Science.gov

Sample records for organizations applied optics

  1. Studies on integrated optics at the State Institute of Applied Optics Scientific Manufacturing Organization

    NASA Astrophysics Data System (ADS)

    Mirumyants, S. O.; Pryakhin, Yu. A.

    1994-02-01

    This paper gives a brief history of how reseach and development in integrated optics has evolved and progressed at the State Institute of Applied Optics Scientific Manufacturing Organization. Systems developed for basic integrated-optics modules in the 0.5-5 micrometer spectral range are presented, and it is shown that they can be used, in particular, to detect laser radiation and to create miniature high-frequency sensors of wavefront normals, of linear displacements, and of rotation angle and rate.

  2. Organic nonlinear optical materials

    NASA Technical Reports Server (NTRS)

    Umegaki, S.

    1987-01-01

    Recently, it became clear that organic compounds with delocalized pi electrons show a great nonlinear optical response. Especially, secondary nonlinear optical constants of more than 2 digits were often seen in the molecular level compared to the existing inorganic crystals such as LiNbO3. The crystallization was continuously tried. Organic nonlinear optical crystals have a new future as materials for use in the applied physics such as photomodulation, optical frequency transformation, opto-bistabilization, and phase conjugation optics. Organic nonlinear optical materials, e.g., urea, O2NC6H4NH2, I, II, are reviewed with 50 references.

  3. Organic Materials For Optical Switching

    NASA Technical Reports Server (NTRS)

    Cardelino, Beatriz H.

    1993-01-01

    Equations predict properties of candidate materials. Report presents results of theoretical study of nonlinear optical properties of organic materials. Such materials used in optical switching devices for computers and telecommunications, replacing electronic switches. Optical switching potentially offers extremely high information throughout in compact hardware.

  4. Applied optics to engineering photonics: a retrospective

    NASA Astrophysics Data System (ADS)

    Tatam, Ralph P.

    2011-12-01

    This paper provides a short overview of the time I spent as a member of the Applied Optics Group at the University of Kent (1985-1989) followed by a review of my research during my time at Cranfield University (1989 to date).

  5. Polarization-sensitive optical coherence tomography applied to intervertebral disk

    NASA Astrophysics Data System (ADS)

    Matcher, Stephen J.; Winlove, Peter; Gangnus, Sergei V.

    2003-07-01

    Polarization-sensitive optical coherence tomography (PSOCT) is a powerful new optical imaging modality that is sensitive to the birefringence properties of tissues. It thus has potential applications in studying the large-scale ordering of collagen fibers within connective tisues and changes related to pathology. As a tissue for study by PSOCT, intervertebral disk respresents an interesting system as the collagen organization is believed to show pronounced variations with depth, on a spatial scale of about 100 μm. We have used a polarization-sensitive optical coherence tomography system to measure the birefringence properties of bovine caudal intervertebral disk and compared this with equine flexor tendon. The result for equine tendon, δ = (3.0 +/- 0.5)x10-3 at 1.3 μm, is in broad agreement with values reported for bovine tendon, while bovine intervertebral disk displays a birefringence of about half this, δ = 1.2 x 10-3 at 1.3 μm. While tendon appears to show a uniform fast-axis over 0.8 mm depth, intervertebral disk shows image contrast at all orientations relative to a linearly polarized input beam, suggesting a variation in fast-axis orientation with depth. These initial results suggest that PSOCT could be a useful tool to study collagen organization within this tissue and its variation with applied load and disease.

  6. Applied physics: Optical trapping for space mirrors.

    PubMed

    McGloin, David

    2014-02-27

    Might it be possible to create mirrors for space telescopes, using nothing but microscopic particles held in place by light? A study that exploits a technique called optical binding provides a step towards this goal.

  7. Dielectric barrier discharges applied for optical spectrometry

    NASA Astrophysics Data System (ADS)

    Brandt, S.; Schütz, A.; Klute, F. D.; Kratzer, J.; Franzke, J.

    2016-09-01

    The present review reflects the importance of dielectric barrier discharges for optical spectrometric detection in analytical chemistry. In contrast to usual discharges with a direct current the electrodes are separated by at least one dielectric barrier. There are two main features of the dielectric barrier discharges: they can serve as dissociation and excitation devices as well as ionization sources, respectively. This article portrays various application fields of dielectric barrier discharges in analytical chemistry used for elemental and molecular detection with optical spectrometry.

  8. Optical high-performance computing: introduction to the JOSA A and Applied Optics feature.

    PubMed

    Caulfield, H John; Dolev, Shlomi; Green, William M J

    2009-08-01

    The feature issues in both Applied Optics and the Journal of the Optical Society of America A focus on topics of immediate relevance to the community working in the area of optical high-performance computing.

  9. Applying the ABCs in provider organizations.

    PubMed

    Pandey, Seema

    2012-11-01

    Activity-based costing (ABC) is an accounting technique designed to guard against potentially serious financial problems that can arise when an organization's accounting costs deviate significantly from its actual costs. In general, an ABC analysis considers two factors: a cost element (a directly measurable unit of cost, such as the cost of an item) and a cost driver (a directly measurable feature of the service, such as how often the item is used). ABC is best applied to specific service areas, orservice packages, for which consumption of resources is largely predictable and atomic units of services can be accurately identified. PMID:23173369

  10. Applying the ABCs in provider organizations.

    PubMed

    Pandey, Seema

    2012-11-01

    Activity-based costing (ABC) is an accounting technique designed to guard against potentially serious financial problems that can arise when an organization's accounting costs deviate significantly from its actual costs. In general, an ABC analysis considers two factors: a cost element (a directly measurable unit of cost, such as the cost of an item) and a cost driver (a directly measurable feature of the service, such as how often the item is used). ABC is best applied to specific service areas, orservice packages, for which consumption of resources is largely predictable and atomic units of services can be accurately identified.

  11. (Optical characterization techniques applied to ceramic oxides)

    SciTech Connect

    Abraham, M.M.

    1990-10-15

    The traveler collaborated with M.J.M. Leask, J.M. Baker, B. Bleaney, and others at the Clarendon Laboratory, Oxford University, Oxford, UK, to Study Tetragonal rare-earth phosphates and vanadates by optical and magnetic spectroscopy. This work is related to similar studies that have been performed at ORNL by the Synthesis and Properties of Novel Materials Group in the Solid State Division.

  12. Optical correlator techniques applied to robotic vision

    NASA Technical Reports Server (NTRS)

    Hine, Butler P., III; Reid, Max B.; Downie, John D.

    1991-01-01

    Vision processing is one of the most computationally intensive tasks required of an autonomous robot. The data flow from a single typical imaging sensor is roughly 60 Mbits/sec, which can easily overload current on-board processors. Optical correlator-based processing can be used to perform many of the functions required of a general robotic vision system, such as object recognition, tracking, and orientation determination, and can perform these functions fast enough to keep pace with the incoming sensor data. We describe a hybrid digital electronic/analog optical robotic vision processing system developed at Ames Research Center to test concepts and algorithms for autonomous construction, inspection, and maintenance of space-based habitats. We discuss the system architecture design and implementation, its performance characteristics, and our future plans. In particular, we compare the performance of the system to a more conventional all digital electronic system developed concurrently. The hybrid system consistently outperforms the digital electronic one in both speed and robustness.

  13. Diffractometry and scatterometry at the Institute of Applied Optics, Warsaw

    NASA Astrophysics Data System (ADS)

    Daszkiewicz, Marek

    1994-10-01

    The last 25 years of activity of the Wasaw Institute of Applied Optics (Instytut Optyki Stosowanej - IOS) (formerly Central Optical Laboratory) in diffractometry and scatterometry is presented. The methods of investigations and different types of apparatuses (especially diffractometers) developed in IOS are described. Examples of practical applications of diffractometry and scatterometry are shown.

  14. Teaching applied optics at the Univ. of Minho

    NASA Astrophysics Data System (ADS)

    Costa, Manuel F. M.

    1995-10-01

    In this communication we make a brief presentation of the branch of Applied Optics of the University of Mihno's undergraduate course of Applied Physics. The course of Applied Physics began in the year 1988/89. Previously we had just a course devoted to the formation of future physics and chemistry teachers at high school level. The Applied Physics course specialized in Optics appeared due to the growth of the physics department and due to request from the industry. The Applied Physics course has two specialization's on the field of applied optics: Optometry; and Optics and Lasers. The topics covered in the two first years of the course ar common to the two branches. On the second semester of the third year the students must choose between either one. The number of students on the Optometry branch was usually almost four times the number of Applied Optics and Lasers students. Nevertheless this tendency is rapidly changing. A short analysis of the result obtained will be presented focusing on last couple of years' advances. Presented will also be the results of an inquest made on students's opinions about the quality of the course, and their own performance and expectations.

  15. Trends in optical coherence tomography applied to medical imaging

    NASA Astrophysics Data System (ADS)

    Podoleanu, Adrian G.

    2014-01-01

    The number of publications on optical coherence tomography (OCT) continues to double every three years. Traditionally applied to imaging the eye, OCT is now being extended to fields outside ophthalmology and optometry. Widening its applicability, progress in the core engine of the technology, and impact on development of novel optical sources, make OCT a very active and rapidly evolving field. Trends in the developments of different specific devices, such as optical sources, optical configurations and signal processing will be presented. Encompassing studies on both the configurations as well as on signal processing themes, current research in Kent looks at combining spectral domain with time domain imaging for long axial range and simultaneous imaging at several depths. Results of the collaborative work of the Applied Optics Group in Kent with organisers of this conference will be presented, with reference to 3D monitoring of abfraction.

  16. Optical trapping inside living organisms

    NASA Astrophysics Data System (ADS)

    Hansen, Poul M.; Oddershede, Lene B.

    2005-08-01

    We use optical tweezers to investigate processes happening inside ving cells. In a previous study, we trapped naturally occurring lipid granules inside living yeast cells, and used them to probe the viscoelastic properties of the cytoplasm. However, we prefer to use probes which can be specifically attached to various organelles within the living cells in order to optically quantify the forces acting on these organelles. Therefore, we have chosen to use nanometer sized gold beads as probes. These gold beads can be conjugated and attached chemically to the organelles of interest. Only Rayleigh metallic particles can be optically trapped and for these it is the case that the larger the beads, the larger the forces which can be exerted and thus measured using optical tweezers. The gold nanoparticles are injected into the cytoplasm using micropipettes. The very rigid cell wall of the S. pombe yeast cells poses a serious obstacle to this injection. In order to be able to punch a hole in the cell, first, the cells have to be turned into protoplasts, where only a lipid bilayer separates the cytoplasm from the surrounding media. We show how to perform micropipette delivery into the protoplasts and also how the protoplasts can be ablated using the trapping laserlight. Finally, we demonstrate that we can transform the protoplasts back to normal yeast cells.

  17. Applying Knowledge Management to an Organization's Transformation

    NASA Technical Reports Server (NTRS)

    Potter, Shannon; Gill, Tracy; Fritsche, Ralph

    2008-01-01

    Although workers in the information age have more information at their fingertips than ever before, the ability to effectively capture and reuse actual knowledge is still a surmounting challenge for many organizations. As high tech organizations transform from providing complex products and services in an established domain to providing them in new domains, knowledge remains an increasingly valuable commodity. This paper explores the supply and demand elements of the "knowledge market" within the International Space Station and Spacecraft Processing Directorate (ISSSPD) of NASA's Kennedy Space Center (KSC). It examines how knowledge supply and knowledge demand determine the success of an organization's knowledge management (KM) activities, and how the elements of a KM infrastructure (tools, culture, and training), can be used to create and sustain knowledge supply and demand

  18. Applied study of optical interconnection link in computer cluster

    NASA Astrophysics Data System (ADS)

    Zhou, Ge; Tian, Jindong; Zhang, Nan; Jing, Wencai; Li, Haifeng

    2000-10-01

    In this paper, some study results to apply fiber link to a computer cluster are presented. The research is based on a ring network topology for a cluster system, which is connected by gigabit/s virtual parallel optical fiber link (VPOFLink) and its driver is for Linux Operating System, the transmission protocol of VPOFLink is compliant with Ethernet standard. We have studied the effect of different types of motherboard on transmission rate of the VPOFLink, and have analyzed the influence of optical interconnection network topology and computer networks protocol on the performance of this optical interconnection computer cluster. The round-trip transmission bandwidth of the VPOFLink have been tested, and the factors that limit transmission bandwidth, such as modes of forwarding data packets in the optical interconnection ring networks, and the size of the link buffer etc., are investigated.

  19. Electro-optic properties of organic nanotubes.

    PubMed

    Stoylov, Stoyl P; Stoilova-McPhie, Svetla

    2011-08-10

    In this review article the theoretical and experimental possibilities of applying EO-methods for estimation of the physico-chemical properties of the organic nanotubes (ONTs) are studied. The ONTs are highly organized nanostructures of strongly elongated, anysometric, and hollow cylinders with a size range of 1 nm to 10,000 nm, e.g. in aqueous solutions they could behave as colloid (disperse) particles. They have high interaction ability due to their extremely large curved, rolled-up external surfaces (bilayers of membrane walls) and unique properties because of their specific electric charge distribution and dynamics that make possible the functionalization of their surfaces. Thus they could template guestsubstances such as membrane proteins and protein complexes on the exterior surfaces and in the membrane. We performed our investigations for the case of ONT aqueous colloid suspension. Following our earlier proposition of the general expression for the electro-optic (EO) effect we derived equations for the evaluation of the electric properties of ONT particles such as mechanism of electric polarization and identification of their most important electric Dipole Moments (DM), permanent (pDM) and induced (iDMs). Further we recommend ways for the calculation of their magnitude and direction. Also we evaluated some geometrical properties such as length of the ONT particles and their polydispersity. The knowledge that we provided about the ONT properties may enable us to elucidate and predict their biological activity. Templating biological active ligands (such as membrane proteins and protein complexes) on the inner and outer surfaces as well as in the surface membrane creates their potential usefulness as carrier and deliverer of biopharmaceuticals in bio-nanodevices. The theoretical equations were compared with the experimental data for ONTs such as (lipid) LNT, Tobacco Mosaic Virus (TMV) and microtubules (MT). Comparison of EO methods with other methods used till

  20. Electro-optic properties of organic nanotubes.

    PubMed

    Stoylov, Stoyl P; Stoilova-McPhie, Svetla

    2011-08-10

    In this review article the theoretical and experimental possibilities of applying EO-methods for estimation of the physico-chemical properties of the organic nanotubes (ONTs) are studied. The ONTs are highly organized nanostructures of strongly elongated, anysometric, and hollow cylinders with a size range of 1 nm to 10,000 nm, e.g. in aqueous solutions they could behave as colloid (disperse) particles. They have high interaction ability due to their extremely large curved, rolled-up external surfaces (bilayers of membrane walls) and unique properties because of their specific electric charge distribution and dynamics that make possible the functionalization of their surfaces. Thus they could template guestsubstances such as membrane proteins and protein complexes on the exterior surfaces and in the membrane. We performed our investigations for the case of ONT aqueous colloid suspension. Following our earlier proposition of the general expression for the electro-optic (EO) effect we derived equations for the evaluation of the electric properties of ONT particles such as mechanism of electric polarization and identification of their most important electric Dipole Moments (DM), permanent (pDM) and induced (iDMs). Further we recommend ways for the calculation of their magnitude and direction. Also we evaluated some geometrical properties such as length of the ONT particles and their polydispersity. The knowledge that we provided about the ONT properties may enable us to elucidate and predict their biological activity. Templating biological active ligands (such as membrane proteins and protein complexes) on the inner and outer surfaces as well as in the surface membrane creates their potential usefulness as carrier and deliverer of biopharmaceuticals in bio-nanodevices. The theoretical equations were compared with the experimental data for ONTs such as (lipid) LNT, Tobacco Mosaic Virus (TMV) and microtubules (MT). Comparison of EO methods with other methods used till

  1. Nonlinear optical studies of organic monolayers

    SciTech Connect

    Shen, Y.R.

    1988-02-01

    Second-order nonlinear optical effects are forbidden in a medium with inversion symmetry, but are necessarily allowed at a surface where the inversion summary is broken. They are often sufficiently strong so that a submonolayer perturbation of the surface can be readily detected. They can therefore be used as effective tools to study monolayers adsorbed at various interfaces. We discuss here a number of recent experiments in which optical second harmonic generation (SHG) and sum-frequency generation (SFG) are employed to probe and characterize organic monolayers. 15 refs., 5 figs.

  2. Highly Non-Linear Optical (NLO) organic crystals and films. Electrooptical organic materials

    NASA Technical Reports Server (NTRS)

    Mcmanus, Samuel P.; Rosenberger, Franz; Matthews, John

    1987-01-01

    Devices employing nonlinear optics (NLO) hold great promise for important applications in integrated optics, optical information processing and telecommunications. Properly designed organics possess outstanding optical and electrooptical properties which will substantially advance many technologies including electrooptical switching, optical amplification for communications, and parallel processing for hybrid optical computers. A brief comparison of organic and inorganic materials is given.

  3. Understanding and applying open-path optical sensing data

    NASA Astrophysics Data System (ADS)

    Virag, Peter; Kricks, Robert J.

    1999-02-01

    During the last 10 years, open-path air monitors have evolved to yield reliable and effective measurements of single and multiple compounds on a real-time basis. To many individuals within the optical remote sensing community, the attributes of open-path and its the potential uses seem unlimited. Then why has the market has been stagnant for the last few years? The reason may center on how open-path information is applied and how well the end user understands that information. We constantly try to compare open-path data to risk/health or safety levels that are based for use at a single point and for a specific averaging period often far longer than a typical open-path data point. Often this approach is perceived as putting a square peg in a round hole. This perception may be well founded, as open-path data at times may need to go through extensive data manipulation and assumptions before it can be applied. This paper will review pervious open-path monitoring programs and their success in applying the data collected. We will also look at how open-path data is being currently used, some previous pitfalls in data use, alternate methods of data interpretation, and how open-path data can be best practically applied to fit current needs.

  4. Optical interconnects: the Parallel Optical Link Organization (POLO) approach

    NASA Astrophysics Data System (ADS)

    Ishak, Waguih S.; Hahn, Kenneth H.; Booth, Bruce L.; Mueller, Ervin H.; Levi, Anthony F. J.; Craig, Richard R.

    1995-04-01

    The Parallel Optical Link Organization (POLO) is an industry consortium of Hewlett-Packard, Du Pont, AMP, University of Southern California, and SDL, supported by ARPA and will operate between August 1994 and August 1997. The POLO Consortium was formed to leverage the individual strengths of its members to develop low-cost, high-performance optical interconnect modules for applications in workstation clusters, high-speed switching systems, and multimedia. The goal of the program is to demonstrate the manufacturability of affordable optoelectronic transceiver modules and to provide application platforms that show a clear advantage over copper-wire interconnections. The technical objective of the program is to provide a 10 - 20 Gb/s parallel channel optical interconnect module with a projected manufacturing cost of about $10 per channel. In addition, the POLO Consortium provides a complete solution to the end user, including a programmable host interface module and software interface. The POLO Consortium has formed a User Group consisting of seven world-leading computer, telecommunication, and optoelectronic subsystem manufacturers. Regular meetings with the User Group are planned and at the first meeting, a full set of POLO Module specifications have been discussed and generated. The POLO Consortium will provide the User Group members with hardware for evaluation and feedback.

  5. Influencing organizations to promote health: applying stakeholder theory.

    PubMed

    Kok, Gerjo; Gurabardhi, Zamira; Gottlieb, Nell H; Zijlstra, Fred R H

    2015-04-01

    Stakeholder theory may help health promoters to make changes at the organizational and policy level to promote health. A stakeholder is any individual, group, or organization that can influence an organization. The organization that is the focus for influence attempts is called the focal organization. The more salient a stakeholder is and the more central in the network, the stronger the influence. As stakeholders, health promoters may use communicative, compromise, deinstitutionalization, or coercive methods through an ally or a coalition. A hypothetical case study, involving adolescent use of harmful legal products, illustrates the process of applying stakeholder theory to strategic decision making.

  6. Influencing organizations to promote health: applying stakeholder theory.

    PubMed

    Kok, Gerjo; Gurabardhi, Zamira; Gottlieb, Nell H; Zijlstra, Fred R H

    2015-04-01

    Stakeholder theory may help health promoters to make changes at the organizational and policy level to promote health. A stakeholder is any individual, group, or organization that can influence an organization. The organization that is the focus for influence attempts is called the focal organization. The more salient a stakeholder is and the more central in the network, the stronger the influence. As stakeholders, health promoters may use communicative, compromise, deinstitutionalization, or coercive methods through an ally or a coalition. A hypothetical case study, involving adolescent use of harmful legal products, illustrates the process of applying stakeholder theory to strategic decision making. PMID:25829111

  7. Optical Trapping Techniques Applied to the Study of Cell Membranes

    NASA Astrophysics Data System (ADS)

    Morss, Andrew J.

    Optical tweezers allow for manipulating micron-sized objects using pN level optical forces. In this work, we use an optical trapping setup to aid in three separate experiments, all related to the physics of the cellular membrane. In the first experiment, in conjunction with Brian Henslee, we use optical tweezers to allow for precise positioning and control of cells in suspension to evaluate the cell size dependence of electroporation. Theory predicts that all cells porate at a transmembrane potential VTMof roughly 1 V. The Schwann equation predicts that the transmembrane potential depends linearly on the cell radius r, thus predicting that cells should porate at threshold electric fields that go as 1/r. The threshold field required to induce poration is determined by applying a low voltage pulse to the cell and then applying additional pulses of greater and greater magnitude, checking for poration at each step using propidium iodide dye. We find that, contrary to expectations, cells do not porate at a constant value of the transmembrane potential but at a constant value of the electric field which we find to be 692 V/cm for K562 cells. Delivering precise dosages of nanoparticles into cells is of importance for assessing toxicity of nanoparticles or for genetic research. In the second experiment, we conduct nano-electroporation—a novel method of applying precise doses of transfection agents to cells—by using optical tweezers in conjunction with a confocal microscope to manipulate cells into contact with 100 nm wide nanochannels. This work was done in collaboration with Pouyan Boukany of Dr. Lee's group. The small cross sectional area of these nano channels means that the electric field within them is extremely large, 60 MV/m, which allows them to electrophoretically drive transfection agents into the cell. We find that nano electroporation results in excellent dose control (to within 10% in our experiments) compared to bulk electroporation. We also find that

  8. Optical design of organic light emitting diodes

    NASA Astrophysics Data System (ADS)

    Wang, Z. B.; Helander, M. G.; Xu, X. F.; Puzzo, D. P.; Qiu, J.; Greiner, M. T.; Lu, Z. H.

    2011-03-01

    Out-coupling of light from organic light emitting diodes (OLEDs) is a significant challenge for the application of OLEDs in solid state lighting. Most of the light is trapped in the stratified thin film structure and the glass substrate. In this study, an optical model is developed to simulate the optical electrical field for OLEDs with a stratified structure based on the dipole source term and transfer matrix approach. The exciton distribution is also considered in the proposed model. OLEDs with weak microcavity are selected to evaluate the model. Calculation of the electroluminescence spectrum, device efficiency as well as the angular dependence is shown to have a good agreement with the experimental data. Moreover, by using the weak microcavity design, an OLED of more than 70% improved efficiency is achieved.

  9. Physics and agriculture: applied optics to plant fertilization and breeding

    NASA Astrophysics Data System (ADS)

    Diomandé, K.; Soro, P. A.; Zoro, G. H.; Krou, V. A.

    2011-08-01

    The economy of Côte d'Ivoire rests on the agriculture. In order to contribute to the development of this agriculture, we have oriented our research field on applied optics to agriculture. Then, our research concerns mainly the Laser Induced chlorophyll fluorescence in plants. A simple laser-induced fluorescence set up has been designed and built at the Laboratory of Crystallography and Molecular Physics (LaCPM) at the University of Cocody (Abidjan, COTE D'IVOIRE). With this home set up we first have studied the fluorescence spectra of the "chlorophyll" to characterize the potassium deficiency in oil palm (Elaeis guineensis Jacq,). However, we found that the results differed for samples along terraced plots. The study of this phenomenon called "border effect", has enabled us to realize that sampling should be done after two rows of safety in each plot. We also applied the Laser Induced chlorophyll fluorescence technique to improve the plant breeding. For this, we have characterized the rubber tree seedlings in nurseries. And so we have highlighted those sensible to drought and resistant ones.

  10. An Application of the Programmatic Organization Model to Applied Research.

    ERIC Educational Resources Information Center

    Haring, Norris G.; Krug, David A.

    Presented is a programatic organization model which is applied to research needs in special education. Major advantages of the model are given to be that of providing for several research activities which focus on one common problem, reducing the duplication of research effort, providing greater efficiency in use of research personnel and…

  11. How Do Organic Chemistry Students Understand and Apply Hydrogen Bonding?

    ERIC Educational Resources Information Center

    Henderleiter, J.; Smart, R.; Anderson, J.; Elian, O.

    2001-01-01

    Examines how students completing a two-semester organic sequence understand, explain, and apply hydrogen bonding to determine the physical attributes of molecules. Suggests that some students completing what is typically their second year of college-level chemistry still possess misconceptions about hydrogen bonds. (Contains 21 references.) (ASK)

  12. Applying the balanced scorecard in healthcare provider organizations.

    PubMed

    Inamdar, Noorein; Kaplan, Robert S; Bower, Marvin

    2002-01-01

    Several innovative healthcare executives have recently introduced a new business strategy implementation tool: the Balanced Scorecard. The scorecard's measurement and management system provides the following potential benefits to healthcare organizations: It aligns the organization around a more market-oriented, customer-focused strategy It facilitates, monitors, and assesses the implementation of the strategy It provides a communication and collaboration mechanism It assigns accountability for performance at all levels of the organization It provides continual feedback on the strategy and promotes adjustments to marketplace and regulatory changes. We surveyed executives in nine provider organizations that were implementing the Balanced Scorecard. We asked about the following issues relating to its implementation and effect: 1. The role of the Balanced Scorecard in relation to a well-defined vision, mission, and strategy 2. The motivation for adopting the Balanced Scorecard 3. The difference between the Balanced Scorecard and other measurement systems 4. The process followed to develop and implement the Balanced Scorecard 5. The challenges and barriers during the development and implementation process 6. The benefits gained by the organization from adoption and use. The executives reported that the Balanced Scorecard strategy implementation and performance management tool could be successfully applied in the healthcare sector, enabling organizations to improve their competitive market positioning, financial results, and customer satisfaction. This article concludes with guidelines for other healthcare provider organizations to capture the benefits of the Balanced Scorecard performance management system.

  13. Multifunctional organic thin films and their electronic/optical properties

    NASA Astrophysics Data System (ADS)

    Shao, Yan

    The concept of multifunctional organic thin films and their electronic/optical properties has been applied to organic functional device design, fabrication, and characterization. The organic devices involve organic light-emitting diodes (OLEDs) and organic photovoltaic devices (OPV) in this dissertation. In the research of graded junction structure of OLEDs, two kinds of naturally-formed graded junction (NFGJ) structures, sharp and shallow graded junctions, can be formed using single thermal evaporation boat loaded with uniformly mixed charge transport and light-emitting materials. OLEDs with NFGJ have been demonstrated in Chapter 3; the performance is comparable to the heterojunction OLEDs, but with better device lifetime. A novel method to prepare highly uniform mixed organic solid solutions through a high temperature and high-pressure fusion process has been demonstrated in Chapter 4. A series of fused organic solid solution (FOSS) compounds with NPD doped with different organic emitting dopants were prepared and DSC technique was utilized to determine the thermal characteristics. For the first time, the schematic phase diagram for this binary system has been obtained. High performance OLEDs of single color and white emission were fabricated and the device properties were characterized. In Chapter 5, an efficient photovoltaic heterojunction of tetracene and fullerene has been investigated and high performance organic solar cells have been demonstrated by thermal deposition and successive heat treatment. The preliminary conclusion for this enhancement is discussed and supported by atomic force microscopy images, absorption spectra and x-ray diffraction analysis. Additionally, an effective organic photovoltaic heterojunction based on the typical triplet material PtOEP was demonstrated. It is believed that introducing appropriate organic materials with long exciton lifetime is a very promising way to improve photovoltaic performance.

  14. Optical band gaps of organic semiconductor materials

    NASA Astrophysics Data System (ADS)

    Costa, José C. S.; Taveira, Ricardo J. S.; Lima, Carlos F. R. A. C.; Mendes, Adélio; Santos, Luís M. N. B. F.

    2016-08-01

    UV-Vis can be used as an easy and forthright technique to accurately estimate the band gap energy of organic π-conjugated materials, widely used as thin films/composites in organic and hybrid electronic devices such as OLEDs, OPVs and OFETs. The electronic and optical properties, including HOMO-LUMO energy gaps of π-conjugated systems were evaluated by UV-Vis spectroscopy in CHCl3 solution for a large number of relevant π-conjugated systems: tris-8-hydroxyquinolinatos (Alq3, Gaq3, Inq3, Al(qNO2)3, Al(qCl)3, Al(qBr)3, In(qNO2)3, In(qCl)3 and In(qBr)3); triphenylamine derivatives (DDP, p-TTP, TPB, TPD, TDAB, m-MTDAB, NPB, α-NPD); oligoacenes (naphthalene, anthracene, tetracene and rubrene); oligothiophenes (α-2T, β-2T, α-3T, β-3T, α-4T and α-5T). Additionally, some electronic properties were also explored by quantum chemical calculations. The experimental UV-Vis data are in accordance with the DFT predictions and indicate that the band gap energies of the OSCs dissolved in CHCl3 solution are consistent with the values presented for thin films.

  15. Optical fiber smart structures applied to secure containers

    SciTech Connect

    Sliva, P.; Gordon, N.R.; Stahl, K.A.; Simmon, K.L.; Anheier, N.C.

    1994-07-01

    A prototype secure container was prepared that uses continually monitored optical fiber as the smart structure. A small ({approx}7.6 cm {times} 10.2 cm {times} 12.7 cm), matchbox-shaped container consisting of an inner drawer within an outer shell was fabricated from polymer resin. The optical fiber was sandwiched between additional non-optical, strength-promoting fibers and embedded into the polymer. The additional non-optical fiber provides strength to the container, protects the optical fiber from damage, hides the fiber and acts as a decoy. The optical fiber was wound with a winding density such that a high probability of fiber damage would be expected if the container was penetrated.

  16. Tactile-optical 3D sensor applying image processing

    NASA Astrophysics Data System (ADS)

    Neuschaefer-Rube, Ulrich; Wissmann, Mark

    2009-01-01

    The tactile-optical probe (so-called fiber probe) is a well-known probe in micro-coordinate metrology. It consists of an optical fiber with a probing element at its end. This probing element is adjusted in the imaging plane of the optical system of an optical coordinate measuring machine (CMM). It can be illuminated through the fiber by a LED. The position of the probe is directly detected by image processing algorithms available in every modern optical CMM and not by deflections at the fixation of the probing shaft. Therefore, the probing shaft can be very thin and flexible. This facilitates the measurement with very small probing forces and the realization of very small probing elements (diameter: down to 10 μm). A limitation of this method is that at present the probe does not have full 3D measurement capability. At the Physikalisch-Technische Bundesanstalt (PTB), several arrangements and measurement principles for a full 3D tactile-optical probe have been implemented and tested successfully in cooperation with Werth-Messtechnik, Giessen, Germany. This contribution provides an overview of the results of these activities.

  17. Applying Organ Clearance Concepts in a Clinical Setting

    PubMed Central

    2008-01-01

    Objective To teach doctor of pharmacy (PharmD) students how to apply organ clearance concepts in a clinical setting in order to optimize dose management, select the right drug product, and promote better patient-centered care practices. Design A student-focused 5-hour topic entitled "Organ Clearance Concepts: Modeling and Clinical Applications" was developed and delivered to second-year PharmD students. Active-learning techniques, such as reading assignments and thought-provoking questions, and collaborative learning techniques, such as small groups, were used. Student learning was assessed using application cards and a minute paper. Assessment Overall student responses to topic presentation were overwhelmingly positive. The teaching strategies here discussed allowed students to play an active role in their own learning process and provided the necessary connection to keep them motivated, as mentioned in the application cards and minute paper assessments. Students scored an average of 88% on the examination given at the end of the course. Conclusion By incorporating active-learning and collaborative-learning techniques in presenting material on organ clearance concept, students gained a more thorough knowledge of dose management and drug-drug interactions than if the concepts had been presented using a traditional lecture format. This knowledge will help students in solving critical patient situations in a real-world context. PMID:19214275

  18. Optical design of low glare luminaire applied for tunnel light

    NASA Astrophysics Data System (ADS)

    Tsai, M. S.; Lee, X. H.; Lo, Y. C.; Sun, C. C.

    2014-09-01

    In this study, a low glare and high-efficient tunnel lighting design which consists of a cluster light-emitting diode and a free-form lens is presented. Most of the energy emitted from the proposed luminaire is transmitted onto the surface of the road in front of drivers, and the probability that the energy is emitted directly into drivers' eyes is low. Compared with traditional fluorescent lamps, the proposed luminaire, of which the optical utilization factor, optical efficiency, and uniformity are, respectively, 44%, 92.5%, and 0.72, performs favorably in traffic safety, energy saving, and glare reduction.

  19. Geometric and Applied Optics, Science (Experimental): 5318.04.

    ERIC Educational Resources Information Center

    Sanderson, Robert C.

    This unit of instruction presents a laboratory-oriented course which relates the sources and behaviors of light to man's control and uses of light. Successful completion of Algebra I and Plane Geometry is strongly recommended as indicators of success. The course is recommended if the student plans further studies in science, optical technology, or…

  20. Applying total quality management concepts to public health organizations.

    PubMed Central

    Kaluzny, A D; McLaughlin, C P; Simpson, K

    1992-01-01

    Total quality management (TQM) is a participative, systematic approach to planning and implementing a continuous organizational improvement process. Its approach is focused on satisfying customers' expectations, identifying problems, building commitment, and promoting open decision-making among workers. TQM applies analytical tools, such as flow and statistical charts and check sheets, to gather data about activities within an organization. TQM uses process techniques, such as nominal groups, brainstorming, and consensus forming to facilitate communication and decision making. TQM applications in the public sector and particularly in public health agencies have been limited. The process of integrating TQM into public health agencies complements and enhances the Model Standards Program and assessment methodologies, such as the Assessment Protocol for Excellence in Public Health (APEX-PH), which are mechanisms for establishing strategic directions for public health. The authors examine the potential for using TQM as a method to achieve and exceed standards quickly and efficiently. They discuss the relationship of performance standards and assessment methodologies with TQM and provide guidelines for achieving the full potential of TQM in public health organizations. The guidelines include redefining the role of management, defining a common corporate culture, refining the role of citizen oversight functions, and setting realistic estimates of the time needed to complete a task or project. PMID:1594734

  1. Applying fiber optical methods for toxicological testing in vitro

    NASA Astrophysics Data System (ADS)

    Maerz, Holger K.; Buchholz, Rainer; Emmrich, Frank; Fink, Frank; Geddes, Clive L.; Pfeifer, Lutz; Raabe, Ferdinand; Scheper, Thomas-Helmut; Ulrich, Elizabeth; Marx, Uwe

    1999-04-01

    The new medical developments, e.g. immune therapy, patient oriented chemotherapy or even gene therapy, create a questionable doubt to the further requirement of animal test. Instead the call for humanitarian reproductive in vitro models becomes increasingly louder. Pharmaceutical usage of in vitro has a long proven history. In cancer research and therapy, the effect of chemostatica in vitro in the so-called oncobiogram is being tested; but the assays do not always correlate with in vivo-like drug resistance and sensitivity. We developed a drug test system in vitro, feasible for therapeutic drug monitoring by the combination of tissue cultivation in hollow fiber bioreactors and fiber optic sensors for monitoring the pharmaceutical effect. Using two fiber optic sensors - an optical oxygen sensor and a metabolism detecting Laserfluoroscope, we were able to successfully monitor the biological status of tissue culture and the drug or toxic effects of in vitro pharmaceutical testing. Furthermore, we developed and patented a system for monitoring the effect of minor toxic compounds which can induce Sick Building Syndrome.

  2. Validation and qualification of surface-applied fibre optic strain sensors using application-independent optical techniques

    NASA Astrophysics Data System (ADS)

    Schukar, Vivien G.; Kadoke, Daniel; Kusche, Nadine; Münzenberger, Sven; Gründer, Klaus-Peter; Habel, Wolfgang R.

    2012-08-01

    Surface-applied fibre optic strain sensors were investigated using a unique validation facility equipped with application-independent optical reference systems. First, different adhesives for the sensor's application were analysed regarding their material properties. Measurements resulting from conventional measurement techniques, such as thermo-mechanical analysis and dynamic mechanical analysis, were compared with measurements resulting from digital image correlation, which has the advantage of being a non-contact technique. Second, fibre optic strain sensors were applied to test specimens with the selected adhesives. Their strain-transfer mechanism was analysed in comparison with conventional strain gauges. Relative movements between the applied sensor and the test specimen were visualized easily using optical reference methods, digital image correlation and electronic speckle pattern interferometry. Conventional strain gauges showed limited opportunities for an objective strain-transfer analysis because they are also affected by application conditions.

  3. Influencing Organizations to Promote Health: Applying Stakeholder Theory

    ERIC Educational Resources Information Center

    Kok, Gerjo; Gurabardhi, Zamira; Gottlieb, Nell H.; Zijlstra, Fred R. H.

    2015-01-01

    Stakeholder theory may help health promoters to make changes at the organizational and policy level to promote health. A stakeholder is any individual, group, or organization that can influence an organization. The organization that is the focus for influence attempts is called the focal organization. The more salient a stakeholder is and the more…

  4. Apply lightweight recognition algorithms in optical music recognition

    NASA Astrophysics Data System (ADS)

    Pham, Viet-Khoi; Nguyen, Hai-Dang; Nguyen-Khac, Tung-Anh; Tran, Minh-Triet

    2015-02-01

    The problems of digitalization and transformation of musical scores into machine-readable format are necessary to be solved since they help people to enjoy music, to learn music, to conserve music sheets, and even to assist music composers. However, the results of existing methods still require improvements for higher accuracy. Therefore, the authors propose lightweight algorithms for Optical Music Recognition to help people to recognize and automatically play musical scores. In our proposal, after removing staff lines and extracting symbols, each music symbol is represented as a grid of identical M ∗ N cells, and the features are extracted and classified with multiple lightweight SVM classifiers. Through experiments, the authors find that the size of 10 ∗ 12 cells yields the highest precision value. Experimental results on the dataset consisting of 4929 music symbols taken from 18 modern music sheets in the Synthetic Score Database show that our proposed method is able to classify printed musical scores with accuracy up to 99.56%.

  5. Use of a fiber optic probe for organic species determination

    DOEpatents

    Ekechukwu, Amy A.

    1996-01-01

    A fiber optic probe for remotely detecting the presence and concentration organic species in aqueous solutions. The probe includes a cylindrical housing with an organic species indicator, preferably diaminonaphthyl sulfonic acid adsorbed in a silica gel (DANS-modified gel), contained in the probe's distal end. The probe admits aqueous solutions to the probe interior for mixing within the DANS-modified gel. An optical fiber transmits light through the DANS-modified gel while the indicator reacts with organic species present in the solution, thereby shifting the location of the fluorescent peak. The altered light is reflected to a receiving fiber that carries the light to a spectrophotometer or other analysis device.

  6. 40 CFR 35.4011 - Do the general grant regulations for nonprofit organizations apply to TAGs?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... other nonprofit organizations. Because EPA awards TAGs to nonprofit organizations, 40 CFR part 30... nonprofit organizations apply to TAGs? 35.4011 Section 35.4011 Protection of Environment ENVIRONMENTAL... Assistance General § 35.4011 Do the general grant regulations for nonprofit organizations apply to TAGs?...

  7. APPLIED OPTICS. Overcoming Kerr-induced capacity limit in optical fiber transmission.

    PubMed

    Temprana, E; Myslivets, E; Kuo, B P-P; Liu, L; Ataie, V; Alic, N; Radic, S

    2015-06-26

    Nonlinear optical response of silica imposes a fundamental limit on the information transfer capacity in optical fibers. Communication beyond this limit requires higher signal power and suppression of nonlinear distortions to prevent irreversible information loss. The nonlinear interaction in silica is a deterministic phenomenon that can, in principle, be completely reversed. However, attempts to remove the effects of nonlinear propagation have led to only modest improvements, and the precise physical mechanism preventing nonlinear cancellation remains unknown. We demonstrate that optical carrier stability plays a critical role in canceling Kerr-induced distortions and that nonlinear wave interaction in silica can be substantially reverted if optical carriers possess a sufficient degree of mutual coherence. These measurements indicate that fiber information capacity can be notably increased over previous estimates.

  8. Organic materials with nonlinear optical properties

    DOEpatents

    Stupp, S.I.; Son, S.; Lin, H.C.

    1995-05-02

    The present invention is directed to organic materials that have the ability to double or triple the frequency of light that is directed through the materials. Particularly, the present invention is directed to the compound 4-[4-(2R)-2-cyano-7-(4{prime}-pentyloxy-4-biphenylcarbonyloxy)phenylheptylidenephenylcarbonyloxy]benzaldehyde, which can double the frequency of light that is directed through the compound. The invention is also directed to the compound (12-hydroxy-5,7-dodecadiynyl)-4{prime}-[(4{prime}-pentyloxy-4-biphenyl)carbonyloxy]-4-biphenylcarboxylate, and its polymeric form. The polymeric form can triple the frequency of light directed through it. 4 figs.

  9. Organic materials with nonlinear optical properties

    DOEpatents

    Stupp, Samuel I.; Son, Sehwan; Lin, Hong-Cheu

    1995-01-01

    The present invention is directed to organic materials that have the ability to double or triple the frequency of light that is directed through the materials. Particularly, the present invention is directed to the compound 4-[4-(2R)-2-cyano-7-(4'-pentyloxy-4-biphenylcarbonyloxy)phenylheptylidene) phenylcarbonyloxy]benzaldehyde, which can double the frequency of light that is directed through the compound. The invention is also directed to the compound (12-hydroxy-5,7-dodecadiynyl) 4'-[(4'-pentyloxy-4-biphenyl)carbonyloxy]-4-biphenylcarboxylate, and its polymeric form. The polymeric form can triple the frequency of light directed through it.

  10. Strong optical confinement and multimode emission of organic photonic dots

    NASA Astrophysics Data System (ADS)

    Langner, M.; Gehlhaar, R.; Schriever, C.; Fröb, H.; Lyssenko, V. G.; Leo, K.

    2007-10-01

    We report on the optical mode structure of laterally confined organic microcavities. For preparation, an organic semiconductor is evaporated through a mask with square sized holes, resulting in photonic dots with approximately 5μm diameter. Using a microscope setup, we observe a complex mode structure in transmission and photoluminescence. From the mode mapping, we conclude a strong three-dimensional optical confinement. The near and far field spectra are modeled by transfer matrix calculations and a Fourier transform of the internal electric field distribution, respectively.

  11. Implementation of Optical Characterization for Flexible Organic Electronics Applications

    NASA Astrophysics Data System (ADS)

    Laskarakis, A.; Logothetidis, S.

    One of the most rapidly evolving sectors of the modern science and technology is the flexible organic electronic devices (FEDs) that are expected to significantly improve and revolutionize our everyday life. The FED application includes the generation of electricity by renewable sources (by organic photovoltaic cells - OPVs), power storage (thin film batteries), the visualization of information (by organic displays), the working and living environment (ambient lighting, sensors), safety, market (smart labels, radio frequency identification tags - RFID), textiles (smart fabrics with embedded display and sensor capabilities), as well as healthcare (smart sensors for vital sign monitoring), etc. Although there has been important progresses in inorganic-based Si devices, there are numerous advances in the organic (semiconducting, conducting), inorganic, and hybrid (organic-inorganic) materials that exhibit desirable properties and stability, and in the synthesis and preparation methods. The understanding of the organic material properties can lead to the fast progress of the functionality and performance of FEDs. The investigation of the optical properties of these materials can promote the understanding of the optical, electrical, structural properties of organic semiconductors and electrodes and can contribute to the optimization of the synthesis process and the tuning of their structure and morphology. In this chapter, we will describe briefly some of the advances toward the implementation of optical characterization methods, such as Spectroscopic Ellipsometry (SE) from the infrared to the visible and ultraviolet spectral region for the study of materials (flexible polymer substrates, barrier layers, transparent electrodes) to be used for application in the fabrication of FEDs.

  12. Organic non-linear optics and opto-electronics

    NASA Astrophysics Data System (ADS)

    Maldonado, J. L.; Ramos-Ortíz, G.; Rodríguez, M.; Meneses-Nava, M. A.; Barbosa-García, O.; Santillán, R.; Farfán, N.

    2010-12-01

    π-conjugated organic molecules and polymers are of great importance in physics, chemistry, material science and engineering. It is expected that, in the near future, organic materials will find widespread use in many technological applications. In the case of organic opto-electronic systems, the list of devices includes light emitting diodes (OLEDs), photovoltaic cells (OPVs), field-effect transistors (OFET), photorefractive materials for light manipulation, among others. These materials are also used for photonic applications: all-optical switching, modulators, optical correlators, plastic waveguides, all polymeric integrated circuits, solid-state lasers, and for biophotonic applications as in the case of the development of organic labels for multiphoton microscopy and photodynamic therapy. The advances in the developing of organic compounds with better mechanical, electrical, and optical (linear and non-linear) characteristics are of a great importance for this field. Here, we present the research on this area carried out at the Centro de Investigaciones en Óp-tica (CIO), in collaboration with Chemistry Departments of different institutions. This work focuses on the optical characterization of materials through several techniques such as TOF, FWM, TBC, THG Maker Fringes, HRS, Z-scan, and TPEF. Additionally, some applications, such as dynamic holography by using photorefractive polymers, and OPVs cells will be discussed.

  13. Crystal growth of organics for nonlinear optical applications

    NASA Technical Reports Server (NTRS)

    Singh, N. B.; Mazelsky, R.

    1993-01-01

    The crystal growth and characterization of organic and inorganic nonlinear optical materials were extensively studied. For example, inorganic crystals such as thallium arsenic selenide were studied in our laboratory for several years and crystals in sizes over 2.5 cm in diameter are available. Organic crystals are suitable for the ultraviolet and near infrared region, but are relatively less developed than their inorganic counterparts. Very high values of the second harmonic conversion efficiency and the electro-optic coefficient were reported for organic compounds. Single crystals of a binary organic alloy based on m.NA and CNA were grown and higher second harmonic conversion efficiency than the values reported for m.NA were observed.

  14. Experimental scrambling and noise reduction applied to the optical encryption of QR codes.

    PubMed

    Barrera, John Fredy; Vélez, Alejandro; Torroba, Roberto

    2014-08-25

    In this contribution, we implement two techniques to reinforce optical encryption, which we restrict in particular to the QR codes, but could be applied in a general encoding situation. To our knowledge, we present the first experimental-positional optical scrambling merged with an optical encryption procedure. The inclusion of an experimental scrambling technique in an optical encryption protocol, in particular dealing with a QR code "container", adds more protection to the encoding proposal. Additionally, a nonlinear normalization technique is applied to reduce the noise over the recovered images besides increasing the security against attacks. The opto-digital techniques employ an interferometric arrangement and a joint transform correlator encrypting architecture. The experimental results demonstrate the capability of the methods to accomplish the task.

  15. Applying Operant Conditioning Principles to the Management of Organizations.

    ERIC Educational Resources Information Center

    DeVries, David L.; Jablonsky, Stephen F.

    Following Walter Nord (1969), the present article contains a predictive model of individual behavior based on both operant conditioning and management literatures. The behavior of an organizational member is seen as a function of the reinforcement contingencies applied by various groups in his environment and of his cognitive assessment of such…

  16. Novel organic-inorganic hybrid materials for optical interconnects

    NASA Astrophysics Data System (ADS)

    Sato, Tetsuo

    2011-01-01

    Optical materials in the optical printed circuit board are required to overcome soldering process. In detail, the material should not have absorption and shape changes after several tens of seconds heating at around 250°C. For such application field, we have developed a novel organic-inorganic hybrid material having a high thermal stability and low absorption at telecom wavelength. The material is designed to UV and/or Thermal curable resin, and soluble to popular organic solvents. We fabricated a rigid optical waveguides on a SiO2/Si wafers by UV lithography. The size of waveguide was 40 μm in width, 30 μm in height, and 7 cm in length. Optical attenuation of the waveguide measured by the cut back method was 0.1 dB/cm at 850 nm, 0.29 dB/cm at 1310 nm, and 0.45 dB/cm at 1550 nm. These values are good low attenuation for the Near-IR optical communication. The 5% weight loss temperature of the UV cured material was 402°C. The waveguide showed almost no attenuation increase even after 1min heating at 300°C. In addition, the material is having a high refractive index of n=1.60 at 633 nm and a low curing shrinkage of 4.7%. We have demonstrated to fabricate a bulk body sample by UV curing, and obtained high uniformity cured materials with 5 mm-thick and 1 cm-diameter. From these properties, the developed organic-inorganic material is expected to be beneficial for the optical interconnection such as micro lenses and optical packages.

  17. Antireflective coatings applied from metal-organic derived liquid precursors.

    PubMed

    Yoldas, B E; O'Keeffe, T W

    1979-09-15

    Antireflective (AR) coatings, which are produced from organometallic driven solutions containing oxide constituents in a chemically polymerized form, are presented. These solutions leave a film on substrates which, upon heat treatment, converts to a glasslike oxide film having the desired optical thickness and index of refraction. The index can be varied continuously from 1.4 to 2.4; thus the AR coatings can be fine-tuned for different substrates and for specific wavelengths of light. Silicon solar cells AR-coated by this technique showed as much as 49% improvement in efficiency over the uncoated state. The real advantage of the process, however, lies in the fact that it is simple, well-suited for automated mass production of photovoltaic cells, and reduces the cost of coating application from an estimated $0.20 per W-package to about $0.01 per W-package. PMID:20212817

  18. TOPICAL REVIEW: Rational design of organic electro-optic materials

    NASA Astrophysics Data System (ADS)

    Dalton, L. R.

    2003-05-01

    Quantum mechanical calculations are used to optimize the molecular first hyperpolarizability of organic chromophores and statistical mechanical calculations are used to optimize the translation of molecular hyperpolarizability to macroscopic electro-optic activity (to values of greater than 100 pm V-1 at telecommunications wavelengths). Macroscopic material architectures are implemented exploiting new concepts in nanoscale architectural engineering. Multi-chromophore-containing dendrimers and dendronized polymers not only permit optimization of electro-optic activity but also of auxiliary properties including optical loss (both absorption and scattering), thermal and photochemical stability and processability. New reactive ion etching and photolithographic techniques permit the fabrication of three-dimensional optical circuitry and the integration of that circuitry with semiconductor very-large-scale integration electronics and silica fibre optics. Electro-optic devices have been fabricated exploiting stripline, cascaded prism and microresonator device structures. Sub-1 V drive voltages and operational bandwidths of greater than 100 GHz have been demonstrated. Both single-and double-ring microresonators have been fabricated for applications such as active wavelength division multiplexing. Free spectral range values of 1 THz and per channel modulation bandwidths of 15 GHz have been realized permitting single-chip data rates of 500 Gb s-1. Other demonstrated devices include phased array radar, optical gyroscopes, acoustic spectrum analysers, ultrafast analog/digital converters and ultrahigh bandwidth signal generators.

  19. Recent NMR developments applied to organic-inorganic materials.

    PubMed

    Bonhomme, Christian; Gervais, Christel; Laurencin, Danielle

    2014-02-01

    In this contribution, the latest developments in solid state NMR are presented in the field of organic-inorganic (O/I) materials (or hybrid materials). Such materials involve mineral and organic (including polymeric and biological) components, and can exhibit complex O/I interfaces. Hybrids are currently a major topic of research in nanoscience, and solid state NMR is obviously a pertinent spectroscopic tool of investigation. Its versatility allows the detailed description of the structure and texture of such complex materials. The article is divided in two main parts: in the first one, recent NMR methodological/instrumental developments are presented in connection with hybrid materials. In the second part, an exhaustive overview of the major classes of O/I materials and their NMR characterization is presented.

  20. Phenomenological model for charge dynamics and optical response of disordered systems: Application to organic semiconductors

    NASA Astrophysics Data System (ADS)

    Fratini, S.; Ciuchi, S.; Mayou, D.

    2014-06-01

    We provide a phenomenological formula that describes the low-frequency optical absorption of charge carriers in disordered systems with localization. This allows us to extract, from experimental data on the optical conductivity, the relevant microscopic parameters determining the transport properties, such as the carrier localization length and the elastic and inelastic scattering times. This general formula is tested and applied here to organic semiconductors, where dynamical molecular disorder is known to play a key role in the transport properties. The present treatment captures the basic ideas underlying the recently proposed transient localization scenario for charge transport, extending it from the dc mobility to the frequency domain. When applied to existing optical measurements in rubrene field-effect transistors, our analysis provides quantitative evidence for the transient localization phenomenon. Possible applications to other disordered electronic systems are briefly discussed.

  1. Use of a fiber optic probe for organic species determination

    DOEpatents

    Ekechukwu, A.A.

    1996-12-10

    A fiber optic probe is described for remotely detecting the presence and concentration organic species in aqueous solutions. The probe includes a cylindrical housing with an organic species indicator, preferably diaminonaphthyl sulfonic acid adsorbed in a silica gel (DANS-modified gel), contained in the probe`s distal end. The probe admits aqueous solutions to the probe interior for mixing within the DANS-modified gel. An optical fiber transmits light through the DANS-modified gel while the indicator reacts with organic species present in the solution, thereby shifting the location of the fluorescent peak. The altered light is reflected to a receiving fiber that carries the light to a spectrophotometer or other analysis device. 5 figs.

  2. Role of spatial distortions on the quadratic nonlinear optical properties of octupolar organic and metallo-organic molecules

    NASA Astrophysics Data System (ADS)

    Bidault, Sébastien; Brasselet, Sophie; Zyss, Joseph; Maury, Olivier; Le Bozec, Hubert

    2007-01-01

    Following on the recent experimental demonstration of a discrepancy between the nonlinear optical (NLO) behavior of several π-conjugated chromophores and their assumed octupolar symmetry, the authors investigate how geometrical distortions influence the NLO response of multipolar push-pull molecules. Their analytical model is set on a basis of valence-bond and charge-transfer states to estimate the hyperpolarizability of organic and metallo-organic chromophores using the lowest possible number of variables. Since symmetry breakdown changes the definition of the molecular Cartesian framework, tensorial spherical coordinates are implemented. The evolution of the nonlinear molecular anisotropy with possible rotational deviations is then evaluated for two recently studied chromophores. Zero-frequency calculations show that, outside optical resonance, weak geometrical distortions lead to strong anisotropy variations in agreement with experimental data. Their goal is to underscore which molecular engineering strategies should be applied when designing a photoisomerizable nonlinear octupole.

  3. Organic Single-Crystal Light-Emitting Transistor Coupling with Optical Feedback Resonators

    PubMed Central

    Bisri, Satria Zulkarnaen; Sawabe, Kosuke; Imakawa, Masaki; Maruyama, Kenichi; Yamao, Takeshi; Hotta, Shu; Iwasa, Yoshihiro; Takenobu, Taishi

    2012-01-01

    Organic light-emitting transistors (OLETs) are of great research interest because they combine the advantage of the active channel of a transistor that can control the luminescence of an in-situ light-emitting diode in the same device. Here we report a novel single-crystal OLET (SCLET) that is coupled with single crystal optical feedback resonators. The combination of single-crystal waveguides with native Fabry-Perot cavities, formed by parallel crystal edges, drastically lowers the threshold energy for spectral narrowing and non-linear intensity enhancement. We apply this structure to SCLETs and demonstrate the first fabrication of a SCLET with the optical feedback resonators. PMID:23248748

  4. Optical Detection of Organic Chemical Biosignatures at Hydrothermal Vents

    NASA Technical Reports Server (NTRS)

    Conrad, P. G.; Lane, A. L.; Bhartia, R.; Hug, W. H.

    2004-01-01

    We have developed a non-contact, optical life detection instrument that can detect organic chemical biosignatures in a number of different environments, including dry land, shallow aqueous, deep marine or in ice. Hence, the instrument is appropriate as a biosignature survey tool both for Mars exploration or in situ experiments in an ice-covered ocean such as one might wish to explore on Europa. Here, we report the results we obtained on an expedition aboard the Russian oceanographic vessel Akademik Mstislav Keldysh to hydrothermal vent sites in the Pacific Ocean using our life detection instrument MCDUVE, a multichannel, deep ultraviolet excitation fluorescence detector. MCDUVE detected organic material distribution on rocks near the vent, as well as direct detection of organisms, both microbial and microscopic. We also were able to detect organic material issuing directly from vent chimneys, measure the organic signature of the water column as we ascended, and passively observe the emission of light directly from some vents.

  5. Comparative, transcriptome analysis of self-organizing optic tissues

    PubMed Central

    Andrabi, Munazah; Kuraku, Shigehiro; Takata, Nozomu; Sasai, Yoshiki; Love, Nick R.

    2015-01-01

    Embryonic stem (ES) cells have a remarkable capacity to self-organize complex, multi-layered optic cups in vitro via a culture technique called SFEBq. During both SFEBq and in vivo optic cup development, Rax (Rx) expressing neural retina epithelial (NRE) tissues utilize Fgf and Wnt/β-catenin signalling pathways to differentiate into neural retina (NR) and retinal-pigmented epithelial (RPE) tissues, respectively. How these signaling pathways affect gene expression during optic tissue formation has remained largely unknown, especially at the transcriptome scale. Here, we address this question using RNA-Seq. We generated Rx+ optic tissue using SFEBq, exposed these tissues to either Fgf or Wnt/β-catenin stimulation, and assayed their gene expression across multiple time points using RNA-Seq. This comparative dataset will help elucidate how Fgf and Wnt/β-catenin signaling affect gene expression during optic tissue differentiation and will help inform future efforts to optimize in vitro optic tissue culture technology. PMID:26110066

  6. Characterization of Optical Fiber Strength Under Applied Tensile Stress and Bending Stress

    SciTech Connect

    P.E. Klingsporn

    2011-08-01

    Various types of tensile testing and bend radius tests were conducted on silica core/silica cladding optical fiber of different diameters with different protective buffer coatings, fabricated by different fiber manufacturers. The tensile tests were conducted to determine not only the average fiber strengths at failure, but also the distribution in fracture strengths, as well as the influence of buffer coating on fracture strength. The times-to-failure of fiber subjected to constant applied bending stresses of various magnitudes were measured to provide a database from which failure times of 20 years or more, and the corresponding minimum bend radius, could be extrapolated in a statistically meaningful way. The overall study was done to provide an understanding of optical fiber strength in tensile loading and in applied bending stress as related to applications of optical fiber in various potential coizfgurations for weapons and enhanced surveillance campaigns.

  7. Volatile Organic Compound Optical Fiber Sensors: A Review

    PubMed Central

    Elosua, Cesar; Matias, Ignacio R.; Bariain, Candido; Arregui, Francisco J.

    2006-01-01

    Volatile organic compound (VOC) detection is a topic of growing interest with applications in diverse fields, ranging from environmental uses to the food or chemical industries. Optical fiber VOC sensors offering new and interesting properties which overcame some of the inconveniences found on traditional gas sensors appeared over two decades ago. Thanks to its minimum invasive nature and the advantages that optical fiber offers such as light weight, passive nature, low attenuation and the possibility of multiplexing, among others, these sensors are a real alternative to electronic ones in electrically noisy environments where electronic sensors cannot operate correctly. In the present work, a classification of these devices has been made according to the sensing mechanism and taking also into account the sensing materials or the different methods of fabrication. In addition, some solutions already implemented for the detection of VOCs using optical fiber sensors will be described with detail.

  8. Fiber optic micromirror sensor for volatile organic compounds

    SciTech Connect

    Butler, M.A.; Ricco, A.J.; Buss, R. )

    1990-04-01

    With the growing concern over environmental pollution, there is a need for sensors to locate and measure the distribution of a wide range of pollutants. In this paper the authors report a fiber optic sensor, based on a thin film micromirror, which responds to a wide range of volatile organic compounds (VOCs). This generic class of sensor will be useful for monitoring applications where the pollutant has already been identified.

  9. Self-Assembled Organic Nanocrystals with Strong Nonlinear Optical Response.

    PubMed

    Rosenne, Shaked; Grinvald, Eran; Shirman, Elijah; Neeman, Lior; Dutta, Sounak; Bar-Elli, Omri; Ben-Zvi, Regev; Oksenberg, Eitan; Milko, Petr; Kalchenko, Vyacheslav; Weissman, Haim; Oron, Dan; Rybtchinski, Boris

    2015-11-11

    Facile molecular self-assembly affords a new family of organic nanocrystals that, unintuitively, exhibit a significant nonlinear optical response (second harmonic generation, SHG) despite the relatively small molecular dipole moment of the constituent molecules. The nanocrystals are self-assembled in aqueous media from simple monosubstituted perylenediimide (PDI) molecular building blocks. Control over the crystal dimensions can be achieved via modification of the assembly conditions. The combination of a simple fabrication process with the ability to generate soluble SHG nanocrystals with tunable sizes may open new avenues in the area of organic SHG materials.

  10. Optical and THz reflectance investigations of organic solar cells

    NASA Astrophysics Data System (ADS)

    Sporea, Dan; Mihai, Laura; Sporea, Adelina; Galagan, Yulia

    2016-04-01

    Two Organic Photovoltaic devices having a photoactive layer containing Poly[N-9'-heptadecanyl-2,7-carbazole-alt-5,5- (4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (PCDTBT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM, 99%), and the layer sequences - glass/ITO/ZnO/PAL/PEDOT:PSS/Ag/encapsulation were non-destructively investigated by diffuse optical spectral reflectance, THz spectroscopy and THz imaging. The proposed methods proved to be powerful tools to support quality assurance in organic solar cells development, facilitating both the localization of manufacturing defects and the device degradation, as they are combined with "classical" evaluation means.

  11. Highly Non-Linear Optical (NLO) organic crystals

    NASA Technical Reports Server (NTRS)

    Harris, J. Milton

    1987-01-01

    This research project involves the synthesis and characterization of organic materials having powerful nonlinear optical (NLO) properties and the growth of highly ordered crystals and monomolecular films of these materials. Research in four areas is discussed: theoretical design of new materials, characterization of NLO materials, synthesis of new materials and development of coupling procedures for forming layered films, and improvement of the techniques for vapor phase and solution phase growth of high quality organic crystals. Knowledge gained from these experiments will form the basis for experiments in the growth of these crystals.

  12. 13 CFR 120.703 - How does an organization apply to become an Intermediary?

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false How does an organization apply to become an Intermediary? 120.703 Section 120.703 Business Credit and Assistance SMALL BUSINESS ADMINISTRATION BUSINESS LOANS Microloan Program § 120.703 How does an organization apply to become...

  13. Applying Western Organization Development in China: Lessons from a Case of Success

    ERIC Educational Resources Information Center

    Wang, Jia

    2010-01-01

    Purpose: The purpose of this paper is to explore a successful case of a Chinese state-owned enterprise (SOE) as it applied western organization development (OD) approaches. Specifically, this study seeks to answer two questions: How has western organization development and change (OD/C) been applied in one Chinese SOE? and What lessons can be…

  14. The tunable electronic structure and optic absorption properties of phosphorene by a normally applied electric field

    NASA Astrophysics Data System (ADS)

    Yang, Mou; Duan, Hou-Jian; Wang, Rui-Qiang

    2016-10-01

    We studied the electronic structure and optical absorption properties of phosphorene (a monolayer black phosphorus) under a normally applied electric field. The electric field enlarges the energy gap, weakens the effective mass anisotropy, and increases the effective mass component along the armchair direction (x-direction) for both conduction and valence bands but provides little change to the component along the zigzag direction (y-direction). The band edge optical absorption is completely polarized in the x-direction, and decreases when increasing the electric field. If the exciting frequency is beyond the energy gap, the absorption for the y-polarized light becomes nonzero, but the absorption is still highly polarized.

  15. Nondestructive Optical Determination of Fiber Organization in Intact Myocardial Wall

    PubMed Central

    SMITH, REBECCA M.; MATIUKAS, ARVYDAS; ZEMLIN, CHRISTIAN W.; PERTSOV, ARKADY M.

    2010-01-01

    Mapping the myocardial fiber organization is important for assessing the electrical and mechanical properties of normal and diseased hearts. Current methods to determine the fiber organization have several limitations: histological sectioning mechanically distorts the tissue and is labor-intensive, while diffusion tensor imaging has low spatial resolution and requires expensive MRI scanners. Here, we utilized optical clearing, a fluorescent dye, and confocal microscopy to create three-dimensional reconstructions of the myocardial fiber organization of guinea pig and mouse hearts. We have optimized the staining and clearing procedure to allow for the nondestructive imaging of whole hearts with a thickness up to 3.5 mm. Myocardial fibers could clearly be identified at all depths in all preparations. We determined the change of fiber orientation across strips of guinea pig left ventricular wall. Our study confirms the qualitative result that there is a steady counterclockwise fiber rotation across the ventricular wall. Quantitatively, we found a total fiber rotation of 105.7 ± 14.9° (mean ± standard error of the mean); this value lies within the range reported by previous studies. These results show that optical clearing, in combination with a fluorescent dye and confocal microscopy, is a practical and accurate method for determining myocardial fiber organization. PMID:18393296

  16. Applying LED in full-field optical coherence tomography for gastrointestinal endoscopy

    NASA Astrophysics Data System (ADS)

    Yang, Bor-Wen; Wang, Yu-Yen; Juan, Yu-Shan; Hsu, Sheng-Jie

    2015-08-01

    Optical coherence tomography (OCT) has become an important medical imaging technology due to its non-invasiveness and high resolution. Full-field optical coherence tomography (FF-OCT) is a scanning scheme especially suitable for en face imaging as it employs a CMOS/CCD device for parallel pixels processing. FF-OCT can also be applied to high-speed endoscopic imaging. Applying cylindrical scanning and a right-angle prism, we successfully obtained a 360° tomography of the inner wall of an intestinal cavity through an FF-OCT system with an LED source. The 10-μm scale resolution enables the early detection of gastrointestinal lesions, which can increase detection rates for esophageal, stomach, or vaginal cancer. All devices used in this system can be integrated by MOEMS technology to contribute to the studies of gastrointestinal medicine and advanced endoscopy technology.

  17. A novel organic nonlinear optical crystal: Creatininium succinate

    NASA Astrophysics Data System (ADS)

    Thirumurugan, R.; Anitha, K.

    2015-06-01

    A novel organic material complex of creatininium succinate (CS) has been synthesized and single crystals were grown by the reaction of creatinine and succinic acid from aqueous solution by employing the technique of slow evaporation at room temperature. The structure of the grown crystal has been elucidated using single crystal X-ray diffraction analysis and the structure was refined by least-squares method to R = 0.027 for 1840 reflections. FT-IR spectral investigation has been carried out to identify the various functional groups in the title compound. UV-Vis transmission was carried out which shows the crystal has a good optical transmittance in the visible region with lower cutoff wavelength around 220 nm. Nonlinear optical property of the crystal was confirmed by Kurtz-Perry powder technique.

  18. A novel organic nonlinear optical crystal: Creatininium succinate

    SciTech Connect

    Thirumurugan, R.; Anitha, K.

    2015-06-24

    A novel organic material complex of creatininium succinate (CS) has been synthesized and single crystals were grown by the reaction of creatinine and succinic acid from aqueous solution by employing the technique of slow evaporation at room temperature. The structure of the grown crystal has been elucidated using single crystal X-ray diffraction analysis and the structure was refined by least-squares method to R = 0.027 for 1840 reflections. FT-IR spectral investigation has been carried out to identify the various functional groups in the title compound. UV–Vis transmission was carried out which shows the crystal has a good optical transmittance in the visible region with lower cutoff wavelength around 220 nm. Nonlinear optical property of the crystal was confirmed by Kurtz-Perry powder technique.

  19. OPTICAL correlation identification technology applied in underwater laser imaging target identification

    NASA Astrophysics Data System (ADS)

    Yao, Guang-tao; Zhang, Xiao-hui; Ge, Wei-long

    2012-01-01

    The underwater laser imaging detection is an effective method of detecting short distance target underwater as an important complement of sonar detection. With the development of underwater laser imaging technology and underwater vehicle technology, the underwater automatic target identification has gotten more and more attention, and is a research difficulty in the area of underwater optical imaging information processing. Today, underwater automatic target identification based on optical imaging is usually realized with the method of digital circuit software programming. The algorithm realization and control of this method is very flexible. However, the optical imaging information is 2D image even 3D image, the amount of imaging processing information is abundant, so the electronic hardware with pure digital algorithm will need long identification time and is hard to meet the demands of real-time identification. If adopt computer parallel processing, the identification speed can be improved, but it will increase complexity, size and power consumption. This paper attempts to apply optical correlation identification technology to realize underwater automatic target identification. The optics correlation identification technology utilizes the Fourier transform characteristic of Fourier lens which can accomplish Fourier transform of image information in the level of nanosecond, and optical space interconnection calculation has the features of parallel, high speed, large capacity and high resolution, combines the flexibility of calculation and control of digital circuit method to realize optoelectronic hybrid identification mode. We reduce theoretical formulation of correlation identification and analyze the principle of optical correlation identification, and write MATLAB simulation program. We adopt single frame image obtained in underwater range gating laser imaging to identify, and through identifying and locating the different positions of target, we can improve

  20. OPTICAL correlation identification technology applied in underwater laser imaging target identification

    NASA Astrophysics Data System (ADS)

    Yao, Guang-Tao; Zhang, Xiao-Hui; Ge, Wei-Long

    2011-11-01

    The underwater laser imaging detection is an effective method of detecting short distance target underwater as an important complement of sonar detection. With the development of underwater laser imaging technology and underwater vehicle technology, the underwater automatic target identification has gotten more and more attention, and is a research difficulty in the area of underwater optical imaging information processing. Today, underwater automatic target identification based on optical imaging is usually realized with the method of digital circuit software programming. The algorithm realization and control of this method is very flexible. However, the optical imaging information is 2D image even 3D image, the amount of imaging processing information is abundant, so the electronic hardware with pure digital algorithm will need long identification time and is hard to meet the demands of real-time identification. If adopt computer parallel processing, the identification speed can be improved, but it will increase complexity, size and power consumption. This paper attempts to apply optical correlation identification technology to realize underwater automatic target identification. The optics correlation identification technology utilizes the Fourier transform characteristic of Fourier lens which can accomplish Fourier transform of image information in the level of nanosecond, and optical space interconnection calculation has the features of parallel, high speed, large capacity and high resolution, combines the flexibility of calculation and control of digital circuit method to realize optoelectronic hybrid identification mode. We reduce theoretical formulation of correlation identification and analyze the principle of optical correlation identification, and write MATLAB simulation program. We adopt single frame image obtained in underwater range gating laser imaging to identify, and through identifying and locating the different positions of target, we can improve

  1. Total light loss optic spectroscopy. Progress towards a fiber optic Raman organic vapor sensor

    SciTech Connect

    Kyle, K.R.; Vess, T.M.; Angel, S.M.

    1993-09-01

    A Raman probe has been developed utilizing a single optical fiber as both a light pipe and an active sensing element. By coating a small segment of the surface of an exposed glass fiber core with a thin polymer film, an inverted waveguide is formed where light transmitted down the fiber is stripped out of the core and into the polymer film. The polymer coating is used both as a waveguide and as a medium for concentrating small organic molecules to be interrogated by Raman spectroscopy. The ability of the fiber optic thin film waveguide probe to detect organic vapors is demonstrated. The utility of the probe in the detection of nonaqueous phase liquids (NAPLs) is also described.

  2. Integrated optics structures on sol-gel derived organic-inorganic hybrids for optical communications

    NASA Astrophysics Data System (ADS)

    André, P. S.; Vicente, C. M. S.; Fernandes, V.; Marques, C. A. F.; Pecoraro, E.; Nogueira, R. N.; Wada, N.; Carlos, L. D.; Marques, P. G.; Ferreira, R. A. S.

    2011-05-01

    Organic-inorganic hybrid materials are a technologically key class of advanced multifunctional materials that fulfil the challenging strict requirements of the beginning of the century: higher levels of sophistication, miniaturisation, recyclability, reliability and low energy consumption with potential to be used as low-cost components in optical networks operating at high bit rates. In this work, high-rejection optical filters (19 dB) first-order Bragg gratings inscribed in channel waveguides written in thin films of sol-gel derived organic-inorganic hybrid based on methacrylic acid modified zirconium tetrapropoxide, Zr(OPrn)4, (so-called di-ureasils), using UV-laser direct-write method.

  3. Nonlinear optical properties of organic materials: A theoretical study

    NASA Technical Reports Server (NTRS)

    Cardelino, Beatriz H.

    1991-01-01

    Replacement of electronic switching circuits in computing and telecommunication systems with purely optical devices offers the potential for extremely high throughput and compact information processing systems. The potential application of organic materials containing molecules with large nonresonant nonlinear effects in this area have triggered intensive research during the last decade. Interest on this area was due to two facts: (1) that many organic materials show nonlinearities that are orders of magnitude larger than those of conventional inorganic materials such as lithium niobate and potassium dihydrogen phosphate; and (2) that organic materials show much flexibility in terms of molecular designs. Some of the desirable characteristics that these materials should have are that they be transparent to the frequency of the incident laser and its second or third harmonic, that they have a high damage threshold, and, in the case of second-order effects, that their crystal structure or molecular orientation be accentric. Since polymeric assemblages can enhance the nonlinear response of organic molecules severalfold, efforts have been directed toward the synthesis of thin films with interpenetrating lattices of electroactive molecules. The goal of this theoretical investigation is to predict the magnitude of the molecular polarizabilities of organic molecules that could be incorporated into films. These calculations are intended to become a powerful tool to assist material scientists in screening for the best candidates for optical applications. The procedure that was developed for the present calculations is based on the static-field approach, and is a modification to the method developed by Dewar and Stewart, 1984 for calculating molecular linear polarizabilities.

  4. Additive and synergistic effects on plant growth from polymers and organic matter applied to soil simultaneously

    SciTech Connect

    Wallace, A.; Wallace, G.A.

    1986-05-01

    The effect of applying to soil combinations of organic sources was tested and an anionic polyacrylamide and both singly on emergence and growth of tomato and wheat plants. The interactions were generally additive and synergistic. The organic sources and polyacrylamide often had a sparing effect on the need for the other. In one test with an organic source high in N (6%), there was a negative interaction on growth of tomato plants between the polyacrylamide and the organic source. In a test in which the polyacrylamide was applied to soil in solution with a high application of composted manure, the interaction on growth of tomato seedlings was additive. Maximum response for tomatoes for soils low in soil organic matter to polyacrylamide was obtained for low 224 kg ha/sup -1/) rather than high (448 and 1120 kg ha/sup -1/) application levels with or without addition of other organics. Interaction between polyacrylamide and organics on plant growth varied with soil characteristics.

  5. Optical Properties of Photovoltaic Organic-Inorganic Lead Halide Perovskites.

    PubMed

    Green, Martin A; Jiang, Yajie; Soufiani, Arman Mahboubi; Ho-Baillie, Anita

    2015-12-01

    Over the last several years, organic-inorganic lead halide perovskites have rapidly emerged as a new photovoltaic contender. Although energy conversion efficiency above 20% has now been certified, improved understanding of the material properties contributing to these high performance levels may allow the progression to even higher efficiency, stable cells. The optical properties of these new materials are important not only to device design but also because of the insight they provide into less directly accessible properties, including energy-band structures, binding energies, and likely impact of excitons, as well as into absorption and inverse radiative recombination processes.

  6. Probing electric fields within organic transistors by nonlinear optics

    NASA Astrophysics Data System (ADS)

    Miranda, Paulo B.; Motti, Silvia G.; Gomes, Douglas J. C.

    2015-03-01

    Organic field-effect transistors (OFETs) are important building blocks in many organic devices, but further improvements in their performance will require a detailed knowledge of their operation mechanism. Thus mapping the electric fields in OFETs, both in the active organic layer and inside the gate dielectric, will allow a direct comparison with theoretical OFET models and guide advances in device engineering. The nonlinear optical processes of sum-frequency generation (SFG) and second-harmonic generation (SHG) may be used to probe electric fields in OFETs. With a proper choice of pump wavelength, SHG can selectively probe the field component along the OFET channel, inside the organic semiconductor. In contrast, SFG may probe the field within any organic material by selecting a specific molecular vibration and monitoring the field-enhanced SFG signal. Here we investigate OFETs fabricated with a polythiophene derivative (P3HT) on silicon substrates and with the insulating polymer PMMA for the dielectric layer. Both the strength and sign of the electric field in PMMA can be determined, yielding a direct probe of charge accumulation along the OFET channel. An extension of this technique to map the spatial distribution of accumulated charge along the channel will also be discussed. Work funded by FAPESP and CNPq (Brazil).

  7. Features in optical absorption and photocurrent spectra of organic solar cells due to organic/organic interface

    NASA Astrophysics Data System (ADS)

    Ismail, Yasser A. M.; Soga, Tetsuo; Jimbo, Takashi

    2011-05-01

    We surprisingly found that, organic/organic interface had a direct and pronounced impact on optical absorption and photocurrent spectra of organic solar cell at a favorable wavelength region of the visible solar spectrum. The organic/organic interface was formed as a result of connection between coumarin 6 (C6): [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) blend films and indium-tin oxide (ITO)/poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS) electrode. Optical absorption measurement was carried out for ITO/PEDOT:PSS/C6:PCBM films, while external quantum efficiency measurement was carried out for ITO/PEDOT:PSS/C6:PCBM/Al solar cells, with varying C6:PCBM blend concentration. We found that, the C6:PCBM blend in the ITO/PEDOT:PSS/C6:PCBM films had an additional feature in the absorption spectra at the wavelength range of 520-800 nm, at which the C6 dye, PCBM, PEDOT:PSS, and ITO were transparent. An additional feature, also, appeared in photocurrent spectra of the C6:PCBM films in the ITO/PEDOT:PSS/C6:PCBM/Al solar cells at the same wavelength range. The new features in the optical absorption and photocurrent spectra of the investigated solar cells originated, in all probability, due to optically induced sup-band transitions in the C6:PCBM blend films at the interface with ITO/PEDOT:PSS electrode. Thus, the C6:PCBM blend films produced a charge carrier generation interface due to connection with ITO/PEDOT:PSS electrode. As a result of this charge carrier generation interface, the power conversion efficiency of the corresponding solar cell is improved. Taking into consideration these new findings, the high-band-gap organic materials will take more importance as sensitizers in organic optoelectronic applications.

  8. Detection of organic nanoparticles within tissues using optical iterative method

    NASA Astrophysics Data System (ADS)

    Yariv, Inbar; Fixler, Dror; Lubart, Rachel; Duadi, Hamootal; Lipovsky, Anat

    2016-03-01

    Various techniques for recovering optical parameters were developed over the years. However each has its limitations, constraints and disadvantages (e.g. accuracy, computational speed, sample assembly, distinguishing between the different parameters, etc.). This research suggests an optical technique for extracting the reduced scattering coefficient (μs') of substances by examining the light transmission through or reflection from them. It uses the multiple planes Gerchberg- Saxton (G-S) algorithm to reconstruct the light phase created by the substance. At the end of the algorithm, μs' can be estimated from the standard deviation (STD) of the retrieved phase of the reemitted light. We will use the theory to compute the phase's STD that directly correlated to the optical properties of different substances. Two possible applications for this technique, out of many others, are nanoparticles (NPs) penetration depth determination, for promoting topical medications, and detection of milk components quantitative signature as en route to milk content monitoring tool. For the former application, three materials were fabricated into NPs and all presented an activity enhancement with their size reduction. Then the NPs were applied on tissues and detected by our technique. For the latter, different milk content concentrations were examined resulting with different STD values suggesting it can be used as indicator for the milk component concentrations.

  9. Multifocus microscopy with precise color multi-phase diffractive optics applied in functional neuronal imaging.

    PubMed

    Abrahamsson, Sara; Ilic, Rob; Wisniewski, Jan; Mehl, Brian; Yu, Liya; Chen, Lei; Davanco, Marcelo; Oudjedi, Laura; Fiche, Jean-Bernard; Hajj, Bassam; Jin, Xin; Pulupa, Joan; Cho, Christine; Mir, Mustafa; El Beheiry, Mohamed; Darzacq, Xavier; Nollmann, Marcelo; Dahan, Maxime; Wu, Carl; Lionnet, Timothée; Liddle, J Alexander; Bargmann, Cornelia I

    2016-03-01

    Multifocus microscopy (MFM) allows high-resolution instantaneous three-dimensional (3D) imaging and has been applied to study biological specimens ranging from single molecules inside cells nuclei to entire embryos. We here describe pattern designs and nanofabrication methods for diffractive optics that optimize the light-efficiency of the central optical component of MFM: the diffractive multifocus grating (MFG). We also implement a "precise color" MFM layout with MFGs tailored to individual fluorophores in separate optical arms. The reported advancements enable faster and brighter volumetric time-lapse imaging of biological samples. In live microscopy applications, photon budget is a critical parameter and light-efficiency must be optimized to obtain the fastest possible frame rate while minimizing photodamage. We provide comprehensive descriptions and code for designing diffractive optical devices, and a detailed methods description for nanofabrication of devices. Theoretical efficiencies of reported designs is ≈90% and we have obtained efficiencies of > 80% in MFGs of our own manufacture. We demonstrate the performance of a multi-phase MFG in 3D functional neuronal imaging in living C. elegans. PMID:27231594

  10. Multifocus microscopy with precise color multi-phase diffractive optics applied in functional neuronal imaging

    PubMed Central

    Abrahamsson, Sara; Ilic, Rob; Wisniewski, Jan; Mehl, Brian; Yu, Liya; Chen, Lei; Davanco, Marcelo; Oudjedi, Laura; Fiche, Jean-Bernard; Hajj, Bassam; Jin, Xin; Pulupa, Joan; Cho, Christine; Mir, Mustafa; El Beheiry, Mohamed; Darzacq, Xavier; Nollmann, Marcelo; Dahan, Maxime; Wu, Carl; Lionnet, Timothée; Liddle, J. Alexander; Bargmann, Cornelia I.

    2016-01-01

    Multifocus microscopy (MFM) allows high-resolution instantaneous three-dimensional (3D) imaging and has been applied to study biological specimens ranging from single molecules inside cells nuclei to entire embryos. We here describe pattern designs and nanofabrication methods for diffractive optics that optimize the light-efficiency of the central optical component of MFM: the diffractive multifocus grating (MFG). We also implement a “precise color” MFM layout with MFGs tailored to individual fluorophores in separate optical arms. The reported advancements enable faster and brighter volumetric time-lapse imaging of biological samples. In live microscopy applications, photon budget is a critical parameter and light-efficiency must be optimized to obtain the fastest possible frame rate while minimizing photodamage. We provide comprehensive descriptions and code for designing diffractive optical devices, and a detailed methods description for nanofabrication of devices. Theoretical efficiencies of reported designs is ≈90% and we have obtained efficiencies of > 80% in MFGs of our own manufacture. We demonstrate the performance of a multi-phase MFG in 3D functional neuronal imaging in living C. elegans. PMID:27231594

  11. Multifocus microscopy with precise color multi-phase diffractive optics applied in functional neuronal imaging.

    PubMed

    Abrahamsson, Sara; Ilic, Rob; Wisniewski, Jan; Mehl, Brian; Yu, Liya; Chen, Lei; Davanco, Marcelo; Oudjedi, Laura; Fiche, Jean-Bernard; Hajj, Bassam; Jin, Xin; Pulupa, Joan; Cho, Christine; Mir, Mustafa; El Beheiry, Mohamed; Darzacq, Xavier; Nollmann, Marcelo; Dahan, Maxime; Wu, Carl; Lionnet, Timothée; Liddle, J Alexander; Bargmann, Cornelia I

    2016-03-01

    Multifocus microscopy (MFM) allows high-resolution instantaneous three-dimensional (3D) imaging and has been applied to study biological specimens ranging from single molecules inside cells nuclei to entire embryos. We here describe pattern designs and nanofabrication methods for diffractive optics that optimize the light-efficiency of the central optical component of MFM: the diffractive multifocus grating (MFG). We also implement a "precise color" MFM layout with MFGs tailored to individual fluorophores in separate optical arms. The reported advancements enable faster and brighter volumetric time-lapse imaging of biological samples. In live microscopy applications, photon budget is a critical parameter and light-efficiency must be optimized to obtain the fastest possible frame rate while minimizing photodamage. We provide comprehensive descriptions and code for designing diffractive optical devices, and a detailed methods description for nanofabrication of devices. Theoretical efficiencies of reported designs is ≈90% and we have obtained efficiencies of > 80% in MFGs of our own manufacture. We demonstrate the performance of a multi-phase MFG in 3D functional neuronal imaging in living C. elegans.

  12. Temperature and pressure fiber-optic sensors applied to minimally invasive diagnostics and therapies

    NASA Astrophysics Data System (ADS)

    Hamel, Caroline; Pinet, Éric

    2006-02-01

    We present how fiber-optic temperature or pressure sensors could be applied to minimally invasive diagnostics and therapies. For instance a miniature pressure sensor based on micro-optical mechanical systems (MOMS) could solve most of the problems associated with fluidic pressure transduction presently used for triggering purposes. These include intra-aortic balloon pumping (IABP) therapy and other applications requiring detection of fast and/or subtle fluid pressure variations such as for intracranial pressure monitoring or for urology diagnostics. As well, miniature temperature sensors permit minimally invasive direct temperature measurement in diagnostics or therapies requiring energy transfer to living tissues. The extremely small size of fiber-optic sensors that we have developed allows quick and precise in situ measurements exactly where the physical parameters need to be known. Furthermore, their intrinsic immunity to electromagnetic interference (EMI) allows for the safe use of EMI-generating therapeutic or diagnostic equipments without compromising the signal quality. With the trend of ambulatory health care and the increasing EMI noise found in modern hospitals, the use of multi-parameter fiber-optic sensors will improve constant patient monitoring without any concern about the effects of EMI disturbances. The advantages of miniature fiberoptic sensors will offer clinicians new monitoring tools that open the way for improved diagnostic accuracy and new therapeutic technologies.

  13. Optical diagnostic test of stress conditions of aquatic organisms.

    PubMed

    Axenov-Gribanov, Denis V; Gurkov, Anton N; Shakhtanova, Nadezhda S; Bedulina, Daria S; Timofeyev, Maxim A; Meglinski, Igor

    2011-09-01

    Global climate change has become a dire reality and its impact is expected to rise dramatically in the near future. Combined with the day-to-day human activities the climatic changes heavily affect the environment. In particular, a global temperature increase accompanied by a number of anthropogenic chemicals falling within the freshwater ecosystem results in a dramatic enhancement of the overall stress for most aquatic organisms. This leads to a significant shift in the species inventory and potential breakdown of the water ecosystem with severe consequences for local economies and water supply. In order to understand and predict the influence of climatic changes on the physiological and biochemical processes that take place in living aquatic organisms we explore the application of optical spectroscopy for monitoring and quantitative assessment of antioxidant enzymes activity in benthic amphipods of Lake Baikal. We demonstrate that the changes of the enzymes activity in Baikal amphipods undergoing thermal and/or hypoxia stress can be observed and documented by UV and optical spectroscopy both in vivo and in vitro. PMID:21548104

  14. How Settings Change People: Applying Behavior Setting Theory to Consumer-Run Organizations

    ERIC Educational Resources Information Center

    Brown, Louis D.; Shepherd, Matthew D.; Wituk, Scott A.; Meissen, Greg

    2007-01-01

    Self-help initiatives stand as a classic context for organizational studies in community psychology. Behavior setting theory stands as a classic conception of organizations and the environment. This study explores both, applying behavior setting theory to consumer-run organizations (CROs). Analysis of multiple data sets from all CROs in Kansas…

  15. 40 CFR 262.100 - To what organizations does this subpart apply?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Laboratories XL Project-Laboratory Environmental Management Standard § 262.100 To what organizations does this... 40 Protection of Environment 27 2013-07-01 2013-07-01 false To what organizations does this subpart apply? 262.100 Section 262.100 Protection of Environment ENVIRONMENTAL PROTECTION...

  16. 40 CFR 262.100 - To what organizations does this subpart apply?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Laboratories XL Project-Laboratory Environmental Management Standard § 262.100 To what organizations does this... 40 Protection of Environment 26 2014-07-01 2014-07-01 false To what organizations does this subpart apply? 262.100 Section 262.100 Protection of Environment ENVIRONMENTAL PROTECTION...

  17. Electrical and optical properties of organic thin films

    SciTech Connect

    Buckner, S.L.

    1991-01-01

    This research examines the applicability of organic thin films as electric insulators in metal-insulator-semiconductor (MIS) and metal-insulator-metal (MIM) devices and an anti-reflective (A-R) coatings for solar cells. Films of anthracene, stearic acid, and diacetylene alcohol were examined for their electrical and optical properties. Two techniques were used to deposit the films for these studies. Thermal evaporation in vacuum was used to deposit aluminum as electrodes and contacts in MIS and MIM devices. The organic films were deposited by either thermal evaporation or the Langmuir-Blodgett (L-B) dipping technique. Several vacuum systems and an L-B trough were fabricated for these studies and their design and construction are outlined. Several types of measurements were used to examined the properties of the organic films. For each type of measurement made on the devices, theories are outlined to analyze the data obtained. Finally, conclusions are drawn as to the applicable of these types of organic materials as insulators and coatings for semiconductor devices.

  18. Nano- and microparticles of organic fluorescent dyes: self-organization and optical properties.

    PubMed

    Fery-Forgues, Suzanne; Abyan, Mouhammad; Lamere, Jean-François

    2008-01-01

    Organic nanostructured materials are of increasing interest for applications in the fields of bioanalysis, photocatalysis, photonics, and organic light-emitting diodes. However, their preparation is still difficult to control and their optical properties are inadequately known. A solvent-exchange process called the "reprecipitation method" was used here to prepare nano- and microcrystals from fluorescent dyes belonging, for example, to the coumarin and nitrobenzoxadiazole (NBD) series. Typically, the dyes were dissolved in a hydrophilic organic solvent and then suddenly placed in an aqueous environment, where they spontaneously produce molecular assemblies. According to the self-association properties of the dyes and to the experimental conditions used, the nano- and microcrystals obtained exhibited different sizes and shapes, as observed by fluorescence and electron microscopy. In some cases, the crystal habit was controlled by adding some additives to the reprecipitation medium. The overall optical properties of the free-standing particles in suspension were generally quite close to those of the dissolved dyes. However, strong distortions of the absorption and emission spectra were observed for crystals grown in the presence of ionic additives. Under the fluorescence microscope, individual microcrystals may show peculiar emission characteristics, displaying bright and dark zones, or behaving like tiny optical fibers.

  19. Applying UV cameras for SO2 detection to distant or optically thick volcanic plumes

    NASA Astrophysics Data System (ADS)

    Kern, Christoph; Werner, Cynthia; Elias, Tamar; Sutton, A. Jeff; Lübcke, Peter

    2013-07-01

    Ultraviolet (UV) camera systems represent an exciting new technology for measuring two dimensional sulfur dioxide (SO2) distributions in volcanic plumes. The high frame rate of the cameras allows the retrieval of SO2 emission rates at time scales of 1 Hz or higher, thus allowing the investigation of high-frequency signals and making integrated and comparative studies with other high-data-rate volcano monitoring techniques possible. One drawback of the technique, however, is the limited spectral information recorded by the imaging systems. Here, a framework for simulating the sensitivity of UV cameras to various SO2 distributions is introduced. Both the wavelength-dependent transmittance of the optical imaging system and the radiative transfer in the atmosphere are modeled. The framework is then applied to study the behavior of different optical setups and used to simulate the response of these instruments to volcanic plumes containing varying SO2 and aerosol abundances located at various distances from the sensor. Results show that UV radiative transfer in and around distant and/or optically thick plumes typically leads to a lower sensitivity to SO2 than expected when assuming a standard Beer-Lambert absorption model. Furthermore, camera response is often non-linear in SO2 and dependent on distance to the plume and plume aerosol optical thickness and single scatter albedo. The model results are compared with camera measurements made at Kilauea Volcano (Hawaii) and a method for integrating moderate resolution differential optical absorption spectroscopy data with UV imagery to retrieve improved SO2 column densities is discussed.

  20. Applying UV cameras for SO2 detection to distant or optically thick volcanic plumes

    USGS Publications Warehouse

    Kern, Christoph; Werner, Cynthia; Elias, Tamar; Sutton, A. Jeff; Lübcke, Peter

    2013-01-01

    Ultraviolet (UV) camera systems represent an exciting new technology for measuring two dimensional sulfur dioxide (SO2) distributions in volcanic plumes. The high frame rate of the cameras allows the retrieval of SO2 emission rates at time scales of 1 Hz or higher, thus allowing the investigation of high-frequency signals and making integrated and comparative studies with other high-data-rate volcano monitoring techniques possible. One drawback of the technique, however, is the limited spectral information recorded by the imaging systems. Here, a framework for simulating the sensitivity of UV cameras to various SO2 distributions is introduced. Both the wavelength-dependent transmittance of the optical imaging system and the radiative transfer in the atmosphere are modeled. The framework is then applied to study the behavior of different optical setups and used to simulate the response of these instruments to volcanic plumes containing varying SO2 and aerosol abundances located at various distances from the sensor. Results show that UV radiative transfer in and around distant and/or optically thick plumes typically leads to a lower sensitivity to SO2 than expected when assuming a standard Beer–Lambert absorption model. Furthermore, camera response is often non-linear in SO2 and dependent on distance to the plume and plume aerosol optical thickness and single scatter albedo. The model results are compared with camera measurements made at Kilauea Volcano (Hawaii) and a method for integrating moderate resolution differential optical absorption spectroscopy data with UV imagery to retrieve improved SO2 column densities is discussed.

  1. Layer-Resolved Evolution of Organic Thin Films Monitored by Photoelectron Emission Microscopy and Optical Reflectance Spectroscopy

    PubMed Central

    2015-01-01

    Photoelectron emission microscopy (PEEM) and differential (optical) reflectance spectroscopy (DRS) have proven independently to be versatile analytical tools for monitoring the evolution of organic thin films during growth. In this paper, we present the first experiment in which both techniques have been applied simultaneously and synchronously. We illustrate how the combined PEEM and DRS results can be correlated to obtain an extended perspective on the electronic and optical properties of a molecular film dependent on the film thickness and morphology. As an example, we studied the deposition of the organic molecule α-sexithiophene on Ag(111) in the thickness range from submonolayers up to several monolayers. PMID:26523159

  2. Near real-time measurement of forces applied by an optical trap to a rigid cylindrical object

    NASA Astrophysics Data System (ADS)

    Glaser, Joseph; Hoeprich, David; Resnick, Andrew

    2014-07-01

    An automated data acquisition and processing system is established to measure the force applied by an optical trap to an object of unknown composition in real time. Optical traps have been in use for the past 40 years to manipulate microscopic particles, but the magnitude of applied force is often unknown and requires extensive instrument characterization. Measuring or calculating the force applied by an optical trap to nonspherical particles presents additional difficulties which are also overcome with our system. Extensive experiments and measurements using well-characterized objects were performed to verify the system performance.

  3. Motivating Company Personnel by Applying the Semi-self-organized Teams Principle

    NASA Astrophysics Data System (ADS)

    Kumlander, Deniss

    The only way nowadays to improve stability of software development process in the global rapidly evolving world is to be innovative and involve professionals into projects motivating them using both material and non material factors. In this paper self-organized teams are discussed. Unfortunately not all kind of organizations can benefit directly from agile method including applying self-organized teams. The paper proposes semi-self-organized teams presenting it as a new and promising motivating factor allowing deriving many positive sides of been self-organized and partly agile and been compliant to less strict conditions for following this innovating process. The semi-self organized teams are reliable at least in the short-term perspective and are simple to organize and support.

  4. Improvement of optical extraction efficiency of organic light-emitting diode using a large area nano-pattern.

    PubMed

    Jung, Jae-Hun; Lee, Ui-Hyung; Jul, Young-Gu

    2012-07-01

    In order to improve optical extraction efficiencies, we propose a nano-patterned organic light-emitting diode (OLED) which doesn't rely on high precision lithography nor rigorous periodicity. The nano-pattern is fabricated by spin-coating PS (poly-styrene) spheres on the substrate and carrying out reactive ion etching and flattening using dielectric material. The verification of the optical properties of the nano patterns was carried out by fabricating OLED-like structures using quantum dot and distributed Bragg reflector (DBR). As a result, the nano-patterned structure showed a 28% increase in optical efficiency compared to the non-patterned sample. In addition, the use of a prism sheet on the backside of a glass substrate also showed a 23% increase in optical efficiency by disturbing the total internal reflection between glass and air. In this way, the large area nano-patterns can be fabricated and applied to increasing the optical extraction in OLED.

  5. [Techniques of on-line monitoring volatile organic compounds in ambient air with optical spectroscopy].

    PubMed

    Du, Zhen-Hui; Zhai, Ya-Qiong; Li, Jin-Yi; Hu, Bo

    2009-12-01

    Volatile organic compounds (VOCs) are harmful gaseous pollutants in the ambient air. The techniques of on-line monitoring VOCs are very significant for environment protection. Until now, there is no single technology that can meet all the needs of monitoring various VOCs. The characteristics and present situation of several optical methods, which can be applied to on-line monitoring VOCs, including non dispersive infrared (NDIR), Fourier transform infrared (FTIR) spectroscopy, differential optical absorption spectroscopy (DOAS), and laser spectroscopy were reviewed. Comparison was completed between the national standard methods and spectroscopic method for measuring VOCs. The main analysis was focused on the status and trends of tuning diode laser absorption spectroscopy (TDLAS) technology. PMID:20210131

  6. Superior characteristics of organic chalcone single crystals as efficient nonlinear optical material

    NASA Astrophysics Data System (ADS)

    Kiran, A. John; Kim, H. C.; Kim, K.; Rotermund, F.; Ravindra, H. J.; Dharmaprakash, S. M.; Lim, H.

    2008-03-01

    High-quality biaxial single crystals of chalcone derivatives were grown by solution growth technique. Their molecular structures were designed to possess large second-order nonlinearities by choosing proper donor/acceptor groups while retaining a high transparency in the visible and infrared spectral regions. The second-order nonlinear optical coefficients, determined by applying the Maker fringe technique, were found to be much larger than those of LiB3O5, KTiOPO4, KH2PO4, and urea. The advantages, such as easy synthesis and crystal growth, low cutoff wavelength (<450nm ), large optical nonlinearity, and high damage threshold (>7.2GW/cm2), make these organic crystals promising for efficient frequency doubling.

  7. Leaching of Particulate and Dissolved Organic Carbon from Compost Applied to Bioretention Systems

    NASA Astrophysics Data System (ADS)

    Iqbal, Hamid; Flury, Markus; Mullane, Jessica; Baig, Muhammad

    2015-04-01

    Compost is used in bioretention systems to improve soil quality, to promote plant growth, and to remove metal contaminants from stormwater. However, compost itself, particularly when applied freshly, can be a source of contamination of the stormwater. To test the potential contamination caused by compost when applied to bioretention systems, we continuously leached a compost column with water under unsaturated conditions and characterized dissolved and particulate organic matter in the leachate. Freshly applied, mature compost leached up to 400 mg/L of dissolved organic carbon and 2,000 mg/L of suspended particulate organic carbon. It required a cumulative water flux of 4,000 mm until concentrations of dissolved and particulate organic carbon declined to levels typical for surface waters. Although, dissolved and particulate organic carbon are not contaminants per se, they can facilitate the movement of metals, thereby enhancing the mobility of toxic metals present in stormwater. Therefore, we recommended that compost is washed before it is applied to bioretention systems. Keywords compost; leachate; alkali extract; dissolved organic carbon; flux

  8. Optical Spintronics in Organic-Inorganic Perovskite Photovoltaics

    PubMed Central

    Li, Junwen; Haney, Paul M.

    2016-01-01

    Organic-inorganic halide CH3NH3PbI3 solar cells have attracted enormous attention in recent years due to their remarkable power conversion efficiency. When inversion symmetry is broken, these materials should exhibit interesting spin-dependent properties as well, owing to their strong spin-orbit coupling. In this work, we consider the spin-dependent optical response of CH3NH3PbI3. We first use density functional theory to compute the ballistic spin current generated by absorption of unpolarized light. We then consider diffusive transport of photogenerated charge and spin for a thin CH3NH3PbI3 layer with a passivated surface and an Ohmic, non-selective contact. The spin density and spin current are evaluated by solving the drift-diffusion equations for a simplified 3-dimensional Rashba model of the electronic structure of the valence and conduction bands. We provide analytic expressions for the photon flux required to induce measurable spin densities, and propose that these spin densities can provide useful information about the role of grain boundaries in the photovoltaic behavior of these materials. We also discuss the prospects for measuring the optically generated spin current with the inverse spin Hall effect. PMID:27453958

  9. Optical spintronics in organic-inorganic perovskite photovoltaics

    NASA Astrophysics Data System (ADS)

    Li, Junwen; Haney, Paul M.

    2016-04-01

    Organic-inorganic halide CH3NH3PbI3 solar cells have attracted enormous attention in recent years due to their remarkable power conversion efficiency. When inversion symmetry is broken, these materials should exhibit interesting spin-dependent properties as well, owing to their strong spin-orbit coupling. In this work, we consider the spin-dependent optical response of CH3NH3PbI3 . We first use density functional theory to compute the ballistic spin current generated by absorption of unpolarized light. We then consider diffusive transport of photogenerated charge and spin for a thin CH3NH3PbI3 layer with a passivated surface and an Ohmic, nonselective contact. The spin density and spin current are evaluated by solving the drift-diffusion equations for a simplified three-dimensional Rashba model of the electronic structure of the valence and conduction bands. We provide analytic expressions for the photon flux required to induce measurable spin densities, and propose that these spin densities can provide useful information about the role of grain boundaries in the photovoltaic behavior of these materials. We also discuss the prospects for measuring the optically generated spin current with the inverse spin Hall effect.

  10. Multi-spectral optical simulation system applied in hardware-in-the-loop

    NASA Astrophysics Data System (ADS)

    Yu, Hong; Lei, Jie; Gao, Yang; Liu, Yang

    2009-07-01

    The Multi-spectral simulation system has been constructed at Beijing Simulation Center (BSC) for hardware-in-the-loop (HWIL) testing of optical and infrared seekers, in single-band and dual-band, or even multi-band. This multi-spectral simulation facility consists primarily of several projectors and a wide-angular simulation mechanism, the projector technologies utilized at BSC include a broadband point source collimator, a laser echo simulator and a visible scene projection system. These projectors can be used individually with the wide-angular simulation mechanism, or any combination of both or all of three can be used according to different needs. The configuration and performance of each technology are reviewed in the paper. Future plans include two IR imaging projectors which run at high frame frequency. The multi-spectral optical simulation system has been successfully applied for visible and IR imaging seekers testing in HWIL simulation. The laser echo simulator hardware will be applied soon.

  11. Nano-particle based scattering layers for optical efficiency enhancement of organic light-emitting diodes and organic solar cells

    NASA Astrophysics Data System (ADS)

    Chang, Hong-Wei; Lee, Jonghee; Hofmann, Simone; Hyun Kim, Yong; Müller-Meskamp, Lars; Lüssem, Björn; Wu, Chung-Chih; Leo, Karl; Gather, Malte C.

    2013-05-01

    The performance of both organic light-emitting diodes (OLEDs) and organic solar cells (OSC) depends on efficient coupling between optical far field modes and the emitting/absorbing region of the device. Current approaches towards OLEDs with efficient light-extraction often are limited to single-color emission or require expensive, non-standard substrates or top-down structuring, which reduces compatibility with large-area light sources. Here, we report on integrating solution-processed nano-particle based light-scattering films close to the active region of organic semiconductor devices. In OLEDs, these films efficiently extract light that would otherwise remain trapped in the device. Without additional external outcoupling structures, translucent white OLEDs containing these scattering films achieve luminous efficacies of 46 lm W-1 and external quantum efficiencies of 33% (both at 1000 cd m-2). These are by far the highest numbers ever reported for translucent white OLEDs and the best values in the open literature for any white device on a conventional substrate. By applying additional light-extraction structures, 62 lm W-1 and 46% EQE are reached. Besides universally enhancing light-extraction in various OLED configurations, including flexible, translucent, single-color, and white OLEDs, the nano-particle scattering film boosts the short-circuit current density in translucent organic solar cells by up to 70%.

  12. Luminescence Sensors Applied to Water Analysis of Organic Pollutants—An Update

    PubMed Central

    Ibañez, Gabriela A.; Escandar, Graciela M.

    2011-01-01

    The development of chemical sensors for environmental analysis based on fluorescence, phosphorescence and chemiluminescence signals continues to be a dynamic topic within the sensor field. This review covers the fundamentals of this type of sensors, and an update on recent works devoted to quantifying organic pollutants in environmental waters, focusing on advances since about 2005. Among the wide variety of these contaminants, special attention has been paid polycyclic aromatic hydrocarbons, pesticides, explosives and emerging organic pollutants. The potential of coupling optical sensors with multivariate calibration methods in order to improve the selectivity is also discussed. PMID:22247654

  13. Thermal and optical properties of new organic nonlinear optical single crystals

    NASA Astrophysics Data System (ADS)

    Menezes, Anthoni Praveen; Jayarama, A.

    2014-04-01

    Nonlinear optical (NLO) materials are useful in a number of industrial applications. Organic NLO single crystals of 3-(4-chlorophenyl)-1-(pyridin-3-yl) prop-2-en-1-one (4-Chloro chalcone, 4CC) and 3-(4-bromophenyl)-1-(pyridin-3-yl) prop-2-en-1-one (4-bromo chalcone, 4BC), having large second harmonic generation efficiency (SHG), were grown by slow evaporation technique. The thermal analysis reveals that these chalcone derivatives possess better thermal stability in comparison with urea. Both the crystals 4CC and 4BC are non-linear optically active with SHG efficiencies of 4 and 1.4 times that of urea respectively. The UV-Visible spectrum reveals that the crystals are transparent in the entire visible region. The substitution of a chloro group at the para position of the phenylene moiety is better in increasing the SHG efficiency of the crystal compared to a bromo group. Good thermal stability, optical transparency and SHG response make the crystals useful for frequency doubling of diode laser down to 435nm.

  14. Characterization of optically stimulated luminescence dosemeters to measure organ doses in diagnostic radiology

    PubMed Central

    Endo, A; Katoh, T; Kobayashi, I; Joshi, R; Sur, J; Okano, T

    2012-01-01

    Objective The aim of this study was to assess the characteristics of an optically stimulated luminescence dosemeter (OSLD) for use in diagnostic radiology and to apply the OSLD in measuring the organ doses by panoramic radiography. Methods The dose linearity, energy dependency and angular dependency of aluminium oxide-based OSLDs were examined using an X-ray generator to simulate various exposure settings in diagnostic radiology. The organ doses were then measured by inserting the dosemeters into an anthropomorphic phantom while using three panoramic machines. Results The dosemeters demonstrated consistent dose linearity (coefficient of variation<1.5%) and no significant energy dependency (coefficient of variation<1.5%) under the applied exposure conditions. They also exhibited negligible angular dependency (≤10%). The organ doses of the X-ray as a result of panoramic imaging by three machines were calculated using the dosemeters. Conclusion OSLDs can be utilized to measure the organ doses in diagnostic radiology. The availability of these dosemeters in strip form proves to be reliably advantageous. PMID:22116136

  15. A novel optical calorimetry dosimetry approach applied to an HDR Brachytherapy source

    NASA Astrophysics Data System (ADS)

    Cavan, A.; Meyer, J.

    2013-06-01

    The technique of Digital Holographic Interferometry (DHI) is applied to the measurement of radiation absorbed dose distribution in water. An optical interferometer has been developed that captures the small variations in the refractive index of water due to the radiation induced temperature increase ΔT. The absorbed dose D is then determined with high temporal and spatial resolution using the calorimetric relation D=cΔT (where c is the specific heat capacity of water). The method is capable of time resolving 3D spatial calorimetry. As a proof-of-principle of the approach, a prototype DHI dosimeter was applied to the measurement of absorbed dose from a High Dose Rate (HDR) Brachytherapy source. Initial results are in agreement with modelled doses from the Brachyvision treatment planning system, demonstrating the viability of the system for high dose rate applications. Future work will focus on applying corrections for heat diffusion and geometric effects. The method has potential to contribute to the dosimetry of diverse high dose rate applications which require high spatial resolution such as microbeam radiotherapy (MRT) or small field proton beam dosimetry but may potentially also be useful for interface dosimetry.

  16. Optical Properties of Polymers Relevant to Secondary Organic Aerosols

    NASA Astrophysics Data System (ADS)

    Marrero-Ortiz, W.; Gomez-Hernandez, M. E.; Xu, W.; Guo, S.; Zhang, R.

    2014-12-01

    Atmospheric aerosols play a critical role in climate directly by scattering and absorbing solar radiation and indirectly by modifying the cloud formation. Currently, the direct and indirect effects of aerosols represent the largest uncertainty in climate predictions models. Some aerosols are directly emitted, but the majority are formed in the atmosphere by the oxidation of gaseous precursors. However, the formation of aerosols at the molecular level is not fully characterized. Certain category of secondary organic aerosols (SOA), which represent a significant fraction of the total aerosol burden, can be light-absorbing, also known as brown carbon. However, the overall contribution of SOA to the brown carbon and the related climate forcing is poorly understood. Such incomplete understanding is due in part to the chemical complexity of SOA and the lack of knowledge regarding SOA formation, transformation, and optical properties. Based on previous laboratory experiments, field measurements, and modeling studies, it has been suggested that the polymers and oligomers play an important role in the SOA formation. Atmospheric polymers could be produced by the hydration or heterogeneous reactions of epoxides and small α-dicarbonyls. Their aqueous chemistry products have been shown to give light-absorbing and high molecular weight oligomeric species, which increase the SOA mass production and alter the direct and indirect effect of aerosols. In this paper, the aerosol chemistry of small α-dicarbonyl compounds with amines is investigated and the associated optical properties are measured using spectroscopic techniques. The differences between primary, secondary and tertiary amines with glyoxal and methylglyoxal are evaluated in terms of SOA browning efficiency. Atmospheric implications of our present work for understanding the formation of light-absorbing SOA will be presented, particularly in terms of the product distribution of light-absorbing SOA formed by aqueous phase

  17. Applying Hofstede's Cross-Cultural Theory of Organizations to School Governance: A French Case Study.

    ERIC Educational Resources Information Center

    Fowler, Frances C.

    This paper applies Geert Hofstede's cross-cultural theory of organizational structure and behavior to school administration, examining the governance structure of the French public school system to determine how accurately it predicts the form of that educational organization. The first section of the paper presents Hofstede's theory and his…

  18. Graphic Organizers Applied to Secondary Algebra Instruction for Students with Learning Disorders

    ERIC Educational Resources Information Center

    Ives, Bob

    2007-01-01

    Students who have particular difficulty in mathematics are a growing concern for educators. Graphic organizers have been shown to improve reading comprehension and may be applied to upper level secondary mathematics content. In two systematic replications, one randomly assigned group was taught to solve systems of linear equations through direct…

  19. 24 CFR 5.1003 - Use of a universal identifier for organizations applying for HUD grants.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 24 Housing and Urban Development 1 2010-04-01 2010-04-01 false Use of a universal identifier for organizations applying for HUD grants. 5.1003 Section 5.1003 Housing and Urban Development Office of the Secretary, Department of Housing and Urban Development GENERAL HUD PROGRAM REQUIREMENTS; WAIVERS...

  20. 20 CFR 641.620 - How may an organization apply for section 502(e) funding?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ...(e) funding? 641.620 Section 641.620 Employees' Benefits EMPLOYMENT AND TRAINING ADMINISTRATION, DEPARTMENT OF LABOR PROVISIONS GOVERNING THE SENIOR COMMUNITY SERVICE EMPLOYMENT PROGRAM Private Sector Training Projects Under Section 502(e) of the OAA § 641.620 How may an organization apply for section...

  1. 40 CFR 262.100 - To what organizations does this subpart apply?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false To what organizations does this subpart apply? 262.100 Section 262.100 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE...

  2. 40 CFR 262.100 - To what organizations does this subpart apply?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false To what organizations does this subpart apply? 262.100 Section 262.100 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE...

  3. Resonant state expansion applied to two-dimensional open optical systems

    NASA Astrophysics Data System (ADS)

    Doost, M. B.; Langbein, W.; Muljarov, E. A.

    2013-04-01

    The resonant state expansion (RSE), a rigorous perturbative method in electrodynamics, is applied to two-dimensional open optical systems. The analytically solvable homogeneous dielectric cylinder is used as an unperturbed system, and its Green's function is shown to contain a cut in the complex frequency plane, which is included in the RSE basis. The complex eigenfrequencies of modes are calculated using the RSE for a selection of perturbations which mix unperturbed modes of different orbital momentum, such as half-cylinder, thin-film, and thin-wire perturbation, demonstrating the accuracy and convergency of the method. The resonant states for the thin-wire perturbation are shown to reproduce an approximative analytical solution.

  4. Theoretical evaluation of measurement uncertainties of two-color pyrometry applied to optical diagnostics

    SciTech Connect

    Fu Tairan; Cheng Xiaofang; Yang Zangjian

    2008-11-10

    We present a theoretical analysis of two-color pyrometry applied to optical diagnostics. A two-color pyrometer built with a single CCD is advantageous due to the simple system design. We evaluate the possibility and degree of ill-conditionness on the basis of measurement uncertainties for different measurement approaches of this two-color system. We classify measurement approaches. The corresponding ill-conditionness criterion is established. The greater the criterion value is, the worse the ill-conditioned degree of solution is. So, the optimum choice of measurement approach for the two-color system is achieved through intercomparison of the criterion values. Numerical examples are also given to illustrate this point. The theoretical analysis not only provides an effective way of evaluating different measurement approaches, but also may help us to better understand the influences that determine the choices between wavelength/waveband measurements and calibration/noncalibration modes for temperature and soot distribution.

  5. Theoretical evaluation of measurement uncertainties of two-color pyrometry applied to optical diagnostics.

    PubMed

    Fu, Tairan; Cheng, Xiaofang; Yang, Zangjian

    2008-11-10

    We present a theoretical analysis of two-color pyrometry applied to optical diagnostics. A two-color pyrometer built with a single CCD is advantageous due to the simple system design. We evaluate the possibility and degree of ill-conditionness on the basis of measurement uncertainties for different measurement approaches of this two-color system. We classify measurement approaches. The corresponding ill-conditionness criterion is established. The greater the criterion value is, the worse the ill-conditioned degree of solution is. So, the optimum choice of measurement approach for the two-color system is achieved through intercomparison of the criterion values. Numerical examples are also given to illustrate this point. The theoretical analysis not only provides an effective way of evaluating different measurement approaches, but also may help us to better understand the influences that determine the choices between wavelength/waveband measurements and calibration/noncalibration modes for temperature and soot distribution. PMID:19002237

  6. Optical Image Analysis Applied to Pore Network Quantification of Sandstones Under Experimental CO2 Injection

    NASA Astrophysics Data System (ADS)

    Berrezueta, E.; González, L.; Ordóñez, B.; Luquot, L.; Quintana, L.; Gallastegui, G.; Martínez, R.; Olaya, P.; Breitner, D.

    2015-12-01

    This research aims to propose a protocol for pore network quantification in sandstones applying the Optical Image Analysis (OIA) procedure, which guarantees the measurement reproducibility and its reliability. Two geological formations of sandstone, located in Spain and potentially suitable for CO2 sequestration, were selected for this study: a) the Cretaceous Utrillas unit, at the base of the Cenozoic Duero Basin and b) a Triassic unit at the base of the Cenozoic Guadalquivir Basin. Sandstone samples were studied before and after the CO2 experimental injection using Optical and scanning electronic microscopy (SEM), while the quantification of petrographic changes was done with OIA. The first phase of the rersearch consisted on a detailed mineralogical and petrographic study of the sandstones (before and after CO2-injection), for which we observed thin sections. Later, the methodological and experimental processes of the investigation were focused on i) adjustment and calibration of OIA tools; ii) data acquisition protocol based on image capture with different polarization conditions (synchronized movement of polarizers), using 7 images of the same mineral scene (6 in crossed polarizer and 1 in parallel polarizer); and iii) automated identification and segmentation of pore in 2D mineral images, generating applications by executable macros. Finally, once the procedure protocols had been, the compiled data was interpreted through an automated approach and the qualitative petrography was carried out. The quantification of changes in the pore network through OIA (porosity increase ≈ 2.5%) has allowed corroborate the descriptions obtained by SEM and microscopic techniques, which consisted in an increase in the porosity when CO2 treatment occurs. Automated-image identification and quantification of minerals, pores and textures together with petrographic analysis can be applied to improve pore system characterization in sedimentary rocks. This research offers numerical

  7. A 10-year global gridded Aerosol Optical Thickness Reanalysis for climate and applied applications

    NASA Astrophysics Data System (ADS)

    Lynch, P.; Reid, J. S.; Zhang, J.; Westphal, D. L.; Campbell, J. R.; Curtis, C. A.; Hegg, D.; Hyer, E. J.; Sessions, W.; Shi, Y.; Turk, J.

    2013-12-01

    While standalone satellite and model aerosol products see wide utilization, there is a significant need of a best-available fused product on a regular grid for numerous climate and applied applications. Remote sensing and modeling technologies have now advanced to a point where aerosol data assimilation is an operational reality at numerous centers. It is inevitable that, like meteorological reanalyses, aerosol reanalyses will see heavy use in the near future. A first long term, 2003-2012 global 1x1 degree and 6-hourly aerosol optical thickness (AOT) reanalysis product has been generated. The goal of this effort is not only for climate applications, but to generate a dataset that can be used by the US Navy to understand operationally hindering aerosol events, aerosol impacts on numerical weather prediction, and application of electro-optical technologies. The reanalysis utilizes Navy Aerosol Analysis and Prediction System (NAAPS) at its core and assimilates quality controlled collection 5 Moderate Resolution Imaging Spectroradiometer (MODIS) AOD with minor corrections from Multi-angle Imaging SpectroRaditometer (MISR). A subset of this product includes Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) lidar assimilation since its launch in mid-2006. Surface aerosol sources, including dust and smoke, in the aerosol model have been regionally tuned so that fine and coarse mode AOTs best match those resolve by ground-based Aerosol Robotic Network (AERONET). The AOT difference between the model and satellite AOT is then used to adjust other aerosol processes, eg., sources, dry deposition, etc. Aerosol wet deposition is constrained with satellite-retrieved precipitation. The final AOT reanalysis is shown to exhibit good agreement with AERONET. Here we review the development of the reanalysis and consider issues particular to aerosol reanalyses that make them distinct from standard meteorological reanalyses. Considerations are also made for extending such work

  8. Marine organism repellent covering for protection of underwater objects and method of applying same

    SciTech Connect

    Fischer, K.J.

    1993-07-13

    A method is described of protecting the surface of underwater objects from fouling by growth of marine organisms thereon comprising the steps of: (A) applying a layer of waterproof adhesive to the surface to be protected; (B) applying to the waterproof adhesive layer, a deposit of cayenne pepper material; (C) applying a permeable layer of copper containing material to the adhesive layer in such a configuration as to leave certain areas of the outer surface of the adhesive layer exposed, through open portions of the permeable layer, to the ambient environment of the surface to be protected when such surface is submerged in water; (D) the permeable layer having the property of being a repellent to marine organisms.

  9. Methods of biomedical optical imaging: from subcellular structures to tissues and organs

    NASA Astrophysics Data System (ADS)

    Turchin, I. V.

    2016-05-01

    Optical bioimaging methods have a wide range of applications in the life sciences, most notably including the molecular resolution study of subcellular structures, small animal molecular imaging, and structural and functional clinical diagnostics of tissue layers and organs. We review fluorescent microscopy, fluorescent macroscopy, optical coherence tomography, optoacoustic tomography, and optical diffuse spectroscopy and tomography from the standpoint of physical fundamentals, applications, and progress.

  10. The Optics Institute of Southern California: organizing and implementing outreach effort

    NASA Astrophysics Data System (ADS)

    Silberman, Donn M.

    2003-10-01

    The Optics Institute of Southern California is organizing the local educational outreach effort. Working with local optics businesses, society chapters, science discovery centers, K-12, community college and university educators, and others from the global optics education and training community, the OISC is becoming a one-stop clearing house for a wide range of educational outreach activities.

  11. Optical Properties of Mixed Black Carbon, Inorganic and Secondary Organic Aerosols

    SciTech Connect

    Paulson, S E

    2012-05-30

    Summarizes the achievements of the project, which are divided into four areas: 1) Optical properties of secondary organic aerosols; 2) Development and of a polar nephelometer to measure aerosol optical properties and theoretical approaches to several optical analysis problems, 3) Studies on the accuracy of measurements of absorbing carbon by several methods, and 4) Environmental impacts of biodiesel.

  12. 3D Fluorescence Quenching of Dissolved Organic Matter Applying PARAFAC Treatment

    NASA Astrophysics Data System (ADS)

    Zhao, H. A.; Garnier, C.; Redon, R.; Mounier, S.

    2009-12-01

    Dissolved Organic Matter (DOM) exists everywhere in the environment. The studies of DOM in aquatic ecosystems enable us to obtain some information on its coming future and the importance of its role in the bio-geochemical processes. The fluorescence technique makes analyzes possible on the basis of the optical propriety of the DOM including its fluorophores composition and its complexation propriety face to face to certain metal (3). Recently for luminescence spectrum it is possible to determine the fluorescent component composition by the statistical analysis of parallel factor analysis (PARAFAC) with excitation-emission matrix (EEM) (1). The complexation propriety between DOM and metals is accessible by measuring the fluorescence quenching (FQ) functional to the metal additions. The EEMs in the FQ experiments contain maximal information as a whole of fluorescent DOM (FDOM). This work presents a quenching experience brought from copper ions titration onto a tropical river water sample (Rio Negro à Sao Gabriel Brésil) of 5mgC/L carbon concentration and 1.68 nano-molaire initial copper ions concentration (pH=4.5). A titration of copper ions (Cu(NO3)2) has been applied at total analytical concentration of copper-ions from 10-9M jusqu’à 10-3M. Fifty (50) EEM were obtained and gathered in order to analyze the FQ by PARAFAC. This statistic treatment permits us to extract 2 fluorescent components with the whole EEM: C1 (λex=225-235nm/λem=420-425nm) and C2 (λex=250-260nm and 345-355nm/λem=470-480nm) corresponding to the peaks already descript in the literature. Using the participation to the total fluorescence of these peaks, we have observed clearly that the fluorescence diminution was not uniform. The measurement of complexation propriety by this new approach gives the values following: K1=10E4.6; L1=10E-7.8 et K2=10E4.46; L2=10E-9 respectively the components C1 et C2. These results conform that determined in the literature by FQ. The utilisation of PARAFAC has

  13. Toward Investigating Optically Trapped Organic Aerosols with CARS Microspectroscopy

    NASA Astrophysics Data System (ADS)

    Voss, L. F.

    2009-12-01

    The Intergovernmental Panel on Climate Change notes the huge uncertainty in the effect that atmospheric aerosols play in determining overall global temperature, specifically in their ability to nucleate clouds. To better understand aerosol chemistry, the novel coupling of gradient force optical trapping with broad bandwidth coherent anti-Stokes Raman scattering (CARS) spectroscopy is being developed to study single particles suspended in air. Building on successful designs employed separately for the techniques, this hybrid technology will be used to explain how the oxidation of organic compounds changes the chemical and physical properties of aerosols. By trapping the particles, an individual aerosol can be studied for up to several days. Using a broad bandwidth pulse for one of the incident beams will result in a Raman vibrational spectrum from every laser pulse. Combined with signal enhancement due to resonance and coherence of nonlinear CARS spectroscopy, this technique will allow for acquisition of data on the millisecond time scale, facilitating the study of dynamic processes. This will provide insights on how aerosols react with and absorb species from the gas phase. These experiments will increase understanding of aerosol oxidation and growth mechanisms and the effects that aerosols have on our atmosphere and climate. Progress in efforts developing this novel technique to study model systems is presented.

  14. Determination of environmental organic pollutants with a portable optical immunosensor.

    PubMed

    Mauriz, E; Calle, A; Montoya, A; Lechuga, L M

    2006-04-15

    A portable surface plasmon resonance (SPR) optical biosensor device is described as a direct immunosensing system to determine organic pollutants in natural water samples. Monitoring of organochlorine (DDT), organophosphorus (chlorpyrifos) and carbamate (carbaryl) compounds within the concentration levels stipulated by the European legislation, can be accomplished using this immunosensor. The lowest limit of detection (LOD) was obtained for DDT, at 20 ng L(-1), whilst 50 ng L(-1) and 0.9 microg L(-1), were achieved for chlorpyrifos and carbaryl, respectively. Matrix effects were evaluated for the carbaryl immunoassay in different water types with detection limits within the range of carbaryl standard curves in distilled water (0.9-1.4 microg L(-1)). The covalent immobilization of the analyte derivative through an alkanethiol self-assembled monolayer (SAM) allowed the reusability of the sensor surface during more than 250 regeneration cycles. The quality of the regeneration was proved over a 1-month period of continuous working. The analysis time for a complete assay cycle, including regeneration, comprises 24 min. Our portable SPR-sensor system is already a market product, commercialized by the company SENSIA, SL. The size and electronic configuration of the device allow its portability and utilization on real contaminated locations.

  15. Integration of an organic photodetector onto a plastic optical fiber by means of spray coating technique.

    PubMed

    Binda, Maddalena; Natali, Dario; Iacchetti, Antonio; Sampietro, Marco

    2013-08-21

    A working prototype of integrated fiber/receiver system for optical data transmission is realized. The prototype is made by directly depositing an organic photodetector onto a plastic optical fiber. For the deposition of the organic layers, spray coating is successfully exploited. Operation over four orders of magnitude range of light intensities as well as photoresponse to pulsed stimulation are demonstrated.

  16. Racemization and the origin of optically active organic compounds in living organisms

    NASA Technical Reports Server (NTRS)

    Bada, J. L.; Miller, S. L.

    1987-01-01

    The organic compounds synthesized in prebiotic experiments are racemic mixtures. A number of proposals have been offered to explain how asymmetric organic compounds formed on the Earth before life arose, with the influence of chiral weak nuclear interactions being the most frequent proposal. This and other proposed asymmetric syntheses give only sight enantiomeric excess and any slight excess will be degraded by racemization. This applies particularly to amino acids where half-lives of 10(5)-10(6) years are to be expected at temperatures characteristic of the Earth's surface. Since the generation of chiral molecules could not have been a significant process under geological conditions, the origins of this asymmetry must have occurred at the time of the origin of life or shortly thereafter. It is possible that the compounds in the first living organisms were prochiral rather than chiral; this is unlikely for amino acids, but it is possible for the monomers of RNA-like molecules.

  17. Colored polydimethylsiloxane micropillar arrays for high throughput measurements of forces applied by genetic model organisms.

    PubMed

    Khare, Siddharth M; Awasthi, Anjali; Venkataraman, V; Koushika, Sandhya P

    2015-01-01

    Measuring forces applied by multi-cellular organisms is valuable in investigating biomechanics of their locomotion. Several technologies have been developed to measure such forces, for example, strain gauges, micro-machined sensors, and calibrated cantilevers. We introduce an innovative combination of techniques as a high throughput screening tool to assess forces applied by multiple genetic model organisms. First, we fabricated colored Polydimethylsiloxane (PDMS) micropillars where the color enhances contrast making it easier to detect and track pillar displacement driven by the organism. Second, we developed a semi-automated graphical user interface to analyze the images for pillar displacement, thus reducing the analysis time for each animal to minutes. The addition of color reduced the Young's modulus of PDMS. Therefore, the dye-PDMS composite was characterized using Yeoh's hyperelastic model and the pillars were calibrated using a silicon based force sensor. We used our device to measure forces exerted by wild type and mutant Caenorhabditis elegans moving on an agarose surface. Wild type C. elegans exert an average force of ∼1 μN on an individual pillar and a total average force of ∼7.68 μN. We show that the middle of C. elegans exerts more force than its extremities. We find that C. elegans mutants with defective body wall muscles apply significantly lower force on individual pillars, while mutants defective in sensing externally applied mechanical forces still apply the same average force per pillar compared to wild type animals. Average forces applied per pillar are independent of the length, diameter, or cuticle stiffness of the animal. We also used the device to measure, for the first time, forces applied by Drosophila melanogaster larvae. Peristaltic waves occurred at 0.4 Hz applying an average force of ∼1.58 μN on a single pillar. Our colored microfluidic device along with its displacement tracking software allows us to measure forces

  18. Colored polydimethylsiloxane micropillar arrays for high throughput measurements of forces applied by genetic model organisms

    PubMed Central

    Khare, Siddharth M.; Awasthi, Anjali; Venkataraman, V.; Koushika, Sandhya P.

    2015-01-01

    Measuring forces applied by multi-cellular organisms is valuable in investigating biomechanics of their locomotion. Several technologies have been developed to measure such forces, for example, strain gauges, micro-machined sensors, and calibrated cantilevers. We introduce an innovative combination of techniques as a high throughput screening tool to assess forces applied by multiple genetic model organisms. First, we fabricated colored Polydimethylsiloxane (PDMS) micropillars where the color enhances contrast making it easier to detect and track pillar displacement driven by the organism. Second, we developed a semi-automated graphical user interface to analyze the images for pillar displacement, thus reducing the analysis time for each animal to minutes. The addition of color reduced the Young's modulus of PDMS. Therefore, the dye-PDMS composite was characterized using Yeoh's hyperelastic model and the pillars were calibrated using a silicon based force sensor. We used our device to measure forces exerted by wild type and mutant Caenorhabditis elegans moving on an agarose surface. Wild type C. elegans exert an average force of ∼1 μN on an individual pillar and a total average force of ∼7.68 μN. We show that the middle of C. elegans exerts more force than its extremities. We find that C. elegans mutants with defective body wall muscles apply significantly lower force on individual pillars, while mutants defective in sensing externally applied mechanical forces still apply the same average force per pillar compared to wild type animals. Average forces applied per pillar are independent of the length, diameter, or cuticle stiffness of the animal. We also used the device to measure, for the first time, forces applied by Drosophila melanogaster larvae. Peristaltic waves occurred at 0.4 Hz applying an average force of ∼1.58 μN on a single pillar. Our colored microfluidic device along with its displacement tracking software allows us to measure forces

  19. The Relationship Between Dissolved Organic Matter Composition and Organic Matter Optical Properties in Freshwaters

    NASA Astrophysics Data System (ADS)

    Aiken, G.; Spencer, R. G.; Butler, K.

    2010-12-01

    Dissolved organic matter (DOM) chemistry and flux are potentially useful, albeit, underutilized, indicators of watershed characteristics, climate influences on watershed hydrology and soils, and changes associated with resource management. Source materials, watershed geochemistry, oxidative processes and hydrology exert strong influences on the nature and reactivity of DOM in aquatic systems. The molecules that comprise DOM, in turn, control a number of environmental processes important for ecosystem function including light penetration and photochemistry, microbial activity, mineral dissolution/precipitation, and the transport and reactivity of hydrophobic compounds and metals (e.g. Hg). In particular, aromatic molecules derived from higher plants exert strong controls on aquatic photochemistry, and on the transport and biogeochemistry of metals. Assessment of DOM composition and transport, therefore, can provide a basis for understanding watershed processes and biogeochemistry of rivers and streams. Here we present results of multi-year studies designed to assess the seasonal and spatial variability of DOM quantity and quality for 57 North American Rivers. DOM concentrations and composition, based on DOM fractionation on XAD resins, ultraviolet (UV)/visible absorption and fluorescence spectroscopic analyses, and specific compound analyses, varied greatly both between sites and seasonally within a given site. DOM in these rivers exhibited a wide range of concentration (<80 to >4000 µM C* L-1) and specific ultra-violet absorbance at 254 nm (SUVA254) (0.6 to 5 L *mg C-1 *m-1), an optical measurement that is an indicator of aromatic carbon content. In almost all systems, UV absorbance measured at specific wavelengths (e.g. 254 nm) correlated strongly with DOM and hydrophobic organic acid (HPOA) content (aquatic humic substances). The relationships between dissolved organic carbon (DOC) concentration and absorbance for the range of systems were quite variable due to

  20. Developing a framework for applying disassembly planning and demanufacturing modeling to organic processing waste streams

    NASA Astrophysics Data System (ADS)

    Rosentrater, Kurt A.; Tang, Ying

    2005-11-01

    Alternative disposal methods for food and other organic manufacturing waste streams are increasingly being investigated. Direct shipping, blending, extrusion, pelleting, and drying are commonly used to produce finished human food, animal feed, industrial products, and components ready for further manufacture. This paper discusses a new initiative whose goal is to develop a computer model based on analytical methods used for disassembly planning and demanufacturing modeling, but applied to organic processing waste streams. Upon completion, the simulation model discussed here will be used to analyze various liquid, sludge, and solid byproduct streams in order to determine optimal reprocessing avenues for specific manufacturing firms.

  1. Performance evaluation of gratings applied by genetic algorithm for the real-time optical interconnection

    NASA Astrophysics Data System (ADS)

    Yoon, Jin-Seon; Kim, Nam; Suh, HoHyung; Jeon, Seok Hee

    2000-03-01

    In this paper, gratings to apply for the optical interconnection are designed using a genetic algorithm (GA) for a robust and efficient schema. The real-time optical interconnection system architecture is composed with LC-SLM, CCD array detector, IBM-PC, He-Ne laser, and Fourier transform lens. A pixelated binary phase grating is displayed on LC-SLM and could interconnect incoming beams to desired output spots freely by real-time. So as to adapt a GA for finding near globally-cost solutions, a chromosome is coded as a binary integer of length 32 X 32, the stochastic tournament method for decreasing the stochastic sampling error is performed, and a single-point crossover having 16 X 16 block size is used. The characteristics on the several parameters are analyzed in the desired grating design. Firstly, as the analysis of the effect on the probability of crossover, a designed grating when the probability of crossover is 0.75 has a 74.7[%] high diffraction efficiency and a 1.73 X 10-1 uniformity quantitatively, where the probability of mutation is 0.001 and the population size is 300. Secondly, on the probability of mutation, a designed grating when the probability of mutation is 0.001 has a 74.4[%] high efficiency and a 1.61 X 10-1 uniformity quantitatively, where the probability of crossover is 1.0 and the population size is 300. Thirdly, on the population size, a designed grating when the population size is 300 and the generation is 400 has above 74[%] diffraction efficiency, where the probability of mutation is 0.001 and the probability of crossover is 1.0.

  2. Device applications and structural and optical properties of Indigo - A biodegradable, low-cost organic semiconductor

    NASA Astrophysics Data System (ADS)

    Wang, Zhengjun; Pisane, Kelly L.; Sierros, Konstantinos; Seehra, Mohindar S.; Korakakis, Dimitris

    2015-03-01

    Currently, memory devices based on organic materials are attracting great attention due to their simplicity in device structure, mechanical flexibility, potential for scalability, low-cost potential, low-power operation, and large capacity for data storage. In a recent paper from our group, Indigo-based nonvolatile organic write-once-read-many-times (WORM) memory device, consisting of a 100nm layer of indigo sandwiched between an indium tin oxide (ITO) cathode and an Al anode, has been reported. This device is found to be at its low resistance state (ON state) and can be switched to high resistance state (OFF state) by applying a positive bias with ON/OFF current ratio of the device being up to 1.02 × e6. A summary of these results along with the structural and optical properties of indigo powder will be reported. Analysis of x-ray diffraction shows a monoclinic structure with lattice parameters a(b)[c] = 0.924(0.577)[0.1222]nm and β =117° . Optical absorption shows a band edge at 1.70 eV with peak of absorption occurring at 1.90 eV. These results will be interpreted in terms of the HOMO-LUMO bands of Indigo.

  3. Intense laser effects on the optical properties of asymmetric GaAs double quantum dots under applied electric field

    NASA Astrophysics Data System (ADS)

    Bejan, Doina; Niculescu, Ecaterina Cornelia

    2016-06-01

    We investigated the combined effects of a non-resonant intense laser field and a static electric field on the electronic structure and the nonlinear optical properties (absorption, optical rectification) of a GaAs asymmetric double quantum dot under a strong probe field excitation. The calculations were performed within the compact density-matrix formalism under steady state conditions using the effective mass approximation. Our results show that: (i) the electronic structure and optical properties are sensitive to the dressed potential; (ii) under applied electric fields, an increase of the laser intensity induces a redshift of the optical absorption and rectification spectra; (iii) the augment of the electric field strength leads to a blueshift of the spectra; (iv) for high electric fields the optical spectra show a shoulder-like feature, related with the occurrence of an anti-crossing between the two first excited levels.

  4. Accelerated Optical Projection Tomography Applied to In Vivo Imaging of Zebrafish

    PubMed Central

    Correia, Teresa; Yin, Jun; Ramel, Marie-Christine; Andrews, Natalie; Katan, Matilda; Bugeon, Laurence; Dallman, Margaret J.; McGinty, James; Frankel, Paul; French, Paul M. W.; Arridge, Simon

    2015-01-01

    Optical projection tomography (OPT) provides a non-invasive 3-D imaging modality that can be applied to longitudinal studies of live disease models, including in zebrafish. Current limitations include the requirement of a minimum number of angular projections for reconstruction of reasonable OPT images using filtered back projection (FBP), which is typically several hundred, leading to acquisition times of several minutes. It is highly desirable to decrease the number of required angular projections to decrease both the total acquisition time and the light dose to the sample. This is particularly important to enable longitudinal studies, which involve measurements of the same fish at different time points. In this work, we demonstrate that the use of an iterative algorithm to reconstruct sparsely sampled OPT data sets can provide useful 3-D images with 50 or fewer projections, thereby significantly decreasing the minimum acquisition time and light dose while maintaining image quality. A transgenic zebrafish embryo with fluorescent labelling of the vasculature was imaged to acquire densely sampled (800 projections) and under-sampled data sets of transmitted and fluorescence projection images. The under-sampled OPT data sets were reconstructed using an iterative total variation-based image reconstruction algorithm and compared against FBP reconstructions of the densely sampled data sets. To illustrate the potential for quantitative analysis following rapid OPT data acquisition, a Hessian-based method was applied to automatically segment the reconstructed images to select the vasculature network. Results showed that 3-D images of the zebrafish embryo and its vasculature of sufficient visual quality for quantitative analysis can be reconstructed using the iterative algorithm from only 32 projections—achieving up to 28 times improvement in imaging speed and leading to total acquisition times of a few seconds. PMID:26308086

  5. Optical microsystem for analysis of diffuse reflectance and fluorescence signals applied to early gastrointestinal cancer detection.

    PubMed

    Pimenta, Sara; Castanheira, Elisabete M S; Minas, Graça

    2015-01-30

    The detection of cancer at its earliest stage is crucial in order to increase the probability of a successful treatment. Optical techniques, specifically diffuse reflectance and fluorescence, may considerably improve the ability to detect pre-cancerous lesions. These techniques have high sensitivity to some biomarkers present on the tissues, providing morphological and biochemical information of normal and diseased tissue. The development of a chip sized spectroscopy microsystem, based on these techniques, will greatly improve the early diagnosis of gastrointestinal cancers. The main innovation is the detection of the spectroscopic signals using only few, but representative, spectral bands allowing for miniaturization. This paper presents the mathematical models, its validation and analysis for retrieving data of the measured spectroscopic signals. These models were applied to a set of phantoms clearly representative of gastrointestinal tissues, leading to a more accurate diagnostic by a pathologist. Moreover, it was demonstrated that the models can use the reconstructed spectroscopic signals based only on its extraction on those specific spectral bands. As a result, the viability of the spectroscopy microsystem implementation was proved.

  6. Optical conductivity and optical effective mass in a high-mobility organic semiconductor: Implications for the nature of charge transport

    NASA Astrophysics Data System (ADS)

    Li, Yuan; Yi, Yuanping; Coropceanu, Veaceslav; Brédas, Jean-Luc

    2014-12-01

    We present a multiscale modeling of the infrared optical properties of the rubrene crystal. The results are in very good agreement with the experimental data that point to nonmonotonic features in the optical conductivity spectrum and small optical effective masses. We find that, in the static-disorder approximation, the nonlocal electron-phonon interactions stemming from low-frequency lattice vibrations can decrease the optical effective masses and lead to lighter quasiparticles. On the other hand, the charge-transport and infrared optical properties of the rubrene crystal at room temperature are demonstrated to be governed by localized carriers driven by inherent thermal disorders. Our findings underline that the presence of apparently light carriers in high-mobility organic semiconductors does not necessarily imply bandlike transport.

  7. Low-cost organic pulse sources for integrated optical modules

    NASA Astrophysics Data System (ADS)

    Hiltunen, Jussi A.; Rantala, Juha T.

    2001-05-01

    The transient and steady state performance of organic light- emitting devices (OLEDs) has been investigated with a view towards suitability for pulse sources. The rise and fall times of the electroluminescence of the different structures and materials were afforded special attention. The tested devices cover single and multi-layer structures with different layer thicknesses. Both molecular and polymeric- based devices were tested. Molecular materials used in the OLEDs were N, N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine (TPD) as a hole transporter, tris-(8-hydroxyquinolate) aluminum (Alq3) as an electron transporter/emitter and 4,7-diphenyl-1,10-phenanthroline (BCP) as a hole blocking material. Poly)2-methoxy, 5-(2'-ethyl-hexoxy)-1,4- phenylene-vinylene) (MEH-PPV) and poly(3,4- ethylenedioxythiophene)/poly(styrene) (PEDOT/PSS) were the polymeric materials used in the devices. The effect of the driving voltage on the response time and the current density in transients was under investigation. In addition, changes in the response time were studied, when the bias voltage was applied.

  8. Statistical Track-Before-Detect Methods Applied to Faint Optical Observations of Resident Space Objects

    NASA Astrophysics Data System (ADS)

    Fujimoto, K.; Yanagisawa, T.; Uetsuhara, M.

    Automated detection and tracking of faint objects in optical, or bearing-only, sensor imagery is a topic of immense interest in space surveillance. Robust methods in this realm will lead to better space situational awareness (SSA) while reducing the cost of sensors and optics. They are especially relevant in the search for high area-to-mass ratio (HAMR) objects, as their apparent brightness can change significantly over time. A track-before-detect (TBD) approach has been shown to be suitable for faint, low signal-to-noise ratio (SNR) images of resident space objects (RSOs). TBD does not rely upon the extraction of feature points within the image based on some thresholding criteria, but rather directly takes as input the intensity information from the image file. Not only is all of the available information from the image used, TBD avoids the computational intractability of the conventional feature-based line detection (i.e., "string of pearls") approach to track detection for low SNR data. Implementation of TBD rooted in finite set statistics (FISST) theory has been proposed recently by Vo, et al. Compared to other TBD methods applied so far to SSA, such as the stacking method or multi-pass multi-period denoising, the FISST approach is statistically rigorous and has been shown to be more computationally efficient, thus paving the path toward on-line processing. In this paper, we intend to apply a multi-Bernoulli filter to actual CCD imagery of RSOs. The multi-Bernoulli filter can explicitly account for the birth and death of multiple targets in a measurement arc. TBD is achieved via a sequential Monte Carlo implementation. Preliminary results with simulated single-target data indicate that a Bernoulli filter can successfully track and detect objects with measurement SNR as low as 2.4. Although the advent of fast-cadence scientific CMOS sensors have made the automation of faint object detection a realistic goal, it is nonetheless a difficult goal, as measurements

  9. Synthesis, structural, optical and thermal studies of an organic nonlinear optical 4-aminopyridinium maleate single crystal

    NASA Astrophysics Data System (ADS)

    Pandi, P.; Peramaiyan, G.; Kumar, M. Krishna; Kumar, R. Mohan; Jayavel, R.

    2012-03-01

    Synthesis and growth of a novel organic nonlinear optical (NLO) crystal of 4-aminopyridinium maleate (4APM) in larger size by the slow evaporation solution growth technique are reported. Single crystal and powder X-ray diffraction analyses reveal that 4APM crystallizes in monoclinic system with space group P21 with cell parameters a = 8.140(4) Å, b = 5.457(5) Å, c = 10.926(10) Å and volume = 481.4(7) Å3. The grown crystal has been characterized by Fourier transform infrared and UV-visible spectral analyses. Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) have been carried out to study its thermal properties. Dielectric measurements have been carried out to study the distribution of charges within the crystal. The mechanical strength of the crystal has been studied by using Vickers' microhardness test. The etching studies have been carried out on the grown crystal. The Kurtz and Perry powder SHG technique confirms the NLO property of the grown crystal and the SHG efficiency of 4APM was found to be 4.8 times greater than that of KDP crystal.

  10. Evaluation of topically applied copper(II) oxide nanoparticle cytotoxicity in human skin organ culture.

    PubMed

    Cohen, Dror; Soroka, Yoram; Ma'or, Zeev; Oron, Miriam; Portugal-Cohen, Meital; Brégégère, François Menahem; Berhanu, Deborah; Valsami-Jones, Eugenia; Hai, Noam; Milner, Yoram

    2013-02-01

    The increasing use of nano-sized materials in our environment, and in many consumer products, dictates new safety concerns. In particular, adequate experimental models are needed to evaluate skin toxicity of metal oxide ions, commonly found in cosmetic and dermatologic preparations. We have addressed the biological effects of topically applied copper oxide (CuO) nanoparticles in human skin organ cultures, using light and electron microscopy, and biochemical tests. Nanoparticles were more toxic than micro-sized particles, and their effects were stronger when supplied in growth medium than in topical application. Still topically applied CuO nanoparticles induced inflammatory cytokine secretion and necrosis, especially in epidermis deprived of its protective cornea. Since nanoparticle penetration was not seen, we propose that they may adhere to skin surface, react with the local acidic environment, and generate soluble ions that make their way to inner sites. This work illustrates the abilities of skin organ culture to evaluate the biological effects of topically-applied materials on skin in vitro. PMID:22954531

  11. Self-aligned optical couplings by self-organized waveguides toward luminescent targets in organic/inorganic hybrid materials.

    PubMed

    Yoshimura, Tetsuzo; Iida, Makoto; Nawata, Hideyuki

    2014-06-15

    Self-organization of optical waveguides is observed between two opposed optical fibers placed in a photosensitive organic/inorganic hybrid material, Sunconnect. A luminescent target containing coumarin 481 was deposited onto the edge of one of the two fibers at the core. When a 448-nm write beam was introduced from the other fiber, the write beam and the luminescence from the photoexcited target increased the refractive index of Sunconnect to induce self-focusing. Traces of waveguides were seen to grow from the cores of both fibers and merged into a single self-aligned optical coupling between the fibers. This optical solder functionality enabled increases in both coupling efficiency and tolerance to lateral misalignment of the fibers.

  12. Self-aligned optical couplings by self-organized waveguides toward luminescent targets in organic/inorganic hybrid materials.

    PubMed

    Yoshimura, Tetsuzo; Iida, Makoto; Nawata, Hideyuki

    2014-06-15

    Self-organization of optical waveguides is observed between two opposed optical fibers placed in a photosensitive organic/inorganic hybrid material, Sunconnect. A luminescent target containing coumarin 481 was deposited onto the edge of one of the two fibers at the core. When a 448-nm write beam was introduced from the other fiber, the write beam and the luminescence from the photoexcited target increased the refractive index of Sunconnect to induce self-focusing. Traces of waveguides were seen to grow from the cores of both fibers and merged into a single self-aligned optical coupling between the fibers. This optical solder functionality enabled increases in both coupling efficiency and tolerance to lateral misalignment of the fibers. PMID:24978520

  13. The Electric and Optical Properties of Doped Small Molecular Organic Light-Emitting Devices

    SciTech Connect

    Kwang-Ohk Cheon

    2003-08-05

    Organic light-emitting devices (OLEDs) constitute a new and exciting emissive display technology. In general, the basic OLED structure consists of a stack of fluorescent organic layers sandwiched between a transparent conducting-anode and metallic cathode. When an appropriate bias is applied to the device, holes are injected from the anode and electrons from the cathode; some of the recombination events between the holes and electrons result in electroluminescence (EL). Until now, most of the efforts in developing OLEDs have focused on display applications, hence on devices within the visible range. However some organic devices have been developed for ultraviolet or infrared emission. Various aspects of the device physics of doped small molecular OLEDs were described and discussed. The doping layer thickness and concentration were varied systematically to study their effects on device performances, energy transfer, and turn-off dynamics. Low-energy-gap DCM2 guest molecules, in either {alpha}-NPD or DPVBi host layers, are optically efficient fluorophores but also generate deep carrier trap-sites. Since their traps reduce the carrier mobility, the current density decreases with increased doping concentration. At the same time, due to efficient energy transfer, the quantum efficiency of the devices is improved by light doping or thin doping thickness, in comparison with the undoped neat devices. However, heavy doping induces concentration quenching effects. Thus, the doping concentration and doping thickness may be optimized for best performance.

  14. Synthesis and evaluation of sensitizer drug photorelease chemistry: Micro-optic method applied to singlet oxygen generation and drug delivery

    NASA Astrophysics Data System (ADS)

    Ghosh, Goutam

    This thesis summarizes a new micro-optic method for singlet oxygen generation and sensitizer drug delivery, which include i) synthesis and evaluation of a first generation device for drug delivery from native and fluorinated silica probe tips, ii) synthesis of PEG conjugated sensitizers to study phototoxicity in ovarian cancer cells, and iii) synthesis and evaluation of tris-PEGylated chlorin conjugated fluorinated silica for its future integration into the device to use as a 2nd generation device. A first generation micro-optic device was developed that works by sparging O2 gas and light generating cytotoxic singlet oxygen that cleaves the covalently attached drug (sensitizer) from the probe tip at the distal end of the fiber. The aim is to develop a 1st and 2nd generation device for site specific delivery of photosensitizer and singlet oxygen to overcome the challenges involved in systemic administration of the sensitizer. Synthesis and evaluation of drug (pheophorbide-a) delivery applying micro-optic method from native and fluorinated silica probe tip was achieved. The amount of sensitizer photocleavage depends on the loading level of sensitizer onto the probe tips. We also found that photorelease efficiency depends on the nature of the solvents where sensitizer is photocleaved. For example, no photorelease was observed in an aqueous solvent where sensitizer remained adsorbed to the native silica probe-tip. But, 90% photocleavage was obtained in octanol. A significant amount of photosensitizer (formate ester of pyropheophorbide- a) diffused into the liposome when photocleavage study was carried out in liposome. Substantial increase of photorelease was observed in organic solvent when pyropheophorbide-a (PPa) sensitizer was attached to the partially fluorinated porous Vycor glass. We also explored sensitizer photorelease from the fluorinated silica surface at various temperatures and we found that autocatalytic photorelease happened at room temperature and above

  15. New method to determine the optical rotatory dispersion of inorganic crystals applied to some samples of Carpathian Quartz.

    PubMed

    Dimitriu, Dan Gheorghe; Dorohoi, Dana Ortansa

    2014-10-15

    A new method to determine the optical rotatory dispersion (ORD) in the visible range, based on a channeled spectrum obtained with a uniax inorganic crystal introduced between two crossed polarizers with its optical axis parallel to the light propagation direction is detailed in this paper. When the studied inorganic crystals are transparent, this method permits the estimation of the optical rotatory dispersion in the visible range, for which the cheap polarizers are available. The speed of the measurements is very high, because the estimations are made from the channeled spectrum obtained for a single arrangement of the optical components. By using a computer, ORD is quickly determined for the visible range. The results obtained by this method for some Carpathian Quartz samples are consistent with those from literature. The proposed method can be also applied in UV and IR spectral ranges, when the anisotropic layers are transparent and the linearly polarized radiations can be obtained.

  16. A neuro-evolutive technique applied for predicting the liquid crystalline property of some organic compounds

    NASA Astrophysics Data System (ADS)

    Drăgoi, Elena-Niculina; Curteanu, Silvia; Lisa, Cătălin

    2012-10-01

    A simple self-adaptive version of the differential evolution algorithm was applied for simultaneous architectural and parametric optimization of feed-forward neural networks, used to classify the crystalline liquid property of a series of organic compounds. The developed optimization methodology was called self-adaptive differential evolution neural network (SADE-NN) and has the following characteristics: the base vector used is chosen as the best individual in the current population, two differential terms participate in the mutation process, the crossover type is binomial, a simple self-adaptive mechanism is employed to determine the near-optimal control parameters of the algorithm, and the integration of the neural network into the differential evolution algorithm is performed using a direct encoding scheme. It was found that a network with one hidden layer is able to make accurate predictions, indicating that the proposed methodology is efficient and, owing to its flexibility, it can be applied to a large range of problems.

  17. Biosafety assessment protocols for new organisms in New Zealand: Can they apply internationally to emerging technologies?

    SciTech Connect

    Barratt, B.I.P. . E-mail: barbara.barratt@agresearch.co.nz; Moeed, A.; Malone, L.A.

    2006-05-15

    An analysis of established biosafety protocols for release into the environment of exotic plants and biological control agents for weeds and arthropod pests has been carried out to determine whether such protocols can be applied to relatively new and emerging technologies intended for the primary production industries, such as transgenic plants. Example case studies are described to indicate the scope of issues considered by regulators who make decisions on new organism releases. No transgenic plants have been released to date in New Zealand, but two field test approvals are described as examples. An analysis of the biosafety protocols has shown that, while many of the risk criteria considered for decision-making by regulators are similar for all new organisms, a case-by-case examination of risks and potential impacts is required in order to fully assess risk. The value of post-release monitoring and validation of decisions made by regulators is emphasised.

  18. Wavelet image processing applied to optical and digital holography: past achievements and future challenges

    NASA Astrophysics Data System (ADS)

    Jones, Katharine J.

    2005-08-01

    The link between wavelets and optics goes back to the work of Dennis Gabor who both invented holography and developed Gabor decompositions. Holography involves 3-D images. Gabor decompositions involves 1-D signals. Gabor decompositions are the predecessors of wavelets. Wavelet image processing of holography, both optical holography and digital holography, will be examined with respect to past achievements and future challenges.

  19. Huygens-Feynman-Fresnel principle as the basis of applied optics.

    PubMed

    Gitin, Andrey V

    2013-11-01

    The main relationships of wave optics are derived from a combination of the Huygens-Fresnel principle and the Feynman integral over all paths. The stationary-phase approximation of the wave relations gives the correspondent relations from the point of view of geometrical optics.

  20. Huygens-Feynman-Fresnel principle as the basis of applied optics.

    PubMed

    Gitin, Andrey V

    2013-11-01

    The main relationships of wave optics are derived from a combination of the Huygens-Fresnel principle and the Feynman integral over all paths. The stationary-phase approximation of the wave relations gives the correspondent relations from the point of view of geometrical optics. PMID:24216640

  1. Pu-239 organ specific dosimetric model applied to non-human biota

    NASA Astrophysics Data System (ADS)

    Kaspar, Matthew Jason

    There are few locations throughout the world, like the Maralinga nuclear test site located in south western Australia, where sufficient plutonium contaminate concentration levels exist that they can be utilized for studies of the long-term radionuclide accumulation in non-human biota. The information obtained will be useful for the potential human users of the site while also keeping with international efforts to better understand doses to non-human biota. In particular, this study focuses primarily on a rabbit sample set collected from the population located within the site. Our approach is intended to employ the same dose and dose rate methods selected by the International Commission on Radiological Protection and adapted by the scientific community for similar research questions. These models rely on a series of simplifying assumptions on biota and their geometry; in particular; organisms are treated as spherical and ellipsoidal representations displaying the animal mass and volume. These simplifications assume homogeneity of all animal tissues. In collaborative efforts between Colorado State University and the Australian Nuclear Science and Technology Organisation (ANSTO), we are expanding current knowledge on radionuclide accumulation in specific organs causing organ-specific dose rates, such as Pu-239 accumulating in bone, liver, and lungs. Organ-specific dose models have been developed for humans; however, little has been developed for the dose assessment to biota, in particular rabbits. This study will determine if it is scientifically valid to use standard software, in particular ERICA Tool, as a means to determine organ-specific dosimetry due to Pu-239 accumulation in organs. ERICA Tool is normally applied to whole organisms as a means to determine radiological risk to whole ecosystems. We will focus on the aquatic model within ERICA Tool, as animal organs, like aquatic organisms, can be assumed to lie within an infinite uniform medium. This model would

  2. Prediction of nonlinear optical properties of large organic molecules

    NASA Technical Reports Server (NTRS)

    Cardelino, Beatriz H.

    1992-01-01

    The preparation of materials with large nonlinear responses usually requires involved synthetic processes. Thus, it is very advantageous for materials scientists to have a means of predicting nonlinear optical properties. The prediction of nonlinear optical properties has to be addressed first at the molecular level and then as bulk material. For relatively large molecules, two types of calculations may be used, which are the sum-over-states and the finite-field approach. The finite-field method was selected for this research, because this approach is better suited for larger molecules.

  3. Effect of the condensation of hybrid organic-inorganic sol-gel materials on the optical properties of tripan blue

    NASA Astrophysics Data System (ADS)

    Hicks, Craig; Morshed, Muhammad; Melia, Garrett; Barton, Killian; Duffy, Brendan; Oubaha, Mohamed

    2015-09-01

    The work reported in this paper highlights the effect of sol-gel structures on the optical properties of a typical organic dye (Trypan Blue, TB). Three transition-metal-based hybrid sol-gel materials with different structures and morphologies were developed and characterised by TEM. The optical properties of TB were investigated by incorporating it in the different sol-gel materials and the UV-Visible spectra recorded in both liquid and solid state, in thin-coatings cured at temperatures in the range 100-150 °C. These studies revealed two relevant results. First, the sol-gel morphology plays a critical role in the optical properties of the dye. The effect of the sol-gel host matrix on the optical properties of the dye is attributed to the steric hindrance of the nanostructures, themselves intimately dependant on the reactivity of the transition metal. For instance, the less condensed system showed the highest reactivity with the dye, while the more condensed system exhibited limited interaction with the dye, symbolised by a significant change or quasi-unchanged UV-Visible spectra, respectively. It is also shown that the increase of the condensation degree of the sol-gel coatings by heat-curing can dramatically alter the optical properties of the dye especially for the most condensed sol-gel systems. This has been attributed to proximity effects enabled by the further increase of the materials densities. The results reported here aim to provide a better understanding of how material formulations can influence the optical properties of organic dyes and suggest that the structure of the host matrix along with the applied curing process have to be fully considered and assessed in the choice of organic dyes for a given application.

  4. Optical properties of thin gold films applied to Schottky barrier solar cells

    NASA Technical Reports Server (NTRS)

    YEH Y. M.

    1974-01-01

    The Schottky barrier solar cell is considered a possible candidate for converting solar to electrical energy both for space and terrestrial applications. Knowledge of the optical constants of the ultrathin metal film used in the cell is essential for analyzing and designing higher efficiency Schottky barrier cells. The optical constants of 7.5 -nm (75-A) gold films on gallium arsenide have been obtained. In addition, the absolute collection efficiency of Schottky barrier solar cells has been determined from measured spectral response and optical constants of the gold film.

  5. Photographic-Based Optical Evaluation of Tissues and Biomaterials Used for Corneal Surface Repair: A New Easy-Applied Method

    PubMed Central

    Gonzalez-Andrades, Miguel; Cardona, Juan de la Cruz; Ionescu, Ana Maria; Mosse, Charles A.; Brown, Robert A.

    2015-01-01

    Purpose Tissues and biomaterials used for corneal surface repair require fulfilling specific optical standards prior to implantation in the patient. However, there is not a feasible evaluation method to be applied in clinical or Good Manufacturing Practice settings. In this study, we describe and assess an innovative easy-applied photographic-based method (PBM) for measuring functional optical blurring and transparency in corneal surface grafts. Methods Plastic compressed collagen scaffolds (PCCS) and multilayered amniotic membranes (AM) samples were optically and histologically evaluated. Transparency and image blurring measures were obtained by PBM, analyzing photographic images of a standardized band pattern taken through the samples. These measures were compared and correlated to those obtained applying the Inverse Adding-Doubling (IAD) technique, which is the gold standard method. Results All the samples used for optical evaluation by PBM or IAD were histological suitable. PCCS samples presented transmittance values higher than 60%, values that increased with increasing wavelength as determined by IAD. The PBM indicated that PCCS had a transparency ratio (TR) value of 80.3±2.8%, with a blurring index (BI) of 50.6±4.2%. TR and BI obtained from the PBM showed a high correlation (ρ>|0.6|) with the diffuse transmittance and the diffuse reflectance, both determined using the IAD (p<0.005). The AM optical properties showed that there was a largely linear relationship between the blurring and the number of amnion layers, with more layers producing greater blurring. Conclusions This innovative proposed method represents an easy-applied technique for evaluating transparency and blurriness of tissues and biomaterials used for corneal surface repair. PMID:26566050

  6. Image processing techniques applied to the detection of optic disk: a comparison

    NASA Astrophysics Data System (ADS)

    Kumari, Vijaya V.; Narayanan, Suriya N.

    2010-02-01

    In retinal image analysis, the detection of optic disk is of paramount importance. It facilitates the tracking of various anatomical features and also in the extraction of exudates, drusens etc., present in the retina of human eye. The health of retina crumbles with age in some people during the presence of exudates causing Diabetic Retinopathy. The existence of exudates increases the risk for age related macular Degeneration (AMRD) and it is the leading cause for blindness in people above the age of 50.A prompt diagnosis when the disease is at the early stage can help to prevent irreversible damages to the diabetic eye. Screening to detect diabetic retinopathy helps to prevent the visual loss. The optic disk detection is the rudimentary requirement for the screening. In this paper few methods for optic disk detection were compared which uses both the properties of optic disk and model based approaches. They are uniquely used to give accurate results in the retinal images.

  7. Gerchberg-Saxton algorithm applied to a translational-variant optical setup.

    PubMed

    Amézquita-Orozco, Ricardo; Mejía-Barbosa, Yobani

    2013-08-12

    The standard Gerchberg-Saxton (GS) algorithm is normally used to find the phase (measured on two different parallel planes) of a propagating optical field (usually far-field propagation), given that the irradiance information on those planes is known. This is mostly used to calculate the modulation function of a phase mask so that when illuminated by a plane wave, it produces a known far-field irradiance distribution, or the equivalent, to calculate the phase mask to be used in a Fourier optical system so the desired pattern is obtained on the image plane. There are some extensions of the GS algorithm that can be used when the transformations that describe the optical setup are non-unitary, for example the Yang-Gu algorithm, but these are usually demonstrated using nonunitary translational-invariant optical systems. In this work a practical approach to use the GS algorithm is presented, where raytracing together with the Huygens-Fresnel principle are used to obtain the transformations that describe the optical system, so the calculation can be made when the field is propagated through a translational-variant optical system (TVOS) of arbitrary complexity. Some numerical results are shown for a system where a microscope objective composed by 5 lenses is used. PMID:23938827

  8. Adaptive optics applied to coherent anti-Stokes Raman scattering microscopy

    NASA Astrophysics Data System (ADS)

    Girkin, John M.; Poland, Simon P.; Wright, Amanda J.; Freudiger, Christian; Evans, Conor L.; Xie, X. Sunney

    2008-02-01

    We report on the use of adaptive optics in coherent anti-Stokes Raman scattering microscopy (CARS) to improve the image brightness and quality at increased optical penetration depths in biological material. The principle of the technique is to shape the incoming wavefront in such a way that it counteracts the aberrations introduced by imperfect optics and the varying refractive index of the sample. In recent years adaptive optics have been implemented in multiphoton and confocal microscopy. CARS microscopy is proving to be a powerful tool for non-invasive and label-free biomedical imaging with vibrational contrast. As the contrast mechanism is based on a 3 rd order non-linear optical process, it is highly susceptible to aberrations, thus CARS signals are commonly lost beyond the depth of ~100 μm in tissue. We demonstrate the combination of adaptive optics and CARS microscopy for deep-tissue imaging using a deformable membrane mirror. A random search optimization algorithm using the CARS intensity as the figure of merit determined the correct mirror-shape in order to correct for the aberrations. We highlight two different methods of implementation, using a look up table technique and by performing the optimizing in situ. We demonstrate a significant increase in brightness and image quality in an agarose/polystyrene-bead sample and white chicken muscle, pushing the penetration depth beyond 200 μm.

  9. Dynamic and reversible organization of zeolite L crystals induced by holographic optical tweezers.

    PubMed

    Woerdemann, Mike; Gläsener, Stefan; Hörner, Florian; Devaux, André; De Cola, Luisa; Denz, Cornelia

    2010-10-01

    Organization and patterning of zeolite L crystals with their unique properties such as their one-dimensional nano channel system is of highest topical interest with various applications in many areas of science. We demonstrate full three-dimensional optical control of single zeolite L crystals and for the first time fully reversible, dynamic organization of a multitude of individually controlled zeolite L crystals.

  10. Segment Orientation and Optical Birefringence of Amorphous Polymers Under Tensile Deformation: Novel Computational Method applied to Different Glassy Polycarbonates

    NASA Astrophysics Data System (ADS)

    Natarajan, Upendra; Sulatha, M. S.

    2005-03-01

    Orientation dependent optical properties of Bisphenol A polycarbonate and two aliphatic substituted polycarbonates in glassy phase have been studied by atomistic modeling using molecular mechanics simulations under tensile deformation. Probability distributions and orientation functions show that phenylene rings and carbonate groups vectors along the main chain orient towards stretching direction following deformation. Interchain packing of rings and carbonates become ordered with strain. Efficient computational approach for calculation of optical birefringence of amorphous polymers is presented and applied to the polycarbonates in detail. Polarizability anisotropy of the polymer segments and chain as a function of deformation is calculated by combining information on the conformations and group polarizabilities, and used to estimate birefringence during deformation. Simulated and experimental values for segment orientation and bulk birefringence are in very good agreement. Effect of the optical properties of atomic groups on bulk birefringence is brought forth for the first time by molecular simulation for polymers other than polyethylene.

  11. Doppler optical coherence microscopy and tomography applied to inner ear mechanics

    SciTech Connect

    Page, Scott; Freeman, Dennis M.; Ghaffari, Roozbeh

    2015-12-31

    While it is clear that cochlear traveling waves underlie the extraordinary sensitivity, frequency selectivity, and dynamic range of mammalian hearing, the underlying micromechanical mechanisms remain unresolved. Recent advances in low coherence measurement techniques show promise over traditional laser Doppler vibrometry and video microscopy, which are limited by low reflectivities of cochlear structures and restricted optical access. Doppler optical coherence tomography (DOCT) and Doppler optical coherence microscopy (DOCM) both utilize a broadband source to limit constructive interference of scattered light to a small axial depth called a coherence gate. The coherence gate can be swept axially to image and measure sub-nanometer motions of cochlear structures throughout the cochlear partition. The coherence gate of DOCT is generally narrower than the confocal gate of the focusing optics, enabling increased axial resolution (typically 15 μm) within optical sections of the cochlear partition. DOCM, frequently implemented in the time domain, centers the coherence gate on the focal plane, achieving enhanced lateral and axial resolution when the confocal gate is narrower than the coherence gate. We compare these two complementary systems and demonstrate their utility in studying cellular and micromechanical mechanisms involved in mammalian hearing.

  12. Influence of dissolved organic materials on turbid water optical properties and remote-sensing reflectance

    NASA Technical Reports Server (NTRS)

    Witte, W. G.; Whitlock, C. H.; Harriss, R. C.; Usry, J. W.; Poole, L. R.; Houghton, W. M.; Morris, W. D.; Gurganus, E. A.

    1982-01-01

    The effects of dissolved organic materials on turbid-water optical properties are assessed, by means of field measurements and laboratory simulations in which upwelled reflectance, attenuation, absorption, and backscatter spectral properties at wavelengths from 450 to 800 nm are examined in relation to water chemistry. The data show that dissolved organic materials decrease upwelled reflectance from turbid waters, and that the decrease in reflectance is a nonlinear function of concentration with the largest gradients at low carbon concentrations, depending on wavelength. Upwelled reflectance is found to be highly correlated with two backscatter-absorption parameters used in some optical models, which are nonlinear with dissolved organic material concentration change.

  13. Integrated optical and electrical modeling of plasmon-enhanced thin film photovoltaics: A case-study on organic devices

    SciTech Connect

    Rourke, Devin; Ahn, Sungmo; Nardes, Alexandre M.; Lagemaat, Jao van de; Kopidakis, Nikos; Park, Wounjhang

    2014-09-21

    The nanoscale light control for absorption enhancement of organic photovoltaic (OPV) devices inevitably produces strongly non-uniform optical fields. These non-uniformities due to the localized optical modes are a primary route toward absorption enhancement in OPV devices. Therefore, a rigorous modeling tool taking into account the spatial distribution of optical field and carrier generation is necessary. Presented here is a comprehensive numerical model to describe the coupled optical and electrical behavior of plasmon-enhanced polymer:fullerene bulk heterojunction (BHJ) solar cells. In this model, a position-dependent electron-hole pair generation rate that could become highly non-uniform due to photonic nanostructures is directly calculated from the optical simulations. By considering the absorption and plasmonic properties of nanophotonic gratings included in two different popular device architectures, and applying the Poisson, current continuity, and drift/diffusion equations, the model predicts quantum efficiency, short-circuit current density, and desired carrier mobility ratios for bulk heterojunction devices incorporating nanostructures for light management. In particular, the model predicts a significant degradation of device performance when the carrier species with lower mobility are generated far from the collecting electrode. Consequently, an inverted device architecture is preferred for materials with low hole mobility. This is especially true for devices that include plasmonic nanostructures. Additionally, due to the incorporation of a plasmonic nanostructure, we use simulations to theoretically predict absorption band broadening of a BHJ into energies below the band gap, resulting in a 4.8% increase in generated photocurrent.

  14. Manipulating Magneto-Optic Properties of a Chiral Polymer by Doping with Stable Organic Biradicals.

    PubMed

    Lim, Chang-Keun; Cho, Min Ju; Singh, Ajay; Li, Qi; Kim, Won Jin; Jee, Hong Sub; Fillman, Kathlyn L; Carpenter, Stephanie H; Neidig, Michael L; Baev, Alexander; Swihart, Mark T; Prasad, Paras N

    2016-09-14

    We report the first example of tuning the large magneto-optic activity of a chiral polymer by addition of stable organic biradicals. The spectral dispersion of Verdet constant, which quantifies magneto-optic response, differs substantially between the base polymer and the nanocomposite. We employed a microscopic model, supported by atomistic calculations, to rationalize the behavior of this nanocomposite system. The suggested mechanism involves magnetic coupling between helical conjugated polymer fibrils, with spatially delocalized helical π-electron density, and the high density of spin states provided by the biradical dopants, which leads to synergistic enhancement of magneto-optic response. Our combined experimental and theoretical studies reveal that the manipulation of magnetic coupling in this new class of magneto-optic materials offers an opportunity to tailor the magnitude, sign, and spectral dispersion of the Verdet constant over a broad range of wavelengths, from the UV to the near-IR. This provides a new strategy for creating conformable materials with extraordinary magneto-optic activity, which can ultimately enable new applications requiring spatially and temporally resolved measurement of extremely weak magnetic fields. In particular, magneto-optic materials, presently employed in technologies like optical isolators and optical circulators, could be used in ultrasensitive optical magnetometers. This, in turn, could open a path toward mapping of brain activity via optical magnetoencephalography. PMID:27518762

  15. Net transformation of phosphorus forms applied as inorganic and organic amendments to a calcareous soil

    NASA Astrophysics Data System (ADS)

    Audette, Yuki; O'Halloran, Ivan; Voroney, Paul

    2016-04-01

    The forms of phosphorus (P) in animal manure composts are different from that of synthetic P fertilizers, and this could affect how soil P chemistry will be altered when they are used as P amendments. The objective of this study was to analyze the net changes in the nature and dynamics of plant available P forms applied either as inorganic P (KH2PO4) or turkey litter compost (TLC) in calcareous soil with and without plant growth. Forms of TLC-P were characterized by x-ray diffraction and solution 31P NMR spectroscopy techniques. The amounts of various P forms in soils were measured by a sequential fractionation method after 4, 8, 12 and 16 weeks incubation. Brushite (Ca-P) and newberyite (Mg-P) were the major forms of inorganic P, and phosphate monoester was the major form of organic P present in TLC. The addition of inorganic P fertilizer increased the labile/moderately labile P, whereas the compost increased the moderately labile P extractable with weak acid (pH 4.2). Even though the amount of the labile P fraction in the compost-treated soil was smaller than that in the fertilizer-treated soils, ryegrass growth and plant P uptake were greater. The net transformation of the labile/moderately labile P was slower in the compost-treated soil without plant growth, however it was faster with plant growth. This study showed that P applied either as an inorganic or an organic amendment was recovered in different P fractions in a calcareous soil, and therefore it is expected that the P source would affect soil P chemistry. A weak acid extractable inorganic P fraction should be considered as plant available P especially in the compost-treated soil, that is converted into plant available P through direct and/or indirect root-induced acidification in the rhizosphere.

  16. Poling and characterization of a novel organic/polymer electro-optic material

    NASA Astrophysics Data System (ADS)

    Liao, Jinkun; Tang, Xianzhong; Lu, Rongguo; Tang, Xionggui; Li, Heping; Zhang, Xiaoxia; Liu, Yongzhi

    2010-10-01

    Electro-optic organic/polymer material is important for the fabrication of polymer integrated optic-electronic devices and organic sensors. Recently, a novel organic high μβ value chromophore FFC have been synthesized by molecular design. The absorption spectrum in 400-4000 cm-1 is measured for the material, and the measurement result shows that the absorption loss is negligibly small. An organic/polymer high electro-optic activity material FFC/PSU is obtained by dissolving guest FFC (wt. 20%) and a host polysulfone (PSU) in a solvent. The resolvability of cyclohexanone for the material is satisfactory by comparison with other solvents experimentally, and the preparation of FFC/PSU thin film is ease relatively. The materiel is poled by electric field-assisted contact poling, and the near optimum poling condition is determined by adjusting poling parameters as pre-curing duration, poling temperature and poling voltage etc. The electro-optic coefficient of the material is measured as high as 130pm/V by using the widely accepted simple reflection technique. The investigation indicates that the FFC/PSU has excellent characteristics, such as high electro-optic coefficient, low absorption loss, good thermal stability and capability for withstanding the subsequent process techniques, suitable for the fabrication of high-performance integrated optic-electronic devices and sensors.

  17. Optical Engines, Organic Spintronics & Ice-Cube/Astranomcs Notions

    NASA Astrophysics Data System (ADS)

    Hidajatullah-Maksoed, Fatahillah; Faizal-Imaduddin, Fauzan

    2015-09-01

    Refers to ``Optical engines for light energy detection,'' PhysicsToday,June 2012, h 60 denotes NewPortCorp's OptoFlash is a miniature multichannel spectrometer engine that detects lght energy at multiple wavelengths. According to NewPort, the demultiplexing optical engine is easy to customize. Involves the Computational Fluid Dynamics/ContractForDifferences, there were sought for ``LaserDopplerVelocimetry/LDV, we intended to comprises the lVDT include in Sensor technology as well as to PVDF/polyvynilidine fluoride who comprises giant flexoelectric in alpha-phase-Xiaoning Jiang et al.``Flexoelectric Nanogenerator:Materials, structures & devices,'' 2013 paved with good intentions, the ``jellium model'' [Overhauser, 1963a] maybe can be interrelated to reflex action & primary process used by Id to avoids pain in painstakingly to wieghs spin relaxation & dephasing process that guides ``EQILIBRATION.'' Also offered the spintronics using PID-controller, from Microbisl Cells to ``The Motor Response inPlasma Heating.'' Further, the Aug 1985 FAA Certification for IAI 1125 ASTRA Jet Corp inherently existed between Julian C. Blecker's dissertation to ``realistic mathematics'' from Prof. R.K. Sembiring/MA-ITB. Great acknowledgment devotes to HE. Mr. Drs. P. SWANTORO through the Jakarta-based BCA Bank.

  18. Integrated optical components using hybrid organic-inorganic materials prepared by sol-gel technology

    NASA Astrophysics Data System (ADS)

    Mishechkin, Oleg Viktorovich

    2003-10-01

    A technological platform based on low-temperature hybrid sol-gel method for fabrication of optical waveguides and integrated optical components has been developed. The developed chemistry for doping incorporation in the host network provides a range of refractive indexes (1.444--1.51) critical for device optimization. A passivation method for improving long-term stability of organic-inorganic sol-gel material is reported. The degradation of waveguide loss over time due to moisture adsorption from the atmosphere is drastically suppressed by coating the material with a protective thin SiO2 film. The results indicate a long-term optical loss below 0.3 dB/cm for protected waveguides. The theory of multimode interference couplers employing self-imaging effect is described. A novel approach for design of high-performance MMI devices in low-contrast material is proposed. The design method is based on optimization of refractive index contrast and width of a multimode waveguide (the body of MMI couplers) to achieve a maximum number of constructively interfering modes resulting to the best self-imaging. This optimization is carried out using 3D BPM simulations. This method was applied to design 1 x 4, 1 x 12, and 4 x 4 MMI couplers and led to a superior performance in excess loss, power imbalance in output ports, and polarization sensitivity. Taking advantage of the inherent input-output phase relations in a 4 x 4 MMI coupler, an optical 90° hybrid is realized by incorporation a Y-junction to coherently excite two ports of the coupler. A series of MMI couplers were fabricated and characterized. The experimental results are in good agreement with the design. Measured performance of the sol-gel derived MMI components was compared to analogues fabricated by other technologies. The comparison demonstrates the superior performance of the sol-gel devices. The polarization sensitivity of all fabricated couplers is below 0.05 dB.

  19. Superluminal, luminal, and subluminal nondiffracting pulses applied to free-space optical systems: theoretical description.

    PubMed

    Garay-Avendaño, Roger L; Zamboni-Rached, Michel

    2016-03-01

    In this paper, we show theoretically nondiffracting pulses with arbitrary peak velocities that are suitable for data signal transmission without distortion over long distances using different techniques of signal modulation. Our results provide closed-form analytical solutions to the wave equation describing superluminal, luminal, and subluminal ideal nondiffracting pulses with frequency spectra commonly used in the field of optical communications. PMID:26974644

  20. Investigation of organic nonlinear optical crystals for harmonic frequency conversion and electro-optics. Final technical report

    SciTech Connect

    1998-01-01

    The authors are conducting a detailed study of the crystal growth of different organic materials and their physical, optical and morphological properties. The crystals are grown by a novel solution crystal growth technique developed by the principal investigator at Alabama A and M University (AAMU). The studies included the measurement of solubility of organic NLO materials in different solvents, growth of crystals by solution growth technique, and the characterization of optical properties and damage threshold of crystals for high power laser applications. Two different NLO crystals of 4-Aminobenzophenone (ABP) and 3-methoxy-4-hydroxy-benzaldehyde (MHBA) were investigated during the course of this investigation. A paper on ABP crystals was published in Journal of Crystal Growth in 1997.

  1. All-Optical Two-Dimensional Serial-to-Parallel Pulse Converter Using an Organic Film with Femtosecond Optical Response

    NASA Astrophysics Data System (ADS)

    Tatsuura, Satoshi; Wada, Osamu; Furuki, Makoto; Tian, Minquan; Sato, Yasuhiro; Iwasa, Izumi; Pu, Lyong Sun

    2001-04-01

    In this study, we introduce a new concept of all-optical two-dimensional serial-to-parallel pulse converters. Femtosecond optical pulses can be understood as thin plates of light traveling in space. When a femtosecond signal-pulse train and a single gate pulse were fed onto a material with a finite incident angle, each signal-pulse plate met the gate-pulse plate at different locations in the material due to the time-of-flight effect. Meeting points can be made two-dimensional by adding a partial time delay to the gate pulse. By placing a nonlinear optical material at an appropriate position, two-dimensional serial-to-parallel conversion of a signal-pulse train can be achieved with a single gate pulse. We demonstrated the detection of parallel outputs from a 1-Tb/s optical-pulse train through the use of a BaB2O4 crystal. We also succeeded in demonstrating 1-Tb/s serial-to-parallel operation through the use of a novel organic nonlinear optical material, squarylium-dye J-aggregate film, which exhibits ultrafast recovery of bleached absorption.

  2. Broadband energy-efficient optical modulation by hybrid integration of silicon nanophotonics and organic electro-optic polymer

    NASA Astrophysics Data System (ADS)

    Zhang, Xingyu; Hosseini, Amir; Subbaraman, Harish; Luo, Jingdong; Jen, Alex K.-Y.; Chung, Chi-jui; Yan, Hai; Pan, Zeyu; Nelson, Robert L.; Chen, Ray T.

    2015-03-01

    Silicon-organic hybrid integrated devices have emerging applications ranging from high-speed optical interconnects to photonic electromagnetic-field sensors. Silicon slot photonic crystal waveguides (PCWs) filled with electro-optic (EO) polymers combine the slow-light effect in PCWs with the high polarizability of EO polymers, which promises the realization of high-performance optical modulators. In this paper, a broadband, power-efficient, low-dispersion, and compact optical modulator based on an EO polymer filled silicon slot PCW is presented. A small voltage-length product of Vπ×L=0.282V×mm is achieved, corresponding to an unprecedented record-high effective in-device EO coefficient (r33) of 1230pm/V. Assisted by a backside gate voltage, the modulation response up to 50GHz is observed, with a 3-dB bandwidth of 15GHz, and the estimated energy consumption is 94.4fJ/bit at 10Gbit/s. Furthermore, lattice-shifted PCWs are utilized to enhance the optical bandwidth by a factor of ~10X over other modulators based on non-band-engineered PCWs and ring-resonators.

  3. Optical spacing effect in organic photovoltaic cells incorporating a dilute acceptor layer

    SciTech Connect

    Menke, S. Matthew; Lindsay, Christopher D.; Holmes, Russell J.

    2014-06-16

    The addition of spacing layers in organic photovoltaic cells (OPVs) can enhance light absorption by optimizing the spatial distribution of the incident optical field in the multilayer structure. We explore the optical spacing effect in OPVs achieved using a diluted electron acceptor layer of C{sub 60}. While optical spacing is often realized by optimizing buffer layer thickness, we find that optical spacing via dilution leads to cells with similar or enhanced photocurrent. This is observed despite a smaller quantity of absorbing molecules, suggesting a more efficient use of absorbed photons. In fact, dilution is found to concentrate optical absorption near the electron donor-acceptor interface, resulting in a marked increase in the exciton diffusion efficiency. Contrasting the use of changes in thickness to engineer optical absorption, the use of dilution does not significantly alter the overall thickness of the OPV. Optical spacing via dilution is shown to be a viable alternative to more traditional optical spacing techniques and may be especially useful in the continued optimization of next-generation, tandem OPVs where it is important to minimize competition for optical absorption between individual sub-cells.

  4. Optical spacing effect in organic photovoltaic cells incorporating a dilute acceptor layer

    NASA Astrophysics Data System (ADS)

    Menke, S. Matthew; Lindsay, Christopher D.; Holmes, Russell J.

    2014-06-01

    The addition of spacing layers in organic photovoltaic cells (OPVs) can enhance light absorption by optimizing the spatial distribution of the incident optical field in the multilayer structure. We explore the optical spacing effect in OPVs achieved using a diluted electron acceptor layer of C60. While optical spacing is often realized by optimizing buffer layer thickness, we find that optical spacing via dilution leads to cells with similar or enhanced photocurrent. This is observed despite a smaller quantity of absorbing molecules, suggesting a more efficient use of absorbed photons. In fact, dilution is found to concentrate optical absorption near the electron donor-acceptor interface, resulting in a marked increase in the exciton diffusion efficiency. Contrasting the use of changes in thickness to engineer optical absorption, the use of dilution does not significantly alter the overall thickness of the OPV. Optical spacing via dilution is shown to be a viable alternative to more traditional optical spacing techniques and may be especially useful in the continued optimization of next-generation, tandem OPVs where it is important to minimize competition for optical absorption between individual sub-cells.

  5. Organic crystalline films for optical applications and related methods of fabrication

    NASA Technical Reports Server (NTRS)

    Leyderman, Alexander (Inventor); Cui, Yunlong (Inventor)

    2003-01-01

    The present invention provides organic single crystal films of less than 20 .mu.m, and devices and methods of making such films. The crystal films are useful in electro-optical applications and can be provided as part of an electro-optical device which provides strength, durability, and relative ease of manipulation of the mono-crystalline films during and after crystal growth.

  6. Growth and characterization of a new organic nonlinear optical crystal: semicarbazone of p-dimethylamino benzaldehyde

    NASA Astrophysics Data System (ADS)

    Manivannan, S.; Dhanuskodi, S.

    2003-10-01

    Semicarbazone of p-dimethylamino benzaldehyde (SCPDB) is a new organic material with interesting quadratic nonlinear optical properties, in particular second harmonic generation (SHG). SCPDB was synthesized and single crystals were grown by low temperature solution method. Unit cell parameters were evaluated by single crystal X-ray diffraction technique. The formation of the material was confirmed qualitatively by FT-IR and FT-Raman spectral analyses and its optical transmittance studied. SHG efficiency is found to be comparable to urea.

  7. Fiber-optic technologies for advanced thermo-therapy applied ex vivo to liver tumors

    NASA Astrophysics Data System (ADS)

    Tosi, D.; Perrone, G.; Vallan, A.; Braglia, A.; Liu, Y.; Macchi, E. G.; Braschi, G.; Gallati, M.; Cigada, A.; Poeggel, S.; Duraibabu, D. B.; Leen, G.; Lewis, E.

    2015-07-01

    Thermal ablation, using radiofrequency, microwave, and laser sources, is a common treatment for hepatic tumors. Sensors allow monitoring, at the point of treatment, the evolution of thermal ablation procedures. We present optical fiber sensors that allow advanced capabilities for recording the biophysical phenomena occurring in the tissue in real time. Distributed or quasi-distributed thermal sensors allow recording temperature with spatial resolution ranging from 0.1 mm to 5 mm. In addition, a thermally insensitive pressure sensor allows recording pressure rise, supporting advanced treatment of encapsulated tumors. Our investigation is focused on two case studies: (1) radiofrequency ablation of hepatic tissue, performed on a phantom with a stem-shaped applicator; (2) laser ablation of a liver phantom, performed with a fiber laser. The main measurement results are discussed, comparing the technologies used for the investigation, and drawing the potential for using optical fiber sensors for "smart"-ablation.

  8. Hybrid Organic-Inorganic Coordination Complexes as Tunable Optical Response Materials.

    PubMed

    Travis, Will; Knapp, Caroline E; Savory, Christopher N; Ganose, Alex M; Kafourou, Panagiota; Song, Xingchi; Sharif, Zainab; Cockcroft, Jeremy K; Scanlon, David O; Bronstein, Hugo; Palgrave, Robert G

    2016-04-01

    Novel lead and bismuth dipyrido complexes have been synthesized and characterized by single-crystal X-ray diffraction, which shows their structures to be directed by highly oriented π-stacking of planar fully conjugated organic ligands. Optical band gaps are influenced by the identity of both the organic and inorganic component. Density functional theory calculations show optical excitation leads to exciton separation between inorganic and organic components. Using UV-vis, photoluminescence, and X-ray photoemission spectroscopies, we have determined the materials' frontier energy levels and show their suitability for photovoltaic device fabrication by use of electron- and hole-transport materials such as TiO2 and spiro-OMeTAD respectively. Such organic/inorganic hybrid materials promise greater electronic tunability than the inflexible methylammonium lead iodide structure through variation of both the metal and organic components.

  9. Proven high-reliability assembly methods applied to avionics fiber-optics high-speed transceivers

    NASA Astrophysics Data System (ADS)

    Lauzon, Jocelyn; Leduc, Lorrain; Bessette, Daniel; Bélanger, Nicolas; Larose, Robert; Dion, Bruno

    2012-06-01

    Harsh environment avionics applications require operating temperature ranges that can extend to, and exceed -50 to 115°C. For obvious maintenance, management and cost arguments, product lifetimes as long as 20 years are also sought. This leads to mandatory long-term hermeticity that cannot be obtained with epoxy or silicone sealing; but only with glass seal or metal solder or brazing. A hermetic design can indirectly result in the required RF shielding of the component. For fiber-optics products, these specifications need to be compatible with the smallest possible size, weight and power consumption. The products also need to offer the best possible high-speed performances added to the known EMI immunity in the transmission lines. Fiber-optics transceivers with data rates per fiber channel up to 10Gbps are now starting to be offered on the market for avionics applications. Some of them are being developed by companies involved in the "normal environment" telecommunications market that are trying to ruggedize their products packaging in order to diversify their customer base. Another approach, for which we will present detailed results, is to go back to the drawing boards and design a new product that is adapted to proven MIL-PRF-38534 high-reliability packaging assembly methods. These methods will lead to the introduction of additional requirements at the components level; such as long-term high-temperature resistance for the fiber-optic cables. We will compare both approaches and demonstrate the latter, associated with the redesign, is the preferable one. The performance of the fiber-optic transceiver we have developed, in terms of qualification tests such as temperature cycling, constant acceleration, hermeticity, residual gaz analysis, operation under random vibration and mechanical shocks and accelerated lifetime tests will be presented. The tests are still under way, but so far, we have observed no performance degradation of such a product after more than

  10. Optical polarimetry applied to the development of a noninvasive in-vivo glucose monitor

    NASA Astrophysics Data System (ADS)

    Cameron, Brent D.; Baba, Justin S.; Cote, Gerard L.

    2000-05-01

    The application of optical polarimetry, using the anterior chamber of the eye as the sensing site, is being investigated as a potential method to develop a noninvasive physiological glucose monitor. First, we present results characterizing the optical rotatory dispersion of the main optically active analytes found within the aqueous humor of the eye including, glucose, albumin, and ascorbic acid. This information is used in conjunction with multiple linear regression to demonstrate how multispectral polarimetry can be used to minimize glucose prediction error in samples containing varying physiological concentrations of glucose and albumin. For this multispectral study, a novel dual wavelength (532 nm and 635 nm) polarimeter was designed and constructed. This sensor is novel in that it provides simultaneous measurements using a 532 nm laser in an open- loop configuration and a 635 nm laser in a closed-loop configuration. In addition, we present in vivo results using New Zealand White rabbits that indicate the time delay between blood and aqueous human glucose levels is below ten minutes. Lastly, we provide preliminary in vivo polarimetric results and discuss the main issues currently hindering the measurement of glucose.

  11. Optical absorption in transparent PDMS materials applied for multimode waveguides fabrication

    NASA Astrophysics Data System (ADS)

    Cai, D. K.; Neyer, A.; Kuckuk, R.; Heise, H. M.

    2008-03-01

    The optical properties of transparent PDMS polymer materials, which can be integrated into general printed circuit board (PCB) for data communication, are of great interest due to the substantial market expectations for the near future. For the present paper, it was found that the absorption loss in polydimethylsiloxane (PDMS) is mainly caused by the vibrational overtone and combination bands of the CH 3-groups of the polymer in the spectral datacom region of 600-900 nm. Based on observed positions of fundamental, overtone and combination bands of the methyl-group, as recorded within the mid- and near-infrared spectra, anharmonicity constants and normal vibration frequencies were determined. Thus, an empirical equation for estimating the wavelengths with the most significant intrinsic absorption loss due to the corresponding band positions was formulated, which was found to agree well with the experimental data. In addition, PDMS multimode waveguides were fabricated and the respective optical insertion loss was measured at 850 nm, which is commercially used for optical datacom transmission and finally the thermal stability of PDMS multimode waveguides was verified as well.

  12. Measuring the effects of topically applied skin optical clearing agents and modeling the effects and consequences for laser therapies

    NASA Astrophysics Data System (ADS)

    Verkruysse, Wim; Khan, Misbah; Choi, Bernard; Svaasand, Lars O.; Nelson, J. Stuart

    2005-04-01

    Human skin prepared with an optical clearing agent manifests reduced scattering as a result of de-hydration and refractive index matching. This has potentially large effects for laser therapies of several skin lesions such as port wine stain, hair removal and tattoo removal. With most topically applied clearing agents the clearing effect is limited because they penetrate poorly through the intact superficial skin layer (stratum corneum). Agent application modi other than topical are impractical and have limited the success of optical clearing in laser dermatology. In recent reports, however, a mixture of lipofylic and hydrofylic agents was shown to successfully penetrate through the intact stratum corneum layer which has raised new interest in this field. Immediately after application, the optical clearing effect is superficial and, as the agent diffuses through the skin, reduced scattering is manifested in deeper skin layers. For practical purposes as well as to maximize therapeutic success, it is important to quantify the reduced scattering as well as the trans-cutaneous transport dynamics of the agent. We determined the time and tissue depth resolved effects of optically cleared skin by inserting a microscopic reflector array in the skin. Depth dependent light intensity was measured by quantifying the signal of the reflector array with optical coherence tomography. A 1-dimensional mass diffusion model was used to estimate a trans-cutaneous transport diffusion constant for the clearing agent mixture. The results are used in Monte Carlo modeling to determine the optimal time of laser treatment after topical application of the optical clearing agent.

  13. 25 CFR 900.44 - What minimum general standards apply to all Indian tribe or tribal organization financial...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... or tribal organization financial management systems when carrying out a self-determination contract... Financial Management Systems § 900.44 What minimum general standards apply to all Indian tribe or tribal organization financial management systems when carrying out a self-determination contract? The fiscal...

  14. 25 CFR 900.44 - What minimum general standards apply to all Indian tribe or tribal organization financial...

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... or tribal organization financial management systems when carrying out a self-determination contract... Financial Management Systems § 900.44 What minimum general standards apply to all Indian tribe or tribal organization financial management systems when carrying out a self-determination contract? The fiscal...

  15. 25 CFR 900.44 - What minimum general standards apply to all Indian tribe or tribal organization financial...

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... or tribal organization financial management systems when carrying out a self-determination contract... Financial Management Systems § 900.44 What minimum general standards apply to all Indian tribe or tribal organization financial management systems when carrying out a self-determination contract? The fiscal...

  16. 25 CFR 900.44 - What minimum general standards apply to all Indian tribe or tribal organization financial...

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... or tribal organization financial management systems when carrying out a self-determination contract... Financial Management Systems § 900.44 What minimum general standards apply to all Indian tribe or tribal organization financial management systems when carrying out a self-determination contract? The fiscal...

  17. 25 CFR 900.44 - What minimum general standards apply to all Indian tribe or tribal organization financial...

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... or tribal organization financial management systems when carrying out a self-determination contract... Financial Management Systems § 900.44 What minimum general standards apply to all Indian tribe or tribal organization financial management systems when carrying out a self-determination contract? The fiscal...

  18. 25 CFR 900.38 - Do these standards apply to the subcontractors of an Indian tribe or tribal organization carrying...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... HEALTH AND HUMAN SERVICES CONTRACTS UNDER THE INDIAN SELF-DETERMINATION AND EDUCATION ASSISTANCE ACT Standards for Tribal or Tribal Organization Management Systems General § 900.38 Do these standards apply to... Indian tribe or tribal organization carrying out a self-determination contract? 900.38 Section...

  19. Mustiscaling Analysis applied to field Water Content through Distributed Fiber Optic Temperature sensing measurements

    NASA Astrophysics Data System (ADS)

    Benitez Buelga, Javier; Rodriguez-Sinobas, Leonor; Sanchez, Raul; Gil, Maria; Tarquis, Ana M.

    2014-05-01

    signal variation, or to see at which scales signals are most correlated. This can give us an insight into the dominant processes An alternative to both of the above methods has been described recently. Relative entropy and increments in relative entropy has been applied in soil images (Bird et al., 2006) and in soil transect data (Tarquis et al., 2008) to study scale effects localized in scale and provide the information that is complementary to the information about scale dependencies found across a range of scales. We will use them in this work to describe the spatial scaling properties of a set of field water content data measured in an extension of a corn field, in a plot of 500 m2 and an spatial resolution of 25 cm. These measurements are based on an optics cable (BruggSteal) buried on a ziz-zag deployment at 30cm depth. References Bird, N., M.C. Díaz, A. Saa, and A.M. Tarquis. 2006. A review of fractal and multifractal analysis of soil pore-scale images. J. Hydrol. 322:211-219. Kravchenko, A.N., R. Omonode, G.A. Bollero, and D.G. Bullock. 2002. Quantitative mapping of soil drainage classes using topographical data and soil electrical conductivity. Soil Sci. Soc. Am. J. 66:235-243. Lark, R.M., A.E. Milne, T.M. Addiscott, K.W.T. Goulding, C.P. Webster, and S. O'Flaherty. 2004. Scale- and location-dependent correlation of nitrous oxide emissions with soil properties: An analysis using wavelets. Eur. J. Soil Sci. 55:611-627. Lark, R.M., S.R. Kaffka, and D.L. Corwin. 2003. Multiresolution analysis of data on electrical conductivity of soil using wavelets. J. Hydrol. 272:276-290. Lark, R. M. and Webster, R. 1999. Analysis and elucidation of soil variation using wavelets. European J. of Soil Science, 50(2): 185-206. Mandelbrot, B.B. 1982. The fractal geometry of nature. W.H. Freeman, New York. Percival, D.B., and A.T. Walden. 2000. Wavelet methods for time series analysis. Cambridge Univ. Press, Cambridge, UK. Tarquis, A.M., N.R. Bird, A.P. Whitmore, M.C. Cartagena, and

  20. Mustiscaling Analysis applied to field Water Content through Distributed Fiber Optic Temperature sensing measurements

    NASA Astrophysics Data System (ADS)

    Benitez Buelga, Javier; Rodriguez-Sinobas, Leonor; Sanchez, Raul; Gil, Maria; Tarquis, Ana M.

    2014-05-01

    signal variation, or to see at which scales signals are most correlated. This can give us an insight into the dominant processes An alternative to both of the above methods has been described recently. Relative entropy and increments in relative entropy has been applied in soil images (Bird et al., 2006) and in soil transect data (Tarquis et al., 2008) to study scale effects localized in scale and provide the information that is complementary to the information about scale dependencies found across a range of scales. We will use them in this work to describe the spatial scaling properties of a set of field water content data measured in an extension of a corn field, in a plot of 500 m2 and an spatial resolution of 25 cm. These measurements are based on an optics cable (BruggSteal) buried on a ziz-zag deployment at 30cm depth. References Bird, N., M.C. Díaz, A. Saa, and A.M. Tarquis. 2006. A review of fractal and multifractal analysis of soil pore-scale images. J. Hydrol. 322:211-219. Kravchenko, A.N., R. Omonode, G.A. Bollero, and D.G. Bullock. 2002. Quantitative mapping of soil drainage classes using topographical data and soil electrical conductivity. Soil Sci. Soc. Am. J. 66:235-243. Lark, R.M., A.E. Milne, T.M. Addiscott, K.W.T. Goulding, C.P. Webster, and S. O'Flaherty. 2004. Scale- and location-dependent correlation of nitrous oxide emissions with soil properties: An analysis using wavelets. Eur. J. Soil Sci. 55:611-627. Lark, R.M., S.R. Kaffka, and D.L. Corwin. 2003. Multiresolution analysis of data on electrical conductivity of soil using wavelets. J. Hydrol. 272:276-290. Lark, R. M. and Webster, R. 1999. Analysis and elucidation of soil variation using wavelets. European J. of Soil Science, 50(2): 185-206. Mandelbrot, B.B. 1982. The fractal geometry of nature. W.H. Freeman, New York. Percival, D.B., and A.T. Walden. 2000. Wavelet methods for time series analysis. Cambridge Univ. Press, Cambridge, UK. Tarquis, A.M., N.R. Bird, A.P. Whitmore, M.C. Cartagena, and

  1. Computational Study of Linear and Nonlinear Optical Properties of Single Molecules and Clusters of Organic Electro-Optic Chromophores

    NASA Astrophysics Data System (ADS)

    Garrett, Kerry

    Organic electro-optic (OEO) materials integrated into silicon-organic hybrid (SOH) devices afford significant improvements in size, weight, power, and bandwidth (SWAP) performance of integrated electronic/photonic systems critical for current and next generation telecommunication, computer, sensor, transportation, and defense technologies. Improvement in molecular first hyperpolarizability, and in turn electro-optic activity, is crucial to further improvement in the performance of SOH devices. The timely preparation of new chromophores with improved molecular first hyperpolarizability requires theoretical guidance; however, common density functional theory (DFT) methods often perform poorly for optical properties in systems with substantial intramolecular charge transfer character. The first part of this dissertation describes the careful evaluation of popular long-range correction (LC) and range-separated hybrid (RSH) density functional theory (DFT) for definition of structure/function relationships crucial for the optimization of molecular first hyperpolarizability, beta. In particular, a benchmark set of well-characterized OEO chromophores is used to compare calculated results with the corresponding experimentally measured linear and nonlinear optical properties; respectively, the wavelength of the peak one-photon absorption energy, lambdamax, and beta. A goal of this work is to systematically determine the amount of exact exchange in LC/RSH-DFT methods required for accurately computing these properties for a variety OEO chromophores. High-level electron correlation (post-Hartree-Fock) methods are also investigated and compared with DFT. Included are results for the computation of beta using second-order Moller-Plesset perturbation theory (MP2) and the double-hybrid method, B2PLYP. The second part of this work transitions from single-molecule studies to computing bulk electronic and nonlinear optical properties of molecular crystals and isotropic ensembles of a

  2. Three-dimensional confocal optical imagery of precambrian microscopic organisms.

    PubMed

    Schopf, J William; Tripathi, Abhishek B; Kudryavtsev, Anatoliy B

    2006-02-01

    A major difficulty that has long hindered studies of organic-walled Precambrian microbes in petrographic thin sections is the accurate documentation of their three-dimensional morphology. To address this need, we here demonstrate the use of confocal laser scanning microscopy. This technique, both non-intrusive and non-destructive, can provide data by which to objectively characterize, in situ and at submicron-scale resolution, the cellular and organismal morphology of permineralized (petrified) microorganisms. Application of this technique can provide information in three dimensions about the morphology, taphonomy, and fidelity of preservation of such fossils at a spatial resolution unavailable by any other means.

  3. Anisotropic optical distribution of powder phosphor materials applied in medical imaging instrumentation

    NASA Astrophysics Data System (ADS)

    Liaparinos, P. F.

    2016-02-01

    Image quality for medical purposes is related to the useful diagnostic information that can be extracted from an image. The performance of indirect X-ray detectors, which in turn affects the quality of the medical image, can be significantly influenced by the characteristics of the phosphor, employed to convert incident radiation into emitted light. Given the technological and medical importance of phosphor materials, understanding the fundamental effects of optical anisotropy is crucial. The purpose of the present paper was to examine the influence of optical anisotropy in optical diffusion within the powder phosphor-based X-ray detectors. The present investigation was based on Mie scattering theory and Monte Carlo simulation techniques. The variation of the anisotropy factor was examined for: (1) light wavelengths in the range 400-700 nm, (2) particle refractive index between 1.5 and 2 and (3) three regions of particle sizes: nanoscale (from 10 up to 100 nm), submicron scale (from 100 nm up to 1 μm), and microscale (from 1 up to 10 μm). In addition, optical diffusion performance was carried out considering: (a) anisotropy factor values 0.2, 0.5, 0.8 which represent different aspects of light propagation after scattering and (b) phosphors of different layer thickness, 100 (thin layer) and 300 μm (thick layer), respectively. Results showed that the highest variation on the anisotropy factor was observed in the submicron scale, and, in particular, for grain diameters between 100 and 600 nm (increase from 0.1 up to 0.8). In addition, Monte Carlo simulations showed that the spread of light photons decreases (i.e., high spatial resolution) with the decrease in the anisotropy factor. In particular, the FWHM was found to decrease with the anisotropy factor: (1) 11.4 % at 100 μm and 4.2 %, at 300 μm layer thickness, for light extinction coefficient 0.217 μm-1 and (2) 1.9 % at 100 μm and 2.0 %, at 300 μm layer thickness, for light extinction coefficient 3 μm-1

  4. The early-stage diagnosis of albinic embryos by applying optical coherence tomography

    NASA Astrophysics Data System (ADS)

    Yang, Bor-Wen; Wang, Shih-Yuan; Wang, Yu-Yen; Cai, Jyun-Jhang; Chang, Chung-Hao

    2013-09-01

    Albinism is a kind of congenital disease of abnormal metabolism. Poecilia reticulata (guppy fish) is chosen as the model to study the development of albinic embryos as it is albinic, ovoviviparous and with short life period. This study proposed an imaging method for penetrative embryo investigation using optical coherence tomography. By imaging through guppy mother’s reproduction purse, we found the embryo’s eyes were the early-developed albinism features. As human’s ocular albinism typically appear at about four weeks old, it is the time to determine if an embryo will grow into an albino.

  5. Optical fiber imaging for high speed plasma motion diagnostics: Applied to low voltage circuit breakers

    SciTech Connect

    McBride, J. W.; Balestrero, A.; Tribulato, G.; Ghezzi, L.; Cross, K. J.

    2010-05-15

    An integrated portable measurement system is described for the study of high speed and high temperature unsteady plasma flows such as those found in the vicinity of high current switching arcs. An array of optical fibers allows the formation of low spatial resolution images, with a maximum capture rate of 1x10{sup 6} images per second (1 MHz), with 8 bit intensity resolution. Novel software techniques are reported to allow imaging of the arc; and to measure arc trajectories. Results are presented on high current (2 kA) discharge events in a model test fixture and on the application to a commercial low voltage circuit breaker.

  6. A statistical model for road surface friction forecasting applying optical road weather measurements

    NASA Astrophysics Data System (ADS)

    Hippi, M.; Juga, I.; Nurmi, P.

    2009-09-01

    Road surface friction is defined as the grip between car tyre and underlying surface. Poor friction often plays a crucial role in wintertime car accidents. Friction can decrease dramatically during snowfall or when wet road surface temperature falls below zero. Even a thin layer of ice or snow can decrease friction substantially increasing the risk of accidents. Many studies have shown that road surface temperature, road conditions and friction can fluctuate dramatically within short distances under specific weather situations. Friction or grip can be improved with road maintenance activities like salting and gritting. Salting will melt the ice or snow layer, whereas gritting will improve the grip. Salting is effective only above -5C temperatures. Light snowfall together with low temperatures can result in very slippery driving conditions. Finnish Road Administration's observing network covers c. 500 road weather stations in Finland. Almost 100 of them are equipped with optical sensors (in winter 2008-2009). The number of optical sensors has increased remarkably during past few years. The optical measuring devices are Vaisala DSC111 sensors which measure the depth of water, snow and ice on the road surface and also produce an estimate of the state of road and prevailing friction. Observation data from road weather stations with optical sensors were collected from winter 2007/08, and a couple of representative (from a weather perspective) stations were selected for detailed statistical analysis. The purpose of the study was to find a statistical relationship between the observed values and, especially, the correlation between friction and other road weather parameters. Consequently, a model based on linear regression was developed. With the model friction being the dependent variable, the independent variables having highest correlations were the composite of ice and snow (water content) on the road, and the road surface temperature. In the case of a wet road

  7. MaizeGDB: The Maize Model Organism Database for Basic, Translational, and Applied Research

    PubMed Central

    Lawrence, Carolyn J.; Harper, Lisa C.; Schaeffer, Mary L.; Sen, Taner Z.; Seigfried, Trent E.; Campbell, Darwin A.

    2008-01-01

    In 2001 maize became the number one production crop in the world with the Food and Agriculture Organization of the United Nations reporting over 614 million tonnes produced. Its success is due to the high productivity per acre in tandem with a wide variety of commercial uses. Not only is maize an excellent source of food, feed, and fuel, but also its by-products are used in the production of various commercial products. Maize's unparalleled success in agriculture stems from basic research, the outcomes of which drive breeding and product development. In order for basic, translational, and applied researchers to benefit from others' investigations, newly generated data must be made freely and easily accessible. MaizeGDB is the maize research community's central repository for genetics and genomics information. The overall goals of MaizeGDB are to facilitate access to the outcomes of maize research by integrating new maize data into the database and to support the maize research community by coordinating group activities. PMID:18769488

  8. A new microscope optics for laser dark-field illumination applied to high precision two dimensional measurement of specimen displacement

    NASA Astrophysics Data System (ADS)

    Noda, Naoki; Kamimura, Shinji

    2008-02-01

    With conventional light microscopy, precision in the measurement of the displacement of a specimen depends on the signal-to-noise ratio when we measure the light intensity of magnified images. This implies that, for the improvement of precision, getting brighter images and reducing background light noise are both inevitably required. For this purpose, we developed a new optics for laser dark-field illumination. For the microscopy, we used a laser beam and a pair of axicons (conical lenses) to get an optimal condition for dark-field observations. The optics was applied to measuring two dimensional microbead displacements with subnanometer precision. The bandwidth of our detection system overall was 10kHz. Over most of this bandwidth, the observed noise level was as small as 0.1nm/√Hz.

  9. From hyperons to applied optics: {open_quotes}Winston Cones{close_quotes} during and after ZGS era

    SciTech Connect

    Swallow, E.C. |

    1994-12-31

    This paper discusses developments in light collection which had their origin in efforts to construct high performance gas Cerenkov detectors for precision studies of hyperon beta decays at the ZGS. The resulting devices, know generally as {open_quotes}compound parabolic concentrators,{close_quotes} have found applications ranging from nuclear and particle physics experiments to solar energy concentration, instrument illumination, and understanding the optics of visual receptors. Interest in these devices and the ideas underlying them stimulated the development of a substantial new subfield of physics: nonimaging optics. This progression provides an excellent example of some ways in which unanticipated - and often unanticipatable - applied science and {open_quotes}practical{close_quotes} devices naturally emerge from first-rate basic science. The characteristics of this process suggest that the term {open_quotes}spinoff{close_quotes} commonly used to denote it is misleading and in need of replacement.

  10. Optical macro-tweezers: trapping of highly motile micro-organisms

    NASA Astrophysics Data System (ADS)

    Thalhammer, G.; Steiger, R.; Bernet, S.; Ritsch-Marte, M.

    2011-04-01

    Optical micromanipulation stands for contact-free handling of microscopic particles by light. Optical forces can manipulate non-absorbing objects in a large range of sizes, e.g., from biological cells down to cold atoms. Recently much progress has been made going from the micro- down to the nanoscale. Less attention has been paid to going the other way, trapping increasingly large particles. Optical tweezers typically employ a single laser beam tightly focused by a microscope objective of high numerical aperture to stably trap a particle in three dimensions (3D). As the particle size increases, stable 3D trapping in a single-beam trap requires scaling up the optical power, which eventually induces adverse biological effects. Moreover, the restricted field of view of standard optical tweezers, dictated by the use of high NA objectives, is particularly unfavorable for catching actively moving specimens. Both problems can be overcome by traps with counter-propagating beams. Our 'macro-tweezers' are especially designed to trap highly motile organisms, as they enable three-dimensional all-optical trapping and guiding in a volume of 2 × 1 × 2 mm3. Here we report for the first time the optical trapping of large actively swimming organisms, such as for instance Euglena protists and dinoflagellates of up to 70 µm length. Adverse bio-effects are kept low since trapping occurs outside high intensity regions, e.g., focal spots. We expect our approach to open various possibilities in the contact-free handling of 50-100 µm sized objects that could hitherto not be envisaged, for instance all-optical holding of individual micro-organisms for taxonomic identification, selective collecting or tagging.

  11. Crystal structure, growth and nonlinear optical studies of isonicotinamide p-nitrophenol: A new organic crystal for optical limiting applications

    NASA Astrophysics Data System (ADS)

    Vijayalakshmi, A.; Vidyavathy, B.; Vinitha, G.

    2016-08-01

    Isonicotinamide p-nitrophenol (ICPNP), a new organic material, was synthesized using methanol solvent. Single crystals of ICPNP were grown using a slow evaporation solution growth technique. Crystal structure of ICPNP is elucidated by single crystal X-ray diffraction analysis. It belongs to monoclinic crystal system with space group of P21/c. It forms two dimensional networks by O-H…O, N-H…O and C-H…O hydrogen bonds. The molecular structure of ICPNP was further confirmed by Fourier transform infrared (FTIR) spectral analysis. The optical transmittance range and the lower cut-off wavelength (421 nm) with the optical band gap (2.90 eV) of the ICPNP crystal were determined by UV-vis-NIR spectral study. Thermal behavior of ICPNP was studied by thermo gravimetric and differential thermal analyses (TG/DTA). The relative dielectric permittivity was calculated for various temperature ranges. Laser damage threshold of ICPNP crystal was found to be 1.9 GW/cm2 using an Nd:YAG laser. A Z-scan technique was employed to measure the nonlinear absorption coefficient, nonlinear refractive index and nonlinear optical susceptibility. Optical limiting behavior of ICPNP was observed at 35 mW input power.

  12. Optical properties in the UV and visible spectral region of organic acids relevant to tropospheric aerosols

    NASA Astrophysics Data System (ADS)

    Lund Myhre, C. E.; Nielsen, C. J.

    2004-09-01

    Refractive and absorption indices in the UV and visible region of selected aqueous organic acids relevant to tropospheric aerosols are reported. The acids investigated are the aliphatic dicarboxylic acids oxalic, malonic, tartronic, succinic and glutaric acid. In addition we report data for pyruvic, pinonic, benzoic and phthalic acid. To cover a wide range of conditions we have investigated the aqueous organic acids at different concentrations spanning from highly diluted samples to concentrations close to saturation. The density of the investigated samples is reported and a parameterisation of the absorption and refractive index that allows the calculation of the optical constants of mixed aqueous organic acids at different concentrations is presented. The single scattering albedo is calculated for two size distributions using measured and a synthetic set of optical constants. The results show that tropospheric aerosols consisting of only these organic acids and water have a pure scattering effect.

  13. Optical properties in the UV and visible spectral region of organic acids relevant to tropospheric aerosols

    NASA Astrophysics Data System (ADS)

    Lund Myhre, C. E.; Nielsen, C. J.

    2004-06-01

    Refractive and absorption indices in the UV and visible region of selected aqueous organic acids relevant to tropospheric aerosols are reported. The acids investigated are the aliphatic dicarboxylic acids oxalic, malonic, tartronic, succinic and glutaric acid. In addition we report data for pyruvic, pinonic, benzoic and phthalic acid. To cover a wide range of conditions we have investigated the aqueous organic acids at different concentrations spanning from highly diluted samples to concentrations close to saturation. The density of the investigated samples is reported and a parameterisation of the absorption and refractive index that allows the calculation of the optical constants of mixed aqueous organic acids at different concentrations is presented. The single scattering albedo is calculated for two size distributions using measured and a synthetic set of optical constants. The results show that tropospheric aerosols consisting of only these organic acids and water have a pure scattering effect.

  14. The removal kinetics of dissolved organic matter and the optical clarity of groundwater

    NASA Astrophysics Data System (ADS)

    Chapelle, Francis H.; Shen, Yuan; Strom, Eric W.; Benner, Ronald

    2016-09-01

    Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d-1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d-1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20-75 μM; 0.26-1 mg L-1) and ultraviolet absorption coefficient values ( a 254 < 5 m-1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.

  15. The removal kinetics of dissolved organic matter and the optical clarity of groundwater

    NASA Astrophysics Data System (ADS)

    Chapelle, Francis H.; Shen, Yuan; Strom, Eric W.; Benner, Ronald

    2016-04-01

    Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d-1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d-1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20-75 μM; 0.26-1 mg L-1) and ultraviolet absorption coefficient values (a 254 < 5 m-1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.

  16. APPLYING OPEN-PATH OPTICAL SPECTROSCOPY TO HEAVY-DUTY DIESEL EMISSIONS

    EPA Science Inventory

    Non-dispersive infrared absorption has been used to measure gaseous emissions for both stationary and mobile sources. Fourier transform infrared spectroscopy has been used for stationary sources as both extractive and open-path methods. We have applied the open-path method for bo...

  17. New light-trapping concept by means of several optical components applied to compact holographic 3D concentration solar module

    NASA Astrophysics Data System (ADS)

    Villamarín Villegas, Ayalid M.; Pérez López, Francisco J.; Calo López, Antonio; Rodríguez San Segundo, Hugo-José

    2014-05-01

    A new light-trapping concept is presented, which joins broad bandwidth volume phase reflection holograms (VPRH) working together with three other optical components: specifically designed three-dimensional (3D) cavities, Total Internal Reflection (TIR) within an optical medium, and specular reflection by means of a highly reflective surface. This concept is applied to the design and development of both low concentration photovoltaic (LCPV) and solar thermal modules reaching a concentration factor of up to 3X. Higher concentrations are feasible for use in concentrated solar power (CSP) devices. The whole system is entirely made of polymeric materials (except for the solar cells or fluid carrying pipes), thus reducing cost by up to 40%. The module concentrates solar light onto solar cells - or fluid carrying pipes - with no need for active tracking of the sun, covering the whole seasonal and daily incident angle spectrum while it also minimizes optical losses. In this work we analyze the first experimentally measured optical characteristics and performance of VPRH in dichromated gelatin film (DCG) in our concept. The VPRH can reach high diffraction efficiencies (˜98%, ignoring Fresnel reflection losses). Thanks to specifically designed raw material, coating and developing process specifications, also very broad selective spectral (higher than 300 nm) and angular bandwidths (˜+20º) per grating are achieved. The VPRH was optimized to use silicon solar cells, but designs for other semiconductor devices or for fluid heating are feasible. The 3D shape, the hologram's and reflective surface's optical quality, the TIR effect and the correct coupling of all the components are key to high performance of the concentration solar module.

  18. Ultrafast Rotation of Light Fields Applied to Highly Non-Linear Optics

    NASA Astrophysics Data System (ADS)

    Quéré, Fabien

    2014-05-01

    Femtosecond laser beams can exhibit spatio-temporal couplings (STC), i.e. a temporal dependence of their spatial properties, or vice versa. Although these couplings have long been considered as detrimental for high-intensity and ultrafast experiments, moderate and controlled STC provide a powerful means of controlling high-intensity laser-matter interactions. This talk will first explain the basics of a particular STC, where the propagation direction of laser light rotates in time on the femtosecond time scale. Laser pulses with such ultrafast wavefront rotation can be used to generate attosecond pulses of light through non-linear optical processes. We show that these pulses, periodically generated in each laser cycle, can then be emitted in spatially separated beamlets. This effects provides a new type of light sources called attosecond lighthouses, and can be exploited for ultrafast measurements with femtosecond resolution, in a scheme called photonic streaking.

  19. APPLIED OPTICS. Voltage-tunable circular photogalvanic effect in silicon nanowires.

    PubMed

    Dhara, Sajal; Mele, Eugene J; Agarwal, Ritesh

    2015-08-14

    Electronic bands in crystals can support nontrivial topological textures arising from spin-orbit interactions, but purely orbital mechanisms can realize closely related dynamics without breaking spin degeneracies, opening up applications in materials containing only light elements. One such application is the circular photogalvanic effect (CPGE), which is the generation of photocurrents whose magnitude and polarity depend on the chirality of optical excitation. We show that the CPGE can arise from interband transitions at the metal contacts to silicon nanowires, where inversion symmetry is locally broken by an electric field. Bias voltage that modulates this field further controls the sign and magnitude of the CPGE. The generation of chirality-dependent photocurrents in silicon with a purely orbital-based mechanism will enable new functionalities in silicon that can be integrated with conventional electronics.

  20. Laser-electron beam interaction applied to optical amplifiers and oscillators

    NASA Technical Reports Server (NTRS)

    Pantell, R. H.; Piestrup, M. A.

    1976-01-01

    Momentum modulation of a relativistic electron beam by a Nd:YAG laser is demonstrated. The electrons, at 100 MeV energy, interact with the laser light in helium gas at standard temperature and pressure. At an angle of 6.55 mrad between the two wavevectors, corresponding to the Cerenkov angle, a given electron remains in a field of constant phase as it passes through the light beam. The experimental arrangement is illustrated showing the trajectories of the electron and light. The particle momentum is measured by a mass spectrometer, and the angle between the wavevectors is controlled by a rotatable mirror. Experimental results indicate that momentum modulation of an electron beam may be used for amplification. A possible configuration for an optical klystron is illustrated.

  1. Photodynamics of optical excitations in one-dimensional models for organic salts.

    NASA Astrophysics Data System (ADS)

    Rincon, Julian; Al-Hassanieh, Khaled; Feiguin, Adrian; Dagotto, Elbio

    2015-03-01

    We study the time-dependent evolution of photogenerated optical excitations in a model for organic salts, using the density matrix renormalization group method. The model consists of the quarter-filled one-dimensional extended Peierls-Hubbard Hamiltonian interacting with a classical time-dependent electric field. Our main results show that the overall dynamics of the dominating 4kF bond and charge instabilities corresponds to a gigantic fluctuating behavior as a function of time, whereas the 2kF state remains largely unaffected. These results remain valid regardless of the nature of the optical excitations and whether the system is driven resonantly or not. We compare our calculations with experimental pump-and-probe ultrafast spectroscopy studies of the optical conductivity in organic compounds.

  2. Optical Properties of Fluorescent Mixtures: Comparing Quantum Dots to Organic Dyes

    ERIC Educational Resources Information Center

    Hutchins, Benjamin M.; Morgan, Thomas T.; Ucak-Astarlioglu, Mine G.; Wlilliams, Mary Elizabeth

    2007-01-01

    The study describes and compares the size-dependent optical properties of organic dyes with those of semiconductor nanocrystals or quantum dots (QDs). The analysis shows that mixtures of QDs contain emission colors that are sum of the individual QD components.

  3. Stable inverted small molecular organic solar cells using a p-doped optical spacer.

    PubMed

    Lee, Sang-Hoon; Seo, Ji-Won; Lee, Jung-Yong

    2015-01-01

    We report inverted small molecular organic solar cells using a doped window layer as an optical spacer. The optical spacer was used to shift the optical field distribution inside the active layers, generating more charge carriers from sunlight. In this report, N,N,N',N'-tetrakis(4-methoxyphenyl)-benzidine (MeO-TPD) was doped with 2,2-(perfluoronaphthalene-2,6-diylidene)dimalononitrile (F6-TCNNQ), a p-type dopant material. P-doped MeO-TPD was adopted as an optical spacer because it has a large energy band gap, and its conductivity can be increased by several orders of magnitude through a doping process. As a result, a power conversion efficiency of 4.15% was achieved with the doped window layer of optimized thickness. Lastly, we present significantly improved stability of the inverted devices with the MeO-TPD layer. PMID:25407588

  4. Optical properties of dissolved organic matter (DOM): Effects of biological and photolytic degradation

    USGS Publications Warehouse

    Hansen, Angela; Kraus, Tamara; Pellerin, Brian; Fleck, Jacob; Downing, Bryan D.; Bergamaschi, Brian

    2016-01-01

    Advances in spectroscopic techniques have led to an increase in the use of optical properties (absorbance and fluorescence) to assess dissolved organic matter (DOM) composition and infer sources and processing. However, little information is available to assess the impact of biological and photolytic processing on the optical properties of original DOM source materials. We measured changes in commonly used optical properties and indices in DOM leached from peat soil, plants, and algae following biological and photochemical degradation to determine whether they provide unique signatures that can be linked to original DOM source. Changes in individual optical parameters varied by source material and process, with biodegradation and photodegradation often causing values to shift in opposite directions. Although values for different source materials overlapped at the end of the 111-day lab experiment, multivariate statistical analyses showed that unique optical signatures could be linked to original DOM source material even after degradation, with 17 optical properties determined by discriminant analysis to be significant (p<0.05) in distinguishing between DOM source and environmental processing. These results demonstrate that inferring the source material from optical properties is possible when parameters are evaluated in combination even after extensive biological and photochemical alteration.

  5. Optical Flow Applied to Time-Lapse Image Series to Estimate Glacier Motion in the Southern Patagonia Ice Field

    NASA Astrophysics Data System (ADS)

    Lannutti, E.; Lenzano, M. G.; Toth, C.; Lenzano, L.; Rivera, A.

    2016-06-01

    In this work, we assessed the feasibility of using optical flow to obtain the motion estimation of a glacier. In general, former investigations used to detect glacier changes involve solutions that require repeated observations which are many times based on extensive field work. Taking into account glaciers are usually located in geographically complex and hard to access areas, deploying time-lapse imaging sensors, optical flow may provide an efficient solution at good spatial and temporal resolution to describe mass motion. Several studies in computer vision and image processing community have used this method to detect large displacements. Therefore, we carried out a test of the proposed Large Displacement Optical Flow method at the Viedma Glacier, located at South Patagonia Icefield, Argentina. We collected monoscopic terrestrial time-lapse imagery, acquired by a calibrated camera at every 24 hour from April 2014 until April 2015. A filter based on temporal correlation and RGB color discretization between the images was applied to minimize errors related to changes in lighting, shadows, clouds and snow. This selection allowed discarding images that do not follow a sequence of similarity. Our results show a flow field in the direction of the glacier movement with acceleration in the terminus. We analyzed the errors between image pairs, and the matching generally appears to be adequate, although some areas show random gross errors related to the presence of changes in lighting. The proposed technique allowed the determination of glacier motion during one year, providing accurate and reliable motion data for subsequent analysis.

  6. Versatile optical coherence tomography system applied to the imaging of teeth

    NASA Astrophysics Data System (ADS)

    Amaechi, Bennett T.; Podoleanu, Adrian Gh.; Rogers, John A.; Higham, Susan M.; Dunne, Shane; Jackson, David A.

    2002-06-01

    The utility of a versatile multifunctional standalone Optical Coherence Tomography (OCT)/confocal system for imaging dental tissue was investigated. The system can collect A-scan (reflectivity versus depth graph), longitudinal (B-scan) and en-face (C-scan) OCT images, simultaneously with a confocal image. The power to the sample was 250(mu) W, wavelength (lambda) =850 nm and the depth resolution in air was 16 micrometers . The OCT images showed caries lesions as volumes of reduced reflectivity. Transversal images (C-scan) showed the en-face slices of the tooth tissue like in confocal microscopy. Longitudinal images showed the depth of the lesion into the tooth tissue as well as the different structural layers of sound tooth in the same way as seen in ultrasound images. A-scans performed in locations selected in the en-face images provided quantitative data about the reflectivity versus depth. The confocal channel was extremely useful for guidance and it has also shown the integral of the intensity over depth at transversal locations. We concluded that OCT proved capable to detect an early caries lesion, to show the depth of the lesion into the tissue, and quantitatively assess the degree of demineralization.

  7. Excimer laser ablation lithography applied to the fabrication of reflective diffractive optics

    NASA Astrophysics Data System (ADS)

    Flury, M.; Benatmane, A.; Gérard, P.; Montgomery, P. C.; Fontaine, J.; Engel, T.; Schunck, J. P.; Fogarassy, E.

    2003-03-01

    We propose a low cost technique for the production of diffractive optical elements (DOE). These elements are devoted to high power lasers beam shaping in the mid-infrared wavelengths. This process called laser ablation lithography (LAL), may seem similar to laser beam writing (LBW) in the way the whole DOE's design is reproduced pixel by pixel on the substrate placed on a computer controlled XY translation stage. A first difference is that the photoresist is not exposed with UV light but is directly ablated with short excimer laser pulses. Furthermore, with LAL technique the size of the smallest pixel ( 5 μm×5 μm) is more than 10 times greater than those produced by LBW. We discuss in details the experimental set-up for LAL and demonstrate that it gives a resolution up to 10 times greater than photolithography with flexible masks. This makes LAL a promising solution for the production of DOE for use with Nd:YAG lasers. New applications of DOEs are finally introduced with high power lasers sources, such as laser marking or multi-point brazing.

  8. High Resolution Numerical Model of Optically Heated Float-Zone Crystal Growth with Applied Magnetic Field

    NASA Astrophysics Data System (ADS)

    Huang, Yue; Houchens, Brent

    2008-11-01

    During optically heated float-zone crystal growth processing, thermocapillary forces drive a flow in the melt. This steady, axisymmetric base flow is susceptible to instabilities, resulting in defects as the final crystal is solidified from the melt. To damp these instabilities, a magnetic field is employed. The stability of this flow, neglecting buoyancy, is studied with a full-zone model. The velocity and temperature fields are calculated by a spectral collocation method using Chebyshev polynomials as basis functions. Obtaining accurate base flows is crucial to the success of the subsequent stability analysis. A 2nd order vorticity transport representation is compared with a 4th order stream function representation. At low Hartmann numbers, the results are in good agreement. However, as resolution demands increase, the 2nd order vorticity transport formulation yields a better numerical representation by avoiding large computational errors caused by 4th and 3rd derivatives of Chebyshev terms in the 4th order stream function representation. This allows the stability analysis to be carried out at larger Hartmann numbers, where the critical thermocapillary Reynolds number is much greater.

  9. Organic-based electro-optic modulators for microwave photonic applications

    NASA Astrophysics Data System (ADS)

    Eng, David

    As cutting-edge microwave photonic systems with higher complexity and stringent device requirement are being developed, the demand higher performance modulators with lower drive voltages and higher bandwidth is beginning to overtake the physical limitations of existing modulators based in LiNbO3. To address this growing demand, groundbreaking work in the field of organic electro-optic materials has been achieved over the past 10--15 years that has resulted in materials with electro-optic coefficients up to 10 times that of LiNbO3 and with demonstrated response times into the THz regime. This dissertation details work towards developing low drive-voltage, high bandwidth organic-based electro-optic modulators to support next generation microwave photonic systems. Initial efforts were focused on designing an organic electro-optic material based low frequency phase modulator and developing a fabrication procedure that successfully integrates the material without compromising its electro optic activity. Additionally a procedure for inducing the high electro-optic activity in the waveguide core through a process known as 'poling' was developed. The phase modulators were then characterized to confirm the expected high electro-optic activity and correspondingly low drive voltages. To transition from low frequency modulation to broadband operation it was necessary to gather some dielectric information of the waveguide materials for RF design. Because traditional RF dielectric constant measurements assume thick substrates on the order of 100s of microns, a modified microstrip ring resonator technique was developed to measure the dielectric constant of thin, polymer waveguide films on the order of 10 mum out to 110 GHz. A high frequency traveling wave microstrip modulator was then designed and optimized for operation up to 50 GHz, and efforts were turned towards RF packaging of the microstrip modulators for practical utilization and integration. To feed the RF signals a

  10. Synthesis, linear optical, non-linear optical, thermal and mechanical characterizations of dye-doped semi-organic NLO crystals

    NASA Astrophysics Data System (ADS)

    Sesha Bamini, N.; Vidyalakshmy, Y.; Choedak, Tenzin; Kejalakshmy, N.; Muthukrishnan, P.; Ancy, C. J.

    2015-06-01

    Organic laser dyes Coumarin 485, Coumarin 540 and Rhodamine 590 Chloride were used to dope potassium acid phthalate crystals (KAP). Dye-doped KAP crystals with different dye concentrations such as 0.01 mM, 0.03 mM, 0.05 mM, 0.07 mM and 0.09 mM (in the KAP growth solution) were grown. The linear optical, non-linear optical, mechanical and thermal characterizations of dye-doped KAP crystals were studied and compared to understand the effect of dye and dye concentration on the KAP crystal. Absorption and emission studies of KAP and dye-doped KAP single crystals indicated the inclusion of the dye into the KAP crystal lattice. The effect of dye and its concentration on the SHG efficiency of the KAP crystal was studied using the Kurtz and Perry powder technique. It was observed that the absorption maximum wavelength and concentration of the dye used for doping the KAP single crystal decided the SHG efficiency of the dye-doped KAP single crystals. The mechanical hardness of the dye-doped and undoped (pure) KAP single crystals were studied using the Vickner’s microhardness test. It was observed that doping the KAP crystals with the laser dyes changed them from softer material to harder material. Etching studies showed an improvement in the optical quality of the KAP crystal after doping with laser dyes.

  11. Optical coherence tomography applied to the evaluation of wear of composite resin for posterior teeth

    NASA Astrophysics Data System (ADS)

    Mota, Cláudia C. B. O.; Guerra, Bruna A.; Machado, Brena S. A.; Cabral, Adolfo J.; Gomes, Anderson S. L.

    2015-06-01

    Resin composites are widely used as restorative materials due to their excellent aesthetical and mechanical properties. Posterior teeth are constantly submitted to occlusal stress and upon restoration require more resistant resins. The aim of this study was to analyze in vitro the wear suffered over time by restorations in resin composite in posterior teeth, by Optical Coherence Tomography (OCT). 30 molars had occlusal cavities prepared and were randomly divided into three groups (n=10) and restored with resin composite: G1: Filtek P90 (3M/ESPE), G2: Tetric N-Ceram (Ivoclar Vivadent); G3: Filtek P60 (3M/ESPE). Specimens were subjected to initial analysis by OCT (OCP930SR, Thorlabs, axial resolution 6.2 μm) and stereoscopic microscope. Specimens were submitted to thermocycling (500 cycles, 5-55 °C) and subjected to simulated wear through a machine chewing movements (Wear Machine WM001), projecting four years of use. After mechanical cycles, the specimens were submitted to a second evaluation by the OCT and stereoscopic microscopy. As a result, it was observed that 90% of the restorations of both groups had fractures and/or points of stress concentration, considered niches for early dissemination of new fracture lines. It was also found that G1 and G2 had more points of stress concentration, whereas G3 had a higher incidence of fracture lines already propagated. It was concluded that the G3 showed more brittle behavior at the masticatory wear when compared to G1 and G2.

  12. Integrated electro-optic devices of melt-processable single-crystalline organic films

    NASA Astrophysics Data System (ADS)

    Figi, Harry; Jazbinšek, Mojca; Hunziker, Christoph; Koechlin, Manuel; Günter, Peter

    2010-02-01

    Organic electro-optic (EO) materials are the materials of choice for high speed optical modulators with modulation frequencies greater than 100 GHz. This is due to the large EO effects observed and a low material dispersion of the dielectric constant resulting in a very small velocity mismatch between the optical and electrical waves. However, the implementation of organic materials into real devices has been hindered by several factors such as an insufficient long-term thermal and photochemical stability of the widely investigated poled polymers or the lack of available structuring techniques for the inherently superior organic EO crystalline materials. Here we report on the realization of integrated organic EO single-crystalline Mach-Zehnder modulators by a recently developed melt based channel growth technique. The main fabrication concept is to grow the organic EO singlecrystals from the melt directly in pre-structured and electroded waveguide channels, which were obtained by standard optical lithographic techniques and wafer bonding. By this method single crystal structure details with a size below 30 nm have been achieved and the growth of single-crystalline Mach-Zehnder modulators has been successfully demonstrated, where we have chosen DAT2 (2-(3-(2-(4-dimethylaminophenyl)vinyl)-5,5- dimethylcyclohex-2-enylidene)malononitrile) as EO material. The half-wave voltage × length product determined in the DAT2 based Mach-Zehnder modulators has been found to be 78 +/- 2 Vcm for TE-modes and 60 +/-1 Vcm for TM-modes at a wavelength of 1.55 μm. The accuracy and reproducibility of the process allowed also for the realization of the first EO single-crystalline microring resonator in an organic material.

  13. Electro-Optic Modulator Based on Organic Planar Waveguide Integrated with Prism Coupler

    NASA Technical Reports Server (NTRS)

    Sarkisov, Sergey S.

    2002-01-01

    The objectives of the project, as they were formulated in the proposal, are the following: (1) Design and development of novel electro-optic modulator using single crystalline film of highly efficient electro-optic organic material integrated with prism coupler; (2) Experimental characterization of the figures-of-merit of the modulator. It is expected to perform with an extinction ratio of 10 dB at a driving signal of 5 V; (3) Conclusions on feasibility of the modulator as an element of data communication systems of future generations. The accomplishments of the project are the following: (1) The design of the electro-optic modulator based on a single crystalline film of organic material NPP has been explored; (2) The evaluation of the figures-of-merit of the electro-optic modulator has been performed; (3) Based on the results of characterization of the figures-of-merit, the conclusion was made that the modulator based on a thin film of NPP is feasible and has a great potential of being used in optic communication with a modulation bandwidth of up to 100 GHz and a driving voltage of the order of 3 to 5 V.

  14. Blob identification algorithms applied to laser speckle to characterize optical turbulence

    NASA Astrophysics Data System (ADS)

    Cauble, Galen D.; Wayne, David T.

    2015-09-01

    Laser beam speckle resulting from atmospheric turbulence contains information about the propagation channel. The number and size of the speckle cells can be used to infer the spatial coherence and thus the Cn2 along a path. The challenge with this technique is the rapidly evolving speckle pattern and non-uniformity of the speckle cells. In this paper we investigate modern blob counting techniques used in biology, microscopy, and medical imaging. These methods are then applied to turbulent speckle images to estimate the number and size of the speckle cells. Speckle theory is reviewed for different beam types and different regimes of turbulence. Algorithms are generated to calculate path Cn2 from speckle information and path geometry. The algorithms are tested on speckle images from experimental data collected over a turbulent 1km path and compared to Cn2 measurements collected in parallel.

  15. Integrated optical and electrical modeling of plasmon-enhanced thin film photovoltaics: A case-study on organic devices

    SciTech Connect

    Rourke, D; Ahn, S; Nardes, AM; van de Lagemaat, J; Kopidakis, N; Park, W

    2014-09-21

    The nanoscale light control for absorption enhancement of organic photovoltaic (OPV) devices inevitably produces strongly non-uniform optical fields. These non-uniformities due to the localized optical modes are a primary route toward absorption enhancement in OPV devices. Therefore, a rigorous modeling tool taking into account the spatial distribution of optical field and carrier generation is necessary. Presented here is a comprehensive numerical model to describe the coupled optical and electrical behavior of plasmon-enhanced polymer: fullerene bulk heterojunction (BHJ) solar cells. In this model, a position-dependent electron-hole pair generation rate that could become highly non-uniform due to photonic nanostructures is directly calculated from the optical simulations. By considering the absorption and plasmonic properties of nanophotonic gratings included in two different popular device architectures, and applying the Poisson, current continuity, and drift/diffusion equations, the model predicts quantum efficiency, short-circuit current density, and desired carrier mobility ratios for bulk heterojunction devices incorporating nanostructures for light management. In particular, the model predicts a significant degradation of device performance when the carrier species with lower mobility are generated far from the collecting electrode. Consequently, an inverted device architecture is preferred for materials with low hole mobility. This is especially true for devices that include plasmonic nanostructures. Additionally, due to the incorporation of a plasmonic nanostructure, we use simulations to theoretically predict absorption band broadening of a BHJ into energies below the band gap, resulting in a 4.8% increase in generated photocurrent. (C) 2014 AIP Publishing LLC.

  16. Optical Measurements and Modeling to Estimate Concentrations and Fluxes of Organic Matter in the Southern Ocean

    NASA Technical Reports Server (NTRS)

    Stramski, Dariusz; Mitchell, B. Greg; Marra, John W. (Technical Monitor)

    2001-01-01

    This project was a collaboration between two Principal Investigators, Dr. Dariusz Stramski and Dr. Greg Mitchell of Scripps Institution of Oceanography, University of California San Diego. Our overall goal was to conduct optical measurements and modeling to estimate concentrations of organic matter in the Southern Ocean in support of the U.S. JGOFS Process Study in this region. Key variables and processes of high relevance to accomplish the JGOFS goals include time and space resolution of phytoplankton pigments, particulate organic carbon, and the formation and export of organic carbon. Our project focused on establishing the fundamental relationships for parameterization of these variables and processes in terms of the optical properties of seawater, and developing understanding of why the Southern Ocean differs from other low-latitude systems, or has differentiation within. Our approach builds upon historical observations that optical properties provide a useful proxy for key reservoirs of organic matter such as chlorophyll alpha (Chl) and particulate organic carbon (POC) concentrations, which are of relevance to the JGOFS objectives. We carried out detailed studies of in situ and water sample optical properties including spectral reflectance, absorption, beam attenuation, scattering, and backscattering coefficients. We evaluated the ability to estimate Chl from the spectral reflectance (ocean color) in the Southern Ocean. We examined relationships between the ocean optical properties and particulate organic carbon. We developed, for the first time, an algorithm for estimating particulate organic carbon concentration in the surface ocean from satellite imagery of ocean color. With this algorithm, we obtained maps of POC distribution in the Southern Ocean showing the seasonal progression of POC in the austral spring-summer season. We also developed a semianalytical reflectance model for the investigated polar waters based on our field measurements of absorption

  17. Third order optical nonlinearities characteristics of Disperse Red1 organic dye molecules inside of polymeric nanocapsules

    NASA Astrophysics Data System (ADS)

    Sharifimehr, Mohammad Reza; Ayoubi, Kazem; Mohajerani, Ezeddin

    2015-11-01

    Measuring nonlinear optical response of a specific material in a mixture, not only leads to investigate the behavior of a particular component in various circumstances, but also can be a way to select suitable combination and optimum concentration of additives and therefore obtaining the maximum nonlinear optical signals. In this work, by using dual-arm Z-scan technique, the nonlinear refractive index of Disperse Red1 (DR1) organic dye molecules inside the core of prepared polymeric nanocapsules was measured among various materials which prepared nanocapsules were made of them. Then the measured value was compared with nonlinear refractive index of DR1 solved in dichloromethane.

  18. Optical modeling of organic solar cells based on rubrene and C70.

    PubMed

    Cao, Jing; Zhan, Zhen; Hou, Lintao; Long, Yongbing; Liu, Pengyi; Mai, Wenjie

    2012-08-10

    Optical modeling based on the transfer matrix method is employed to investigate the performance of the organic planar heterojunction solar cell with rubrene/C70 as the active layer. The detailed investigation is directed into the effects of layer thickness of the rubrene and C70 on the total absorbed photon density in the active layer. It is revealed that the optical interference plays important role in the performance of the device and the optimal device performance is achieved when the thicknesses of the rubrene and C70 are set as 33 and 28 nm. The simulated results are also confirmed by the experimental data. PMID:22885586

  19. Electro-optical techniques for the investigation of photoplethysmographic signals in human abdominal organs

    NASA Astrophysics Data System (ADS)

    Kyriacou, P. A.; Crerar-Gilber, A.; Langford, R. M.; Jones, D. P.

    2006-07-01

    There is a need for reliable continuous monitoring of abdominal organ oxygen saturation (SpO2). Splanchnic ischaemia may ultimately lead to cellular hypoxia and necrosis and may well contribute to the development of multiple organ failures and increased mortality. A new reflectance electro-optical photoplethysmographic (PPG) probe and signal processing system were developed. PPG signals from abdominal organs (bowel, liver, and kidney) and the finger were obtained from 12 anaesthetised patients. The amplitudes of the abdominal organ PPGs were, on average, approximately the same as those obtained simultaneously from the finger. These observations suggest that pulse oximetry may be a valid monitoring technique for abdominal organs such as the bowel liver and kidney.

  20. When families talk: applying interpretative phenomenological analysis to African American families discussing their awareness, commitment, and knowledge of organ donation.

    PubMed

    Long, Shawn D; Morgan, Susan E; Harrison, Tyler; Afifi, Walid A; Stephenson, Michael; Reichert, Tom; Morse, Chris

    2012-01-01

    This paper applies interpretative phenomenological analysis as a tool to understand ways African American families discuss and make sense of their knowledge, awareness, and commitment of the organ donation process. African American families (n = 20) participated in self-directed conversations based on the organ donor model, which is grounded in the theory of reasoned action and the theory of motivated information management. Results indicate that the media strongly influences an individual's willingness to participate in the organ donation process and their commitment to further discuss their decisions with close family members. Greater attention should be given to cultural-specific campaigns to increase the number of African American donors. PMID:23560358

  1. Menzerath-Altmann Law: Statistical Mechanical Interpretation as Applied to a Linguistic Organization

    NASA Astrophysics Data System (ADS)

    Eroglu, Sertac

    2014-10-01

    The distribution behavior described by the empirical Menzerath-Altmann law is frequently encountered during the self-organization of linguistic and non-linguistic natural organizations at various structural levels. This study presents a statistical mechanical derivation of the law based on the analogy between the classical particles of a statistical mechanical organization and the distinct words of a textual organization. The derived model, a transformed (generalized) form of the Menzerath-Altmann model, was termed as the statistical mechanical Menzerath-Altmann model. The derived model allows interpreting the model parameters in terms of physical concepts. We also propose that many organizations presenting the Menzerath-Altmann law behavior, whether linguistic or not, can be methodically examined by the transformed distribution model through the properly defined structure-dependent parameter and the energy associated states.

  2. Parallel optical read-out of micromechanical pillars applied to prostate specific membrane antigen detection.

    PubMed

    Tardivo, Martina; Toffoli, Valeria; Fracasso, Giulio; Borin, Daniele; Dal Zilio, Simone; Colusso, Andrea; Carrato, Sergio; Scoles, Giacinto; Meneghetti, Moreno; Colombatti, Marco; Lazzarino, Marco

    2015-10-15

    Micro and nanomechanical resonators represent a promising platform for proteins label-free detection because of their extreme sensitivity, fast response and low cost. Micro-pillars are columnar resonators that can be easily arranged in dense arrays of several thousand sensors in a squared mm. To exploit such a large density, however, a method for tracking independently micropillars resonance frequency is required. Here we present a detection method based on CCD imaging and software image analysis, which can measure the resonance frequency of tens of pillars in parallel. Acquiring simultaneously the frequency shift of up to 40 sensors and applying a proper statistical analysis, we were able to overcome the variability of the single measures improving the device sensitivity at low analyte concentration range. As a proof of concept, this method has been tested for the detection of a tumor marker, the Prostate Specific Membrane Antigen (PSMA). Pillars have been functionalized with an antibody against PSMA. The tumor marker (PSMA) has been detected in a range of concentrations between 300 pM and 100 nM, in buffer and in diluted bovine serum. The sensitivity of our method was limited only by the affinity constant of the antigen-antibody recognition. Moreover, this detection technique demonstrated to be effective in the 1-6 nM range, which is the window of PSMA concentration of clinical interest.

  3. A polypeptide-DNA hybrid with selective linking capability applied to single molecule nano-mechanical measurements using optical tweezers.

    PubMed

    Moayed, Fatemeh; Mashaghi, Alireza; Tans, Sander J

    2013-01-01

    Many applications in biosensing, biomaterial engineering and single molecule biophysics require multiple non-covalent linkages between DNA, protein molecules, and surfaces that are specific yet strong. Here, we present a novel method to join proteins and dsDNA molecule at their ends, in an efficient, rapid and specific manner, based on the recently developed linkage between the protein StrepTactin (STN) and the peptide StrepTag II (ST). We introduce a two-step approach, in which we first construct a hybrid between DNA and a tandem of two STs peptides (tST). In a second step, this hybrid is linked to polystyrene bead surfaces and Maltose Binding Protein (MBP) using STN. Furthermore, we show the STN-tST linkage is more stable against forces applied by optical tweezers than the commonly used biotin-Streptavidin (STV) linkage. It can be used in conjunction with Neutravidin (NTV)-biotin linkages to form DNA tethers that can sustain applied forces above 65 pN for tens of minutes in a quarter of the cases. The method is general and can be applied to construct other surface-DNA and protein-DNA hybrids. The reversibility, high mechanical stability and specificity provided by this linking procedure make it highly suitable for single molecule mechanical studies, as well as biosensing and lab on chip applications.

  4. Studying the reversal mode of the magnetization vector versus applied field angle using generalized magneto-optical ellipsometry

    SciTech Connect

    Pufall, M. R.; Berger, A.

    1999-10-26

    The authors used the technique of vector Generalized Magneto-optical Ellipsometry to study the behavior of the magnetization vector of a 50 Co thin film as a function of external field magnitude and direction. With this method, which determines the both the direction and magnitude of the magnetization, averaged over the 1 mm incident laser beam, they were able to determine the relative contributions of magnetization rotation and domain formation to the reversal of M. The Co sample had a uniaxial in-plane anisotropy. The authors found that when the angle between the applied field and the easy axis was greater than {approximately} 40 degrees, the reversal occurred primarily by rotation of the magnetization, accompanied by a small reduction of the magnitude of M. In this angular region, the critical field-the field at which there is a large jump in the angle of M -- as a function of applied field angle followed a coherent rotation model. However, at applied field angles less than 40 degrees to the easy axis, they found a larger reduction in {vert_bar}M{vert_bar} occurring before and during the jump in the magnetization angle. The jump also occurred at fields much lower than those predicted by the coherent rotation model, indicating a reversal mode initiated by domain formation.

  5. A Polypeptide-DNA Hybrid with Selective Linking Capability Applied to Single Molecule Nano-Mechanical Measurements Using Optical Tweezers

    PubMed Central

    Tans, Sander J.

    2013-01-01

    Many applications in biosensing, biomaterial engineering and single molecule biophysics require multiple non-covalent linkages between DNA, protein molecules, and surfaces that are specific yet strong. Here, we present a novel method to join proteins and dsDNA molecule at their ends, in an efficient, rapid and specific manner, based on the recently developed linkage between the protein StrepTactin (STN) and the peptide StrepTag II (ST). We introduce a two-step approach, in which we first construct a hybrid between DNA and a tandem of two STs peptides (tST). In a second step, this hybrid is linked to polystyrene bead surfaces and Maltose Binding Protein (MBP) using STN. Furthermore, we show the STN-tST linkage is more stable against forces applied by optical tweezers than the commonly used biotin-Streptavidin (STV) linkage. It can be used in conjunction with Neutravidin (NTV)-biotin linkages to form DNA tethers that can sustain applied forces above 65 pN for tens of minutes in a quarter of the cases. The method is general and can be applied to construct other surface-DNA and protein-DNA hybrids. The reversibility, high mechanical stability and specificity provided by this linking procedure make it highly suitable for single molecule mechanical studies, as well as biosensing and lab on chip applications. PMID:23336001

  6. 20 CFR 641.620 - How may an organization apply for pilot, demonstration, and evaluation project funding?

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ..., demonstration, and evaluation project funding? 641.620 Section 641.620 Employees' Benefits EMPLOYMENT AND TRAINING ADMINISTRATION, DEPARTMENT OF LABOR PROVISIONS GOVERNING THE SENIOR COMMUNITY SERVICE EMPLOYMENT PROGRAM Pilot, Demonstration, and Evaluation Projects § 641.620 How may an organization apply for...

  7. 20 CFR 641.620 - How may an organization apply for pilot, demonstration, and evaluation project funding?

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ..., demonstration, and evaluation project funding? 641.620 Section 641.620 Employees' Benefits EMPLOYMENT AND TRAINING ADMINISTRATION, DEPARTMENT OF LABOR PROVISIONS GOVERNING THE SENIOR COMMUNITY SERVICE EMPLOYMENT PROGRAM Pilot, Demonstration, and Evaluation Projects § 641.620 How may an organization apply for...

  8. 20 CFR 641.620 - How may an organization apply for pilot, demonstration, and evaluation project funding?

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ..., demonstration, and evaluation project funding? 641.620 Section 641.620 Employees' Benefits EMPLOYMENT AND TRAINING ADMINISTRATION, DEPARTMENT OF LABOR PROVISIONS GOVERNING THE SENIOR COMMUNITY SERVICE EMPLOYMENT PROGRAM Pilot, Demonstration, and Evaluation Projects § 641.620 How may an organization apply for...

  9. 20 CFR 641.620 - How may an organization apply for pilot, demonstration, and evaluation project funding?

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ..., demonstration, and evaluation project funding? 641.620 Section 641.620 Employees' Benefits EMPLOYMENT AND TRAINING ADMINISTRATION, DEPARTMENT OF LABOR PROVISIONS GOVERNING THE SENIOR COMMUNITY SERVICE EMPLOYMENT PROGRAM Pilot, Demonstration, and Evaluation Projects § 641.620 How may an organization apply for...

  10. 42 CFR 60.30 - Which organizations are eligible to apply to be HEAL lenders and holders?

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 1 2013-10-01 2013-10-01 false Which organizations are eligible to apply to be HEAL lenders and holders? 60.30 Section 60.30 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GRANTS HEALTH EDUCATION ASSISTANCE LOAN PROGRAM The Lender and Holder § 60.30...

  11. 42 CFR 60.30 - Which organizations are eligible to apply to be HEAL lenders and holders?

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 1 2014-10-01 2014-10-01 false Which organizations are eligible to apply to be HEAL lenders and holders? 60.30 Section 60.30 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GRANTS HEALTH EDUCATION ASSISTANCE LOAN PROGRAM The Lender and Holder § 60.30...

  12. 42 CFR 60.30 - Which organizations are eligible to apply to be HEAL lenders and holders?

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 1 2011-10-01 2011-10-01 false Which organizations are eligible to apply to be HEAL lenders and holders? 60.30 Section 60.30 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GRANTS HEALTH EDUCATION ASSISTANCE LOAN PROGRAM The Lender and Holder § 60.30...

  13. 42 CFR 60.30 - Which organizations are eligible to apply to be HEAL lenders and holders?

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 1 2012-10-01 2012-10-01 false Which organizations are eligible to apply to be HEAL lenders and holders? 60.30 Section 60.30 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GRANTS HEALTH EDUCATION ASSISTANCE LOAN PROGRAM The Lender and Holder § 60.30...

  14. 42 CFR 60.30 - Which organizations are eligible to apply to be HEAL lenders and holders?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 1 2010-10-01 2010-10-01 false Which organizations are eligible to apply to be HEAL lenders and holders? 60.30 Section 60.30 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES GRANTS HEALTH EDUCATION ASSISTANCE LOAN PROGRAM The Lender and Holder § 60.30...

  15. 25 CFR 900.43 - What are the general financial management system standards that apply to a tribal organization...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 25 Indians 2 2010-04-01 2010-04-01 false What are the general financial management system... ASSISTANCE ACT Standards for Tribal or Tribal Organization Management Systems Standards for Financial Management Systems § 900.43 What are the general financial management system standards that apply to a...

  16. 25 CFR 900.43 - What are the general financial management system standards that apply to a tribal organization...

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 2 2013-04-01 2013-04-01 false What are the general financial management system... ASSISTANCE ACT Standards for Tribal or Tribal Organization Management Systems Standards for Financial Management Systems § 900.43 What are the general financial management system standards that apply to a...

  17. 25 CFR 900.43 - What are the general financial management system standards that apply to a tribal organization...

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 25 Indians 2 2012-04-01 2012-04-01 false What are the general financial management system... ASSISTANCE ACT Standards for Tribal or Tribal Organization Management Systems Standards for Financial Management Systems § 900.43 What are the general financial management system standards that apply to a...

  18. 25 CFR 900.43 - What are the general financial management system standards that apply to a tribal organization...

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 2 2011-04-01 2011-04-01 false What are the general financial management system... ASSISTANCE ACT Standards for Tribal or Tribal Organization Management Systems Standards for Financial Management Systems § 900.43 What are the general financial management system standards that apply to a...

  19. 25 CFR 900.43 - What are the general financial management system standards that apply to a tribal organization...

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 25 Indians 2 2014-04-01 2014-04-01 false What are the general financial management system... ASSISTANCE ACT Standards for Tribal or Tribal Organization Management Systems Standards for Financial Management Systems § 900.43 What are the general financial management system standards that apply to a...

  20. Hybrid organic/inorganic copolymers with strongly hydrogen-bond acidic properties for acoustic wave and optical sensors

    SciTech Connect

    Grate, J.W.; Kaganove, S.N.; Patrash, S.J.

    1997-05-01

    Hybrid organic/inorganic polymers have been prepared incorporating fluoroalkyl-substituted bisphenol groups linked using oligosiloxane spacers. These hydrogen-bond acidic materials have glass-to-rubber transition temperatures below room temperature and are excellent sorbents for basic vapors. The physical properties such as viscosity and refractive index can be tuned by varying the length of the oligosiloxane spacers and the molecular weight. In addition, the materials are easily cross-linked to yield solid elastomers. The potential use of these materials for chemical sensing has been demonstrated by applying them to surface acoustic wave devices as thin films and detecting the hydrogen-bond basic vapor dimethyl methylphosphonate with high sensitivity. It has also been demonstrated that one of these materials with suitable viscosity and refractive index can be used to clad silica optical fibers; the cladding was applied to freshly drawn fiber using a fiber drawing tower. These fibers have potential as evanescent wave optical fiber sensors. 38 refs., 2 figs.

  1. Optically and electrically driven organic thin film transistors with diarylethene photochromic channel layers.

    PubMed

    Hayakawa, Ryoma; Higashiguchi, Kenji; Matsuda, Kenji; Chikyow, Toyohiro; Wakayama, Yutaka

    2013-05-01

    We achieved drain-current switching of diarylethene-channel field-effect transistors with light- and electric-field effects. The drain current was reversibly changed by alternating ultraviolet and visible light irradiation. Stress is placed on the fact that the on/off ratio realized by light irradiation was 1 × 10(2) (1 × 10(4)%) and this value is much larger than those in other photochromism-based transistors. These results indicate that the drain current was effectively controlled by light irradiation. Furthermore, the on and off states modulated by light were maintained without light irradiation even after 1 week, exhibiting that our transistor works as an optical memory. We clarified that the light-driven modulation can be attributed to the transformation in the π-conjugation system accompanied by photoisomerization. These findings have the potential to attain high-performance optoelectrical organic devices including optical sensors, optical memory, and photoswitching transistors.

  2. Feasibility of a feedback control of atomic self-organization in an optical cavity

    SciTech Connect

    Ivanov, D. A. Ivanova, T. Yu.

    2015-08-15

    Many interesting nonlinear effects are based on the strong interaction of motional degrees of freedom of atoms with an optical cavity field. Among them is the spatial self-organization of atoms in a pattern where the atoms group in either odd or even sites of the cavity-induced optical potential. An experimental observation of this effect can be simplified by using, along with the original cavity-induced feedback, an additional electronic feedback based on the detection of light leaking the cavity and the control of the optical potential for the atoms. Following our previous study, we show that this approach is more efficient from the laser power perspective than the original scheme without the electronic feedback.

  3. Integrated optical frequency shifter in silicon-organic hybrid (SOH) technology.

    PubMed

    Lauermann, M; Weimann, C; Knopf, A; Heni, W; Palmer, R; Koeber, S; Elder, D L; Bogaerts, W; Leuthold, J; Dalton, L R; Rembe, C; Freude, W; Koos, C

    2016-05-30

    We demonstrate for the first time a waveguide-based frequency shifter on the silicon photonic platform using single-sideband modulation. The device is based on silicon-organic hybrid (SOH) electro-optic modulators, which combine conventional silicon-on-insulator waveguides with highly efficient electro-optic cladding materials. Using small-signal modulation, we demonstrate frequency shifts of up to 10 GHz. We further show large-signal modulation with optimized waveforms, enabling a conversion efficiency of -5.8 dB while suppressing spurious side-modes by more than 23 dB. In contrast to conventional acousto-optic frequency shifters, our devices lend themselves to large-scale integration on silicon substrates, while enabling frequency shifts that are several orders of magnitude larger than those demonstrated with all-silicon serrodyne devices. PMID:27410095

  4. Growth and characterization of an organic nonlinear optical material: L-Histidine malonate

    NASA Astrophysics Data System (ADS)

    Ramya, K.; Saraswathi, N. T.; Raja, C. Ramachandra

    2016-10-01

    L-Histidine malonate is one of the potential organic material for nonlinear optical applications. Single crystals of L-Histidine malonate were grown by the liquid diffusion method. The lattice parameter values were evaluated from single crystal X-ray diffraction technique. The Fourier Transform Infra Red and Raman spectral studies were employed to identify the different modes of vibrations of molecular groups in the crystal. Optical characterization and the percentage of optical transmission were recorded using UV-vis-NIR spectroscopy. The molecular structure was established by proton and carbon Nuclear magnetic resonance spectral studies. The thermal behavior of the material has been studied by Thermo gravimetric and Differential thermal plots. The second harmonic generation conversion efficiency was found out from the powder technique of Kurtz and Perry.

  5. Optical and morphological characteristics of organic thin films for optoelectronic devices

    NASA Astrophysics Data System (ADS)

    Zhong, Zhiyou; Sun, Fenglou

    2007-12-01

    Organic semiconductor thin films of tri-(8-hydroxyquinoline)-aluminum (Alq), 9,10-di-(2-naphthyl)-anthracene (ADN), and N,N'bis(naphthalen-1-yl)-N,N'bis(phenyl)-benzidine (NPB) for optoelectronic devices were deposited onto glass substrates by vacuum sublimation technique. The surface morphology and roughness of the thin film were characterized by means of atomic force microscopy (AFM). Experimental results indicate that all thin films present similar granular topography but different surface roughness. In addition, the optical transmittance spectra of thin films were measured by a double beam spectrophotometer and their corresponding optical properties were investigated. The complex refractive index and the optical band gap of thin films were obtained, respectively. Meanwhile, the dispersion behavior of the refractive index was studied in terms of Wemple-DiDomenico single oscillator model, and the oscillator parameters were achieved.

  6. The design of the CMOS wireless bar code scanner applying optical system based on ZigBee

    NASA Astrophysics Data System (ADS)

    Chen, Yuelin; Peng, Jian

    2008-03-01

    The traditional bar code scanner is influenced by the length of data line, but the farthest distance of the wireless bar code scanner of wireless communication is generally between 30m and 100m on the market. By rebuilding the traditional CCD optical bar code scanner, a CMOS code scanner is designed based on the ZigBee to meet the demands of market. The scan system consists of the CMOS image sensor and embedded chip S3C2401X, when the two dimensional bar code is read, the results show the inaccurate and wrong code bar, resulted from image defile, disturber, reads image condition badness, signal interference, unstable system voltage. So we put forward the method which uses the matrix evaluation and Read-Solomon arithmetic to solve them. In order to construct the whole wireless optics of bar code system and to ensure its ability of transmitting bar code image signals digitally with long distances, ZigBee is used to transmit data to the base station, and this module is designed based on image acquisition system, and at last the wireless transmitting/receiving CC2430 module circuit linking chart is established. And by transplanting the embedded RTOS system LINUX to the MCU, an applying wireless CMOS optics bar code scanner and multi-task system is constructed. Finally, performance of communication is tested by evaluation software Smart RF. In broad space, every ZIGBEE node can realize 50m transmission with high reliability. When adding more ZigBee nodes, the transmission distance can be several thousands of meters long.

  7. Development of resonator analysis applied in hybrid slab laser with consideration of optical gain and thermal lens effect.

    PubMed

    Ma, Xingkun; Huang, Lei; Gong, Mali; Liu, Qiang; Zhang, Haitao; Yan, Ping

    2013-07-10

    By introducing the rate equations and light intensity propagating equations into the fast Fourier transform-based calculation, the optical gain served as the connection between the light field and light intensity, its influence over mode pattern was studied. Thermal lens effect was also investigated by means of finite element analysis. The analysis was applied to a slab laser with a hybrid cavity. A similar experimental study was also carried out in the laboratory. TEM(00) mode with sidelobes along the unstable direction was observed both in the calculation and experiment. As predicted in the analysis, the homogeneity of the pump light improved the beam quality. Numerical and experimental results of pump threshold and slope efficiency were also presented. PMID:23852199

  8. Development studies towards an 11-year global gridded aerosol optical thickness reanalysis for climate and applied applications

    NASA Astrophysics Data System (ADS)

    Lynch, P.; Reid, J. S.; Westphal, D. L.; Zhang, J.; Hogan, T. F.; Hyer, E. J.; Curtis, C. A.; Hegg, D. A.; Shi, Y.; Campbell, J. R.; Rubin, J. I.; Sessions, W. R.; Turk, F. J.; Walker, A. L.

    2015-12-01

    While standalone satellite and model aerosol products see wide utilization, there is a significant need in numerous climate and applied applications for a fused product on a regular grid. Aerosol data assimilation is an operational reality at numerous centers, and like meteorological reanalyses, aerosol reanalyses will see significant use in the near future. Here we present a standardized 2003-2013 global 1° × 1° and 6 hourly modal aerosol optical thickness (AOT) reanalysis product. This dataset can be applied to basic and applied earth system science studies of significant aerosol events, aerosol impacts on numerical weather prediction, and electro-optical propagation and sensor performance, among other uses. This paper describes the science of how to develop and score an aerosol reanalysis product. This reanalysis utilizes a modified Navy Aerosol Analysis and Prediction System (NAAPS) at its core and assimilates quality controlled retrievals of AOT from the Moderate Resolution Imaging Spectroradiometer (MODIS) on Terra and Aqua and the Multi-angle Imaging SpectroRadiometer (MISR) on Terra. The aerosol source functions, including dust and smoke, were regionally tuned to obtain the best match between the model fine and coarse mode AOTs and the Aerosol Robotic Network (AERONET) AOTs. Other model processes, including deposition, were tuned to minimize the AOT difference between the model and satellite AOT. Aerosol wet deposition in the tropics is driven with satellite retrieved precipitation, rather than the model field. The final reanalyzed fine and coarse mode AOT at 550 nm is shown to have good agreement with AERONET observations, with global mean root mean square error around 0.1 for both fine and coarse mode AOTs. This paper includes a discussion of issues particular to aerosol reanalyses that make them distinct from standard meteorological reanalyses, considerations for extending such a reanalysis outside of the NASA A-Train era, and examples of how the

  9. Moisture resistant and anti-reflection optical coatings produced by plasma polymerization of organic compounds

    NASA Technical Reports Server (NTRS)

    Hollahan, J. R.; Wydeven, T.

    1975-01-01

    The need for protective coatings on critical optical surfaces, such as halide crystal windows or lenses used in spectroscopy, has long been recognized. It has been demonstrated that thin, one micron, organic coatings produced by polymerization of flourinated monomers in low temperature gas discharge (plasma) exhibit very high degrees of moisture resistence, e.g., hundreds of hours protection for cesium iodide vs. minutes before degradation sets in for untreated surfaces. The index of refraction of these coatings is intermediate between that of the halide substrate and air, a condition for anti-reflection, another desirable property of optical coatings. Thus, the organic coatings not only offer protection, but improved transmittance as well. The polymer coating is non-absorbing over the range 0.4 to 40 microns with an exception at 8.0 microns, the expected absorption for C-F bonds.

  10. Intrinsic fiber optic absorption sensor for the detection of volatile organic compounds

    NASA Astrophysics Data System (ADS)

    Klunder, Gregory L.; Silva, Robert J.; Russo, Richard E.

    1994-03-01

    A core-based intrinsic fiber optic absorption sensor has been developed for the detection of volatile organic compounds. The sensor can detect organics in aqueous solutions or in the vapor phase without a chemical reaction. The distal ends of transmission and receiving fibers are connected by a small section of an optically clear silicone rubber. The silicone rubber section acts both as a lightpipe and as a selective membrane into which the analyte molecules can diffuse. Absorption spectra obtained in the nearinfrared (NIR) provide qualitative and quantitative information about the analyte. Water, which has strong broadband absorption in aqueous solutions of the NIR, is excluded from the spectra due to the hydrophobic properties of the silicone rubber. In a stirred solution, the sensor reaches equilibrium in approximately 10 minutes. The current limit of detection is 1.0 ppm for TCE in an aqueous solution.

  11. Zeolite-fiber integrated optical chemical sensors for detection of dissolved organics in water.

    PubMed

    Zhang, Jian; Dong, Junhang; Luo, Ming; Xiao, Hai; Murad, Sohail; Normann, Randy A

    2005-09-13

    MFI zeolite coated optical fiber sensors have been developed for in situ detection of dissolved organics in water. The sensors operate by monitoring the optical reflectivity changes caused by the selective adsorption of organic molecules, i.e., 2-propanol or pentanoic acid in this study, from aqueous solutions in the zeolitic pores. Reversible and monotonic sensor signals were observed in response to the variation of 2-propanol concentration in water with fast response. However, the sensor exhibited a much slower response to pentanoic acid than to 2-propanol. It was also found that substitution of Si by Al in the MFI framework increased the adsorption of pentanoic acid that resulted in enhanced sensor responses.

  12. Self-Organization of Light in Optical Media with Competing Nonlinearities

    NASA Astrophysics Data System (ADS)

    Maucher, F.; Pohl, T.; Skupin, S.; Krolikowski, W.

    2016-04-01

    We study the propagation of light beams through optical media with competing nonlocal nonlinearities. We demonstrate that the nonlocality of competing focusing and defocusing nonlinearities gives rise to self-organization and stationary states with stable hexagonal intensity patterns, akin to transverse crystals of light filaments. Signatures of this long-range ordering are shown to be observable in the propagation of light in optical waveguides and even in free space. We consider a specific form of the nonlinear response that arises in atomic vapor upon proper light coupling. Yet, the general phenomenon of self-organization is a generic consequence of competing nonlocal nonlinearities, and may, hence, also be observed in other settings.

  13. Self-Organization of Light in Optical Media with Competing Nonlinearities.

    PubMed

    Maucher, F; Pohl, T; Skupin, S; Krolikowski, W

    2016-04-22

    We study the propagation of light beams through optical media with competing nonlocal nonlinearities. We demonstrate that the nonlocality of competing focusing and defocusing nonlinearities gives rise to self-organization and stationary states with stable hexagonal intensity patterns, akin to transverse crystals of light filaments. Signatures of this long-range ordering are shown to be observable in the propagation of light in optical waveguides and even in free space. We consider a specific form of the nonlinear response that arises in atomic vapor upon proper light coupling. Yet, the general phenomenon of self-organization is a generic consequence of competing nonlocal nonlinearities, and may, hence, also be observed in other settings.

  14. UV/Vis visible optical waveguides fabricated using organic-inorganic nanocomposite layers.

    PubMed

    Simone, Giuseppina; Perozziello, Gerardo

    2011-03-01

    Nanocomposite layers based on silica nanoparticles and a methacrylate matrix are synthesized by a solvent-free process and characterized in order to realize UV/Vis transparent optical waveguides. Chemical functionalization of the silica nanoparticles permits to interface the polymers and the silica. The refractive index, roughness and wettability and the machinability of the layers can be tuned changing the silica nanoparticle concentration and chemical modification of the surface of the nanoparticles. The optical transparency of the layers is affected by the nanoparticles organization between the organic chains, while it increased proportionally with respect to silica concentration. Nanocomposite layers with a concentration of 40 wt% in silica reached UV transparency for a wavelength of 250 nm. UV/Vis transparent waveguides were micromilled through nanocomposite layers and characterized. Propagation losses were measured to be around 1 dB cm(-1) at a wavelength of 350 nm.

  15. A Comprehensive Dust Model Applied to the Resolved Beta Pictoris Debris Disk from Optical to Radio Wavelengths

    NASA Astrophysics Data System (ADS)

    Ballering, Nicholas P.; Su, Kate Y. L.; Rieke, George H.; Gáspár, András

    2016-06-01

    We investigate whether varying the dust composition (described by the optical constants) can solve a persistent problem in debris disk modeling—the inability to fit the thermal emission without overpredicting the scattered light. We model five images of the β Pictoris disk: two in scattered light from the Hubble Space Telescope (HST)/Space Telescope Imaging Spectrograph at 0.58 μm and HST/Wide Field Camera 3 (WFC 3) at 1.16 μm, and three in thermal emission from Spitzer/Multiband Imaging Photometer for Spitzer (MIPS) at 24 μm, Herschel/PACS at 70 μm, and Atacama Large Millimeter/submillimeter Array at 870 μm. The WFC3 and MIPS data are published here for the first time. We focus our modeling on the outer part of this disk, consisting of a parent body ring and a halo of small grains. First, we confirm that a model using astronomical silicates cannot simultaneously fit the thermal and scattered light data. Next, we use a simple generic function for the optical constants to show that varying the dust composition can improve the fit substantially. Finally, we model the dust as a mixture of the most plausible debris constituents: astronomical silicates, water ice, organic refractory material, and vacuum. We achieve a good fit to all data sets with grains composed predominantly of silicates and organics, while ice and vacuum are, at most, present in small amounts. This composition is similar to one derived from previous work on the HR 4796A disk. Our model also fits the thermal spectral energy distribution, scattered light colors, and high-resolution mid-IR data from T-ReCS for this disk. Additionally, we show that sub-blowout grains are a necessary component of the halo.

  16. Investigation into the optical characteristics of the top-illuminated organic solar cells with graphene electrode

    NASA Astrophysics Data System (ADS)

    Long, Yongbing; Li, Bowen; Li, Yuanxing; Zheng, Wenhao; Wang, Qiwen; Su, Runmei

    2014-06-01

    Optical modeling based on transfer matrix method is employed to investigate optical performance of the top-illuminated organic solar cells (OSCs) with graphene electrode. For the graphene-based OSCs with thin active layer,the upper limit to short-circuit current density (?) is improved when compared with that of the indium tin oxide-based devices. This is attributed to the zero-order optical resonance of the weak microcavity (WMC) constructed within the devices. But for the devices with relatively thicker active layer, ? is reduced by the off-resonance suppression of the WMC structure. By capping a WO3 layer on the graphene electrode to tune the WMC structure, the off-resonance suppression can be eliminated and ? for the graphene-based OSCs is significantly raised due to the combined effects of the first-order and other higher order optical resonance of the WMC. In addition, the capping layer can be used to improve ? for the top-illuminated OSCs with various organic materials as the active layer. Finally, it is demonstrated that ? for the graphene-based OSCs with a WMC structure decreases according to Lambert's cosine law when the incident angle increases.

  17. Recent Advances in Organic Photovoltaics: Device Structure and Optical Engineering Optimization on the Nanoscale.

    PubMed

    Luo, Guoping; Ren, Xingang; Zhang, Su; Wu, Hongbin; Choy, Wallace C H; He, Zhicai; Cao, Yong

    2016-03-23

    Organic photovoltaic (OPV) devices, which can directly convert absorbed sunlight to electricity, are stacked thin films of tens to hundreds of nanometers. They have emerged as a promising candidate for affordable, clean, and renewable energy. In the past few years, a rapid increase has been seen in the power conversion efficiency of OPV devices toward 10% and above, through comprehensive optimizations via novel photoactive donor and acceptor materials, control of thin-film morphology on the nanoscale, device structure developments, and interfacial and optical engineering. The intrinsic problems of short exciton diffusion length and low carrier mobility in organic semiconductors creates a challenge for OPV designs for achieving optically thick and electrically thin device structures to achieve sufficient light absorption and efficient electron/hole extraction. Recent advances in the field of OPV devices are reviewed, with a focus on the progress in device architecture and optical engineering approaches that lead to improved electrical and optical characteristics in OPV devices. Successful strategies are highlighted for light wave distribution, modulation, and absorption promotion inside the active layer of OPV devices by incorporating periodic nanopatterns/nanostructures or incorporating metallic nanomaterials and nanostructures. PMID:26856789

  18. Growth and characterization of a new nonlinear optical organic crystal: 2,4,6-Trimethylacetanilide

    NASA Astrophysics Data System (ADS)

    Upadhyaya, V.; Prabhu, Sharada G.

    2015-09-01

    A new nonlinear optical organic material, 2,4,6-trimethylacetanilide (246TMAA), also known as N-[2,4,6- trimethylphenyl]acetamide, has been synthesized and grown as a single crystal by the slow evaporation technique by organic solvents. The grown crystals have been characterized by morphology study. The crystals are prismatic. Surface examination shows granular dendritic pattern in optical micrograph. The Scanning Electron Micrograph shows the layered growth of the crystal. The Differential Scanning Calorimeter plot shows no phase change until melting point (219°C). The density of the crystals is 1.1g/cc and the crystals are soft. The crystals are transparent in the visible region and in the ultra-violet region till 280 nm. 246TMAA crystallizes with 2 molecules in a monoclinic unit cell in the noncentrosymmetric point group m, space group Pn. Refractive indices of this optically biaxial crystal along the three crystallophysical axes have been measured at 633 nm. The optical second harmonic generation efficiency of the crystal at 1064 nm is about half that of the urea crystal, measured by powder method using Nd:YAG laser. The results show that the 246TMAA crystal can efficiently be used for up-conversion of infrared radiation into visible green light. The powder X-ray diffraction spectrum of the crystal has been obtained.

  19. Recent Advances in Organic Photovoltaics: Device Structure and Optical Engineering Optimization on the Nanoscale.

    PubMed

    Luo, Guoping; Ren, Xingang; Zhang, Su; Wu, Hongbin; Choy, Wallace C H; He, Zhicai; Cao, Yong

    2016-03-23

    Organic photovoltaic (OPV) devices, which can directly convert absorbed sunlight to electricity, are stacked thin films of tens to hundreds of nanometers. They have emerged as a promising candidate for affordable, clean, and renewable energy. In the past few years, a rapid increase has been seen in the power conversion efficiency of OPV devices toward 10% and above, through comprehensive optimizations via novel photoactive donor and acceptor materials, control of thin-film morphology on the nanoscale, device structure developments, and interfacial and optical engineering. The intrinsic problems of short exciton diffusion length and low carrier mobility in organic semiconductors creates a challenge for OPV designs for achieving optically thick and electrically thin device structures to achieve sufficient light absorption and efficient electron/hole extraction. Recent advances in the field of OPV devices are reviewed, with a focus on the progress in device architecture and optical engineering approaches that lead to improved electrical and optical characteristics in OPV devices. Successful strategies are highlighted for light wave distribution, modulation, and absorption promotion inside the active layer of OPV devices by incorporating periodic nanopatterns/nanostructures or incorporating metallic nanomaterials and nanostructures.

  20. Optically Detected Magnetic Resonance and Thermal Activation Spectroscopy Study of Organic Semiconductors

    SciTech Connect

    Chang-Hwan Kim

    2003-12-12

    Organic electronic materials are a new class of emerging materials. Organic light emitting devices (OLEDs) are the most promising candidates for future flat panel display technologies. The photophysical characterization is the basic research step one must follow to understand this new class of materials and devices. The light emission properties are closely related to the transport properties of these materials. The objective of this dissertation is to probe the relation between transport and photophysical properties of organic semiconductors. The transport characteristics were evaluated by using thermally stimulated current and thermally stimulated luminescence techniques. The photoluminescence detected magnetic resonance and photoluminescence quantum yield studies provide valuable photophysical information on this class of materials. OLEDs are already in the market. However, detailed studies on the degradation mechanisms are still lacking. Since both optically detected magnetic resonance and thermal activation spectroscopy probe long-lived defect-related states in organic semiconductors, the combined study generates new insight on the OLED operation and degradation mechanisms.

  1. Organic electroluminescent devices and method for improving energy efficiency and optical stability thereof

    DOEpatents

    Heller, Christian Maria

    2004-04-27

    An organic electroluminescent device ("OELD") has a controllable brightness, an improved energy efficiency, and stable optical output at low brightness. The OELD is activated with a series of voltage pulses, each of which has a maximum voltage value that corresponds to the maximum power efficiency when the OELD is activated. The frequency of the pulses, or the duty cycle, or both are chosen to provide the desired average brightness.

  2. Polarimeter with linear response for measuring optical activity in organic compounds

    NASA Astrophysics Data System (ADS)

    Flores, Jorge L.; Montoya, Marcial; Garcia-Torales, G.; Gonzalez Alvarez, Alejandro

    2005-08-01

    A polarimeter designed for measuring small rotation angles on the polarization plane of light is described. The experimental device employs one fixed polarizer and a rotating analyzer. The system generates a periodical intensity signal, which is then Fourier analyzed. The coefficients of Fourier Transform contain information about rotation angles produced by organic compounds that exhibited optical activity. The experimental device can be used to determine the sugar concentration in agave juice.

  3. Alchemy in the underworld - recent progress and future potential of organic geochemistry applied to speleothems.

    NASA Astrophysics Data System (ADS)

    Blyth, Alison

    2016-04-01

    Speleothems are well used archives for chemical records of terrestrial environmental change, and the integration of records from a range of isotopic, inorganic, and organic geochemical techniques offers significant power in reconstructing both changes in past climates and identifying the resultant response in the overlying terrestrial ecosystems. The use of organic geochemistry in this field offers the opportunity to recover new records of vegetation change (via biomarkers and compound specific isotopes), temperature change (via analysis of glycerol dialkyl glycerol tetraethers, a compound group derived from microbes and varying in structure in response to temperature and pH), and changes in soil microbial behaviour (via combined carbon isotope analysis). However, to date the use of organic geochemical techniques has been relatively limited, due to issues relating to sample size, concerns about contamination, and unanswered questions about the origins of the preserved organic matter and rates of transport. Here I will briefly review recent progress in the field, and present a framework for the future research needed to establish organic geochemical analysis in speleothems as a robust palaeo-proxy approach.

  4. Dynamic contrast-enhanced optical imaging of in vivo organ function

    NASA Astrophysics Data System (ADS)

    Amoozegar, Cyrus B.; Wang, Tracy; Bouchard, Matthew B.; McCaslin, Addason F. H.; Blaner, William S.; Levenson, Richard M.; Hillman, Elizabeth M. C.

    2012-09-01

    Conventional approaches to optical small animal molecular imaging suffer from poor resolution, limited sensitivity, and unreliable quantitation, often reducing their utility in practice. We previously demonstrated that the in vivo dynamics of an injected contrast agent could be exploited to provide high-contrast anatomical registration, owing to the temporal differences in each organ's response to the circulating fluorophore. This study extends this approach to explore whether dynamic contrast-enhanced optical imaging (DyCE) can allow noninvasive, in vivo assessment of organ function by quantifying the differing cellular uptake or wash-out dynamics of an agent in healthy and damaged organs. Specifically, we used DyCE to visualize and measure the organ-specific uptake dynamics of indocyanine green before and after induction of transient liver damage. DyCE imaging was performed longitudinally over nine days, and blood samples collected at each imaging session were analyzed for alanine aminotransferase (ALT), a liver enzyme assessed clinically as a measure of liver damage. We show that changes in DyCE-derived dynamics of liver and kidney dye uptake caused by liver damage correlate linearly with ALT concentrations, with an r2 value of 0.91. Our results demonstrate that DyCE can provide quantitative, in vivo, longitudinal measures of organ function with inexpensive and simple data acquisition.

  5. Tunable organization of cellulose nanocrystals for controlled thermal and optical response

    NASA Astrophysics Data System (ADS)

    Diaz A., Jairo A.

    The biorenewable nature of cellulose nanocrystals (CNCs) has opened up new opportunities for cost-effective, sustainable materials design. By taking advantage of their distinctive structural properties and self-assembly, promising applications have started to nurture the fields of flexible electronics, biomaterials, and nanocomposites. CNCs exhibit two fundamental characteristics: rod-like morphology (5-20 nm wide, 50-500 nm long), and lyotropic behavior (i.e., liquid crystalline mesophases formed in solvents), which offer unique opportunities for structural control and fine tuning of thermal and optical properties based on a proper understanding of their individual behavior and interactions at different length scales. In the present work, we attempt to provide an integral description of the influence of single crystals in the thermal and optical response exhibited by nanostructured films. Our approach involved the connection of experimental evidence with predictions of molecular dynamics (MD) simulations. In order to assess the effect of CNC orientation in the bulk response, we produced cellulose nanostructured films under two different mechanisms, namely, self-organization and shear orientation. Self-organized nanostructured films exhibited the typical iridescent optical reflection generated by chiral nematic organization. Shear oriented films disrupted the cholesteric organization, generating highly aligned structures with high optical transparency. The resultant CNC organization present in all nanostructured films was estimated by a second order statistical orientational distribution based on two- dimensional XRD signals. A new method to determine the coefficient of thermal expansion (CTE) in a contact-free fashion was developed to properly characterize the thermal expansion of thin soft films by excluding other thermally activated phenomena. The method can be readily extended to other soft materials to accurately measure thermal strains in a non

  6. Controlling of the optical properties of the solutions of the PTCDI-C8 organic semiconductor

    NASA Astrophysics Data System (ADS)

    Erdoğan, Erman; Gündüz, Bayram

    2016-09-01

    N,N'-Dioctyl-3,4,9,10 perylenedicarboximide (PTCDI-C8) organic semiconductor have vast applications in solar cells, thermoelectric generators, thin film photovoltaics and many other optoelectronic devices. These applications of the materials are based on their spectral and optical properties. The solutions of the PTCDI-C8 for different molarities were prepared and the spectral and optical mesaurements were analyzed. Effects of the molarities on optical properties were investigated. Vibronic structure has been observed based on the absorption bands of PTCDI-C8 semiconductor with seven peaks at 2.292, 2.451, 2.616, 3.212, 3.851, 4.477 and 4.733 eV. The important spectral parameteres such as molar/mass extinction coefficients, absorption coefficient of the PTCDI-C8 molecule were calculated. Optical properties such as angle of incidence/refraction, optical band gap, real and imaginary parts of dielectric constant, loss factor and electrical susceptibility of the the PTCDI-C8 were obtained. Finally, we discussed these parameters for optoelectronic applications and compared with related parameters in literature.

  7. Optically controllable dual-gate organic transistor produced via phase separation between polymer semiconductor and photochromic spiropyran molecules.

    PubMed

    Ishiguro, Yasushi; Hayakawa, Ryoma; Chikyow, Toyohiro; Wakayama, Yutaka

    2014-07-01

    We produced an optically controllable dual-gate organic field-effect transistor by a simple one-step spin-coating of a mixed solution of photochromic spiropyran (SP) and poly(3-hexylthiophene) (P3HT). Postannealing enhanced polymer chain ordering of P3HT to induce phase separation into an SP-rich lower layer and an SP-free upper layer. These layers worked independently as transistor channels with distinct optical responsivity. The top channel was optically inactive, but the bottom channel was optically active, because of the photoisomerization of SP. These results demonstrate the potential of our technique to produce a multifunctional photoactive organic transistor by a simple process.

  8. Electrochemical noise methods applied to the study of organic coatings and pretreatments

    SciTech Connect

    Bierwagen, G.P.; Talhnan, D.E.; Touzain, S.; Smith, A.; Twite, R.; Balbyshev, V.; Pae, Y.

    1998-12-31

    The use of electrochemical noise methods (ENM) to examine organic coatings was first performed in 1986 by Skerry and Eden. The technique uses the spontaneous voltage and current noise that occurs between two identical coated electrodes in electrolyte immersion to determine resistance properties of the coating as well as low frequency noise impedance data for the system. It is a non-perturbing measurement, and one that allows judgment and ranking of coating systems performance. This paper will summarize work in the lab over the past five years on the use of ENM for examining the properties of organic coatings and pretreatment over metals. They have studied marine coatings, pipeline coatings, coil coatings, electrodeposited organic coatings (e-coats), and aircraft coatings by this method and found it to be useful, especially when used in conjunction with impedance and other electrochemical techniques.

  9. Characterization of low-pressure microwave and radio frequency discharges in oxygen applying optical emission spectroscopy and multipole resonance probe

    NASA Astrophysics Data System (ADS)

    Steves, Simon; Styrnoll, Tim; Mitschker, Felix; Bienholz, Stefan; Nikita, Bibinov; Awakowicz, Peter

    2013-11-01

    Optical emission spectroscopy (OES) and multipole resonance probe (MRP) are adopted to characterize low-pressure microwave (MW) and radio frequency (RF) discharges in oxygen. In this context, both discharges are usually applied for the deposition of permeation barrier SiOx films on plastic foils or the inner surface of plastic bottles. For technological reasons the MW excitation is modulated and a continuous wave (cw) RF bias is used. The RF voltage produces a stationary low-density plasma, whereas the high-density MW discharge is pulsed. For the optimization of deposition process and the quality of the deposited barrier films, plasma conditions are characterized using OES and MRP. To simplify the comparison of applied diagnostics, both MW and RF discharges are studied separately in cw mode. The OES and MRP diagnostic methods complement each other and provide reliable information about electron density and electron temperature. In the MW case, electron density amounts to ne = (1.25 ± 0.26) × 1017 m-3, and kTe to 1.93 ± 0.20 eV, in the RF case ne = (6.8 ± 1.8)×1015 m-3 and kTe = 2.6 ± 0.35 eV. The corresponding gas temperatures are 760±40 K and 440±20 K.

  10. 7 CFR 322.14 - Documentation; applying for a permit to import a restricted organism.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS..., subspecies or strain, and author (if known). (5) Type of organism. Select or write “Bees and/or bee germ...) of approval. Is your facility approved for the species of bees or bee germ plasm for which you...

  11. 7 CFR 322.14 - Documentation; applying for a permit to import a restricted organism.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS..., subspecies or strain, and author (if known). (5) Type of organism. Select or write “Bees and/or bee germ...) of approval. Is your facility approved for the species of bees or bee germ plasm for which you...

  12. 7 CFR 322.14 - Documentation; applying for a permit to import a restricted organism.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS..., subspecies or strain, and author (if known). (5) Type of organism. Select or write “Bees and/or bee germ...) of approval. Is your facility approved for the species of bees or bee germ plasm for which you...

  13. Applying the Interaction Equivalency Theorem to Online Courses in a Large Organization

    ERIC Educational Resources Information Center

    Rodriguez, Brenda Cecilia Padilla; Armellini, Alejandro

    2014-01-01

    Finding effective ways of designing online courses is a priority for corporate organizations. The interaction equivalency theorem states that meaningful learning can be achieved as long as courses are designed with at least a high level of one of three types of interactions (learner-content, learner-teacher or learner-learner). This study aimed to…

  14. 40 CFR 262.100 - To what organizations does this subpart apply?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE University Laboratories XL Project-Laboratory Environmental Management Standard § 262.100 To what organizations does this... Burlington, Vermont (“Universities”); and (b) It is a laboratory at one of the Universities...

  15. 7 CFR 322.14 - Documentation; applying for a permit to import a restricted organism.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS..., subspecies or strain, and author (if known). (5) Type of organism. Select or write “Bees and/or bee germ...) of approval. Is your facility approved for the species of bees or bee germ plasm for which you...

  16. 7 CFR 322.14 - Documentation; applying for a permit to import a restricted organism.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... (Continued) ANIMAL AND PLANT HEALTH INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE BEES, BEEKEEPING BYPRODUCTS..., subspecies or strain, and author (if known). (5) Type of organism. Select or write “Bees and/or bee germ...) of approval. Is your facility approved for the species of bees or bee germ plasm for which you...

  17. Contending with Poverty: Applied Research in a Community-Based Poverty Intervention Organization.

    ERIC Educational Resources Information Center

    McGettigan, Timothy

    This paper describes preliminary results from a study at the Crisis Control Ministry, a poverty relief organization in Winston-Salem (North Carolina). The intent of the study was to explore the nature of and influences on contemporary urban poverty by having the investigator serve as a volunteer interviewer at the Crisis Control Ministry. Another…

  18. Magneto-transport and optical control of magnetization in organic systems: From polymers to molecule-based magnets

    NASA Astrophysics Data System (ADS)

    Bozdag, Kadriye Deniz

    Organic systems can be synthesized to have various impressive properties such as room temperature magnetism, electrical conductivity as high as conventional metals and magnetic field dependent transport. In this dissertation, we report comprehensive experimental studies in two different classes of organic systems, V-Cr Prussian blue molecule-based magnets and polyaniline nanofiber networks. The first system, V-Cr Prussian blue magnets, belongs to a family of cyano-bridged bi-metallic compounds which display a broad range of interesting photoinduced magnetic properties. A notable example for optically controllable molecule-based magnets is Co-Fe Prussian blue magnet (Tc ˜ 12 K), which exhibits light-induced changes in between magnetic states together with glassy behavior. In this dissertation, the first reports of reversible photoinduced magnetic phenomena in V-Cr Prussian blue analogs and the analysis of its AC and DC magnetization behavior are presented. Optical excitation of V-Cr Prussian blue, one of the few room temperature molecule-based magnets, with UV light (lambda = 350 nm) suppresses magnetization, whereas subsequent excitation with green light (lambda = 514 nm) increases magnetization. The partial recovery effect of green light is observed only when the sample is previously UV-irradiated. Moreover the photoinduced state has a long lifetime at low temperatures (tau > 106 s at T = 10 K) indicating that V-Cr Prussian blue reaches a hidden metastable state upon illumination with UV light. The effects of optical excitation are maintained up to 200 K and completely erased when the sample is warmed above 250 K. Results of detailed magnetic studies and the likely microscopic mechanisms for the photo illumination effects on magnetic properties are discussed. The second organic system, polyaniline nanofiber networks, was synthesized via dilute polymerization and studied at low and high electric and magnetic fields for temperatures 2 K--250 K for their magneto

  19. 41 CFR 102-74.465 - Is a person or organization that wishes to use a public area required to apply for a permit from...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... organization that wishes to use a public area required to apply for a permit from a Federal agency? 102-74.465... Buildings Application for Permit § 102-74.465 Is a person or organization that wishes to use a public area required to apply for a permit from a Federal agency? Yes, any person or organization wishing to use...

  20. 41 CFR 102-74.465 - Is a person or organization that wishes to use a public area required to apply for a permit from...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... organization that wishes to use a public area required to apply for a permit from a Federal agency? 102-74.465... Buildings Application for Permit § 102-74.465 Is a person or organization that wishes to use a public area required to apply for a permit from a Federal agency? Yes, any person or organization wishing to use...

  1. 41 CFR 102-74.465 - Is a person or organization that wishes to use a public area required to apply for a permit from...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... organization that wishes to use a public area required to apply for a permit from a Federal agency? 102-74.465... Buildings Application for Permit § 102-74.465 Is a person or organization that wishes to use a public area required to apply for a permit from a Federal agency? Yes, any person or organization wishing to use...

  2. 41 CFR 102-74.465 - Is a person or organization that wishes to use a public area required to apply for a permit from...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... organization that wishes to use a public area required to apply for a permit from a Federal agency? 102-74.465... Buildings Application for Permit § 102-74.465 Is a person or organization that wishes to use a public area required to apply for a permit from a Federal agency? Yes, any person or organization wishing to use...

  3. 41 CFR 102-74.465 - Is a person or organization that wishes to use a public area required to apply for a permit from...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... organization that wishes to use a public area required to apply for a permit from a Federal agency? 102-74.465... Buildings Application for Permit § 102-74.465 Is a person or organization that wishes to use a public area required to apply for a permit from a Federal agency? Yes, any person or organization wishing to use...

  4. Activation of Organic Photovoltaic Light Detectors Using Bend Leakage from Optical Fibers.

    PubMed

    Griffith, Matthew J; Willis, Matthew S; Kumar, Pankaj; Holdsworth, John L; Bezuidenhout, Henco; Zhou, Xiaojing; Belcher, Warwick; Dastoor, Paul C

    2016-03-01

    This work investigates the detection and subsequent utilization of leaked light from bends in a silica optical fiber using organic photovoltaic detectors. The optic power lost by single mode and multimode silica optical fibers was calibrated for bend radii between 1 and 7 mm for 532 and 633 nm light, exhibiting excellent agreement with previous theoretical solutions. The spatial location of maximum power leakage on the exterior of the fiber was found to exist in the same plane as the fiber, with a 10° offset from the normal. Two different organic photovoltaic detectors fabricated using a poly(3-hexylthiophene):indene-C60-bisadduct donor-acceptor blend cast from chloroform and chlorobenzene were fabricated to detect the leaked light. The two detectors exhibited different photovoltaic performances, predominantly due to different active layer thicknesses. Both devices showed sensitivity to leakage light, exhibiting voltages between 200 and 300 mV in response to leaked light from the fiber. The temporal responses of the devices were observed to differ, with a rise time from 10% to 90% of maximum voltage of 1430 μs for the chlorobenzene device, and a corresponding rise time of 490 μs for the higher performing chloroform device. The two OPVs were used to simultaneously detect leaked light from induced bends in the optical fiber, with the differing temporal profiles employed to create a unique time-correlated detection signal with enhanced security. The delay between detection of each OPV voltage could be systematically varied, allowing for either a programmable and secure single detection signal or triggering of multiple events with variable time resolution. The results reported in this study present exciting avenues toward the deployment of this simple and noninvasive optical detection system in a range of different applications. PMID:26891938

  5. Activation of Organic Photovoltaic Light Detectors Using Bend Leakage from Optical Fibers.

    PubMed

    Griffith, Matthew J; Willis, Matthew S; Kumar, Pankaj; Holdsworth, John L; Bezuidenhout, Henco; Zhou, Xiaojing; Belcher, Warwick; Dastoor, Paul C

    2016-03-01

    This work investigates the detection and subsequent utilization of leaked light from bends in a silica optical fiber using organic photovoltaic detectors. The optic power lost by single mode and multimode silica optical fibers was calibrated for bend radii between 1 and 7 mm for 532 and 633 nm light, exhibiting excellent agreement with previous theoretical solutions. The spatial location of maximum power leakage on the exterior of the fiber was found to exist in the same plane as the fiber, with a 10° offset from the normal. Two different organic photovoltaic detectors fabricated using a poly(3-hexylthiophene):indene-C60-bisadduct donor-acceptor blend cast from chloroform and chlorobenzene were fabricated to detect the leaked light. The two detectors exhibited different photovoltaic performances, predominantly due to different active layer thicknesses. Both devices showed sensitivity to leakage light, exhibiting voltages between 200 and 300 mV in response to leaked light from the fiber. The temporal responses of the devices were observed to differ, with a rise time from 10% to 90% of maximum voltage of 1430 μs for the chlorobenzene device, and a corresponding rise time of 490 μs for the higher performing chloroform device. The two OPVs were used to simultaneously detect leaked light from induced bends in the optical fiber, with the differing temporal profiles employed to create a unique time-correlated detection signal with enhanced security. The delay between detection of each OPV voltage could be systematically varied, allowing for either a programmable and secure single detection signal or triggering of multiple events with variable time resolution. The results reported in this study present exciting avenues toward the deployment of this simple and noninvasive optical detection system in a range of different applications.

  6. Particulate organic carbon and inherent optical properties during 2008 North Atlantic Bloom Experiment

    NASA Astrophysics Data System (ADS)

    Cetinić, Ivona; Perry, Mary Jane; Briggs, Nathan T.; Kallin, Emily; D'Asaro, Eric A.; Lee, Craig M.

    2012-06-01

    The co-variability of particulate backscattering (bbp) and attenuation (cp) coefficients and particulate organic carbon (POC) provides a basis for estimating POC on spatial and temporal scales that are impossible to obtain with traditional sampling and chemical analysis methods. However, the use of optical proxies for POC in the open ocean is complicated by variable relationships reported in the literature between POC and cp or bbp. During the 2008 North Atlantic Bloom experiment, we accrued a large data set consisting of >300 POC samples and simultaneously measured cp and bbp. Attention to sampling detail, use of multiple types of POC blanks, cross-calibration of optical instruments, and parallel measurements of other biogeochemical parameters facilitated distinction between natural and methodological-based variability. The POC versuscp slope varied with plankton community composition but not depth; slopes were 11% lower for the diatom versus the recycling community. Analysis of literature POC versus cp slopes indicates that plankton composition is responsible for a large component of that variability. The POC versus bbp slope decreased below the pycnocline by 20%, likely due to changing particle composition associated with remineralization and fewer organic rich particles. The higher bbp/cp ratios below the mixed layer are also indicative of particles of lower organic density. We also observed a peculiar platform effect that resulted in ˜27% higher values for downcast versus upcast bbp measurements. Reduction in uncertainties and improvement of accuracies of POC retrieved from optical measurements is important for autonomous sampling, and requires community consensus for standard protocols for optics and POC.

  7. Applying Community Organizing Principles to Assess Health Needs in New Haven, Connecticut.

    PubMed

    Santilli, Alycia; Carroll-Scott, Amy; Ickovics, Jeannette R

    2016-05-01

    The Affordable Care Act added requirements for nonprofit hospitals to conduct community health needs assessments. Guidelines are minimal; however, they require input and representation from the broader community. This call echoes 2 decades of literature on the importance of including community members in all aspects of research design, a tenet of community organizing. We describe a community-engaged research approach to a community health needs assessment in New Haven, Connecticut. We demonstrate that a robust community organizing approach provided unique research benefits: access to residents for data collection, reliable data, leverage for community-driven interventions, and modest improvements in behavioral risk. We make recommendations for future community-engaged efforts and workforce development, which are important for responding to increasing calls for community health needs assessments. PMID:26985599

  8. Applying Community Organizing Principles to Assess Health Needs in New Haven, Connecticut.

    PubMed

    Santilli, Alycia; Carroll-Scott, Amy; Ickovics, Jeannette R

    2016-05-01

    The Affordable Care Act added requirements for nonprofit hospitals to conduct community health needs assessments. Guidelines are minimal; however, they require input and representation from the broader community. This call echoes 2 decades of literature on the importance of including community members in all aspects of research design, a tenet of community organizing. We describe a community-engaged research approach to a community health needs assessment in New Haven, Connecticut. We demonstrate that a robust community organizing approach provided unique research benefits: access to residents for data collection, reliable data, leverage for community-driven interventions, and modest improvements in behavioral risk. We make recommendations for future community-engaged efforts and workforce development, which are important for responding to increasing calls for community health needs assessments.

  9. A generic organ based ontology system, applied to vertebrate heart anatomy, development and physiology.

    PubMed

    Bertens, Laura M F; Slob, Joris; Verbeek, Fons J

    2011-09-08

    We present a novel approach to modelling biological information using ontologies. The system interlinks three ontologies, comprising anatomical, developmental and taxonomical information, and includes instances of structures for different species. The framework is constructed for comparative analyses in the field of evolutionary development. We have applied the approach to the vertebrate heart and present four case studies of the functionality of the system, focusing on cross-species comparisons, developmental studies, physiological studies and 3D visualisation.

  10. Fast response organic light-emitting diode for visible optical communication

    NASA Astrophysics Data System (ADS)

    Fukuda, Takeshi; Taniguchi, Yoshio

    2008-02-01

    We examined fast response organic light-emitting diodes (OLEDs) for new applications of visible optical communications. For the practical use in this field, the fast transmission speed of OLEDs is required to be used in many applications, but the low carrier mobility of organic materials and the long fluorescence lifetime (FL) organic emitting materials limit the transmission speed of OLEDs. Therefore, we investigated the influence of the FL on transient properties of photoluminescence (PL), which were evaluated by the frequency dependence of PL intensity excited by a modulated violet laser diode. The FLs of several organic emitting materials were also measured, and we found the clear relationship between the FL and the transient properties of PL intensity. The fastest cutoff frequency of PL intensity was achieved 160 MHz utilizing short FL material, 1,4-bis[2-[4-[N,N-di(ptolyl)amino]phenl]vinyl]benzene. We also investigated another way to increase the transmission speed utilizing a semiconductor-organic multilayer structure, of which ZnS was used as an electron transport layer. The maximum cutoff frequency of this device was achieved 20.3 MHz, while that of the organic multilayer structure was 8.7 MHz at a sine wave voltage of 7 V and a bias voltage of 5 V. This result indicates that the high carrier mobility of the ZnS layer causes the increase in the transmission speed of OLEDs. We demonstrated one institutive demonstrator module of visible optical communications, which consisted of the transceiver module with an OLED and the pen-type receiver module with a photo-diode at a point. The movie files was transmitted at a speed of 230 kbps, when the point of a pen-type receiver module approaches the emitting area of an OLED. Furthermore, the pseudo-random signal with 1Mbps was also transmitted with this visible optical communication system. Such a system enables to connect between transceiver and receiver module without precious alignment because of the large

  11. Encapsulation of functional organic compounds in nanoglass for optically anisotropic coatings.

    PubMed

    Stöter, Matthias; Biersack, Bernhard; Rosenfeldt, Sabine; Leitl, Markus J; Kalo, Hussein; Schobert, Rainer; Yersin, Hartmut; Ozin, Geoffrey A; Förster, Stephan; Breu, Josef

    2015-04-13

    A novel approach is presented for the encapsulation of organic functional molecules between two sheets of 1 nm thin silicate layers, which like glass are transparent and chemically stable. An ordered heterostructure with organic interlayers strictly alternating with osmotically swelling sodium interlayers can be spontaneously delaminated into double stacks with the organic interlayers sandwiched between two silicate layers. The double stacks show high aspect ratios of >1000 (typical lateral extension 5000 nm, thickness 4.5 nm). This newly developed technique can be used to mask hydrophobic functional molecules and render them completely dispersible in water. The combination of the structural anisotropy of the silicate layers and a preferred orientation of molecules confined in the interlayer space allows polymer nanocomposite films to be cast with a well-defined orientation of the encapsulated molecules, thus rendering the optical properties of the nanocoatings anisotropic. PMID:25703020

  12. How to control optical activity in organic-silver hybrid nanoparticles.

    PubMed

    Hidalgo, Francisco; Noguez, Cecilia

    2016-08-14

    The mechanisms that originate and control optical activity in organic-metal hybrid nanoparticles (NPs) are identified using a time-perturbed density functional theory. Electronic circular dichroism (CD) is studied in terms of the intrinsic chirality of the ligands, the number of ligands and the induced chirality by the arrangement of the ligands on the NP. Left-handed cysteine and achiral methylthio ligands adsorbed on an icosahedral silver NP are investigated. The analysis of CD allows the identification of the spectral regions when the induced chirality by the ligand array dominates over the intrinsic chirality of the ligands, determining conditions for CD control and enlargement. These results would be significant in the discussion of experimental CD spectra of organic-metal hybrid NPs, which might allow the development of new strategies to improve the sensitivity of chiroptical spectroscopies for the identification of bio and organic molecules. PMID:27406401

  13. Probing and Modeling of Carrier Motion in Organic Field Effect Transistors by Optical Second Harmonic Generation

    SciTech Connect

    Iwamoto, Mitsumasa

    2009-07-10

    We here report a novel optical second harmonic generation (SHG) measurement that allows an electric field formed in organic solid to be probed. We examined the SHG intensity profile that changes depending on space charge field caused by carrier injection. Experiments making use of time resolved SHG technique has revealed dynamic changes of SHG intensity profiles arising from pentacene, and that carrier transport in OFET was diffusion-like. Calculations using drift-diffusion equation well accounted for the visualized carrier motion probed by time-resolved SHG. Finally, we conclude that experiments and analysis based on dielectrics physics is a very effective way for analyzing carrier behaviors in organic materials as well as in organic thin film devices.

  14. Detection of Organic Compounds in Water by an Optical Absorbance Method

    PubMed Central

    Kim, Chihoon; Eom, Joo Beom; Jung, Soyoun; Ji, Taeksoo

    2016-01-01

    This paper proposes an optical method which allows determination of the organic compound concentration in water by measurement of the UV (ultraviolet) absorption at a wavelength of 250 nm~300 nm. The UV absorbance was analyzed by means of a multiple linear regression model for estimation of the total organic carbon contents in water, which showed a close correlation with the UV absorbance, demonstrating a high adjusted coefficient of determination, 0.997. The comparison of the TOC (total organic carbon) concentrations for real samples (tab water, sea, and river) calculated from the UV absorbance spectra, and those measured by a conventional TOC analyzer indicates that the higher the TOC value the better the agreement. This UV absorbance method can be easily configured for real-time monitoring water pollution, and built into a compact system applicable to industry areas. PMID:26742043

  15. Vertical Single-Crystalline Organic Nanowires on Graphene: Solution-Phase Epitaxy and Optical Microcavities.

    PubMed

    Zheng, Jian-Yao; Xu, Hongjun; Wang, Jing Jing; Winters, Sinéad; Motta, Carlo; Karademir, Ertuğrul; Zhu, Weigang; Varrla, Eswaraiah; Duesberg, Georg S; Sanvito, Stefano; Hu, Wenping; Donegan, John F

    2016-08-10

    Vertically aligned nanowires (NWs) of single crystal semiconductors have attracted a great deal of interest in the past few years. They have strong potential to be used in device structures with high density and with intriguing optoelectronic properties. However, fabricating such nanowire structures using organic semiconducting materials remains technically challenging. Here we report a simple procedure for the synthesis of crystalline 9,10-bis(phenylethynyl) anthracene (BPEA) NWs on a graphene surface utilizing a solution-phase van der Waals (vdW) epitaxial strategy. The wires are found to grow preferentially in a vertical direction on the surface of graphene. Structural characterization and first-principles ab initio simulations were performed to investigate the epitaxial growth and the molecular orientation of the BPEA molecules on graphene was studied, revealing the role of interactions at the graphene-BPEA interface in determining the molecular orientation. These free-standing NWs showed not only efficient optical waveguiding with low loss along the NW but also confinement of light between the two end facets of the NW forming a microcavity Fabry-Pérot resonator. From an analysis of the optical dispersion within such NW microcavities, we observed strong slowing of the waveguided light with a group velocity reduced to one-tenth the speed of light. Applications of the vertical single-crystalline organic NWs grown on graphene will benefit from a combination of the unique electronic properties and flexibility of graphene and the tunable optical and electronic properties of organic NWs. Therefore, these vertical organic NW arrays on graphene offer the potential for realizing future on-chip light sources. PMID:27438189

  16. Estimating dissolved organic carbon concentration in turbid coastal waters using optical remote sensing observations

    NASA Astrophysics Data System (ADS)

    Cherukuru, Nagur; Ford, Phillip W.; Matear, Richard J.; Oubelkheir, Kadija; Clementson, Lesley A.; Suber, Ken; Steven, Andrew D. L.

    2016-10-01

    Dissolved Organic Carbon (DOC) is an important component in the global carbon cycle. It also plays an important role in influencing the coastal ocean biogeochemical (BGC) cycles and light environment. Studies focussing on DOC dynamics in coastal waters are data constrained due to the high costs associated with in situ water sampling campaigns. Satellite optical remote sensing has the potential to provide continuous, cost-effective DOC estimates. In this study we used a bio-optics dataset collected in turbid coastal waters of Moreton Bay (MB), Australia, during 2011 to develop a remote sensing algorithm to estimate DOC. This dataset includes data from flood and non-flood conditions. In MB, DOC concentration varied over a wide range (20-520 μM C) and had a good correlation (R2 = 0.78) with absorption due to coloured dissolved organic matter (CDOM) and remote sensing reflectance. Using this data set we developed an empirical algorithm to derive DOC concentrations from the ratio of Rrs(412)/Rrs(488) and tested it with independent datasets. In this study, we demonstrate the ability to estimate DOC using remotely sensed optical observations in turbid coastal waters.

  17. Optics of an individual organic molecular mesowire waveguide: directional light emission and anomalous refractive index

    NASA Astrophysics Data System (ADS)

    Tripathi, Ravi P. N.; Dasgupta, Arindam; Chikkaraddy, Rohit; Pratim Patra, Partha; Vasista, Adarsh B.; Pavan Kumar, G. V.

    2016-06-01

    We report on experimental investigations performed on an isolated organic mesowire waveguide resting on a glass substrate. The waveguide was made of diaminoanthraquinone (DAAQ) molecular aggregates. First, we show directional emission of light from distal ends of the DAAQ waveguide. For a given mesowire geometry, operating in passive or photoluminescence regimes, we quantified the emission angles by combining multi-wavelength Fourier-plane optical microscopy and photoluminescence micro-spectroscopy. We found light emission in the photoluminescence regime to be more directional in nature compared to the passive waveguiding regime, which was supported by three-dimensional finite-difference time-domain (FDTD) simulations. Second, we measured the anomalous behaviour of refractive index as a function of emission wavelength using the spectra of directionally emitted light. Third, by using spatial-filtered collection optics, we observed and quantified single-excitation dual-channel directional, active emission from DAAQ mesowire. The results discussed herein has implication not only in understanding some fundamental aspects of exciton-polariton mediated directional light emission, but also in applications such as organic optical antennas and photonic couplers.

  18. How to control optical activity in organic-silver hybrid nanoparticles

    NASA Astrophysics Data System (ADS)

    Hidalgo, Francisco; Noguez, Cecilia

    2016-07-01

    The mechanisms that originate and control optical activity in organic-metal hybrid nanoparticles (NPs) are identified using a time-perturbed density functional theory. Electronic circular dichroism (CD) is studied in terms of the intrinsic chirality of the ligands, the number of ligands and the induced chirality by the arrangement of the ligands on the NP. Left-handed cysteine and achiral methylthio ligands adsorbed on an icosahedral silver NP are investigated. The analysis of CD allows the identification of the spectral regions when the induced chirality by the ligand array dominates over the intrinsic chirality of the ligands, determining conditions for CD control and enlargement. These results would be significant in the discussion of experimental CD spectra of organic-metal hybrid NPs, which might allow the development of new strategies to improve the sensitivity of chiroptical spectroscopies for the identification of bio and organic molecules.The mechanisms that originate and control optical activity in organic-metal hybrid nanoparticles (NPs) are identified using a time-perturbed density functional theory. Electronic circular dichroism (CD) is studied in terms of the intrinsic chirality of the ligands, the number of ligands and the induced chirality by the arrangement of the ligands on the NP. Left-handed cysteine and achiral methylthio ligands adsorbed on an icosahedral silver NP are investigated. The analysis of CD allows the identification of the spectral regions when the induced chirality by the ligand array dominates over the intrinsic chirality of the ligands, determining conditions for CD control and enlargement. These results would be significant in the discussion of experimental CD spectra of organic-metal hybrid NPs, which might allow the development of new strategies to improve the sensitivity of chiroptical spectroscopies for the identification of bio and organic molecules. Electronic supplementary information (ESI) available. See DOI: 10.1039/C6

  19. Organization of the channel-switching process in parallel computer systems based on a matrix optical switch

    NASA Technical Reports Server (NTRS)

    Golomidov, Y. V.; Li, S. K.; Popov, S. A.; Smolov, V. B.

    1986-01-01

    After a classification and analysis of electronic and optoelectronic switching devices, the design principles and structure of a matrix optical switch is described. The switching and pair-exclusion operations in this type of switch are examined, and a method for the optical switching of communication channels is elaborated. Finally, attention is given to the structural organization of a parallel computer system with a matrix optical switch.

  20. Applying membrane technology to air stripping effluent for remediation of groundwater contaminated with volatile organic compounds

    SciTech Connect

    Brown, J.J.; Erickson, M.D.; Beskid, N.J.

    1993-12-31

    Remediation groundwater contaminated by volatile organic compounds (VOCs) requires cost- and technically-effective solutions. This paper reviews the options for VOC removal from remediation air streams, focusing on membrane separation. The basic separation science and technology, results of performance tests, and results of cost studies for membrane separation are presented. Competing technologies are discussed and compared with membrane separation. Membrane separation combined with air stripping will provide an economically and environmentally safe technology for remediation of VOC-contaminated groundwater and, as it matures, may become the preferred method. 9 refs., 6 figs., 2 tabs.

  1. Optical, electrical, and magnetic field studies of organic materials for light emitting diodes and photovoltaic applications

    NASA Astrophysics Data System (ADS)

    Basel, Tek Prasad

    We studied optical, electrical, and magnetic field responses of films and devices based on organic semiconductors that are used for organic light emitting diodes (OLEDs) and photovoltaic (OPV) solar cell applications. Our studies show that the hyperfine interaction (HFI)-mediated spin mixing is the key process underlying various magnetic field effects (MFE) and spin transport in aluminum tris(8-hydroxyquinoline)[Alq3]-based OLEDs and organic spin-valve (OSV). Conductivity-detected magnetic resonance in OLEDs and magneto-resistance (MR) in OSVs show substantial isotope dependence. In contrast, isotope-insensitive behavior in the magneto-conductance (MC) of same devices is explained by the collision of spin ½ carriers with triplet polaron pairs. We used steady state optical spectroscopy for studying the energy transfer dynamics in films and OLEDs based on host-guest blends of the fluorescent polymer and phosphorescent molecule. We have also studied the magnetic-field controlled color manipulation in these devices, which provide a strong proof for the `polaron-pair' mechanism underlying the MFE in organic devices. The critical issue that hampers organic spintronics device applications is significant magneto-electroluminescence (MEL) at room temperature (RT). Whereas inorganic spin valves (ISVs) show RT magneto-resistance, MR>80%, however, the devices do not exhibit electroluminescence (EL). In contrast, OLEDs show substantive EL emission, and are particularly attractive because of their flexibility, low cost, and potential for multicolor display. We report a conceptual novel hybrid organic/inorganic spintronics device (h-OLED), where we employ both ISV with large MR at RT, and OLED that has efficient EL emission. We investigated the charge transfer process in an OPV solar cell through optical, electrical, and magnetic field measurements of thin films and devices based on a low bandgap polymer, PTB7 (fluorinated poly-thienothiophene-benzodithiophene). We found that

  2. Generation of ultra-short THz pulses in new optical nonlinear materials based on organic polymers

    NASA Astrophysics Data System (ADS)

    Mikerin, S. L.; Plekhanov, A. I.; Simanchuk, A. E.; Yakimanskii, A. V.

    2016-07-01

    Using the method of optical rectification of femtosecond laser pulses, we report the generation of short (a few field cycles) terahertz pulses in the samples of films based on polyimides with covalently bound chromophore molecules of DR type. The spectral width of the produced pulses is limited by the pump pulse duration. The quadratic nonlinear optical properties are imparted to the films in the process of their fabrication by orienting the chromophore molecules in the external electric field of the applied electrodes having an original configuration. The samples are compared with the ZnTe crystal. Using the methods of coherent spectroscopy, their transmission and refractive index dispersion spectra are investigated in the frequency range 0.5 – 2.6 THz. The studied polymer composition is promising for the application in coherent spectrometers both for increasing the working spectral range without dips and for improving the spatial resolution in the near-field terahertz spectroscopy.

  3. Study of organic contamination induced by outgassing materials. Application to the Laser MégaJoule optics

    NASA Astrophysics Data System (ADS)

    Favrat, O.; Mangote, B.; Tovena-Pécault, I.; Néauport, J.

    2014-02-01

    Organic contamination may decrease the targeted performances of coated surfaces. To study the contamination induced by surrounding materials, a method using a thermal extractor is presented in the first part of this work. Besides its normal operation (analyses of outgassing compounds from a material), this device is used in an original way to contaminate and decontaminate samples. Efficiency of contamination and decontamination protocols are assessed by automated thermal desorption and gas chromatography coupled with mass spectrometry and by secondary ion mass spectrometry coupled with a time of flight mass analyzer. This enables to study the contamination induced by a bulk material outgassing and to take in consideration the possible competition between outgassed species. This method is then applied to investigate contamination of Laser MégaJoule sol-gel coated optics by a retractable sheath. The impact of the temperature on the outgassing of the sheath has been highlighted. Increasing temperature from 30 to 50 °C enables the outgassing of organophosphorous compounds and increases the outgassing of oxygenated compounds and phthalates. Chemical analyses of contaminated optics have highlighted affinities between the sol-gel coating and phthalates and organophosphorous, and low affinities with aromatics and terpens. Finally, samples with increasing levels of contamination have been realized. However a saturation phenomenon is observed at 90 ng cm-2.

  4. Multi-parameter optical image interpretations based on self-organizing mapping

    NASA Astrophysics Data System (ADS)

    Klose, Christian D.; Klose, A. K.; Netz, U.; Scheel, A.; Beuthan, J.; Hielscher, Andreas H.

    2008-02-01

    We found that using more than one parameter derived from optical tomographic images can lead to better image classification results compared to cases when only one parameter is used.. In particular we present a multi-parameter classification approach, called self-organizing mapping (SOM), for detecting synovitis in arthritic finger joints based on sagittal laser optical tomography (SLOT). This imaging modality can be used to determine various physical parameters such as minimal absorption and scattering coefficients in an image of the proximal interphalengeal joint. Results were compared to different gold standards: magnet resonance imaging, ultra-sonography and clinical evaluation. When compared to classifications based on single-parameters, e.g., absorption minimum only, the study reveals that multi-parameter classifications lead to higher classification sensitivities and specificities and statistical significances with p-values <5 per cent. Finally, the data suggest that image analyses are more reliable and avoid ambiguous interpretations when using more than one parameter.

  5. [Scaling methods applied to set priorities in training programs in organizations].

    PubMed

    Sanduvete Chaves, Susana; Barbero García, María Isabel; Chacón Moscoso, Salvador; Pérez-Gil, J Antonio; Holgado Tello, F Pablo; Sánchez Martín, Milagrosa; Lozano Lozano, J Antonio

    2009-11-01

    Criteria to assess the needs in order to plan training programs are not usually defined explicitly in organizational contexts. We propose scaling methods as a feasible and useful procedure to set priorities of training programs; also, we propose the most suitable method for this intervention context. 404 employees from a public organization completed an ad hoc questionnaire to assess training needs in different areas from 2004 to 2006; concretely, 117, 75 and 286 stimuli were scaled, respectively. Then, four scaling methods were compared: Dunn-Rankin's method and three methods derived from Thurstone's Law of Categorical Judgment--ranking, successive intervals and equal-appearing intervals. The feasibility and utility of these scaling methods to solve the problems described is shown. Taking into account the most accurate compared methods, we propose ranking as the most parsimonious method (with regard to procedure simplicity). Future research developments are described.

  6. Crystal engineering on superpolyhedral building blocks in metal-organic frameworks applied in gas adsorption.

    PubMed

    Chen, Ying Pin; Liu, Tian Fu; Fordham, Stephen; Zhou, Hong Cai

    2015-12-01

    Two metal-organic frameworks [PCN-426(Ni) and PCN-427(Cu)] have been designed and synthesized to investigate the structure predictability using a SBB (supermolecular building blocks) approach. Tetratopic ligands featuring 120° angular carboxylate moieties were coordinated with a [Ni3(μ3-O)] cluster and a [Cu2O2] unit, respectively. As topologically predicted, 4-connected networks with square coordination adopted the nbo net for the Ni-MOF and ssb net for the Cu-MOF. PCN-426(Ni) was augmented with 12-connected octahedral SBBs, while PCN-427(Cu) was constructed with tetragonal open channels. After a CO2 supercritical drying procedure, the PCN-426(Ni) possessed a Brunauer-Emmett-Teller (BET) surface area as high as 3935 m(2) g(-1) and impressively high N2 uptake of 1500 cm(3) g(-1). This work demonstrates the generalization of the SBB strategy, finding an alternative to inconvenient synthetic processes to achieve the desired structural features.

  7. Evaluation of industrially applied heat-transfer fluids as liquid organic hydrogen carrier systems.

    PubMed

    Brückner, Nicole; Obesser, Katharina; Bösmann, Andreas; Teichmann, Daniel; Arlt, Wolfgang; Dungs, Jennifer; Wasserscheid, Peter

    2014-01-01

    Liquid organic hydrogen carrier (LOHC) systems offer a very attractive method for the decentralized storage of renewable excess energy. In this contribution, industrially well-established heat-transfer oils (typically sold under trade names, e.g., Marlotherm) are proposed as a new class of LOHC systems. It is demonstrated that the liquid mixture of isomeric dibenzyltoluenes (m.p. -39 to -34 °C, b.p. 390 °C) can be readily hydrogenated to the corresponding mixture of perhydrogenated analogues by binding 6.2 wt% of H2. The liquid H2 -rich form can be stored and transported similarly to diesel fuel. It readily undergoes catalytic dehydrogenation at temperatures above 260 °C, which proves its applicability as a reversible H2 carrier. The presented LOHC systems are further characterized by their excellent technical availability at comparably low prices, full registration of the H2 -lean forms, and excellent thermal stabilities. PMID:23956191

  8. Evaluation of industrially applied heat-transfer fluids as liquid organic hydrogen carrier systems.

    PubMed

    Brückner, Nicole; Obesser, Katharina; Bösmann, Andreas; Teichmann, Daniel; Arlt, Wolfgang; Dungs, Jennifer; Wasserscheid, Peter

    2014-01-01

    Liquid organic hydrogen carrier (LOHC) systems offer a very attractive method for the decentralized storage of renewable excess energy. In this contribution, industrially well-established heat-transfer oils (typically sold under trade names, e.g., Marlotherm) are proposed as a new class of LOHC systems. It is demonstrated that the liquid mixture of isomeric dibenzyltoluenes (m.p. -39 to -34 °C, b.p. 390 °C) can be readily hydrogenated to the corresponding mixture of perhydrogenated analogues by binding 6.2 wt% of H2. The liquid H2 -rich form can be stored and transported similarly to diesel fuel. It readily undergoes catalytic dehydrogenation at temperatures above 260 °C, which proves its applicability as a reversible H2 carrier. The presented LOHC systems are further characterized by their excellent technical availability at comparably low prices, full registration of the H2 -lean forms, and excellent thermal stabilities.

  9. Fluorescence spectroscopy to study dissolved organic matter interactions with agrochemicals applied in Swiss vineyards.

    PubMed

    Daouk, Silwan; Frege, Carla; Blanc, Nicolas; Mounier, Stéphane; Redon, Roland; Merdy, Patricia; Lucas, Yves; Pfeifer, Hans-Rudolf

    2015-06-01

    UV/Vis fluorescence spectroscopy was used to study the possible interactions of dissolved organic matter (DOM) with the herbicide glyphosate and copper-based fungicide used in vineyards. The study focused on the role of DOM in the transport of these micropollutants from parcels to surface waters (river, lake). Soil solution and river water samples were collected in the Lavaux vineyard area, western Switzerland. Their fluorescence excitation emission matrices (EEM) were decomposed using parallel factor (PARAFAC) analysis, and compared to their content in glyphosate and copper. PARAFAC analysis of EEM of both types of samples showed the contribution of protein-like and humic-like fluorophores. In soil water samples, complexes between fulvic-like and humic-like fluorophores of DOM, copper, and glyphosate were likely formed. In surface water, DOM-copper and glyphosate-copper interactions were observed, but not between glyphosate and DOM.

  10. Hydrologic Impacts of a Surface-Applied, Organic Emulsion on Arid Soils

    NASA Astrophysics Data System (ADS)

    Young, M. H.; Caldwell, T. G.; Goreham, J.; Meadows, D. G.; Shafer, D. S.; Miller, J. J.; McDonald, E. V.

    2005-12-01

    In-place stabilization of environmental contaminants over land areas poses interesting logistical challenges, especially when considering the impact of the stabilizing agent on soil hydrologic processes like infiltration and surface runoff. As one part of a larger field-based study, we investigated the potential hydrologic impacts of using an organic-based emulsion which was designed to stabilize disturbed and undisturbed desert soils. The emulsion, a blend of organic esters, surfactants, water, and a proprietary chelating agent, was tested at the Yuma Proving Ground, Yuma, AZ. The goal of the study was to determine whether, and to what extent, field application of this emulsion altered the soil hydraulic properties and hence the infiltration and runoff potential. A randomized complete block design was used to investigate the effects of soil age (old vs young), treatment concentration (control vs two dilution levels), disturbance level (disturbed vs undisturbed), and time (1 year exposure) on the soil hydraulic properties. Hydraulic properties were determined using a 20 cm diameter tension infiltrometer (triplicate measurements for each treatment combination). Initial results show a significant reduction in the saturated hydraulic conductivity by nearly two orders of magnitude following treatment with the emulsion. Triplicate rainfall simulation experiments were also conducted on the test plots to investigate rainfall-runoff processes. Results immediately following treatment show a reduced time to ponding and a higher potential for surface runoff. Tests conducted quarterly for one year after application, however, indicate that hydrologic impacts diminished with time. Targeted laboratory tests are ongoing to better identify the breakdown mechanisms of the emulsion. The field and laboratory results will help guide larger-scale field applications based on actual field conditions.

  11. Organic Light-Emitting Diodes (OLEDs) and Optically-Detected Magnetic Resonance (ODMR) studies on organic materials

    SciTech Connect

    Cai, Min

    2011-01-01

    Organic semiconductors have evolved rapidly over the last decades and currently are considered as the next-generation technology for many applications, such as organic light-emitting diodes (OLEDs) in flat-panel displays (FPDs) and solid state lighting (SSL), and organic solar cells (OSCs) in clean renewable energy. This dissertation focuses mainly on OLEDs. Although the commercialization of the OLED technology in FPDs is growing and appears to be just around the corner for SSL, there are still several key issues that need to be addressed: (1) the cost of OLEDs is very high, largely due to the costly current manufacturing process; (2) the efficiency of OLEDs needs to be improved. This is vital to the success of OLEDs in the FPD and SSL industries; (3) the lifetime of OLEDs, especially blue OLEDs, is the biggest technical challenge. All these issues raise the demand for new organic materials, new device structures, and continued lower-cost fabrication methods. In an attempt to address these issues, we used solution-processing methods to fabricate highly efficient small molecule OLEDs (SMOLEDs); this approach is costeffective in comparison to the more common thermal vacuum evaporation. We also successfully made efficient indium tin oxide (ITO)-free SMOLEDs to further improve the efficiency of the OLEDs. We employed the spin-dependent optically-detected magnetic resonance (ODMR) technique to study the luminescence quenching processes in OLEDs and organic materials in order to understand the intrinsic degradation mechanisms. We also fabricated polymer LEDs (PLEDs) based on a new electron-accepting blue-emitting polymer and studied the effect of molecular weight on the efficiency of PLEDs. All these studies helped us to better understand the underlying relationship between the organic semiconductor materials and the OLEDs’ performance, and will subsequently assist in further enhancing the efficiency of OLEDs. With strongly improved device performance (in addition to

  12. Organic Light-Emitting Diodes (OLEDs) and Optically-Detected Magnetic Resonance (ODMR) studies on organic materials

    NASA Astrophysics Data System (ADS)

    Cai, Min

    Organic semiconductors have evolved rapidly over the last decades and currently are considered as the next-generation technology for many applications, such as organic light-emitting diodes (OLEDs) in flat-panel displays (FPDs) and solid state lighting (SSL), and organic solar cells (OSCs) in clean renewable energy. This dissertation focuses mainly on OLEDs. Although the commercialization of the OLED technology in FPDs is growing and appears to be just around the corner for SSL, there are still several key issues that need to be addressed: (1) the cost of OLEDs is very high, largely due to the costly current manufacturing process; (2) the efficiency of OLEDs needs to be improved. This is vital to the success of OLEDs in the FPD and SSL industries; (3) the lifetime of OLEDs, especially blue OLEDs, is the biggest technical challenge. All these issues raise the demand for new organic materials, new device structures, and continued lower-cost fabrication methods. In an attempt to address these issues, we used solution-processing methods to fabricate highly efficient small molecule OLEDs (SMOLEDs); this approach is cost-effective in comparison to the more common thermal vacuum evaporation. We also successfully made efficient indium tin oxide (ITO)-free SMOLEDs to further improve the efficiency of the OLEDs. We employed the spin-dependent optically-detected magnetic resonance (ODMR) technique to study the luminescence quenching processes in OLEDs and organic materials in order to understand the intrinsic degradation mechanisms. We also fabricated polymer LEDs (PLEDs) based on a new electron-accepting blue-emitting polymer and studied the effect of molecular weight on the efficiency of PLEDs. All these studies helped us to better understand the underlying relationship between the organic semiconductor materials and the OLEDs' performance, and will subsequently assist in further enhancing the efficiency of OLEDs. With strongly improved device performance (in addition to

  13. Micro-optics for simultaneous multi-spectral imaging applied to chemical/biological and IED detection

    NASA Astrophysics Data System (ADS)

    Hinnrichs, Michele

    2012-06-01

    Using diffractive micro-lenses configured in an array and placed in close proximity to the focal plane array will enable a small compact simultaneous multispectral imaging camera. This approach can be applied to spectral regions from the ultraviolet (UV) to the long-wave infrared (LWIR). The number of simultaneously imaged spectral bands is determined by the number of individually configured diffractive optical micro-lenses (lenslet) in the array. Each lenslet images at a different wavelength determined by the blaze and set at the time of manufacturing based on application. In addition, modulation of the focal length of the lenslet array with piezoelectric or electro-static actuation will enable spectral band fill-in allowing hyperspectral imaging. Using the lenslet array with dual-band detectors will increase the number of simultaneous spectral images by a factor of two when utilizing multiple diffraction orders. Configurations and concept designs will be presented for detection application for biological/chemical agents, buried IED's and reconnaissance. The simultaneous detection of multiple spectral images in a single frame of data enhances the image processing capability by eliminating temporal differences between colors and enabling a handheld instrument that is insensitive to motion.

  14. Optical constraints of kerogen from 0.15 to 40 microns: Comparison with meteoritic organics

    NASA Technical Reports Server (NTRS)

    Khare, Bishun N.; Thompson, W. R.; Sagan, C.; Arakawa, E. T.; Meisse, C.; Gilmour, I.

    1990-01-01

    Kerogens are dark, complex organic materials produced on the Earth primarily by geologic processing of biologic materials, but kerogens have chemical and spectral similarities to some classes of highly processed extraterrestrial organic materials. Kerogen-like solids were proposed as constitutents of the very dark reddish surfaces of some asteroids and are also spectrally similar to some carbonaceous organic residues and the Iapetus dark material. Kerogen can thus serve as a useful laboratory analog to very dark, spectrally red extraterrestrial materials; its optical constants can be used to investigate the effects of particle size, void space and mixing of bright and dark components in models of scattering by dark asteroidal, cometary, and satellite surfaces. Measurements of the optical constants of both Type 2 kerogen and of macromolecular organic residue from the Murchison carbonaceous chondrite via transmission and reflection measurements on thin films are reported. The real part of the refractive index, n, is determined by variable incidence-angle reflectance to be 1.60 + or - 0.05 from 0.4 to 2.0 micrometers wavelength. Work extending the measurement of n to longer wavelengths is in progress. The imaginary part of the refractive index, k, shows substantial structure from 0.15 to 40 micrometers. The values are accurate to + or - 20 percent in the UV and IR regions and to + or - 30 percent in the visible. The k values of organic residues were also measured from the Murchison meteorite. Comparison of the kerogen and Murchison data reveals that between 0.15 and 40 microns, Murchison has a similar structure but no bands as sharp as in kerogen, and that the k values for Murchison are significantly higher than those of kerogen.

  15. SU-E-J-187: Management of Optic Organ Motion in Fractionated Stereotactic Radiotherapy

    SciTech Connect

    Manning, M; Maurer, J

    2015-06-15

    Purpose: Fractionated stereotactic radiotherapy (FSRT) for optic nerve tumors can potentially use planning target volume (PTV) expansions as small as 1–5 mm. However, the motion of the intraorbital segment of the optic nerve has not been studied. Methods: A subject with a right optic nerve sheath meningioma underwent CT simulation in three fixed gaze positions: right, left, and fixed forward at a marker. The gross tumor volume (GTV) and the organs-at-risk (OAR) were contoured on all three scans. An IMRT plan using 10 static non-coplanar fields to 50.4 Gy in 28 fractions was designed to treat the fixed-forward gazing GTV with a 1 mm PTV, then resulting coverage was evaluated for the GTV in the three positions. As an alternative, the composite structures were computed to generate the internal target volume (ITV), 1 mm expansion free-gazing PTV, and planning organat-risk volumes (PRVs) for free-gazing treatment. A comparable IMRT plan was created for the free-gazing PTV. Results: If the patient were treated using the fixed forward gaze plan looking straight, right, and left, the V100% for the GTV was 100.0%, 33.1%, and 0.1%, respectively. The volumes of the PTVs for fixed gaze and free-gazing plans were 0.79 and 2.21 cc, respectively, increasing the PTV by a factor of 2.6. The V100% for the fixed gaze and free-gazing plans were 0.85 cc and 2.8 cc, respectively increasing the treated volume by a factor of 3.3. Conclusion: Fixed gaze treatment appears to provide greater organ sparing than free-gazing. However unanticipated intrafraction right or left gaze can produce a geometric miss. Further study of optic nerve motion appears to be warranted in areas such as intrafraction optical confirmation of fixed gaze and optimized gaze directions to minimize lens and other normal organ dose in cranial radiotherapy.

  16. Electrochemically Organized Isolated Fullerene-Rich Thin Films with Optical Limiting Properties.

    PubMed

    Kang, Shusen; Zhang, Jian; Sang, Liwen; Shrestha, Lok Kumar; Zhang, Zhe; Lu, Ping; Li, Feng; Li, Mao; Ariga, Katsuhiko

    2016-09-21

    Electrochemical assembly was applied directly to determine the aggregation of nanoclusters in isolated fullerene-rich (54-63 wt %) thin films. The electroactive reactions were achieved using electroactive carbazole and pyrene, which led to distinguishable nanoparticle-like and irregular cluster formations. These films, with amorphous and transparent states, showed good photoactivity and significant optical limiting response with an excellent threshold of 63 mJ cm(-2). This work thus paves a way to assemble highly isolated (or monodispersed) building blocks into thin films at the molecular level with control of the nanostructural formations through important molecular design. PMID:27580965

  17. Optically readout write once read many memory with single active organic layer

    NASA Astrophysics Data System (ADS)

    Nguyen, Viet Cuong; Lee, Pooi See

    2016-01-01

    An optically readable write once read many memory (WORM) in Ag/Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH PPV)/ITO is demonstrated in this work. Utilising characteristics of the organic light emitting diode structure of Ag/MEH PPV/ITO and electrochemical metallization of Ag, a WORM with light emitting capability can be realised. The simple fabrication process and multifunction capability of the device can be useful for future wearable optoelectronics and photomemory applications, where fast and parallel readout can be achieved by photons.

  18. Structural, vibrational, thermal and optical studies of organic single crystal: Benzotriazolium p-toluene sulfonate (BTPTS)

    NASA Astrophysics Data System (ADS)

    Kumar, R. Ramesh; Sathya, P.; Gopalakrishnan, R.

    2016-05-01

    Benzotriazolium p-toluene sulfonate (BTPTS) was grown by solution growth technique. The powder X-ray diffraction analysis was carried out to evaluate crystal system of the compound. LeBail Profile fitting analysis was performed to extract the individual peak intensities. FTIR spectrum analysis was recorded to study vibration frequencies of the prepared organic salt. Thermal studies were carried out using TG-DSC analysis. Optical absorption and energy band gap of the title compound was evaluated by UV-Vis spectral study.

  19. Structural, optical, thermal and mechanical characterization of an organic nonlinear optical material: 4-methyl-3-nitrobenzoic acid single crystal

    NASA Astrophysics Data System (ADS)

    Bharathi, M. Divya; Ahila, G.; Mohana, J.; Chakkaravarthi, G.; Anbalagan, G.

    2016-11-01

    Organic single crystals of 4-methyl-3-nitrobenzoic acid (4M3N) have been grown by slow evaporation solution growth technique at room temperature. The single crystal X-ray diffraction study reveals that 4M3N crystallizes in monoclinic system with space group P21/n. The crystalline perfection of the crystal was analyzed by high resolution X-ray diffraction (HRXRD) measurements. The functional groups present in 4M3N have been identified from FT-IR and FT-Raman spectra. The lower cut-off wavelength of 4M3N is found to be 404 nm and the optical band gap is calculated as 2.91 eV. The refractive index shows normal behavior with wavelength. The physio chemical changes, decomposition and stability of the 4M3N compound were established by TG-DTA studies. Vickers microhardness measurement concludes that 4M3N belongs to soft material (n=2.5) category. The LDT value is found to be higher than that of KDP and some of the important organic NLO materials. The third order nonlinear refractive index and nonlinear absorption coefficient of the 4M3N have been measured by Z-scan studies. The imaginary and real parts of the third-order susceptibility values were determined as Im χ3=9.129×10-11 esu and Re χ3=1.4034×10-9 esu respectively. The dislocation density was calculated to be 3.0448×106 cm-2 which indicates the quality of the crystal.

  20. Sewage sludge applied to agricultural soil: Ecotoxicological effects on representative soil organisms.

    PubMed

    Carbonell, G; Pro, J; Gómez, N; Babín, M M; Fernández, C; Alonso, E; Tarazona, J V

    2009-05-01

    Application of sewage sludge to agricultural lands is a current practice in EU. European legislation permits its use when concentrations of metals in soil do not increase above the maximum permissible limits. In order to assess the fate and the effects on representative soil organisms of sewage sludge amendments on agricultural lands, a soil microcosm (multi-species soil system-MS3) experiment was performed. The MS3 columns were filled with spiked soil at three different doses: 30, 60 and 120tha(-1) fresh wt. Seed plants (Triticum aestivum, Vicia sativa and Brassica rapa) and earthworms (Eisenia fetida) were introduced into the systems. After a 21-d exposure period, a statistically significant increase for Cd, Cu, Zn and Hg concentrations was found for the soils treated with the highest application rate. Dose-related increase was observed for nickel concentrations in leachates. Plants and earthworm metal body burden offer much more information than metal concentrations and help to understand the potential for metal accumulation. Bioaccumulation factor (BAF(plant-soil)) presented a different behavior among species and large differences for BAF(earthworm-soil), from control or sewage-amended soil, for Cd and Hg were found. B. rapa seed germination was reduced. Statistically significant decrease in fresh biomass was observed for T. aestivum and V. sativa at the highest application rate, whereas B. rapa biomass decreased at any application rate. Enzymatic activities (dehydrogenase and phosphatase) as well as respiration rate on soil microorganisms were enlarged.

  1. Changing environmental conditions and applying organic fertilizers in Origanum vulgare L.

    PubMed Central

    Murillo-Amador, Bernardo; Morales-Prado, Luis E.; Troyo-Diéguez, Enrique; Córdoba-Matson, Miguel V.; Hernández-Montiel, Luis G.; Rueda-Puente, Edgar O.; Nieto-Garibay, Alejandra

    2015-01-01

    Any improvement in agricultural systems that results in higher production should also reduce negative environmental impacts and enhance sustainability. The aim of this research was to investigate the effect of two different production systems, one open-field and the other shade-enclosure with four bocashi doses, in order to find the best environmental option in terms of yield, physiological and morphometric characteristics in one oregano (Origanum vulgare L.) cultivar. In this study a completely randomized block design was used with four replications and evaluated for photosynthetic and transpiration rate, stomatal conductance, chlorophyll, leaf area and temperature, aerial and roots fresh and dry biomass, fresh and dry yield. The results showed that oregano adapted best to the shade-enclosure with increase yield of fresh and dry leaf weight of 165% and 118%, respectively, when compared to open-field. Also, higher doses of bocashi improved yield in both environments but more so in shade-enclosure. Soil moisture retention was higher in shade-enclosure which was reflected in physiological variables for soil matric potential, transpiration, stomatal conductivity, photosynthesis being significantly higher in shade-enclosure compared to open-field, thus improving yield. It seems that oregano plants can be grown and perform better under shade-enclosure than open-field and bocashi is a suitable organic fertilizer. PMID:26257756

  2. Transient electrically detected magnetic resonance spectroscopy applied to organic solar cells

    SciTech Connect

    Kraffert, Felix; Steyrleuthner, Robert; Meier, Christoph; Bittl, Robert; Behrends, Jan

    2015-07-27

    The influence of light-induced paramagnetic states on the photocurrent generated by polymer:fullerene solar cells is studied using spin-sensitive techniques in combination with laser-flash excitation. For this purpose, we developed a setup that allows for simultaneous detection of transient electron paramagnetic resonance as well as transient electrically detected magnetic resonance (trEDMR) signals from fully processed and encapsulated solar cells. Combining both techniques provides a direct link between photoinduced triplet excitons, charge transfer states, and free charge carriers as well as their influence on the photocurrent generated by organic photovoltaic devices. Our results obtained from solar cells based on poly(3-hexylthiophene) as electron donor and a fullerene-based electron acceptor show that the resonant signals observed in low-temperature (T = 80 K) trEDMR spectra can be attributed to positive polarons in the polymer as well as negative polarons in the fullerene phase, indicating that both centers are involved in spin-dependent processes that directly influence the photocurrent.

  3. Changing environmental conditions and applying organic fertilizers in Origanum vulgare L.

    PubMed

    Murillo-Amador, Bernardo; Morales-Prado, Luis E; Troyo-Diéguez, Enrique; Córdoba-Matson, Miguel V; Hernández-Montiel, Luis G; Rueda-Puente, Edgar O; Nieto-Garibay, Alejandra

    2015-01-01

    Any improvement in agricultural systems that results in higher production should also reduce negative environmental impacts and enhance sustainability. The aim of this research was to investigate the effect of two different production systems, one open-field and the other shade-enclosure with four bocashi doses, in order to find the best environmental option in terms of yield, physiological and morphometric characteristics in one oregano (Origanum vulgare L.) cultivar. In this study a completely randomized block design was used with four replications and evaluated for photosynthetic and transpiration rate, stomatal conductance, chlorophyll, leaf area and temperature, aerial and roots fresh and dry biomass, fresh and dry yield. The results showed that oregano adapted best to the shade-enclosure with increase yield of fresh and dry leaf weight of 165% and 118%, respectively, when compared to open-field. Also, higher doses of bocashi improved yield in both environments but more so in shade-enclosure. Soil moisture retention was higher in shade-enclosure which was reflected in physiological variables for soil matric potential, transpiration, stomatal conductivity, photosynthesis being significantly higher in shade-enclosure compared to open-field, thus improving yield. It seems that oregano plants can be grown and perform better under shade-enclosure than open-field and bocashi is a suitable organic fertilizer.

  4. Optical signatures of dissolved organic matter from the Endeavour and Axial vent fields

    NASA Astrophysics Data System (ADS)

    Stubbins, A.; Butterfield, D.; Rossel, P. E.; Dittmar, T.

    2011-12-01

    Recent studies have revealed that hydrothermal systems in the deep ocean are both sources and processors of dissolved organic matter (DOM). Sub-floor stores of fossil organic carbon may be exported to the deep ocean directly adding fossil C to the deep ocean dissolved organic carbon (DOC) pool and altering its apparent age. Fossil methane and carbon dioxide are also exported from vents. These C sources can then be utilized by chemotrophs and later enter the DOM pool as fossil DOC. Finally, when deep ocean waters are entrained into vent systems, the resultant heating may alter the chemical and optical properties of the DOM in these deep ocean waters. Dissolved organic matter (DOM) samples were collected from vents ranging in temperature from 10 to over 300 degrees centigrade across the Endeavour and Axial fields along the Juan de Fuca ridge. Elevated DOC and protein-like fluorescence reveal the vents to fuel the chemotrophic production of organic matter either in the adjacent water column or local sediments. High DOC and increased humic-like fluorescence in the hottest vent fluids, suggests the thermal degradation of DOM either from buried fossil sources or the entrainment of local waters enriched in DOC due to chemotrophic productivity. Natural and radio-carbon analyses are underway and will provide further insight into the ultimate source of this colored, fluorescent hydrothermal DOM.

  5. Three-dimensional imaging of the developing mouse female reproductive organs with optical coherence tomography

    NASA Astrophysics Data System (ADS)

    Burton, Jason C.; Wang, Shang; Behringer, Richard R.; Larina, Irina V.

    2016-03-01

    Infertility is a known major health concern and is estimated to impact ~15% of couples in the U.S. The majority of failed pregnancies occur before or during implantation of the fertilized embryo into the uterus. Understanding the mechanisms regulating development by studying mouse reproductive organs could significantly contribute to an improved understanding of normal development of reproductive organs and developmental causes of infertility in humans. Towards this goal, we report a three-dimensional (3D) imaging study of the developing mouse reproductive organs (ovary, oviduct, and uterus) using optical coherence tomography (OCT). In our study, OCT was used for 3D imaging of reproductive organs without exogenous contrast agents and provides micro-scale spatial resolution. Experiments were conducted in vitro on mouse reproductive organs ranging from the embryonic day 14.5 to adult stages. Structural features of the ovary, oviduct, and uterus are presented. Additionally, a comparison with traditional histological analysis is illustrated. These results provide a basis for a wide range of infertility studies in mouse models. Through integration with traditional genetic and molecular biology approaches, this imaging method can improve understanding of ovary, oviduct, and uterus development and function, serving to further contribute to our understanding of fertility and infertility.

  6. Synthesis, growth, structural, optical, thermal and mechanical properties of an organic Urea maleic acid single crystals for nonlinear optical applications

    NASA Astrophysics Data System (ADS)

    Vinothkumar, P.; Kumar, R. Mohan; Jayavel, R.; Bhaskaran, A.

    2016-07-01

    A potential organic urea maleic acid (UMA) was synthesized and single crystals were grown at room temperature by slow evaporation and seed rotation methods. The grown crystal has been subjected to single crystal XRD analysis and found to have been crystallized in a noncentrosymmetric monoclinic crystal system with Cc as space group. The High resolution X-ray diffraction analysis revealed that the specimen is free from structural grain boundaries. The transparency of the grown crystal was confirmed by optical absorption and transmittance spectra with lower cut-off wavelength of 285 nm. The microhardness test was carried out on different planes to study the load dependent hardness values. The dislocation density of the UMA crystal was estimated from the etching studies. The dielectric permittivity and dielectric loss of the grown crystal was carried out as a function of frequency for different temperatures along three crystallographic axes. Thermal properties of UMA crystals were studied by TG-DTA analysis and it is stable upto 112 °C. The laser induced surface damage threshold of the grown crystal was measured using Nd: YAG laser. The birefringence of the crystal measured in the visible region was found to vary with the wavelength. The particle size dependent SHG of the sample was measured with different input energies by Kurtz's powder method using Nd:YAG laser.

  7. An optical model for the remote sensing of coloured dissolved organic matter in coastal/ocean waters

    NASA Astrophysics Data System (ADS)

    Tiwari, S. P.; Shanmugam, P.

    2011-07-01

    An optical model is developed for the remote sensing of coloured dissolved organic matter (CDOM) in a wide range of waters within coastal and open ocean environments. The absorption of CDOM (denoted as a g) is generally considered as an exponential form model, which has two important parameters - the slope S and absorption of CDOM at a reference wavelength a g( λ0). The empirical relationships for deriving these two parameters are established using in-situ bio-optical datasets. These relationships use the spectral remote sensing reflectance (R rs) ratio at two wavelengths R rs(670)/R rs(490), which avoids the known atmospheric correction problems and is sensitive to CDOM absorption and chlorophyll in coastal/ocean waters. This ratio has tight relationships with a g(412) and a g(443) yielding correlation coefficients between 0.77 and 0.78. The new model, with the above parameterization applied to independent datasets (NOMAD SeaWiFS match-ups and Carder datasets), shows good retrievals of the a g( λ) with regression slopes close to unity, little bias and low mean relative and root mean square errors. These statistical estimates improve significantly over other inversion models (e.g., Linear Matrix-LM and Garver-Siegel-Maritorena-GSM semi-analytical models) when applied to the same datasets. These results demonstrate a good performance of the proposed model in both coastal and open ocean waters, which has the potential to improve our knowledge of the biogeochemical cycles and processes in these domains.

  8. Paleobiology of a Precambrian Shale: Geology, organic geochemistry, and paleontology are applied to the problem of detection of ancient life.

    PubMed

    Barghoorn, E S; Meinschein, W G; Schopf, J W

    1965-04-23

    Investigations have been made of crude oil, pristane, phytane, steranetype and optically active alkanes, porphyrins, microfossils, and the stable isotopes of carbon and of sulfur found in the Nonesuch shale of Precambrian age from Northern Michigan. These sediments are approximately 1 billion years old. Geologic evidence indicates that they were deposited in a nearshore deltaic environment. Porphyrins are found in the siltstones but not in the crude oils of the Nonesuch formation-evidence that these chemical fossils are adsorbed or absorbed and immobile. This immobility makes it highly unlikely that these porphyrins could have moved from younger formations into the Nonesuch sediments, and the widely disseminated particulate organic matters and fossils in this Precambrian shale are certainly indigenous.

  9. Post-annealed gallium and aluminum co-doped zinc oxide films applied in organic photovoltaic devices

    PubMed Central

    2014-01-01

    Gallium and aluminum co-doped zinc oxide (GAZO) films were produced by magnetron sputtering. The GAZO films were post-annealed in either vacuum or hydrogen microwave plasma. Vacuum- and hydrogen microwave plasma-annealed GAZO films show different surface morphologies and lattice structures. The surface roughness and the spacing between adjacent (002) planes decrease; grain growth occurs for the GAZO films after vacuum annealing. The surface roughness increases and nanocrystals are grown for the GAZO films after hydrogen microwave plasma annealing. Both vacuum and hydrogen microwave plasma annealing can improve the electrical and optical properties of GAZO films. Hydrogen microwave plasma annealing improves more than vacuum annealing does for GAZO films. An electrical resistivity of 4.7 × 10−4 Ω-cm and average optical transmittance in the visible range from 400 to 800 nm of 95% can be obtained for the GAZO films after hydrogen microwave plasma annealing. Hybrid organic photovoltaic (OPV) devices were fabricated on the as-deposited, vacuum-annealed, and hydrogen microwave plasma-annealed GAZO-coated glass substrates. The active layer consisted of blended poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61 butyric acid methyl ester (PCBM) in the OPV devices. The power conversion efficiency of the OPV devices is 1.22% for the hydrogen microwave plasma-annealed GAZO films, which is nearly two times higher compared with that for the as-deposited GAZO films. PMID:25352768

  10. Synthesis, growth and characterization of organic nonlinear optical bis-glycine maleate (BGM) single crystals

    NASA Astrophysics Data System (ADS)

    Balasubramanian, D.; Murugakoothan, P.; Jayavel, R.

    2010-05-01

    A new organic compound of bis-glycine maleate was synthesized in the alkaline medium of 10% ammonium hydroxide solution. The bulk single crystals of Bis-Glycine Maleate (BGM) have been grown by slow cooling method. The grown crystals were characterized by employing single crystal and powder X-ray diffraction, Fourier transform infrared, optical absorption spectral studies and thermo gravimetric analysis. The microhardness studies confirmed that the BGM has a fairly high Vicker's hardness number value (41 kg mm -2) in comparison to other organic NLO crystals. Second harmonic generation efficiency of the crystal measured by Kurtz-Perry powder method using Nd:YAG laser is found to be comparable to that of potassium dihydrogen phosphate (KDP). Frequency dependent dielectric studies were carried out along the major growth axis.

  11. Optical properties of microstructured surface-grown and transferred organic nanofibers

    NASA Astrophysics Data System (ADS)

    Kjelstrup-Hansen, Jakob; Tavares, Luciana; de Oliveira Hansen, Roana Melina; Liu, Xuhai; Bordo, Kirill; Rubahn, Horst-Günter

    2011-01-01

    Specially designed surface micro- and nanostructures allow one to steer the bottom up self-organized growth of crystalline nanoaggregates from wide bandgap organic molecules, which possess extraordinary optoelectronic properties. Polarized light-emitting para-hexaphenylene nanofiber arrays exemplify such ``self-growing'' nanophotonic devices. The methodology behind this growth is an alternative to transfer of nanofiber arrays from specific growth substrates onto device platforms. We compared the optical properties of transferred and in situ grown nanofibers in terms of polarization function and emission homogeneity and also studied the temperature dependence of the emission spectra of transferred nanofiber arrays. Both types of nanofibers show the same spatial emission characteristics along their long axes and also the same polarization ratio. However, in nanofiber arrays, the polarization ratio decreases in the case of structured surface-grown nanofibers since the mutual orientation of the nanofibers is less perfect than for transferred fibers.

  12. Optical modeling of sunlight by using partially coherent sources in organic solar cells.

    PubMed

    Alaibakhsh, Hamzeh; Darvish, Ghafar

    2016-03-01

    We investigate the effects of coherent and partially coherent sources in optical modeling of organic solar cells. Two different organic solar cells are investigated: one without substrate and the other with a millimeter-sized glass substrate. The coherent light absorption is calculated with rigorous coupled-wave analysis. The result of this method is convolved with a distribution function to calculate the partially coherent light absorption. We propose a new formulation to accurately model sunlight as a set of partially coherent sources. In the structure with glass substrate, the accurate sunlight modeling results in the elimination of coherent effects in the thick substrate, but the coherency in other layers is not affected. Using partially coherent sources instead of coherent sources for simulations with sunlight results in a smoother absorption spectrum, but the change in the absorption efficiency is negligible. PMID:26974647

  13. Teaching lens, optical systems, and opto-mechanical systems design at the Irvine Center for Applied Competitive Technologies (CACT)

    NASA Astrophysics Data System (ADS)

    Doushkina, Valentina V.; Silberman, Donn M.

    2007-09-01

    For well over a decade, the Laser Electro-Optics Technology (LET) program has been teaching introductory laser and optics classes at Irvine Valley College (IVC). At the beginning of the telecom boom, the Irvine CACT was established to teach optics fabrication to support the many optics fabrication businesses in Southern California. In the past few years, these two programs have merged - with some help from the Optics Institute of Southern California (OISC) - and grown under the newly established Advanced Technology and Education Park (ATEP). IVC and ATEP are both operated by the South Orange County Community College District (SOCCCD). This year a new program of three courses was established to teach, in sequence, lens, optical systems and optomechanical systems design. This paper reviews the reasons for establishing these courses and their content, the students' motivations for taking them and their employers' incentives for encouraging the students.

  14. Optical properties and aging of light-absorbing secondary organic aerosol

    DOE PAGES

    Liu, Jiumeng; Lin, Peng; Laskin, Alexander; Laskin, Julia; Kathmann, Shawn M.; Wise, Matthew; Caylor, Ryan; Imholt, Felisha; Selimovic, Vanessa; Shilling, John E.

    2016-10-14

    The light-absorbing organic aerosol (OA) commonly referred to as “brown carbon” (BrC) has attracted considerable attention in recent years because of its potential to affect atmospheric radiation balance, especially in the ultraviolet region and thus impact photochemical processes. A growing amount of data has indicated that BrC is prevalent in the atmosphere, which has motivated numerous laboratory and field studies; however, our understanding of the relationship between the chemical composition and optical properties of BrC remains limited. We conducted chamber experiments to investigate the effect of various volatile organic carbon (VOC) precursors, NOx concentrations, photolysis time, and relative humidity (RH) on the light absorptionmore » of selected secondary organic aerosols (SOA). Light absorption of chamber-generated SOA samples, especially aromatic SOA, was found to increase with NOx concentration, at moderate RH, and for the shortest photolysis aging times. The highest mass absorption coefficient (MAC) value is observed from toluene SOA products formed under high-NOx conditions at moderate RH, in which nitro-aromatics were previously identified as the major light-absorbing compounds. BrC light absorption is observed to decrease with photolysis time, correlated with a decline of the organic nitrate fraction of SOA. SOA formed from mixtures of aromatics and isoprene absorb less visible (Vis) and ultraviolet (UV) light than SOA formed from aromatic precursors alone on a mass basis. However, the mixed SOA absorption was underestimated when optical properties were predicted using a two-product SOA formation model, as done in many current climate models. Further investigation, including analysis on detailed mechanisms, are required to explain the discrepancy.« less

  15. Optical properties and aging of light-absorbing secondary organic aerosol

    NASA Astrophysics Data System (ADS)

    Liu, Jiumeng; Lin, Peng; Laskin, Alexander; Laskin, Julia; Kathmann, Shawn M.; Wise, Matthew; Caylor, Ryan; Imholt, Felisha; Selimovic, Vanessa; Shilling, John E.

    2016-10-01

    The light-absorbing organic aerosol (OA) commonly referred to as "brown carbon" (BrC) has attracted considerable attention in recent years because of its potential to affect atmospheric radiation balance, especially in the ultraviolet region and thus impact photochemical processes. A growing amount of data has indicated that BrC is prevalent in the atmosphere, which has motivated numerous laboratory and field studies; however, our understanding of the relationship between the chemical composition and optical properties of BrC remains limited. We conducted chamber experiments to investigate the effect of various volatile organic carbon (VOC) precursors, NOx concentrations, photolysis time, and relative humidity (RH) on the light absorption of selected secondary organic aerosols (SOA). Light absorption of chamber-generated SOA samples, especially aromatic SOA, was found to increase with NOx concentration, at moderate RH, and for the shortest photolysis aging times. The highest mass absorption coefficient (MAC) value is observed from toluene SOA products formed under high-NOx conditions at moderate RH, in which nitro-aromatics were previously identified as the major light-absorbing compounds. BrC light absorption is observed to decrease with photolysis time, correlated with a decline of the organic nitrate fraction of SOA. SOA formed from mixtures of aromatics and isoprene absorb less visible (Vis) and ultraviolet (UV) light than SOA formed from aromatic precursors alone on a mass basis. However, the mixed SOA absorption was underestimated when optical properties were predicted using a two-product SOA formation model, as done in many current climate models. Further investigation, including analysis on detailed mechanisms, are required to explain the discrepancy.

  16. Radiation dose to radiosensitive organs in PET/CT myocardial perfusion examination using versatile optical fibre

    NASA Astrophysics Data System (ADS)

    Salasiah, M.; Nordin, A. J.; Fathinul Fikri, A. S.; Hishar, H.; Tamchek, N.; Taiman, K.; Ahmad Bazli, A. K.; Abdul-Rashid, H. A.; Mahdiraji, G. A.; Mizanur, R.; Noor, Noramaliza M.

    2013-05-01

    Cardiac positron emission tomography (PET) provides a precise method in order to diagnose obstructive coronary artery disease (CAD), compared to single photon emission tomography (SPECT). PET is suitable for obese and patients who underwent pharmacologic stress procedures. It has the ability to evaluate multivessel coronary artery disease by recording changes in left ventricular function from rest to peak stress and quantifying myocardial perfusion (in mL/min/g of tissue). However, the radiation dose to the radiosensitive organs has become crucial issues in the Positron Emission Tomography/Computed Tomography(PET/CT) scanning procedure. The objective of this study was to estimate radiation dose to radiosensitive organs of patients who underwent PET/CT myocardial perfusion examination at Centre for Diagnostic Nuclear Imaging, Universiti Putra Malaysia in one month period using versatile optical fibres (Ge-B-doped Flat Fibre) and LiF (TLD-100 chips). All stress and rest paired myocardial perfusion PET/CT scans will be performed with the use of Rubidium-82 (82Rb). The optic fibres were loaded into plastic capsules and attached to patient's eyes, thyroid and breasts prior to the infusion of 82Rb, to accommodate the ten cases for the rest and stress PET scans. The results were compared with established thermoluminescence material, TLD-100 chips. The result shows that radiation dose given by TLD-100 and Germanium-Boron-doped Flat Fiber (Ge-B-doped Flat Fiber) for these five organs were comparable to each other where the p>0.05. For CT scans,thyroid received the highest dose compared to other organs. Meanwhile, for PET scans, breasts received the highest dose.

  17. Crystal structure and characterization of a novel organic optical crystal: 2-Aminopyridinium trichloroacetate

    SciTech Connect

    Dhanaraj, P.V.; Rajesh, N.P.; Vinitha, G.; Bhagavannarayana, G.

    2011-05-15

    Research highlights: {yields} Good quality crystals of 2-aminopyridinium trichloroacetate were grown for first time. {yields} 2-Aminopyridinium trichloroacetate crystal belongs to monoclinic crystal system with space group P21/c. {yields} 2-Aminopyridinium trichloroacetate crystal exhibits third order nonlinear optical properties. {yields} 2-Aminopyridinium trichloroacetate is a low dielectric constant material. -- Abstract: 2-Aminopyridinium trichloroacetate, a novel organic optical material has been synthesized and crystals were grown from aqueous solution employing the technique of controlled evaporation. 2-Aminopyridinium trichloroacetate crystallizes in monoclinic system with space group P2{sub 1}/c and the lattice parameters are a = 8.598(5) A, b = 11.336(2) A, c = 11.023(2) A, {beta} = 102.83(1){sup o} and volume = 1047.5(3) A{sup 3}. High-resolution X-ray diffraction measurements were performed to analyze the structural perfection of the grown crystals. Thermal analysis shows a sharp endothermic peak at 124 {sup o}C due to melting reaction of 2-aminopyridinium trichloroacetate. UV-vis-NIR studies reveal that 2-aminopyridinium trichloroacetate has UV cutoff wavelength at 354 nm. Dielectric studies show that dielectric constant and dielectric loss decreases with increasing frequency and finally it becomes almost a constant at higher frequencies for all temperatures. The negative nonlinear optical parameters of 2-aminopyridinium trichloroacetate were derived by the Z-scan technique.

  18. Monte Carlo analysis on probe performance for endoscopic diffuse optical spectroscopy of tubular organ

    NASA Astrophysics Data System (ADS)

    Zhang, Yunyao; Zhu, Jingping; Cui, Weiwen; Nie, Wei; Li, Jie; Xu, Zhenghong

    2015-03-01

    We investigated the performance of endoscopic diffuse optical spectroscopy probes with circular or linear fiber arrangements for tubular organ cancer detection. Probe performance was measured by penetration depth. A Monte Carlo model was employed to simulate light transport in the hollow cylinder that both emits and receives light from the inner boundary of the sample. The influence of fiber configurations and tissue optical properties on penetration depth was simulated. The results show that under the same condition, probes with circular fiber arrangement penetrate deeper than probes with linear fiber arrangement, and the difference between the two probes' penetration depth decreases with an increase in the 'distance between source and detector (SD)' and the radius of the probe. Other results show that the penetration depths and their differences both decrease with an increase in the absorption coefficient and the reduced scattering coefficient but remain constant with changes in the anisotropy factor. Moreover, the penetration depth was more affected by the absorption coefficient than the reduced scattering coefficient. It turns out that in NIR band, probes with linear fiber arrangements are more appropriate for diagnosing superficial cancers, whereas probes with circular fiber arrangements should be chosen for diagnosing adenocarcinoma. But in UV-VIS band, the two probe configurations exhibit nearly the same. These results are useful in guiding endoscopic diffuse optical spectroscopy-based diagnosis for esophageal, cervical, colorectal and other cancers.

  19. Organic nanoclusters for nonlinear optics: from model systems to cooperative nanoassemblies with enhanced NLO responses

    NASA Astrophysics Data System (ADS)

    Terenziani, Francesca; Parthasarathy, Venkatakrishnan; Ghosh, Sampa; Pandey, Ravindra; Das, Puspendu K.; Blanchard-Desce, Mireille

    2009-08-01

    While structure-properties relationships are quite actively and successfully investigated at the molecular level of engineering of optical nonlinear responses, supramolecular structure-property relationships are an appealing field. The realization that interchromophoric interactions between strongly polar/polarizable NLO chromophores can significantly affect the NLO response of each chromophoric unit as well as promote associations has opened new dimensions for molecular design. Several elegant routes have been implemented to hinder or counterbalance dipole-dipole interactions between dipolar NLO chromophores for the elaboration of second-order materials (for SHG or electro-optical modulation). At opposite, we have implemented a reverse strategy by confining discrete numbers of NLO push-pull chromophores in close proximity within covalent organic nanoclusters with the aim to exploit interchromophoric interactions in order to achieve enhanced NLO responses. As a proof of concept, we present here the investigation of two-series of multichromophoric covalent assemblies built from NLO push-pull chromophores showing that cooperative enhancement can be achieved both for second-order optical responses (first hyperpolarizabilities) or third-order responses (two-photon absorption cross-sections).

  20. In vivo X-ray elemental imaging of single cell model organisms manipulated by laser-based optical tweezers

    PubMed Central

    Vergucht, Eva; Brans, Toon; Beunis, Filip; Garrevoet, Jan; De Rijcke, Maarten; Bauters, Stephen; Deruytter, David; Vandegehuchte, Michiel; Van Nieuwenhove, Ine; Janssen, Colin; Burghammer, Manfred; Vincze, Laszlo

    2015-01-01

    We report on a radically new elemental imaging approach for the analysis of biological model organisms and single cells in their natural, in vivo state. The methodology combines optical tweezers (OT) technology for non-contact, laser-based sample manipulation with synchrotron radiation confocal X-ray fluorescence (XRF) microimaging for the first time. The main objective of this work is to establish a new method for in vivo elemental imaging in a two-dimensional (2D) projection mode in free-standing biological microorganisms or single cells, present in their aqueous environment. Using the model organism Scrippsiella trochoidea, a first proof of principle experiment at beamline ID13 of the European Synchrotron Radiation Facility (ESRF) demonstrates the feasibility of the OT XRF methodology, which is applied to study mixture toxicity of Cu-Ni and Cu-Zn as a result of elevated exposure. We expect that the new OT XRF methodology will significantly contribute to the new trend of investigating microorganisms at the cellular level with added in vivo capability. PMID:25762511

  1. In vivo X-ray elemental imaging of single cell model organisms manipulated by laser-based optical tweezers.

    PubMed

    Vergucht, Eva; Brans, Toon; Beunis, Filip; Garrevoet, Jan; De Rijcke, Maarten; Bauters, Stephen; Deruytter, David; Vandegehuchte, Michiel; Van Nieuwenhove, Ine; Janssen, Colin; Burghammer, Manfred; Vincze, Laszlo

    2015-01-01

    We report on a radically new elemental imaging approach for the analysis of biological model organisms and single cells in their natural, in vivo state. The methodology combines optical tweezers (OT) technology for non-contact, laser-based sample manipulation with synchrotron radiation confocal X-ray fluorescence (XRF) microimaging for the first time. The main objective of this work is to establish a new method for in vivo elemental imaging in a two-dimensional (2D) projection mode in free-standing biological microorganisms or single cells, present in their aqueous environment. Using the model organism Scrippsiella trochoidea, a first proof of principle experiment at beamline ID13 of the European Synchrotron Radiation Facility (ESRF) demonstrates the feasibility of the OT XRF methodology, which is applied to study mixture toxicity of Cu-Ni and Cu-Zn as a result of elevated exposure. We expect that the new OT XRF methodology will significantly contribute to the new trend of investigating microorganisms at the cellular level with added in vivo capability. PMID:25762511

  2. In vivo X-ray elemental imaging of single cell model organisms manipulated by laser-based optical tweezers

    NASA Astrophysics Data System (ADS)

    Vergucht, Eva; Brans, Toon; Beunis, Filip; Garrevoet, Jan; de Rijcke, Maarten; Bauters, Stephen; Deruytter, David; Vandegehuchte, Michiel; van Nieuwenhove, Ine; Janssen, Colin; Burghammer, Manfred; Vincze, Laszlo

    2015-03-01

    We report on a radically new elemental imaging approach for the analysis of biological model organisms and single cells in their natural, in vivo state. The methodology combines optical tweezers (OT) technology for non-contact, laser-based sample manipulation with synchrotron radiation confocal X-ray fluorescence (XRF) microimaging for the first time. The main objective of this work is to establish a new method for in vivo elemental imaging in a two-dimensional (2D) projection mode in free-standing biological microorganisms or single cells, present in their aqueous environment. Using the model organism Scrippsiella trochoidea, a first proof of principle experiment at beamline ID13 of the European Synchrotron Radiation Facility (ESRF) demonstrates the feasibility of the OT XRF methodology, which is applied to study mixture toxicity of Cu-Ni and Cu-Zn as a result of elevated exposure. We expect that the new OT XRF methodology will significantly contribute to the new trend of investigating microorganisms at the cellular level with added in vivo capability.

  3. Observation of electric potential in organic thin-film transistor by bias-applied hard X-ray photoemission spectroscopy

    NASA Astrophysics Data System (ADS)

    Watanabe, Takeshi; Tada, Keisuke; Yasuno, Satoshi; Oji, Hiroshi; Yoshimoto, Noriyuki; Hirosawa, Ichiro

    2016-03-01

    The effect of gate voltage on electric potential in a pentacene (PEN) layer was studied by hard X-ray photoelectron spectroscopy under a bias voltage. It was observed that applying a negative gate voltage substantially increases the width of a C 1s peak. This suggested that injected and accumulated carriers in an organic thin film transistor channel modified the potential depth profile in PEN. It was also observed that the C 1s kinetic energy tends to increase monotonically with threshold voltage.

  4. Relevance of cardiomyocyte mechano-electric coupling to stretch-induced arrhythmias: optical voltage/calcium measurement in mechanically stimulated cells, tissues and organs.

    PubMed

    Seo, Kinya; Inagaki, Masashi; Hidaka, Ichiro; Fukano, Hana; Sugimachi, Masaru; Hisada, Toshiaki; Nishimura, Satoshi; Sugiura, Seiryo

    2014-08-01

    Stretch-induced arrhythmias are multi-scale phenomena in which alterations in channel activities and/or calcium handling lead to the organ level derangement of the heart rhythm. To understand how cellular mechano-electric coupling (MEC) leads to stretch-induced arrhythmias at the organ level, we developed stretching devices and optical voltage/calcium measurement techniques optimized to each cardiac level. This review introduces these experimental techniques of (1) optical voltage measurement coupled with a carbon-fiber technique for single isolated cardiomyocytes, (2) optical voltage mapping combined with motion tracking technique for myocardial tissue/whole heart preparations and (3) real-time calcium imaging coupled with a laser optical trap technique for cardiomyocytes. Following the overview of each methodology, results are presented. We conclude that individual MEC in cardiomyocytes can be heterogeneous at the ventricular level, especially when moderate amplitude mechanical stretches are applied to the heart, and that this heterogeneous MEC can evoke focal excitation that develops into re-entrant arrhythmias.

  5. Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate

    SciTech Connect

    Vijayakumar, P.; Anandha Babu, G.; Ramasamy, P.

    2012-04-15

    Graphical abstract: p-Toluidinium p-toluenesulphonate (p-TTS) an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that p-TTS crystallizes in monoclinic crystal system. p-TTS single crystal belongs to negative birefringence crystal. Second harmonic conversion efficiency of p-TTS has been found to be 1.3 times higher than that of KDP. Multiple shot surface laser damage threshold is determined to be 0.30 GW/cm{sup 2} at 1064 nm laser radiation. Highlights: Black-Right-Pointing-Pointer It deals with the synthesis, growth and characterization of p-TTS an organic NLO crystal. Black-Right-Pointing-Pointer Wide optical transparency window between 280 nm and 1100 nm. Black-Right-Pointing-Pointer Negative birefringence crystal and dispersion of birefringence is negligibly small. Black-Right-Pointing-Pointer Thermal study reveals that the grown crystal is stable up to 210 Degree-Sign C. Black-Right-Pointing-Pointer Multiple shot surface laser damage threshold is 0.30 GW/cm{sup 2} at 1064 nm laser radiation. -- Abstract: p-Toluidinium p-toluenesulphonate (p-TTS) an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that p-TTS crystallizes in monoclinic crystal system. The structural perfection of the grown p-TTS single crystal has been analyzed by high-resolution X-ray diffraction rocking curve measurements. Fourier transform infrared spectral studies have been performed to identify the functional groups. The optical transmittance window and the lower cutoff wavelength of the grown crystals have been identified by UV-vis-IR studies. Birefringence of p-TTS crystal has been studied using channel spectrum measurement. The laser damage threshold value was measured using Nd:YAG laser. The second harmonic conversion efficiency of p-TTS has

  6. CARBON LOSS AND OPTICAL PROPERTY CHANGES DURING LONG-TERM PHOTOCHEMICAL AND BIOLOGICAL DEGRADATION OF ESTUARINE DISSOLVED ORGANIC MATTER

    EPA Science Inventory

    Terrestrially derived dissolved organic matter (DOM) impacts the optical properties of coastal seawater and affects carbon cycling on a global scale. We studied sequential long-term photochemical and biological degradation of estuarine dissolved organic matter from the
    Satilla...

  7. Distinct optical chemistry of dissolved organic matter in urban pond ecosystems.

    PubMed

    McEnroe, Nicola A; Williams, Clayton J; Xenopoulos, Marguerite A; Porcal, Petr; Frost, Paul C

    2013-01-01

    Urbanization has the potential to dramatically alter the biogeochemistry of receiving freshwater ecosystems. We examined the optical chemistry of dissolved organic matter (DOM) in forty-five urban ponds across southern Ontario, Canada to examine whether optical characteristics in these relatively new ecosystems are distinct from other freshwater systems. Dissolved organic carbon (DOC) concentrations ranged from 2 to 16 mg C L(-1) across the ponds with an average value of 5.3 mg C L(-1). Excitation-emission matrix (EEM) spectroscopy and parallel factor analysis (PARAFAC) modelling showed urban pond DOM to be characterized by microbial-like and, less importantly, by terrestrial derived humic-like components. The relatively transparent, non-humic DOM in urban ponds was more similar to that found in open water, lake ecosystems than to rivers or wetlands. After irradiation equivalent to 1.7 days of natural solar radiation, DOC concentrations, on average, decreased by 38% and UV absorbance decreased by 25%. Irradiation decreased the relative abundances of terrestrial humic-like components and increased protein-like aspects of the DOM pool. These findings suggest that high internal production and/or prolonged exposure to sunlight exerts a distinct and significant influence on the chemistry of urban pond DOM, which likely reduces its chemical similarity with upstream sources. These properties of urban pond DOM may alter its biogeochemical role in these relatively novel aquatic ecosystems.

  8. Electronic and optical excitations in building blocks of the metal organic framework MOF-5

    NASA Astrophysics Data System (ADS)

    Shi, Bin; Hung, Linda; Yildirim, Taner; Ogut, Serdar

    Metal organic frameworks (MOFs) are a relatively new class of materials which are made of metal-oxide clusters linked by organic bridging ligands. In recent years, MOFs have received considerable attention due to their widely tunable structural, chemical and physical properties. We investigate one of the well characterized MOFs, MOF-5, whose framework consists of tetrahedral [Zn40]6+ units linked by rigid arylcarboxylate ligands. We use many-body perturbation (GW +BSE) and time-dependent DFT methods in real space to examine the electronic and optical excitations in the building blocks of MOF-5, such as Zn4O(COOH)6, basic zinc acetate [Zn4O(CH3COO)6], and tetranuclear zinc benzoate [Zn4O(C6H5COO)6]. The calculated spectra are compared with available experimental measurements and existing calculations to shed light on the controversy regarding the nature (metal-ligand versus ligand-ligand) of low-energy electronic and optical excitations in MOF-5. Supported by DOE Grant No. DE-SC0001853.

  9. Distinct Optical Chemistry of Dissolved Organic Matter in Urban Pond Ecosystems

    PubMed Central

    McEnroe, Nicola A.; Williams, Clayton J.; Xenopoulos, Marguerite A.; Porcal, Petr; Frost, Paul C.

    2013-01-01

    Urbanization has the potential to dramatically alter the biogeochemistry of receiving freshwater ecosystems. We examined the optical chemistry of dissolved organic matter (DOM) in forty-five urban ponds across southern Ontario, Canada to examine whether optical characteristics in these relatively new ecosystems are distinct from other freshwater systems. Dissolved organic carbon (DOC) concentrations ranged from 2 to 16 mg C L-1 across the ponds with an average value of 5.3 mg C L-1. Excitation-emission matrix (EEM) spectroscopy and parallel factor analysis (PARAFAC) modelling showed urban pond DOM to be characterized by microbial-like and, less importantly, by terrestrial derived humic-like components. The relatively transparent, non-humic DOM in urban ponds was more similar to that found in open water, lake ecosystems than to rivers or wetlands. After irradiation equivalent to 1.7 days of natural solar radiation, DOC concentrations, on average, decreased by 38% and UV absorbance decreased by 25%. Irradiation decreased the relative abundances of terrestrial humic-like components and increased protein-like aspects of the DOM pool. These findings suggest that high internal production and/or prolonged exposure to sunlight exerts a distinct and significant influence on the chemistry of urban pond DOM, which likely reduces its chemical similarity with upstream sources. These properties of urban pond DOM may alter its biogeochemical role in these relatively novel aquatic ecosystems. PMID:24348908

  10. Field-dependent magneto-optical Kerr effect spectroscopy applied to the magnetic component diagnosis of a rubrene/Ni system.

    PubMed

    Li, Wen; Fronk, Michael; Albrecht, Manfred; Franke, Mechthild; Zahn, Dietrich R T; Salvan, Georgeta

    2014-07-28

    Polar magneto-optical Kerr effect (MOKE) spectroscopy in the energy range from 1.75 eV to 5 eV at different magnetic field strength was applied to study Ni nanostructures formed on rubrene nanoislands. The magnetic hysteresis curves measured by MOKE change the shape depending on the photon energy and therefore deviate from those measured by superconducting quantum interference device (SQUID) magnetometry. Similar optical effects were previously observed in inorganic heterostructures. Our observations show that it correlates to the change in lineshape of the MOKE rotation and ellipticity spectra as a function of magnetic field strength. We show that this spectral dependence on magnetic field can be exploited to separate the contributions of two magnetic components to the magneto-optical spectra and hysteresis. The proposed model does not require the a priori knowledge of the (magneto-)optical constants of the heterostructure and its components. PMID:25089464

  11. Magneto-optical study of the intermediate state in type-I superconductors: Effects of sample shape and applied current

    SciTech Connect

    Hoberg, Jacob Ray

    2008-01-01

    The magnetic flux structures in the intermediate state of bulk, pinning-free Type-I superconductors are studied using a high resolution magneto-optical imaging technique. Unlike most previous studies, this work focuses on the pattern formation of the coexisting normal and superconducting phases in the intermediate state. The influence of various parameters such as sample shape, structure defects (pinning) and applied current are discussed in relation to two distinct topologies: flux tubes (closed topology) and laminar (open topology). Imaging and magnetization measurements performed on samples of different shapes (cones, hemispheres and slabs), show that contrary to previous beliefs, the tubular structure is the equilibrium topology, but it is unstable toward defects and flux motion. Moreover, the application of current into a sample with the geometric barrier can replace an established laminar structure with flux tubes. At very high currents, however, there exists a laminar 'stripe pattern.' Quantitative analysis of the mean tube diameter is shown to be in good agreement with the prediction proposed by Goren and Tinkham. This is the first time that this model has been confirmed experimentally. Further research into the flux tube phase shows a direct correlation with the current loop model proposed in the 1990's by Goldstein, Jackson and Dorsey. There also appears a range of flux tube density that results in a suprafroth structure, a well-formed polygonal mesh, which behaves according to the physics of foams, following standard statistical laws such as von Neumann and Lewis. The reaction of flux structures to a fast-ramped magnetic field was also studied. This provided an alignment of the structure not normally observed at slow ramp rates.

  12. Optical spectroscopy applied to the analysis of medieval and post-medieval plain flat glass fragments excavated in Belgium

    NASA Astrophysics Data System (ADS)

    Meulebroeck, W.; Wouters, H.; Baert, K.; Ceglia, A.; Terryn, H.; Nys, K.; Thienpont, H.

    2010-04-01

    Window glass fragments from four Belgian sites were studied and for a set of eighty-five samples the UV-VIS-NIR transmission spectra were analyzed. This collection contains historical and archaeological finds originating from religious buildings namely the Basilica of Our Lady of Hanswijk in Mechelen (17th-20thc) and the Church of Our Lady in Bruges (16th-20thc) as well as from secular buildings as a private house/Antwerp (18th-1948) and the castle of Middelburg-in-Flanders (1448-17thc). All sites contain material on the hinge point between the medieval and the industrial tradition. The variation in composition of the analyzed samples can be explained by the use of different glassmaking recipes, more specifically the use of different raw materials. The composition of window glass differs essentially in the type of flux, using a potash rich fluxing agent until the post-medieval times and industrial soda from the 19th century onwards. A second difference concerns the iron impurities in the glass. For all fragments a clear compositional classification could be made based on the iron concentration. These conclusions were based on archaeological research and drawn after submitting samples to expensive, complex, time-consuming and destructive chemical analyzing methods. Our study indicates that similar conclusions could be made applying the proposed optical based methodology for plain window glass. As a whole, the obtained results make it possible to cluster the fragments for a particular site based on three different sensing parameters: the UV absorption edge, the color and the presence of characteristic absorption bands. This information helps in identifying trends to date window glass collections and indicating the use of different raw materials, production technologies and/or provenance.

  13. Calculated organ doses using Monte Carlo simulations in a reference male phantom undergoing HDR brachytherapy applied to localized prostate carcinoma

    SciTech Connect

    Candela-Juan, Cristian; Perez-Calatayud, Jose; Ballester, Facundo; Rivard, Mark J.

    2013-03-15

    Purpose: The aim of this study was to obtain equivalent doses in radiosensitive organs (aside from the bladder and rectum) when applying high-dose-rate (HDR) brachytherapy to a localized prostate carcinoma using {sup 60}Co or {sup 192}Ir sources. These data are compared with results in a water phantom and with expected values in an infinite water medium. A comparison with reported values from proton therapy and intensity-modulated radiation therapy (IMRT) is also provided. Methods: Monte Carlo simulations in Geant4 were performed using a voxelized phantom described in International Commission on Radiological Protection (ICRP) Publication 110, which reproduces masses and shapes from an adult reference man defined in ICRP Publication 89. Point sources of {sup 60}Co or {sup 192}Ir with photon energy spectra corresponding to those exiting their capsules were placed in the center of the prostate, and equivalent doses per clinical absorbed dose in this target organ were obtained in several radiosensitive organs. Values were corrected to account for clinical circumstances with the source located at various positions with differing dwell times throughout the prostate. This was repeated for a homogeneous water phantom. Results: For the nearest organs considered (bladder, rectum, testes, small intestine, and colon), equivalent doses given by {sup 60}Co source were smaller (8%-19%) than from {sup 192}Ir. However, as the distance increases, the more penetrating gamma rays produced by {sup 60}Co deliver higher organ equivalent doses. The overall result is that effective dose per clinical absorbed dose from a {sup 60}Co source (11.1 mSv/Gy) is lower than from a {sup 192}Ir source (13.2 mSv/Gy). On the other hand, equivalent doses were the same in the tissue and the homogeneous water phantom for those soft tissues closer to the prostate than about 30 cm. As the distance increased, the differences of photoelectric effect in water and soft tissue, and appearance of other materials

  14. Molecular organization of the desmosome as revealed by direct stochastic optical reconstruction microscopy.

    PubMed

    Stahley, Sara N; Bartle, Emily I; Atkinson, Claire E; Kowalczyk, Andrew P; Mattheyses, Alexa L

    2016-08-01

    Desmosomes are macromolecular junctions responsible for providing strong cell-cell adhesion. Because of their size and molecular complexity, the precise ultrastructural organization of desmosomes is challenging to study. Here, we used direct stochastic optical reconstruction microscopy (dSTORM) to resolve individual plaque pairs for inner and outer dense plaque proteins. Analysis methods based on desmosomal mirror symmetry were developed to measure plaque-to-plaque distances and create an integrated map. We quantified the organization of desmoglein 3, plakoglobin and desmoplakin (N-terminal, rod and C-terminal domains) in primary human keratinocytes. Longer desmosome lengths correlated with increasing plaque-to-plaque distance, suggesting that desmoplakin is arranged with its long axis at an angle within the plaque. We next examined whether plaque organization changed in different adhesive states. Plaque-to-plaque distance for the desmoplakin rod and C-terminal domains decreased in PKP-1-mediated hyperadhesive desmosomes, suggesting that protein reorganization correlates with function. Finally, in human epidermis we found a difference in plaque-to-plaque distance for the desmoplakin C-terminal domain, but not the desmoplakin rod domain or plakoglobin, between basal and suprabasal cells. Our data reveal the molecular organization of desmosomes in cultured keratinocytes and skin as defined by dSTORM. PMID:27505428

  15. Prediction of nonlinear optical properties of organic materials. General theoretical considerations

    NASA Technical Reports Server (NTRS)

    Cardelino, B.; Moore, C.; Zutaut, S.

    1993-01-01

    The prediction of nonlinear optical properties of organic materials is geared to assist materials scientists in the selection of good candidate molecules. A brief summary of the quantum mechanical methods used for estimating hyperpolarizabilities will be presented. The advantages and limitations of each technique will be discussed. Particular attention will be given to the finite-field method for calculating first and second order hyperpolarizabilities, since this method is better suited for large molecules. Corrections for dynamic fields and bulk effects will be discussed in detail, focusing on solvent effects, conformational isomerization, core effects, dispersion, and hydrogen bonding. Several results will be compared with data obtained from third-harmonic-generation (THG) and dc-induced second harmonic generation (EFISH) measurements. These comparisons will demonstrate the qualitative ability of the method to predict the relative strengths of hyperpolarizabilities of a class of compounds. The future application of molecular mechanics, as well as other techniques, in the study of bulk properties and solid state defects will be addressed. The relationship between large values for nonlinear optical properties and large conjugation lengths is well known, and is particularly important for third-order processes. For this reason, the materials with the largest observed nonresonant third-order properties are conjugated polymers. An example of this type of polymer is polydiacetylene. One of the problems in dealing with polydiacetylene is that substituents which may enhance its nonlinear properties may ultimately prevent it from polymerizing. A model which attempts to predict the likelihood of solid-state polymerization is considered, along with the implications of the assumptions that are used. Calculations of the third-order optical properties and their relationship to first-order properties and energy gaps will be discussed. The relationship between monomeric and

  16. Ethanol alters gene expression and cell organization during optic vesicle evagination.

    PubMed

    Santos-Ledo, A; Cavodeassi, F; Carreño, H; Aijón, J; Arévalo, R

    2013-10-10

    Ethanol has been described as a teratogen in vertebrate development. During early stages of brain formation, ethanol affects the evagination of the optic vesicles, resulting in synophthalmia or cyclopia, phenotypes where the optic vesicles partially or totally fuse. The mechanisms by which ethanol affects the morphogenesis of the optic vesicles are however largely unknown. In this study we make use of in situ hybridization, electron microscopy and immunohistochemistry to show that ethanol has profound effects on cell organization and gene expression during the evagination of the optic vesicles. Exposure to ethanol during early eye development alters the expression patterns of some genes known to be important for eye morphogenesis, such as rx3/1 and six3a. Furthermore, exposure to ethanol interferes with the acquisition of neuroepithelial features by the eye field cells, which is clear at ultrastructual level. Indeed, ethanol disrupts the acquisition of fusiform cellular shapes within the eye field. In addition, tight junctions do not form and retinal progenitors do not properly polarize, as suggested by the mis-localization and down-regulation of zo1. We also show that the ethanol-induced cyclopic phenotype is significantly different to that observed in cyclopic mutants, suggesting a complex effect of ethanol on a variety of targets. Our results show that ethanol not only disrupts the expression pattern of genes involved in retinal morphogenesis, such as rx3 and rx1, but also disrupts the changes in cell polarity that normally occur during eye field splitting. Thus, ethylic teratology seems to be related not only to modifications in gene expression and cell death but also to alterations in cell morphology.

  17. AnSBBR applied to organic matter and sulfate removal: interaction effect between feed strategy and COD/sulfate ratio.

    PubMed

    Friedl, Gregor F; Mockaitis, Gustavo; Rodrigues, José A D; Ratusznei, Suzana M; Zaiat, Marcelo; Foresti, Eugênio

    2009-10-01

    A mechanically stirred anaerobic sequencing batch reactor containing anaerobic biomass immobilized on polyurethane foam cubes, treating low-strength synthetic wastewater (500 mg COD L(-1)), was operated under different operational conditions to assess the removal of organic matter and sulfate. These conditions were related to fill time, defined by the following feed strategies: batch mode of 10 min, fed-batch mode of 3 h and fed-batch mode of 6 h, and COD/[SO(4)(2-)] ratios of 1.34, 0.67, and 0.34 defined by organic matter concentration of 500 mg COD L(-1) and sulfate concentrations of 373, 746, and 1,493 mg SO(4)(2-) L(-1) in the influent. Thus, nine assays were performed to investigate the influence of each of these parameters, as well as the interaction effect, on the performance of the system. The reactor operated with agitation of 400 rpm, total volume of 4.0 L, and treated 2.0 L synthetic wastewater in 8-h cycles at 30 +/- 1 degrees C. During all assays, the reactor showed operational stability in relation to the monitored variables such as COD, sulfate, sulfide, sulfite, volatile acids, bicarbonate alkalinity, and solids, thus demonstrating the potential to apply this technology to the combined removal of organic matter and sulfate. In general, the results showed that the 3-h fed-batch operation with a COD/[SO(4)(2-)] ratio of 0.34 presented the best conditions for organic matter removal (89%). The best efficiency for sulfate removal (71%) was accomplished during the assay with a COD/[SO(4)(2-)] ratio of 1.34 and a fill time of 6 h. It was also observed that as fill time and sulfate concentration in the influent increased, the ratio between removed sulfate load and removed organic load also increased. However, it should be pointed out that the aim of this study was not to optimize the removal of organic matter and sulfate, but rather to analyze the behavior of the reactor during the different feed strategies and applied COD/[SO(4)(2-)] ratios, and mainly to

  18. Optical Properties of Moderately-Absorbing Organic and Mixed Organic/Inorganic Particles at Very High Humidities

    SciTech Connect

    Bond, Tami C; Rood, Mark J; Brem, Benjamin T; Mena-Gonzalez, Francisco C; Chen, Yanju

    2012-04-16

    Relative humidity (RH) affects the water content of an aerosol, altering its ability to scatter and absorb light, which is important for aerosol effects on climate and visibility. This project involves in situ measurement and modeling of aerosol optical properties including absorption, scattering and extinction at three visible wavelengths (467, 530, 660 nm), for organic carbon (OC) generated by pyrolysis of biomass, ammonium sulfate and sodium chloride, and their mixtures at controlled RH conditions. Novel components of this project include investigation of: (1) Changes in all three of these optical properties at scanned RH conditions; (2) Optical properties at RH values up to 95%, which are usually extrapolated instead of measured; and (3) Examination of aerosols generated by the pyrolysis of wood, which is representative of primary atmospheric organic carbon, and its mixture with inorganic aerosol. Scattering and extinction values were used to determine light absorption by difference and single scattering albedo values. Extensive instrumentation development and benchmarking with independently measured and modeled values were used to obtain and evaluate these new results. The single scattering albedo value for a dry absorbing polystyrene microsphere benchmark agreed within 0.02 (absolute value) with independently published results at 530 nm. Light absorption by a nigrosin (sample light-absorbing) benchmark increased by a factor of 1.24 +/-0.06 at all wavelengths as RH increased from 38 to 95%. Closure modeling with Mie theory was able to reproduce this increase with the linear volume average (LVA) refractive index mixing rule for this water soluble compound. Absorption by biomass OC aerosol increased by a factor of 2.1 +/- 0.7 and 2.3 +/- 1.2 between 32 and 95% RH at 467 nm and 530 nm, but there was no detectable absorption at 660 nm. Additionally, the spectral dependence of absorption by OC that was observed with filter measurements was confirmed qualitatively

  19. Measurements of thermodynamic and optical properties of selected aqueous organic and organic-inorganic mixtures of atmospheric relevance.

    PubMed

    Lienhard, Daniel M; Bones, David L; Zuend, Andreas; Krieger, Ulrich K; Reid, Jonathan P; Peter, Thomas

    2012-10-11

    Atmospheric aerosol particles can exhibit liquid solution concentrations supersaturated with respect to the dissolved organic and inorganic species and supercooled with respect to ice. In this study, thermodynamic and optical properties of sub- and supersaturated aqueous solutions of atmospheric interest are presented. The density, refractive index, water activity, ice melting temperatures, and homogeneous ice freezing temperatures of binary aqueous solutions containing L(+)-tartaric acid, tannic acid, and levoglucosan and ternary aqueous solutions containing levoglucosan and one of the salts NH(4)HSO(4), (NH(4))(2)SO(4), and NH(4)NO(3) have been measured in the supersaturated concentration range for the first time. In addition, the density and refractive index of binary aqueous citric acid and raffinose solutions and the glass transition temperatures of binary aqueous L(+)-tartaric acid and levoglucosan solutions have been measured. The data presented here are derived from experiments on single levitated microdroplets and bulk solutions and should find application in thermodynamic and atmospheric aerosol models as well as in food science applications.

  20. Acousto-Optic Tunable Filter Spectroscopic Instrumentation for Quantitative Near-Ir Analysis of Organic Materials.

    NASA Astrophysics Data System (ADS)

    Eilert, Arnold James

    1995-01-01

    The utility of near-IR spectroscopy for routine quantitative analyses of a wide variety of compositional, chemical, or physical parameters of organic materials is well understood. It can be used for relatively fast and inexpensive non-destructive bulk material analysis before, during, and after processing. It has been demonstrated as being a particularly useful technique for numerous analytical applications in cereal (food and feed) science and industry. Further fulfillment of the potential of near-IR spectroscopic analysis, both in the process and laboratory environment, is reliant upon the development of instrumentation that is capable of meeting the challenges of increasingly difficult applications. One approach to the development of near-IR spectroscopic instrumentation that holds a great deal of promise is acousto-optic tunable filter (AOTF) technology. A combination of attributes offered by AOTF spectrometry, including speed, optical throughput, wavelength reproducibility, ruggedness (no -moving-parts operation) and flexibility, make it particularly desirable for numerous applications. A series of prototype (research model) acousto -optic tunable filter instruments were developed and tested in order to investigate the feasibility of the technology for quantitative near-IR spectrometry. Development included design, component procurement, assembly and/or configuration of the optical and electronic subsystems of which each functional spectrometer arrangement was comprised, as well as computer interfacing and acquisition/control software development. Investigation of this technology involved an evolution of several operational spectrometer systems, each of which offered improvements over its predecessor. Appropriate testing was conducted at various stages of development. Demonstrations of the potential applicability of our AOTF spectrometer to quantitative process monitoring or laboratory analysis of numerous organic substances, including food materials, were

  1. Charge transport in organic multi-layer devices under electric and optical fields

    NASA Astrophysics Data System (ADS)

    Park, June Hyoung

    2007-12-01

    Charge transport in small organic molecules and conjugated conducting polymers under electric or optical fields is studied by using field effect transistors and photo-voltaic cells with multiple thin layers. With these devices, current under electric field, photo-current under optical field, and luminescence of optical materials are measured to characterize organic and polymeric materials. For electric transport studies, poly(3,4-ethylenedioxythiophene) doped by polystyrenesulfonic acid is used, which is conductive with conductivity of approximately 25 S/cm. Despite their high conductance, field effect transistors based on the films are successfully built and characterized by monitoring modulations of drain current by gate voltage and IV characteristic curves. Due to very thin insulating layers of poly(vinylphenol), the transistors are relative fast under small gate voltage variation although heavy ions are involved in charge transport. In IV characteristic curves, saturation effects can be observed. Analysis using conventional field effect transistor model indicates high mobility of charge carriers, 10 cm2/V·sec, which is not consistent with the mobility of the conducting polymer. It is proposed that the effect of a small density of ions injected via polymer dielectric upon application of gate voltage and the ion compensation of key hopping sites accounts for the operation of the field effect transistors. For the studies of transport under optical field, photovoltaic cells with 3 different dendrons, which are efficient to harvest photo-excited electrons, are used. These dendrons consist of two electron-donors (tetraphenylporphyrin) and one electron-accepter (naphthalenediimide). Steady-state fluorescence measurements show that inter-molecular interaction is dominant in solid dendron film, although intra-molecular interaction is still present. Intra-molecular interaction is suggested by different fluorescence lifetimes between solutions of donor and dendrons. This

  2. Pan-arctic trends in terrestrial dissolved organic matter from optical measurements

    NASA Astrophysics Data System (ADS)

    Mann, Paul; Spencer, Robert; Hernes, Peter; Six, Johan; Aiken, George; Tank, Suzanne; McClelland, James; Butler, Kenna; Dyda, Rachael; Holmes, Robert

    2016-03-01

    Climate change is causing extensive warming across arctic regions resulting in permafrost degradation, alterations to regional hydrology, and shifting amounts and composition of dissolved organic matter (DOM) transported by streams and rivers. Here, we characterize the DOM composition and optical properties of the six largest arctic rivers draining into the Arctic Ocean to examine the ability of optical measurements to provide meaningful insights into terrigenous carbon export patterns and biogeochemical cycling. The chemical composition of aquatic DOM varied with season, spring months were typified by highest lignin phenol and dissolved organic carbon (DOC) concentrations with greater hydrophobic acid content, and lower proportions of hydrophilic compounds, relative to summer and winter months. Chromophoric DOM (CDOM) spectral slope (S275-295) tracked seasonal shifts in DOM composition across river basins. Fluorescence and parallel factor analysis identified seven components across the six Arctic rivers. The ratios of 'terrestrial humic-like' versus 'marine humic-like' fluorescent components co-varied with lignin monomer ratios over summer and winter months, suggesting fluorescence may provide information on the age and degradation state of riverine DOM. CDOM absorbance (a350) proved a sensitive proxy for lignin phenol concentrations across all six river basins and over the hydrograph, enabling for the first time the development of a single pan-arctic relationship between a350 and terrigenous DOC (R2 = 0.93). Combining this lignin proxy with high-resolution monitoring of a350, pan-arctic estimates of annual lignin flux were calculated to range from 156 to 185 Gg, resulting in shorter and more constrained estimates of terrigenous DOM residence times in the Arctic Ocean (spanning 7 months to 2½ years). Furthermore, multiple linear regression models incorporating both absorbance and fluorescence variables proved capable of explaining much of the variability in

  3. Impact of local compressive stress on the optical transitions of single organic dye molecules

    NASA Astrophysics Data System (ADS)

    Stöttinger, Sven; Hinze, Gerald; Diezemann, Gregor; Oesterling, Ingo; Müllen, Klaus; Basché, Thomas

    2014-03-01

    The ability to mechanically control the optical properties of individual molecules is a grand challenge in nanoscience and could enable the manipulation of chemical reactivity at the single-molecule level. In the past, light has been used to alter the emission wavelength of individual molecules or modulate the energy transfer quantum yield between them. Furthermore, tensile stress has been applied to study the force dependence of protein folding/unfolding and of the chemistry and photochemistry of single molecules, although in these mechanical experiments the strength of the weakest bond limits the amount of applicable force. Here, we show that compressive stress modifies the photophysical properties of individual dye molecules. We use an atomic force microscope tip to prod individual molecules adsorbed on a surface and follow the effect of the applied force on the electronic states of the molecule by fluorescence spectroscopy. Applying a localized compressive force on an isolated molecule induces a stress that is redistributed throughout the structure. Accordingly, we observe reversible spectral shifts and even shifts that persist after retracting the microscope tip, which we attribute to transitions to metastable states. Using quantum-mechanical calculations, we show that these photophysical changes can be associated with transitions among the different possible conformers of the adsorbed molecule.

  4. Optical soliton in dielectric fibers and self-organization of turbulence in plasmas in magnetic fields

    PubMed Central

    Hasegawa, Akira

    2009-01-01

    One important discovery in the twentieth century physics is the natural formation of a coherent or a well-ordered structure in continuous media, in contrary to degradation of the state as predicted earlier from the second law of thermodynamics. Here nonlinearity plays the essential role in its process. The discovery of soliton, a localized stable wave in a nonlinear and dispersive medium and the self-organization of fluid turbulence are of the major examples. A soliton is formed primarily in one-dimensional medium where the dispersion and nonlinearity play the essential role. Here the temporal evolution can be described by an infinite dimensional Hamiltonian system that is integrable. While a self-organization appears in an infinite dimensional non-Hamiltonian (or dissipative) system where more than two conservative quantities exist in the limit of no dissipation. In this manuscript, by showing examples of the optical soliton in dielectric fibers and self-organization of turbulence in a toroidal plasma in a magnetic field, we demonstrate these interesting discoveries. The manuscript is intended to describe these discoveries more on philosophical basis with some sacrifice on mathematical details so that the idea is conveyed to those in the wide area of sciences. PMID:19145067

  5. Associations Between the Molecular and Optical Properties of Dissolved Organic Matter in the Florida Everglades, a Model Coastal Wetland System.

    PubMed

    Wagner, Sasha; Jaffé, Rudolf; Cawley, Kaelin; Dittmar, Thorsten; Stubbins, Aron

    2015-01-01

    Optical properties are easy-to-measure proxies for dissolved organic matter (DOM) composition, source, and reactivity. However, the molecular signature of DOM associated with such optical parameters remains poorly defined. The Florida coastal Everglades is a subtropical wetland with diverse vegetation (e.g., sawgrass prairies, mangrove forests, seagrass meadows) and DOM sources (e.g., terrestrial, microbial, and marine). As such, the Everglades is an excellent model system from which to draw samples of diverse origin and composition to allow classically-defined optical properties to be linked to molecular properties of the DOM pool. We characterized a suite of seasonally- and spatially-collected DOM samples using optical measurements (EEM-PARAFAC, SUVA254, S275-295, S350-400, SR, FI, freshness index, and HIX) and ultrahigh resolution mass spectrometry (FTICR-MS). Spearman's rank correlations between FTICR-MS signal intensities of individual molecular formulae and optical properties determined which molecular formulae were associated with each PARAFAC component and optical index. The molecular families that tracked with the optical indices were generally in agreement with conventional biogeochemical interpretations. Therefore, although they represent only a small portion of the bulk DOM pool, absorbance, and fluorescence measurements appear to be appropriate proxies for the aquatic cycling of both optically-active and associated optically-inactive DOM in coastal wetlands. PMID:26636070

  6. Associations between the molecular and optical properties of dissolved organic matter in the Florida Everglades, a model coastal wetland system

    NASA Astrophysics Data System (ADS)

    Wagner, Sasha; Jaffe, Rudolf; Cawley, Kaelin; Dittmar, Thorsten; Stubbins, Aron

    2015-11-01

    Optical properties are easy-to-measure proxies for dissolved organic matter (DOM) composition, source and reactivity. However, the molecular signature of DOM associated with such optical parameters remains poorly defined. The Florida coastal Everglades is a subtropical wetland with diverse vegetation (e.g., sawgrass prairies, mangrove forests, seagrass meadows) and DOM sources (e.g., terrestrial, microbial and marine). As such, the Everglades is an excellent model system from which to draw samples of diverse origin and composition to allow classically-defined optical properties to be linked to molecular properties of the DOM pool. We characterized a suite of seasonally- and spatially-collected DOM samples using optical measurements (EEM-PARAFAC, SUVA254, S275-295, S350-400, SR, FI, freshness index and HIX) and ultrahigh resolution mass spectrometry (FTICR-MS). Spearman’s rank correlations between FTICR-MS signal intensities of individual molecular formulae and optical properties determined which molecular formulae were associated with each PARAFAC component and optical index. The molecular families that tracked with the optical indices were generally in agreement with conventional biogeochemical interpretations. Therefore, although they represent only a small portion of the bulk DOM pool, absorbance and fluorescence measurements appear to be appropriate proxies for the aquatic cycling of both optically-active and associated optically-inactive DOM in coastal wetlands.

  7. Associations Between the Molecular and Optical Properties of Dissolved Organic Matter in the Florida Everglades, a Model Coastal Wetland System.

    PubMed

    Wagner, Sasha; Jaffé, Rudolf; Cawley, Kaelin; Dittmar, Thorsten; Stubbins, Aron

    2015-01-01

    Optical properties are easy-to-measure proxies for dissolved organic matter (DOM) composition, source, and reactivity. However, the molecular signature of DOM associated with such optical parameters remains poorly defined. The Florida coastal Everglades is a subtropical wetland with diverse vegetation (e.g., sawgrass prairies, mangrove forests, seagrass meadows) and DOM sources (e.g., terrestrial, microbial, and marine). As such, the Everglades is an excellent model system from which to draw samples of diverse origin and composition to allow classically-defined optical properties to be linked to molecular properties of the DOM pool. We characterized a suite of seasonally- and spatially-collected DOM samples using optical measurements (EEM-PARAFAC, SUVA254, S275-295, S350-400, SR, FI, freshness index, and HIX) and ultrahigh resolution mass spectrometry (FTICR-MS). Spearman's rank correlations between FTICR-MS signal intensities of individual molecular formulae and optical properties determined which molecular formulae were associated with each PARAFAC component and optical index. The molecular families that tracked with the optical indices were generally in agreement with conventional biogeochemical interpretations. Therefore, although they represent only a small portion of the bulk DOM pool, absorbance, and fluorescence measurements appear to be appropriate proxies for the aquatic cycling of both optically-active and associated optically-inactive DOM in coastal wetlands.

  8. Associations Between the Molecular and Optical Properties of Dissolved Organic Matter in the Florida Everglades, a Model Coastal Wetland System

    PubMed Central

    Wagner, Sasha; Jaffé, Rudolf; Cawley, Kaelin; Dittmar, Thorsten; Stubbins, Aron

    2015-01-01

    Optical properties are easy-to-measure proxies for dissolved organic matter (DOM) composition, source, and reactivity. However, the molecular signature of DOM associated with such optical parameters remains poorly defined. The Florida coastal Everglades is a subtropical wetland with diverse vegetation (e.g., sawgrass prairies, mangrove forests, seagrass meadows) and DOM sources (e.g., terrestrial, microbial, and marine). As such, the Everglades is an excellent model system from which to draw samples of diverse origin and composition to allow classically-defined optical properties to be linked to molecular properties of the DOM pool. We characterized a suite of seasonally- and spatially-collected DOM samples using optical measurements (EEM-PARAFAC, SUVA254, S275−295, S350−400, SR, FI, freshness index, and HIX) and ultrahigh resolution mass spectrometry (FTICR-MS). Spearman's rank correlations between FTICR-MS signal intensities of individual molecular formulae and optical properties determined which molecular formulae were associated with each PARAFAC component and optical index. The molecular families that tracked with the optical indices were generally in agreement with conventional biogeochemical interpretations. Therefore, although they represent only a small portion of the bulk DOM pool, absorbance, and fluorescence measurements appear to be appropriate proxies for the aquatic cycling of both optically-active and associated optically-inactive DOM in coastal wetlands. PMID:26636070

  9. Validation of an optical model applied to the beam down CSP facility at the Masdar Institute Solar Platform

    NASA Astrophysics Data System (ADS)

    Grange, Benjamin; Kumar, Vikas; Torres, Juliana Beltran; Perez, Victor G.; Armstrong, Peter R.; Slocum, Alexander; Calvet, Nicolas

    2016-05-01

    In the framework of the CSPonD Demo project, the optical characterization of the Beam Down Optical Experiment (BDOE) heliostats field is an important step to certify the required power is provided. To achieve this goal, an experiment involving a single heliostat is carried out. The results of the experiment and the comparison with simulated results are presented in this paper. Only the reflection on the heliostat is observed in order to have a better assessment of its optical performance. The heliostat reflectance is modified and the experimental and simulated concentration distribution are confronted. Results indicate that the shapes of the concentration distributions are quite similar, hence validating the optical model respects the geometry of the BDOE. Moreover these results lead to an increase of the optimized heliostat reflectance when the incident angle on the heliostat decreases. Further investigation is required to validate this method with all the individual heliostats of the BDOE solar field.

  10. Optical Properties of Hybrid Inorganic/Organic Thin Film Encapsulation Layers for Flexible Top-Emission Organic Light-Emitting Diodes.

    PubMed

    An, Jae Seok; Jang, Ha Jun; Park, Cheol Young; Youn, Hongseok; Lee, Jong Ho; Heo, Gi-Seok; Choi, Bum Ho; Lee, Choong Hun

    2015-10-01

    Inorganic/organic hybrid thin film encapsulation layers consist of a thin Al2O3 layer together with polymer material. We have investigated optical properties of thin film encapsulation layers for top-emission flexible organic light-emitting diodes. The transmittance of hybrid thin film encapsulation layers and the electroluminescent spectrum of organic light-emitting diodes that were passivated by hybrid organic/inorganic thin film encapsulation layers were also examined as a function of the thickness of inorganic Al203 and monomer layers. The number of interference peaks, their intensity, and their positions in the visible range can be controlled by varying the thickness of inorganic Al2O3 layer. On the other hand, changing the thickness of monomer layer had a negligible effect on the optical properties. We also verified that there is a trade-off between transparency in the visible range and the permeation of water vapor in hybrid thin film encapsulation layers. As the number of dyads decreased, optical transparency improved while the water vapor permeation barrier was degraded. Our study suggests that, in top-emission organic light-emitting diodes, the thickness of each thin film encapsulation layer, in particular that of the inorganic layer, and the number of dyads should be controlled for highly efficient top-emission flexible organic light-emitting diodes. PMID:26726488

  11. Optical Properties of Hybrid Inorganic/Organic Thin Film Encapsulation Layers for Flexible Top-Emission Organic Light-Emitting Diodes.

    PubMed

    An, Jae Seok; Jang, Ha Jun; Park, Cheol Young; Youn, Hongseok; Lee, Jong Ho; Heo, Gi-Seok; Choi, Bum Ho; Lee, Choong Hun

    2015-10-01

    Inorganic/organic hybrid thin film encapsulation layers consist of a thin Al2O3 layer together with polymer material. We have investigated optical properties of thin film encapsulation layers for top-emission flexible organic light-emitting diodes. The transmittance of hybrid thin film encapsulation layers and the electroluminescent spectrum of organic light-emitting diodes that were passivated by hybrid organic/inorganic thin film encapsulation layers were also examined as a function of the thickness of inorganic Al203 and monomer layers. The number of interference peaks, their intensity, and their positions in the visible range can be controlled by varying the thickness of inorganic Al2O3 layer. On the other hand, changing the thickness of monomer layer had a negligible effect on the optical properties. We also verified that there is a trade-off between transparency in the visible range and the permeation of water vapor in hybrid thin film encapsulation layers. As the number of dyads decreased, optical transparency improved while the water vapor permeation barrier was degraded. Our study suggests that, in top-emission organic light-emitting diodes, the thickness of each thin film encapsulation layer, in particular that of the inorganic layer, and the number of dyads should be controlled for highly efficient top-emission flexible organic light-emitting diodes.

  12. In vivo skin absorption dynamics of topically applied pharmaceuticals monitored by fiber-optic diffuse reflectance spectroscopy

    NASA Astrophysics Data System (ADS)

    Kim, Ki-Hong; Jheon, Sanghoon; Kim, Jong-Ki

    2007-03-01

    A simple non-invasive ultra-violet/visible (UV/vis) diffusive reflectance spectroscopy combined with fiber-optics was investigated to elicit the dynamics of skin penetration in vivo of a pharmaceutical, aminolevulinic acid polyethylene glycol cream (5-ALA-PEG cream). Temporal data of the reflectance, R( λ), were measured from a bare skin region and from a skin region treated with 5-ALA cream. The difference in apparent optical density [(ΔAOD) = Δ log[1/ R( λ)

  13. Organization of columnar inputs in the third optic ganglion of a highly visual crab.

    PubMed

    Bengochea, Mercedes; Berón de Astrada, Martín

    2014-01-01

    Motion information provides essential cues for a wide variety of animal behaviors such as mate, prey, or predator detection. In decapod crustaceans and pterygote insects, visual codification of object motion is associated with visual processing in the third optic neuropile, the lobula. In this neuropile, tangential neurons collect motion information from small field columnar neurons and relay it to the midbrain where behavioral responses would be finally shaped. In highly ordered structures, detailed knowledge of the neuroanatomy can give insight into their function. In spite of the relevance of the lobula in processing motion information, studies on the neuroarchitecture of this neuropile are scant. Here, by applying dextran-conjugated dyes in the second optic neuropile (the medulla) of the crab Neohelice, we mass stained the columnar neurons that convey visual information into the lobula. We found that the arborizations of these afferent columnar neurons lie at four main lobula depths. A detailed examination of serial optical sections of the lobula revealed that these input strata are composed of different number of substrata and that the strata are thicker in the centre of the neuropile. Finally, by staining the different lobula layers composed of tangential processes we combined the present characterization of lobula input strata with the previous characterization of the neuroarchitecture of the crab's lobula based on reduced-silver preparations. We found that the third lobula input stratum overlaps with the dendrites of lobula giant tangential neurons. This suggests that columnar neurons projecting from the medulla can directly provide visual input to the crab's lobula giant neurons. PMID:24929118

  14. Organization of columnar inputs in the third optic ganglion of a highly visual crab.

    PubMed

    Bengochea, Mercedes; Berón de Astrada, Martín

    2014-01-01

    Motion information provides essential cues for a wide variety of animal behaviors such as mate, prey, or predator detection. In decapod crustaceans and pterygote insects, visual codification of object motion is associated with visual processing in the third optic neuropile, the lobula. In this neuropile, tangential neurons collect motion information from small field columnar neurons and relay it to the midbrain where behavioral responses would be finally shaped. In highly ordered structures, detailed knowledge of the neuroanatomy can give insight into their function. In spite of the relevance of the lobula in processing motion information, studies on the neuroarchitecture of this neuropile are scant. Here, by applying dextran-conjugated dyes in the second optic neuropile (the medulla) of the crab Neohelice, we mass stained the columnar neurons that convey visual information into the lobula. We found that the arborizations of these afferent columnar neurons lie at four main lobula depths. A detailed examination of serial optical sections of the lobula revealed that these input strata are composed of different number of substrata and that the strata are thicker in the centre of the neuropile. Finally, by staining the different lobula layers composed of tangential processes we combined the present characterization of lobula input strata with the previous characterization of the neuroarchitecture of the crab's lobula based on reduced-silver preparations. We found that the third lobula input stratum overlaps with the dendrites of lobula giant tangential neurons. This suggests that columnar neurons projecting from the medulla can directly provide visual input to the crab's lobula giant neurons.

  15. Dissolved Organic Carbon and Optical Properties as Indicators of Trihalomethane Formation Potential in an Agricultural Watershed

    NASA Astrophysics Data System (ADS)

    Pellerin, B. A.; Bergamaschi, B. A.; Spencer, R. G.

    2006-12-01

    Elevated concentrations of dissolved organic carbon (DOC) in the Sacramento-San Joaquin Delta waters may result in the formation of high levels of carcinogenic disinfection byproducts such as trihalomethane during drinking water treatment. The importance of Central Valley agricultural lands as sources of DOC and THM- precursors upstream of the Delta is presently unknown. We are quantifying contributions of DOC and THM- precursors from the Willow Slough watershed, a 425 km2 agriculturally-dominated catchment. During 2006, water samples were collected weekly at the mouth of the watershed and analyzed for DOC concentrations, optical properties (UV absorbance and fluorescence), and trihalomethane formation potential (THMFP). Additional synoptic samples were collected seasonally (winter, spring, summer) from 16 watershed locations and analyzed for optical properties, DOC concentrations, and THMFP. DOC concentrations generally ranged from approximately 2 to 4 mg/L at the watershed outlet during winter and spring, but increased weekly to 8 mg/L following the onset of irrigation. The THMFP at the mouth of the water was correlated with DOC concentration (r2 = 0.87), with higher concentrations during high discharge events and lower concentrations during summer and prolonged rain-free periods. In addition, the species of THM varied between high and low-flow periods, with THM formation dominated by brominated species during low- flow periods and chlorinated species during rainfall-runoff events. Optical characterization of DOC via UV absorbance and fluorescence suggests changes in DOC composition between high- and low-flow periods, likely reflective of changing sources and flowpaths of runoff.

  16. Chemical and optical changes in freshwater dissolved organic matter exposed to solar radiation

    USGS Publications Warehouse

    Osburn, C.L.; Morris, D.P.; Thorn, K.A.; Moeller, R.E.

    2001-01-01

    We studied the chemical and optical changes in the dissolved organic matter (DOM) from two freshwater lakes and a Sphagnum bog after exposure to solar radiation. Stable carbon isotopes and solid-state 13C-NMR spectra of DOM were used together with optical and chemical data to interpret results from experimental exposures of DOM to sunlight and from seasonal observations of two lakes in northeastern Pennsylvania. Solar photochemical oxidation of humic-rich bog DOM to smaller LMW compounds and to DIC was inferred from losses of UV absorbance, optical indices of molecular weight and changes in DOM chemistry. Experimentally, we observed a 1.2??? enrichment in ??13C and a 47% loss in aromatic C functionality in bog DOM samples exposed to solar UVR. Similar results were observed in the surface waters of both lakes. In late summer hypolimnetic water in humic Lake Lacawac, we observed 3 to 4.5??? enrichments in ??13C and a 30% increase in aromatic C relative to early spring values during spring mixing. These changes coincided with increases in molecular weight and UV absorbance. Anaerobic conditions of the hypolimnion in Lake Lacawac suggest that microbial metabolism may be turning over allochthonous C introduced during spring mixing, as well as autochthonous C. This metabolic activity produces HMW DOM during the summer, which is photochemically labile and isotopically distinct from allochthonous DOM or autochthonous DOM. These results suggest both photooxidation of allochthonous DOM in the epilimnion and autotrophic production of DOM by bacteria in the hypolimnion cause seasonal trends in the UV absorbance of lakes.

  17. Investigation of nonlinear optical properties of various organic materials by the Z-scan method

    NASA Astrophysics Data System (ADS)

    Ganeev, R. A.; Boltaev, G. S.; Tugushev, R. I.; Usmanov, T.

    2012-06-01

    We have studied the nonlinear optical properties of various organic materials (vegetable oil, juice, wine, cognac, Coca-Cola and Fanta drinks, Nescafé coffee, tea, gasoline, clock oil, glycerol, and polyphenyl ether) that are used in everyday life. Their nonlinearities have been studied by the Z-scan method in the near-IR and visible spectral ranges. We have shown that the majority of samples possess a nonlinear absorption; however, some of the studied materials show a strong saturated absorption and nonlinear refraction. Red wine and glycerol proved to be the most interesting materials. For these samples, we have observed a change in the sign of the nonlinear absorption with increasing laser intensity, which was attributed to the competition between two-photon absorption and saturated absorption.

  18. Optical design of transparent metal grids for plasmonic absorption enhancement in ultrathin organic solar cells.

    PubMed

    Kim, Inho; Lee, Taek Seong; Jeong, Doo Seok; Lee, Wook Seong; Kim, Won Mok; Lee, Kyeong-Seok

    2013-07-01

    Transparent metal grid combining with plasmonic absorption enhancement is a promising replacement to indium tin oxide thin films. We numerically demonstrate metal grids in one or two dimension lead to plasmonic absorption enhancements in ultrathin organic solar cells. In this paper, we study optical design of metal grids for plasmonic light trapping and identify different plasmonic modes of the surface plasmon polaritons excited at the interfaces of glass/metal grids, metal grids/active layers, and the localized surface plasmon resonance of the metal grids using numerical calculations. One dimension metal grids with the optimal design of a width and a period lead to the absorption enhancement in the ultrathin active layers of 20 nm thickness by a factor of 2.6 under transverse electric polarized light compared to the case without the metal grids. Similarly, two dimensional metal grids provide the absorption enhancement by a factor of 1.8 under randomly polarized light. PMID:24104493

  19. Stable water-dispersed organic nanoparticles: preparation, optical properties, and cell imaging application.

    PubMed

    Yang, Shumin; Lu, Dan; Tian, Leilei; He, Feng; Chen, Geng; Shen, Fangzhong; Xu, Hong; Ma, Yuguang

    2011-05-01

    Water-dispersed organic nanoparticles (NPs) constructed by the conjugated molecule 2,5,2',5'-tetra(4'-N,N-diphenylaminostyryl)biphenyl (DPA-TSB) with a high luminescence and large two-photon absorption (TPA) section were fabricated via the reprecipitation method. The average size of the NPs can be controlled from 40 nm to 80 nm by adjusting the reprecipitation conditions. The NPs in water dispersions showed high aggregative and optical stability, which were due to contributions from the special cruciform configuration and amorphous nature of DPA-TSB molecules. The cellular uptake behavior of DPA-TSB NPs was investigated to show their cell staining capabilities as nanoprobes using a confocal microscopy test in vitro. The results demonstrated that DPA-TSB NPs were readily internalized into cytoplasm with no apparent toxicity for up to 24 h, implying excellent imaging capabilities.

  20. Organic nanofibers from squarylium dyes: local morphology, optical, and electrical properties

    NASA Astrophysics Data System (ADS)

    Balzer, Frank; Schiek, Manuela; Osadnik, Andreas; Lützen, Arne; Rubahn, Horst-Günter

    2012-02-01

    Environmentally stable, non-toxic squarylium dyes with strong absorption maxima in the red and near infrared spectral region are known for almost fifty years. Despite the fact that their optoelectronic properties distinguish them as promising materials for organics based photovoltaic cells, they have regained attention only very recently. For their application in heterojunction solar cells knowledge of their nanoscopic morphology as well as nanoscopic electrical properties is paramount. In this paper thin films from two different squarylium dyes, from squarylium (SQ) and from hydroxy-squarylium (SQOH) are investigated. The thin films are either solution casted or vacuum sublimed onto substrates such as muscovite mica, which are known to promote self-assembly into oriented, crystalline nanostructures such as nanofibers. Local characterization is performed via (polarized) optical microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), and Kelvin probe force microscopy (KPFM).

  1. Polarization-resolved spectroscopy imaging of grain boundaries and optical excitations in crystalline organic thin films

    PubMed Central

    Pan, Z.; Rawat, N.; Cour, I.; Manning, L.; Headrick, R. L.; Furis, M.

    2015-01-01

    Exploration of optical properties of organic crystalline semiconductors thin films is challenging due to submicron grain sizes and the presence of numerous structural defects, disorder and grain boundaries. Here we report on the results of combined linear dichroism (LD)/ polarization-resolved photoluminescence (PL) scanning microscopy experiments that simultaneously probe the excitonic radiative recombination and the molecular ordering in solution-processed metal-free phthalocyanine crystalline thin films with macroscopic grain sizes. LD/PL images reveal the relative orientation of the singlet exciton transition dipoles at the grain boundaries and the presence of a localized electronic state that acts like a barrier for exciton diffusion across the grain boundary. We also show how this energy barrier can be entirely eliminated through the optimization of deposition parameters that results in films with large grain sizes and small-angle boundaries. These studies open an avenue for exploring the influence of long-range order on exciton diffusion and carrier transport. PMID:26365682

  2. Relationship between oxidation level and optical properties of secondary organic aerosol.

    PubMed

    Lambe, Andrew T; Cappa, Christopher D; Massoli, Paola; Onasch, Timothy B; Forestieri, Sara D; Martin, Alexander T; Cummings, Molly J; Croasdale, David R; Brune, William H; Worsnop, Douglas R; Davidovits, Paul

    2013-06-18

    Brown carbon (BrC), which may include secondary organic aerosol (SOA), can be a significant climate-forcing agent via its optical absorption properties. However, the overall contribution of SOA to BrC remains poorly understood. Here, correlations between oxidation level and optical properties of SOA are examined. SOA was generated in a flow reactor in the absence of NOx by OH oxidation of gas-phase precursors used as surrogates for anthropogenic (naphthalene, tricyclo[5.2.1.0(2,6)]decane), biomass burning (guaiacol), and biogenic (α-pinene) emissions. SOA chemical composition was characterized with a time-of-flight aerosol mass spectrometer. SOA mass-specific absorption cross sections (MAC) and refractive indices were calculated from real-time cavity ring-down photoacoustic spectrometry measurements at 405 and 532 nm and from UV-vis spectrometry measurements of methanol extracts of filter-collected particles (300 to 600 nm). At 405 nm, SOA MAC values and imaginary refractive indices increased with increasing oxidation level and decreased with increasing wavelength, leading to negligible absorption at 532 nm. Real refractive indices of SOA decreased with increasing oxidation level. Comparison with literature studies suggests that under typical polluted conditions the effect of NOx on SOA absorption is small. SOA may contribute significantly to atmospheric BrC, with the magnitude dependent on both precursor type and oxidation level. PMID:23701291

  3. Relationship between Oxidation Level and Optical Properties of Secondary Organic Aerosol

    NASA Astrophysics Data System (ADS)

    Lambe, A. T.; Cappa, C. D.; Massoli, P.; Onasch, T. B.; Forestieri, S.; Martin, A. T.; Cummings, M. J.; Croasdale, D. R.; Brune, W. H.; Worsnop, D. R.; Davidovits, P.

    2013-12-01

    Brown carbon (BrC), which may include secondary organic aerosol (SOA), can be a significant climate-forcing agent via its optical absorption properties. However, the overall contribution of SOA to BrC remains poorly understood. Here, correlations between oxidation level and optical properties of SOA are examined. SOA was generated in a flow reactor in the absence of NOx by OH oxidation of gas-phase precursors used as surrogates for anthropogenic (naphthalene, tricyclo-[5.2.1.02,6]decane), biomass burning (guaiacol), and biogenic (α-pinene) emissions. SOA chemical composition was characterized with a time-of-flight aerosol mass spectrometer. SOA mass-specific absorption cross sections (MAC) and refractive indices were calculated from real-time cavity ring-down photoacoustic spectrometry measurements at 405 and 532 nm and from UV-vis spectrometry measurements of methanol extracts of filter-collected particles (300 to 600 nm). At 405 nm, SOA MAC values and imaginary refractive indices increased with increasing oxidation level and decreased with increasing wavelength, leading to negligible absorption at 532 nm. Real refractive indices of SOA decreased with increasing oxidation level. Comparison with literature studies suggests that under typical polluted conditions the effect of NOx on SOA absorption is small. SOA may contribute significantly to atmospheric BrC, with the magnitude dependent on both precursor type and oxidation level. Mass-specific absorption cross sections (MAC) of SOA at λ = 405 nm as a function of the O/C ratio

  4. Reversible Structural Swell-Shrink and Recoverable Optical Properties in Hybrid Inorganic-Organic Perovskite.

    PubMed

    Zhang, Yupeng; Wang, Yusheng; Xu, Zai-Quan; Liu, Jingying; Song, Jingchao; Xue, Yunzhou; Wang, Ziyu; Zheng, Jialu; Jiang, Liangcong; Zheng, Changxi; Huang, Fuzhi; Sun, Baoquan; Cheng, Yi-Bing; Bao, Qiaoliang

    2016-07-26

    Ion migration in hybrid organic-inorganic perovskites has been suggested to be an important factor for many unusual behaviors in perovskite-based optoelectronics, such as current-voltage hysteresis, low-frequency giant dielectric response, and the switchable photovoltaic effect. However, the role played by ion migration in the photoelectric conversion process of perovskites is still unclear. In this work, we provide microscale insights into the influence of ion migration on the microstructure, stability, and light-matter interaction in perovskite micro/nanowires by using spatially resolved optical characterization techniques. We observed that ion migration, especially the migration of MA(+) ions, will induce a reversible structural swell-shrink in perovskites and recoverably affect the reflective index, quantum efficiency, light-harvesting, and photoelectric properties. The maximum ion migration quantity in perovskites was as high as approximately 30%, resulting in lattice swell or shrink of approximately 4.4%. Meanwhile, the evidence shows that ion migration in perovskites could gradually accelerate the aging of perovskites because of lattice distortion in the reversible structural swell-shrink process. Knowledge regarding reversible structural swell-shrink and recoverable optical properties may shed light on the development of optoelectronic and converse piezoelectric devices based on perovskites.

  5. Analyzing degradation effects of organic light-emitting diodes via transient optical and electrical measurements

    SciTech Connect

    Schmidt, Tobias D. Jäger, Lars; Brütting, Wolfgang; Noguchi, Yutaka; Ishii, Hisao

    2015-06-07

    Although the long-term stability of organic light-emitting diodes (OLEDs) under electrical operation made significant progress in recent years, the fundamental underlying mechanisms of the efficiency decrease during operation are not well understood. Hence, we present a comprehensive degradation study of an OLED structure comprising the well-known green phosphorescent emitter Ir(ppy){sub 3}. We use transient methods to analyze both electrical and optical changes during an accelerated aging protocol. Combining the results of displacement current measurements with time-resolved investigation of the excited states lifetimes of the emitter allows for a correlation of electrical (e.g., increase of the driving voltage due to trap formation) and optical (e.g., decrease of light-output) changes induced by degradation. Therewith, it is possible to identify two mechanisms resulting in the drop of the luminance: a decrease of the radiative quantum efficiency of the emitting system due to triplet-polaron-quenching at trapped charge carriers and a modified charge carrier injection and transport, as well as trap-assisted non-radiative recombination resulting in a deterioration of the charge carrier balance of the device.

  6. Reversible Structural Swell-Shrink and Recoverable Optical Properties in Hybrid Inorganic-Organic Perovskite.

    PubMed

    Zhang, Yupeng; Wang, Yusheng; Xu, Zai-Quan; Liu, Jingying; Song, Jingchao; Xue, Yunzhou; Wang, Ziyu; Zheng, Jialu; Jiang, Liangcong; Zheng, Changxi; Huang, Fuzhi; Sun, Baoquan; Cheng, Yi-Bing; Bao, Qiaoliang

    2016-07-26

    Ion migration in hybrid organic-inorganic perovskites has been suggested to be an important factor for many unusual behaviors in perovskite-based optoelectronics, such as current-voltage hysteresis, low-frequency giant dielectric response, and the switchable photovoltaic effect. However, the role played by ion migration in the photoelectric conversion process of perovskites is still unclear. In this work, we provide microscale insights into the influence of ion migration on the microstructure, stability, and light-matter interaction in perovskite micro/nanowires by using spatially resolved optical characterization techniques. We observed that ion migration, especially the migration of MA(+) ions, will induce a reversible structural swell-shrink in perovskites and recoverably affect the reflective index, quantum efficiency, light-harvesting, and photoelectric properties. The maximum ion migration quantity in perovskites was as high as approximately 30%, resulting in lattice swell or shrink of approximately 4.4%. Meanwhile, the evidence shows that ion migration in perovskites could gradually accelerate the aging of perovskites because of lattice distortion in the reversible structural swell-shrink process. Knowledge regarding reversible structural swell-shrink and recoverable optical properties may shed light on the development of optoelectronic and converse piezoelectric devices based on perovskites. PMID:27386731

  7. Physical and Mathematical Methods for Removing Organic Interference from Optical Isotope Measurements

    NASA Astrophysics Data System (ADS)

    Hsiao, G.; Chappellet-Volini, L.; Vu, D.

    2012-12-01

    Portable high precision isotope analyzers using CRDS technology have greatly increased the use of stable isotopes in hydrological, oceanographic, and ecological studies over the past five years. However studies of some water samples yielded incorrect isotopic values indicating some form of spectroscopic interference. Subsequent work has shown that waters derived from some plants containing interfering alcohols but meteoric waters are not affected. The initial approach to handling such samples was to use spectroscopic anomalies to identify and flag affected samples for later analysis by non-optical methods. This presentation will examine the approaches developed within the past year to allow for accurate analysis of such samples by optical methods. The first approach uses an advanced spectroscopic model to identify and quantify alcohols present in the sample. The alcohol signal is incorporated into the overall fit of the measure spectra to calculate the concentration of the individual isotopes. It was found that the δ18O value could be calculated with high accuracy, the result for the δ2H value was sufficient for many applications. The second approach uses physical treatment of the sample to break down the organic molecules into non-interfering species. The liquid sample is injected into a flash vaporizer then the vapor travels through a cartridge for physical treatment prior to analysis by CRDS. Inside the cartridge the organic molecules undergo oxidation at high temperature in the air carrier gas when exposed to the catalyst. This approach is highly effective for ethanol solutions as high as 5% as well as for the complex mixtures of alcohols found in plants. Comparison of the results of both of these methods will be compared with tertiary techniques such as IRMS where possible.

  8. Effect of intrinsic organic carbon on the optical properties of fresh diesel soot

    PubMed Central

    Adler, Gabriella; Riziq, Ali Abo; Erlick, Carynelisa; Rudich, Yinon

    2010-01-01

    This study focuses on the retrieval of the normalized mass absorption cross section (MAC) of soot using theoretical calculations that incorporate new measurements of the optical properties of organic carbon (OC) intrinsic to fresh diesel soot. Intrinsic OC was extracted by water and an organic solvent, and the complex refractive index of the extracted OC was derived at 532 and 355-nm wavelengths using cavity ring-down aerosol spectrometry. The extracted OC was found to absorb weakly in the visible wavelengths and moderately at blue wavelengths. The mass ratio of OC and elemental carbon (EC) in the collected particles was evaluated using a thermo-optical method. The measured EC/OC ratio in the soot exhibited substantial variability from measurement to measurement, ranging between 2 and 5. To test the sensitivity of the MAC to this variability, three different EC/OC ratios (2∶1, 1∶1, and 1∶2) were chosen as representative. Particle size and spherule morphology were estimated using scanning electron microscopy, and the soot was found to be primarily in the form of aggregates with a dominant aggregate diameter mode in the range 200–250 nm. The measured refractive index of the extracted OC was used with a variety of theoretical models to calculate the MAC of internally mixed diesel soot at 532 and 355 nm. We conclude that Rayleigh–Debye–Gans theory on clusters of coated spherules and T-matrix of a solid EC spheroid coated by intrinsic OC are both consistent with previous measurements; however, Rayleigh–Debye–Gans theory provides a more realistic physical model for the calculation PMID:20018649

  9. A novel approach to smart grid technology for electrical power transmission lines by a self-organized optical network node based on optical bistability

    NASA Astrophysics Data System (ADS)

    Nakanishi, Soichiro; Sasaki, Wakao

    2011-01-01

    In this work, we have demonstrated a new smart grid model by our novel green photonics technology based on selforganized optical networks realizing an autonomous peer-to-peer electric power transmissions without centralized control for the power grid. In this optical network, we introduced an adaptive algorithm for concurrent peer-to-peer communications, by utilizing optical nonlinearity depending only on the signal strength passing through the network. This method is applicable for autonomous organization of functions for ad-hoc electric power distribution systems for the power grid. For this purpose, a simple optical- electrical hybrid bistable circuit composed of such as light emitting diode (LED) and photo diode (PD), has been incorporated into the network node. In the experiment, the method uses a simple, local adaptation of transmission weights at each network node, which enables self-organizing functions of the network, such as self-routing, self-optimization, self-recovery and self-protection. Based on this method, we have demonstrated experimentally a new smart grid model applicable for ad-hoc electric power distribution systems mediated by power comsumptions. In this model, electric power flow is controlled autonomously through the self-organized network nodes associated with individual power facilities having photovoltaics and electric storage devices, etc., and the nodes convert the amounts of electric power supply and/or comsumption to the light intensity values using above mentioned transmission weights at each node. As a consequence, we have experimentally demonstrated a simple shorthaul system model for ad-hoc electric power distribution with a self-organized optical network as a novel green photonics technology application for smart grid.

  10. Use of Rigid Liquid Crystalline Polypeptides as Alignment Matrices for Organic Nonlinear Optical Molecules.

    NASA Astrophysics Data System (ADS)

    Tokarski, Zbigniew

    The orientation of nonlinear optical (NLO) organic molecules is crucial for the existence of high values for the macroscopic susceptibilities. The orientation and interaction of several smaller NLO active molecules with an easily alignable polypeptide host was investigated to determine which functional groups and molecular shapes would produce the largest orientation with the host material; these parameters included aromatic vs aliphatic, polar vs nonpolar, saturate vs unsaturated hydrocarbons and the length of the guest molecule. The host materials were either poly ( gamma-benzyl-l-glutamate) (PBLG) or poly ( gamma-ethyl-l-glutamate) (PELG) lyotropic liquid crystals. These host polymers formed pseudo-hexagonal crystalline structures with long rigid alpha -helical backbones. The interstitial alignment of the guest molecules was dictated by the overall alignment of the host polypeptide rigid rods. Within these films many of the guest molecules existed in a metastable state that delayed phase separation for several hours. The rate of phase separation was influenced by the concentration of the guest molecule and on the side chain moiety of the polypeptide. Guest phase separation to a solid or a liquid occurred at a faster rate in PELG films, due to the lack of the side chain induced hindrance, than in PBLG films. An indicator of the occurrence of phase separation was with the onset of opaqueness in the films. The thin polypeptide films containing the aligned guest molecules became optically opaque as the incompatibilities between the side chains of the polypeptides and the guest molecules increased. The nonlinear optical susceptibility measurements were hampered by either the low guest solubility or the low concentration level required to avoid the guest -host incompatibility. Electro-optic and degenerate two and four wave mixing were done and produced signals in solutions but not in the doped films. The semiflexible aromatic guest molecules, such as the derivatives

  11. A 45° saw-dicing process applied to a glass substrate for wafer-level optical splitter fabrication for optical coherence tomography

    NASA Astrophysics Data System (ADS)

    Maciel, M. J.; Costa, C. G.; Silva, M. F.; Gonçalves, S. B.; Peixoto, A. C.; Ribeiro, A. Fernando; Wolffenbuttel, R. F.; Correia, J. H.

    2016-08-01

    This paper reports on the development of a technology for the wafer-level fabrication of an optical Michelson interferometer, which is an essential component in a micro opto-electromechanical system (MOEMS) for a miniaturized optical coherence tomography (OCT) system. The MOEMS consists on a titanium dioxide/silicon dioxide dielectric beam splitter and chromium/gold micro-mirrors. These optical components are deposited on 45° tilted surfaces to allow the horizontal/vertical separation of the incident beam in the final micro-integrated system. The fabrication process consists of 45° saw dicing of a glass substrate and the subsequent deposition of dielectric multilayers and metal layers. The 45° saw dicing is fully characterized in this paper, which also includes an analysis of the roughness. The optimum process results in surfaces with a roughness of 19.76 nm (rms). The actual saw dicing process for a high-quality final surface results as a compromise between the dicing blade’s grit size (#1200) and the cutting speed (0.3 mm s-1). The proposed wafer-level fabrication allows rapid and low-cost processing, high compactness and the possibility of wafer-level alignment/assembly with other optical micro components for OCT integrated imaging.

  12. A 45° saw-dicing process applied to a glass substrate for wafer-level optical splitter fabrication for optical coherence tomography

    NASA Astrophysics Data System (ADS)

    Maciel, M. J.; Costa, C. G.; Silva, M. F.; Gonçalves, S. B.; Peixoto, A. C.; Ribeiro, A. Fernando; Wolffenbuttel, R. F.; Correia, J. H.

    2016-08-01

    This paper reports on the development of a technology for the wafer-level fabrication of an optical Michelson interferometer, which is an essential component in a micro opto-electromechanical system (MOEMS) for a miniaturized optical coherence tomography (OCT) system. The MOEMS consists on a titanium dioxide/silicon dioxide dielectric beam splitter and chromium/gold micro-mirrors. These optical components are deposited on 45° tilted surfaces to allow the horizontal/vertical separation of the incident beam in the final micro-integrated system. The fabrication process consists of 45° saw dicing of a glass substrate and the subsequent deposition of dielectric multilayers and metal layers. The 45° saw dicing is fully characterized in this paper, which also includes an analysis of the roughness. The optimum process results in surfaces with a roughness of 19.76 nm (rms). The actual saw dicing process for a high-quality final surface results as a compromise between the dicing blade’s grit size (#1200) and the cutting speed (0.3 mm s‑1). The proposed wafer-level fabrication allows rapid and low-cost processing, high compactness and the possibility of wafer-level alignment/assembly with other optical micro components for OCT integrated imaging.

  13. Evaluation of optical and electronic properties of silicon nano-agglomerates embedded in SRO: applying density functional theory

    PubMed Central

    2014-01-01

    In systems in atomic scale and nanoscale such as clusters or agglomerates constituted by particles from a few to less than 100 atoms, quantum confinement effects are very important. Their optical and electronic properties are often dependent on the size of the systems and the way in which the atoms in these clusters are bonded. Generally, these nanostructures display optical and electronic properties significantly different to those found in corresponding bulk materials. Silicon agglomerates embedded in silicon rich oxide (SRO) films have optical properties, which have been reported to be directly dependent on silicon nanocrystal size. Furthermore, the room temperature photoluminescence (PL) of SRO has repeatedly generated a huge interest due to its possible applications in optoelectronic devices. However, a plausible emission mechanism has not been widely accepted in the scientific community. In this work, we present a short review about the experimental results on silicon nanoclusters in SRO considering different techniques of growth. We focus mainly on their size, Raman spectra, and photoluminescence spectra. With this as background, we employed the density functional theory with a functional B3LYP and a basis set 6-31G* to calculate the optical and electronic properties of clusters of silicon (constituted by 15 to 20 silicon atoms). With the theoretical calculation of the structural and optical properties of silicon clusters, it is possible to evaluate the contribution of silicon agglomerates in the luminescent emission mechanism, experimentally found in thin SRO films. PMID:25276105

  14. Effects on soil organic matter mineralization and microbiological properties of applying compost to burned and unburned soils.

    PubMed

    Turrión, M B; Lafuente, F; Mulas, R; López, O; Ruipérez, C; Pando, V

    2012-03-01

    This study was undertaken in the context of a project of reclamation of a burned forest area applying municipal waste compost (MWC) and it consisted of an incubation experience carried out under laboratory conditions. The objectives of this research were to asses the effect of three doses of MWC added to burned and unburned calcareous soils on a) SOM mineralization and b) soil microbiological parameters. The laboratory incubation experience was carried out with three compost doses (1, 2 and 4% w/w) on a burned soil and another unburned one from an adjacent plot, besides the corresponding control samples. The mineralization kinetics of the organic matter was studied for 92 days. The kinetics data were adjusted to a double exponential model, showing two C pools of different degrees of resistance to mineralization and concentration, with half-life times of 1.9-4.9 and 34-76 days, respectively. In the unburned soil, the initial potential mineralization rate of the labile and stable C pools showed an opposed behavior, increased and decreased with the MWC dose, respectively. However in the burned soil no significant tendencies were observed. Although applying compost tended to increase the size of more labile pool with respect to total mineralizable C, however most of the soil or compost OM did not result mineralizable in the short and medium term. The compost amendment did not increase soil microbial activity.

  15. Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: organic carbon

    NASA Astrophysics Data System (ADS)

    Dillner, A. M.; Takahama, S.

    2014-11-01

    Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, the organic carbon concentration is measured using thermal methods such as Thermal-Optical Reflectance (TOR) from quartz fiber filters. Here, methods are presented whereby Fourier Transform Infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters are used to accurately predict TOR OC. Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filters. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites sampled during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to artifact-corrected TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date which leads to precise and accurate OC predictions by FT-IR as indicated by high coefficient of determination (R2; 0.96), low bias (0.02 μg m-3, all μg m-3 values based on the nominal IMPROVE sample volume of 32.8 m-3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision and accuracy to collocated TOR measurements. FT-IR spectra are also divided into calibration and test sets by OC mass and by OM / OC which reflects the organic composition of the particulate matter and is obtained from organic functional group composition; this division also leads to precise and accurate OC predictions. Low OC concentrations have higher bias and normalized error due to TOR analytical errors and artifact correction errors, not due to the range of OC mass of the samples in the calibration set. However, samples with low OC mass can be used to predict samples with high OC mass indicating that the

  16. Effect of applied voltage, initial concentration and natural organic matter on sequential reduction/oxidation of nitrobenzene by graphite electrodes

    PubMed Central

    Sun, Mei; Reible, Danny D.; Lowry, Gregory V.; Gregory, Kelvin B.

    2012-01-01

    Carbon electrodes are proposed in reactive sediment caps for in situ treatment of contaminants. The electrodes produce reducing conditions and H2 at the cathode and oxidizing conditions and O2 at the anode. Emplaced perpendicular to seepage flow, the electrodes provide the opportunity for sequential reduction and oxidation of contaminants. The objectives of this study are to demonstrate degradation of nitrobenzene (NB) as a probe compound for sequential electrochemical reduction and oxidation, and to determine the effect of applied voltage, initial concentration and natural organic matter on the degradation rate. In H-cell reactors with graphite electrodes and buffer solution, NB was reduced stoichiometrically to aniline (AN) at the cathode with nitrosobenzene (NSB) as the intermediate. AN was then removed at the anode, faster than the reduction step. No common AN oxidation intermediate was detected in the system. Both the first order reduction rate constants of NB (kNB) and NSB (kNSB) increased with applied voltage between 2V and 3.5 V (when the initial NB concentration was 100 µM, kNB=0.3 d−1 and kNSB=0.04 d−1at 2V; kNB=1.6 d−1 and kNSB=0.64 d−1at 3.5 V) but stopped increasing beyond the threshold of 3.5V. When initial NB concentration decreased from 100 to 5 µM, kNB and kNSB became 9 and 5 times faster, respectively, suggesting that competition for active sites on the electrode surface is an important factor in NB degradation. Presence of natural organic matter (in forms of either humic acid or Anacostia River sediment porewater) decreased kNB while slightly increased kNSB, but only to a limited extent (~factor of 3) for dissolved organic carbon content up to 100 mg/l. These findings suggest that electrode-based reactive sediment capping via sequential reduction/oxidation is a potentially robust and tunable technology for in situ contaminants degradation. PMID:22571797

  17. Optical sensors based on monolithic integrated organic light-emitting diodes (OLEDs)

    NASA Astrophysics Data System (ADS)

    Reckziegel, S.; Kreye, D.; Puegner, T.; Grillberger, C.; Toerker, M.; Vogel, U.; Amelung, J.

    2008-04-01

    Organic light-emitting diodes (OLEDs) permit the monolithic integration of microelectronic circuits and light-emitting devices on the same silicon chip. By the use of integrated photodetectors, low-cost CMOS processes and simple packaging; economically produced optoelectronic integrated circuits (OEICs) with combined sensors and actuating elements can be realized. The OLEDs are deposited directly on the top metal layer. The metal layer serves as electrode and defines the bright area. Furthermore, the area below the electrodes can be used for integrated circuits. Due to efficient emitter with low operating voltage it is possible to renounce high-voltage devices depending on selected CMOS process. Thus manufacturing cost can be further reduced. Different CMOS metallizations were examined and their effects on organic light-emitting diodes were analyzed. Red (628nm) and orange (597nm) emitting p-i-n OLEDs with a radiance of 5W/m2sr at 2.8V and 3.0V and a half angle of +/-45° were realized on metal layer with low roughness. Near infra-red emitters are in development. We will present an optical microsystem. The functionality of combined sensors and actuating elements as well as advantages and difficulties of the monolithic integration of OLEDs and CMOS will be discussed. The chip was manufactured in a commercial 1μm CMOS technology. The fabricated microsystem combines three different types of sensors: a reflective sensor, a colour sensor and a particle flow sensor.

  18. Structure, Optical Absorption, and Performance of Organic Solar Cells Improved by Gold Nanoparticles in Buffer Layers.

    PubMed

    Yang, Yingguo; Feng, Shanglei; Li, Meng; Wu, Zhongwei; Fang, Xiao; Wang, Fei; Geng, Dongping; Yang, Tieying; Li, Xiaolong; Sun, Baoquan; Gao, Xingyu

    2015-11-11

    11-Mercaptoundecanoic acid (MUA)-stabilized gold nanoparticles (AuNPs) embedded in copper phthalocyanine (CuPc) were used as a buffer layer between a poly(3-hexyl-thiophene) (P3HT)/[6,6]-phenyl C61-butyric acid methyl ester (PCBM) bulk heterojunction and anodic indium-tin oxide (ITO) substrate. As systematic synchrotron-based grazing incidence X-ray diffraction (GIXRD) experiments demonstrated that the AuNPs present in the buffer layer can improve the microstructure of the active layer with a better lamella packing of P3HT from the surface to the interior, UV-visible absorption spectrum measurements revealed enhanced optical absorption due to the localized surface plasma resonance (LSPR) generated by the AuNPs. The device of ITO/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate/CuPc:MUA-stabilized AuNPs/P3HT:PCBM/LiF/Al was found with over 24% enhancement of power conversion efficiency (PCE) in comparison with reference devices without AuNPs. This remarkable improvement in PCE should be partially attributed to LSPR generated by the AuNPs and partially to improved crystallization as well as preferred orientation order of P3HT due to the presence of the AuNPs, which would promote more applications of metal NPs in the organic photovoltaic devices and other organic multilayer devices. PMID:26477556

  19. Organic component vapor pressures and hygroscopicities of aqueous aerosol measured by optical tweezers.

    PubMed

    Cai, Chen; Stewart, David J; Reid, Jonathan P; Zhang, Yun-hong; Ohm, Peter; Dutcher, Cari S; Clegg, Simon L

    2015-01-29

    Measurements of the hygroscopic response of aerosol and the particle-to-gas partitioning of semivolatile organic compounds are crucial for providing more accurate descriptions of the compositional and size distributions of atmospheric aerosol. Concurrent measurements of particle size and composition (inferred from refractive index) are reported here using optical tweezers to isolate and probe individual aerosol droplets over extended timeframes. The measurements are shown to allow accurate retrievals of component vapor pressures and hygroscopic response through examining correlated variations in size and composition for binary droplets containing water and a single organic component. Measurements are reported for a homologous series of dicarboxylic acids, maleic acid, citric acid, glycerol, or 1,2,6-hexanetriol. An assessment of the inherent uncertainties in such measurements when measuring only particle size is provided to confirm the value of such a correlational approach. We also show that the method of molar refraction provides an accurate characterization of the compositional dependence of the refractive index of the solutions. In this method, the density of the pure liquid solute is the largest uncertainty and must be either known or inferred from subsaturated measurements with an error of <±2.5% to discriminate between different thermodynamic treatments.

  20. Optical characterization of dissolved organic matter in the Amazon River Plume and the adjacent deep ocean

    NASA Astrophysics Data System (ADS)

    Cao, F.; Medeiros, P. M.; Miller, W. L.

    2012-12-01

    The Amazon River is the largest river in the world and a major source of terrestrially-derived organic matter to the Atlantic Ocean, accounting for ~ 20% of the global freshwater discharge. To document the quantity and quality of the colored dissolved organic matter (CDOM) in the Amazon River Plume (ARP), the optical properties (absorption and fluorescence intensity) of the CDOM were investigated in water samples collected during two cruises conducted at periods of low (Sep/2011) and high (Jul/2012) river discharge. Excitation emission matrix fluoresces combined with parallel factor analysis (EEMS-PARAFAC) was used to determine the composition of the CDOM, and four components were identified: two terrestrial humic-like components (C1 and C4), one marine humic-like component (C3), and one autochthonous tryptophan-like component (C2). This agrees with results of mass spectrometry analysis that showed a distinction among DOM composition found in river, plume, and open ocean water. Correlation analysis between the fluorescence components and salinity in the ARP suggests that humic-like fluorescent components can be used to trace DOM mixing behavior in the ARP and adjacent waters.

  1. Optical properties of secondary organic aerosols generated by photooxidation of aromatic hydrocarbons

    PubMed Central

    Li, Kun; Wang, Weigang; Ge, Maofa; Li, Jiangjun; Wang, Dong

    2014-01-01

    The refractive index (RI) is the fundamental characteristic that affects the optical properties of aerosols, which could be some of the most important factors influencing direct radiative forcing. The secondary organic aerosols (SOAs) generated by the photooxidation of benzene, toluene, ethylbenzene and m-xylene (BTEX) under low-NOx and high-NOx conditions are explored in this study. The particles generated in our experiments are considered to be spherical, based on atomic force microscopy (AFM) images, and nonabsorbent at a wavelength of 532 nm, as determined by ultraviolet-visible light (UV-Vis) spectroscopy. The retrieved RIs at 532 nm for the SOAs range from 1.38–1.59, depending on several factors, such as different precursors and NOx levels. The RIs of the SOAs are altered differently as the NOx concentration increases as follows: the RIs of the SOAs derived from benzene and toluene increase, whereas those of the SOAs derived from ethylbenzene and m-xylene decrease. Finally, by comparing the experimental data with the model values, we demonstrate that the models likely overestimate the RI values of the SOA particles to a certain extent, which in turn overestimates the global direct radiative forcing of the organic particles. PMID:24815734

  2. SITHON: A Wireless Network of in Situ Optical Cameras Applied to the Early Detection-Notification-Monitoring of Forest Fires

    PubMed Central

    Tsiourlis, Georgios; Andreadakis, Stamatis; Konstantinidis, Pavlos

    2009-01-01

    The SITHON system, a fully wireless optical imaging system, integrating a network of in-situ optical cameras linking to a multi-layer GIS database operated by Control Operating Centres, has been developed in response to the need for early detection, notification and monitoring of forest fires. This article presents in detail the architecture and the components of SITHON, and demonstrates the first encouraging results of an experimental test with small controlled fires over Sithonia Peninsula in Northern Greece. The system has already been scheduled to be installed in some fire prone areas of Greece. PMID:22408536

  3. Modified thermal-optical analysis using spectral absorption selectivity to distinguish black carbon from pyrolized organic carbon

    SciTech Connect

    Hadley, Odelle; Hadley, O.L.; Corrigan, C.E.; Kirchstetter, T.W.

    2008-04-14

    Black carbon (BC), a main component of combustion-generated soot, is a strong absorber of sunlight and contributes to climate change. Measurement methods for BC are uncertain, however. This study presents a method for analyzing the BC mass loading on a quartz fiber filter using a modified thermal-optical analysis method, wherein light transmitted through the sample is measured over a spectral region instead of at a single wavelength as the sample is heated. Evolution of the spectral light transmission signal depends on the relative amounts of light-absorbing BC and char, the latter of which forms when organic carbon in the sample pyrolyzes during heating. Absorption selectivities of BC and char are found to be distinct and are used to apportion the amount of light attenuated by each component in the sample. Light attenuation is converted to mass concentration based on derived mass attenuation efficiencies (MAE) of BC and char. The fraction of attenuation due to each component are scaled by their individual MAE values and added together as the total mass of light absorbing carbon (LAC). An iterative algorithm is used to find the MAE values for both BC and char that provide the best fit to the carbon mass remaining on the filter (derived from direct measurements of thermally evolved CO{sub 2}) at temperatures higher than 480 C. This method was applied to measure the BC concentration in precipitation samples collected from coastal and mountain sites in Northern California. The uncertainty in measured BC concentration of samples that contained a high concentration of organics susceptible to char ranged from 12 to 100 percent, depending on the mass loading of BC on the filter. The lower detection limit for this method was approximately 0.35 {micro}g BC and uncertainty approached 20 percent for BC mass loading greater than 1.0 {micro}g BC.

  4. Ten new predicted covalent organic frameworks with strong optical response in the visible and near infrared

    NASA Astrophysics Data System (ADS)

    Yang, Li-Ming; Dornfeld, Matthew; Hui, Pik-Mai; Frauenheim, Thomas; Ganz, Eric

    2015-06-01

    We use density functional theory to predict and evaluate 10 novel covalent organic frameworks (COFs), labeled (X4Y)(BDC)3, (X = C/Si; Y = C, Si, Ge, Sn, and Pb), with topology based on metal organic framework isoreticular metal-organic framework (IRMOF-1), but with new elements substituted for the corner atoms. We show that these new materials are stable structures using frequency calculations. For two structures, (C4C and Si4C) molecular dynamics simulations were performed to demonstrate stability of the systems up to 600 K for 10 ps. This demonstrates the remarkable stability of these systems, some of which may be experimentally accessible. For the C4C material, we also explored the stability of isolated corners and linkers and vacuum and started to build the structure from these pieces. We discuss the equilibrium lattice parameters, formation enthalpies, electronic structures, chemical bonding, and mechanical and optical properties. The predicted bulk moduli of these COFs range from 18.9 to 23.9 GPa, larger than that of IRMOF-1 (ca. 15.4 GPa), and larger than many existing 3D COF materials. The band gaps range from 1.5 to 2.1 eV, corresponding to 600-830 nm wavelength (orange through near infrared). The negative values of the formation enthalpy suggest that they are stable and should be experimentally accessible under suitable conditions. Seven materials distort the crystal structure to a lower space group symmetry Fm-3, while three materials maintain the original Fm-3m space group symmetry. All of the new materials are highly luminescent. We hope that this work will inspire efforts for experimental synthesis of these new materials.

  5. Ten new predicted covalent organic frameworks with strong optical response in the visible and near infrared.

    PubMed

    Yang, Li-Ming; Dornfeld, Matthew; Hui, Pik-Mai; Frauenheim, Thomas; Ganz, Eric

    2015-06-28

    We use density functional theory to predict and evaluate 10 novel covalent organic frameworks (COFs), labeled (X4Y)(BDC)3, (X = C/Si; Y = C, Si, Ge, Sn, and Pb), with topology based on metal organic framework isoreticular metal-organic framework (IRMOF-1), but with new elements substituted for the corner atoms. We show that these new materials are stable structures using frequency calculations. For two structures, (C4C and Si4C) molecular dynamics simulations were performed to demonstrate stability of the systems up to 600 K for 10 ps. This demonstrates the remarkable stability of these systems, some of which may be experimentally accessible. For the C4C material, we also explored the stability of isolated corners and linkers and vacuum and started to build the structure from these pieces. We discuss the equilibrium lattice parameters, formation enthalpies, electronic structures, chemical bonding, and mechanical and optical properties. The predicted bulk moduli of these COFs range from 18.9 to 23.9 GPa, larger than that of IRMOF-1 (ca. 15.4 GPa), and larger than many existing 3D COF materials. The band gaps range from 1.5 to 2.1 eV, corresponding to 600-830 nm wavelength (orange through near infrared). The negative values of the formation enthalpy suggest that they are stable and should be experimentally accessible under suitable conditions. Seven materials distort the crystal structure to a lower space group symmetry Fm-3, while three materials maintain the original Fm-3m space group symmetry. All of the new materials are highly luminescent. We hope that this work will inspire efforts for experimental synthesis of these new materials.

  6. Ten new predicted covalent organic frameworks with strong optical response in the visible and near infrared

    SciTech Connect

    Yang, Li-Ming E-mail: ganzx001@umn.edu; Frauenheim, Thomas; Dornfeld, Matthew; Hui, Pik-Mai; Ganz, Eric E-mail: ganzx001@umn.edu

    2015-06-28

    We use density functional theory to predict and evaluate 10 novel covalent organic frameworks (COFs), labeled (X{sub 4}Y)(BDC){sub 3}, (X = C/Si; Y = C, Si, Ge, Sn, and Pb), with topology based on metal organic framework isoreticular metal-organic framework (IRMOF-1), but with new elements substituted for the corner atoms. We show that these new materials are stable structures using frequency calculations. For two structures, (C{sub 4}C and Si{sub 4}C) molecular dynamics simulations were performed to demonstrate stability of the systems up to 600 K for 10 ps. This demonstrates the remarkable stability of these systems, some of which may be experimentally accessible. For the C{sub 4}C material, we also explored the stability of isolated corners and linkers and vacuum and started to build the structure from these pieces. We discuss the equilibrium lattice parameters, formation enthalpies, electronic structures, chemical bonding, and mechanical and optical properties. The predicted bulk moduli of these COFs range from 18.9 to 23.9 GPa, larger than that of IRMOF-1 (ca. 15.4 GPa), and larger than many existing 3D COF materials. The band gaps range from 1.5 to 2.1 eV, corresponding to 600–830 nm wavelength (orange through near infrared). The negative values of the formation enthalpy suggest that they are stable and should be experimentally accessible under suitable conditions. Seven materials distort the crystal structure to a lower space group symmetry Fm-3, while three materials maintain the original Fm-3m space group symmetry. All of the new materials are highly luminescent. We hope that this work will inspire efforts for experimental synthesis of these new materials.

  7. Nonlinear Optical Properties of Organic and Polymeric Thin Film Materials of Potential for Microgravity Processing Studies

    NASA Technical Reports Server (NTRS)

    Abdeldayem, Hossin; Frazier, Donald O.; Paley, Mark S.; Penn, Benjamin; Witherow, William K.; Bank, Curtis; Shields, Angela; Hicks, Rosline; Ashley, Paul R.

    1996-01-01

    In this paper, we will take a closer look at the state of the art of polydiacetylene, and metal-free phthalocyanine films, in view of the microgravity impact on their optical properties, their nonlinear optical properties and their potential advantages for integrated optics. These materials have many attractive features with regard to their use in integrated optical circuits and optical switching. Thin films of these materials processed in microgravity environment show enhanced optical quality and better molecular alignment than those processed in unit gravity. Our studies of these materials indicate that microgravity can play a major role in integrated optics technology. Polydiacetylene films are produced by UV irradiation of monomer solution through an optical window. This novel technique of forming polydiacetylene thin films has been modified for constructing sophisticated micro-structure integrated optical patterns using a pre-programmed UV-Laser beam. Wave guiding through these thin films by the prism coupler technique has been demonstrated. The third order nonlinear parameters of these films have been evaluated. Metal-free phthalocyanine films of good optical quality are processed in our laboratories by vapor deposition technique. Initial studies on these films indicate that they have excellent chemical, laser, and environmental stability. They have large nonlinear optical parameters and show intrinsic optical bistability. This bistability is essential for optical logic gates and optical switching applications. Waveguiding and device making investigations of these materials are underway.

  8. Significant Lowering Optical Loss of Electrodes via using Conjugated Polyelectrolytes Interlayer for Organic Laser in Electrically Driven Device Configuration

    PubMed Central

    Yi, Jianpeng; Niu, Qiaoli; Xu, Weidong; Hao, Lin; Yang, Lei; Chi, Lang; Fang, Yueting; Huang, Jinjin; Xia, Ruidong

    2016-01-01

    One of the challenges toward electrically driven organic lasers is the huge optical loss associated with the contact of electrodes and organic gain medium in device. We demonstrated a significant reduction of the optical loss by using our newly developed conjugated polyelectrolytes (CPE) PPFN+Br− as interlayer between gain medium and electrode. The optically pumped amplified spontaneous emission (ASE) was observed at very low threshold for PFO as optical gain medium and up to 37 nm thick CPE as interlayer in device configuration, c.f., a 5.7-fold ASE threshold reduction from pump energy 150 μJ/cm2 for ITO/PFO to 26.3 μJ/cm2 for ITO/PPFN+Br−/PFO. Furthermore, ASE narrowing displayed at pump energy up to 61.8 μJ/cm2 for device ITO/PEDOT:PSS/PFO/PPFN+Br−/Ag, while no ASE was observed for the reference devices without CPE interlayer at pump energy up to 240 μJ/cm2. The optically pumped lasing operation has also been achieved at threshold up to 45 μJ/cm2 for one-dimensional distributed feedback laser fabricated on ITO etched grating in devices with CPE interlayer, demonstrating a promising device configuration for addressing the challenge of electrically driven organic lasers. PMID:27165729

  9. Significant Lowering Optical Loss of Electrodes via using Conjugated Polyelectrolytes Interlayer for Organic Laser in Electrically Driven Device Configuration

    NASA Astrophysics Data System (ADS)

    Yi, Jianpeng; Niu, Qiaoli; Xu, Weidong; Hao, Lin; Yang, Lei; Chi, Lang; Fang, Yueting; Huang, Jinjin; Xia, Ruidong

    2016-05-01

    One of the challenges toward electrically driven organic lasers is the huge optical loss associated with the contact of electrodes and organic gain medium in device. We demonstrated a significant reduction of the optical loss by using our newly developed conjugated polyelectrolytes (CPE) PPFN+Br- as interlayer between gain medium and electrode. The optically pumped amplified spontaneous emission (ASE) was observed at very low threshold for PFO as optical gain medium and up to 37 nm thick CPE as interlayer in device configuration, c.f., a 5.7-fold ASE threshold reduction from pump energy 150 μJ/cm2 for ITO/PFO to 26.3 μJ/cm2 for ITO/PPFN+Br-/PFO. Furthermore, ASE narrowing displayed at pump energy up to 61.8 μJ/cm2 for device ITO/PEDOT:PSS/PFO/PPFN+Br-/Ag, while no ASE was observed for the reference devices without CPE interlayer at pump energy up to 240 μJ/cm2. The optically pumped lasing operation has also been achieved at threshold up to 45 μJ/cm2 for one-dimensional distributed feedback laser fabricated on ITO etched grating in devices with CPE interlayer, demonstrating a promising device configuration for addressing the challenge of electrically driven organic lasers.

  10. Retrieval of Electronic Spectra of Charge Carriers in Organic Field-Effect Transistors from Charge Modulation Reflectance Spectra Distorted by Optical Interference

    NASA Astrophysics Data System (ADS)

    Miyata, Kiyoshi; Ishino, Yuta; Watanabe, Kazuya; Miwa, Kazumoto; Uemura, Takafumi; Takeya, Jun; Matsumoto, Yoshiyasu

    2013-06-01

    Charge modulation (CM) spectroscopy is useful for detecting and characterizing the electronic structure of charge carriers accumulated in organic field-effect transistors (OFETs). However, CM spectra are distorted by optical interference due to multiple reflections in OFETs particularly when reflection configurations are used. In this study, we demonstrated a method for retrieving the spectra of complex refractive indices of carriers from the distorted CM spectra by using a 4×4 matrix algorithm with general transition matrices. We tested this method by applying it to the CM spectra of a rubrene single-crystal FET measured at several incident angles of light. In spite of the strong distortion of the CM spectra, we could retrieve the spectrum of the imaginary part of refractive indices, which is similar to that observed in the transmission configuration. This method extends the applicability of CM spectroscopy to OFETs with opaque electrodes, where transmission configurations cannot possibly be applied.

  11. Penetration studies of topically applied substances: Optical determination of the amount of stratum corneum removed by tape stripping.

    PubMed

    Lademann, J; Ilgevicius, A; Zurbau, O; Liess, H D; Schanzer, S; Weigmann, H J; Antoniou, C; Pelchrzim, R V; Sterry, W

    2006-01-01

    Tape stripping is a standard measuring method for the investigation of the dermatopharmacokinetics of topically applied substances using adhesive films. These tape strips are successively applied and removed from the skin after application and penetration of topically applied substances. Thus, layers of corneocytes and some amount of topical applied substances are removed. The amount of substances and the amount of stratum corneum removed with a single tape strip has to be determined for the calculation of the penetration profile. The topically applied substances removed from the skin can be determined by classical analytical methods like high-pressure liquid chromatography, mass spectroscopy, and spectroscopic measurements. The amount of corneocytes on the tape strips can be easily detected by their pseudoabsorption. In the present paper, an easy and cheap corneocyte density analyzer is presented that is based on a slide projector. Comparing the results of the measurements obtained by the corneocyte density analyzer and by uv-visible spectrometry, identical results were obtained.

  12. Evaluating Corneal Collagen Organization Using High Resolution Non Linear Optical (NLO) Macroscopy*

    PubMed Central

    Jester, James V.; Winkler, Moritz; Jester, Bryan E.; Nien, Chyong; Chai, Dongyul; Brown, Donald J.

    2010-01-01

    Purpose Recent developments in non-linear optical (NLO) imaging using femtosecond lasers provides a non-invasive method for detecting collagen fibers by imaging second harmonic generated (SHG) signals. However, this technique is limited by the small field of view (FoV) necessary to generate SHG signals. The purpose of this report is to review our efforts to greatly extend the FoV in order to assess the entire collagen structure using high resolution macroscopic (HRMac) imaging. Methods Intact human eyes were fixed under pressure and the whole cornea (13 mm diameter) excised and embedded in low melting point agar for vibratome sectioning (200–300 μm). Sections were then optically scanned using a Zeiss LSM 510 Meta and Chameleon femtosecond laser to generate SHG images. For each vibratome section, an overlapping series of 3-D data sets (466 × 466 × 150 μm) were taken covering the entire tissue (15 mm × 6 mm area) using a motorized, mechanical stage. The 3-D data sets were then concatenated to generate an NLO based tomograph. Results HRMac of the cornea yielded large macroscopic (80 Meg Pixels per plane), 3-dimensional tomographs with high resolution (0.81 μm later, 2.0 μm axial) in which individual collagen fibers (stromal lamellae) could be traced, segmented and extracted. 3-D reconstructions suggested that the anterior cornea is comprised of highly intertwined lamellae that insert into the anterior limiting lamina (Bowman’s Layer). Conclusion We conclude that HRMac using NLO based tomography provides a powerful new tool to assess collagen structural organization within the cornea. PMID:20724856

  13. 12 CFR 159.3 - What are the characteristics of, and what requirements apply to, subordinate organizations of...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ...-to-one-borrower (LTOB) regulation (12 CFR part 32) apply? (1) The LTOB regulation does not apply to... savings associations (HOLA section 5(c) and part 160 of this chapter) apply? (1) Your assets and those...

  14. 12 CFR 159.3 - What are the characteristics of, and what requirements apply to, subordinate organizations of...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ...-to-one-borrower (LTOB) regulation (12 CFR part 32) apply? (1) The LTOB regulation does not apply to... savings associations (HOLA section 5(c) and part 160 of this chapter) apply? (1) Your assets and those...

  15. Methanol selective fibre-optic gas sensor with a nanoporous thin film of organic-inorganic hybrid multilayers

    NASA Astrophysics Data System (ADS)

    Wang, T.; Okuda, H.; Lee, S.-W.

    2015-07-01

    The development of an evanescent wave optical fibre (EWOF) sensor modified with an organic-inorganic hybrid nanoporous thin film for alcohol vapor detection was demonstrated. The optical fibre with a core diameter of 200 μm was bent into U-shape probe optic fibre to enhance the penetation depth of light transferred into the evanescent filed. The bended region of the fibre was modified with a multilayered thin film of poly(allyamine hydrochloride) and silica nanoparticels, (PAH/SiO2)n, by a layer-by-layer (LbL) film deposition technique, followed by infusion of tetrakis(4- sulfophenyl)porphine, TPPS. The mesoporous film structure showed high sensitivity and selectivity to methanol by the aid of the TPPS infused inside the film. The optical sensor response was reversible and reproducible over many times of exposures to analytes, which was caused by the change in refractive index (RI) of the film.

  16. Learning predictive models that use pattern discovery--a bootstrap evaluative approach applied in organ functioning sequences.

    PubMed

    Toma, Tudor; Bosman, Robert-Jan; Siebes, Arno; Peek, Niels; Abu-Hanna, Ameen

    2010-08-01

    An important problem in the Intensive Care is how to predict on a given day of stay the eventual hospital mortality for a specific patient. A recent approach to solve this problem suggested the use of frequent temporal sequences (FTSs) as predictors. Methods following this approach were evaluated in the past by inducing a model from a training set and validating the prognostic performance on an independent test set. Although this evaluative approach addresses the validity of the specific models induced in an experiment, it falls short of evaluating the inductive method itself. To achieve this, one must account for the inherent sources of variation in the experimental design. The main aim of this work is to demonstrate a procedure based on bootstrapping, specifically the .632 bootstrap procedure, for evaluating inductive methods that discover patterns, such as FTSs. A second aim is to apply this approach to find out whether a recently suggested inductive method that discovers FTSs of organ functioning status is superior over a traditional method that does not use temporal sequences when compared on each successive day of stay at the Intensive Care Unit. The use of bootstrapping with logistic regression using pre-specified covariates is known in the statistical literature. Using inductive methods of prognostic models based on temporal sequence discovery within the bootstrap procedure is however novel at least in predictive models in the Intensive Care. Our results of applying the bootstrap-based evaluative procedure demonstrate the superiority of the FTS-based inductive method over the traditional method in terms of discrimination as well as accuracy. In addition we illustrate the insights gained by the analyst into the discovered FTSs from the bootstrap samples.

  17. Organic Materials for Electro-Optic and Optoelectronic Applications: Understanding Structure -- Property Relationships

    NASA Astrophysics Data System (ADS)

    Kosilkin, Ilya V.

    Organic materials are promising candidates for application to electro-optics (EO) due to such advantages as tunable properties, ease of processability and the possibility of chip-scale integration. To achieve EO activity on a bulk level, noncentrosymmetric alignment of chromophores is required. However, modern chromophores with high first-order molecular hyperpolarizability have large ground state dipole moments that oppose acentric order, diminishing EO performance. To address this, a better understanding of the relationship between molecular structure and bulk EO activity is required. In Chapter 2, the effects of functionalization of the benchmark chromophore YLD-124 on poling efficiency were studied. Substituents with different electronic nature and different sizes at the middle six-membered ring were explored. Attachment of a t-butylphenoxy group resulted in a 40% increase of the poling efficiency r33/Ep as well as significantly enhanced photostability. Unexpected optical properties of the functionalized chromophores in media with different polarities are explained in terms of electronic effects and aggregation. In Chapter 3, the synthesis of two chromophores with oblate shape is reported based on computational predictions that oblate spheroids with dipole moments formed short range linear stacks. These chromophores are potential candidates for application to a new type of nanophotonic device in which only several molecular layers of EO active material are required. An alternative approach for creating bulk acentricity upon crystallization is discussed in Chapter 4. A functionalization of two chromophores with acentric structure was performed in order to reduce the melting temperature of the parent materials. It was found that such a molecular arrangement is sensitive to the nature of the functionalization of the parent chromophores. Finally, the performance of novel polymerizable ionic liquids (PIL) as electrolytes for optoelectronic applications in polymeric

  18. Tuning The Optical, Charge Injection, and Charge Transport Properties of Organic Electronic Devices

    NASA Astrophysics Data System (ADS)

    Zalar, Peter

    Since the early 1900's, synthetic insulating polymers (plastics) have slowly taken over the role that traditional materials like wood or metal have had as basic components for construction, manufactured goods, and parts. Plastics allow for high throughput, low temperature processing, and control of bulk properties through molecular modifications. In the same way, pi-conjugated organic molecules are emerging as a possible substitute for inorganic materials due to their electronic properties. The semiconductive nature of pi-conjugated materials make them an attractive candidate to replace inorganic materials, primarily due to their promise for low cost and large-scale production of basic semiconducting devices such as light-emitting diodes, solar cells, and field-effect transistors. Before organic semiconductors can be realized as a commercial product, several hurdles must be cleared. The purpose of this dissertation is to address three distinct properties that dominate the functionality of devices harnessing these materials: (1) optical properties, (2) charge injection, and (3) charge transport. First, it is shown that the electron injection barrier in the emissive layer of polymer light-emitting diodes can be significantly reduced by processing of novel conjugated oligoelectrolytes or deoxyribonucleic acid atop the emissive layer. Next, the charge transport properties of several polymers could be modified by processing them from solvents containing small amounts of additives or by using regioregular and enantiopure chemical structures. It is then demonstrated that the optical and electronic properties of Lewis basic polymer structures can be readily modified by interactions with strongly electron-withdrawing Lewis acids. Through red-shifted absorption, photoluminescence, and electroluminescence, a single pi-conjugated backbone can be polychromatic. In addition, interaction with Lewis acids can remarkably p-dope the hole transport of the parent polymer, leading to a

  19. Turbulence statistics applied to calculate expected turbulence-induced scintillation effects on electro-optical systems in different climatic regions

    NASA Astrophysics Data System (ADS)

    Weiss-Wrana, Karin R.

    2005-08-01

    The refractive-index structure parameter Cn2 is the parameter most commonly used to describe the optically active turbulence. In the past, FGAN-FOM carried out long-term experiments in moderate climate (Central Europe, Germany), arid (summer), and semiarid (winter) climate (Middle East, Israel). Since Cn2 usually changes as a function of time of day and of season its influence on electro-optical systems should be expressed in a statistical way. We composed a statistical data base of Cn2 values. The cumulative frequency of occurrence was calculated for a time interval of two hours around noon (time of strongest turbulence), at night, and around sunrise (time of weakest turbulence) for an arbitrarily selected period of one month in summer and in winter. In October 2004 we extended our long-term turbulence experiments to subarctic climate (North Europe, Norway). First results of our turbulence measurement over snow-covered terrain indicate Cn2 values which are similar or even higher than measured values in Central European winter. The statistical data base was used to calculate the expected turbulence-induced aperture-averaged scintillation index for free-space optical systems (FSO system) in different climates. The calculations were performed for commercially available FSO systems with wavelength of 785 nm and 1.55 µm respectively and with aperture diameters of the receiver of 60 mm and 150 mm for horizontal path at two heights, 2.3 m and 10 m above ground.

  20. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: organic carbon

    NASA Astrophysics Data System (ADS)

    Dillner, A. M.; Takahama, S.

    2015-03-01

    Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, organic carbon is measured from a quartz fiber filter that has been exposed to a volume of ambient air and analyzed using thermal methods such as thermal-optical reflectance (TOR). Here, methods are presented that show the feasibility of using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters to accurately predict TOR OC. This work marks an initial step in proposing a method that can reduce the operating costs of large air quality monitoring networks with an inexpensive, non-destructive analysis technique using routinely collected PTFE filter samples which, in addition to OC concentrations, can concurrently provide information regarding the composition of organic aerosol. This feasibility study suggests that the minimum detection limit and errors (or uncertainty) of FT-IR predictions are on par with TOR OC such that evaluation of long-term trends and epidemiological studies would not be significantly impacted. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least-squares regression is used to calibrate sample FT-IR absorbance spectra to TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date. The calibration produces precise and accurate TOR OC predictions of the test set samples by FT-IR as indicated by high coefficient of variation (R2; 0.96), low bias (0.02 μg m-3, the nominal IMPROVE sample volume is 32.8 m3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision to collocated TOR measurements. FT-IR spectra are also

  1. Label-free optical lymphangiography: development of an automatic segmentation method applied to optical coherence tomography to visualize lymphatic vessels using Hessian filters.

    PubMed

    Yousefi, Siavash; Qin, Jia; Zhi, Zhongwei; Wang, Ruikang K

    2013-08-01

    Lymphatic vessels are a part of the circulatory system that collect plasma and other substances that have leaked from the capillaries into interstitial fluid (lymph) and transport lymph back to the circulatory system. Since lymph is transparent, lymphatic vessels appear as dark hallow vessel-like regions in optical coherence tomography (OCT) cross sectional images. We propose an automatic method to segment lymphatic vessel lumen from OCT structural cross sections using eigenvalues of Hessian filters. Compared to the existing method based on intensity threshold, Hessian filters are more selective on vessel shape and less sensitive to intensity variations and noise. Using this segmentation technique along with optical micro-angiography allows label-free noninvasive simultaneous visualization of blood and lymphatic vessels in vivo. Lymphatic vessels play an important role in cancer, immune system response, inflammatory disease, wound healing and tissue regeneration. Development of imaging techniques and visualization tools for lymphatic vessels is valuable in understanding the mechanisms and studying therapeutic methods in related disease and tissue response.

  2. Label-free optical lymphangiography: development of an automatic segmentation method applied to optical coherence tomography to visualize lymphatic vessels using Hessian filters

    NASA Astrophysics Data System (ADS)

    Yousefi, Siavash; Qin, Jia; Zhi, Zhongwei; Wang, Ruikang K.

    2013-08-01

    Lymphatic vessels are a part of the circulatory system that collect plasma and other substances that have leaked from the capillaries into interstitial fluid (lymph) and transport lymph back to the circulatory system. Since lymph is transparent, lymphatic vessels appear as dark hallow vessel-like regions in optical coherence tomography (OCT) cross sectional images. We propose an automatic method to segment lymphatic vessel lumen from OCT structural cross sections using eigenvalues of Hessian filters. Compared to the existing method based on intensity threshold, Hessian filters are more selective on vessel shape and less sensitive to intensity variations and noise. Using this segmentation technique along with optical micro-angiography allows label-free noninvasive simultaneous visualization of blood and lymphatic vessels in vivo. Lymphatic vessels play an important role in cancer, immune system response, inflammatory disease, wound healing and tissue regeneration. Development of imaging techniques and visualization tools for lymphatic vessels is valuable in understanding the mechanisms and studying therapeutic methods in related disease and tissue response.

  3. Label-free optical lymphangiography: development of an automatic segmentation method applied to optical coherence tomography to visualize lymphatic vessels using Hessian filters.

    PubMed

    Yousefi, Siavash; Qin, Jia; Zhi, Zhongwei; Wang, Ruikang K

    2013-08-01

    Lymphatic vessels are a part of the circulatory system that collect plasma and other substances that have leaked from the capillaries into interstitial fluid (lymph) and transport lymph back to the circulatory system. Since lymph is transparent, lymphatic vessels appear as dark hallow vessel-like regions in optical coherence tomography (OCT) cross sectional images. We propose an automatic method to segment lymphatic vessel lumen from OCT structural cross sections using eigenvalues of Hessian filters. Compared to the existing method based on intensity threshold, Hessian filters are more selective on vessel shape and less sensitive to intensity variations and noise. Using this segmentation technique along with optical micro-angiography allows label-free noninvasive simultaneous visualization of blood and lymphatic vessels in vivo. Lymphatic vessels play an important role in cancer, immune system response, inflammatory disease, wound healing and tissue regeneration. Development of imaging techniques and visualization tools for lymphatic vessels is valuable in understanding the mechanisms and studying therapeutic methods in related disease and tissue response. PMID:23922124

  4. Nanoscale Spatial Organization of Prokaryotic Cells Studied by Super-Resolution Optical Microscopy

    NASA Astrophysics Data System (ADS)

    McEvoy, Andrea Lynn

    All cells spatially organize their interiors, and this arrangement is necessary for cell viability. Until recently, it was believed that only eukaryotic cells spatially segregate their components. However, it is becoming increasingly clear that bacteria also assemble their proteins into complex patterns. In eukaryotic cells, spatial organization arises from membrane bound organelles as well as motor transport proteins which can move cargos within the cell. To date, there are no known motor transport proteins in bacteria and most microbes lack membrane bound organelles, so it remains a mystery how bacterial spatial organization emerges. In hind-sight it is not surprising that bacteria also exhibit complex spatial organization considering much of what we have learned about the basic processes that take place in all cells, such as transcription and translation was first discovered in prokaryotic cells. Perhaps the fundamental principles that govern spatial organization in prokaryotic cells may be applicable in eukaryotic cells as well. In addition, bacteria are attractive model organism for spatial organization studies because they are genetically tractable, grow quickly and much biochemical and structural data is known about them. A powerful tool for observing spatial organization in cells is the fluorescence microscope. By specifically tagging a protein of interest with a fluorescent probe, it is possible to examine how proteins organize and dynamically assemble inside cells. A significant disadvantage of this technology is its spatial resolution (approximately 250 nm laterally and 500 nm axially). This limitation on resolution causes closely spaced proteins to look blurred making it difficult to observe the fine structure within the complexes. This resolution limit is especially problematic within small cells such as bacteria. With the recent invention of new optical microscopies, we now can surpass the existing limits of fluorescence imaging. In some cases, we can

  5. Performance Analysis of Extracted Rule-Base Multivariable Type-2 Self-Organizing Fuzzy Logic Controller Applied to Anesthesia

    PubMed Central

    Fan, Shou-Zen; Shieh, Jiann-Shing

    2014-01-01

    We compare type-1 and type-2 self-organizing fuzzy logic controller (SOFLC) using expert initialized and pretrained extracted rule-bases applied to automatic control of anaesthesia during surgery. We perform experimental simulations using a nonfixed patient model and signal noise to account for environmental and patient drug interaction uncertainties. The simulations evaluate the performance of the SOFLCs in their ability to control anesthetic delivery rates for maintaining desired physiological set points for muscle relaxation and blood pressure during a multistage surgical procedure. The performances of the SOFLCs are evaluated by measuring the steady state errors and control stabilities which indicate the accuracy and precision of control task. Two sets of comparisons based on using expert derived and extracted rule-bases are implemented as Wilcoxon signed-rank tests. Results indicate that type-2 SOFLCs outperform type-1 SOFLC while handling the various sources of uncertainties. SOFLCs using the extracted rules are also shown to outperform those using expert derived rules in terms of improved control stability. PMID:25587533

  6. Thermodynamics and dynamics of atomic self-organization in an optical cavity

    NASA Astrophysics Data System (ADS)

    Schütz, Stefan; Jäger, Simon B.; Morigi, Giovanna

    2015-12-01

    Pattern formation of atoms in high-finesse optical resonators results from the mechanical forces of light associated with superradiant scattering into the cavity mode. It occurs when the laser intensity exceeds a threshold value such that the pumping processes counteract the losses. We consider atoms driven by a laser and coupling with a mode of a standing-wave cavity and describe their dynamics with a Fokker-Planck equation, in which the atomic motion is semiclassical but the cavity field is a full quantum variable. The asymptotic state of the atoms is a thermal state, whose temperature is solely controlled by the detuning between the laser and the cavity frequency and by the cavity loss rate. From this result we derive the free energy and show that in the thermodynamic limit self-organization is a second-order phase transition. The order parameter is the field inside the resonator to which one can associate a magnetization in analogy to ferromagnetism, the control field is the laser intensity, but the steady state is intrinsically out of equilibrium. In the symmetry-broken phase, quantum noise induces jumps of the spatial density between two ordered patterns: We characterize the statistical properties of this temporal behavior at steady state and show that the thermodynamic properties of the system can be extracted by detecting the light at the cavity output. The results of our analysis are in full agreement with previous studies; we extend them by deriving a self-consistent theory which is valid also when the cavity field is in the shot-noise limit and elucidate the nature of the self-organization transition.

  7. Catalytically solid-phase self-organization of nanoporous SnS with optical depolarizability

    NASA Astrophysics Data System (ADS)

    Cheng, Chih-Hsien; Chi, Yu-Chieh; Wu, Chung-Lun; Lin, Chun-Jung; Tsai, Ling-Hsuan; Chang, Jung-Hung; Chen, Mu Ku; Shih, Min-Hsiung; Lee, Chao-Kuei; Wu, Chih-I.; Tsai, Din Ping; Lin, Gong-Ru

    2016-02-01

    The catalytic solid-phase synthesis of self-organized nanoporous tin sulfide (SnS) with enhanced absorption, manipulative transmittance and depolarization features is demonstrated. Using an ultralow radio-frequency (RF) sputtering power, the variation of the orientation angle between the anodized aluminum oxide (AAO) membrane and the axis of the sputtered ion beam detunes the catalytically synthesized SnS from nanorod to nanoporous morphology, along the sidewall of the AAO membrane. The ultraslow catalytic sputtering synthesis on the AAO at the RF plasma power of 20 W and the orientation angle of 0° regulates the porosity and integrality of nanoporous SnS, with average pore diameter of 80-150 nm. When transferring from planar to nanoporous structure, the phase composition changes from SnS to SnS2-Sn2S3, and the optical bandgap shrinks from 1.43 to 1.16 eV, due to the preferred crystalline orientation, which also contributes to an ultralow reflectance of <1% at 200-500 nm when both the transmittance and the surface scattering remain at their maxima. The absorption coefficient is enhanced by nearly one order of magnitude with its minimum of >5 × 104 cm-1 at the wavelength between 200 and 700 nm, due to the red-shifting of the absorption spectrum to at least 100 nm. The catalytically self-organized nanoporous SnS causes strong haze and beam divergence of 20°-30° by depolarized nonlinear scattering at the surface, which favors the solar energy conversion with reduced surface reflection and enhanced photon scattering under preserved transmittance.

  8. The influence of voltage applied between the electrodes on optical and morphological properties of the InGaN thin films grown by thermionic vacuum arc.

    PubMed

    Özen, Soner; Şenay, Volkan; Pat, Suat; Korkmaz, Şadan

    2016-01-01

    The aim of this research is to investigate the optical and morphological properties of the InGaN thin films deposited onto amorphous glass substrates in two separate experiments with two different voltages applied between the electrodes, i.e. 500 and 600 V by means of the thermionic vacuum arc technique. This technique is original for thin film deposition and it enables thin film production in a very short period of time. The optical and morphological properties of the films were investigated by using field emission scanning electron microscope, atomic force microscope, spectroscopic ellipsometer, reflectometer, spectrophotometer, and optical tensiometer. Optical properties were also supported by empirical relations. The deposition rates were calculated as 3 and 3.3 nm/sec for 500 and 600 V, respectively. The increase in the voltage also increased the refractive index, grain size, root mean square roughness and surface free energy. According to the results of the wetting experiments, InGaN samples were low-wettable, also known as hydrophobic.

  9. Donor impurity-related linear and nonlinear intraband optical absorption coefficients in quantum ring: effects of applied electric field and hydrostatic pressure.

    PubMed

    Barseghyan, Manuk G; Restrepo, Ricardo L; Mora-Ramos, Miguel E; Kirakosyan, Albert A; Duque, Carlos A

    2012-01-01

    : The linear and nonlinear intraband optical absorption coefficients in GaAs three-dimensional single quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and electric field, applied along the growth direction of the heterostructure, the energies of the ground and first excited states of a donor impurity have been found using the effective mass approximation and a variational method. The energies of these states are examined as functions of the dimensions of the structure, electric field, and hydrostatic pressure. We have also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as a function of incident photon energy for several configurations of the system. It is found that the variation of distinct sizes of the structure leads to either a redshift and/or a blueshift of the resonant peaks of the intraband optical spectrum. In addition, we have found that the application of an electric field leads to a redshift, whereas the influence of hydrostatic pressure leads to a blueshift (in the case of on-ring-center donor impurity position) of the resonant peaks of the intraband optical spectrum. PMID:23021497

  10. [CHROMATIN ORGANIZATION IN CELL CYCLE OF AMOEBA PROTEUS ACCORDING TO OPTICAL TOMOGRAPHY DATA].

    PubMed

    Demin, S Yu; Berdieva, M A; Podlipaeva, Yu I; Yudin, A L; Goodkov, A V

    2015-01-01

    For the first time the nuclear cycle of large freshwater amoeba Amoeba proteus was studied by the method of optical tomography. The nuclei were fixed in situ in the cells of synchronized culture, stained by DAPI and examined by confocal laser scanning microscope. 3D-images of intranuclear chromatin were studied in details at different stages of nuclear cycle. The obtained data, together with literary ones allow represent the dynamics of structural organization of the nucleus in Amoeba proteus cell cycle in a new fashion. It was concluded that in this species the two-stage interphase takes place, as well as mitosis of peculiar type which does not correspond to any known type of mitosis according to classification existing now. It is presumed that in the course of nuclear cycle the chromosomes and/or their fragments are amplified, this presumption being in a good correspondence with the data about nuclear DNA hyperreplication in the cell cycle of A. proteus. As a result of chromosomes amplification their number may vary at different stages of cell cycle, and it allows to explain the contradictory data concerning the exact number of chromosomes in this species. The elimination of extra-DNA occurs mainly at the stage between prophase and prometaphase. We presume the majority of chromosomes, or may be even all of them to be referred to cholocentric type according to their behaviour during the mitosis.

  11. Optical properties of low bandgap copolymer PTB7 for organic photovoltaic applications

    NASA Astrophysics Data System (ADS)

    Huynh, Uyen; Basel, Tek; Xu, Tao; Lu, Luyao; Zheng, Tianyue; Yu, Luping; Vardeny, Valy

    2014-09-01

    We used both cw and transient spectroscopies for studying the optical properties and photoexcitations in the low bandgap copolymer PTB7 that has been used in organic photovoltaic applications (OPV). Surprisingly we observed two primary photoexcitations that are generated within ~150 fs (our time resolution); we identify them as singlet exciton (S1) and triplet-pair (1TT). The singlet exciton has been considered to be the only primary photoexcitation in regular π-conjugated polymers and is related with a transient absorption band that peaks at an energy value close to the exciton binding energy (~0.4 eV in PTB7). The TT pair is a novel photoexcitation species in low band-gap π-conjugated copolymers. It has an absorption band close to that of isolated triplet exciton, and may readily dissociate at the donoracceptor interfaces in the PTB7/fullerene blend. This finding may explain the underlying mechanism for the high obtained power conversion efficiency in OPV devices based on the PTB7 copolymer.

  12. Fermi surface study of organic conductors using a magneto-optical measurement under high magnetic fields

    NASA Astrophysics Data System (ADS)

    Kimata, M.; Ohta, H.; Koyama, K.; Motokawa, M.; Kondo, R.; Kagoshima, S.; Tanaka, H.; Tokumoto, M.; Kobayashi, H.; Kobayashi, A.

    2006-11-01

    Magneto-optical measurements have been performed in organic conductors β''-(BEDT-TTF)2CsCd(SCN)4 and λ-(BETS)2FeCl4. Although the zero magnetic field ground state of β''-(BEDT-TTF)2CsCd(SCN)4is considered as the density wave state, periodic orbit resonances (POR's) attributed to quasi-one-dimensional (Q1D) and quasi-two-dimensional (Q2D) Fermi surfaces (FS's) have been observed above 6 T. The existence of these FS's are predicted by the band calculation based on room temperature lattice parameters. This result may suggest the destruction of the density wave state at 6 T, and the primal metallic state revives in the high field phase above 6 T. In the case of λ-(BETS)2FeCl4, large changes of the transmission intensity of electromagnetic waves around 10 T, which correspond to the insulator-metal transition, have been observed. However, no POR-like resonance has been observed. This may be due to the restriction of the observed frequency-field region.

  13. TOPICAL REVIEW: Magneto-optical studies of low-dimensional organic conductors

    NASA Astrophysics Data System (ADS)

    Ohta, Hitoshi; Kimata, Motoi; Oshima, Yugo

    2009-04-01

    Our periodic orbit resonance (POR) results on quasi-two-dimensional (q2D), highly anisotropic q2D and quasi-one-dimensional (q1D) organic conductors are reviewed together with our rotational cavity magneto-optical measurement system. Higher order POR up to seventh order has been observed in the q2D system (BEDT-TTF)2Br(DIA), and the experimental conditions to observe POR and the cyclotron resonance (CR) are discussed. Highly anisotropic q2D Fermi surface (FS) in β''-(BEDT-TTF)(TCNQ), which was considered to have q1D FS previously, is proposed by our POR measurements, and the possible interpretations of other experimental results of β''-(BEDT-TTF)(TCNQ) are discussed assuming the highly anisotropic q2D FS. Finally, detailed q1D FS of (DMET)2I3, obtained from our POR results, is discussed in connection with the typical q1D system (TMTSF)2ClO4.

  14. Influence of electron transport layer thickness on optical properties of organic light-emitting diodes

    SciTech Connect

    Liu, Guohong; Liu, Yong; Li, Baojun; Zhou, Xiang

    2015-06-07

    We investigate experimentally and theoretically the influence of electron transport layer (ETL) thickness on properties of typical N,N′-diphenyl-N,N′-bis(1-naphthyl)-[1,1′-biphthyl]-4,4′-diamine (NPB)/tris-(8-hydroxyquinoline) aluminum (Alq{sub 3}) heterojunction based organic light-emitting diodes (OLEDs), where the thickness of ETL is varied to adjust the distance between the emitting zone and the metal electrode. The devices showed a maximum current efficiency of 3.8 cd/A when the ETL thickness is around 50 nm corresponding to an emitter-cathode distance of 80 nm, and a second maximum current efficiency of 2.6 cd/A when the ETL thickness is around 210 nm corresponding to an emitter-cathode distance of 240 nm. We adopt a rigorous electromagnetic approach that takes parameters, such as dipole orientation, polarization, light emitting angle, exciton recombination zone, and diffusion length into account to model the optical properties of devices as a function of varying ETL thickness. Our simulation results are accurately consistent with the experimental results with a widely varying thickness of ETL, indicating that the theoretical model may be helpful to design high efficiency OLEDs.

  15. Small optical gap molecules and polymers: using theory to design more efficient materials for organic photovoltaics.

    PubMed

    Risko, Chad; Brédas, Jean-Luc

    2014-01-01

    Recent improvements in the power conversion efficiencies of organic solar cells have been derived through a combination of new materials, processing, and device designs. A key factor has also been quantum-chemical studies that have led to a better understanding not only of the intrinsic electronic and optical properties of the materials but also of the physical processes that take place during the photovoltaic effect. In this chapter we review some recent quantum-chemical investigations of donor-acceptor copolymers, systems that have found wide use as the primary absorbing and hole-transport materials in bulk-heterojunction solar cells. We underline a number of current limitations with regard to available electronic structure methods and in terms of the understanding of the processes involved in solar cell operation. We conclude with a brief outlook that discusses the need to develop multiscale simulation methods that combine quantum-chemical techniques with large-scale classically-based simulations to provide a more complete picture.

  16. Investigation on growth, structural, optical, thermal, dielectric and mechanical properties of organic L-prolinium trichloroacetate single crystals

    SciTech Connect

    Boopathi, K.; Rajesh, P.; Ramasamy, P.

    2012-09-15

    Graphical abstract: L-Prolinium trichloroacetate is an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that L-PTCA crystallizes in trigonal crystal system. The optical band gab is found to be 4.26 eV. Second harmonic conversion efficiency of L-PTCA has been found to be half that of KDP. Highlights: ► It deals with the synthesis, growth and characterization of L-PTCA an organic NLO crystal. ► Wide optical transparency window between 260 nm and 1100 nm. ► Thermal study reveals that the grown crystal is stable up to 127 °C. ► L-PTCA crystal exhibits the second order nonlinear optical properties. -- Abstract: A new organic nonlinear optical material L-prolinium trichloroacetate (L-PTCA) single crystal has been synthesized and grown by slow solvent evaporation technique at room temperature using water as solvent. Single-crystal X-ray diffractometer was utilized to measure unit cell parameters and to confirm lattice parameter. The powder X-ray diffraction pattern of the grown L-PTCA has been indexed. The modes of vibration of different molecular groups present in the sample were identified by the FTIR spectral analysis. The optical transmittance window and the lower cutoff wavelength of the L-PTCA have been identified by UV–vis–NIR studies. Thermal stability of the L-prolinium trichloroacetate was determined by TGA/DTA measurements. Dielectric measurements were carried out at various temperatures at frequency range 10–1 MHz. The mechanical properties of the grown crystals have been analyzed by Vickers microhardness method. The chemical etching studies were carried out on the grown crystals. Its SHG efficiency has been tested by Kurtz powder method.

  17. A novel elevating structure design applied on the motion behavior analysis of micro optical devices by CMOS-MEMS process

    NASA Astrophysics Data System (ADS)

    Tsai, Chien-Chung; Fan, Zhen-Hao; Lin, Pei-Hao

    2006-01-01

    The paper proposed a novel curb structure to elevate the micro optical devices by the driving force of micro array thermal actuator, MATA. The effects of spring structure and curb structure on the maximum displacements and the variation of surface flatness of the elevated micro mirror varied with operation voltage are investigated. The motion behaviors of the elevated micro mirror are stimulated and analyzed to get the maximum displacement and inclined angle of the device. The results demonstrate the wider width, longer pitch and more pitch numbers of spring structure are; the maximum displacement of the elevated micro mirror is larger. Compared the effects of spring structure and curb structure on the maximum displacement of the elevated micro mirror, there are more influence on the variation of maximum displacement due to the varied spring structure than the varied curb structure. On the other hand, the variation of surface flatness of the elevated micro mirror is more significant by the varied pitch number of spring structure and the varied width of curb structure. The maximum displacement and inclined angle of proposed micro optical device are 58.6μm and 17.04°C, respectively.

  18. Langley method applied in study of aerosol optical depth in the Brazilian semiarid region using 500, 670 and 870 nm bands for sun photometer calibration

    NASA Astrophysics Data System (ADS)

    Cerqueira, J. G.; Fernandez, J. H.; Hoelzemann, J. J.; Leme, N. M. P.; Sousa, C. T.

    2014-10-01

    Due to the high costs of commercial monitoring instruments, a portable sun photometer was developed at INPE/CRN laboratories, operating in four bands, with two bands in the visible spectrum and two in near infrared. The instrument calibration process is performed by applying the classical Langley method. Application of the Langley’s methodology requires a site with high optical stability during the measurements, which is usually found in high altitudes. However, far from being an ideal site, Harrison et al. (1994) report success with applying the Langley method to some data for a site in Boulder, Colorado. Recently, Liu et al. (2011) show that low elevation sites, far away from urban and industrial centers can provide a stable optical depth, similar to high altitudes. In this study we investigated the feasibility of applying the methodology in the semiarid region of northeastern Brazil, far away from pollution areas with low altitudes, for sun photometer calibration. We investigated optical depth stability using two periods of measurements in the year during dry season in austral summer. The first one was in December when the native vegetation naturally dries, losing all its leaves and the second one was in September in the middle of the dry season when the vegetation is still with leaves. The data were distributed during four days in December 2012 and four days in September 2013 totaling eleven half days of collections between mornings and afternoons and by means of fitted line to the data V0 values were found. Despite the high correlation between the collected data and the fitted line, the study showed a variation between the values of V0 greater than allowed for sun photometer calibration. The lowest V0 variation reached in this experiment with values lower than 3% for the bands 500, 670 and 870 nm are displayed in tables. The results indicate that the site needs to be better characterized with studies in more favorable periods, soon after the rainy season.

  19. Early and one-year stroke case fatality in Sao Paulo, Brazil: applying the World Health Organization's stroke STEPS.

    PubMed

    Goulart, Alessandra C; Bensenor, Isabela M; Fernandes, Tiotrefis G; Alencar, Airlane P; Fedeli, Ligia M; Lotufo, Paulo A

    2012-11-01

    Case fatality rate is considered a main determinant of stroke mortality trends. We applied the World Health Organization's Stroke STEPS to identify case fatality rates in a community hospital in Brazil. We evaluated all patients with first-ever stroke seeking acute care at the hospital's emergency ward between April 2006 and December 2008 to verify early and late case fatality according to stroke subtype. We used years of formal education as a surrogate for socioeconomic status. Of 430 first-ever stroke events, 365 (84.9%) were ischemic and 65 (15.1%) were intracerebral hemorrhage. After 1 year, we adjudicated 108 deaths (86 ischemic; 22 hemorrhagic). Age-adjusted case fatality rates for ischemic stroke and intracerebral hemorrhage were 6.0% v 19.8% at 10 days, 10.6% v 22.1% at 28 days, 17.6% v 29.1% at 6 months, and 21.0% v 31.5% at 1 year. Illiteracy or no formal education was a predictor of death at 6 months (odds ratio [OR], 4.31; 95% confidence interval [CI] 1.34-13.91) and 1 year (OR, 4.21; 95% CI, 1.45-12.28) in patients with ischemic stroke, as well as at 6 months (OR, 3.19; 95% CI, 1.17-8.70) and 1 year (OR, 3.30; 95% CI, 1.30-8.45) for all stroke patients. Other variables, including previous cardiovascular risk factors and acute medical care, did not change this association to a statistically significant degree. In conclusion, case fatality, particularly up to 6 months, was higher in hemorrhagic stroke, and lack of formal education was associated with increased stroke mortality.

  20. Applying tattoo dye as a third-harmonic generation contrast agent for in vivo optical virtual biopsy of human skin.

    PubMed

    Tsai, Ming-Rung; Lin, Chen-Yu; Liao, Yi-Hua; Sun, Chi-Kuang

    2013-02-01

    Third-harmonic generation (THG) microscopy has been reported to provide intrinsic contrast in elastic fibers, cytoplasmic membrane, nucleus, actin filaments, lipid bodies, hemoglobin, and melanin in human skin. For advanced molecular imaging, exogenous contrast agents are developed for a higher structural or molecular specificity. We demonstrate the potential of the commonly adopted tattoo dye as a THG contrast agent for in vivo optical biopsy of human skin. Spectroscopy and microscopy experiments were performed on cultured cells with tattoo dyes, in tattooed mouse skin, and in tattooed human skin to demonstrate the THG enhancement effect. Compared with other absorbing dyes or nanoparticles used as exogenous THG contrast agents, tattoo dyes are widely adopted in human skin so that future clinical biocompatibility evaluation is relatively achievable. Combined with the demonstrated THG enhancement effect, tattoo dyes show their promise for future clinical imaging applications. PMID:23389681

  1. Biochemical and Physiological Characterization: Development & Apply Optical Methods for Charaterizing Biochemical Protein-Protein Interactions in MR-1

    SciTech Connect

    Weiss, Shimon

    2006-08-30

    The objectives of this report are to: Develop novel site-specific protein labeling chemistries for assaying protein-protein interactions in MR-1; and development of a novel optical acquisition and data analysis method for characterizing protein-protein interactions in MR-1 model systems. Our work on analyzing protein-protein interactions in MR-1 is divided in four areas: (1) expression and labeling of MR-1 proteins; (2) general scheme for site-specific fluorescent labeling of expressed proteins; (3) methodology development for monitoring protein-protein interactions; and (4) study of protein-protein interactions in MR-1. In this final report, we give an account for our advances in all areas.

  2. Sensitive CH4 detection applying quantum cascade laser based optical feedback cavity-enhanced absorption spectroscopy.

    PubMed

    Lang, N; Macherius, U; Wiese, M; Zimmermann, H; Röpcke, J; van Helden, J H

    2016-03-21

    We report on sensitive detection of atmospheric methane employing quantum cascade laser based optical feedback cavity-enhanced absorption spectroscopy (OF-CEAS). An instrument has been built utilizing a continuous-wave distributed feedback quantum cascade laser (cw-QCL) with a V-shaped cavity, a common arrangement that reduces feedback to the laser from non-resonant reflections. The spectrometer has a noise equivalent absorption coefficient of 3.6 × 10-9 cm-1 Hz-1/2 for a spectral scan of CH4 at 7.39 μm. From an Allan-Werle analysis a detection limit of 39 parts per trillion of CH4 at atmospheric pressure within 50 s acquisition time was found.

  3. Applying tattoo dye as a third-harmonic generation contrast agent for in vivo optical virtual biopsy of human skin

    NASA Astrophysics Data System (ADS)

    Tsai, Ming-Rung; Lin, Chen-Yu; Liao, Yi-Hua; Sun, Chi-Kuang

    2013-02-01

    Third-harmonic generation (THG) microscopy has been reported to provide intrinsic contrast in elastic fibers, cytoplasmic membrane, nucleus, actin filaments, lipid bodies, hemoglobin, and melanin in human skin. For advanced molecular imaging, exogenous contrast agents are developed for a higher structural or molecular specificity. We demonstrate the potential of the commonly adopted tattoo dye as a THG contrast agent for in vivo optical biopsy of human skin. Spectroscopy and microscopy experiments were performed on cultured cells with tattoo dyes, in tattooed mouse skin, and in tattooed human skin to demonstrate the THG enhancement effect. Compared with other absorbing dyes or nanoparticles used as exogenous THG contrast agents, tattoo dyes are widely adopted in human skin so that future clinical biocompatibility evaluation is relatively achievable. Combined with the demonstrated THG enhancement effect, tattoo dyes show their promise for future clinical imaging applications.

  4. Fabrication of optical element from unidirectional grown imidazole-imidazolium picrate monohydrate (IIP) organic crystals for nonlinear optical applications

    NASA Astrophysics Data System (ADS)

    Vivek, P.; Murugakoothan, P.

    2014-12-01

    Nonlinear optical bulk single crystal of Imidazole-imidazolium picrate monohydrate (IIP) has been grown by Sankaranarayanan-Ramasamy (SR) method using acetonitrile as solvent. First time we report the bulk growth of IIP crystal by SR method. The transparent IIP single crystal of maximum diameter 21 mm and length 46 mm was obtained by employing SR method. The grown crystal was subjected to high resolution X-ray diffraction, UV-vis-NIR transmittance, refractive index, hardness, dielectric and laser damage threshold studies. The crystalline perfection of the grown crystal was analyzed using HRXRD. Cut off wavelength and optical transmission window of the crystal was assessed by UV-vis-NIR and the refractive index of the crystal was found. The mechanical property of the crystal was estimated by Vicker's hardness test. The dielectric property of the crystal was measured as a function of frequency. The laser damage threshold value was determined. The particle size dependent second harmonic generation efficiency for IIP was evaluated with standard reference material potassium dihydrogen phosphate (KDP) by Kurtz-Perry powder method using Nd:YAG laser, which established the existence of phase matching. The second harmonic generation (SHG) of IIP crystal was investigated by the SHG Maker fringes technique. The mechanism of growth is revealed by carrying out chemical etching using acetonitrile as etchant.

  5. Polarized optical spectroscopy applied to investigate two poly(phenylene-vinylene) polymers with different side chain structures

    NASA Astrophysics Data System (ADS)

    Pâlsson, Lars-Olof; Vaughan, Helen L.; Monkman, Andrew P.

    2006-10-01

    Two related poly(phenylene-vinylene) (PPV) light-emitting polymers have been investigated by means of polarized optical spectroscopy. The purpose of the investigation was to investigate the nature of the interactions in thin films and to examine what impact the difference in side chain structure and molecular weight in poly(2'-methoxy-5-2-ethyl-hexoxy)-1,4-phenylene vinylene (MEH-PPV) and poly(2-(3',7'-dimethyloctyloxy)-5-methoxy-1,4-phenylene-vinylene) (OC1C10-PPV) has on the electronic and optical properties of the two polymers. Aligning the polymers by dispersing them in anisotropic solvents and stretched films shows that the side chains have an impact on the relative orientations of the transition dipole moments. In anisotropic solvents the linear dichroism is larger for MEH-PPV than for the related polymer OC1C10-PPV, while in stretched films the opposite situation prevails. A lower polarization of the luminescence from OC1C10-PPV, relative to MEH-PPV, was also obtained independent of alignment medium used. The data therefore suggest that while mechanical stretching may align the OC1C10-PPV to a greater degree, the emitting species is distinct from the absorbing species. The circular dichroism (CD) spectra of both polymers undergo dramatic changes when the liquid phase and the solid state (film) are compared. The solution CD spectra shows no evidence of interchain interactions; instead the spectra of both systems indicate a helical conformation of the polymers. The CD spectra of films are dramatically different with the strong Cotton effect being observed. This points to the formation of an aggregate in the film, with an associated ground state interaction, an interchain species such as a physical dimer, or a more complex higher aggregate.

  6. Growth and characterization of bis-glycine sodium nitrate (BGSN), a novel semi-organic nonlinear optical crystal

    NASA Astrophysics Data System (ADS)

    Sankar, R.; Ragahvan, C. M.; Mohan Kumar, R.; Jayavel, R.

    2007-11-01

    Single crystals of bis-glycine sodium nitrate (BGSN), a semi-organic nonlinear optical (NLO) material, have been grown by slow cooling method. Good optical quality single crystals with dimensions up to 1.6×1.6×1.0 cm 3 are obtained. Using a single-crystal diffractometer, the morphology of BGSN crystal was identified. Powder X-ray diffraction confirms the crystalline nature of BGSN. The grown crystals were characterized by optical transmission spectrum (UV) and FTIR studies. The NLO property of the crystal was confirmed by Kurtz second harmonic generation (SHG) test, and the output power generated by the crystal was compared with that of KDP. The thermal stability of the crystal was studied by thermo-gravimetric analysis (TGA), differential thermal analysis (DTA) and differential scanning calorimetry (DSC). Micro hardness study was carried out for different planes, and the anisotropy behavior of the crystal was observed.

  7. Photometric flow injection determination of phosphate on a PDMS microchip using an optical detection system assembled with an organic light emitting diode and an organic photodiode.

    PubMed

    Liu, Rong; Ishimatsu, Ryoichi; Yahiro, Masayuki; Adachi, Chihaya; Nakano, Koji; Imato, Toshihiko

    2015-01-01

    A compact photometric detector was constructed from an organic light emitting diode (OLED) based on a europium complex, europium(diben-zoylmethanato)3(bathophenanthroline) (Eu(DBM)3bath), as the light source and an organic photodiode (OPD) fabricated from a hetero-junction of two layers of copper phthalocyanine (CuPc)/fullerene (C60) as the photo-detector on a microchip prepared from poly(dimethylsiloxan) (PDMS) and was applied to the determination of phosphate. The OLED and the OPD were fabricated by a vapor deposition method on an indium tin oxide (ITO) coated glass substrate with the following layered structure; Glass (0.7 mm)/ITO (110 nm)/4,4'-bis[N-(1-naphthyl)-N-phenyl amino]-biphenyl (α-NPD) (30 nm)/4,4'-di(N-carbazolyl)biphenyl (CBP): Eu(3+) (8 wt%, 30 nm)/bathocuproine (BCP) (30 nm)/aluminum tris(8-hydroxyquinoline) (Alq3) (25 nm)/magnesium and silver (MgAg) (100 nm)/Ag (10nm) and Glass (0.7 mm)/ITO (110 nm)/CuPc (35 nm)/C60 (50 nm)/BCP (10 nm)/Ag (50 nm), respectively. The OLED based on the europium complex emitted a sharp light at the wavelength of 612 nm with a full width at half maximum (FWHM) of 8 nm. The performance of the photometric detector assembled was evaluated based on measurements of the absorbance of different concentrations of malachite green (MG) solutions for a batch system with 1cm long path length. The molar absorptive coefficient of the MG solution, calculated from the photocurrent of the OPD, was in good agreement with the value reported in the literature. A microchip with two inlets and one outlet U-shaped channel was prepared by a conventional photolithograph method. The OLED and the OPD were configured so as to face each other through the PDMS microchip in parallel in order to align the light axis of the OLED and the OPD with the flow cell (optical path length of 5mm), which was located at the end of outlet. For the determination of phosphate, an ion-association reaction between MG and a molybdenum-phosphate complex was utilized

  8. Photometric flow injection determination of phosphate on a PDMS microchip using an optical detection system assembled with an organic light emitting diode and an organic photodiode.

    PubMed

    Liu, Rong; Ishimatsu, Ryoichi; Yahiro, Masayuki; Adachi, Chihaya; Nakano, Koji; Imato, Toshihiko

    2015-01-01

    A compact photometric detector was constructed from an organic light emitting diode (OLED) based on a europium complex, europium(diben-zoylmethanato)3(bathophenanthroline) (Eu(DBM)3bath), as the light source and an organic photodiode (OPD) fabricated from a hetero-junction of two layers of copper phthalocyanine (CuPc)/fullerene (C60) as the photo-detector on a microchip prepared from poly(dimethylsiloxan) (PDMS) and was applied to the determination of phosphate. The OLED and the OPD were fabricated by a vapor deposition method on an indium tin oxide (ITO) coated glass substrate with the following layered structure; Glass (0.7 mm)/ITO (110 nm)/4,4'-bis[N-(1-naphthyl)-N-phenyl amino]-biphenyl (α-NPD) (30 nm)/4,4'-di(N-carbazolyl)biphenyl (CBP): Eu(3+) (8 wt%, 30 nm)/bathocuproine (BCP) (30 nm)/aluminum tris(8-hydroxyquinoline) (Alq3) (25 nm)/magnesium and silver (MgAg) (100 nm)/Ag (10nm) and Glass (0.7 mm)/ITO (110 nm)/CuPc (35 nm)/C60 (50 nm)/BCP (10 nm)/Ag (50 nm), respectively. The OLED based on the europium complex emitted a sharp light at the wavelength of 612 nm with a full width at half maximum (FWHM) of 8 nm. The performance of the photometric detector assembled was evaluated based on measurements of the absorbance of different concentrations of malachite green (MG) solutions for a batch system with 1cm long path length. The molar absorptive coefficient of the MG solution, calculated from the photocurrent of the OPD, was in good agreement with the value reported in the literature. A microchip with two inlets and one outlet U-shaped channel was prepared by a conventional photolithograph method. The OLED and the OPD were configured so as to face each other through the PDMS microchip in parallel in order to align the light axis of the OLED and the OPD with the flow cell (optical path length of 5mm), which was located at the end of outlet. For the determination of phosphate, an ion-association reaction between MG and a molybdenum-phosphate complex was utilized

  9. The influence of applied magnetic fields on the optical properties of zero- and one-dimensional CdSe nanocrystals.

    PubMed

    Blumling, Daniel E; McGill, Stephen; Knappenberger, Kenneth L

    2013-10-01

    Shape-dependent exciton relaxation dynamics of CdSe 0-D nanocrystals and 1-D nanorods were studied using low-temperature (4.2 K), time-resolved and intensity-integrated magneto-photoluminscence (MPL) spectroscopy. Analysis of the average MPL rate constants from several different nanocrystal quantum dots and rods excited by 400 nm light in applied magnetic fields up to 17.5 T revealed size-dependent energy gaps separating bright and dark exciton fine-structure states. For 1-D nanorods under strong cross-sectional confinement and large length-to-diameter aspect ratios, efficient mixing of bright and dark exciton states was achieved using relatively low applied field strengths (≤4 T). The effect was attributed, in part, to decreased confinement of CdSe hole states associated with the long axis of the nanorod, which resulted in reduction of the energy gaps separating the bright and dark states. Increased control over the angle formed between the applied field vectors and the nanocrystal c-axis led to more efficient and uniform mixing of nanorod exciton states than for quantum dots. The findings suggest 1-D nanostructures are advantageous over 0-D ones for field-responsive applications. PMID:23945622

  10. Hybrid conjugated organic oligomers consisting of oligodiacetylene and thiophene units: synthesis and optical properties.

    PubMed

    Pilzak, Gregor S; van Gruijthuijsen, Kitty; van Doorn, Reindert H; van Lagen, Barend; Sudhölter, Ernst J R; Zuilhof, Han

    2009-09-14

    Novel and highly soluble hybrid conjugated organic oligomers consisting of oligodiacetylene and thiophene units have been synthesized in high purity through iterative and divergent approaches based on a sequence of Sonogashira reactions. The series of thiophene-containing oligodiacetylenes (ThODAs) and homocoupled ThODAs (HThODAs) show--both in solution and in the solid state--a strong optical absorption, which is progressively red shifted with increasing chain length. The linear correlation of the absorption maximum (lambda(A)(max)) with the inverse of conjugation length (CL = number of double and triple bonds) shows that the effective conjugation length of this system is extended up to at least CL = 20. Furthermore, absorption measurements of dropcast thin films display not only a bathochromic shift of the absorption maxima but also a higher wavelength absorption, which is attributed to increased pi-pi interactions. The wavelength of the maximum fluorescence emission (lambda(E)(max)) also increases with CL, and emission is maximal for oligomers with CL=7-12 (fluorescence quantum yield Phi(F) = approximately 0.2). Both longer and shorter oligomers display marginal emission. The calculated Stokes shifts of these planar materials are relatively large (0.4 eV) for all oligomers, and likely due to excitation to the S(2) state, thus suggesting that the presence of enyne moieties dominates the ordering of the lowest excited states. The fluorescence lifetimes (tau(F)) are short (tau(F,max) = <1 ns) and closely follow the tendency obtained for the fluorescence quantum yield. The anisotropy lifetimes show a near-linear increase with CL, in line with highly rigid oligomers. PMID:19637259

  11. Diel Variability in Dissolved Organic Matter Composition Determined by in-situ Optical Measurements.

    NASA Astrophysics Data System (ADS)

    Spencer, R. G.; Pellerin, B. A.; Bergamaschi, B. A.; Downing, B. D.; Kraus, T. E.; Hernes, P. J.

    2006-12-01

    Annual and interannual variability in DOM concentration and composition in rivers has been well documented however few studies have evaluated changes in DOM over short time scales such as diel cycles. Recent research has shown that concentrations of dissolved oxygen, inorganic nitrogen and trace metals for example vary considerably over diel cycles in streams and rivers due to a combination of biological, physical and chemical processes. In this study DOM variability was investigated over the diel cycle under stable riverine summer flow conditions in the San Joaquin River (California, U.S.A.) to evaluate if high resolution in-situ optical measurements revealed changes in DOM concentration and composition. Bulk dissolved organic carbon (DOC) concentrations showed no clear trend over diel cycles but in contrast the absorption coefficient of chromophoric DOM (CDOM) measured in situ at 350nm (a350 m-1 showed a clear diurnal pattern with CDOM maxima in the late evening and minima in the early morning. Similar diurnal patterns were recorded at a254 m- 1 and a440 m-1, absorbance wavelengths which have also been referred too as proxies for DOC quality and quantity. Chlorophyll-a fluorescence showed the same diurnal pattern as CDOM absorbance with early evening maxima and early morning minima in concentrations and previous studies indicate that phytoplankton is the primary source of organic matter in the San Joaquin River during summer months. In situ DOM fluorescence (measured at excitiation 370 nm, emission 450 nm) and spectral slope (S) calculated using a non-linear fit of an exponential function to the absorption spectrum in the range of 290 - 350 nm both showed clear diurnal patterns. With respect to DOM fluorescence and S290-350 maxima were recorded in the morning and minima in the late evening and so were out of phase with CDOM absorbance and chlorophyll-a fluorescence. This asynchronous pattern in DOM fluorescence and absorption coefficients over diel cycles in our

  12. Growth of thin films of organic nonlinear optical materials by vapor growth processes - An overview and examination of shortfalls

    NASA Technical Reports Server (NTRS)

    Frazier, D. O.; Penn, B. G.; Witherow, W. K.; Paley, M. S.

    1991-01-01

    Research on the growth of second- and third-order nonlinear optical (NLO) organic thin film by vapor deposition is reviewed. Particular attention is given to the experimental methods for growing thin films of p-chlorophenylurea, diacetylenes, and phthalocyanines; characteristics of the resulting films; and approaches for advancing thin film technology. It is concluded that the growth of NLO thin films by vapor processes is a promising method for the fabrication of planar waveguides for nonlinear optical devices. Two innovative approaches are proposed including a method of controlling the input beam frequency to maximize nonlinear effects in thin films and single crystals, and the alternate approach to the molecular design of organic NLO materials by increasing the transition dipole moment between ground and excited states of the molecule.

  13. Methodological challenges of optical tweezers-based X-ray fluorescence imaging of biological model organisms at synchrotron facilities.

    PubMed

    Vergucht, Eva; Brans, Toon; Beunis, Filip; Garrevoet, Jan; Bauters, Stephen; De Rijcke, Maarten; Deruytter, David; Janssen, Colin; Riekel, Christian; Burghammer, Manfred; Vincze, Laszlo

    2015-07-01

    Recently, a radically new synchrotron radiation-based elemental imaging approach for the analysis of biological model organisms and single cells in their natural in vivo state was introduced. The methodology combines optical tweezers (OT) technology for non-contact laser-based sample manipulation with synchrotron radiation confocal X-ray fluorescence (XRF) microimaging for the first time at ESRF-ID13. The optical manipulation possibilities and limitations of biological model organisms, the OT setup developments for XRF imaging and the confocal XRF-related challenges are reported. In general, the applicability of the OT-based setup is extended with the aim of introducing the OT XRF methodology in all research fields where highly sensitive in vivo multi-elemental analysis is of relevance at the (sub)micrometre spatial resolution level.

  14. Impact of storage induced outgassing organic contamination on laser induced damage of silica optics at 351 nm.

    PubMed

    Bien-Aimé, K; Belin, C; Gallais, L; Grua, P; Fargin, E; Néauport, J; Tovena-Pecault, I

    2009-10-12

    The impact of storage conditions on laser induced damage density at 351 nm on bare fused polished silica samples has been studied. Intentionally outgassing of polypropylene pieces on silica samples was done. We evidenced an important increase of laser induced damage density on contaminated samples demonstrating that storage could limit optics lifetime performances. Atomic Force Microscopy (AFM) and Gas Chromatography -Mass Spectrometry (GC-MS) have been used to identify the potential causes of this effect. It shows that a small quantity of organic contamination deposited on silica surface is responsible for this degradation. Various hypotheses are proposed to explain the damage mechanism. The more likely hypothesis is a coupling between surface defects of optics and organic contaminants.

  15. Synthesis, structural, optical, thermal and dielectric studies on new organic nonlinear optical crystal by solution growth technique

    NASA Astrophysics Data System (ADS)

    Prakash, M.; Geetha, D.; Lydia Caroline, M.

    2013-04-01

    Single crystals of L-phenylalanine-benzoic acid (LPBA) were successfully grown from aqueous solution by solvent evaporation technique. Purity of the crystals was increased by the method of recrystallization. The XRD analysis confirms that the crystal belongs to the monoclinic system with noncentrosymmetric space group P21. The chemical structure of compound was established by FT-NMR technique. The presence of functional groups was estimated qualitatively by Fourier transform infrared analysis (FT-IR). Ultraviolet-visible spectral analyses showed that the crystal has low UV cut-off at 254 nm combined with very good transparency of 90% in a wide range. The optical band gap was estimated to be 6.91 eV. Thermal behavior has been studied with TGA/DTA analyses. The existence of second harmonic generation (SHG) efficiency was found to be 0.56 times the value of KDP. The dielectric behavior of the sample was also studied for the first time.

  16. Synthesis, structural, optical, thermal and dielectric studies on new organic nonlinear optical crystal by solution growth technique.

    PubMed

    Prakash, M; Geetha, D; Lydia Caroline, M

    2013-04-15

    Single crystals of L-phenylalanine-benzoic acid (LPBA) were successfully grown from aqueous solution by solvent evaporation technique. Purity of the crystals was increased by the method of recrystallization. The XRD analysis confirms that the crystal belongs to the monoclinic system with noncentrosymmetric space group P21. The chemical structure of compound was established by FT-NMR technique. The presence of functional groups was estimated qualitatively by Fourier transform infrared analysis (FT-IR). Ultraviolet-visible spectral analyses showed that the crystal has low UV cut-off at 254 nm combined with very good transparency of 90% in a wide range. The optical band gap was estimated to be 6.91 eV. Thermal behavior has been studied with TGA/DTA analyses. The existence of second harmonic generation (SHG) efficiency was found to be 0.56 times the value of KDP. The dielectric behavior of the sample was also studied for the first time.

  17. An organic dye-polymer (phenol red-poly (vinyl alcohol)) composite architecture towards tunable -optical and -saturable absorption characteristics

    NASA Astrophysics Data System (ADS)

    Sreedhar, Sreeja; Illyaskutty, Navas; Sreedhanya, S.; Philip, Reji; Muneera, C. I.

    2016-05-01

    Herein, we demonstrate that blending an organic dye (guest/filler), with a vinyl polymer (host template), is an inexpensive and simple approach for the fabrication of multifunctional photonic materials which could display an enhancement in the desirable properties of the constituent materials and, at the same time provide novel synergistic properties for the guest-host system. A new guest-host nanocomposite system comprising Phenol Red dye and poly (vinyl alcohol) as guest and host template, respectively, which exhibits tunable optical characteristics and saturable absorption behavior, is introduced. The dependence of local electronic environment provided by the polymer template and the interactions of the polymer molecules with the encapsulated guest molecules on the observed optical/nonlinear absorption behavior is discussed. An understanding of the tunability of the optical/ photophysical processes, with respect to the filler content, as discussed herein could help in the design of improved optical materials for several photonic device applications like organic light emitting diodes and saturable absorbers.

  18. Estimating absorbing black carbon and organic carbon optical properties from AERONET and MISR data over East Asia

    NASA Astrophysics Data System (ADS)

    Chen, B.; Ramanathan, V.; Huang, J.; Zhang, G. J.; Xu, Y.

    2011-12-01

    The radiative forcing due to carbonaceous aerosols is one of the largest source of uncertainties in global and regional climate change. Black carbon and organic carbon from biomass and fossil fuel are two major types of carbonaceous aerosols. In this study we use available ground based and satellite observations to infer the optical properties of black and organic carbon. NASA's AERONET and MISR data over East Asia provide the observational basis. We use the spectral variations in the observed aerosol extinction optical depth and absorption optical depth to categorize the optical properties including their mixing state with other aerosols such as dust and other inorganic aerosols. We create 8 different categories of aerosol mixtures: Dust, Biomass Burning, Fossil Fuel, Aged Fossil Fuel, Mixed Dust with Biomass Burning, Mixed Dust with Aged Fossil Fuel, Mixed Biomass Burning with Fossil Fuel, and Mixed Dust, Biomass Burning, with Fossil Fuel, over the following 6 regions of East Asia: Nepal, Gobi, North Industrial China, South Industrial China, Southeast Asia, and Korea/Japan. Our results are compared with independent surface observations over China using Aethalometers and Single Particle Soot Photometers.

  19. Growth and birefringence studies of semi organic non-linear optical LHB single crystal

    NASA Astrophysics Data System (ADS)

    Jayaramakrishnan, V.; Prasanyaa, T.; Haris, M.; Bhoopathi, G.

    2015-02-01

    In the last few decades nonlinear optical materials are getting attention in the field of optical data storage, telecommunication, second harmonic generation (SHG) and optical signal processing, etc. In the present work we are reporting the single crystal growth of L-Histidine with hydro-bromic acid. The L-Histidine bromide (LHB) single crystals have been harvested from the solution in a span of 34 days by adopting slow cooling solution growth technique. The grown crystals have been subjected to powder X-ray diffraction studies to identify the cell parameters and structure. The crystalline perfection has been defined by rocking curve (HRXRD) analysis. Optical transmission spectra reveal the optical properties of the grown crystals. The Modified channel spectrum (MCS) method has been adopted for the study of spectral dependence of linear birefringence over the wavelength range 480-620 nm. The second harmonic generation efficiency was tested by using Kurtz and Perry method, keeping KDP as reference.

  20. Optical Coherence Tomography to Measure Sound-Induced Motions Within the Mouse Organ of Corti In Vivo.

    PubMed

    Jawadi, Zina; Applegate, Brian E; Oghalai, John S

    2016-01-01

    The measurement of mechanical vibrations within the living cochlea is critical to understanding the first nonlinear steps in auditory processing, hair cell stimulation, and cochlear amplification. However, it has proven to be a challenging endeavor. This chapter describes how optical coherence tomography (OCT) can be used to measure vibrations within the tissues of the organ of Corti. These experimental measurements can be performed within the unopened cochlea of living mice routinely and reliably. PMID:27259941

  1. Optical Signature of Charge Transfer in n-Type Carbon Nanotube Transistors Doped with Printable Organic Molecules

    NASA Astrophysics Data System (ADS)

    Shimizu, Ryo; Matsuzaki, Satoki; Yanagi, Kazuhiro; Takenobu, Taishi

    2012-12-01

    Single-walled carbon nanotubes (SWCNTs) are known to be p-type semiconductors, due to unintentional hole doping. Therefore, air-stable electron dopants are important for the fabrication of logic circuits. Recently, n-type characteristics of SWCNT film transistors have been achieved by using several types of donative organic molecules, and these molecular dopants have opened a route for application. However, it is still unclear whether the cause of n-type operation is the Fermi level shift of SWCNTs or the lowering of the Schottky barrier for electrons. In this study, we found the evidences of electron transfer from organic molecules to SWCNTs using optical measurements.

  2. Optical bedside monitoring of cerebral perfusion: technological and methodological advances applied in a study on acute ischemic stroke

    NASA Astrophysics Data System (ADS)

    Steinkellner, Oliver; Gruber, Clemens; Wabnitz, Heidrun; Jelzow, Alexander; Steinbrink, Jens; Fiebach, Jochen B.; MacDonald, Rainer; Obrig, Hellmuth

    2010-11-01

    We present results of a clinical study on bedside perfusion monitoring of the human brain by optical bolus tracking. We measure the kinetics of the contrast agent indocyanine green using time-domain near-IR spectroscopy (tdNIRS) in 10 patients suffering from acute unilateral ischemic stroke. In all patients, a delay of the bolus over the affected when compared to the unaffected hemisphere is found (mean: 1.5 s, range: 0.2 s to 5.2 s). A portable time-domain near-IR reflectometer is optimized and approved for clinical studies. Data analysis based on statistical moments of time-of-flight distributions of diffusely reflected photons enables high sensitivity to intracerebral changes in bolus kinetics. Since the second centralized moment, variance, is preferentially sensitive to deep absorption changes, it provides a suitable representation of the cerebral signals relevant for perfusion monitoring in stroke. We show that variance-based bolus tracking is also less susceptible to motion artifacts, which often occur in severely affected patients. We present data that clearly manifest the applicability of the tdNIRS approach to assess cerebral perfusion in acute stroke patients at the bedside. This may be of high relevance to its introduction as a monitoring tool on stroke units.

  3. Dynamic optical interferometry applied to analyse out of plane displacement fields for crack propagation in brittle materials

    NASA Astrophysics Data System (ADS)

    Hedan, S.; Pop, O.; Valle, V.; Cottron, M.

    2006-08-01

    We propose in this paper, to analyse, the evolution of out-of-plane displacement fields for a crack propagation in brittle materials. As the crack propagation is a complex process that involves the deformation mechanisms, the out-of-plane displacement measurement gives pertinent information about the 3D effects. For investigation, we use the interferometric method. The optical device includes a laser source, a Michelson interferometer and an ultra high-speed CCD camera. To take into account the crack velocity, we dispose of a maximum frame rate of 1Mfps. The experimental tests have been carried out for a SEN (Single Edge Notch) specimen of PMMA material. The crack propagation is initiated by adding a dynamic energy given by the impact of a cutter on the initial crack. The obtained interferograms are analysed with a new phase extraction method entitled MPC [6]. This analysis, which has been developed specially for dynamic studies, gives the out-of-plane displacement with an accuracy of about 10 nm.

  4. 2D and 3D optical diagnostic techniques applied to Madonna dei Fusi by Leonardo da Vinci

    NASA Astrophysics Data System (ADS)

    Fontana, R.; Gambino, M. C.; Greco, M.; Marras, L.; Materazzi, M.; Pampaloni, E.; Pelagotti, A.; Pezzati, L.; Poggi, P.; Sanapo, C.

    2005-06-01

    3D measurement and modelling have been traditionally applied to statues, buildings, archeological sites or similar large structures, but rarely to paintings. Recently, however, 3D measurements have been performed successfully also on easel paintings, allowing to detect and document the painting's surface. We used 3D models to integrate the results of various 2D imaging techniques on a common reference frame. These applications show how the 3D shape information, complemented with 2D colour maps as well as with other types of sensory data, provide the most interesting information. The 3D data acquisition was carried out by means of two devices: a high-resolution laser micro-profilometer, composed of a commercial distance meter mounted on a scanning device, and a laser-line scanner. The 2D data acquisitions were carried out using a scanning device for simultaneous RGB colour imaging and IR reflectography, and a UV fluorescence multispectral image acquisition system. We present here the results of the techniques described, applied to the analysis of an important painting of the Italian Reinassance: `Madonna dei Fusi', attributed to Leonardo da Vinci.

  5. Development and Test of a 1,000 Level 3C Fiber Optic Borehole Seismic Receiver Array Applied to Carbon Sequestration

    SciTech Connect

    Paulsson, Bjorn N.P.

    2015-02-28

    To address the critical site characterization and monitoring needs for CCS programs, US Department of Energy (DOE) awarded Paulsson, Inc. in 2010 a contract to design, build and test a fiber optic based ultra-large bandwidth clamped borehole seismic vector array capable of deploying up to one thousand 3C sensor pods suitable for deployment into high temperature and high pressure boreholes. Paulsson, Inc. has completed a design or a unique borehole seismic system consisting of a novel drill pipe based deployment system that includes a hydraulic clamping mechanism for the sensor pods, a new sensor pod design and most important – a unique fiber optic seismic vector sensor with technical specifications and capabilities that far exceed the state of the art seismic sensor technologies. These novel technologies were all applied to the new borehole seismic system. In combination these technologies will allow for the deployment of up to 1,000 3C sensor pods in vertical, deviated or horizontal wells. Laboratory tests of the fiber optic seismic vector sensors developed during this project have shown that the new borehole seismic sensor technology is capable of generating outstanding high vector fidelity data with extremely large bandwidth: 0.01 – 6,000 Hz. Field tests have shown that the system can record events at magnitudes much smaller than M-2.3 at frequencies up to 2,000 Hz. The sensors have also proved to be about 100 times more sensitive than the regular coil geophones that are used in borehole seismic systems today. The fiber optic seismic sensors have furthermore been qualified to operate at temperatures over 300°C (572°F). The fibers used for the seismic sensors in the system are used to record Distributed Temperature Sensor (DTS) data allowing additional value added data to be recorded simultaneously with the seismic vector sensor data.

  6. Advanced processing methods to introduce and preserve dipole orientation in organic electro-optic materials for next generation photonic devices

    NASA Astrophysics Data System (ADS)

    Huang, Su

    Organic electro-optic (E-O) materials have attracted considerable research attention in the past 20 years due to their rising potentials in a lot of novel photonic applications, such as high-speed telecommunication, terahertz generation and ultra-fast optical interconnections. Chapter 2 of this dissertation focuses on a barrier layer approach to improve the poling efficiency of electro-optic polymers. First of all, high conduction current from excessive charge injection is identified as a fundamental challenge of effective poling. After analyzing the conduction mechanism, we introduce a sol-gel derived thin titanium dioxide (TiO2) layer that can significantly block excessive charge injection and reduce the leakage current during high field poling. Ultralarge E-O coefficients, up to 160-350 pm/V at 1310 nm have been achieved by poling with such a barrier, which are 26%-40% higher than the results poled without such a TiO2 layer. This enhancement is explained by the suppressed charge injection and space charge accumulation by the insertion of the high injection barrier from the TiO2 barrier layer. In Chapter 3, the impact of the inserted barrier layer on the temporal alignment stability of E-O polymers is discussed. Considerable stability enhancement is confirmed using both standard 500-hour temporal alignment stability test at 85 °C and thermally stimulated discharge method. We suggest that the enhancement comes from improved stability of the screening charge. During poling the additional barrier layer helps to lower the injection and thus the space charge accumulation. And this reduced space charge accumulation further helps to replace the space charge part in the total formulation of screening charge with more stable interface trapped charge. We thus expand this knowledge to a group of other materials that can also block excessive charge injection and suppressed space charge accumulation, including dielectric polymers polyvinyl alcohol (PVA), poly(4-vinylphenol

  7. Optical Simulation and Optimization of Light Extraction Efficiency for Organic Light Emitting Diodes

    NASA Astrophysics Data System (ADS)

    Su, Hang

    Current organic light emitting diodes (OLEDs) suffer from the low light extraction efficiency. In this thesis, novel OLED structures including photonic crystal, Fabry-Perot resonance cavity and hyperbolic metamaterials were numerically simulated and theoretically investigated. Finite-difference time-domain (FDTD) method was employed to numerically simulate the light extraction efficiency of various 3D OLED structures. With photonic crystal structures, a maximum of 30% extraction efficiency is achieved. A higher external quantum efficiency of 35% is derived after applying Fabry-Perot resonance cavity into OLEDs. Furthermore, different factors such as material properties, layer thicknesses and dipole polarizations and locations have been studied. Moreover, an upper limit for the light extraction efficiency of 80% is reached theoretically with perfect reflector and single dipole polarization and location. To elucidate the physical mechanism, transfer matrix method is introduced to calculate the spectral-hemispherical reflectance of the multilayer OLED structures. In addition, an attempt of using hyperbolic metamaterial in OLED has been made and resulted in 27% external quantum efficiency, due to the similar mechanism of wave interference as Fabry-Perot structure. The simulation and optimization methods and findings would facilitate the design of next generation, high-efficiency OLED devices.

  8. Structural, thermal, linear and nonlinear optical studies of an organic optical limiter based on reverse saturable absorption

    NASA Astrophysics Data System (ADS)

    Menezes, Anthoni Praveen; Raghavendra, S.; Jayarama, A.; Sarveshwara, H. P.; Dharmaprakash, S. M.

    2016-09-01

    A new derivative of chalcone, 3-(4-bromophenyl)-1-(pyridin-4-yl) prop-2-en-1-one (4BP4AP), crystallizing in centrosymmetric structure has been synthesized using the Claisen-Schmidt condensation reaction method. The FTIR and FT-Raman spectral studies were carried out on 4BP4AP for structural conformation. The single crystals were grown using slow evaporation solution growth technique. The single crystal XRD of the crystal shows that the crystal system of 4BP4AP is triclinic with space group P-1. Scanning electron microscope images enunciate the surface smoothness and the two dimensional growth mechanisms in the crystal. The crystal is transparent in the entire visible region as indicated by the UV-VIS-NIR spectrum. The thermal stability and phase transition of the compound was studied by thermogravimetric and differential scanning calorimetric analysis and found to be stable up to 200 °C. By performing the open aperture z-scan experiment, nonlinear absorption and optical limiting behavior of the crystal were studied. The crystal can be used for optoelectronic application due to its excellent photo-physical properties.

  9. Synthesis, structural, optical, thermal and dielectric studies on new organic nonlinear optical crystal by solution growth technique.

    PubMed

    Prakash, M; Geetha, D; Lydia Caroline, M

    2013-04-15

    Single crystals of L-phenylalanine-benzoic acid (LPBA) were successfully grown from aqueous solution by solvent evaporation technique. Purity of the crystals was increased by the method of recrystallization. The XRD analysis confirms that the crystal belongs to the monoclinic system with noncentrosymmetric space group P21. The chemical structure of compound was established by FT-NMR technique. The presence of functional groups was estimated qualitatively by Fourier transform infrared analysis (FT-IR). Ultraviolet-visible spectral analyses showed that the crystal has low UV cut-off at 254 nm combined with very good transparency of 90% in a wide range. The optical band gap was estimated to be 6.91 eV. Thermal behavior has been studied with TGA/DTA analyses. The existence of second harmonic generation (SHG) efficiency was found to be 0.56 times the value of KDP. The dielectric behavior of the sample was also studied for the first time. PMID:23416904

  10. Tidal Marsh Outwelling of Dissolved Organic Matter and Resulting Temporal Variability in Coastal Water Optical and Biogeochemical Properties

    NASA Technical Reports Server (NTRS)

    Tzortziou, Maria; Neale, Patrick J.; Megonigal, J. Patrick; Butterworth, Megan; Jaffe, Rudolf; Yamashita, Youhei

    2010-01-01

    Coastal wetlands are highly dynamic environments at the land-ocean interface where human activities, short-term physical forcings and intense episodic events result in high biological and chemical variability. Long being recognized as among the most productive ecosystems in the world, tidally-influenced coastal marshes are hot spots of biogeochemical transformation and exchange. High temporal resolution observations that we performed in several marsh-estuarine systems of the Chesapeake Bay revealed significant variability in water optical and biogeochemical characteristics at hourly time scales, associated with tidally-driven hydrology. Water in the tidal creek draining each marsh was sampled every hour during several semi-diurnal tidal cycles using ISCO automated samplers. Measurements showed that water leaving the marsh during ebbing tide was consistently enriched in dissolved organic carbon (DOC), frequently by more than a factor of two, compared to water entering the marsh during flooding tide. Estimates of DOC fluxes showed a net DOC export from the marsh to the estuary during seasons of both low and high biomass of marsh vegetation. Chlorophyll amounts were typically lower in the water draining the marsh, compared to that entering the marsh during flooding tide, suggesting that marshes act as transformers of particulate to dissolved organic matter. Moreover, detailed optical and compositional analyses demonstrated that marshes are important sources of optically and chemically distinctive, relatively complex, high molecular weight, aromatic-rich and highly colored dissolved organic compounds. Compared to adjacent estuarine waters, marsh-exported colored dissolved organic matter (CDOM) was characterized by considerably stronger absorption (more than a factor of three in some cases), larger DOC-specific absorption, lower exponential spectral slope, larger fluorescence signal, lower fluorescence per unit absorbance, and higher fluorescence at visible wavelengths

  11. Optical emission spectroscopy of microwave-plasmas at atmospheric pressure applied to the growth of organosilicon and organotitanium nanopowders

    NASA Astrophysics Data System (ADS)

    Kilicaslan, A.; Levasseur, O.; Roy-Garofano, V.; Profili, J.; Moisan, M.; Côté, C.; Sarkissian, A.; Stafford, L.

    2014-03-01

    An atmospheric-pressure plasma sustained by an electromagnetic surface wave (SW) in the microwave regime combined with a bubbler/flash evaporator for the injection of liquid precursors was used to produce organosilicon and organotitanium nanopowders. Following the addition of hexamethyldisiloxane (HMDSO) vapors in the nominally pure argon plasma, optical emission spectra revealed the apparition of strong C2 molecular bands along with Si and Balmer H emission lines. Such features were not observed in our atmospheric-pressure Ar/HMDSO discharges controlled by dielectric barriers, indicating that microwave plasmas are characterized by much higher fragmentation levels of the precursors due to much higher electron densities. Emission spectra from the Ar/HMDSO SW plasma further showed a high-intensity continuum, the intensity of which decreased with time as powders started to form on the discharge tube walls. In presence of titanium isopropoxide (TTIP) vapors in the nominally pure Ar plasma, the emission was dominated by Ar and Ti lines, with no trace of carbon and no continuum. Fourier-Transform Infrared (FTIR) Spectroscopy of the powders formed in Ar/HMDSO plasmas showed very strong Si-(CH3)x and O-Si-(CH3)x bands, which is consistent with the formation of silicon oxycarbide. Transmission Electron Microscopy (TEM) further showed tube and sheet-like nanofeatures as well as larger structures consisting of agglomerated primary clusters. On the other hand, introduction of O2 in Ar/HMDSO plasmas produced only round-like nanoparticles with strong Si-O-Si bands and no trace of carbon, consistent with the formation of SiOx. The average size of the silica nanoparticles was 50 nm. FTIR spectra of powders formed in Ar/TTIP plasmas showed strong Ti-O signals, even without the addition of O2 in the gas phase. Corresponding TEM analysis showed nano- and agglomerated features comparable to those obtained in Ar/HMDSO although the average size of the titanate nanoparticles was smaller

  12. Optical emission spectroscopy of microwave-plasmas at atmospheric pressure applied to the growth of organosilicon and organotitanium nanopowders

    SciTech Connect

    Kilicaslan, A.; Levasseur, O.; Roy-Garofano, V.; Profili, J.; Moisan, M.; Stafford, L.; Côté, C.; Sarkissian, A.

    2014-03-21

    An atmospheric-pressure plasma sustained by an electromagnetic surface wave (SW) in the microwave regime combined with a bubbler/flash evaporator for the injection of liquid precursors was used to produce organosilicon and organotitanium nanopowders. Following the addition of hexamethyldisiloxane (HMDSO) vapors in the nominally pure argon plasma, optical emission spectra revealed the apparition of strong C{sub 2} molecular bands along with Si and Balmer H emission lines. Such features were not observed in our atmospheric-pressure Ar/HMDSO discharges controlled by dielectric barriers, indicating that microwave plasmas are characterized by much higher fragmentation levels of the precursors due to much higher electron densities. Emission spectra from the Ar/HMDSO SW plasma further showed a high-intensity continuum, the intensity of which decreased with time as powders started to form on the discharge tube walls. In presence of titanium isopropoxide (TTIP) vapors in the nominally pure Ar plasma, the emission was dominated by Ar and Ti lines, with no trace of carbon and no continuum. Fourier-Transform Infrared (FTIR) Spectroscopy of the powders formed in Ar/HMDSO plasmas showed very strong Si-(CH{sub 3}){sub x} and O-Si-(CH{sub 3}){sub x} bands, which is consistent with the formation of silicon oxycarbide. Transmission Electron Microscopy (TEM) further showed tube and sheet-like nanofeatures as well as larger structures consisting of agglomerated primary clusters. On the other hand, introduction of O{sub 2} in Ar/HMDSO plasmas produced only round-like nanoparticles with strong Si-O-Si bands and no trace of carbon, consistent with the formation of SiO{sub x}. The average size of the silica nanoparticles was 50 nm. FTIR spectra of powders formed in Ar/TTIP plasmas showed strong Ti-O signals, even without the addition of O{sub 2} in the gas phase. Corresponding TEM analysis showed nano- and agglomerated features comparable to those obtained in Ar/HMDSO although the

  13. Optical studies of the charge transfer complex in polythiophene/fullerene blends for organic photovoltaic applications

    NASA Astrophysics Data System (ADS)

    Drori, T.; Holt, J.; Vardeny, Z. V.

    2010-08-01

    We studied the photophysics of regioregular polythiophene/ C61 (RR-P3HT/PCBM) blend films utilized for organic photovoltaic applications using the femtosecond transient and steady-state photomodulation techniques with above-gap and below-gap pump excitations and electroabsorption spectroscopy. We provide strong evidence for the existence of charge transfer complex (CTC) state in the blend that is formed deep inside the optical gap of the polymer and fullerene constituents, which is clearly revealed in the electroabsorption spectrum with an onset at 1.2 eV. We identify this “midgap” band as the lowest lying CTC state formed at the interfaces separating the polymer and fullerene phases. With above-gap pump excitation the primary photoexcitations in the blend are excitons and polarons in the polymer domains that are generated within the experimental time resolution (150 fs), having distinguishable photoinduced absorption (PA) bands in the mid-IR. The photogenerated excitons subsequently decay within ˜10ps , consistent with the polymer weak photoluminescence in the blend. In contrast, with below-gap pump excitation, a new PA band in the mid-IR is generated within our time resolution, which is associated with photogenerated species that decay into polarons at much later times; also no PA of excitons is observed. We interpret the photoexcitations as CT excitons, which with below-gap pump excitation are resonantly generated on the CTC states at the interfaces, as the first step for polaron generation, without involving intrachain excitons in the polymer phase. We found that the polarons generated with below-gap pump excitation are trapped at the interfaces with relatively long lifetime, and thus may generate polarons on the polymer chains and fullerene molecules with a different mechanism than with above-gap excitation. In any case the interfacial polarons generated with below-gap excitation do not substantially contribute to the photocurrent density in photovoltaic

  14. Nonlinear Optical Macroscopic Assessment of 3-D Corneal Collagen Organization and Axial Biomechanics

    PubMed Central

    Winkler, Moritz; Chai, Dongyul; Kriling, Shelsea; Nien, Chyong Jy; Brown, Donald J.; Jester, Bryan; Juhasz, Tibor

    2011-01-01

    Purpose. To characterize and quantify the collagen fiber (lamellar) organization of human corneas in three dimensions by using nonlinear optical high-resolution macroscopy (NLO-HRMac) and to correlate these findings with mechanical data obtained by indentation testing of corneal flaps. Methods. Twelve corneas from 10 donors were studied. Vibratome sections, 200 μm thick, from five donor eyes were cut along the vertical meridian from limbus to limbus (arc length, 12 mm). Backscattered second harmonic–generated (SHG) NLO signals from these sections were collected as a series of overlapping 3-D images, which were concatenated to form a single 3-D mosaic (pixel resolution: 0.44 μm lateral, 2 μm axial). Collagen fiber intertwining was quantified by determining branching point density as a function of stromal depth. Mechanical testing was performed on corneal flaps from seven additional eyes. Corneas were cut into three layers (anterior, middle, and posterior) using a femtosecond surgical laser system and underwent indentation testing to determine the elastic modulus for each layer. Results. The 3-D reconstructions revealed complex collagen fiber branching patterns in the anterior cornea, with fibers extending from the anterior limiting lamina (ALL, Bowman's layer), intertwining with deeper fibers and reinserting back to the ALL, forming bow spring–like structures. Measured branching-point density was four times higher in the anterior third of the cornea than in the posterior third and decreased logarithmically with increasing distance from the ALL. Indentation testing showed an eightfold increase in elastic modulus in the anterior stroma. Conclusions. The axial gradient in lamellar intertwining appears to be associated with an axial gradient in the effective elastic modulus of the cornea, suggesting that collagen fiber intertwining and formation of bow spring–like structures provide structural support similar to cross-beams in bridges and large-scale structures

  15. Black carbon aerosol mixing state, organic aerosols and aerosol optical properties over the United Kingdom

    NASA Astrophysics Data System (ADS)

    McMeeking, G. R.; Morgan, W. T.; Flynn, M.; Highwood, E. J.; Turnbull, K.; Haywood, J.; Coe, H.

    2011-09-01

    Black carbon (BC) aerosols absorb sunlight thereby leading to a positive radiative forcing and a warming of climate and can also impact human health through their impact on the respiratory system. The state of mixing of BC with other aerosol species, particularly the degree of internal/external mixing, has been highlighted as a major uncertainty in assessing its radiative forcing and hence its climate impact, but few in situ observations of mixing state exist. We present airborne single particle soot photometer (SP2) measurements of refractory BC (rBC) mass concentrations and mixing state coupled with aerosol composition and optical properties measured in urban plumes and regional pollution over the United Kingdom. All data were obtained using instrumentation flown on the UK's BAe-146-301 large Atmospheric Research Aircraft (ARA) operated by the Facility for Airborne Atmospheric Measurements (FAAM). We measured sub-micron aerosol composition using an aerosol mass spectrometer (AMS) and used positive matrix factorization to separate hydrocarbon-like (HOA) and oxygenated organic aerosols (OOA). We found a higher number fraction of thickly coated rBC particles in air masses with large OOA relative to HOA, higher ozone-to-nitrogen oxides (NOx) ratios and large concentrations of total sub-micron aerosol mass relative to rBC mass concentrations. The more ozone- and OOA-rich air masses were associated with transport from continental Europe, while plumes from UK cities had higher HOA and NOx and fewer thickly coated rBC particles. We did not observe any significant change in the rBC mass absorption efficiency calculated from rBC mass and light absorption coefficients measured by a particle soot absorption photometer despite observing significant changes in aerosol composition and rBC mixing state. The contributions of light scattering and absorption to total extinction (quantified by the single scattering albedo; SSA) did change for different air masses, with lower SSA

  16. Optical properties of organic thin films of 4-tricyanovinyl-{N}, {N}-diethylaniline

    NASA Astrophysics Data System (ADS)

    El-Nahass, M. M.; Abd-El-Rahman, K. F.; Darwish, A. A. A.

    2009-11-01

    Optical properties of 4-tricyanovinyl-N, N-diethylaniline thin films were investigated using spectrophotometric measurement of transmittance and reflectance at normal incidence of light in the wavelength range of 200-2500 nm. The optical constants (refractive index, n, and absorption index, k) were calculated using a computer program based on Murmann's exact equations. The calculated optical constants are independent of the film thickness and their values are decreased by annealing temperature. The optical dispersion parameters have been analysed by single oscillator model. The type of transition in as-deposited films is indirect allowed with a value of energy gap equals to 1.45 eV, which increased to 1.51 eV upon annealing. in here

  17. Electro-optical probe for studying local fields in organic heterostructures

    NASA Astrophysics Data System (ADS)

    Blinov, L. M.; Lazarev, V. V.; Semeikin, A. S.; Usol'tseva, N. V.; Yudin, S. G.

    2013-03-01

    Dielectric, optical, and electro-optical properties of thin Langmuir films (40-130 nm thick) of meso-substituted palladium tetraphenylporphyrin have been investigated. The key parameter of the characteristic electro-absorption band of this material—the difference in the polarizability for the excited and ground states of its molecules—has been determined. The example of determining the local field in the polymer ferroelectric in the composition of two-layer heterostructure is shown.

  18. Neural organization of first optic neuropils in the littoral crab Hemigrapsus oregonensis and the semiterrestrial species Chasmagnathus granulatus

    PubMed Central

    Sztarker, Julieta; Strausfeld, Nicholas; Andrew, David; Tomsic, Daniel

    2014-01-01

    Crustaceans are among the most extensively distributed arthropods, occupying many ecologies and manifesting a great variety of compound eye optics; but in comparison with insects, relatively little is known about the organization and neuronal morphologies of their underlying optic neuropils. Most studies, which have been limited to descriptions of the first neuropil - the lamina - suggest that different species have approximately comparable cell types. However, such studies have been limited with regard to the types of neurons they identify and most omit their topographic relationships. It is also uncertain whether similarities, such as they are, are independent of visual ecologies. The present account describes and compares the morphologies and dispositions of monopolar and other efferent neurons as well as the organization of tangential and smaller centrifugal neurons in two grapsoid crabs, one from the S. Atlantic, the other from the N. Pacific. Because these species occupy significantly disparate ecologies we ask whether this might be reflected in differences of cell arrangements within the most peripheral levels of the visual system. The present study identifies such differences with respect to the organization of centrifugal neurons to the lamina. We also identify in both species neurons in the lamina that have hitherto not been identified in crustaceans and we draw specific comparisons between the layered organization of the grapsoid lamina and layered laminas of insects. PMID:19123235

  19. Neural organization of first optic neuropils in the littoral crab Hemigrapsus oregonensis and the semiterrestrial species Chasmagnathus granulatus.

    PubMed

    Sztarker, Julieta; Strausfeld, Nicholas; Andrew, David; Tomsic, Daniel

    2009-03-10

    Crustaceans are among the most extensively distributed arthropods, occupying many ecologies and manifesting a great variety of compound eye optics; but in comparison with insects, relatively little is known about the organization and neuronal morphologies of their underlying optic neuropils. Most studies, which have been limited to descriptions of the first neuropil--the lamina--suggest that different species have approximately comparable cell types. However, such studies have been limited with regard to the types of neurons they identify and most omit their topographic relationships. It is also uncertain whether similarities, such as they are, are independent of visual ecologies. The present account describes and compares the morphologies and dispositions of monopolar and other efferent neurons as well as the organization of tangential and smaller centrifugal neurons in two grapsoid crabs, one from the South Atlantic, the other from the North Pacific. Because these species occupy significantly disparate ecologies we ask whether this might be reflected in differences of cell arrangements within the most peripheral levels of the visual system. The present study identifies such differences with respect to the organization of centrifugal neurons to the lamina. We also identify in both species neurons in the lamina that have hitherto not been identified in crustaceans and we draw specific comparisons between the layered organization of the grapsoid lamina and layered laminas of insects.

  20. Fibre Optic Probes For Ophthalmology

    NASA Astrophysics Data System (ADS)

    Romaniuk, Ryszard S.

    1986-09-01

    One of the most interesting fields of application of optical fibre technology is the medicine. Among other medical disciplines the field of ophthalmology is very interesting for these applications because of optical character of the organ of vision. After some remarks of a general nature, and concerning the needs of modern ophthalmology, we will review here our trials to apply optical fibre devices for the optical surgery, therapy and diagnosis in the ophthalmology. The devices include: optical fibre illuminators for the applications with operational probes (crioprobes, termal probes, a vitrotom etc.) and some of the diagnostic equipment (like Goldman lens etc.), optical fibre gradient microoptics for delivering of a laser beam to the appropriate internal structures of the eyeglobe, optical fibre lacrimaloscope for the screening of the lacrimal ducts and another one for the orbit. A general conception of the multitask fibre optic microprobe fcr ophthalmological applications - operations and diagnosis/1/ - concludes the work.