Varank, Gamze; Demir, Ahmet; Yetilmezsoy, Kaan; Bilgili, M. Sinan; Top, Selin; Sekman, Elif
2011-11-15
Highlights: > We conduct 1D advection-dispersion modeling to estimate transport parameters. > We examine fourteen phenolic compounds and three inorganic contaminants. > 2-MP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,3,4,6-TeCP have the highest coefficients. > Dispersion coefficients of Cu are determined to be higher than Zn and Fe. > Transport of phenolics can be prevented by zeolite and bentonite in landfill liners. - Abstract: One-dimensional (1D) advection-dispersion transport modeling was conducted as a conceptual approach for the estimation of the transport parameters of fourteen different phenolic compounds (phenol, 2-CP, 2-MP, 3-MP, 4-MP, 2-NP, 4-NP, 2,4-DNP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,4,6-TCP, 2,3,4,6-TeCP, PCP) and three different inorganic contaminants (Cu, Zn, Fe) migrating downward through the several liner systems. Four identical pilot-scale landfill reactors (0.25 m{sup 3}) with different composite liners (R1: 0.10 + 0.10 m of compacted clay liner (CCL), L{sub e} = 0.20 m, k{sub e} = 1 x 10{sup -8} m/s, R2: 0.002-m-thick damaged high-density polyethylene (HDPE) geomembrane overlying 0.10 + 0.10 m of CCL, L{sub e} = 0.20 m, k{sub e} = 1 x 10{sup -8} m/s, R3: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick bentonite layer encapsulated between 0.10 + 0.10 m CCL, L{sub e} = 0.22 m, k{sub e} = 1 x 10{sup -8} m/s, R4: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick zeolite layer encapsulated between 0.10 + 0.10 m CCL, L{sub e} = 0.22 m, k{sub e} = 4.24 x 10{sup -7} m/s) were simultaneously run for a period of about 540 days to investigate the nature of diffusive and advective transport of the selected organic and inorganic contaminants. The results of 1D transport model showed that the highest molecular diffusion coefficients, ranging from 4.77 x 10{sup -10} to 10.67 x 10{sup -10} m{sup 2}/s, were estimated for phenol (R4), 2-MP (R1), 2,4-DNP (R2), 2,4-DCP (R1), 2,6-DCP (R2), 2,4,5-TCP (R2) and 2,3,4,6-TeCP (R1). For all reactors
Arthur S. Rood
2005-03-30
This report describes the Mixing Cell Model code, a one-dimensional model for water flow and solute transport in the unsaturated zone under steady-state or transient flow conditions. The model is based on the principles and assumptions underlying mixing cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water flow equations are derived from the continuity equation assuming that unit-gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material-specific moisture characteristic curves. Solute transport processes include explicit treatment of advective processes, first-order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute transport equations: (1) the Mixing-Cell Model for Flow (MCMF) solves transient water flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute transport problem. The transient water flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each
A. S. Rood
2009-04-01
This report describes the Mixing Cell Model code, a one-dimensional model for water flow and solute transport in the unsaturated zone under steady-state or transient flow conditions. The model is based on the principles and assumptions underlying mixing cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water flow equations are derived from the continuity equation assuming that unit-gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material-specific moisture characteristic curves. Solute transport processes include explicit treatment of advective processes, first-order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute transport equations: (1) the Mixing-Cell Model for Flow (MCMF) solves transient water flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute transport problem. The transient water flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each
A. S. Rood
2010-10-01
This report describes the Mixing Cell Model code, a one-dimensional model for water flow and solute transport in the unsaturated zone under steady-state or transient flow conditions. The model is based on the principles and assumptions underlying mixing cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water flow equations are derived from the continuity equation assuming that unit-gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material-specific moisture characteristic curves. Solute transport processes include explicit treatment of advective processes, first-order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute transport equations: (1) the Mixing-Cell Model for Flow (MCMF) solves transient water flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute transport problem. The transient water flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each
A. S. Rood
2005-03-01
This report describes the Mixing Cell Model code, a one-dimensional model for water flow and solute transport in the unsaturated zone under steady-state or transient flow conditions. The model is based on the principles and assumptions underlying mixing cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water flow equations are derived from the continuity equation assuming that unit-gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material-specific moisture characteristic curves. Solute transport processes include explicit treatment of advective processes, first-order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute transport equations: (1) the Mixing-Cell Model for Flow (MCMF) solves transient water flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute transport problem. The transient water flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each
Algorithms and a short description of the D1_Flow program for numerical modeling of one-dimensional steady-state flow in horizontally heterogeneous aquifers with uneven sloping bases are presented. The algorithms are based on the Dupuit-Forchheimer approximations. The program per...
SIMPLE ONE-DIMENSIONAL TRANSPORT CODE FOR MAGNETIZED TARGET FUSION
STEFANO MIGLUIOLO - MIT
1999-10-30
A one-dimensional (in space) time-dependent simulation code is development to study the transport of energy and particles in a field reversed configuration (FRC) plasma that is undergoing radial contraction. This contraction is due to an imploding metallic liner, which is treated through a boundary condition.
Duality and phase diagram of one-dimensional transport
NASA Astrophysics Data System (ADS)
Bhattacharjee, Somendra M.
2007-02-01
The idea of duality in one-dimensional nonequilibrium transport is introduced by generalizing the observations by Mukherji and Mishra. A general approach is developed for the classification and characterization of the steady state phase diagrams which are shown to be determined by the nature of the zeros of a set of coarse-grained functions that encode the microscopic dynamics. A new class of nonequilibrium multicritical points has been identified.
Users manual for a one-dimensional Lagrangian transport model
Schoellhamer, D.H.; Jobson, H.E.
1986-01-01
A Users Manual for the Lagrangian Transport Model (LTM) is presented. The LTM uses Lagrangian calculations that are based on a reference frame moving with the river flow. The Lagrangian reference frame eliminates the need to numerically solve the convective term of the convection-diffusion equation and provides significant numerical advantages over the more commonly used Eulerian reference frame. When properly applied, the LTM can simulate riverine transport and decay processes within the accuracy required by most water quality studies. The LTM is applicable to steady or unsteady one-dimensional unidirectional flows in fixed channels with tributary and lateral inflows. Application of the LTM is relatively simple and optional capabilities improve the model 's convenience. Appendices give file formats and three example LTM applications that include the incorporation of the QUAL II water quality model 's reaction kinetics into the LTM. (Author 's abstract)
Quasi one dimensional transport in individual electrospun composite nanofibers
Avnon, A. Datsyuk, V.; Trotsenko, S.; Wang, B.; Zhou, S.
2014-01-15
We present results of transport measurements of individual suspended electrospun nanofibers Poly(methyl methacrylate)-multiwalled carbon nanotubes. The nanofiber is comprised of highly aligned consecutive multiwalled carbon nanotubes. We have confirmed that at the range temperature from room temperature down to ∼60 K, the conductance behaves as power-law of temperature with an exponent of α ∼ 2.9−10.2. The current also behaves as power law of voltage with an exponent of β ∼ 2.3−8.6. The power-law behavior is a footprint for one dimensional transport. The possible models of this confined system are discussed. Using the model of Luttinger liquid states in series, we calculated the exponent for tunneling into the bulk of a single multiwalled carbon nanotube α{sub bulk} ∼ 0.06 which agrees with theoretical predictions.
Energy transport in one-dimensional disordered granular solids.
Achilleos, V; Theocharis, G; Skokos, Ch
2016-02-01
We investigate the energy transport in one-dimensional disordered granular solids by extensive numerical simulations. In particular, we consider the case of a polydisperse granular chain composed of spherical beads of the same material and with radii taken from a random distribution. We start by examining the linear case, in which it is known that the energy transport strongly depends on the type of initial conditions. Thus, we consider two sets of initial conditions: an initial displacement and an initial momentum excitation of a single bead. After establishing the regime of sufficiently strong disorder, we focus our study on the role of nonlinearity for both sets of initial conditions. By increasing the initial excitation amplitudes we are able to identify three distinct dynamical regimes with different energy transport properties: a near linear, a weakly nonlinear, and a highly nonlinear regime. Although energy spreading is found to be increasing for higher nonlinearities, in the weakly nonlinear regime no clear asymptotic behavior of the spreading is found. In this regime, we additionally find that energy, initially trapped in a localized region, can be eventually detrapped and this has a direct influence on the fluctuations of the energy spreading. We also demonstrate that in the highly nonlinear regime, the differences in energy transport between the two sets of initial conditions vanish. Actually, in this regime the energy is almost ballistically transported through shocklike excitations.
Charge transport through one-dimensional Moiré crystals
Bonnet, Roméo; Lherbier, Aurélien; Barraud, Clément; Rocca, Maria Luisa Della; Lafarge, Philippe; Charlier, Jean-Christophe
2016-01-01
Moiré superlattices were generated in two-dimensional (2D) van der Waals heterostructures and have revealed intriguing electronic structures. The appearance of mini-Dirac cones within the conduction and valence bands of graphene is one of the most striking among the new quantum features. A Moiré superstructure emerges when at least two periodic sub-structures superimpose. 2D Moiré patterns have been particularly investigated in stacked hexagonal 2D atomic lattices like twisted graphene layers and graphene deposited on hexagonal boron-nitride. In this letter, we report both experimentally and theoretically evidence of superlattices physics in transport properties of one-dimensional (1D) Moiré crystals. Rolling-up few layers of graphene to form a multiwall carbon nanotube adds boundaries conditions that can be translated into interference fringes-like Moiré patterns along the circumference of the cylinder. Such a 1D Moiré crystal exhibits a complex 1D multiple bands structure with clear and robust interband quantum transitions due to the presence of mini-Dirac points and pseudo-gaps. Our devices consist in a very large diameter (>80 nm) multiwall carbon nanotubes of high quality, electrically connected by metallic electrodes acting as charge reservoirs. Conductance measurements reveal the presence of van Hove singularities assigned to 1D Moiré superlattice effect and illustrated by electronic structure calculations. PMID:26786067
Charge transport through one-dimensional Moiré crystals
NASA Astrophysics Data System (ADS)
Bonnet, Roméo; Lherbier, Aurélien; Barraud, Clément; Rocca, Maria Luisa Della; Lafarge, Philippe; Charlier, Jean-Christophe
2016-01-01
Moiré superlattices were generated in two-dimensional (2D) van der Waals heterostructures and have revealed intriguing electronic structures. The appearance of mini-Dirac cones within the conduction and valence bands of graphene is one of the most striking among the new quantum features. A Moiré superstructure emerges when at least two periodic sub-structures superimpose. 2D Moiré patterns have been particularly investigated in stacked hexagonal 2D atomic lattices like twisted graphene layers and graphene deposited on hexagonal boron-nitride. In this letter, we report both experimentally and theoretically evidence of superlattices physics in transport properties of one-dimensional (1D) Moiré crystals. Rolling-up few layers of graphene to form a multiwall carbon nanotube adds boundaries conditions that can be translated into interference fringes-like Moiré patterns along the circumference of the cylinder. Such a 1D Moiré crystal exhibits a complex 1D multiple bands structure with clear and robust interband quantum transitions due to the presence of mini-Dirac points and pseudo-gaps. Our devices consist in a very large diameter (>80 nm) multiwall carbon nanotubes of high quality, electrically connected by metallic electrodes acting as charge reservoirs. Conductance measurements reveal the presence of van Hove singularities assigned to 1D Moiré superlattice effect and illustrated by electronic structure calculations.
Nonequilibrium electronic transport in a one-dimensional Mott insulator
Heidrich-Meisner, F.; Gonzalez, Ivan; Al-Hassanieh, K. A.; Feiguin, A. E.; Rozenberg, M. J.; Dagotto, Elbio R
2010-01-01
We calculate the nonequilibrium electronic transport properties of a one-dimensional interacting chain at half filling, coupled to noninteracting leads. The interacting chain is initially in a Mott insulator state that is driven out of equilibrium by applying a strong bias voltage between the leads. For bias voltages above a certain threshold we observe the breakdown of the Mott insulator state and the establishment of a steady-state elec- tronic current through the system. Based on extensive time-dependent density-matrix renormalization-group simulations, we show that this steady-state current always has the same functional dependence on voltage, independent of the microscopic details of the model and we relate the value of the threshold to the Lieb-Wu gap. We frame our results in terms of the Landau-Zener dielectric breakdown picture. Finally, we also discuss the real-time evolution of the current, and characterize the current-carrying state resulting from the breakdown of the Mott insulator by computing the double occupancy, the spin structure factor, and the entanglement entropy.
Ballistic transport in one-dimensional random dimer photonic crystals
NASA Astrophysics Data System (ADS)
Cherid, Samira; Bentata, Samir; Zitouni, Ali; Djelti, Radouan; Aziz, Zoubir
2014-04-01
Using the transfer-matrix technique and the Kronig Penney model, we numerically and analytically investigate the effect of short-range correlated disorder in Random Dimer Model (RDM) on transmission properties of the light in one dimensional photonic crystals made of three different materials. Such systems consist of two different structures randomly distributed along the growth direction, with the additional constraint that one kind of these layers always appear in pairs. It is shown that the one dimensional random dimer photonic crystals support two types of extended modes. By shifting of the dimer resonance toward the host fundamental stationary resonance state, we demonstrate the existence of the ballistic response in these systems.
Xu, Bruce S; Lollar, Barbara Sherwood; Passeport, Elodie; Sleep, Brent E
2016-04-15
Aqueous phase diffusion-related isotope fractionation (DRIF) for carbon isotopes was investigated for common groundwater contaminants in systems in which transport could be considered to be one-dimensional. This paper focuses not only on theoretically observable DRIF effects in these systems but introduces the important concept of constraining "observable" DRIF based on constraints imposed by the scale of measurements in the field, and on standard limits of detection and analytical uncertainty. Specifically, constraints for the detection of DRIF were determined in terms of the diffusive fractionation factor, the initial concentration of contaminants (C0), the method detection limit (MDL) for isotopic analysis, the transport time, and the ratio of the longitudinal mechanical dispersion coefficient to effective molecular diffusion coefficient (Dmech/Deff). The results allow a determination of field conditions under which DRIF may be an important factor in the use of stable carbon isotope measurements for evaluation of contaminant transport and transformation for one-dimensional advective-dispersive transport. This study demonstrates that for diffusion-dominated transport of BTEX, MTBE, and chlorinated ethenes, DRIF effects are only detectable for the smaller molar mass compounds such as vinyl chloride for C0/MDL ratios of 50 or higher. Much larger C0/MDL ratios, corresponding to higher source concentrations or lower detection limits, are necessary for DRIF to be detectable for the higher molar mass compounds. The distance over which DRIF is observable for VC is small (less than 1m) for a relatively young diffusive plume (<100years), and DRIF will not easily be detected by using the conventional sampling approach with "typical" well spacing (at least several meters). With contaminant transport by advection, mechanical dispersion, and molecular diffusion this study suggests that in field sites where Dmech/Deff is larger than 10, DRIF effects will likely not be
Characterization of Thermal Transport in One-dimensional Solid Materials
Liu, Guoqing; Lin, Huan; Tang, Xiaoduan; Bergler, Kevin; Wang, Xinwei
2014-01-01
The TET (transient electro-thermal) technique is an effective approach developed to measure the thermal diffusivity of solid materials, including conductive, semi-conductive or nonconductive one-dimensional structures. This technique broadens the measurement scope of materials (conductive and nonconductive) and improves the accuracy and stability. If the sample (especially biomaterials, such as human head hair, spider silk, and silkworm silk) is not conductive, it will be coated with a gold layer to make it electronically conductive. The effect of parasitic conduction and radiative losses on the thermal diffusivity can be subtracted during data processing. Then the real thermal conductivity can be calculated with the given value of volume-based specific heat (ρcp), which can be obtained from calibration, noncontact photo-thermal technique or measuring the density and specific heat separately. In this work, human head hair samples are used to show how to set up the experiment, process the experimental data, and subtract the effect of parasitic conduction and radiative losses. PMID:24514072
Thermal transport in disordered one-dimensional spin chains
NASA Astrophysics Data System (ADS)
Poboiko, Igor; Feigel'man, Mikhail
2015-12-01
We study a one-dimensional anisotropic XXZ Heisenberg spin-1/2 chain with weak random fields hizSiz by means of Jordan-Wigner transformation to spinless Luttinger liquid with disorder and bosonization technique. First, we reinvestigate the phase diagram of the system in terms of dimensionless disorder γ =
Half-range acceleration for one-dimensional transport problems
Zika, M.R.; Larsen, E.W.
1998-12-31
Researchers have devoted considerable effort to developing acceleration techniques for transport iterations in highly diffusive problems. The advantages and disadvantages of source iteration, rebalance, diffusion synthetic acceleration (DSA), transport synthetic acceleration (TSA), and projection acceleration methods are documented in the literature and will not be discussed here except to note that no single method has proven to be applicable to all situations. Here, the authors describe a new acceleration method that is based solely on transport sweeps, is algebraically linear (and is therefore amenable to a Fourier analysis), and yields a theoretical spectral radius bounded by one-third for all cases. This method does not introduce spatial differencing difficulties (as is the case for DSA) nor does its theoretical performance degrade as a function of mesh and material properties (as is the case for TSA). Practical simulations of the new method agree with the theoretical predictions, except for scattering ratios very close to unity. At this time, they believe that the discrepancy is due to the effect of boundary conditions. This is discussed further.
NASA Astrophysics Data System (ADS)
Pérez Guerrero, J. S.; Skaggs, T. H.
2010-08-01
SummaryMathematical models describing contaminant transport in heterogeneous porous media are often formulated as an advection-dispersion transport equation with distance-dependent transport coefficients. In this work, a general analytical solution is presented for the linear, one-dimensional advection-dispersion equation with distance-dependent coefficients. An integrating factor is employed to obtain a transport equation that has a self-adjoint differential operator, and a solution is found using the generalized integral transform technique (GITT). It is demonstrated that an analytical expression for the integrating factor exists for several transport equation formulations of practical importance in groundwater transport modeling. Unlike nearly all solutions available in the literature, the current solution is developed for a finite spatial domain. As an illustration, solutions for the particular case of a linearly increasing dispersivity are developed in detail and results are compared with solutions from the literature. Among other applications, the current analytical solution will be particularly useful for testing or benchmarking numerical transport codes because of the incorporation of a finite spatial domain.
A one-dimensional heat-transport model for conduit flow in karst aquifers
Long, A.J.; Gilcrease, P.C.
2009-01-01
A one-dimensional heat-transport model for conduit flow in karst aquifers is presented as an alternative to two or three-dimensional distributed-parameter models, which are data intensive and require knowledge of conduit locations. This model can be applied for cases where water temperature in a well or spring receives all or part of its water from a phreatic conduit. Heat transport in the conduit is simulated by using a physically-based heat-transport equation that accounts for inflow of diffuse flow from smaller openings and fissures in the surrounding aquifer during periods of low recharge. Additional diffuse flow that is within the zone of influence of the well or spring but has not interacted with the conduit is accounted for with a binary mixing equation to proportion these different water sources. The estimation of this proportion through inverse modeling is useful for the assessment of contaminant vulnerability and well-head or spring protection. The model was applied to 7 months of continuous temperature data for a sinking stream that recharges a conduit and a pumped well open to the Madison aquifer in western South Dakota. The simulated conduit-flow fraction to the well ranged from 2% to 31% of total flow, and simulated conduit velocity ranged from 44 to 353 m/d.
Robust unidirectional transport in a one-dimensional metacrystal with long-range hopping
NASA Astrophysics Data System (ADS)
Longhi, S.
2016-11-01
In two- and three-dimensional structures, topologically protected chiral edge modes offer a powerful mean to realize robust light transport. However, little attention has been paid so far to robust one-way transport in one-dimensional systems. Here it is shown that unidirectional transport, which is immune to disorder and backscattering, can occur in certain one-dimensional metacrystals with long-range hopping without resorting to topological protection. Such metacrystals are described by an effective Hermitian Hamiltonian with broken time-reversal symmetry, and transport does not require adiabatic (Thouless) pumping. A simple implementation in optics of such one-dimensional metacrystals, based on transverse light dynamics in a self-imaging optical cavity with phase gratings, is suggested.
Li, Lei; Liang, Lizhi; Wu, Heng; Zhu, Xinhua
2016-12-01
One-dimensional nanostructures, including nanowires, nanorods, nanotubes, nanofibers, and nanobelts, have promising applications in mesoscopic physics and nanoscale devices. In contrast to other nanostructures, one-dimensional nanostructures can provide unique advantages in investigating the size and dimensionality dependence of the materials' physical properties, such as electrical, thermal, and mechanical performances, and in constructing nanoscale electronic and optoelectronic devices. Among the one-dimensional nanostructures, one-dimensional perovskite manganite nanostructures have been received much attention due to their unusual electron transport and magnetic properties, which are indispensable for the applications in microelectronic, magnetic, and spintronic devices. In the past two decades, much effort has been made to synthesize and characterize one-dimensional perovskite manganite nanostructures in the forms of nanorods, nanowires, nanotubes, and nanobelts. Various physical and chemical deposition techniques and growth mechanisms are explored and developed to control the morphology, identical shape, uniform size, crystalline structure, defects, and homogenous stoichiometry of the one-dimensional perovskite manganite nanostructures. This article provides a comprehensive review of the state-of-the-art research activities that focus on the rational synthesis, structural characterization, fundamental properties, and unique applications of one-dimensional perovskite manganite nanostructures in nanotechnology. It begins with the rational synthesis of one-dimensional perovskite manganite nanostructures and then summarizes their structural characterizations. Fundamental physical properties of one-dimensional perovskite manganite nanostructures are also highlighted, and a range of unique applications in information storages, field-effect transistors, and spintronic devices are discussed. Finally, we conclude this review with some perspectives/outlook and future
ONE-DIMENSIONAL HYDRODYNAMIC/SEDIMENT TRANSPORT MODEL FOR STREAM NETWORKS: TECHNICAL REPORT
This technical report describes a new sediment transport model and the supporting post-processor, and sampling procedures for sediments in streams. Specifically, the following items are described herein:
EFDC1D - This is a new one-dimensional hydrodynamic and sediment tr...
Perturbative and iterative methods for photon transport in one-dimensional waveguides
NASA Astrophysics Data System (ADS)
Obi, Kenechukwu C.; Shen, Jung-Tsung
2015-05-01
The problems of photon transport in one-dimensional waveguides have recently attracted great attentions. We consider the case of single photons scattering off a Λ-type three-level quantum emitter, and discuss the perturbative treatments of the scattering processes in terms of Born approximation for the Lippmann-Schwinger formalism. We show that the iterative Born series of the scattering amplitudes converge to the exact results obtained by other approaches. The generalization of our work provides a foundational basis for efficient computational schemes for photon scattering problems in one-dimensional waveguides.
One-dimensional electronic transport at the organic charge-transfer interfaces under high pressures
Kang, N.; Auban-Senzier, P.; Li, C.; Poulard, C.; Pasquier, C. R.
2014-05-12
We have characterized the charge transport properties of the electronic state at the interface between tetrathiofulvalene and 7,7,8,8-tetracyanoquinodimethane organic crystals as a function of pressure. At low temperature and for all studied pressures, the conductance and the current through the interface exhibit a power-law dependence on both temperature and bias voltage which reveal features of quasi-one-dimensional character. The transport behavior as well as the pressure dependence of the power-law exponent is consistent with a one-dimensional Wigner crystal model. Our results demonstrate that organic heterointerfaces can provide an ideal platform for exploring the rich electronic phenomena in low-dimensional systems.
Rapid water transportation through narrow one-dimensional channels by restricted hydrogen bonds.
Ohba, Tomonori; Kaneko, Katsumi; Endo, Morinobu; Hata, Kenji; Kanoh, Hirofumi
2013-01-29
Water plays an important role in controlling chemical reactions and bioactivities. For example, water transportation through water channels in a biomembrane is a key factor in bioactivities. However, molecular-level mechanisms of water transportation are as yet unknown. Here, we investigate water transportation through narrow and wide one-dimensional (1D) channels on the basis of water-vapor adsorption rates and those determined by molecular dynamics simulations. We observed that water in narrow 1D channels was transported 3-5 times faster than that in wide 1D channels, although the narrow 1D channels provide fewer free nanospaces for water transportation. This rapid transportation is attributed to the formation of fewer hydrogen bonds between water molecules adsorbed in narrow 1D channels. The water-transportation mechanism provides the possibility of rapid communication through 1D channels and will be useful in controlling reactions and activities in water systems.
An exact solution of solute transport by one-dimensional random velocity fields
Cvetkovic, V.D.; Dagan, G.; Shapiro, A.M.
1991-01-01
The problem of one-dimensional transport of passive solute by a random steady velocity field is investigated. This problem is representative of solute movement in porous media, for example, in vertical flow through a horizontally stratified formation of variable porosity with a constant flux at the soil surface. Relating moments of particle travel time and displacement, exact expressions for the advection and dispersion coefficients in the Focker-Planck equation are compared with the perturbation results for large distances. The first- and second-order approximations for the dispersion coefficient are robust for a lognormal velocity field. The mean Lagrangian velocity is the harmonic mean of the Eulerian velocity for large distances. This is an artifact of one-dimensional flow where the continuity equation provides for a divergence free fluid flux, rather than a divergence free fluid velocity. ?? 1991 Springer-Verlag.
Electron trapping and transport by supersonic solitons in one-dimensional systems
NASA Technical Reports Server (NTRS)
Zmuidzinas, J. S.
1978-01-01
A one-dimensional chain of ions or molecules and electrons described by a Froehlich-type Hamiltonian with quartic phonon anharmonicities is investigated. It is shown that the anharmonic lattice supports supersonic solitons which under favorable circumstances may trap electrons and transport them along the lattice. For a lattice constant/soliton spatial extent quotient of the order of 0.1, rough estimates give electron trapping energies in the meV range. They imply a useful temperature range, up to tens of degrees K, for observing the new effect. The activation energy of a lattice soliton is proportional to the molecular mass and is therefore quite high (about 1 eV) for typical quasi-one-dimensional organic systems.
Wuebbles, D.J.
1981-09-01
Since the LLNL one-dimensional coupled transport and chemical kinetics model of the troposphere and stratosphere was originally developed in 1972 (Chang et al., 1974), there have been many changes to the model's representation of atmospheric physical and chemical processes. A brief description is given of the current LLNL one-dimensional coupled transport and chemical kinetics model of the troposphere and stratosphere.
Coulomb blockade and transport in a chain of one-dimensional quantum dots.
Fogler, Michael M; Malinin, Sergey V; Nattermann, Thomas
2006-09-01
A long one-dimensional wire with a finite density of strong random impurities is modeled as a chain of weakly coupled quantum dots. At low temperature T and applied voltage V its resistance is limited by breaks: randomly occurring clusters of quantum dots with a special length distribution pattern that inhibit the transport. Because of the interplay of interaction and disorder effects the resistance can exhibit T and V dependences that can be approximated by power laws. The corresponding two exponents differ greatly from each other and depend not only on the intrinsic electronic parameters but also on the impurity distribution statistics.
Non-ohmic variable-range hopping transport in one-dimensional conductors.
Fogler, M M; Kelley, R S
2005-10-14
We investigate theoretically the effect of a finite electric field on the resistivity of a disordered one-dimensional system in the variable-range hopping regime. We find that at low fields the transport is inhibited by rare fluctuations in the random distribution of localized states that create high-resistance breaks in the hopping network. As the field increases, the breaks become less resistive. In strong fields the breaks are overrun and the electron distribution function is driven far from equilibrium. The logarithm of the resistance initially shows a simple exponential drop with the field, followed by a logarithmic dependence, and finally, by an inverse square-root law.
Photon transport in a one-dimensional nanophotonic waveguide QED system
NASA Astrophysics Data System (ADS)
Liao, Zeyang; Zeng, Xiaodong; Nha, Hyunchul; Zubairy, M. Suhail
2016-06-01
The waveguide quantum electrodynamics (QED) system may have important applications in quantum device and quantum information technology. In this article we review the methods being proposed to calculate photon transport in a one-dimensional (1D) waveguide coupled to quantum emitters. We first introduce the Bethe ansatz approach and the input-output formalism to calculate the stationary results of a single photon transport. Then we present a dynamical time-dependent theory to calculate the real-time evolution of the waveguide QED system. In the longtime limit, both the stationary theory and the dynamical calculation give the same results. Finally, we also briefly discuss the calculations of the multiphoton transport problems.
Proceedings of the Advanced Seminar on one-dimensional, open-channel Flow and transport modeling
Schaffranek, Raymond W.
1989-01-01
In view of the increased use of mathematical/numerical simulation models, of the diversity of both model investigations and informational project objectives, and of the technical demands of complex model applications by U.S. Geological Survey personnel, an advanced seminar on one-dimensional open-channel flow and transport modeling was organized and held on June 15-18, 1987, at the National Space Technology Laboratory, Bay St. Louis, Mississippi. Principal emphasis in the Seminar was on one-dimensional flow and transport model-implementation techniques, operational practices, and application considerations. The purposes of the Seminar were to provide a forum for the exchange of information, knowledge, and experience among model users, as well as to identify immediate and future needs with respect to model development and enhancement, user support, training requirements, and technology transfer. The Seminar program consisted of a mix of topical and project presentations by Geological Survey personnel. This report is a compilation of short papers that summarize the presentations made at the Seminar.
Eigen decomposition solution to the one-dimensional time-dependent photon transport equation.
Handapangoda, Chintha C; Pathirana, Pubudu N; Premaratne, Malin
2011-02-14
The time-dependent one-dimensional photon transport (radiative transfer) equation is widely used to model light propagation through turbid media with a slab geometry, in a vast number of disciplines. Several numerical and semi-analytical techniques are available to accurately solve this equation. In this work we propose a novel efficient solution technique based on eigen decomposition of the vectorized version of the photon transport equation. Using clever transformations, the four variable integro-differential equation is reduced to a set of first order ordinary differential equations using a combination of a spectral method and the discrete ordinates method. An eigen decomposition approach is then utilized to obtain the closed-form solution of this reduced set of ordinary differential equations.
Single photon transport along a one-dimensional waveguide with a side manipulated cavity QED system.
Yan, Cong-Hua; Wei, Lian-Fu
2015-04-20
An external mirror coupling to a cavity with a two-level atom inside is put forward to control the photon transport along a one-dimensional waveguide. Using a full quantum theory of photon transport in real space, it is shown that the Rabi splittings of the photonic transmission spectra can be controlled by the cavity-mirror couplings; the splittings could still be observed even when the cavity-atom system works in the weak coupling regime, and the transmission probability of the resonant photon can be modulated from 0 to 100%. Additionally, our numerical results show that the appearance of Fano resonance is related to the strengths of the cavity-mirror coupling and the dissipations of the system. An experimental demonstration of the proposal with the current photonic crystal waveguide technique is suggested.
Ballistic one-dimensional transport in InAs nanowires monolithically integrated on silicon
NASA Astrophysics Data System (ADS)
Gooth, J.; Schaller, V.; Wirths, S.; Schmid, H.; Borg, M.; Bologna, N.; Karg, S.; Riel, H.
2017-02-01
We present the monolithic integration and electrical characterization of InAs nanowires (NWs) with the well-defined geometries and positions on Si as a platform for quantum transport studies. Hereby, one-dimensional (1D) ballistic transport with step-like 1D conductance quantization in units of 2e2/h is demonstrated for NWs with the widths between 28 nm and 58 nm and a height of 40 nm. The electric field control of up to four individual modes is achieved. Furthermore, the sub-band structure of the nanowires is investigated using bias spectroscopy. The splitting between the first and the second sub-band increases as the width of the NWs is reduced, whereas the degeneracy of the second sub-band can be tuned by the symmetry of the NW cross section, in accordance with a "particle in a box" model. The length-dependent studies reveal ballistic transport for up to 300 nm and quasi-ballistic transport with a mean free path of 470 nm for longer InAs NW channels at 30 K. We anticipate that the ballistic 1D transport in monolithically integrated InAs NWs presented here will form the basis for sophisticated quantum wire devices for the future integrated circuits with additional functionalities.
NASA Astrophysics Data System (ADS)
Kopelevich, Dmitry I.
2013-10-01
Transport of a fullerene-like nanoparticle across a lipid bilayer is investigated by coarse-grained molecular dynamics (MD) simulations. Potentials of mean force (PMF) acting on the nanoparticle in a flexible bilayer suspended in water and a bilayer restrained to a flat surface are computed by constrained MD simulations. The rate of the nanoparticle transport into the bilayer interior is predicted using one-dimensional Langevin models based on these PMFs. The predictions are compared with the transport rates obtained from a series of direct (unconstrained) MD simulations of the solute transport into the flexible bilayer. It is observed that the PMF acting on the solute in the flexible membrane underestimates the transport rate by more than an order of magnitude while the PMF acting on the solute in the restrained membrane yields an accurate estimate of the activation energy for transport into the flexible membrane. This paradox is explained by a coexistence of metastable membrane configurations for a range of the solute positions inside and near the flexible membrane. This leads to a significant reduction of the contribution of the transition state to the mean force acting on the solute. Restraining the membrane shape ensures that there is only one stable membrane configuration corresponding to each solute position and thus the transition state is adequately represented in the PMF. This mechanism is quite general and thus this phenomenon is expected to occur in a wide range of interfacial systems. A simple model for the free energy landscape of the coupled solute-membrane system is proposed and validated. This model explicitly accounts for effects of the membrane deformations on the solute transport and yields an accurate prediction of the activation energy for the solute transport.
Kopelevich, Dmitry I
2013-10-07
Transport of a fullerene-like nanoparticle across a lipid bilayer is investigated by coarse-grained molecular dynamics (MD) simulations. Potentials of mean force (PMF) acting on the nanoparticle in a flexible bilayer suspended in water and a bilayer restrained to a flat surface are computed by constrained MD simulations. The rate of the nanoparticle transport into the bilayer interior is predicted using one-dimensional Langevin models based on these PMFs. The predictions are compared with the transport rates obtained from a series of direct (unconstrained) MD simulations of the solute transport into the flexible bilayer. It is observed that the PMF acting on the solute in the flexible membrane underestimates the transport rate by more than an order of magnitude while the PMF acting on the solute in the restrained membrane yields an accurate estimate of the activation energy for transport into the flexible membrane. This paradox is explained by a coexistence of metastable membrane configurations for a range of the solute positions inside and near the flexible membrane. This leads to a significant reduction of the contribution of the transition state to the mean force acting on the solute. Restraining the membrane shape ensures that there is only one stable membrane configuration corresponding to each solute position and thus the transition state is adequately represented in the PMF. This mechanism is quite general and thus this phenomenon is expected to occur in a wide range of interfacial systems. A simple model for the free energy landscape of the coupled solute-membrane system is proposed and validated. This model explicitly accounts for effects of the membrane deformations on the solute transport and yields an accurate prediction of the activation energy for the solute transport.
Analytically-derived sensitivities in one-dimensional models of solute transport in porous media
Knopman, D.S.
1987-01-01
Analytically-derived sensitivities are presented for parameters in one-dimensional models of solute transport in porous media. Sensitivities were derived by direct differentiation of closed form solutions for each of the odel, and by a time integral method for two of the models. Models are based on the advection-dispersion equation and include adsorption and first-order chemical decay. Boundary conditions considered are: a constant step input of solute, constant flux input of solute, and exponentially decaying input of solute at the upstream boundary. A zero flux is assumed at the downstream boundary. Initial conditions include a constant and spatially varying distribution of solute. One model simulates the mixing of solute in an observation well from individual layers in a multilayer aquifer system. Computer programs produce output files compatible with graphics software in which sensitivities are plotted as a function of either time or space. (USGS)
Anomalous quantum heat transport in a one-dimensional harmonic chain with random couplings.
Yan, Yonghong; Zhao, Hui
2012-07-11
We investigate quantum heat transport in a one-dimensional harmonic system with random couplings. In the presence of randomness, phonon modes may normally be classified as ballistic, diffusive or localized. We show that these modes can roughly be characterized by the local nearest-neighbor level spacing distribution, similarly to their electronic counterparts. We also show that the thermal conductance G(th) through the system decays rapidly with the system size (G(th) ∼ L(-α)). The exponent α strongly depends on the system size and can change from α < 1 to α > 1 with increasing system size, indicating that the system undergoes a transition from a heat conductor to a heat insulator. This result could be useful in thermal control of low-dimensional systems.
Lee, Sang Uck; Mizuseki, Hiroshi; Kawazoe, Yoshiyuki
2010-12-01
We present a systematic analysis of electron transport characteristics for one-dimensional heterojunctions with two multi-nitrogen-doped (multi-N-doped) capped carbon nanotubes (CNTs) facing one another at different numbers of nitrogen atoms and conformations. Our results show that the modification of the molecular orbitals by the nitrogen dopants generates conducting channels in the designed heterojunctions inducing multi-switching behavior with sequential negative differential resistance (NDR). The NDR behavior significantly depends on the doping site and conformation of doped nitrogen atoms. Furthermore, we provide a clear interpretation for the NDR behavior by a rigid shift model of the HOMO- and LUMO-filtered energy levels in the left and right electrodes under the applied biases. We believe that our results will give an insight into the design and implementation of various electronic logic functions based on CNTs for applications in the field of nanoelectronics.
A comprehensive one-dimensional numerical model for solute transport in rivers
NASA Astrophysics Data System (ADS)
Barati Moghaddam, Maryam; Mazaheri, Mehdi; MohammadVali Samani, Jamal
2017-01-01
One of the mechanisms that greatly affect the pollutant transport in rivers, especially in mountain streams, is the effect of transient storage zones. The main effect of these zones is to retain pollutants temporarily and then release them gradually. Transient storage zones indirectly influence all phenomena related to mass transport in rivers. This paper presents the TOASTS (third-order accuracy simulation of transient storage) model to simulate 1-D pollutant transport in rivers with irregular cross-sections under unsteady flow and transient storage zones. The proposed model was verified versus some analytical solutions and a 2-D hydrodynamic model. In addition, in order to demonstrate the model applicability, two hypothetical examples were designed and four sets of well-established frequently cited tracer study data were used. These cases cover different processes governing transport, cross-section types and flow regimes. The results of the TOASTS model, in comparison with two common contaminant transport models, shows better accuracy and numerical stability.
NASA Astrophysics Data System (ADS)
Paradiso, Daniele; Perelli Cippo, Enrico; Gorini, Giuseppe; Rossi, Giorgio; Larese, John Z.
The development of new materials for use in energy and environmental applications is of great interest, in particular in the areas of gas separation and carbon capture, where molecular transport plays a significant role. The dipeptides are organic molecules that offer an attractive possibility in such areas, because they form open hexagonal crystalline structures (space group P61) with quasi one-dimensional channels of tunable pore diameters in the range 3-6 Å. These molecular crystals exhibit selective adsorption, as well as, water and gas transport properties: these are believed to result from collective vibrations of the crystal structure that are coupled to the motions of the guest molecules within the channels. Current studies focus on characterizing the system methane and L-Isoleucyl-L-Valine (IV): this was initially done with high-resolution adsorption isotherms; then, high-resolution Inelastic Neutron Scattering measurements at the Spallation Neutron Source (BASIS spectrometer) revealed clear rotational tunneling peaks, offering details to unravel the potential energy surface of the system, as well as, evidences that channels flexibility and dynamical motion of the molecules have influence on the dipeptides adsorption properties.
Runkel, Robert L.
2010-01-01
OTEQ is a mathematical simulation model used to characterize the fate and transport of waterborne solutes in streams and rivers. The model is formed by coupling a solute transport model with a chemical equilibrium submodel. The solute transport model is based on OTIS, a model that considers the physical processes of advection, dispersion, lateral inflow, and transient storage. The equilibrium submodel is based on MINTEQ, a model that considers the speciation and complexation of aqueous species, acid-base reactions, precipitation/dissolution, and sorption. Within OTEQ, reactions in the water column may result in the formation of solid phases (precipitates and sorbed species) that are subject to downstream transport and settling processes. Solid phases on the streambed may also interact with the water column through dissolution and sorption/desorption reactions. Consideration of both mobile (waterborne) and immobile (streambed) solid phases requires a unique set of governing differential equations and solution techniques that are developed herein. The partial differential equations describing physical transport and the algebraic equations describing chemical equilibria are coupled using the sequential iteration approach. The model's ability to simulate pH, precipitation/dissolution, and pH-dependent sorption provides a means of evaluating the complex interactions between instream chemistry and hydrologic transport at the field scale. This report details the development and application of OTEQ. Sections of the report describe model theory, input/output specifications, model applications, and installation instructions. OTEQ may be obtained over the Internet at http://water.usgs.gov/software/OTEQ.
One-dimensional numerical modeling of sediment transport and bed deformation in open channels
NASA Astrophysics Data System (ADS)
El Kadi Abderrezzak, Kamal; Paquier, André
2009-05-01
A one-dimensional numerical model for simulating unsteady flow and sediment transport in open channels is presented and tested. The flow hydrodynamics is represented by the shallow water equations, and the bed morphodynamics is represented by the Exner equation and an additional equation describing the nonequilibrium sediment transport. Sediment size distribution is represented by the median grain diameter and the standard deviation, instead of the usual modeling with multiple particle size classes. Various methods for computing bed elevation changes at a cross section due to erosion or deposition of sediment are proposed and tested, including an innovative approach that relates the spatial pattern of erosion and deposition rates to boundary shear stress distribution, which is calculated by the Merged Perpendicular Method. An explicit finite difference scheme is employed for solving the water and sediment governing equations. The pertinence of the model is examined for two hypothetical cases. The model is then tested on one set of laboratory experiments on bed degradation under steady flow, showing excellent model data fit, and indicating that incorporating a nonequilibrium sediment transport equation into the model structure is an important element in reproducing the bed degradation process. Finally, the model is applied to simulate the morphological changes taking place in the Ha!Ha! River (Quebec) after the failure of the Ha!Ha! Dyke on July 1996. Relevant results can be obtained in terms of changes in longitudinal bed profile and cross-sectional geometry as well as water levels, although some discrepancies are obtained between the simulated and surveyed cross-sectional geometries, mainly because bank failure and channel widening are not modeled.
Electronic transport properties in random one-dimensional chains containing mesoscopic-ring defects
NASA Astrophysics Data System (ADS)
Huang, X.
1999-11-01
We study the electronic transport properties in one-dimensional systems with two kinds of mesoscopic ring defects: squarelike mesoscopic ring (SMR) defects and siamese-twins-like mescoscopic ring (STMR) defects. By using the transfer-matrix method, the resonant energies (where the transmission coefficient T=1) are derived successfully for both system. For the one SMR defect system, two resonant energies are found as a function of the magnetic flux Φ threading the ring defect, while for the latter case, two magnetic-flux-dependent and one magnetic-flux-independent resonant energies are predicted in the system, furthermore, if Φ takes some specific values, one of the Φ-dependent resonant energies may be the same as the Φ-independent resonant energy. The word ``resonant'' is used to describe this situation. When a finite concentration of SMR or STMR defects are randomly embedded in a perfect chain, the numerical results confirm all the analytical predictions. Finally, for the ``resonant'' case, we show numerically a rather wide perfect transmission region which is almost ten times as wide as that of the ``unresonant'' case.
Single-photon transport through an atomic chain coupled to a one-dimensional nanophotonic waveguide
NASA Astrophysics Data System (ADS)
Liao, Zeyang; Zeng, Xiaodong; Zhu, Shi-Yao; Zubairy, M. Suhail
2015-08-01
We study the dynamics of a single-photon pulse traveling through a linear atomic chain coupled to a one-dimensional (1D) single mode photonic waveguide. We derive a time-dependent dynamical theory for this collective many-body system which allows us to study the real time evolution of the photon transport and the atomic excitations. Our analytical result is consistent with previous numerical calculations when there is only one atom. For an atomic chain, the collective interaction between the atoms mediated by the waveguide mode can significantly change the dynamics of the system. The reflectivity of a photon can be tuned by changing the ratio of coupling strength and the photon linewidth or by changing the number of atoms in the chain. The reflectivity of a single-photon pulse with finite bandwidth can even approach 100 % . The spectrum of the reflected and transmitted photon can also be significantly different from the single-atom case. Many interesting physical phenomena can occur in this system such as the photonic band-gap effects, quantum entanglement generation, Fano-like interference, and superradiant effects. For engineering, this system may serve as a single-photon frequency filter, single-photon modulation, and may find important applications in quantum information.
One-dimensional solute transport in stratified sands at short travel distances.
Al-Tabbaa, A; Ayotamuno, J M; Martin, R J
2000-03-13
This paper presents laboratory-scale experimental observations on the migration of a non-reactive pollutant, sodium chloride, through stratified sands at short travel distances under one-dimensional flow conditions. Sand stratifications, perpendicular, parallel and inclined to the main flow direction, were used and contrary to most other published research work, flow was forced through the stratifications at a constant mean pore water velocity. The paper therefore examines the isolated effects of the different dispersion properties and particle size distribution of the sands used on their dispersion behaviour in different stratification configurations under the specified flow conditions. The initial part of the work on homogeneous sands produced differences in the dispersion which was found to be particle size distribution- and volume-dependent. For the stratified configurations and for the same volume of soil, the results showed different dispersion behaviour at the outflow position depending on the type of stratification and the sequence of the sands within each stratification. The paper presented a picture of the effect of various soils and flow conditions imposed on the transport of the solute and provided useful data on the profile of solute concentration for remediation purposes.
Likhachev, Vladimir N; Vinogradov, George A; Astakhova, Tatyana Yu; Yakovenko, Andrey E
2006-01-01
In the present paper we thoroughly investigated the dynamics, kinetics, and the transport properties of the one-dimensional (1D) mass-disordered lattice of harmonic oscillators with the number of particles N < or =5000. The thermostat is simulated by the Langevin sources. Our method is adequate to any 1D lattice with linear equations of motion. Two accurate methods to calculate the temporal behavior of pair correlation functions were developed. The feature of the considered disordered model is an existence of localized states with great relaxation times tau to their stationary states. The exponential growth tau proportional variant exp(N) is observed. A method which allows us to extend the range of computed relaxation times up to tau approximately =(10)300 is suggested. The stationary state is unique. The thermal conduction x has the nonmonotonic character versus N: for the number of particles N < 300 the thermal conduction increases as x proportional variant ln N and reaches the maximal value at N approximately =300. At larger values the decreasing asymptotic is observed: x proportional variant N -alpha, and alpha approximately 0.27. An influence of parameters on the calculated properties was analyzed. Mathematical problems associated with the computation of very large times of establishing the stationary states were extensively studied.
A one-dimensional mixed porohyperelastic transport swelling finite element model with growth
Harper, J.L.; Simon, B.R.; Vande Geest, J.P.
2013-01-01
A one-dimensional, large-strain, mixed porohyperelastic transport and swelling (MPHETS) finite element model was developed in MATLAB and incorporated with a well-known growth model for soft tissues to allow the model to grow (increase in length) or shrink (decrease in length) at constant material density. By using the finite element model to determine the deformation and stress state, it is possible to implement different growth laws in the program in the future to simulate how soft tissues grow and behave when exposed to various stimuli (e.g. mechanical, chemical, or electrical). The essential assumptions needed to use the MPHETS model with growth are clearly identified and explained in this paper. The primary assumption in this work, however, is that the stress upon which growth acts is the stress in the solid skeleton, i.e. the effective stress, Seff. It is shown that significantly different amounts of growth are experienced for the same loading conditions when using a porohyperelastic model as compared to a purely solid model. In one particular example, approximately 51% less total growth occurred in the MPHETS model than in the solid model even though both problems were subjected to the same external loading. This work represents a first step in developing more sophisticated models capable of capturing the complex mechanical and biochemical environment in growing and remodeling tissues. PMID:23778062
Quasi one-dimensional transport in doped polythiophene and polythiophene thin film transistors
NASA Astrophysics Data System (ADS)
Yuen, Jonathan Dsu-Bei
Conducting and semiconducting polymers are important materials in the development of printed, mechanically flexible, large area electronics for various applications, such as flat panel displays and photovoltaic cells. The development of conjugated polymers of high mobility for thin-film transistor active layers, in particular, has been very rapid, starting with early mobilities of around 10-4cm2/Vs to a recent report of 1cm 2/Vs in transistors with an active layer of poly(2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene) (PBTTT). Metallic behavior has a long history in the field of conjugated polymers and recently, even "true" metallic transport has been observed with drho/dT > 0. Thus, development of such high-mobility polymers also raises the possibility that similar behavior will also occur in such materials. A suitable candidate is PBTTT, which is a high performance, rigid-rod conjugated polymer that possesses a thermally-induced liquid crystalline phase where the polymer chains pack into stacked structures, forming two-dimensional layered terraces which extend laterally over hundreds of nanometers, contributing greatly to its high mobility. In this work, the electrical properties of PBTTT are studied under high charge densities both as the active layer in transistors and in electrochemically doped films, in order to determine the mechanism that governs its transport. This thesis will first describe the process of experimental setup and optimization required to produce high performance transistors and doped films; data derived from this is analyzed and correlated to suitable models that may describe charge behavior in these samples. We show that the data obtained using a wide range of parameters (temperature, gate-induced carrier density, source-drain voltage and doping level) scale onto the universal curve predicted for transport in a systems with electronic structure described by the Luttinger Liquid model, a one-dimensional "metallic" system where
NASA Technical Reports Server (NTRS)
Misiakos, K.; Lindholm, F. A.
1986-01-01
Several parameters of certain three-dimensional semiconductor devices including diodes, transistors, and solar cells can be determined without solving the actual boundary-value problem. The recombination current, transit time, and open-circuit voltage of planar diodes are emphasized here. The resulting analytical expressions enable determination of the surface recombination velocity of shallow planar diodes. The method involves introducing corresponding one-dimensional models having the same values of these parameters.
Self-consistent mode-coupling approach to one-dimensional heat transport
NASA Astrophysics Data System (ADS)
Delfini, Luca; Lepri, Stefano; Livi, Roberto; Politi, Antonio
2006-06-01
In the present Rapid Communication we present an analytical and numerical solution of the self-consistent mode-coupling equations for the problem of heat conductivity in one-dimensional systems. Such a solution leads us to propose a different scenario to accommodate the known results obtained so far for this problem. More precisely, we conjecture that the universality class is determined by the leading order of the nonlinear interaction potential. Moreover, our analysis allows us to determine the memory kernel, whose expression puts on a more firm basis the previously conjectured connection between anomalous heat conductivity and anomalous diffusion.
NASA Astrophysics Data System (ADS)
Chen, Yunmin; Xie, Haijian; Ke, Han; Chen, Renpeng
2009-09-01
An analytical solution for one-dimensional contaminant diffusion through multi-layered media is derived regarding the change of the concentration of contaminants at the top boundary with time. The model accounts for the arbitrary initial conditions and the conditions of zero concentration and zero mass flux on the bottom boundary. The average degree of diffusion of the layered system is introduced on the basis of the solution. The results obtained by the presented analytical solutions agree well with those obtained by the numerical methods presented in the literature papers. The application of the analytical solution to the problem of landfill liner design is illustrated by considering a composite liner consisting of geomembrane and compacted clay liner. The results show that the 100-year mass flux of benzene at the bottom of the composite liner is 45 times higher than that of acetone for the same composite liner. The half-life of the contaminant has a great influence on the solute flux of benzene diffused into the underlying aquifer. Results also indicates that an additional 2.9-5.0 m of the conventional (untreated) compacted clay liner under the geomembrane is required to achieve the same level of protection as provided by 0.60 m of the Hexadecyltrimethylammonium (HDTMA)-treated compacted clay liners in conjunction with the geomembrane. Applications of the solution are also presented in the context of a contaminated two-layered media to demonstrate that different boundary and initial conditions can greatly affect the decontamination rate of the problem. The method is relatively simple to apply and can be used for performing equivalency analysis of landfill liners, preliminary design of groundwater remediation system, evaluating experimental results, and verifying more complex numerical models.
Heat and particle transport in a one-dimensional hard-point gas model with on-site potential
Wang, Lei
2015-05-15
Heat and particle transport in a one-dimensional hard-point gas of elastically colliding particles are studied. In the nonequal mass case, due to the presence of on-site potential, the heat conduction of the model obeys the Fourier law and all the transport coefficients asymptotically approach constants in the thermodynamic limit. The thermoelectric figure of merit ZT increases slowly with the system length L and is proportional to the height of the potential barriers H in high H regime. These findings may serve as a guide for future theoretical and experimental studies.
A One-group, One-dimensional Transport Benchmark in Cylindrical Geometry
Barry Ganapol; Abderrafi M. Ougouag
2006-06-01
A 1-D, 1-group computational benchmark in cylndrical geometry is described. This neutron transport benchmark is useful for evaluating reactor concepts that possess azimuthal symmetry such as a pebble-bed reactor.
Electronic transport properties of one dimensional lithium nanowire using density functional theory
Thakur, Anil; Kumar, Arun; Chandel, Surjeet; Ahluwalia, P. K.
2015-05-15
Single nanowire electrode devices are a unique platform for studying as energy storage devices. Lithium nanowire is of much importance in lithium ion batteries and therefore has received a great deal of attention in past few years. In this paper we investigated structural and electronic transport properties of Li nanowire using density functional theory (DFT) with SIESTA code. Electronic transport properties of Li nanowire are investigated theoretically. The calculations are performed in two steps: first an optimized geometry for Li nanowire is obtained using DFT calculations, and then the transport relations are obtained using NEGF approach. SIESTA and TranSIESTA simulation codes are used in the calculations correspondingly. The electrodes are chosen to be the same as the central region where transport is studied, eliminating current quantization effects due to contacts and focusing the electronic transport study to the intrinsic structure of the material. By varying chemical potential in the electrode regions, an I-V curve is traced which is in agreement with the predicted behavior. Agreement of bulk properties of Li with experimental values make the study of electronic and transport properties in lithium nanowires interesting because they are promising candidates as bridging pieces in nanoelectronics. Transmission coefficient and V-I characteristic of Li nano wire indicates that Li nanowire can be used as an electrode device.
Electronic transport properties of one dimensional lithium nanowire using density functional theory
NASA Astrophysics Data System (ADS)
Thakur, Anil; Kumar, Arun; Chandel, Surjeet; Ahluwalia, P. K.
2015-05-01
Single nanowire electrode devices are a unique platform for studying as energy storage devices. Lithium nanowire is of much importance in lithium ion batteries and therefore has received a great deal of attention in past few years. In this paper we investigated structural and electronic transport properties of Li nanowire using density functional theory (DFT) with SIESTA code. Electronic transport properties of Li nanowire are investigated theoretically. The calculations are performed in two steps: first an optimized geometry for Li nanowire is obtained using DFT calculations, and then the transport relations are obtained using NEGF approach. SIESTA and TranSIESTA simulation codes are used in the calculations correspondingly. The electrodes are chosen to be the same as the central region where transport is studied, eliminating current quantization effects due to contacts and focusing the electronic transport study to the intrinsic structure of the material. By varying chemical potential in the electrode regions, an I-V curve is traced which is in agreement with the predicted behavior. Agreement of bulk properties of Li with experimental values make the study of electronic and transport properties in lithium nanowires interesting because they are promising candidates as bridging pieces in nanoelectronics. Transmission coefficient and V-I characteristic of Li nano wire indicates that Li nanowire can be used as an electrode device.
Benchmarking a Visual-Basic based multi-component one-dimensional reactive transport modeling tool
NASA Astrophysics Data System (ADS)
Torlapati, Jagadish; Prabhakar Clement, T.
2013-01-01
We present the details of a comprehensive numerical modeling tool, RT1D, which can be used for simulating biochemical and geochemical reactive transport problems. The code can be run within the standard Microsoft EXCEL Visual Basic platform, and it does not require any additional software tools. The code can be easily adapted by others for simulating different types of laboratory-scale reactive transport experiments. We illustrate the capabilities of the tool by solving five benchmark problems with varying levels of reaction complexity. These literature-derived benchmarks are used to highlight the versatility of the code for solving a variety of practical reactive transport problems. The benchmarks are described in detail to provide a comprehensive database, which can be used by model developers to test other numerical codes. The VBA code presented in the study is a practical tool that can be used by laboratory researchers for analyzing both batch and column datasets within an EXCEL platform.
Analytical solutions for one-dimensional colloid transport in saturated fractures
NASA Astrophysics Data System (ADS)
Abdel-Salam, Assem; Chrysikopoulos, Constantinos V.
Closed-form analytical solutions for colloid transport in single rock fractures with and without colloid penetration into the rock matrix are derived for constant concentration as well as constant flux boundary conditions. A single fracture is idealized as two semi-infinite parallel plates. It is assumed that colloidal particles undergo irreversible deposition onto fracture surfaces and may penetrate into the rock matrix, and deposit irreversibly onto rock matrix solid surfaces. The solutions are obtained by taking Laplace transforms to the governing transport equations and boundary conditions with respect to time and space. For the case of no colloid penetration into the rock matrix, the solutions are expressed in terms of exponentials and complimentary error functions; whereas, for the case of colloid penetration into the rock matrix, the solutions are expressed in terms of convolution integrals and modified Bessel functions. The impact of the model parameters on colloid transport is examined. The results from several simulations indicate that liquid-phase as well as deposited colloid concentrations in the fracture are sensitive to the fracture surface deposition coefficient, the fracture aperture, and the Brownian diffusion coefficient for colloidal particles penetrating the rock matrix. Furthermore, it is shown that the differences between the two boundary conditions investigated are minimized at dominant advective transport conditions. The constant concentration condition overestimates liquid-phase colloid concentrations, whereas the constant flux condition leads to conservation of mass.
One dimensional heavy ion beam transport: Energy independent model. M.S. Thesis
NASA Technical Reports Server (NTRS)
Farhat, Hamidullah
1990-01-01
Attempts are made to model the transport problem for heavy ion beams in various targets, employing the current level of understanding of the physics of high-charge and energy (HZE) particle interaction with matter are made. An energy independent transport model, with the most simplified assumptions and proper parameters is presented. The first and essential assumption in this case (energy independent transport) is the high energy characterization of the incident beam. The energy independent equation is solved and application is made to high energy neon (NE-20) and iron (FE-56) beams in water. The numerical solutions is given and compared to a numerical solution to determine the accuracy of the model. The lower limit energy for neon and iron to be high energy beams is calculated due to Barkas and Burger theory by LBLFRG computer program. The calculated values in the density range of interest (50 g/sq cm) of water are: 833.43 MeV/nuc for neon and 1597.68 MeV/nuc for iron. The analytical solutions of the energy independent transport equation gives the flux of different collision terms. The fluxes of individual collision terms are given and the total fluxes are shown in graphs relative to different thicknesses of water. The values for fluxes are calculated by the ANASTP computer code.
NASA Astrophysics Data System (ADS)
Soldano, Caterina
The investigation of the electronic and magnetotransport properties at low temperature in individual MWNT with embedded clusters are here presented. The majority of studies of transport in MWNT reported in literature has been carried out on arc-discharge grown tubes, generally considered "clean" and defect-free. In this project, individual MWNT grown in alumina template are used; these tubes are highly disordered compared for example to arc-discharge ones, conditions that dramatically will impact the charge transport. As-fabricated devices are in general highly resistive. A large decrease in the value of the device resistance can be achieved through a controlled and fast high-bias sweep method (HBT) across the sample. Scanning electron microscopy analysis shows that this method induces a metal (platinum) decoration of the MWNT surface as a consequence of the large amount of Joule heating developed during the sweep. Temperature dependence study (5
Wang, Ru; Wang, Zhuo; Leigh, Joe; Sobh, Nahil; Millet, Larry; Gillette, Martha U.; Levine, Alex J.; Popescu, Gabriel
2011-01-01
We studied the active transport of intracellular components along neuron processes with a new method developed in our laboratory, dispersion-relation phase spectroscopy. This method is able to quantitatively map spatially the heterogeneous dynamics of the concentration field of the cargos at submicron resolution without the need for tracking individual components. The results in terms of density correlation function reveal that the decay rate is linear in wavenumber, which is consistent with a narrow Lorentzian distribution of cargo velocity. PMID:21862838
NASA Astrophysics Data System (ADS)
Kosevich, Yuriy A.; Savin, Alexander V.
2016-10-01
We provide molecular dynamics simulation of heat transport and energy diffusion in one-dimensional molecular chains with different interparticle pair potentials at zero and non-zero temperature. We model the thermal conductivity (TC) and energy diffusion (ED) in the chain of coupled rotators and in the Lennard-Jones chain either without or with the confining parabolic interparticle potential. The considered chains without the confining potential have normal TC and ED at non-zero temperature, while the corresponding chains with the confining potential are characterized by anomalous (diverging with the system length) TC and superdiffusion of energy. Similar effect is produced by the anharmonic quartic confining pair potential. We confirm in such a way that, surprisingly, the confining pair potential makes both heat transport and energy diffusion anomalous in one-dimensional phononic systems. We show that the normal TC is always accompanied by the normal ED in the thermalized anharmonic chains, while the superdiffusion of energy occurs in the thermalized chains with only anomalous heat transport.
Revealing origin of quasi-one dimensional current transport in defect rich two dimensional materials
Lotz, Mikkel R.; Boll, Mads; Bøggild, Peter; Petersen, Dirch H.; Hansen, Ole; Kjær, Daniel
2014-08-04
The presence of defects in graphene have for a long time been recognized as a bottleneck for its utilization in electronic and mechanical devices. We recently showed that micro four-point probes may be used to evaluate if a graphene film is truly 2D or if defects in proximity of the probe will lead to a non-uniform current flow characteristic of lower dimensionality. In this work, simulations based on a finite element method together with a Monte Carlo approach are used to establish the transition from 2D to quasi-1D current transport, when applying a micro four-point probe to measure on 2D conductors with an increasing amount of line-shaped defects. Clear 2D and 1D signatures are observed at low and high defect densities, respectively, and current density plots reveal the presence of current channels or branches in defect configurations yielding 1D current transport. A strong correlation is found between the density filling factor and the simulation yield, the fraction of cases with 1D transport and the mean sheet conductance. The upper transition limit is shown to agree with the percolation threshold for sticks. Finally, the conductance of a square sample evaluated with macroscopic edge contacts is compared to the micro four-point probe conductance measurements and we find that the micro four-point probe tends to measure a slightly higher conductance in samples containing defects.
O'Dell, R.D.; Brinkley, F.W. Jr.; Marr, D.R.
1982-02-01
ONEDANT is designed for the CDC-7600, but the program has been implemented and run on the IBM-370/190 and CRAY-I computers. ONEDANT solves the one-dimensional multigroup transport equation in plane, cylindrical, spherical, and two-angle plane geometries. Both regular and adjoint, inhomogeneous and homogeneous (k/sub eff/ and eigenvalue search) problems subject to vacuum, reflective, periodic, white, albedo, or inhomogeneous boundary flux conditions are solved. General anisotropic scattering is allowed and anisotropic inhomogeneous sources are permitted. ONEDANT numerically solves the one-dimensional, multigroup form of the neutral-particle, steady-state form of the Boltzmann transport equation. The discrete-ordinates approximation is used for treating the angular variation of the particle distribution and the diamond-difference scheme is used for phase space discretization. Negative fluxes are eliminated by a local set-to-zero-and-correct algorithm. A standard inner (within-group) iteration, outer (energy-group-dependent source) iteration technique is used. Both inner and outer iterations are accelerated using the diffusion synthetic acceleration method. (WHK)
Quantum ballistic transport by interacting two-electron states in quasi-one-dimensional channels
Huang, Danhong; Gumbs, Godfrey; Abranyos, Yonatan; Pepper, Michael; Kumar, Sanjeev
2015-11-15
For quantum ballistic transport of electrons through a short conduction channel, the role of Coulomb interaction may significantly modify the energy levels of two-electron states at low temperatures as the channel becomes wide. In this regime, the Coulomb effect on the two-electron states is calculated and found to lead to four split energy levels, including two anticrossing-level and two crossing-level states. Moreover, due to the interplay of anticrossing and crossing effects, our calculations reveal that the ground two-electron state will switch from one anticrossing state (strong confinement) to a crossing state (intermediate confinement) as the channel width gradually increases and then back to the original anticrossing state (weak confinement) as the channel width becomes larger than a threshold value. This switching behavior leaves a footprint in the ballistic conductance as well as in the diffusion thermoelectric power of electrons. Such a switching is related to the triple spin degeneracy as well as to the Coulomb repulsion in the central region of the channel, which separates two electrons away and pushes them to different channel edges. The conductance reoccurrence region expands from the weak to the intermediate confinement regime with increasing electron density.
Kavitha, L; Priya, R; Ayyappan, N; Gopi, D; Jayanthi, S
2016-01-01
The dynamics of protons in a one-dimensional hydrogen-bonded (HB) polypeptide chain (PC) is investigated theoretically. A new Hamiltonian is formulated with the inclusion of higher-order molecular interactions between peptide groups (PGs). The wave function of the excitation state of a single particle is replaced by a new wave function of a two-quanta quasi-coherent state. The dynamics is governed by a higher-order nonlinear Schrödinger equation and the energy transport is performed by the proton soliton. A nonlinear multiple-scale perturbation analysis has been performed and the evolution of soliton parameters such as velocity and amplitude is explored numerically. The proton soliton is thermally stable and very robust against these perturbations. The energy transport by the proton soliton is more appropriate to understand the mechanism of energy transfer in biological processes such as muscle contraction, DNA replication, and neuro-electric pulse transfer on biomembranes.
Length-dependent thermal transport in one-dimensional self-assembly of planar π-conjugated molecules
NASA Astrophysics Data System (ADS)
Tang, Hao; Xiong, Yucheng; Zu, Fengshuo; Zhao, Yang; Wang, Xiaomeng; Fu, Qiang; Jie, Jiansheng; Yang, Juekuan; Xu, Dongyan
2016-06-01
This work reports a thermal transport study in quasi-one-dimensional organic nanostructures self-assembled from conjugated planar molecules via π-π interactions. Thermal resistances of single crystalline copper phthalocyanine (CuPc) and perylenetetracarboxylic diimide (PTCDI) nanoribbons are measured via a suspended thermal bridge method. We experimentally observed the deviation from the linear length dependence for the thermal resistance of single crystalline β-phase CuPc nanoribbons, indicating possible subdiffusion thermal transport. Interestingly, a gradual transition to the linear length dependence is observed with the increase of the lateral dimensions of CuPc nanoribbons. The measured thermal resistance of single crystalline CuPc nanoribbons shows an increasing trend with temperature. However, the trend of temperature dependence of thermal resistance is reversed after electron irradiation, i.e., decreasing with temperature, indicating that the single crystalline CuPc nanoribbons become `amorphous'. Similar behavior is also observed for PTCDI nanoribbons after electron irradiation, proving that the electron beam can induce amorphization of single crystalline self-assembled nanostructures of planar π-conjugated molecules. The measured thermal resistance of the `amorphous' CuPc nanoribbon demonstrates a roughly linear dependence on the nanoribbon length, suggesting that normal diffusion dominates thermal transport.This work reports a thermal transport study in quasi-one-dimensional organic nanostructures self-assembled from conjugated planar molecules via π-π interactions. Thermal resistances of single crystalline copper phthalocyanine (CuPc) and perylenetetracarboxylic diimide (PTCDI) nanoribbons are measured via a suspended thermal bridge method. We experimentally observed the deviation from the linear length dependence for the thermal resistance of single crystalline β-phase CuPc nanoribbons, indicating possible subdiffusion thermal transport
User's Guide for Mixed-Size Sediment Transport Model for Networks of One-Dimensional Open Channels
Bennett, James P.
2001-01-01
This user's guide describes a mathematical model for predicting the transport of mixed sizes of sediment by flow in networks of one-dimensional open channels. The simulation package is useful for general sediment routing problems, prediction of erosion and deposition following dam removal, and scour in channels at road embankment crossings or other artificial structures. The model treats input hydrographs as stepwise steady-state, and the flow computation algorithm automatically switches between sub- and supercritical flow as dictated by channel geometry and discharge. A variety of boundary conditions including weirs and rating curves may be applied both external and internal to the flow network. The model may be used to compute flow around islands and through multiple openings in embankments, but the network must be 'simple' in the sense that the flow directions in all channels can be specified before simulation commences. The location and shape of channel banks are user specified, and all bedelevation changes take place between these banks and above a user-specified bedrock elevation. Computation of sediment-transport emphasizes the sand-size range (0.0625-2.0 millimeter) but the user may select any desired range of particle diameters including silt and finer (<0.0625 millimeter). As part of data input, the user may set the original bed-sediment composition of any number of layers of known thickness. The model computes the time evolution of total transport and the size composition of bed- and suspended-load sand through any cross section of interest. It also tracks bed -surface elevation and size composition. The model is written in the FORTRAN programming language for implementation on personal computers using the WINDOWS operating system and, along with certain graphical output display capability, is accessed from a graphical user interface (GUI). The GUI provides a framework for selecting input files and parameters of a number of components of the sediment-transport
NASA Astrophysics Data System (ADS)
Okamoto, Kentaro; Tanaka, Toshiyuki; Fujita, Wataru; Awaga, Kunio; Inabe, Tamotsu
2007-08-01
We here examine the electrical and magnetic properties of the isostructural NT3•MCl4 ( NT=naphtho [2,1- d :6,5- d' ]bis([1,2,3] dithiazole and M=Ga and Fe). The crystal structure of NT3•MCl4 consists of one-dimensional π -stacking chains of NT with strong interchain interactions caused by electrostatic Sδ+•••Nδ- contacts. This structure includes four NT molecules with significant differences in molecular structure and charge, exhibiting a characteristic charge ordering, namely, three-dimensional alternation of charge-rich (or -intermediate) and -poor molecules. NT3•GaCl4 and NT3•FeCl4 are found to be semiconductors with σRT˜0.5Scm-1 and to exhibit a nonlinear electrical transport at room temperature with a very low threshold field of 80Vcm-1 for the negative differential resistance. This threshold field significantly increases with a decrease in temperature. The X -band electron paramagnetic resonance (EPR) spectra of NT3•GaCl4 consist of a single-line absorption ascribable to that of the NT+ cation. When the sample is exposed to a current at room temperature, this signal exhibits a drastic decrease in intensity with little change in linewidth. This is attributed to the inhomogeneous formation of EPR-silent conducting pathways for the nonlinear transport. The temperature dependence of the EPR spin susceptibility χs of NT3•GaCl4 suggests a transition toward a spin-gap state below 20K ; χs exhibits a Bonner-Fisher-type temperature dependence above 20K , but gradually collapses to zero below this temperature.
Runkel, Robert L.
1998-01-01
OTIS is a mathematical simulation model used to characterize the fate and transport of water-borne solutes in streams and rivers. The governing equation underlying the model is the advection-dispersion equation with additional terms to account for transient storage, lateral inflow, first-order decay, and sorption. This equation and the associated equations describing transient storage and sorption are solved using a Crank-Nicolson finite-difference solution. OTIS may be used in conjunction with data from field-scale tracer experiments to quantify the hydrologic parameters affecting solute transport. This application typically involves a trial-and-error approach wherein parameter estimates are adjusted to obtain an acceptable match between simulated and observed tracer concentrations. Additional applications include analyses of nonconservative solutes that are subject to sorption processes or first-order decay. OTIS-P, a modified version of OTIS, couples the solution of the governing equation with a nonlinear regression package. OTIS-P determines an optimal set of parameter estimates that minimize the squared differences between the simulated and observed concentrations, thereby automating the parameter estimation process. This report details the development and application of OTIS and OTIS-P. Sections of the report describe model theory, input/output specifications, sample applications, and installation instructions.
This technical report describes the new one-dimensional (1D) hydrodynamic and sediment transport model EFDC1D. This model that can be applied to stream networks. The model code and two sample data sets are included on the distribution CD. EFDC1D can simulate bi-directional unstea...
Technology Transfer Automated Retrieval System (TEKTRAN)
Analytical solutions of the advection-dispersion solute transport equation remain useful for a large number of applications in science and engineering. In this paper we extend the Duhamel theorem, originally established for diffusion type problems, to the case of advective-dispersive transport subj...
Ncube, Siphephile; Chimowa, George; Chiguvare, Zivayi; Bhattacharyya, Somnath
2014-07-14
The superiority of the electronic transport properties of single-walled carbon nanotube (SWNT) ropes over SWNT mats is verified from low temperature and frequency-dependent transport. The overall change of resistance versus in nanotube mats shows that 3D variable range hopping is the dominant conduction mechanism within the 2–300 K range. The magneto-resistance (MR) is found to be predominantly negative with a parabolic nature, which can also be described by the hopping model. Although the positive upturn of the MR at low temperatures establishes the contribution from quantum interference, the inherent quantum transport in individual tubes is suppressed at elevated temperatures. Therefore, to minimize multi-channel effects from inter-tube interactions and other defects, two-terminal devices were fabricated from aligned SWNT (extracted from a mat) for low temperature transport as well as high-frequency measurements. In contrast to the mat, the aligned ropes exhibit step-like features in the differential conductance within the 80–300 K temperature range. The effects of plasmon propagation, unique to one dimension, were identified in electronic transport as a non-universal power-law dependence of the differential conductance on temperature and source-drain voltage. The complex impedance showed high power transmission capabilities up to 65 GHz as well as oscillations in the frequency range up to 30 GHz. The measurements suggest that aligned SWNT ropes have a realistic potential for high-speed device applications.
NASA Astrophysics Data System (ADS)
Ncube, Siphephile; Chimowa, George; Chiguvare, Zivayi; Bhattacharyya, Somnath
2014-07-01
The superiority of the electronic transport properties of single-walled carbon nanotube (SWNT) ropes over SWNT mats is verified from low temperature and frequency-dependent transport. The overall change of resistance versus in nanotube mats shows that 3D variable range hopping is the dominant conduction mechanism within the 2-300 K range. The magneto-resistance (MR) is found to be predominantly negative with a parabolic nature, which can also be described by the hopping model. Although the positive upturn of the MR at low temperatures establishes the contribution from quantum interference, the inherent quantum transport in individual tubes is suppressed at elevated temperatures. Therefore, to minimize multi-channel effects from inter-tube interactions and other defects, two-terminal devices were fabricated from aligned SWNT (extracted from a mat) for low temperature transport as well as high-frequency measurements. In contrast to the mat, the aligned ropes exhibit step-like features in the differential conductance within the 80-300 K temperature range. The effects of plasmon propagation, unique to one dimension, were identified in electronic transport as a non-universal power-law dependence of the differential conductance on temperature and source-drain voltage. The complex impedance showed high power transmission capabilities up to 65 GHz as well as oscillations in the frequency range up to 30 GHz. The measurements suggest that aligned SWNT ropes have a realistic potential for high-speed device applications.
Dupree, S. A.
1980-06-01
The use of adjoint techniques to determine the interaction of externally incident collimated beams of particles with cylindrical targets is a convenient means of examining a class of problems important in radiation transport studies. The theory relevant to such applications is derived, and a simple example involving a fissioning target is discussed. Results from both discrete ordinates and Monte Carlo transport-code calculations are presented, and comparisons are made with results obtained from forward calculations. The accuracy of the discrete ordinates adjoint results depends on the order of angular quadrature used in the calculation. Reasonable accuracy by using EQN quadratures can be expected from order S/sub 16/ or higher.
NASA Astrophysics Data System (ADS)
Mieles, J. M.; Zhan, H.
2010-12-01
Permeable reactive barriers (PRBs) have been accepted by the EPA as an effective groundwater remediation technology. Effective implementation of this in-situ technology requires accurate site characterization to identify the chemicals of concern (COCs) present, their interactions (if any), and their required residence time in the PRB to achieve regulatory concentrations at the point of compliance (POC). Therefore, minimizing performance uncertainties in the design phase is key. Among these uncertainties determining the required PRB thickness is the most important and has been examined in other studies. Less attention, however, has been devoted to developing a practical yet rigorous tool for modeling multi-species reactive transport in the barrier-aquifer system. In this study Park and Zhan’s [2009] mass conservative semi-analytical solution - developed to calculate the required PRB thickness based on the decay of one species - is expanded to four reactive species. For example, the expanded solution could be used to model the degradation pathway from tetrachloroethylene (PCE) to vinyl chloride (VC). The solution is presented in two forms: The steady-state solution programmed into Excel can quickly assist designers in determining the required PRB thickness so that all COCs involved in the degradation pathway achieve regulatory limits at the POC. The second form is the transient solution which is solved by numerically inverting the Laplace transform. The semi-analytical solution presented in this study has several advantages over prior solutions. For example, the influent and effluent boundary conditions of the PRB are mass conservative and both dispersion and decay rate differences between the PRB and aquifer are considered. In addition, the transient solution allows for different retardation factors to be considered in both transport media and for each species.
Kerstein, A.R.
1996-12-31
One-Dimensional Turbulence is a new turbulence modeling strategy involving an unsteady simulation implemented in one spatial dimension. In one dimension, fine scale viscous and molecular-diffusive processes can be resolved affordably in simulations at high turbulence intensity. The mechanistic distinction between advective and molecular processes is thereby preserved, in contrast to turbulence models presently employed. A stochastic process consisting of mapping {open_quote}events{close_quote} applied to a one-dimensional velocity profile represents turbulent advection. The local event rate for given eddy size is proportional to the velocity difference across the eddy. These properties cause an imposed shear to induce an eddy cascade analogous in many respects to the eddy cascade in turbulent flow. Many scaling and fluctuation properties of self-preserving flows, and of passive scalars introduced into these flows, are reproduced.
Gureghian, A.B.
1990-08-01
Analytical solutions based on the Laplace transforms are presented for the one-dimensional, transient, advective-dispersive transport of a reacting radionuclide through a discrete planar fracture with constant aperture subject to diffusion in the surrounding rock matrix where both regions of solute migration display residual concentrations. The dispersion-free solutions, which are of closed form, are also reported. The solution assumes that the ground-water flow regime is under steady-state and isothermal conditions and that the rock matrix is homogeneous, isotropic, and saturated with stagnant water. The verification of the solution was performed by means of related analytical solutions dealing with particular aspects of the transport problem under investigation on the one hand, and a numerical solution capable of handling the complete problem on the other. The integrals encountered in the general solution are evaluated by means of a composite Gauss-Legendre quadrature scheme. 9 refs., 8 figs., 32 tabs.
Qian, Zekan; Li, Rui; Hou, Shimin; Xue, Zengquan; Sanvito, Stefano
2007-11-21
An efficient self-consistent approach combining the nonequilibrium Green's function formalism with density functional theory is developed to calculate electron transport properties of molecular devices with quasi-one-dimensional (1D) electrodes. Two problems associated with the low dimensionality of the 1D electrodes, i.e., the nonequilibrium state and the uncertain boundary conditions for the electrostatic potential, are circumvented by introducing the reflectionless boundary conditions at the electrode-contact interfaces and the zero electric field boundary conditions at the electrode-molecule interfaces. Three prototypical systems, respectively, an ideal ballistic conductor, a high resistance tunnel junction, and a molecular device, are investigated to illustrate the accuracy and efficiency of our approach.
NASA Technical Reports Server (NTRS)
Ghorai, S. K.
1983-01-01
The purpose of this project was to use a one-dimensional discrete coordinates transport code called ANISN in order to determine the energy-angle-spatial distribution of neutrons in a 6-feet cube rock box which houses a D-T neutron generator at its center. The project was two-fold. The first phase of the project involved adaptation of the ANISN code written for an IBM 360/75/91 computer to the UNIVAC system at JSC. The second phase of the project was to use the code with proper geometry, source function and rock material composition in order to determine the neutron flux distribution around the rock box when a 14.1 MeV neutron generator placed at its center is activated.
NASA Astrophysics Data System (ADS)
Katzourakis, Vasileios; Chrysikopoulos, Constantinos
2016-04-01
The present work re-introduces ColloidFit, which is an autonomous, modular, multipurpose fitting software for dense colloid and biocolloid transport phenomena in porous media. The initial version of ColloidFit, introduced by Sim and Chrysikopoulos (1995), was substantially improved and combined with a relatively intuitive and easy to use graphical user interface. The re-introduced ColloidFit can simulate the migration of suspended colloid or biocolloid particles in one-dimensional, water saturated, homogeneous porous media with uniform flow, accounting for non-equilibrium attachment onto the solid matrix, as well as gravitational effects. Furthermore, the improved ColloidFit software employs a variety of non-equilibrium, linear and nonlinear models for the simulation of colloid attachment onto a solid matrix under batch experimental conditions. The re-introduced ColloidFit uses the state of the art fitting software "Pest" to estimate unknown model parameter values, together with their 95% confidence intervals. Pest is a model-independent parameter estimation software capable of adjusting model parameters, so that discrepancies between model-generated data and the corresponding experimental measurements are reduced to a user preselected minimum. The fitting process is graphed and displayed in real time. The user is allowed to overview every step of the fitting progress, and if needed to change the initial parameter values. The re-introduced ColloidFit software is expected to make the fitting process of colloid and biocolloid transport data, just a simple task.
NASA Astrophysics Data System (ADS)
Suzuki, Yohichi; Singh, Rupashree Balia; Matsuzaki, Hiroyuki; Furube, Akihiro; Ma, Guijun; Hisatomi, Takashi; Domen, Kazunari; Seki, Kazuhiko
2016-09-01
The semiconductor La5Ti2CuS5O7 (LTC) is a potential photocatalyst capable of operating under visible light irradiation and behaves both as a photocathode and anode when embedded onto metal layers. Time-resolved diffuse reflectance (TRDR) measurements were carried out on LTC powder and LTC deposited on Au as the back contact using the particle-transfer method. Results of TRDR measurements of powdered LTC indicated the existence of long-lived photo-excited carriers, and suggested the existence of a mechanism for preventing carrier loss in LTC. Prior research has reported that LTC has a rod-shaped crystal structure and that electrons and holes are transported through different, spatially separated channels. Based on this, we introduced a one-dimensional carrier transport model. By analyzing TRDR data, we extracted material parameters such as the diffusion coefficient of LTC. Theoretical results indicated that a micron-sized LTC particle would be preferable if carriers trapped at the top-surface do contribute to photocatalytic gas generation.
Parkhurst, David L.; Appelo, C.A.J.
1999-01-01
PHREEQC version 2 is a computer program written in the C programming language that is designed to perform a wide variety of low-temperature aqueous geochemical calculations. PHREEQC is based on an ion-association aqueous model and has capabilities for (1) speciation and saturation-index calculations; (2) batch-reaction and one-dimensional (1D) transport calculations involving reversible reactions, which include aqueous, mineral, gas, solid-solution, surface-complexation, and ion-exchange equilibria, and irreversible reactions, which include specified mole transfers of reactants, kinetically controlled reactions, mixing of solutions, and temperature changes; and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for differences in composition between waters, within specified compositional uncertainty limits.New features in PHREEQC version 2 relative to version 1 include capabilities to simulate dispersion (or diffusion) and stagnant zones in 1D-transport calculations, to model kinetic reactions with user-defined rate expressions, to model the formation or dissolution of ideal, multicomponent or nonideal, binary solid solutions, to model fixed-volume gas phases in addition to fixed-pressure gas phases, to allow the number of surface or exchange sites to vary with the dissolution or precipitation of minerals or kinetic reactants, to include isotope mole balances in inverse modeling calculations, to automatically use multiple sets of convergence parameters, to print user-defined quantities to the primary output file and (or) to a file suitable for importation into a spreadsheet, and to define solution compositions in a format more compatible with spreadsheet programs. This report presents the equations that are the basis for chemical equilibrium, kinetic, transport, and inverse-modeling calculations in PHREEQC; describes the input for the program; and presents examples that demonstrate most of the program's capabilities.
NASA Astrophysics Data System (ADS)
Hemme, C.; van Berk, W.
2015-12-01
In carbon capture and storage (CCS) systems supercritical CO2 is injected into a reservoir and dissolves in the reservoir brine. Subsequently, CO2(aq) diffuses into the cap rock to regions of lower total pressure and temperature and triggers CO2-water-rock interactions that are coupled with mass transport and result in precipitation and/or dissolution of minerals along the CO2 migration path. Such hydrogeochemical interactions change porosities and are responsible for the improvement or deterioration of the long term integrity of the system. This study presents a semi-generic hydrogeochemical model based on chemical equilibrium thermodynamics, data from several CO2 storage systems, and plausible assumptions regarding non-available data. One-dimensional reactive transport modeling is performed by using the U.S.G.S. PHREEQC code (3.1.4-8929; phreeqc.dat database) to identify and quantify the loss or gain of total porosity affected by hydrogeochemical reactions driven by diffusive mass transport exposed to pressure and temperature gradients. A fine spatial and temporal discretization, the use of non-reactive tracers, and a broad variety of modeling scenarios enable the calculation of the relevant timescale for simulations of long-term storage of CO2 and the consideration of the pressure dependent mass action law constants along the CO2 migration path. Modeling results show that the relevant timescale for simulations of long-term storage of CO2 is in the range of 106 years, and that pressure/temperature conditions, heterogeneities (veins and fractures) and the mineralogical composition of the cap rock have the strongest influence on the increase in cap rock porosity (maximum increase from initial 5 % to 7.5 %). Critical parameter combinations - total pressure effects are crucial - could put long-term integrity at risks. Nevertheless, a wide range of conditions and parameter combinations for safe CO2 storage is identified by other modeling scenarios.
One-Dimensionality and Whiteness
ERIC Educational Resources Information Center
Calderon, Dolores
2006-01-01
This article is a theoretical discussion that links Marcuse's concept of one-dimensional society and the Great Refusal with critical race theory in order to achieve a more robust interrogation of whiteness. The author argues that in the context of the United States, the one-dimensionality that Marcuse condemns in "One-Dimensional Man" is best…
Mass transport contamination study
NASA Technical Reports Server (NTRS)
Robertson, S. J.
1972-01-01
A theoretical analysis was performed to determine the effects of outgassing and waste dumping on the contamination field around an orbiting spacecraft. The spacecraft was assumed to be spherical in shape with the mass flow emitting uniformly from the spherical surface at a constant rate and in a D'Lambertian spatial distribution. The outflow of gases were assumed to be neutrally charged and of a single species with a molecular weight characteristic of a composite of the actual species involved in the mass flow. The theoretical analysis showed that, for outgassing only, less than 1.5 percent of the outgas products will return to the Skylab spacecraft as a result of intermolecular collisions. When the total mass flow from the spacecraft, including waste dumps and reaction control motor firings, was considered, it was estimated that about 30 percent will return to the spacecraft.
de Vries, M. Peter; Weiss, Lawrence A.
2001-01-01
The Hudson River is being considered for use as a supplemental source of water supply for New York City during droughts. One proposal entails withdrawal of Hudson River water from locations near Newburgh, Chelsea, or Kingston, but the extent to which this could cause the salt front to advance upstream to points where it could adversely affect community water supplies is unknown. The U.S. Geological Survey (USGS) one-dimensional Branch-Network Dynamic Flow model (BRANCH) was used in conjunction with the USGS one-dimensional Branched Lagrangian Solute-Transport Model (BLTM) to simulate the effect of five water-withdrawal scenarios on the salt-front location.The modeled reach contains 132 miles of the lower Hudson River between the Federal Dam at Troy and Hastings-on-Hudson (near New York City). The BRANCH model was calibrated and verified to 19 tidal-cycle discharge measurements made at 11 locations by conventional and acoustic Doppler current-profiler methods. Maximum measured instantaneous tidal flow ranged from 20,000 ft3/s (cubic feet per second) at Albany to 368,000 ft3/s at Tellers Point; daily-mean flow at Green Island near Troy ranged from 3,030 ft3/s to 45,000 ft3/s during the flow measurements. Successive ebb- and flood-flow volumes were measured and compared with computed volumes; daily-mean bias was -1.6 percent (range from -21.0 to +23.7 percent; 13.5 percent mean absolute error). Daily-mean deviation between simulated and measured stage at eight locations (from Bowline Point to Albany) over the 19 tidal-cycle measurements averaged +0.06 ft (range from -0.31 to +0.40 ft; 0.21 ft root mean square error, RMSE). These results indicate that the model can accurately simulate flow in the Hudson River under a wide range of flow, tide, and meteorological conditions.The BLTM was used to simulate chloride transport in the 61-mi reach from Turkey Point to Bowline Point under two seasonal conditions in 1990.one representing spring conditions of high inflow and low
de Vries, M. Peter; Weiss, L.A.
2001-01-01
The Hudson River is being considered for use as a supplemental source of water supply for New York City during droughts. One proposal entails withdrawal of Hudson River water from locations near Newburgh, Chelsea, or Kingston, but the extent to which this could cause the salt front to advance upstream to points where it could adversely affect community water supplies is unknown. The U.S. Geological Survey (USGS) one-dimensional Branch-Network Dynamic Flow model (BRANCH) was used in conjunction with the USGS one-dimensional Branched Lagrangian Solute-Transport Model (BLTM) to simulate the effect of five water-withdrawal scenarios on the salt-front location. The modeled reach contains 132 miles of the lower Hudson River between the Federal Dam at Troy and Hastings-on-Hudson (near New York City). The BRANCH model was calibrated and verified to 19 tidal-cycle discharge measurements made at 11 locations by conventional and acoustic Doppler current-profiler methods. Maximum measured instantaneous tidal flow ranged from 20,000 ft3/s (cubic feet per second) at Albany to 368,000 ft3/s at Tellers Point; daily-mean flow at Green Island near Troy ranged from 3,030 ft3/s to 45,000 ft3/s during the flow measurements. Successive ebb- and flood-flow volumes were measured and compared with computed volumes; daily-mean bias was -1.6 percent (range from -21.0 to +23.7 percent; 13.5 percent mean absolute error). Daily-mean deviation between simulated and measured stage at eight locations (from Bowline Point to Albany) over the 19 tidal-cycle measurements averaged +0.06 ft (range from -0.31 to +0.40 ft; 0.21 ft root mean square error, RMSE). These results indicate that the model can accurately simulate flow in the Hudson River under a wide range of flow, tide, and meteorological conditions. The BLTM was used to simulate chloride transport in the 61-mi reach from Turkey Point to Bowline Point under two seasonal conditions in 1990.one representing spring conditions of high inflow and low
NASA Astrophysics Data System (ADS)
Dewaide, Lorraine; Bonniver, Isabelle; Rochez, Gaëtan; Hallet, Vincent
2016-03-01
This paper presents the modelling results of several tracer-tests performed in the cave system of Han-sur-Lesse (South Belgium). In Han-sur-Lesse, solute flows along accessible underground river stretches and through flooded areas that are rather unknown in terms of geometry. This paper focus on the impact of those flooded areas on solute transport and their dimensioning. The program used (One-dimensional Transport with Inflow and Storage: OTIS) is based on the two-region non equilibrium model that supposes the existence of an immobile water zone along the main flow zone in which solute can be caught. The simulations aim to replicate experimental breakthrough curves (BTCs) by adapting the main transport and geometric parameters that govern solute transport in karst conduits. Furthermore, OTIS allows a discretization of the investigated system, which is particularly interesting in systems presenting heterogeneous geometries. Simulation results show that transient storage is a major process in flooded areas and that the crossing of these has a major effect on the BTCs shape. This influence is however rather complex and very dependent of the flooded areas geometry and transport parameters. Sensibility tests performed in this paper aim to validate the model and show the impact of the parametrization on the BTCs shape. Those tests demonstrate that transient storage is not necessarily transformed in retardation. Indeed, significant tailing effect is only observed in specific conditions (depending on the system geometry and/or the flow) that allow residence time in the storage area to be longer than restitution time. This study ends with a comparison of solute transport in river stretches and in flooded areas.
Parkhurst, David L.; Appelo, C.A.J.
2013-01-01
PHREEQC version 3 is a computer program written in the C and C++ programming languages that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC implements several types of aqueous models: two ion-association aqueous models (the Lawrence Livermore National Laboratory model and WATEQ4F), a Pitzer specific-ion-interaction aqueous model, and the SIT (Specific ion Interaction Theory) aqueous model. Using any of these aqueous models, PHREEQC has capabilities for (1) speciation and saturation-index calculations; (2) batch-reaction and one-dimensional (1D) transport calculations with reversible and irreversible reactions, which include aqueous, mineral, gas, solid-solution, surface-complexation, and ion-exchange equilibria, and specified mole transfers of reactants, kinetically controlled reactions, mixing of solutions, and pressure and temperature changes; and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for differences in composition between waters within specified compositional uncertainty limits. Many new modeling features were added to PHREEQC version 3 relative to version 2. The Pitzer aqueous model (pitzer.dat database, with keyword PITZER) can be used for high-salinity waters that are beyond the range of application for the Debye-Hückel theory. The Peng-Robinson equation of state has been implemented for calculating the solubility of gases at high pressure. Specific volumes of aqueous species are calculated as a function of the dielectric properties of water and the ionic strength of the solution, which allows calculation of pressure effects on chemical reactions and the density of a solution. The specific conductance and the density of a solution are calculated and printed in the output file. In addition to Runge-Kutta integration, a stiff ordinary differential equation solver (CVODE) has been included for kinetic calculations with multiple rates that occur at widely different time scales
Contaminant transport in Massachusetts Bay
Butman, Bradford
Construction of a new treatment plant and outfall to clean up Boston Harbor is currently one of the world's largest public works projects, costing about $4 billion. There is concern about the long-term impact of contaminants on Massachusetts Bay and adjacent Gulf of Maine because these areas are used extensively for transportation, recreation, fishing, and tourism, as well as waste disposal. Public concern also focuses on Stellwagen Bank, located on the eastern side of Massachusetts Bay, which is an important habitat for endangered whales. Contaminants reach Massachusetts Bay not only from Boston Harbor, but from other coastal communities on the Gulf of Maine, as well as from the atmosphere. Knowledge of the pathways, mechanisms, and rates at which pollutants are transported throughout these coastal environments is needed to address a wide range of management questions.
Wang, Yuwen; Zhang, Yongyou; Zhang, Qingyun; Zou, Bingsuo; Schwingenschlogl, Udo
2016-01-01
We study the dynamics of an ultrafast single photon pulse in a one-dimensional waveguide two-point coupled with a Jaynes-Cummings system. We find that for any single photon input the transmissivity depends periodically on the separation between the two coupling points. For a pulse containing many plane wave components it is almost impossible to suppress transmission, especially when the width of the pulse is less than 20 times the period. In contrast to plane wave input, the waveform of the pulse can be modified by controlling the coupling between the waveguide and Jaynes-Cummings system. Tailoring of the waveform is important for single photon manipulation in quantum informatics. PMID:27653770
NASA Astrophysics Data System (ADS)
Cohn, Joshua L.; Dos Santos, Carlos A. M.; Neumeier, John J.
We present resistivity, Hall, Seebeck, and Nernst coefficient measurements in the range 0 . 4 K <= T <= 20 K on single crystals of the quasi-one-dimensional (Q1D) metal, Li0.9Mo6O17 with current along the Q1D metallic chains. At temperatures below the nominal superconducting transition temperature (Tc = 2 K), a transition from hole-like (μ0 H < 1 T) to electron-like (μ0 H >= 2 T) behavior is evidenced in the magnetotransport coefficients. Possible insights from these results into the nature of the mysterious density-wave ordera,b responsible for the upturn in resistivity below ~ 25 K will be discussed. a. Work supported by the U.S. Department of Energy, Office of Basic Energy Sciences (DE-FG02-12ER46888, Univ. Miami), the National Science Foundation (DMR-0907036, Mont. St. Univ.), and in Lorena by the CNPq (308162/2013-7) and FAPESP (2009/54001-2).
Modelling contaminant transport for pumping wells in riverbank filtration systems.
Mustafa, Shaymaa; Bahar, Arifah; Aziz, Zainal Abdul; Suratman, Saim
2016-01-01
Analytical study of the influence of both the pumping well discharge rate and pumping time on contaminant transport and attenuation is significant for hydrological and environmental science applications. This article provides an analytical solution for investigating the influence of both pumping time and travelling time together for one-dimensional contaminant transport in riverbank filtration systems by using the Green's function approach. The basic aim of the model is to understand how the pumping time and pumping rate, which control the travelling time, can affect the contaminant concentration in riverbank filtration systems. Results of analytical solutions are compared with the results obtained using a MODFLOW numerical model. Graphically, it is found that both analytical and numerical solutions have almost the same behaviour. Additionally, the graphs indicate that any increase in the pumping rate or simulation pumping time should increase the contamination in groundwater. The results from the proposed analytical model are well matched with the data collected from a riverbank filtration site in France. After this validation, the model is then applied to the first pilot project of a riverbank filtration system conducted in Malaysia. Sensitivity analysis results highlight the importance of degradation rates of contaminants on groundwater quality, for which higher utilization rates lead to the faster consumption of pollutants.
Kurylyk, Barret L.; McKenzie, Jeffrey M; MacQuarrie, Kerry T. B.; Voss, Clifford I.
2014-01-01
Numerous cold regions water flow and energy transport models have emerged in recent years. Dissimilarities often exist in their mathematical formulations and/or numerical solution techniques, but few analytical solutions exist for benchmarking flow and energy transport models that include pore water phase change. This paper presents a detailed derivation of the Lunardini solution, an approximate analytical solution for predicting soil thawing subject to conduction, advection, and phase change. Fifteen thawing scenarios are examined by considering differences in porosity, surface temperature, Darcy velocity, and initial temperature. The accuracy of the Lunardini solution is shown to be proportional to the Stefan number. The analytical solution results obtained for soil thawing scenarios with water flow and advection are compared to those obtained from the finite element model SUTRA. Three problems, two involving the Lunardini solution and one involving the classic Neumann solution, are recommended as standard benchmarks for future model development and testing.
One-dimensional Quantum Fluids
NASA Astrophysics Data System (ADS)
Gervais, Guillaume
2015-03-01
Fifty year ago, Joachim Mazdak Luttinger generalized the Tomonaga theory of interactions in a one-dimensional metal and show that the prior restrictions imposed by Tomonaga were not necessary. This model is now known as the Tomonaga- Luttinger liquid model (TLL) and most remarkably it does have mathematically exact solutions. In the case of electrons, it predicts that the spin and charge sector should separate, with each of them propagating with their own velocities. While there has been many attempts (some with great success) to observe TLL behaviour in clean quantum wires designed on an ultra-clean semiconductor platform, overall the Luttinger physics is experimentally still in its infancy. For instance, little is known regarding the 1D physics in a strongly-interacting neutral system, whether from the point-of-view of TLL theory or even localization physics. Helium-4, the paradigm superfluid, and Helium-3, the paradigm Fermi liquid, should in principleboth become Luttinger liquids if taken to the one-dimensional limit. In the bosonic case, this is supported by large-scale Quantum Monte Carlo simulations which found that a lengthscale of ~ 2 nm is sufficient for the system to crossover to the 1D regime and display universal Luttinger scaling. At McGill University, an experiment has been constructed to measure the liquid helium mass flow through a single nanopore. The technique consists of drilling a single nanopore in a SiN membrane using a TEM, and then applying a pressure gradient across the membrane. Previously published data in 45nm diameter hole determined the superfluid critical velocity to be close to the limit set by the Feynman vortex rings model. More recent work performed on nanopores with radii as small as 3 nm (and a length of 30nm) show the critical exponent for superfluid velocity to significantly deviate from its bulk value, 2/3. This is an important hint for the crossing over to the one-dimensional state in a strongly-correlated bosonic liquid.
NASA Astrophysics Data System (ADS)
Vasylenko, Anna A.; Misko, Vyacheslav R.
2015-04-01
When floating on a two-dimensional surface of superfluid 4He, electrons arrange themselves in two-dimensional crystalline structure known as Wigner crystal. In channels, the boundaries interfere the crystalline order and in case of very narrow channels one observes a quasi-one-dimensional (quasi-1D) Wigner crystal formed by just a few rows of electrons and, ultimately, one row in the "quantum wire" regime. Recently, the "quantum wire" regime was accessed experimentally [D.G. Rees, H. Totsuji, K. Kono, Phys. Rev. Lett. 108, 176801 (2012)] resulting in unusual transport phenomena such as, e.g., oscillations in the electron conductance. Using molecular dynamics simulations, we study the nonlinear transport of electrons in channels with various types of constrictions: single and multiple symmetric and asymmetric geometrical constrictions with varying width and length, and saddle-point-type potentials with varying gate voltage. In particular, we analyze the average particle velocity of the particles and the corresponding electron current versus the driving force or the gate voltage. We have revealed a significant difference in the dynamics for long and short constrictions: The oscillations of the average velocity of the particles for the systems with short constrictions exhibit a clear correlation with the transitions between the states with different numbers of rows of particles; on the other hand, for the systems with longer constrictions these oscillations are suppressed. The obtained results qualitatively agree with the experimental observations. Next, we propose a FET-like structure that consists of a channel with asymmetric constrictions. We show that applying a transverse bias results either in increase of the average particle velocity or in its suppression thus allowing a flexible control tool over the electron transport. The advantage of the asymmetric FET is that it does not have a gate and it allows an easy control of relatively large electron flow
Modeling Facilitated Contaminant Transport by Mobile Bacteria
NASA Astrophysics Data System (ADS)
Corapcioglu, M. Yavuz; Kim, Seunghyun
1995-01-01
Introduction of exogenous biocolloids such as genetically engineered bacteria in a bioremediation operation can enhance the transport of contaminants in groundwater by reducing the retardation effects. Because of their colloidal size and favorable surface conditions, bacteria are efficient contaminant carriers. In cases where contaminants have a low mobility in porous media because of their high partition with solid matrix, facilitated contaminant transport by mobile bacteria can create high contaminant fluxes. When metabolically active mobile bacteria are present in a subsurface environment, the system can be treated as consisting of three phases: water phase, bacterial phase, and stationary solid matrix phase. In this work a mathematical model based on mass balance equations is developed to describe the facilitated transport and fate of a contaminant and bacteria in a porous medium. Bacterial partition between the bulk solution and the stationary solid matrix and contaminant partition among three phases are represented by expressions in terms of measurable quantities. Solutions were obtained to provide estimates of contaminant and bacterial concentrations. A dimensional analysis of the transport model was utilized to estimate model parameters from the experimental data and to assess the effect of several parameters on model behavior. The model results matched favorably with experimental data of Jenkins and Lion (1993). The presence of mobile bacteria enhances the contaminant transport. However, bacterial consumption of the contaminant, which serves as a bacterial nutrient, can attenuate the contaminant mobility. The work presented in this paper is the first three-phase model to include the effects of substrate metabolism on the fate of groundwater contaminants.
Verification tests for contaminant transport codes
Rowe, R.K.; Nadarajah, P.
1996-12-31
The importance of verifying contaminant transport codes and the techniques that may be used in this verification process are discussed. Commonly used contaminant transport codes are characterized as belonging to one of several types or classes of solution, such as analytic, finite layer, boundary element, finite difference and finite element. Both the level of approximation and the solution methodology should be verified for each contaminant transport code. One powerful method that may be used in contaminant transport code verification is cross-checking (benchmarking) with other codes. This technique is used to check the results of codes from one solution class with the results of codes from another solution class. In this paper cross-checking is performed for three classes of solution; these are, analytic, finite layer, and finite element.
Bäßler, Svenja Hamdou, Bacel; Sergelius, Philip; Michel, Ann-Kathrin; Zierold, Robert; Gooth, Johannes; Reith, Heiko; Nielsch, Kornelius
2015-11-02
The geometry of topological insulators (TIs) has a major impact on the magnetoelectric band structure of their surface states. Here, we investigate the surface states of cylindrical TI bismuth telluride selenide nanowires with three different diameters, by parallel and transverse magnetoresistance (MR) measurements. In parallel configuration, we observe Aharonov-Bohm oscillations as well as weak antilocalization, indicating two-dimensional TI surface states. In transverse magnetic fields, we observed MR oscillations that are non-linear against the reciprocal of the magnetic field and thus cannot be explained by two- or three-dimensional states. Instead, our transport data analysis reveals that these MR oscillations are the consequence of one-dimensional edge channels at the nanowire surface that form due to the projection of the external magnetic field on the cylindrically curved surface plane in high magnetic fields. Our observation provides an exotic class of surface states that might be used for electronic and spintronic devices.
Gureghian, A.B.; Wu, Y.T.; Sagar, B.; Codell, R.A.
1992-12-01
Exact analytical solutions based on the Laplace transforms are derived for describing the one-dimensional space-time-dependent, advective transport of a decaying species in a layered, saturated rock system intersected by a planar fracture of varying aperture. These solutions, which account for advection in fracture, molecular diffusion into the rock matrix, adsorption in both fracture and matrix, and radioactive decay, predict the concentrations in both fracture and rock matrix and the cumulative mass in the fracture. The solute migration domain in both fracture and rock is assumed to be semi-infinite with non-zero initial conditions. The concentration of each nuclide at the source is allowed to decay either continuously or according to some periodical fluctuations where both are subjected to either a step or band release mode. Two numerical examples related to the transport of Np-237 and Cm-245 in a five-layered system of fractured rock were used to verify these solutions with several well established evaluation methods of Laplace inversion integrals in the real and complex domain. In addition, with respect to the model parameters, a comparison of the analytically derived local sensitivities for the concentration and cumulative mass of Np-237 in the fracture with the ones obtained through a finite-difference method of approximation is also reported.
Contamination transport modeling with CTSP (Conference Presentation)
NASA Astrophysics Data System (ADS)
Brieda, Lubos
2016-09-01
CTSP (Contamination Transport Simulation Program) is a simulation program for performing detailed molecular and particulate contaminant transport analyses using complex, CAD-generated geometries. CTSP concurrently traces many simulation macroparticles, allowing it to compute contaminant partial pressures. The code uses a detailed surface model that supports multiple trapped gases and a multi-component surface layer. The molecular residence time is computed by considering surface temperature and activation energies. This paper describes the implemented algorithms and demonstrates the code with several test cases. These include outgassing in a vacuum chamber, spacecraft venting, particulate transport in an air flow, and redistribution of paint flakes on an orbiting satellite. The paper is concluded by summarizing the on-going effort to parallelize the code and utilize GPUs, and to add support for electrostatic return modeling by computing space potential using Green's functions.
Second virial coefficient of one dimensional gas
Mijatovic, M.
1982-08-01
The second virial coefficient of a one dimensional gas is calculated using the expressions for the scattering amplitude. The scattering amplitude is chosen in the form of rational function of wave vector.
One-Dimensional Czedli-Type Islands
ERIC Educational Resources Information Center
Horvath, Eszter K.; Mader, Attila; Tepavcevic, Andreja
2011-01-01
The notion of an island has surfaced in recent algebra and coding theory research. Discrete versions provide interesting combinatorial problems. This paper presents the one-dimensional case with finitely many heights, a topic convenient for student research.
Factorizations of one-dimensional classical systems
Kuru, Senguel; Negro, Javier
2008-02-15
A class of one-dimensional classical systems is characterized from an algebraic point of view. The Hamiltonians of these systems are factorized in terms of two functions that together with the Hamiltonian itself close a Poisson algebra. These two functions lead directly to two time-dependent integrals of motion from which the phase motions are derived algebraically. The systems so obtained constitute the classical analogues of the well known factorizable one-dimensional quantum mechanical systems.
One dimensional representations in quantum optics
NASA Technical Reports Server (NTRS)
Janszky, J.; Adam, P.; Foldesi, I.; Vinogradov, An. V.
1993-01-01
The possibility of representing the quantum states of a harmonic oscillator not on the whole alpha-plane but on its one dimensional manifolds is considered. It is shown that a simple Gaussian distribution along a straight line describes a quadrature squeezed state while a similar Gaussian distribution along a circle leads to the amplitude squeezed state. The connection between the one dimensional representations and the usual Glauber representation is discussed.
One-dimensional Gromov minimal filling problem
NASA Astrophysics Data System (ADS)
Ivanov, Alexandr O.; Tuzhilin, Alexey A.
2012-05-01
The paper is devoted to a new branch in the theory of one-dimensional variational problems with branching extremals, the investigation of one-dimensional minimal fillings introduced by the authors. On the one hand, this problem is a one-dimensional version of a generalization of Gromov's minimal fillings problem to the case of stratified manifolds. On the other hand, this problem is interesting in itself and also can be considered as a generalization of another classical problem, the Steiner problem on the construction of a shortest network connecting a given set of terminals. Besides the statement of the problem, we discuss several properties of the minimal fillings and state several conjectures. Bibliography: 38 titles.
Potential for plastics to transport hydrophobic contaminants.
Teuten, Emma L; Rowland, Steven J; Galloway, Tamara S; Thompson, Richard C
2007-11-15
Plastic debris litters marine and terrestrial habitats worldwide. It is ingested by numerous species of animals, causing deleterious physical effects. High concentrations of hydrophobic organic contaminants have also been measured on plastic debris collected from the environment, but the fate of these contaminants is poorly understood. Here, we examine the uptake and subsequent release of phenanthrene by three plastics. Equilibrium distribution coefficients for sorption of phenanthrene from seawater onto the plastics varied by more than an order of magnitude (polyethylene > polypropylene > polyvinyl chloride (PVC)). In all cases, sorption to plastics greatly exceeded sorption to two natural sediments. Desorption rates of phenanthrene from the plastics or sediments back into solution spanned several orders of magnitude. As expected, desorption occurred more rapidly from the sediments than from the plastics. Using the equilibrium partitioning method, the effects of adding very small quantities of plastic with sorbed phenanthrene to sediment inhabited by the lugworm (Arenicola marina) were evaluated. We estimate that the addition of as little as 1 microg of contaminated polyethylene to a gram of sediment would give a significant increase in phenanthrene accumulation by A. marina. Thus, plastics may be important agents in the transport of hydrophobic contaminants to sediment-dwelling organisms.
One-Dimensional Fluids with Positive Potentials
NASA Astrophysics Data System (ADS)
Fantoni, Riccardo
2017-03-01
We study a class of one-dimensional classical fluids with penetrable particles interacting through positive, purely repulsive, pair-potentials. Starting from some lower bounds to the total potential energy, we draw results on the thermodynamic limit of the given model.
One-Dimensional Oscillator in a Box
ERIC Educational Resources Information Center
Amore, Paolo; Fernandez, Francisco M.
2010-01-01
We discuss a quantum-mechanical model of two particles that interact by means of a harmonic potential and are confined to a one-dimensional box with impenetrable walls. We apply perturbation theory to the cases of different and equal masses and analyse the symmetry of the states in the latter case. We compare the approximate perturbation results…
One-dimensional differential Hardy inequality.
Kalybay, Aigerim
2017-01-01
We establish necessary and sufficient conditions for the one-dimensional differential Hardy inequality to hold, including the overdetermined case. The solution is given in terms different from those of the known results. Moreover, the least constant for this inequality is estimated.
One-dimensional quantum pump simulated by cold atoms
NASA Astrophysics Data System (ADS)
Xiao, Yun-Chang; Zhu, Ming-Han; Liu, Zheng-Qin
2015-05-01
Quantum pump set up in one-dimensional (1D) channel was proposed by the cold atom simulation. The target pumping system is driven by the double time-dependent potentials. We investigated that the system can be achieved via the study of the cold atoms simulation. And by using the Floquet scattering method and the related transport theories in the mesoscopic systems, simulations of the pumping processes were presented in detail.
Can contaminant transport models predict breakthrough?
Peng, Wei-Shyuan; Hampton, Duane R.; Konikow, Leonard F.; Kambham, Kiran; Benegar, Jeffery J.
2000-01-01
A solute breakthrough curve measured during a two-well tracer test was successfully predicted in 1986 using specialized contaminant transport models. Water was injected into a confined, unconsolidated sand aquifer and pumped out 125 feet (38.3 m) away at the same steady rate. The injected water was spiked with bromide for over three days; the outflow concentration was monitored for a month. Based on previous tests, the horizontal hydraulic conductivity of the thick aquifer varied by a factor of seven among 12 layers. Assuming stratified flow with small dispersivities, two research groups accurately predicted breakthrough with three-dimensional (12-layer) models using curvilinear elements following the arc-shaped flowlines in this test. Can contaminant transport models commonly used in industry, that use rectangular blocks, also reproduce this breakthrough curve? The two-well test was simulated with four MODFLOW-based models, MT3D (FD and HMOC options), MODFLOWT, MOC3D, and MODFLOW-SURFACT. Using the same 12 layers and small dispersivity used in the successful 1986 simulations, these models fit almost as accurately as the models using curvilinear blocks. Subtle variations in the curves illustrate differences among the codes. Sensitivities of the results to number and size of grid blocks, number of layers, boundary conditions, and values of dispersivity and porosity are briefly presented. The fit between calculated and measured breakthrough curves degenerated as the number of layers and/or grid blocks decreased, reflecting a loss of model predictive power as the level of characterization lessened. Therefore, the breakthrough curve for most field sites can be predicted only qualitatively due to limited characterization of the hydrogeology and contaminant source strength.
Transient One-dimensional Pipe Flow Analyzer
1986-04-08
TOPAZ-SNLL, the Transient One- dimensional Pipe flow AnalyZer code, is a user-friendly computer program for modeling the heat transfer, fluid mechanics, and thermodynamics of multi-species gas transfer in arbitrary arrangements of pipes, valves, vessels, and flow branches. Although the flow conservation equations are assumed to be one-dimensional and transient, multidimensional features of internal fluid flow and heat transfer may be accounted for using the available quasi-steady flow correlations (e.g., Moody friction factor correlation and various form loss and heat transfer correlations). Users may also model the effects of moving system boundaries such as pistons, diaphragms, and bladders. The features of fully compressible flow are modeled, including the propagation of shocks and rarefaction waves, as well as the establishment of multiple choke points along the flow path.
One-dimensional opal photonic crystals
NASA Astrophysics Data System (ADS)
Kapitonov, A. M.
2008-12-01
One-dimensional opals are 1D self-assembled close packed colloidal crystals consisting of monodisperse colloidal globules. Polystyrene globules with sizes in the 1.9-10 μm range sit on a flat substrate and touch two neighbors in diametrally opposite contact points. These opals are quasi-1D photonic crystals. Optical modes, including whispering gallery modes of individual globules, coupled collective modes, and nanojet-induced modes, are visualized in 1D opals.
Packaging and transportation of radioactively contaminated lead
Gleason, Eugene; Holden, Gerard
2007-07-01
Under the management of the Nuclear Decommissioning Authority (NDA) the government of the United Kingdom has launched an ambitious program to remediate the nation's nuclear waste legacy. Over a twenty-five year period NDA plans to decommission several first generation nuclear power plants and other radioactive facilities. The use innovative, safe 'fit for purpose' technologies will be a major part of this complex program. This paper will present a case study of a recently completed project undertaken in support of the nuclear decommissioning activities at the Sellafield site in the United Kingdom. The focus is on an innovative application of new packaging technology developed for the safe transportation of radioactively contaminated lead objects. Several companies collaborated on the project and contributed to its safe and successful conclusion. These companies include British Nuclear Group, Gravatom Engineering, W. F. Bowker Transport, Atlantic Container Lines, MHF Logistical Solutions and Energy Solutions. New containers and a new innovative inter-modal packaging system to transport the radioactive lead were developed and demonstrated during the project. The project also demonstrated the potential contribution of international nuclear recycling activities as a safe, economic and feasible technical option for nuclear decommissioning in the United Kingdom. (authors)
Computer model of one-dimensional equilibrium controlled sorption processes
Grove, D.B.; Stollenwerk, K.G.
1984-01-01
A numerical solution to the one-dimensional solute-transport equation with equilibrium-controlled sorption and a first-order irreversible-rate reaction is presented. The computer code is written in FORTRAN language, with a variety of options for input and output for user ease. Sorption reactions include Langmuir, Freundlich, and ion-exchange, with or without equal valance. General equations describing transport and reaction processes are solved by finite-difference methods, with nonlinearities accounted for by iteration. Complete documentation of the code, with examples, is included. (USGS)
Electrodeposition of one-dimensional nanostructures.
She, Guangwei; Mu, Lixuan; Shi, Wensheng
2009-01-01
Electrodeposition is a simple and flexible method for the synthesis of one-dimensional (1D) nanostructures and has attracted more and more attention in recent years. 1D nanostructures of metals, semiconductors and polymers have been successfully fabricated by electrodeposition. Templates were often used in the electrochemical process to realize the 1D growth. On the other hand, some materials with intrinsic anisotropic crystal structures can also be prepared by the template-free electrochemical method. In this paper, we review the recent patents progress and offer some prospects of future directions in electrodeposition of 1D nanostructures.
A one-dimensional tunable magnetic metamaterial.
Butz, S; Jung, P; Filippenko, L V; Koshelets, V P; Ustinov, A V
2013-09-23
We present experimental data on a one-dimensional super-conducting metamaterial that is tunable over a broad frequency band. The basic building block of this magnetic thin-film medium is a single-junction (rf-) superconducting quantum interference device (SQUID). Due to the nonlinear inductance of such an element, its resonance frequency is tunable in situ by applying a dc magnetic field. We demonstrate that this results in tunable effective parameters of our metamaterial consisting of 54 rf-SQUIDs. In order to obtain the effective magnetic permeability μr,eff from the measured data, we employ a technique that uses only the complex transmission coefficient S₂₁.
One-dimensional ZnO nanostructures.
Jayadevan, K P; Tseng, T Y
2012-06-01
The wide-gap semiconductor ZnO with nanostructures such as nanoparticle, nanorod, nanowire, nanobelt, nanotube has high potential for a variety of applications. This article reviews the fundamentals of one-dimensional ZnO nanostructures, including processing, structure, property, application and their processing-microstructure-property correlation. Various fabrication methods of the ZnO nanostructures including vapor-liquid-solid process, vapor-solid growth, solution growth, solvothermal growth, template-assisted growth and self-assembly are introduced. The characterization and properties of the ZnO nanostructures are described. The possible applications of these nanostructures are also discussed.
Perched-Water Analysis Related to Deep Vadose Zone Contaminant Transport and Impact to Groundwater
Oostrom, Martinus; Truex, Michael J.; Carroll, KC; Chronister, Glen B.
2013-11-15
Perched-water conditions have been observed in the vadose zone above a fine-grained zone that is located just a few meters above the water table beneath the B-complex at the Hanford Site. The perched water, containing elevated concentrations of uranium and technetium-99, is important to consider in evaluating the future flux of contaminated water into the groundwater. A study was conducted to examine the perched-water conditions and quantitatively evaluate 1) factors that control perching behavior, 2) contaminant flux toward groundwater, and, 3) associated groundwater impact. Based on the current vertical transport pathways and large areal extent of the perched system, the evaluation was conducted using a one-dimensional (1-D) analysis. Steady-state scoping calculations showed that the perching-layer hydraulic conductivity is likely to be up to two orders of magnitude less than the base case value obtained from Hanford site literature. Numerical flow and transport simulations provided both steady-state and transient system estimates of water and contaminant behavior and were used to further refine the range of conditions consistent with current observations of perched water height and to provide estimates of future water and contaminant flux to groundwater. With a recharge rate of 6 cm/yr, representative of current disturbed surface conditions, contaminant flux from the perched water occurs over a time interval of tens of years. However, if the recharge rate is 0.35 cm/yr, representative of returning recharge to pre-Hanford Site levels, the contaminant flux into the groundwater is spread over hundreds of years. It was also demonstrated that removal of perched water by pumping would reduce the flux of water (and associated contaminants) to the groundwater, thereby impacting the long-term rate of contaminant movement to the groundwater.
Feed gas contaminant removal in ion transport membrane systems
Underwood, Richard Paul [Allentown, PA; Makitka, III, Alexander; Carolan, Michael Francis [Allentown, PA
2012-04-03
An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.
One-Dimensional Photonic Crystal Superprisms
NASA Technical Reports Server (NTRS)
Ting, David
2005-01-01
Theoretical calculations indicate that it should be possible for one-dimensional (1D) photonic crystals (see figure) to exhibit giant dispersions known as the superprism effect. Previously, three-dimensional (3D) photonic crystal superprisms have demonstrated strong wavelength dispersion - about 500 times that of conventional prisms and diffraction gratings. Unlike diffraction gratings, superprisms do not exhibit zero-order transmission or higher-order diffraction, thereby eliminating cross-talk problems. However, the fabrication of these 3D photonic crystals requires complex electron-beam substrate patterning and multilayer thin-film sputtering processes. The proposed 1D superprism is much simpler in structural complexity and, therefore, easier to design and fabricate. Like their 3D counterparts, the 1D superprisms can exhibit giant dispersions over small spectral bands that can be tailored by judicious structure design and tuned by varying incident beam direction. Potential applications include miniature gas-sensing devices.
One-dimensional spinon spin currents
NASA Astrophysics Data System (ADS)
Hirobe, Daichi; Sato, Masahiro; Kawamata, Takayuki; Shiomi, Yuki; Uchida, Ken-Ichi; Iguchi, Ryo; Koike, Yoji; Maekawa, Sadamichi; Saitoh, Eiji
2017-01-01
Quantum spin fluctuation in a low-dimensional or frustrated magnet breaks magnetic ordering while keeping spin correlation. Such fluctuation has been a central topic in magnetism because of its relevance to high-Tc superconductivity and topological states. However, utilizing such spin states has been quite difficult. In a one-dimensional spin-1/2 chain, a particle-like excitation called a spinon is known to be responsible for spin fluctuation in a paramagnetic state. Spinons behave as a Tomonaga-Luttinger liquid at low energy, and the spin system is often called a quantum spin chain. Here we show that a quantum spin chain generates and carries spin current, which is attributed to spinon spin current. This is demonstrated by observing an anisotropic negative spin Seebeck effect along the spin chains in Sr2CuO3. The results show that spin current can flow even in an atomic channel owing to long-range spin fluctuation.
Three one-dimensional structural heating programs
NASA Technical Reports Server (NTRS)
Wing, L. D.
1978-01-01
Two computer programs for calculating profiles in a ten-element structure consisting of up to ten materials are presented, along with a third program for calculating the mean temperature for a payload container placed in an orbiting vehicle cargo bay. The three programs are related by the sharing of a common analytical technique; the energy balance is based upon one-dimensional heat transfer. The first program, NQLDW112, assumes a non-ablating surface. NQLDW117 is very similar but allows the outermost element to ablate. NQLDW040 calculates an average temperature profile through an idealized model of the real payload cannister and contents in the cargo bay of an orbiting vehicle.
One-dimensional frequency-based spectroscopy.
Cygan, Agata; Wcisło, Piotr; Wójtewicz, Szymon; Masłowski, Piotr; Hodges, Joseph T; Ciuryło, Roman; Lisak, Daniel
2015-06-01
Recent developments in optical metrology have tremendously improved the precision and accuracy of the horizontal (frequency) axis in measured spectra. However, the vertical (typically absorbance) axis is usually based on intensity measurements that are subject to instrumental errors which limit the spectrum accuracy. Here we report a one-dimensional spectroscopy that uses only the measured frequencies of high-finesse cavity modes to provide complete information about the dispersive properties of the spectrum. Because this technique depends solely on the measurement of frequencies or their differences, it is insensitive to systematic errors in the detection of light intensity and has the potential to become the most accurate of all absorptive and dispersive spectroscopic methods. The experimental results are compared to measurements by two other high-precision cavity-enhanced spectroscopy methods. We expect that the proposed technique will have significant impact in fields such as fundamental physics, gas metrology and environmental remote sensing.
Superfluid helium-4 in one dimensional channel
NASA Astrophysics Data System (ADS)
Kim, Duk Y.; Banavar, Samhita; Chan, Moses H. W.; Hayes, John; Sazio, Pier
2013-03-01
Superfluidity, as superconductivity, cannot exist in a strict one-dimensional system. However, the experiments employing porous media showed that superfluid helium can flow through the pores of nanometer size. Here we report a study of the flow of liquid helium through a single hollow glass fiber of 4 cm in length with an open id of 150 nm between 1.6 and 2.3 K. We found the superfluid transition temperature was suppressed in the hollow cylinder and that there is no flow above the transition. Critical velocity at temperature below the transition temperature was determined. Our results bear some similarity to that found by Savard et. al. studying the flow of helium through a nanohole in a silicon nitrite membrane. Experimental study at Penn State is supported by NSF Grants No. DMR 1103159.
FACILITATED TRANSPORT OF INORGANIC CONTAMINANTS IN GROUNDWATER: PART II. COLLOIDAL TRANSPORT
This project consisted of both field and laboratory components. Field studies evaluated routine sampling procedures for determination of aqueous inorganicgeochemistry and assessment of contaminant transport by colloidal mobility. Research at three different metal-contaminated sit...
NASA Astrophysics Data System (ADS)
Sanders, J. E.; Miller, G. R.
2015-12-01
Magnetic shell crosslinked knedel-like nanoparticles (MSCKs) were originally engineered to aid in the cleanup of oil spills. These polymeric particles are spherical and approximately 70 nm in diameter. MSCKs have a hydrophobic shell and hydrophilic core which encapsulates suspended iron oxide nanoparticles, rendering them magnetic. MSCKs operate like discrete surfactant packets: increasing the mobility and apparent solubility of hydrophobic species, but do so within the confines of discrete particles which can then be recovered by filtration or magnetic removal. MSCKs accomplish this via sequestration of hydrophobic species from through the hydrophilic shell and into the hydrophobic core where hydrocarbon contaminants are entropically stabilized. In batch reactor testing, MSCKs have been shown to sequester crude oil up to ten times their mass (1000 mg of oil per 100 mg of MSCKs). This study examines the transport characteristics and contaminant sequestration capabilities of MSCKs in saturated porous media, in order to establish their potential for use in groundwater remediation. Baseline MSCK transport parameters were determined via one dimensional impulse column experiments. MSCKs were readily transported in saturated sand, with an average recovery rate of 99%. In the presence of 10% clay particles, recovery was reduced to 68%. MSCKs were able to completely sequester an aqueous phase pollutant (8.7 mg/L m-xylene), although it further reduced their recovery rate to 61% in sand and 53% in clay. The presence of a free phase contaminant (5% of pore space occupied by mineral oil) reduced MSCKs recovery in sand to 53%. The MSCKs recovered in the effluent had sequestered the mineral at ratios far below their capability (3-10 mg of oil per 100 mg of MSCKs). Overall, this study indicated that MSCKs show a number of promising attributes for use in remediation. However, further manipulation of their chemical and morphological properties is needed, with the objective of
One-dimensional boron nanostructures: Prediction, synthesis, characterizations, and applications.
Tian, Jifa; Xu, Zhichuan; Shen, Chengmin; Liu, Fei; Xu, Ningsheng; Gao, Hong-Jun
2010-08-01
One-dimensional (1D) boron nanostructures are very potential for nanoscale electronic devices since their physical properties including electric transport and field emission have been found very promising as compared to other well-developed 1D nanomaterials. In this article, we review the current progress that has been made on 1D boron nanostructures in terms of theoretical prediction, synthetic techniques, characterizations and potential applications. To date, the synthesis of 1D boron nanostructures has been well-developed. The popular structures include nanowires, nanobelts, and nanocones. Some of these 1D nanostructures exhibited improved electric transport properties over bulk boron materials as well as promising field emission properties. By current experimental findings, 1D boron nanostructures are promising to be one of core materials for future nanodevices. More efforts are expected to be made in future on the controlled growth of 1D boron nanostructures and tailoring their physical properties.
One-dimensional quantum spin heterojunction as a thermal switch
NASA Astrophysics Data System (ADS)
Yang, Chuan-Jing; Jin, Li-Hui; Gong, Wei-Jiang
2016-03-01
We study the thermal transport through a quantum spin-1 2 heterojunction, which consists of a finite-size chain with two-site anisotropic XY interaction and three-site XZX+YZY interaction coupled at its ends to two semi-infinite isotropic XY chains. By performing the Jordan-Wigner transformation, the original spin Hamiltonian is mapped onto a fermionic Hamiltonian. Then, the fermionic structure is discussed, and the heat current as a function of structural parameters is evaluated. It is found that the magnetic fields applied at respective chains play different roles in adjusting the heat current in this heterojunction. Moreover, the interplay between the anisotropy of the XY interaction and the three-site spin interaction assists to further control the thermal transport. In view of the numerical results, we propose this heterojunction to be an alternate candidate for manipulating the heat current in one-dimensional (1D) systems.
Preliminary study of niobium alloy contamination by transport through helium
NASA Technical Reports Server (NTRS)
Scheuermann, C. M.; Moore, T. J.; Wheeler, D. R.
1987-01-01
Transport of gaseous contaminants through the working fluid to or from sensitive refractory alloys is theoretically possible during long time operation of Brayton and Stirling space power generation systems which use a gas as the working fluid. A test was designed which could give an answer to whether transport of contaminants through the working fluid was a potential major problem. The findings of that preliminary study are summarized.
Transmission resonances anomaly in one-dimensional disordered quantum systems
NASA Astrophysics Data System (ADS)
Eisenbach, A.; Bliokh, Y.; Freilkher, V.; Kaveh, M.; Berkovits, R.
2016-07-01
Connections between the electronic eigenstates and conductivity of one-dimensional (1D) disordered systems is studied in the framework of the tight-binding model. We show that for weak disorder only part of the states exhibit resonant transmission and contribute to the conductivity. The rest of the eigenvalues are not associated with peaks in transmission and the amplitudes of their wave functions do not exhibit a significant maxima within the sample. Moreover, unlike ordinary states, the lifetimes of these "hidden" modes either remain constant or even decrease (depending on the coupling with the leads) as the disorder becomes stronger. In a wide range of the disorder strengths, the averaged ratio of the number of transmission peaks to the total number of the eigenstates is independent of the degree of disorder and is close to the value √{2 /5 }, which was derived analytically in the weak-scattering approximation. These results are in perfect analogy to the spectral and transport properties of light in one-dimensional randomly inhomogeneous media [Y. P. Bliokh et al., New J. Phys. 17, 113009 (2015), 10.1088/1367-2630/17/11/113009], which provides strong grounds to believe that the existence of hidden, nonconducting modes is a general phenomenon inherent to 1D open random systems, and their fraction of the total density of states is the same for quantum particles and classical waves.
Simulating higher-dimensional geometries in GADRAS using approximate one-dimensional solutions.
Thoreson, Gregory G.; Mitchell, Dean J; Harding, Lee T.
2013-02-01
The Gamma Detector Response and Analysis Software (GADRAS) software package is capable of simulating the radiation transport physics for one-dimensional models. Spherical shells are naturally one-dimensional, and have been the focus of development and benchmarking. However, some objects are not spherical in shape, such as cylinders and boxes. These are not one-dimensional. Simulating the radiation transport in two or three dimensions is unattractive because of the extra computation time required. To maintain computational efficiency, higher-dimensional geometries require approximations to simulate them in one-dimension. This report summarizes the theory behind these approximations, tests the theory against other simulations, and compares the results to experimental data. Based on the results, it is recommended that GADRAS users always attempt to approximate reality using spherical shells. However, if fissile material is present, it is imperative that the shape of the one-dimensional model matches the fissile material, including the use of slab and cylinder geometry.
One-dimensional Electron Gases at Oxide Interfaces
NASA Astrophysics Data System (ADS)
Cao, Yanwei; Zhong, Zhicheng; Shafer, P.; Liu, Xiaoran; Kareev, M.; Middey, S.; Meyers, D.; Arenholz, E.; Chakhalian, Jak
Emergence of two-dimensional electron gases (2DEG) at the oxide interfaces of two dissimilar insulators is a remarkable manifestation of interface engineering. With continuously reduced dimensionality, it arises an interesting question: could one-dimensional electron gases (1DEG) be designed at oxide interfaces? So far there is no report on this. Here, we report on the formation of 1DEG at the carefully engineered titanate heterostructures. Combined resonant soft X-ray linear dichroism with electrical transport and the first-principles calculations have confirmed the formation of 1DEG driven by the interfacial symmetry breaking. Our findings provide a route to engineer new electronic and magnetic states. This work was supported by Gordon and Betty Moore Foundation, DODARO, DOE, and the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy.
A reactive transport model for mercury fate in contaminated soil--sensitivity analysis.
Leterme, Bertrand; Jacques, Diederik
2015-11-01
We present a sensitivity analysis of a reactive transport model of mercury (Hg) fate in contaminated soil systems. The one-dimensional model, presented in Leterme et al. (2014), couples water flow in variably saturated conditions with Hg physico-chemical reactions. The sensitivity of Hg leaching and volatilisation to parameter uncertainty is examined using the elementary effect method. A test case is built using a hypothetical 1-m depth sandy soil and a 50-year time series of daily precipitation and evapotranspiration. Hg anthropogenic contamination is simulated in the topsoil by separately considering three different sources: cinnabar, non-aqueous phase liquid and aqueous mercuric chloride. The model sensitivity to a set of 13 input parameters is assessed, using three different model outputs (volatilized Hg, leached Hg, Hg still present in the contaminated soil horizon). Results show that dissolved organic matter (DOM) concentration in soil solution and the binding constant to DOM thiol groups are critical parameters, as well as parameters related to Hg sorption to humic and fulvic acids in solid organic matter. Initial Hg concentration is also identified as a sensitive parameter. The sensitivity analysis also brings out non-monotonic model behaviour for certain parameters.
Transport of trace contaminants through porous media
NASA Technical Reports Server (NTRS)
Madey, R.
1975-01-01
Research accomplishments in the following areas are discussed: (1) the calibration of the gas chromatograph for acetaldehyde and ethanol; (2) the development of data reduction and analysis methods; (3) the generation and analysis of experimental data for the transport of 100 ppm acetaldehyde through a cylindrical bed packed with activated carbon granules; (4) the generation and analysis of experimental data for the transport of 100 ppm ethanol through a cylindrical bed packed with activated carbon granules; and (5) a comparison of the volume adsorption capacity of activated carbon for 100 ppm concentrations of acetaldehyde, ethanol, and acetone. Activities in progress and planned activities are reviewed.
Preliminary study of niobium alloy contamination by transport through helium
NASA Technical Reports Server (NTRS)
Scheuermann, Coulson M.; Moore, Thomas J.; Wheeler, Donald R.
1987-01-01
Preliminary tests were conducted to determine if interstitial element transport through a circulating helium working fluid was a potential problem in Brayton and Stirling space power systems. Test specimens exposed to a thermal gradient for up to 3000-hr included Nb-1%Zr, a Sm-Co alloy (referred to as SmCo in this paper), Hiperco 50 steel, and alumina to simulate various engine components of the Brayton and Stirling systems. Results indicate that helium transport of interstitial contaminants can be minimized over a 7-yr life with a monometallic Nb-1%Zr design. Exposure with other materials indicated a potential for interstitial contaminant transport. Determination of contamination kinetics and the effects on structural integrity will require additional testing.
Tomasko, D.
1990-04-01
One-dimensional analytical expressions are developed to simulate two processes in a homogeneous porous medium: contaminant transport through a porous medium that has a zero-concentration sink located at a finite distance from a step-function source; and contaminant transport through a porous medium that has an initial steady-state distribution corresponding to a constant strength source and zero-concentration sink separated by a finite distance. The governing equations are cast in dimensionless form, making use of the flow system's Peclet number. Evaluation of the analytical expressions is accomplished by numerical inversion of Laplace-space concentrations using either a full Fourier series approach with acceleration, or the Stehfest algorithm. The analytical expressions are used to evaluate possible contaminant conditions at the Weldon Spring quarry near Weldon Spring, Missouri. The following results have been found: contaminant concentrations should be at or near steady-state conditions; the spatial distribution of contaminants should be a function of the flow system's Peclet number; contaminant concentrations near the Femme Osage Slough should approach zero; contaminant concentrations near the quarry during dewatering and bulk-waste removal should monotonically decrease with time; and the spatial distribution of contaminants during remedial activities should be relatively flat, especially near the dewatering pumps. Future work will entail evaluating existing radionuclide or chemical concentration data to determine the applicability of the proposed contaminant transport model and to improve the hydrogeological conceptualization of the quarry area and vicinity. 20 refs., 27 figs.
Outgassing study of spacecraft materials and contaminant transport simulations
NASA Astrophysics Data System (ADS)
Wong, Chung M.; Labatete-Goeppinger, Aura C.; Fowler, Jesse D.; Easton, Myriam P.; Liu, De-Ling
2016-09-01
Contamination control plays an important role in sustaining spacecraft performance. One spacecraft degradation mechanism involves long-term on-orbit molecular outgassing from spacecraft materials. The outgassed molecules may accumulate on thermal control surfaces and/or optics, causing degradation. In this study, we performed outgassing measurements of multiple spacecraft materials, including adhesives, Nylon Velcro, and other assembly materials through a modified ASTM E595 test method. The modified ASTM E595 test had the source and receiver temperature remained at 125°C and 25°C, respectively, but with prolonged outgassing periods of two weeks. The condensable contaminants were analyzed by Fourier Transform Infrared Spectroscopy (FTIR) and Gas Chromatography/Mass Spectrometry (GC/MS) to determine their spectral transmission and chemical composition. The FTIR spectra showed several spacecraft materials, primarily adhesives and potting materials, exhibiting slight absorption from contaminants consisting of hydroxyl groups and carboxylic acids. To gain insight into molecular contaminant transport, simulations were conducted to characterize contaminant accumulation inside a hypothetical space system cavity. The simulation indicated that contaminant molecules bouncing inside the hypothetical payload cavity can lead to deposition on colder surfaces, even though large openings are available to provide venting pathways for escaping to space. The newly established molecular contaminant transport simulation capability holds the promise of providing quantitative guidance for future spacecraft and its venting design.
The effects of a perturbed source on contaminant transport near the Weldon Spring quarry
Tomasko, D.
1989-03-01
The effects of a perturbed contamination source at the Weldon Spring quarry in St. Charles County, Missouri, on downstream solute concentrations were investigated using one-dimensional analytical solutions to an advection-dispersion equation developed for both constant-strength and multiple-stepped source functions. A sensitivity study using parameter base-case values and ranges consistent with the geologic conceptualization of the quarry area indicates that the parameters having the greatest effect on predicted concentrations are the distance from the quarry to the point of interest, the average linear groundwater velocity, the contaminant retardation coefficient, and the amplitude and duration of the source perturbation caused by response action activities. Use of base-case parameter value and realistic values for the amplitude and duration of the source perturbation produced a small effect on solute concentrations near the western extremity of the nearby municipal well field, as well as small uncertainties in the predicted results for the assumed model. The effect of simplifying assumptions made in deriving the analytic solution is unknown: use of a multidimensional flow and transport model and additional field work are needed to validate the model. 13 refs., 18 figs.
CONTAMINANT TRANSPORT IN PARALLEL FRACTURED MEDIA: SUDICKY AND FRIND REVISITED
This paper is concerned with a modified, nondimensional form of the parallel fracture, contaminant transport model of Sudicky and Frind (1982). The modifications include the boundary condition at the fracture wall, expressed by a parameter, and the power-law relationship between...
CONTAMINANT TRANSPORT IN PARALLEL FRACTURED MEDIA: SUDICKY AND FRIND REVISITED
This paper is concerned with a modified, nondimensional form of the parallel fracture, contaminant transport model of Sudicky and Frind (1982). The modifications include the boundary condition at the fracture wall, expressed by a parameter , and the power-law relationship betwe...
Transportation cask contamination weeping: A program leading to prevention
Bennett, P. C.; Doughty, D. H.; Chambers, W. B.
1991-01-01
This paper describes the problem of cask contamination weeping, and efforts to understand the phenomenon and to eliminate its occurrence during spent nuclear fuel transport. The paper analyses of field experience and scoping experiments, and concentrates on current modelling and experimental validation efforts. The weeping'' phenomenon associated with spent fuel transportation casks (also known as sweating'') is believed to be due to the conversion of fixed contamination on the external surface of the cask to a removable form. Spent fuel transportation casks are loaded under water at nuclear power plants in a spent fuel storage pool, exposing the cask surfaces to contamination by radionuclides present in the pool water including {sup 137}Cs, {sup 134}Cs, and {sup 60}Co. The external surfaces of loaded casks are routinely surveyed for removable contamination and decontaminated to 1/10 of the US and IAEA regulatory limits prior to being released for shipment (49CFR 1983, IAEA 1989). However, 3% to 8% of US spent fuel casks have arrived at final destinations with removable surface contamination in excess of that allowed by regulation, though many preshipment surveys have shown contaminant levels to be within allowable limits (Grella 1987). Attempts to reduce the incidence of weeping have met with limited success and resulted in time-consuming operational constraints and procedures that significantly increase cask processing times and occupational exposures at loading facilities. As the US Department of Energy (DOE) moves toward a high volume spent fuel transportation campaign beginning in 1998, the elimination of weeping occurrence and minimization of operational constraints has received increased attention.
Contaminant Transport Through Subsurface Material from the DOE Hanford Reservation
Pace, M.N.; Mayes, M.A.; Jardine, P.M.; Fendorf, S.E.; Nehlhorn, T.L.; Yin, X.P.; Ladd, J.; Teerlink, J.; Zachara, J.M.
2003-03-26
Accelerated migration of contaminants in the vadose zone has been observed beneath tank farms at the U.S. Department of Energy's Hanford Reservation. This paper focuses on the geochemical processes controlling the fate and transport of contaminants in the sediments beneath the Hanford tank farms. Laboratory scale batch sorption experiments and saturated transport experiments were conducted using reactive tracers U(VI), Sr, Cs, Co and Cr(VI) to investigate geochemical processes controlling the rates and mechanisms of sorption to Hanford subsurface material. Results indicate that the rate of sorption is influenced by changes in solution chemistry such as ionic strength, pH and presence of competing cations. Sediment characteristics such as mineralogy, iron content and cation/anion exchange capacity coupled with the dynamics of flow impact the number of sites available for sorption. Investigative approaches using a combination of batch and transport experiments will contribute to the conceptual and Hanford vadose zone.
Reentrant phase coherence in a quasi-one-dimensional superconductor
NASA Astrophysics Data System (ADS)
Ansermet, Diane; Petrovic, Alexander P.; He, Shikun; Chernyshov, Dmitri; Hoesch, Moritz; Salloum, Diala; Gougeon, Patrick; Potel, Michel; Boeri, Lilia; Andersen, Ole K.; Panagopoulos, Christos
Short coherence lengths characteristic of low-dimensional superconductors are related to high critical fields or temperatures. Fatally, such materials are often sensitive to disorder and suffer from phase fluctuations in the order parameter which diverge with temperature T, magnetic field H or current I. To solve synthesis and fluctuation problems, we propose to build superconductors from inhomogeneous composites of nanofilaments. Single crystals of quasi-one-dimensional Na2-δMo6Se6 featuring Na vacancy disorder (δ ~ 0 . 2) behave as percolative networks of superconducting nanowires. Long range order is established via transverse coupling between individual filaments, yet phase coherence is unstable to fluctuations and localization in the zero-(T, H, I) limit. A region of reentrant phase coherence develops upon raising (T, H, I) and is attributed to an enhancement of the transverse coupling due to electron delocalization. The observed reentrance in the electronic transport coincides with a peak in the Josephson energy EJ at non-zero (T, H, I). Na2-δMo6Se6 is a blueprint for a new generation of low dimensional superconductors with resilience to phase fluctuations at high (T, H, I). This work was supported by the National Research Foundation, Singapore, through Grant NRF-CRP4-2008-04.
THE IMPACT OF GROUND WATER-SURFACE WATER INTERACTIONS ON CONTAMINANT TRANSPORT AT CONTAMINATED SITES
The purpose of this document is to provide an overview of the dynamics of chemical processes that govern contaminant transport and speciation during water exchange across the GW/SW transition zone. A conceptual model of the GW/SW transition zone is defined to serve as a starting...
Monitoring Potential Transport of Radioactive Contaminants in Shallow Ephemeral Channels
Miller, Julianne J.; Mizell, Steve A.; Nikolich, George; Campbell, Scott A.
2012-02-01
The U.S. Department of Energy (DOE) National Nuclear Security Administration (NNSA), Nevada Site Office (NSO), Environmental Restoration Soils Activity has authorized the Desert Research Institute (DRI) to conduct field assessments of potential sediment transport of contaminated soil from Corrective Action Unit (CAU) 550, Area 8 Smoky Contamination Area (CA), during precipitation runoff events. CAU 550 includes Corrective Action Sites (CASs) 08-23-03, 08-23-04, 08-23-06, and 08-23-07; these CASs are associated with tests designated Ceres, Smoky, Oberon, and Titania, respectively.
One-dimensional Pt induced chains on Si(337)
NASA Astrophysics Data System (ADS)
McChesney, Jessica; Bostwick, A.; Rotenberg, E.; Lapeyre, Gerald
2006-03-01
The use of high index Si surfaces as templates for the formation of adsorbate induced one-dimensional chain structures have attracted considerable interest. These systems have been used as a test bed in which to study low-dimension physics and components of nanoelectronics. In addition to the Ag and Au induced chains reported to form on the Si(337) surface, Pt also produces one-dimensional chains. Angle-resolved photoemission spectroscopy was used to investigate the electronic structure of these new Pt chains. The valence band mapping confirms the one-dimensional nature of these chains as seen in LEED. Supported by ONR and DOE.
Torsional Detwinning Domino in Nanotwinned One-Dimensional Nanostructures.
Zhou, Haofei; Li, Xiaoyan; Wang, Ying; Liu, Zishun; Yang, Wei; Gao, Huajian
2015-09-09
How to maintain sustained deformation in one-dimensional nanostructures without localized failure is an important question for many applications of nanotechnology. Here we report a phenomenon of torsional detwinning domino that leads to giant rotational deformation without localized failure in nanotwinned one-dimensional metallic nanostructures. This mechanism is demonstrated in nanotwinned Cu nanorods via molecular dynamics simulations, where coherent twin boundaries are transformed into twist boundaries and then dissolved one by one, resulting in practically unlimited rotational deformation. This finding represents a fundamental advance in our understanding of deformation mechanisms in one-dimensional metallic nanostructures.
IMPACT OF REDOX DISEQUILIBRIA ON CONTAMINANT TRANSPORT AND REMEDIATION IN SUBSURFACE SYSTEMS
Partitioning to mineral surfaces exerts significant control on inorganic contaminant transport in subsurface systems. Remedial technologies for in-situ treatment of subsurface contamination are frequently designed to optimize the efficiency of contaminant partitioning to solid s...
NASA Astrophysics Data System (ADS)
Ouyang, Ying
2002-09-01
Phytoremediation is an emerging technology that uses plants and their associated rhizospheric microorganisms to remove, degrade, detoxify, or contain contaminants located in the soil, sediments, groundwater, surface water, and even the atmosphere. This study investigates phytoremediation of 1,4-dioxane from a contaminated sandy soil by a poplar cutting, which is associated with water flow in the soil as well as water movement and 1,4-dioxane translocation in the xylem and phloem systems. An existing one-dimensional mathematical model for coupled transport of water, heat, and solutes in the soil-plant-atmosphere continuum (CTSPAC) is modified for the purpose of this study. The model is calibrated with the laboratory experimental measurements prior to its applications. A simulation scenario is then performed to investigate phytoremediation of 1,4-dioxane by a poplar cutting in response to daily water flow and 1,4-dioxane transport for a simulation period of 7 days. Simulation shows that 1,4-dioxane concentration is high in leaves and low in roots with the stem in between. However, 1,4-dioxane mass in the stem (60%) is higher than that of leaves (28%) and roots (12%). This occurs because the stem volume used in this study is larger than those of leaves and roots. The simulation further reveals that about 30% of the soil 1,4-dioxane is removed within 7 days, resulting mainly from root uptake. A plot of the 1,4-dioxane concentrations in plant compartments as a function of time shows that the highest concentration in leaves is about 2600 μg/cm 3 and the lowest concentration in roots is about 350 μg/cm 3 at the end of the simulation. Results indicate that leaves are an important compartment for 1,4-dioxane accumulation and transpiration. This study suggests that the modified CTSPAC model could be a useful tool for phytoremediation estimations.
An investigation of dopping profile for a one dimensional heterostructure
NASA Astrophysics Data System (ADS)
Huang, Zhaohui
2005-03-01
A one-dimensional junction is formed by joining two silicon nanowires whose surfaces are terminated with capping groups of different electronegativity and polarizability. If this heterostructure is doped (with e.g. phosphorous) on the side with the higher bandgap, the system becomes a modulation doped heterostructure with novel one-dimensional electrostatics. We use density functional theory calculations in the pseudopotential approximation, plus empirical model calculations, to investigate doping profiles in this new class of nanostructures.
Simulation of contaminated sediment transport in White Oak Creek basin
Bao, Y.; Clapp, R.B.; Brenkert, A.L.; Moore, T.D.; Fontaine, T.A.
1995-12-31
This paper presents a systematic approach to management of the contaminated sediments in the White Oak Creek watershed at Oak Ridge National Laboratory near Oak Ridge, Tennessee. The primary contaminant of concern is radioactive cesium-137 ({sup 137}Cs), which binds to soil and sediment particles. The key components in the approach include an intensive sampling and monitoring system for flood events; modeling of hydrological processes, sediment transport, and contaminant flux movement; and a decision framework with a detailed human health risk analysis. Emphasis is placed on modeling of watershed rainfall-runoff and contaminated sediment transport during flooding periods using the Hydrologic Simulation Program- Fortran (HSPF) model. Because a large number of parameters are required in HSPF modeling, the major effort in the modeling process is the calibration of model parameters to make simulation results and measured values agree as closely as possible. An optimization model incorporating the concepts of an expert system was developed to improve calibration results and efficiency. Over a five-year simulation period, the simulated flows match the observed values well. Simulated total amount of sediment loads at various locations during storms match with the observed values within a factor of 1.5. Simulated annual releases of {sup 137}Cs off-site locations match the data within a factor of 2 for the five-year period. The comprehensive modeling approach can provide a valuable tool for decision makers to quantitatively analyze sediment erosion, deposition, and transport; exposure risk related to radionuclides in contaminated sediment; and various management strategies.
Modeling subsurface contaminant reactions and transport at the watershed scale
Gwo, J.P.; Jardine, P.M.; D`Azevedo, E.F.; Wilson, G.V.
1997-12-01
The objectives of this research are: (1) to numerically examine the multiscale effects of physical and chemical mass transfer processes on watershed scale, variably saturated subsurface contaminant transport, and (2) to conduct numerical simulations on watershed scale reactive solute transport and evaluate their implications to uncertainty characterization and cost benefit analysis. Concurrent physical and chemical nonequilibrium caused by inter aggregate gradients of pressure head and solute concentration and intra-aggregate geochemical and microbiological processes, respectively, may arise at various scales and flowpaths. To this date, experimental investigations of these complex processes at watershed scale remain a challenge and numerical studies are often needed for guidance of water resources management and decision making. This research integrates the knowledge bases developed during previous experimental and numerical investigations at a proposed waste disposal site at the Oak Ridge National Laboratory to study the concurrent effects of physical and chemical nonequilibrium. Comparison of numerical results with field data indicates that: (1) multiregion, preferential flow and solute transport exist under partially saturated condition and can be confirmed theoretically, and that (2) mass transfer between pore regions is an important process influencing contaminant movement in the subsurface. Simulations of watershed scale, multi species reactive solute transport suggest that dominance of geochemistry and hydrodynamics may occur simultaneously at different locales and influence the movement of one species relative to another. Execution times on the simulations of the reactive solute transport model also indicate that the model is ready to assist the selection of important parameters for site characterization.
Prediction methodology for contaminant transport from rangeland watersheds
Devaurs, M.A.; Springer, E.P.; Lane, L.J.; Langhorst, G.J.
1988-01-01
Weather on arid and semiarid lands can be extremely variable. Runoff is generally emphermeral, and high intensity, short-duration rainfall events are the major stimulus for runoff events. Transport of sediment and associated contaminants occurs with these infrequent events. Incorporation of variability in weather into any prediction technology is essential to provide accurate representations of climate-induced uncertainty in predictions of hydrologic response. The objective of this study is to investigate a method for including short-term climatic variations in analyses for contaminant transport from rangeland watersheds in arid/semiarid regions. Short term is defined here as a twenty to fifty time frame and it is assumed that lone term climatic fluctuations are not observed during this time. Also, most weather records are available for this time period; predictions of greater length are extrapolations of existing records unless corroborative data for longer term trends are collected. Predictions are being made with condensable uncertainty in the weather inputs even if the models for water, sediment, and contaminant transport are perfectly unknown. This study will incorporate uncertainty in weather inputs into the prediction process and address the ramifications of this uncertainty. Uncertainty introduced by improper model or parameter specification is only briefly addressed.
One dimensional time-to-explode (ODTX) in HMX spheres
Breshears, D.
1997-06-02
In a series of papers researchers at Lawrence Livermore National Laboratory (LLNL) have reported measurements of the time to explosion in spheres of various high explosives following a rapid, uniform increase in the surface temperature of the sphere. Due to the spherical symmetry, the time-dependent properties of the explosive (temperature, chemical composition, etc.) are functions of the radial spatial coordinate only; thus the name one-dimensional time-to-explosion (ODTX). The LLNL researchers also report an evolving series of computational modeling results for the ODTX experiments, culminating in those obtained using a sophisticated heat transfer code incorporating accurate descriptions of chemical reaction. Although the chemical reaction mechanism used to describe HMX decomposition is quite simple, the computational results agree very well with the experimental data. In addition to reproducing the magnitude and temperature dependence of the measured times to explosion, the computational results also agree with the results of post reaction visual inspection. The ODTX experiments offer a near-ideal example of a transport process (heat transfer in this case) tightly coupled with chemical reaction. The LLNL computational model clearly captures the important features of the ODTX experiments. An obvious question of interest is to what extent the model and/or its individual components (specifically the chemical reaction mechanism) are applicable to other experimental scenarios. Valid exploration of this question requires accurate understanding of (1) the experimental scenario addressed by the LLNL model and (2) details of the application of the model. The author reports here recent work addressing points (1) and (2).
Jeffrey Yang, Y; Goodrich, James A; Clark, Robert M; Li, Sylvana Y
2008-03-01
A modified one-dimensional Danckwerts convection-dispersion-reaction (CDR) model is numerically simulated to explain the observed chlorine residual loss for a "slug" of reactive contaminants instantaneously introduced into a drinking water pipe of assumed no or negligible wall demand. In response to longitudinal dispersion, a contaminant propagates into the bulk phase where it reacts with disinfectants in the water. This process generates a U-shaped pattern of chlorine residual loss in a time-series concentration plot. Numerical modeling indicates that the residual loss curve geometry (i.e., slope, depth, and width) is a function of several variables such as axial Péclet number, reaction rate constants, molar fraction of the fast- and slow-reacting contaminants, and the quasi-steady-state chlorine decay inside the "slug" which serves as a boundary condition of the CDR model. Longitudinal dispersion becomes dominant for less reactive contaminants. Pilot-scale pipe flow experiments for a non-reactive sodium fluoride tracer and the fast-reacting aldicarb, a pesticide, were conducted under turbulent flow conditions (Re=9020 and 25,000). Both the experimental results and the CDR modeling are in agreement showing a close relationship among the aldicarb contaminant "slug", chlorine residual loss and its variations, and a concentration increase of chloride as the final reaction product. Based on these findings, the residual loss curve and its geometry are useful tools to identify the presence of a contaminant "slug" and infer its reactive properties in adaptive contaminant detections.
One-dimensional rainbow technique using Fourier domain filtering.
Wu, Yingchun; Promvongsa, Jantarat; Wu, Xuecheng; Cen, Kefa; Grehan, Gerard; Saengkaew, Sawitree
2015-11-16
Rainbow refractometry can measure the refractive index and the size of a droplet simultaneously. The refractive index measurement is extracted from the absolute rainbow scattering angle. Accordingly, the angular calibration is vital for accurate measurements. A new optical design of the one-dimensional rainbow technique is proposed by using a one-dimensional spatial filter in the Fourier domain. The relationship between the scattering angle and the CCD pixel of a recorded rainbow image can be accurately determined by a simple calibration. Moreover, only the light perpendicularly incident on the lens in the angle (φ) direction is selected, which exactly matches the classical inversion algorithm used in rainbow refractometry. Both standard and global one-dimensional rainbow techniques are implemented with the proposed optical design, and are successfully applied to measure the refractive index and the size of a line of n-heptane droplets.
One-dimensional dynamics in locally heated liquid layers
NASA Astrophysics Data System (ADS)
Burguete, J.; Maza, D.; Mancini, H. L.
2003-01-01
Recent results on one-dimensional patterns in locally heated experiments are presented. A fluid layer is heated locally by a nearly one-dimensional heater, and subjected to both horizontal and vertical temperature gradients. Depending on the fluid depth and on the temperature difference established across the layer different convective regimes appear. When a very small temperature gradient is applied a basic convective state appears. It consists of two big rolls parallel to the heater and filling the convective cell. A primary instability in the homogeneous basic flow gives rise to a one-dimensional cellular stationary pattern. For higher values of the control parameters, time-dependent patterns appear through a secondary instability. Various regimes are analyzed: oscillations, traveling waves and alternating patterns. The hydrodynamic characteristics of these patterns are provided. Local temperature measurements allows to describe the physical mechanisms responsible for the instabilities. The similarities and discrepancies of the experimental data with some theoretical models are provided.
Few-body route to one-dimensional quantum liquids
NASA Astrophysics Data System (ADS)
Valiente, Manuel; Öhberg, Patrik
2016-11-01
Gapless many-body quantum systems in one spatial dimension are universally described by the Luttinger liquid effective theory at low energies. Essentially, only two parameters enter the effective low-energy description, namely, the speed of sound and the Luttinger parameter. These are highly system dependent and their calculation requires accurate nonperturbative solutions of the many-body problem. Here we present a simple theoretical method that only uses collisional information to extract the low-energy properties of spinless one-dimensional systems. Our results are in remarkable agreement with available results for integrable models and from large-scale Monte Carlo simulations of one-dimensional helium and hydrogen isotopes. Moreover, we estimate theoretically the critical point for spinodal decomposition in one-dimensional 4He and show that the exponent governing the divergence of the Luttinger parameter near the critical point is exactly 1/2, in excellent agreement with Monte Carlo simulations.
Some topological states in one-dimensional cold atomic systems
Mei, Feng; Zhang, Dan-Wei; Zhu, Shi-Liang
2015-07-15
Ultracold atoms trapped in optical lattices nowadays have been widely used to mimic various models from condensed-matter physics. Recently, many great experimental progresses have been achieved for producing artificial magnetic field and spin–orbit coupling in cold atomic systems, which turn these systems into a new platform for simulating topological states. In this paper, we give a review focusing on quantum simulation of topologically protected soliton modes and topological insulators in one-dimensional cold atomic system. Firstly, the recent achievements towards quantum simulation of one-dimensional models with topological non-trivial states are reviewed, including the celebrated Jackiw–Rebbi model and Su–Schrieffer–Heeger model. Then, we will introduce a dimensional reduction method for systematically constructing high dimensional topological states in lower dimensional models and review its applications on simulating two-dimensional topological insulators in one-dimensional optical superlattices.
Quantum solution for the one-dimensional Coulomb problem
Nunez-Yepez, H. N.; Salas-Brito, A. L.; Solis, Didier A.
2011-06-15
The one-dimensional hydrogen atom has been a much studied system with a wide range of applications. Since the pioneering work of Loudon [R. Loudon, Am. J. Phys. 27, 649 (1959).], a number of different features related to the nature of the eigenfunctions have been found. However, many of the claims made throughout the years in this regard are not correct--such as the existence of only odd eigenstates or of an infinite binding-energy ground state. We explicitly show that the one-dimensional hydrogen atom does not admit a ground state of infinite binding energy and that the one-dimensional Coulomb potential is not its own supersymmetric partner. Furthermore, we argue that at the root of many such false claims lies the omission of a superselection rule that effectively separates the right side from the left side of the singularity of the Coulomb potential.
Transport of soluble and unsoluble contaminants in compound vortex
NASA Astrophysics Data System (ADS)
Stepanova, Eugenia
2010-05-01
Transport of solvable substances by separate vortices and vortex flows is studied regularly in environmental and laboratory conditions. The compound vortex is generated in the cylindrical container by the rotating disk. It is possible to observe strongly pronounced area - a vortex core by means of dye injection into the centre of surface trough. Inside the fluid the dye gathers in the central cylindrical area. On a free surface contaminants are located in separate compact areas - in bounded areas near the vertical axis of compound vortex and spiral arms. The separate tinted and clear water areas are observed for a long time in scales of activator rotation period. Parameters of flow patterns geometry are measured in wide range of basic flow conditions. Strong effect of unsoluble contaminant on general flow dynamics in the container is found. Registered flow patterns are compared with environmental observations.
Random registry shifts in quasi-one-dimensional adsorbate systems
NASA Astrophysics Data System (ADS)
Schäfer, J.; Erwin, S. C.; Hansmann, M.; Song, Z.; Rotenberg, E.; Kevan, S. D.; Hellberg, C. S.; Horn, K.
2003-02-01
The apparent contradiction of one-dimensional adsorbate chains on Si(111) having a 3×2 unit cell and yet a 3×1 diffraction pattern is resolved for the example of Ba/Si(111)-(3×2). Random registry shifts between adsorbate chains are observed in tunneling microscopy, with very short interchain correlation lengths. Fourier analysis provides a natural explanation for a pseudo-(3×1) diffraction pattern. Within density-functional theory such registry shifts can occur with essentially negligible energy cost, leading to entropy-driven, virtually perfect disorder. Substrate states of high symmetry and one-dimensional character are inferred to promote this phenomenon.
Random registry shifts in quasi-one-dimensional adsorbate systems
Schafer, J.; Erwin, S.C.; Hansmann, M.; Song, Z.; Rotenberg, E.; Kevan, S.D.; Hellberg, C.S.; Horn, K.
2003-02-18
The apparent contradiction of one-dimensional adsorbate chains on Si(111) having a 3x2 unit cell and yet a 3x1 diffraction pattern is resolved for the example of Ba/Si(111)-(3x2). Random registry shifts between adsorbate chains are observed in tunneling microscopy, with very short interchain correlation lengths. Fourier analysis provides a natural explanation for a pseudo-(3x1) diffraction pattern. Within density-functional theory such registry shifts can occur with essentially negligible energy cost, leading to entropy-driven, virtually perfect disorder. Substrate states of high symmetry and one-dimensional character are inferred to promote this phenomenon.
Lie symmetry algebra of one-dimensional nonconservative dynamical systems
NASA Astrophysics Data System (ADS)
Liu, Cui-Mei; Wu, Run-Heng; Fu, Jing-Li
2007-09-01
Lie symmetry algebra of linear nonconservative dynamical systems is studied in this paper. By using 1-1 mapping, the Lie point and Lie contact symmetry algebras are obtained from two independent solutions of the one-dimensional linear equations of motion.
Underwater striling engine design with modified one-dimensional model
NASA Astrophysics Data System (ADS)
Li, Daijin; Qin, Kan; Luo, Kai
2015-09-01
Stirling engines are regarded as an efficient and promising power system for underwater devices. Currently, many researches on one-dimensional model is used to evaluate thermodynamic performance of Stirling engine, but in which there are still some aspects which cannot be modeled with proper mathematical models such as mechanical loss or auxiliary power. In this paper, a four-cylinder double-acting Stirling engine for Unmanned Underwater Vehicles (UUVs) is discussed. And a one-dimensional model incorporated with empirical equations of mechanical loss and auxiliary power obtained from experiments is derived while referring to the Stirling engine computer model of National Aeronautics and Space Administration (NASA). The P-40 Stirling engine with sufficient testing results from NASA is utilized to validate the accuracy of this one-dimensional model. It shows that the maximum error of output power of theoretical analysis results is less than 18% over testing results, and the maximum error of input power is no more than 9%. Finally, a Stirling engine for UUVs is designed with Schmidt analysis method and the modified one-dimensional model, and the results indicate this designed engine is capable of showing desired output power.
Underwater striling engine design with modified one-dimensional model
NASA Astrophysics Data System (ADS)
Li, Daijin; Qin, Kan; Luo, Kai
2015-05-01
Stirling engines are regarded as an efficient and promising power system for underwater devices. Currently, many researches on one-dimensional model is used to evaluate thermodynamic performance of Stirling engine, but in which there are still some aspects which cannot be modeled with proper mathematical models such as mechanical loss or auxiliary power. In this paper, a four-cylinder double-acting Stirling engine for Unmanned Underwater Vehicles (UUVs) is discussed. And a one-dimensional model incorporated with empirical equations of mechanical loss and auxiliary power obtained from experiments is derived while referring to the Stirling engine computer model of National Aeronautics and Space Administration (NASA). The P-40 Stirling engine with sufficient testing results from NASA is utilized to validate the accuracy of this one-dimensional model. It shows that the maximum error of output power of theoretical analysis results is less than 18% over testing results, and the maximum error of input power is no more than 9%. Finally, a Stirling engine for UUVs is designed with Schmidt analysis method and the modified one-dimensional model, and the results indicate this designed engine is capable of showing desired output power.
Approximate Approaches to the One-Dimensional Finite Potential Well
ERIC Educational Resources Information Center
Singh, Shilpi; Pathak, Praveen; Singh, Vijay A.
2011-01-01
The one-dimensional finite well is a textbook problem. We propose approximate approaches to obtain the energy levels of the well. The finite well is also encountered in semiconductor heterostructures where the carrier mass inside the well (m[subscript i]) is taken to be distinct from mass outside (m[subscript o]). A relevant parameter is the mass…
The Long Decay Model of One-Dimensional Projectile Motion
ERIC Educational Resources Information Center
Lattery, Mark Joseph
2008-01-01
This article introduces a research study on student model formation and development in introductory mechanics. As a point of entry, I present a detailed analysis of the Long Decay Model of one-dimensional projectile motion. This model has been articulated by Galileo ("in De Motu") and by contemporary students. Implications for instruction are…
One-Dimensional Ising Model with "k"-Spin Interactions
ERIC Educational Resources Information Center
Fan, Yale
2011-01-01
We examine a generalization of the one-dimensional Ising model involving interactions among neighbourhoods of "k" adjacent spins. The model is solved by exploiting a connection to an interesting computational problem that we call ""k"-SAT on a ring", and is shown to be equivalent to the nearest-neighbour Ising model in the absence of an external…
Teaching Module for One-Dimensional, Transient Conduction.
ERIC Educational Resources Information Center
Ribando, Robert J.; O'Leary, Gerald W.
1998-01-01
Describes a PC-based teaching module designed to instruct engineering students in transient one-dimensional conduction heat transfer analysis. The discussion considers problem formulation, nondimensionalization, discretization, numerical stability and the time-step restriction, program operation, and program verification. (MES)
Toward precise solution of one-dimensional velocity inverse problems
Gray, S.; Hagin, F.
1980-01-01
A family of one-dimensional inverse problems are considered with the goal of reconstructing velocity profiles to reasonably high accuracy. The travel-time variable change is used together with an iteration scheme to produce an effective algorithm for computation. Under modest assumptions the scheme is shown to be convergent.
Optically induced zener tunneling in one-dimensional lattices.
Fratalocchi, Andrea; Assanto, Gaetano; Brzdakiewicz, Kasia A; Karpierz, Mirek A
2006-03-15
We investigate Landau-Zener tunneling in one-dimensional liquid crystalline waveguide arrays by all-optical impression of acceleration with an additional beam. We derive the Zener model from the governing equations and demonstrate a novel approach to Floquet-Bloch band tunneling.
Strong correlations and topological order in one-dimensional systems
NASA Astrophysics Data System (ADS)
De Gottardi, Wade Wells
This thesis presents theoretical studies of strongly correlated systems as well as topologically ordered systems in 1D. Non-Fermi liquid behavior characteristic of interacting 1D electron systems is investigated with an emphasis on experimentally relevant setups and observables. The existence of end Majorana fermions in a 1D p-wave superconductor subject to periodic, incommensurate and disordered potentials is studied. The Tomonaga-Luttinger liquid (TLL), a model of interacting electrons in one spatial dimension, is considered in the context of two systems of experimental interest. First, a study of the electronic properties of single-walled armchair carbon nanotubes in the presence of transverse electric and magnetic fields is presented. As a result of their effect on the band structure and electron wave functions, fields alter the nature of the (effective) Coulomb interaction in tubes. In particular, it is found that fields couple to nanotube bands (or valleys), a quantum degree of freedom inherited from the underlying graphene lattice. As revealed by a detailed TLL calculation, it is predicted that fields induce electrons to disperse into their spin, band, and charge components. Fields also provide a means of tuning the shell-filling behavior associated with short tubes. The phenomenon of charge fractionalization is investigated in a one-dimensional ring. TLL theory predicts that momentum-resolved electrons injected into the ring will fractionalize into clockwise- and counterclockwise-moving quasiparticles. As a complement to transport measurements in quantum wires connected to leads, non-invasive measures involving the magnetic field profiles around the ring are proposed. Topological aspects of 1D p-wave superconductors are explored. The intimate connection between non-trivial topology (fermions) and spontaneous symmetry breaking (spins) in one-dimension is investigated. Building on this connection, a spin ladder system endowed with vortex degrees of freedom is
Assessing conceptual models for subsurface reactive transport of inorganic contaminants
Davis, James A.; Yabusaki, Steven B.; Steefel, Carl; Zachara, John M.; Curtis, Gary P.; Redden, George D.; Criscenti, Louise J.; Honeyman, Bruce D.
2004-01-01
In many subsurface situations where human health and environmental quality are at risk (e.g., contaminant hydrogeology petroleum extraction, carbon sequestration, etc.),scientists and engineers are being asked by federal agency decision-makers to predict the fate of chemical species under conditions where both reactions and transport are processes of first-order importance.In 2002, a working group (WG) was formed by representatives of the U.S. Geological Survey, Environmental Protection Agency, Department of Energy Nuclear Regulatory Commission, Department of Agriculture, and Army Engineer Research and Development Center to assess the role of reactive transport modeling (RTM) in addressing these situations. Specifically the goals of the WG are to (1) evaluate the state of the art in conceptual model development and parameterization for RTM, as applied to soil,vadose zone, and groundwater systems, and (2) prioritize research directions that would enhance the practical utility of RTM.
Subsurface Flow and Contaminant Transport Documentation and User's Guide
Aleman, S.E.
1999-07-28
This report documents a finite element code designed to model subsurface flow and contaminant transport, named FACT. FACT is a transient three-dimensional, finite element code designed to simulate isothermal groundwater flow, moisture movement, and solute transport in variably saturated and fully saturated subsurface porous media. The code is designed specifically to handle complex multi-layer and/or heterogeneous aquifer systems in an efficient manner and accommodates a wide range of boundary conditions. Additionally, 1-D and 2-D (in Cartesian coordinates) problems are handled in FACT by simply limiting the number of elements in a particular direction(s) to one. The governing equations in FACT are formulated only in Cartesian coordinates.
Analysis of Contaminant Transport through the Vadose and Saturated Zones for Source Screening
NASA Astrophysics Data System (ADS)
Bedekar, V.; Neville, C. J.; Tonkin, M. J.
2010-12-01
At complex sites there may be many potential source areas. Screening level analyses are useful to identify which of the source areas should be the focus of detailed investigation and analysis. A screening tool has been developed to evaluate the threat posed by waste sites on groundwater quality. This tool implements analytical solutions to simulate contaminant transport through the vadose and saturated zones and predict time-varying concentrations at potential groundwater receptors. The screening tool is developed within a user friendly, Microsoft ExcelTM based interface; however, care has been taken to implement rigorous solutions. The screening tool considers the following mechanisms: (a) Partitioning of soil contamination in to an equivalent dissolved concentration. For a time-invariant source, the solution is generalized from [3] for sorption and decay. For a time-varying source, the solution represents a special, degenerate, case of a solution implemented in ATRANS [2]; (b) One-dimensional (1D) transport of the dissolved contamination through the vadose zone considering 1D dispersion, equilibrium sorption, and first order transformation reactions. Steady state infiltration and moisture content are assumed; (c) Blending (mixing) of ambient water quality in the saturated zone with the contaminated water leaching from the vadose zone; and (d) Three-dimensional (3D) transport through the saturated zone using the formulation provided in [2], considering advection, dispersion, sorption, and first-order transformation reactions. The solution is derived using integral transform methods, following approaches adopted in [1] and [4]. Independent verification showed that the analytical techniques implemented in this study generate solutions that closely approximate those obtained using sophisticated numerical approaches, with a systematic over-estimate of the likely impact to groundwater that (predictably) stems from the use of a 1D approximation in the vadose zone. As a
Spin-drag relaxation time in one-dimensional spin-polarized Fermi gases
NASA Astrophysics Data System (ADS)
Rainis, Diego; Polini, Marco; Tosi, M. P.; Vignale, G.
2008-01-01
Spin propagation in systems of one-dimensional interacting fermions at finite temperature is intrinsically diffusive. The spreading rate of a spin packet is controlled by a transport coefficient termed “spin drag” relaxation time τsd . In this paper we present both numerical and analytical calculations of τsd for a two-component spin-polarized cold Fermi gas trapped inside a tight atomic waveguide. At low temperatures we find an activation law for τsd , in agreement with earlier calculations of Coulomb drag between slightly asymmetric quantum wires, but with a different and much stronger temperature dependence of the prefactor. Our results provide a fundamental input for microscopic time-dependent spin-density functional theory calculations of spin transport in one-dimensional inhomogeneous systems of interacting fermions.
Emergence of correlated optics in one-dimensional waveguides for classical and quantum atomic gases
NASA Astrophysics Data System (ADS)
Ruostekoski, Janne; Javanainen, Juha
2016-09-01
We analyze the emergence of correlated optical phenomena in the transmission of light through a waveguide that confines classical or ultracold quantum degenerate atomic ensembles. The conditions of the correlated collective response are identified in terms of atom density, thermal broadening, and photon losses by using stochastic Monte Carlo simulations and transfer matrix methods of transport theory. We also calculate the "cooperative Lamb shift" for the waveguide transmission resonance, and discuss line shifts that are specific to effectively one-dimensional waveguide systems.
Luttinger parameter of quasi-one-dimensional para -H2
NASA Astrophysics Data System (ADS)
Ferré, G.; Gordillo, M. C.; Boronat, J.
2017-02-01
We have studied the ground-state properties of para-hydrogen in one dimension and in quasi-one-dimensional configurations using the path-integral ground-state Monte Carlo method. This method produces zero-temperature exact results for a given interaction and geometry. The quasi-one-dimensional setup has been implemented in two forms: the inner channel inside a carbon nanotube coated with H2 and a harmonic confinement of variable strength. Our main result is the dependence of the Luttinger parameter on the density within the stable regime. Going from one dimension to quasi-one dimension, keeping the linear density constant, produces a systematic increase of the Luttinger parameter. This increase is, however, not enough to reach the superfluid regime and the system always remain in the quasicrystal regime, according to Luttinger liquid theory.
Fibonacci anyon excitations of one-dimensional dipolar lattice bosons
NASA Astrophysics Data System (ADS)
Äńurić, Tanja; Biedroń, Krzysztof; Zakrzewski, Jakub
2017-02-01
We study a system of dipolar bosons in a one-dimensional optical lattice using exact diagonalization and density matrix renormalization group methods. In particular, we analyze low energy properties of the system at an average filling of 3/2 atoms per lattice site. We identify the region of the parameter space where the system has non-Abelian Fibonacci anyon excitations that correspond to fractional domain walls between different charge-density waves. When such one-dimensional systems are combined into a two-dimensional network, braiding of Fibonacci anyon excitations has potential application for fault tolerant, universal, topological quantum computation. Contrary to previous calculations, our results also demonstrate that super-solid phases are not present in the phase diagram for the discussed 3/2 average filling. Instead, decreasing the value of the nearest-neighbor tunneling strength leads to a direct, Berezinskii-Kosterlitz-Thouless, superfluid to charge-density-wave quantum phase transition.
One-dimensional Si nanolines in hydrogenated Si(001)
NASA Astrophysics Data System (ADS)
François, Bianco; Köster, Sigrun A.; Owen, James G. H.; Renner, Christoph; Bowler, David R.
2012-02-01
We present a detailed study of the structural and electronic properties of a self-assembled silicon nanoline embedded in the H-terminated silicon (001) surface, known as the Haiku stripe. The nanoline is a perfectly straight and defect free endotaxial structure of huge aspect ratio; it can grow micrometre long at a constant width of exactly four Si dimers (1.54 nm). Another remarkable property is its capacity to be exposed to air without suffering any degradation. The nanoline grows independently of any step edges at tunable densities, from isolated nanolines to a dense array of nanolines. In addition to these unique structural characteristics, scanning tunnelling microscopy and density functional theory reveal a one-dimensional state confined along the Haiku core. This nanoline is a promising candidate for the long sought after electronic solid-state one-dimensional model system to explore the fascinating quantum properties emerging in such reduced dimensionality. Phys. Rev. B, 84, 035328 (2011)
On numerical modeling of one-dimensional geothermal histories
Haugerud, R.A.
1989-01-01
Numerical models of one-dimensional geothermal histories are one way of understanding the relations between tectonics and transient thermal structure in the crust. Such models can be powerful tools for interpreting geochronologic and thermobarometric data. A flexible program to calculate these models on a microcomputer is available and examples of its use are presented. Potential problems with this approach include the simplifying assumptions that are made, limitations of the numerical techniques, and the neglect of convective heat transfer. ?? 1989.
Single parameter scaling in one-dimensional localization revisited
Deych; Lisyansky; Altshuler
2000-03-20
The variance of the Lyapunov exponent is calculated exactly in the one-dimensional Anderson model with random site energies distributed according to the Cauchy distribution. We find a new significant scaling parameter in the system, and derive an exact analytical criterion for single parameter scaling which differs from the commonly used condition of phase randomization. The results obtained are applied to the Kronig-Penney model with the potential in the form of periodically positioned delta functions with random strength.
Defects in a nonlinear pseudo one-dimensional solid
NASA Astrophysics Data System (ADS)
Blanchet, Graciela B.; Fincher, C. R., Jr.
1985-03-01
These infrared studies of acetanilide together with the existence of two equivalent structures for the hydrogen-bonded chain suggest the possibility of a topological defect state rather than a Davydov soliton as suggested previously. Acetanilide is an example of a class of one-dimensional materials where solitons are a consequence of a twofold degenerate structure and the nonlinear dynamics of the hydrogen-bonded network.
Thermalization in a one-dimensional integrable system
Grisins, Pjotrs; Mazets, Igor E.
2011-11-15
We present numerical results demonstrating the possibility of thermalization of single-particle observables in a one-dimensional system, which is integrable in both the quantum and classical (mean-field) descriptions (a quasicondensate of ultracold, weakly interacting bosonic atoms are studied as a definite example). We find that certain initial conditions admit the relaxation of single-particle observables to the equilibrium state reasonably close to that corresponding to the Bose-Einstein thermal distribution of Bogoliubov quasiparticles.
Nonequilibrium statistical mechanics in one-dimensional bose gases
NASA Astrophysics Data System (ADS)
Baldovin, F.; Cappellaro, A.; Orlandini, E.; Salasnich, L.
2016-06-01
We study cold dilute gases made of bosonic atoms, showing that in the mean-field one-dimensional regime they support stable out-of-equilibrium states. Starting from the 3D Boltzmann-Vlasov equation with contact interaction, we derive an effective 1D Landau-Vlasov equation under the condition of a strong transverse harmonic confinement. We investigate the existence of out-of-equilibrium states, obtaining stability criteria similar to those of classical plasmas.
Fast Integration of One-Dimensional Boundary Value Problems
NASA Astrophysics Data System (ADS)
Campos, Rafael G.; Ruiz, Rafael García
2013-11-01
Two-point nonlinear boundary value problems (BVPs) in both unbounded and bounded domains are solved in this paper using fast numerical antiderivatives and derivatives of functions of L2(-∞, ∞). This differintegral scheme uses a new algorithm to compute the Fourier transform. As examples we solve a fourth-order two-point boundary value problem (BVP) and compute the shape of the soliton solutions of a one-dimensional generalized Korteweg-de Vries (KdV) equation.
Thermal breakage of a discrete one-dimensional string.
Lee, Chiu Fan
2009-09-01
We study the thermal breakage of a discrete one-dimensional string, with open and fixed ends, in the heavily damped regime. Basing our analysis on the multidimensional Kramers escape theory, we are able to make analytical predictions on the mean breakage rate and on the breakage propensity with respect to the breakage location on the string. We then support our predictions with numerical simulations.
Free-surface turbulent flow and contaminants transport modeling
Wang, S.S.Y.
1994-12-31
The requirement of maintaining the environmental quality and ecological balance of the surface water systems at the acceptable level both now and in the future has accelerated the development and refinement of a cost-effective engineering analysis and design tool--Computational Modeling. This paper presents the progress of an on-going study to develop and refine computational models to simulate the free-surface turbulent flows and contaminants transport phenomena. New developments include: the efficient Element Method, which adopts the advantages of both Finite Element and Finite Difference; the most effective up-winding and/or characteristic-path integration; the prescribed solution forcing to conduct modeling verification studies of this correctness and capabilities in prediction of nonlinear effects; among others. The newly refined computational models have been applied to simulate unsteady, three-dimensional, turbulent, free-surface flows and pollutant transport in lakes, reservoirs, streams, rivers, estuaries, and coastal waters with natural (highly-irregular) geometric configurations. They have been verified in some cases to be able to predict basic physical characteristics of the free surface flows including boundary layer separations and re-attachments, wake flow and vortex shedding, corner separation and re-circulation, etc. They are also capable of simulating the transport of solute substances, solid particles and heat energy in these waters. Results can be displayed in stationary (snapshots) color graphics and in animation (motion pictures) recorded on video cassettes.
Analysis of necking based on a one-dimensional model
NASA Astrophysics Data System (ADS)
Audoly, Basile; Hutchinson, John W.
2016-12-01
Dimensional reduction is applied to derive a one-dimensional energy functional governing tensile necking localization in a family of initially uniform prismatic solids, including as particular cases rectilinear blocks in plane strain and cylindrical bars undergoing axisymmetric deformations. The energy functional depends on both the axial stretch and its gradient. The coefficient of the gradient term is derived in an exact and general form. The one-dimensional model is used to analyze necking localization for nonlinear elastic materials that experience a maximum load under tensile loading, and for a class of nonlinear materials that mimic elastic-plastic materials by displaying a linear incremental response when stretch switches from increasing to decreasing. Bifurcation predictions for the onset of necking from the simplified theory compared with exact results suggest the approach is highly accurate at least when the departures from uniformity are not too large. Post-bifurcation behavior is analyzed to the point where the neck is fully developed and localized to a region on the order of the thickness of the block or bar. Applications to the nonlinear elastic and elastic-plastic materials reveal the highly unstable nature of necking for the former and the stable behavior for the latter, except for geometries where the length of the block or bar is very large compared to its thickness. A formula for the effective stress reduction at the center of a neck is established based on the one-dimensional model, which is similar to that suggested by Bridgman (1952).
Dynamical structure factor of one-dimensional hard rods
NASA Astrophysics Data System (ADS)
Motta, M.; Vitali, E.; Rossi, M.; Galli, D. E.; Bertaina, G.
2016-10-01
The zero-temperature dynamical structure factor S (q ,ω ) of one-dimensional hard rods is computed using state-of-the-art quantum Monte Carlo and analytic continuation techniques, complemented by a Bethe ansatz analysis. As the density increases, S (q ,ω ) reveals a crossover from the Tonks-Girardeau gas to a quasisolid regime, along which the low-energy properties are found in agreement with the nonlinear Luttinger liquid theory. Our quantitative estimate of S (q ,ω ) extends beyond the low-energy limit and confirms a theoretical prediction regarding the behavior of S (q ,ω ) at specific wave vectors Qn=n 2 π /a , where a is the core radius, resulting from the interplay of the particle-hole boundaries of suitably rescaled ideal Fermi gases. We observe significant similarities between hard rods and one-dimensional 4He at high density, suggesting that the hard-rods model may provide an accurate description of dense one-dimensional liquids of quantum particles interacting through a strongly repulsive, finite-range potential.
A Linear Systems Approach to Segmented Watershed Contaminant Transport
NASA Astrophysics Data System (ADS)
Carleton, J. N.
2013-12-01
The U.S. Environmental Protection Agency (USEPA) employs simulation models to estimate concentrations of pesticide residues in surface waters for risk assessment. These models have historically been used to simulate runoff loadings from homogeneous landscapes to isolated, well-mixed lentic systems that generically represent vulnerable waters. Recent efforts to refine this approach in terms of realism and geographic specificity have focused on enhancing the level of detail of the landscape representation, rather than that of receiving water hydrology. Linear systems theory and transfer function based approaches have been applied by various investigators to the representation of contaminant leaching through soils, and to surface water hydrology (e.g., unit hydrographs), but rarely to contaminant transport either within surface waters, or through multi-compartment systems such as stream networks. This poster describes a straightforward approach to simulating watersheds as segmented into collections of linked water bodies. The approach employs convolution integrals, impulse response functions, and the Discrete Fourier Transform to propagate concentration time series from upstream to downstream locations. Given knowledge only of estimated mean stream residence times, with appropriately-scaled segmentations of catchments, realistic representations of concentration dynamics are shown to be achievable. These representations are based upon high-frequency atrazine monitoring data sets collected over common time periods from upstream and downstream locations within the same small watersheds. Simulated concentrations are shown to match measured concentrations well in both the temporal and spectral domains without the need for calibration, and despite inherent simplifying assumptions such as steady flow. The approach may have utility for enhancing surface water hydrologic representation in contaminant modeling used for regulatory purposes.
Coliform contamination of a coastal embayment: Sources and transport pathways
Weiskel, P.K.; Howes, B.L.; Heufelder, G.R.
1996-01-01
Fecal bacterial contamination of nearshore waters has direct economic impacts to coastal communities through the loss of shellfisheries and restrictions of recreational uses. We conducted seasonal measurements of fecal coliform (FC) sources and transport pathways contributing to FC contamination of Buttermilk Bay, a shallow embayment adjacent to Buzzards Bay, MA. Typical of most coastal embayments, there were no direct sewage discharges (i.e., outfalls), and fecal bacteria from human, domestic animal, and wildlife pools entered open waters primarily through direct deposition or after transport through surface waters or groundwaters. Direct fecal coliform inputs to bay waters occurred primarily in winter (December-March) from waterfowl, ~33 x 1012 FC yr-1 or ~67% of the total annual loading. Effects of waterfowl inputs on bay FC densities were mitigated by their seasonality, wide distribution across the bay surface, and the apparent limited dispersal from fecal pellets. On-site disposal of sewage by septic systems was the single largest FC source in the watershed-embayment system, 460 x 1012 FC yr-1, but due to attenuation during subsurface transport only a minute fraction, < 0.006 x 1012 FC yr-1, reached bay waters (<0.01% of annual input to bay). Instead, surface water flows, via storm drains and natural streams under both wet- and dry-weather conditions, contributed the major terrestrial input, 12 x 1012 FC yr-1 (24% of annual input), all from animal sources. Since most of the surface water FC inputs were associated with periodic, short-duration rain events with discharge concentrated in nearshore zones, wet-weather flows were found to have a disproportionately high impact on nearshore FC levels. Elution of FC from shoreline deposits of decaying vegetation (wrack) comprised an additional coliform source. Both laboratory and field experiments suggest significant elution of bacteria from wrack, ~3 x 1012 FC yr-1 on a bay-wide basis (6% of annual input), primarily
Choi, SangKook; Park, Cheol-Hwan; Louie, Steven G
2014-07-11
Electron supercollimation, in which a wave packet is guided to move undistorted along a selected direction, is a highly desirable property that has yet to be realized experimentally. Disorder in general is expected to inhibit supercollimation. Here we report a counterintuitive phenomenon of electron supercollimation by disorder in graphene and related Dirac fermion materials. We show that one can use one-dimensional disorder potentials to control electron wave packet transport. This is distinct from known systems where an electron wave packet would be further spread by disorder and hindered in the potential fluctuating direction. The predicted phenomenon has significant implications in the understanding and applications of electron transport in Dirac fermion materials.
Local chiral symmetry and charge-density waves in one-dimensional conductors
NASA Astrophysics Data System (ADS)
Sakita, B.; Shizuya, K.
1990-09-01
Symmetry-related features of charge-density-wave transport phenomena are studied using a non-mean-field effective Lagrangian approach. It is pointed out that a local chiral symmetry (based on the Kač-Moody algebra) emerges in the low-energy structure of one-dimensional electron-phonon systems. From this symmetry follow directly power-law correlations of both electrons and phonons. The Peierls instability is suppressed owing to one-dimensional fluctuations. Still the charge-density wave arises and the chiral anomaly can account for acceleration of a sliding charge-density wave along with a phonon-drag effect. The problem of pinning of charge-density waves is discussed in relation to explicit breakings of the chiral symmetry.
One-dimensional behavior and high thermoelectric power factor in thin indium arsenide nanowires
Mensch, P.; Karg, S. Schmidt, V.; Gotsmann, B.; Schmid, H.; Riel, H.
2015-03-02
Electrical conductivity and Seebeck coefficient of quasi-one-dimensional indium arsenide (InAs) nanowires with 20 nm diameter are investigated. The carrier concentration of the passivated nanowires was modulated by a gate electrode. A thermoelectric power factor of 1.7 × 10{sup −3} W/m K{sup 2} was measured at room temperature. This value is at least as high as in bulk-InAs and exceeds by far typical values of thicker InAs nanowires with three-dimensional properties. The interpretation of the experimental results in terms of power-factor enhancement by one-dimensionality is supported by model calculations using the Boltzmann transport formalism.
Ordering of small particles in one-dimensional coherent structures by time-periodic flows.
Pushkin, D O; Melnikov, D E; Shevtsova, V M
2011-06-10
Small particles transported by a fluid medium do not necessarily have to follow the flow. We show that for a wide class of time-periodic incompressible flows inertial particles have a tendency to spontaneously align in one-dimensional dynamic coherent structures. This effect may take place for particles so small that often they would be expected to behave as passive tracers and be used in PIV measurement technique. We link the particle tendency to form one-dimensional structures to the nonlinear phenomenon of phase locking. We propose that this general mechanism is, in particular, responsible for the enigmatic formation of the "particle accumulation structures" discovered experimentally in thermocapillary flows more than a decade ago and unexplained until now.
One-Dimensional Scanning Approach to Shock Sensing
NASA Technical Reports Server (NTRS)
Tokars, Roger; Adamovsky, Girgory; Floyd, Bertram
2009-01-01
Measurement tools for high speed air flow are sought both in industry and academia. Particular interest is shown in air flows that exhibit aerodynamic shocks. Shocks are accompanied by sudden changes in density, pressure, and temperature. Optical detection and characterization of such shocks can be difficult because the medium is normally transparent air. A variety of techniques to analyze these flows are available, but they often require large windows and optical components as in the case of Schlieren measurements and/or large operating powers which precludes their use for in-flight monitoring and applications. The one-dimensional scanning approach in this work is a compact low power technique that can be used to non-intrusively detect shocks. The shock is detected by analyzing the optical pattern generated by a small diameter laser beam as it passes through the shock. The optical properties of a shock result in diffraction and spreading of the beam as well as interference fringes. To investigate the feasibility of this technique a shock is simulated by a 426 m diameter optical fiber. Analysis of results revealed a direct correlation between the optical fiber or shock location and the beam s diffraction pattern. A plot of the width of the diffraction pattern vs. optical fiber location reveals that the width of the diffraction pattern was maximized when the laser beam is directed at the center of the optical fiber. This work indicates that the one-dimensional scanning approach may be able to determine the location of an actual shock. Near and far field effects associated with a small diameter laser beam striking an optical fiber used as a simulated shock are investigated allowing a proper one-dimensional scanning beam technique.
Three material and four material one-dimensional phononic crystals
NASA Astrophysics Data System (ADS)
Kriegel, Ilka; Scotognella, Francesco
2017-01-01
In this work, we studied one-dimensional phononic structures for selective acoustic filtering. The structures are composed of three and four materials which have different elastic properties. We have observed that the phononic band gaps split in two and three transmission valleys for the three-material and the four-material based phononic structures, respectively. Furthermore, the number of transmission peaks between the split gaps is directly related to the number of unit cells composing the phononic structures. The observations of this work can be useful for the fabrication of acoustic filters with the possibility to select the transmission of particular frequencies.
Parallel solution of sparse one-dimensional dynamic programming problems
NASA Technical Reports Server (NTRS)
Nicol, David M.
1989-01-01
Parallel computation offers the potential for quickly solving large computational problems. However, it is often a non-trivial task to effectively use parallel computers. Solution methods must sometimes be reformulated to exploit parallelism; the reformulations are often more complex than their slower serial counterparts. We illustrate these points by studying the parallelization of sparse one-dimensional dynamic programming problems, those which do not obviously admit substantial parallelization. We propose a new method for parallelizing such problems, develop analytic models which help us to identify problems which parallelize well, and compare the performance of our algorithm with existing algorithms on a multiprocessor.
Quantum mechanics of graphene with a one-dimensional potential
Miserev, D. S.; Entin, M. V.
2012-10-15
Electron states in graphene with a one-dimensional potential have been studied. An approximate solution has been obtained for a small angle between vectors of the incident electron momentum and potential gradient. Exactly solvable problems with a potential of the smoothened step type U(x) Utanh(x/a) and a potential with a singularity U(x) = -U/(|x| + d) are considered. The transmission/reflection coefficients and phases for various potential barriers are determined. A quasi-classical solution is obtained.
A statistical formulation of one-dimensional electron fluid turbulence
NASA Technical Reports Server (NTRS)
Fyfe, D.; Montgomery, D.
1977-01-01
A one-dimensional electron fluid model is investigated using the mathematical methods of modern fluid turbulence theory. Non-dissipative equilibrium canonical distributions are determined in a phase space whose co-ordinates are the real and imaginary parts of the Fourier coefficients for the field variables. Spectral densities are calculated, yielding a wavenumber electric field energy spectrum proportional to k to the negative second power for large wavenumbers. The equations of motion are numerically integrated and the resulting spectra are found to compare well with the theoretical predictions.
One-dimensional hydrodynamic model generating a turbulent cascade
NASA Astrophysics Data System (ADS)
Matsumoto, Takeshi; Sakajo, Takashi
2016-05-01
As a minimal mathematical model generating cascade analogous to that of the Navier-Stokes turbulence in the inertial range, we propose a one-dimensional partial-differential-equation model that conserves the integral of the squared vorticity analog (enstrophy) in the inviscid case. With a large-scale random forcing and small viscosity, we find numerically that the model exhibits the enstrophy cascade, the broad energy spectrum with a sizable correction to the dimensional-analysis prediction, peculiar intermittency, and self-similarity in the dynamical system structure.
One-dimensional model of fluidized-bed combustor dynamics
Perez, R.B.
1980-01-01
Starting from Soo's basic multiphase equations, a set of one-dimensional time-dependent hydrodynamic and enthalpy equations was developed for a fluidized bed reactor by averaging over its cross sectional area. The following effects were not considered in the derivation of the FBC equations: forces to accelerate the apparent mass of the solid particle, basset force, heat exchange by radiation between solids and fluid or within each phase, and electrodynamic effects. Within these restrictions, the material developed here forms the basis for a sequel to this report devoted to the development of stability studies and to the application of stochastic methods for FBC surveillance.
One-dimensional intense laser pulse solitons in a plasma
Sudan, R.N.; Dimant, Y.S.; Shiryaev, O.B.
1997-05-01
A general analytical framework is developed for the nonlinear dispersion relations of a class of large amplitude one-dimensional isolated envelope solitons for modulated light pulse coupled to electron plasma waves, previously investigated numerically [Kozlov {ital et al.}, Zh. Eksp. Teor. Fiz. {bold 76}, 148 (1979); Kaw {ital et al.}, Phys. Rev. Lett. {bold 68}, 3172 (1992)]. The analytical treatment of weakly nonlinear solitons [Kuehl and Zhang, Phys. Rev. E {bold 48}, 1316 (1993)] is extended to the strongly nonlinear limit. {copyright} {ital 1997 American Institute of Physics.}
Singular Spectrum of Lebesgue Measure Zerofor One-Dimensional Quasicrystals
NASA Astrophysics Data System (ADS)
Lenz, Daniel
The spectrum of one-dimensional discrete Schr\\"odinger operators associated to strictly ergodic dynamical systems is shown to coincide with the set of zeros of the Lyapunov exponent if and only if the Lyapunov exponent exists uniformly. This is used to obtain Cantor spectrum of zero Lebesgue measure for all aperiodic subshifts with uniform positive weights. This covers, in particular, all aperiodic subshifts arising from primitive substitutions including new examples as e.g. the Rudin-Shapiro substitution. Our investigation is not based on trace maps. Instead it relies on an Oseledec type theorem due to A. Furman and a uniform ergodic theorem due to the author.
Numerical computations on one-dimensional inverse scattering problems
NASA Technical Reports Server (NTRS)
Dunn, M. H.; Hariharan, S. I.
1983-01-01
An approximate method to determine the index of refraction of a dielectric obstacle is presented. For simplicity one dimensional models of electromagnetic scattering are treated. The governing equations yield a second order boundary value problem, in which the index of refraction appears as a functional parameter. The availability of reflection coefficients yield two additional boundary conditions. The index of refraction by a k-th order spline which can be written as a linear combination of B-splines is approximated. For N distinct reflection coefficients, the resulting N boundary value problems yield a system of N nonlinear equations in N unknowns which are the coefficients of the B-splines.
Strongly anisotropic wetting on one-dimensional nanopatterned surfaces.
Xia, Deying; Brueck, S R J
2008-09-01
This communication reports strongly anisotropic wetting behavior on one-dimensional nanopatterned surfaces. Contact angles, degree of anisotropy, and droplet distortion are measured on micro- and nanopatterned surfaces fabricated with interference lithography. Both the degree of anisotropy and the droplet distortion are extremely high as compared with previous reports because of the well-defined nanostructural morphology. The surface is manipulated to tune with the wetting from hydrophobic to hydrophilic while retaining the structural wetting anisotropy with a simple silica nanoparticle overcoat. The wetting mechanisms are discussed. Potential applications in microfluidic devices and evaporation-induced pattern formation are demonstrated.
Quantum Criticality of Quasi-One-Dimensional Topological Anderson Insulators
NASA Astrophysics Data System (ADS)
Altland, Alexander; Bagrets, Dmitry; Fritz, Lars; Kamenev, Alex; Schmiedt, Hanno
2014-05-01
We present an analytic theory of quantum criticality in the quasi-one-dimensional topological Anderson insulators of class AIII and BDI. We describe the systems in terms of two parameters (g, χ) representing localization and topological properties, respectively. Surfaces of half-integer valued χ define phase boundaries between distinct topological sectors. Upon increasing system size, the two parameters exhibit flow similar to the celebrated two-parameter flow describing the class A quantum Hall insulator. However, unlike the quantum Hall system, an exact analytical description of the entire phase diagram can be given. We check the quantitative validity of our theory by comparison to numerical transfer matrix computations.
Correlations in light propagation in one-dimensional waveguides
NASA Astrophysics Data System (ADS)
Javanainen, Juha; Ruostekoski, Janne
2016-05-01
We study light propagation between atoms in a one-dimensional waveguide both analytically and using numerical simulations. We employ classical electrodynamics, but in the limit of low light intensity the results are essentially exact also for quantum mechanics. We characterize the cooperative interactions between the atoms mediated by the electromagnetic field. The focus is on resonance shifts for various statistics of the positions of the atoms, such as statistically independent positions or atoms in a regular lattice. These shifts, potentially important if 1D waveguides are to be used in metrology, are different from the usual resonance shifts found in three spatial dimensions.
Saturable discrete vector solitons in one-dimensional photonic lattices
Vicencio, Rodrigo A.; Smirnov, Eugene; Rueter, Christian E.; Kip, Detlef; Stepic, Milutin
2007-09-15
Localized vectorial modes, with equal frequencies and mutually orthogonal polarizations, are investigated both analytically and experimentally in a one-dimensional photonic lattice with defocusing saturable nonlinearity. It is shown that these modes may span over many lattice elements and that energy transfer among the two components is both phase and intensity dependent. The transverse electrically polarized mode exhibits a single-hump structure and spreads in cascades in saturation, while the transverse magnetically polarized mode exhibits splitting into a two-hump structure. Experimentally such discrete vector solitons are observed in lithium niobate lattices for both coherent and mutually incoherent excitations.
Coupling of impurity modes in one-dimensional periodic systems.
Royo, P; Stanley, R P; Ilegems, M
2001-07-01
One-dimensional periodic dielectric structures are known to exhibit band gaps because of their symmetry. Defect states can be found in the band gaps if an impurity layer is added to the lattice such that the symmetry of the structure is broken. In this paper, we consider the case where a second impurity layer is added and we discuss the existence of coupling between the two defects. We discuss the possibility of exploiting the coupling of impurity modes in the realization of tunable wavelength emitting devices and dual-wavelength vertical-cavity surface-emitting lasers.
One-dimensional metal oxide nanostructures for heterogeneous catalysis.
Zhang, Qian; Wang, Hsin-Yi; Jia, Xinli; Liu, Bin; Yang, Yanhui
2013-08-21
Metal oxides are of paramount importance in heterogeneous catalysis as either supports or active phases. Controlled synthesis of one-dimensional (1D) metal oxide nanostructures has received enormous attention in heterogeneous catalysis due to the possibility of tailoring the properties of metal oxides by tuning their shapes, sizes, and compositions. This feature article highlights recent advances in shape controlled synthesis of 1D metal oxide nanostructures and their applications in heterogeneous catalysis, with the aim of introducing new insights into the heterogeneous catalyst design.
Wave propagation in one-dimensional microscopic granular chains
NASA Astrophysics Data System (ADS)
Lin, Wei-Hsun; Daraio, Chiara
2016-11-01
We employ noncontact optical techniques to generate and measure stress waves in uncompressed, one-dimensional microscopic granular chains, and support our experiments with discrete numerical simulations. We show that the wave propagation through dry particles (150 μm radius) is highly nonlinear and it is significantly influenced by the presence of defects (e.g., surface roughness, interparticle gaps, and misalignment). We derive an analytical relation between the group velocity and gap size, and define bounds for the formation of highly nonlinear solitary waves as a function of gap size and axial misalignment.
Molecular nanostamp based on one-dimensional porphyrin polymers.
Kanaizuka, Katsuhiko; Izumi, Atsushi; Ishizaki, Manabu; Kon, Hiroki; Togashi, Takanari; Miyake, Ryosuke; Ishida, Takao; Tamura, Ryo; Haga, Masa-aki; Moritani, Youji; Sakamoto, Masatomi; Kurihara, Masato
2013-08-14
Surface design with unique functional molecules by a convenient one-pot treatment is an attractive project for the creation of smart molecular devices. We have employed a silane coupling reaction of porphyrin derivatives that form one-dimensional polymer wires on substrates. Our simple one-pot treatment of a substrate with porphyrin has successfully achieved the construction of nanoscale bamboo shoot structures. The nanoscale bamboo shoots on the substrates were characterized by atomic force microscopy (AFM), UV-vis spectra, and X-ray diffraction (XRD) measurements. The uneven and rigid nanoscale structure has been used as a stamp for constructing bamboo shoot structures of fullerene.
One-dimensional hydrodynamic simulation of high energy density experiments
NASA Astrophysics Data System (ADS)
Grinenko, A.
2009-07-01
A new one-dimensional hydrodynamic code for simulation of experiments involving the creation of high energy density in matter by means of laser or heavy ion beam irradiation is described. The code uses well-tested second order Lagrangian scheme in combination with the flux-limited van Leer convection algorithm for re-mapping to an arbitrary grid. Simple test cases with self-similar solutions are examined. Finally, the heating of solid targets by lasers and ions beams is investigated as examples.
Polarization hydrodynamics in a one-dimensional polariton condensate
NASA Astrophysics Data System (ADS)
Larré, P.-É.; Pavloff, N.; Kamchatnov, A. M.
2013-12-01
We study the hydrodynamics of a nonresonantly pumped polariton condensate in a quasi-one-dimensional quantum wire taking into account the spin degree of freedom. We clarify the relevance of the Landau criterion for superfluidity in this dissipative two-component system. Two Cherenkov-like critical velocities are identified corresponding to the opening of different channels of radiation: one of (damped) density fluctuations and another of (weakly damped) polarization fluctuations. We determine the drag force exerted onto an external obstacle and propose experimentally measurable consequences of the specific features of the fluctuations of polarization.
Absolute negative mobility in a one-dimensional overdamped system
NASA Astrophysics Data System (ADS)
Chen, Ru-Yin; Nie, Lin-Ru; Pan, Wan-Li; Zhang, Jian-Qiang
2015-10-01
A one-dimensional overdamped system consisting of a symmetric periodic potential, a constant bias force and a trichotomous noise was investigated. In the frame of master equations, we derived analytical expression of its current. By means of numerical calculations, the results indicate that the current first increases, then decreases and finally increases with the bias force increasing, i.e., an absolute negative mobility (ANM) phenomenon. Our further investigations presented dependence of the ANM phenomenon on parameters of the noise. Its intrinsic physical mechanism was also open up, and a minimal model with ANM phenomenon is demonstrated.
One-dimensional neutron imager for the Sandia Z facility.
Fittinghoff, David N; Bower, Dan E; Hollaway, James R; Jacoby, Barry A; Weiss, Paul B; Buckles, Robert A; Sammons, Timothy J; McPherson, Leroy A; Ruiz, Carlos L; Chandler, Gordon A; Torres, José A; Leeper, Ramon J; Cooper, Gary W; Nelson, Alan J
2008-10-01
A multiinstitution collaboration is developing a neutron imaging system for the Sandia Z facility. The initial system design is for slit aperture imaging system capable of obtaining a one-dimensional image of a 2.45 MeV source producing 5x10(12) neutrons with a resolution of 320 microm along the axial dimension of the plasma, but the design being developed can be modified for two-dimensional imaging and imaging of DT neutrons with other resolutions. This system will allow us to understand the spatial production of neutrons in the plasmas produced at the Z facility.
Quantum Simulations of One-Dimensional Nanostructures under Arbitrary Deformations
NASA Astrophysics Data System (ADS)
Koskinen, Pekka
2016-09-01
A powerful technique is introduced for simulating mechanical and electromechanical properties of one-dimensional nanostructures under arbitrary combinations of bending, twisting, and stretching. The technique is based on an unconventional control of periodic symmetry which eliminates artifacts due to deformation constraints and quantum finite-size effects and allows transparent electronic-structure analysis. Via density-functional tight-binding implementation, the technique demonstrates its utility by predicting nonlinear electromechanical properties in carbon nanotubes and abrupt behavior in the structural yielding of Au7 and Mo6 S6 nanowires. The technique drives simulations markedly closer to the realistic modeling of these slender nanostructures under experimental conditions.
Coherent Backscattering of Light Off One-Dimensional Atomic Strings
NASA Astrophysics Data System (ADS)
Sørensen, H. L.; Béguin, J.-B.; Kluge, K. W.; Iakoupov, I.; Sørensen, A. S.; Müller, J. H.; Polzik, E. S.; Appel, J.
2016-09-01
We present the first experimental realization of coherent Bragg scattering off a one-dimensional system—two strings of atoms strongly coupled to a single photonic mode—realized by trapping atoms in the evanescent field of a tapered optical fiber, which also guides the probe light. We report nearly 12% power reflection from strings containing only about 1000 cesium atoms, an enhancement of 2 orders of magnitude compared to reflection from randomly positioned atoms. This result paves the road towards collective strong coupling in 1D atom-photon systems. Our approach also allows for a straightforward fiber connection between several distant 1D atomic crystals.
Functional One-Dimensional Lipid Bilayers on Carbon Nanotube Templates
Artyukhin, A; Shestakov, A; Harper, J; Bakajin, O; Stroeve, P; Noy, A
2004-07-23
We present one-dimensional (1-D) lipid bilayer structures that integrate carbon nanotubes with a key biological environment-phospholipid membrane. Our structures consist of lipid bilayers wrapped around carbon nanotubes modified with a hydrophilic polymer cushion layer. Despite high bilayer curvature, the lipid membrane maintains its fluidity and can sustain repeated damage-recovery cycles. We also present the first evidence of spontaneous insertion of pore-forming proteins into 1-D lipid bilayers. These structures could lead to the development of new classes of biosensors and bioelectronic devices.
Scanned gate microscopy of a one-dimensional quantum dot.
Zhang, Lingfeng M; Fogler, Michael M
2006-10-01
We analyze electrostatic interaction between a sharp conducting tip and a thin one-dimensional wire, e.g., a carbon nanotube, in a scanned gate microscopy (SGM) experiment. The problem is analytically tractable if the wire resides on a thin dielectric substrate above a metallic backgate. The characteristic spatial scale of the electrostatic coupling to the tip is equal to its height above the substrate. Numerical simulations indicate that imaging of individual electrons by SGM is possible once the mean electron separation exceeds this scale (typically, a few tens of nm). Differences between weakly and strongly invasive SGM regimes are pointed out.
Numerical Simulations of One-dimensional Microstructure Dynamics
Berezovski, M.; Berezovski, A.; Engelbrecht, J.
2010-05-21
Results of numerical simulations of one-dimensional wave propagation in microstructured solids are presented and compared with the corresponding results of wave propagation in given layered media. A linear microstructure model based on Mindlin theory is adopted and represented in the framework of the internal variable theory. Fully coupled systems of equations for macro-motion and microstructure evolution are rewritten in the form of conservation laws. A modification of wave propagation algorithm is used for numerical calculations. It is shown how the initial microstructure model can be improved in order to match the results obtained by both approaches.
Dislocation-mediated melting of one-dimensional Rydberg crystals
Sela, Eran; Garst, Markus; Punk, Matthias
2011-08-15
We consider cold Rydberg atoms in a one-dimensional optical lattice in the Mott regime with a single atom per site at zero temperature. An external laser drive with Rabi frequency {Omega} and laser detuning {Delta} creates Rydberg excitations whose dynamics is governed by an effective spin-chain model with (quasi) long-range interactions. This system possesses intrinsically a large degree of frustration resulting in a ground-state phase diagram in the ({Delta},{Omega}) plane with a rich topology. As a function of {Delta}, the Rydberg blockade effect gives rise to a series of crystalline phases commensurate with the optical lattice that form a so-called devil's staircase. The Rabi frequency {Omega}, on the other hand, creates quantum fluctuations that eventually lead to a quantum melting of the crystalline states. Upon increasing {Omega}, we find that generically a commensurate-incommensurate transition to a floating Rydberg crystal that supports gapless phonon excitations occurs first. For even larger {Omega}, dislocations within the floating Rydberg crystal start to proliferate and a second, Kosterlitz-Thouless-Nelson-Halperin-Young dislocation-mediated melting transition finally destroys the crystalline arrangement of Rydberg excitations. This latter melting transition is generic for one-dimensional Rydberg crystals and persists even in the absence of an optical lattice. The floating phase and the concomitant transitions can, in principle, be detected by Bragg scattering of light.
Optical parametric oscillation in one-dimensional microcavities
NASA Astrophysics Data System (ADS)
Lecomte, Timothée; Ardizzone, Vincenzo; Abbarchi, Marco; Diederichs, Carole; Miard, Audrey; Lemaitre, Aristide; Sagnes, Isabelle; Senellart, Pascale; Bloch, Jacqueline; Delalande, Claude; Tignon, Jerome; Roussignol, Philippe
2013-04-01
We present a comprehensive investigation of optical parametric oscillation in resonantly excited one-dimensional semiconductor microcavities with embedded quantum wells. Such solid-state structures feature a fine control over light-matter coupling and produce a photonic/polaritonic mode fan that is exploited for the efficient emission of parametric beams. We implement an energy-degenerate optical parametric oscillator with balanced signal and idler intensities via a polarization-inverting mechanism. In this paper, we (i) precisely review the multimode photonic/polaritonic structure of individual emitters, (ii) provide a thorough comparison between experiment and theory, focusing on the power and the threshold dependence on the exciton-photon detuning, (iii) discuss the influence of inhomogeneous broadening of the excitonic transition and finite size, and (iv) find that a large exciton-photon detuning is a key parameter to reach a high output power and a high conversion efficiency. Our study highlights the predictive character of the polariton interaction theory and the flexibility of one-dimensional semiconductor microcavities as a platform to study parametric phenomena.
One dimensional global and local solution for ICRF heating
Wang, C.Y.; Batchelor, D.B.; Jaeger, E.F.; Carter, M.D.
1995-02-01
A numerical code GLOSI [Global and Local One-dimensional Solution for Ion cyclotron range of frequencies (ICRF) heating] is developed to solve one-dimensional wave equations resulting from the use of radio frequency (RF) waves to heat plasmas. The code uses a finite difference method. Due to its numerical stability, the code can be used to find both global and local solutions when imposed with appropriate boundary conditions. Three types of boundary conditions are introduced to describe wave scattering, antenna wave excitation, and fixed tangential wave magnetic field. The scattering boundary conditions are especially useful for local solutions. The antenna wave excitation boundary conditions can be used to excite fast and slow waves in a plasma. The tangential magnetic field boundary conditions are used to calculate impedance matrices, which describe plasma and antenna coupling and can be used by an antenna code to calculate antenna loading. These three types of boundary conditions can also be combined to describe various physical situations in RF plasma heating. The code also includes plasma thermal effects and calculates collisionless power absorption and kinetic energy flux. The plasma current density is approximated by a second-order Larmor radius expansion, which results in a sixth-order ordinary differential equation.
Magnetic Stimulation of One-Dimensional Neuronal Cultures
Rotem, Assaf; Moses, Elisha
2008-01-01
Transcranial magnetic stimulation is a remarkable tool for neuroscience research, with a multitude of diagnostic and therapeutic applications. Surprisingly, application of the same magnetic stimulation directly to neurons that are dissected from the brain and grown in vitro was not reported to activate them to date. Here we report that central nervous system neurons patterned on large enough one-dimensional rings can be magnetically stimulated in vitro. In contrast, two-dimensional cultures with comparable size do not respond to excitation. This happens because the one-dimensional pattern enforces an ordering of the axons along the ring, which is designed to follow the lines of the magnetically induced electric field. A small group of sensitive (i.e., initiating) neurons respond even when the network is disconnected, and are presumed to excite the entire network when it is connected. This implies that morphological and electrophysiological properties of single neurons are crucial for magnetic stimulation. We conjecture that the existence of a select group of neurons with higher sensitivity may occur in the brain in vivo as well, with consequences for transcranial magnetic stimulation. PMID:18326634
Majorana fermion exchange in quasi-one-dimensional networks
NASA Astrophysics Data System (ADS)
Clarke, David J.; Sau, Jay D.; Tewari, Sumanta
2011-07-01
Heterostructures of spin-orbit coupled materials with s-wave superconductors are thought to be capable of supporting zero-energy Majorana bound states. Such excitations are known to obey non-Abelian statistics in two dimensions, and are thus relevant to topological quantum computation (TQC). In a one-dimensional system, Majorana states are localized to phase boundaries. In order to bypass the constraints of one dimension, a wire network may be created, allowing the exchange of Majoranas by way of junctions in the network. Alicea have proposed such a network as a platform for TQC, showing that the Majorana bound states obey non-Abelian exchange statistics even in quasi-one-dimensional systems. Here we show that the particular realization of non-Abelian statistics produced in a Majorana wire network is highly dependent on the local properties of individual wire junctions. For a simply connected network, the possible realizations can be characterized by the chirality of individual junctions. There is in general no requirement for junction chiralities to remain consistent across a wire network. We show how the chiralities of different junctions may be compared experimentally and discuss the implications for TQC in Majorana wire networks.
Hydrogen peroxide stabilization in one-dimensional flow columns.
Schmidt, Jeremy T; Ahmad, Mushtaque; Teel, Amy L; Watts, Richard J
2011-09-25
Rapid hydrogen peroxide decomposition is the primary limitation of catalyzed H(2)O(2) propagations in situ chemical oxidation (CHP ISCO) remediation of the subsurface. Two stabilizers of hydrogen peroxide, citrate and phytate, were investigated for their effectiveness in one-dimensional columns of iron oxide-coated and manganese oxide-coated sand. Hydrogen peroxide (5%) with and without 25 mM citrate or phytate was applied to the columns and samples were collected at 8 ports spaced 13 cm apart. Citrate was not an effective stabilizer for hydrogen peroxide in iron-coated sand; however, phytate was highly effective, increasing hydrogen peroxide residuals two orders of magnitude over unstabilized hydrogen peroxide. Both citrate and phytate were effective stabilizers for manganese-coated sand, increasing hydrogen peroxide residuals by four-fold over unstabilized hydrogen peroxide. Phytate and citrate did not degrade and were not retarded in the sand columns; furthermore, the addition of the stabilizers increased column flow rates relative to unstabilized columns. These results demonstrate that citrate and phytate are effective stabilizers of hydrogen peroxide under the dynamic conditions of one-dimensional columns, and suggest that citrate and phytate can be added to hydrogen peroxide before injection to the subsurface as an effective means for increasing the radius of influence of CHP ISCO.
Hydrogen peroxide stabilization in one-dimensional flow columns
NASA Astrophysics Data System (ADS)
Schmidt, Jeremy T.; Ahmad, Mushtaque; Teel, Amy L.; Watts, Richard J.
2011-09-01
Rapid hydrogen peroxide decomposition is the primary limitation of catalyzed H 2O 2 propagations in situ chemical oxidation (CHP ISCO) remediation of the subsurface. Two stabilizers of hydrogen peroxide, citrate and phytate, were investigated for their effectiveness in one-dimensional columns of iron oxide-coated and manganese oxide-coated sand. Hydrogen peroxide (5%) with and without 25 mM citrate or phytate was applied to the columns and samples were collected at 8 ports spaced 13 cm apart. Citrate was not an effective stabilizer for hydrogen peroxide in iron-coated sand; however, phytate was highly effective, increasing hydrogen peroxide residuals two orders of magnitude over unstabilized hydrogen peroxide. Both citrate and phytate were effective stabilizers for manganese-coated sand, increasing hydrogen peroxide residuals by four-fold over unstabilized hydrogen peroxide. Phytate and citrate did not degrade and were not retarded in the sand columns; furthermore, the addition of the stabilizers increased column flow rates relative to unstabilized columns. These results demonstrate that citrate and phytate are effective stabilizers of hydrogen peroxide under the dynamic conditions of one-dimensional columns, and suggest that citrate and phytate can be added to hydrogen peroxide before injection to the subsurface as an effective means for increasing the radius of influence of CHP ISCO.
Stopping time of a one-dimensional bounded quantum walk
NASA Astrophysics Data System (ADS)
Luo, Hao; Zhan, Xiang; Zhang, Peng; Xue, Peng
2016-11-01
The stopping time of a one-dimensional bounded classical random walk (RW) is defined as the number of steps taken by a random walker to arrive at a fixed boundary for the first time. A quantum walk (QW) is a non-trivial generalization of RW, and has attracted a great deal of interest from researchers working in quantum physics and quantum information. In this paper, we develop a method to calculate the stopping time for a one-dimensional QW. Using our method, we further compare the properties of stopping time for QW and RW. We find that the mean value of the stopping time is the same for both of these problems. However, for short times, the probability for a walker performing a QW to arrive at the boundary is larger than that for a RW. This means that, although the mean stopping time of a quantum and classical walker are the same, the quantum walker has a greater probability of arriving at the boundary earlier than the classical walker. Project supported by the National Natural Science Foundation of China (Grant Nos. 11222430, 11434011, and 11474049), the National Basic Research Program of China (Grant No. 2012CB922104), the Fundamental Research Funds for the Central Universities, China, and the Research Funds of Renmin University of China (Grant No. 16XNLQ03).
EVALUATION OF THE STATE-OF-THE-ART CONTAMINATED SEDIMENT TRANSPORT AND FATE MODELING SYSTEM
Modeling approaches for evaluating the transport and fate of sediment and associated contaminants are briefly reviewed. The main emphasis is on: 1) the application of EFDC (Environmental Fluid Dynamics Code), the state-of-the-art contaminated sediment transport and fate public do...
Melting of Wigner Crystal on Helium in Quasi-One-Dimensional Geometry
NASA Astrophysics Data System (ADS)
Ikegami, Hiroki; Akimoto, Hikota; Kono, Kimitoshi
2015-05-01
We discuss melting of a Wigner crystal formed on a free surface of superfluid He, in quasi-one-dimensional (Q1D) channels of width between 5 and 15 m. We reexamine our previous transport data (Ikegami et al. in Phys Rev B 82:201104(R), 2010), in particular, by estimating the number of electrons across the channel in a more accurate way with the aid of numerical calculations of distributions of the electrons in the channels. The results of reexamination indicate more convincingly that the melting of the Wigner crystal in the Q1D geometry is understood by the finite size effect on the Kosterlitz-Thouless-Halperin-Nelson-Young melting process. We also present technical details of the transport measurements of the electrons in a Q1D geometry, including a fabrication method of devices used for the transport measurements, numerical simulations of response of the devices, and a procedure for analyzing transport data.
A Sectored-One-Dimensional Model for Simulating Combustion Instabilities in Premix Combustors
NASA Technical Reports Server (NTRS)
Paxson, Daniel E.
1999-01-01
A one-dimensional, CFD based combustor simulation has been developed that exhibits self-excited, thermoacoustic oscillations in premixed combustor geometries that typically have large, abrupt changes in cross sectional area. The combustor geometry is approximated by dividing it into a finite number of one-dimensional sectors. Within each sector, the equations of motion are integrated numerically, along with a species transport and a reaction equation. Across the sectors, mass and energy are conserved, and momentum loss is prescribed using appropriately compatible boundary conditions that account for the area change. The resulting simulation and associated boundary conditions essentially represent a one-dimensional, multi-block technique. Details of the simulation code are presented herein. Results are then shown comparing experimentally observed and simulated operation of a particular combustor rig that exhibited different instabilities at different operating points. It will be shown that the simulation closely matched the rig data in oscillation amplitudes, frequencies, and operating points at which the instabilities occurred. Finally, advantages and limitations of the simulation technique are discussed.
Modeling uranium transport in acidic contaminated groundwater with base addition.
Zhang, Fan; Luo, Wensui; Parker, Jack C; Brooks, Scott C; Watson, David B; Jardine, Philip M; Gu, Baohua
2011-06-15
This study investigates reactive transport modeling in a column of uranium(VI)-contaminated sediments with base additions in the circulating influent. The groundwater and sediment exhibit oxic conditions with low pH, high concentrations of NO(3)(-), SO(4)(2-), U and various metal cations. Preliminary batch experiments indicate that additions of strong base induce rapid immobilization of U for this material. In the column experiment that is the focus of the present study, effluent groundwater was titrated with NaOH solution in an inflow reservoir before reinjection to gradually increase the solution pH in the column. An equilibrium hydrolysis, precipitation and ion exchange reaction model developed through simulation of the preliminary batch titration experiments predicted faster reduction of aqueous Al than observed in the column experiment. The model was therefore modified to consider reaction kinetics for the precipitation and dissolution processes which are the major mechanism for Al immobilization. The combined kinetic and equilibrium reaction model adequately described variations in pH, aqueous concentrations of metal cations (Al, Ca, Mg, Sr, Mn, Ni, Co), sulfate and U(VI). The experimental and modeling results indicate that U(VI) can be effectively sequestered with controlled base addition due to sorption by slowly precipitated Al with pH-dependent surface charge. The model may prove useful to predict field-scale U(VI) sequestration and remediation effectiveness.
Spin accumulation on a one-dimensional mesoscopic Rashba ring.
Zhang, Zhi-Yong
2006-04-26
The nonequilibrium spin accumulation on a one-dimensional (1D) mesoscopic Rashba ring is investigated with unpolarized current injected through ideal leads. Due to the Rashba spin-orbit (SO) coupling and back-scattering at the interfaces between the leads and the ring, a beating pattern is formed in the fast oscillation of spin accumulation. If every beating period is complete, a plateau is formed, where the variation of spin accumulation with the external voltage is slow, but if new incomplete periods emerge in the envelope function, a transitional region appears. This plateau structure and the beating pattern are related to the tunnelling through spin-dependent resonant states. Because of the Aharonov-Casher (AC) effect, the average spin accumulation oscillates quasi-periodically with the Rashba SO coupling and has a series of zeros. In some situations, the direction of the average spin accumulation can be reversed by the external voltage in this 1D Rashba ring.
Strongly Interacting One-dimensional Systems with Small Mass Imbalance
NASA Astrophysics Data System (ADS)
Volosniev, Artem G.
2017-03-01
We study a strongly interacting system of N identical bosons and one impurity in a one-dimensional trap. First, we assume that the particles have identical masses and analyze the corresponding set-up. After that, we study the influence of a small mass asymmetry on our analysis. In particular, we discuss how the structure of the wave function and the degeneracy in the impenetrable regime depend on the mass ratio and the shape of the trapping potential. To illustrate our findings, we consider a four-body system in a box and in an oscillator. We show that in the former case the system has the smallest energy when a heavy (light) impurity is close to the edge (center) of the trap. And we demonstrate that the opposite is true in the latter case.
Medical image denoising using one-dimensional singularity function model.
Luo, Jianhua; Zhu, Yuemin; Hiba, Bassem
2010-03-01
A novel denoising approach is proposed that is based on a spectral data substitution mechanism through using a mathematical model of one-dimensional singularity function analysis (1-D SFA). The method consists in dividing the complete spectral domain of the noisy signal into two subsets: the preserved set where the spectral data are kept unchanged, and the substitution set where the original spectral data having lower signal-to-noise ratio (SNR) are replaced by those reconstructed using the 1-D SFA model. The preserved set containing original spectral data is determined according to the SNR of the spectrum. The singular points and singularity degrees in the 1-D SFA model are obtained through calculating finite difference of the noisy signal. The theoretical formulation and experimental results demonstrated that the proposed method allows more efficient denoising while introducing less distortion, and presents significant improvement over conventional denoising methods.
Experiment and simulation on one-dimensional plasma photonic crystals
Zhang, Lin; Ouyang, Ji-Ting
2014-10-15
The transmission characteristics of microwaves passing through one-dimensional plasma photonic crystals (PPCs) have been investigated by experiment and simulation. The PPCs were formed by a series of discharge tubes filled with argon at 5 Torr that the plasma density in tubes can be varied by adjusting the discharge current. The transmittance of X-band microwaves through the crystal structure was measured under different discharge currents and geometrical parameters. The finite-different time-domain method was employed to analyze the detailed properties of the microwaves propagation. The results show that there exist bandgaps when the plasma is turned on. The properties of bandgaps depend on the plasma density and the geometrical parameters of the PPCs structure. The PPCs can perform as dynamical band-stop filter to control the transmission of microwaves within a wide frequency range.
One-Dimensional Time to Explosion (Thermal Sensitivity) of ANPZ
Hsu, P.; Hust, G.; McClelland, M.; Gresshoff, M.
2014-11-12
Incidents caused by fire and combat operations can heat energetic materials that may lead to thermal explosion and result in structural damage and casualty. Some explosives may thermally explode at fairly low temperatures (< 100 C) and the violence from thermal explosion may cause a significant damage. Thus it is important to understand the response of energetic materials to thermal insults. The One Dimensional Time to Explosion (ODTX) system at the Lawrence Livermore National Laboratory has been used for decades to measure times to explosion, threshold thermal explosion temperature, and determine kinetic parameters of energetic materials. Samples of different configurations (pressed part, powder, paste, and liquid) can be tested in the system. The ODTX testing can also provide useful data for assessing the thermal explosion violence of energetic materials. This report summarizes the recent ODTX experimental data and modeling results for 2,6-diamino-3,5-dintropyrazine (ANPZ).
Strongly-Refractive One-Dimensional Photonic Crystal Prisms
NASA Technical Reports Server (NTRS)
Ting, David Z. (Inventor)
2004-01-01
One-dimensional (1D) photonic crystal prisms can separate a beam of polychromatic electromagnetic waves into constituent wavelength components and can utilize unconventional refraction properties for wavelength dispersion over significant portions of an entire photonic band rather than just near the band edges outside the photonic band gaps. Using a ID photonic crystal simplifies the design and fabrication process and allows the use of larger feature sizes. The prism geometry broadens the useful wavelength range, enables better optical transmission, and exhibits angular dependence on wavelength with reduced non-linearity. The properties of the 1 D photonic crystal prism can be tuned by varying design parameters such as incidence angle, exit surface angle, and layer widths. The ID photonic crystal prism can be fabricated in a planar process, and can be used as optical integrated circuit elements.
Characterizing high- n quasi-one-dimensional strontium Rydberg atoms
NASA Astrophysics Data System (ADS)
Hiller, Moritz; Yoshida, Shuhei; Burgdörfer, Joachim; Ye, Shuzhen; Zhang, Xinyue; Dunning, F. Barry
2014-05-01
The production of high- n, n ~ 300 , quasi-one-dimensional strontium Rydberg atoms by two-photon excitation of selected extreme Stark states in the presence of a weak dc field is examined using a crossed laser-atom beam geometry. The polarization of the product states is probed using three independent techniques which are analyzed with the aid of classical-trajectory Monte Carlo simulations that employ initial ensembles based on quantum calculations using a two-active-electron model. Comparisons between theory and experiment demonstrate that the product states have large dipole moments, ~ 1 . 0 - 1 . 2n2 a . u . and that they can be engineered using pulsed electric fields to create a wide variety of target states. Research supported by the NSF, the Robert A Welch Foundation, and the FWF (Austria).
Enhanced multiple exciton generation in quasi-one-dimensional semiconductors.
Cunningham, Paul D; Boercker, Janice E; Foos, Edward E; Lumb, Matthew P; Smith, Anthony R; Tischler, Joseph G; Melinger, Joseph S
2011-08-10
The creation of a single electron-hole pair (i.e., exciton) per incident photon is a fundamental limitation for current optoelectronic devices including photodetectors and photovoltaic cells. The prospect of multiple exciton generation per incident photon is of great interest to fundamental science and the improvement of solar cell technology. Multiple exciton generation is known to occur in semiconductor nanostructures with increased efficiency and reduced threshold energy compared to their bulk counterparts. Here we report a significant enhancement of multiple exciton generation in PbSe quasi-one-dimensional semiconductors (nanorods) over zero-dimensional nanostructures (nanocrystals), characterized by a 2-fold increase in efficiency and reduction of the threshold energy to (2.23 ± 0.03)E(g), which approaches the theoretical limit of 2E(g). Photovoltaic cells based on PbSe nanorods are capable of improved power conversion efficiencies, in particular when operated in conjunction with solar concentrators.
Equilibrium properties of a one-dimensional kinetic system.
NASA Technical Reports Server (NTRS)
Williams, J. H.; Joyce, G.
1973-01-01
One-dimensional systems of N = 500 and 250 particles in equilibrium are numerically simulated utilizing the method of molecular dynamics. Periodic boundary conditions are imposed. The classical two-body interaction potential is short range, repulsive and has a corresponding finite force. The equations of state are determined for densities both less and greater than one. Corresponding theoretical isochores are determined from models based on nearest-neighbor interactions and on a truncated virial expansion, and a comparison is made with the experimental isochores. Time independent radial distributions are constructed numerically and discussed. A change of state from a solidlike state to a fluid-gas state based on the penetrability of the particles is predicted. The transition temperatures are estimated from the radial distribution functions and the nearest-neighbor model. Self-diffusion is observed and the corresponding constants are determined from the velocity autocorrelation functions.
Solution of a one-dimensional ablation model
NASA Astrophysics Data System (ADS)
Rupertijunior, Nerbe Jose
1991-11-01
Ablation in multilayered one-dimensional media is studied. A finite element technique using a Streamline Upwind/Petrov-Galerkin (SU/PG) formulation is employed with a moving mesh which adapts itself to the moving boundary at each time step. The SU/PG formulation is used to avoid oscillations caused by first order derivatives in the energy equation. Ablation problems with time-dependent heat fluxes and a typical example in aerospace thermal protection applications are solved. Critical comparisons are made with finite differences results recently obtained through the control volume approach with exponential differencing. The generalized integral transform technique (GITT) is used as an alternative solution to ablation in multilayered media and to validate the results obtained by the finite element method. The eigenvalues needed in the GITT solution are determined simultaneously with the tansformed temperatures by rewriting the associated transcedental equations into ordinary differential equations.
Switching synchronization in one-dimensional memristive networks
NASA Astrophysics Data System (ADS)
Slipko, Valeriy A.; Shumovskyi, Mykola; Pershin, Yuriy V.
2015-11-01
We report on a switching synchronization phenomenon in one-dimensional memristive networks, which occurs when several memristive systems with different switching constants are switched from the high- to low-resistance state. Our numerical simulations show that such a collective behavior is especially pronounced when the applied voltage slightly exceeds the combined threshold voltage of memristive systems. Moreover, a finite increase in the network switching time is found compared to the average switching time of individual systems. An analytical model is presented to explain our observations. Using this model, we have derived asymptotic expressions for memory resistances at short and long times, which are in excellent agreement with results of our numerical simulations.
One dimensional simulations of transients in heavy ion injectors
Barnard, J.J.; Caporaso, G.J.; Yu, S.S.; Eylon, E.
1993-05-11
A fast-running time-dependent one-dimensional particle code has been developed to simulate transients in both electrostatic quadrupole and electrostatic column heavy-ion injectors. Two-dimensional effects are incorporated through the use of an approximation to the transverse part of the Laplacian operator. Longitudinal electric fields are solved on a mesh. An external circuit is coupled to the column, and the effect of the beam on the circuit is modeled. Transients such as initial current spikes, space-charge de-bunching, and beam loading of the circuit, are simulated. Future directions for the code include introduction of envelope and centroid equations to provide beam radius and displacement information and the modeling of secondary electron currents arising from beam-spill.
Magnons in one-dimensional k-component Fibonacci structures
Costa, C. H.; Vasconcelos, M. S.
2014-05-07
We have studied the magnon transmission through of one-dimensional magnonic k-component Fibonacci structures, where k different materials are arranged in accordance with the following substitution rule: S{sub n}{sup (k)}=S{sub n−1}{sup (k)}S{sub n−k}{sup (k)} (n≥k=0,1,2,…), where S{sub n}{sup (k)} is the nth stage of the sequence. The calculations were carried out in exchange dominated regime within the framework of the Heisenberg model and taking into account the RPA approximation. We have considered multilayers composed of simple cubic spin-S Heisenberg ferromagnets, and, by using the powerful transfer-matrix method, the spin wave transmission is obtained. It is demonstrated that the transmission coefficient has a rich and interesting magnonic pass- and stop-bands structures, which depends on the frequency of magnons and the k values.
A Reduced Order, One Dimensional Model of Joint Response
DOHNER,JEFFREY L.
2000-11-06
As a joint is loaded, the tangent stiffness of the joint reduces due to slip at interfaces. This stiffness reduction continues until the direction of the applied load is reversed or the total interface slips. Total interface slippage in joints is called macro-slip. For joints not undergoing macro-slip, when load reversal occurs the tangent stiffness immediately rebounds to its maximum value. This occurs due to stiction effects at the interface. Thus, for periodic loads, a softening and rebound hardening cycle is produced which defines a hysteretic, energy absorbing trajectory. For many jointed sub-structures, this hysteretic trajectory can be approximated using simple polynomial representations. This allows for complex joint substructures to be represented using simple non-linear models. In this paper a simple one dimensional model is discussed.
CHARGE ORDER FLUCTUATIONS IN ONE-DIMENSIONAL SILICIDES
Zeng, Changgan; Kent, P. R.C.; Kim, Tae-Hwan; Li, An-Ping; Weitering, Hanno H.
2014-01-01
Metallic nanowires are of great interest as interconnects in future nanoelectronic circuits. They also represent important systems for understanding the complexity of electronic interactions and conductivity in one-dimension. We have fabricated exceptionally long and uniform YSi2 nanowires via self-assembly of yttrium atoms on Si(001). The thinnest wires represent one of the closest realizations of the isolated Peierls chain, exhibiting van-Hove type singularities in the one-dimensional density of states and charge order fluctuations below 150 K. The structure of the wire was determined though a detailed comparison of scanning tunneling microscopy data and first-principles calculations. Sporadic broadenings of the wires’ cross section imply the existence of a novel metal-semiconductor junction whose electronic properties are governed by the finite-size- and temperature-scaling of the charge ordering correlation. PMID:18552849
Loschmidt echo in one-dimensional interacting Bose gases
Lelas, K.; Seva, T.; Buljan, H.
2011-12-15
We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.
Chaos in a one-dimensional compressible flow.
Gerig, Austin; Hübler, Alfred
2007-04-01
We study the dynamics of a one-dimensional discrete flow with open boundaries--a series of moving point particles connected by ideal springs. These particles flow towards an inlet at constant velocity, pass into a region where they are free to move according to their nearest neighbor interactions, and then pass an outlet where they travel with a sinusoidally varying velocity. As the amplitude of the outlet oscillations is increased, we find that the resident time of particles in the chamber follows a bifurcating (Feigenbaum) route to chaos. This irregular dynamics may be related to the complex behavior of many particle discrete flows or is possibly a low-dimensional analogue of nonstationary flow in continuous systems.
Majorana fermion exchange in strictly one-dimensional structures
NASA Astrophysics Data System (ADS)
Chiu, Ching-Kai; Vazifeh, M. M.; Franz, M.
2015-04-01
It is generally thought that the adiabatic exchange of two identical particles is impossible in one spatial dimension. Here we describe a simple protocol that permits the adiabatic exchange of two Majorana fermions in a one-dimensional topological superconductor wire. The exchange relies on the concept of “Majorana shuttle” whereby a π domain wall in the superconducting order parameter which hosts a pair of ancillary majoranas delivers one zero mode across the wire while the other one tunnels in the opposite direction. The method requires some tuning of parameters and does not, therefore, enjoy full topological protection. The resulting exchange statistics, however, remain non-Abelian for a wide range of parameters that characterize the exchange.
NASA Astrophysics Data System (ADS)
Vidal, A. J.; Astrakharchik, G. E.; Vranješ Markić, L.; Boronat, J.
2016-05-01
The ground-state properties of one-dimensional electron-spin-polarized hydrogen 1H, deuterium 2H, and tritium 3H are obtained by means of quantum Monte Carlo methods. The equations of state of the three isotopes are calculated for a wide range of linear densities. The pair correlation function and the static structure factor are obtained and interpreted within the framework of the Luttinger liquid theory. We report the density dependence of the Luttinger parameter and use it to identify different physical regimes: Bogoliubov Bose gas, super-Tonks-Girardeau gas, and quasi-crystal regimes for bosons; repulsive, attractive Fermi gas, and quasi-crystal regimes for fermions. We find that the tritium isotope is the one with the richest behavior. Our results show unambiguously the relevant role of the isotope mass in the properties of this quantum system.
Capillary condensation in one-dimensional irregular confinement
NASA Astrophysics Data System (ADS)
Handford, Thomas P.; Pérez-Reche, Francisco J.; Taraskin, Sergei N.
2013-07-01
A lattice-gas model with heterogeneity is developed for the description of fluid condensation in finite sized one-dimensional pores of arbitrary shape. Mapping to the random-field Ising model allows an exact solution of the model to be obtained at zero-temperature, reproducing the experimentally observed dependence of the amount of fluid adsorbed in the pore on external pressure. It is demonstrated that the disorder controls the sorption for long pores and can result in H2-type hysteresis. Finite-temperature Metropolis dynamics simulations support analytical findings in the limit of low temperatures. The proposed framework is viewed as a fundamental building block of the theory of capillary condensation necessary for reliable structural analysis of complex porous media from adsorption-desorption data.
Erosion by a one-dimensional random walk
NASA Astrophysics Data System (ADS)
Chisholm, Rebecca H.; Hughes, Barry D.; Landman, Kerry A.
2014-08-01
We consider a model introduced by Baker et al. [Phys. Rev. E 88, 042113 (2013), 10.1103/PhysRevE.88.042113] of a single lattice random walker moving on a domain of allowed sites, surrounded by blocked sites. The walker enlarges the allowed domain by eroding the boundary at its random encounters with blocked boundary sites: attempts to step onto blocked sites succeed with a given probability and convert these sites to allowed sites. The model interpolates continuously between the Pólya random walker on the one-dimensional lattice and a "blind" walker who attempts freely, but always aborts, moves to blocked sites. We obtain some exact results about the walker's location and the rate of erosion.
Critical conductance of a one-dimensional doped Mott insulator
NASA Astrophysics Data System (ADS)
Garst, M.; Novikov, D. S.; Stern, Ady; Glazman, L. I.
2008-01-01
We consider the two-terminal conductance of a one-dimensional Mott insulator undergoing the commensurate-incommensurate quantum phase transition to a conducting state. We treat the leads as Luttinger liquids. At a specific value of compressibility of the leads, corresponding to the Luther-Emery point, the conductance can be described in terms of the free propagation of noninteracting fermions with charge e/2 . At that point, the temperature dependence of the conductance across the quantum phase transition is described by a Fermi function. The deviation from the Luther-Emery point in the leads changes the temperature dependence qualitatively. In the metallic state, the low-temperature conductance is determined by the properties of the leads, and is described by the conventional Luttinger-liquid theory. In the insulating state, conductance occurs via activation of e/2 charges, and is independent of the Luttinger-liquid compressibility.
Quantum quench dynamics in analytically solvable one-dimensional models
NASA Astrophysics Data System (ADS)
Iucci, Anibal; Cazalilla, Miguel A.; Giamarchi, Thierry
2008-03-01
In connection with experiments in cold atomic systems, we consider the non-equilibrium dynamics of some analytically solvable one-dimensional systems which undergo a quantum quench. In this quench one or several of the parameters of the Hamiltonian of an interacting quantum system are changed over a very short time scale. In particular, we concentrate on the Luttinger model and the sine-Gordon model in the Luther-Emery point. For the latter, we show that the order parameter and the two-point correlation function relax in the long time limit to the values determined by a generalized Gibbs ensemble first discussed by J. T. Jaynes [Phys. Rev. 106, 620 (1957); 108, 171 (1957)], and recently conjectured by M. Rigol et.al. [Phys. Rev. Lett. 98, 050405 (2007)] to apply to the non-equilibrium dynamics of integrable systems.
Atom-Molecule Coherence in a One-Dimensional System
NASA Astrophysics Data System (ADS)
Citro, R.; Orignac, E.
2005-09-01
We study a model of one-dimensional fermionic atoms with a narrow Feshbach resonance that allows them to bind in pairs to form bosonic molecules. We show that at low energy, a coherence develops between the molecule and fermion Luttinger liquids. At the same time, a gap opens in the spin excitation spectrum. The coherence implies that the order parameters for the molecular Bose-Einstein condensation and the atomic BCS pairing become identical. Moreover, both bosonic and fermionic charge density wave correlations decay exponentially, in contrast with a usual Luttinger liquid. We exhibit a Luther-Emery point where the systems can be described in terms of noninteracting pseudofermions. At this point we discuss the threshold behavior of density-density response functions.
Configurational and energy landscape in one-dimensional Coulomb systems
NASA Astrophysics Data System (ADS)
Varela, Lucas; Téllez, Gabriel; Trizac, Emmanuel
2017-02-01
We study a one-dimensional Coulomb system, where two charged colloids are neutralized by a collection of point counterions, with global neutrality. With temperature being given, two situations are addressed: Either the colloids are kept at fixed positions (canonical ensemble) or the force acting on the colloids is fixed (isobaric-isothermal ensemble). The corresponding partition functions are worked out exactly, in view of determining which arrangement of counterions is optimal. How many counterions should be in the confined segment between the colloids? For the remaining ions outside, is there a left-right symmetry breakdown? We evidence a cascade of transitions as system size is varied in the canonical treatment or as pressure is increased in the isobaric formulation.
Configurational and energy landscape in one-dimensional Coulomb systems.
Varela, Lucas; Téllez, Gabriel; Trizac, Emmanuel
2017-02-01
We study a one-dimensional Coulomb system, where two charged colloids are neutralized by a collection of point counterions, with global neutrality. With temperature being given, two situations are addressed: Either the colloids are kept at fixed positions (canonical ensemble) or the force acting on the colloids is fixed (isobaric-isothermal ensemble). The corresponding partition functions are worked out exactly, in view of determining which arrangement of counterions is optimal. How many counterions should be in the confined segment between the colloids? For the remaining ions outside, is there a left-right symmetry breakdown? We evidence a cascade of transitions as system size is varied in the canonical treatment or as pressure is increased in the isobaric formulation.
Magnons in one-dimensional k-component Fibonacci structures
NASA Astrophysics Data System (ADS)
Costa, C. H.; Vasconcelos, M. S.
2014-05-01
We have studied the magnon transmission through of one-dimensional magnonic k-component Fibonacci structures, where k different materials are arranged in accordance with the following substitution rule: Sn(k)=Sn-1(k)Sn-k(k) (n ≥k=0,1,2,…), where Sn(k) is the nth stage of the sequence. The calculations were carried out in exchange dominated regime within the framework of the Heisenberg model and taking into account the RPA approximation. We have considered multilayers composed of simple cubic spin-S Heisenberg ferromagnets, and, by using the powerful transfer-matrix method, the spin wave transmission is obtained. It is demonstrated that the transmission coefficient has a rich and interesting magnonic pass- and stop-bands structures, which depends on the frequency of magnons and the k values.
One-dimensional three-body problem via symbolic dynamics.
Tanikawa, Kiyotaka; Mikkola, Seppo
2000-09-01
Symbolic dynamics is applied to the one-dimensional three-body problem with equal masses. The sequence of binary collisions along an orbit is expressed as a symbol sequence of two symbols. Based on the time reversibility of the problem and numerical data, inadmissible (i.e., unrealizable) sequences of collisions are systematically found. A graph for the transitions among various regions in the Poincare section is constructed. This graph is used to find an infinite number of periodic sequences, which implies an infinity of periodic orbits other than those accompanying a simple periodic orbit called the Schubart orbit. Finally, under reasonable assumptions on inadmissible sequences, we prove that the set of admissible symbol sequences forms a Cantor set. (c) 2000 American Institute of Physics.
Stepwise nanopore evolution in one-dimensional nanostructures.
Choi, Jang Wook; McDonough, James; Jeong, Sangmoo; Yoo, Jee Soo; Chan, Candace K; Cui, Yi
2010-04-14
We report that established simple lithium (Li) ion battery cycles can be used to produce nanopores inside various useful one-dimensional (1D) nanostructures such as zinc oxide, silicon, and silver nanowires. Moreover, porosities of these 1D nanomaterials can be controlled in a stepwise manner by the number of Li-battery cycles. Subsequent pore characterization at the end of each cycle allows us to obtain detailed snapshots of the distinct pore evolution properties in each material due to their different atomic diffusion rates and types of chemical bonds. Also, this stepwise characterization led us to the first observation of pore size increases during cycling, which can be interpreted as a similar phenomenon to Ostwald ripening in analogous nanoparticle cases. Finally, we take advantage of the unique combination of nanoporosity and 1D materials and demonstrate nanoporous silicon nanowires (poSiNWs) as excellent supercapacitor (SC) electrodes in high power operations compared to existing devices with activated carbon.
Crystallographic shear mechanisms in Rh one-dimensional oxides
NASA Astrophysics Data System (ADS)
Hernando, María; Boulahya, Khalid; Parras, Marina; González-Calbet, José M.
2005-02-01
Electron diffraction and high resolution electron microscopy have been used to characterize two new one-dimensional superstructures in the A sbnd Rh sbnd O system (A = Ca, Sr) related to the 2H-ABO 3-type. They are formed by the intergrowth of n A 3A'BO 6 blocks, showing the Sr 4RhO 6-type, with A 12A' 2B 8O 30 blocks, constituted by two A 3O 9 and two A 3A'O 6 layers alternating in the stacking sequence 1:1, leading to the A 27A' 7B 13O 60 ( n=5) and A 30A' 8B 14O 66 ( n=6) compositions. A crystallographic shear mechanism is proposed to describe the structural relationship between Sr 4RhO 6 (A 3A'BO 6-type) and the new superstructures.
One-dimensional hybrid nanostructures for heterogeneous photocatalysis and photoelectrocatalysis.
Xiao, Fang-Xing; Miao, Jianwei; Tao, Hua Bing; Hung, Sung-Fu; Wang, Hsin-Yi; Yang, Hong Bin; Chen, Jiazang; Chen, Rong; Liu, Bin
2015-05-13
Semiconductor-based photocatalysis and photoelectrocatalysis have received considerable attention as alternative approaches for solar energy harvesting and storage. The photocatalytic or photoelectrocatalytic performance of a semiconductor is closely related to the design of the semiconductor at the nanoscale. Among various nanostructures, one-dimensional (1D) nanostructured photocatalysts and photoelectrodes have attracted increasing interest owing to their unique optical, structural, and electronic advantages. In this article, a comprehensive review of the current research efforts towards the development of 1D semiconductor nanomaterials for heterogeneous photocatalysis and photoelectrocatalysis is provided and, in particular, a discussion of how to overcome the challenges for achieving full potential of 1D nanostructures is presented. It is anticipated that this review will afford enriched information on the rational exploration of the structural and electronic properties of 1D semiconductor nanostructures for achieving more efficient 1D nanostructure-based photocatalysts and photoelectrodes for high-efficiency solar energy conversion.
A radiating one-dimensional current sheet configuration
NASA Technical Reports Server (NTRS)
Pritchett, P. L.; Coroniti, F. V.
1993-01-01
The structure of the x-independent (one-dimensional) forced current sheet including a self consistent By component is investigated for the case of small normal field component, Bz/B0 much less than 1. A hybrid (kinetic ions, massless fluid electrons) simulation model is used to demonstrate that such a current sheet has a time-dependent structure which radiates incompressible Alfven waves with amplitude of the order of the asymptotic (lobe) field strength B0. The central density enhancement acts as the source of a propagating wavetrain in which Bx rotates into By and back again. One of the characteristic signatures of the radiating current sheet is the presence of a reversal in Bx (or By) without a corresponding increase in density.
One dimensional modeling of blood flow in large networks
NASA Astrophysics Data System (ADS)
Wang, Xiaofei; Lagree, Pierre-Yves; Fullana, Jose-Maria; Lorthois, Sylvie; Institut de Mecanique des Fluides de Toulouse Collaboration
2014-11-01
A fast and valid simulation of blood flow in large networks of vessels can be achieved with a one-dimensional viscoelastic model. In this paper, we developed a parallel code with this model and computed several networks: a circle of arteries, a human systemic network with 55 arteries and a vascular network of mouse kidney with more than one thousand segments. The numerical results were verified and the speedup of parallel computing was tested on multi-core computers. The evolution of pressure distributions in all the networks were visualized and we can see clearly the propagation patterns of the waves. This provides us a convenient tool to simulate blood flow in networks.
Entangling Qubits in a One-Dimensional Harmonic Oscillator
NASA Astrophysics Data System (ADS)
Owen, Edmund; Dean, Matthew; Barnes, Crispin
2012-02-01
We present a method for generating entanglement between qubits associated with a pair of particles interacting in a one-dimensional harmonic potential. By considering the effect of the interaction on the energy spectrum of the system, we show that, under certain approximations, a ``power-of-SWAP" operation is performed on the initial two-qubit quantum state without requiring any time-dependent control. Initialization errors and deviations from our approximation are shown to have a negligible effect on the final state. Using a GPU-accelerated iteration scheme to find numerical solutions to the two-particle time-dependent Schr"odinger equation, we demonstrate that it is possible to generate maximally entangled Bell states between the two qubits with high fidelity for a range of possible interaction potentials.
One-dimensional photonic crystals as selective back reflectors
NASA Astrophysics Data System (ADS)
Gondek, Ewa; Karasiński, Paweł
2013-06-01
Using the sol-gel technology and dip-coating method involving the deposition of silica layers and titania layers, we have fabricated symmetrical structures with one-dimensional photonic crystals on both sides of glass substrates. For the structure with five bilayers (SiO2/TiO2) we have obtained the maximum reflectance of 0.967 for the wavelength λr=493 nm and full width at half maximum of the main reflectance peak of FWHM=185 nm. The fabricated structures have been analyzed theoretically with the application of the transfer matrix 2×2 method, allowing for complex refraction indexes for the component layers. The paper presents the applied theoretical model and the discussion involving the calculated and experimental results. Good agreement between the calculation and experimental results has been obtained. The elaborated photonic structures can be applied in solar light concentrators for photovoltaic systems.
One-dimensional photonic crystal fishbone hybrid nanocavity with nanoposts
Lu, Tsan-Wen; Lin, Pin-Tso; Lee, Po-Tsung
2014-05-12
We propose and investigate a one-dimensional photonic crystal (PhC) fishbone (FB) hybrid nanocavity lying on silver substrate with a horizontal air slot. With very few PhC periods, the confined transverse-magnetic, TM{sub 10} hybrid mode concentrated within the air slot shows high quality factor over effective mode volume ratio larger than 10{sup 5}λ{sup −3}. Most importantly, this FB hybrid nanocavity allows formation of low-index nanoposts within the air slot without significantly affecting the mode properties. These nanoposts guarantee the structural stabilities under different environmental perturbations. Furthermore, capabilities of our proposed design in serving as optical sensors and tweezers for bio-sized nanoparticles are also investigated.
One-dimensional photonic crystal fishbone hybrid nanocavity with nanoposts
NASA Astrophysics Data System (ADS)
Lu, Tsan-Wen; Lin, Pin-Tso; Lee, Po-Tsung
2014-05-01
We propose and investigate a one-dimensional photonic crystal (PhC) fishbone (FB) hybrid nanocavity lying on silver substrate with a horizontal air slot. With very few PhC periods, the confined transverse-magnetic, TM10 hybrid mode concentrated within the air slot shows high quality factor over effective mode volume ratio larger than 105λ-3. Most importantly, this FB hybrid nanocavity allows formation of low-index nanoposts within the air slot without significantly affecting the mode properties. These nanoposts guarantee the structural stabilities under different environmental perturbations. Furthermore, capabilities of our proposed design in serving as optical sensors and tweezers for bio-sized nanoparticles are also investigated.
Bjorken flow in one-dimensional relativistic magnetohydrodynamics with magnetization
NASA Astrophysics Data System (ADS)
Pu, Shi; Roy, Victor; Rezzolla, Luciano; Rischke, Dirk H.
2016-04-01
We study the one-dimensional, longitudinally boost-invariant motion of an ideal fluid with infinite conductivity in the presence of a transverse magnetic field, i.e., in the ideal transverse magnetohydrodynamical limit. In an extension of our previous work Roy et al., [Phys. Lett. B 750, 45 (2015)], we consider the fluid to have a nonzero magnetization. First, we assume a constant magnetic susceptibility χm and consider an ultrarelativistic ideal gas equation of state. For a paramagnetic fluid (i.e., with χm>0 ), the decay of the energy density slows down since the fluid gains energy from the magnetic field. For a diamagnetic fluid (i.e., with χm<0 ), the energy density decays faster because it feeds energy into the magnetic field. Furthermore, when the magnetic field is taken to be external and to decay in proper time τ with a power law ˜τ-a, two distinct solutions can be found depending on the values of a and χm. Finally, we also solve the ideal magnetohydrodynamical equations for one-dimensional Bjorken flow with a temperature-dependent magnetic susceptibility and a realistic equation of state given by lattice-QCD data. We find that the temperature and energy density decay more slowly because of the nonvanishing magnetization. For values of the magnetic field typical for heavy-ion collisions, this effect is, however, rather small. It is only for magnetic fields about an order of magnitude larger than expected for heavy-ion collisions that the system is substantially reheated and the lifetime of the quark phase might be extended.
A One-Dimensional Synthetic-Aperture Microwave Radiometer
NASA Technical Reports Server (NTRS)
Doiron, Terence; Piepmeier, Jeffrey
2010-01-01
A proposed one-dimensional synthetic- aperture microwave radiometer could serve as an alternative to either the two-dimensional synthetic-aperture radiometer described in the immediately preceding article or to a prior one-dimensional one, denoted the Electrically Scanned Thinned Array Radiometer (ESTAR), mentioned in that article. The proposed radiometer would operate in a pushbroom imaging mode, utilizing (1) interferometric cross-track scanning to obtain cross-track resolution and (2) the focusing property of a reflector for along-track resolution. The most novel aspect of the proposed system would be the antenna (see figure), which would include a cylindrical reflector of offset parabolic cross section. The reflector could be made of a lightweight, flexible material amenable to stowage and deployment. Other than a stowage/deployment mechanism, the antenna would not include moving parts, and cross-track scanning would not entail mechanical rotation of the antenna. During operation, the focal line, parallel to the cylindrical axis, would be oriented in the cross-track direction, so that placement of receiving/radiating elements at the focal line would afford the desired along-track resolution. The elements would be microwave feed horns sparsely arrayed along the focal line. The feed horns would be oriented with their short and long cross-sectional dimensions parallel and perpendicular, respectively, to the cylindrical axis to obtain fan-shaped beams having their broad and narrow cross-sectional dimensions parallel and perpendicular, respectively, to the cylindrical axis. The interference among the beams would be controlled in the same manner as in the ESTAR to obtain along-cylindrical- axis (cross-track) resolution and cross-track scanning.
One-dimensional cloud fluid model for propagating star formation
NASA Technical Reports Server (NTRS)
Titus, Timothy N.; Struck-Marcell, Curtis
1990-01-01
The aim of this project was to study the propagation of star formation (SF) with a self-consistent deterministic model for the interstellar gas. The questions of under what conditions does star formation propagate in this model and what are the mechanisms of the propagation are explored. Here, researchers used the deterministic Oort-type cloud fluid model of Scalo and Struck-Marcell (1984, also see the review of Struck-Marcell, Scalo and Appleton 1987). This cloud fluid approach includes simple models for the effects of cloud collisional coalescence or disruption, collisional energy dissipation, and cloud disruption and acceleration as the result of young star winds, HII regions and supernovae. An extensive one-zone parameter study is presented in Struck-Marcell and Scalo (1987). To answer the questions above, researchers carried out one-dimensional calculations for an annulus within a galactic disk, like the so-called solar neighborhood of the galactic chemical evolution. In the calculations the left-hand boundary is set equal to the right hand boundary. The calculation is obviously idealized; however, it is computationally convenient to study the first order effects of propagating star formation. The annulus was treated as if it were at rest, i.e., in the local rotating frame. This assumption may remove some interesting effects of a supersonic gas flow, but was necessary to maintain a numerical stability in the annulus. The results on the one-dimensional propagation of SF in the Oort cloud fluid model follow: (1) SF is propagated by means of hydrodynamic waves, which can be generated by external forces or by the pressure generated by local bursts. SF is not effectively propagated via diffusion or variation in cloud interaction rates without corresponding density and velocity changes. (2) The propagation and long-range effects of SF depend on how close the gas density is to the critical threshold value, i.e., on the susceptibility of the medium.
Influence of Cemented Layers on Contaminant Transport in Mine Tailings
NASA Astrophysics Data System (ADS)
Ptacek, C.; Blowes, D.; Jambor, J.; Moncur, M.; Gunsinger, M.; Doerr, N.
2004-12-01
Exposure of sulfide-mine tailings to atmospheric oxygen leads to the initiation of a series of reactions, including sulfide oxidation, acid neutralization and metal attenuation reactions. As oxygen ingresses into the tailings, the oxidation front moves downward and inward from the edges of the tailings surface. At or near the acid neutralization front, secondary phases can accumulate, leading to the formation of hardpan layers. Field studies were conducted at three mine sites to evaluate the role of cemented layers in influencing contaminant transport from oxidized tailings. Detailed field measurements were made, including collection of water and gas samples from the vadose and groundwater zones. Cores were collected for mineralogical and chemical analyses to evaluate the extent of sulfide mineral oxidation and accumulation of secondary phases. Calculations of mineral saturation indices were made using ion-pair and ion-interaction models that were modified to account for the very high solute concentrations observed in the tailings pore waters. At a site that has been oxidizing for 25 years, a massive Fe(III)-bearing hardpan, containing gypsum, goethite and jarosite, has formed over the last 15 years. At a site that has been oxidizing for 35 years, an Fe(III)-bearing hardpan is also present. At a site that has been oxidizing for 70 years, a massive Fe(II)-bearing hardpan containing melanterite and gypsum is present below the zone of active oxidation. Above this zone, there are discontinuous Fe(III)-bearing cemented layers that are likely oxidized remnants of the original Fe(II) hardpan. Calculated mineral saturation indices are consistent with the observed accumulations of secondary phases. Transient perched water table conditions have developed above the massive Fe(II) hardpan, leading to the lateral transport of sulfide oxidation products along the hardpan and the formation of seepage zones above the permanent water table. Chemical extractions and mineralogical
On-surface formation of one-dimensional polyphenylene through Bergman cyclization.
Sun, Qiang; Zhang, Chi; Li, Zhiwen; Kong, Huihui; Tan, Qinggang; Hu, Aiguo; Xu, Wei
2013-06-12
On-surface fabrication of covalently interlinked conjugated nanostructures has attracted significant attention, mainly because of the high stability and efficient electron transport ability of these structures. Here, from the interplay of scanning tunneling microscopy imaging and density functional theory calculations, we report for the first time on-surface formation of one-dimensional polyphenylene chains through Bergman cyclization followed by radical polymerization on Cu(110). The formed surface nanostructures were further corroborated by the results for the ex situ-synthesized molecular product after Bergman cyclization. These findings are of particular interest and importance for the construction of molecular electronic nanodevices on surfaces.
Pseudo one-dimensional analysis of polymer electrolyte fuel cell cold-start
Mukherjee, Partha P; Mukundan, Rangachary; Borup, Rodney L; Wang, Yun; Mishlera, Jeff
2009-01-01
This paper investigates the electrochemical kinetics, oxygen transport, and solid water formation in polymer electrolyte fuel cell (PEFC) during cold start. Following [Yo Wang, J. Electrochem. Soc., 154 (2007) B1041-B1048], we develop a pseudo one-dimensional analysis, which enables the evaluation of the impact of ice volume fraction and temperature variations on cell performance during cold-start. The oxygen profile, starvation ice volume fraction, and relevant overpotentials are obtained. This study is valuable for studying the characteristics of PEFC cold-start.
Numerical studies of variable-range hopping in one-dimensional systems
NASA Astrophysics Data System (ADS)
Rodin, A. S.; Fogler, M. M.
2010-03-01
We report on our recent numerical study [1] of hopping transport in disordered one-dimensional systems. A fast new algorithm, based on Dijkstra shortest-path algorithm, is devised to find the lowest-resistance path through the hopping network at arbitrary electric field. Probability distribution functions of individual resistances on the path and the net resistance are calculated and fitted to compact analytic formulas. Qualitative differences between statistics of resistance fluctuations in Ohmic and non-Ohmic regimes are elucidated. The results are compared with prior theoretical and experimental work on the subject.[6pt] [1] A. S. Rodin and M. M. Fogler, Phys. Rev. B 80, 155435 (2009).
Contaminant transport and biodegradation in saturated porous media: model development and simulation
NASA Astrophysics Data System (ADS)
Kim, Song-Bae
2005-12-01
A mathematical model is developed to describe the contaminant transport, sorption, and biodegradation in saturated porous media. In the model development, sorption was accounted for as a kinetic process for the contaminant transport. In addition, a double Monod function was incorporated into the model to describe the biodegradation of contaminants and utilization of oxygen. In the description of bacterial transport, reversible and irreversible depositions of bacteria were considered as kinetic processes in the model. The model equations were solved numerically with a fully implicit finite-difference method along with the Runge-Kutta method. The simulation showed that contaminant transport in porous media could be greatly affected by sorption and biodegradation processes. Sensitivity analysis demonstrated that the contaminant transport model was insensitive to the changes of desorption rate constant for contaminants kb, half-saturation constant for oxygen Ko, bacterial yield factor Y, and oxygen use coefficient F. However, the model was sensitive to the changes of adsorption rate constant for contaminants kf, maximum utilization rate of contaminants max, and half-saturation constant for contaminants K_{c}, and so their values should be selected carefully in the modelling process. Copyright
Xie, Haijian; Yan, Huaxiang; Feng, Shijin; Wang, Qiao; Chen, Peixiong
2016-10-01
One-dimensional mathematical model is developed to investigate the behavior of contaminant transport in landfill composite liner system considering coupled effect of consolidation, diffusion, and degradation. The first- and second-type bottom boundary conditions are used to derive the steady-state and quasi-steady-state analytical solutions. The concentration profiles obtained by the proposed analytical solution are in good agreement with those obtained by the laboratory tests. The bottom concentration and flux of the soil liners can be greatly reduced when the degradation effect and porosity changing are considered. For the case under steady-state, the bottom flux and concentration for the case with t 1/2 =10 years can be 2.8 and 5.5 times lower than those of the case with t 1/2 =100 years, respectively. The bottom concentration and flux of the soil liners can be greatly reduced when the coefficient of volume compressibility decreases. For quasi-steady-state and with t 1/2 = 10 years, the bottom flux and concentration for the case with m v = 0.02/MPa can be 17.4 and 21 times lower than the case with m v = 0.5/MPa. This may be due to the fact that the true fluid velocity induced by consolidation is greater for the case with high coefficient of volume compressibility. The bottom flux for the case with single compacted clay liner (CCL) can be 1.5 times larger than that for the case with GMB/CCL considering diffusion and consolidation for DCM. The proposed analytical model can be used for verification of more complicated numerical models and assessment of the coupled effect of diffusion, consolidation, and degradation on contaminant transport in landfill liner systems.
Wang, Bin; Li, Xianglong; Luo, Bin; Jia, Yuying; Zhi, Linjie
2013-02-21
A unique silicon-based anode for lithium ion batteries is developed via the facile hybridization of one-dimensional silicon nanowires and two-dimensional graphene sheets. The resulting paper-like film holds advantages highly desirable for not only accommodating the volume change of silicon, but also facilitating the fast transport of electron and lithium ions.
Chen, Kuo-Fu
1996-11-01
The health risks for an individual exposed to contaminants released from SRS outfalls from 1989 to 1995 were estimated. The exposure pathways studied are ingestion of drinking water, ingestion of contaminated fish and dermal contact with contaminants in water while swimming. The estimated incremental risks for an individual developing cancer vary from 3.E-06 to 1.0E-05. The estimated total exposure chronic noncancer hazard indices vary from 6.E-02 to 1.E-01. The critical contaminants were ranked based on their cancer risks and chronic noncarcinogenic hazard quotients. For cancer risks, the critical contaminants released from SRS outfalls are arsenic, tetrachloroethylene, and benzene. For chronic noncarcinogenic risks, the critical contaminants released from srs outfalls are cadmium, arsenic, silver, chromium, mercury, selenium, nitrate, manganese, zinc, nickel, uranium, barium, copper, tetrachloroethylene, cyanide, and phenol. The critical pathways in decreasing risk order are ingestion of contaminated fish, ingestion of drinking water and dermal contact with contaminants in water while swimming.
An adaptive grid algorithm for one-dimensional nonlinear equations
NASA Technical Reports Server (NTRS)
Gutierrez, William E.; Hills, Richard G.
1990-01-01
Richards' equation, which models the flow of liquid through unsaturated porous media, is highly nonlinear and difficult to solve. Step gradients in the field variables require the use of fine grids and small time step sizes. The numerical instabilities caused by the nonlinearities often require the use of iterative methods such as Picard or Newton interation. These difficulties result in large CPU requirements in solving Richards equation. With this in mind, adaptive and multigrid methods are investigated for use with nonlinear equations such as Richards' equation. Attention is focused on one-dimensional transient problems. To investigate the use of multigrid and adaptive grid methods, a series of problems are studied. First, a multigrid program is developed and used to solve an ordinary differential equation, demonstrating the efficiency with which low and high frequency errors are smoothed out. The multigrid algorithm and an adaptive grid algorithm is used to solve one-dimensional transient partial differential equations, such as the diffusive and convective-diffusion equations. The performance of these programs are compared to that of the Gauss-Seidel and tridiagonal methods. The adaptive and multigrid schemes outperformed the Gauss-Seidel algorithm, but were not as fast as the tridiagonal method. The adaptive grid scheme solved the problems slightly faster than the multigrid method. To solve nonlinear problems, Picard iterations are introduced into the adaptive grid and tridiagonal methods. Burgers' equation is used as a test problem for the two algorithms. Both methods obtain solutions of comparable accuracy for similar time increments. For the Burgers' equation, the adaptive grid method finds the solution approximately three times faster than the tridiagonal method. Finally, both schemes are used to solve the water content formulation of the Richards' equation. For this problem, the adaptive grid method obtains a more accurate solution in fewer work units and
Using the NASA GRC Sectored-One-Dimensional Combustor Simulation
NASA Technical Reports Server (NTRS)
Paxson, Daniel E.; Mehta, Vishal R.
2014-01-01
The document is a user manual for the NASA GRC Sectored-One-Dimensional (S-1-D) Combustor Simulation. It consists of three sections. The first is a very brief outline of the mathematical and numerical background of the code along with a description of the non-dimensional variables on which it operates. The second section describes how to run the code and includes an explanation of the input file. The input file contains the parameters necessary to establish an operating point as well as the associated boundary conditions (i.e. how it is fed and terminated) of a geometrically configured combustor. It also describes the code output. The third section describes the configuration process and utilizes a specific example combustor to do so. Configuration consists of geometrically describing the combustor (section lengths, axial locations, and cross sectional areas) and locating the fuel injection point and flame region. Configuration requires modifying the source code and recompiling. As such, an executable utility is included with the code which will guide the requisite modifications and insure that they are done correctly.
One-dimensional flows of an imperfect diatomic gas
NASA Technical Reports Server (NTRS)
1959-01-01
With the assumptions that Berthelot's equation of state accounts for molecular size and intermolecular force effects, and that changes in the vibrational heat capacities are given by a Planck term, expressions are developed for analyzing one-dimensional flows of a diatomic gas. The special cases of flow through normal and oblique shocks in free air at sea level are investigated. It is found that up to a Mach number 10 pressure ratio across a normal shock differs by less than 6 percent from its ideal gas value; whereas at Mach numbers above 4 the temperature rise is considerable below and hence the density rise is well above that predicted assuming ideal gas behavior. It is further shown that only the caloric imperfection in air has an appreciable effect on the pressures developed in the shock process considered. The effects of gaseous imperfections on oblique shock-flows are studied from the standpoint of their influence on the life and pressure drag of a flat plate operating at Mach numbers of 10 and 20. The influence is found to be small. (author)
A disorder-enhanced quasi-one-dimensional superconductor
Petrović, A. P.; Ansermet, D.; Chernyshov, D.; Hoesch, M.; Salloum, D.; Gougeon, P.; Potel, M.; Boeri, L.; Panagopoulos, C.
2016-01-01
A powerful approach to analysing quantum systems with dimensionality d>1 involves adding a weak coupling to an array of one-dimensional (1D) chains. The resultant quasi-1D (q1D) systems can exhibit long-range order at low temperature, but are heavily influenced by interactions and disorder due to their large anisotropies. Real q1D materials are therefore ideal candidates not only to provoke, test and refine theories of strongly correlated matter, but also to search for unusual emergent electronic phases. Here we report the unprecedented enhancement of a superconducting instability by disorder in single crystals of Na2−δMo6Se6, a q1D superconductor comprising MoSe chains weakly coupled by Na atoms. We argue that disorder-enhanced Coulomb pair-breaking (which usually destroys superconductivity) may be averted due to a screened long-range Coulomb repulsion intrinsic to disordered q1D materials. Our results illustrate the capability of disorder to tune and induce new correlated electron physics in low-dimensional materials. PMID:27448209
A Smart Colorful Supercapacitor with One Dimensional Photonic Crystals
Liu, Cihui; Liu, Xing; Xuan, Hongyun; Ren, Jiaoyu; Ge, Liqin
2015-01-01
To meet the pressing demands for portable and flexible equipment in contemporary society, developing flexible, lightweight, and sustainable supercapacitor systems with large power densities, long cycle life, and ease of strongly required. However, estimating the state-of-charge of existing supercapacitors is difficult, and thus their service life is limited. In this study, we fabricate a flexible color indicative supercapacitor device with mesoporous polyaniline (mPANI)/Poly(N-Isopropyl acrylamide-Graphene Oxide-Acrylic Acid) (P(NiPPAm-GO-AA)) one dimensional photonic crystals (1DPCs) as the electrode material through a low-cost, eco-friendly, and scalable fabrication process. We found that the state-of-charge could be monitored by the structural color oscillation due to the change in the photonic band gap position of the 1DPCs. The flexible 1DPCs supercapacitor is thin at 3 mm and exhibits good specific capacitance of 22.6 F g−1 with retention of 91.1% after 3,000 cycles. This study shows the application of the 1DPCs supercapacitor as a visual ultrathin power source. The technology may find many applications in future wearable electronics. PMID:26689375
Topological water wave states in a one-dimensional structure
NASA Astrophysics Data System (ADS)
Yang, Zhaoju; Gao, Fei; Zhang, Baile
2016-07-01
Topological concepts have been introduced into electronic, photonic, and phononic systems, but have not been studied in surface-water-wave systems. Here we study a one-dimensional periodic resonant surface-water-wave system and demonstrate its topological transition. By selecting three different water depths, we can construct different types of water waves - shallow, intermediate and deep water waves. The periodic surface-water-wave system consists of an array of cylindrical water tanks connected with narrow water channels. As the width of connecting channel varies, the band diagram undergoes a topological transition which can be further characterized by Zak phase. This topological transition holds true for shallow, intermediate and deep water waves. However, the interface state at the boundary separating two topologically distinct arrays of water tanks can exhibit different bands for shallow, intermediate and deep water waves. Our work studies for the first time topological properties of water wave systems, and paves the way to potential management of water waves.
Approximate approaches to the one-dimensional finite potential well
NASA Astrophysics Data System (ADS)
Singh, Shilpi; Pathak, Praveen; Singh, Vijay A.
2011-11-01
The one-dimensional finite well is a textbook problem. We propose approximate approaches to obtain the energy levels of the well. The finite well is also encountered in semiconductor heterostructures where the carrier mass inside the well (mi) is taken to be distinct from mass outside (mo). A relevant parameter is the mass discontinuity ratio β = mi/mo. To correctly account for the mass discontinuity, we apply the BenDaniel-Duke boundary condition. We obtain approximate solutions for two cases: when the well is shallow and when the well is deep. We compare the approximate results with the exact results and find that higher-order approximations are quite robust. For the shallow case, the approximate solution can be expressed in terms of a dimensionless parameter σl = 2moV0L2/planck2 (or σ = β2σl for the deep case). We show that the lowest-order results are related by a duality transform. We also discuss how the energy upscales with L (E~1/Lγ) and obtain the exponent γ. Exponent γ → 2 when the well is sufficiently deep and β → 1. The ratio of the masses dictates the physics. Our presentation is pedagogical and should be useful to students on a first course on elementary quantum mechanics or low-dimensional semiconductors.
One-dimensional Kac model of dense amorphous hard spheres
NASA Astrophysics Data System (ADS)
Ikeda, H.; Ikeda, A.
2015-08-01
We introduce a new model of hard spheres under confinement for the study of the glass and jamming transitions. The model is a one-dimensional chain of the d-dimensional boxes each of which contains the same number of hard spheres, and the particles in the boxes of the ends of the chain are quenched at their equilibrium positions. We focus on the infinite-dimensional limit (d \\to ∞) of the model and analytically compute the glass transition densities using the replica liquid theory. From the chain length dependence of the transition densities, we extract the characteristic length scales at the glass transition. The divergence of the lengths are characterized by the two exponents, -1/4 for the dynamical transition and -1 for the ideal glass transition, which are consistent with those of the p-spin mean-field spin glass model. We also show that the model is useful for the study of the growing length scale at the jamming transition.
One-Dimensional Quasi-Relativistic Particle in the Box
NASA Astrophysics Data System (ADS)
Kaleta, Kamil; Kwaśnicki, Mateusz; Małecki, Jacek
2013-09-01
The eigenvalues and eigenfunctions of the one-dimensional quasi-relativistic Hamiltonian (-ℏ2c2d2/dx2 + m2c4)1/2 + Vwell(x) (the Klein-Gordon square-root operator with electrostatic potential) with the infinite square well potential Vwell(x) are studied. Eigenvalues represent energies of a "massive particle in the box" quasi-relativistic model. Approximations to eigenvalues λn are given, uniformly in n, ℏ, m, c and a, with error less than C1ℏca-1exp(-C2ℏ-1mca)n-1. Here 2a is the width of the potential well. As a consequence, the spectrum is simple and the nth eigenvalue is equal to (nπ/2 - π/8)ℏc/a + O(1/n) as n → ∞. Non-relativistic, zero mass and semi-classical asymptotic expansions are included as special cases. In the final part, some L2 and L∞ properties of eigenfunctions are studied.
Trapped Atoms in One-Dimensional Photonic Crystals
NASA Astrophysics Data System (ADS)
Kimble, H.
2013-05-01
I describe one-dimensional photonic crystals that support a guided mode suitable for atom trapping within a unit cell, as well as a second probe mode with strong atom-photon interactions. A new hybrid trap is analyzed that combines optical and Casimir-Polder forces to form stable traps for neutral atoms in dielectric nanostructures. By suitable design of the band structure, the atomic spontaneous emission rate into the probe mode can exceed the rate into all other modes by more than tenfold. The unprecedented single-atom reflectivity r0 ~= 0 . 9 for the guided probe field could create new scientific opportunities, including quantum many-body physics for 1 D atom chains with photon-mediated interactions and high-precision studies of vacuum forces. Towards these goals, my colleagues and I are pursuing numerical simulation, device fabrication, and cold-atom experiments with nanoscopic structures. Funding is provided by by the IQIM, an NSF PFC with support of the Moore Foundation, by the AFOSR QuMPASS MURI, by the DoD NSSEFF program (HJK), and by NSF Grant PHY0652914 (HJK). DEC acknowledges funding from Fundacio Privada Cellex Barcelona.
Numerical Method of Characteristics for One-Dimensional Blood Flow.
Acosta, Sebastian; Puelz, Charles; Riviére, Béatrice; Penny, Daniel J; Rusin, Craig G
2015-08-01
Mathematical modeling at the level of the full cardiovascular system requires the numerical approximation of solutions to a one-dimensional nonlinear hyperbolic system describing flow in a single vessel. This model is often simulated by computationally intensive methods like finite elements and discontinuous Galerkin, while some recent applications require more efficient approaches (e.g. for real-time clinical decision support, phenomena occurring over multiple cardiac cycles, iterative solutions to optimization/inverse problems, and uncertainty quantification). Further, the high speed of pressure waves in blood vessels greatly restricts the time step needed for stability in explicit schemes. We address both cost and stability by presenting an efficient and unconditionally stable method for approximating solutions to diagonal nonlinear hyperbolic systems. Theoretical analysis of the algorithm is given along with a comparison of our method to a discontinuous Galerkin implementation. Lastly, we demonstrate the utility of the proposed method by implementing it on small and large arterial networks of vessels whose elastic and geometrical parameters are physiologically relevant.
Screw dislocation-driven growth of one-dimensional nanomaterials
NASA Astrophysics Data System (ADS)
Meng, Fei
Nanoscience and nanotechnology are impacting our lives in many ways, from electronic and photonic devices to biosensors. They also hold the promise of tackling the renewable energy challenges facing us. However, one limiting scientific challenge is the effective and efficient bottom-up synthesis of nanomaterials. In this thesis, we discuss the fundamental theories of screw dislocation-driven growth of various nanostructures including one-dimensional nanowires and nanotubes, two-dimensional nanoplates, and three-dimensional hierarchical tree-like nanostructures. We then introduce the transmission electron microscopy (TEM) techniques to structurally characterize the dislocation-driven nanomaterials for future searching and identifying purposes. We summarize the guidelines for rationally designing the dislocation-driven growth and discuss specific examples to illustrate how to implement the guidelines. We also show that dislocation growth is a general and versatile mechanism that can be used to grow a variety of nanomaterials via distinct reaction chemistry and synthetic methods. The fundamental investigation and development of dislocation-driven growth of nanomaterials will create a new dimension to the rational design and synthesis of increasingly complex nanomaterials.
One-dimensional consolidation in unsaturated soils under cyclic loading
NASA Astrophysics Data System (ADS)
Lo, Wei-Cheng; Sposito, Garrison; Lee, Jhe-Wei; Chu, Hsiuhua
2016-05-01
The one-dimensional consolidation model of poroelasticity of Lo et al. (2014) for an unsaturated soil under constant loading is generalized to include an arbitrary time-dependent loading. A closed-form solution for the pore water and air pressures along with the total settlement is derived by employing a Fourier series representation in the spatial domain and a Laplace transformation in the time domain. This solution is illustrated for the important example of a fully-permeable soil cylinder with an undrained initial condition acted upon by a periodic stress. Our results indicate that, in terms of a dimensionless time scale, the transient solution decays to zero most slowly in a water-saturated soil, whereas for an unsaturated soil, the time for the transient solution to die out is inversely proportional to the initial water saturation. The generalization presented here shows that the diffusion time scale for pore water in an unsaturated soil is orders of magnitude greater than that in a water-saturated soil, mainly because of the much smaller hydraulic conductivity of the former.
One-dimensional surface phonon polaritons in boron nitride nanotubes
NASA Astrophysics Data System (ADS)
Xu, Xiaoji G.; Ghamsari, Behnood G.; Jiang, Jian-Hua; Gilburd, Leonid; Andreev, Gregory O.; Zhi, Chunyi; Bando, Yoshio; Golberg, Dmitri; Berini, Pierre; Walker, Gilbert C.
2014-08-01
Surface polaritons, which are electromagnetic waves coupled to material charge oscillations, have enabled applications in concentrating, guiding and harvesting optical energy below the diffraction limit. Surface plasmon polaritons involve oscillations of electrons and are accessible in noble metals at visible and near-infrared wavelengths, whereas surface phonon polaritons (SPhPs) rely on phonon resonances in polar materials, and are active in the mid-infrared. Noble metal surface plasmon polaritons have limited applications in the mid-infrared. SPhPs at flat interfaces normally possess long polariton wavelengths and provide modest field confinement/enhancement. Here we demonstrate propagating SPhPs in a one-dimensional material consisting of a boron nitride nanotube at mid-infrared wavelengths. The observed SPhP exhibits high field confinement and enhancement, and a very high effective index (neff~70). We show that the modal and propagation length characteristics of the SPhPs may be controlled through the nanotube size and the supporting substrates, enabling mid-infrared applications.
One-dimensional surface phonon polaritons in boron nitride nanotubes.
Xu, Xiaoji G; Ghamsari, Behnood G; Jiang, Jian-Hua; Gilburd, Leonid; Andreev, Gregory O; Zhi, Chunyi; Bando, Yoshio; Golberg, Dmitri; Berini, Pierre; Walker, Gilbert C
2014-08-26
Surface polaritons, which are electromagnetic waves coupled to material charge oscillations, have enabled applications in concentrating, guiding and harvesting optical energy below the diffraction limit. Surface plasmon polaritons involve oscillations of electrons and are accessible in noble metals at visible and near-infrared wavelengths, whereas surface phonon polaritons (SPhPs) rely on phonon resonances in polar materials, and are active in the mid-infrared. Noble metal surface plasmon polaritons have limited applications in the mid-infrared. SPhPs at flat interfaces normally possess long polariton wavelengths and provide modest field confinement/enhancement. Here we demonstrate propagating SPhPs in a one-dimensional material consisting of a boron nitride nanotube at mid-infrared wavelengths. The observed SPhP exhibits high field confinement and enhancement, and a very high effective index (neff~70). We show that the modal and propagation length characteristics of the SPhPs may be controlled through the nanotube size and the supporting substrates, enabling mid-infrared applications.
Dynamic response of one-dimensional bosons in a trap
Golovach, Vitaly N.; Minguzzi, Anna; Glazman, Leonid I.
2009-10-15
We calculate the dynamic structure factor S(q,{omega}) of a one-dimensional (1D) interacting Bose gas confined in a harmonic trap. The effective interaction depends on the strength of the confinement enforcing the (1D) motion of atoms; interaction may be further enhanced by superimposing an optical lattice on the trap potential. In the compressible state, we find that the smooth variation in the gas density around the trap center leads to softening of the singular behavior of S(q,{omega}) at the first Lieb excitation mode compared to the behavior predicted for homogeneous 1D systems. Nevertheless, the density-averaged response S(q,{omega}) remains a nonanalytic function of q and {omega} at the first Lieb excitation mode in the limit of weak trap confinement. The exponent of the power-law nonanalyticity is modified due to the inhomogeneity in a universal way and thus bears unambiguously the information about the (homogeneous) Lieb-Liniger model. A strong optical lattice causes formation of Mott phases. Deep in the Mott regime, we predict a semicircular peak in S(q,{omega}) centered at the on-site repulsion energy, {omega}=U. Similar peaks of smaller amplitudes exist at multiples of U as well. We explain the suppression of the dynamic response with entering into the Mott regime, observed recently by Clement et al. [Phys. Rev. Lett. 102, 155301 (2009)], based on an f-sum rule for the Bose-Hubbard model.
Weak lasing in one-dimensional polariton superlattices.
Zhang, Long; Xie, Wei; Wang, Jian; Poddubny, Alexander; Lu, Jian; Wang, Yinglei; Gu, Jie; Liu, Wenhui; Xu, Dan; Shen, Xuechu; Rubo, Yuri G; Altshuler, Boris L; Kavokin, Alexey V; Chen, Zhanghai
2015-03-31
Bosons with finite lifetime exhibit condensation and lasing when their influx exceeds the lasing threshold determined by the dissipative losses. In general, different one-particle states decay differently, and the bosons are usually assumed to condense in the state with the longest lifetime. Interaction between the bosons partially neglected by such an assumption can smear the lasing threshold into a threshold domain--a stable lasing many-body state exists within certain intervals of the bosonic influxes. This recently described weak lasing regime is formed by the spontaneously symmetry breaking and phase-locking self-organization of bosonic modes, which results in an essentially many-body state with a stable balance between gains and losses. Here we report, to our knowledge, the first observation of the weak lasing phase in a one-dimensional condensate of exciton-polaritons subject to a periodic potential. Real and reciprocal space photoluminescence images demonstrate that the spatial period of the condensate is twice as large as the period of the underlying periodic potential. These experiments are realized at room temperature in a ZnO microwire deposited on a silicon grating. The period doubling takes place at a critical pumping power, whereas at a lower power polariton emission images have the same periodicity as the grating.
Weak lasing in one-dimensional polariton superlattices
Zhang, Long; Xie, Wei; Wang, Jian; Poddubny, Alexander; Lu, Jian; Wang, Yinglei; Gu, Jie; Liu, Wenhui; Xu, Dan; Shen, Xuechu; Rubo, Yuri G.; Altshuler, Boris L.; Kavokin, Alexey V.; Chen, Zhanghai
2015-01-01
Bosons with finite lifetime exhibit condensation and lasing when their influx exceeds the lasing threshold determined by the dissipative losses. In general, different one-particle states decay differently, and the bosons are usually assumed to condense in the state with the longest lifetime. Interaction between the bosons partially neglected by such an assumption can smear the lasing threshold into a threshold domain—a stable lasing many-body state exists within certain intervals of the bosonic influxes. This recently described weak lasing regime is formed by the spontaneously symmetry breaking and phase-locking self-organization of bosonic modes, which results in an essentially many-body state with a stable balance between gains and losses. Here we report, to our knowledge, the first observation of the weak lasing phase in a one-dimensional condensate of exciton–polaritons subject to a periodic potential. Real and reciprocal space photoluminescence images demonstrate that the spatial period of the condensate is twice as large as the period of the underlying periodic potential. These experiments are realized at room temperature in a ZnO microwire deposited on a silicon grating. The period doubling takes place at a critical pumping power, whereas at a lower power polariton emission images have the same periodicity as the grating. PMID:25787253
One-dimensional nanoferroic rods; synthesis and characterization
NASA Astrophysics Data System (ADS)
Ahmed, M. A.; Seddik, U.; Okasha, N.; Imam, N. G.
2015-11-01
One-dimensional nanoferroic rods of BaTiO3 were synthesized by improved citrate auto-combustion technology using tetrabutyl titanate. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), transmission electron microscopy (TEM), atomic force microscopy (AFM) and Fourier transform infrared spectroscopy (FTIR) have been used to characterize the prepared sample. The results indicated that the crystal structure of BaTiO3 is tetragonal phase with an average crystallite size of 47 nm. SEM image gives a cauliflower-like morphology of the agglomerated nanorods. The stoichiometry of the chemical composition of the BaTiO3 ceramic was confirmed by EDX. TEM micrograph exhibited that BaTiO3 nanoparticles have rod-like shape with an average length of 120 nm and width of 43 nm. AFM was used to investigate the surface topography and its roughness. The topography image in 3D showed that the BaTiO3 particles have a rod shape with an average particle size of 116 nm which in agreement with 3D TEM result.
Supercurrent states in one-dimensional finite-size rings
NASA Astrophysics Data System (ADS)
Kashurnikov, Vladimir A.; Podlivaev, Alexei I.; Prokof'ev, Nikolai V.; Svistunov, Boris V.
1996-05-01
We consider topological supercurrent excitations (SC's) in one-dimensional (1D) mesoscopic rings. In the superfluid phase such excitations are well defined except for (i) a tunneling between resonating states with clockwise and counterclockwise currents, which may be characterized by the amplitude Δ, and (ii) a decay of SC assisted by phonons of the substrate, both effects being macroscopically small. Our approach, being based on the hydrodynamical action for the phase field and its generalization to the effective Hamiltonian, explicitly takes into account transitions between the states with different topological numbers and turns out to be very effective for the calculation of Δ and estimation of the decay width of SC, as well as for the unified description of all known 1D superfluid-insulator transitions. Most attention is paid to the calculation of the macroscopic scaling of Δ (the main superfluid characteristic of a mesoscopic system) under different conditions: a commensurate system, a system with single impurity, and a disordered system. The results are in a very good agreement with the exact-diagonalization spectra of the boson Hubbard models. Apart from really 1D electron wires we discuss two other important experimental systems: the 2D electron gas in the fractional quantum Hall effect state and quasi-1D superconducting rings. We suggest some experimental setups for studying SC, e.g., via persistent current measurements, resonant electromagnetic absorption or echo signals, and relaxation of the metastable current states.
Validation and Comparison of One-Dimensional Graound Motion Methodologies
B. Darragh; W. Silva; N. Gregor
2006-06-28
Both point- and finite-source stochastic one-dimensional ground motion models, coupled to vertically propagating equivalent-linear shear-wave site response models are validated using an extensive set of strong motion data as part of the Yucca Mountain Project. The validation and comparison exercises are presented entirely in terms of 5% damped pseudo absolute response spectra. The study consists of a quantitative analyses involving modeling nineteen well-recorded earthquakes, M 5.6 to 7.4 at over 600 sites. The sites range in distance from about 1 to about 200 km in the western US (460 km for central-eastern US). In general, this validation demonstrates that the stochastic point- and finite-source models produce accurate predictions of strong ground motions over the range of 0 to 100 km and for magnitudes M 5.0 to 7.4. The stochastic finite-source model appears to be broadband, producing near zero bias from about 0.3 Hz (low frequency limit of the analyses) to the high frequency limit of the data (100 and 25 Hz for response and Fourier amplitude spectra, respectively).
Numerical method of characteristics for one-dimensional blood flow
NASA Astrophysics Data System (ADS)
Acosta, Sebastian; Puelz, Charles; Rivière, Béatrice; Penny, Daniel J.; Rusin, Craig G.
2015-08-01
Mathematical modeling at the level of the full cardiovascular system requires the numerical approximation of solutions to a one-dimensional nonlinear hyperbolic system describing flow in a single vessel. This model is often simulated by computationally intensive methods like finite elements and discontinuous Galerkin, while some recent applications require more efficient approaches (e.g. for real-time clinical decision support, phenomena occurring over multiple cardiac cycles, iterative solutions to optimization/inverse problems, and uncertainty quantification). Further, the high speed of pressure waves in blood vessels greatly restricts the time step needed for stability in explicit schemes. We address both cost and stability by presenting an efficient and unconditionally stable method for approximating solutions to diagonal nonlinear hyperbolic systems. Theoretical analysis of the algorithm is given along with a comparison of our method to a discontinuous Galerkin implementation. Lastly, we demonstrate the utility of the proposed method by implementing it on small and large arterial networks of vessels whose elastic and geometrical parameters are physiologically relevant.
Solitary Wave in One-dimensional Buckyball System at Nanoscale.
Xu, Jun; Zheng, Bowen; Liu, Yilun
2016-02-19
We have studied the stress wave propagation in one-dimensional (1-D) nanoscopic buckyball (C60) system by molecular dynamics (MD) simulation and quantitative modeling. Simulation results have shown that solitary waves are generated and propagating in the buckyball system through impacting one buckyball at one end of the buckyball chain. We have found the solitary wave behaviors are closely dependent on the initial temperature and impacting speed of the buckyball chain. There are almost no dispersion and dissipation of the solitary waves (stationary solitary wave) for relatively low temperature and high impacting speed. While for relatively high temperature and low impacting speed the profile of the solitary waves is highly distorted and dissipated after propagating several tens of buckyballs. A phase diagram is proposed to describe the effect of the temperature and impacting speed on the solitary wave behaviors in buckyball system. In order to quantitatively describe the wave behavior in buckyball system, a simple nonlinear-spring model is established, which can describe the MD simulation results at low temperature very well. The results presented in this work may lay a solid step towards the further understanding and manipulation of stress wave propagation and impact energy mitigation at nanoscale.
Multi-symplectic, Lagrangian, one-dimensional gas dynamics
NASA Astrophysics Data System (ADS)
Webb, G. M.
2015-05-01
The equations of Lagrangian, ideal, one-dimensional, compressible gas dynamics are written in a multi-symplectic form using the Lagrangian mass coordinate m and time t as independent variables, and in which the Eulerian position of the fluid element x = x(m, t) is one of the dependent variables. This approach differs from the Eulerian, multi-symplectic approach using Clebsch variables. Lagrangian constraints are used to specify equations for xm, xt, and St consistent with the Lagrangian map, where S is the entropy of the gas. We require St = 0 corresponding to advection of the entropy S with the flow. We show that the Lagrangian Hamiltonian equations are related to the de Donder-Weyl multi-momentum formulation. The pullback conservation laws and the symplecticity conservation laws are discussed. The pullback conservation laws correspond to invariance of the action with respect to translations in time (energy conservation) and translations in m in Noether's theorem. The conservation law due to m-translation invariance gives rise to a novel nonlocal conservation law involving the Clebsch variable r used to impose ∂S(m, t)/∂t = 0. Translation invariance with respect to x in Noether's theorem is associated with momentum conservation. We obtain the Cartan-Poincaré form for the system, and use it to obtain a closed ideal of two-forms representing the equation system.
Developing one-dimensional implosions for inertial confinement fusion science
Kline, John L.; Yi, Sunghwan A.; Simakov, Andrei Nikolaevich; ...
2016-12-12
Experiments on the National Ignition Facility show that multi-dimensional effects currently dominate the implosion performance. Low mode implosion symmetry and hydrodynamic instabilities seeded by capsule mounting features appear to be two key limiting factors for implosion performance. One reason these factors have a large impact on the performance of inertial confinement fusion implosions is the high convergence required to achieve high fusion gains. To tackle these problems, a predictable implosion platform is needed meaning experiments must trade-off high gain for performance. LANL has adopted three main approaches to develop a one-dimensional (1D) implosion platform where 1D means measured yield overmore » the 1D clean calculation. A high adiabat, low convergence platform is being developed using beryllium capsules enabling larger case-to-capsule ratios to improve symmetry. The second approach is liquid fuel layers using wetted foam targets. With liquid fuel layers, the implosion convergence can be controlled via the initial vapor pressure set by the target fielding temperature. The last method is double shell targets. For double shells, the smaller inner shell houses the DT fuel and the convergence of this cavity is relatively small compared to hot spot ignition. However, double shell targets have a different set of trade-off versus advantages. As a result, details for each of these approaches are described.« less
Developing one-dimensional implosions for inertial confinement fusion science
Kline, John L.; Yi, Sunghwan A.; Simakov, Andrei Nikolaevich; Olson, Richard Edward; Wilson, Douglas Carl; Kyrala, George Amine; Perry, Theodore Sonne; Batha, Steven H.; Dewald, Eddie L.; Ralph, Joe E.; Strozzi, David J.; MacPhee, Andy G.; Callahan, Debbie A.; Hinkel, Denise; Hurricane, Omar A.; Leeper, Ramon J.; Zylstra, Alex B.; Peterson, Robert Ross; Haines, Brian Michael; Yin, Lin; Bradley, Paul Andrew; Shah, Rahul C.; Braun, Tom; Biener, Jorgan; Kozioziemski, Bernie J.; Sater, Jim D.; Biener, Monika M.; Hamza, Alex V.; Nikroo, Abbas; Berzak Hopkins, Laura F.; Ho, Darwin; LePape, Sebastian; Meezan, Nathan B.; Montgomery, David S.; Daughton, William Scott; Merritt, Elizabeth Catherine; Cardenas, Tana; Dodd, Evan S.
2016-12-12
Experiments on the National Ignition Facility show that multi-dimensional effects currently dominate the implosion performance. Low mode implosion symmetry and hydrodynamic instabilities seeded by capsule mounting features appear to be two key limiting factors for implosion performance. One reason these factors have a large impact on the performance of inertial confinement fusion implosions is the high convergence required to achieve high fusion gains. To tackle these problems, a predictable implosion platform is needed meaning experiments must trade-off high gain for performance. LANL has adopted three main approaches to develop a one-dimensional (1D) implosion platform where 1D means measured yield over the 1D clean calculation. A high adiabat, low convergence platform is being developed using beryllium capsules enabling larger case-to-capsule ratios to improve symmetry. The second approach is liquid fuel layers using wetted foam targets. With liquid fuel layers, the implosion convergence can be controlled via the initial vapor pressure set by the target fielding temperature. The last method is double shell targets. For double shells, the smaller inner shell houses the DT fuel and the convergence of this cavity is relatively small compared to hot spot ignition. However, double shell targets have a different set of trade-off versus advantages. As a result, details for each of these approaches are described.
One-dimensional quantum walk with a moving boundary
Kwek, Leong Chuan; Setiawan
2011-09-15
Quantum walks are interesting models with potential applications to quantum algorithms and physical processes such as photosynthesis. In this paper, we study two models of one-dimensional quantum walks, namely, quantum walks with a moving absorbing wall and quantum walks with one stationary and one moving absorbing wall. For the former, we calculate numerically the survival probability, the rate of change of average position, and the rate of change of standard deviation of the particle's position in the long time limit for different wall velocities. Moreover, we also study the asymptotic behavior and the dependence of the survival probability on the initial particle's state. While for the latter, we compute the absorption probability of the right stationary wall for different velocities and initial positions of the left wall boundary. The results for these two models are compared with those obtained for the classical model. The difference between the results obtained for the quantum and classical models can be attributed to the difference in the probability distributions.
Solitary Wave in One-dimensional Buckyball System at Nanoscale
Xu, Jun; Zheng, Bowen; Liu, Yilun
2016-01-01
We have studied the stress wave propagation in one-dimensional (1-D) nanoscopic buckyball (C60) system by molecular dynamics (MD) simulation and quantitative modeling. Simulation results have shown that solitary waves are generated and propagating in the buckyball system through impacting one buckyball at one end of the buckyball chain. We have found the solitary wave behaviors are closely dependent on the initial temperature and impacting speed of the buckyball chain. There are almost no dispersion and dissipation of the solitary waves (stationary solitary wave) for relatively low temperature and high impacting speed. While for relatively high temperature and low impacting speed the profile of the solitary waves is highly distorted and dissipated after propagating several tens of buckyballs. A phase diagram is proposed to describe the effect of the temperature and impacting speed on the solitary wave behaviors in buckyball system. In order to quantitatively describe the wave behavior in buckyball system, a simple nonlinear-spring model is established, which can describe the MD simulation results at low temperature very well. The results presented in this work may lay a solid step towards the further understanding and manipulation of stress wave propagation and impact energy mitigation at nanoscale. PMID:26891624
A Smart Colorful Supercapacitor with One Dimensional Photonic Crystals
NASA Astrophysics Data System (ADS)
Liu, Cihui; Liu, Xing; Xuan, Hongyun; Ren, Jiaoyu; Ge, Liqin
2015-12-01
To meet the pressing demands for portable and flexible equipment in contemporary society, developing flexible, lightweight, and sustainable supercapacitor systems with large power densities, long cycle life, and ease of strongly required. However, estimating the state-of-charge of existing supercapacitors is difficult, and thus their service life is limited. In this study, we fabricate a flexible color indicative supercapacitor device with mesoporous polyaniline (mPANI)/Poly(N-Isopropyl acrylamide-Graphene Oxide-Acrylic Acid) (P(NiPPAm-GO-AA)) one dimensional photonic crystals (1DPCs) as the electrode material through a low-cost, eco-friendly, and scalable fabrication process. We found that the state-of-charge could be monitored by the structural color oscillation due to the change in the photonic band gap position of the 1DPCs. The flexible 1DPCs supercapacitor is thin at 3 mm and exhibits good specific capacitance of 22.6 F g-1 with retention of 91.1% after 3,000 cycles. This study shows the application of the 1DPCs supercapacitor as a visual ultrathin power source. The technology may find many applications in future wearable electronics.
Nucleation and growth of nanoscaled one-dimensional materials
NASA Astrophysics Data System (ADS)
Cui, Hongtao
Nanoscaled one-dimensional materials have attracted great interest due to their novel physical and chemical properties. The purpose of this dissertation is to study the nucleation and growth mechanisms of carbon nanotubes and silicon nitride nanowires with their field emission applications in mind. As a result of this research, a novel methodology has been developed to deposit aligned bamboo-like carbon nanotubes on substrates using a methane and ammonia mixture in microwave plasma enhanced chemical deposition. Study of growth kinetics suggests that the carbon diffusion through bulk catalyst particles controls growth in the initial deposition process. Microstructures of carbon nanotubes are affected by the growth temperature and carbon concentration in the gas phase. High-resolution transmission electron microscope confirms the existence of the bamboo-like structure. Electron diffraction reveals that the iron-based catalyst nucleates and sustains the growth of carbon nanotubes. A nucleation and growth model has been constructed based upon experimental data and observations. In the study of silicon nitride nanoneedles, a vapor-liquid-solid model is employed to explain the nucleation and growth processes. Ammonia plasma etching is proposed to reduce the size of the catalyst and subsequently produce the novel needle-like nanostructure. High-resolution transmission electron microscope shows the structure is well crystallized and composed of alpha-silicon nitride. Other observations in the structure are also explained.
Dispersive excitations in one-dimensional ionic Hubbard model
NASA Astrophysics Data System (ADS)
Hafez Torbati, M.; Drescher, Nils A.; Uhrig, Götz S.
2014-06-01
A detailed study of the one-dimensional ionic Hubbard model with interaction U is presented. We focus on the band insulating (BI) phase and the spontaneously dimerized insulating (SDI) phase which appears on increasing U. By a recently introduced continuous unitary transformation [H. Krull et al., Phys. Rev. B 86, 125113 (2012), 10.1103/PhysRevB.86.125113] we are able to describe the system even close to the phase transition from BI to SDI although the bare perturbative series diverges before the transition is reached. First, the dispersion of single fermionic quasiparticles is determined in the full Brillouin zone. Second, we describe the binding phenomena between two fermionic quasiparticles leading to an S =0 and to an S =1 exciton. The latter corresponds to the lowest spin excitation and defines the spin gap which remains finite through the transition from BI to SDI. The former becomes soft at the transition, indicating that the SDI corresponds to a condensate of these S =0 excitons. This view is confirmed by a BCS mean-field theory for the SDI phase.
Majorana Fermions in Disordered Quasi-One-Dimensional Topological Superconductors
NASA Astrophysics Data System (ADS)
Potter, Andrew; Lee, Patrick
2012-02-01
Majorana fermions have long been predicted to emerge in certain quantum Hall states and other naturally occurring p-wave superconductors. However, these materials are quite delicate and consequently the experimental realization of Majorana fermions remains elusive. The possibility of engineering 1D networks of topological superconducting wires from conventional materials offers a promising alternative route to realize Majorana fermions and probe their predicted non-Abelian statistics. In practice, it is impossible to fabricate perfectly clean and strictly one-dimensional structures; how do these non-idealities affect the proposed Majorana states? This talk will show that Majorana end states are robust away from the strict 1D limit, so long as the sample width is not much larger than the superconducting coherence length. The effects of disorder are potentially more severe, as impurity scattering is generally pair-breaking and tends to suppress the gap protecting the Majorana modes. Finally, we propose new candidate materials and geometries that greatly simplify the experimental setup and mitigate the harmful effects of disorder.
Topological phase in one-dimensional Rashba wire
NASA Astrophysics Data System (ADS)
Sa-Ke, Wang; Jun, Wang; Jun-Feng, Liu
2016-07-01
We study the possible topological phase in a one-dimensional (1D) quantum wire with an oscillating Rashba spin-orbital coupling in real space. It is shown that there are a pair of particle-hole symmetric gaps forming in the bulk energy band and fractional boundary states residing in the gap when the system has an inversion symmetry. These states are topologically nontrivial and can be characterized by a quantized Berry phase ±π or nonzero Chern number through dimensional extension. When the Rashba spin-orbital coupling varies slowly with time, the system can pump out 2 charges in a pumping cycle because of the spin flip effect. This quantized pumping is protected by topology and is robust against moderate disorders as long as the disorder strength does not exceed the opened energy gap. Project supported by the National Natural Science Foundation of China (Grant Nos. 115074045 and 11204187) and the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20131284).
Single ions trapped in a one-dimensional optical lattice.
Enderlein, Martin; Huber, Thomas; Schneider, Christian; Schaetz, Tobias
2012-12-07
We report on three-dimensional optical trapping of single ions in a one-dimensional optical lattice formed by two counterpropagating laser beams. We characterize the trapping parameters of the standing-wave using the ion as a sensor stored in a hybrid trap consisting of a radio-frequency (rf), a dc, and the optical potential. When loading ions directly from the rf into the standing-wave trap, we observe a dominant heating rate. Monte Carlo simulations confirm rf-induced parametric excitations within the deep optical lattice as the main source. We demonstrate a way around this effect by an alternative transfer protocol which involves an intermediate step of optical confinement in a single-beam trap avoiding the temporal overlap of the standing-wave and the rf field. Implications arise for hybrid (rf-optical) and pure optical traps as platforms for ultracold chemistry experiments exploring atom-ion collisions or quantum simulation experiments with ions, or combinations of ions and atoms.
Topological water wave states in a one-dimensional structure
Yang, Zhaoju; Gao, Fei; Zhang, Baile
2016-01-01
Topological concepts have been introduced into electronic, photonic, and phononic systems, but have not been studied in surface-water-wave systems. Here we study a one-dimensional periodic resonant surface-water-wave system and demonstrate its topological transition. By selecting three different water depths, we can construct different types of water waves - shallow, intermediate and deep water waves. The periodic surface-water-wave system consists of an array of cylindrical water tanks connected with narrow water channels. As the width of connecting channel varies, the band diagram undergoes a topological transition which can be further characterized by Zak phase. This topological transition holds true for shallow, intermediate and deep water waves. However, the interface state at the boundary separating two topologically distinct arrays of water tanks can exhibit different bands for shallow, intermediate and deep water waves. Our work studies for the first time topological properties of water wave systems, and paves the way to potential management of water waves. PMID:27373982
Interspecies tunneling in one-dimensional Bose mixtures
Pflanzer, Anika C.; Zoellner, Sascha; Schmelcher, Peter
2010-02-15
We study the ground-state properties and quantum dynamics of few-boson mixtures with strong interspecies repulsion in one-dimensional traps. If one species localizes at the center, e.g., due to a very large mass compared to the other component, it represents an effective barrier for the latter, and the system can be mapped onto identical bosons in a double well. For weaker localization, the barrier atoms begin to respond to the light component, leading to an induced attraction between the mobile atoms that may even outweigh their bare intraspecies repulsion. To explain the resulting effects, we derive an effective Hubbard model for the lighter species accounting for the back action of the barrier in correction terms to the lattice parameters. Also the tunneling is drastically affected: by varying the degree of localization of the 'barrier' atoms, the dynamics of intrinsically noninteracting bosons can change from Rabi oscillations to effective pair tunneling. For identical fermions (or fermionized bosons), this leads to the tunneling of attractively bound pairs.
One-dimensional kinetics modifications for BWR reload methods
Chandola, V.; Robichaud, J.D.
1990-01-01
Yankee Atomic Electric Company (YAEC) currently uses RETRAN-02 to analyze limiting transients and establish operating minimum critical power ratio (MCPR) limits for Vermont Yankee (VY) boiling water reactor (BWR) reload analysis. The US Nuclear Regulatory Commission-approved analysis methods, used in previous cycles, use the point-kinetics modeling option in RETRAN-02 to represent transient-induced neutronic feedback. RETRAN-02 also contains a one-dimensional (1-D) kinetics neutronic feedback model option that provides a more accurate transient power prediction than the point-kinetics model. In the past few fuel cycles, the thermal or MCPR operating margin at VY has eroded due to increases in fuel cycle length. To offset this decrease, YAEC has developed the capability to use the more accurate 1-D kinetics RETRAN option. This paper reviews the qualification effort for the YAEC BWR methods. This paper also presents a comparison between RETRAN-02 predictions using 1-D and point kinetics for the limiting transient, and demonstrates the typical gain in thermal margin from 1-D kinetics.
Bulk-edge correspondence of one-dimensional quantum walks
NASA Astrophysics Data System (ADS)
Cedzich, C.; Grünbaum, F. A.; Stahl, C.; Velázquez, L.; Werner, A. H.; Werner, R. F.
2016-05-01
We outline a theory of symmetry protected topological phases of one-dimensional quantum walks. We assume spectral gaps around the symmetry-distinguished points +1 and -1, in which only discrete eigenvalues are allowed. The phase classification by integer or binary indices extends the classification known for translation invariant systems in terms of their band structure. However, our theory requires no translation invariance whatsoever, and the indices we define in this general setting are invariant under arbitrary symmetric local perturbations, even those that cannot be continuously contracted to the identity. More precisely we define two indices for every walk, characterizing the behavior far to the right and far to the left, respectively. Their sum is a lower bound on the number of eigenstates at +1 and -1. For a translation invariant system the indices add up to zero, so one of them already characterizes the phase. By joining two bulk phases with different indices we get a walk in which the right and left indices no longer cancel, so the theory predicts bound states at +1 or -1. This is a rigorous statement of bulk-edge correspondence. The results also apply to the Hamiltonian case with a single gap at zero.
Carbyne with finite length: The one-dimensional sp carbon
Pan, Bitao; Xiao, Jun; Li, Jiling; Liu, Pu; Wang, Chengxin; Yang, Guowei
2015-01-01
Carbyne is the one-dimensional allotrope of carbon composed of sp-hybridized carbon atoms. Definitive evidence for carbyne has remained elusive despite its synthesis and preparation in the laboratory. Given the remarkable technological breakthroughs offered by other allotropes of carbon, including diamond, graphite, fullerenes, carbon nanotubes, and graphene, interest in carbyne and its unusual potential properties remains intense. We report the first synthesis of carbyne with finite length, which is clearly composed of alternating single bonds and triple bonds, using a novel process involving laser ablation in liquid. Spectroscopic analyses confirm that the product is the structure of sp hybridization with alternating carbon-carbon single bonds and triple bonds and capped by hydrogen. We observe purple-blue fluorescence emissions from the gap between the highest occupied molecular orbital and the lowest unoccupied molecular orbital of carbyne. Condensed-phase carbyne crystals have a hexagonal lattice and resemble the white crystalline powder produced by drying a carbyne solution. We also establish that the combination of gold and alcohol is crucial to carbyne formation because carbon-hydrogen bonds can be cleaved with the help of gold catalysts under the favorable thermodynamic environment provided by laser ablation in liquid and because the unique configuration of two carbon atoms in an alcohol molecule matches the elementary entity of carbyne. This laboratory synthesis of carbyne will enable the exploration of its properties and applications. PMID:26601318
Transmission properties of one-dimensional ternary plasma photonic crystals
Shiveshwari, Laxmi; Awasthi, S. K.
2015-09-15
Omnidirectional photonic band gaps (PBGs) are found in one-dimensional ternary plasma photonic crystals (PPC) composed of single negative metamaterials. The band characteristics and transmission properties are investigated through the transfer matrix method. We show that the proposed structure can trap light in three-dimensional space due to the elimination of Brewster's angle transmission resonance allowing the existence of complete PBG. The results are discussed in terms of incident angle, layer thickness, dielectric constant of the dielectric material, and number of unit cells (N) for TE and TM polarizations. It is seen that PBG characteristics is apparent even in an N ≥ 2 system, which is weakly sensitive to the incident angle and completely insensitive to the polarization. Finite PPC could be used for multichannel transmission filter without introducing any defect in the geometry. We show that the locations of the multichannel transmission peaks are in the allowed band of the infinite structure. The structure can work as a single or multichannel filter by varying the number of unit cells. Binary PPC can also work as a polarization sensitive tunable filter.
Fractal geometry in an expanding, one-dimensional, Newtonian universe.
Miller, Bruce N; Rouet, Jean-Louis; Le Guirriec, Emmanuel
2007-09-01
Observations of galaxies over large distances reveal the possibility of a fractal distribution of their positions. The source of fractal behavior is the lack of a length scale in the two body gravitational interaction. However, even with new, larger, sample sizes from recent surveys, it is difficult to extract information concerning fractal properties with confidence. Similarly, three-dimensional N-body simulations with a billion particles only provide a thousand particles per dimension, far too small for accurate conclusions. With one-dimensional models these limitations can be overcome by carrying out simulations with on the order of a quarter of a million particles without compromising the computation of the gravitational force. Here the multifractal properties of two of these models that incorporate different features of the dynamical equations governing the evolution of a matter dominated universe are compared. For each model at least two scaling regions are identified. By employing criteria from dynamical systems theory it is shown that only one of them can be geometrically significant. The results share important similarities with galaxy observations, such as hierarchical clustering and apparent bifractal geometry. They also provide insights concerning possible constraints on length and time scales for fractal structure. They clearly demonstrate that fractal geometry evolves in the mu (position, velocity) space. The observed patterns are simply a shadow (projection) of higher-dimensional structure.
One dimensional coordination polymers: Synthesis, crystal structures and spectroscopic properties
NASA Astrophysics Data System (ADS)
Karaağaç, Dursun; Kürkçüoğlu, Güneş Süheyla; Şenyel, Mustafa; Şahin, Onur
2016-11-01
Two new one dimensional (1D) cyanide complexes, namely [M(4-aepy)2(H2O)2][Pt(CN)4], (4-aepy = 4-(2-aminoethyl)pyridine M = Cu(II) (1) or Zn(II) (2)), have been synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction, thermal and elemental analyses techniques. The crystallographic analyses reveal that 1 and 2 are isomorphous and isostructural, and crystallize in the monoclinic system and C2 space group. The Pt(II) ions are coordinated by four cyanide-carbon atoms in the square-planar geometry and the [Pt(CN)4]2- ions act as a counter ion. The M(II) ions display an N4O2 coordination sphere with a distorted octahedral geometry, the nitrogen donors belonging to four molecules of the organic 4-aepy that act as unidentate ligands and two oxygen atoms from aqua ligands. The crystal structures of 1 and 2 are similar each other and linked via intermolecular hydrogen bonding, Pt⋯π interactions to form 3D supramolecular network. Vibration assignments of all the observed bands are given and the spectral features also supported to the crystal structures of the complexes.
One-dimensional simulation of lanthanide isotachophoresis using COMSOL.
Dixon, Derek R; Clark, Sue B; Ivory, Cornelius F
2012-03-01
Electrokinetic separations can be used to quickly separate rare earth metals to determine their forensic signature. In this work, we simulate the concentration and separation of trivalent lanthanide cations by isotachophoresis. A one-dimensional simulation is developed using COMSOL v4.0a, a commercial finite element simulator, to represent the isotachophoretic separation of three lanthanides: lanthanum, terbium, and lutetium. The binding ligand chosen for complexation with the lanthanides is α-hydroxyisobutyric acid (HIBA) and the buffer system includes acetate, which also complexes with the lanthanides. The complexes formed between the three lanthanides, HIBA, and acetate are all considered in the simulation. We observe that the presence of only lanthanide:HIBA complexes in a buffer system with 10 mM HIBA causes the slowest lanthanide peak (lutetium) to split from the other analytes. The addition of lanthanide:acetate complexes into the simulation of the same buffer system eliminates this splitting. Decreasing the concentration of HIBA in the buffer to 7 mM causes the analyte stack to migrate faster through the capillary.
Automated quantification of one-dimensional nanostructure alignment on surfaces
NASA Astrophysics Data System (ADS)
Dong, Jianjin; Goldthorpe, Irene A.; Mohieddin Abukhdeir, Nasser
2016-06-01
A method for automated quantification of the alignment of one-dimensional (1D) nanostructures from microscopy imaging is presented. Nanostructure alignment metrics are formulated and shown to be able to rigorously quantify the orientational order of nanostructures within a two-dimensional domain (surface). A complementary image processing method is also presented which enables robust processing of microscopy images where overlapping nanostructures might be present. Scanning electron microscopy (SEM) images of nanowire-covered surfaces are analyzed using the presented methods and it is shown that past single parameter alignment metrics are insufficient for highly aligned domains. Through the use of multiple parameter alignment metrics, automated quantitative analysis of SEM images is shown to be possible and the alignment characteristics of different samples are able to be quantitatively compared using a similarity metric. The results of this work provide researchers in nanoscience and nanotechnology with a rigorous method for the determination of structure/property relationships, where alignment of 1D nanostructures is significant.
Cooperative eigenmodes and scattering in one-dimensional atomic arrays
NASA Astrophysics Data System (ADS)
Bettles, Robert J.; Gardiner, Simon A.; Adams, Charles S.
2016-10-01
Collective coupling between dipoles can dramatically modify the optical response of a medium. Such effects depend strongly on the geometry of the medium and the polarization of the light. Using a classical coupled dipole model, here we investigate the simplest case of one-dimensional arrays of interacting atomic dipoles driven by a weak laser field. Changing the polarization and direction of the driving field allows us to separately address superradiant, subradiant, redshifted, and blueshifted eigenmodes, as well as observe strong Fano-like interferences between different modes. The cooperative eigenvectors can be characterized by the phase difference between nearest-neighbor dipoles, ranging from all oscillating in phase to all oscillating out of phase with their nearest neighbors. Investigating the eigenvalue behavior as a function of atom number and lattice spacing, we find that certain eigenmodes of an infinite atomic chain have the same decay rate as a single atom between two mirrors. The effects we observe provide a framework for collective control of the optical response of a medium, giving insight into the behavior of more complicated geometries, as well as providing further evidence for the dipolar analog of cavity QED.
Digital noise generators using one-dimensional chaotic maps
Martínez-Ñonthe, J. A; Palacios-Luengas, L.; Cruz-Irisson, M.; Vazquez Medina, R.; Díaz Méndez, J. A.
2014-05-15
This work shows how to improve the statistical distribution of signals produced by digital noise generators designed with one-dimensional (1-D) chaotic maps. It also shows that in a digital electronic design the piecewise linear chaotic maps (PWLCM) should be considered because they do not have stability islands in its chaotic behavior region, as it occurs in the case of the logistic map, which is commonly used to build noise generators. The design and implementation problems of the digital noise generators are analyzed and a solution is proposed. This solution relates the output of PWLCM, usually defined in the real numbers' domain, with a codebook of S elements, previously defined. The proposed solution scheme produces digital noise signals with a statistical distribution close to a uniform distribution. Finally, this work shows that it is possible to have control over the statistical distribution of the noise signal by selecting the control parameter of the PWLCM and using, as a design criterion, the bifurcation diagram.
Conjugated Molecules Described by a One-Dimensional Dirac Equation.
Ernzerhof, Matthias; Goyer, Francois
2010-06-08
Starting from the Hückel Hamiltonian of conjugated hydrocarbon chains (ethylene, allyl radical, butadiene, pentadienyl radical, hexatriene, etc.), we perform a simple unitary transformation and obtain a Dirac matrix Hamiltonian. Thus already small molecules are described exactly in terms of a discrete Dirac equation, the continuum limit of which yields a one-dimensional Dirac Hamiltonian. Augmenting this Hamiltonian with specially adapted boundary conditions, we find that all the orbitals of the unsaturated hydrocarbon chains are reproduced by the continuous Dirac equation. However, only orbital energies close to the highest occupied molecular orbital/lowest unoccupied molecular orbital energy are accurately predicted by the Dirac equation. Since it is known that a continuous Dirac equation describes the electronic structure of graphene around the Fermi energy, our findings answer the question to what extent this peculiar electronic structure is already developed in small molecules containing a delocalized π-electron system. We illustrate how the electronic structure of small polyenes carries over to a certain class of rectangular graphene sheets and eventually to graphene itself. Thus the peculiar electronic structure of graphene extends to a large degree to the smallest unsaturated molecule (ethylene).
Malve, Olli; Salo, Simo; Verta, Matti; Forsius, John
2003-08-01
River Kymijoki, the fourth largest river in Finland, has been heavily polluted by pulp mill effluents as well as by chemical industry. Loading has been reduced considerably, although remains of past emissions still exist in river sediments. The sediments are highly contaminated with polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated diphenyl ethers (PCDEs), and mercury originating from production of the chlorophenolic wood preservative (Ky-5) and other sources. The objective of this study was to simulate the transport of these PCDD/F compounds with a one-dimensional flow and transport model and to assess the impact of restoration dredging. Using the estimated trend in PCDD/F loading, downstream concentrations were calculated until 2020. If contaminated sediments are removed by dredging, the temporary increase of PCDD/F concentrations in downstream water and surface sediments will be within acceptable limits. Long-term predictions indicated only a minor decrease in surface sediment concentrations but a major decrease if the most contaminated sediments close to the emission source were removed. A more detailed assessment of the effects is suggested.
Chemical contaminants in the Wadden Sea: Sources, transport, fate and effects
NASA Astrophysics Data System (ADS)
Laane, R. W. P. M.; Vethaak, A. D.; Gandrass, J.; Vorkamp, K.; Köhler, A.; Larsen, M. M.; Strand, J.
2013-09-01
The Wadden Sea receives contaminants from various sources and via various transport routes. The contaminants described in this overview are various metals (Cd, Cu, Hg, Pb and Zn) and various organic contaminants (polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and lindane (hexachlorocyclohexane, γ-HCH)). In addition, information is presented about other and emerging contaminants such as antifouling biocides (e.g. TBT and Irgarol), brominated flame retardants (BFRs), poly- and perfluorinated compounds (PFCs) and pharmaceutical and personal care products (PPCPs). Special attention is given to biogeochemical processes that contribute to the mobilization of contaminants in the surface sediments of the Wadden Sea. Finally, the effects on organisms of contaminants are reviewed and discussed. The main source of contaminants in the Wadden Sea are the rivers Rhine (via de Dutch coastal zone), Elbe and Weser. The Wadden Sea is not a sink for contaminants and adsorbed contaminants are transported from east to west. The surface sediments of the Wadden Sea are an important source for contaminants to the water above. The input and concentration of most contaminants have significantly decreased in water, sediments, organisms (e.g., mussel, flounder and bird eggs) in various parts of the Wadden Sea in the last three decades. Remarkably, the Cd concentration in mussels is increasing the last decades. In recent decades, the effects of contaminants on organisms (e.g., flounder, seal) have fallen markedly. Most of the affected populations have recovered, except for TBT induced effects in snails. Little is known about the concentration and effects of most emerging contaminants and the complex environmental mixtures of contaminants. It is recommended to install an international coordinated monitoring programme for contaminants and their effects in the whole Wadden Sea and to identify the chemical contaminants that really cause the effect.
NASA Astrophysics Data System (ADS)
Zhou, L.; Gong, Z. R.; Liu, Y. X.; Sun, C. P.; Nori, F.
2010-03-01
We analyze the coherent transport of a single photon, which propagates in a one-dimensional coupled-resonator waveguide and is scattered by a controllable two-level system located inside one of the resonators of this waveguide. Our approach, which uses discrete coordinates, unifies low and high energy effective theories for single-photon scattering. We show that the controllable two-level system can behave as a quantum switch for the coherent transport of a single photon. This study may inspire new electro-optical single-photon quantum devices. We also suggest an experimental setup based on superconducting transmission line resonators and qubits. References: L. Zhou, Z.R. Gong, Y.X. Liu, C.P. Sun, F. Nori, Controllable scattering of photons inside a one-dimensional resonator waveguide, Phys. Rev. Lett. 101, 100501 (2008). L. Zhou, H. Dong, Y.X. Liu, C.P. Sun, F. Nori, Quantum super-cavity with atomic mirrors, Phys. Rev. A 78, 063827 (2008).
Lü, Xiaoling; Jiang, Liwei; Zheng, Yisong
2014-01-22
Analytic solutions of the quasi-one-dimensional (q1D) electron states around an extended line defect in a graphene lattice are derived within the tight-binding model. Then, the electronic properties of this kind of boundary state in graphene are studied in detail. It is found that one subband composed of the even-parity boundary states emerges in the vicinity of the Dirac point. In particular, when the bulk band is gapped, such a one-dimensional subband remains in the bandgap, spanning two inequivalent valleys. In addition, this boundary state subband exhibits nontrivial dispersion, which can carry the valley polarized charge current flowing along the extended line defect. As a result, the line defect behaves like a one-dimensional channel for electronic transport. Moreover, its appearance in graphene or a hexagonal boron nitride sheet provides a promising way to print electric circuits in these two-dimensional materials.
NASA Astrophysics Data System (ADS)
Yen, C. T.; Tiller, W. A.
1992-03-01
A one-dimensional mathematical analysis is made of the redistribution of solute which occurs during crystal growth from a convected melt. In this analysis, the important contribution from lateral melt convection to one-dimensional solute redistribution analysis is taken into consideration via an annihilation/creation term in the one-dimensional solute transport equation. Calculations of solute redistribution under steady-state conditions have been carried out analytically. It is found that this new solute redistribution model overcomes several weaknesses that occur when applying the Burton, Prim and Slichter solute segregation equation (1953) in real melt growth situations. It is also found that, with this correction, the diffusion coefficients for solute's in liquid silicon are now found to be in the same range as other liquid metal diffusion coefficients.
Technology Transfer Automated Retrieval System (TEKTRAN)
Improving strategies for monitoring subsurface contaminant transport includes performance comparison of competing models, developed independently or obtained via model abstraction. Model comparison and parameter discrimination involve specific performance indicators selected to better understand s...
Investigations at Pinal Creek, Arizona, evaluated routine sampling procedures for determination of aqueous inorganic geochemistry and assessment of contaminant transport by colloidal mobility. Sampling variables included pump type and flow rate, collection under air or nitrogen,...
ONE-DIMENSIONAL ACCELERATOR IN PULSAR OUTER MAGNETOSPHERE REVISITED
Lin, G. F.; Zhang, L.
2009-07-10
We re-examine the one-dimensional (1D) vacuum and nonvacuum accelerators in the outer magnetosphere of rotation-powered pulsars by considering the limit of trans-field height through pair-production process. In the original 1D nonvacuum outer gap model, both the Poisson equation for electrical potential and the Boltzmann equations of particles and gamma-rays are solved self-consistently by assuming the trans-field height as a free parameter, usually resulting in a narrow outer gap (i.e., gap length along magnetic field lines is short). In the modified 1D nonvacuum outer gap model, two improvements have been made: the trans-field height is limited by photon-photon pair production process and the outer boundary of the outer gap can be extended outside the light cylinder. Under the above assumptions, we self-consistently solve the Poisson equation for electrical potential, and the Boltzmann equations of electrons/positrons and gamma-rays in both vacuum and nonvacuum outer gaps for the parameters of both Vela and Geminga pulsars. We obtain an approximate geometry of the outer gap, i.e., the trans-field height is limited by the pair-production process and increases with the radial distance to the star, and the width of the outer gap starts at the inner boundary (near the null charge surface in the vacuum case) and ends at the outer boundary which is located inside or outside the light cylinder depending on the inclination angle. Our calculated results also indicate that gamma-ray spectrum from a wide outer gap is flatter than the one from a narrow outer gap and the relation between the electric field and trans-field height has an important effect on the structure of the outer gap.
Filtration-guided assembly for patterning one-dimensional nanostructures.
Zhang, Yaozhong; Wang, Chuan; Yeom, Junghoon
2017-04-07
Tremendous progress has been made in synthesizing various types of one-dimensional (1D) nanostructures (NSs), such as nanotubes and nanowires, but some technical challenges still remain in the deterministic assembly of the solution-processed 1D NSs for device integration. In this work we investigate a scalable yet inexpensive nanomaterial assembly method, namely filtration-guided assembly (FGA), to place nanomaterials into desired locations as either an individual entity or ensembles, and form functional devices. FGA not only addresses the assembly challenges but also encompasses the notion of green nanomanufacturing, maximally utilizing nanomaterials and eliminating a waste stream of nanomaterials into the environment. FGA utilizes selective filtration of 1D NSs through the open windows on the nanoporous filter membrane whose surface is patterned by a polymer mask for guiding the 1D NS deposition. The modified soft-lithographic technique called blanket transfer (BT) is employed to create the various photoresist patterns of sub-10-micron resolution on the nanoporous filter membrane like mixed cellulose acetate. We use single-walled carbon nanotubes (SWCNTs) as a model 1D NS and demonstrate the fabrication of an array pattern of homogeneous 1D NS network films over an area of 20 cm(2) within 10 min. The FGA-patterned SWCNT network films are transferred onto the substrate using the adhesive-based transfer technique, and show the highly uniform film thickness and resistance measurements across the entire substrate. Finally, the electrical performance of the back-gated transistors made from the FGA and transfer method of 95% pure SWCNTs is demonstrated.
One-dimensional semirelativistic Hamiltonian with multiple Dirac delta potentials
NASA Astrophysics Data System (ADS)
Erman, Fatih; Gadella, Manuel; Uncu, Haydar
2017-02-01
In this paper, we consider the one-dimensional semirelativistic Schrödinger equation for a particle interacting with N Dirac delta potentials. Using the heat kernel techniques, we establish a resolvent formula in terms of an N ×N matrix, called the principal matrix. This matrix essentially includes all the information about the spectrum of the problem. We study the bound state spectrum by working out the eigenvalues of the principal matrix. With the help of the Feynman-Hellmann theorem, we analyze how the bound state energies change with respect to the parameters in the model. We also prove that there are at most N bound states and explicitly derive the bound state wave function. The bound state problem for the two-center case is particularly investigated. We show that the ground state energy is bounded below, and there exists a self-adjoint Hamiltonian associated with the resolvent formula. Moreover, we prove that the ground state is nondegenerate. The scattering problem for N centers is analyzed by exactly solving the semirelativistic Lippmann-Schwinger equation. The reflection and the transmission coefficients are numerically and asymptotically computed for the two-center case. We observe the so-called threshold anomaly for two symmetrically located centers. The semirelativistic version of the Kronig-Penney model is shortly discussed, and the band gap structure of the spectrum is illustrated. The bound state and scattering problems in the massless case are also discussed. Furthermore, the reflection and the transmission coefficients for the two delta potentials in this particular case are analytically found. Finally, we solve the renormalization group equations and compute the beta function nonperturbatively.
Spatial modes in one-dimensional models for capillary jets
NASA Astrophysics Data System (ADS)
Guerrero, J.; González, H.; García, F. J.
2016-03-01
One-dimensional (1D) models are widely employed to simplify the analysis of axisymmetric capillary jets. These models postulate that, for slender deformations of the free surface, the radial profile of the axial velocity can be approximated as uniform (viscous slice, averaged, and Cosserat models) or parabolic (parabolic model). In classical works on spatial stability analysis with 1D models, considerable misinterpretation was generated about the modes yielded by each model. The already existing physical analysis of three-dimensional (3D) axisymmetric spatial modes enables us to relate these 1D spatial modes to the exact 3D counterparts. To do so, we address the surface stimulation problem, which can be treated as linear, by considering the effect of normal and tangential stresses to perturb the jet. A Green's function for a spatially local stimulation having a harmonic time dependence provides the general formalism to describe any time-periodic stimulation. The Green's function of this signaling problem is known to be a superposition of the spatial modes, but in fact these modes are of fundamental nature, i.e., not restricted to the surface stimulation problem. The smallness of the wave number associated with each mode is the criterion to validate or invalidate the 1D approaches. The proposed axial-velocity profiles (planar or parabolic) also have a remarkable influence on the outcomes of each 1D model. We also compare with the classical 3D results for (i) conditions for absolute instability, and (ii) the amplitude of the unstable mode resulting from both normal and tangential surface stress stimulation. Incidentally, as a previous task, we need to re-deduce 1D models in order to include eventual stresses of various possible origins (electrohydrodynamic, thermocapillary, etc.) applied on the free surface, which were not considered in the previous general formulations.
Filtration-guided assembly for patterning one-dimensional nanostructures
NASA Astrophysics Data System (ADS)
Zhang, Yaozhong; Wang, Chuan; Yeom, Junghoon
2017-04-01
Tremendous progress has been made in synthesizing various types of one-dimensional (1D) nanostructures (NSs), such as nanotubes and nanowires, but some technical challenges still remain in the deterministic assembly of the solution-processed 1D NSs for device integration. In this work we investigate a scalable yet inexpensive nanomaterial assembly method, namely filtration-guided assembly (FGA), to place nanomaterials into desired locations as either an individual entity or ensembles, and form functional devices. FGA not only addresses the assembly challenges but also encompasses the notion of green nanomanufacturing, maximally utilizing nanomaterials and eliminating a waste stream of nanomaterials into the environment. FGA utilizes selective filtration of 1D NSs through the open windows on the nanoporous filter membrane whose surface is patterned by a polymer mask for guiding the 1D NS deposition. The modified soft-lithographic technique called blanket transfer (BT) is employed to create the various photoresist patterns of sub-10-micron resolution on the nanoporous filter membrane like mixed cellulose acetate. We use single-walled carbon nanotubes (SWCNTs) as a model 1D NS and demonstrate the fabrication of an array pattern of homogeneous 1D NS network films over an area of 20 cm2 within 10 min. The FGA-patterned SWCNT network films are transferred onto the substrate using the adhesive-based transfer technique, and show the highly uniform film thickness and resistance measurements across the entire substrate. Finally, the electrical performance of the back-gated transistors made from the FGA and transfer method of 95% pure SWCNTs is demonstrated.
One dimensional blood flow in a planetocentric orbit
NASA Astrophysics Data System (ADS)
Haranas, Ioannis; Gkigkitzis, Ioannis
2012-05-01
All life on earth is accustomed to the presence of gravity. When gravity is altered, biological processes can go awry. It is of great importance to ensure safety during a spaceflight. Long term exposure to microgravity can trigger detrimental physiological responses in the human body. Fluid redistribution coupled with fluid loss is one of the effects. In particular, in microgravity blood volume is shifted towards the thorax and head. Sympathetic nervous system-induced vasoconstriction is needed to maintain arterial pressure, while venoconstriction limits venous pooling of blood prevents further reductions in venous return of blood to the heart. In this paper, we modify an existing one dimensional blood flow model with the inclusion of the hydrostatic pressure gradient that further depends on the gravitational field modified by the oblateness and rotation of the Earth. We find that the velocity of the blood flow VB is inversely proportional to the blood specific volume d, also proportional to the oblateness harmonic coefficient J2, the angular velocity of the Earth ωE, and finally proportional to an arbitrary constant c. For c = -0.39073 and ξH = -0.5 mmHg, all orbits result to less blood flow velocities than that calculated on the surface of the Earth. From all considered orbits, elliptical polar orbit of eccentricity e = 0.2 exhibit the largest flow velocity VB = 1.031 m/s, followed by the orbits of inclination i = 45°and 0°. The Earth's oblateness and its rotation contribute a 0.7% difference to the blood flow velocity.
Spectroscopy of one-dimensionally inhomogeneous media with quadratic nonlinearity
Golubkov, A A; Makarov, Vladimir A
2011-11-30
We present a brief review of the results of fifty years of development efforts in spectroscopy of one-dimensionally inhomogeneous media with quadratic nonlinearity. The recent original results obtained by the authors show the fundamental possibility of determining, from experimental data, the coordinate dependences of complex quadratic susceptibility tensor components of a onedimensionally inhomogeneous (along the z axis) medium with an arbitrary frequency dispersion, if the linear dielectric properties of the medium also vary along the z axis and are described by a diagonal tensor of the linear dielectric constant. It is assumed that the medium in question has the form of a plane-parallel plate, whose surfaces are perpendicular to the direction of the inhomogeneity. Using the example of several components of the tensors X{sup (2)}(z, {omega}{sub 1} {+-} {omega}{sub 2}; {omega}{sub 1}, {+-} {omega}{sub 2}), we describe two methods for finding their spatial profiles, which differ in the interaction geometry of plane monochromatic fundamental waves with frequencies {omega}{sub 1} and {omega}{sub 2}. The both methods are based on assessing the intensity of the waves propagating from the plate at the sum or difference frequency and require measurements over a range of angles of incidence of the fundamental waves. Such measurements include two series of additional estimates of the intensities of the waves generated under special conditions by using the test and additional reference plates, which eliminates the need for complicated phase measurements of the complex amplitudes of the waves at the sum (difference) frequency.
MULTI-IFE-A one-dimensional computer code for Inertial Fusion Energy (IFE) target simulations
NASA Astrophysics Data System (ADS)
Ramis, R.; Meyer-ter-Vehn, J.
2016-06-01
The code MULTI-IFE is a numerical tool devoted to the study of Inertial Fusion Energy (IFE) microcapsules. It includes the relevant physics for the implosion and thermonuclear ignition and burning: hydrodynamics of two component plasmas (ions and electrons), three-dimensional laser light ray-tracing, thermal diffusion, multigroup radiation transport, deuterium-tritium burning, and alpha particle diffusion. The corresponding differential equations are discretized in spherical one-dimensional Lagrangian coordinates. Two typical application examples, a high gain laser driven capsule and a low gain radiation driven marginally igniting capsule are discussed. In addition to phenomena relevant for IFE, the code includes also components (planar and cylindrical geometries, transport coefficients at low temperature, explicit treatment of Maxwell's equations) that extend its range of applicability to laser-matter interaction at moderate intensities (<1016 W cm-2). The source code design has been kept simple and structured with the aim to encourage user's modifications for specialized purposes.
One-Dimensional Poole-Frenkel Conduction in the Single Defect Limit.
Pan, Deng; Fuller, Elliot J; Gül, O Tolga; Collins, Philip G
2015-08-12
A single point defect surrounded on either side by quasi-ballistic, semimetallic carbon nanotube is a nearly ideal system for investigating disorder in one-dimensional (1D) conductors and comparing experiment to theory. Here, individual single-walled nanotubes (SWNTs) are investigated before and after the incorporation of single point defects. Transport and local Kelvin Probe force microscopy independently demonstrate high-resistance depletion regions over 1.0 μm wide surrounding one point defect in semimetallic SWNTs. Transport measurements show that conductance through such wide depletion regions occurs via a modified, 1D version of Poole-Frenkel field-assisted emission. Given the breadth of theory dedicated to the possible effects of disorder in 1D systems, it is surprising that a Poole-Frenkel mechanism appears to describe defect scattering and resistance in this semimetallic system.
Moment-Preserving SN Discretizations for the One-Dimensional Fokker-Planck Equation
Warsa, James S.; Prinja, Anil K.
2012-06-14
The Fokker-Planck equation: (1) Describes the transport and interactions of charged particles, (2) Many small-angle scattering collisions, (3) Asymptotic limit of the Boltzmann equation (Pomraning, 1992), and (4) The Boltzmann collision operator becomes the angular Laplacian. SN angular discretization: (1) Angular flux is collocated at the SN quadrature points, (2) The second-order derivatives in the Laplacian term must be discretized, and (3) Weighted finite-difference method preserves zeroth and first moments (Morel, 1985). Moment-preserving methods: (1) Collocate the Fokker-Planck operator at the SN quadrature points, (2) Develop several related and/or equivalent methods, and (3) Motivated by discretizations for the angular derivative appearing in the transport equation in one-dimensional spherical coordinates.
NASA Astrophysics Data System (ADS)
Teichert, Fabian; Zienert, Andreas; Schuster, Jörg; Schreiber, Michael
2017-04-01
We derive an improved version of the recursive Green's function formalism (RGF), which is a standard tool in the quantum transport theory. We consider the case of disordered quasi one-dimensional materials where the disorder is applied in form of randomly distributed realistic defects, leading to partly periodic Hamiltonian matrices. The algorithm accelerates the common RGF in the recursive decimation scheme, using the iteration steps of the renormalization decimation algorithm. This leads to a smaller effective system, which is treated using the common forward iteration scheme. The computational complexity scales linearly with the number of defects, instead of linearly with the total system length for the conventional approach. We show that the scaling of the calculation time of the Green's function depends on the defect density of a random test system. Furthermore, we discuss the calculation time and the memory requirement of the whole transport formalism applied to defective carbon nanotubes.
Controllable scattering of photons in a one-dimensional resonator waveguide
NASA Astrophysics Data System (ADS)
Sun, C. P.; Zhou, L.; Gong, Z. R.; Liu, Y. X.; Nori, F.
2009-03-01
We analyze the coherent transport of a single photon, which propagates in a one-dimensional coupled-resonator waveguide and is scattered by a controllable two-level system located inside one of the resonators of this waveguide. Our approach, which uses discrete coordinates, unifies low and high energy effective theories for single-photon scattering. We show that the controllable two-level system can behave as a quantum switch for the coherent transport of a single photon. This study may inspire new electro-optical single-photon quantum devices. We also suggest an experimental setup based on superconducting transmission line resonators and qubits. [4pt] L. Zhou, Z.R. Gong, Y.X. Liu, C.P. Sun, F. Nori, Controllable scattering of photons in a 1D resonator waveguide, Phys. Rev. Lett. 101, 100501 (2008). URL: http://link.aps.org/abstract/PRL/v101/e100501
Bai, Chunmei; Li, Yusong
2014-08-01
Accurately predicting the transport of contaminants in the field is subject to multiple sources of uncertainty due to the variability of geological settings, the complexity of field measurements, and the scarcity of data. Such uncertainties can be amplified when modeling some emerging contaminants, such as engineered nanomaterials, when a fundamental understanding of their fate and transport is lacking. Typical field work includes collecting concentration at a certain location for an extended period of time, or measuring the movement of plume for an extended period time, which would result in a time series of observation data. This work presents an effort to evaluate the possibility of applying time series analysis, particularly, autoregressive integrated moving average (ARIMA) models, to forecast contaminant transport and distribution in the subsurface environment. ARIMA modeling was first assessed in terms of its capability to forecast tracer transport at two field sites, which had different levels of heterogeneity. After that, this study evaluated the applicability of ARIMA modeling to predict the transport of engineered nanomaterials at field sites, including field measured data of nanoscale zero valent iron and (nZVI) and numerically generated data for the transport of nano-fullerene aggregates (nC60). This proof-of-concept effort demonstrates the possibility of applying ARIMA to predict the contaminant transport in the subsurface environment. Like many other statistical models, ARIMA modeling is only descriptive and not explanatory. The limitation and the challenge associated with applying ARIMA modeling to contaminant transport in the subsurface are also discussed.
NASA Astrophysics Data System (ADS)
Bai, Chunmei; Li, Yusong
2014-08-01
Accurately predicting the transport of contaminants in the field is subject to multiple sources of uncertainty due to the variability of geological settings, the complexity of field measurements, and the scarcity of data. Such uncertainties can be amplified when modeling some emerging contaminants, such as engineered nanomaterials, when a fundamental understanding of their fate and transport is lacking. Typical field work includes collecting concentration at a certain location for an extended period of time, or measuring the movement of plume for an extended period time, which would result in a time series of observation data. This work presents an effort to evaluate the possibility of applying time series analysis, particularly, autoregressive integrated moving average (ARIMA) models, to forecast contaminant transport and distribution in the subsurface environment. ARIMA modeling was first assessed in terms of its capability to forecast tracer transport at two field sites, which had different levels of heterogeneity. After that, this study evaluated the applicability of ARIMA modeling to predict the transport of engineered nanomaterials at field sites, including field measured data of nanoscale zero valent iron and (nZVI) and numerically generated data for the transport of nano-fullerene aggregates (nC60). This proof-of-concept effort demonstrates the possibility of applying ARIMA to predict the contaminant transport in the subsurface environment. Like many other statistical models, ARIMA modeling is only descriptive and not explanatory. The limitation and the challenge associated with applying ARIMA modeling to contaminant transport in the subsurface are also discussed.
Iwasaki, T; Nabi, M; Shimizu, Y; Kimura, I
2015-01-01
A numerical model capable of simulating the transfer of (137)Cs in rivers associated with transport of fine sediment is presented. The accident at Fukushima Dai-ichi Nuclear Power Plant (FDNPP) released radionuclides into the atmosphere, and after fallout several radionuclides in them, such as radiocesium ((134)Cs, (137)Cs) and radioiodine ((131)I) were adsorbed on surface soil particles around FDNPP and transported by surface water. To understand the transport and deposition of the radioactive contaminant along with surface soil particles and its flux to the ocean, we modeled the transport of the (137)Cs contaminant by computing the water flow and the associated washload and suspended load transport. We have developed a two-dimensional model to simulate the plane flow structure, sediment transport and associated (137)Cs contaminant transport in rivers by combining a shallow water flow model and an advection-diffusion equation for the transport of sediment. The proposed model has been applied to the lower reach of Abukuma River, which is the main river in the highly contaminated area around FDNPP. The numerical results indicate that most (137)Cs supplied from the upstream river reach with washload would directly reach to Pacific Ocean. In contrast, washload-oriented (137)Cs supplied from the upstream river basin has a limited role in the radioactive contamination in the river. The results also suggest that the proposed framework of computational model can be a potential tool for understanding the sediment-oriented (137)Cs behavior in rivers.
Characterization of Contaminant Transport Using Naturally-Occurring U-Series Disequilibria
TEH-LUNG KU
2001-06-01
Study the migration of nuclear waste contaminants in subsurface fractured systems using naturally occurring uranium and thorium-series radionuclides as tracers under in-situ physico-chemical and hydrogeologic conditions. Radioactive disequilibria among members of these decay-series nuclides can provide information on the rates of adsorption-desorption and transport of contaminants as well as on fluid transport and rock dissolution in a natural setting.
Truex, Michael J.; Oostrom, Martinus; Tartakovsky, Guzel D.
2015-09-01
An approach was developed for evaluating vadose zone transport and attenuation of aqueous wastes containing inorganic (non-volatile) contaminants that were disposed of at the land surface (i.e., directly to the ground in cribs, trenches, tile fields, etc.) and their effect on the underlying groundwater. The approach provides a structured method for estimating transport of contaminants through the vadose zone and the resulting temporal profile of groundwater contaminant concentrations. The intent of the approach is also to provide a means for presenting and explaining the results of the transport analysis in the context of the site-specific waste disposal conditions and site properties, including heterogeneities and other complexities. The document includes considerations related to identifying appropriate monitoring to verify the estimated contaminant transport and associated predictions of groundwater contaminant concentrations. While primarily intended for evaluating contaminant transport under natural attenuation conditions, the approach can also be applied to identify types of, and targets for, mitigation approaches in the vadose zone that would reduce the temporal profile of contaminant concentrations in groundwater, if needed.
BIOPLUME MODEL FOR CONTAMINANT TRANSPORT AFFECTED BY OXYGEN LIMITED BIODEGRADATION
Many of the organic pollutants entering ground water are potentially biodegradable in the subsurface. This potential has been demonstrated in aquifers contaminated by wood-creosoting process wastes. The persistence of many of these organic compounds in the subsurface indicated ...
Intermolecular band dispersion in quasi-one-dimensional adenine assemblies.
Wang, Ying; Fleurence, Antoine; Yamada-Takamura, Yukiko; Friedlein, Rainer
2011-12-07
Highly-ordered, hydrated adenine multilayer films grown on the surface of highly-oriented pyrolytic graphite, HOPG(0001), display extended electronic states, affording anisotropic band-like charge transport along the π-π stacking direction.
Large-Scale Sediment Routing: Development of a One-Dimensional Model Incorporating Sand Storage
NASA Astrophysics Data System (ADS)
Wiele, S. M.; Wilcock, P. R.; Grams, P. E.
2005-12-01
Routing sediment through long reaches and networks requires a balance between model efficiency, data availability, and accurate representation of sediment flux and storage. The first two often constrain the appropriate model to one dimension, but such models are unable to capture changes in sediment storage in side-channel environments, which are typically driven by two-dimensional transport fields. Side-channel environments are especially important in canyon channels. Routing of sand in canyon channels can be further complicated by transport of sand over a cobble or boulder bed and by remote locations, which can hinder measurement of channel shape. We have produced a one-dimensional model that routes water and sand through the Colorado River below Glen Canyon Dam in Arizona. Our model differs from conventional one-dimensional models in several significant ways: (1) exchange of sand between the main downstream current and eddies, which cannot be directly represented by a one-dimensional model, is included by parameterizing predictions over a wide range of conditions from a multidimensional model; (2) suspended-sand transport over an extremely rough and sparsely sand-covered bed, which is not accurately represented in conventional sand-transport relations or boundary conditions, is calculated in our model with newly developed algorithms (see Grams and others, this meeting); (3) the channel is represented by reach-averaged properties, thereby reducing data requirements and increasing model efficiency; and (4) the model is coupled with an unsteady-flow model, thereby accounting for frequent changes in discharge produced by variations in releases in this power-producing regulated river. Numerical models can contribute to the explanation of observed changes in sand storage, extrapolate field observations to unobserved flows, and evaluate alternative dam-operation strategies for preserving the sand resource. Model applications can address several significant management
Extracting complexity waveforms from one-dimensional signals
Kalauzi, Aleksandar; Bojić, Tijana; Rakić, Ljubisav
2009-01-01
Background Nonlinear methods provide a direct way of estimating complexity of one-dimensional sampled signals through calculation of Higuchi's fractal dimension (1
Quasi-one-dimensional models for glassy dynamics
NASA Astrophysics Data System (ADS)
Pal, Prasanta
2011-12-01
We describe analytical calculations and simulations of the quasi-one-dimensional (Q1-D) model for glassy dynamics. In the Q1-D models, hard rods undergo single-file diffusion through a series of narrow channels connected by J intersections. The topology of the model is specified by J, the maximum number of rods in each middle channel K, and the number of rods N. We assume that the rods cannot turn at the intersections, and thus there is a single, continuous route through the system. This model displays hallmarks of glassy dynamics including caging behavior and subdiffusion, rapid growth in the structural relaxation time and collective particle rearrangements. The mean-square displacement Sigma(t) for the Q1-D model displays four dynamical regimes: 1) short-time diffusion Sigma( t) ˜ t, 2) a plateau Sigma(t) ˜ t0 caused by caging behavior, 3) single-file diffusion characterized by anomalous scaling Sigma(t) ˜ t0.5 at intermediate times, and 4) a crossover to long-tine diffusion Sigma(t) ˜ t for times that grow with the system size. We develop a general procedure for calculating analytically the structural relaxation time tD, beyond which the system undergoes long-time diffusion, as a function of density and system topology. The method involves several steps: 1) uniquely defining the set of microstates for the system and transitions among them, 2) constructing networks of connected microstates and identifying minimal, closed, directed loops that give rise to structural relaxation, 3) calculating the probabilities for obtaining each of the microstates that form the closed loops and for transitioning from one microstate to another, and 4) using these probabilities to deduce the dependence of tD on packing fraction. We find that to obeys power-law scaling tD ˜ (φ g-φ)-alpha, where φ g (the packing fraction corresponding to complete kinetic arrest) and alpha depend on the system topology, and can be calculated exactly. The analytical calculations are supported
Soil and biosolid nano- and macro-colloid properties and contaminant transport behavior
NASA Astrophysics Data System (ADS)
Ghezzi, Jessique L.
Despite indications that they are potential contaminant transport systems and threats to groundwater quality, very little effort has been invested in comparing contaminant transport behavior of natural environmental nanocolloids and their corresponding macrocolloid fractions in the presence of As, Se, Pb, and Cu contaminants. This study involved physico-chemical, mineralogical, stability and contaminant-transport characterizations of nano- (< 100 nm) and macro-colloids (100-2000 nm) fractionated from three Kentucky soils and one biosolid waste. Particle size was investigated with SEM/TEM and dynamic light scattering. Surface reactivity was estimated using CEC and zeta potential. Mineralogical composition was determined by XRD, FTIR, and thermogravimetric analyses. Sorption isotherms assessed affinities for Cu2+, Pb2+, AsO3-, and SeO4 -2 contaminants, while settling kinetics experiments of suspensions at 0, 2 and 10 mg/L contaminants determined stability and transportability potential. Undisturbed 18x30 cm KY Ashton Loam soil monoliths were also used for transport experiments, involving infusion of 50 mg L-1 colloid suspensions spiked with 2 mg L-1 mixed contaminant loads in unsaturated, steady state, unit gradient downward percolation experiments. Overall, nanocolloids exhibited greater stability over corresponding macrocolloids in the presence and absence of contaminants following specific mineralogy trends. Physicochemical characterizations indicated that extensive organic carbon surface coatings and higher Al/Fe:Si ratios may have induced higher stability in the nanocolloid fractions, in spite of some hindrance by nano-aggregation phenomena. In the transport experiments, nanocolloids eluted significantly higher concentrations of colloids, total, and colloid-bound metals than corresponding macrocolloids. Contaminant elutions varied by colloid type, mineralogy and contaminant, with the following sequences: soil-colloids>bio-colloids, smectitic
The physicist's companion to current fluctuations: one-dimensional bulk-driven lattice gases
NASA Astrophysics Data System (ADS)
Lazarescu, Alexandre
2015-12-01
One of the main features of statistical systems out of equilibrium is the currents they exhibit in their stationary state: microscopic currents of probability between configurations, which translate into macroscopic currents of mass, charge, etc. Understanding the general behaviour of these currents is an important step towards building a universal framework for non-equilibrium steady states akin to the Gibbs-Boltzmann distribution for equilibrium systems. In this review, we consider one-dimensional bulk-driven particle gases, and in particular the asymmetric simple exclusion process (ASEP) with open boundaries, which is one of the most popular models of one-dimensional transport. We focus, in particular, on the current of particles flowing through the system in its steady state, and on its fluctuations. We show how one can obtain the complete statistics of that current, through its large deviation function, by combining results from various methods: exact calculation of the cumulants of the current, using the integrability of the model; direct diagonalization of a biased process in the limits of very high or low current; hydrodynamic description of the model in the continuous limit using the macroscopic fluctuation theory. We give a pedagogical account of these techniques, starting with a quick introduction to the necessary mathematical tools, as well as a short overview of the existing works relating to the ASEP. We conclude by drawing the complete dynamical phase diagram of the current. We also remark on a few possible generalizations of these results.
Non-periodic one-dimensional ideal conductors and integrable turbulence
NASA Astrophysics Data System (ADS)
Zakharov, Dmitry V.; Zakharov, Vladimir E.; Dyachenko, Sergey A.
2016-12-01
To relate the motion of a quantum particle to the properties of the potential is a fundamental problem of physics, which is far from being solved. Can a medium with a potential which is neither periodic nor quasi-periodic be a conductor? That question seems to have been never addressed, despite being both interesting and having practical importance. Here we propose a new approach to the spectral problem of the one-dimensional Schrödinger operator with a bounded potential. We construct a wide class of potentials having a spectrum consisting of the positive semiaxis and finitely many bands on the negative semiaxis. These potentials, which we call primitive, are reflectionless for positive energy and in general are neither periodic nor quasi-periodic. Moreover, they can be stochastic, and yet allow ballistic transport, and thus describe one-dimensional ideal conductors. Primitive potentials also generate a new class of solutions of the KdV hierarchy. Stochastic primitive potentials describe integrable turbulence, which is important for hydrodynamics and nonlinear optics. We construct the potentials by numerically solving a system of singular integral equations. We hypothesize that finite-gap potentials are a subclass of primitive potentials, and prove this in the case of one-gap potentials.
Prediction of contaminant fate and transport in potable water systems using H2OFate
NASA Astrophysics Data System (ADS)
Devarakonda, Venkat; Manickavasagam, Sivakumar; VanBlaricum, Vicki; Ginsberg, Mark
2009-05-01
BlazeTech has recently developed a software called H2OFate to predict the fate and transport of chemical and biological contaminants in water distribution systems. This software includes models for the reactions of these contaminants with residual disinfectant in bulk water and at the pipe wall, and their adhesion/reactions with the pipe walls. This software can be interfaced with sensors through SCADA systems to monitor water distribution networks for contamination events and activate countermeasures, as needed. This paper presents results from parametric calculations carried out using H2OFate for a simulated contaminant release into a sample water distribution network.
Technology Transfer Automated Retrieval System (TEKTRAN)
Contaminant transport processes in streams, rivers, and other surface water bodies can be analyzed or predicted using the advection-dispersion equation and related transport models. In part 1 of this two-part series we presented a large number of one- and multi-dimensional analytical solutions of t...
Comparison of contaminant transport in agricultural drainage water and urban stormwater runoff
Technology Transfer Automated Retrieval System (TEKTRAN)
Transport of nitrogen and phosphorus from agricultural and urban landscapes to surface water bodies can cause adverse environmental impacts including hypoxia and harmful algal blooms. The main objective of this long-term study was to quantify and compare contaminant transport from a subsurface-drain...
FACT (Version 2.0) - Subsurface Flow and Contaminant Transport Documentation and User's Guide
Aleman, S.E.
2000-05-05
This report documents a finite element code designed to model subsurface flow and contaminant transport, named FACT. FACT is a transient three-dimensional, finite element code designed to simulate isothermal groundwater flow, moisture movement, and solute transport in variably saturated and fully saturated subsurface porous media.
Interest in coupled biodegradation and transport of organic contaminants has expanded greatly in the past several years. In a system in which biodegradation is coupled with solute transport, the magnitude and rate of biodegradation is influenced not only by pr...
Contaminant transport in two central Missouri karst recharge areas
Technology Transfer Automated Retrieval System (TEKTRAN)
Karst watersheds with significant losing streams represent a particularly vulnerable setting for ground water contamination because of the direct connection to surface water. Because of the existing agricultural land-use and future likelihood of urbanization, two losing stream karst basins were chos...
Contaminant transport in two central Missouri karst recharge areas
Technology Transfer Automated Retrieval System (TEKTRAN)
Karst watersheds with significant losing streams represent a particularly vulnerable setting for ground water contamination because of the direct connection to surface water. Because of the existing agricultural land-use and future threat of heavy urbanization, two losing stream karst basins were ch...
Contaminant Transport in Two Central Missouri Karst Recharge Areas
Technology Transfer Automated Retrieval System (TEKTRAN)
Karst watersheds with significant losing streams represent a particularly vulnerable setting for ground water contamination because of the direct connection to surface water. Because of the existing agricultural land-use and future threat of heavy urbanization, two losing stream karst basins were ch...
EMERGING CONTAMINANTS IN THE WATER CYCLE: FATE AND TRANSPORT
In the past decade, the scientific community and general public have become increasingly aware of the potential for the presence of unregulated, and generally unmonitored contaminants, found at low concentrations in surface, ground and drinking water. The most common pathway for...
Binning, P.; Celia, M.A.; Johnson, J.C.
1995-05-01
A numerical model of multiphase air-water flow and contaminant transport in the unsaturated zone is presented. The multiphase flow equations are solved using the two-pressure, mixed form of the equations with a modified Picard linearization of the equations and a finite element spatial approximation. A volatile contaminant is assumed to be transported in either phase, or in both phases simultaneously. The contaminant partitions between phases with an equilibrium distribution given by Henry`s Law or via kinetic mass transfer. The transport equations are solved using a Galerkin finite element method with reduced integration to lump the resultant matrices. The numerical model is applied to published experimental studies to examine the behavior of the air phase and associated contaminant movement under water infiltration. The model is also used to evaluate a hypothetical design for a low-level radioactive waste disposal facility. The model has been developed in both one and two dimensions; documentation and computer codes are available for the one-dimensional flow and transport model.
Influencing factors on particle-bound contaminant transport in the Elbe estuary
NASA Astrophysics Data System (ADS)
Kleisinger, Carmen; Haase, Holger; Schubert, Birgit
2016-04-01
Particulate matter, i.e. suspended particulate matter and sediments in rivers and estuaries, often are contaminated with trace metals and selected organic contaminants and are mainly associated with fine-grained fractions. Transport processes and fate of particles in estuaries are influenced by several factors, e.g. freshwater discharge, tide, flow velocity and dredging activities (Kappenberg et al., 2007). Understanding the transport processes in estuaries may help to achieve the objectives of the Water Framework Directive and the Marine Strategy Framework Directive. The German Federal Institute of Hydrology (BfG) operates for more than 20 years five monitoring sites in the Elbe estuary in order to monitor the development of particle-bound contaminant concentrations over time and to understand their transport mechanisms. Results of the monitoring revealed freshwater discharge as an important influencing factor on the transport of contaminated particulate matter (Ackermann et al., 2007). The bidirectional transport of marine and fluvial water and particulate matter in estuaries results in a turbidity zone where large amounts of particulate matter are temporarily retained and thus in a delayed transport of particulate matter towards the sea. The extent and the location of the turbidity zone as well as the ratio of highly contaminated fluvial and less contaminated marine sediments at a given location are mainly influenced by the freshwater discharge (Kowalewska et al., 2011). Furthermore, at high freshwater discharge conditions the highly contaminated particulate matter from fluvial origin are transported downstream the estuary, whereas at low freshwater discharges, upstream transport of less contaminated marine sediments prevails. Hence, residence times of particulate matter in the estuary are difficult to estimate. Furthermore, sedimentation areas with flow reduced conditions, e.g. wadden areas or branches of the Elbe estuary, may act as sinks for particle bound
Separation of neutral and charge modes in one-dimensional chiral edge channels.
Bocquillon, E; Freulon, V; Berroir, J-M; Degiovanni, P; Plaçais, B; Cavanna, A; Jin, Y; Fève, G
2013-01-01
Coulomb interactions have a major role in one-dimensional electronic transport. They modify the nature of the elementary excitations from Landau quasiparticles in higher dimensions to collective excitations in one dimension. Here we report the direct observation of the collective neutral and charge modes of the two chiral co-propagating edge channels of opposite spins of the quantum Hall effect at filling factor 2. Generating a charge density wave at frequency f in the outer channel, we measure the current induced by inter-channel Coulomb interaction in the inner channel after a 3-μm propagation length. Varying the driving frequency from 0.7 to 11 GHz, we observe damped oscillations in the induced current that result from the phase shift between the fast charge and slow neutral eigenmodes. We measure the dispersion relation and dissipation of the neutral mode from which we deduce quantitative information on the interaction range and parameters.
One-Dimensional Self-Organization and Nonequilibrium Phase Transition in a Hamiltonian System
NASA Astrophysics Data System (ADS)
Wang, Jiao; Casati, Giulio
2017-01-01
Self-organization and nonequilibrium phase transitions are well known to occur in two- and three-dimensional dissipative systems. Here, instead, we provide numerical evidence that these phenomena also occur in a one-dimensional Hamiltonian system. To this end, we calculate the heat conductivity by coupling the two ends of our system to two heat baths at different temperatures. It is found that when the temperature difference is smaller than a critical value, the heat conductivity increases with the system size in power law with an exponent considerably smaller than 1. However, as the temperature difference exceeds the critical value, the system's behavior undergoes a transition and the heat conductivity tends to diverge linearly with the system size. Correspondingly, an ordered structure emerges. These findings suggest a new direction for exploring the transport problems in one dimension.
Thermal conductance of one-dimensional materials calculated with typical lattice models
NASA Astrophysics Data System (ADS)
Zhang, Chunyi; Kang, Wei; Wang, Jianxiang
2016-11-01
We show through calculations on typical lattice models that thermal conductance σ can well describe the near-equilibrium thermal transport property of one-dimensional materials of finite length, which presents a situation often met in the application of nanoscale devices. The σ generally contains contributions from the material itself and those from the thermal reservoirs. The intrinsic σ of the material, i.e., the one with the fewest external influences, can be efficiently calculated with the help of the "blackbody"-like nonreflective thermal reservoir, either through the nonequilibrium method or through the Green-Kubo-type formula. σ thus calculated would be helpful to guide the design of thermal management and heat control in nanoscale devices.
Yamamoto, Yohei
2012-01-01
Electroactive one-dimensional (1D) nano-objects possess inherent unidirectional charge and energy transport capabilities along with anisotropic absorption and emission of light, which are of great advantage for the development of nanometer-scale electronics and optoelectronics. In particular, molecular nanowires formed by self-assembly of π-conjugated molecules attract increasing attention for application in supramolecular electronics. This review introduces recent topics related to electroactive molecular nanowires. The nanowires are classified into four categories with respect to the electronic states of the constituent molecules: electron donors, acceptors, donor–acceptor pairs and miscellaneous molecules that display interesting electronic properties. Although many challenges still remain for practical use, state-of-the-art 1D supramolecular nanomaterials have already brought significant advances to both fundamental chemical sciences and technological applications. PMID:27877488
Separation of neutral and charge modes in one-dimensional chiral edge channels
NASA Astrophysics Data System (ADS)
Bocquillon, E.; Freulon, V.; Berroir, J.-. M.; Degiovanni, P.; Plaçais, B.; Cavanna, A.; Jin, Y.; Fève, G.
2013-05-01
Coulomb interactions have a major role in one-dimensional electronic transport. They modify the nature of the elementary excitations from Landau quasiparticles in higher dimensions to collective excitations in one dimension. Here we report the direct observation of the collective neutral and charge modes of the two chiral co-propagating edge channels of opposite spins of the quantum Hall effect at filling factor 2. Generating a charge density wave at frequency f in the outer channel, we measure the current induced by inter-channel Coulomb interaction in the inner channel after a 3-μm propagation length. Varying the driving frequency from 0.7 to 11 GHz, we observe damped oscillations in the induced current that result from the phase shift between the fast charge and slow neutral eigenmodes. We measure the dispersion relation and dissipation of the neutral mode from which we deduce quantitative information on the interaction range and parameters.
Noise, delocalization, and quantum diffusion in one-dimensional tight-binding models
NASA Astrophysics Data System (ADS)
Gholami, Ehsan; Lashkami, Zahra Mohammaddoust
2017-02-01
As an unusual type of anomalous diffusion behavior, namely (transient) superballistic transport, has been experimentally observed recently, but it is not yet well understood. In this paper, we investigate the white noise effect (in the Markov approximation) on quantum diffusion in one-dimensional tight-binding models with a periodic, disordered, and quasiperiodic region of size L attached to two perfect lattices at both ends in which the wave packet is initially located at the center of the sublattice. We find that in a completely localized system, inducing noise could delocalize the system to a desirable diffusion phase. This controllable system may be used to investigate the interplay of disorder and white noise, as well as to explore an exotic quantum phase.
Porous one-dimensional nanostructures through confined cooperative self-assembly.
Bai, Feng; Sun, Zaicheng; Wu, Huimeng; Haddad, Raid E; Coker, Eric N; Huang, Jian Yu; Rodriguez, Mark A; Fan, Hongyou
2011-12-14
We report a simple confined self-assembly process to synthesize nanoporous one-dimensional photoactive nanostructures. Through surfactant-assisted cooperative interactions (e.g., π-π stacking, ligand coordination, and so forth) of the macrocyclic building block, zinc meso-tetra (4-pyridyl) porphyrin (ZnTPyP), self-assembled ZnTPyP nanowires and nanorods with controlled diameters and aspect ratios are prepared. Electron microscopy characterization in combination with X-ray diffraction and gas sorption experiments indicate that these materials exhibit stable single-crystalline and high surface area nanoporous frameworks with well-defined external morphology. Optical characterizations using UV-vis spectroscopy and fluorescence imaging and spectroscopy show enhanced collective optical properties over the individual chromophores (ZnTPyP), favorable for exciton formation and transport.
Large Eddy Simulation of Motion-Induced Contaminant Transports in Room Compartments
NASA Astrophysics Data System (ADS)
Choi, Jung-Il; Edwards, Jack
2011-11-01
Large eddy simulation (LES) of contaminant transports due to complex human and door motions is conducted for characterizing the effect of the motion-induced wakes on the contaminant transports in room compartments where a contaminated and clean room are connected by a vestibule. We utilize a LES technique with an immersed-boundary method for moving objects (Choi et al., JCP 2007; Choi and Edwards, Indoor Air 2008) and extend the technique to include Eulerian descriptions of gas-phase contaminant transport as well as thermal energy transfer. We demonstrate details of contaminant transport due to human- and door-motion induced wake development during a short-duration event involving the movement of a person (or persons) from a contaminated room, through a vestibule, into a clean room. Parametric studies that capture the effects of human walking pattern, door operation, over-pressure level, and vestibule size are systematically conducted. The results of parameteric studies will be shown in the final presentation. Supported by DARPA/SPO program (HR0011-05-C-0157) and WCU program (R31-10049) of NRF.
NASA Astrophysics Data System (ADS)
Padilla, I. Y.; Steele, K.
2008-05-01
The karst aquifer of the North Coast of Puerto Rico represents a significant source of water for drinking purposes, as well as ecosystem sustainability. The same characteristics making this aquifer the most productive in the island, fast infiltration and rapid flow in karst conduits, make the aquifers vulnerable highly vulnerable to contamination. Once in the ground water, organic contaminants move through the karst aquifers by complex pathways dictated by system characteristics and flow regimes. Ground water flow in karst aquifers is subscribed to two types of flow systems: conduit flow and diffuse flow. Transport in conduit-flow dominated systems tends to convey solutes rapidly through the system to a discharge or point without much attenuation. Transport in diffuse- flow systems, on the other hand, causes significant solute retardation and serves as a long-term source of contamination. Although it is common to attribute one type of predominant flow regime, most carbonate aquifers are characterized by a mixture of both flow systems. The north coast aquifer of Puerto Rico has been impacted by a large number of contaminates sites. During the last 25 years, 10 Superfund sites have been declared in the zone and others are being evaluated for inclusion in the National Priority List. The work presented herein addresses the potential impact of these sites on the extent of contamination and discusses the transport mechanisms affecting the transport and persistence of organic contaminants in the north coast aquifer of Puerto Rico. Preliminary evaluation indicates that fate and transport of these contaminants is controlled by a combinations of conduit- and diffuse-flow mechanisms, where conduits tend to concentrate water and contaminants and convey it rapidly or to "trapping" diffusive-flow zones of smaller pore-size zones.
Wingert, Matthew C; Chen, Zack C Y; Kwon, Shooshin; Xiang, Jie; Chen, Renkun
2012-02-01
Thermal conductivity of one-dimensional nanostructures, such as nanowires, nanotubes, and polymer chains, is of significant interest for understanding nanoscale thermal transport phenomena as well as for practical applications in nanoelectronics, energy conversion, and thermal management. Various techniques have been developed during the past decade for measuring this fundamental quantity at the individual nanostructure level. However, the sensitivity of these techniques is generally limited to 1 × 10(-9) W∕K, which is inadequate for small diameter nanostructures that potentially possess thermal conductance ranging between 10(-11) and 10(-10) W∕K. In this paper, we demonstrate an experimental technique which is capable of measuring thermal conductance of ∼10(-11) W∕K. The improved sensitivity is achieved by using an on-chip Wheatstone bridge circuit that overcomes several instrumentation issues. It provides a more effective method of characterizing the thermal properties of smaller and less conductive one-dimensional nanostructures. The best sensitivity experimentally achieved experienced a noise equivalent temperature below 0.5 mK and a minimum conductance measurement of 1 × 10(-11) W∕K. Measuring the temperature fluctuation of both the four-point and bridge measurements over a 4 h time period shows a reduction in measured temperature fluctuation from 100 mK to 0.6 mK. Measurement of a 15 nm Ge nanowire and background conductance signal with no wire present demonstrates the increased sensitivity of the bridge method over the traditional four-point I-V measurement. This ultra-sensitive measurement platform allows for thermal measurements of materials at new size scales and will improve our understanding of thermal transport in nanoscale structures.
Benthic processes affecting contaminant transport in Upper Klamath Lake, Oregon
Kuwabara, James S.; Topping, Brent R.; Carter, James L.; Carlson, Rick A; Parchaso, Francis; Fend, Steven V.; Stauffer-Olsen, Natalie; Manning, Andrew J.; Land, Jennie M.
2016-09-30
Executive SummaryMultiple sampling trips during calendar years 2013 through 2015 were coordinated to provide measurements of interdependent benthic processes that potentially affect contaminant transport in Upper Klamath Lake (UKL), Oregon. The measurements were motivated by recognition that such internal processes (for example, solute benthic flux, bioturbation and solute efflux by benthic invertebrates, and physical groundwater-surface water interactions) were not integrated into existing management models for UKL. Up until 2013, all of the benthic-flux studies generally had been limited spatially to a number of sites in the northern part of UKL and limited temporally to 2–3 samplings per year. All of the benthic invertebrate studies also had been limited to the northern part of the lake; however, intensive temporal (weekly) studies had previously been completed independent of benthic-flux studies. Therefore, knowledge of both the spatial and temporal variability in benthic flux and benthic invertebrate distributions for the entire lake was lacking. To address these limitations, we completed a lakewide spatial study during 2013 and a coordinated temporal study with weekly sampling of benthic flux and benthic invertebrates during 2014. Field design of the spatially focused study in 2013 involved 21 sites sampled three times as the summer cyanobacterial bloom developed (that is, May 23, June 13, and July 3, 2013). Results of the 27-week, temporally focused study of one site in 2014 were summarized and partitioned into three periods (referred to herein as pre-bloom, bloom and post-bloom periods), each period involving 9 weeks of profiler deployments, water column and benthic sampling. Partitioning of the pre-bloom, bloom, and post-bloom periods were based on water-column chlorophyll concentrations and involved the following date intervals, respectively: April 15 through June 10, June 17 through August 13, and August 20 through October 16, 2014. To examine
Abrams , Robert H.; Loague, Keith
2000-01-01
This paper, the first of two parts [see Abrams and Loague, this issue], takes the compartmentalized approach for the geochemical evolution of redox zones presented by Abrams et al. [1998] and embeds it within a solute transport framework. In this paper the compartmentalized approach is generalized to facilitate the description of its incorporation into a solute transport simulator. An equivalent formulation is developed which removes any discontinuities that may occur when switching compartments. Rate-limited redox reactions are modeled with a modified Monod relationship that allows either the organic substrate or the electron acceptor to be the rate-limiting reactant. Thermodynamic constraints are used to inhibit lower-energy redox reactions from occurring under infeasible geochemical conditions without imposing equilibrium on the lower-energy reactions. The procedure used allows any redox reaction to be simulated as being kinetically limited or thermodynamically limited, depending on local geochemical conditions. Empirical reaction inhibition methods are not needed. The sequential iteration approach (SIA), a technique which allows the number of solute transport equations to be reduced, is adopted to solve the coupled geochemical/solute transport problem. When the compartmentalized approach is embedded within the SIA, with the total analytical concentration of each component as the dependent variable in the transport equation, it is possible to reduce the number of transport equations even further than with the unmodified SIA. A one-dimensional, coupled geochemical/solute transport simulation is presented in which redox zones evolve dynamically in time and space. The compartmentalized solute transport (COMPTRAN) model described in this paper enables the development of redox zones to be simulated under both kinetic and thermodynamic constraints. The modular design of COMPTRAN facilitates the use of many different, preexisting solute transport and geochemical codes
NASA Astrophysics Data System (ADS)
Abrams, Robert H.; Loague, Keith
2000-08-01
This paper, the first of two parts [see Abrams and Loague, this issue], takes the compartmentalized approach for the geochemical evolution of redox zones presented by Abrams et al. [1998] and embeds it within a solute transport framework. In this paper the compartmentalized approach is generalized to facilitate the description of its incorporation into a solute transport simulator. An equivalent formulation is developed which removes any discontinuities that may occur when switching compartments. Rate-limited redox reactions are modeled with a modified Monod relationship that allows either the organic substrate or the electron acceptor to be the rate-limiting reactant. Thermodynamic constraints are used to inhibit lower-energy redox reactions from occurring under infeasible geochemical conditions without imposing equilibrium on the lower-energy reactions. The procedure used allows any redox reaction to be simulated as being kinetically limited or thermodynamically limited, depending on local geochemical conditions. Empirical reaction inhibition methods are not needed. The sequential iteration approach (SIA), a technique which allows the number of solute transport equations to be reduced, is adopted to solve the coupled geochemical/solute transport problem. When the compartmentalized approach is embedded within the SIA, with the total analytical concentration of each component as the dependent variable in the transport equation, it is possible to reduce the number of transport equations even further than with the unmodified SIA. A one-dimensional, coupled geochemical/solute transport simulation is presented in which redox zones evolve dynamically in time and space. The compartmentalized solute transport (COMPTRAN) model described in this paper enables the development of redox zones to be simulated under both kinetic and thermodynamic constraints. The modular design of COMPTRAN facilitates the use of many different, preexisting solute transport and geochemical codes
Wastewater contaminant transport and treatment in a nutrient limited ribbed fen
NASA Astrophysics Data System (ADS)
McCarter, C. P. R.; Price, J. S.; Branfireun, B. A.
2015-12-01
To minimize the discharge of wastewater contaminants from remote northern communities and mining operations, fen peatlands in sub-arctic regions are used for tertiary wastewater treatment to detain, transform, and remove these contaminants. However, there is a limited understanding of contaminant transport and treatment in fen peatlands, particularly in sub-arctic Canada. To better characterize wastewater contaminant transport and treatment in these systems, approximately 44 m3 day-1 of simulated wastewater, concentrated custom-blend fertilizer (NO3-, PO33-, and SO42-) and Cl- diluted with water, was pumped into a small 0.5 ha sub-arctic ribbed fen continuously for 47 days (July 15th -August 31st 2014). Contaminant concentration of 3 similar ribbed fens varied between 0.0-3.0 mg L-1 over the study period (May - September 2014). An exponential increase in transmissivity (2.4 to 16.8 m2 day-1) as the water table rose (~0.16 m) increased the average linear groundwater velocity (0.5 to 3.4 m day-1) and resulted in rapid SO42- (0.8 m day-1) and Cl- (1.9 m day-1) transport. Notwithstanding the rapid transport of Cl-, diffusion into inactive pores still retarded Cl- transport by a factor of 1.8. Contrary to the rapid transport of SO42- and Cl-, the other contaminants were rapidly removed from the pore water (likely through biological uptake or adsorption) and minimal transport was observed (0.29 and 0.04 m day-1 for PO33- and NO3-, respectively). Northern ribbed fens have a large capacity to detain certain wastewater contaminants (e.g., NO3- and PO33-), yet allow rapid transport of others (e.g., SO42- and Cl-). Thus, these peatlands have the potential to significantly decrease wastewater contamination in northern aquatic environment by both biogeochemical and physical processes but careful management of the hydrology is required to prevent the release of mobile contaminants.
POWELL, KIMBERLYR.
2004-05-25
Implementation of monitored natural attenuation (MNA) as a remediation method requires a mechanistic understanding of the natural attenuation processes occurring at a given site. For inorganic contaminants, natural attenuation typically involves a decrease in metal toxicity and/or mobility. These natural processes include dilution, dispersion, sorption (including adsorption, absorption, and precipitation), and redox processes. In order to better quantify these processes in terms of metal availability, sequential extraction experiments were carried out on subsurface soil samples impacted by a low pH, high sulfate, metals (Be, Ni, U, As) plume associated with the long-term operation of a coal plant at the Savannah River Site. These laboratory scale studies provide mechanistic information regarding the solid phases in the soils associated with natural attenuation of the contaminant metals. This data provides input to be evaluated in the definition of the contaminant source term as well as transport of contaminants for site transport models.
Carrigan, C.R.; Hudson, G.B.
1998-06-01
'The intent of this research program is to obtain an improved understanding of vadose zone transport processes and to develop field and modeling techniques required to characterize contaminant transport in the unsaturated zone at DOE sites. For surface spills and near-surface leaks of chemicals, the vadose zone may well become a long-term source of contamination for the underlying water table. Transport of contaminants can occur in both the liquid and gas phases of the unsaturated zone. This transport occurs naturally as a result of diffusion, buoyancy forces (gravity), capillarity and barometric pressure variations. In some cases transport can be enhanced by anisotropies present in hydrologic regimes. This is particularly true for gas-phase transport which may be subject to vertical pumping resulting from atmospheric pressure changes. For liquid-phase flows, heterogeneity may enhance the downward transport of contaminants to the water table depending on soil properties and the scale of the surface spill or near-surface leak. Characterization techniques based upon the dynamics of transport processes are likely to yield a better understanding of the potential for contaminant transport at a specific site than methods depending solely on hydrologic properties derived from a borehole. Such dynamic-characterization techniques can be useful for evaluating sites where contamination presently exists as well as for providing an objective basis to evaluate the efficacy of proposed as well as implemented clean-up technologies. The real-time monitoring of processes that may occur during clean-up of tank waste and the mobility of contaminants beneath the Hanford storage tanks during sluicing operations is one example of how techniques developed in this effort can be applied to current remediation problems. In the future, such dynamic-characterization methods might also be used as part of the site-characterization process for determining suitable locations of new DOE facilities
Transport of PCBs with leachate water from the contaminated soil.
Kobasić, Vedranka Hodak; Picer, Mladen; Picer, Nena; Calić, Violeta
2008-08-01
Contaminated soil was taken from the area around the damaged capacitor of an electrical transformer station in Zadar (Croatia) and a phytoremediation experimental field was constructed with lysimeters. The levels of PCBs in the leachate water samples were measured nearly 3 years. The experiment was conducted under natural climatic conditions, through hot summers and mild winters. Although the amounts of leachated PCBs from the polluted soil were relatively small, their concentrations in leachate water samples from 1,500 to 29,000 ng L(-1) substantially exceeded the maximum allowed concentration of the total PCBs in the fishponds of Croatia (1 ng L(-1)).
Advances in Dynamic Transport of Organic Contaminants in Karst Groundwater Systems
NASA Astrophysics Data System (ADS)
Padilla, I. Y.; Vesper, D.; Alshawabkeh, A.; Hellweger, F.
2011-12-01
Karst groundwater systems develop in soluble rocks such as limestone, and are characterized by high permeability and well-developed conduit porosity. These systems provide important freshwater resources for human consumption and ecological integrity of streams, wetlands, and coastal zones. The same characteristics that make karst aquifers highly productive make them highly vulnerable to contamination. As a result, karst aquifers serve as an important route for contaminants exposure to humans and wildlife. Transport of organic contaminants in karst ground-water occurs in complex pathways influenced by the flow mechanism predominating in the aquifer: conduit-flow dominated systems tend to convey solutes rapidly through the system to a discharge point without much attenuation; diffuse-flow systems, on the other hand, can cause significant solute retardation and slow movement. These two mechanisms represent end members of a wide spectrum of conditions found in karst areas, and often a combination of conduit- and diffuse-flow mechanisms is encountered, where both flow mechanisms can control the fate and transport of contaminants. This is the case in the carbonate aquifers of northern Puerto Rico. This work addresses advances made on the characterization of fate and transport processes in karst ground-water systems characterized by variable conduit and/or diffusion dominated flow under high- and low-flow conditions. It involves laboratory-scale physical modeling and field-scale sampling and historical analysis of contaminant distribution. Statistical analysis of solute transport in Geo-Hydrobed physical models shows the heterogeneous character of transport dynamics in karstic units, and its variability under different flow regimes. Field-work analysis of chlorinated volatile organic compounds and phthalates indicates a large capacity of the karst systems to store and transmit contaminants. This work is part of the program "Puerto Rico Testsite for Exploring Contamination
Modeling Groundwater Flow and Contaminant Transport in Fractured Aquifers
2005-03-01
1987. Wu, Yu-Shu, H.H. Liu, and G.S. Bodvarsson . "Effect of small-scale fractures on flow and transport processes at Yucca Mountain, Nevada...34 Lawrence Berkeley National Laboratory, Paper LBNL-51848 (December 5, 2002). Wu, Y.S., H.H. Liu, and G.S. Bodvarsson . “A triple-continuum approach for
Bioaccumulation and transport of contaminants: migrating sockeye salmon as vectors of mercury.
Baker, Matthew R; Schindler, Daniel E; Holtgrieve, Gordon W; St Louis, Vincent L
2009-12-01
Biological transport by migratory animals is increasingly recognized as important to the long-range dispersal of toxic contaminants. Mercury (Hg) contamination is a widespread environmental concern with serious health implications for humans and wildlife. Due to their unique life history, anadromous salmon may act as important vectors for this contaminant, transferring Hg between marine and freshwater ecosystems. Previous analyses have considered contaminant transport by salmon to be unidirectional. These studies have evaluated Hg import to freshwater by spawning adults, but have not quantitatively assessed export through the migration of juveniles to the ocean. To determine the total Hg burden to freshwater systems by sockeye salmon, we reconstructed the net transport of Hg to the Wood River System in Bristol Bay, Alaska accounting for fluxes in (via adults) and out (via juveniles) of the system. Hg concentrations were higher in juvenile than adult salmon. Hg export from freshwater systems by salmon ranged from 3 to 30% of total import. Proportional export by smolts may be higher for populations under heavy exploitation with strong density dependence in juvenile recruitment. Full consideration of contaminant loading by migratory species requires attention to the relative contaminant flux at all life history stages and the effects of density dependent growth and survival.
Color image analysis of contaminants and bacteria transport in porous media
Rashidi, M.; Dehmeshid, J.; Dacini, F.; Cole, L.; Dickenson, E.
1997-07-01
Transport of contaminants and bacteria in aqueous heterogeneous saturated porous systems have been studies experimentally using a novel fluorescent microscopic imaging (FMI) technique. The approach involves color visualization and quantification of bacterium and contaminant distributions within a transparent porous column. By introducing stained bacteria and an organic dye as a contaminant into the column and illuminating the porous regions with a planar sheet of laser beam, contaminant and bacterial transport processes through the porous medium can be observed and measured microscopically. A computer controlled CCD camera is used to record the fluorescent images as a function of time. These images are recorded by a frame accurate high resolution VCR and are then analyzed using a color image analysis code written in our laboratories. The color images are digitalized this way and simultaneously concentration and velocity distributions of both contaminant and bacterium are evaluated as a function of time and pore characteristics. The approach provides a unique dynamic probe to observe these transport processes microscopically. These results are extremely valuable in in-situ bioremediation problems since microscopic particle-contaminant-bacterium interactions are the key to understanding and optimization of these processes.
NASA Astrophysics Data System (ADS)
Périard, Yann; José Gumiere, Silvio; Rousseau, Alain N.; Caron, Jean
2013-04-01
Certain contaminants may travel faster through soils when they are sorbed to subsurface colloidal particles. Indeed, subsurface colloids may act as carriers of some contaminants accelerating their translocation through the soil into the water table. This phenomenon is known as colloid-facilitated contaminant transport. It plays a significant role in contaminant transport in soils and has been recognized as a source of groundwater contamination. From a mechanistic point of view, the attachment/detachment of the colloidal particles from the soil matrix or from the air-water interface and the straining process may modify the hydraulic properties of the porous media. Šimůnek et al. (2006) developed a model that can simulate the colloid-facilitated contaminant transport in variably saturated porous media. The model is based on the solution of a modified advection-dispersion equation that accounts for several processes, namely: straining, exclusion and attachement/detachement kinetics of colloids through the soil matrix. The solutions of these governing, partial differential equations are obtained using a standard Galerkin-type, linear finite element scheme, implemented in the HYDRUS-2D/3D software (Šimůnek et al., 2012). Modeling colloid transport through the soil and the interaction of colloids with the soil matrix and other contaminants is complex and requires the characterization of many model parameters. In practice, it is very difficult to assess actual transport parameter values, so they are often calibrated. However, before calibration, one needs to know which parameters have the greatest impact on output variables. This kind of information can be obtained through a sensitivity analysis of the model. The main objective of this work is to perform local and global sensitivity analyses of the colloid-facilitated contaminant transport module of HYDRUS. Sensitivity analysis was performed in two steps: (i) we applied a screening method based on Morris' elementary
Heat conduction in one-dimensional aperiodic quantum Ising chains.
Li, Wenjuan; Tong, Peiqing
2011-03-01
The heat conductivity of nonperiodic quantum Ising chains whose ends are connected with heat baths at different temperatures are studied numerically by solving the Lindblad master equation. The chains are subjected to a uniform transverse field h, while the exchange coupling J{m} between the nearest-neighbor spins takes the two values J{A} and J{B} arranged in Fibonacci, generalized Fibonacci, Thue-Morse, and period-doubling sequences. We calculate the energy-density profile and energy current of the resulting nonequilibrium steady states to study the heat-conducting behavior of finite but large systems. Although these nonperiodic quantum Ising chains are integrable, it is clearly found that energy gradients exist in all chains and the energy currents appear to scale as the system size ~N{α}. By increasing the ratio of couplings, the exponent α can be modulated from α > -1 to α < -1 corresponding to the nontrivial transition from the abnormal heat transport to the heat insulator. The influences of the temperature gradient and the magnetic field to heat conduction have also been discussed.
Influence of long-term sediment transport on contaminant dispersal in a turbid estuary
NASA Astrophysics Data System (ADS)
Uncles, R. J.; Woodrow, T. Y.; Stephens, J. A.
1987-11-01
Theoretical calculations are made of the long-term transport of fine sediment in a turbid estuary, and its possible consequences for the tidally averaged distribution of a contaminant whose partitioning between dissolved and particulate phases is dependent on salinity. It is found that the partitioning has a crucial effect on the levels of dissolved contaminant, in agreement with the observations of MORRIS (1986, The Science of the Total Environment, 49, 297-304). Calculations also imply that the vertical fluxes of particulate contaminant between water column and bed have a profound influence on these levels.
Impact of scaling and body movement on contaminant transport in airliner cabins
NASA Astrophysics Data System (ADS)
Mazumdar, Sagnik; Poussou, Stephane B.; Lin, Chao-Hsin; Isukapalli, Sastry S.; Plesniak, Michael W.; Chen, Qingyan
2011-10-01
Studies of contaminant transport have been conducted using small-scale models. This investigation used validated Computational Fluid Dynamics (CFD) to examine if a small-scale water model could reveal the same contaminant transport characteristics as a full-scale airliner cabin. But due to similarity problems and the difficulty of scaling the geometry, a perfect scale up from a small water model to an actual air model was found to be impossible. The study also found that the seats and passengers tended to obstruct the lateral transport of the contaminants and confine their spread to the aisle of the cabin. The movement of a crew member or a passenger could carry a contaminant in its wake to as many rows as the crew member or passenger passed. This could be the reason why a SARS infected passenger could infect fellow passengers who were seated seven rows away. To accurately simulate the contaminant transport, the shape of the moving body should be a human-like model.
Modeling the emission, transport and deposition of contaminated dust from a mine tailing site.
Stovern, Michael; Betterton, Eric A; Sáez, A Eduardo; Villar, Omar Ignacio Felix; Rine, Kyle P; Russell, Mackenzie R; King, Matt
2014-01-01
Mining operations are potential sources of airborne particulate metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern US by climate models may make contaminated atmospheric dust and aerosols increasingly important, due to potential deleterious effects on human health and ecology. Dust emissions and dispersion of contaminants from the Iron King Mine tailings in Dewey-Humboldt, Arizona, a Superfund site, are currently being investigated through in situ field measurements and computational fluid dynamics modeling. These tailings are significantly contaminated with lead and arsenic with an average soil concentration of 1616 and 1420 ppm, respectively. Similar levels of these contaminants have also been measured in soil samples taken from the area surrounding the mine tailings. Using a computational fluid dynamics model, we have been able to model dust transport from the mine tailings to the surrounding region. The model includes a distributed Eulerian model to simulate fine aerosol transport and a Lagrangian approach to model fate and transport of larger particles. In order to improve the accuracy of the dust transport simulations both regional topographical features and local weather patterns have been incorporated into the model simulations.
Organic contaminant transport and fate in the subsurface: Evolution of knowledge and understanding
NASA Astrophysics Data System (ADS)
Essaid, Hedeff I.; Bekins, Barbara A.; Cozzarelli, Isabelle M.
2015-07-01
Toxic organic contaminants may enter the subsurface as slightly soluble and volatile nonaqueous phase liquids (NAPLs) or as dissolved solutes resulting in contaminant plumes emanating from the source zone. A large body of research published in Water Resources Research has been devoted to characterizing and understanding processes controlling the transport and fate of these organic contaminants and the effectiveness of natural attenuation, bioremediation, and other remedial technologies. These contributions include studies of NAPL flow, entrapment, and interphase mass transfer that have advanced from the analysis of simple systems with uniform properties and equilibrium contaminant phase partitioning to complex systems with pore-scale and macroscale heterogeneity and rate-limited interphase mass transfer. Understanding of the fate of dissolved organic plumes has advanced from when biodegradation was thought to require oxygen to recognition of the importance of anaerobic biodegradation, multiple redox zones, microbial enzyme kinetics, and mixing of organic contaminants and electron acceptors at plume fringes. Challenges remain in understanding the impacts of physical, chemical, biological, and hydrogeological heterogeneity, pore-scale interactions, and mixing on the fate of organic contaminants. Further effort is needed to successfully incorporate these processes into field-scale predictions of transport and fate. Regulations have greatly reduced the frequency of new point-source contamination problems; however, remediation at many legacy plumes remains challenging. A number of fields of current relevance are benefiting from research advances from point-source contaminant research. These include geologic carbon sequestration, nonpoint-source contamination, aquifer storage and recovery, the fate of contaminants from oil and gas development, and enhanced bioremediation.
Organic contaminant transport and fate in the subsurface: evolution of knowledge and understanding
Essaid, Hedeff I.; Bekins, Barbara A.; Cozzarelli, Isabelle M.
2015-01-01
Toxic organic contaminants may enter the subsurface as slightly soluble and volatile nonaqueous phase liquids (NAPLs) or as dissolved solutes resulting in contaminant plumes emanating from the source zone. A large body of research published in Water Resources Research has been devoted to characterizing and understanding processes controlling the transport and fate of these organic contaminants and the effectiveness of natural attenuation, bioremediation, and other remedial technologies. These contributions include studies of NAPL flow, entrapment, and interphase mass transfer that have advanced from the analysis of simple systems with uniform properties and equilibrium contaminant phase partitioning to complex systems with pore-scale and macroscale heterogeneity and rate-limited interphase mass transfer. Understanding of the fate of dissolved organic plumes has advanced from when biodegradation was thought to require oxygen to recognition of the importance of anaerobic biodegradation, multiple redox zones, microbial enzyme kinetics, and mixing of organic contaminants and electron acceptors at plume fringes. Challenges remain in understanding the impacts of physical, chemical, biological, and hydrogeological heterogeneity, pore-scale interactions, and mixing on the fate of organic contaminants. Further effort is needed to successfully incorporate these processes into field-scale predictions of transport and fate. Regulations have greatly reduced the frequency of new point-source contamination problems; however, remediation at many legacy plumes remains challenging. A number of fields of current relevance are benefiting from research advances from point-source contaminant research. These include geologic carbon sequestration, nonpoint-source contamination, aquifer storage and recovery, the fate of contaminants from oil and gas development, and enhanced bioremediation.
One dimensional modeling of anthropogenic beach berm erosion
NASA Astrophysics Data System (ADS)
Shakeri Majd, M.; Sanders, B. F.
2013-12-01
Anthropogenic beach berms (sometimes called artificial berms or artificial dunes) are in use internationally to guard against beach overtopping and consequent coastal flooding. Berms can be constructed on a seasonal basis or in anticipation of a hazardous event, e.g., when a storm is expected to arrive coincident with an astronomical high tide. In either case, a common approach is to scrape sand from the foreshore with heavy equipment and deposit it on the crest of the natural beach dune, thus providing added protection from the possibility of wave overtopping. Given the potential for higher sea levels globally and more extreme storm events, anthropogenic berms will surely be tested to their limits and will ultimately fail, causing flooding. A better understanding of the conditions under which these berms fail is therefore needed to support coastal flood risk management. An experimental campaign in Newport Beach, California was conducted to document the dynamic erosion of prototype beach berms under a rising tide and mild to moderate wave conditions. Terrestrial laser scanning (TLS) of the berm produced a digital model of how the berm shape evolved over time. Here, a numerical model of swash zone hydromorphodynamics based on shallow-water flow physics is presented to evaluate whether and to what extent the timing and degree of berm erosion and overtopping can be predicted from first principles. The model tightly couples flow and sediment transport within an approximate Riemann solver, and thus is of the Godunov-type variety of finite volume schemes. Additionally, the model includes an avalanching scheme to account for non-hydrodynamic slumping down the angle of repose. Results indicate that it is possible to calibrate the model for a particular event, and then successfully predict erosion for another event, but due to parameter sensitivities, it is unlikely that the model can be applied at a site without calibration (true prediction).
Modeling the transport behavior of 16 emerging organic contaminants during soil aquifer treatment.
Nham, Hang Thuy Thi; Greskowiak, Janek; Nödler, Karsten; Rahman, Mohammad Azizur; Spachos, Thomas; Rusteberg, Bernd; Massmann, Gudrun; Sauter, Martin; Licha, Tobias
2015-05-01
In this study, four one-dimensional flow and transport models based on the data of a field scale experiment in Greece were constructed to investigate the transport behavior of sixteen organic trace pollutants during soil aquifer treatment. At the site, tap water and treated wastewater were intermittently infiltrated into a porous aquifer via a small pilot pond. Electrical conductivity data was used to calibrate the non-reactive transport models. Transport and attenuation of the organic trace pollutants were simulated assuming 1st order degradation and linear adsorption. Sorption was found to be largely insignificant at this site for the compounds under investigation. In contrast, flow path averaged first order degradation rate constants were mostly higher compared to the literature and lay between 0.036 d(-1) for clofibric acid and 0.9 d(-1) for ibuprofen, presumably owing to the high temperatures and a well adapted microbial community originating from the wastewater treatment process. The study highlights the necessity to obtain intrinsic attenuation parameters at each site, as findings cannot easily be transferred from one site to another.
Feed gas contaminant control in ion transport membrane systems
Carolan, Michael Francis; Minford, Eric; Waldron, William Emil
2009-07-07
Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.
Transport of PCBs with leachate water from contaminated soil.
Kobasić, Vedranka Hodak; Picer, Mladen; Picer, Nena; Calić, Violeta
2008-08-01
Natural soil contaminated with PCBs was used in this study. The soil was excavated from the area around the damaged capacitor of an electrical transformer station in Zadar (ETS 110/35 kV). A lysimeter experiment was conducted for 17 months under natural climatic conditions and designed to measure the concentration of PCB in the soil and leachates. Our research field was composed of four plots and there were three lysimeters on each plot. After 12 months, a negligible quantity of Aroclor 1248 (an average of 0.24%) and the Sigma 7 key PCB congeners (SigmaPCB(7); IUPAC No.: PCB 28, PCB 52, PCB 101, PCB 118, PCB 138, PCB 153 and PCB 180) were leached from the soils into the water collected under the lysimeters (an average of 0.32%). During two soil samplings, the soil was taken at three depths from each lysimeter. The distribution of Aroclor 1248 and 7 individual PCB congeners in the soil layers was determined before and after planting. Plot No. 1 had the highest percentage of contaminant removal after 12 months. The data indicate that the Sigma 7 key PCBs in the surface soil layers of all the plots decreased and the removal percentages ranged between 19.0% (Plot No. 2) and 47.6% (Plot No. 1). Volatilization from the soil surface may be the most important mechanism for the loss of these "more volatile" PCB congeners. The results showed an accumulation of PCBs in the deepest level of the soil plots, probably due to the vertical transfer of the PCBs and the lack of volatilization.
NASA Astrophysics Data System (ADS)
Mosthaf, K.; Rosenberg, L.; Balbarini, N.; Broholm, M. M.; Bjerg, P. L.; Binning, P. J.
2014-12-01
It is important to understand the fate and transport of contaminants in limestone aquifers because they are a major drinking water resource. This is challenging because they are highly heterogeneous; with micro-porous grains, flint inclusions, and being heavily fractured. Several modeling approaches have been developed to describe contaminant transport in fractured media, such as the discrete fracture (with various fracture geometries), equivalent porous media (with and without anisotropy), and dual porosity models. However, these modeling concepts are not well tested for limestone geologies. Given available field data and model purpose, this paper therefore aims to develop, examine and compare modeling approaches for transport of contaminants in fractured limestone aquifers. The model comparison was conducted for a contaminated site in Denmark, where a plume of a dissolved contaminant (PCE) has migrated through a fractured limestone aquifer. Multilevel monitoring wells have been installed at the site and available data includes information on spill history, extent of contamination, geology and hydrogeology. To describe the geology and fracture network, data from borehole logs was combined with an analysis of heterogeneities and fractures from a nearby excavation (analog site). Methods for translating the geological information and fracture mapping into each of the model concepts were examined. Each model was compared with available field data, considering both model fit and measures of model suitability. An analysis of model parameter identifiability and sensitivity is presented. Results show that there is considerable difference between modeling approaches, and that it is important to identify the right one for the actual scale and model purpose. A challenge in the use of field data is the determination of relevant hydraulic properties and interpretation of aqueous and solid phase contaminant concentration sampling data. Traditional water sampling has a bias
Contaminant transport in a single fracture: Periodic boundary and flow conditions
NASA Astrophysics Data System (ADS)
Lowell, Robert P.
1989-05-01
The effects of time-periodic inlet contaminant concentration and groundwater flow velocity on contaminant transport in a single, planar fracture, imbedded in a relatively impermeable rock matrix, are investigated. The calculations show that the contaminant propagates as a damped traveling wave into the matrix and along the fracture. If longitudinal dispersion is neglected, penetration of the wave into the matrix and fracture depends upon the input frequency σ as σ-½. Under uniform flow conditions, a daily oscillation penetrates into the matrix and fracture approximately 1 cm and 1 m, respectively. An annual oscillation penetrates approximately 10 cm and tens of meters for the matrix and fracture, respectively. These results depend upon physical properties of the rock matrix and fracture, and upon the flow velocity. Because longitudinal dispersion acts to further damp the amplitude of the traveling waves, these results give maximum penetration distances for the waves. If the flow velocity also has a small, time-periodic component, the downstream contaminant oscillations are virtually unchanged unless the inlet condition and flow have the same frequency. In this case, a dc transport of contaminant transport occurs that may have an amplitude as large as one-half of the magnitude of the velocity oscillation. These results indicate that in the absence of resonance, negligible error occurs in treating contaminant transport using mean inlet and flow conditions rather than more realistic time-varying ones. Observations of oscillations, however, can be used to provide useful information on rock and fracture transport properties such as D' and D.
It is well known that the fate and transport of contaminants in the subsurface are controlled by complex processes including advection, dispersion-diffusion, and chemical reactions. However, the interplay between the physical transport processes and chemical reactions, and their...
Gent, David B.; Wani, Altaf; Alshawabkeh, Akram N.
2012-01-01
A combination of direct electrochemical reduction and in-situ alkaline hydrolysis has been proposed to decompose energetic contaminants such as 1,3,5-Trinitroperhydro- 1,3,5-triazine and 2,4,6-Trinitrotoluene (RDX) in deep aquifers. This process utilizes natural groundwater convection to carry hydroxide produced by an upstream cathode to remove the contaminant at the cathode as well as in the pore water downstream as it migrates toward the anode. Laboratory evaluation incorporated fundamental principles of column design coupled with reactive contaminant modeling including electrokinetics transport. Batch and horizontal sand-packed column experiments included both alkaline hydrolysis and electrochemical treatment to determine RDX decomposition reaction rate coefficients. The sand packed columns simulated flow through a contaminated aquifer with a seepage velocity of 30.5 cm/day. Techniques to monitor and record the transient electric potential, hydroxide transport and contaminant concentration within the column were developed. The average reaction rate coefficients for both the alkaline batch (0.0487 hr−1) and sand column (0.0466 hr−1) experiments estimated the distance between the cathode and anode required to decompose 0.5 mg/L RDX to the USEPA drinking water lifetime Health Advisory level of 0.002 mg/L to be 145 and 152 cm. PMID:23472044
Synthesis and characterization of boron-based one-dimensional nanostructures
NASA Astrophysics Data System (ADS)
Otten, Carolyn Jones
New synthetic methods for the preparation of boron-based one-dimensional nanostructures are developed that employ catalytic chemical vapor deposition. The structures, morphologies, and elemental compositions of the nanostructures are characterized using electron microscopy and spectroscopy. Electrical-transport measurements performed on individual boron nanowires assess their potential as nanoscale interconnects. Multi-walled boron nitride nanotubes are generated from a molten salt mixture containing (NH4)2SO4, NaBH4, and Co3O4 at 300--400°C. Volatile BN-containing species generated in the molten salt are transported via a carrier gas to a nickel boride catalyst at 1100°C, whereupon precursor decomposition upon the catalyst material results in the formation of crystalline boron nitride nanotubes. The BN nanotubes have concentric-tube structures, are free of internal closures, have crystalline walls, and exhibit lengths of up to ca. 5 mum. The nanotubes often possess bulbous, flag-like, or club-like tip closures. A root-growth mechanism is proposed for the catalyzed process. This work provides the first CVD synthesis of BN nanotubes not requiring the use of carbon nanotube templates. A theoretical prediction for the existence of conductive boron nanotubes inspired our next project in the search for ideal nanostructured electrical interconnects for nanoelectronics. Promising candidates should be highly refractory, covalently bonded, and conductive irrespective of their crystallographic orientation. We report the growth of crystalline boron nanowires from a nickel boride catalyst using diborane at temperatures of 1100°C. However, our one-dimensional boron nanostructures are dense nanowhiskers rather than hollow nanotubes. Electrical-conductivity measurements indicate the boron nanowires to be semiconductors, with properties consistent with bulk elemental boron. To our knowledge, these are the first measurements reported on crystalline boron nanowires. To probe the
Chemical factors influencing colloid-facilitated transport of contaminants in porous media
Roy, Sujoy B.; Dzombak, David A.
1997-01-01
The effects of colloids on the transport of two strongly sorbing solutesa hydrophobic organic compound, phenanthrene, and a metal ion, Ni2+were studied in sand-packed laboratory columns under different pH and ionic strength conditions. Two types of column experiments were performed as follows: (i) sorption/mobilization experiments where the contaminant was first sorbed in the column under conditions where no colloids were released and mobilized under conditions where colloids were released as a result of ionic strength reduction in the influent; and (ii) transport experiments where the contaminant, dissolved or sorbed on colloids, was injected into columns packed with a strongly sorbing porous medium. In the first type of experiment, contaminant mobilization was significant only when all releasable colloids were flushed from the column. In all other cases, although high colloid particle concentrations were encountered, there was no marked effect on total contaminant concentrations. In the second type of experiment, colloid deposition efficiencies were shown to control the enhancement of transport. The deposition efficiency was a function of the pH (for a high organic content sand) and of the contaminant concentration (for a charged species such as Ni2+).
A New One-dimensional Quantum Material - Ta2Pd3Se8 Atomic Chain
NASA Astrophysics Data System (ADS)
Liu, Xue; Liu, Jinyu; Hu, Jin; Yue, Chunlei; Mao, Zhiqiang; Wei, Jiang; Antipina, Liubov; Sorokin, Pavel; Sanchez, Ana
Since the discovery of carbon nanotube, there has been a persistent effort to search for other one dimensional (1D) quantum systems. However, only a few examples have been found. We report a new 1D example - semiconducting Ta2Pd3Se8. We demonstrate that the Ta2Pd3Se8 nanowire as thin as 1.3nm can be easily obtained by applying simple mechanical exfoliation from its bulk counterpart. High resolution TEM shows an intrinsic 1D chain-like crystalline morphology on these nano wires, indicating weak bonding between these atomic chains. Theoretical calculation shows a direct bandgap structure, which evolves from 0.53eV in the bulk to 1.04eV in single atomic chain. The field effect transistor based on Ta2Pd3Se8 nanowire achieved a promising performance with 104On/Off ratio and 80 cm2V-1s-1 mobility. Low temperature transport study reflects two different mechanisms, variable range hopping and thermal activation, which dominate the transport properties at different temperature regimes. Ta2Pd3Se8 nanowire provides an intrinsic 1D material system for the study low dimensional condensed matter physics.
Shuttling heat across one-dimensional homogenous nonlinear lattices with a Brownian heat motor
NASA Astrophysics Data System (ADS)
Li, Nianbei; Zhan, Fei; Hänggi, Peter; Li, Baowen
2009-07-01
We investigate directed thermal heat flux across one-dimensional homogenous nonlinear lattices when no net thermal bias is present on average. A nonlinear lattice of Fermi-Pasta-Ulam-type or Lennard-Jones-type system is connected at both ends to thermal baths which are held at the same temperature on temporal average. We study two different modulations of the heat bath temperatures, namely: (i) a symmetric, harmonic ac driving of temperature of one heat bath only and (ii) a harmonic mixing drive of temperature acting on both heat baths. While for case (i) an adiabatic result for the net heat transport can be derived in terms of the temperature-dependent heat conductivity of the nonlinear lattice a similar such transport approach fails for the harmonic mixing case (ii). Then, for case (ii), not even the sign of the resulting Brownian motion induced heat flux can be predicted a priori. A nonvanishing heat flux (including a nonadiabatic reversal of flux) is detected which is the result of an induced dynamical symmetry breaking mechanism in conjunction with the nonlinearity of the lattice dynamics. Computer simulations demonstrate that the heat flux is robust against an increase of lattice sizes. The observed ratchet effect for such directed heat currents is quite sizable for our studied class of homogenous nonlinear lattice structures, thereby making this setup accessible for experimental implementation and verification.
One-dimensional carbon nanostructures for terahertz electron-beam radiation
NASA Astrophysics Data System (ADS)
Tantiwanichapan, Khwanchai; Swan, Anna K.; Paiella, Roberto
2016-06-01
One-dimensional carbon nanostructures such as nanotubes and nanoribbons can feature near-ballistic electronic transport over micron-scale distances even at room temperature. As a result, these materials provide a uniquely suited solid-state platform for radiation mechanisms that so far have been the exclusive domain of electron beams in vacuum. Here we consider the generation of terahertz light based on two such mechanisms, namely, the emission of cyclotronlike radiation in a sinusoidally corrugated nanowire (where periodic angular motion is produced by the mechanical corrugation rather than an externally applied magnetic field), and the Smith-Purcell effect in a rectilinear nanowire over a dielectric grating. In both cases, the radiation properties of the individual charge carriers are investigated via full-wave electrodynamic simulations, including dephasing effects caused by carrier collisions. The overall light output is then computed with a standard model of charge transport for two particularly suitable types of carbon nanostructures, i.e., zigzag graphene nanoribbons and armchair single-wall nanotubes. Relatively sharp emission peaks at geometrically tunable terahertz frequencies are obtained in each case. The corresponding output powers are experimentally accessible even with individual nanowires, and can be scaled to technologically significant levels using array configurations. These radiation mechanisms therefore represent a promising paradigm for light emission in condensed matter, which may find important applications in nanoelectronics and terahertz photonics.
Synthesis, Characterization and Applications of One-Dimensional Metal Oxide Nanostructures
NASA Astrophysics Data System (ADS)
Santulli, Alexander
Nanomaterials have been of keen research interest, owing to their exciting and unique properties (e.g. optical, magnetic, electronic, and mechanical). These properties allow nanomaterials to have many applications in areas of medicine, alternative energy, catalysis, and information storage. In particular, one-dimensional (1D) nanomaterials are highly advantageous, owing to the inherent anisotropic nature, which allows for effective transport and study of properties on the nanoscale. More specifically, 1D metal oxide nanomaterials are of particular interest, owing to their high thermal and chemical stability, as well as their intriguing optical, electronic, and magnetic properties. Herein, we will investigate the synthesis and characterization of vanadium oxide, lithium niobate and chromium oxide. We will explore the methodologies utilized for the synthesis of these materials, as well as the overall properties of these unique nanomaterials. Furthermore, we will explore the application of titanium dioxide nanomaterials as the electron transport layer in dye sensitized solar cells (DSSCs), with an emphasis on the effect of the nanoscale morphology on the overall device efficiency.
One-Dimensional Earth-Abundant Nanomaterials for Water-Splitting Electrocatalysts.
Li, Jun; Zheng, Gengfeng
2017-03-01
Hydrogen fuel acquisition based on electrochemical or photoelectrochemical water splitting represents one of the most promising means for the fast increase of global energy need, capable of offering a clean and sustainable energy resource with zero carbon footprints in the environment. The key to the success of this goal is the realization of robust earth-abundant materials and cost-effective reaction processes that can catalyze both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), with high efficiency and stability. In the past decade, one-dimensional (1D) nanomaterials and nanostructures have been substantially investigated for their potential in serving as these electrocatalysts for reducing overpotentials and increasing catalytic activity, due to their high electrochemically active surface area, fast charge transport, efficient mass transport of reactant species, and effective release of gas produced. In this review, we summarize the recent progress in developing new 1D nanomaterials as catalysts for HER, OER, as well as bifunctional electrocatalysts for both half reactions. Different categories of earth-abundant materials including metal-based and metal-free catalysts are introduced, with their representative results presented. The challenges and perspectives in this field are also discussed.
Ballistic One-Dimensional InAs Nanowire Cross-Junction Interconnects.
Gooth, Johannes; Borg, Mattias; Schmid, Heinz; Schaller, Vanessa; Wirths, Stephan; Moselund, Kirsten; Luisier, Mathieu; Karg, Siegfried; Riel, Heike
2017-04-12
Coherent interconnection of quantum bits remains an ongoing challenge in quantum information technology. Envisioned hardware to achieve this goal is based on semiconductor nanowire (NW) circuits, comprising individual NW devices that are linked through ballistic interconnects. However, maintaining the sensitive ballistic conduction and confinement conditions across NW intersections is a nontrivial problem. Here, we go beyond the characterization of a single NW device and demonstrate ballistic one-dimensional (1D) quantum transport in InAs NW cross-junctions, monolithically integrated on Si. Characteristic 1D conductance plateaus are resolved in field-effect measurements across up to four NW-junctions in series. The 1D ballistic transport and sub-band splitting is preserved for both crossing-directions. We show that the 1D modes of a single injection terminal can be distributed into multiple NW branches. We believe that NW cross-junctions are well-suited as cross-directional communication links for the reliable transfer of quantum information as required for quantum computational systems.
Influence of seaward boundary condition on contaminant transport in unconfined coastal aquifers
NASA Astrophysics Data System (ADS)
Zhang, Q.; Volker, R. E.; Lockington, D. A.
2001-06-01
Contaminant transport in coastal aquifers is complicated partly due to the conditions at the seaward boundary including seawater intrusion and tidal variations of sea level. Their inclusion in modelling this system will be computationally expensive. Therefore, it will be instructive to investigate the consequence of simplifying the seaward boundary condition by neglecting the seawater density and tidal variations in numerical predictions of contaminant transport in this zone. This paper presents a comparison of numerical predictions for a simplified seaward boundary condition with experimental results for a corresponding realistic one including a saltwater interface and tidal variations. Different densities for contaminants are considered. The comparison suggests that the neglect of the seawater intrusion and tidal variations does not affect noticeably the overall migration rate of the plume before it reaches the saltwater interface. However, numerical prediction shows that a more dense contaminant travels further seaward and part of the solute mass exits under the sea if the seawater density is not included. This is not consistent with the experimental result, which shows that the contaminant travels upwards to the shoreline along the saltwater interface. Neglect of seawater density, therefore, will result in an underestimation of the exit rate of solute mass around the coastline and fictitious migration paths under the seabed. For a less dense contaminant, neglect of seawater density has little effect on numerical prediction of migration paths.
Influence of seaward boundary condition on contaminant transport in unconfined coastal aquifers.
Zhang, Q; Volker, R E; Lockington, D A
2001-06-01
Contaminant transport in coastal aquifers is complicated partly due to the conditions at the seaward boundary including seawater intrusion and tidal variations of sea level. Their inclusion in modelling this system will be computationally expensive. Therefore, it will be instructive to investigate the consequence of simplifying the seaward boundary condition by neglecting the seawater density and tidal variations in numerical predictions of contaminant transport in this zone. This paper presents a comparison of numerical predictions for a simplified seaward boundary condition with experimental results for a corresponding realistic one including a saltwater interface and tidal variations. Different densities for contaminants are considered. The comparison suggests that the neglect of the seawater intrusion and tidal variations does not affect noticeably the overall migration rate of the plume before it reaches the saltwater interface. However, numerical prediction shows that a more dense contaminant travels further seaward and part of the solute mass exits under the sea if the seawater density is not included. This is not consistent with the experimental result, which shows that the contaminant travels upwards to the shoreline along the saltwater interface. Neglect of seawater density, therefore, will result in an underestimation of the exit rate of solute mass around the coastline and fictitious migration paths under the seabed. For a less dense contaminant, neglect of seawater density has little effect on numerical prediction of migration paths.
Dynamic one-dimensional modeling of secondary settling tanks and design impacts of sizing decisions.
Li, Ben; Stenstrom, Michael K
2014-03-01
As one of the most significant components in the activated sludge process (ASP), secondary settling tanks (SSTs) can be investigated with mathematical models to optimize design and operation. This paper takes a new look at the one-dimensional (1-D) SST model by analyzing and considering the impacts of numerical problems, especially the process robustness. An improved SST model with Yee-Roe-Davis technique as the PDE solver is proposed and compared with the widely used Takács model to show its improvement in numerical solution quality. The improved and Takács models are coupled with a bioreactor model to reevaluate ASP design basis and several popular control strategies for economic plausibility, contaminant removal efficiency and system robustness. The time-to-failure due to rising sludge blanket during overloading, as a key robustness indicator, is analyzed to demonstrate the differences caused by numerical issues in SST models. The calculated results indicate that the Takács model significantly underestimates time to failure, thus leading to a conservative design.
Technology Transfer Automated Retrieval System (TEKTRAN)
Analytical solutions of the advection-dispersion equation and related models are indispensable for predicting or analyzing contaminant transport processes in streams and rivers, as well as in other surface water bodies. Many useful analytical solutions originated in disciplines other than surface-w...
NASA Astrophysics Data System (ADS)
Zhu, Chen; Burden, David S.
2001-10-01
Mineralogical compositions and their spatial distributions are important initial conditions for reactive transport modeling. However, popular Kd-based "reactive" transport models only require contaminant concentrations in the pore fluids as initial conditions, and minerals implicitly represent infinite sources and sinks in these models. That situation results in a general neglect of mineralogical characterization in site investigations. This study uses a coupled multi-component reactive mass transport model to predict the natural attenuation of a ground water plume at a uranium mill tailings site in western USA. Numerous ground water geochemistry data are available at this site, but mineralogical data are sketchy. Even given the well-defined pore fluid chemistry, variations of secondary mineral species and mineral abundances in the aquifer resulted in significantly different modeling outcomes. Results show that the amount of calcite in the aquifer determines the distances of plume migration. The possible presence of jurbanite, an aluminum sulfate phase, can store acidity temporarily but cause more severe contamination on a later date. The surfaces of iron oxyhydroxides can store significant amounts of sulfate and protons and serve as a second source for prolonged contamination. These simulations under field conditions illustrate that mineralogical compositions are an essential requirement for accurate prediction of contaminant fate and transport.
Zhu, C; Burden, D S
2001-10-01
Mineralogical compositions and their spatial distributions are important initial conditions for reactive transport modeling. However, popular Kd-based "reactive" transport models only require contaminant concentrations in the pore fluids as initial conditions, and minerals implicitly represent infinite sources and sinks in these models. That situation results in a general neglect of mineralogical characterization in site investigations. This study uses a coupled multi-component reactive mass transport model to predict the natural attenuation of a ground water plume at a uranium mill tailings site in western USA. Numerous ground water geochemistry data are available at this site, but mineralogical data are sketchy. Even given the well-defined pore fluid chemistry, variations of secondary mineral species and mineral abundances in the aquifer resulted in significantly different modeling outcomes. Results show that the amount of calcite in the aquifer determines the distances of plume migration. The possible presence of jurbanite, an aluminum sulfate phase, can store acidity temporarily but cause more severe contamination on a later date. The surfaces of iron oxyhydroxides can store significant amounts of sulfate and protons and serve as a second source for prolonged contamination. These simulations under field conditions illustrate that mineralogical compositions are an essential requirement for accurate prediction of contaminant fate and transport.
PREDICTION OF CONTAMINATED SEDIMENT TRANSPORT IN THE MAURICE RIVER-UNION LAKE, NEW JERSEY, USA
This paper describes a sediment and contaminant transport model and its application to the Maurice River-Union Lake system in southern New Jersey, USA for the purpose of characterizing and forecasting sediment and arsenic distributions before and after proposed dredging activitie...
PREDICTION OF CONTAMINATED SEDIMENT TRANSPORT IN THE MAURICE RIVER-UNION LAKE, NEW JERSEY, USA
A sediment and contaminant transport model and its application to the Maurice River-Union Lake system in southern New Jersey, USA is described. The application is meant to characterize and forecast sediment and arsenic (As) distributions before and after proposed dredging activit...
NASA Astrophysics Data System (ADS)
Lemke, Lawrence D.; Cypher, Joseph A.
2010-06-01
Numerical groundwater flow and contaminant transport modeling incorporating three alternative conceptual models was conducted in 2005 to assess remedial actions and predict contaminant concentrations in an unconfined glacial aquifer located in Milford, Michigan, USA. Three alternative conceptual models were constructed and independently calibrated to evaluate uncertainty in the geometry of an aquitard underlying the aquifer and the extent to which infiltration from two manmade surface water bodies influenced the groundwater flow field. Contaminant transport for benzene, cis-DCE, and MTBE was modeled for a 5-year period that included a 2-year history match from July 2003 to May 2005 and predictions for a 3-year period ending in July 2008. A postaudit of model performance indicates that predictions for pumping wells, which integrated the transport signal across multiple model layers, were reliable but unable to differentiate between alternative conceptual model responses. In contrast, predictions for individual monitoring wells with limited screened intervals were less consistent, but held promise for evaluating alternative hydrogeologic models. Results of this study suggest that model conceptualization can have important practical implications for the delineation of contaminant transport pathways using monitoring wells, but may exert less influence on integrated predictions for pumping wells screened over multiple numerical model layers.
NASA Astrophysics Data System (ADS)
Wilson, C. J.; Canfield, H. E.; Crowell, K. J.; Lane, L. J.
2003-12-01
The May 2000 Cerro Grande Fire severely burned the headwaters of many of the canyon streams draining through the Los Alamos National Laboratory (LANL), Los Alamos County and Pueblos in Northern New Mexico. The fire increased observed flood magnitudes and hillslope erosion rates by one to two orders of magnitude above pre-fire conditions. A set of modeling activities was undertaken to predict the potential impacts of post-fire floods on channel and floodplain evolution, and sediment and contaminant transport in the steep streams draining the burn area. A contaminant transport model, Reach6, was developed and coupled to the HEC6T sediment transport model to predict redistribution and offsite transport of contaminated channel and floodplain sediments. Model predictions were tested against observed flood data. In particular, the HEC6T predictions were tested against high-resolution Airborne Laser Swath Mapping (ALSM) topographic data, collected before and after a 1440 cfs flash flood in a canyon contaminated with low levels of legacy Pu. The ALSM data showed the spatial distribution of channel and floodplain scour and deposition throughout the canyon. These data formed the backbone of our model testing process, along with observed sediment and Pu concentration data. Good correlation was found between predicted and observed data for the 1440cfs event, and led to application of the HEC6T model in assessing the effectiveness of remediation and stabilization strategies for Pueblo Canyon. LANL LA-UR-03-6382.
THE ONSITE ON-LINE CALCULATORS AND TRAINING FOR SUBSURFACE CONTAMINANT TRANSPORT SITE ASSESSMENT
EPA has developed a suite of on-line calculators called "OnSite" for assessing transport of environmental contaminants in the subsurface. The purpose of these calculators is to provide methods and data for common calculations used in assessing impacts from subsurface contaminatio...
Technology Transfer Automated Retrieval System (TEKTRAN)
The movement of autogenic recharge through the shallow epikarstic zone in soil-mantled karst aquifers is important in understanding recharge areas and rates, groundwater storage, and contaminant transport processes. The groundwater flow in agricultural karst areas, such as Kentucky’s Pennyroyal Plat...
Todd Arbogast; Steve Bryant; Clint N. Dawson; Mary F. Wheeler
1998-08-31
This report describes briefly the work of the Center for Subsurface Modeling (CSM) of the University of Texas at Austin (and Rice University prior to September 1995) on the Partnership in Computational Sciences Consortium (PICS) project entitled Grand Challenge Problems in Environmental Modeling and Remediation: Groundwater Contaminant Transport.
Yang, Bing; Xue, Nandong; Ding, Qiong; Vogt, Rolf David; Zhou, Lingli; Li, Fasheng; Wu, Guanglong; Zhang, Shilei; Zhou, Dandan; Liu, Bo; Yan, Yunzhong
2014-11-01
An assessment in China of the application of a transportable indirect thermal dryer unit for the remediation of soils contaminated with polychlorinated biphenyls (PCBs) demonstrated that it is well suited to remove PCBs from soils. A remarkable reduction of total PCBs in soils from 163-770 μg g(-1) to 0.08-0.15 μg g(-1) was achieved. This represented removal efficiencies of greater than 99.9% and an approximate 100% removal of the toxic equivalent of the PCBs. Furthermore, the emissions to the atmosphere from the unit were in compliance with current PCBs regulations. In conclusion, remediation of PCBs-contaminated soils based on a transportable indirect thermal dryer unit appears to be a highly efficient and environmentally sound treatment technology that has huge implications for cleaning thousands of regionally dispersed sites of PCBs contamination in China.
NASA Astrophysics Data System (ADS)
Ilyin, O. V.
2016-02-01
We consider the one-dimensional integro-differential Boltzmann equation for Maxwell particles with inelastic collisions. We show that the equation has a five-dimensional algebra of point symmetries for all dissipation parameter values and obtain an optimal system of one-dimensional subalgebras and classes of invariant solutions.
NASA Astrophysics Data System (ADS)
Wierenga, P. J.; Hills, R. G.; Hudson, D. B.
1991-10-01
A comprehensive field trench study was conducted in a semiarid area of southern New Mexico to provide data to test deterministic and stochastic models of vadose zone flow and transport. A 4 m by 9 m area was irrigated with water containing a tracer using a carefully controlled drip irrigation system. The area was heavily instrumented with tensiometers and neutron probe access tubes to monitor water movement and with suction tubes to monitor solute transport. Approximately 600 disturbed and 600 core samples of soil were taken to support deterministic and stochastic characterization of the soil water hydraulic parameters. The core sample-based saturated hydraulic conductivities ranged from 1.4 to 6731 cm/d with a mean of 533 cm/d and a standard deviation of 647 cm/d, indicating significant spatial variability. However, visual observation of the wetting front on the trench wall shows no indication of preferential flow or water flow through visible root channels and cracks. The tensiometer readings and the neutron probe measurements also suggest that the wetting front moves in a fairly homogeneous fashion despite the significant spatial variability of the saturated hydraulic conductivity. In addition to the description of the experiment and the presentation of the experimental results, predictions of simple one-dimensional uniform and layered soil deterministic models for infiltration are presented and compared to field observations. These models are presented here to provide a base case against which more sophisticated deterministic and stochastic models can be compared in the future. The results indicate that the simple models give adequate predictions of the overall movement of the wetting front through the soil during infiltration. However, the models give poor predictions of point values for water content due to the spatial variability of the soil. Comparisons between the one-dimensional infiltration model predictions and field observations show that the use of
Blessent, Daniela; Jørgensen, Peter R; Therrien, René
2014-01-01
We used the FRAC3Dvs numerical model (Therrien and Sudicky 1996) to compare the dual-porosity (DP), equivalent porous medium (EPM), and discrete fracture matrix diffusion (DFMD) conceptual models to predict field-scale contaminant transport in a fractured clayey till aquitard. The simulations show that the DP, EPM, and DFMD models could be equally well calibrated to reproduce contaminant breakthrough in the till aquitard for a base case. In contrast, when groundwater velocity and degradation rates are modified with respect to the base case, the DP method simulated contaminant concentrations up to three orders of magnitude different from those calculated by the DFMD model. In previous simulations of well-characterized column experiments, the DFMD method reproduced observed changes in solute transport for a range of flow and transport conditions comparable to those of the field-scale simulations, while the DP and EPM models required extensive recalibration to avoid high magnitude errors in predicted mass transport. The lack of robustness with respect to variable flow and transport conditions suggests that DP models and effective porosity EPM models have limitations for predicting cause-effect relationships in environmental planning. The study underlines the importance of obtaining well-characterized experimental data for further studies and evaluation of model key process descriptions and model suitability.
Bandy, P.J.; Hall, L.F.
1993-03-01
This report presents information on computer codes for numerical and analytical models that have been used at the Idaho National Engineering Laboratory (INEL) to model ground water and surface water flow and contaminant transport. Organizations conducting modeling at the INEL include: EG G Idaho, Inc., US Geological Survey, and Westinghouse Idaho Nuclear Company. Information concerning computer codes included in this report are: agency responsible for the modeling effort, name of the computer code, proprietor of the code (copyright holder or original author), validation and verification studies, applications of the model at INEL, the prime user of the model, computer code description, computing environment requirements, and documentation and references for the computer code.
Abrams , Robert H.; Loague, Keith
2000-01-01
This paper, the second of two parts [see Abrams and Loague, this issue], reports the field-scale application of COMPTRAN (compartmentalized solute transport model) for simulating the development of redox zones. COMPTRAN is fully developed and described in the companion paper. Redox zones, which are often delineated by the relative concentrations of dissolved oxygen, have been observed around the globe. The distribution of other redox-sensitive species is affected by redox zonation. At the U.S. Geological Survey's Cape Cod research site, an anoxic zone containing high concentrations of dissolved iron has been observed. Field data were abstracted from the Cape Cod site for the one-dimensional and two-dimensional COMPTRAN simulations reported in this paper. The purpose of the concept-development simulations was to demonstrate that the compartmentalized approach reported by Abrams et al. [1998] can be linked with a solute transport model to simulate field-scale phenomena. The results presented in this paper show that COMPTRAN successfully simulated the development of redox zones at the field scale, including trends in pH and alkalinity. Thermodynamic constraints were used to prevent lower-energy redox reactions from occurring under infeasible geochemical conditions without imposing equilibrium among all redox species. Empirical methods of reaction inhibition were not needed for the simulations conducted for this study. COMPTRAN can be extended easily to include additional compartments and reactions and is capable of handling complex velocity fields in more than one dimension.
NASA Astrophysics Data System (ADS)
Abrams, Robert H.; Loague, Keith
2000-08-01
This paper, the second of two parts [see Abrams and Loague, this issue], reports the field-scale application of COMPTRAN (compartmentalized solute transport model) for simulating the development of redox zones. COMPTRAN is fully developed and described in the companion paper. Redox zones, which are often delineated by the relative concentrations of dissolved oxygen, have been observed around the globe. The distribution of other redox-sensitive species is affected by redox zonation. At the U.S. Geological Survey's Cape Cod research site, an anoxic zone containing high concentrations of dissolved iron has been observed. Field data were abstracted from the Cape Cod site for the one-dimensional and two-dimensional COMPTRAN simulations reported in this paper. The purpose of the concept-development simulations was to demonstrate that the compartmentalized approach reported by Abrams et al. [1998] can be linked with a solute transport model to simulate field-scale phenomena. The results presented in this paper show that COMPTRAN successfully simulated the development of redox zones at the field scale, including trends in pH and alkalinity. Thermodynamic constraints were used to prevent lower-energy redox reactions from occurring under infeasible geochemical conditions without imposing equilibrium among all redox species. Empirical methods of reaction inhibition were not needed for the simulations conducted for this study. COMPTRAN can be extended easily to include additional compartments and reactions and is capable of handling complex velocity fields in more than one dimension.
Gas sensors based on one dimensional nanostructured metal-oxides: a review.
Arafat, M M; Dinan, B; Akbar, Sheikh A; Haseeb, A S M A
2012-01-01
Recently one dimensional (1-D) nanostructured metal-oxides have attracted much attention because of their potential applications in gas sensors. 1-D nanostructured metal-oxides provide high surface to volume ratio, while maintaining good chemical and thermal stabilities with minimal power consumption and low weight. In recent years, various processing routes have been developed for the synthesis of 1-D nanostructured metal-oxides such as hydrothermal, ultrasonic irradiation, electrospinning, anodization, sol-gel, molten-salt, carbothermal reduction, solid-state chemical reaction, thermal evaporation, vapor-phase transport, aerosol, RF sputtering, molecular beam epitaxy, chemical vapor deposition, gas-phase assisted nanocarving, UV lithography and dry plasma etching. A variety of sensor fabrication processing routes have also been developed. Depending on the materials, morphology and fabrication process the performance of the sensor towards a specific gas shows a varying degree of success. This article reviews and evaluates the performance of 1-D nanostructured metal-oxide gas sensors based on ZnO, SnO(2), TiO(2), In(2)O(3), WO(x), AgVO(3), CdO, MoO(3), CuO, TeO(2) and Fe(2)O(3). Advantages and disadvantages of each sensor are summarized, along with the associated sensing mechanism. Finally, the article concludes with some future directions of research.
NASA Astrophysics Data System (ADS)
Lee, Jung Ah; Rok Lim, Young; Jung, Chan Su; Choi, Jun Hee; Im, Hyung Soon; Park, Kidong; Park, Jeunghee; Kim, Gyu Tae
2016-10-01
To develop the advanced electronic devices, the surface/interface of each component must be carefully considered. Here, we investigate the electrical properties of metal-semiconductor nanoscale junction using conductive atomic force microscopy (C-AFM). Single-crystalline CdS, CdSe, and ZnO one-dimensional nanostructures are synthesized via chemical vapor transport, and individual nanobelts (or nanowires) are used to fabricate nanojunction electrodes. The current-voltage (I -V) curves are obtained by placing a C-AFM metal (PtIr) tip as a movable contact on the nanobelt (or nanowire), and often exhibit a resistive switching behavior that is rationalized by the Schottky (high resistance state) and ohmic (low resistance state) contacts between the metal and semiconductor. We obtain the Schottky barrier height and the ideality factor through fitting analysis of the I-V curves. The present nanojunction devices exhibit a lower Schottky barrier height and a higher ideality factor than those of the bulk materials, which is consistent with the findings of previous works on nanostructures. It is shown that C-AFM is a powerful tool for characterization of the Schottky contact of conducting channels between semiconductor nanostructures and metal electrodes.
One-dimensional Si/Ge nanowires and their heterostructures for multifunctional applications—a review
NASA Astrophysics Data System (ADS)
Ray, Samit K.; Katiyar, Ajit K.; Raychaudhuri, Arup K.
2017-03-01
Remarkable progress has been made in the field of one-dimensional semiconductor nanostructures for electronic and photonic devices. Group-IV semiconductors and their heterostructures have dominated the years of success in microelectronic industry. However their use in photonic devices is limited since they exhibit poor optical activity due to indirect band gap nature of Si and Ge. Reducing their dimensions below a characteristic length scale of various fundamental parameters like exciton Bohr radius, phonon mean free path, critical size of magnetic domains, exciton diffusion length etc result in the significant modification of bulk properties. In particular, light emission from Si/Ge nanowires due to quantum confinement, strain induced band structure modification and impurity doping may lead to the integration of photonic components with mature silicon CMOS technology in near future. Several promising applications based on Si and Ge nanowires have already been well established and studied, while others are now at the early demonstration stage. The control over various forms of energy and carrier transport through the unconstrained dimension makes Si and Ge nanowires a promising platform to manufacture advanced solid-state devices. This review presents the progress of the research with emphasis on their potential application of Si/Ge nanowires and their heterostructures for electronic, photonic, sensing and energy devices.
Gas Sensors Based on One Dimensional Nanostructured Metal-Oxides: A Review
Arafat, M. M.; Dinan, B.; Akbar, Sheikh A.; Haseeb, A. S. M. A.
2012-01-01
Recently one dimensional (1-D) nanostructured metal-oxides have attracted much attention because of their potential applications in gas sensors. 1-D nanostructured metal-oxides provide high surface to volume ratio, while maintaining good chemical and thermal stabilities with minimal power consumption and low weight. In recent years, various processing routes have been developed for the synthesis of 1-D nanostructured metal-oxides such as hydrothermal, ultrasonic irradiation, electrospinning, anodization, sol-gel, molten-salt, carbothermal reduction, solid-state chemical reaction, thermal evaporation, vapor-phase transport, aerosol, RF sputtering, molecular beam epitaxy, chemical vapor deposition, gas-phase assisted nanocarving, UV lithography and dry plasma etching. A variety of sensor fabrication processing routes have also been developed. Depending on the materials, morphology and fabrication process the performance of the sensor towards a specific gas shows a varying degree of success. This article reviews and evaluates the performance of 1-D nanostructured metal-oxide gas sensors based on ZnO, SnO2, TiO2, In2O3, WOx, AgVO3, CdO, MoO3, CuO, TeO2 and Fe2O3. Advantages and disadvantages of each sensor are summarized, along with the associated sensing mechanism. Finally, the article concludes with some future directions of research. PMID:22969344
U(1) chiral symmetry in a one-dimensional interacting electron system with spin
NASA Astrophysics Data System (ADS)
Lee, Taejin
2016-11-01
We study a spin-dependent Tomonaga-Luttinger model in one dimension, which describes electron transport through a single barrier. Using the Fermi-Bose equivalence in one dimension, we map the model onto a massless Thirring model with a boundary interaction. A field theoretical perturbation theory for the model has been developed, and the chiral symmetry is found to play an important role. The classical bulk action possesses a global U A (1)4 chiral symmetry because the fermion fields are massless. This global chiral symmetry is broken by the boundary interaction, and the bosonic degrees of freedom, corresponding to a chiral phase transformation, become dynamical. They acquire an additional kinetic action from the fermion path-integral measure and govern the critical behaviors of the physical operators. On the critical line where the boundary interaction becomes marginal, they decouple from the fermi fields. Consequently, the action reduces to the free-field action, which contains only a fermion bilinear boundary mass term as an interaction term. By using a renormalization group analysis, we obtain a new critical line, which differs from the previously known critical lines in the literature. The result of this work implies that the phase diagram of the one-dimensional electron system may have a richer structure than previously thought.
Ray, Samit K; Katiyar, Ajit K; Raychaudhuri, Arup K
2017-03-03
Remarkable progress has been made in the field of one-dimensional semiconductor nanostructures for electronic and photonic devices. Group-IV semiconductors and their heterostructures have dominated the years of success in microelectronic industry. However their use in photonic devices is limited since they exhibit poor optical activity due to indirect band gap nature of Si and Ge. Reducing their dimensions below a characteristic length scale of various fundamental parameters like exciton Bohr radius, phonon mean free path, critical size of magnetic domains, exciton diffusion length etc result in the significant modification of bulk properties. In particular, light emission from Si/Ge nanowires due to quantum confinement, strain induced band structure modification and impurity doping may lead to the integration of photonic components with mature silicon CMOS technology in near future. Several promising applications based on Si and Ge nanowires have already been well established and studied, while others are now at the early demonstration stage. The control over various forms of energy and carrier transport through the unconstrained dimension makes Si and Ge nanowires a promising platform to manufacture advanced solid-state devices. This review presents the progress of the research with emphasis on their potential application of Si/Ge nanowires and their heterostructures for electronic, photonic, sensing and energy devices.
Tran, T D; Simpson, R L; Maienschein, J; Tarver, C
2001-03-23
The thermal explosion of trinitrotoluene (TNT) is used as a basis for evaluating the performance of a new One-Dimensional-Time-to-Explosion (ODTX) apparatus. The ODTX experiment involves holding a 12.7 mm-diameter spherical explosive sample under confinement (150 MPa) at a constant elevated temperature until the confining pressure is exceeded by the evolution of gases during chemical decomposition. The resulting time to explosion as a function of temperature provides valuable decomposition kinetic information. A comparative analysis of the measurements obtained from the new unit and an older system is presented. Discussion on selected performance aspects of the new unit will also be presented. The thermal explosion of TNT is highly dependent on the material. Analysis of the time to explosion is complicated by historical and experimental factors such as material variability, sample preparation, temperature measurement and system errors. Many of these factors will be addressed. Finally, a kinetic model using a coupled thermal and heat transport code (chemical TOPAZ) was used to match the experimental data.
Cheng, Tao; Saiers, James E
2015-01-01
Colloid-facilitated transport of contaminants in the vadose zone has important implications to groundwater quality, and has received considerable attention. Natural organic matter (NOM) is ubiquitous in subsurface environments, and its influence on mineral colloids and solute transport has been well documented. However, research on the influence of NOM on colloid-facilitated transport is limited. The objective of this paper is to elucidate the effects of NOM on colloid-facilitated transport of a radioactive contaminant (Cs-137) within partially-saturated sediments. Measurements made with re-packed columns reveal that Cs-137 mobility was low when mineral colloids were absent and was unaffected by the presence of NOM. The addition of mineral colloids to influent increased Cs-137 mobility, and effluent Cs-137 was dominated by the colloid-associated form. When NOM was added to systems that contained mineral colloids and Cs-137, the mobility of Cs-137 further increased. A mathematical model simulating colloid-facilitated transport showed that NOM increases Cs-137 transport by increasing colloid mobility and reducing the rate of Cs-137 adsorption to the porous medium.
Effect of interchain frustration in quasi-one-dimensional conductors at half-filling
NASA Astrophysics Data System (ADS)
Tsuchiizu, M.; Suzumura, Y.; Bourbonnais, C.
2007-04-01
We examine the effect of frustrated interchain hoppings t_{\\perp 1} and t_{\\perp 2} on one-dimensional Mott insulators. By applying an N_\\perp -chain two-loop renormalization-group method to the half-filled quasi-one-dimensional Hubbard model, we show that the system remains insulating even for the large t_{\\perp 1} as far as t_{\\perp 2}=0 and vice versa, whereas a metallic state emerges by increasing both interchain hoppings. We also discuss the metallic behaviour suggested in the quasi-one-dimensional organic compound (TTM-TTP)I3 under high pressure.
1986-12-01
Version 00 The MEDUSA-IB code performs implosion and thermonuclear burn calculations of an ion beam driven ICF target, based on one-dimensional plasma hydrodynamics and transport theory. It can calculate the following values in spherical geometry through the progress of implosion and fuel burnup of a multi-layered target. (1) Hydrodynamic velocities, density, ion, electron and radiation temperature, radiation energy density, Rs and burn rate of target as a function of coordinates and time, (2) Fusion gain as a function of time, (3) Ionization degree, (4) Temperature dependent ion beam energy deposition, (5) Radiation, -particle and neutron spectra as a function of time.
Berman, D. H.; Khodas, M.; Flatté, M. E.
2014-10-15
We study the spin transport in a quasi-one-dimensional channel defined in a two-dimensional electron gas. The combined action of geometrical confinement and the spin precession is analyzed. We demonstrate that for certain orientations of the in-plane magnetic field and for specific range of its magnitude the spin polarization exhibits a strong decrease referred to as ballistic spin resonance (BSR). The phenomenon is due to the commensuration of the Zeeman and inter-subband energy splitting. We show that the BSR requires a finite spin-orbit (SO) interaction although the condition for the BSR onset is independent on SO coupling.
Coupled Geochemical and Reactive Transport Modeling of Organic Contaminants in a Pyrite-Rich Aquifer
NASA Astrophysics Data System (ADS)
Sarioglu, S. M.; Copty, N. K.
2004-12-01
Although pH is recognized as a key factor influencing bacterial activity, existing groundwater transport models generally do not directly account for the effect of pH on the biodegradation of organic compounds. The purpose of this study is to develop a coupled reactive transport and geochemical model that explicitly incorporates the effect of spatial and temporal variations of the pH on the biodegradation of organic contaminants. The model consists of two modules: a transport module and a geochemical module. The transport module uses a Crank-Nicholson finite-difference formulation to solve the groundwater flow and transport equations for the hydrocarbon, dissolved oxygen, microbial mass and all reactive groundwater species influencing the hydrocarbon biodegradation and pH distribution. The geochemical module allows for the simulation of both kinetically defined as well as geochemical equilibrium reactions. The governing non-linear system of equations is solved using an iterative multi-step operator-splitting algorithm. Both modules account for heterogeneity in the definition of the hydrogeological and biochemical parameters. For demonstration, the model is applied to a hypothetical pyrite-rich aquifer contaminated with petroleum hydrocarbons. A commonly used practice for the remediation of aquifers contaminated with petroleum hydrocarbons is the delivery of oxygen for the enhanced aerobic biodegradation of the organic contaminant. However, the presence of pyrite may interfere with the intended purpose of the supplied oxygen, leading to undesirable side effects. Specifically, oxygen readily reacts with the sulfide minerals leading to depletion of oxygen and acidification of the subsurface environment and, subsequently, the inadvertent inhibition of the microbial activity. The developed coupled geochemical and reactive transport model is used to quantify these processes and assess the dominance of the various chemical reactions. Both abiotic and biotic pyrite
Singhal, Naresh; Islam, Jahangir
2008-02-19
This paper uses the findings from a column study to develop a reactive model for exploring the interactions occurring in leachate-contaminated soils. The changes occurring in the concentrations of acetic acid, sulphate, suspended and attached biomass, Fe(II), Mn(II), calcium, carbonate ions, and pH in the column are assessed. The mathematical model considers geochemical equilibrium, kinetic biodegradation, precipitation-dissolution reactions, bacterial and substrate transport, and permeability reduction arising from bacterial growth and gas production. A two-step sequential operator splitting method is used to solve the coupled transport and biogeochemical reaction equations. The model gives satisfactory fits to experimental data and the simulations show that the transport of metals in soil is controlled by multiple competing biotic and abiotic reactions. These findings suggest that bioaccumulation and gas formation, compared to chemical precipitation, have a larger influence on hydraulic conductivity reduction.
Development of the one dimensional Fog Model PAFOG for operational Use at Munich Airport
NASA Astrophysics Data System (ADS)
Thoma, C.; Schneider, W.; Rohn, M.; Röhner, P.; Beckmann, B.-R.; Masbou, M.; Bott, A.
2010-07-01
Reduced visibility due to heavy fog is a hazard for land, sea, and air traffic. Especially for air transportation systems, reduced visibility leads to significant cost increments. Therefore, it is of particular importance to predict poor visibility fog events at airports accurately. In iPort-VIS, part of an aviation research program funded by the German Ministry for economy and technology, a site specific fog forecast system for Munich airport will be developed in cooperation between DWD, the German Aviation Control (DFS) and University of Bonn. The principal component of this forecast system is the one dimensional fog forecast model PAFOG (PArameterised FOG) that will be upgraded to operational use. The model consists of a parameterised microphysics scheme. The particle size distribution of cloud droplets is taken into account by a lognormal distribution and the visibility is calculated dependent on liquid water content and droplet concentration based on the Koschmieder formula. The turbulence in the atmospheric boundary layer is treated by the Mellor and Yamada closure scheme of order 2.5 in which a prognostic equation for the Turbulent Kinetic Energy (TKE) is solved. Radiative transports are considered by a Delta-Two-Stream Method with 18 spectral bands. Due to the fact that fog is a small scale complex phenomenon with high spatial and temporal variability, detailed knowledge of the atmospheric boundary layer structure is fundamental to get a realistic fog forecast. A time nudging scheme has been developed for integrating local observations (vertical profiles of temperature and specific humidity) periodically during the forecast. The system has been tested in several case studies with data from Lindenberg observatory and will be adapted to Munich airport with a new measurement system that will be installed by DWD. A second version of the nudging scheme, driven by the forecast of the high-resolution COSMO-DE model by DWD, is currently under development.
On the one-dimensional chemistry-diffusion model in planetary atmospheres
NASA Astrophysics Data System (ADS)
Zhang, Xi; Showman, Adam
Most of the current atmospheric chemistry models for planets (e.g., Krasnopolsky & Parshev 1981; Yung et al., 1984; Lavvas et al., 2008) and exo-planets (e.g., Moses et al., 2011; Line et al., 2011; Hu et al., 2012) adopt a one-dimensional (1D) chemistry-diffusion approach in the vertical coordinate such as pressure or altitude. Although only a crude approximation, these 1D models have succeeded in explaining the global-averaged vertical profiles of many chemical species in observations. One of the important assumptions of these models is that, all chemical species are transported via the same eddy diffusion profile. Here we show that, as also noticed in the Earth community (e.g., Holton 1986), in the presence of horizontal transport driven by eddies in the middle atmospheres such as the stratospheres on Earth and Titan, this “homogenous eddy diffusion” assumption generally breaks down. Instead, the eddy diffusion should depend both on the horizontal eddy mixing and the chemical lifetime of the species. It implies that the long-lived species and short-lived species could have significantly different eddy diffusion profiles. We show analytically why this new approach is more physically based. We also show numerically why the old approach fails compared with the globally averaged results from a more realistic two-dimensional (2D) simulation using the state-of-art Caltech/JPL 2D chemistry-diffusion-advection model (Zhang et al., 2013), and discuss the possible consequences. This research was supported by the Bisgrove Scholar Program in the University of Arizona.
A one-dimensional radiative convective model with detailed cloud microphysics
Simmons, J.; Lie-Svendsen, O.; Stamnes, K.
1995-04-01
The Arctic is a key element in determining the radiation budget of the earth. Within the polar regions, the net radiation (incoming solar radiation minus outgoing infrared radiation) is negative. To understand the role this energy deficit plays in the overall radiation budget, one must examine the prevalent atmospheric features of the Arctic. One such feature is a persistent layer of low-altitude, stratiform clouds found over the central Arctic predominantly from April to September. These Arctic stratus clouds (ASC) modulate the earth`s radiation budget by contributing to the vertical transport of heat. It is, therefore, crucial to understand the radiative properties of Arctic stratus clouds. We believe that the radiative properties of ASC are strongly coupled with their cloud microphysics. Our aim is to develop a model that will determine if this coupling is sufficient to describe the observed characteristic properties, such as lifetime and the multi-layered structure, of ASC. In addition, we hope to provide useful input to measurement programs at the Atmospheric Radiation Measurement Program`s North Slope of Alaska site by isolating the measurable parameters that influence the overall radiative properties of ASC. Several features of ASC have been integrated directly into the one-dimensional model currently being developed. Generally, ASC cover large areas and exhibit reasonable horizontal homogeneity but extensive vertical inhomogeneities. Therefore, in our model, we have assumed radiative processes are important in determining vertical structure while not considering horizontal transport. In addition, ASC occur in defined, multi-layered structures. This feature of the ASC, in conjunction with their horizontal homogeneity, justifies the use of radiative transfer theory for plane-parallel geometry with multiple scattering. Finally, ASC are generally long-lived and precipitate little during their lifetimes.
Lindenmeier, C.W.; Serne, R.J.; Conca, J.L.
1995-09-01
The objectives of this report and subsequent volumes include describing progress on (1) development and optimization of experimental methods to quantify the release of contaminants from solid wastes and their subsequent interactions with unsaturated sediments and (2) the creation of empirical data that become input parameters to performance assessment (PA) analyses for future Hanford Site disposal units and baseline risk assessments for inactive and existing solid waste disposal units. For this report, efforts focused on developing methodologies to evaluate contaminant transport in Trench 8 (W-5 Burial Ground) sediments under unsaturated (vadose zone) conditions. To accomplish this task, a series of flow-through column tests were run using standard saturated column systems, Wierenga unsaturated column systems (both commercial and modified), and the Unsaturated Flow Apparatus (UFA). The reactants investigated were {sup 85}Sr, {sup 236}U, and {sup 238}U as reactive tracers, and tritium as a non-reactive tracer. Results indicate that for moderately unsaturated conditions (volumetric water contents >50 % of saturation), the Wierenga system performed reasonably well such that long water residence times (50-147 h) were achieved, and reasonably good steady-state flow conditions were maintained. The major drawbacks in using this system for reactive tracer work included (1) the inability to achieve reproducible and constant moisture content below 50% of saturation, (2) the four to six month time required to complete a single test, and (3) the propensity for mechanical failure resulting from laboratory power outages during the prolonged testing period.
NASA Astrophysics Data System (ADS)
Mulligan, Ann; Uchupi, Elazar
Fresh water resources of sufficient quantity and quality are critical for maintaining societies and for supporting additional growth and development. When these resources are threatened or compromised, as can occur through the release of hazardous compounds, additional stress is placed on the water supply system from loss of the resource and changes in the demand structure.In western Cape Cod, Massachusetts, such problems are currently being encountered as a result of contaminant releases from the Massachusetts Military Reservation (MMR). An effective long-term response to subsurface contamination requires, among other things, determining the lithology, stratigraphy, and structure of aquifer materials and their effects on groundwater flow and contaminant transport. A recent review and analysis of subsurface data across Cape Cod offers a new interpretation of the geologic history of the Cape, with potential implications for groundwater issues facing western Cape Cod (the Upper Cape).
Sensitivity analysis of unsaturated flow and contaminant transport with correlated parameters
NASA Astrophysics Data System (ADS)
Pan, Feng; Zhu, Jianting; Ye, Ming; Pachepsky, Yakov A.; Wu, Yu-Shu
2011-02-01
SummaryThis study conducts sensitivity and uncertainty analysis for predicting unsaturated flow and contaminant transport in a layered heterogeneous system. The objectives of this work are to: (1) examine the effects of parameter correlations on the sensitivity of unsaturated flow and contaminant transport and (2) assess the relative contributions of parameter uncertainties to the uncertainties of flow and transport at each hydrogeologic layer. Using the unsaturated zone (UZ) of Yucca Mountain (YM) in Nevada, USA, as an example, the study considers cases of independent and correlated parameters. A sampling-based regression method is used, when the model input parameters are independent, and a decomposition method is used for the correlated case. When the parameters are independent, the uncertainty in permeability has the largest contribution to the uncertainties in simulated percolation flux and mass of the reactive tracer arriving at the water table. For the percolation flux, the second largest contribution is from the van Genuchten α; the sorption coefficient of the reactive tracer is the second most important parameter for the tracer mass arrival uncertainty. The sensitivity to the sorption coefficient is larger in the layers of devitrified and zeolitic tuffs than in the layers of vitric tuff. Contributions of the uncertainties in van Genuchten n and porosity to the percolation flux and tracer transport uncertainties are larger in the case of correlated parameters compared with the case of independent parameters due to the correlations of n and porosity with the van Genuchten α and permeability, respectively. These results illustrate the significant effects of parameter correlations on the sensitivity and uncertainty of unsaturated flow and transport. The findings are of significance in facilitating future characterizations to reduce the parameter uncertainties and associated predictive uncertainties of flow and contaminant transport in unsaturated fractured
Comparison of Contaminant Transport in Agricultural Drainage Water and Urban Stormwater Runoff.
Ghane, Ehsan; Ranaivoson, Andry Z; Feyereisen, Gary W; Rosen, Carl J; Moncrief, John F
2016-01-01
Transport of nitrogen and phosphorus from agricultural and urban landscapes to surface water bodies can cause adverse environmental impacts. The main objective of this long-term study was to quantify and compare contaminant transport in agricultural drainage water and urban stormwater runoff. We measured flow rate and contaminant concentration in stormwater runoff from Willmar, Minnesota, USA, and in drainage water from subsurface-drained fields with surface inlets, namely, Unfertilized and Fertilized Fields. Commercial fertilizer and turkey litter manure were applied to the Fertilized Field based on agronomic requirements. Results showed that the City Stormwater transported significantly higher loads per unit area of ammonium, total suspended solids (TSS), and total phosphorus (TP) than the Fertilized Field, but nitrate load was significantly lower. Nitrate load transport in drainage water from the Unfertilized Field was 58% of that from the Fertilized Field. Linear regression analysis indicated that a 1% increase in flow depth resulted in a 1.05% increase of TSS load from the City Stormwater, a 1.07% increase in nitrate load from the Fertilized Field, and a 1.11% increase in TP load from the Fertilized Field. This indicates an increase in concentration with a rise in flow depth, revealing that concentration variation was a significant factor influencing the dynamics of load transport. Further regression analysis showed the importance of targeting high flows to reduce contaminant transport. In conclusion, for watersheds similar to this one, management practices should be directed to load reduction of ammonium and TSS from urban areas, and nitrate from cropland while TP should be a target for both.
Comparison of Contaminant Transport in Agricultural Drainage Water and Urban Stormwater Runoff
Ranaivoson, Andry Z.; Feyereisen, Gary W.; Rosen, Carl J.; Moncrief, John F.
2016-01-01
Transport of nitrogen and phosphorus from agricultural and urban landscapes to surface water bodies can cause adverse environmental impacts. The main objective of this long-term study was to quantify and compare contaminant transport in agricultural drainage water and urban stormwater runoff. We measured flow rate and contaminant concentration in stormwater runoff from Willmar, Minnesota, USA, and in drainage water from subsurface-drained fields with surface inlets, namely, Unfertilized and Fertilized Fields. Commercial fertilizer and turkey litter manure were applied to the Fertilized Field based on agronomic requirements. Results showed that the City Stormwater transported significantly higher loads per unit area of ammonium, total suspended solids (TSS), and total phosphorus (TP) than the Fertilized Field, but nitrate load was significantly lower. Nitrate load transport in drainage water from the Unfertilized Field was 58% of that from the Fertilized Field. Linear regression analysis indicated that a 1% increase in flow depth resulted in a 1.05% increase of TSS load from the City Stormwater, a 1.07% increase in nitrate load from the Fertilized Field, and a 1.11% increase in TP load from the Fertilized Field. This indicates an increase in concentration with a rise in flow depth, revealing that concentration variation was a significant factor influencing the dynamics of load transport. Further regression analysis showed the importance of targeting high flows to reduce contaminant transport. In conclusion, for watersheds similar to this one, management practices should be directed to load reduction of ammonium and TSS from urban areas, and nitrate from cropland while TP should be a target for both. PMID:27930684
Lewis, Mark S.
2008-01-15
The packaging, transportation and disposal of large, retired reactor components from operating or decommissioning nuclear plants pose unique challenges from a technical as well as regulatory compliance standpoint. In addition to the routine considerations associated with any radioactive waste disposition activity, such as characterization, ALARA, and manifesting, the technical challenges for large radioactively contaminated components, such as access, segmentation, removal, packaging, rigging, lifting, mode of transportation, conveyance compatibility, and load securing require significant planning and execution. In addition, the current regulatory framework, domestically in Titles 49 and 10 and internationally in TS-R-1, does not lend itself to the transport of these large radioactively contaminated components, such as reactor vessels, steam generators, reactor pressure vessel heads, and pressurizers, without application for a special permit or arrangement. This paper addresses the methods of overcoming the technical and regulatory challenges. The challenges and disposition decisions do differ during decommissioning versus component replacement during an outage at an operating plant. During decommissioning, there is less concern about critical path for restart and more concern about volume reduction and waste minimization. Segmentation on-site is an available option during decommissioning, since labor and equipment will be readily available and decontamination activities are routine. The reactor building removal path is also of less concern and there are more rigging/lifting options available. Radionuclide assessment is necessary for transportation and disposal characterization. Characterization will dictate the packaging methodology, transportation mode, need for intermediate processing, and the disposal location or availability. Characterization will also assist in determining if the large component can be transported in full compliance with the transportation
[Influences of surfactant on the transport of PAHs in artificially contaminated soil columns].
Chen, Jing; Wang, Xue-jun; Hu, Jun-dong; Tao, Shu; Liu, Wen-xin
2005-03-01
The effect of anionic surfactant LAS on leaching of PAHs from artificially contaminated soil was studied. The interaction of these processes were studied in a two-layer column experiment with a base layer of uncontaminated soil(9cm) and a top layer of artificially contaminated soil(1cm). Results show that 5 critical micelle concentration (CMC) LAS enhanced the transport of PAHs. The breakthrough curves of low ring PAHs followed the normal distribution and the relative leaching ratios of 4 or more rings PAHs were low, and not more than 10%. The transport of PAHs was retarded compared with LAS, and the high ring PAHs were retarded more significantly. Linear correlation was observed between the relative leachability of the individual PAHs and the octanol/water coefficient of PAHs.
NASA Astrophysics Data System (ADS)
Hillebrand, O.; Nödler, K.; Licha, T.; Geyer, T.
2012-04-01
The application of organic micro-contaminants as indicators for contamination sources in aquifers and surface-water bodies has been increasingly discussed in the literature over the last years. One of the proposed substances was caffeine. It served as indicator for wastewater-leakage to various systems. As well, wastewater volumes could be estimated from caffeine concentrations. Although caffeine is known to be degradable, the degradation rates are normally only determined from mass balances or laboratory experiments. Degradation rates obtained from mass balances are relatively uncertain, as the input-function is difficult to be assessed. Laboratory experiments are hardly capable to consider the full complexity of natural systems and can rarely be transferred to those. To solve this problem, in-situ degradation rates of reactive indicators have to be determined. Especially multitracer tests can be used to access compound-specific transport parameters and degradation rates, relative to conservative tracers. A multitracer test with caffeine and uranine has been performed in a karst system (catchment of the Gallusquelle spring, SW Germany). From the breakthrough curves of the tracers, the transport behavior and the in-situ degradation rate of caffeine could be deduced. The tracers were injected into a sinkhole with a linear distance of 3000 m to the spring. The mean residence time of the tracers was found to be 84 h at a flow velocity of 35 m/h. Throughout the whole experiment, the spring discharge was constant at 187 L/s. Uranine served as conservative reference-tracer for the calibration of a one-dimensional transport model with respect to solute-unspecific parameters. Relative to that, the tracer breakthrough curve of caffeine was interpreted. As solute-specific parameters the retardation coefficient as well as degradation rate of caffeine in the investigated karst aquifer could be determined. The results indicate, that caffeine is slightly retarded in the
NASA Astrophysics Data System (ADS)
Libera, A.; de Barros, F.; Guadagnini, A.
2015-12-01
We study and compare the effect of temporally variable and uniform pumping regimes on key features of contaminant transport in a randomly heterogeneous aquifer. Pumping wells are used for groundwater supply in the context of urban, agricultural, and industrial activities. Groundwater management agencies typically schedule groundwater extraction through a predefined sequence of pumping periods to balance benefits to anthropogenic activities and environmental needs. The impact of the spatial variability of aquifer hydraulic properties, such as hydraulic conductivity, on contaminant transport and associated solute residence times are widely studied. Only a limited number of studies address the way a given pumping schedule affects contaminant plume behavior in heterogeneous aquifers. In this context, the feedback between a transient pumping regime and contaminant breakthrough curves is largely unexplored. Our goal is to investigate the way diverse groundwater extraction strategies affect the history of solute concentration recovered at the well while accounting for the natural variability of the geological system, in the presence of incomplete information on hydraulic conductivity distribution. Considering the joint effects of spatially heterogeneous hydraulic conductivity and temporally varying well pumping rates, this work offers a realistic evaluation of groundwater contamination risk. The latter is here considered in the context of human health and is quantified in terms of the probability that harm will result from exposure to a contaminant found in groundwater. Two scenarios are considered: a pumping well that extracts a given amount of water operating (a) at a constant pumping rate and (b) under transient conditions. The analysis is performed within a numerical Monte Carlo framework. We probe the impact of diverse geostatistical structures to describe aquifer heterogeneity on solute breakthrough curves and the statistics of target environmental performance
The transport of contaminants during storms in the White Oak Creek and Melton Branch Watersheds
Solomon, D.K.; Marsh, J.D.; Wickliff, D.S.; Larsen, I.L.; Clapp, R.B.
1989-03-01
This report documents are transport of contaminants from SWSA 5 along two principle pathways: the saturated groundwater system and the intermittently saturated stormflow system. The results of a baseflow sampling effort and a dye tracer study, indicated that much of the transport through the saturated groundwater system occurs along discrete geologic features. These features appear to be related to the contact between the Maryville and Nolichucky members of the Conasauga shale. Three discrete sources of tritium to Melton Branch Stream (MBS) were identified and traced to SWSA 5 by measuring soil moisture and evapotranspiration along transects between MBS and SWSA 5.
NASA Astrophysics Data System (ADS)
Cvetkovic, Vladimir; Fiori, Aldo; Dagan, Gedeon
2016-04-01
The driving mechanism of contaminant transport in aquifers is groundwater flow, which is controlled by boundary conditions and heterogeneity of hydraulic properties. In this work we show how hydrodynamics and mass transfer can be combined in a general analytical manner to derive a physically-based (or process-based) residence time distribution for a given integral scale of the hydraulic conductivity; the result can be applied for a broad class of linear mass transfer processes. The derived tracer residence time distribution is a transfer function with parameters to be inferred from combined field and laboratory measurements. It is scalable relative to the correlation length and applicable for an arbitrary statistical distribution of the hydraulic conductivity. Based on the derived residence time distribution, the coefficient of variation and skewness of contaminant residence time are illustrated assuming a log-normal hydraulic conductivity distribution and first-order mass transfer. We show that for a low Damkohler number the coefficient of variation is more strongly influenced by mass transfer than by heterogeneity, whereas skewness is more strongly influenced by heterogeneity. The derived physically-based residence time distribution for solute transport in heterogeneous aquifers is particularly useful for studying natural attenuation of contaminants. We illustrate the relative impacts of high heterogeneity and a generalised (non-Fickian) multi-rate mass transfer on natural attenuation defined as contaminant mass loss from injection to a downstream compliance boundary.
Chorover, Jon; Perdrial, Nico; Mueller, Karl; Strepka, Caleb; OÃÂÃÂ¢ÃÂÃÂÃÂÃÂDay, Peggy; Rivera, Nelson; Um, Wooyong; Chang, Hyun-Shik; Steefel, Carl; Thompson, Aaron
2012-11-05
Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided thorough characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, partial pressure of carbon dioxide, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions. In this final report, we provide detailed descriptions of our results from this three-year study, completed in 2012 following a one-year no cost extension.
NASA Astrophysics Data System (ADS)
Matiatos, Ioannis; Papadopoulou, Maria P.; Varouchakis, Emmanouil A.
2016-04-01
As groundwater remains one of the most critical natural resources worldwide, numerical models of groundwater flow and contaminant mass transport provide a reliable tool for the efficient protection, planning and sustainable management of groundwater resources. This work focuses on the evaluation of the performance of different numerical models which have been developed to simulate spatiotemporal groundwater flow and contaminant mass transport in a coastal aquifer system. The evaluation of the models' performance has been based on 9 different statistical measures and indices of goodness of fit. Overall, the simulation of groundwater level and contaminant mass concentration delivered very good calibration and validation results in all cases, quite close to the desired values. Maps of aquifer water level and contaminant mass concentrations are provided for all cases in order the differences to be discussed and assessed. The selection of the appropriate model(s) is case oriented and it should be based on the problem's characteristics in order the spatiotemporal variability of the components under study to be optimally estimated.
Removing volatile contaminants from the unsaturated zone by inducing advective air-phase transport
Baehr, A.L.; Hoag, G.E.; Marley, M.C.
1989-01-01
Organic liquids inadvertently spilled and then distributed in the unsaturated zone can pose a long-term threat to ground water. Many of these substances have significant volatility, and thereby establish a premise for contaminant removal from the unsaturated zone by inducing advective air-phase transport with wells screened in the unsaturated zone. In order to focus attention on the rates of mass transfer from liquid to vapour phases, sand columns were partially saturated with gasoline and vented under steady air-flow conditions. The ability of an equilibrium-based transport model to predict the hydrocarbon vapor flux from the columns implies an efficient rate of local phase transfer for reasonably high air-phase velocities. Thus the success of venting remediations will depend primarily on the ability to induce an air-flow field in a heterogeneous unsaturated zone that will intersect the distributed contaminant. To analyze this aspect of the technique, a mathematical model was developed to predict radially symmetric air flow induced by venting from a single well. This model allows for in-situ determinations of air-phase permeability, which is the fundamental design parameter, and for the analysis of the limitations of a single well design. A successful application of the technique at a site once contaminated by gasoline supports the optimism derived from the experimental and modeliing phases of this study, and illustrates the well construction and field methods used to document the volatile contaminant recovery. ?? 1989.
Hodgson, K.M.; Lunsford, T.R.; Panjabi, G.
1994-01-01
The Reverse Osmosis/Coupled Transport process is a innovative means of removing radionuclides from contaminated groundwater at the Hanford Site. Specifically, groundwater in the 200 West Area of the Hanford Site has been contaminated with uranium, technetium, and nitrate. Investigations are proceeding to determine the most cost effective method to remove these contaminants. The process described in this paper combines three different membrane technologies (reverse osmosis, coupled transport, and nanofiltration to purify the groundwater while extracting and concentrating uranium, technetium, and nitrate into separate solutions. This separation allows for the future use of the radionuclides, if needed, and reduces the amount of waste that will need to be disposed of. This process has the potential to concentrate the contaminants into solutions with volumes in a ratio of 1/10,000 of the feed volume. This compares to traditional volume reductions of 10 to 100 for ion exchange and stand-alone reverse osmosis. The successful demonstration of this technology could result in significant savings in the overall cost of decontaminating the groundwater.
Ultra-refractive and extended-range one-dimensional photonic crystal superprisms
NASA Technical Reports Server (NTRS)
Ting, D. Z. Y.
2003-01-01
We describe theoretical analysis and design of one-dimensional photonic crystal prisms. We found that inside the photonic crystal, for frequencies near the band edges, light propagation direction is extremely sensitive to the variations in wavelength and incident angle.
A Large Class of Exact Solutions to the One-Dimensional Schrodinger Equation
ERIC Educational Resources Information Center
Karaoglu, Bekir
2007-01-01
A remarkable property of a large class of functions is exploited to generate exact solutions to the one-dimensional Schrodinger equation. The method is simple and easy to implement. (Contains 1 table and 1 figure.)
NASA Astrophysics Data System (ADS)
Gvelesiani, Simon; Lippoth, Friedrich; Walker, Christoph
2015-12-01
We provide sufficient and almost optimal conditions for global existence of classical solutions in parabolic Hölder spaces to quasilinear one-dimensional parabolic problems with dynamical boundary conditions.
Safety analysis report for packaging, onsite, long-length contaminated equipment transport system
McCormick, W.A.
1997-05-09
This safety analysis report for packaging describes the components of the long-length contaminated equipment (LLCE) transport system (TS) and provides the analyses, evaluations, and associated operational controls necessary for the safe use of the LLCE TS on the Hanford Site. The LLCE TS will provide a standardized, comprehensive approach for the disposal of approximately 98% of LLCE scheduled to be removed from the 200 Area waste tanks.
A Fast Fourier transform stochastic analysis of the contaminant transport problem
Deng, F.W.; Cushman, J.H.; Delleur, J.W.
1993-01-01
A three-dimensional stochastic analysis of the contaminant transport problem is developed in the spirit of Naff (1990). The new derivation is more general and simpler than previous analysis. The fast Fourier transformation is used extensively to obtain numerical estimates of the mean concentration and various spatial moments. Data from both the Borden and Cape Cod experiments are used to test the methodology. Results are comparable to results obtained by other methods, and to the experiments themselves.
Quasicrystalline electronic states of a one-dimensionally modulated Ag film.
Moras, P; Theis, W; Ferrari, L; Gardonio, S; Fujii, J; Horn, K; Carbone, C
2006-04-21
Ag films on GaAs(110) exhibit a one-dimensional quasiperiodic modulation, resulting in a Fibonacci sequence of parallel stripes with two different widths. Valence level photoemission shows that the Ag electronic states acquire a unique character along the quasiperiodic direction, distinctively manifested by a hierarchy of energy level replicas and avoided crossings at characteristic intervals in reciprocal space. These observations demonstrate the strong influence of the one-dimensional quasiperiodic potential on the Ag film states.
Elementary excitations for the one-dimensional Hubbard model at finite temperatures
NASA Astrophysics Data System (ADS)
Tomiyama, A.; Suga, S.; Okiji, A.
1997-07-01
The elementary excitations for the one-dimensional Hubbard model at finite temperatures are studied with the use of the Bethe ansatz solution. The formulation is based on the method of Yang and Yang, which was developed for the one-dimensional boson systems with the 0953-8984/9/27/014/img1-function type interaction. The dispersion relations and the excitation spectrums are obtained numerically for the charge and the spin degrees of freedom.
Bertsch, Paul M.; Seaman, John C.
1999-01-01
Surface reactive phases of soils and aquifers, comprised of phyllosilicate and metal oxohydroxide minerals along with humic substances, play a critical role in the regulation of contaminant fate and transport. Much of our knowledge concerning contaminant-mineral interactions at the molecular level, however, is derived from extensive experimentation on model mineral systems. Although these investigations have provided a foundation for understanding reactive surface functional groups on individual mineral phases, the information cannot be readily extrapolated to complex mineral assemblages in natural systems. Recent studies have elucidated the role of less abundant mineral and organic substrates as important surface chemical modifiers and have demonstrated complex coupling of reactivity between permanent-charge phyllosilicates and variable-charge Fe-oxohydroxide phases. Surface chemical modifiers were observed to control colloid generation and transport processes in surface and subsurface environments as well as the transport of solutes and ionic tracers. The surface charging mechanisms operative in the complex mineral assemblages cannot be predicted based on bulk mineralogy or by considering surface reactivity of less abundant mineral phases based on results from model systems. The fragile nature of mineral assemblages isolated from natural systems requires novel techniques and experimental approaches for investigating their surface chemistry and reactivity free of artifacts. A complete understanding of the surface chemistry of complex mineral assemblages is prerequisite to accurately assessing environmental and human health risks of contaminants or in designing environmentally sound, cost-effective chemical and biological remediation strategies. PMID:10097043
Apul, Defne S; Gardner, Kevin H; Eighmy, T Taylor
2007-01-01
The goal of this research was to provide a tool for regulators to evaluate the groundwater contamination from the use of virgin and secondary materials in road construction. A finite element model, HYDRUS2D, was used to evaluate generic scenarios for secondary material use in base layers. Use of generic model results for particular applications was demonstrated through a steel slag example. The hydrology and reactive transport of contaminants were modeled in a two-dimensional cross section of a road. Model simulations showed that in an intact pavement, lateral velocities from the edge towards the centerline may transport contaminants in the base layer. The dominant transport mechanisms are advection closer to the edge and diffusion closer to the centerline. A shoulder joint in the pavement allows 0.03 to 0.45 m(3)/day of infiltration per meter of joint length as a function of the base and subgrade hydrology and the rain intensity. Scenario simulations showed that salts in the base layer of pavements are depleted by 99% in the first 20 years, whereas the metals may not reach the groundwater in 20 years at any significant concentrations if the pavement is built on adsorbing soils.
Apul, Defne S. Gardner, Kevin H. Eighmy, T. Taylor
2007-07-01
The goal of this research was to provide a tool for regulators to evaluate the groundwater contamination from the use of virgin and secondary materials in road construction. A finite element model, HYDRUS2D, was used to evaluate generic scenarios for secondary material use in base layers. Use of generic model results for particular applications was demonstrated through a steel slag example. The hydrology and reactive transport of contaminants were modeled in a two-dimensional cross section of a road. Model simulations showed that in an intact pavement, lateral velocities from the edge towards the centerline may transport contaminants in the base layer. The dominant transport mechanisms are advection closer to the edge and diffusion closer to the centerline. A shoulder joint in the pavement allows 0.03 to 0.45 m{sup 3}/day of infiltration per meter of joint length as a function of the base and subgrade hydrology and the rain intensity. Scenario simulations showed that salts in the base layer of pavements are depleted by 99% in the first 20 years, whereas the metals may not reach the groundwater in 20 years at any significant concentrations if the pavement is built on adsorbing soils.
Fraction of uninfected walkers in the one-dimensional Potts model
NASA Astrophysics Data System (ADS)
O'Donoghue, S. J.; Bray, A. J.
2002-05-01
The dynamics of the one-dimensional q-state Potts model, in the zero-temperature limit, can be formulated through the motion of random walkers which either annihilate (A+A-->∅) or coalesce (A+A-->A) with a q-dependent probability. We consider all of the walkers in this model to be mutually infectious. Whenever two walkers meet, they experience mutual contamination. Walkers which avoid an encounter with another random walker up to time t remain uninfected. The fraction of uninfected walkers is known to obey a power-law decay U(t)~t-φ(q), with a nontrivial exponent φ(q) [C. Monthus, Phys. Rev. E 54, 4844 (1996); S. N. Majumdar and S. J. Cornell, ibid. 57, 3757 (1998)]. We probe the numerical values of φ(q) to a higher degree of accuracy than previous simulations and relate the exponent φ(q) to the persistence exponent θ(q) [B. Derrida, V. Hakim, and V. Pasquier, Phys. Rev. Lett. 75, 751 (1995)], through the relation φ(q)=γ(q)θ(q) where γ is an exponent introduced in [S. J. O'Donoghue and A. J. Bray, preceding paper, Phys. Rev. E 65, XXXX (2002)]. Our study is extended to include the coupled diffusion-limited reaction A+A-->B, B+B-->A in one dimension with equal initial densities of A and B particles. We find that the density of walkers decays in this model as ρ(t)~t-1/2. The fraction of sites unvisited by either an A or a B particle is found to obey a power law, P(t)~t-θ with θ~=1.33. We discuss these exponents within the context of the q-state Potts model and present numerical evidence that the fraction of walkers which remain uninfected decays as U(t)~t-φ, where φ~=1.13 when infection occurs between like particles only, and φ~=1.93 when we also include cross-species contamination. We find that the relation between φ and θ in this model can also be characterized by an exponent γ, where similarly, φ=γθ.
A semi-analytical solution for simulating contaminant transport subject to chain-decay reactions.
Sudicky, Edward A; Hwang, Hyoun-Tae; Illman, Walter A; Wu, Yu-Shu; Kool, Jan B; Huyakorn, Peter
2013-01-01
We present a set of new, semi-analytical solutions to simulate three-dimensional contaminant transport subject to first-order chain-decay reactions. The aquifer is assumed to be areally semi-infinite, but finite in thickness. The analytical solution can treat the transformation of contaminants into daughter products, leading to decay chains consisting of multiple contaminant species and various reaction pathways. The solution in its current form is capable of accounting for up to seven species and four decay levels. The complex pathways are represented by means of first-order decay and production terms, while branching ratios account for decay stoichiometry. Besides advection, dispersion, bio-chemical or radioactive decay and daughter product formation, the model also accounts for sorption of contaminants on the aquifer solid phase with each species having a different retardation factor. First-type contaminant boundary conditions are utilized at the source (x=0 m) and can be either constant-in-time for each species, or the concentration can be allowed to undergo first-order decay. The solutions are obtained by exponential Fourier, Fourier cosine and Laplace transforms. Limiting forms of the solutions can be obtained in closed form, but we evaluate the general solutions by numerically inverting the analytical solutions in exponential Fourier and Laplace transform spaces. Various cases are generated and the solutions are verified against the HydroGeoSphere numerical model.
Steingraeber, M.T.; Wiener, J.G.
1995-01-01
Burrowing mayfly nymphs (Ephemeroptera) inhabit and ingest fine-grained sediments and detritus that may be enriched with metals and persistent organic compounds. The burrowing nymphs can externally adsorb and internally assimilate these contaminants, providing a link for the food chain transfer of potentially toxic substances from sediments to organisms in higher trophic levels. The emergent adults are short-lived and do not feed, thus their gut contents do not contribute greatly to their total contaminant burden. These characteristics make Hexagenia spp. And certain other burrowing mayflies useful for assessing ecosystem contamination. General protocols are presented for the collection, processing and analysis of emergent mayflies to assess the spatial distribution and bioaccumulation of sediment-associated contaminants in aquatic ecosystems. Two essential components of this bioassessment approach are a network of on-site volunteers with the materials and instructions needed to correctly collect and store samples and quality assurance procedures to estimate the accuracy of chemical analyses. The utility of this approach is demonstrated with an example of its application to the Upper Mississippi River (USA). Determination of cadmium, mercury and polychlorinated biphenyl congeners in emergent Hexagenia bilineata from a 1250 km reach of this river revealed (1) several source areas of contaminants and (2) distinct patterns in the bioaccumulation (and apparent sediment-associated transport) of each residue on both small and large spatial scales.
Transport of contaminants by Arctic sea ice and surface ocean currents
Pfirman, S.
1995-12-31
Sea ice and ocean currents transport contaminants in the Arctic from source areas on the shelves, to biologically active regions often more than a thousand kilometers away. Coastal regions along the Siberian margin are polluted by discharges of agricultural, industrial and military wastes in river runoff, from atmospheric deposition and ocean dumping. The Kara Sea is of particular concern because of deliberate dumping of radioactive waste, as well as the large input of polluted river water. Contaminants are incorporated in ice during suspension freezing on the shelves, and by atmospheric deposition during drift. Ice releases its contaminant load through brine drainage, surface runoff of snow and meltwater, and when the floe disintegrates. The marginal ice zone, a region of intense biological activity, may also be the site of major contaminant release. Potentially contaminated ice from the Kara Sea is likely to influence the marginal ice zones of the Barents and Greenland seas. From studies conducted to date it appears that sea ice from the Kara Sea does not typically enter the Beaufort Gyre, and thus is unlikely to affect the northern Canadian and Alaskan margins.
Monitoring Potential Transport of Radioactive Contaminants in Shallow Ephemeral Channels: FY 2012
Miller, Julianne J.; Mizell, Steve A.; McCurdy, Greg; Campbell, Scott A.
2012-09-01
The US Department of Energy (DOE) National Nuclear Security Administration (NNSA), Nevada Site Office (NSO), Environmental Management’s Soils Activity has authorized the Desert Research Institute (DRI) to conduct field assessments of potential sediment transport of contaminated soil from Corrective Action Unit (CAU) 550, Smoky Contamination Area (CA), during precipitation runoff events. CAU 550 includes Corrective Action Sites (CASs) 08-23-03, 08-23-04, 08-23-06, and 08-23-07; these CASs are associated with tests designated Ceres, Smoky, Oberon, and Titania, respectively. Field measurements at the T-4 Atmospheric Test Site, CAU 370, suggest that radioactive material may have migrated along a shallow ephemeral drainage that traverses the site (NNSA/NSO, 2009). (It is not entirely clear how contaminated soils got into their present location at the T-4 Site, but flow to the channel has been redirected and the contamination does not appear to be migrating at present.) Although DRI initially looked at the CAU 370 site, given that it could not be confirmed that migration of contamination into the channel was natural, an alternate study site was selected at CAU 550. Aerial surveys in selected portions of the Nevada National Security Site (NNSS) also suggest that radioactivity may be migrating along ephemeral channels in Areas 3, 8, 11, 18, and 25 (Colton, 1999). Figure 1 shows the results of a low-elevation aerial survey (Colton, 1999) in Area 8. The numbered markers in Figure 1 identify ground zero for three safety experiments conducted in 1958 [Oberon (number 1), Ceres (number 2), and Titania (number 4)] and a weapons effects test conducted in 1964, Mudpack (number 3). This survey suggests contaminants may be migrating down the ephemeral channels that traverse CAU 550. Note particularly the lobe of higher concentration extending southeastward at the south end of the high concentration area marked as number 3 in Figure 1. CAU 550 in Area 8 of the NNSS was selected for
The stability and transport of radiolabeled Fe_{2}O_{3} particles were studied using laboratory batch and column techniques. Core material collected from a shallow sand and gravel aquifer was used as the immobile column matrix material. Variables in the study incl...
Knopman, Debra S.; Voss, Clifford I.
1987-01-01
The spatial and temporal variability of sensitivities has a significant impact on parameter estimation and sampling design for studies of solute transport in porous media. Physical insight into the behavior of sensitivities is offered through an analysis of analytically derived sensitivities for the one-dimensional form of the advection-dispersion equation. When parameters are estimated in regression models of one-dimensional transport, the spatial and temporal variability in sensitivities influences variance and covariance of parameter estimates. Several principles account for the observed influence of sensitivities on parameter uncertainty. (1) Information about a physical parameter may be most accurately gained at points in space and time. (2) As the distance of observation points from the upstream boundary increases, maximum sensitivity to velocity during passage of the solute front increases. (3) The frequency of sampling must be 'in phase' with the S shape of the dispersion sensitivity curve to yield the most information on dispersion. (4) The sensitivity to the dispersion coefficient is usually at least an order of magnitude less than the sensitivity to velocity. (5) The assumed probability distribution of random error in observations of solute concentration determines the form of the sensitivities. (6) If variance in random error in observations is large, trends in sensitivities of observation points may be obscured by noise. (7) Designs that minimize the variance of one parameter may not necessarily minimize the variance of other parameters.
Ator, Scott; Garcia, Ana Maria.
2016-01-01
Understanding spatial variability in contaminant fate and transport is critical to efficient regional water-quality restoration. An approach to capitalize on previously calibrated spatially referenced regression (SPARROW) models to improve the understanding of contaminant fate and transport was developed and applied to the case of nitrogen in the 166,000 km2 Chesapeake Bay watershed. A continuous function of four hydrogeologic, soil, and other landscape properties significant (α = 0.10) to nitrogen transport from uplands to streams was evaluated and compared among each of the more than 80,000 individual catchments (mean area, 2.1 km2) in the watershed. Budgets (including inputs, losses or net change in storage in uplands and stream corridors, and delivery to tidal waters) were also estimated for nitrogen applied to these catchments from selected upland sources. Most (81%) of such inputs are removed, retained, or otherwise processed in uplands rather than transported to surface waters. Combining SPARROW results with previous budget estimates suggests 55% of this processing is attributable to denitrification, 23% to crop or timber harvest, and 6% to volatilization. Remaining upland inputs represent a net annual increase in landscape storage in soils or biomass exceeding 10 kg per hectare in some areas. Such insights are important for planning watershed restoration and for improving future watershed models.
A Generalized Model for Transport of Contaminants in Soil by Electric Fields
Paz-Garcia, Juan M.; Baek, Kitae; Alshawabkeh, Iyad D.; Alshawabkeh, Akram N.
2012-01-01
A generalized model applicable to soils contaminated with multiple species under enhanced boundary conditions during treatment by electric fields is presented. The partial differential equations describing species transport are developed by applying the law of mass conservation to their fluxes. Transport, due to migration, advection and diffusion, of each aqueous component and complex species are combined to produce one partial differential equation hat describes transport of the total analytical concentrations of component species which are the primary dependent variables. This transport couples with geochemical reactions such as aqueous equilibrium, sorption, precipitation and dissolution. The enhanced model is used to simulate electrokinetic cleanup of lead and copper contaminants at an Army Firing Range. Acid enhancement is achieved by the use of adipic acid to neutralize the basic front produced for the cathode electrochemical reaction. The model is able to simulate enhanced application of the process by modifying the boundary conditions. The model showed that kinetics of geochemical reactions, such as metals dissolution/leaching and redox reactions might be significant for realistic prediction of enhanced electrokinetic extraction of metals in real world applications. PMID:22242884
Evaluation of wastewater contaminant transport in surface waters using verified Lagrangian sampling.
Antweiler, Ronald C; Writer, Jeffrey H; Murphy, Sheila F
2014-02-01
Contaminants released from wastewater treatment plants can persist in surface waters for substantial distances. Much research has gone into evaluating the fate and transport of these contaminants, but this work has often assumed constant flow from wastewater treatment plants. However, effluent discharge commonly varies widely over a 24-hour period, and this variation controls contaminant loading and can profoundly influence interpretations of environmental data. We show that methodologies relying on the normalization of downstream data to conservative elements can give spurious results, and should not be used unless it can be verified that the same parcel of water was sampled. Lagrangian sampling, which in theory samples the same water parcel as it moves downstream (the Lagrangian parcel), links hydrologic and chemical transformation processes so that the in-stream fate of wastewater contaminants can be quantitatively evaluated. However, precise Lagrangian sampling is difficult, and small deviations - such as missing the Lagrangian parcel by less than 1h - can cause large differences in measured concentrations of all dissolved compounds at downstream sites, leading to erroneous conclusions regarding in-stream processes controlling the fate and transport of wastewater contaminants. Therefore, we have developed a method termed "verified Lagrangian" sampling, which can be used to determine if the Lagrangian parcel was actually sampled, and if it was not, a means for correcting the data to reflect the concentrations which would have been obtained had the Lagrangian parcel been sampled. To apply the method, it is necessary to have concentration data for a number of conservative constituents from the upstream, effluent, and downstream sites, along with upstream and effluent concentrations that are constant over the short-term (typically 2-4h). These corrections can subsequently be applied to all data, including non-conservative constituents. Finally, we show how data
NASA Astrophysics Data System (ADS)
Kim, Song-Bae; Corapcioglu, M. Yavuz
2002-09-01
In riverbank filtration, the removal of organic contaminants is an important task for the production of good quality drinking water. The transport of an organic contaminant in riverbank filtration can be retarded by sorption on to the solid matrix and facilitated by the presence of mobile colloids. In the presence of dissolved organic matter (DOM) and bacteria, the subsurface environment can be modeled as a four-phase porous medium: two mobile colloidal phases, an aqueous phase, and a solid matrix. In this study, a kinetic model is developed to simulate the contaminant transport in riverbank filtration in the presence of DOM and bacteria. The bacterial deposition and the contaminant sorption on bacteria and DOM are expressed with kinetic expressions. The model equations are solved numerically with a fully implicit finite difference method. Simulation results show that the contaminant mobility increases greatly in riverbank filtration due to the presence of DOM. The mobility can be enhanced further when the bacteria and DOM are present together in the aquifer. In this system, the total aqueous phase contaminant concentration, Cct+, includes the contaminant dissolved in the aqueous phase, Cc+, the contaminant sorbed to DOM, σcd+, and the contaminant sorbed to mobile bacteria, Cb+σcbm+, (i.e. Cct+= Cc++ σcd++ Cb+σcbm+). Sensitivity analysis illustrates that the distribution of the total aqueous phase contaminants among the dissolved phase, DOM and bacteria is changed significantly with various Damköhler numbers related to the contaminant sorption on mobile colloids.
One-dimensional radiation-hydrodynamic scaling studies of imploding spherical plasma liners
Awe, T. J.; Adams, C. S.; Davis, J. S.; Hanna, D. S.; Hsu, S. C.; Cassibry, J. T.
2011-07-15
One-dimensional radiation-hydrodynamic simulations are performed to develop insight into the scaling of stagnation pressure with initial conditions of an imploding spherical plasma shell or ''liner.'' Simulations reveal the evolution of high-Mach-number (M), annular, spherical plasma flows during convergence, stagnation, shock formation, and disassembly, and indicate that cm- and {mu}s-scale plasmas with peak pressures near 1 Mbar can be generated by liners with initial kinetic energy of several hundred kilo-joules. It is shown that radiation transport and thermal conduction must be included to avoid non-physical plasma temperatures at the origin which artificially limit liner convergence and, thus, the peak stagnation pressure. Scalings of the stagnated plasma lifetime ({tau}{sub stag}) and average stagnation pressure (P{sub stag}, the pressure at the origin, averaged over {tau}{sub stag}) are determined by evaluating a wide range of liner initial conditions. For high-M flows, {tau}{sub stag} {approx} {Delta}R/v{sub 0}, where {Delta}R and v{sub 0} are the initial liner thickness and velocity, respectively. Furthermore, for argon liners, P{sub stag} scales approximately as v{sub 0}{sup 15/4} over a wide range of initial densities (n{sub 0}) and as n{sub 0}{sup 1/2} over a wide range of v{sub 0}. The approximate scaling P{sub stag} {approx} M{sup 3/2} is also found for a wide range of liner-plasma initial conditions.
One-dimensional conduction through supporting electrolytes: Two-scale cathodic Debye layer
NASA Astrophysics Data System (ADS)
Almog, Yaniv; Yariv, Ehud
2011-10-01
Supporting-electrolyte solutions comprise chemically inert cations and anions, produced by salt dissolution, together with a reactive ionic species that may be consumed and generated on bounding ion-selective surfaces (e.g., electrodes or membranes). Upon application of an external voltage, a Faraday current is thereby established. It is natural to analyze this ternary-system process through a one-dimensional transport problem, employing the thin Debye-layer limit. Using a simple model of ideal ion-selective membranes, we have recently addressed this problem for moderate voltages [Yariv and Almog, Phys. Rev. Lett.PRLTAO0031-900710.1103/PhysRevLett.105.176101 105, 176101 (2010)], predicting currents that scale as a fractional power of Debye thickness. We address herein the complementary problem of moderate currents. We employ matched asymptotic expansions, separately analyzing the two inner thin Debye layers adjacent to the ion-selective surfaces and the outer electroneutral region outside them. A straightforward calculation following comparable singular-perturbation analyses of binary systems is frustrated by the prediction of negative ionic concentrations near the cathode. Accompanying numerical simulations, performed for small values of Debye thickness, indicate a number unconventional features occurring at that region, such as inert-cation concentration amplification and electric-field intensification. The current-voltage correlation data of the electrochemical cell, obtained from compilation of these simulations, does not approach a limit as the Debye thickness vanishes. Resolution of these puzzles reveals a transformation of the asymptotic structure of the cathodic Debye layer. This reflects the emergence of an internal boundary layer, adjacent to the cathode, wherein field and concentration scaling differs from those of the Gouy-Chapman theory. The two-scale feature of the cathodic Debye layer is manifested through a logarithmic voltage scaling with Debye
A semi-analytical method for simulating transient contaminant transport originating from the dissolution of multicomponent nonaqueous phase liquid (NAPL) pools in three-dimensional, saturated, homogeneous porous media is presented. Each dissolved component may undergo first-order...
Chromatographic alteration of a nonionic surfactant mixture during transport through DNAPL-contaminated aquifer sediment may occur due to differential loss of oligomers to sediment and to dense nonaqueous phase liquid (DNAPL). These losses may significantly alter the solubilizing...