40 CFR 63.822 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the MSDS meets the data requirements of § 63.827(b) and (c). The purpose of the CPDS is to assist the... weight-fraction, kg/kg. (4) Chij=the organic HAP content of solvent j, added to solids-containing material i, expressed as a weight-fraction, kg/kg. (5) Chj=the organic HAP content of solvent j, expressed...

40 CFR 63.498 - Back-end process provisions-recordkeeping.

Code of Federal Regulations, 2011 CFR

2011-07-01

... be the crumb rubber dry weight of the rubber leaving the stripper. (iv) The organic HAP content of... be the crumb rubber dry weight of the crumb rubber leaving the stripper. (iii) The hourly average of... test runs. (1) The uncontrolled residual organic HAP content in the latex or dry crumb rubber, as...

40 CFR 63.498 - Back-end process provisions-recordkeeping.

Code of Federal Regulations, 2012 CFR

2012-07-01

... be the crumb rubber dry weight of the rubber leaving the stripper. (iv) The organic HAP content of... be the crumb rubber dry weight of the crumb rubber leaving the stripper. (iii) The hourly average of... test runs. (1) The uncontrolled residual organic HAP content in the latex or dry crumb rubber, as...

40 CFR 63.498 - Back-end process provisions-recordkeeping.

Code of Federal Regulations, 2014 CFR

2014-07-01

... be the crumb rubber dry weight of the rubber leaving the stripper. (iv) The organic HAP content of... be the crumb rubber dry weight of the crumb rubber leaving the stripper. (iii) The hourly average of... test runs. (1) The uncontrolled residual organic HAP content in the latex or dry crumb rubber, as...

40 CFR 63.498 - Back-end process provisions-recordkeeping.

Code of Federal Regulations, 2013 CFR

2013-07-01

... be the crumb rubber dry weight of the rubber leaving the stripper. (iv) The organic HAP content of... be the crumb rubber dry weight of the crumb rubber leaving the stripper. (iii) The hourly average of... test runs. (1) The uncontrolled residual organic HAP content in the latex or dry crumb rubber, as...

40 CFR 63.5798 - What if I want to use, or I manufacture, an application technology (new or existing) whose...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Pollutants: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open... organic HAP emissions test data obtained using EPA test methods or their equivalent. The emission test data should be obtained using a range of resin or gel coat HAP contents to demonstrate the...

40 CFR 63.5798 - What if I want to use, or I manufacture, an application technology (new or existing) whose...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Pollutants: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open... organic HAP emissions test data obtained using EPA test methods or their equivalent. The emission test data should be obtained using a range of resin or gel coat HAP contents to demonstrate the...

40 CFR 63.5798 - What if I want to use, or I manufacture, an application technology (new or existing) whose...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Pollutants: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open... organic HAP emissions test data obtained using EPA test methods or their equivalent. The emission test data should be obtained using a range of resin or gel coat HAP contents to demonstrate the...

40 CFR 63.829 - Recordkeeping requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... mass of all HAP containing materials used and the mass fraction of HAP present in each HAP containing... the criteria of § 63.821(b)(1), the owner or operator shall maintain records of the total mass of each... maintain records of the total mass and organic HAP content of each material applied on product and...

40 CFR 63.829 - Recordkeeping requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... mass of all HAP containing materials used and the mass fraction of HAP present in each HAP containing... the criteria of § 63.821(b)(1), the owner or operator shall maintain records of the total mass of each... maintain records of the total mass and organic HAP content of each material applied on product and...

40 CFR 63.829 - Recordkeeping requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... mass of all HAP containing materials used and the mass fraction of HAP present in each HAP containing... the criteria of § 63.821(b)(1), the owner or operator shall maintain records of the total mass of each... maintain records of the total mass and organic HAP content of each material applied on product and...

40 CFR 63.829 - Recordkeeping requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... mass of all HAP containing materials used and the mass fraction of HAP present in each HAP containing... the criteria of § 63.821(b)(1), the owner or operator shall maintain records of the total mass of each... maintain records of the total mass and organic HAP content of each material applied on product and...

40 CFR 63.5797 - How do I determine the organic HAP content of my resins and gel coats?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Plastic Composites Production Calculating Organic Hap Emissions Factors for Open Molding and Centrifugal... material manufacturer, such as manufacturer's formulation data and material safety data sheets (MSDS...

40 CFR 63.5797 - How do I determine the organic HAP content of my resins and gel coats?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Plastic Composites Production Calculating Organic Hap Emissions Factors for Open Molding and Centrifugal... material manufacturer, such as manufacturer's formulation data and material safety data sheets (MSDS...

40 CFR 63.5797 - How do I determine the organic HAP content of my resins and gel coats?

Code of Federal Regulations, 2014 CFR

2014-07-01

...: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open Molding and... the material manufacturer, such as manufacturer's formulation data and material safety data sheets...

40 CFR 63.5797 - How do I determine the organic HAP content of my resins and gel coats?

Code of Federal Regulations, 2013 CFR

2013-07-01

...: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open Molding and... the material manufacturer, such as manufacturer's formulation data and material safety data sheets...

40 CFR 63.5749 - How do I calculate the organic HAP content of aluminum wipedown solvents?

Code of Federal Regulations, 2011 CFR

2011-07-01

... the past 12 months, liters. Dj= density of aluminum wipedown solvent j, kilograms per liter. Wj= mass fraction of organic HAP in aluminum wipedown solvent j. m = number of different aluminum surface coatings...

40 CFR Table 8 to Subpart Wwww of... - Initial Compliance With Organic HAP Emissions Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

... SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Reinforced Plastic... organic HAP emissions limit . . . You have demonstrated initial complianceif . . . 1. open molding and... contents. 2. open molding centrifugal casting, continuous lamination/casting, SMC and BMC manufacturing...

40 CFR Table 8 to Subpart Wwww of... - Initial Compliance With Organic HAP Emissions Limits

Code of Federal Regulations, 2011 CFR

2011-07-01

... organic HAP emissions limit . . . You have demonstrated initial complianceif . . . 1. open molding and... contents. 2. open molding centrifugal casting, continuous lamination/casting, SMC and BMC manufacturing... die injection, and/or wet-area enclosures that meet the criteria of § 63.5830. 6. pultrusion...

40 CFR 63.5753 - How do I calculate the combined organic HAP content of aluminum wipedown solvents and aluminum...

Code of Federal Regulations, 2010 CFR

2010-07-01

... HAP content of aluminum wipedown solvents and aluminum recreational boat surface coatings? 63.5753... Standards for Hazardous Air Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat... wipedown solvents and aluminum recreational boat surface coatings? (a) Use equation 1 of this section to...

40 CFR 63.5753 - How do I calculate the combined organic HAP content of aluminum wipedown solvents and aluminum...

Code of Federal Regulations, 2011 CFR

2011-07-01

... HAP content of aluminum wipedown solvents and aluminum recreational boat surface coatings? 63.5753... Standards for Hazardous Air Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat... wipedown solvents and aluminum recreational boat surface coatings? (a) Use equation 1 of this section to...

Multi-walled carbon nanotubes/graphene oxide hybrid and nanohydroxyapatite composite: A novel coating to prevent dentin erosion.

PubMed

Nahorny, Sídnei; Zanin, Hudson; Christino, Vinie Abreu; Marciano, Fernanda Roberta; Lobo, Anderson Oliveira; Soares, Luís Eduardo Silva

2017-10-01

To date is emergent the development of novel coatings to protect erosion, especially to preventive dentistry and restorative dentistry. Here, for the first time we report the effectiveness of multi-walled carbon nanotube/graphene oxide hybrid carbon-base material (MWCNTO-GO) combined with nanohydroxyapatite (nHAp) as a protective coating for dentin erosion. Fourier transform Raman spectroscopy (FT-Raman), scanning electron (SEM), and transmission electron (TEM) microscopy were used to investigated the coatings and the effect of acidulated phosphate fluoride gel (APF) treatment on bovine teeth root dentin before and after erosion. The electrochemical corrosion performance of the coating was evaluated. Raman spectra identified that: (i) the phosphate (ν 1 PO 4 3- ) content of dentin was not significantly affected by the treatments and (ii) the carbonate (ν 1 CO 3 2- ) content in dentin increased when nHAp was used. However, the nHAp/MWCNTO-GO composite exposited lower levels of organic matrix (CH bonds) after erosion compared to other treatments. Interesting, SEM micrographs identified that the nHAp/MWCNTO-GO formed layers after erosive cycling when associate with APF treatment, indicating a possible chemical bond among them. Treatments of root dentin with nHAp, MWCNTO-GO, APF_MWCNTO-GO, and APF_nHAp/MWCNTO-GO increased the carbonate content, carbonate/phosphate ratio, and organic matrix band area after erosion. The potentiodynamic polarization curves and Nyquist plot showed that nHAp, MWCNT-GO and nHAp/MWCNT-GO composites acted as protective agents against corrosion process. Clearly, the nHAp/MWCNTO-GO composite was stable after erosive cycling and a thin and acid-resistant film was formed when associated to APF treatment. Copyright © 2017 Elsevier B.V. All rights reserved.

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.4371 - What definitions apply to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... wiper blades. Thus, it includes any cleaning material used in the web coating and printing subcategory... process operation run at atmospheric pressure would be a different operating scenario from the same dyeing process operation run under pressure. Organic HAP content means the mass of organic HAP per mass of solids...

40 CFR 63.5749 - How do I calculate the organic HAP content of aluminum wipedown solvents?

Code of Federal Regulations, 2013 CFR

2013-07-01

... solvents, kilograms of HAP per liter of total coating solids from aluminum primers, top coats, and clear... = volume of aluminum primer, top coat, or clear coat i used in the past 12 months, liters. Solidsi= solids content aluminum primer, top coat, or clear coat i, liter solids per liter of coating. (b) Compliance is...

40 CFR 63.5749 - How do I calculate the organic HAP content of aluminum wipedown solvents?

Code of Federal Regulations, 2012 CFR

2012-07-01

... solvents, kilograms of HAP per liter of total coating solids from aluminum primers, top coats, and clear... = volume of aluminum primer, top coat, or clear coat i used in the past 12 months, liters. Solidsi= solids content aluminum primer, top coat, or clear coat i, liter solids per liter of coating. (b) Compliance is...

40 CFR 63.5749 - How do I calculate the organic HAP content of aluminum wipedown solvents?

Code of Federal Regulations, 2014 CFR

2014-07-01

... solvents, kilograms of HAP per liter of total coating solids from aluminum primers, top coats, and clear... = volume of aluminum primer, top coat, or clear coat i used in the past 12 months, liters. Solidsi = solids content aluminum primer, top coat, or clear coat i, liter solids per liter of coating. (b) Compliance is...

40 CFR Table 1 to Subpart Bbbbb of... - Requirements for Performance Tests

Code of Federal Regulations, 2014 CFR

2014-07-01

... HAP used as the calibration gas must be the single organic HAP representing the largest percent of... determining compliance with a ppmv concentration limit. c. Conduct gas molecular weight analysis i. Method 3... York, NY 10016-5990) as an alternative to EPA Method 3B. d. Measure moisture content of the stack gas...

40 CFR 63.4981 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... recordkeeping when data are based on a business accounting period. Organic HAP content means the mass of organic... CFR 70.2. Startup, initial means the first time equipment is brought online in a facility. Surface...

40 CFR 63.5997 - How do I conduct tests and procedures for tire cord production affected sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

...) to confirm the reported HAP content. If the results of an analysis by EPA Method 311 are different... determinations. (2) Unless you demonstrate otherwise, the HAP content analysis must be based on coatings prior to...) Methods to determine the mass percent of each HAP in coatings. (1) To determine the HAP content in the...

40 CFR 63.1104 - Process vents from continuous unit operations: applicability assessment procedures and methods.

Code of Federal Regulations, 2010 CFR

2010-07-01

... accordance with the applicable weight-percent, TOC concentration, or organic HAP concentration requirement in... rate, regulated organic HAP concentration, total organic HAP or TOC concentration, heating value, and... volumetric flow rate, regulated organic HAP concentration, total organic HAP or TOC concentration, and any...

40 CFR 63.3531 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... fraction of organic HAP for each material. Determine the mass fraction of organic HAP for each coating and... coating. Wc,i = Mass fraction of organic HAP in coating, i, kg organic HAP per kg coating. m = Number of...,j = Density of thinner, j, kg per liter. Wt,j = Mass fraction of organic HAP in thinner, j, kg...

40 CFR 63.4151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... option. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of... coating per liter coating. Wc,i = mass fraction of organic HAP in coating, i, kg organic HAP per kg... thinner per liter thinner. Wt,j = mass fraction of organic HAP in thinner, j, kg organic HAP per kg...

40 CFR 63.3531 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... fraction of organic HAP for each material. Determine the mass fraction of organic HAP for each coating and... coating. Wc,i = Mass fraction of organic HAP in coating, i, kg organic HAP per kg coating. m = Number of...,j = Density of thinner, j, kg per liter. Wt,j = Mass fraction of organic HAP in thinner, j, kg...

40 CFR 63.3531 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... fraction of organic HAP for each material. Determine the mass fraction of organic HAP for each coating and... coating. Wc,i = Mass fraction of organic HAP in coating, i, kg organic HAP per kg coating. m = Number of...,j = Density of thinner, j, kg per liter. Wt,j = Mass fraction of organic HAP in thinner, j, kg...

40 CFR 63.4151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... option. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of... coating per liter coating. Wc,i = mass fraction of organic HAP in coating, i, kg organic HAP per kg... thinner per liter thinner. Wt,j = mass fraction of organic HAP in thinner, j, kg organic HAP per kg...

40 CFR Table 6 to Subpart Vvvv of... - Default Organic HAP Contents of Petroleum Solvent Groups

Code of Federal Regulations, 2010 CFR

2010-07-01

... Spirits 150 EC, Naphtha, Mixed Hydrocarbon, Aliphatic Hydrocarbon, Aliphatic Naptha, Naphthol Spirits... Aromatic Naphtha, Light Aromatic Hydrocarbons, Aromatic Hydrocarbons, Light Aromatic Solvent.) 6 4% Xylene...

40 CFR 63.5390 - How do I measure the HAP content of a finish?

Code of Federal Regulations, 2010 CFR

2010-07-01

... analysis by EPA Method 311 are different from the HAP content determined by another means, the EPA Method... content analysis as determined in paragraph (a) of this section for each finish when you perform one of... 40 Protection of Environment 12 2010-07-01 2010-07-01 true How do I measure the HAP content of a...

40 CFR 63.3360 - What performance tests must I conduct?

Code of Federal Regulations, 2012 CFR

2012-07-01

... monthly liquid-liquid material balance. (c) Organic HAP content. If you determine compliance with the... alternative to Method 3B the manual method for measuring the oxygen, carbon dioxide, and carbon monoxide... meters (dscm)/h. Cc = Concentration of organic compounds as carbon, ppmv. 12.0 = Molecular weight of...

40 CFR 63.3360 - What performance tests must I conduct?

Code of Federal Regulations, 2013 CFR

2013-07-01

... monthly liquid-liquid material balance. (c) Organic HAP content. If you determine compliance with the... alternative to Method 3B the manual method for measuring the oxygen, carbon dioxide, and carbon monoxide... meters (dscm)/h. Cc = Concentration of organic compounds as carbon, ppmv. 12.0 = Molecular weight of...

40 CFR 63.3360 - What performance tests must I conduct?

Code of Federal Regulations, 2014 CFR

2014-07-01

... monthly liquid-liquid material balance. (c) Organic HAP content. If you determine compliance with the... alternative to Method 3B the manual method for measuring the oxygen, carbon dioxide, and carbon monoxide... meters (dscm)/h. Cc = Concentration of organic compounds as carbon, ppmv. 12.0 = Molecular weight of...

40 CFR 63.5752 - How do I calculate the organic HAP content of aluminum recreational boat surface coatings?

Code of Federal Regulations, 2011 CFR

2011-07-01

... content of aluminum recreational boat surface coatings? 63.5752 Section 63.5752 Protection of Environment... AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Boat Manufacturing Standards for Aluminum Recreational Boat Surface Coating Operations § 63.5752 How do I calculate...

40 CFR Figure 1 to Subpart Tttt of... - Example Logs for Recording Leather Finish Use and HAP Content

Code of Federal Regulations, 2010 CFR

2010-07-01

... Finishing Operations Part 63, Subpt. TTTT, Fig. 1 Figure 1 to Subpart TTTT of Part 63—Example Logs for Recording Leather Finish Use and HAP Content Month:______Year:______ Finish Inventory Log Finish type Finish usage(pounds) HAP Content(mass fraction) Date and time Operator's name Product process operation Monthly...

40 CFR 63.3360 - What performance tests must I conduct?

Code of Federal Regulations, 2010 CFR

2010-07-01

... decimal point (for example, 0.763). (2) Method 24. For coatings, determine the volatile organic content as... National Emission Standards for Hazardous Air Pollutants: Paper and Other Web Coating General Requirements... control organic HAP on any individual web coating line or any group of web coating lines by: You must: (1...

40 CFR 63.3360 - What performance tests must I conduct?

Code of Federal Regulations, 2011 CFR

2011-07-01

... decimal point (for example, 0.763). (2) Method 24. For coatings, determine the volatile organic content as... National Emission Standards for Hazardous Air Pollutants: Paper and Other Web Coating General Requirements... control organic HAP on any individual web coating line or any group of web coating lines by: You must: (1...

40 CFR 63.4741 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... compliant material option. If the mass fraction of organic HAP of a coating equals zero, determined... fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified...

40 CFR 63.4141 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... the compliant material option. If the mass fraction of organic HAP of a coating equals zero... fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified...

40 CFR 63.4141 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... the compliant material option. If the mass fraction of organic HAP of a coating equals zero... fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified...

40 CFR 63.4741 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... compliant material option. If the mass fraction of organic HAP of a coating equals zero, determined... fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified...

40 CFR 63.116 - Process vent provisions-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2010 CFR

2010-07-01

... conduct a performance test to determine percent emission reduction or outlet organic HAP or TOC... organic HAP concentration and percent reduction may be measured as either total organic HAP or as TOC... measurement of total organic HAP or TOC (minus methane and ethane) concentrations in all vent streams and...

40 CFR 63.1326 - Batch process vents-recordkeeping provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... single highest-HAP recipe. (3) Total annual uncontrolled TOC or organic HAP emissions, determined at the...): (i) For an incinerator or non-combustion control device, the percent reduction of organic HAP or TOC... percent reduction of organic HAP or TOC achieved, as determined using the procedures specified in § 63...

40 CFR 63.4320 - By what date must I conduct the initial compliance demonstration?

Code of Federal Regulations, 2010 CFR

2010-07-01

... period, the organic HAP content of each coating and printing material you applied and the mass fraction... applicable limit in Table 1 to this subpart, and documentation that in web coating/printing operations you...

40 CFR 63.3951 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... reclaimed. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of... coating per liter coating. Wc,i = Mass fraction of organic HAP in coating, i, kg organic HAP per kg coating. For reactive adhesives as defined in § 63.3981, use the mass fraction of organic HAP that is...

40 CFR 63.4321 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... dyeing or finishing material with a mass fraction of organic HAP that exceeds the applicable emission... fraction of organic HAP for each material. You must determine the mass fraction of organic HAP for each... (appendix A to 40 CFR part 63). You may use Method 311 for determining the mass fraction of organic HAP. Use...

40 CFR 63.4321 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... dyeing or finishing material with a mass fraction of organic HAP that exceeds the applicable emission... fraction of organic HAP for each material. You must determine the mass fraction of organic HAP for each... (appendix A to 40 CFR part 63). You may use Method 311 for determining the mass fraction of organic HAP. Use...

40 CFR 63.3951 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... reclaimed. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of... coating per liter coating. Wc,i = Mass fraction of organic HAP in coating, i, kg organic HAP per kg coating. For reactive adhesives as defined in § 63.3981, use the mass fraction of organic HAP that is...

40 CFR 63.3951 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... reclaimed. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of... coating per liter coating. Wc,i = Mass fraction of organic HAP in coating, i, kg organic HAP per kg coating. For reactive adhesives as defined in § 63.3981, use the mass fraction of organic HAP that is...

40 CFR 63.3531 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2011 CFR

2011-07-01

... be performed with either metric or English units. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of organic HAP for each coating and thinner used during each... thinner, j, kg per liter. Wt,j = Mass fraction of organic HAP in thinner, j, kg organic HAP per kg thinner...

Surface-modified silk hydrogel containing hydroxyapatite nanoparticle with hyaluronic acid-dopamine conjugate.

PubMed

Kim, Hyung Hwan; Park, Jong Bo; Kang, Min Ji; Park, Young Hwan

2014-09-01

Silk fibroin/hydroxyapatite (SF/HAp) composite hydrogels were fabricated in this study, having different HAp contents (0-33 wt%) in SF matrix hydrogel. Surface modification of HAp nanoparticle with hyaluronic acid (HA)-dopamine (DA) conjugate improved a dispersibility of HAp in aqueous SF solution due to its negatively charged surface and therefore, fabrication of the SF composite hydrogel having HAp nanoparticles inside could be possible. Zeta potential of surface-modified HAP was examined by ELS. It demonstrates that surface of HAp was well modified to a negative charge with HA-DA. Morphological structure of SF hydrogel containing surface-modified HAp was examined by FE-SEM for analyzing pore structure of hydrogel and deposition of HAp nanoparticle in SF hydrogel. It was found that HAp nanoparticles were uniformly deposited on the pore wall of SF hydrogel. Structural characteristics of SF/HAp composite hydrogel was performed using X-ray diffraction and FT-IR analysis. It was found that β-sheet crystal conformation of SF was significantly influenced by the HAp content during gelation of a mixture of SF and HAp. As a result of MTT assay, the SF/HAp composite hydrogel showed excellent cell proliferation ability. Therefore, it is expected that SF hydrogel containing HAp nanoparticles has a high potential as bone regeneration scaffold. Copyright © 2014 Elsevier B.V. All rights reserved.

40 CFR 63.5796 - What are the organic HAP emissions factor equations in Table 1 to this subpart, and how are they...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Organic Hap Emissions Factors for Open Molding and Centrifugal Casting § 63.5796 What are the organic HAP... emissions factors. Equations are available for each open molding operation and centrifugal casting operation... incorporated in the facility's air emissions permit and are based on actual facility HAP emissions test data...

40 CFR 63.5796 - What are the organic HAP emissions factor equations in Table 1 to this subpart, and how are they...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Organic Hap Emissions Factors for Open Molding and Centrifugal Casting § 63.5796 What are the organic HAP... emissions factors. Equations are available for each open molding operation and centrifugal casting operation... incorporated in the facility's air emissions permit and are based on actual facility HAP emissions test data...

40 CFR 63.5796 - What are the organic HAP emissions factor equations in Table 1 to this subpart, and how are they...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Organic Hap Emissions Factors for Open Molding and Centrifugal Casting § 63.5796 What are the organic HAP... emissions factors. Equations are available for each open molding operation and centrifugal casting operation... incorporated in the facility's air emissions permit and are based on actual facility HAP emissions test data...

Hydroxyapatite-based sorbents: elaboration, characterization and application for the removal of catechol from the aqueous phase.

PubMed

Sebei, Haroun; Pham Minh, Doan; Lyczko, Nathalie; Sharrock, Patrick; Nzihou, Ange

2017-10-01

Hydroxyapatite (HAP) is highly considered as good sorbent for the removal of metals from the aqueous phase. However, soluble metals co-exist with organic pollutants in wastewaters. But little work has been devoted to investigate the reactivity of HAP for the removal of organic compounds. The main objective of this work is to study the reactivity of HAP-based sorbents for the removal of catechol as a model organic pollutant from an aqueous solution. Thus, HAP sorbents were firstly synthesized using calcium carbonate and potassium dihydrogen phosphate under moderate conditions (25-80°C, atmospheric pressure). A zinc-doped HAP was also used as sorbent, which was obtained from the contact of HAP with an aqueous solution of zinc nitrate. All the sorbents were characterized by different standard physico-chemical techniques. The sorption of catechol was carried out in a batch reactor under stirring at room temperature and pressure. Zinc-doped HAP sorbent was found to be more reactive than non-doped HAP sorbents for the fixation of catechol. The highest sorption capacity was of 15 mg of C per gram of zinc-doped HAP sorbent. The results obtained suggest the reaction scheme of HAP sorbents with metals and organic pollutants when HAP sorbents were used for the treatment of complex wastewaters.

Hydroxyapatite moldable formulation using natural rubber latex as binder.

PubMed

Sailaja, G S; Ramesh, P; Varma, H K

2007-07-01

A simple but efficient processing method for shaping intricate bioceramic green bodies has been developed by using natural rubber latex as binder. Different shapes of hydroxyapatite Ca10(PO4)6(OH)2 (HAP) were molded from a composite formulation containing wet precipitated HAP, natural rubber latex (NRL), and a stabilizer. On controlled heat treatment followed by sintering, dense shapes of HAP contours were obtained. The thermal degradation profile of HAP-NRL composites shows that NRL degrades slowly without any abrupt exotherm. The results of energy dispersive X-ray analysis together with inductively coupled plasma (ICP) analysis indicate that the inorganic residue of NRL does not contain any heavy element. The sintered density of the samples increased with increased HAP content in the formulation and percentage shrinkage reduced accordingly. On varying the HAP content in the formulation from 35 to 95 wt %, the compositions with 85, 90, 92, and 95 wt % HAP showed better flexural strength in the range 40-54 MPa and a flexural modulus value in the range 36-50 GPa. The fracture morphology, as observed by the scanning electron microscope confirms that with increased HAP content in the formulation the sample microstructure attains higher uniformity. The Vickers microhardness for the samples sintered at two different temperatures (1150 and 1250 degrees C) showed that hardness increases with increase in the sintering temperature with a maximum for the highest HAP loaded formulation. Copyright 2006 Wiley Periodicals, Inc.

40 CFR 63.5752 - How do I calculate the organic HAP content of aluminum recreational boat surface coatings?

Code of Federal Regulations, 2010 CFR

2010-07-01

... clear coat i used in the past 12 months, liters. Di= density of coating i, kilograms per liter. Wi= mass... of thinner, activator, or additive k used in the past 12 months, liters. Dk= density of thinner...

40 CFR 63.3151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants... separately calculate the mass average organic HAP content of the materials used during the initial compliance...

40 CFR 63.3151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants... separately calculate the mass average organic HAP content of the materials used during the initial compliance...

Effect of ring-opening polymerization condition on the characteristic and mechanical properties of hydroxyapatite/poly(ethylene glutarate) biomaterials.

PubMed

Monvisade, Pathavuth; Siriphannon, Punnama; Tapcharoen, Walailak

2009-09-01

Preparation of hydroxyapatite/poly(ethylene glutarate) (HAp/PEG) composites was carried out by ring-opening polymerization (ROP) of cyclic oligo(ethylene glutarate) in porous HAp scaffolds using various reaction temperatures and times. The content of ROP-PEG interpenetrated into the porous HAp scaffold was about 13-18 wt % with the values of number average molecular weight (overline_M{n}) and weight average molecular weight (overline_M{W}) of 2120-3630 and 2760-5250 g/mol, respectively. The increase in polymerization time and temperature brought about increase in molecular weight of ROP-PEG, but decrease in its content. Compressive strength and compressive modulus of the HAp/PEG composites were about 5.8-20.1 and 105-208 MPa, respectively. These mechanical properties depend upon the effects of distribution, content, and molecular weight of ROP-PEG in the composites. In vitro bioactivity of the HAp/PEG composites was studied by soaking them in simulated body fluid (SBF) for 28 days. The formation of HAp nanocrystal on the composite surfaces through the consumption of calcium and phosphorus from the SBF solution was observed after soaking, indicating the bioactivity of these HAp/PEG composites.

Properties of tungsten coating deposited onto copper by high-speed atmospheric plasma spraying

NASA Astrophysics Data System (ADS)

Jianjun, Huang; Fan, Wang; Ying, Liu; Shishou, Jiang; Xisheng, Wang; Bing, Qi; Liang, Gao

2011-07-01

Tungsten (W) coatings were fabricated on copper (Cu) by high-speed atmospheric plasma spray (HAPS) technique. The properties of the porosity, oxygen content, bonding strength and microhardness were measured. The results obtained indicated that the HAPS-W coating showed good properties particularly in terms of porosity and oxygen content. The porosity of the HAPS-W coating was 2.3% and the distribution of pore size diameter was mainly concentrated in the range of 0.01-1 μm. The oxygen content of the coating measured by means of Nitrogen/Oxygen Determinator was about 0.10 wt.%. These initial results suggest that the HAPS-W coating has achieved the reported properties of the vacuum plasma spray (VPS) W coating. Compared with VPS, HAPS-W technique could provide a convenient and low cost way to obtain adequate W coatings for fusion applications.

Study on the removal of organic micropollutants from aqueous and ethanol solutions by HAP membranes with tunable hydrophilicity and hydrophobicity.

PubMed

He, Junyong; Li, Yulian; Cai, Xingguo; Chen, Kai; Zheng, Hejing; Wang, Chengming; Zhang, Kaisheng; Lin, Dongyue; Kong, Lingtao; Liu, Jinhuai

2017-05-01

A biocompatible and uniquely defined hydroxyapatite (HAP) adsorption membrane with a sandwich structure was developed for the removal of organic micropollutants for the first time. Both the adsorption and membrane technique were used for the removal of organic micropollutants. The hydrophilicity and hydrophobicity of the HAP adsorbent and membrane were tunable by controlling the surface structure of HAP. The adsorption of organic micropollutants on the HAP adsorbent was studied in batch experiments. The adsorption process was fit with the Freundlich model, while the adsorption kinetics followed the pseudo-second-order model. The HAP membrane could remove organic micropollutants effectively by dynamic adsorption in both aqueous and ethanol solutions. The removal efficiencies of organic micropollutants depended on the solution composition, membrane thickness and hydrophilicity, flow rate, and the initial concentration of organic micropollutants. The adsorption capacities of the HAP membrane with a sandwich structure (membrane thickness was 0.3 mm) were 6700, 6510, 6310, 5960, 5490, 5230, 4980 and 4360 L m -2 for 1-naphthyl amine, 2-naphthol, bisphenol S, propranolol hydrochloride, metolachlor, ethinyl oestradiol, 2,4-dichlorophenol and bisphenol A, respectively, when the initial concentration was 3.0 mg L -1 . The biocompatible HAP adsorption membrane can be easily regenerated by methanol and was thus demonstrated to be a novel concept for the removal of organic micropollutants from both aqueous and organic solutions. Copyright © 2017 Elsevier Ltd. All rights reserved.

40 CFR 63.825 - Standards: Product and packaging rotogravure and wide-web flexographic printing.

Code of Federal Regulations, 2014 CFR

2014-07-01

... inks, coatings, varnishes, adhesives, primers, solvents, reducers, thinners, and other materials... calculated equivalent allowable mass based on the organic HAP and solids contents of the inks, coatings... (b)(1) through (b)(10) of this section: (1) Demonstrate that each ink, coating, varnish, adhesive...

40 CFR 63.825 - Standards: Product and packaging rotogravure and wide-web flexographic printing.

Code of Federal Regulations, 2013 CFR

2013-07-01

... inks, coatings, varnishes, adhesives, primers, solvents, reducers, thinners, and other materials... calculated equivalent allowable mass based on the organic HAP and solids contents of the inks, coatings... (b)(1) through (b)(10) of this section: (1) Demonstrate that each ink, coating, varnish, adhesive...

40 CFR 63.825 - Standards: Product and packaging rotogravure and wide-web flexographic printing.

Code of Federal Regulations, 2012 CFR

2012-07-01

... inks, coatings, varnishes, adhesives, primers, solvents, reducers, thinners, and other materials... calculated equivalent allowable mass based on the organic HAP and solids contents of the inks, coatings... (b)(1) through (b)(10) of this section: (1) Demonstrate that each ink, coating, varnish, adhesive...

40 CFR Table 5 to Subpart Vvvv of... - Default Organic HAP Contents of Solvents and Solvent Blends

Code of Federal Regulations, 2010 CFR

2010-07-01

...-88-3 100 Toluene. 2. Xylene(s) 1330-20-7 100 Xylenes, ethylbenzene. 3. Hexane 110-54-3 50 n-hexane. 4. n-hexane 110-54-3 100 n-hexane. 5. Ethylbenzene 100-41-4 100 Ethylbenzene. 6. Aliphatic 140 0 None...

40 CFR Table 5 to Subpart Vvvv of... - Default Organic HAP Contents of Solvents and Solvent Blends

Code of Federal Regulations, 2011 CFR

2011-07-01

...-88-3 100 Toluene. 2. Xylene(s) 1330-20-7 100 Xylenes, ethylbenzene. 3. Hexane 110-54-3 50 n-hexane. 4. n-hexane 110-54-3 100 n-hexane. 5. Ethylbenzene 100-41-4 100 Ethylbenzene. 6. Aliphatic 140 0 None...

40 CFR 63.3152 - How do I demonstrate continuous compliance with the emission limitations?

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of... compliance, the mass average organic HAP content for each compliance period, determined according to § 63...

40 CFR 63.3150 - By what date must I conduct the initial compliance demonstration?

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of Automobiles and Light... month. You must determine the mass average organic HAP content of the materials used each month for each...

40 CFR 63.3151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of... mass average organic HAP content of the materials used during the initial compliance period for each...

40 CFR 63.4311 - What reports must I submit?

Code of Federal Regulations, 2010 CFR

2010-07-01

...-on controls, or the organic HAP overall control efficiency compliance option for web coating/printing... emission rate with add-on controls option, the organic HAP overall control efficiency option, or the oxidizer outlet organic HAP concentration option and there were no periods during which the continuous...

40 CFR Table 2 to Subpart Eeee of... - Emission Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

... emissions of total organic HAP (or, upon approval, TOC) by at least 95 weight-percent or, as an option, to... organic HAP (or, upon approval, TOC) by at least 95 weight-percent or, as an option, to an exhaust... total organic HAP (or, upon approval, TOC) from the loading of organic liquids either by venting the...

40 CFR 63.654 - Heat exchange systems.

Code of Federal Regulations, 2012 CFR

2012-07-01

... section. (1) All heat exchangers that are in organic HAP service within the heat exchange system that...., the heat exchange system does not contain any heat exchangers that are in organic HAP service as... exchange system in organic HAP service or from each heat exchanger exit line for each heat exchanger or...

40 CFR 63.654 - Heat exchange systems.

Code of Federal Regulations, 2011 CFR

2011-07-01

... section. (1) All heat exchangers that are in organic HAP service within the heat exchange system that...., the heat exchange system does not contain any heat exchangers that are in organic HAP service as... exchange system in organic HAP service or from each heat exchanger exit line for each heat exchanger or...

Source reduction of VOC and hazardous organic emissions from wood furniture coatings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, E.W.; McCrillis, R.C.

1996-12-31

Under US EPA sponsorship, AeroVironment, Inc. and Adhesives Coating Co. are teaming up to develop and demonstrate a wood furniture coating system containing no volatile organic compounds (VOCs) and no hazardous air pollutants (HAPs), making it less hazardous to use, and emitting no detectable VOCs and HAPs during curing, therefore contributing significantly to emission reduction. Earlier work on a new topcoat showed excellent performance characteristics in terms of adhesion, gloss value, dry time, hardness, organic solvents content, and chemical/stain resistance. The VOC contents of both the clear topcoat and the white pigmented topcoat were less than 10 g/L, the detectionmore » list of the test method (EPA Method 24). This coating`s performance and properties compared favorably with those of other low-VOC waterborne coatings. Currently, low-/no-VOC stain and sealer wood coatings are being developed so that a complete low-/no-VOC wood coating system will be available for public use. The compatibility of coating components (a stain and sealer) to go with the topcoat is currently being evaluated. The complete system will be demonstrated at several furniture plants. A marketing plan of the developed products is part of this demonstration project.« less

40 CFR 63.1426 - Process vent requirements for determining organic HAP concentration, control efficiency, and...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Production § 63.1426 Process vent requirements for determining organic HAP concentration, control efficiency..., total organic HAP, or as TOC minus methane and ethane according to the procedures specified. When... methane and ethane) concentrations in all process vent streams and primary and secondary fuels introduced...

40 CFR 63.4310 - What notifications must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

... need to submit copies of any test reports. (i) Mass fraction of organic HAP and mass fraction of solids for one coating or printing formulation including thinning materials, mass fraction of organic HAP for one cleaning material and mass fraction of organic HAP for all of the regulated materials as purchased...

40 CFR 63.4130 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of... period. (e) A record of the mass fraction of organic HAP for each coating, thinner, and cleaning material...

40 CFR 63.4130 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of... period. (e) A record of the mass fraction of organic HAP for each coating, thinner, and cleaning material...

40 CFR 63.4310 - What notifications must I submit?

Code of Federal Regulations, 2012 CFR

2012-07-01

... need to submit copies of any test reports. (i) Mass fraction of organic HAP and mass fraction of solids for one coating or printing formulation including thinning materials, mass fraction of organic HAP for one cleaning material and mass fraction of organic HAP for all of the regulated materials as purchased...

40 CFR 63.4310 - What notifications must I submit?

Code of Federal Regulations, 2014 CFR

2014-07-01

... need to submit copies of any test reports. (i) Mass fraction of organic HAP and mass fraction of solids for one coating or printing formulation including thinning materials, mass fraction of organic HAP for one cleaning material and mass fraction of organic HAP for all of the regulated materials as purchased...

40 CFR 63.4130 - What records must I keep?

Code of Federal Regulations, 2013 CFR

2013-07-01

... to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of... period. (e) A record of the mass fraction of organic HAP for each coating, thinner, and cleaning material...

40 CFR 63.2525 - What records must I keep?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing Notification, Reports... because the non-reactive organic HAP is the only HAP and usage is less than 10,000 lb/yr, as specified in... report that total uncontrolled organic HAP emissions from the batch process vents in an MCPU will be less...

40 CFR 63.2525 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

...) National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing... because the non-reactive organic HAP is the only HAP and usage is less than 10,000 lb/yr, as specified in... report that total uncontrolled organic HAP emissions from the batch process vents in an MCPU will be less...

40 CFR 63.2525 - What records must I keep?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing Notification, Reports... because the non-reactive organic HAP is the only HAP and usage is less than 10,000 lb/yr, as specified in... report that total uncontrolled organic HAP emissions from the batch process vents in an MCPU will be less...

Characterization and Bioactivity Evaluation of (Polyetheretherketone/Polyglycolicacid)-Hydroyapatite Scaffolds for Tissue Regeneration

PubMed Central

Shuai, Cijun; Shuai, Chenying; Wu, Ping; Yuan, Fulai; Feng, Pei; Yang, Youwen; Guo, Wang; Fan, Xiaohan; Su, Ting; Peng, Shuping; Gao, Chengde

2016-01-01

Bioactivity and biocompatibility are crucial for tissue engineering scaffolds. In this study, hydroxyapatite (HAP) was incorporated into polyetheretherketone/polyglycolicacid (PEEK/PGA) hybrid to improve its biological properties, and the composite scaffolds were developed via selective laser sintering (SLS). The effects of HAP on physical and chemical properties of the composite scaffolds were investigated. The results demonstrated that HAP particles were distributed evenly in PEEK/PGA matrix when its content was no more than 10 wt %. Furthermore, the apatite-forming ability became better with increasing HAP content after immersing in simulated body fluid (SBF). Meanwhile, the composite scaffolds presented a greater degree of cell attachment and proliferation than PEEK/PGA scaffolds. These results highlighted the potential of (PEEK/PGA)-HAP scaffolds for tissue regeneration. PMID:28774058

40 CFR 63.5767 - What records must I keep?

Code of Federal Regulations, 2013 CFR

2013-07-01

... facility is not controlled by an add-on control device (i.e., you are complying with organic HAP content... add-on control device, you must keep the records specified in § 63.10(b) relative to control device startup, shut down, and malfunction events; control device performance tests; and continuous monitoring...

40 CFR 63.5767 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... facility is not controlled by an add-on control device (i.e., you are complying with organic HAP content... add-on control device, you must keep the records specified in § 63.10(b) relative to control device startup, shut down, and malfunction events; control device performance tests; and continuous monitoring...

40 CFR 63.5767 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... facility is not controlled by an add-on control device (i.e., you are complying with organic HAP content... add-on control device, you must keep the records specified in § 63.10(b) relative to control device startup, shut down, and malfunction events; control device performance tests; and continuous monitoring...

40 CFR 63.498 - Back-end process provisions-recordkeeping.

Code of Federal Regulations, 2010 CFR

2010-07-01

... be the crumb rubber dry weight of the rubber leaving the stripper. (iv) The organic HAP content of... stripper. (B) For solution processes, this quantity shall be the crumb rubber dry weight of the crumb rubber leaving the stripper. (iii) The hourly average of all stripper parameter results; (iv) If one or...

40 CFR Table 5 to Subpart Vvvv of... - Default Organic HAP Contents of Solvents and Solvent Blends

Code of Federal Regulations, 2012 CFR

2012-07-01

.... Toluene 108-88-3 100 Toluene. 2. Xylene(s) 1330-20-7 100 Xylenes, ethylbenzene. 3. Hexane 110-54-3 50 n-hexane. 4. n-hexane 110-54-3 100 n-hexane. 5. Ethylbenzene 100-41-4 100 Ethylbenzene. 6. Aliphatic 140 0...

40 CFR Table 5 to Subpart Vvvv of... - Default Organic HAP Contents of Solvents and Solvent Blends

Code of Federal Regulations, 2013 CFR

2013-07-01

.... Toluene 108-88-3 100 Toluene. 2. Xylene(s) 1330-20-7 100 Xylenes, ethylbenzene. 3. Hexane 110-54-3 50 n-hexane. 4. n-hexane 110-54-3 100 n-hexane. 5. Ethylbenzene 100-41-4 100 Ethylbenzene. 6. Aliphatic 140 0...

40 CFR Table 5 to Subpart Vvvv of... - Default Organic HAP Contents of Solvents and Solvent Blends

Code of Federal Regulations, 2014 CFR

2014-07-01

.... Toluene 108-88-3 100 Toluene. 2. Xylene(s) 1330-20-7 100 Xylenes, ethylbenzene. 3. Hexane 110-54-3 50 n-hexane. 4. n-hexane 110-54-3 100 n-hexane. 5. Ethylbenzene 100-41-4 100 Ethylbenzene. 6. Aliphatic 140 0...

40 CFR 63.4551 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR... organic HAP in coating, i, kg organic HAP per kg coating. For reactive adhesives as defined in § 63.4581... reactive adhesives as defined in § 63.4581, use the mass fraction of organic HAP that is emitted as...

40 CFR 63.4751 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... rate without add-on controls option. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of organic HAP for each coating, thinner, and cleaning material used during each... of coating, i, grams coating per liter coating. Wc,i = Mass fraction of organic HAP in coating, i...

40 CFR 63.4310 - What notifications must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

... according to § 63.4321(e)(1) or (2). You do not need to submit copies of any test reports. (i) Mass fraction of organic HAP and mass fraction of solids for one coating or printing formulation including thinning materials, mass fraction of organic HAP for one cleaning material and mass fraction of organic HAP for all...

40 CFR 63.3930 - What records must I keep?

Code of Federal Regulations, 2011 CFR

2011-07-01

... formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating... coating. If you conducted testing to determine mass fraction of organic HAP, density, or volume fraction... rather than a record of the volume used. (e) A record of the mass fraction of organic HAP for each...

40 CFR 63.4751 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... rate without add-on controls option. (a) Determine the mass fraction of organic HAP for each material. Determine the mass fraction of organic HAP for each coating, thinner, and cleaning material used during each... of coating, i, grams coating per liter coating. Wc,i = Mass fraction of organic HAP in coating, i...

40 CFR Table 8 to Subpart Eeee of... - Continuous Compliance With Emission Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

..., items 1 through 6 a. Reduce total organic HAP (or, upon approval, TOC) emissions from the closed vent... organic HAP (or, upon approval, TOC) in the exhaust of combustion devices i. Performing CMS monitoring and... HAP (or, upon approval, TOC) emissions during the loading of organic liquids from the closed vent...

40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2010 CFR

2010-07-01

... either total organic HAP or TOC. For purposes of this paragraph (c), the term “batch emission episode... ensure the measurement of total organic HAP or TOC (minus methane and ethane) concentrations in all batch... organic HAP or TOC, as appropriate. Alternatively, any other method or data that has been validated...

40 CFR Table 4 to Subpart Ffff of... - Emission Limits for Storage Tanks

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORIES National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical... HAP emissions by ≥95 percent by weight or to ≤20 ppmv of TOC or organic HAP and ≤20 ppmv of hydrogen... devices (excluding a flare); or ii. Reduce total organic HAP emissions by venting emissions through a...

40 CFR Table 4 to Subpart Ppp of... - Known Organic HAP From Polyether Polyol Products

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Known Organic HAP From Polyether Polyol... CATEGORIES National Emission Standards for Hazardous Air Pollutant Emissions for Polyether Polyols Production Pt. 63, Subpt. PPP, Table 4 Table 4 to Subpart PPP of Part 63—Known Organic HAP From Polyether Polyol...

Characterizing the inorganic/organic interface in cancer bone metastasis

NASA Astrophysics Data System (ADS)

Wu, Fei

Bone metastasis frequently occurs in patients with advanced breast cancer and remains a major source of mortality. At the molecular level, bone is a nanocomposite composed of inorganic bone mineral deposited within an organic extracellular matrix (ECM). Although the exact mechanisms of bone metastasis remain unclear, the nanoscale materials properties of bone mineral have been implicated in this process. Bone apatite is closely related to synthetic hydroxyapatite (HAP, Ca10(PO4)6(OH)2) in terms of structural and mechanical properties. Additionally, although the primary protein content of bone is collagen I, the glycoprotein fibronectin (Fn) is essential in maintaining the overall integrity of the bone matrix. Importantly, in vivo, neither breast cancer cells nor normal bone cells interact directly with the bone mineral but rather with the protein film adsorbed onto the mineral surface. Therefore, we hypothesized that breast cancer cell functions were regulated by differential fibronectin adsorption onto hydroxyapatite, which led to pathological remodeling of the bone matrix and sustained bone metastasis. Three model systems containing HAP and Fn were developed for this thesis. In model system I, a library of synthetic HAP nanoparticles were utilized to investigate the effect of mineral size, shape, and crystallinity on Fn conformation, using Forster resonance energy transfer (FRET) spectroscopy. In model system II, Fn-functionalized large geologic HAP crystals were used instead of HAP nanoparticles to avoid cellular uptake when investigating subsequent cell functions. Overall our FRET analysis (models I and II) revealed that Fn conformation depended on size, surface chemistry, and roughness of underlying HAP. When breast cancer cells were seeded on the Fn-coated HAP crystal facets (model II), our data indicated high secretion levels of proangiogenic and proinflammatory factors associated with the presence of unfolded Fn conformations, likely caused by differential engagement of cell receptors integrins with the underlying Fn. Finally, in model system III, Fn fibrillar structures (mimicking the bone matrix) were fabricated and characterized in presence of HAP nanoparticles, suggesting that the presence of microcalcifications found in tumorous/inflammed tissues affects both the structural and mechanical properties of the surrounding ECM. Collectively, our study of cellular behavior regulated by mineral/ECM interactions provides insights into the pathogenesis of breast cancer bone metastasis as well as other HAP-related inflammation.

40 CFR 63.3370 - How do I demonstrate compliance with the emission standards?

Code of Federal Regulations, 2014 CFR

2014-07-01

... equivalent allowable organic HAP (Equation 13a or b of § 63.3370). (4) Use of a capture system and control... control devices (i) Average equivalent organic HAP emission rate does not exceed 0.2 kg organic HAP per kg... material applied on the web coating line or group of web coating lines controlled by a common control...

40 CFR 63.3370 - How do I demonstrate compliance with the emission standards?

Code of Federal Regulations, 2012 CFR

2012-07-01

... equivalent allowable organic HAP (Equation 13a or b of § 63.3370). (4) Use of a capture system and control... control devices (i) Average equivalent organic HAP emission rate does not exceed 0.2 kg organic HAP per kg... material applied on the web coating line or group of web coating lines controlled by a common control...

40 CFR 63.3370 - How do I demonstrate compliance with the emission standards?

Code of Federal Regulations, 2013 CFR

2013-07-01

... equivalent allowable organic HAP (Equation 13a or b of § 63.3370). (4) Use of a capture system and control... control devices (i) Average equivalent organic HAP emission rate does not exceed 0.2 kg organic HAP per kg... material applied on the web coating line or group of web coating lines controlled by a common control...

40 CFR 63.3151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... paragraph (d) of this section. (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for each material used during the compliance period by... 40 CFR part 63). You may use Method 311 for determining the mass fraction of organic HAP. Use the...

40 CFR 63.1333 - Additional requirements for performance testing.

Code of Federal Regulations, 2010 CFR

2010-07-01

... paragraphs (b)(1) and (b)(2) of this section. ER19JN00.041 Where: ERMBS = Emission rate of organic HAP or TOC from continuous process vents, kg/Mg product. Ei = Emission rate of organic HAP or TOC from continuous... hours in a year for control device j. Ei=Mass rate of TOC or total organic HAP at the inlet of control...

40 CFR 63.1571 - How and when do I conduct a performance test or other initial compliance demonstration?

Code of Federal Regulations, 2010 CFR

2010-07-01

... heating value, TOC emission rate, and total organic HAP emission rate expected to yield the highest daily... conditions; (3) You may use maximum flow rate, TOC emission rate, organic HAP emission rate, or organic HAP or TOC concentration specified or implied within a permit limit applicable to the process vent; or (4...

40 CFR Table 5 to Subpart Eeee of... - Requirements for Performance Tests and Design Evaluations

Code of Federal Regulations, 2010 CFR

2010-07-01

... 1 through 10 a. A performance test to determine the organic HAP (or, upon approval, TOC) control... appendix A of 40 CFR part 63 for measuring form-aldehyde (A) Total organic HAP (or, upon approval, TOC), or... total organic HAP (or, upon approval, TOC) emissions are reduced by the required weight-percent or, as...

40 CFR 63.490 - Batch front-end process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2010 CFR

2010-07-01

... may be based on either total organic HAP or TOC. For purposes of this paragraph (c), the term “batch... inlet sampling sites shall ensure the measurement of total organic HAP or TOC (minus methane and ethane... used to determine the concentration of organic HAP or TOC, as appropriate. Alternatively, any other...

40 CFR 63.3490 - What emission limits must I meet?

Code of Federal Regulations, 2013 CFR

2013-07-01

... must limit organic HAP emissions to the atmosphere to no more than the emission limit(s) in Table 1 to... reduce organic HAP emissions to the atmosphere to no more than the limit(s) in Table 3 to this subpart... must limit organic HAP emissions to the atmosphere to no more than the emission limit(s) in Table 2 to...

40 CFR 63.3490 - What emission limits must I meet?

Code of Federal Regulations, 2014 CFR

2014-07-01

... must limit organic HAP emissions to the atmosphere to no more than the emission limit(s) in Table 1 to... reduce organic HAP emissions to the atmosphere to no more than the limit(s) in Table 3 to this subpart... must limit organic HAP emissions to the atmosphere to no more than the emission limit(s) in Table 2 to...

40 CFR 63.3490 - What emission limits must I meet?

Code of Federal Regulations, 2012 CFR

2012-07-01

... must limit organic HAP emissions to the atmosphere to no more than the emission limit(s) in Table 1 to... reduce organic HAP emissions to the atmosphere to no more than the limit(s) in Table 3 to this subpart... must limit organic HAP emissions to the atmosphere to no more than the emission limit(s) in Table 2 to...

40 CFR 63.4751 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... mass of organic HAP emissions during the month, grams. A = Total mass of organic HAP in the coatings used during the month, grams, as calculated in Equation 1A of this section. B = Total mass of organic HAP in the thinners used during the month, grams, as calculated in Equation 1B of this section. C...

40 CFR Table 4 to Subpart Ppp of... - Known Organic HAP From Polyether Polyol Products

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 11 2011-07-01 2011-07-01 false Known Organic HAP From Polyether Polyol Products 4 Table 4 to Subpart PPP of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Production Pt. 63, Subpt. PPP, Table 4 Table 4 to Subpart PPP of Part 63—Known Organic HAP From Polyether...

40 CFR Table 4 to Subpart Ppp of... - Known Organic HAP From Polyether Polyol Products

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 12 2014-07-01 2014-07-01 false Known Organic HAP From Polyether Polyol Products 4 Table 4 to Subpart PPP of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Polyether Polyols Production Pt. 63, Subpt. PPP, Table 4 Table 4 to Subpart PPP of Part 63—Known Organic HAP...

40 CFR Table 4 to Subpart Ppp of... - Known Organic HAP From Polyether Polyol Products

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 12 2013-07-01 2013-07-01 false Known Organic HAP From Polyether Polyol Products 4 Table 4 to Subpart PPP of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION... Polyether Polyols Production Pt. 63, Subpt. PPP, Table 4 Table 4 to Subpart PPP of Part 63—Known Organic HAP...

40 CFR Table 4 to Subpart Ppp of... - Known Organic HAP From Polyether Polyol Products

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 12 2012-07-01 2011-07-01 true Known Organic HAP From Polyether Polyol Products 4 Table 4 to Subpart PPP of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Pt. 63, Subpt. PPP, Table 4 Table 4 to Subpart PPP of Part 63—Known Organic HAP From Polyether Polyol...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Organic HAP Emission Limits for Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Organic HAP Emission Limits for Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Organic HAP Emission Limits for Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Organic HAP Emission Limits for Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Organic HAP Emission Limits for Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Organic HAP Emission Limits for Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL..., Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking...

40 CFR 63.5758 - How do I determine the organic HAP content of materials?

Code of Federal Regulations, 2010 CFR

2010-07-01

... for each material used in your open molding resin and gel coat operations, carpet and fabric adhesive... ASTM) to measure the mass fraction of volatile matter of resins and gel coats for open molding... section, such as manufacturer's formulation data, according to paragraphs (a)(5)(i) through (iii) of this...

40 CFR Table 2 to Subpart Vvvv of... - Alternative Organic HAP Content Requirements for Open Molding Resin and Gel Coat Operations

Code of Federal Regulations, 2010 CFR

2010-07-01

... Requirements for Open Molding Resin and Gel Coat Operations 2 Table 2 to Subpart VVVV of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air...

40 CFR 63.496 - Back-end process provisions-procedures to determine compliance using control or recovery devices.

Code of Federal Regulations, 2010 CFR

2010-07-01

... total organic HAP (or TOC, minus methane and ethane) emissions in all process vent streams and primary... TOC (minus methane and ethane) may be measured instead of total organic HAP. (C) The mass rates shall... and outlet of the control device shall be the sum of all total organic HAP (or TOC, minus methane and...

40 CFR 63.117 - Process vent provisions-reporting and recordkeeping requirements for group and TRE determinations...

Code of Federal Regulations, 2010 CFR

2010-07-01

... period of the performance testing. (ii) For an incinerator, the percent reduction of organic HAP or TOC... organic HAP or TOC (parts per million by volume, by compound) determined as specified in § 63.116(c) of... fuel and is not mixed with the primary fuel, the percent reduction of organic HAP or TOC, or the...

40 CFR Table 2 to Subpart Mmm of... - Standards for New and Existing PAI Sources

Code of Federal Regulations, 2010 CFR

2010-07-01

... TOC. Processes having uncontrolled HCl and chlorine emissions ≥6.8 Mg/yr 94% for HCl and chlorine per... November 10, 1997 98% gaseous organic HAP control per vent or ≤20 ppmv TOC outlet limit. New: Processes having uncontrolled organic HAP emissions ≥0.15 Mg/yr 98% for organic HAP per process or ≤20 ppmv TOC...

40 CFR Table 16 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 16 Table 16 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 16 Table 16 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

40 CFR Table 16 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 16 Table 16 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 16 Table 16 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

40 CFR Table 16 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 16 Table 16 to Subpart UUU of Part 63 Protection of Environment..., Subpt. UUU, Table 16 Table 16 to Subpart UUU of Part 63—Operating Limits for Organic HAP Emissions From...

40 CFR Table 16 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 16 Table 16 to Subpart UUU of Part 63 Protection of Environment..., Subpt. UUU, Table 16 Table 16 to Subpart UUU of Part 63—Operating Limits for Organic HAP Emissions From...

40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment..., Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP Emissions From...

40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment..., Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP Emissions From...

40 CFR Table 9 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 9 Table 9 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 9 Table 9 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

40 CFR Table 16 to Subpart Uuu of... - Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 16 Table 16 to Subpart UUU of Part 63 Protection of Environment... Units Pt. 63, Subpt. UUU, Table 16 Table 16 to Subpart UUU of Part 63—Operating Limits for Organic HAP...

Hydroxyapatite induces spontaneous polymerization of model self-etch dental adhesives.

PubMed

Zhang, Ying; Wu, Ningjing; Bai, Xinyan; Xu, Changqi; Liu, Yi; Wang, Yong

2013-10-01

The objective of this study is to report for the first time the spontaneous polymerization phenomenon of self-etch dental adhesives induced by hydroxylapatite (HAp). Model self-etch adhesives were prepared by using a monomer mixture of bis[2-(methacryloyloxy)ethyl] phosphate (2MP) with 2-hydroxyethyl methacrylate (HEMA). The initiator system consisted of camphorquinone (CQ, 0.022 mmol/g) and ethyl 4-dimethylaminobenzoate (4E, 0.022-0.088 mmol/g). HAp (2-8 wt.%) was added to the neat model adhesive. In a dark environment, the polymerization was monitored in-situ using ATR/FT-IR, and the mechanical properties of the polymerized adhesives were evaluated using nanoindentation technique. Results indicated that spontaneous polymerization was not observed in the absence of HAp. However, as different amounts of HAp were incorporated into the adhesives, spontaneous polymerization was induced. Higher HAp content led to higher degree of conversion (DC), higher rate of polymerization (RP) and shorter induction period (IP). In addition, higher 4E content also elevated DC and RP and reduced IP of the adhesives. Nanoindentation result suggested that the Young's modulus of the polymerized adhesives showed similar dependence on HAp and 4E contents. In summary, interaction with HAp could induce spontaneous polymerization of the model self-etch adhesives. This result provides important information for understanding the initiation mechanism of the self-etch adhesives, and may be of clinical significance to strengthen the adhesive/dentin interface based on the finding. Copyright © 2013 Elsevier B.V. All rights reserved.

Hydroxyapatite induces spontaneous polymerization of model self-etch dental adhesives

PubMed Central

Zhang, Ying; Wu, Ningjing; Bai, Xinyan; Xu, Changqi; Liu, Yi; Wang, Yong

2013-01-01

The objective of this study is to report for the first time the spontaneous polymerization phenomenon of self-etch dental adhesives induced by hydroxylapatite (HAp). Model self-etch adhesives were prepared by using a monomer mixture of bis[2-(methacryloyloxy)ethyl] phosphate (2MP) with 2-hydroxyethyl methacrylate (HEMA). The initiator system consisted of camphorquinone (CQ, 0.022 mmol/g) and ethyl 4-dimethylaminobenzoate (4E, 0.022–0.088 mmol/g). HAp (2–8 wt.%) was added to the neat model adhesive. In a dark environment, the polymerization was monitored in-situ using ATR/FT-IR, and the mechanical properties of the polymerized adhesives were evaluated using nanoindentation technique. Results indicated that spontaneous polymerization was not observed in the absence of HAp. However, as different amounts of HAp were incorporated into the adhesives, spontaneous polymerization was induced. Higher HAp content led to higher degree of conversion (DC), higher rate of polymerization (RP) and shorter induction period (IP). In addition, higher 4E content also elevated DC and RP and reduced IP of the adhesives. Nanoindentation result suggested that the Young's modulus of the polymerized adhesives showed similar dependence on HAp and 4E contents. In summary, interaction with HAp could induce spontaneous polymerization of the model self-etch adhesives. This result provides important information for understanding the initiation mechanism of the self-etch adhesives, and may be of clinical significance to strengthen the adhesive/dentin interface based on the finding. PMID:23910263

40 CFR Table 4 to Subpart Ffff of... - Emission Limits for Storage Tanks

Code of Federal Regulations, 2010 CFR

2010-07-01

... HAP emissions by ≥95 percent by weight or to ≤20 ppmv of TOC or organic HAP and ≤20 ppmv of hydrogen... ≥95 percent by weight or to ≤20 ppmv of TOC or organic HAP and ≤20 ppmv of hydrogen halide and halogen...

40 CFR 65.66 - Recordkeeping provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... applicable criteria in table 1 to this subpart shall record the organic HAP or TOC concentration as measurement using the sampling site and HAP or TOC concentration determination procedures specified in § 65.64... to § 65.63(f). (2) If the process vent is Group 2B on the basis of organic HAP or TOC concentration...

40 CFR 63.4761 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2013 CFR

2013-07-01

... HAP emission reduction for the controlled coating operation during the month, grams. Ac = Total mass of organic HAP in the coatings used in the controlled coating operation during the month, grams. Bc..., grams, as calculated in Equation 1B of this section. Cc = Total mass of organic HAP in the cleaning...

40 CFR 63.4761 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2011 CFR

2011-07-01

... HAP emission reduction for the controlled coating operation during the month, grams. Ac = Total mass of organic HAP in the coatings used in the controlled coating operation during the month, grams. Bc..., grams, as calculated in Equation 1B of this section. Cc = Total mass of organic HAP in the cleaning...

40 CFR 63.4761 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2014 CFR

2014-07-01

... HAP emission reduction for the controlled coating operation during the month, grams. Ac = Total mass of organic HAP in the coatings used in the controlled coating operation during the month, grams. Bc..., grams, as calculated in Equation 1B of this section. Cc = Total mass of organic HAP in the cleaning...

40 CFR 63.4761 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2010 CFR

2010-07-01

... HAP emission reduction for the controlled coating operation during the month, grams. Ac = Total mass of organic HAP in the coatings used in the controlled coating operation during the month, grams. Bc..., grams, as calculated in Equation 1B of this section. Cc = Total mass of organic HAP in the cleaning...

40 CFR 63.4761 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2012 CFR

2012-07-01

... HAP emission reduction for the controlled coating operation during the month, grams. Ac = Total mass of organic HAP in the coatings used in the controlled coating operation during the month, grams. Bc..., grams, as calculated in Equation 1B of this section. Cc = Total mass of organic HAP in the cleaning...

40 CFR Table 1 to Subpart Oooo of... - Emission Limits for New or Reconstructed and Existing Affected Sources in the Printing, Coating...

Code of Federal Regulations, 2010 CFR

2010-07-01

... may choose any one of the following limits:Reduce organic HAP emissions to the atmosphere by achieving... atmosphere to no more than 0.08 kg of organic HAP per kg of solids applied; or If you use an oxidizer to... emissions to the atmosphere by achieving at least a 97 percent organic HAP overall control efficiency; Limit...

40 CFR Table 1 to Subpart Oooo of... - Emission Limits for New or Reconstructed and Existing Affected Sources in the Printing, Coating...

Code of Federal Regulations, 2011 CFR

2011-07-01

... may choose any one of the following limits:Reduce organic HAP emissions to the atmosphere by achieving... atmosphere to no more than 0.08 kg of organic HAP per kg of solids applied; or If you use an oxidizer to... emissions to the atmosphere by achieving at least a 97 percent organic HAP overall control efficiency; Limit...

40 CFR Table 8 to Subpart G of... - Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Organic HAP's Subject to the Wastewater... Operations, and Wastewater Pt. 63, Subpt. G, Table 8 Table 8 to Subpart G of Part 63—Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources Chemical name CAS No. a Allyl chloride...

40 CFR Table 8 to Subpart G of... - Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 9 2011-07-01 2011-07-01 false Organic HAP's Subject to the Wastewater... Operations, and Wastewater Pt. 63, Subpt. G, Table 8 Table 8 to Subpart G of Part 63—Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources Chemical name CAS No. a Allyl chloride...

Hydroxyapatite Effect on Photopolymerization of Self-etching Adhesives with Different Aggressiveness

PubMed Central

Zhang, Ying; Wang, Yong

2012-01-01

Objective To understand the correlation of the acidic monomer/hydroxyapatite (HAp) reaction with the photopolymerization behavior of self-etching adhesives with different aggressiveness. Methods Two commercial self-etching adhesives the strong Adper Prompt L-Pop (APLP, pH~0.8) and the mild Adper Easy Bond (AEB, pH~2.5) were used. HAp powders were incorporated into both adhesives to acquire solutions with concentrations of 0, 1, 3, 5, 7 wt%. The attenuated total reflectance Fourier transform infrared (ATR/FT-IR) technique was employed to collect the in-situ spectra during light-curing, from which the degree of conversion (DC) and polymerization rate (PR) were calculated. The pH of each tested solution was also measured. Results Without HAp incorporation, the DC and PR of the strong APLP (7.8% and 0.12%/s, respectively) were much lower than those of the mild AEB (85.5% and 5.7%/s, respectively). The DC and PR of APLP displayed an apparent increasing trend with the HAp content. For example, the DC increased from 7.8% to 58.4% and the PR increased from 0.12 to 3.8%/s when the HAp content increased from 0 to 7 wt%. In contrast, the DC and PR of AEB were much less affected by the HAp content. The observations were correlated well with the spectral and pH changes, which indicated that APLP underwent a higher extent of chemical reaction with HAp than AEB. Conclusions The results disclosed the important role of the acidic monomer/HAp chemical reaction in improving the photopolymerization of the strong (low-pH) self-etching adhesives such as APLP. The phenomenon of polymerization improvement strongly depended on the adhesive aggressiveness. PMID:22445789

Evolutionary history of the HAP2/GCS1 gene and sexual reproduction in metazoans.

PubMed

Steele, Robert E; Dana, Catherine E

2009-11-03

The HAP2/GCS1 gene first appeared in the common ancestor of plants, animals, and protists, and is required in the male gamete for fusion to the female gamete in the unicellular organisms Chlamydomonas and Plasmodium. We have identified a HAP2/GCS1 gene in the genome sequence of the sponge Amphimedon queenslandica. This finding provides a continuous evolutionary history of HAP2/GCS1 from unicellular organisms into the metazoan lineage. Divergent versions of the HAP2/GCS1 gene are also present in the genomes of some but not all arthropods. By examining the expression of the HAP2/GCS1 gene in the cnidarian Hydra, we have found the first evidence supporting the hypothesis that HAP2/GCS1 was used for male gamete fusion in the ancestor of extant metazoans and that it retains that function in modern cnidarians.

40 CFR Table 1 to Subpart Oooo of... - Emission Limits for New or Reconstructed and Existing Affected Sources in the Printing, Coating...

Code of Federal Regulations, 2012 CFR

2012-07-01

... operations You may choose any one of the following limits:Reduce organic HAP emissions to the atmosphere by... atmosphere to no more than 0.08 kg of organic HAP per kg of solids applied; or If you use an oxidizer to... emissions to the atmosphere by achieving at least a 97 percent organic HAP overall control efficiency; Limit...

40 CFR Table 1 to Subpart Oooo of... - Emission Limits for New or Reconstructed and Existing Affected Sources in the Printing, Coating...

Code of Federal Regulations, 2013 CFR

2013-07-01

... operations You may choose any one of the following limits:Reduce organic HAP emissions to the atmosphere by... atmosphere to no more than 0.08 kg of organic HAP per kg of solids applied; or If you use an oxidizer to... emissions to the atmosphere by achieving at least a 97 percent organic HAP overall control efficiency; Limit...

40 CFR Table 1 to Subpart Oooo of... - Emission Limits for New or Reconstructed and Existing Affected Sources in the Printing, Coating...

Code of Federal Regulations, 2014 CFR

2014-07-01

... operations You may choose any one of the following limits:Reduce organic HAP emissions to the atmosphere by... atmosphere to no more than 0.08 kg of organic HAP per kg of solids applied; or If you use an oxidizer to... emissions to the atmosphere by achieving at least a 97 percent organic HAP overall control efficiency; Limit...

Effects of low molecular weight organic acids on the immobilization of aqueous Pb(II) using phosphate rock and different crystallized hydroxyapatite.

PubMed

Wei, Wei; Cui, Jing; Wei, Zhenggui

2014-06-01

Understanding the effects of low molecular weight organic acids (LMWOAs) on the transformation of Pb(II) to geochemically stable pyromorphite (PY) by apatite materials (AMs), has considerable benefits for risk assessment and remediation strategies for contaminated water and soil. In this study, we systematically investigated the immobilization of Pb(II) from aqueous solution by natural phosphate rock (PR) and different crystallized hydroxyapatite (HAp) in the absence and presence of LMWOAs (oxalic, malic and citric acids). The results indicated that the effectiveness of PR and HAp in immobilizing Pb(II) followed in descending order by HAp2 (the poorly crystallized HAp), HAp1 (the well crystallized HAp) and PR, regardlessof the presence of LMWOAs. The presence of malic and citric acids significantly decreased the immobilizationefficiency of Pb(II) by HAp1 and PR, clarifying the lower adsorption affinities of Pb(II)-organic acid complexes on HAp1 and PR rather than Pb(II) ion. On thecontrary, oxalic acid could markedly enhance the removal of Pb(II) from aqueous solution by HAp1 and PR through the formation of lead oxalate, which was confirmed by FT-IR and XRDanalysis. Results also showed that LMWOAs had little promoting or inhibiting effect on the immobilization of Pb(II) by HAp2. This study suggested that the ubiquity of LMWOAs in natural environments could retard the transformation efficiency of Pb(II) to PY by AMs, especiallyin thepresenceof oxalic acid, and the poorly crystallized HAp2 had great potential to remediate Pb(II)-contaminated water and soil due to its insusceptibility to LMWOAs. Copyright © 2013 Elsevier Ltd. All rights reserved.

40 CFR 63.3370 - How do I demonstrate compliance with the emission standards?

Code of Federal Regulations, 2011 CFR

2011-07-01

... or group of web coating lines controlled by a common control device during the month. (vi) If... monthly HAP applied (Equation 6 of § 63.3370) is less than the calculated equivalent allowable organic HAP (Equation 13a or b of § 63.3370). (4) Use of a capture system and control device (i) Overall organic HAP...

40 CFR 63.5796 - What are the organic HAP emissions factor equations in Table 1 to this subpart, and how are they...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Emissions Factors for Open Molding and Centrifugal Casting § 63.5796 What are the organic HAP emissions... factors. Equations are available for each open molding operation and centrifugal casting operation and... incorporated in the facility's air emissions permit and are based on actual facility HAP emissions test data...

40 CFR 63.5796 - What are the organic HAP emissions factor equations in Table 1 to this subpart, and how are they...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Emissions Factors for Open Molding and Centrifugal Casting § 63.5796 What are the organic HAP emissions... factors. Equations are available for each open molding operation and centrifugal casting operation and... incorporated in the facility's air emissions permit and are based on actual facility HAP emissions test data...

40 CFR 63.3941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... § 63.3890 and must use no thinner and/or other additive, or cleaning material that contains organic HAP... organic HAP. For reactive adhesives in which some of the HAP react to form solids and are not emitted to... part, rather than Method 24. You may use the volatile fraction that is emitted, as measured by the...

40 CFR 63.3941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... § 63.3890 and must use no thinner and/or other additive, or cleaning material that contains organic HAP... organic HAP. For reactive adhesives in which some of the HAP react to form solids and are not emitted to... part, rather than Method 24. You may use the volatile fraction that is emitted, as measured by the...

40 CFR 63.3941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... § 63.3890 and must use no thinner and/or other additive, or cleaning material that contains organic HAP... organic HAP. For reactive adhesives in which some of the HAP react to form solids and are not emitted to... part, rather than Method 24. You may use the volatile fraction that is emitted, as measured by the...

40 CFR 63.1281 - Control equipment requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... performance requirements: (A) Reduces the mass content of either TOC or total HAP in the gases vented to the....1282(d); (B) Reduces the concentration of either TOC or total HAP in the exhaust gases at the outlet to... condenser) or other control device that is designed and operated to reduce the mass content of either TOC or...

Investigating an organ-targeting platform based on hydroxyapatite nanoparticles using a novel in situ method of radioactive ¹²⁵Iodine labeling.

PubMed

Ignjatović, Nenad; Vranješ Djurić, Sanja; Mitić, Zarko; Janković, Drina; Uskoković, Dragan

2014-10-01

In this study, we have investigated the synthesis of nanoparticles of hydroxyapatite (HAp) and hydroxyapatite coated with chitosan (HAp/Ch) and the chitosan-poly-d,l-lactide-co-glycolide polymer blend (HAp/Ch-PLGA) as an organ-targeting system. We have examined and defined the final destination, as well as the dynamics and the pathways of the synthesized particles following intravenous administration in vivo. The XRD, ZP, FT-IR and SEM analyses have confirmed that the hydroxyapatite nanoparticles with d50=72 nm are coated with polymers. Radioactive 125-Iodine ((125)I), a low energy gamma emitter, was used to develop a novel in situ method for the radiolabeling of particles and investigation of their biodistribution. (125)I-labeled particles exhibited high stability in saline and serum over the second day, which justified their use in the following in vivo studies. The biodistribution of (125)I-labeled particles after intravenous injection in rats differed significantly: HAp particles mostly targeted the liver, HAp/Ch the spleen and the liver, while HAp/Ch-PLGA targeted the lungs. Twenty-four hours post injection, HAp particles were excreted completely, while both (125)I-HAp/Ch and (125)I-HAp/Ch-PLGA were retained in the body for a prolonged period of time with more than 20% of radioactivity still found in different organs. Copyright © 2014 Elsevier B.V. All rights reserved.

Applicability of canisters for sample storage in the determination of hazardous air pollutants

NASA Astrophysics Data System (ADS)

Kelly, Thomas J.; Holdren, Michael W.

This paper evaluates the applicability of canisters for storage of air samples containing volatile organic compounds listed among the 189 hazardous air pollutants (HAPs) in the 1990 U.S. Clean Air Act Amendments. Nearly 100 HAPs have sufficient vapor pressure to be considered volatile compounds. Of those volatile organic HAPs, 52 have been tested previously for stability during storage in canisters. The published HAP stability studies are reviewed, illustrating that for most of the 52 HAPs tested, canisters are an effective sample storage approach. However, the published stability studies used a variety of canister types and test procedures, and generally considered only a few compounds in a very small set of canisters. A comparison of chemical and physical properties of the HAPs has also been conducted, to evaluate the applicability of canister sampling for other HAPs, for which canister stability testing has never been conducted. Of 45 volatile HAPs never tested in canisters, this comparison identifies nine for which canisters should be effective, and 17 for which canisters are not likely to be effective. For the other 19 HAPs, no clear decision can be reached on the likely applicability of air sample storage in canisters.

40 CFR 63.105 - Maintenance wastewater requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Standards for Organic Hazardous Air Pollutants From the Synthetic Organic Chemical Manufacturing Industry... wastewaters containing those organic HAP's listed in table 9 of subpart G of this part. (b) The owner or... will be followed to properly manage the wastewater and control organic HAP emissions to the atmosphere...

40 CFR 63.105 - Maintenance wastewater requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... National Emission Standards for Organic Hazardous Air Pollutants From the Synthetic Organic Chemical... for maintenance wastewaters containing those organic HAP's listed in table 9 of subpart G of this part... procedures that will be followed to properly manage the wastewater and control organic HAP emissions to the...

40 CFR 63.105 - Maintenance wastewater requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... National Emission Standards for Organic Hazardous Air Pollutants From the Synthetic Organic Chemical... for maintenance wastewaters containing those organic HAP's listed in table 9 of subpart G of this part... procedures that will be followed to properly manage the wastewater and control organic HAP emissions to the...

One Ion to Rule Them All: Combined Antibacterial, Osteoinductive and Anticancer Properties of Selenite-Incorporated Hydroxyapatite

PubMed Central

Uskoković, Vuk; Iyer, Maheshwar Adiraj; Wu, Victoria M.

2017-01-01

Although hydroxyapatite (HAp) has been doped with dozens of different ions, the quest for an ion imparting a combination of properties conducive to bone healing is still ongoing. Because of its protean potency and the similarity in size and shape to the phosphate tetrahedron, selenite ion presents a natural ionic substitute in HAp. The incorporation of selenite into synthetic HAp using two different methods – co-precipitation and ion-exchange sorption - was studied for its effect on crystal properties and on a triad of biological responses: antibacterial, anticancer and osteoinductive. Co-precipitation yielded HAp with higher selenite contents than sorption and the stoichiometry of HAp richest in selenite was represented as Ca9.75(PO4)5.75(SeO3)0.25(OH)1.75. Crystallinity of HAp decreased in direct proportion with the amount of selenite incorporated. Because of their lower selenite content, HAp powders prepared by ion-exchange exhibited a consistently higher crystallinity compared to the co-precipitated ones. Annealing partially recovered the crystallinity, yet the difference in crystallinity between powders prepared by co-precipitation and by ion-exchange remained, suggesting that the amorphization is mainly due to structural incorporation of selenite, not its effect on the crystal growth kinetics. The addition of selenite changed the morphology of HAp nanoparticles from acicular to rounded and affected the crystal lattice parameters in different ways depending on whether the powders were annealed or not. As for the annealed powders, the incorporation of selenite contracted the lattice in both a and c crystallographic directions. In the agar diffusion assay, the effectiveness of HAp was more dependent on the presence or absence of selenite in it than on its concentration and was highest against E. coli and S. aureus, moderately high against S. enteritidis and ineffective against P. aeruginosa. In liquid inoculation tests, on the other hand, the antibacterial activity of HAp was directly proportional to the amount of selenite contained in it. The viability of K7M2 osteosarcoma cells decreased in direct proportion with the amount of selenite in HAp and was significantly different from the untreated control and from pure HAp at contents equal to or higher than 1.9 wt.%. In contrast, no reduction was observed in the viability of primary fibroblasts treated with HAp incorporating different amounts of selenite ions, suggesting their potentially selective anticancer activity: lethal for the cancer cells and harmless for the healthy cells. Finally, mRNA expression of bone gamma-carboxyglutamate protein (BGLAP3) was higher in differentiated MC3T3-E1 osteoblastic cells treated with selenite-incorporated HAp particles than in cells treated with pure HAp. The osteoinductive effect was due to an overall higher metabolic activity of cells treated with the particles and not due to increased proliferation. In such a way, a triad of antibacterial, osteoinductive and anticancer activities was attributed to selenite-incorporated HAp. PMID:28944060

40 CFR Table 2 to Subpart Ooo of... - Known Organic Hazardous Air Pollutants (HAP) From the Manufacture of Amino/Phenolic Resins

Code of Federal Regulations, 2011 CFR

2011-07-01

... (HAP) From the Manufacture of Amino/Phenolic Resins 2 Table 2 to Subpart OOO of Part 63 Protection of... Pollutant Emissions: Manufacture of Amino/Phenolic Resins Pt. 63, Subpt. OOO, Table 2 Table 2 to Subpart OOO of Part 63—Known Organic Hazardous Air Pollutants (HAP) From the Manufacture of Amino/Phenolic Resins...

40 CFR Table 2 to Subpart Ooo of... - Known Organic Hazardous Air Pollutants (HAP) From the Manufacture of Amino/Phenolic Resins

Code of Federal Regulations, 2010 CFR

2010-07-01

... (HAP) From the Manufacture of Amino/Phenolic Resins 2 Table 2 to Subpart OOO of Part 63 Protection of... Pollutant Emissions: Manufacture of Amino/Phenolic Resins Pt. 63, Subpt. OOO, Table 2 Table 2 to Subpart OOO of Part 63—Known Organic Hazardous Air Pollutants (HAP) From the Manufacture of Amino/Phenolic Resins...

Hazardous Air Pollutant Free Replacement for Specification A-A-1936A Contact Adhesive

DTIC Science & Technology

2014-02-01

volatile organic compound (VOC). Six alternative low-HAP or HAP-free commercial adhesives were evaluated using high-pressure decorative plastic laminate... compounds (VOCs) (5). The HAPs are petroleum distillate, n-hexane, and toluene. Also, this product contains cyclohexane (VOC), and acetone (HAP and...vinyl, drywall , wood, and plywood (19). This product contains toluene HAP/VOC at 1–5 wt.% (20). 4 3. Experimental Method 3.1 Edge Lift Test

Zirconia/Hydroxyapatite Composites Synthesized Via Sol-Gel: Influence of Hydroxyapatite Content and Heating on Their Biological Properties

PubMed Central

Bollino, Flavia; Armenia, Emilia; Tranquillo, Elisabetta

2017-01-01

Zirconia (ZrO2) and zirconia-based glasses and ceramics are materials proposed for use in the dental and orthopedic fields. In this work, ZrO2 glass was modified by adding different amounts of bioactive and biocompatible hydroxyapatite (HAp). ZrO2/HAp composites were synthesized via the sol-gel method and heated to different temperatures to induce modifications of their chemical structure, as ascertained by Fourier transform infrared spectroscopy (FTIR) analysis. The aim was to investigate the effect of both HAp content and heating on the biological performances of ZrO2. The materials’ bioactivity was studied by soaking samples in a simulated body fluid (SBF). FTIR and scanning electron microscopy (SEM)) analyses carried out after exposure to SBF showed that all materials are bioactive, i.e., they are able to form a hydroxyapatite layer on their surface. Moreover, the samples were soaked in a solution containing bovine serum albumin (BSA). FTIR analysis proved that the synthesized materials are able to adsorb the blood protein, the first step of cell adhesion. WST-8 ([2-(2-methoxy-4-nitrophenyl)-3-(4-nitrophenyl)-5-(2,4-disulfophenyl)-2H-tetrazolium, monosodium salt]) assay showed that no cytotoxicity effects were induced by the materials’ extract. However, the results proved that bioactivity increases with both the HAp content and the temperature used for the thermal treatment, whereas biocompatibility increases with heating but is not affected by the HAp content. PMID:28773116

Water-dispersible hydroxyapatite nanoparticles synthesized in aqueous solution containing grape seed extract

NASA Astrophysics Data System (ADS)

Zhou, Ruchao; Si, Shaoxiong; Zhang, Qiyi

2012-02-01

A novel and effective method for the preparation of water-dispersible nano-hydroxyapatite (nHAp) particles was reported. nHAp was prepared in the presence of grape seed polyphenol (GSP) solution with different concentrations. Chemical precipitation method was adopted to produce pure nHAp and modified nHAp (nHAp-GSP) at 60 °C for 2 h. The chemical nature of the products was detected by Fourier transform infrared spectroscopy (FTIR) and thermal gravimetric analysis (TGA). Moreover, the crystal structure and morphology of particles was confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the spherical nHAp particles with a diameter of 20-50 nm could be synthesized at 60 °C. The zeta potential values of pure nHAp and nHAp-GSP are -0.36 mV and -26.1 mV respectively. According to the sedimentary time, the colloidal stability of nHAp-GSP in water could be improved dramatically with the increase of GSP content and the particles tended to exist as dispersive nanoparticles without aggregation. All the results indicated that GSP exhibited strong binding to nHAp and enhanced the colloidal stability of nHAp particles.

40 CFR 63.2505 - How do I comply with the alternative standard?

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical... control device(s), it must reduce HAP emissions to an outlet total organic HAP concentration of 50 ppmv or...

40 CFR 63.2505 - How do I comply with the alternative standard?

Code of Federal Regulations, 2011 CFR

2011-07-01

... National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing... device(s), it must reduce HAP emissions to an outlet total organic HAP concentration of 50 ppmv or less...

40 CFR 63.2505 - How do I comply with the alternative standard?

Code of Federal Regulations, 2010 CFR

2010-07-01

... National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing... device(s), it must reduce HAP emissions to an outlet total organic HAP concentration of 50 ppmv or less...

40 CFR 63.4293 - What work practice standards must I meet?

Code of Federal Regulations, 2010 CFR

2010-07-01

... option, the organic HAP overall control efficiency option, or the oxidizer outlet organic HAP... must be conveyed from one location to another in closed containers or pipes. (4) Mixing vessels which...

Hydroxyapatite/collagen bone-like nanocomposite.

PubMed

Kikuchi, Masanori

2013-01-01

Our group has succeeded to synthesize material with bone-like nanostructure and bone-like inorganic and organic composition via self-organization mechanism between them using simultaneous titration method under controlled pH and temperature. The hydroxyapatite/collagen (HAp/Col) bone-like nanocomposite completely incorporated into bone remodeling process to be substituted by new bone. Cells cultured on the HAp/Col revealed very interesting reactions. Osteoblast-like MG63 cells showed upregulation of alkaline phosphatase >3 times greater than MG63 cells cultured on tissue culture polystyrene (TCPS). MG63 cells 3-dimensionally cultured in a "HAp/Col sponge," a porous HAp/Col having sponge-like viscoelasticity, accumulated calcium phosphate nodules on extracellular matrices they secreted. Bone marrow cells co-cultured with osteoblasts on HAp/Col differentiated to osteoclasts without differentiation supplements. This phenomenon is not found in cells cultured on hydroxyapatite ceramics and TCPS, and rarely in cells cultured on dentin. These results suggest that HAp/Col is a good candidate for tissue engineering of bone as well as bone filler. In a clinical test as a bone filler, the HAp/Col sponge was significantly better than porous β-tricalcium phosphate. The HAp/Col sponge has been approved by the Japanese government and will be used as greatly needed bone filler in patients. In addition to the above, HAp/Col coating on titanium revealed higher osteo-conductivity than HAp-coated titanium and bare titanium and improved direct bonding between titanium and newly formed bone. The HAp/Col coating may be used for metal devices requiring osseointegration.

40 CFR 63.2520 - What reports must I submit and when?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing Notification, Reports... that contain energetics and organic peroxides, and rationale for why meeting the emission limit... is the only HAP and usage is less than 10,000 lb/yr, the total uncontrolled organic HAP emissions...

40 CFR 63.2520 - What reports must I submit and when?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing Notification, Reports... that contain energetics and organic peroxides, and rationale for why meeting the emission limit... is the only HAP and usage is less than 10,000 lb/yr, the total uncontrolled organic HAP emissions...

40 CFR 63.2465 - What requirements must I meet for process vents that emit hydrogen halide and halogen HAP or HAP...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Pollutants: Miscellaneous Organic Chemical Manufacturing Emission Limits, Work Practice Standards, and... the mass emission rate of HAP metals based on process knowledge, engineering assessment, or test data...

40 CFR 65.67 - Reporting provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., organic HAP or TOC concentration, and/or TRE index value required under § 65.63(f) and recorded under § 65... 2B process vent, the organic HAP or TOC concentration of the vent stream is recalculated according to...

40 CFR 63.4690 - What emission limits must I meet?

Code of Federal Regulations, 2012 CFR

2012-07-01

... source, you must limit organic HAP emissions to the atmosphere to no more than the applicable emission... 63.4761. (b) For an existing affected source, you must limit organic HAP emissions to the atmosphere...

The Haemophilus influenzae Hap autotransporter mediates microcolony formation and adherence to epithelial cells and extracellular matrix via binding regions in the C-terminal end of the passenger domain.

PubMed

Fink, Doran L; Buscher, Amy Z; Green, Bruce; Fernsten, Phillip; St Geme, Joseph W

2003-03-01

The pathogenesis of non-typable Haemophilus influenzae disease begins with colonization of the nasopharynx and is facilitated by bacterial adherence to respiratory mucosa. The H. influenzae Hap autotransporter is a non-pilus adhesin that promotes adherence to epithelial cells and selected extracellular matrix proteins and mediates bacterial aggregation and microcolony formation. In addition, Hap has serine protease activity. Hap contains a 110 kDa internal passenger domain called HapS and a 45 kDa C-terminal translocator domain called Hapbeta. In the present study, we sought to define the structural basis for Hap adhesive activities. Based on experiments using a panel of monoclonal antibodies against HapS, a deletion derivative lacking most of HapS and a purified fragment of HapS, we established that adherence to epithelial cells is mediated by sequences within the C-terminal 311 residues of HapS. In additional experiments, we discovered that bacterial aggregation is also mediated by sequences within the C-terminal 311 residues of HapS and occurs via HapS-HapS interaction between molecules on neighbouring organisms. Finally, we found that adherence to fibronectin, laminin and collagen IV is mediated in part by sequences within the C-terminal 311 residues of HapS and in full by sequences within the C-terminal 511 residues of HapS. Taken together, these results demonstrate that all Hap adhesive activities reside in the C-terminal portion of HapS. Coupled with earlier observations, the current results establish that HapS adhesive activities and HapS protease activity are contained in separate modules of the protein.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baybas, Demet, E-mail: dbaybas@cumhuriyet.edu.tr; Ulusoy, Ulvi, E-mail: ulusoy@cumhuriyet.edu.tr

The composite of synthetically produced hydroxyapatite (HAP) and polyacrylamide was prepared (PAAm-HAP) and characterized by BET, FT-IR, TGA, XRD, SEM and PZC analysis. The adsorptive features of HAP and PAAm-HAP were compared for UO{sub 2}{sup 2+} and Th{sup 4+}. The entrapment of HAP into PAAm-HAP did not change the structure of HAP. Both structures had high affinity to the studied ions. The adsorption capacity of PAAm-HAP was than that of HAP. The adsorption dependence on pH and ionic intensity provided supportive evidences for the effect of complex formation on adsorption process. The adsorption kinetics was well compatible to pseudo secondmore » order model. The values of enthalpy and entropy changes were positive. Th{sup 4+} adsorption from the leachate obtained from a regional fluorite rock confirmed the selectivity of PAAm-HAP for this ion. In consequence, PAAm-HAP should be considered amongst favorite adsorbents for especially deposition of nuclear waste containing U and Th, and radionuclide at secular equilibrium with these elements. - Graphical abstract: SEM images of hydroxyapatite (HAP) and polyacrylamide-hydroxyapatite (PAAm-HAP), and the adsorption isotherms for Uranium and Thorium. Highlights: Black-Right-Pointing-Pointer Composite of PAAm-HAP was synthesized from hydroxyapatite and polyacrylamide. Black-Right-Pointing-Pointer The materials were characterized by BET, FT-IR, XRD, SEM, TGA and PZC analysis. Black-Right-Pointing-Pointer HAP and PAAm-HAP had high sorption capacity and very rapid uptake for UO{sub 2}{sup 2+} and Th{sup 4+}. Black-Right-Pointing-Pointer Super porous PAAm was obtained from PAAm-HAP after its removal of HAP content. Black-Right-Pointing-Pointer The composite is potential for deposition of U, Th and its associate radionuclides.« less

40 CFR 63.5545 - What are my monitoring installation, operation, and maintenance requirements?

Code of Federal Regulations, 2010 CFR

2010-07-01

... measure organic HAP emissions; and (iv) PS-15 of 40 CFR part 60, appendix B, for CEMS that use Fourier transform infrared spectroscopy to measure organic HAP emissions. (2) You must conduct a performance...

Peat Water Purification by Hydroxyapatite (HAp) Synthesized from Waste Pensi (Corbicula moltkiana) Shells

NASA Astrophysics Data System (ADS)

Fajri Alif, Matlal; Aprillia, Wandha; Arief, Syukri

2018-01-01

Hydroxyapatite (HAP) were synthesized from Pensi (Corbicula moltkiana) sheels by hydrothermal method and used as adsorbent for peat water purification. Batch adsorption experiments were performed to investigate the effects of various factors such as contact time, adsorbent dosage, and pH. The obtained materials were characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and scanning electron microscope (SEM). Results showed that HAP calcined at 900°C (HAP900) and 1000°C (HAP1000) have a poorly crystalline shape. HAP900 also contain Tetracalsium Phosphate (TTCP) with a Ca/P molar ratio 2.18, while HAP 1000 contain HAp with a Ca/P molar ratio 1.67. Optimum condition for peat water purification with HAP900 and HAP1000 were both achieved at 1 hours, 1 grams adsorben mass at pH 2. SEM micrographs show that after purification, the surface of HAP were covered by organic compounds from peat water.

40 CFR 63.4961 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2010 CFR

2010-07-01

... the compliance period, kg. AI = Total mass of organic HAP in the coatings used in the controlled... coating operation in Equation 1D of this section. ER23MY03.028 Where: AI = Total mass of organic HAP in...

40 CFR Table 5 to Subpart U of... - Known Organic HAP Emitted From the Production of Elastomer Products

Code of Federal Regulations, 2014 CFR

2014-07-01

... products] Organic HAP/Chemical name (CAS No.) Elastomer product/subcategory BR EPI EPR HYP NEO NBL NBR PBR.... NEO = Neoprene. NBL = Nitrile Butadiene Latex. NBR = Nitrile Butadiene Rubber. PBR/SBRS...

40 CFR Table 5 to Subpart U of... - Known Organic HAP Emitted From the Production of Elastomer Products

Code of Federal Regulations, 2012 CFR

2012-07-01

... products] Organic HAP/Chemical name (CAS No.) Elastomer product/subcategory BR EPI EPR HYP NEO NBL NBR PBR.... NEO = Neoprene. NBL = Nitrile Butadiene Latex. NBR = Nitrile Butadiene Rubber. PBR/SBRS...

40 CFR Table 5 to Subpart U of... - Known Organic HAP Emitted From the Production of Elastomer Products

Code of Federal Regulations, 2011 CFR

2011-07-01

... products] Organic HAP/Chemical name (CAS No.) Elastomer product/subcategory BR EPI EPR HYP NEO NBL NBR PBR.... NEO = Neoprene. NBL = Nitrile Butadiene Latex. NBR = Nitrile Butadiene Rubber. PBR/SBRS...

40 CFR Table 5 to Subpart U of... - Known Organic HAP Emitted From the Production of Elastomer Products

Code of Federal Regulations, 2013 CFR

2013-07-01

... products] Organic HAP/Chemical name (CAS No.) Elastomer product/subcategory BR EPI EPR HYP NEO NBL NBR PBR.... NEO = Neoprene. NBL = Nitrile Butadiene Latex. NBR = Nitrile Butadiene Rubber. PBR/SBRS...

40 CFR 63.4730 - What records must I keep?

Code of Federal Regulations, 2011 CFR

2011-07-01

... to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of..., and cleaning material used during each compliance period. (e) A record of the mass fraction of organic...

40 CFR 63.4730 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... used to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of..., and cleaning material used during each compliance period. (e) A record of the mass fraction of organic...

40 CFR 63.4730 - What records must I keep?

Code of Federal Regulations, 2013 CFR

2013-07-01

... used to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of..., and cleaning material used during each compliance period. (e) A record of the mass fraction of organic...

40 CFR 63.4730 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... used to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning... mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of..., and cleaning material used during each compliance period. (e) A record of the mass fraction of organic...

40 CFR Table 6 to Subpart Ffff of... - Requirements for Equipment Leaks

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORIES National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical... equipment leaks: For all . . . And that is part of . . . You must . . . 1. Equipment that is in organic HAP... as specified in § 63.2480(c) and (d). 2. Equipment that is in organic HAP service at a new source a...

40 CFR 63.4322 - How do I demonstrate continuous compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... which the mass fraction of organic HAP, determined according to the requirements of § 63.4321(e)(1)(iv... which the mass fraction of organic HAP exceeded the applicable emission limit in Table 1 to this subpart...

40 CFR 63.4322 - How do I demonstrate continuous compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... which the mass fraction of organic HAP, determined according to the requirements of § 63.4321(e)(1)(iv... which the mass fraction of organic HAP exceeded the applicable emission limit in Table 1 to this subpart...

40 CFR 63.4322 - How do I demonstrate continuous compliance with the emission limitations?

Code of Federal Regulations, 2011 CFR

2011-07-01

... which the mass fraction of organic HAP, determined according to the requirements of § 63.4321(e)(1)(iv... which the mass fraction of organic HAP exceeded the applicable emission limit in Table 1 to this subpart...

40 CFR 63.4322 - How do I demonstrate continuous compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... which the mass fraction of organic HAP, determined according to the requirements of § 63.4321(e)(1)(iv... which the mass fraction of organic HAP exceeded the applicable emission limit in Table 1 to this subpart...

40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... Cj=Average inlet or outlet concentration of TOC or sample organic HAP component j of the gas stream...), where standard temperature is 20 °C. Cj=Inlet or outlet concentration of TOC or sample organic HAP...

40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2014 CFR

2014-07-01

.... Cj=Average inlet or outlet concentration of TOC or sample organic HAP component j of the gas stream...), where standard temperature is 20 °C. Cj=Inlet or outlet concentration of TOC or sample organic HAP...

40 CFR 63.1325 - Batch process vents-performance test methods and procedures to determine compliance.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... Cj=Average inlet or outlet concentration of TOC or sample organic HAP component j of the gas stream...), where standard temperature is 20 °C. Cj=Inlet or outlet concentration of TOC or sample organic HAP...

40 CFR 63.4090 - What emission limits must I meet?

Code of Federal Regulations, 2014 CFR

2014-07-01

... organic HAP emissions to the atmosphere to no more than 0.13 kilogram per liter (kg/liter) (1.1 pound per... affected source, you must limit organic HAP emissions to the atmosphere to no more than 0.022 kg/liter (0...

40 CFR 63.4090 - What emission limits must I meet?

Code of Federal Regulations, 2012 CFR

2012-07-01

... organic HAP emissions to the atmosphere to no more than 0.13 kilogram per liter (kg/liter) (1.1 pound per... affected source, you must limit organic HAP emissions to the atmosphere to no more than 0.022 kg/liter (0...

40 CFR 63.4090 - What emission limits must I meet?

Code of Federal Regulations, 2013 CFR

2013-07-01

... organic HAP emissions to the atmosphere to no more than 0.13 kilogram per liter (kg/liter) (1.1 pound per... affected source, you must limit organic HAP emissions to the atmosphere to no more than 0.022 kg/liter (0...

Ti6Al4V laser surface preparation and functionalization using hydroxyapatite for biomedical applications.

PubMed

Faria, D; Abreu, C S; Buciumeanu, M; Dourado, N; Carvalho, O; Silva, F S; Miranda, G

2018-05-01

This work presents a novel texture design for implants surface functionalization, through the creation of line-shaped textures on Ti6Al4V surfaces and subsequent sintering of hydroxyapatite (HAp) powder into the designated locations. HAp-rich locations were designed to avoid HAp detachment during insertion, thus guaranteeing an effective osseointegration. This process starts by creating textured lines using a Nd:YAG laser, filling these lines with HAp powder and sintering HAp using a CO 2 laser. The adhesion of HAp is known to be influenced by HAp sintering parameters, especially laser power and scanning speed and also by the textured lines manufacturing. Different laser parameters combinations were used to assess the sintering and adhesion of HAp to the textured lines. HAp adhesion was assessed by performing high energy ultrasonic cavitation tests and sliding tests mimicking an implant insertion, with Ti6Al4V/HAp specimens sliding against animal bone. The HAp content retained after these tests was measured and results showed that an excellent HAp sintering and adhesion was achieved when using a scan speed of 1 mm/s and laser power between 9 and 9.6 W. It is important to emphasize that results indicated that the HAp bioactivity was maintained when using these conditions, validating this functionalization process for the production of hip prosthesis with improved bioactivity. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 106B: 1534-1545, 2018. © 2017 Wiley Periodicals, Inc.

Frequency of hospital acquired pneumonia and its microbiological etiology in medical intensive care unit.

PubMed

Imran, Muhammad; Amjad, Alina; Haidri, Fakhir Raza

2016-01-01

The objectives were to assess the frequency of hospital acquired pneumonia (HAP) in patients admitted to intensive care unit (ICU) and to determine the frequencies of different etiological organisms in these patients. This was descriptive cross sectional study, which was carried out in medical ICU of Shifa International Hospital Islamabad from January 2013 to January 2014. A total of 1866 patients were admitted in the department of medicine including medical ICU. They were evaluated for HAP and the causative organisms were cultured from these patients. Identification was carried out by standard biochemical profile of the organisms. The total number of patients admitted in medical ICU for any reason were 346. HAP was diagnosed in 88 patients (25.4%). The average age of patients admitted in Medical ICU with HAP was 48 years with the range of 16 to 82 years. 56 were male and 32 females. 42 patients (47.7%) died in medical ICU with HAP. Microbiological analysis showed that Pseudomonas aeruginosa were 27 (30.6%), Acinetobacter spp. were 12 (13.6%), Candida albicans were 12 (13.6%), Klebsiellapneumoniae were 9 (10.2%), Streptococcus spp. were 9 (10.2%), Escherichia coli were 5 (5.6%), Stenotrophomonas spp. were 4(4.5%), Methicillin Resistant Staphylococcus Aureus (MRSA) were 4 (4.5%) others organisms 6 (6.8%). The frequency of HAP in Medical ICU of our hospital is 88 out of 346 (25.4%). The commonest organism identified was Pseudomonas aeruginosa (30.6%) followed by Acinetobacter and Candida albican (13.6% each).

40 CFR Table 2 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Batch Process Vents

Code of Federal Regulations, 2012 CFR

2012-07-01

... Pollutants: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 2 Table 2 to Subpart FFFF... Group 1 batch process vents a. Reduce collective uncontrolled organic HAP emissions from the sum of all... a flare); or Not applicable. b. Reduce collective uncontrolled organic HAP emissions from the sum of...

40 CFR 63.2354 - What performance tests, design evaluations, and performance evaluations must I conduct?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., appendix A, to determine compliance with the organic HAP or TOC emission limit, you may use EPA Method 18... formaldehyde control efficiency as a surrogate for total organic HAP or TOC efficiency, or at the outlet of a...

National review of ambient air toxics observations.

PubMed

Strum, Madeleine; Scheffe, Richard

2016-02-01

Ambient air observations of hazardous air pollutant (HAPs), also known as air toxics, derived from routine monitoring networks operated by states, local agencies, and tribes (SLTs), are analyzed to characterize national concentrations and risk across the nation for a representative subset of the 187 designated HAPs. Observations from the National Air Toxics Trend Sites (NATTS) network of 27 stations located in most major urban areas of the contiguous United States have provided a consistent record of HAPs that have been identified as posing the greatest risk since 2003 and have also captured similar concentration patterns of nearly 300 sites operated by SLTs. Relatively high concentration volatile organic compounds (VOCs) such as benzene, formaldehyde, and toluene exhibit the highest annual average concentration levels, typically ranging from 1 to 5 µg/m(3). Halogenated (except for methylene chloride) and semivolatile organic compounds (SVOCs) and metals exhibit concentrations typically 2-3 orders of magnitude lower. Formaldehyde is the highest national risk driver based on estimated cancer risk and, nationally, has not exhibited significant changes in concentration, likely associated with the large pool of natural isoprene and formaldehyde emissions. Benzene, toluene, ethylbenzene, and 1,3-butadiene are ubiquitous VOC HAPs with large mobile source contributions that continue to exhibit declining concentrations over the last decade. Common chlorinated organic compounds such as ethylene dichloride and methylene chloride exhibit increasing concentrations. The variety of physical and chemical attributes and measurement technologies across 187 HAPs result in a broad range of method detection limits (MDLs) and cancer risk thresholds that challenge confidence in risk results for low concentration HAPs with MDLs near or greater than risk thresholds. From a national monitoring network perspective, the ability of the HAPs observational database to characterize the multiple pollutant and spatial scale patterns influencing exposure is severely limited and positioned to benefit by leveraging a variety of emerging measurement technologies. Ambient air toxics observation networks have limited ability to characterize the broad suite of hazardous air pollutants (HAPs) that affect exposures across multiple spatial scales. While our networks are best suited to capture major urban-scale signals of ubiquitous volatile organic compound HAPs, incorporation of sensing technologies that address regional and local-scale exposures should be pursued to address major gaps in spatial resolution. Caution should be exercised in interpreting HAPs observations based on data proximity to minimum detection limit and risk thresholds.

40 CFR Appendix - Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Limits for Open Molding, Centrifugal Casting, and SMC Manufacturing Operations Where the Standards Are... CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Reinforced Plastic Composites..., Table 5 Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC...

Electric field-assisted formation of organically modified hydroxyapatite (ormoHAP) spheres in carboxymethylated gelatin gels.

PubMed

Heinemann, C; Heinemann, S; Kruppke, B; Worch, H; Thomas, J; Wiesmann, H P; Hanke, T

2016-10-15

A biomimetic strategy was developed in order to prepare organically modified hydroxyapatite (ormoHAP) with spherical shape. The technical approach is based on electric field-assisted migration of calcium ions and phosphate ions into a hydrogel composed of carboxymethylated gelatin. The electric field as well as the carboxymethylation using glucuronic acid (GlcA) significantly accelerates the mineralization process, which makes the process feasible for lab scale production of ormoHAP spheres and probably beyond. A further process was developed for gentle separation of the ormoHAP spheres from the gelatin gel without compromising the morphology of the mineral. The term ormoHAP was chosen since morphological analyses using electron microscopy (SEM, TEM) and element analysis (EDX, FT-IR, XRD) confirmed that carboxymethylated gelatin molecules use to act as organic templates for the formation of nanocrystalline HAP. The hydroxyapatite (HAP) crystals self-organize to form hollow spheres with diameters ranging from 100 to 500nm. The combination of the biocompatible chemical composition and the unique structure of the nanocomposites is considered to be a useful basis for future applications in functionalized degradable biomaterials. A novel bioinspired mineralization process was developed based on electric field-assisted migration of calcium and phosphate ions into biochemically carboxymethylated gelatin acting as organic template. Advantages over conventional hydroxyapatite include particle size distribution and homogeneity as well as achievable mechanical properties of relevant composites. Moreover, specifically developed calcium ion or phosphate ion release during degradation can be useful to adjust the fate of bone cells in order to manipulate remodeling processes. The hollow structure of the spheres can be useful for embedding drugs in the core, encapsulated by the highly mineralized outer shell. In this way, controlled drug release could be achieved, which enables advanced strategies for threating bone-related diseases, e.g. osteoporosis and multiple myeloma. Copyright © 2016. Published by Elsevier Ltd.

In situ X-ray scattering evaluation of heat-induced ultrastructural changes in dental tissues and synthetic hydroxyapatite

PubMed Central

Sui, Tan; Sandholzer, Michael A.; Lunt, Alexander J. G.; Baimpas, Nikolaos; Smith, Andrew; Landini, Gabriel; Korsunsky, Alexander M.

2014-01-01

Human dental tissues consist of inorganic constituents (mainly crystallites of hydroxyapatite, HAp) and organic matrix. In addition, synthetic HAp powders are frequently used in medical and chemical applications. Insights into the ultrastructural alterations of skeletal hard tissues exposed to thermal treatment are crucial for the estimation of temperature of exposure in forensic and archaeological studies. However, at present, only limited data exist on the heat-induced structural alterations of human dental tissues. In this paper, advanced non-destructive small- and wide angle X-ray scattering (SAXS/WAXS) synchrotron techniques were used to investigate the in situ ultrastructural alterations in thermally treated human dental tissues and synthetic HAp powders. The crystallographic properties were probed by WAXS, whereas HAp grain size distribution changes were evaluated by SAXS. The results demonstrate the important role of the organic matrix that binds together the HAp crystallites in responding to heat exposure. This is highlighted by the difference in the thermal behaviour between human dental tissues and synthetic HAp powders. The X-ray analysis results are supported by thermogravimetric analysis. The results concerning the HAp crystalline architecture in natural and synthetic HAp powders provide a reliable basis for deducing the heating history for dental tissues in the forensic and archaeological context, and the foundation for further development and optimization of biomimetic material design. PMID:24718447

40 CFR Table 2 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Batch Process Vents

Code of Federal Regulations, 2010 CFR

2010-07-01

...: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 2 Table 2 to Subpart FFFF of Part 63... vents a. Reduce collective uncontrolled organic HAP emissions from the sum of all batch process vents... applicable. b. Reduce collective uncontrolled organic HAP emissions from the sum of all batch process vents...

40 CFR Table 2 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Batch Process Vents

Code of Federal Regulations, 2011 CFR

2011-07-01

...: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 2 Table 2 to Subpart FFFF of Part 63... vents a. Reduce collective uncontrolled organic HAP emissions from the sum of all batch process vents... applicable. b. Reduce collective uncontrolled organic HAP emissions from the sum of all batch process vents...

40 CFR 63.3930 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... manufacturer's formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and/or other additive, and cleaning material, and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP...

40 CFR 63.4312 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... manufacturer's formulation data or test data used to determine the mass fraction of organic HAP for coating, printing, slashing, dyeing, finishing, thinning, and cleaning materials; and the mass fraction of solids for coating and printing materials. If you conducted testing to determine mass fraction of organic HAP...

40 CFR 63.3930 - What records must I keep?

Code of Federal Regulations, 2013 CFR

2013-07-01

... manufacturer's formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and/or other additive, and cleaning material, and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP...

40 CFR 63.4312 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... manufacturer's formulation data or test data used to determine the mass fraction of organic HAP for coating, printing, slashing, dyeing, finishing, thinning, and cleaning materials; and the mass fraction of solids for coating and printing materials. If you conducted testing to determine mass fraction of organic HAP...

40 CFR 63.3512 - What records must I keep?

Code of Federal Regulations, 2011 CFR

2011-07-01

... for each coating. If you conducted testing to determine mass fraction of organic HAP, density, or... and thinner used during each compliance period. (e) A record of the mass fraction of organic HAP for... suppliers or manufacturers, such as manufacturer's formulation data, or test data used to determine the mass...

40 CFR 63.3930 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... manufacturer's formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and/or other additive, and cleaning material, and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP...

40 CFR Table 1 to Subpart Bbbbb of... - Requirements for Performance Tests

Code of Federal Regulations, 2010 CFR

2010-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Semiconductor... necessary. 2. Process vent stream a. Measure organic and inorganic HAP concentration (two method option) i... simultaneous sampling at inlet and outlet of control device and analyze for same organic and inorganic HAP at...

40 CFR Table 1 to Subpart Bbbbb of... - Requirements for Performance Tests

Code of Federal Regulations, 2011 CFR

2011-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for Semiconductor... necessary. 2. Process vent stream a. Measure organic and inorganic HAP concentration (two method option) i... simultaneous sampling at inlet and outlet of control device and analyze for same organic and inorganic HAP at...

40 CFR 63.494 - Back-end process provisions-residual organic HAP and emission limitations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... producing butyl rubber, epichlorohydrin elastomer, neoprene, and nitrile butadiene rubber shall not exceed... processes at affected sources producing butyl rubber, epichlorohydrin elastomer, neoprene, and nitrile... submitted in accordance with § 63.499(f)(1). (i) For butyl rubber, the organic HAP emission limitation shall...

40 CFR 63.746 - Standards: Depainting operations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... filter system, three-stage filter system, or other control system equivalent to the three-stage filter... section, and with the requirements specified in paragraph (b) where there are no controls for organic HAP, or paragraph (c) where organic HAP are controlled using a control system. This section does not apply...

PARAMETRIC EVALUATION OF VOC/HAP (VOLATILE ORGANIC COMPOUNDS-HAZARDOUS/TOXIC AIR POLLUTANTS) DESTRUCTION VIA CATALYTIC INCINERATION

EPA Science Inventory

The report describes the use of a pilot-scale catalytic incineration unit/solvent generation system to investigate the effectiveness of catalytic incineration as a way to destroy volatile organic compounds (VOCs) and hazardous/toxic air pollutants (HAPs). Objectives of the study ...

The Haemophilus influenzae Hap Autotransporter Binds to Fibronectin, Laminin, and Collagen IV

PubMed Central

Fink, Doran L.; Green, Bruce A.; St. Geme III, Joseph W.

2002-01-01

Nontypeable Haemophilus influenzae (NTHI) initiates infection by colonizing the upper respiratory tract mucosa. NTHI disease frequently occurs in the context of respiratory tract inflammation, where organisms encounter damaged epithelium and exposed basement membrane. In this study, we examined interactions between the H. influenzae Hap adhesin and selected extracellular matrix proteins. Hap is an autotransporter protein that undergoes autoproteolytic cleavage, with release of the adhesive passenger domain, Haps, from the bacterial cell surface. We found that Hap promotes bacterial adherence to purified fibronectin, laminin, and collagen IV and that Hap-mediated adherence is enhanced by inhibition of autoproteolysis. Adherence is inhibited by pretreatment of bacteria with a polyclonal antiserum recognizing Haps. Purified Haps binds with high affinity to fibronectin, laminin, and collagen IV but not to collagen II. Binding of Haps to fibronectin involves interaction with the 45-kDa gelatin-binding domain but not the 30-kDa heparin-binding domain of fibronectin. Taken together, these observations suggest that interactions between Hap and extracellular matrix proteins may play an important role in NTHI colonization of the respiratory tract. PMID:12183535

Green synthesis of Si-incorporated hydroxyapatite using sodium metasilicate as silicon precursor and in vitro antibiotic release studies.

PubMed

Abinaya Sindu, P; Kolanthai, Elayaraja; Suganthi, R V; Thanigai Arul, K; Manikandan, E; Catalani, Luiz H; Narayana Kalkura, S

2017-10-01

The aim of the current study is to synthesize nanosized silicon incorporated HAp (Si-HAP) using sodium metasilicate as the silicon source. The sol-gel derived samples were further subjected to microwave irradiation. Incorporation of Si into HAp did not alter the HAp phase, as confirmed by the X-ray diffraction analysis (XRD). Moreover, variation in the lattice parameters of the Si-incorporated HAp indicates that Si is substituted into the HAp lattice. The decrease in the intensity of the peaks attributed to hydroxyl groups, which appeared in the FTIR and Raman spectra of Si-HAp, further confirms the Si substitution in HAp lattices. The silicon incorporation enhanced the nanorods length by 70%, when compared to that of pure HAp. Microwave irradiation improved the crystallinity of Si-HAp when compared to as-synthesized Si-HAp samples. As-synthesized Si-incorporated HAp sample showed an intense blue emission under UV excitation. Microwave irradiation reduced the intensity of blue emission and exhibited red shift due to the reduction of defects in the Si-HAp crystal. The morphological change from rod to spherical and ribbon-like forms was observed with an increase in silicon content. Further, Si-HAp exhibited better bioactivity and low dissolution rate. Initially there was a burst release of amoxicillin from all the samples, subsequently it followed a sustained release. The microwave-irradiated HAp showed extended period of sustained release than that of as-synthesized HAp and Si-HAp. Similarly, the microwave-irradiated Si-incorporated samples exhibited prolonged drug release, as compared to that of the as-synthesized samples. Hence, Si-HAp is rapidly synthesized by a simple and cost effective method without inducing any additional phases, as compared to the conventional sintering process. This study provides a new insight into the rapid green synthesis of Si-HAp. Si-HAp could emerge as a promising material for the bone tissue replacement and as a drug delivery system. Copyright © 2017 Elsevier B.V. All rights reserved.

Drawing on Student Knowledge of Neuroanatomy and Neurophysiology

ERIC Educational Resources Information Center

Slominski, Tara N.; Momsen, Jennifer L.; Montplaisir, Lisa M.

2017-01-01

Drawings are an underutilized assessment format in Human Anatomy and Physiology (HA&P), despite their potential to reveal student content understanding and alternative conceptions. This study used student-generated drawings to explore student knowledge in a HA&P course. The drawing tasks in this study focused on chemical synapses between…

40 CFR 63.5994 - How do I conduct tests and procedures for tire production affected sources?

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emissions Standards for Hazardous Air Pollutants... to determine the mass percent of HAP in cements and solvents. To determine the HAP content in the...

40 CFR 63.5997 - How do I conduct tests and procedures for tire cord production affected sources?

Code of Federal Regulations, 2013 CFR

2013-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emissions Standards for Hazardous Air...? (a) Methods to determine the mass percent of each HAP in coatings. (1) To determine the HAP content...

40 CFR 63.5994 - How do I conduct tests and procedures for tire production affected sources?

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Rubber Tire... mass percent of HAP in cements and solvents. To determine the HAP content in the cements and solvents...

40 CFR 63.3941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR... organic HAP. For reactive adhesives in which some of the HAP react to form solids and are not emitted to... reactive adhesives in which some of the HAP react to form solids and are not emitted to the atmosphere, you...

Parallel nano-assembling of a multifunctional GO/HapNP coating on ultrahigh-purity magnesium for biodegradable implants

NASA Astrophysics Data System (ADS)

Santos, C.; Piedade, C.; Uggowitzer, P. J.; Montemor, M. F.; Carmezim, M. J.

2015-08-01

This work reports the one-step fabrication of a novel coating on ultra high purity magnesium using a parallel nano assembling process. The multifunctional biodegradable surface was obtained by adding hydroxyapatite nanoparticles (HapNP) plus graphene oxide (GO). The coating was characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffractometer (XRD), micro-Raman spectroscopy. The thin phosphate coating (thickness of 1 μm) reveals a uniform coverage with cypress like structures. The incorporation of HapNP and GO promotes the hydrophilic behavior of the coating surface. The results revealed that the proposed coating can be used to tailor the surface properties such as wettability by adjusting the contents of HapNP and GO. The in vitro degradation rate of the coated magnesium suggests that the presence of HapNP and GO/HapNP in the phosphate coating decreased the current density compared to the single phosphate coating and uncoated magnesium. This study also reveals the HapNP/GO/phosphate coating induces apatite formation, showing suitable degradability that makes it a promising coating candidate for enhanced bone regeneration.

40 CFR Table 1 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Continuous Process Vents

Code of Federal Regulations, 2010 CFR

2010-07-01

...: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 1 Table 1 to Subpart FFFF of Part 63... vent a. Not applicable i. Reduce emissions of total organic HAP by ≥98 percent by weight or to an outlet process concentration ≤20 ppmv as organic HAP or TOC by venting emissions through a closed-vent...

40 CFR Table 5 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Transfer Racks

Code of Federal Regulations, 2011 CFR

2011-07-01

... Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 5 Table 5 to Subpart FFFF of Part 63—Emission... each . . . You must . . . 1. Group 1 transfer rack a. Reduce emissions of total organic HAP by ≥98 percent by weight or to an outlet concentration ≤20 ppmv as organic HAP or TOC by venting emissions...

40 CFR Table 1 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Continuous Process Vents

Code of Federal Regulations, 2012 CFR

2012-07-01

... Pollutants: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 1 Table 1 to Subpart FFFF... continuous process vent a. Not applicable i. Reduce emissions of total organic HAP by ≥98 percent by weight or to an outlet process concentration ≤20 ppmv as organic HAP or TOC by venting emissions through a...

40 CFR Table 1 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Continuous Process Vents

Code of Federal Regulations, 2011 CFR

2011-07-01

...: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 1 Table 1 to Subpart FFFF of Part 63... vent a. Not applicable i. Reduce emissions of total organic HAP by ≥98 percent by weight or to an outlet process concentration ≤20 ppmv as organic HAP or TOC by venting emissions through a closed-vent...

40 CFR Table 19 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 19 Table 19 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 19 Table 19 to Subpart UUU of Part 63—Initial Compliance With Organic...

40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous Compliance With Organic...

40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance With Organic...

40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance With Organic...

40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous Compliance With Organic...

40 CFR Table 20 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 20 Table 20 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 20 Table 20 to Subpart UUU of Part 63—Continuous Compliance With Organic...

Microwave-induced production of boron-doped HAp (B-HAp) and B-HAp coated composite scaffolds.

PubMed

Tunçay, Ekin Ö; Demirtaş, T Tolga; Gümüşderelioğlu, Menemşe

2017-03-01

The aim of the present study is to produce boron (B) doped hydroxyapatite (B-HAp), which has an osteoinductive property, and investigate in-vitro osteogenesis potential of B-HAp coated chitosan (B-HAp/Ch) scaffolds. At first, B-HAp was produced by the interaction of ions within the concentrated synthetic body fluid containing boron (B-SBF) with microwave energy. Boron incorporation into HAp structure was performed by the substitution of borate ions with phosphate and hydroxyl ions. Experiments were carried out with different microwave powers and exposure times, and optimum conditions for the production of B-HAp were determined. B-HAp precipitated from B-SBF by 600W microwave power has 1.15±0.11% (w/w) B, 1.40 (w/w) Ca/P ratio, 4.30±0.07% (w/w) carbonate content, 30±4nm rod-like morphology and bone-like amorphous structure. Then, chitosan scaffolds that were prepared by freeze-drying were coated with B-HAp by performing microwave-assisted precipitation in the presence of scaffolds to improve their bioactivities and mechanical properties. The formation of apatite layer and the penetration of apatites into the pores were observed by scanning electron microscopy (SEM). Fourier Transform Infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD) analysis also confirmed the presence of B-HAp layer. As control, hydroxyapatite coated chitosan scaffolds (HAp/Ch) produced at the same conditions were used. The results of cell culture studies indicated that B releasing from scaffolds enhances proliferation and osteoblastic differentiation of MC3T3-E1 cells. This work emphasized the importance of the use of B within the scaffolds for enhancing in-vitro bone tissue engineering applications. Copyright © 2017 Elsevier GmbH. All rights reserved.

40 CFR 63.4910 - What notifications must I submit?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., accuracy, and completeness of the report. Such certifications must also comply with the requirements of 40... need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one... mass of organic HAP contained in the waste materials for which you are claiming an allowance in...

40 CFR 63.1426 - Process vent requirements for determining organic HAP concentration, control efficiency, and...

Code of Federal Regulations, 2011 CFR

2011-07-01

... National Emission Standards for Hazardous Air Pollutant Emissions for Polyether Polyols Production § 63... percent reduction may be measured as total epoxide, total organic HAP, or as TOC minus methane and ethane... TOC (minus methane and ethane) concentrations in all process vent streams and primary and secondary...

40 CFR 63.1426 - Process vent requirements for determining organic HAP concentration, control efficiency, and...

Code of Federal Regulations, 2012 CFR

2012-07-01

... National Emission Standards for Hazardous Air Pollutant Emissions for Polyether Polyols Production § 63... percent reduction may be measured as total epoxide, total organic HAP, or as TOC minus methane and ethane... TOC (minus methane and ethane) concentrations in all process vent streams and primary and secondary...

40 CFR 63.4910 - What notifications must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

... need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating. (iii... mass of organic HAP contained in the waste materials for which you are claiming an allowance in...

40 CFR 63.3512 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... used to determine the mass fraction of organic HAP and density for each coating and thinner and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction...) A record of the mass fraction of organic HAP for each coating and thinner used during each...

40 CFR 63.3512 - What records must I keep?

Code of Federal Regulations, 2013 CFR

2013-07-01

... used to determine the mass fraction of organic HAP and density for each coating and thinner and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction...) A record of the mass fraction of organic HAP for each coating and thinner used during each...

40 CFR 63.4530 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and/or other additive, and cleaning material, and the mass fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP, density, or mass fraction of...

40 CFR 63.4510 - What notifications must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner and/or other additive, and for one cleaning material. (ii) Mass fraction of coating solids... required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste materials...

40 CFR 63.824 - Standards: Publication rotogravure printing.

Code of Federal Regulations, 2012 CFR

2012-07-01

....000 For the purposes of this calculation, the mass fraction of organic HAP present in the recovered volatile matter is assumed to be equal to the mass fraction of organic HAP present in the volatile matter... section: (i) Perform a liquid-liquid material balance for each month as follows: (A) Measure the mass of...

40 CFR 63.4530 - What records must I keep?

Code of Federal Regulations, 2013 CFR

2013-07-01

... formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and/or other additive, and cleaning material, and the mass fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP, density, or mass fraction of...

40 CFR 63.4510 - What notifications must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner and/or other additive, and for one cleaning material. (ii) Mass fraction of coating solids... required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste materials...

40 CFR 63.4710 - What notifications must I submit?

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating, one thinner, and one... is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.4910 - What notifications must I submit?

Code of Federal Regulations, 2014 CFR

2014-07-01

... need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating. (iii... mass of organic HAP contained in the waste materials for which you are claiming an allowance in...

40 CFR 63.824 - Standards: Publication rotogravure printing.

Code of Federal Regulations, 2013 CFR

2013-07-01

....000 For the purposes of this calculation, the mass fraction of organic HAP present in the recovered volatile matter is assumed to be equal to the mass fraction of organic HAP present in the volatile matter... section: (i) Perform a liquid-liquid material balance for each month as follows: (A) Measure the mass of...

40 CFR 63.3512 - What records must I keep?

Code of Federal Regulations, 2014 CFR

2014-07-01

... used to determine the mass fraction of organic HAP and density for each coating and thinner and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction...) A record of the mass fraction of organic HAP for each coating and thinner used during each...

40 CFR 63.4710 - What notifications must I submit?

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating, one thinner, and one... is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.4530 - What records must I keep?

Code of Federal Regulations, 2012 CFR

2012-07-01

... formulation data, or test data used to determine the mass fraction of organic HAP and density for each coating, thinner and/or other additive, and cleaning material, and the mass fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP, density, or mass fraction of...

40 CFR 63.4910 - What notifications must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

... need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating. (iii... mass of organic HAP contained in the waste materials for which you are claiming an allowance in...

40 CFR 63.4510 - What notifications must I submit?

Code of Federal Regulations, 2012 CFR

2012-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner and/or other additive, and for one cleaning material. (ii) Mass fraction of coating solids... required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste materials...

40 CFR 63.4510 - What notifications must I submit?

Code of Federal Regulations, 2014 CFR

2014-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner and/or other additive, and for one cleaning material. (ii) Mass fraction of coating solids... required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste materials...

40 CFR 63.4710 - What notifications must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating, one thinner, and one... is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.4730 - What records must I keep?

Code of Federal Regulations, 2010 CFR

2010-07-01

... to determine the mass fraction of organic HAP and density for each coating, thinner, and cleaning material and the volume fraction of coating solids for each coating. If you conducted testing to determine mass fraction of organic HAP, density, or volume fraction of coating solids, you must keep a copy of...

40 CFR Appendix - Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC Manufacturing Operations Where the Standards Are Based on a 95 Percent Reduction Requirement Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL...

40 CFR Appendix - Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC...

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC Manufacturing Operations Where the Standards Are Based on a 95 Percent Reduction Requirement Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL...

40 CFR Appendix - Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC Manufacturing Operations Where the Standards Are Based on a 95 Percent Reduction Requirement Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL...

40 CFR 63.5830 - What are my options for meeting the standards for pultrusion operations subject to the 60 weight...

Code of Federal Regulations, 2010 CFR

2010-07-01

... standards for pultrusion operations subject to the 60 weight percent organic HAP emissions reductions... National Emissions Standards for Hazardous Air Pollutants: Reinforced Plastic Composites Production Options... operations subject to the 60 weight percent organic HAP emissions reductions requirement? You must use one or...

40 CFR Table 4 to Subpart Rrrr of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups 1

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 4 to Subpart IIIi of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 6 to Subpart Qqqq of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 6 to Subpart Qqqq of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Rrrr of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups 1

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 7 to Subpart Kkkk of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 7 to Subpart Kkkk of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 4 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 4 to Subpart IIIi of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 7 to Subpart Kkkk of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 7 to Subpart Kkkk of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 6 to Subpart Qqqq of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 3 to Subpart Nnnn of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 3 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 4 to Subpart Rrrr of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups 1

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 3 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 4 to Subpart Rrrr of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups 1

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Nnnn of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 5 to Subpart Oooo of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Nnnn of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 5 to Subpart Oooo of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Printing, Coating...

40 CFR Table 5 to Subpart Oooo of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart IIIi of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 4 to Subpart Nnnn of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart IIIi of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 4 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 4 to Subpart IIIi of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 7 to Subpart Kkkk of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 4 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 5 to Subpart Qqqq of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Rrrr of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups 1

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 5 to Subpart Oooo of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Printing, Coating...

40 CFR Table 4 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 3 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 4 to Subpart Nnnn of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 3 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 4 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 4 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 6 to Subpart Qqqq of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

40 CFR Table 3 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 3 to Subpart IIIi of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 5 to Subpart Oooo of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 4 to Subpart Oooo of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 6 to Subpart Qqqq of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants...

40 CFR Table 3 to Subpart Mmmm of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating...

40 CFR Table 3 to Subpart Pppp of... - Default Organic HAP Mass Fraction for Solvents and Solvent Blends

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants for...

40 CFR Table 4 to Subpart Nnnn of... - Default Organic HAP Mass Fraction for Petroleum Solvent Groups a

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Default Organic HAP Mass Fraction for... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants: Surface Coating of...

Nanostructure and elastic modulus of single trabecula in bovine cancellous bone.

PubMed

Yamada, Satoshi; Tadano, Shigeru; Fukuda, Sakurako

2014-11-07

We aimed to investigate the elastic modulus of trabeculae using tensile tests and assess the effects of nanostructure at the hydroxyapatite (HAp) crystal scale on the elastic modulus. In the experiments, 18 trabeculae that were at least 3mm in length in the proximal epiphysis of three adult bovine femurs were used. Tensile tests were conducted using a small tensile testing device coupled with microscopy under air-dried condition. The c-axis orientation of HAp crystals and the degree of orientation were measured by X-ray diffraction. To observe the deformation behavior of HAp crystals under tensile loading, the same tensile tests were conducted in X-ray diffraction measurements. The mineral content of specimens was evaluated using energy dispersive X-ray spectrometry. The elastic modulus of a single trabecula varied from 4.5 to 23.6 GPa, and the average was 11.5 ± 5.0 GPa. The c-axis of HAp crystals was aligned with the trabecular axis and the crystals were lineally deformed under tensile loading. The ratio of the HAp crystal strain to the tissue strain (strain ratio) had a significant correlation with the elastic modulus (r=0.79; P<0.001). However, the mineral content and the degree of orientation did not vary widely and did not correlate with the elastic modulus in this study. It suggests that the strain ratio may represent the nanostructure of a single trabecula and would determine the elastic modulus as well as mineral content and orientation. Copyright © 2014 Elsevier Ltd. All rights reserved.

40 CFR Table 3 to Subpart Wwww of... - Organic HAP Emissions Limits for Existing Open Molding Sources, New Open Molding Sources Emitting...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Existing Open Molding Sources, New Open Molding Sources Emitting Less Than 100 TPY of HAP, and New and... CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Reinforced Plastic Composites... Existing Open Molding Sources, New Open Molding Sources Emitting Less Than 100 TPY of HAP, and New and...

Bioinspired Ultralight Inorganic Aerogel for Highly Efficient Air Filtration and Oil-Water Separation.

PubMed

Zhang, Yong-Gang; Zhu, Ying-Jie; Xiong, Zhi-Chao; Wu, Jin; Chen, Feng

2018-04-18

Inorganic aerogels have been attracting great interest owing to their distinctive structures and properties. However, the practical applications of inorganic aerogels are greatly restricted by their high brittleness and high fabrication cost. Herein, inspired by the cancellous bone, we have developed a novel kind of hydroxyapatite (HAP) nanowire-based inorganic aerogel with excellent elasticity, which is highly porous (porosity ≈ 99.7%), ultralight (density 8.54 mg/cm 3 , which is about 0.854% of water density), and highly adiabatic (thermal conductivity 0.0387 W/m·K). Significantly, the as-prepared HAP nanowire aerogel can be used as the highly efficient air filter with high PM 2.5 filtration efficiency. In addition, the HAP nanowire aerogel is also an ideal candidate for continuous oil-water separation, which can be used as a smart switch to separate oil from water continuously. Compared with organic aerogels, the as-prepared HAP nanowire aerogel is biocompatible, environmentally friendly, and low-cost. Moreover, the synthetic method reported in this work can be scaled up for large-scale production of HAP nanowires, free from the use of organic solvents. Therefore, the as-prepared new kind of HAP nanowire aerogel is promising for the applications in various fields.

40 CFR 63.5997 - How do I conduct tests and procedures for tire cord production affected sources?

Code of Federal Regulations, 2011 CFR

2011-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Rubber...) Methods to determine the mass percent of each HAP in coatings. (1) To determine the HAP content in the...

40 CFR 63.3951 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR... coating. For reactive adhesives as defined in § 63.3981, use the mass fraction of organic HAP that is... organic HAP per kg thinner and/or other additive. For reactive adhesives as defined in § 63.3981, use the...

40 CFR 63.5798 - What if I want to use, or I manufacture, an application technology (new or existing) whose...

Code of Federal Regulations, 2010 CFR

2010-07-01

...: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open Molding and... description of the resin or gel coat application technology and supporting organic HAP emissions test data obtained using EPA test methods or their equivalent. The emission test data should be obtained using a...

40 CFR 63.5798 - What if I want to use, or I manufacture, an application technology (new or existing) whose...

Code of Federal Regulations, 2011 CFR

2011-07-01

...: Reinforced Plastic Composites Production Calculating Organic Hap Emissions Factors for Open Molding and... description of the resin or gel coat application technology and supporting organic HAP emissions test data obtained using EPA test methods or their equivalent. The emission test data should be obtained using a...

40 CFR 63.4710 - What notifications must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

...). You do not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating, for one thinner, and for one cleaning material. (ii) Volume fraction of coating solids for one coating... and the mass of organic HAP contained in the waste materials for which you are claiming an allowance...

40 CFR 63.4941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

... material option. (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for each coating, thinner, and cleaning material used during the... 311 (appendix A to 40 CFR part 63). You may use Method 311 for determining the mass fraction of...

40 CFR 63.3510 - What notifications must I submit?

Code of Federal Regulations, 2014 CFR

2014-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating and for one thinner. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating... density is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.4941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

... material option. (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for each coating, thinner, and cleaning material used during the... 311 (appendix A to 40 CFR part 63). You may use Method 311 for determining the mass fraction of...

40 CFR 63.3510 - What notifications must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating and for one thinner. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating... density is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.3510 - What notifications must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating and for one thinner. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating... density is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.3510 - What notifications must I submit?

Code of Federal Regulations, 2012 CFR

2012-07-01

... not need to submit copies of any test reports. (i) Mass fraction of organic HAP for one coating and for one thinner. (ii) Volume fraction of coating solids for one coating. (iii) Density for one coating... density is required. (iv) The amount of waste materials and the mass of organic HAP contained in the waste...

40 CFR 63.4941 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

... material option. (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass fraction of organic HAP for each coating, thinner, and cleaning material used during the... 311 (appendix A to 40 CFR part 63). You may use Method 311 for determining the mass fraction of...

40 CFR 63.4161 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2014 CFR

2014-07-01

... compliance period, kg. AI = total mass of organic HAP in the coatings used in the controlled coating... this section: ER23JY02.007 Where: AI = mass of organic HAP in the coatings used in the controlled... recovery system using a liquid-liquid material balance during the compliance period, kg. AI = total mass of...

40 CFR 63.4161 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2012 CFR

2012-07-01

... compliance period, kg. AI = total mass of organic HAP in the coatings used in the controlled coating... this section: ER23JY02.007 Where: AI = mass of organic HAP in the coatings used in the controlled... recovery system using a liquid-liquid material balance during the compliance period, kg. AI = total mass of...

40 CFR 65.63 - Performance and group status change requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... material or TOC by at least 98 weight-percent or to a concentration of less than 20 parts per million by... recalculate the TRE index value, flow, or TOC or organic hazardous air pollutant (HAP) concentration according.... Engineering assessments shall meet the specifications in § 65.64(i). (2) Concentration. The TOC or organic HAP...

40 CFR Table 6 to Subpart Eeee of... - Initial Compliance With Emission Limits

Code of Federal Regulations, 2010 CFR

2010-07-01

... approval, TOC) emissions by at least 95 weight-percent, or as an option for nonflare combustion devices to an exhaust concentration of ≤20 ppmv Total organic HAP (or, upon approval, TOC) emissions, based on..., or new affected source Reduce total organic HAP (or, upon approval, TOC) emissions from the loading...

40 CFR 63.7184 - What emission limitations, operating limits, and work practice standards must I meet?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Pollutants for Semiconductor Manufacturing Emission Standards § 63.7184 What emission limitations, operating... this section on and after the compliance dates specified in § 63.7183. (b) Process vents—organic HAP emissions. For each organic HAP process vent, other than process vents from storage tanks, you must limit...

40 CFR 63.7184 - What emission limitations, operating limits, and work practice standards must I meet?

Code of Federal Regulations, 2011 CFR

2011-07-01

... Pollutants for Semiconductor Manufacturing Emission Standards § 63.7184 What emission limitations, operating... this section on and after the compliance dates specified in § 63.7183. (b) Process vents—organic HAP emissions. For each organic HAP process vent, other than process vents from storage tanks, you must limit...

40 CFR 63.4720 - What reports must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

...; and if applicable, the calculation used to determine mass of organic HAP in waste materials according... determine mass of organic HAP in waste materials according to § 63.4751(e)(4); the calculation of the total... certification or audit. (vi) The date and time that each CPMS was inoperative, except for zero (low-level) and...

40 CFR 63.4120 - What reports must I submit?

Code of Federal Regulations, 2013 CFR

2013-07-01

... organic HAP in waste materials according to § 63.4151(e)(4). You do not need to submit background data... § 63.4151 and, if applicable, the calculation used to determine the mass of organic HAP in waste... CPMS was inoperative, except for zero (low-level) and high-level checks. (7) The date, time, and...

40 CFR 63.4120 - What reports must I submit?

Code of Federal Regulations, 2011 CFR

2011-07-01

... organic HAP in waste materials according to § 63.4151(e)(4). You do not need to submit background data... § 63.4151 and, if applicable, the calculation used to determine the mass of organic HAP in waste... CPMS was inoperative, except for zero (low-level) and high-level checks. (7) The date, time, and...

40 CFR 63.4161 - How do I demonstrate initial compliance?

Code of Federal Regulations, 2010 CFR

2010-07-01

... compliance period, kg. AI = total mass of organic HAP in the coatings used in the controlled coating... this section: ER23JY02.007 Where: AI = mass of organic HAP in the coatings used in the controlled... recovery system using a liquid-liquid material balance during the compliance period, kg. AI = total mass of...

40 CFR 63.1565 - What are my requirements for organic HAP emissions from catalytic cracking units?

Code of Federal Regulations, 2010 CFR

2010-07-01

... according to the procedures in the plan. (4) The emission limitations and operating limits for organic HAP... work practice standards? You must: (1) Install, operate, and maintain a continuous monitoring system... operating limit in Table 9 of this subpart that applies to you according to the procedures in Table 11 of...

40 CFR 63.1565 - What are my requirements for organic HAP emissions from catalytic cracking units?

Code of Federal Regulations, 2011 CFR

2011-07-01

... according to the procedures in the plan. (4) The emission limitations and operating limits for organic HAP... work practice standards? You must: (1) Install, operate, and maintain a continuous monitoring system... operating limit in Table 9 of this subpart that applies to you according to the procedures in Table 11 of...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking Units As...

40 CFR Table 8 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Catalytic Cracking Units 8 Table 8 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 8 Table 8 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Cracking Units As...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Reforming Units As...

40 CFR Table 15 to Subpart Uuu of... - Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... Catalytic Reforming Units 15 Table 15 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 15 Table 15 to Subpart UUU of Part 63—Organic HAP Emission Limits for Catalytic Reforming Units As...

Rational design of a high-strength bone scaffold platform based on in situ hybridization of bacterial cellulose/nano-hydroxyapatite framework and silk fibroin reinforcing phase.

PubMed

Jiang, Pei; Ran, Jiabing; Yan, Pan; Zheng, Lingyue; Shen, Xinyu; Tong, Hua

2018-02-01

Bacterial cellulose/hydroxyapatite (BC/HAp) composite had favourable bioaffinity but its poor mechanical strength limited its widespread applications in bone tissue engineering (BTE). Silk fibroin, which possesses special crystalline structure, has been widely used as organic reinforcing material, and different SFs have different amino acid sequences, which exhibit different bioaffinity and mechanical properties. In this regard, bacterial cellulose-Antheraea yamamai silk fibroin/hydroxyapatite (BC-AYSF/HAp), bacterial cellulose-Bombyx mori silk fibroin/hydroxyapatite (BC-BMSF/HAp), and BC/HAp nano-composites were synthesized via a novel in situ hybridization method. Compared with BC/HAp and BC-BMSF/HAp, the BC-AYSF/HAp exhibited better interpenetration, which may benefit for the transportation of nutrients and wastes, the adhesion of cells as well. Additionally, the BC-AYSF/HAp also presented superior thermal stability than the other two composites revealed by differential thermal analysis (DTA) and thermogravimetric analysis (TGA). Compression testing indicated that the mechanical strength of BC-BMSF/HAp was greatly reinforced compared with BC/HAp and was even a little higher than that of BC-AYSF/HAp. Tensile testing showed that BC-AYSF/HAp possesses extraordinary mechanical properties with a higher elastic modulus at low strain and higher fracture strength simultaneously than the other two composites. In vitro cell culture exhibited that MC3T3-E1 cells on the BC-AYSF/HAp membrane took on higher proliferative potential than those on the BC-BMSF/HAp membrane. These results suggested that compared with BC-BMSF/HAp, the BC-AYSF/HAp composite was more appropriate as an ideal bone scaffold platform or biomedical membrane to be used in BTE.

Effects for rapid conversion from abalone shell to hydroxyapaptite nanosheets by ionic surfactants.

PubMed

Zhong, Shengnan; Wen, Zhenliang; Chen, Jingdi; Li, Qian; Shi, Xuetao; Ding, Shinnjyh; Zhang, Qiqing

2017-08-01

Hydroxyapatite (HAP) has been widely used for repairing or substituting human hard tissues. In this paper, two typical ionic surfactants, cation hexadecyltrimethylammonium bromide (CTAB) and anion sodium dodecyl sulfate (SDS), were used for rapid conversion of HAP from abalone shell. From field emission scanning electron microscopy (FESEM), the prepared HAP is flake-like structure. From X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermal analysis, these samples contain a small amount of calcium carbonate whose content gradually increases by increasing the surfactants. The results showed that the HAP formed fast on the layer of abalone shell powder with the assistance of CTAB and SDS. Copyright © 2017 Elsevier B.V. All rights reserved.

Simultaneous X-ray and neutron diffraction Rietveld refinements of nanophase iron substituted hydroxyapatite

NASA Astrophysics Data System (ADS)

Kyriacou, Andreas

The effect of Fe substitution on the crystal structure of hydroxyapatite (HAp) is studied by applying simultaneous Rietveld refinements of powder x-ray and neutron diffraction patterns. Fe is one of the trace elements replacing Ca in HAp, which is the major mineral phase in bones and teeth. The morphology and magnetic properties of the Fe-HAp system are also studied by transmission electron microscopy and magnetization measurements. Samples of Ca(5-x)Fex(PO4)3OH with 0 ≤ x ≤ 0.3 were prepared. Single phase HAp was identified in x-ray diffraction patterns (XRD) of samples with x < 0.1 inferring that the solubility limits are less than 0.1. Hematite (alpha-Fe2O3) is identified as a secondary phase for higher Fe content. The refined parameters show that Fe is incorporated in the HAp structure by replacing Ca in the two crystallographic sites with a preference at the Ca2 site. This preference explains the small effect of the Fe substitution on the lattice constants of HAp. The overall decrease of the lattice constants is explained by the ionic size difference of Ca and Fe. The increasing trend of the a-lattice constant with x in the Fe substituted samples is attributed to a lattice relaxation caused by the substitution of the 4- and 6-fold Fe at the 7- and 9-fold Ca1 and Ca2 sites. This Ca local geometry reduction is indicated by a slight increase of the Ca1-O3 and Ca2-O1 bond lengths. Above the solubility limit x = 0.05, the Fe is partitioned in and out of the HAp structure with increasing nominal Fe content x. The excess Fe is oxidized to hematite. The TEM analysis and magnetic measurements support the results of the simultaneous Rietveld refinements. The TEM images show no significant effect on the morphology and size of the HAp particles upon Fe incorporation. The particles are either spheres or short rods of dimensions 20--60 nm. Hematite particles are imaged in the samples with x exceeding the solubility limit. These particles are spheres, about 15 nm in diameter and are more resistant to electron beam damage. Magnetic measurements reveal a transition of the diamagnetic pure HAp to paramagnetic Fe substituted HAp.

40 CFR 63.3521 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2013 CFR

2013-07-01

.... (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified... to be 0.5 percent of the material by mass, you do not have to count it. Express the mass fraction of...

40 CFR 63.3521 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2014 CFR

2014-07-01

.... (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified... to be 0.5 percent of the material by mass, you do not have to count it. Express the mass fraction of...

40 CFR 63.3521 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2012 CFR

2012-07-01

.... (a) Determine the mass fraction of organic HAP for each material used. You must determine the mass...). You may use Method 311 for determining the mass fraction of organic HAP. Use the procedures specified... to be 0.5 percent of the material by mass, you do not have to count it. Express the mass fraction of...

40 CFR 63.1433 - Wastewater provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... exclusively to organic HAP listed on Table 8 of 40 CFR part 63, subpart G. (ii) When the HON requirements in §§ 63.132 through 63.149 refer to Table 9 compounds, the owner or operator is only required to consider compounds that meet the definition of organic HAP in § 63.1423 and that are listed in Table 9 of 40 CFR part...

40 CFR 63.1426 - Process vent requirements for determining organic HAP concentration, control efficiency, and...

Code of Federal Regulations, 2010 CFR

2010-07-01

... percent reduction may be measured as total epoxide, total organic HAP, or as TOC minus methane and ethane... TOC (minus methane and ethane) concentrations in all process vent streams and primary and secondary... million by volume total epoxide or TOC limit in § 63.1425(b)(1)(ii) or (b)(2)(iii), the sampling site...

40 CFR 63.115 - Process vent provisions-methods and procedures for process vent group determination.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 2 process vent definition of this subpart shall measure either total organic HAP or TOC... either TOC (minus methane and ethane) or organic HAP shall be calculated according to paragraph (c)(3)(ii)(A) or (c)(3)(ii)(B) of this section as applicable. (A) The TOC concentration (CTOC) is the sum of...

40 CFR 63.4751 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2011 CFR

2011-07-01

... during the month, grams. A = Total mass of organic HAP in the coatings used during the month, grams, as... month, grams, as calculated in Equation 1B of this section. C = Total mass of organic HAP in the cleaning materials used during the month, grams, as calculated in Equation 1C of this section. Rw = Total...

40 CFR Table 4 to Subpart Ffff of... - Emission Limits for Storage Tanks

Code of Federal Regulations, 2012 CFR

2012-07-01

... CATEGORIES (CONTINUED) National Emission Standards for Hazardous Air Pollutants: Miscellaneous Organic Chemical Manufacturing Pt. 63, Subpt. FFFF, Table 4 Table 4 to Subpart FFFF of Part 63—Emission Limits for.... Reduce total HAP emissions by ≥95 percent by weight or to ≤20 ppmv of TOC or organic HAP and ≤20 ppmv of...

40 CFR 63.5870 - How do I calculate annual uncontrolled and controlled organic HAP emissions from my wet-out area...

Code of Federal Regulations, 2014 CFR

2014-07-01

... apply to each formula applied on each line, determine how much of each formula for each end product is... controlled oven organic HAP emissions estimation equations or factors to each formula. You must determine the... coated end products. This step creates end product/thickness combinations. (2) Identify each formula used...

40 CFR 63.5870 - How do I calculate annual uncontrolled and controlled organic HAP emissions from my wet-out area...

Code of Federal Regulations, 2012 CFR

2012-07-01

... apply to each formula applied on each line, determine how much of each formula for each end product is... controlled oven organic HAP emissions estimation equations or factors to each formula. You must determine the... coated end products. This step creates end product/thickness combinations. (2) Identify each formula used...

40 CFR 63.5870 - How do I calculate annual uncontrolled and controlled organic HAP emissions from my wet-out area...

Code of Federal Regulations, 2013 CFR

2013-07-01

... apply to each formula applied on each line, determine how much of each formula for each end product is... controlled oven organic HAP emissions estimation equations or factors to each formula. You must determine the... coated end products. This step creates end product/thickness combinations. (2) Identify each formula used...

40 CFR 63.5870 - How do I calculate annual uncontrolled and controlled organic HAP emissions from my wet-out area...

Code of Federal Regulations, 2011 CFR

2011-07-01

... each formula applied on each line, determine how much of each formula for each end product is applied... controlled oven organic HAP emissions estimation equations or factors to each formula. You must determine the... coated end products. This step creates end product/thickness combinations. (2) Identify each formula used...

40 CFR Table 12 to Subpart Wwww of... - Data Requirements for New and Existing Continuous Lamination Lines and Continuous Casting Lines...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Continuous Lamination Lines and Continuous Casting Lines Complying With a Lbs/Ton Organic HAP Emissions Limit... Requirements for New and Existing Continuous Lamination Lines and Continuous Casting Lines Complying With a Lbs... with a lbs/ton organic HAP emissions limit for continuous lamination lines and continuous casting lines...

40 CFR Table 2 to Subpart II of... - Volatile Organic HAP (VOHAP) Limits for Marine Coatings

Code of Federal Regulations, 2013 CFR

2013-07-01

... for Marine Coatings 2 Table 2 to Subpart II of Part 63 Protection of Environment ENVIRONMENTAL... (Surface Coating) Pt. 63, Subpt. II, Table 2 Table 2 to Subpart II of Part 63—Volatile Organic HAP (VOHAP) Limits for Marine Coatings Coating category VOHAP limits a,b,c Grams/liter coating (minus water and...

40 CFR Table 2 to Subpart II of... - Volatile Organic HAP (VOHAP) Limits for Marine Coatings

Code of Federal Regulations, 2012 CFR

2012-07-01

... for Marine Coatings 2 Table 2 to Subpart II of Part 63 Protection of Environment ENVIRONMENTAL... (Surface Coating) Pt. 63, Subpt. II, Table 2 Table 2 to Subpart II of Part 63—Volatile Organic HAP (VOHAP) Limits for Marine Coatings Coating category VOHAP limits a,b,c Grams/liter coating (minus water and...

40 CFR Table 2 to Subpart II of... - Volatile Organic HAP (VOHAP) Limits for Marine Coatings

Code of Federal Regulations, 2014 CFR

2014-07-01

... for Marine Coatings 2 Table 2 to Subpart II of Part 63 Protection of Environment ENVIRONMENTAL... (Surface Coating) Pt. 63, Subpt. II, Table 2 Table 2 to Subpart II of Part 63—Volatile Organic HAP (VOHAP) Limits for Marine Coatings Coating category VOHAP limits a b c Grams/liter coating (minus water and...

40 CFR Table 2 to Subpart II of... - Volatile Organic HAP (VOHAP) Limits for Marine Coatings

Code of Federal Regulations, 2010 CFR

2010-07-01

... for Marine Coatings 2 Table 2 to Subpart II of Part 63 Protection of Environment ENVIRONMENTAL... (Surface Coating) Pt. 63, Subpt. II, Table 2 Table 2 to Subpart II of Part 63—Volatile Organic HAP (VOHAP) Limits for Marine Coatings Coating category VOHAP limits a,b,c Grams/liter coating (minus water and...

40 CFR Table 2 to Subpart II of... - Volatile Organic HAP (VOHAP) Limits for Marine Coatings

Code of Federal Regulations, 2011 CFR

2011-07-01

... for Marine Coatings 2 Table 2 to Subpart II of Part 63 Protection of Environment ENVIRONMENTAL... (Surface Coating) Pt. 63, Subpt. II, Table 2 Table 2 to Subpart II of Part 63—Volatile Organic HAP (VOHAP) Limits for Marine Coatings Coating category VOHAP limits a,b,c Grams/liter coating (minus water and...

40 CFR 63.3151 - How do I demonstrate initial compliance with the emission limitations?

Code of Federal Regulations, 2010 CFR

2010-07-01

... matter and use that value as a substitute for mass fraction of organic HAP. (3) Alternative method. You may use an alternative test method for determining the mass fraction of organic HAP once the Administrator has approved it. You must follow the procedure in § 63.7(f) to submit an alternative test method...

40 CFR 63.5890 - How do I calculate an organic HAP emissions factor to demonstrate compliance for continuous...

Code of Federal Regulations, 2010 CFR

2010-07-01

... for Hazardous Air Pollutants: Reinforced Plastic Composites Production Testing and Initial Compliance... per year Oc=controlled oven organic HAP emissions, lbs per year R=total usage of neat resin plus, tpy G=total usage of neat gel coat plus, tpy (b) Averaging option. Use Equation 2 of this section to...

40 CFR 63.5820 - What are my options for meeting the standards for continuous lamination/casting operations?

Code of Federal Regulations, 2010 CFR

2010-07-01

...: Reinforced Plastic Composites Production Options for Meeting Standards § 63.5820 What are my options for... weight percent organic HAP emissions reduction limit in Table 3 to this subpart, you have the option of demonstrating that you achieve 95 percent reduction of all wet-out area organic HAP emissions. (d) Combination...

40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

Cells Recognize and Prefer Bone-like Hydroxyapatite: Biochemical Understanding of Ultrathin Mineral Platelets in Bone.

PubMed

Liu, Cuilian; Zhai, Halei; Zhang, Zhisen; Li, Yaling; Xu, Xurong; Tang, Ruikang

2016-11-09

Hydroxyapatite (HAP) nanocrystallites in all types of bones are distinguished by their ultrathin characteristics, which are uniaxially oriented with fibrillar collagen to uniquely expose the (100) faces. We speculate that living organisms prefer the specific crystal morphology and orientation of HAP because of the interactions between cells and crystals at the mineral-cell interface. Here, bone-like platy HAP (p-HAP) and two different rod-like HAPs were synthesized to investigate the ultrathin mineral modulating effect on cell bioactivity and bone generation. Cell viability and osteogenic differentiation of mesenchymal stem cells (MSCs) were significantly promoted by the platy HAP with (100) faces compared to rod-like HAPs with (001) faces as the dominant crystal orientation, which indicated that MSCs can recognize the crystal face and prefer the (100) HAP faces. This face-specific preference is dependent on the selective adsorption of fibronectin (FN), a plasma protein that plays a central role in cell adhesion, on the HAP surface. This selective adsorption is further confirmed by molecule dynamics (MD) simulation. Our results demonstrate that it is an intelligent choice for cells to use ultrathin HAP with a large (100) face as a basic building block in the hierarchical structure of bone, which is crucial to the promotion of MSCs osteoinductions during bone formation.

Influence of hydrothermal synthesis parameters on the properties of hydroxyapatite nanoparticles.

PubMed

Kuśnieruk, Sylwia; Wojnarowicz, Jacek; Chodara, Agnieszka; Chudoba, Tadeusz; Gierlotka, Stanislaw; Lojkowski, Witold

2016-01-01

Hydroxyapatite (HAp) nanoparticles of tunable diameter were obtained by the precipitation method at room temperature and by microwave hydrothermal synthesis (MHS). The following parameters of the obtained nanostructured HAp were determined: pycnometric density, specific surface area, phase purity, lattice parameters, particle size, particle size distribution, water content, and structure. HAp nanoparticle morphology and structure were determined using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). X-ray diffraction measurements confirmed crystalline HAp was synthesized, which was pure in terms of phase. It was shown that by changing the synthesis parameters, the diameter of HAp nanoparticles could be controlled. The average diameter of the HAp nanoparticles was determined by Scherrer's equation via the Nanopowder XRD Processor Demo web application, which interprets the results of specific surface area and TEM measurements using the dark-field technique. The obtained nanoparticles with average particle diameter ranging from 8-39 nm were characterized by having homogeneous morphology with a needle shape and a narrow particle size distribution. Strong similarities were found when comparing the properties of some types of nanostructured hydroxyapatite with natural occurring apatite found in animal bones and teeth.

40 CFR 63.4781 - What definitions apply to this subpart?

Code of Federal Regulations, 2014 CFR

2014-07-01

..., stains, sealers, topcoats, basecoats, primers, enamels, inks, and adhesives. Laminated wood product means... HAP to the mass of a material in which it is contained, expressed as grams of organic HAP per gram of...

40 CFR 63.4781 - What definitions apply to this subpart?

Code of Federal Regulations, 2012 CFR

2012-07-01

..., stains, sealers, topcoats, basecoats, primers, enamels, inks, and adhesives. Laminated wood product means... HAP to the mass of a material in which it is contained, expressed as grams of organic HAP per gram of...

40 CFR 63.4781 - What definitions apply to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

..., stains, sealers, topcoats, basecoats, primers, enamels, inks, and adhesives. Laminated wood product means... HAP to the mass of a material in which it is contained, expressed as grams of organic HAP per gram of...

40 CFR 63.4781 - What definitions apply to this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

..., stains, sealers, topcoats, basecoats, primers, enamels, inks, and adhesives. Laminated wood product means... HAP to the mass of a material in which it is contained, expressed as grams of organic HAP per gram of...

40 CFR 63.4781 - What definitions apply to this subpart?

Code of Federal Regulations, 2011 CFR

2011-07-01

..., stains, sealers, topcoats, basecoats, primers, enamels, inks, and adhesives. Laminated wood product means... HAP to the mass of a material in which it is contained, expressed as grams of organic HAP per gram of...

Pure and zinc doped nano-hydroxyapatite: Synthesis, characterization, antimicrobial and hemolytic studies

NASA Astrophysics Data System (ADS)

Tank, Kashmira P.; Chudasama, Kiran S.; Thaker, Vrinda S.; Joshi, Mihir J.

2014-09-01

The structural, antimicrobial, and hemolytic properties and bioactivity have been studied of pure hydroxyapatite (HAP) and zinc doped hydroxyapatite (Zn-HAP) nano-particles for their medical applications. Pure HAP and Zn-HAP nano-particles were synthesized by the surfactant mediated approach. The doping of zinc was estimated by EDAX. The average particle size was determined by applying Scherrer's formula to powdered XRD patterns. The nano-particle morphology was studied by TEM and the presence of various functional groups was identified by FTIR spectroscopy. Good antimicrobial activity of nano-HAP and nano-Zn-HAP was found against five organisms, viz., Pseudomonas aeruginosa and Shigella flexneri as Gram negative as well as Micrococcus luteus, Staphylococcous aureus and Bacillus cereus as Gram positive. The ability of new apatite formation on the surface of pure and doped HAP samples was studied by using Simulated Body Fluid (SBF) in vitro. Hemolytic study indicated that all samples were non-hemolytic and suggesting potential application as bone implant material.

Durable Self-Cleaning Coatings for Architectural Surfaces by Incorporation of TiO2 Nano-Particles into Hydroxyapatite Films

PubMed Central

Sassoni, Enrico; D’Amen, Eros; Roveri, Norberto

2018-01-01

To prevent soiling of marble exposed outdoors, the use of TiO2 nano-particles has been proposed in the literature by two main routes, both raising durability issues: (i) direct application to marble surface, with the risk of particle leaching by rainfall; (ii) particle incorporation into inorganic or organic coatings, with the risk of organic coating degradation catalyzed by TiO2 photoactivity. Here, we investigated the combination of nano-TiO2 and hydroxyapatite (HAP), previously developed for marble protection against dissolution in rain and mechanical consolidation. HAP-TiO2 combination was investigated by two routes: (i) sequential application of HAP followed by nano-TiO2 (“H+T”); (ii) simultaneous application by introducing nano-TiO2 into the phosphate solution used to form HAP (“HT”). The self-cleaning ability was evaluated before and after prolonged exposure to simulated rain. “H+T” and “HT” coatings exhibited much better resistance to nano-TiO2 leaching by rain, compared to TiO2 alone. In “H+T” samples, TiO2 nano-particles adhere better to HAP (having flower-like morphology and high specific surface area) than to marble. In “HT” samples, thanks to chemical bonds between nano-TiO2 and HAP, the particles are firmly incorporated in the HAP coating, which protects them from leaching by rain, without diminishing their photoactivity and without being degraded by them. PMID:29360789

40 CFR 63.5799 - How do I calculate my facility's organic HAP emissions on a tpy basis for purposes of determining...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Emissions Factors for Open Molding and Centrifugal Casting § 63.5799 How do I calculate my facility's... new facility that does not have any of the following operations: Open molding, centrifugal casting... existing facilities, do not include any organic HAP emissions where resin or gel coat is applied to an open...

40 CFR 63.5799 - How do I calculate my facility's organic HAP emissions on a tpy basis for purposes of determining...

Code of Federal Regulations, 2010 CFR

2010-07-01

... Emissions Factors for Open Molding and Centrifugal Casting § 63.5799 How do I calculate my facility's... new facility that does not have any of the following operations: Open molding, centrifugal casting... existing facilities, do not include any organic HAP emissions where resin or gel coat is applied to an open...

40 CFR 63.5799 - How do I calculate my facility's organic HAP emissions on a tpy basis for purposes of determining...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Calculating Organic Hap Emissions Factors for Open Molding and Centrifugal Casting § 63.5799 How do I.../casting operations, or a new facility that does not have any of the following operations: Open molding... coat is applied to an open centrifugal mold using open molding application techniques. Table 1 and the...

40 CFR 63.5799 - How do I calculate my facility's organic HAP emissions on a tpy basis for purposes of determining...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Calculating Organic Hap Emissions Factors for Open Molding and Centrifugal Casting § 63.5799 How do I.../casting operations, or a new facility that does not have any of the following operations: Open molding... coat is applied to an open centrifugal mold using open molding application techniques. Table 1 and the...

40 CFR Table 5 to Subpart Wwww of... - Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC...

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Alternative Organic HAP Emissions Limits for Open Molding, Centrifugal Casting, and SMC Manufacturing Operations Where the Standards Are Based on a 95 Percent Reduction Requirement 5 Table 5 to Subpart WWWW of Part 63 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED)...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance...

40 CFR Table 19 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 19 Table 19 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 19 Table 19 to Subpart UUU of Part 63—Initial Compliance...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63—Continuous...

40 CFR Table 18 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units 18 Table 18 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 18 Table 18 to Subpart UUU of Part 63—Requirements for...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63—Continuous...

40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

Code of Federal Regulations, 2010 CFR

2010-07-01

...) for Carbon Monoxide (CO) 11 Table 11 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 11 Table 11 to Subpart UUU of Part 63—Requirements for Performance Tests for Organic HAP Emissions...

40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63—Continuous...

40 CFR Table 20 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 20 Table 20 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 20 Table 20 to Subpart UUU of Part 63—Continuous...

40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 13 Table 13 to Subpart UUU of Part 63—Continuous...

40 CFR Table 20 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 20 Table 20 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 20 Table 20 to Subpart UUU of Part 63—Continuous...

40 CFR Table 18 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units 18 Table 18 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 18 Table 18 to Subpart UUU of Part 63—Requirements for...

40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63...

40 CFR Table 12 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Initial Compliance With Organic HAP Emission Limits for Catalytic Cracking Units 12 Table 12 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 12 Table 12 to Subpart UUU of Part 63—Initial Compliance...

40 CFR Table 19 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 13 2013-07-01 2012-07-01 true Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 19 Table 19 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 19 Table 19 to Subpart UUU of Part 63—Initial Compliance...

40 CFR Table 18 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units 18 Table 18 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 18 Table 18 to Subpart UUU of Part 63—Requirements for...

40 CFR Table 21 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Reforming Units 21 Table 21 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 21 Table 21 to Subpart UUU of Part 63...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63—Continuous...

40 CFR Table 20 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 20 Table 20 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 20 Table 20 to Subpart UUU of Part 63—Continuous...

40 CFR Table 18 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 12 2011-07-01 2009-07-01 true Requirements for Performance Tests for Organic HAP Emissions From Catalytic Reforming Units 18 Table 18 to Subpart UUU of Part 63 Protection of... Units Pt. 63, Subpt. UUU, Table 18 Table 18 to Subpart UUU of Part 63—Requirements for Performance Tests...

40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

Code of Federal Regulations, 2011 CFR

2011-07-01

...) for Carbon Monoxide (CO) 11 Table 11 to Subpart UUU of Part 63 Protection of Environment ENVIRONMENTAL... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 11 Table 11 to Subpart UUU of Part 63—Requirements for Performance Tests for Organic HAP Emissions...

40 CFR Table 14 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 13 2012-07-01 2012-07-01 false Continuous Compliance With Operating Limits for Organic HAP Emissions From Catalytic Cracking Units 14 Table 14 to Subpart UUU of Part 63... Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 14 Table 14 to Subpart UUU of Part 63...

40 CFR Table 19 to Subpart Uuu of... - Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 13 2014-07-01 2014-07-01 false Initial Compliance With Organic HAP Emission Limits for Catalytic Reforming Units 19 Table 19 to Subpart UUU of Part 63 Protection of... Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 19 Table 19 to Subpart UUU of Part 63—Initial Compliance...

Biomimetic synthesis of hybrid hydroxyapatite nanoparticles using nanogel template for controlled release of bovine serum albumin.

PubMed

Qin, Jinli; Zhong, Zhenyu; Ma, Jun

2016-05-01

A biomimetic method was used to prepare hybrid hydroxyapatite (HAP) nanoparticles with chitosan/polyacrylic acid (CS-PAA) nanogel. The morphology, structure, crystallinity, thermal properties and biocompatibility of the obtained hybrid nanogel-HAP nanoparticles have been characterized. In addition, bovine serum albumin (BSA) was used as a model protein to study the loading and release behaviors of the hybrid nanogel-HAP nanoparticles. The results indicated that the obtained HAP nanoparticles were agglomerated and the nanogel could regulate the formation of HAP. When the nanogel concentration decreased, different HAP crystal shapes and agglomerate structures were obtained. The loading amount of BSA reached 67.6 mg/g for the hybrid nanoparticles when the mineral content was 90.4%, which decreased when the nanogel concentration increased. The release profile of BSA was sustained in neutral buffer. Meanwhile, an initial burst release was found at pH 4.5 due to the desorption of BSA from the surface, followed by a slow release. The hemolysis percentage of the hybrid nanoparticles was close to the negative control, and these particles were non-toxic to bone marrow stromal stem cells. The results suggest that these hybrid nanogel-HAP nanoparticles are promising candidate materials for biocompatible drug delivery systems. Copyright © 2016 Elsevier B.V. All rights reserved.

Effect of hydroxyapatite on the biodegradation and biomechanical stability of polyester nanocomposites for orthopaedic applications.

PubMed

Jayabalan, M; Shalumon, K T; Mitha, M K; Ganesan, K; Epple, M

2010-03-01

The effect of hydroxyapatite (HAP) on the performance of nanocomposites of an unsaturated polyester, i.e., hydroxy-terminated high molecular weight poly(proplyene fumarate) (HT-PPFhm), was investigated. A thermoset nanocomposite was prepared with nanoparticles of calcined HAP (<100 nm, rod-like shape, filler content 30 wt.%), HT-PPFhm and N-vinyl pyrrolidone, dibenzoyl peroxide and N,N-dimethyl aniline. Two more nanocomposites were prepared with precipitated HAP nanoparticles (<100 nm rod-like shape) and commercially available HAP nanoparticles (<200 nm spherical shape), respectively. Calcined HAP nanoparticles resulted in very good crosslinking in the resin matrix with high crosslinking density and interfacial bonding with the polymer, owing to the rod-like shape of the nanoparticles; this gave improved biomechanical strength and modulus and also controlled degradation of the nanocomposite for scaffold formation. The tissue compatibility and osteocompatibility of the nanocomposite containing calcined HAP nanoparticles was evaluated. The tissue compatibility was studied by intramuscular implantation in a rabbit animal model for 3 months as per ISO standard 10993/6. The in vivo femoral bone repair was also carried out in the rabbit animal model as per ISO standard 10993/6. The nanocomposite containing calcined HAP nanoparticles is both biocompatible and osteocompatible. Copyright 2009 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

DEMONSTRATION OF NO-VOC/NO-HAP WOOD FURNITURE COATING SYSTEM

EPA Science Inventory

The United States Environmental Protection Agency has contracted with AeroVironment Environmental Services, Inc. and its subcontractor, Adhesives Coating Co., to develop and demonstrate a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood furniture coating s...

The activity of the artemisinic aldehyde Δ11(13) reductase promoter is important for artemisinin yield in different chemotypes of Artemisia annua L.

PubMed

Yang, Ke; Monfared, Sajad Rashidi; Monafared, Rashidi Sajad; Wang, Hongzhen; Lundgren, Anneli; Brodelius, Peter E

2015-07-01

The artemisinic aldehyde double bond reductase (DBR2) plays an important role in the biosynthesis of the antimalarial artemisinin in Artemisia annua. Artemisinic aldehyde is reduced into dihydroartemisinic aldehyde by DBR2. Artemisinic aldehyde can also be oxidized by amorpha-4,11-diene 12-hydroxylase and/or aldehyde dehydrogenase 1 to artemisinic acid, a precursor of arteannuin B. In order to better understand the effects of DBR2 expression on the flow of artemisinic aldehyde into either artemisinin or arteannuin B, we determined the content of dihydroartemisinic aldehyde, artemisinin, artemisinic acid and arteannuin B content of A. annua varieties sorted into two chemotypes. The high artemisinin producers (HAPs), which includes the '2/39', 'Chongqing' and 'Anamed' varieties, produce more artemisinin than arteannuin B; the low artemisinin producers (LAPs), which include the 'Meise', 'Iran#8', 'Iran#14', 'Iran#24' and 'Iran#47' varieties, produce more arteannuin B than artemisinin. Quantitative PCR showed that the relative expression of DBR2 was significantly higher in the HAP varieties. We cloned and sequenced the promoter of the DBR2 gene from varieties of both the LAP and the HAP groups. There were deletions/insertions in the region just upstream of the ATG start codon in the LAP varities, which might be the reason for the different promoter activities of the HAP and LAP varieties. The relevance of promoter variation, DBR2 expression levels and artemisinin biosynthesis capabilities are discussed and a selection method for HAP varieties with a DNA marker is suggested. Furthermore, putative cis-acting regulatory elements differ between the HAP and LAP varieties.

Synthesis and characterization of silver doped hydroxyapatite nanocomposite coatings and evaluation of their antibacterial and corrosion resistance properties in simulated body fluid.

PubMed

Mirzaee, Majid; Vaezi, Mohammadreza; Palizdar, Yahya

2016-12-01

Silver-doped hydroxyapatite (Ca10-xAgx(PO4)6(OH)2-x) films were synthesized and deposited on anodized titanium (Ti) using electrophoretic. The influence of different silver-dopant contents (X=0, 0.02, 0.05, 0.08 and 0.1) on the phase formation and microstructure of the powders were characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscope (XPS), and Fourier transform infrared spectrum analysis (FT-IR). XRD analysis confirmed the formation of Hexagonal structure of hydroxyapatite (HAp) annealed at 600°C with a small shift in the major peak position toward lower angles with adding silver. FT-IR spectroscopy disclosed the presence of the different vibrational modes matching to phosphates and hydroxyl groups and the absence of any band characteristics to silver. XPS analysis showed that 75% and 23% of silver was in the chemical states of Ag(2+) and Ag(+), respectively. However, only about 2% of silver was in the Ag(0) state, resulting in the high quality of nanocomposite films. The anodization treatment improves the bond strength between the Ag doped HAp deposited layers on TiO2. HAp and silver doped HAp (X=0.05) are regarded to be hydrophilic due to a large number of -OH groups on the surface. The sample with content of silver (x=0.05) also showed excellent antimicrobial efficacy (>99% reduction in viable cells). Electrochemical reveals the passive current densities of the HAp coated anodized Ti are lower than those of silver doped HAp coated anodized Ti, leading to a slightly lower corrosion resistance. Copyright © 2016 Elsevier B.V. All rights reserved.

Modified Fe3O4- hydroxyapatite nanocomposites as heterogeneous catalysts in three UV, Vis and Fenton like degradation systems

NASA Astrophysics Data System (ADS)

Valizadeh, S.; Rasoulifard, M. H.; Dorraji, M. S. Seyed

2014-11-01

The magnetite-hydroxyapatite (M-HAP) nanocomposites were prepared by a chemical co- precipitation procedure and characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and diffuse reflectance spectra (DRS). The ability of the synthesized catalyst for photocatalytic degradation of Acid Blue 25 (AB25), as an organic dye, under UV irradiation was studied. The catalyst was modified employing transition metals (Mn, Fe, Co, Ni, Cu and Zn) trying to improve the catalytic performance of HAP in absence of UV irradiation and in the presence of hydrogen peroxide i.e. a Fenton like reaction. The best results obtained for Cu and Co modified M-HAPs and the effect of operational parameters such pH, amount of catalyst and hydrogen peroxide concentration was studied. In order to investigate the performance of HAP based photocatalyst in visible light region, M-HAP was modified with silver ions. At the end, Langmuir-Hinshelwood kinetic expression used to evaluate and compare the catalytic systems. The strongest degradation activity was observed for Ag-M-HAP/Vis system because of Ag3PO4 formation. Apparent reaction rate constant (Kapp) by Ag-M-HAP/Vis was 63, 36 and 19 times faster than Cu-M-HAP(II)/H2O2, Co-M-HAP(II)/H2O2 and M-HAP (I)/UV systems, respectively.

Newly Developed Biocompatible Material: Dispersible Titanium-Doped Hydroxyapatite Nanoparticles Suitable for Antibacterial Coating on Intravascular Catheters.

PubMed

Furuzono, Tsutomu; Okazaki, Masatoshi; Azuma, Yoshinao; Iwasaki, Mitsunobu; Kogai, Yasumichi; Sawa, Yoshiki

2017-01-01

Thirteen patients with chlorhexidine-silver sulfadiazine-impregnated catheters have experienced serious anaphylactic shock in Japan. These adverse reactions highlight the lack of commercially available catheters impregnated with strong antibacterial chemical agents. A system should be developed that can control both biocompatibility and antibacterial activity. Hydroxyapatite (HAp) is biocompatible with bone and skin tissues. To provide antibacterial activity by using an external physical stimulus, titanium (Ti) ions were doped into the HAp structure. Highly dispersible, Ti-doped HAp (Ti-HAp) nanoparticles suitable as a coating material were developed. In 3 kinds of Ti-HAp [Ti/(Ca + Ti) = 0.05, 0.1, 0.2], the Ti content in the HAp was approximately 70% of that used in the Ti-HAp preparation, as determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES). ICP-AES and X-ray diffraction showed Ti ions were well substituted into the HAp lattice. The nanoparticles were almost uniformly coated on a polyethylene (PE) sheet in a near-monolayer with a surface coverage ratio >95%. The antibacterial activity of the Ti-HAp nanoparticles containing 7.3% Ti ions and coating the sheet was evaluated by calculating the survival ratio of Pseudomonas aeruginosa on the coated sheet after ultraviolet (UV) irradiation. The Ti-HAp-coated sheet showed a 50% decrease in the number of P. aeruginosa compared with that on an uncoated control PE sheet after UV irradiation for 30 s. Key Messages: A system of biocompatibility and antibacterial activity with an on/off switch controlled by external UV stimulation was developed. The system is expected to be applicable in long-term implanted intravascular catheters. © 2017 S. Karger AG, Basel.

Arabidopsis HAP2/GCS1 is a gamete fusion protein homologous to somatic and viral fusogens

PubMed Central

Valansi, Clari; Moi, David; Leikina, Evgenia; Matveev, Elena; Chernomordik, Leonid V.

2017-01-01

Cell–cell fusion is inherent to sexual reproduction. Loss of HAPLESS 2/GENERATIVE CELL SPECIFIC 1 (HAP2/GCS1) proteins results in gamete fusion failure in diverse organisms, but their exact role is unclear. In this study, we show that Arabidopsis thaliana HAP2/GCS1 is sufficient to promote mammalian cell–cell fusion. Hemifusion and complete fusion depend on HAP2/GCS1 presence in both fusing cells. Furthermore, expression of HAP2 on the surface of pseudotyped vesicular stomatitis virus results in homotypic virus–cell fusion. We demonstrate that the Caenorhabditis elegans Epithelial Fusion Failure 1 (EFF-1) somatic cell fusogen can replace HAP2/GCS1 in one of the fusing membranes, indicating that HAP2/GCS1 and EFF-1 share a similar fusion mechanism. Structural modeling of the HAP2/GCS1 protein family predicts that they are homologous to EFF-1 and viral class II fusion proteins (e.g., Zika virus). We name this superfamily Fusexins: fusion proteins essential for sexual reproduction and exoplasmic merger of plasma membranes. We suggest a common origin and evolution of sexual reproduction, enveloped virus entry into cells, and somatic cell fusion. PMID:28137780

40 CFR Table 8 to Subpart G of... - Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources

Code of Federal Regulations, 2012 CFR

2012-07-01

... Wastewater Provisions for Process Units at New Sources 8 Table 8 to Subpart G of Part 63 Protection of... Vessels, Transfer Operations, and Wastewater Pt. 63, Subpt. G, Table 8 Table 8 to Subpart G of Part 63—Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources Chemical name CAS No...

40 CFR Table 8 to Subpart G of... - Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources

Code of Federal Regulations, 2013 CFR

2013-07-01

... Wastewater Provisions for Process Units at New Sources 8 Table 8 to Subpart G of Part 63 Protection of... Vessels, Transfer Operations, and Wastewater Pt. 63, Subpt. G, Table 8 Table 8 to Subpart G of Part 63—Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources Chemical name CAS No...

40 CFR Table 8 to Subpart G of... - Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources

Code of Federal Regulations, 2014 CFR

2014-07-01

... Wastewater Provisions for Process Units at New Sources 8 Table 8 to Subpart G of Part 63 Protection of... Vessels, Transfer Operations, and Wastewater Pt. 63, Subpt. G, Table 8 Table 8 to Subpart G of Part 63—Organic HAP's Subject to the Wastewater Provisions for Process Units at New Sources Chemical name CAS No...

CASE STUDIES: LOW-VOC/HAP WOOD FURNITURE COATINGS

EPA Science Inventory

The report gives results of a study in which wood furniture manufacturing facilities were identified that had converted at least one of their primary coating steps to low-volatile organic compound (VOC)/hazardous Air pollutant (HAP) wood furniture coatings: high-solids, water...

Case study project: The use of low-VOC/HAP coatings at wood furniture manufacturing facilities. Report for March 1995--March 1999

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marshall, A.M.; Jones, J.W.; Fields, J.L.

1999-07-01

The paper discusses a study of pollution prevention and the use of low-VOC/HAP (volatile organic compound/hazardous air pollutant) coatings at wood furniture manufacturing facilities. The study is to identify wood furniture and cabinet manufacturing facilities that have converted to low-VOC/HAP coatings and to develop case studies for those facilities. The case studies include a discussion of the types of products each facility manufactures; the types of low-VOC/HAP coatings each facility is using; problems encountered in converting to low-VOC/HAP coatings; equipment changes that were required; costs associated with the conversion process, including capital costs associated with equipment purchases, research and developmentmore » costs, and operating costs such as operator training in new application techniques;advantages/ disadvantages of the low-VOC/HAP coatings; and customer feedback on products finished with the low-VOC/HAP coatings. The paper discusses the progress of the study and pollution prevention options at wood furniture manufacturing facilities.« less

HapX-Mediated Iron Homeostasis Is Essential for Rhizosphere Competence and Virulence of the Soilborne Pathogen Fusarium oxysporum[C][W][OA

PubMed Central

López-Berges, Manuel S.; Capilla, Javier; Turrà, David; Schafferer, Lukas; Matthijs, Sandra; Jöchl, Christoph; Cornelis, Pierre; Guarro, Josep; Haas, Hubertus; Di Pietro, Antonio

2012-01-01

Soilborne fungal pathogens cause devastating yield losses and are highly persistent and difficult to control. During the infection process, these organisms must cope with limited availability of iron. Here we show that the bZIP protein HapX functions as a key regulator of iron homeostasis and virulence in the vascular wilt fungus Fusarium oxysporum. Deletion of hapX does not affect iron uptake but causes derepression of genes involved in iron-consuming pathways, leading to impaired growth under iron-depleted conditions. F. oxysporum strains lacking HapX are reduced in their capacity to invade and kill tomato (Solanum lycopersicum) plants and immunodepressed mice. The virulence defect of ΔhapX on tomato plants is exacerbated by coinoculation of roots with a biocontrol strain of Pseudomonas putida, but not with a siderophore-deficient mutant, indicating that HapX contributes to iron competition of F. oxysporum in the tomato rhizosphere. These results establish a conserved role for HapX-mediated iron homeostasis in fungal infection of plants and mammals. PMID:22968717

The Janus transcription factor HapX controls fungal adaptation to both iron starvation and iron excess

PubMed Central

Gsaller, Fabio; Hortschansky, Peter; Beattie, Sarah R; Klammer, Veronika; Tuppatsch, Katja; Lechner, Beatrix E; Rietzschel, Nicole; Werner, Ernst R; Vogan, Aaron A; Chung, Dawoon; Mühlenhoff, Ulrich; Kato, Masashi; Cramer, Robert A; Brakhage, Axel A; Haas, Hubertus

2014-01-01

Balance of physiological levels of iron is essential for every organism. In Aspergillus fumigatus and other fungal pathogens, the transcription factor HapX mediates adaptation to iron limitation and consequently virulence by repressing iron consumption and activating iron uptake. Here, we demonstrate that HapX is also essential for iron resistance via activating vacuolar iron storage. We identified HapX protein domains that are essential for HapX functions during either iron starvation or high-iron conditions. The evolutionary conservation of these domains indicates their wide-spread role in iron sensing. We further demonstrate that a HapX homodimer and the CCAAT-binding complex (CBC) cooperatively bind an evolutionary conserved DNA motif in a target promoter. The latter reveals the mode of discrimination between general CBC and specific HapX/CBC target genes. Collectively, our study uncovers a novel regulatory mechanism mediating both iron resistance and adaptation to iron starvation by the same transcription factor complex with activating and repressing functions depending on ambient iron availability. PMID:25092765

Microsphere-Based Scaffolds Encapsulating Tricalcium Phosphate And Hydroxyapatite For Bone Regeneration

PubMed Central

Gupta, Vineet; Lyne, Dina V.; Barragan, Marilyn; Berkland, Cory J.; Detamore, Michael S.

2016-01-01

Bioceramic mixtures of tricalcium phosphate (TCP) and hydroxyapatite (HAp) are widely used for bone regeneration because of their excellent cytocompatibility, osteoconduction, and osteoinduction. Therefore, we hypothesized that incorporation of a mixture of TCP and HAp in microsphere-based scaffolds would enhance osteogenesis of rat bone marrow stromal cells (rBMSCs) compared to a positive control of scaffolds with encapsulated bone-morphogenic protein-2 (BMP-2). Poly(D,L-lactic-co-glycolic acid) (PLGA) microsphere-based scaffolds encapsulating TCP and HAp mixtures in two different ratios (7:3 and 1:1) were fabricated with the same net ceramic content (30 wt%) to evaluate how incorporation of these ceramic mixtures would affect the osteogenesis in rBMSCs. Encapsulation of TCP/HAp mixtures impacted microsphere morphologies and the compressive moduli of the scaffolds. Additionally, TCP/HAp mixtures enhanced the end-point secretion of extracellular matrix (ECM) components relevant to bone tissue compared to the “blank” (PLGA-only) microsphere-based scaffolds as evidenced by the biochemical, gene expression, histology, and immunohistochemical characterization. Moreover, the TCP/HAp mixture groups even surpassed the BMP-2 positive control group in some instances in terms of matrix synthesis and gene expression. Lastly, gene expression data suggested that the rBMSCs responded differently to different TCP/HAp ratios presented to them. Altogether, it can be concluded that TCP/HAp mixtures stimulated the differentiation of rBMSCs toward an osteoblastic phenotype, and therefore may be beneficial in gradient microsphere-based scaffolds for osteochondral regeneration. PMID:27272903

DEVELOPMENT OF A NO-VOC/NO-HAP WOOD FURNITURE COATINGS SYSTEM

EPA Science Inventory

The report gives results of the development and demonstration of a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood furniture coating system. The performance characteristics of the new coating system are excellent in terms of adhesion, drying time, gloss, ...

Molecular mechanics of tropocollagen-hydroxyapatite biomaterials

NASA Astrophysics Data System (ADS)

Dubey, Devendra Kumar

Hard biomaterials such as bone, dentin, and nacre show remarkable mechanical performance and serve as inspiration for development of next generation of composite materials with high strength and toughness. Such materials have primarily an organic phase (e.g. tropocollagen (TC) or chitin) and a mineral phase (e.g. hydroxyapatite (HAP) or aragonite) arranged in a staggered arrangement at nanoscopic length scales. Interfacial interactions between the organic phases and the mineral phases and structural effects arising due to the staggered and hierarchical arrangements are identified to be the two most important determinants for high mechanical performance of such biomaterials. Effects of these determinants in such biomaterials are further intertwined with factors such as loading configuration, chemical environment, mineral crystal shape, and residue sequences in polymer chains. Atomistic modeling is a desired approach to investigate such sub nanoscale issues as experimental techniques for investigations at such small scale are still in nascent stage. For this purpose, explicit three dimensional (3D) molecular dynamics (MD) and ab initio MD simulations of quasi-static mechanical deformations of idealized Tropocollagen-Hydroxyapatite (TC-HAP) biomaterials with distinct interfacial arrangements and different loading configurations are performed. Focus is on developing insights into the molecular level mechanics of TC-HAP biomaterials at fundamental lengthscale with emphasis on interface phenomenon. Idealized TC-HAP atomistic models are analyzed for their mechanical strength and fracture failure behavior from the viewpoint of interfacial interactions between TC and HAP and associated molecular mechanisms. In particular, study focuses on developing an understanding of factors such as role of interfacial structural arrangement, hierarchical structure design, influence of water, effect of changes in HAP crystal shape, and mutations in TC molecule on the mechanical strength of TC-HAP biomaterials. In conjunction, a continuum level tension-shear-chain (TSC) model is also implemented to analyze fracture resistance characteristics in TC-HAP nanocomposites. Results and analyses shed light on the failure mechanisms in TC-HAP type nanocomposite systems with a chemo-mechanical understanding of the interfacial interaction between TC and HAP. Analyses show that (1) failure of TC-HAP nanocomposites at nanoscale is predominantly peak strain dependent phenomenon, (2) presence of water in most cases strengthens the TC-HAP biomaterial by acting as a bridge via hydrogen bond mediated crosslinks, (3) TC-HAP nanostructures with plate shaped HAP crystals show higher toughness and stability as compared to TC-HAP nanostructures with needle shaped HAP crystals, and (4) mutations in TC are responsible for Osteogenesis Imperfecta bone disorder in an indirect manner, wherein mutations in TC affect the shape and distribution of mineral phase during growth and nucleation period of bone. Overall study emphasizes that interfacial structural arrangement between polymer phase and mineral phase in TC-HAP and similar nanocomposite biomaterials is an important factor in determining their mechanical strength and should be carefully studied and selected for development of high performance nanocomposite biomaterials. Findings and understandings from this research have significant impact on polymer-ceramic nanocomposite mechanics, biomaterial and biomimetic materials development, and bone fragility disorders related medical science development.

A novel self-catalyzed photoATRP strategy for preparation of fluorescent hydroxyapatite nanoparticles and their biological imaging

NASA Astrophysics Data System (ADS)

Jiang, Ruming; Liu, Meiying; Huang, Hongye; Huang, Long; Huang, Qiang; Wen, Yuanqing; Cao, Qian-yong; Tian, Jianwen; Zhang, Xiaoyong; Wei, Yen

2018-03-01

Hydroxyapatite (HAp), as an important biomaterial for the regeneration and reconstruction of bone tissue, has attracted more and more attention of researchers and scientists due to its unique structure and compositions. However, the preparation of fluorescent HAp with controllable morphology has achieved only limited success. In this work, we reported a novel strategy to construct the water dispersible fluorescent HAp nanorods via the combination of ligand exchange and metal-free atom transfer radical polymerization (ATRP). The Br-containing fluorescent HAp nanorods with controllable size and morphology were first prepared through hydrothermal treatment. A multifunctional organic molecule (named as PTH-Br) with aggregation-induced emission feature was immobilized on the surface of hydrophobic HAp nanorods through ligand exchange reaction. The PTH-Br could be used as the initiator and catalyst for surface-initiated metal-free ATRP using poly(ethylene glycol) methacrylate as monomer to obtain hydrophilic fluorescent HAp polymer nanoparticles. This strategy successfully endowed HAp nanorods excellent fluorescence properties and favorable water dispersibility but well preserved their regular morphology. Biological assays demonstrated that the HAp-PTH-poly(PEGMA) nanoparticles exhibited good biocompatibility and efficient cell uptake performance. Taken together, we have developed a rather facile strategy based on the surface ligand exchange reaction and metal-free photoATRP to fabricate fluorescent HAp with controllable size and morphology, high water dispersibility and biological properties. These HAp-PTH-poly(PEGMA) nanoparticles should be novel and promising candidates for biomedical applications.

Structure and properties of hydroxyapatite/hydroxyethyl cellulose acetate composite films.

PubMed

Azzaoui, K; Mejdoubi, E; Lamhamdi, A; Zaoui, S; Berrabah, M; Elidrissi, A; Hammouti, B; Fouda, Moustafa M G; Al-Deyab, Salem S

2015-01-22

The main aim of this research work was to develop a new inorganic-organic film. Hydroxyapaptite (HAp) particles that represent the inorganic phase was mixed well with hydroxyethyl cellulose acetate (HECA), which representing the organic phase and then the inorganic-organic films were fabricated by evaporating of the solvent. The structure as well as the properties of the formed films were characterized using different analytical tools such as field emission scanning electron microscopy (FEG-SEM), thermo-gravimetric analysis (TGA), Fourier transform infra-red (FT-IR) spectroscopy. The obtained results revealed that, the HAp nanoparticles was well dispersed and well immobilized throughout the formed films. This can be attributed to the role of the nano- and micropores in the HECA substrate. In addition, a strong interaction occurred between HAp and HECA matrix. The results showed also good thermal stability and miscibility as well. Copyright © 2014 Elsevier Ltd. All rights reserved.

Polarization-induced surface charges in hydroxyapatite ceramics

NASA Astrophysics Data System (ADS)

Horiuchi, N.; Nakaguki, S.; Wada, N.; Nozaki, K.; Nakamura, M.; Nagai, A.; Katayama, K.; Yamashita, K.

2014-07-01

Calcium hydroxyapatite (HAp; Ca10(PO4)6(OH)2) is a well-known biomaterial that is the main inorganic component of bones and teeth. Control over the surface charge on HAp would be a key advance in the development of the material for tissue engineering. We demonstrate here that surface charge can be induced by an electrical poling process using the Kelvin method. Positive and negative charges were induced on the HAp surface in response to the applied electric field in the poling process. The surface charging is attributed to dipole polarization that is homogeneously distributed in HAp. Additionally, the surface charging is considered to originate from the organization of OH- ions into a polar phase in the structure.

HAP-PRO USER'S MANUAL (FOR USE WITH VERSION 1.0)

EPA Science Inventory

The primary purpose of the Hazardous Air Pollutant Program (HAP-PRO) is to assist permit engineers in reviewing applications for control of air toxics by calculating the capital and annual costs for 6 volatile organic compound (VOC) and 3 different particulate control devices, i...

CASE STUDIES: LOW-VOC/HAP WOOD FURNITURE COATINGS (PROJECT SUMMARY)

EPA Science Inventory

The report gives results of a study in which wood furniture manufacturing fa-cilities were identified that had converted at least one of their primary coating steps to low-volatile organic compound (VOC)/hazardous air pollut-ant (HAP) wood furniture coatings [high-solids, waterbo...

Demonstration of Military Composites with Low Hazardous Air Pollutant Content

DTIC Science & Technology

2006-11-01

reducing styrene emissions from vinyl ester (VE) resins is to replace some or all of the styrene with fatty acid -based monomers. Fatty acid ...composite production, and painting applications. These trapping devices need to absorb most of the VOC/HAP emissions and then efficiently remove the...device to trap a significant portion of the emissions is cost prohibitive. Secondly, although these devices remove the VOCs/HAPs from the

Electrochemical Corrosion and In Vitro Bioactivity of SiO2:ZrO2-Coated 316L Stainless Steel in Simulated Body Fluid

NASA Astrophysics Data System (ADS)

Srinivasan, A.; Rajendran, N.

2015-08-01

The effect of Si:Zr ratio on the in vitro bioactivity and electrochemical corrosion behavior of SiO2:ZrO2-mixed oxide-coated 316L stainless steel (SS) was evaluated in simulated body fluid (SBF) solution for 72, 120, and 168 h. Growth of Hydroxyapatite (HAp) was accelerated when Si content in the coating was increased. The Zr content in the coating improved the corrosion resistance of 316L SS rather than accelerating the HAp growth. When the Si:Zr ratio was 50:50, the coating exhibited significant improvement in corrosion resistance as well as HAp growth. The mechanism of HAp growth was proposed based on the change in surface zeta potential values of the coatings. Potentiodynamic polarization studies revealed about 10 and 5 times reduction in corrosion current density ( i corr) values for SiO2:ZrO2 (50:50)-coated 316L SS after 168 h of immersion compared to SiO2, ZrO2, and Si:Zr (70:30) coatings in SBF solutions thus confirming the superior corrosion resistance. The equivalent circuit parameters derived from electrochemical impedance spectroscopy studies further confirmed significant improvement in charge transfer resistance value even after 168 h of exposure.

Environmentally critical elements in channel and cleaned samples of Illinois coals

USGS Publications Warehouse

Demir, I.; Ruch, R.R.; Damberger, H.H.; Harvey, R.D.; Steele, J.D.; Ho, K.K.

1998-01-01

Sixteen trace and minor elements that occur in coal are listed among 189 substances identified as 'hazardous air pollutants' (HAPs) in the US Clean Air Act Amendments of 1990. We investigated the occurrence and cleanability of the 16 HAPs in Illinois coals, as a contribution to the discussion about the potential effect of pending environmental regulations on the future use of these coals in power generation. The average ash content of the samples of conventionally cleaned as-shipped coals is about 20% lower than that of standard channel samples. Conventional cleaning reduces the average concentrations of As, Cd, Co, Hg, Mn, Ni, Pb, Sb and Th in the as-shipped coals by more than 20% relative to channel samples. Thus, basing assessments of health risks from emissions of HAPs during coal combustion on channel samples without appropriate adjustment would overestimate the risk. Additional cleaning by froth-flotation reduces the ash content of finely-ground as-shipped coals by as much as 76% at an 80% combustibles recovery. Although the average froth-flotation cleanability for the majority of HAPs is less than that for ash, the cleanabilities in some individual cases approaches, or even exceeds, the cleanability for ash, depending on the modes of occurrences of the elements. ?? 1997 Elsevier Science Ltd.

Structural analysis of strontium in human teeth treated with surface pre-reacted glass-ionomer filler eluate by using extended X-ray absorption fine structure analysis.

PubMed

Uo, Motohiro; Wada, Takahiro; Asakura, Kiyotaka

2017-03-31

The bioactive effects of strontium released from surface pre-reacted glass-ionomer (S-PRG) fillers may aid in caries prevention. In this study, the local structure of strontium taken up by teeth was estimated by extended X-ray absorption fine structure analysis. Immersing teeth into S-PRG filler eluate increased the strontium content in enamel and dentin by more than 100 times. The local structure of strontium in enamel and dentin stored in distilled water was the same as that in synthetic strontium-containing hydroxyapatite (SrHAP). Moreover, the local structure of strontium in enamel and dentin after immersion in the S-PRG filler eluate was also similar to that of SrHAP. After immersion in the S-PRG filler eluate, strontium was suggested to be incorporated into the hydroxyapatite (HAP) of enamel and dentin at the calcium site in HAP.

Sparse Tensor Decomposition for Haplotype Assembly of Diploids and Polyploids.

PubMed

Hashemi, Abolfazl; Zhu, Banghua; Vikalo, Haris

2018-03-21

Haplotype assembly is the task of reconstructing haplotypes of an individual from a mixture of sequenced chromosome fragments. Haplotype information enables studies of the effects of genetic variations on an organism's phenotype. Most of the mathematical formulations of haplotype assembly are known to be NP-hard and haplotype assembly becomes even more challenging as the sequencing technology advances and the length of the paired-end reads and inserts increases. Assembly of haplotypes polyploid organisms is considerably more difficult than in the case of diploids. Hence, scalable and accurate schemes with provable performance are desired for haplotype assembly of both diploid and polyploid organisms. We propose a framework that formulates haplotype assembly from sequencing data as a sparse tensor decomposition. We cast the problem as that of decomposing a tensor having special structural constraints and missing a large fraction of its entries into a product of two factors, U and [Formula: see text]; tensor [Formula: see text] reveals haplotype information while U is a sparse matrix encoding the origin of erroneous sequencing reads. An algorithm, AltHap, which reconstructs haplotypes of either diploid or polyploid organisms by iteratively solving this decomposition problem is proposed. The performance and convergence properties of AltHap are theoretically analyzed and, in doing so, guarantees on the achievable minimum error correction scores and correct phasing rate are established. The developed framework is applicable to diploid, biallelic and polyallelic polyploid species. The code for AltHap is freely available from https://github.com/realabolfazl/AltHap . AltHap was tested in a number of different scenarios and was shown to compare favorably to state-of-the-art methods in applications to haplotype assembly of diploids, and significantly outperforms existing techniques when applied to haplotype assembly of polyploids.

Greener synthesis of electrospun collagen/hydroxyapatite composite fibers with an excellent microstructure for bone tissue engineering

PubMed Central

Zhou, Yuanyuan; Yao, Hongchang; Wang, Jianshe; Wang, Dalu; Liu, Qian; Li, Zhongjun

2015-01-01

In bone tissue engineering, collagen/hydroxyapatite (HAP) fibrous composite obtained via electrospinning method has been demonstrated to support the cells’ adhesion and bone regeneration. However, electrospinning of natural collagen often requires the use of cytotoxic organic solvents, and the HAP crystals were usually aggregated and randomly distributed within a fibrous matrix of collagen, limiting their clinical potential. Here, an effective and greener method for the preparation of collagen/HAP composite fibers was developed for the first time, and this green product not only had 40 times higher mechanical properties than that previously reported, but also had an excellent microstructure similar to that of natural bone. By dissolving type I collagen in environmentally friendly phosphate buffered saline/ethanol solution instead of the frequently-used cytotoxic organic solvents, followed with the key step of desalination, co-electrospinning the collagen solution with the HAP sol, generates a collagen/HAP composite with a uniform and continuous fibrous morphology. Interestingly, the nano-HAP needles were found to preferentially orient along the longitudinal direction of the collagen fibers, which mimicked the nanostructure of natural bones. Based on the characterization of the related products, the formation mechanism for this novel phenomenon was proposed. After cross-linking with 1-ethyl-3-(3-dimethyl-aminopropyl)-1-carbodiimide hydrochloride/N-hydroxysuccinimide, the obtained composite exhibited a significant enhancement in mechanical properties. In addition, the biocompatibility of the obtained composite fibers was evaluated by in vitro culture of the human myeloma cells (U2-OS). Taken together, the process outlined herein provides an effective, non-toxic approach for the fabrication of collagen/HAP composite nanofibers that could be good candidates for bone tissue engineering. PMID:25995630

Greener synthesis of electrospun collagen/hydroxyapatite composite fibers with an excellent microstructure for bone tissue engineering.

PubMed

Zhou, Yuanyuan; Yao, Hongchang; Wang, Jianshe; Wang, Dalu; Liu, Qian; Li, Zhongjun

2015-01-01

In bone tissue engineering, collagen/hydroxyapatite (HAP) fibrous composite obtained via electrospinning method has been demonstrated to support the cells' adhesion and bone regeneration. However, electrospinning of natural collagen often requires the use of cytotoxic organic solvents, and the HAP crystals were usually aggregated and randomly distributed within a fibrous matrix of collagen, limiting their clinical potential. Here, an effective and greener method for the preparation of collagen/HAP composite fibers was developed for the first time, and this green product not only had 40 times higher mechanical properties than that previously reported, but also had an excellent microstructure similar to that of natural bone. By dissolving type I collagen in environmentally friendly phosphate buffered saline/ethanol solution instead of the frequently-used cytotoxic organic solvents, followed with the key step of desalination, co-electrospinning the collagen solution with the HAP sol, generates a collagen/HAP composite with a uniform and continuous fibrous morphology. Interestingly, the nano-HAP needles were found to preferentially orient along the longitudinal direction of the collagen fibers, which mimicked the nanostructure of natural bones. Based on the characterization of the related products, the formation mechanism for this novel phenomenon was proposed. After cross-linking with 1-ethyl-3-(3-dimethyl-aminopropyl)-1-carbodiimide hydrochloride/N-hydroxysuccinimide, the obtained composite exhibited a significant enhancement in mechanical properties. In addition, the biocompatibility of the obtained composite fibers was evaluated by in vitro culture of the human myeloma cells (U2-OS). Taken together, the process outlined herein provides an effective, non-toxic approach for the fabrication of collagen/HAP composite nanofibers that could be good candidates for bone tissue engineering.

40 CFR 63.5170 - How do I demonstrate compliance with the standards?

Code of Federal Regulations, 2011 CFR

2011-07-01

... for individual or groups of coil coating lines; or overall organic HAP control efficiency is at least... compliant coatings and control devices and maintaining an acceptable equivalent emission rate Average... facility. (6) Control efficiency calculation of HAP emitted. For each work station or group of work...

40 CFR 63.5170 - How do I demonstrate compliance with the standards?

Code of Federal Regulations, 2010 CFR

2010-07-01

... for individual or groups of coil coating lines; or overall organic HAP control efficiency is at least... compliant coatings and control devices and maintaining an acceptable equivalent emission rate Average... facility. (6) Control efficiency calculation of HAP emitted. For each work station or group of work...

DEMONSTRATION OF A NO-VOC/NO-HAP WOOD KITCHEN CABINET COATING SYSTEM

EPA Science Inventory

The report gives results of the development and demonstration of a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood furniture coating system at two cabinet manufacturing plants: one in Portland, OR, and the other in Redwood City, CA. Technology transfer ef...

POLLUTION PREVENTION AND THE USE OF LOW-VOC/HAP COATINGS AT WOOD FURNITURE MANUFACTURING FACILITIES

EPA Science Inventory

The paper discusses a study of pollution prevention and the use of low-VOC/HAP (volatile organic compound/hazardous air pollutant) coatings at wood furniture manufacturing facilities. The study is to identify wood furniture and cabinet manufacturing facilities that have converted...

CASE STUDY PROJECT: THE USE OF LOW-VOC/HAP COATINGS AT WOOD FURNITURE MANUFACTURING FACILITIES

EPA Science Inventory

The paper discusses a study of pollution prevention and the use of low-VOC/HAP (volatile organic compound/hazardous air pollutant) coatings at wood furniture manufacturing facilities. The study is to identify wood furniture and cabinet manufacturing facilities that have converted...

Hydroxyapatite hierarchically nanostructured porous hollow microspheres: rapid, sustainable microwave-hydrothermal synthesis by using creatine phosphate as an organic phosphorus source and application in drug delivery and protein adsorption.

PubMed

Qi, Chao; Zhu, Ying-Jie; Lu, Bing-Qiang; Zhao, Xin-Yu; Zhao, Jing; Chen, Feng; Wu, Jin

2013-04-22

Hierarchically nanostructured porous hollow microspheres of hydroxyapatite (HAP) are a promising biomaterial, owing to their excellent biocompatibility and porous hollow structure. Traditionally, synthetic hydroxyapatite is prepared by using an inorganic phosphorus source. Herein, we report a new strategy for the rapid, sustainable synthesis of HAP hierarchically nanostructured porous hollow microspheres by using creatine phosphate disodium salt as an organic phosphorus source in aqueous solution through a microwave-assisted hydrothermal method. The as-obtained products are characterized by powder X-ray diffraction (XRD), Fourier-transform IR (FTIR) spectroscopy, SEM, TEM, Brunauer-Emmett-Teller (BET) nitrogen sorptometry, dynamic light scattering (DLS), and thermogravimetric analysis (TGA). SEM and TEM micrographs show that HAP hierarchically nanostructured porous hollow microspheres consist of HAP nanosheets or nanorods as the building blocks and DLS measurements show that the diameters of HAP hollow microspheres are within the range 0.8-1.5 μm. The specific surface area and average pore size of the HAP porous hollow microspheres are 87.3 m(2) g(-1) and 20.6 nm, respectively. The important role of creatine phosphate disodium salt and the influence of the experimental conditions on the products were systematically investigated. This method is facile, rapid, surfactant-free and environmentally friendly. The as-prepared HAP porous hollow microspheres show a relatively high drug-loading capacity and protein-adsorption ability, as well as sustained drug and protein release, by using ibuprofen as a model drug and hemoglobin (Hb) as a model protein, respectively. These experiments indicate that the as-prepared HAP porous hollow microspheres are promising for applications in biomedical fields, such as drug delivery and protein adsorption. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

[Nosocomial pneumonia].

PubMed

Díaz, Emili; Martín-Loeches, Ignacio; Vallés, Jordi

2013-12-01

The hospital acquired pneumonia (HAP) is one of the most common infections acquired among hospitalised patients. Within the HAP, the ventilator-associated pneumonia (VAP) is the most common nosocomial infection complication among patients with acute respiratory failure. The VAP and HAP are associated with increased mortality and increased hospital costs. The rise in HAP due to antibiotic-resistant bacteria also causes an increase in the incidence of inappropriate empirical antibiotic therapy, with an associated increased risk of hospital mortality. It is very important to know the most common organisms responsible for these infections in each hospital and each Intensive Care Unit, as well as their antimicrobial susceptibility patterns, in order to reduce the incidence of inappropriate antibiotic therapy and improve the prognosis of patients. Additionally, clinical strategies aimed at the prevention of HAP and VAP should be employed in hospital settings caring for patients at risk for these infections. Copyright © 2013 Elsevier España, S.L. All rights reserved.

Characteristics of major volatile organic hazardous air pollutants in the urban air of Kaohsiung city.

PubMed

Huang, Mei-Chuan; Lin, Jim Juimin

2007-10-01

The concentrations and characteristics of volatile organic hazardous air pollutants (HAPs) in the urban city of Kaohsiung from motor vehicles and dense pollutant sources has become a national concern. To continuously monitor volatile organic HAPs, sampling sites were selected near the four air-quality monitoring stations established by Ethe nvironmental Protection Administration of Taiwan ROC, namely Nan-tz, Tso-ying, San-min and Hsiao-kang, from north to south. An on-site automated online monitor of volatile organic compounds (VOCs) was used for continuous monitoring. This study performed two consecutive days of 24-h monitoring of five volatile organic HAPs form August to October 2005 at the four monitoring sites, which cover the northern, central, and southern areas of Kaohsiung city. The average monitored concentration was 2.78-4.84 ppb for benzene, 5.90-9.66 ppb for toluene, 3.62-5.90 ppb for ethylbenzene, 3.73-5.34 ppb for m,p-xylene, 3.38-4.22 ppb for o-xylene, and 4.48-7.00 ppb for styrene. The average monitored concentrations of the major volatile organic HAPs tended to follow the pattern San-min > Nan-tz > Hsiao-kang > Tso-ying. Among all the species monitored in this study, toluene had the highest ambient concentration, followed by styrene, m,p-xylene, ethylbenzene, o-xylene, and benzene. The results showed that the concentration at night was higher than that in the day for toluene at Nan-tz, San-min, Hsiao-kang, and for benzene at Nan-tz and Hsiao-kang.

Surface polyPEGylation of Eu3+ doped luminescent hydroxyapatite nanorods through the combination of ligand exchange and metal free surface initiated atom transfer radical polymerization

NASA Astrophysics Data System (ADS)

Zeng, Guangjian; Liu, Meiying; Heng, Chunning; Huang, Qiang; Mao, Liucheng; Huang, Hongye; Hui, Junfeng; Deng, Fengjie; Zhang, Xiaoyong; Wei, Yen

2017-03-01

The Eu3+ doped luminescent hydroxyapatite (HAp) nanorods with uniform size and morphology can be synthesized by hydrothermal route. However, these HAp nanorods are coated by hydrophobic oleylamine, which makes them difficult to be dispersed in aqueous solution and impede their biomedical applications. In this work, Eu3+ doped luminescent polymers functionalized HAp nanorods were prepared through the combination of ligand exchange reaction and metal free surface initiated atom transfer radical polymerization (ATRP) method. In this procedure, the amino group functionalized HAp nanorods were first prepared by ligand exchange reaction using adenosine monophosphate (AMP) as ligand. Then the Br-containing initiators (HAp-Br) were introduced onto the surface of HAp-AMP nanorods through the amidation reaction. Finally, polymers functionalized HAp nanorods were prepared by metal free ATRP method using poly(ethylene glycol) methacrylate (PEGMA) as monomer and 10-phenylphenothiazine (PTH) as organic photocatalyst. The properties of these obtained HAp nanocomposites (HAP-polyPEGMA nanorods) were characterized by means of transmission electron microscopy, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy and thermogravimetric analysis in detail. The cell imaging of these HAP-polyPEGMA nanorods was examined using laser scanning confocal microscope to evaluate their biomedical applications. We demonstrated for the first time that hydrophobic luminescent HAp nanorods can be functionalized with polyPEGMA through the combination of ligand exchange reaction and metal free surface initiated ATRP. As compared with the traditional ATRP, the metal free ATRP can overcome the toxic and fluorescence quenching effects of metal catalysts such as copper ions. More importantly, the strategy described in this work should also be utilized for fabrications of many other luminescent polymer nanocomposites due to its good monomer adoptability.