optimizing biogeochemical reduction: Topics by Science.gov

Apparatus for Cold, Pressurized Biogeochemical Experiments

NASA Technical Reports Server (NTRS)

Amashukeli, Xenia; Pappalardo, Robert T.; Connon, Stephanie A.; Gleeson, Damhnait F.

2010-01-01

A laboratory apparatus has been devised as a means of studying plausible biogeochemical reactions under high-pressure, low-temperature aqueous, anaerobic conditions like those conjectured to prevail in a liquid water ocean on Europa (the fourth largest moon of the planet Jupiter). The experiments to be performed by use of this apparatus are intended to enhance understanding of how life (if any) could originate and evolve in the Europa ocean environment. Inasmuch as terrestrial barophilic, psychrophilic organisms that thrive under anaerobic conditions are used in the experiments, the experiments may also contribute to terrestrial biogeochemistry. The apparatus (see figure) includes a bolt-closure reaction vessel secured inside a refrigerator that maintains a temperature of 4 C. Pressurized water is supplied to the interior of the vessel by a hydrostatic pump, which is attached to the vessel via high-pressure fittings. The terrestrial organisms used in the experiments thus far have been several facultative barophilic, psychrophilic stains of Shewanella bacteria. In the experiments, these organisms have been tested for reduction of ferric ion by growing them in the presence of a ferric food source under optimized terrestrial conditions. The short-term goal of these experiments has been to select Shewanella strains that exhibit iron-reduction capability and test their ability to facilitate biogeochemical reduction of iron under temperature and pressure conditions imitating those in Europa s ocean. It is anticipated, that, once growth under Europa-like conditions has been achieved, the selected Shewanella strains will be used to facilitate biogeochemical reactions of sulfate and carbonate with hydrogen gas. Any disequilibrium of the products with the environment would be interpreted as signifying biogenic activity and the possibility of life in Europa s ocean.
Linking Chaotic Advection with Subsurface Biogeochemical Processes

NASA Astrophysics Data System (ADS)

Mays, D. C.; Freedman, V. L.; White, S. K.; Fang, Y.; Neupauer, R.

2017-12-01

This work investigates the extent to which groundwater flow kinematics drive subsurface biogeochemical processes. In terms of groundwater flow kinematics, we consider chaotic advection, whose essential ingredient is stretching and folding of plumes. Chaotic advection is appealing within the context of groundwater remediation because it has been shown to optimize plume spreading in the laminar flows characteristic of aquifers. In terms of subsurface biogeochemical processes, we consider an existing model for microbially-mediated reduction of relatively mobile uranium(VI) to relatively immobile uranium(IV) following injection of acetate into a floodplain aquifer beneath a former uranium mill in Rifle, Colorado. This model has been implemented in the reactive transport code eSTOMP, the massively parallel version of STOMP (Subsurface Transport Over Multiple Phases). This presentation will report preliminary numerical simulations in which the hydraulic boundary conditions in the eSTOMP model are manipulated to simulate chaotic advection resulting from engineered injection and extraction of water through a manifold of wells surrounding the plume of injected acetate. This approach provides an avenue to simulate the impact of chaotic advection within the existing framework of the eSTOMP code.
Identifying biogeochemical processes beneath stormwater infiltration ponds in support of a new best management practice for groundwater protection

USGS Publications Warehouse

O'Reilly, Andrew M.; Chang, Ni-Bin; Wanielista, Martin P.; Xuan, Zhemin; Schirmer, Mario; Hoehn, Eduard; Vogt, Tobias

2011-01-01

When applying a stormwater infiltration pond best management practice (BMP) for protecting the quality of underlying groundwater, a common constituent of concern is nitrate. Two stormwater infiltration ponds, the SO and HT ponds, in central Florida, USA, were monitored. A temporal succession of biogeochemical processes was identified beneath the SO pond, including oxygen reduction, denitrification, manganese and iron reduction, and methanogenesis. In contrast, aerobic conditions persisted beneath the HT pond, resulting in nitrate leaching into groundwater. Biogeochemical differences likely are related to soil textural and hydraulic properties that control surface/subsurface oxygen exchange. A new infiltration BMP was developed and a full-scale application was implemented for the HT pond. Preliminary results indicate reductions in nitrate concentration exceeding 50% in soil water and shallow groundwater beneath the HT pond.
Assessment of the GHG Reduction Potential from Energy Crops Using a Combined LCA and Biogeochemical Process Models: A Review

PubMed Central

Jiang, Dong; Hao, Mengmeng; Wang, Qiao; Huang, Yaohuan; Fu, Xinyu

2014-01-01

The main purpose for developing biofuel is to reduce GHG (greenhouse gas) emissions, but the comprehensive environmental impact of such fuels is not clear. Life cycle analysis (LCA), as a complete comprehensive analysis method, has been widely used in bioenergy assessment studies. Great efforts have been directed toward establishing an efficient method for comprehensively estimating the greenhouse gas (GHG) emission reduction potential from the large-scale cultivation of energy plants by combining LCA with ecosystem/biogeochemical process models. LCA presents a general framework for evaluating the energy consumption and GHG emission from energy crop planting, yield acquisition, production, product use, and postprocessing. Meanwhile, ecosystem/biogeochemical process models are adopted to simulate the fluxes and storage of energy, water, carbon, and nitrogen in the soil-plant (energy crops) soil continuum. Although clear progress has been made in recent years, some problems still exist in current studies and should be addressed. This paper reviews the state-of-the-art method for estimating GHG emission reduction through developing energy crops and introduces in detail a new approach for assessing GHG emission reduction by combining LCA with biogeochemical process models. The main achievements of this study along with the problems in current studies are described and discussed. PMID:25045736
Modeling Global Ocean Biogeochemistry With Physical Data Assimilation: A Pragmatic Solution to the Equatorial Instability

NASA Astrophysics Data System (ADS)

Park, Jong-Yeon; Stock, Charles A.; Yang, Xiaosong; Dunne, John P.; Rosati, Anthony; John, Jasmin; Zhang, Shaoqing

2018-03-01

Reliable estimates of historical and current biogeochemistry are essential for understanding past ecosystem variability and predicting future changes. Efforts to translate improved physical ocean state estimates into improved biogeochemical estimates, however, are hindered by high biogeochemical sensitivity to transient momentum imbalances that arise during physical data assimilation. Most notably, the breakdown of geostrophic constraints on data assimilation in equatorial regions can lead to spurious upwelling, resulting in excessive equatorial productivity and biogeochemical fluxes. This hampers efforts to understand and predict the biogeochemical consequences of El Niño and La Niña. We develop a strategy to robustly integrate an ocean biogeochemical model with an ensemble coupled-climate data assimilation system used for seasonal to decadal global climate prediction. Addressing spurious vertical velocities requires two steps. First, we find that tightening constraints on atmospheric data assimilation maintains a better equatorial wind stress and pressure gradient balance. This reduces spurious vertical velocities, but those remaining still produce substantial biogeochemical biases. The remainder is addressed by imposing stricter fidelity to model dynamics over data constraints near the equator. We determine an optimal choice of model-data weights that removed spurious biogeochemical signals while benefitting from off-equatorial constraints that still substantially improve equatorial physical ocean simulations. Compared to the unconstrained control run, the optimally constrained model reduces equatorial biogeochemical biases and markedly improves the equatorial subsurface nitrate concentrations and hypoxic area. The pragmatic approach described herein offers a means of advancing earth system prediction in parallel with continued data assimilation advances aimed at fully considering equatorial data constraints.
Surrogate-Based Optimization of Biogeochemical Transport Models

NASA Astrophysics Data System (ADS)

Prieß, Malte; Slawig, Thomas

2010-09-01

First approaches towards a surrogate-based optimization method for a one-dimensional marine biogeochemical model of NPZD type are presented. The model, developed by Oschlies and Garcon [1], simulates the distribution of nitrogen, phytoplankton, zooplankton and detritus in a water column and is driven by ocean circulation data. A key issue is to minimize the misfit between the model output and given observational data. Our aim is to reduce the overall optimization cost avoiding expensive function and derivative evaluations by using a surrogate model replacing the high-fidelity model in focus. This in particular becomes important for more complex three-dimensional models. We analyse a coarsening in the discretization of the model equations as one way to create such a surrogate. Here the numerical stability crucially depends upon the discrete stepsize in time and space and the biochemical terms. We show that for given model parameters the level of grid coarsening can be choosen accordingly yielding a stable and satisfactory surrogate. As one example of a surrogate-based optimization method we present results of the Aggressive Space Mapping technique (developed by John W. Bandler [2, 3]) applied to the optimization of this one-dimensional biogeochemical transport model.
Catchment Legacies and Time Lags: A Parsimonious Watershed Model to Predict the Effects of Legacy Storage on Nitrogen Export

PubMed Central

Van Meter, Kimberly J.; Basu, Nandita B.

2015-01-01

Nutrient legacies in anthropogenic landscapes, accumulated over decades of fertilizer application, lead to time lags between implementation of conservation measures and improvements in water quality. Quantification of such time lags has remained difficult, however, due to an incomplete understanding of controls on nutrient depletion trajectories after changes in land-use or management practices. In this study, we have developed a parsimonious watershed model for quantifying catchment-scale time lags based on both soil nutrient accumulations (biogeochemical legacy) and groundwater travel time distributions (hydrologic legacy). The model accurately predicted the time lags observed in an Iowa watershed that had undergone a 41% conversion of area from row crop to native prairie. We explored the time scales of change for stream nutrient concentrations as a function of both natural and anthropogenic controls, from topography to spatial patterns of land-use change. Our results demonstrate that the existence of biogeochemical nutrient legacies increases time lags beyond those due to hydrologic legacy alone. In addition, we show that the maximum concentration reduction benefits vary according to the spatial pattern of intervention, with preferential conversion of land parcels having the shortest catchment-scale travel times providing proportionally greater concentration reductions as well as faster response times. In contrast, a random pattern of conversion results in a 1:1 relationship between percent land conversion and percent concentration reduction, irrespective of denitrification rates within the landscape. Our modeling framework allows for the quantification of tradeoffs between costs associated with implementation of conservation measures and the time needed to see the desired concentration reductions, making it of great value to decision makers regarding optimal implementation of watershed conservation measures. PMID:25985290
Catchment legacies and time lags: a parsimonious watershed model to predict the effects of legacy storage on nitrogen export.

PubMed

Van Meter, Kimberly J; Basu, Nandita B

2015-01-01

Nutrient legacies in anthropogenic landscapes, accumulated over decades of fertilizer application, lead to time lags between implementation of conservation measures and improvements in water quality. Quantification of such time lags has remained difficult, however, due to an incomplete understanding of controls on nutrient depletion trajectories after changes in land-use or management practices. In this study, we have developed a parsimonious watershed model for quantifying catchment-scale time lags based on both soil nutrient accumulations (biogeochemical legacy) and groundwater travel time distributions (hydrologic legacy). The model accurately predicted the time lags observed in an Iowa watershed that had undergone a 41% conversion of area from row crop to native prairie. We explored the time scales of change for stream nutrient concentrations as a function of both natural and anthropogenic controls, from topography to spatial patterns of land-use change. Our results demonstrate that the existence of biogeochemical nutrient legacies increases time lags beyond those due to hydrologic legacy alone. In addition, we show that the maximum concentration reduction benefits vary according to the spatial pattern of intervention, with preferential conversion of land parcels having the shortest catchment-scale travel times providing proportionally greater concentration reductions as well as faster response times. In contrast, a random pattern of conversion results in a 1:1 relationship between percent land conversion and percent concentration reduction, irrespective of denitrification rates within the landscape. Our modeling framework allows for the quantification of tradeoffs between costs associated with implementation of conservation measures and the time needed to see the desired concentration reductions, making it of great value to decision makers regarding optimal implementation of watershed conservation measures.
Investigation of In-situ Biogeochemical Reduction of Chlorinated Solvents in Groundwater by Reduced Iron Minerals

EPA Science Inventory

Biogeochemical transformation is a process in which chlorinated solvents are degraded abiotically by reactive minerals formed by, at least in part or indirectly from, anaerobic biological processes. Five mulch biowall and/or vegetable oil-based bioremediation applications for tr...
Evaluating the role of sulfur and hyporheic exchange in biogeochemical cycling in riparian wetlands

NASA Astrophysics Data System (ADS)

Ng, G. H. C.; O'Hara, P. A.; Santelli, C. M.; Rosenfeld, C.; Yourd, A.

2017-12-01

Although the mixing of surface water and groundwater is well-recognized to support hotspots of redox activities such as denitrification, few hyporheic zone studies have examined sulfur reactions. Because sulfate concentrations in wetlands, lake beds, and stream beds are low compared to in marine settings, the hierarchical redox tower dictates that sulfate reduction should play a substantially lesser role in biogeochemical cycling than nitrate or iron reduction when these sediments become anoxic. However, recent experiments challenge the classically held redox sequence by revealing "cryptic" sulfur cycling that can support unexpectedly high sulfate reduction rates and could be driving iron and carbon cycling through coupled reactions. Sulfur biogeochemical processes remain poorly understood in field settings, where little is known about the impact of hydrologic fluxes. Our study examines how hyporheic flux can "kick" forward cryptic sulfur cycling and related iron and carbon reactions by perturbing geochemical gradients to which microbial communities respond. We evaluate field-scale cycling of iron, sulfur, and carbon through a combination of hydrologic monitoring, microbial and geochemical analyses, and reactive-transport modeling at a riparian wetland site in northeastern Minnesota that is impacted by mining practices. In particular, we assess how varying fluxes between high sulfate concentration surface water and lower sulfate concentration groundwater over a season could be (1) facilitating intensified sulfur cycling coupled to abiotic iron reduction and (2) altering methane release possibly through anaerobic methane oxidation. Our findings can help clarify the importance of sulfur in non-marine biogeochemical cycling and provide better understanding of how anthropogenic activities can impact critical freshwater systems.
Scientific Discovery through Advanced Computing (SciDAC-3) Partnership Project Annual Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hoffman, Forest M.; Bochev, Pavel B.; Cameron-Smith, Philip J..

The Applying Computationally Efficient Schemes for BioGeochemical Cycles ACES4BGC Project is advancing the predictive capabilities of Earth System Models (ESMs) by reducing two of the largest sources of uncertainty, aerosols and biospheric feedbacks, with a highly efficient computational approach. In particular, this project is implementing and optimizing new computationally efficient tracer advection algorithms for large numbers of tracer species; adding important biogeochemical interactions between the atmosphere, land, and ocean models; and applying uncertainty quanti cation (UQ) techniques to constrain process parameters and evaluate uncertainties in feedbacks between biogeochemical cycles and the climate system.
Error assessment of biogeochemical models by lower bound methods (NOMMA-1.0)

NASA Astrophysics Data System (ADS)

Sauerland, Volkmar; Löptien, Ulrike; Leonhard, Claudine; Oschlies, Andreas; Srivastav, Anand

2018-03-01

Biogeochemical models, capturing the major feedbacks of the pelagic ecosystem of the world ocean, are today often embedded into Earth system models which are increasingly used for decision making regarding climate policies. These models contain poorly constrained parameters (e.g., maximum phytoplankton growth rate), which are typically adjusted until the model shows reasonable behavior. Systematic approaches determine these parameters by minimizing the misfit between the model and observational data. In most common model approaches, however, the underlying functions mimicking the biogeochemical processes are nonlinear and non-convex. Thus, systematic optimization algorithms are likely to get trapped in local minima and might lead to non-optimal results. To judge the quality of an obtained parameter estimate, we propose determining a preferably large lower bound for the global optimum that is relatively easy to obtain and that will help to assess the quality of an optimum, generated by an optimization algorithm. Due to the unavoidable noise component in all observations, such a lower bound is typically larger than zero. We suggest deriving such lower bounds based on typical properties of biogeochemical models (e.g., a limited number of extremes and a bounded time derivative). We illustrate the applicability of the method with two real-world examples. The first example uses real-world observations of the Baltic Sea in a box model setup. The second example considers a three-dimensional coupled ocean circulation model in combination with satellite chlorophyll a.
Modeling impacts of water and fertilizer management on the ecosystem service of rice rotated cropping system in China

NASA Astrophysics Data System (ADS)

Chen, H.; Yu, C.; Li, C.

2015-12-01

Sustainable agricultural intensification demand optimum resource managements of agro-ecosystems. Detailed information on the impacts of water use and nutrient application on agro-ecosystem services including crop yields, greenhouse gas (GHG) emissions and nitrogen (N) loss is the key to guide field managements. In this study, we use the DeNitrification-DeComposition (DNDC) model to simulate the biogeochemical processes for rice rotated cropping systems in China. We set varied scenarios of water use in more than 1600 counties, and derived optimal rates of N application for each county in accordance to water use scenarios. Our results suggest that 0.88 ± 0.33 Tg per year (mean ± standard deviation) of synthetic N could be reduced without reducing rice yields, which accounts for 15.7 ± 5.9% of current N application in China. Field managements with shallow flooding and optimal N applications could enhance ecosystem services on a national scale, leading to 34.3% reduction of GHG emissions (CH4, N2O, and CO2), 2.8% reduction of overall N loss (NH3 volatilization, denitrification and N leaching) and 1.7% increase of rice yields, as compared to current management conditions. Among provinces with major rice production, Jiangsu, Yunnan, Guizhou, and Hubei could achieve more than 40% reduction of GHG emissions under appropriate water managements, while Zhejiang, Guangdong, and Fujian could reduce more than 30% N loss with optimal N applications. Our modeling efforts suggest that China is likely to benefit from reforming water and fertilization managements for rice rotated cropping system in terms of sustainable crop yields, GHG emission mitigation and N loss reduction, and the reformation should be prioritized in the above-mentioned provinces. Keywords: water regime, nitrogen fertilization, sustainable management, ecological modeling, DNDC
Biogeochemical carbon coupling influences global precipitation in geoengineering experiments

NASA Astrophysics Data System (ADS)

Fyfe, J. C.; Cole, J. N. S.; Arora, V. K.; Scinocca, J. F.

2013-02-01

Abstract Climate model studies in which CO2-induced global warming is offset by engineered decreases of incoming solar radiation are generally robust in their prediction of reduced amounts of global precipitation. While this precipitation response has been explained on the basis of changes in net radiation controlling evaporative processes at the surface, there has been relatively little consideration of the relative role of biogeochemical carbon-cycle interactions. To address this issue, we employ an Earth System Model that includes oceanic and terrestrial carbon components to isolate the impact of biogeochemical carbon coupling on the precipitation response in geoengineering experiments for two types of solar radiation management. We show that carbon coupling is responsible for a large fraction of the global precipitation reduction in such geoengineering experiments and that the primary effect comes from reduced transpiration through the leaves of plants and trees in the terrestrial component of the carbon cycle due to elevated CO2. Our results suggest that biogeochemical interactions are as important as changes in net radiation and that climate models that do not account for such carbon coupling may significantly underestimate precipitation reductions in a geoengineered world. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1406720-targeted-quantification-functional-enzyme-dynamics-environmental-samples-microbially-mediated-biogeochemical-processes-targeted-quantification-functional-enzyme-dynamics','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1406720-targeted-quantification-functional-enzyme-dynamics-environmental-samples-microbially-mediated-biogeochemical-processes-targeted-quantification-functional-enzyme-dynamics">Targeted quantification of functional enzyme dynamics in environmental samples for microbially mediated biogeochemical processes: Targeted quantification of functional enzyme dynamics</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Li, Minjing; Gao, Yuqian; Qian, Wei-Jun Microbially mediated biogeochemical processes are catalyzed by enzymes that control the transformation of carbon, nitrogen, and other elements in environment. The dynamic linkage between enzymes and biogeochemical species transformation has, however, rarely been investigated because of the lack of analytical approaches to efficiently and reliably quantify enzymes and their dynamics in soils and sediments. Herein, we developed a signature peptide-based technique for sensitively quantifying dissimilatory and assimilatory enzymes using nitrate-reducing enzymes in a hyporheic zone sediment as an example. Moreover, the measured changes in enzyme concentration were found to correlate with the nitrate reduction rate in a way different frommore » that inferred from biogeochemical models based on biomass or functional genes as surrogates for functional enzymes. This phenomenon has important implications for understanding and modeling the dynamics of microbial community functions and biogeochemical processes in environments. Our results also demonstrate the importance of enzyme quantification for the identification and interrogation of those biogeochemical processes with low metabolite concentrations as a result of faster enzyme-catalyzed consumption of metabolites than their production. The dynamic enzyme behaviors provide a basis for the development of enzyme-based models to describe the relationship between the microbial community and biogeochemical processes.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70039045','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70039045">Cyclic biogeochemical processes and nitrogen fate beneath a subtropical stormwater infiltration basin</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> O'Reilly, Andrew M.; Chang, Ni-Bin; Wanielista, Martin P. 2012-01-01 A stormwater infiltration basin in north–central Florida, USA, was monitored from 2007 through 2008 to identify subsurface biogeochemical processes, with emphasis on N cycling, under the highly variable hydrologic conditions common in humid, subtropical climates. Cyclic variations in biogeochemical processes generally coincided with wet and dry hydrologic conditions. Oxidizing conditions in the subsurface persisted for about one month or less at the beginning of wet periods with dissolved O2 and NO3- showing similar temporal patterns. Reducing conditions in the subsurface evolved during prolonged flooding of the basin. At about the same time O2 and NO3- reduction concluded, Mn, Fe and SO42- reduction began, with the onset of methanogenesis one month later. Reducing conditions persisted up to six months, continuing into subsequent dry periods until the next major oxidizing infiltration event. Evidence of denitrification in shallow groundwater at the site is supported by median NO3-–N less than 0.016 mg L-1, excess N2 up to 3 mg L-1 progressively enriched in δ15N during prolonged basin flooding, and isotopically heavy δ15N and δ18O of NO3- (up to 25‰ and 15‰, respectively). Isotopic enrichment of newly infiltrated stormwater suggests denitrification was partially completed within two days. Soil and water chemistry data suggest that a biogeochemically active zone exists in the upper 1.4 m of soil, where organic carbon was the likely electron donor supplied by organic matter in soil solids or dissolved in infiltrating stormwater. The cyclic nature of reducing conditions effectively controlled the N cycle, switching N fate beneath the basin from NO3- leaching to reduction in the shallow saturated zone. Results can inform design of functionalized soil amendments that could replace the native soil in a stormwater infiltration basin and mitigate potential NO3- leaching to groundwater by replicating the biogeochemical conditions under the observed basin. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018CSR...161...29L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018CSR...161...29L">San Francisco Bay nutrients and plankton dynamics as simulated by a coupled hydrodynamic-ecosystem model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Liu, Qianqian; Chai, Fei; Dugdale, Richard; Chao, Yi; Xue, Huijie; Rao, Shivanesh; Wilkerson, Frances; Farrara, John; Zhang, Hongchun; Wang, Zhengui; Zhang, Yinglong 2018-06-01 An open source coupled physical-biogeochemical model is developed for San Francisco Bay (SFB) to study nutrient cycling and plankton dynamics as well as to assist ecosystem based management and risk assessment. The biogeochemical model in this study is based on the Carbon, Silicate and Nitrogen Ecosystem (CoSiNE) model, and coupled to the unstructured grid, Semi-Implicit Cross-scale Hydroscience Integrated System Model (SCHISM). The SCHISM-CoSiNE model reproduces the spatial and temporal variability in nutrients and plankton biomass, and its physical and biogeochemical performance is successfully tested using comparisons with shipboard and fixed station observations. The biogeochemical characteristics of the SFB during wet and dry years are investigated by changing the input of the major rivers. River discharges from the Sacramento and San Joaquin Rivers affect the phytoplankton biomass in North SFB through both advection and dilution of nutrient (including ammonium, NH4) concentrations in the river. The reduction in residence time caused by increased inflows can result in decreased biomass accumulation, while the corresponding reduction in NH4 concentration favors the growth of biomass. In addition, the model is used to make a series of sensitivity experiments to examine the response of SFB to changes in 1) nutrient loading from rivers and wastewater treatment plants (WWTPs), 2) a parameter (ψ) defining NH4 inhibition of nitrate (NO3) uptake by phytoplankton, 3) bottom grazing and 4) suspended sediment concentration. The model results show that changes in NH4 input from rivers or WWTPs affect the likelihood of phytoplankton blooms via NH4 inhibition and that the choice of ψ is critical. Bottom grazing simulated here as increased plankton mortality demonstrates the potential for bivalve reduction of chlorophyll biomass and the need to include bivalve grazing in future models. Furthermore, the model demonstrates the need to include sediments and their contribution to turbidity and availability of light. This biogeochemical model is suitable for other estuaries with similar ecological issues and anthropogenic stressors. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2002EGSGA..27.5316E','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2002EGSGA..27.5316E">Assimilation of Sea Color Data Into A Three Dimensional Biogeochemical Model: Sensitivity Experiments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Echevin, V.; Levy, M.; Memery, L. The assimilation of two dimensional sea color data fields into a 3 dimensional coupled dynamical-biogeochemical model is performed using a 4DVAR algorithm. The biogeochemical model includes description of nitrates, ammonium, phytoplancton, zooplancton, detritus and dissolved organic matter. A subset of the biogeochemical model poorly known parameters (for example,phytoplancton growth, mortality,grazing) are optimized by minimizing a cost function measuring misfit between the observations and the model trajectory. Twin experiments are performed with an eddy resolving model of 5 km resolution in an academic configuration. Starting from oligotrophic conditions, an initially unstable baroclinic anticyclone splits into several eddies. Strong vertical velocities advect nitrates into the euphotic zone and generate a phytoplancton bloom. Biogeochemical parameters are perturbed to generate surface pseudo-observations of chlorophyll,which are assimilated in the model in order to retrieve the correct parameter perturbations. The impact of the type of measurement (quasi-instantaneous, daily mean, weekly mean) onto the retrieved set of parameters is analysed. Impacts of additional subsurface measurements and of errors in the circulation are also presented. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1917930C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1917930C">SEAPODYM-LTL: a parsimonious zooplankton dynamic biomass model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Conchon, Anna; Lehodey, Patrick; Gehlen, Marion; Titaud, Olivier; Senina, Inna; Séférian, Roland 2017-04-01 Mesozooplankton organisms are of critical importance for the understanding of early life history of most fish stocks, as well as the nutrient cycles in the ocean. Ongoing climate change and the need for improved approaches to the management of living marine resources has driven recent advances in zooplankton modelling. The classical modeling approach tends to describe the whole biogeochemical and plankton cycle with increasing complexity. We propose here a different and parsimonious zooplankton dynamic biomass model (SEAPODYM-LTL) that is cost efficient and can be advantageously coupled with primary production estimated either from satellite derived ocean color data or biogeochemical models. In addition, the adjoint code of the model is developed allowing a robust optimization approach for estimating the few parameters of the model. In this study, we run the first optimization experiments using a global database of climatological zooplankton biomass data and we make a comparative analysis to assess the importance of resolution and primary production inputs on model fit to observations. We also compare SEAPODYM-LTL outputs to those produced by a more complex biogeochemical model (PISCES) but sharing the same physical forcings. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/17996980','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/17996980">One-dimensional model for biogeochemical interactions and permeability reduction in soils during leachate permeation.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Singhal, Naresh; Islam, Jahangir 2008-02-19 This paper uses the findings from a column study to develop a reactive model for exploring the interactions occurring in leachate-contaminated soils. The changes occurring in the concentrations of acetic acid, sulphate, suspended and attached biomass, Fe(II), Mn(II), calcium, carbonate ions, and pH in the column are assessed. The mathematical model considers geochemical equilibrium, kinetic biodegradation, precipitation-dissolution reactions, bacterial and substrate transport, and permeability reduction arising from bacterial growth and gas production. A two-step sequential operator splitting method is used to solve the coupled transport and biogeochemical reaction equations. The model gives satisfactory fits to experimental data and the simulations show that the transport of metals in soil is controlled by multiple competing biotic and abiotic reactions. These findings suggest that bioaccumulation and gas formation, compared to chemical precipitation, have a larger influence on hydraulic conductivity reduction. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li class="active">1</li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_2" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li class="active">2</li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="21"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20030001107&hterms=Sulfur&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3DSulfur','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20030001107&hterms=Sulfur&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3DSulfur">Biogeochemical Cycles of Carbon and Sulfur</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> DesMarais, David J.; DeVincenzi, D. (Technical Monitor) 2002-01-01 The elements carbon (C) and sulfur (S) interact with each other across a network of elemental reservoirs that are interconnected by an array of physical, chemical and biological processes. These networks are termed the biogeochemical C and S cycles. The compounds of C are highly important, not only as organic matter, but also as atmospheric greenhouse gases, pH buffers in seawater, oxidation-reduction buffers virtually everywhere, and key magmatic constituents affecting plutonism and volcanism. The element S assumes important roles as an oxidation-reduction partner with C and Fe in biological systems, as a key constituent in magmas and volcanic gases, and as a major influence upon pH in certain environments. This presentation describes the modern biogeochemical C and S cycles. Measurements are described whereby stable isotopes can help to infer the nature and quantitative significance of biological and geological processes involved in the C and S cycles. This lecture also summarizes the geological and climatologic aspects of the ancient C and S cycles, as well as the planetary and extraterrestrial processes that influenced their evolution over millions to billions of years. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007GBioC..21.1001T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007GBioC..21.1001T">Assimilation of seasonal chlorophyll and nutrient data into an adjoint three-dimensional ocean carbon cycle model: Sensitivity analysis and ecosystem parameter optimization</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tjiputra, Jerry F.; Polzin, Dierk; Winguth, Arne M. E. 2007-03-01 An adjoint method is applied to a three-dimensional global ocean biogeochemical cycle model to optimize the ecosystem parameters on the basis of SeaWiFS surface chlorophyll observation. We showed with identical twin experiments that the model simulated chlorophyll concentration is sensitive to perturbation of phytoplankton and zooplankton exudation, herbivore egestion as fecal pellets, zooplankton grazing, and the assimilation efficiency parameters. The assimilation of SeaWiFS chlorophyll data significantly improved the prediction of chlorophyll concentration, especially in the high-latitude regions. Experiments that considered regional variations of parameters yielded a high seasonal variance of ecosystem parameters in the high latitudes, but a low variance in the tropical regions. These experiments indicate that the adjoint model is, despite the many uncertainties, generally capable to optimize sensitive parameters and carbon fluxes in the euphotic zone. The best fit regional parameters predict a global net primary production of 36 Pg C yr-1, which lies within the range suggested by Antoine et al. (1996). Additional constraints of nutrient data from the World Ocean Atlas showed further reduction in the model-data misfit and that assimilation with extensive data sets is necessary. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1015902-model-based-analysis-role-biological-hydrological-geochemical-factors-affecting-uranium-bioremediation','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1015902-model-based-analysis-role-biological-hydrological-geochemical-factors-affecting-uranium-bioremediation">Model-Based Analysis of the Role of Biological, Hydrological and Geochemical Factors Affecting Uranium Bioremediation</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Zhao, Jiao; Scheibe, Timothy D.; Mahadevan, Radhakrishnan 2011-01-24 Uranium contamination is a serious concern at several sites motivating the development of novel treatment strategies such as the Geobacter-mediated reductive immobilization of uranium. However, this bioremediation strategy has not yet been optimized for the sustained uranium removal. While several reactive-transport models have been developed to represent Geobacter-mediated bioremediation of uranium, these models often lack the detailed quantitative description of the microbial process (e.g., biomass build-up in both groundwater and sediments, electron transport system, etc.) and the interaction between biogeochemical and hydrological process. In this study, a novel multi-scale model was developed by integrating our recent model on electron capacitancemore » of Geobacter (Zhao et al., 2010) with a comprehensive simulator of coupled fluid flow, hydrologic transport, heat transfer, and biogeochemical reactions. This mechanistic reactive-transport model accurately reproduces the experimental data for the bioremediation of uranium with acetate amendment. We subsequently performed global sensitivity analysis with the reactive-transport model in order to identify the main sources of prediction uncertainty caused by synergistic effects of biological, geochemical, and hydrological processes. The proposed approach successfully captured significant contributing factors across time and space, thereby improving the structure and parameterization of the comprehensive reactive-transport model. The global sensitivity analysis also provides a potentially useful tool to evaluate uranium bioremediation strategy. The simulations suggest that under difficult environments (e.g., highly contaminated with U(VI) at a high migration rate of solutes), the efficiency of uranium removal can be improved by adding Geobacter species to the contaminated site (bioaugmentation) in conjunction with the addition of electron donor (biostimulation). The simulations also highlight the interactive effect of initial cell concentration and flow rate on U(VI) reduction.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS43B2055Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS43B2055Y">Multimillennium changes in dissolved oxygen under global warming: results from an AOGCM and offline ocean biogeochemical model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yamamoto, A.; Abe-Ouchi, A.; Shigemitsu, M.; Oka, A.; Takahashi, K.; Ohgaito, R.; Yamanaka, Y. 2016-12-01 Long-term oceanic oxygen change due to global warming is still unclear; most future projections (such as CMIP5) are only performed until 2100. Indeed, few previous studies using conceptual models project oxygen change in the next thousands of years, showing persistent global oxygen reduction by about 30% in the next 2000 years, even after atmospheric carbon dioxide stops rising. Yet, these models cannot sufficiently represent the ocean circulation change: the key driver of oxygen change. Moreover, considering serious effect oxygen reduction has on marine life and biogeochemical cycling, long-term oxygen change should be projected for higher validity. Therefore, we used a coupled atmosphere-ocean general circulation model (AOGCM) and an offline ocean biogeochemical model, investigating realistic long-term changes in oceanic oxygen concentration and ocean circulation. We integrated these models for 2000 years under atmospheric CO2 doubling and quadrupling. After global oxygen reduction in the first 500 years, oxygen concentration in deep ocean globally recovers and overshoots, despite surface oxygen decrease and weaker Atlantic Meridional Overturning Circulation. Deep ocean convection in the Weddell Sea recovers and overshoots, after initial cessation. Thus, enhanced deep convection and associated Antarctic Bottom Water supply oxygen-rich surface waters to deep ocean, resulting global deep ocean oxygenation. We conclude that the change in ocean circulation in the Southern Ocean potentially drives millennial-scale oxygenation in the deep ocean; contrary to past reported long-term oxygen reduction and general expectation. In presentation, we will discuss the mechanism of response of deep ocean convection in the Weddell Sea and show the volume changes of hypoxic waters. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23734151','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23734151">Biogeochemical implications of the ubiquitous colonization of marine habitats and redox gradients by Marinobacter species.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Handley, Kim M; Lloyd, Jonathan R 2013-01-01 The Marinobacter genus comprises widespread marine bacteria, found in localities as diverse as the deep ocean, coastal seawater and sediment, hydrothermal settings, oceanic basalt, sea-ice, sand, solar salterns, and oil fields. Terrestrial sources include saline soil and wine-barrel-decalcification wastewater. The genus was designated in 1992 for the Gram-negative, hydrocarbon-degrading bacterium Marinobacter hydrocarbonoclasticus. Since then, a further 31 type strains have been designated. Nonetheless, the metabolic range of many Marinobacter species remains largely unexplored. Most species have been classified as aerobic heterotrophs, and assessed for limited anaerobic pathways (fermentation or nitrate reduction), whereas studies of low-temperature hydrothermal sediments, basalt at oceanic spreading centers, and phytoplankton have identified species that possess a respiratory repertoire with significant biogeochemical implications. Notable physiological traits include nitrate-dependent Fe(II)-oxidation, arsenic and fumarate redox cycling, and Mn(II) oxidation. There is also evidence for Fe(III) reduction, and metal(loid) detoxification. Considering the ubiquity and metabolic capabilities of the genus, Marinobacter species may perform an important and underestimated role in the biogeochemical cycling of organics and metals in varied marine habitats, and spanning aerobic-to-anoxic redox gradients. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3660661','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3660661">Biogeochemical implications of the ubiquitous colonization of marine habitats and redox gradients by Marinobacter species</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Handley, Kim M.; Lloyd, Jonathan R. 2013-01-01 The Marinobacter genus comprises widespread marine bacteria, found in localities as diverse as the deep ocean, coastal seawater and sediment, hydrothermal settings, oceanic basalt, sea-ice, sand, solar salterns, and oil fields. Terrestrial sources include saline soil and wine-barrel-decalcification wastewater. The genus was designated in 1992 for the Gram-negative, hydrocarbon-degrading bacterium Marinobacter hydrocarbonoclasticus. Since then, a further 31 type strains have been designated. Nonetheless, the metabolic range of many Marinobacter species remains largely unexplored. Most species have been classified as aerobic heterotrophs, and assessed for limited anaerobic pathways (fermentation or nitrate reduction), whereas studies of low-temperature hydrothermal sediments, basalt at oceanic spreading centers, and phytoplankton have identified species that possess a respiratory repertoire with significant biogeochemical implications. Notable physiological traits include nitrate-dependent Fe(II)-oxidation, arsenic and fumarate redox cycling, and Mn(II) oxidation. There is also evidence for Fe(III) reduction, and metal(loid) detoxification. Considering the ubiquity and metabolic capabilities of the genus, Marinobacter species may perform an important and underestimated role in the biogeochemical cycling of organics and metals in varied marine habitats, and spanning aerobic-to-anoxic redox gradients. PMID:23734151 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006JCHyd..88..119K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006JCHyd..88..119K">Field-scale demonstration of induced biogeochemical reductive dechlorination at Dover Air Force Base, Dover, Delaware</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kennedy, Lonnie G.; Everett, Jess W.; Becvar, Erica; DeFeo, Donald 2006-11-01 Biogeochemical reductive dechlorination (BiRD) is a new remediation approach for chlorinated aliphatic hydrocarbons (CAHs). The approach stimulates common sulfate-reducing soil bacteria, facilitating the geochemical conversion of native iron minerals into iron sulfides. Iron sulfides have the ability to chemically reduce many common CAH compounds including PCE, TCE, DCE, similar to zero valent iron (Fe 0). Results of a field test at Dover Air Force Base, Dover, Delaware, are given in this paper. BiRD was stimulated by direct injection of Epson salt (MgSO 4·7H 2O) and sodium (L) lactate (NaC 3H 5O 3) in five injection wells. Sediment was sampled before and 8 months after injection. Significant iron sulfide minerals developed in the sandy aquifer matrix. From ground water analyses, treatment began a few weeks after injection with up to 95% reduction in PCE, TCE, and cDCE in less than 1 year. More complete CAH treatment is likely at a larger scale than this demonstration. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=277845','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=277845">Modeling of the structure-specific kinetics of abiotic, dark reduction of Hg(II) complexed by O/N and S functional groups in humic acids while accounting for time-dependent structural rearrangement</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Redox transformations involving electron transfer from natural organic matter (NOM) are important for the mercury (Hg) biogeochemical cycle. In the water column light drives the reduction of Hg(II) to Hg(0), whereas in soils and sediments dark reduction of Hg(II) is of greater importance. The object... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27909425','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27909425">Thermodynamic and Kinetic Response of Microbial Reactions to High CO2.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jin, Qusheng; Kirk, Matthew F 2016-01-01 Geological carbon sequestration captures CO 2 from industrial sources and stores the CO 2 in subsurface reservoirs, a viable strategy for mitigating global climate change. In assessing the environmental impact of the strategy, a key question is how microbial reactions respond to the elevated CO 2 concentration. This study uses biogeochemical modeling to explore the influence of CO 2 on the thermodynamics and kinetics of common microbial reactions in subsurface environments, including syntrophic oxidation, iron reduction, sulfate reduction, and methanogenesis. The results show that increasing CO 2 levels decreases groundwater pH and modulates chemical speciation of weak acids in groundwater, which in turn affect microbial reactions in different ways and to different extents. Specifically, a thermodynamic analysis shows that increasing CO 2 partial pressure lowers the energy available from syntrophic oxidation and acetoclastic methanogenesis, but raises the available energy of microbial iron reduction, hydrogenotrophic sulfate reduction and methanogenesis. Kinetic modeling suggests that high CO 2 has the potential of inhibiting microbial sulfate reduction while promoting iron reduction. These results are consistent with the observations of previous laboratory and field studies, and highlight the complexity in microbiological responses to elevated CO 2 abundance, and the potential power of biogeochemical modeling in evaluating and quantifying these responses. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5112241','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5112241">Thermodynamic and Kinetic Response of Microbial Reactions to High CO2</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Jin, Qusheng; Kirk, Matthew F. 2016-01-01 Geological carbon sequestration captures CO2 from industrial sources and stores the CO2 in subsurface reservoirs, a viable strategy for mitigating global climate change. In assessing the environmental impact of the strategy, a key question is how microbial reactions respond to the elevated CO2 concentration. This study uses biogeochemical modeling to explore the influence of CO2 on the thermodynamics and kinetics of common microbial reactions in subsurface environments, including syntrophic oxidation, iron reduction, sulfate reduction, and methanogenesis. The results show that increasing CO2 levels decreases groundwater pH and modulates chemical speciation of weak acids in groundwater, which in turn affect microbial reactions in different ways and to different extents. Specifically, a thermodynamic analysis shows that increasing CO2 partial pressure lowers the energy available from syntrophic oxidation and acetoclastic methanogenesis, but raises the available energy of microbial iron reduction, hydrogenotrophic sulfate reduction and methanogenesis. Kinetic modeling suggests that high CO2 has the potential of inhibiting microbial sulfate reduction while promoting iron reduction. These results are consistent with the observations of previous laboratory and field studies, and highlight the complexity in microbiological responses to elevated CO2 abundance, and the potential power of biogeochemical modeling in evaluating and quantifying these responses. PMID:27909425 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=189410&keyword=PH+AND+test&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=189410&keyword=PH+AND+test&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Promising Emerging Mechanisms</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Most applications of enhanced in situ bioremediation are based on biological reductive dechlorination. Anaerobic metabolism can also produce reactive minerals that allow for in situ biogeochemical transformation of chlorinated organic contaminants such as PCE, TCE, and cis-DCE. ... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20040191782','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20040191782">Biogeochemical Cycles of Carbon and Sulfur on Early Earth (and on Mars?)</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> DesMarais, D. J. 2004-01-01 The physical and chemical interactions between the atmosphere, hydrosphere, geosphere and biosphere can be examined for elements such as carbon (C) and sulfur (S) that have played central roles for both life and the environment. The compounds of C are highly important, not only as organic matter, but also as atmospheric greenhouse gases, pH buffers in seawater, oxidation-reduction buffers virtually everywhere, and key magmatic constituents affecting plutonism and volcanism. S assumes important roles as an oxidation-reduction partner with C and Fe in biological systems, as a key constituent in magmas and volcanic gases, and as a major influence upon pH in certain environments. These multiple roles of C and S interact across a network of elemental reservoirs interconnected by physical, chemical and biological processes. These networks are termed biogeochemical C and S cycles. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1430450-multiscale-investigation-biofilm-distribution-its-impact-macroscopic-biogeochemical-reaction-rates-biofilm-distribution-rate-scaling','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1430450-multiscale-investigation-biofilm-distribution-its-impact-macroscopic-biogeochemical-reaction-rates-biofilm-distribution-rate-scaling">Multiscale Investigation on Biofilm Distribution and Its Impact on Macroscopic Biogeochemical Reaction Rates: BIOFILM DISTRIBUTION AND RATE SCALING</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Yan, Zhifeng; Liu, Chongxuan; Liu, Yuanyuan Biofilms are critical locations for biogeochemical reactions in the subsurface environment. The occurrence and distribution of biofilms at microscale as well as their impacts on macroscopic biogeochemical reaction rates are still poorly understood. This paper investigated the formation and distributions of biofilms in heterogeneous sediments using multiscale models, and evaluated the effects of biofilm heterogeneity on local and macroscopic biogeochemical reaction rates. Sediment pore structures derived from X-ray computed tomography were used to simulate the microscale flow dynamics and biofilm distribution in the sediment column. The response of biofilm formation and distribution to the variations in hydraulic and chemical propertiesmore » was first examined. One representative biofilm distribution was then utilized to evaluate its effects on macroscopic reaction rates using nitrate reduction as an example. The results revealed that microorganisms primarily grew on the surfaces of grains and aggregates near preferential flow paths where both electron donor and acceptor were readily accessible, leading to the heterogeneous distribution of biofilms in the sediments. The heterogeneous biofilm distribution decreased the macroscopic rate of biogeochemical reactions as compared with those in homogeneous cases. Operationally considering the heterogeneous biofilm distribution in macroscopic reactive transport models such as using dual porosity domain concept can significantly improve the prediction of biogeochemical reaction rates. Overall, this study provided important insights into the biofilm formation and distribution in soils and sediments as well as their impacts on the macroscopic manifestation of reaction rates.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017WRR....53.8698Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017WRR....53.8698Y">Multiscale Investigation on Biofilm Distribution and Its Impact on Macroscopic Biogeochemical Reaction Rates</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yan, Zhifeng; Liu, Chongxuan; Liu, Yuanyuan; Bailey, Vanessa L. 2017-11-01 Biofilms are critical locations for biogeochemical reactions in the subsurface environment. The occurrence and distribution of biofilms at microscale as well as their impacts on macroscopic biogeochemical reaction rates are still poorly understood. This paper investigated the formation and distributions of biofilms in heterogeneous sediments using multiscale models and evaluated the effects of biofilm heterogeneity on local and macroscopic biogeochemical reaction rates. Sediment pore structures derived from X-ray computed tomography were used to simulate the microscale flow dynamics and biofilm distribution in the sediment column. The response of biofilm formation and distribution to the variations in hydraulic and chemical properties was first examined. One representative biofilm distribution was then utilized to evaluate its effects on macroscopic reaction rates using nitrate reduction as an example. The results revealed that microorganisms primarily grew on the surfaces of grains and aggregates near preferential flow paths where both electron donor and acceptor were readily accessible, leading to the heterogeneous distribution of biofilms in the sediments. The heterogeneous biofilm distribution decreased the macroscopic rate of biogeochemical reactions as compared with those in homogeneous cases. Operationally considering the heterogeneous biofilm distribution in macroscopic reactive transport models such as using dual porosity domain concept can significantly improve the prediction of biogeochemical reaction rates. Overall, this study provided important insights into the biofilm formation and distribution in soils and sediments as well as their impacts on the macroscopic manifestation of reaction rates. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=84967&Lab=NERL&keyword=effects+AND+temperature+AND+oxygen+AND+consumption+AND+fish&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=84967&Lab=NERL&keyword=effects+AND+temperature+AND+oxygen+AND+consumption+AND+fish&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">BIOGEOCHEMICAL INDICATORS IN AQUATIC ECOSYSTEMS</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Loadings of excess organic wastes and associated nutrients to aquatic systems has numerous deleterious consequences with respect to the ecosystem services provided by these important ecosystems including perturbation of organic matter and nutrient cycling rates, reduction in diss... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeCoA.211..214P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeCoA.211..214P">Biogeochemical N signatures from rate-yield trade-offs during in vitro chemosynthetic NO3- reduction by deep-sea vent ε-Proteobacteria and Aquificae growing at different temperatures</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Pérez-Rodríguez, Ileana; Sievert, Stefan M.; Fogel, Marilyn L.; Foustoukos, Dionysis I. 2017-08-01 NO3- reduction is a metabolism that is widespread among ε-Proteobacteria and Aquificae, two abundant classes of microorganisms found at deep-sea vents. In this study, we used Sulfurovum lithotrophicum, Caminibacter mediatlanticus and Thermovibrio ammonificans as representatives of these groups to study ecophysiological, metabolic and biogeochemical parameters associated with chemolithoautotrophic NO3- reduction under different temperature regimes. We observed that while S. lithotrophicum and C. mediatlanticus achieved higher cell densities than T. ammonificans, the overall NO3- consumption by the latter was on average ∼9 and ∼5 times faster on a per cell basis, respectively. Comparison with previously published data from other cultured vent ε-Proteobacteria and Aquificae suggests that the rate-yield trade-offs observed in our experiments are generally conserved between these two groups in line with their ecophysiologies. Kinetic isotope effects of N from NO3- reduction were 9.6 ± 2.7‰ for S. lithotrophicum, 6.4 ± 0.7‰ for C. mediatlanticus and 8.8 ± 0.6‰ for T. ammonificans. Our results help evaluate how metabolic partitioning between growth efficiency and reaction kinetics during chemolithoautotrophic NO3- reduction affect the concentration and isotope composition of N compounds at deep-sea hydrothermal vents. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70018740','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70018740">Fate of microbial metabolites of hydrocarbons in a coastal plain aquifer: The role of electron acceptors</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Cozzarelli, I.M.; Herman, J.S.; Baedecker, M. Jo 1995-01-01 A combined field and laboratory study was undertaken to understand the distribution and geochemical conditions that influence the prevalence of low molecular weight organic acids in groundwater of a shallow aquifer contaminated with gasoline. Aromatic hydrocarbons from gasoline were degraded by microbially mediated oxidation-reduction reactions, including reduction of nitrate, sulfate, and Fe(III). The biogeochemical reactions changed overtime in response to changes in the hydrogeochemical conditions in the aquifer. Aliphatic and aromatic organic acids were associated with hydrocarbon degradation in anoxic zones of the aquifer. Laboratory microcosms demonstrated that the biogeochemical fate of specific organic acids observed in groundwater varied with the structure of the acid and the availability of electron acceptors. Benzoic and phenylacetic acid were degraded by indigenous aquifer microorganisms when nitrate was supplied as an electron acceptor. Aromatic acids with two or more methyl substituants on the benzene ring persisted under nitrate-reducing conditions. Although iron reduction and sulfate reduction were important processes in situ and occurred in the microcosms, these reactions were not coupled to the biological oxidation of aromatic organic acids that were added to the microcosms as electron donors. ?? 1995 American Chemical Society. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=202968&Lab=NRMRL&keyword=bioremediation&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=202968&Lab=NRMRL&keyword=bioremediation&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Contributions of Fe Minerals to Abiotic Dechlorination</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Most applications of enhanced in situ bioremediation are based on biological reductive dechlorination. Anaerobic metabolism can also produce reactive minerals that allow for in situ biogeochemical transformation of chlorinated organic contaminants such as PCE, TCE, and cis-DCE. ... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.4605M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.4605M">Plant Nitrogen Uptake in Terrestrial Biogeochemical Models</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marti, Alejandro; Cox, Peter; Sitch, Stephen; Jones, Chris; Liddicoat, spencer 2013-04-01 Most terrestrial biogeochemical models featured in the last Intergovernmental Panel on Climate Change (IPPC) Assessment Report highlight the importance of the terrestrial Carbon sequestration and feedbacks between the terrestrial Carbon cycle and the climate system. However, these models have been criticized for overestimating predicted Carbon sequestration and its potential climate feedback when calculating the rate of future climate change because they do not account for the Carbon sequestration constraints caused by nutrient limitation, particularly Nitrogen (N). This is particularly relevant considering the existence of a substantial deficit of Nitrogen for plants in most areas of the world. To date, most climate models assume that plants have access to as much Nitrogen as needed, but ignore the nutrient requirements for new vegetation growth. Determining the natural demand and acquisition for Nitrogen and its associated resource optimization is key when accounting for the Carbon sequestration constrains caused by nutrient limitation. The few climate models that include C-N dynamics have illustrated that the stimulation of plant growth over the coming century may be two to three times smaller than previously predicted. This reduction in growth is partially offset by an increase in the availability of nutrients resulting from an accelerated rate of decomposition of dead plants and other organic matter that occurring with a rise in temperature. However, this offset does not counterbalance the reduced level of plant growth calculated by natural nutrient limitations. Additionally, Nitrogen limitation is also expected to become more pronounced in some ecosystems as atmospheric CO2 concentration increases; resulting in less new growth and higher atmospheric CO2 concentrations than originally expected. This study compares alternative models of plant N uptake as found in different terrestrial biogeochemical models against field measurements, and introduces a new N-uptake model to the Joint UK Land Environment Simulator (JULES).. Acknowledgements This work has been funded by the European Commission FP7-PEOPLE-ITN-2008 Marie Curie Action: "Greencycles II: FP7-PEOPLE-ITN-2008 Marie Curie Action: "Networks for Initial Training" </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B14A..01S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B14A..01S">Microbial Selenite Reduction and the Selenium Biogeochemical Cycle</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Stolz, J. F.; Wells, M. 2016-12-01 Selenium is an essential trace element utilized by many species in the three domains of life. In most Bacteria and Archaea, selenium is primarily assimilated to form selenocysteine, the 21st amino acid (Sec). Additionally selenium can be methylated, demethylated, or used as a terminal electron acceptor in dissimilatory selenate or selenite reduction. Although progress has been made on elucidating the synthesis of selenoproteins, less is known of their occurrence, diversity, and functionality, primarily due to poor genome annotation (e.g., failure to recognize UGA as a Sec and not a stop codon) and proteomics analysis (e.g., failure to detect Sec in LC/MS-MS). Furthermore important parts of the selenium biogeochemical cycle remain to be fully explored, in particular the reduction of Se(IV) to Se(O). We have examined the selenoproteome of a selenate respiring bacterium Sulfurospirillum barnesii strain SES-3, which reduces Se(VI) to Se(0) and the dissimilatory selenite reducing bacterium, Bacillus selenitireducens, strain MLS-10, which reduces Se(IV) to Se(0). Candidate selenoproteins including D-proline reductase, formate dehydrogenase, and methionine-S sulfoxide reductase have been identified in the genomes. A putative dissimilatory selenate reducase (Ser) was found in the genome of S. barnesii. More significant was the discovery of a candidate for the respiratory selenite reductase in B. selenitireducens as determined by in gel assays and LC/MS-MS. The latter has provided a hint at the potential diversity of DSiR bacteria and the development of molecular probes for investigating DSiR in the selenium biogeochemical cycle. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li class="active">2</li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_3" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li class="active">3</li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="41"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=199056&Lab=NRMRL&keyword=permanganate&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=199056&Lab=NRMRL&keyword=permanganate&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Biogeochemical Barriers: Redox Behavior of Metals and Metalloids</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Redox conditions and pH are arguably the most important geochemical parameters that control contaminant transport and fate in groundwater systems. Oxidation-reduction (redox) reactions mediate the chemical behavior of both inorganic and organic chemical constituents by affecting... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24673287','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24673287">The genetic potential for key biogeochemical processes in Arctic frost flowers and young sea ice revealed by metagenomic analysis.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Bowman, Jeff S; Berthiaume, Chris T; Armbrust, E Virginia; Deming, Jody W 2014-08-01 Newly formed sea ice is a vast and biogeochemically active environment. Recently, we reported an unusual microbial community dominated by members of the Rhizobiales in frost flowers at the surface of Arctic young sea ice based on the presence of 16S gene sequences related to these strains. Here, we use metagenomic analysis of two samples, from a field of frost flowers and the underlying young sea ice, to explore the metabolic potential of this surface ice community. The analysis links genes for key biogeochemical processes to the Rhizobiales, including dimethylsulfide uptake, betaine glycine turnover, and halocarbon production. Nodulation and nitrogen fixation genes characteristic of terrestrial root-nodulating Rhizobiales were generally lacking from these metagenomes. Non-Rhizobiales clades at the ice surface had genes that would enable additional biogeochemical processes, including mercury reduction and dimethylsulfoniopropionate catabolism. Although the ultimate source of the observed microbial community is not known, considerations of the possible role of eolian deposition or transport with particles entrained during ice formation favor a suspended particle source for this microbial community. © 2014 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4524164','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4524164">The Impact of Gamma Radiation on Sediment Microbial Processes</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Brown, Ashley R.; Boothman, Christopher; Pimblott, Simon M. 2015-01-01 Microbial communities have the potential to control the biogeochemical fate of some radionuclides in contaminated land scenarios or in the vicinity of a geological repository for radioactive waste. However, there have been few studies of ionizing radiation effects on microbial communities in sediment systems. Here, acetate and lactate amended sediment microcosms irradiated with gamma radiation at 0.5 or 30 Gy h−1 for 8 weeks all displayed NO3− and Fe(III) reduction, although the rate of Fe(III) reduction was decreased in 30-Gy h−1 treatments. These systems were dominated by fermentation processes. Pyrosequencing indicated that the 30-Gy h−1 treatment resulted in a community dominated by two Clostridial species. In systems containing no added electron donor, irradiation at either dose rate did not restrict NO3−, Fe(III), or SO42− reduction. Rather, Fe(III) reduction was stimulated in the 0.5-Gy h−1-treated systems. In irradiated systems, there was a relative increase in the proportion of bacteria capable of Fe(III) reduction, with Geothrix fermentans and Geobacter sp. identified in the 0.5-Gy h−1 and 30-Gy h−1 treatments, respectively. These results indicate that biogeochemical processes will likely not be restricted by dose rates in such environments, and electron accepting processes may even be stimulated by radiation. PMID:25841009 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28238364','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28238364">Design and performance of subgrade biogeochemical reactors.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Gamlin, Jeff; Downey, Doug; Shearer, Brad; Favara, Paul 2017-12-15 Subgrade biogeochemical reactors (SBGRs), also commonly referred to as in situ bioreactors, are a unique technology for treatment of contaminant source areas and groundwater plume hot spots. SBGRs have most commonly been configured for enhanced reductive dechlorination (ERD) applications for chlorinated solvent treatment. However, they have also been designed for other contaminant classes using alternative treatment media. The SBGR technology typically consists of removal of contaminated soil via excavation or large-diameter augers, and backfill of the soil void with gravel and treatment amendments tailored to the target contaminant(s). In most cases SBGRs include installation of infiltration piping and a low-flow pumping system (typically solar-powered) to recirculate contaminated groundwater through the SBGR for treatment. SBGRs have been constructed in multiple configurations, including designs capable of meeting limited access restrictions at heavily industrialized sites, and at sites with restrictions on surface disturbance due to sensitive species or habitat issues. Typical performance results for ERD applications include 85 to 90 percent total molar reduction of chlorinated volatile organic compounds (CVOCs) near the SBGR and rapid clean-up of adjacent dissolved contaminant source areas. Based on a review of the literature and CH2M's field-scale results from over a dozen SBGRs with a least one year of performance data, important site-specific design considerations include: 1) hydraulic residence time should be long enough for sufficient treatment but not too long to create depressed pH and stagnant conditions (e.g., typically between 10 and 60 days), 2) reactor material should balance appropriate organic mulch as optimal bacterial growth media along with other organic additives that provide bioavailable organic carbon, 3) a variety of native bacteria are important to the treatment process, and 4) biologically mediated generation of iron sulfides along with addition of iron pyrite sands as an abiotic polishing step within the reactor has been observed to be an efficient treatment train for chlorinated solvent sites. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGeo...12.5567D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGeo...12.5567D">The biogeochemical structuring role of horizontal stirring: Lagrangian perspectives on iron delivery downstream of the Kerguelen Plateau</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> d'Ovidio, F.; Della Penna, A.; Trull, T. W.; Nencioli, F.; Pujol, M.-I.; Rio, M.-H.; Park, Y.-H.; Cotté, C.; Zhou, M.; Blain, S. 2015-10-01 Field campaigns are instrumental in providing ground truth for understanding and modeling global ocean biogeochemical budgets. A survey however can only inspect a fraction of the global oceans, typically a region hundreds of kilometers wide for a temporal window of the order of (at most) several weeks. This spatiotemporal domain is also the one in which the mesoscale activity induces through horizontal stirring a strong variability in the biogeochemical tracers, with ephemeral, local contrasts which can easily mask the regional and seasonal gradients. Therefore, whenever local in situ measures are used to infer larger-scale budgets, one faces the challenge of identifying the mesoscale structuring effect, if not simply to filter it out. In the case of the KEOPS2 investigation of biogeochemical responses to natural iron fertilization, this problem was tackled by designing an adaptive sampling strategy based on regionally optimized multisatellite products analyzed in real time by specifically designed Lagrangian diagnostics. This strategy identified the different mesoscale and stirring structures present in the region and tracked the dynamical frontiers among them. It also enabled back trajectories for the ship-sampled stations to be estimated, providing important insights into the timing and pathways of iron supply, which were explored further using a model based on first-order iron removal. This context was essential for the interpretation of the field results. The mesoscale circulation-based strategy was also validated post-cruise by comparing the Lagrangian maps derived from satellites with the patterns of more than one hundred drifters, including some adaptively released during KEOPS2 and a subsequent research voyage. The KEOPS2 strategy was adapted to the specific biogeochemical characteristics of the region, but its principles are general and will be useful for future in situ biogeochemical surveys. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015BGD....12..779D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015BGD....12..779D">The biogeochemical structuring role of horizontal stirring: Lagrangian perspectives on iron delivery downstream of the Kerguelen plateau</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> d'Ovidio, F.; Della Penna, A.; Trull, T. W.; Nencioli, F.; Pujol, I.; Rio, M. H.; Park, Y.-H.; Cotté, C.; Zhou, M.; Blain, S. 2015-01-01 Field campaigns are instrumental in providing ground truth for understanding and modelling global ocean biogeochemical budgets. A survey however can only inspect a fraction of the global oceans, typically a region 100s km wide for a temporal window of the order of (at most) several weeks. This spatiotemporal domain is also the one in which the mesoscale activity induces through horizontal stirring a strong variability in the biogeochemical tracers, with ephemeral, local contrasts which can easily mask the regional and seasonal gradients. Therefore, whenever local in-situ measures are used to infer larger scale budgets one faces the challenge of identifying the mesoscale structuring effect, if not simply to filter it out. In the case of the KEOPS2 investigation of biogeochemical responses to natural iron fertilization, this problem was tackled by designing an adaptive sampling strategy based on regionally-optimized multisatellite products analyzed in real time by specifically designed Lagrangian diagnostics. This strategy identified the different mesoscale and stirring structures present in the region and tracked the dynamical frontiers among them. It also enabled back-trajectories for the ship sampled stations to be estimated, providing important insights into the timing and pathways of iron supply, which were explored further using model based on first order iron removal. This context was essential for the interpretation of the field results. The mesoscale circulation based strategy was also validated post-cruise by comparing the Lagrangian maps derived from satellite with the patterns of more than one hundred drifters adaptively released during KEOPS2 and a subsequent research voyage. The KEOPS2 strategy was adapted to the specific biogeochemical characteristics of the region, but its principles are general and will be useful for future in-situ biogeochemical surveys. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=158258&keyword=processes+AND+waste+AND+solid&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=158258&keyword=processes+AND+waste+AND+solid&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">MINERALOGICAL PRESERVATION OF SOLID SAMPLES COLLECTED FROM ANOXIC SUBSURFACE ENVIRONMENTS</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Remedial technologies utilized at hazardous waste sites for the treatment of metal and metalloid contaminants often take advantage of reduction-oxidation (redox) processes to reach ground water clean up goals. This is because redox reactions, in many cases, govern the biogeochem... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B34B..03Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B34B..03Y">Biogeochemical stability and reactions of iron-organic carbon complexes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yang, Y.; Adhikari, D.; Zhao, Q.; Dunham-Cheatham, S.; Das, K.; Mejia, J.; Huang, R.; Wang, X.; Poulson, S.; Tang, Y.; Obrist, D.; Roden, E. E. 2017-12-01 Our core hypothesis is that the degradation rate of soil organic carbon (OC) is governed by the amount of iron (Fe)-bound OC, and the ability of microbial communities to utilize OC as an energy source and electron shuttle for Fe reduction that in turn stimulates reductive release of Fe-bound labile dissolved OC. This hypothesis is being systematically evaluated using model Fe-OC complexes, natural soils, and microcosm system. We found that hematite-bound aliphatic C was more resistant to reduction release, although hematite preferred to sorb more aromatic C. Resistance to reductive release represents a new mechanism that aliphatic soil OC was stabilized by association with Fe oxide. In other studies, pyrogenic OC was found to facilitate the reduction of hematite, by enhancing extracellular electron transport and sorbing Fe(II). For ferrihydrite-OC co-precipitates, the reduction of Fe and release of OC was closely governed by the C/Fe ratio in the system. Based on the XPS, XANES and XAFS analysis, the transformation of Fe speciation was heterogeneous, depending on the conformation and composition of Fe-OC complexes. For natural soils, we investigated the quantity, characteristics, and reactivity of Fe-bound OC in soils collected from 14 forests in the United States. Fe-bound OC contributed up to 57.8% of total OC in the forest soils. Under the anaerobic conditions, the reduction of Fe was positively correlated to the electron accepting capacity of OC. Our findings highlight the closely coupled dynamics of Fe and OC, with broad implications on the turnover of OC and biogeochemical cycles of Fe. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.C54A..05M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.C54A..05M">Microbial Energetics Beneath the Taylor Glacier, Antarctica</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Mikucki, J. A.; Turchyn, A. V.; Farquhar, J.; Priscu, J. C.; Schrag, D. P.; Pearson, A. 2007-12-01 Subglacial microbiology is controlled by glacier hydrology, bedrock lithology, and the preglacial ecosystem. These factors can all affect metabolic function by influencing electron acceptor and donor availability in the subglacial setting leaving biogeochemical signatures that can be used to determine ecosystem processes. Blood Falls, an iron-rich, episodic subglacial outflow from the Taylor Glacier in the McMurdo Dry Valleys Antarctica provides an example of how microbial community structure and function can provide insight into subglacial hydrology. This subglacial outflow contains cryoconcentrated, Pliocene-age seawater salts that pooled in the upper Taylor Valley and was subsequently covered by the advance of the Taylor Glacier. Biogeochemical measurements, culture-based techniques, and genomic analysis were used to characterize microbes and chemistry associated with the subglacial outflow. The isotopic composition of important geochemical substrates (i.e., δ34Ssulfate, Δ33Ssulfate, δ18Osulfate, δ18Owater, Δ14SDIC) were also measured to provide more detail on subglacial microbial energetics. Typically, subglacial systems, when driven to anoxia by the hydrolysis of organic matter, will follow a continuum of redox chemistries utilizing electron acceptors with decreasing reduction potential (e.g., Fe (III), sulfate, CO2). Our data provide no evidence for sulfate reduction below the Taylor Glacier despite high dissolved organic carbon (450 μM C) and measurable metabolic activity. We contend that, in the case of the Taylor Glacier, the in situ bioenergetic reduction potential has been 'short-circuited' at Fe(III)-reduction and excludes sulfate reduction and methanogenesis. Given the length of time that this marine system has been isolated from phototrophic production (~2 Mya) the ability to degrade and consume increasingly recalcitrant organic carbon is likely an important component to the observed redox chemistry. Our work indicates that glacier hydrology imparts strong feedbacks on the availability of oxygen as an electron acceptor and may be a robust regulator of the in situ metabolism. This biogeochemical regulation in turn affects the chemical nature of subglacial efflux. Blood Falls demonstrates that measurements of geochemistry and microbial diversity can support models of subglacial hydrology. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015GeoRL..42.6014L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015GeoRL..42.6014L">Dust fluxes and iron fertilization in Holocene and Last Glacial Maximum climates</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lambert, Fabrice; Tagliabue, Alessandro; Shaffer, Gary; Lamy, Frank; Winckler, Gisela; Farias, Laura; Gallardo, Laura; De Pol-Holz, Ricardo 2015-07-01 Mineral dust aerosols play a major role in present and past climates. To date, we rely on climate models for estimates of dust fluxes to calculate the impact of airborne micronutrients on biogeochemical cycles. Here we provide a new global dust flux data set for Holocene and Last Glacial Maximum (LGM) conditions based on observational data. A comparison with dust flux simulations highlights regional differences between observations and models. By forcing a biogeochemical model with our new data set and using this model's results to guide a millennial-scale Earth System Model simulation, we calculate the impact of enhanced glacial oceanic iron deposition on the LGM-Holocene carbon cycle. On centennial timescales, the higher LGM dust deposition results in a weak reduction of <10 ppm in atmospheric CO2 due to enhanced efficiency of the biological pump. This is followed by a further ~10 ppm reduction over millennial timescales due to greater carbon burial and carbonate compensation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70023088','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70023088">Further biogeochemical characterization of a trichloroethene-contaminated fractured dolomite aquifer: Electron source and microbial communities involved in reductive dechlorination</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Hohnstock-Ashe, A. M.; Plummer, S.M.; Yager, R.M.; Baveye, P.; Madsen, E.L. 2001-01-01 A recent article presented geochemical and microbial evidence establishing metabolic adaptation to and in-situ reductive dechlorination of trichloroethene (TCE) in a fractured dolomite aquifer. This study was designed to further explore site conditions and microbial populations and to explain previously reported enhancement of reductive dechlorination by the addition of pulverized dolomite to laboratory microcosms. A survey of groundwater geochemical parameters (chlorinated ethenes, ethene, H2, CH4, DIC, DOC, and ??13C values for CH4, DIC, and DOC) indicated that in situ reductive dechlorination was ongoing and that an unidentified pool of organic carbon was contributing, likely via microbial respiration, to the large and relatively light onsite DIC pool. Petroleum hydrocarbons associated with the dolomite rock were analyzed by GC/MS and featured a characteristically low ??13C value. Straight chain hydrocarbons were extracted from the dolomite previously found to stimulate reductive dechlorination; these were particularly depleted in hexadecane (HD). Thus, we hypothesized that HD and related hydrocarbons might be anaerobically respired and serve both as the source of onsite DIC and support reductive dechlorination of TCE. Microcosms amended with pulverized dolomite demonstrated reductive dechlorination, whereas a combusted dolomite amendment did not. HD-amended microcosms were also inactive. Therefore, the stimulatory factor in the pulverized dolomite was heat labile, but that component was not HD. Amplified Ribosomal DNA Restriction Analysis (ARDRA) of the microbial populations in well waters indicated that a relatively low diversity, sulfur-transforming community outside the plume was shifted toward a high diversity community including Dehalococcoides ethenogenes-type microorganisms inside the zone of contamination. These observations illustrate biogeochemical intricacies of in situ reductive dechlorination reactions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011JARS....5a3516I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011JARS....5a3516I">Calibration of a biome-biogeochemical cycles model for modeling the net primary production of teak forests through inverse modeling of remotely sensed data</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Imvitthaya, Chomchid; Honda, Kiyoshi; Lertlum, Surat; Tangtham, Nipon 2011-01-01 In this paper, we present the results of a net primary production (NPP) modeling of teak (Tectona grandis Lin F.), an important species in tropical deciduous forests. The biome-biogeochemical cycles or Biome-BGC model was calibrated to estimate net NPP through the inverse modeling approach. A genetic algorithm (GA) was linked with Biome-BGC to determine the optimal ecophysiological model parameters. The Biome-BGC was calibrated by adjusting the ecophysiological model parameters to fit the simulated LAI to the satellite LAI (SPOT-Vegetation), and the best fitness confirmed the high accuracy of generated ecophysioligical parameter from GA. The modeled NPP, using optimized parameters from GA as input data, was evaluated using daily NPP derived by the MODIS satellite and the annual field data in northern Thailand. The results showed that NPP obtained using the optimized ecophysiological parameters were more accurate than those obtained using default literature parameterization. This improvement occurred mainly because the model's optimized parameters reduced the bias by reducing systematic underestimation in the model. These Biome-BGC results can be effectively applied in teak forests in tropical areas. The study proposes a more effective method of using GA to determine ecophysiological parameters at the site level and represents a first step toward the analysis of the carbon budget of teak plantations at the regional scale. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=107117&keyword=Population+AND+numbers&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=107117&keyword=Population+AND+numbers&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">MOLECULAR PHYLOGENETIC AND BIOGEOCHEMICAL STUDIES OF SULFATE-REDUCING BACTERIA IN THE RHIZOSPHERE OF SPARTINA ALTERNIFLORA</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> The population composition and biogeochemistry of sulfate-reducing bacteria (SRB) in the rhizosphere of the marsh grass Spartina alterniflora was investigated over two growing seasons using molecular probing, enumerations of culturable SRB, and measurements of SO42- reduction rat... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2004AGUFMOS51A1287T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2004AGUFMOS51A1287T">Analysis of Seasonal Chlorophyll-a Using An Adjoint Three-Dimensional Ocean Carbon Cycle Model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tjiputra, J.; Winguth, A.; Polzin, D. 2004-12-01 The misfit between numerical ocean model and observations can be reduced using data assimilation. This can be achieved by optimizing the model parameter values using adjoint model. The adjoint model minimizes the model-data misfit by estimating the sensitivity or gradient of the cost function with respect to initial condition, boundary condition, or parameters. The adjoint technique was used to assimilate seasonal chlorophyll-a data from the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) satellite to a marine biogeochemical model HAMOCC5.1. An Identical Twin Experiment (ITE) was conducted to test the robustness of the model and the non-linearity level of the forward model. The ITE experiment successfully recovered most of the perturbed parameter to their initial values, and identified the most sensitive ecosystem parameters, which contribute significantly to model-data bias. The regional assimilations of SeaWiFS chlorophyll-a data into the model were able to reduce the model-data misfit (i.e. the cost function) significantly. The cost function reduction mostly occurred in the high latitudes (e.g. the model-data misfit in the northern region during summer season was reduced by 54%). On the other hand, the equatorial regions appear to be relatively stable with no strong reduction in cost function. The optimized parameter set is used to forecast the carbon fluxes between marine ecosystem compartments (e.g. Phytoplankton, Zooplankton, Nutrients, Particulate Organic Carbon, and Dissolved Organic Carbon). The a posteriori model run using the regional best-fit parameterization yields approximately 36 PgC/yr of global net primary productions in the euphotic zone. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014OcMod..81...25L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014OcMod..81...25L">Assessing the utility of frequency dependent nudging for reducing biases in biogeochemical models</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lagman, Karl B.; Fennel, Katja; Thompson, Keith R.; Bianucci, Laura 2014-09-01 Bias errors, resulting from inaccurate boundary and forcing conditions, incorrect model parameterization, etc. are a common problem in environmental models including biogeochemical ocean models. While it is important to correct bias errors wherever possible, it is unlikely that any environmental model will ever be entirely free of such errors. Hence, methods for bias reduction are necessary. A widely used technique for online bias reduction is nudging, where simulated fields are continuously forced toward observations or a climatology. Nudging is robust and easy to implement, but suppresses high-frequency variability and introduces artificial phase shifts. As a solution to this problem Thompson et al. (2006) introduced frequency dependent nudging where nudging occurs only in prescribed frequency bands, typically centered on the mean and the annual cycle. They showed this method to be effective for eddy resolving ocean circulation models. Here we add a stability term to the previous form of frequency dependent nudging which makes the method more robust for non-linear biological models. Then we assess the utility of frequency dependent nudging for biological models by first applying the method to a simple predator-prey model and then to a 1D ocean biogeochemical model. In both cases we only nudge in two frequency bands centered on the mean and the annual cycle, and then assess how well the variability in higher frequency bands is recovered. We evaluate the effectiveness of frequency dependent nudging in comparison to conventional nudging and find significant improvements with the former. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=238358&keyword=export&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=238358&keyword=export&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Riparian forest effects on nitrogen export to an agricultural stream inferred from experimental data and a model</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> The effects of riparian vegetation on the reduction of agricultural nitrogen export to streams have been well described experimentally, but a clear understanding of process-level hydrological and biogeochemical controls can be difficult to ascertain from data alone. We apply a ne... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=335570','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=335570">Naturally occurring soil salinity does not reduce N-transforming enzymes or organisms</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Soil salinity can negatively affect plant production and important biogeochemical cycles which are mainly carried out by soil microbes. The objective of this study was to contribute new information on soil biological N transformations by examining the impact primary salinity reduction has on a) the ... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.H41D0928A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.H41D0928A">Quantifying Linkages between Biogeochemical Processes in a Contaminated Aquifer-Wetland System Using Multivariate Statistics and HP1</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Arora, B.; Mohanty, B. P.; McGuire, J. T. 2009-12-01 Fate and transport of contaminants in saturated and unsaturated zones in the subsurface is controlled by complex biogeochemical processes such as precipitation, sorption-desorption, ion-exchange, redox, etc. In dynamic systems such as wetlands and anaerobic aquifers, these processes are coupled and can interact non-linearly with each other. Variability in measured hydrological, geochemical and microbiological parameters thus corresponds to multiple processes simultaneously. To infer the contributing processes, it is important to eliminate correlations and to identify inter-linkages between factors. The objective of this study is to develop quantitative relationships between hydrological (initial and boundary conditions, hydraulic conductivity ratio, and soil layering), geochemical (mineralogy, surface area, redox potential, and organic matter) and microbiological factors (MPN) that alter the biogeochemical processes at the column scale. Data used in this study were collected from controlled flow experiments in: i) two homogeneous soil columns, ii) a layered soil column, iii) a soil column with embedded clay lenses, and iv) a soil column with embedded clay lenses and one central macropore. The soil columns represent increasing level of soil structural heterogeneity to better mimic the Norman Landfill research site. The Norman Landfill is a closed municipal facility with prevalent organic contamination. The sources of variation in the dataset were explored using multivariate statistical techniques and dominant biogeochemical processes were obtained using principal component analysis (PCA). Furthermore, artificial neural networks (ANN) coupled with HP1 was used to develop mathematical rules identifying different combinations of factors that trigger, sustain, accelerate/decelerate, or discontinue the biogeochemical processes. Experimental observations show that infiltrating water triggers biogeochemical processes in all soil columns. Similarly, slow release of water from low permeability clay lenses sustain biogeochemical cycling for a longer period of time than in homogeneous soil columns. Preliminary results indicate: i) certain variables (anion, cation concentrations, etc.) do not follow normal or lognormal distributions even at the column scale, ii) strong correlations exist between parameters related to redox geochemistry (pH with S2- concentrations), and iii) PCA can identify dominant processes (e.g. iron and sulfate reduction) occurring in the system by grouping together causative variables (e.g. dominant TEAPs). </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B21E0526S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B21E0526S">Mycorrhizal Controls on Nitrogen Uptake Drive Carbon Cycling at the Global Scale</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Shi, M.; Fisher, J. B.; Brzostek, E. R.; Phillips, R. 2015-12-01 Nearly all plants form symbiotic relationships with one of two types of mycorrhizal fungi—arbuscular mycorrhizae (AM) and ectomycorrhizal (ECM) fungi, which are essential to global biogeochemical cycling of nutrient elements. In soils with higher rates of nitrogen and phosphorus mineralization from organic matter, AM-associated plants can be better adapted than ECM-associated plants. Importantly, the photosynthate costs of nutrient uptake for AM-associated plants are usually lower than that for ECM-associated plants. Thus, the global carbon cycle is closely coupled with mycorrhizal controls on N uptake. To investigate the potential climate dependence of terrestrial environments from AM- and ECM-associated plants, this study uses the Community Atmosphere Model (CAM) with a plant productivity-optimized N acquisition model—the Fixation and Uptake of Nitrogen (FUN) model—integrated into its land model—the Community Land Model (CLM). This latest version of CLM coupled with FUN allows for the assessment of mycorrhizal controls on global biogeochemical cycling. Here, we show how the historical evolution of AM- and ECM-associations altered regional and global biogeochemical cycling and climate, and future projections over the next century. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013NatCC...3..979T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013NatCC...3..979T">The impact of temperature on marine phytoplankton resource allocation and metabolism</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Toseland, A.; Daines, S. J.; Clark, J. R.; Kirkham, A.; Strauss, J.; Uhlig, C.; Lenton, T. M.; Valentin, K.; Pearson, G. A.; Moulton, V.; Mock, T. 2013-11-01 Marine phytoplankton are responsible for ~50% of the CO2 that is fixed annually worldwide, and contribute massively to other biogeochemical cycles in the oceans. Their contribution depends significantly on the interplay between dynamic environmental conditions and the metabolic responses that underpin resource allocation and hence biogeochemical cycling in the oceans. However, these complex environment-biome interactions have not been studied on a larger scale. Here we use a set of integrative approaches that combine metatranscriptomes, biochemical data, cellular physiology and emergent phytoplankton growth strategies in a global ecosystems model, to show that temperature significantly affects eukaryotic phytoplankton metabolism with consequences for biogeochemical cycling under global warming. In particular, the rate of protein synthesis strongly increases under high temperatures even though the numbers of ribosomes and their associated rRNAs decreases. Thus, at higher temperatures, eukaryotic phytoplankton seem to require a lower density of ribosomes to produce the required amounts of cellular protein. The reduction of phosphate-rich ribosomes in warmer oceans will tend to produce higher organismal nitrogen (N) to phosphate (P) ratios, in turn increasing demand for N with consequences for the marine carbon cycle due to shifts towards N-limitation. Our integrative approach suggests that temperature plays a previously unrecognized, critical role in resource allocation and marine phytoplankton stoichiometry, with implications for the biogeochemical cycles that they drive. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_1");'>1</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li class="active">3</li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_4" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li class="active">4</li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="61"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B31B0020H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B31B0020H">Genome-to-Watershed Predictive Understanding of Terrestrial Environments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hubbard, S. S.; Agarwal, D.; Banfield, J. F.; Beller, H. R.; Brodie, E.; Long, P.; Nico, P. S.; Steefel, C. I.; Tokunaga, T. K.; Williams, K. H. 2014-12-01 Although terrestrial environments play a critical role in cycling water, greenhouse gasses, and other life-critical elements, the complexity of interactions among component microbes, plants, minerals, migrating fluids and dissolved constituents hinders predictive understanding of system behavior. The 'Sustainable Systems 2.0' project is developing genome-to-watershed scale predictive capabilities to quantify how the microbiome affects biogeochemical watershed functioning, how watershed-scale hydro-biogeochemical processes affect microbial functioning, and how these interactions co-evolve with climate and land-use changes. Development of such predictive capabilities is critical for guiding the optimal management of water resources, contaminant remediation, carbon stabilization, and agricultural sustainability - now and with global change. Initial investigations are focused on floodplains in the Colorado River Basin, and include iterative model development, experiments and observations with an early emphasis on subsurface aspects. Field experiments include local-scale experiments at Rifle CO to quantify spatiotemporal metabolic and geochemical responses to O2and nitrate amendments as well as floodplain-scale monitoring to quantify genomic and biogeochemical response to natural hydrological perturbations. Information obtained from such experiments are represented within GEWaSC, a Genome-Enabled Watershed Simulation Capability, which is being developed to allow mechanistic interrogation of how genomic information stored in a subsurface microbiome affects biogeochemical cycling. This presentation will describe the genome-to-watershed scale approach as well as early highlights associated with the project. Highlights include: first insights into the diversity of the subsurface microbiome and metabolic roles of organisms involved in subsurface nitrogen, sulfur and hydrogen and carbon cycling; the extreme variability of subsurface DOC and hydrological controls on carbon and nitrogen cycling; geophysical identification of floodplain hotspots that are useful for model parameterization; and GEWaSC demonstration of how incorporation of identified microbial metabolic processes improves prediction of the larger system biogeochemical behavior. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=62689&keyword=thalassia&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=62689&keyword=thalassia&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">INFLUENCE OF THE SEAGRASS THALASSIA TESTUDINUM ON THE COMMUNITY COMPOSITION AND ACTIVITY OF SULFATE-REDUCING BACTERIA IN AN ESSENTIAL COAST MARINE HABITAT</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Biogeochemical cycling of nutrients and sulfate reduction rates (SRR) were studied in relation to the community composition of sulfate-reducing bacteria SRB) in a Thalassia testudinum bed and in adjacent unvegetated areas. Sampling took place in Santa Rosa Sound, Pensacola, Flori... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21277054','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21277054">Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Guo, Huaming; Zhang, Bo; Li, Yuan; Berner, Zsolt; Tang, Xiaohui; Norra, Stefan; Stüben, Doris 2011-04-01 Little is known about the importance of drainage/irrigation channels and biogeochemical processes in arsenic distribution of shallow groundwaters from the Hetao basin. This investigation shows that although As concentrations are primarily dependent on reducing conditions, evaporation increases As concentration in the centre of palaeo-lake sedimentation. Near drainage channels, groundwater As concentrations are the lowest in suboxic-weakly reducing conditions. Results demonstrate that both drainage and irrigation channels produce oxygen-rich water that recharges shallow groundwaters and therefore immobilize As. Groundwater As concentration increases with a progressive decrease in redox potential along the flow path in an alluvial fan. A negative correlation between SO₄²⁻ concentrations and δ³⁴S values indicates that bacterial reduction of SO₄²⁻ occurs in reducing aquifers. Due to high concentrations of Fe (> 0.5 mg L⁻¹), reductive dissolution of Fe oxides is believed to cause As release from aquifer sediments. Target aquifers for safe drinking water resources are available in alluvial fans and near irrigation channels. Copyright © 2011 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1399243-impact-organic-carbon-electron-donors-microbial-community-development-under-iron-sulfate-reducing-conditions','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1399243-impact-organic-carbon-electron-donors-microbial-community-development-under-iron-sulfate-reducing-conditions">Impact of Organic Carbon Electron Donors on Microbial Community Development under Iron- and Sulfate-Reducing Conditions</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Kwon, Man Jae; O’Loughlin, Edward J.; Boyanov, Maxim I.; ... 2016-01-22 Although iron- and sulfate-reducing bacteria in subsurface environments have crucial roles in biogeochemical cycling of C, Fe, and S, how specific electron donors impact the compositional structure and activity of native iron- and/or sulfate-reducing communities is largely unknown. To understand this better, we created bicarbonate-buffered batch systems in duplicate with three different electron donors (acetate, lactate, or glucose) paired with ferrihydrite and sulfate as the electron acceptors and inoculated them with subsurface sediment as the microbial inoculum. Sulfate and ferrihydrite reduction occurred simultaneously and were faster with lactate than with acetate. 16S rRNA-based sequence analysis of the communities over timemore » revealed that Desulfotomaculum was the major driver for sulfate reduction coupled with propionate oxidation in lactate-amended incubations. The reduction of sulfate resulted in sulfide production and subsequent abiotic reduction of ferrihydrite. In contrast, glucose promoted faster reduction of ferrihydrite, but without reduction of sulfate. Interestingly, the glucose-amended incubations led to two different biogeochemical trajectories among replicate bottles that resulted in distinct coloration (white and brown). The two outcomes in geochemical evolution might be due to the stochastic evolution of the microbial communities or subtle differences in the initial composition of the fermenting microbial community and its development via the use of different glucose fermentation pathways available within the community. Synchrotron-based x-ray analysis indicated that siderite and amorphous Fe(II) were formed in the replicate bottles with glucose, while ferrous sulfide and vivianite were formed with lactate or acetate. As a result, these data sets reveal that use of different C utilization pathways projects significant changes in microbial community composition over time that uniquely impact both the geochemistry and mineralogy of subsurface environments.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1399243','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1399243">Impact of Organic Carbon Electron Donors on Microbial Community Development under Iron- and Sulfate-Reducing Conditions</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Kwon, Man Jae; O’Loughlin, Edward J.; Boyanov, Maxim I. Although iron- and sulfate-reducing bacteria in subsurface environments have crucial roles in biogeochemical cycling of C, Fe, and S, how specific electron donors impact the compositional structure and activity of native iron- and/or sulfate-reducing communities is largely unknown. To understand this better, we created bicarbonate-buffered batch systems in duplicate with three different electron donors (acetate, lactate, or glucose) paired with ferrihydrite and sulfate as the electron acceptors and inoculated them with subsurface sediment as the microbial inoculum. Sulfate and ferrihydrite reduction occurred simultaneously and were faster with lactate than with acetate. 16S rRNA-based sequence analysis of the communities over timemore » revealed that Desulfotomaculum was the major driver for sulfate reduction coupled with propionate oxidation in lactate-amended incubations. The reduction of sulfate resulted in sulfide production and subsequent abiotic reduction of ferrihydrite. In contrast, glucose promoted faster reduction of ferrihydrite, but without reduction of sulfate. Interestingly, the glucose-amended incubations led to two different biogeochemical trajectories among replicate bottles that resulted in distinct coloration (white and brown). The two outcomes in geochemical evolution might be due to the stochastic evolution of the microbial communities or subtle differences in the initial composition of the fermenting microbial community and its development via the use of different glucose fermentation pathways available within the community. Synchrotron-based x-ray analysis indicated that siderite and amorphous Fe(II) were formed in the replicate bottles with glucose, while ferrous sulfide and vivianite were formed with lactate or acetate. As a result, these data sets reveal that use of different C utilization pathways projects significant changes in microbial community composition over time that uniquely impact both the geochemistry and mineralogy of subsurface environments.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26800443','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26800443">Impact of Organic Carbon Electron Donors on Microbial Community Development under Iron- and Sulfate-Reducing Conditions.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kwon, Man Jae; O'Loughlin, Edward J; Boyanov, Maxim I; Brulc, Jennifer M; Johnston, Eric R; Kemner, Kenneth M; Antonopoulos, Dionysios A 2016-01-01 Although iron- and sulfate-reducing bacteria in subsurface environments have crucial roles in biogeochemical cycling of C, Fe, and S, how specific electron donors impact the compositional structure and activity of native iron- and/or sulfate-reducing communities is largely unknown. To understand this better, we created bicarbonate-buffered batch systems in duplicate with three different electron donors (acetate, lactate, or glucose) paired with ferrihydrite and sulfate as the electron acceptors and inoculated them with subsurface sediment as the microbial inoculum. Sulfate and ferrihydrite reduction occurred simultaneously and were faster with lactate than with acetate. 16S rRNA-based sequence analysis of the communities over time revealed that Desulfotomaculum was the major driver for sulfate reduction coupled with propionate oxidation in lactate-amended incubations. The reduction of sulfate resulted in sulfide production and subsequent abiotic reduction of ferrihydrite. In contrast, glucose promoted faster reduction of ferrihydrite, but without reduction of sulfate. Interestingly, the glucose-amended incubations led to two different biogeochemical trajectories among replicate bottles that resulted in distinct coloration (white and brown). The two outcomes in geochemical evolution might be due to the stochastic evolution of the microbial communities or subtle differences in the initial composition of the fermenting microbial community and its development via the use of different glucose fermentation pathways available within the community. Synchrotron-based x-ray analysis indicated that siderite and amorphous Fe(II) were formed in the replicate bottles with glucose, while ferrous sulfide and vivianite were formed with lactate or acetate. These data sets reveal that use of different C utilization pathways projects significant changes in microbial community composition over time that uniquely impact both the geochemistry and mineralogy of subsurface environments. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016BGeo...13.4945S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016BGeo...13.4945S">Wetland eco-engineering: measuring and modeling feedbacks of oxidation processes between plants and clay-rich material</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Saaltink, Rémon; Dekker, Stefan C.; Griffioen, Jasper; Wassen, Martin J. 2016-09-01 Interest is growing in using soft sediment as a foundation in eco-engineering projects. Wetland construction in the Dutch lake Markermeer is an example: here, dredging some of the clay-rich lake-bed sediment and using it to construct wetland will soon begin. Natural processes will be utilized during and after construction to accelerate ecosystem development. Knowing that plants can eco-engineer their environment via positive or negative biogeochemical plant-soil feedbacks, we conducted a 6-month greenhouse experiment to identify the key biogeochemical processes in the mud when Phragmites australis is used as an eco-engineering species. We applied inverse biogeochemical modeling to link observed changes in pore water composition to biogeochemical processes. Two months after transplantation we observed reduced plant growth and shriveling and yellowing of foliage. The N : P ratios of the plant tissue were low, and these were affected not by hampered uptake of N but by enhanced uptake of P. Subsequent analyses revealed high Fe concentrations in the leaves and roots. Sulfate concentrations rose drastically in our experiment due to pyrite oxidation; as reduction of sulfate will decouple Fe-P in reducing conditions, we argue that plant-induced iron toxicity hampered plant growth, forming a negative feedback loop, while simultaneously there was a positive feedback loop, as iron toxicity promotes P mobilization as a result of reduced conditions through root death, thereby stimulating plant growth and regeneration. Given these two feedback mechanisms, we propose the use of Fe-tolerant species rather than species that thrive in N-limited conditions. The results presented in this study demonstrate the importance of studying the biogeochemical properties of the situated sediment and the feedback mechanisms between plant and soil prior to finalizing the design of the eco-engineering project. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28502020','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28502020">Biogeochemical zonation of sulfur during the discharge of groundwater to lake in desert plateau (Dakebo Lake, NW China).</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Su, Xiaosi; Cui, Geng; Wang, Huang; Dai, Zhenxue; Woo, Nam-Chil; Yuan, Wenzhen 2018-06-01 As one of the important elements of controlling the redox system within the hyporheic and hypolentic zone, sulfur is involved in a series of complex biogeochemical processes such as carbon cycle, water acidification, formation of iron and manganese minerals, redox processes of trace metal elements and a series of important ecological processes. Previous studies on biogeochemistry of the hyporheic and hypolentic zones mostly concentrated on nutrients of nitrogen and phosphorus, heavy metals and other pollutants. Systematic study of biogeochemical behavior of sulfur and its main controlling factors within the lake hypolentic zone is very urgent and important. In this paper, a typical desert plateau lake, Dakebo Lake in northwestern China, was taken for example within which redox zonation and biogeochemical characteristics of sulfur affected by hydrodynamic conditions were studied based on not only traditional hydrochemical analysis, but also environmental isotope evidence. In the lake hypolentic zone of the study area, due to the different hydrodynamic conditions, vertical profile of sulfur species and environmental parameters differ at the two sites of the lake (western side and center). Reduction of sulfate, deposition and oxidation of sulfide, dissolution and precipitation of sulfur-bearing minerals occurred are responded well to Eh, dissolved oxygen, pH, organic carbon and microorganism according to which the lake hypolentic zone can be divided into reduced zone containing H 2 S, reduced zone containing no H 2 S, transition zone and oxidized zone. The results of this study provide valuable insights for understanding sulfur conversion processes and sulfur biogeochemical zonation within a lake hypolentic zone in an extreme plateau arid environment and for protecting the lake-wetland ecosystem in arid and semiarid regions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.4427P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.4427P">Hyporheic zone as a bioreactor: sediment heterogeneity influencing biogeochemical processes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Perujo, Nuria; Romani, Anna M.; Sanchez-Vila, Xavier 2017-04-01 Mediterranean fluvial systems are characterized by frequent periods of low flow or even drought. During low flow periods, water from wastewater treatment plants (WWTPs) is proportionally large in fluvial systems. River water might be vertically transported through the hyporheic zone, and then porous medium acts as a complementary treatment system since, as water infiltrates, a suite of biogeochemical processes occurs. Subsurface sediment heterogeneity plays an important role since it influences the interstitial fluxes of the medium and drives biomass growing, determining biogeochemical reactions. In this study, WWTP water was continuously infiltrated for 3 months through two porous medium tanks: one consisting of 40 cm of fine sediment (homogeneous); and another comprised of two layers of different grain size sediments (heterogeneous), 20 cm of coarse sediment in the upper part and 20 cm of fine one in the bottom. Several hydrological, physicochemical and biological parameters were measured periodically (weekly at the start of the experiment and biweekly at the end). Analysed parameters include dissolved nitrogen, phosphorus, organic carbon, and oxygen all measured at the surface, and at 5, 20 and 40 cm depth. Variations in hydraulic conductivity with time were evaluated. Sediment samples were also analysed at three depths (surface, 20 and 40 cm) to determine bacterial density, chlorophyll content, extracellular polymeric substances, and biofilm function (extracellular enzyme activities and carbon substrate utilization profiles). Preliminary results suggest hydraulic conductivity to be the main driver of the differences in the biogeochemical processes occurring in the subsurface. At the heterogeneous tank, a low nutrient reduction throughout the whole medium is measured. In this medium, high hydraulic conductivity allows for a large amount of infiltrating water, but with a small residence time. Since some biological processes are largely time-dependent, small water residence time results in low nutrient reduction. Moreover, high nitrification and low ammonium concentration in the interface of the two grain-size layers are measured, probably related to high dissolved oxygen concentration at the coarse-fine sediment interface, further promoting accumulation of bacteria and algae. In contrast, the homogeneous tank shows low dissolved oxygen values and high denitrification in depth which could be related to lower overall hydraulic conductivity, as compared to the heterogeneous tank. The preliminary analysis of our results indicates a key role of hydraulic conductivity on biogeochemical processes in the porous medium but, at the same time that it is strongly interacting with sediment grain-size distribution and the development of biofilm. The final scope of this study is to know the interactions between physicochemical and biological components in sediments in order to understand in detail the biogeochemical processes occurring. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1184285-disturbed-subsurface-microbial-communities-follow-equivalent-trajectories-despite-different-structural-starting-points','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1184285-disturbed-subsurface-microbial-communities-follow-equivalent-trajectories-despite-different-structural-starting-points">Disturbed subsurface microbial communities follow equivalent trajectories despite different structural starting points</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Handley, Kim M.; Wrighton, Kelly C.; Miller, Christopher S. 2015-03-01 We explored the impact of the starting community composition and structure on ecosystem response to perturbations using organic carbon amendment experiments. Subsurface sediment was partitioned into flow-through columns, and the microbial communities were initially stimulated in situ by addition of acetate as a carbon and electron donor source. This drove community richness and evenness down, and pushed the system into a new biogeochemical state characterized by iron reduction. Reconstructed near-full-length 16S rRNA gene sequence analysis indicated a concomitant enrichment of Desulfuromonadales, Comamonadaceae and Bacteroidetes lineages. After 10 to 12 days, acetate was exchange for lactate in a subset of columns.more » Following the clear onset of sulfate reduction (35 days after acetate-amendment), acetate was substituted for lactate in additional columns. Acetatestimulated communities differed markedly during each biogeochemical regime and at each lactate-switch. Regardless, however, of when communities were switched to lactate, they followed comparable trajectories with respect to composition and structure, with convergence evident one week after each switch, and marked after one month of lactate amendment. During sulfate reduction all treatments were enriched in Firmicutes and a number of species likely involved in sulfate reduction (notably Desulfobulbus, Desulfosporosinus, Desulfitobacterium and Desulfotomaculum). Lactate treatments were distinguished by substantially lower relative abundances of Desulfotomaculum and Bacteroidetes, and enrichments of Psychrosinus and Clostridiales species. Results imply that the structure of the starting community was not significant in controlling organism selection in community succession.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009AGUFM.H31E0828B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009AGUFM.H31E0828B">Microbial Community Phylogenetic and Functional Succession in Chromium-Reducing Aquifer-Derived Microcosms</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brodie, E. L.; Beller, H. R.; Goldfarb, K. C.; Han, R.; Santee, C. A. 2009-12-01 In situ reductive immobilization, whereby highly soluble Cr(VI) species are reduced to poorly soluble Cr(III) species, is a favored approach for remediating Cr-contaminated groundwater. How microbial populations respond phylogenetically and functionally to the injection of an organic electron donor to stimulate Cr(VI) reduction is unclear, as are the relative contributions of direct enzymatic Cr(VI) reduction versus indirect (e.g. sulfide-mediated) reduction. In this study, we inoculated anaerobic microcosms with groundwater from the Cr-contaminated Hanford 100H site (WA) and supplemented them with lactate and the electron acceptors nitrate, sulfate, and amorphous ferric oxyhydroxide. The microcosms progressed successively through nitrate-reducing, sulfate-reducing, and Fe(III)-reducing conditions, and after a second nitrate amendment, nitrate-dependent Fe(II)-oxidizing conditions. Cr(VI) reduction occurred during both the denitrification and the sulfate/iron reduction phases. DNA and RNA were harvested during each major biogeochemical phase and were subjected to PhyloChip analysis, qPCR, and transcript sequencing. Bacterial community succession followed a trajectory related to the sequential use of electron acceptors. During denitrification, bacterial communities were enriched in known denitrifiers within the Beta- and Gamma-proteobacteria and became phylogenetically clustered. Fermenters became enriched following nitrate reduction, preceding both iron and sulfate reduction. Iron reduction was stoichiometrically related to the formation of hydrogen sulfide and, although iron reducers were detected during this phase, their iron-reducing activity was not confirmed. Following the depletion of lactate and sulfate, iron reduction rates decreased and acetate and propionate concentrations stabilized, indicating a marginal contribution of acetate-coupled iron reduction. Rapid Fe(II) oxidation occurred following the nitrate amendment with a concomitant reduction of nitrate to nitrite and an increased abundance of Beta-proteobacterial species related to known anaerobic Fe(II)-oxidizing bacteria. To uncover the microbial mechanisms contributing to the biogeochemical complexity encountered, even under controlled laboratory incubations, requires alternatives to standard phylogenetic analyses. Our ongoing efforts in analyzing the community transcriptomes (mRNA) should provide valuable insight into the relative rates of direct versus indirect mechanisms of Cr(VI) immobilization in contaminated aquifers. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMOS21A1348F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMOS21A1348F">Enhanced Sulfate Reduction and Carbon Sequestration in Sediments Underlying the Core of the Arabian Sea Oxygen Minimum Zone</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fernandes, S. Q.; Mazumdar, A.; Peketi, A.; Bhattacharya, S.; Carvalho, M.; Da Silva, R.; Roy, R.; Mapder, T.; Roy, C.; Banik, S. K.; Ghosh, W. 2017-12-01 The oxygen minimum zone (OMZ) of the Arabian Sea in the northern Indian Ocean is one of the three major global sites of open ocean denitrification. The functionally anoxic water column between 150 to 1200 mbsl plays host to unique biogeochemical processes and organism interactions. Little is known, however, about the consequence of the low dissolved oxygen on the underlying sedimentary biogeochemical processes. Here we present, for the first time, a comprehensive investigation of sediment biogeochemistry of the Arabian Sea OMZ by coupling pore fluid analyses with microbial diversity data in eight sediment cores collected across a transect off the west coast of India in the Eastern Arabian Sea. We observed that in sediments underlying the core of the OMZ, high organic carbon sequestration coincides with a high diversity of all bacteria (the majority of which are complex organic matter hydrolyzers) and sulfate reducing bacteria (simple organic compound utilizers). Depth-integrated sulfate reduction rate also intensifies in this territory. These biogeochemical features, together with the detected shallowing of the sulfate-methane interface and buildup of pore-water sulfide, are all reflective of heightened carbon-sulfur cycling in the sediments underlying the OMZ core. Our data suggests that the sediment biogeochemistry of the OMZ is sensitive to minute changes in bottom water dissolved oxygen, and is dictated by the potential abundance and bioavailability of complex to simple carbon compounds which can stimulate a cascade of geomicrobial activities pertaining to the carbon-sulfur cycle. Our findings hold implications in benthic ecology and sediment diagenesis. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27743654','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27743654">Impacts of detrital nano- and micro-scale particles (dNP) on contaminant dynamics in a coal mine AMD treatment system.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lefticariu, Liliana; Sutton, Stephen R; Bender, Kelly S; Lefticariu, Mihai; Pentrak, Martin; Stucki, Joseph W 2017-01-01 Pollutants in acid mine drainage (AMD) are usually sequestered in neoformed nano- and micro-scale particles (nNP) through precipitation, co-precipitation, and sorption. Subsequent biogeochemical processes may control nNP stability and thus long-term contaminant immobilization. Mineralogical, chemical, and microbiological data collected from sediments accumulated over a six-year period in a coal-mine AMD treatment system were used to identify the pathways of contaminant dynamics. We present evidence that detrital nano- and micron-scale particles (dNP), composed mostly of clay minerals originating from the partial weathering of coal-mine waste, mediated biogeochemical processes that catalyzed AMD contaminant (1) immobilization by facilitating heterogeneous nucleation and growth of nNP in oxic zones, and (2) remobilization by promoting phase transformation and reductive dissolution of nNP in anoxic zones. We found that dNP were relatively stable under acidic conditions and estimated a dNP content of ~0.1g/L in the influent AMD. In the AMD sediments, the initial nNP precipitates were schwertmannite and poorly crystalline goethite, which transformed to well-crystallized goethite, the primary nNP repository. Subsequent reductive dissolution of nNP resulted in the remobilization of up to 98% of S and 95% of Fe accompanied by the formation of a compact dNP layer. Effective treatment of pollutants could be enhanced by better understanding the complex, dynamic role dNP play in mediating biogeochemical processes and contaminant dynamics at coal-mine impacted sites. Copyright © 2016 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..1512504A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..1512504A">Biogeochemial modeling of biodegradation and stable isotope fractionation of DCE in a small-scale wetland</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Alvarez-Zaldívar, Pablo; Imfeld, Gwenaël; Maier, Uli; Centler, Florian; Thullner, Martin 2013-04-01 In recent years, the use of (constructed) wetlands has gained significant attention for the in situ remediation of groundwater contaminated with (chlorinated) organic hydrocarbons. Although many sophisticated experimental methods exist for the assessment of contaminant removal in such wetlands the understanding how changes in wetland hydrochemistry affect the removal processes is still limited. This knowledge gap might be reduced by the use of biogeochemical reactive transport models. This study presents the reactive transport simulation of a small-scale constructed wetland treated with groundwater containing cis-1,2-dichloroethene (cDCE). Simulated processes consider different cDCE biodegradation pathways and the associated carbon isotope fractionation, a set of further (bio)geochemical processes as well as the activity of the plant roots. Spatio-temporal hydrochemical and isotope data from a long-term constructed wetland experiment [1] are used to constrain the model. Simulation results for the initial oxic phase of the wetland experiment indicate carbon isotope enrichment factors typical for cometabolic DCE oxidation, which suggests that aerobic treatment of cDCE is not an optimal remediation strategy. For the later anoxic phase of the experiment model derived enrichment factors indicate reductive dechlorination pathways. This degradation is promoted at all wetland depths by a sufficient availability of electron donor and carbon sources from root exudates, which makes the anoxic treatment of groundwater in such wetlands an effective remediation strategy. In combination with the previous experimental data results from this study suggest that constructed wetlands are viable remediation means for the treatment of cDCE contaminated groundwater. Reactive transport models can improve the understanding of the factors controlling chlorinated ethenes removal, and the used model approach would also allow for an optimization of the wetland operation needed for a complete degradation of these contaminants. [1] Imfeld, G., Aragonés, C., Zeiger, S., von Eckstädt, C., Paschke, H., Trabitzsch, R., Weiss, H., and Richnow, H. (2008). Tracking in situ biodegradation of 1,2-dicholoroethenes in a model wetland. Environ. Sci. Technol., 42: 7924-7930. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21439607','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21439607">Cost assessment and ecological effectiveness of nutrient reduction options for mitigating Phaeocystis colony blooms in the Southern North Sea: an integrated modeling approach.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lancelot, Christiane; Thieu, Vincent; Polard, Audrey; Garnier, Josette; Billen, Gilles; Hecq, Walter; Gypens, Nathalie 2011-05-01 Nutrient reduction measures have been already taken by wealthier countries to decrease nutrient loads to coastal waters, in most cases however, prior to having properly assessed their ecological effectiveness and their economic costs. In this paper we describe an original integrated impact assessment methodology to estimate the direct cost and the ecological performance of realistic nutrient reduction options to be applied in the Southern North Sea watershed to decrease eutrophication, visible as Phaeocystis blooms and foam deposits on the beaches. The mathematical tool couples the idealized biogeochemical GIS-based model of the river system (SENEQUE-RIVERSTRAHLER) implemented in the Eastern Channel/Southern North Sea watershed to the biogeochemical MIRO model describing Phaeocystis blooms in the marine domain. Model simulations explore how nutrient reduction options regarding diffuse and/or point sources in the watershed would affect the Phaeocystis colony spreading in the coastal area. The reference and prospective simulations are performed for the year 2000 characterized by mean meteorological conditions, and nutrient reduction scenarios include and compare upgrading of wastewater treatment plants and changes in agricultural practices including an idealized shift towards organic farming. A direct cost assessment is performed for each realistic nutrient reduction scenario. Further the reduction obtained for Phaeocystis blooms is assessed by comparison with ecological indicators (bloom magnitude and duration) and the cost for reducing foam events on the beaches is estimated. Uncertainty brought by the added effect of meteorological conditions (rainfall) on coastal eutrophication is discussed. It is concluded that the reduction obtained by implementing realistic environmental measures on the short-term is costly and insufficient to restore well-balanced nutrient conditions in the coastal area while the replacement of conventional agriculture by organic farming might be an option to consider in the nearby future. Copyright © 2011 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.H41B1307P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.H41B1307P">Data and Model Uncertainties associated with Biogeochemical Groundwater Remediation and their impact on Decision Analysis</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Pandey, S.; Vesselinov, V. V.; O'Malley, D.; Karra, S.; Hansen, S. K. 2016-12-01 Models and data are used to characterize the extent of contamination and remediation, both of which are dependent upon the complex interplay of processes ranging from geochemical reactions, microbial metabolism, and pore-scale mixing to heterogeneous flow and external forcings. Characterization is wrought with important uncertainties related to the model itself (e.g. conceptualization, model implementation, parameter values) and the data used for model calibration (e.g. sparsity, measurement errors). This research consists of two primary components: (1) Developing numerical models that incorporate the complex hydrogeology and biogeochemistry that drive groundwater contamination and remediation; (2) Utilizing novel techniques for data/model-based analyses (such as parameter calibration and uncertainty quantification) to aid in decision support for optimal uncertainty reduction related to characterization and remediation of contaminated sites. The reactive transport models are developed using PFLOTRAN and are capable of simulating a wide range of biogeochemical and hydrologic conditions that affect the migration and remediation of groundwater contaminants under diverse field conditions. Data/model-based analyses are achieved using MADS, which utilizes Bayesian methods and Information Gap theory to address the data/model uncertainties discussed above. We also use these tools to evaluate different models, which vary in complexity, in order to weigh and rank models based on model accuracy (in representation of existing observations), model parsimony (everything else being equal, models with smaller number of model parameters are preferred), and model robustness (related to model predictions of unknown future states). These analyses are carried out on synthetic problems, but are directly related to real-world problems; for example, the modeled processes and data inputs are consistent with the conditions at the Los Alamos National Laboratory contamination sites (RDX and Chromium). </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1913886N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1913886N">Spectral induced polarization as a tool to map subsurface biogeochemical hot spots: a first laboratory evaluation in the Fe-S system</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Nordsiek, Sven; Gilfedder, Ben; Frei, Sven 2017-04-01 Zones of intense biogeochemical reactivity (hot spots) arise in the saturated subsurface at the interface between regions with oxidizing and reducing conditions. Hot spots are both sinks and sources of different chemical compounds, thus they are of particular importance for element cycling in the subsurface. However, the investigation of hot spot structures is difficult, because they are not directly identifiable from the surface and can only be investigated by invasive methods in the subsurface. Additionally, they often form in sensitive wetland ecosystems where only non-destructive measurements are applicable to avoid significant degradation of these sensitive environments. Under these circumstances, geophysical methods may provide useful tools to identify biogeochemically active regions. One of the most important biogeochemical reactions in wetlands is the reduction of sulphate and formation and accumulation of FexSy minerals (where x and y delineate mineral stoichiometry). These reactions only occur in specific hot spots where specific chemical and microbial conditions are met. Within a research project concerning biogeochemical transformations and turnover in wetlands, we investigate the applicability of the geoelectrical method of spectral induced polarization (SIP) to locate and monitor regions containing polarizing FexSy particles as indicator for biogeochemical hot spots. After developing and testing a sample holder and a set of non-polarizing electrodes for laboratory SIP measurements, we performed experiments on natural soil samples taken from the hyporheic zone of a local river channel. The collected material originates from a location known for biogeochemical activity. The sample contains a high percentage of dark grayish/black sediment interpreted as FexSy, and possibly pyrite (FeS2). The material was homogenized and split into four samples. The FexSy concentration was adjusted to three different levels by oxidation using H2O2. For all samples we recorded the SIP spectra in the frequency range between 0.26 Hz and 25 Hz repeatedly. The sensitivity of SIP measurements to the FexSy content is promising. For a sample of the sediment saturated with its natural fluid (conductivity > 600 μS/cm), we observed phase shifts of more than 7 mrad at frequencies between 1 and 10 Hz. We expect a lower fluid conductivity and thus a larger maximum phase shift for measurements in wetlands. The application of the SIP method in field surveys at places with biogeochemical activity will be the next step in our study. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B13B0468C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B13B0468C">Investigating the organic carbon cycle and the anaerobic oxidation of methane in the Guaymas Basin: a biogeochemical approach</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cathalot, C.; Decker, C.; Caprais, J.; Ruffine, L.; Le Bruchec, J.; Olu, K. 2013-12-01 The Guaymas Basin is a pretty unique environment located in the Gulf of California and characterized by the emanation of fluids enriched in hydrocarbon, mainly methane, and sulfides. In this peculiar environment, both cold seeps and hydrothermal vents co-exist very closely, and are separated only by a few kilometers. In addition, highly productive surface waters and strong terrestrial inputs are responsible for strong sedimentation rates in this area. This special geological system allows for the development of various and complex macrofaunal and/or bacterial assemblages, based on chemosynthetic activity. These sea-bottom communities have been previously described [1,2] and several studies have demonstrated the occurrence of Anaerobic Oxidation of Methane (AOM) in the shallow sediment layers. Nevertheless, the quantification of the biogeochemical processes (e.g. rates, relative proportions) involved in both ecosystems in relation with the associated communities, and their role in the local organic carbon (OC) cycle is still lacking. Using a diagenetic modeling approach, this study aims at studying the OC production and recycling processes by describing the biogeochemical pathways and their associated rates in the ecosystems from the Guaymas Basin. Twelve stations presenting distinct biological assemblages (microbial mats, vesicomyids and bare sediment) were selected among both cold-seeps and hydrothermal vents sites from the Guaymas basin. A transport-reaction model including respiration, sulfate reduction, methanogenesis and AOM was developed and applied to each station. To constrain the model, at each station, cores were sampled using an ROV and the pore-waters extracted using Rhizon syringes. Pore-water concentrations of CH4, SO42-, Cl- and H2S were then measured. In addition, ex situ O2 microprofiles equipped with microsensors and in situ incubations using benthic chambers were performed to estimate the sediment uptake rates (O2, H2S, CH4). The overall dataset was used to feed the model. The preliminary results indicate 1) significant differences of biogeochemical processes between the different biological assemblages and 2) between the cold seeps and hydrothermal vents sites. Model outputs show the occurrence of AOM and sulfate reduction at all sites except the reference (i.e. bare sediment) confirming hence the chemosynthetic activity (OC production) within the specific biological assemblages (mats and Vesicomyid). AOM in bacterial mats was more active in hydrothermal vents than in cold-seeps. In addition, the results indicate strong sulfate reduction rates in Vesicomyids assemblages but with a clear mismatch between modeled and measured H2S concentrations in the sediment: such differences reflect the symbiosis chemosynthetic activity (i.e. the H2S consumption) within the organisms. This integrated model-data approach proves hence to be useful to infer the biogeochemical functioning of biological ecosystems. [1] Kallmeyer, J. & Boetius, A (2004): Applied and Environmental Microbiology, 70, 2, 1231-1233. [2] Biddle J. F. et al. (2012). ISME J. 6 1018-1031 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70031337','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70031337">Centimeter-scale characterization of biogeochemical gradients at a wetland-aquifer interface using capillary electrophoresis</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Baez-Cazull, S.; McGuire, J.T.; Cozzarelli, I.M.; Raymond, A.; Welsh, L. 2007-01-01 Steep biogeochemical gradients were measured at mixing interfaces in a wetland-aquifer system impacted by landfill leachate in Norman, Oklahoma. The system lies within a reworked alluvial plain and is characterized by layered low hydraulic conductivity wetland sediments interbedded with sandy aquifer material. Using cm-scale passive diffusion samplers, "peepers", water samples were collected in a depth profile to span interfaces between surface water and a sequence of deeper sedimentary layers. Geochemical indicators including electron acceptors, low-molecular-weight organic acids, base cations, and NH4+ were analyzed by capillary electrophoresis (CE) and field techniques to maximize the small sample volumes available from the centimeter-scale peepers. Steep concentration gradients of biogeochemical indicators were observed at various interfaces including those created at sedimentary boundaries and boundaries created by heterogeneities in organic C and available electron acceptors. At the sediment-water interface, chemical profiles with depth suggest that SO42 - and Fe reduction dominate driven by inputs of organic C from the wetland and availability of electron acceptors. Deeper in the sediments (not associated with a lithologic boundary), a steep gradient of organic acids (acetate maximum 8.8 mM) and NH4+ (maximum 36 mM) is observed due to a localized source of organic matter coupled with the lack of electron acceptor inputs. These findings highlight the importance of quantifying the redox reactions occurring in small interface zones and assessing their role on biogeochemical cycling at the system scale. ?? 2007 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.6285B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.6285B">Dimensionless Numbers For Morphological, Thermal And Biogeochemical Controls Of Hyporheic Processes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bellin, Alberto; Marzadri, Alessandra; Tonina, Daniele 2013-04-01 Transport of solutes and heat within the hyporheic zone are interface processes that gained growing attention in the last decade, when several modelling strategies have been proposed, mainly at the local or reach scale. We propose to upscale local hyporheic biogeochemical processes to reach and network scales by means of a Lagrangian modelling framework, which allows to consider the impact of the flow structure on the processes modelled. This analysis shows that geochemical processes can be parametrized through two new Damköhler numbers, DaO, and DaT. DaO = ?up,50-?lim is defined as the ratio between the median hyporheic residence time, ?up,50 and the time of consuming dissolved oxygen to a prescribed threshold concentration, ?lim, below which reductive reactions are activated. It quantifies the biogeochemical status of the hyporheic zone and could be a metric for upscaling local hyporheic biogeochemical processes to reach and river-network scale processes. In addition, ?up,50 is the time scale of hyporheic advection; while ?lim is the representative time scale of biogeochemical reactions and indicates the distance along the streamline, measured as the time needed to travel that distance, that a particle of water travels before the dissolved oxygen concentration declines to [DO]lim, the value at which denitrification is activated. We show that DaO is representative of the redox status and indicates whether the hyporheic zone is a source or a sink of nitrate. Values of DaO larger than 1 indicate prevailing anaerobic conditions, whereas values smaller than 1 prevailing aerobic conditions. Similarly, DaT quantifies the importance of the temperature daily oscillations of the stream water on the hyporheic environment. It is defined as the ratio between ?up,50, and the time limit at which the ratio between the amplitude of the temperature oscillation within the hyporheic zone (evaluated along the streamline) and in the stream water is smaller than e-1. We show that values of DaT > 1 indicate a thermally stable hyporheic zone, where organism metabolism is not influenced by surface water thermal oscillations and biogeochemical reaction rates depend on the mean daily stream water temperature. Values smaller than 1 suggest that organisms need to adapt to the daily thermal variations and biogeochemical reaction rates will depend on the daily fluctuations induced by stream water. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_2");'>2</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li class="active">4</li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_5" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li class="active">5</li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="81"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23397992','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23397992">U(VI) bioreduction with emulsified vegetable oil as the electron donor--microcosm tests and model development.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Tang, Guoping; Wu, Wei-Min; Watson, David B; Parker, Jack C; Schadt, Christopher W; Shi, Xiaoqing; Brooks, Scott C 2013-04-02 We conducted microcosm tests and biogeochemical modeling to study U(VI) reduction in contaminated sediments amended with emulsified vegetable oil (EVO). Indigenous microorganisms in the sediments degraded EVO and stimulated Fe(III), U(VI), and sulfate reduction, and methanogenesis. Acetate concentration peaked in 100-120 days in the EVO microcosms versus 10-20 days in the oleate microcosms, suggesting that triglyceride hydrolysis was a rate-limiting step in EVO degradation and subsequent reactions. Acetate persisted 50 days longer in oleate- and EVO- than in ethanol-amended microcosms, indicating that acetate-utilizing methanogenesis was slower in the oleate and EVO than ethanol microcosms. We developed a comprehensive biogeochemical model to couple EVO hydrolysis, production, and oxidation of long-chain fatty acids (LCFA), glycerol, acetate, and hydrogen, reduction of Fe(III), U(VI) and sulfate, and methanogenesis with growth and decay of multiple functional microbial groups. By estimating EVO, LCFA, and glycerol degradation rate coefficients, and introducing a 100 day lag time for acetoclastic methanogenesis for oleate and EVO microcosms, the model approximately matched observed sulfate, U(VI), and acetate concentrations. Our results confirmed that EVO could stimulate U(VI) bioreduction in sediments and the slow EVO hydrolysis and acetate-utilizing methanogens growth could contribute to longer term bioreduction than simple substrates (e.g., ethanol, acetate, etc.) in the subsurface. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1214871','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1214871">Constraining the role of iron in environmental nitrogen transformations. Dual stable isotope systematics of abiotic NO 2- reduction by Fe(II) and its production of N 2O</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Johnston, David; Wankel, Scott David; Buchwald, Carolyn Redox reactions involving nitrogen and iron have been shown to have important implications for mobilization of priority contaminants. Thus, an understanding of the linkages between their biogeochemical cycling is critical for predicting subsurface mobilization of radionuclides such as uranium. Despite mounting evidence for biogeochemical interactions between iron and nitrogen, our understanding of their environmental importance remains limited. Here we present an investigation of abiotic nitrite (NO 2 -) reduction by Fe(II) or ‘chemodenitrification,’ and its relevance to the production of nitrous oxide (N 2O), specifically focusing on dual (N and O) isotope systematics under a variety of environmentally relevant conditions.more » We observe a range of kinetic isotope effects that are regulated by reaction rates, with faster rates at higher pH (~8), higher concentrations of Fe(II) and in the presence of mineral surfaces. A clear non-linear relationship between rate constant and kinetic isotope effects of NO 2 - reduction was evident (with larger isotope effects at slower rates) and is interpreted as reflecting the dynamics of Fe(II)-N reaction intermediates. N and O isotopic composition of product N 2O also suggests a complex network of parallel and/or competing pathways. Our findings suggest that NO 2 - reduction by Fe(II) may represent an important abiotic source of environmental N 2O, especially in iron-rich environments experiencing dynamic redox variations. This study provides a multi-compound, multi-isotope framework for evaluating the environmental occurrence of abiotic NO 2 - reduction and N 2O formation, helping future studies constrain the relative roles of abiotic and biological N 2O production pathways.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2007AGUFM.B51B0364A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2007AGUFM.B51B0364A">Biogeochemical Reactions Under Simulated Europa Ocean Conditions</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Amashukeli, X.; Connon, S. A.; Gleeson, D. F.; Kowalczyk, R. S.; Pappalardo, R. T. 2007-12-01 Galileo data have demonstrated the probable presence of a liquid water ocean on Europa, and existence of salts and carbon dioxide in the satellite's surface ice (e.g., Carr et al., 1998; McCord et al., 1999, Pappalardo et al., 1999; Kivelson et al., 2000). Subsequently, the discovery of chemical signatures of extinct or extant life in Europa's ocean and on its surface became a distinct possibility. Moreover, understanding of Europa's potential habitability is now one of the major goals of the Europa Orbiter Flagship mission. It is likely, that in the early stages of Europa's ocean formation, moderately alkaline oceanic sulfate-carbonate species and a magnetite-silicate mantel could have participated in low-temperature biogeochemical sulfur, iron and carbon cycles facilitated by primitive organisms (Zolotov and Shock, 2004). If periodic supplies of fresh rock and sulfate-carbonate ions are available in Europa's ocean, then an exciting prospect exists that life may be present in Europa's ocean today. In our laboratory, we began the study of the plausible biogeochemical reactions under conditions appropriate to Europa's ocean using barophilic psychrophilic organisms that thrive under anaerobic conditions. In the near absence of abiotic synthetic pathways due to low Europa's temperatures, the biotic synthesis may present a viable opportunity for the formation of the organic and inorganic compounds under these extreme conditions. This work is independent of assumptions regarding hydrothermal vents at Europa's ocean floor or surface-derived oxidant sources. For our studies, we have fabricated a high-pressure (5,000 psi) reaction vessel that simulates aqueous conditions on Europa. We were also successful at reviving barophilic psychrophilic strains of Shewanella bacterium, which serve as test organisms in this investigation. Currently, facultative barophilic psychrophilic stains of Shewanella are grown in the presence of ferric food source; the strains exhibiting iron reduction capability will be later selected and used to facilitate biogeochemical reduction of iron under simulated temperature and pressure of Europa's ocean. The results of this work will enable us to ascertain whether Europa's cold, high-pressure ocean is capable of supporting life. In addition, the data from this study will help in generating a list of organic and inorganic target molecules for future remote sensing and in situ exploration missions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1198482-variable-stoichiometry-dissolved-organic-matter-cycling-community-earth-system-model','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1198482-variable-stoichiometry-dissolved-organic-matter-cycling-community-earth-system-model">Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; ... 2014-06-16 Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a~fact that is often omitted from biogeochemical-ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observational data coveragemore » and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C / N / P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr -1 (143 Tmol C yr -1), 16.4 Tmol N yr -1, and 1 Tmol P yr -1, respectively with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. DOC export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1198058-variable-stoichiometry-dissolved-organic-matter-cycling-community-earth-system-model','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1198058-variable-stoichiometry-dissolved-organic-matter-cycling-community-earth-system-model">Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; ... 2015-01-12 Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a fact that is often omitted from biogeochemical ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observationalmore » data coverage and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C : N : P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model (CESM) and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr -1 (143 Tmol C yr -1, 16.4 Tmol N yr -1, and 1 Tmol P yr -1, respectively, with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. Dissolved organic carbon (DOC) export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMGC13A1134F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMGC13A1134F">High-Resolution Biogeochemical Simulation Identifies Practical Opportunities for Bioenergy Landscape Intensification Across Diverse US Agricultural Regions</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Field, J.; Adler, P. R.; Evans, S.; Paustian, K.; Marx, E.; Easter, M. 2015-12-01 The sustainability of biofuel expansion is strongly dependent on the environmental footprint of feedstock production, including both direct impacts within feedstock-producing areas and potential leakage effects due to disruption of existing food, feed, or fiber production. Assessing and minimizing these impacts requires novel methods compared to traditional supply chain lifecycle assessment. When properly validated and applied at appropriate spatial resolutions, biogeochemical process models are useful for simulating how the productivity and soil greenhouse gas fluxes of cultivating both conventional crops and advanced feedstock crops respond across gradients of land quality and management intensity. In this work we use the DayCent model to assess the biogeochemical impacts of agricultural residue collection, establishment of perennial grasses on marginal cropland or conservation easements, and intensification of existing cropping at high spatial resolution across several real-world case study landscapes in diverse US agricultural regions. We integrate the resulting estimates of productivity, soil carbon changes, and nitrous oxide emissions with crop production budgets and lifecycle inventories, and perform a basic optimization to generate landscape cost/GHG frontiers and determine the most practical opportunities for low-impact feedstock provisioning. The optimization is constrained to assess the minimum combined impacts of residue collection, land use change, and intensification of existing agriculture necessary for the landscape to supply a commercial-scale biorefinery while maintaining exiting food, feed, and fiber production levels. These techniques can be used to assess how different feedstock provisioning strategies perform on both economic and environmental criteria, and sensitivity of performance to environmental and land use factors. The included figure shows an example feedstock cost-GHG mitigation tradeoff frontier for a commercial-scale cellulosic biofuel facility in Kansas. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70178260','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70178260">Biogeochemical redox processes and their impact on contaminant dynamics</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Borch, Thomas; Kretzschmar, Ruben; Kappler, Andreas; Van Cappellen, Philippe; Ginder-Vogel, Matthew; Campbell, Kate M. 2010-01-01 Life and element cycling on Earth is directly related to electron transfer (or redox) reactions. An understanding of biogeochemical redox processes is crucial for predicting and protecting environmental health and can provide new opportunities for engineered remediation strategies. Energy can be released and stored by means of redox reactions via the oxidation of labile organic carbon or inorganic compounds (electron donors) by microorganisms coupled to the reduction of electron acceptors including humic substances, iron-bearing minerals, transition metals, metalloids, and actinides. Environmental redox processes play key roles in the formation and dissolution of mineral phases. Redox cycling of naturally occurring trace elements and their host minerals often controls the release or sequestration of inorganic contaminants. Redox processes control the chemical speciation, bioavailability, toxicity, and mobility of many major and trace elements including Fe, Mn, C, P, N, S, Cr, Cu, Co, As, Sb, Se, Hg, Tc, and U. Redox-active humic substances and mineral surfaces can catalyze the redox transformation and degradation of organic contaminants. In this review article, we highlight recent advances in our understanding of biogeochemical redox processes and their impact on contaminant fate and transport, including future research needs. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19950048882&hterms=solar+radiation&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D60%26Ntt%3Dsolar%2Bradiation','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19950048882&hterms=solar+radiation&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D60%26Ntt%3Dsolar%2Bradiation">Solar radiation, phytoplankton pigments and the radiant heating of the equatorial Pacific warm pool</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Siegel, David A.; Ohlmann, J. Carter; Washburn, Libe; Bidigare, Robert R.; Nosse, Craig T.; Fields, Erik; Zhou, Yimei 1995-01-01 Recent optical, physical, and biological oceanographic observations are used to assess the magnitude and variability of the penetrating flux of solar radiation through the mixed layer of the warm water pool (WWP) of the western equatorial Pacific Ocean. Typical values for the penetrative solar flux at the climatological mean mixed layer depth for the WWP (30 m) are approx. 23 W/sq m and are a large fraction of the climatological mean net air-sea heat flux (approx. 40 W/sq m). The penetrating solar flux can vary significantly on synoptic timescales. Following a sustained westerly wind burst in situ solar fluxes were reduced in response to a near tripling of mixed layer phytoplankton pigment concentrations. This results in a reduction in the penetrative flux at depth (5.6 W/sq m at 30 m) and corresponds to a biogeochemically mediated increase in the mixed layer radiant heating rate of 0.13 C per month. These observations demonstrate a significant role of biogeochemical processes on WWP thermal climate. We speculate that this biogeochemically mediated feedback process may play an important role in enhancing the rate at which the WWP climate system returns to normal conditions following a westerly wind burst event. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1713446N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1713446N">FRAM (FRontiers in Arctic marine Monitoring: The FRAM Ocean Observing System) planned efforts for integrated water column biogeochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Nielsdóttir, Maria; Salter, Ian; Kanzow, Torsten; Boetius, Antje 2015-04-01 The Arctic is a region undergoing rapid environmental change and will be subject to multiple stressors in the coming decades. Reductions in sea ice concentration; warming, increased terrigenous inputs and Atlantification are all expected to exert a significant impact on the structure and function of Arctic ecosystems. The Fram Strait is a particularly important region because it acts as a gateway in the exchange of Atlantic and Arctic water masses. The logistical constraints in conducting year round biogeochemical measurements in such areas impose a significant limitation to our understanding of these complicated ecosystems. To address these important challenges the German ministry of research has funded a multi-million Euro infrastructure project (FRAM). Over the next five years FRAM will develop a remote access and autonomous sampling infrastructure to improve the temporal and spatial resolution of biogeochemical measurements in the Fram Strait and central Arctic. Here we present a summary of sampling strategies, technological innovations and biogeochemical parameters that will be addressed over the duration of the project. Specific emphasis will be placed on platforms for monitoring nutrient dynamics, carbonate chemistry, organic carbon flux and the development of a sustained microbial observatory. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1096601','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1096601">Innovative Water Management Technology to Reduce Environmental Impacts of Produced Water</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Castle, James; Rodgers, John; Alley, Bethany 2013-05-15 Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobicmore » biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or ?footprint? of a full-size CWTS for a given inflow rate of produced water.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1097078','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1097078">Innovative Water Management Technology to Reduce Environment Impacts of Produced Water</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Castle, James W.; Rodgers, John H.; Alley, Bethany 2013-08-08 Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobicmore » biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or footprint of a full-size CWTS for a given inflow rate of produced water.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1097079','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1097079">Innovative Water Management Technology to Reduce Environment Impacts of Produced Water</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Castle, James; Rodgers, John; Alley, Bethany 2013-05-15 Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobicmore » biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or footprint of a full-size CWTS for a given inflow rate of produced water.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28716941','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28716941">Cryptic oxygen cycling in anoxic marine zones.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Garcia-Robledo, Emilio; Padilla, Cory C; Aldunate, Montserrat; Stewart, Frank J; Ulloa, Osvaldo; Paulmier, Aurélien; Gregori, Gerald; Revsbech, Niels Peter 2017-08-01 Oxygen availability drives changes in microbial diversity and biogeochemical cycling between the aerobic surface layer and the anaerobic core in nitrite-rich anoxic marine zones (AMZs), which constitute huge oxygen-depleted regions in the tropical oceans. The current paradigm is that primary production and nitrification within the oxic surface layer fuel anaerobic processes in the anoxic core of AMZs, where 30-50% of global marine nitrogen loss takes place. Here we demonstrate that oxygenic photosynthesis in the secondary chlorophyll maximum (SCM) releases significant amounts of O 2 to the otherwise anoxic environment. The SCM, commonly found within AMZs, was dominated by the picocyanobacteria Prochlorococcus spp. Free O 2 levels in this layer were, however, undetectable by conventional techniques, reflecting a tight coupling between O 2 production and consumption by aerobic processes under apparent anoxic conditions. Transcriptomic analysis of the microbial community in the seemingly anoxic SCM revealed the enhanced expression of genes for aerobic processes, such as nitrite oxidation. The rates of gross O 2 production and carbon fixation in the SCM were found to be similar to those reported for nitrite oxidation, as well as for anaerobic dissimilatory nitrate reduction and sulfate reduction, suggesting a significant effect of local oxygenic photosynthesis on Pacific AMZ biogeochemical cycling. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3575751','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3575751">SULFATE REDUCTION IN GROUNDWATER: CHARACTERIZATION AND APPLICATIONS FOR REMEDIATION</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Miao, Z.; Brusseau, M. L.; Carroll, K. C.; Carreón-Diazconti, C.; Johnson, B. 2013-01-01 Sulfate is ubiquitous in groundwater, with both natural and anthropogenic sources. Sulfate reduction reactions play a significant role in mediating redox conditions and biogeochemical processes for subsurface systems. They also serve as the basis for innovative in-situ methods for groundwater remediation. An overview of sulfate reduction in subsurface environments is provided, along with a brief discussion of characterization methods and applications for addressing acid mine drainage. We then focus on two innovative, in-situ methods for remediating sulfate-contaminated groundwater, the use of zero-valent iron (ZVI) and the addition of electron-donor substrates. The advantages and limitations associated with the methods are discussed, with examples of prior applications. PMID:21947714 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B41H0156H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B41H0156H">A Description of an Acidophilic, Iron Reducer, Geobacter sp. FeAm09 Isolated from Tropical Soils</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Healy, O.; Souchek, J.; Heithoff, A.; LaMere, B.; Pan, D.; Hollis, G.; Yang, W. H.; Silver, W. L.; Weber, K. A. 2014-12-01 Iron (Fe) is the fourth most abundant element in the Earth's crust and plays a significant role controlling the geochemistry in soils, sediments, and aquatic systems. As part of a study to understand microbially-catalysed iron biogeochemical cycling in tropical soils, an iron reducing isolate, strain FeAm09, was obtained. Strain FeAm09 was isolated from acidic, Fe-rich soils collected from a tropical forest (Luquillo Experimental Forest, Puerto Rico). Strain FeAm09 is a rod-shaped, motile, Gram-negative bacterium. Taxonomic analysis of the near complete 16S rRNA gene sequence revealed that strain FeAm09 is 94.7% similar to Geobacter lovleyi, placing it in the genus Geobacter within the Family Geobacteraceae in the Deltaproteobacteria. Characterization of the optimal growth conditions revealed that strain FeAm09 is a moderate acidophile with an optimal growth pH of 5.0. The optimal growth temperature was 37°C. Growth of FeAm09 was coupled to the reduction of soluble Fe(III), Fe(III)-NTA, with H2, fumarate, ethanol, and various organic acids and sugars serving as the electron donor. Insoluble Fe(III), in the form of synthetic ferrihydrite, was reduced by strain FeAm09 using acetate or H2 as the electron donor. The use of H2 as an electron donor in the presence of CO2 and absence of organic carbon and assimilation of 14C-labelled CO2 into biomass indicate that strain FeAm09 is an autotrophic Fe(III)-reducing bacterium. Together, these data describe the first acidophilic, autotrophic Geobacter species. Iron reducing bacteria were previously shown to be as abundant in tropical soils as in saturated sediments (lake-bottoms) and saturated soils (wetlands) where Fe(III) reduction is more commonly recognized as a dominant mode of microbial respiration. Furthermore, Fe(III) reduction was identified as a primary driver of carbon mineralization in these tropical soils (Dubinsky et al. 2010). In addition to mineralizing organic carbon, Geobacter sp. FeAm09 is likely to also play an indirect role in carbon cycling by consuming H2 promoting microbial carbon fermentation in iron-rich tropical soils. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19850024422','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19850024422">Phototrophic bacteria and their role in the biogeochemical sulfur cycle</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Trueper, H. G. 1985-01-01 An essential step that cannot be bypassed in the biogeochemical cycle of sulfur today is dissimilatory sulfate reduction by anaerobic bacteria. The enormous amounts of sulfides produced by these are oxidized again either anaerobically by phototrophic bacteria or aerobically by thiobacilli and large chemotrophic bacteria (Beggiatoa, Thiovulum, etc.). Phototrophic bacteria use sulfide, sulfur, thiosulfate, and sulfite as electron donors for photosynthesis. The most obvious intermediate in their oxidative sulfur metabolism is a long chain polysulfide that appears as so called sulfur globules either inside (Chromatiaceae) or outside (Ectothiorhodospiraceae, Chlorobiaceae, and some of the Rhodospirillaceae) the cells. The assimilation of sulfur compounds in phototrophic bacteria is in principle identical with that of nonphototrophic bacteria. However, the Chlorobiaceae and some of the Chromatiaceae and Rhodospirillaceae, unable to reduce sulfate, rely upon reduced sulfur for biosynthetic purposes. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28769951','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28769951">Biogeochemical and Ecomorphological Niche Segregation of Mediterranean Woody Species along a Local Gradient.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> de la Riva, Enrique G; Marañón, Teodoro; Violle, Cyrille; Villar, Rafael; Pérez-Ramos, Ignacio M 2017-01-01 According with niche theory the species are specialized in different ecological niches, being able to coexist as result of a differential use of resources. In this context, the biogeochemical niche hypothesis proposes that species have an optimal elemental composition which results from the link between the chemical and morphological traits for the optimum plant functioning. Thus, and attending to the limiting similarity concept, different elemental composition and plant structure among co-occurring species may reduce competition, promoting different functional niches. Different functional habits associated with leaf life-span or growth forms are associated with different strategies for resource uptake, which could promote niche partitioning. In the present study, based on the biogeochemical niche concept and the use of resources in different proportions, we have focused on leaf traits (morphological and chemical) associated with resource uptake, and explored the niche partitioning among functional habits: leaf life-span (deciduous, evergreen, and semideciduous) and growth (tree, shrub, and arborescent-shrub). To this end, we have quantified the hypervolume of the leaf functional trait space (both structure and chemical composition) in a sample of 45 Mediterranean woody species from Sierra Morena Mountains (Spain) growing along a local soil resource gradient. Our results show consistent variation in functional space for woody communities distributed along the environmental gradient. Thus, communities dominated by deciduous trees with faster growth and a predominant acquisitive strategy were characteristic of bottom forests and showed highest leaf biogeochemical space. While semideciduous shrubs and evergreen (arborescent, trees) species, characterized by a conservative strategy, dominated ridge forests and showed smaller functional space. In addition, within each topographical zone or environment type, the foliar biogeochemical niche partitioning would underlie the species ability to coexist by diverging on leaf nutrient composition and resource uptake. Lower niche overlap among functional habits were found, which support that different growth forms and leaf life-habits may facilitate the coexistence of the woody species and niche partitioning along and within the gradient. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008AGUFM.B52A..01A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008AGUFM.B52A..01A">Incorporating microbes into large-scale biogeochemical models</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Allison, S. D.; Martiny, J. B. 2008-12-01 Micro-organisms, including Bacteria, Archaea, and Fungi, control major processes throughout the Earth system. Recent advances in microbial ecology and microbiology have revealed an astounding level of genetic and metabolic diversity in microbial communities. However, a framework for interpreting the meaning of this diversity has lagged behind the initial discoveries. Microbial communities have yet to be included explicitly in any major biogeochemical models in terrestrial ecosystems, and have only recently broken into ocean models. Although simplification of microbial communities is essential in complex systems, omission of community parameters may seriously compromise model predictions of biogeochemical processes. Two key questions arise from this tradeoff: 1) When and where must microbial community parameters be included in biogeochemical models? 2) If microbial communities are important, how should they be simplified, aggregated, and parameterized in models? To address these questions, we conducted a meta-analysis to determine if microbial communities are sensitive to four environmental disturbances that are associated with global change. In all cases, we found that community composition changed significantly following disturbance. However, the implications for ecosystem function were unclear in most of the published studies. Therefore, we developed a simple model framework to illustrate the situations in which microbial community changes would affect rates of biogeochemical processes. We found that these scenarios could be quite common, but powerful predictive models cannot be developed without much more information on the functions and disturbance responses of microbial taxa. Small-scale models that explicitly incorporate microbial communities also suggest that process rates strongly depend on microbial interactions and disturbance responses. The challenge is to scale up these models to make predictions at the ecosystem and global scales based on measurable parameters. We argue that meeting this challenge will require a coordinated effort to develop a series of nested models at scales ranging from the micron to the globe in order to optimize the tradeoff between model realism and feasibility. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.4710S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.4710S">Constructing wetlands: measuring and modeling feedbacks of oxidation processes between plants and clay-rich material</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Saaltink, Rémon; Dekker, Stefan C.; Griffioen, Jasper; Wassen, Martin J. 2016-04-01 Interest is growing in using soft sediment as a building material in eco-engineering projects. Wetland construction in the Dutch lake Markermeer is an example: here the option of dredging some of the clay-rich lake-bed sediment and using it to construct 10.000 ha of wetland will soon go under construction. Natural processes will be utilized during and after construction to accelerate ecosystem development. Knowing that plants can eco-engineer their environment via positive or negative biogeochemical plant-soil feedbacks, we conducted a six-month greenhouse experiment to identify the key biogeochemical processes in the mud when Phragmites australis is used as an eco-engineering species. We applied inverse biogeochemical modeling to link observed changes in pore water composition to biogeochemical processes. Two months after transplantation we observed reduced plant growth and shriveling as well as yellowing of foliage. The N:P ratios of plant tissue were low and were affected not by hampered uptake of N but by enhanced uptake of P. Plant analyses revealed high Fe concentrations in the leaves and roots. Sulfate concentrations rose drastically in our experiment due to pyrite oxidation; as reduction of sulfate will decouple Fe-P in reducing conditions, we argue that plant-induced iron toxicity hampered plant growth, forming a negative feedback loop, while simultaneously there was a positive feedback loop, as iron toxicity promotes P mobilization as a result of reduced conditions through root death, thereby stimulating plant growth and regeneration. Given these two feedback mechanisms, we propose that when building wetlands from these mud deposits Fe-tolerant species are used rather than species that thrive in N-limited conditions. The results presented in this study demonstrate the importance of studying the biogeochemical properties of the building material and the feedback mechanisms between plant and soil prior to finalizing the design of the eco-engineering project. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014GeCoA.142..166M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014GeCoA.142..166M">Competing retention pathways of uranium upon reaction with Fe(II)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Massey, Michael S.; Lezama-Pacheco, Juan S.; Jones, Morris E.; Ilton, Eugene S.; Cerrato, José M.; Bargar, John R.; Fendorf, Scott 2014-10-01 Biogeochemical retention processes, including adsorption, reductive precipitation, and incorporation into host minerals, are important in contaminant transport, remediation, and geologic deposition of uranium. Recent work has shown that U can become incorporated into iron (hydr)oxide minerals, with a key pathway arising from Fe(II)-induced transformation of ferrihydrite, (Fe(OH)3·nH2O) to goethite (α-FeO(OH)); this is a possible U retention mechanism in soils and sediments. Several key questions, however, remain unanswered regarding U incorporation into iron (hydr)oxides and this pathway's contribution to U retention, including: (i) the competitiveness of U incorporation versus reduction to U(IV) and subsequent precipitation of UO2; (ii) the oxidation state of incorporated U; (iii) the effects of uranyl aqueous speciation on U incorporation; and, (iv) the mechanism of U incorporation. Here we use a series of batch reactions conducted at pH ∼7, [U(VI)] from 1 to 170 μM, [Fe(II)] from 0 to 3 mM, and [Ca] at 0 or 4 mM coupled with spectroscopic examination of reaction products of Fe(II)-induced ferrihydrite transformation to address these outstanding questions. Uranium retention pathways were identified and quantified using extended X-ray absorption fine structure (EXAFS) spectroscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. Analysis of EXAFS spectra showed that 14-89% of total U was incorporated into goethite, upon reaction with Fe(II) and ferrihydrite. Uranium incorporation was a particularly dominant retention pathway at U concentrations ⩽50 μM when either uranyl-carbonato or calcium-uranyl-carbonato complexes were dominant, accounting for 64-89% of total U. With increasing U(VI) and Fe(II) concentrations, U(VI) reduction to U(IV) became more prevalent, but U incorporation remained a functioning retention pathway. These findings highlight the potential importance of U(V) incorporation within iron oxides as a retention process of U across a wide range of biogeochemical environments and the sensitivity of uranium retention processes to operative (bio)geochemical conditions. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_3");'>3</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li class="active">5</li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_6" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li class="active">6</li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="101"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1167628-competing-retention-pathways-uranium-upon-reaction-fe-ii','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1167628-competing-retention-pathways-uranium-upon-reaction-fe-ii">Competing retention pathways of uranium upon reaction with Fe(II)</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Massey, Michael S.; Lezama Pacheco, Juan S.; Jones, Morris Biogeochemical retention processes, including adsorption, reductive precipitation, and incorporation into host minerals, are important in contaminant transport, remediation, and geologic deposition of uranium. Recent work has shown that U can become incorporated into iron (hydr)oxide minerals, with a key pathway arising from Fe(II)-induced transformation of ferrihydrite, (Fe(OH)3•nH2O) to goethite (α-FeO(OH)); this is a possible U retention mechanism in soils and sediments. Several key questions, however, remain unanswered regarding U incorporation into iron (hydr)oxides and this pathway’s contribution to U retention, including: (i) the competitiveness of U incorporation versus reduction to U(IV) and subsequent precipitation of UO2; (ii) the oxidation statemore » of incorporated U; (iii) the effects of uranyl aqueous speciation on U incorporation; and, (iv) the mechanism of U incorporation. Here we use a series of batch reactions conducted at pH ~7, [U(VI)] from 1 to 170 μM, [Fe(II)] from 0 to 3 mM, and [Ca] at 0 or 4 mM) coupled with spectroscopic examination of reaction products of Fe(II)-induced ferrihydrite transformation to address these outstanding questions. Uranium retention pathways were identified and quantified using extended x-ray absorption fine structure (EXAFS) spectroscopy, x-ray powder diffraction, x-ray photoelectron spectroscopy, and transmission electron microscopy. Analysis of EXAFS spectra showed that 14 to 89% of total U was incorporated into goethite, upon reaction with Fe(II) and ferrihydrite. Uranium incorporation was a particularly dominant retention pathway at U concentrations ≤ 50 μM when either uranyl-carbonato or calcium-uranyl-carbonato complexes were dominant, accounting for 64 to 89% of total U. With increasing U(VI) and Fe(II) concentrations, U(VI) reduction to U(IV) became more prevalent, but U incorporation remained a functioning retention pathway. These findings highlight the potential importance of U(V) incorporation within iron oxides as a retention process of U across a wide range of biogeochemical environments and the sensitivity of uranium retention processes to operative (bio)geochemical conditions.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005JPhy4.125...31S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005JPhy4.125...31S">Application of the photoacoustic method to the measurement of acetylene reduction by nitrogenase enzyme</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Schramm, D. U.; Sthel, M. S.; Carneiro, L. O.; Franco, A. A.; Campos, A. C.; Vargas, H. 2005-06-01 Nitrogenase is an enzyme responsible for the reduction of the atmospheric N2 into NH4^+, which represents the key entry point of the molecular nitrogen into the biogeochemical cycle of nitrogen. This enzyme is present in the rhizobial bacteroids, which are symbionts in a Leguminosae plant (Acacia Holosericea), and also reduces acetylene into ethylene at the same rate as the nitrogen reduction. Therefore, a CO2 Laser Photoacoustic system was used for detecting and monitoring the ethylene emission by the nitrogenase activity, in the rhizobial symbionts in Acacia Holosericea, when they are confined in test tubes with acetylene at two different volumes (0.1 and 0.5 ml). Ethylene concentrations are also determined in the ppm range. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AREPS..42..249B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AREPS..42..249B">Mercury Isotopes in Earth and Environmental Sciences</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Blum, Joel D.; Sherman, Laura S.; Johnson, Marcus W. 2014-05-01 Virtually all biotic, dark abiotic, and photochemical transformations of mercury (Hg) produce Hg isotope fractionation, which can be either mass dependent (MDF) or mass independent (MIF). The largest range in MDF is observed among geological materials and rainfall impacted by anthropogenic sources. The largest positive MIF of Hg isotopes (odd-mass excess) is caused by photochemical degradation of methylmercury in water. This signature is retained through the food web and measured in all freshwater and marine fish. The largest negative MIF of Hg isotopes (odd-mass deficit) is caused by photochemical reduction of inorganic Hg and has been observed in Arctic snow and plant foliage. Ratios of MDF to MIF and ratios of 199Hg MIF to 201Hg MIF are often diagnostic of biogeochemical reaction pathways. More than a decade of research demonstrates that Hg isotopes can be used to trace sources, biogeochemical cycling, and reactions involving Hg in the environment. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70019713','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70019713">Short-term effects of salinity reduction and drainage on salt-marsh biogeochemical cycling and Spartina (Cordgrass) production</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Portnoy, J.W.; Valiela, I. 1997-01-01 To assess the biogeochemical effects of tidal restrictions on salt-marsh sulfur cycling and plant growth, cores of short-form Spartina alterniflora peat were desalinated and kept either waterlogged or drained in greenhouse microcosms. Changes in net Spartina production, and porewater and solid phase chemistry of treated cores were compared to natural conditions in the field collection site over a 21-mo period. Net production among treatments increased significantly in drained and waterlogged peat compared to field conditions during the first growing season. Constantly high sulfide in waterlogged cores accompanied reduced plant growth. Aeration invigorated growth in drained cores but led to oxidization of sulfide minerals and to lowered pH. During the second growing season, growth declined in the drained treatment, probably because of acidification and decreased dissolved inorganic nitrogen. Results are pertinent to the success of current wetland protection and restoration activities in the coastal zone. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4055836','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4055836">Enhanced role of eddies in the Arctic marine biological pump</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Watanabe, Eiji; Onodera, Jonaotaro; Harada, Naomi; Honda, Makio C.; Kimoto, Katsunori; Kikuchi, Takashi; Nishino, Shigeto; Matsuno, Kohei; Yamaguchi, Atsushi; Ishida, Akio; Kishi, Michio J. 2014-01-01 The future conditions of Arctic sea ice and marine ecosystems are of interest not only to climate scientists, but also to economic and governmental bodies. However, the lack of widespread, year-long biogeochemical observations remains an obstacle to understanding the complicated variability of the Arctic marine biological pump. Here we show an early winter maximum of sinking biogenic flux in the western Arctic Ocean and illustrate the importance of shelf-break eddies to biological pumping from wide shelves to adjacent deep basins using a combination of year-long mooring observations and three-dimensional numerical modelling. The sinking flux trapped in the present study included considerable fresh organic material with soft tissues and was an order of magnitude larger than previous estimates. We predict that further reductions in sea ice will promote the entry of Pacific-origin biological species into the Arctic basin and accelerate biogeochemical cycles connecting the Arctic and subarctic oceans. PMID:24862402 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24746891','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24746891">Managing urban nutrient biogeochemistry for sustainable urbanization.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lin, Tao; Gibson, Valerie; Cui, Shenghui; Yu, Chang-Ping; Chen, Shaohua; Ye, Zhilong; Zhu, Yong-Guan 2014-09-01 Urban ecosystems are unique in the sense that human activities are the major drivers of biogeochemical processes. Along with the demographic movement into cities, nutrients flow towards the urban zone (nutrient urbanization), causing the degradation of environmental quality and ecosystem health. In this paper, we summarize the characteristics of nutrient cycling within the urban ecosystem compared to natural ecosystems. The dynamic process of nutrient urbanization is then explored taking Xiamen city, China, as an example to examine the influence of rapid urbanization on food sourced nitrogen and phosphorus metabolism. Subsequently, the concept of a nutrient footprint and calculation method is introduced from a lifecycle perspective. Finally, we propose three system approaches to mend the broken biogeochemical cycling. Our study will contribute to a holistic solution which achieves synergies between environmental quality and food security, by integrating technologies for nutrient recovery and waste reduction. Copyright © 2014 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28472587','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28472587">Sea Level Rise Induced Arsenic Release from Historically Contaminated Coastal Soils.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> LeMonte, Joshua J; Stuckey, Jason W; Sanchez, Joshua Z; Tappero, Ryan; Rinklebe, Jörg; Sparks, Donald L 2017-06-06 Climate change-induced perturbations in the hydrologic regime are expected to impact biogeochemical processes, including contaminant mobility and cycling. Elevated levels of geogenic and anthropogenic arsenic are found along many coasts around the world, most notably in south and southeast Asia but also in the United States, particularly along the Mid-Atlantic coast. The mechanism by and the extent to which arsenic may be released in contaminated coastal soils due to sea level rise are unknown. Here we show a series of data from a coastal arsenic-contaminated soil exposed to sea and river waters in biogeochemical microcosm reactors across field-validated redox conditions. We find that reducing conditions lead to arsenic release from historically contaminated coastal soils through reductive dissolution of arsenic-bearing mineral oxides in both sea and river water inundations, with less arsenic release from seawater scenarios than river water due to inhibition of oxide dissolution. For the first time, we systematically display gradation of solid phase soil-arsenic speciation across defined redox windows from reducing to oxidizing conditions in natural waters by combining biogeochemical microcosm experiments and X-ray absorption spectroscopy. Our results demonstrate the threat of sea level rise stands to impact arsenic release from contaminated coastal soils by changing redox conditions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1434765-sea-level-rise-induced-arsenic-release-from-historically-contaminated-coastal-soils','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1434765-sea-level-rise-induced-arsenic-release-from-historically-contaminated-coastal-soils">Sea Level Rise Induced Arsenic Release from Historically Contaminated Coastal Soils</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> LeMonte, Joshua J.; Stuckey, Jason W.; Sanchez, Joshua Z.; ... 2017-05-04 Climate change-induced perturbations in the hydrologic regime are expected to impact biogeochemical processes, including contaminant mobility and cycling. Elevated levels of geogenic and anthropogenic arsenic are found along many coasts around the world, most notably in south and southeast Asia but also in the United States, particularly along the Mid-Atlantic coast. The mechanism by and the extent to which arsenic may be released in contaminated coastal soils due to sea level rise are unknown. Here we show a series of data from a coastal arsenic-contaminated soil exposed to sea and river waters in biogeochemical microcosm reactors across field-validated redox conditions.more » We find that reducing conditions lead to arsenic release from historically contaminated coastal soils through reductive dissolution of arsenic-bearing mineral oxides in both sea and river water inundations, with less arsenic release from seawater scenarios than river water due to inhibition of oxide dissolution. For the first time, we systematically display gradation of solid phase soil-arsenic speciation across defined redox windows from reducing to oxidizing conditions in natural waters by combining biogeochemical microcosm experiments and X-ray absorption spectroscopy. Here, our results demonstrate the threat of sea level rise stands to impact arsenic release from contaminated coastal soils by changing redox conditions.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1434765','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1434765">Sea Level Rise Induced Arsenic Release from Historically Contaminated Coastal Soils</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> LeMonte, Joshua J.; Stuckey, Jason W.; Sanchez, Joshua Z. Climate change-induced perturbations in the hydrologic regime are expected to impact biogeochemical processes, including contaminant mobility and cycling. Elevated levels of geogenic and anthropogenic arsenic are found along many coasts around the world, most notably in south and southeast Asia but also in the United States, particularly along the Mid-Atlantic coast. The mechanism by and the extent to which arsenic may be released in contaminated coastal soils due to sea level rise are unknown. Here we show a series of data from a coastal arsenic-contaminated soil exposed to sea and river waters in biogeochemical microcosm reactors across field-validated redox conditions.more » We find that reducing conditions lead to arsenic release from historically contaminated coastal soils through reductive dissolution of arsenic-bearing mineral oxides in both sea and river water inundations, with less arsenic release from seawater scenarios than river water due to inhibition of oxide dissolution. For the first time, we systematically display gradation of solid phase soil-arsenic speciation across defined redox windows from reducing to oxidizing conditions in natural waters by combining biogeochemical microcosm experiments and X-ray absorption spectroscopy. Here, our results demonstrate the threat of sea level rise stands to impact arsenic release from contaminated coastal soils by changing redox conditions.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70023111','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70023111">Characterizing multiple timescales of stream and storage zone interaction that affect solute fate and transport in streams</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Choi, Jungyill; Harvey, Judson W.; Conklin, Martha H. 2000-01-01 The fate of contaminants in streams and rivers is affected by exchange and biogeochemical transformation in slowly moving or stagnant flow zones that interact with rapid flow in the main channel. In a typical stream, there are multiple types of slowly moving flow zones in which exchange and transformation occur, such as stagnant or recirculating surface water as well as subsurface hyporheic zones. However, most investigators use transport models with just a single storage zone in their modeling studies, which assumes that the effects of multiple storage zones can be lumped together. Our study addressed the following question: Can a single‐storage zone model reliably characterize the effects of physical retention and biogeochemical reactions in multiple storage zones? We extended an existing stream transport model with a single storage zone to include a second storage zone. With the extended model we generated 500 data sets representing transport of nonreactive and reactive solutes in stream systems that have two different types of storage zones with variable hydrologic conditions. The one storage zone model was tested by optimizing the lumped storage parameters to achieve a best fit for each of the generated data sets. Multiple storage processes were categorized as possessing I, additive; II, competitive; or III, dominant storage zone characteristics. The classification was based on the goodness of fit of generated data sets, the degree of similarity in mean retention time of the two storage zones, and the relative distributions of exchange flux and storage capacity between the two storage zones. For most cases (>90%) the one storage zone model described either the effect of the sum of multiple storage processes (category I) or the dominant storage process (category III). Failure of the one storage zone model occurred mainly for category II, that is, when one of the storage zones had a much longer mean retention time (ts ratio > 5.0) and when the dominance of storage capacity and exchange flux occurred in different storage zones. We also used the one storage zone model to estimate a “single” lumped rate constant representing the net removal of a solute by biogeochemical reactions in multiple storage zones. For most cases the lumped rate constant that was optimized by one storage zone modeling estimated the flux‐weighted rate constant for multiple storage zones. Our results explain how the relative hydrologic properties of multiple storage zones (retention time, storage capacity, exchange flux, and biogeochemical reaction rate constant) affect the reliability of lumped parameters determined by a one storage zone transport model. We conclude that stream transport models with a single storage compartment will in most cases reliably characterize the dominant physical processes of solute retention and biogeochemical reactions in streams with multiple storage zones. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28117550','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28117550">Abundant carbon substrates drive extremely high sulfate reduction rates and methane fluxes in Prairie Pothole Wetlands.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Dalcin Martins, Paula; Hoyt, David W; Bansal, Sheel; Mills, Christopher T; Tfaily, Malak; Tangen, Brian A; Finocchiaro, Raymond G; Johnston, Michael D; McAdams, Brandon C; Solensky, Matthew J; Smith, Garrett J; Chin, Yu-Ping; Wilkins, Michael J 2017-08-01 Inland waters are increasingly recognized as critical sites of methane emissions to the atmosphere, but the biogeochemical reactions driving such fluxes are less well understood. The Prairie Pothole Region (PPR) of North America is one of the largest wetland complexes in the world, containing millions of small, shallow wetlands. The sediment pore waters of PPR wetlands contain some of the highest concentrations of dissolved organic carbon (DOC) and sulfur species ever recorded in terrestrial aquatic environments. Using a suite of geochemical and microbiological analyses, we measured the impact of sedimentary carbon and sulfur transformations in these wetlands on methane fluxes to the atmosphere. This research represents the first study of coupled geochemistry and microbiology within the PPR and demonstrates how the conversion of abundant labile DOC pools into methane results in some of the highest fluxes of this greenhouse gas to the atmosphere ever reported. Abundant DOC and sulfate additionally supported some of the highest sulfate reduction rates ever measured in terrestrial aquatic environments, which we infer to account for a large fraction of carbon mineralization in this system. Methane accumulations in zones of active sulfate reduction may be due to either the transport of free methane gas from deeper locations or the co-occurrence of methanogenesis and sulfate reduction. If both respiratory processes are concurrent, any competitive inhibition of methanogenesis by sulfate-reducing bacteria may be lessened by the presence of large labile DOC pools that yield noncompetitive substrates such as methanol. Our results reveal some of the underlying mechanisms that make PPR wetlands biogeochemical hotspots, which ultimately leads to their critical, but poorly recognized role in regional greenhouse gas emissions. © 2017 John Wiley & Sons Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1406680-abundant-carbon-substrates-drive-extremely-high-sulfate-reduction-rates-methane-fluxes-prairie-pothole-wetlands','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1406680-abundant-carbon-substrates-drive-extremely-high-sulfate-reduction-rates-methane-fluxes-prairie-pothole-wetlands">Abundant carbon substrates drive extremely high sulfate reduction rates and methane fluxes in Prairie Pothole Wetlands</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Dalcin Martins, Paula; Hoyt, David W.; Bansal, Sheel Inland waters are increasingly recognized as critical sites of methane emissions to the atmosphere, but the biogeochemical reactions driving such fluxes are less well understood. The Prairie Pothole Region (PPR) of North America is one of the largest wetland complexes in the world, containing millions of small, shallow wetlands. The sediment pore waters of PPR wetlands contain some of the highest concentrations of dissolved organic carbon (DOC) and sulfur species ever recorded in terrestrial aquatic environments. Using a suite of geochemical and microbiological analyses we measured the impact of sedimentary carbon and sulfur transformations in these wetlands on methane fluxesmore » to the atmosphere. This research represents the first study of coupled geochemistry and microbiology within the PPR, and demonstrates how the conversion of abundant labile DOC pools into methane results in some of the highest fluxes of this greenhouse gas to the atmosphere ever reported. Abundant DOC and sulfate additionally supported some of the highest sulfate reduction rates ever measured in terrestrial aquatic environments, which we infer to account for a large fraction of carbon mineralization in this system. Methane accumulations in zones of active sulfate reduction may be due to either the transport of free methane gas from deeper locations, or the co-occurrence of methanogenesis and sulfate reduction. If both respiratory processes are concurrent, any competitive inhibition of methanogenesis by sulfate-reducing bacteria may be lessened by the presence of large labile DOC pools that yield non-competitive substrates such as methanol. Our results reveal some of the underlying mechanisms that make PPR wetlands biogeochemical hotspots, which ultimately leads to their critical, but poorly recognized role in regional greenhouse gas emissions.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70190163','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70190163">Abundant carbon substrates drive extremely high sulfate reduction rates and methane fluxes in Prairie Pothole Wetlands</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Martins, Paula; Hoyt, David W.; Bansal, Sheel; Mills, Christopher T.; Tfaily, Malak; Tangen, Brian; Finocchiaro, Raymond; Johnston, Michael D.; McAdams, Brandon C.; Solensky, Matthew J.; Smith, Garrett J.; Chin, Yu-Ping; Wilkins, Michael J. 2017-01-01 Inland waters are increasingly recognized as critical sites of methane emissions to the atmosphere, but the biogeochemical reactions driving such fluxes are less well understood. The Prairie Pothole Region (PPR) of North America is one of the largest wetland complexes in the world, containing millions of small, shallow wetlands. The sediment pore waters of PPR wetlands contain some of the highest concentrations of dissolved organic carbon (DOC) and sulfur species ever recorded in terrestrial aquatic environments. Using a suite of geochemical and microbiological analyses, we measured the impact of sedimentary carbon and sulfur transformations in these wetlands on methane fluxes to the atmosphere. This research represents the first study of coupled geochemistry and microbiology within the PPR and demonstrates how the conversion of abundant labile DOC pools into methane results in some of the highest fluxes of this greenhouse gas to the atmosphere ever reported. Abundant DOC and sulfate additionally supported some of the highest sulfate reduction rates ever measured in terrestrial aquatic environments, which we infer to account for a large fraction of carbon mineralization in this system. Methane accumulations in zones of active sulfate reduction may be due to either the transport of free methane gas from deeper locations or the co-occurrence of methanogenesis and sulfate reduction. If both respiratory processes are concurrent, any competitive inhibition of methanogenesis by sulfate-reducing bacteria may be lessened by the presence of large labile DOC pools that yield noncompetitive substrates such as methanol. Our results reveal some of the underlying mechanisms that make PPR wetlands biogeochemical hotspots, which ultimately leads to their critical, but poorly recognized role in regional greenhouse gas emissions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUSM.H25A..01P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUSM.H25A..01P">Impact of Hydrologic Variability on Ecosystem Dynamics and the Sustainable Use of Soil and Water Resources</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Porporato, A. M. 2013-05-01 We discuss the key processes by which hydrologic variability affects the probabilistic structure of soil moisture dynamics in water-controlled ecosystems. These in turn impact biogeochemical cycling and ecosystem structure through plant productivity and biodiversity as well as nitrogen availability and soil conditions. Once the long-term probabilistic structure of these processes is quantified, the results become useful to understand the impact of climatic changes and human activities on ecosystem services, and can be used to find optimal strategies of water and soil resources management under unpredictable hydro-climatic fluctuations. Particular applications regard soil salinization, phytoremediation and optimal stochastic irrigation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.2113L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.2113L">Nutrient transports in the Baltic Sea - results from a 30-year physical-biogeochemical reanalysis</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Liu, Ye; Meier, H. E. Markus; Eilola, Kari 2017-04-01 Long-term oxygen and nutrient transports in the Baltic Sea are reconstructed using the Swedish Coastal and Ocean Biogeochemical model (SCOBI) coupled to the Rossby Centre Ocean model (RCO). Two simulations with and without data assimilation covering the period 1970-1999 are carried out. Here, the <q>weakly coupled</q> scheme with the Ensemble Optimal Interpolation (EnOI) method is adopted to assimilate observed profiles in the reanalysis system. The reanalysis shows considerable improvement in the simulation of both oxygen and nutrient concentrations relative to the free run. Further, the results suggest that the assimilation of biogeochemical observations has a significant effect on the simulation of the oxygen-dependent dynamics of biogeochemical cycles. From the reanalysis, nutrient transports between sub-basins, between the coastal zone and the open sea, and across latitudinal and longitudinal cross sections are calculated. Further, the spatial distributions of regions with nutrient import or export are examined. Our results emphasize the important role of the Baltic proper for the entire Baltic Sea, with large net transport (export minus import) of nutrients from the Baltic proper into the surrounding sub-basins (except the net phosphorus import from the Gulf of Riga and the net nitrogen import from the Gulf of Riga and Danish Straits). In agreement with previous studies, we found that the Bothnian Sea imports large amounts of phosphorus from the Baltic proper that are retained in this sub-basin. For the calculation of sub-basin budgets, the location of the lateral borders of the sub-basins is crucial, because net transports may change sign with the location of the border. Although the overall transport patterns resemble the results of previous studies, our calculated estimates differ in detail considerably. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22555750','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22555750">Enrichment of arsenic transforming and resistant heterotrophic bacteria from sediments of two salt lakes in Northern Chile.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lara, José; Escudero González, Lorena; Ferrero, Marcela; Chong Díaz, Guillermo; Pedrós-Alió, Carlos; Demergasso, Cecilia 2012-05-01 Microbial populations are involved in the arsenic biogeochemical cycle in catalyzing arsenic transformations and playing indirect roles. To investigate which ecotypes among the diverse microbial communities could have a role in cycling arsenic in salt lakes in Northern Chile and to obtain clues to facilitate their isolation in pure culture, sediment samples from Salar de Ascotán and Salar de Atacama were cultured in diluted LB medium amended with NaCl and arsenic, at different incubation conditions. The samples and the cultures were analyzed by nucleic acid extraction, fingerprinting analysis, and sequencing. Microbial reduction of As was evidenced in all the enrichments carried out in anaerobiosis. The results revealed that the incubation factors were more important for determining the microbial community structure than arsenic species and concentrations. The predominant microorganisms in enrichments from both sediments belonged to the Firmicutes and Proteobacteria phyla, but most of the bacterial ecotypes were confined to only one system. The occurrence of an active arsenic biogeochemical cycle was suggested in the system with the highest arsenic content that included populations compatible with microorganisms able to transform arsenic for energy conservation, accumulate arsenic, produce H(2), H(2)S and acetic acid (potential sources of electrons for arsenic reduction) and tolerate high arsenic levels. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1328276-critical-biogeochemical-functions-subsurface-associated-bacteria-from-new-phyla-little-studied-lineages','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1328276-critical-biogeochemical-functions-subsurface-associated-bacteria-from-new-phyla-little-studied-lineages">Critical biogeochemical functions in the subsurface are associated with bacteria from new phyla and little studied lineages</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Hug, Laura A.; Thomas, Brian C.; Sharon, Itai; ... 2015-07-22 Nitrogen, sulfur and carbon fluxes in the terrestrial subsurface are determined by the intersecting activities of microbial community members, yet the organisms responsible are largely unknown. Metagenomic methods can identify organisms and functions, but genome recovery is often precluded by data complexity. To address this limitation, we developed subsampling assembly methods to re-construct high-quality draft genomes from complex samples. Here, we applied these methods to evaluate the interlinked roles of the most abundant organisms in biogeochemical cycling in the aquifer sediment. Community proteomics confirmed these activities. The eight most abundant organisms belong to novel lineages, and two represent phyla withmore » no previously sequenced genome. Four organisms are predicted to fix carbon via the Calvin Benson Bassham, Wood Ljungdahl or 3-hydroxyproprionate/4-hydroxybutarate pathways. The profiled organisms are involved in the network of denitrification, dissimilatory nitrate reduction to ammonia, ammonia oxidation and sulfate reduction/oxidation, and require substrates supplied by other community members. An ammonium-oxidizing Thaumarchaeote is the most abundant community member, despite low ammonium concentrations in the groundwater. Finally, this organism likely benefits from two other relatively abundant organisms capable of producing ammonium from nitrate, which is abundant in the groundwater. Overall, dominant members of the microbial community are interconnected through exchange of geochemical resources.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5547588','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5547588">Cryptic oxygen cycling in anoxic marine zones</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Padilla, Cory C.; Stewart, Frank J.; Ulloa, Osvaldo; Paulmier, Aurélien; Gregori, Gerald; Revsbech, Niels Peter 2017-01-01 Oxygen availability drives changes in microbial diversity and biogeochemical cycling between the aerobic surface layer and the anaerobic core in nitrite-rich anoxic marine zones (AMZs), which constitute huge oxygen-depleted regions in the tropical oceans. The current paradigm is that primary production and nitrification within the oxic surface layer fuel anaerobic processes in the anoxic core of AMZs, where 30–50% of global marine nitrogen loss takes place. Here we demonstrate that oxygenic photosynthesis in the secondary chlorophyll maximum (SCM) releases significant amounts of O2 to the otherwise anoxic environment. The SCM, commonly found within AMZs, was dominated by the picocyanobacteria Prochlorococcus spp. Free O2 levels in this layer were, however, undetectable by conventional techniques, reflecting a tight coupling between O2 production and consumption by aerobic processes under apparent anoxic conditions. Transcriptomic analysis of the microbial community in the seemingly anoxic SCM revealed the enhanced expression of genes for aerobic processes, such as nitrite oxidation. The rates of gross O2 production and carbon fixation in the SCM were found to be similar to those reported for nitrite oxidation, as well as for anaerobic dissimilatory nitrate reduction and sulfate reduction, suggesting a significant effect of local oxygenic photosynthesis on Pacific AMZ biogeochemical cycling. PMID:28716941 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014GeCoA.136..247L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014GeCoA.136..247L">Fe(II)- and sulfide-facilitated reduction of 99Tc(VII)O4- in microbially reduced hyporheic zone sediments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lee, Ji-Hoon; Zachara, John M.; Fredrickson, James K.; Heald, Steve M.; McKinley, James P.; Plymale, Andrew E.; Resch, Charles T.; Moore, Dean A. 2014-07-01 Redox-reactive, biogeochemical phases generated by reductive microbial activity in hyporheic zone sediments from a dynamic groundwater-river interaction zone were evaluated for their ability to reduce soluble pertechnetate [99Tc(VII)O4-] to less soluble Tc(IV). The sediments were bioreduced by indigenous microorganisms that were stimulated by organic substrate addition in synthetic groundwater with or without sulfate. In most treatments, 20 μmol L-1 initial aqueous Tc(VII) was reduced to near or below detection (3.82 × 10-9 mol L-1) over periods of days to months in suspensions of variable solids concentrations. Native sediments containing significant lithogenic Fe(II) in various phases were, in contrast, unreactive with Tc(VII). The reduction rates in the bioreduced sediments increased with increases in sediment mass, in proportion to weak acid-extractable Fe(II) and sediment-associated sulfide (AVS). The rate of Tc(VII) reduction was first order with respect to both aqueous Tc(VII) concentration and sediment mass, but correlations between specific reductant concentrations and reaction rate were not found. X-ray microprobe measurements revealed a strong correlation between Tc hot spots and Fe-containing mineral particles in the sediment. However, only a portion of Fe-containing particles were Tc-hosts. The Tc-hot spots displayed a chemical signature (by EDXRF) similar to pyroxene. The application of autoradiography and electron microprobe allowed further isolation of Tc-containing particles that were invariably found to be ca 100 μm aggregates of primary mineral material embedded within a fine-grained phyllosilicate matrix. EXAFS spectroscopy revealed that the Tc(IV) within these were a combination of a Tc(IV)O2-like phase and Tc(IV)-Fe surface clusters, with a significant fraction of a TcSx-like phase in sediments incubated with SO42-. AVS was implicated as a more selective reductant at low solids concentration even though its concentration was below that required for stoichiometric reduction of Tc(VII). These results demonstrate that composite mineral aggregates may be redox reaction centers in coarse-textured hyporheic zone sediments regardless of the dominant anoxic biogeochemical processes. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1172449-fe-ii-sulfide-facilitated-reduction-vii-o4-microbially-reduced-hyporheic-zone-sediments','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1172449-fe-ii-sulfide-facilitated-reduction-vii-o4-microbially-reduced-hyporheic-zone-sediments">Fe(II)- and Sulfide-Facilitated Reduction of 99Tc(VII)O4- in Microbially Reduced Hyporheic Zone Sediments</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Lee, Ji-Hoon; Zachara, John M.; Fredrickson, Jim K. Redox-reactive, biogeochemical phases generated by reductive microbial activity in hyporheic zone sediments from a dynamic groundwater-river interaction zone were evaluated for their ability to reduce soluble pertechnetate [99Tc(VII)O4-] to less soluble Tc(IV). The sediments were bioreduced by indigenous microorganisms that were stimulated by organic substrate addition in synthetic groundwater with or without sulfate. In most treatments, 20 µmol L-1 initial aqueous Tc(VII) was reduced to near or below detection (3.82×10-9 mol L-1) over periods of days to months in suspensions of variable solids concentrations. Native sediments containing significant lithogenic Fe(II) in various phases were, in contrast, unreactive with Tc(VII). Themore » reduction rates in the bioreduced sediments increased with increases in sediment mass, in proportion to weak acid-extractable Fe(II) and sediment-associated sulfide (AVS). The rate of Tc(VII) reduction was first order with respect to both aqueous Tc(VII) concentration and sediment mass, but correlations between specific reductant concentrations and reaction rate were not found. X-ray microprobe measurements revealed a strong correlation between Tc hot spots and Fe-containing mineral particles in the sediment. However, only a portion of Fe-containing particles were Tc-hosts. The Tc-hot spots displayed a chemical signature (by EDXRF) similar to pyroxene. The application of autoradiography and electron microprobe allowed further isolation of Tc-containing particles that were invariably found to be ca 100 µm aggregates of primary mineral material embedded within a fine-grained phyllosilicate matrix. EXAFS spectroscopy revealed that the Tc(IV) within these were a combination of a Tc(IV)O2-like phase and Tc(IV)-Fe surface clusters, with a significant fraction of a TcSx-like phase in sediments incubated with SO42-. AVS was implicated as a more selective reductant at low solids concentration even though its concentration was below that required for stoichiometric reduction of Tc(VII). These results demonstrate that composite mineral aggregates may be redox reaction centers in coarse-textured hyporheic zone sediments regardless of the dominant anoxic biogeochemical processes.« less </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_4");'>4</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li class="active">6</li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_7" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li class="active">7</li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="121"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3809095','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3809095">Enhanced biogeochemical cycling and subsequent reduction of hydraulic conductivity associated with soil-layer interfaces in the vadose zone</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Hansen, David J.; McGuire, Jennifer T.; Mohanty, Binayak P. 2013-01-01 Biogeochemical dynamics in the vadose zone are poorly understood due to the transient nature of chemical and hydrologic conditions, but are nonetheless critical to understanding chemical fate and transport. This study explored the effects of a soil layer on linked geochemical, hydrological, and microbiological processes. Three laboratory soil columns were constructed: a homogenized medium-grained sand, a homogenized organic-rich loam, and a sand-over-loam layered column. Upward and downward infiltration of water was evaluated during experiments to simulate rising water table and rainfall events respectively. In-situ collocated probes measured soil water content, matric potential, and Eh while water samples collected from the same locations were analyzed for Br−, Cl−, NO3−, SO42−, NH4+, Fe2+, and total sulfide. Compared to homogenous columns, the presence of a soil layer altered the biogeochemistry and water flow of the system considerably. Enhanced biogeochemical cycling was observed in the layered column over the texturally homogeneous soil columns. Enumerations of iron and sulfate reducing bacteria showed 1-2 orders of magnitude greater community numbers in the layered column. Mineral and soil aggregate composites were most abundant near the soil-layer interface; the presence of which, likely contributed to an observed order-of-magnitude decrease in hydraulic conductivity. These findings show that quantifying coupled hydrologic-biogeochemical processes occurring at small-scale soil interfaces is critical to accurately describing and predicting chemical changes at the larger system scale. Findings also provide justification for considering soil layering in contaminant fate and transport models because of its potential to increase biodegradation and/or slow the rate of transport of contaminants. PMID:22031578 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMOS23B2007A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMOS23B2007A">Authigenic Carbonate Formation on the Peru Margin; New Insights from IODP Site 1230</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Abdullajintakam, S.; Naehr, T. H. 2015-12-01 Fluid seepage of reduced organic compounds such as methane impacts the geology and biology of the seabed by inducing complex, microbially mediated biogeochemical processes. Authigenic carbonates serve as one of the few permanent records of these of dynamic biogeochemical interactions that involve methanogenesis, methanotrophy, sulfate reduction and carbonate precipitation. Meister et al. (2007) investigated deep-sea dolomite formation at Sites 1227-1229 on the Peru margin, where dolomite precipitation occurs in association with organic carbon-rich continental margin sediments. Geochemical and petrographic studies indicated episodic dolomite precipitation at a dynamic sulfate methane transition zone (SMTZ). Variations in δ13C values of these dolomites between +15‰ and -15‰ were attributed to non-steady state conditions as a result of the upward and downward migration of the SMTZ. Our study aims to better understand the biogeochemical processes associated with authigenic carbonate precipitation in this dynamic deep-sea setting. We focused our efforts on IODP Site 1230, which is a gas-hydrate-bearing site that shows sulphate consumption within the uppermost 10 m below the seafloor as well as high methane production. Using a multi proxy approach, we combined X-ray diffraction, stable isotope geochemistry, and trace metal analysis of authigenic carbonates to elucidate conditions for authigenic carbonate formation. Results from Site 1230 are compared to Sites 1227 and 1229, which lacks gas hydrates and is characterized by high pore water sulfate and low methane concentrations. This study contributes to a more comprehensive understanding of authigenic carbonate formation and associated biogeochemical processes in continental margin sediments. Meister, P., Mckenzie, J. A., Vasconcelos, C., Bernasconi, S., Frank, M., Gutjhar, M. and SCHRAG, D. P. (2007), Dolomite formation in the dynamic deep biosphere: results from the Peru Margin. Sedimentology, 54: 1007-1032. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.H13F1458C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.H13F1458C">Microfluidic Experiments Studying Pore Scale Interactions of Microbes and Geochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chen, M.; Kocar, B. D. 2016-12-01 Understanding how physical phenomena, chemical reactions, and microbial behavior interact at the pore-scale is crucial to understanding larger scale trends in groundwater chemistry. Recent studies illustrate the utility of microfluidic devices for illuminating pore-scale physical-biogeochemical processes and their control(s) on the cycling of iron, uranium, and other important elements 1-3. These experimental systems are ideal for examining geochemical reactions mediated by microbes, which include processes governed by complex biological phenomenon (e.g. biofilm formation, etc.)4. We present results of microfluidic experiments using a model metal reducing bacteria and varying pore geometries, exploring the limitations of the microorganisms' ability to access tight pore spaces, and examining coupled biogeochemical-physical controls on the cycling of redox sensitive metals. Experimental results will provide an enhanced understanding of coupled physical-biogeochemical processes transpiring at the pore-scale, and will constrain and compliment continuum models used to predict and describe the subsurface cycling of redox-sensitive elements5. 1. Vrionis, H. A. et al. Microbiological and geochemical heterogeneity in an in situ uranium bioremediation field site. Appl. Environ. Microbiol. 71, 6308-6318 (2005). 2. Pearce, C. I. et al. Pore-scale characterization of biogeochemical controls on iron and uranium speciation under flow conditions. Environ. Sci. Technol. 46, 7992-8000 (2012). 3. Zhang, C., Liu, C. & Shi, Z. Micromodel investigation of transport effect on the kinetics of reductive dissolution of hematite. Environ. Sci. Technol. 47, 4131-4139 (2013). 4. Ginn, T. R. et al. Processes in microbial transport in the natural subsurface. Adv. Water Resour. 25, 1017-1042 (2002). 5. Scheibe, T. D. et al. Coupling a genome-scale metabolic model with a reactive transport model to describe in situ uranium bioremediation. Microb. Biotechnol. 2, 274-286 (2009). </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010PrOce..86..302L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010PrOce..86..302L">Preliminary forecasts of Pacific bigeye tuna population trends under the A2 IPCC scenario</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lehodey, P.; Senina, I.; Sibert, J.; Bopp, L.; Calmettes, B.; Hampton, J.; Murtugudde, R. 2010-07-01 An improved version of the spatial ecosystem and population dynamics model SEAPODYM was used to investigate the potential impacts of global warming on tuna populations. The model included an enhanced definition of habitat indices, movements, and accessibility of tuna predators to different vertically migrant and non-migrant micronekton functional groups. The simulations covered the Pacific basin (model domain) at a 2° × 2° geographic resolution. The structure of the model allows an evaluation from multiple data sources, and parameterization can be optimized by adjoint techniques and maximum likelihood using fishing data. A first such optimized parameterization was obtained for bigeye tuna ( Thunnus obesus) in the Pacific Ocean using historical catch data for the last 50 years and a hindcast from a coupled physical-biogeochemical model driven by the NCEP atmospheric reanalysis. The parameterization provided very plausible biological parameter values and a good fit to fishing data from the different fisheries, both within and outside the time period used for optimization. We then employed this model to forecast the future of bigeye tuna populations in the Pacific Ocean. The simulation was driven by the physical-biogeochemical fields predicted from a global marine biogeochemistry - climate simulation. This global simulation was performed with the IPSL climate model version 4 (IPSL-CM4) coupled to the oceanic biogeochemical model PISCES and forced by atmospheric CO 2, from historical records over 1860-2000, and under the SRES A2 IPCC scenario for the 21st century (i.e. atmospheric CO 2 concentration reaching 850 ppm in the year 2100). Potential future changes in distribution and abundance under the IPCC scenario are presented but without taking into account any fishing effort. The simulation showed an improvement in bigeye tuna spawning habitat both in subtropical latitudes and in the eastern tropical Pacific (ETP) where the surface temperature becomes optimal for bigeye tuna spawning. The adult feeding habitat also improved in the ETP due to the increase of dissolved oxygen concentration in the sub-surface allowing adults to access deeper forage. Conversely, in the Western Central Pacific the temperature becomes too warm for bigeye tuna spawning. The decrease in spawning is compensated by an increase of larvae biomass in subtropical regions. However, natural mortality of older stages increased due to lower habitat values (too warm surface temperatures, decreasing oxygen concentration in the sub-surface and less food). This increased mortality and the displacement of surviving fish to the eastern region led to stable then declining adult biomass at the end of the century. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS43B2057M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS43B2057M">Understanding the recent changes in the Southern Ocean carbon cycle: A multidisciplinary approach</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Manizza, M.; Kahru, M.; Menemenlis, D.; Nevison, C. D.; Mitchell, B. G.; Keeling, R. F. 2016-12-01 The Southern Ocean represents a key area of the global ocean for the uptake of the CO2 originating from fossil fuels emissions. In these waters, cold temperatures combined with high rates of biological production drive the carbon uptake that accounts for about one-third of the global ocean uptake.Recent studies showed that changes in the Southern Annular Mode (SAM) index, mainly a proxy of the intensity of westerly winds, had a significant impact on the temporal variability of the CO2 uptake in the Southern Ocean. In order to shed light on this problem we propose to use both satellite-derived estimates of ocean productivity and carbon export in combinations of ocean physical and biogeochemical state estimates focusing on the 2006-2013 period. While the estimates of carbon fixation and export based on remote sensing will provide key information on the spatial and temporal variations of the biological carbon pump, the ocean state estimates will provide additional information on physical and carbon cycle processes, including the air-sea CO2 fluxes of the Southern Ocean in the 2006-2013 period where model solutions have been optimized.These physical estimates will be used to force an ocean biogeochemical model (ECCO2-Darwin) that will compute the CO2 uptake for each year. The physical model, forced with optimized atmospheric forcing, aims to realistically simulate interannual ocean climate variability that drives changes in both physical and biogeochemical processes ultimately impacting the carbon uptake of the Southern Ocean, and potentially responding to the SAM index variations.Although in this study great emphasis is given to the role of physical climate variations at driving the CO2 uptake of these polar waters, we will integrate model results with estimates from remote sensing techniques to better understand role of the biological carbon pump and its variability potentially responding to the SAM index changes. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29775934','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29775934">Arsenic speciation dynamics in paddy rice soil-water environment: sources, physico-chemical, and biological factors - A review.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kumarathilaka, Prasanna; Seneweera, Saman; Meharg, Andrew; Bundschuh, Jochen 2018-04-21 Rice is the main staple carbohydrate source for billions of people worldwide. Natural geogenic and anthropogenic sources has led to high arsenic (As) concentrations in rice grains. This is because As is highly bioavailable to rice roots under conditions in which rice is cultivated. A multifaceted and interdisciplinary understanding, both of short-term and long-term effects, are required to identify spatial and temporal changes in As contamination levels in paddy soil-water systems. During flooding, soil pore waters are elevated in inorganic As compared to dryland cultivation systems, as anaerobism results in poorly mobile As(V), being reduced to highly mobile As(III). The formation of iron (Fe) plaque on roots, availability of metal (hydro)oxides (Fe and Mn), organic matter, clay mineralogy and competing ions and compounds (PO 4 3- and Si(OH) 4 ) are all known to influence As(V) and As(III) mobility in paddy soil-water environments. Microorganisms play a key role in As transformation through oxidation/reduction, and methylation/volatilization reactions, but transformation kinetics are poorly understood. Scientific-based optimization of all biogeochemical parameters may help to significantly reduce the bioavailability of inorganic As. Copyright © 2018 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3714343','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3714343">Nitrogenase Reduction of Carbon-Containing Compounds</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Seefeldt, Lance C.; Yang, Zhi-Yong; Duval, Simon; Dean, Dennis R. 2013-01-01 Nitrogenase is an enzyme found in many bacteria and archaea that catalyzes biological dinitrogen fixation, the reduction of N2 to NH3, accounting for the major input of fixed nitrogen into the biogeochemical N cycle. In addition to reducing N2 and protons, nitrogenase can reduce a number of small, non-physiological substrates. Among these alternative substrates are included a wide array of carbon containing compounds. These compounds have provided unique insights into aspects of the nitrogenase mechanism. Recently, it was shown that carbon monoxide (CO) and carbon dioxide (CO2) can also be reduced by nitrogenase to yield hydrocarbons, opening new insights into the mechanism of small molecule activation and reduction by this complex enzyme as well as providing clues for the design of novel molecular catalysts. PMID:23597875 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2814439','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2814439">Mechanism of Mo-Dependent Nitrogenase</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Seefeldt, Lance C.; Hoffman, Brian M.; Dean, Dennis R. 2010-01-01 Nitrogen-fixing bacteria catalyze the reduction of dinitrogen (N2) to two ammonia molecules (NH3), the major contribution of fixed nitrogen into the biogeochemical nitrogen cycle. The most widely studied nitrogenase is the Mo-dependent enzyme. The reduction of N2 by this enzyme involves the transient interaction of two component proteins, designated the Fe protein and the MoFe protein, and minimally requires sixteen MgATP, eight protons, and eight electrons. The current state of knowledge on how these proteins and small molecules together effect the reduction of N2 to ammonia is reviewed. Included is a summary of the roles of the Fe protein and MgATP hydrolysis, information on the roles of the two metal clusters contained in the MoFe protein in catalysis, insights gained from recent success in trapping substrates and inhibitors at the active site metal cluster FeMo-cofactor, and finally, considerations of the mechanism of N2 reduction catalyzed by nitrogenase. PMID:19489731 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5290482','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5290482">The reduction in the biomass of cyanobacterial N2 fixer and the biological pump in the Northwestern Pacific Ocean</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Kim, Dongseon; Jeong, Jin-Hyun; Kim, Tae-Wook; Noh, Jae Hoon; Kim, Hyung Jeek; Choi, Dong Han; Kim, Eung; Jeon, Dongchull 2017-01-01 The comparison of sediment trap data with physical and biogeochemical variables in the surface water column of the Tropical Northwestern Pacific Ocean (TNWPO) indicated that the magnitude of the springtime biological pump has reduced with time due to a corresponding decrease in the biomass of cyanobacterial N2 fixer. The decrease in the biomass of N2 fixer likely resulted from a reduction in phosphate concentrations in response to surface water warming and consequent shoaling of the mixed layer depth during the study period (2009−2014). The same reduction in biological pump was also observed during summer. However, the cause of the summer reduction remains uncertain and is worth assessing in future studies. Our findings have major implications for predicting future trends of the biological pump in the TNWPO, where significant warming has occurred. PMID:28155909 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSMM43A..03C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSMM43A..03C">A Prochlorococcus proving ground for constraint-based metabolic modeling and multi-`omics data integration</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Casey, J.; Ji, B.; Shaoie, S.; Mardinoglu, A.; Sarathi Sen, P.; Jahn, O.; Reda, K.; Leigh, J.; Follows, M. J.; Nielsen, J.; Karl, D. M. 2016-02-01 Representatives of the oligotrophic marine cyanobacterium Prochlorococcus marinus are the smallest free-living photosynthetic organisms, both in terms of physical size and genome size, yet are the most abundant photoautotrophic microbes in the oceans and profoundly influence global biogeochemical cycles. Physiological and regulatory control of nutrient and light stress has been observed in MED4 in culture and in its closely related `ecotype' eMED4 in the field, however its metabolism has not been investigated in detail. We present a genome-scale metabolic network reconstruction of the high-light adapted axenic strain MED4ax ("iJCMED4") for the quantitative analysis of a range of its metabolic phenotypes. The resulting structure is a proving ground for the incorporation of enzyme kinetics, biochemical and elemental compositional data, transcriptomic, proteomic, metabolomic, and fluxomic datasets which can be implemented within a constraint-based metabolic modeling environment. The iJCMED4 stoichiometric model consists of 523 metabolic genes encoding 787 reactions with 673 unique metabolites distributed in 5 sub-cellular compartments and is mass, charge, and thermodynamically balanced. Several variants of flux balance analysis were used to simulate growth and metabolic fluxes over the diel cycle, under various stress conditions (e.g., nitrogen, phosphorus, light), and within the framework of a global biogeochemical model (DARWIN). Model simulations accurately predicted growth rates in culture under a variety of defined medium compositions and there was close agreement of photosynthetic performance, biomass and energy yields and efficiencies, and transporter fluxes for iJCMED4 and culture experiments. In addition to a nearly optimal photosynthetic quotient and central carbon metabolism efficiency, MED4 has made dramatic alterations to redox and phosphorus metabolism across biosynthetic and intermediate pathways. We propose that reductions in phosphate reaction participation reflects the P-deplete environment where MED4 was originally isolated. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26536878','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26536878">Dehalococcoides abundance and alternate electron acceptor effects on large, flow-through trichloroethene dechlorinating columns.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Mirza, Babur S; Sorensen, Darwin L; Dupont, R Ryan; McLean, Joan E 2016-03-01 Trichloroethene (TCE) in groundwater is a major health concern and biostimulation/bioaugmentation-based strategies have been evaluated to achieve complete reductive dechlorination with varying success. Different carbon sources were hypothesized to stimulate different extents of TCE reductive dechlorination. Ecological conditions that developed different dechlorination stages were investigated by quantitating Dehalococcoides 16S rRNA (Dhc) and reductive dehalogenase gene abundance, and by describing biogeochemical properties of laboratory columns in response to this biostimulation. Eight large columns (183 cm × 15.2 cm), packed with aquifer material from Hill AFB, Utah, that were continuously fed TCE for 7.5 years. Duplicate columns were biostimulated with whey or one of two different Newman Zone® emulsified oil formulations containing either nonionic surfactant (EOLN) or standard surfactant (EOL). Two columns were non-stimulated controls. Complete (whey amended), partial (EOLN amended), limited (EOL), and non-TCE dehalogenating systems (controls) developed over the course of the study. Bioaugmentation of half of the columns with Bachman Road culture 3 years prior to dismantling did not influence the extent of TCE dehalogenation. Multivariate analysis clustered samples by biostimulation treatments and extent of TCE dehalogenation. Dhc, tceA, and bvcA gene concentrations did not show a consistent relationship with TCE dehalogenation but the vcrA gene was more abundant in completely dehalogenating, whey-treated columns. The whey columns developed strongly reducing conditions producing Fe(II), sulfide, and methane. Biostimulation with different carbon and energy sources can support high concentrations of diverse Dhc, but carbon addition has a major influence on biogeochemical processes effecting the extent of TCE dehalogenation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA580041','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA580041">Physiological and Biogeochemical Traits of Bleaching and Recovery in the Mounding Species of Coral Porites lobata: Implications for Resilience in Mounding Corals</a> <a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a> 2013-05-02 each recovery interval a suite of analyses were performed to assess their recovery (photosynthesis, respiration, chlorophyll a, energy reserves...maintained despite reductions in chlorophyll a, photosynthesis, and the assimilation of photosynthetically fixed carbon. At the same time, P. lobata corals...lobata corals immediately following bleaching and throughout 11 months of recovery: photosynthesis (P), respiration (R), chlorophyll a (Chl a), total </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H41G1522Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H41G1522Z">Optimizing the Hydrological and Biogeochemical Simulations on a Hillslope with Stony Soil</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhu, Q. 2017-12-01 Stony soils are widely distributed in the hilly area. However, traditional pedotransfer functions are not reliable in predicting the soil hydraulic parameters for these soils due to the impacts of rock fragments. Therefore, large uncertainties and errors may exist in the hillslope hydrological and biogeochemical simulations in stony soils due to poor estimations of soil hydraulic parameters. In addition, homogenous soil hydraulic parameters are usually used in traditional hillslope simulations. However, soil hydraulic parameters are spatially heterogeneous on the hillslope. This may also cause the unreliable simulations. In this study, we obtained soil hydraulic parameters using five different approaches on a tea hillslope in Taihu Lake basin, China. These five approaches included (1) Rossetta predicted and spatially homogenous, (2) Rossetta predicted and spatially heterogeneous), (3) Rossetta predicted, rock fragment corrected and spatially homogenous, (4) Rossetta predicted, rock fragment corrected and spatially heterogeneous, and (5) extracted from observed soil-water retention curves fitted by dual-pore function and spatially heterogeneous (observed). These five sets of soil hydraulic properties were then input into Hydrus-3D and DNDC to simulate the soil hydrological and biogeochemical processes. The aim of this study is testing two hypotheses. First, considering the spatial heterogeneity of soil hydraulic parameters will improve the simulations. Second, considering the impact of rock fragment on soil hydraulic parameters will improve the simulations. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JCHyd.203....9S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JCHyd.203....9S">Volume reduction outweighs biogeochemical processes in controlling phosphorus treatment in aged detention systems</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Shukla, Asmita; Shukla, Sanjay; Annable, Michael D.; Hodges, Alan W. 2017-08-01 Stormwater detention areas (SDAs) play an important role in treating end-of-the-farm runoff in phosphorous (P) limited agroecosystems. Phosphorus transport from the SDAs, including those through subsurface pathways, are not well understood. The prevailing understanding of these systems assumes that biogeochemical processes play the primary treatment role and that subsurface losses can be neglected. Water and P fluxes from a SDA located in a row-crop farm were measured for two years (2009-2011) to assess the SDA's role in reducing downstream P loads. The SDA treated 55% (497 kg) and 95% (205 kg) of the incoming load during Year 1 (Y1, 09-10) and Year 2 (Y2, 10-11), respectively. These treatment efficiencies were similar to surface water volumetric retention (49% in Y1 and 84% in Y2) and varied primarily with rainfall. Similar water volume and P retentions indicate that volume retention is the main process controlling P loads. A limited role of biogeochemical processes was supported by low to no remaining soil P adsorption capacity due to long-term drainage P input. The fact that outflow P concentrations (Y1 = 368.3 μg L- 1, Y2 = 230.4 μg L- 1) could be approximated by using a simple mixing of rainfall and drainage P input further confirmed the near inert biogeochemical processes. Subsurface P losses through groundwater were 304 kg (27% of inflow P) indicating that they are an important source for downstream P. Including subsurface P losses reduces the treatment efficiency to 35% (from 61%). The aboveground biomass in the SDA contained 42% (240 kg) of the average incoming P load suggesting that biomass harvesting could be a cost-effective alternative for reviving the role of biogeochemical processes to enhance P treatment in aged, P-saturated SDAs. The 20-year present economic value of P removal through harvesting was estimated to be 341,000, which if covered through a cost share or a payment for P treatment services program could be a positive outcome for both agriculture and public interests. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28595989','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28595989">Volume reduction outweighs biogeochemical processes in controlling phosphorus treatment in aged detention systems.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Shukla, Asmita; Shukla, Sanjay; Annable, Michael D; Hodges, Alan W 2017-08-01 Stormwater detention areas (SDAs) play an important role in treating end-of-the-farm runoff in phosphorous (P) limited agroecosystems. Phosphorus transport from the SDAs, including those through subsurface pathways, are not well understood. The prevailing understanding of these systems assumes that biogeochemical processes play the primary treatment role and that subsurface losses can be neglected. Water and P fluxes from a SDA located in a row-crop farm were measured for two years (2009-2011) to assess the SDA's role in reducing downstream P loads. The SDA treated 55% (497kg) and 95% (205kg) of the incoming load during Year 1 (Y1, 09-10) and Year 2 (Y2, 10-11), respectively. These treatment efficiencies were similar to surface water volumetric retention (49% in Y1 and 84% in Y2) and varied primarily with rainfall. Similar water volume and P retentions indicate that volume retention is the main process controlling P loads. A limited role of biogeochemical processes was supported by low to no remaining soil P adsorption capacity due to long-term drainage P input. The fact that outflow P concentrations (Y1=368.3μg L -1 , Y2=230.4μg L -1 ) could be approximated by using a simple mixing of rainfall and drainage P input further confirmed the near inert biogeochemical processes. Subsurface P losses through groundwater were 304kg (27% of inflow P) indicating that they are an important source for downstream P. Including subsurface P losses reduces the treatment efficiency to 35% (from 61%). The aboveground biomass in the SDA contained 42% (240kg) of the average incoming P load suggesting that biomass harvesting could be a cost-effective alternative for reviving the role of biogeochemical processes to enhance P treatment in aged, P-saturated SDAs. The 20-year present economic value of P removal through harvesting was estimated to be $341,000, which if covered through a cost share or a payment for P treatment services program could be a positive outcome for both agriculture and public interests. Copyright © 2017. Published by Elsevier B.V. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70189668','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70189668">Mercury bioaccumulation in estuarine fishes: Novel insights from sulfur stable isotopes</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Willacker, James J.; Eagles-Smith, Collin A.; Ackerman, Joshua T. 2017-01-01 Estuaries are transitional habitats characterized by complex biogeochemical and ecological gradients that result in substantial variation in fish total mercury concentrations (THg). We leveraged these gradients and used carbon (δ13C), nitrogen (δ15N), and sulfur (δ34S) stable isotopes to examine the ecological and biogeochemical processes underlying THg bioaccumulation in fishes from the San Francisco Bay Estuary. We employed a tiered approach that first examined processes influencing variation in fish THg among wetlands, and subsequently examined the roles of habitat and within-wetland processes in generating larger-scale patterns in fish THg. We found that δ34S, an indicator of sulfate reduction and habitat specific-foraging, was correlated with fish THg at all three spatial scales. Over the observed ranges of δ34S, THg concentrations in fish increased by up to 860% within wetlands, 560% among wetlands, and 291% within specific impounded wetland habitats. In contrast, δ13C and δ15N were not correlated with THg among wetlands and were only important in low salinity impounded wetlands, possibly reflecting more diverse food webs in this habitat. Together, our results highlight the key roles of sulfur biogeochemistry and ecology in influencing estuarine fish THg, as well as the importance of fish ecology and habitat in modulating the relationships between biogeochemical processes and Hg bioaccumulation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.H33L..04T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.H33L..04T">One multi-media environmental system with linkage between meteorology/ hydrology/ air quality models and water quality model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tang, C.; Lynch, J. A.; Dennis, R. L. 2016-12-01 The biogeochemical processing of nitrogen and associated pollutants is driven by meteorological and hydrological processes in conjunction with pollutant loading. There are feedbacks between meteorology and hydrology that will be affected by land-use change and climate change. Changes in meteorology will affect pollutant deposition. It is important to account for those feedbacks and produce internally consistent simulations of meteorology, hydrology, and pollutant loading to drive the (watershed/water quality) biogeochemical models. In this study, the ecological response to emission reductions in streams in the Potomac watershed was evaluated. Firstly, we simulated the deposition by using the fully coupled Weather Research & Forecasting (WRF) model and the Community Multiscale Air Quality (CAMQ) model; secondly, we created the hydrological data by the offline linked Variable Infiltration Capacity (VIC) model and the WRF model. Lastly, we investigated the water quality by one comprehensive/environment model, namely the linkage of CMAQ, WRF, VIC and the Model of Acidification of Groundwater In Catchment (MAGIC) model from 2002 to 2010.The simulated results (such as NO3, SO4, and SBC) fit well to the observed values. The linkage provides a generally accurate, well-tested tool for evaluating sensitivities to varying meteorology and environmental changes on acidification and other biogeochemical processes, with capability to comprehensively explore strategic policy and management design. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1390570-temporal-dynamics-co-ch-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1390570-temporal-dynamics-co-ch-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils"></a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> RoyChowdhury, Taniya; Bramer, Lisa; Hoyt, David W. Earth System Models predict climate extremes that will impact regional and global hydrology. Aquatic-terrestrial transition zones like wetlands are subjected to the immediate consequence of climate change with shifts in the magnitude and dynamics of hydrologic flow. Such fluctuating hydrology can alter the nature and rate of biogeochemical transformations and significantly impact the carbon balance of the ecosystem. We tested the impacts of fluctuating hydrology and, specifically, the role of antecedent moisture conditions in determining the dominant carbon loss mechanisms in soils sampled from a tidal freshwater wetland system in the lower Columbia River, WA, USA. The objective was tomore » understand shifts in biogeochemical processes in response to changing soil moisture, based on soil respiration and methane production rates, and to elucidate such responses based on the observed electron acceptor and metabolite profiles under laboratory conditions. Metabolomics and biogeochemical process rates provided evidence that soil redox was the principal factor driving metabolic function. Fluctuating redox conditions altered terminal electron acceptor and donor availability and recovery strengths of their concentrations in soil such that a disproportionate release of carbon dioxide stemmed from alternative anaerobic degradation processes like sulfate and iron reduction compared to carbon loss due to methanogenesis. These results show that extended and short-term saturation created conditions conducive to increasing metabolite availability for anaerobic decomposition processes, with a significant lag in methanogenesis. In contrast, extended drying caused a cellular-level stress response and rapid recycling of alternate electron acceptors.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1250473','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1250473">Final Report DE-SC0006997; PI Sharp; Coupled Biological and Micro-XAS/XRF Analysis of In Situ Uranium Biogeochemical Processes</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Sharp, Jonathan O. Project Overview: The impact of the original seed award was substantially increased by leveraging a postdoctoral fellowship (Marie Curie Postdoctoral Fellowship) and parallel funds from (A) synergistic project supported by NSF and (B) with DOE collaborators (PI’s Ranville and Williams) as well as no-cost extension that greatly increased the impact and publications associated with the project. In aligning with SBR priorities, the project’s focus was extended more broadly to explore coupled biogeochemical analysis of metal (im)mobilization processes beyond uranium with a foundation in integrating microbial ecology with geochemical analyses. This included investigations of arsenic and zinc during sulfate reducing conditionsmore » in addition to direct microbial reduction of metals. Complimentary work with NSF funding and collaborative DOE interactions further increased the project scope to investigate metal (im)mobilization coupled to biogeochemical perturbations in forest ecosystems with an emphasis on coupled carbon and metal biogeochemistry. In total, the project was highly impactful and resulted in 9 publications and directly supported salary/tuition for 3 graduate students at various stages of their academic careers as well as my promotion to Associate Professor. In going forward, findings provided inspiration for a two subsequent proposals with collaborators at Lawrence Berkeley Laboratory and others that are currently in review (as of March 2016).« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H42E..03R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H42E..03R">Structure of peat soils and implications for biogeochemical processes and hydrological flow</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Rezanezhad, F.; McCarter, C. P. R.; Gharedaghloo, B.; Kleimeier, C.; Milojevic, T.; Liu, H.; Weber, T. K. D.; Price, J. S.; Quinton, W. L.; Lenartz, B.; Van Cappellen, P. 2017-12-01 Permafrost peatlands contain globally important amounts of soil organic carbon and play major roles in global water, nutrient and biogeochemical cycles. The structure of peatland soils (i.e., peat) are highly complex with unique physical and hydraulic properties; where significant, and only partially reversible, shrinkage occurs during dewatering (including water table fluctuations), compression and/or decomposition. These distinct physical and hydraulic properties controls water flow, which in turn affect reactive and non-reactive solute transport (such as, sorption or degradation) and biogeochemical functions. Additionally, peat further attenuates solute migration through molecular diffusion into the inactive pores of Sphagnum dominated peat. These slow, diffusion-limited solute exchanges between the pore regions may give rise to pore-scale chemical gradients and heterogeneous distributions of microbial habitats and activity in peat soils. Permafrost peat plateaus have the same essential subsurface characteristics as other widely organic soil-covered peatlands, where the hydraulic conductivity is related to the degree of decomposition and soil compression. Increasing levels of decomposition correspond with a reduction of effective pore diameter and consequently restrict water and solute flow (by several orders of magnitude in hydraulic conductivity between the ground surface and a depth of 50 cm). In this presentation, we present the current knowledge of key physical and hydraulic properties related to the structure of globally available peat soils and discuss their implications for water storage, flow and the migration of solutes. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_5");'>5</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li class="active">7</li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_8" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li class="active">8</li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="141"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28088848','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28088848">Mercury Bioaccumulation in Estuarine Fishes: Novel Insights from Sulfur Stable Isotopes.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Willacker, James J; Eagles-Smith, Collin A; Ackerman, Joshua T 2017-02-21 Estuaries are transitional habitats characterized by complex biogeochemical and ecological gradients that result in substantial variation in fish total mercury concentrations (THg). We leveraged these gradients and used carbon (δ 13 C), nitrogen (δ 15 N), and sulfur (δ 34 S) stable isotopes to examine the ecological and biogeochemical processes underlying THg bioaccumulation in fishes from the San Francisco Bay Estuary. We employed a tiered approach that first examined processes influencing variation in fish THg among wetlands, and subsequently examined the roles of habitat and within-wetland processes in generating larger-scale patterns in fish THg. We found that δ 34 S, an indicator of sulfate reduction and habitat specific-foraging, was correlated with fish THg at all three spatial scales. Over the observed ranges of δ 34 S, THg concentrations in fish increased by up to 860% within wetlands, 560% among wetlands, and 291% within specific impounded wetland habitats. In contrast, δ 13 C and δ 15 N were not correlated with THg among wetlands and were only important in low salinity impounded wetlands, possibly reflecting more diverse food webs in this habitat. Together, our results highlight the key roles of sulfur biogeochemistry and ecology in influencing estuarine fish THg, as well as the importance of fish ecology and habitat in modulating the relationships between biogeochemical processes and Hg bioaccumulation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20050000404&hterms=physiology&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dphysiology','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20050000404&hterms=physiology&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D80%26Ntt%3Dphysiology">Iron and manganese in anaerobic respiration: environmental significance, physiology, and regulation</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Nealson, K. H.; Saffarini, D. 1994-01-01 Dissimilatory iron and/or manganese reduction is known to occur in several organisms, including anaerobic sulfur-reducing organisms such as Geobacter metallireducens or Desulfuromonas acetoxidans, and facultative aerobes such as Shewanella putrefaciens. These bacteria couple both carbon oxidation and growth to the reduction of these metals, and inhibitor and competition experiments suggest that Mn(IV) and Fe(III) are efficient electron acceptors similar to nitrate in redox abilities and capable of out-competing electron acceptors of lower potential, such as sulfate (sulfate reduction) or CO2 (methanogenesis). Field studies of iron and/or manganese reduction suggest that organisms with such metabolic abilities play important roles in coupling the oxidation of organic carbon to metal reduction under anaerobic conditions. Because both iron and manganese oxides are solids or colloids, they tend to settle downward in aquatic environments, providing a physical mechanism for the movement of oxidizing potential into anoxic zones. The resulting biogeochemical metal cycles have a strong impact on many other elements including carbon, sulfur, phosphorous, and trace metals. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015NatCC...5..465Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015NatCC...5..465Y">Decoupling of nitrogen and phosphorus in terrestrial plants associated with global changes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yuan, Z. Y.; Chen, Han Y. H. 2015-05-01 Living organisms maintain a balance of chemical elements for optimal growth and reproduction, which plays an important role in global biogeochemical cycles. Human domination of Earth's ecosystems has led to drastic global changes, but it is unclear how these affect the stoichiometric coupling of nutrients in terrestrial plants, the most important food source on Earth. Here we use meta-analyses of 1,418 published studies to show that the ratio of terrestrial plant nitrogen (N) to phosphorus (P) decreases with elevated concentrations of CO2, increasing rainfall, and P fertilization, but increases with warming, drought, and N fertilization. Our analyses also reveal that multiple global change treatments generally result in overall additive effects of single-factor treatments and that the responses of plant nutrients and their stoichiometry are similar in direction, but often greater in controlled than in natural environments. Our results suggest a decoupling of the P biogeochemical cycle from N in terrestrial plants under global changes, which in turn may diminish the provision of ecosystem services. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B31B0419P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B31B0419P">Exploring the controls of soil biogeochemistry in a restored coastal wetland using object-oriented computer simulations of uptake kinetics and thermodynamic optimization in batch reactors</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Payn, R. A.; Helton, A. M.; Poole, G.; Izurieta, C.; Bernhardt, E. S.; Burgin, A. J. 2012-12-01 Many hypotheses have been proposed to predict patterns of biogeochemical redox reactions based on the availability of electron donors and acceptors and the thermodynamic theory of chemistry. Our objective was to develop a computer model that would allow us to test various alternatives of these hypotheses against data gathered from soil slurry batch reactors, experimental soil perfusion cores, and in situ soil profile observations from the restored Timberlake Wetland in coastal North Carolina, USA. Software requirements to meet this objective included the ability to rapidly develop and compare different hypothetical formulations of kinetic and thermodynamic theory, and the ability to easily change the list of potential biogeochemical reactions used in the optimization scheme. For future work, we also required an object pattern that could easily be coupled with an existing soil hydrologic model. These requirements were met using Network Exchange Objects (NEO), our recently developed object-oriented distributed modeling framework that facilitates simulations of multiple interacting currencies moving through network-based systems. An initial implementation of the object pattern was developed in NEO based on maximizing growth of the microbial community from available dissolved organic carbon. We then used this implementation to build a modeling system for comparing results across multiple simulated batch reactors with varied initial solute concentrations, varied biogeochemical parameters, or varied optimization schemes. Among heterotrophic aerobic and anaerobic reactions, we have found that this model reasonably predicts the use of terminal electron acceptors in simulated batch reactors, where reactions with higher energy yields occur before reactions with lower energy yields. However, among the aerobic reactions, we have also found this model predicts dominance of chemoautotrophs (e.g., nitrifiers) when their electron donor (e.g., ammonium) is abundant, despite the fact that aerobic respiration produces a higher energy yield from the available dissolved oxygen. This suggests that incorporation of an alternative hypothesis, such as a maximum efficiency model, may be necessary to explain an observation of substantial aerobic respiration occurring in the presence of high ammonium and oxygen concentrations. We are parameterizing and testing this model based on results from batch reactor experiments that have treated soil slurries with a full factorial combination of various levels of reactive solutes found in freshwater (e.g., nitrate) and seawater (e.g., sulfate). Initial comparisons suggest that the model may need to account for the biogeochemical reactivity of iron and the potential physical influence of salt to properly describe variability in the biogeochemistry of Timberlake soils. Comparisons of these evolving models with field-derived data from soils will ultimately reveal how thermodynamic theory may be used to explain the evolution of nutrient retention and greenhouse gas emission in the Timberlake Wetland, where nutrient behavior is changing after restoration from agricultural land use and where inputs of brackish water are expected to increase due to sea level rise. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B13D0532M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B13D0532M">Plant Nitrogen Uptake in Terrestrial Biogeochemical Models</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Marti Donati, A.; Cox, P.; Smith, M. J.; Purves, D.; Sitch, S.; Jones, C. D. 2013-12-01 Most terrestrial biogeochemical models featured in the last Intergovernmental Panel on Climate Change (IPPC) Assessment Report highlight the importance of the terrestrial Carbon sequestration and feedbacks between the terrestrial Carbon cycle and the climate system. However, these models have been criticized for overestimating predicted Carbon sequestration and its potential climate feedback when calculating the rate of future climate change because they do not account for the Carbon sequestration constraints caused by nutrient limitation, particularly Nitrogen (N). This is particularly relevant considering the existence of a substantial deficit of Nitrogen for plants in most areas of the world. To date, most climate models assume that plants have access to as much Nitrogen as needed, but ignore the nutrient requirements for new vegetation growth. Determining the natural demand and acquisition for Nitrogen and its associated resource optimization is key when accounting for the Carbon sequestration constrains caused by nutrient limitation. The few climate models that include C-N dynamics have illustrated that the stimulation of plant growth over the coming century may be significantly smaller than previously predicted. However, models exhibit wide differences in their predictive accuracy and lead to widely diverging and inconsistent projections accounting for an uncertain Carbon sequestration decrease due to Nitrogen limitation ranging from 7 to 64%. This reduction in growth is partially offset by an increase in the availability of nutrients resulting from an accelerated rate of decomposition of dead plants and other organic matter that occurring with a rise in temperature. However, this offset does not counterbalance the reduced level of plant growth calculated by natural nutrient limitations. Additionally, Nitrogen limitation is also expected to become more pronounced in some ecosystems as atmospheric CO2 concentration increases; resulting in less new growth and higher atmospheric CO2 concentrations than originally expected. This study compares the differences in the predictions of alternative models of plant N uptake found in different terrestrial biogeochemical models with the predictions from a new N-uptake model developed under the Joint UK Land Environment Simulator (JULES) framework. We implement a methodology for the construction, parameterization and evaluation of N uptake models to fully decompose all the N uptake component processes in terms of their parameter uncertainty and the accuracy of their predictions with respect to different empirical data sets. Acknowledgements This work has been funded by the European Commission FP7-PEOPLE-ITN-2008 Marie Curie Action: "Greencycles II: FP7-PEOPLE-ITN-2008 Marie Curie Action: "Networks for Initial Training" </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70112916','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70112916">Airborne-biogeochemical survey test-case results</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Collins, William E.; Chang, Sheng-Huei; Raines, Gary L.; Canney, Frank C.; Ashley, Roger; Barringer, Anthony R. 1980-01-01 Airborne spectroradiometer surveys over several forest-covered sulfide bodies indicate that mineralization has affected the overlying vegetation; anomalous spectral reflectivity properties can be detected in the vegetation using appropriate remote-sensing interments and data-reduction techniques. Mineralization induces subtle changes in the shape of the chlorophyll a and b absorption spectrum between 550 and 750 nm. The observed spectral variations appear specifically to be on the wings of the broad red chlorophyll bars, centered at about 680 nm. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29710650','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29710650">Characterizing variable biogeochemical changes during the treatment of produced oilfield waste.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Hildenbrand, Zacariah L; Santos, Inês C; Liden, Tiffany; Carlton, Doug D; Varona-Torres, Emmanuel; Martin, Misty S; Reyes, Michelle L; Mulla, Safwan R; Schug, Kevin A 2018-09-01 At the forefront of the discussions about climate change and energy independence has been the process of hydraulic fracturing, which utilizes large amounts of water, proppants, and chemical additives to stimulate sequestered hydrocarbons from impermeable subsurface strata. This process also produces large amounts of heterogeneous flowback and formation waters, the subsurface disposal of which has most recently been linked to the induction of anthropogenic earthquakes. As such, the management of these waste streams has provided a newfound impetus to explore recycling alternatives to reduce the reliance on subsurface disposal and fresh water resources. However, the biogeochemical characteristics of produced oilfield waste render its recycling and reutilization for production well stimulation a substantial challenge. Here we present a comprehensive analysis of produced waste from the Eagle Ford shale region before, during, and after treatment through adjustable separation, flocculation, and disinfection technologies. The collection of bulk measurements revealed significant reductions in suspended and dissolved constituents that could otherwise preclude untreated produced water from being utilized for production well stimulation. Additionally, a significant step-wise reduction in pertinent scaling and well-fouling elements was observed, in conjunction with notable fluctuations in the microbiomes of highly variable produced waters. Collectively, these data provide insight into the efficacies of available water treatment modalities within the shale energy sector, which is currently challenged with improving the environmental stewardship of produced water management. Copyright © 2018 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009GeCoA..73.4004C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009GeCoA..73.4004C">Mineralogical and morphological constraints on the reduction of Fe(III) minerals by Geobacter sulfurreducens</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cutting, R. S.; Coker, V. S.; Fellowes, J. W.; Lloyd, J. R.; Vaughan, D. J. 2009-07-01 The biologically-mediated reduction of synthetic samples of the Fe(III)-bearing minerals hematite, goethite, lepidocrocite, feroxhyte, ford ferrihydrite, akaganeite and schwertmannite by Geobacter sulfurreducens has been investigated using microbiological techniques in conjunction with X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). This combination of approaches offers unique insights into the influence of subtle variations in the crystallinity of a given mineral on biogeochemical processes, and has highlighted the importance of (oxyhydr)oxide crystallite morphology in determining the changes occurring in a given mineral phase. Problems arising from normalising the biological Fe(III) reduction rates relative to the specific surface areas of the starting materials are also highlighted. These problems are caused primarily by particle aggregation, and compounded when using spectrophotometric assays to monitor reduction. For example, the initial rates of Fe(III) reduction observed for two synthetic feroxyhytes with different crystallinities (as shown by XRD and TEM studies) but almost identical surface areas, differ substantially. Both microbiological and high-resolution TEM studies show that hematite and goethite are susceptible to limited amounts of Fe(III) reduction, as evidenced by the accumulation of Fe(II) during incubation with G. sulfurreducens and the growth of nodular structures on crystalline goethite laths during incubation. Lepidocrocite and akaganeite readily transform into mixtures of magnetite and goethite, and XRD data indicate that the proportion of magnetite increases within the transformation products as the crystallinity of the starting material decreases. The presence of anthraquinone-2,6-disulfonate (AQDS) as an electron shuttle increases both the initial rate and longer term extent of biological Fe(III) reduction for all of the synthetic minerals examined. High-resolution XPS indicates subtle but measurable differences in the Fe(III):Fe(II) ratios at the mineral surfaces following extended incubation. For example, for a poorly crystalline schwertmannite, deconvolution of the Fe2p 3/2 peak suggests that the Fe(III):Fe(II) ratio of the near-surface regions varies from 1.0 in the starting material to 0.9 following 144 h of incubation with G.sulfurreducens, and to 0.75 following the same incubation period in the presence of 10 μM AQDS. These results have important implications for the biogeochemical cycling of iron. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2003EAEJA....12774B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2003EAEJA....12774B">Biogeochemistry of the coupled manganese-iron-sulfur cycles of intertidal surface sediments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bosselmann, K.; Boettcher, M. E.; Billerbeck, M.; Walpersdorf, E.; Debeer, D.; Brumsack, H.-J.; Huettel, M.; Joergensen, B. B. 2003-04-01 The biogeochemistry of the coupled iron-manganese-sulfur-carbon cycles was studied in temperate intertidal surface sediments of the German Wadden Sea (North Sea). Coastal sampling sites include sand, mixed and mud flats with different organic matter and metal contents and permeability reflecting different hydrodynamic regimes. The field study focusses on the influence of temperature, organic matter load, and sediment types on the dynamics of biogeochemical reactions on different time scales (season, day-night, tidal cycles). One of the main interests was related to the cycling of metals (Mn, Fe) in relation to the activity of sulfate-reducing bacteria. Pore water profiles were investigated by sediment sectioning and high resolution gel sampling techniques. Microbial sulfate reduction rates were measured using radiolabeled sulfate with the whole core incubation technique and the spatial distribution of bacterial activity was visualised by using "2D-photoemulsion-monitoring technique". The biogeochemical sulfur cycle was additionally characterised by the stable isotope ratios (S,O) of different sulfur species (e.g., SO_4, AVS, pyrite). Element transfers (metals, nutrients) across the sediment-water interface were additionally quantified by the application of benthic flux chambers. Microbial sulfate reduction was generally highest in the suboxic zone of the surface sediments indicating its potential importance for the mobilization of iron and manganese. In organic matter poor permeable sediments tidal effects additionally influence the spatial and temporal distribution of dissolved redox-sensitive metals. In organic matter-rich silty and muddy sediments, temperature controlled the microbial sulfate reduction rates. Depth-integrated sulfate reduction rates in sandy sediments were much lower and controlled by both temperature and organic matter. Formation of anoxic sediment surfaces due to local enhanced organic matter load (so-called "black spots") may create windows of an increase flux of metals, nutrients and hydrogen sulfide. Acknowledgements: The study was supported by German Science Foundation within the DFG-research group "BioGeoChemistry of the Waddensea" and Max Planck Society. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21176945','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21176945">Biogeochemical factors influencing net mercury methylation in contaminated freshwater sediments from the St. Lawrence River in Cornwall, Ontario, Canada.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Avramescu, Mary-Luyza; Yumvihoze, Emmanuel; Hintelmann, Holger; Ridal, Jeff; Fortin, Danielle; Lean, David R S 2011-02-01 The activity of various anaerobic microbes, including sulfate reducers (SRB), iron reducers (FeRP) and methanogens (MPA) has been linked to mercury methylation in aquatic systems, although the relative importance of each microbial group in the overall process is poorly understood in natural sediments. The present study focused on the biogeochemical factors (i.e. the relative importance of various groups of anaerobic microbes (FeRP, SRB, and MPA) that affect net monomethylmercury (MMHg) formation in contaminated sediments of the St. Lawrence River (SRL) near Cornwall (Zone 1), Ontario, Canada. Methylation and demethylation potentials were measured separately by using isotope-enriched mercury species ((200)Hg(2+) and MM(199)Hg(+)) in sediment microcosms treated with specific microbial inhibitors. Sediments were sampled and incubated in the dark at room temperature in an anaerobic chamber for 96h. The potential methylation rate constants (K(m)) and demethylation rates (K(d)) were found to differ significantly between microcosms. The MPA-inhibited microcosm had the highest potential methylation rate constant (0.016d(-1)), whereas the two SRB-inhibited microcosms had comparable potential methylation rate constants (0.003d(-1) and 0.002d(-1), respectively). The inhibition of methanogens stimulated net methylation by inhibiting demethylationand by stimulating methylation along with SRB activity. The inhibition of both methanogens and SRB was found to enhance the iron reduction rates but did not completely stop MMHg production. The strong positive correlation between K(m) and Sulfate Reduction Rates (SRR) and between K(d) and Methane Production Rates (MPR) supports the involvement of SRB in Hg methylation and MPA in MMHg demethylation in the sediments. In contrast, the strong negative correlation between K(d) and Iron Reduction Rates (FeRR) shows that the increase in FeRR corresponds to a decrease in demethylation, indicating that iron reduction may influence net methylation in the SLR sediments by decreasing demethylation rather than favouring methylation. Copyright Â© 2010 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ECSS..198..508V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ECSS..198..508V">Predominant terminal electron accepting processes during organic matter degradation: Spatio-temporal changes in Ashtamudi estuary, Kerala, India</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Vincent, Salom Gnana Thanga; Reshmi, R. R.; Hassan, S. Junaid; Nair, K. Deepa; Varma, Ajayakumar 2017-11-01 Anaerobic microbial communities in the anoxic zones degrade organic matter in estuarine sediments. Thermodynamic energy yield for the oxidation reactions with various electron acceptors decreases in the order of O2> NO3- > Mn4+> Fe3+> SO42- > CO2. The predominant terminal electron accepting (TEA) process has an influence on the biogeochemical cycles of nutrients as well as the production of important greenhouse gases such as nitrous oxide and methane from estuarine sediments. The research questions of this study were (1) what are the environmental factors (pH, salinity, organic carbon, sulphate, redox potential) explaining variability in TEA activities such as nitrate reduction rate (NRR), iron reduction rate (IRR), sulphate reduction rate (SRR) and methane production rate (MPR) and (2) which is the predominant TEA process during degradation of organic matter. To determine the TEA activities, sediment samples collected from 13 sampling stations of Ashtamudi estuary during monsoon 2014 and summer 2015 were incubated with sulphate depleted artificial seawater, under anaerobic conditions for 72 h, in microcosms. Spatial variations dominated temporal variations for environmental variables. Nevertheless, biogeochemical processes showed a distinct seasonal variation. Total TEA activity was higher during summer than monsoon, indicating the higher heterotrophic microbial activity favored by high temperature. Individually, SRR was the maximum during summer, while NRR, IRR and MPR were the maximum during monsoon. Sulphate reduction was observed to be the predominant electron accepting process in all sampling stations with cumulative values of 3125.79 and 4046.07 nmol cm-3 day-1 during monsoon and summer respectively. This was followed by NRR, IRR and MPR. Although thermodynamically more favorable, NRR could not predominate due to scarcity of nitrate in sediments. Nevertheless, two-fold and five-fold increase in methanogenesis and denitrification were observed respectively during monsoon in sampling stations, which cannot be ignored, owing to the importance of methane and nitrous oxide as a potent greenhouse gas. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2005AGUFM.B31A0962A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2005AGUFM.B31A0962A">Microbe-Mineral Interactions Along Biogeochemical Gradients in Bahamian Stromatolites: Key to Lithification and Preservation</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Andres, M. S.; Sumner, D. Y.; Visscher, P. T.; Swart, P. K.; Reid, R. P. 2005-12-01 Understanding on how modern stromatolites form and lithify is critical to properly interpreting the origins of ancient stromatolites and the early evolution of life. Lithification in Bahamian stromatolites is tied to specific, 20-60-micron thick horizons characterized by laterally continuous sheets of microcrystalline carbonate (aragonite). Microbial processes associated with these horizons are 1) photosynthetic production by cyanobacteria and 2) heterotrophic respiration by bacteria as well as the production of extrapolymeric substances (EPS). The aim of this study is to better understand the coupling of microstructure and microbial processes. The competing influences of photosynthetic CO2 uptake, sulfate reduction, and degradation of Ca-binding EPS influence both carbonate saturation states and the isotopic composition of dissolved inorganic carbon (DIC). In Bahamian stromatolites, photosynthesis and sulfate reduction are associated with specific microbial mat types creating distinctive chemical gradients that can be preserved in authigenic carbonate. Aragonite that precipitated within stromatolites is > 1 per mill depleted in 13C relative to aragonite precipitated in equilibrium with local seawater. These data suggest that more aragonite precipitates when and where respiration, rather than photosynthesis, influences local DIC, which is consistent with sulfate reduction promoting carbonate precipitation and calcium release during decay of exopolymeric substances. Biogeochemical gradients vary on a temporal and spatial scale as indicated by in-situ pH measurements across a the living mat. Highest pH correlates to maximum photosynthesis signal in the early afternoon while the lowest pH to that of maximum respiration just before sunrise. Corresponding carbon isotope analysis of authigenic carbonate precipitate will determine when microscale biological activity is captured in the mineral phase and potentially preserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GeCoA.205....1P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GeCoA.205....1P">Formation of carbonate pipes in the northern Okinawa Trough linked to strong sulfate exhaustion and iron supply</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Peng, Xiaotong; Guo, Zixiao; Chen, Shun; Sun, Zhilei; Xu, Hengchao; Ta, Kaiwen; Zhang, Jianchao; Zhang, Lijuan; Li, Jiwei; Du, Mengran 2017-05-01 The microbial anaerobic oxidation of methane (AOM), a key biogeochemical process that consumes substantial amounts of methane produced in seafloor sediments, can lead to the formation of carbonate deposits at or beneath the sea floor. Although Fe oxide-driven AOM has been identified in cold seep sediments, the exact mode by which it may influence the formation of carbonate deposits remains poorly understood. Here, we characterize the morphology, petrology and geochemistry of a methane-derived Fe-rich carbonate pipe in the northern Okinawa Trough (OT). We detect abundant authigenic pyrites, as well as widespread trace Fe, within microbial mat-like carbonate veins in the pipe. The in situ δ34S values of these pyrites range from -3.9 to 31.6‰ (VCDT), suggesting a strong consumption of seawater sulfate by sulfate-driven AOM at the bottom of sulfate reduction zone. The positive δ56Fe values of pyrite and notable enrichment of Fe in the OT pipe concurrently indicate that the pyrites are primarily derived from Fe oxides in deep sediments. We propose that the Fe-rich carbonate pipe formed at the bottom of sulfate reduction zone, below which Fe-driven AOM, rather than Fe-oxide reduction coupled to organic matter degradation, might be responsible for the abundantly available Fe2+ in the fluids from which pyrites precipitated. The Fe-rich carbonate pipe described in this study probably represents the first fossil example of carbonate deposits linked to Fe-driven AOM. Because Fe-rich carbonate deposits have also been found at other cold seeps worldwide, we infer that similar processes may play an essential role in biogeochemical cycling of sub-seafloor methane and Fe at continental margins. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H21A1070T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H21A1070T">Biogeochemical Modeling of In Situ U(VI) Reduction and Immobilization with Emulsified Vegetable Oil as the Electron Donor at a Field Site in Oak Ridge, Tennessee</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tang, G.; Parker, J.; Wu, W.; Schadt, C. W.; Watson, D. B.; Brooks, S. C.; Orifrc Team 2011-12-01 A comprehensive biogeochemical model was developed to quantitatively describe the coupled hydrologic, geochemical and microbiological processes that occurred following injection of emulsified vegetable oil (EVO) as the electron donor to immobilize U(VI) at the Oak Ridge Integrated Field Research Challenge site (ORIFRC) in Tennessee. The model couples the degradation of EVO, production and oxidation of long-chain fatty acids (LCFA), glycerol, hydrogen and acetate, reduction of nitrate, manganese, ferrous iron, sulfate and uranium, and methanoganesis with growth of multiple microbial groups. The model describes the evolution of geochemistry and microbial populations not only in the aqueous phase as typically observed, but also in the mineral phase and therefore enables us to evaluate the applicability of rates from the literature for field scale assessment, estimate the retention and degradation rates of EVO and LCFA, and assess the influence of the coupled processes on fate and transport of U(VI). Our results suggested that syntrophic bacteria or metal reducers might catalyze LCFA oxidation in the downstream locations when sulfate was consumed, and competition between methanogens and others for electron donors and slow growth of methanogen might contribute to the sustained reducing condition. Among the large amount of hydrologic, geochemical and microbiological parameter values, the initial biomass, and the interactions (e.g., inhibition) of the microbial functional groups, and the rate and extent of Mn and Fe oxide reduction appear as the major sources of uncertainty. Our model provides a platform to conduct numerical experiments to study these interactions, and could be useful for further iterative experimental and modeling investigations into the bioreductive immobiliztion of radionuclide and metal contaminants in the subsurface. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B11J0566B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B11J0566B">Genomic reconstruction of novel sediment phyla enlightens roles in sedimentary biogeochemical cycling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Baker, B.; Lazar, C.; Seitz, K.; Teske, A.; Hinrichs, K. U.; Dick, G. 2015-12-01 Estuaries are among the most productive habitats on the planet. Microbes in estuary sediments control the turnover of organic carbon, and the anaerobic cycling of nitrogen and sulfur. These communities are complex and primarily made up of uncultured lineages, thus little is known about how ecological and metabolic processes are partitioned in sediments. We reconstructed 82 bacterial and 24 archaeal high-quality genomes from different redox regimes (sulfate-rich, sulfate-methane transition zone, and methane-rich zones) of estuary sediments. These bacteria belong to 23 distinct groups, including uncultured candidate phyla (eg. KSB1, TA06, and KD3-62), and three newly described phyla (WOR-1, and -2, and -3). The archaea encompass 8 widespread sediment lineages including MGB-D, RC-III and IV, Z7ME43, Parvarchaeota, Lokiarchoaeta (MBG-B), SAGMEG, Bathyarchaeota (groups MCG-1, -6, -7, and -15) and previously unrecognized deeply branched phylum "Thorarchaeota". The uncultured phyla mediate essential biogeochemical processes of the estuarine environment. Z7ME43 archaea have genes for S disproportionation (S0 reduction and thiosulfate reduction and oxidation). SAGMEG appear to be strict anaerobes capable of coupling CO/H2 oxidation to either S0 or nitrite reduction and have novel RubisCO genes for carbon fixation. Thorarchaeota contain pathways for acetate production from the degradation of detrital proteins and intermediate S cycling. Furthermore, the gene content of this group revealed links in the evolutionary histories of archaea and eukaryotes. This dataset extents our knowledge of the metabolic potential of several uncultured phyla. We were able to chart the flow of carbon and nutrients through the multiple layers of bacterial processing and reveal potential ecological interactions within the communities. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.3592S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.3592S">Sedimentary sulfides in dune sands of Spiekeroog Island, southern North Sea: A biogeochemical study of sulfur isotope partitioning</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Seibert, Stephan; Schubert, Florian; Schmiedinger, Iris; Böttcher, Michael E.; Massmann, Gudrun 2017-04-01 The formation of iron sulfides in sandy sediments and the associated development of stable isotope signatures is still mechanistically not understood. In dune sands under impact of both fresh and saline water several physico-chemical gradients may develop leading to distinctly different biogeochemical zones. In the present study, a 10 m long core from a dune base at the North Eastern part of Spiekeroog Island, southern North Sea, was investigated for the elemental and stable isotope composition. The pyrite (TRIS) content was quantitatively extracted via an acidic Cr(II) distillation procedure and the stable sulfur isotope composition was determined by means of C-irmMS. The pore waters display a downcore increase in salt contents and a mixing between fresh and salt water. The accumulation of metabolites at depth indicate an increasing superimposition of mixing by microbial decomposition of dissolved organic matter with only limited net sulfate reduction. This indicates an essential open system with respect to dissolved sulfate. The sands were found to be very low in TOC, TIC, and TRIS and dominated by quartz minerals. Under the assumption that North Sea water sulfate was the only substantial sulfate source (d34S = + 21per mil), the sedimentary sulfides indicate an overall sulfur isotope discrimination upon microbial sulfate reduction between 39 and 52 per mil, which is within the range of results from other fully marine sands from the Spiekeroog area and laboratory studies with pure cultures of sulfate-reducing bacteria under low cellular sulfate reduction rates. Further investigations are on the way to understand the processes leading to the iron sulfide formation in these organic-poor substrates. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70003961','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70003961">Factors controlling nitrate fluxes in groundwater in agricultural areas</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Liao, Lixia; Green, Christopher T.; Bekins, Barbara A.; Böhlke, J.K. 2012-01-01 The impact of agricultural chemicals on groundwater quality depends on the interactions of biogeochemical and hydrologic factors. To identify key processes affecting distribution of agricultural nitrate in groundwater, a parsimonious transport model was applied at 14 sites across the U.S. Simulated vertical profiles of NO3-, N2 from denitrification, O2, Cl-, and environmental tracers of groundwater age were matched to observations by adjusting the parameters for recharge rate, unsaturated zone travel time, fractions of N and Cl- inputs leached to groundwater, O2 reduction rate, O2 threshold for denitrification, and denitrification rate. Model results revealed important interactions among biogeochemical and physical factors. Chloride fluxes decreased between the land surface and water table possibly because of Cl- exports in harvested crops (averaging 22% of land-surface Cl- inputs). Modeled zero-order rates of O2 reduction and denitrification were correlated. Denitrification rates at depth commonly exceeded overlying O2 reduction rates, likely because shallow geologic sources of reactive electron donors had been depleted. Projections indicated continued downward migration of NO3- fronts at sites with denitrification rates -1 yr-1. The steady state depth of NO3- depended to a similar degree on application rate, leaching fraction, recharge, and NO3- and O2 reaction rates. Steady state total mass in each aquifer depended primarily on the N application rate. In addition to managing application rates at land surface, efficient water use may reduce the depth and mass of N in groundwater because lower recharge was associated with lower N fraction leached. Management actions to reduce N leaching could be targeted over aquifers with high-recharge and low-denitrification rates. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018OcMod.126...13Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018OcMod.126...13Y">Insights on multivariate updates of physical and biogeochemical ocean variables using an Ensemble Kalman Filter and an idealized model of upwelling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yu, Liuqian; Fennel, Katja; Bertino, Laurent; Gharamti, Mohamad El; Thompson, Keith R. 2018-06-01 Effective data assimilation methods for incorporating observations into marine biogeochemical models are required to improve hindcasts, nowcasts and forecasts of the ocean's biogeochemical state. Recent assimilation efforts have shown that updating model physics alone can degrade biogeochemical fields while only updating biogeochemical variables may not improve a model's predictive skill when the physical fields are inaccurate. Here we systematically investigate whether multivariate updates of physical and biogeochemical model states are superior to only updating either physical or biogeochemical variables. We conducted a series of twin experiments in an idealized ocean channel that experiences wind-driven upwelling. The forecast model was forced with biased wind stress and perturbed biogeochemical model parameters compared to the model run representing the "truth". Taking advantage of the multivariate nature of the deterministic Ensemble Kalman Filter (DEnKF), we assimilated different combinations of synthetic physical (sea surface height, sea surface temperature and temperature profiles) and biogeochemical (surface chlorophyll and nitrate profiles) observations. We show that when biogeochemical and physical properties are highly correlated (e.g., thermocline and nutricline), multivariate updates of both are essential for improving model skill and can be accomplished by assimilating either physical (e.g., temperature profiles) or biogeochemical (e.g., nutrient profiles) observations. In our idealized domain, the improvement is largely due to a better representation of nutrient upwelling, which results in a more accurate nutrient input into the euphotic zone. In contrast, assimilating surface chlorophyll improves the model state only slightly, because surface chlorophyll contains little information about the vertical density structure. We also show that a degradation of the correlation between observed subsurface temperature and nutrient fields, which has been an issue in several previous assimilation studies, can be reduced by multivariate updates of physical and biogeochemical fields. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.B51C0381Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.B51C0381Y">Flow-through Column Experiments and Modeling of Microbially Mediated Cr(VI) Reduction at Hanford 100H</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yang, L.; Molins, S.; Beller, H. R.; Brodie, E. L.; Steefel, C.; Nico, P. S.; Han, R. 2010-12-01 Microbially mediated Cr(VI) reduction at the Hanford 100H area was investigated by flow-through column experiments. Three separate experiments were conducted to promote microbial activities associated with denitrification, iron and sulfate reduction, respectively. Replicate columns packed with natural sediments from the site under anaerobic environment were injected with 5mM Lactate as the electron donor and 5 μM Cr(VI) in all experiments. Sulfate and nitrate solutions were added to act as the main electron acceptors in the respective experiments, while iron columns relied on the indigenous sediment iron (and manganese) oxides as electron acceptors. Column effluent solutions were analyzed by IC and ICP-MS to monitor the microbial consumption/conversion of lactate and the associated Cr(VI) reduction. Biogeochemical reactive transport modeling was performed to gain further insights into the reaction mechanisms and Cr(VI) bioreduction rates. All experimental columns showed a reduction of the injected Cr(VI). Columns under denitrifying conditions showed the least Cr(VI) reduction at early stages (<60 days) compared to columns run under other experimental conditions, but became more active over time, and ultimately showed the most consistent Cr(VI) reduction. A strong correlation between denitrification and Cr(VI) reduction processes was observed and was in agreement with the results obtained in batch experiments with a denitrifying bacterium isolated from the Hanford site. The accumulation of nitrite does not appear to have an adverse effect on Cr(VI) reduction rates. Reactive transport simulations indicated that biomass growth completely depleted influent ammonium, and called for an additional source of N to account for the measured reduction rates. Iron columns were the least active with undetectable consumption of the injected lactate, slowest cell growth, and the smallest change in Cr(VI) concentrations during the course of the experiment. In contrast, columns under sulfate-reducing/fermentative conditions exhibited the greatest Cr(VI) reduction capacity. Two sulfate columns evolved to complete lactate fermentation with acetate and propionate produced in the column effluent after 40 days of experiments. These fermenting columns showed a complete removal of injected Cr(VI), visible precipitation of sulfide minerals, and a significant increase in effluent Fe and Mn concentrations. Reactive transport simulations suggested that direct reduction of Cr(VI) by Fe(II) and Mn(II) released from the sediment could account for the observed Cr(VI) removal. The biogeochemical modeling was employed to test two hypotheses that could explain the release of Fe(II) and Mn(II) from the column sediments: 1) acetate produced by lactate fermentation provided the substrate for the growth of iron(III) and manganese(IV) oxide reducers, and 2) direct reduction of iron(III) and manganese(IV) oxides by hydrogen sulfide generated during sulfate reduction. Overall, experimental and modeling results suggested that Cr(VI) reduction in the sulfate-reducing columns occurred through a complex network of microbial reactions that included fermentation, sulfate reduction, and possibly the stimulated iron-reducing communities. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA209572','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA209572">Characterization of Methanogen Membrane Function: A Genetic Approach</a> <a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a> 1989-06-22 strain Marburg) which has recently been found to catalyze the reduction of CH3-S-CoH with H-S- HTP (mercaptoheptanoyl-O-phospho-L-threonine) to form CH4...and CoH-S-S- HTP . The mixed disulphide is subsequently reduced to yield H-S-CoM (2-mercaptoetljanesulfonic acid) and HS- HTP (7). While all examined...membrane and lipoprotein samples: manual and automated procedures. Meth. Enzy.ZZ:296-301. 16. Mopper, K. and B.F. Taylor. 1986. Biogeochemical cycling </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_6");'>6</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li class="active">8</li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_9" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li class="active">9</li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="161"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GBioC..32..226F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GBioC..32..226F">Biogeochemical Role of Subsurface Coherent Eddies in the Ocean: Tracer Cannonballs, Hypoxic Storms, and Microbial Stewpots?</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Frenger, Ivy; Bianchi, Daniele; Stührenberg, Carolin; Oschlies, Andreas; Dunne, John; Deutsch, Curtis; Galbraith, Eric; Schütte, Florian 2018-02-01 Subsurface eddies are known features of ocean circulation, but the sparsity of observations prevents an assessment of their importance for biogeochemistry. Here we use a global eddying (0.1°) ocean-biogeochemical model to carry out a census of subsurface coherent eddies originating from eastern boundary upwelling systems (EBUS) and quantify their biogeochemical effects as they propagate westward into the subtropical gyres. While most eddies exist for a few months, moving over distances of hundreds of kilometers, a small fraction (<5%) of long-lived eddies propagates over distances greater than 1,000 km, carrying the oxygen-poor and nutrient-rich signature of EBUS into the gyre interiors. In the Pacific, transport by subsurface coherent eddies accounts for roughly 10% of the offshore transport of oxygen and nutrients in pycnocline waters. This "leakage" of subsurface waters can be a significant fraction of the transport by nutrient-rich poleward undercurrents and may contribute to the well-known reduction of productivity by eddies in EBUS. Furthermore, at the density layer of their cores, eddies decrease climatological oxygen locally by close to 10%, thereby expanding oxygen minimum zones. Finally, eddies represent low-oxygen extreme events in otherwise oxygenated waters, increasing the area of hypoxic waters by several percent and producing dramatic short-term changes that may play an important ecological role. Capturing these nonlocal effects in global climate models, which typically include noneddying oceans, would require dedicated parameterizations. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1439016-temporal-dynamics-co2-ch4-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1439016-temporal-dynamics-co2-ch4-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils">Temporal dynamics of CO 2 and CH 4 loss potentials in response to rapid hydrological shifts in tidal freshwater wetland soils</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> RoyChowdhury, Taniya; Bramer, Lisa; Hoyt, David W. tEarth System Models predict climate extremes that will impact regional and global hydrology. Aquatic-terrestrial transition zones like wetlands are subjected to the immediate consequence of climate change with shifts in the magnitude and dynamics of hydrologic flow. Such fluctuating hydrology can alterthe nature and rate of biogeochemical transformations and significantly impact the carbon balance ofthe ecosystem. We tested the impacts of fluctuating hydrology and, specifically, the role of antecedentmoisture conditions in determining the dominant carbon loss mechanisms in soils sampled from a tidalfreshwater wetland system in the lower Columbia River, WA, USA. Our objective was to understand shiftsin biogeochemical processesmore » in response to changing soil moisture, based on soil respiration and methaneproduction rates, and to elucidate such responses based on the observed electron acceptor and metaboliteprofiles under laboratory conditions. Metabolomics and biogeochemical process rates provided evidencethat soil redox was the principal factor driving metabolic function. Fluctuating redox conditions alteredterminal electron acceptor and donor availability and recovery strengths of their concentrations in soilsuch that a disproportionate release of carbon dioxide stemmed from alternative anaerobic degradationprocesses like sulfate and iron reduction compared to carbon loss due to methanogenesis. Our resultsshow that extended and short-term saturation created conditions conducive to increasing metaboliteavailability for anaerobic decomposition processes, with a significant lag in methanogenesis. In contrast,extended drying caused a cellular-level stress response and rapid recycling of alternate electron acceptors.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B11F0521P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B11F0521P">Fe-rich carbonate chimney in Okinawa Trough Implication for Fe-driven Microbial Anaerobic Oxidation of Methane (AMO)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Peng, X.; Guo, Z. 2016-12-01 Marine sediments associated with cold seeps at continental margins discharge substantial amounts of methane. Microbial anaerobic oxidation of methane (AMO) is a key biogeochemical process in these environments, which can trigger the formation of carbonate chimneys within sediments. The exact biogeochemical mechanism of how AMO control the formation of carbonate chimneys and influence their mineralogy and chemistry remains poorly constrained. Here, we use nano-scale secondary ion mass spectrometry to characterize the petrology and geochemistry of methane-derived Fe-rich carbonate chimneys formed between 5-7 Ma in the Northern Okinawa Trough. We find abundant framboid pyrites formed in the authigenic carbonates in the chimneys, indicating a non-Fe limitation sedimentary system. The δ13C values of carbonate (-18.9‰ to -45.9‰, PDB) show their probable origin from a mixing source of biogenic and thermogenic methane. The δ34S values range from -3.9 ± 0.5‰ to 23.2 ± 0.5‰ (VCDT), indicative of a strong exhaustion of sulfates in a local sulfate pool. We proposed that Fe-rich carbonate chimneys formed at the bottom of the sulfate-methane transition zone, beneath which Fe-driven AOM may happen and provide available ferrous for the extensive precipitation of pyrite in carbonate chimneys. The accumulation of reductive Fe in sediments via this process may widely occur in other analogous settings, with important application for Fe and S biogeochemical cycling within deep sediments at continental margins. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1439016-temporal-dynamics-co2and-ch4-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1439016-temporal-dynamics-co2and-ch4-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils">Temporal dynamics of CO2and CH4 loss potentials in response to rapid hydrological shifts in tidal freshwater wetland soils</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Roy Chowdhury, Taniya; Bramer, Lisa M.; Hoyt, Davi 2018-04-15 tEarth System Models predict climate extremes that will impact regional and global hydrology. Aquatic-terrestrial transition zones like wetlands are subjected to the immediate consequence of climate change with shifts in the magnitude and dynamics of hydrologic flow. Such fluctuating hydrology can alterthe nature and rate of biogeochemical transformations and significantly impact the carbon balance ofthe ecosystem. We tested the impacts of fluctuating hydrology and, specifically, the role of antecedentmoisture conditions in determining the dominant carbon loss mechanisms in soils sampled from a tidalfreshwater wetland system in the lower Columbia River, WA, USA. Our objective was to understand shiftsin biogeochemical processesmore » in response to changing soil moisture, based on soil respiration and methaneproduction rates, and to elucidate such responses based on the observed electron acceptor and metaboliteprofiles under laboratory conditions. Metabolomics and biogeochemical process rates provided evidencethat soil redox was the principal factor driving metabolic function. Fluctuating redox conditions alteredterminal electron acceptor and donor availability and recovery strengths of their concentrations in soilsuch that a disproportionate release of carbon dioxide stemmed from alternative anaerobic degradationprocesses like sulfate and iron reduction compared to carbon loss due to methanogenesis. Our resultsshow that extended and short-term saturation created conditions conducive to increasing metaboliteavailability for anaerobic decomposition processes, with a significant lag in methanogenesis. In contrast,extended drying caused a cellular-level stress response and rapid recycling of alternate electron acceptors.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.H11D1223C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.H11D1223C">Hyporheic Exchange Flows and Biogeochemical Patterns near a Meandering Stream: East Fork of the Jemez River, Valles Caldera National Preserve, New Mexico</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Christensen, H.; Wooten, J. P.; Swanson, E.; Senison, J. J.; Myers, K. D.; Befus, K. M.; Warden, J.; Zamora, P. B.; Gomez, J. D.; Wilson, J. L.; Groffman, A.; Rearick, M. S.; Cardenas, M. B. 2012-12-01 A study by the 2012 Hydrogeology Field Methods class of the University of Texas at Austin implemented multiple approaches to evaluate and characterize local hyporheic zone flow and biogeochemical trends in a highly meandering reach of the of the East Fork of the Jemez River, a fourth order stream in northwestern New Mexico. This section of the Jemez River is strongly meandering and exhibits distinct riffle-pool morphology. The high stream sinuosity creates inter-meander hyporheic flow that is also largely influenced by local groundwater gradients. In this study, dozens of piezometers were used to map the water table and flow vectors were then calculated. Surface water and ground water samples were collected and preserved for later geochemical analysis by ICPMS and HPLC, and unstable parameters and alkalinity were measured on-site. Additionally, information was collected from thermal monitoring of the streambed, stream gauging, and from a series of electrical resistivity surveys forming a network across the site. Hyporheic flow paths are suggested by alternating gaining and losing sections of the stream as determined by stream gauging at multiple locations along the reach. Water table maps and calculated fluxes across the sediment-water interface also indicate hyporheic flow paths. We find variability in the distribution of biogeochemical constituents (oxidation-reduction potential, nitrate, ammonium, and phosphate) along interpreted flow paths which is partly consistent with hyporheic exchange. The variability and heterogeneity of reducing and oxidizing conditions is interpreted to be a result of groundwater-surface water interaction. Two-dimensional mapping of biogeochemical parameters show redox transitions along interpreted flow paths. Further analysis of various measured unstable chemical parameters results in observable trends strongly delineated along these preferential flow paths that are consistent with the direction of groundwater flow and the assumed direction of inter-meander hyporheic flow. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010BGeo....7.3593S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010BGeo....7.3593S">Efficiency of small scale carbon mitigation by patch iron fertilization</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sarmiento, J. L.; Slater, R. D.; Dunne, J.; Gnanadesikan, A.; Hiscock, M. R. 2010-11-01 While nutrient depletion scenarios have long shown that the high-latitude High Nutrient Low Chlorophyll (HNLC) regions are the most effective for sequestering atmospheric carbon dioxide, recent simulations with prognostic biogeochemical models have suggested that only a fraction of the potential drawdown can be realized. We use a global ocean biogeochemical general circulation model developed at GFDL and Princeton to examine this and related issues. We fertilize two patches in the North and Equatorial Pacific, and two additional patches in the Southern Ocean HNLC region north of the biogeochemical divide and in the Ross Sea south of the biogeochemical divide. We evaluate the simulations using observations from both artificial and natural iron fertilization experiments at nearby locations. We obtain by far the greatest response to iron fertilization at the Ross Sea site, where sea ice prevents escape of sequestered CO2 during the wintertime, and the CO2 removed from the surface ocean by the biological pump is carried into the deep ocean by the circulation. As a consequence, CO2 remains sequestered on century time-scales and the efficiency of fertilization remains almost constant no matter how frequently iron is applied as long as it is confined to the growing season. The second most efficient site is in the Southern Ocean. The North Pacific site has lower initial nutrients and thus a lower efficiency. Fertilization of the Equatorial Pacific leads to an expansion of the suboxic zone and a striking increase in denitrification that causes a sharp reduction in overall surface biological export production and CO2 uptake. The impacts on the oxygen distribution and surface biological export are less prominent at other sites, but nevertheless still a source of concern. The century time scale retention of iron in this model greatly increases the long-term biological response to iron addition as compared with simulations in which the added iron is rapidly scavenged from the ocean. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009BGD.....610381S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009BGD.....610381S">Efficiency of small scale carbon mitigation by patch iron fertilization</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sarmiento, J. L.; Slater, R. D.; Dunne, J.; Gnanadesikan, A.; Hiscock, M. R. 2009-11-01 While nutrient depletion scenarios have long shown that the high-latitude High Nutrient Low Chlorophyll (HNLC) regions are the most effective for sequestering atmospheric carbon dioxide, recent simulations with prognostic biogeochemical models have suggested that only a fraction of the potential drawdown can be realized. We use a global ocean biogeochemical general circulation model developed at GFDL and Princeton to examine this and related issues. We fertilize two patches in the North and Equatorial Pacific, and two additional patches in the Southern Ocean HNLC region north of the biogeochemical divide and in the Ross Sea south of the biogeochemical divide. We obtain by far the greatest response to iron fertilization at the Ross Sea site. Here the CO2 remains sequestered on century time-scales and the efficiency of fertilization remains almost constant no matter how frequently iron is applied as long as it is confined to the growing season. The second most efficient site is in the Southern Ocean. Here the biological response to iron fertilization is comparable to the Ross Sea, but the enhanced biological uptake of CO2 is more spread out in the vertical and thus less effective at leading to removal of CO2 from the atmosphere. The North Pacific site has lower initial nutrients and thus a lower efficiency. Fertilization of the Equatorial Pacific leads to an expansion of the suboxic zone and a striking increase in denitrification that causes a sharp reduction in overall surface biological export production and CO2 uptake. The impacts on the oxygen distribution and surface biological export are less prominent at other sites, but nevertheless still a source of concern. The century time scale retention of iron in these models greatly increases the long-term biological response to iron addition as compared with models in which the added iron is rapidly scavenged from the ocean. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012EGUGA..14.5592B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012EGUGA..14.5592B">Biogeochemical impacts of aquifer thermal energy storage at 5, 12, 25 and 60°C investigated with anoxic column experiments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bonte, M.; van Breukelen, B. M.; Van Der Wielen, P. W. J. J.; Stuyfzand, P. J. 2012-04-01 Aquifer thermal energy storage (ATES) uses groundwater to store energy for heating or cooling purposes in the built environment. ATES systems are often located in the same aquifers used for public drinking water supply, leading to urgent questions on its environmental impacts. This contribution presents the results of research on the biogeochemical impacts of ATES in anoxic column experiments at 5, 12, 25, and 60° C. In- and effluents are analyzed for major ions, trace elements, heavy metals, dissolved organic carbon (DOC) and UV extinction. Terminal restriction fragment length polymorphism (T-RFLP) of 16S rRNA genes and analysis of adenosine triphosphate (ATP) were used to detect changes in the microbiological population and activity. Results from the column experiments at 5, 25, and 60° C compared to the reference column at 12° C showed a number of changes in biogeochemical conditions: At 5° C, only changes were observed in alkalinity and calcium concentrations, resulting from calcite dissolution. The 25° C and 60° C column effluents from a sediment containing Fe-(hydr)oxides showed an increase in arsenic concentrations, well above the drinking water limit. This is due to either (reductive) dissolution of, or desorption from, iron(hydro)xides containing arsenic. In addition, at these two temperatures sulfate reduction occurred while this was undetectable at 5 and 12° C within the given timeframe (25 days) and analytical accuracy. The carbon source for sulfate reduction is inferred to be sedimentary organic carbon. Increasing DOC with residence time in the 60° C effluent suggests that at 60° C the terminal sulfate reduction step is rate limiting, while at 25° C the enzymatic hydrolization step in sulfate reducing bacteria is overall rate limiting. Specific ultraviolet absorption (SUVA, the ratio of UV extinction and DOC) however shows a clear decrease in reactivity of the humic acid fraction in DOC. This means that the DOC accumulation at 60° C could also be interpreted as a shift from pure microbial mediated organic carbon hydrolysis to chemical organic carbon respiration, yielding less reactive humic acids. The results from the T-RFLP and ATP analyses showed that the microbial population at 60° C was clearly different and less active than at lower temperatures. Overall, it is concluded that water quality can change when higher temperatures (>25 °C) are invoked on anoxic sediments. Impacts from cold storage are limited. This implies that care should be taken when positioning ATES systems at higher temperatures in aquifers that are used for public drinking water supply. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/883644','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/883644">High-resolution mineralogical characterization and biogeochemical modeling of uranium reaction pathways at the FRC</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Chen Zhu 2006-06-15 High-Resolution Mineralogical Characterization and Biogeochemical Modeling of Uranium Reduction Pathways at the Oak Ridge Field-Research Center (FRC) Chen Zhu, Indiana University, David R. Veblen, Johns Hopkins University We have successfully completed a proof-of-concept, one-year grant on a three-year proposal from the former NABIR program, and here we seek additional two-year funding to complete and publish the research. Using a state-of-the-art 300-kV, atomic resolution, Field Emission Gun Transmission Electron Microscope (TEM), we have successfully identified three categories of mineral hosts for uranium in contaminated soils: (1) iron oxides; (2) mixed manganese-iron oxides; and (3) uranium phosphates. Method development using parallel electronmore » energy loss spectroscopy (EELS) associated with the TEM shows great promise for characterizing the valence states of immobilized U during bioremediation. We have also collected 27 groundwater samples from two push-pull field biostimulation tests, which form two time series from zero to approximately 600 hours. The temporal evolution in major cations, anions, trace elements, and the stable isotopes 34S, 18O in sulfate, 15N in nitrate, and 13C in dissolved inorganic carbon (DIC) clearly show that biostimulation resulted in reduction of nitrate, Mn(IV), Fe(III), U(VI), sulfate, and Tc(VII), and these reduction reactions were intimately coupled with a complex network of inorganic reactions evident from alkalinity, pH, Na, K, Mg, and Ca concentrations. From these temporal trends, apparent zero order rates were regressed. However, our extensive suite of chemical and isotopic data sets, perhaps the first and only comprehensive data set available at the FRC, show that the derived rates from these field biostimulation experiments are composite and lump-sum rates. There were several reactions that were occurring at the same time but were masked by these pseudo-zero order rates. A reaction-path model comprising a total of nine redox couples (NO3–/NH4+, MnO2(s)/Mn2+, Fe(OH)3(s) /Fe2+, TcO4–/TcO2(s), UO22+/UO2(s), SO42–/HS–, CO2/CH4, ethanol/acetate, and H+/H2.) is used to simulate the temporal biogeochemical evolution observed in the field tests. Preliminary results show that the models based on thermodynamics and more complex rate laws can generate the apparent zero order rates when several concurrent or competing reactions occur. Professor Alex Halliday of Oxford University, UK, and his postdoctoral associates are measuring the uranium isotopes in our groundwater samples. Newly developed state-of-the-art analytical techniques in measuring variability in 235U/238U offer the potential to distinguish biotic and abiotic uranium reductive mechanisms.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H21A1060T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H21A1060T">Monitoring Physical and Biogeochemical Dynamics of Uranium Bioremediation at the Intermediate Scale</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tarrell, A. N.; Figueroa, L. A.; Rodriguez, D.; Haas, A.; Revil, A. 2011-12-01 Subsurface uranium above desired levels for aquifer use categories exists naturally and from historic mining and milling practices. In situ bioimmobilization offers a cost effective alternative to conventional pump and treat methods by stimulating growth of microorganisms that lead to the reduction and precipitation of uranium. Vital to the long-term success of in situ bioimmobilization is the ability to successfully predict and demonstrate treatment effectiveness to assure that regulatory goals are met. However, successfully monitoring the progress over time is difficult and requires long-term stewardship to ensure effective treatment due to complex physical and biogeochemical heterogeneity. In order to better understand these complexities and the resultant effect on uranium immobilization, innovative systematic monitoring approaches with multiple performance indicators must be investigated. A key issue for uranium bioremediation is the long term stability of solid-phase reduction products. It has been shown that a combination of data from electrode-based monitoring, self-potential monitoring, oxidation reduction potential (ORP), and water level sensors provides insight for identifying and localizing bioremediation activity and can provide better predictions of deleterious biogeochemical change such as pore clogging. In order to test the proof-of-concept of these sensing techniques and to deconvolve redox activity from other electric potential changing events, an intermediate scale 3D tank experiment has been developed. Well-characterized materials will be packed into the tank and an artificial groundwater will flow across the tank through a constant-head boundary. The experiment will utilize these sensing methods to image the electrical current produced by bacteria as well as indications of when and where electrical activity is occurring, such as with the reduction of radionuclides. This work will expand upon current knowledge by exploring the behavior of uranium bioremediation at an intermediate scale, as well as examining the effects from introducing a flow field in a laboratory setting. Data collected from this experiment will help further characterize which factors are contributing to current increases. Additional information concerning the effect of geochemical changes in porosity may also be observed. The results of this work will allow the creation of a new data set collected from a more comprehensive laboratory monitoring network and will allow stakeholders to develop effective decision-making tools on the long-term remediation management at uranium contaminated sites. The data will also aid in the long-term prediction abilities of a reactive transport models. As in situ bioremediation offers a low cost alternative to ex situ treatment methods, the results of this work will help to both reduce cost at existing sites and enable treatment of sites that otherwise have no clear solution. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70034509','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70034509">In Situ Rates of Sulfate Reduction in Response to Geochemical Perturbations</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Kneeshaw, T.A.; McGuire, J.T.; Cozzarelli, I.M.; Smith, E.W. 2011-01-01 Rates of in situ microbial sulfate reduction in response to geochemical perturbations were determined using Native Organism Geochemical Experimentation Enclosures (NOGEEs), a new in situ technique developed to facilitate evaluation of controls on microbial reaction rates. NOGEEs function by first trapping a native microbial community in situ and then subjecting it to geochemical perturbations through the introduction of various test solutions. On three occasions, NOGEEs were used at the Norman Landfill research site in Norman, Oklahoma, to evaluate sulfate-reduction rates in wetland sediments impacted by landfill leachate. The initial experiment, in May 2007, consisted of five introductions of a sulfate test solution over 11 d. Each test stimulated sulfate reduction with rates increasing until an apparent maximum was achieved. Two subsequent experiments, conducted in October 2007 and February 2008, evaluated the effects of concentration on sulfate-reduction rates. Results from these experiments showed that faster sulfate-reduction rates were associated with increased sulfate concentrations. Understanding variability in sulfate-reduction rates in response to perturbations may be an important factor in predicting rates of natural attenuation and bioremediation of contaminants in systems not at biogeochemical equilibrium. Copyright ?? 2011 The Author(s). Journal compilation ?? 2011 National Ground Water Association. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B41C0308F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B41C0308F">A New Biogeochemical Computational Framework Integrated within the Community Land Model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fang, Y.; Li, H.; Liu, C.; Huang, M.; Leung, L. 2012-12-01 Terrestrial biogeochemical processes, particularly carbon cycle dynamics, have been shown to significantly influence regional and global climate changes. Modeling terrestrial biogeochemical processes within the land component of Earth System Models such as the Community Land model (CLM), however, faces three major challenges: 1) extensive efforts in modifying modeling structures and rewriting computer programs to incorporate biogeochemical processes with increasing complexity, 2) expensive computational cost to solve the governing equations due to numerical stiffness inherited from large variations in the rates of biogeochemical processes, and 3) lack of an efficient framework to systematically evaluate various mathematical representations of biogeochemical processes. To address these challenges, we introduce a new computational framework to incorporate biogeochemical processes into CLM, which consists of a new biogeochemical module with a generic algorithm and reaction database. New and updated biogeochemical processes can be incorporated into CLM without significant code modification. To address the stiffness issue, algorithms and criteria will be developed to identify fast processes, which will be replaced with algebraic equations and decoupled from slow processes. This framework can serve as a generic and user-friendly platform to test out different mechanistic process representations and datasets and gain new insight on the behavior of the terrestrial ecosystems in response to climate change in a systematic way. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012GMD.....5..471H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012GMD.....5..471H">Addressing the impact of environmental uncertainty in plankton model calibration with a dedicated software system: the Marine Model Optimization Testbed (MarMOT 1.1 alpha)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hemmings, J. C. P.; Challenor, P. G. 2012-04-01 A wide variety of different plankton system models have been coupled with ocean circulation models, with the aim of understanding and predicting aspects of environmental change. However, an ability to make reliable inferences about real-world processes from the model behaviour demands a quantitative understanding of model error that remains elusive. Assessment of coupled model output is inhibited by relatively limited observing system coverage of biogeochemical components. Any direct assessment of the plankton model is further inhibited by uncertainty in the physical state. Furthermore, comparative evaluation of plankton models on the basis of their design is inhibited by the sensitivity of their dynamics to many adjustable parameters. Parameter uncertainty has been widely addressed by calibrating models at data-rich ocean sites. However, relatively little attention has been given to quantifying uncertainty in the physical fields required by the plankton models at these sites, and tendencies in the biogeochemical properties due to the effects of horizontal processes are often neglected. Here we use model twin experiments, in which synthetic data are assimilated to estimate a system's known "true" parameters, to investigate the impact of error in a plankton model's environmental input data. The experiments are supported by a new software tool, the Marine Model Optimization Testbed, designed for rigorous analysis of plankton models in a multi-site 1-D framework. Simulated errors are derived from statistical characterizations of the mixed layer depth, the horizontal flux divergence tendencies of the biogeochemical tracers and the initial state. Plausible patterns of uncertainty in these data are shown to produce strong temporal and spatial variability in the expected simulation error variance over an annual cycle, indicating variation in the significance attributable to individual model-data differences. An inverse scheme using ensemble-based estimates of the simulation error variance to allow for this environment error performs well compared with weighting schemes used in previous calibration studies, giving improved estimates of the known parameters. The efficacy of the new scheme in real-world applications will depend on the quality of statistical characterizations of the input data. Practical approaches towards developing reliable characterizations are discussed. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/20337706','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/20337706">Prokaryotic functional diversity in different biogeochemical depth zones in tidal sediments of the Severn Estuary, UK, revealed by stable-isotope probing.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Webster, Gordon; Rinna, Joachim; Roussel, Erwan G; Fry, John C; Weightman, Andrew J; Parkes, R John 2010-05-01 Stable isotope probing of prokaryotic DNA was used to determine active prokaryotes using (13)C-labelled substrates (glucose, acetate, CO(2)) in sediment slurries from different biogeochemical zones of the Severn Estuary, UK. Multiple, low concentrations (5 x 100 microM) of (13)C-substrate additions and short-term incubations (7 days) were used to minimize changes in the prokaryotic community, while achieving significant (13)C-incorporation. Analysis demonstrated clear metabolic activity within all slurries, although neither the net sulphate removal nor CH(4) production occurred in the anaerobic sulphate reduction and methanogenesis zone slurries. Some similarities occurred in the prokaryotic populations that developed in different sediment slurries, particularly in the aerobic and dysaerobic zone slurries with (13)C-glucose, which were dominated by Gammaproteobacteria and Marine Group 1 Archaea, whereas both anaerobic sediment slurries incubated with (13)C-acetate showed incorporation into Epsilonproteobacteria and other bacteria, with the sulphate reduction zone slurry also showing (13)C-acetate utilization by Miscellaneous Crenarchaeotic Group Archaea. The lower potential energy methanogenesis zone slurries were the only conditions where no (13)C-incorporation into Archaea occurred, despite Bacteria being labelled; this was surprising because Archaea have been suggested to be adapted to low-energy conditions. Overall, our results highlight that uncultured prokaryotes play important ecological roles in tidal sediments of the Severn Estuary, providing new metabolic information for novel groups of Archaea and suggesting broader metabolisms for largely uncultivated Bacteria. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2001AGUFM.H42B0352B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2001AGUFM.H42B0352B">Climate Variability, Dissolved Organic Carbon, UV Exposure, and Amphibian Decline</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brooks, P. D.; O'Reilly, C. M.; Diamond, S.; Corn, S.; Muths, E.; Tonnessen, K.; Campbell, D. H. 2001-12-01 Increasing levels of UV radiation represent a potential threat to aquatic organisms in a wide range of environments, yet controls on in situ variability on UV exposure are relatively unknown. The primary control on the penetration of UV radiation in surface water environments is the amount of photoreactive dissolved organic carbon (DOC). Consequently, biogeochemical processes that control the cycling of DOC also affect the exposure of aquatic organisms to UV radiation. Three years of monitoring UV extinction and DOC composition in Rocky Mountain, Glacier, Sequoia/ Kings Canyon, and Olympic National Parks demonstrate that the amount of fulvic acid DOC is much more important than the total DOC pool in controlling UV attenuation. This photoreactive component of DOC originates primarily in soil, and is subject both to biogeochemical controls (e.g. temperature, moisture, vegetation, soil type) on production, and hydrologic controls on transport to surface water and consequently UV exposure to aquatic organisms. Both of these controls are positively related to precipitation with greater production and transport associated with higher precipitation amounts. For example, an approximately 20 percent reduction in precipitation from 1999 to 2000 resulted in a 27% - 59% reduction in the amount of photoreactive DOC at three sites in Rocky Mountain National Park. These differences in the amount of hydrophobic DOC result in an increase in UV exposure in the aquatic environment by a factor of 2 or more. Implications of these findings for observed patterns of amphibian decline will be discussed. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70019695','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70019695">Biogeochemical effects of seawater restoration to diked salt marshes</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Portnoy, J.W.; Giblin, A.E. 1997-01-01 We conducted greenhouse microcosm experiments to examine the biogeochemical effects of restoring seawater to historically diked Cape Cod salt marshes. Peat cores from both seasonally flooded and drained diked marshes were waterlogged with seawater, and porewater chemistry was subsequently monitored for 21 mo. The addition of seawater to highly organic, seasonally flooded peat caused the death of freshwater wetland plants, 6-8 cm of sediment subsidence, and increased N and P mineralization. Also, sulfides and alkalinity increased 10-fold, suggesting accelerated decomposition by sulfate reduction. Addition of seawater to the low-organic-content acidic peat from the drained marsh increased porewater pH, alkalinity, PO4-P, and Fe(II), which we attribute to the reestablishment of SO4 and Fe(III) mineral reduction. Increased cation exchange contributed to 6-fold increases in dissolved Fe(II) and Al and 60-fold increases in NH4-N within 6 mo of sail-nation. Seawater reintroductions to seasonally flooded diked marshes will cause porewater sulfides to increase, likely reducing the success of revegetation efforts. Sulfide toxicity is of less concern in resalinated drained peats because of the abundance of Fe(II) to precipitate sulfides, and of NH4-N to offset sulfide inhibition of N uptake. Restoration of either seasonally flooded or drained diked marshes could stimulate potentially large nutrient and Fe(II) releases, which could in turn increase primary production and lower oxygen in receiving waters. These findings suggest that tidal restoration be gradual and carefully monitored. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2004AGUSM.H24A..05S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2004AGUSM.H24A..05S">Microbial Reduction of Fe(III) and U(VI) in Aquifers: Simulations Exploring Coupled Effects of Heterogeneity and Fe(II) Sorption</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Scheibe, T. D.; Fang, Y.; Roden, E. E.; Brooks, S. C.; Chien, Y.; Murray, C. J. 2004-05-01 Uranium is a significant groundwater contaminant at many former mining and processing sites. In its oxidized state, U(VI) is soluble and mobile, although strongly retarded by sorption to natural iron oxide surfaces. It has been demonstrated that commonly occurring subsurface microorganisms can reduce uranium and other metals when provided sufficient carbon as an electron donor. Reduced U(IV) precipitates as a solid phase; therefore biostimulation provides a potential strategy for in situ removal from contaminated groundwater. However, these biogeochemical reactions occur in the context of a complex heterogeneous environment in which flow and transport dynamics and abiotic reactions can have significant impacts. We have constructed a high-resolution numerical model of groundwater flow and multicomponent reactive transport that incorporates heterogeneity in hydraulic conductivity and initial Fe(III) distribution, microbial growth and transport dynamics, and effects of sorption or precipitation of biogenic Fe(II) on availability of Fe(III) as an electron acceptor. The biogeochemical reaction models and their parameters are based on laboratory experiments; the heterogeneous field-scale property distributions are based on interpretations of geophysical and other observations at a highly characterized field site. The model is being run in Monte Carlo mode to examine the controls that these factors exert on 1) the initial distribution of sorbed uranium in an oxic environment and 2) the reduction and immobilization of uranium upon introduction of a soluble electron donor. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H52D..03S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H52D..03S">Soil Biogeochemical and Microbial Feedbacks along a Snowmelt-Dominated Hillslope-to-Floodplain Transect in Colorado.</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sorensen, P.; Beller, H. R.; Bill, M.; Bouskill, N.; Brodie, E.; Chakraborty, R.; Conrad, M. E.; Karaoz, U.; Polussa, A.; Steltzer, H.; Wang, S.; Williams, K. H.; Wilmer, C.; Wu, Y. 2017-12-01 Nitrogen export from mountainous watersheds is a product of multiple interactions among hydrological processes and soil-microbial-plant feedbacks along the continuum from terrestrial to aquatic environments. In snow-dominated systems, like the East River Watershed (CO), seasonal processes such as snowmelt exert significant influence on the annual hydrologic cycle and may also link spatially distinct catchment subsystems, such as hillslope and adjoining riparian floodplains. Further, snowmelt is occurring earlier each year and this is predicted to result in a temporal asynchrony between historically coupled microbial nutrient release and plant nutrient demand in spring, with the potential to increase N export from the East River Watershed. Here we summarize biogeochemical data collected along a hillslope-to-riparian floodplain transect at the East River site. Starting in Fall 2016, we sampled soils at 3 depths and measured dissolved pools of soil nutrients (e.g., NH4+, NO3-, DOC, P), microbial biomass CN, and microbial community composition over a seasonal time course, through periods of snow accumulation, snowmelt, and plant senescence. Soil moisture content in the top 5 cm of floodplain soils was nearly 4X greater across sampling dates, coinciding with 2X greater microbial biomass C, larger extractable pools of NH4+, and smaller pools of NO3- in floodplain vs. hillslope soils. These results suggest that microbially mediated redox processes played an important role in N cycling along the transect. Hillslope vs. floodplain location also appeared to be a key factor that differentiated soil microbial communities (e.g., a more important factor than seasonality or soil depth or type). Snow accumulation and snowmelt exerted substantial influence on soil biogeochemistry. For example, microbial biomass accumulation increased about 2X beneath the winter snowpack. Snowmelt resulted in a precipitous crash in the microbial population, with 2.5X reductions in floodplain and 2X reductions in hillslope soils. Immediately following snowmelt, NO3- concentrations in soil porewater and soil extracts increased dramatically. Overall, these results suggest that N export is strongly influenced by distinct soil biogeochemical and microbiological patterns along hillslope-to-floodplain transects at East River. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1415078','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1415078">Dispersal-Based Microbial Community Assembly Decreases Biogeochemical Function</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Graham, Emily B.; Stegen, James C. Ecological mechanisms influence relationships among microbial communities, which in turn impact biogeochemistry. In particular, microbial communities are assembled by deterministic (e.g., selection) and stochastic (e.g., dispersal) processes, and the relative balance of these two process types is hypothesized to alter the influence of microbial communities over biogeochemical function. We used an ecological simulation model to evaluate this hypothesis, defining biogeochemical function generically to represent any biogeochemical reaction of interest. We assembled receiving communities under different levels of dispersal from a source community that was assembled purely by selection. The dispersal scenarios ranged from no dispersal (i.e., selection-only) to dispersal ratesmore » high enough to overwhelm selection (i.e., homogenizing dispersal). We used an aggregate measure of community fitness to infer a given community’s biogeochemical function relative to other communities. We also used ecological null models to further link the relative influence of deterministic assembly to function. We found that increasing rates of dispersal decrease biogeochemical function by increasing the proportion of maladapted taxa in a local community. Niche breadth was also a key determinant of biogeochemical function, suggesting a tradeoff between the function of generalist and specialist species. Finally, we show that microbial assembly processes exert greater influence over biogeochemical function when there is variation in the relative contributions of dispersal and selection among communities. Taken together, our results highlight the influence of spatial processes on biogeochemical function and indicate the need to account for such effects in models that aim to predict biogeochemical function under future environmental scenarios.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1415078-dispersal-based-microbial-community-assembly-decreases-biogeochemical-function','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1415078-dispersal-based-microbial-community-assembly-decreases-biogeochemical-function">Dispersal-Based Microbial Community Assembly Decreases Biogeochemical Function</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Graham, Emily B.; Stegen, James C. 2017-11-01 Ecological mechanisms influence relationships among microbial communities, which in turn impact biogeochemistry. In particular, microbial communities are assembled by deterministic (e.g., selection) and stochastic (e.g., dispersal) processes, and the relative balance of these two process types is hypothesized to alter the influence of microbial communities over biogeochemical function. We used an ecological simulation model to evaluate this hypothesis, defining biogeochemical function generically to represent any biogeochemical reaction of interest. We assembled receiving communities under different levels of dispersal from a source community that was assembled purely by selection. The dispersal scenarios ranged from no dispersal (i.e., selection-only) to dispersal ratesmore » high enough to overwhelm selection (i.e., homogenizing dispersal). We used an aggregate measure of community fitness to infer a given community’s biogeochemical function relative to other communities. We also used ecological null models to further link the relative influence of deterministic assembly to function. We found that increasing rates of dispersal decrease biogeochemical function by increasing the proportion of maladapted taxa in a local community. Niche breadth was also a key determinant of biogeochemical function, suggesting a tradeoff between the function of generalist and specialist species. Finally, we show that microbial assembly processes exert greater influence over biogeochemical function when there is variation in the relative contributions of dispersal and selection among communities. Taken together, our results highlight the influence of spatial processes on biogeochemical function and indicate the need to account for such effects in models that aim to predict biogeochemical function under future environmental scenarios.« less </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_7");'>7</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li class="active">9</li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_10" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li class="active">10</li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="181"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22742948','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22742948">Nutrient removal using biosorption activated media: preliminary biogeochemical assessment of an innovative stormwater infiltration basin.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> O'Reilly, Andrew M; Wanielista, Martin P; Chang, Ni-Bin; Xuan, Zhemin; Harris, Willie G 2012-08-15 Soil beneath a stormwater infiltration basin receiving runoff from a 23 ha predominantly residential watershed in north-central Florida, USA, was amended using biosorption activated media (BAM) to study the effectiveness of this technology in reducing inputs of nitrogen and phosphorus to groundwater. The functionalized soil amendment BAM consists of a 1.0:1.9:4.1 mixture (by volume) of tire crumb (to increase sorption capacity), silt and clay (to increase soil moisture retention), and sand (to promote sufficient infiltration), which was applied to develop an innovative stormwater infiltration basin utilizing nutrient reduction and flood control sub-basins. Comparison of nitrate/chloride (NO(3)(-)/Cl(-)) ratios for the shallow groundwater indicates that prior to using BAM, NO(3)(-) concentrations were substantially influenced by nitrification or variations in NO(3)(-) input. In contrast, for the new basin utilizing BAM, NO(3)(-)/Cl(-) ratios indicate minor nitrification and NO(3)(-) losses with the exception of one summer sample that indicated a 45% loss. Biogeochemical indicators (denitrifier activity derived from real-time polymerase chain reaction and variations in major ions, nutrients, dissolved and soil gases, and stable isotopes) suggest that NO(3)(-) losses are primarily attributable to denitrification, whereas dissimilatory nitrate reduction to ammonium is a minor process. Denitrification was likely occurring intermittently in anoxic microsites in the unsaturated zone, which was enhanced by the increased soil moisture within the BAM layer and resultant reductions in surface/subsurface oxygen exchange that produced conditions conducive to increased denitrifier activity. Concentrations of total dissolved phosphorus and orthophosphate (PO(4)(3-)) were reduced by more than 70% in unsaturated zone soil water, with the largest decreases in the BAM layer where sorption was the most likely mechanism for removal. Post-BAM PO(4)(3-)/Cl(-) ratios for shallow groundwater indicate predominantly minor increases and decreases in PO(4)(3-) with the exception of one summer sample that indicated a 50% loss. Differences in nutrient variations between the unsaturated zone and shallow groundwater may be the result of the intensity and duration of nutrient removal processes and mixing ratios with water that had undergone little biogeochemical transformation. Observed nitrogen and phosphorus losses demonstrate the potential, as well as the future research needs to improve performance, of the innovative stormwater infiltration basin using BAM for providing passive, economical, stormwater nutrient-treatment technology to support green infrastructure. Copyright © 2012 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28142226','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28142226">Lipids as paleomarkers to constrain the marine nitrogen cycle.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Rush, Darci; Sinninghe Damsté, Jaap S 2017-06-01 Global climate is, in part, regulated by the effect of microbial processes on biogeochemical cycling. The nitrogen cycle, in particular, is driven by microorganisms responsible for the fixation and loss of nitrogen, and the reduction-oxidation transformations of bio-available nitrogen. Within marine systems, nitrogen availability is often the limiting factor in the growth of autotrophic organisms, intrinsically linking the nitrogen and carbon cycles. In order to elucidate the state of these cycles in the past, and help envisage present and future variability, it is essential to understand the specific microbial processes responsible for transforming bio-available nitrogen species. As most microorganisms are soft-bodied and seldom leave behind physical fossils in the sedimentary record, recalcitrant lipid biomarkers are used to unravel microbial processes in the geological past. This review emphasises the recent advances in marine nitrogen cycle lipid biomarkers, underlines the missing links still needed to fully elucidate past shifts in this biogeochemically-important cycle, and provides examples of biomarker applications in the geological past. © 2017 The Authors. Environmental Microbiology published by Society for Applied Microbiology and John Wiley & Sons Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22073651','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22073651">Effect of temperature on biogeochemistry of marine organic-enriched systems: implications in a global warming scenario.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Sanz-Lázaro, Carlos; Valdemarsen, Thomas; Marín, Arnaldo; Holmer, Marianne 2011-10-01 Coastal biogeochemical cycles are expected to be affected by global warming. By means of a mesocosm experiment, the effect of increased water temperature on the biogeochemical cycles of coastal sediments affected by organic-matter enrichment was tested, focusing on the carbon, sulfur, and iron cycles. Nereis diversicolor was used as a model species to simulate macrofaunal bioirrigation activity in natural sediments. Although bioirrigation rates of N. diversicolor were not temperature dependent, temperature did have a major effect on the sediment metabolism. Under organic-enrichment conditions, the increase in sediment metabolism was greater than expected and occurred through the enhancement of anaerobic metabolic pathway rates, mainly sulfate reduction. There was a twofold increase in sediment metabolism and the accumulation of reduced sulfur. The increase in the benthic metabolism was maintained by the supply of electron acceptors through bioirrigation and as a result of the availability of iron in the sediment. As long as the sediment buffering capacity toward sulfides is not surpassed, an increase in temperature might promote the recovery of organic-enriched sediments by decreasing the time for mineralization of excess organic matter. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1259325-importance-biophysical-effects-climate-warming-mitigation-potential-biofuel-crops-over-conterminous-united-states','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1259325-importance-biophysical-effects-climate-warming-mitigation-potential-biofuel-crops-over-conterminous-united-states">Importance of biophysical effects on climate warming mitigation potential of biofuel crops over the conterminous United States</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Zhu, Peng; Zhuang, Qianlai; Eva, Joo; ... 2016-06-21 Current quantification of climate warming mitigation potential (CWMP) of biomass-derived energy has focused primarily on its biogeochemical effects. This study used site-level observations of carbon, water, and energy fluxes of biofuel crops to parameterize and evaluate the community land model (CLM) and estimate CO 2 fluxes, surface energy balance, soil carbon dynamics of corn (Zea mays), switchgrass (Panicum virgatum), and miscanthus (Miscanthus × giganteus) ecosystems across the conterminous United States considering different agricultural management practices and land-use scenarios. Here, we find that neglecting biophysical effects underestimates the CWMP of transitioning from croplands and marginal lands to energy crops. Biogeochemical effectsmore » alone result in changes in carbon storage of -1.9, 49.1, and 69.3 g C m -2 y -1 compared to 20.5, 78.5, and 96.2 g C m -2 y -1 when considering both biophysical and biogeochemical effects for corn, switchgrass, and miscanthus, respectively. The biophysical contribution to CWMP is dominated by changes in latent heat fluxes. Using the model to optimize growth conditions through fertilization and irrigation increases the CWMP further to 79.6, 98.3, and 118.8 g C m -2 y -1, respectively, representing the upper threshold for CWMP. Results also show that the CWMP over marginal lands is lower than that over croplands. Our study highlights that neglecting the biophysical effects of altered surface energy and water balance underestimates the CWMP of transitioning to bioenergy crops at regional scales.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/50690','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/50690">Disturbance decouples biogeochemical cycles across forests of the southeastern US</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Ashley D. Keiser; Jennifer D. Knoepp; Mark A. Bradford 2016-01-01 Biogeochemical cycles are inherently linkedÂ through the stoichiometric demands of the organismsÂ that cycle the elements. Landscape disturbanceÂ can alter element availability and thus theÂ rates of biogeochemical cycling. Nitrification is aÂ fundamental biogeochemical process positively relatedÂ to plant productivity and nitrogen loss fromÂ soils to aquatic systems, and the... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013GMD.....6.1977F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013GMD.....6.1977F">A generic biogeochemical module for Earth system models: Next Generation BioGeoChemical Module (NGBGC), version 1.0</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fang, Y.; Huang, M.; Liu, C.; Li, H.; Leung, L. R. 2013-11-01 Physical and biogeochemical processes regulate soil carbon dynamics and CO2 flux to and from the atmosphere, influencing global climate changes. Integration of these processes into Earth system models (e.g., community land models (CLMs)), however, currently faces three major challenges: (1) extensive efforts are required to modify modeling structures and to rewrite computer programs to incorporate new or updated processes as new knowledge is being generated, (2) computational cost is prohibitively expensive to simulate biogeochemical processes in land models due to large variations in the rates of biogeochemical processes, and (3) various mathematical representations of biogeochemical processes exist to incorporate different aspects of fundamental mechanisms, but systematic evaluation of the different mathematical representations is difficult, if not impossible. To address these challenges, we propose a new computational framework to easily incorporate physical and biogeochemical processes into land models. The new framework consists of a new biogeochemical module, Next Generation BioGeoChemical Module (NGBGC), version 1.0, with a generic algorithm and reaction database so that new and updated processes can be incorporated into land models without the need to manually set up the ordinary differential equations to be solved numerically. The reaction database consists of processes of nutrient flow through the terrestrial ecosystems in plants, litter, and soil. This framework facilitates effective comparison studies of biogeochemical cycles in an ecosystem using different conceptual models under the same land modeling framework. The approach was first implemented in CLM and benchmarked against simulations from the original CLM-CN code. A case study was then provided to demonstrate the advantages of using the new approach to incorporate a phosphorus cycle into CLM. To our knowledge, the phosphorus-incorporated CLM is a new model that can be used to simulate phosphorus limitation on the productivity of terrestrial ecosystems. The method presented here could in theory be applied to simulate biogeochemical cycles in other Earth system models. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFMGC43C1205R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFMGC43C1205R">Sensitivity of land surface modeling to parameters: An uncertainty quantification method applied to the Community Land Model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ricciuto, D. M.; Mei, R.; Mao, J.; Hoffman, F. M.; Kumar, J. 2015-12-01 Uncertainties in land parameters could have important impacts on simulated water and energy fluxes and land surface states, which will consequently affect atmospheric and biogeochemical processes. Therefore, quantification of such parameter uncertainties using a land surface model is the first step towards better understanding of predictive uncertainty in Earth system models. In this study, we applied a random-sampling, high-dimensional model representation (RS-HDMR) method to analyze the sensitivity of simulated photosynthesis, surface energy fluxes and surface hydrological components to selected land parameters in version 4.5 of the Community Land Model (CLM4.5). Because of the large computational expense of conducting ensembles of global gridded model simulations, we used the results of a previous cluster analysis to select one thousand representative land grid cells for simulation. Plant functional type (PFT)-specific uniform prior ranges for land parameters were determined using expert opinion and literature survey, and samples were generated with a quasi-Monte Carlo approach-Sobol sequence. Preliminary analysis of 1024 simulations suggested that four PFT-dependent parameters (including slope of the conductance-photosynthesis relationship, specific leaf area at canopy top, leaf C:N ratio and fraction of leaf N in RuBisco) are the dominant sensitive parameters for photosynthesis, surface energy and water fluxes across most PFTs, but with varying importance rankings. On the other hand, for surface ans sub-surface runoff, PFT-independent parameters, such as the depth-dependent decay factors for runoff, play more important roles than the previous four PFT-dependent parameters. Further analysis by conditioning the results on different seasons and years are being conducted to provide guidance on how climate variability and change might affect such sensitivity. This is the first step toward coupled simulations including biogeochemical processes, atmospheric processes or both to determine the full range of sensitivity of Earth system modeling to land-surface parameters. This can facilitate sampling strategies in measurement campaigns targeted at reduction of climate modeling uncertainties and can also provide guidance on land parameter calibration for simulation optimization. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1390570','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1390570">Temporal dynamics of CO 2 and CH 4 loss potentials in response to rapid hydrological shifts in tidal freshwater wetland soils</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> RoyChowdhury, Taniya; Bramer, Lisa; Hoyt, David W. Earth System Models predict climate extremes that will impact regional and global hydrology. Aquatic-terrestrial transition zones like wetlands are subjected to the immediate consequence of climate change with shifts in the magnitude and dynamics of hydrologic flow. Such fluctuating hydrology can alter the nature and rate of biogeochemical transformations and significantly impact the carbon balance of the ecosystem. We tested the impacts of fluctuating hydrology and, specifically, the role of antecedent moisture conditions in determining the dominant carbon loss mechanisms in soils sampled from a tidal freshwater wetland system in the lower Columbia River, WA, USA. The objective was tomore » understand shifts in biogeochemical processes in response to changing soil moisture, based on soil respiration and methane production rates, and to elucidate such responses based on the observed electron acceptor and metabolite profiles under laboratory conditions. Metabolomics and biogeochemical process rates provided evidence that soil redox was the principal factor driving metabolic function. Fluctuating redox conditions altered terminal electron acceptor and donor availability and recovery strengths of their concentrations in soil such that a disproportionate release of carbon dioxide stemmed from alternative anaerobic degradation processes like sulfate and iron reduction compared to carbon loss due to methanogenesis. These results show that extended and short-term saturation created conditions conducive to increasing metabolite availability for anaerobic decomposition processes, with a significant lag in methanogenesis. In contrast, extended drying caused a cellular-level stress response and rapid recycling of alternate electron acceptors.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1390570-temporal-dynamics-co-ch-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1390570-temporal-dynamics-co-ch-loss-potentials-response-rapid-hydrological-shifts-tidal-freshwater-wetland-soils">Temporal dynamics of CO 2 and CH 4 loss potentials in response to rapid hydrological shifts in tidal freshwater wetland soils</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> RoyChowdhury, Taniya; Bramer, Lisa; Hoyt, David W.; ... 2017-06-27 Earth System Models predict climate extremes that will impact regional and global hydrology. Aquatic-terrestrial transition zones like wetlands are subjected to the immediate consequence of climate change with shifts in the magnitude and dynamics of hydrologic flow. Such fluctuating hydrology can alter the nature and rate of biogeochemical transformations and significantly impact the carbon balance of the ecosystem. We tested the impacts of fluctuating hydrology and, specifically, the role of antecedent moisture conditions in determining the dominant carbon loss mechanisms in soils sampled from a tidal freshwater wetland system in the lower Columbia River, WA, USA. The objective was tomore » understand shifts in biogeochemical processes in response to changing soil moisture, based on soil respiration and methane production rates, and to elucidate such responses based on the observed electron acceptor and metabolite profiles under laboratory conditions. Metabolomics and biogeochemical process rates provided evidence that soil redox was the principal factor driving metabolic function. Fluctuating redox conditions altered terminal electron acceptor and donor availability and recovery strengths of their concentrations in soil such that a disproportionate release of carbon dioxide stemmed from alternative anaerobic degradation processes like sulfate and iron reduction compared to carbon loss due to methanogenesis. These results show that extended and short-term saturation created conditions conducive to increasing metabolite availability for anaerobic decomposition processes, with a significant lag in methanogenesis. In contrast, extended drying caused a cellular-level stress response and rapid recycling of alternate electron acceptors.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRG..122.3322L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRG..122.3322L">Tidal Pumping-Induced Nutrients Dynamics and Biogeochemical Implications in an Intertidal Aquifer</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Liu, Yi; Jiao, Jiu Jimmy; Liang, Wenzhao; Luo, Xin 2017-12-01 Tidal pumping is a major driving force affecting water exchange between land and sea, biogeochemical reactions in the intertidal aquifer, and nutrient loading to the sea. At a sandy beach of Tolo Harbour, Hong Kong, the nutrient (NH4+, NO2-, NO3-, and PO43-) dynamic in coastal groundwater mixing zone (CGMZ) is found to be fluctuated with tidal oscillation. Nutrient dynamic is mainly controlled by tidal pumping-induced organic matter that serves as a reagent of remineralization in the aquifer. NH4+, NO2-, and PO43- are positively correlated with salinity. Both NH4+ and PO43- have negative correlations with oxidation/reduction potential. NH4+ is the major dissolved inorganic nitrogen species in CGMZ. The adsorption of PO43- onto iron oxides occurs at the deep transition zone with a salinity of 5-10 practical salinity unit (psu), and intensive N-loss occurs in near-surface area with a salinity of 10-25 psu. The biogeochemical reactions, producing PO43- and consuming NH4+, are synergistic effect of remineralization-nitrification-denitrification. In CGMZ, the annual NH4+ loss is estimated to be 4.32 × 105 mol, while the minimum annual PO43- production is estimated to be 2.55 × 104 mol. Applying these rates to the entire Tolo Harbour, the annual NH4+ input to the harbor through the remineralization of organic matters is estimated to be 1.02 × 107 mol. The annual NH4+ loss via nitrification is 1.32 × 107 mol, and the annual PO43- production is 7.76 × 105 mol. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5056048','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5056048">Integrating biogeochemistry with multiomic sequence information in a model oxygen minimum zone</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Hawley, Alyse K.; Katsev, Sergei; Torres-Beltran, Monica; Bhatia, Maya P.; Kheirandish, Sam; Michiels, Céline C.; Capelle, David; Lavik, Gaute; Doebeli, Michael; Crowe, Sean A.; Hallam, Steven J. 2016-01-01 Microorganisms are the most abundant lifeform on Earth, mediating global fluxes of matter and energy. Over the past decade, high-throughput molecular techniques generating multiomic sequence information (DNA, mRNA, and protein) have transformed our perception of this microcosmos, conceptually linking microorganisms at the individual, population, and community levels to a wide range of ecosystem functions and services. Here, we develop a biogeochemical model that describes metabolic coupling along the redox gradient in Saanich Inlet—a seasonally anoxic fjord with biogeochemistry analogous to oxygen minimum zones (OMZs). The model reproduces measured biogeochemical process rates as well as DNA, mRNA, and protein concentration profiles across the redox gradient. Simulations make predictions about the role of ubiquitous OMZ microorganisms in mediating carbon, nitrogen, and sulfur cycling. For example, nitrite “leakage” during incomplete sulfide-driven denitrification by SUP05 Gammaproteobacteria is predicted to support inorganic carbon fixation and intense nitrogen loss via anaerobic ammonium oxidation. This coupling creates a metabolic niche for nitrous oxide reduction that completes denitrification by currently unidentified community members. These results quantitatively improve previous conceptual models describing microbial metabolic networks in OMZs. Beyond OMZ-specific predictions, model results indicate that geochemical fluxes are robust indicators of microbial community structure and reciprocally, that gene abundances and geochemical conditions largely determine gene expression patterns. The integration of real observational data, including geochemical profiles and process rate measurements as well as metagenomic, metatranscriptomic and metaproteomic sequence data, into a biogeochemical model, as shown here, enables holistic insight into the microbial metabolic network driving nutrient and energy flow at ecosystem scales. PMID:27655888 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27655888','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27655888">Integrating biogeochemistry with multiomic sequence information in a model oxygen minimum zone.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Louca, Stilianos; Hawley, Alyse K; Katsev, Sergei; Torres-Beltran, Monica; Bhatia, Maya P; Kheirandish, Sam; Michiels, Céline C; Capelle, David; Lavik, Gaute; Doebeli, Michael; Crowe, Sean A; Hallam, Steven J 2016-10-04 Microorganisms are the most abundant lifeform on Earth, mediating global fluxes of matter and energy. Over the past decade, high-throughput molecular techniques generating multiomic sequence information (DNA, mRNA, and protein) have transformed our perception of this microcosmos, conceptually linking microorganisms at the individual, population, and community levels to a wide range of ecosystem functions and services. Here, we develop a biogeochemical model that describes metabolic coupling along the redox gradient in Saanich Inlet-a seasonally anoxic fjord with biogeochemistry analogous to oxygen minimum zones (OMZs). The model reproduces measured biogeochemical process rates as well as DNA, mRNA, and protein concentration profiles across the redox gradient. Simulations make predictions about the role of ubiquitous OMZ microorganisms in mediating carbon, nitrogen, and sulfur cycling. For example, nitrite "leakage" during incomplete sulfide-driven denitrification by SUP05 Gammaproteobacteria is predicted to support inorganic carbon fixation and intense nitrogen loss via anaerobic ammonium oxidation. This coupling creates a metabolic niche for nitrous oxide reduction that completes denitrification by currently unidentified community members. These results quantitatively improve previous conceptual models describing microbial metabolic networks in OMZs. Beyond OMZ-specific predictions, model results indicate that geochemical fluxes are robust indicators of microbial community structure and reciprocally, that gene abundances and geochemical conditions largely determine gene expression patterns. The integration of real observational data, including geochemical profiles and process rate measurements as well as metagenomic, metatranscriptomic and metaproteomic sequence data, into a biogeochemical model, as shown here, enables holistic insight into the microbial metabolic network driving nutrient and energy flow at ecosystem scales. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70036082','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70036082">Uranium and barium cycling in a salt wedge subterranean estuary: The influence of tidal pumping</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Santos, I.R.; Burnett, W.C.; Misra, S.; Suryaputra, I.G.N.A.; Chanton, J.P.; Dittmar, T.; Peterson, R.N.; Swarzenski, P.W. 2011-01-01 The contribution of submarine groundwater discharge (SGD) to oceanic metal budgets is only beginning to be explored. Here, we demonstrate that biogeochemical processes in a northern Florida subterranean estuary (STE) significantly alter U and Ba concentrations entering the coastal ocean via SGD. Tidal pumping controlled the distribution of dissolved metals in shallow beach groundwater. Hourly observations of intertidal groundwaters revealed high U and low Ba concentrations at high tide as a result of seawater infiltration into the coastal aquifer. During ebb tide, U decreased and Ba increased due to freshwater dilution and, more importantly, biogeochemical reactions that removed U and added Ba to solution. U removal was apparently a result of precipitation following the reduction of U(VI) to U(IV). A significant correlation between Ba and dissolved organic carbon (DOC) in shallow beach groundwaters implied a common source, likely the mineralization of marine particulate organic matter driven into the beach face by tidal pumping. In deeper groundwaters, where the labile organic matter had been depleted, Ba correlated with Mn. We estimate that net SGD fluxes were − 163 and + 1660 μmol m− 1 d− 1 for U and Ba, respectively (or − 1 and + 8 μmol m− 2 d− 1 if a 200-m wide seepage area is considered). Our results support the emerging concept that subterranean estuaries are natural biogeochemical reactors where metal concentrations are altered relative to conservative mixing between terrestrial and marine endmembers. These deviations from conservative mixing significantly influence SGD-derived trace metal fluxes. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015JMS...152....1S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015JMS...152....1S">Experiences in multiyear combined state-parameter estimation with an ecosystem model of the North Atlantic and Arctic Oceans using the Ensemble Kalman Filter</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Simon, Ehouarn; Samuelsen, Annette; Bertino, Laurent; Mouysset, Sandrine 2015-12-01 A sequence of one-year combined state-parameter estimation experiments has been conducted in a North Atlantic and Arctic Ocean configuration of the coupled physical-biogeochemical model HYCOM-NORWECOM over the period 2007-2010. The aim is to evaluate the ability of an ensemble-based data assimilation method to calibrate ecosystem model parameters in a pre-operational setting, namely the production of the MyOcean pilot reanalysis of the Arctic biology. For that purpose, four biological parameters (two phyto- and two zooplankton mortality rates) are estimated by assimilating weekly data such as, satellite-derived Sea Surface Temperature, along-track Sea Level Anomalies, ice concentrations and chlorophyll-a concentrations with an Ensemble Kalman Filter. The set of optimized parameters locally exhibits seasonal variations suggesting that time-dependent parameters should be used in ocean ecosystem models. A clustering analysis of the optimized parameters is performed in order to identify consistent ecosystem regions. In the north part of the domain, where the ecosystem model is the most reliable, most of them can be associated with Longhurst provinces and new provinces emerge in the Arctic Ocean. However, the clusters do not coincide anymore with the Longhurst provinces in the Tropics due to large model errors. Regarding the ecosystem state variables, the assimilation of satellite-derived chlorophyll concentration leads to significant reduction of the RMS errors in the observed variables during the first year, i.e. 2008, compared to a free run simulation. However, local filter divergences of the parameter component occur in 2009 and result in an increase in the RMS error at the time of the spring bloom. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1322508-coupling-among-microbial-communities-biogeochemistry-mineralogy-across-biogeochemical-facies','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1322508-coupling-among-microbial-communities-biogeochemistry-mineralogy-across-biogeochemical-facies">Coupling among Microbial Communities, Biogeochemistry, and Mineralogy across Biogeochemical Facies</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Stegen, James C.; Konopka, Allan; McKinely, Jim Physical properties of sediments are commonly used to define subsurface lithofacies and these same physical properties influence subsurface microbial communities. This suggests an (unexploited) opportunity to use the spatial distribution of facies to predict spatial variation in biogeochemically relevant microbial attributes. Here, we characterize three biogeochemical facies—oxidized, reduced, and transition—within one lithofacies and elucidate relationships among facies features and microbial community biomass, diversity, and community composition. Consistent with previous observations of biogeochemical hotspots at environmental transition zones, we find elevated biomass within a biogeochemical facies that occurred at the transition between oxidized and reduced biogeochemical facies. Microbial diversity—the number ofmore » microbial taxa—was lower within the reduced facies and was well-explained by a combination of pH and mineralogy. Null modeling revealed that microbial community composition was influenced by ecological selection imposed by redox state and mineralogy, possibly due to effects on nutrient availability or transport. As an illustrative case, we predict microbial biomass concentration across a three-dimensional spatial domain by coupling the spatial distribution of subsurface biogeochemical facies with biomass-facies relationships revealed here. We expect that merging such an approach with hydro-biogeochemical models will provide important constraints on simulated dynamics, thereby reducing uncertainty in model predictions.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.sciencedirect.com/science/article/pii/S0009254110002962','USGSPUBS'); return false;" href="http://www.sciencedirect.com/science/article/pii/S0009254110002962">Diel biogeochemical processes and their effect on the aqueous chemistry of streams: A review</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Nimick, David A.; Gammons, Christopher H.; Parker, Stephen R. 2011-01-01 This review summarizes biogeochemical processes that operate on diel, or 24-h, time scales in streams and the changes in aqueous chemistry that are associated with these processes. Some biogeochemical processes, such as those producing diel cycles of dissolved O2 and pH, were the first to be studied, whereas processes producing diel concentration cycles of a broader spectrum of chemical species including dissolved gases, dissolved inorganic and organic carbon, trace elements, nutrients, stable isotopes, and suspended particles have received attention only more recently. Diel biogeochemical cycles are interrelated because the cyclical variations produced by one biogeochemical process commonly affect another. Thus, understanding biogeochemical cycling is essential not only for guiding collection and interpretation of water-quality data but also for geochemical and ecological studies of streams. Expanded knowledge of diel biogeochemical cycling will improve understanding of how natural aquatic environments function and thus lead to better predictions of how stream ecosystems might react to changing conditions of contaminant loading, eutrophication, climate change, drought, industrialization, development, and other factors. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.dtic.mil/docs/citations/ADA529222','DTIC-ST'); return false;" href="http://www.dtic.mil/docs/citations/ADA529222">Preconstruction Biogeochemical Analysis of Mercury in Wetlands Bordering the Hamilton Army Airfield (HAAF) Wetlands Restoration Site. Part 3</a> <a target="_blank" rel="noopener noreferrer" href="http://www.dtic.mil/">DTIC Science & Technology</a> 2009-12-01 ER D C/ EL T R- 09 -2 1 Preconstruction Biogeochemical Analysis of Mercury in Wetlands Bordering the Hamilton Army Airfield (HAAF) Wetlands...Preconstruction Biogeochemical Analysis of Mercury in Wetlands Bordering the Hamilton Army Airfield (HAAF) Wetlands Restoration Site Part 3 Elly P. H... mercury methylation and demethylation, and biogeochemical parameters related to the mercury cycle as measured by both conventional and emerging methods </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19920020108','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19920020108">Optimal design of compact spur gear reductions</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Savage, M.; Lattime, S. B.; Kimmel, J. A.; Coe, H. H. 1992-01-01 The optimal design of compact spur gear reductions includes the selection of bearing and shaft proportions in addition to gear mesh parameters. Designs for single mesh spur gear reductions are based on optimization of system life, system volume, and system weight including gears, support shafts, and the four bearings. The overall optimization allows component properties to interact, yielding the best composite design. A modified feasible directions search algorithm directs the optimization through a continuous design space. Interpolated polynomials expand the discrete bearing properties and proportions into continuous variables for optimization. After finding the continuous optimum, the designer can analyze near optimal designs for comparison and selection. Design examples show the influence of the bearings on the optimal configurations. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFMPP34A..05G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFMPP34A..05G">Sulfur cycling in plays an important role in the development of Ocean Anoxic Events</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gomes, M. L.; Raven, M. R.; Fike, D. A.; Gill, B. C.; Johnston, D. T. 2017-12-01 Ocean Anoxic Events (OAEs) are major carbon cycle perturbations marked by enhanced organic carbon deposition in the marine realm and carbon isotope excursions in organic and inorganic carbon. Although not as severe as the "big five" mass extinctions, OAEs had dire consequences for marine ecosystems and thus influenced Mesozoic evolutionary patterns. Sulfur cycle reconstructions provide insight into the biogeochemical processes that played a role in the development of OAEs because the sulfur cycle is linked with the carbon and oxygen cycles. We present sulfur and oxygen isotope records from carbonate-associated sulfate from the Toarcian OAE that documents a positive sulfate-oxygen isotope excursion of +6‰, which is similar to the magnitude of the positive sulfur isotope excursion documented at the same site and other globally distributed sites. This high-resolution record allows us to explore temporal variability in the onset of the isotopic excursions: the onset of the positive sulfate-oxygen isotope excursion occurs at the same stratigraphic interval as the onset of the positive carbon isotope excursion and both precede the onset of the positive sulfate-sulfur isotope excursion. Because oxygen is rapidly recycled during oxidative sulfur cycling, changes in oxidative sulfur cycling affect oxygen isotope values of sulfate without impacting sulfur isotope values. Thus, the early onset of the sulfate-oxygen isotope excursion implies a change in oxidative sulfur cycling, which is likely due to a shoaling of the zone of sulfate reduction. We explore the consequences of sulfate reduction zone shoaling for organic carbon preservation. Specifically, the sulfurization of organic matter, which makes organic matter less susceptible to degradation, occurs more rapidly when the top of the zone of sulfate reduction is near or above the sediment water interface. Therefore, we suggest that the shoaling of the sulfate reduction zone locally changed pathways of oxidative sulfur cycling and enhanced organic carbon preservation. Given synchronous changes in similar, globally-distributed depositional environments, this impacted the global biogeochemical cycles of oxygen, carbon, and nutrients in ways that sustained decreased oxygen availability and influenced extinction patterns of marine organisms. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017WRR....53.9225H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017WRR....53.9225H">Physical Controls on Biogeochemical Processes in Intertidal Zones of Beach Aquifers</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Heiss, James W.; Post, Vincent E. A.; Laattoe, Tariq; Russoniello, Christopher J.; Michael, Holly A. 2017-11-01 Marine ecosystems are sensitive to inputs of chemicals from submarine groundwater discharge. Tidally influenced saltwater-freshwater mixing zones in beach aquifers can host biogeochemical transformations that modify chemical loads prior to discharge. A numerical variable-density groundwater flow and reactive transport model was used to evaluate the physical controls on reactivity for mixing-dependent and mixing-independent reactions in beach aquifers, represented as denitrification and sulfate reduction, respectively. A sensitivity analysis was performed across typical values of tidal amplitude, hydraulic conductivity, terrestrial freshwater flux, beach slope, dispersivity, and DOC reactivity. For the model setup and conditions tested, the simulations demonstrate that denitrification can remove up to 100% of terrestrially derived nitrate, and sulfate reduction can transform up to 8% of seawater-derived sulfate prior to discharge. Tidally driven mixing between saltwater and freshwater promotes denitrification along the boundary of the intertidal saltwater circulation cell in pore water between 1 and 10 ppt. The denitrification zone occupies on average 49% of the mixing zone. Denitrification rates are highest on the landward side of the circulation cell and decrease along circulating flow paths. Reactivity for mixing-dependent reactions increases with the size of the mixing zone and solute supply, while mixing-independent reactivity is controlled primarily by solute supply. The results provide insights into the types of beaches most efficient in altering fluxes of chemicals prior to discharge and could be built upon to help engineer beaches to enhance reactivity. The findings have implications for management to protect coastal ecosystems and the estimation of chemical fluxes to the ocean. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_8");'>8</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li class="active">10</li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_11" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li class="active">11</li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="201"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/16019109','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/16019109">Sorption and transport of iodine species in sediments from the Savannah River and Hanford Sites.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Hu, Qinhong; Zhao, Pihong; Moran, Jean E; Seaman, John C 2005-07-01 Iodine is an important element in studies of environmental protection and human health, global-scale hydrologic processes and nuclear nonproliferation. Biogeochemical cycling of iodine is complex, because iodine occurs in multiple oxidation states and as inorganic and organic species that may be hydrophilic, atmophilic, and biophilic. In this study, we applied new analytical techniques to study the sorption and transport behavior of iodine species (iodide, iodate, and 4-iodoaniline) in sediments collected at the Savannah River and Hanford Sites, where anthropogenic (129)I from prior nuclear fuel processing activities poses an environmental risk. We conducted integrated column and batch experiments to investigate the interconversion, sorption and transport of iodine species, and the sediments we examined exhibit a wide range in organic matter, clay mineralogy, soil pH, and texture. The results of our experiments illustrate complex behavior with various processes occurring, including iodate reduction, irreversible retention or mass loss of iodide, and rate-limited and nonlinear sorption. There was an appreciable iodate reduction to iodide, presumably mediated by the structural Fe(II) in some clay minerals; therefore, careful attention must be given to potential interconversion among species when interpreting the biogeochemical behavior of iodine in the environment. The different iodine species exhibited dramatically different sorption and transport behavior in three sediment samples, possessing different physico-chemical properties, collected from different depths at the Savannah River Site. Our study yielded additional insight into processes and mechanisms affecting the geochemical cycling of iodine in the environment, and provided quantitative estimates of key parameters (e.g., extent and rate of sorption) for risk assessment at these sites. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..16.8158P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..16.8158P">BIO ARGO floats: tools for operational monitoring of the Black Sea</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Palazov, Atanas; Slabakova, Violeta; Peneva, Elisaveta; Stanev, Emil 2014-05-01 The assessment of ecological status in the context of the Water Framework Directive (WFD) and Marine Strategy Framework Directive (MSFD) requires comprehensive knowledge and understanding of the physical and biogeochemical processes that determine the functioning of marine ecosystems. One of the main challenges however is the need of data with frequency relevant to the spatial and temporal scales of the ecological processes. The majority of in situ observations that are commonly used for ecological monitoring of the Black Sea are generally based on near-shore monitoring programs or irregular oceanographic cruises that provide either non-synoptic, coarse resolution realizations of large scale processes or detailed, but time and site specific snapshots of local features. These gaps can be filled by two independent sources: satellite observation and profiling floats. In fact satellite ocean color sensors allows for determination at synoptic scale of water quality parameters through its absorption properties. However the satellite ocean color methods have a number of limitations such as: measurements can only be made during daylight hours; require cloud-free conditions and are sensitive to atmospheric aerosols; provide information only for the upper layer of the ocean (approximately the depth of 10% incident light); algorithms developed for global applications are a source of large uncertainties in the marginal seas and costal areas. These constrains of the optical remote sensing observations can be avoided by using miniature biogeochemical sensors and autonomous platforms that offer remarkable perspectives for observing the "biological" ocean, notably at critical spatiotemporal scales which have been out of reach until recently (Claustre et al., 2010). In the frame of "E-AIMS: Euro-Argo Improvements for the GMES marine Service" 7 EC FP project two Bio Argo floats were deployed in the Black Sea. Beside the traditionally CTD the floats were equipped with biogeochemical sensors (oxygen, irradiance, chl-a and backscattering). The selection of the deployment locations was limited only to the Bulgarian Black Sea waters, so that the optimal deployment strategy that has been chosen was the floats to be deployed in the maximum distant positions from each other along the Black Sea geostrophic current at depth ~ 1800 m. Coincident biogeochemical and in-water radiometric measurements were collected at the time of each float deployment to ensure intercalibration of the instruments mounted on the floats and as well as to find empirical relationship between optical data and biogeochemical variables. The data obtained form Bio floats will be used to: investigate the seasonal evolution of oxygen in the upper layers, including the subsurface oxygen maximum; study the seasonal and inter annual dynamics of phytoplankton blooms in the deeper Black Sea; cross validation of satellite derived Chl-a and backscattering. References: Claustre et al. (2010). Bio-optical profiling floats as new observational tools for biogeochemical and ecosystem studies: potential synergies with ocean color remote sensing. Proceedings of the "OceanObs'09: Sustained Ocean Observations and Information for Society" Conference, Venice/Italy. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GMD....10.2425K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GMD....10.2425K">Evaluation of the transport matrix method for simulation of ocean biogeochemical tracers</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kvale, Karin F.; Khatiwala, Samar; Dietze, Heiner; Kriest, Iris; Oschlies, Andreas 2017-06-01 Conventional integration of Earth system and ocean models can accrue considerable computational expenses, particularly for marine biogeochemical applications. <q>Offline</q> numerical schemes in which only the biogeochemical tracers are time stepped and transported using a pre-computed circulation field can substantially reduce the burden and are thus an attractive alternative. One such scheme is the <q>transport matrix method</q> (TMM), which represents tracer transport as a sequence of sparse matrix-vector products that can be performed efficiently on distributed-memory computers. While the TMM has been used for a variety of geochemical and biogeochemical studies, to date the resulting solutions have not been comprehensively assessed against their <q>online</q> counterparts. Here, we present a detailed comparison of the two. It is based on simulations of the state-of-the-art biogeochemical sub-model embedded within the widely used coarse-resolution University of Victoria Earth System Climate Model (UVic ESCM). The default, non-linear advection scheme was first replaced with a linear, third-order upwind-biased advection scheme to satisfy the linearity requirement of the TMM. Transport matrices were extracted from an equilibrium run of the physical model and subsequently used to integrate the biogeochemical model offline to equilibrium. The identical biogeochemical model was also run online. Our simulations show that offline integration introduces some bias to biogeochemical quantities through the omission of the polar filtering used in UVic ESCM and in the offline application of time-dependent forcing fields, with high latitudes showing the largest differences with respect to the online model. Differences in other regions and in the seasonality of nutrients and phytoplankton distributions are found to be relatively minor, giving confidence that the TMM is a reliable tool for offline integration of complex biogeochemical models. Moreover, while UVic ESCM is a serial code, the TMM can be run on a parallel machine with no change to the underlying biogeochemical code, thus providing orders of magnitude speed-up over the online model. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1256078','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1256078">Genome-Resolved Metagenomic Analysis Reveals Roles for Candidate Phyla and Other Microbial Community Members in Biogeochemical Transformations in Oil Reservoirs</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Hu, Ping; Tom, Lauren; Singh, Andrea Oil reservoirs are major sites of methane production and carbon turnover, processes with significant impacts on energy resources and global biogeochemical cycles. We applied a cultivation-independent genomic approach to define microbial community membership and predict roles for specific organisms in biogeochemical transformations in Alaska North Slope oil fields. Produced water samples were collected from six locations between 1,128 m (24 to 27°C) and 2,743 m (80 to 83°C) below the surface. Microbial community complexity decreased with increasing temperature, and the potential to degrade hydrocarbon compounds was most prevalent in the lower-temperature reservoirs. Sulfate availability, rather than sulfate reduction potential, seems to bemore » the limiting factor for sulfide production in some of the reservoirs under investigation. Most microorganisms in the intermediate- and higher-temperature samples were related to previously studied methanogenic and nonmethanogenic archaea and thermophilic bacteria, but one candidate phylum bacterium, a member of theAcetothermia(OP1), was present in Kuparuk sample K3. The greatest numbers of candidate phyla were recovered from the mesothermic reservoir samples SB1 and SB2. We reconstructed a nearly complete genome for an organism from the candidate phylumParcubacteria(OD1) that was abundant in sample SB1. Consistent with prior findings for members of this lineage, the OD1 genome is small, and metabolic predictions support an obligately anaerobic, fermentation-based lifestyle. At moderate abundance in samples SB1 and SB2 were members of bacteria from other candidate phyla, includingMicrogenomates(OP11),Atribacteria(OP9), candidate phyla TA06 and WS6, andMarinimicrobia(SAR406). The results presented here elucidate potential roles of organisms in oil reservoir biological processes. The activities of microorganisms in oil reservoirs impact petroleum resource quality and the global carbon cycle. In conclusion, we show that bacteria belonging to candidate phyla are present in some oil reservoirs and provide the first insights into their potential roles in biogeochemical processes based on several nearly complete genomes.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26787827','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26787827">Genome-Resolved Metagenomic Analysis Reveals Roles for Candidate Phyla and Other Microbial Community Members in Biogeochemical Transformations in Oil Reservoirs.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Hu, Ping; Tom, Lauren; Singh, Andrea; Thomas, Brian C; Baker, Brett J; Piceno, Yvette M; Andersen, Gary L; Banfield, Jillian F 2016-01-19 Oil reservoirs are major sites of methane production and carbon turnover, processes with significant impacts on energy resources and global biogeochemical cycles. We applied a cultivation-independent genomic approach to define microbial community membership and predict roles for specific organisms in biogeochemical transformations in Alaska North Slope oil fields. Produced water samples were collected from six locations between 1,128 m (24 to 27°C) and 2,743 m (80 to 83°C) below the surface. Microbial community complexity decreased with increasing temperature, and the potential to degrade hydrocarbon compounds was most prevalent in the lower-temperature reservoirs. Sulfate availability, rather than sulfate reduction potential, seems to be the limiting factor for sulfide production in some of the reservoirs under investigation. Most microorganisms in the intermediate- and higher-temperature samples were related to previously studied methanogenic and nonmethanogenic archaea and thermophilic bacteria, but one candidate phylum bacterium, a member of the Acetothermia (OP1), was present in Kuparuk sample K3. The greatest numbers of candidate phyla were recovered from the mesothermic reservoir samples SB1 and SB2. We reconstructed a nearly complete genome for an organism from the candidate phylum Parcubacteria (OD1) that was abundant in sample SB1. Consistent with prior findings for members of this lineage, the OD1 genome is small, and metabolic predictions support an obligately anaerobic, fermentation-based lifestyle. At moderate abundance in samples SB1 and SB2 were members of bacteria from other candidate phyla, including Microgenomates (OP11), Atribacteria (OP9), candidate phyla TA06 and WS6, and Marinimicrobia (SAR406). The results presented here elucidate potential roles of organisms in oil reservoir biological processes. The activities of microorganisms in oil reservoirs impact petroleum resource quality and the global carbon cycle. We show that bacteria belonging to candidate phyla are present in some oil reservoirs and provide the first insights into their potential roles in biogeochemical processes based on several nearly complete genomes. Copyright © 2016 Hu et al. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..1810625M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..1810625M">Abrupt shifts in ecosystem function and intensification of global biogeochemical cycle driven by hydroclimatic extremes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ma, Xuanlong; Huete, Alfredo; Ponce-Campos, Guillermo; Zhang, Yongguang; Xie, Zunyi; Giovannini, Leandro; Cleverly, James; Eamus, Derek 2016-04-01 Amplification of the hydrologic cycle as a consequence of global warming is increasing the frequency, intensity, and spatial extent of extreme climate events globally. The potential influences resulting from amplification of the hydro-climatic cycle, coupled with an accelerating warming trend, pose great concerns on the sustainability of terrestrial ecosystems to sequester carbon, maintain biodiversity, provide ecosystem services, food security, and support human livelihood. Despite the great implications, the magnitude, direction, and carry-over effect of these extreme climate events on ecosystem function, remain largely uncertain. To address these pressing issues, we conducted an observational, interdisciplinary study using satellite retrievals of atmospheric CO2 and photosynthesis (chlorophyll fluorescence), and in-situ flux tower measures of ecosystem-atmosphere carbon exchange, to reveal the shifts in ecosystem function across extreme drought and wet periods. We further determine the factors that govern ecosystem sensitivity to hydroclimatic extremes. We focus on Australia but extended our analyses to other global dryland regions due to their significant role in global biogeochemical cycles. Our results revealed dramatic impacts of drought and wet hydroclimatic extremes on ecosystem function, with abrupt changes in vegetation productivity, carbon uptake, and water-use-efficiency between years. Drought resulted in widespread reductions or collapse in the normal patterns of vegetation growth seasonality such that in many cases there was no detectable phenological cycle during extreme drought years. We further identified a significant increasing trend (p < 0.001) in extreme wet year precipitation amounts over Australia and many other global regions, resulting in an increasing trend in magnitude of the episodic carbon sink pulses coupled to each La Niña-induced wet years. This finding is of global biogeochemical significance, with the consequence of amplifying the global carbon cycle. Lastly, we use landscape measurements of carbon and water fluxes from eddy-covariance towers and field sampling of aboveground net primary productivity from long-term ecological networks to verify the patterns observed by top-down approaches. Our results demonstrate the intensification of hydroclimatic extremes due to global warming is exerting important impacts on ecosystem function, which further have significant implications on global biogeochemical cycles as well as local ecosystem processes. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B54B..01S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B54B..01S">Biogeochemical hotspots following a simulated tree mortality event of southern pine beetle</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Siegert, C. M.; Renninger, H. J.; Karunarathna, S.; Hornslein, N.; Riggins, J. J.; Clay, N. A.; Tang, J. D.; Chaney, B.; Drotar, N. 2017-12-01 Disturbances in forest ecosystems can alter functions like productivity, respiration, and nutrient cycling through the creation of biogeochemical hotspots. These events occur sporadically across the landscape, leading to uncertainty in terrestrial biosphere carbon models, which have yet to capture the full complexity of biotic and abiotic factors driving ecological processes in the terrestrial environment. Given the widespread impact of southern pine beetle on forest ecosystems throughout the southeastern United States, it is critical to management and planning activities to understand the role of these disturbances. As such, we hypothesize that bark beetle killed trees create biogeochemical hotspots in the soils surrounding their trunk as they undergo mortality due to (1) increased soil moisture from reductions in plant water uptake and increased stemflow production, (2) enhanced canopy-derived inputs of carbon and nitrogen, and (3) increased microbial activity and root mortality. In 2015, a field experiment to mimic a southern pine beetle attack was established by girdling loblolly pine trees. Subsequent measurements of throughfall and stemflow for water quantity and quality, transpiration, stem respiration, soil respiration, and soil chemistry were used to quantify the extent of spatial and temporal impacts of tree mortality on carbon budgets. Compared to control trees, girdled trees exhibited reduced water uptake within the first 6 months of the study and succumbed to mortality within 18 months. Over two years, the girdled trees generated 33% more stemflow than control trees (7836 vs. 5882 L m-2). Preliminary analysis of carbon and nitrogen concentrations and dissolved organic matter quality are still pending. In the surrounding soils, C:N ratios were greater under control trees (12.8) than under girdled trees (12.1), which was driven by an increase in carbon around control trees (+0.13 mg C mg-1 soil) and not a decrease around girdled trees (-0.01 mg C mg-1 soil), with no observed differences in N concentrations. Although data from the remaining of the 2017 growing season are still pending, we have thus far demonstrated how tree mortality from southern pine beetle changes single tree hydrologic and biogeochemical cycles. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1256078-genome-resolved-metagenomic-analysis-reveals-roles-candidate-phyla-other-microbial-community-members-biogeochemical-transformations-oil-reservoirs','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1256078-genome-resolved-metagenomic-analysis-reveals-roles-candidate-phyla-other-microbial-community-members-biogeochemical-transformations-oil-reservoirs">Genome-Resolved Metagenomic Analysis Reveals Roles for Candidate Phyla and Other Microbial Community Members in Biogeochemical Transformations in Oil Reservoirs</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Hu, Ping; Tom, Lauren; Singh, Andrea; ... 2016-01-19 Oil reservoirs are major sites of methane production and carbon turnover, processes with significant impacts on energy resources and global biogeochemical cycles. We applied a cultivation-independent genomic approach to define microbial community membership and predict roles for specific organisms in biogeochemical transformations in Alaska North Slope oil fields. Produced water samples were collected from six locations between 1,128 m (24 to 27°C) and 2,743 m (80 to 83°C) below the surface. Microbial community complexity decreased with increasing temperature, and the potential to degrade hydrocarbon compounds was most prevalent in the lower-temperature reservoirs. Sulfate availability, rather than sulfate reduction potential, seems to bemore » the limiting factor for sulfide production in some of the reservoirs under investigation. Most microorganisms in the intermediate- and higher-temperature samples were related to previously studied methanogenic and nonmethanogenic archaea and thermophilic bacteria, but one candidate phylum bacterium, a member of theAcetothermia(OP1), was present in Kuparuk sample K3. The greatest numbers of candidate phyla were recovered from the mesothermic reservoir samples SB1 and SB2. We reconstructed a nearly complete genome for an organism from the candidate phylumParcubacteria(OD1) that was abundant in sample SB1. Consistent with prior findings for members of this lineage, the OD1 genome is small, and metabolic predictions support an obligately anaerobic, fermentation-based lifestyle. At moderate abundance in samples SB1 and SB2 were members of bacteria from other candidate phyla, includingMicrogenomates(OP11),Atribacteria(OP9), candidate phyla TA06 and WS6, andMarinimicrobia(SAR406). The results presented here elucidate potential roles of organisms in oil reservoir biological processes. The activities of microorganisms in oil reservoirs impact petroleum resource quality and the global carbon cycle. In conclusion, we show that bacteria belonging to candidate phyla are present in some oil reservoirs and provide the first insights into their potential roles in biogeochemical processes based on several nearly complete genomes.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29902627','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29902627">The use of biogeochemical models to evaluate mitigation of greenhouse gas emissions from managed grasslands.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Sándor, Renáta; Ehrhardt, Fiona; Brilli, Lorenzo; Carozzi, Marco; Recous, Sylvie; Smith, Pete; Snow, Val; Soussana, Jean-François; Dorich, Christopher D; Fuchs, Kathrin; Fitton, Nuala; Gongadze, Kate; Klumpp, Katja; Liebig, Mark; Martin, Raphaël; Merbold, Lutz; Newton, Paul C D; Rees, Robert M; Rolinski, Susanne; Bellocchi, Gianni 2018-06-11 Simulation models quantify the impacts on carbon (C) and nitrogen (N) cycling in grassland systems caused by changes in management practices. To support agricultural policies, it is however important to contrast the responses of alternative models, which can differ greatly in their treatment of key processes and in their response to management. We applied eight biogeochemical models at five grassland sites (in France, New Zealand, Switzerland, United Kingdom and United States) to compare the sensitivity of modelled C and N fluxes to changes in the density of grazing animals (from 100% to 50% of the original livestock densities), also in combination with decreasing N fertilization levels (reduced to zero from the initial levels). Simulated multi-model median values indicated that input reduction would lead to an increase in the C sink strength (negative net ecosystem C exchange) in intensive grazing systems: -64 ± 74 g C m -2  yr -1 (animal density reduction) and -81 ± 74 g C m -2  yr -1 (N and animal density reduction), against the baseline of -30.5 ± 69.5 g C m -2  yr -1 (LSU [livestock units] ≥ 0.76 ha -1  yr -1 ). Simulations also indicated a strong effect of N fertilizer reduction on N fluxes, e.g. N 2 O-N emissions decreased from 0.34 ± 0.22 (baseline) to 0.1 ± 0.05 g N m -2  yr -1 (no N fertilization). Simulated decline in grazing intensity had only limited impact on the N balance. The simulated pattern of enteric methane emissions was dominated by high model-to-model variability. The reduction in simulated offtake (animal intake + cut biomass) led to a doubling in net primary production per animal (increased by 11.6 ± 8.1 t C LSU -1  yr -1 across sites). The highest N 2 O-N intensities (N 2 O-N/offtake) were simulated at mown and extensively grazed arid sites. We show the possibility of using grassland models to determine sound mitigation practices while quantifying the uncertainties associated with the simulated outputs. Copyright © 2018 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014GeCoA.124...72L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014GeCoA.124...72L">Modeling microbial reaction rates in a submarine hydrothermal vent chimney wall</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> LaRowe, Douglas E.; Dale, Andrew W.; Aguilera, David R.; L'Heureux, Ivan; Amend, Jan P.; Regnier, Pierre 2014-01-01 The fluids emanating from active submarine hydrothermal vent chimneys provide a window into subseafloor processes and, through mixing with seawater, are responsible for steep thermal and compositional gradients that provide the energetic basis for diverse biological communities. Although several models have been developed to better understand the dynamic interplay of seawater, hydrothermal fluid, minerals and microorganisms inside chimney walls, none provide a fully integrated approach to quantifying the biogeochemistry of these hydrothermal systems. In an effort to remedy this, a fully coupled biogeochemical reaction-transport model of a hydrothermal vent chimney has been developed that explicitly quantifies the rates of microbial catalysis while taking into account geochemical processes such as fluid flow, solute transport and oxidation-reduction reactions associated with fluid mixing as a function of temperature. The metabolisms included in the reaction network are methanogenesis, aerobic oxidation of hydrogen, sulfide and methane and sulfate reduction by hydrogen and methane. Model results indicate that microbial catalysis is generally fastest in the hottest habitable portion of the vent chimney (77-102 °C), and methane and sulfide oxidation peak near the seawater-side of the chimney. The fastest metabolisms are aerobic oxidation of H2 and sulfide and reduction of sulfate by H2 with maximum rates of 140, 900 and 800 pmol cm-3 d-1, respectively. The maximum rate of hydrogenotrophic methanogenesis is just under 0.03 pmol cm-3 d-1, the slowest of the metabolisms considered. Due to thermodynamic inhibition, there is no anaerobic oxidation of methane by sulfate (AOM). These simulations are consistent with vent chimney metabolic activity inferred from phylogenetic data reported in the literature. The model developed here provides a quantitative approach to describing the rates of biogeochemical transformations in hydrothermal systems and can be used to constrain the role of microbial activity in the deep subsurface. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.B31E0348B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.B31E0348B">Quantifying the effects of mountain pine beetle infestation on water and biogeochemical cycles at multiple spatial and temporal scales</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brooks, P. D.; Harpold, A. A.; Somor, A. J.; Troch, P. A.; Gochis, D. J.; Ewers, B. E.; Pendall, E.; Biederman, J. A.; Reed, D.; Barnard, H. R.; Whitehouse, F.; Aston, T.; Borkhuu, B. 2010-12-01 Unprecedented levels of bark beetle infestation over the last decade have radically altered forest structure across millions of hectares of Western U.S. montane environments. The widespread extent of this disturbance presents a major challenge for governments and resource managers who lack a predictive understanding of how water and biogeochemical cycles will respond to this disturbance over various temporal and spatial scales. There is a widespread perception, largely based on hydrological responses to fire or logging, that a reduction in both transpiration and interception following tree death will increase soil water availability and catchment water yield. However, few studies have directly addressed the effects of insect-induced forest decline on water and biogeochemical cycling. We address this knowledge gap using observations and modeling at scales from 100 to 109 m2 across study sites in CO and WY that vary in the intensity and timing of beetle infestation and tree death. Our focus on multiple sites with different levels of impact allows us to address two broad, organizing questions: How do changes in vegetation structure associated with MPB alter the partitioning of energy and water? And How do these changes in energy and water availability affect local to regional scale water and biogeochemical cycles? This presentation will focus primarily on energy balance and water partitioning, providing context for ongoing biogeochemical work. During the growing season, stand-scale transpiration declines rapidly and soil moisture increases following infestation, consistent with streamflow data from regional catchments that shows an increase in baseflow following widespread attack. During the winter and spring, stand scale snow surveys and continuous snow depth sensors suggested that the variability in snow cover decreased as the severity of beetle impact increases, but there were no significant stand-scale differences in snow depth among levels of impact. This is due both to an increase in snow under the canopies of dead trees and a decrease in snow cover in canopy gaps. For example, mean snow depth under the canopy was 86cm (CV 0.02) in unimpacted sites and 95cm (CV 0.05) in heavily impacted sites. In canopy gaps however, mean snow depth was 117cm (CV 0.11) in unimpacted sites but only 93cm (CV 0.07) in heavily impacted sites. At the watershed scale, bark beetle infestation was more likely to decrease the amount of both snowmelt and annual runoff, suggesting that the opening of the canopy increases sublimation and evaporation of the snow cover. These data suggest that the disturbance due to bark beetle infestation is both quantitatively and qualitatively different than either fire or logging. Using these observations, we develop a conceptual model for evaluating how biotic and abiotic processes couple water and biogeochemical cycles in forest ecosystems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=256418&Lab=NHEERL&keyword=displacement&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=256418&Lab=NHEERL&keyword=displacement&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Spatial dynamics of biogeochemical processes in the St. Louis River freshwater estuary</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> In the Great Lakes, river-lake transition zones within freshwater estuaries are hydrologically and biogeochemically dynamic areas that regulate nutrient and energy fluxes between rivers and Great Lakes. The goal of our study was to characterize the biogeochemical properties of th... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/895886','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/895886">Field-Integrated Studies of Long-Term Sustainability of Chromium Bioreduction at Hanford 100H Site</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Long, Philip E. 2006-06-01 The objectives of the project are to investigate coupled hydraulic, geochemical, and microbial conditions, and to determine the critical biogeochemical parameters necessary to maximize the extent of Cr(VI) bioreduction and minimize Cr(III) reoxidation in groundwater. Specific goals of the project are as follows: (1) Field testing and monitoring of Cr(VI) bioreduction in ground water and its transformation into insoluble species of Cr(III) at the Hanford 100H site, to develop the optimal strategy of water sampling for chemical, microbial, stable isotope analyses, and noninvasive geophysical monitoring; (2) Bench-scale flow and transport investigations using columns of undisturbed sediments to obtain diffusion andmore » kinetic parameters needed for the development of a numerical model, predictions of Cr(VI) bioreduction, and potential of Cr(III) reoxidation; and (3) Development of a multiphase, multi-component 3D reactive transport model and a code, TOUGHREACT-BIO, to predict coupled biogeochemical-hydrological processes associated with bioremediation, and to calibrate and validate the developed code based on the results of bench-scale and field-scale Cr(VI) biostimulation experiments in ground water at the Hanford Site.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JGRC..122.6968V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JGRC..122.6968V">A data assimilating model for estimating Southern Ocean biogeochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Verdy, A.; Mazloff, M. R. 2017-09-01 A Biogeochemical Southern Ocean State Estimate (B-SOSE) is introduced that includes carbon and oxygen fields as well as nutrient cycles. The state estimate is constrained with observations while maintaining closed budgets and obeying dynamical and thermodynamic balances. Observations from profiling floats, shipboard data, underway measurements, and satellites are used for assimilation. The years 2008-2012 are chosen due to the relative abundance of oxygen observations from Argo floats during this time. The skill of the state estimate at fitting the data is assessed. The agreement is best for fields that are constrained with the most observations, such as surface pCO2 in Drake Passage (44% of the variance captured) and oxygen profiles (over 60% of the variance captured at 200 and 1000 m). The validity of adjoint method optimization for coupled physical-biogeochemical state estimation is demonstrated with a series of gradient check experiments. The method is shown to be mature and ready to synthesize in situ biogeochemical observations as they become more available. Documenting the B-SOSE configuration and diagnosing the strengths and weaknesses of the solution informs usage of this product as both a climate baseline and as a way to test hypotheses. Transport of Intermediate Waters across 32°S supplies significant amounts of nitrate to the Atlantic Ocean (5.57 ± 2.94 Tmol yr-1) and Indian Ocean (5.09 ± 3.06 Tmol yr-1), but much less nitrate reaches the Pacific Ocean (1.78 ± 1.91 Tmol yr-1). Estimates of air-sea carbon dioxide fluxes south of 50°S suggest a mean uptake of 0.18 Pg C/yr for the time period analyzed. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMNS24A..07F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMNS24A..07F">Identification of biogeochemical hot spots using time-lapse hydrogeophysics</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Franz, T. E.; Loecke, T.; Burgin, A. 2016-12-01 The identification and monitoring of biogeochemical hot spots and hot moments is difficult using point based sampling techniques and sensors. Without proper monitoring and accounting of water, energy, and trace gas fluxes it is difficult to assess the environmental footprint of land management practices. One key limitation is optimal placement of sensors/chambers that adequately capture the point scale fluxes and thus a reasonable integration to landscape scale flux. In this work we present time-lapse hydrogeophysical imaging at an old agricultural field converted into a wetland mitigation bank near Dayton, Ohio. While the wetland was previously instrumented with a network of soil sensors and surface chambers to capture a suite of state variables and fluxes, we hypothesize that time-lapse hydrogeophysical imaging is an underutilized and critical reconnaissance tool for effective network design and landscape scaling. Here we combine the time-lapse hydrogeophysical imagery with the multivariate statistical technique of Empirical Orthogonal Functions (EOF) in order to isolate the spatial and temporal components of the imagery. Comparisons of soil core information (e.g. soil texture, soil carbon) from around the study site and organized within like spatial zones reveal statistically different mean values of soil properties. Moreover, the like spatial zones can be used to identify a finite number of future sampling locations, evaluation of the placement of existing sensors/chambers, upscale/downscale observations, all of which are desirable techniques for commercial use in precision agriculture. Finally, we note that combining the EOF analysis with continuous monitoring from point sensors or remote sensing products may provide a robust statistical framework for scaling observations through time as well as provide appropriate datasets for use in landscape biogeochemical models. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.H32B..01S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.H32B..01S">Toxic Compounds in Our Food: Arsenic Uptake By Rice and Potential Mitigation By Silicon</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Seyfferth, A.; Gill, R.; Penido, E. 2014-12-01 Arsenic is a ubiquitous element in soils worldwide and has the potential to negatively impact human and ecosystem health under certain biogeochemical conditions. While arsenic is relatively immobile in most oxidized soils due to a high affinity for soil solids, arsenic becomes mobilized under reduced soil conditions due to the reductive dissolution of iron(III) oxides thereby releasing soil-bound arsenic. Since arsenic is a well-known carcinogen, this plant-soil process has the potential to negatively impact the lives of billions of rice consumers worldwide upon plant uptake and grain storage of released arsenic. Moreover, arsenic uptake by rice is excacerbated by the use of As-laden groundwater for rice irrigation. One proposed strategy to decrease arsenic uptake by rice plants is via an increase in dissolved silicon in paddy soil solution (pore-water), since silicic acid and arsenous acid share an uptake pathway. However, several soil processes that influence arsenic cycling may be affected by silicon including desorption from bulk soil, formation and mineralogy of iron(III) oxide plaque, and adsorption/desorption onto/from iron plaque; the effect of silicon on these soil processes will ultimately dictate the effectiveness of altered dissolved silicon in decreasing arsenic uptake at the root, which in turn dictates the concentration of arsenic found in grains. Furthermore, the source of silicon may impact carbon cycling and, in particular, methane emissions. Here, impacts of altered dissolved silicon on processes that affect rhizospheric biogeochemical cycling of arsenic and subsequent plant-uptake, and how it influences other biogeochemical cycles such as carbon and iron are investigated. We show that silicon can decrease arsenic uptake and grain storage under certain conditions, and that altered silicon affects the type of iron (III) oxide that comprises iron plaque. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017ACP....17.3055S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017ACP....17.3055S">Effects of ozone-vegetation coupling on surface ozone air quality via biogeochemical and meteorological feedbacks</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sadiq, Mehliyar; Tai, Amos P. K.; Lombardozzi, Danica; Martin, Maria Val 2017-02-01 Tropospheric ozone is one of the most hazardous air pollutants as it harms both human health and plant productivity. Foliage uptake of ozone via dry deposition damages photosynthesis and causes stomatal closure. These foliage changes could lead to a cascade of biogeochemical and biogeophysical effects that not only modulate the carbon cycle, regional hydrometeorology and climate, but also cause feedbacks onto surface ozone concentration itself. In this study, we implement a semi-empirical parameterization of ozone damage on vegetation in the Community Earth System Model to enable online ozone-vegetation coupling, so that for the first time ecosystem structure and ozone concentration can coevolve in fully coupled land-atmosphere simulations. With ozone-vegetation coupling, present-day surface ozone is simulated to be higher by up to 4-6 ppbv over Europe, North America and China. Reduced dry deposition velocity following ozone damage contributes to ˜ 40-100 % of those increases, constituting a significant positive biogeochemical feedback on ozone air quality. Enhanced biogenic isoprene emission is found to contribute to most of the remaining increases, and is driven mainly by higher vegetation temperature that results from lower transpiration rate. This isoprene-driven pathway represents an indirect, positive meteorological feedback. The reduction in both dry deposition and transpiration is mostly associated with reduced stomatal conductance following ozone damage, whereas the modification of photosynthesis and further changes in ecosystem productivity are found to play a smaller role in contributing to the ozone-vegetation feedbacks. Our results highlight the need to consider two-way ozone-vegetation coupling in Earth system models to derive a more complete understanding and yield more reliable future predictions of ozone air quality. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H53E1491A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H53E1491A">Relative Linkages of Chlorophyll-a with the Hydroclimatic and Biogeochemical Variables across the Continental U.S. (CONUS)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ahmed, M. H.; Abdul-Aziz, O. I. 2017-12-01 Chlorophyll-a (Chl-a) is a key indicator for stream water quality and ecological health. The characterization of interplay between Chl-a and its numerous hydroclimatic and biogeochemical drivers is complex, and often involves multicollinear datasets. A systematic data analytics methodology was employed to determine the relative linkages of stream Chl-a with its dynamic environmental drivers at 50 stream water quality monitoring stations across the continental U.S. Multivariate statistical techniques of principal component analysis (PCA) and factor analysis (FA), in concert with Pearson correlation analysis, were applied to evaluate interrelationships among hydroclimatic, biogeochemical, and biological variables. Power-law based partial least square regression (PLSR) models were developed with a bootstrap Monte Carlo procedure (1000 iterations) to reliably estimate the comparative linkages of Chl-a by resolving multicollinearity in the data matrices (Nash-Sutcliff efficiency = 0.50-87). The data analytics suggested four environmental regimes of stream Chl-a, as dominated by nutrient, climate, redox, and hydro-atmospheric contributions, respectively. Total phosphorous (TP) was the most dominant driver of stream Chl-a in the nutrient controlled regime. Water temperature demonstrated the strongest control of Chl-a in the climate-dominated regime. Furthermore, pH and stream flow were found to be the most important drivers of Chl-a in the redox and hydro-atmospheric component dominated regimes, respectively. The research led to a significant reduction of dimensionality in the large data matrices, providing quantitative and qualitative insights on the dynamics of stream Chl-a. The findings would be useful to manage stream water quality and ecosystem health in the continental U.S. and around the world under a changing climate and environment. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26593782','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26593782">Influence of Humic Acid Complexation with Metal Ions on Extracellular Electron Transfer Activity.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zhou, Shungui; Chen, Shanshan; Yuan, Yong; Lu, Qin 2015-11-23 Humic acids (HAs) can act as electron shuttles and mediate biogeochemical cycles, thereby influencing the transformation of nutrients and environmental pollutants. HAs commonly complex with metals in the environment, but few studies have focused on how these metals affect the roles of HAs in extracellular electron transfer (EET). In this study, HA-metal (HA-M) complexes (HA-Fe, HA-Cu, and HA-Al) were prepared and characterized. The electron shuttle capacities of HA-M complexes were experimentally evaluated through microbial Fe(III) reduction, biocurrent generation, and microbial azoreduction. The results show that the electron shuttle capacities of HAs were enhanced after complexation with Fe but were weakened when using Cu or Al. Density functional theory calculations were performed to explore the structural geometry of the HA-M complexes and revealed the best binding sites of the HAs to metals and the varied charge transfer rate constants (k). The EET activity of the HA-M complexes were in the order HA-Fe > HA-Cu > HA-Al. These findings have important implications for biogeochemical redox processes given the ubiquitous nature of both HAs and various metals in the environment. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013WRR....49.6425P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013WRR....49.6425P">Optimizing conservation practices in watersheds: Do community preferences matter?</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Piemonti, Adriana D.; Babbar-Sebens, Meghna; Jane Luzar, E. 2013-10-01 This paper focuses on investigating (a) how landowner tenure and attitudes of farming communities affect the preference of individual conservation practices in agricultural watersheds, (b) how spatial distribution of landowner tenure affects the spatial optimization of conservation practices on a watershed scale, and (c) how the different attitudes and preferences of stakeholders can modify the effectiveness of alternatives obtained via classic optimization approaches that do not include the influence of existing social attitudes in a watershed during the search process. Results show that for Eagle Creek Watershed in central Indiana, USA, the most optimal alternatives (i.e., highest benefits for minimum economic costs) are for a scenario when the watershed consists of landowners who operate as farmers on their own land. When a different land-tenure scenario was used for the watershed (e.g., share renters and cash renters), the optimized alternatives had similar nitrate reduction benefits and sediment reduction benefits, but at higher economic costs. Our experiments also demonstrated that social attitudes can lead to alteration of optimized alternatives found via typical optimization approaches. For example, when certain practices were rejected by landowner operators whose attitudes toward practices were driven by economic profits, removal of these practices from the optimized alternatives led to a setback of nitrates reduction by 2-50%, peak flow reductions by 11-98 %, and sediments reduction by 20-77%. In conclusion, this study reveals the potential loss in optimality of optimized alternatives possible, when socioeconomic data on farmer preferences and land tenure are not incorporated within watershed optimization investigations. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_9");'>9</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li class="active">11</li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_12" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li class="active">12</li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="221"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=163405&Lab=NERL&keyword=erickson&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=163405&Lab=NERL&keyword=erickson&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">INTERACTIVE EFFECTS OF SOLAR UV RADIATION AND CLIMATE CHANGE ON BIOGEOCHEMICAL CYCLING</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> This paper assesses research on the interactions of UV radiation (280-400 nm) and global climate change with global biogeochemical cycles at the Earth's surface. The effects of UV-B (280-315 nm), which are dependent on the stratospheric ozone layer, on biogeochemical cycles are o... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B23E0643J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B23E0643J">Effect of dissimilatory iron and sulfate reduction on arsenic dynamics in the wetland rhizosphere and its bioaccumulation in plants</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jaffe, P. R.; Zhang, Z.; Moon, H. S.; Myneni, S. 2015-12-01 The mobility of arsenic in soils is linked to biogeochemical redox processes. The presence of wetland plants in riparian wetlands has a significant impact on the biogeochemical dynamics of the soil/sediment-redoxcline due to the release of root exudates and root turnover and oxygen transfer from the roots into the surrounding sediment. Micro-environmental redox conditions in the rhizosphere affect As, Fe, and S speciation as well as Fe(III) plaque deposition, which affects arsenic transport and uptake by plants. To investigate the dynamics of As coupled to S and Fe cycling in wetlands, mesocosms were operated in a greenhouse under various conditions (high and low Fe, high and low sulfate, with plant and without plants) for four months. Results show that the presence of plants, high Fe, and high SO42- levels enhanced As sequestration in these soils. We hypothesize that this compounding effect is because plants release biodegradable organic carbon, which is used by microorganism to reduce ferrihydrite and SO42- to generate FeS, FeS2, and/or orpiment (As2S3). Over the concentration range studied, As immobilization in soil and uptake by Scirpus actus was mainly controlled by SO42- rather than Fe levels. Under high sulfate levels, As immobilization in soil increased by 50% and As concentrations in plant roots increased by 97%, whereas no significant changes in plant As levels were seen for varying Fe concentrations. More than 80% of As was sequestrated in soils rather than plant uptake. Pore water As speciation analyses indicate that 20% more As(V) was reduced to As(III) under high sulfate as than low sulfate levels and that low Fe was more favorable to the As dissimilatory reduction. More dissimilatory arsenate-respiring bacteria (DARB) under high sulfate were confirmed by quantitative PCR. Arsenic distribution in plant leafs and roots after 30 days of exposure to As was analyzed via Synchrotron X-ray fluorescence analyses. The uptake of As by plants was distributed along leaf veins. The distribution of As in roots was correlated with the distribution of Fe in the roots, rather than with Ca or Zn. These observations expand our understanding of how Fe and S influences microbial As redox metabolisms and provide insights into the biogeochemical coupling between As and S as well as Fe in As contaminated wetlands. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSME23A..08H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSME23A..08H">Biogeochemical provinces in the global ocean based on phytoplankton growth limitation</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hashioka, T.; Hirata, T.; Aita, M. N.; Chiba, S. 2016-02-01 The biogeochemical province is one of the useful concepts for the comprehensive understanding of regional differences of the marine ecosystem. Various biogeochemical provinces for lower-trophic level ecosystem have been proposed using a similarity-based classification of seasonal variations of chl-a concentration typified by Longhurst 1995 and 2006. Such categorizations well capture the regional differences of seasonality as "total phytoplankton". However, background biogeochemical mechanism to characterize the province boundary is not clear. Namely, the dominant phytoplankton group is different among regions and seasons, and their physiological characteristics are significantly different among groups. Recently some pieces of new biogeochemical information are available. One is an estimation of phytoplankton community structure from satellite observation, and it makes clear the key phytoplankton type in each region. Another is an estimation of limitation factors for phytoplankton growth (e.g., nutrients, temperature, light) in each region from modeling studies. In this study, we propose new biogeochemical provinces as a combination between the dominance of phytoplankton (i.e., diatoms, nano-, pico-phytoplankton or coexistence of two/three types) and their growth limitation factors (particularly we focused on nutrient limitation; N, P, Si or Fe). In this combination, we classified the global ocean into 23 biogeochemical provinces. The result suggests that even if the same type of phytoplankton dominates, the background mechanism could be different among regions. On the contrary, even if the regions geographically separate, the background mechanism could be similar among regions. This is important to understand that region/boundary does respond to environmental change. This biogeochemical province is useful for identification of key areas for future observation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/27214','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/27214">A method to efficiently apply a biogeochemical model to a landscape.</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Robert E. Kennedy; David P. Turner; Warren B. Cohen; Michael Guzy 2006-01-01 Biogeochemical models offer an important means of understanding carbon dynamics, but the computational complexity of many models means that modeling all grid cells on a large landscape is computationally burdensome. Because most biogeochemical models ignore adjacency effects between cells, however, a more efficient approach is possible. Recognizing that spatial... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/43585','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/43585">Consequences of climate change for biogeochemical cycling in forests of northeastern North America</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> John L. Campbell; Lindsey E. Rustad; Elizabeth W. Boyer; Sheila F. Christopher; Charles T. Driscoll; Ivan .J. Fernandez; Peter M. Groffman; Daniel Houle; Jana Kiekbusch; Alison H. Magill; Myron J. Mitchell; Scott V. Ollinger 2009-01-01 A critical component of assessing the impacts of climate change on forest ecosystems involves understanding associated changes in biogeochemical cycling of elements. Evidence from research on northeastern North American forests shows that direct effects of climate change will evoke changes in biogeochemical cycling by altering plant physiology forest productivity, and... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H43J1366K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H43J1366K">Biogeochemical and hydrological controls on fate and distribution of trace metals in oiled Gulf salt marshes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Keevan, J.; Natter, M.; Lee, M.; Keimowitz, A.; Okeke, B.; Savrda, C.; Saunders, J. 2011-12-01 On April 20, 2010, the drilling rig Deepwater Horizon exploded in the Gulf of Mexico, resulting in the release of approximately 5 million barrels of crude oil into the environment. Oil and its associated trace metals have been demonstrated to have a detrimental effect on coastal wetland ecosystems. Wetlands are particularly susceptible to oil contamination because they are composed largely of fine-grained sediments, which have a high capacity to adsorb organic matter and metals. The biogeochemical cycling of trace metals can be strongly influenced by microbial activity, specifically those of sulfate- and iron-reducing bacteria. Microbial activity may be enhanced by an increase in amounts of organic matter such as oil. This research incorporates an assessment of levels of trace metals and associated biogeochemical changes from ten coastal marshes in Alabama, Mississippi, and Louisiana. These sampling sites range in their pollution levels from pristine to highly contaminated. A total digestion analysis of wetland sediments shows higher concentrations of certain trace metals (e.g., Ni, Cu, Pb, Zn, Sr, Co, V, Ba, Hg, As) in heavily-oiled areas compared to less-affected and pristine sites. Due to chemical complexation among organic compounds and metals, crude oils often contain elevated levels (up to hundreds of mg/kg) of trace metals At the heavily-oiled Louisiana sites (e.g., Bay Jimmy, Bayou Dulac, Bay Batiste), elevated levels of metals and total organic carbon have been found in sediments down to depths of 30 cm. Clearly the contamination is not limited to shallow sediments and oil, along with various associated metals, may be invading into deeper (pre-industrial) portions of the marsh sediments. Pore-waters extracted from contaminated sediments are characterized by very high levels of reduced sulfur (up to 80 mg/kg), in contrast to fairly low ferrous iron concentrations (<0.02 mg/kg). The influx of oil into the wetlands might provide the initial substrate and carbon source for stimulating sulfate-reducing bacteria. The high sulfur levels, coupled with the low levels of iron, indicate that iron-reducing bacteria are outcompeted by sulfate reducers in oiled salt marshes. Moreover, pore-water pH values show a general increasing trend (ranging from 6.6 to 8.0) with depth, possibly reflecting the combined effects of bacterial sulfate reduction and saltwater intrusion at depth. Despite high levels of trace metals in bulk sediments, concentrations of trace metals dissolved in pore-waters are generally low. It is very likely that high organic matter content and bacterially-mediated sulfate reduction promote metal retention through the formation of sulfide solids. Framboidal pyrites, as well as other sulfides, have been identified, and are currently undergoing XRD, SEM, and EDAX analyses. Continued research is needed to monitor possible re-mobilization of trace metals in changing redox and biogeochemical conditions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19840022596','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19840022596">Global Biology Research Program: Biogeochemical Processes in Wetlands</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Bartlett, D. S. (Editor) 1984-01-01 The results of a workshop examining potential NASA contributions to research on wetland processes as they relate to global biogeochemical cycles are summarized. A wetlands data base utilizing remotely sensed inventories, studies of wetland/atmosphere exchange processes, and the extrapolation of local measurements to global biogeochemical cycling processes were identified as possible areas for NASA support. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015JMS...148..112S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015JMS...148..112S">Decadal biogeochemical history of the south east Levantine basin: Simulations of the river Nile regimes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Suari, Yair; Brenner, Steve 2015-08-01 The south eastern Mediterranean is characterized by antiestuarine circulation which leads to extreme oligotrophic conditions. The Nile river that used to transport fresh water and nutrients into the basin was dammed in 1964 which led to a drastic reduction of fresh water fluxes, and later, changes in Egyptian agriculture and diet led to increased nutrient fluxes. In this paper we present the results of simulations with a biogeochemical model of the south eastern Mediterranean. Four experiments were conducted: (1) present day without riverine inputs; (2) Nile before damming (pre-1964); (3) post-damming 1995 Nile; and (4) fresh water and nutrient discharges of Israeli coastal streams. The present day input simulation (control run) successfully reproduced measured nutrient concentrations, with the exception of simulated chlorophyll concentrations which were slightly higher than observed. The pre-1964 Nile simulation showed a salinity reduction of 2 psu near the Egyptian coast and 0.5 psu along the Israeli coast, as well as elevated chlorophyll a concentrations mostly east of the Nile delta and north to Cyprus. The spring bloom extended from its present peak during February-March to a peak during February-May. The 1995 Nile simulation showed increased chlorophyll a concentrations close to the Egyptian coast. The Israeli coastal stream simulation showed that the effect of the Israeli coastal stream winter flow on chlorophyll converged to control concentrations within about one month, demonstrating the stability and sensitivity of the model to external forcing. The results of this study demonstrate the significance of fresh water fluxes in maintaining marine productivity, which may have large scale effects on the marine ecosystem. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JAESc.149..172H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JAESc.149..172H">Biogeochemical cycles at the sulfate-methane transition zone (SMTZ) and geochemical characteristics of the pore fluids offshore southwestern Taiwan</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hu, Ching-Yi; Frank Yang, Tsanyao; Burr, George S.; Chuang, Pei-Chuan; Chen, Hsuan-Wen; Walia, Monika; Chen, Nai-Chen; Huang, Yu-Chun; Lin, Saulwood; Wang, Yunshuen; Chung, San-Hsiung; Huang, Chin-Da; Chen, Cheng-Hong 2017-11-01 In this study, we used pore water dissolved inorganic carbon (DIC), SO42-, Ca2+ and Mg2+ gradients at the sulfate-methane transition zone (SMTZ) to estimate biogeochemical fluxes for cored sediments collected offshore SW Taiwan. Net DIC flux changes (ΔDIC-Prod) were applied to determine the proportion of sulfate consumption by organic matter oxidation (heterotrophic sulfate reduction) and anaerobic oxidation of methane (AOM), and to determine reliable CH4 fluxes at the SMTZ. Our results show that SO42- profiles are mainly controlled by AOM rather than heterotrophic sulfate reduction. Refinement of CH4 flux estimates enhance our understanding of methane abundance from deep carbon reservoirs to the SMTZ. Concentrations of chloride (Cl-), bromide (Br-) and iodide (I-) dissolved in pore water were used to identify potential sources that control fluid compositions and the behavior of dissolved ions. Constant Cl- concentrations throughout ∼30 m sediment suggest no influence of gas hydrates for the compositions within the core. Bromide (Br-) and Iodine (I-) concentrations increase with sediment depth. The I-/Br- ratio appears to reflect organic matter degradation. SO42- concentrations decrease with sediment depth at a constant rate, and sediment depth profiles of Br- and I- concentrations suggests diffusion as the main transport mechanism. Therefore diffusive flux calculations are reasonable. Coring sites with high CH4 fluxes are more common in the accretionary wedge, amongst thrust faults and fractures, than in the passive continental margin offshore southwestern Taiwan. AOM reactions are a major sink for CH4 passing upward through the SMTZ and prevent high methane fluxes in the water column and to the atmosphere. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70039049','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70039049">Soil property control of biogeochemical processes beneath two subtropical stormwater infiltration basins</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> O'Reilly, Andrew M.; Wanielista, Martin P.; Chang, Ni-Bin; Harris, Willie G.; Xuan, Zhemin 2012-01-01 Substantially different biogeochemical processes affecting nitrogen fate and transport were observed beneath two stormwater infiltration basins in north-central Florida. Differences are related to soil textural properties that deeply link hydroclimatic conditions with soil moisture variations in a humid, subtropical climate. During 2008, shallow groundwater beneath the basin with predominantly clayey soils (median, 41% silt+clay) exhibited decreases in dissolved oxygen from 3.8 to 0.1 mg L-1 and decreases in nitrate nitrogen (NO3-–N) from 2.7 mg L-1 to -1, followed by manganese and iron reduction, sulfate reduction, and methanogenesis. In contrast, beneath the basin with predominantly sandy soils (median, 2% silt+clay), aerobic conditions persisted from 2007 through 2009 (dissolved oxygen, 5.0–7.8 mg L-1), resulting in NO3-–N of 1.3 to 3.3 mg L-1 in shallow groundwater. Enrichment of d15N and d18O of NO3- combined with water chemistry data indicates denitrification beneath the clayey basin and relatively conservative NO3- transport beneath the sandy basin. Soil-extractable NO3-–N was significantly lower and the copper-containing nitrite reductase gene density was significantly higher beneath the clayey basin. Differences in moisture retention capacity between fine- and coarse-textured soils resulted in median volumetric gas-phase contents of 0.04 beneath the clayey basin and 0.19 beneath the sandy basin, inhibiting surface/subsurface oxygen exchange beneath the clayey basin. Results can inform development of soil amendments to maintain elevated moisture content in shallow soils of stormwater infiltration basins, which can be incorporated in improved best management practices to mitigate NO3- impacts. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5066559','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5066559">Microbial Mat Compositional and Functional Sensitivity to Environmental Disturbance</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Preisner, Eva C.; Fichot, Erin B.; Norman, Robert S. 2016-01-01 The ability of ecosystems to adapt to environmental perturbations depends on the duration and intensity of change and the overall biological diversity of the system. While studies have indicated that rare microbial taxa may provide a biological reservoir that supports long-term ecosystem stability, how this dynamic population is influenced by environmental parameters remains unclear. In this study, a microbial mat ecosystem located on San Salvador Island, The Bahamas was used as a model to examine how environmental disturbance affects the protein synthesis potential (PSP) of rare and abundant archaeal and bacterial communities and how these changes impact potential biogeochemical processes. This ecosystem experienced a large shift in salinity (230 to 65 g kg-1) during 2011–2012 following the landfall of Hurricane Irene on San Salvador Island. High throughput sequencing and analysis of 16S rRNA and rRNA genes from samples before and after the pulse disturbance showed significant changes in the diversity and PSP of abundant and rare taxa, suggesting overall compositional and functional sensitivity to environmental change. In both archaeal and bacterial communities, while the majority of taxa showed low PSP across conditions, the overall community PSP increased post-disturbance, with significant shifts occurring among abundant and rare taxa across and within phyla. Broadly, following the post-disturbance reduction in salinity, taxa within Halobacteria decreased while those within Crenarchaeota, Thaumarchaeota, Thermoplasmata, Cyanobacteria, and Proteobacteria, increased in abundance and PSP. Quantitative PCR of genes and transcripts involved in nitrogen and sulfur cycling showed concomitant shifts in biogeochemical cycling potential. Post-disturbance conditions increased the expression of genes involved in N-fixation, nitrification, denitrification, and sulfate reduction. Together, our findings show complex community adaptation to environmental change and help elucidate factors connecting disturbance, biodiversity, and ecosystem function that may enhance ecosystem models. PMID:27799927 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B43C0633Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B43C0633Z">Biogeochemical controls on microbial CH4 and CO2 production in Arctic polygon tundra</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zheng, J. 2016-12-01 Accurately simulating methane (CH4) and carbon dioxide (CO2) emissions from high latitude soils is critically important for reducing uncertainties in soil carbon-climate feedback predictions. The signature polygonal ground of Arctic tundra generates high level of heterogeneity in soil thermal regime, hydrology and oxygen availability, which limits the application of current land surface models with simple moisture response functions. We synthesized CH4 and CO2 production measurements from soil microcosm experiments across a wet-to dry permafrost degradation gradient from low-centered (LCP) to flat-centered (FCP), and high-centered polygons (HCP) to evaluate the relative importance of biogeochemical processes and their response to warming. More degraded polygon (HCP) showed much less carbon loss as CO2 or CH4, while the total CO2 production from FCP is comparable to that from LCP. Maximum CH4 production from the active layer of LCP was nearly 10 times that of permafrost and FCP. Multivariate analyses identifies gravimetric water content and organic carbon content as key predictors for CH4 production, and iron reduction as a key regulator of pH. The synthesized data are used to validate the geochemical model PHREEQC with extended anaerobic organic substrate turnover, fermentation, iron reduction, and methanogenesis reactions. Sensitivity analyses demonstrate that better representations of anaerobic processes and their pH dependency could significantly improve estimates of CH4 and CO2 production. The synthesized data suggest local decreases in CH4 production along the polygon degradation gradient, which is consistent with previous surface flux measurements. Methane oxidation occurring through the soil column of degraded polygons contributes to their low CH4 emissions as well. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22370419','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22370419">Soil property control of biogeochemical processes beneath two subtropical stormwater infiltration basins.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> O'Reilly, Andrew M; Wanielista, Martin P; Chang, Ni-Bin; Harris, Willie G; Xuan, Zhemin 2012-01-01 Substantially different biogeochemical processes affecting nitrogen fate and transport were observed beneath two stormwater infiltration basins in north-central Florida. Differences are related to soil textural properties that deeply link hydroclimatic conditions with soil moisture variations in a humid, subtropical climate. During 2008, shallow groundwater beneath the basin with predominantly clayey soils (median, 41% silt+clay) exhibited decreases in dissolved oxygen from 3.8 to 0.1 mg L and decreases in nitrate nitrogen (NO-N) from 2.7 mg L to <0.016 mg L, followed by manganese and iron reduction, sulfate reduction, and methanogenesis. In contrast, beneath the basin with predominantly sandy soils (median, 2% silt+clay), aerobic conditions persisted from 2007 through 2009 (dissolved oxygen, 5.0-7.8 mg L), resulting in NO-N of 1.3 to 3.3 mg L in shallow groundwater. Enrichment of δN and δO of NO combined with water chemistry data indicates denitrification beneath the clayey basin and relatively conservative NO transport beneath the sandy basin. Soil-extractable NO-N was significantly lower and the copper-containing nitrite reductase gene density was significantly higher beneath the clayey basin. Differences in moisture retention capacity between fine- and coarse-textured soils resulted in median volumetric gas-phase contents of 0.04 beneath the clayey basin and 0.19 beneath the sandy basin, inhibiting surface/subsurface oxygen exchange beneath the clayey basin. Results can inform development of soil amendments to maintain elevated moisture content in shallow soils of stormwater infiltration basins, which can be incorporated in improved best management practices to mitigate NO impacts. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70033555','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70033555">Porewater biogeochemistry and soil metabolism in dwarf red mangrove habitats (Twin Cays, Belize)</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Lee, R.Y.; Porubsky, W.P.; Feller, Ilka C.; McKee, K.L.; Joye, S.B. 2008-01-01 Seasonal variability in biogeochemical signatures was used to elucidate the dominant pathways of soil microbial metabolism and elemental cycling in an oligotrophic mangrove system. Three interior dwarf mangrove habitats (Twin Cays, Belize) where surface soils were overlain by microbial mats were sampled during wet and dry periods of the year. Porewater equilibration meters and standard biogeochemical methods provided steady-state porewater profiles of pH, chloride, sulfate, sulfide, ammonium, nitrate/nitrite, phosphate, dissolved organic carbon, nitrogen, and phosphorus, reduced iron and manganese, dissolved inorganic carbon, methane and nitrous oxide. During the wet season, the salinity of overlying pond water and shallow porewaters decreased. Increased rainwater infiltration through soils combined with higher tidal heights appeared to result in increased organic carbon inventories and more reducing soil porewaters. During the dry season, evaporation increased both surface water and porewater salinities, while lower tidal heights resulted in less reduced soil porewaters. Rainfall strongly influenced inventories of dissolved organic carbon and nitrogen, possibly due to more rapid decay of mangrove litter during the wet season. During both times of year, high concentrations of reduced metabolites accumulated at depth, indicating substantial rates of organic matter mineralization coupled primarily to sulfate reduction. Nitrous oxide and methane concentrations were supersaturated indicating considerable rates of nitrification and/or incomplete denitrification and methanogenesis, respectively. More reducing soil conditions during the wet season promoted the production of reduced manganese. Contemporaneous activity of sulfate reduction and methanogenesis was likely fueled by the presence of noncompetitive substrates. The findings indicate that these interior dwarf areas are unique sites of nutrient and energy regeneration and may be critical to the overall persistence and productivity of mangrove-dominated islands in oligotrophic settings. ?? 2008 Springer Science+Business Media B.V. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70126405','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70126405">Biogeochemical environments of streambed-sediment pore waters withand without arsenic enrichment in a sedimentary rock terrain, New Jersey Piedmont, USA</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Mumford, Adam C.; Barringer, Julia L.; Reilly, Pamela A.; Eberl, Dennis D.; Blum, Alex E.; Young, Lily Y. 2015-01-01 Release of arsenic (As) from sedimentary rocks has resulted in contamination of groundwater in aquifers of the New Jersey Piedmont Physiographic Province, USA; the contamination also may affect the quality of the region's streamwater to which groundwater discharges. Biogeochemical mechanisms involved in the release process were investigated in the streambeds of Six Mile Run and Pike Run, tributaries to the Millstone River in the Piedmont. At Six Mile Run, streambed pore water and shallow groundwater were low or depleted in oxygen, and contained As at concentrations greater than 20μg/L. At Pike Run, oxidizing conditions were present in the streambed, and the As concentration in pore water was 2.1μg/L. The 16S rRNA gene and the As(V) respiratory reductase gene, arrA, were amplified from DNA extracted from streambed pore water at both sites and analyzed, revealing that distinct bacterial communities that corresponded to the redox conditions were present at each site. Anaerobic enrichment cultures were inoculated with pore water from gaining reaches of the streams with acetate and As(V). As(V) was reduced by microbes to As(III) in enrichments with Six Mile Run pore water and groundwater, whereas no reduction occurred in enrichments with Pike Run pore water. Cloning and sequencing of the arrA gene indicated 8 unique operational taxonomic units (OTUs) at Six Mile Run and 11 unique OTUs at Pike Run, which may be representative of the arsenite oxidase gene arxA. Low-oxygen conditions at Six Mile Run have favored microbial As reduction and release, whereas release was inhibited by oxidizing conditions at Pike Run. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70033252','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70033252">Determination of dominant biogeochemical processes in a contaminated aquifer-wetland system using multivariate statistical analysis</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Baez-Cazull, S. E.; McGuire, J.T.; Cozzarelli, I.M.; Voytek, M.A. 2008-01-01 Determining the processes governing aqueous biogeochemistry in a wetland hydrologically linked to an underlying contaminated aquifer is challenging due to the complex exchange between the systems and their distinct responses to changes in precipitation, recharge, and biological activities. To evaluate temporal and spatial processes in the wetland-aquifer system, water samples were collected using cm-scale multichambered passive diffusion samplers (peepers) to span the wetland-aquifer interface over a period of 3 yr. Samples were analyzed for major cations and anions, methane, and a suite of organic acids resulting in a large dataset of over 8000 points, which was evaluated using multivariate statistics. Principal component analysis (PCA) was chosen with the purpose of exploring the sources of variation in the dataset to expose related variables and provide insight into the biogeochemical processes that control the water chemistry of the system. Factor scores computed from PCA were mapped by date and depth. Patterns observed suggest that (i) fermentation is the process controlling the greatest variability in the dataset and it peaks in May; (ii) iron and sulfate reduction were the dominant terminal electron-accepting processes in the system and were associated with fermentation but had more complex seasonal variability than fermentation; (iii) methanogenesis was also important and associated with bacterial utilization of minerals as a source of electron acceptors (e.g., barite BaSO4); and (iv) seasonal hydrological patterns (wet and dry periods) control the availability of electron acceptors through the reoxidation of reduced iron-sulfur species enhancing iron and sulfate reduction. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29172040','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29172040">Effect of long-term fertilization on humic redox mediators in multiple microbial redox reactions.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Guo, Peng; Zhang, Chunfang; Wang, Yi; Yu, Xinwei; Zhang, Zhichao; Zhang, Dongdong 2018-03-01 This study investigated the effects of different long-term fertilizations on humic substances (HSs), humic acids (HAs) and humins, functioning as redox mediators for various microbial redox biotransformations, including 2,2',4,4',5,5'- hexachlorobiphenyl (PCB 153 ) dechlorination, dissimilatory iron reduction, and nitrate reduction, and their electron-mediating natures. The redox activity of HSs for various microbial redox metabolisms was substantially enhanced by long-term application of organic fertilizer (pig manure). As a redox mediator, only humin extracted from soils with organic fertilizer amendment (OF-HM) maintained microbial PCB 153 dechlorination activity (1.03 μM PCB 153 removal), and corresponding HA (OF-HA) most effectively enhanced iron reduction and nitrate reduction by Shewanella putrefaciens. Electrochemical analysis confirmed the enhancement of their electron transfer capacity and redox properties. Fourier transform infrared analysis showed that C=C and C=O bonds, and carboxylic or phenolic groups in HSs might be the redox functional groups affected by fertilization. This research enhances our understanding of the influence of anthropogenic fertility on the biogeochemical cycling of elements and in situ remediation ability in agroecosystems through microorganisms' metabolisms. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70021217','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70021217">Selenium isotope ratios as indicators of selenium sources and oxyanion reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Johnson, T.M.; Herbel, M.J.; Bullen, T.D.; Zawislanski, P.T. 1999-01-01 Selenium stable isotope ratio measurements should serve as indicators of sources and biogeochemical transformations of Se. We report measurements of Se isotope fractionation during selenate reduction, selenite sorption, oxidation of reduced Se in soils, and Se volatilization by algae and soil samples. These results, combined with previous work with Se isotopes, indicate that reduction of soluble oxyanions is the dominant cause of Se isotope fractionation. Accordingly, Se isotope ratios should be useful as indicators of oxyanion reduction, which can transform mobile species to forms that are less mobile and less bioavailable. Additional investigations of Se isotope fractionation are needed to confirm this preliminary assessment. We have developed a new method for measurement of natural Se isotope ratio variation which requires less than 500 ng Se per analysis and yields ??0.2??? precision on 80Se/76Se. A double isotope spike technique corrects for isotopic fractionation during sample preparation and mass spectrometry. The small minimum sample size is important, as Se concentrations are often below 1 ppm in solids and 1 ??g/L in fluids. The Se purification process is rapid and compatible with various sample matrices, including acidic rock or sediment digests. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/20000935-selenium-isotope-ratios-indicators-selenium-sources-oxyanion-reduction','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/20000935-selenium-isotope-ratios-indicators-selenium-sources-oxyanion-reduction">Selenium isotope ratios as indicators of selenium sources and oxyanion reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Johnson, T.M.; Herbel, M.J.; Bullen, T.D. 1999-09-01 Selenium stable isotope ratio measurements should serve as indicators of sources and biogeochemical transformations of Se. The authors report measurements of Se isotope fractionation during selenate reduction, selenite sorption, oxidation of reduced Se in soils, and Se volatilization by algae and soil samples. These results, combined with previous work with Se isotopes, indicate that reduction of soluble oxyanions is the dominant cause of Se isotope fractionation. Accordingly, Se isotope ratios should be useful as indicators of oxyanion reduction, which can transform mobile species to forms that are less mobile and less bioavailable. Additional investigations of Se isotope fractionation are neededmore » to confirm this preliminary assessment. The authors have developed a new method for measurement of natural Se isotope ratio variation which requires less than 500 ng Se per analysis and yields {+-}0.2% precision on {sup 80}Se/{sup 76}Se. A double isotope spike technique corrects for isotopic fractionation during sample preparation and mass spectrometry. The small minimum sample size is important, as Se concentrations are often below 1 ppm in solids and 1 {micro}g/L in fluids. The Se purification process is rapid and compatible with various sample matrices, including acidic rock or sediment digests.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H34H..06M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H34H..06M">Green Infrastructure Increases Biogeochemical Responsiveness, Vegetation Growth and Decreases Runoff in a Semi-Arid City, Tucson, AZ, USA</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Meixner, T.; Papuga, S. A.; Luketich, A. M.; Rockhill, T.; Gallo, E. L.; Anderson, J.; Salgado, L.; Pope, K.; Gupta, N.; Korgaonkar, Y.; Guertin, D. P. 2017-12-01 Green Infrastructure (GI) is often viewed as a mechanism to minimize the effects of urbanization on hydrology, water quality, and other ecosystem services (including the urban heat island). Quantifying the effects of GI requires field measurements of the dimensions of biogeochemical, ecosystem, and hydrologic function that we expect GI to impact. Here we investigated the effect of GI features in Tucson, Arizona which has a low intensity winter precipitation regime and a high intensity summer regime. We focused on understanding the effect of GI on soil hydraulic and biogeochemical properties as well as the effect on vegetation and canopy temperature. Our results demonstrate profound changes in biogeochemical and hydrologic properties and vegetation growth between GI systems and nearby control sites. In terms of hydrologic properties GI soils had increased water holding capacity and hydraulic conductivity. GI soils also have higher total carbon, total nitrogen, and organic matter in general than control soils. Furthermore, we tested the sampled soils (control and GI) for differences in biogeochemical response upon wetting. GI soils had larger respiration responses indicating greater biogeochemical activity overall. Long-term Lidar surveys were used to investigate the differential canopy growth of GI systems versus control sites. The results of this analysis indicate that while a significant amount of time is needed to observe differences in canopy growth GI features due increase tree size and thus likely impact street scale ambient temperatures. Additionally monitoring of transpiration, soil moisture, and canopy temperature demonstrates that GI features increase vegetation growth and transpiration and reduce canopy temperatures. These biogeochemical and ecohydrologic results indicate that GI can increase the biogeochemical processing of soils and increase tree growth and thus reduce urban ambient temperatures. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_10");'>10</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li class="active">12</li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_13" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li class="active">13</li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="241"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013GMDD....6.3211F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013GMDD....6.3211F">A generic biogeochemical module for earth system models</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fang, Y.; Huang, M.; Liu, C.; Li, H.-Y.; Leung, L. R. 2013-06-01 Physical and biogeochemical processes regulate soil carbon dynamics and CO2 flux to and from the atmosphere, influencing global climate changes. Integration of these processes into earth system models (e.g. community land models - CLM), however, currently faces three major challenges: (1) extensive efforts are required to modify modeling structures and to rewrite computer programs to incorporate new or updated processes as new knowledge is being generated, (2) computational cost is prohibitively expensive to simulate biogeochemical processes in land models due to large variations in the rates of biogeochemical processes, and (3) various mathematical representations of biogeochemical processes exist to incorporate different aspects of fundamental mechanisms, but systematic evaluation of the different mathematical representations is difficult, if not impossible. To address these challenges, we propose a new computational framework to easily incorporate physical and biogeochemical processes into land models. The new framework consists of a new biogeochemical module with a generic algorithm and reaction database so that new and updated processes can be incorporated into land models without the need to manually set up the ordinary differential equations to be solved numerically. The reaction database consists of processes of nutrient flow through the terrestrial ecosystems in plants, litter and soil. This framework facilitates effective comparison studies of biogeochemical cycles in an ecosystem using different conceptual models under the same land modeling framework. The approach was first implemented in CLM and benchmarked against simulations from the original CLM-CN code. A case study was then provided to demonstrate the advantages of using the new approach to incorporate a phosphorus cycle into the CLM model. To our knowledge, the phosphorus-incorporated CLM is a new model that can be used to simulate phosphorus limitation on the productivity of terrestrial ecosystems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B31H0565S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B31H0565S">Quantifying Hydro-biogeochemical Model Sensitivity in Assessment of Climate Change Effect on Hyporheic Zone Processes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Song, X.; Chen, X.; Dai, H.; Hammond, G. E.; Song, H. S.; Stegen, J. 2016-12-01 The hyporheic zone is an active region for biogeochemical processes such as carbon and nitrogen cycling, where the groundwater and surface water mix and interact with each other with distinct biogeochemical and thermal properties. The biogeochemical dynamics within the hyporheic zone are driven by both river water and groundwater hydraulic dynamics, which are directly affected by climate change scenarios. Besides that, the hydraulic and thermal properties of local sediments and microbial and chemical processes also play important roles in biogeochemical dynamics. Thus for a comprehensive understanding of the biogeochemical processes in the hyporheic zone, a coupled thermo-hydro-biogeochemical model is needed. As multiple uncertainty sources are involved in the integrated model, it is important to identify its key modules/parameters through sensitivity analysis. In this study, we develop a 2D cross-section model in the hyporheic zone at the DOE Hanford site adjacent to Columbia River and use this model to quantify module and parametric sensitivity on assessment of climate change. To achieve this purpose, We 1) develop a facies-based groundwater flow and heat transfer model that incorporates facies geometry and heterogeneity characterized from a field data set, 2) derive multiple reaction networks/pathways from batch experiments with in-situ samples and integrate temperate dependent reactive transport modules to the flow model, 3) assign multiple climate change scenarios to the coupled model by analyzing historical river stage data, 4) apply a variance-based global sensitivity analysis to quantify scenario/module/parameter uncertainty in hierarchy level. The objectives of the research include: 1) identifing the key control factors of the coupled thermo-hydro-biogeochemical model in the assessment of climate change, and 2) quantify the carbon consumption in different climate change scenarios in the hyporheic zone. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H41F1516D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H41F1516D">Stream biogeochemical resilience in the age of Anthropocene</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dong, H.; Creed, I. F. 2017-12-01 Recent evidence indicates that biogeochemical cycles are being pushed beyond the tolerance limits of the earth system in the age of the Anthropocene placing terrestrial and aquatic ecosystems at risk. Here, we explored the question: Is there empirical evidence of global atmospheric changes driving losses in stream biogeochemical resilience towards a new normal? Stream biogeochemical resilience is the process of returning to equilibrium conditions after a disturbance and can be measured using three metrics: reactivity (the highest initial response after a disturbance), return rate (the rate of return to equilibrium condition after reactive changes), and variance of the stationary distribution (the signal to noise ratio). Multivariate autoregressive models were used to derive the three metrics for streams along a disturbance gradient - from natural systems where global drivers would dominate, to relatively managed or modified systems where global and local drivers would interact. We observed a loss of biogeochemical resilience in all streams. The key biogeochemical constituent(s) that may be driving loss of biogeochemical resilience were identified from the time series of the stream biogeochemical constituents. Non-stationary trends (detected by Mann-Kendall analysis) and stationary cycles (revealed through Morlet wavelet analysis) were removed, and the standard deviation (SD) of the remaining residuals were analyzed to determine if there was an increase in SD over time that would indicate a pending shift towards a new normal. We observed that nitrate-N and total phosphorus showed behaviours indicative of a pending shift in natural and managed forest systems, but not in agricultural systems. This study provides empirical support that stream ecosystems are showing signs of exceeding planetary boundary tolerance levels and shifting towards a "new normal" in response to global changes, which can be exacerbated by local management activities. Future work will consider the potential for cascading effects on downstream systems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23135396','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23135396">Zero-valent sulphur is a key intermediate in marine methane oxidation.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Milucka, Jana; Ferdelman, Timothy G; Polerecky, Lubos; Franzke, Daniela; Wegener, Gunter; Schmid, Markus; Lieberwirth, Ingo; Wagner, Michael; Widdel, Friedrich; Kuypers, Marcel M M 2012-11-22 Emissions of methane, a potent greenhouse gas, from marine sediments are controlled by anaerobic oxidation of methane coupled primarily to sulphate reduction (AOM). Sulphate-coupled AOM is believed to be mediated by a consortium of methanotrophic archaea (ANME) and sulphate-reducing Deltaproteobacteria but the underlying mechanism has not yet been resolved. Here we show that zero-valent sulphur compounds (S(0)) are formed during AOM through a new pathway for dissimilatory sulphate reduction performed by the methanotrophic archaea. Hence, AOM might not be an obligate syntrophic process but may be carried out by the ANME alone. Furthermore, we show that the produced S(0)--in the form of disulphide--is disproportionated by the Deltaproteobacteria associated with the ANME. Our observations expand the diversity of known microbially mediated sulphur transformations and have significant implications for our understanding of the biogeochemical carbon and sulphur cycles. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70099919','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70099919">Floodplain biogeochemical processing of floodwaters in the Atchafalaya River Basin during the Mississippi River flood of 2011</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Scott, Durelle T.; Keim, Richard F.; Edwards, Brandon L.; Jones, C. Nathan; Kroes, Daniel E. 2014-01-01 The 2011 flood in the Lower Mississippi resulted in the second highest recorded river flow diverted into the Atchafalaya River Basin (ARB). The higher water levels during the flood peak resulted in high hydrologic connectivity between the Atchafalaya River and floodplain, with up to 50% of the Atchafalaya River water moving off channel. Water quality samples were collected throughout the ARB over the course of the flood event. Significant nitrate (NO3-) reduction (75%) occurred within the floodplain, resulting in a total NO3- reduction of 16.6% over the flood. The floodplain was a small but measurable source of dissolved reactive phosphorus (SRP) and ammonium (NH4+). Collectively, these results from this large flood event suggest that enhancing river-floodplain connectivity through freshwater diversions will reduce NO3- loads to the Gulf of Mexico during large annual floods. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1014221-thinking-outside-channel-modeling-nitrogen-cycling-networked-river-ecosystems','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1014221-thinking-outside-channel-modeling-nitrogen-cycling-networked-river-ecosystems">Thinking outside the channel: Modeling nitrogen cycling in networked river ecosystems</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Helton, Ashley; Poole, Geoffrey C.; Meyer, Judy 2011-01-01 Agricultural and urban development alters nitrogen and other biogeochemical cycles in rivers worldwide. Because such biogeochemical processes cannot be measured empirically across whole river networks, simulation models are critical tools for understanding river-network biogeochemistry. However, limitations inherent in current models restrict our ability to simulate biogeochemical dynamics among diverse river networks. We illustrate these limitations using a river-network model to scale up in situ measures of nitrogen cycling in eight catchments spanning various geophysical and land-use conditions. Our model results provide evidence that catchment characteristics typically excluded from models may control river-network biogeochemistry. Based on our findings, we identify importantmore » components of a revised strategy for simulating biogeochemical dynamics in river networks, including approaches to modeling terrestrial-aquatic linkages, hydrologic exchanges between the channel, floodplain/riparian complex, and subsurface waters, and interactions between coupled biogeochemical cycles.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26461069','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26461069">Investigation of Cost and Energy Optimization of Drinking Water Distribution Systems.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Cherchi, Carla; Badruzzaman, Mohammad; Gordon, Matthew; Bunn, Simon; Jacangelo, Joseph G 2015-11-17 Holistic management of water and energy resources through energy and water quality management systems (EWQMSs) have traditionally aimed at energy cost reduction with limited or no emphasis on energy efficiency or greenhouse gas minimization. This study expanded the existing EWQMS framework and determined the impact of different management strategies for energy cost and energy consumption (e.g., carbon footprint) reduction on system performance at two drinking water utilities in California (United States). The results showed that optimizing for cost led to cost reductions of 4% (Utility B, summer) to 48% (Utility A, winter). The energy optimization strategy was successfully able to find the lowest energy use operation and achieved energy usage reductions of 3% (Utility B, summer) to 10% (Utility A, winter). The findings of this study revealed that there may be a trade-off between cost optimization (dollars) and energy use (kilowatt-hours), particularly in the summer, when optimizing the system for the reduction of energy use to a minimum incurred cost increases of 64% and 184% compared with the cost optimization scenario. Water age simulations through hydraulic modeling did not reveal any adverse effects on the water quality in the distribution system or in tanks from pump schedule optimization targeting either cost or energy minimization. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25958632','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25958632">[Study on the optimization of monitoring indicators of drinking water quality during health supervision].</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Ye, Bixiong; E, Xueli; Zhang, Lan 2015-01-01 To optimize non-regular drinking water quality indices (except Giardia and Cryptosporidium) of urban drinking water. Several methods including drinking water quality exceed the standard, the risk of exceeding standard, the frequency of detecting concentrations below the detection limit, water quality comprehensive index evaluation method, and attribute reduction algorithm of rough set theory were applied, redundancy factor of water quality indicators were eliminated, control factors that play a leading role in drinking water safety were found. Optimization results showed in 62 unconventional water quality monitoring indicators of urban drinking water, 42 water quality indicators could be optimized reduction by comprehensively evaluation combined with attribute reduction of rough set. Optimization of the water quality monitoring indicators and reduction of monitoring indicators and monitoring frequency could ensure the safety of drinking water quality while lowering monitoring costs and reducing monitoring pressure of the sanitation supervision departments. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2008AGUFM.H31D0899B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2008AGUFM.H31D0899B">Optimization of buffer injection for the effective bioremediation of chlorinated solvents in aquifers</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brovelli, A.; Robinson, C.; Barry, A.; Kouznetsova, I.; Gerhard, J. 2008-12-01 Various techniques have been proposed to enhance biologically-mediated reductive dechlorination of chlorinated solvents in the subsurface, including the addition of fermentable organic substrate for the generation of H2 as an electron donor. One rate-limiting factor for enhanced dechlorination is the pore fluid pH. Organic acids and H+ ions accumulate in dechlorination zones, generating unfavorable conditions for microbial activity (pH < 6.5). The pH variation is a nonlinear function of the amount of reduced chlorinated solvents, and is affected by the organic material fermented, the chemical composition of the pore fluid and the soil's buffering capacity. Consequently, in some cases enhanced remediation schemes rely on buffer injection (e.g., bicarbonate) to alleviate this problem, particularly in the presence of solvent nonaqueous phase liquid (NAPL) source zones. However, the amount of buffer required - particularly in complex, evolving biogeochemical environments - is not well understood. To investigate this question, this work builds upon a geochemical numerical model (Robinson et al., Science of the Total Environment, submitted), which computes the amount of additional buffer required to maintain the pH at a level suitable for bacterial activity for batch systems. The batch model was coupled to a groundwater flow/solute transport/chemical reaction simulator to permit buffer optimization computations within the context of flowing systems exhibiting heterogeneous hydraulic, physical and chemical properties. A suite of simulations was conducted in which buffer optimization was examined within the bounds of the minimum concentration necessary to sustain a pH favorable to microbial activity and the maximum concentration to avoid excessively high pH values (also not suitable to bacterial activity) and mineral precipitation (e.g., calcite, which may lead to pore-clogging). These simulations include an examination of the sensitivity of this buffer concentration range to aquifer heterogeneity and groundwater velocity. This work is part of SABRE (Source Area BioREmediation), a collaborative international research project that aims to evaluate and improve enhanced bioremediation of chlorinated solvent source zones. In this context, numerical simulations are supporting the upscaling of the technique, including identifying the most appropriate buffer injection strategies for field applications </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B53H..02M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B53H..02M">A soil-landscape framework for understanding spatial and temporal variability in biogeochemical processes in catchments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> McGuire, K. J.; Bailey, S. W.; Ross, D. S. 2017-12-01 Heterogeneity in biophysical properties within catchments challenges how we quantify and characterize biogeochemical processes and interpret catchment outputs. Interactions between the spatiotemporal variability of hydrological states and fluxes and soil development can spatially structure catchments, leading to a framework for understanding patterns in biogeochemical processes. In an upland, glaciated landscape at the Hubbard Brook Experimental Forest (HBEF) in New Hampshire, USA, we are embracing the structure and organization of soils to understand the spatial relations between runoff production zones, distinct soil-biogeochemical environments, and solute retention and release. This presentation will use observations from the HBEF to demonstrate that a soil-landscape framework is essential in understanding the spatial and temporal variability of biogeochemical processes in this catchment. Specific examples will include how laterally developed soils reveal the location of active runoff production zones and lead to gradients in primary mineral dissolution and the distribution of weathering products along hillslopes. Soil development patterns also highlight potential carbon and nitrogen cycling hotspots, differentiate acidic conditions, and affect the regulation of surface water quality. Overall, this work demonstrates the importance of understanding the landscape-level structural organization of soils in characterizing the variation and extent of biogeochemical processes that occur in catchments. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1411903-functional-enzyme-based-approach-linking-microbial-community-functions-biogeochemical-process-kinetics','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1411903-functional-enzyme-based-approach-linking-microbial-community-functions-biogeochemical-process-kinetics">Functional Enzyme-Based Approach for Linking Microbial Community Functions with Biogeochemical Process Kinetics</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Li, Minjing; Qian, Wei-jun; Gao, Yuqian The kinetics of biogeochemical processes in natural and engineered environmental systems are typically described using Monod-type or modified Monod-type models. These models rely on biomass as surrogates for functional enzymes in microbial community that catalyze biogeochemical reactions. A major challenge to apply such models is the difficulty to quantitatively measure functional biomass for constraining and validating the models. On the other hand, omics-based approaches have been increasingly used to characterize microbial community structure, functions, and metabolites. Here we proposed an enzyme-based model that can incorporate omics-data to link microbial community functions with biogeochemical process kinetics. The model treats enzymes asmore » time-variable catalysts for biogeochemical reactions and applies biogeochemical reaction network to incorporate intermediate metabolites. The sequences of genes and proteins from metagenomes, as well as those from the UniProt database, were used for targeted enzyme quantification and to provide insights into the dynamic linkage among functional genes, enzymes, and metabolites that are necessary to be incorporated in the model. The application of the model was demonstrated using denitrification as an example by comparing model-simulated with measured functional enzymes, genes, denitrification substrates and intermediates« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27943672','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27943672">Hematite Reduction Buffers Acid Generation and Enhances Nutrient Uptake by a Fermentative Iron Reducing Bacterium, Orenia metallireducens Strain Z6.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Dong, Yiran; Sanford, Robert A; Chang, Yun-Juan; McInerney, Michael J; Fouke, Bruce W 2017-01-03 Fermentative iron-reducing organisms have been identified in a variety of environments. Instead of coupling iron reduction to respiration, they have been consistently observed to use ferric iron minerals as an electron sink for fermentation. In the present study, a fermentative iron reducer, Orenia metallireducens strain Z6, was shown to use iron reduction to enhance fermentation not only by consuming electron equivalents, but also by generating alkalinity that effectively buffers the pH. Fermentation of glucose by this organism in the presence of a ferric oxide mineral, hematite (Fe 2 O 3 ), resulted in enhanced glucose decomposition compared with fermentation in the absence of an iron source. Parallel evidence (i.e., genomic reconstruction, metabolomics, thermodynamic analyses, and calculation of electron transfer) suggested hematite reduction as a proton-consuming reaction effectively consumed acid produced by fermentation. The buffering effect of hematite was further supported by a greater extent of glucose utilization by strain Z6 in media with increasing buffer capacity. Such maintenance of a stable pH through hematite reduction for enhanced glucose fermentation complements the thermodynamic interpretation of interactions between microbial iron reduction and other biogeochemical processes. This newly discovered feature of iron reducer metabolism also has significant implications for groundwater management and contaminant remediation by providing microbially mediated buffering systems for the associated microbial and/or chemical reactions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1087345','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1087345">Optimizing Metalloporphyrin-Catalyzed Reduction Reactions for In Situ Remediation of DOE Contaminants</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Schlautman, Mark A. 2013-07-14 Past activities have resulted in a legacy of contaminated soil and groundwater at Department of Energy facilities nationwide. Uranium and chromium are among the most frequently encountered and highest-priority metal and radionuclide contaminants at DOE installations. Abiotic chemical reduction of uranium and chromium at contaminated DOE sites can be beneficial because the reduced metal species are less soluble in water, less mobile in the environment, and less toxic to humans and ecosystems. Although direct biological reduction has been reported for U(VI) and Cr(VI) in laboratory studies and at some field sites, the reactions can sometimes be slow or even inhibitedmore » due to unfavorable environmental conditions. One promising approach for the in-situ remediation of DOE contaminants is to develop electron shuttle catalysts that can be delivered precisely to the specific subsurface locations where contaminants reside. Previous research has shown that reduction of oxidized organic and inorganic contaminants often can be catalyzed by electron shuttle systems. Metalloporphyrins and their derivatives are well known electron shuttles for many biogeochemical systems, and thus were selected to study their catalytic capabilities for the reduction of chromium and uranium in the presence of reducing agents. Zero valent iron (ZVI) was chosen as the primary electron donor in most experimental systems. Research proceeded in three phases and the key findings of each phase are reported here. Phase I examined Cr(VI) reduction and utilized micro- and nano-sized ZVI as the electron donors. Electron shuttle catalysts tested were cobalt- and iron-containing metalloporphyrins and Vitamin B12. To aid in the recycle and reuse of the nano-sized ZVI and soluble catalysts, sol-gels and calcium-alginate gel beads were tested as immobilization/support matrices. Although the nano-sized ZVI could be incorporated within the alginate gel beads, preliminary attempts to trap it in sol-gels were not successful. Conversely, the water-soluble catalysts could be trapped within sol-gel matrices but they tended to leach out of the alginate gel beads during use. In general, immobilization of the nano-sized ZVI in gel beads and of the catalysts in sol-gels tended to result in slower rates of Cr(VI) reduction, but these effects could be overcome to some extent by using higher reactant/catalyst concentrations. In addition, the lowering of their effectiveness would likely be offset by the benefits obtained when recycling and reusing the materials because they were immobilized. Addition of the catalytic electron shuttles will be most useful when the micro-sized or nano-sized ZVI becomes less reactive with reaction time. Continued work in Phase II in the area of nano-sized ZVI immobilization led to procedures that were successful in incorporating the iron particles in sol-gel matrices. The water-soluble reductants sodium dithionite and L-ascorbic acid were also tested, but their use appeared to lead to formation of complexes with the uranyl cation which limited their effectiveness. Also, although the sol-gel supported nano-sized ZVI showed some promise at reducing uranium, the fluoride used in the sol-gel synthesis protocol appeared to lead to formation of uranyl-fluoride complexes that were less reactive. Because hexavalent chromium is an anion which does not form complexes with fluoride, it was used to demonstrate the intrinsic reactivity of the sol-gel immobilized nano-sized ZVI. Consistent with our observations in Phase I, the sol-gel matrix once again slowed down the reduction reaction but the expected benefits of recycle/reuse should outweigh this adverse effect. The major emphasis in Phase III of this study was to simultaneously incorporate nano-sized ZVI and water-soluble catalysts in the same sol-gel matrix. The catalysts utilized were cobalt complexes of uroporphyrin and protoporphyrin and Cr(VI) reduction was used to test the efficacy of the combined "catalyst + reductant" sol-gel matrix. When enough catalyst was added to the sol-gels, enhancement of the Cr(VI) reduction reaction was observed. At the lowest levels of catalyst addition, however, the rates of Cr(VI) reduction were similar to those systems which only used sol-gel immobilized nano-sized ZVI without any catalyst present. These findings suggest future areas of research that should be pursued to further optimize abiotic reduction reactions of metals with combined "catalyst + reductant" matrices.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EurSS..47..153V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EurSS..47..153V">Biogeochemistry of heavy metals in contaminated excessively moistened soils (Analytical review)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Vodyanitskii, Yu. N.; Plekhanova, I. O. 2014-03-01 The biogeochemical behavior of heavy metals in contaminated excessively moistened soils depends on the development of reducing conditions (either moderate or strong). Upon the moderate biogenic reduction, Cr as the metal with variable valence forms low-soluble compounds, which decreases its availability to plants and prevents its penetration into surface- and groundwater. Creation of artificial barriers for Cr fixation on contaminated sites is based on the stimulation of natural metal-reducing bacteria. Arsenic, being a metalloid with a variable valence, is mobilized upon the moderate biogenic reduction. The mobility of siderophilic heavy metals with a constant valence grows under the moderate reducing conditions at the expense of dissolution of iron (hydr)oxides as carriers of these metals. Zinc, which can enter the newly formed goethite lattice, is an exception. Strong reduction processes in organic excessively moist and flooded soils (usually enriched in S) lead to the formation of low-soluble sulfides of heavy elements with both variable (As) and constant (Cu, Ni, Zn, and Pb) valence. On changing aquatic regime in overmoistened soils and their drying, sulfides of heavy metals are oxidized, and previously fixed metals are mobilized. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009JMS....77...45A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009JMS....77...45A">Numerical model on the material circulation for coastal sediment in Ago Bay, Japan</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Anggara Kasih, G. A.; Chiba, Satoshi; Yamagata, Youichi; Shimizu, Yasuhiro; Haraguchi, Koichi 2009-04-01 In this paper, we study the sediment in Ago Bay from the aspects of the biogeochemical cycle and the mass transport by means of a numerical model. We developed the model by adopting the basic idea of Berg et al. (Berg, P., Rysgaard, S., Thamdrup, B., 2003. Dynamic modeling of early diagenesis and nutrient cycling: A case study in Artic marine sediment. Am. J. Sci. 303, 905-955.), Fossing et al. [Fossing, H., Berg, P., Thamdrup, B., Rysgaard, S., Sorensen, H.M., Nielsen, K.A., 2004. Model set-up for an oxygen and nutrient flux for Aarhus Bay (Denmark). National Environmental Research Institute (NERI) Technical Report No. 483. Ministry of the Environment, Denmark, 65 pp.] and Sayama [Sayama, M., 2000. Analytical technique for the nitrogen circulation in the boundary layer of the coastal sediment. Isao Koike edited, Japan Environmental Management Association for Industry, Tokyo, pp. 51-103. (in Japanese)]. In the model, the biogeochemical processes involve five primary reactions and sixteen secondary reactions. The primary reactions describe the degradation of organic matters, and the secondary reactions describe the miscellaneous reactions such as re-oxidation of reduced species formed as a product from primary reactions, and the crystallizing process of oxidized particles. The transports process includes molecular diffusion, advection, bioturbation and bioirrigation. The model performance is verified by comparing the model predicted data to the observed data. The comparison involves data of vertical distribution of material concentrations and the material fluxes at the sediment-water interface. The comparison shows that the model can reproduce the observed vertical profile and the observed material fluxes at the sediment-water interface. The material circulation result shows that about 42% of dissolved organic matter (DOM) is mineralized by sulfate reduction, around 41% by oxygen respiration, and the remaining is mineralized by denitrification, manganese and iron reduction. As a result, about 47% of the O 2 taken by the sediment is directly used through bacterial oxygen respiration and 34% is used through sulfate reduction. The sensitivity study on the impact of flux change of particulate organic matter shows that 30% reduction of deposition OM flux to the sediment suppresses the oxygen consumption in the sediment from 7.3 mmol O 2/m 2 day to 5.1 mmol O 2/m 2 day. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B22E..02K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B22E..02K">Geomicrobiological cycling of antimony</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kulp, T. R.; Terry, L.; Dovick, M. A.; Braiotta, F. 2013-12-01 Microbiologically catalyzed oxidation and reduction of toxic metalloids (e.g., As, Se, and Te) generally proceeds much faster than corresponding abiotic reactions. These microbial transformations constitute biogeochemical cycles that control chemical speciation and environmental behavior of metalloids in aqueous environments. Particular progress has been made over the past two decades in documenting microbiological biotransformations of As, which include anaerobic respiratory reduction of As(V) to As(III), oxidation of As(III) to As(V) linked to chemoautotrophy or photoautotrophy, and cellular detoxification pathways. By contrast, microbial interactions with Sb, As's group 15 neighbor and a toxic element of emerging global concern, are poorly understood. Our work with sediment microcosms, enrichment cultures, and bacterial isolates suggests that prokaryotic metabolisms may be similarly important to environmental Sb cycling. Enrichment cultures and isolates from a Sb-contaminated mine site in Idaho exhibited Sb(V)-dependent heterotrophic respiration under anaerobic conditions and Sb(III)-dependent autotrophic growth in the presence of air. Live, anoxic cultures reduced 2 mM Sb(V) to Sb(III) within 5 d, while no activity occurred in killed controls. Sb(V) reduction was stimulated by lactate or acetate and was quantitatively coupled to the oxidation of lactate. The oxidation of radiolabeled 14C-acetate (monitored by GC-GPC) demonstrated Sb(V)-dependent oxidation to 14CO2, suggesting a dissimilatory process. Sb(V) dependent growth in cultures was demonstrated by direct counting. Microbiological reduction of Sb(V) also occurred in anerobic sediment microcosms from an uncontaminated suburban lake, but did not appear to be linked to growth and is interpreted as a mechanism of biological detoxification. Aerobic microcosms and cultures from the Idaho mine oxidized 2 mM Sb(III) to Sb(V) within 7 d and coupled this reaction to cell growth quantified by direct counting. An anoxygenic photosynthetic community of purple sulfur bacteria from Pyramid Lake, NV, however, that was capable of growth via anoxygenic photosynthesis using As(III) as an electron donor was not capable of similar growth using Sb(III). These results suggest that geomicrobiological Sb cycling is an important influence on the environmental speciation and behavior of Sb, and portend the presence of a global biogeochemical Sb cycle that is analogous to but distinct from that for As. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29062303','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29062303">Exploring Fingerprints of the Extreme Thermoacidophile Metallosphaera sedula Grown on Synthetic Martian Regolith Materials as the Sole Energy Sources.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kölbl, Denise; Pignitter, Marc; Somoza, Veronika; Schimak, Mario P; Strbak, Oliver; Blazevic, Amir; Milojevic, Tetyana 2017-01-01 The biology of metal transforming microorganisms is of a fundamental and applied importance for our understanding of past and present biogeochemical processes on Earth and in the Universe. The extreme thermoacidophile Metallosphaera sedula is a metal mobilizing archaeon, which thrives in hot acid environments (optimal growth at 74°C and pH 2.0) and utilizes energy from the oxidation of reduced metal inorganic sources. These characteristics of M. sedula make it an ideal organism to further our knowledge of the biogeochemical processes of possible life on extraterrestrial planetary bodies. Exploring the viability and metal extraction capacity of M. sedula living on and interacting with synthetic extraterrestrial minerals, we show that M. sedula utilizes metals trapped in the Martian regolith simulants (JSC Mars 1A; P-MRS; S-MRS; MRS07/52) as the sole energy sources. The obtained set of microbiological and mineralogical data suggests that M. sedula actively colonizes synthetic Martian regolith materials and releases free soluble metals. The surface of bioprocessed Martian regolith simulants is analyzed for specific mineralogical fingerprints left upon M. sedula growth. The obtained results provide insights of biomining of extraterrestrial material as well as of the detection of biosignatures implementing in life search missions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://eric.ed.gov/?q=biomass&pg=2&id=ED569088','ERIC'); return false;" href="https://eric.ed.gov/?q=biomass&pg=2&id=ED569088">Biogeochemistry Science and Education. Part One: Using Non-Traditional Stable Isotopes as Environmental Tracers. Part Two: Identifying and Measuring Undergraduate Misconceptions in Biogeochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://www.eric.ed.gov/ERICWebPortal/search/extended.jsp?_pageLabel=advanced">ERIC Educational Resources Information Center</a> Mead, Chris 2014-01-01 This dissertation is presented in two sections. First, I explore two methods of using stable isotope analysis to trace environmental and biogeochemical processes. Second, I present two related studies investigating student understanding of the biogeochemical concepts that underlie part one. Fe and Hg are each biogeochemically important elements in… </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/46638','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/46638">Searching for biogeochemical hot spots in three dimensions: soil C and N cycling in hydropedologic settings in a northern hardwood forest</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> J.L. Morse; S.F. Werner; C.P. Gillin; C.L. Goodale; S.W. Bailey; K.J. McGuire; P.M. Groffman 2014-01-01 Understanding and predicting the extent, location, and function of biogeochemical hot spots at the watershed scale is a frontier in environmental science. We applied a hydropedologic approach to identify (1) biogeochemical differences among morphologically distinct hydropedologic settings and (2) hot spots of microbial carbon (C) and nitrogen (N) cycling activity in a... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B54D..07S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B54D..07S">Iron: A Biogeochemical Engine That Drives Carbon, Nitrogen, and Phosphorus Cycling in Humid Tropical Forest Soils</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Silver, W. L.; Hall, S. J.; Thompson, A.; Yang, W. H. 2014-12-01 The abundance of redox active Fe minerals has the potential to alter the storage and loss of C, contribute to gaseous N emissions, and control P retention in upland tropical forest soils. High concentrations of short-range order Fe minerals led to Fe(II) production rates of 26-206 μg g d-1 under short-term low redox conditions (Chacón et al. 2006, Liptzin and Silver 2009, Dubinsky et al. 2010). Potential C mineralization from Fe(II) reduction was 34-263 g CO2-C m-2 y-1, C losses equivalent to approximately 10-60 % of annual litterfall production in this forest. Decreased acidity during Fe reduction can destabilize soil aggregates and lead to C losses. Iron is rapidly reoxidized during aerobic periods, which can subsequently lead to C stabilization via complexation reactions. Fe oxidation can also stimulate C losses via pH-driven dissolved organic C production and directly via Fenton reactions. In laboratory experiments, rates of CO2 production were strongly linearly correlated with Fe(II) loss under aerobic conditions, increasing by 0.51 ± 0.02 µg CO2-C g soil h-1 respired for each mg of Fe(II) g-1 soil oxidized or sorbed (Hall and Silver 2013). Iron oxidation has also been linked to dissimilatory NO3- reduction to NH4+ leading to N retention in ecosystems. Fe(III) reduction coupled with NH4+ oxidation (Feammox) can lead to N losses as dinitrogen gas (N2) or nitrous oxide (N2O), a potent greenhouse gas. Estimates suggest that Feammox resulted in gaseous N losses of 1-4 kg N ha-1 y-1 (Yang et al. 2012), rates equivalent to total denitrification in this forest. Oxidized Fe can strongly bind P decreasing it's availability to plant roots. While this is commonly cited as a potential limitation to net primary production in tropical forests, it also helps to retain P in ecosystems with high rainfall and potential leaching losses. Microbial biomass P availability increased significantly with Fe(II) production, suggesting the P mobilized during Fe(II) reduction was rapidly immobilized into biological pools (Liptzin and Silver 2009). Data suggest that Fe-redox cycling may decrease P limitation to NPP, and help maintain forest nutrient stocks. In summary, our results highlight the biogeochemical significance of Fe cycling in upland soils environments and its important role in the dynamics of humid tropical forests. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_11");'>11</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li class="active">13</li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_14" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li class="active">14</li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="261"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70030568','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70030568">Microbial transformations of arsenic in the environment: From soda lakes to aquifers</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Lloyd, J.R.; Oremland, R.S. 2006-01-01 Arsenic is a highly toxic element that supports a surprising range of biogeochemical transformations. The biochemical basis of these microbial interactions is described, with an emphasis on energy-yielding redox biotransformations that cycle between the As5+ and As3+ oxidation states. The subsequent impact of As3+-oxidising and As 5+-reducing prokaryotes on the chemistry of selected environments is also described, focusing on soda lakes with naturally high concentrations of the metalloid and on Southeast Asian aquifer sediments, where the microbial reduction of sorbed As5+ and subsequent mobilisation of As 3+ into water abstracted for drinking and irrigation threaten the lives of millions. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25902522','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25902522">Uranium isotopes fingerprint biotic reduction.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; Monga, Nikhil; Romaniello, Stephen J; Weyer, Stefan; Bernier-Latmani, Rizlan 2015-05-05 Knowledge of paleo-redox conditions in the Earth's history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U), i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth's crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. Additionally, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1048257','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1048257">Dynamics of microbial community composition and function during in-situ bioremediation of a uranium-contaminated aquifer</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Nostrand, J.D. Van; Wu, L.; Wu, W.M. 2010-08-15 A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter{sup -1}). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed thatmore » Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that functional FeRB, SRB, and NRB populations within this system played key roles in this process.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3127627','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3127627">Dynamics of Microbial Community Composition and Function during In Situ Bioremediation of a Uranium-Contaminated Aquifer▿‡</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Van Nostrand, Joy D.; Wu, Liyou; Wu, Wei-Min; Huang, Zhijian; Gentry, Terry J.; Deng, Ye; Carley, Jack; Carroll, Sue; He, Zhili; Gu, Baohua; Luo, Jian; Criddle, Craig S.; Watson, David B.; Jardine, Philip M.; Marsh, Terence L.; Tiedje, James M.; Hazen, Terry C.; Zhou, Jizhong 2011-01-01 A pilot-scale system was established to examine the feasibility of in situ U(VI) immobilization at a highly contaminated aquifer (U.S. DOE Integrated Field Research Challenge site, Oak Ridge, TN). Ethanol was injected intermittently as an electron donor to stimulate microbial U(VI) reduction, and U(VI) concentrations fell to below the Environmental Protection Agency drinking water standard (0.03 mg liter−1). Microbial communities from three monitoring wells were examined during active U(VI) reduction and maintenance phases with GeoChip, a high-density, comprehensive functional gene array. The overall microbial community structure exhibited a considerable shift over the remediation phases examined. GeoChip-based analysis revealed that Fe(III)-reducing bacterial (FeRB), nitrate-reducing bacterial (NRB), and sulfate-reducing bacterial (SRB) functional populations reached their highest levels during the active U(VI) reduction phase (days 137 to 370), in which denitrification and Fe(III) and sulfate reduction occurred sequentially. A gradual decrease in these functional populations occurred when reduction reactions stabilized, suggesting that these functional populations could play an important role in both active U(VI) reduction and maintenance of the stability of reduced U(IV). These results suggest that addition of electron donors stimulated the microbial community to create biogeochemical conditions favorable to U(VI) reduction and prevent the reduced U(IV) from reoxidation and that functional FeRB, SRB, and NRB populations within this system played key roles in this process. PMID:21498771 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018E%26ES..128a2117L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018E%26ES..128a2117L">Research on numerical method for multiple pollution source discharge and optimal reduction program</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Li, Mingchang; Dai, Mingxin; Zhou, Bin; Zou, Bin 2018-03-01 In this paper, the optimal method for reduction program is proposed by the nonlinear optimal algorithms named that genetic algorithm. The four main rivers in Jiangsu province, China are selected for reducing the environmental pollution in nearshore district. Dissolved inorganic nitrogen (DIN) is studied as the only pollutant. The environmental status and standard in the nearshore district is used to reduce the discharge of multiple river pollutant. The research results of reduction program are the basis of marine environmental management. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.A34A..05D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.A34A..05D">Did large animals play an important role in global biogeochemical cycling in the past?</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Doughty, C. 2014-12-01 In the late Pleistocene (~50-10,000 years ago), ninety-seven genera of large animals (>44kg) (megafauna) went extinct, concentrated in the Americas and Australia. The loss of megafauna had major effects on ecosystem structure, seed dispersal and land surface albedo. However, the impact of this dramatic extinction on ecosystem nutrient biogeochemistry, through the lateral transport of dung and bodies, has never been explored. Here we explore these nutrient impacts using a novel mathematical framework that analyses this lateral transport as a diffusion-like process and demonstrates that large animals play a disproportionately large role in the horizontal transfer of nutrients across landscapes. For example, we estimate that the extinction of the Amazonian megafauna led to a >98% reduction in the lateral transfer flux of the limiting nutrient phosphorus (P) with similar, though less extreme, decreases in all continents outside of Africa. This resulted in strong decreases in phosphorus availability in Eastern Amazonia away from fertile floodplains, a decline which may still be ongoing, and current P limitation in the Amazon basin may be partially a relic of an ecosystem without the functional connectedness it once had. More broadly, the Pleistocene megafaunal extinctions resulted in major and ongoing disruptions to terrestrial biogeochemical cycling at continental scales and increased nutrient heterogeneity globally. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5810613','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5810613">CO2 leakage alters biogeochemical and ecological functions of submarine sands</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Molari, Massimiliano; Guilini, Katja; Lott, Christian; Weber, Miriam; de Beer, Dirk; Meyer, Stefanie; Ramette, Alban; Wegener, Gunter; Wenzhöfer, Frank; Martin, Daniel; Cibic, Tamara; De Vittor, Cinzia; Vanreusel, Ann; Boetius, Antje 2018-01-01 Subseabed CO2 storage is considered a future climate change mitigation technology. We investigated the ecological consequences of CO2 leakage for a marine benthic ecosystem. For the first time with a multidisciplinary integrated study, we tested hypotheses derived from a meta-analysis of previous experimental and in situ high-CO2 impact studies. For this, we compared ecological functions of naturally CO2-vented seafloor off the Mediterranean island Panarea (Tyrrhenian Sea, Italy) to those of nonvented sands, with a focus on biogeochemical processes and microbial and faunal community composition. High CO2 fluxes (up to 4 to 7 mol CO2 m−2 hour−1) dissolved all sedimentary carbonate, and comigration of silicate and iron led to local increases of microphytobenthos productivity (+450%) and standing stocks (+300%). Despite the higher food availability, faunal biomass (−80%) and trophic diversity were substantially lower compared to those at the reference site. Bacterial communities were also structurally and functionally affected, most notably in the composition of heterotrophs and microbial sulfate reduction rates (−90%). The observed ecological effects of CO2 leakage on submarine sands were reproduced with medium-term transplant experiments. This study assesses indicators of environmental impact by CO2 leakage and finds that community compositions and important ecological functions are permanently altered under high CO2. PMID:29441359 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29336556','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29336556">Linking Spectral Induced Polarization (SIP) and Subsurface Microbial Processes: Results from Sand Column Incubation Experiments.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Mellage, Adrian; Smeaton, Christina M; Furman, Alex; Atekwana, Estella A; Rezanezhad, Fereidoun; Van Cappellen, Philippe 2018-02-20 Geophysical techniques, such as spectral induced polarization (SIP), offer potentially powerful approaches for in situ monitoring of subsurface biogeochemistry. The successful implementation of these techniques as monitoring tools for reactive transport phenomena, however, requires the deconvolution of multiple contributions to measured signals. Here, we present SIP spectra and complementary biogeochemical data obtained in saturated columns packed with alternating layers of ferrihydrite-coated and pure quartz sand, and inoculated with Shewanella oneidensis supplemented with lactate and nitrate. A biomass-explicit diffusion-reaction model is fitted to the experimental biogeochemical data. Overall, the results highlight that (1) the temporal response of the measured imaginary conductivity peaks parallels the microbial growth and decay dynamics in the columns, and (2) SIP is sensitive to changes in microbial abundance and cell surface charging properties, even at relatively low cell densities (<10 8 cells mL -1 ). Relaxation times (τ) derived using the Cole-Cole model vary with the dominant electron accepting process, nitrate or ferric iron reduction. The observed range of τ values, 0.012-0.107 s, yields effective polarization diameters in the range 1-3 μm, that is, 2 orders of magnitude smaller than the smallest quartz grains in the columns, suggesting that polarization of the bacterial cells controls the observed chargeability and relaxation dynamics in the experiments. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5989612','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5989612">The hunt for the most-wanted chemolithoautotrophic spookmicrobes</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> 2018-01-01 ABSTRACT Microorganisms are the drivers of biogeochemical methane and nitrogen cycles. Essential roles of chemolithoautotrophic microorganisms in these cycles were predicted long before their identification. Dedicated enrichment procedures, metagenomics surveys and single-cell technologies have enabled the identification of several new groups of most-wanted spookmicrobes, including novel methoxydotrophic methanogens that produce methane from methylated coal compounds and acetoclastic ‘Candidatus Methanothrix paradoxum’, which is active in oxic soils. The resultant energy-rich methane can be oxidized via a suite of electron acceptors. Recently, ‘Candidatus Methanoperedens nitroreducens’ ANME-2d archaea and ‘Candidatus Methylomirabilis oxyfera’ bacteria were enriched on nitrate and nitrite under anoxic conditions with methane as an electron donor. Although ‘Candidatus Methanoperedens nitroreducens’ and other ANME archaea can use iron citrate as an electron acceptor in batch experiments, the quest for anaerobic methane oxidizers that grow via iron reduction continues. In recent years, the nitrogen cycle has been expanded by the discovery of various ammonium-oxidizing prokaryotes, including ammonium-oxidizing archaea, versatile anaerobic ammonium-oxidizing (anammox) bacteria and complete ammonium-oxidizing (comammox) Nitrospira bacteria. Several biogeochemical studies have indicated that ammonium conversion occurs under iron-reducing conditions, but thus far no microorganism has been identified. Ultimately, iron-reducing and sulfate-dependent ammonium-oxidizing microorganisms await discovery. PMID:29873717 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23438796','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23438796">U(VI) bioreduction with emulsified vegetable oil as the electron donor--model application to a field test.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Tang, Guoping; Watson, David B; Wu, Wei-Min; Schadt, Christopher W; Parker, Jack C; Brooks, Scott C 2013-04-02 We amended a shallow fast-flowing uranium (U) contaminated aquifer with emulsified vegetable oil (EVO) and subsequently monitored the biogeochemical responses for over a year. Using a biogeochemical model developed in a companion article (Tang et al., Environ. Sci. Technol.2013, doi: 10.1021/es304641b) based on microcosm tests, we simulated geochemical and microbial dynamics in the field test during and after the 2-h EVO injection. When the lab-determined parameters were applied in the field-scale simulation, the estimated rate coefficient for EVO hydrolysis in the field was about 1 order of magnitude greater than that in the microcosms. Model results suggested that precipitation of long-chain fatty acids, produced from EVO hydrolysis, with Ca in the aquifer created a secondary long-term electron donor source. The model predicted substantial accumulation of denitrifying and sulfate-reducing bacteria, and U(IV) precipitates. The accumulation was greatest near the injection wells and along the lateral boundaries of the treatment zone where electron donors mixed with electron acceptors in the groundwater. While electron acceptors such as sulfate were generally considered to compete with U(VI) for electrons, this work highlighted their role in providing electron acceptors for microorganisms to degrade complex substrates thereby enhancing U(VI) reduction and immobilization. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29441359','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29441359">CO2 leakage alters biogeochemical and ecological functions of submarine sands.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Molari, Massimiliano; Guilini, Katja; Lott, Christian; Weber, Miriam; de Beer, Dirk; Meyer, Stefanie; Ramette, Alban; Wegener, Gunter; Wenzhöfer, Frank; Martin, Daniel; Cibic, Tamara; De Vittor, Cinzia; Vanreusel, Ann; Boetius, Antje 2018-02-01 Subseabed CO 2 storage is considered a future climate change mitigation technology. We investigated the ecological consequences of CO 2 leakage for a marine benthic ecosystem. For the first time with a multidisciplinary integrated study, we tested hypotheses derived from a meta-analysis of previous experimental and in situ high-CO 2 impact studies. For this, we compared ecological functions of naturally CO 2 -vented seafloor off the Mediterranean island Panarea (Tyrrhenian Sea, Italy) to those of nonvented sands, with a focus on biogeochemical processes and microbial and faunal community composition. High CO 2 fluxes (up to 4 to 7 mol CO 2 m -2 hour -1 ) dissolved all sedimentary carbonate, and comigration of silicate and iron led to local increases of microphytobenthos productivity (+450%) and standing stocks (+300%). Despite the higher food availability, faunal biomass (-80%) and trophic diversity were substantially lower compared to those at the reference site. Bacterial communities were also structurally and functionally affected, most notably in the composition of heterotrophs and microbial sulfate reduction rates (-90%). The observed ecological effects of CO 2 leakage on submarine sands were reproduced with medium-term transplant experiments. This study assesses indicators of environmental impact by CO 2 leakage and finds that community compositions and important ecological functions are permanently altered under high CO 2 . </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.B53B..08G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.B53B..08G">Extracellular Electron Transfer and Survival Strategies in Acid Mine Drainage Impacted Soils</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gorby, Y. A.; Senko, J. 2011-12-01 Acid mine drainage (AMD) is a prominent and increasing problem in the greater Appalachian region of the United States and throughout the world. Recognition of the importance of extracellular electron transfer (EET) in microbial communities has provided a fertile research environment for multidisciplinary collaborations to emerge and effectively address complex questions with important environmental implications. Our research focuses on the components, strategies and mechanisms of EET in soil systems impacted by AMD and extends to other biogeochemical systems typified by steep redox gradients. Organisms within acid mine drainage use Fe(II) as their primary electron donor and couple Fe(II) oxidation to the reduction of oxygen as the terminal electron acceptor. Biogenic minerals formed by this process completely encase microbes in think deposits that would seem to limit diffusion of both Fe(II) and O2 for access by the organisms. We have developed methods for catalytically removing biogenic minerals revealing microorganisms and a fine network of filamentous extracellular material. Here we present a status report of our efforts to characterize the molecular and electronic properties of these filaments and to address the hypothesis that at least some of these filaments are electrically conductive microbial nanowires that facilitate electron transfer reactions within this complex biogeochemical system. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFM.B11D0039Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFM.B11D0039Z">Exploring a microbial ecosystem approach to modeling deep ocean biogeochemical cycles</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zakem, E.; Follows, M. J. 2014-12-01 Though microbial respiration of organic matter in the deep ocean governs ocean and atmosphere biogeochemistry, it is not represented mechanistically in current global biogeochemical models. We seek approaches that are feasible for a global resolution, yet still reflect the enormous biodiversity of the deep microbial community and its associated metabolic pathways. We present a modeling framework grounded in thermodynamics and redox reaction stoichiometry that represents diverse microbial metabolisms explicitly. We describe a bacterial/archaeal functional type with two parameters: a growth efficiency representing the chemistry underlying a bacterial metabolism, and a rate limitation given by the rate of uptake of each of the necessary substrates for that metabolism. We then apply this approach to answer questions about microbial ecology. As a start, we resolve two dominant heterotrophic respiratory pathways- reduction of oxygen and nitrate- and associated microbial functional types. We combine these into an ecological model and a two-dimensional ocean circulation model to explore the organization, biogeochemistry, and ecology of oxygen minimum zones. Intensified upwelling and lateral transport conspire to produce an oxygen minimum at mid-depth, populated by anaerobic denitrifiers. This modeling approach should ultimately allow for the emergence of bacterial biogeography from competition of metabolisms and for the incorporation of microbial feedbacks to the climate system. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70024531','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70024531">Natural attenuation of chlorinated solvents at Area 6, Dover Air Force Base: Groundwater biogeochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Witt, M.E.; Klecka, G.M.; Lutz, E.J.; Ei, T.A.; Grosso, N.R.; Chapelle, F.H. 2002-01-01 Monitored natural attenuation (MNA) has recently emerged as a viable groundwater remediation technology in the United States. Area 6 at Dover Air Force Base (Dover, DE) was chosen as a test site to examine the potential for MNA of tetrachloroethene (PCE) and trichloroethene (TCE) in groundwater and aquifer sediments. A "lines of evidence" approach was used to document the occurrence of natural attenuation. Chlorinated hydrocarbon and biogeochemical data were used to develop a site-specific conceptual model where both anaerobic and aerobic biological processes are responsible for the destruction of PCE, TCE, and daughter metabolites. An examination of groundwater biogeochemical data showed a region of depleted dissolved oxygen with elevated dissolved methane and hydrogen concentrations. Reductive dechlorination likely dominated in the anaerobic portion of the aquifer where PCE and TCE levels were observed to decrease with a simultaneous increase in cis-1,2-dichloroethene (cis-DCE), vinyl chloride (VC), ethene, and dissolved chloride. Near the anaerobic/aerobic interface, concentrations of cis-DCE and VC decreased to below detection limits, presumably due to aerobic biotransformation processes. Therefore, the contaminant and daughter product plumes present at the site appear to have been naturally attenuated by a combination of active anaerobic and aerobic biotransformation processes. ?? 2002 Elsevier Science B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOS.B34B0361S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOS.B34B0361S">Implications of a More Comprehensive Nitrogen Cycle in a Global Biogeochemical Ocean Model</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Six, K. D.; Ilyina, T. 2016-02-01 Nitrogen plays a crucial role for nearly all living organisms in the Earth system. Changes in the marine nitrogen cycle not only alter the marine biota, but will also have an impact on the marine carbon cycle and, in turn, on climate due to the close coupling of the carbon-nitrogen cycle. The understanding of processes and controls of the marine nitrogen cycle is therefore a prerequisite to reduce uncertainties in the prediction of future climate. Nevertheless, most ocean biogeochemical components of modern Earth system models have a rather simplistic representation of marine N-cycle mainly focusing on nitrate. Here we present results of the HAMburg Ocean Carbon Cycle model (HAMOCC) as part of the MPI-ESM which was extended by a prognostic representation of ammonium and nitrite to resolve important processes of the marine N-cycle such as nitrification and anaerobic ammonium oxidation (anammox). Additionally, we updated the production of nitrous oxide, an important greenhouse gas, allowing for two sources from oxidation of ammonium (nitrification) and from reduction of nitrite (nitrifier-denitrification) at low oxygen concentrations. Besides an extended model data comparison we discuss the following aspects of the N-cycle by model means: (1) contribution of anammox to the loss of fixed nitrogen, and (2) production and emission of marine nitrous oxide. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.H23G1653Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.H23G1653Z">Estimation of biogeochemical climate regulation services in Chinese forest ecosystems</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhang, Y.; Li, S. 2016-12-01 As the global climate is changing, the climate regulation service of terrestrial ecosystem has been widely studied. Forests, as one of the most important terrestrial ecosystem types, is the biggest carbon pool or sink on land and can regulate climate through both biophysical and biogeochemical means. China is a country with vast forested areas and a variety of forest ecosystems types. Although current studies have related the climate regulation service of forest in China with biophysical or biogeochemical mechanism, there is still a lack of quantitative estimation of climate regulation services, especially for the biogeochemical climate regulation service. The GHGV (greenhouse gas value) is an indicator that can quantify the biochemical climate regulation service using ecosystems' stored organic matter, annual greenhouse gas flux, and potential greenhouse gas exchange rates during disturbances over a multiple year time frame. Therefore, we used GHGV to estimate the contribution of China's ten main forest types to biogeochemical climate regulation and generate the pattern of biochemical climate regulation service in Chinese forest ecosystems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H41F1521H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H41F1521H">Characterization of Thermal Refugia and Biogeochemical Hotspots at Sleepers River Watershed, VT</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hwang, K.; Chandler, D. G.; Kelleher, C.; Shanley, J. B.; Shaw, S. B. 2017-12-01 During low flow, changes in the extent of the channel network in headwater catchments depend on groundwater-surface water interactions, and dictate thermal and biogeochemical heterogeneities. Channel reaches with low temperature may act as refugia for valued species such as brook trout, and warmer reaches with high dissolved organic matter may act as biogeochemical hotspots. Prior studies have found uniform scaling of hydrologic and biogeochemical processes above certain spatial thresholds but sizable heterogeneities in these processes below the threshold. We utilize high resolution measurements of water quality parameters including stream temperature, conductivity and fluorescent dissolved organic matter (fDOM) at tributaries in two catchments of Sleepers River Watershed, Vermont to investigate seasonal and spatial variation of water quality and scaling of stream chemistry within the intensive study area and the larger Sleepers River Watershed. This study leverages findings from various small scale regional studies to identify differences in headwater channel reach behavior in a similar climate across some dissimilar geomorphic units, to inform the identification of thermal refugia and biogeochemical hotspots. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24216541','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24216541">Pharmacodynamically optimized erythropoietin treatment combined with phlebotomy reduction predicted to eliminate blood transfusions in selected preterm infants.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Rosebraugh, Matthew R; Widness, John A; Nalbant, Demet; Cress, Gretchen; Veng-Pedersen, Peter 2014-02-01 Preterm very-low-birth-weight (VLBW) infants weighing <1.5 kg at birth develop anemia, often requiring multiple red blood cell transfusions (RBCTx). Because laboratory blood loss is a primary cause of anemia leading to RBCTx in VLBW infants, our purpose was to simulate the extent to which RBCTx can be reduced or eliminated by reducing laboratory blood loss in combination with pharmacodynamically optimized erythropoietin (Epo) treatment. Twenty-six VLBW ventilated infants receiving RBCTx were studied during the first month of life. RBCTx simulations were based on previously published RBCTx criteria and data-driven Epo pharmacodynamic optimization of literature-derived RBC life span and blood volume data corrected for phlebotomy loss. Simulated pharmacodynamic optimization of Epo administration and reduction in phlebotomy by ≥ 55% predicted a complete elimination of RBCTx in 1.0-1.5 kg infants. In infants <1.0 kg with 100% reduction in simulated phlebotomy and optimized Epo administration, a 45% reduction in RBCTx was predicted. The mean blood volume drawn from all infants was 63 ml/kg: 33% required for analysis and 67% discarded. When reduced laboratory blood loss and optimized Epo treatment are combined, marked reductions in RBCTx in ventilated VLBW infants were predicted, particularly among those with birth weights >1.0 kg. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.H21C1055C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.H21C1055C">Development of interactive graphic user interfaces for modeling reaction-based biogeochemical processes in batch systems with BIOGEOCHEM</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chang, C.; Li, M.; Yeh, G. 2010-12-01 The BIOGEOCHEM numerical model (Yeh and Fang, 2002; Fang et al., 2003) was developed with FORTRAN for simulating reaction-based geochemical and biochemical processes with mixed equilibrium and kinetic reactions in batch systems. A complete suite of reactions including aqueous complexation, adsorption/desorption, ion-exchange, redox, precipitation/dissolution, acid-base reactions, and microbial mediated reactions were embodied in this unique modeling tool. Any reaction can be treated as fast/equilibrium or slow/kinetic reaction. An equilibrium reaction is modeled with an implicit finite rate governed by a mass action equilibrium equation or by a user-specified algebraic equation. A kinetic reaction is modeled with an explicit finite rate with an elementary rate, microbial mediated enzymatic kinetics, or a user-specified rate equation. None of the existing models has encompassed this wide array of scopes. To ease the input/output learning curve using the unique feature of BIOGEOCHEM, an interactive graphic user interface was developed with the Microsoft Visual Studio and .Net tools. Several user-friendly features, such as pop-up help windows, typo warning messages, and on-screen input hints, were implemented, which are robust. All input data can be real-time viewed and automated to conform with the input file format of BIOGEOCHEM. A post-processor for graphic visualizations of simulated results was also embedded for immediate demonstrations. By following data input windows step by step, errorless BIOGEOCHEM input files can be created even if users have little prior experiences in FORTRAN. With this user-friendly interface, the time effort to conduct simulations with BIOGEOCHEM can be greatly reduced. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B31E2041F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B31E2041F">Microbial ecology of soda lakes: investigating sulfur and nitrogen cycling at Mono Lake, CA, USA</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fairbanks, D.; Phillips, A. A.; Wells, M.; Bao, R.; Fullerton, K. M.; Stamps, B. W.; Speth, D. R.; Johnson, H.; Sessions, A. L. 2017-12-01 Soda lakes represent unique ecosystems characterized by extremes of pH, salinity and distinct geochemical cycling. Despite these extreme conditions, soda lakes are important repositories of biological adaptation and have a highly functional microbial system. We investigated the biogeochemical cycling of sulfur and nitrogen compounds in Mono Lake, California, located east of the Sierra Nevada mountains. Mono lake is characterized by hyperalkaline, hypersaline and high sulfate concentrations and can enter prolonged periods of meromixis due to freshwater inflow. Typically, the microbial sulfur cycle is highly active in soda lakes with both oxidation and reduction of sulfur compounds. However, the biological sulfur cycle is connected to many other main elemental cycles such as carbon, nitrogen and metals. Here we investigated the interaction between sulfur and nitrogen cycling in Mono lake using a combination of molecular, isotopic, and geochemical observations to explore the links between microbial phylogenetic composition and functionality. Metagenomic and 16S rRNA gene amplicon sequencing were determined at two locations and five depths in May 2017. 16S rRNA gene amplicon sequencing analysis revealed organisms capable of both sulfur and nitrogen cycling. The relative abundance and distribution of functional genes (dsrA, soxAB, nifH, etc) were also determined. These genetic markers indicate the potential in situ relevance of specific carbon, nitrogen, and sulfur pathways in the water column prior to the transition to meromictic stratification. However, genes for sulfide oxidation, denitrification, and ammonification were present. Genome binning guided by the most abundant dsrA sequences, GC content, and abundance with depth identified a Thioalkalivibrio paradoxus bin containing genes capable of sulfur oxidation, denitrification, and nitrate reduction. The presence of a large number of sulfur and nitrogen cycling genes associated with Thioalkalivibrio paradoxus suggests thiosulfate oxidation may be coupled to nitrate reduction despite the extremely low level of nitrate in Mono Lake. Our results illustrate the centrality of living organisms in both shaping and responding to geochemical cycles, as well as future directions for exploring coupled biogeochemical cycles in Mono Lake. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_12");'>12</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li class="active">14</li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_15" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li class="active">15</li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="281"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23727691','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23727691">Biogeochemical processes controlling the mobility of major ions and trace metals in aquitard sediments beneath an oil sand tailing pond: laboratory studies and reactive transport modeling.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Holden, A A; Haque, S E; Mayer, K U; Ulrich, A C 2013-08-01 Increased production and expansion of the oil sand industry in Alberta are of great benefit to the economy, but they carry major environmental challenges. The volume of fluid fine tailings requiring storage is 840×10(6) m(3) and growing, making it imperative that we better understand the fate and transport of oil sand process-affected water (OSPW) seepage from these facilities. Accordingly, the current study seeks to characterize both a) the potential for major ion and trace element release, and b) the principal biogeochemical processes involved, as tailing pond OSPW infiltrates into, and interacts with, underlying glacial till sediments prior to reaching down gradient aquifers or surface waters. Objectives were addressed through a series of aqueous and solid phase experiments, including radial diffusion cells, an isotope analysis, X-ray diffraction, and sequential extractions. The diffusion cells were also simulated in a reactive transport framework to elucidate key reaction processes. The experiments indicate that the ingress and interaction of OSPW with the glacial till sediment-pore water system will result in: a mitigation of ingressing Na (retardation), displacement and then limited precipitation of exchangeable Ca and Mg (as carbonates), sulfate reduction and subsequent precipitation of the produced sulfides, as well as biodegradation of organic carbon. High concentrations of ingressing Cl (~375 mg L(-1)) and Na (~575 mg L(-1)) (even though the latter is delayed, or retarded) are expected to migrate through the till and into the underlying sand channel. Trace element mobility was influenced by ion exchange, oxidation-reduction, and mineral phase reactions including reductive dissolution of metal oxyhydroxides - in accordance with previous observations within sandy aquifer settings. Furthermore, although several trace elements showed the potential for release (Al, B, Ba, Cd, Mn, Pb, Si, Sr), large-scale mobilization is not supported. Thus, the present results suggest that in addition to the commonly cited naphthenic acids, remediation of OSPW-impacted groundwater will need to address high concentrations of major ions contributing to salinization. Copyright © 2013 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015CSR...111..197D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015CSR...111..197D">Total maximum allocated load calculation of nitrogen pollutants by linking a 3D biogeochemical-hydrodynamic model with a programming model in Bohai Sea</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dai, Aiquan; Li, Keqiang; Ding, Dongsheng; Li, Yan; Liang, Shengkang; Li, Yanbin; Su, Ying; Wang, Xiulin 2015-12-01 The equal percent removal (EPR) method, in which pollutant reduction ratio was set as the same in all administrative regions, failed to satisfy the requirement for water quality improvement in the Bohai Sea. Such requirement was imposed by the developed Coastal Pollution Total Load Control Management. The total maximum allocated load (TMAL) of nitrogen pollutants in the sea-sink source regions (SSRs) around the Bohai Rim, which is the maximum pollutant load of every outlet under the limitation of water quality criteria, was estimated by optimization-simulation method (OSM) combined with loop approximation calculation. In OSM, water quality is simulated using a water quality model and pollutant load is calculated with a programming model. The effect of changes in pollutant loads on TMAL was discussed. Results showed that the TMAL of nitrogen pollutants in 34 SSRs was 1.49×105 ton/year. The highest TMAL was observed in summer, whereas the lowest in winter. TMAL was also higher in the Bohai Strait and central Bohai Sea and lower in the inner area of the Liaodong Bay, Bohai Bay and Laizhou Bay. In loop approximation calculation, the TMAL obtained was considered satisfactory for water quality criteria as fluctuation of concentration response matrix with pollutant loads was eliminated. Results of numerical experiment further showed that water quality improved faster and were more evident under TMAL input than that when using the EPR method </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5547584','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5547584">Cellular trade-offs and optimal resource allocation during cyanobacterial diurnal growth</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Knoop, Henning; Bockmayr, Alexander; Steuer, Ralf 2017-01-01 Cyanobacteria are an integral part of Earth’s biogeochemical cycles and a promising resource for the synthesis of renewable bioproducts from atmospheric CO2. Growth and metabolism of cyanobacteria are inherently tied to the diurnal rhythm of light availability. As yet, however, insight into the stoichiometric and energetic constraints of cyanobacterial diurnal growth is limited. Here, we develop a computational framework to investigate the optimal allocation of cellular resources during diurnal phototrophic growth using a genome-scale metabolic reconstruction of the cyanobacterium Synechococcus elongatus PCC 7942. We formulate phototrophic growth as an autocatalytic process and solve the resulting time-dependent resource allocation problem using constraint-based analysis. Based on a narrow and well-defined set of parameters, our approach results in an ab initio prediction of growth properties over a full diurnal cycle. The computational model allows us to study the optimality of metabolite partitioning during diurnal growth. The cyclic pattern of glycogen accumulation, an emergent property of the model, has timing characteristics that are in qualitative agreement with experimental findings. The approach presented here provides insight into the time-dependent resource allocation problem of phototrophic diurnal growth and may serve as a general framework to assess the optimality of metabolic strategies that evolved in phototrophic organisms under diurnal conditions. PMID:28720699 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFMPA33B..07F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFMPA33B..07F">The complexity of earth observation valuation: Modeling the patterns and processes of agricultural production and groundwater quality to construct a production possibilities frontier</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Forney, W.; Raunikar, R. P.; Bernknopf, R.; Mishra, S. 2012-12-01 A production possibilities frontier (PPF) is a graph comparing the production interdependencies for two commodities. In this case, the commodities are defined as the ecosystem services of agricultural production and groundwater quality. This presentation focuses on the refinement of techniques used in an application to estimate the value of remote sensing information. Value of information focuses on the use of uncertain and varying qualities of information within a specific decision-making context for a certain application, which in this case included land use, biogeochemical, hydrogeologic, economic and geospatial data and models. The refined techniques include deriving alternate patterns and processes of ecosystem functions, new estimates of ecosystem service values to construct a PPF, and the extension of this work into decision support systems. We have coupled earth observations of agricultural production with groundwater quality measurements to estimate the value of remote sensing information in northeastern Iowa to be 857M ± 198M (at the 2010 price level) per year. We will present an improved method for modeling crop rotation patterns to include multiple years of rotation, reduction in the assumptions associated with optimal land use allocations, and prioritized improvement of the resolution of input data (for example, soil resources and topography). The prioritization focuses on watersheds that were identified at a coarse-scale of analysis to have higher intensities of agricultural production and lower probabilities of groundwater survivability (in other words, remaining below a regulatory threshold for nitrate pollution) over time, and thus require finer-scaled modeling and analysis. These improved techniques and the simulation of certain scale-dependent policy and management actions, which trade-off the objectives of optimizing crop value versus maintaining potable groundwater, and provide new estimates for the empirical values of the PPF. The calculation of a PPF in this way provides a decision maker with a tool to consider the ramifications of different policies, management practices and regional objectives. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20020074590&hterms=cycling&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DTitle%26N%3D0%26No%3D50%26Ntt%3Dcycling','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20020074590&hterms=cycling&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DTitle%26N%3D0%26No%3D50%26Ntt%3Dcycling">Biogeochemical Cycling</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Bebout, Brad; Fonda, Mark (Technical Monitor) 2002-01-01 This lecture will introduce the concept of biogeochemical cycling. The roles of microbes in the cycling of nutrients, production and consumption of trace gases, and mineralization will be briefly introduced. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27010658','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27010658">Collaborative Emission Reduction Model Based on Multi-Objective Optimization for Greenhouse Gases and Air Pollutants.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Meng, Qing-chun; Rong, Xiao-xia; Zhang, Yi-min; Wan, Xiao-le; Liu, Yuan-yuan; Wang, Yu-zhi 2016-01-01 CO2 emission influences not only global climate change but also international economic and political situations. Thus, reducing the emission of CO2, a major greenhouse gas, has become a major issue in China and around the world as regards preserving the environmental ecology. Energy consumption from coal, oil, and natural gas is primarily responsible for the production of greenhouse gases and air pollutants such as SO2 and NOX, which are the main air pollutants in China. In this study, a mathematical multi-objective optimization method was adopted to analyze the collaborative emission reduction of three kinds of gases on the basis of their common restraints in different ways of energy consumption to develop an economic, clean, and efficient scheme for energy distribution. The first part introduces the background research, the collaborative emission reduction for three kinds of gases, the multi-objective optimization, the main mathematical modeling, and the optimization method. The second part discusses the four mathematical tools utilized in this study, which include the Granger causality test to analyze the causality between air quality and pollutant emission, a function analysis to determine the quantitative relation between energy consumption and pollutant emission, a multi-objective optimization to set up the collaborative optimization model that considers energy consumption, and an optimality condition analysis for the multi-objective optimization model to design the optimal-pole algorithm and obtain an efficient collaborative reduction scheme. In the empirical analysis, the data of pollutant emission and final consumption of energies of Tianjin in 1996-2012 was employed to verify the effectiveness of the model and analyze the efficient solution and the corresponding dominant set. In the last part, several suggestions for collaborative reduction are recommended and the drawn conclusions are stated. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4806840','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4806840">Collaborative Emission Reduction Model Based on Multi-Objective Optimization for Greenhouse Gases and Air Pollutants</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Zhang, Yi-min; Wan, Xiao-le; Liu, Yuan-yuan; Wang, Yu-zhi 2016-01-01 CO2 emission influences not only global climate change but also international economic and political situations. Thus, reducing the emission of CO2, a major greenhouse gas, has become a major issue in China and around the world as regards preserving the environmental ecology. Energy consumption from coal, oil, and natural gas is primarily responsible for the production of greenhouse gases and air pollutants such as SO2 and NOX, which are the main air pollutants in China. In this study, a mathematical multi-objective optimization method was adopted to analyze the collaborative emission reduction of three kinds of gases on the basis of their common restraints in different ways of energy consumption to develop an economic, clean, and efficient scheme for energy distribution. The first part introduces the background research, the collaborative emission reduction for three kinds of gases, the multi-objective optimization, the main mathematical modeling, and the optimization method. The second part discusses the four mathematical tools utilized in this study, which include the Granger causality test to analyze the causality between air quality and pollutant emission, a function analysis to determine the quantitative relation between energy consumption and pollutant emission, a multi-objective optimization to set up the collaborative optimization model that considers energy consumption, and an optimality condition analysis for the multi-objective optimization model to design the optimal-pole algorithm and obtain an efficient collaborative reduction scheme. In the empirical analysis, the data of pollutant emission and final consumption of energies of Tianjin in 1996–2012 was employed to verify the effectiveness of the model and analyze the efficient solution and the corresponding dominant set. In the last part, several suggestions for collaborative reduction are recommended and the drawn conclusions are stated. PMID:27010658 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018E%26ES..107a2007G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018E%26ES..107a2007G">Evaluation of heavy metal pollution in bogs of Tomsk region on change in biogeochemical activity of ericaceous shrubs</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gaskova, L. P. 2018-01-01 The article discusses the change in biogeochemical activity of plant species in bogs under the influence of various types of human impact (roads, cities, drainage of mires, fire). It has been established that ericaceous shrubs, depending on the species, react with varying degrees of intensity to anthropogenic influences. The biogeochemical activity of species increased by 2.5 to 4.8 times in polluted sites. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2681642','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2681642">Light-Dependent Transcriptional Regulation of Genes of Biogeochemical Interest in the Diploid and Haploid Life Cycle Stages of Emiliania huxleyi▿ †</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Richier, Sophie; Kerros, Marie-Emmanuelle; de Vargas, Colomban; Haramaty, Liti; Falkowski, Paul G.; Gattuso, Jean-Pierre 2009-01-01 The expression of genes of biogeochemical interest in calcifying and noncalcifying life stages of the coccolithophore Emiliania huxleyi was investigated. Transcripts potentially involved in calcification were tested through a light-dark cycle. These transcripts were more abundant in calcifying cells and were upregulated in the light. Their application as potential candidates for in situ biogeochemical proxies is also suggested. PMID:19304825 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://rosap.ntl.bts.gov/view/dot/23112','DOTNTL'); return false;" href="https://rosap.ntl.bts.gov/view/dot/23112">Optimized deployment of emission reduction technologies for large fleets.</a> <a target="_blank" rel="noopener noreferrer" href="http://ntlsearch.bts.gov/tris/index.do">DOT National Transportation Integrated Search</a> 2011-06-01 This research study produced an optimization framework for determining the most efficient emission : reduction strategies among vehicles and equipment in a large fleet. The Texas Department of : Transportations (TxDOTs) fleet data were utilized... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018PMB....63a5036G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018PMB....63a5036G">Optimization of spatiotemporally fractionated radiotherapy treatments with bounds on the achievable benefit</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gaddy, Melissa R.; Yıldız, Sercan; Unkelbach, Jan; Papp, Dávid 2018-01-01 Spatiotemporal fractionation schemes, that is, treatments delivering different dose distributions in different fractions, can potentially lower treatment side effects without compromising tumor control. This can be achieved by hypofractionating parts of the tumor while delivering approximately uniformly fractionated doses to the surrounding tissue. Plan optimization for such treatments is based on biologically effective dose (BED); however, this leads to computationally challenging nonconvex optimization problems. Optimization methods that are in current use yield only locally optimal solutions, and it has hitherto been unclear whether these plans are close to the global optimum. We present an optimization framework to compute rigorous bounds on the maximum achievable normal tissue BED reduction for spatiotemporal plans. The approach is demonstrated on liver tumors, where the primary goal is to reduce mean liver BED without compromising any other treatment objective. The BED-based treatment plan optimization problems are formulated as quadratically constrained quadratic programming (QCQP) problems. First, a conventional, uniformly fractionated reference plan is computed using convex optimization. Then, a second, nonconvex, QCQP model is solved to local optimality to compute a spatiotemporally fractionated plan that minimizes mean liver BED, subject to the constraints that the plan is no worse than the reference plan with respect to all other planning goals. Finally, we derive a convex relaxation of the second model in the form of a semidefinite programming problem, which provides a rigorous lower bound on the lowest achievable mean liver BED. The method is presented on five cases with distinct geometries. The computed spatiotemporal plans achieve 12-35% mean liver BED reduction over the optimal uniformly fractionated plans. This reduction corresponds to 79-97% of the gap between the mean liver BED of the uniform reference plans and our lower bounds on the lowest achievable mean liver BED. The results indicate that spatiotemporal treatments can achieve substantial reductions in normal tissue dose and BED, and that local optimization techniques provide high-quality plans that are close to realizing the maximum potential normal tissue dose reduction. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.B13E0608R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.B13E0608R">Riparian zone hydrology and biogeochemistry as a function of stream evolution stage in glaciated landscapes of the US Northeast</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Rook, S. P.; Vidon, P.; Walter, M. T. 2011-12-01 The management of riparian buffer strips is often regarded as one of the most economical and sustainable methods of managing non-point source pollution and water quality. However, current riparian management often follows a 'one size fits all' design, which fails to recognize the complexity of the many biogeochemical processes that regulate pollutant transformation and retention in these systems. This study addresses two critical gaps in knowledge: (1) How carbon, nitrogen, phosphorous, and iron cycles interact with one another (rather than individually). (2) How stream channel geometry and evolution regulate these nutrient cycles and greenhouse gas (GHG) dynamics in the near stream zone. This project specifically explores the hydrological and biogeochemical functioning of riparian zones across a gradient of stream meander evolution stages, with the primary goal of understanding and predicting potential interactions between nutrient dynamics in these systems. Key research questions include: (1) How does stream meander curvature affect riparian zone hydrology? (2) How does stream meander curvature influence riparian zone biogeochemistry? (3) What relationships exist among N, P, Fe, and GHG dynamics? We instrumented three riparian sites near Ithaca, NY, with a dense network of wells, piezometers, and static chambers. These sites represent three riparian zones along three evolution stages of stream meanders: an inner meander, a straight stream section, and an outer bend of the stream with an oxbow lake formation. In spring through fall 2011, water samples and gas samples were collected at a tri-weekly bases at each of the three sites. Water samples were analyzed for oxidation-reduction potential, dissolved oxygen, temperature, FeII/FeIII, nutrients (NO3-, NH4+, PO43-) and dissolved organic carbon (DOC). GHG fluxes at the soil-atmosphere interface were measured for N2O, CO2, and CH4 gases. We predict that stream curvature will significantly affect groundwater flow direction in the riparian zones. Owing to more prolonged saturation, we expect that the oxbow setting will exhibit anoxic conditions, and associated biogeochemistry. Finally, we hypothesize clear relationships among N, P, Fe, and GHG dynamics. In areas of significant denitrification, we expect to see an increase in Fe reduction, PO43- release, N2O emission, and CH4 emission, and a decrease in CO2 emission. Quantifying these interactions will enhance our ability to model riparian biogeochemical processes, promote water quality, and comprehend to what extent the promotion of riparian zones for nitrate removal is done at the expense of air quality (with respect to GHG emissions) and/or water quality (with respect to P). </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016DSRII.125..117W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016DSRII.125..117W">Repeated occurrences of methanogenic zones, diagenetic dolomite formation and linked silicate alteration in southern Bering Sea sediments (Bowers Ridge, IODP Exp. 323 Site U1341)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wehrmann, L. M.; Ockert, C.; Mix, A. C.; Gussone, N.; Teichert, B. M. A.; Meister, P. 2016-03-01 Diagenetic precipitates, such as dolomite, and the chemistry of residual deeply buried porewater often represent the only traces of past biogeochemical activity in marine sediments. A 600 m thick sedimentary section, recently drilled at Integrated Ocean Drilling Program (IODP) Site U1341 on Bowers Ridge (southern Bering Sea), provides insight into such a 4.3 Ma old paleo-diagenetic archive. Hard-lithified calcite-dolomite layers, and laminae of disseminated carbonate, were recovered in diatom-rich sediments over a depth range of 400 m. Carbon isotope values of the diagenetic carbonates between -16.6 and -14.4‰ (VPDB) and strontium isotope ratios of dolomites close to past seawater values suggest carbonate precipitation induced by the production of dissolved inorganic carbon (DIC) during elevated rates of organic carbon mineralization, primarily via sulfate reduction, at shallow sediment depth below the paleo-seafloor. Diagenetic carbonates at 280-440 m below seafloor were likely also produced by the intermittent onset of sulfate reduction coupled to the anaerobic oxidation of methane (AOM) at sulfate-methane transition zones (SMTZ). These microbially mediated processes do not occur in the sediment at this site at present but were likely connected to the presence of a methanogenic zone at 2.58-2.51 Ma. A minimum in sulfate concentrations in modern porewaters and low sedimentary Ba/Al ratios resulting from former sulfate depletion are reminiscent of the presence of this large methanogenic zone. The minimum in sulfate concentrations is reflected in a minimum in magnesium concentrations, less radiogenic strontium and isotopically light calcium in the porewater. It is proposed that magnesium was removed from the porewater during carbonate precipitation and volcanic ash alteration which occurred in the former methanogenic zone and also released strontium with a less radiogenic isotope ratio and isotopically light calcium into the porewater. The isotopic composition of porewater calcium was also influenced by ammonium-calcium exchange on clay minerals and carbonate recrystallization. Our study elucidates the response of porewater element concentrations and isotopic profiles interlinked with the formation of diagenetic carbonates to changes in the deposition of organic carbon in sediments of deeper water sites (>2000 m water depth) over prolonged timescales. It shows that variations in biogeochemical processes in response to changes in oceanographic conditions and a dynamic subseafloor biogeochemical zonation have to also be taken into account at these deep water sites for a global assessment of organic carbon burial fluxes and remineralization. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.H51A1168L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.H51A1168L">Soil Oxidation-Reduction Potential and Plant Photosynthetic Capacity in the Northern Pantanal of Mato Grosso, Brazil</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lathuilliere, M. J.; Johnson, M. S.; Dalmagro, H. J.; Pinto Junior, O. B.; Couto, E. G. 2013-12-01 Plant communities of the Pantanal wetland are able to survive long periods of climatic and physiological stress in the dry and wet seasons. During inundation, soil oxygen demand increases dramatically as reducing soil conditions create stress in the root system with possible impacts on photosynthetic capacity of plants. We look at inundation cycles of a tree island (locally known as a cordilheira) in the Northern Pantanal near Poconé, Mato Grosso, and relate soil oxidation-reduction potential and soil oxygen depletion to the photosynthetic capacity of two plant communities of flooded scrub forest (Vochysia divergens and Curatela americana). Results show a drop in soil oxidation-reduction potential of over 400 mV, to levels below the absolute value of -200 mV, following inundation around the tree island. Both plant species showed increased carbon assimilation at highest soil oxygen demand despite a change in stomatal conductance, suggesting adaptation to the inundated environment. Absolute values of soil oxidation-reduction potential also allow for the determination of specific soil chemical reactions characteristic of the tree island environment, namely the reduction of iron(III), or carbon dioxide which in turn produces methane. Our combined analysis of soil chemistry with plant ecophysiology allows for a better understanding of soil-plant interactions in the Pantanal, specifically the drivers of biogeochemical processes between inundation periods. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26079555','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26079555">An interprovincial cooperative game model for air pollution control in China.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Xue, Jian; Zhao, Laijun; Fan, Longzhen; Qian, Ying 2015-07-01 The noncooperative air pollution reduction model (NCRM) that is currently adopted in China to manage air pollution reduction of each individual province has inherent drawbacks. In this paper, we propose a cooperative air pollution reduction game model (CRM) that consists of two parts: (1) an optimization model that calculates the optimal pollution reduction quantity for each participating province to meet the joint pollution reduction goal; and (2) a model that distribute the economic benefit of the cooperation (i.e., pollution reduction cost saving) among the provinces in the cooperation based on the Shapley value method. We applied the CRM to the case of SO2 reduction in the Beijing-Tianjin-Hebei region in China. The results, based on the data from 2003-2009, show that cooperation helps lower the overall SO2 pollution reduction cost from 4.58% to 11.29%. Distributed across the participating provinces, such a cost saving from interprovincial cooperation brings significant benefits to each local government and stimulates them for further cooperation in pollution reduction. Finally, sensitivity analysis is performed using the year 2009 data to test the parameters' effects on the pollution reduction cost savings. China is increasingly facing unprecedented pressure for immediate air pollution control. The current air pollution reduction policy does not allow cooperation and is less efficient. In this paper we developed a cooperative air pollution reduction game model that consists of two parts: (1) an optimization model that calculates the optimal pollution reduction quantity for each participating province to meet the joint pollution reduction goal; and (2) a model that distributes the cooperation gains (i.e., cost reduction) among the provinces in the cooperation based on the Shapley value method. The empirical case shows that such a model can help improve efficiency in air pollution reduction. The result of the model can serve as a reference for Chinese government pollution reduction policy design. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19970018785','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19970018785">Effects of Planetary Gear Ratio on Mean Service Life</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Savage, M.; Rubadeux, K. L.; Coe, H. H. 1996-01-01 Planetary gear transmissions are compact, high-power speed reductions which use parallel load paths. The range of possible reduction ratios is bounded from below and above by limits on the relative size of the planet gears. For a single plane transmission, the planet gear has no size at a ratio of two. As the ratio increases, so does the size of the planets relative to the sizes of the sun and ring. Which ratio is best for a planetary reduction can be resolved by studying a series of optimal designs. In this series, each design is obtained by maximizing the service life for a planetary with a fixed size, gear ratio, input speed power and materials. The planetary gear reduction service life is modeled as a function of the two-parameter Weibull distributed service lives of the bearings and gears in the reduction. Planet bearing life strongly influences the optimal reduction lives which point to an optimal planetary reduction ratio in the neighborhood of four to five. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H54B..02A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H54B..02A">Climate Regulation Services of Natural and Managed Ecosystems of the Americas</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Anderson-Teixeira, K. J.; Snyder, P. K.; Twine, T. E.; Costa, M. H.; Cuadra, S.; DeLucia, E. H. 2011-12-01 Terrestrial ecosystems regulate climate through both biogeochemical mechanisms (greenhouse gas regulation) and biophysical mechanisms (regulation of water and energy). Land management therefore provides some of the most effective strategies for climate change mitigation. However, most policies aimed at climate protection through land management, including UNFCCC mechanisms and bioenergy sustainability standards, account only for biogeochemical climate services. By ignoring biophysical climate regulation services that in some cases offset the biogeochemical regulation services, these policies run the risk of failing to advance the best climate solutions. Quantifying the combined value of biogeochemical and biophysical climate regulation services remains an important challenge. Here, we use a combination of data synthesis and modeling to quantify how biogeochemical and biophysical effects combine to shape the climate regulation value (CRV) of 18 natural and managed ecosystem types across the Western Hemisphere. Natural ecosystems generally had higher CRVs than agroecosystems, largely driven by differences in biogeochemical services. Biophysical contributions ranged from minimal to dominant. They were highly variable in space and across ecosystem types, and their relative importance varied strongly with the spatio-temporal scale of analysis. Our findings pertain to current efforts to protect climate through land management. Specifically, they reinforce the importance of protecting tropical forests and recent findings that the climatic effects of bioenergy production may be somewhat more positive than previously estimated. Given that biophysical effects in some cases dominate, ensuring effective climate protection through land management requires consideration of combined biogeochemical and biophysical climate regulation services. While quantification of ecosystem climate services is necessarily complex, our CRV index serves as one potential approach to measure the full climate services of terrestrial ecosystems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS43B2035W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS43B2035W">Biogeochemical Coupling between Ocean and Sea Ice</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Wang, S.; Jeffery, N.; Maltrud, M. E.; Elliott, S.; Wolfe, J. 2016-12-01 Biogeochemical processes in ocean and sea ice are tightly coupled at high latitudes. Ongoing changes in Arctic and Antarctic sea ice domain likely influence the coupled system, not only through physical fields but also biogeochemical properties. Investigating the system and its changes requires representation of ocean and sea ice biogeochemical cycles, as well as their coupling in Earth System Models. Our work is based on ACME-HiLAT, a new offshoot of the Community Earth System Model (CESM), including a comprehensive representation of marine ecosystems in the form of the Biogeochemical Elemental Cycling Module (BEC). A full vertical column sea ice biogeochemical module has recently been incorporated into the sea ice component. We have further introduced code modifications to couple key growth-limiting nutrients (N, Si, Fe), dissolved and particulate organic matter, and phytoplankton classes that are important in polar regions between ocean and sea ice. The coupling of ocean and sea ice biology-chemistry will enable representation of key processes such as the release of important climate active constituents or seeding algae from melting sea ice into surface waters. Sensitivity tests suggest sea ice and ocean biogeochemical coupling influences phytoplankton competition, biological production, and the CO2 flux. Sea ice algal seeding plays an important role in determining phytoplankton composition of Arctic early spring blooms, since different groups show various responses to the seeding biomass. Iron coupling leads to increased phytoplankton biomass in the Southern Ocean, which also affects carbon uptake via the biological pump. The coupling of macronutrients and organic matter may have weaker influences on the marine ecosystem. Our developments will allow climate scientists to investigate the fully coupled responses of the sea ice-ocean BGC system to physical changes in polar climate. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27059435','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27059435">Dynamic, mechanistic, molecular-level modelling of cyanobacteria: Anabaena and nitrogen interaction.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Hellweger, Ferdi L; Fredrick, Neil D; McCarthy, Mark J; Gardner, Wayne S; Wilhelm, Steven W; Paerl, Hans W 2016-09-01 Phytoplankton (eutrophication, biogeochemical) models are important tools for ecosystem research and management, but they generally have not been updated to include modern biology. Here, we present a dynamic, mechanistic, molecular-level (i.e. gene, transcript, protein, metabolite) model of Anabaena - nitrogen interaction. The model was developed using the pattern-oriented approach to model definition and parameterization of complex agent-based models. It simulates individual filaments, each with individual cells, each with genes that are expressed to yield transcripts and proteins. Cells metabolize various forms of N, grow and divide, and differentiate heterocysts when fixed N is depleted. The model is informed by observations from 269 laboratory experiments from 55 papers published from 1942 to 2014. Within this database, we identified 331 emerging patterns, and, excluding inconsistencies in observations, the model reproduces 94% of them. To explore a practical application, we used the model to simulate nutrient reduction scenarios for a hypothetical lake. For a 50% N only loading reduction, the model predicts that N fixation increases, but this fixed N does not compensate for the loading reduction, and the chlorophyll a concentration decreases substantially (by 33%). When N is reduced along with P, the model predicts an additional 8% reduction (compared to P only). © 2016 Society for Applied Microbiology and John Wiley & Sons Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B11G1741A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B11G1741A">Deep subsurface life in Bengal Fan sediments (IODP Exp. 354)</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Adhikari, R. R.; Heuer, V. B.; Elvert, M.; Kallmeyer, J.; Kitte, J. A.; Wörmer, L.; Hinrichs, K. U. 2017-12-01 We collected Bengal Fan sediment samples along a 8°N transect during International Ocean Discovery Program Expedition 354 (February - March 2015, Singapore - Colombo, Sri Lanka) to study subseafloor life in this, as yet unstudied, area. Among other biogeochemical parameters, we quantified microbial biomass by analyzing prokaryotic cells using epifluorescence microscopy after detaching cells from the sediment, and bacterial endospores by analyzing the diagnostic biomarker dipicolinic acid (DPA) by detection of fluorescence of the terbium-DPA complex. To gain understanding of total microbial activity, we quantified hydrogen utilization potential of hydrogenase enzymes, which are ubiquitous in subsurface microorganisms, by using a tritium assay. We measured highest cell concentrations of ca. 108 cells g-1 in shallow sediments close to the seafloor. These concentrations are one to two orders of magnitude lower than in most marine continental margin settings [1]. Similar to the global trend [1], cell concentrations decreased with depth according to a power-law function. Endospore concentrations scattered between ca. 105 and 107 cells g-1 sediment at all sites and depths. We could not observe a clear relationship of endospore concentration and sediment depth; instead, it appears to be linked to lithology and total organic carbon content. Bulk Hydrogenase enzyme activity ranged from nmolar to μmolar range of H2 g-1d-1. Similar to previous observations [2], per-cell hydrogen utilization depends on vertical biogeochemical zones, which could be due to the differences in hydrogen utilization requirements/efficiency of the respective metabolic processes such as sulfate reduction, methanogenesis, fermentation etc. Bengal fan is highly dynamic due to channel and levee systems and the sediments are dominated by turbidites, thick sand layers and hemipelagic deposits, which may control biogeochemical zonation. Based on our microbial biomass and activity data, we suggest that the nature, quality and origin of sedimentary material influence the deep subsurface life. [1] Kallmeyer et al., (2012) PNAS 109(40), 16213-16216 [2] Adhikari et al., (2016) Frontiers in Microbiology 7:8 </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_13");'>13</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li class="active">15</li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_16" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li class="active">16</li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="301"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..17.8403A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..17.8403A">The significance of GW-SW interactions for biogeochemical processes in sandy streambeds</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Arnon, Shai; De Falco, Natalie; Fox, Aryeh; Laube, Gerrit; Schmidt, Christian; Fleckenstein, Jan; Boano, Fulvio 2015-04-01 Stream-groundwater interactions have a major impact on hyporheic exchange fluxes in sandy streambeds. However, the physical complexity of natural streams has limited our ability to study these types of interactions systematically, and to evaluate their importance to biogeochemical processes and nutrient cycling. In this work we were able to quantify the effect of losing and gaining fluxes on hyporheic exchange and nutrient cycling in homogeneous and heterogeneous streambeds by combining experiments in laboratory flumes and modeling. Tracer experiments for measuring hyporheic exchange were done using dyes and NaCl under various combinations of overlying water velocity and losing or gaining fluxes. Nutrient cycling experiments were conducted after growing a benthic biofilm by spiking with Sodium Benzoate (as a source of labile dissolved organic carbon, DOC) and measuring DOC and oxygen dynamics. The combination of experimental observations and modeling revealed that interfacial transport increases with the streambed hydraulic conductivity and proportional to the square of the overlying water velocity. Hyporheic exchange fluxes under losing and gaining flow conditions were similar, and became smaller when the losing or gaining flux increases. Increasing in streambed hydraulic conductivity led to higher hyporheic fluxes and reduction in the effects of losing and gaining flow conditions to constrain exchange. Despite the evident effect of flow conditions on hyporheic exchange, labile DOC uptake was positively linked to increasing overlying water velocity but was not affected by losing and gaining fluxes. This is because microbial aerobic activity was taking place at the upper few millimeters of the streambed as shown by local oxygen consumption rates, which was measured using microelectrodes. Based on modeling work, it is expected that GW-SW interaction will be more significant for less labile DOC and anaerobic processes. Our results enable us to study systematically the coupling between flow conditions and biogeochemical processes under highly controlled physical and chemical conditions and are expected to improve our understanding of nutrient cycling in streams. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JMS...174...89L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JMS...174...89L">Impact of urban effluents on summer hypoxia in the highly turbid Gironde Estuary, applying a 3D model coupling hydrodynamics, sediment transport and biogeochemical processes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lajaunie-Salla, Katixa; Wild-Allen, Karen; Sottolichio, Aldo; Thouvenin, Bénédicte; Litrico, Xavier; Abril, Gwenaël 2017-10-01 Estuaries are increasingly degraded due to coastal urban development and are prone to hypoxia problems. The macro-tidal Gironde Estuary is characterized by a highly concentrated turbidity maximum zone (TMZ). Field observations show that hypoxia occurs in summer in the TMZ at low river flow and a few days after the spring tide peak. In situ data highlight lower dissolved oxygen (DO) concentrations around the city of Bordeaux, located in the upper estuary. Interactions between multiple factors limit the understanding of the processes controlling the dynamics of hypoxia. A 3D biogeochemical model was developed, coupled with hydrodynamics and a sediment transport model, to assess the contribution of the TMZ and the impact of urban effluents through wastewater treatment plants (WWTPs) and sewage overflows (SOs) on hypoxia. Our model describes the transport of solutes and suspended material and the biogeochemical mechanisms impacting oxygen: primary production, degradation of all organic matter (i.e. including phytoplankton respiration, degradation of river and urban watershed matter), nitrification and gas exchange. The composition and the degradation rates of each variable were characterized by in situ measurements and experimental data from the study area. The DO model was validated against observations in Bordeaux City. The simulated DO concentrations show good agreement with field observations and satisfactorily reproduce the seasonal and neap-spring time scale variations around the city of Bordeaux. Simulations show a spatial and temporal correlation between the formation of summer hypoxia and the location of the TMZ, with minimum DO centered in the vicinity of Bordeaux. To understand the contribution of the urban watershed forcing, different simulations with the presence or absence of urban effluents were compared. Our results show that in summer, a reduction of POC from SO would increase the DO minimum in the vicinity of Bordeaux by 3% of saturation. Omitting discharge from SO and WWTPs, DO would improve by 10% of saturation and mitigate hypoxic events. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B21C0462O','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B21C0462O">Linking Metabolism, Elemental Cycles, and Environmental Conditions in the Deep Biosphere: Growth of a Model Extremophile, Archaeoglobus fulgidus, Under High-Pressure Conditions</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Oliver, G. C. M.; Cario, A.; Rogers, K. L. 2015-12-01 A majority of Earth's biosphere is hosted in subsurface environments where global-scale biogeochemical and energy cycles are driven by diverse microbial communities that operate on and are influenced by micro-scale environmental variables. While the subsurface hosts a variety of geochemical and geothermal conditions, elevated pressures are common to all subsurface ecosystems. Understanding how microbes adapt to and thrive in high-pressure environments is essential to linking microbial subsurface processes with global-scale cycles. Here we are using a model extremophile, Archaeoglobus fulgidus, to determine how elevated pressures affect the growth, metabolism, and physiology of subsurface microorganisms. A. fulgidus cycles carbon and sulfur via heterotrophic and autotrophic sulfate reduction in various high temperature and high-pressure niches including shallow marine vents, deep-sea hydrothermal vents, and deep oil reservoirs. Here we report the results of A. fulgidus growth experiments at optimum temperature, 83°C, and pressures up to 600 bars. Exponential growth was observed over the entire pressure range, though growth rates were diminished at 500 and 600 bars compared to ambient pressure experimental controls. At pressures up to 400 bars, cell density yields and growth rates were at least as high as ambient pressure controls. Elevated pressures and extended incubation times stimulated cell flocculation, a common stress response in this strain, and cellular morphology was affected at pressures exceeding 400 bars. These results suggest that A. fulgidus continues carbon, sulfur and energy cycling unaffected by elevated pressures up to 400 bars, representing a variety of subsurface environments. The ability of subsurface organisms to drive biogeochemical cycles at elevated pressures is a critical link between the surface and subsurface biospheres and understanding how species-scale processes operate under these conditions is a vital part of global-scale biogeochemical models. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29126247','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29126247">The mycorrhizal type governs root exudation and nitrogen uptake of temperate tree species.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Liese, Rebecca; Lübbe, Torben; Albers, Nora W; Meier, Ina C 2018-01-01 Even though the two dominant mycorrhizal associations of temperate tree species differentially couple carbon (C) and nitrogen (N) cycles in temperate forests, systematic differences between the biogeochemical cycles of arbuscular mycorrhizal (AM) and ectomycorrhizal (ECM) tree species remain poorly described. A classification according to the mycorrhizal type offers the chance, though, to develop a global frame concept for the prediction of temperate ecosystem responses to environmental change. Focusing on the influence of mycorrhizal types on two key plant processes of biogeochemical cycling (root exudation and N acquisition), we investigated four temperate deciduous tree species per mycorrhizal type in a drought experiment in large mesocosms. We hypothesized that (H1) C loss by root exudation is higher in ECM than in AM trees, (H2) drought leads to higher reductions in root exudation of drought-sensitive ECM trees and (H3) inorganic N uptake is higher in AM than in ECM trees. In contradiction to H2, we found no systematic difference in root exudation between the mycorrhizal types at ample soil moisture, but almost twofold higher exudation in ECM trees when exposed to soil drought. In addition, photosynthetic C cost of root exudation strongly increased by ~10-fold in drought-treated ECM trees, while it only doubled in AM trees, which confirms H1. With respect to H3, we corroborated that AM trees had higher absolute and relative inorganic N acquisition rates than ECM trees, while the organic N uptake did not differ between mycorrhizal types. We conclude that ECM trees are less efficient in inorganic N uptake than AM trees, but ECM trees increase root C release as an adaptive response to dry soil to maintain hydraulic conductivity and/or nutrient availability. These systematic differences in key biogeochemical processes support hints on the key role of the mycorrhizal types in coupling C and N cycles in temperate forests. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20040012617','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20040012617">Biogeochemical Cycles in Degraded Lands</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Davidson, Eric A.; Vieira, Ima Celia G.; ReisdeCarvalho, Claudio Jose; DeanedeAbreuSa, Tatiana; deSouzaMoutinho, Paulo R.; Figueiredo, Ricardo O.; Stone, Thomas A. 2004-01-01 The objectives of this project were to define and describe the types of landscapes that fall under the broad category of "degraded lands" and to study biogeochemical cycles across this range of degradation found in secondary forests. We define degraded land as that which has lost part of its capacity of renovation of a productive ecosystem, either in the context of agroecosystems or as native communities of vegetation. This definition of degradation permits evaluation of biogeochemical constraints to future land uses. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://aem.asm.org/content/55/9/2333.abstract','USGSPUBS'); return false;" href="http://aem.asm.org/content/55/9/2333.abstract">Selenate reduction to elemental selenium by anaerobic bacteria in sediments and culture: biogeochemical significance of a novel, sulfate-independent respiration</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Oremland, Ronald S.; Hollibaugh, James T.; Maest, Ann S.; Presser, Theresa S.; Miller, Laurence G.; Culbertson, Charles W. 1989-01-01 Interstitial water profiles of SeO42−, SeO32−, SO42−, and Cl− in anoxic sediments indicated removal of the seleno-oxyanions by a near-surface process unrelated to sulfate reduction. In sediment slurry experiments, a complete reductive removal of SeO42− occurred under anaerobic conditions, was more rapid with H2 or acetate, and was inhibited by O2, NO3−, MnO2, or autoclaving but not by SO42− or FeOOH. Oxidation of acetate in sediments could be coupled to selenate but not to molybdate. Reduction of selenate to elemental selenium was determined to be the mechanism for loss from solution. Selenate reduction was inhibited by tungstate and chromate but not by molybdate. A small quantity of the elemental selenium precipitated into sediments from solution could be resolublized by oxidation with either nitrate or FeOOH, but not with MnO2. A bacterium isolated from estuarine sediments demonstrated selenate-dependent growth on acetate, forming elemental selenium and carbon dioxide as respiratory end products. These results indicate that dissimilatory selenate reduction to elemental selenium is the major sink for selenium oxyanions in anoxic sediments. In addition, they suggest application as a treatment process for removing selenium oxyanions from wastewaters and also offer an explanation for the presence of selenite in oxic waters. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013ESASP.710E..44D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013ESASP.710E..44D">Guiding Biogeochemical Campaigns with High Resolution Altimetry: Waiting for the SWOT Mission</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> d'Ovidio, Francesco; Zhou, Meng; Park, Young Hyang; Nencioli, Francesco; Resplandy, Laure; Doglioli, Andrea; Petrenko, Anne; Blain, Stephane; Queguiner, Bernard 2013-09-01 Biogeochemical processes in the ocean are strongly affected by the horizontal mesoscale ( 10-100 km) and submesoscale (1-10 km) circulation. Eddies and filaments can create strong dishomogeneity, either amplifying small-scale diffusion processes (mixing) or creating tracer reservoirs. This variability has a direct effect on the biogeochemical budgets - controlling for instances tracer fluxes across climatological fronts, or part of the vertical exchanges. This variability also provides a challenge to in situ studies, because sites few tens of kms or few weeks apart may be representative of very different situations. Here we discuss how altimetry observation can be exploited in order to track in near- real-time transport barriers and mixing regions and guide a biogeochemical adaptative sampling strategy. As a case study, we focus on the recent KEOPS2 campaign (Kerguelen region, October-November 2012) which employed Lagrangian diagnostics of a specifically designed high resolution, regional altimetric product produced by CLS (with support from CNES) analyzed with several Lagrangian diagnostics. Such approach anticipates possible uses of incoming high resolution altimetry data for biogeochemical studies. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018AREPS..46..521B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018AREPS..46..521B">Role of Soil Erosion in Biogeochemical Cycling of Essential Elements: Carbon, Nitrogen, and Phosphorus</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Berhe, Asmeret Asefaw; Barnes, Rebecca T.; Six, Johan; Marín-Spiotta, Erika 2018-05-01 Most of Earth's terrestrial surface is made up of sloping landscapes. The lateral distribution of topsoil by erosion controls the availability, stock, and persistence of essential elements in the terrestrial ecosystem. Over the last two decades, the role of soil erosion in biogeochemical cycling of essential elements has gained considerable interest from the climate, global change, and biogeochemistry communities after soil erosion and terrestrial sedimentation were found to induce a previously unaccounted terrestrial sink for atmospheric carbon dioxide. More recent studies have highlighted the role of erosion in the persistence of organic matter in soil and in the biogeochemical cycling of elements beyond carbon . Here we synthesize available knowledge and data on how erosion serves as a major driver of biogeochemical cycling of essential elements. We address implications of erosion-driven changes in biogeochemical cycles on the availability of essential elements for primary production, on the magnitude of elemental exports downstream, and on the exchange of greenhouse gases from the terrestrial ecosystem to the atmosphere. Furthermore, we explore fates of eroded material and how terrestrial mass movement events play major roles in modifying Earth's climate. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26744050','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26744050">The role of biogeochemical hotspots, landscape heterogeneity, and hydrological connectivity for minimizing forestry effects on water quality.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Laudon, Hjalmar; Kuglerová, Lenka; Sponseller, Ryan A; Futter, Martyn; Nordin, Annika; Bishop, Kevin; Lundmark, Tomas; Egnell, Gustaf; Ågren, Anneli M 2016-02-01 Protecting water quality in forested regions is increasingly important as pressures from land-use, long-range transport of air pollutants, and climate change intensify. Maintaining forest industry without jeopardizing sustainability of surface water quality therefore requires new tools and approaches. Here, we show how forest management can be optimized by incorporating landscape sensitivity and hydrological connectivity into a framework that promotes the protection of water quality. We discuss how this approach can be operationalized into a hydromapping tool to support forestry operations that minimize water quality impacts. We specifically focus on how hydromapping can be used to support three fundamental aspects of land management planning including how to (i) locate areas where different forestry practices can be conducted with minimal water quality impact; (ii) guide the off-road driving of forestry machines to minimize soil damage; and (iii) optimize the design of riparian buffer zones. While this work has a boreal perspective, these concepts and approaches have broad-scale applicability. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70186939','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70186939">Recent directions taken in water, energy, and biogeochemical budgets research</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Lins, Harry F. 1994-01-01 Understanding and predicting global change is a major scientific focus of the late 20th century. Although atmospheric scientists have made substantial progress in developing models that account for many components of the climate system, significant progress is needed in understanding processes associated with the exchange of water, energy, and carbon between terrestrial systems and the atmosphere.To strengthen terrestrial process research, especially research associated with the interactions of water, energy, gases, nutrients, and vegetation, the U.S. Geological Survey initiated an intensive study of Water, Energy, and Biogeochemical Budgets (WEBB). WEBB is aimed at improving understanding of processes controlling terrestrial water, energy, and biogeochemical fluxes, their interactions, and their relations to climatic variables; and the ability to predict continental water, energy, and biogeochemical budgets over a range of spatial and temporal scales. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70188041','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70188041">A suggestion for computing objective function in model calibration</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Wu, Yiping; Liu, Shuguang 2014-01-01 A parameter-optimization process (model calibration) is usually required for numerical model applications, which involves the use of an objective function to determine the model cost (model-data errors). The sum of square errors (SSR) has been widely adopted as the objective function in various optimization procedures. However, ‘square error’ calculation was found to be more sensitive to extreme or high values. Thus, we proposed that the sum of absolute errors (SAR) may be a better option than SSR for model calibration. To test this hypothesis, we used two case studies—a hydrological model calibration and a biogeochemical model calibration—to investigate the behavior of a group of potential objective functions: SSR, SAR, sum of squared relative deviation (SSRD), and sum of absolute relative deviation (SARD). Mathematical evaluation of model performance demonstrates that ‘absolute error’ (SAR and SARD) are superior to ‘square error’ (SSR and SSRD) in calculating objective function for model calibration, and SAR behaved the best (with the least error and highest efficiency). This study suggests that SSR might be overly used in real applications, and SAR may be a reasonable choice in common optimization implementations without emphasizing either high or low values (e.g., modeling for supporting resources management). </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018ESD.....9..525B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018ESD.....9..525B">The impact of uncertainty on optimal emission policies</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Botta, Nicola; Jansson, Patrik; Ionescu, Cezar 2018-05-01 We apply a computational framework for specifying and solving sequential decision problems to study the impact of three kinds of uncertainties on optimal emission policies in a stylized sequential emission problem.We find that uncertainties about the implementability of decisions on emission reductions (or increases) have a greater impact on optimal policies than uncertainties about the availability of effective emission reduction technologies and uncertainties about the implications of trespassing critical cumulated emission thresholds. The results show that uncertainties about the implementability of decisions on emission reductions (or increases) call for more precautionary policies. In other words, delaying emission reductions to the point in time when effective technologies will become available is suboptimal when these uncertainties are accounted for rigorously. By contrast, uncertainties about the implications of exceeding critical cumulated emission thresholds tend to make early emission reductions less rewarding. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.B13B1770W','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.B13B1770W">Global Emissions of Nitrous Oxide: Key Source Sectors, their Future Activities and Technical Opportunities for Emission Reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Winiwarter, W.; Höglund-Isaksson, L.; Klimont, Z.; Schöpp, W.; Amann, M. 2017-12-01 Nitrous oxide originates primarily from natural biogeochemical processes, but its atmospheric concentrations have been strongly affected by human activities. According to IPCC, it is the third largest contributor to the anthropogenic greenhouse gas emissions (after carbon dioxide and methane). Deep decarbonization scenarios, which are able to constrain global temperature increase within 1.5°C, require strategies to cut methane and nitrous oxide emissions on top of phasing out carbon dioxide emissions. Employing the Greenhouse gas and Air pollution INteractions and Synergies (GAINS) model, we have estimated global emissions of nitrous oxide until 2050. Using explicitly defined emission reduction technologies we demonstrate that, by 2030, about 26% ± 9% of the emissions can be avoided assuming full implementation of currently existing reduction technologies. Nearly a quarter of this mitigation can be achieved at marginal costs lower than 10 Euro/t CO2-eq with the chemical industry sector offering important reductions. Overall, the largest emitter of nitrous oxide, agriculture, also provides the largest emission abatement potentials. Emission reduction may be achieved by precision farming methods (variable rate technology) as well as by agrochemistry (nitrification inhibitors). Regionally, the largest emission reductions are achievable where intensive agriculture and industry are prevalent (production and application of mineral fertilizers): Centrally Planned Asia including China, North and Latin America, and South Asia including India. Further deep cuts in nitrous oxide emissions will require extending reduction efforts beyond strictly technological solutions, i.e., considering behavioral changes, including widespread adoption of "healthy diets" minimizing excess protein consumption. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1224058-uranium-isotopes-fingerprint-biotic-reduction','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1224058-uranium-isotopes-fingerprint-biotic-reduction">Uranium isotopes fingerprint biotic reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Stylo, Malgorzata; Neubert, Nadja; Wang, Yuheng; ... 2015-04-20 Knowledge of paleo-redox conditions in the Earth’s history provides a window into events that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox processes remains unexplored due to the inability to discriminate biotic from abiotic redox transformations in the rock record. The ability to deconvolute these two processes would provide a means to identify environmental niches in which microbial activity was prevalent at a specific time in paleo-history and to correlate specific biogeochemical events with the corresponding microbial metabolism. Here, we demonstrate that the isotopic signature associated with microbial reduction of hexavalent uranium (U),more » i.e., the accumulation of the heavy isotope in the U(IV) phase, is readily distinguishable from that generated by abiotic uranium reduction in laboratory experiments. Thus, isotope signatures preserved in the geologic record through the reductive precipitation of uranium may provide the sought-after tool to probe for biotic processes. Because uranium is a common element in the Earth’s crust and a wide variety of metabolic groups of microorganisms catalyze the biological reduction of U(VI), this tool is applicable to a multiplicity of geological epochs and terrestrial environments. The findings of this study indicate that biological activity contributed to the formation of many authigenic U deposits, including sandstone U deposits of various ages, as well as modern, Cretaceous, and Archean black shales. In addition, engineered bioremediation activities also exhibit a biotic signature, suggesting that, although multiple pathways may be involved in the reduction, direct enzymatic reduction contributes substantially to the immobilization of uranium.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=238300&keyword=human+AND+communication&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=238300&keyword=human+AND+communication&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Environmental Optimization Using the WAste Reduction Algorithm (WAR)</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Traditionally chemical process designs were optimized using purely economic measures such as rate of return. EPA scientists developed the WAste Reduction algorithm (WAR) so that environmental impacts of designs could easily be evaluated. The goal of WAR is to reduce environme... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017GMD....10.4525H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017GMD....10.4525H">CHROTRAN 1.0: A mathematical and computational model for in situ heavy metal remediation in heterogeneous aquifers</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hansen, Scott K.; Pandey, Sachin; Karra, Satish; Vesselinov, Velimir V. 2017-12-01 Groundwater contamination by heavy metals is a critical environmental problem for which in situ remediation is frequently the only viable treatment option. For such interventions, a multi-dimensional reactive transport model of relevant biogeochemical processes is invaluable. To this end, we developed a model, chrotran, for in situ treatment, which includes full dynamics for five species: a heavy metal to be remediated, an electron donor, biomass, a nontoxic conservative bio-inhibitor, and a biocide. Direct abiotic reduction by donor-metal interaction as well as donor-driven biomass growth and bio-reduction are modeled, along with crucial processes such as donor sorption, bio-fouling, and biomass death. Our software implementation handles heterogeneous flow fields, as well as arbitrarily many chemical species and amendment injection points, and features full coupling between flow and reactive transport. We describe installation and usage and present two example simulations demonstrating its unique capabilities. One simulation suggests an unorthodox approach to remediation of Cr(VI) contamination. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1374320','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1374320">CHROTRAN: a mathematical and computational model for in situ heavy metal remediation in heterogeneous aquifers</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Hansen, Scott; Pandey, Sachin; Karra, Satish Groundwater contamination by heavy metals is a critical environmental problem for which in situ remediation is frequently the only viable treatment option. For such interventions, a three-dimensional reactive transport model of relevant biogeochemical processes is invaluable. To this end, we developed a model, CHROTRAN, for in situ treatment, which includes full dynamics for five species: a heavy metal to be remediated, an electron donor, biomass, a nontoxic conservative bio-inhibitor, and a biocide. Direct abiotic reduction by donor-metal interaction as well as donor-driven biomass growth and bio-reduction are modeled, along with crucial processes such as donor sorption, bio-fouling and biomass death.more » Our software implementation handles heterogeneous flow fields, arbitrarily many chemical species and amendment injection points, and features full coupling between flow and reactive transport. We describe installation and usage and present two example simulations demonstrating its unique capabilities. One simulation suggests an unorthodox approach to remediation of Cr(VI) contamination.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1374320-chrotran-mathematical-computational-model-situ-heavy-metal-remediation-heterogeneous-aquifers','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1374320-chrotran-mathematical-computational-model-situ-heavy-metal-remediation-heterogeneous-aquifers">CHROTRAN: a mathematical and computational model for in situ heavy metal remediation in heterogeneous aquifers</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Hansen, Scott; Pandey, Sachin; Karra, Satish; ... 2017-04-25 Groundwater contamination by heavy metals is a critical environmental problem for which in situ remediation is frequently the only viable treatment option. For such interventions, a three-dimensional reactive transport model of relevant biogeochemical processes is invaluable. To this end, we developed a model, CHROTRAN, for in situ treatment, which includes full dynamics for five species: a heavy metal to be remediated, an electron donor, biomass, a nontoxic conservative bio-inhibitor, and a biocide. Direct abiotic reduction by donor-metal interaction as well as donor-driven biomass growth and bio-reduction are modeled, along with crucial processes such as donor sorption, bio-fouling and biomass death.more » Our software implementation handles heterogeneous flow fields, arbitrarily many chemical species and amendment injection points, and features full coupling between flow and reactive transport. We describe installation and usage and present two example simulations demonstrating its unique capabilities. One simulation suggests an unorthodox approach to remediation of Cr(VI) contamination.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2006EnGeo..50..219H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2006EnGeo..50..219H">Concentrations and speciation of arsenic along a groundwater flow-path in the Upper Floridan aquifer, Florida, USA</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Haque, S. E.; Johannesson, K. H. 2006-05-01 Arsenic (As) concentrations and speciation were determined in groundwaters along a flow-path in the Upper Floridan aquifer (UFA) to investigate the biogeochemical “evolution“ of As in this relatively pristine aquifer. Dissolved inorganic As species were separated in the field using anion-exchange chromatography and subsequently analyzed by inductively coupled plasma mass spectrometry. Total As concentrations are higher in the recharge area groundwaters compared to down-gradient portions of UFA. Redox conditions vary from relatively oxic to anoxic along the flow-path. Mobilization of As species in UFA groundwaters is influenced by ferric iron reduction and subsequent dissolution, sulfate reduction, and probable pyrite precipitation that are inferred from the data to occur along distinct regions of the flow-path. In general, the distribution of As species are consistent with equilibrium thermodynamics, such that arsenate dominates in more oxidizing waters near the recharge area, and arsenite predominates in the progressively reducing groundwaters beyond the recharge area. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSMM41A..06V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSMM41A..06V">Using metagenomic and metatranscriptomic observations to test a thermodynamic-based model of community metabolic expression over time and space</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Vallino, J. J.; Huber, J. A. 2016-02-01 Marine biogeochemistry is orchestrated by a complex and dynamic community of microorganisms that attempt to maximize their own fecundity through a combination of competition and cooperation. At a systems level, the community can be described as a distributed metabolic network, where different species contribute their own unique set of metabolic capabilities. Our current project attempts to understand the governing principles that describe amplification or attenuation of metabolic pathways within the network through a combination of modeling and metagenomic, metatranscriptomic and biogeochemical observations. We will describe and present results from our thermodynamic-based model that determines optimal pathway expression from available resources based on the principle of maximum entropy production (MEP); that is, based on the hypothesis that non-equilibrium systems organize to maximize energy dissipation. The MEP model currently predicts metabolic pathway expression over time, and one spatial dimension. Model predictions will be compared to biogeochemical observations and gene presence and expression from samples collected over time and space from a costal meromictic basin (Siders Pond) located in Falmouth MA, US. Siders Pond permanent stratification, caused by occasional seawater intrusion, results in steep chemoclines and redox gradients, which supports both aerobic and anaerobic phototrophs as well as sulfur, Fe and Mn redox cycles. The diversity of metabolic capability and expression we have observed over depth makes it an ideal system to test our thermodynamic-based model. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_14");'>14</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li class="active">16</li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_17" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li class="active">17</li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="321"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS51A2022M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS51A2022M">LiveOcean: A Daily Forecast Model of Ocean Acidification for Shellfish Growers</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> MacCready, P.; Siedlecki, S. A.; McCabe, R. M. 2016-12-01 The coastal estuaries of the NE Pacific host a highly productive shellfish industry, but in the past decade they have suffered from many years in which no natural set of oysters occurred. It appears that coastal waters with low Aragonite saturation state may be the cause. This "acidified" water is the result of (i) upwelling of NE Pacific water from near the shelf break that is already low in pH, and (ii) further acidification of that water by productivity and remineralization on the shelf, and (iii) increasing atmospheric CO2. As part of a coordinated research response to this issue, we have developed the LiveOcean modeling system, which creates daily three-day forecasts of circulation and biogeochemical properties in Oregon-Washington-British Columbia coastal and estuarine waters. The system includes realistic tides, atmospheric forcing (from a regional WRF model), ocean boundary conditions (from HYCOM), and rivers (from USGS and Environment Canada). The model is also used for Harmful Algal Bloom prediction. There has been extensive validation of hindcast runs for currents and hydrography, and more limited validation of biogeochemical variables. Model results are pushed daily to the cloud, and made available to the public through the NANOOS Visualization System (NVS). NVS also includes automated model-data comparisons with real-time NDBC and OOI moorings. Future work will focus on optimizing the utility of this system for regional shellfish growers. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AGUFM.H42F..05Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AGUFM.H42F..05Y">Quantification of effective plant rooting depth: advancing global hydrological modelling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yang, Y.; Donohue, R. J.; McVicar, T. 2017-12-01 Plant rooting depth (Zr) is a key parameter in hydrological and biogeochemical models, yet the global spatial distribution of Zr is largely unknown due to the difficulties in its direct measurement. Moreover, Zr observations are usually only representative of a single plant or several plants, which can differ greatly from the effective Zr over a modelling unit (e.g., catchment or grid-box). Here, we provide a global parameterization of an analytical Zr model that balances the marginal carbon cost and benefit of deeper roots, and produce a climatological (i.e., 1982-2010 average) global Zr map. To test the Zr estimates, we apply the estimated Zr in a highly transparent hydrological model (i.e., the Budyko-Choudhury-Porporato (BCP) model) to estimate mean annual actual evapotranspiration (E) across the globe. We then compare the estimated E with both water balance-based E observations at 32 major catchments and satellite grid-box retrievals across the globe. Our results show that the BCP model, when implemented with Zr estimated herein, optimally reproduced the spatial pattern of E at both scales and provides improved model outputs when compared to BCP model results from two already existing global Zr datasets. These results suggest that our Zr estimates can be effectively used in state-of-the-art hydrological models, and potentially biogeochemical models, where the determination of Zr currently largely relies on biome type-based look-up tables. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1454927-ecohydrological-modeling-agroecosystems-examples-challenges','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1454927-ecohydrological-modeling-agroecosystems-examples-challenges">Ecohydrological modeling in agroecosystems: Examples and challenges</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Porporato, A.; Feng, X.; Manzoni, S.; ... 2015-06-01 We report that human societies are increasingly altering the water and biogeochemical cycles to both improve ecosystem productivity and reduce risks associated with the unpredictable variability of climatic drivers. These alterations, however, often cause large negative environmental consequences, raising the question as to how societies can ensure a sustainable use of natural resources for the future. Here we discuss how ecohydrological modeling may address these broad questions with special attention to agroecosystems. The challenges related to modeling the two-way interaction between society and environment are illustrated by means of a dynamical model in which soil and water quality supports themore » growth of human society but is also degraded by excessive pressure, leading to critical transitions and sustained societal growth-collapse cycles. We then focus on the coupled dynamics of soil water and solutes (nutrients or contaminants), emphasizing the modeling challenges, presented by the strong nonlinearities in the soil and plant system and the unpredictable hydroclimatic forcing, that need to be overcome to quantitatively analyze problems of soil water sustainability in both natural and agricultural ecosystems. Finally, we discuss applications of this framework to problems of irrigation, soil salinization, and fertilization and emphasize how optimal solutions for large-scale, long-term planning of soil and water resources in agroecosystems under uncertainty could be provided by methods from stochastic control, informed by physically and mathematically sound descriptions of ecohydrological and biogeochemical interactions.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017BGeo...14.1445N','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017BGeo...14.1445N">Viable cold-tolerant iron-reducing microorganisms in geographically diverse subglacial environments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Nixon, Sophie L.; Telling, Jon P.; Wadham, Jemma L.; Cockell, Charles S. 2017-03-01 Subglacial environments are known to harbour metabolically diverse microbial communities. These microbial communities drive chemical weathering of underlying bedrock and influence the geochemistry of glacial meltwater. Despite its importance in weathering reactions, the microbial cycling of iron in subglacial environments, in particular the role of microbial iron reduction, is poorly understood. In this study we address the prevalence of viable iron-reducing microorganisms in subglacial sediments from five geographically isolated glaciers. Iron-reducing enrichment cultures were established with sediment from beneath Engabreen (Norway), Finsterwalderbreen (Svalbard), Leverett and Russell glaciers (Greenland), and Lower Wright Glacier (Antarctica). Rates of iron reduction were higher at 4 °C compared with 15 °C in all but one duplicated second-generation enrichment culture, indicative of cold-tolerant and perhaps cold-adapted iron reducers. Analysis of bacterial 16S rRNA genes indicates Desulfosporosinus were the dominant iron-reducing microorganisms in low-temperature Engabreen, Finsterwalderbreen and Lower Wright Glacier enrichments, and Geobacter dominated in Russell and Leverett enrichments. Results from this study suggest microbial iron reduction is widespread in subglacial environments and may have important implications for global biogeochemical iron cycling and export to marine ecosystems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28499584','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28499584">Extremely high sulfate reduction, sediment oxygen demand and benthic nutrient flux associated with a large-scale artificial dyke and its implication to benthic-pelagic coupling in the Yeongsan River estuary, Yellow Sea.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kim, Sung-Han; Lee, Jae Seong; Hyun, Jung-Ho 2017-07-15 We investigated environmental impact of large-scale dyke on the sediment geochemistry, sulfate reduction rates (SRRs), sediment oxygen demand (SOD) and potential contribution of benthic nutrient flux (BNF) to primary production in the Yeongsan River estuary, Yellow Sea. The sediment near the dyke (YE1) with high organic carbon (C org ) content (>4%, dry wt.) was characterized by extremely high SOD (327mmolm -2 d -1 ) and SRRs (91-140mmolm -2 d -1 ). The sulfate reduction accounted for 73% of C org oxidation, and was responsible for strikingly high concentrations of NH 4 + (7.7mM), PO 4 3- (67μM) and HS - (487μM) in pore water. The BNF at YE1 accounted for approximately 200% of N and P required for primary production in the water column. The results present one of the most extreme cases that the construction of an artificial dyke may have profound impacts on the biogeochemical and ecological processes in coastal ecosystems. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1332078-biogeochemical-processes-regulating-mobility-uranium-sediments','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1332078-biogeochemical-processes-regulating-mobility-uranium-sediments">Biogeochemical Processes Regulating the Mobility of Uranium in Sediments</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Belli, Keaton M.; Taillefert, Martial This book chapters reviews the latest knowledge on the biogeochemical processes regulating the mobility of uranium in sediments. It contains both data from the literature and new data from the authors. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1409001','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1409001">Structural Mass Saving Potential of a 5-MW Direct-Drive Generator Designed for Additive Manufacturing</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Sethuraman, Latha; Fingersh, Lee J; Dykes, Katherine L As wind turbine blade diameters and tower height increase to capture more energy in the wind, higher structural loads results in more structural support material increasing the cost of scaling. Weight reductions in the generator transfer to overall cost savings of the system. Additive manufacturing facilitates a design-for-functionality approach, thereby removing traditional manufacturing constraints and labor costs. The most feasible additive manufacturing technology identified for large, direct-drive generators in this study is powder-binder jetting of a sand cast mold. A parametric finite element analysis optimization study is performed, optimizing for mass and deformation. Also, topology optimization is employed for eachmore » parameter-optimized design.The optimized U-beam spoked web design results in a 24 percent reduction in structural mass of the rotor and 60 percent reduction in radial deflection.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B53F0571R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B53F0571R">Assessing the Impact of Model Parameter Uncertainty in Simulating Grass Biomass Using a Hybrid Carbon Allocation Strategy</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Reyes, J. J.; Adam, J. C.; Tague, C. 2016-12-01 Grasslands play an important role in agricultural production as forage for livestock; they also provide a diverse set of ecosystem services including soil carbon (C) storage. The partitioning of C between above and belowground plant compartments (i.e. allocation) is influenced by both plant characteristics and environmental conditions. The objectives of this study are to 1) develop and evaluate a hybrid C allocation strategy suitable for grasslands, and 2) apply this strategy to examine the importance of various parameters related to biogeochemical cycling, photosynthesis, allocation, and soil water drainage on above and belowground biomass. We include allocation as an important process in quantifying the model parameter uncertainty, which identifies the most influential parameters and what processes may require further refinement. For this, we use the Regional Hydro-ecologic Simulation System, a mechanistic model that simulates coupled water and biogeochemical processes. A Latin hypercube sampling scheme was used to develop parameter sets for calibration and evaluation of allocation strategies, as well as parameter uncertainty analysis. We developed the hybrid allocation strategy to integrate both growth-based and resource-limited allocation mechanisms. When evaluating the new strategy simultaneously for above and belowground biomass, it produced a larger number of less biased parameter sets: 16% more compared to resource-limited and 9% more compared to growth-based. This also demonstrates its flexible application across diverse plant types and environmental conditions. We found that higher parameter importance corresponded to sub- or supra-optimal resource availability (i.e. water, nutrients) and temperature ranges (i.e. too hot or cold). For example, photosynthesis-related parameters were more important at sites warmer than the theoretical optimal growth temperature. Therefore, larger values of parameter importance indicate greater relative sensitivity in adequately representing the relevant process to capture limiting resources or manage atypical environmental conditions. These results may inform future experimental work by focusing efforts on quantifying specific parameters under various environmental conditions or across diverse plant functional types. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20000044868&hterms=design&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DTitle%26N%3D0%26No%3D70%26Ntt%3Ddesign','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20000044868&hterms=design&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DTitle%26N%3D0%26No%3D70%26Ntt%3Ddesign">Supersonic Aerodynamic Design Improvements of an Arrow-Wing HSCT Configuration Using Nonlinear Point Design Methods</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Unger, Eric R.; Hager, James O.; Agrawal, Shreekant 1999-01-01 This paper is a discussion of the supersonic nonlinear point design optimization efforts at McDonnell Douglas Aerospace under the High-Speed Research (HSR) program. The baseline for these optimization efforts has been the M2.4-7A configuration which represents an arrow-wing technology for the High-Speed Civil Transport (HSCT). Optimization work on this configuration began in early 1994 and continued into 1996. Initial work focused on optimization of the wing camber and twist on a wing/body configuration and reductions of 3.5 drag counts (Euler) were realized. The next phase of the optimization effort included fuselage camber along with the wing and a drag reduction of 5.0 counts was achieved. Including the effects of the nacelles and diverters into the optimization problem became the next focus where a reduction of 6.6 counts (Euler W/B/N/D) was eventually realized. The final two phases of the effort included a large set of constraints designed to make the final optimized configuration more realistic and they were successful albeit with a loss of performance. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19870017694','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19870017694">Enhanced viscous flow drag reduction using acoustic excitation</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Nagel, Robert T. 1987-01-01 Proper acoustic excitation of a single large-eddy break-up device can increase the resulting drag reduction and, after approximately 40 to 50 delta downstream, provide net drag reduction. Precise optimization of the input time delay, amplitude and response threshold is difficult but possible to achieve. Drag reduction is improved with optimized conditions. The possibility of optimized processing strongly suggests a mechanism which involves interaction of the acoustic waves and large eddies at the trailing edge of the large eddy break-up device. Although the mechanism for spreading of this phenomenon is unknown, it is apparent that the drag reduction effect does tend to spread spanwise as the flow convects downstream. The phenomenon is not unique to a particular blade configuration or flow velocity, although all data have been obtained at relatively low Reynolds numbers. The general repeatibility of the results for small configuration changes serves as verification of the phenomenon. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009WRR....45.6406M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009WRR....45.6406M">Development of a multiobjective optimization tool for the selection and placement of best management practices for nonpoint source pollution control</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Maringanti, Chetan; Chaubey, Indrajeet; Popp, Jennie 2009-06-01 Best management practices (BMPs) are effective in reducing the transport of agricultural nonpoint source pollutants to receiving water bodies. However, selection of BMPs for placement in a watershed requires optimization of the available resources to obtain maximum possible pollution reduction. In this study, an optimization methodology is developed to select and place BMPs in a watershed to provide solutions that are both economically and ecologically effective. This novel approach develops and utilizes a BMP tool, a database that stores the pollution reduction and cost information of different BMPs under consideration. The BMP tool replaces the dynamic linkage of the distributed parameter watershed model during optimization and therefore reduces the computation time considerably. Total pollutant load from the watershed, and net cost increase from the baseline, were the two objective functions minimized during the optimization process. The optimization model, consisting of a multiobjective genetic algorithm (NSGA-II) in combination with a watershed simulation tool (Soil Water and Assessment Tool (SWAT)), was developed and tested for nonpoint source pollution control in the L'Anguille River watershed located in eastern Arkansas. The optimized solutions provided a trade-off between the two objective functions for sediment, phosphorus, and nitrogen reduction. The results indicated that buffer strips were very effective in controlling the nonpoint source pollutants from leaving the croplands. The optimized BMP plans resulted in potential reductions of 33%, 32%, and 13% in sediment, phosphorus, and nitrogen loads, respectively, from the watershed. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1710388C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1710388C">An Earth system view on boundaries for human perturbation of the N and P cycles</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cornell, Sarah; de Vries, Wim 2015-04-01 The appropriation and transformation of land, water, and living resources can alter Earth system functioning, and potentially undermine the basis for the sustainability of our societies. Human activities have greatly increased the flows of reactive forms of nitrogen (N) and phosphorus (P) in the Earth system. These non-substitutable nutrient elements play a fundamental role in the human food system. Furthermore, the current mode of social and economic globalization, and its effect on the present-day energy system, also has large effects including large NOx-N emissions through combustion. Until now, this perturbation of N and P cycles has been treated largely as a local/regional issue, and managed in terms of direct impacts (water, land or air pollution). However, anthropogenic N and P cycle changes affect physical Earth system feedbacks (through greenhouse gas and aerosol changes) and biogeochemical feedbacks (via ecosystem changes, links to the carbon cycle, and altered nutrient limitation) with impacts that can be far removed from the direct sources. While some form of N and P management at the global level seems likely to be needed for continued societal development, the current local-level and sectorial management is often problematically simplistic, as seen in the tensions between divergent N management needs for climate change mitigation, air pollution control, food production, and ecosystem conservation. We require a step change in understanding complex biogeochemical, physical and socio-economic interactions in order to analyse these effects together, and inform policy trade-offs to minimize emergent systemic risks. Planetary boundaries for N and P cycle perturbation have recently been proposed. We discuss the current status of these precautionary boundaries and how we may improve on these preliminary assessments. We present an overview of the human perturbation of the global biogeochemical cycles of N and P and its interaction with the functioning of the Earth system. There are various N and P impacts, which vary in space and time and are associated with multiple human drivers. There are multiple possible constraints that need to be considered; for P there is an issue with absolute availability, but not for N. The societal benefits (e.g. food production) and environmental impacts (e.g. eutrophication) are linked through stoichiometry, which differs in terrestrial and aquatic systems, presenting challenges for any global optimization approach. By setting out these features, we can better assess how to apply and improve our current analytic frameworks, models, and data for safer navigation of the biogeochemical complexities of global sustainability. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1455286-iodate-reduction-shewanella-oneidensis-does-involve-nitrate-reductase','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1455286-iodate-reduction-shewanella-oneidensis-does-involve-nitrate-reductase">Iodate Reduction by Shewanella oneidensis Does Not Involve Nitrate Reductase</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Mok, Jung Kee; Toporek, Yael J.; Shin, Hyun-Dong Microbial iodate (IO 3 -) reduction is a major component of the iodine biogeochemical reaction network and is the basis of alternative strategies for remediation of iodine-contaminated environments. The molecular mechanism of microbial IO 3 - reduction, however, is not well understood. In microorganisms displaying IO 3 - and nitrate (NO 3 -) reduction activities, NO 3 - reductase is postulated to reduce IO 3 - as alternate electron acceptor. In the present study, whole genome analyses of 25 NO 3 --reducing Shewanella strains identified various combinations of genes encoding one assimilatory (cytoplasmic Nas) and three dissimilatory (membrane-associated Nar andmore » periplasmic Napα and Napβ) NO 3 - reductases. S. oneidensis was the only Shewanella strain whose genome encoded a single NO 3 - reductase (Napβ). Terminal electron acceptor competition experiments in S. oneidensis batch cultures amended with both NO 3 - and IO 3 - demonstrated that neither NO 3 - nor IO 3 - reduction activities were competitively inhibited by the presence of the competing electron acceptor. The lack of involvement of S. oneidensis Napβ in IO 3 - reduction was confirmed via phenotypic analysis of an in-frame gene deletion mutant lacking napβΑ (encoding the NO 3 --reducing NapβA catalytic subunit). S. oneidensis ΔnapβA was unable to reduce NO 3 -, yet reduced IO 3 - at rates higher than the wild-type strain. Thus, NapβA is required for dissimilatory NO 3 - reduction by S. oneidensis, while neither the assimilatory (Nas) nor dissimilatory (Napα, Napβ, and Nar) NO 3 - reductases are required for IO 3 - reduction. These findings oppose the traditional view that NO 3 - reductase reduces IO 3 - as alternate electron acceptor and indicate that S. oneidensis reduces IO 3 - via an as yet undiscovered enzymatic mechanism.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1171894-metabolic-interdependencies-between-phylogenetically-novel-fermenters-respiratory-organisms-unconfined-aquifer','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1171894-metabolic-interdependencies-between-phylogenetically-novel-fermenters-respiratory-organisms-unconfined-aquifer"></a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Wrighton, Kelly C.; Castelle, Cindy; Wilkins, Michael J. Fermentation-based metabolism is an important ecosystem function often associated with environments rich in organic carbon, such as wetlands, sewage sludge, and the mammalian gut. The diversity of microorganisms and pathways involved in carbon and hydrogen cycling in sediments and aquifers and the impacts of these processes on other biogeochemical cycles remain poorly understood. Here we used metagenomics and proteomics to characterize microbial communities sampled from an aquifer adjacent to the Colorado River at Rifle, Colorado, USA, and document interlinked microbial roles in geochemical cycling. The organic carbon content in the aquifer was elevated via two acetate-based biostimulation treatments. Samples weremore » collected at three time points, with the objective of extensive genome recovery to enable metabolic reconstruction of the community. Fermentative community members include genomes from a new phylum (ACD20), phylogenetically novel members of the Chloroflexi and Bacteroidetes, as well as candidate phyla genomes (OD1, BD1-5, SR1, WWE3, ACD58, TM6, PER, and OP11). These organisms have the capacity to produce hydrogen, acetate, formate, ethanol, butyrate, and lactate, activities supported by proteomic data. The diversity and expression of hydrogenases suggests the importance of hydrogen currency in the subsurface. Our proteogenomic data further indicate the consumption of fermentation intermediates by Proteobacteria can be coupled to nitrate, sulfate, and iron reduction. Thus, fermentation carried out by previously unstudied members of sediment microbial communities may be an important driver of diverse subsurface biogeochemical cycles.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSOD11A..08D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSOD11A..08D">Ten Years of Observatory Science from Saanich Inlet on the VENUS Cabled Ocean Observatory</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dewey, R. K.; Tunnicliffe, V.; Macoun, P.; Round, A. 2016-02-01 The Saanich Inlet array of the VENUS cabled ocean observatory, maintained and operated by Ocean Networks Canada, was installed in February 2006, and in 2016 will have supported ten years of comprehensive interactive science. Representing the first in the present generation of cabled observing technologies, this coastal array has provided continuous high power and broadband communications to a variety of instrument platforms, hundreds of sensors, and enabled dozens of short, medium, and long-term studies. Saanich Inlet is a protected fjord with limited tidal action, resulting in an extremely productive environment, with strong seasonal chemical variations driven by episodic deep water renewal events and oxygen reduction processes. The breadth of the research has included microbial and benthic community dynamics, biogeochemical cycles, forensics, quantifying inter-annual variations, benthic-pelagic coupling, sensor testing, plankton dynamics, and bio-turbulence. Observatory measurements include core water properties (CTD & O2) and water-column echo-sounder records, as well as experiment-oriented deployments utilizing cameras, Gliders, Dopplers, hydrophones, and a variety of biogeochemical sensors. With a recently installed Buoy Profiler System for monitoring the entire water column, community plans continue with a dedicated Redox experiment through the 2016-17 seasons. Highlights from the dozens of research papers and theses will be presented to demonstrate the achievements enabled by a comprehensive coastal cabled observing system. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24914800','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24914800">Genomic insights into the uncultured genus 'Candidatus Magnetobacterium' in the phylum Nitrospirae.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Lin, Wei; Deng, Aihua; Wang, Zhang; Li, Ying; Wen, Tingyi; Wu, Long-Fei; Wu, Martin; Pan, Yongxin 2014-12-01 Magnetotactic bacteria (MTB) of the genus 'Candidatus Magnetobacterium' in phylum Nitrospirae are of great interest because of the formation of hundreds of bullet-shaped magnetite magnetosomes in multiple bundles of chains per cell. These bacteria are worldwide distributed in aquatic environments and have important roles in the biogeochemical cycles of iron and sulfur. However, except for a few short genomic fragments, no genome data are available for this ecologically important genus, and little is known about their metabolic capacity owing to the lack of pure cultures. Here we report the first draft genome sequence of 3.42 Mb from an uncultivated strain tentatively named 'Ca. Magnetobacterium casensis' isolated from Lake Miyun, China. The genome sequence indicates an autotrophic lifestyle using the Wood-Ljungdahl pathway for CO2 fixation, which has not been described in any previously known MTB or Nitrospirae organisms. Pathways involved in the denitrification, sulfur oxidation and sulfate reduction have been predicted, indicating its considerable capacity for adaptation to variable geochemical conditions and roles in local biogeochemical cycles. Moreover, we have identified a complete magnetosome gene island containing mam, mad and a set of novel genes (named as man genes) putatively responsible for the formation of bullet-shaped magnetite magnetosomes and the arrangement of multiple magnetosome chains. This first comprehensive genomic analysis sheds light on the physiology, ecology and biomineralization of the poorly understood 'Ca. Magnetobacterium' genus. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.H13C1546K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.H13C1546K">Modeling the fate of nitrogen on the catchment scale using a spatially explicit hydro-biogeochemical simulation system</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Klatt, S.; Butterbach-Bahl, K.; Kiese, R.; Haas, E.; Kraus, D.; Molina-Herrera, S. W.; Kraft, P. 2015-12-01 The continuous growth of the human population demands an equally growing supply for fresh water and food. As a result, available land for efficient agriculture is constantly diminishing which forces farmers to cultivate inferior croplands and intensify agricultural practices, e.g., increase the use of synthetic fertilizers. This intensification of marginal areas in particular will cause a dangerous rise in nitrate discharge into open waters or even drinking water resources. In order to reduce the amount of nitrate lost by surface runoff or lateral subsurface transport, bufferstrips have proved to be a valuable means. Current laws, however, promote rather static designs (i.e., width and usage) even though a multitude of factors, e.g., soil type, slope, vegetation and the nearby agricultural management, determines its effectiveness. We propose a spatially explicit modeling approach enabling to assess the effects of those factors on nitrate discharge from arable lands using the fully distributed hydrology model CMF coupled to the complex biogeochemical model LandscapeDNDC. Such a modeling scheme allows to observe the displacement of dissolved nutrients in both vertical and horizontal directions and serves to estimate both their uptake by the vegetated bufferstrip and loss to the environment. First results indicate a significant reduction of nitrate loss in the presence of a bufferstrip (2.5 m). We show effects induced by various buffer strip widths and plant cover on the nitrate retention. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19880064715&hterms=Functions+helicopter&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3DFunctions%2Bhelicopter','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19880064715&hterms=Functions+helicopter&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3DFunctions%2Bhelicopter">Optimization of helicopter airframe structures for vibration reduction considerations, formulations and applications</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Murthy, T. Sreekanta 1988-01-01 Several key issues involved in the application of formal optimization technique to helicopter airframe structures for vibration reduction are addressed. Considerations which are important in the optimization of real airframe structures are discussed. Considerations necessary to establish relevant set of design variables, constraints and objectives which are appropriate to conceptual, preliminary, detailed design, ground and flight test phases of airframe design are discussed. A methodology is suggested for optimization of airframes in various phases of design. Optimization formulations that are unique to helicopter airframes are described and expressions for vibration related functions are derived. Using a recently developed computer code, the optimization of a Bell AH-1G helicopter airframe is demonstrated. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018E%26ES..108d2036Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018E%26ES..108d2036Y">A Review of Industrial Heat Exchange Optimization</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yao, Junjie 2018-01-01 Heat exchanger is an energy exchange equipment, it transfers the heat from a working medium to another working medium, which has been wildly used in petrochemical industry, HVAC refrigeration, aerospace and so many other fields. The optimal design and efficient operation of the heat exchanger and heat transfer network are of great significance to the process industry to realize energy conservation, production cost reduction and energy consumption reduction. In this paper, the optimization of heat exchanger, optimal algorithm and heat exchanger optimization with different objective functions are discussed. Then, optimization of the heat exchanger and the heat exchanger network considering different conditions are compared and analysed. Finally, all the problems discussed are summarized and foresights are proposed. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://sofia.usgs.gov/publications/ofr/97-454/','USGSPUBS'); return false;" href="http://sofia.usgs.gov/publications/ofr/97-454/">Geochemistry of surface and pore water at USGS coring sites in wetlands of South Florida, 1994 and 1995</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Orem, William H.; Lerch, Harry E.; Rawlik, Peter 2002-01-01 In this report, we present preliminary data on surface and pore water geochemistry from 22 sites in south Florida sampled during 1994 and 1995. These results are part of a larger study designed to evaluate the role of biogeochemical processes in sediments in the cycling of carbon, nitrogen, phosphorus, and sulfur in the south Florida ecosystem. The data are briefly discussed in regard to regional trends in the concentrations of chemical species, and general diagenetic processes in sediments. These results are part of a larger study designed to evaluate the role of biogeochemical processes in sediments in the cycling of carbon, nitrogen, phosphorus, and sulfur in the south Florida ecosystem. These elements play a crucial role in regulating organic sedimentation, nutrient dynamics, redox conditions, and the biogeochemistry of mercury in the threatened wetlands of south Florida. Pore water samples for chemical analyis were obtained using a piston corer/squeezer designed to avoid compression of the sediment and avoid oxidation and contamination of the pore water samples. Results show distinct regional trends in both surface water and pore water geochemistry. Most chemical species in surface and pore water show peak concentrations in Water Conservation Area 2A, with diminishing concentrations to the south and west into Water Conservation Area 3A, and Everglades National Park. The largest differences observed were for phosphate and sulfide, with concentrations in pore waters in Water Conservation Area 2A up to 500x higher than concentrations observed in freshwater marsh areas of Water Conservation Area 3A and Everglades National Park. Sites near the Hillsboro Canal in Water Conservation Area 2A are heavily contaminated with both phosphorus and sulfur. Pore water profiles for dissolved reactive phosphate suggest that recycling of phosphorus at these contaminated sites occurs primarily in the upper 20 cm of sediment. High levels of sulfide in pore water in Water Conservation Area 2A may inhibit mercury methylation here. At sites in Water Conservation Area 3A south of Alligator Alley, sulfide levels are much lower and sulfate reduction in the sediments here may be conducive to methyl mercury formation. Concentration versus depth profiles of biogeochemically important chemical species in pore water at most sites are smoth curves amenable to modelling using standard diagenetic equations. This should allow prediction of rates of biogeochemical processes in these sediments for incorporation in ecosystem models. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_15");'>15</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li class="active">17</li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_18" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li class="active">18</li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="341"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/20640024-reduction-theorems-optimal-unambiguous-state-discrimination-density-matrices','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/20640024-reduction-theorems-optimal-unambiguous-state-discrimination-density-matrices">Reduction theorems for optimal unambiguous state discrimination of density matrices</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Raynal, Philippe; Luetkenhaus, Norbert; Enk, Steven J. van 2003-08-01 We present reduction theorems for the problem of optimal unambiguous state discrimination of two general density matrices. We show that this problem can be reduced to that of two density matrices that have the same rank n and are described in a Hilbert space of dimensions 2n. We also show how to use the reduction theorems to discriminate unambiguously between N mixed states (N{>=}2) </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017JPhCS.908a2051A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017JPhCS.908a2051A">Design optimization of rear uprights for UniMAP Automotive Racing Team Formula SAE racing car</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Azmeer, M.; Basha, M. H.; Hamid, M. F.; Rahman, M. T. A.; Hashim, M. S. M. 2017-10-01 In an automobile, the rear upright are used to provide a physical mounting and links the suspension arms to the hub and wheel assembly. In this work, static structural and shape optimization analysis for rear upright for UniMAP’s Formula SAE racing car had been done using ANSYS software with the objective to reduce weight while maintaining the structural strength of the vehicle upright. During the shape optimization process, the component undergoes 25%, 50% and 75 % weight reduction in order to find the best optimal shape of the upright. The final design of the upright is developed considering the weight reduction, structural integrity and the manufacturability. The final design achieved 21 % weight reduction and is able to withstand several loads. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.H23I..02B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.H23I..02B">Progress in understanding uranium(IV) speciation and dynamics in biologically reduced sediments: Research at molecular to centimeter scales by the SLAC SFA program</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bargar, J.; Williams, K. H.; Campbell, K. M.; Stubbs, J. E.; Suvorova, E.; Lezama-Pacheco, J. S.; Alessi, D.; Stylo, M.; Handley, K. M.; Bernier-Latmani, R.; Cerrato, J.; Davis, J. A.; Fox, P. M.; Giammar, D.; Long, P. E. 2011-12-01 The chemical and physical forms of U(IV) in reduced sediments, as well as the biogeochemical processes by which they form and transform, profoundly influence the stability of reduced U(IV) species and the behavior of uranium in biostimulated aquifers. Obtaining such information in field sediments is important because biogeochemical field conditions and their time dependence are difficult to replicate in the laboratory. The majority of contaminated aquifers in which bioremediation is of potential interest, including the Old Rifle, CO IFRC site, exhibit relatively low uranium sediment concentrations, i.e., < 10 ppm, presenting a formidable challenge to the use of spectroscopy and microscopy techniques that typically require 10-fold or higher uranium loadings. We have developed an in-situ column technique to study U(IV) species and evolving microbial communities in the Old Rifle aquifer and to correlate them with changes in trace and major ion groundwater composition during biostimulation treatments. Sediments were examined using x-ray and electron microscopy, x-ray absorption spectroscopy (XAS), and chemical extractions. XAS analysis showed that U(IV) occurred predominantly or exclusively as monomeric U(IV) complexes coordinated to oxo (or similar N/C) neighbors, and is associated with biomass or Fe sulfides. Even in the latter case, U(IV) was not coordinated directly to S neighbors. Sediment-hosted monomeric U(IV) complexes were found to partially transform into uraninite in the aquifer over a subsequent 12 month period. This work establishes the importance of monomeric U(IV) complexes in subsurface sediments at the Old Rifle site and provides a conceptual framework in which previously observed U(IV) reduction products can be related. These experiments also establish that U(IV) species are dynamic in aquifers and can undergo non-oxidative transformation reactions. These new results have important implications for uranium reactive transport models, long-term assessment of remediation technologies, and understanding natural uranium reduction in aquifers. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22204939','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22204939">Impact of sulfate pollution on anaerobic biogeochemical cycles in a wetland sediment.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Baldwin, Darren S; Mitchell, Alison 2012-03-15 The impact of sulfate pollution is increasingly being seen as an issue in the management of inland aquatic ecosystems. In this study we use sediment slurry experiments to explore the addition of sulfate, with or without added carbon, on the anaerobic biogeochemical cycles in a wetland sediment that previously had not been exposed to high levels of sulfate. Specifically we looked at the cycling of S (sulfate, dissolved and particulate sulfide--the latter measured as acid volatile sulfide; AVS), C (carbon dioxide, bicarbonate, methane and the short chain volatile fatty acids formate, acetate, butyrate and propionate), N (dinitrogen, ammonium, nitrate and nitrite) and redox active metals (Fe(II) and Mn(II)). Sulfate had the largest effects on the cycling of S and C. All the added S at lower loadings were converted to AVS over the course of the experiment (30 days). At the highest loading (8 mmol) less than 50% of consumed S was converted to AVS, however this is believed to be a kinetic effect. Although sulfate reduction was occurring in sediments with added sulfate, dissolved sulfide concentrations remained low throughout the study. Sulfate addition affected methanogenesis. In the absence of added carbon, addition of sulfate, even at a loading of 1 mmol, resulted in a halving of methane formation. The initial rate of formation of methane was not affected by sulfate if additional carbon was added to the sediment. However, there was evidence for anaerobic methane oxidation in those sediments with added sulfate and carbon, but not in those sediments treated only with carbon. Surprisingly, sulfate addition had little apparent impact on N dynamics; previous studies have shown that sulfide can inhibit denitrification and stimulate dissimilatory nitrate reduction to ammonia. We propose that because most of the reduced sulfur was in particulate form, levels of dissolved sulfide were too low to interfere with the N cycle. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B24A..07G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B24A..07G">High-resolution (SIMS) versus bulk sulfur isotope patterns of pyrite in Proterozoic microbialites with diverse mat textures</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gomes, M. L.; Fike, D. A.; Bergmann, K.; Knoll, A. H. 2015-12-01 Sulfur (S) isotope signatures of sedimentary pyrite preserved in marine rocks provide a rich suite of information about changes in biogeochemical cycling associated with the evolution of microbial metabolisms and oxygenation of Earth surface environments. Conventionally, these S isotope records are based on bulk rock measurements. Yet, in modern microbial mat environments, S isotope compositions of sulfide can vary by up to 40‰ over a spatial range of ~ 1 mm. Similar ranges of S isotope variability have been found in Archean pyrite grains using both Secondary Ion Mass Spectrometry and other micro-analytical techniques. These micron-scale patterns have been linked to changes in rates of microbial sulfate reduction and/or sulfide oxidation, isotopic distillation of the sulfate reservoir due to microbial sulfate reduction, and post-depositional alteration. Fine-scale mapping of S isotope compositions of pyrite can thus be used to differentiate primary environmental signals from post-depositional overprinting - improving our understanding of both. Here, we examine micron-scale S isotope patterns of pyrite in microbialites from the Mesoproterozoic-Neoproterozoic Sukhaya Tunguska Formation and Neoproterozoic Draken Formation in order to explore S isotope variability associated with different mat textures and pyrite grain morphologies. A primary goal is to link modern observations of how sulfide spatial isotope distributions reflect active microbial communities present at given depths in the mats to ancient processes driving fine-sale pyrite variability in microbialites. We find large (up to 60‰) S isotope variability within a spatial range of less than 2.5cm. The micron-scale S isotope measurements converge around the S isotope composition of pyrite extracted from bulk samples of the same microbialites. These micron-scale pyrite S isotope patterns have the potential to reveal important information about ancient biogeochemical cycling in Proterozoic mat environments with implications for interpreting S isotope signatures from the geological record. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.H42G..07S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.H42G..07S">Hydrologically Controlled Arsenic Release in Deltaic Wetlands and Coastal Riparian Zones</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Stuckey, J.; LeMonte, J. J.; Yu, X.; Schaefer, M.; Kocar, B. D.; Benner, S. G.; Rinklebe, J.; Tappero, R.; Michael, H. A.; Fendorf, S. E.; Sparks, D. L. 2016-12-01 Wetland and riparian zone hydrology exerts critical controls on the biogeochemical cycling of metal contaminants including arsenic. The role of wetlands in driving geogenic arsenic release to groundwater has been debated in the deltas of South and Southeast Asia where the largest impacted human population resides. In addition, groundwater in coastal areas worldwide, such as those in South and Southeast Asia and the Mid-Atlantic of the U.S., is at risk to largely unexplored biogeochemical and hydrologic impacts of projected sea level rise. First, we present data from fresh-sediment incubations, in situ model sediment incubations and a controlled field experiment with manipulated wetland hydrology and organic carbon inputs in the minimally disturbed upper Mekong Delta. Here we show that arsenic release is limited to near-surface sediments of permanently saturated wetlands where both organic carbon and arsenic-bearing solids are sufficiently reactive for microbial oxidation of organic carbon and reduction of arsenic-bearing iron oxides. In contrast, within the deeper aquifer or seasonally saturated sediments, reductive dissolution of iron oxides is observed only when either more reactive exogenous forms of iron oxides or organic carbon are added, revealing a potential thermodynamic restriction to microbial metabolism. Second, in order to assess the potential impacts of sea level rise on arsenic release to groundwater, we determined the changes in arsenic speciation and partitioning in sediment collected from an anthropogenically contaminated coastal riparian zone under controlled Eh regimes in both seawater and freshwater systems. Here we show greater arsenic release under anoxic/suboxic conditions in the freshwater system than in the seawater system, potentially due to high salinity induced microbial inhibition. Collectively, our work shows that shifting hydrologic conditions in deltaic wetlands and tidally influenced zones impacts the extent of arsenic release to groundwater. Land and water management decisions that increase the duration of wetland inundation may promote arsenic release to groundwater. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.V21B..07I','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.V21B..07I">Micro-Scale Sulfur and Carbon Isotope Analysis of a Neoarchean Stromatolite: Evidence for a Profound Redox Transition in Shelf Margins prior to the Great Oxidation Event</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Ilhardt, P.; House, C. H.; Altermann, W. 2016-12-01 Neoarchean shelf margin environments such as the Campbellrand-Malmani platform are believed to have been sites of substantial O2 accumulation and nutrient cycling prior to the Great Oxidation Event (GOE). Stromatolites in particular serve as biogeochemical "hotspots" where evidence of various metabolic pathways and bacterial lineages can be traced through geochemical fingerprints. We identified morphologically-unique, organic-rimmed pyrite grains embedded in the dolomitic lamina of a Campbellrand Subgroup stromatolite (2.6 Ga). Carbon and sulfur isotopes measured in situ revealed a multi-layered microbial community employing photoautotrophic carbon fixation, organic matter respiration, sulfate reduction, and potentially assimilation of methane. In particular, unusually high kerogen δ13Corg and pyrite δ34S compositions are consistent with a semi-aerobic ecosystem recycling photosynthetic biomass and sulfate reduction in sulfate-limited porewaters, respectively. In addition, an array of positive Δ33S values suggests incorporation of atmospherically-derived sulfur formed from volcanic SO2 photochemistry and isolated in particulate form. We argue the Δ33S-δ34S trend is best explained by mixing between a δ34S-enriched coastal marine sulfate reservoir and stratospheric Δ33S-positive sulfate or elemental sulfur aerosols. The hypothesized buildup of sulfur gases at higher altitudes agrees with prior arguments for increased subaerial felsic volcanism and intense plume activity coinciding with oxidation of the upper mantle. We suggest explosive subaerial eruptions sustained a stratospheric SO2 reservoir that underwent photochemistry via long-wavelength (250-330 nm) UV radiation to produce positive MIF-carrying aerosol particles (sulfate or sulfur) in the Neoarchean. This contrasts with Paleoarchean sulfur chemistry dominated by SO2 photolysis in the 190-220 nm excitation band and points to an evolving Archean atmosphere, culminating in a coupled biogeochemical-tectonic redox transformation that fundamentally changed the atmospheric sulfur cycle and ultimately prompted the GOE. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20090005245&hterms=CDOM&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DCDOM','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20090005245&hterms=CDOM&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D10%26Ntt%3DCDOM">Improving Coastal Ocean Color Validation Capabilities through Application of Inherent Optical Properties (IOPs)</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Mannino, Antonio 2008-01-01 Understanding how the different components of seawater alter the path of incident sunlight through scattering and absorption is essential to using remotely sensed ocean color observations effectively. This is particularly apropos in coastal waters where the different optically significant components (phytoplankton, detrital material, inorganic minerals, etc.) vary widely in concentration, often independently from one another. Inherent Optical Properties (IOPs) form the link between these biogeochemical constituents and the Apparent Optical Properties (AOPs). understanding this interrelationship is at the heart of successfully carrying out inversions of satellite-measured radiance to biogeochemical properties. While sufficient covariation of seawater constituents in case I waters typically allows empirical algorithms connecting AOPs and biogeochemical parameters to behave well, these empirical algorithms normally do not hold for case I1 regimes (Carder et al. 2003). Validation in the context of ocean color remote sensing refers to in-situ measurements used to verify or characterize algorithm products or any assumption used as input to an algorithm. In this project, validation capabilities are considered those measurement capabilities, techniques, methods, models, etc. that allow effective validation. Enhancing current validation capabilities by incorporating state-of-the-art IOP measurements and optical models is the purpose of this work. Involved in this pursuit is improving core IOP measurement capabilities (spectral, angular, spatio-temporal resolutions), improving our understanding of the behavior of analytical AOP-IOP approximations in complex coastal waters, and improving the spatial and temporal resolution of biogeochemical data for validation by applying biogeochemical-IOP inversion models so that these parameters can be computed from real-time IOP sensors with high sampling rates. Research cruises supported by this project provides for collection and processing of seawater samples for biogeochemical (pigments, DOC and POC) and optical (CDOM and POM absorption coefficients) analyses to enhance our understanding of the linkages between in-water optical measurements (IOPs and AOPs) and biogeochemical constituents and to provide a more comprehensive suite of validation products. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21043129','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21043129">[Ammonia-oxidizing archaea and their important roles in nitrogen biogeochemical cycling: a review].</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Liu, Jing-Jing; Wu, Wei-Xiang; Ding, Ying; Shi, De-Zhi; Chen, Ying-Xu 2010-08-01 As the first step of nitrification, ammonia oxidation is the key process in global nitrogen biogeochemical cycling. So far, the autotrophic ammonia-oxidizing bacteria (AOB) in the beta- and gamma-subgroups of proteobacteria have been considered as the most important contributors to ammonia oxidation, but the recent researches indicated that ammonia-oxidizing archaea (AOA) are widely distributed in various kinds of ecosystems and quantitatively predominant, playing important roles in the global nitrogen biogeochemical cycling. This paper reviewed the morphological, physiological, and ecological characteristics and the molecular phylogenies of AOA, and compared and analyzed the differences and similarities of the ammonia monooxygenase (AMO) and its encoding genes between AOA and AOB. In addition, the potential significant roles of AOA in nitrogen biogeochemical cycling in aquatic and terrestrial ecosystems were summarized, and the future research directions of AOA in applied ecology and environmental protection were put forward. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28419976','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28419976">Microbial extracellular enzymes in biogeochemical cycling of ecosystems.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Luo, Ling; Meng, Han; Gu, Ji-Dong 2017-07-15 Extracellular enzymes, primarily produced by microorganisms, affect ecosystem processes because of their essential roles in degradation, transformation and mineralization of organic matter. Extracellular enzymes involved in the cycling of carbon (C), nitrogen (N) and phosphorus (P) have been widely investigated in many different ecosystems, and several enzymes have been recognized as key components in regulating C storage and nutrient cycling. In this review, it was the first time to summarize the specific extracellular enzymes related to C storage and nutrient cycling for better understanding the important role of microbial extracellular enzymes in biogeochemical cycling of ecosystems. Subsequently, ecoenzymatic stoichiometry - the relative ratio of extracellular enzyme, has been reviewed and further provided a new perspective for understanding biogeochemical cycling of ecosystems. Finally, the new insights of using microbial extracellular enzyme in indicating biogeochemical cycling and then protecting ecosystems have been suggested. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015EGUGA..1713016K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015EGUGA..1713016K">Sulfur and carbon isotope biogeochemistry of a rewetted brackish fen</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Koebsch, Franziska; Gehre, Matthias; Winkel, Matthias; Koehler, Stefan; Koch, Marian; Jurasinski, Gerald; Spitzy, Alejandro; Liebner, Susanne; Sachs, Torsten; Schmiedinger, Iris; Kretzschmann, Lisett; Saborowski, Anke; Böttcher, Michael E. 2015-04-01 Coastal wetlands are at the interface between terrestrial freshwater and marine and exhibit very specific biogeochemical conditions. Intermittent sea water intrusion affects metabolic pathways, i. e. anaerobic carbon metabolism is progressively dominated by sulfate reduction with lower contribution of methanogenesis whilst methane production is increasingly shifted from acetoclastic to hydrogenotrophic. Due to expanding anthropogenic impact a large proportion of coastal ecosystems is degraded with severe implications for the biogeochemical processes. We use concentration patterns and stable isotope signatures of water, sulfate, dissolved carbonate, and methane (δ2H, δ13C, δ18O, δ34S) to investigate the S and C metabolic cycle in a rewetted fen close to the southern Baltic Sea border. Such studies are crucial to better predict dynamic ecosystem feedback to global change like organic matter (OM) decomposition or greenhouse gas emissions. Yet, little is known about the metabolic pathways in such environments. The study site is part of the TERENO Observatory "Northeastern German Lowlands' and measurements of methane emissions have run since 2009. High methane fluxes up to 800 mg m-2 hr-1 indicate that methanogenesis is the dominant C metabolism pathway despite of high sulfate concentrations (up to 37 mM). The presented data are part of a comprehensive biogeochemical investigation that we conducted in autumn 2014 and that comprises 4 pore water profiles and sediment samples within a transect of 300-1500 m distance to the Baltic Sea. Depth of organic layers ranged from 25 to 140 cm with high OM contents (up to 90 dwt.%). Sulfate/chloride ratios in the pore waters were lower than in the Baltic Sea for most sites and sediment depths indicated a substantial net sulfate loss. Sulfide concentrations were negligible at the top and increased parallel to the sulfate concentrations with depth to values of up to 0.3 mM. One pore water profiles situated 1150 m from the Baltic Sea coast line exhibited a significant excess of sulfate. Preliminary sulfur isotope analysis of pore water sulfate from a location nearest to this profile revealed an enrichment in 34S (24.9 to 41.8o ) in comparison to Baltic Sea sulfate (21o ). This confirms high degrees of net sulfate reduction. Considering the yet high sulfate concentrations we hypothesize that local processes might supply additional sulfate and that the sulfide produced from sulfate reduction might either be lost by upwards diffusion towards the atmosphere or converted into other S compounds such as pyrite or organic compounds. The isotopic signatures of methane (δ13C: -68 to -57o and δ2H: -133 to -157o respectively) indicated acetoclastic methanogenesis to be the most dominant methane production pathway. However, estimated fractionation factors are comparatively high (1.050-1.065). Enrichment of heavy 13C in methane at the top of the sediment was either caused by methane oxidation or variation in substrate availability (e. g. due to peat degradation). The interpretation of our data in the light of further results will provide deeper insights into metabolic pathways and possible interactions between both coupled element cycles for coastal ecosystems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.B13C0581B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.B13C0581B">Biogeochemical Processes Related to Metal Removal and Toxicity Reduction in the H-02 Constructed Wetland, Savannah River Site</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Burgess, E. A.; Mills, G. L.; Harmon, M.; Samarkin, V. 2011-12-01 The H-02 wetland system was designed to treat building process water and storm water runoff from multiple sources associated with the Tritium Facility at the DOE-Savannah River Site, Aiken, SC. The wetland construction included the addition of gypsum (calcium sulfate) to foster a sulfate-reducing bacterial population. Conceptually, the wetland functions as follows: ? Cu and Zn initially bind to both dissolved and particulate organic detritus within the wetland. ? A portion of this organic matter is subsequently deposited into the surface sediments within the wetland. ? The fraction of Cu and Zn that is discharged in the wetland effluent is organically complexed, less bioavailable, and consequently, less toxic. ? The Cu and Zn deposited in the surface sediments are eventually sequestered into insoluble sulfide minerals in the wetland. Development of the H-02 system has been closely monitored; sampling began in August 2007, shortly after its construction. This monitoring has included the measurement of water quality parameters, Cu and Zn concentrations in surface water and sediments, as well as, characterization of the prokaryotic (e.g., bacterial) component of wetland biogeochemical processes. Since the beginning of the study, the mean influent Cu concentration was 31.5±12.1 ppb and the mean effluent concentration was 11.9±7.3 ppb, corresponding to an average Cu removal of 64%. Zn concentrations were more variable, averaging 39.2±13.8 ppb in the influent and 25.7±21.3 ppb in the effluent. Average Zn removal was 52%. The wetland also ameliorated high pH values associated with influent water to values similar to those measured at reference sites. Seasonal variations in DOC concentration corresponded to seasonal variations in Cu and Zn removal efficiency. The concentration of Cu and Zn in the surface layer of the sediments has increased over the lifetime of the wetland and, like removal efficiency, demonstrated seasonal variation. Within its first year, the H-02 wetland showed biomarkers for sulfate-reducing bacteria. Sulfate-reduction and methane-oxidation rates in the sediments were determined using radiotracer techniques. Sulfate-reduction was detected in all depths of sediment cores, even in surface detritus layers. Gas measurements from H-02 sediments demonstrated that methane is available to support a methane oxidizing community, and active methane-oxidation was detected in the sediments and overlying water. Our results demonstrate that the H-02 wetlands are functioning successfully to remove Cu and Zn from influent waters. The continued success and long-term sustainability of the functioning H-02 system is predicated on maintaining in situ biogeochemistry. However, the relative importance of various biogeochemical cycles remains unclear. For example, the Cu and Zn deposited in the sediments are associated with organic detritus at the sediment surface; the extent and rate at which the metals will redistribute to more recalcitrant sulfide mineral phases remain to be determined. Thus, the H-02 wetland system is a valuable resource not only for metal removal at SRS, but also can further enhance the understanding of wetland function within the scientific and regulatory communities. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.2929P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.2929P">Thermodynamics at work - on the limits and potentials of biogeochemical processes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Peiffer, Stefan 2017-04-01 The preferential use of high potential electron acceptors by microorganisms has lead to the classical concept of a redox sequence with a sequential use of O2 nitrate, Fe(III), sulfate, and finally CO2 as electron acceptors for respiration (Stumm & Morgan, 1996). Christian Blodau has rigourously applied this concept to constrain the thermodynamical limits at which specific aquatic systems operate. In sediments from acidic mining lakes his analysis revealed that sulfate reducers are not competitive as long as low-crystallinity ferric oxides are available for organic matter decomposition (Blodau et al, 1998). This analysis opened up the possibility to generalize the linkage between the iron and sulphur cycle in such systems and to constrain the biogeochemical limits for remediation (e. g. Peine et al, 2000). In a similar approach, Beer & Blodau (2007) were able to demonstrate that constraints on the removal of products from acetoclastic methanogenesis in deeper peat layers are inhibiting organic matter decomposition and provide a thermodynamic argument for peat accumulation. In this contribution I will review such ideas and further refine the limits and potentials of biogeochemical reactions in terms of redox-active metastable phases (RAMPS) that are typically mixed-valent carbon-, iron-, and sulfur-containing compounds and which allow for the occurrence of a number of enigmatic reactions, e. g. limited greenhouse gas emission (CH4) under dynamic redox conditions. It is proposed that redox equivalents are generated, stored and recycled during oxidation and reduction cycles thus suppressing methanogenesis (Blodau, 2002). Such RAMPS will preferentially occur at dynamic interfaces being exposed to frequent redox cycles. The concept of RAMPS will be illustrated along the interaction between ferric (hydr)oxides and dissolved sulphide. Recent studies using modern analytical tools revealed the formation of a number of amorphous products within a short time scale (days) both on the Fe and S side (Peiffer & Wan, 2016; Wan et al, 2014) which will allow for the occurrence of cryptic sulphur cycles, i. e. high turnover of sulphide and sulfate without the appearance of dissolved sulphide species. References Beer, J; Blodau, C (2007): Transport and thermodynamics constrain belowground carbon turover in a northern peatland, Geochim. Cosmochim. Acta, 71, 2989-3002 Blodau, C. (2002). "Carbon cycling in peatlands: A review of processes and controls." Environmental Reviews 10(2): 111-134. Blodau, C; Hoffmann, S; Peine, A; Peiffer, S (1998): Iron and sulfate reduction in the sediments of acid mine lake 116 (Brandenburg, Germany): Rates and geochemical evaluation, Water, Air and Soil Pollution, 108, 249-270 Peiffer, S., Wan M. (2016) Reductive Dissolution and Reactivity of Ferric (Hydr)oxides, in Faivre, D., Iron Oxides: From Nature to Applications, Wiley-VCH, chapter 3, 29-51 Peine, A; Küsel, K; Tritschler, A; Peiffer, S (2000): Electron flow in an iron-rich acidic sedimant - evidence for an acidity-driven iron cycle, Limnol. Oceanogr., 45(5), 1077-1087 Stumm, W.; Morgan, J. J. (1996): Aquatic Chemistry, Wiley Wan, M., Shchukarev, A., Lohmayer, R., Planer-Friedrich, B., Peiffer, S. (2014) Occurrence of surface polysulfides during the interaction between ferric (hydr)oxides and aqueous sulfide. Environmental Science and Technology, 48, 5076-5084 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1033841-variably-saturated-flow-multicomponent-biogeochemical-reactive-transport-modeling-uranium-bioremediation-field-experiment','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1033841-variably-saturated-flow-multicomponent-biogeochemical-reactive-transport-modeling-uranium-bioremediation-field-experiment">Variably Saturated Flow and Multicomponent Biogeochemical Reactive Transport Modeling of a Uranium Bioremediation Field Experiment</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Yabusaki, Steven B.; Fang, Yilin; Williams, Kenneth H. 2011-11-01 Field experiments at a former uranium mill tailings site have identified the potential for stimulating indigenous bacteria to catalyze the conversion of aqueous uranium in the +6 oxidation state to immobile solid-associated uranium in the +4 oxidation state. This effectively removes uranium from solution resulting in groundwater concentrations below actionable standards. Three-dimensional, coupled variably-saturated flow and biogeochemical reactive transport modeling of a 2008 in situ uranium bioremediation field experiment is used to better understand the interplay of transport rates and biogeochemical reaction rates that determine the location and magnitude of key reaction products. A comprehensive reaction network, developed largely throughmore » previous 1-D modeling studies, was used to simulate the impacts on uranium behavior of pulsed acetate amendment, seasonal water table variation, spatially-variable physical (hydraulic conductivity, porosity) and geochemical (reactive surface area) material properties. A principal challenge is the mechanistic representation of biologically-mediated terminal electron acceptor process (TEAP) reactions whose products significantly alter geochemical controls on uranium mobility through increases in pH, alkalinity, exchangeable cations, and highly reactive reduction products. In general, these simulations of the 2008 Big Rusty acetate biostimulation field experiment in Rifle, Colorado confirmed previously identified behaviors including (1) initial dominance by iron reducing bacteria that concomitantly reduce aqueous U(VI), (2) sulfate reducing bacteria that become dominant after {approx}30 days and outcompete iron reducers for the acetate electron donor, (3) continuing iron-reducer activity and U(VI) bioreduction during dominantly sulfate reducing conditions, and (4) lower apparent U(VI) removal from groundwater during dominantly sulfate reducing conditions. New knowledge on simultaneously active metal and sulfate reducers has been incorporated into the modeling. In this case, an initially small population of slow growing sulfate reducers is active from the initiation of biostimulation. Three-dimensional, variably saturated flow modeling was used to address impacts of a falling water table during acetate injection. These impacts included a significant reduction in aquifer saturated thickness and isolation of residual reactants and products, as well as unmitigated uranium, in the newly unsaturated vadose zone. High permeability sandy gravel structures resulted in locally high flow rates in the vicinity of injection wells that increased acetate dilution. In downgradient locations, these structures created preferential flow paths for acetate delivery that enhanced local zones of TEAP reactivity and subsidiary reactions. Conversely, smaller transport rates associated with the lower permeability lithofacies (e.g., fine) and vadose zone were shown to limit acetate access and reaction. Once accessed by acetate, however, these same zones limited subsequent acetate dilution and provided longer residence times that resulted in higher concentrations of TEAP products when terminal electron donors and acceptors were not limiting. Finally, facies-based porosity and reactive surface area variations were shown to affect aqueous uranium concentration distributions; however, the ranges were sufficiently small to preserve general trends. Large computer memory and high computational performance were required to simulate the detailed coupled process models for multiple biogeochemical components in highly resolved heterogeneous materials for the 110-day field experiment and 50 days of post-biostimulation behavior. In this case, a highly-scalable subsurface simulator operating on 128 processor cores for 12 hours was used to simulate each realization. An equivalent simulation without parallel processing would have taken 60 days, assuming sufficient memory was available.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28151654','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28151654">Extracellular Saccharide-Mediated Reduction of Au3+ to Gold Nanoparticles: New Insights for Heavy Metals Biomineralization on Microbial Surfaces.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kang, Fuxing; Qu, Xiaolei; Alvarez, Pedro J J; Zhu, Dongqiang 2017-03-07 Biomineralization is a critical process controlling the biogeochemical cycling, fate, and potential environmental impacts of heavy metals. Despite the indispensability of extracellular polymeric substances (EPS) to microbial life and their ubiquity in soil and aquatic environments, the role played by EPS in the transformation and biomineralization of heavy metals is not well understood. Here, we used gold ion (Au 3+ ) as a model heavy metal ion to quantitatively assess the role of EPS in biomineralization and discern the responsible functional groups. Integrated spectroscopic analyses showed that Au 3+ was readily reduced to zerovalent gold nanoparticles (AuNPs, 2-15 nm in size) in aqueous suspension of Escherichia coli or dissolved EPS extracted from microbes. The majority of AuNPs (95.2%) was formed outside Escherichia coli cells, and the removal of EPS attached to cells pronouncedly suppressed Au 3+ reduction, reflecting the predominance of the extracellular matrix in Au 3+ reduction. XPS, UV-vis, and FTIR analyses corroborated that Au 3+ reduction was mediated by the hemiacetal groups (aldehyde equivalents) of reducing saccharides of EPS. Consistently, the kinetics of AuNP formation obeyed pseudo-second-order reaction kinetics with respect to the concentrations of Au 3+ and the hemiacetal groups in EPS, with minimal dependency on the source of microbial EPS. Our findings indicate a previously overlooked, universally significant contribution of EPS to the reduction, mineralization, and potential detoxification of metal species with high oxidation state. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1855672','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1855672">Potential for Mercury Reduction by Microbes in the High Arctic▿</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Poulain, Alexandre J.; Ní Chadhain, Sinéad M.; Ariya, Parisa A.; Amyot, Marc; Garcia, Edenise; Campbell, Peter G. C.; Zylstra, Gerben J.; Barkay, Tamar 2007-01-01 The contamination of polar regions due to the global distribution of anthropogenic pollutants is of great concern because it leads to the bioaccumulation of toxic substances, methylmercury among them, in Arctic food chains. Here we present the first evidence that microbes in the high Arctic possess and express diverse merA genes, which specify the reduction of ionic mercury [Hg(II)] to the volatile elemental form [Hg(0)]. The sampled microbial biomass, collected from microbial mats in a coastal lagoon and from the surface of marine macroalgae, was comprised of bacteria that were most closely related to psychrophiles that had previously been described in polar environments. We used a kinetic redox model, taking into consideration photoredox reactions as well as mer-mediated reduction, to assess if the potential for Hg(II) reduction by Arctic microbes can affect the toxicity and environmental mobility of mercury in the high Arctic. Results suggested that mer-mediated Hg(II) reduction could account for most of the Hg(0) that is produced in high Arctic waters. At the surface, with only 5% metabolically active cells, up to 68% of the mercury pool was resolved by the model as biogenic Hg(0). At a greater depth, because of incident light attenuation, the significance of photoredox transformations declined and merA-mediated activity could account for up to 90% of Hg(0) production. These findings highlight the importance of microbial redox transformations in the biogeochemical cycling, and thus the toxicity and mobility, of mercury in polar regions. PMID:17293515 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1167142','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1167142">MURMoT. Design and Application of Microbial Uranium Reduction Monitoring Tools</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Loeffler, Frank E. 2014-12-31 Uranium (U) contamination in the subsurface is a major remediation challenge at many DOE sites. Traditional site remedies present enormous costs to DOE; hence, enhanced bioremediation technologies (i.e., biostimulation and bioaugmentation) combined with monitoring efforts are being considered as cost-effective corrective actions to address subsurface contamination. This research effort improved understanding of the microbial U reduction process and developed new tools for monitoring microbial activities. Application of these tools will promote science-based site management decisions that achieve contaminant detoxification, plume control, and long-term stewardship in the most efficient manner. The overarching hypothesis was that the design, validation and application ofmore » a suite of new molecular and biogeochemical tools advance process understanding, and improve environmental monitoring regimes to assess and predict in situ U immobilization. Accomplishments: This project (i) advanced nucleic acid-based approaches to elucidate the presence, abundance, dynamics, spatial distribution, and activity of metal- and radionuclide-detoxifying bacteria; (ii) developed proteomics workflows for detection of metal reduction biomarker proteins in laboratory cultures and contaminated site groundwater; (iii) developed and demonstrated the utility of U isotopic fractionation using high precision mass spectrometry to quantify U(VI) reduction for a range of reduction mechanisms and environmental conditions; and (iv) validated the new tools using field samples from U-contaminated IFRC sites, and demonstrated their prognostic and diagnostic capabilities in guiding decision making for environmental remediation and long-term site stewardship.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EGUGA..15.3552S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EGUGA..15.3552S">Biogeochemical cycles of Chernobyl-born radionuclides in the contaminated forest ecosystems: long-term dynamics of the migration processes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Shcheglov, Alexey; Tsvetnova, Ol'ga; Klyashtorin, Alexey 2013-04-01 Biogeochemical migration is a dominant factor of the radionuclide transport through the biosphere. In the early XX century, V.I. Vernadskii, a Russian scientist known, noted about a special role living things play in transport and accumulation of natural radionuclide in various environments. The role of biogeochemical processes in migration and redistribution of technogenic radionuclides is not less important. In Russia, V. M. Klechkovskii and N.V. Timofeev-Ressovskii showed some important biogeochemical aspects of radionuclide migration by the example of global fallout and Kyshtym accident. Their followers, R.M. Alexakhin, M.A. Naryshkin, N.V. Kulikov, F.A. Tikhomirov, E.B. Tyuryukanova, and others also contributed a lot to biogeochemistry of radionuclides. In the post-Chernobyl period, this area of knowledge received a lot of data that allowed building the radioactive element balance and flux estimation in various biogeochemical cycles [Shcheglov et al., 1999]. Regrettably, many of recent radioecological studies are only focused on specific radionuclide fluxes or pursue some applied tasks, missing the holistic approach. Most of the studies consider biogeochemical fluxes of radioactive isotopes in terms of either dose estimation or radionuclide migration rates in various food chains. However, to get a comprehensive picture and develop a reliable forecast of environmental, ecological, and social consequences of radioactive pollution in a vast contaminated area, it is necessary to investigate all the radionuclide fluxes associated with the biogeochemical cycles in affected ecosystems. We believe such an integrated approach would be useful to study long-term environmental consequences of the Fukushima accident as well. In our long-term research, we tried to characterize the flux dynamics of the Chernobyl-born radionuclides in the contaminated forest ecosystems and landscapes as a part of the integrated biogeochemical process. Our field studies were started in June of 1986 (less than two months after the accident) and have been continued up to now, focused on the most common forest ecosystems scattered over the contaminated areas of Russian Federation and Ukraine. A comprehensive analysis of the 137Cs and 90Sr biogeochemical fluxes shows that downward radionuclide fluxes (those directed from tree crowns to the soil) dominated over the upward fluxes (from the soil to forest vegetation) in the first years after the accident. Currently, the biological cycle in the contaminated ecosystems is a main factor impeding further vertical migration of long-lived radionuclides from upper soil layers to the ground water. The role of biota as a retardation factor depends on landscape type as well. In accumulative landscapes (with positive material balance), biota plays leading role in radionuclide retardation, while in eluvial landscapes (with the negative balance) soil absorbing complex serves as the dominant barrier for radionuclides leaching down the soil profile. The manifestation of both soil- and biota-driven factors depends on the radionuclide chemical speciation in the initial fallout. The latter factor is most important for 137Cs, yet less manifested for 90Sr. Among the biota components, fungi and forest vegetation are of particular importance for 137Cs and 90Sr accumulation, respectively. In summary, biogeochemical cycles of 137Cs and 90Sr in the investigated forest ecosystems serve as main factors impeding the radionuclide migration from the fallout to ground water. Larger-scale landscape factors determine the radionuclide flux intensity in the biogeochemical cycles and affect the radionuclide spatial variability in the contaminated biota components. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28378610','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28378610">Continuous Adaptive Population Reduction (CAPR) for Differential Evolution Optimization.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Wong, Ieong; Liu, Wenjia; Ho, Chih-Ming; Ding, Xianting 2017-06-01 Differential evolution (DE) has been applied extensively in drug combination optimization studies in the past decade. It allows for identification of desired drug combinations with minimal experimental effort. This article proposes an adaptive population-sizing method for the DE algorithm. Our new method presents improvements in terms of efficiency and convergence over the original DE algorithm and constant stepwise population reduction-based DE algorithm, which would lead to a reduced number of cells and animals required to identify an optimal drug combination. The method continuously adjusts the reduction of the population size in accordance with the stage of the optimization process. Our adaptive scheme limits the population reduction to occur only at the exploitation stage. We believe that continuously adjusting for a more effective population size during the evolutionary process is the major reason for the significant improvement in the convergence speed of the DE algorithm. The performance of the method is evaluated through a set of unimodal and multimodal benchmark functions. In combining with self-adaptive schemes for mutation and crossover constants, this adaptive population reduction method can help shed light on the future direction of a completely parameter tune-free self-adaptive DE algorithm. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2004ThApC..78..157B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2004ThApC..78..157B">The role of ecosystem-atmosphere interactions in simulated Amazonian precipitation decrease and forest dieback under global climate warming</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Betts, R. A.; Cox, P. M.; Collins, M.; Harris, P. P.; Huntingford, C.; Jones, C. D. A suite of simulations with the HadCM3LC coupled climate-carbon cycle model is used to examine the various forcings and feedbacks involved in the simulated precipitation decrease and forest dieback. Rising atmospheric CO2 is found to contribute 20% to the precipitation reduction through the physiological forcing of stomatal closure, with 80% of the reduction being seen when stomatal closure was excluded and only radiative forcing by CO2 was included. The forest dieback exerts two positive feedbacks on the precipitation reduction; a biogeophysical feedback through reduced forest cover suppressing local evaporative water recycling, and a biogeochemical feedback through the release of CO2 contributing to an accelerated global warming. The precipitation reduction is enhanced by 20% by the biogeophysical feedback, and 5% by the carbon cycle feedback from the forest dieback. This analysis helps to explain why the Amazonian precipitation reduction simulated by HadCM3LC is more extreme than that simulated in other GCMs; in the fully-coupled, climate-carbon cycle simulation, approximately half of the precipitation reduction in Amazonia is attributable to a combination of physiological forcing and biogeophysical and global carbon cycle feedbacks, which are generally not included in other GCM simulations of future climate change. The analysis also demonstrates the potential contribution of regional-scale climate and ecosystem change to uncertainties in global CO2 and climate change projections. Moreover, the importance of feedbacks suggests that a human-induced increase in forest vulnerability to climate change may have implications for regional and global scale climate sensitivity. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_16");'>16</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li class="active">18</li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_19" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li class="active">19</li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="361"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19940014760','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19940014760">The carbon isotope biogeochemistry of (epsilon)CO2 production in a methanogenic marine sediment</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Boehme, Susan E. 1993-01-01 To investigate the relationship between sigma(CO2) delta(C-13) values and rates of the dominant remineralization processes at the organic-rich field site of Cape Lookout Bight, NC, the isotopic composition of porewater sigma(CO2) was measured on a seasonal basis. The sigma(CO2) delta(C-13) values varies seasonally in response to changes in rates of sulfate reduction and methanogenesis, the dominant remineralization processes at this site. A tube incubation experiment was also performed to determine the isotopic signature of the sigma(CO2) produced by sulfate reduction and methanogenesis. The delta(C-13) of the sigma(CO2) produced in the sulfate reduction zone determined from the tube incubation was -14.3 plus or minus 1.9, a value enriched in C-13 relative to the labile organic fraction. The C-13-enrichment may be caused by low rates of methanogenesis occurring in the sulfate reduction zone. The delta(C-13) of the sigma(CO2) produced in the methanogenic zone was estimated to be +44 per mil, whereas the co-produced methane was -65 per mil. The fractionation factor for CO2 reduction was calculated to be 1.055, a value in agreement with previous estimates at this site. The measured concentration and delta(C-13) of the sigma(CO2) at Cape Lookout was closely reproduced by a diagenetic model using the measured rates of sulfate reduction and sigma(CO2) production, and the isotopic signature of the sigma(CO2) production in the two biogeochemical zones. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=91799','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=91799">Evidence for Microbial Fe(III) Reduction in Anoxic, Mining-Impacted Lake Sediments (Lake Coeur d'Alene, Idaho)</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Cummings, David E.; March, Anthony W.; Bostick, Benjamin; Spring, Stefan; Caccavo, Frank; Fendorf, Scott; Rosenzweig, R. Frank 2000-01-01 Mining-impacted sediments of Lake Coeur d'Alene, Idaho, contain more than 10% metals on a dry weight basis, approximately 80% of which is iron. Since iron (hydr)oxides adsorb toxic, ore-associated elements, such as arsenic, iron (hydr)oxide reduction may in part control the mobility and bioavailability of these elements. Geochemical and microbiological data were collected to examine the ecological role of dissimilatory Fe(III)-reducing bacteria in this habitat. The concentration of mild-acid-extractable Fe(II) increased with sediment depth up to 50 g kg−1, suggesting that iron reduction has occurred recently. The maximum concentrations of dissolved Fe(II) in interstitial water (41 mg liter−1) occurred 10 to 15 cm beneath the sediment-water interface, suggesting that sulfidogenesis may not be the predominant terminal electron-accepting process in this environment and that dissolved Fe(II) arises from biological reductive dissolution of iron (hydr)oxides. The concentration of sedimentary magnetite (Fe3O4), a common product of bacterial Fe(III) hydroxide reduction, was as much as 15.5 g kg−1. Most-probable-number enrichment cultures revealed that the mean density of Fe(III)-reducing bacteria was 8.3 × 105 cells g (dry weight) of sediment−1. Two new strains of dissimilatory Fe(III)-reducing bacteria were isolated from surface sediments. Collectively, the results of this study support the hypothesis that dissimilatory reduction of iron has been and continues to be an important biogeochemical process in the environment examined. PMID:10618217 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23802169','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23802169">Promoted reduction of tellurite and formation of extracellular tellurium nanorods by concerted reaction between iron and Shewanella oneidensis MR-1.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Kim, Dong-Hun; Kim, Min-Gyu; Jiang, Shenghua; Lee, Ji-Hoon; Hur, Hor-Gil 2013-08-06 The reduction of tellurite (Te(IV)) by dissimilatory metal reducing bacterium, Shewanella oneidensis MR-1, was promoted in the presence of Fe(III) in comparison with Te(IV) bioreduction in the absence of Fe(III). Electron microscopic analyses revealed that iron promoted Te(IV) reduction led to form exclusively extracellular crystalline Te(0) nanorods, as compared to the mostly intracellular formation of Te(0) nanorods in the absence of Fe(III). The Te K-edge X-ray absorption spectrometric analyses demonstrated that S. oneidensis MR-1 in the presence of Fe(III) reduced Te(IV) to less harmful metallic Te(0) nanorods through the precipitation of tellurite (Te(IV)Ox) complex by the bacterial respiration of Fe(III) to Fe(II) under anaerobic conditions. However, Fe(II) ion itself was only able to precipitate the solid tellurite (Te(IV)Ox) complex from the Te(IV) solution, which was not further reduced to Te(0). The results clearly indicated that bacterial S. oneidensis MR-1 plays important roles in the reduction and crystallization of Te(0) nanorods by as yet undetermined biochemical mechanisms. As compared to the slow bacterial Te(IV) reduction in the absence of Fe(III), the rapid reduction of Te(IV) to Te(0) by the concerted biogeochemical reaction between Fe(II) and S. oneidensis MR-1 could be applied for the sequestration and detoxification of Te(IV) in the environments as well as for the preparation of extracellular Te(0) nanorod structures. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26762391','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26762391">Enhanced reduction of Fe(III) oxides and methyl orange by Klebsiella oxytoca in presence of anthraquinone-2-disulfonate.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Yu, Lei; Wang, Shi; Tang, Qing-Wen; Cao, Ming-Yue; Li, Jia; Yuan, Kun; Wang, Ping; Li, Wen-Wei 2016-05-01 Klebsiella oxytoca GS-4-08 is capable of azo dye reduction, but its quinone respiration and Fe(III) reduction abilities have not been reported so far. In this study, the abilities of this strain were reported in detail for the first time. As the biotic reduction of Fe(III) plays an important role in the biogeochemical cycles, two amorphous Fe(III) oxides were tested as the sole electron acceptor during the anaerobic respiration of strain GS-4-08. For the reduction of goethite and hematite, the biogenic Fe(II) concentrations reached 0.06 and 0.15 mM, respectively. Humic acid analog anthraquinone-2-disulfonate (AQS) was found to serve as an electron shuttle to increase the reduction of both methyl orange (MO) and amorphous Fe(III) oxides, and improve the dye tolerance of the strain. However, the formation of Fe(II) was not accelerated by biologically reduced AQS (B-AH2QS) because of the high bioavailability of soluble Fe(III). For the K. oxytoca strain, high soluble Fe(III) concentrations (above 1 mM) limit its growth and decolorization ability, while lower soluble Fe(III) concentrations produce an electron competition with MO initially, and then stimulate the decolorization after the electron couples of Fe(III)/Fe(II) are formed. With the ability to respire both soluble Fe(III) and insoluble Fe(III) oxides, this formerly known azo-reducer may be used as a promising model organism for the study of the interaction of these potentially competing processes in contaminated environments. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4018907','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4018907">Sulfur Species as Redox Partners and Electron Shuttles for Ferrihydrite Reduction by Sulfurospirillum deleyianum</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Lohmayer, Regina; Kappler, Andreas; Lösekann-Behrens, Tina 2014-01-01 Iron(III) (oxyhydr)oxides can represent the dominant microbial electron acceptors under anoxic conditions in many aquatic environments, which makes understanding the mechanisms and processes regulating their dissolution and transformation particularly important. In a previous laboratory-based study, it has been shown that 0.05 mM thiosulfate can reduce 6 mM ferrihydrite indirectly via enzymatic reduction of thiosulfate to sulfide by the sulfur-reducing bacterium Sulfurospirillum deleyianum, followed by abiotic reduction of ferrihydrite coupled to reoxidation of sulfide. Thiosulfate, elemental sulfur, and polysulfides were proposed as reoxidized sulfur species functioning as electron shuttles. However, the exact electron transfer pathway remained unknown. Here, we present a detailed analysis of the sulfur species involved. Apart from thiosulfate, substoichiometric amounts of sulfite, tetrathionate, sulfide, or polysulfides also initiated ferrihydrite reduction. The portion of thiosulfate produced during abiotic ferrihydrite-dependent reoxidation of sulfide was about 10% of the total sulfur at maximum. The main abiotic oxidation product was elemental sulfur attached to the iron mineral surface, which indicates that direct contact between microorganisms and ferrihydrite is necessary to maintain the iron reduction process. Polysulfides were not detected in the liquid phase. Minor amounts were found associated either with microorganisms or the mineral phase. The abiotic oxidation of sulfide in the reaction with ferrihydrite was identified as rate determining. Cysteine, added as a sulfur source and a reducing agent, also led to abiotic ferrihydrite reduction and therefore should be eliminated when sulfur redox reactions are investigated. Overall, we could demonstrate the large impact of intermediate sulfur species on biogeochemical iron transformations. PMID:24632263 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=339269&Lab=NERL&keyword=Charles+AND+Will&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=339269&Lab=NERL&keyword=Charles+AND+Will&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Landscape Conservation of Aquatic Habitats Promotes Watershed-scale Biological, Biogeochemical, and Hydrological Functions</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Wetlands are exceptionally productive landscape features that provide critical habitat for endemic species, threatened/endangered and migratory animals, store floodwaters and maintain baseflows in stream systems, recharge groundwaters, and biogeochemically and physically affect n... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=182865&keyword=computer+AND+Operating+AND+systems&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=182865&keyword=computer+AND+Operating+AND+systems&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">CALIBRATION OF SUBSURFACE BATCH AND REACTIVE-TRANSPORT MODELS INVOLVING COMPLEX BIOGEOCHEMICAL PROCESSES</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> In this study, the calibration of subsurface batch and reactive-transport models involving complex biogeochemical processes was systematically evaluated. Two hypothetical nitrate biodegradation scenarios were developed and simulated in numerical experiments to evaluate the perfor... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009EGUGA..11.3377R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009EGUGA..11.3377R">Soil tillage conservation and its effect on erosion control, water management and carbon sequestration</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Rusu, Dr.; Gus, Dr.; Bogdan, Dr.; Moraru, Dr.; Pop, Dr.; Clapa, Dr.; Pop, Drd. 2009-04-01 The energetic function of the soil expressed through the potential energy accumulated through humus, the biogeochemical function (the circuit of the nutrient elements) are significantly influenced by its hydrophysical function and especially by the state of the bedding- consolidation, soil capacity of retaining an optimal quantity of water, and then its gradual disponibility for plant consumption. The understanding of soil functions and management including nutrient production, stocking, filtering and transforming minerals, water , organic matter , gas circuit and furnishing breeding material, all make the basis of human activity, Earth's past, present and especially future. The minimum tillage soil systems - paraplow, chisel or rotary grape - are polyvalent alternatives for basic preparation, germination bed preparation and sowing, for fields and crops with moderate loose requirements being optimized technologies for: soil natural fertility activation and rationalization, reduction of erosion, increasing the accumulation capacity for water and realization of sowing in the optimal period. By continuously applying for 10 years the minimum tillage system in a crop rotation: corn - soy-bean - wheat - potato / rape, an improvement in physical, hydro-physical and biological properties of soil was observed, together with the rebuilt of structure and increase of water permeability of soil. The minimum tillage systems ensure an adequate aerial-hydrical regime for the biological activity intensity and for the nutrients solubility equilibrium. The vegetal material remaining at the soil surface or superficially incorporated has its contribution to intensifying the biological activity, being an important resource of organic matter. The minimum tillage systems rebuild the soil structure, improving the global drainage of soil which allows a rapid infiltration of water in soil. The result is a more productive soil, better protected against wind and water erosion and needing less fuel for preparing the germination bed. Presently it is necessary a change concerning the concept of conservation practices and a new approach regarding the control of erosion. The real conservation of soil must be expanded beyond the traditional understanding of soil erosion. The real soil conservation is represented by carbon management. We need to focus to another level concerning conservation by focusing on of soil quality. Carbon management is necessary for a complex of matters including soil, water management, field productivity, biological fuel and climatic change. Profound research is necessary in order to establish the carbon sequestration practices and their implementation impact. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009EGUGA..11.1481R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009EGUGA..11.1481R">Soil tillage conservation and its effect on erosion control, water management and carbon sequestration</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Rusu, T.; Gus, P.; Bogdan, I.; Moraru, P.; Pop, A.; Clapa, D.; Pop, L. 2009-04-01 The energetic function of the soil expressed through the potential energy accumulated through humus, the biogeochemical function (the circuit of the nutrient elements) are significantly influenced by its hydrophysical function and especially by the state of the bedding- consolidation, soil capacity of retaining an optimal quantity of water, and then its gradual disponibility for plant consumption. The understanding of soil functions and management including nutrient production, stocking, filtering and transforming minerals, water , organic matter, gas circuit and furnishing breeding material, all make the basis of human activity, Earth's past, present and especially future. The minimum tillage soil systems - paraplow, chisel or rotary grape - are polyvalent alternatives for basic preparation, germination bed preparation and sowing, for fields and crops with moderate loose requirements being optimized technologies for: soil natural fertility activation and rationalization, reduction of erosion, increasing the accumulation capacity for water and realization of sowing in the optimal period. By continuously applying for 10 years the minimum tillage system in a crop rotation: corn - soy-bean - wheat - potato / rape, an improvement in physical, hydro-physical and biological properties of soil was observed, together with the rebuilt of structure and increase of water permeability of soil. The minimum tillage systems ensure an adequate aerial-hydrical regime for the biological activity intensity and for the nutrients solubility equilibrium. The vegetal material remaining at the soil surface or superficially incorporated has its contribution to intensifying the biological activity, being an important resource of organic matter. The minimum tillage systems rebuild the soil structure, improving the global drainage of soil which allows a rapid infiltration of water in soil. The result is a more productive soil, better protected against wind and water erosion and needing less fuel for preparing the germination bed. Presently it is necessary a change concerning the concept of conservation practices and a new approach regarding the control of erosion. The real conservation of soil must be expanded beyond the traditional understanding of soil erosion. The real soil conservation is represented by carbon management. We need to focus to another level concerning conservation by focusing on of soil quality. Carbon management is necessary for a complex of matters including soil, water management, field productivity, biological fuel and climatic change. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017CMAME.319..217Y','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017CMAME.319..217Y">Algorithms and analyses for stochastic optimization for turbofan noise reduction using parallel reduced-order modeling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Yang, Huanhuan; Gunzburger, Max 2017-06-01 Simulation-based optimization of acoustic liner design in a turbofan engine nacelle for noise reduction purposes can dramatically reduce the cost and time needed for experimental designs. Because uncertainties are inevitable in the design process, a stochastic optimization algorithm is posed based on the conditional value-at-risk measure so that an ideal acoustic liner impedance is determined that is robust in the presence of uncertainties. A parallel reduced-order modeling framework is developed that dramatically improves the computational efficiency of the stochastic optimization solver for a realistic nacelle geometry. The reduced stochastic optimization solver takes less than 500 seconds to execute. In addition, well-posedness and finite element error analyses of the state system and optimization problem are provided. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3536105','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3536105">Genomic and Physiological Characterization of the Chromate-Reducing, Aquifer-Derived Firmicute Pelosinus sp. Strain HCF1</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Han, Ruyang; Karaoz, Ulas; Lim, HsiaoChien; Brodie, Eoin L. 2013-01-01 Pelosinus spp. are fermentative firmicutes that were recently reported to be prominent members of microbial communities at contaminated subsurface sites in multiple locations. Here we report metabolic characteristics and their putative genetic basis in Pelosinus sp. strain HCF1, an isolate that predominated anaerobic, Cr(VI)-reducing columns constructed with aquifer sediment. Strain HCF1 ferments lactate to propionate and acetate (the methylmalonyl-coenzyme A [CoA] pathway was identified in the genome), and its genome encodes two [NiFe]- and four [FeFe]-hydrogenases for H2 cycling. The reduction of Cr(VI) and Fe(III) may be catalyzed by a flavoprotein with 42 to 51% sequence identity to both ChrR and FerB. This bacterium has unexpected capabilities and gene content associated with reduction of nitrogen oxides, including dissimilatory reduction of nitrate to ammonium (two copies of NrfH and NrfA were identified along with NarGHI) and a nitric oxide reductase (NorCB). In this strain, either H2 or lactate can act as a sole electron donor for nitrate, Cr(VI), and Fe(III) reduction. Transcriptional studies demonstrated differential expression of hydrogenases and nitrate and nitrite reductases. Overall, the unexpected metabolic capabilities and gene content reported here broaden our perspective on what biogeochemical and ecological roles this species might play as a prominent member of microbial communities in subsurface environments. PMID:23064329 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29803094','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29803094">Synchronous microbial vanadium (V) reduction and denitrification in groundwater using hydrogen as the sole electron donor.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Jiang, Yufeng; Zhang, Baogang; He, Chao; Shi, Jiaxin; Borthwick, Alistair G L; Huang, Xueyang 2018-05-21 Groundwater co-contaminated by vanadium (V) (V(V)) and nitrate requires efficient remediation to prevent adverse environmental impacts. However, little is known about simultaneous bio-reductions of V(V) and nitrate supported by gaseous electron donors in aquifers. This study is among the first to examine microbial V(V) reduction and denitrification with hydrogen as the sole electron donor. V(V) removal efficiency of 91.0 ± 3.2% was achieved in test bioreactors within 7 d, with synchronous, complete removal of nitrate. V(V) was reduced to V(IV), which precipitated naturally under near-neutral conditions, and nitrate tended to be converted to nitrogen, both of which processes helped to purify the groundwater. Volatile fatty acids (VFAs) were produced from hydrogen oxidation. High-throughput 16S rRNA gene sequencing and metagenomic analyses revealed the evolutionary behavior of microbial communities and functional genes. The genera Dechloromonas and Hydrogenophaga promoted bio-reductions of V(V) and nitrate directly coupled to hydrogen oxidation. Enriched Geobacter and denitrifiers also indicated synergistic mechanism, with VFAs acting as organic carbon sources for heterotrophically functional bacteria while reducing V(V) and nitrate. These findings are likely to be useful in revealing biogeochemical fates of V(V) and nitrate in aquifer and developing technology for removing them simultaneously from groundwater. Copyright © 2018 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27631786','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27631786">Geochemical and microbial community determinants of reductive dechlorination at a site biostimulated with glycerol.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Atashgahi, Siavash; Lu, Yue; Zheng, Ying; Saccenti, Edoardo; Suarez-Diez, Maria; Ramiro-Garcia, Javier; Eisenmann, Heinrich; Elsner, Martin; J M Stams, Alfons; Springael, Dirk; Dejonghe, Winnie; Smidt, Hauke 2017-03-01 Biostimulation is widely used to enhance reductive dechlorination of chlorinated ethenes in contaminated aquifers. However, the knowledge on corresponding biogeochemical responses is limited. In this study, glycerol was injected in an aquifer contaminated with cis-dichloroethene (cDCE), and geochemical and microbial shifts were followed for 265 days. Consistent with anoxic conditions and sulfate reduction after biostimulation, MiSeq 16S rRNA gene sequencing revealed temporarily increased relative abundance of Firmicutes, Bacteriodetes and sulfate reducing Deltaproteobacteria. In line with 13 C cDCE enrichment and increased Dehalococcoides mccartyi (Dcm) numbers, dechlorination was observed toward the end of the field experiment, albeit being incomplete with accumulation of vinyl chloride. This was concurrent with (i) decreased concentrations of dissolved organic carbon (DOC), reduced relative abundances of fermenting and sulfate reducing bacteria that have been suggested to promote Dcm growth by providing electron donor (H 2 ) and essential corrinoid cofactors, (ii) increased sulfate concentration and increased relative abundance of Epsilonproteobacteria and Deferribacteres as putative oxidizers of reduced sulfur compounds. Strong correlations of DOC, relative abundance of fermenters and sulfate reducers, and dechlorination imply the importance of syntrophic interactions to sustain robust dechlorination. Tracking microbial and environmental parameters that promote/preclude enhanced reductive dechlorination should aid development of sustainable bioremediation strategies. © 2016 Society for Applied Microbiology and John Wiley & Sons Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20010089871','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20010089871">Robust Airfoil Optimization to Achieve Consistent Drag Reduction Over a Mach Range</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Li, Wu; Huyse, Luc; Padula, Sharon; Bushnell, Dennis M. (Technical Monitor) 2001-01-01 We prove mathematically that in order to avoid point-optimization at the sampled design points for multipoint airfoil optimization, the number of design points must be greater than the number of free-design variables. To overcome point-optimization at the sampled design points, a robust airfoil optimization method (called the profile optimization method) is developed and analyzed. This optimization method aims at a consistent drag reduction over a given Mach range and has three advantages: (a) it prevents severe degradation in the off-design performance by using a smart descent direction in each optimization iteration, (b) there is no random airfoil shape distortion for any iterate it generates, and (c) it allows a designer to make a trade-off between a truly optimized airfoil and the amount of computing time consumed. For illustration purposes, we use the profile optimization method to solve a lift-constrained drag minimization problem for 2-D airfoil in Euler flow with 20 free-design variables. A comparison with other airfoil optimization methods is also included. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=372814','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=372814">Dissimilatory Fe(III) and Mn(IV) reduction.</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Lovley, D R 1991-01-01 The oxidation of organic matter coupled to the reduction of Fe(III) or Mn(IV) is one of the most important biogeochemical reactions in aquatic sediments, soils, and groundwater. This process, which may have been the first globally significant mechanism for the oxidation of organic matter to carbon dioxide, plays an important role in the oxidation of natural and contaminant organic compounds in a variety of environments and contributes to other phenomena of widespread significance such as the release of metals and nutrients into water supplies, the magnetization of sediments, and the corrosion of metal. Until recently, much of the Fe(III) and Mn(IV) reduction in sedimentary environments was considered to be the result of nonenzymatic processes. However, microorganisms which can effectively couple the oxidation of organic compounds to the reduction of Fe(III) or Mn(IV) have recently been discovered. With Fe(III) or Mn(IV) as the sole electron acceptor, these organisms can completely oxidize fatty acids, hydrogen, or a variety of monoaromatic compounds. This metabolism provides energy to support growth. Sugars and amino acids can be completely oxidized by the cooperative activity of fermentative microorganisms and hydrogen- and fatty-acid-oxidizing Fe(III) and Mn(IV) reducers. This provides a microbial mechanism for the oxidation of the complex assemblage of sedimentary organic matter in Fe(III)- or Mn(IV)-reducing environments. The available evidence indicates that this enzymatic reduction of Fe(III) or Mn(IV) accounts for most of the oxidation of organic matter coupled to reduction of Fe(III) and Mn(IV) in sedimentary environments. Little is known about the diversity and ecology of the microorganisms responsible for Fe(III) and Mn(IV) reduction, and only preliminary studies have been conducted on the physiology and biochemistry of this process. PMID:1886521 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=248231&keyword=soil+AND+carbon+AND+climate&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=248231&keyword=soil+AND+carbon+AND+climate&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Climate change effects on watershed hydrological and biogeochemical processes</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Projected changes in climate are widely expected to alter watershed processes. However, the extent of these changes is difficult to predict because complex interactions among affected hydrological and biogeochemical processes will likely play out over many decades and spatial sc... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=275754&keyword=urban+AND+landscape&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=275754&keyword=urban+AND+landscape&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Spatial Distribution of Small Water Body Types in Indiana Ecoregions</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Due to their large numbers and biogeochemical activity, small water bodies (SWBs), such as ponds and wetlands, can have substantial cumulative effects on hydrologic and biogeochemical processes. Using updated National Wetland Inventory data, we describe the spatial distribution o... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=307256&keyword=Pollution+AND+Soil&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=307256&keyword=Pollution+AND+Soil&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Nitrous Oxide Emissions from Biofuel Crops and Parameterization in the EPIC Biogeochemical Model</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> This presentation describes year 1 field measurements of N2O fluxes and crop yields which are used to parameterize the EPIC biogeochemical model for the corresponding field site. Initial model simulations are also presented. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1429750','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1429750"></a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Hammond, Glenn Edward; Yang, Xiaofan; Song, Xuehang The groundwater-surface water interaction zone (GSIZ) plays an important role in riverine and watershed ecosystems as the exchange of waters of variable composition and temperature (hydrologic exchange flows) stimulate microbial activity and associated biogeochemical reactions. Variable temporal and spatial scales of hydrologic exchange flows, heterogeneity of the subsurface environment, and complexity of biogeochemical reaction networks in the GSIZ present challenges to incorporation of fundamental process representations and model parameterization across a range of spatial scales (e.g. from pore-scale to field scale). This paper presents a novel hybrid multiscale simulation approach that couples hydrologic-biogeochemical (HBGC) processes between two distinct length scalesmore » of interest.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018MMTB..tmp..945S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018MMTB..tmp..945S">Optimization of Quenching Parameters for the Reduction of Titaniferous Magnetite Ore by Lean Grade Coal Using the Taguchi Method and Its Isothermal Kinetic Study</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sarkar, Bitan Kumar; Kumar, Nikhil; Dey, Rajib; Das, Gopes Chandra 2018-06-01 In the present study, a unique method is adopted to achieve higher reducibility of titaniferous magnetite lump ore (TMO). In this method, TMO is initially heated followed by water quenching. The quenching process generates cracks due to thermal shock in the dense TMO lumps, which, in turn, increases the extent of reduction (EOR) using the lean grade coal as a reductant. The optimum combination of parameters found by using Taguchi's L27 orthogonal array (OA) (five factors, three levels) is - 8 + 4 mm of particle size (PS1), 1423 K of quenching temperature (Qtemp2), 15 minutes of quenching time (Qtime3), 3 times the number of quenching {(No. of Q)3}, and 120 minutes of reduction time (Rtime3) at fixed reduction temperature of 1473 K. At optimized levels of the parameters, 92.39 pct reduction is achieved. Isothermal reduction kinetics of the quenched TMO lumps at the optimized condition reveals mixed controlled mechanisms [initially contracting geometry (CG3) followed by diffusion (D3)]. Activation energies calculated are 69.895 KJ/mole for CG3 and 39.084 KJ/mole for D3. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_17");'>17</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li class="active">19</li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_20" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li class="active">20</li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="381"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5496733','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5496733">Artifact reduction in short-scan CBCT by use of optimization-based reconstruction</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Zhang, Zheng; Han, Xiao; Pearson, Erik; Pelizzari, Charles; Sidky, Emil Y; Pan, Xiaochuan 2017-01-01 Increasing interest in optimization-based reconstruction in research on, and applications of, cone-beam computed tomography (CBCT) exists because it has been shown to have to potential to reduce artifacts observed in reconstructions obtained with the Feldkamp–Davis–Kress (FDK) algorithm (or its variants), which is used extensively for image reconstruction in current CBCT applications. In this work, we carried out a study on optimization-based reconstruction for possible reduction of artifacts in FDK reconstruction specifically from short-scan CBCT data. The investigation includes a set of optimization programs such as the image-total-variation (TV)-constrained data-divergency minimization, data-weighting matrices such as the Parker weighting matrix, and objects of practical interest for demonstrating and assessing the degree of artifact reduction. Results of investigative work reveal that appropriately designed optimization-based reconstruction, including the image-TV-constrained reconstruction, can reduce significant artifacts observed in FDK reconstruction in CBCT with a short-scan configuration. PMID:27046218 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.C53A0835T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.C53A0835T">Biogeochemistry and Genetic Potential related to Denitrification of Heterotrophic Bacteria isolated from Lake Vida Cryobrine</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Trubl, G.; Kuhn, E.; Ichimura, A.; Fritsen, C. H.; Murray, A. E. 2012-12-01 Lake Vida, one of the largest lakes in McMurdo Dry Valleys, Antarctica, is a thick block of ice permeated by brine channels below 16 m that contain the highest levels of nitrous oxide (N2O) that have been reported from a terrestrial environment (86.6 ± 5.9 μM). The subzero -13.4oC brine (18% salinity) has an unusual geochemistry with high levels of iron, dissolved organic carbon, nitrate, and ammonium. A number of heterotrophic bacteria were cultivated from this unusual, extreme ecosystem that has been isolated for at least three thousand years. The aim of this research was to phylogenetically characterize the bacterial isolates (using 16S ribosomal RNA analysis) and investigate their denitrifying abilities and genetic potential related to key reactions in the denitrification cycle. Fifteen phylotypes were isolated from Lake Vida brine among three phyla: Gammaproteobacteria, Actinobacteria, and Firmicutes. Based on the 16S ribosomal RNA analysis, Marinobacter was the most abundant (56%) genus identified among the 57 isolates. The other isolates were related to the genera Psychrobacter, Exiguobacterium, Kocuria, and Microbacterium. Representatives of each phylotype were characterized and verified for: (1) Nitrate (NO3-) reduction to either N2O or dinitrogen (N2) by Gas Chromatography; (2) presence of the genes nirK or nirS for NO3- reduction and nosZ for nitric oxide (NO) reduction by polymerase chain reaction (PCR); and (3) growth response to salinity and temperature gradients. Thirty five of the Lake Vida isolates produced either N2O or N2 coupled to cell growth. All 57 isolates have grown across a 32°C temperature range (-10°C to 22°C) and 54 isolates were halotolerant bacteria (growing in 0% to 16% salinity), while the last three isolates were halophilic. Electron microscopy revealed membrane vesicles and extracellular polymeric substances (EPS) around the Lake Vida isolates, which may be a survival adaptation. Investigating the denitrification and other biogeochemical cycles of Lake Vida can help us comprehend the origin of the high levels of N2O in the brine, provide insight into the origin of the Lake and the culture collection established from this isolated cryoecosystem will be useful for future physiological and biogeochemical experimentation to explore the limits of life. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70039044','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70039044">Nutrient removal using biosorption activated media: preliminary biogeochemical assessment of an innovative stormwater infiltration basin</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> O'Reilly, Andrew M.; Wanielista, Martin P.; Chang, Ni-Bin; Xuan, Zhemin; Harris, Willie G. 2012-01-01 Soil beneath a stormwater infiltration basin receiving runoff from a 22.7 ha predominantly residential watershed in central Florida, USA, was amended using biosorption activated media (BAM) to study the effectiveness of this technology in reducing inputs of nitrogen and phosphorus to groundwater. The functionalized soil amendment BAM consists of a 1.0:1.9:4.1 mixture (by volume) of tire crumb (to increase sorption capacity), silt and clay (to increase soil moisture retention), and sand (to promote sufficient infiltration), which was applied to develop a prototype stormwater infiltration basin utilizing nutrient reduction and flood control sub-basins. Comparison of nitrate/chloride (NO3-/Cl-) ratios for the shallow groundwater indicate that prior to using BAM, NO3- concentrations were substantially influenced by nitrification or variations in NO3- input. In contrast, for the prototype basin utilizing BAM, NO3-/Cl- ratios indicate minor nitrification and NO3- losses with the exception of one summer sample that indicated a 45% loss. Biogeochemical indicators (denitrifier activity derived from real-time polymerase chain reaction and variations in major ions, nutrients, dissolved and soil gases, and stable isotopes) suggest NO3- losses are primarily attributable to denitrification, whereas dissimilatory nitrate reduction to ammonium is a minor process. Denitrification was likely occurring intermittently in anoxic microsites in the unsaturated zone, which was enhanced by increased soil moisture within the BAM layer and resultant reductions in surface/subsurface oxygen exchange that produced conditions conducive to increased denitrifier activity. Concentrations of total dissolved phosphorus and orthophosphate (PO43-) were reduced by more than 70% in unsaturated zone soil water, with the largest decreases in the BAM layer where sorption was the most likely mechanism for removal. Post-BAM PO43-/Cl- ratios for shallow groundwater indicate predominantly minor increases and decreases in PO43- with the exception of one summer sample that indicated a 50% loss. Differences in nutrient variations between the unsaturated zone and shallow groundwater may be the result of the intensity and duration of nutrient removal processes and mixing ratios with water that had not undergone significant chemical changes. Observed nitrogen and phosphorus losses demonstrate the potential, as well as future research needs to improve performance, of the prototype stormwater infiltration basin using BAM for providing passive, economical, stormwater nutrient-treatment technology to support green infrastructure. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1611004J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1611004J">Isotope biogeochemical assessment of natural biodegradation processes in open cast pit mining landscapes</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jeschke, Christina; Knöller, Kay; Koschorreck, Matthias; Ussath, Maria; Hoth, Nils 2014-05-01 In Germany, a major share of the energy production is based on the burning of lignite from open cast pit mines. The remediation and re-cultivation of the former mining areas in the Lusatian and Central German lignite mining district is an enormous technical and economical challenge. After mine closures, the surrounding landscapes are threatened by acid mine drainage (AMD), i.e. the acidification and mineralization of rising groundwater with metals and inorganic contaminants. The high content of sulfur (sulfuric acid, sulfate), nitrogen (ammonium) and iron compounds (iron-hydroxides) deteriorates the groundwater quality and decelerates sustainable development of tourism in (former) mining landscapes. Natural biodegradation or attenuation (NA) processes of inorganic contaminants are considered to be a technically low impact and an economically beneficial solution. The investigations of the stable isotope compositions of compounds involved in NA processes helps clarify the dynamics of natural degradation and provides specific informations on retention processes of sulfate and nitrogen-compounds in mine dump water, mine dump sediment, and residual pit lakes. In an active mine dump we investigated zones where the process of bacterial sulfate reduction, as one very important NA process, takes place and how NA can be enhanced by injecting reactive substrates. Stable isotopes signatures of sulfur and nitrogen components were examined and evaluated in concert with hydrogeochemical data. In addition, we delineated the sources of ammonium pollution in mine dump sediments and investigated nitrification by 15N-labeling techniques to calculate the limit of the conversion of harmful ammonium to nitrate in residual mining lakes. Ultimately, we provided an isotope biogeochemical assessment of natural attenuation of sulfate and ammonium at mine dump sites and mining lakes. Also, we estimated the risk potential for water in different compartments of the hydrological system. In laboratory experiments, we tested reactive materials that may speed up the process of bacterial sulfate reduction. In in-situ experiments, we quantified nitrification rates. Based on the results, we are able to suggest promising technical measures that enhance natural attenuation processes at mine dump site and in mining lakes. The natural water cycle in lignite mining landscapes is heavily impacted by human activities. Basically, nature is capable of cleaning itself to a certain extent after mining activities stopped. However, it is our responsibility to support biogeochemical processes to make them more efficient and more sustainable. Isotopic monitoring proved to be an excellent tool for assessing the relevance and performance of different re-cultivation measures for a positive long-term development of the water quality in large-scale aquatic systems affected by the impact of lignite mining. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2010AGUFM.H51D0937B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2010AGUFM.H51D0937B">Instream Attenuation of Nitrogen and Phosphorus in Non-Point Source Dominated Streams: Hydrologic and Biogeochemical Controls</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Bray, E. N.; Chen, X.; Keller, A. A. 2010-12-01 Non-point source inputs of total nitrogen (TN) and total phosphorus (TP) in rivers are the leading causes of water quality degradation in the United States (Turner and Rabalais, 2003; Broussard and Turner, 2009). Yet it remains a challenge to adequately quantify the relative role and influence of physical hydrological processes versus biogeochemical processes on the attenuation of TN and TP for individual river reaches. A watershed-scale study of instream dynamics and attenuation of TN and TP in northeastern U.S. headwater streams demonstrates that physical and hydrological processes exert greater control over nutrient removal than biogeochemical processes. To explore these interactions under various attenuation scenarios, we developed the watershed-scale model (WARMF) for 97 catchments to simulate watershed processes, hydrology, and diffuse source loads of nutrients. We simulated a hypothetical nutrient release at a rate of 1 kg/d of TN (50% as ammonium and 50% as nitrate) and TP (100% as phosphate) to predict response lengths of downstream catchments. Resulting attenuation factors are presented as the change in mean load at a given location, normalized to the change in the catchment in which the load is applied. Results indicate that for most catchments, the TN and TP load increase is attenuated from the stream within a few tens of kilometers. Fifty percent attenuation occurs across length scales ranging from a few hundreds of meters to kilometers if the load is introduced in the headwaters, indicating the most rapid nutrient removal occurs in the smallest headwater streams but generally decreases with distance downstream. There are some differences in the attenuation factors for TN and TP, although the pattern of attenuation is the same. Sensitivity analyses highlight five hydrological parameters of paramount importance to concentrations of N and P, namely precipitation, evaporation coefficients (magnitude and skewness), soil layer thickness, soil saturated moisture and soil hydraulic conductivity. These model parameters have a significant effect on the concentrations of nutrients, with TN exhibiting greater sensitivity. Further, attenuation results suggest that stream depth, flow regime, and density of agriculture in small headwater streams are potentially important controls to nutrient uptake and removal; i.e. during periods of low flow, dilution is reduced, attenuation length increases, and removal processes may be dominated by settling as opposed to biogeochemistry. Instream attenuation and model results can be used to assess 1) the scale and nature of best management practices which must be adopted to result in nutrient reductions, 2) the downstream distance at which load reductions will be effective, and 3) the hydrological characteristics of the river network which exert considerable influence on attenuation lengths and nutrient removal. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017E%26ES..100a2212C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017E%26ES..100a2212C">A Summary of Research on Energy Saving and Emission Reduction of Transportation</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cheng, Dongxiang; Wu, Lufen 2017-12-01 Road transport is an important part of transportation, and road in the field of energy-saving emission reduction is a very important industry. According to the existing problems of road energy saving and emission reduction, this paper elaborates the domestic and international research on energy saving and emission reduction from three aspects: road network optimization, pavement material and pavement maintenance. Road network optimization may be overlooked, and the research content is still relatively preliminary; pavement materials mainly from the asphalt pavement temperature mixed asphalt technology research; pavement maintenance technology development is relatively comprehensive. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=194985&keyword=reactive+AND+program&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=194985&keyword=reactive+AND+program&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">NIGHTHAWK - A Program for Modeling Saturated Batch and Column Experiments Incorporating Equilibrium and Kinetic Biogeochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> NIGHTHAWK simulates the fate and transport of biogeochemically reactive contaminants in the saturated subsurface. Version 1.2 supports batch and one- dimensional advective-dispersive-reactive transport involving a number of biogeochemical processes, including: microbially-mediate... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=308263&Lab=NERL&keyword=law&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=308263&Lab=NERL&keyword=law&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Spatial Distribution of Small Water Body Types across Indiana Ecoregions</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Due to their large numbers and biogeochemical activity, small water bodies (SWB), such as ponds and wetlands, can have substantial cumulative effects on hydrologic, biogeochemical, and biological processes; yet the spatial distributions of various SWB types are often unknown. Usi... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26992509','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26992509">DoE optimization of a mercury isotope ratio determination method for environmental studies.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Berni, Alex; Baschieri, Carlo; Covelli, Stefano; Emili, Andrea; Marchetti, Andrea; Manzini, Daniela; Berto, Daniela; Rampazzo, Federico 2016-05-15 By using the experimental design (DoE) technique, we optimized an analytical method for the determination of mercury isotope ratios by means of cold-vapor multicollector ICP-MS (CV-MC-ICP-MS) to provide absolute Hg isotopic ratio measurements with a suitable internal precision. By running 32 experiments, the influence of mercury and thallium internal standard concentrations, total measuring time and sample flow rate was evaluated. Method was optimized varying Hg concentration between 2 and 20 ng g(-1). The model finds out some correlations within the parameters affect the measurements precision and predicts suitable sample measurement precisions for Hg concentrations from 5 ng g(-1) Hg upwards. The method was successfully applied to samples of Manila clams (Ruditapes philippinarum) coming from the Marano and Grado lagoon (NE Italy), a coastal environment affected by long term mercury contamination mainly due to mining activity. Results show different extents of both mass dependent fractionation (MDF) and mass independent fractionation (MIF) phenomena in clams according to their size and sampling sites in the lagoon. The method is fit for determinations on real samples, allowing for the use of Hg isotopic ratios to study mercury biogeochemical cycles in complex ecosystems. Copyright © 2016 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011JGRG..116.1029S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011JGRG..116.1029S">Natural and drought scenarios in an east central Amazon forest: Fidelity of the Community Land Model 3.5 with three biogeochemical models</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Sakaguchi, Koichi; Zeng, Xubin; Christoffersen, Bradley J.; Restrepo-Coupe, Natalia; Saleska, Scott R.; Brando, Paulo M. 2011-03-01 Recent development of general circulation models involves biogeochemical cycles: flows of carbon and other chemical species that circulate through the Earth system. Such models are valuable tools for future projections of climate, but still bear large uncertainties in the model simulations. One of the regions with especially high uncertainty is the Amazon forest where large-scale dieback associated with the changing climate is predicted by several models. In order to better understand the capability and weakness of global-scale land-biogeochemical models in simulating a tropical ecosystem under the present day as well as significantly drier climates, we analyzed the off-line simulations for an east central Amazon forest by the Community Land Model version 3.5 of the National Center for Atmospheric Research and its three independent biogeochemical submodels (CASA', CN, and DGVM). Intense field measurements carried out under Large Scale Biosphere-Atmosphere Experiment in Amazonia, including forest response to drought from a throughfall exclusion experiment, are utilized to evaluate the whole spectrum of biogeophysical and biogeochemical aspects of the models. Our analysis shows reasonable correspondence in momentum and energy turbulent fluxes, but it highlights three processes that are not in agreement with observations: (1) inconsistent seasonality in carbon fluxes, (2) biased biomass size and allocation, and (3) overestimation of vegetation stress to short-term drought but underestimation of biomass loss from long-term drought. Without resolving these issues the modeled feedbacks from the biosphere in future climate projections would be questionable. We suggest possible directions for model improvements and also emphasize the necessity of more studies using a variety of in situ data for both driving and evaluating land-biogeochemical models. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23744573','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23744573">The impacts of climate change and human activities on biogeochemical cycles on the Qinghai-Tibetan Plateau.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Chen, Huai; Zhu, Qiuan; Peng, Changhui; Wu, Ning; Wang, Yanfen; Fang, Xiuqing; Gao, Yongheng; Zhu, Dan; Yang, Gang; Tian, Jianqing; Kang, Xiaoming; Piao, Shilong; Ouyang, Hua; Xiang, Wenhua; Luo, Zhibin; Jiang, Hong; Song, Xingzhang; Zhang, Yao; Yu, Guirui; Zhao, Xinquan; Gong, Peng; Yao, Tandong; Wu, Jianghua 2013-10-01 With a pace of about twice the observed rate of global warming, the temperature on the Qinghai-Tibetan Plateau (Earth's 'third pole') has increased by 0.2 °C per decade over the past 50 years, which results in significant permafrost thawing and glacier retreat. Our review suggested that warming enhanced net primary production and soil respiration, decreased methane (CH(4)) emissions from wetlands and increased CH(4) consumption of meadows, but might increase CH(4) emissions from lakes. Warming-induced permafrost thawing and glaciers melting would also result in substantial emission of old carbon dioxide (CO(2)) and CH(4). Nitrous oxide (N(2)O) emission was not stimulated by warming itself, but might be slightly enhanced by wetting. However, there are many uncertainties in such biogeochemical cycles under climate change. Human activities (e.g. grazing, land cover changes) further modified the biogeochemical cycles and amplified such uncertainties on the plateau. If the projected warming and wetting continues, the future biogeochemical cycles will be more complicated. So facing research in this field is an ongoing challenge of integrating field observations with process-based ecosystem models to predict the impacts of future climate change and human activities at various temporal and spatial scales. To reduce the uncertainties and to improve the precision of the predictions of the impacts of climate change and human activities on biogeochemical cycles, efforts should focus on conducting more field observation studies, integrating data within improved models, and developing new knowledge about coupling among carbon, nitrogen, and phosphorus biogeochemical cycles as well as about the role of microbes in these cycles. © 2013 John Wiley & Sons Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.3039B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.3039B">Multi-scale controls on spatial variability in river biogeochemical cycling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Blaen, Phillip; Kurz, Marie; Knapp, Julia; Mendoza-Lera, Clara; Lee-Cullin, Joe; Klaar, Megan; Drummond, Jennifer; Jaeger, Anna; Zarnetske, Jay; Lewandowski, Joerg; Marti, Eugenia; Ward, Adam; Fleckenstein, Jan; Datry, Thibault; Larned, Scott; Krause, Stefan 2016-04-01 Excessive nutrient concentrations are common in surface waters and groundwaters in agricultural catchments worldwide. Increasing geomorphological heterogeneity in river channels may help to attenuate nutrient pollution by facilitating water exchange fluxes with the hyporheic zone; a site of intense microbial activity where biogeochemical cycling rates can be high. However, the controls on spatial variability in biogeochemical cycling, particularly at scales relevant for river managers, are largely unknown. Here, we aimed to assess: 1) how differences in river geomorphological heterogeneity control solute transport and rates of biogeochemical cycling at sub-reach scales (102 m); and 2) the relative magnitude of these differences versus those relating to reach scale substrate variability (103 m). We used the reactive tracer resazurin (Raz), a weakly fluorescent dye that transforms to highly fluorescent resorufin (Rru) under mildly reducing conditions, as a proxy to assess rates of biogeochemical cycling in a lowland river in southern England. Solute tracer tests were conducted in two reaches with contrasting substrates: one sand-dominated and the other gravel-dominated. Each reach was divided into sub-reaches that varied in geomorphic complexity (e.g. by the presence of pool-riffle sequences or the abundance of large woody debris). Slug injections of Raz and the conservative tracer fluorescein were conducted in each reach during baseflow conditions (Q ≈ 80 L/s) and breakthrough curves monitored using in-situ fluorometers. Preliminary results indicate overall Raz:Rru transformation rates in the gravel-dominated reach were more than 50% higher than those in the sand-dominated reach. However, high sub-reach variability in Raz:Rru transformation rates and conservative solute transport parameters suggests small scale targeted management interventions to alter geomorphic heterogeneity may be effective in creating hotspots of river biogeochemical cycling and nutrient load attenuation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AGUFM.B31I..05B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AGUFM.B31I..05B">Water, Carbon, and Nutrient Cycling Following Insect-induced Tree Mortality: How Well Do Plot-scale Observations Predict Ecosystem-Scale Response?</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Brooks, P. D.; Barnard, H. R.; Biederman, J. A.; Borkhuu, B.; Edburg, S. L.; Ewers, B. E.; Gochis, D. J.; Gutmann, E. D.; Harpold, A. A.; Hicke, J. A.; Pendall, E.; Reed, D. E.; Somor, A. J.; Troch, P. A. 2011-12-01 Widespread tree mortality caused by insect infestations and drought has impacted millions of hectares across western North America in recent years. Although previous work on post-disturbance responses (e.g. experimental manipulations, fire, and logging) provides insight into how water and biogeochemical cycles may respond to insect infestations and drought, we find that the unique nature of these drivers of tree mortality complicates extrapolation to larger scales. Building from previous work on forest disturbance, we present a conceptual model of how temporal changes in forest structure impact the individual components of energy balance, hydrologic partitioning, and biogeochemical cycling and the interactions among them. We evaluate and refine this model using integrated observations and process modeling on multiple scales including plot, stand, flux tower footprint, hillslope, and catchment to identify scaling relationships and emergent patterns in hydrological and biogeochemical responses. Our initial results suggest that changes in forest structure at point or plot scales largely have predictable effects on energy, water, and biogeochemical cycles that are well captured by land surface, hydrological, and biogeochemical models. However, observations from flux towers and nested catchments suggest that both the hydrological and biogeochemical effects observed at tree and plot scales may be attenuated or exacerbated at larger scales. Compensatory processes are associated with attenuation (e.g. as transpiration decreases, evaporation and sublimation increase), whereas both attenuation and exacerbation may result from nonlinear scaling behavior across transitions in topography and ecosystem structure that affect the redistribution of energy, water, and solutes. Consequently, the effects of widespread tree mortality on ecosystem services of water supply and carbon sequestration will likely depend on how spatial patterns in mortality severity across the landscape affect large-scale hydrological partitioning. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013EnOp...45..719T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013EnOp...45..719T">New algorithms for optimal reduction of technical risks</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Todinov, M. T. 2013-06-01 The article features exact algorithms for reduction of technical risk by (1) optimal allocation of resources in the case where the total potential loss from several sources of risk is a sum of the potential losses from the individual sources; (2) optimal allocation of resources to achieve a maximum reduction of system failure; and (3) making an optimal choice among competing risky prospects. The article demonstrates that the number of activities in a risky prospect is a key consideration in selecting the risky prospect. As a result, the maximum expected profit criterion, widely used for making risk decisions, is fundamentally flawed, because it does not consider the impact of the number of risk-reward activities in the risky prospects. A popular view, that if a single risk-reward bet with positive expected profit is unacceptable then a sequence of such identical risk-reward bets is also unacceptable, has been analysed and proved incorrect. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=67340&Lab=NCER&keyword=nitrogen+AND+balance&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=67340&Lab=NCER&keyword=nitrogen+AND+balance&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">SEASONAL VARIATION IN THE BIOGEOCHEMICAL CYCLING OF SESTON IN GRAND TRAVERSE BAY, LAKE MICHIGAN. (R825151)</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> This study describes the biogeochemical cycling of seston in Grand Traverse Bay, Lake Michigan. Seston was characterized by carbon and nitrogen elemental and isotopic abundances. Fluorescence, temperature, light transmittance, and concentrations of dissolved inorganic nitrogen we... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=60995&keyword=ocean+AND+climate+AND+changes&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=60995&keyword=ocean+AND+climate+AND+changes&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">PHOTOREACTIONS IN SURFACE WATERS AND THEIR ROLE IN BIOGEOCHEMICAL CYCLES</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> During the past decade significant interest has developed in the influence of photochemical reactions on biogeochemical cycles in surface waters of lakes and the sea. A major portion of recent research on these photoreactions has focused on the colored component of dissolved org... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=216548&keyword=Two+AND+photon&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=216548&keyword=Two+AND+photon&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Understanding Biogeochemical Transformations Of Trace Elements In Multi Metal-Rich Geomaterials Under Stimulated Redox Conditions</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Natural and anthropogenic influences on hydrological conditions can induce periodic or long-term reduced conditions in geologic materials. Such conditions can cause significant impacts on biogeochemical processes of trace elements in subsurface or near surface environments. The... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=230278&Lab=NHEERL&keyword=evapotranspiration&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=230278&Lab=NHEERL&keyword=evapotranspiration&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Catchment hydro-biogeochemical response to climate change and future land-use</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> The potential interacting effects of climate change and future land-use on hydrological and biogeochemical dynamics rarely have been described at the catchment level and are difficult or impossible to capture through experimentation or observation alone. We apply a new model, Vi... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=214116&Lab=NHEERL&keyword=Post+AND+test+AND+pre+AND+test&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=214116&Lab=NHEERL&keyword=Post+AND+test+AND+pre+AND+test&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Catchment hydro-biogeochemical response to forest harvest intensity and spatial pattern</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> We apply a new model, Visualizing Ecosystems for Land Management Assessment (VELMA), to Watershed 10 (WS10) in the H.J. Andrews Experimental Forest to simulate the effects of harvest intensity and spatial pattern on catchment hydrological and biogeochemical processes. Specificall... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/1015325','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/1015325">Preface [to special section on recent Loch Vale Watershed research</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Baron, Jill S.; Williams, Mark W. 2000-01-01 Catchment-scale intensive and extensive research conducted over the last decade shows that our understanding of the biogeochemical and hydrologic processes in subalpine and alpine basins is not yet sufficiently mature to model and predict how biogeochemical transformations and surface water quality will change in response to climatic or human-driven changes in energy, water, and chemicals. A better understanding of these processes is needed for input to decision-making regulatory agencies and federal land managers. In recognition of this problem the National Research Council [1998] has identified as a critical research need an improved understanding of how global change will affect biogeochemical interactions with the hydrologic cycle and biogeochemical controls over the transport of water, nutrients, and materials from land to freshwater ecosystems. Improved knowledge of alpine and subalpine ecosystems is particularly important since high-elevation catchments are very sensitive to small changes in the flux of energy, chemicals, and water. Furthermore, alpine ecosystems may act as early warning indicators for ecosystem changes at lower elevations. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_18");'>18</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li class="active">20</li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_21" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li class="active">21</li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="401"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016ECSS..183..136S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016ECSS..183..136S">The role of forcing agents on biogeochemical variability along the southwestern Adriatic coast: The Gulf of Manfredonia case study</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Specchiulli, Antonietta; Bignami, Francesco; Marini, Mauro; Fabbrocini, Adele; Scirocco, Tommaso; Campanelli, Alessandra; Penna, Pierluigi; Santucci, Angela; D'Adamo, Raffaele 2016-12-01 This study investigates how multiple forcing factors such as rivers, surface marine circulation and winds affect hydrology and biogeochemical processes in the Gulf of Manfredonia and the seas around the Gargano peninsula, in the south-western Adriatic Sea. The study adopted an integrated approach, using in situ and remote sensing data, as well as the output of current models. The data reveal variability in the area's hydrography induced by local freshwater sources, the Western Adriatic Current (WAC) flowing from the north along the Italian coast, and the current patterns under different wind regimes. Specifically, exchange with offshore waters in the gulf induces variability in salinity and biogeochemical content, even within the same season, i.e. winter, in our case. This strong dependence on physical and biogeochemical factors makes the Manfredonia-Gargano ecosystem vulnerable to climate change, which could compromise its important role as a nursery area for the Adriatic Sea. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.B53D..03R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.B53D..03R">Integrating Environmental Genomics and Biogeochemical Models: a Gene-centric Approach</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Reed, D. C.; Algar, C. K.; Huber, J. A.; Dick, G. 2013-12-01 Rapid advances in molecular microbial ecology have yielded an unprecedented amount of data about the evolutionary relationships and functional traits of microbial communities that regulate global geochemical cycles. Biogeochemical models, however, are trailing in the wake of the environmental genomics revolution and such models rarely incorporate explicit representations of bacteria and archaea, nor are they compatible with nucleic acid or protein sequence data. Here, we present a functional gene-based framework for describing microbial communities in biogeochemical models that uses genomics data and provides predictions that are readily testable using cutting-edge molecular tools. To demonstrate the approach in practice, nitrogen cycling in the Arabian Sea oxygen minimum zone (OMZ) was modelled to examine key questions about cryptic sulphur cycling and dinitrogen production pathways in OMZs. By directly linking geochemical dynamics to the genetic composition of microbial communities, the method provides mechanistic insights into patterns and biogeochemical consequences of marine microbes. Such an approach is critical for informing our understanding of the key role microbes play in modulating Earth's biogeochemistry. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS43B2029D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS43B2029D">A hierarchy of ocean biogeochemical comprehensiveness for Earth System Modeling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dunne, J. P. 2016-12-01 As Earth System Models mature towards more quantitative explanations of ocean carbon cycle interactions and are applied to an increasingly diverse array of living marine resource communities, the draw towards biogeochemical and ecological comprehensiveness intensifies. However, this draw to comprehensiveness must also be balanced with the added cost of handling additional tracers. One way that GFDL has addressed this constraint is by developing a series of biogeochemical modules based on the 30 tracer TOPAZ formulation used in GFDL's CMIP5 contribution in both simplifying the biogeochemistry down to the 6 tracer BLING formulation and 3 tracer mini-BLING formulation, and in the other direction improving on ecosystem comprehensiveness with the 33 tracer COBALT formulation. We discuss the comparative advantages and disadvantages along this continuum of complexity in terms of both biogeochemical and ecological fidelity and applicability. We also discuss a related approach to separate out other modules for ideal age, 14C, CFCs, SF6, Argon and other tracer suites, allowing use to run an array of experimental designs to suite different needs. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19930007426','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19930007426">An optimization-based integrated controls-structures design methodology for flexible space structures</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Maghami, Peiman G.; Joshi, Suresh M.; Armstrong, Ernest S. 1993-01-01 An approach for an optimization-based integrated controls-structures design is presented for a class of flexible spacecraft that require fine attitude pointing and vibration suppression. The integrated design problem is posed in the form of simultaneous optimization of both structural and control design variables. The approach is demonstrated by application to the integrated design of a generic space platform and to a model of a ground-based flexible structure. The numerical results obtained indicate that the integrated design approach can yield spacecraft designs that have substantially superior performance over a conventional design wherein the structural and control designs are performed sequentially. For example, a 40-percent reduction in the pointing error is observed along with a slight reduction in mass, or an almost twofold increase in the controlled performance is indicated with more than a 5-percent reduction in the overall mass of the spacecraft (a reduction of hundreds of kilograms). </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/29205280','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/29205280">Maximizing neotissue growth kinetics in a perfusion bioreactor: An in silico strategy using model reduction and Bayesian optimization.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Mehrian, Mohammad; Guyot, Yann; Papantoniou, Ioannis; Olofsson, Simon; Sonnaert, Maarten; Misener, Ruth; Geris, Liesbet 2018-03-01 In regenerative medicine, computer models describing bioreactor processes can assist in designing optimal process conditions leading to robust and economically viable products. In this study, we started from a (3D) mechanistic model describing the growth of neotissue, comprised of cells, and extracellular matrix, in a perfusion bioreactor set-up influenced by the scaffold geometry, flow-induced shear stress, and a number of metabolic factors. Subsequently, we applied model reduction by reformulating the problem from a set of partial differential equations into a set of ordinary differential equations. Comparing the reduced model results to the mechanistic model results and to dedicated experimental results assesses the reduction step quality. The obtained homogenized model is 10 5 fold faster than the 3D version, allowing the application of rigorous optimization techniques. Bayesian optimization was applied to find the medium refreshment regime in terms of frequency and percentage of medium replaced that would maximize neotissue growth kinetics during 21 days of culture. The simulation results indicated that maximum neotissue growth will occur for a high frequency and medium replacement percentage, a finding that is corroborated by reports in the literature. This study demonstrates an in silico strategy for bioprocess optimization paying particular attention to the reduction of the associated computational cost. © 2017 Wiley Periodicals, Inc. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28983493','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28983493">Use of a channelized Hotelling observer to assess CT image quality and optimize dose reduction for iteratively reconstructed images.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Favazza, Christopher P; Ferrero, Andrea; Yu, Lifeng; Leng, Shuai; McMillan, Kyle L; McCollough, Cynthia H 2017-07-01 The use of iterative reconstruction (IR) algorithms in CT generally decreases image noise and enables dose reduction. However, the amount of dose reduction possible using IR without sacrificing diagnostic performance is difficult to assess with conventional image quality metrics. Through this investigation, achievable dose reduction using a commercially available IR algorithm without loss of low contrast spatial resolution was determined with a channelized Hotelling observer (CHO) model and used to optimize a clinical abdomen/pelvis exam protocol. A phantom containing 21 low contrast disks-three different contrast levels and seven different diameters-was imaged at different dose levels. Images were created with filtered backprojection (FBP) and IR. The CHO was tasked with detecting the low contrast disks. CHO performance indicated dose could be reduced by 22% to 25% without compromising low contrast detectability (as compared to full-dose FBP images) whereas 50% or more dose reduction significantly reduced detection performance. Importantly, default settings for the scanner and protocol investigated reduced dose by upward of 75%. Subsequently, CHO-based protocol changes to the default protocol yielded images of higher quality and doses more consistent with values from a larger, dose-optimized scanner fleet. CHO assessment provided objective data to successfully optimize a clinical CT acquisition protocol. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMED33G..01F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMED33G..01F">The Power of Storytelling: A Native Hawaiian Approach to Science Communication</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Frank, K. L. 2016-12-01 Generational assimilation of observational data enabled Native Hawaiians to preserve a holistic understanding of the connectivity, structure and function - from mountain to sea - within their island ecosystems. Their intimate understandings of the geographic and temporal variability in winds, rains, and currents, and how these factors governed the extent and distribution of biodiversity were perpetuated through stories, songs and chants. Many of these oral histories - which conveyed information via anthropomorphized characters in entertaining and engaging plots - preserved the scientific integrity of traditional phenomenological observations and remain shockingly consistent with contemporary biogeochemical and geophysical observations. These indigenous methods of communicating scientific knowledge are clear models for contemporary best practices in geoscience communication. Storytelling is a tried and true mechanism that both engages and teaches diverse audiences of all ages, ethnicities and skill levels. Scientific storytelling - which can either be examinations of indigenous stories through scientific lenses, or generations of new stories based on scientific observation - enables multiple layers of meaning and levels of knowledge acquisition that bridge cultural and historical place-based knowledge with contemporary knowledge systems. Here, I will share my journey of optimizing the engagement of Native Hawaiian communities (students, land managers, stewards, practitioners, etc…) with my biogeochemical research on a Native Hawaiian coastal estuarine environment (Héeia Fishpond). I will speak about the importance and effectiveness of disseminating research in culturally accessible formats by framing research in the context of traditional knowledge to help elevate the perception of "science" in the Hawaiian community. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26188990','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26188990">Spatial optimization of watershed management practices for nitrogen load reduction using a modeling-optimization framework.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Yang, Guoxiang; Best, Elly P H 2015-09-15 Best management practices (BMPs) can be used effectively to reduce nutrient loads transported from non-point sources to receiving water bodies. However, methodologies of BMP selection and placement in a cost-effective way are needed to assist watershed management planners and stakeholders. We developed a novel modeling-optimization framework that can be used to find cost-effective solutions of BMP placement to attain nutrient load reduction targets. This was accomplished by integrating a GIS-based BMP siting method, a WQM-TMDL-N modeling approach to estimate total nitrogen (TN) loading, and a multi-objective optimization algorithm. Wetland restoration and buffer strip implementation were the two BMP categories used to explore the performance of this framework, both differing greatly in complexity of spatial analysis for site identification. Minimizing TN load and BMP cost were the two objective functions for the optimization process. The performance of this framework was demonstrated in the Tippecanoe River watershed, Indiana, USA. Optimized scenario-based load reduction indicated that the wetland subset selected by the minimum scenario had the greatest N removal efficiency. Buffer strips were more effective for load removal than wetlands. The optimized solutions provided a range of trade-offs between the two objective functions for both BMPs. This framework can be expanded conveniently to a regional scale because the NHDPlus catchment serves as its spatial computational unit. The present study demonstrated the potential of this framework to find cost-effective solutions to meet a water quality target, such as a 20% TN load reduction, under different conditions. Copyright © 2015 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70187163','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70187163">The General Ensemble Biogeochemical Modeling System (GEMS) and its applications to agricultural systems in the United States: Chapter 18</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Liu, Shuguang; Tan, Zhengxi; Chen, Mingshi; Liu, Jinxun; Wein, Anne; Li, Zhengpeng; Huang, Shengli; Oeding, Jennifer; Young, Claudia; Verma, Shashi B.; Suyker, Andrew E.; Faulkner, Stephen P. 2012-01-01 The General Ensemble Biogeochemical Modeling System (GEMS) was es in individual models, it uses multiple site-scale biogeochemical models to perform model simulations. Second, it adopts Monte Carlo ensemble simulations of each simulation unit (one site/pixel or group of sites/pixels with similar biophysical conditions) to incorporate uncertainties and variability (as measured by variances and covariance) of input variables into model simulations. In this chapter, we illustrate the applications of GEMS at the site and regional scales with an emphasis on incorporating agricultural practices. Challenges in modeling soil carbon dynamics and greenhouse emissions are also discussed. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26275395','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26275395">Mercury mobilization and speciation linked to bacterial iron oxide and sulfate reduction: A column study to mimic reactive transfer in an anoxic aquifer.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Hellal, Jennifer; Guédron, Stéphane; Huguet, Lucie; Schäfer, Jörg; Laperche, Valérie; Joulian, Catherine; Lanceleur, Laurent; Burnol, André; Ghestem, Jean-Philippe; Garrido, Francis; Battaglia-Brunet, Fabienne 2015-09-01 Mercury (Hg) mobility and speciation in subsurface aquifers is directly linked to its surrounding geochemical and microbial environment. The role of bacteria on Hg speciation (i.e., methylation, demethylation and reduction) is well documented, however little data is available on their impact on Hg mobility. The aim of this study was to test if (i) Hg mobility is due to either direct iron oxide reduction by iron reducing bacteria (IRB) or indirect iron reduction by sulfide produced by sulfate reducing bacteria (SRB), and (ii) to investigate its subsequent fate and speciation. Experiments were carried out in an original column setup combining geochemical and microbiological approaches that mimic an aquifer including an interface of iron-rich and iron depleted zones. Two identical glass columns containing iron oxides spiked with Hg(II) were submitted to (i) direct iron reduction by IRB and (ii) to indirect iron reduction by sulfides produced by SRB. Results show that in both columns Hg was leached and methylated during the height of bacterial activity. In the column where IRB are dominant, Hg methylation and leaching from the column was directly correlated to bacterial iron reduction (i.e., Fe(II) release). In opposition, when SRB are dominant, produced sulfide induced indirect iron oxide reduction and rapid adsorption of leached Hg (or produced methylmercury) on neoformed iron sulfides (e.g., Mackinawite) or its precipitation as HgS. At the end of the SRB column experiment, when iron-oxide reduction was complete, filtered Hg and Fe concentrations increased at the outlet suggesting a leaching of Hg bound to FeS colloids that may be a dominant mechanism of Hg transport in aquifer environments. These experimental results highlight different biogeochemical mechanisms that can occur in stratified sub-surface aquifers where bacterial activities play a major role on Hg mobility and changes in speciation. Copyright © 2015 Elsevier B.V. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/12626273','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/12626273">Dust in the Earth system: the biogeochemical linking of land, air and sea.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Ridgwell, Andy J 2002-12-15 Understanding the response of the Earth's climate system to anthropogenic perturbation has been a pressing priority for society since the late 1980s. However, recent years have seen a major paradigm shift in how such an understanding can be reached. Climate change demands analysis within an integrated 'Earth-system' framework, taken to encompass the suite of interacting physical, chemical, biological and human processes that, in transporting and transforming materials and energy, jointly determine the conditions for life on the whole planet. This is a highly complex system, characterized by multiple nonlinear responses and thresholds, with linkages often between apparently disparate components. The interconnected nature of the Earth system is wonderfully illustrated by the diverse roles played by atmospheric transport of mineral 'dust', particularly in its capacity as a key pathway for the delivery of nutrients essential to plant growth, not only on land, but perhaps more importantly, in the ocean. Dust therefore biogeochemically links land, air and sea. This paper reviews the biogeochemical role of mineral dust in the Earth system and its interaction with climate, and, in particular, the potential importance of both past and possible future changes in aeolian delivery of the micro-nutrient iron to the ocean. For instance, if, in the future, there was to be a widespread stabilization of soils for the purpose of carbon sequestration on land, a reduction in aeolian iron supply to the open ocean would occur. The resultant weakening of the oceanic carbon sink could potentially offset much of the carbon sequestered on land. In contrast, during glacial times, enhanced dust supply to the ocean could have 'fertilized' the biota and driven atmospheric CO(2) lower. Dust might even play an active role in driving climatic change; since changes in dust supply may affect climate, and changes in climate, in turn, influence dust, a 'feedback loop' is formed. Possible feedback mechanisms are identified, recognition of whose operation could be crucial to our understanding of major climatic transitions over the past few million years. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMNS24A..04A','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMNS24A..04A">Magnetic susceptibility as a proxy for the hydrobiogeochemical cycling of iron within the water table fluctuation zone at hydrocarbon contaminated sites</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Atekwana, E. A.; Enright, A.; Atekwana, E. A.; Beaver, C. L.; Rossbach, S.; Slater, L. D.; Ntarlagiannis, D. 2016-12-01 Sharp redox gradients are indicative of enhanced biogeochemical activity and occur at or near the water table. Hydrologic forcing drives changes in redox state and oxygen levels, enhancing the elemental cycling of metals, and coupling different biogeochemical cycles. These coupled hydrobiogeochemical cycles are often difficult to study in the field using geochemical and microbial proxies because of direct sampling limitations, the costs associated with these techniques, and because the dynamic nature of these processes complicates the interpretation of single time point measurements, which may not give accurate representations of prevailing conditions. Geophysical techniques can provide both the spatial and temporal resolution needed to elucidate these processes. Here we investigated the use of magnetic susceptibility (c) as a viable proxy for understanding the biogeochemical cycling of iron at several hydrocarbon contaminated sites where active intrinsic bioremediation is occurring. We performed borehole c logging using a Bartington c probe in the field as well as made c measurements on core samples retrieved from the field sites. Our results show the following: (1) in both sulfate-rich and sulfate-poor aquifers, excursions in c are coincident with zones of free product contamination and are limited to the water table fluctuation (smear) zone; (2) c values within the free product plume and contamination source zones are higher compared to values within the dissolved product plume; (3) high c coincides with zones of elevated Fe (II) and Fe (III) concentrations extracted from aquifer solids; and (4) the mixed valence magnetite and greigite were the dominant magnetic minerals. The c excursions are limited to the water table fluctuation zones because fluctuating water level conditions are hot beds for microbial activity due to the steep hydrocarbon and nutrients and consequently redox gradients. High water levels during periods of recharge favor anaerobic conditions enhancing iron reduction, while low water conditions during drought periods favor iron oxidation due to increased oxygen penetration. Such conditions favor mixed valent iron minerals such as magnetite and greigite. We conclude that c measurements are a low cost, rapid monitoring tool for assessing the elemental cycling of iron. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..19.8619B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..19.8619B">Changing Atmospheric Acidity and the Oceanic Solubility of Nutrients</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Baker, Alex; Sarin, Manmohan; Duce, Robert; Jickells, Tim; Kanakidou, Maria; Myriokefalitakis, Stelios; Ito, Akinori; Turner, David; Mahowald, Natalie; Middag, Rob; Guieu, Cecile; Gao, Yuan; Croot, Peter; Shelley, Rachel; Perron, Morgane 2017-04-01 The atmospheric deposition of nutrients to the ocean is known to play a significant role in the marine carbon cycle. The impact of such deposition is dependent on the identity of the nutrient in question (e.g., N, P, Fe, Co, Zn, Ni, Cd), the location of the deposition, and the bioavailability of the deposited nutrient. Bioavailability is largely governed by the chemical speciation of a nutrient and, in general, insoluble species are not bioavailable. For Fe and P (and perhaps the other nutrient trace metals) solubility increases during transport through the atmosphere. The causes of this increase are complex, but interactions of aerosol particles with acids appears to play a significant role. Emissions of acidic (SO2 and NOx) and alkaline (NH3) gases have increased significantly since the Industrial Revolution, with a net increase in atmospheric acidity. This implies that Fe and P solubility may also have increased over this time period, potentially resulting in increased marine productivity. More recently, pollution controls have decreased emissions of SO2 from some regions and further reductions in SO2 and NOx are likely in the future. Emissions of NH3 are much more difficult to control however, and are projected to stabilise or increase slightly to the end of this century. Future anthropogenic emissions are thus likely to change the acidity of the atmosphere downwind of major urban / industrial centres, with potential consequences for the supply of soluble nutrients to the ocean. To address these issues UN/GESAMP Working Group 38, The Atmospheric Input of Chemicals to the Ocean, is convening a workshop on this topic at the University of East Anglia in February, 2017. The goals of this workshop are to review and synthesize the current scientific information on the solubility of aerosol-associated key biogeochemical elements, the biogeochemical controls on aerosol solubility, and the pH sensitivity of those controls; to consider the likely changes in solubility of key species into the future and the potential biogeochemical consequences of such changes; and to identify the key future research needs to reduce uncertainties in predictive capability in this area. The results, conclusions, and recommendations of this workshop will be presented. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMPP23B2325B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMPP23B2325B">The simulated climate of the Last Glacial Maximum and insights into the global carbon cycle.</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Buchanan, P. J.; Matear, R.; Lenton, A.; Phipps, S. J.; Chase, Z.; Etheridge, D. M. 2016-12-01 The ocean's ability to store large quantities of carbon, combined with the millennial longevity over which this reservoir is overturned, has implicated the ocean as a key driver of glacial-interglacial climates. However, the combination of processes that cause an accumulation of carbon within the ocean during glacial periods is still under debate. Here we present simulations of the Last Glacial Maximum (LGM) using the CSIRO Mk3L-COAL Earth System Model to test the contribution of key biogeochemical processes to ocean carbon storage. For the coupled LGM simulation, we find that significant cooling (3.2 °C), expanded minimum (Northern Hemisphere: 105 %; Southern Hemisphere: 225 %) and maximum (Northern Hemisphere: 145 %; Southern Hemisphere: 120 %) sea ice cover, and a reorganisation of the overturning circulation caused significant changes in ocean biogeochemical fields. The coupled LGM simulation stores an additional 322 Pg C in the deep ocean relative to the Pre-Industrial (PI) simulation. However, 839 Pg C is lost from the upper ocean via equilibration with a lower atmospheric CO2 concentration, causing a net loss of 517 Pg C relative to the PI simulation. The LGM deep ocean also experiences an oxygenation (>100 mmol O2 m-3) and deepening of the aragonite saturation depth (> 2,000 m deeper) at odds with proxy reconstructions. Hence, these physical changes cannot in isolation produce plausible biogeochemistry nor the required drawdown of atmospheric CO2 of 80-100 ppm at the LGM. With modifications to key biogeochemical processes, which include an increased export of organic matter due to a simulated release from iron limitation, a deepening of remineralisation and decreased inorganic carbon export driven by cooler temperatures, we find that the carbon content in the glacial oceanic reservoir can be increased (326 Pg C) to a level that is sufficient to explain the reduction in atmospheric and terrestrial carbon at the LGM (520 ± 400 Pg C). These modifications also go some way to reconcile simulated export production, aragonite saturation state and oxygen fields with those that have been reconstructed by proxy measurements, thereby implicating past changes in ocean biogeochemistry as an essential driver of the climate system. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015AGUFM.B11E0487F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015AGUFM.B11E0487F">Linking Nitrogen-Cycling Microbial Communities to Environmental Fluctuations and Biogeochemical Activity in a Large, Urban Estuary: the San Francisco Bay-Delta</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Francis, C. 2015-12-01 Nitrogen (N) availability is an important factor controlling productivity and thus carbon cycling in estuaries. The fate of N in estuaries depends on the activities of the microbes that carry out the N-cycle, which in turn depend on factors such as organic matter availability, dissolved inorganic N, salinity, oxygen, and temperature. Key microbial N transformations include nitrification (the aerobic oxidation of ammonia to nitrite and nitrate) and denitrification (the anaerobic reduction of nitrate to dinitrogen gas). While denitrification leads to N loss, nitrification is the only link between reduced N (produced by decomposition) and oxidized N (substrates for N loss processes), and both processes are known to produce nitrous oxide (N2O), a potent greenhouse gas. Understanding controls of N-cycling in the San Francisco Bay-Delta (SFBD)—the largest estuary on the west coast of North America—is particularly important, as this urban estuary is massively polluted with N, even compared to classic "eutrophic" systems. Interestingly, the SFBD has been spared the detrimental consequences of nutrient enrichment, largely due to high suspended sediment concentrations (and thus low light penetration) throughout the water column, combined with high grazing pressure. However, the recent "clearing" of SFBD waters due to a sharp decrease in suspended sediments may significantly alter the ecology of the estuary, by increasing phytoplankton growth. Thus, the SFBD may be losing its historical resilience to eutrophication, and may soon be "high-nutrient, low-chlorophyll" no more. Elucidating the environmental factors affecting the community structure, activity, and functioning of N-cycling microbes in SFBD is crucial for determining how changes in turbidity and productivity will be propagated throughout the ecosystem. While substantial ecological research in the SFBD has focused on phytoplankton and food webs, bacterial and archaeal communities have received far less attention. Using a combination of molecular, biogeochemical, and 'omics' approaches, we have been examining how N-cycling microbial communities throughout the SFBD change in relation to environmental fluctuations—a critical step in understanding how microbial populations drive biogeochemical cycling in this estuary. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4814501','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4814501">Methane Seep in Shallow-Water Permeable Sediment Harbors High Diversity of Anaerobic Methanotrophic Communities, Elba, Italy</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Ruff, S. Emil; Kuhfuss, Hanna; Wegener, Gunter; Lott, Christian; Ramette, Alban; Wiedling, Johanna; Knittel, Katrin; Weber, Miriam 2016-01-01 The anaerobic oxidation of methane (AOM) is a key biogeochemical process regulating methane emission from marine sediments into the hydrosphere. AOM is largely mediated by consortia of anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB), and has mainly been investigated in deep-sea sediments. Here we studied methane seepage at four spots located at 12 m water depth in coastal, organic carbon depleted permeable sands off the Island of Elba (Italy). We combined biogeochemical measurements, sequencing-based community analyses and in situ hybridization to investigate the microbial communities of this environment. Increased alkalinity, formation of free sulfide and nearly stoichiometric methane oxidation and sulfate reduction rates up to 200 nmol g-1 day-1 indicated the predominance of sulfate-coupled AOM. With up to 40 cm thickness the zones of AOM activity were unusually large and occurred in deeper sediment horizons (20–50 cm below seafloor) as compared to diffusion-dominated deep-sea seeps, which is likely caused by advective flow of pore water due to the shallow water depth and permeability of the sands. Hydrodynamic forces also may be responsible for the substantial phylogenetic and unprecedented morphological diversity of AOM consortia inhabiting these sands, including the clades ANME-1a/b, ANME-2a/b/c, ANME-3, and their partner bacteria SEEP-SRB1a and SEEP-SRB2. High microbial dispersal, the availability of diverse energy sources and high habitat heterogeneity might explain that the emission spots shared few microbial taxa, despite their physical proximity. Although the biogeochemistry of this shallow methane seep was very different to that of deep-sea seeps, their key functional taxa were very closely related, which supports the global dispersal of key taxa and underlines strong selection by methane as the predominant energy source. Mesophilic, methane-fueled ecosystems in shallow-water permeable sediments may comprise distinct microbial habitats due to their unique biogeochemical and physical characteristics. To link AOM phylotypes with seep habitats and to enable future meta-analyses we thus propose that seep environment ontology needs to be further specified. PMID:27065954 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/27065954','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/27065954">Methane Seep in Shallow-Water Permeable Sediment Harbors High Diversity of Anaerobic Methanotrophic Communities, Elba, Italy.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Ruff, S Emil; Kuhfuss, Hanna; Wegener, Gunter; Lott, Christian; Ramette, Alban; Wiedling, Johanna; Knittel, Katrin; Weber, Miriam 2016-01-01 The anaerobic oxidation of methane (AOM) is a key biogeochemical process regulating methane emission from marine sediments into the hydrosphere. AOM is largely mediated by consortia of anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB), and has mainly been investigated in deep-sea sediments. Here we studied methane seepage at four spots located at 12 m water depth in coastal, organic carbon depleted permeable sands off the Island of Elba (Italy). We combined biogeochemical measurements, sequencing-based community analyses and in situ hybridization to investigate the microbial communities of this environment. Increased alkalinity, formation of free sulfide and nearly stoichiometric methane oxidation and sulfate reduction rates up to 200 nmol g(-1) day(-1) indicated the predominance of sulfate-coupled AOM. With up to 40 cm thickness the zones of AOM activity were unusually large and occurred in deeper sediment horizons (20-50 cm below seafloor) as compared to diffusion-dominated deep-sea seeps, which is likely caused by advective flow of pore water due to the shallow water depth and permeability of the sands. Hydrodynamic forces also may be responsible for the substantial phylogenetic and unprecedented morphological diversity of AOM consortia inhabiting these sands, including the clades ANME-1a/b, ANME-2a/b/c, ANME-3, and their partner bacteria SEEP-SRB1a and SEEP-SRB2. High microbial dispersal, the availability of diverse energy sources and high habitat heterogeneity might explain that the emission spots shared few microbial taxa, despite their physical proximity. Although the biogeochemistry of this shallow methane seep was very different to that of deep-sea seeps, their key functional taxa were very closely related, which supports the global dispersal of key taxa and underlines strong selection by methane as the predominant energy source. Mesophilic, methane-fueled ecosystems in shallow-water permeable sediments may comprise distinct microbial habitats due to their unique biogeochemical and physical characteristics. To link AOM phylotypes with seep habitats and to enable future meta-analyses we thus propose that seep environment ontology needs to be further specified. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1391703-disturbed-subsurface-microbial-communities-follow-equivalent-trajectories-despite-different-structural-starting-points-microbial-community-succession-disturbance','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1391703-disturbed-subsurface-microbial-communities-follow-equivalent-trajectories-despite-different-structural-starting-points-microbial-community-succession-disturbance">Disturbed subsurface microbial communities follow equivalent trajectories despite different structural starting points: Microbial community succession and disturbance</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Handley, Kim M.; Wrighton, Kelly C.; Miller, Christopher S. 2014-04-18 Microbial community structure, and niche and neutral processes can all influence response to disturbance. Here, we provide experimental evidence for niche versus neutral and founding community effects during a bioremediation-related organic carbon disturbance. Subsurface sediment, partitioned into 22 flow-through columns, was stimulated in situ by the addition of acetate as a carbon and electron donor source. This drove the system into a new transient biogeochemical state characterized by iron reduction and enriched Desulfuromonadales, Comamonadaceae and Bacteroidetes lineages. After approximately 1 month conditions favoured sulfate reduction, and were accompanied by a substantial increase in the relative abundance of Desulfobulbus, Desulfosporosinus, Desulfitobacteriummore » and Desulfotomaculum. Two subsets of four to five columns each were switched from acetate to lactate amendment during either iron (earlier) or sulfate (later) reduction. Hence, subsets had significantly different founding communities. All lactate treatments exhibited lower relative abundances of Desulfotomaculum and Bacteroidetes, enrichments of Clostridiales and Psychrosinus species, and a temporal succession from highly abundant Clostridium sensu stricto to Psychrosinus. Regardless of starting point, lactate-switch communities followed comparable structural trajectories, whereby convergence was evident 9 to 16 days after each switch, and significant after 29 to 34 days of lactate addition. Results imply that neither the founding community nor neutral processes influenced succession following perturbation.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25412274','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25412274">Iron-mediated anaerobic oxidation of methane in brackish coastal sediments.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Egger, Matthias; Rasigraf, Olivia; Sapart, Célia J; Jilbert, Tom; Jetten, Mike S M; Röckmann, Thomas; van der Veen, Carina; Bândă, Narcisa; Kartal, Boran; Ettwig, Katharina F; Slomp, Caroline P 2015-01-06 Methane is a powerful greenhouse gas and its biological conversion in marine sediments, largely controlled by anaerobic oxidation of methane (AOM), is a crucial part of the global carbon cycle. However, little is known about the role of iron oxides as an oxidant for AOM. Here we provide the first field evidence for iron-dependent AOM in brackish coastal surface sediments and show that methane produced in Bothnian Sea sediments is oxidized in distinct zones of iron- and sulfate-dependent AOM. At our study site, anthropogenic eutrophication over recent decades has led to an upward migration of the sulfate/methane transition zone in the sediment. Abundant iron oxides and high dissolved ferrous iron indicate iron reduction in the methanogenic sediments below the newly established sulfate/methane transition. Laboratory incubation studies of these sediments strongly suggest that the in situ microbial community is capable of linking methane oxidation to iron oxide reduction. Eutrophication of coastal environments may therefore create geochemical conditions favorable for iron-mediated AOM and thus increase the relevance of iron-dependent methane oxidation in the future. Besides its role in mitigating methane emissions, iron-dependent AOM strongly impacts sedimentary iron cycling and related biogeochemical processes through the reduction of large quantities of iron oxides. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=19940007993&hterms=acidification+ocean&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3Dacidification%2Bocean','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=19940007993&hterms=acidification+ocean&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D40%26Ntt%3Dacidification%2Bocean">The effects of acid deposition on sulfate reduction and methane production in peatlands</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Murray, Georgia L.; Hines, Mark E.; Bayley, Suzanne E. 1992-01-01 Peatlands, as fens and bods, make up a large percentage of northern latitude terrestrial environments. They are organic rich and support an active community of anaerobic bacteria, such as methanogenic and sulfate-reducing bacteria. The end products of these microbial activities, methane and hydrogen sulfide, are important components in the global biogeochemical cycles of carbon and sulfur. Since these two bacterial groups compete for nutritional substrates, increases in sulfate deposition due to acid rain potentially can disrupt the balance between these processes leading to a decrease in methane production and emission. This is significant because methane is a potent greenhouse gas that effects the global heat balance. A section of Mire 239 in the Experimental Lakes Area, in Northwestern Ontario, was artificially acidified and rates of sulfate reduction and methane production were measured with depth. Preliminary results suggested that methane production was not affected immediately after acidification. However, concentrations of dissolved methane decreased and dissolved sulfide increased greatly after acidification and both took several days to recover. The exact mechanism for the decrease in methane was not determined. Analyses are under way which will be used to determine rates of sulfate reduction. These results will be available by Spring and will be discussed. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_19");'>19</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li class="active">21</li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_22" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li class="active">22</li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="421"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1613590C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1613590C">Early-diagenetic processes in marine mangrove sediments from Guadeloupe, French West Indies</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Crémière, Antoine; Sebilo, Mathieu; Strauss, Harald; Gros, Olivier; Laverman, Anniet M. 2014-05-01 Sediment and pore-water geochemistry were investigated in two short sediment cores from the Manche-à-eau lagoon (Guadeloupe, French Caribbean island) surrounded by mangroves trees. These sediments present high total organic carbon content, ranging between 10 to 18 % wt, mainly originating from mangrove litter fall. Oxygen is depleted in the first few millimetres of the sediment indicating active organic carbon degradation. Seawater sulphate is entirely consumed within the first 20 cm of the sediments and total organic carbon content decreases with depth pointing out that early-diagenetic degradation of organic matter occurs with sulphate reduction. Sulphide produced as the results of sulphate reduction partly reacts with detrital iron-bearing minerals and precipitates as pyrite which is consistent with high amounts of sulphur in the sediments (4-5 % wt). The sulphur isotopic composition (δ34S) of both dissolved sulphate and sulphide in pore-water increases with depth displaying a large apparent isotopic fractionation (Δ34S) between both species of 65-80o as a result of bacterial sulphate reduction. Scanning electron microscopy investigation reveals that a part of the carbonate alkalinity produced either by organic matter oxidation or anaerobic methane oxidation leads to authigenic carbonates precipitation. These results provide straightforward evidence that carbon and sulphur biogeochemical cycles are intimately governed by sedimentary microbial activity. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4295021','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4295021">Activity and phylogenetic diversity of sulfate-reducing microorganisms in low-temperature subsurface fluids within the upper oceanic crust</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Robador, Alberto; Jungbluth, Sean P.; LaRowe, Douglas E.; Bowers, Robert M.; Rappé, Michael S.; Amend, Jan P.; Cowen, James P. 2015-01-01 The basaltic ocean crust is the largest aquifer system on Earth, yet the rates of biological activity in this environment are unknown. Low-temperature (<100°C) fluid samples were investigated from two borehole observatories in the Juan de Fuca Ridge (JFR) flank, representing a range of upper oceanic basement thermal and geochemical properties. Microbial sulfate reduction rates (SRR) were measured in laboratory incubations with 35S-sulfate over a range of temperatures and the identity of the corresponding sulfate-reducing microorganisms (SRM) was studied by analyzing the sequence diversity of the functional marker dissimilatory (bi)sulfite reductase (dsrAB) gene. We found that microbial sulfate reduction was limited by the decreasing availability of organic electron donors in higher temperature, more altered fluids. Thermodynamic calculations indicate energetic constraints for metabolism, which together with relatively higher cell-specific SRR reveal increased maintenance requirements, consistent with novel species-level dsrAB phylotypes of thermophilic SRM. Our estimates suggest that microbially-mediated sulfate reduction may account for the removal of organic matter in fluids within the upper oceanic crust and underscore the potential quantitative impact of microbial processes in deep subsurface marine crustal fluids on marine and global biogeochemical carbon cycling. PMID:25642212 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24219167','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24219167">Dissimilatory reduction and transformation of ferrihydrite-humic acid coprecipitates.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Shimizu, Masayuki; Zhou, Jihai; Schröder, Christian; Obst, Martin; Kappler, Andreas; Borch, Thomas 2013-01-01 Organic matter (OM) is present in most terrestrial environments and is often found coprecipitated with ferrihydrite (Fh). Sorption or coprecipitation of OM with Fe oxides has been proposed to be an important mechanism for long-term C preservation. However, little is known about the impact of coprecipitated OM on reductive dissolution and transformation of Fe(III) (oxyhydr)oxides. Thus, we study the effect of humic acid (HA) coprecipitation on Fh reduction and secondary mineral formation by the dissimilatory Fe(III)-reducing bacterium Shewanella putrefaciens strain CN32. Despite similar crystal structure for all coprecipitates investigated, resembling 2-line Fh, the presence of coprecipitated HA resulted in lower specific surface areas. In terms of reactivity, coprecipitated HA resulted in slower Fh bioreduction rates at low C/Fe ratios (i.e., C/Fe ≤ 0.8), while high C/Fe ratios (i.e., C/Fe ≥ 1.8) enhanced the extent of bioreduction compared to pure Fh. The coprecipitated HA also altered the secondary Fe mineralization pathway by inhibiting goethite formation, reducing the amount of magnetite formation, and increasing the formation of a green rust-like phase. This study indicates that coprecipitated OM may influence the rates, pathway, and mineralogy of biogeochemical Fe cycling and anaerobic Fe respiration within soils. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=306030&Lab=NERL&keyword=erickson&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=306030&Lab=NERL&keyword=erickson&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Effects of Stratospheric Ozone Depletion, Solar UV Radiation, and Climate Change on Biogeochemical Cycling: Interactions and Feedbacks</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Climate change modulates the effects of solar UV radiation on biogeochemical cycles in terrestrial and aquatic ecosystems, particularly for carbon cycling, resulting in UV-mediated positive or negative feedbacks on climate. Possible positive feedbacks discussed in this assessment... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=116350&keyword=microbiota&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=116350&keyword=microbiota&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">INTERACTIONS OF CHANGING CLIMATE AND ULTRAVIOLET RADIATION IN AQUATIC AND TERRESTRIAL BIOGEOCHEMICAL CYCLES</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> During the past decade interest has developed in the interactive effects of climate change and UV radiation on aquatic and terrestrial biogeochemical cycles. This talk used selected case studies to illustrate approaches that are being used to investigate these intriguing processe... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/26778864','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/26778864">QUADRO: A SUPERVISED DIMENSION REDUCTION METHOD VIA RAYLEIGH QUOTIENT OPTIMIZATION.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Fan, Jianqing; Ke, Zheng Tracy; Liu, Han; Xia, Lucy We propose a novel Rayleigh quotient based sparse quadratic dimension reduction method-named QUADRO (Quadratic Dimension Reduction via Rayleigh Optimization)-for analyzing high-dimensional data. Unlike in the linear setting where Rayleigh quotient optimization coincides with classification, these two problems are very different under nonlinear settings. In this paper, we clarify this difference and show that Rayleigh quotient optimization may be of independent scientific interests. One major challenge of Rayleigh quotient optimization is that the variance of quadratic statistics involves all fourth cross-moments of predictors, which are infeasible to compute for high-dimensional applications and may accumulate too many stochastic errors. This issue is resolved by considering a family of elliptical models. Moreover, for heavy-tail distributions, robust estimates of mean vectors and covariance matrices are employed to guarantee uniform convergence in estimating non-polynomially many parameters, even though only the fourth moments are assumed. Methodologically, QUADRO is based on elliptical models which allow us to formulate the Rayleigh quotient maximization as a convex optimization problem. Computationally, we propose an efficient linearized augmented Lagrangian method to solve the constrained optimization problem. Theoretically, we provide explicit rates of convergence in terms of Rayleigh quotient under both Gaussian and general elliptical models. Thorough numerical results on both synthetic and real datasets are also provided to back up our theoretical results. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.V51A3032C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.V51A3032C">Biogeochemical Mg cycle in the Barton Peninsula, King George Island, West Antarctica</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Choi, H. B.; Ryu, J. S.; Lee, J.; Lim, H. S.; Yoon, H. 2016-12-01 Understanding of biogeochemical Mg cycle is important in terms of plant growth as well as global climate because Mg participates in numerous biogeochemical processes. Here, we collected rock, soil, water and moss samples in the Barton peninsula, King George Island, West Antarctica, and measured their elemental and Mg isotope compositions in order to quantify and understand the biogeochemical processes of the Mg cycle. Elemental results show that the input of seawater derived Mg mainly controls dissolved Mg in meltwater. Mg isotope compositions in rocks and soils are consistent within the error, -0.03 ± 0.15‰ (n=6) and +0.03 ± 0.07‰ (n=8), respectively. However, δ26Mg values of meltwater and moss are -0.69 ± 0.09‰ (n=34) and -0.46 ± 0.19‰ (n=16), respectively, indicating that mosses display higher δ26Mg values compared to meltwater they uptake. This implies an isotope fractionation in favor of heavy isotopes during moss growth. The apparent Mg isotope fractionation between moss and meltwater (Δ26Mgmoss-meltwater) ranges from 0.02‰ to 0.55‰, with an average of +0.29‰ (n=6), which is within the range previously reported during higher plant growth. Our finding suggests that enhanced plant growth in Arctic and Antarctica due to climate change and global warming may play an important role in the biogeochemical Mg cycle globally. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1910523S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1910523S">Flow characteristics control turnover of polar trace organic compounds in the hyporheic zone of an urban lowland river</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Schaper, Jonas L.; Seher, Wiebke; Jaeger, Anna; Galloway, Jason; Nuetzmann, Gunnar; Putschew, Anke; Lewandowski, Joerg 2017-04-01 Hyporheic zones are hypothesized to be important sinks for polar trace organic compounds (TrOCs) in lotic systems, mitigating potential adverse effects of TrOCs on ecosystem functioning and drinking water production. Predicting the fate of TrOCs in the hyporheic zone, however, is difficult as the attenuation rate itself as well as the biogeochemical factors and hydrological conditions controlling attenuation rates are unknown. We used time series of temperature depth profiles as well as heat pulse sensing with a 1D advection dispersion transport model to calculate first order attenuation rates of several TrOCs from equilibrium depth profiles in an urban lowland river in Berlin, Germany. Ring enclosures were used to prohibit horizontal flow and to create distinct biogeochemical conditions within the hyporheic zone. Flow characteristics as well as biogeochemical conditions showed pronounced differences between depth profiles inside and outside of enclosures. TrOCs attenuation rates varied considerably among compounds reflecting their general susceptibility to biodegradation and sorption. While for some compounds such as benzotriazole and sulfamethoxazole redox conditions had an influence on attenuation rates, the fate of other compounds was not affected by biogeochemical parameters. Under loosing conditions, hyporheic zones of urban lowland rivers can thus be regarded as sinks for TrOCs. Their effectiveness is dependent on both, hyporheic exchange characteristics as well as biogeochemical parameters. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/28392240','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/28392240">Effect of home construction on soil carbon storage-A chronosequence case study.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Majidzadeh, Hamed; Lockaby, B Graeme; Governo, Robin 2017-07-01 Urbanization results in the rapid expansion of impervious surfaces, therefore a better understanding of biogeochemical consequences of soil sealing is crucial. Previous research documents a significant reduction in soil carbon and nitrogen content, however, it is unclear if this decrease is a result of top soil removal or long-term soil sealing. In this study, soil biogeochemical properties were quantified beneath homes built on a crawl space at two depths (0-10 cm, and 10-20 cm). All homes, 11-114 years in age, were sampled in the Piedmont region of Alabama and Georgia, USA. This age range enabled the use of a chronosequence approach to estimate carbon loss or gain under the sampled homes. The difference in soil carbon content beneath homes and adjoining urban lawns showed a quadratic relation with age. Maximum C loss occurred at approximately fifty years. The same pattern was observed for MBC: C ratio suggesting that the soil carbon content was decreasing beneath the homes for first fifty years, then increased afterward. The average soil C and N content in the top 10 cm were respectively 61.86% (±4.42%), and 65.77% (±5.65%) lower underneath the homes in comparison to urban lawns. Microbial biomass carbon (MBC), and nitrogen (MBN) were significantly lower below the homes compared to the urban lawns, while bulk density and phosphorus content were higher beneath the homes. Copyright © 2017 Elsevier Ltd. All rights reserved. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/23630015','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/23630015">Winter climate change effects on soil C and N cycles in urban grasslands.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Durán, Jorge; Rodríguez, Alexandra; Morse, Jennifer L; Groffman, Peter M 2013-09-01 Despite growing recognition of the role that cities have in global biogeochemical cycles, urban systems are among the least understood of all ecosystems. Urban grasslands are expanding rapidly along with urbanization, which is expected to increase at unprecedented rates in upcoming decades. The large and increasing area of urban grasslands and their impact on water and air quality justify the need for a better understanding of their biogeochemical cycles. There is also great uncertainty about the effect that climate change, especially changes in winter snow cover, will have on nutrient cycles in urban grasslands. We aimed to evaluate how reduced snow accumulation directly affects winter soil frost dynamics, and indirectly greenhouse gas fluxes and the processing of carbon (C) and nitrogen (N) during the subsequent growing season in northern urban grasslands. Both artificial and natural snow reduction increased winter soil frost, affecting winter microbial C and N processing, accelerating C and N cycles and increasing soil : atmosphere greenhouse gas exchange during the subsequent growing season. With lower snow accumulations that are predicted with climate change, we found decreases in N retention in these ecosystems, and increases in N2 O and CO2 flux to the atmosphere, significantly increasing the global warming potential of urban grasslands. Our results suggest that the environmental impacts of these rapidly expanding ecosystems are likely to increase as climate change brings milder winters and more extensive soil frost. © 2013 John Wiley & Sons Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25149868','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25149868">δ34S and δ18O of dissolved sulfate as biotic tracer of biogeochemical influences on arsenic mobilization in groundwater in the Hetao Plain, Inner Mongolia, China.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Li, M D; Wang, Y X; Li, P; Deng, Y M; Xie, X J 2014-12-01 Environmental isotopology of sulfur and oxygen of dissolved sulfate in groundwater was conducted in the Hetao Plain, northwestern China, aiming to better understand the processes controlling arsenic mobilization in arsenic-rich aqueous systems. A total of 22 groundwater samples were collected from domestic wells in the Hetao Plain. Arsenic concentrations ranged from 11.0 to 388 μg/L. The δ(34)S-SO4 and δ(18)O-SO4 values of dissolved sulfate covered a range from +1.48 to +22.4‰ and +8.17‰ to +14.8‰ in groundwater, respectively. The wide range of δ(34)S-SO4 values reflected either an input of different sources of sulfate, such as gypsum dissolution and fertilizer application, or a modification from biogeochemical process of bacterial sulfate reduction. The positive correlation between δ(34)S-SO4 and arsenic concentrations suggested that bacteria mediated processes played an important role in the mobilization of arsenic. The δ(18)O-SO4 values correlated non-linearly with δ(34)S-SO4, but within a relatively narrow range (+8.17 to +14.8‰), implying that complexities inherent in the sulfate-oxygen (O-SO4(2-)) origins, for instance, water-derived oxygen (O-H2O), molecular oxygen (O-O2) and isotope exchanging with dissolved oxides, are accounted for oxygen isotope composition of dissolved sulfate in groundwater in the Hetao Plain. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/16104853','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/16104853">Communities of nirS-type denitrifiers in the water column of the oxygen minimum zone in the eastern South Pacific.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Castro-González, Maribeb; Braker, Gesche; Farías, Laura; Ulloa, Osvaldo 2005-09-01 The major sites of water column denitrification in the ocean are oxygen minimum zones (OMZ), such as one in the eastern South Pacific (ESP). To understand the structure of denitrifying communities in the OMZ off Chile, denitrifier communities at two sites in the Chilean OMZ (Antofagasta and Iquique) and at different water depths were explored by terminal restriction fragment length polymorphism analysis and cloning of polymerase chain reaction (PCR)-amplified nirS genes. NirS is a functional marker gene for denitrification encoding cytochrome cd1-containing nitrite reductase, which catalyses the reduction of nitrite to nitric oxide, the key step in denitrification. Major differences were found between communities from the two geographic locations. Shifts in community structure occurred along a biogeochemical gradient at Antofagasta. Canonical correspondence analysis indicated that O2, NO3-, NO2- and depth were important environmental factors governing these communities along the biogeochemical gradient in the water column. Phylogenetic analysis grouped the majority of clones from the ESP in distinct clusters of genes from presumably novel and yet uncultivated denitrifers. These nirS clusters were distantly related to those found in the water column of the Arabian Sea but the phylogenetic distance was even higher compared with environmental sequences from marine sediments or any other habitat. This finding suggests similar environmental conditions trigger the development of denitrifiers with related nirS genotypes despite large geographic distances. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS51A2020S','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS51A2020S">Distribution and Magnitude of Dinitrogen Fixation in the Eastern Tropical North Pacific Oxygen Deficient Zone.</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Selden, C.; Mulholland, M. R.; Widner, B.; Bernhardt, P. W.; Macías Tapia, A.; Jayakumar, A. 2016-12-01 The Eastern Tropical North Pacific Ocean (ETNP) hosts one of the world's three major open ocean oxygen deficient zones (ODZs). Hotspots for fixed nitrogen (N) loss processes, ODZs have classically been discounted as areas of significant dinitrogen (N2) fixation, the microbe-mediated reduction of N2 to ammonium (NH4+), which has historically been ascribed primarily to euphotic, nutrient-deplete tropical waters. Challenging this paradigm, active expression of nifH (the dinitrogen reductase structural gene) has recently been documented in the ETNP, Eastern Tropical South Pacific, and Arabian Sea ODZs, implying a closer coupling of fixed nitrogen input and loss processes than previously thought. Here, we report rates of N2 fixation measured in the ETNP ODZ along vertical gradients of oxygen, light, and dissolved N concentrations. Detailed vertical profiles of N2 fixation rates and dissolved N concentrations made within the ODZ were compared with similar profiles from oxic waters outside the ODZ. In addition, different organic carbon sources were investigated as potential rate-limiting factors for N2 fixation in sub-euphotic waters. By establishing the magnitude and distribution of N2 fixation in the ETNP ODZ, this study contributes to current understanding of N cycling in anoxic and aphotic waters, and serves to elucidate nuances in the global N budget, enabling more accurate biogeochemical modeling. Understanding these processes in present day ODZs is crucial for predicting how ongoing anthropogenic intensification of coastal ODZs will alter biogeochemical cycles in the future. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFM.B31G0543C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFM.B31G0543C">Soil-atmosphere N2O and CH4 exchanges was suppressed by litter layer in a subtropical secondary forest</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cui, J. J.; Lai, D. Y. F. 2016-12-01 Forest soil has a great potential in affecting future climate change through biogeochemical cycling and exchanging greenhouse gases (GHGs) with the atmosphere. As a proxy of changing atmospheric CO2 concentration, enhanced litter production arising from CO2 fertilization can affect soil GHG fluxes and induce feedbacks to the climate system. However, these litter-soil- atmosphere interactions remain unclear, especially in subtropical forests. In this study, we carried out static chamber measurements and field manipulations in a subtropical secondary forest in Hong Kong over one year to investigate the temporal variations and controls, as well as the effects of changing litter amounts on soil-atmosphere GHG fluxes. Our results show distinct seasonal pattern of GHG fluxes and soil parameters over the study period. While CO2 flux did not respond significantly to litter manipulation, regression analysis indicates that CO2 flux was regulated by soil temperature and soil moisture. Litter reduction stimulated mean N2O emissions by 105%, and the positive effect was most pronounced during the hot-humid season from May to October. On the other hand, litter addition was found to reduce CH4 uptake by 32%. Our findings suggest that the presence of litter might serve a physical barrier for gas diffusion. It is suggested that the biogeochemical feedback arising from litterfall should be taken into account in simulating the response of forest GHG fluxes to future global change. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.4594G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.4594G">Greenhouse gas emissions and N turnover along an altitudinal gradient at Mt. Kilimanjaro, Tanzania.</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Gütlein, Adrian; Gerschlauer, Friederike; Zistl-Schlingmann, Marcus; Dannenmann, Michael; Meier, Rudolf; Kolar, Alison; Butterbach-Bahl, Klaus; Kiese, Ralf 2016-04-01 Worldwide climate and land-use change force alterations in various ecosystem properties and functions such as diversity and activity of soil microbial communities which are responsible for biogeochemical processes like soil nitrogen (N) turnover and associated greenhouse gas (GHG) exchange. Tropical deforestation is highest in Africa and despite the importance of those ecosystems to global climate and biogeochemical cycles, data for greenhouse gas exchange is still rare (Serca et al., 1994, Werner et al., 2007) and no study regarding N turnover processes has been published yet. For that reason, we focused on seven different land-use types extending along an altitudinal gradient (950 -- 3880m) at Mt. Kilimanjaro, East Africa, covering (semi-) natural savanna, two montane forests and one afro alpine ecosystem, an extensive agroforest (homegarden) and an intensively managed coffee plantation. On all ecosystems we measured CO_2, CH4 and N_2O fluxes and gross rates of ammonification, nitrification, N immobilization, and dissimilatory nitrate reduction to ammonium (DNRA). GHG results reveal pronounced N_2O fluxes depending mainly on soil moisture and to a lesser extent on soil temperature. Emissions are highest during the rainy seasons while lowest at dry season conditions. The largest N_2O emissions are recognizable at Ocotea forest, most likely due to the generally higher SOC/ totN and wetter conditions favoring formation and emission of N_2O via denitrification. Soils of the studied ecosystems were a sink of atmospheric CH </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/20000030743','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/20000030743">Nontangent, Developed Contour Bulkheads for a Single-Stage Launch Vehicle</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Wu, K. Chauncey; Lepsch, Roger A., Jr. 2000-01-01 Dry weights for single-stage launch vehicles that incorporate nontangent, developed contour bulkheads are estimated and compared to a baseline vehicle with 1.414 aspect ratio ellipsoidal bulkheads. Weights, volumes, and heights of optimized bulkhead designs are computed using a preliminary design bulkhead analysis code. The dry weights of vehicles that incorporate the optimized bulkheads are predicted using a vehicle weights and sizing code. Two optimization approaches are employed. A structural-level method, where the vehicle's three major bulkhead regions are optimized separately and then incorporated into a model for computation of the vehicle dry weight, predicts a reduction of4365 lb (2.2 %) from the 200,679-lb baseline vehicle dry weight. In the second, vehicle-level, approach, the vehicle dry weight is the objective function for the optimization. For the vehicle-level analysis, modified bulkhead designs are analyzed and incorporated into the weights model for computation of a dry weight. The optimizer simultaneously manipulates design variables for all three bulkheads to reduce the dry weight. The vehicle-level analysis predicts a dry weight reduction of 5129 lb, a 2.6% reduction from the baseline weight. Based on these results, nontangent, developed contour bulkheads may provide substantial weight savings for single stage vehicles. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19930001794','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19930001794">Maximum life spiral bevel reduction design</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Savage, M.; Prasanna, M. G.; Coe, H. H. 1992-01-01 Optimization is applied to the design of a spiral bevel gear reduction for maximum life at a given size. A modified feasible directions search algorithm permits a wide variety of inequality constraints and exact design requirements to be met with low sensitivity to initial values. Gear tooth bending strength and minimum contact ratio under load are included in the active constraints. The optimal design of the spiral bevel gear reduction includes the selection of bearing and shaft proportions in addition to gear mesh parameters. System life is maximized subject to a fixed back-cone distance of the spiral bevel gear set for a specified speed ratio, shaft angle, input torque, and power. Significant parameters in the design are: the spiral angle, the pressure angle, the numbers of teeth on the pinion and gear, and the location and size of the four support bearings. Interpolated polynomials expand the discrete bearing properties and proportions into continuous variables for gradient optimization. After finding the continuous optimum, a designer can analyze near optimal designs for comparison and selection. Design examples show the influence of the bearing lives on the gear parameters in the optimal configurations. For a fixed back-cone distance, optimal designs with larger shaft angles have larger service lives. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015HESS...19.3557C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015HESS...19.3557C">Improving multi-objective reservoir operation optimization with sensitivity-informed dimension reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chu, J.; Zhang, C.; Fu, G.; Li, Y.; Zhou, H. 2015-08-01 This study investigates the effectiveness of a sensitivity-informed method for multi-objective operation of reservoir systems, which uses global sensitivity analysis as a screening tool to reduce computational demands. Sobol's method is used to screen insensitive decision variables and guide the formulation of the optimization problems with a significantly reduced number of decision variables. This sensitivity-informed method dramatically reduces the computational demands required for attaining high-quality approximations of optimal trade-off relationships between conflicting design objectives. The search results obtained from the reduced complexity multi-objective reservoir operation problems are then used to pre-condition the full search of the original optimization problem. In two case studies, the Dahuofang reservoir and the inter-basin multi-reservoir system in Liaoning province, China, sensitivity analysis results show that reservoir performance is strongly controlled by a small proportion of decision variables. Sensitivity-informed dimension reduction and pre-conditioning are evaluated in their ability to improve the efficiency and effectiveness of multi-objective evolutionary optimization. Overall, this study illustrates the efficiency and effectiveness of the sensitivity-informed method and the use of global sensitivity analysis to inform dimension reduction of optimization problems when solving complex multi-objective reservoir operation problems. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.H31I1232P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.H31I1232P">Effect of land tenure and stakeholders attitudes on optimization of conservation practices in agricultural watersheds</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Piemonti, A. D.; Babbar-Sebens, M.; Luzar, E. J. 2012-12-01 Modeled watershed management plans have become valuable tools for evaluating the effectiveness and impacts of conservation practices on hydrologic processes in watersheds. In multi-objective optimization approaches, several studies have focused on maximizing physical, ecological, or economic benefits of practices in a specific location, without considering the relationship between social systems and social attitudes on the overall optimality of the practice at that location. For example, objectives that have been commonly used in spatial optimization of practices are economic costs, sediment loads, nutrient loads and pesticide loads. Though the benefits derived from these objectives are generally oriented towards community preferences, they do not represent attitudes of landowners who might operate their land differently than their neighbors (e.g. farm their own land or rent the land to someone else) and might have different social/personal drivers that motivate them to adopt the practices. In addition, a distribution of such landowners could exist in the watershed, leading to spatially varying preferences to practices. In this study we evaluated the effect of three different land tenure types on the spatial-optimization of conservation practices. To perform the optimization, we used a uniform distribution of land tenure type and a spatially varying distribution of land tenure type. Our results show that for a typical Midwestern agricultural watershed, the most optimal solutions (i.e. highest benefits for minimum economic costs) found were for a uniform distribution of landowners who operate their own land. When a different land-tenure was used for the watershed, the optimized alternatives did not change significantly for nitrates reduction benefits and sediment reduction benefits, but were attained at economic costs much higher than the costs of the landowner who farms her/his own land. For example, landowners who rent to cash-renters would have to spend ~120% higher costs than landowners who operate their own land, to attain the same benefits. We also tested the effect of different social attitudes on the final preferences of the optimized alternatives and its consequences over the total effectiveness of the standard optimization approaches. The results suggest that, for example, when practices were removed from the system due to landowners' attitudes driven by economic profits, then the modified alternatives experienced a decrease in nitrates reduction by 2-50%, and decrease in peak flow reductions by 11-98 %, and decrease in sediments reduction by 20-77%. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/biblio/1047356-thermodynamics-electron-flow-bacterial-deca-heme-cytochrome-mtrf','SCIGOV-STC'); return false;" href="https://www.osti.gov/biblio/1047356-thermodynamics-electron-flow-bacterial-deca-heme-cytochrome-mtrf">Thermodynamics of Electron Flow in the Bacterial Deca-heme Cytochrome MtrF</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Breuer, Marian; Zarzycki, Piotr P.; Blumberger, Jochen 2012-07-01 Electron transporting multiheme cytochromes are essential to the metabolism of microbes that inhabit soils and carry out important biogeochemical processes. Recently the first crystal structure of a prototype bacterial deca-heme cytochrome (MtrF) has been resolved and its electrochemistry characterized. However, the molecular details of electron conductance along heme chains in the cytochrome are difficult to access via experiment due to the nearly identical chemical nature of the heme cofactors. Here we employ large-scale molecular dynamics simulations to compute the reduction potentials of the ten hemes of MtrF in aqueous solution. We find that as a whole they fall within amore » range of about 0.3 V in agreement with experiment. Individual reduction potentials give rise to a free energy profile for electron conduction that is approximately symmetric with respect to the center of the protein. Our calculations indicate that there is no significant potential bias along the orthogonal octa- and tetra-heme chains suggesting that under aqueous conditions MtrF is a nearly reversible two-dimensional conductor.« less </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_20");'>20</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li class="active">22</li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_23" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li class="active">23</li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="441"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUFMOS43B2049T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUFMOS43B2049T">Mechanisms and detectability of oxygen depletion in the North Atlantic</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tjiputra, J. F.; Goris, N.; Lauvset, S. K.; Schwinger, J. 2016-12-01 Dissolved oxygen is a key tracer in models used to represent the tight interaction between ocean biogeochemical cycle and circulation. Future ocean warming and stratification are projected, leading to a reduced oxygen concentration. Reduction in export production, in contrast, is projected to increase subsurface concentration by lowering the oxygen consumption during organic matter remineralization. In this exercise, we use a suite of CMIP5 models to study the oxygen evolution under the RCP8.5 scenario focusing on the North Atlantic, a region of rapid and steady circulation change. Most models agree with a large reduction in the deep North Atlantic (north of 40N), whereas an increase is projected in the upper subtropical ocean region. We attribute the former to weakening of the net primary production due to stronger stratification and the latter to less air-sea oxygen flux owing to less ventilation. The models also show that interior oxygen could provide earlier indicator of climate change than surface tracers. Sustained observation of oxygen is therefore crucial to reaffirm the ongoing circulation change due to global warming. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2012AGUFM.B11A0399B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2012AGUFM.B11A0399B">Genomic and Physiological Characterization of the Chromate-Reducing, Aquifer-Derived Firmicute Pelosinus sp. Strain HCF1</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Beller, H. R.; Han, R.; Karaoz, U.; Lim, H.; Brodie, E. L. 2012-12-01 Pelosinus species are fermentative firmicutes that were recently reported to be prominent members of microbial communities at contaminated subsurface sites in multiple locations. Here we report metabolic characteristics and their putative genetic basis in Pelosinus sp. strain HCF1, an isolate that predominated anaerobic, Cr(VI)-reducing columns constructed with Hanford 100H aquifer sediment (constituting 80% of the total bacterial population in the columns). Strain HCF1 ferments lactate to propionate and acetate (a complete fermentation pathway was identified in the genome) and its genome encodes both [NiFe]- and [FeFe]-hydrogenases for H2 cycling. This bacterium has unexpected capabilities and gene content associated with reduction of nitrogen oxides. In this strain, either H2 or lactate can act as a sole electron donor for nitrate, Cr(VI), and Fe(III) reduction. Transcriptional studies demonstrated differential expression of nitrate reductases and hydrogenases. Overall, the unexpected metabolic capabilities and gene content reported here broaden our perspective on what biogeochemical and ecological roles this species might play as a prominent member of microbial communities in subsurface environments. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016htmp.book..281Z','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016htmp.book..281Z">Experimental Investigation on Reduction Kinetics of Stainless Steel-Making Slag in Iron Bath Smelting Reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Zhang, Bo; Liu, Jienan; Yang, Yanfeng; Liu, Luming; Liu, Jiechao; Luo, Lijian; Ma, Yubao; Hong, Xin Reduction kinetics of stainless steel slag in iron bath smelting reduction was studied at the temperature of 1500°C ˜ 1650°C. It was concluded that the reduction process consisted of two parts. That is to say smelting reduction was controlled by stainless steel slag melting initially and by interface reaction later. In order to increase smelting reaction rate, the melting point of slag should be decreased at the first stage and adjust the liquidity of slag at later stage. Smelting reaction rate will be accelerated by means of optimize the slag content. The optimal reduction result that all most all of the chromium in slag been recovered was obtained in temperature was 1500°C, basicity of slag was 1.0˜1.2, the value of Al2O3+MgO was 25%. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/7874','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/7874">Restoration effects on N cycling pools and processes</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> James M. Vose; Chris Geron; John Walker; Karsten Raulund-Rasmussen 2005-01-01 Over the past several years, there has been an acceleration of restoration efforts to mitigate the consequences (i.e., ground and surface water chemical pollutants, erosion, etc.) of degraded ecosystems and enhance structural and functional components of watershed ecosystems that regulate biogeochemical cycling and associated aquatic components. Biogeochemical... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=232678&Lab=NERL&keyword=erickson&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=232678&Lab=NERL&keyword=erickson&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Effects of Solar UV Radiation and Climate Change on Biogeochemical Cycling: Interactions and Feedbacks</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Solar UV radiation, climate and other drivers of global change are undergoing significant changes and models forecast that these changes will continue for the remainder of this century. Here we assess the effects of solar UV radiation on biogeochemical cycles and the interactions... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=105290&keyword=ocean+AND+climate+AND+changes&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=105290&keyword=ocean+AND+climate+AND+changes&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">INTERACTIVE EFFECTS OF OZONE DEPLETION AND CLIMATE CHANGE ON BIOGEOCHEMICAL CYCLES</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> The effects of ozone depletion on global biogeochemical cycles, via increased UV-B radiation at the Earth's surface, have continued to be documented over the past 4 years. In this report we also document various effects of UV-B that interact with global climate change because the... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/39661','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/39661">Thinking outside the channel: modeling nitrogen cycling in networked river ecosystems</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Ashley M. Helton; Geoffrey C. Poole; Judy L. Meyer; Wilfred M. Wollheim; Bruce J. Peterson; Patrick J. Mulholland; Emily S. Bernhardt; Jack A. Stanford; Clay Arango; Linda R. Ashkenas; Lee W. Cooper; Walter K. Dodds; Stanley V. Gregory; Robert O. Hall; Stephen K. Hamilton; Sherri L. Johnson; William H. McDowell; Jody D. Potter; Jennifer L. Tank; Suzanne M. Thomas; H. Maurice Valett; Jackson R. Webster; Lydia Zeglin 2011-01-01 Agricultural and urban development alters nitrogen and other biogeochemical cycles in rivers worldwide. Because such biogeochemical processes cannot be measured empirically across whole river networks, simulation models are critical tools for understanding river-network biogeochemistry. However, limitations inherent in current models restrict our ability to simulate... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/7373','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/7373">Ecophysiological parameters for Pacific Northwest trees.</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Amy E. Hessl; Cristina Milesi; Michael A. White; David L. Peterson; Robert E. Keane 2004-01-01 We developed a species- and location-specific database of published ecophysiological variables typically used as input parameters for biogeochemical models of coniferous and deciduous forested ecosystems in the Western United States. Parameters are based on the requirements of Biome-BGC, a widely used biogeochemical model that was originally parameterized for the... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=105435&keyword=NH4&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=105435&keyword=NH4&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">EFFECT OF NUTRIENT LOADING ON BIOGEOCHEMICAL AND MICROBIAL PROCESSES IN A NEW ENGLAND HIGH SALT MARSH, SPARTINA PATNES, (AITON MUHL)</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> Coastal marshes represent an important transitional zone between uplands and estuaries and can assimilate nutrient inputs from uplands. We examined the effects of nitrogen (N) and phosphorus (P) fertilization on biogeochemical and microbial processes during the summer growing sea... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=307056','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=307056">Biogeochemical research priorities for sustainable biofuel and bioenergy feedstock production in the Americas</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Rapid expansion in biomass production for biofuels and bioenergy in the Americas is increasing demands on the ecosystem resources required to sustain soil and site productivity. We review the current state of knowledge and highlight gaps in research on biogeochemical processes and ecosystem sustaina... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://ntrs.nasa.gov/search.jsp?R=20040089418&hterms=ecosystems+agricultural&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3Decosystems%2Bagricultural','NASA-TRS'); return false;" href="https://ntrs.nasa.gov/search.jsp?R=20040089418&hterms=ecosystems+agricultural&qs=Ntx%3Dmode%2Bmatchall%26Ntk%3DAll%26N%3D0%26No%3D30%26Ntt%3Decosystems%2Bagricultural">Considerations in miniaturizing simplified agro-ecosystems for advanced life support</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Volk, T. 1996-01-01 Miniaturizing the Earth's biogeochemical cycles to support human life during future space missions is the goal of the NASA research and engineering program in advanced life support. Mission requirements to reduce mass, volume, and power have focused efforts on (1) a maximally simplified agro-ecosystem of humans, food crops, and microbes; and, (2) a design for optimized productivity of food crops with high light levels over long days, with hydroponics, with elevated carbon dioxide and other controlled environmental factors, as well as with genetic selection for desirable crop properties. Mathematical modeling contributes to the goals by establishing trade-offs, by analyzing the growth and development of experimental crops, and by pointing to the possibilities of directed phasic control using modified field crop models to increase the harvest index. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/11540423','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/11540423">Considerations in miniaturizing simplified agro-ecosystems for advanced life support.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Volk, T 1996-01-01 Miniaturizing the Earth's biogeochemical cycles to support human life during future space missions is the goal of the NASA research and engineering program in advanced life support. Mission requirements to reduce mass, volume, and power have focused efforts on (1) a maximally simplified agro-ecosystem of humans, food crops, and microbes; and, (2) a design for optimized productivity of food crops with high light levels over long days, with hydroponics, with elevated carbon dioxide and other controlled environmental factors, as well as with genetic selection for desirable crop properties. Mathematical modeling contributes to the goals by establishing trade-offs, by analyzing the growth and development of experimental crops, and by pointing to the possibilities of directed phasic control using modified field crop models to increase the harvest index. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014JCHyd.164..240M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014JCHyd.164..240M">The impact of biostimulation on the fate of sulfate and associated sulfur dynamics in groundwater</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Miao, Ziheng; Carreón-Diazconti, Concepcion; Carroll, Kenneth C.; Brusseau, Mark L. 2014-08-01 The impact of electron-donor addition on sulfur dynamics for a groundwater system with low levels of metal contaminants was evaluated with a pilot-scale biostimulation test conducted at a former uranium mining site. Geochemical and stable-isotope data collected before, during, and after the test were analyzed to evaluate the sustainability of sulfate reducing conditions induced by the test, the fate of hydrogen sulfide, and the impact on aqueous geochemical conditions. The results of site characterization activities conducted prior to the test indicated the absence of measurable bacterial sulfate reduction. The injection of an electron donor (ethanol) induced bacterial sulfate reduction, as confirmed by an exponential decrease of sulfate concentration in concert with changes in oxidation-reduction potential, redox species, alkalinity, production of hydrogen sulfide, and fractionation of δ34S-sulfate. High, stoichiometrically-equivalent hydrogen sulfide concentrations were not observed until several months after the start of the test. It is hypothesized that hydrogen sulfide produced from sulfate reduction was initially sequestered in the form of iron sulfides until the exhaustion of readily reducible iron oxides within the sediment. The fractionation of δ34S for sulfate was atypical, wherein the enrichment declined in the latter half of the experiment. It was conjectured that mixing effects associated with the release of sulfate from sulfate minerals associated with the sediments, along with possible sulfide re-oxidation contributed to this behavior. The results of this study illustrate the biogeochemical complexity that is associated with in-situ biostimulation processes involving bacterial sulfate reduction. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4136432','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4136432">THE IMPACT OF BIOSTIMULATION ON THE FATE OF SULFATE AND ASSOCIATED SULFUR DYNAMICS IN GROUNDWATER</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Miao, Ziheng; Carreón-Diazconti, Concepcion; Carroll, Kenneth C.; Brusseau, Mark L. 2014-01-01 The impact of electron-donor addition on sulfur dynamics for a groundwater system with low levels of metal contaminants was evaluated with a pilot-scale biostimulation test conducted at a former uranium mining site. Geochemical and stable-isotope data collected before, during, and after the test were analyzed to evaluate the sustainability of sulfate reducing conditions induced by the test, the fate of hydrogen sulfide, and the impact on aqueous geochemical conditions. The results of site characterization activities conducted prior to the test indicated the absence of measurable bacterial sulfate reduction. The injection of an electron donor (ethanol) induced bacterial sulfate reduction, as confirmed by an exponential decrease of sulfate concentration in concert with changes in oxidation-reduction potential, redox species, alkalinity, production of hydrogen sulfide, and fractionation of δ34S-sulfate. High, stoichiometrically-equivalent hydrogen sulfide concentrations were not observed until several months after the start of the test. It is hypothesized that hydrogen sulfide produced from sulfate reduction was initially sequestered in the form of iron sulfides until the exhaustion of readily reducible iron oxides associated with the sediment. The fractionation of δ34S for sulfate was atypical, wherein the enrichment declined in the latter half of the experiment. It was conjectured that mixing effects associated with the release of sulfate from sulfate minerals associated with the sediments, along with possible sulfide re-oxidation contributed to this behavior. The results of this study illustrate the biogeochemical complexity that is associated with in-situ biostimulation processes involving bacterial sulfate reduction. PMID:25016586 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..16.5282P','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..16.5282P">Biogeochemical mass balances in a turbid tropical reservoir. Field data and modelling approach</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Phuong Doan, Thuy Kim; Némery, Julien; Gratiot, Nicolas; Schmid, Martin 2014-05-01 The turbid tropical Cointzio reservoir, located in the Trans Mexican Volcanic Belt (TMVB), behaves as a warm monomictic water body (area = 6 km2, capacity 66 Mm3, residence time ~ 1 year). It is strategic for the drinking water supply of the city of Morelia, capital of the state of Michoacán, and for downstream irrigation during the dry season. This reservoir is a perfect example of a human-impacted system since its watershed is mainly composed of degraded volcanic soils and is subjected to high erosion processes and agricultural loss. The reservoir is threatened by sediment accumulation and nutrients originating from untreated waters in the upstream watershed. The high content of very fine clay particles and the lack of water treatment plants lead to serious episodes of eutrophication (up to 70 μg chl. a L-1), high levels of turbidity (Secchi depth < 30 cm) and a long period of anoxia (from May to October). Based on intensive field measurements in 2009 (deposited sediment, benthic chamber, water vertical profiles, reservoir inflow and outflow) we determined suspended sediment (SS), carbon (C), nitrogen (N) and phosphorus (P) mass balances. Watershed SS yields were estimated at 35 t km2 y-1 of which 89-92 % were trapped in the Cointzio reservoir. As a consequence the reservoir has already lost 25 % of its initial storage capacity since its construction in 1940. Nutrient mass balances showed that 50 % and 46 % of incoming P and N were retained by sedimentation, and mainly eliminated through denitrification respectively. Removal of C by 30 % was also observed both by sedimentation and through gas emission. To complete field data analyses we examined the ability of vertical one dimensional (1DV) numerical models (Aquasim biogeochemical model coupled with k-ɛ mixing model) to reproduce the main biogeochemical cycles in the Cointzio reservoir. The model can describe all the mineralization processes both in the water column and in the sediment. The values of the entire mass balance of nutrients and of the mineralization rates (denitrification and aerobic benthic mineralization) calculated from the model fitted well to the field measurements. Furthermore, this analysis indicates that the benthic mineralizations are the dominant processes involved in the nutrients release. This is the first implementation of a biogeochemical model applied to a highly productive reservoir in the TMVB in order to estimate nutrients release from sediments. It could be used for scenarios of reduction of eutrophication in the reservoir. This study provides a good example of the behavior of a small tropical reservoir under intense human pressure and it will help stakeholders to adopt appropriate strategies for the management of turbid tropical reservoirs. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5877337','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=5877337">Long-Term Cultivation and Metagenomics Reveal Ecophysiology of Previously Uncultivated Thermophiles Involved in Biogeochemical Nitrogen Cycle</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Kato, Shingo; Sakai, Sanae; Hirai, Miho; Tasumi, Eiji; Nishizawa, Manabu; Suzuki, Katsuhiko; Takai, Ken 2018-01-01 Many thermophiles thriving in a natural high-temperature environment remain uncultivated, and their ecophysiological functions in the biogeochemical cycle remain unclear. In the present study, we performed long-term continuous cultivation at 65°C and 70°C using a microbial mat sample, collected from a subsurface geothermal stream, as the inoculum, and reconstructed the whole genome of the maintained populations using metagenomics. Some metagenome-assembled genomes (MAGs), affiliated into phylum-level bacterial and archaeal clades without cultivated representatives, contained genes involved in nitrogen metabolism including nitrification and denitrification. Our results show genetic components and their potential interactions for the biogeochemical nitrogen cycle in a subsurface geothermal environment. PMID:29459499 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25039209','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25039209">Experimenting with ecosystem interaction networks in search of threshold potentials in real-world marine ecosystems.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Thrush, Simon F; Hewitt, Judi E; Parkes, Samantha; Lohrer, Andrew M; Pilditch, Conrad; Woodin, Sarah A; Wethey, David S; Chiantore, Mariachiara; Asnaghi, Valentina; De Juan, Silvia; Kraan, Casper; Rodil, Ivan; Savage, Candida; Van Colen, Carl 2014-06-01 Thresholds profoundly affect our understanding and management of ecosystem dynamics, but we have yet to develop practical techniques to assess the risk that thresholds will be crossed. Combining ecological knowledge of critical system interdependencies with a large-scale experiment, we tested for breaks in the ecosystem interaction network to identify threshold potential in real-world ecosystem dynamics. Our experiment with the bivalves Macomona liliana and Austrovenus stutchburyi on marine sandflats in New Zealand demonstrated that reductions in incident sunlight changed the interaction network between sediment biogeochemical fluxes, productivity, and macrofauna. By demonstrating loss of positive feedbacks and changes in the architecture of the network, we provide mechanistic evidence that stressors lead to break points in dynamics, which theory predicts predispose a system to a critical transition. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018Sci...359.1139M','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018Sci...359.1139M">Sustained climate warming drives declining marine biological productivity</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Moore, J. Keith; Fu, Weiwei; Primeau, Francois; Britten, Gregory L.; Lindsay, Keith; Long, Matthew; Doney, Scott C.; Mahowald, Natalie; Hoffman, Forrest; Randerson, James T. 2018-03-01 Climate change projections to the year 2100 may miss physical-biogeochemical feedbacks that emerge later from the cumulative effects of climate warming. In a coupled climate simulation to the year 2300, the westerly winds strengthen and shift poleward, surface waters warm, and sea ice disappears, leading to intense nutrient trapping in the Southern Ocean. The trapping drives a global-scale nutrient redistribution, with net transfer to the deep ocean. Ensuing surface nutrient reductions north of 30°S drive steady declines in primary production and carbon export (decreases of 24 and 41%, respectively, by 2300). Potential fishery yields, constrained by lower–trophic-level productivity, decrease by more than 20% globally and by nearly 60% in the North Atlantic. Continued high levels of greenhouse gas emissions could suppress marine biological productivity for a millennium. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSPO24B2956R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSPO24B2956R">Anisotropic Shear Dispersion Parameterization for Mesoscale Eddy Transport</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Reckinger, S. J.; Fox-Kemper, B. 2016-02-01 The effects of mesoscale eddies are universally treated isotropically in general circulation models. However, the processes that the parameterization approximates, such as shear dispersion, typically have strongly anisotropic characteristics. The Gent-McWilliams/Redi mesoscale eddy parameterization is extended for anisotropy and tested using 1-degree Community Earth System Model (CESM) simulations. The sensitivity of the model to anisotropy includes a reduction of temperature and salinity biases, a deepening of the southern ocean mixed-layer depth, and improved ventilation of biogeochemical tracers, particularly in oxygen minimum zones. The parameterization is further extended to include the effects of unresolved shear dispersion, which sets the strength and direction of anisotropy. The shear dispersion parameterization is similar to drifter observations in spatial distribution of diffusivity and high-resolution model diagnosis in the distribution of eddy flux orientation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017AtmEn.170..303T','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017AtmEn.170..303T">Mercury emission to the atmosphere from municipal solid waste landfills: A brief review</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Tao, Zhengkai; Dai, Shijin; Chai, Xiaoli 2017-12-01 Municipal solid waste (MSW) landfill is regarded as an important emission source of atmospheric mercury (Hg), which is associated with potential health and environmental risks, as outlined by the Minamata Convention on Hg. This review presents the current state of knowledge with regards to landfill Hg sources, Hg levels in MSW and cover soils, Hg emission to the atmosphere, available Hg biogeochemical transformations, research methods for Hg emission, and important areas for future research. In addition, strategies for controlling landfill Hg emissions are considered, including reducing the Hg load in landfill and in situ controls. These approaches mainly focus on Hg source reduction, Hg recycling programs, public education, and in situ technology such as timely soil cover, vegetation, and end-of-pipe technology for controlling Hg emission from landfill gas. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li class="active">23</li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_24" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li class="active">24</li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="461"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/22227831','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/22227831">Modeling and optimization of reductive degradation of chloramphenicol in aqueous solution by zero-valent bimetallic nanoparticles.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Singh, Kunwar P; Singh, Arun K; Gupta, Shikha; Rai, Premanjali 2012-07-01 The present study aims to investigate the individual and combined effects of temperature, pH, zero-valent bimetallic nanoparticles (ZVBMNPs) dose, and chloramphenicol (CP) concentration on the reductive degradation of CP using ZVBMNPs in aqueous medium. Iron-silver ZVBMNPs were synthesized. Batch experimental data were generated using a four-factor statistical experimental design. CP reduction by ZVBMNPs was optimized using the response surface modeling (RSM) and artificial neural network-genetic algorithm (ANN-GA) approaches. The RSM and ANN methodologies were also compared for their predictive and generalization abilities using the same training and validation data set. Reductive by-products of CP were identified using liquid chromatography-mass spectrometry technique. The optimized process variables (RSM and ANN-GA approaches) yielded CP reduction capacity of 57.37 and 57.10 mg g(-1), respectively, as compared to the experimental value of 54.0 mg g(-1) with un-optimized variables. The ANN-GA and RSM methodologies yielded comparable results and helped to achieve a higher reduction (>6%) of CP by the ZVBMNPs as compared to the experimental value. The root mean squared error, relative standard error of prediction and correlation coefficient between the measured and model-predicted values of response variable were 1.34, 3.79, and 0.964 for RSM and 0.03, 0.07, and 0.999 for ANN models for the training and 1.39, 3.47, and 0.996 for RSM and 1.25, 3.11, and 0.990 for ANN models for the validation set. Predictive and generalization abilities of both the RSM and ANN models were comparable. The synthesized ZVBMNPs may be used for an efficient reductive removal of CP from the water. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/25588118','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/25588118">Modeling nitrous oxide production and reduction in soil through explicit representation of denitrification enzyme kinetics.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Zheng, Jianqiu; Doskey, Paul V 2015-02-17 An enzyme-explicit denitrification model with representations for pre- and de novo synthesized enzymes was developed to improve predictions of nitrous oxide (N2O) accumulations in soil and emissions from the surface. The metabolic model of denitrification is based on dual-substrate utilization and Monod growth kinetics. Enzyme synthesis/activation was incorporated into each sequential reduction step of denitrification to regulate dynamics of the denitrifier population and the active enzyme pool, which controlled the rate function. Parameterizations were developed from observations of the dynamics of N2O production and reduction in soil incubation experiments. The model successfully reproduced the dynamics of N2O and N2 accumulation in the incubations and revealed an important regulatory effect of denitrification enzyme kinetics on the accumulation of denitrification products. Pre-synthesized denitrification enzymes contributed 20, 13, 43, and 62% of N2O that accumulated in 48 h incubations of soil collected from depths of 0-5, 5-10, 10-15, and 15-25 cm, respectively. An enzyme activity function (E) was defined to estimate the relative concentration of active enzymes and variation in response to environmental conditions. The value of E allows for activities of pre-synthesized denitrification enzymes to be differentiated from de novo synthesized enzymes. Incorporating explicit representations of denitrification enzyme kinetics into biogeochemical models is a promising approach for accurately simulating dynamics of the production and reduction of N2O in soils. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/21284319','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/21284319">Selenium stable isotope investigation into selenium biogeochemical cycling in a lacustrine environment: Sweitzer Lake, Colorado.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Clark, Scott K; Johnson, Thomas M 2010-01-01 We present a comprehensive set of Se concentration and isotope ratio data collected over a 3-yr period from dissolved, sediment-hosted, and organically bound Se in a Se-contaminated lake and littoral wetland. Median isotope ratios of these various pools of Se spanned a narrow isotopic range (delta80/76Se(SRM-3149)) = 1.14-2.40 per thousand). Selenium (VI) reduction in the sediments is an important process in this system, but its isotopic impact is muted by the lack of direct contact between surface waters and reduction sites within sediments. This indicates that using Se isotope data as an indicator of microbial or abiotic Se oxyanion reduction is not effective in this or other similar systems. Isotopic data suggest that most Se(IV) in the lake originates from oxidation of organically bound Se rather than directly through Se(VI) reduction. Mobilization of Se(VI) from bedrock involves only a slight isotopic shift. Temporally constant isotopic differences observed in Se(VI) from two catchment areas suggest the potential for tracing Se(VI) from different source areas. Phytoplankton isotope ratios are close to those of the water, with a small depletion in heavy isotopes (0.56 per thousand). Fish tissues nearly match the phytoplankton, being only slightly depleted in the heavier isotopes. This suggests the potential for Se isotopes as migration indicators. Volatile, presumably methylated Se was isotopically very close to median values for phytoplankton and macrophytes, indicating a lack of isotopic fractionation during methylation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19940007981','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19940007981">Sulfate reduction and other sedimentary biogeochemistry in a northern New England salt marsh</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Hines, Mark E.; Knollmeyer, Stephen L.; Tugel, Joyce B. 1992-01-01 Sulfate reduction rates, dissolved iron and sulfide concentrations, and titration alkalinity were measured in salt marsh soils along a transect that included areas inhabited by both the tall and short forms of Spartina alterniflora and by Spartina patens. Pore waters were collected with in situ 'sippers' to acquire temporal data from the same location without disturbing plant roots. During 1984, data collected at weekly intervals showed rapid temporal changes in belowground biogeochemical processes that coincided with changes in S. alterniflora physiology. Rates of SO4(-2) reduction increased fivefold (to greater than 2.5 micromol ml(sup -1)d(sup -1)) when plants began elongating aboveground yet decreased fourfold upon plant flowering. This rapid increase in rates of SO4(-2) reduction must have been fueled by dissolved organic matter released from roots only during active growth. Once plants flowered, the supply of oxidants to the soil decreased and sulfide and alkalinity concentrations increased despite decreases in SO4(-2) reduction and increases in SO4(-2):Cl(-) ratios. Sulfide concentrations were highest in soils inhabited by tallest plants. During 1985, S. alterniflora became infested with fly larvae (Chaetopsis apicalis John) and aboveground growth ceased in late June. This cessation was accompanied by decreased rates of SO4(-2) reduction similar to those noted during the previous year when flowering occurred. After the fly infestation, the pore-water chemical profiles of these soils resembled profiles of soils inhabited by the short form of S. alterniflora. The SO4(-2) reduction rates in S. patens soils are the first reported. Rates were similar to those in S. alterniflora except that they did not increase greatly when S. patens was elongating. Tidal and rainfall events produced desiccation-saturation cycles that altered redox conditions in the S. patens soils, resulting in rapid changes in the dissolution and precipitation of iron and in the magnitude and spatial distribution of SO4(-2) reduction. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009EGUGA..11.7614D','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009EGUGA..11.7614D">Reductive dissolution of As(V)-Fe oxyhydroxides: an experimental insight at biogeochemical interfaces in soil</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Dia, A.; Davranche, M.; Fakih, M.; Nowack, B.; Morin, G.; Gruau, G. 2009-04-01 Iron (III) oxides are ubiquitous components of soils, sediments, aquifers and geological materials. Trace metals associate with Fe (III) oxides as adsorbed or co-precipitated species and, consequently the biogeochemical cycles of Fe and trace metals are closely linked. Using a new monitoring tool recently developed, this study was dedicated to understand how do interplay biological and mineralogical (crystallographic and specific surface area) controls in the Fe oxyhydroxide reductive dissolution within soils and which can be the consequences on associated trace metal release. For this purpose, polymer slides covered by synthetic As-spiked ferrihydrite (As-Fh) or As-spiked lepidocrocite (As-Lp) were inserted into an organic-rich wetland soil in non conventional columns system under anaerobic conditions. This technique was developed to allow the insertion of slides into a structured soil without significant disturbance and to avoid the mechanical abrasion of oxides from slides that would occur in an equilibrium batch system under stirring. Slides were recovered after different periods of time to evaluate (i) the impact of (bio)reduction on both Fe-oxide dissolution and secondary mineral precipitation and, (ii) the subsequent effects on As mobility. XRF analyses of the slides were conducted before and after contact with the soil to determine the amount of Fe and associated As remaining on the slides. Fe(II), acetate, nitrate, sulphate and total metals of the soil solution was followed through time by ion chromatography and ICP-MS measurements. The important bacterial colonization and occurrence of biofilm evidenced by SEM analyses of the slides suggested the presence of biologically mediated processes. As previously shown elsewhere the kinetics of the suspected occurring bacterial reduction differ significantly from abiotic reduction data from literature. The important point is that conversely to what has been observed in published experimental data, the dissolution rates remained here fairly constant through time since the organic matter present in the interacting solution complexed the released Fe(II), which was therefore not able to accumulate onto the bacterial cell surfaces. The organic matter mediated complexation of Fe(II) prevented thus the progressive inhibition of the enzymatic reduction to occur as elsewhere evidenced with other experimental conditions. As expected, the reductive dissolution of the less crystallized ferrihydrite started quicker than that of lepidocrocite. The newly formed minerals were mostly composed of Fe-sulphides. Iron(II) complexation by organic molecules in solution likely prevented formation of secondary Fe(II, III)-rich minerals. The relative proportion of As(III) increased with time on the As-Fh slides, and was combined with a decrease of the Fe/As ratio, suggesting a partial adsorption of As(III) onto minerals. By contrast, for lepidocrocite, the Fe/As ratio increased, suggesting that As(III) was less readsorbed due the lower available site number and the deletion of As adsorption sites on the reduced lepidocrocite surface. Only a weak proportion of As(III) was sequestered by readsorption onto unreduced Fe-oxides and possibly on secondary Fe-sulphide minerals, especially when the iron oxide had a low surface area. Therefore, wetlands and their waterlogged soils could be a non negligible source of As within soils, migrating first through soil solutions and then to the whole hydrosystem. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/56015','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/56015">A Framework to Assess Biogeochemical Response to Ecosystem Disturbance Using Nutrient Partitioning Ratios</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> J. Marty Kranabetter; Kendra K. McLauchlan; Sara K. Enders; Jennifer M. Fraterrigo; Philip E. Higuera; Jesse L. Morris; Edward B. Rastetter; Rebecca Barnes; Brian Buma; Daniel G. Gavin; Laci M. Gerhart; Lindsey Gillson; Peter Hietz; Michelle C. Mack; Brenden McNeil; Steven Perakis 2016-01-01 Disturbances affect almost all terrestrial ecosystems, but it has been difficult to identify general principles regarding these influences. To improve our understanding of the long-term consequences of disturbance on terrestrial ecosystems, we present a conceptual framework that analyzes disturbances by their biogeochemical impacts. We posit that the ratio of... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://hdl.handle.net/2060/19940026113','NASA-TRS'); return false;" href="http://hdl.handle.net/2060/19940026113">Towards coupled physical-biogeochemical models of the ocean carbon cycle</a> <a target="_blank" rel="noopener noreferrer" href="http://ntrs.nasa.gov/search.jsp">NASA Technical Reports Server (NTRS)</a> Rintoul, Stephen R. 1992-01-01 The purpose of this review is to discuss the critical gaps in our knowledge of ocean dynamics and biogeochemical cycles. It is assumed that the ultimate goal is the design of a model of the earth system that can predict the response to changes in the external forces driving climate. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/20167','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/20167">Differences in net primary production and biogeochemistry between contrasting floodplain forests</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Erik B. Schilling; B. Graeme Lockaby 2000-01-01 A firm understanding of the driving forces controlling variation among wetland forests continues to elude scientists and land managersâspecifically the biogeochemical processes controlling vegetation production. Within contrasting wetland forests, insight into the biogeochemical processes driving productivity levels may befound by examining the degree to which nitrogen... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=247615','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=247615">Comparative Biogeochemical Cycles of Bioenergy Crops Reveal Nitrogen-Fixation and Low GHG Emissions in a Miscanthus x giganteus Agro-ecosystem</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> We evaluated the relative greenhouse gas mitigation potential of plant species considered as biofuel feedstock crops by simulating the biogeochemical processes associated with Miscanthus x giganteus, Panicum virgatum, Zea mays, and a mixed prairie community. DayCent model simulations for Miscanthus ... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.fs.usda.gov/treesearch/pubs/53597','TREESEARCH'); return false;" href="https://www.fs.usda.gov/treesearch/pubs/53597">Use of combined biogeochemical model approaches and empirical data to assess critical loads of nitrogen</a> <a target="_blank" rel="noopener noreferrer" href="http://www.fs.usda.gov/treesearch/">Treesearch</a> Mark Fenn; Charles Driscoll; Quingtao Zhou; Leela Rao; Thomas Meixner; Edith Allen; Fengming Yuan; Timothy Sullivan 2015-01-01 Empirical and dynamic biogeochemical modelling are complementary approaches for determining the critical load (CL) of atmospheric nitrogen (N) or other constituent deposition that an ecosystem can tolerate without causing ecological harm. The greatest benefits are obtained when these approaches are used in combination. Confounding environmental factors can complicate... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=233338&Lab=NHEERL&keyword=displacement&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50','EPA-EIMS'); return false;" href="https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=233338&Lab=NHEERL&keyword=displacement&actType=&TIMSType=+&TIMSSubTypeID=&DEID=&epaNumber=&ntisID=&archiveStatus=Both&ombCat=Any&dateBeginCreated=&dateEndCreated=&dateBeginPublishedPresented=&dateEndPublishedPresented=&dateBeginUpdated=&dateEndUpdated=&dateBeginCompleted=&dateEndCompleted=&personID=&role=Any&journalID=&publisherID=&sortBy=revisionDate&count=50">Forging the Link: Using a Conservative Mixing Framework to Characterize Connections between Rivers and Great Lakes in River-lake Transition Zones</a> <a target="_blank" rel="noopener noreferrer" href="http://oaspub.epa.gov/eims/query.page">EPA Science Inventory</a> River-to-Great Lake transition zones are hydrologically, biogeochemically and biologically dynamic areas that regulate nutrient and energy fluxes between rivers and Great Lakes. Our goal is to characterize the biogeochemical properties of the river-lake transition zones and under... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=273283','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=273283">Quantification of terrestrial ecosystem carbon dynamics in the conterminous United States combining a process-based biogeochemical model and MODIS and AmeriFlux data</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Satellite remote sensing provides continuous temporal and spatial information of terrestrial ecosystems. Using these remote sensing data and eddy flux measurements and biogeochemical models, such as the Terrestrial Ecosystem Model (TEM), should provide a more adequate quantification of carbon dynami... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=289879','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=289879">Nitrous oxide emissions from cropland: A procedure for calibrating the DayCent biogeochemical model using inverse modelling</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> DayCent is a biogeochemical model of intermediate complexity widely used to simulate greenhouse gases (GHG), soil organic carbon (SOC) and nutrients in crop, grassland, forest and savannah ecosystems. Although this model has been applied to a wide range of ecosystems, it is still typically parameter... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=344044','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=344044">Estimating landscape-scale impacts of agricultural management on soil carbon using measurements and models.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Agriculture covers 40% of Earth’s ice-free land area and has broad impacts on global biogeochemical cycles. While some agricultural management changes are small in scale or impact, others have the potential to shift biogeochemical cycles at landscape and larger scales if widely adopted. Understandin... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://www.ars.usda.gov/research/publications/publication/?seqNo115=339205','TEKTRAN'); return false;" href="http://www.ars.usda.gov/research/publications/publication/?seqNo115=339205">Advances in the application of amino acid nitrogen isotopic analysis in ecological and biogeochemical studies</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ars.usda.gov/research/publications/find-a-publication/">USDA-ARS?s Scientific Manuscript database</a> Compound-specific isotopic analysis of amino acids (CSIA-AA) has emerged in the last decade as a powerful approach for tracing the origins and fate of nitrogen in ecological and biogeochemical studies. This approach is based on the empirical knowledge that source AAs (i.e., phenylalanine), fractiona... </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1429744','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1429744">Drought Conditions Maximize the Impact of High-Frequency Flow Variations on Thermal Regimes and Biogeochemical Function in the Hyporheic Zone.</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> None, None Anthropogenic activities, such as dam operations, often induce larger and more frequent stage fluctuations than those occurring in natural rivers. However, the long-term impact of such flow variations on thermal and biogeochemical dynamics of the associated hyporheic zone (HZ) is poorly understood. A heterogeneous, two-dimensional thermo-hydro-biogeochemical model revealed an important interaction between high-frequency flow variations and watershed-scale hydrology. High-frequency stage fluctuations had their strongest thermal and biogeochemical impacts when the mean river stage was low during fall and winter. An abnormally thin snowpack in 2015, however, created a low river stage during summer and early fall, whereby high frequency stagemore » fluctuations caused the HZ to be warmer than usual. This study provided the scientific basis to assess the potential ecological consequences of the high-frequency flow variations in a regulated river, as well as guidance on how to maximize the potential benefits—or minimize the drawbacks—of river regulation to river ecosystems.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2015OcDyn..65.1335G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2015OcDyn..65.1335G">Impacts of mesoscale eddies in the South China Sea on biogeochemical cycles</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Guo, Mingxian; Chai, Fei; Xiu, Peng; Li, Shiyu; Rao, Shivanesh 2015-09-01 Biogeochemical cycles associated with mesoscale eddies in the South China Sea (SCS) were investigated. The study was based on a coupled physical-biogeochemical Pacific Ocean model (Regional Ocean Model System-Carbon, Silicate, and Nitrogen Ecosystem, ROMS-CoSiNE) simulation for the period from 1991 to 2008. A total of 568 mesoscale eddies with lifetime longer than 30 days were used in the analysis. Composite analysis revealed that the cyclonic eddies were associated with abundance of nutrients, phytoplankton, and zooplankton while the anticyclonic eddies depressed biogeochemical cycles, which are generally controlled by the eddy pumping mechanism. In addition, diatoms were dominant in phytoplankton species due to the abundance of silicate. Dipole structures of vertical fluxes with net upward motion in cyclonic eddies and net downward motion in anticyclonic eddies were revealed. During the lifetime of an eddy, the evolutions of physical, biological, and chemical structures were not linearly coupled at the eddy core where plankton grew, and composition of the community depended not only on the physical and chemical processes but also on the adjustments by the predator-prey relationship. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70035842','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70035842">Biogeochemical processes on tree islands in the greater everglades: Initiating a new paradigm</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Wetzel, P.R.; Sklar, Fred H.; Coronado, C.A.; Troxler, T.G.; Krupa, S.L.; Sullivan, P.L.; Ewe, S.; Price, R.M.; Newman, S.; Orem, W.H. 2011-01-01 Scientists' understanding of the role of tree islands in the Everglades has evolved from a plant community of minor biogeochemical importance to a plant community recognized as the driving force for localized phosphorus accumulation within the landscape. Results from this review suggest that tree transpiration, nutrient infiltration from the soil surface, and groundwater flow create a soil zone of confluence where nutrients and salts accumulate under the head of a tree island during dry periods. Results also suggest accumulated salts and nutrients are flushed downstream by regional water flows during wet periods. That trees modulate their environment to create biogeochemical hot spots and strong nutrient gradients is a significant ecological paradigm shift in the understanding of the biogeochemical processes in the Everglades. In terms of island sustainability, this new paradigm suggests the need for distinct dry-wet cycles as well as a hydrologic regime that supports tree survival. Restoration of historic tree islands needs further investigation but the creation of functional tree islands is promising. Copyright ?? 2011 Taylor & Francis Group, LLC. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JPhCS.753e2020H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JPhCS.753e2020H">Controller design for wind turbine load reduction via multiobjective parameter synthesis</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hoffmann, A. F.; Weiβ, F. A. 2016-09-01 During the design process for a wind turbine load reduction controller many different, sometimes conflicting requirements must be fulfilled simultaneously. If the requirements can be expressed as mathematical criteria, such a design problem can be solved by a criterion-vector and multi-objective design optimization. The software environment MOPS (Multi-Objective Parameter Synthesis) supports the engineer for such a design optimization. In this paper MOPS is applied to design a multi-objective load reduction controller for the well-known DTU 10 MW reference wind turbine. A significant reduction in the fatigue criteria especially the blade damage can be reached by the use of an additional Individual Pitch Controller (IPC) and an additional tower damper. This reduction is reached as a trade-off with an increase of actuator load. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014EGUGA..1613522C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014EGUGA..1613522C">Reanalysis of biogeochemical properties in the Mediterranean Sea</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Cossarini, Gianpiero; Teruzzi, Anna; Salon, Stefano; Solidoro, Cosimo 2014-05-01 In the 3D variational (3DVAR) assimilation approach the error covariance matrix can be decomposed in a series of operators. The decomposition makes the 3DVAR particularly suitable for marine biogeochemistry data assimilation, because of the reduced computational costs of the method and its modularity, which allows to define the covariance among the biogeochemical variables in a specific operator. In the present work, the results of 3DVAR assimilation of surface chlorophyll concentration in a multi-annual simulation of the Mediterranean Sea biogeochemistry are presented. The assimilated chlorophyll concentrations are obtained from satellite observations (Volpe et al. 2012). The multi-annual simulation is carried out using the OPATM-BFM model (Lazzari et al. 2012), which describes the low trophic web dynamics and is offline coupled with the MFS physical model (Oddo et al. 2009). In the OPATM-BFM four types of phytoplankton are simulated in terms of their content in carbon, nitrogen, phosphorous, silicon and chlorophyll. In the 3DVAR the error covariance matrix has been decomposed in three different operators, which account for the vertical, the horizontal and the biogeochemical covariance (Teruzzi et al. 2014). The biogeochemical operator propagates the result of the assimilation to the OPATM-BFM variables, providing innovation for the components of the four phytoplankton types. The biogeochemical covariance has been designed supposing that the assimilation preserves the physiological status and the relative abundances of phytoplankton types. Practically, the assimilation preserves the internal quotas of the components for each phytoplankton as long as the optimal growth rate condition are maintained. The quotas preservation is not applied when the phytoplankton is in severe declining growth phase, and the correction provided by the assimilation is set equal to zero. Moreover, the relative abundances among the phytoplankton functional types are preserved. The 3DVAR has been applied to the Mediterranean Sea for the period 1999-2010 with weekly assimilation. The results of the multi-annual run show that the assimilation improves the model skill in terms of a better representation of the mean chlorophyll concentrations over the Mediterranean Sea sub-regions and also in terms of spatial and temporal definition of local bloom events. Furthermore, the comparison with nutrients climatology based on in situ measurements show that the non assimilated variables are consistent with observations. The application of the 3DVAR revealed that in specific cases the correction introduced by the assimilation is not maintained by the model dynamics. In these cases, the satellite observations are characterized by local patchy bloom events, which are not well captured by the model. It has been observed that, since the bloom events are strongly affected by the vertical mixing dynamics, which support nutrients to the surface layer, a possible source of error are the mixing conditions provided by the physical model. Oddo et al. 2009. Ocean Science, 5(4), 461-473, doi:10.5194/os-5-461-2009. Lazzari et al. 2012. Biogeosciences, 9(1), 217-233, doi:10.5194/bg-9-217-2012. Teruzzi et al. 2014. Journal of Geophysical Research, 119, 1-18, doi:10.1002/2013JC009277. Volpe et al. 2012. Ocean Science Discussions, 9(2), 1349-1385, doi:10.5194/osd-9-1349-2012. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li class="active">24</li> <li><a href="#" onclick='return showDiv("page_25");'>25</a></li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div id="page_25" class="hiddenDiv"> <div class="row"> <div class="col-sm-12"> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li class="active">25</li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> <div class="row"> <div class="col-sm-12"> <ol class="result-class" start="481"> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1377412-technical-note-generic-law-minimum-flux-limiter-simulating-substrate-limitation-biogeochemical-models','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1377412-technical-note-generic-law-minimum-flux-limiter-simulating-substrate-limitation-biogeochemical-models">Technical Note: A generic law-of-the-minimum flux limiter for simulating substrate limitation in biogeochemical models</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Tang, J. Y.; Riley, W. J. 2016-02-05 We present a generic flux limiter to account for mass limitations from an arbitrary number of substrates in a biogeochemical reaction network. The flux limiter is based on the observation that substrate (e.g., nitrogen, phosphorus) limitation in biogeochemical models can be represented as to ensure mass conservative and non-negative numerical solutions to the governing ordinary differential equations. Application of the flux limiter includes two steps: (1) formulation of the biogeochemical processes with a matrix of stoichiometric coefficients and (2) application of Liebig's law of the minimum using the dynamic stoichiometric relationship of the reactants. This approach contrasts with the ad hoc down-regulationmore » approaches that are implemented in many existing models (such as CLM4.5 and the ACME (Accelerated Climate Modeling for Energy) Land Model (ALM)) of carbon and nutrient interactions, which are error prone when adding new processes, even for experienced modelers. Through an example implementation with a CENTURY-like decomposition model that includes carbon, nitrogen, and phosphorus, we show that our approach (1) produced almost identical results to that from the ad hoc down-regulation approaches under non-limiting nutrient conditions, (2) properly resolved the negative solutions under substrate-limited conditions where the simple clipping approach failed, (3) successfully avoided the potential conceptual ambiguities that are implied by those ad hoc down-regulation approaches. We expect our approach will make future biogeochemical models easier to improve and more robust.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.ncbi.nlm.nih.gov/pubmed/24449851','PUBMED'); return false;" href="https://www.ncbi.nlm.nih.gov/pubmed/24449851">Gene-centric approach to integrating environmental genomics and biogeochemical models.</a> <a target="_blank" rel="noopener noreferrer" href="https://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pubmed">PubMed</a> Reed, Daniel C; Algar, Christopher K; Huber, Julie A; Dick, Gregory J 2014-02-04 Rapid advances in molecular microbial ecology have yielded an unprecedented amount of data about the evolutionary relationships and functional traits of microbial communities that regulate global geochemical cycles. Biogeochemical models, however, are trailing in the wake of the environmental genomics revolution, and such models rarely incorporate explicit representations of bacteria and archaea, nor are they compatible with nucleic acid or protein sequence data. Here, we present a functional gene-based framework for describing microbial communities in biogeochemical models by incorporating genomics data to provide predictions that are readily testable. To demonstrate the approach in practice, nitrogen cycling in the Arabian Sea oxygen minimum zone (OMZ) was modeled to examine key questions about cryptic sulfur cycling and dinitrogen production pathways in OMZs. Simulations support previous assertions that denitrification dominates over anammox in the central Arabian Sea, which has important implications for the loss of fixed nitrogen from the oceans. Furthermore, cryptic sulfur cycling was shown to attenuate the secondary nitrite maximum often observed in OMZs owing to changes in the composition of the chemolithoautotrophic community and dominant metabolic pathways. Results underscore the need to explicitly integrate microbes into biogeochemical models rather than just the metabolisms they mediate. By directly linking geochemical dynamics to the genetic composition of microbial communities, the method provides a framework for achieving mechanistic insights into patterns and biogeochemical consequences of marine microbes. Such an approach is critical for informing our understanding of the key role microbes play in modulating Earth's biogeochemistry. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018GBioC..32..565B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018GBioC..32..565B">Dynamic Biological Functioning Important for Simulating and Stabilizing Ocean Biogeochemistry</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Buchanan, P. J.; Matear, R. J.; Chase, Z.; Phipps, S. J.; Bindoff, N. L. 2018-04-01 The biogeochemistry of the ocean exerts a strong influence on the climate by modulating atmospheric greenhouse gases. In turn, ocean biogeochemistry depends on numerous physical and biological processes that change over space and time. Accurately simulating these processes is fundamental for accurately simulating the ocean's role within the climate. However, our simulation of these processes is often simplistic, despite a growing understanding of underlying biological dynamics. Here we explore how new parameterizations of biological processes affect simulated biogeochemical properties in a global ocean model. We combine 6 different physical realizations with 6 different biogeochemical parameterizations (36 unique ocean states). The biogeochemical parameterizations, all previously published, aim to more accurately represent the response of ocean biology to changing physical conditions. We make three major findings. First, oxygen, carbon, alkalinity, and phosphate fields are more sensitive to changes in the ocean's physical state. Only nitrate is more sensitive to changes in biological processes, and we suggest that assessment protocols for ocean biogeochemical models formally include the marine nitrogen cycle to assess their performance. Second, we show that dynamic variations in the production, remineralization, and stoichiometry of organic matter in response to changing environmental conditions benefit the simulation of ocean biogeochemistry. Third, dynamic biological functioning reduces the sensitivity of biogeochemical properties to physical change. Carbon and nitrogen inventories were 50% and 20% less sensitive to physical changes, respectively, in simulations that incorporated dynamic biological functioning. These results highlight the importance of a dynamic biology for ocean properties and climate. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://pubs.er.usgs.gov/publication/70022169','USGSPUBS'); return false;" href="https://pubs.er.usgs.gov/publication/70022169">Fractionation of selenium isotopes during bacterial respiratory reduction of selenium oxyanions</a> <a target="_blank" rel="noopener noreferrer" href="http://pubs.er.usgs.gov/pubs/index.jsp?view=adv">USGS Publications Warehouse</a> Herbel, M.J.; Johnson, T.M.; Oremland, R.S.; Bullen, T.D. 2000-01-01 Reduction of selenium oxyanions by microorganisms is an important process in the biogeochemical cycling of selenium. Numerous bacteria can reduce Se oxyanions, which are used as electron acceptors during the oxidation of organic matter in anoxic environments. In this study, we used a double spike (82Se and 74Se) thermal ionization mass spectrometry technique to quantify the isotopic fractionation achieved by three different species of anaerobic bacteria capable of accomplishing growth by respiratory reduction of selenate [SeO42- or Se(VI)] or selenite [SeO32- or Se(IV)] to Se(IV) or elemental selenium [Se(0)] coupled with the oxidation of lactate. Isotopic discrimination in these closed system experiments was evaluated by Rayleigh fractionation equations and numerical models. Growing cultures of Bacillus selenitireducens, a haloalkaliphile capable of growth using Se(IV) as an electron acceptor, induced a 80Se/76Se fractionation of -8.0 ?? 0.4??? (instantaneous ?? value) during reduction of Se(IV) to Se(0). With Bacillus arsenicoselenatis, a haloalkaliphile capable of growth using Se(VI) as an electron acceptor, fractionations of -5.0 ?? 0.5??? and -6.0 ?? 1.0??? were observed for reduction of Se(VI) to Se(IV) and reduction of Se(IV) to Se(0), respectively. In growing cultures of Sulfurospirillum barnesii, a freshwater species capable of growth using Se(VI), fractionation was small initially, but near the end of the log growth phase, it increased to -4.0 ?? 1.0??? and -8.4 ?? 0.4??? for reduction of Se(VI) to Se(IV) and reduction of Se(IV) to Se(O), respectively. Washed cell suspensions of S. barnesii induced fractionations of -1.1 ?? 0.4??? during Se(VI) reduction, and -9.1 ?? 0.5% for Se(IV) reduction, with some evidence for smaller values (e.g., -1.7???) in the earliest-formed Se(0) results. These results demonstrate that dissimilatory reduction of selenate or selenite induces significant isotopic fractionation, and suggest that significant Se isotope ratio variation will be found in nature. Copyright (C) 2000 Elsevier Science Ltd. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016AGUOSAH41A..08F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016AGUOSAH41A..08F">Proximate and Ultimate Limiting Nutrients in the Mississippi River Plume: Implications for Hypoxia Reduction Through Nutrient Management</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fennel, K.; Laurent, A. 2016-02-01 A large hypoxic area (15,000 km2 on average) forms every summer over the Texas-Louisiana shelf in the northern Gulf of Mexico due to decay of organic matter that is primarily derived from nutrient inputs from the Mississippi/Atchafalaya River System. Efforts are underway to reduce the extent of hypoxic conditions through nutrient management in the watershed; for example, an interagency Hypoxia Task Force is developing Action Plans with input from various stakeholders that set out targets for hypoxia reduction. An open question is by how much nutrient loads would have to be decreased in order to produce the desired reductions in hypoxia and when these would be measurable over natural variability. We have performed a large number of multi-year nutrient load reduction scenarios with a regional biogeochemical model for the region. The model is based on the Regional Ocean Modeling System (ROMS), explicitly includes nitrogen (N) and phosphorus (P) species as inorganic nutrients, and has been shown to realistically reproduce the key processes responsible for hypoxia generation. We have quantified the effects of differential reductions in river N and P loads on hypoxic extent. An assessment of the effects of N versus P reductions is important because, thus far, nutrient management efforts have focused on N, yet P is known to limit primary production in spring and early summer. A debate is ongoing as to whether targets for P reductions should be set and whether nutrient reduction efforts should focus solely on P, which results primarily from urban and industrial point sources and is uncoupled from agricultural fertilizer application. Our results strongly indicate that N is the `ultimate' limiting nutrient to primary production determining the areal extent and duration of hypoxic conditions in a cumulative sense, while P is temporarily limiting in spring. Although reductions in river P load would decrease hypoxic extent in early summer, they would have a much smaller effect than N reductions on the cumulative extent and duration of hypoxic conditions. Combined reductions of N and P have the greatest effect. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.3323F','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.3323F">Proximate versus ultimate limiting nutrients in the Mississippi River Plume and Implications for Hypoxia Reductions through Nutrient Management</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Fennel, Katja; Laurent, Arnaud 2016-04-01 A large hypoxic area (15,000 km2 on average) forms every summer over the Texas-Louisiana shelf in the northern Gulf of Mexico due to decay of organic matter that is primarily derived from nutrient inputs from the Mississippi/Atchafalaya River System. Efforts are underway to reduce the extent of hypoxic conditions through nutrient management in the watershed; for example, an interagency Hypoxia Task Force is developing Action Plans with input from various stakeholders that set out targets for hypoxia reduction. An open question is how far nutrient loads would have to be decreased in order to produce the desired reductions in hypoxia and when these would be measurable given significant natural variability. We have simulated a large number of multi-year nutrient load reduction scenarios with a regional biogeochemical model for the region. The model is based on the Regional Ocean Modeling System (ROMS), explicitly includes nitrogen (N) and phosphorus (P) species as inorganic nutrients, and has been shown to realistically reproduce the key processes responsible for hypoxia generation. We have quantified the effects of differential reductions in river N and P loads on hypoxic extent. An assessment of the effects of N versus P reductions is important because, thus far, nutrient management efforts have focused on N, yet P is known to limit primary production in spring and early summer. A debate is ongoing as to whether targets for P reductions should be set and whether nutrient reduction efforts should focus solely on P, which results primarily from urban and industrial point sources and is uncoupled from agricultural fertilizer application. Our results strongly indicate that N is the 'ultimate' limiting nutrient to primary production determining the areal extent and duration of hypoxic conditions in a cumulative sense, while P is temporarily limiting in spring. Although reductions in river P load would decrease hypoxic extent in early summer, they would have a much smaller effect than N reductions on the cumulative extent and duration of hypoxic conditions. Combined reductions of N and P have the greatest effect. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3736416','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=3736416">Optimized Hyper Beamforming of Linear Antenna Arrays Using Collective Animal Behaviour</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Ram, Gopi; Mandal, Durbadal; Kar, Rajib; Ghoshal, Sakti Prasad 2013-01-01 A novel optimization technique which is developed on mimicking the collective animal behaviour (CAB) is applied for the optimal design of hyper beamforming of linear antenna arrays. Hyper beamforming is based on sum and difference beam patterns of the array, each raised to the power of a hyperbeam exponent parameter. The optimized hyperbeam is achieved by optimization of current excitation weights and uniform interelement spacing. As compared to conventional hyper beamforming of linear antenna array, real coded genetic algorithm (RGA), particle swarm optimization (PSO), and differential evolution (DE) applied to the hyper beam of the same array can achieve reduction in sidelobe level (SLL) and same or less first null beam width (FNBW), keeping the same value of hyperbeam exponent. Again, further reductions of sidelobe level (SLL) and first null beam width (FNBW) have been achieved by the proposed collective animal behaviour (CAB) algorithm. CAB finds near global optimal solution unlike RGA, PSO, and DE in the present problem. The above comparative optimization is illustrated through 10-, 14-, and 20-element linear antenna arrays to establish the optimization efficacy of CAB. PMID:23970843 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2009IEITF..92.3111C','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2009IEITF..92.3111C">Optimizing Controlling-Value-Based Power Gating with Gate Count and Switching Activity</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Chen, Lei; Kimura, Shinji In this paper, a new heuristic algorithm is proposed to optimize the power domain clustering in controlling-value-based (CV-based) power gating technology. In this algorithm, both the switching activity of sleep signals (p) and the overall numbers of sleep gates (gate count, N) are considered, and the sum of the product of p and N is optimized. The algorithm effectively exerts the total power reduction obtained from the CV-based power gating. Even when the maximum depth is kept to be the same, the proposed algorithm can still achieve power reduction approximately 10% more than that of the prior algorithms. Furthermore, detailed comparison between the proposed heuristic algorithm and other possible heuristic algorithms are also presented. HSPICE simulation results show that over 26% of total power reduction can be obtained by using the new heuristic algorithm. In addition, the effect of dynamic power reduction through the CV-based power gating method and the delay overhead caused by the switching of sleep transistors are also shown in this paper. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4712455','PMC'); return false;" href="https://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=4712455">QUADRO: A SUPERVISED DIMENSION REDUCTION METHOD VIA RAYLEIGH QUOTIENT OPTIMIZATION</a> <a target="_blank" rel="noopener noreferrer" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?DB=pmc">PubMed Central</a> Fan, Jianqing; Ke, Zheng Tracy; Liu, Han; Xia, Lucy 2016-01-01 We propose a novel Rayleigh quotient based sparse quadratic dimension reduction method—named QUADRO (Quadratic Dimension Reduction via Rayleigh Optimization)—for analyzing high-dimensional data. Unlike in the linear setting where Rayleigh quotient optimization coincides with classification, these two problems are very different under nonlinear settings. In this paper, we clarify this difference and show that Rayleigh quotient optimization may be of independent scientific interests. One major challenge of Rayleigh quotient optimization is that the variance of quadratic statistics involves all fourth cross-moments of predictors, which are infeasible to compute for high-dimensional applications and may accumulate too many stochastic errors. This issue is resolved by considering a family of elliptical models. Moreover, for heavy-tail distributions, robust estimates of mean vectors and covariance matrices are employed to guarantee uniform convergence in estimating non-polynomially many parameters, even though only the fourth moments are assumed. Methodologically, QUADRO is based on elliptical models which allow us to formulate the Rayleigh quotient maximization as a convex optimization problem. Computationally, we propose an efficient linearized augmented Lagrangian method to solve the constrained optimization problem. Theoretically, we provide explicit rates of convergence in terms of Rayleigh quotient under both Gaussian and general elliptical models. Thorough numerical results on both synthetic and real datasets are also provided to back up our theoretical results. PMID:26778864 </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/servlets/purl/1357747','SCIGOV-STC'); return false;" href="https://www.osti.gov/servlets/purl/1357747">Pseudo-spectral control of a novel oscillating surge wave energy converter in regular waves for power optimization including load reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/search">DOE Office of Scientific and Technical Information (OSTI.GOV)</a> Tom, Nathan M.; Yu, Yi -Hsiang; Wright, Alan D. The aim of this study is to describe a procedure to maximize the power-to-load ratio of a novel wave energy converter (WEC) that combines an oscillating surge wave energy converter with variable structural components. The control of the power-take-off torque will be on a wave-to-wave timescale, whereas the structure will be controlled statically such that the geometry remains the same throughout the wave period. Linear hydrodynamic theory is used to calculate the upper and lower bounds for the time-averaged absorbed power and surge foundation loads while assuming that the WEC motion remains sinusoidal. Previous work using pseudo-spectral techniques to solvemore » the optimal control problem focused solely on maximizing absorbed energy. This work extends the optimal control problem to include a measure of the surge foundation force in the optimization. The objective function includes two competing terms that force the optimizer to maximize power capture while minimizing structural loads. A penalty weight was included with the surge foundation force that allows control of the optimizer performance based on whether emphasis should be placed on power absorption or load shedding. Results from pseudo-spectral optimal control indicate that a unit reduction in time-averaged power can be accompanied by a greater reduction in surge-foundation force.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('https://www.osti.gov/pages/biblio/1357747-pseudo-spectral-control-novel-oscillating-surge-wave-energy-converter-regular-waves-power-optimization-including-load-reduction','SCIGOV-DOEP'); return false;" href="https://www.osti.gov/pages/biblio/1357747-pseudo-spectral-control-novel-oscillating-surge-wave-energy-converter-regular-waves-power-optimization-including-load-reduction">Pseudo-spectral control of a novel oscillating surge wave energy converter in regular waves for power optimization including load reduction</a> <a target="_blank" rel="noopener noreferrer" href="http://www.osti.gov/pages">DOE PAGES</a> Tom, Nathan M.; Yu, Yi -Hsiang; Wright, Alan D.; ... 2017-04-18 The aim of this study is to describe a procedure to maximize the power-to-load ratio of a novel wave energy converter (WEC) that combines an oscillating surge wave energy converter with variable structural components. The control of the power-take-off torque will be on a wave-to-wave timescale, whereas the structure will be controlled statically such that the geometry remains the same throughout the wave period. Linear hydrodynamic theory is used to calculate the upper and lower bounds for the time-averaged absorbed power and surge foundation loads while assuming that the WEC motion remains sinusoidal. Previous work using pseudo-spectral techniques to solvemore » the optimal control problem focused solely on maximizing absorbed energy. This work extends the optimal control problem to include a measure of the surge foundation force in the optimization. The objective function includes two competing terms that force the optimizer to maximize power capture while minimizing structural loads. A penalty weight was included with the surge foundation force that allows control of the optimizer performance based on whether emphasis should be placed on power absorption or load shedding. Results from pseudo-spectral optimal control indicate that a unit reduction in time-averaged power can be accompanied by a greater reduction in surge-foundation force.« less </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013OcScD..10.1997H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013OcScD..10.1997H">Adapting to life: ocean biogeochemical modelling and adaptive remeshing</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hill, J.; Popova, E. E.; Ham, D. A.; Piggott, M. D.; Srokosz, M. 2013-11-01 An outstanding problem in biogeochemical modelling of the ocean is that many of the key processes occur intermittently at small scales, such as the sub-mesoscale, that are not well represented in global ocean models. As an example, state-of-the-art models give values of primary production approximately two orders of magnitude lower than those observed in the ocean's oligotrophic gyres, which cover a third of the Earth's surface. This is partly due to their failure to resolve sub-mesoscale phenomena, which play a significant role in nutrient supply. Simply increasing the resolution of the models may be an inefficient computational solution to this problem. An approach based on recent advances in adaptive mesh computational techniques may offer an alternative. Here the first steps in such an approach are described, using the example of a~simple vertical column (quasi 1-D) ocean biogeochemical model. We present a novel method of simulating ocean biogeochemical behaviour on a vertically adaptive computational mesh, where the mesh changes in response to the biogeochemical and physical state of the system throughout the simulation. We show that the model reproduces the general physical and biological behaviour at three ocean stations (India, Papa and Bermuda) as compared to a high-resolution fixed mesh simulation and to observations. The simulations capture both the seasonal and inter-annual variations. The use of an adaptive mesh does not increase the computational error, but reduces the number of mesh elements by a factor of 2-3, so reducing computational overhead. We then show the potential of this method in two case studies where we change the metric used to determine the varying mesh sizes in order to capture the dynamics of chlorophyll at Bermuda and sinking detritus at Papa. We therefore demonstrate adaptive meshes may provide a~suitable numerical technique for simulating seasonal or transient biogeochemical behaviour at high spatial resolution whilst minimising computational cost. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014OcSci..10..323H','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014OcSci..10..323H">Adapting to life: ocean biogeochemical modelling and adaptive remeshing</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Hill, J.; Popova, E. E.; Ham, D. A.; Piggott, M. D.; Srokosz, M. 2014-05-01 An outstanding problem in biogeochemical modelling of the ocean is that many of the key processes occur intermittently at small scales, such as the sub-mesoscale, that are not well represented in global ocean models. This is partly due to their failure to resolve sub-mesoscale phenomena, which play a significant role in vertical nutrient supply. Simply increasing the resolution of the models may be an inefficient computational solution to this problem. An approach based on recent advances in adaptive mesh computational techniques may offer an alternative. Here the first steps in such an approach are described, using the example of a simple vertical column (quasi-1-D) ocean biogeochemical model. We present a novel method of simulating ocean biogeochemical behaviour on a vertically adaptive computational mesh, where the mesh changes in response to the biogeochemical and physical state of the system throughout the simulation. We show that the model reproduces the general physical and biological behaviour at three ocean stations (India, Papa and Bermuda) as compared to a high-resolution fixed mesh simulation and to observations. The use of an adaptive mesh does not increase the computational error, but reduces the number of mesh elements by a factor of 2-3. Unlike previous work the adaptivity metric used is flexible and we show that capturing the physical behaviour of the model is paramount to achieving a reasonable solution. Adding biological quantities to the adaptivity metric further refines the solution. We then show the potential of this method in two case studies where we change the adaptivity metric used to determine the varying mesh sizes in order to capture the dynamics of chlorophyll at Bermuda and sinking detritus at Papa. We therefore demonstrate that adaptive meshes may provide a suitable numerical technique for simulating seasonal or transient biogeochemical behaviour at high vertical resolution whilst minimising the number of elements in the mesh. More work is required to move this to fully 3-D simulations. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016EGUGA..18.8275B','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016EGUGA..18.8275B">Geomorphic and substrate controls on spatial variability in river solute transport and biogeochemical cycling</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Blaen, Phillip; Kurz, Marie; Knapp, Julia; Mendoza-Lera, Clara; Lee-Cullin, Joe; Klaar, Megan; Drummond, Jen; Jaeger, Anna; Zarnetske, Jay; Lewandowski, Joerg; Marti, Eugenia; Ward, Adam; Fleckenstein, Jan; Datry, Thibault; Larned, Scott; Krause, Stefan 2016-04-01 Nutrient concentrations in surface waters and groundwaters are increasing in many agricultural catchments worldwide as a result of anthropogenic activities. Increasing geomorphological heterogeneity in river channels may help to attenuate nutrient pollution by facilitating water exchange fluxes with the hyporheic zone; a site of intense microbial activity where biogeochemical transformation rates (e.g. denitrification) can be high. However, the controls on spatial variability in biogeochemical cycling, particularly at scales relevant for river managers, are not well understood. Here, we aimed to assess: 1) how differences in geomorphological heterogeneity control river solute transport and rates of biogeochemical cycling at sub-reach scales (102 m); and 2) the relative magnitude of these differences versus those relating to reach scale substrate variability (103 m). We used the reactive 'smart' tracer resazurin (Raz), a weakly fluorescent dye that transforms to highly fluorescent resorufin (Rru) under mildly reducing conditions, as a proxy to assess rates of biogeochemical cycling in a lowland river in southern England. Solute tracer tests were conducted in two reaches with contrasting substrates: one sand-dominated and the other gravel-dominated. Each reach was divided into sub-reaches that varied in geomorphic complexity (e.g. by the presence of pool-riffle sequences or the abundance of large woody debris). Slug injections of Raz and the conservative tracer fluorescein were conducted in each reach during baseflow conditions (Q ≈ 80 L/s) and breakthrough curves monitored using in-situ fluorometers. Preliminary results indicate overall Raz:Rru transformation rates in the gravel-dominated reach were more than 50% higher than those in the sand-dominated reach. However, high sub-reach variability in Raz:Rru transformation rates and conservative solute transport parameters suggests small-scale targeted management interventions to alter geomorphic heterogeneity may be effective in creating hotspots of river biogeochemical cycling and nutrient load attenuation. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2013AGUFM.H44B..07J','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2013AGUFM.H44B..07J">Emergent Archetype Hydrological-Biogeochemical Response Patterns in Heterogeneous Catchments</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Jawitz, J. W.; Gall, H. E.; Rao, P. 2013-12-01 What can spatiotemporally integrated patterns observed in stream hydrologic and biogeochemical signals generated in response to transient hydro-climatic and anthropogenic forcing tell us about the interactions between spatially heterogeneous soil-mediated hydrological and biogeochemical processes? We seek to understand how the spatial structure of solute sources coupled with hydrologic responses affect observed concentration-discharge (C-Q) patterns. These patterns are expressions of the spatiotemporal structure of solute loads exported from managed catchments, and their likely ecological consequences manifested in receiving water bodies (e.g., wetlands, rivers, lakes, and coastal waters). We investigated the following broad questions: (1) How does the correlation between flow-generating areas and biogeochemical source areas across a catchment evolve under stochastic hydro-climatic forcing? (2) What are the feasible hydrologic and biogeochemical responses that lead to the emergence of the observed archetype C-Q patterns? and; (3) What implications do these coupled dynamics have for catchment monitoring and implementation of management practices? We categorize the observed temporal signals into three archetypical C-Q patterns: dilution; accretion, and constant concentration. We introduce a parsimonious stochastic model of heterogeneous catchments, which act as hydrologic and biogeochemical filters, to examine the relationship between spatial heterogeneity and temporal history of solute export signals. The core concept of the modeling framework is considering the types and degree of spatial correlation between solute source zones and flow generating zones, and activation of different portions of the catchments during rainfall events. Our overarching hypothesis is that each of the archetype C-Q patterns can be generated by explicitly linking landscape-scale hydrologic responses and spatial distributions of solute source properties within a catchment. The model simulations reproduce the three major C-Q patterns observed in published data, offering valuable insight into coupled catchment processes. The findings have important implications for effective catchment management for water quality improvement, and stream monitoring strategies. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2018BGeo...15...73K','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2018BGeo...15...73K">Assimilating bio-optical glider data during a phytoplankton bloom in the southern Ross Sea</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Kaufman, Daniel E.; Friedrichs, Marjorie A. M.; Hemmings, John C. P.; Smith, Walker O., Jr. 2018-01-01 The Ross Sea is a region characterized by high primary productivity in comparison to other Antarctic coastal regions, and its productivity is marked by considerable variability both spatially (1-50 km) and temporally (days to weeks). This variability presents a challenge for inferring phytoplankton dynamics from observations that are limited in time or space, which is often the case due to logistical limitations of sampling. To better understand the spatiotemporal variability in Ross Sea phytoplankton dynamics and to determine how restricted sampling may skew dynamical interpretations, high-resolution bio-optical glider measurements were assimilated into a one-dimensional biogeochemical model adapted for the Ross Sea. The assimilation of data from the entire glider track using the micro-genetic and local search algorithms in the Marine Model Optimization Testbed improves the model-data fit by ˜ 50 %, generating rates of integrated primary production of 104 g C m-2 yr-1 and export at 200 m of 27 g C m-2 yr-1. Assimilating glider data from three different latitudinal bands and three different longitudinal bands results in minimal changes to the simulations, improves the model-data fit with respect to unassimilated data by ˜ 35 %, and confirms that analyzing these glider observations as a time series via a one-dimensional model is reasonable on these scales. Whereas assimilating the full glider data set produces well-constrained simulations, assimilating subsampled glider data at a frequency consistent with cruise-based sampling results in a wide range of primary production and export estimates. These estimates depend strongly on the timing of the assimilated observations, due to the presence of high mesoscale variability in this region. Assimilating surface glider data subsampled at a frequency consistent with available satellite-derived data results in 40 % lower carbon export, primarily resulting from optimized rates generating more slowly sinking diatoms. This analysis highlights the need for the strategic consideration of the impacts of data frequency, duration, and coverage when combining observations with biogeochemical modeling in regions with strong mesoscale variability. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2014AGUFMGC11E0599R','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2014AGUFMGC11E0599R">Calibration of Daycent biogeochemical model for rice paddies in three agro-ecological zones in Peninsular India to optimize cropping practices and predict GHG emissions</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Rajan, S.; Kritee, K.; Keough, C.; Parton, W. J.; Ogle, S. M. 2014-12-01 Rice is a staple for nearly half of the world population with irrigated and rainfed lowland rice accounting for about 80% of the worldwide harvested rice area. Increased atmospheric CO2 and rising temperatures are expected to adversely affect rice yields by the end of the 21st century. In addition, different crop management practices affect methane and nitrous oxide emissions from rice paddies antagonistically warranting a review of crop management practices such that farmers can adapt to the changing climate and also help mitigate climate change. The Daily DayCent is a biogeochemical model that operates on a daily time step, driven by four ecological drivers, i.e. climate, soil, vegetation, and management practices. The model is widely used to simulate daily fluxes of various gases, plant productivity, nutrient availability, and other ecosystem parameters in response to changes in land management and climate. We employed the DayCent model as a tool to optimize rice cropping practices in Peninsular India so as to develop a set of farming recommendations to ensure a triple win (i.e. higher yield, higher profit and lower GHG emissions). We applied the model to simulate both N2O and CH4 emissions, and crop yields from four rice paddies in three different agro-ecological zones under different management practices, and compared them with measured GHG and yield data from these plots. We found that, like all process based models, the biggest constraint in using the model was input data acquisition. Lack of accurate documentation of historic land use and management practices, missing historical daily weather data, and difficulty in obtaining digital records of soil and crop/vegetation parameters related to our experimental plots came in the way of our execution of this model. We will discuss utilization of estimates based on available literature, or knowledge-based values in lieu of missing measured parameters in our simulations with DayCent which could prove to be a solution to overcome data limitations in modeling with DayCent and other process based models for developing regions of the world. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2017EGUGA..1914421L','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2017EGUGA..1914421L">Toward the assimilation of biogeochemical data in the CMEMS BIOMER coupled physical-biogeochemical operational system</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Lamouroux, Julien; Testut, Charles-Emmanuel; Lellouche, Jean-Michel; Perruche, Coralie; Paul, Julien 2017-04-01 The operational production of data-assimilated biogeochemical state of the ocean is one of the challenging core projects of the Copernicus Marine Environment Monitoring Service. In that framework - and with the April 2018 CMEMS V4 release as a target - Mercator Ocean is in charge of improving the realism of its global ¼° BIOMER coupled physical-biogeochemical (NEMO/PISCES) simulations, analyses and re-analyses, and to develop an effective capacity to routinely estimate the biogeochemical state of the ocean, through the implementation of biogeochemical data assimilation. Primary objectives are to enhance the time representation of the seasonal cycle in the real time and reanalysis systems, and to provide a better control of the production in the equatorial regions. The assimilation of BGC data will rely on a simplified version of the SEEK filter, where the error statistics do not evolve with the model dynamics. The associated forecast error covariances are based on the statistics of a collection of 3D ocean state anomalies. The anomalies are computed from a multi-year numerical experiment (free run without assimilation) with respect to a running mean in order to estimate the 7-day scale error on the ocean state at a given period of the year. These forecast error covariances rely thus on a fixed-basis seasonally variable ensemble of anomalies. This methodology, which is currently implemented in the "blue" component of the CMEMS operational forecast system, is now under adaptation to be applied to the biogeochemical part of the operational system. Regarding observations - and as a first step - the system shall rely on the CMEMS GlobColour Global Ocean surface chlorophyll concentration products, delivered in NRT. The objective of this poster is to provide a detailed overview of the implementation of the aforementioned data assimilation methodology in the CMEMS BIOMER forecasting system. Focus shall be put on (1) the assessment of the capabilities of this data assimilation methodology to provide satisfying statistics of the model variability errors (through space-time analysis of dedicated representers of satellite surface Chla observations), (2) the dedicated features of the data assimilation configuration that have been implemented so far (e.g. log-transformation of the analysis state, multivariate Chlorophyll-Nutrient control vector, etc.) and (3) the assessment of the performances of this future operational data assimilation configuration. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2011AN....332..227G','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2011AN....332..227G">The X-shooter pipeline</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Goldoni, P. 2011-03-01 The X-shooter data reduction pipeline is an integral part of the X-shooter project, it allows the production of reduced data in physical quantities from the raw data produced by the instrument. The pipeline is based on the data reduction library developed by the X-shooter consortium with contributions from France, The Netherlands and ESO and it uses the Common Pipeline Library (CPL) developed at ESO. The pipeline has been developed for two main functions. The first function is to monitor the operation of the instrument through the reduction of the acquired data, both at Paranal, for a quick-look control, and in Garching, for a more thorough evaluation. The second function is to allow an optimized data reduction for a scientific user. In the following I will first outline the main steps of data reduction with the pipeline then I will briefly show two examples of optimization of the results for science reduction. </li> <li> <a target="_blank" rel="noopener noreferrer" onclick="trackOutboundLink('http://adsabs.harvard.edu/abs/2016JSV...376...95V','NASAADS'); return false;" href="http://adsabs.harvard.edu/abs/2016JSV...376...95V">Topology optimization of two-dimensional elastic wave barriers</a> <a target="_blank" rel="noopener noreferrer" href="http://adsabs.harvard.edu/abstract_service.html">NASA Astrophysics Data System (ADS)</a> Van hoorickx, C.; Sigmund, O.; Schevenels, M.; Lazarov, B. S.; Lombaert, G. 2016-08-01 Topology optimization is a method that optimally distributes material in a given design domain. In this paper, topology optimization is used to design two-dimensional wave barriers embedded in an elastic halfspace. First, harmonic vibration sources are considered, and stiffened material is inserted into a design domain situated between the source and the receiver to minimize wave transmission. At low frequencies, the stiffened material reflects and guides waves away from the surface. At high frequencies, destructive interference is obtained that leads to high values of the insertion loss. To handle harmonic sources at a frequency in a given range, a uniform reduction of the response over a frequency range is pursued. The minimal insertion loss over the frequency range of interest is maximized. The resulting design contains features at depth leading to a reduction of the insertion loss at the lowest frequencies and features close to the surface leading to a reduction at the highest frequencies. For broadband sources, the average insertion loss in a frequency range is optimized. This leads to designs that especially reduce the response at high frequencies. The designs optimized for the frequency averaged insertion loss are found to be sensitive to geometric imperfections. In order to obtain a robust design, a worst case approach is followed. </li> </ol> <div class="pull-right"> <ul class="pagination"> <li><a href="#" onclick='return showDiv("page_1");'>«</a></li> <li><a href="#" onclick='return showDiv("page_21");'>21</a></li> <li><a href="#" onclick='return showDiv("page_22");'>22</a></li> <li><a href="#" onclick='return showDiv("page_23");'>23</a></li> <li><a href="#" onclick='return showDiv("page_24");'>24</a></li> <li class="active">25</li> <li><a href="#" onclick='return showDiv("page_25");'>»</a></li> </ul> </div> </div> </div> </div> <div class="footer-extlink text-muted" style="margin-bottom:1rem; text-align:center;">Some links on this page may take you to non-federal websites. 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Sample records for optimizing biogeochemical reduction