suggesting that broad-band data may be sufficient to detect and map oil-impacted wetlands. AVIRIS narrow-band data performs better detecting vegetation stress, followed by WorldView2, RapidEye and then Landsat 15 m (pan sharpened) data. Higher quality sensor optics and higher signal-to-noise ratio (SNR) may also improve detection and mapping of oil-impacted wetlands; we found that resampled coarser resolution AVIRIS data with higher SNR performed better than either of the three satellite sensors. The ability to acquire imagery during certain times (midday, low tide, etc.) or a certain date (cloud-free, etc.) is also important in these tidal wetlands; WorldView2 imagery captured at high-tide detected a narrower band of shoreline affected by oil likely because some of the impacted wetland was below the tideline. These results suggest that while multispectral data may be sufficient for detecting the extent of oil-impacted wetlands, high spectral and spatial resolution, high-quality sensor characteristics, and the ability to control time of image acquisition may improve assessment and monitoring of vegetation stress and recovery post oil spills. PMID:29439504

Measuring ignitability for in situ burning of oil spills weathered under Arctic conditions: from laboratory studies to large-scale field experiments.

PubMed

Fritt-Rasmussen, Janne; Brandvik, Per Johan

2011-08-01

This paper compares the ignitability of Troll B crude oil weathered under simulated Arctic conditions (0%, 50% and 90% ice cover). The experiments were performed in different scales at SINTEF's laboratories in Trondheim, field research station on Svalbard and in broken ice (70-90% ice cover) in the Barents Sea. Samples from the weathering experiments were tested for ignitability using the same laboratory burning cell. The measured ignitability from the experiments in these different scales showed a good agreement for samples with similar weathering. The ice conditions clearly affected the weathering process, and 70% ice or more reduces the weathering and allows a longer time window for in situ burning. The results from the Barents Sea revealed that weathering and ignitability can vary within an oil slick. This field use of the burning cell demonstrated that it can be used as an operational tool to monitor the ignitability of oil spills. Copyright © 2011 Elsevier Ltd. All rights reserved.

Review of oil and HNS accidental spills in Europe: identifying major environmental monitoring gaps and drawing priorities.

PubMed

Neuparth, T; Moreira, S M; Santos, M M; Reis-Henriques, M A

2012-06-01

The European Atlantic area has been the scene of a number of extensive shipping incidents with immediate and potential long-term impacts to marine ecosystems. The occurrence of accidental spills at sea requires an effective response that must include a well executed monitoring programme to assess the environmental contamination and damage of the affected marine habitats. Despite a number of conventions and protocols developed by international and national authorities that focused on the preparedness and response to oil and HNS spills, much remains to be done, particularly in relation to the effectiveness of the environmental monitoring programmes implemented after oil and HNS spills. Hence, the present study reviews the status of the environmental monitoring programmes established following the major spill incidents over the last years in European waters, aiming at identifying the key monitoring gaps and drawing priorities for an effective environmental monitoring of accidental spills. Copyright © 2012 Elsevier Ltd. All rights reserved.

Environmental effects of the Deepwater Horizon oil spill: A review.

PubMed

Beyer, Jonny; Trannum, Hilde C; Bakke, Torgeir; Hodson, Peter V; Collier, Tracy K

2016-09-15

The Deepwater Horizon oil spill constituted an ecosystem-level injury in the northern Gulf of Mexico. Much oil spread at 1100-1300m depth, contaminating and affecting deepwater habitats. Factors such as oil-biodegradation, ocean currents and response measures (dispersants, burning) reduced coastal oiling. Still, >2100km of shoreline and many coastal habitats were affected. Research demonstrates that oiling caused a wide range of biological effects, although worst-case impact scenarios did not materialize. Biomarkers in individual organisms were more informative about oiling stress than population and community indices. Salt marshes and seabird populations were hard hit, but were also quite resilient to oiling effects. Monitoring demonstrated little contamination of seafood. Certain impacts are still understudied, such as effects on seagrass communities. Concerns of long-term impacts remain for large fish species, deep-sea corals, sea turtles and cetaceans. These species and their habitats should continue to receive attention (monitoring and research) for years to come. Copyright © 2016 Elsevier Ltd. All rights reserved.

[Analysis on oil fume particles in catering industry cooking emission].

PubMed

Tan, De-Sheng; Kuang, Yuan-Cheng; Liu, Xin; Dai, Fei-Hong

2012-06-01

By measuring the particulate matter of oil fume which is over 10 microm or below 10 microm separately and using microradiography and Electrical Low Pressure Impactor (ELPI), it is found out the distributing characteristic of oil fume particles in catering industry cooking emission. The result shows that the diameter of the oil fume particles which was sedimentated in the kitchen is between 10-400 microm, the concentration peak value is between 10-100 microm. The diameter of oil fume aerosol is mostly smaller than 1 microm, while the concentration peak value is between 0.063-0.109 microm. In addition, the mass concentration peak value is between 6.560-9.990 microm. Through the analysis to the physical characteristics of oil fume from catering industry cooking emissions, the eigenvalue of the oil fume has been found and the feature matter for monitoring the oil fume has been discovered to provide a reasonable standard for controlling and monitoring the catering industry cooking emission.

Revealing the properties of oils from their dissolved hydrocarbon compounds in water with an integrated sensor array system.

PubMed

Qi, Xiubin; Crooke, Emma; Ross, Andrew; Bastow, Trevor P; Stalvies, Charlotte

2011-09-21

This paper presents a system and method developed to identify a source oil's characteristic properties by testing the oil's dissolved components in water. Through close examination of the oil dissolution process in water, we hypothesise that when oil is in contact with water, the resulting oil-water extract, a complex hydrocarbon mixture, carries the signature property information of the parent oil. If the dominating differences in compositions between such extracts of different oils can be identified, this information could guide the selection of various sensors, capable of capturing such chemical variations. When used as an array, such a sensor system can be used to determine parent oil information from the oil-water extract. To test this hypothesis, 22 oils' water extracts were prepared and selected dominant hydrocarbons analyzed with Gas Chromatography-Mass Spectrometry (GC-MS); the subsequent Principal Component Analysis (PCA) indicates that the major difference between the extract solutions is the relative concentration between the volatile mono-aromatics and fluorescent polyaromatics. An integrated sensor array system that is composed of 3 volatile hydrocarbon sensors and 2 polyaromatic hydrocarbon sensors was built accordingly to capture the major and subtle differences of these extracts. It was tested by exposure to a total of 110 water extract solutions diluted from the 22 extracts. The sensor response data collected from the testing were processed with two multivariate analysis tools to reveal information retained in the response patterns of the arrayed sensors: by conducting PCA, we were able to demonstrate the ability to qualitatively identify and distinguish different oil samples from their sensor array response patterns. When a supervised PCA, Linear Discriminate Analysis (LDA), was applied, even quantitative classification can be achieved: the multivariate model generated from the LDA achieved 89.7% of successful classification of the type of the oil samples. By grouping the samples based on the level of viscosity and density we were able to reveal the correlation between the oil extracts' sensor array responses and their original oils' feature properties. The equipment and method developed in this study have promising potential to be readily applied in field studies and marine surveys for oil exploration or oil spill monitoring.

Exxon Valdez Oil Spill Restoration Project final report: Monitoring for evaluation of recovery and restoration of injured nearshore resources

USGS Publications Warehouse

Ballachey, Brenda E.; Bodkin, James L.; Kloecker, Kimberly A.; Dean, Tom; Colettie, Heather A

2015-01-01

In 2012, we completed three consecutive years of full field sampling in WPWS for EVOS Restoration Project 10100750. Nearshore monitoring was conducted in collaboration with the NPS SWAN I&M program and, beginning in 2012, as part of the EVOSTC GWA program. Data collection was done in accordance with standard operating procedures set forth to monitor marine water chemistry and quality, marine intertidal invertebrates, kelps and seagrasses, marine birds, black oystercatchers, and sea otters. Summer sampling in 2012 represented the fourth year of sampling in WPWS (an initial year of sampling was done in WPWS in 2007; EVOS Restoration Project 070750). Based on our monitoring of nearshore species in WPWS, and comparisons of data from WPWS and other areas within the Gulf of Alaska, we have no evidence of continued injury to biological resources at the spatial scales we are monitoring. A key finding is that recovery of the sea otter population is no longer constrained by exposure to lingering oil; this is consistent with related EVOSTC studies on harlequin ducks (Restoration Project 12120114-Q). We anticipate continued annual nearshore monitoring in WPWS and at KATM and KEFJ under GWA, with data summaries and analyses including all three areas to provide a larger spatial and temporal context to the understanding of processes and patterns in nearshore ecosystems of the GOA which were impacted by the EVOS of 1989.

Microbial diversity of an oil-water processing site and its associated oil field: the possible role of microorganisms as information carriers from oil-associated environments.

PubMed

van der Kraan, Geert M; Bruining, Johannes; Lomans, Bart P; van Loosdrecht, Mark C M; Muyzer, Gerard

2010-03-01

The phylogenetic diversity of Bacteria and Archaea in water retrieved from a Dutch oil field and units of the associated oil-water separation site were determined using two culture-independent methods. Denaturing gradient gel electrophoresis of PCR-amplified 16S rRNA gene fragments was used to scan the microbial diversity in (1) the oil-water emulsion produced, (2) two different oil-water separator tanks, (3) a wash tank and (4) a water injector. Longer 16S rRNA gene fragments were amplified, cloned and sequenced to determine the diversity in more detail. One of the questions addressed was whether the detected microorganisms could serve as indicators for the environments from which they were retrieved. It was observed that the community found in the production water resembled those reported previously in oil reservoirs, indicating that these ecosystems harbor specific microbial communities. It was shown that changes, like a decrease in temperature, cause a distinctive shift in these communities. The addition of SO(3)(2-) to the wash tank as ammonium bisulphite, used in the oil industry to scavenge oxygen, resulted in a complete community change, giving rise to an unwanted sulphate-reducing community. The fact that these changes in the community can be linked to changes in their environment might indicate that these tools can be used for the monitoring of changing conditions in oil reservoirs upon, for example, water flooding.

30 CFR 250.270 - What decisions will MMS make on the DPP or DOCD and within what timeframe?

Code of Federal Regulations, 2011 CFR

2011-07-01

..., REGULATION, AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Plans and Information Review and Decision Process for the Dpp Or Docd § 250.270... provide monitoring information. (2) Require you to modify your proposed DPP or DOCD It fails to make...

30 CFR 550.270 - What decisions will BOEM make on the DPP or DOCD and within what timeframe?

Code of Federal Regulations, 2014 CFR

2014-07-01

... MANAGEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Plans and Information Review and Decision Process for the Dpp Or Docd § 550.270 What decisions... provide monitoring information. (2) Require you to modify your proposed DPP or DOCD, It fails to make...

30 CFR 250.270 - What decisions will MMS make on the DPP or DOCD and within what timeframe?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Plans and Information Review and Decision Process for the Dpp Or Docd § 250.270 What decisions will MMS make... decision and may require you to meet certain conditions, including those to provide monitoring information...

Health effects research in direct coal liquefaction. Studies of H-coal distillates: Phase I. PDU samples - the effects of hydrotreatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Epler, J.L.; Fry, R.J.M.; Larimer, F.W.

1981-11-01

A multi-divisional effort aimed at the integrated assessment of the health and environmental effects of various coal conversion and shale oil technologies is being carried out. The feasibility of using health effects bioassays to predict the potential biohazard of various H-Coal derived test materials is examined in a coupled chemical and biological approach. The primary focus of the research is the use of preliminary chemical characterizations and preparation for bioassay, followed by testing in short-term assays in order to rapidly ascertain the potential biohazard. Mammalian toxicological assays parallel the testing. Raw and hydrotreated product liquids from process development units ofmore » H-Coal and the pilot plant solvent refined coal process were examined for acute toxicity monitored as population growth impairment of Tetrahymena exposed to aqueous extracts and for mutagenic activity monitored as revertants of Salmonella exposed to metabolically activated chemical class fractions. Medium to high severity hydrotreatment appears to be an effective means of reducing biological activity, presumably by reducing the aromaticity and heteroatom content. Five basic mammalian, acute toxicity tests have been conducted with selected H-coal samples and shale oil derivatives. The data show that H-Coal samples are moderately toxic whereas the toxicity of shale oil derived products is slight and comparable to samples obtained from naturally occurring petroleums. No overt skin or eye toxicity was found. The present data reveal that coal-derived distillates generated by the H-coal process are highly carcinogenic to mouse skin. An extreme form of neurotoxicity associated with dermal exposure to one of the lighter, minimally carcinogenic, materials was noted. (DMC)« less

Solid fat content measurement as a substitute for total polar compound analysis

USDA-ARS?s Scientific Manuscript database

Monitoring of oxidative degradation in frying oils is essential for determining an appropriate discard time. The most reliable method for monitoring the extent of oxidation in edible oils is the determination of total polar compounds. However, this method is time-consuming and not practical to execu...

Solid fat content measurement as an alternative to total polar compound analysis

USDA-ARS?s Scientific Manuscript database

Monitoring of oxidative degradation in frying oils is essential for determining an appropriate discard time. The most reliable method for monitoring the extent of oxidation in edible oils is the determination of total polar compounds (TPC). However, this method is time-consuming and not practical ...

Indicators used to monitor subsurface oil during the Deepwater Horizon Event

EPA Science Inventory

The Gulf of Mexico Deepwater Horizon oil spill was the largest accidental marine spill in the history of the petroleum industry. The spill was also unprecedented due to the extreme depth of the wellhead leak within the ocean, posing unique challenges to the monitoring efforts, w...

Dinosterane and other steroidal hydrocarbons of dinoflagellate origin in sediments and petroleum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Summons, R.E.; Volkman, J.K.; Boreham, C.J.

1987-11-01

The steroidal alkanes of a selection of sediments and oils have been examined by GC-MS with multiple metastable reaction monitoring. Specific 4-methyl sterane isomers have been identified by comparison with isomers synthesized from sterols isolated from dinoflagellates. An immature marine oil shale and two mature marine oils of Triassic to early Cretaceous age contained high concentrations of C{sub 30} steranes comprising desmethyl, 24-ethyl-4{alpha}-methylcholestane and 4{alpha},23,24-trimethylcholestane (dinosterane) isomers. An immature non-marine oil shale and two non-marine oils of Cretaceous to Eocene age contained stereoisomers of 24-ethyl-4{alpha}-methylcholestane as the dominant C{sub 30} steranes. Reaction monitoring analyses in GC-MS are particularly suited tomore » unravelling complex distributions of homologous and stereoisomeric steroids encountered in oils and their source rocks.« less

Polarimetric SAR Models for Oil Fields Monitoring in China Seas

NASA Astrophysics Data System (ADS)

Buono, A.; Nunziata, F.; Li, X.; Wei, Y.; Ding, X.

2014-11-01

In this study, physical-based models for polarimetric Synthetic Aperture Radar (SAR) oil fields monitoring are proposed. They all share a physical rationale relying on the different scattering mechanisms that characterize a free sea surface, an oil slick-covered sea surface, and a metallic target. In fact, sea surface scattering is well modeled by a Bragg-like behaviour, while a strong departure from Bragg scattering is in place when dealing with oil slicks and targets. Furthermore, the proposed polarimetric models aim at addressing simultaneously target and oil slick detection, providing useful extra information with respect to single-pol SAR data in order to approach oil discrimination and classification. Experiments undertaken over East and South China Sea from actual C-band RadarSAT-2 full-pol SAR data witness the soundness of the proposed rationale.

Polarimetric SAR Models for Oil Fields Monitoring in China Seas

NASA Astrophysics Data System (ADS)

Buono, A.; Nunziata, F.; Li, X.; Wei, Y.; Ding, X.

2014-11-01

In this study, physical-based models for polarimetric Synthetic Aperture Radar (SAR) oil fields monitoring are proposed. They all share a physical rationale relying on the different scattering mechanisms that characterize a free sea surface, an oil slick-covered sea surface, and a metallic target. In fact, sea surface scattering is well modeled by a Bragg-like behaviour, while a strong departure from Bragg scattering is in place when dealing with oil slicks and targets. Furthermore, the proposed polarimetric models aim at addressing simultaneously target and oil slick detection, providing useful extra information with respect to single-pol SAR data in order to approach oil discrimination and classification.Experiments undertaken over East and South China Sea from actual C-band RadarSAT-2 full-pol SAR data witness the soundness of the proposed rationale.

Using normal ranges for interpreting results of monitoring and tiering to guide future work: A case study of increasing polycyclic aromatic compounds in lake sediments from the Cold Lake oil sands (Alberta, Canada) described in Korosi et al. (2016).

PubMed

Munkittrick, Kelly R; Arciszewski, Tim J

2017-12-01

Since the publishing of the Kelly et al. papers (2009, 2010) describing elevated contaminants in snow near the Alberta oil sands, there has been a significant expansion of monitoring efforts, enhanced by $50M a year contributed by industry to a regional Joint Oil Sands Monitoring (JOSM) program. In parallel to the intensification of research and monitoring efforts, including expansion of measured indicators, techniques for chemical analysis have also become more sensitive. Both factors contribute to the increased sensitivity and power, and improve our capacity to detect any change. The increase in capability requires a counterbalance to account for trivial change. This can be done using an interpretative approach that requires contextualization of differences to meaningfully inform environmental monitoring programs and provide focus for action. Experience obtained through 25 years of involvement with Canada's Environmental Effects Monitoring (EEM) program has shown that a tiered program informed by triggers can provide the context to make decisions about monitoring priorities. Here we provide a potential interpretation framework using a case study around the Korosi et al. (2016) study which found recent increases in alkylated polycyclic aromatic compounds (aPACs) in the Cold Lake in situ oil sands area. Public contaminant profiles from the JOSM studies in the oil sands region are used to evaluate the changes using an interpretation framework based on estimated normal ranges using existing data for site-specific, local and regional (distant) levels that was modelled after the tiered Canadian EEM design. Copyright © 2017 Elsevier Ltd. All rights reserved.

Research on calibration method of downhole optical fiber temperature measurement and its application in SAGD well

NASA Astrophysics Data System (ADS)

Lu, Zhiwei; Han, Li; Hu, Chengjun; Pan, Yong; Duan, Shengnan; Wang, Ningbo; Li, Shijian; Nuer, Maimaiti

2017-10-01

With the development of oil and gas fields, the accuracy and quantity requirements of real-time dynamic monitoring data needed for well dynamic analysis and regulation are increasing. Permanent, distributed downhole optical fiber temperature and pressure monitoring and other online real-time continuous data monitoring has become an important data acquisition and transmission technology in digital oil field and intelligent oil field construction. Considering the requirement of dynamic analysis of steam chamber developing state in SAGD horizontal wells in F oil reservoir in Xinjiang oilfield, it is necessary to carry out real-time and continuous temperature monitoring in horizontal section. Based on the study of the principle of optical fiber temperature measurement, the factors that cause the deviation of optical fiber temperature sensing are analyzed, and the method of fiber temperature calibration is proposed to solve the problem of temperature deviation. Field application in three wells showed that it could attain accurate measurement of downhole temperature by temperature correction. The real-time and continuous downhole distributed fiber temperature sensing technology has higher application value in the reservoir management of SAGD horizontal wells. It also has a reference for similar dynamic monitoring in reservoir production.

Tracking and Monitoring Oil Slicks Using remote Sensing

NASA Astrophysics Data System (ADS)

Klemas, V. V.

2011-12-01

Tracking and Monitoring Oil Slicks Using Remote Sensing Victor Klemas, Ph.D. , College of Earth, Ocean and Environment, University of Delaware, Newark, DE 19716 Abstract Oil spills can harm marine life in the ocean, estuaries and wetlands. To limit the damage by a spill and facilitate cleanup efforts, emergency managers need information on spill location, size and extent, direction and speed of oil movement, wind, current, and wave information for predicting oil drift and dispersion. The main operational data requirements are fast turn-around time and frequent imaging to monitor the dynamics of the spill. Radar and multispectral remote sensors on satellites and aircraft meet most of these requirements by tracking the spilled oil at various resolutions, over wide areas and at frequent intervals. They also provide key inputs to drift prediction models and facilitate targeting of skimming and booming efforts. Satellite data are frequently supplemented by information provided by aircraft, ships and remotely controlled underwater robots. The Sea Princess tanker grounding off the coast of Wales and the explosion on the Deepwater Horizon rig in the Gulf of Mexico provide two representative, yet different, scenarios for evaluating the effectiveness of remote sensors during oil spill emergencies. Session NH17: Remote Sensing of Natural Hazards Session Chair: Ramesh P. Singh Sponsor: Natural Hazards (NH)

Use of Acetate, Propionate, and Butyrate for Reduction of Nitrate and Sulfate and Methanogenesis in Microcosms and Bioreactors Simulating an Oil Reservoir

PubMed Central

Shen, Yin; An, Dongshan; Voordouw, Gerrit

2017-01-01

ABSTRACT Acetate, propionate, and butyrate (volatile fatty acids [VFA]) occur in oil field waters and are frequently used for microbial growth of oil field consortia. We determined the kinetics of use of these VFA components (3 mM each) by an anaerobic oil field consortium in microcosms containing 2 mM sulfate and 0, 4, 6, 8, or 13 mM nitrate. Nitrate was reduced first, with a preference for acetate and propionate. Sulfate reduction then proceeded with propionate (but not butyrate) as the electron donor, whereas the fermentation of butyrate (but not propionate) was associated with methanogenesis. Microbial community analyses indicated that Paracoccus and Thauera (Paracoccus-Thauera), Desulfobulbus, and Syntrophomonas-Methanobacterium were the dominant taxa whose members catalyzed these three processes. Most-probable-number assays showed the presence of up to 107/ml of propionate-oxidizing sulfate-reducing bacteria (SRB) in waters from the Medicine Hat Glauconitic C field. Bioreactors with the same concentrations of sulfate and VFA responded similarly to increasing concentrations of injected nitrate as observed in the microcosms: sulfide formation was prevented by adding approximately 80% of the nitrate dose needed to completely oxidize VFA to CO2 in both. Thus, this work has demonstrated that simple time-dependent observations of the use of acetate, propionate, and butyrate for nitrate reduction, sulfate reduction, and methanogenesis in microcosms are a good proxy for these processes in bioreactors, monitoring of which is more complex. IMPORTANCE Oil field volatile fatty acids acetate, propionate, and butyrate were specifically used for nitrate reduction, sulfate reduction, and methanogenic fermentation. Time-dependent analyses of microcosms served as a good proxy for these processes in a bioreactor, mimicking a sulfide-producing (souring) oil reservoir: 80% of the nitrate dose required to oxidize volatile fatty acids to CO2 was needed to prevent souring in both. Our data also suggest that propionate is a good substrate to enumerate oil field SRB. PMID:28130297

Mesocosm study on weathering characteristics of Iranian Heavy crude oil with and without dispersants.

PubMed

Joo, Changkyu; Shim, Won Joon; Kim, Gi Beum; Ha, Sung Yong; Kim, Moonkoo; An, Joon Geon; Kim, Eunsic; Kim, Beom; Jung, Seung Won; Kim, Young-Ok; Yim, Un Hyuk

2013-03-15

The environmental fate of Iranian Heavy crude oil (IHC) with and without an added oil spill dispersant (OSD) has been studied using a 1000 kL capacity in situ mesocosm. Physical weathering and chemical composition changes of the oil were monitored for 77 days. Compound-specific effects of the OSD could be observed as changes over time in the content of the total petroleum hydrocarbon (TPH), unresolved complex mixture (UCM), alkanes, polycyclic aromatic hydrocarbons (PAHs), hopanes and steranes in the oil. As oil weathers, most hydrocarbons showed a rapid decreasing phase followed by a slowdown and stabilization. Recalcitrant biomarkers, however, showed a different trend. An increase in hydrocarbon contents in the form of UCM occurred after OSD treatment. The enhanced solubility of the low molecular weight PAHs by the OSD decreased the half-life of the alkylated PAHs in the OD. After 77 days of exposure at the sea surface, both the oils with and without the OSD exhibited moderate weathering. Most of the source diagnostic indices maintained their source information, and the weathering indices indicated that evaporation, dissolution, and dispersion were the major weathering processes. The mass balance of the weathered oil was calculated using laboratory and mesocosm data and the results demonstrate the importance of using a mesocosm for the production of environmentally realistic data. Copyright © 2013 Elsevier B.V. All rights reserved.

Geological hazard monitoring system in Georgia

NASA Astrophysics Data System (ADS)

Gaprindashvili, George

2017-04-01

Georgia belongs to one of world's most complex mountainous regions according to the scale and frequency of Geological processes and damage caused to population, farmlands, and Infrastructure facilities. Geological hazards (landslide, debrisflow/mudflow, rockfall, erosion and etc.) are affecting many populated areas, agricultural fields, roads, oil and gas pipes, high-voltage electric power transmission towers, hydraulic structures, and tourist complexes. Landslides occur almost in all geomorphological zones, resulting in wide differentiation in the failure types and mechanisms and in the size-frequency distribution. In Georgia, geological hazards triggered by: 1. Activation of highly intense earthquakes; 2. Meteorological events provoking the disaster processes on the background of global climatic change; 3. Large-scale Human impact on the environment. The prediction and monitoring of Geological Hazards is a very wide theme, which involves different researchers from different spheres. Geological hazard monitoring is essential to prevent and mitigate these hazards. In past years in Georgia several monitoring system, such as Ground-based geodetic techniques, Debrisflow Early Warning System (EWS) were installed on high sensitive landslide and debrisflow areas. This work presents description of Geological hazard monitoring system in Georgia.

Assessment of space sensors for ocean pollution monitoring

NASA Technical Reports Server (NTRS)

Alvarado, U. R.; Tomiyasu, K.; Gulatsi, R. L.

1980-01-01

Several passive and active microwave, as well as passive optical remote sensors, applicable to the monitoring of oil spills and waste discharges at sea, are considered. The discussed types of measurements relate to: (1) spatial distribution and properties of the pollutant, and (2) oceanic parameters needed to predict the movement of the pollutants and their impact upon land. The sensors, operating from satellite platforms at 700-900 km altitudes, are found to be useful in mapping the spread of oil in major oil spills and in addition, can be effective in producing wind and ocean parameters as inputs to oil trajectory and dispersion models. These capabilities can be used in countermeasures.

Spiral Bevel Gear Damage Detection Using Decision Fusion Analysis

NASA Technical Reports Server (NTRS)

Dempsey, Paula J.; Handschuh, Robert F.; Afjeh, Abdollah A.

2002-01-01

A diagnostic tool for detecting damage to spiral bevel gears was developed. Two different monitoring technologies, oil debris analysis and vibration, were integrated using data fusion into a health monitoring system for detecting surface fatigue pitting damage on gears. This integrated system showed improved detection and decision-making capabilities as compared to using individual monitoring technologies. This diagnostic tool was evaluated by collecting vibration and oil debris data from fatigue tests performed in the NASA Glenn Spiral Bevel Gear Fatigue Rigs. Data was collected during experiments performed in this test rig when pitting damage occurred. Results show that combining the vibration and oil debris measurement technologies improves the detection of pitting damage on spiral bevel gears.

Timely detection and monitoring of oil leakage by satellite optical data.

NASA Astrophysics Data System (ADS)

Grimaldi, C. S. L.; Coviello, I.; Lacava, T.; Pergola, N.; Tramutoli, V.

2009-04-01

Sea oil pollution can derive from different sources. Accidental release of oil into the oceans caused by "human errors" (tankers collisions and/or shipwrecks) or natural hazards (hurricanes, landslides, earthquakes) have remarkable ecological impact on maritime and coastal environments. Katrina Hurricane, for example, hitting oil and gas infrastructures off USA coasts caused the destruction of more than 100 platforms and the release into the sea of more than 10,000 gallons of crude oil. In order to reduce the environmental impact of such kind of technological hazards, timely detection and continuously updated information are fundamental. Satellite remote sensing can give a significant contribution in such a direction. Nowadays, SAR (Synthetic Aperture Radar) technology has been recognized as the most efficient for oil spill detection and mapping, thanks to the high spatial resolution and all-time/weather capability of the present operational sensors. Anyway, due to their current revisiting cycles, SAR systems cannot be profitably used for a rapid detection and for a continuous and near real-time monitoring of these phenomena. Until COSMO-Skymed SAR constellation, that will be able to improve SAR observational frequency, will not be fully operational, passive optical sensors on board meteorological satellites, thanks to their high temporal resolution, may represent a suitable alternative for early detection and continuous monitoring of oil spills, provided that adequate and reliable data analysis techniques exist. Recently, an innovative technique for oil spill detection and monitoring, based on the general Robust Satellite Techniques (RST) approach, has been proposed. It exploits the multi-temporal analysis of optical data acquired by both AVHRR (Advanced Very High Resolution Radiometer) and MODIS (Moderate Resolution Imaging Spectroradiometer) sensors in order to detect, automatically and timely, the presence of oil spill over the sea surface, trying to minimize the "false-detections" possibly caused by spurious effects (e.g. clouds). In this paper, preliminary results obtained applying the proposed methodology to different test-cases are shown and discussed.

Phytonadione Content in Branded Intravenous Fat Emulsions.

PubMed

Forchielli, Maria Luisa; Conti, Matteo; Motta, Roberto; Puggioli, Cristina; Bersani, Germana

2017-03-01

Intravenous fat emulsions (IVFE) with different fatty acid compositions contain vitamin E as a by-product of vegetable and animal oil during the refining processes. Likewise, other lipid-soluble vitamins may be present in IVFE. No data, however, exist about phytonadione (vitamin K1) concentration in IVFE information leaflets. Therefore, our aim was to evaluate the phytonadione content in different IVFE. Analyses were carried out in triplicate on 6 branded IVFE as follows: 30% soybean oil (100%), 20% olive-soybean oil (80%-20%), 20% soybean-medium-chain triglycerides (MCT) coconut oil (50%-50%), 20% soybean-olive-MCT-fish oil (30%-25%-30%-15%), 20% soybean-MCT-fish oil (40%-50%-10%), and 10% pure fish oil (100%). Phytonadione was analyzed and quantified by a quali-quantitative liquid chromatography-mass spectrometry (LC-MS) method after its extraction from the IVFE by an isopropyl alcohol-hexane mixture, reverse phase-liquid chromatography, and specific multiple-reaction monitoring for phytonadione and vitamin d3 (as internal standard). This method was validated through specificity, linearity, and accuracy. Average vitamin K1 content was 500, 100, 90, 100, 95, and 70 µg/L in soybean oil, olive-soybean oil, soybean-MCT coconut oil, soybean-olive-MCT-fish oil, soybean-MCT-fish oil, and pure fish oil intravenous lipid emulsions (ILEs), respectively. The analytical LC-MS method was extremely effective in terms of specificity, linearity ( r = 0.99), and accuracy (coefficient of variation <5%). Phytonadione is present in IVFE, and its intake varies according to IVFE type and the volume administered. It can contribute to daily requirements and become clinically relevant when simultaneously infused with multivitamins during long-term parenteral nutrition. LC-MS seems adequate in assessing vitamin K1 intake in IVFE.

30 CFR 250.457 - What equipment is required to monitor drilling fluids?

Code of Federal Regulations, 2011 CFR

2011-07-01

... ENFORCEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Drilling Operations Drilling Fluid Requirements § 250.457 What equipment is required... 30 Mineral Resources 2 2011-07-01 2011-07-01 false What equipment is required to monitor drilling...

Monitoring Mediterranean marine pollution using remote sensing and hydrodynamic modelling

NASA Astrophysics Data System (ADS)

La Loggia, Goffredo; Capodici, Fulvio; Ciraolo, Giuseppe; Drago, Aldo; Maltese, Antonino

2011-11-01

Human activities contaminate both coastal areas and open seas, even though impacts are different in terms of pollutants, ecosystems and recovery time. In particular, Mediterranean offshore pollution is mainly related to maritime transport of oil, accounting for 25% of the global maritime traffic and, during the last 25 years, for nearly 7% of the world oil accidents, thus causing serious biological impacts on both open sea and coastal zone habitats. This paper provides a general review of maritime pollution monitoring using integrated approaches of remote sensing and hydrodynamic modeling; focusing on the main results of the MAPRES (Marine pollution monitoring and detection by aerial surveillance and satellite images) research project on the synergistic use of remote sensing, forecasting, cleanup measures and environmental consequences. The paper also investigates techniques of oil spill detection using SAR images, presenting the first results of "Monitoring of marine pollution due to oil slick", a COSMO-SkyMed funded research project where X-band SAR constellation images provided by the Italian Space Agency are used. Finally, the prospect of using real time observations of marine surface conditions is presented through CALYPSO project (CALYPSO-HF Radar Monitoring System and Response against Marine Oil Spills in the Malta Channel), partly financed by the EU under the Operational Programme Italia-Malta 2007-2013. The project concerns the setting up of a permanent and fully operational HF radar observing system, capable of recording surface currents (in real-time with hourly updates) in the stretch of sea between Malta and Sicily. A combined use of collected data and numerical models, aims to optimize intervention and response in the case of marine oil spills.

Crystallization using reverse micelles and water-in-oil microemulsion systems: the highly selective tool for the purification of organic compounds from complex mixtures.

PubMed

Kljajic, Alen; Bester-Rogac, Marija; Klobcar, Andrej; Zupet, Rok; Pejovnik, Stane

2013-02-01

The active pharmaceutical ingredient orlistat is usually manufactured using a semi-synthetic procedure, producing crude product and complex mixtures of highly related impurities with minimal side-chain structure variability. It is therefore crucial for the overall success of industrial/pharmaceutical application to develop an effective purification process. In this communication, we present the newly developed water-in-oil reversed micelles and microemulsion system-based crystallization process. Physiochemical properties of the presented crystallization media were varied through surfactants and water composition, and the impact on efficiency was measured through final variation of these two parameters. Using precisely defined properties of the dispersed water phase in crystallization media, a highly efficient separation process in terms of selectivity and yield was developed. Small-angle X-ray scattering, high-performance liquid chromatography, mass spectrometry, and scanning electron microscopy were used to monitor and analyze the separation processes and orlistat products obtained. Typical process characteristics, especially selectivity and yield in regard to reference examples, were compared and discussed. Copyright © 2012 Wiley Periodicals, Inc.

Fiber Bragg grating sensors in harsh environments: considerations and industrial monitoring applications

NASA Astrophysics Data System (ADS)

Méndez, Alexis

2017-06-01

Over the last few years, fiber optic sensors (FOS) have seen an increased acceptance and widespread use in industrial sensing and in structural monitoring in civil, aerospace, marine, oil & gas, composites and other applications. One of the most prevalent types in use today are fiber Bragg grating (FBG) sensors. Historically, FOS have been an attractive solution because of their EM immunity and suitability for use in harsh environments and rugged applications with extreme temperatures, radiation exposure, EM fields, high voltages, water contact, flammable atmospheres, or other hazards. FBG sensors have demonstrated that can operate reliably in many different harsh environment applications but proper type and fabrication process are needed, along with suitable packaging and installation procedure. In this paper, we review the impact that external factors and environmental conditions play on FBG's performance and reliability, and describe the appropriate sensor types and protection requirements suitable for a variety of harsh environment applications in industrial furnaces, cryogenic coolers, nuclear plants, maritime vessels, oil & gas wells, aerospace crafts, automobiles, and others.

Tracing Acetylene Dissolved in Transformer Oil by Tunable Diode Laser Absorption Spectrum.

PubMed

Ma, Guo-Ming; Zhao, Shu-Jing; Jiang, Jun; Song, Hong-Tu; Li, Cheng-Rong; Luo, Ying-Ting; Wu, Hao

2017-11-02

Dissolved gas analysis (DGA) is widely used in monitoring and diagnosing of power transformer, since the insulation material in the power transformer decomposes gases under abnormal operation condition. Among the gases, acetylene, as a symbol of low energy spark discharge and high energy electrical faults (arc discharge) of power transformer, is an important monitoring parameter. The current gas detection method used by the online DGA equipment suffers from problems such as cross sensitivity, electromagnetic compatibility and reliability. In this paper, an optical gas detection system based on TDLAS technology is proposed to detect acetylene dissolved in transformer oil. We selected a 1530.370 nm laser in the near infrared wavelength range to correspond to the absorption peak of acetylene, while using the wavelength modulation strategy and Herriott cell to improve the detection precision. Results show that the limit of detection reaches 0.49 ppm. The detection system responds quickly to changes of gas concentration and is easily to maintenance while has no electromagnetic interference, cross-sensitivity, or carrier gas. In addition, a complete detection process of the system takes only 8 minutes, implying a practical prospect of online monitoring technology.

Demulsification of dilute oil/water emulsions with organic electrolytes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jansson, M.; Pes, M.A.

1994-03-15

Tetraalkylammonium and tetraalkylphosphonium ions induce oil droplet coalescence in dilute oil/water emulsions stabilized by sodium dodecanoate. This was shown by dynamic light-scattering, monitoring oil droplet sizes, and kinetic measurements of oil droplet aggregation. A large ion size, a symmetrical ion geometry and a strongly interacting counterion were found to be important criteria for organic electrolytes to be efficient demulsifiers.

Real time monitoring of the minute dynamic variation at the crude oil-water interface.

PubMed

Duan, Ming; Ding, Ziling; Wang, Hu; Xiong, Yan

2018-02-21

Quantitative recording of the minute dynamic variation at an oil-water interface is always a great challenge. Dual polarization interferometry (DPI) presents an approach in monitoring the variations of mass, thickness, and density at the interface with high resolution. In this study, a planar crude oil-water interface was established by spin-coating on a DPI chip surface. Different concentrations of sodium dodecyl sulphate (SDS) and polyacrylamide (PAM) were injected into the interface. The absorption of free SDS molecules, in low concentrations, can be interpreted as a two-step absorption. With the existence of micelles in higher concentrations, the crude oil molecules tend to be taken away by the micelles. The absorptions of the polymers at the interface are different from SDS. The crude oil can hardly be taken away by the polymers. Instead, the hydrophobic segments of polymers insert into the oil film and hydrophilic groups stretch into the solution.

Determination of Component Contents of Blend Oil Based on Characteristics Peak Value Integration.

PubMed

Xu, Jing; Hou, Pei-guo; Wang, Yu-tian; Pan, Zhao

2016-01-01

Edible blend oil market is confused at present. It has some problems such as confusing concepts, randomly named, shoddy and especially the fuzzy standard of compositions and ratios in blend oil. The national standard fails to come on time after eight years. The basic reason is the lack of qualitative and quantitative detection of vegetable oils in blend oil. Edible blend oil is mixed by different vegetable oils according to a certain proportion. Its nutrition is rich. Blend oil is eaten frequently in daily life. Different vegetable oil contains a certain components. The mixed vegetable oil can make full use of their nutrients and make the nutrients more balanced in blend oil. It is conducive to people's health. It is an effectively way to monitor blend oil market by the accurate determination of single vegetable oil content in blend oil. The types of blend oil are known, so we only need for accurate determination of its content. Three dimensional fluorescence spectra are used for the contents in blend oil. A new method of data processing is proposed with calculation of characteristics peak value integration in chosen characteristic area based on Quasi-Monte Carlo method, combined with Neural network method to solve nonlinear equations to obtain single vegetable oil content in blend oil. Peanut oil, soybean oil and sunflower oil are used as research object to reconcile into edible blend oil, with single oil regarded whole, not considered each oil's components. Recovery rates of 10 configurations of edible harmonic oil is measured to verify the validity of the method of characteristics peak value integration. An effective method is provided to detect components content of complex mixture in high sensitivity. Accuracy of recovery rats is increased, compared the common method of solution of linear equations used to detect components content of mixture. It can be used in the testing of kinds and content of edible vegetable oil in blend oil for the food quality detection, and provide an effective reference for the creation of national standards.

Application of fluorescence and PARAFAC to assess vertical distribution of subsurface hydrocarbons and dispersant during the Deepwater Horizon oil spill.

PubMed

Mendoza, Wilson G; Riemer, Daniel D; Zika, Rod G

2013-05-01

We evaluated the use of excitation and emission matrix (EEM) fluorescence and parallel factorial analysis (PARAFAC) modeling techniques for monitoring crude oil components in the water column. Four of the seven derived PARAFAC loadings were associated with the Macondo crude oil components. The other three components were associated with the dispersant, an unresolved component and colored dissolved organic matter (CDOM). The fluorescence of the associated benzene and naphthalene-like components of crude oil exhibited a maximum at ∼1200 m. The maximum fluorescence of the component associated with the dispersant (i.e., Corexit EC9500A) was observed at the same depth. The plume observed at this depth was attributed to the dispersed crude oil from the Deepwater Horizon oil spill. Results demonstrate the application of EEM and PARAFAC to simultaneously monitor selected PAH, dispersant-containing and humic-like fluorescence components in the oil spill region in the Gulf of Mexico.

Environmental assessment of a crude-oil heater using staged air lances for NOx reduction. Volume 1. Technical results. Final report June 1981-November 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

DeRosier, R.

1984-07-01

This volume of the report gives emission results from field tests of a crude-oil process heater burning a combination of oil and refinery gas. The heater had been modified by adding a system for injecting secondary air to reduce NOx emissions. One test was conducted with the staged air system (low NOx), and the other, without (baseline). Tests included continuous monitoring of flue gas emissions and source assessment sampling system (SASS) sampling of the flue gas with subsequent laboratory analysis of the samples utilizing gas chromatography (GC), infrared spectrometry (IR), gas chromatography/mass spectroscopy (GC/MS), and low resolution mass spectrometry (SSMS)more » for trace metals. LRMS analysis suggested the presence of eight compound categories in the organic emissions during the baseline test and four in the low-NOx test.« less

Monitoring and mapping leaf area index of rubber and oil palm in small watershed area

NASA Astrophysics Data System (ADS)

Rusli, N.; Majid, M. R.

2014-02-01

Existing conventional methods to determine LAI are tedious and time consuming for implementation in small or large areas. Thus, raster LAI data which are available free were downloaded for 4697.60 km2 of Sungai Muar watershed area in Johor. The aim of this study is to monitor and map LAI changes of rubber and oil palm throughout the years from 2002 to 2008. Raster datasets of LAI value were obtained from the National Aeronautics and Space Administration (NASA) website of available years from 2002 to year 2008. These data, were mosaicked and subset utilizing ERDAS Imagine 9.2. Next, the LAI raster dataset was multiplied by a scale factor of 0.1 to derive the final LAI value. Afterwards, to determine LAI values of rubber and oil palms, the boundaries of each crop from land cover data of the years 2002, 2006 and 2008 were exploited to overlay with LAI raster dataset. A total of 5000 sample points were generated utilizing the Hawths Tool (extension in ARcGIS 9.2) within these boundaries area and utilized for extracting LAI value of oil palm and rubber. In integration, a wide range of literature review was conducted as a guideline to derive LAI value of oil palm and rubber which range from 0 to 6. The results show, an overall mean LAI value from year 2002 to 2008 as decremented from 4.12 to 2.5 due to land cover transition within these years. In 2002, the mean LAI value of rubber and oil palm is 2.65 and 2.53 respectively. Meanwhile in 2006, the mean LAI value for rubber and oil palm is 2.54 and 2.82 respectively. In 2008, the mean LAI value for both crops is 0.85 for rubber and 1.04 for oil palm. In conclusion, apart from the original function of LAI which is related to the growth and metabolism of vegetation, the changes of LAI values from year 2002 to 2008 also capable to explain the process of land cover changes in a watershed area.

Liquid volume monitoring based on ultrasonic sensor and Arduino microcontroller

NASA Astrophysics Data System (ADS)

Husni, M.; Siahaan, D. O.; Ciptaningtyas, H. T.; Studiawan, H.; Aliarham, Y. P.

2016-04-01

Incident of oil leakage and theft in oil tank often happens. To prevent it, the liquid volume insides the tank needs to be monitored continuously. Aim of the study is to calculate the liquid volume inside oil tank on any road condition and send the volume data and location data to the user. This research use some ultrasonic sensors (to monitor the fluid height), Bluetooth modules (to sent data from the sensors to the Arduino microcontroller), Arduino Microcontroller (to calculate the liquid volume), and also GPS/GPRS/GSM Shield module (to get location of vehicle and sent the data to the Server). The experimental results show that the accuracy rate of monitoring liquid volume inside tanker while the vehicle is in the flat road is 99.33% and the one while the vehicle is in the road with elevation angle is 84%. Thus, this system can be used to monitor the tanker position and the liquid volume in any road position continuously via web application to prevent illegal theft.

Methane rising from the Deep: Hydrates, Bubbles, Oil Spills, and Global Warming

NASA Astrophysics Data System (ADS)

Leifer, I.; Rehder, G. J.; Solomon, E. A.; Kastner, M.; Asper, V. L.; Joye, S. B.

2011-12-01

Elevated methane concentrations in near-surface waters and the atmosphere have been reported for seepage from depths of nearly 1 km at the Gulf of Mexico hydrate observatory (MC118), suggesting that for some methane sources, deepsea methane is not trapped and can contribute to atmospheric greenhouse gas budgets. Ebullition is key with important sensitivity to the formation of hydrate skins and oil coatings, high-pressure solubility, bubble size and bubble plume processes. Bubble ROV tracking studies showed survival to near thermocline depths. Studies with a numerical bubble propagation model demonstrated that consideration of structure I hydrate skins transported most methane only to mid-water column depths. Instead, consideration of structure II hydrates, which are stable to far shallower depths and appropriate for natural gas mixtures, allows bubbles to survive to far shallower depths. Moreover, model predictions of vertical methane and alkane profiles and bubble size evolution were in better agreement with observations after consideration of structure II hydrate properties as well as an improved implementation of plume properties, such as currents. These results demonstrate the importance of correctly incorporating bubble hydrate processes in efforts to predict the impact of deepsea seepage as well as to understand the fate of bubble-transported oil and methane from deepsea pipeline leaks and well blowouts. Application to the DWH spill demonstrated the importance of deepsea processes to the fate of spilled subsurface oil. Because several of these parameters vary temporally (bubble flux, currents, temperature), sensitivity studies indicate the importance of real-time monitoring data.

Response of captive, breeding mallards to oiled water

USGS Publications Warehouse

Custer, T.W.; Albers, P.H.

1980-01-01

Behavioral response of mallard ducks to Prudhoe Bay crude oil slicks on water basins. Water basins were oiled with either 5 or 100 ul of oil and monitored with time-lapse cameras for 24 hr before and after water treatment. Measured time of first entry and amount of time spent on the water.

Influence of deep frying on the unsaponifiable fraction of vegetable edible oils enriched with natural antioxidants.

PubMed

Orozco, Mara I; Priego-Capote, Feliciano; Luque de Castro, Maria D

2011-07-13

The influence of deep frying, mimicked by 20 heating cycles at 180 °C (each cycle from ambient temperature to 180 °C maintained for 5 min), on the unsaponifiable fraction of vegetable edible oils represented by three characteristic families of compounds (namely, phytosterols, aliphatic alcohols, and triterpenic compounds) has been studied. The target oils were extra virgin olive oil (with intrinsic content of phenolic antioxidants), refined sunflower oil enriched with antioxidant phenolic compounds isolated from olive pomace, refined sunflower oil enriched with an autoxidation inhibitor (dimethylpolysiloxane), and refined sunflower oil without enrichment. Monitoring of the target analytes as a function of both heating cycle and the presence of natural antioxidants was also evaluated by comparison of the profiles after each heating cycle. Identification and quantitation of the target compounds were performed by gas cromatography-mass spectrometry in single ion monitoring mode. Analysis of the heated oils revealed that the addition of natural antioxidants could be an excellent strategy to decrease degradation of lipidic components of the unsaponifiable fraction with the consequent improvement of stability.

Visualization of spatial patterns and temporal trends for aerial surveillance of illegal oil discharges in western Canadian marine waters.

PubMed

Serra-Sogas, Norma; O'Hara, Patrick D; Canessa, Rosaline; Keller, Peter; Pelot, Ronald

2008-05-01

This paper examines the use of exploratory spatial analysis for identifying hotspots of shipping-based oil pollution in the Pacific Region of Canada's Exclusive Economic Zone. It makes use of data collected from fiscal years 1997/1998 to 2005/2006 by the National Aerial Surveillance Program, the primary tool for monitoring and enforcing the provisions imposed by MARPOL 73/78. First, we present oil spill data as points in a "dot map" relative to coastlines, harbors and the aerial surveillance distribution. Then, we explore the intensity of oil spill events using the Quadrat Count method, and the Kernel Density Estimation methods with both fixed and adaptive bandwidths. We found that oil spill hotspots where more clearly defined using Kernel Density Estimation with an adaptive bandwidth, probably because of the "clustered" distribution of oil spill occurrences. Finally, we discuss the importance of standardizing oil spill data by controlling for surveillance effort to provide a better understanding of the distribution of illegal oil spills, and how these results can ultimately benefit a monitoring program.

Environmental monitoring of the area surrounding oil wells in Val d'Agri (Italy): element accumulation in bovine and ovine organs.

PubMed

Miedico, Oto; Iammarino, Marco; Paglia, Giuseppe; Tarallo, Marina; Mangiacotti, Michele; Chiaravalle, A Eugenio

2016-06-01

In this work, environmental heavy metal contamination in the Val d'Agri area of Southern Italy was monitored, measuring the accumulation of 18 heavy metals (U, Hg, Pb, Cd, As, Sr, Sn, V, Ni, Cr, Mo, Co, Cu, Zn, Ca, Mn, Fe, and Al) in the organs of animals raised in the surrounding area (kidney, lung, and liver of bovine and ovine species). Val d'Agri features various oil processing centers which are potentially a significant source of environmental pollution, making it essential to perform studies that will outline the state of the art on which any recovery plans and interventions may be developed. The analysis was carried out using official and accredited analytical methods based on inductively coupled plasma mass spectrometry, and the measurements were statistically processed in order to give a contribution to risk assessment. Even though five samples showed Pb and Cd concentrations above the limits defined in the European Commission Regulation (EC) No 1881/2006, the mean concentrations of most elements suggest that contamination in this area is low. Consequently, these results also suggest that there is no particular risk for human exposure to toxic trace elements. Nevertheless, the findings of this work confirm that element accumulation in ovine species is correlated with geographical livestock area. Therefore, ovine-specific organs might be used as bioindicators for monitoring contamination by specific toxic elements in exposed areas.

Non-Dispersive Infrared Sensor for Online Condition Monitoring of Gearbox Oil.

PubMed

Rauscher, Markus S; Tremmel, Anton J; Schardt, Michael; Koch, Alexander W

2017-02-18

The condition of lubricating oil used in automotive and industrial gearboxes must be controlled in order to guarantee optimum performance and prevent damage to machinery parts. In normal practice, this is done by regular oil change intervals and routine laboratory analysis, both of which involve considerable operating costs. In this paper, we present a compact and robust optical sensor that can be installed in the lubrication circuit to provide quasi-continuous information about the condition of the oil. The measuring principle is based on non-dispersive infrared spectroscopy. The implemented sensor setup consists of an optical measurement cell, two thin-film infrared emitters, and two four-channel pyroelectric detectors equipped with optical bandpass filters. We present a method based on multivariate partial least squares regression to select appropriate optical bandpass filters for monitoring the oxidation, water content, and acid number of the oil. We perform a ray tracing analysis to analyze and correct the influence of the light path in the optical setup on the optical parameters of the bandpass filters. The measurement values acquired with the sensor for three different gearbox oil types show high correlation with laboratory reference data for the oxidation, water content, and acid number. The presented sensor can thus be a useful supplementary tool for the online condition monitoring of lubricants when integrated into a gearbox oil circuit.

Non-Dispersive Infrared Sensor for Online Condition Monitoring of Gearbox Oil

PubMed Central

Rauscher, Markus S.; Tremmel, Anton J.; Schardt, Michael; Koch, Alexander W.

2017-01-01

The condition of lubricating oil used in automotive and industrial gearboxes must be controlled in order to guarantee optimum performance and prevent damage to machinery parts. In normal practice, this is done by regular oil change intervals and routine laboratory analysis, both of which involve considerable operating costs. In this paper, we present a compact and robust optical sensor that can be installed in the lubrication circuit to provide quasi-continuous information about the condition of the oil. The measuring principle is based on non-dispersive infrared spectroscopy. The implemented sensor setup consists of an optical measurement cell, two thin-film infrared emitters, and two four-channel pyroelectric detectors equipped with optical bandpass filters. We present a method based on multivariate partial least squares regression to select appropriate optical bandpass filters for monitoring the oxidation, water content, and acid number of the oil. We perform a ray tracing analysis to analyze and correct the influence of the light path in the optical setup on the optical parameters of the bandpass filters. The measurement values acquired with the sensor for three different gearbox oil types show high correlation with laboratory reference data for the oxidation, water content, and acid number. The presented sensor can thus be a useful supplementary tool for the online condition monitoring of lubricants when integrated into a gearbox oil circuit. PMID:28218701

Trans-fatty acids in cooking oils in Bogota, Colombia: changes in the food supply from 2008 to 2013.

PubMed

Moynihan, Meghan; Villamor, Eduardo; Marin, Constanza; Mora-Plazas, Mercedes; Campos, Hannia; Baylin, Ana

2015-12-01

Long-chain n-3 fatty acid intake in Colombia is low because fish consumption is limited. Vegetable oils with high n-3 fatty acid content are recommended, but their concentrations of trans fats were high in previous studies. Thus, regular monitoring of the fatty acid composition of vegetable oils is required. Our objective was to quantify the fatty acid composition in commercially available oils in Bogota, Colombia and determine if composition changed from 2008 to 2013. Cross-sectional study. We obtained samples of all commercially available oils reported in a survey of low- and middle-income families with a child participating in the Bogota School Children Cohort. Bogota, Colombia. Not applicable. Sunflower oil had the highest trans-fatty acid content (2.18%). Canola oil had the lowest proportion of trans-fatty acids (0.40%) and the highest n-3 fatty acid content (9.37%). In terms of percentage reduction from 2008 to 2013 in 18:1 and 18:2 trans-fatty acids, canola oil had 89% and 65% reduction, mixed oils had 44% and 48% reduction, and sunflower oil had 25% and 51 % reduction, respectively. Soyabean oil became widely available in 2013. The content of trans-fatty acids decreased in all oils from 2008 to 2013, suggesting a voluntary reduction by industry. We believe that regular monitoring of the fatty acid composition of oils is warranted.

Oil shale processing as a source of aquatic pollution: monitoring of the biologic effects in caged and feral freshwater fish.

PubMed Central

Tuvikene, A; Huuskonen, S; Koponen, K; Ritola, O; Mauer, U; Lindström-Seppä, P

1999-01-01

The biologic effects of the oil shale industry on caged rainbow trout (Oncorhynchus mykiss) as well as on feral perch (Perca fluviatilis) and roach (Rutilus rutilus) were studied in the River Narva in northeast Estonia. The River Narva passes the oil shale mining and processing area and thus receives elevated amounts of polycyclic aromatic hydrocarbons (PAHs), heavy metals, and sulfates. The effects of the chemical load were monitored by measuring cytochrome P4501A (CYP1A)-dependent monooxygenase (MO) activities [7-ethoxyresorufin O-deethylase and aryl hydrocarbon hydroxylase (AHH)] as well as conjugation enzyme activities [glutathione S-transferase (GST) and UDP-glucuronosyltransferase] in the liver of fish. CYP1A induction was further studied by detecting the amount and occurrence of the CYP1A protein. Histopathology of tissues (liver, kidney, spleen, and intestine) and the percentage of micronuclei in fish erythrocytes were also determined. Selected PAHs and heavy metals (Cd, Cu, Hg, and Pb) were measured from fish muscle and liver. In spite of the significant accumulation of PAHs, there was no induction of MO activities in any studied fish species. When compared to reference samples, AHH activities were even decreased in feral fish at some of the exposed sites. Detection of CYP1A protein content and the distribution of the CYP1A enzyme by immunohistochemistry also did not show extensive CYP1A induction. Instead, GST activities were significantly increased at exposed sites. Detection of histopathology did not reveal major changes in the morphology of tissues. The micronucleus test also did not show any evidence of genotoxicity. Thus, from the parameters studied, GST activity was most affected. The lack of catalytic CYP1A induction in spite of the heavy loading of PAHs was not studied but has been attributed to the elevated content of other compounds such as heavy metals, some of which can act as inhibitors for MOs. Another possible explanation of this lack of induction is that through adaptation processes the fish could have lost some of their sensitivity to PAHs. Either complex pollution caused by oil shale processing masked part of the harmful effects measured in this study, or oil shale industry did not have any severe effects on fish in the River Narva. Our study illustrates the difficulties in estimating risk in cases where there are numerous various contaminants affecting the biota. Images Figure 1 Figure 2 PMID:10464075

Glandular trichome density and essential oil composition in leaves and inflorescences of Lippia origanoides Kunth (Verbenaceae) in the Brazilian Cerrado.

PubMed

Tozin, Luiz R S; Marques, Marcia O M; Rodrigues, Tatiane M

2015-01-01

The essential oils from leaves and inflorescences of Lippia origanoides Kunth present aromatic and medicinal potential and have been used to treat several diseases, including melanoma. In Brazil, L. origanoides is commonly found in campo cerrado and cerrado stricto sensu, physiognomies featured mainly by the differential light conditions to which short and medium-sized plants are subjected. Our aim was to investigate the glandular trichome density and the yield and chemical composition of the essential oils in leaves and inflorescences of L. origanoides from campo cerrado and cerrado stricto sensu. For glandular density analysis, leaves and inflorescences were processed according to conventional techniques for scanning electron microscopy. The essential oils of leaves and inflorescences were obtained by hydrodistillation and identified with gas chromatography. Bracts and sepals showed the highest glandular density, followed by petals and leaves. The glandular density in the abaxial leaf surface was higher in individuals from the campo cerrado. In both populations the essential oil yield was higher in inflorescences than in leaves. The chemical composition of the essential oils varied among individuals from different areas and inside a same population. Our results demonstrated the chemical plasticity of L. origanoides suggesting the importance of monitoring its popular use.

A proactive system for maritime environment monitoring.

PubMed

Moroni, Davide; Pieri, Gabriele; Tampucci, Marco; Salvetti, Ovidio

2016-01-30

The ability to remotely detect and monitor oil spills is becoming increasingly important due to the high demand of oil-based products. Indeed, shipping routes are becoming very crowded and the likelihood of oil slick occurrence is increasing. In this frame, a fully integrated remote sensing system can be a valuable monitoring tool. We propose an integrated and interoperable system able to monitor ship traffic and marine operators, using sensing capabilities from a variety of electronic sensors, along with geo-positioning tools, and through a communication infrastructure. Our system is capable of transferring heterogeneous data, freely and seamlessly, between different elements of the information system (and their users) in a consistent and usable form. The system also integrates a collection of decision support services providing proactive functionalities. Such services demonstrate the potentiality of the system in facilitating dynamic links among different data, models and actors, as indicated by the performed field tests. Copyright © 2015 Elsevier Ltd. All rights reserved.

Spatial and temporal ecological variability in the northern Gulf of Alaska: What have we learned since the Exxon Valdez oil spill?

NASA Astrophysics Data System (ADS)

Aderhold, Donna G. R.; Lindeberg, Mandy R.; Holderied, Kris; Pegau, W. Scott

2018-01-01

This special issue examines oceanographic and biological variability in the northern Gulf of Alaska region with an emphasis on recent monitoring efforts of the Gulf Watch Alaska (GWA) and Herring Research and Monitoring (HRM) programs funded by the Exxon Valdez Oil Spill Trustee Council (EVOSTC). These programs are designed to improve our understanding of how changing environmental conditions affect Gulf of Alaska ecosystems and the long-term status of resources injured by the Exxon Valdez oil spill.

DOE Office of Scientific and Technical Information (OSTI.GOV)

P. Somasundaran

The aim of the project is to develop a knowledge base to help the design of enhanced processes for mobilizing and extracting untrapped oil. We emphasize evaluation of novel surfactant mixtures and obtaining optimum combinations of the surfactants for efficient chemical flooding EOR processes. In this regard, an understanding of the aggregate shape, size and structure is crucial since these properties govern the crude oil removal efficiency. During the three-year period, the adsorption and aggregation behavior of sugar-based surfactants and their mixtures with other types of surfactants have been studied. Sugar-based surfactants are made from renewable resources, nontoxic and biodegradable.more » They are miscible with water and oil. These environmentally benign surfactants feature high surface activity, good salinity, calcium and temperature tolerance, and unique adsorption behavior. They possess the characteristics required for oil flooding surfactants and have the potential for replacing currently used surfactants in oil recovery. A novel analytical ultracentrifugation technique has been successfully employed for the first time, to characterize the aggregate species present in mixed micellar solution due to its powerful ability to separate particles based on their size and shape and monitor them simultaneously. Analytical ultracentrifugation offers an unprecedented opportunity to obtain important information on mixed micelles, structure-performance relationship for different surfactant aggregates in solution and their role in interfacial processes. Initial sedimentation velocity investigations were conducted using nonyl phenol ethoxylated decyl ether (NP-10) to choose the best analytical protocol, calculate the partial specific volume and obtain information on sedimentation coefficient, aggregation mass of micelles. Four softwares: OptimaTM XL-A/XL-I data analysis software, DCDT+, Svedberg and SEDFIT, were compared for the analysis of sedimentation velocity experimental data. The results have been compared to that from Light Scattering. Based on the tests, Svedberg and SEDFIT analysis were chosen for further studies.« less

High-sensitivity gas-mapping 3D imager and method of operation

DOEpatents

Kreitinger, Aaron; Thorpe, Michael

2018-05-15

Measurement apparatuses and methods are disclosed for generating high-precision and -accuracy gas concentration maps that can be overlaid with 3D topographic images by rapidly scanning one or several modulated laser beams with a spatially-encoded transmitter over a scene to build-up imagery. Independent measurements of the topographic target distance and path-integrated gas concentration are combined to yield a map of the path-averaged concentration between the sensor and each point in the image. This type of image is particularly useful for finding localized regions of elevated (or anomalous) gas concentration making it ideal for large-area leak detection and quantification applications including: oil and gas pipeline monitoring, chemical processing facility monitoring, and environmental monitoring.

Treatment of automotive industry oily wastewater by electrocoagulation: statistical optimization of the operational parameters.

PubMed

GilPavas, Edison; Molina-Tirado, Kevin; Gómez-García, Miguel Angel

2009-01-01

An electrocoagulation process was used for the treatment of oily wastewater generated from an automotive industry in Medellín (Colombia). An electrochemical cell consisting of four parallel electrodes (Fe and Al) in bipolar configuration was implemented. A multifactorial experimental design was used for evaluating the influence of several parameters including: type and arrangement of electrodes, pH, and current density. Oil and grease removal was defined as the response variable for the statistical analysis. Additionally, the BOD(5), COD, and TOC were monitored during the treatment process. According to the results, at the optimum parameter values (current density = 4.3 mA/cm(2), distance between electrodes = 1.5 cm, Fe as anode, and pH = 12) it was possible to reach a c.a. 95% oils removal, COD and mineralization of 87.4% and 70.6%, respectively. A final biodegradability (BOD(5)/COD) of 0.54 was reached.

Vermicomposting of a lignocellulosic waste from olive oil industry: a pilot scale study.

PubMed

Benítez, E; Sainz, H; Melgar, R; Nogales, R

2002-04-01

The vermicomposting with Eisenia andrei of dry olive cake, a lignocellulosic waste produced during the extraction of olive oil, either alone or mixed with municipal biosolids, was studied in a nine-month pilot scale experiment. Number and biomass of earthworms and enzyme activities were periodically monitored and relevant properties of the final products were determined. In the assayed substrates, the total biomass of earthworms increased at the end of the experimental period between 9 and 12-fold respectively in comparison with the earthworm biomass initially inoculated. The increase in hydrolytic enzymes and overall microbial activity during the vermicomposting process indicated the biodegradation of the olive cake and resulted in the disappearance of the initial phytotoxicity of the substrate. However, the recalcitrant lignocellulosic nature of the dry olive cake prevented suitable humification during the vermicomposting process. For this reason, in addition to organic amendments, other management procedures should be considered.

International Symposium on Remote Sensing of Environment, 9th, University of Michigan, Ann Arbor, Mich., April 15-19, 1974, Proceedings. Volumes 1, 2 & 3

NASA Technical Reports Server (NTRS)

1974-01-01

The present work gathers together numerous papers describing the use of remote sensing technology for mapping, monitoring, and management of earth resources and man's environment. Studies using various types of sensing equipment are described, including multispectral scanners, radar imagery, spectrometers, lidar, and aerial photography, and both manual and computer-aided data processing techniques are described. Some of the topics covered include: estimation of population density in Tokyo districts from ERTS-1 data, a clustering algorithm for unsupervised crop classification, passive microwave sensing of moist soils, interactive computer processing for land use planning, the use of remote sensing to delineate floodplains, moisture detection from Skylab, scanning thermal plumes, electrically scanning microwave radiometers, oil slick detection by X-band synthetic aperture radar, and the use of space photos for search of oil and gas fields. Individual items are announced in this issue.

LOOP marine and estuarine monitoring program, 1978-95 : volume 5 : demersal nekton.

DOT National Transportation Integrated Search

1998-01-01

The Louisiana Offshore Oil Port (LOOP) facilities in coastal Louisiana provide the United States with the country's only Superport for off-loading deep draft tankers. The facilities transport oil ashore through pipelines, and temporarily store oil be...

Borehole geophysical monitoring of amendment emplacement and geochemical changes during vegetable oil biostimulation, Anoka County Riverfront Park, Fridley, Minnesota

USGS Publications Warehouse

Lane, John W.; Day-Lewis, Frederick D.; Johnson, Carole D.; Joesten, Peter K.; Kochiss, Christopher S.

2007-01-01

Based on the geophysical data, conceptual models of the distributions of emulsified vegetable oil and ground water with altered chemistry were developed. The field data indicate that, in several cases, the plume of ground water with altered chemistry would not be detected by direct chemical sampling given the construction of monitoring wells; hence the geophysical data provide valuable site-specific insights for the interpretation of water samples and monitoring of biostimulation projects. Application of geophysical methods to data from the ACP demonstrated the utility of radar for monitoring biostimulation injections.

Thermal deterioration of virgin olive oil monitored by ATR-FTIR analysis of trans content.

PubMed

Tena, Noelia; Aparicio, Ramón; García-González, Diego L

2009-11-11

The monitoring of frying oils by an effective and rapid method is one of the demands of food companies and small food retailers. In this work, a method based on ATR-FTIR has been developed for monitoring the oil degradation in frying procedures. The IR bands changing during frying in sunflower, soybean, and virgin olive oils have been examined in their linear relationship with the content of total polar compounds, which is a preferred parameter for frying control. The bands assigned to conjugated and isolated trans double bonds that are commonly used for the determination of trans content provided the best relationships. Then, the area covering 978-960 cm(-1) was chosen to build a model for predicting polar material content for the particular case of virgin olive oil. A virgin olive oil was heated up to 94 h, and samples collected every 2 h constituted the training set. These samples were analyzed to obtain their FTIR spectra and to determine the composition of fatty acids and the content of total polar compounds. The excellent results predicting the polar material content (adjusted R(2) 0.997) was successfully validated with an external set of samples. The analysis of the fatty acid composition confirmed the relationship between the trans content and the content of total polar compounds.

Harlequin duck (Histrionicus histrionicus) perspective: Harlequin duck population recovery following the Exxon Valdez oil spill: Progress, process, and constraints

USGS Publications Warehouse

Esler, Daniel N.; Bowman, Timothy D.; Trust, Kimberly A.; Ballachey, Brenda E.; Dean, Thomas A.; Jewett, Stephen C.; O'Clair, Charles E.; Holland-Bartels, Leslie E.

2002-01-01

Following the 1989 Exxon Valdez oil spill in Prince William Sound, Alaska, we studied the status of recovery of harlequin duck (Histrionicus histrionicus) populations during 1995-1998. We evaluated potential constraints to full recovery, including (1) exposure to residual oil, (2) food limitation, and (3) intrinsic demographic limitations on population growth rates. In this paper, we synthesize the findings from our work and incorporate information from other harlequin duck research and monitoring programs to provide a comprehensive evaluation of the response of this species to the Exxon Valdez oil spill. We conclude that harlequin duck populations had not fully recovered by 1998. Furthermore, adverse effects continued as many as 9 years after the oil spill, in contrast to the conventional paradigm that oil spill effects on bird populations are short-lived. These conclusions are based on the findings that (1) elevated cytochrome P450 induction on oiled areas indicated continued exposure to oil in 1998, (2) adult female winter survival was lower on oiled than unoiled areas during 1995-1998, (3) fall population surveys by the Alaska Department of Fish and Game indicated numerical declines in oiled areas during 1995-1997, and (4) densities on oiled areas in 1996 and 1997 were lower than expected using models that accounted for effects of habitat attributes. Based on hypothesized links between oil contamination and demography, we suggest that harlequin duck population recovery was constrained primarily by continued oil exposure. Full population recovery also will be delayed by the time necessary for intrinsic population growth to allow return to pre-spill numbers following cessation of residual oil spill effects. Although not all wildlife species were affected by the Exxon Valdez oil spill, and some others may have recovered quickly from any effects, harlequin duck life history characteristics and benthic, nearshore feeding habits make them susceptible to both initial and long-term oil spill effects.

Which Members of the Microbial Communities Are Active? Microarrays

NASA Astrophysics Data System (ADS)

Morris, Brandon E. L.

Here, we introduce the concept of microarrays, discuss the advantages of several different types of arrays and present a case study that illustrates a targeted-profiling approach to bioremediation of a hydrocarbon-contaminated site in an Arctic environment. The majority of microorganisms in the terrestrial subsurface, particularly those involved in 'heavy oil' formation, reservoir souring or biofouling remain largely uncharacterised (Handelsman, 2004). There is evidence though that these processes are biologically catalysed, including stable isotopic composition of hydrocarbons in oil formations (Pallasser, 2000; Sun et al., 2005), the absence of biodegraded oil from reservoirs warmer than 80°C (Head et al., 2003) or negligible biofouling in the absence of biofilms (Dobretsov et al., 2009; Lewandowski and Beyenal, 2008), and all clearly suggest an important role for microorganisms in the deep biosphere in general and oilfield systems in particular. While the presence of sulphate-reducing bacteria in oilfields was first observed in the early twentieth century (Bastin, 1926), it was only through careful experiments with isolates from oil systems or contaminated environments that unequivocal evidence for hydrocarbon biodegradation under anaerobic conditions was provided (for a review, see Widdel et al., 2006). Work with pure cultures and microbial enrichments also led to the elucidation of the biochemistry of anaerobic aliphatic and aromatic hydrocarbon degradation and the identification of central metabolites and genes involved in the process, e.g. (Callaghan et al., 2008; Griebler et al., 2003; Kropp et al., 2000). This information could then be extrapolated to the environment to monitor degradation processes and determine if in situ microbial populations possessed the potential for contaminant bioremediation, e.g. Parisi et al. (2009). While other methods have also been developed to monitor natural attenuation of hydrocarbons (Meckenstock et al., 2004), we are only at the early stages of understanding the microbial processes that occur in petroliferous formations and the surrounding subterranean environment. Important first steps in characterising the microbiology of oilfield systems involve identifying the microbial community structure and determining how population diversity changes are affected by the overall geochemical and biological parameters of the system. This is relatively easy to do today by using general 16S rRNA primers for PCR and building clone libraries. For example, previous studies using molecular methods characterised many dominant prokaryotes in petroleum reservoirs (Orphan et al., 2000) and in two Alaskan North Slope oil facilities (Duncan et al., 2009; Pham et al., 2009). However, the problem is that more traditional molecular biology approaches, such as 16S clone libraries, fail to detect large portions of the community perhaps missing up to half of the biodiversity (see Hong et al., 2009) and require significant laboratory time to construct large libraries necessary to increase the probability of detecting the majority of even bacterial biodiversity. In the energy sector, the overarching desire would be to quickly assess the extent of in situ hydrocarbon biodegradation or to disrupt detrimental processes such as biofouling, and in these cases it may not be necessary to identify specific microbial species. Rather, it would be more critical to evaluate metabolic processes or monitor gene products that are implicated in the specific activity of interest. Research goals such as these are well suited for a tailored application of microarray technology.

Portable system for temperature monitoring in all phases of wine production.

PubMed

Boquete, Luciano; Cambralla, Rafael; Rodríguez-Ascariz, J M; Miguel-Jiménez, J M; Cantos-Frontela, J J; Dongil, J

2010-07-01

This paper presents a low-cost and highly versatile temperature-monitoring system applicable to all phases of wine production, from grape cultivation through to delivery of bottled wine to the end customer. Monitoring is performed by a purpose-built electronic system comprising a digital memory that stores temperature data and a ZigBee communication system that transmits it to a Control Centre for processing and display. The system has been tested under laboratory conditions and in real-world operational applications. One of the system's advantages is that it can be applied to every phase of wine production. Moreover, with minimum modification, other variables of interest (pH, humidity, etc.) could also be monitored and the system could be applied to other similar sectors, such as olive-oil production. 2010 ISA. Published by Elsevier Ltd. All rights reserved.

Diagnostics of wear in aeronautical systems

NASA Technical Reports Server (NTRS)

Wedeven, L. D.

1979-01-01

The use of appropriate diagnostic tools for aircraft oil wetted components is reviewed, noting that it can reduce direct operating costs through reduced unscheduled maintenance, particularly in helicopter engine and transmission systems where bearing failures are a significant cost factor. Engine and transmission wear modes are described, and diagnostic methods for oil and wet particle analysis, the spectrometric oil analysis program, chip detectors, ferrography, in-line oil monitor and radioactive isotope tagging are discussed, noting that they are effective over a limited range of particle sizes but compliment each other if used in parallel. Fine filtration can potentially increase time between overhauls, but reduces the effectiveness of conventional oil monitoring techniques so that alternative diagnostic techniques must be used. It is concluded that the development of a diagnostic system should be parallel and integral with the development of a mechanical system.

A low cost mid-infrared sensor for on line contamination monitoring of lubricating oils in marine engines

NASA Astrophysics Data System (ADS)

Ben Mohammadi, L.; Kullmann, F.; Holzki, M.; Sigloch, S.; Klotzbuecher, T.; Spiesen, J.; Tommingas, T.; Weismann, P.; Kimber, G.

2010-04-01

The chemical and physical condition of oils in marine engines must be monitored to ensure optimum performance of the engine and to avoid damage by degraded oil not adequately lubricating the engine. Routine monitoring requires expensive laboratory testing and highly skilled analysts. This work describes the adaptation and implementation of a mid infrared (MIR) sensor module for continued oil condition monitoring in two-stroke and four-stroke diesel engines. The developed sensor module will help to reduce costs in oil analysis by eliminating the need to collect and send samples to a laboratory for analysis. The online MIR-Sensor module measures the contamination of oil with water, soot, as well as the degradation indicated by the TBN (Total Base Number) value. For the analysis of water, TBN, and soot in marine engine oils, four spectral regions of interest have been identified. The optical absorption in these bands correlating with the contaminations is measured simultaneously by using a four-field thermopile detector, combined with appropriate bandpass filters. Recording of the MIR-absorption was performed in a transmission mode using a flow-through cell with appropriate path length. Since in this case no spectrometer is required, the sensor including the light source, the flowthrough- cell, and the detector can be realised at low cost and in a very compact manner. The optical configuration of the sensor with minimal component number and signal intensity optimisation at the four-field detector was implemented by using non-sequential ray tracing simulation. The used calibration model was robust enough to predict accurately the value for soot, water, and TBN concentration for two-stroke and four-stroke engine oils. The sensor device is designed for direct installation on the host engine or machine and, therefore, becoming an integral part of the lubrication system. It can also be used as a portable stand-alone system for machine fluid analysis in the field.

Studies of soil and ecohydrological processes in oil-gas production regions.

NASA Astrophysics Data System (ADS)

Khodyreva, E. Ya.; Khodyrev, Yu. P.

2009-04-01

For a better understanding and describing of the functional interactions between processes in soil and drinking, underground and stratum waters in oil-gas production regions we used laboratory and field monitoring methods of studies. The control of ecological situation dynamics in oil-gas production regions proposes a presence of primary data about parameter-indicators, which characterize a state of the object under investigation. One of these parameters is the concentration of heavy metal salts in drinking and stratum waters. Isolation of some compounds, which are extracted as impurities of oil and water during recovery of hydrocarbons from productive horizons, would enhance profitableness of recovery. Because accompanying impurities are a mixture of different salts and complexes, the methods of multielement analysis give the most objective evaluation of total content of some elements by search and prospecting. The developed method of laser mass-spectrometric analysis of oil and drinking, underground and industrial waters allows to investigate the samples on all elements of the periodical system simultaneously with limit sensitivity 0.1 mkg/l. The preparation of the oil and water probes was carried out by sublimation of highly volatile fractions in vacuum at 100 0C. The samples of drinking and underground waters, oils and industrial waters from wells of oil field Romashkin (Tatarstan) were chosen as the object for the research. In respect to possible metal extraction scandium is of most interest in inspected area because it's very high cost and availability of water-soluble pattern, most probably chloride. Its concentration in one well was 1 mg/l in water and 0.01 mg/l in oil. According to the received data of laser mass-spectrometric analysis, industrial waters on the activity investigated territory joint-stock company "Tatneft" contain 220-330 kg / ton of salts of metals that does by their potential source of alternative raw material for the chemical industry. Soil is an important component of the earth's biosphere because of its crucial role in the hydrological cycle. For revealing possible correlation between spatial distributions of the valuable elements contained both in industrial waters and in tests of soils, 79 samples are prepared and investigated. These tests are selected at superficial geochemical shooting (field monitoring methods of studies) Aznakaevskoi, Karamalinskoi and Sabanchinskoi areas of joint-stock company " Tatneft ". Circuits of distribution of valuable elements on the investigated territory are constructed also a quantitative estimation of the maintenance makro- and microcomponents is given. From the found out elements the greatest interest Na, Mg, K, Ca, Cl, Br and their connections represent because of very high concentration and scandium owing to the cost. Now cost of scandium in the world market approximately in 25 times exceeds cost of gold and is not observed yet tendencies to its decrease. Presence of impurity of salts of heavy metals and their connections in soils, drinking, underground and stratum waters, definition of their concentration and comparison from maximum concentration limit allows to establish the control over dynamics of ecohydrological conditions and in due time to take measures on reduction of negative influence of processes of development of hydrocarbon raw material by an environment.

Exposure to oil mist and oil vapour during offshore drilling in norway, 1979-2004.

PubMed

Steinsvåg, Kjersti; Bråtveit, Magne; Moen, Bente E

2006-03-01

To describe personal exposure to airborne hydrocarbon contaminants (oil mist and oil vapour) from 1979 to 2004 in the mud-handling areas of offshore drilling facilities operating on the Norwegian continental shelf when drilling with oil-based muds. Qualitative and quantitative information was gathered during visits to companies involved in offshore oil and gas production in Norway. Monitoring reports on oil mist and oil vapour exposure covered 37 drilling facilities. Exposure data were analysed using descriptive statistics and by constructing linear mixed-effects models. Samples had been taken during the use of three generations of hydrocarbon base oils, namely diesel oils (1979-1984), low-aromatic mineral oils (1985-1997) and non-aromatic mineral oils (1998-2004). Sampling done before 1984 showed high exposure to diesel vapour (arithmetic mean, AM = 1217 mg m(-3)). When low-aromatic mineral oils were used, the exposure to oil mist and oil vapour was 4.3 and 36 mg m(-3), and the respective AMs for non-aromatic mineral oils were reduced to 0.54 and 16 mg m(-3). Downward time trends were indicated for both oil mist (6% per year) and oil vapour (8% per year) when the year of monitoring was introduced as a fixed effect in a linear mixed-effects model analysis. Rig type, technical control measures and mud temperature significantly determined exposure to oil mist. Rig type, type of base oil, viscosity of the base oil, work area, mud temperature and season significantly determined exposure to oil vapour. Major decreases in variability were found for the between-rig components. Exposure to oil mist and oil vapour declined over time in the mud-handling areas of offshore drilling facilities. Exposure levels were associated with rig type, mud temperature, technical control measures, base oil, viscosity of the base oil, work area and season.

First evaluation of foraminiferal metabarcoding for monitoring environmental impact from an offshore oil drilling site.

PubMed

Laroche, Olivier; Wood, Susanna A; Tremblay, Louis A; Ellis, Joanne I; Lejzerowicz, Franck; Pawlowski, Jan; Lear, Gavin; Atalah, Javier; Pochon, Xavier

2016-09-01

At present, environmental impacts from offshore oil and gas activities are partly determined by measuring changes in macrofauna diversity. Morphological identification of macrofauna is time-consuming, expensive and dependent on taxonomic expertise. In this study, we evaluated the applicability of using foraminiferal-specific metabarcoding for routine monitoring. Sediment samples were collected along distance gradients from two oil platforms off Taranaki (New Zealand) and their physico-chemical properties, foraminiferal environmental DNA/RNA, and macrofaunal composition analyzed. Macrofaunal and foraminiferal assemblages showed similar shifts along impact gradients, but responded differently to environmental perturbations. Macrofauna were affected by hypoxia, whereas sediment grain size appeared to drive shifts in foraminifera. We identified eight foraminiferal molecular operational taxonomic units that have potential to be used as bioindicator taxa. Our results show that metabarcoding represents an effective tool for assessing foraminiferal communities near offshore oil and gas platforms, and that it can be used to complement current monitoring techniques. Copyright © 2016 Elsevier Ltd. All rights reserved.

Photopyroelectric Monitoring of Olive's Ripening Conditions and Olive Oil Quality Using Pulsed Wideband IR Thermal Source

NASA Astrophysics Data System (ADS)

Abu-Taha, M. I.; Sarahneh, Y.; Saleh, A. M.

The present study is based on band absorption of radiation from pulsed wideband infrared (IR) thermal source (PWBS) in conjunction with polyvinylidene fluoride film (PVDF). It is the first time to be employed to monitor the ripening state of olive fruit. Olive's characteristics vary at different stages of ripening, and hence, cultivation of olives at the right time is important in ensuring the best oil quality and maximizes the harvest yield. The photopyroelectric (PPE) signal resulting from absorption of wideband infrared (IR) radiation by fresh olive juice indicates the ripening stage of olives, i.e., allows an estimate of the suitable harvest time. The technique was found to be very useful in discriminating between olive oil samples according to geographical region, shelf life, some storage conditions, and deliberate adulteration. Our results for monitoring oil accumulation in olives during the ripening season agree well with the complicated analytical studies carried out by other researchers.

Effect of cross-linking of interfacial sodium caseinate by natural processing on the oxidative stability of oil-in-water (o/w) emulsions.

PubMed

Phoon, Pui Yeu; Paul, Lake N; Burgner, John W; San Martin-Gonzalez, M Fernanda; Narsimhan, Ganesan

2014-04-02

This study investigated how enzymatic cross-linking of interfacial sodium caseinate and emulsification, via high-pressure homogenization, influenced the intrinsic oxidative stability of 4% (w/v) menhaden oil-in-water emulsions stabilized by 1% (w/v) caseinate at pH 7. Oil oxidation was monitored by the ferric thiocyanate perioxide value assay. Higher homogenization pressure resulted in improved intrinsic emulsion oxidative stability, which is attributed to increased interfacial cross-linking as indicated by higher weighted average sedimentation coefficients of interfacial protein species (from 11.2 S for 0 kpsi/0.1 MPa to 18 S for 20 kpsi/137.9 MPa). Moderate dosage of transglutaminase at 0.5-1.0 U/mL emulsion enhanced intrinsic emulsion oxidative stability further, despite a contradictory reduction in the antioxidant property of cross-linked caseinate as tested by the 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) assay. This implied the prominent role of cross-linked interfacial caseinate as a physical barrier for oxygen transfer, hence its efficacy in retarding oil oxidation.

30 CFR 250.519 - How often do I have to monitor for casing pressure?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false How often do I have to monitor for casing pressure? 250.519 Section 250.519 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Well-Completion Operations Casing Pressure Management §...

30 CFR 250.519 - How often do I have to monitor for casing pressure?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 2 2011-07-01 2011-07-01 false How often do I have to monitor for casing pressure? 250.519 Section 250.519 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT, REGULATION, AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER CONTINENTAL SHELF Oil and Gas Well-Completion...

Harlequin duck population recovery following the 'Exxon Valdez' oil spill: Progress, process and constraints

USGS Publications Warehouse

Esler, Daniel N.; Bowman, Timothy D.; Trust, Kimberly A.; Ballachey, Brenda E.; Dean, Thomas A.; Jewett, Stephen C.; O'Clair, Charles E.

2002-01-01

Following the 1989 'Exxon Valdez' oil spill in Prince William Sound, Alaska, we studied the status of recovery of harlequin duck Histrionicus histrionicus populations during 1995 to 1998. We evaluated potential constraints on full recovery, including (1) exposure to residual oil; (2) food limitation; and (3) intrinsic demographic limitations on population growth rates. In this paper, we synthesize the findings from our work and incorporate information from other harlequin duck research and monitoring programs to provide a comprehensive evaluation of the response of this species to the 'Exxon Valdez' spill. We conclude that harlequin duck populations had not fully recovered by 1998. Furthermore, adverse effects continued as many as 9 yr after the oil spill, in contrast to the conventional paradigm that oil spill effects on bird populations are short-lived. These conclusions are based on the findings that (1) elevated cytochrome P450 (CYP1A) induction on oiled areas indicated continued exposure to oil in 1998; (2) adult female winter survival was lower on oiled than unoiled areas during 1995 to 1998; (3) fall population surveys by the Alaska Department of Fish and Game indicated numerical declines in oiled areas during 1995 to 1997; and (4) densities on oiled areas in 1996 and 1997 were lower than expected using models that accounted for effects of habitat attributes. Based on hypothesized links between oil contamination and demography, we suggest that harlequin duck population recovery was constrained primarily by continued oil exposure. Full population recovery will also be delayed by the time necessary for intrinsic population growth to allow return to pre-spill numbers following cessation of residual oil spill effects. Although not all wildlife species were affected by the 'Exxon Valdez' oil spill, and some others may have recovered quickly from any effects, harlequin duck life history characteristics and benthic, nearshore feeding habits make them susceptible to both initial and long-term oil spill effects.

Impact of NiB Coating on the Efficiency, Scuffing, and Wear of Gear Contacts

DTIC Science & Technology

2013-05-01

required for gear applications. 15. SUBJECT TERMS surface engineering, tribology , traction, wear, scuffing, transmission efficiency 16. SECURITY...force. A third thermocouple was placed inside the oil reservoir to measure supply temperature. The temperature measurements were also monitored and...in figure 7b. Similarly, a commonly used chemical polishing process was applied to a third batch of ground specimens to achieve smoother isotropic

Physical and chemical characterization of residual oil-fired power plant emissions

EPA Science Inventory

Although the toxicity of oil combustion emissions is a significant public health concern, few studies characterize the emissions from plant-scale utility boilers firing residual oil. This study remedies that deficiency by sampling and monitoring stack emissions from a 432 Giga Jo...

33 CFR 155.710 - Qualifications of person in charge.

Code of Federal Regulations, 2012 CFR

2012-07-01

... SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL POLLUTION PREVENTION REGULATIONS FOR VESSELS... control and monitoring systems, the procedures for reporting pollution incidents, and, if installed, the Crude-Oil Washing (COW), inert-gas, and vapor-control systems—to safely conduct a transfer of fuel oil...

33 CFR 155.710 - Qualifications of person in charge.

Code of Federal Regulations, 2011 CFR

2011-07-01

... SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL POLLUTION PREVENTION REGULATIONS FOR VESSELS... control and monitoring systems, the procedures for reporting pollution incidents, and, if installed, the Crude-Oil Washing (COW), inert-gas, and vapor-control systems—to safely conduct a transfer of fuel oil...

Diagnosing the level of stress on a mangrove species (Laguncularia racemosa) contaminated with oil: A necessary step for monitoring mangrove ecosystems.

PubMed

Reinert, Fernanda; de Pinho, Camila Ferreira; Ferreira, Marcio Alves

2016-12-15

Monitoring the effects of pollution on mangrove vegetation is a challenge. A specific study using an oil spill simulation on mangrove species was conducted to address this challenge. We tested the effectiveness of the chlorophyll a fluorescence kinetics as a fast and robust method to diagnose the vitality of Laguncularia racemosa. We used L. racemosa plants contaminated with marine fuel oil in mangrove microcosm models. Several parameters of the JIP-test were capable of detecting the impairment of the photosynthetic function prior to the visual manifestation of symptoms in response to oil contamination. The results support the use of the chlorophyll fluorescence transient as a reliable, fast and easy to apply diagnostic method for evaluating oil-impacted mangroves. To the best of our knowledge, it is the first time that consistent data showing photosynthetic impairment in response to oil contamination is shown for a mangrove tree species. Copyright © 2016 Elsevier Ltd. All rights reserved.

Plant species affect colonization patterns and metabolic activity of associated endophytes during phytoremediation of crude oil-contaminated soil.

PubMed

Fatima, K; Imran, A; Amin, I; Khan, Q M; Afzal, M

2016-04-01

Plants coupled with endophytic bacteria hold great potential for the remediation of polluted environment. The colonization patterns and activity of inoculated endophytes in rhizosphere and endosphere of host plant are among the primary factors that may influence the phytoremediation process. However, these colonization patterns and metabolic activity of the inoculated endophytes are in turn controlled by none other than the host plant itself. The present study aims to determine such an interaction specifically for plant-endophyte systems remediating crude oil-contaminated soil. A consortium (AP) of two oil-degrading endophytic bacteria (Acinetobacter sp. strain BRSI56 and Pseudomonas aeruginosa strain BRRI54) was inoculated to two grasses, Brachiaria mutica and Leptochloa fusca, vegetated in crude oil-contaminated soil. Colonization patterns and metabolic activity of the endophytes were monitored in the rhizosphere and endosphere of the plants. Bacterial augmentation enhanced plant growth and crude oil degradation. Maximum crude oil degradation (78%) was achieved with B. mutica plants inoculated with AP consortium. This degradation was significantly higher than those treatments, where plants and bacteria were used individually or L. fusca and endophytes were used in combination. Moreover, colonization and metabolic activity of the endophytes were higher in the rhizosphere and endosphere of B. mutica than L. fusca. The plant species affected not only colonization pattern and biofilm formation of the inoculated bacteria in the rhizosphere and endosphere of the host plant but also affected the expression of alkane hydroxylase gene, alkB. Hence, the investigation revealed that plant species can affect colonization patterns and metabolic activity of inoculated endophytic bacteria and ultimately the phytoremediation process.

Stability of omega-3 fatty acids in fortified surimi seafoods during chilled storage.

PubMed

Pérez-Mateos, Miriam; Boyd, Leon; Lanier, Tyre

2004-12-29

Physical, chemical, and sensory properties of cooked surimi seafood gels (crab analogue) fortified with omega-3 fatty acids (FA) were monitored during chilled storage. Three sources of stabilized omega-3 FA (fish oil concentrate, menhaden oil, and a purified marine oil) were each incorporated into gels to an omega-3 FA content of 1.5 or 2.5%, w/w. Omega-3 FA stability, development of off-flavors, and changes in color and texture were monitored during chilled storage for 2 months. Gels with fish oil concentrate developed fishy flavor and aroma within 30 days and were eliminated from the study. Gels containing menhaden oil and purified marine oil exhibited little change in sensory properties or oxidation products throughout 2 months of storage. Relative polyene index values (ratio of polyunsaturated to saturated fatty acids) indicated that the omega-3 FA were stable at both levels of addition. Omega-3 fortified gels were whiter than control gels, and gel texture was modified when menhaden and purified oils were added but not significantly affected by the level of omega-3 addition.

Eat-by-light: fiber-optic and micro-optic devices for food safety and quality assessment

NASA Astrophysics Data System (ADS)

Mignani, A. G.; Ciaccheri, L.; Cucci, C.; Mencaglia, A. A.; Cimato, A.; Attilio, C.; Thienpont, H.; Ottevaere, H.; Paolesse, R.; Mastroianni, M.; Monti, D.; Buonocore, G.; Del Nobile, A.; Mentana, A.; Dall'Asta, C.; Faccini, A.; Galaverna, G.; Dossena, A.

2007-07-01

A selection of fiber-optic and micro-optic devices is presented designed and tested for monitoring the quality and safety of typical foods, namely the extra virgin olive oil, the beer, and the milk. Scattered colorimetry is used for the authentication of various types of extra virgin olive oil and beer, while a fiber-optic-based device for UV-VIS-NIR absorption spectroscopy is exploited in order to obtain the hyperspectral optical signature of olive oil. This is done not only for authentication purposes, but also so as to correlate the spectral data with the content of fatty acids that are important nutritional factors. A micro-optic sensor for the detection of olive oil aroma is presented. It is capable of distinguishing different ageing levels of extra virgin olive oil. It shows effective potential for acting as a smart cap of bottled olive oil in order to achieve a non-destructive olfactory perception of oil ageing. Lastly, a compact portable fluorometer is experimented for the rapid monitoring of the carcinogenic M1 aflatoxin in milk.

Data from exploratory sampling of groundwater in selected oil and gas areas of coastal Los Angeles County and Kern and Kings Counties in southern San Joaquin Valley, 2014–15: California oil, gas, and groundwater project

USGS Publications Warehouse

Dillon, David B.; Davis, Tracy A.; Landon, Matthew K.; Land, Michael T.; Wright, Michael T.; Kulongoski, Justin T.

2016-12-09

Exploratory sampling of groundwater in coastal Los Angeles County and Kern and Kings Counties of the southern San Joaquin Valley was done by the U.S. Geological Survey from September 2014 through January 2015 as part of the California State Water Resources Control Board’s Water Quality in Areas of Oil and Gas Production Regional Groundwater Monitoring Program. The Regional Groundwater Monitoring Program was established in response to the California Senate Bill 4 of 2013 mandating that the California State Water Resources Control Board design and implement a groundwater-monitoring program to assess potential effects of well-stimulation treatments on groundwater resources in California. The U.S. Geological Survey is in cooperation with the California State Water Resources Control Board to collaboratively implement the Regional Groundwater Monitoring Program through the California Oil, Gas, and Groundwater Project. Many researchers have documented the utility of different suites of chemical tracers for evaluating the effects of oil and gas development on groundwater quality. The purpose of this exploratory sampling effort was to determine whether tracers reported in the literature could be used effectively in California. This reconnaissance effort was not designed to assess the effects of oil and gas on groundwater quality in the sampled areas. A suite of water-quality indicators and geochemical tracers were sampled at groundwater sites in selected areas that have extensive oil and gas development. Groundwater samples were collected from a total of 51 wells, including 37 monitoring wells at 17 multiple-well monitoring sites in coastal Los Angeles County and 5 monitoring wells and 9 water-production wells in southern San Joaquin Valley, primarily in Kern and Kings Counties. Groundwater samples were analyzed for field waterquality indicators; organic constituents, including volatile and semi-volatile organic compounds and dissolved organic carbon indicators; naturally present inorganic constituents, including trace elements, nutrients, major and minor ions, and iron species; naturally present stable and radioactive isotopes; dissolved noble gases; dissolved standard and hydrocarbon gases, δ13C of methane, ethane, and δ2 H of methane. In total, 249 constituents and water-quality indicators were measured. Four types of quality-control samples (blanks, replicates, matrix spikes, and surrogates spiked in environmental and blank samples) were collected at approximately 10 percent of the wells. The quality-control data were used to determine whether the groundwater-sample data were of sufficient quality for the measured analytes to be used as potential indicators of oil and gas effects. The data from the 51 groundwater samples and from the quality-control samples are presented in this report.

Label-free in situ imaging of oil body dynamics and chemistry in germination

PubMed Central

Waschatko, Gustav; Billecke, Nils; Schwendy, Sascha; Jaurich, Henriette; Bonn, Mischa; Vilgis, Thomas A.

2016-01-01

Plant oleosomes are uniquely emulsified lipid reservoirs that serve as the primary energy source during seed germination. These oil bodies undergo significant changes regarding their size, composition and structure during normal seedling development; however, a detailed characterization of these oil body dynamics, which critically affect oil body extractability and nutritional value, has remained challenging because of a limited ability to monitor oil body location and composition during germination in situ. Here, we demonstrate via in situ, label-free imaging that oil bodies are highly dynamic intracellular organelles that are morphologically and biochemically remodelled extensively during germination. Label-free, coherent Raman microscopy (CRM) combined with bulk biochemical measurements revealed the temporal and spatial regulation of oil bodies in native soya bean cotyledons during the first eight days of germination. Oil bodies undergo a cycle of growth and shrinkage that is paralleled by lipid and protein compositional changes. Specifically, the total protein concentration associated with oil bodies increases in the first phase of germination and subsequently decreases. Lipids contained within the oil bodies change in saturation and chain length during germination. Our results show that CRM is a well-suited platform to monitor in situ lipid dynamics and local chemistry and that oil bodies are actively remodelled during germination. This underscores the dynamic role of lipid reservoirs in plant development. PMID:27798279

Measurement of atmospheric pollutants associated with oil and natural gas exploration and production activity in Pennsylvania's Allegheny National Forest.

PubMed

Pekney, Natalie J; Veloski, Garret; Reeder, Matthew; Tamilia, Joseph; Rupp, Erik; Wetzel, Alan

2014-09-01

Oil and natural gas exploration and production (E&P) activities generate emissions from diesel engines, compressor stations, condensate tanks, leaks and venting of natural gas, construction of well pads, and well access roads that can negatively impact air quality on both local and regional scales. A mobile, autonomous air quality monitoring laboratory was constructed to collect measurements of ambient concentrations of pollutants associated with oil and natural gas E&P activities. This air-monitoring laboratory was deployed to the Allegheny National Forest (ANF) in northwestern Pennsylvania for a campaign that resulted in the collection of approximately 7 months of data split between three monitoring locations between July 2010 and June 2011. The three monitoring locations were the Kane Experimental Forest (KEF) area in Elk County, which is downwind of the Sackett oilfield; the Bradford Ranger Station (BRS) in McKean County, which is downwind of a large area of historic oil and gas productivity; and the U.S. Forest Service Hearts Content campground (HC) in Warren County, which is in an area relatively unimpacted by oil and gas development and which therefore yielded background pollutant concentrations in the ANF. Concentrations of criteria pollutants ozone and NO2 did not vary significantly from site to site; averages were below National Ambient Air Quality Standards. Concentrations of volatile organic compounds (VOCs) associated with oil and natural gas (ethane, propane, butane, pentane) were highly correlated. Applying the conditional probability function (CPF) to the ethane data yielded most probable directions of the sources that were coincident with known location of existing wells and activity. Differences between the two impacted and one background site were difficult to discern, suggesting the that the monitoring laboratory was a great enough distance downwind of active areas to allow for sufficient dispersion with background air such that the localized plumes were not detected. Implications: Monitoring of pollutants associated with oil and natural gas exploration and production activity at three sites within the Allegheny National Forest (ANF) showed only slight site-to-site differences even with one site far removed from these activities. However, the impact was evident not in detection of localized plumes but in regional elevated ethane concentrations, as ethane can be considered a tracer species for oil and natural gas activity. The data presented serve as baseline conditions for evaluation of impacts from future development of Marcellus or Utica shale gas reserves.

Noise suppression in surface microseismic data by τ-p transform

USGS Publications Warehouse

Forghani-Arani, Farnoush; Batzle, Mike; Behura, Jyoti; Willis, Mark; Haines, Seth; Davidson, Michael

2013-01-01

Surface passive seismic methods are receiving increased attention for monitoring changes in reservoirs during the production of unconventional oil and gas. However, in passive seismic data the strong cultural and ambient noise (mainly surface-waves) decreases the effectiveness of these techniques. Hence, suppression of surface-waves is a critical step in surface microseismic monitoring. We apply a noise suppression technique, based on the τ — p transform, to a surface passive seismic dataset recorded over a Barnett Shale reservoir undergoing a hydraulic fracturing process. This technique not only improves the signal-to-noise ratios of added synthetic microseismic events, but it also preserves the event waveforms.

Ex situ bioremediation of oil-contaminated soil.

PubMed

Lin, Ta-Chen; Pan, Po-Tsen; Cheng, Sheng-Shung

2010-04-15

An innovative bioprocess method, Systematic Environmental Molecular Bioremediation Technology (SEMBT) that combines bioaugmentation and biostimulation with a molecular monitoring microarray biochip, was developed as an integrated bioremediation technology to treat S- and T-series biopiles by using the landfarming operation and reseeding process to enhance the bioremediation efficiency. After 28 days of the bioremediation process, diesel oil (TPH(C10-C28)) and fuel oil (TPH(C10-C40)) were degraded up to approximately 70% and 63% respectively in the S-series biopiles. When the bioaugmentation and biostimulation were applied in the beginning of bioremediation, the microbial concentration increased from approximately 10(5) to 10(6) CFU/g dry soil along with the TPH biodegradation. Analysis of microbial diversity in the contaminated soils by microarray biochips revealed that Acinetobacter sp. and Pseudomonas aeruginosa were the predominant groups in indigenous consortia, while the augmented consortia were Gordonia alkanivorans and Rhodococcus erythropolis in both series of biopiles during bioremediation. Microbial respiration as influenced by the microbial activity reflected directly the active microbial population and indirectly the biodegradation of TPH. Field experimental results showed that the residual TPH concentration in the complex biopile was reduced to less than 500 mg TPH/kg dry soil. The above results demonstrated that the SEMBT technology is a feasible alternative to bioremediate the oil-contaminated soil. Crown Copyright 2009. Published by Elsevier B.V. All rights reserved.

77 FR 49489 - Oil and Natural Gas Sector: New Source Performance Standards and National Emission Standards for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-16

...This action finalizes the review of new source performance standards for the listed oil and natural gas source category. In this action the EPA revised the new source performance standards for volatile organic compounds from leaking components at onshore natural gas processing plants and new source performance standards for sulfur dioxide emissions from natural gas processing plants. The EPA also established standards for certain oil and gas operations not covered by the existing standards. In addition to the operations covered by the existing standards, the newly established standards will regulate volatile organic compound emissions from gas wells, centrifugal compressors, reciprocating compressors, pneumatic controllers and storage vessels. This action also finalizes the residual risk and technology review for the Oil and Natural Gas Production source category and the Natural Gas Transmission and Storage source category. This action includes revisions to the existing leak detection and repair requirements. In addition, the EPA has established in this action emission limits reflecting maximum achievable control technology for certain currently uncontrolled emission sources in these source categories. This action also includes modification and addition of testing and monitoring and related notification, recordkeeping and reporting requirements, as well as other minor technical revisions to the national emission standards for hazardous air pollutants. This action finalizes revisions to the regulatory provisions related to emissions during periods of startup, shutdown and malfunction.

Kinetic Evaluation of Lipid Oils Conversion to Biofuel Using Layered Double Hydroxide Doped with Triazabicyclodece Catalyst

NASA Astrophysics Data System (ADS)

Nato Lopez, Frank D.

Worldwide, there is an ever increasing need for sustainable, renewable fuels that will accommodate the rapidly increasing energy demand and provide independence from fossil fuels. The search for a sustainable alternative to petroleum based fuels has been a great challenge to the scientific community; therefore, great efforts are being made to overcome the fossil fuels dependence by exploring the prominent field of biofuels (bioethanol and biodiesel). Traditional biodiesel is produced from feedstocks such as vegetable oils and animal fats by converting the triglycerides with methanol in the presence of a homogeneous catalyst to produce fatty acid methyl esters (FAMEs). However, drawbacks of this process are the undesired glycerol byproduct and post reaction processing, including separation from reaction mixture, that results in high costs factors. In the present work, the reaction kinetics of a glycerol-free biodiesel method is studied. This method consists of the transesterification of a vegetable oil (i.e. canola oil) using dimethyl carbonate (DMC) as an alternative methylating agent in presence of layered double hydroxides doped with triazabicyclodecene catalyst (a basic organocatalyst). Furthermore, is theorized that this heterogeneous catalyst (TBD/LDH) simultaneously converts both FFAs and triglycerides due to acid sites formed by Al3+ active sites of the LDH structure. Additionally, the versatility of the Raman in situ technique was used as quantitative analysis tool to monitor the reaction kinetics and collect real time data.

[Evolution of technology and occupational exposures in petrochemical industry and in petroleum refining].

PubMed

Cottica, Danilo; Grignani, Elena

2013-01-01

The industry of oil refining and petrochemical play an important role in terms of number of employees in the Italian production. Often the terms "petroleum refining" and "petrochemical" are used interchangeably to define processes that occur in complex plants, which grow outdoors on large surfaces and a visual impact is not irrelevant. In reality, the two areas involve potential exposure to different chemical agents, related to raw materials processed and the specific products. The petrochemical uses as raw materials, the oil fractions, obtained by distillation in the refinery, or natural gas; petrochemical products are, usually, single compounds with a specific degree of purity, used as basic raw materials for the entire industry of organic chemistry, from the production of plastics to pharmaceuticals. The oil refining, that is the topic of this paper, processes mainly oil to obtain mixtures of hydrocarbon compounds, the products of which are specified on the basis of aptitude for use. For example gasolines, are obtained by mixing of fractions of the first distillation, reforming products, antiknock. The paper illustrates, necessarily broadly due to the complexity of the productive sectors, the technological and organizational changes that have led to a significant reduction of occupational exposure to chemical agents, the results of environmental monitoring carried out in some refineries both during routine conditions that during scheduled maintenance activities with plant shutdown and a store of petroleum products. The chemical agents measured are typical for presence, physico-chemical properties and toxicological characteristics of the manufacturing processes of petroleum products like benzene, toluene, xylenes, ethyl benzene, n-hexane, Volatile Hydrocarbons belonging to gasoline, kerosene, diesel fuel. Data related to both personal sampling and fixed positions.

Conductometric Sensors for Monitoring Degradation of Automotive Engine Oil†

PubMed Central

Latif, Usman; Dickert, Franz L.

2011-01-01

Conductometric sensors have been fabricated by applying imprinted polymers as receptors for monitoring engine oil quality. Titania and silica layers are synthesized via the sol-gel technique and used as recognition materials for acidic components present in used lubricating oil. Thin-film gold electrodes forming an interdigitated structure are used as transducers to measure the conductance of polymer coatings. Optimization of layer composition is carried out by varying the precursors, e.g., dimethylaminopropyltrimethoxysilane (DMAPTMS), and aminopropyl-triethoxysilane (APTES). Characterization of these sensitive materials is performed by testing against oil oxidation products, e.g., carbonic acids. The results depict that imprinted aminopropyltriethoxysilane (APTES) polymer is a promising candidate for detecting the age of used lubricating oil. In the next strategy, polyurethane-nanotubes composite as sensitive material is synthesized, producing appreciable differentiation pattern between fresh and used oils at elevated temperature with enhanced sensitivity. PMID:22164094

Monitoring of Olympic National Park Beaches to determine fate and effects of spilled bunker C fuel oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strand, J.A.; Cullinan, V.I.; Crecelius, E.A.

1990-10-01

On December 23, 1988, the barge Nestucca was accidentally struck by its tow, a Souse Brothers Towing Company tug, releasing approximately 230,000 gallons of Bunker C fuel oil and fouling beaches from Grays Harbor north to Vancouver Island. Affected beaches in Washington included a 40-mile-long strip that has been recently added to Olympic National Park. The purpose of the monitoring program documented in this report was to determine the fate of spilled Bunker C fuel oil on selected Washington coastal beaches. We sought to determine (1) how much oil remained in intertidal and shallow subtidal habitats following clean-up and weathering,more » (2) to what extent intertidal and/or shallow subtidal biotic assemblages have been contaminated, and (3) how rapidly the oil has left the ecosystem. 45 refs., 18 figs., 8 tabs.« less

Integrated Geophysical Monitoring Program to Study Flood Performance and Incidental CO2 Storage Associated with a CO2 EOR Project in the Bell Creek Oil Field

NASA Astrophysics Data System (ADS)

Burnison, S. A.; Ditty, P.; Gorecki, C. D.; Hamling, J. A.; Steadman, E. N.; Harju, J. A.

2013-12-01

The Plains CO2 Reduction (PCOR) Partnership, led by the Energy & Environmental Research Center, is working with Denbury Onshore LLC to determine the effect of a large-scale injection of carbon dioxide (CO2) into a deep clastic reservoir for the purpose of simultaneous CO2 enhanced oil recovery (EOR) and to study incidental CO2 storage at the Bell Creek oil field located in southeastern Montana. This project will reduce CO2 emissions by more than 1 million tons a year while simultaneously recovering an anticipated 30 million barrels of incremental oil. The Bell Creek project provides a unique opportunity to use and evaluate a comprehensive suite of technologies for monitoring, verification, and accounting (MVA) of CO2 on a large-scale. The plan incorporates multiple geophysical technologies in the presence of complementary and sometimes overlapping data to create a comprehensive data set that will facilitate evaluation and comparison. The MVA plan has been divided into shallow and deep subsurface monitoring. The deep subsurface monitoring plan includes 4-D surface seismic, time-lapse 3-D vertical seismic profile (VSP) surveys incorporating a permanent borehole array, and baseline and subsequent carbon-oxygen logging and other well-based measurements. The goal is to track the movement of CO2 in the reservoir, evaluate the recovery/storage efficiency of the CO2 EOR program, identify fluid migration pathways, and determine the ultimate fate of injected CO2. CO2 injection at Bell Creek began in late May 2013. Prior to injection, a monitoring and characterization well near the field center was drilled and outfitted with a distributed temperature-monitoring system and three down-hole pressure gauges to provide continuous real-time data of the reservoir and overlying strata. The monitoring well allows on-demand access for time-lapse well-based measurements and borehole seismic instrumentation. A 50-level permanent borehole array of 3-component geophones was installed in a second monitoring well. A pre-injection series of carbon-oxygen logging across the reservoir was acquired in 35 wells. The baseline 3-D surface seismic survey was acquired in September 2012. A 3-D VSP incorporating two wells and 2 square miles of overlapping seismic coverage in the middle of the field was acquired in May 2013. Initial iterations of geologic modeling and reservoir simulation of the field have been completed. Currently, passive seismic monitoring with the permanent borehole array is being conducted during injection. Interpretation results from the baseline surface 3-D survey and preliminary results from the baseline 3-D VSP are being evaluated and integrated into the reservoir model. The PCOR Partnership's philosophy is to combine site characterization, modeling, and monitoring strategies into an iterative process to produce descriptive integrated results. The comprehensive effort at Bell Creek will allow a comparison of the effectiveness of several complementary geophysical and well-based methods in meeting the goals of the deep subsurface monitoring effort.

Oil pollution signatures by remote sensing.

NASA Technical Reports Server (NTRS)

Catoe, C. E.; Mclean, J. T.

1972-01-01

Study of the possibility of developing an effective remote sensing system for oil pollution monitoring which would be capable of detecting oil films on water, mapping the areal extent of oil slicks, measuring slick thickness, and identifying the oil types. In the spectral regions considered (ultraviolet, visible, infrared, microwave, and radar), the signatures were sufficiently unique when compared to the background so that it was possible to detect and map oil slicks. Both microwave and radar techniques are capable of operating in adverse weather. Fluorescence techniques show promise in identifying oil types. A multispectral system will be required to detect oil, map its distribution, estimate film thickness, and characterize the oil pollutant.

33 CFR 157.12d - Technical specifications.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Design, Equipment, and Installation § 157.12d Technical specifications. (a) Oil discharge monitoring and... effectively under all environmental conditions normally encountered by oil tankers, and must be designed and... must be designed so a discharge of dirty-ballast or other oil-contaminated water from the cargo tank...

33 CFR 157.12d - Technical specifications.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Design, Equipment, and Installation § 157.12d Technical specifications. (a) Oil discharge monitoring and... effectively under all environmental conditions normally encountered by oil tankers, and must be designed and... must be designed so a discharge of dirty-ballast or other oil-contaminated water from the cargo tank...

Inadequate environmental monitoring around offshore oil and gas platforms on the Grand Bank of Eastern Canada: are risks to marine birds known?

PubMed

Burke, C M; Montevecchi, W A; Wiese, F K

2012-08-15

Petroleum exploration and production on the Grand Bank of eastern Canada overlaps with productive marine habitat that supports over 40 million marine birds annually. Environmental assessments for oil and gas projects in the region predict insignificant adverse effects on marine birds from oil spills, incineration in platform flares and collisions. Limited baseline data on seasonal occupancies and a failure to quantify the nature and extent of marine bird attraction to platforms and related mortality undermines these assessments. We conducted 22 surveys to offshore platforms on the Grand Bank during 1999-2003 to measure avian associations with platforms and to determine the level of monitoring needed to assess the risks to marine birds. We document seasonal shifts in marine bird occurrences and higher densities of auks (fall) and shearwaters (summer) around platforms relative to surrounding areas. The limited temporal and spatial coverage of our surveys is more robust than existing industry monitoring efforts, yet it is still inadequate to quantify the scale of marine bird associations with platforms or their associated mortality risks. Systematic observations by independent biologists on vessels and platforms are needed to generate reliable assessments of risks to marine birds. Instead, the regulatory body for offshore oil and gas in eastern Canada (Canada - Newfoundland and Labrador Offshore Petroleum Board; C-NLOPB) supports industry self-reporting as the accepted form of environmental monitoring. Conflicting responsibilities of oil and gas regulatory agencies for both energy development and environmental monitoring are major barriers to transparency, unbiased scientific inquiry and adequate environmental protection. Similar conflicts with the oil and gas regulatory body in the United States, the former Minerals and Management Service (MMS) were identified by the U.S. President as a major contributor to the Deepwater Horizon disaster in the Gulf of Mexico. The MMS has since been restructured into the Bureau of Ocean Energy Management, (BOEM) with separate departments responsible for drilling leases and the regulation of drilling activities. Similar restructuring of the oil and gas regulatory bodies in Canada is needed for better public information, scientific investigation and environmental protection in the offshore. Copyright © 2012 Elsevier Ltd. All rights reserved.

Use of Acetate, Propionate, and Butyrate for Reduction of Nitrate and Sulfate and Methanogenesis in Microcosms and Bioreactors Simulating an Oil Reservoir.

PubMed

Chen, Chuan; Shen, Yin; An, Dongshan; Voordouw, Gerrit

2017-04-01

Acetate, propionate, and butyrate (volatile fatty acids [VFA]) occur in oil field waters and are frequently used for microbial growth of oil field consortia. We determined the kinetics of use of these VFA components (3 mM each) by an anaerobic oil field consortium in microcosms containing 2 mM sulfate and 0, 4, 6, 8, or 13 mM nitrate. Nitrate was reduced first, with a preference for acetate and propionate. Sulfate reduction then proceeded with propionate (but not butyrate) as the electron donor, whereas the fermentation of butyrate (but not propionate) was associated with methanogenesis. Microbial community analyses indicated that Paracoccus and Thauera ( Paracoccus - Thauera ), Desulfobulbus , and Syntrophomonas - Methanobacterium were the dominant taxa whose members catalyzed these three processes. Most-probable-number assays showed the presence of up to 10 7 /ml of propionate-oxidizing sulfate-reducing bacteria (SRB) in waters from the Medicine Hat Glauconitic C field. Bioreactors with the same concentrations of sulfate and VFA responded similarly to increasing concentrations of injected nitrate as observed in the microcosms: sulfide formation was prevented by adding approximately 80% of the nitrate dose needed to completely oxidize VFA to CO 2 in both. Thus, this work has demonstrated that simple time-dependent observations of the use of acetate, propionate, and butyrate for nitrate reduction, sulfate reduction, and methanogenesis in microcosms are a good proxy for these processes in bioreactors, monitoring of which is more complex. IMPORTANCE Oil field volatile fatty acids acetate, propionate, and butyrate were specifically used for nitrate reduction, sulfate reduction, and methanogenic fermentation. Time-dependent analyses of microcosms served as a good proxy for these processes in a bioreactor, mimicking a sulfide-producing (souring) oil reservoir: 80% of the nitrate dose required to oxidize volatile fatty acids to CO 2 was needed to prevent souring in both. Our data also suggest that propionate is a good substrate to enumerate oil field SRB. Copyright © 2017 American Society for Microbiology.

The Mediterranean Decision Support System for Marine Safety dedicated to oil slicks predictions

NASA Astrophysics Data System (ADS)

Zodiatis, G.; De Dominicis, M.; Perivoliotis, L.; Radhakrishnan, H.; Georgoudis, E.; Sotillo, M.; Lardner, R. W.; Krokos, G.; Bruciaferri, D.; Clementi, E.; Guarnieri, A.; Ribotti, A.; Drago, A.; Bourma, E.; Padorno, E.; Daniel, P.; Gonzalez, G.; Chazot, C.; Gouriou, V.; Kremer, X.; Sofianos, S.; Tintore, J.; Garreau, P.; Pinardi, N.; Coppini, G.; Lecci, R.; Pisano, A.; Sorgente, R.; Fazioli, L.; Soloviev, D.; Stylianou, S.; Nikolaidis, A.; Panayidou, X.; Karaolia, A.; Gauci, A.; Marcati, A.; Caiazzo, L.; Mancini, M.

2016-11-01

In the Mediterranean sea the risk from oil spill pollution is high due to the heavy traffic of merchant vessels for transporting oil and gas, especially after the recent enlargement of the Suez canal and to the increasing coastal and offshore installations related to the oil industry in general. The basic response to major oil spills includes different measures and equipment. However, in order to strengthen the maritime safety related to oil spill pollution in the Mediterranean and to assist the response agencies, a multi-model oil spill prediction service has been set up, known as MEDESS-4MS (Mediterranean Decision Support System for Marine Safety). The concept behind the MEDESS-4MS service is the integration of the existing national ocean forecasting systems in the region with the Copernicus Marine Environmental Monitoring Service (CMEMS) and their interconnection, through a dedicated network data repository, facilitating access to all these data and to the data from the oil spill monitoring platforms, including the satellite data ones, with the well established oil spill models in the region. The MEDESS-4MS offer a range of service scenarios, multi-model data access and interactive capabilities to suite the needs of REMPEC (Regional Marine Pollution Emergency Response Centre for the Mediterranean Sea) and EMSA-CSN (European Maritime Safety Agency-CleanseaNet).

Evaluation of an oil-debris monitoring device for use in helicopter transmissions

NASA Technical Reports Server (NTRS)

Lewicki, David G.; Blanchette, Donald M.; Biron, Gilles

1992-01-01

Experimental tests were performed on an OH-58A helicopter main-rotor transmission to evaluate an oil-debris monitoring device (ODMD). The tests were performed in the NASA 500-hp Helicopter Transmission Test Stand. Five endurance tests were run as part of a U.S. Navy/NASA/Army advanced lubricants program. The tests were run at 100 percent design speed, 117-percent design torque, and 121 C (250 F) oil inlet temperature. Each test lasted between 29 and 122 hr. The oils that were used conformed to MIL-L-23699 and DOD-L-85734 specifications. One test produced a massive sun-gear fatigue failure; another test produced a small spall on one sun-gear tooth; and a third test produced a catastrophic planet-bearing cage failure. The ODMD results were compared with oil spectroscopy results. The capability of the ODMD to detect transmission component failures was not demonstrated. Two of the five tests produced large amounts of debris. For these two tests, two separate ODMD sensors failed, possibly because of prolonged exposure to relatively high oil temperatures. One test produced a small amount of debris and was not detected by the ODMD or by oil spectroscopy. In general, the ODMD results matched the oil spectroscopy results. The ODMD results were extremely sensitive to oil temperature and flow rate.

Oil Spill Map for Indian Sea Region based on Bhuvan- Geographic Information System using Satellite Images

NASA Astrophysics Data System (ADS)

Vijaya kumar, L. J.; Kishore, J. K.; Kesava Rao, P.; Annadurai, M.; Dutt, C. B. S.; Hanumantha Rao, K.; Sasamal, S. K.; Arulraj, M.; Prasad, A. V. V.; Kumari, E. V. S. Sita; Satyanarayana, S. N.; Shenoy, H. P.

2014-11-01

Oil spills in the ocean are a serious marine disaster that needs regular monitoring for environmental risk assessment and mitigation. Recent use of Polarimetric SAR imagery in near real time oil spill detection systems is associated with attempts towards automatic and unambiguous oil spill detection based on decomposition methods. Such systems integrate remote sensing technology, geo information, communication system, hardware and software systems to provide key information for analysis and decision making. Geographic information systems (GIS) like BHUVAN can significantly contribute to oil spill management based on Synthetic Aperture Radar (SAR) images. India has long coast line from Gujarat to Bengal and hundreds of ports. The increase in shipping also increases the risk of oil spills in our maritime zone. The availability of RISAT-1 SAR images enhances the scope to monitor oil spills and develop GIS on Bhuvan which can be accessed by all the users, such as ships, coast guard, environmentalists etc., The GIS enables realization of oil spill maps based on integration of the geographical, remote sensing, oil & gas production/infrastructure data and slick signatures detected by SAR. SAR and GIS technologies can significantly improve the realization of oil spill footprint distribution maps. Preliminary assessment shows that the Bhuvan promises to be an ideal solution to understand spatial, temporal occurrence of oil spills in the marine atlas of India. The oil spill maps on Bhuvan based GIS facility will help the ONGC and Coast Guard organization.

Flow cytometry: a promising technique for the study of silicone oil-induced particulate formation in protein formulations.

PubMed

Ludwig, D Brett; Trotter, Joseph T; Gabrielson, John P; Carpenter, John F; Randolph, Theodore W

2011-03-15

Subvisible particles in formulations intended for parenteral administration are of concern in the biopharmaceutical industry. However, monitoring and control of subvisible particulates can be complicated by formulation components, such as the silicone oil used for the lubrication of prefilled syringes, and it is difficult to differentiate microdroplets of silicone oil from particles formed by aggregated protein. In this study, we demonstrate the ability of flow cytometry to resolve mixtures comprising subvisible bovine serum albumin (BSA) aggregate particles and silicone oil emulsion droplets with adsorbed BSA. Flow cytometry was also used to investigate the effects of silicone oil emulsions on the stability of BSA, lysozyme, abatacept, and trastuzumab formulations containing surfactant, sodium chloride, or sucrose. To aid in particle characterization, the fluorescence detection capabilities of flow cytometry were exploited by staining silicone oil with BODIPY 493/503 and model proteins with Alexa Fluor 647. Flow cytometric analyses revealed that silicone oil emulsions induced the loss of soluble protein via protein adsorption onto the silicone oil droplet surface. The addition of surfactant prevented protein from adsorbing onto the surface of silicone oil droplets. There was minimal formation of homogeneous protein aggregates due to exposure to silicone oil droplets, although oil droplets with surface-adsorbed trastuzumab exhibited flocculation. The results of this study demonstrate the utility of flow cytometry as an analytical tool for monitoring the effects of subvisible silicone oil droplets on the stability of protein formulations. Copyright © 2010 Elsevier Inc. All rights reserved.

Applicability of spectral indices on thickness identification of oil slick

NASA Astrophysics Data System (ADS)

Niu, Yanfei; Shen, Yonglin; Chen, Qihao; Liu, Xiuguo

2016-10-01

Hyperspectral remote sensing technology has played a vital role in the identification and monitoring of oil spill events, and amount of spectral indices have been developed. In this paper, the applicability of six frequently-used indices is analyzed, and a combination of spectral indices in aids of support vector machine (SVM) algorithm is used to identify the oil slicks and corresponding thickness. The six spectral indices are spectral rotation (SR), spectral absorption depth (HI), band ratio of blue and green (BG), band ratio of BG and shortwave infrared index (BGN), 555nm and 645nm normalized by the blue band index (NB) and spectral slope (ND). The experimental study is conducted in the Gulf of Mexico oil spill zone, with Airborne Visible Infrared Imaging Spectrometer (AVIRIS) hyperspectral imagery captured in May 17, 2010. The results show that SR index is the best in all six indices, which can effectively distinguish the thickness of the oil slick and identify it from seawater; HI index and ND index can obviously distinguish oil slick thickness; BG, BGN and NB are more suitable to identify oil slick from seawater. With the comparison among different kernel functions of SVM, the classify accuracy show that the polynomial and RBF kernel functions have the best effect on the separation of oil slick thickness and the relatively pure seawater. The applicability of spectral indices of oil slick and the method of oil film thickness identification will in aids of oil/gas exploration and oil spill monitoring.

Research on visible and near infrared spectral-polarimetric properties of soil polluted by crude oil

NASA Astrophysics Data System (ADS)

Shen, Hui-yan; Zhou, Pu-cheng; Pan, Bang-long

2017-10-01

Hydrocarbon contaminated soil can impose detrimental effects on forest health and quality of agricultural products. To manage such consequences, oil leak indicators should be detected quickly by monitoring systems. Remote sensing is one of the most suitable techniques for monitoring systems, especially for areas which are uninhabitable and difficulty to access. The most available physical quantities in optical remote sensing domain are the intensity and spectral information obtained by visible or infrared sensors. However, besides the intensity and wavelength, polarization is another primary physical quantity associated with an optical field. During the course of reflecting light-wave, the surface of soil polluted by crude oil will cause polarimetric properties which are related to the nature of itself. Thus, detection of the spectralpolarimetric properties for soil polluted by crude oil has become a new remote sensing monitoring method. In this paper, the multi-angle spectral-polarimetric instrument was used to obtain multi-angle visible and near infrared spectralpolarimetric characteristic data of soil polluted by crude oil. And then, the change rule between polarimetric properties with different affecting factors, such as viewing zenith angle, incidence zenith angle of the light source, relative azimuth angle, waveband of the detector as well as different grain size of soil were discussed, so as to provide a scientific basis for the research on polarization remote sensing for soil polluted by crude oil.

Remote sensing detection of atmospheric pollutants using lidar, sodar and correlation with air quality data in an industrial area

NASA Astrophysics Data System (ADS)

Steffens, Juliana; da Costa, Renata F.; Landulfo, Eduardo; Guardani, Roberto; Moreira, Paulo F., Jr.; Held, Gerhard

2011-11-01

Optical remote sensing techniques have obvious advantages for monitoring gas and aerosol emissions, since they enable the operation over large distances, far from hostile environments, and fast processing of the measured signal. In this study two remote sensing devices, namely a Lidar (Light Detection and Ranging) for monitoring the vertical profile of backscattered light intensity, and a Sodar (Acoustic Radar, Sound Detection and Ranging) for monitoring the vertical profile of the wind vector were operated during specific periods. The acquired data were processed and compared with data of air quality obtained from ground level monitoring stations, in order to verify the possibility of using the remote sensing techniques to monitor industrial emissions. The campaigns were carried out in the area of the Environmental Research Center (Cepema) of the University of Sao Paulo, in the city of Cubatao, Brazil, a large industrial site, where numerous different industries are located, including an oil refinery, a steel plant, as well as fertilizer, cement and chemical/petrochemical plants. The local environmental problems caused by the industrial activities are aggravated by the climate and topography of the site, unfavorable to pollutant dispersion. Results of a campaign are presented for a 24- hour period, showing data of a Lidar, an air quality monitoring station and a Sodar.

A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, October 1--December 31, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robbins, G.A.; Brandes, S.D.; Winschel, R.A.

1995-05-01

The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A samplemore » bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. During this quarter, analyses were completed on 65 process samples from representative periods of HRI Run POC-2 in which coal, coal/plastics, and coal/rubber were the feedstocks. A sample of the oil phase of the oil/water separator from HRI Run POC-1 was analyzed to determine the types and concentrations of phenolic compounds. Chemical analyses and microautoclave tests were performed to monitor the oxidation and measure the reactivity of the standard coal (Old Ben Mine No. 1) which has been used for the last six years to determine solvent quality of process oils analyzed in this and previous DOE contracts.« less

Tank Level Detection Devices for the Carriage of Oil : Oil Pollution Act of 1990, Section 4110

DOT National Transportation Integrated Search

1992-12-29

This study was conducted to assess the technical feasibility of satisfying the requirements of Section 4110 of the Oil Pollution Act of 1990 (OPA 90), which calls for minimum regulatory standards tank level monitoring devices in teh cargo tanks of ta...

Detection and quantification of fugitive emissions from Colorado oil and gas production operations using remote monitoring

EPA Science Inventory

Western states contain vast amounts of oil and gas production. For example, Weld County Colorado contains approximately 25,000 active oil and gas well sites with associated production operations. There is little information on the air pollutant emission potential from this source...

40 CFR 63.9990 - What are the subcategories of EGUs?

Code of Federal Regulations, 2012 CFR

2012-07-01

... coal or gasified solid oil-derived fuel. For purposes of compliance, monitoring, recordkeeping, and...) National Emission Standards for Hazardous Air Pollutants: Coal- and Oil-Fired Electric Utility Steam... equal to 8,300 Btu/lb, and (2) EGUs designed for low rank virgin coal. (b) Oil-fired EGUs are...

40 CFR 63.9990 - What are the subcategories of EGUs?

Code of Federal Regulations, 2013 CFR

2013-07-01

... coal or gasified solid oil-derived fuel. For purposes of compliance, monitoring, recordkeeping, and...) National Emission Standards for Hazardous Air Pollutants: Coal- and Oil-Fired Electric Utility Steam... equal to 8,300 Btu/lb, and (2) EGUs designed for low rank virgin coal. (b) Oil-fired EGUs are...

40 CFR 63.9990 - What are the subcategories of EGUs?

Code of Federal Regulations, 2014 CFR

2014-07-01

... coal or gasified solid oil-derived fuel. For purposes of compliance, monitoring, recordkeeping, and...) National Emission Standards for Hazardous Air Pollutants: Coal- and Oil-Fired Electric Utility Steam... equal to 8,300 Btu/lb, and (2) EGUs designed for low rank virgin coal. (b) Oil-fired EGUs are...

40 CFR 63.10000 - What are my general requirements for complying with this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants: Coal- and Oil... of startup and shutdown; however, for coal-fired, liquid oil-fired, or solid oil-derived fuel-fired... associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and...

40 CFR 63.10000 - What are my general requirements for complying with this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants: Coal- and Oil... of startup and shutdown; however, for coal-fired, liquid oil-fired, or solid oil-derived fuel-fired... associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and...

The Assessment of Instruments for Detecting Surface Water Spills Associated with Oil and Gas Operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, Aubrey E.; Hopkinson, Leslie; Soeder, Daniel

Surface water and groundwater risks associated with unconventional oil and gas development result from potential spills of the large volumes of chemicals stored on-site during drilling and hydraulic fracturing operations, and the return to the surface of significant quantities of saline water produced during oil or gas well production. To better identify and mitigate risks, watershed models and tools are needed to evaluate the dispersion of pollutants in possible spill scenarios. This information may be used to determine the placement of in-stream water-quality monitoring instruments and to develop early-warning systems and emergency plans. A chemical dispersion model has been usedmore » to estimate the contaminant signal for in-stream measurements. Spills associated with oil and gas operations were identified within the Susquehanna River Basin Commission’s Remote Water Quality Monitoring Network. The volume of some contaminants was found to be sufficient to affect the water quality of certain drainage areas. The most commonly spilled compounds and expected peak concentrations at monitoring stations were used in laboratory experiments to determine if a signal could be detected and positively identified using standard water-quality monitoring equipment. The results were compared to historical data and baseline observations of water quality parameters, and showed that the chemicals tested do commonly affect water quality parameters. This work is an effort to demonstrate that hydrologic and water quality models may be applied to improve the placement of in-stream water quality monitoring devices. This information may increase the capability of early-warning systems to alert community health and environmental agencies of surface water spills associated with unconventional oil and gas operations.« less

An improved RST approach for timely alert and Near Real Time monitoring of oil spill disasters by using AVHRR data

NASA Astrophysics Data System (ADS)

Grimaldi, C. S. L.; Casciello, D.; Coviello, I.; Lacava, T.; Pergola, N.; Tramutoli, V.

2011-05-01

Information acquired and provided in Near Real Time is fundamental in contributing to reduce the impact of different sea pollution sources on the maritime environment. Optical data acquired by sensors aboard meteorological satellites, thanks to their high temporal resolution as well as to their delivery policy, can be profitably used for a Near Real Time sea monitoring, provided that accurate and reliable methodologies for analysis and investigation are designed, implemented and fully assessed. In this paper, the results achieved by the application of an improved version of RST (Robust Satellite Technique) to oil spill detection and monitoring will be shown. In particular, thermal infrared data acquired by the NOAA-AVHRR (National Oceanic and Atmospheric Administration-Advanced Very High Resolution Radiometer) have been analyzed and a new RST-based change detection index applied to the case of the oil spills that occurred off the Kuwait and Saudi Arabian coasts in January 1991 and during the Lebanon War in July 2006. The results obtained, even in comparison with those achieved by other AVHRR-based techniques, confirm the unique performance of the proposed approach in automatically detecting the presence of oil spill with a high level of reliability and sensitivity. Moreover, the potential of the extension of the proposed technique to sensors onboard geostationary satellites will be discussed within the context of oil spill monitoring systems, integrating products generated by high temporal (optical) and high spatial (radar) resolution satellite systems.

Concept of an advanced hyperspectral remote sensing system for pipeline monitoring

NASA Astrophysics Data System (ADS)

Keskin, Göksu; Teutsch, Caroline D.; Lenz, Andreas; Middelmann, Wolfgang

2015-10-01

Areas occupied by oil pipelines and storage facilities are prone to severe contamination due to leaks caused by natural forces, poor maintenance or third parties. These threats have to be detected as quickly as possible in order to prevent serious environmental damage. Periodical and emergency monitoring activities need to be carried out for successful disaster management and pollution minimization. Airborne remote sensing stands out as an appropriate choice to operate either in an emergency or periodically. Hydrocarbon Index (HI) and Hydrocarbon Detection Index (HDI) utilize the unique absorption features of hydrocarbon based materials at SWIR spectral region. These band ratio based methods require no a priori knowledge of the reference spectrum and can be calculated in real time. This work introduces a flexible airborne pipeline monitoring system based on the online quasi-operational hyperspectral remote sensing system developed at Fraunhofer IOSB, utilizing HI and HDI for oil leak detection on the data acquired by an SWIR imaging sensor. Robustness of HI and HDI compared to state of the art detection algorithms is evaluated in an experimental setup using a synthetic dataset, which was prepared in a systematic way to simulate linear mixtures of selected background and oil spectra consisting of gradually decreasing percentages of oil content. Real airborne measurements in Ettlingen, Germany are used to gather background data while the crude oil spectrum was measured with a field spectrometer. The results indicate that the system can be utilized for online and offline monitoring activities.

Acute toxicity of Corexit EC9500A and assessment of dioctyl sulfosuccinate as an indicator for monitoring four oil dispersants applied to diluted bitumen.

PubMed

MacInnis, Ceara Y; Brunswick, Pamela; Park, Grace H; Buday, Craig; Schroeder, Grant; Fieldhouse, Ben; Brown, Carl E; van Aggelen, Graham; Shang, Dayue

2018-05-01

The present study investigated oil dispersant toxicity to fish species typical of the cooler regions of Canada, together with less well-documented issues pertaining to oil dispersant monitoring. The oil dispersant toxicity of Corexit EC9500A was assessed for the freshwater fish species rainbow trout and the seawater species coho, chinook, and chum, with a final median lethal concentration (LC50) acute lethality range between 35.3 and 59.8 mg/L. The LC50 range was calculated using confirmed 0-h dispersant concentrations that were justified by fish mortality within the first 24 h of exposure and by variability of the dispersant indicator dioctyl sulfosuccinate (DOSS) used to monitor concentrations at later time points. To investigate DOSS as an oil dispersant indicator in the environment, microcosm systems were prepared containing Corexit EC9500A, Finasol OSR52, Slickgone NS, and Slickgone EW dispersants together with diluted bitumen. The DOSS indicator recovery was found to be stable for up to 13 d at 5 °C, 8 d at 10 °C, but significantly less than 8 d at ≥15 °C. After 3 d at temperatures ≥15 °C, the DOSS indicator recovery became less accurate and was dependent on multiple environmental factors including temperature, microbial activity, and aeration, with potential for loss of solvents and stabilizers. A final assessment determined DOSS to be a discrepant indicator for long-term monitoring of oil dispersant in seawater. Environ Toxicol Chem 2018;37:1309-1319. © 2018 SETAC. © 2018 SETAC.

Air Monitoring Data for BP Spill/Deepwater Horizon

EPA Pesticide Factsheets

The Deepwater Horizon oil spill (also referred to as the BP oil spill) began on 20 April 2010 in the Gulf of Mexico on the BP-operated Macondo Prospect. Following the explosion and sinking of the Deepwater Horizon oil rig, a sea-floor oil gusher flowed for 87 days, until it was capped on 15 July 2010.In response to the BP oil spill, EPA sampled air, water, sediment, and waste generated by the cleanup operations.

Environmental Impacts and Recovery After the Hebei Spirit Oil Spill in Korea.

PubMed

Yim, U H; Khim, J S; Kim, M; Jung, J-H; Shim, W J

2017-07-01

The Hebei Spirit oil spill (HSOS) on December 7, 2007 was the worst oil spill recorded in Korea, with the release of approximately 10,900 tons of crude oil and 375 km of coastline polluted along the west coast of Korea. Cleanup operation was conducted by official and contract responders as well as volunteers for massive oil containment and removal of heavy accumulations of stranded oil. Together with the oil cleanup, a long-term environmental impact assessment (EIA) of the HSOS was initiated based on the Marine Environmental Management Act, which covers oil contamination in a multimedia environment, toxic effects on organisms, and ecosystem injury. This review summarizes the long-term monitoring results of HSOS EIA focused on (1) pollution status of seawater, sediment, and bivalves, (2) ecotoxicological effects, and (3) ecosystem recovery. Overall, concentrations of petroleum hydrocarbons in the environment indicated that their concentrations were well down to at or near background or pre-spill contamination levels at most sites after 1 year. The potential toxic effects of residual oils in sediments have decreased to background levels in most coastal areas of Taean. The entire ecosystem in the most affected area of the Taean coasts appear to be considerably, but not fully, recovered at present, namely after 8 years of the HSOS. The presence of lingering oil and elevated contamination levels at several sites still require continuous long-term monitoring.

Long-term monitoring data to describe the fate of polycyclic aromatic hydrocarbons in Deepwater Horizon oil submerged off Alabama's beaches.

PubMed

Yin, Fang; John, Gerald F; Hayworth, Joel S; Clement, T Prabhakar

2015-03-01

The 2010 Deepwater Horizon (DWH) catastrophe had considerable impact on the ∼ 50 km long sandy beach system located along the Alabama shoreline. We present a four-year dataset to characterize the temporal evolution of various polycyclic aromatic hydrocarbons (PAHs) and their alkylated homologs trapped in the residual oil buried along the shoreline. Field samples analyzed include the first arrival oil collected from Perdido Bay, Alabama in June 2010, and multiple oil spill samples collected until August 2014. Our field data show that, as of August 2014, DWH oil is still trapped along Alabama's beaches as submerged oil, predominately in the form of surface residual oil balls (SRBs). Chemical characterization data show that various PAHs present in the spilled oil (MC252 crude) weathered by about 45% to 100% when the oil was floating over the open ocean system in the Gulf of Mexico. Light PAHs, such as naphthalenes, were fully depleted, whereas heavy PAHs, such as chrysenes, were only partially depleted by about 45%. However, the rate of PAH weathering appears to have decreased significantly once the oil was buried within the partially-closed SRB environment. Concentration levels of several heavy PAHs have almost remained constant over the past 4 years. Our data also show that evaporation was most likely the primary weathering mechanism for PAH removal when the oil was floating over the ocean, although photo-degradation and other physico-chemical processes could have contributed to some additional weathering. Chemical data presented in this study indicate that submerged oil containing various heavy PAHs (for example, parent and alkylated chrysenes) is likely to remain in the beach system for several years. It is also likely that the organisms living in these beach environments would have an increased risk of exposure to heavy PAHs trapped in the non-recoverable form of buried DWH oil spill residues. Copyright © 2014 Elsevier B.V. All rights reserved.

Effects of a chemical dispersant and crude oil on breeding ducks

USGS Publications Warehouse

Albers, P.H.; Gay, M.L.

1982-01-01

Effects of chemically dispersed crude oil on mallard reproduction. Incubating female mallards were exposed to a water source treated with either Prudhoe Bay crude oil, Corexit 9527, or a combination of oil and dispersant during the first 10 da of development. Used thermocouple probes to monitor incubation temperature. Measured hatching success, incubation temperature, and survival of ducklings to 1 wk of age.

Graphene deposited onto aligned zinc oxide nanorods as an efficient coating for headspace solid-phase microextraction of gasoline fractions from oil samples.

PubMed

Wen, Congying; Li, Mengmeng; Li, Wangbo; Li, Zizhou; Duan, Wei; Li, Yulong; Zhou, Jie; Li, Xiyou; Zeng, Jingbin

2017-12-29

The content of gasoline fraction in oil samples is not only an important indicator of oil quality, but also an indispensable fundamental data for oil refining and processing. Before its determination, efficient preconcentration and separation of gasoline fractions from complicated matrices is essential. In this work, a thin layer of graphene (G) was deposited onto oriented ZnO nanorods (ZNRs) as a SPME coating. By this approach, the surface area of G was greatly enhanced by the aligned ZNRs, and the surface polarity of ZNRs was changed from polar to less polar, which were both beneficial for the extraction of gasoline fractions. In addition, the ZNRs were well protected by the mechanically and chemically stable G, making the coating highly durable for use. With headspace SPME (HS-SPME) mode, the G/ZNRs coating can effectively extract gasoline fractions from various oil samples, whose extraction efficiency achieved 1.5-5.4 and 2.1-8.2 times higher than those of a G and commercial 7-μm PDMS coating respectively. Coupled with GC-FID, the developed method is sensitive, simple, cost effective and easily accessible for the analysis of gasoline fractions. Moreover, the method is also feasible for the detection of gasoline markers in simulated oil-polluted water, which provides an option for the monitoring of oil spill accident. Copyright © 2017 Elsevier B.V. All rights reserved.

Bacterial community changes during bioremediation of aliphatic hydrocarbon-contaminated soil.

PubMed

Militon, Cécile; Boucher, Delphine; Vachelard, Cédric; Perchet, Geoffrey; Barra, Vincent; Troquet, Julien; Peyretaillade, Eric; Peyret, Pierre

2010-12-01

The microbial community response during the oxygen biostimulation process of aged oil-polluted soils is poorly documented and there is no reference for the long-term monitoring of the unsaturated zone. To assess the potential effect of air supply on hydrocarbon fate and microbial community structure, two treatments (0 and 0.056 mol h⁻¹ molar flow rate of oxygen) were performed in fixed bed reactors containing oil-polluted soil. Microbial activity was monitored continuously over 2 years throughout the oxygen biostimulation process. Microbial community structure before and after treatment for 12 and 24 months was determined using a dual rRNA/rRNA gene approach, allowing us to characterize bacteria that were presumably metabolically active and therefore responsible for the functionality of the community in this polluted soil. Clone library analysis revealed that the microbial community contained many rare phylotypes. These have never been observed in other studied ecosystems. The bacterial community shifted from Gammaproteobacteria to Actinobacteria during the treatment. Without aeration, the samples were dominated by a phylotype linked to the Streptomyces. Members belonging to eight dominant phylotypes were well adapted to the aeration process. Aeration stimulated an Actinobacteria phylotype that might be involved in restoring the ecosystem studied. Phylogenetic analyses suggested that this phylotype is a novel, deep-branching member of the Actinobacteria related to the well-studied genus Acidimicrobium. FEMS Microbiology Ecology © 2010 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. No claim to original French government works.

Analysis of oxidised heavy paraffininc products by high temperature comprehensive two-dimensional gas chromatography.

PubMed

Potgieter, H; Bekker, R; Beigley, J; Rohwer, E

2017-08-04

Heavy petroleum fractions are produced during crude and synthetic crude oil refining processes and they need to be upgraded to useable products to increase their market value. Usually these fractions are upgraded to fuel products by hydrocracking, hydroisomerization and hydrogenation processes. These fractions are also upgraded to other high value commercial products like lubricant oils and waxes by distillation, hydrogenation, and oxidation and/or blending. Oxidation of hydrogenated heavy paraffinic fractions produces high value products that contain a variety of oxygenates and the characterization of these heavy oxygenates is very important for the control of oxidation processes. Traditionally titrimetric procedures are used to monitor oxygenate formation, however, these titrimetric procedures are tedious and lack selectivity toward specific oxygenate classes in complex matrices. Comprehensive two-dimensional gas chromatography (GC×GC) is a way of increasing peak capacity for the comprehensive analysis of complex samples. Other groups have used HT-GC×GC to extend the carbon number range attainable by GC×GC and have optimised HT-GC×GC parameters for the separation of aromatics, nitrogen-containing compounds as well as sulphur-containing compounds in heavy petroleum fractions. HT-GC×GC column combinations for the separation of oxygenates in oxidised heavy paraffinic fractions are optimised in this study. The advantages of the HT-GC×GC method in the monitoring of the oxidation reactions of heavy paraffinic fraction samples are illustrated. Copyright © 2017 Elsevier B.V. All rights reserved.

Factors Governing the Germination of Sulfate-Reducing Desulfotomaculum Endospores Involved in Oil Reservoir Souring.

NASA Astrophysics Data System (ADS)

Sherry, A.; Bell, E.; Cueto, G.; Suarez-Suarez, A.; Pilloni, G.; Hubert, C. R.

2015-12-01

Reservoir souring is caused by the activity of sulfate-reducing microorganisms (SRM) in subsurface oil reservoirs, and is often induced by seawater injection during secondary oil recovery. Souring can potentially contribute to corrosion of infrastructure, health and safety hazards to the workforce, and reduction in value by increasing refining costs associated with producing the oil resource. Souring causes annual losses in the billions of dollars to the oil industry. Endospore-forming SRM, such as Desulfotomaculum spp., are often suspected culprits in reservoir souring. Endospores can survive unfavourable conditions for long periods, yet remain poised to germinate and become active if conditions become more favourable. Factors governing endospore germination are poorly understood, but are thought to include availability of nutrients, possibly metabolic by products of other anaerobic bioprocesses, and/or variations in temperature. Most research has focused on aerobic Bacillus spp., with very few studies dedicated to spore germination among anaerobes (order Clostridiales) including the sulfate-reducing Desulfotomaculum found in anoxic subsurface petroleum reservoirs. For Desulfotomaculum spores in deep hot oil reservoirs, cold seawater introduction during secondary oil recovery may create thermal viability zones for sulfate reduction near the injection wellbore. To evaluate these processes, sulfate-containing microcosms were prepared with different marine sediments as a source of spores, and amended with organic substrates in the presence or absence of oil. Incubation at 80°C for six days was followed by a down-shift in temperature to 60°C to mimic cold seawater injection into a hot reservoir. Souring did not occur at 80°C, but commenced within hours at 60°C. Microcosms were monitored for sulfate reduction and organic acids in combination with next generation sequencing of 16S rRNA genes (Ion Torrent, Illumina MiSeq). Through a combination of high-throughput microbial DNA sequencing and geochemical process analyses we show that altered conditions in oil reservoirs during seawater flooding activates dormant Desulfotomaculum endospores, which leads to reservoir souring, and provide insights on the factors governing the germination of endospores in the deep hot biosphere.

Comparison of the SidePak personal monitor with the Aerosol Particle Sizer (APS).

PubMed

Sánchez Jiménez, Araceli; van Tongeren, Martie; Galea, Karen S; Steinsvåg, Kjersti; MacCalman, Laura; Cherrie, John W

2011-06-01

The aim of this study was to compare the performance of the TSI Aerodynamic Particle Sizer (APS) and the TSI portable photometer SidePak to measure airborne oil mist particulate matter (PM) with aerodynamic diameters below 10 μm, 2.5 μm and 1 μm (PM(10), PM(2.5) and PM(1)). Three SidePaks each fitted with either a PM(10), PM(2.5) or a PM(1) impactor and an APS were run side by side in a controlled chamber. Oil mist from two different mineral oils and two different drilling fluid systems commonly used in offshore drilling technologies were generated using a nebulizer. Compared to the APS, the SidePaks overestimated the concentration of PM(10) and PM(2.5) by one order of magnitude and PM(1) concentrations by two orders of magnitude after exposure to oil mist for 3.3-6.5 min at concentrations ranging from 0.003 to 18.1 mg m(-3) for PM(10), 0.002 to 3.96 mg m(-3) for PM(2.5) and 0.001 to 0.418 mg m(-3) for PM(1) (as measured by the APS). In a second experiment a SidePak monitor previously exposed to oil mist overestimated PM(10) concentrations by 27% compared to measurements from another SidePak never exposed to oil mist. This could be a result of condensation of oil mist droplets in the optical system of the SidePak. The SidePak is a very useful instrument for personal monitoring in occupational hygiene due to its light weight and quiet pump. However, it may not be suitable for the measurement of particle concentrations from oil mist.

Development of a field testing protocol for identifying Deepwater Horizon oil spill residues trapped near Gulf of Mexico beaches.

PubMed

Han, Yuling; Clement, T Prabhakar

2018-01-01

The Deepwater Horizon (DWH) accident, one of the largest oil spills in U.S. history, contaminated several beaches located along the Gulf of Mexico (GOM) shoreline. The residues from the spill still continue to be deposited on some of these beaches. Methods to track and monitor the fate of these residues require approaches that can differentiate the DWH residues from other types of petroleum residues. This is because, historically, the crude oil released from sources such as natural seeps and anthropogenic discharges have also deposited other types of petroleum residues on GOM beaches. Therefore, identifying the origin of these residues is critical for developing effective management strategies for monitoring the long-term environmental impacts of the DWH oil spill. Advanced fingerprinting methods that are currently used for identifying the source of oil spill residues require detailed laboratory studies, which can be cost-prohibitive. Also, most agencies typically use untrained workers or volunteers to conduct shoreline monitoring surveys and these worker will not have access to advanced laboratory facilities. Furthermore, it is impractical to routinely fingerprint large volumes of samples that are collected after a major oil spill event, such as the DWH spill. In this study, we propose a simple field testing protocol that can identify DWH oil spill residues based on their unique physical characteristics. The robustness of the method is demonstrated by testing a variety of oil spill samples, and the results are verified by characterizing the samples using advanced chemical fingerprinting methods. The verification data show that the method yields results that are consistent with the results derived from advanced fingerprinting methods. The proposed protocol is a reliable, cost-effective, practical field approach for differentiating DWH residues from other types of petroleum residues.

Development of a field testing protocol for identifying Deepwater Horizon oil spill residues trapped near Gulf of Mexico beaches

PubMed Central

Han, Yuling

2018-01-01

The Deepwater Horizon (DWH) accident, one of the largest oil spills in U.S. history, contaminated several beaches located along the Gulf of Mexico (GOM) shoreline. The residues from the spill still continue to be deposited on some of these beaches. Methods to track and monitor the fate of these residues require approaches that can differentiate the DWH residues from other types of petroleum residues. This is because, historically, the crude oil released from sources such as natural seeps and anthropogenic discharges have also deposited other types of petroleum residues on GOM beaches. Therefore, identifying the origin of these residues is critical for developing effective management strategies for monitoring the long-term environmental impacts of the DWH oil spill. Advanced fingerprinting methods that are currently used for identifying the source of oil spill residues require detailed laboratory studies, which can be cost-prohibitive. Also, most agencies typically use untrained workers or volunteers to conduct shoreline monitoring surveys and these worker will not have access to advanced laboratory facilities. Furthermore, it is impractical to routinely fingerprint large volumes of samples that are collected after a major oil spill event, such as the DWH spill. In this study, we propose a simple field testing protocol that can identify DWH oil spill residues based on their unique physical characteristics. The robustness of the method is demonstrated by testing a variety of oil spill samples, and the results are verified by characterizing the samples using advanced chemical fingerprinting methods. The verification data show that the method yields results that are consistent with the results derived from advanced fingerprinting methods. The proposed protocol is a reliable, cost-effective, practical field approach for differentiating DWH residues from other types of petroleum residues. PMID:29329313

The Utility of SAR to Monitor Ocean Processes.

DTIC Science & Technology

1981-11-01

echo received from ocean waves include the motion of the a horizontally polarized wave will have its E vector parallel to scattering surfaces, the so...radiation is defined by the direction of the electric field intensity, E, vector . For example, a horizontally polarized wave will have its E vector ...Oil Spill Off the East Coast of the United States ................ .... 55 19. L-band Parallel and Cross Polarized SAR Imagery of Ice in the Beaufort

Contactless laser viscometer for flowing liquid films

NASA Astrophysics Data System (ADS)

Michels, Alexandre F.; Menegotto, Thiago; Grieneisen, Hans-Peter; Horowitz, Flavio

2005-12-01

This work briefly reviews recent progress in interferometric monitoring of spin and of dip coating, from a unified point of view, and its application for contactless viscometry of liquid films. Considering the associated models and measurement uncertainties, the method was validated for both coating processes with oil standards of known viscosities and constant refractive indices. Limitations and perspectives for application of the laser viscometer to liquid films with a varying refractive index are also discussed.

Transmission Bearing Damage Detection Using Decision Fusion Analysis

NASA Technical Reports Server (NTRS)

Dempsey, Paula J.; Lewicki, David G.; Decker, Harry J.

2004-01-01

A diagnostic tool was developed for detecting fatigue damage to rolling element bearings in an OH-58 main rotor transmission. Two different monitoring technologies, oil debris analysis and vibration, were integrated using data fusion into a health monitoring system for detecting bearing surface fatigue pitting damage. This integrated system showed improved detection and decision-making capabilities as compared to using individual monitoring technologies. This diagnostic tool was evaluated by collecting vibration and oil debris data from tests performed in the NASA Glenn 500 hp Helicopter Transmission Test Stand. Data was collected during experiments performed in this test rig when two unanticipated bearing failures occurred. Results show that combining the vibration and oil debris measurement technologies improves the detection of pitting damage on spiral bevel gears duplex ball bearings and spiral bevel pinion triplex ball bearings in a main rotor transmission.

Geochemical typing of crude oils from the Gulf of Thailand and the Natuna Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shiefelbein, C.; Haven, H.L.T.

The geochemical characteristics of approximately thirty oils from the Gulf of Thailand and Natuna Sea have been measured, viz., sulfur, vanadium and nickel content, density, [sup 13]C isotopes of the isolated aliphatic and aromatic hydrocarbon fractions, capillary gas chromatography of the whole oil, and gas chromatography-mass spectrometry (GC-MS). The GC-MS analysis included the classical monitoring of specific ions (SIM mode) as well as sophisticated multiple reaction monitoring (MRM) measurements (MRM mode). These latter analyses are of key importance for the detection of 24-propylsteranes, a prerequisite for the discrimination between lacustrine/deltaic oils vs. marine crude oils. Classification of the different typesmore » of oil families encountered in this region was based on visual inspection of the data, supported by multivariate statistical analysis. In the Gulf of Thailand, which includes oils from the Pattani trough and the northern part of the Malay basin, essentially three different types are recognized, generated by lacustrine, resinous, and carbonate source rocks. The situation encountered in the Natuna sea, including oils from the southern part of the Malay basin (Indonesia), the Penyu basin, and the west and east Natuna basins is almost similar to the same suite of different oil types. Although the geochemical characteristics of the resinous-derived oils are more or less similar in all basins, the lacustrine-derived oils exhibit large variations especially expressed in their isotopic signature. Interestingly, the carbonate-sourced oils from the east Natuna basin show characteristics that resemble those of the main oil family found offshore northwest Palawan.« less

Oil Spill Disasters Detection and Monitoring by RST Analysis of Optical Satellite Radiances: the Case of Deepwater Horizon Platform in the Gulf of Mexico

NASA Astrophysics Data System (ADS)

Pergola, N.; Grimaldi, S. C.; Coviello, I.; Faruolo, M.; Lacava, T.; Tramutoli, V.

2010-12-01

Marine oil spill disasters may have devastating effects on the marine and coastal environment. For monitoring and mitigation purposes, timely detection and continuously updated information on polluted areas are required. Satellite remote sensing can give a significant contribution in such a direction. Nowadays, SAR (Synthetic Aperture Radar) technology has been recognized as the most efficient for oil spill detection and mapping, thanks to the high spatial resolution and all-time/all-weather capability of the present operational sensors. Anyway, the present SARs revisiting time does not allow for a rapid detection and a near real-time monitoring of these phenomena at global scale. Passive optical sensors, on board meteorological satellites, thanks to their high temporal resolution (from a few hours to 15 minutes, depending on the characteristics of the platform/sensor), may represent, at this moment, a suitable SAR alternative/complement for oil spill detection and monitoring. Up to now, some techniques, based on optical satellite data, have been proposed for “a posteriori” mapping of already known oil spill discharges. On the other hand, reliable satellite methods for an automatic and timely detection of oil spills, for surveillance and warning purposes, are still currently missing. Recently, an innovative technique for automatic and near real time oil spill detection and monitoring has been proposed. The technique is based on the general RST (Robust Satellite Technique) approach which exploits multi-temporal satellite records in order to obtain a former characterization of the measured signal, in terms of expected value and natural variability, providing a further identification of signal anomalies by an automatic, unsupervised change detection step. Results obtained by using AVHRR (Advanced Very High Resolution Radiometer) Thermal Infrared data, in different geographic areas and observational conditions, demonstrated excellent detection capabilities both in term of sensitivity (to the presence even of thin/old oil films) and reliability (up to zero occurrence of false alarms), mainly due to the RST invariance regardless of local and environmental conditions. Exploiting its complete independence on the specific satellite platform, RST approach has been successfully exported to the Moderate Resolution Imaging Spectroradiometer (MODIS) aboard Terra and Aqua satellites. In this paper, results obtained applying the proposed methodology to the recent oil spill disaster of Deepwater Horizon Platform in the gulf of Mexico, that discharged over 5 million barrels (550 million litres) in the ocean, will be shown. A dense temporal series of RST-based oil spill maps, obtained by using MODIS TIR records, are commented, emphasizing and discussing main peculiarities and specific characteristics of this event. Preliminary findings, possible residual limits and future perspectives will be also presented and discussed.

[Monitoring of public health in the Kashagan oil and gas field].

PubMed

Kenessariev, U I; Zinulin, U Z; Yerzhanova, A E; Amrin, M K; Aybasova, Zh A

According to explored hydrocarbon reserves the Republic of Kazakhstan (RK) is among ten top countries rich in oil deposits. In connection with the intensive development of oil and gas industry environmental protection and public health issues became subject of a great interest from both scientists ’ and health practitioners ’ side. Results of the study included in this article are devoted to the study of health of the population, living near the “Bolashak” installation of complex preparation of oil and gas. There is a preliminary oil refining process coming from the Kashagan field and its further export. Analysis proved air pollution to be the one of the major risk factors for the health of the residing people. In the area there are problems of fresh water supply and frequent accidents at sewage plants. Landfills for municipal solid waste does not meet sanitary standards. The health care system of Makat district is characterized by uncompleted personnel and lack of beds. Indices of the mortality rate over the study period declined by 28.8%. As a result, population growth over the study the period was characterized by a tendency to increase. In 2013 population sought medical advice due to respiratory diseases, injuries and poisoning, diseases of blood and hemopoietic organs, diseases of the skin and subcutaneous tissue and nervous system.

Kernel parameter variation-based selective ensemble support vector data description for oil spill detection on the ocean via hyperspectral imaging

NASA Astrophysics Data System (ADS)

Uslu, Faruk Sukru

2017-07-01

Oil spills on the ocean surface cause serious environmental, political, and economic problems. Therefore, these catastrophic threats to marine ecosystems require detection and monitoring. Hyperspectral sensors are powerful optical sensors used for oil spill detection with the help of detailed spectral information of materials. However, huge amounts of data in hyperspectral imaging (HSI) require fast and accurate computation methods for detection problems. Support vector data description (SVDD) is one of the most suitable methods for detection, especially for large data sets. Nevertheless, the selection of kernel parameters is one of the main problems in SVDD. This paper presents a method, inspired by ensemble learning, for improving performance of SVDD without tuning its kernel parameters. Additionally, a classifier selection technique is proposed to get more gain. The proposed approach also aims to solve the small sample size problem, which is very important for processing high-dimensional data in HSI. The algorithm is applied to two HSI data sets for detection problems. In the first HSI data set, various targets are detected; in the second HSI data set, oil spill detection in situ is realized. The experimental results demonstrate the feasibility and performance improvement of the proposed algorithm for oil spill detection problems.

Assessment of the use of space technology in the monitoring of oil spills and ocean pollution: Executive summary

NASA Technical Reports Server (NTRS)

Alvarado, U. R. (Editor)

1980-01-01

The adequacy of current technology in terms of stage of maturity, of sensing, support systems, and information extraction was assessed relative to oil spills, waste pollution, and inputs to pollution trajectory models. Needs for advanced techniques are defined and the characteristics of a future satellite system are determined based on the requirements of U.S. agencies involved in pollution monitoring.

Land Disturbance Associated with Oil and Gas Development and Effects of Development-Related Land Disturbance on Dissolved-Solids Loads in Streams in the Upper Colorado River Basin, 1991, 2007, and 2025

USGS Publications Warehouse

Buto, Susan G.; Kenney, Terry A.; Gerner, Steven J.

2010-01-01

Oil and gas resource development in the Upper Colorado River Basin (UCRB) has increased substantially since the year 2000. The UCRB encompasses several significant oil and gas producing areas that have the potential for continued oil and gas resource development. Land disturbance associated with oil and gas resource development is caused by activities related to constructing drill pads to contain drilling and well maintenance equipment and roads to access the drill pad. Land disturbed by oil and gas development has the potential to cause increased erosion, stream degradation, habitat fragmentation and alteration, and increase public use of areas that may be environmentally sensitive. Land disturbance resulting from oil and gas resource development has not been monitored and mapped on a regional scale in the UCRB. However, information on the location and age of oil and gas wells in the UCRB is available. These data combined with geographic data analysis and modeling techniques were used to estimate the total area of disturbed land associated with oil and gas resource development in 1991 and in 2007 in the UCRB. Additional information about anticipated oil and gas development in the UCRB was used to project land disturbance to the year 2025. Results of the analysis indicate that approximately 117,500 acres (183 mi2) of total land disturbance was associated with drill pads and related roads in the UCRB in 1991. The estimated area of disturbed land associated with oil and gas development increased 53 percent to 179,400 acres (280 mi2) in 2007. Projecting oil and gas development through 2025 results in a potential near doubling of the land surface disturbance to approximately 319,300 acres (500 mi2). Estimated land disturbance for 1991 and 2007 were input to a contaminant transport model developed for the UCRB to assess the statistical significance of energy-related land disturbance to contributing dissolved solids to basin streams. The statistical assessment was an observational study based on an existing model and available water-quality monitoring data for the basin. No new data were collected for the analysis. The source coefficient calibrated for the disturbed lands associated with oil and gas development in 2007 was zero, which indicated that estimated land disturbance from oil and gas development is not statistically significant in explaining dissolved solids in UCRB streams. The lack of significance in the contaminant transport modeling framework may be due to the amount of available monitoring data, the spatial distribution of monitoring sites with respect to land disturbance, or the overall quantity of land disturbance associated with oil and gas development basin wide. Finally, dissolved-solids loads derived from natural landscapes may be similar to loads derived from lands disturbed by oil and gas resource development. The model recalibration done for this study confirms calibration results from Kenney and others (2009): the most significant contributor to dissolved solids in the UCRB is irrigated agricultural land, which covers an area substantially larger than the estimated area disturbed by oil and gas development and is subjected to artificially applied water.

Home Cooking and Phenolics: Effect of Thermal Treatment and Addition of Extra Virgin Olive Oil on the Phenolic Profile of Tomato Sauces.

PubMed

Vallverdú-Queralt, Anna; Regueiro, Jorge; Rinaldi de Alvarenga, José Fernando; Torrado, Xavier; Lamuela-Raventos, Rosa M

2014-04-09

Tomato products are a key component of the Mediterranean diet, which is strongly related to a reduced risk of cardiovascular events. The effect of cooking time (15, 30, 45, and 60 min) and the addition of extra virgin olive oil (5 and 10%) on the phenolic content of tomato sauces was monitored using liquid chromatography coupled to tandem mass spectrometry. Concentration of phenolics in the tomato sauces decreased during the cooking process, with the exception of caffeic acid and tyrosol. The main degradation observed was the oxidation of quercetin, since the hydroxy-function at the C-ring of this flavonoid is not blocked by a sugar moiety, unlike rutin. Higher levels of virgin olive oil in tomato sauce seemed to enhance the extraction of phenolic compounds from the tomato, leading to higher phenolic contents in the sauces. Thus, the food matrix containing the phenolic compounds plays a crucial role in determining their accessibility.

Culinary practices mimicking a polysaccharide-rich recipe enhance the bioaccessibility of fat-soluble micronutrients.

PubMed

Dhuique-Mayer, Claudie; Servent, Adrien; Descalzo, Adriana; Mouquet-Rivier, Claire; Amiot, Marie-Josèphe; Achir, Nawel

2016-11-01

This study was carried out to assess the impact of heat processing of a complex emulsion on the behavior of fat soluble micronutrients (FSM) in a traditional Tunisian dish. A simplified recipe involved, dried mucilage-rich jute leaves, tomato paste and olive oil, followed by a cooking treatment (150min). Hydrothermal pattern and viscosity were monitored along with the changes of FSM content and the bioaccessibility (called micellarization, using an in vitro digestion model). Partitioning of carotenoids differed according to their lipophilicity: lycopene, β-carotene and lutein diffused to the oil phase (100%, 70% and 10% respectively). In contrast with the poor carotenes/tocopherol bioaccessibility (0.9-1%), the highest micellarization was observed for lutein (57%) and it increased with heating time and viscosity change. Domestic culinary cooking practices probably increase the bioavailability of carotenes mainly by their diffusion to the oil phase, facilitating their in vivo transfer into micelles. Copyright © 2016 Elsevier Ltd. All rights reserved.

Intelligent ship traffic monitoring for oil spill prevention: risk based decision support building on AIS.

PubMed

Eide, Magnus S; Endresen, Oyvind; Brett, Per Olaf; Ervik, Jon Leon; Røang, Kjell

2007-02-01

The paper describes a model, which estimates the risk levels of individual crude oil tankers. The intended use of the model, which is ready for trial implementation at The Norwegian Coastal Administrations new Vardø VTS (Vessel Traffic Service) centre, is to facilitate the comparison of ships and to support a risk based decision on which ships to focus attention on. For a VTS operator, tasked with monitoring hundreds of ships, this is a valuable decision support tool. The model answers the question, "Which ships are likely to produce an oil spill accident, and how much is it likely to spill?".

Offshore platform sourced pollution monitoring using space-borne fully polarimetric C and X band synthetic aperture radar.

PubMed

Singha, Suman; Ressel, Rudolf

2016-11-15

Use of polarimetric SAR data for offshore pollution monitoring is relatively new and shows great potential for operational offshore platform monitoring. This paper describes the development of an automated oil spill detection chain for operational purposes based on C-band (RADARSAT-2) and X-band (TerraSAR-X) fully polarimetric images, wherein we use polarimetric features to characterize oil spills and look-alikes. Numbers of near coincident TerraSAR-X and RADARSAT-2 images have been acquired over offshore platforms. Ten polarimetric feature parameters were extracted from different types of oil and 'look-alike' spots and divided into training and validation dataset. Extracted features were then used to develop a pixel based Artificial Neural Network classifier. Mutual information contents among extracted features were assessed and feature parameters were ranked according to their ability to discriminate between oil spill and look-alike spots. Polarimetric features such as Scattering Diversity, Surface Scattering Fraction and Span proved to be most suitable for operational services. Copyright © 2016 Elsevier Ltd. All rights reserved.

Satellite Monitoring of Oil Spills in the Mediterranean Sea For 1999-2004

NASA Astrophysics Data System (ADS)

Topouzelis, Konstantinos; Muellenhoff, Oliver; Tarchi, Dario; Ferraro, Guido

2008-01-01

Besides accidental pollution caused by ships in distress, different types of routine ship operations lead to deliberate discharges of oil in the sea. Accidental pollution at sea can be reduced but never completely eliminated. On the other hand, deliberate illegal discharges from ships can indeed be reduced by the strict enforcement of existing regulations and the control, monitoring and surveillance of maritime traffic. Operational discharges are the greatest source of marine pollution from ships, and the one which poses a long-term threat to the marine and coastal environment.The present activities of the Joint Research Centre (JRC), in the field of monitoring sea-based oil pollution using space-borne radar imagery are described. The results obtained for the period 1999-2004 for the Mediterranean Sea are presented. This analysis is of special interest due to the lack of a regular aerial surveillance as that in the North and Baltic Sea. This action helped to reveal what the dimension of the oil pollution problem is, thus stressing the need for more concerted international actions.

Investigating the use of oil platform marine fouling invertebrates as monitors of oil exposure in the Northern Gulf of Mexico.

PubMed

Pie, Hannah V; Heyes, Andrew; Mitchelmore, Carys L

2015-03-01

The concentration of 51 parent and alkylated PAHs was examined in oysters, Ostrea equestris, and corals, Tubastrea coccinea, collected from oil-rig structures off the coast of Louisiana during April and May 2011 to investigate their potential use as monitors for offshore contamination events. Corals and oysters collected from both sampling trips had lower PAH accumulation than most bivalves collected in previous studies near the shoreline of Louisiana and elsewhere in the Gulf of Mexico. In April, total PAH (TPAH) concentrations ranged from 8.73 to 15.17 ng g(-1) in corals and 2.52 to 22.04 ng g(-1) in oysters. In May, corals and oysters had elevated concentrations of TPAH ranging from 24.28 to 79.23 ng g(-1) and 7.18 to 95.55 ng g(-1), respectively. This increase could be a result of Mississippi River flooding that occurred during that time, as evidenced by the high perylene concentrations (3.92-41.49 ng g(-1)) measured in May oysters. Oysters and corals collected in May from MC21B, the closest rig to the Mississippi River Delta, had the highest TPAH concentrations observed among all locations and the only rig to have predominantly petrogenic source inputs. Overall, given the low baseline of PAHs demonstrated in this study and the rapid accumulation of diagnostic chemicals in response to a possible contamination event (i.e. sediment plume from May flooding), oil-rig invertebrates could make excellent monitoring tools to examine the exposure to and recovery from oil (and oil-spill response options) in the offshore Northern Gulf of Mexico. Pre-spill baseline data of chemical and biological biomarkers of contamination is key to better estimating the impacts and recovery of oil exposure. Therefore, this screen of PAH accumulation represents a crucial first step in determining baseline contaminant levels in order to utilize these unique resources as monitors for offshore oil exposure in the Northern Gulf of Mexico. Copyright © 2014 Elsevier B.V. All rights reserved.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sale, D.M.; Gibeaut, J.C.; Short, J.W.

Following the Exxon Valdez oil spill, sediment traps were deployed in nearshore subtidal areas of Prince William Sound, Alaska (PWS) to monitor particulate chemistry and mineralogy. Complemented by benthic sediment chemistry and core sample stratigraphy at the study sites, results were compared to historical trends and data from other Exxon Valdez studies. These results clearly indicate the transport of oil-laden sediments from oiled shorelines to adjacent subtidal sediments. The composition of hydrocarbons adsorbed to settling particulates at sites adjacent to oiled shorelines matched the PAH pattern of weathered Exxon Valdez crude oil.

Antioxidant Enzyme Activities and Secondary Metabolite Profiling of Oil Palm Seedlings Treated with Combination of NPK Fertilizers Infected with Ganoderma boninense.

PubMed

Sahebi, Mahbod; Hanafi, Mohamed M; Mohidin, Hasmah; Rafii, M Y; Azizi, Parisa; Idris, Abu Seman; Fariz, A; Abiri, Rambod; Taheri, Sima; Moradpoor, Mehdi

2018-01-01

Oil palm ( Elaeis guineensis Jacq) is one of the major sources of edible oil. Reducing the effect of Ganoderma, main cause of basal stem rot (BSR) on oil palm, is the main propose of this study. Understanding the oil palm defense mechanism against Ganoderma infection through monitoring changes in the secondary metabolite compounds levels before/after infection by Ganoderma under different fertilizing treatment is required. Oil palm requires macro- and microelements for growth and yield. Manipulating the nutrient for oil palm is a method to control the disease. The 3-4-month-old oil palm seedlings were given different macronutrient treatments to evaluate induction of defense related enzymes and production of secondary metabolite compounds in response to G. boninense inoculation. The observed trend of changes in the infected and uninfected seedlings was a slightly higher activity for β -1,3-glucanases, chitinase, peroxidase, and phenylalanine ammonia-lyase during the process of pathogenesis. It was found that PR proteins gave positive response to the interaction between oil palm seedlings and Ganoderma infection. Although the responses were activated systematically, they were short-lasting as the changes in enzymes activities appeared before the occurrence of visible symptoms. Effect of different nutrients doses was obviously observed among the results of the secondary metabolite compounds. Many identified/unidentified metabolite compounds were presented, of which some were involved in plant cell defense mechanism against pathogens, mostly belonging to alkaloids with bitter-tasting nitrogenous-compounds, and some had the potential to be used as new markers to detect basal stem rot at the initial step of disease.

Cyber Physical Intelligence for Oil Spills (CPI)

NASA Astrophysics Data System (ADS)

Lary, D. J.

2015-12-01

The National Academy of Sciences estimate 1.7 to 8.8 million tons of oil are released into global waters every year. The effects of these spills include dead wildlife, oil covered marshlands and contaminated water. Deepwater horizon cost approximately $50 billion and severely challenged response capabilities. In such large spills optimizing a coordinated response is a particular challenge. This challenge can be met in a revolutionary new way by using an objectively optimized Cyber Physical Decision Making System (CPS) for rapid response products and a framework for objectively optimized decision-making in an uncertain environment. The CPS utilizes machine learning for the processing of the massive real-time streams of Big Data from comprehensive hyperspectral remote sensing acquired by a team of low-cost robotic aerial vehicles, providing a real-time aerial view and stream of hyperspectral imagery from the near UV to the thermal infrared, and a characterization of oil thickness, oil type and oil weathering. The objective decision making paradigm is modeled on the human brain and provides the optimal course trajectory for response vessels to achieve the most expeditious cleanup of oil spills using the available resources. In addition, oil spill cleanups often involve surface oil burns that can lead to air quality issues. The aerial vehicles comprehensively characterize air quality in real-time, streaming location, temperature, pressure, humidity, the abundance of 6 criterion pollutants (O3, CO, NO, NO2, SO2, and H2S) and the full size distribution of airborne particulates. This CPS can be readily applied to other systems in agriculture, water conversation, monitoring of stream quality, air quality, diagnosing risk of wild fires, etc..

Antioxidant Enzyme Activities and Secondary Metabolite Profiling of Oil Palm Seedlings Treated with Combination of NPK Fertilizers Infected with Ganoderma boninense

PubMed Central

Mohidin, Hasmah; Idris, Abu Seman; Fariz, A.; Abiri, Rambod; Taheri, Sima; Moradpoor, Mehdi

2018-01-01

Oil palm (Elaeis guineensis Jacq) is one of the major sources of edible oil. Reducing the effect of Ganoderma, main cause of basal stem rot (BSR) on oil palm, is the main propose of this study. Understanding the oil palm defense mechanism against Ganoderma infection through monitoring changes in the secondary metabolite compounds levels before/after infection by Ganoderma under different fertilizing treatment is required. Oil palm requires macro- and microelements for growth and yield. Manipulating the nutrient for oil palm is a method to control the disease. The 3-4-month-old oil palm seedlings were given different macronutrient treatments to evaluate induction of defense related enzymes and production of secondary metabolite compounds in response to G. boninense inoculation. The observed trend of changes in the infected and uninfected seedlings was a slightly higher activity for β-1,3-glucanases, chitinase, peroxidase, and phenylalanine ammonia-lyase during the process of pathogenesis. It was found that PR proteins gave positive response to the interaction between oil palm seedlings and Ganoderma infection. Although the responses were activated systematically, they were short-lasting as the changes in enzymes activities appeared before the occurrence of visible symptoms. Effect of different nutrients doses was obviously observed among the results of the secondary metabolite compounds. Many identified/unidentified metabolite compounds were presented, of which some were involved in plant cell defense mechanism against pathogens, mostly belonging to alkaloids with bitter-tasting nitrogenous-compounds, and some had the potential to be used as new markers to detect basal stem rot at the initial step of disease. PMID:29721500

Crude oil metabolites in groundwater at two spill sites

USGS Publications Warehouse

Bekins, Barbara A.; Cozzarelli, Isabelle M.; Erickson, Melinda L.; Steenson, Ross; Thorn, Kevin A.

2016-01-01

Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.

Characterization of successional changes in bacterial community composition during bioremediation of used motor oil-contaminated soil in a boreal climate.

PubMed

Yan, Lijuan; Sinkko, Hanna; Penttinen, Petri; Lindström, Kristina

2016-01-15

The widespread use of motor oil makes it a notable risk factor to cause scattered contamination in soil. The monitoring of microbial community dynamics can serve as a comprehensive tool to assess the ecological impact of contaminants and their disappearance in the ecosystem. Hence, a field study was conducted to monitor the ecological impact of used motor oil under different perennial cropping systems (fodder galega, brome grass, galega-brome grass mixture and bare fallow) in a boreal climate zone. Length heterogeneity PCR characterized a successional pattern in bacterial community following oil contamination over a four-year bioremediation period. Soil pH and electrical conductivity were associated with the shifts in bacterial community composition. Crops had no detectable effect on bacterial community composition or complexity. However, the legume fodder galega increased soil microbial biomass, expressed as soil total DNA. Oil contamination induced an abrupt change in bacterial community composition at the early stage, yet the effect did not last as long as the oil in soil. The successional variation in bacterial community composition can serve as a sensitive ecological indicator of oil contamination and remediation in situ. Copyright © 2015 Elsevier B.V. All rights reserved.

Pipeline oil fire detection with MODIS active fire products

NASA Astrophysics Data System (ADS)

Ogungbuyi, M. G.; Martinez, P.; Eckardt, F. D.

2017-12-01

We investigate 85 129 MODIS satellite active fire events from 2007 to 2015 in the Niger Delta of Nigeria. The region is the oil base for Nigerian economy and the hub of oil exploration where oil facilities (i.e. flowlines, flow stations, trunklines, oil wells and oil fields) are domiciled, and from where crude oil and refined products are transported to different Nigerian locations through a network of pipeline systems. Pipeline and other oil facilities are consistently susceptible to oil leaks due to operational or maintenance error, and by acts of deliberate sabotage of the pipeline equipment which often result in explosions and fire outbreaks. We used ground oil spill reports obtained from the National Oil Spill Detection and Response Agency (NOSDRA) database (see www.oilspillmonitor.ng) to validate MODIS satellite data. NOSDRA database shows an estimate of 10 000 spill events from 2007 - 2015. The spill events were filtered to include largest spills by volume and events occurring only in the Niger Delta (i.e. 386 spills). By projecting both MODIS fire and spill as `input vector' layers with `Points' geometry, and the Nigerian pipeline networks as `from vector' layers with `LineString' geometry in a geographical information system, we extracted the nearest MODIS events (i.e. 2192) closed to the pipelines by 1000m distance in spatial vector analysis. The extraction process that defined the nearest distance to the pipelines is based on the global practices of the Right of Way (ROW) in pipeline management that earmarked 30m strip of land to the pipeline. The KML files of the extracted fires in a Google map validated their source origin to be from oil facilities. Land cover mapping confirmed fire anomalies. The aim of the study is to propose a near-real-time monitoring of spill events along pipeline routes using 250 m spatial resolution of MODIS active fire detection sensor when such spills are accompanied by fire events in the study location.

Environmental impacts of the Chennai oil spill accident - A case study.

PubMed

Han, Yuling; Nambi, Indumathi M; Prabhakar Clement, T

2018-06-01

Chennai, a coastal city in India with a population of over 7 million people, was impacted by a major oil spill on January 28th 2017. The spill occurred when two cargo ships collided about two miles away from the Chennai shoreline. The accident released about 75 metric tons of heavy fuel oil into the Bay of Bengal. This case study provides field observations and laboratory characterization data for this oil spill accident. Our field observations show that the seawalls and groins, which were installed along the Chennai shoreline to manage coastal erosion problems, played a significant role in controlling the oil deposition patterns. A large amount of oil was trapped within the relatively stagnant zone near the seawall-groin intersection region. The initial cleanup efforts used manual methods to skim the trapped oil and these efforts indeed helped recover large amount of oil. Our laboratory data show that the Chennai oil spill residues have unique fingerprints of hopanes and steranes which can be used to track the spill. Our weathering experiments show that volatilization processes should have played a significant role in degrading the oil during initial hours. The characterization data show that the source oil contained about 503,000 mg/kg of total petroleum hydrocarbons (TPH) and 17,586 mg/kg of total polycyclic aromatic hydrocarbons (PAHs). The field samples collected 6 and 62 days after the spill contained about 71,000 and 28,000 mg/kg of TPH and 4854 and 4016 mg/kg of total PAHs, respectively. The field samples had a relatively large percentage of heavy PAHs, and most of these PAHs are highly toxic compounds that are difficult to weather and their long-term effects on coastal ecosystems are largely unknown. Therefore, more detailed studies are needed to monitor and track the long term environmental impacts of the Chennai oil spill residues on the Bay of Bengal coastal ecosystem. Copyright © 2018 Elsevier B.V. All rights reserved.

33 CFR 157.12f - Workshop functional test requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12f Workshop functional test requirements. (a) Each oil content meter and each control section of a monitoring system must be subjected to a... protocol must be received with each unit delivered. (b) A functional test conducted on an oil content meter...

33 CFR 157.12f - Workshop functional test requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12f Workshop functional test requirements. (a) Each oil content meter and each control section of a monitoring system must be subjected to a... protocol must be received with each unit delivered. (b) A functional test conducted on an oil content meter...

33 CFR 157.12f - Workshop functional test requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... CARRYING OIL IN BULK Design, Equipment, and Installation § 157.12f Workshop functional test requirements. (a) Each oil content meter and each control section of a monitoring system must be subjected to a... protocol must be received with each unit delivered. (b) A functional test conducted on an oil content meter...

40 CFR 63.10000 - What are my general requirements for complying with this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... Administrator which may include, but is not limited to, monitoring results, review of operation and maintenance... SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants: Coal- and Oil... of startup and shutdown; however, for coal-fired, liquid oil-fired, or solid oil-derived fuel-fired...

USE OF HOPANE AS A CONSERVATIVE BIOMARKER FOR MONITORING THE BIOREMEDIATION EFFECTIVENESS OF CRUDE OIL CONTAMINATING A SANDY BEACH

EPA Science Inventory

Much of the variability inherent in crude oil bioremediation field studies can be eliminated by normalizing analyte concentrations to the concentration of a nonbiodegradable biomarker such as hopane. This was demonstrated with data from a field study in which crude oil was intent...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.14 - Specific provisions for monitoring opacity.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.14 Specific provisions for monitoring opacity. (a) Coal-fired units and oil-fired units. The owner or operator shall meet the general... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Specific provisions for monitoring...

40 CFR 75.14 - Specific provisions for monitoring opacity.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.14 Specific provisions for monitoring opacity. (a) Coal-fired units and oil-fired units. The owner or operator shall meet the general... 40 Protection of Environment 17 2014-07-01 2014-07-01 false Specific provisions for monitoring...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.14 - Specific provisions for monitoring opacity.

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.14 Specific provisions for monitoring opacity. (a) Coal-fired units and oil-fired units. The owner or operator shall meet the general... 40 Protection of Environment 16 2011-07-01 2011-07-01 false Specific provisions for monitoring...

40 CFR 75.12 - Specific provisions for monitoring NOX emission rate.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) AIR PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.12 Specific provisions for monitoring NOX emission rate. (a) Coal-fired units, gas-fired nonpeaking units or oil-fired... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring NOX...

40 CFR 75.14 - Specific provisions for monitoring opacity.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.14 Specific provisions for monitoring opacity. (a) Coal-fired units and oil-fired units. The owner or operator shall meet the general... 40 Protection of Environment 17 2012-07-01 2012-07-01 false Specific provisions for monitoring...

40 CFR 75.14 - Specific provisions for monitoring opacity.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROGRAMS (CONTINUED) CONTINUOUS EMISSION MONITORING Monitoring Provisions § 75.14 Specific provisions for monitoring opacity. (a) Coal-fired units and oil-fired units. The owner or operator shall meet the general... 40 Protection of Environment 17 2013-07-01 2013-07-01 false Specific provisions for monitoring...

33 CFR 154.525 - Monitoring devices.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Monitoring devices. 154.525... Monitoring devices. The COTP may require the facility to install monitoring devices if the installation of monitoring devices at the facility would significantly limit the size of a discharge of oil or hazardous...

Near Real Time Analytics of Human Sensor Networks in the Realm of Big Data

NASA Astrophysics Data System (ADS)

Aulov, O.; Halem, M.

2012-12-01

With the prolific development of social media, emergency responders have an increasing interest in harvesting social media from outlets such as Flickr, Twitter, and Facebook, in order to assess the scale and specifics of extreme events including wild fires, earthquakes, terrorist attacks, oil spills, etc. A number of experimental platforms have successfully been implemented to demonstrate the utilization of social media data in extreme events, including Twitter Earthquake Detector, which relied on tweets for earthquake monitoring; AirTwitter, which used tweets for air quality reporting; and our previous work, using Flickr data as boundary value forcings to improve the forecast of oil beaching in the aftermath of the Deepwater Horizon oil spill. The majority of these platforms addressed a narrow, specific type of emergency and harvested data from a particular outlet. We demonstrate an interactive framework for monitoring, mining and analyzing a plethora of heterogeneous social media sources for a diverse range of extreme events. Our framework consists of three major parts: a real time social media aggregator, a data processing and analysis engine, and a web-based visualization and reporting tool. The aggregator gathers tweets, Facebook comments from fan pages, Google+ posts, forum discussions, blog posts (such as LiveJournal and Blogger.com), images from photo-sharing platforms (such as Flickr, Picasa), videos from video-sharing platforms (youtube, Vimeo), and so forth. The data processing and analysis engine pre-processes the aggregated information and annotates it with geolocation and sentiment information. In many cases, the metadata of the social media posts does not contain geolocation information—-however, a human reader can easily guess from the body of the text what location is discussed. We are automating this task by use of Named Entity Recognition (NER) algorithms and a gazetteer service. The visualization and reporting tool provides a web-based, user-friendly interface that provides time-series analysis and plotting tools, geo-spacial visualization tools with interactive maps, and cause-effect inference tools. We demonstrate how we address big data challenges of monitoring, aggregating and analyzing vast amounts of social media data at a near realtime. As a result, our framework not only allows emergency responders to augment their situational awareness with social media information, but can also allow them to extract geophysical data and incorporate it into their analysis models.

Submersible optical sensors exposed to chemically dispersed crude oil: wave tank simulations for improved oil spill monitoring.

PubMed

Conmy, Robyn N; Coble, Paula G; Farr, James; Wood, A Michelle; Lee, Kenneth; Pegau, W Scott; Walsh, Ian D; Koch, Corey R; Abercrombie, Mary I; Miles, M Scott; Lewis, Marlon R; Ryan, Scott A; Robinson, Brian J; King, Thomas L; Kelble, Christopher R; Lacoste, Jordanna

2014-01-01

In situ fluorometers were deployed during the Deepwater Horizon (DWH) Gulf of Mexico oil spill to track the subsea oil plume. Uncertainties regarding instrument specifications and capabilities necessitated performance testing of sensors exposed to simulated, dispersed oil plumes. Dynamic ranges of the Chelsea Technologies Group AQUAtracka, Turner Designs Cyclops, Satlantic SUNA and WET Labs, Inc. ECO, exposed to fresh and artificially weathered crude oil, were determined. Sensors were standardized against known oil volumes and total petroleum hydrocarbons and benzene-toluene-ethylbenzene-xylene measurements-both collected during spills, providing oil estimates during wave tank dilution experiments. All sensors estimated oil concentrations down to 300 ppb oil, refuting previous reports. Sensor performance results assist interpretation of DWH oil spill data and formulating future protocols.

[Ecologo-hygienic criteria and monitoring indices of oil-contaminated peaty soils].

PubMed

Dubinina, O N; Khusnutdinova, N Yu; Mikhailova, L V; Yakhina, M R

2014-01-01

Intensive oil extraction in Khanty-Mansi Autonomous Okrug is not uncommon accompanied by emergency situations giving rise to the pollution of soil, surface and groundwater and causing an elevation in the population morbidity rate. The purpose of the study is to substantiate the basis for information value of hygienic indices of peat soils with low levels of oil contamination: from background values to exceeding the latters as much as 10-20 times, to apply in the study results in hygienic monitoring and oil regulation. The study was performed in accordance with the current methodological regulations. There was established the expediency of determination in transforming in the soil, composition of the petroleum hydrocarbons not only alkanes but arenes and resin-asphaltene fractions, indices of phytotoxicity, translocation of petroleum products into plants testing of soil extracts on protozoa and invertebrates.

Biodiesel transesterification kinetics monitored by pH measurement.

PubMed

Clark, William M; Medeiros, Nicholas J; Boyd, Donal J; Snell, Jared R

2013-05-01

Quantification of a pH change that was observed over the course of the transesterification reaction that converts vegetable oil to biodiesel may provide a simple method to monitor the reaction. Transesterification of canola oil at 6:1 methanol to oil ratio with 0.5 wt.% KOH as catalyst was studied at 25, 35, and 45 °C. Reaction conversion was correlated to pH measurements and the results were shown to be in agreement with an independent measure of conversion using an enzymatic assay for glycerol. Rate constants obtained from these measurements are consistent with those in the literature. The measured pH change appears to be related to dilution of OH(-) ions as the oil is converted to products rather than to depletion of OH(-) due to reaction. Copyright © 2013 Elsevier Ltd. All rights reserved.

Tapered Roller Bearing Damage Detection Using Decision Fusion Analysis

NASA Technical Reports Server (NTRS)

Dempsey, Paula J.; Kreider, Gary; Fichter, Thomas

2006-01-01

A diagnostic tool was developed for detecting fatigue damage of tapered roller bearings. Tapered roller bearings are used in helicopter transmissions and have potential for use in high bypass advanced gas turbine aircraft engines. A diagnostic tool was developed and evaluated experimentally by collecting oil debris data from failure progression tests conducted using health monitoring hardware. Failure progression tests were performed with tapered roller bearings under simulated engine load conditions. Tests were performed on one healthy bearing and three pre-damaged bearings. During each test, data from an on-line, in-line, inductance type oil debris sensor and three accelerometers were monitored and recorded for the occurrence of bearing failure. The bearing was removed and inspected periodically for damage progression throughout testing. Using data fusion techniques, two different monitoring technologies, oil debris analysis and vibration, were integrated into a health monitoring system for detecting bearing surface fatigue pitting damage. The data fusion diagnostic tool was evaluated during bearing failure progression tests under simulated engine load conditions. This integrated system showed improved detection of fatigue damage and health assessment of the tapered roller bearings as compared to using individual health monitoring technologies.

Modelling of Seismic and Resistivity Responses during the Injection of CO2 in Sandstone Reservoir

NASA Astrophysics Data System (ADS)

Omar, Muhamad Nizarul Idhafi Bin; Almanna Lubis, Luluan; Nur Arif Zanuri, Muhammad; Ghosh, Deva P.; Irawan, Sonny; Regassa Jufar, Shiferaw

2016-07-01

Enhanced oil recovery plays vital role in production phase in a producing oil field. Initially, in many cases hydrocarbon will naturally flow to the well as respect to the reservoir pressure. But over time, hydrocarbon flow to the well will decrease as the pressure decrease and require recovery method so called enhanced oil recovery (EOR) to recover the hydrocarbon flow. Generally, EOR works by injecting substances, such as carbon dioxide (CO2) to form a pressure difference to establish a constant productive flow of hydrocarbon to production well. Monitoring CO2 performance is crucial in ensuring the right trajectory and pressure differences are established to make sure the technique works in recovering hydrocarbon flow. In this paper, we work on computer simulation method in monitoring CO2 performance by seismic and resistivity model, enabling geoscientists and reservoir engineers to monitor production behaviour as respect to CO2 injection.

Fugitive Methane Gas Emission Monitoring in oil and gas industry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klein, Levente

Identifying fugitive methane leaks allow optimization of the extraction process, can extend gas extraction equipment lifetime, and eliminate hazardous work conditions. We demonstrate a wireless sensor network based on cost effective and robust chemi-resistive methane sensors combined with real time analytics to identify leaks from 2 scfh to 10000 scfh. The chemi-resistive sensors were validated for sensitivity better than 1 ppm of methane plume detection. The real time chemical sensor and wind data is integrated into an inversion models to identify the location and the magnitude of the methane leak. This integrated solution can be deployed in outdoor environment formore » long term monitoring of chemical plumes.« less

Turbine Fuels from Tar Sands Bitumen and Heavy Oil. Phase I. Preliminary Process Analysis.

DTIC Science & Technology

1985-04-09

OIL RESERVOIRS OF THE UNITED STATES Resource: Oil -in-Place State Field Name (County) (Million Bbls.) Arkansas Smackover Old (Union) 1,6U0 California...Flow Schematic for Gas Oil Feed Hydrotreater 94 14 Summary of Case Studies for Processing Bitumen from New Mexico 95 15 Summary of Case Studies for...Naphtha Hydrotreating Process Estimates 112 14 Gas Oil Hydrocracking Process Estimates 113 l! Gas Oil Hydrotreating Process Estimate 114 16 Fluid

Physical and chemical characterization of petroleum products by GC-MS.

PubMed

Mendez, A; Meneghini, R; Lubkowitz, J

2007-01-01

There is a need for reliable and fast means of monitoring refining, conversion, and upgrading processes aiming to increase the yield of light distillates, and thus, reducing the oil barrel bottoms. By simultaneously utilizing the FID and mass selective detectors while splitting the column effluent in a controlled way, it is possible to obtain identical gas chromatograms and total ion chromatograms from a single run. This means that besides the intensity vs. time graphs, the intensity vs. mass and boiling point can also be obtained. As a result, physical and chemical characterization can be performed in a simple and rapid manner. Experimental results on middle, heavy distillates, and crude oil fractions show clearly the effect of upgrading processes on the chemical composition and yields of diesel, jet fuels, and high vacuum gasoil fractions. The methodology is fully compliant with ASTM D-2887, D-7213, D-6352, and D7169 for simulated distillation and the previously mentioned mass spectrometry standards. The group type analysis correlated satisfactorily with high-performance liquid chromatography data.

Leaching of polycyclic aromatic hydrocarbons from oil shale processing waste deposit: a long-term field study.

PubMed

Jefimova, Jekaterina; Irha, Natalya; Reinik, Janek; Kirso, Uuve; Steinnes, Eiliv

2014-05-15

The leaching behavior of selected polycyclic aromatic hydrocarbons (PAHs) from an oil shale processing waste deposit was monitored during 2005-2009. Samples were collected from the deposit using a special device for leachate sampling at field conditions without disturbance of the upper layers. Contents of 16 priority PAHs in leachate samples collected from aged and fresh parts of the deposit were determined by GC-MS. The sum of the detected PAHs in leachates varied significantly throughout the study period: 19-315 μg/l from aged spent shale, and 36-151 μg/l from fresh spent shale. Among the studied PAHs the low-molecular weight compounds phenanthrene, naphthalene, acenaphthylene, and anthracene predominated. Among the high-molecular weight PAHs benzo[a]anthracene and pyrene leached in the highest concentrations. A spent shale deposit is a source of PAHs that could infiltrate into the surrounding environment for a long period of time. Copyright © 2014 Elsevier B.V. All rights reserved.

Confirmation of heavy metal ions in used lubricating oil from a passenger car using chelating self-assembled monolayer.

PubMed

Ko, Young Gun; Kim, Choong Hyun

2006-09-01

In order to prevent engine failure, the oil must be changed before it loses its protective properties. It is necessary to monitor the actual physical and chemical condition of the oil to reliably determine the optimum oil-change interval. Our study focuses on the condition of the lubricating oil in an operated car engine. Shear stress curves and viscosity curves as a function of the shear rate for fresh and used lubricating oil were examined. Metal nitrate was detected in the lubricating oil from the operated car engine through the use of a chelating self-assembled monolayer.

Ex-situ bioremediation of crude oil in soil, a comparative kinetic analysis.

PubMed

Mohajeri, Leila; Aziz, Hamidi Abdul; Isa, Mohamed Hasnain; Zahed, Mohammad Ali; Mohajeri, Soraya

2010-07-01

Weathered crude oil (WCO) removals in shoreline sediment samples were monitored for 60 days in bioremediation experimentation. Experimental modeling was carried out using statistical design of experiments. At optimum conditions maximum of 83.13, 78.06 and 69.92% WCO removals were observed for 2, 16 and 30 g/kg initial oil concentrations, respectively. Significant variations in the crude oil degradation pattern were observed with respect to oil, nutrient and microorganism contents. Crude oil bioremediation were successfully described by a first-order kinetic model. The study indicated that the rate of hydrocarbon biodegradation increased with decrease of crude oil concentrations.

Integrated assessment of oil pollution using biological monitoring and chemical fingerprinting.

PubMed

Lewis, Ceri; Guitart, Carlos; Pook, Chris; Scarlett, Alan; Readman, James W; Galloway, Tamara S

2010-06-01

A full assessment of the impact of oil and chemical spills at sea requires the identification of both the polluting chemicals and the biological effects they cause. Here, a combination of chemical fingerprinting of surface oils, tissue residue analysis, and biological effects measures was used to explore the relationship between spilled oil and biological impact following the grounding of the MSC Napoli container ship in Lyme Bay, England in January 2007. Initially, oil contamination remained restricted to a surface slick in the vicinity of the wreck, and there was no chemical evidence to link biological impairment of animals (the common limpet, Patella vulgata) on the shore adjacent to the oil spill. Secondary oil contamination associated with salvage activities in July 2007 was also assessed. Chemical analyses of aliphatic hydrocarbons and terpanes in shell swabs taken from limpet shells provided an unequivocal match with the fuel oil carried by the ship. Corresponding chemical analysis of limpet tissues revealed increased concentrations of polycyclic aromatic hydrocarbons (PAHs) dominated by phenanthrene and C1 to C3 phenanthrenes with smaller contributions from heavier molecular weight PAHs. Concurrent ecotoxicological tests indicated impairment of cellular viability (p < 0.001), reduced immune function (p < 0.001), and damage to DNA (Comet assay, p < 0.001) in these animals, whereas antioxidant defenses were elevated relative to un-oiled animals. These results illustrate the value of combining biological monitoring with chemical fingerprinting for the rapid identification of spilled oils and their sublethal impacts on biota in situ. Copyright 2010 SETAC.

Effect of soybean lecithin on iron-catalyzed or chlorophyll-photosensitized oxidation of canola oil emulsion.

PubMed

Choe, Jeesu; Oh, Boyoung; Choe, Eunok

2014-11-01

The effect of soybean lecithin addition on the iron-catalyzed or chlorophyll-photosensitized oxidation of emulsions consisting of purified canola oil and water (1:1, w/w) was studied based on headspace oxygen consumption using gas chromatography and hydroperoxide production using the ferric thiocyanate method. Addition levels of iron sulfate, chlorophyll, and soybean lecithin were 5, 4, and 350 mg/kg, respectively. Phospholipids (PLs) during oxidation of the emulsions were monitored by high performance liquid chromatography. Addition of soybean lecithin to the emulsions significantly reduced and decelerated iron-catalyzed oil oxidation by lowering headspace oxygen consumption and hydroperoxide production. However, soybean lecithin had no significant antioxidant effect on chlorophyll-photosensitized oxidation of the emulsions. PLs in soybean lecithin added to the emulsions were degraded during both oxidation processes, although there was little change in PL composition. Among PLs in soybean lecithin, phosphatidylethanolamine and phosphatidylinositol were degraded the fastest in the iron-catalyzed and the chlorophyll-photosensitized oxidation, respectively. The results suggest that addition of soybean lecithin as an emulsifier can also improve the oxidative stability of oil in an emulsion. © 2014 Institute of Food Technologists®

Wet separation processes as method to separate limestone and oil shale

NASA Astrophysics Data System (ADS)

Nurme, Martin; Karu, Veiko

2015-04-01

Biggest oil shale industry is located in Estonia. Oil shale usage is mainly for electricity generation, shale oil generation and cement production. All these processes need certain quality oil shale. Oil shale seam have interlayer limestone layers. To use oil shale in production, it is needed to separate oil shale and limestone. A key challenge is find separation process when we can get the best quality for all product types. In oil shale separation typically has been used heavy media separation process. There are tested also different types of separation processes before: wet separation, pneumatic separation. Now oil shale industry moves more to oil production and this needs innovation methods for separation to ensure fuel quality and the changes in quality. The pilot unit test with Allmineral ALLJIG have pointed out that the suitable new innovation way for oil shale separation can be wet separation with gravity, where material by pulsating water forming layers of grains according to their density and subsequently separates the heavy material (limestone) from the stratified material (oil shale)bed. Main aim of this research is to find the suitable separation process for oil shale, that the products have highest quality. The expected results can be used also for developing separation processes for phosphorite rock or all others, where traditional separation processes doesn't work property. This research is part of the study Sustainable and environmentally acceptable Oil shale mining No. 3.2.0501.11-0025 http://mi.ttu.ee/etp and the project B36 Extraction and processing of rock with selective methods - http://mi.ttu.ee/separation; http://mi.ttu.ee/miningwaste/

Object-based inversion of crosswell radar tomography data to monitor vegetable oil injection experiments

USGS Publications Warehouse

Lane, John W.; Day-Lewis, Frederick D.; Versteeg, Roelof J.; Casey, Clifton C.

2004-01-01

Crosswell radar methods can be used to dynamically image ground-water flow and mass transport associated with tracer tests, hydraulic tests, and natural physical processes, for improved characterization of preferential flow paths and complex aquifer heterogeneity. Unfortunately, because the raypath coverage of the interwell region is limited by the borehole geometry, the tomographic inverse problem is typically underdetermined, and tomograms may contain artifacts such as spurious blurring or streaking that confuse interpretation.We implement object-based inversion (using a constrained, non-linear, least-squares algorithm) to improve results from pixel-based inversion approaches that utilize regularization criteria, such as damping or smoothness. Our approach requires pre- and post-injection travel-time data. Parameterization of the image plane comprises a small number of objects rather than a large number of pixels, resulting in an overdetermined problem that reduces the need for prior information. The nature and geometry of the objects are based on hydrologic insight into aquifer characteristics, the nature of the experiment, and the planned use of the geophysical results.The object-based inversion is demonstrated using synthetic and crosswell radar field data acquired during vegetable-oil injection experiments at a site in Fridley, Minnesota. The region where oil has displaced ground water is discretized as a stack of rectangles of variable horizontal extents. The inversion provides the geometry of the affected region and an estimate of the radar slowness change for each rectangle. Applying petrophysical models to these results and porosity from neutron logs, we estimate the vegetable-oil emulsion saturation in various layers.Using synthetic- and field-data examples, object-based inversion is shown to be an effective strategy for inverting crosswell radar tomography data acquired to monitor the emplacement of vegetable-oil emulsions. A principal advantage of object-based inversion is that it yields images that hydrologists and engineers can easily interpret and use for model calibration.

Optical microsystem for analyzing engine lubricants

NASA Astrophysics Data System (ADS)

Scott, Andrew J.; Mabesa, Jose R., Jr.; Gorsich, David; Rathgeb, Brian; Said, Ali A.; Dugan, Mark; Haddock, Tom F.; Bado, Philippe W.

2004-12-01

It is possible to dramatically improve the performance, reliability, and maintainability of vehicles and other similarly complex equipment if improved sensing and diagnostics systems are available. Each year military and commercial maintenance personnel unnecessarily replace, at scheduled intervals, significant amounts of lubricant fluids in vehicles, weapon systems, and supporting equipment. Personnel draw samples of fluids and send them to test labs for analysis to determine if replacement is necessary. Systematic use of either on-board (embedded) lubricant quality analysis capabilities will save millions of dollars each year in avoided fluid changes, saved labor, prevented damage to mechanical components while providing associated environmental benefits. This paper discusses the design, the manufacturing, and the evaluation of robust optical sensors designed to monitor the condition of industrial fluids. The sensors reported are manufactured from bulk fused silica substrates. They incorporate three-dimensional micro fluidic circuitry side-by-side with three-dimensional wave guided optical networks. The manufacturing of the optical waveguides are completed using a direct-write process based on the use of femtosecond laser pulses to locally alter the structure of the glass substrate at the nano-level. The microfluidic circuitry is produced using the same femtosecond laser based process, followed by an anisotropic wet chemical etching step. Data will be presented regarding the use of these sensors to monitor the quality of engine oil and possibly some other vehicle lubricants such as hydraulic oil.

Subsurface Monitoring of CO2 Sequestration - A Review and Look Forward

NASA Astrophysics Data System (ADS)

Daley, T. M.

2012-12-01

The injection of CO2 into subsurface formations is at least 50 years old with large-scale utilization of CO2 for enhanced oil recovery (CO2-EOR) beginning in the 1970s. Early monitoring efforts had limited measurements in available boreholes. With growing interest in CO2 sequestration beginning in the 1990's, along with growth in geophysical reservoir monitoring, small to mid-size sequestration monitoring projects began to appear. The overall goals of a subsurface monitoring plan are to provide measurement of CO2 induced changes in subsurface properties at a range of spatial and temporal scales. The range of spatial scales allows tracking of the location and saturation of the plume with varying detail, while finer temporal sampling (up to continuous) allows better understanding of dynamic processes (e.g. multi-phase flow) and constraining of reservoir models. Early monitoring of small scale pilots associated with CO2-EOR (e.g., the McElroy field and the Lost Hills field), developed many of the methodologies including tomographic imaging and multi-physics measurements. Large (reservoir) scale sequestration monitoring began with the Sleipner and Weyburn projects. Typically, large scale monitoring, such as 4D surface seismic, has limited temporal sampling due to costs. Smaller scale pilots can allow more frequent measurements as either individual time-lapse 'snapshots' or as continuous monitoring. Pilot monitoring examples include the Frio, Nagaoka and Otway pilots using repeated well logging, crosswell imaging, vertical seismic profiles and CASSM (continuous active-source seismic monitoring). For saline reservoir sequestration projects, there is typically integration of characterization and monitoring, since the sites are not pre-characterized resource developments (oil or gas), which reinforces the need for multi-scale measurements. As we move beyond pilot sites, we need to quantify CO2 plume and reservoir properties (e.g. pressure) over large scales, while still obtaining high resolution. Typically the high-resolution (spatial and temporal) tools are deployed in permanent or semi-permanent borehole installations, where special well design may be necessary, such as non-conductive casing for electrical surveys. Effective utilization of monitoring wells requires an approach of modular borehole monitoring (MBM) were multiple measurements can be made. An example is recent work at the Citronelle pilot injection site where an MBM package with seismic, fluid sampling and distributed fiber sensing was deployed. For future large scale sequestration monitoring, an adaptive borehole-monitoring program is proposed.

Does phosphate enhance the natural attenuation of crude oil in groundwater under defined redox conditions?

PubMed

Ponsin, Violaine; Mouloubou, Olsen Raïnness; Prudent, Pascale; Höhener, Patrick

2014-11-15

After a crude oil spill caused by a broken pipeline in 2009 to a gravel aquifer in southern France, degradation processes under various redox conditions progressively established, but at rates that predict a long life-time of the source under natural attenuation after partial source removal. In this study, we aimed at identifying the rate-limiting factors for each redox condition, with special emphasis on phosphate as limiting nutrient. The study was conducted in laboratory microcosms assembled with material collected on site: sediments, water from monitoring wells, oil and microbial sludge. Redox conditions were promoted by adding electron acceptors (either oxygen, nitrate, limonite (FeO(OH)), cryptomelane (K(Mn(4+),Mn(2+))8O16), or sulfate). For each condition, the role of phosphate was studied by repeated additions for up to 290days. The results showed a very strong stimulation of aerobic and denitrifying rates of oil degradation by phosphate, provided that oxygen and nitrate were repeatedly supplied. Phosphate caused also a marked stimulation of methanogenic degradation, and a relatively small stimulation of metal reduction. These anaerobic processes started only after marked lag phases, and phosphate shortened the lag phase for methanogenic degradation. Degradation of aromatic and aliphatic hydrocarbons with less than 8 carbons, including benzene, was confirmed even under unstimulated conditions. It is concluded that degradation rates at the site are limited by both, availability of electron acceptors and availability of phosphate needed for promoting microbial growth. Copyright © 2014 Elsevier B.V. All rights reserved.

Louisiana offshore terminal authority environmental monitoring

DOT National Transportation Integrated Search

2002-09-01

The current Louisiana Offshore Oil Port (LOOP) monitoring program includes seasonal monitoring of aquatic and marine resources, sediment composition, and water quality on a five-year cycle. These data provide an update to the existing long-term LOOP ...

Short-term thermal stability of transformer and motor oils at wide range of moisture contents

NASA Astrophysics Data System (ADS)

Volosnikov, D. V.; Povolotskiy, I. I.; Skripov, P. V.

2018-01-01

Method of controlled pulse heating of a wire probe was used for studying heat transfer and thermal stability of energy oils and motor oils in the presence of low quantities of moisture. The technique of two-pulse heating is the most suitable method for monitoring the actual state of oils. A distinct signal-response accompanying the appearance of moisture in the tested sample has been revealed.