The Antarctic Ozone Hole.

ERIC Educational Resources Information Center

Stolarski, Richard S.

1988-01-01

Discusses the Airborne Antarctic Ozone Experiment (1987) and the findings of the British Antarctic Survey (1985). Proposes two theories for the appearance of the hole in the ozone layer over Antarctica which appears each spring; air pollution and natural atmospheric shifts. Illustrates the mechanics of both. Supports worldwide chlorofluorocarbon…

Southern America stratospheric ozone variation during the last decade (1996-2005)

NASA Astrophysics Data System (ADS)

Imai, T.; Martin, I.; Iha, K.; Souza, S.

Stratospheric ozone variation in the last decade reveals important dynamics of environmental areas in Brazil possible to be correlated with natural disasters like droughts in the Amazon region and the first hurricane observed in Santa Catarina at sea temperatures bellow 22 r C in South America A team of 74 ozone specialists lead by Prof Fahey from 1965 to 2001 elaborated a very well known graphic The graphic shows that the global ozone remained constant from 1965 to 1980 with 3 000 megatons of Global Ozone when it started to quickly decline in approximately 3 or 80 megatons per year In 2001 more than 50 of the ozone was depleted IPCC specialists recognize the ozone depletion of Fahey studies in the IPCC 2001 8-1 decision the Climate Change and the Ozone Depletion In 2002 Fahey s works went through a deep methodological conference being approved by 44 more specialists in Atmospheric Chemistry in Les Diabretes Switzerland The ozone hole after 1985 reached about 27 millions km 2 or 5 of the surface of the Planet and there practically all the stratospheric ozone annually disappeared in the beginning of October Projecting these figures until 2005 we reached 70 when Katrina Hurricane and Amazons River drought happens and in 2015 the depletion will reach 100 But between 2003 and 2005 the IPCC using the same graphic and exchanging the annual loss of ozone quota for deviation specialist starts saying that the problem will be solved in 2050 That the biggest deviation of --5 was in 1993

On the Size of the Antarctic Ozone Hole

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, Eric R.; Kawa, S. Randolph

2002-01-01

The Antarctic ozone hole is a region of extremely large ozone depletion that is roughly centered over the South Pole. Since 1979, the area coverage of the ozone hole has grown from near zero size to over 24 Million sq km. In the 8-year period from 1981 to 1989, the area expanded by 18 Million sq km. During the last 5 years, the hole has been observed to exceed 25 Million sq km over brief periods. In the spring of 2002, the size of the ozone hole barely reached 20 Million sq km for only a couple of days. We will review these size observations, the size trends, and the interannual variability of the size. The area is derived from the area enclosed by the 220 DU total ozone contour. We will discuss the rationale for the choice of 220 DU: 1) it is located near the steep gradient between southern mid-latitudes and the polar region, and 2) 220 DU is a value that is lower than the pre-1979 ozone observations over Antarctica during the spring period. The phenomenal growth of the ozone hole was directly caused by the increases of chlorine and bromine compounds in the stratosphere. In this talk, we will show the relationship of the ozone hole's size to the interannual variability of Antarctic spring temperatures. In addition, we will show the relationship of these same temperatures to planetary-scale wave forcings.

A Review of Atmospheric Ozone and Current Thinking on the Antarctic Ozone Hole.

DTIC Science & Technology

1987-01-01

UNIVERSITY OF CALIFORNIA 0 A Review of Atmospheric ozone and Current Thinking on the Antartic Ozone Hole A thesis submitted in partial satisfaction of the...4. TI TLE (Pit 5,1tlfie) S. TYPE OF REPORT & PFRIOO COVERED A Review of Atmospheric Ozone and Current THESIS/DA/;J.At1AAU00 Thinking on the Antartic ...THESIS A Review of Atmospheric Ozone and Current Thinking on the Antartic Ozone Hole by Randolph Antoine Fix Master of Science in Atmospheric Science

The Antarctic ozone hole

NASA Technical Reports Server (NTRS)

Stolarski, Richard S.

1988-01-01

Processes that may be responsible for the thinning in the ozone layer above the South Pole are described. The chlorine catalytic cycle which destroys ozone is described, as are the major types of reactions that are believed to interfere with this cycle by forming chlorine reservoirs. The suspected contributions of polar stratospheric clouds to these processes are examined. Finally, the possibility that the ozone hole may be due more to a shift in atmospheric dynamics than to chemical destruction is addressed.

The Antarctic Ozone Hole: An Update

NASA Technical Reports Server (NTRS)

Douglass, Anne R.; Newman, Paul A.; Solomon, Susan

2014-01-01

The stratospheric ozone hole, an annual occurrence during austral spring, is caused by heterogeneous conversion of hydrogen chloride and chlorine nitrate to chlorine radicals. These reactions take place of polar stratospheric cloud particles in the cold, isolate Antarctic winter vortex. The chlorine radicals participate in chemical reactions that rapidly deplete ozone when sunlight returns at the end of polar night. International agreements eliminated production of the culprit anthropogenic chlorofluorocarbons in the late 1990s, but due to their long stratospheric lifetime (50-100 years), the ozone hole will continue its annual appearance for years to come.

What Controls the Size of the Antarctic Ozone Hole?

NASA Technical Reports Server (NTRS)

Bhartia, P. K. (Technical Monitor); Newman, Paul A.; Kawa, S. Randolph; Nash, Eric R.

2002-01-01

The Antarctic ozone hole is a region of extremely large ozone depletion that is roughly centered over the South Pole. Since 1979, the area coverage of the ozone hole has grown from near zero size to over 24 Million square kilometers. In the 8-year period from 1981 to 1989, the area expanded by 18 Million square kilometers. During the last 5 years, the hole has been observed to exceed 25 Million square kilometers over brief periods. We will review these size observations, the size trends, and the interannual variability of the size. The area is derived from the area enclosed by the 220 DU total ozone contour. We will discuss the rationale for the choice of 220 DU: 1) it is located near the steep gradient between southern mid-latitudes and the polar region, and 2) 220 DU is a value that is lower than the pre- 1979 ozone observations over Antarctica during the spring period. The phenomenal growth of the ozone hole was directly caused by the increases of chlorine and bromine compounds in the stratosphere. In this talk, we will show the relationship of the ozone hole's size to the interannual variability of Antarctic spring temperatures. In addition, we will show the relationship of these same temperatures to planetary-scale wave forcings.

Causes and effects of a hole. [in Antarctic ozone layer

NASA Technical Reports Server (NTRS)

Margitan, J. J.

1987-01-01

Preliminary results from the U.S. National Ozone Expedition (NOZE) to Antarctica are reviewed. The NOZE ozonesonde measurements showed significant vertical structure in the hole, with 80 percent depletion in some of the 1 km layers but only 20 percent in adjacent layers. The depletion was confined to the 12-20 km region, beginning first at higher altitude and progressing downward. This is strong evidence against the theory that the ozone hole is due to solar activity producing odd nitrogen at high altitudes which is transported downwards, leading to enhanced odd-nitrogen catalytic cycles that destroy ozone. Nitrous oxide data show unusually low concentrations within the polar vortex, which is evidence against the theory that the hole is caused by a purely dynamical mechanism in which rising air motions within the polar vortex lead to reduced column densities of ozone. It is tentatively concluded that a chemical mechanism involving man-made chlorofluorocarbons is the likely cause of ozone depletion in the hole.

Tropospheric Ozone Pollution Transport Traced from the TOMS (Total Ozone Mapping Spectrometer) Instrument During the Nashville-1999 Campaign

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Frolov, A. D.; Hudson, R. D.; Witte, J. C.; Einaudi, Franco (Technical Monitor)

2000-01-01

Over the past several years, we have developed two new tropospheric ozone retrievals from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMS-direct method [("TDOT" = TOMS Direct Ozone in the Troposphere; Frolov et al., 2000] represents a new algorithm that uses TOMS radiances directly (i.e., not previously processed for TOMS ozone) to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution. These events tend to occur in certain meteorological regimes. For example, mid-latitude pollution usually occurs on the backside of subtropical fronts, as low pv, usually moist air intrudes to the extra-tropics. July 1999 was a month characterized by robust pollution in the eastern US, with high ozone, as detected by TOMS, originating over south central states and moving up the Atlantic seaboard. This corresponds to 50-80 DU in tropospheric ozone column depth. In most cases, further transport occurred to the North Atlantic, with ozone plumes traveling to western Europe in 4-5 days. Examples of high ozone and transit across boundaries within the US, as well as US->Europe, give a regional context for model results and field measurements taken in the SE US during the Nashville-1999 campaign period. Validation of the TDOT maps is made with ozonesondes taken during that time. TDOT maps also show ozone pollution from Asia traveling to the western US in July 1999.

AIRS Ozone Burden During Antarctic Winter: Time Series from 8/1/2005 to 9/30/2005

NASA Image and Video Library

2007-07-24

The Atmospheric Infrared Sounder (AIRS) provides a daily global 3-dimensional view of Earth's ozone layer. Since AIRS observes in the thermal infrared spectral range, it also allows scientists to view from space the Antarctic ozone hole for the first time continuously during polar winter. This image sequence captures the intensification of the annual ozone hole in the Antarctic Polar Vortex. http://photojournal.jpl.nasa.gov/catalog/PIA09938

The Antarctic Ozone Hole: New Approaches for Detection of the Onset of Stratospheric Ozone Recovery

NASA Astrophysics Data System (ADS)

de Laat, J.; van Weele, M.; van der A, R. J.

2016-12-01

An important aspect of human influences on climate concerns the Antarctic ozone hole, the strong thinning of the thickness of the ozone layer during springtime over Antarctica, first observed in the early 1980s. Antarctic stratospheric ozone is expected to fully recover in the second half of the 21st century because of policy measures to eliminate emissions of ozone depleting substances. Identification of the onset of this recovery would mark an important scientific and political milestone, but has remained difficult so far owing to natural climate variability and methodological ambiguities. In this presentation, we will first give a brief introduction to methods that have been used in the past to try to identify the onset of recovery, and discuss their shortcomings and ambiguities. Secondly, we introduce and discuss a several observations-based new approaches for ozone recovery detection in the Antarctic Ozone Hole that we have developed, explain why we believe these methods are more robust than standard methods, and outline how they circumvent crucial pitfalls of the previously used methods. Finally, we present our analyses, showing that these new approaches applied to various sets of remote sensing observations provide the best evidence to date that that ozone destruction within the Antarctic Ozone Hole has significantly decreased since approximately the year 2000, and which can be attributed to concurrently decreasing ozone depleting substances.

The Antarctic Ozone Hole: Initial Results from Aura / OMI Compared with TOMS

NASA Technical Reports Server (NTRS)

McPeters, R.; Bhartia, P. K.; Newman, P.

2004-01-01

A series of TOMS instruments (on November 7 , Meteor 3, and Earth Probe) has been monitoring the annual development of the Antarctic ozone hole since the 1980s. The ozone mapping instrument on Aura, OMI, is expected to take over this record of observation from the aging Earth Probe TOMS instrument. The area of the ozone hole can be taken as a sensitive indicator of the magnitude of ozone destruction each year. The timing of initial formation of the ozone hole and its duration are sensitive to the atmospheric dynamics of the southern polar regions. The entire TOMS data record (1978 - 2004) has recently been reprocessed with the new version 8 algorithm, which includes a revised calibration. The effect has been to slightly increase ozone hole area over earlier estimates, but only by 23%. OMI (ozone monitoring instrument) on Aura is a hyperspectral imaging instrument that operates in a pushbroom mode to measure solar backscattered radiation in the ultraviolet and visible. OMI has higher spatial resolution than TOMS - 14 x 24 km versus 38 km x 38 km from TOMS. OMI has now begin mapping total column ozone on a global basis in a measurement similar to TOMS. The ozone hole measurements for 2003 are compared with those from Earth Probe TOMS.

Bromine-Chlorine Coupling in the Antarctic Ozone Hole

NASA Technical Reports Server (NTRS)

Danilin, Michael Y.; Sze, Nien-Dak; Ko, Malcolm K. W.; Rodriquez, Jose M.; Prather, Michael J.

1996-01-01

The contribution from the chlorine and bromine species in the formation of the Antarctic ozone hole is evaluated. Since chlorine and bromine compounds are of different industrial origin, it is desirable, from a policy point of view, to be able to attribute chlorine-catalyzed loss of ozone with those reactions directly involving chlorine species, and likewise for bromine-catalyzed loss. In the stratosphere, however, most of the chemical families are highly coupled, and, for example, changes in the chlorine abundance will alter the partitioninig in other families and thus the rate of ozone loss. This modeling study examines formation of the Antarctic ozone hole for a wide range of bromine concentrations (5 - 25 pptv) and for chlorine concentrations typical of the last two decades (1.5, 2.5 and 3.5 ppbv). We follow the photochemical evolution of a single parcel of air, typical of the inner Antarctic vortex (50 mbar, 70 deg. S, NO(sub y) = 2 ppbv, with Polar Stratospheric Clouds(PSC)) from August 1 to November 1. For all of these ranges of chlorine and bromine loading, we would predict a substantial ozone hole (local depletion greater than 90%) within the de-nitrified, PSC- perturbed vortex. The contributions of the different catalytic cycles responsible for ozone loss are tabulated. The deep minimum in ozone is driven primarily by the chlorine abundance. As bromine levels decrease, the magnitude of the chlorine-catalyzed ozone loss increases to take up the slack. This is because bromine suppresses ClO by accelerating the conversion of ClO an Cl2O2 back to HCI. For this range of conditions, the local relative efficiency of ozone destruction per bromine atom to that per chlorine atom (alpha-factor) ranges from 33 to 55, decreasing with increase of bromine.

CANOZE measurements of the Arctic ozone hole

NASA Technical Reports Server (NTRS)

Evans, W. F. J.; Kerr, J. B.; Fast, H.

1988-01-01

In CANOZE 1 (Canadian Ozone Experiment), a series of 20 ozone profile measurements were made in April, 1986 from Alert at 82.5 N. CANOZE is the Canadian program for study of the Arctic winter ozone layer. In CANOZE 2, ozone profile measurements were made at Saskatoon, Edmonton, Churchill and Resolute during February and March, 1987 with ECC ozonesondes. Ground based measurements of column ozone, nitrogen dioxide and hydrochloric acid were conducted at Saskatoon. Two STRATOPROBE balloon flights were conducted on February 26 and March 19, 1987. Two aerosol flights were conducted by the University of Wyoming. The overall results of this study will be reported and compared with the NOZE findings. The results from CANOZE 3 in 1988, are also discussed. In 1988, as part of CANOZE 3, STRATOPROBE balloon flights were conducted from Saskatchewan on January 27 and February 13. A new lightweight infrared instrument was developed and test flown. A science flight was successfully conducted from Alert (82.5 N) on March 9, 1988 when the vortex was close to Alert; a good measurement of the profile of nitric acid was obtained. Overall, the Arctic spring ozone layer exhibits many of the features of the Antarctic ozone phenomenon, although there is obviously not a hole present every year. The Arctic ozone field in March, 1986 demonstrated many similarities to the Antarctic ozone hole. The TOMS imagery showed a crater structure in the ozone field similar to the Antarctic crater in October. Depleted layers of ozone were found in the profiles around 15 km, very similar to those reported from McMurdo. Enhanced levels of nitric acid were measured in air which had earlier been in the vortex. The TOMS imagery for March 1987 did not show an ozone crater, but will be examined for an ozone crater in February and March, 1988, the target date for the CANOZE 3 project.

[Changes in hemodialysis adequacy in Lithuania during 1999-2005].

PubMed

Ziginskiene, Edita; Kuzminskis, Vytautas; Sileikiene, Elvyra; Tamosaitis, Algirdas; Sirevicius, Virgilijus

2007-01-01

Despite the improvement of hemodialysis technique, mortality of chronic hemodialysis patients remains quite high. It considerably depends on dialysis adequacy. The aim of the study was to evaluate the adequacy of hemodialysis procedure and its changes in Lithuania during 1999-2005. Between 1999 and 2005 in December, all hemodialysis centers in Lithuania were annually visited, and data on the type of hemodialysis, duration of hemodialysis (hours per week), single-pool Kt/V were collected from all hemodialysis patients. The percentage of patients on bicarbonate hemodialysis sharply increased from 57.9% in 1999 to 100% in 2001 (P<0.001), and the duration of hemodialysis procedure increased (67.3% of hemodialysis patients were dialyzed 12 and more hours per week in 2005 vs. 41.3% in 1999, P<0.001). The percentage of patients who were dialyzed three times per week increased from 51% in 1999 to 77% in 2005 (P<0.001). The mean Kt/V was 0.81+/-0.53 in 1999, but it increased to 1.21+/-0.27 in 2005 (P<0.001). More than half (54%) of all hemodialysis patients in 2005 had Kt/V > or =1.2 vs. more than one-third (36%) in 1999 (P<0.001). The mean Kt/V of patients who were on dialysis three times per week was 1.25+/-0.6; two times per week, 1.30+/-0.8; and one time per week, 1.27+/-0.26 in 2003. In 2005, the results were 1.21+/-0.27, 1.22+/-0.26, and 1.16+/-0.29, respectively (P>0.05). CONCLUSIONS. 1. The improvement of the quality of hemodialysis was observed in Lithuania during 1999-2005: a) from 2001, patients received only bicarbonate hemodialysis; b) weekly duration of hemodialysis increased; c) Kt/V improved. 2. Despite the improvement of hemodialysis quality, it is not optimal yet and is associated with insufficient duration of hemodialysis.

Observations of chlorine monoxide over Scott Base, Antarctica, during the ozone hole, 1996-2005

USGS Publications Warehouse

Connor, Brian; Solomon, Philip; Barrett, James; Mooney, Thomas; Parrish, Alan

2007-01-01

We report observations of chlorine monoxide, ClO, in the lower stratosphere, made from Scott Base (77.85º S, 166.77º E) in springtime during each year, 1996-2005. The ClO amounts in the atmosphere are retrieved from remote measurements of microwave emission spectra. ClO column densities of up to about 2.5 × 1015 cm-2 are recorded during September, when chlorine is present in chemically active forms due to reactions on the surface of Polar Stratospheric Cloud (PSC) particles. Maximum mixing ratios of ClO are approximately 2 ppbv. The annual average of ClO column density during the activation period is anticorrelated with similar averages of ozone column measured at nearby Arrival Heights, with correlation coefficient of –0.81, and with averages of ozone mass integrated over the entire polar region, with similar correlation coefficients. There was a substantial decrease in ClO amounts during 2002-2004. There has been no systematic change in the timing of chlorine deactivation attributable to secular change in the Antarctic vortex

Selected Measurements of Total Arctic Column Ozone Amounts from Aura Ozone Monitoring Instrument, 2004-2005 Arctic Winter

NASA Image and Video Library

2005-06-02

Images from the Ozone Monitoring Instrument onboard NASA Aura spacecraft shows the average total column ozone during the months of January and March, and the total column ozone on the single day of 11 March, 2005.

Does coupled ocean enhance ozone-hole-induced Southern Hemisphere circulation changes?

NASA Astrophysics Data System (ADS)

Son, S. W.; Han, B. R.; Kim, S. Y.; Park, R.

2017-12-01

The ozone-hole-induced Southern Hemisphere (SH) circulation changes, such as poleward shift of westerly jet and Hadley cell widening, have been typically explored with either coupled general circulation models (CGCMs) prescribing stratospheric ozone or chemistry-climate models (CCMs) prescribing surface boundary conditions. Only few studies have utilized ocean-coupled CCMs with a relatively coarse resolution. To better quantify the role of interactive chemistry and coupled ocean in the ozone-hole-induced SH circulation changes, the present study examines a set of CGCM and CCM simulations archived for the Coupled Model Intercomparison Project phase 5 (CMIP5) and CCM initiative (CCMI). Although inter-model spread of Antarctic ozone depletion is substantially large especially in the austral spring, both CGCMs with relatively simple ozone chemistry and CCMs with fully interactive comprehensive chemistry reasonably well reproduce long-term trends of Antarctic ozone and the associated polar-stratospheric temperature changes. Most models reproduce a poleward shift of SH jet and Hadley-cell widening in the austral summer in the late 20th century as identified in reanalysis datasets. These changes are quasi-linearly related with Antarctic ozone changes, confirming the critical role of Antarctic ozone depletion in the austral-summer zonal-mean circulation changes. The CGCMs with simple but still interactive ozone show slightly stronger circulation changes than those with prescribed ozone. However, the long-term circulation changes in CCMs are largely insensitive to the coupled ocean. While a few models show the enhanced circulation changes when ocean is coupled, others show essentially no changes or even weakened circulation changes. This result suggests that the ozone-hole-related stratosphere-troposphere coupling in the late 20th century may be only weakly sensitive to the coupled ocean.

Long-term changes in ozone mini-hole event frequency over the Northern Hemisphere derived from ground-based measurements

NASA Astrophysics Data System (ADS)

Krzycin, Janusz W.

2002-10-01

Decadal changes of ozone mini-hole event appearance over the Northern Hemisphere midlatitudes are examined based on daily total ozone data from seven stations having long records (four decades or more) of ozone observations. The various threshold methods for accepting and rejecting the ozone minima as mini-holes are examined. Mini-hole event activity is seen to be rather stable when averaged over a decadal time scale if the mini-holes are selected as large negative departures (exceeding 20%) relative to the moving long-term total ozone reference. The results are compared with a previous ozone mini-hole climatology derived from satellite data (TOMS measurements on board the Nimbus-7 satellite for the period 1978-93). A nonlinear statistical model (MARS), which takes into account various total ozone dynamical proxies (from NCEP-NCAR reanalysis), is used to study dynamical factors responsible for the ozone extremes over Arosa in the period 1950-99. The model explains as much as 95% of the total variance of the ozone extremes. The model-observation differences averaged over the decadal intervals are rather smooth throughout the whole period analysed. It is suggested that the short-term dynamical processes controlling the appearance of ozone extremes influenced the ozone field in a similar way before and after the onset of abrupt ozone depletion in the early 1980s. The analysis of the ozone profile and the tropopause pressure (from the ozonesondings over Hohenpeissenberg, 1966-99) during mini-hole events shows 60% ozone reduction in the lower stratosphere and an approximately 50 hPa upward shift of the thermal tropopause there.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

NASA Astrophysics Data System (ADS)

Fernandez, Rafael Pedro; Kinnison, Douglas E.; Lamarque, Jean-Francois; Tilmes, Simone; Saiz-Lopez, Alfonso

2017-04-01

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSLBr) enhances stratospheric ozone depletion. Based on a dual set of 1960-2100 coupled chemistry-climate simulations (i.e. with and without VSLBr), we show that the maximum Antarctic ozone hole depletion increases by up to 14% when natural VSLBr are considered, in better agreement with ozone observations. The impact of the additional 5 pptv VSLBr on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of 5 million km2, which is equivalent in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSLBr in CAM-Chem does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affect the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by year 2070, and indicates that natural VSLBr chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. This work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.

Ozone in Lombardy: Years 1998-1999

NASA Astrophysics Data System (ADS)

Sesana, L.; Begnini, S.; Toscani, D.; Facchini, U.; Balasso, A.; Borelli, P.

2003-11-01

Photochemical pollutants, especially ozone, have reached very high levels in Lombardy in recent years, with peaks of up to 150 ppb in late spring and summer. Lombardy, lying on the Po Plain, supports a large number of cities and industries and these, along with heavy traffic, produce copious amounts of primary pollutants such as nitrogen oxides and numerous volatile organic compounds. Furthermore, the peculiar orography of this region fosters the stagnation of air masses on a basin-scale and the presence of diurnal breezes towards northern areas, along with the evolution of the Mixing Layer, spread the polluted air masses over a large territory. Numerous stations in Lombardy give the concentrations of ozone and of nitrogen oxides. In this paper, ozone measurements carried out at the plain area around Milan and at pre-alpine sites in the spring and summer 1998 and 1999 will be shown and discussed, focusing on the months of May and July. The study of temporal and spatial behaviour of ozone goes hand in hand with the analysis of the Boundary Layer's evolution. A number of radon stations were operating in Milan and in other sites in Lombardy. Measurements of atmospheric concentrations of radon yield an index of atmospheric stability, of the formation of thermal inversion, of convective turbulence, and of the movement of air masses, and hence they are very relevant to the understanding of the conditions of atmospheric pollutants.

AIRS Ozone Burden During Antarctic Winter: Time Series from 8/1/2005 to 9/30/2005

NASA Technical Reports Server (NTRS)

2007-01-01

[figure removed for brevity, see original site] Click on the image for movie of AIRS Ozone Burden During Antarctic Winter

AIRS provides a daily global 3-dimensional view of Earth's ozone layer. Since AIRS observes in the thermal infrared spectral range, it also allows scientists to view from space the Antarctic ozone hole for the first time continuously during polar winter. This image sequence captures the intensification of the annual ozone hole in the Antarctic Polar Vortex.

The Atmospheric Infrared Sounder Experiment, with its visible, infrared, and microwave detectors, provides a three-dimensional look at Earth's weather. Working in tandem, the three instruments can make simultaneous observations all the way down to the Earth's surface, even in the presence of heavy clouds. With more than 2,000 channels sensing different regions of the atmosphere, the system creates a global, 3-D map of atmospheric temperature and humidity and provides information on clouds, greenhouse gases, and many other atmospheric phenomena. The AIRS Infrared Sounder Experiment flies onboard NASA's Aqua spacecraft and is managed by NASA's Jet Propulsion Laboratory, Pasadena, Calif., under contract to NASA. JPL is a division of the California Institute of Technology in Pasadena.

Column NO2-total ozone-stratospheric temperature relationships associated with the Arctic and Antarctic ozone holes

NASA Astrophysics Data System (ADS)

Aheyeva, Viktoryia; Gruzdev, Aleksandr; Grishaev, Mikhail

Data of ground-based measurements of NO2 column contents are analyzed to study winter-spring NO2 anomalies associated with negative anomalies in column ozone and stratospheric temperature. Episodes of significant decrease in column NO2 contents in the winter-spring period of 2011 in the northern hemisphere (NH) were detected at European and Siberian stations of Zvenigorod (55.7°N, Moscow Region) and Tomsk (56.5°N, West Siberia) in the middle latitudes, Harestua (60.2°N), Sodankyla (67.4°N, both in North Europe), and Zhigansk (66.8°N, East Siberia) in the high latitudes, and at the Arctic station of Scoresbysund (70.5°N, Greenland). All the stations, except Tomsk, are a part of the Network of the Detection of Atmospheric Composition Change (NDACC), and the data are accesses at http://ndacc.org. The decrease in NO2 is generally accompanied by total ozone and stratospheric temperature decrease and is shown to be caused by the transport of stratospheric air from the region of the ozone hole observed that season in the Arctic. Overpass total ozone data from Giovanni service and radiosonde data were used for the analysis. Although negative NO2 anomalies due to the transport from the Arctic were also observed in some other years, the anomalies in 2011 reached record magnitudes. A significant positive correlation has been found between variations in NO2 and ozone columns as well as NO2 column and stratospheric temperature during the winter-spring period of 2011, whereas the correlation is much weaker in years without Arctic ozone depletion. The correlation becomes even stronger if only episodes with significant NO2 decrease are considered. For example the correlation coefficients between NO2 and ozone columns deviations are about 0.9 for Zvenigorod and Scoresbysund. Correlation coefficients between variations in column NO2 and total ozone and stratospheric temperature as well as coefficients of regression of NO2 on ozone and temperature in the winter-spring period of

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

NASA Astrophysics Data System (ADS)

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean-Francois; Tilmes, Simone; Saiz-Lopez, Alfonso

2017-02-01

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSLBr) enhances stratospheric ozone depletion. Based on a dual set of 1960-2100 coupled chemistry-climate simulations (i.e. with and without VSLBr), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSLBr are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSLBr on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ˜ 5 million km2, which is equivalent in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSLBr in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSLBr chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. This work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean -Francois

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSL Br) enhances stratospheric ozone depletion. Based on a dual set of 1960–2100 coupled chemistry–climate simulations (i.e. with and without VSL Br), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSL Br are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSL Br on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ~5 million km 2, which is equivalentmore » in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSL Br in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSL Br chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. As a result, this work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.« less

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

DOE PAGES

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean -Francois; ...

2017-02-03

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSL Br) enhances stratospheric ozone depletion. Based on a dual set of 1960–2100 coupled chemistry–climate simulations (i.e. with and without VSL Br), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSL Br are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSL Br on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ~5 million km 2, which is equivalentmore » in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSL Br in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSL Br chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. As a result, this work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.« less

Hidden Homicide Increases in the USA, 1999–2005

PubMed Central

Hu, Guoqing; Webster, Daniel

2008-01-01

Prior to 1999, dramatic fluctuations in homicide rates were driven by changes in the rates of firearm homicide among men aged 15–24. Since 2000, the overall homicide rate has appeared stable, masking any changes in population subgroups. We analyzed recent trends in homicide rates by weapon, age, race, gender, state, and urbanization to determine whether the risk of victimization increased substantially during 1999–2005 for demographic subgroups. The analysis of WISQARS™ data and Wonder data from Centers for Disease Control and Prevention revealed no trend in the homicide rate nationally between 1999 and 2005; this obscured large increases in firearm homicide rates among black men aged 25–44 and among white men aged 25–34. Between 1999 and 2005, for ages 25–44 combined, the increase for black men was 31% compared with 12% for white men. Significant increases among men aged 25–44 occurred in Alabama, California, Michigan, Minnesota, Nebraska, Nevada, New Jersey, Ohio, Pennsylvania, Texas, and Washington. The firearm homicide rate increased the most in large central metropolitan areas (+32%) and large fringe metropolitan areas (+30%) for men aged 25–44. We conclude that the recent, unrecognized increases in firearm homicide among men aged 25–44, especially black men, in large metropolitan areas merit the attention of policymakers. PMID:18509760

A measurement/model comparison of ozone photochemical loss in the Antarctic ozone hole using Polar Ozone and Aerosol Measurement observations and the Match technique

NASA Astrophysics Data System (ADS)

Hoppel, Karl; Bevilacqua, Richard; Canty, Timothy; Salawitch, Ross; Santee, Michelle

2005-10-01

The Polar Ozone and Aerosol Measurement (POAM III) instrument has provided 6 years (1998 to present) of Antarctic ozone profile measurements, which detail the annual formation of the ozone hole. During the period of ozone hole formation the measurement latitude follows the edge of the polar night and presents a unique challenge for comparing with model simulations. The formation of the ozone hole has been simulated by using a photochemical box model with an ensemble of trajectories, and the results were sampled at the measurement latitude for comparison with the measured ozone. The agreement is generally good but very sensitive to the model dynamics and less sensitive to changes in the model chemistry. In order to better isolate the chemical ozone loss the Match technique was applied to 5 years of data to directly calculate ozone photochemical loss rates. The measured loss rates are specific to the high solar zenith angle conditions of the POAM-Match trajectories and are found to increase slowly from July to early August and then increase rapidly until mid-September. The Match results are sensitive to the choice of meteorological analysis used for the trajectory calculations. The ECMWF trajectories yield the smallest, and perhaps most accurate, peak loss rates that can be reproduced by a photochemical model using standard JPL 2002 kinetics, assuming reactive bromine (BrOx) of 14 pptv based solely on contributions from CH3Br and halons, and without requiring ClOx to exceed the upper limit for available inorganic chlorine of 3.7 ppbv. Larger Match ozone loss rates are found for the late August and early September period if trajectories based on UKMO and NCEP analyses are employed. Such loss rates require higher values for ClO and/or BrO than can be simulated using JPL 2002 chemical kinetics and complete activation of chlorine. In these cases, the agreement between modeled and measured loss rates is significantly improved if the model employs larger ClOOCl cross

Observational Diagnoses of Extratropical Ozone STE from 2005-2010

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Douglass, Anne R.; Witte, Jacquie C.; Kaplan, Trevor B.

2011-01-01

The transport of ozone from the stratosphere to the extratropical troposphere is an important boundary condition to tropospheric chemistry. However, previous direct estimates from models and indirect estimates from observations have poorly constrained the magnitude of ozone stratosphere-troposphere exchange (STE). In this study we provide a direct diagnosis of the extratropical ozone STE using data from the Microwave Limb Sounder on Aura and output of the MERRA reanalysis over the time period from 2005 to the present. We find that the mean annual STE is about 275 Tg yr-1 and 205 Tg yr-1 in the NH and SH, respectively. The interannual variability of the magnitude is about twice as great in the NH than the SH. This variability is dominated by the seasonal variability during the late winter and spring. A comparison of the ozone flux to the mass flux reveals that there is not a simple relationship between the two quantities. This presentation will also examine the magnitude and distribution of ozone in the lower stratosphere relative to the years of maximum and minimum ozone STE

Decending motion of particle and its effect on ozone hole chemistry

NASA Technical Reports Server (NTRS)

Iwasaka, Y.

1988-01-01

Particle descending motion is one possible process which causes ozone loss near the tropopause in the Antarctic spring. However, this particle size distribution has not yet been measured. Particle settling is an important redistribution process of the chemical constituents contained in the particles. To understand particle settling effects on the Ozone Hole, information on the size distribution and the chemical composition of the particles is necessary.

Evolution of the Antarctic polar vortex in spring: Response of a GCM to a prescribed Antarctic ozone hole

NASA Technical Reports Server (NTRS)

Boville, B. A.; Kiehl, J. T.; Briegleb, B. P.

1988-01-01

The possible effect of the Antartic ozone hole on the evolution of the polar vortex during late winter and spring using a general circulation model (GCM) is examined. The GCM is a version of the NCAR Community Climate Model whose domain extends from the surface to the mesosphere and is similar to that described on Boville and Randel (1986). Ozone is not a predicted variable in the model. A zonally averaged ozone distribution is specified as a function of latitude, pressure and month for the radiation parameterization. Rather that explicitly address reasons for the formation of the ozone hole, researchers postulate its existence and ask what effect it has on the subsequent evolution of the vortex. The evolution of the model when an ozone hole is imposed is then discussed.

Spatial, temporal, and vertical variability of polar stratospheric ozone loss in the Arctic winters 2004/2005-2009/2010

NASA Astrophysics Data System (ADS)

Kuttippurath, J.; Godin-Beekmann, S.; Lefèvre, F.; Goutail, F.

2010-10-01

The polar stratospheric ozone loss during the Arctic winters 2004/2005-2009/2010 is investigated by using high resolution simulations from the chemical transport model Mimosa-Chim and observations from Aura Microwave Limb Sounder (MLS), by applying the passive tracer technique. The winter 2004/2005 shows the coldest temperatures, highest area of polar stratospheric clouds and strongest chlorine activation in 2004/2005-2009/2010. The ozone loss diagnosed from both simulations and measurements inside the polar vortex at 475 K ranges from 0.7 ppmv in the warm winter 2005/2006 to 1.5-1.7 ppmv in the cold winter 2004/2005. Halogenated (chlorine and bromine) catalytic cycles contribute to 75-90% of the ozone loss at this level. At 675 K the lowest loss of 0.3-0.5 ppmv is computed in 2008/2009, and the highest loss of 1.3 ppmv is estimated in 2006/2007 by the model and in 2004/2005 by MLS. Most of the ozone loss (60-75%) at this level results from nitrogen catalytic cycles rather than halogen cycles. At both 475 and 675 K levels the simulated ozone and ozone loss evolution inside the vortex is in reasonably good agreement with the MLS observations. The ozone partial column loss in 350-850 K deduced from the model calculations at the MLS sampling locations inside the polar vortex ranges between 43 DU in 2005/2006 and 109 DU in 2004/2005, while those derived from the MLS observations range between 26 DU and 115 DU for the same winters. The partial column ozone depletion derived in that vertical range is larger than that estimated in 350-550 K by 19±7 DU on average, mainly due to NOx chemistry. The column ozone loss estimates from both Mimosa-Chim and MLS in 350-850 K are generally in good agreement with those derived from ground-based ultraviolet-visible spectrometer total ozone observations for the respective winters, except in 2010.

REPORT OF THE DECEMBER 15, 1999 EPA SATELLITE FORUM ON OZONE MONITORING, MAPPING AND PUBLIC OUTREACH

EPA Science Inventory

This report provides a summary of the US EPA's December 15, 1999 satellite forum on technology transfer tools for ozone monitoring, mapping, and public outreach under the EPA Environmental Monitoring for Public Access and Community Tracking (EMPACT) Program's Ozone Mapping Projec...

Tennessee's forest land area was stable 1999-2005 but early successional forest area declined

Treesearch

Christopher M. Oswalt

2008-01-01

A new analysis of the most recent (2005) annualized moving average data for Tennessee indicates that the area of forest land in the State remained stable between 1999 and 2005. Although trends in forest land area vary from region to region within the State, Tennessee neither lost nor gained forest land between 1999 and 2005. However, Tennessee had more than 2.5 times...

Stratospheric Ozone Variations Caused by Solar Proton Events between 1963 and 2005

NASA Technical Reports Server (NTRS)

Jackman, Charles H.; Fleming, Eric L.

2006-01-01

Solar proton fluxes have been measured by satellites for over forty years (1963-2005). Several satellites, including the NASA Interplanetary Monitoring Platforms (1963-1993) and the NOAA Geostationary Operational Environmental Satellites (1994-2005), have been used to compile this long-term dataset. Some solar eruptions lead to solar proton events (SPEs) at the Earth, which typically last a few days. High energy solar protons associated with SPEs precipitate on the Earth's atmosphere and cause increases in odd hydrogen (HOx) and odd nitrogen (NOy) in the polar cap regions (greater than 60 degrees geomagnetic). The enhanced HOx leads to short-lived ozone depletion (days) due to the short lifetime of HOx constituents. The enhanced NOy leads to long-lived ozone changes because of the long lifetime of the NOy family in the stratosphere and lower mesosphere. Very large SPEs occurred in 1972, 1989, 2000, 2001, and 2003 and were predicted to cause maximum total ozone depletions of 1-3%, which lasted for several months to years past the events. These long-term ozone changes caused by SPES are discussed.

Tropospheric ozone variability over Singapore from August 1996 to December 1999

NASA Astrophysics Data System (ADS)

Yonemura, S.; Tsuruta, H.; Maeda, T.; Kawashima, S.; Sudo, S.; Hayashi, M.

Vertical ozone profiles over Singapore (lat 1°20'N, long 103°53'E) have been monitored by ozonesondes twice a month since August 1996. We report the vertical ozone profiles over Singapore from August 1996 to the end of 1999. During this time, large ozone enhancements occurred during three periods: March-June 1997, September-November 1997, and February-May 1998. These ozone enhancements were larger over Singapore than over Malaysia. Backward trajectory analyses revealed that the enhancements during September-November 1997, and February-May 1998 were associated with biomass burning in Indonesia and Southeast Asia. Outside the three periods, ozone concentrations over Singapore differed from those over Malaysia by not more than 2.5% at altitudes of between 2.6 and 7.6 km and by not more than 12% at altitudes of between 1 and 13.5 km. The minimum ozone concentrations in the middle and the upper troposphere were about 20 ppbv and were observed when the wind was easterly from the Pacific Ocean. Ozone concentrations at the bottom of the troposphere were near zero when the wind was southerly to westerly (from the larger, more urbanized and industrialized part of Singapore and the Strait of Malacca), implying that ozone-destroying reactions were occurring with high concentrations of urban pollutants. We conclude that the ozone enhancements observed in the free troposphere resulted from the effects of extensive biomass burning combined with the modified circulation (suppressed convection of maritime air masses) that occurs during El Niño events.

A chemical definition of the boundary of the Antarctic ozone hole

NASA Technical Reports Server (NTRS)

Proffitt, M. H.; Powell, J. A.; Tuck, A. F.; Fahey, D. W.; Kelly, K. K.; Krueger, A. J.; Schoeberl, M. R.; Gary, B. L.; Margitan, J. J.; Chan, K. R.

1989-01-01

A program designed to study the Antarctic ozone hole using ER-2 high-altitude and DC-8 aircraft was conducted out of Punta Arenas, Chile during August 17-September 22, 1987. Graphs are presented of ozone and chlorine monoxide when crossing the boundary of the chemically perturbed region on August 23 and on September 21. Interpretations of ClO, H2O, and N2O measurements are presented, indicating ongoing diabetic cooling and advective poleward transport across the boundary.

TRANSPORT, RADIATIVE, AND DYNAMICAL EFFECTS OF THE ANTARCTIC OZONE HOLE: A GFDL "SKYHI" MODEL EXPERIMENT

EPA Science Inventory

The GFDL 'SKYHI' general circulation model has been used to simulate the effect of the Antarctic "ozone hole" phenomenon on the radiative and dynamical environment of the lower stratosphere. oth the polar ozone destruction and photochemical restoration chemistries are calculated ...

Numerical simulation of ozone loss in the Antarctic winters 2005-2008: Comparison with MLS measurements

NASA Astrophysics Data System (ADS)

Kuttippurath, J.; Godin-Beekmann, S.; Lefevre, F.; Pazmino, A.

2009-04-01

The ozone loss in the recent Antarctic winters were high enough to pause a lag in the recovery phase of stratospheric ozone above this continent. We quantitatively examine the extent of ozone loss variability during 2005-2008 with simulations from a high resolution chemical transport model, MIMOSA-CHIM. The simulated results are cross-checked with the observed loss from Microwave Limb Sounder (MLS) satellite sensor data. This study uses the vortex averaged data at the potential temperature level 475 K from both MIMOSA and MLS to estimate the ozone loss by transport method. Minimum temperatures calculated from ECMWF analyzes over 50-90°S at 475 K are coldest in 2008 during June-July and in 2006 during September-November. In general, Antarctic winters experience NAT temperatures from mid-May to mid-October and ICE temperatures from June to September. Due to the saturation of chemical ozone loss, the year-to-year difference in temperatures do not have a large effect. The estimated cumulative ozone loss from MIMOSA-CHIM at 475 K is 3.2 in 2005, 2.9 in 2006, 2.8 in 2007 and 2.0 ppm in 2008. The measured cumulative loss in the respective years also show similar values: respectively 3.3, 3.2, 2.8 and 2.2 ppm in 2005, 2006, 2007 and 2008. Both data sets show the same loss trend, as the cumulative loss is highest in 2005 followed by 2006 and the lowest in 2008, and are in accord with the chlorine activation and denitrification found in the respective winters. The simulations in 2008 lack adequate diabatic descent as assessed from tracer simulations in comparison with measurements. This eventually produced relatively lower values for ozone loss in 2008 in both data sets even though the observed chlorine activation was found to be similar to previous winters.

Australian Students' Appreciation of the Greenhouse Effect and the Ozone Hole.

ERIC Educational Resources Information Center

Fisher, Brian

1998-01-01

Examines students' explanations of the greenhouse effect and the hole in the ozone layer, using a life-world and scientific dichotomy. Illuminates ideas often expressed in classrooms and sheds light on the progression in students' developing powers of explanation. Contains 17 references. (DDR)

The Antarctic Ozone Hole

ERIC Educational Resources Information Center

Jones, Anna E.

2008-01-01

Since the mid 1970s, the ozone layer over Antarctica has experienced massive destruction during every spring. In this article, we will consider the atmosphere, and what ozone and the ozone layer actually are. We explore the chemistry responsible for the ozone destruction, and learn about why conditions favour ozone destruction over Antarctica. For…

An Assessment of the Ozone Loss During the 1999-2000 SOLVE Campaign

NASA Technical Reports Server (NTRS)

Schoeberl, M. R.; Newman, P. A.; Lait, L. R.; McGee, T.; Burris, J.; Browell, E. V.; Richard, E.; VonderGathen, P.; Beveliaqua, R.; Mikkelsen, I. S.;

Influence of equatorial QBO (quasi-biennial oscillation) and SST (sea-surface temperature) on polar total ozone, and the 1990 Antarctic ozone hole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angell, J.K.

1990-09-01

Based on data through 1989, comparisons are made between the variation of total ozone at Resolute, Canada (75{degree}N) and South Pole, and the variation of low-stratospheric temperature at Singapore (reflecting the equatorial QBO) and SST in eastern equatorial Pacific (reflecting the ENSO phenomenon). Total-ozone variations at Resolute have been more closely related to the QBO, whereas the total-ozone variations at South Pole appear to have been almost equally related to QBO and SST. When the average of 50 mb and 30 mb June-July-August (JJA) values of Singapore temperature ({bar T}) increased from one year to the next, the decrease inmore » South Pole springtime total ozone for the same years averaged 21 {plus minus} 14% greater than when {bar T} decreased. When the JJA values of equatorial SST increased from one year to the next, the decrease in South Pole springtime total ozone for the same years averaged 18 {plus minus} 12% greater than when SST decreased. In the 6 cases when JJA values of both Singapore {bar T} and equatorial SST increased from one year to the next, the spring values of South Pole total ozone have decreased, whereas in the 6 cases when both {bar T} and SST decreased from one year to the next, South Pole total ozone has increased. Both Singapore {bar T} and equatorial SST will probably be warmer in JJA of 1990 than they were in JJA of 1989 suggesting, based on these previous relations, an even deeper Antarctic ozone hole in 1990 than in 1989 and ending the biennial variation in depth of the hole of the last 6 years.« less

The Changing South Polar Cap of Mars: 1999-2005

NASA Technical Reports Server (NTRS)

2005-01-01

13 July 2005 The south polar residual cap of Mars is composed of layered, frozen carbon dioxide. In 1999, the Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) showed that the carbon dioxide layers have been eroded to form a variety of circular pits, arcuate scarps, troughs, buttes, and mesas. In 2001, MOC images designed to provide repeated views of the areas imaged in 1999 -- with the hope of creating stereo (3-D) images, so that the height of scarps and depth of pits could be measured -- showed that the scarps had retreated, pits enlarged, and buttes and mesas shrank. Only carbon dioxide is volatile enough in the martian environment to have caused such dramatic changes -- the scarps were seen to retreat at an average rate of 3 meters (about 3 yards) per Mars year. Most of the scarp retreat occurs during the southern summer season; in some areas the scarps move as much as 8 meters, in others, only 1 meter per Mars year.

Three Mars years have now elapsed since MOC first surveyed the south polar cap in 1999. Over the past several months, MGS MOC has been re-imaging areas that were seen in 1999, 2001, and 2003, to develop a detailed look at how the landscape has been changing. This animated GIF provides an example of the dramatic changes that have occurred during the past three martian years. The first image, a sub-frame of M09-05244, was acquired on 21 November 1999. The second image, a sub-frame of S06-00973, was obtained on 11 May 2005. The animation shows the changes that have occurred between 1999 and 2005. Each summer, the cap has lost more carbon dioxide. This may mean that the carbon dioxide content of the martian atmosphere has been increasing, bit by very tiny little bit, each of the years that MGS has been orbiting the red planet. These observations also imply that there was once a time, in the not-too-distant past (because there are no impact craters on the polar cap), when the atmosphere was somewhat thinner and colder, to permit the layers

Arctic chemical Ozone Loss Observed by the AROTEL Instrument during the SOLVE Campaign, December 1999 - March 2000

NASA Technical Reports Server (NTRS)

McGee, Thomas J.; Burris, John F.; Hoegy, Walter; Newman, Paul; Heaps,William; Silbert, Donald; Lait, Leslie; Sumnicht, Grant; Twigg, Laurence

2000-01-01

During the winter of 1999-2000, the AROTEL instrument was deployed on the NASA DC-8 at Kiruna, Sweden for the SAGE III Ozone Loss Validation Experiment (SOLVE). Measurements of ozone, temperature and aerosols were made on 18 local science flights from December to March. Extremely low temperatures were observed throughout most of the Arctic vortex and polar stratospheric clouds were observed throughout the Arctic area during January. Significant ozone loss was measured after the sun began to rise on the vortex area in February. Ozone mixing ratios as low as 800 ppbv were observed during flights in March.

HISTORY OF TROPOSPHERIC OZONE FOR THE SAN BERNARDINO MOUNTAINS OF SOUTHERN CALIFORNIA, 1963-1999

EPA Science Inventory

A historical database of hourly O3 concentrations for Crestline, California in 1963-1999 has been developed based on all available representative oxidant/ozone monitoring data taken since 1963. All data were obtained from the California Air Resources Board and the U.S. Departmen...

An Assessment of the Ozone Loss During the 1999-2000 SOLVE Arctic Campaign

NASA Technical Reports Server (NTRS)

Schoeberl, Mark R.; Newman, Paul A.; Lait, Leslie R.; McGee, Thomas J.; Burris, John F.; Browell, Edward V.; Grant, William B.; Richard, Eric; VonderGathen, Peter; Bevilacqua, Richard;

A major event of Antarctic ozone hole influence in southern Brazil in October 2016: an analysis of tropospheric and stratospheric dynamics

NASA Astrophysics Data System (ADS)

Dornelles Bittencourt, Gabriela; Bresciani, Caroline; Kirsch Pinheiro, Damaris; Valentin Bageston, José; Schuch, Nelson Jorge; Bencherif, Hassan; Paes Leme, Neusa; Vaz Peres, Lucas

2018-03-01

The Antarctic ozone hole is a cyclical phenomenon that occurs during the austral spring where there is a large decrease in ozone content in the Antarctic region. Ozone-poor air mass can be released and leave through the Antarctic ozone hole, thus reaching midlatitude regions. This phenomenon is known as the secondary effect of the Antarctic ozone hole. The objective of this study is to show how tropospheric and stratospheric dynamics behaved during the occurrence of this event. The ozone-poor air mass began to operate in the region on 20 October 2016. A reduction of ozone content of approximately 23 % was observed in relation to the climatology average recorded between 1992 and 2016. The same air mass persisted over the region and a drop of 19.8 % ozone content was observed on 21 October. Evidence of the 2016 event occurred through daily mean measurements of the total ozone column made with a surface instrument (Brewer MkIII no. 167 Spectrophotometer) located at the Southern Space Observatory (29.42° S, 53.87° W) in São Martinho da Serra, Rio Grande do Sul. Tropospheric dynamic analysis showed a post-frontal high pressure system on 20 and 21 October 2016, with pressure levels at sea level and thickness between 1000 and 500 hPa. Horizontal wind cuts at 250 hPa and omega values at 500 hPa revealed the presence of subtropical jet streams. When these streams were allied with positive omega values at 500 hPa and a high pressure system in southern Brazil and Uruguay, the advance of the ozone-poor air mass that caused intense reductions in total ozone content could be explained.

Stratospheric column NO2 anomalies over Russia related to the 2011 Arctic ozone hole

NASA Astrophysics Data System (ADS)

Aheyeva, Viktoryia; Gruzdev, Aleksandr; Elokhov, Aleksandr; Grishaev, Mikhail; Salnikova, Natalia

2013-04-01

We analyze data of spectrometric measurements of stratospheric column NO2 contents at mid- and high-latitude stations of Zvenigorod (55.7°N, Moscow region), Tomsk (56.5°N, West Siberia), and Zhigansk (66.8°N, East Siberia). Measurements are done in visual spectral range with zenith-viewing spectrometers during morning and evening twilights. Alongside column NO2 contents, vertical profiles of NO2 are retrieved at the Zvenigorod station. Zvenigorod and Zhigansk are the measurement stations within the Network for the Detection of Atmospheric Composition Change (NDACC). For interpretation of results of analysis of NO2 data, data of Ozone Monitoring Instrument measurements of total column ozone and rawinsonde data are also analyzed and back trajectories calculated with the help of HYSPLIT trajectory model are used. Significant negative anomalies in stratospheric NO2 columns accompanied by episodes of significant cooling of the stratosphere and decrease in total ozone were observed at the three stations in the winter-spring period of 2011. Trajectory analysis shows that the anomalies were caused by the transport of stratospheric air from the region of the ozone hole observed that season in the Arctic. Although negative NO2 anomalies due to the transport from the Arctic were also observed in some other years, the anomalies in 2011 have had record magnitudes. Analysis of NO2 vertical profiles at Zvenigorod shows that the NO2 anomaly in 2011 compared to other years anomalies was additionally contributed by the denitrification of the Arctic lower stratosphere. NO2 profiles show that a certain degree of the denitrification probably survived even after the ozone hole.

Investigations of Stratosphere-Troposphere Exchange of Ozone Derived From MLS Observations

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Schoeberl, Mark R.; Ziemke, Jerry R.

2006-01-01

Daily high-resolution maps of stratospheric ozone have been constructed using observations by MLS combined with trajectory information. These fields are used to determine the extratropical stratosphere-troposphere exchange (STE) of ozone for the year 2005 using two diagnostic methods. The resulting two annual estimates compare well with past model- and observational-based estimates. Initial analyses of the seasonal characteristics indicate that significant STE of ozone in the polar regions occurs only during spring and early summer. We also examine evidence that the Antarctic ozone hole is responsible for a rapid decrease in the rate of ozone STE during the SH spring. Subtracting the high-resolution stratospheric ozone fiom OMI total column measurements creates a high-resolution tropospheric ozone residual (HTOR) product. The HTOR fields are compared to the spatial distribution of the ozone STE. We show that the mean tropospheric ozone maxima tend to occur near locations of significant ozone STE. This suggests that STE may be responsible for a significant fraction of many mean tropospheric ozone anomalies.

Graphene Oxide by UV-Ozone Treatment as an Efficient Hole Extraction Layer for Highly Efficient and Stable Polymer Solar Cells.

PubMed

Xia, Yingdong; Pan, Yufeng; Zhang, Haijuan; Qiu, Jian; Zheng, Yiting; Chen, Yonghua; Huang, Wei

2017-08-09

The hole extraction layer has a significant impact on the achievement of high-efficiency polymer solar cells (PSCs). Here, we report an efficient approach to direct UV-ozone treatment by larger device performance enhancement employing graphene oxide (GO). The dramatic performance enhancement of PSCs with the P3HT:PCBM blend as an active layer was demonstrated by the UV-ozone treatment of GO for 30 min: best power conversion efficiency (PCE) of 4.18%, fill factor of 0.63, J sc of 10.94 mA cm -2 , and V oc of 0.61 V, which are significantly higher than those of the untreated GO (1.82%) and highly comparable PEDOT:PSS-based PSCs (3.73%). In addition, PSCs with UV-ozone-treated GO showed a longer stability than PSCs with PEDOT:PSS. The significant enhancement of PCEs of PSCs can be attributed to the fact that ozone molecules can oxidize GO into CO 2 and leave highly conductive graphene particles. We suggest that this simple UV-ozone treatment can provide an efficient method for highly efficient GO hole extraction in high-performance PSCs.

The Antarctic Ice Sheet, Sea Ice, and the Ozone Hole: Satellite Observations of how they are Changing

NASA Technical Reports Server (NTRS)

Parkinson, Claire L.

2012-01-01

Antarctica is the Earth's coldest and highest continent and has major impacts on the climate and life of the south polar vicinity. It is covered almost entirely by the Earth's largest ice sheet by far, with a volume of ice so great that if all the Antarctic ice were to go into the ocean (as ice or liquid water), this would produce a global sea level rise of about 60 meters (197 feet). The continent is surrounded by sea ice that in the wintertime is even more expansive than the continent itself and in the summertime reduces to only about a sixth of its wintertime extent. Like the continent, the expansive sea ice cover has major impacts, reflecting the sun's radiation back to space, blocking exchanges between the ocean and the atmosphere, and providing a platform for some animal species while impeding other species. Far above the continent, the Antarctic ozone hole is a major atmospheric phenomenon recognized as human-caused and potentially quite serious to many different life forms. Satellites are providing us with remarkable information about the ice sheet, the sea ice, and the ozone hole. Satellite visible and radar imagery are providing views of the large scale structure of the ice sheet never seen before; satellite laser altimetry has produced detailed maps of the topography of the ice sheet; and an innovative gravity-measuring two-part satellite has allowed mapping of regions of mass loss and mass gain on the ice sheet. The surrounding sea ice cover has a satellite record that goes back to the 1970s, allowing trend studies that show a decreasing sea ice presence in the region of the Bellingshausen and Amundsen seas, to the west of the prominent Antarctic Peninsula, but increasing sea ice presence around much of the rest of the continent. Overall, sea ice extent around Antarctica has increased at an average rate of about 17,000 square kilometers per year since the late 1970s, as determined from satellite microwave data that can be collected under both light and

Ozone Loss From Quasi-Conservative Coordinate Mapping During the 1999-2000 SOLVE Campaign

NASA Technical Reports Server (NTRS)

Lait, L. R.; Schoeberl, M. R.; Newman, P. A.; McGee, T.; Burris, J.; Browell, E. V.; Richard, E.; Braathen, G. O.; Bojkov, B. R.; Goutail, F.;

Surface and Tropospheric Ozone Profile Variability (1999-2014) at the TOLNet Site of Table Mountain, California

NASA Astrophysics Data System (ADS)

Granados-Muñoz, M. J.; Leblanc, T.

2015-12-01

Ozone in the lower troposphere acts as an air pollutant affecting human health and vegetation. Tropospheric ozone sources and variability are not yet fully identified or understood and recent studies reveal the importance of increasing the number of tropospheric ozone profiling stations and long term measurements. As part of the international monitoring network NDACC, and the U.S.-based network TOLNet, a differential absorption lidar has been performing tropospheric ozone measurements (3-20 km) at the JPL Table Mountain Facility (TMF, California) since 1999, and surface measurements have been performed since 2013 with a UV photometric analyzer. Because of the site's geolocation and high elevation, background tropospheric ozone, unaffected by the boundary layer dynamics and local anthropogenic emissions of ozone precursors, is usually expected. However, transboundary ozone contributions such as stratospheric intrusions and Asian pollution episodes are frequently detected. In this study, a statistical analysis of the 14-year lidar profiles and the 2.5-year surface data is presented. Seasonal, interannual and diurnal variability and its possible causes (e.g. El Nino/La Nina events, North American Monsoon) are investigated. Together with the high elevation surface data gathered at TMF, surface data from ARB stations nearby are analyzed to understand the lowermost tropospheric ozone variability component. The frequency of stratospheric intrusions and Asian pollution episodes reaching the Western U.S. is also examined in an attempt to understand the relative contribution of each process to the observed variability throughout the troposphere. The Table Mountain surface and lidar measurements are expected to contribute significantly to the emerging system of global air quality observations, and to the improvement of global and regional data assimilation and modeling.

Southern Hemisphere Additional Ozonesondes (SHADOZ) Ozone Climatology (2005-2009): Tropospheric and Tropical Tropopause Layer (TTL) Profiles with Comparisons to Omi-based Ozone Products

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Miller, Sonya K.; Tilmes, Simone; Kollonige, Debra W.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Johnson, Brian J.; Fujiwara, Masatomo; Schmidlin, F. J.; Coetzee, G. J. R.;

Southern Hemisphere Additional Ozonesondes (SHADOZ) ozone climatology (2005-2009): Tropospheric and tropical tropopause layer (TTL) profiles with comparisons to OMI-based ozone products

NASA Astrophysics Data System (ADS)

Thompson, Anne M.; Miller, Sonya K.; Tilmes, Simone; Kollonige, Debra W.; Witte, Jacquelyn C.; Oltmans, Samuel J.; Johnson, Bryan J.; Fujiwara, Masatomo; Schmidlin, F. J.; Coetzee, G. J. R.; Komala, Ninong; Maata, Matakite; Bt Mohamad, Maznorizan; Nguyo, J.; Mutai, C.; Ogino, S.-Y.; da Silva, F. Raimundo; Leme, N. M. Paes; Posny, Francoise; Scheele, Rinus; Selkirk, Henry B.; Shiotani, Masato; Stübi, René; Levrat, Gilbert; Calpini, Bertrand; Thouret, ValéRie; Tsuruta, Haruo; Canossa, Jessica Valverde; VöMel, Holger; Yonemura, S.; Diaz, Jorge AndréS.; Tan Thanh, Nguyen T.; Thuy Ha, Hoang T.

2012-12-01

We present a regional and seasonal climatology of SHADOZ ozone profiles in the troposphere and tropical tropopause layer (TTL) based on measurements taken during the first five years of Aura, 2005-2009, when new stations joined the network at Hanoi, Vietnam; Hilo, Hawaii; Alajuela/Heredia, Costa Rica; Cotonou, Benin. In all, 15 stations operated during that period. A west-to-east progression of decreasing convective influence and increasing pollution leads to distinct tropospheric ozone profiles in three regions: (1) western Pacific/eastern Indian Ocean; (2) equatorial Americas (San Cristóbal, Alajuela, Paramaribo); (3) Atlantic and Africa. Comparisons in total ozone column from soundings, the Ozone Monitoring Instrument (OMI, on Aura, 2004-) satellite and ground-based instrumentation are presented. Most stations show better agreement with OMI than they did for EP/TOMS comparisons (1998-2004; Earth-Probe/Total Ozone Mapping Spectrometer), partly due to a revised above-burst ozone climatology. Possible station biases in the stratospheric segment of the ozone measurement noted in the first 7 years of SHADOZ ozone profiles are re-examined. High stratospheric bias observed during the TOMS period appears to persist at one station. Comparisons of SHADOZ tropospheric ozone and the daily Trajectory-enhanced Tropospheric Ozone Residual (TTOR) product (based on OMI/MLS) show that the satellite-derived column amount averages 25% low. Correlations between TTOR and the SHADOZ sondes are quite good (typical r2= 0.5-0.8), however, which may account for why some published residual-based OMI products capture tropospheric interannual variability fairly realistically. On the other hand, no clear explanations emerge for why TTOR-sonde discrepancies vary over a wide range at most SHADOZ sites.

Nimbus-7 TOMS Antarctic ozone atlas: August through November, 1989

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Penn, Lanning M.; Larko, David E.; Doiron, Scott D.; Guimaraes, Patricia T.

1990-01-01

Because of the great environmental significance of ozone and to support continuing research at the Antarctic and other Southern Hemisphere stations, the development of the 1989 ozone hole was monitored using data from the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) instrument, produced in near-real-time. This Atlas provides a complete set of daily polar orthographic projections of the TOMS total ozone measurements over the Southern Hemisphere for the period August 1 through November 30, 1989. The 1989 ozone hole developed in a manner similar to that of 1987, reaching a comparable depth in early October. This was in sharp contrast to the much weaker hole of 1988. The 1989 ozone hole remained at polar latitudes as it filled in November, in contrast to other recent years when the hole drifted to mid-latitudes before disappearing. Daily ozone values above selected Southern Hemisphere stations are presented, along with comparisons of the 1989 ozone distribution to that of other years.

The 1988 Antarctic ozone monitoring Nimbus-7 TOMS data atlas

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Penn, Lanning M.; Larko, David E.; Doiron, Scott D.; Guimaraes, Patricia T.

1989-01-01

Because of the great environmental significance of ozone and to support continuing research at McMurdo, Syowa, and other Southern Hemisphere stations, the development of the 1988 ozone hole was monitored using data from the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) instrument, produced in near-real-time. This Atlas provides a complete set of daily polar orthographic projections of the TOMS total ozone measurements over the Southern Hemisphere for the period August 1 through November 17, 1988. Although total ozone in mini-holes briefly dropped below 150 DU in late August, the main ozone hole is seen to be much less pronounced than in 1987. Minimum values, observed in late September and early October 1988, were seldom less than 175 DU. Compared with the same period in 1987, when a pronounced ozone hole whose minimum value of 109 Dobson Units (DU) was the lowest total ozone ever observed, the 1988 ozone hole is displaced from the South Pole, opposing a persistent maximum with values consistently above 500 DU. Daily ozone values above selected Southern Hemisphere stations are presented, along with comparisons of the 1988 ozone distribution to that of other years.

Is the Ozone Hole over Your Classroom?

ERIC Educational Resources Information Center

Cordero, Eugene C.

2002-01-01

Reports on a survey of first year university science students regarding their understanding of the ozone layer, ozone depletion, and the effect of ozone depletion on Australia. Suggests that better teaching resources for environmental issues such as ozone depletion and global warming are needed before improvements in student understanding can be…

Analysis of TES Satellite Ozone Observations from 2005 to 2013 to Understand Global Air Pollution Transport

NASA Astrophysics Data System (ADS)

Kladar, R. M.; Cooper, O. R.

2015-12-01

To better understand the causes of ozone formation and transport, we create and analyze global satellite ozone retrieval products for ground level to upper tropospheric ozone concentrations over the years 2005 to 2013 using the Tropospheric Emission Spectrometer (TES) that rides aboard the NASA Aura satellite. Many global and regional tropospheric ozone trends are not fully understood. Observing many different pressure levels between 1000 hPa to 215 hPa, we focus on the areas where model and other observation strategies disagree, namely the Arabian Peninsula, the Australian outback, and the southern Sahara. We observe (and these areas may be experiencing) unusually high ozone concentrations. We also comment on the historically high ozone areas such as China, Northern India, western Europe, and the western and southern United States and how known phenomena compare to our observations. Many observations confirm known mechanisms of ozone formation and transport, such as the effect of the yearly monsoon cycle in South, Southeast, and East Asia. Others, such as the surprisingly high monthly average concentrations on the Arabian Peninsula and Southern Sahara, deserve more thorough investigation. Several hypotheses for these disagreement areas are put forward here. Lastly, we comment on the usefulness of the TES instrument for trends analysis and future global observations.

Extreme Events: low and high total ozone over Arosa, Switzerland

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Stübi, R.; Weihs, P.; Holawe, F.; Peter, T.; Davison, A. C.

2009-04-01

The frequency distribution of days with extreme low (termed ELOs) and high (termed EHOs) total ozone is analyzed for the world's longest total ozone record (Arosa, Switzerland - for details see Staehelin et al.,1998a,b), with new tools from extreme value theory (e.g. Coles, 2001; Ribatet, 2007). A heavy-tail focused approach is used through the fitting of the Generalized Pareto Distribution (GPD) to the Arosa time series. Asymptotic arguments (Pickands, 1975) justify the use of the GPD for modeling exceedances over a high (or below a low) enough threshold (Coles, 2001). The analysis shows that the GPD is appropriate for modeling the frequency distribution in total ozone above or below a mathematically well-defined threshold. While previous studies focused on so termed ozone mini-holes and mini-highs (e.g. Bojkov and Balis, 2001, Koch et al., 2005), this study is the first to present a mathematical description of extreme events in low and high total ozone for a northern mid-latitudes site (Rieder et al., 2009). The results show (a) an increase in days with extreme low (ELOs) and (b) a decrease in days with extreme high total ozone (EHOs) during the last decades, (c) that the general trend in total ozone is strongly determined by these extreme events and (d) that fitting the GPD is an appropriate method for the estimation of the frequency distribution of so-called ozone mini-holes. Furthermore, this concept allows one to separate the effect of Arctic ozone depletion from that of in situ mid-latitude ozone loss. As shown by this study, ELOs and EHOs have a strong influence on mean values in total ozone and the "extremes concept" could be further used also for validation of Chemistry-Climate-Models (CCMs) within the scientific community. References: Bojkov, R. D., and Balis, D.S.: Characteristics of episodes with extremely low ozone values in the northern middle latitudes 1975-2000, Ann. Geophys., 19, 797-807, 2001. Coles, S.: An Introduction to Statistical Modeling of

Association of Smoking with Body Weight in US High School Students, 1999-2005

ERIC Educational Resources Information Center

Seo, Dong-Chul; Jiang, Nan; Kolbe, Lloyd J.

2009-01-01

Objectives: To investigate the association of current smoking with body mass index (BMI) and perceived body weight among high school students in the United States. Methods: We analyzed data from the 1999-2005 Youth Risk Behavior Survey. Results: Perceived body weight and BMI were associated with adolescents' current smoking. Adjusted odds ratios…

The signs of Antarctic ozone hole recovery.

PubMed

Kuttippurath, Jayanarayanan; Nair, Prijitha J

2017-04-03

Absorption of solar radiation by stratospheric ozone affects atmospheric dynamics and chemistry, and sustains life on Earth by preventing harmful radiation from reaching the surface. Significant ozone losses due to increases in the abundances of ozone depleting substances (ODSs) were first observed in Antarctica in the 1980s. Losses deepened in following years but became nearly flat by around 2000, reflecting changes in global ODS emissions. Here we show robust evidence that Antarctic ozone has started to recover in both spring and summer, with a recovery signal identified in springtime ozone profile and total column measurements at 99% confidence for the first time. Continuing recovery is expected to impact the future climate of that region. Our results demonstrate that the Montreal Protocol has indeed begun to save the Antarctic ozone layer.

Processes Affecting Tropospheric Ozone Inferred from Ozonesonde and Other Tracer Data from the R/V R H Brown Atlantic Cruise (37N-34S) in January-February 1999

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Doddridge, B. G.; Luke, W. T.; Johnson, J. E.; Witte, J. C.; Reynolds, R. M.; Johnson, B.; Oltmans, S. J.

1999-01-01

During the Aerosols-99 trans-Atlantic cruise from Norfolk, VA, to Cape Town, South Africa, 22 ozonesondes were launched from the NOAA R/V R H Brown between 17 Jan and 6 Feb 1999, with all sondes but one reaching 30 km. A composite of ozone profiles along the transect shows high free tropospheric ozone (up to 100 ppbv at 9 km) between 5N and 20S, a coherent feature straddling either side of the ITCZ. Latitudinal variations of tropospheric ozone are interpreted using correlative measurements of surface ozone, CO, water vapor, and aerosol optical thickness (column absorbance) measured from the ship. Elevated ozone in the lower troposphere results from photochemical reactions of precursors emitted by biomass burning north of the ITCZ. However, the greatest ozone mixing ratios are in the mid-troposphere south of the ITCZ, which gives evidence of interhemispheric transport. Column-integrated tropospheric ozone, 35 DU from 0-16 km, agrees with that derived from the TOMS satellite by the modified-residual method [Thompson and Hudson, 1999]. NCEP wind fields, ship-launched radiosondes and back trajectories are consistent with a picture of recirculating air parcels centered in the tropical Atlantic region which is identified with the maximum wave-one amplitude in total ozone seen in sondes and by satellite.

Tropospheric Ozone Pollution from Space: New Views from the TOMS (Total Ozone Mapping Spectrometer) Instrument

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Hudson, Robert D.; Frolov, Alexander D.; Witte, Jacquelyn C.; Kucsera, Tom L.; Einaudi, Franco (Technical Monitor)

2000-01-01

New products from the TOMS (Total Ozone Mapping Spectrometer) >satellite instrument can resolve pollution events in tropical and mid-latitudes, Over the past several years, we have developed tropospheric ozone data sets by two methods. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMSdirect method [Hudson et at., 2000] represents a new algorithm that uses TOMS radiances to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution, Absorbing aerosols (dust and smoke; Herman et at., 1997 Hsu et al., 1999), a standard TOMS product, provide transport and/or source marker information to interpret tropospheric ozone. For the Nimbus 7/TOMS observing period (1979-1992), modified-residual TTO (tropical tropospheric ozone) appears as two maps/month at I-degree latitude 2-degree longitude resolution at a homepage and digital data are available (20S to 20N) by ftp at http://metosrv2. umd.edu/tropo/ 14y_data.d. Preliminary modified-residual TTO data from the operational Earth-Probe/TOMS (1996- present) are posted in near-real-time at the same website. Analyses with the new tropospheric ozone and aerosol data are illustrated by the following (I)Signals in tropical tropospheric ozone column and smoke amount during ENSO (El Nino-Southern Oscillation) events, e.g. 1982-1983 and the intense ENSO induced biomass fires of 1997-1998 over the Indonesian region [Thompson et a[, 2000a, Thompson and Hudson, 1999]. (2) Trends in tropospheric ozone and smoke aerosols in various tropical regions (Atlantic, Pacific, Africa, Brazil). No significant trends were found for ozone from1980-1990 [Thompson and Hudson, 19991 although smoke aerosols increased during the period [Hsu et al.,1999]. (3) Temporal and spatial offsets

On the relevance of the methane oxidation cycle to ozone hole chemistry

NASA Technical Reports Server (NTRS)

Mueller, Rolf; Crutzen, Paul J.

1994-01-01

High concentrations of active chlorine are clearly responsible for the observed ozone depletion during the Antarctic polar spring. However, the mechanism behind the activation of chlorine from the reservoirs species HCl and ClONO2 and the maintenance of extremely high levels of active chlorine after polar sunrise is less well understood. Here, we focus on the influence of the methane oxidation cycle on 'ozone hole' chemistry through its effect on HOx and ClOx radicals. We demonstrate the great potential importance of the heterogeneous reaction HCl + HOCl yields Cl2 + H2O and the gasphase reaction ClO + CH3O2 yields ClOO + CH3O under sunlight conditions in polar spring. Under these conditions, the heterogeneous reaction is the main sink for HOx radicals. Through this channel, the HCl reservoir may be almost completely depleted. The gas phase reaction may control the levels of the CH3O2 radical, provided that high levels of ClO exist. Otherwise this radical initiates a sequence of reactions leading to a considerable loss of active chlorine. Moreover, the production of HOx radicals is reduced, and thereby the efficiency of the heterogeneous reaction limited. The two reactions together may accomplish the complete conversion of HCl into active chlorine, thereby leading to a rapid destruction of ozone.

Scientific assessment of stratospheric ozone: 1989, volume 1

NASA Technical Reports Server (NTRS)

1990-01-01

A scientific review is presented of the current understanding of stratospheric ozone. There have been highly significant advances in the understanding of the impact of human activities on the Earth's protective ozone layer. There are four major findings that each heighten the concern that chlorine and bromine containing chemicals can lead to a significant depletion of stratospheric ozone: (1) Antarctic ozone hole (the weight of evidence indicates that chlorinated and brominated chemicals are responsible for the ozone hole; (2) Perturbed arctic chemistry (the same potentially ozone destroying processes were identified in the Arctic stratosphere); (3) Long term ozone decreases; and (4) Model limitations (gaps in theoretical models used for assessment studies).

A Time-Stratified Case-Crossover Study of Ambient Ozone Exposure and Emergency Department Visits for Specific Respiratory Diagnoses in California (2005–2008)

PubMed Central

Malig, Brian J.; Pearson, Dharshani L.; Chang, Yun Brenda; Broadwin, Rachel; Basu, Rupa; Green, Rochelle S.; Ostro, Bart

2015-01-01

Background: Studies have explored ozone’s connection to asthma and total respiratory emergency department visits (EDVs) but have neglected other specific respiratory diagnoses despite hypotheses relating ozone to respiratory infections and allergic responses. Objective: We examined relationships between ozone and EDVs for respiratory visits, including specifically acute respiratory infections (ARI), asthma, pneumonia, chronic obstructive pulmonary disease (COPD), and upper respiratory tract inflammation (URTI). Methods: We conducted a multi-site time-stratified case-crossover study of ozone exposures for approximately 3.7 million respiratory EDVs from 2005 through 2008 among California residents living within 20 km of an ozone monitor. Conditional logistic regression was used to estimate associations by climate zone. Random effects meta-analysis was then applied to estimate pooled excess risks (ER). Effect modification by season, distance from the monitor and individual demographic characteristics (i.e., age, race/ethnicity, sex, and payment method), and confounding by other gaseous air pollutants were also investigated. Meta-regression was utilized to explore how climate zone–level meteorological, demographic, and regional differences influenced estimates. Results: We observed ozone-associated increases in all respiratory, asthma, and ARI visits, which were slightly larger in the warm season [asthma ER per 10-ppb increase in mean of same and previous 3 days ozone exposure (lag03) = 2.7%, 95% CI: 1.5, 3.9; ARI ERlag03 = 1.4%, 95% CI: 0.8, 1.9]. EDVs for pneumonia, COPD, and URTI were also significantly associated with ozone exposure over the whole year, but typically more consistently so during the warm season. Conclusions: Short-term ozone exposures among California residents living near an ozone monitor were positively associated with EDVs for asthma, ARI, pneumonia, COPD, and URTI from 2005 through 2008. Those associations were typically larger and more

Attenuation by clouds of UV radiation for low stratospheric ozone conditions

NASA Astrophysics Data System (ADS)

Orte, Facundo; Wolfram, Elian; Salvador, Jacobo; D'Elia, Raúl; Quiroga, Jonathan; Quel, Eduardo; Mizuno, Akira

2017-02-01

Stratospheric poor ozone air masses related to the polar ozone hole overpass subpolar regions in the Southern Hemisphere during spring and summer seasons, resulting in increases of surface Ultraviolet Index (UVI). The impact of these abnormal increases in the ultraviolet radiation could be overestimated if clouds are not taking into account. The aim of this work is to determine the percentage of cases in which cloudiness attenuates the high UV radiation that would reach the surface in low total ozone column situations and in clear sky hypothetical condition for Río Gallegos, Argentina. For this purpose, we analysed UVI data obtained from a multiband filter radiometer GUV-541 (Biospherical Inc.) installed in the Observatorio Atmosférico de la Patagonia Austral (OAPA-UNIDEF (MINDEF - CONICET)) (51 ° 33' S, 69 ° 19' W), Río Gallegos, since 2005. The database used covers the period 2005-2012 for spring seasons. Measured UVI values are compared with UVI calculated using a parametric UV model proposed by Madronich (2007), which is an approximation for the UVI for clear sky, unpolluted atmosphere and low surface albedo condition, using the total ozone column amount, obtained from the OMI database for our case, and the solar zenith angle. It is observed that ˜76% of the total low ozone amount cases, which would result in high and very high UVI categories for a hypothetical (modeled) clear sky condition, are attenuated by clouds, while 91% of hypothetical extremely high UVI category are also attenuated.

Time series analysis of ozone data in Isfahan

NASA Astrophysics Data System (ADS)

Omidvari, M.; Hassanzadeh, S.; Hosseinibalam, F.

2008-07-01

Time series analysis used to investigate the stratospheric ozone formation and decomposition processes. Different time series methods are applied to detect the reason for extreme high ozone concentrations for each season. Data was convert into seasonal component and frequency domain, the latter has been evaluated by using the Fast Fourier Transform (FFT), spectral analysis. The power density spectrum estimated from the ozone data showed peaks at cycle duration of 22, 20, 36, 186, 365 and 40 days. According to seasonal component analysis most fluctuation was in 1999 and 2000, but the least fluctuation was in 2003. The best correlation between ozone and sun radiation was found in 2000. Other variables which are not available cause to this fluctuation in the 1999 and 2001. The trend of ozone is increasing in 1999 and is decreasing in other years.

Polar stratospheric clouds and ozone depletion

NASA Technical Reports Server (NTRS)

Toon, Owen B.; Turco, Richard P.

1991-01-01

A review is presented of investigations into the correlation between the depletion of ozone and the formation of polar stratospheric clouds (PSCs). Satellite measurements from Nimbus 7 showed that over the years the depletion from austral spring to austral spring has generally worsened. Approximately 70 percent of the ozone above Antarctica, which equals about 3 percent of the earth's ozone, is lost during September and October. Various hypotheses for ozone depletion are discussed including the theory suggesting that chlorine compounds might be responsible for the ozone hole, whereby chlorine enters the atmosphere as a component of chlorofluorocarbons produced by humans. The three types of PSCs, nitric acid trihydrate, slowly cooling water-ice, and rapidly cooling water-ice clouds act as important components of the Antarctic ozone depletion. It is indicated that destruction of the ozone will be more severe each year for the next few decades, leading to a doubling in area of the Antarctic ozone hole.

Interannual variability of the Antarctic ozone hole in a GCM. Part 2: A comparison of unforced and QBO-induced variability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shindell, D.T.; Rind, D.; Balachandran, N.

1999-06-15

Simulations were performed with the Goddard Institute for Space Studies GCM including a prescribed quasi-biennial oscillation (QBO), applied at a constant maximum value, and a physically realistic parameterization of the heterogeneous chemistry responsible for severe polar ozone loss. While the QBO is primarily a stratospheric phenomenon, in this model the QBO modulates the amount and propagation of planetary wave energy in the troposphere as well as in the stratosphere. Dynamical activity is greater in the easterly than in the unforced case, while westerly years are dynamically more quiescent. By altering zonal winds and potential vorticity, the QBO forcing changes themore » refraction of planetary waves beginning in midwinter, causing the lower-stratospheric zonal average temperatures at Southern Hemisphere high latitudes to be [approximately]3--5 K warmer in the easterly phase than in the westerly during the late winter and early spring. Ozone loss varies nonlinearly with temperature, due to the sharp threshold for formation of heterogeneous chemistry surfaces, so that the mean daily total mass of ozone depleted in this region during September was 8.7 [times] 10[sup 10] kg in the QBO easterly maximum, as compared with 12.0 [times] 10[sup 10] kg in the westerly maximum and 10.3 [times] 10[sup 10] kg in the unforced case. Through this mechanism, the midwinter divergence of the Eliassen-Palm flux is well correlated with the subsequent springtime total ozone loss (R[sup 2] = 0.6). The chemical ozone loss differences are much larger than QBO-induced transport differences in the authors' model. Inclusion of the QBO forcing also increased the maximum variability in total ozone loss from the [approximately]20% value found in the unforced runs to [approximately]50%. These large variations in ozone depletion are very similar in size to the largest observed variations in the severity of the ozone hole. The results suggest that both random variability and periodic QBO

Children's and adults' knowledge and models of reasoning about the ozone layer and its depletion

NASA Astrophysics Data System (ADS)

Leighton, Jacqueline P.; Bisanz, Gay L.

2003-01-01

As environmental concepts, the ozone layer and ozone hole are important to understand because they can profoundly influence our health. In this paper, we examined: (a) children's and adults' knowledge of the ozone layer and its depletion, and whether this knowledge increases with age' and (b) how the 'ozone layer' and 'ozone hole' might be structured as scientific concepts. We generated a standardized set of questions and used it to interview 24 kindergarten students, 48 Grade 3 students, 24 Grade 5 students, and 24 adults in university, in Canada. An analysis of participants' responses revealed that adults have more knowledge than children about the ozone layer and ozone hole, but both adults and children exhibit little knowledge about protecting themselves from the ozone hole. Moreover, only some participants exhibited 'mental models' in their conceptual understanding of the ozone layer and ozone hole. The implications of these results for health professionals, educators, and scientists are discussed.

Emergence of healing in the Antarctic ozone layer

NASA Astrophysics Data System (ADS)

Solomon, Susan; Ivy, Diane J.; Kinnison, Doug; Mills, Michael J.; Neely, Ryan R.; Schmidt, Anja

2016-07-01

Industrial chlorofluorocarbons that cause ozone depletion have been phased out under the Montreal Protocol. A chemically driven increase in polar ozone (or “healing”) is expected in response to this historic agreement. Observations and model calculations together indicate that healing of the Antarctic ozone layer has now begun to occur during the month of September. Fingerprints of September healing since 2000 include (i) increases in ozone column amounts, (ii) changes in the vertical profile of ozone concentration, and (iii) decreases in the areal extent of the ozone hole. Along with chemistry, dynamical and temperature changes have contributed to the healing but could represent feedbacks to chemistry. Volcanic eruptions have episodically interfered with healing, particularly during 2015, when a record October ozone hole occurred after the Calbuco eruption.

A Discussion of Upper Stratospheric Ozone Asymmetry and Ozone Trend Changes

NASA Technical Reports Server (NTRS)

Li, Jinlong; Cunnold, Derek M.; Wang, Hsiang-Jui; Yang, Eun-Su; Newchurch, Mike J.

2002-01-01

Analyses from SAGE I/II version 6.0 data exhibit upper stratospheric ozone trends which are not significantly different from those in version 5.96 data. Trend calculations show larger downward trends at mid-high latitudes in the Southern Hemisphere than in the Northern Hemisphere, particularly in 1980s. There are also indications of decreasing downward trends with time from 1979 to 1999. We have used a chemical box model and the UARS measurements of long lived gases, CH4, H2O, NO(x), and temperature to show that, with a constant Cl(sub y) trend, a hemispheric ozone trend asymmetry of 1%/decade at 45 deg. around 43 km is expected due to the hemispheric differences of temperature and CH4 during late winter/early. Also ozone trends should have been approximately 1%/decade more negative from 1979-1989 than from 1989-1999 because of the chemical feedbacks. The model results further indicate that both the reported decrease in CH4 and the increase in H2O in HALOE measurements will result in a larger downward ozone trend and a decrease in the hemispheric ozone trend asymmetry.

A feasibility study of methods for stopping the depletion of ozone over Antarctica

NASA Technical Reports Server (NTRS)

1988-01-01

Ways of stopping the ozone depletion in the ozone hole over Antarctica were studied. The basic objectives were: (1) to define and understand the phenomenon of the ozone hole; (2) to determine possible methods of stopping the ozone depletion; (3) to identify unknowns about the hole and possible solutions. Two basic ways of attacking the problem were identified. First is replenishment of ozone as it is being depleted. Second is elimination of ozone destroying agents from the atmosphere. The second method is a more permanent form of the solution. Elimination and replenishment methods are discussed in detail.

Aura Microwave Limb Sounder Animation Illustrating the Interaction Between Temperatures and Chemicals Involved in Ozone Destruction, 2004-2005 Arctic Winter

NASA Image and Video Library

2005-06-02

This still from an animation created from data from the Microwave Limb Sounder instrument on NASA Aura spacecraft depicts the complex interaction of chemicals involved in the destruction of ozone during the 2005 Arctic winter.

Reexamination of the relation between depth of the Antarctic ozone hole, and equatorial QBO and SST, 1962-1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Angell, J.K.

1993-08-06

This paper reports on an examination of previous data to see if a correlation can be found between the average depth of the Antarctic ozone hole, and the equatorial quasi-biennial oscillation (QBO) and/or sea surface temperature (SST). Data from the period 1962 to 1992 is examined. The only ozone data which spans this period is the Dobson total ozone data from the South Pole. The data considered is the average from mid October through November. The 50 mb zonal wind at Singapore is taken as a measure of the QBO. The average SST in the region 12S - 2N, 180Wmore » - 90W, the El Nino region, is taken for the SST value. The objective of this correlation is for predictive purposes. There is a weak correlation to the QBO, and a much weaker correlation to the SST from this data set.« less

Polar ozone

NASA Technical Reports Server (NTRS)

Solomon, S.; Grose, W. L.; Jones, R. L.; Mccormick, M. P.; Molina, Mario J.; Oneill, A.; Poole, L. R.; Shine, K. P.; Plumb, R. A.; Pope, V.

1990-01-01

The observation and interpretation of a large, unexpected ozone depletion over Antarctica has changed the international scientific view of stratospheric chemistry. The observations which show the veracity, seasonal nature, and vertical structure of the Antarctic ozone hole are presented. Evidence for Arctic and midlatitude ozone loss is also discussed. The chemical theory for Antarctic ozone depletion centers around the occurrence of polar stratospheric clouds (PSCs) in Antarctic winter and spring; the climatology and radiative properties of these clouds are presented. Lab studies of the physical properties of PSCs and the chemical processes that subsequently influence ozone depletion are discussed. Observations and interpretation of the chemical composition of the Antarctic stratosphere are described. It is shown that the observed, greatly enhanced abundances of chlorine monoxide in the lower stratosphere are sufficient to explain much if not all of the ozone decrease. The dynamic meteorology of both polar regions is given, interannual and interhemispheric variations in dynamical processes are outlined, and their likely roles in ozone loss are discussed.

Emergence of healing in the Antarctic ozone layer.

PubMed

Solomon, Susan; Ivy, Diane J; Kinnison, Doug; Mills, Michael J; Neely, Ryan R; Schmidt, Anja

2016-07-15

Industrial chlorofluorocarbons that cause ozone depletion have been phased out under the Montreal Protocol. A chemically driven increase in polar ozone (or "healing") is expected in response to this historic agreement. Observations and model calculations together indicate that healing of the Antarctic ozone layer has now begun to occur during the month of September. Fingerprints of September healing since 2000 include (i) increases in ozone column amounts, (ii) changes in the vertical profile of ozone concentration, and (iii) decreases in the areal extent of the ozone hole. Along with chemistry, dynamical and temperature changes have contributed to the healing but could represent feedbacks to chemistry. Volcanic eruptions have episodically interfered with healing, particularly during 2015, when a record October ozone hole occurred after the Calbuco eruption. Copyright © 2016, American Association for the Advancement of Science.

Detection and Attribution of the Recovery of Polar Ozone

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Nash, E. R.; Douglass, A. R.; Nielsen, J. E.; Pawson, S.; Stolarski, R. S.

2008-01-01

The Antarctic ozone hole develops each year and culminates by early spring (late September - early October). The severity of the hole has been assessed from satellites using the minimum total ozone value from the October monthly mean (depth of the hole), calculating the average area coverage during this September-October period, and by estimating ozone mass deficit. Profile information shows that ozone is completely destroyed in the 14-2 1 km layer by early October. Ozone is mainly destroyed by halogen (chlorine and bromine) catalytic cycles, and these losses are modulated by temperature variations. Because atmospheric halogen levels are responding to international agreements that limit or phase out production, the amount of halogens in the stratosphere should decrease over the next few decades. Both models and projections of ozone depleting substances (ODSs) into the 21St century reveal that polar ozone levels should recover in the 2060- 2070 period. In this talk, we will review current projections of polar ozone recovery. Using models and ODs projections, we explore both the past, near future (2008-2025), and far future (> 2025) levels of polar ozone. Finally, we will discuss various factors that complicate recovery such as greenhouse gas changes (e.g., cooling in the upper stratosphere) and the acceleration of the Brewer-Dobson circulation.

Linking Horizontal And Vertical Transports of Biomass Fire Emissions to the Tropical Atlantic Ozone Paradox during the Northern Hemisphere Winter Season: II. 1998-1999.

NASA Technical Reports Server (NTRS)

Jenkins, Gregory S.; Ryu, Jung-Hee; Thompson, Anne M.; Witte, Jacquelyn C.

2002-01-01

The horizontal and vertical transport of biomass fire emissions in West Africa during November 1998 through February 1999, are examined using all available data including wind, fire, aerosol, precipitation, lightning and outgoing longwave radiation. Ozonesonde data from the Aerosols99 Trans-Atlantic cruise are also included with rain and wind analyses. The results here support earlier studies that ozone and ozone precursors associated with biomass burning are confined to the lower troposphere primarily due to the lack of deep convection over land areas. Ozone and its precursors are horizontally transported equatorward or towards the west by winds in the 1000-700 hPa layers. However, rising adiabatic motions associated with the diurnal evolution of the West African n can transport ozone and its precursors vertically into the free troposphere above the marine boundary layer. Moreover, lightning from South America, Central Africa and mesoscale convective systems in the Gulf of Guinea can lead to elevated ozone mixing ratios in the middle and upper troposphere.

Device performance and lifetime of polymer:fullerene solar cells with UV-ozone-irradiated hole-collecting buffer layers.

PubMed

Lee, Seungsoo; Nam, Sungho; Lee, Hyena; Kim, Hwajeong; Kim, Youngkyoo

2011-11-18

We report the influence of UV-ozone irradiation of the hole-collecting buffer layers on the performance and lifetime of polymer:fullerene solar cells. UV-ozone irradiation was targeted at the surface of the poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) layers by varying the irradiation time up to 600 s. The change of the surface characteristics in the PEDOT:PSS after UV-ozone irradiation was measured by employing optical absorption spectroscopy, photoelectron yield spectroscopy, and contact angle measurements, while Raman and X-ray photoelectron spectroscopy techniques were introduced for more microscopic analysis. Results showed that the UV-ozone irradiation changed the chemical structure/composition of the surface of the PEDOT:PSS layers leading to the gradual increase of ionization potential with irradiation time in the presence of up-and-down variations in the contact angle (polarity). This surface property change was attributed to the formation of oxidative components, as evidenced by XPS and Auger electron images, which affected the sheet resistance of the PEDOT:PSS layers. Interestingly, device performance was slightly improved by short irradiation (up to 10 s), whereas it was gradually decreased by further irradiation. The short-duration illumination test showed that the lifetime of solar cells with the UV-ozone irradiated PEDOT:PSS layer was improved due to the protective role of the oxidative components formed upon UV-ozone irradiation against the attack of sulfonic acid groups in the PEDOT:PSS layer to the active layer. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

From ozone mini-holes and mini-highs towards extreme value theory: New insights from extreme events and non-stationarity

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Stübi, R.; Weihs, P.; Holawe, F.; Peter, T.; Davison, A. C.

2009-04-01

Over the last few decades negative trends in stratospheric ozone have been studied because of the direct link between decreasing stratospheric ozone and increasing surface UV-radiation. Recently a discussion on ozone recovery has begun. Long-term measurements of total ozone extending back earlier than 1958 are limited and only available from a few stations in the northern hemisphere. The world's longest total ozone record is available from Arosa, Switzerland (Staehelin et al., 1998a,b). At this site total ozone measurements have been made since late 1926 through the present day. Within this study (Rieder et al., 2009) new tools from extreme value theory (e.g. Coles, 2001; Ribatet, 2007) are applied to select mathematically well-defined thresholds for extreme low and extreme high total ozone. A heavy-tail focused approach is used by fitting the Generalized Pareto Distribution (GPD) to the Arosa time series. Asymptotic arguments (Pickands, 1975) justify the use of the GPD for modeling exceedances over a sufficiently high (or below a sufficiently low) threshold (Coles, 2001). More precisely, the GPD is the limiting distribution of normalized excesses over a threshold, as the threshold approaches the endpoint of the distribution. In practice, GPD parameters are fitted, to exceedances by maximum likelihood or other methods - such as the probability weighted moments. A preliminary step consists in defining an appropriate threshold for which the asymptotic GPD approximation holds. Suitable tools for threshold selection as the MRL-plot (mean residual life plot) and TC-plot (stability plot) from the POT-package (Ribatet, 2007) are presented. The frequency distribution of extremes in low (termed ELOs) and high (termed EHOs) total ozone and their influence on the long-term changes in total ozone are analyzed. Further it is shown that from the GPD-model the distribution of so-called ozone mini holes (e.g. Bojkov and Balis, 2001) can be precisely estimated and that the

Observations and theories related to Antarctic ozone changes

NASA Technical Reports Server (NTRS)

Hartmann, D.; Watson, R. T.; Cox, Richard A.; Kolb, C.; Mahlman, J.; Mcelroy, M.; Plumb, A.; Ramanathan, V.; Schoeberl, M.; Solomon, S.

1989-01-01

In 1985, there was a report of a large, sudden, and unanticipated decrease in the abundance of springtime Antarctic ozone over the last decade. By 1987, ozone decreases of more than 50 percent in the total column, and 95 percent locally between 15 and 20 km, had been observed. The scientific community quickly rose to the challenge of explaining this remarkable discovery; theoreticians soon developed a series of chemical and dynamical hypotheses to explain the ozone loss. Three basic theories were proposed to explain the springtime ozone hole. (1) The ozone hole is caused by the increasing atmospheric loadings of manmade chemicals containing chlorine (chlorofluorocarbons (CFC's) and bromine (halons)). These chemicals efficiently destroy ozone in the lower stratosphere in the Antarctic because of the special geophysical conditions, of an isolated air mass (polar vortex) with very cold temperatures, that exist there. (2) The circulation of the atmosphere in spring has changed from being predominantly downward over Antarctica to upward. This would mean that ozone poor air from the troposphere, instead of ozone rich air from the upper stratosphere, would be transported into the lower Antarctic stratosphere. (3) The abundance of the oxides of nitrogen in the lower Antarctic stratosphere is periodically enhanced by solar activity. Nitrogen oxides are produced in the upper mesosphere and thermosphere and then transported downward into the lower stratosphere in Antarctica, resulting in the chemical destruction of ozone. The climatology and trends of ozone, temperature, and polar stratospheric clouds are discussed. Also, the transport and chemical theories for the Antarctic ozone hole are presented.

Impact of climate variability on tropospheric ozone.

PubMed

Grewe, Volker

2007-03-01

A simulation with the climate-chemistry model (CCM) E39/C is presented, which covers both the troposphere and stratosphere dynamics and chemistry during the period 1960 to 1999. Although the CCM, by its nature, is not exactly representing observed day-by-day meteorology, there is an overall model's tendency to correctly reproduce the variability pattern due to an inclusion of realistic external forcings, like observed sea surface temperatures (e.g. El Niño), major volcanic eruption, solar cycle, concentrations of greenhouse gases, and Quasi-Biennial Oscillation. Additionally, climate-chemistry interactions are included, like the impact of ozone, methane, and other species on radiation and dynamics, and the impact of dynamics on emissions (lightning). However, a number of important feedbacks are not yet included (e.g. feedbacks related to biogenic emissions and emissions due to biomass burning). The results show a good representation of the evolution of the stratospheric ozone layer, including the ozone hole, which plays an important role for the simulation of natural variability of tropospheric ozone. Anthropogenic NO(x) emissions are included with a step-wise linear trend for each sector, but no interannual variability is included. The application of a number of diagnostics (e.g. marked ozone tracers) allows the separation of the impact of various processes/emissions on tropospheric ozone and shows that the simulated Northern Hemisphere tropospheric ozone budget is not only dominated by nitrogen oxide emissions and other ozone pre-cursors, but also by changes of the stratospheric ozone budget and its flux into the troposphere, which tends to reduce the simulated positive trend in tropospheric ozone due to emissions from industry and traffic during the late 80s and early 90s. For tropical regions the variability in ozone is dominated by variability in lightning (related to ENSO) and stratosphere-troposphere exchange (related to Northern Hemisphere Stratospheric

Nadir Ozone Profile Retrieval from SCIAMACHY: application to the Antarctic Ozone Hole

NASA Astrophysics Data System (ADS)

Shah, Sweta; Piet, Stammes; Tuinder, Olaf N. E.; de Laat, Jos

2017-04-01

We present new nadir ozone profile retrievals using SCIAMACHY UV reflectance spectra for the mission period of the Envisat satellite. We have used the most recent Level-1 data version (v8 with degradation correction included) in the UV range (265-330 nm) and have used the OPERA optimal estimation algorithm (van Peet et al., AMT, 2014) developed in KNMI. We first show the comparison of the retrieved satellite profiles to co-located ozone sonde profiles in order to evaluate the accuracy of the retrieved ozone profile dataset. Based on these results, we have further processed the SCIAMCHY nadir dataset, specifically all the southern hemisphere pixels south of 45 degrees latitude for the months of August-November for the complete years 2003-2011. We show the monthly mean profiles, time-series of daily averages and minima of the retrieved stratospheric columns, and finally the ozone profile trend over the years 2003-2011. We also show the comparison of our results with the literature and hence the consistency of this new SCIAMACHY dataset.

The epidemiology of pertussis in the Australian Capital Territory, 1999 to 2005--epidemics of testing, disease or false positives?

PubMed

Wylks, Clare E; Ewald, Ben; Guest, Charles

2007-12-01

The increase in pertussis notifications since the 1990s in many countries, including Australia, has been attributed to improved diagnosis. This study aimed to describe the epidemiology of pertussis in the Australian Capital Territory from 1999 to 2005, determine whether the apparent changes could be accounted for by greater recognition and testing, and explore the impact of false positive serology results associated with faulty test kits. The Australian Capital Territory resident notification, laboratory and separation data from 1999 to 2005 were examined and the proportions of positive tests across time periods and age groups compared. Notification rates increased in the years 2000, 2003 and 2005. There was a shift in the age distribution of cases, from children and teenagers in 2000, to teenagers in 2003 and adults in 2005. Testing activity and notification activity were closely related. Comparing the epidemic periods to the preceding inter-epidemic periods, the proportion of positive tests was maintained or increased for all age groups combined and for adults and children (e.g. statistically significant increase from 7.8% to 14.0% in the 2005 epidemic in adults). During each epidemic the proportion of positive tests was statistically significantly higher in the age group with the highest notification activity. Despite similar testing rates in adults in 2003 and 2005, greater disease activity was reported in 2005. Although the numbers were small, polymerase chain reaction and culture positive test results increased in 2003 but not in 2005. The proportion of positive polymerase chain reaction results increased in 2003, providing strong evidence that the apparent epidemic of 2003 was due to a true increase in underlying disease activity. Because of the uncertainty surrounding the timing of the false positive serology results, the study provides weaker support for a true epidemic of pertussis in 2005.

Quantifying the ozone and ultraviolet benefits already achieved by the Montreal Protocol.

PubMed

Chipperfield, M P; Dhomse, S S; Feng, W; McKenzie, R L; Velders, G J M; Pyle, J A

2015-05-26

Chlorine- and bromine-containing ozone-depleting substances (ODSs) are controlled by the 1987 Montreal Protocol. In consequence, atmospheric equivalent chlorine peaked in 1993 and has been declining slowly since then. Consistent with this, models project a gradual increase in stratospheric ozone with the Antarctic ozone hole expected to disappear by ∼2050. However, we show that by 2013 the Montreal Protocol had already achieved significant benefits for the ozone layer. Using a 3D atmospheric chemistry transport model, we demonstrate that much larger ozone depletion than observed has been avoided by the protocol, with beneficial impacts on surface ultraviolet. A deep Arctic ozone hole, with column values <120 DU, would have occurred given meteorological conditions in 2011. The Antarctic ozone hole would have grown in size by 40% by 2013, with enhanced loss at subpolar latitudes. The decline over northern hemisphere middle latitudes would have continued, more than doubling to ∼15% by 2013.

Quantifying the ozone and ultraviolet benefits already achieved by the Montreal Protocol

PubMed Central

Chipperfield, M. P.; Dhomse, S. S.; Feng, W.; McKenzie, R. L.; Velders, G.J.M.; Pyle, J. A.

2015-01-01

Chlorine- and bromine-containing ozone-depleting substances (ODSs) are controlled by the 1987 Montreal Protocol. In consequence, atmospheric equivalent chlorine peaked in 1993 and has been declining slowly since then. Consistent with this, models project a gradual increase in stratospheric ozone with the Antarctic ozone hole expected to disappear by ∼2050. However, we show that by 2013 the Montreal Protocol had already achieved significant benefits for the ozone layer. Using a 3D atmospheric chemistry transport model, we demonstrate that much larger ozone depletion than observed has been avoided by the protocol, with beneficial impacts on surface ultraviolet. A deep Arctic ozone hole, with column values <120 DU, would have occurred given meteorological conditions in 2011. The Antarctic ozone hole would have grown in size by 40% by 2013, with enhanced loss at subpolar latitudes. The decline over northern hemisphere middle latitudes would have continued, more than doubling to ∼15% by 2013. PMID:26011106

Quantifying the ozone and ultraviolet benefits already achieved by the Montreal Protocol

NASA Astrophysics Data System (ADS)

Chipperfield, M. P.; Dhomse, S. S.; Feng, W.; McKenzie, R. L.; Velders, G. J. M.; Pyle, J. A.

2015-05-01

Chlorine- and bromine-containing ozone-depleting substances (ODSs) are controlled by the 1987 Montreal Protocol. In consequence, atmospheric equivalent chlorine peaked in 1993 and has been declining slowly since then. Consistent with this, models project a gradual increase in stratospheric ozone with the Antarctic ozone hole expected to disappear by ~2050. However, we show that by 2013 the Montreal Protocol had already achieved significant benefits for the ozone layer. Using a 3D atmospheric chemistry transport model, we demonstrate that much larger ozone depletion than observed has been avoided by the protocol, with beneficial impacts on surface ultraviolet. A deep Arctic ozone hole, with column values <120 DU, would have occurred given meteorological conditions in 2011. The Antarctic ozone hole would have grown in size by 40% by 2013, with enhanced loss at subpolar latitudes. The decline over northern hemisphere middle latitudes would have continued, more than doubling to ~15% by 2013.

The World Already Avoided: Quantifying the Ozone Benefits Achieved by the Montreal Protocol

NASA Astrophysics Data System (ADS)

Chipperfield, Martyn; Dhomse, Sandip; Feng, Wuhu; McKenzie, Richard; Velders, Guus; Pyle, John

2015-04-01

Chlorine and bromine-containing ozone-depleting substances (ODSs) are controlled by the 1987 Montreal Protocol. In consequence, atmospheric equivalent chlorine peaked in 1993 and has been declining slowly since then. Consistent with this, models project a gradual increase in stratospheric ozone with the Antarctic Ozone Hole expected to disappear by ~2050. However, we show that by 2014 the Montreal Protocol has already achieved significant benefits for the ozone layer. Using an off-line 3-D atmospheric chemistry model, we demonstrate that much larger ozone depletion than observed has been avoided by the protocol, with benefits for surface UV and climate. A deep Arctic Ozone Hole, with column values <120 DU, would have occurred given the meteorological conditions in 2011. The Antarctic Ozone Hole would have grown in size by 40% by 2013, with enhanced loss at subpolar latitudes. The ozone decline over northern hemisphere middle latitudes would have continued, more than doubling to ~15% by 2013.

ER-2 #809 awaits pilot entry for the third flight of the SAGE III Ozone Loss and Validation Experiment (SOLVE)

NASA Image and Video Library

2000-01-28

ER-2 #809 awaiting pilot entry for the third flight of the SAGE III Ozone Loss and Validation Experiment (SOLVE). The ER-2, a civilian variant of Lockheed's U-2, and another NASA flying laboratory, Dryden's DC-8, were based north of the Arctic Circle in Kiruna, Sweden during the winter of 2000 to study ozone depletion as part of SOLVE. A large hangar built especially for research, "Arena Arctica" housed the instrumented aircraft and the scientists. Scientists have observed unusually low levels of ozone over the Arctic during recent winters, raising concerns that ozone depletion there could become more widespread as in the Antarctic ozone hole. The NASA-sponsored international mission took place between November 1999 and March 2000 and was divided into three phases. The DC-8 was involved in all three phases returning to Dryden between each phase. The ER-2 flew sample collection flights between January and March, remaining in Sweden from Jan. 9 through March 16. "The collaborative campaign will provide an immense new body of information about the Arctic stratosphere," said program scientist Dr. Michael Kurylo, NASA Headquarters. "Our understanding of the Earth's ozone will be greatly enhanced by this research."

Langley Research Highlights 1999: Advanced Aerospace Technology Clouds That Help Create the Ozone Hole Capturing Comet Dust

NASA Technical Reports Server (NTRS)

2000-01-01

This report contains highlights of some of the major accomplishments and applications made by NASA Langley Research Center and its university partners and industry colleagues during 1999. The highlights illustrate the broad range of research and technology activities carried out by NASA Langley and the contributions of this work toward maintaining United States' leadership in aeronautics and space research. The Center's historic national role since 1917 continues in Aerospace Technology research with an additional major role in Earth Science research. Langley also partners closely with other NASA Centers and the Jet Propulsion Laboratory in Space Science and the Human Exploration and Development of Space. A color version is available at http://larcpubs.larc.nasa.gov/randt/1999/. For further information, contact Dennis Bushnell, Senior Scientist, Mail Stop 110, NASA Langley Research Center, Hampton, Virginia 23681-2199, (757)-864-8987, e-mail address: d.m.bushnell@larc.nasa.gov.

Polar Ozone Loss Rates: Comparison Of Match Observations With Simulations Of 3-D Chemical Transport Model And Box Model

NASA Astrophysics Data System (ADS)

Tripathi, O. P.; Godin-Beekmann, S.; Lefevre, F.; Marchand, M.; Pazmino, A.; Hauchecorne, A.

2005-12-01

Model simulations of ozone loss rates during recent arctic and Antarctic winters are compared with the observed ozone loss rates from the match technique. Arctic winters 1994/1995, 1999/2000, 2002/2003 and the Antarctic winter 2003 were considered for the analysis. We use a high resolution chemical transport model MIMOSA-CHIM and REPROBUS box model for the calculation of ozone loss rates. Trajectory model calculations show that the ozone loss rates are dependent on the initialization fields. On the one hand when chemical fields are initialized by UCAM (University of Cambridge SLIMCAT model simulated fields) the loss rates were underestimated by a factor of two whereas on the other hand when it is initialized by UL (University of Leeds) fields the model loss rates are in a very good agreement with match loss rates at lower levels. The study shows a very good agreement between MIMOSA-CHIM simulation and match observation in 1999/2000 winter at both levels, 450 and 500 K, except slight underestimation in March at 500 K. But in January we have a very good agreement. This is also true for 1994/1995 when we consider simulated ozone loss rate in view of the ECMWF wind deficiency assuming that match observations were not made on isolated trajectories. Sensitivity tests, by changing JCl2O2 value, particle number density and heating rates, performed for the arctic winter 1999/2000 shows that we need to improve our understanding of particle number density and heating rate calculation mechanism. Burkholder JCl2O2 has improved the comparison of MIMOSA-CHIM model results with observations (Tripathi et al., 2005). In the same study the comparison results were shown to improved by changing heating rates and number density through NAT particle sedimentation.

The 1987 Airborne Antarctic Ozone Experiment: the Nimbus-7 TOMS Data Atlas

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Ardanuy, Philip E.; Sechrist, Frank S.; Penn, Lanning M.; Larko, David E.; Doiron, Scott D.; Galimore, Reginald N.

1988-01-01

Total ozone data taken by the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) played a central role in the successful outcome of the 1987 Airborne Antarctic Ozone Experiment. The near-real-time TOMS total ozone observations were suppled within hours of real time to the operations center in Punta Arenas, Chile, over a telecommunications network designed specifically for this purpose. The TOMS data preparation and method of transfer over the telecommunications links are reviewed. This atlas includes a complete set of the near-real-time TOMS orbital overpass data over regions around the Palmer Peninsula of Antarctica for the period of August 8 through September 29, 1987. Also provided are daily polar orthographic projections of TOMS total ozone measurements over the Southern Hemisphere from August through November 1987. In addition, a chronology of the salient points of the experiment, along with some latitudinal cross sections and time series at locations of interest of the TOMS total ozone observations are presented. The TOMS total ozone measurements are evaluated along the flight tracks of each of the ER-2 and DC-8 missions during the experiment. The ozone hole is shown here to develop in a monotonic progression throughout late August and September. The minimum total ozone amount was found on 5 October, when its all-time lowest value of 109 DU is recorded. The hole remains well defined, but fills gradually from mid-October through mid-November. The hole's dissolution is observed here to begin in mid-November, when it elongates and begins to rotate. By the end of November, the south pole is no longer located within the ozone hole.

Knowledge about the Greenhouse Effect and the Effects of the Ozone Layer among Norwegian Pupils Finishing Compulsory Education in 1989, 1993, and 2005—What Now?

NASA Astrophysics Data System (ADS)

Kirkeby Hansen, Pål J.

2010-02-01

The greenhouse effect and the effects of the ozone layer have been in the media and public focus for more than two decades. During the same period, Norwegian compulsory schools have had four national curricula. The two last-mentioned prescribe explicitly the two topics. Media and public discourse might have been sources of information causing informal learning among pupils. The point of departure for this questionnaire-based examination of the development of pupils' knowledge about the greenhouse effect and the effects of the ozone layer from 1989 to 2005 is the changing curricula and formal and informal learning. In 2005 the trends seem to be that more pupils confuse the greenhouse effect with the effects of the ozone layer. At the same time, specific knowledge about the greenhouse effect is improving. This article will discuss some possible causes for these trends, and give some recommendations for teaching the topics in accordance with the last national curriculum implemented in 2006.

ER-2 #809 and DC-8 in Arena Arctica hangar in Kiruna, Sweden prior to the SAGE III Ozone Loss and Validation Experiment (SOLVE)

NASA Image and Video Library

2000-01-23

NASA ER-2 # 809 and its DC-8 shown in Arena Arctica before the SAGE III Ozone Loss and Validation Experiment (SOLVE). The two airborne science platforms were based north of the Arctic Circle in Kiruna, Sweden, during the winter of 2000 to study ozone depletion as part of SOLVE. A large hangar built especially for research, "Arena Arctica" housed the instrumented aircraft and the scientists. Scientists have observed unusually low levels of ozone over the Arctic during recent winters, raising concerns that ozone depletion there could become more widespread as in the Antarctic ozone hole. The NASA-sponsored international mission took place between November 1999 and March 2000 and was divided into three phases. The DC-8 was involved in all three phases returning to Dryden between each phase. The ER-2 flew sample collection flights between January and March, remaining in Sweden from Jan. 9 through March 16. "The collaborative campaign will provide an immense new body of information about the Arctic stratosphere," said program scientist Dr. Michael Kurylo, NASA Headquarters. "Our understanding of the Earth's ozone will be greatly enhanced by this research."

"Holes" in Student Understanding: Addressing Prevalent Misconceptions regarding Atmospheric Environmental Chemistry

ERIC Educational Resources Information Center

Kerr, Sara C.; Walz, Kenneth A.

2007-01-01

There is a misconception among undergraduate students that global warming is caused by holes in the ozone layer. In this study, we evaluated the presence of this and other misconceptions surrounding atmospheric chemistry that are responsible for the entanglement of the greenhouse effect and the ozone hole in students' conceptual frameworks. We…

Ozone Layer Observations

NASA Technical Reports Server (NTRS)

McPeters, Richard; Bhartia, P. K. (Technical Monitor)

2002-01-01

The US National Aeronautics and Space Administration (NASA) has been monitoring the ozone layer from space using optical remote sensing techniques since 1970. With concern over catalytic destruction of ozone (mid-1970s) and the development of the Antarctic ozone hole (mid-1980s), long term ozone monitoring has become the primary focus of NASA's series of ozone measuring instruments. A series of TOMS (Total Ozone Mapping Spectrometer) and SBUV (Solar Backscatter Ultraviolet) instruments has produced a nearly continuous record of global ozone from 1979 to the present. These instruments infer ozone by measuring sunlight backscattered from the atmosphere in the ultraviolet through differential absorption. These measurements have documented a 15 Dobson Unit drop in global average ozone since 1980, and the declines in ozone in the antarctic each October have been far more dramatic. Instruments that measure the ozone vertical distribution, the SBUV and SAGE (Stratospheric Aerosol and Gas Experiment) instruments for example, show that the largest changes are occurring in the lower stratosphere and upper troposphere. The goal of ozone measurement in the next decades will be to document the predicted recovery of the ozone layer as CFC (chlorofluorocarbon) levels decline. This will require a continuation of global measurements of total column ozone on a global basis, but using data from successor instruments to TOMS. Hyperspectral instruments capable of measuring in the UV will be needed for this purpose. Establishing the relative roles of chemistry and dynamics will require instruments to measure ozone in the troposphere and in the stratosphere with good vertical resolution. Instruments that can measure other chemicals important to ozone formation and destruction will also be needed.

Chemical Loss of Polar Ozone: Present Understanding and Remaining Uncertainties

NASA Technical Reports Server (NTRS)

Salawitch, Ross; Canty, Tim; Cunnold, Derek; Dorf, Marcel; Frieler, Katja; Godin-Beekman, Sophie; Newchurch, Michael; Pfeilsticker, Klaus; Rex, Markus; Stimpfle, Rick;

Variations in total ozone column and biologically effective solar UV exposure doses in Bologna, Italy during the period 2005-2010

NASA Astrophysics Data System (ADS)

Petkov, Boyan; Vitale, Vito; Tomasi, Claudio; Mazzola, Mauro; Lanconelli, Christian; Lupi, Angelo; Busetto, Maurizio

2014-01-01

Variations in total ozone column and sun exposures able to cause erythema and damage the DNA molecules were observed by the narrow-band filter radiometer UV-RAD in Bologna, Italy from 2005 to 2010. The ozone columns determined from the UV-RAD measurements were found to be close to those provided by the satellite Ozone Monitoring Instrument (OMI) showing an average discrepancy of 1 % with standard deviation of ± 6 %. Analysis of the data highlights a well-marked annual cycle of the ozone column variations while the oscillations with periods of 8, 18 and 34 months present much smaller amplitudes. The influence of the frequency of solar irradiance measurements on the accuracy of the evaluated daily exposure dose has been studied and it was found that time intervals no longer than 5-10 min between the measurements of erythema and DNA damage effective UV irradiances provide a satisfactory assessment of the corresponding daily exposures. The latter do not present significant year-to-year variations for the period under study, while their annual distributions show slight changes likely due to the specific cloud cover and ozone column variability for different years. The annual erythemal exposure dose for 2007-2010 varied between 603.7 and 638.1 kJ m-2, while the corresponding sun exposure affecting DNA changed from 6.38 to 7.91 kJ m-2.

Changes in surface solar UV irradiances and total ozone during the solar eclipse of August 11, 1999

NASA Astrophysics Data System (ADS)

Zerefos, C. S.; Balis, D. S.; Meleti, C.; Bais, A. F.; Tourpali, K.; Kourtidis, K.; Vanicek, K.; Cappellani, F.; Kaminski, U.; Colombo, T.; Stübi, R.; Manea, L.; Formenti, P.; Andreae, M. O.

2000-11-01

During the solar eclipse of August 11, 1999, intensive measurements of UV solar irradiance and total ozone were performed at a number of observatories located near the path of the Moon's shadow. At the Laboratory of Atmospheric Physics (LAP) of the Aristotle University of Thessaloniki, Greece, global and direct spectra of UV solar irradiances (285-365 nm) were recorded with a double monochromator, and erythemal irradiances were measured with broadband pyranometers. In addition, higher-frequency measurements of global and direct irradiances at six UV wavelengths were performed with a single Brewer spectrophotometer. Total ozone measurements were also performed with Dobson and Brewer spectrophotometers at Hradec Kralove (Czech Republic), Ispra (Italy), Sestola (Italy), Hohenpeissenberg (Germany), Bucharest (Romania), Arosa (Switzerland), and Thessaloniki (Greece). From the spectral UV measurements the limb darkening effect of the solar disk was tentatively quantified from differences of measured solar spectral irradiances at the peak of the eclipse (near to limb conditions) and before the eclipse. Two blackbody curves were fit to the preeclipse and peak eclipse spectra, which have shown a difference in effective temperatures of about 165°K between the limb and the whole of the solar disk. The limb darkening effect is larger at the shorter UV wavelengths. The ratio of the diffuse to direct solar irradiances during the eclipse shows that the diffuse component is reduced much less compared to the decline of the direct solar irradiance at the shorter wavelengths. Moreover, a 20-min oscillation of erythemal UV-B solar irradiance was observed before and after the time of the eclipse maximum under clear skies, indicating a possible 20-min fluctuation in total ozone, presumably caused by the eclipse-induced gravity waves. This work also shows that routine total ozone measurements with a Brewer or a Dobson spectrophotometer should be used with caution during a solar eclipse

SAGE II Ozone Analysis

NASA Technical Reports Server (NTRS)

Cunnold, Derek; Wang, Ray

2002-01-01

Publications from 1999-2002 describing research funded by the SAGE II contract to Dr. Cunnold and Dr. Wang are listed below. Our most recent accomplishments include a detailed analysis of the quality of SAGE II, v6.1, ozone measurements below 20 km altitude (Wang et al., 2002 and Kar et al., 2002) and an analysis of the consistency between SAGE upper stratospheric ozone trends and model predictions with emphasis on hemispheric asymmetry (Li et al., 2001). Abstracts of the 11 papers are attached.

Assessment of SAGE Version 6.1 Ozone Data Quality

NASA Technical Reports Server (NTRS)

Wang, Hsiang J.; Cunnold, Derek M.; Thomason, Larry W.; Zawodny, Joseph M.; Bodeker, Greg E.

2002-01-01

The SAGE-II V6.1 ozone retrievals are shown to be of better precision at all levels and to be much more accurate than previous retrievals in the lower stratosphere below 20 km altitude. A filtering procedure for removing anomalous ozone profiles associated with volcanic aerosol/cloud effects and other identified artifacts in V6.1 ozone is described. The agreement between SAGE and ozonesondes in the mean is shown to be approximately 10% down to the tropopause. Relative to the sondes SAGE tends to slightly overestimate ozone (less than 5%) between 15 and 20 km altitude, and systematically underestimates ozone in the troposphere by approximately 30% in the regions between 8 km altitude and 2 km below the tropopause. The precisions (random errors) of SAGE ozone retrievals above 25 km altitude are estimated to be 4% or better; they are a factor of ten worse below 16 km altitude. Linear trends in the differences between coincident SAGE and ozonesondes measurement are generally less than 0.3 %/year and not significantly different from zero in 95% confidence intervals. Compared to V5.96 retrievals, ozone trend differences between 20 and 50 km altitude are approximately 0. 1 %/year, below 20 km altitude the SAGE II trends are more positive by approximately 0.2 %/year. For the 1984-1999 period the SAGE-II shows a localized ozone loss of -0.4(+/- 0.25) %/year (2gigma) in the tropics at 20 km altitude. In the lower stratosphere between 16 and 22 km altitudes, the SAGE shows significant ozone losses in the mid-latitudes in both Hemispheres during the 1979-1999 periods. The ozone trends range from -0.24(+/- 0.18) to -0.77(+/- 0.46) (2sigma)%/year. However in the 1984-1999 period, the downward trends are smaller (-0.07 to - 0.25 %/year) in this altitude range, and the trends in the integrated column from 12 to 17 km altitude in mid-latitudes (35 deg - 60 deg) are not significantly different from zero (0.1 +?- 0.6 (2sigma)%/year). Averaged over the tropics (20 deg S to 20 deg N

Regional Variability in Ozone in the Tropical and Subtropical Free Troposphere and Tropopause Transition Layer based on Aura-Era SHADOZ Data (2005-2009)

NASA Astrophysics Data System (ADS)

Miller, S. K.; Thompson, A. M.; Witte, J. C.; Balashov, N. V.; Kollonige, D. E.

2012-12-01

The more than 5000 sets of ozone and P-T-U profiles provided for the tropics and subtropics by the Southern Hemisphere Additional Ozonesondes (SHADOZ) since 1998 have provided a wealth of insights into convective and mixing processes, especially in the upper troposphere through lower stratosphere. The observations have been used in evaluations of satellite ozone and chemical-transport and climate-chemistry models. Recently, we analyzed a climatology of ozone profiles based on the 2005-2009 SHADOZ data when 4 new stations joined the network (15 stations total), giving latitudinal coverage from 25S to 21N. We answer the following questions: How do ozone distributions at two new subtropical stations, Hanoi and Hilo in the northern hemisphere, compare to those at the southern subtropical stations, Irene and La Réunion? Are there better-defined regional classifications of tropospheric and tropopause transition layer (TTL) SHADOZ ozone profiles in the tropics, defined as within + 18 degrees latitude, than the Atlantic-Pacific differentiation identified in published studies with 1998-2004 SHADOZ data? Three distinct regions of the tropics are identified based on the criteria: ozone structure in the TTL; convective influence inferred from laminar identification (LID) of ozone and potential temperature; degree of pollution in the free troposphere (FT). These are: (1) western Pacific/eastern Indian Ocean; (2) equatorial Americas (San Cristóbal, Alajuela, Paramaribo); (3) Atlantic Ocean and Africa. In addition, we have re-examined potential trends in FT and TTL ozone at several SHADOZ stations for which data extend back to the early 1990s.

The impact of policy changes on consumer behaviour and alcohol consumption in Scania, Sweden 1999-2005.

PubMed

Stafström, Martin; Ostergren, Per-Ölof

2014-01-01

To analyse the hypothesis that a gradual deregulation of traveller allowances, starting in 2001 and ending in 2004, on alcoholic beverages changed consumer behaviours that ultimately led to an increase in alcohol consumption in southern Sweden between in 2005 compared with 1999. The data for this general population random sample prospective cohort study with repeated measurements were collected in 1999 (T1) and in 2005 (T2) in the county of Scania, analysing the answers from 8612 individuals, who at T1 were alcohol consumers and 18-80 years old. Aggregate age-adjusted general mean alcohol consumption did not change significantly between T1 and T2. Significant downward changes were found in a number of demographical and socioeconomic sub-groups. Generalized linear model analyses indicated that the uptake of buying alcohol from a private person was associated with significantly higher consumption (P < 0.001). No longer buying alcohol from a private person, consuming illicitly distilled spirits or buying alcohol abroad were significantly associated with lower consumption at follow-up. Interaction effects between changing consumer behaviours were also identified. The deregulation of the cross-border trade of alcohol into Sweden did not, within our sample, lead to an increase in consumption. There were, however, significant decreases in consumption levels within different socio-demographic sub-groups. In relation to changing consumer behaviours both upward and downward shifts in drinking trends were observed. © The Author 2014. Medical Council on Alcohol and Oxford University Press. All rights reserved.

Dynamical component of seasonal and year-to-year changes in Antarctic and global ozone

NASA Technical Reports Server (NTRS)

Tung, Ka Kit; Yang, HU

1988-01-01

The dynamics of the ozone concetration components of the Antarctic ozone hole as related to seasonal and year-to-year temperature changes in August, September, October, and November during the 1979-1985 period is studied using a zonally averaged model in which all transport fields are fixed by input temperature data. The results suggest that, prior to 1984, both the seasonal and year-to year variability of the zonal-mean Antarctic ozone minimum and the surrounding maximum can be accounted for by temperature dynamics without invoking changes in chemical composition (e.g., chlorine content) or special chemistry. The same dynamical mechanism also accounts for the good simulation of the observed seasonal and latitudinal structure of column ozone in other parts of the world. However, chemical depletion of ozone may have become more important after 1984. The model also appears to underpredict the September ozone decline in years, leading to an underprediction of the recent minimum values in the Antarctic ozone hole.

Microphysical Modelling of the 1999-2000 Arctic Winter. 2; Chlorine Activation and Ozone Depletion

NASA Technical Reports Server (NTRS)

Drdla, K.; Schoeberl, M. R.; Gore, Warren J. (Technical Monitor)

2001-01-01

The effect of a range of assumptions about polar stratospheric clouds (PSCs) on ozone depletion has been assessed using at couple microphysical/photochemical model. The composition of the PSCs was varied (ternary solutions, nitric acid trihydrate, nitric acid dehydrate, or ice), as were parameters that affected the levels of denitrification and dehydration. Ozone depletion was affected by assumptions about PSC freezing because of the variability in resultant nitrification chlorine activation in all scenarios was similar despite the range of assumed PSC compositions. Vortex-average ozone loss exceeded 40% in the lower stratosphere for simulations without nitrification an additional ozone loss of 15-20% was possible in scenarios where vortex-average nitrification reached 60%. Ozone loss intensifies non-linearly with enhanced nitrification in air parcels with 90% nitrification 40% ozone loss in mid-April can be attributed to nitrification alone. However, these effects are sensitive to the stability of the vortex in springtime: nitrification only began to influence ozone depletion in mid-March.

The modeled latitudinal distribution of the ozone quasi-biennial oscillation using observed equatorial winds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gray, L.J.; Ruth, S.

1993-04-15

A simulation of precise years of the quasi-biennial oscillation (QBO) is achieved in a two-dimensional model by relaxing the modeled equatorial winds in the lower stratosphere toward radiosonde observations. The model has been run for the period 1971-90. A QBO signal in column ozone is produced in the model that agrees reasonably well with observational data from the BUV, TOMS, and SAGE II satellite datasets. The model results confirm previous indications of the importance of the interaction of the QBO with the annual cycle in the determination of the subtropical ozone anomaly. The low-frequency modulation of the subtropical ozone anomalymore » is now particularly clear. The low-frequency modulation of the subtropical ozone anomaly in the model arises as a result of the interaction of the QBO with the annual cycle in the vertical advection by the Hadley circulation. The possibility of a further, similar modulation arising from the interaction of the equatorial wind QBO and the annual cycle in midlatitude eddy activity is discussed, with particular emphasis on the implications for the eddy transfer of ozone to high latitudes and on the ability to predict the severity of the Antarctic ozone hole. A link is proposed between the QBO signal in the severity of the Antarctic ozone hole and the amount of ozone observed in the subtropical/midlatitude springtime maximum in the Southern Hemisphere. On the basis of this relationship, the reliability of the model as a predictor of the severity of the ozone hole is explored. A conclusion of the study is that a reliable predictor of the severity of the ozone hole must take into account the timing of the descent of the equatorial wind QBO at the equator with respect to the annual cycle and that the use, as in previous studies, of a single parameter, such as the sign of the 50-mb equatorial wind, will not be entirely reliable because it cannot do this. 31 refs., 11 figs.« less

Decadal-Scale Responses in Middle and Upper Stratospheric Ozone From SAGE II Version 7 Data

NASA Technical Reports Server (NTRS)

Remsberg, E. E.

2014-01-01

Stratospheric Aerosol and Gas Experiment (SAGE II) version 7 (v7) ozone profiles are analyzed for their decadal-scale responses in the middle and upper stratosphere for 1991 and 1992-2005 and compared with those from its previous version 6.2 (v6.2). Multiple linear regression (MLR) analysis is applied to time series of its ozone number density vs. altitude data for a range of latitudes and altitudes. The MLR models that are fit to the time series data include a periodic 11 yr term, and it is in-phase with that of the 11 yr, solar UV (Ultraviolet)-flux throughout most of the latitude/ altitude domain of the middle and upper stratosphere. Several regions that have a response that is not quite in-phase are interpreted as being affected by decadal-scale, dynamical forcings. The maximum minus minimum, solar cycle (SClike) responses for the ozone at the low latitudes are similar from the two SAGE II data versions and vary from about 5 to 2.5% from 35 to 50 km, although they are resolved better with v7. SAGE II v7 ozone is also analyzed for 1984-1998, in order to mitigate effects of end-point anomalies that bias its ozone in 1991 and the analyzed results for 1991-2005 or following the Pinatubo eruption. Its SC-like ozone response in the upper stratosphere is of the order of 4%for 1984-1998 vs. 2.5 to 3%for 1991-2005. The SAGE II v7 results are also recompared with the responses in ozone from the Halogen Occultation Experiment (HALOE) that are in terms of mixing ratio vs. pressure for 1991-2005 and then for late 1992- 2005 to avoid any effects following Pinatubo. Shapes of their respective response profiles agree very well for 1992-2005. The associated linear trends of the ozone are not as negative in 1992-2005 as in 1984-1998, in accord with a leveling off of the effects of reactive chlorine on ozone. It is concluded that the SAGE II v7 ozone yields SC-like ozone responses and trends that are of better quality than those from v6.2.

Dynamic evaluation of CMAQ part I: Separating the effects of changing emissions and changing meteorology on ozone levels between 2002 and 2005 in the eastern US

EPA Science Inventory

A dynamic evaluation of the Community Multiscale Air Quality (CMAQ) modeling system version 5.0.1 was conducted to evaluate the model's ability to predict changes in ozone levels between 2002 and 2005, a time period characterized by emission reductions associated with the EPA's N...

Impact of downward-mixing ozone on surface ozone accumulation in southern Taiwan.

PubMed

Lin, Ching-Ho

2008-04-01

The ozone that initially presents in the previous day's afternoon mixing layer can remain in the nighttime atmosphere and then be carried over to the next morning. Finally, this ozone can be brought to the ground by downward mixing as mixing depth increases during the daytime, thereby increasing surface ozone concentrations. Variation of ozone concentration during each of these periods is investigated in this work. First, ozone concentrations existing in the daily early morning atmosphere at the altitude range of the daily maximum mixing depth (residual ozone concentrations) were measured using tethered ozonesondes on 52 experimental days during 2004-2005 in southern Taiwan. Daily downward-mixing ozone concentrations were calculated by a box model coupling the measured daily residual ozone concentrations and daily mixing depth variations. The ozone concentrations upwind in the previous day's afternoon mixing layer were estimated by the combination of back air trajectory analysis and known previous day's surface ozone distributions. Additionally, the relationship between daily downward-mixing ozone concentration and daily photochemically produced ozone concentration was examined. The latter was calculated by removing the former from daily surface maximum ozone concentration. The measured daily residual ozone concentrations distributed at 12-74 parts per billion (ppb) with an average of 42 +/- 17 ppb are well correlated with the previous upwind ozone concentration (R2 = 0.54-0.65). Approximately 60% of the previous upwind ozone was estimated to be carried over to the next morning and became the observed residual ozone. The daily downward-mixing ozone contributes 48 +/- 18% of the daily surface maximum ozone concentration, indicating that the downward-mixing ozone is as important as daily photochemically produced ozone to daily surface maximum ozone accumulation. The daily downward-mixing ozone is poorly correlated with the daily photochemically produced ozone and

UARS Microwave Limb Sounder Observations of Upper Atmosphere Ozone and Chlorine Monoxide

NASA Technical Reports Server (NTRS)

Flower, D.; Froidevaux, L.; Jarnot, R.; Read, W.; Waters, J.

1994-01-01

UARS MLS observations of stratospheric ozone and chlorine monoxide are described. Enhanced concentrations of ClO, the predominant form of reactive chlorine responsible for ozone depletion, are seen within both the northern and southern winter polar vortices. In the southern hemisphere, this leads directly to the development of the annual Antarctic ozone hole. While ozone depletion is also observed in the north, it is less severe and there is considerable interannual variability.

What would have happened to the ozone layer if chlorofluorocarbons (CFCs) had not been regulated?

NASA Astrophysics Data System (ADS)

Oman, L.; Newman, P. A.; Douglass, A. R.; Fleming, E. L.; Frith, S. M.; Hurwitz, M.; Kawa, S. R.; Jackman, C. H.; Krotkov, N. A.; Nash, E. R.; Nielsen, J. E.; Pawson, S.; Stolarski, R. S.; Velders, G. J.

2010-12-01

The Montreal Protocol on Substances that Deplete the Ozone Layer was negotiated in 1987 and by 2010 had been signed by all of the nations of the world. In this presentation we use a fully coupled radiation-chemical-dynamical model to simulate a future world where ozone depletion substances (ODSs) were never regulated. In this “world avoided” simulation, ODS levels increase by 3% per year. From 1980 to 2020 we find that 17% of the globally average column ozone is destroyed, and from 1980 to 2065 67% is destroyed. Severe polar depletions (e.g., the Antarctic ozone hole) become year-round rather than just seasonal. Ozone levels in the tropical lower stratosphere remain constant until about 2053 and then collapse to near zero by 2058 as a result of heterogeneous chemical processes (as currently observed in the Antarctic ozone hole). The tropical cooling that triggers the ozone collapse is caused by an increase of the tropical lower stratospheric upwelling. In response to ozone changes, ultraviolet (UV) radiation increases, tripling the erythemal (sunburn) radiation in the northern summer mid-latitudes by 2065.

Passive ozone network of Dallas: a modeling opportunity with community involvement. 2.

PubMed

Sather, M E; Varns, J L; Mulik, J D; Glen, G; Smith, L; Stallings, C

2001-11-15

Attaining the current lower tropospheric U.S. ozone standards continues to be a difficult task for many areas in the U.S. Concentrations of ozone above the standards negatively affects human health, agricultural crops, forests, and other ecosystem elements. This paper describes year two (1999) of a regional networking of passive and continuous ozone monitoring sites in the Dallas-Fort Worth (DFW) Metroplex region. The objectives of the second year of study were to (1) validate conclusions of the 1998 Passive Ozone Network of Dallas (POND) I study, (2) define the value of taking 12-h diurnal samples in addition to 24-h samples, and (3) add to the scientific knowledge base of rural/urban ozone comparison studies. Results of the POND II (1999) study demonstrated that ozone concentrations exceeding the new 8-h ozone standard could be recorded at least 130 km, or 80 miles, from the DFW Metroplex core in more rural areas. In addition, results of the POND II study indicated that ozone concentrations exceeding the 8-h standard probably occurred in areas recording a 12-h daytime ozone concentration above 60 parts per billion (ppb). The 12-h passive ozone data from POND II also suggests the relative magnitude of anthropogenic pollution influence could be assessed for rural passive ozone sites. The data from the POND II study provide modelers a rich database for future photochemical subgrid development for the DFW ozone nonattainment area. Indeed, the POND database provides a great amount of additional ozone ambient data covering 26 8-h and 13 1-h ozone standard exceedance days over an approximate 25000 km2 region. These data should help decrease uncertainties derived from future DFW ozone model exercises.

Tropical Tropospheric Ozone: New Insights from Remote Sensing and Field Studies

NASA Technical Reports Server (NTRS)

Thompson, Anne

1999-01-01

This talk will summarize our recent research in tropical tropospheric ozone studies in the field and from space. New tropospheric ozone and aerosol products from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument will be highlighted (Hudson and Thompson, 1998; Thompson and Hudson, 1999). These are suitable for studying processes like ozone pollution resulting from biomass fires, seasonal and interannual variations and trends. Archived maps of tropospheric ozone over the tropics, from the Nimbus 7 observing period (1979-1992) are available in digital form at our website. Real-time processing of TOMS data has produced images of tropical tropospheric ozone (TTO) since early 1997, using Earth-Probe TOMS; these maps are also available on the homepage.

Change in ozone trends at southern high latitudes

NASA Technical Reports Server (NTRS)

Yang, E.-S.; Cunnold, D. M.; Newchurch, M. J.; Salawitch, R. J.

2005-01-01

Long-term ozone variations at 60-70degS in spring are investigated using ground-based and satellite measurements. Strong positive correlation is shown between year-to-year variations of ozone and temperature in the Antarctic collar region in Septembers and Octobers. Based on this relationship, the effect of year-to-year variations in vortex dynamics has been filtered out. This process results in an ozone time series that shows increasing springtime ozone losses over the Antarctic until the mid-1990s. Since approximately 1997 the ozone losses have leveled off. The analysis confirms that this change is consistent across all instruments and is statistically significant at the 95% confidence level. This analysis quantifies the beginning of the recovery of the ozone hole, which is expected from the leveling off of stratospheric halogen loading due to the ban on CFCs and other halocarbons initiated by the Montreal Protocol.

Ozone vertical profile changes over South Pole

NASA Technical Reports Server (NTRS)

Oltmans, S. J.; Hofmann, D. J.; Komhyr, W. D.; Lathrop, J. A.

1994-01-01

Important changes in the ozone vertical profile over South Pole, Antarctica have occurred both during the recent period of measurements, 1986-1991, and since an earlier set of soundings was carried out from 1967-1971. From the onset of the 'ozone hole' over Antarctica in the early 1980s, there has been a tendency for years with lower spring ozone amounts to alternate with years with somewhat higher (although still depleted) ozone amounts. Beginning in 1989 there have been three consecutive years of strong depletion although the timing of the breakdown of the vortex has varied from year to year. Comparison of the vertical profiles between the two periods of study reveals the dramatic decreases in the ozone amounts in the stratosphere between 15-21 km during the spring. In addition, it appears that summer values are also now much lower in this altitude region.

Assimilation of MLS and OMI Ozone Data

NASA Technical Reports Server (NTRS)

Stajner, I.; Wargan, K.; Chang, L.-P.; Hayashi, H.; Pawson, S.; Froidevaux, L.; Livesey, N.

2005-01-01

Ozone data from Aura Microwave Limb Sounder (MLS) and Ozone Monitoring Instrument (OMI) were assimilated into the ozone model at NASA's Global Modeling and Assimilation Office (GMAO). This assimilation produces ozone fields that are superior to those from the operational GMAO assimilation of Solar Backscatter Ultraviolet (SBUV/2) instrument data. Assimilation of Aura data improves the representation of the "ozone hole" and the agreement with independent Stratospheric Aerosol and Gas Experiment (SAGE) III and ozone sonde data. Ozone in the lower stratosphere is captured better: mean state, vertical gradients, spatial and temporal variability are all improved. Inclusion of OMI and MLS data together, or separately, in the assimilation system provides a way of checking how consistent OMI and MLS data are with each other, and with the ozone model. We found that differences between OMI total ozone column data and model forecasts decrease after MLS data are assimilated. This indicates that MLS stratospheric ozone profiles are consistent with OMI total ozone columns. The evaluation of error characteristics of OMI and MLS ozone will continue as data from newer versions of retrievals becomes available. We report on the initial step in obtaining global assimilated ozone fields that combine measurements from different Aura instruments, the ozone model at the GMAO, and their respective error characteristics. We plan to use assimilated ozone fields in estimation of tropospheric ozone. We also plan to investigate impacts of assimilated ozone fields on numerical weather prediction through their use in radiative models and in the assimilation of infrared nadir radiance data from NASA's Advanced Infrared Sounder (AIRS).

Links between extreme UV-radiation, total ozone, surface albedo and cloudiness: An analysis of 30 years of data from Switzerland and Austria

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Weihs, P.; Vuilleumier, L.; Blumthaler, M.; Holawe, F.; Lindfors, A.; Maeder, J. A.; Simic, S.; Wagner, J. E.; Walker, D.; Ribatet, M.

2009-04-01

.: A composite study on the structure and formation of ozone miniholes and minihights over central Europe, J. Geophys. Res., 32, doi:10.1029/2004GL022062, 2005. Lindfors, A., and Vuilleumier, L.: Erythemal UV at Davos (Switzerland), 1926-2003, estimated using total ozone, sunshine duration, and snow depth, J. Geophys. Res., 110, D02104, doi:10.1029/2004JD005231, 2005. Molina, M. J., and Rowland, F. S.: Stratospheric sink for chlorofluoromethans: Chlorine atom-catalysed destruction of ozone, Nature, 249, 810-812, 1974. Rieder, H.E., Holawe, F., Simic, S., Blumthaler, M., Krzyscin, J.W., Wagner J.E., Schmalwieser A.W., and Weihs, P.: Reconstruction of erythemal UV-doses for two stations in Austria: A comparison between alpine and urban regions, Atmos. Chem. Phys., 8, 6309-6323, 2008. Rieder, H.E., Staehelin, J., Maeder, J.A., Ribatet, M., Stübi, R., Weihs, P., Holawe, F., Peter, T., and Davison, A.C.: From ozone mini holes and mini highs towards extreme value theory: New insights from extreme events and non stationarity, submitted to J. Geophys. Res., 2009. Staehelin, J., Kegel, R., and Harris, N. R.: Trend analysis of the homogenized total ozone series of Arosa (Switzerland), 1929-1996, J. Geophys. Res., 103(D7), 8389-8400, doi:10.1029/97JD03650, 1998a. Staehelin, J., Renaud, A., Bader, J., McPeters, R., Viatte, P., Hoegger, B., Bugnion, V., Giroud, M., and Schill, H.: Total ozone series at Arosa (Switzerland): Homogenization and data comparison, J. Geophys. Res., 103(D5), 5827-5842, doi:10.1029/97JD02402, 1998b.

Influence of El Niño-Southern Oscillation on the interannual variability of tropospheric ozone in the northern midlatitudes

NASA Astrophysics Data System (ADS)

Koumoutsaris, S.; Bey, I.; Generoso, S.; Thouret, V.

2008-10-01

We use the Goddard Earth Observing System Chem (GEOS-Chem) model to interpret long-term measurements of tropospheric ozone (O3) and carbon monoxide (CO) and to investigate the factors that contribute to their interannual variation (IAV) during the period from 1987 to 2005. The model reproduces relatively well the observed IAV of CO. The simulation of O3 IAV is not as successful. In particular, the negative anomalies in 1991-1993 and the following upward trend in 1993-1996 observed at several sites in the northern midlatitudes are not reproduced by the model, which may result from a poor representation of stratospheric chemistry and dynamics. We examine in detail the period of 1998-1999 when a large anomaly in tropospheric ozone column is observed and simulated over Europe (maximum of +4.9 Dobson units). Three consecutive periods can be distinguished from January 1998 to April 1999, during which different processes affected the O3 burden over Europe. Spring 1998 is largely influenced by the preceding 1997 El Niño that affects (1) stratosphere-troposphere exchange and (2) Asian pollution export and transport toward Europe by a change in convective activity in East Asia and a strengthening of the subtropical jet stream. An enhanced pollution export from North America is also noticed for this period. The second period (summer-fall 1998) shows a mixed influence from both boreal wildfires and Asian pollution. The third period is influenced by enhanced wildfires in Southeast Asia. Throughout the period from 1987 to 2005, positive anomalies in tropospheric O3 column and in surface O3 are found over Europe in the spring following an El Niño year.

Seasonal Changes in Tropospheric Ozone Concentrations over South Korea and Its Link to Ozone Precursors

NASA Astrophysics Data System (ADS)

Jung, H. C.; Moon, B. K.; Wie, J.

2017-12-01

Concentration of tropospheric ozone over South Korea has steadily been on the rise in the last decades, mainly due to rapid industrializing and urbanizing in the Eastern Asia. To identify the characteristics of tropospheric ozone in South Korea, we fitted a sine function to the surface ozone concentration data from 2005 to 2014. Based on fitted sine curves, we analyzed the shifts in the dates on which ozone concentration reached its peak in the calendar year. Ozone monitoring sites can be classified into type types: where the highest annual ozone concentration kept occurring sooner (Esites) and those that kept occurring later (Lsites). The seasonal analysis shows that the surface ozone had increased more rapidly in Esites than in Lsites in the past decade during springtime and vice-versa during summertime. We tried to find the reason for the different seasonal trends with the relationship between ozone and ozone precursors. As a result, it was found that the changes in the ground-level ozone concentration in the spring and summer times are considerably influenced by changes in nitrogen dioxide concentration, and this is closely linked to the destruction (production) process of ozone by nitrogen dioxide in spring (summer). The link between tropospheric ozone and nitrogen dioxide discussed in this study will have to be thoroughly examined through climate-chemistry modeling in the future. Acknowledgements This research was supported by the Korea Ministry of Environment (MOE) as "Climate Change Correspondence Program."

Particle Events as a Possible Source of Large Ozone Loss during Magnetic Polarity Transitions

NASA Technical Reports Server (NTRS)

vonKoenig, M.; Burrows, J. P.; Chipperfield, M. P.; Jackman, C. H.; Kallenrode, M.-B.; Kuenzi, K. F.; Quack, M.

2002-01-01

The energy deposition in the mesosphere and stratosphere during large extraterrestrial charged particle precipitation events has been known for some time to contribute to ozone losses due to the formation of potential ozone destroying species like NO(sub x), and HO(sub x). These impacts have been measured and can be reproduced with chemistry models fairly well. In the recent past, however, even the impact of the largest solar proton events on the total amount of ozone has been small compared to the dynamical variability of ozone, and to the anthropogenic induced impacts like the Antarctic 'ozone hole'. This is due to the shielding effect of the magnetic field. However, there is evidence that the earth's magnetic field may approach a reversal. This could lead to a decrease of magnetic field strength to less than 25% of its usual value over a period of several centuries . We show that with realistic estimates of very large solar proton events, scenarios similar to the Antarctic ozone hole of the 1990s may occur during a magnetic polarity transition.

Tropical Tropospheric Ozone: New Insights from Remote Sensing, Sondes and Field Studies

NASA Technical Reports Server (NTRS)

Thompson, Anne M.

1999-01-01

This talk will summarize our recent research in tropical tropospheric ozone studies in the field and from space. New tropospheric ozone and aerosol products from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument will be highlighted (Hudson and Thompson, 1998; Thompson and Hudson, 1999). These are suitable for studying processes like ozone pollution resulting from biomass fires, seasonal and interannual variations and trends. Archived maps of tropospheric ozone over the tropics, from the Nimbus 7 observing period (1979-1992) are available in digital form at our website: http://metosrv2.umd.edu/-tropo. Real-time processing of TOMS data has produced images of tropical tropospheric ozone (TTO) since early 1997, using Earth-Probe TOMS; these maps are also available on the homepage. The need for validation data for TTO maps has led to establishment of the NASA/NOAA-sponsored SHADOZ (Southern Hemisphere Additional Ozonesondes) network, from which a 2-year record of high-quality ozonesonde data can be obtained: (http://hyperion.gsfc.nasa.gov/Data-services/Shadoz/shadoz-hmpg2.htrnl). Examples will be shown, along with ozonesondes from the January-February 1999 Aerosols-99 cruise of the R/V Ronald H Brown from Virginia to Cape Town, South Africa.

Children's and Adults' Knowledge and Models of Reasoning about the Ozone Layer and Its Depletion.

ERIC Educational Resources Information Center

Leighton, Jacqueline P.; Bisanz, Gay L.

2003-01-01

Examines children's and adults' knowledge of the ozone layer and its depletion, whether this knowledge increases with age, and how the ozone layer and ozone hole might be structured as scientific concepts. Uses a standardized set of questions to interview children and adults in Canada. Discusses implications of the results for health…

Total ozone patterns over the northern mid-latitudes: spatial correlations, extreme events and dynamical contributions

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Ribatet, M.; Bodeker, G. E.; Davison, A. C.

2009-04-01

Tools from geostatistics and extreme value theory are applied to analyze spatial correlations in total ozone for the northern mid-latitudes. The dataset used in this study is the NIWA combined total ozone dataset (Bodeker et al., 2001; Müller et al., 2008). New tools from extreme value theory (Coles, 2001; Ribatet, 2007) have recently been applied to the world's longest total ozone record from Arosa, Switzerland (e.g. Staehelin 1998a,b), in order to describe extreme events in low and high total ozone (Rieder et al., 200x). Within the current study, patterns in spatial correlation and frequency distributions of extreme events (e.g. ELOs and EHOs) are studied for the northern mid-latitudes. New insights in spatial patterns of total ozone for the northern mid-latitudes are presented. Koch et al. (2005) found that the increase in fast isentropic transport of tropical air to northern mid-latitudes contributed significantly to ozone changes between 1980 and 1989. Within this study the influence of changes in atmospheric dynamics (e.g. tropospheric and lower stratospheric pressure systems) on column ozone over the northern mid-latitudes is analyzed for the time period 1979-2007. References: Bodeker, G.E., J.C. Scott, K. Kreher, and R.L. McKenzie, Global ozone trends in potential vorticity coordinates using TOMS and GOME intercompared against the Dobson network: 1978-1998, J. Geophys. Res., 106 (D19), 23029-23042, 2001. Coles, S.: An Introduction to Statistical Modeling of Extreme Values, Springer Series in Statistics, ISBN:1852334592, Springer, Berlin, 2001. Koch, G., H. Wernli, C. Schwierz, J. Staehelin, and T. Peter (2005), A composite study on the structure and formation of ozone miniholes and minihighs over central Europe, Geophys. Res. Lett., 32, L12810, doi:10.1029/2004GL022062. Müller, R., Grooß, J.-U., Lemmen, C., Heinze, D., Dameris, M., and Bodeker, G.: Simple measures of ozone depletion in the polar stratosphere, Atmos. Chem. Phys., 8, 251-264, 2008. Ribatet

Satellite Observations of Enhanced Tropospheric Ozone Associated with Biomass Burning in Africa and Madagascar

NASA Technical Reports Server (NTRS)

Aikin, A. C.; Ziemke, J. R.; Thorpe, A.; Einaudi, Franco (Technical Monitor)

2000-01-01

Tropospheric ozone over Africa and Madagascar is enhanced by 10 to 15 DU in October. This maximum coincides with the time of maximum biomass area burning in Africa and Madagascar. Ozone observations were made from 1979 to 1999 using the TOMS tropospheric ozone convective cloud differential method. As a result of easterly trade winds, ozone originating on Madagascar is transported to the west over the Mozambique Channel. In El Nino years higher level westerly winds descend to transport low level ozone easterly. This results in African continental ozone being transported east of Madagascar. Long range transport of African ozone is observed during El Nino periods.

Ozone Temperature Correlations in the Upper Stratosphere as a Measure of Chlorine Content

NASA Technical Reports Server (NTRS)

Stolarski, Richard S.; Douglass, Ann R.; Remsberg, Ellis E.; Livesey, Nathaniel J.; Gille, John C.

2012-01-01

We use data from the Nimbus-7 Limb Infrared Monitor of the Stratosphere (LIMS) for the 1978-1979 period together with data from the Upper Atmosphere Research Satellite Microwave Limb Sounder (UARS MLS) for the years 1993 to 1999, the Aura MLS for the years 2004 to 2011, and the Aura High Resolution Infrared Limb Sounder (HIRDLS) for the years 2005 to 2007 to examine ozone-temperature correlations in the upper stratosphere. Our model simulations indicate that the sensitivity coefficient of the ozone response to temperature (Delta ln(O3)/Delta.(l/T)) decreases as chlorine has increased in the stratosphere and should increase in the future as chlorine decreases. The data are in agreement with our simulation of the past. We also find that the sensitivity coefficient does not change in a constant-chlorine simulation. Thus the change in the sensitivity coefficient depends on the change in chlorine, but not on the change in greenhouse gases. We suggest that these and future data can be used to track the impact of chlorine added to the stratosphere and also to track the recovery of the stratosphere as chlorine is removed under the provisions of the Montreal Protocol.

Influence of isentropic transport on seasonal ozone variations in the lower stratosphere and subtropical upper troposphere

NASA Technical Reports Server (NTRS)

Jing, P.; Cunnold, D. M.; Yang, E.-S.; Wang, H.-J.

2005-01-01

The isentropic cross-tropopause ozone transport has been estimated in both hemispheres in 1999 based on the potential vorticity mapping of Stratospheric Aerosol and Gas Experiment 11 ozone measurements and contour advection calculations using the NASA Goddard Space Flight Center Global and Modeling Assimilation Office analysis. The estimated net isentropic stratosphere-to-troposphere ozone flux is approx.118 +/- 61 x 10(exp9)kg/yr globally within the layer between 330 and 370 K in 1999; 60% of it is found in the Northern Hemisphere, and 40% is found in the Southern Hemisphere. The monthly average ozone fluxes are strongest in summer and weakest in winter in both hemispheres. The seasonal variations of ozone in the lower stratosphere (LS) and upper troposphere (UT) have been analyzed using ozonesonde observations from ozonesonde stations in the extratropics and subtropics, respectively. It is shown that observed ozone levels increase in the UT over subtropical ozonesonde stations and decrease in the LS over extratropical stations in late spring/early summer and that the ozone increases in the summertime subtropical UT are unlikely to be explained by photochemical ozone production and diabatic transport alone. We conclude that isentropic transport is a significant contributor to ozone levels in the subtropical upper troposphere, especially in summer.

On Springtime Ozone Enhancements in the Lower Troposphere Over Beijing

NASA Astrophysics Data System (ADS)

Huang, J.; Liu, H.; Chan, C.; Crawford, J. H.; Considine, D. B.; Zhang, Y.; Zheng, X.; Oltmans, S. J.; Liu, S. C.; Thouret, V.

2012-12-01

Tropospheric ozone is an important greenhouse gas, the primary source of hydroxyl radical (OH) that controls the tropospheric oxidizing capacity, and a major air pollutant near the surface. Previous studies showed that ozone concentrations in the lower troposphere (LT) over Beijing have increased over the past two decades as a result of rapid industrialization in China. As part of an ozonesonde sounding campaign, called Transport of Air Pollutants and Tropospheric Ozone over China (TAPTO-China), intensive measurements of ozone vertical profiles (16 in total) were conducted in Beijing during April 11 - May 15, 2005. Thirteen vertical profiles were also sampled by the Measurement of Ozone and Water Vapor by Airbus In-Service Aircraft (MOZAIC) program during April 3 - May 29, 2005. High ozone concentrations (up to 94.7 ppbv) were frequently observed in the LT (~1.5-2km) during this period. We evaluate here the capability of a 3-D chemical transport model (GEOS-Chem at 2°x2.5° resolution) to reproduce these ozone enhancements, and use the model to examine transport pathways for ozone pollution and quantify their sources. The model captures the occurrences but significantly underestimates the magnitude of ozone enhancements. By tagging ozone produced in different source regions and conducting sensitivity simulations with the model, we show that Asian troposphere and Asian anthropogenic pollution made the major contributions to those ozone enhancements. Contributions from European and North American troposphere and anthropogenic pollution reduced during these events, compared to those days without ozone enhancements. We find that most of the ozone enhancements observed in the LT occurred under southerly wind and warmer conditions. Their occurrence frequency appears to be related to the onset of Asian summer monsoon. The influence of regional transport from different source regions in East Asia will also be discussed.

As polar ozone mends, UV shield closer to equator thins

NASA Astrophysics Data System (ADS)

Reese, April

2018-02-01

Thirty years after nations banded together to phase out chemicals that destroy stratospheric ozone, the gaping hole in Earth's ultraviolet radiation shield above Antarctica is shrinking. But new findings suggest that at midlatitudes, where most people live, the ozone layer in the lower stratosphere is growing more tenuous—for reasons that scientists are struggling to fathom. In an analysis published this week, researchers found that from 1998 to 2016, ozone in the lower stratosphere ebbed by 2.2 Dobson units—a measure of ozone thickness—even as concentrations in the upper stratosphere rose by about 0.8 Dobson units. The culprit may be ozone-eating chemicals such as dichloromethane that break down within 6 months after escaping into the air.

Comparing Model Ozone Loss during the SOLVE and SOLVE-2 Winters

NASA Technical Reports Server (NTRS)

Drdla, K.

2003-01-01

Model simulations have been used to analyze the factors influencing ozone loss during the 1999-2000 and 2002-2003 js. For both winters, the evolution of the Arctic vortex from November to April has been simulated using a trajectory-based microphysical and photochemical model. Extensive PSC formation and strong ozone depletion are evident in both winters. However, the ozone loss begins earlier in the 2002-2003 winter, with significant ozone depletion by early January. Analysis of the model results shows that during December 2002 not only cold temperatures but also the vortex structure was critical, allowing PSC-processed air parcels to experience significant solar exposure. The resultant ozone loss can be differentiated from ozone loss that occurs in the springtime, in particular because of the continued exposure to PSCs. For example, chlorine reactivation by the PSCs causes ozone loss to be insensitive to denitrification. Therefore, diagnosing the extent of ozone loss early in the winter is critical In understanding the overall winter-long ozone depletion.

Children's Models of Understanding of Two Major Global Environmental Issues (Ozone Layer and Greenhouse Effect).

ERIC Educational Resources Information Center

Boyes, Edward; Stanisstreet, Martin

1997-01-01

Aims to quantify the models that 13- and 14 year-old students hold about the causes of the greenhouse effect and ozone layer depletion. Assesses the prevalence of those ideas that link the two phenomena. Twice as many students think that holes in the ozone layer cause the greenhouse effect than think the greenhouse effect causes ozone depletion.…

Looking at Ozone From a New Angle: Shuttle Ozone Limb Sounding Experiment-2 (SOLSE-2)

NASA Technical Reports Server (NTRS)

McPeters, Richard; Hilsenrath, Ernest; Janz, Scott; Brown, Tammy (Technical Monitor)

2002-01-01

The ozone layer above Earth is our planet's fragile sunscreen, protecting people, vegetation, and wildlife. NASA has been measuring ozone for more than 20 years by looking down, but SOLSE-2 will show that more information is available by looking at ozone from the side, at Earth's limb or atmospheric boundary. When the ozone layer is compromised, increased ultraviolet (UV) levels from the sun cause health problems ranging from severe sunburns to skin cancer and cataracts. A concerted global effort has been made to reduce or eliminate the production of chemicals that deplete ozone, but the ozone layer is not expected to recover for many decades because these chemicals can remain active in the atmosphere for up to 100 years. We know now that ozone monitoring needs to be focused in the lower stratosphere. The discovery of the ozone hole in 1985 demonstrated that very large changes in ozone were occurring in the lower stratosphere near 20 km, instead of the upper stratosphere as first expected, and where current ozone instruments are focused. Measuring ozone from a tangential perspective that is centered at the limb provides ozone profiles concentrated in the lower stratosphere. The first flight of SOLSE proved that this technique achieves the accuracy and coverage of traditional measurements, and surpasses the altitude resolution and depth of retrieval of conventional techniques. Results from the first flight convinced the science community to design the next generation ozone monitoring satellite based on SOLSE. The Ozone Mapping and Profiling Suite (OMPS) is currently being built for the NPOESS satellite. The primary objective of SOLSE-2 is to confirm the promising results of the first flight over a wider range of viewing conditions and spectral wavelengths. Sometimes a really hard problem can be solved when you look at it from a different angle! While scientists conduct research, protect yourself by observing the UV index and spend less unprotected time outdoors.

Drift-corrected Odin-OSIRIS ozone product: algorithm and updated stratospheric ozone trends

NASA Astrophysics Data System (ADS)

Bourassa, Adam E.; Roth, Chris Z.; Zawada, Daniel J.; Rieger, Landon A.; McLinden, Chris A.; Degenstein, Douglas A.

2018-01-01

A small long-term drift in the Optical Spectrograph and Infrared Imager System (OSIRIS) stratospheric ozone product, manifested mostly since 2012, is quantified and attributed to a changing bias in the limb pointing knowledge of the instrument. A correction to this pointing drift using a predictable shape in the measured limb radiance profile is implemented and applied within the OSIRIS retrieval algorithm. This new data product, version 5.10, displays substantially better both long- and short-term agreement with Microwave Limb Sounder (MLS) ozone throughout the stratosphere due to the pointing correction. Previously reported stratospheric ozone trends over the time period 1984-2013, which were derived by merging the altitude-number density ozone profile measurements from the Stratospheric Aerosol and Gas Experiment (SAGE) II satellite instrument (1984-2005) and from OSIRIS (2002-2013), are recalculated using the new OSIRIS version 5.10 product and extended to 2017. These results still show statistically significant positive trends throughout the upper stratosphere since 1997, but at weaker levels that are more closely in line with estimates from other data records.

Future heat waves and surface ozone

NASA Astrophysics Data System (ADS)

Meehl, Gerald A.; Tebaldi, Claudia; Tilmes, Simone; Lamarque, Jean-Francois; Bates, Susan; Pendergrass, Angeline; Lombardozzi, Danica

2018-06-01

A global Earth system model is used to study the relationship between heat waves and surface ozone levels over land areas around the world that could experience either large decreases or little change in future ozone precursor emissions. The model is driven by emissions of greenhouse gases and ozone precursors from a medium-high emission scenario (Representative Concentration Pathway 6.0–RCP6.0) and is compared to an experiment with anthropogenic ozone precursor emissions fixed at 2005 levels. With ongoing increases in greenhouse gases and corresponding increases in average temperature in both experiments, heat waves are projected to become more intense over most global land areas (greater maximum temperatures during heat waves). However, surface ozone concentrations on future heat wave days decrease proportionately more than on non-heat wave days in areas where ozone precursors are prescribed to decrease in RCP6.0 (e.g. most of North America and Europe), while surface ozone concentrations in heat waves increase in areas where ozone precursors either increase or have little change (e.g. central Asia, the Mideast, northern Africa). In the stabilized ozone precursor experiment, surface ozone concentrations increase on future heat wave days compared to non-heat wave days in most regions except in areas where there is ozone suppression that contributes to decreases in ozone in future heat waves. This is likely associated with effects of changes in isoprene emissions at high temperatures (e.g. west coast and southeastern North America, eastern Europe).

What would have happened to the ozone layer if chlorofluorocarbons (CFCs) had not been regulated?

NASA Astrophysics Data System (ADS)

Newman, P. A.; Oman, L. D.; Douglass, A. R.; Fleming, E. L.; Frith, S. M.; Hurwitz, M. M.; Kawa, S. R.; Jackman, C. H.; Krotkov, N. A.; Nash, E. R.; Nielsen, J. E.; Pawson, S.; Stolarski, R. S.; Velders, G. J.

2008-12-01

Ozone depletion by chlorofluorocarbons (CFCs) was first proposed by Molina and Rowland in their 1974 Nature paper. Since that time, the scientific connection between ozone losses and CFCs and other ozone depleting substances (ODSs) has been firmly established with laboratory measurements, atmospheric observations, and modeling research. The nations of the world implemented the Montreal Protocol (and amendments) which stopped ODS production in 1992. In this presentation we use a fully coupled radiation- chemical-dynamical model to simulate a future world where ODSs were never regulated and ODS production grew at an annual rate of 3%. In this "world avoided" simulation, 17% of the globally average column ozone is destroyed by 2020, and 67% is destroyed by 2065 in comparison to 1980. Large ozone depletions in the polar region become year-round rather than just seasonal as is currently observed in the Antarctic ozone hole. Very large temperature decreases are observed in response to circulation changes and decreased shortwave radiation absorption by ozone. Ozone levels in the tropical lower stratosphere remain constant until about 2053 and then collapse to near zero by 2058 as a result of heterogeneous chemical processes (as currently observed in the Antarctic ozone hole). The tropical cooling that triggers the ozone collapse is caused by an increase of the tropical upwelling. In response to ozone changes, ultraviolet (UV) radiation increases, tripling the erythemal (sunburn) radiation in the northern summer mid-latitudes by 2065.

Use of cigarettes and other tobacco products among students aged 13-15 years--worldwide, 1999-2005.

PubMed

2006-05-26

The use of tobacco in any form is a major preventable cause of premature death and disease. Globally, nearly 5 million persons die every year from tobacco-related illnesses, with disproportionately higher mortality occurring in developing countries. The Global Youth Tobacco Survey (GYTS), initiated in 1999 by the World Health Organization (WHO), CDC, and the Canadian Public Health Association, is a school-based survey that includes questions on prevalence of cigarette and other tobacco use; attitudes toward tobacco; access to tobacco products; exposure to secondhand smoke, school curricula on tobacco, media, and advertising; and smoking cessation. This report presents estimates of self-reported cigarette and other tobacco-product use during 1999-2005 in 132 different countries and the Gaza Strip/West Bank. The data are aggregated within each of the six WHO regions. GYTS data indicate that nearly two of every 10 students reported currently using a tobacco product, with no statistically significant difference between the proportion of those reporting cigarette smoking (8.9%) and other tobacco use (11.2%). Use of tobacco by adolescents is a major public health problem in all six WHO regions. Worldwide, more countries need to develop, implement, and evaluate their tobacco-control programs to address the use of all types of tobacco products, especially among girls.

The ocean's role in polar climate change: asymmetric Arctic and Antarctic responses to greenhouse gas and ozone forcing

PubMed Central

Marshall, John; Armour, Kyle C.; Scott, Jeffery R.; Kostov, Yavor; Hausmann, Ute; Ferreira, David; Shepherd, Theodore G.; Bitz, Cecilia M.

2014-01-01

In recent decades, the Arctic has been warming and sea ice disappearing. By contrast, the Southern Ocean around Antarctica has been (mainly) cooling and sea-ice extent growing. We argue here that interhemispheric asymmetries in the mean ocean circulation, with sinking in the northern North Atlantic and upwelling around Antarctica, strongly influence the sea-surface temperature (SST) response to anthropogenic greenhouse gas (GHG) forcing, accelerating warming in the Arctic while delaying it in the Antarctic. Furthermore, while the amplitude of GHG forcing has been similar at the poles, significant ozone depletion only occurs over Antarctica. We suggest that the initial response of SST around Antarctica to ozone depletion is one of cooling and only later adds to the GHG-induced warming trend as upwelling of sub-surface warm water associated with stronger surface westerlies impacts surface properties. We organize our discussion around ‘climate response functions’ (CRFs), i.e. the response of the climate to ‘step’ changes in anthropogenic forcing in which GHG and/or ozone-hole forcing is abruptly turned on and the transient response of the climate revealed and studied. Convolutions of known or postulated GHG and ozone-hole forcing functions with their respective CRFs then yield the transient forced SST response (implied by linear response theory), providing a context for discussion of the differing warming/cooling trends in the Arctic and Antarctic. We speculate that the period through which we are now passing may be one in which the delayed warming of SST associated with GHG forcing around Antarctica is largely cancelled by the cooling effects associated with the ozone hole. By mid-century, however, ozone-hole effects may instead be adding to GHG warming around Antarctica but with diminished amplitude as the ozone hole heals. The Arctic, meanwhile, responding to GHG forcing but in a manner amplified by ocean heat transport, may continue to warm at an

The ocean's role in polar climate change: asymmetric Arctic and Antarctic responses to greenhouse gas and ozone forcing.

PubMed

Marshall, John; Armour, Kyle C; Scott, Jeffery R; Kostov, Yavor; Hausmann, Ute; Ferreira, David; Shepherd, Theodore G; Bitz, Cecilia M

2014-07-13

In recent decades, the Arctic has been warming and sea ice disappearing. By contrast, the Southern Ocean around Antarctica has been (mainly) cooling and sea-ice extent growing. We argue here that interhemispheric asymmetries in the mean ocean circulation, with sinking in the northern North Atlantic and upwelling around Antarctica, strongly influence the sea-surface temperature (SST) response to anthropogenic greenhouse gas (GHG) forcing, accelerating warming in the Arctic while delaying it in the Antarctic. Furthermore, while the amplitude of GHG forcing has been similar at the poles, significant ozone depletion only occurs over Antarctica. We suggest that the initial response of SST around Antarctica to ozone depletion is one of cooling and only later adds to the GHG-induced warming trend as upwelling of sub-surface warm water associated with stronger surface westerlies impacts surface properties. We organize our discussion around 'climate response functions' (CRFs), i.e. the response of the climate to 'step' changes in anthropogenic forcing in which GHG and/or ozone-hole forcing is abruptly turned on and the transient response of the climate revealed and studied. Convolutions of known or postulated GHG and ozone-hole forcing functions with their respective CRFs then yield the transient forced SST response (implied by linear response theory), providing a context for discussion of the differing warming/cooling trends in the Arctic and Antarctic. We speculate that the period through which we are now passing may be one in which the delayed warming of SST associated with GHG forcing around Antarctica is largely cancelled by the cooling effects associated with the ozone hole. By mid-century, however, ozone-hole effects may instead be adding to GHG warming around Antarctica but with diminished amplitude as the ozone hole heals. The Arctic, meanwhile, responding to GHG forcing but in a manner amplified by ocean heat transport, may continue to warm at an accelerating rate.

Tropical Tropospheric Ozone: A Multi-Satellite View From TOMS and Other Instruments

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Hudson, Robert D.; Guo, Hua; Witte, Jacquelyn C.; Kucsera, Tom L.; Seybold, Matthew G.; Einaudi, Franco (Technical Monitor)

2000-01-01

New tropospheric ozone and aerosol products from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument can resolve episodic pollution events in the tropics and interannual and seasonal variability. Modified-residual (MR) Nimbus 7 tropical tropospheric ozone (TTO), two maps/month (1979-1992, 1-deg latitude by 2-deg longitude) within the region in which total ozone displays a tropical wave-one pattern (maximum 20S to 20N), are available in digital form at http://metosrv2.umd.edu/tropo. Also available are preliminary 1996-1999 MR-TTO maps based on real-time Earth-Probe (EP)/TOMS observations. Examples of applications are given.

Persistent polar depletion of stratospheric ozone and emergent mechanisms of ultraviolet radiation-mediated health dysregulation.

PubMed

Dugo, Mark A; Han, Fengxiang; Tchounwou, Paul B

2012-01-01

Year 2011 noted the first definable ozone "hole" in the Arctic region, serving as an indicator to the continued threat of dangerous ultraviolet radiation (UVR) exposure caused by the deterioration of stratospheric ozone in the northern hemisphere. Despite mandates of the Montreal Protocol to phase out the production of ozone-depleting chemicals (ODCs), the relative stability of ODCs validates popular notions of persistent stratospheric ozone for several decades. Moreover, increased UVR exposure through stratospheric ozone depletion is occurring within a larger context of physiologic stress and climate change across the biosphere. In this review, we provide commentaries on stratospheric ozone depletion with relative comparisons between the well-known Antarctic ozone hole and the newly defined ozone hole in the Arctic. Compared with the Antarctic region, the increased UVR exposure in the Northern Hemisphere poses a threat to denser human populations across North America, Europe, and Asia. In this context, we discuss emerging targets of UVR exposure that can potentially offset normal biologic rhythms in terms of taxonomically conserved photoperiod-dependent seasonal signaling and entrainment of circadian clocks. Consequences of seasonal shifts during critical life history stages can alter fitness and condition, whereas circadian disruption is increasingly becoming associated as a causal link to increased carcinogenesis. We further review the significance of genomic alterations via UVR-induced modulations of phase I and II transcription factors located in skin cells, the aryl hydrocarbon receptor (AhR), and the nuclear factor (erythroid-derived 2)-related factor 2 (Nrf2), with emphasis on mechanism that can lead to metabolic shifts and cancer. Although concern for adverse health consequences due to increased UVR exposure are longstanding, recent advances in biochemical research suggest that AhR and Nrf2 transcriptional regulators are likely targets for UVR

Stratospheric ClO and ozone from the Microwave Limb Sounder on the Upper Atmosphere Research Satellite

NASA Technical Reports Server (NTRS)

Waters, J. W.; Froidevaux, L.; Read, W. G.; Manney, G. L.; Elson, L. S.; Flower, D. A.; Jarnot, R. F.; Harwood, R. S.

1993-01-01

Concentrations of atmospheric ozone and of ClO (the predominant form of reactive chlorine responsible for stratospheric ozone depletion) are reported for both the Arctic and Antarctic winters of the past 18 months. Chlorine in the lower stratosphere was almost completely converted to chemically reactive forms in both the northern and southern polar winter vortices. This occurred in the south long before the development of the Antarctic ozone hole, suggesting that ozone loss can be masked by influx of ozone-rich air.

Changing dental caries and periodontal disease patterns among a cohort of Ethiopian immigrants to Israel: 1999–2005

PubMed Central

Vered, Yuval; Zini, Avi; Livny, Alon; Mann, Jonathan; Sgan-Cohen, Harold D

2008-01-01

Background Dental epidemiology has indicated that immigrants and minority ethnic groups should be regarded as high risk populations on the verge of oral health deterioration. The objectives of this study were to measure the changing pattern of dental caries, periodontal health status and tooth cleaning behaviour among a cohort of Ethiopian immigrants to Israel between the years 1999–2005. Methods Increment of dental caries and periodontal health status was recorded among a cohort of 672 Ethiopian immigrants, utilizing the DMFT and CPI indices. Data were gathered during 1999–2000 and five years later, during 2004–2005. Participants were asked about their oral hygiene habits in Ethiopia and in Israel five years since their immigration. Results Regarding dental caries, at baseline 70.1% of the examinees were caries-free, as compared to 57.3% after five years. DMFT had increased from 1.48 to 2.31. For periodontal health status, at baseline, 94.7% demonstrated no periodontal pockets (CPI scores 0–2) and 5.3% revealed periodontal pockets (CPI scores 3&4), compared to 75.6% and 24.4%, respectively after five years. At baseline, 74% reported cleaning their teeth exclusively utilizing chewing and cleaning sticks common in Ethiopia. After five years, 97% reported cleaning their teeth exclusively utilizing toothbrushes. Conclusion The deterioration in the oral health status, especially the alarming and significant worsening of periodontal health status, among this immigrant group, emphasizes the need for health promotion and maintenance among immigrants and minority groups in changing societies. An "acclimatizing and integrating" model of oral health promotion among minority and immigrant groups is suggested. PMID:18828927

Investigation of the Short-Time Variability of Tropical Tropospheric Ozone

NASA Technical Reports Server (NTRS)

Randriambelo, Tantely; Baray, Jean-Luc; Baldy, Serge; Thompson, Anne M.; Oltmans, Samuel; Keckhut, Philippe

2003-01-01

Since 1998, a ground based tropospheric ozone lidar has been running at Reunion Island and has been involved with a daily measurement campaign that was performed in the latter part of the biomass burning season, during November-December 1999. The averaged ozone profile obtained during November-December 1 999 agrees well with averaged ozone profile obtained from ozonesondes launch at Reunion during November-December (1992- 2001). Comparing weekly sonde launches (part of the Southern Hemisphere Additional Ozonesondes: SHADOZ program) with the daily ground-based lidar observations shows that some striking features of the day to day variability profiles are not observed in the sonde measurements. Ozone profiles respond to the nature of disturbances which vary from the one day to the next. The vertical ozone distribution at Reunion is examined as a function of prevailing atmospheric circulation. Backtrajectories show that most of the enhanced ozone crossed over biomass burning and convectively active regions in Madagascar and the southern African continent. The analyses of the meteorological data show that ozone stratification profiles are in agreement with the movement of the synoptical situations in November-December 1999. Three different sequences of transport are explained using wind fields. The first sequence from 23 to 25 November is characterized by Northerly transport, the second sequence from 26 to 30 November, the air masses are influenced by meridional transport. The third sequence from 2 to 6 December is characterized by westerly transport associated with the subtropical jet stream. The large standard deviations of lidar profiles in the middle and upper troposphere are in agreement with the upper wind variabilities which evidence passing ridge and trough disturbances. During the transition period between the dry season and the wet season, multiple ozone sources including stratosphere-troposphere exchanges, convection and biomass burning contribute to

What Would Have Happened to the Ozone Layer if Chlorofluorocarbons (CFCs) had not been Regulated?

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Oman, L. D.; Douglass, A. R.; Fleming, E. L.; Frith, S. M.; Hurwitz, M. M.; Kawa, S. R.; Jackman, C. H.; Krotkov, N. A.; Nash, E. R.;

Interannual (1999-2005) morphodynamic evolution of macro-tidal salt marshes in Mont-Saint-Michel Bay (France)

NASA Astrophysics Data System (ADS)

Détriché, Sébastien; Susperregui, Anne-Sophie; Feunteun, Eric; Lefeuvre, Jean-Claude; Jigorel, Alain

2011-04-01

This paper provides a detailed study on the sedimentation patterns and the recent morphodynamic evolution affecting the macro-tidal salt marshes located west of the Mont-Saint-Michel (France). Twenty-two stations along three transects on the marshes were seasonally monitored for marsh surface level variations from 1999 to 2005, using a sediment erosion bar. The corresponding erosion/accretion rates were obtained together with data on topography, vegetation cover, and grain size of surface sediment. To examine the mechanisms contributing to the salt marsh sedimentation, the data and their evolution were treated with respect to tides, relative mean regional sea level, and wind speed/frequency variations. From 1999 to 2005, the marsh was globally accreting (from 3.45 to 38.11 mm yr -1 in the low marsh, up to 4.91 mm yr -1 in the middle marsh, and up to 1.35 mm yr -1 in the high marsh), while the study was conducted during a window of decreasing trend in mean regional sea level (-2.45 mm yr -1 according to regional-averaged time series). These sedimentation rates are one of the highest recorded worldwide; however, the sedimentation was not found to be continuous over the period in question. This pattern is illustrated by the strong extension of the marshes from 1999 to 2002, and the relative stability observed from 2003 to 2005. The imported and reworked sediments are trapped and fixed by the dense vegetation ( Puccinellia maritima, Halimione portulacoides), inducing the general seaward extension of the marshes. The processes governing sediment budget (accretion/erosion) show annual, seasonal, and spatial variability on the marsh. Spatial variations display contrasted patterns of erosion/sedimentation between the low, middle, and high marsh, and between the different transects. These patterns are a result of distance from sediment sources, strong heterogeneity in vegetation cover (human induced or not), and contrasting topographic and micro-topographic characteristics

The search for signs of recovery of the ozone layer.

PubMed

Weatherhead, Elizabeth C; Andersen, Signe Bech

2006-05-04

Evidence of mid-latitude ozone depletion and proof that the Antarctic ozone hole was caused by humans spurred policy makers from the late 1980s onwards to ratify the Montreal Protocol and subsequent treaties, legislating for reduced production of ozone-depleting substances. The case of anthropogenic ozone loss has often been cited since as a success story of international agreements in the regulation of environmental pollution. Although recent data suggest that total column ozone abundances have at least not decreased over the past eight years for most of the world, it is still uncertain whether this improvement is actually attributable to the observed decline in the amount of ozone-depleting substances in the Earth's atmosphere. The high natural variability in ozone abundances, due in part to the solar cycle as well as changes in transport and temperature, could override the relatively small changes expected from the recent decrease in ozone-depleting substances. Whatever the benefits of the Montreal agreement, recovery of ozone is likely to occur in a different atmospheric environment, with changes expected in atmospheric transport, temperature and important trace gases. It is therefore unlikely that ozone will stabilize at levels observed before 1980, when a decline in ozone concentrations was first observed.

Latitudinal gradients in O3 and CO during INDOEX 1999

NASA Astrophysics Data System (ADS)

Stehr, J. W.; Ball, W. P.; Dickerson, R. R.; Doddridge, B. G.; Piety, C. A.; Johnson, J. E.

2002-10-01

Measurements of ozone and carbon monoxide (CO) from the INDOEX 1999 experiment show large differences in concentrations of ozone and CO between the Northern Hemisphere and the Southern Hemisphere. These measurements confirm the theory that the Intertropical Convergence Zone (ITCZ) serves as a barrier to mixing over the Indian Ocean, effectively separating the polluted air in the Northern Hemisphere from cleaner air in the Southern Hemisphere. In spite of CO levels similar to those observed off the coast of North America, there is relatively little ozone off the coast of India. The ozone-to-CO ratio in air coming from India is 0.14, lower than 0.3 or 0.4 in air being transported to Bermuda from North America. Diurnal cycles are observed in both CO and ozone. INDOEX data taken onboard the R/V Ronald H. Brown show an average diurnal cycle in ozone of 20%, while data from the island of Kaashidhoo in the Republic of Maldives indicate a diurnal variation of 19%, consistent with our analyses of other experiments. Diurnal variations of this magnitude are larger than expected from ozone destruction by conventional HOx chemistry alone, implying that the sink of ozone in the remote marine boundary layer is likely considerably larger than had been assumed. Additional chemical cycles must be fairly substantial—large enough to rival HOx chemistry in ozone destruction.

Observation of ozone and aerosols in the Antarctic ozone hole of 1991 under the Polar Patrol Balloon (PPB) Project. Preliminary result

NASA Technical Reports Server (NTRS)

Hayashi, Masahiko; Murata, Isao; Iwasaka, Yasunobu; Kondo, Yutaka; Kanzawa, Hiroshi

1994-01-01

We present preliminary results for the PPB (Polar Patrol Balloon) experiment. The balloon was launched at 07:55 UT on 23 September and dropped at 21 UT on 28 September 1991. During the period, ozone and aerosol concentrations were measured correspondingly along the track. During the Lagrangian type observation, drastic change of ozone concentration in 'same air mass' and positive correlation between ozone concentration and sulfate aerosol amount were obtained at the level within 80-78 hPa. During the descent motion at 80 deg S active PSC's (type-1 and -2) were observed from 200 hPa to 80 hPa.

Observing the Impact of Calbuco Volcanic Aerosols on South Polar Ozone Depletion in 2015

NASA Astrophysics Data System (ADS)

Stone, Kane A.; Solomon, Susan; Kinnison, Doug E.; Pitts, Michael C.; Poole, Lamont R.; Mills, Michael J.; Schmidt, Anja; Neely, Ryan R.; Ivy, Diane; Schwartz, Michael J.; Vernier, Jean-Paul; Johnson, Bryan J.; Tully, Matthew B.; Klekociuk, Andrew R.; König-Langlo, Gert; Hagiya, Satoshi

2017-11-01

The Southern Hemisphere Antarctic stratosphere experienced two noteworthy events in 2015: a significant injection of sulfur from the Calbuco volcanic eruption in Chile in April and a record-large Antarctic ozone hole in October and November. Here we quantify Calbuco's influence on stratospheric ozone depletion in austral spring 2015 using observations and an Earth system model. We analyze ozonesondes, as well as data from the Microwave Limb Sounder. We employ the Community Earth System Model, version 1, with the Whole Atmosphere Community Climate Model (WACCM) in a specified dynamics setup, which includes calculations of volcanic effects. The Cloud-Aerosol Lidar with Orthogonal Polarization data indicate enhanced volcanic liquid sulfate 532 nm backscatter values as far poleward as 68°S during October and November (in broad agreement with WACCM). Comparison of the location of the enhanced aerosols to ozone data supports the view that aerosols played a major role in increasing the ozone hole size, especially at pressure levels between 150 and 100 hPa. Ozonesonde vertical ozone profiles from the sites of Syowa, South Pole, and Neumayer display the lowest individual October or November measurements at 150 hPa since the 1991 Mount Pinatubo eruption period, with Davis showing similarly low values, but no available 1990 data. The analysis suggests that under the cold conditions ideal for ozone depletion, stratospheric volcanic aerosol particles from the moderate-magnitude eruption of Calbuco in 2015 greatly enhanced austral ozone depletion, particularly at 55-68°S, where liquid binary sulfate aerosols have a large influence on ozone concentrations.

Statistical methods and regression analysis of stratospheric ozone and meteorological variables in Isfahan

NASA Astrophysics Data System (ADS)

Hassanzadeh, S.; Hosseinibalam, F.; Omidvari, M.

2008-04-01

Data of seven meteorological variables (relative humidity, wet temperature, dry temperature, maximum temperature, minimum temperature, ground temperature and sun radiation time) and ozone values have been used for statistical analysis. Meteorological variables and ozone values were analyzed using both multiple linear regression and principal component methods. Data for the period 1999-2004 are analyzed jointly using both methods. For all periods, temperature dependent variables were highly correlated, but were all negatively correlated with relative humidity. Multiple regression analysis was used to fit the meteorological variables using the meteorological variables as predictors. A variable selection method based on high loading of varimax rotated principal components was used to obtain subsets of the predictor variables to be included in the linear regression model of the meteorological variables. In 1999, 2001 and 2002 one of the meteorological variables was weakly influenced predominantly by the ozone concentrations. However, the model did not predict that the meteorological variables for the year 2000 were not influenced predominantly by the ozone concentrations that point to variation in sun radiation. This could be due to other factors that were not explicitly considered in this study.

Ozone Climatological Profiles for Version 8 TOMS and SBUV Retrievals

NASA Technical Reports Server (NTRS)

McPeters, R. D.; Logan, J. A.; Labow, G. J.

2003-01-01

A new altitude dependent ozone climatology has been produced for use with the latest Total Ozone Mapping Spectrometer (TOMS) and Solar Backscatter Ultraviolet (SBUV) retrieval algorithms. The climatology consists of monthly average profiles for ten degree latitude zones covering from 0 to 60 km. The climatology was formed by combining data from SAGE II (1988 to 2000) and MLS (1991-1999) with data from balloon sondes (1988-2002). Ozone below about 20 km is based on balloons sondes, while ozone above 30 km is based on satellite measurements. The profiles join smoothly between 20 and 30 km. The ozone climatology in the southern hemisphere and tropics has been greatly enhanced in recent years by the addition of balloon sonde stations under the SHADOZ (Southern Hemisphere Additional Ozonesondes) program. A major source of error in the TOMS and SBUV retrieval of total column ozone comes from their reduced sensitivity to ozone in the lower troposphere. An accurate climatology for the retrieval a priori is important for reducing this error on the average. The new climatology follows the seasonal behavior of tropospheric ozone and reflects its hemispheric asymmetry. Comparisons of TOMS version 8 ozone with ground stations show an improvement due in part to the new climatology.

Ozone Monitoring Instrument Observations of Interannual Increases in SO2 Emissions from Indian Coal-fired Power Plants During 2005-2012

NASA Technical Reports Server (NTRS)

Lu, Zifeng; Streets, David D.; de Foy, Benjamin; Krotkov, Nickolay A.

2014-01-01

Due to the rapid growth of electricity demand and the absence of regulations, sulfur dioxide (SO2) emissions from coal-fired power plants in India have increased notably in the past decade. In this study, we present the first interannual comparison of SO2 emissions and the satellite SO2 observations from the Ozone Monitoring Instrument (OMI) for Indian coal-fired power plants during the OMI era of 2005-2012. A detailed unit-based inventory is developed for the Indian coal-fired power sector, and results show that its SO2 emissions increased dramatically by 71 percent during 2005-2012. Using the oversampling technique, yearly high-resolution OMI maps for the whole domain of India are created, and they reveal a continuous increase in SO2 columns over India. Power plant regions with annual SO2 emissions greater than 50 Gg year-1 produce statistically significant OMI signals, and a high correlation (R equals 0.93) is found between SO2 emissions and OMI-observed SO2 burdens. Contrary to the decreasing trend of national mean SO2 concentrations reported by the Indian Government, both the total OMI-observed SO2 and average SO2 concentrations in coal-fired power plant regions increased by greater than 60 percent during 2005-2012, implying the air quality monitoring network needs to be optimized to reflect the true SO2 situation in India.

Ozone monitoring instrument observations of interannual increases in SO2 emissions from Indian coal-fired power plants during 2005-2012.

PubMed

Lu, Zifeng; Streets, David G; de Foy, Benjamin; Krotkov, Nickolay A

2013-12-17

Due to the rapid growth of electricity demand and the absence of regulations, sulfur dioxide (SO2) emissions from coal-fired power plants in India have increased notably in the past decade. In this study, we present the first interannual comparison of SO2 emissions and the satellite SO2 observations from the Ozone Monitoring Instrument (OMI) for Indian coal-fired power plants during the OMI era of 2005-2012. A detailed unit-based inventory is developed for the Indian coal-fired power sector, and results show that its SO2 emissions increased dramatically by 71% during 2005-2012. Using the oversampling technique, yearly high-resolution OMI maps for the whole domain of India are created, and they reveal a continuous increase in SO2 columns over India. Power plant regions with annual SO2 emissions greater than 50 Gg year(-1) produce statistically significant OMI signals, and a high correlation (R = 0.93) is found between SO2 emissions and OMI-observed SO2 burdens. Contrary to the decreasing trend of national mean SO2 concentrations reported by the Indian Government, both the total OMI-observed SO2 and annual average SO2 concentrations in coal-fired power plant regions increased by >60% during 2005-2012, implying the air quality monitoring network needs to be optimized to reflect the true SO2 situation in India.

Extreme events in total ozone over Arosa - Part 1: Application of extreme value theory

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Peter, T.; Ribatet, M.; Davison, A. C.; Stübi, R.; Weihs, P.; Holawe, F.

2010-10-01

In this study ideas from extreme value theory are for the first time applied in the field of stratospheric ozone research, because statistical analysis showed that previously used concepts assuming a Gaussian distribution (e.g. fixed deviations from mean values) of total ozone data do not adequately address the structure of the extremes. We show that statistical extreme value methods are appropriate to identify ozone extremes and to describe the tails of the Arosa (Switzerland) total ozone time series. In order to accommodate the seasonal cycle in total ozone, a daily moving threshold was determined and used, with tools from extreme value theory, to analyse the frequency of days with extreme low (termed ELOs) and high (termed EHOs) total ozone at Arosa. The analysis shows that the Generalized Pareto Distribution (GPD) provides an appropriate model for the frequency distribution of total ozone above or below a mathematically well-defined threshold, thus providing a statistical description of ELOs and EHOs. The results show an increase in ELOs and a decrease in EHOs during the last decades. The fitted model represents the tails of the total ozone data set with high accuracy over the entire range (including absolute monthly minima and maxima), and enables a precise computation of the frequency distribution of ozone mini-holes (using constant thresholds). Analyzing the tails instead of a small fraction of days below constant thresholds provides deeper insight into the time series properties. Fingerprints of dynamical (e.g. ENSO, NAO) and chemical features (e.g. strong polar vortex ozone loss), and major volcanic eruptions, can be identified in the observed frequency of extreme events throughout the time series. Overall the new approach to analysis of extremes provides more information on time series properties and variability than previous approaches that use only monthly averages and/or mini-holes and mini-highs.

Extreme events in total ozone over Arosa - Part 1: Application of extreme value theory

NASA Astrophysics Data System (ADS)

Rieder, H. E.; Staehelin, J.; Maeder, J. A.; Peter, T.; Ribatet, M.; Davison, A. C.; Stübi, R.; Weihs, P.; Holawe, F.

2010-05-01

In this study ideas from extreme value theory are for the first time applied in the field of stratospheric ozone research, because statistical analysis showed that previously used concepts assuming a Gaussian distribution (e.g. fixed deviations from mean values) of total ozone data do not adequately address the structure of the extremes. We show that statistical extreme value methods are appropriate to identify ozone extremes and to describe the tails of the Arosa (Switzerland) total ozone time series. In order to accommodate the seasonal cycle in total ozone, a daily moving threshold was determined and used, with tools from extreme value theory, to analyse the frequency of days with extreme low (termed ELOs) and high (termed EHOs) total ozone at Arosa. The analysis shows that the Generalized Pareto Distribution (GPD) provides an appropriate model for the frequency distribution of total ozone above or below a mathematically well-defined threshold, thus providing a statistical description of ELOs and EHOs. The results show an increase in ELOs and a decrease in EHOs during the last decades. The fitted model represents the tails of the total ozone data set with high accuracy over the entire range (including absolute monthly minima and maxima), and enables a precise computation of the frequency distribution of ozone mini-holes (using constant thresholds). Analyzing the tails instead of a small fraction of days below constant thresholds provides deeper insight into the time series properties. Fingerprints of dynamical (e.g. ENSO, NAO) and chemical features (e.g. strong polar vortex ozone loss), and major volcanic eruptions, can be identified in the observed frequency of extreme events throughout the time series. Overall the new approach to analysis of extremes provides more information on time series properties and variability than previous approaches that use only monthly averages and/or mini-holes and mini-highs.

A Contribution Toward Understanding the Biospherical Significance of Antarctic Ozone Depletion

NASA Astrophysics Data System (ADS)

Lubin, Dan; Mitchell, B. Greg; Frederick, John E.; Alberts, Amy D.; Booth, C. R.; Lucas, Timothy; Neuschuler, David

1992-05-01

Measurements of biologically active UV radiation made by the National Science Foundation (NSF) scanning spectroradiometer (UV-monitor) at Palmer Station, Antarctica, during the Austral springs of 1988, 1989, and 1990 are presented and compared. Column ozone abundance above Palmer Station is computed from these measurements using a multiple wavelength algorithm. Two contrasting action spectra (biological weighting functions) are used to estimate the biologically relevant dose from the spectral measurements: a standard weighting function for damage to DNA, and a new action spectrum representing the potential for photosynthesis inhibition in Antarctic phytoplankton. The former weights only UV-B wavelengths (280-320 nm) and gives the most weight to wavelengths shorter than 300 nm, while the latter includes large contributions out to 355 nm. The latter is the result of recent Antarctic field work and is relevant in that phytoplankton constitute the base of the Antarctic food web. The modest ozone hole of 1988, in which the ozone abundance above Palmer Station never fell below 200 Dobson units (DU), brought about summerlike doses of DNA-effective UV radiation 2 months early, but UV doses which could inhibit photosynthesis in phytoplankton did not exceed a clear-sky "maximum normal" dose for that time of year. The severe ozone holes of 1989 and 1990, in which the ozone abundance regularly fell below 200 DU, brought about increases in UV surface irradiance weighted by either action spectrum. Ozone abundances and dose-weighted irradiances provided by the NSF UV-monitor are used to derive the radiation amplification factors (RAFs) for both DNA-effective irradiance and phytoplankton-effective irradiance. The RAF for DNA-effective irradiance is nonlinear in ozone abundance and is in excess of the popular "two for one" rule, while the RAF for phytoplankton-effective irradiance approximately follows a "one for one" rule.

The Application of TOMS Ozone, Aerosol and UV-B Data to Madagascar Air Quality Determination

NASA Technical Reports Server (NTRS)

Aikin, A.C.; Einaudi, Franco (Technical Monitor)

2000-01-01

Total Ozone Mapping Spectrometer (TOMS) data products for the area of Madagascar are presented. In addition to total ozone, aerosols and UV-B tropospheric ozone results are shown from 1979 to the present. Tropospheric ozone over Africa and Madagascar is enhanced by 10 to 15 DU in October. This maximum coincides with the time of maximum biomass area burning in Africa and Madagascar. Ozone observations were made from 1979 to 1999 using the TOMS tropospheric ozone convective cloud differential method. As a result of easterly trade winds, ozone originating on Madagascar is transported to the west over the Mozambique Channel. In El Nino years higher level westerly winds descend to transport low level ozone easterly. This results in African continental ozone being transported east of Madagascar. Long range transport of African ozone is observed during El Nino periods. The potential of TOMS and other space data for use in public education and research on Madagascar air quality is demonstrated.

Atmospheric ozone and colors of the Antarctic twilight sky.

PubMed

Lee, Raymond L; Meyer, Wolfgang; Hoeppe, Götz

2011-10-01

Zenith skylight is often distinctly blue during clear civil twilights, and much of this color is due to preferential absorption at longer wavelengths by ozone's Chappuis bands. Because stratospheric ozone is greatly depleted in the austral spring, such decreases could plausibly make Antarctic twilight colors less blue then, including at the zenith. So for several months in 2005, we took digital images of twilight zenith and antisolar skies at Antarctica's Georg von Neumayer Station. Our colorimetric analysis of these images shows only weak correlations between ozone concentration and twilight colors. We also used a spectroradiometer at a midlatitude site to measure zenith twilight spectra and colors. At both locations, spectral extinction by aerosols seems as important as ozone absorption in explaining colors seen throughout the twilight sky.

Pesticides and nitrate in groundwater underlying citrus croplands, Lake Wales Ridge, central Florida, 1999-2005.

USGS Publications Warehouse

Choquette, Anne F.

2014-01-01

This report summarizes pesticide and nitrate (as nitrogen) results from quarterly sampling of 31 surficial-aquifer wells in the Lake Wales Ridge Monitoring Network during April 1999 through January 2005. The wells, located adjacent to citrus orchards and used for monitoring only, were generally screened (sampled) within 5 to 40 feet of the water table. Of the 44 citrus pesticides and pesticide degradates analyzed, 17 were detected in groundwater samples. Parent pesticides and degradates detected in quarterly groundwater samples, ordered by frequency of detection, included norflurazon, demethyl norflurazon, simazine, diuron, bromacil, aldicarb sulfone, aldicarb sulfoxide, deisopropylatrazine (DIA), imidacloprid, metalaxyl, thiazopyr monoacid, oxamyl, and aldicarb. Reconnaissance sampling of five Network wells yielded detection of four additional pesticide degradates (hydroxysimazine, didealkylatrazine, deisopropylhydroxyatrazine, and hydroxyatrazine). The highest median concentration values per well, based on samples collected during the 1999–2005 period (n=14 to 24 samples per well), included 3.05 µg/L (micrograms per liter) (simazine), 3.90 µg/L (diuron), 6.30 µg/L (aldicarb sulfone), 6.85 µg/L (aldicarb sulfoxide), 22.0 µg/L (demethyl norflurazon), 25.0 µg/ (norflurazon), 89 µg/ (bromacil), and 25.5 mg/L (milligrams per liter) (nitrate). Nitrate concentrations exceeded the 10 mg/L (as nitrogen) drinking water standard in one or more groundwater samples from 28 of the wells, and the median nitrate concentration among these wells was 14 mg/L. Sampled groundwater pesticide concentrations exceeded Florida’s health-guidance benchmarks for aldicarb sulfoxide and aldicarb sulfone (4 wells), the sum of aldicarb and its degradates (6 wells), simazine (2 wells), the sum of simazine and DIA (3 wells), diuron (2 wells), bromacil (1 well), and the sum of norflurazon and demethyl norflurazon (1 well). The magnitude of fluctuations in groundwater pesticide

The influence of climate change and the timing of stratospheric warmings on Arctic ozone depletion

NASA Astrophysics Data System (ADS)

Austin, John; Butchart, Neal

1994-01-01

Satellite data are presented showing the timing of sudden warmings in the lower stratosphere during the winters 1979-1992. A three-dimensional dynamical-radiative-photochemical model is used to establish how Arctic ozone depletion will respond to a doubling of CO2 according to the timing of the warmings. In a series of idealized experiments the timing of the warmings is varied by specifying different geopotential wave amplitudes at the 316-mbar model lower boundary. Results from a "transient climate change experiment" show that the chosen wave amplitudes are appropriate for both the current and the doubled CO2 atmosphere. For doubled CO2 the experiments show that any significant risk of an Arctic ozone hole will be confined to those years with only a late stratospheric warming. In all other years the results suggest that springtime total ozone over the Arctic is more likely to increase by a small amount due to a combination of slower homogeneous chemistry and changes in transport. The predictions obtained from the idealized studies are then tested by prescribing at the model lower boundary the observed geopotential wave amplitudes from two specific years with late winter warmings. Doubling CO2 amounts produced no significant increase in ozone depletion with the 1989 wave amplitudes, but with 1990 wave amplitudes, an Arctic ozone hole occurred with minimum column of 187 Dobson Units. This contrasting response is attributed to the large midwinter pulse in the 1989 wave amplitudes compared to the less dramatic and shorter timescale fluctuations in the 1990 wave amplitudes. It is concluded that under doubled CO2 conditions an Arctic ozone hole is likely to occur in years with late stratospheric warmings following winters in which there were no significant pulses in the upper tropospheric planetary wave amplitudes.

Air Quality Criteria for Ozone and Related Photochemical Oxidants (First External Review Draft)

EPA Science Inventory

This first external review draft of the Air Quality Criteria for Ozone and Related Photochemical Oxidants (Ozone Criteria Document) is being released in January 2005 for public comment and for review by EPA's Clean A...

Balloon-borne observations of the development and vertical structure of the Antarctic ozone hole in 1986

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Harder, J. W.; Rolf, S. R.; Rosen, J. M.

1987-01-01

The vertical distribution of ozone measured at McMurdo Station, Antarctica using balloon-borne sensors on 33 occasions during November 6, 1986 - August 25, 1986 is described. These observations suggest a highly structured cavity confined to the 12-20 km altitude region. In the 17-19 km altitude range, the ozone volume mixing ratio declined from about 2 ppm at the end of August to about 0.5 ppm by mid-October. The average decay in this region can be described as exponential with a half life of about 25 days. While total ozone, as obtained from profile integration, declined only about 35 percent, the integrated ozone between 14 and 18 km declined more than 70 percent. Vertical ozone profiles in the vortex revealed unusual structure with major features from 1 to 5 km thick which had suffered ozone depletions as great as 90 percent.

Organic pollutants removal in wastewater by heterogeneous photocatalytic ozonation.

PubMed

Xiao, Jiadong; Xie, Yongbing; Cao, Hongbin

2015-02-01

Heterogeneous photocatalysis and ozonation are robust advanced oxidation processes for eliminating organic contaminants in wastewater. The combination of these two methods is carried out in order to enhance the overall mineralization of refractory organics. An apparent synergism between heterogeneous photocatalysis and ozonation has been demonstrated in many literatures, which gives rise to an improvement of total organic carbon removal. The present overview dissects the heterogeneous catalysts and the influences of different operational parameters, followed by the discussion on the kinetics, mechanism, economic feasibility and future trends of this integrated technology. The enhanced oxidation rate mainly results from a large amount of hydroxyl radicals generated from a synergistically induced decomposition of dissolved ozone, besides superoxide ion radicals and the photo-induced holes. Six reaction pathways possibly exist for the generation of hydroxyl radicals in the reaction mechanism of heterogeneous photocatalytic ozonation. Copyright © 2014 Elsevier Ltd. All rights reserved.

An overview af SAGE I and II ozone measurements

NASA Technical Reports Server (NTRS)

Mccormick, M. P.; Zawodny, J. M.; Veiga, R. E.; Larsen, J. C.; Wang, P. H.

1989-01-01

The stratospheric Aerosol and Gas Experiments (SAGE) I and II measure Mie, Rayleigh, and gaseous extinction profiles using the solar occultation technique. These global measurements yield ozone profiles with a vertical resolution of 1 km which have been routinely obtained for the periods from February 1979 to November 1981 (SAGE I) and October 1984 to the present (SAGE II). The long-term periodic behavior of the measured ozone is presented as well as case studies of the observed short-term spatial and temporal variability. A linear regression shows annual, semiannual, and quasi-biennial oscillation features at various altitudes and latitudes which, in general, agree with past work. Also, ozone, aerosol, and water vapor data are described for the Antarctic springtime, showing large variation relative to the vortex. Cross-sections in latitude and altitude and polar plots at various altitudes clearly delineate the ozone hole vertically and areally.

Hybrid UV-Ozone-Treated rGO-PEDOT:PSS as an Efficient Hole Transport Material in Inverted Planar Perovskite Solar Cells

NASA Astrophysics Data System (ADS)

Wang, Shuying; Huang, Xiaona; Sun, Haoxuan; Wu, Chunyang

2017-12-01

Inverted planar perovskite solar cells (PSCs), which are regarded as promising devices for new generation of photovoltaic systems, show many advantages, such as low-temperature film formation, low-cost fabrication, and smaller hysteresis compared with those of traditional n-i-p PSCs. As an important carrier transport layer in PSCs, the hole transport layer (HTL) considerably affects the device performance. Therefore, HTL modification becomes one of the most critical issues in improving the performance of PSCs. In this paper, we report an effective and environmentally friendly UV-ozone treatment method to enhance the hydrophilia of reduced graphene oxide (rGO) with its excellent electrical performance. The treated rGO was applied to doped poly(3,4-ethylenedioxythiophene) poly(styrene-sulfonate) (PEDOT:PSS) as HTL material of PSCs. Consequently, the performance of rGO/PEDOT:PSS-doped PSCs was improved significantly, with power conversion efficiency (PCE) of 10.7%, Jsc of 16.75 mA/cm2, Voc of 0.87 V, and FF of 75%. The PCE of this doped PSCs was 27% higher than that of the PSCs with pristine PEDOT:PSS as HTL. This performance was attributed to the excellent surface morphology and optimized hole mobility of the solution-processable rGO-modified PEDOT:PSS.

An unusual stratospheric ozone decrease in the Southern Hemisphere subtropics linked to isentropic air-mass transport as observed over Irene (25.5° S, 28.1° E) in mid-May 2002

NASA Astrophysics Data System (ADS)

Semane, N.; Bencherif, H.; Morel, B.; Hauchecorne, A.; Diab, R. D.

2006-06-01

A prominent ozone minimum of less than 240 Dobson Units (DU) was observed over Irene (25.5° S, 28.1° E), a subtropical site in the Southern Hemisphere, by the Total Ozone Mapping Spectrometer (TOMS) during May 2002 with an extremely low ozone value of less than 219 DU recorded on 12 May, as compared to the climatological mean value of 249 DU for May between 1999 and 2005. In this study, the vertical structure of this ozone minimum is examined using ozonesonde measurements performed over Irene on 15 May 2002, when the total ozone (as given by TOMS) was about 226 DU. It is shown that this ozone minimum is of Antarctic polar origin with a low-ozone layer in the middle stratosphere above 625 K (where the climatological ozone gradient points equatorward), and is of tropical origin with a low-ozone layer in the lower stratosphere between the 400-K and 450-K isentropic levels (where the climatological ozone gradient is reversed). The upper and lower depleted parts of the ozonesonde profile for 15 May are then respectively attributed to equatorward and poleward transport of low-ozone air toward the subtropics in the Southern Hemisphere. The tropical air moving over Irene and the polar one passing over the same area associated with enhanced planetary-wave activity are successfully simulated using the high-resolution advection contour model of Ertel's potential vorticity MIMOSA. The unusual distribution of ozone over Irene during May 2002 in the middle stratosphere is connected to the anomalously pre-conditioned structure of the polar vortex at that time of the year. The winter stratospheric wave driving leading to the ozone minimum is investigated by means of the Eliassen-Palm flux computed from the European Center for Medium-range Weather Forecasts (ECMWF) ERA40 re-analyses.

Identification of influential events concerning the Antarctic ozone hole over southern Brazil and the biological effects induced by UVB and UVA radiation in an endemic treefrog species.

PubMed

Passaglia Schuch, André; Dos Santos, Mauricio Beux; Mendes Lipinski, Victor; Vaz Peres, Lucas; Dos Santos, Caroline Peripolli; Zanini Cechin, Sonia; Jorge Schuch, Nelson; Kirsh Pinheiro, Damaris; da Silva Loreto, Elgion Lúcio

2015-08-01

The increased incidence of solar ultraviolet radiation (UV) due to ozone depletion has been affecting both terrestrial and aquatic ecosystems and it may help to explain the enigmatic decline of amphibian populations in specific localities. In this work, influential events concerning the Antarctic ozone hole were identified in a dataset containing 35 years of ozone measurements over southern Brazil. The effects of environmental doses of UVB and UVA radiation were addressed on the morphology and development of Hypsiboas pulchellus tadpole (Anura: Hylidae), as well as on the induction of malformation after the conclusion of metamorphosis. These analyzes were complemented by the detection of micronucleus formation in blood cells. 72 ozone depletion events were identified from 1979 to 2013. Surprisingly, their yearly frequency increased three-fold during the last 17 years. The results clearly show that H. pulchellus tadpole are much more sensitive to UVB than UVA light, which reduces their survival and developmental rates. Additionally, the rates of micronucleus formation by UVB were considerably higher compared to UVA even after the activation of photolyases enzymes by a further photoreactivation treatment. Consequently, a higher occurrence of malformation was observed in UVB-irradiated individuals. These results demonstrate the severe genotoxic impact of UVB radiation on this treefrog species and its importance for further studies aimed to assess the impact of the increased levels of solar UVB radiation on declining species of the Hylidae family. Copyright © 2015 Elsevier Inc. All rights reserved.

Ensemble simulations of the role of the stratosphere in the attribution of northern extratropical tropospheric ozone variability

NASA Astrophysics Data System (ADS)

Hess, P.; Kinnison, D.; Tang, Q.

2015-03-01

Despite the need to understand the impact of changes in emissions and climate on tropospheric ozone, the attribution of tropospheric interannual ozone variability to specific processes has proven difficult. Here, we analyze the stratospheric contribution to tropospheric ozone variability and trends from 1953 to 2005 in the Northern Hemisphere (NH) mid-latitudes using four ensemble simulations of the free running (FR) Whole Atmosphere Community Climate Model (WACCM). The simulations are externally forced with observed time-varying (1) sea-surface temperatures (SSTs), (2) greenhouse gases (GHGs), (3) ozone depleting substances (ODS), (4) quasi-biennial oscillation (QBO), (5) solar variability (SV) and (6) stratospheric sulfate surface area density (SAD). A detailed representation of stratospheric chemistry is simulated, including the ozone loss due to volcanic eruptions and polar stratospheric clouds. In the troposphere, ozone production is represented by CH4-NOx smog chemistry, where surface chemical emissions remain interannually constant. Despite the simplicity of its tropospheric chemistry, at many NH measurement locations, the interannual ozone variability in the FR WACCM simulations is significantly correlated with the measured interannual variability. This suggests the importance of the external forcing applied in these simulations in driving interannual ozone variability. The variability and trend in the simulated 1953-2005 tropospheric ozone from 30 to 90° N at background surface measurement sites, 500 hPa measurement sites and in the area average are largely explained on interannual timescales by changes in the 30-90° N area averaged flux of ozone across the 100 hPa surface and changes in tropospheric methane concentrations. The average sensitivity of tropospheric ozone to methane (percent change in ozone to a percent change in methane) from 30 to 90° N is 0.17 at 500 hPa and 0.21 at the surface; the average sensitivity of tropospheric ozone to the 100 h

Response of Antarctic sea surface temperature and sea ice to ozone depletion

NASA Astrophysics Data System (ADS)

Ferreira, D.; Gnanadesikan, A.; Kostov, Y.; Marshall, J.; Seviour, W.; Waugh, D.

2017-12-01

The influence of the Antarctic ozone hole extends all the way from the stratosphere through the troposphere down to the surface, with clear signatures on surface winds, and SST during summer. In this talk we discuss the impact of these changes on the ocean circulation and sea ice state. We are notably motivated by the observed cooling of the surface Southern Ocean and associated increase in Antarctic sea ice extent since the 1970s. These trends are not reproduced by CMIP5 climate models, and the underlying mechanism at work in nature and the models remain unexplained. Did the ozone hole contribute to the observed trends?Here, we review recent advances toward answering these issues using "abrupt ozone depletion" experiments. The ocean and sea ice response is rather complex, comprising two timescales: a fast ( 1-2y) cooling of the surface ocean and sea ice cover increase, followed by a slower warming trend, which, depending on models, flip the sign of the SST and sea ice responses on decadal timescale. Although the basic mechanism seems robust, comparison across climate models reveal large uncertainties in the timescales and amplitude of the response to the extent that even the sign of the ocean and sea ice response to ozone hole and recovery remains unconstrained. After briefly describing the dynamics and thermodynamics behind the two-timescale response, we will discuss the main sources of uncertainties in the modeled response, namely cloud effects and air-sea heat exchanges, surface wind stress response and ocean eddy transports. Finally, we will consider the implications of our results on the ability of coupled climate models to reproduce observed Southern Ocean changes.

Potential For Stratospheric Ozone Depletion During Carboniferous

NASA Astrophysics Data System (ADS)

Bill, M.; Goldstein, A. H.

Methyl bromide (CH3Br) constitutes the largest source of bromine atoms to the strato- sphere whereas methyl chloride (CH3Cl) is the most abundant halocarbon in the tro- posphere. Both gases play an important role in stratospheric ozone depletion. For in- stance, Br coupled reactions are responsible for 30 to 50 % of total ozone loss in the polar vortex. Currently, the largest natural sources of CH3Br and CH3Cl appear to be biological production in the oceans, inorganic production during biomass burning and plant production in salt marsh ecosystems. Variations of paleofluxes of CH3Br and CH3Cl can be estimated by analyses of oceanic paleoproductivity, stratigraphic analyses of frequency and distribution of fossil charcoal indicating the occurrence of wildfires, and/or by paleoreconstruction indicating the extent of salt marshes. Dur- ing the lower Carboniferous time (Tournaisian-Visean), the southern margin of the Laurasian continent was characterized by charcoal deposits. Estimation on frequency of charcoal layers indicates that wildfires occur in a range of 3-35 years (Falcon-Lang 2000). This suggests that biomass burning could be an important source of CH3Br and CH3Cl during Tournaisian-Viesan time. During Tounaisian and until Merame- cian carbon and oxygen isotope records have short term oscillations (Bruckschen et al. 1999, Mii et al. 1999). Chesterian time (mid- Carboniferous) is marked by an in- crease in delta18O values ( ~ 2 permil) and an increase of glacial deposit frequency suggesting lower temperatures. The occurrence of glacial deposits over the paleopole suggests polar conditions and the associated special features of polar mete- orology such as strong circumpolar wind in the stratosphere (polar vortex) and polar stratospheric clouds. Thus, conditions leading to polar statospheric ozone depletion can be found. Simultaneously an increase in delta13C values is documented. We interpret the positive shift in delta13C as a result of higher bioproductivity

Spatio-temporal observations of tertiary ozone maximum

NASA Astrophysics Data System (ADS)

Sofieva, V. F.; Kyrölä, E.; Verronen, P. T.; Seppälä, A.; Tamminen, J.; Marsh, D. R.; Smith, A. K.; Bertaux, J.-L.; Hauchecorne, A.; Dalaudier, F.; Fussen, D.; Vanhellemont, F.; Fanton D'Andon, O.; Barrot, G.; Guirlet, M.; Fehr, T.; Saavedra, L.

2009-03-01

We present spatio-temporal distributions of tertiary ozone maximum (TOM), based on GOMOS (Global Ozone Monitoring by Occultation of Stars) ozone measurements in 2002-2006. The tertiary ozone maximum is typically observed in the high-latitude winter mesosphere at altitude ~72 km. Although the explanation for this phenomenon has been found recently - low concentrations of odd-hydrogen cause the subsequent decrease in odd-oxygen losses - models have had significant deviations from existing observations until recently. Good coverage of polar night regions by GOMOS data has allowed for the first time obtaining spatial and temporal observational distributions of night-time ozone mixing ratio in the mesosphere. The distributions obtained from GOMOS data have specific features, which are variable from year to year. In particular, due to a long lifetime of ozone in polar night conditions, the downward transport of polar air by the meridional circulation is clearly observed in the tertiary ozone maximum time series. Although the maximum tertiary ozone mixing ratio is achieved close to the polar night terminator (as predicted by the theory), TOM can be observed also at very high latitudes, not only in the beginning and at the end, but also in the middle of winter. We have compared the observational spatio-temporal distributions of tertiary ozone maximum with that obtained using WACCM (Whole Atmosphere Community Climate Model) and found that the specific features are reproduced satisfactorily by the model. Since ozone in the mesosphere is very sensitive to HOx concentrations, energetic particle precipitation can significantly modify the shape of the ozone profiles. In particular, GOMOS observations have shown that the tertiary ozone maximum was temporarily destroyed during the January 2005 and December 2006 solar proton events as a result of the HOx enhancement from the increased ionization.

Massive global ozone loss predicted following regional nuclear conflict

PubMed Central

Mills, Michael J.; Toon, Owen B.; Turco, Richard P.; Kinnison, Douglas E.; Garcia, Rolando R.

2008-01-01

We use a chemistry-climate model and new estimates of smoke produced by fires in contemporary cities to calculate the impact on stratospheric ozone of a regional nuclear war between developing nuclear states involving 100 Hiroshima-size bombs exploded in cities in the northern subtropics. We find column ozone losses in excess of 20% globally, 25–45% at midlatitudes, and 50–70% at northern high latitudes persisting for 5 years, with substantial losses continuing for 5 additional years. Column ozone amounts remain near or <220 Dobson units at all latitudes even after three years, constituting an extratropical “ozone hole.” The resulting increases in UV radiation could impact the biota significantly, including serious consequences for human health. The primary cause for the dramatic and persistent ozone depletion is heating of the stratosphere by smoke, which strongly absorbs solar radiation. The smoke-laden air rises to the upper stratosphere, where removal mechanisms are slow, so that much of the stratosphere is ultimately heated by the localized smoke injections. Higher stratospheric temperatures accelerate catalytic reaction cycles, particularly those of odd-nitrogen, which destroy ozone. In addition, the strong convection created by rising smoke plumes alters the stratospheric circulation, redistributing ozone and the sources of ozone-depleting gases, including N2O and chlorofluorocarbons. The ozone losses predicted here are significantly greater than previous “nuclear winter/UV spring” calculations, which did not adequately represent stratospheric plume rise. Our results point to previously unrecognized mechanisms for stratospheric ozone depletion. PMID:18391218

Godiva, a European Project for Ozone and Trace Gas Measurements from GOME

NASA Astrophysics Data System (ADS)

Goede, A. P. H.; Tanzi, C. P.; Aben, I.; Burrows, J. P.; Weber, M.; Perner, D.; Monks, P. S.; Llewellyn-Jones, D.; Corlett, G. K.; Arlander, D. W.; Platt, U.; Wagner, T.; Pfeilsticker, K.; Taalas, P.; Kelder, H.; Piters, A.

GODIVA (GOME Data Interpretation, Validation and Application) is a European Commission project aimed at the improvement of GOME (Global Ozone Monitoring Experiment) data products. Existing data products include global ozone, NO2 columns and (ir)radiances. Advanced data products include O3 profiles, BrO, HCHO and OCIO columns. These data are validated by ground-based and balloon borne instruments. Calibration issues are investigated by in-flight monitoring using several complementary calibration sources, as well as an on-ground replica of the GOME instrument. The results will lead to specification of operational processing of the EUMETSAT ozone Satellite Application Facility as well as implementation of the improved and new GOME data products in the NILU database for use in the European THESEO (Third European Stratospheric Experiment on Ozone) campaign of 1999

Simulated sensitivity of seasonal ozone exposure in the Great Lakes region to changes in anthropogenic emissions in the presence of interannual variability

Treesearch

Jerome D. Fast; Warren E. Heilman

2005-01-01

A coupled meteorological and chemical modeling system with a 12-km horizontal grid spacing was used to simulate the evolution of ozone over the Great Lakes region between May and September of 1999 and 2001. The overall temporal and spatial variations in hourly ozone concentrations and ozone exposure from control simulations agreed reasonably well with the observations...

Climate change impacts on projections of excess mortality at 2030 using spatially varying ozone-temperature

EPA Science Inventory

We project the change in ozone-related mortality burden attributable to changes in climate between a historical (1995-2005) and near-future (2025-2035) time period while incorporating a non-linear and synergistic effect of ozone and temperature on mortality. We simulate air quali...

History of Ozone Research: From Schonbein to the Present

NASA Technical Reports Server (NTRS)

Stolarski, Richard S.

1999-01-01

In 1840, C.F. Schonbein recognized that the smell generated in several different electrical and chemical processes was a single substance. He named this substance "ozein" from the Greek for "to smell". This substance we know today as ozone. Several periods can be distinguished in the continued development of our understanding of ozone. Throughout the late 19th century, the identity and properties of ozone were established and described. Ozone was recognized to be a constituent of normal air and tests were established to measure its concentration. Its disinfectant properties were recognized. New methods were developed for making ozone in the laboratory. In 1879, ultraviolet spectroscopic techniques were applied to the measurement of the solar spectrum and it was discovered by Comu that the spectrum was cut off at about 300 nm wavelength. Hartley suggested, based on laboratory measurements, that this cutoff was due to ozone in the atmosphere which he correctly asserted was somewhere in the upper atmosphere. This began the period of development of the amount and distribution of ozone throughout the atmosphere. In 1930, Chapman put forward the first theory of the formation and destruction of ozone. By the mid-1960s it was becoming obvious that the description of the chemical loss term was inadequate. By the early 1970s the chemical destruction of ozone by the oxides of hydrogen, nitrogen, chlorine, and bromine was recognized as an essential element in the chemical balance determining the ozone concentration. Today, ozone is a broad research project which crosses the boundaries of traditional disciplines. Stratospheric ozone loss due to chlorofluorocarbons is a newsworthy item. The Antarctic ozone hole opens up every spring. The provisions of the Montreal Protocol were agreed upon by countries around the world and promise to reduce the future levels of ozone-destroying chlorine in the stratosphere. Ozone concentrations in polluted cities are a subject of local and

The GEOS Ozone Data Assimilation System: Specification of Error Statistics

NASA Technical Reports Server (NTRS)

Stajner, Ivanka; Riishojgaard, Lars Peter; Rood, Richard B.

2000-01-01

A global three-dimensional ozone data assimilation system has been developed at the Data Assimilation Office of the NASA/Goddard Space Flight Center. The Total Ozone Mapping Spectrometer (TOMS) total ozone and the Solar Backscatter Ultraviolet (SBUV) or (SBUV/2) partial ozone profile observations are assimilated. The assimilation, into an off-line ozone transport model, is done using the global Physical-space Statistical Analysis Scheme (PSAS). This system became operational in December 1999. A detailed description of the statistical analysis scheme, and in particular, the forecast and observation error covariance models is given. A new global anisotropic horizontal forecast error correlation model accounts for a varying distribution of observations with latitude. Correlations are largest in the zonal direction in the tropics where data is sparse. Forecast error variance model is proportional to the ozone field. The forecast error covariance parameters were determined by maximum likelihood estimation. The error covariance models are validated using x squared statistics. The analyzed ozone fields in the winter 1992 are validated against independent observations from ozone sondes and HALOE. There is better than 10% agreement between mean Halogen Occultation Experiment (HALOE) and analysis fields between 70 and 0.2 hPa. The global root-mean-square (RMS) difference between TOMS observed and forecast values is less than 4%. The global RMS difference between SBUV observed and analyzed ozone between 50 and 3 hPa is less than 15%.

Ozone adsorption on carbon nanoparticles

NASA Astrophysics Data System (ADS)

Chassard, Guillaume; Gosselin, Sylvie; Visez, Nicolas; Petitprez, Denis

2014-05-01

realized by selecting the particles size with a differential mobility analyser. We observed a strong size-dependent increase in reactivity with the decrease of particles size. This result is relevant for the health issues. Indeed the smallest particles are most likely to penetrate deep into the lungs. Competitive reactions between ozone and other species like H2O or atomic oxygen were also considered. Oxygen atoms were generated by photolysis of O3 (or O2) and were chosen because it is believed to form the same reactive oxygen intermediates than ozone. A weak water physisorption on soot was observed revealing hydrophobic properties of particles. Oxygen atoms were found to be strongly reactive. A Langmuir behavior was observed for oxygen atoms adsorption on carbon particles and we were able to determine an initial uptake coefficient of approximately 2.10-2. [1] Fenidel, W., et al., Interaction between carbon or iron aerosol particles and ozone. Atmospheric Environment, 1995. 29(9): p. 967-973. [2] Smith, D. and A. Chughtai, Reaction kinetics of ozone at low concentrations with n-hexane soot. Journal of geophysical research, 1996. 101(D14): p. 19607-19,620. [3] Kamm, S., et al., The heterogeneous reaction of ozone with soot aerosol. Atmospheric Environment, 1999. 33(28): p. 4651-4661. [4] Stephens, S., M.J. Rossi, and D.M. Golden, The heterogeneous reaction of ozone on carbonaceous surfaces. International journal of chemical kinetics, 1986. 18(10): p. 1133-1149. [5] Pöschl, U., et al., Interaction of ozone and water vapor with spark discharge soot aerosol particles coated with benzo [a] pyrene: O3 and H2O adsorption, benzo [a] pyrene degradation, and atmospheric implications. The Journal of Physical Chemistry A, 2001. 105(16): p. 4029-4041.

Simulations of binary black hole mergers

NASA Astrophysics Data System (ADS)

Lovelace, Geoffrey

2017-01-01

Advanced LIGO's observations of merging binary black holes have inaugurated the era of gravitational wave astronomy. Accurate models of binary black holes and the gravitational waves they emit are helping Advanced LIGO to find as many gravitational waves as possible and to learn as much as possible about the waves' sources. These models require numerical-relativity simulations of binary black holes, because near the time when the black holes merge, all analytic approximations break down. Following breakthroughs in 2005, many research groups have built numerical-relativity codes capable of simulating binary black holes. In this talk, I will discuss current challenges in simulating binary black holes for gravitational-wave astronomy, and I will discuss the tremendous progress that has already enabled such simulations to become an essential tool for Advanced LIGO.

Persistent Polar Depletion of Stratospheric Ozone and Emergent Mechanisms of Ultraviolet Radiation-Mediated Health Dysregulation

PubMed Central

Dugo, Mark A.; Han, Fengxiang

2013-01-01

Year 2011 noted the first definable ozone “hole” in the Arctic region, serving as an indicator to the continued threat of dangerous ultraviolet radiation (UVR) exposure caused by the deterioration of stratospheric ozone in the northern hemisphere. Despite mandates of the Montreal Protocol to phase out the production of ozone depleting chemicals (ODCs), the relative stability of ODCs validates popular notions of persistent stratospheric ozone for several decades. Moreover, increased UVR exposure through stratospheric ozone depletion is occurring within a larger context of physiological stress and climate change across the biosphere. In this review, we provide commentaries on stratospheric ozone depletion with relative comparisons between the well-known Antarctic ozone hole and the newly defined ozone hole in the Arctic. Compared to the Antarctic region, increased UVR exposure in the Northern Hemisphere poses a threat to denser human populations across North America, Europe and Asia. In this context, we discuss emerging targets of UVR exposure that can potentially offset normal biological rhythms in terms of taxonomically conserved photoperiod dependent seasonal signaling and entrainment of circadian clocks. Consequences of seasonal shifts during critical life history stages can alter the fitness and condition, while circadian disruption is increasingly becoming associated as a causal link to increased carcinogenesis. We further review the significance of genomic alterations via UVR induced modulations of phase I and phase II transcription factors, the aryl hydrocarbon receptor (AhR) and the Nuclear factor (erythroid-derived 2)-like 2 (Nrf2), with emphasis on mechanism that can lead to metabolic shifts and cancer. While concern for adverse health consequences due to increased UVR exposure are longstanding, recent advances in biochemical research suggest that AhR and Nrf2 transcriptional regulators are likely targets for UVR mediated dysregulations of rhymicity

Spatio-temporal observations of the tertiary ozone maximum

NASA Astrophysics Data System (ADS)

Sofieva, V. F.; Kyrölä, E.; Verronen, P. T.; Seppälä, A.; Tamminen, J.; Marsh, D. R.; Smith, A. K.; Bertaux, J.-L.; Hauchecorne, A.; Dalaudier, F.; Fussen, D.; Vanhellemont, F.; Fanton D'Andon, O.; Barrot, G.; Guirlet, M.; Fehr, T.; Saavedra, L.

2009-07-01

We present spatio-temporal distributions of the tertiary ozone maximum (TOM), based on GOMOS (Global Ozone Monitoring by Occultation of Stars) ozone measurements in 2002-2006. The tertiary ozone maximum is typically observed in the high-latitude winter mesosphere at an altitude of ~72 km. Although the explanation for this phenomenon has been found recently - low concentrations of odd-hydrogen cause the subsequent decrease in odd-oxygen losses - models have had significant deviations from existing observations until recently. Good coverage of polar night regions by GOMOS data has allowed for the first time to obtain spatial and temporal observational distributions of night-time ozone mixing ratio in the mesosphere. The distributions obtained from GOMOS data have specific features, which are variable from year to year. In particular, due to a long lifetime of ozone in polar night conditions, the downward transport of polar air by the meridional circulation is clearly observed in the tertiary ozone maximum time series. Although the maximum tertiary ozone mixing ratio is achieved close to the polar night terminator (as predicted by the theory), TOM can be observed also at very high latitudes, not only in the beginning and at the end, but also in the middle of winter. We have compared the observational spatio-temporal distributions of the tertiary ozone maximum with that obtained using WACCM (Whole Atmosphere Community Climate Model) and found that the specific features are reproduced satisfactorily by the model. Since ozone in the mesosphere is very sensitive to HOx concentrations, energetic particle precipitation can significantly modify the shape of the ozone profiles. In particular, GOMOS observations have shown that the tertiary ozone maximum was temporarily destroyed during the January 2005 and December 2006 solar proton events as a result of the HOx enhancement from the increased ionization.

A New SBUV Ozone Profile Time Series

NASA Technical Reports Server (NTRS)

McPeters, Richard

2011-01-01

Under NASA's MEaSUREs program for creating long term multi-instrument data sets, our group at Goddard has re-processed ozone profile data from a series of SBUV instruments. We have processed data from the Nimbus 7 SBUV instrument (1979-1990) and data from SBUV/2 instruments on NOAA-9 (1985-1998), NOAA-11 (1989-1995), NOAA-16 (2001-2010), NOAA-17 (2002-2010), and NOAA-18 (2005-2010). This reprocessing uses the version 8 ozone profile algorithm but now uses the Brion, Daumont, and Malicet (BMD) ozone cross sections instead of the Bass and Paur cross sections. The new cross sections have much better resolution, and extended wavelength range, and a more consistent temperature dependence. The re-processing also uses an improved cloud height climatology based on the Raman cloud retrievals of OMI. Finally, the instrument-to-instrument calibration is set using matched scenes so that ozone diurnal variation in the upper stratosphere does not alias into the ozone trands. Where there is no instrument overlap, SAGE and MLS are used to estimate calibration offsets. Preliminary analysis shows a more coherent time series as a function of altitude. The net effect on profile total column ozone is on average an absolute reduction of about one percent. Comparisons with ground-based systems are significantly better at high latitudes.

Antarctic Ultraviolet Radiation Climatology from Total Ozone Mapping Spectrometer Data

NASA Technical Reports Server (NTRS)

Lubin, Dan

2004-01-01

This project has successfully produced a climatology of local noon spectral surface irradiance covering the Antarctic continent and the Southern Ocean, the spectral interval 290-700 nm (UV-A, UV-B, and photosynthetically active radiation, PAR), and the entire sunlit part of the year for November 1979-December 1999. Total Ozone Mapping Spectrometer (TOMS) data were used to specify column ozone abundance and UV-A (360- or 380-nm) reflectivity, and passive microwave (MW) sea ice concentrations were used to specify the surface albedo over the Southern Ocean. For this latter task, sea ice concentration retrievals from the Nimbus-7 Scanning Multichannel Microwave Radiometer (SMMR) and its successor, the Defense Meteorological Satellite Program (DMSP) Special Sensor Microwave Imager (SSM/I) were identified with ultraviolet/visible-wavelength albedos based on an empirical TOMS/MW parameterization developed for this purpose (Lubin and Morrow, 2001). The satellite retrievals of surface albedo and UV-A reflectivity were used in a delta-Eddington radiative transfer model to estimate cloud effective optical depth. These optical depth estimates were then used along with the total ozone and surface albedo to calculate the downwelling spectral UV and PAR irradiance at the surface. These spectral irradiance maps were produced for every usable day of TOMS data between 1979-1999 (every other day early in the TOMS program, daily later on).

Ozone Exposure, Cardiopulmonary Health, and Obesity: A Substantive Review.

PubMed

Koman, Patricia D; Mancuso, Peter

2017-07-17

From 1999-2014, obesity prevalence increased among adults and youth. Obese individuals may be uniquely susceptible to the proinflammatory effects of ozone because obese humans and animals have been shown to experience a greater decline in lung function than normal-weight subjects. Obesity is independently associated with limitations in lung mechanics with increased ozone dose. However, few epidemiologic studies have examined the interaction between excess weight and ozone exposure among adults. Using PubMed keyword searches and reference lists, we reviewed epidemiologic evidence to identify potential response-modifying factors and determine if obese or overweight adults are at increased risk of ozone-related health effects. We initially identified 170 studies, of which seven studies met the criteria of examining the interaction of excess weight and ozone exposure on cardiopulmonary outcomes in adults, including four short-term ozone exposure studies in controlled laboratory settings and three community epidemiologic studies. In the studies identified, obesity was associated with decreased lung function and increased inflammatory mediators. Results were inconclusive about the effect modification when data were stratified by sex. Obese and overweight populations should be considered as candidate at-risk groups for epidemiologic studies of cardiopulmonary health related to air pollution exposures. Air pollution is a modifiable risk factor that may decrease lung function among obese individuals with implications for environmental and occupational health policy.

Design of a Vehicle-Based Intervention System to Prevent Ozone Loss

NASA Technical Reports Server (NTRS)

Mason, William H.; Kirchbaum, Nathan; Kay, Jacob; Benoliel, Alexander M.; Lynn, Sean R.; Bunker, Deborah; Hesbach, Thomas D., Jr.; Howerton, Everett B.; Hreinsson, Gudbjoern; Mistr, E. Kirk

1993-01-01

Reduced quantities of ozone in the atmosphere allow greater levels of ultraviolet (UV) radiation to reach the earth's surface. The 1992/1993 project goals for the Virginia Tech Senior Design Team were to 1) understand the processes which contribute to stratospheric ozone loss, 2) examine ways to prevent ozone loss, and 3) define the requirements for an implementation vehicle to carry out the prevention scheme. A scheme proposed by R.J. Cicerone, el al late in 1991 was selected because of its supporting research and economic feasibility. This scheme uses hydrocarbon injected into the Antarctic ozone hole to form stable compounds with free chlorine, thus reducing ozone depletion. A study of the hydrocarbon injection requirements determined that 130 aircraft traveling Mach 2.4 at a maximum altitude of 66,000 ft. would provide the most economic approach to preventing ozone loss. Each aircraft would require an 8,000 nm. range and be able to carry 35,000 lbs. of propane. The propane would be stored in a three-tank high pressure system. Modularity and multi-role functionality were selected to be key design features. Missions originate from airports located in South America and Australia.

Quantifying stratospheric ozone trends: Complications due to stratospheric cooling

NASA Astrophysics Data System (ADS)

McLinden, C. A.; Fioletov, V.

2011-02-01

Recent studies suggest that ozone turnaround (the second stage of ozone recovery) is near. Determining precisely when this occurs, however, will be complicated by greenhouse gas-induced stratospheric cooling as ozone trends derived from profile data in different units and/or vertical co-ordinates will not agree. Stratospheric cooling leads to simultaneous trends in air density and layer thicknesses, confounding the interpretation of ozone trends. A simple model suggests that instruments measuring ozone in different units may differ as to the onset of turnaround by a decade, with some indicting a continued decline while others an increase. This concept was illustrated by examining the long-term (1979-2005) ozone trends in the SAGE (Stratospheric Aerosol and Gas Experiment) and SBUV (Solar Backscatter Ultraviolet) time series. Trends from SAGE, which measures number density as a function of altitude, and SBUV, which measures partial column as a function of pressure, are known to differ by 4-6%/decade in the upper stratosphere. It is shown that this long-standing difference can be reconciled to within 2%/decade when the trend in temperature is properly accounted for.

The Aviation System Monitoring and Modeling (ASMM) Project: A Documentation of its History and Accomplishments: 1999-2005

NASA Technical Reports Server (NTRS)

Statler, Irving C. (Editor)

2007-01-01

The Aviation System Monitoring and Modeling (ASMM) Project was one of the projects within NASA s Aviation Safety Program from 1999 through 2005. The objective of the ASMM Project was to develop the technologies to enable the aviation industry to undertake a proactive approach to the management of its system-wide safety risks. The ASMM Project entailed four interdependent elements: (1) Data Analysis Tools Development - develop tools to convert numerical and textual data into information; (2) Intramural Monitoring - test and evaluate the data analysis tools in operational environments; (3) Extramural Monitoring - gain insight into the aviation system performance by surveying its front-line operators; and (4) Modeling and Simulations - provide reliable predictions of the system-wide hazards, their causal factors, and their operational risks that may result from the introduction of new technologies, new procedures, or new operational concepts. This report is a documentation of the history of this highly successful project and of its many accomplishments and contributions to improved safety of the aviation system.

Prevalence of prescription and illicit drugs in pregnancy-associated non-natural deaths of Florida mothers, 1999-2005.

PubMed

Hardt, Nancy; Wong, Tit D; Burt, Martha J; Harrison, Ross; Winter, Will; Roth, Jeffrey

2013-11-01

Abuse of prescription and illicit drugs has been rapidly increasing. This study examines the prevalence of drug use in the non-natural deaths of pregnant or recently pregnant women. Records from Florida's Pregnancy Associated Mortality Review conducted between 1999 and 2005 (n = 415) were linked to 385 toxicology reports obtained from Florida medical examiners' offices. The final study sample consisted of 169 drug-positive, pregnancy-associated non-natural deaths. Of these, 86 were positive for both blood and urine, 64 were positive for blood only and five for urine only, and the remainder were positive for some other specimen. Among these deaths, 91 cases (54%) involved prescription drugs, 78 cases (46%) involved illicit drugs, and 69 cases (41%) involved alcohol. Opioids constituted the majority of deaths associated with prescription drugs. Substantial co-use of opioids and benzodiazepines was seen. Pregnant or recently pregnant women may have more interactions with healthcare providers, which may present more opportunities for intervention and prevention. © 2013 American Academy of Forensic Sciences.

Observational Diagnoses of Extratropical Ozone STE During the Aura Era

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Douglass, Anne R.; Witte, Jacquie C.; Kaplan, Trevor B.

2011-01-01

The transport of ozone from the stratosphere to the extratropical troposphere is an important boundary condition to tropospheric chemistry. However, previous direct estimates from models and indirect estimates from observations have poorly constrained the magnitude of ozone stratosphere-troposphere exchange (STE). In this study we provide a direct diagnosis of the extratropical ozone STE using data from the Microwave Limb Sounder on Aura and output of the MERRA reanalysis over the time period from 2005 to the present. We find that the mean annual STE is about 275 Tg/yr and 205 Tg/yr in the NH and SH, respectively. The interannual variability of the magnitude is about twice as great in the NH than the SH. We find that this variability is dominated by the seasonal variability during the late winter and spring. A comparison of the ozone flux to the mass flux reveals that there is not a simple relationship between the two quantities. This presentation will also examine the magnitude and distribution of ozone in the lower stratosphere relative to the years of maximum and minimum ozone STE. Finally, we will examine any possible signature of increased ozone STE in the troposphere using sonde and tropospheric ozone residual (TOR) data, and output from the Global Modeling Initiative Chemistry Transport Model (GMI CTM).

Aura Microwave Limb Sounder Estimates of Ozone Loss, 2004/2005 Arctic Winter

NASA Image and Video Library

2005-06-02

These data maps from the Microwave Limb Sounder on NASA Aura spacecraft depict levels of hydrogen chloride, chlorine monoxide, and ozone at an altitude of approximately 19 km 490,000 ft on selected days during the 2004-05 Arctic winter.

Rapid growth in nitrogen dioxide pollution over Western China, 2005-2013

NASA Astrophysics Data System (ADS)

Cui, Y.-Z.; Lin, J.-T.; Song, C.; Liu, M.-Y.; Yan, Y.-Y.; Xu, Y.; Huang, B.

2015-12-01

Western China has experienced rapid industrialization and urbanization since the implementation of the National Western Development Strategies (the "Go West" movement) in 1999. This transition has affected the spatial and temporal characteristics of nitrogen dioxide (NO2) pollution. In this study, we analyze the trends and variability of tropospheric NO2 vertical column densities (VCDs) from 2005 to 2013 over Western China, based on a wavelet analysis on monthly mean NO2 data derived from the Ozone Monitoring Instrument (OMI) measurements. We focus on the anthropogenic NO2 by subtracting region-specific "background" values dominated by natural sources. We find significant NO2 growth over Western China between 2005 and 2013 (8.6 ± 0.9 % yr-1 on average, relative to 2005), with the largest increments (15 % yr-1 or more) over parts of several city clusters. The NO2 pollution in most provincial regions rose rapidly from 2005 to 2011 but stabilized or declined afterwards. The NO2 trends were driven mainly by changes in anthropogenic emissions, as confirmed by a nested GEOS-Chem model simulation and a comparison with Chinese official emission statistics. The rate of NO2 growth during 2005-2013 reaches 11.3 ± 1.0 % yr-1 over Northwestern China, exceeding the rates over Southwestern China (5.9 ± 0.6 % yr-1) and the three well-known polluted regions in the east (5.3 ± 0.8 % yr-1 over Beijing-Tianjin-Hebei, 4.0 ± 0.6 % yr-1} over the Yangtze River Delta, and -3.3 ± 0.3 % yr-1 over the Pearl River Delta). Additional socioeconomic analyses suggest that the rapid NO2 growth in Northwestern China is likely related to the fast developing resource- and pollution-intensive industries along with the "Go West" movement as well as relatively weak emission controls. Further efforts should be made to alleviate NOx pollution to achieve sustainable development in Western China.

Rapid growth in nitrogen dioxide pollution over Western China, 2005-2013

NASA Astrophysics Data System (ADS)

Cui, Yuanzheng; Lin, Jintai; Song, Chunqiao; Liu, Mengyao; Yan, Yingying; Xu, Yuan; Huang, Bo

2016-05-01

Western China has experienced rapid industrialization and urbanization since the implementation of the National Western Development Strategies (the "Go West" movement) in 1999. This transition has affected the spatial and temporal characteristics of nitrogen dioxide (NO2) pollution. In this study, we analyze the trends and variability of tropospheric NO2 vertical column densities (VCDs) from 2005 to 2013 over Western China, based on a wavelet analysis on monthly mean NO2 data derived from the Ozone Monitoring Instrument (OMI) measurements. We focus on the anthropogenic NO2 by subtracting region-specific "background" values dominated by natural sources. After removing the background influences, we find significant anthropogenic NO2 growth over Western China between 2005 and 2013 (8.6 ± 0.9 % yr-1 on average, relative to 2005), with the largest increments (15 % yr-1 or more) over parts of several city clusters. The NO2 pollution in most provincial-level regions rose rapidly from 2005 to 2011 but stabilized or declined afterwards. The NO2 trends were driven mainly by changes in anthropogenic emissions, as confirmed by a nested GEOS-Chem model simulation and a comparison with Chinese official emission statistics. The rate of NO2 growth during 2005-2013 reaches 11.3 ± 1.0 % yr-1 over Northwestern China, exceeding the rates over Southwestern China (5.9 ± 0.6 % yr-1) and the three well-known polluted regions in the east (5.3 ± 0.8 % yr-1 over Beijing-Tianjin-Hebei, 4.0 ± 0.6 % yr-1 over the Yangtze River Delta, and -3.3 ± 0.3 % yr-1 over the Pearl River Delta). Subsequent socioeconomic analyses suggest that the rapid NO2 growth over Northwestern China is likely related to the fast developing resource- and pollution-intensive industries along with the "Go West" movement as well as relatively weak emission controls. Further efforts should be made to alleviate NOx pollution to achieve sustainable development in Western China.

Human Health and Economic Impacts of Ozone Reductions by Income Group.

PubMed

Saari, Rebecca K; Thompson, Tammy M; Selin, Noelle E

2017-02-21

Low-income households may be disproportionately affected by ozone pollution and ozone policy. We quantify how three factors affect the relative benefits of ozone policies with household income: (1) unequal ozone reductions; (2) policy delay; and (3) economic valuation methods. We model ozone concentrations under baseline and policy conditions across the full continental United States to estimate the distribution of ozone-related health impacts across nine income groups. We enhance an economic model to include these impacts across household income categories, and present its first application to evaluate the benefits of ozone reductions for low-income households. We find that mortality incidence rates decrease with increasing income. Modeled ozone levels yield a median of 11 deaths per 100 000 people in 2005. Proposed policy reduces these rates by 13%. Ozone reductions are highest among low-income households, which increases their relative welfare gains by up to 4% and decreases them for the rich by up to 8%. The median value of reductions in 2015 is either $30 billion (in 2006 U.S. dollars) or $1 billion if reduced mortality risks are valued with willingness-to-pay or as income from increased life expectancy. Ozone reductions were relatively twice as beneficial for the lowest- compared to the highest-income households. The valuation approach affected benefits more than a policy delay or differential ozone reductions with income.

Arctic “ozone hole” in a cold volcanic stratosphere

PubMed Central

Tabazadeh, A.; Drdla, K.; Schoeberl, M. R.; Hamill, P.; Toon, O. B.

2002-01-01

Optical depth records indicate that volcanic aerosols from major eruptions often produce clouds that have greater surface area than typical Arctic polar stratospheric clouds (PSCs). A trajectory cloud–chemistry model is used to study how volcanic aerosols could affect springtime Arctic ozone loss processes, such as chlorine activation and denitrification, in a cold winter within the current range of natural variability. Several studies indicate that severe denitrification can increase Arctic ozone loss by up to 30%. We show large PSC particles that cause denitrification in a nonvolcanic stratosphere cannot efficiently form in a volcanic environment. However, volcanic aerosols, when present at low altitudes, where Arctic PSCs cannot form, can extend the vertical range of chemical ozone loss in the lower stratosphere. Chemical processing on volcanic aerosols over a 10-km altitude range could increase the current levels of springtime column ozone loss by up to 70% independent of denitrification. Climate models predict that the lower stratosphere is cooling as a result of greenhouse gas built-up in the troposphere. The magnitude of column ozone loss calculated here for the 1999–2000 Arctic winter, in an assumed volcanic state, is similar to that projected for a colder future nonvolcanic stratosphere in the 2010 decade. PMID:11854461

Issues in Stratospheric Ozone Depletion.

NASA Astrophysics Data System (ADS)

Lloyd, Steven Andrew

Following the announcement of the discovery of the Antarctic ozone hole in 1985 there have arisen a multitude of questions pertaining to the nature and consequences of polar ozone depletion. This thesis addresses several of these specific questions, using both computer models of chemical kinetics and the Earth's radiation field as well as laboratory kinetic experiments. A coupled chemical kinetic-radiative numerical model was developed to assist in the analysis of in situ field measurements of several radical and neutral species in the polar and mid-latitude lower stratosphere. Modeling was used in the analysis of enhanced polar ClO, mid-latitude diurnal variation of ClO, and simultaneous measurements of OH, HO_2, H_2 O and O_3. Most importantly, such modeling was instrumental in establishing the link between the observed ClO and BrO concentrations in the Antarctic polar vortex and the observed rate of ozone depletion. The principal medical concern of stratospheric ozone depletion is that ozone loss will lead to the enhancement of ground-level UV-B radiation. Global ozone climatology (40^circS to 50^ circN latitude) was incorporated into a radiation field model to calculate the biologically accumulated dosage (BAD) of UV-B radiation, integrated over days, months, and years. The slope of the annual BAD as a function of latitude was found to correspond to epidemiological data for non-melanoma skin cancers for 30^circ -50^circN. Various ozone loss scenarios were investigated. It was found that a small ozone loss in the tropics can provide as much additional biologically effective UV-B as a much larger ozone loss at higher latitudes. Also, for ozone depletions of > 5%, the BAD of UV-B increases exponentially with decreasing ozone levels. An important key player in determining whether polar ozone depletion can propagate into the populated mid-latitudes is chlorine nitrate, ClONO_2 . As yet this molecule is only indirectly accounted for in computer models and field

An estimate of the Antarctic ozone modulation by the QBO. [Quasi-Biennial Oscillation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mancini, E.; Visconti, G.; Pitari, G.

1991-02-01

The possible effects of the QBO on the ozone distribution have been studied including in a 2D model a parameterization of Kelvin and Rossby-gravity wave forcing in the lower equatorial stratosphere. A chemical code complete with heterogeneous reactions allows a simulation of the ozone depletion due to the increase of stratospheric chlorine. With this model, the authors study the possible modulation of the secular trend in the Antarctic ozone hole by the QBO. When heterogeneous chemistry is not included, the model shows a polar ozone oscillation ({plus minus}6 Dobson Units) comparable to that deduced from early measurements (1970-1975). When heterogeneousmore » reactions are taken into account, the model predicts a larger ozone oscillation in the Southern Hemisphere ({plus minus}12 Dobson Units) comparable to that obtained from recent observations. This behavior seems to point out a QBO induced temperature effect and its feedback on PSC with activation of heterogeneous chemistry.« less

Neurological adverse events temporally associated to mass vaccination against yellow fever in Juiz de Fora, Brazil, 1999-2005.

PubMed

Fernandes, Guilherme Côrtes; Camacho, Luiz Antonio Bastos; Sá Carvalho, Marilia; Batista, Maristela; de Almeida, Sonia Maria Rodrigues

2007-04-20

The identification of adverse events following immunization (AEFI) and their prompt investigation are important to allow a timely and scientifically based response to the users of immunization services. This article presents an analysis of notified AEFI cases between 1999 and 2005 and their temporal association with 2001 yellow fever vaccination campaign, AEFI notification attributed to yellow fever vaccination rose from 0.06 to 1.32 per 100,000 vaccinees in Brazil, between 1998 and 2000. During the 2001 yellow fever mass vaccination campaign held in Juiz de Fora, Brazil, 12 cases of aseptic meningitis were temporally associated to yellow fever vaccination, but clinical and laboratory data were not available to confirm nor deny causality. Epidemiological studies associated to enhanced surveillance and standardized protocols should take advantage of public health interventions like mass vaccination campaigns and implementation of new vaccination strategies in order to assess and investigate vaccine safety.

Ozone Time Series From GOMOS and SAGE II Measurements

NASA Astrophysics Data System (ADS)

Kyrola, E. T.; Laine, M.; Tukiainen, S.; Sofieva, V.; Zawodny, J. M.; Thomason, L. W.

2011-12-01

Satellite measurements are essential for monitoring changes in the global stratospheric ozone distribution. Both the natural variation and anthropogenic change are strongly dependent on altitude. Stratospheric ozone has been measured from space with good vertical resolution since 1985 by the SAGE II solar occultation instrument. The advantage of the occultation measurement principle is the self-calibration, which is essential to ensuring stable time series. SAGE II measurements in 1985-2005 have been a valuable data set in investigations of trends in the vertical distribution of ozone. This time series can now be extended by the GOMOS measurements started in 2002. GOMOS is a stellar occultation instrument and offers, therefore, a natural continuation of SAGE II measurements. In this paper we study how well GOMOS and SAGE II measurements agree with each other in the period 2002-2005 when both instruments were measuring. We detail how the different spatial and temporal sampling of these two instruments affect the conformity of measurements. We study also how the retrieval specifics like absorption cross sections and assumed aerosol modeling affect the results. Various combined time series are constructed using different estimators and latitude-time grids. We also show preliminary results from a novel time series analysis based on Markov chain Monte Carlo approach.

The Effect of Representing Bromine from VSLS on the Simulation and Evolution of Antarctic Ozone

NASA Technical Reports Server (NTRS)

Oman, Luke D.; Douglass, Anne R.; Salawitch, Ross J.; Canty, Timothy P.; Ziemke, Jerald R.; Manyin, Michael

2016-01-01

We use the Goddard Earth Observing System Chemistry Climate Model (GEOSCCM), a contributor to both the 2010 and 2014 WMO Ozone Assessment Reports, to show that inclusion of 5 parts per trillion (ppt) of stratospheric bromine(Br(sub y)) from very short lived substances (VSLS) is responsible for about a decade delay in ozone hole recovery. These results partially explain the significantly later recovery of Antarctic ozone noted in the 2014 report, as bromine from VSLS was not included in the 2010 Assessment. We show multiple lines of evidence that simulations that account for VSLS Br(sub y) are in better agreement with both total column BrO and the seasonal evolution of Antarctic ozone reported by the Ozone Monitoring Instrument (OMI) on NASAs Aura satellite. In addition, the near zero ozone levels observed in the deep Antarctic lower stratospheric polar vortex are only reproduced in a simulation that includes this Br(sub y) source from VSLS.

The Effect of Representing Bromine from VSLS on the Simulation and Evolution of Antarctic Ozone

PubMed Central

Oman, Luke D.; Douglass, Anne R.; Salawitch, Ross J.; Canty, Timothy P.; Ziemke, Jerald R.; Manyin, Michael

2018-01-01

We use the Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM), a contributor to both the 2010 and 2014 WMO Ozone Assessment Reports, to show that inclusion of 5 parts per trillion (ppt) of stratospheric bromine (Bry) from very short-lived substances (VSLS) is responsible for about a decade delay in ozone hole recovery. These results partially explain the significantly later recovery of Antarctic ozone noted in the 2014 report, as bromine from VSLS was not included in the 2010 Assessment. We show multiple lines of evidence that simulations that account for VSLS Bry are in better agreement with both total column BrO and the seasonal evolution of Antarctic ozone reported by the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite. In addition, the near zero ozone levels observed in the deep Antarctic lower stratospheric polar vortex are only reproduced in a simulation that includes this Bry source from VSLS. PMID:29551840

Observations of, and sources of the spatial and temporal variability of ozone in the middle atmosphere on climatological time scales (OZMAP) and equatorial dynamics: Seasonal variations of ozone trends

NASA Technical Reports Server (NTRS)

Entzian, G.; Grasnick, K. H.; Taubenheim, J.

1989-01-01

The long term trends (least square linear regression with time) of ozone content at seven European, seven North American, three Japanese and two tropical stations during 21 years (1964 to 1984) are analyzed. In all regions negative trends are observed during the 1970s, but are partly compensated by limited periods of positive trends during the late 1960s and late 1970s. Solely the North American ozone data show negative trends in all 10 year periods. When the long term ozone trends are evaluated for each month of the year separately, a seasonal variation is revealed, which in Europe and North America has largest negative trends in late winter and spring. While in Europe the negative trends in winter/spring are partly compensated by positive trends in summer, in North America the summer values reach only zero, retaining the significant negative trend in annual mean values. In contrast to the antarctic ozone hole, the spring reduction of ozone in Europe and in North America is associated with stratospheric temperatures increasing in the analyzed period and therefore is consistent with the major natural ozone production and loss processes.

The total ozone and UV solar radiation over Stara Zagora, Bulgaria

NASA Astrophysics Data System (ADS)

Mendeva, B. D.; Gogosheva, Ts. N.; Petkov, B. H.; Krastev, D. G.

The results from direct ground-based solar UV irradiance measurements and the total ozone content (TOC) over Stara Zagora (42° 25'N, 25° 37'E), Bulgaria are presented. During the period 1999-2003 the TOC data show seasonal variations, typical for the middle latitudes - maximum in the spring and minimum in the autumn. The comparison between TOC ground-based data and Global Ozone Monitoring Experiment (GOME) satellite-borne ones shows a seasonal dependence of the differences between them. A strong negative relationship between the total ozone and the 305 nm wavelength irradiance was found. The dependence between the two variables is significant ( r = -0.62 ± 0.18) at 98% confidence level. The direct sun UV doses for some specific biological effects (erythema and eyes) are obtained. The estimation of the radiation amplification factor RAF shows that the ozone reduction by 1% increases the erythemal dose by 2.3%. The eye-damaging doses are more influenced by the TOC changes and in this case RAF = -2.7%. The amount of these biological doses depended on the solar altitude over the horizon. This dependence was not so strong when the total ozone content in the atmosphere was lower.

Accelerated measles control--Cambodia, 1999-2002.

PubMed

2003-01-10

Cambodia is recovering from approximately 30 years of civil war that resulted in the breakdown of the country's public health infrastructure. In 1999, the Ministry of Health initiated a measles-control program with the goal of reducing the annual incidence of measles to <10,000 cases in 2005 by strengthening measles surveillance, improving routine vaccination coverage, implementing supplementary measles immunization activities (SIAs), and providing vitamin A during outbreak investigations and SIAs. This report summarizes measles-vaccination activities and their impact in reducing reported measles cases from 13,827 in 1999 to 1,234 in 2002 and suggests options for future measles-control efforts in postconflict situations.

Increased recognition of Powassan encephalitis in the United States, 1999-2005.

PubMed

Hinten, Steven R; Beckett, Geoffrey A; Gensheimer, Kathleen F; Pritchard, Elizabeth; Courtney, Thomas M; Sears, Stephen D; Woytowicz, John M; Preston, David G; Smith, Robert P; Rand, Peter W; Lacombe, Eleanor H; Holman, Mary S; Lubelczyk, Charles B; Kelso, Patsy Tassler; Beelen, Andrew P; Stobierski, Mary Grace; Sotir, Mark J; Wong, Susan; Ebel, Gregory; Kosoy, Olga; Piesman, Joseph; Campbell, Grant L; Marfin, Anthony A

2008-12-01

Powassan virus (POWV) disease is a rare human disease caused by a tick-borne encephalitis group flavivirus maintained in a transmission cycle between Ixodes cookei and other ixodid ticks and small and medium-sized mammals. During 1958-1998, only 27 POWV disease cases (mostly Powassan encephalitis) were reported from eastern Canada and the northeastern United States (average, 0.7 cases per year). During 1999-2005, nine cases (described herein) of serologically confirmed POWV disease were reported in the United States (average, 1.3 cases per year): four from Maine, two from New York, and one each from Michigan, Vermont, and Wisconsin. The Michigan and Wisconsin cases are the first ever reported from the north-central United States. Of these nine patients, 5 (56%) were men, the median age was 69 years (range: 25-91 years), and 6 (67%) had onset during May-July. All but one patient developed encephalitis with acute onset of profound muscle weakness, confusion, and other severe neurologic signs. In one case, no neurologic symptoms were present but the presence of pleocytosis, an elevated cerebrospinal fluid (CSF) protein concentration, and POWV-specific immunoglobulin M in CSF suggested neuroinvasion. All patients recovered from their acute disease, but most had long-term neurologic sequelae. Periresidential ecologic investigations were performed in three cases, including tests of local mammals and ticks for evidence of POWV infection. Woodchucks (Marmota monax), striped skunks (Mephitis mephitis), and a raccoon (Procyon lotor) collected at two of the Maine case-patients' residences had neutralizing antibody titers to POWV. I. cookei were found on woodchucks and skunks and questing in grassy areas of one of these residences; all were negative for POWV. Although POWV disease is rare, it is probably under-recognized, and it causes significant morbidity, and thus is an additional tick-borne emerging infectious disease entity. Because no vaccine or specific therapy is

High levels of ultraviolet radiation observed by ground-based instruments below the 2011 Arctic ozone hole

NASA Astrophysics Data System (ADS)

Bernhard, G.; Dahlback, A.; Fioletov, V.; Heikkilä, A.; Johnsen, B.; Koskela, T.; Lakkala, K.; Svendby, T.

2013-11-01

Greatly increased levels of ultraviolet (UV) radiation were observed at thirteen Arctic and sub-Arctic ground stations in the spring of 2011, when the ozone abundance in the Arctic stratosphere dropped to the lowest amounts on record. Measurements of the noontime UV Index (UVI) during the low-ozone episode exceeded the climatological mean by up to 77% at locations in the western Arctic (Alaska, Canada, Greenland) and by up to 161% in Scandinavia. The UVI measured at the end of March at the Scandinavian sites was comparable to that typically observed 15-60 days later in the year when solar elevations are much higher. The cumulative UV dose measured during the period of the ozone anomaly exceeded the climatological mean by more than two standard deviations at 11 sites. Enhancements beyond three standard deviations were observed at seven sites and increases beyond four standard deviations at two sites. At the western sites, the episode occurred in March, when the Sun was still low in the sky, limiting absolute UVI anomalies to less than 0.5 UVI units. At the Scandinavian sites, absolute UVI anomalies ranged between 1.0 and 2.2 UVI units. For example, at Finse, Norway, the noontime UVI on 30 March was 4.7, while the climatological UVI is 2.5. Although a UVI of 4.7 is still considered moderate, UV levels of this amount can lead to sunburn and photokeratitis during outdoor activity when radiation is reflected upward by snow towards the face of a person or animal. At the western sites, UV anomalies can be well explained with ozone anomalies of up to 41% below the climatological mean. At the Scandinavian sites, low ozone can only explain a UVI increase of 50-60%. The remaining enhancement was mainly caused by the absence of clouds during the low-ozone period.

High levels of ultraviolet radiation observed by ground-based instruments below the 2011 Arctic ozone hole

NASA Astrophysics Data System (ADS)

Bernhard, G.; Dahlback, A.; Fioletov, V.; Heikkilä, A.; Johnsen, B.; Koskela, T.; Lakkala, K.; Svendby, T. M.

2013-06-01

Greatly increased levels of ultraviolet (UV) radiation were observed at thirteen Arctic and sub-Arctic ground stations in the spring of 2011 when the ozone abundance in the Arctic stratosphere dropped to the lowest amounts on record. Measurements of the noontime UV Index (UVI) during the low-ozone episode exceeded the climatological mean by up to 77% at locations in the western Arctic (Alaska, Canada, Greenland) and by up to 161% in Scandinavia. The UVI measured at the end of March at the Scandinavian sites was comparable to that typically observed 15-60 days later in the year when solar elevations are much higher. The cumulative UV dose measured during the period of the ozone anomaly exceeded the climatological mean by more than two standard deviations at 11 sites. Enhancements beyond three standard deviations were observed at seven sites and increases beyond four standard deviations at two sites. At the western sites, the episode occurred in March when the Sun was still low in the sky, limiting absolute UVI anomalies to less than 0.5 UVI units. At the Scandinavian sites, absolute UVI anomalies ranged between 1.0 and 2.2 UVI units. For example, at Finse, Norway, the noontime UVI on 30 March was 4.7 while the climatological UVI is 2.5. Although a UVI of 4.7 is still considered moderate, UV levels of this amount can lead to sunburn and photokeratitis during outdoor activity when radiation is reflected upward by snow towards the face of a person or animal. At the western sites, UV anomalies can be well explained with ozone anomalies of up to 41% below the climatological mean. At the Scandinavian sites, low ozone can only explain a UVI increase by 50-60%. The remaining enhancement was mainly caused by the absence of clouds during the low-ozone period.

Chronic Exposure to Ambient Ozone and Asthma Hospital Admissions among Children

PubMed Central

Lin, Shao; Liu, Xiu; Le, Linh H.; Hwang, Syni-An

2008-01-01

Background The association between chronic exposure to air pollution and adverse health outcomes has not been well studied. Objective This project investigated the impact of chronic exposure to high ozone levels on childhood asthma admissions in New York State. Methods We followed a birth cohort born in New York State during 1995–1999 to first asthma admission or until 31 December 2000. We identified births and asthma admissions through the New York State Integrated Child Health Information System and linked these data with ambient ozone data (8-hr maximum) from the New York State Department of Environmental Conservation. We defined chronic ozone exposure using three indicators: mean concentration during the follow-up period, mean concentration during the ozone season, and proportion of follow-up days with ozone levels > 70 ppb. We performed logistic regression analysis to adjust for child’s age, sex, birth weight, and gestational age; maternal race/ethnicity, age, education, insurance status, smoking during pregnancy, and poverty level; and geographic region, temperature, and copollutants. Results Asthma admissions were significantly associated with increased ozone levels for all chronic exposure indicators (odds ratios, 1.16–1.68), with a positive dose–response relationship. We found stronger associations among younger children, low sociodemographic groups, and New York City residents as effect modifiers. Conclusion Chronic exposure to ambient ozone may increase the risk of asthma admissions among children. Younger children and those in low socioeconomic groups have a greater risk of asthma than do other children at the same ozone level. PMID:19079727

7-year of surface ozone in a coastal city of central Italy: Observations and models

NASA Astrophysics Data System (ADS)

Biancofiore, Fabio; Verdecchia, Marco; Di Carlo, Piero; Tomassetti, Barbara; Aruffo, Eleonora; Busilacchio, Marcella; Bianco, Sebastiano; Di Tommaso, Sinibaldo; Colangeli, Carlo

2014-05-01

Hourly concentrations of ozone (O3) and nitrogen dioxide (NO2) have been measured for seven years, from 1998 to 2005, in a seaside town in the central Italy. Seasonal trends of O3 and NO2 recorded in the considered years are studied. Furthermore, we have focused our attention on data collected during the 2005, analyzing them using two different methods: a regression model and a neural network model. Both models are used to simulate the hourly ozone concentration, using several sets of input. In order to evaluate the performance of the model four statistical criteria are used: correlation coefficient (R), fractional bias (FB), normalized mean squared error (NMSE) e factor of two (FA2). All the criteria show that the neural network has better results compared to the regression model in all the simulations. In addiction we have tested some improvements of the neural network model, results of these tests are discussed. Finally, we have used the neural network to forecast the ozone hourly concentrations a day ahead and 1, 3, 6, 12 hour ahead. Performances of the model in predicting ozone levels are discussed.

Reconstruction of daily erythemal UV radiation values for the last century - The benefit of modelled ozone

NASA Astrophysics Data System (ADS)

Junk, J.; Feister, U.; Rozanov, E.; Krzyścin, J. W.

2013-05-01

Solar erythemal UV radiation (UVER) is highly relevant for numerous biological processes that affect plants, animals, and human health. Nevertheless, long-term UVER records are scarce. As significant declines in the column ozone concentration were observed in the past and a recovery of the stratospheric ozone layer is anticipated by the middle of the 21st century, there is a strong interest in the temporal variation of UVER time series. Therefore, we combined groundbased measurements of different meteorological variables with modeled ozone data sets to reconstruct time series of daily totals of UVER at the Meteorological Observatory Potsdam, Germany. Artificial neural networks were trained with measured UVER, sunshine duration, the day of year, measured and modeled total column ozone, as well as the minimum solar zenith angle. This allows for the reconstruction of daily totals of UVER for the period from 1901 to 1999. Additionally, analyses of the long-term variations from 1901 until 1999 of the reconstructed, new UVER data set are presented. The time series of monthly and annual totals of UVER provide a long-term meteorological basis for epidemiological investigations in human health and occupational medicine for the region of Potsdam and Berlin. A strong benefit of our ANN-approach is the fact that it can be easily adapted to different geographical locations, as successfully tested in the framework of the COSTAction 726.

Ozone response to a CO2 doubling - Results from a stratospheric circulation model with heterogeneous chemistry

NASA Technical Reports Server (NTRS)

Pitari, G.; Palermi, S.; Visconti, G.; Prinn, R. G.

1992-01-01

A spectral 3D model of the stratosphere has been used to study the sensitivity of polar ozone with respect to a carbon dioxide increase. The lower stratospheric cooling associated with an imposed CO2 doubling may increase the probability of polar stratospheric cloud (PSC) formation and this affect ozone. The ozone perturbation obtained with the inclusion of a simple parameterization for heterogeneous chemistry on PSCs is compared to that relative to a pure homogeneous chemistry. In both cases the temperature perturbation is determined by a CO2 doubling, while the total chlorine content is kept at the present level. It is shown that the lower temperature may increase the depth and the extension of the ozone hole by extending the area amenable to PSC formation. It may be argued that this effect, coupled with an increasing amount of chlorine, may produce a positive feedback on the ozone destruction.

Patterns of Radiotherapy Practice for Patients With Cervical Cancer in Japan, 2003-2005: Changing Trends in the Pattern of Care Process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tomita, Natsuo, E-mail: ntomita@aichi-cc.jp; Toita, Takafumi; Kodaira, Takeshi

2012-08-01

Purpose: The patterns of care study (PCS) of radiotherapy for cervical cancer in Japan over the last 10 years was reviewed. Methods and Materials: The Japanese PCS working group analyzed data from 1,200 patients (1995-1997, 591 patients; 1999-2001, 324 patients; 2003-2005, 285 patients) with cervical cancer treated with definitive radiotherapy in Japan. Results: Patients in the 2001-2003 survey were significantly younger than those in the 1999-2001 study (p < 0.0001). Histology, performance status, and International Federation of Gynecology and Obstetrics stage were not significantly different among the three survey periods. Use of combinations of chemotherapy has increased significantly during thosemore » periods (1995-1997, 24%; 1999-2001, 33%; 2003-2005, 54%; p < 0.0001). The ratio of patients receiving concurrent chemotherapy has also dramatically increased (1995-1997, 20%; 1999-2001, 54%; 2003-2005, 83%; p < 0.0001). As for external beam radiotherapy (EBRT), the application rate of four-field portals has greatly increased over the three survey periods (1995-1997, 2%; 1999-2001, 7%; 2003-2005, 21%; p < 0.0001). In addition, the use of an appropriate beam energy for EBRT has shown an increase (1995-1997, 67%; 1999-2001, 74%; 2003-2005, 81%; p = 0.064). As for intracavitary brachytherapy (ICBT), an iridium source has become increasingly popular (1995-1997, 27%; 1999-2001, 42%; 2003-2005, 84%; p < 0.0001). Among the three surveys, the ratio of patients receiving ICBT (1995-1997, 77%; 1999-2001, 82%; 2003-2005, 78%) has not changed. Although follow-up was inadequate in each survey, no significant survival differences were observed (p = 0.36), and rates of late Grade 3 or higher toxicity were significantly different (p = 0.016). Conclusions: The Japanese PCS has monitored consistent improvements over the past 10 years in the application of chemotherapy, timing of chemotherapy, and EBRT methods. However, there is still room for improvement, especially in the

Changes in concentrations of triazine and acetamide herbicides by bank filtration, ozonation, and chlorination in a public water supply

USGS Publications Warehouse

Verstraeten, Ingrid M.; Thurman, E.M.; Lindsey, M.E.; Lee, E.C.; Smith, R.D.

2002-01-01

The changes in triazine and acetamide concentrations in water during natural and artificial treatment by bank filtration, ozonation, filtration, and chlorination were measured at the well field and drinking water treatment plant of Lincoln, Nebraska, USA. The city's groundwater supply is affected by induced infiltration and transport of triazines and acetamide herbicides from the Platte River in late spring and early summer. The objective of the study was to evaluate the effect of infiltration and treatment on the presence of triazines and acetamides in drinking water. Samples of river water, well water, and public supply water at various stages of water treatment were collected from 1997-1999 during spring-runoff when the presence of herbicides in the Platte River is largest. In 1999, parent compounds were reduced by 76% of the concentration present in river water (33% by bank filtration, 41% by ozonation, and 1.5% by chlorination). Metabolites of herbicides for which analytical techniques existed were reduced by 21% (plus 26% by bank filtration, minus 23% by ozonation, and minus 24% by chlorination). However, increases in concentrations of specific metabolite compounds were identified after bank filtration and ozonation. After bank filtration, increases in cyanazine amide, cyanazine acid, and deethylcyanazine acid were identified. After ozonation, concentrations of deisopropylatrazine, deethylatrazine, didealkylatrazine, atrazine amide-I, hydroxydeethylatrazine, hydroxydeisopopylatrazine, deethylcyanazine acid, and deethylcyanazine increased. Concentrations of cyanazine acid and ethanesulfonic and oxanilic acids of acetamides decreased during ozonation. Our findings suggest that bank filtration and ozonation of water in part can shift the assessment of risk to human health associated with the consumption of the water from the parent compounds to their degradation products.

Is the ozone climate penalty robust in Europe?

NASA Astrophysics Data System (ADS)

Colette, Augustin; Andersson, Camilla; Baklanov, Alexander; Bessagnet, Bertrand; Brandt, Jørgen; Christensen, Jesper H.; Doherty, Ruth; Engardt, Magnuz; Geels, Camilla; Giannakopoulos, Christos; Hedegaard, Gitte B.; Katragkou, Eleni; Langner, Joakim; Lei, Hang; Manders, Astrid; Melas, Dimitris; Meleux, Frédérik; Rouïl, Laurence; Sofiev, Mikhail; Soares, Joana; Stevenson, David S.; Tombrou-Tzella, Maria; Varotsos, Konstantinos V.; Young, Paul

2015-08-01

Ozone air pollution is identified as one of the main threats bearing upon human health and ecosystems, with 25 000 deaths in 2005 attributed to surface ozone in Europe (IIASA 2013 TSAP Report #10). In addition, there is a concern that climate change could negate ozone pollution mitigation strategies, making them insufficient over the long run and jeopardising chances to meet the long term objective set by the European Union Directive of 2008 (Directive 2008/50/EC of the European Parliament and of the Council of 21 May 2008) (60 ppbv, daily maximum). This effect has been termed the ozone climate penalty. One way of assessing this climate penalty is by driving chemistry-transport models with future climate projections while holding the ozone precursor emissions constant (although the climate penalty may also be influenced by changes in emission of precursors). Here we present an analysis of the robustness of the climate penalty in Europe across time periods and scenarios by analysing the databases underlying 11 articles published on the topic since 2007, i.e. a total of 25 model projections. This substantial body of literature has never been explored to assess the uncertainty and robustness of the climate ozone penalty because of the use of different scenarios, time periods and ozone metrics. Despite the variability of model design and setup in this database of 25 model projection, the present meta-analysis demonstrates the significance and robustness of the impact of climate change on European surface ozone with a latitudinal gradient from a penalty bearing upon large parts of continental Europe and a benefit over the North Atlantic region of the domain. Future climate scenarios present a penalty for summertime (JJA) surface ozone by the end of the century (2071-2100) of at most 5 ppbv. Over European land surfaces, the 95% confidence interval of JJA ozone change is [0.44; 0.64] and [0.99; 1.50] ppbv for the 2041-2070 and 2071-2100 time windows, respectively.

Ecstasy Use among U.S. Adolescents from 1999 to 2008

PubMed Central

Wu, Ping; Liu, Xinhua; Pham, Trang Hoang; Jin, Jue; Fan, Bin; Jin, Zhezhen

2010-01-01

Aims To investigate trends in rates of ecstasy use among US adolescents from 1999 to 2008, and to examine the associations between the major sociodemographic factors, especially gender, and ecstasy use, during this period. Methods The adolescent subsamples (ages 12–17) from the 1999–2008 NHSDA/NSDUH surveys were used for the current study. Data from adolescents’ self–reports on use of ecstasy and of other drugs, as well as sociodemographic characteristics, were used in the analyses. Results There was an increasing trend in adolescent ecstasy use from 1999 to 2002, which was followed by a decreasing trend from 2002 to 2005, and a slight rise from 2005 to 2008. In contrast to some other drugs, ecstasy was more likely to be used by girls than by boys. This gender difference persisted over the 10-year period and could not be explained by other demographic factors. Conclusion Given the known health consequences of ecstasy use, especially for females, the observed gender difference in adolescent ecstasy use should be taken into account by drug prevention and intervention programs. PMID:20570447

Plants as indicators of urban air pollution (ozone and trace elements) in Pisa, Italy.

PubMed

Nali, Cristina; Crocicchi, Lara; Lorenzini, Giacomo

2004-07-01

A biennial integrated survey, based on the use of vascular plants for the bioindication of the effects of tropospheric ozone, was performed in the area of Pisa (Tuscany, Central Italy). It also investigated the distribution of selected trace elements in plants and the data were compared with those obtained from the use of passive samplers, automatic analysers of ozone and lichen biodiversity. Photochemically produced ozone proved to be present during the warm season, with maximum hourly means surpassing 100 ppb: the use of supersensitive tobacco Bel-W3 confirmed the value of detailed, cost-effective, monitoring surveys. Trials with clover clones demonstrate that sensitive plants undergo severe biomass reduction in the current ozone regime. The mean NC-S (clover clone sensitive to ozone):NC-R (resistant) biomass ratio ranged from 0.7 (in 1999) to 0.5 (in 2000). The economic impact of these reductions deserves attention. The data obtained using passive ozone samplers exceeded those obtained using an automatic analyser. The mapping of epiphytic lichen biodiversity was not related to the geographical ozone distribution as can be seen from the tobacco's response. Lettuce plants grown under standardized conditions were used positively as bioaccumulators of trace elements: Pb was abundantly recovered, but a large portion of this element was removed by washing.

Field responses of Prunus serotina and Asclepias syriaca to ozone around southern Lake Michigan.

PubMed

Bennett, J P; Jepsen, E A; Roth, J A

2006-07-01

Higher ozone concentrations east of southern Lake Michigan compared to west of the lake were used to test hypotheses about injury and growth effects on two plant species. We measured approximately 1000 black cherry trees and over 3000 milkweed stems from 1999 to 2001 for this purpose. Black cherry branch elongation and milkweed growth and pod formation were significantly higher west of Lake Michigan while ozone injury was greater east of Lake Michigan. Using classification and regression tree (CART) analyses we determined that departures from normal precipitation, soil nitrogen and ozone exposure/peak hourly concentrations were the most important variables affecting cherry branch elongation, and milkweed stem height and pod formation. The effects of ozone were not consistently comparable with the effects of soil nutrients, weather, insect or disease injury, and depended on species. Ozone SUM06 exposures greater than 13 ppm-h decreased cherry branch elongation 18%; peak 1-h exposures greater than 93 ppb reduced milkweed stem height 13%; and peak 1-h concentrations greater than 98 ppb reduced pod formation 11% in milkweed.

Long-term Evolution of Upper Stratospheric Ozone at Selected Stations of the Network for the Detection of Stratospheric Change (NDSC)

NASA Technical Reports Server (NTRS)

Steinbrecht, W.; Claude, H.; Schoenenborn, F.; McDermid, I. S.; LeBlanc, T.; Godin, S.; Swart, D. P. J.; Meijer, Y. J.; Bodecker, G. E.; Connor, B. J.;

The benefit of modeled ozone data for the reconstruction of a 99-year UV radiation time series

NASA Astrophysics Data System (ADS)

Junk, J.; Feister, U.; Helbig, A.; GöRgen, K.; Rozanov, E.; KrzyśCin, J. W.; Hoffmann, L.

2012-08-01

Solar erythemal UV radiation (UVER) is highly relevant for numerous biological processes that affect plants, animals, and human health. Nevertheless, long-term UVER records are scarce. As significant declines in the column ozone concentration were observed in the past and a recovery of the stratospheric ozone layer is anticipated by the middle of the 21st century, there is a strong interest in the temporal variation of UVERtime series. Therefore, we combined ground-based measurements of different meteorological variables with modeled ozone data sets to reconstruct time series of daily totals of UVER at the Meteorological Observatory, Potsdam, Germany. Artificial neural networks were trained with measured UVER, sunshine duration, the day of year, measured and modeled total column ozone, as well as the minimum solar zenith angle. This allows for the reconstruction of daily totals of UVERfor the period from 1901 to 1999. Additionally, analyses of the long-term variations from 1901 until 1999 of the reconstructed, new UVER data set are presented. The time series of monthly and annual totals of UVERprovide a long-term meteorological basis for epidemiological investigations in human health and occupational medicine for the region of Potsdam and Berlin. A strong benefit of our ANN-approach is the fact that it can be easily adapted to different geographical locations, as successfully tested in the framework of the COSTAction 726.

Analysis of year-to-year ozone variation over the subtropical western Pacific region using EP_TOMS data and CCSR/NIES nudging CTM

NASA Astrophysics Data System (ADS)

Zhou, L. B.; Akiyoshi, H.; Kawahira, K.

2003-10-01

The year-to-year ozone variation over the subtropical western Pacific region is studied, especially the ozone lows in the 1996/1997, 1998/1999, and 2001/2002 winters, using the Earth Probe Total Ozone Mapping Spectrometer (EP_TOMS) ozone data from August 1996 to July 2002. Regression analyses show that dynamical signals, such as the quasi-biennial oscillation, play an important role in determining total ozone variation. A nudging chemical transport model (CTM) is used to simulate the year-to-year ozone variation and explain the mechanism for producing ozone lows in a three-dimensional distribution of ozone. The CTM was developed using the Center for Climate System Research/National Institute for Environmental Studies (CCSR/NIES) atmospheric general circulation model and introducing a nudging process for temperature and horizontal wind velocity. The year-to-year ozone variation, especially the winter ozone low, is well simulated by the model excluding heterogeneous reaction processes between 45°S and 45°N latitude. Results show that the year-to-year ozone variation is mainly controlled by dynamical transport processes.

Long-term erythemal UV doses at Sodankylä estimated using total ozone, sunshine duration, and snow depth

NASA Astrophysics Data System (ADS)

Lindfors, A. V.; Arola, A.; Kaurola, J.; Taalas, P.; SvenøE, T.

2003-08-01

A method for estimating daily erythemal UV doses using total ozone, sunshine duration, and snow depth has been developed. The method consists of three steps: (1) daily clear-sky UV doses were simulated using the UVSPEC radiative transfer program, with daily values of total ozone as input data, (2) an empirical relationship was sought between the simulated clear-sky UV doses, the measured UV doses, and the duration of bright sunshine, and (3) daily erythemal UV doses were estimated using this relationship. The method accounts for the varying surface albedo by dividing the period of interest into winter and summer days, depending on the snow depth. Using this method, the daily erythemal UV doses at Sodankylä were estimated for the period 1950-1999. This was done using Tromsø's total ozone together with Sodankylä's own sunshine duration and snow depth as input data. Although the method is fairly simple, the results are in good agreement, even on the daily scale, with the UV radiation measured with the Brewer spectrophotometer at Sodankylä. Over the period 1950-1999 a statistically significant increasing trend of 3.9% per decade in erythemal UV doses was found for March. The fact that this trend is much more pronounced during the latter part of the period, which is also the case for April, suggests a connection to the stratospheric ozone depletion. For July, on the other hand, a significant decreasing trend of 3.3% per decade, supported by the changes in both total ozone and sunshine duration, was found.

Long-term Ozone Changes and Associated Climate Impacts in CMIP5 Simulations

NASA Technical Reports Server (NTRS)

Eyring, V.; Arblaster, J. M.; Cionni, I.; Sedlacek, J.; Perlwitz, J.; Young, P. J.; Bekki, S.; Bergmann, D.; Cameron-Smith, P.; Collins, W. J.;

Overview for the reanalysis of Mariner 9 UV spectrometer data for ozone, cloud, and dust abundances, and their interaction over climate timescales

NASA Technical Reports Server (NTRS)

Lindner, Bernhard Lee

1992-01-01

Mariner 9 UV spectrometer data were reinverted for the ozone abundance, cloud abundance, dust abundance, and polar-cap albedo. The original reduction of the spectra ignored the presence of atmospheric dust and clouds, even though their abundance is substantial and can mask appreciable amounts of ozone if not accounted for (Lindner, 1988). The Mariner 9 ozone data has been used as a benchmark in all theoretical models of atmospheric composition, escape, and photochemistry. A second objective is to examine the data for the interrelationship of the ozone cycle, dust cycle, and cloud cycle, on an annual, inter-annual, and climatic basis, testing predictions by Lindner (1988). This also has implications for many terrestrial ozone studies, such as the ozone hole, acid rain, and ozone-smog. A third objective is to evaluate the efficacy of the reflectance spectroscopy technique at retrieving the ozone abundance on Mars. This would be useful for planning ozone observations on future Mars missions or the terrestrial troposphere.

A Total Ozone Dependent Ozone Profile Climatology Based on Ozone-Sondes and Aura MLS Data

NASA Astrophysics Data System (ADS)

Labow, G. J.; McPeters, R. D.; Ziemke, J. R.

2014-12-01

A new total ozone-based ozone profile climatology has been created for use in satellite and/or ground based ozone retrievals. This climatology was formed by combining data from the Microwave Limb Sounder (MLS) with data from balloon sondes and binned by zone and total ozone. Because profile shape varies with total column ozone, this climatology better captures the ozone variations than the previously used seasonal climatologies, especially near the tropopause. This is significantly different than ozone climatologies used in the past as there is no time component. The MLS instrument on Aura has excellent latitude coverage and measures ozone profiles daily from the upper troposphere to the lower mesosphere at ~3.5 km resolution. Almost a million individual MLS ozone measurements are merged with data from over 55,000 ozonesondes which are then binned as a function of total ozone. The climatology consists of average ozone profiles as a function of total ozone for six 30 degree latitude bands covering altitudes from 0-75 km (in Z* pressure altitude coordinates). This new climatology better represents the profile shape as a function of total ozone than previous climatologies and shows some remarkable and somewhat unexpected correlations between total ozone and ozone in the lower altitudes, particularly in the lower and middle troposphere. These data can also be used to infer biases and errors in either the MLS retrievals or ozone sondes.

Tropospheric ozone maxima observed over the Arabian Sea during the pre-monsoon

NASA Astrophysics Data System (ADS)

Jia, Jia; Ladstätter-Weißenmayer, Annette; Hou, Xuewei; Rozanov, Alexei; Burrows, John P.

2017-04-01

An enhancement of the tropospheric ozone column (TOC) over Arabian Sea (AS) during the pre-monsoon season is reported in this study. The potential sources of the AS spring ozone pool are investigated by use of multiple data sets (e.g., SCIAMACHY Limb-Nadir-Matching TOC, OMI/MLS TOC, TES TOC, MACC reanalysis data, MOZART-4 model and HYSPLIT model). Three-quarters of the enhanced ozone concentrations are attributed to the 0-8 km height range. The main source of the ozone enhancement is considered to be caused by long-range transport of ozone pollutants from India (˜ 50 % contributions to the lowest 4 km, ˜ 20 % contributions to the 4-8 km height range), the Middle East, Africa and Europe (˜ 30 % in total). In addition, the vertical pollution accumulation in the lower troposphere, especially at 4-8 km, was found to be important for the AS spring ozone pool formation. Local photochemistry, on the other hand, plays a negligible role in producing ozone at the 4-8 km height range. In the 0-4 km height range, ozone is quickly removed by wet deposition. The AS spring TOC maxima are influenced by the dynamical variations caused by the sea surface temperature (SST) anomaly during the El Niño period in 2005 and 2010 with a ˜ 5 DU decrease.

Not just about sunburn--the ozone hole's profound effect on climate has significant implications for Southern Hemisphere ecosystems.

PubMed

Robinson, Sharon A; Erickson, David J

2015-02-01

Climate scientists have concluded that stratospheric ozone depletion has been a major driver of Southern Hemisphere climate processes since about 1980. The implications of these observed and modelled changes in climate are likely to be far more pervasive for both terrestrial and marine ecosystems than the increase in ultraviolet-B radiation due to ozone depletion; however, they have been largely overlooked in the biological literature. Here, we synthesize the current understanding of how ozone depletion has impacted Southern Hemisphere climate and highlight the relatively few documented impacts on terrestrial and marine ecosystems. Reviewing the climate literature, we present examples of how ozone depletion changes atmospheric and oceanic circulation, with an emphasis on how these alterations in the physical climate system affect Southern Hemisphere weather, especially over the summer season (December-February). These potentially include increased incidence of extreme events, resulting in costly floods, drought, wildfires and serious environmental damage. The ecosystem impacts documented so far include changes to growth rates of South American and New Zealand trees, decreased growth of Antarctic mosses and changing biodiversity in Antarctic lakes. The objective of this synthesis was to stimulate the ecological community to look beyond ultraviolet-B radiation when considering the impacts of ozone depletion. Such widespread changes in Southern Hemisphere climate are likely to have had as much or more impact on natural ecosystems and food production over the past few decades, than the increased ultraviolet radiation due to ozone depletion. © 2014 John Wiley & Sons Ltd.

Ozone profile measurements at McMurdo Station Antarctica during the spring of 1987

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Harder, J. W.; Rosen, J. M.; Hereford, J.; Carpenter, J. R.

1988-01-01

During the Antarctic spring of 1986, 33 ozone soundings were conducted from McMurdo Station. These data indicated that the springtime decrease in ozone occurred rapidly between the altitudes of 12 and 20 km. During 1987, these measurements were repeated with 50 soundings between 29 August and 9 November. Digital conversions of standard electrochemical cell ozonesondes were again employed. The ozonesonde pumps were individually calibrated for flow rate as the high altitude performance of these pumps have been in question. While these uncertainties are not large in the region of the ozone hole, they are significant at high altitude and apparently resulted in an underestimate of total ozone of about 7 percent (average) as compared to the Total Ozone Mapping Spectrometer (TOMS) in 1986, when the flow rate recommended by the manufacturer was used. At the upper altitudes (approx. 30 km) the flow rate may be overestimated by as much as 15 percent using recommended values (see Harder et al., The UW Digital Ozonesonde: Characteristics and Flow Rate Calibration, poster paper, this workshop). These upper level values are used in the extrapolation, at constant mixing ratio, required to complete the sounding for total ozone. The first sounding was on 29 August, prior to major ozone depletion, when 274 DU total ozone (25 DU extrapolated) was observed. By early October total ozone had decreased to the 150 DU range; it then increased during mid-October owing to motion of the vortex and returned to a value of 148 DU (29 DU extrapolated) on 27 October.

ER-2 #809 awaits pilot entry for the third flight of the SAGE III Ozone Loss and Validation Experime

NASA Technical Reports Server (NTRS)

2000-01-01

ER-2 #809 awaiting pilot entry for the third flight of the SAGE III Ozone Loss and Validation Experiment (SOLVE). The ER-2, a civilian variant of Lockheed's U-2, and another NASA flying laboratory, Dryden's DC-8, were based north of the Arctic Circle in Kiruna, Sweden during the winter of 2000 to study ozone depletion as part of SOLVE. A large hangar built especially for research, 'Arena Arctica' housed the instrumented aircraft and the scientists. Scientists have observed unusually low levels of ozone over the Arctic during recent winters, raising concerns that ozone depletion there could become more widespread as in the Antarctic ozone hole. The NASA-sponsored international mission took place between November 1999 and March 2000 and was divided into three phases. The DC-8 was involved in all three phases returning to Dryden between each phase. The ER-2 flew sample collection flights between January and March, remaining in Sweden from Jan. 9 through March 16. 'The collaborative campaign will provide an immense new body of information about the Arctic stratosphere,' said program scientist Dr. Michael Kurylo, NASA Headquarters. 'Our understanding of the Earth's ozone will be greatly enhanced by this research.' ER-2s bearing tail numbers 806 and 809 are used as airborne science platforms by NASA's Dryden Flight Research Center. The aircraft are platforms for a variety of high-altitude science missions flown over various parts of the world. They are also used for earth science and atmospheric sensor research and development, satellite calibration and data validation. The ER-2s are capable of carrying a maximum payload of 2,600 pounds of experiments in a nose bay, the main equipment bay behind the cockpit, two wing-mounted superpods and small underbody and trailing edges. Most ER-2 missions last about six hours with ranges of about 2,200 nautical miles. The aircraft typically fly at altitudes above 65,000 feet. On November 19, 1998, an ER-2 set a world record for

On the Tropospheric Measurements of Ozone by the Stratospheric Aerosol and Gas Experiment II (SAGE II, version 6.1) in the Tropics

NASA Technical Reports Server (NTRS)

Kar, J.; Trepte, C. R.; Thomason, L. W.; Zawodny, J. M.; Cunnold, D. M.; Wang, H. J.

2002-01-01

Tropospheric measurements of ozone from SAGE II (version 6.1) in the tropics have been analyzed using 12 years of data (1985-1990, 1994-1999). The seasonally averaged vertical profiles of the ozone mixing ratio in the upper troposphere have been presented for the first time from satellite measurements. These profiles show qualitative similarities with corresponding seasonal mean ozonesonde profiles at northern and southern tropical stations and are about 40-50% less than the sonde values. Despite this systematic offset, the measurements appear to be consistent with a zonal wave one pattern in the upper tropospheric column ozone and with the recently predicted summertime ozone enhancement over the Middle East. These results thus affirm the usefulness of the occultation method in studying tropospheric ozone.

The Observed Response of Ozone Monitoring Instrument (OMI) NO2 Columns to NOx Emission Controls on Power Plants in the United States: 2005-2011

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; deFoy, Benjamin; Lamsal, Lok N.; Streets, David G.; Lu, Zifeng; Pickering, Kenneth E.; Krotkov, Nickolay A.

2013-01-01

We show that Aura Ozone Monitoring Instrument (OMI) nitrogen dioxide (NO2) tropospheric column data may be used to assess changes of the emissions of nitrogen oxides (NOx) from power plants in the United States, though careful interpretation of the data is necessary. There is a clear response for OMI NO2 data to NOx emission reductions from power plants associated with the implementation of mandated emission control devices (ECDs) over the OMI record (2005e2011). This response is scalar for all intents and purposes, whether the reduction is rapid or incremental over several years. However, it is variable among the power plants, even for those with the greatest absolute decrease in emissions. We document the primary causes of this variability, presenting case examples for specific power plants.

Accurate Satellite-Derived Estimates of Tropospheric Ozone Radiative Forcing

NASA Technical Reports Server (NTRS)

Joiner, Joanna; Schoeberl, Mark R.; Vasilkov, Alexander P.; Oreopoulos, Lazaros; Platnick, Steven; Livesey, Nathaniel J.; Levelt, Pieternel F.

2008-01-01

Estimates of the radiative forcing due to anthropogenically-produced tropospheric O3 are derived primarily from models. Here, we use tropospheric ozone and cloud data from several instruments in the A-train constellation of satellites as well as information from the GEOS-5 Data Assimilation System to accurately estimate the instantaneous radiative forcing from tropospheric O3 for January and July 2005. We improve upon previous estimates of tropospheric ozone mixing ratios from a residual approach using the NASA Earth Observing System (EOS) Aura Ozone Monitoring Instrument (OMI) and Microwave Limb Sounder (MLS) by incorporating cloud pressure information from OMI. Since we cannot distinguish between natural and anthropogenic sources with the satellite data, our estimates reflect the total forcing due to tropospheric O3. We focus specifically on the magnitude and spatial structure of the cloud effect on both the shortand long-wave radiative forcing. The estimates presented here can be used to validate present day O3 radiative forcing produced by models.

AN ANNUAL EVALUATION OF THE 2005 RELEASE OF MODELS-3 CMAQ

EPA Science Inventory

An annual operation performance evaluation of the 2005 release of Models-3 CMAQ v4.5 has been performed. The poster presented results from the winter and summer season for sulfate, nitrate, ammonium, elemental carbon, organic carbon, PM2.5 mass and AQS 8-hr maximum ozone. Stati...

Evidence of Stratosphere-to-Troposphere Transport Within a Mesoscale Model and Total Ozone Mapping Spectrometer Total Ozone

NASA Technical Reports Server (NTRS)

Olsen, Mark A.; Stanford, John L.

2001-01-01

We evaluate evidence for stratospheric mass transport into, and mass remaining in, the troposphere during an intense midlatitude cyclone. Mesoscale forecast model analysis fields from the Mesoscale Analysis and Prediction System were matched with total ozone observations from the Total Ozone Measurement Spectrometer. Combined with parcel back trajectory calculations, the analyses imply that two mechanisms contributed to the mass exchange: (1) An area of dynamically induced exchange was observed on the cyclone's southern edge. Parcels originally in the stratosphere crossed the jet core and were diluted through turbulent mixing with tropospheric air; (2) Diabetic effects reduced parcel potential vorticity (PC) for trajectories traversing precipitation regions, creating a 'PV hole' signature in the center of the cyclone. Air with characteristics of ozone and water vapor found in the lower stratosphere remained in the troposphere. The strength of the latter process may be unusual. Combined with other research, these results suggest that precipitation-induced diabetic effects can significantly modify (either decreasing or increasing) parcel potential vorticity, depending on parcel trajectory configuration with respect to maximum heating regions and jet core. The diabetic heating effect on stratosphere-troposphere exchange (STE) is more important to tropopause erosion than to altering parcel trajectories. In addition, these results underline the importance of using not only PC but also chemical constituents for diagnoses of STE.

Influence of ozone and nitrogen deposition on bark beetle activity under drought conditions

Treesearch

Michele Eatough Jones; Timothy D. Paine; Mark E. Fenn; Mark A. Poth

2004-01-01

Four years of severe drought from 1999 through 2003 led to unprecedented bark beetle activity in ponderosa and Jeffrey pine in the San Bernardino and San Jacinto Mountains of southern California. Pines in the San Bernardino Mountains also were heavily impacted by ozone and nitrogenous pollutants originating from urban and agricultural areas in the Los Angeles basin. We...

Field responses of Prunus serotina and Asclepias syriaca to ozone around southern Lake Michigan

USGS Publications Warehouse

Bennett, J.P.; Jepsen, E.A.; Roth, J.A.

2006-01-01

Higher ozone concentrations east of southern Lake Michigan compared to west of the lake were used to test hypotheses about injury and growth effects on two plant species. We measured approximately 1000 black cherry trees and over 3000 milkweed stems from 1999 to 2001 for this purpose. Black cherry branch elongation and milkweed growth and pod formation were significantly higher west of Lake Michigan while ozone injury was greater east of Lake Michigan. Using classification and regression tree (CART) analyses we determined that departures from normal precipitation, soil nitrogen and ozone exposure/peak hourly concentrations were the most important variables affecting cherry branch elongation, and milkweed stem height and pod formation. The effects of ozone were not consistently comparable with the effects of soil nutrients, weather, insect or disease injury, and depended on species. Ozone SUM06 exposures greater than 13 ppm-h decreased cherry branch elongation 18%; peak 1-h exposures greater than 93 ppb reduced milkweed stem height 13%; and peak 1-h concentrations greater than 98 ppb reduced pod formation 11% in milkweed. Decreased cherry branch elongation, milkweed stem height and pod production, and foliar injury on both species occurred at sites around southern Lake Michigan at ozone exposures of 13 SUM06 ppm-h and 93a??98 ppb peak hourly.

Copernicus atmospheric service for stratospheric ozone: validation and intercomparison of four near real-time analyses, 2009-2012

NASA Astrophysics Data System (ADS)

Lefever, K.; van der A, R.; Baier, F.; Christophe, Y.; Errera, Q.; Eskes, H.; Flemming, J.; Inness, A.; Jones, L.; Lambert, J.-C.; Langerock, B.; Schultz, M. G.; Stein, O.; Wagner, A.; Chabrillat, S.

2014-05-01

polar lower stratosphere during ozone depletion events. The assimilation of near real-time (NRT) Microwave Limb Sounder (MLS) profiles which only go down to 68 hPa is not able to correct for the deficiency of the underlying MOZART model, which may be related to the applied meteorological fields. Biases of BASCOE compared to ozonesonde or ACE-FTS ozone profiles do not exceed 10% over the entire vertical stratospheric range, thanks to the good performance of the model in ozone hole conditions and the assimilation of offline MLS profiles going down to 215 hPa. TM3DAM provides very realistic total ozone columns, but is not designed to provide information on the vertical distribution of ozone. Compared to ozonesondes and ACE-FTS satellite data, SACADA performs best in the Arctic, but shows large biases (>50%) for ozone in the lower stratosphere in the Tropics and in the Antarctic, especially during ozone hole conditions. This study shows that ozone analyses with realistic total ozone column densities do not necessarily yield good agreement with the observed ozone profiles. It also shows the large benefit obtained from the assimilation of a single limb-scanning instrument (Aura MLS) with a high density of observations. Hence even state-of-the-art models of stratospheric chemistry still require the assimilation of limb observations for a correct representation of the vertical distribution of ozone in the stratosphere.

Spatial regression analysis on 32 years of total column ozone data

NASA Astrophysics Data System (ADS)

Knibbe, J. S.; van der A, R. J.; de Laat, A. T. J.

2014-08-01

between 30° N and 30° S, particularly over the Pacific. The contribution of explanatory variables describing seasonal ozone variation is generally large at mid- to high latitudes. We observe ozone increases with potential vorticity and day length and ozone decreases with geopotential height and variable ozone effects due to the polar vortex in regions to the north and south of the polar vortices. Recovery of ozone is identified globally. However, recovery rates and uncertainties strongly depend on choices that can be made in defining the explanatory variables. The application of several trend models, each with their own pros and cons, yields a large range of recovery rate estimates. Overall these results suggest that care has to be taken in determining ozone recovery rates, in particular for the Antarctic ozone hole.

Application of OMI Observations to a Space-Based Indicator of NOx and VOC Controls on Surface Ozone Formation

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; Olson, Jennifer R.; Sillman, Sanford; Martin, Randall V.; Lamsal, Lok; Hu, Yongtao; Pickering, Kenneth E.; Retscher, Christian; Allen, Dale J.;

Recent Advances in Ozone Data Assimilation at the GMAO - Towards a New Reanalysis

NASA Technical Reports Server (NTRS)

Krzysztof, Wargan; Pawson, S.; Nielsen, J. E.; Witte, J.; Douglass, A.; Strahan, S.; Joiner, J.; Bhartia, P. K.; Livesey, N.; Read, W.;

Five Blind Men and an Elephant: Comparing Aura Ozone Datasets and Sonde with Model Simulations

NASA Astrophysics Data System (ADS)

Tang, Q.; Prather, M. J.

2011-12-01

The four Earth Observing System (EOS) Aura satellite ozone measurements (HIRDLS, MLS, OMI, and TES) as well as the coincident WOUDC sonde are the five ``blind men'' touching the ``elephant'' (ozone). They all measure ozone (O3) in the upper troposphere and lower stratosphere (UT/LS) region, providing the great opportunity to study how the tropospheric ozone is influenced by the stratospheric source, an important tropospheric ozone budget term with large uncertainties and discrepancies across different models and methods. Based upon the 2-D autocorrelation for the tropospheric column ozone anomalies of the OMI swaths, we show that the stratosphere-troposphere exchange (STE) processes occur on the scale of a few hundred kilometers. Applying the high resolution (1o±1o±40-layer±0.5 hr) atmospheric chemistry transport model (CTM) as a transfer standard, we compare the noncoincident Aura level 2 swath datasets with the exact matching simulations of each measurement to investigate the consistency of different instruments as well as evaluate the accuracy of modeled ozone. Different signs of the CTM biases against HIRDLS, MLS, and TES are found from tropics to northern hemisphere (NH) mid-latitudes in July 2005 at 215 hPa and over tropics at 147 hPa for July 2005 and January 2006, suggesting inconsistency across these Aura datasets. On the other hand, the CTM has great positive biases against satellite observations in the lower stratosphere of winter time southern hemisphere (SH) mid-latitudes, which is probably attributed to the problems in the stratospheric circulation of the driving met-fields. The model's ability of reproducing STE-related processes, such as tropospheric folds (TFs), is confirmed by the comparisons with WOUDC sonde. We found eight cases in year 2005 with all the four Aura measurements available and folding structures in the coincident sonde profile. The case studies indicate that all the four Aura instruments demonstrate some skills in catching the

The unusual persistence of an ozone hole over a southern mid-latitude station during the Antarctic spring 2009: a multi-instrument study

NASA Astrophysics Data System (ADS)

Wolfram, E. A.; Salvador, J.; Orte, F.; D'Elia, R.; Godin-Beekmann, S.; Kuttippurath, J.; Pazmiño, A.; Goutail, F.; Casiccia, C.; Zamorano, F.; Paes Leme, N.; Quel, E. J.

2012-10-01

Record-low ozone column densities (with a minimum of 212 DU) persisted over three weeks at the Río Gallegos NDACC (Network for the Detection of Atmospheric Composition Change) station (51.5° S, 69.3° W) in November 2009. Total ozone remained two standard deviations below the climatological mean for five consecutive days during this period. The statistical analysis of 30 years of satellite data from the Multi Sensor Reanalysis (MSR) database for Río Gallegos revealed that such a long-lasting low-ozone episode is a rare occurrence. The event is examined using height-resolved ozone lidar measurements at Río Gallegos, and observations from satellite and ground-based instruments. The computed relative difference between the measured total ozone and the climatological monthly mean shows reductions varying between 10 and 30% with an average decrease of 25%. The mean absolute difference of total ozone column with respect to climatological monthly mean ozone column is around 75 DU. Extreme values of the UV index (UVI) were measured at the ground for this period, with the daily maximum UVI of around 13 on 15 and 28 November. The high-resolution MIMOSA-CHIM (Modélisation Isentrope du transport Méso-échelle de l'Ozone Stratosphérique par Advection) model was used to interpret the ozone depletion event. An ozone decrease of about 2 ppmv was observed in mid-November at the 550 K isentropic level (~22 km). The position of Río Gallegos relative to the polar vortex was classified using equivalent latitude maps. During the second week of November, the vortex was over the station at all isentropic levels, but after 20 November and until the end of the month, only the 10 lower levels in the stratosphere were affected by vortex overpasses with ozone poor air masses. A rapid recovery of the ozone column density was observed later, due to an ozone rich filament moving over Río Gallegos between 18 and 24 km in the first two weeks of December 2009.

Climate Change Impacts on Projections of Excess Mortality at 2030 using Spatially-Varying Ozone-Temperature Risk Surfaces

PubMed Central

Wilson, Ander; Reich, Brian J.; Nolte, Christopher G.; Spero, Tanya L.; Hubbell, Bryan; Rappold, Ana G.

2017-01-01

We project the change in ozone-related mortality burden attributable to changes in climate between a historical (1995–2005) and near-future (2025–2035) time period while incorporating a nonlinear and synergistic effect of ozone and temperature on mortality. We simulate air quality from climate projections varying only biogenic emissions and holding anthropogenic emissions constant, thus attributing changes in ozone only to changes in climate and independent of changes in air pollutant emissions. We estimate nonlinear, spatially-varying, ozone-temperature risk surfaces for 94 US urban areas using observed data. Using the risk surfaces and climate projections we estimate daily mortality attributable to ozone exceeding 40 ppb (moderate level) and 75 ppb (US ozone NAAQS) for each time period. The average increases in city-specific median April-October ozone and temperature between time periods are 1.02 ppb and 1.94°F; however, the results varied by region. Increases in ozone due to climate change result in an increase in ozone-mortality burden. Mortality attributed to ozone exceeding 40 ppb increases by 7.7% (1.6%, 14.2%). Mortality attributed to ozone exceeding 75 ppb increases by 14.2% (1.6%, 28.9%). The absolute increase in excess ozone mortality is larger for changes in moderate ozone levels, reflecting the larger number of days with moderate ozone levels. PMID:27005744

Sources of Springtime Tropospheric Ozone Over North China: A Modeling Analysis of Ozonesonde and Satellite Observations

NASA Astrophysics Data System (ADS)

Liu, H.; Chan, C.; Huang, J.; Zhang, Y.; Choi, H.; Crawford, J. H.; Considine, D. B.; Zheng, X.; Oltmans, S. J.; Liu, S. C.; Zhang, L.; Liu, X.; Thouret, V.

2012-12-01

Tropospheric ozone concentrations and emissions of NOx have both increased significantly over China as a result of rapid industrialization during the past decade. These trends degrade local and regional air quality and have important effects on background tropospheric ozone and surface ozone over downwind North Pacific and North America. In-situ observations of tropospheric ozone over China are therefore essential to testing and improving our understanding of the impact of Asian anthropogenic (versus natural) emissions and various chemical, physical, and dynamical processes on both regional and global tropospheric ozone. Despite their critical importance, in-situ observations of tropospheric ozone profiles over China have been few and far between in most of the country. To investigate the ensemble of processes that control the distribution, variability, and sources of springtime tropospheric ozone over China and its surrounding regions, an intensive ozonesonde sounding campaign, called Transport of Air Pollutants and Tropospheric Ozone over China (TAPTO-China), was conducted at nine locations across China in the springs of 2004 (South China) and 2005 (North China). In this paper, we use a global 3-D model of tropospheric chemistry (GEOS-Chem) to examine the characteristics of distribution and variability and quantify various sources of tropospheric ozone over North China by analysis of intensive ozonesonde data obtained at four stations in North / Northwest China during the second phase of TAPTO-China (April-May 2005). These four stations include Xining (36.43N, 101.45E), Beijing (39.80N, 116.18E), Longfengshan (44.44N, 127.36E), and Aletai (47.73N, 88.08E). We drive GEOS-Chem with two sets of assimilated meteorological observations (GEOS-4 and GEOS-5) from the Goddard Earth Observing System (GEOS) of the NASA Global Modeling and Assimilation Office (GAMO), allowing us to examine the impacts of variability in meteorology. We show that the observed tropospheric

Structure and stress state of Hawaiian island basalts penetrated by the Hawaii Scientific Drilling Project deep core hole

USGS Publications Warehouse

Morin, R.H.; Wilkens, R.H.

2005-01-01

As part of the Hawaii Scientific Drilling Project (HSDP), an exploratory hole was drilled in 1993 to a depth of 1056 meters below sea level (mbsl) and a deeper hole was drilled to 3098 mbsl in 1999. A set of geophysical well logs was obtained in the deeper hole that provides fundamental information regarding the structure and the state of stress that exist within a volcanic shield. The acoustic televiewer generates digital, magnetically oriented images of the borehole wall, and inspection of this log yields a continuous record of fracture orientation with depth and also with age to 540 ka. The data depict a clockwise rotation in fracture strike through the surficial Mauna Loa basalts that settles to a constant heading in the underlying Mauna Kea rocks. This behavior reflects the depositional slope directions of lavas and the locations of volcanic sources relative to the drill site. The deviation log delineates the trajectory of the well bore in three-dimensional space. This path closely follows changes in fracture orientation with depth as the drill bit is generally prodded perpendicular to fracture strike during the drilling process. Stress-induced breakouts observed in the televiewer log identify the orientations ot the maximum and minimum horizontal principal stresses to be north-south and east-west, respectively. This stress state is attributed to the combination of a sharp break in onshore-offshore slope that reduces stress east-west and the emergence of Kilauea that increases stress north-south. Breakouts are extensive and appear over approximately 30% of the open hole. Copyright 2005 by the American Geophysical Union.

Black holes surrounded by uniformly rotating rings

NASA Astrophysics Data System (ADS)

Petroff, D.; Ansorg, M.

2006-01-01

This paper provides a brief summary of a talk on rings surrounding Black Holes that was given at the spring meeting 2005 of the German physical society (DPG). A detailed discussion of the topics covered in the talk can be found in [1].

Global ozone observations from the UARS MLS: An overview of zonal-mean results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Froidevaux, L.; Waters, J.W.; Read, W.G.

1994-10-15

Global ozone observations from the Microwave Limb Sounder (MLS) aboard the Upper Atmosphere Research Satellite (UARS) are presented, in both vertically resolved and column abundance formats. The authors review the zonal-mean ozone variations measured over the two and a half years since launch in September 1991. Well-known features such as the annual and semiannual variations are ubiquitous. In the equatorial regions, longer-term changes are believed to be related to the quasi-biennial oscillation (QBO), with a strong semiannual signal above 20 hPa. Ozone values near 50 hPa exhibit an equatorial low from October 1991 to June 1992, after which the lowmore » ozone pattern splits into two subtropical lows (possibly in connection with residual circulation changes tied to the QBO) and returns to an equatorial low in September 1993. The ozone hole development at high southern latitudes is apparent in MLS column data integrated down to 100 hPa, with a pattern generally consistent with Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) measurements of total column; the MLS data reinforce current knowledge of this lower-stratospheric phenomenon by providing a height-dependent view of the variations. The region from 30{degrees}S to 30{degrees}N (an area equal to half the global area) shows very little change in the ozone column from year to year and within each year. Finally, residual ozone values extracted from TOMS-minus-MLS column data are briefly presented as a preliminary view into the potential usefulness of such studies, with information on tropospheric ozone as an ultimate goal. 99 refs., 13 figs.« less

Representativeness of single lidar stations and SBUV overpasses in zonally averaged ozone layered means, their trends and the role of proxies

NASA Astrophysics Data System (ADS)

Petropavlovskikh, I. V.; Zerefos, C. S.; Kapsomenakis, J. N.; Eleftheratos, K.; Tourpali, K.; Hubert, D.; Godin-Beekmann, S.; Steinbrecht, W.; Frith, S. M.; Sofieva, V.

2017-12-01

The paper is focusing on the representativeness of single lidar stations and SBUV overpasses in searching for trends in the vertical ozone profiles. It was found that from the lower to the upper stratosphere single or grouped stations correlate well with zonal means calculated from SBUV overpasses in a global perspective. The best representativeness in vertical ozone profiles is found within 5 degrees of latitude north or south of any LIDAR station or SBUV overpasses at which the latitude range is expanded as we move to the upper stratospheric layers. The paper includes a detailed analysis on a ranking of proxy footprints in the vertical ozone profiles. Major proxies studied are of different kinds: those outside of the earth system (solar cycle), those who represent dynamic processes (the QBO, the AO, AAO, ENSO), the volcanic aerosol component (AOD) and the manmade contribution to chemistry (EESC). The trends have been studied after removal of proxies from the total available SBUV records during the period 1980-2015. As seen in the detailed contributions of the proxies major contributions come from chemistry, the solar cycle and AOD. It appears that at some particular years the synergistic contribution of proxies which although contribute smaller amplitudes to ozone individually, when composited can result to anomalies that may influence the long term change or trend in the ozone profiles. Notable periods for the synergistic negative anomalies can be seen in 1983, 1985, 1988, 1992, 1993, 1995, 1997, 1999, 2002, 2004, 2006, 2008, 2011, 2013. During all these years ozone at about 24 km dropped below -6% of the mean. The so-called "inflection point" between 1997 and 1999 marks the large reduction of the significant negative ozone trends, followed by the recent period of positive ozone change 1998-2015 which is observed above 15 hPa whose significance remains to be proven due to its smaller period in comparison to the total period of 36 years of ozone profiles (1980-2015).

Report of a large depletion in the ozone layer over southern Brazil and Uruguay by using multi-instrumental data

NASA Astrophysics Data System (ADS)

Bresciani, Caroline; Dornelles Bittencourt, Gabriela; Valentin Bageston, José; Kirsch Pinheiro, Damaris; Schuch, Nelson Jorge; Bencherif, Hassan; Paes Leme, Neusa; Vaz Peres, Lucas

2018-03-01

Ozone is one of the chemical compounds that form part of the atmosphere. It plays a key role in the stratosphere where the ozone layer is located and absorbs large amounts of ultraviolet radiation. However, during austral spring (August-November), there is a massive destruction of the ozone layer, which is known as the Antarctic ozone hole. This phenomenon decreases ozone concentration in that region, which may affect other regions in addition to the polar one. This anomaly may also reach mid-latitudes; hence, it is called the secondary effect of the Antarctic ozone hole. Therefore, this study aims to identify the passage of an ozone secondary effect (OSE) event in the region of the city of Santa Maria - RS (29.68° S, 53.80° W) by means of a multi-instrumental analysis using the satellites TIMED/SABER, AURA/MLS, and OMI-ERS. Measurements were made in São Martinho da Serra/RS - Brazil (29.53° S, 53.85° W) using a sounding balloon and a Brewer Spectrophotometer. In addition, the present study aims to describe and analyse the influence that this stratospheric ozone reduction has on temperatures presented by these instruments, including data collected through the radio occultation technique. The event was first identified by the AURA/MLS satellite on 19 October 2016 over Uruguay. This reduction in ozone concentration was found by comparing the climatology for the years 1996-1998 for the state of Rio Grande do Sul, which is close to Uruguay. This event was already observed in Santa Maria/RS-Brazil on 20 October 2016 as presented by the OMI-ERS satellite and the Brewer Spectrophotometer. Moreover, a significant decrease was reported by the TIMED/SABER satellite in Uruguay. On 21 October, the poor ozone air mass was still over the region of interest, according to the OMI-ERS satellite, data from the sounding balloon launched in Santa Maria/RS-Brazil, and measurements made by the AURA/MLS satellite. Furthermore, the influence of ozone on the

Evaluation of ACCMIP Outgoing Longwave Radiation from Tropospheric Ozone Using TES Satellite Observations.

NASA Technical Reports Server (NTRS)

Bowman, Kevin W.; Shindell, Drew Todd; Worden, H. M.; Lamarque, J. F.; Young, P. J.; Stevenson, D. S.; Qu, Z.; delaTorre, M.; Bergmann, D.; Cameron-Smith, P. J.;

NAEP 1999 Long-Term Trend Technical Analysis Report: Three Decades of Student Performance. NCES 2005-484

ERIC Educational Resources Information Center

Allen, Nancy L.; McClellan, Catherine A.; Stoeckel, Joan J.

2005-01-01

This report provides an update to the technical analysis procedures documenting the 1996 National Assessment of Educational Progress (NAEP) as presented in "The NAEP 1996 Technical Report" (Allen, Carlson, and Zelenak, 1999). It describes how the 1999 long-term trend data were incorporated into the trend analyses. Since no national main…

Free Radicals and Reactive Intermediates for the SAGE III Ozone Loss and Validation Experiment (SOLVE) Mission

NASA Technical Reports Server (NTRS)

Anderson, James G.

2001-01-01

This grant provided partial support for participation in the SAGE III Ozone Loss and Validation Experiment. The NASA-sponsored SOLVE mission was conducted Jointly with the European Commission-sponsored Third European Stratospheric Experiment on Ozone (THESEO 2000). Researchers examined processes that control ozone amounts at mid to high latitudes during the arctic winter and acquired correlative data needed to validate the Stratospheric Aerosol and Gas Experiment (SAGE) III satellite measurements that are used to quantitatively assess high-latitude ozone loss. The campaign began in September 1999 with intercomparison flights out of NASA Dryden Flight Research Center in Edwards. CA. and continued through March 2000. with midwinter deployments out of Kiruna. Sweden. SOLVE was co-sponsored by the Upper Atmosphere Research Program (UARP). Atmospheric Effects of Aviation Project (AEAP). Atmospheric Chemistry Modeling and Analysis Program (ACMAP). and Earth Observing System (EOS) of NASA's Earth Science Enterprise (ESE) as part of the validation program for the SAGE III instrument.

Spatial, temporal, and vertical variability of polar stratospheric ozone loss in the Arctic winters 2004/05-2009/10

NASA Astrophysics Data System (ADS)

Kuttippurath, J.; Godin-Beekmann, S.; Lefèvre, F.; Goutail, F.

2010-06-01

The stratospheric ozone loss during the Arctic winters 2004/05-2009/10 is investigated by using high resolution simulations from the chemical transport model Mimosa-Chim and observations from Microwave Limb Sounder (MLS) on Aura by the passive tracer technique. The winter 2004/05 was the coldest of the series with strongest chlorine activation. The ozone loss diagnosed from both model and measurements inside the polar vortex at 475 K ranges from ~1-0.7 ppmv in the warm winter 2005/06 to 1.7 ppmv in the cold winter 2004/05. Halogenated (chlorine and bromine) catalytic cycles contribute to 75-90% of the accumulated ozone loss at this level. At 675 K the lowest loss of ~0.4 ppmv is computed in 2008/09 from both simulations and observations and, the highest loss is estimated in 2006/07 by the model (1.3 ppmv) and in 2004/05 by MLS (1.5 ppmv). Most of the ozone loss (60-75%) at this level results from cycles catalysed by nitrogen oxides (NO and NO2) rather than halogens. At both 475 and 675 K levels the simulated ozone evolution inside the polar vortex is in reasonably good agreement with the observations. The ozone total column loss deduced from the model calculations at the MLS sampling locations inside the vortex ranges between 40 DU in 2005/06 and 94 DU in 2004/05, while that derived from observations ranges between 37 DU and 111 DU in the same winters. These estimates from both Mimosa-Chim and MLS are in general good agreement with those from the ground-based UV-VIS (ultra violet-visible) ozone loss analyses for the respective winters.

Application of quantitative structure activity relationship (QSAR) models to predict ozone toxicity in the lung.

PubMed

Kafoury, Ramzi M; Huang, Ming-Ju

2005-08-01

The sequence of events leading to ozone-induced airway inflammation is not well known. To elucidate the molecular and cellular events underlying ozone toxicity in the lung, we hypothesized that lipid ozonation products (LOPs) generated by the reaction of ozone with unsaturated fatty acids in the epithelial lining fluid and cell membranes play a key role in mediating ozone-induced airway inflammation. To test our hypothesis, we ozonized 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphatidylcholine (POPC) and generated LOPs. Confluent human bronchial epithelial cells were exposed to the derivatives of ozonized POPC-9-oxononanoyl, 9-hydroxy-9-hydroperoxynonanoyl, and 8-(5-octyl-1,2,4-trioxolan-3-yl-)octanoyl-at a concentration of 10 muM, and the activity of phospholipases A2 (PLA2), C (PLC), and D (PLD) was measured (1, 0.5, and 1 h, respectively). Quantitative structure-activity relationship (QSAR) models were utilized to predict the biological activity of LOPs in airway epithelial cells. The QSAR results showed a strong correlation between experimental and computed activity (r = 0.97, 0.98, 0.99, for PLA2, PLC, and PLD, respectively). The results indicate that QSAR models can be utilized to predict the biological activity of the various ozone-derived LOP species in the lung. Copyright 2005 Wiley Periodicals, Inc.

Near-real-time TOMS, telecommunications and meteorological support for the 1987 Airborne Antarctic Ozone Experiment

NASA Technical Reports Server (NTRS)

Ardanuy, P.; Victorine, J.; Sechrist, F.; Feiner, A.; Penn, L.

1988-01-01

The goal of the 1987 Airborne Antarctic Ozone Experiment was to improve the understanding of the mechanisms involved in the formation of the Antarctic ozone hole. Total ozone data taken by the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) played a central role in the successful outcome of the experiment. During the experiment, the near-real-time TOMS total ozone observations were supplied within hours of real time to the operations center in Punta Arenas, Chile. The final report summarizes the role which Research and Data Systems (RDS) Corporation played in the support of the experiment. The RDS provided telecommunications to support the science and operations efforts for the Airborne Antarctic Ozone Experiment, and supplied near real-time weather information to ensure flight and crew safety; designed and installed the telecommunications network to link NASA-GSFC, the United Kingdom Meteorological Office (UKMO), Palmer Station, the European Center for Medium-Range Weather Forecasts (ECMWF) to the operation at Punta Arenas; engineered and installed stations and other stand-alone systems to collect data from designated low-orbiting polar satellites and beacons; provided analyses of Nimbus-7 TOMS data and backup data products to Punta Arenas; and provided synoptic meteorological data analysis and reduction.

Mirrored changes in Antarctic ozone and stratospheric temperature in the late 20th versus early 21st centuries

NASA Astrophysics Data System (ADS)

Solomon, Susan; Ivy, Diane; Gupta, Mukund; Bandoro, Justin; Santer, Benjamin; Fu, Qiang; Lin, Pu; Garcia, Rolando R.; Kinnison, Doug; Mills, Michael

2017-08-01

Observed and modeled patterns of lower stratospheric seasonal trends in Antarctic ozone and temperature in the late 20th (1979-2000) and the early 21st (2000-2014) centuries are compared. Patterns of pre-2000 observed Antarctic ozone decreases and stratospheric cooling as a function of month and pressure are followed by opposite-signed (i.e., "mirrored") patterns of ozone increases and warming post-2000. An interactive chemistry-climate model forced by changes in anthropogenic ozone depleting substances produces broadly similar mirrored features. Statistical analysis of unforced model simulations (from long-term model control simulations of a few centuries up to 1000 years) suggests that internal and solar natural variability alone is unable to account for the pattern of observed ozone trend mirroring, implying that forcing is the dominant driver of this behavior. Radiative calculations indicate that ozone increases have contributed to Antarctic warming of the lower stratosphere over 2000-2014, but dynamical changes that are likely due to internal variability over this relatively short period also appear to be important. Overall, the results support the recent finding that the healing of the Antarctic ozone hole is underway and that coupling between dynamics, chemistry, and radiation is important for a full understanding of the causes of observed stratospheric temperature and ozone changes.

Tropospheric jet response to Antarctic ozone depletion: An update with Chemistry-Climate Model Initiative (CCMI) models

NASA Astrophysics Data System (ADS)

Son, Seok-Woo; Han, Bo-Reum; Garfinkel, Chaim I.; Kim, Seo-Yeon; Park, Rokjin; Abraham, N. Luke; Akiyoshi, Hideharu; Archibald, Alexander T.; Butchart, N.; Chipperfield, Martyn P.; Dameris, Martin; Deushi, Makoto; Dhomse, Sandip S.; Hardiman, Steven C.; Jöckel, Patrick; Kinnison, Douglas; Michou, Martine; Morgenstern, Olaf; O’Connor, Fiona M.; Oman, Luke D.; Plummer, David A.; Pozzer, Andrea; Revell, Laura E.; Rozanov, Eugene; Stenke, Andrea; Stone, Kane; Tilmes, Simone; Yamashita, Yousuke; Zeng, Guang

2018-05-01

The Southern Hemisphere (SH) zonal-mean circulation change in response to Antarctic ozone depletion is re-visited by examining a set of the latest model simulations archived for the Chemistry-Climate Model Initiative (CCMI) project. All models reasonably well reproduce Antarctic ozone depletion in the late 20th century. The related SH-summer circulation changes, such as a poleward intensification of westerly jet and a poleward expansion of the Hadley cell, are also well captured. All experiments exhibit quantitatively the same multi-model mean trend, irrespective of whether the ocean is coupled or prescribed. Results are also quantitatively similar to those derived from the Coupled Model Intercomparison Project phase 5 (CMIP5) high-top model simulations in which the stratospheric ozone is mostly prescribed with monthly- and zonally-averaged values. These results suggest that the ozone-hole-induced SH-summer circulation changes are robust across the models irrespective of the specific chemistry-atmosphere-ocean coupling.

Ozone

MedlinePlus

Ozone is a gas. It can be good or bad, depending on where it is. "Good" ozone occurs naturally about 10 to 30 miles above ... the sun's ultraviolet rays. Part of the good ozone layer is gone. Man-made chemicals have destroyed ...

Observations of Ozone-aerosol Correlated Behaviour in the Lower Stratosphere During the EASOE Campaign

NASA Technical Reports Server (NTRS)

Digirolamo, P.; Cacciani, M.; Disarra, A.; Fiocco, G.; Fua, D.; Joergensen, T. S.; Knudsen, B.; Larsen, N.

1992-01-01

The question of possible interactions between ozone and stratospheric aerosol has been open for a long time. Measurements carried out after the Mt. Agung and El Chicon eruptions showed evidence of negative correlations between the presence of volcanic stratospheric aerosols and ozone concentration. Evidence for negative correlations in the polar winter has been also found. It is only after the discovery of the Antarctic ozone hole that catalytic effects related to low temperature heterogeneous chemistry have become the object of much investigation, now extended to the role of volcanic aerosol in the ozone reduction. These phenomena can be the object of various interpretations, not mutually exclusive, including the effect of transport, diffuse radiation as well as heterogeneous chemistry. The present paper provides preliminary results of simultaneous measurements of ozone and aerosol, carried out at Thule, Greenland, during the winter 1991-92. The European Stratospheric Ozone Experiment (EASOE) was aimed at monitoring the winter Arctic stratosphere in order to obtain a deeper insight of the ozone destruction processes taking place in the polar regions. A large amount of aerosol was injected into the lower stratosphere by the recent eruption of Volcano Pinatubo. A lidar system, already operational in Thule since November 1990, has provided detailed measurements of the stratospheric aerosol concentration during EASOE. In the same period, a large number of ozonesondes were launched. Although no PSC formation was detected over Thule, the simultaneous measurement of the stratospheric aerosol and ozone profiles give the possibility to study interactions occurring in the stratosphere between these two constituents.

Variability of Antarctic ozone loss in the last decade (2004-2013): high resolution simulations compared to Aura MLS observations

NASA Astrophysics Data System (ADS)

Kuttippurath, J.; Godin-Beekmann, S.; Lefèvre, F.; Santee, M. L.; Froidevaux, L.; Hauchecorne, A.

2014-11-01

A detailed analysis of the polar ozone loss processes during ten recent Antarctic winters is presented with high resolution Mimosa-Chim model simulations and high frequency polar vortex observations from the Aura Microwave Limb Sounder (MLS) instrument. Our model results for the Antarctic winters 2004-2013 show that chemical ozone loss starts in the edge region of the vortex at equivalent latitudes (EqLs) of 65-69° S in mid-June/July. The loss progresses with time at higher EqLs and intensifies during August-September over the range 400-600 K. The loss peaks in late September/early October, where all EqLs (65-83°) show similar loss and the maximum loss (>2 ppmv [parts per million by volume]) is found over a broad vertical range of 475-550 K. In the lower stratosphere, most winters show similar ozone loss and production rates. In general, at 500 K, the loss rates are about 2-3 ppbv sh-1 (parts per billion by volume/sunlit hour) in July and 4-5 ppbv sh-1 in August/mid-September, while they drop rapidly to zero by late September. In the middle stratosphere, the loss rates are about 3-5 ppbv sh-1 in July-August and October at 675 K. It is found that the Antarctic ozone hole (June-September) is controlled by the halogen cycles at about 90-95% (ClO-ClO, BrO-ClO, and ClO-O) and the loss above 700 K is dominated by the NOx cycle at about 70-75%. On average, the Mimosa-Chim simulations show that the very cold winters of 2005 and 2006 exhibit a maximum loss of ~3.5 ppmv around 550 K or about 149-173 DU over 350-850 K and the warmer winters of 2004, 2010, and 2012 show a loss of ~2.6 ppmv around 475-500 K or 131-154 DU over 350-850 K. The winters of 2007, 2008, and 2011 were moderately cold and thus both ozone loss and peak loss altitudes are between these two ranges (3 ppmv around 500 K or 150 ± 10 DU). The modeled ozone loss values are in reasonably good agreement with those estimated from Aura MLS measurements, but the model underestimates the observed ClO, largely due

16 CFR 260.11 - Ozone-safe and ozone-friendly claims.

Code of Federal Regulations, 2013 CFR

2013-01-01

... 16 Commercial Practices 1 2013-01-01 2013-01-01 false Ozone-safe and ozone-friendly claims. 260.11... THE USE OF ENVIRONMENTAL MARKETING CLAIMS § 260.11 Ozone-safe and ozone-friendly claims. It is... friendly to, the ozone layer or the atmosphere. Example 1: A product is labeled “ozone-friendly.” The claim...

16 CFR 260.11 - Ozone-safe and ozone-friendly claims.

Code of Federal Regulations, 2014 CFR

2014-01-01

... 16 Commercial Practices 1 2014-01-01 2014-01-01 false Ozone-safe and ozone-friendly claims. 260.11... THE USE OF ENVIRONMENTAL MARKETING CLAIMS § 260.11 Ozone-safe and ozone-friendly claims. It is... friendly to, the ozone layer or the atmosphere. Example 1: A product is labeled “ozone-friendly.” The claim...

ER-2 #809 and DC-8 in Arena Arctica hangar in Kiruna, Sweden prior to the SAGE III Ozone Loss and Va

NASA Technical Reports Server (NTRS)

2000-01-01

NASA ER-2 # 809 and its DC-8 shown in Arena Arctica before the SAGE III Ozone Loss and Validation Experiment (SOLVE). The two airborne science platforms were based north of the Arctic Circle in Kiruna, Sweden, during the winter of 2000 to study ozone depletion as part of SOLVE. A large hangar built especially for research, 'Arena Arctica' housed the instrumented aircraft and the scientists. Scientists have observed unusually low levels of ozone over the Arctic during recent winters, raising concerns that ozone depletion there could become more widespread as in the Antarctic ozone hole. The NASA-sponsored international mission took place between November 1999 and March 2000 and was divided into three phases. The DC-8 was involved in all three phases returning to Dryden between each phase. The ER-2 flew sample collection flights between January and March, remaining in Sweden from Jan. 9 through March 16. 'The collaborative campaign will provide an immense new body of information about the Arctic stratosphere,' said program scientist Dr. Michael Kurylo, NASA Headquarters. 'Our understanding of the Earth's ozone will be greatly enhanced by this research.' ER-2s bearing tail numbers 806 and 809 are used as airborne science platforms by NASA's Dryden Flight Research Center. The aircraft are platforms for a variety of high-altitude science missions flown over various parts of the world. They are also used for earth science and atmospheric sensor research and development, satellite calibration and data validation. The ER-2s are capable of carrying a maximum payload of 2,600 pounds of experiments in a nose bay, the main equipment bay behind the cockpit, two wing-mounted superpods and small underbody and trailing edges. Most ER-2 missions last about six hours with ranges of about 2,200 nautical miles. The aircraft typically fly at altitudes above 65,000 feet. On November 19, 1998, an ER-2 set a world record for medium weight aircraft reaching an altitude of 68,700 feet. The

Analysis of 1970-1995 Trends in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS-CHEM Model

NASA Technical Reports Server (NTRS)

Fusco, Andrew C.; Logan, Jennifer A.

2004-01-01

breakup of the ozone hole.

The Quasi-biennial Oscillation and Annual Variations in Tropical Ozone from SHADOZ and HALOE

NASA Technical Reports Server (NTRS)

Witte, J. C.; Schoeberl, M. R.; Douglass, A. R.; Thompson, A. M.

2008-01-01

We examine the tropical ozone mixing ratio perturbation fields generated from a monthly ozone climatology using 1998 to 2006 ozonesonde data from the Southern Hemisphere Additional Ozonesondes (SHADOZ) network and the 13-year satellite record from 1993 to 2005 obtained from the Halogen Occultation Experiment (HALOE). The long time series and high vertical resolution of the ozone and temperature profiles from the SHADOZ sondes coupled with good tropical coverage north and south of the equator gives a detailed picture of the ozone structure in the lowermost stratosphere down through the tropopause where the picture obtained from HALOE measurements is blurred by coarse vertical resolution. Ozone perturbations respond to annual variations in the Brewer-Dobson Circulation (BDC) in the region just above the cold-point tropopause to around 20 km. Annual cycles in ozone and temperature are well correlated. Above 20 km, ozone and temperature perturbations are dominated by the Quasi-biennial Oscillation (QBO). Both satellite and sonde records show good agreement between positive and negative ozone mixing ratio anomalies and alternating QBO westerly and easterly wind shears from the Singapore rawinsondes with a mean periodicity of 26 months for SHADOZ and 25 months for HALOE. There is a temporal offset of one to three months with the QBO wind shear ahead of the ozone anomaly field. The meridional length scales for the annual cycle and the QBO, obtained using the temperature anomalies and wind shears in the thermal wind equation, compare well with theoretical calculations.

An Estimation of the Climatic Effects of Stratospheric Ozone Losses during the 1980s. Appendix K

NASA Technical Reports Server (NTRS)

MacKay, Robert M.; Ko, Malcolm K. W.; Shia, Run-Lie; Yang, Yajaing; Zhou, Shuntai; Molnar, Gyula

1997-01-01

In order to study the potential climatic effects of the ozone hole more directly and to assess the validity of previous lower resolution model results, the latest high spatial resolution version of the Atmospheric and Environmental Research, Inc., seasonal radiative dynamical climate model is used to simulate the climatic effects of ozone changes relative to the other greenhouse gases. The steady-state climatic effect of a sustained decrease in lower stratospheric ozone, similar in magnitude to the observed 1979-90 decrease, is estimated by comparing three steady-state climate simulations: 1) 1979 greenhouse gas concentrations and 1979 ozone, II) 1990 greenhouse gas concentrations with 1979 ozone, and III) 1990 greenhouse gas concentrations with 1990 ozone. The simulated increase in surface air temperature resulting from nonozone greenhouse gases is 0.272 K. When changes in lower stratospheric ozone are included, the greenhouse warming is 0.165 K, which is approximately 39% lower than when ozone is fixed at the 1979 concentrations. Ozone perturbations at high latitudes result in a cooling of the surface-troposphere system that is greater (by a factor of 2.8) than that estimated from the change in radiative forcing resulting from ozone depiction and the model's 2 x CO, climate sensitivity. The results suggest that changes in meridional heat transport from low to high latitudes combined with the decrease in the infrared opacity of the lower stratosphere are very important in determining the steady-state response to high latitude ozone losses. The 39% compensation in greenhouse warming resulting from lower stratospheric ozone losses is also larger than the 28% compensation simulated previously by the lower resolution model. The higher resolution model is able to resolve the high latitude features of the assumed ozone perturbation, which are important in determining the overall climate sensitivity to these perturbations.

ER-2 #809 on the SAGE III Ozone Loss and Validation Experiment (SOLVE) with pilot Dee Porter prepari

NASA Technical Reports Server (NTRS)

2000-01-01

Lockheed Martin pilot Dee Porter climbs up the ladder wearing a heavy tan pressure suit, preparing to board NASA ER-2 #809 at Kiruna, Sweden, for the third flight in the SAGE III Ozone Loss and Validation Experiment. Assisting him is Jim Sokolik, a Lockheed Martin life support technician. Number 809, one of Dryden's two high-flying ER-2 Airborne Science aircraft, a civilian variant of Lockheed's U-2, and another NASA flying laboratory, Dryden's DC-8, were based north of the Arctic Circle in Kiruna, Sweden during the winter of 2000 to study ozone depletion as part of the SAGE III Ozone Loss and Validation Experiment (SOLVE). A large hangar built especially for research, 'Arena Arctica' housed the instrumented aircraft and the scientists. Scientists have observed unusually low levels of ozone over the Arctic during recent winters, raising concerns that ozone depletion there could become more widespread as in the Antarctic ozone hole. The NASA-sponsored international mission took place between November 1999 and March 2000 and was divided into three phases. The DC-8 was involved in all three phases returning to Dryden between each phase. The ER-2 flew sample collection flights between January and March, remaining in Sweden from Jan. 9 through March 16. 'The collaborative campaign will provide an immense new body of information about the Arctic stratosphere,' said program scientist Dr. Michael Kurylo, NASA Headquarters. 'Our understanding of the Earth's ozone will be greatly enhanced by this research.' ER-2s bearing tail numbers 806 and 809 are used as airborne science platforms by NASA's Dryden Flight Research Center. The aircraft are platforms for a variety of high-altitude science missions flown over various parts of the world. They are also used for earth science and atmospheric sensor research and development, satellite calibration and data validation. The ER-2s are capable of carrying a maximum payload of 2,600 pounds of experiments in a nose bay, the main

Interactive Ozone and Methane Chemistry in GISS-E2 Historical and Future Climate Simulations

NASA Technical Reports Server (NTRS)

Shindell, D. T.; Pechony, O.; Voulgarakis, A.; Faluvegi, G.; Nazarenko. L.; Lamarque, J.-F.; Bowman, K.; Milly, G.; Kovari, B.; Ruedy, R.;

2000 NAEP--1999, TIMSS Linking Report. Working Paper Series. NCES 2005-01

ERIC Educational Resources Information Center

Johnson, Eugene; Cohen, Jon; Chen, Wen-Hung; Jiang, Tao; Zhang, Yu

2005-01-01

This is the second study linking NAEP to TIMSS. The first study linked the 1996 NAEP to the 1995 TIMSS (Johnson, 1998). This study attempted to link the 2000 grade 8 NAEP in mathematics and science to the 1999 grade 8 TIMSS (which also assessed mathematics and science). The major purpose of both studies, assuming a successful link, was to allow…

Multiannual tropical tropospheric ozone columns and the case of the 2015 el Niño event

NASA Astrophysics Data System (ADS)

Leventidou, Elpida; Eichmann, Kai-Uwe; Weber, Mark; Burrows, John P.

2016-04-01

Stratospheric ozone is well known for protecting the surface from harmful ultraviolet solar radiation whereas ozone in the troposphere plays a more complex role. In the lower troposphere ozone can be extremely harmful for human health as it can oxidize biological tissues and causes respiratory problems. Several studies have shown that the tropospheric ozone burden (300±30Tg (IPCC, 2007)) increases by 1-7% per decade in the tropics (Beig and Singh, 2007; Cooper et al., 2014) which makes the need to monitor it on a global scale crucial. Remote sensing from satellites has been proven to be very useful in providing consistent information of tropospheric ozone concentrations over large areas. Tropical tropospheric ozone columns can be retrieved with the Convective Cloud Differential (CCD) technique (Ziemke et al. 1998) using retrieved total ozone columns and cloud parameters from space-borne observations. We have developed a CCD-IUP algorithm which was applied to GOME/ ERS-2 (1995-2003), SCIAMACHY/ Envisat (2002-2012), and GOME-2/ MetOpA (2007-2012) weighting function DOAS (Coldewey-Egbers et al., 2005, Weber et al., 2005) total ozone data. A unique long-term record of monthly averaged tropical tropospheric ozone columns (20°S - 20°N) was created starting in 1996. This dataset has been extensively validated by comparisons with SHADOZ (Thompson et al., 2003) ozonesonde data and limb-nadir Matching (Ebojie et al. 2014) tropospheric ozone data. The comparison shows good agreement with respect to range, inter-annual variation, and variance. Biases where found to be within 5DU and the RMS errors less than 10 DU. This 17-years dataset has been harmonized into one consistent time series, taking into account the three instruments' difference in ground pixel size. The harmonised dataset is used to determine tropical tropospheric ozone trends and climatological values. The 2015 el Niño event has been characterised as one of the top three strongest el Niños since 1950. El Ni

Spatiotemporal trends in ground-level ozone concentrations and metrics in France over the time period 1999-2012.

PubMed

Sicard, Pierre; Serra, Romain; Rossello, Philippe

2016-08-01

The hourly ozone (O3) data from 332 background monitoring stations, spread in France, were analyzed over the period 1999-2012 and short-term trends were calculated. In the current climate change context, the calculation of human health- and vegetation-relevant metrics, and of associated trends, provides a consistent method to establish proper and effective policies to reduce the adverse O3 effects. The generation of optimal O3 maps, for risk and exposure assessment, is challenging. To overcome this issue, starting from a set of stations, a hybrid regression-interpolation approach was proposed. Annual surface O3 metrics, O3 human health metrics (number of exceedances of daily maximum 8-h values greater than 60 ppb and SOMO35) and O3 vegetation impact metrics (AOT40 for vegetation and forests) were investigated at individual sites. Citizens are more exposed to high O3 levels in rural areas than people living in the cities. The annual mean concentrations decreased by -0.12ppbyear(-1) at rural stations, and the significant reduction at 67% of stations, particularly during the warm season, in the number of episodic high O3 concentrations (e.g. 98th percentile, -0.19ppbyear(-1)) can be associated with the substantial reductions in NOx and VOCs emissions in the EU-28 countries since the early 1990s Inversely, the O3 background level is rising at 76% of urban sites (+0.14ppbyear(-1)), particularly during the cold period. This rise can be attributed to increases in imported O3 by long-range transport and to a low O3 titration by NO due to the reduction in local NOx emissions. The decrease in health-related and vegetation-relevant O3 metrics, at almost all stations, is driven by decreases in regional photochemical O3 formation and in peak O3 concentrations. The short-term trends highlight that the threat to population and vegetation declined between 1999 and 2012 in France, demonstrating the success of European control strategies over the last 20 years. However, for all

Design of a vehicle based system to prevent ozone loss

NASA Technical Reports Server (NTRS)

Lynn, Sean R.; Bunker, Deborah; Hesbach, Thomas D., Jr.; Howerton, Everett B.; Hreinsson, G.; Mistr, E. Kirk; Palmer, Matthew E.; Rogers, Claiborne; Tischler, Dayna S.; Wrona, Daniel J.

1993-01-01

Reduced quantities of ozone in the atmosphere allow greater levels of ultraviolet light (UV) radiation to reach the earth's surface. This is known to cause skin cancer and mutations. Chlorine liberated from Chlorofluorocarbons (CFC's) and natural sources initiate the destruction of stratospheric ozone through a free radical chain reaction. The project goals are to understand the processes which contribute to stratospheric ozone loss, examine ways to prevent ozone loss, and design a vehicle-based system to carry out the prevention scheme. The 1992/1993 design objectives were to accomplish the first two goals and define the requirements for an implementation vehicle to be designed in detail starting next year. Many different ozone intervention schemes have been proposed though few have been researched and none have been tested. A scheme proposed by R.J. Cicerone, Scott Elliot and R.P.Turco late in 1991 was selected because of its research support and economic feasibility. This scheme uses hydrocarbon injected into the Antarctic ozone hole to form stable compounds with free chlorine, thus reducing ozone depletion. Because most polar ozone depletion takes place during a 3-4 week period each year, the hydrocarbon must be injected during this time window. A study of the hydrocarbon injection requirements determined that 100 aircraft traveling Mach 2.4 at a maximum altitude of 66,000 ft. would provide the most economic approach to preventing ozone loss. Each aircraft would require an 8,000 nm. range and be able to carry 35,000 lbs. of propane. The propane would be stored in a three-tank high pressure system. Missions would be based from airport regions located in South America and Australia. To best provide the requirements of mission analysis, an aircraft with L/D(sub cruise) = 10.5, SFC = 0.65 (the faculty advisor suggested that this number is too low) and a 250,000 lb TOGW was selected as a baseline. Modularity and multi-role functionality were selected to be key

Tropospheric Ozone and Photochemical Smog

NASA Astrophysics Data System (ADS)

Sillman, S.

2003-12-01

emitted species, in a process that is driven by sunlight and is accelerated by warm temperatures. This smog is largely the product of gasoline-powered engines (especially automobiles), although coal-fired industry can also generate photochemical smog. The process of photochemical smog formation was first identified by Haagen-Smit and Fox (1954) in association with Los Angeles, a city whose geography makes it particularly susceptible to this type of smog formation. Sulfate aerosols and organic particulates are often produced concurrently with ozone, giving rise to a characteristic milky-white haze associated with this type of air pollution.Today ozone and particulates are recognized as the air pollutants that are most likely to affect human health adversely. In the United States, most major metropolitan areas have periodic air pollution events with ozone in excess of government health standards. Violations of local health standards also occur in major cities in Canada and in much of Europe. Other cities around the world (especially Mexico City) also experience very high ozone levels. In addition to urban-scale events, elevated ozone occurs in region-wide events in the eastern USA and in Western Europe, with excess ozone extending over areas of 1,000 km2 or more. Ozone plumes of similar extent are found in the tropics (especially in Central Africa) at times of high biomass burning (e.g., Jenkins et al., 1997; Chatfield et al., 1998). In some cases ozone associated with biomass burning has been identified at distances up to 104 km from its sources (Schultz et al., 1999).Ozone also has a significant impact on the global troposphere, and ozone chemistry is a major component of global tropospheric chemistry. Global background ozone concentrations are much lower than urban or regional concentrations during pollution events, but there is evidence that the global background has increased as a result of human activities (e.g., Wang and Jacob, 1998; Volz and Kley, 1988). A rise in

The impact of speciated VOCs on regional ozone increment derived from measurements at the UK EMEP supersites between 1999 and 2012

NASA Astrophysics Data System (ADS)

Malley, C. S.; Braban, C. F.; Dumitrean, P.; Cape, J. N.; Heal, M. R.

2015-03-01

The impact of 27 volatile organic compounds (VOC) on the regional O3 increment was investigated using measurements made at the UK EMEP supersites Harwell (1999-2001 and 2010-2012) and Auchencorth (2012). Ozone at these sites is representative of rural O3 in south-east England and northern UK, respectively. Monthly-diurnal regional O3 increment was defined as the difference between the regional and hemispheric background O3 concentrations, respectively derived from oxidant vs. NOx correlation plots, and cluster analysis of back trajectories arriving at Mace Head, Ireland. At Harwell, which had substantially greater regional ozone increments than at Auchencorth, variation in the regional O3 increment mirrored afternoon depletion of VOCs due to photochemistry (after accounting for diurnal changes in boundary layer mixing depth, and weighting VOC concentrations according to their photochemical ozone creation potential). A positive regional O3 increment occurred consistently during the summer, during which time afternoon photochemical depletion was calculated for the majority of measured VOCs, and to the greatest extent for ethene and m + p-xylene. This indicates that, of the measured VOCs, ethene and m + p-xylene emissions reduction would be most effective in reducing the regional O3 increment, but that reductions in a larger number of VOCs would be required for further improvement. The VOC diurnal photochemical depletion was linked to the sources of the VOC emissions through the integration of gridded VOC emissions estimates over 96 h air-mass back trajectories. This demonstrated that the effectiveness of VOC gridded emissions for use in measurement and modelling studies is limited by the highly aggregated nature of the 11 SNAP source sectors in which they are reported, as monthly variation in speciated VOC trajectory emissions did not reflect monthly changes in individual VOC diurnal photochemical depletion. Additionally, the major VOC emission source sectors during

Forecast, measurement, and modeling of an unprecedented polar ozone filament event over Mauna Loa Observatory, Hawaii

NASA Astrophysics Data System (ADS)

Tripathi, Om Prakash; Leblanc, Thierry; McDermid, I. Stuart; LefèVre, Frank; Marchand, Marion; Hauchecorne, Alain

2006-10-01

In mid-March 2005 the northern lower stratospheric polar vortex experienced a severe stretching episode, bringing a large polar filament far south of Alaska toward Hawaii. This meridional intrusion of rare extent, coinciding with the polar vortex final warming and breakdown, was followed by a zonal stretching in the wake of the easterly propagating subtropical main flow. This caused polar air to remain over Hawaii for several days before diluting into the subtropics. After being successfully forecasted to pass over Hawaii by the high-resolution potential vorticity advection model Modèle Isentrope du transport Méso-échelle de l'Ozone Stratosphérique par Advection (MIMOSA), the filament was observed on isentropic surfaces between 415 K and 455 K (17-20 km) by the Jet Propulsion Laboratory stratospheric ozone lidar measurements at Mauna Loa Observatory, Hawaii, between 16 and 19 March 2005. It was materialized as a thin layer of enhanced ozone peaking at 1.6 ppmv in a region where the climatological values usually average 1.0 ppmv. These values were compared to those obtained by the three-dimensional Chemistry-Transport Model MIMOSA-CHIM. Agreement between lidar and model was excellent, particularly in the similar appearance of the ozone peak near 435 K (18.5 km) on 16 March, and the persistence of this layer at higher isentropic levels for the following three days. Passive ozone, also modeled by MIMOSA-CHIM, was at about 3-4 ppmv inside the filament while above Hawaii. A detailed history of the modeled chemistry inside the filament suggests that the air mass was still polar ozone-depleted when passing over Hawaii. The filament quickly separated from the main vortex after its Hawaiian overpass. It never reconnected and, in less than 10 days, dispersed entirely in the subtropics.

Forecast, Measurement, and Modeling of an Unprecedented Polar Ozone Filament Event over Mauna Loa Observatory, Hawaii

NASA Technical Reports Server (NTRS)

Tripathi, Om Prakash; Leblanc, Thierry; McDermid, I. Stuart; Lefevre, Frank; Marchand, Marion; Hauchecorne, Alain

2006-01-01

In mid-March 2005 the northern lower stratospheric polar vortex experienced a severe stretching episode, bringing a large polar filament far south of Alaska toward Hawaii. This meridional intrusion of rare extent, coinciding with the polar vortex final warming and breakdown, was followed by a zonal stretching in the wake of the easterly propagating subtropical main flow. This caused polar air to remain over Hawaii for several days before diluting into the subtropics. After being successfully forecasted to pass over Hawaii by the high-resolution potential vorticity advection model Modele Isentrope du transport Meso-echelle de l'Ozone Stratospherique par Advection (MIMOSA), the filament was observed on isentropic surfaces between 415 K and 455 K (17-20 km) by the Jet Propulsion Laboratory stratospheric ozone lidar measurements at Mauna Loa Observatory, Hawaii, between 16 and 19 March 2005. It was materialized as a thin layer of enhanced ozone peaking at 1.6 ppmv in a region where the climatological values usually average 1.0 ppmv. These values were compared to those obtained by the three dimensional Chemistry-Transport Model MIMOSA-CHIM. Agreement between lidar and model was excellent, particularly in the similar appearance of the ozone peak near 435 K (18.5 km) on 16 March, and the persistence of this layer at higher isentropic levels for the following three days. Passive ozone, also modeled by MIMOSA-CHIM, was at about 3-4 ppmv inside the filament while above Hawaii. A detailed history of the modeled chemistry inside the filament suggests that the air mass was still polar ozone- depleted when passing over Hawaii. The filament quickly separated from the main vortex after its Hawaiian overpass. It never reconnected and, in less than 10 days, dispersed entirely in the subtropics.

Tropospheric ozone (TOR) trend over three major inland Indian cities: Delhi, Hyderabad and Bangalore

NASA Astrophysics Data System (ADS)

Kulkarni, Pavan S.; Ghude, Sachin D.; Bortoli, D.

2010-10-01

An analysis of tropospheric column ozone using the NASA Langley TOR data during 1979-2005 has been done to investigate the trend over major Indian cities Delhi, Hyderabad and Bangalore. India was under social democratic-based policies before 1990s. Economic Liberalization began in nineties which lead to a significant growth in industrial, energy and transport sectors in major cities. Our analysis shows that there is a systematic increase in the number of months with higher tropospheric ozone values after 1990. A comparison of TOR climatology before and after 1990 over these cities shows evidence of increase in the tropospheric ozone after 1990. Trend obtained from the model shows significant change during monsoon over Delhi and during pre-monsoon and post-monsoon over Hyderabad and Bangalore. The present analysis using TOR technique demonstrates the TOR potential to detect changes in tropospheric ozone over large cities which are impacted by large anthropogenic pollution.

Ultraviolet-ozone surface modification for non-wetting hole transport materials based inverted planar perovskite solar cells with efficiency exceeding 18%

NASA Astrophysics Data System (ADS)

Xu, Xiuwen; Ma, Chunqing; Cheng, Yuanhang; Xie, Yue-Min; Yi, Xueping; Gautam, Bhoj; Chen, Shengmei; Li, Ho-Wa; Lee, Chun-Sing; So, Franky; Tsang, Sai-Wing

2017-08-01

Non-wetting hole transport materials (HTMs) have great potential in facilitating large-sized perovskite crystal growth and enhancing device stability by opposing moisture ingress, However, the severe non-wetting issue limits the wide application of these materials in low-temperature solution-processed inverted planar perovskite solar cells (PVSCs), and corresponding devices are rarely reported. Here, a facile ultraviolet-ozone (UVO) modification method is demonstrated to overcome this issue. By carefully controlling the UVO modification time, the surface wettability of poly-TPD can be tuned without affecting the bulk properties of the film, hence perovskite films with desired grain size and excellent coverage can be deposited via a one-step spin-coating method. Benefiting from the high-quality perovskite, well-matched energy level alignment and hydrophobic property of poly-TPD, the resulting PVSCs show a champion power conversion efficiency of 18.19% with significantly enhanced stability as compared to the PEDOT:PSS counterparts. Moreover, the UVO modification approach also demonstrates its validity when being extended to other hydrophobic HTMs. This work not only provides a general strategy to broaden the selection pool of HTMs for solution-processed inverted planar PVSCs, but also may triggers the exploration of more advanced strategies to make non-wetting HTMs applicable in solution-processed inverted planar PVSCs.

Ozone Layer Protection

MedlinePlus

... Offices Labs and Research Centers Contact Us Share Ozone Layer Protection The stratospheric ozone layer is Earth’s “ ... to ozone-depleting substances, and sun safety. Stratospheric Ozone Layer Basic Ozone Layer Science Health and Environmental ...

27 Years of Satellite Ozone Data: Merging of Data Records from Multiple Instruments to Observe Global Trends and Recovery

NASA Technical Reports Server (NTRS)

Stolarski, Richard S.

2007-01-01

Satellite measurements provide a unique global view of the stratospheric ozone layer. The perspective from satellites allowed for the early mapping of the extent of the phenomenon that became known as the ozone hole. The use of the satellite data for global trends outside of the ozone hole confronts the problem of the possible drift of the calibration of the instrument. The TOMS and SBUV instruments on Nimbus 7 lasted for more than a decade. During that time, the diffuser plate used to reflect sunlight into the measurement degraded (darkened) and the instruments each had a number of events that made calibration determination difficult. Initially the TOMS data were used for global trends by adjusting the overall calibration to agree with a set of ground-based measurement stations. But this was unsatisfactory because the record was not independent of those ground measurements and problems were found in many of the ground stations by using TOMS as a transfer standard. After many years of dedicated work, the TOMS/SBUV team learned how to correct for instrument drift, remove the interfering effects of aerosols, and establish instrument-to-instrument calibrations resulting in a long-term record that can be used for accurate trend and recovery determination. The global view of the satellites allows for determination not only of temporal change in ozone, but spatial fingerprints that allow more confidence in assigning cause to observed changes.

Health benefits from large-scale ozone reduction in the United States.

PubMed

Berman, Jesse D; Fann, Neal; Hollingsworth, John W; Pinkerton, Kent E; Rom, William N; Szema, Anthony M; Breysse, Patrick N; White, Ronald H; Curriero, Frank C

2012-10-01

Exposure to ozone has been associated with adverse health effects, including premature mortality and cardiopulmonary and respiratory morbidity. In 2008, the U.S. Environmental Protection Agency (EPA) lowered the primary (health-based) National Ambient Air Quality Standard (NAAQS) for ozone to 75 ppb, expressed as the fourth-highest daily maximum 8-hr average over a 24-hr period. Based on recent monitoring data, U.S. ozone levels still exceed this standard in numerous locations, resulting in avoidable adverse health consequences. We sought to quantify the potential human health benefits from achieving the current primary NAAQS standard of 75 ppb and two alternative standard levels, 70 and 60 ppb, which represent the range recommended by the U.S. EPA Clean Air Scientific Advisory Committee (CASAC). We applied health impact assessment methodology to estimate numbers of deaths and other adverse health outcomes that would have been avoided during 2005, 2006, and 2007 if the current (or lower) NAAQS ozone standards had been met. Estimated reductions in ozone concentrations were interpolated according to geographic area and year, and concentration-response functions were obtained or derived from the epidemiological literature. We estimated that annual numbers of avoided ozone-related premature deaths would have ranged from 1,410 to 2,480 at 75 ppb to 2,450 to 4,130 at 70 ppb, and 5,210 to 7,990 at 60 ppb. Acute respiratory symptoms would have been reduced by 3 million cases and school-loss days by 1 million cases annually if the current 75-ppb standard had been attained. Substantially greater health benefits would have resulted if the CASAC-recommended range of standards (70-60 ppb) had been met. Attaining a more stringent primary ozone standard would significantly reduce ozone-related premature mortality and morbidity.

Health Benefits from Large-Scale Ozone Reduction in the United States

PubMed Central

Berman, Jesse D.; Fann, Neal; Hollingsworth, John W.; Pinkerton, Kent E.; Rom, William N.; Szema, Anthony M.; Breysse, Patrick N.; White, Ronald H.

2012-01-01

Background: Exposure to ozone has been associated with adverse health effects, including premature mortality and cardiopulmonary and respiratory morbidity. In 2008, the U.S. Environmental Protection Agency (EPA) lowered the primary (health-based) National Ambient Air Quality Standard (NAAQS) for ozone to 75 ppb, expressed as the fourth-highest daily maximum 8-hr average over a 24-hr period. Based on recent monitoring data, U.S. ozone levels still exceed this standard in numerous locations, resulting in avoidable adverse health consequences. Objectives: We sought to quantify the potential human health benefits from achieving the current primary NAAQS standard of 75 ppb and two alternative standard levels, 70 and 60 ppb, which represent the range recommended by the U.S. EPA Clean Air Scientific Advisory Committee (CASAC). Methods: We applied health impact assessment methodology to estimate numbers of deaths and other adverse health outcomes that would have been avoided during 2005, 2006, and 2007 if the current (or lower) NAAQS ozone standards had been met. Estimated reductions in ozone concentrations were interpolated according to geographic area and year, and concentration–response functions were obtained or derived from the epidemiological literature. Results: We estimated that annual numbers of avoided ozone-related premature deaths would have ranged from 1,410 to 2,480 at 75 ppb to 2,450 to 4,130 at 70 ppb, and 5,210 to 7,990 at 60 ppb. Acute respiratory symptoms would have been reduced by 3 million cases and school-loss days by 1 million cases annually if the current 75-ppb standard had been attained. Substantially greater health benefits would have resulted if the CASAC-recommended range of standards (70–60 ppb) had been met. Conclusions: Attaining a more stringent primary ozone standard would significantly reduce ozone-related premature mortality and morbidity. PMID:22809899

The impact of climate change on ozone-related mortality in Sydney.

PubMed

Physick, William; Cope, Martin; Lee, Sunhee

2014-01-13

Coupled global, regional and chemical transport models are now being used with relative-risk functions to determine the impact of climate change on human health. Studies have been carried out for global and regional scales, and in our paper we examine the impact of climate change on ozone-related mortality at the local scale across an urban metropolis (Sydney, Australia). Using three coupled models, with a grid spacing of 3 km for the chemical transport model (CTM), and a mortality relative risk function of 1.0006 per 1 ppb increase in daily maximum 1-hour ozone concentration, we evaluated the change in ozone concentrations and mortality between decades 1996-2005 and 2051-2060. The global model was run with the A2 emissions scenario. As there is currently uncertainty regarding a threshold concentration below which ozone does not impact on mortality, we calculated mortality estimates for the three daily maximum 1-hr ozone concentration thresholds of 0, 25 and 40 ppb. The mortality increase for 2051-2060 ranges from 2.3% for a 0 ppb threshold to 27.3% for a 40 ppb threshold, although the numerical increases differ little. Our modeling approach is able to identify the variation in ozone-related mortality changes at a suburban scale, estimating that climate change could lead to an additional 55 to 65 deaths across Sydney in the decade 2051-2060. Interestingly, the largest increases do not correspond spatially to the largest ozone increases or the densest population centres. The distribution pattern of changes does not seem to vary with threshold value, while the magnitude only varies slightly.

The Impact of Climate Change on Ozone-Related Mortality in Sydney

PubMed Central

Physick, William; Cope, Martin; Lee, Sunhee

2014-01-01

Coupled global, regional and chemical transport models are now being used with relative-risk functions to determine the impact of climate change on human health. Studies have been carried out for global and regional scales, and in our paper we examine the impact of climate change on ozone-related mortality at the local scale across an urban metropolis (Sydney, Australia). Using three coupled models, with a grid spacing of 3 km for the chemical transport model (CTM), and a mortality relative risk function of 1.0006 per 1 ppb increase in daily maximum 1-hour ozone concentration, we evaluated the change in ozone concentrations and mortality between decades 1996–2005 and 2051–2060. The global model was run with the A2 emissions scenario. As there is currently uncertainty regarding a threshold concentration below which ozone does not impact on mortality, we calculated mortality estimates for the three daily maximum 1-hr ozone concentration thresholds of 0, 25 and 40 ppb. The mortality increase for 2051–2060 ranges from 2.3% for a 0 ppb threshold to 27.3% for a 40 ppb threshold, although the numerical increases differ little. Our modeling approach is able to identify the variation in ozone-related mortality changes at a suburban scale, estimating that climate change could lead to an additional 55 to 65 deaths across Sydney in the decade 2051–2060. Interestingly, the largest increases do not correspond spatially to the largest ozone increases or the densest population centres. The distribution pattern of changes does not seem to vary with threshold value, while the magnitude only varies slightly. PMID:24419047

Antarctic ozone loss in 1989-2010: evidence for ozone recovery?

NASA Astrophysics Data System (ADS)

Kuttippurath, J.; Lefèvre, F.; Pommereau, J.-P.; Roscoe, H. K.; Goutail, F.; Pazmiño, A.; Shanklin, J. D.

2012-04-01

We present a detailed estimation of chemical ozone loss in the Antarctic polar vortex from 1989 to 2010. The analyses include ozone loss estimates for 12 Antarctic ground-based (GB) stations. All GB observations show minimum ozone in the late September-early October period. Among the stations, the lowest minimum ozone values are observed at South Pole and the highest at Dumont d'Urville. The ozone loss starts by mid-June at the vortex edge and then progresses towards the vortex core with time. The loss intensifies in August-September, peaks by the end of September-early October, and recovers thereafter. The average ozone loss in the Antarctic is revealed to be about 33-50% in 1989-1992 in agreement with the increase in halogens during this period, and then stayed at around 48% due to saturation of the loss. The ozone loss in the warmer winters (e.g. 2002, and 2004) is lower (37-46%) and in the colder winters (e.g. 2003, and 2006) is higher (52-55%). Because of small inter-annual variability, the correlation between ozone loss and the volume of polar stratospheric clouds yields ~0.51. The GB ozone and ozone loss values are in good agreement with those found from the space-based observations of the Total Ozone Mapping Spectrometer/Ozone Monitoring Instrument (TOMS/OMI), the Global Ozone Monitoring Experiment (GOME), the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY), and the Aura Microwave Limb Sounder (MLS), where the differences are within ±5% and are mostly within the error bars of the measurements. The piece-wise linear trends computed from the September-November vortex average GB and TOMS/OMI ozone show about -4 to -5.6 DU (Dobson Unit) yr-1 in 1989-1996 and about +1 DU yr-1 in 1997-2010. The trend during the former period is significant at 95% confidence intervals, but the trend in 1997-2010 is significant only at 85% confidence intervals. Our analyses suggest a period of about 9-10 yr to get the first detectable ozone

Treatment of soft drink process wastewater by ozonation, ozonation-H₂O₂ and ozonation-coagulation processes.

PubMed

García-Morales, M A; Roa-Morales, G; Barrera-Díaz, C; Balderas-Hernández, P

2012-01-01

In this research, we studied the treatment of wastewater from the soft drink process using oxidation with ozone. A scheme composed of sequential ozonation-peroxide, ozonation-coagulation and coagulation-ozonation treatments to reduce the organic matter from the soft drink process was also used. The samples were taken from the conventional activated sludge treatment of the soft drink process, and the experiments using chemical oxidation with ozone were performed in a laboratory using a reactor through a porous plate glass diffuser with air as a feedstock for the generation of ozone. Once the sample was ozonated, the treatments were evaluated by considering the contact time, leading to greater efficiency in removing colour, turbidity and chemical oxygen demand (COD). The effect of ozonation and coagulant coupled with treatment efficiency was assessed under optimal conditions, and substantial colour and turbidity removal were found (90.52% and 93.33%, respectively). This was accompanied by a 16.78% reduction in COD (initial COD was 3410 mg/L). The absorbance spectra of the oxidised products were compared using UV-VIS spectroscopy to indicate the level of oxidation of the wastewater. We also determined the kinetics of decolouration and the removal of turbidity with the best treatment. The same treatment was applied to the sample taken from the final effluent of the activated sludge system, and a COD removal efficiency of 100% during the first minute of the reaction with ozone was achieved. As a general conclusion, we believe that the coagulant polyaluminum chloride - ozone (PAC- ozone) treatment of wastewater from the manufacturing of soft drinks is the most efficient for removing turbidity and colour and represents an advantageous option to remove these contaminants because their removal was performed in minutes compared to the duration of traditional physical, chemical and biological processes that require hours or days.

Impact Assessment of Global Temperature Perturbations on Urban and Regional Ozone Levels in South Texas

NASA Astrophysics Data System (ADS)

Biswas, Jhumoor; John, Kuruvilla; Farooqui, Zuber

The recent Intergovernmental Panel on Climate Change report predicts significant temperature increases over the century which constitutes the pulse of climate variability in a region. A modeling study was performed to identify the potential impact of temperature perturbations on tropospheric ozone concentrations in South Texas. A future case modeling scenario which incorporates appropriate emission reduction strategies without accounting for climatic inconsistencies was used in this study. The photochemical modeling was undertaken for a high ozone episode of 13-20 September 1999, and a future modeling scenario was projected for ozone episode days in 2007 utilizing the meteorological conditions prevalent in the base year. The temperatures were increased uniformly throughout the simulation domain and through the vertical layers by 2°C, 3°C, 4°C, 5°C, and 6°C, respectively in the future year modeling case. These temperature perturbations represented the outcome of extreme climate change within the study region. Significantly large changes in peak ozone concentrations were predicted by the photochemical model. For the 6°C temperature perturbation, the greatest amplification in the maximum 8-h ozone concentrations within urban areas of the modeling domain was approximately 12 ppb. In addition, transboundary flux from major industrialized urban areas played a major role in supplementing the high ozone concentrations during the perturbed temperature scenarios. The Unites States Environmental Protection Agency (USEPA) is currently proposing stricter 8-h ozone standards. The effect of temperature perturbations on ozone exceedances based on current and potential stringent future National Ambient Air Quality Standards (NAAQS) was also studied. Temperatures had an appreciable spatial impact on the 8-h ozone exceedances with a considerable increase in spatial area exceeding the NAAQS for the 8-h ozone levels within the study region for each successive augmentation in

Chemical and Dynamical Impacts of Stratospheric Sudden Warmings on Arctic Ozone Variability

NASA Technical Reports Server (NTRS)

Strahan, S. E.; Douglass, A. R.; Steenrod, S. D.

2016-01-01

We use the Global Modeling Initiative (GMI) chemistry and transport model with Modern-Era Retrospective Analysis for Research and Applications (MERRA) meteorological fields to quantify heterogeneous chemical ozone loss in Arctic winters 2005-2015. Comparisons to Aura Microwave Limb Sounder N2O and O3 observations show the GMI simulation credibly represents the transport processes and net heterogeneous chemical loss necessary to simulate Arctic ozone. We find that the maximum seasonal ozone depletion varies linearly with the number of cold days and with wave driving (eddy heat flux) calculated from MERRA fields. We use this relationship and MERRA temperatures to estimate seasonal ozone loss from 1993 to 2004 when inorganic chlorine levels were in the same range as during the Aura period. Using these loss estimates and the observed March mean 63-90N column O3, we quantify the sensitivity of the ozone dynamical resupply to wave driving, separating it from the sensitivity of ozone depletion to wave driving. The results show that about 2/3 of the deviation of the observed March Arctic O3 from an assumed climatological mean is due to variations in O3 resupply and 13 is due to depletion. Winters with a stratospheric sudden warming (SSW) before mid-February have about 1/3 the depletion of winters without one and export less depletion to the midlatitudes. However, a larger effect on the spring midlatitude ozone comes from dynamical differences between warm and cold Arctic winters, which can mask or add to the impact of exported depletion.

A Statistical Modeling Framework for Projecting Future Ambient Ozone and its Health Impact due to Climate Change

PubMed Central

Chang, Howard H.; Hao, Hua; Sarnat, Stefanie Ebelt

2014-01-01

The adverse health effects of ambient ozone are well established. Given the high sensitivity of ambient ozone concentrations to meteorological conditions, the impacts of future climate change on ozone concentrations and its associated health effects are of concern. We describe a statistical modeling framework for projecting future ozone levels and its health impacts under a changing climate. This is motivated by the continual effort to evaluate projection uncertainties to inform public health risk assessment. The proposed approach was applied to the 20-county Atlanta metropolitan area using regional climate model (RCM) simulations from the North American Regional Climate Change Assessment Program. Future ozone levels and ozone-related excesses in asthma emergency department (ED) visits were examined for the period 2041–2070. The computationally efficient approach allowed us to consider 8 sets of climate model outputs based on different combinations of 4 RCMs and 4 general circulation models. Compared to the historical period of 1999–2004, we found consistent projections across climate models of an average 11.5% higher ozone levels (range: 4.8%, 16.2%), and an average 8.3% (range: −7% to 24%) higher number of ozone exceedance days. Assuming no change in the at-risk population, this corresponds to excess ozone-related ED visits ranging from 267 to 466 visits per year. Health impact projection uncertainty was driven predominantly by uncertainty in the health effect association and climate model variability. Calibrating climate simulations with historical observations reduced differences in projections across climate models. PMID:24764746

Decadal Trends and Variability of Tropospheric Ozone over Oil and Gas Regions over 2005 - 2015

NASA Astrophysics Data System (ADS)

Zhou, Y.; Mao, H.; Sive, B. C.

2017-12-01

Tropospheric ozone (O3), which is produced largely by photochemical oxidation of nitrogen oxides (NOx) and volatile organic compounds, is a serious and ubiquitous air pollutant with strong negative health effects. Recent technological innovations such as horizontal drilling and hydraulic fracturing have accelerated oil and natural gas production in the U.S. since 2005. The additional input of O3 precursors from expanding natural gas production might prolong the effort to comply the current O3 standard (70 ppbv). The objective of this study is to investigate the impact of oil and gas extractions on variability and long term trends of O3 in the intermountain west under varying meteorological conditions. We investigated long-term O3 trends at 13 rural sites, which were within 100 km of the shale play in the U.S. intermountain west. Significant decreasing trends (-0.35 - -3.38 ppbv yr-1) were found in seasonal O3 design values at six sites in spring, summer, or fall, while no trends were found in wintertime O3 at any sites. Wintertime O3 at each site showed strong and consistent interannual variation over 2006 - 2015, and was negatively correlated with the Arctic Oscillation (AO) Index. The negative correlation was a result of multiple factors, such as in situ O3 photochemical production, stratospheric intrusion, and transport from the Arctic and California. In summer, wildfire emissions were the dominate driver to the interannual variations of high percentiles O3 at each site, while meteorological conditions (i.e., temperature and relative humidity) determined the interannual variations of low percentiles O3. Box model simulations indicated that O3 production rates were 31.51 ppbv h-1 over winters of 2012 - 2014 and 32.12 ppbv h-1 in summer 2014 around shale gas extraction regions.

Ozone decomposition

PubMed Central

Batakliev, Todor; Georgiev, Vladimir; Anachkov, Metody; Rakovsky, Slavcho

2014-01-01

Catalytic ozone decomposition is of great significance because ozone is a toxic substance commonly found or generated in human environments (aircraft cabins, offices with photocopiers, laser printers, sterilizers). Considerable work has been done on ozone decomposition reported in the literature. This review provides a comprehensive summary of the literature, concentrating on analysis of the physico-chemical properties, synthesis and catalytic decomposition of ozone. This is supplemented by a review on kinetics and catalyst characterization which ties together the previously reported results. Noble metals and oxides of transition metals have been found to be the most active substances for ozone decomposition. The high price of precious metals stimulated the use of metal oxide catalysts and particularly the catalysts based on manganese oxide. It has been determined that the kinetics of ozone decomposition is of first order importance. A mechanism of the reaction of catalytic ozone decomposition is discussed, based on detailed spectroscopic investigations of the catalytic surface, showing the existence of peroxide and superoxide surface intermediates. PMID:26109880

NASA Observatory Confirms Black Hole Limits

NASA Astrophysics Data System (ADS)

2005-02-01

The very largest black holes reach a certain point and then grow no more, according to the best survey to date of black holes made with NASA's Chandra X-ray Observatory. Scientists have also discovered many previously hidden black holes that are well below their weight limit. These new results corroborate recent theoretical work about how black holes and galaxies grow. The biggest black holes, those with at least 100 million times the mass of the Sun, ate voraciously during the early Universe. Nearly all of them ran out of 'food' billions of years ago and went onto a forced starvation diet. Focus on Black Holes in the Chandra Deep Field North Focus on Black Holes in the Chandra Deep Field North On the other hand, black holes between about 10 and 100 million solar masses followed a more controlled eating plan. Because they took smaller portions of their meals of gas and dust, they continue growing today. "Our data show that some supermassive black holes seem to binge, while others prefer to graze", said Amy Barger of the University of Wisconsin in Madison and the University of Hawaii, lead author of the paper describing the results in the latest issue of The Astronomical Journal (Feb 2005). "We now understand better than ever before how supermassive black holes grow." One revelation is that there is a strong connection between the growth of black holes and the birth of stars. Previously, astronomers had done careful studies of the birthrate of stars in galaxies, but didn't know as much about the black holes at their centers. DSS Optical Image of Lockman Hole DSS Optical Image of Lockman Hole "These galaxies lose material into their central black holes at the same time that they make their stars," said Barger. "So whatever mechanism governs star formation in galaxies also governs black hole growth." Astronomers have made an accurate census of both the biggest, active black holes in the distance, and the relatively smaller, calmer ones closer by. Now, for the first

The contribution of atmospheric proxies to the vertical distribution of ozone over Summit Station, Greenland

NASA Astrophysics Data System (ADS)

Bahramvash Shams, S.; Walden, V. P.; Oltmans, S. J.; Petropavlovskikh, I. V.; Kivi, R.; Thölix, L.

2017-12-01

The current trend and future concentrations of atmospheric ozone are active areas of research as the effect of the Montreal Protocol is realized. The trend of ozone is due to various chemical and dynamical parameters that create, destroy, and transport atmospheric ozone. These important parameters can be represented by different proxies, but their effects on ozone concentration are not completely understood. Previous studies show that proxies related to ozone have different contributions depending on latitude and altitude. In this study, we use vertical profiles of ozone derived from ozonesondes launched by the NOAA Global Monitoring Division at Summit Station, Greenland from 2005 to 2016. The effects of different proxies on ozone are investigated. Summit Station is located at 3,200 meters above sea level on the Greenland Ice Sheet and is a unique place in the Arctic. We use a stepwise multiple regression (MLR) technique to remove the seasonal cycle of ozone and investigate how the different proxies [solar flux (SF), the Quasi-Biennial Oscillation (QBO), the El Nino-Southern Oscillation index (ENSO), the Arctic Oscillation (AO), eddy heat flux (EHF), the volume of polar stratospheric clouds (VPSC), equivalent latitude (EL), and the tropopause pressure (TP)] affect the vertical distribution of ozone over Summit. The MLR is applied separately to total column ozone (TCO) as well as partial ozone columns (PCO) in the troposphere and the lower, middle, and upper stratosphere. Our results show that dynamical processes are important contributors to ozone concentrations over Summit Station. Tropospheric pressure and the QBO are effective predictors of ozone in the troposphere, lower and middle stratosphere, and to the TCO. The VPSC is an important contributor to changes in ozone in the middle stratosphere. AO explains part of low/mid stratospheric and TCO ozone cycle. A simulation model of ozone over Summit built from the MLR results explains the seasonal cycle and the

Development of a UAV-based Global Ozone Lidar Demonstrator (GOLD)

NASA Astrophysics Data System (ADS)

Browell, E. V.; Deyoung, R. J.; Hair, J. W.; Ismail, S.; McGee, T.; Hardesty, R. M.; Brewer, W. A.; McDermid, I. S.

2006-12-01

Global ozone measurements are needed across the troposphere with high vertical resolution to enable comprehensive studies of continental and intercontinental atmospheric chemistry and dynamics, which are affected by diverse natural and human-induced processes. The development of a unattended aerial vehicle (UAV) based Global Ozone Lidar Demonstrator (GOLD) is an important step in enabling a space-based ozone and aerosol lidar and for conducting unique UAV-based large-scale atmospheric investigations. The GOLD system will incorporate the most advanced technology developed under the NASA Laser Risk Reduction Program (LRRP) and the Small Business Innovative Research (SBIR) program to produce a compact, autonomously operating ozone and aerosol Differential Absorption Lidar (DIAL) system for a UAV platform. This system will leverage advanced Nd:YAG and optical parametric oscillator (OPO) laser technologies being developed by ITT Industries under the LRRP and the autonomously operating ozone DIAL system being developed by Science and Engineering Services Inc. (SESI) under an SBIR Phase-3 contract. Laser components from ITT will be integrated into the SESI DIAL system, and the resulting GOLD system will be flight tested on a NASA UAV. The development of the GOLD system was initiated as part of the NASA Instrument Incubator Program in December 2005, and great progress has been made towards completing major GOLD subsystems. ITT has begun construction of the high-power Nd:YAG pump laser and the ultraviolet OPO for generating the ozone DIAL wavelengths of 290 and 300 nm and the aerosol visible wavelength at 532 nm. SESI is completing the Phase-3 SBIR contract for the delivery and demonstration of the ozone DIAL receiver and data system, and NOAA is completing detector evaluations for use in the GOLD system. Welch Mechanical is examining system designs for integrating GOLD into the external pod that will be hung under the new IKANA (Predator-B) UAV that NASA Dryden is

The Sensitivity of U.S. Surface Ozone Formation to NOx, and VOCs as Viewed from Space

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; Sillman, Sanford; Retscher, Christian; Pickering, Kenneth E.; Martin, Randall V.; Celarier, Edward A.

2009-01-01

We investigated variations in the sensitivity of surface ozone formation in summer to precursor species concentrations of volatile organic compounds (VOCs) and nitrogen oxides (NO(x)) as inferred from the ratio of tropospheric columns of formaldehyde and nitrogen dioxide from the Aura Ozone Monitoring Instrument (OMI). The data indicate that ozone formation became: 1. more sensitive to NO(x) over most of the U.S, from 2005 to 2007 because of substantial decreases in NO(x) emissions primarily from stationary sources, and 2. more sensitive to NO(x) with increasing temperature, in part because emissions of highly reactive, biogenic isoprene increase with temperature, thus increasing the total VOC reactivity. Based on our interpretation of the data, current strategies implemented to reduce unhealthy levels of surface ozone should focus more on reducing NO(x) emissions, except in some downtown areas which have historically benefited from reductions in VOC emissions.

Ab Initio Studies of Stratospheric Ozone Depletion Chemistry

NASA Technical Reports Server (NTRS)

Lee, Timothy J.; Head-Gordon, Martin; Langhoff, Stephen R. (Technical Monitor)

1995-01-01

An overview of the current understanding of ozone depletion chemistry, particularly with regards the formation of the so-called Antarctic ozone hole, will be presented together with an outline as to how ab initio quantum chemistry can be used to further our understanding of stratospheric chemistry. The ability of modern state-of-the art ab initio quantum chemical techniques to characterize reliably the gas-phase molecular structure, vibrational spectrum, electronic spectrum, and thermal stability of fluorine, chlorine, bromine and nitrogen oxide species will be demonstrated by presentation of some example studies. The ab initio results will be shown to be in excellent agreement with the available experimental data, and where the experimental data are either not known or are inconclusive, the theoretical results are shown to fill in the gaps and to resolve experimental controversies. In addition, ab initio studies in which the electronic spectra and the characterization of excited electronic states of halogen oxide species will also be presented. Again where available, the ab initio results are compared to experimental observations, and are used to aid in the interpretation of experimental studies.

40 CFR Appendix H to Subpart G of... - Substitutes Subject to Use Restrictions and Unacceptable Substitutes, Effective May 28, 1999

Code of Federal Regulations, 2010 CFR

2010-07-01

... STRATOSPHERIC OZONE Significant New Alternatives Policy Program Pt. 82, Subpt. G, App. H Appendix H to Subpart G..., 1999 CFC-12 Automobile and Non-automobile Motor Vehicle Air Conditioners, Retrofit and New Criteria for... inch or the thread direction must be reversed (i.e. right-handed vs. left-handed). Simply changing the...

African Equatorial and Subtropical Ozone Plumes: Recurrences Timescales of the Brown Cloud Trans-African Plumes and Other Plumes

NASA Technical Reports Server (NTRS)

Chatfield, Robert B.; Thompson, Anne M.; Guan, Hong; Witte, Jacquelyn C.

2004-01-01

We have found repeated illustrations in the maps of Total Tropospheric Ozone (TTO) of apparent transport of ozone from the Indian Ocean to the Equatorial Atlantic Ocean. Most interesting are examples that coincide with the INDOEX observations of late northern winter, 1999. Three soundings associated with the SHADOZ (Southern Hemisphere Additional Ozonesondes) network help confirm and quantify degree of influence of pollution, lightning, and stratospheric sources, suggesting that perhaps 40% of increased Atlantic ozone could be Asian pollution during periods of maximum identified in the TTO maps. We outline recurrent periods of apparent ozone transport from Indian to Atlantic Ocean regions both during and outside the late-winter period. These are placed in the context of some general observations about factors controlling recurrence timescales for the expression of both equatorial and subtropical plumes. Low-level subtropical plumes are often controlled by frontal systems approaching the Namib coast; these direct mid-level air into either easterly equatorial plumes or westerly mid- troposphere plumes. Equatorial plumes of ozone cross Africa on an easterly path due to the occasional coincidence of two phenomena: (1) lofting of ozone to mid and upper levels, often in the Western Indian Ocean, and (2) the eastward extension of an Equatorial African easterly jet.

Convective Lofting Links Indian Ocean Air Pollution to Paradoxical South Atlantic Ozone Maxima

NASA Technical Reports Server (NTRS)

Chatfield, Robert B.; Guan, Hong; Thompson, Anne M.; Witte, Jacquelyn C.

2003-01-01

We describe a broad resolution of the "Atlantic Paradox" concerning the seasonal and geographic distribution of tropical tropospheric ozone. We describe periods of significant maximum tropospheric O3 for Jan.-April, 1999, exploiting satellite estimates and SHADOZ (Southern Hemisphere Additional Ozonesondes). Trajectory analyses connecting sondes and Total Tropospheric Ozone (TTO)O3 maps suggest a complex influence from the Indian Ocean: beginning with mixed combustion sources, then low level transport, cumulonimbus venting, and finally high-level transport to the west, with possible mixing over Africa. For the Jan.- March highest column-O3 periods in the Atlantic, distinct sounding peaks trace to specific NO sources, especially lightning, while in the same episodes, recurring every 30 or 60 days, more diffuse buildups of Indian-to-Atlantic pollution make important contributions.

Convective lofting links Indian Ocean air pollution to paradoxical South Atlantic ozone maxima

NASA Technical Reports Server (NTRS)

Chatfield, R. B.; Guan, H.; Thompson, A. M.; Witte, J. C.

2005-01-01

We describe a broad resolution of the Atlantic Parado concerning the seasonal and geographic distribution, of tropical tropospheric ozone. We highlight periods of significant maximum tropospheric O3 for Jan.- April, 1999, exploiting satellite estimates and SHADOZ (Southern Hemisphere Additional Ozonesondes). Trajectory analyses connecting sondes and Total Tropospheric Ozone (TTO) maps suggest a complex influence from the Indian Ocean: beginning with mixed combustion sources, then low level transport, cumulonimbus venting, possible stratospheric input, and finally high-level transport to the west, with possible mixing over Africa. For the Jan.-March highest column-O3 periods in the Atlantic, distinct sounding peaks trace to specific NO sources, especially lightning, while in the same episodes, recurring every 20-50 days, more diffuse buildups of Indian-to-Atlantic pollution make important contributions.

The Effect of Lake Temperatures and Emissions on Ozone Exposure in the Western Great Lakes Region

Treesearch

Jerome D. Fast; Warren E. Heilman

2003-01-01

A meteorological-chemical model with a 12-km horizontal grid spacing was used to simulate the evolution of ozone over the western Great Lakes region during a 30-day period in the summer of 1999. Lake temperatures in the model were based on analyses derived from daily satellite measurements. The model performance was evaluated using operational surface and upper-air...

Influence of low ozone episodes on erythemal UV-B radiation in Austria

NASA Astrophysics Data System (ADS)

Schwarz, Matthias; Baumgartner, Dietmar J.; Pietsch, Helga; Blumthaler, Mario; Weihs, Philipp; Rieder, Harald E.

2017-06-01

This study investigates the influence of low ozone episodes on UV-B radiation in Austria during the period 1999 to 2015. To this aim observations of total column ozone (TCO) in the Greater Alpine Region (Arosa, Switzerland; Hohenpeissenberg, Germany; Hradec Kralove, Czech Republic; Sonnblick, Austria), and erythemal UV-B radiation, available from 12 sites of the Austrian UV-B monitoring network, are analyzed. As previous definitions for low ozone episodes are not particularly suited to investigate effects on UV radiation, a novel threshold approach—considering anomalies—is developed to provide a joint framework for the analysis of extremes. TCO and UV extremes are negatively correlated, although modulating effects of sunshine duration impact the robustness of the statistical relationship. Therefore, information on relative sunshine duration (SDrel), available at (or nearby) UV-B monitoring sites, is included as explanatory variable in the analysis. The joint analysis of anomalies of both UV index (UVI) and total ozone (∆UVI, ∆TCO) and SDrel across sites shows that more than 65% of observations with strongly negative ozone anomalies (∆TCO < -1) led to positive UVI anomalies. Considering only days with strongly positive UVI anomaly (∆UVI > 1), we find (across all sites) that about 90% correspond to negative ∆TCO. The remaining 10% of days occurred during fair weather conditions (SDrel ≥ 80%) explaining the appearance of ∆UVI > 1 despite positive TCO anomalies. Further, we introduce an anomaly amplification factor (AAF), which quantifies the expected change of the ∆UVI for a given change in ∆TCO.

Temperature and Slant Path Effects in Dobson and Brewer Total Ozone Measurements

NASA Astrophysics Data System (ADS)

Scarnato, B.; Staehelin, J.; Peter, T.; Groebner, J.; Stuebi, R.

2009-12-01

There is a worldwide tendency to replace Dobson spectrophotometers in ground-based total ozone (TOZ) measurements by more advanced Brewer spectrophotometers. Ensuring the homogeneity of these datasets is of utmost importance if changes in TOZ of few percent over long time periods are to be diagnosed accurately. Previous studies have identified a seasonal bias of few percent between mid-latitude Brewer and Dobson measurements. At Arosa (Switzerland), two Dobson and three Brewer instruments are co-located since 1998, providing a unique dataset of quasi-simultaneous observations, invaluable to study systematic differences between these measurements. The differences are partially attributed to the seasonal variability in atmospheric temperatures and ozone slant paths (OSP). The sensitivity to the temperature dependence of the ozone absorption cross-section are calculated for each operational Brewer spectrophotometers at Arosa by using different high and low resolution reference spectra appropriately weighted with the instruments' slit functions, whereas the information of the primary standard instruments are used for all the Dobson instruments. The Brewer retrieval algorithm reveals a higher sensitivity to the reference spectra applied than the Dobson. When adopting the Bass and Paur (1985) or Malicet et al. (1995) ozone absorption spectra with their specific temperature dependence, and correcting for the OSP effect, the seasonal bias between Dobson and Brewer TOZ measurements is reduced to 0.6%. Conversely these differences increase using the spectral data of Burrows (1999). This finding illustrates, that the accuracy of ground-based spectrophotometric TOZ measurements is limited by the uncertainty in the ozone cross-sections measured by different internationally leading laboratories.

Regional and local background ozone in Houston during Texas Air Quality Study 2006

NASA Astrophysics Data System (ADS)

Langford, A. O.; Senff, C. J.; Banta, R. M.; Hardesty, R. M.; Alvarez, R. J.; Sandberg, Scott P.; Darby, Lisa S.

2009-04-01

Principal Component Analysis (PCA) is used to isolate the common modes of behavior in the daily maximum 8-h average ozone mixing ratios measured at 30 Continuous Ambient Monitoring Stations in the Houston-Galveston-Brazoria area during the Second Texas Air Quality Study field intensive (1 August to 15 October 2006). Three principal components suffice to explain 93% of the total variance. Nearly 84% is explained by the first component, which is attributed to changes in the "regional background" determined primarily by the large-scale winds. The second component (6%) is attributed to changes in the "local background," that is, ozone photochemically produced in the Houston area and spatially and temporally averaged by local circulations. Finally, the third component (3.5%) is attributed to short-lived plumes containing high ozone originating from industrial areas along Galveston Bay and the Houston Ship Channel. Regional background ozone concentrations derived using the first component compare well with mean ozone concentrations measured above the Gulf of Mexico by the tunable profiler for aerosols and ozone lidar aboard the NOAA Twin Otter. The PCA regional background values also agree well with background values derived using the lowest daily 8-h maximum method of Nielsen-Gammon et al. (2005), provided the Galveston Airport data (C34) are omitted from that analysis. The differences found when Galveston is included are caused by the sea breeze, which depresses ozone at Galveston relative to sites further inland. PCA removes the effects of this and other local circulations to obtain a regional background value representative of the greater Houston area.

Reconciliation of Halogen-Induced Ozone Loss with the Total-Column Ozone Record

NASA Technical Reports Server (NTRS)

Shepherd, T. G.; Plummer, D. A.; Scinocca, J. F.; Hegglin, M. I.; Fioletov, V. E.; Reader, M. C.; Remsberg, E.; von Clarmann, T.; Wang, H. J.

2014-01-01

The observed depletion of the ozone layer from the 1980s onwards is attributed to halogen source gases emitted by human activities. However, the precision of this attribution is complicated by year-to-year variations in meteorology, that is, dynamical variability, and by changes in tropospheric ozone concentrations. As such, key aspects of the total-column ozone record, which combines changes in both tropospheric and stratospheric ozone, remain unexplained, such as the apparent absence of a decline in total-column ozone levels before 1980, and of any long-term decline in total-column ozone levels in the tropics. Here we use a chemistry-climate model to estimate changes in halogen-induced ozone loss between 1960 and 2010; the model is constrained by observed meteorology to remove the eects of dynamical variability, and driven by emissions of tropospheric ozone precursors to separate out changes in tropospheric ozone. We show that halogen-induced ozone loss closely followed stratospheric halogen loading over the studied period. Pronounced enhancements in ozone loss were apparent in both hemispheres following the volcanic eruptions of El Chichon and, in particular, Mount Pinatubo, which significantly enhanced stratospheric aerosol loads. We further show that approximately 40% of the long-term non-volcanic ozone loss occurred before 1980, and that long-term ozone loss also occurred in the tropical stratosphere. Finally, we show that halogeninduced ozone loss has declined by over 10% since stratospheric halogen loading peaked in the late 1990s, indicating that the recovery of the ozone layer is well underway.

Effects of stratospheric ozone recovery on photochemistry and ozone air quality in the troposphere

NASA Astrophysics Data System (ADS)

Zhang, H.; Wu, S.; Huang, Y.; Wang, Y.

2014-04-01

There has been significant stratospheric ozone depletion since the late 1970s due to ozone-depleting substances (ODSs). With the implementation of the Montreal Protocol and its amendments and adjustments, stratospheric ozone is expected to recover towards its pre-1980 level in the coming decades. In this study, we examine the implications of stratospheric ozone recovery for the tropospheric chemistry and ozone air quality with a global chemical transport model (GEOS-Chem). With a full recovery of the stratospheric ozone, the projected increases in ozone column range from 1% over the low latitudes to more than 10% over the polar regions. The sensitivity factor of troposphere ozone photolysis rate, defined as the percentage changes in surface ozone photolysis rate for 1% increase in stratospheric ozone column, shows significant seasonal variation but is always negative with absolute value larger than one. The expected stratospheric ozone recovery is found to affect the tropospheric ozone destruction rates much more than the ozone production rates. Significant decreases in surface ozone photolysis rates due to stratospheric ozone recovery are simulated. The global average tropospheric OH decreases by 1.7%, and the global average lifetime of tropospheric ozone increases by 1.5%. The perturbations to tropospheric ozone and surface ozone show large seasonal and spatial variations. General increases in surface ozone are calculated for each season, with increases by up to 0.8 ppbv in the remote areas. Increases in ozone lifetime by up to 13% are found in the troposphere. The increased lifetimes of tropospheric ozone in response to stratospheric ozone recovery enhance the intercontinental transport of ozone and global pollution, in particular for the summertime. The global background ozone attributable to Asian emissions is calculated to increase by up to 15% or 0.3 ppbv in the Northern Hemisphere in response to the projected stratospheric ozone recovery.

Tropospheric Vertical Distribution of Tropical Atlantic Ozone Observed by TES during the Northern African Biomass Burning Season

NASA Technical Reports Server (NTRS)

Jourdain, L.; Worden, H. M.; Worden, J. R.; Bowman, K.; Li, Q.; Eldering, A.; Kulawik, S. S.; Osterman, G.; Boersma, K. F.; Fisher, B.;

Numerical Treatment of Thin Accretion Disk Dynamics around Rotating Black Holes

NASA Astrophysics Data System (ADS)

Yildiran, Deniz; Donmez, Orhan

In the present study, we perform the numerical simulation of a relativistic thin accretion disk around the nonrotating and rapidly rotating black holes using the general relativistic hydrodynamic code with Kerr in Kerr-Schild coordinate that describes the central rotating black hole. Since the high energy X-rays are produced close to the event horizon resulting the black hole-disk interaction, this interaction should be modeled in the relativistic region. We have set up two different initial conditions depending on the values of thermodynamical variables around the black hole. In the first setup, the computational domain is filled with constant parameters without injecting gas from the outer boundary. In the second, the computational domain is filled with the matter which is then injected from the outer boundary. The matter is assumed to be at rest far from the black hole. Both cases are modeled over a wide range of initial parameters such as the black hole angular momentum, adiabatic index, Mach number and asymptotic velocity of the fluid. It has been found that initial values and setups play an important role in determining the types of the shock cone and in designating the events on the accretion disk. The continuing injection from the outer boundary presents a tail shock to the steady state accretion disk. The opening angle of shock cone grows as long as the rotation parameter becomes larger. A more compressible fluid (bigger adiabatic index) also presents a bigger opening angle, a spherical shock around the rotating black hole, and less accumulated gas in the computational domain. While results from [J. A. Font, J. M. A. Ibanez and P. Papadopoulos, Mon. Not. R. Astron. Soc. 305 (1999) 920] indicate that the tail shock is warped around for the rotating hole, our study shows that it is the case not only for the warped tail shock but also for the spherical and elliptical shocks around the rotating black hole. The warping around the rotating black hole in our case

Search for gravitational wave ringdowns from perturbed intermediate mass black holes in LIGO-Virgo data from 2005-2010

NASA Astrophysics Data System (ADS)

Aasi, J.; Abbott, B. P.; Abbott, R.; Abbott, T.; Abernathy, M. R.; Acernese, F.; Ackley, K.; Adams, C.; Adams, T.; Addesso, P.; Adhikari, R. X.; Affeldt, C.; Agathos, M.; Aggarwal, N.; Aguiar, O. D.; Ain, A.; Ajith, P.; Alemic, A.; Allen, B.; Allocca, A.; Amariutei, D.; Andersen, M.; Anderson, R.; Anderson, S. B.; Anderson, W. G.; Arai, K.; Araya, M. C.; Arceneaux, C.; Areeda, J.; Aston, S. M.; Astone, P.; Aufmuth, P.; Aulbert, C.; Austin, L.; Aylott, B. E.; Babak, S.; Baker, P. T.; Ballardin, G.; Ballmer, S. W.; Barayoga, J. C.; Barbet, M.; Barish, B. C.; Barker, D.; Barone, F.; Barr, B.; Barsotti, L.; Barsuglia, M.; Barton, M. A.; Bartos, I.; Bassiri, R.; Basti, A.; Batch, J. C.; Bauchrowitz, J.; Bauer, Th. S.; Bavigadda, V.; Behnke, B.; Bejger, M.; Beker, M. G.; Belczynski, C.; Bell, A. S.; Bell, C.; Benacquista, M.; Bergmann, G.; Bersanetti, D.; Bertolini, A.; Betzwieser, J.; Beyersdorf, P. T.; Bilenko, I. A.; Billingsley, G.; Birch, J.; Biscans, S.; Bitossi, M.; Bizouard, M. A.; Black, E.; Blackburn, J. K.; Blackburn, L.; Blair, D.; Bloemen, S.; Bock, O.; Bodiya, T. P.; Boer, M.; Bogaert, G.; Bogan, C.; Bond, C.; Bondu, F.; Bonelli, L.; Bonnand, R.; Bork, R.; Born, M.; Boschi, V.; Bose, Sukanta; Bosi, L.; Bradaschia, C.; Brady, P. R.; Braginsky, V. B.; Branchesi, M.; Brau, J. E.; Briant, T.; Bridges, D. O.; Brillet, A.; Brinkmann, M.; Brisson, V.; Brooks, A. F.; Brown, D. A.; Brown, D. D.; Brückner, F.; Buchman, S.; Bulik, T.; Bulten, H. J.; Buonanno, A.; Burman, R.; Buskulic, D.; Buy, C.; Cadonati, L.; Cagnoli, G.; Bustillo, J. Calderón; Calloni, E.; Camp, J. B.; Campsie, P.; Cannon, K. C.; Canuel, B.; Cao, J.; Capano, C. D.; Carbognani, F.; Carbone, L.; Caride, S.; Castiglia, A.; Caudill, S.; Cavaglià, M.; Cavalier, F.; Cavalieri, R.; Celerier, C.; Cella, G.; Cepeda, C.; Cesarini, E.; Chakraborty, R.; Chalermsongsak, T.; Chamberlin, S. J.; Chao, S.; Charlton, P.; Chassande-Mottin, E.; Chen, X.; Chen, Y.; Chincarini, A.; Chiummo, A.; Cho, H. S.; Chow, J.; Christensen, N.; Chu, Q.; Chua, S. S. Y.; Chung, S.; Ciani, G.; Clara, F.; Clark, J. A.; Cleva, F.; Coccia, E.; Cohadon, P.-F.; Colla, A.; Collette, C.; Colombini, M.; Cominsky, L.; Constancio, M.; Conte, A.; Cook, D.; Corbitt, T. R.; Cordier, M.; Cornish, N.; Corpuz, A.; Corsi, A.; Costa, C. A.; Coughlin, M. W.; Coughlin, S.; Coulon, J.-P.; Countryman, S.; Couvares, P.; Coward, D. M.; Cowart, M.; Coyne, D. C.; Coyne, R.; Craig, K.; Creighton, J. D. E.; Crowder, S. G.; Cumming, A.; Cunningham, L.; Cuoco, E.; Dahl, K.; Canton, T. Dal; Damjanic, M.; Danilishin, S. L.; D'Antonio, S.; Danzmann, K.; Dattilo, V.; Daveloza, H.; Davier, M.; Davies, G. S.; Daw, E. J.; Day, R.; Dayanga, T.; Debreczeni, G.; Degallaix, J.; Deléglise, S.; Del Pozzo, W.; Denker, T.; Dent, T.; Dereli, H.; Dergachev, V.; De Rosa, R.; DeRosa, R. T.; DeSalvo, R.; Dhurandhar, S.; Díaz, M.; Di Fiore, L.; Di Lieto, A.; Di Palma, I.; Di Virgilio, A.; Dolique, V.; Donath, A.; Donovan, F.; Dooley, K. L.; Doravari, S.; Dossa, S.; Douglas, R.; Downes, T. P.; Drago, M.; Drever, R. W. P.; Driggers, J. C.; Du, Z.; Ducrot, M.; Dwyer, S.; Eberle, T.; Edo, T.; Edwards, M.; Effler, A.; Eggenstein, H.; Ehrens, P.; Eichholz, J.; Eikenberry, S. S.; Endrőczi, G.; Essick, R.; Etzel, T.; Evans, M.; Evans, T.; Factourovich, M.; Fafone, V.; Fairhurst, S.; Fang, Q.; Farinon, S.; Farr, B.; Farr, W. M.; Favata, M.; Fehrmann, H.; Fejer, M. M.; Feldbaum, D.; Feroz, F.; Ferrante, I.; Ferrini, F.; Fidecaro, F.; Finn, L. S.; Fiori, I.; Fisher, R. P.; Flaminio, R.; Fournier, J.-D.; Franco, S.; Frasca, S.; Frasconi, F.; Frede, M.; Frei, Z.; Freise, A.; Frey, R.; Fricke, T. T.; Fritschel, P.; Frolov, V. V.; Fulda, P.; Fyffe, M.; Gair, J.; Gammaitoni, L.; Gaonkar, S.; Garufi, F.; Gehrels, N.; Gemme, G.; Gendre, B.; Genin, E.; Gennai, A.; Ghosh, S.; Giaime, J. A.; Giardina, K. D.; Giazotto, A.; Gill, C.; Gleason, J.; Goetz, E.; Goetz, R.; Goggin, L. M.; Gondan, L.; González, G.; Gordon, N.; Gorodetsky, M. L.; Gossan, S.; Goßler, S.; Gouaty, R.; Gräf, C.; Graff, P. B.; Granata, M.; Grant, A.; Gras, S.; Gray, C.; Greenhalgh, R. J. S.; Gretarsson, A. M.; Groot, P.; Grote, H.; Grover, K.; Grunewald, S.; Guidi, G. M.; Guido, C.; Gushwa, K.; Gustafson, E. K.; Gustafson, R.; Hammer, D.; Hammond, G.; Hanke, M.; Hanks, J.; Hanna, C.; Hanson, J.; Harms, J.; Harry, G. M.; Harry, I. W.; Harstad, E. D.; Hart, M.; Hartman, M. T.; Haster, C.-J.; Haughian, K.; Heidmann, A.; Heintze, M.; Heitmann, H.; Hello, P.; Hemming, G.; Hendry, M.; Heng, I. S.; Heptonstall, A. W.; Heurs, M.; Hewitson, M.; Hild, S.; Hoak, D.; Hodge, K. A.; Holt, K.; Hooper, S.; Hopkins, P.; Hosken, D. J.; Hough, J.; Howell, E. J.; Hu, Y.; Huerta, E.; Hughey, B.; Husa, S.; Huttner, S. H.; Huynh, M.; Huynh-Dinh, T.; Ingram, D. R.; Inta, R.; Isogai, T.; Ivanov, A.; Iyer, B. R.; Izumi, K.; Jacobson, M.; James, E.; Jang, H.; Jaranowski, P.; Ji, Y.; Jiménez-Forteza, F.; Johnson, W. W.; Jones, D. I.; Jones, R.; Jonker, R. J. G.; Ju, L.; K, Haris; Kalmus, P.; Kalogera, V.; Kandhasamy, S.; Kang, G.; Kanner, J. B.; Karlen, J.; Kasprzack, M.; Katsavounidis, E.; Katzman, W.; Kaufer, H.; Kawabe, K.; Kawazoe, F.; Kéfélian, F.; Keiser, G. M.; Keitel, D.; Kelley, D. B.; Kells, W.; Khalaidovski, A.; Khalili, F. Y.; Khazanov, E. A.; Kim, C.; Kim, K.; Kim, N.; Kim, N. G.; Kim, Y.-M.; King, E. J.; King, P. J.; Kinzel, D. L.; Kissel, J. S.; Klimenko, S.; Kline, J.; Koehlenbeck, S.; Kokeyama, K.; Kondrashov, V.; Koranda, S.; Korth, W. Z.; Kowalska, I.; Kozak, D. B.; Kremin, A.; Kringel, V.; Krishnan, B.; Królak, A.; Kuehn, G.; Kumar, A.; Kumar, D. Nanda; Kumar, P.; Kumar, R.; Kuo, L.; Kutynia, A.; Kwee, P.; Landry, M.; Lantz, B.; Larson, S.; Lasky, P. D.; Lawrie, C.; Lazzarini, A.; Lazzaro, C.; Leaci, P.; Leavey, S.; Lebigot, E. O.; Lee, C.-H.; Lee, H. K.; Lee, H. M.; Lee, J.; Leonardi, M.; Leong, J. R.; Le Roux, A.; Leroy, N.; Letendre, N.; Levin, Y.; Levine, B.; Lewis, J.; Li, T. G. F.; Libbrecht, K.; Libson, A.; Lin, A. C.; Littenberg, T. B.; Litvine, V.; Lockerbie, N. A.; Lockett, V.; Lodhia, D.; Loew, K.; Logue, J.; Lombardi, A. L.; Lorenzini, M.; Loriette, V.; Lormand, M.; Losurdo, G.; Lough, J.; Lubinski, M. J.; Lück, H.; Luijten, E.; Lundgren, A. P.; Lynch, R.; Ma, Y.; Macarthur, J.; Macdonald, E. P.; MacDonald, T.; Machenschalk, B.; MacInnis, M.; Macleod, D. M.; Magana-Sandoval, F.; Mageswaran, M.; Maglione, C.; Mailand, K.; Majorana, E.; Maksimovic, I.; Malvezzi, V.; Man, N.; Manca, G. M.; Mandel, I.; Mandic, V.; Mangano, V.; Mangini, N.; Mantovani, M.; Marchesoni, F.; Marion, F.; Márka, S.; Márka, Z.; Markosyan, A.; Maros, E.; Marque, J.; Martelli, F.; Martin, I. W.; Martin, R. M.; Martinelli, L.; Martynov, D.; Marx, J. N.; Mason, K.; Masserot, A.; Massinger, T. J.; Matichard, F.; Matone, L.; Matzner, R. A.; Mavalvala, N.; Mazumder, N.; Mazzolo, G.; McCarthy, R.; McClelland, D. E.; McGuire, S. C.; McIntyre, G.; McIver, J.; McLin, K.; Meacher, D.; Meadors, G. D.; Mehmet, M.; Meidam, J.; Meinders, M.; Melatos, A.; Mendell, G.; Mercer, R. A.; Meshkov, S.; Messenger, C.; Meyers, P.; Miao, H.; Michel, C.; Mikhailov, E. E.; Milano, L.; Milde, S.; Miller, J.; Minenkov, Y.; Mingarelli, C. M. F.; Mishra, C.; Mitra, S.; Mitrofanov, V. P.; Mitselmakher, G.; Mittleman, R.; Moe, B.; Moesta, P.; Moggi, A.; Mohan, M.; Mohapatra, S. R. P.; Moraru, D.; Moreno, G.; Morgado, N.; Morriss, S. R.; Mossavi, K.; Mours, B.; Mow-Lowry, C. M.; Mueller, C. L.; Mueller, G.; Mukherjee, S.; Mullavey, A.; Munch, J.; Murphy, D.; Murray, P. G.; Mytidis, A.; Nagy, M. F.; Nardecchia, I.; Naticchioni, L.; Nayak, R. K.; Necula, V.; Nelemans, G.; Neri, I.; Neri, M.; Newton, G.; Nguyen, T.; Nitz, A.; Nocera, F.; Nolting, D.; Normandin, M. E. N.; Nuttall, L. K.; Ochsner, E.; O'Dell, J.; Oelker, E.; Oh, J. J.; Oh, S. H.; Ohme, F.; Oppermann, P.; O'Reilly, B.; O'Shaughnessy, R.; Osthelder, C.; Ottaway, D. J.; Ottens, R. S.; Overmier, H.; Owen, B. J.; Padilla, C.; Pai, A.; Palashov, O.; Palomba, C.; Pan, H.; Pan, Y.; Pankow, C.; Paoletti, F.; Papa, M. A.; Paris, H.; Pasqualetti, A.; Passaquieti, R.; Passuello, D.; Pedraza, M.; Penn, S.; Perreca, A.; Phelps, M.; Pichot, M.; Pickenpack, M.; Piergiovanni, F.; Pierro, V.; Pinard, L.; Pinto, I. M.; Pitkin, M.; Poeld, J.; Poggiani, R.; Poteomkin, A.; Powell, J.; Prasad, J.; Premachandra, S.; Prestegard, T.; Price, L. R.; Prijatelj, M.; Privitera, S.; Prodi, G. A.; Prokhorov, L.; Puncken, O.; Punturo, M.; Puppo, P.; Qin, J.; Quetschke, V.; Quintero, E.; Quiroga, G.; Quitzow-James, R.; Raab, F. J.; Rabeling, D. S.; Rácz, I.; Radkins, H.; Raffai, P.; Raja, S.; Rajalakshmi, G.; Rakhmanov, M.; Ramet, C.; Ramirez, K.; Rapagnani, P.; Raymond, V.; Razzano, M.; Re, V.; Read, J.; Recchia, S.; Reed, C. M.; Regimbau, T.; Reid, S.; Reitze, D. H.; Rhoades, E.; Ricci, F.; Riles, K.; Robertson, N. A.; Robinet, F.; Rocchi, A.; Rodruck, M.; Rolland, L.; Rollins, J. G.; Romano, R.; Romanov, G.; Romie, J. H.; Rosińska, D.; Rowan, S.; Rüdiger, A.; Ruggi, P.; Ryan, K.; Salemi, F.; Sammut, L.; Sandberg, V.; Sanders, J. R.; Sannibale, V.; Santiago-Prieto, I.; Saracco, E.; Sassolas, B.; Sathyaprakash, B. S.; Saulson, P. R.; Savage, R.; Scheuer, J.; Schilling, R.; Schnabel, R.; Schofield, R. M. S.; Schreiber, E.; Schuette, D.; Schutz, B. F.; Scott, J.; Scott, S. M.; Sellers, D.; Sengupta, A. S.; Sentenac, D.; Sequino, V.; Sergeev, A.; Shaddock, D.; Shah, S.; Shahriar, M. S.; Shaltev, M.; Shapiro, B.; Shawhan, P.; Shoemaker, D. H.; Sidery, T. L.; Siellez, K.; Siemens, X.; Sigg, D.; Simakov, D.; Singer, A.; Singer, L.; Singh, R.; Sintes, A. M.; Slagmolen, B. J. J.; Slutsky, J.; Smith, J. R.; Smith, M.; Smith, R. J. E.; Smith-Lefebvre, N. D.; Son, E. J.; Sorazu, B.; Souradeep, T.; Staley, A.; Stebbins, J.; Steinlechner, J.; Steinlechner, S.; Stephens, B. C.; Steplewski, S.; Stevenson, S.; Stone, R.; Stops, D.; Strain, K. A.; Straniero, N.; Strigin, S.; Sturani, R.; Stuver, A. L.; Summerscales, T. Z.; Susmithan, S.; Sutton, P. J.; Swinkels, B.; Tacca, M.; Talukder, D.; Tanner, D. B.; Tarabrin, S. P.; Taylor, R.; Thirugnanasambandam, M. P.; Thomas, M.; Thomas, P.; Thorne, K. A.; Thorne, K. S.; Thrane, E.; Tiwari, V.; Tokmakov, K. V.; Tomlinson, C.; Tonelli, M.; Torres, C. V.; Torrie, C. I.; Travasso, F.; Traylor, G.; Tse, M.; Ugolini, D.; Unnikrishnan, C. S.; Urban, A. L.; Urbanek, K.; Vahlbruch, H.; Vajente, G.; Valdes, G.; Vallisneri, M.; van Beuzekom, M.; van den Brand, J. F. J.; Van Den Broeck, C.; van der Sluys, M. V.; van Heijningen, J.; van Veggel, A. A.; Vass, S.; Vasúth, M.; Vaulin, R.; Vecchio, A.; Vedovato, G.; Veitch, J.; Veitch, P. J.; Venkateswara, K.; Verkindt, D.; Verma, S. S.; Vetrano, F.; Viceré, A.; Vincent-Finley, R.; Vinet, J.-Y.; Vitale, S.; Vo, T.; Vocca, H.; Vorvick, C.; Vousden, W. D.; Vyachanin, S. P.; Wade, A.; Wade, L.; Wade, M.; Walker, M.; Wallace, L.; Wang, M.; Wang, X.; Ward, R. L.; Was, M.; Weaver, B.; Wei, L.-W.; Weinert, M.; Weinstein, A. J.; Weiss, R.; Welborn, T.; Wen, L.; Wessels, P.; West, M.; Westphal, T.; Wette, K.; Whelan, J. T.; Whitcomb, S. E.; White, D. J.; Whiting, B. F.; Wiesner, K.; Wilkinson, C.; Williams, K.; Williams, L.; Williams, R.; Williams, T.; Williamson, A. R.; Willis, J. L.; Willke, B.; Wimmer, M.; Winkler, W.; Wipf, C. C.; Wiseman, A. G.; Wittel, H.; Woan, G.; Worden, J.; Yablon, J.; Yakushin, I.; Yamamoto, H.; Yancey, C. C.; Yang, H.; Yang, Z.; Yoshida, S.; Yvert, M.; ZadroŻny, A.; Zanolin, M.; Zendri, J.-P.; Zhang, Fan; Zhang, L.; Zhao, C.; Zhu, X. J.; Zucker, M. E.; Zuraw, S.; Zweizig, J.; LIGO Scientific Collaboration; Virgo Collaboration

2014-05-01

We report results from a search for gravitational waves produced by perturbed intermediate mass black holes (IMBH) in data collected by LIGO and Virgo between 2005 and 2010. The search was sensitive to astrophysical sources that produced damped sinusoid gravitational wave signals, also known as ringdowns, with frequency 50≤f0/Hz≤2000 and decay timescale 0.0001≲τ/s≲0.1 characteristic of those produced in mergers of IMBH pairs. No significant gravitational wave candidate was detected. We report upper limits on the astrophysical coalescence rates of IMBHs with total binary mass 50≤M/M⊙≤450 and component mass ratios of either 1:1 or 4:1. For systems with total mass 100≤M/M⊙≤150, we report a 90% confidence upper limit on the rate of binary IMBH mergers with nonspinning and equal mass components of 6.9×10-8 Mpc-3 yr-1. We also report a rate upper limit for ringdown waveforms from perturbed IMBHs, radiating 1% of their mass as gravitational waves in the fundamental, ℓ=m =2, oscillation mode, that is nearly three orders of magnitude more stringent than previous results.

Trends in Fatalities From Distracted Driving in the United States, 1999 to 2008

PubMed Central

Stimpson, Jim P.

2010-01-01

Objectives. We examined trends in distracted driving fatalities and their relation to cell phone use and texting volume. Methods. The Fatality Analysis Reporting System (FARS) records data on all road fatalities that occurred on public roads in the United States from 1999 to 2008. We studied trends in distracted driving fatalities, driver and crash characteristics, and trends in cell phone use and texting volume. We used multivariate regression analysis to estimate the relation between state-level distracted driving fatalities and texting volumes. Results. After declining from 1999 to 2005, fatalities from distracted driving increased 28% after 2005, rising from 4572 fatalities to 5870 in 2008. Crashes increasingly involved male drivers driving alone in collisions with roadside obstructions in urban areas. By use of multivariate analyses, we predicted that increasing texting volumes resulted in more than 16 000 additional road fatalities from 2001 to 2007. Conclusions. Distracted driving is a growing public safety hazard. Specifically, the dramatic rise in texting volume since 2005 appeared to be contributing to an alarming rise in distracted driving fatalities. Legislation enacting texting bans should be paired with effective enforcement to deter drivers from using cell phones while driving. PMID:20864709

Trends in fatalities from distracted driving in the United States, 1999 to 2008.

PubMed

Wilson, Fernando A; Stimpson, Jim P

2010-11-01

We examined trends in distracted driving fatalities and their relation to cell phone use and texting volume. The Fatality Analysis Reporting System (FARS) records data on all road fatalities that occurred on public roads in the United States from 1999 to 2008. We studied trends in distracted driving fatalities, driver and crash characteristics, and trends in cell phone use and texting volume. We used multivariate regression analysis to estimate the relation between state-level distracted driving fatalities and texting volumes. After declining from 1999 to 2005, fatalities from distracted driving increased 28% after 2005, rising from 4572 fatalities to 5870 in 2008. Crashes increasingly involved male drivers driving alone in collisions with roadside obstructions in urban areas. By use of multivariate analyses, we predicted that increasing texting volumes resulted in more than 16,000 additional road fatalities from 2001 to 2007. Distracted driving is a growing public safety hazard. Specifically, the dramatic rise in texting volume since 2005 appeared to be contributing to an alarming rise in distracted driving fatalities. Legislation enacting texting bans should be paired with effective enforcement to deter drivers from using cell phones while driving.

PHOTOCHEMICAL AIR POLLUTION IN THE NORTH OF PORTUGAL: A HIGH TROPOSHERIC OZONE EPISODE

NASA Astrophysics Data System (ADS)

Monteiro, A.; Carvalho, A.; Tchepel, O.; Ferreira, J.; Martins, H.; Miranda, A.; Borrego, C.; Saavedra, S.; Rodríguez, A.; Souto, J. A.

2009-12-01

Very high concentrations of ozone are continuously measured at the monitoring station at Lamas d’Olo, located at the North of Portugal,. A particular high photochemical episode occurred between 11 and 13 of July 2005, registering ozone hourly maximum values above 350 µg.m-3. This ozone-rich episode is investigated in this paper, in order to identify its origin and formation. Besides the analysis of both meteorological and air quality monitoring datasets, a numerical modelling approach, based on MM5-CAMx system, was used to simulate the dispersion and transport (horizontal and vertical) of the photochemical pollutants and its precursors. A cross spectrum analysis of the meteorological and air quality time series was performed, in the frequency domain, to establish the relationships between ozone data measured at Lamas d’Olo with air quality data from neighbourhood stations and meteorological parameters. Results point out different behaviour/contribution between the analysed sites. Moreover, different contributions of the u and v wind component on the ozone concentration fluctuations were found suggesting the presence a mountain breeze circulation and a north synoptic transport. The preliminary modelling results pointed out that the vertical transport of pollutants are responsible for the measured high concentrations, combined with particular meteorological conditions, related to the planetary boundary layer (PBL) development. The pollutants transported and existent at high vertical levels are captured/trapped when the PBL height reaches its daily maximum, and extremely high ozone ground level concentrations are consequently measured.

Comparison of scientific findings from major ozone field studies in North America and Europe

NASA Astrophysics Data System (ADS)

Solomon, Paul; Cowling, Ellis; Hidy, George; Furiness, Cari

During the past decade, nearly 600 million dollars were invested in more than 30 major field studies in North America and Europe examining tropospheric ozone chemistry, meteorology, precursor emissions, and modeling. Most of these studies were undertaken to provide new or refined knowledge about ozone accumulation and to assist in the development of economical and effective emissions management practices for ozone. In this paper, we describe a selection of field research programs conducted under a wide range of geographical and climatological conditions in North America and Europe. The designs of these studies were generally similar, employing a combination of ground-based observation networks, upper-air sampling, and meteorological observations. Analysis and interpretation of the resulting data were combined with improved inventories of ozone precursor emissions and air quality modeling to develop new or enhanced knowledge about photochemical processes under various tropospheric conditions. The scientific results from these studies contained few surprises; in fact, they generally affirmed the conclusions in the review by the US National Research Council (NRC, 1999). Key findings include: (1) reaffirmation that tropospheric ozone is a multi-scale phenomenon extending to continental boundaries; (2) aerometric conditions aloft are important to ground-level ozone; (3) biogenic sources make important contributions to VOC and NO x emissions in parts of eastern North America and southern Europe; (4) emissions estimates are among the more uncertain components of predictive models for ozone; (5) recirculating flow over complex terrain and large water bodies are universally important factors affecting accumulation of ozone at the ground; (6) nonlinearities in ozone response to precursor changes create important degrees of freedom in management strategies - VOC and NO x sensitivities vary extensively in urban and rural areas, making decisions about emissions management

CONTRIBUTION TO INDOOR OZONE LEVELS OF AN OZONE GENERATOR

EPA Science Inventory

This report gives results of a study of a commonly used commercially available ozone generator, undertaken to determine its impact on indoor ozone levels. xperiment were conducted in a typical mechanically ventilated office and in a test house. he generated ozone and the in-room ...

Development of Compact Ozonizer with High Ozone Output by Pulsed Power

NASA Astrophysics Data System (ADS)

Tanaka, Fumiaki; Ueda, Satoru; Kouno, Kanako; Sakugawa, Takashi; Akiyama, Hidenori; Kinoshita, Youhei

Conventional ozonizer with a high ozone output using silent or surface discharges needs a cooling system and a dielectric barrier, and therefore becomes a large machine. A compact ozonizer without the cooling system and the dielectric barrier has been developed by using a pulsed power generated discharge. The wire to plane electrodes made of metal have been used. However, the ozone output was low. Here, a compact and high repetition rate pulsed power generator is used as an electric source of a compact ozonizer. The ozone output of 6.1 g/h and the ozone yield of 86 g/kWh are achieved at 500 pulses per second, input average power of 280 W and an air flow rate of 20 L/min.

Introduction to the SONEX (Subsonic Assessment Ozone and Nitrogen Oxides Experiment) and POLINAT-2 (Pollution from Aircraft Emissions in the North Atlantic Flight Corridor) Special Issue

NASA Technical Reports Server (NTRS)

Thompson, Anne M.; Singh, Hanwant B.; Schlager, Hans; Einaudi, Franco (Technical Monitor)

2000-01-01

Emissions of atmospheric species from the engines of subsonic aircraft at cruise altitude (roughly, above seven kilometers) are of concern to scientists, the aviation industry and policymakers for two reasons. First, water vapor, soot and sulfur oxides, and related heterogeneous processes, may modify clouds and aerosols enough to perturb radiative forcing in the UT/LS (upper troposphere/lower stratosphere). A discussion of these phenomena appears in Chapter 3 of the IPCC Aviation Assessment (1999). An airborne campaign conducted to evaluate aviation effects on contrail, cirrus and cloud formation, is described in Geophysical Research Letters. The second concern arises from subsonic aircraft emissions of nitrogen oxides (NO + NO2 = NO(sub x)), CO, and hydrocarbons. These species may add to the background mixture of photochemically reactive species that form ozone. In the UT/LS, ozone is a highly effective greenhouse gas. The impacts of subsonic aircraft emissions on tropospheric NO(sub x) and ozone budgets have been studied with models that focus on UT chemistry [e.g. see discussions of individual models in Brasseur et al., 1998; Friedl et al., 1997; IPCC, 1999]. Depending on the model used, projected increases in the global subsonic aircraft fleet from 1992 to 2015 will lead to a 50-100 pptv increase in UT/LS NO. at 12 km (compared to 50-150 pptv background) in northern hemisphere midlatitudes. The corresponding 12-km ozone increase is 7-11 ppbv, or 5-10% (Chapter 4 in IPCC, 1999). Two major sources of uncertainties in model estimates of aviation effects are: (1) the often limited degree to which global models - the scale required to evaluate aircraft emissions - realistically simulate atmospheric transport and other physical processes; (2) limited UT/LS observations of trace gases with which to evaluate model performance. In response to the latter deficiency, a number of airborne campaigns aimed at elucidating the effect of aircraft on atmospheric nitrogen oxides

The Met Office HadGEM3-ES chemistry-climate model: evaluation of stratospheric dynamics and its impact on ozone

NASA Astrophysics Data System (ADS)

Hardiman, Steven C.; Butchart, Neal; O'Connor, Fiona M.; Rumbold, Steven T.

2017-03-01

Free-running and nudged versions of a Met Office chemistry-climate model are evaluated and used to investigate the impact of dynamics versus transport and chemistry within the model on the simulated evolution of stratospheric ozone. Metrics of the dynamical processes relevant for simulating stratospheric ozone are calculated, and the free-running model is found to outperform the previous model version in 10 of the 14 metrics. In particular, large biases in stratospheric transport and tropical tropopause temperature, which existed in the previous model version, are substantially reduced, making the current model more suitable for the simulation of stratospheric ozone. The spatial structure of the ozone hole, the area of polar stratospheric clouds, and the increased ozone concentrations in the Northern Hemisphere winter stratosphere following sudden stratospheric warmings, were all found to be sensitive to the accuracy of the dynamics and were better simulated in the nudged model than in the free-running model. Whilst nudging can, in general, provide a useful tool for removing the influence of dynamical biases from the evolution of chemical fields, this study shows that issues can remain in the climatology of nudged models. Significant biases in stratospheric vertical velocities, age of air, water vapour, and total column ozone still exist in the Met Office nudged model. Further, these can lead to biases in the downward flux of ozone into the troposphere.

Ground Based, Millimeter Wave Measurement of Ozone in the Middle Atmosphere

NASA Technical Reports Server (NTRS)

Parrish, Alan

2000-01-01

There is a need for highly reliable measurements of stratospheric ozone. Policy makers worldwide concerned with public health rely oil a clear consensus from the scientific community as a basis for ozone-related environmental policy that has a significant impact oil national economies. Tile latest Such consensus was presented in WMO, and used in a 1999 meeting of the parties considering amendments to the Montreal Protocol oil Substances that Deplete the Ozone Layer. Tile scientific community, in turn, needs highly precise and accurate measurements of ozone levels, and small time derivatives of these levels, both in continued - development of its understanding of the physical and chemical processes involved and as clear evidence that these processes are occurring as stated. Over most of the world, changes in ozone levels are small. For example, over the heavily populated northern midlatitudes, the linearized rate of ozone decline is between 0.2% per year and 0.7% per year, depending on altitude. These values are small enough to make measurement requirements technically challenging. Data quality may suffer from imperfections in individual instruments. In one instance, early results from a satellite-borne ozone sensor were later found to be invalid because of calibration drift. Even in the absence of drift, tile absolute calibration of a new sensor may differ slightly from that of its predecessor in service. Most ozone remote sensing instruments operate at ultraviolet or infrared wavelengths where scattering from dust and aerosols must be taken into account; results from these systems may be or are affected following a major volcanic eruption, such as tile one at Mt. Pinatubo in 1991. Given these difficulties, a consensus of measurements from several independent systems is required to insure a reliable understanding of stratospheric ozone levels. Because of the above-described need for highly precise and accurate ozone measurements using several independent techniques

Entropy and temperature from black-hole/near-horizon-CFT duality

NASA Astrophysics Data System (ADS)

Rodriguez, Leo; Yildirim, Tuna

2010-08-01

We construct a two-dimensional CFT, in the form of a Liouville theory, in the near-horizon limit of four- and three-dimensional black holes. The near-horizon CFT assumes two-dimensional black hole solutions first introduced by Christensen and Fulling (1977 Phys. Rev. D 15 2088-104) and expanded to a greater class of black holes via Robinson and Wilczek (2005 Phys. Rev. Lett. 95 011303). The two-dimensional black holes admit a Diff(S1) subalgebra, which upon quantization in the horizon limit becomes Virasoro with calculable central charge. This charge and the lowest Virasoro eigen-mode reproduce the correct Bekenstein-Hawking entropy of the four- and three-dimensional black holes via the known Cardy formula (Blöte et al 1986 Phys. Rev. Lett. 56 742; Cardy 1986 Nucl. Phys. B 270 186). Furthermore, the two-dimensional CFT's energy-momentum tensor is anomalous. However, in the horizon limit the energy-momentum tensor becomes holomorphic equaling the Hawking flux of the four- and three-dimensional black holes. This encoding of both entropy and temperature provides a uniformity in the calculation of black hole thermodynamic and statistical quantities for the non-local effective action approach.

Relationship between VOC and NOx emissions and chemical production of tropospheric ozone in the Aburrá Valley (Colombia).

PubMed

Toro, María Victoria; Cremades, Lázaro V; Calbó, Josep

2006-10-01

Relationship between volatile organic compounds (VOC) and nitrogen oxides (NOx) emissions and the chemical production of tropospheric ozone is studied through mathematical simulation. The study is applied to the Aburrá Valley, in the Colombian Andes, which is a practically unknown area from the point of view of ozone formation. The model used for this application is the European modelling of atmospheric constituents (EUMAC) zooming model (EZM) which consists of a mesoscale prognostic model (MEMO, mesoscale meteorological model) and a chemical reaction model (MUSE, multiscale for the atmospheric dispersion of reactive species), coupled to the chemical mechanism EMEP (European monitoring and evaluation program). The analysis is performed for a real episode that was characterized by high ozone production and that happened during the 23rd and 24th December, 1999 in Medellín (Colombia). From this real scenario, a sensitivity analysis has been carried out in order to assess the influence of VOC and NOx amounts on ozone production and to extract some conclusions for future ozone abatement policies in Andean regions. As far as ozone air quality is concerned, it is shown that in order to keep current levels the emphasis must be put to avoid increasing NOx emissions, or alternatively, to augment VOC emissions in order to have a high VOC/NOx ratio.

Children's Models of the Ozone Layer and Ozone Depletion.

ERIC Educational Resources Information Center

Christidou, Vasilia; Koulaidis, Vasilis

1996-01-01

The views of 40 primary students on ozone and its depletion were recorded through individual, semi-structured interviews. The data analysis resulted in the formation of a limited number of models concerning the distribution and role of ozone in the atmosphere, the depletion process, and the consequences of ozone depletion. Identifies five target…

Ozone bioindicator

Treesearch

John W. Coulston; Mark J. Ambrose

2007-01-01

Why Is Ozone Important? Ground-level ozone occurs at phytotoxic levels in the United States (Lefohn and Pinkerton 1988). Elevated levels of ozone can cause foliar injury to several tree species, may cause growth loss, and can make trees more susceptible to insects and pathogens (Chappelka and Samuelson 1998). However, tree species have varying degrees of sensitivity to...

Ozone, Tropospheric

NASA Technical Reports Server (NTRS)

Fishman, Jack

1995-01-01

In the early part of the 20th century, ground-based and balloon-borne measurements discovered that most of atmosphere's ozone is located in the stratosphere with highest concentrations located between 15 and 30 km (9,3 and 18.6 miles). For a long time, it was believed that tropospheric ozone originated from the stratosphere and that most of it was destroyed by contact with the earth's surface. Ozone, O3, was known to be produced by the photo-dissociation of molecular oxygen, O2, a process that can only occur at wavelengths shorter than 242 nm. Because such short-wave-length radiation is present only in the stratosphere, no tropospheric ozone production is possible by this mechanism. In the 1940s, however, it became obvious that production of ozone was also taking place in the troposphere. The overall reaction mechanism was eventually identified by Arie Haagen-Smit of the California Institute of Technology, in highly polluted southern California. The copious emissions from the numerous cars driven there as a result of the mass migration to Los Angeles after World War 2 created the new unpleasant phenomenon of photochemical smog, the primary component of which is ozone. These high levels of ozone were injuring vegetable crops, causing women's nylons to run, and generating increasing respiratory and eye-irritation problems for the populace. Our knowledge of tropospheric ozone increased dramatically in the early 1950s as monitoring stations and search centers were established throughout southern California to see what could be done to combat this threat to human health and the environment.

Urban Summertime Ozone of China: Peak Ozone Hour and Nighttime Mixing

NASA Astrophysics Data System (ADS)

Qu, H.; Wang, Y.; Zhang, R.

2017-12-01

We investigate the observed diurnal cycle of summertime ozone in the cities of China using a regional chemical transport model. The simulated daytime ozone is in general agreement with the observations. Model simulations suggest that the ozone peak time and peak concentration are a function of NOx (NO + NO2) and volatile organic compound (VOC) emissions. The differences between simulated and observed ozone peak time and peak concentration in some regions can be applied to understand biases in the emission inventories. For example, the VOCs emissions are underestimated over the Pearl River Delta (PRD) region, and either NOx emissions are underestimated or VOC emissions are overestimated over the Yangtze River Delta (YRD) regions. In contrast to the general good daytime ozone simulations, the simulated nighttime ozone has a large low bias of up to 40 ppbv. Nighttime ozone in urban areas is sensitive to the nocturnal boundary-layer mixing, and enhanced nighttime mixing (from the surface to 200-500 m) is necessary for the model to reproduce the observed level of ozone.

Tropospheric ozone toxicity vs. usefulness of ozone therapy.

PubMed

Bocci, Velio Alvaro

2007-02-01

There is a general consensus that continuous inhalation of air polluted with ozone is detrimental for the lungs and vital organs. Even if the concentration of tropospheric ozone is slightly above the tolerated dose, toxicity ensues owing to the cumulative dose inhaled for months. However, in medicine ozone is used as a real drug and a precise concentration and therapeutic dosage must be calibrated against the antioxidant capacity of blood. As ozone reacts with blood, it generates pharmacological messengers such as H(2)O(2) and lipid oxidation products (LOPs). These activate several biochemical pathways in blood cells, which after reinfusion are responsible for therapeutic activities lasting several days. Neither acute nor chronic toxicity has been registered.

Ozone depleting substances: a key forcing of the Brewer-Dobson circulation

NASA Astrophysics Data System (ADS)

Abalos, M.; Polvani, L. M.; Garcia, R. R.; Kinnison, D. E.; Randel, W. J.

2017-12-01

In contrast with monotonically-increasing greenhouse gases (GHG), Ozone Depleting Substances (ODS) peak approximately on the year 2000 and decrease thereafter, thanks to the Montreal Protocol. We examine the influence of these anthropogenic emissions on the Brewer-Dobson circulation (BDC) using specifically designed runs of the Community Earth System Model - Whole Atmosphere Community Climate Model (CESM-WACCM). Consistent with previous works, we find a dominant role of ODSs on the observed BDC acceleration up to 2000 in the SH summer, through dynamical changes induced by the ozone hole. We extend the analyses to quantify the influence of ODSs on the BDC for different regions and seasons, and compare the model results to observational estimates. Finally, we show that ODSs will substantially reduce the GHG-induced BDC acceleration in the future. Specifically, the trends in stratospheric mean age of air will be 4 times smaller in the period 2000-2080 as compared to the period 1965-2000.

Temperature and slant path effects in Dobson and Brewer total ozone measurements

NASA Astrophysics Data System (ADS)

Scarnato, B.; Staehelin, J.; Peter, T.; GröBner, J.; Stübi, R.

2009-12-01

There is a worldwide tendency to replace Dobson spectrophotometers in ground-based total ozone (TOZ) measurements by more advanced Brewer spectrophotometers. Ensuring the homogeneity of these data sets is of utmost importance if changes in TOZ of a few percent over long time periods are to be diagnosed accurately. Previous studies have identified a seasonal bias of a few percent between midlatitude Brewer and Dobson measurements. At Arosa (Switzerland), two Dobson and three Brewer instruments have been colocated since 1998, providing a unique data set of quasi-simultaneous observations, invaluable to study systematic differences between these measurements. The differences are partially attributed to the seasonal variability in atmospheric temperatures and ozone slant paths (OSP). The sensitivity to the temperature dependence of the ozone absorption cross section is calculated for each operational Brewer spectrophotometers at Arosa by using different high- and low-resolution reference spectra appropriately weighted with the instruments' slit functions, whereas the information on the primary standard instruments is used for all the Dobson instruments. The Brewer retrieval algorithm reveals a higher sensitivity to the reference spectra applied than the Dobson. When adopting the Bass and Paur (1985) or Malicet et al. (1995) ozone absorption spectra with their specific temperature dependence, and correcting for the OSP effect, the seasonal bias between Dobson and Brewer TOZ measurements is reduced to 0.6%. Conversely, these differences increase when using the spectral data of Burrows et al. (1999). This finding illustrates that the accuracy of ground-based spectrophotometric TOZ measurements is limited by the uncertainty in the ozone cross sections measured by different internationally leading laboratories.

Representativeness of single lidar stations for zonally averaged ozone profiles, their trends and attribution to proxies

NASA Astrophysics Data System (ADS)

Zerefos, Christos; Kapsomenakis, John; Eleftheratos, Kostas; Tourpali, Kleareti; Petropavlovskikh, Irina; Hubert, Daan; Godin-Beekmann, Sophie; Steinbrecht, Wolfgang; Frith, Stacey; Sofieva, Viktoria; Hassler, Birgit

2018-05-01

This paper is focusing on the representativeness of single lidar stations for zonally averaged ozone profile variations over the middle and upper stratosphere. From the lower to the upper stratosphere, ozone profiles from single or grouped lidar stations correlate well with zonal means calculated from the Solar Backscatter Ultraviolet Radiometer (SBUV) satellite overpasses. The best representativeness with significant correlation coefficients is found within ±15° of latitude circles north or south of any lidar station. This paper also includes a multivariate linear regression (MLR) analysis on the relative importance of proxy time series for explaining variations in the vertical ozone profiles. Studied proxies represent variability due to influences outside of the earth system (solar cycle) and within the earth system, i.e. dynamic processes (the Quasi Biennial Oscillation, QBO; the Arctic Oscillation, AO; the Antarctic Oscillation, AAO; the El Niño Southern Oscillation, ENSO), those due to volcanic aerosol (aerosol optical depth, AOD), tropopause height changes (including global warming) and those influences due to anthropogenic contributions to atmospheric chemistry (equivalent effective stratospheric chlorine, EESC). Ozone trends are estimated, with and without removal of proxies, from the total available 1980 to 2015 SBUV record. Except for the chemistry related proxy (EESC) and its orthogonal function, the removal of the other proxies does not alter the significance of the estimated long-term trends. At heights above 15 hPa an inflection point between 1997 and 1999 marks the end of significant negative ozone trends, followed by a recent period between 1998 and 2015 with positive ozone trends. At heights between 15 and 40 hPa the pre-1998 negative ozone trends tend to become less significant as we move towards 2015, below which the lower stratosphere ozone decline continues in agreement with findings of recent literature.

Analysis of ozone precursor data from Baton Rouge, Houston, El Paso, and Dallas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sather, M.E.; Kemp, M.G.

1998-12-31

Ongoing analyses of ozone precursor data continue to be performed for Baton Rouge, Louisiana, and Houston, El Paso, and Dallas, Texas. All four areas have collected ambient monitoring data for ozone, nitrogen oxides (NO{sub x}), and over 50 volatile organic compound (VOC) species in accordance with the Photochemical Assessment Monitoring Stations (PAMS) requirements. The PAMS program was initiated to provide more detailed VOC, NO{sub x}, and meteorological data for scientists, modelers, and managers working toward eliminating violations of the ozone National Ambient Air Quality Standards (NAAQS). This paper will focus on several useful analyses of PAMS data for the fourmore » study areas including: (1) a trends analysis of Total Non-Methane Organic Compounds (TNMOC), NO{sub x}, and ozone data from two Baton Rouge sites, (2) results of TNMOC/NO{sub x} ratio analyses for the three Baton Rouge PAMS sites which can provide a starting point for evaluating specific site sensitivity to changes in VOC or NO{sub x} ambient concentrations, (3) results of benzene/toluene ratio analyses which supply information on aged/fresh air masses, and (4) results of ethylene/acetylene ratio analyses which are useful in determining the impacts of catalytic/noncatalytic vehicles. This paper will also discuss the continuing maturation of the PAMS program in Baton Rouge, Houston, and El Paso. The Dallas area is expected to formally begin implementing a PAMS program in 1998 after the area is reclassified to a serious status for ozone pollution. In addition, the Beaumont, Texas area is currently scheduled to be reclassified to a serious status for ozone pollution in the 1998/1999 time period, and thus would also need to begin implementing a PAMS program.« less

Understanding ozone mechanisms to alleviate ceramic membrane fouling

NASA Astrophysics Data System (ADS)

Chu, Irma Giovanna Llamosas

Ceramic membranes are a strong prospect as an advanced treatment in the drinking water domain. But their high capital cost and the lack of specific research on their performance still discourage their application in this field. Thus, knowing that fouling is the main drawback experienced in filtration processes, this bench-scale study was aimed to assess the impact of an ozonation pre-treatment on the alleviation of the fouling of UF ceramic membranes. Preozonation and filtration steps were performed under two different pH and ozone doses. Chosen pH values were at the limits of natural surface waters range (6.5 and 8.5) to keep practicability. Raw water from the Thousand Isle's river at Quebec-Canada was used for the tests. The filtration setup involved an unstirred dead-end filtration cell operated at constant flux. Results showed that pre-oxidation by ozone indeed reduced the fouling degree of the membranes according to the dose applied (up to 60 and 85% for membranes 8 and 50 kDa, respectively). Direct NOM oxidation was found responsible for this effect as the presence of molecular ozone was not essential to achieve these results. In the context of this experiment, however, pH showed to be more effective than the ozonation pre-treatment to keep fouling at low levels: 70% lower at pH 6.5 than at pH 8.5 for un-ozonated waters, which was contrary to most of the literature found on the topic (Changwon, 2013; De Angelis & Fidalgo, 2013; Karnik et al., 2005; S. Lee & Kim, 2014). This behaviour results mainly from the operation mode used in the experiment, the electrical repulsions between MON molecules at basic pH that led to the accumulation of material on the feed side of the membranes (concentration polarisation) and ulterior cake formation. In addition, solution pH showed an influence in the definition of fouling mechanisms. At solution pH 6.5, which was precisely the isoelectric point of the membranes (+/-6.5), the blocking fouling mode was frequently detected

Earth's Endangered Ozone

ERIC Educational Resources Information Center

Panofsky, Hans A.

1978-01-01

Included are (1) a discussion of ozone chemistry; (2) the effects of nitrogen fertilizers, fluorocarbons, and high level aircraft on the ozone layer; and (3) the possible results of a decreasing ozone layer. (MR)

Aircraft cabin ozone measurements on B747-100 and B747-SP aircraft: Correlations with atmospheric ozone and ozone encounter statistics

NASA Technical Reports Server (NTRS)

Perkins, P. J.; Holdeman, J. D.; Gauntner, D. J.

1978-01-01

Simultaneous measurements of atmospheric (outside) ozone concentration and ozone levels in the cabin of the B747-100 and B747-SP airliners were made by NASA to evaluate the aircraft cabin ozone contamination problem. Instrumentation on these aircraft measured ozone from an outside probe and at one point in the cabin. Average ozone in the cabin of the B747-100 was 39 percent of the outside. Ozone in the cabin of the B747-SP measured 82 percent of the outside, before corrective measures. Procedures to reduce the ozone in this aircraft included changes in the cabin air circulation system, use of the high-temperature 15th stage compressor bleed, and charcoal filters in the inlet cabin air ducting, which as separate actions reduced the ozone to 58, 19 and 5 percent, respectively. The potential for the NASA instrumented B747 aircraft to encounter high levels of cabin ozone was derived from atmospheric oxone measurements on these aircraft. Encounter frequencies for two B747-100's were comparable even though the route structures were different. The B747-SP encountered high ozone than did the B747-100's.

Five blind men and an elephant: can NASA Aura measurements quantify the stratosphere-troposphere exchange of ozone flux?

NASA Astrophysics Data System (ADS)

Tang, Q.; Prather, M. J.

2011-09-01

We examine whether the instantaneous ozone (O3) measurements from the four Aura instruments can quantify the stratosphere-troposphere exchange (STE) flux of O3, an important term of the tropospheric O3 budget. Comparing the level 2 (L2) Aura swaths and ozone sondes with the coincident, high-resolution (1°×1°×40-layer×0.5 h) simulations using the University of California, Irvine chemistry transport model (CTM) for years 2005-2006, it is revealed in many cases that all four Aura datasets have some skill in catching the STE process, while missing many of them. Despite a few cases, the individual retrievals in the upper troposphere and lower stratosphere contain too much noise preventing the quantification and integration of STE flux with Aura L2 data. The CTM is applied as a transfer standard to compare with different Aura observations. The statistics of exact matching CTM-Aura comparisons identify the model's high biases in the lower stratosphere and the inconsistency amongst different instruments, such as from tropics to Northern Hemisphere mid-latitudes in July 2005 at 215 hPa and over tropics at 147 hPa for July 2005 and January 2006.

Multiscale multifractal properties between ground-level ozone and its precursors in rural area in Hong Kong.

PubMed

He, Hong-di; Qiao, Zhong-Xia; Pan, Wei; Lu, Wei-Zhen

2017-07-01

In rural area, due to the reduction of NOx and CO emitted from vehicle exhausts, the ozone photochemical reaction exhibits relatively weak effect and ozone formation presents different pattern with its precursors in contrast to urban situation. Hence, in this study, we apply detrended cross-correlation analysis to investigate the multifractal properties between ozone and its precursors in a rural area in Hong Kong. The observed databases of ozone, NO 2 , NOx and CO levels during 2005-2014 are obtained from a rural monitoring station in Hong Kong. Based on the collected database, the cross-correlation analysis is carried out firstly to examine the cross-correlation patterns and the results indicate that close interactive relations exist between them. Then the detrended cross-correlation analysis is performed for further analysis. The multifractal characters occur between ozone and its precursors. The long-term cross-correlations behaviors in winter are verified to be stronger than that in other seasons. Additionally, the method is extended on daily averaged data to explore the multifractal property on various time scales. The long-term cross-correlation behavior of ozone vs NO 2 and NOx on daily basis becomes weaker while that of ozone vs CO becomes stronger. The multifractal properties for all pairs in summer are found to be the strongest among the whole year. These findings successfully illustrate that the multifractal analysis is a useful tool for describing the temporal scaling behaviors of ozone trends in different time series in rural areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

Ozone and Ozone By-Products in the Cabins of Commercial Aircraft

PubMed Central

Weisel, Clifford; Weschler, Charles J.; Mohan, Kris; Vallarino, Jose; Spengler, John D.

2013-01-01

The aircraft cabin represents a unique indoor environment due to its high surface-to-volume ratio, high occupant density and the potential for high ozone concentrations at cruising altitudes. Ozone was continuously measured and air was sampled on sorbent traps, targeting carbonyl compounds, on 52 transcontinental U.S. or international flights between 2008 and 2010. The sampling was predominantly on planes that did not have ozone scrubbers (catalytic converters). Peak ozone levels on aircraft without catalytic convertors exceeded 100 ppb, with some flights having periods of more than an hour when the ozone levels were > 75ppb. Ozone was greatly reduced on relatively new aircraft with catalytic convertors, but ozone levels on two flights whose aircraft had older convertors were similar to those on planes without catalytic convertors. Hexanal, heptanal, octanal, nonanal, decanal and 6-methyl-5-hepten-2-one (6-MHO) were detected in the aircraft cabin at sub- to low ppb levels. Linear regression models that included the log transformed mean ozone concentration, percent occupancy and plane type were statistically significant and explained between 18 and 25% of the variance in the mixing ratio of these carbonyls. Occupancy was also a significant factor for 6-MHO, but not the linear aldehydes, consistent with 6-MHO’s formation from the reaction between ozone and squalene, which is present in human skin oils. PMID:23517299

Comparative Analysis of the Long-term Trends of the Surface Ozone Concentration at Elevated Sites in the Alps and in Caucasus Region

NASA Astrophysics Data System (ADS)

Tarasova, O. A.; Staehelin, J.; Prevot, A. S.; Senik, I. A.; Sosonkin, M. G.; Cui, J.

2007-12-01

Analysis of the long-term surface ozone records of two mountain sites, namely Kislovodsk High Mountain Station (KHMS) in Caucasus, Russia (43.7°N, 42.7°E, 2070 asl.) and Jungfraujoch (JFJ) in Switzerland (46.5°N, 7.9°E, 3580m asl) will be presented. A strong increase in ozone concentration (up +0.46±0.11ppb/year) was found at JFJ while ozone significantly deceased at KHMS (-0.65 ±0.09 ppb/year) during 1990-2005. We will compare trends values for earlier years (1990-2001) and for the latter ones (1993-2005). Among the possible reasons of the trends difference the impact of atmospheric transport is studied. Both vertical and horizontal components are considered in connection with ozone concentration trends. Transport analysis is based on 3D trajectories using LAGRANTO. There was no substantial difference in trends detected for different PV-levels or PBL filtered cases, while the main difference has been found in the source areas of the air masses at the two locations and inside different advection sectors at the each particular site. Trends will be compared (for the two receptor sites and two periods) for filtered subsets of upper tropospheric/stratospheric cases (based on PV and trajectory altitude), cases impacted by Planetary Boundary Layer (based on PBL height) and in different horizontal advection clusters. The work is financially supported by the Swiss National Science Foundation (JRP IB7320-110831), European Commission (Marie-Curie IIF project N 039905 - FP6-2005-Mobility-7) and Russian Foundation for Basic Research (projects 06-05-64427 and 06-05-65308) and contributes to ACCENT T&TP project.

Tropospheric Ozone Determined from Aura OMI and MLS: Evaluation of Measurements and Comparison with the Global Modeling Initiative's Chemical Transport Model

NASA Technical Reports Server (NTRS)

Ziemke, J. R.; Chandra, S.; Duncan, B. N.; Froidevaux, L.; Bhartia, P. K.; Levelt, P. F.; Waters, J. W.

2006-01-01

Ozone measurements from the OMI and MLS instruments on board the Aura satellite are used for deriving global distributions of tropospheric column ozone (TCO). TCO is determined using the tropospheric ozone residual method which involves subtracting measurements of MLS stratospheric column ozone (SCO) from OMI total column ozone after adjusting for intercalibration differences of the two instruments using the convective-cloud differential method. The derived TCO field, which covers one complete year of mostly continuous daily measurements from late August 2004 through August 2005, is used for studying the regional and global pollution on a timescale of a few days to months. The seasonal and zonal characteristics of the observed TCO fields are also compared with TCO fields derived from the Global Modeling Initiative's Chemical Transport Model. The model and observations show interesting similarities with respect to zonal and seasonal variations. However, there are notable differences, particularly over the vast region of the Saharan desert.

Ozone, ozone production rates and NO observations on the outskirts of Quito, Ecuador

NASA Astrophysics Data System (ADS)

Cazorla, M.

2014-12-01

Air quality measurements of ambient ozone, ozone production rates and nitrogen oxides, in addition to baseline meterology observations, are being taken at a recently built roof-top facility on the campus of Universidad San Francisco de Quito, in Ecuador. The measurement site is located in Cumbayá, a densely populated valley adjacent to the city of Quito. Time series of ozone and NO are being obtained with commercial air quality monitors. Rush-hour peaks of NO, above 100 ppb, have been observed, while daytime ozone levels are low. In addition, ozone production rates are being measured with the Ecuadorian version of the MOPS, Measurement of Ozone Production Sensor, originally built at Penn State University in 2010. NO and ozone observations and test results of measured ozone production rates will be presented.

Decline in Antarctic Ozone Depletion and Lower Stratospheric Chlorine Determined From Aura Microwave Limb Sounder Observations

NASA Astrophysics Data System (ADS)

Strahan, Susan E.; Douglass, Anne R.

2018-01-01

Attribution of Antarctic ozone recovery to the Montreal protocol requires evidence that (1) Antarctic chlorine levels are declining and (2) there is a reduction in ozone depletion in response to a chlorine decline. We use Aura Microwave Limb Sounder measurements of O3, HCl, and N2O to demonstrate that inorganic chlorine (Cly) from 2013 to 2016 was 223 ± 93 parts per trillion lower in the Antarctic lower stratosphere than from 2004 to 2007 and that column ozone depletion declined in response. The mean Cly decline rate, 0.8%/yr, agrees with the expected rate based on chlorofluorocarbon lifetimes. N2O measurements are crucial for identifying changes in stratospheric Cly loading independent of dynamical variability. From 2005 to 2016, the ozone depletion and Cly time series show matching periods of decline, stability, and increase. The observed sensitivity of O3 depletion to changing Cly agrees with the sensitivity simulated by the Global Modeling Initiative chemistry transport model integrated with Modern Era Retrospective Analysis for Research and Applications 2 meteorology.

Ozone and the stratosphere

NASA Technical Reports Server (NTRS)

Shimazaki, Tatsuo

1987-01-01

It is shown that the stratospheric ozone is effective in absorbing almost all radiation below 300 nm at heights below 300 km. The distribution of global ozone in the troposphere and the lower stratosphere, and the latitudinal variations of the total ozone column over four seasons are considered. The theory of the ozone layer production is discussed together with catalytic reactions for ozone loss and the mechanisms of ozone transport. Special attention is given to the anthropogenic perturbations, such as SST exhaust gases and freon gas from aerosol cans and refrigerators, that may cause an extensive destruction of the stratospheric ozone layer and thus have a profound impact on the world climate and on life.

Behavior, distribution and variability of surface ozone at an arid region in the south of Iberian Peninsula (Seville, Spain).

PubMed

Adame, José A; Lozano, Antonio; Bolívar, Juan P; De la Morena, Benito A; Contreras, Juan; Godoy, Francisca

2008-01-01

In order to improve our knowledge of the surface ozone in the south of the Iberian Peninsula, annual, monthly, weekly and daily ozone concentrations have been closely monitored in the Seville metropolitan area highlighting those episodes that exceed the European Ozone Directive. A three-year period (2003-2005) and eight ozone stations were used; five of them located in the city's busiest areas and the rest in adjacent zones ( approximately 25km). In addition, the wind regime was also studied in order to understand the main characteristics of the surface atmospheric dynamics. The lowest ozone concentrations 17-33microgm(-3) took place in January while the highest 57-95microgm(-3) occurred in June. The ozone concentration week-weekend differences from May to September indicate that this phenomenon does not affect the ozone stations analysed. Daily cycles show minimum values between 7:00 and 8:00 UTC and maximum at noon, exceeding 90microgm(-3) during summer months. From March to October the ozone concentrations were above the target value for the protection of human health, especially during the summer months, with values up to 30% over the limit. The information threshold has been exceeded at all ozone stations studied but with greater frequency in the stations far from the city centre. In addition, at these latter stations the alert threshold was also exceeded on six occasions. This study in the city of Seville indicates that the high ozone levels are due to local atmospheric effects, mainly since the ozone air masses may undergo recirculation processes. The ozone is transported to the city from the S-SW, having a major impact in the NE areas.

Evidence for a Continuous Decline in Lower Stratospheric Ozone Offsetting Ozone Layer Recovery

NASA Technical Reports Server (NTRS)

Ball, William T.; Alsing, Justin; Mortlock, Daniel J.; Staehelin, Johannes; Haigh, Joanna D.; Peter, Thomas; Tummon, Fiona; Stuebi, Rene; Stenke, Andrea; Anderson, John;

Evidence for a continuous decline in lower stratospheric ozone offsetting ozone layer recovery

NASA Astrophysics Data System (ADS)

Ball, William T.; Alsing, Justin; Mortlock, Daniel J.; Staehelin, Johannes; Haigh, Joanna D.; Peter, Thomas; Tummon, Fiona; Stübi, Rene; Stenke, Andrea; Anderson, John; Bourassa, Adam; Davis, Sean M.; Degenstein, Doug; Frith, Stacey; Froidevaux, Lucien; Roth, Chris; Sofieva, Viktoria; Wang, Ray; Wild, Jeannette; Yu, Pengfei; Ziemke, Jerald R.; Rozanov, Eugene V.

2018-02-01

Ozone forms in the Earth's atmosphere from the photodissociation of molecular oxygen, primarily in the tropical stratosphere. It is then transported to the extratropics by the Brewer-Dobson circulation (BDC), forming a protective ozone layer around the globe. Human emissions of halogen-containing ozone-depleting substances (hODSs) led to a decline in stratospheric ozone until they were banned by the Montreal Protocol, and since 1998 ozone in the upper stratosphere is rising again, likely the recovery from halogen-induced losses. Total column measurements of ozone between the Earth's surface and the top of the atmosphere indicate that the ozone layer has stopped declining across the globe, but no clear increase has been observed at latitudes between 60° S and 60° N outside the polar regions (60-90°). Here we report evidence from multiple satellite measurements that ozone in the lower stratosphere between 60° S and 60° N has indeed continued to decline since 1998. We find that, even though upper stratospheric ozone is recovering, the continuing downward trend in the lower stratosphere prevails, resulting in a downward trend in stratospheric column ozone between 60° S and 60° N. We find that total column ozone between 60° S and 60° N appears not to have decreased only because of increases in tropospheric column ozone that compensate for the stratospheric decreases. The reasons for the continued reduction of lower stratospheric ozone are not clear; models do not reproduce these trends, and thus the causes now urgently need to be established.

Ozone Trend Detectability

NASA Technical Reports Server (NTRS)

Campbell, J. W. (Editor)

1981-01-01

The detection of anthropogenic disturbances in the Earth's ozone layer was studied. Two topics were addressed: (1) the level at which a trend in total ozoning is detected by existing data sources; and (2) empirical evidence in the prediction of the depletion in total ozone. Error sources are identified. The predictability of climatological series, whether empirical models can be trusted, and how errors in the Dobson total ozone data impact trend detectability, are discussed.

Model Assessment of the Impact on Ozone of Subsonic and Supersonic Aircraft

NASA Technical Reports Server (NTRS)

Ko, Malcolm; Weisenstein, Debra; Danilin, Michael; Scott, Courtney; Shia, Run-Lie

2000-01-01

This is the final report for work performed between June 1999 through May 2000. The work represents continuation of the previous contract which encompasses five areas: (1) continued refinements and applications of the 2-D chemistry-transport model (CTM) to assess the ozone effects from aircraft operation in the stratosphere; (2) studying the mechanisms that determine the evolution of the sulfur species in the aircraft plume and how such mechanisms affect the way aircraft sulfur emissions should be introduced into global models; (3) the development of diagnostics in the AER 3-wave interactive model to assess the importance of the dynamics feedback and zonal asymmetry in model prediction of ozone response to aircraft operation; (4) the development of a chemistry parameterization scheme in support of the global modeling initiative (GMI); and (5) providing assessment results for preparation of national and international reports which include the "Aviation and the Global Atmosphere" prepared by the Intergovernmental Panel on Climate Change, "Assessment of the effects of high-speed aircraft in the stratosphere: 1998" by NASA, and the "Model and Measurements Intercomparison II" by NASA. Part of the work was reported in the final report. We participated in the SAGE III Ozone Loss and Validation Experiment (SOLVE) campaign and we continue with our analyses of the data.

OZONE BYPRODUCT FORMATION

EPA Science Inventory

The use of ozone for water treatment has been increasing as ozone has great potential for degrading water pollutants and inactivating viruses, Giardia cysts, and Cryptosporidium oocysts. Although it appears that ozone generates less undesirable disinfection by-products (DBPs) th...

The characteristics of tropospheric ozone seasonality observed from ozone soundings at Pohang, Korea.

PubMed

Kim, Jae H; Lee, H J; Lee, S H

2006-07-01

This paper presents the first analysis of vertical ozone sounding measurements over Pohang, Korea. The main focus is to analyze the seasonal variation of vertical ozone profiles and determine the mechanisms controlling ozone seasonality. The maxima ozone at the surface and in the free troposphere are observed in May and June, respectively. In comparison with the ozone seasonality at Oki (near sea level) and Happo (altitude of 1840 m) in Japan, which are located at the same latitude as of Pohang, we have found that the time of the ozone maximum at the Japanese sites is always a month earlier than at Pohang. Analysis of the wind flow at the surface shows that the wind shifts from westerly to southerly in May over Japan, but in June over Pohang. However, this wind shift above boundary layer occurs a month later. This wind shift results in significantly smaller amounts of ozone because the southerly wind brings clean wet tropical air. It has been suggested that the spring ozone maximum in the lower troposphere is due to polluted air transported from China. However, an enhanced ozone amount over the free troposphere in June appears to have a different origin. A tongue-like structure in the time-height cross-section of ozone concentrations, which starts from the stratosphere and extends to the middle troposphere, suggests that the ozone enhancement occurs due to a gradual migration of ozone from the stratosphere. The high frequency of dry air with elevated ozone concentrations in the upper troposphere in June suggests that the air is transported from the stratosphere. HYSPLIT trajectory analysis supports the hypothesis that enhanced ozone in the free troposphere is not likely due to transport from sources of anthropogenic activity.

SMM mesospheric ozone measurements

NASA Technical Reports Server (NTRS)

Aikin, A. C.

1990-01-01

The main objective was to understand the secular and seasonal behavior of ozone in the lower mesosphere, 50 to 70 km. This altitude region is important in understanding the factors which determine ozone behavior. A secondary objective is the study of stratospheric ozone in the polar regions. Use is made of results from the SBUV satellite borne instrument. In the Arctic the interaction between chlorine compounds and low molecular weight hydrocarbons is studied. More than 30,000 profiles were obtained using the UVSP instrument on the SMM spacecraft. Several orbits of ozone data per day were obtained allowing study of the current rise in solar activity from the minimum until the present. Analysis of Nimbus 7 SBUV data in Antarctic spring indicates that ozone is depleted within the polar vortex relative to ozone outside the vortex. This depletion confirms the picture of ozone loss at altitudes where polar stratospheric clouds exist. In addition, there is ozone loss above the cloud level indicating that there is another mechanism in addition to ozone loss initiated by heterogeneous chlorine reactions on cloud particles.

Four years of ground-based total ozone measurements by visible spectrometry in Antarctica

NASA Technical Reports Server (NTRS)

Goutail, F.; Pommereau, J. P.; Sarkissian, A.

1994-01-01

Visible spectrometers SAOZ have been developed at Service d'Aeronomie for permanent ground-based ozone monitoring at all latitudes up to the polar circle in winter. Observations are made by looking at the sunlight scattered at zenith in the visible range, twice a day, at sunrise and sunset. Compared to ozone observations in the UV generally in use, visible observations in the small Chappuis bands at twilight have the advantages of being independent of stratospheric temperature, little contaminated by tropospheric ozone and multiple scattering, and of permitting observations even in winter at the polar circle. SAOZ instruments have been installed since 1988 at several stations in the Antarctic and the Arctic. More than four years data at Dumont d'Urville in Terre Adelie (67 deg S) are now available. The station is generally located at the edge of the vortex in spring and therefore the ozone hole is seen there only occasionally. The lowest values (140 DU) were reported in early October 1991. According to these first regular observations throughout the whole winter ozone seems to increase in late autumn and winter. Its decay does not start before the end of August. Although of smaller amplitude than with the previous version five data, the ratio between the groundbased and satellite/TOMS measurements displays a systematic seasonal variation correlated partly to the sun zenith angle of observations from orbit and partly to the temperature of the stratosphere. Since ground-based measurements are always made at 90 deg SZA, the SZA dependence must come from the satellite data interpretation (TOMS observations are between 43 to 88 deg SZA). The temperature dependence could be partly due to variations of ozone absorption cross-sections in the ultraviolet used by the satellite spectrometer, and partly to a systematic seasonal cycle of the air mass factor use in the interpretation of the ground based observations. However, the last contribution appears to be too small to

Measurements and Modeling of The Air Pollution and The Meteorology On A Complex Topography Region: Case Study Grenoble 1998/1999

NASA Astrophysics Data System (ADS)

Couach, O.; Balin, I.; Jimenez, R.; Quaglia, P.; Kirchner, F.; Ristori, P.; Simeonov, V.; Clappier, A.; van den Bergh, H.; Calpini, B.

In order to understand, to predict and to elaborate solutions concerning the photo- chemical and meteorological processes, which occur often in the summer time over the Grenoble city and its three surroundings valleys, both modeling and measurement approaches were considered. Two intensive air pollution and meteorological measure- ments campaigns were performed in 1998 and 1999. Ozone (O3) and other pollutants (NOx, CH2O, SO2, etc) as well as wind, temperature, solar radiation and relative hu- midity were intensively measured at surface level combined with 3D measurements range by using: an instrumented aircraft (Metair), two ozone lidars (e.g. EPFL ozone dial lidar) and wind profilers (e.g.Degreane). This poster will focus on the main results of these measurements like the 3D ozone distribution, the mixing height/planetary boundary layer evolution, the meteorological behavior, and the other pollutants evalu- ation. The paper also highlights the use of these measurements as a necessary database for comparison and checking (validation) of the model performances and thus to allow modeling solutions in predicting the air pollution events and thus permitting to build the right abatement strategies.

A comparative study of ozonation, iron coated zeolite catalyzed ozonation and granular activated carbon catalyzed ozonation of humic acid.

PubMed

Gümüş, Dilek; Akbal, Feryal

2017-05-01

This study compares ozonation (O 3 ), iron coated zeolite catalyzed ozonation (ICZ-O 3 ) and granular activated carbon catalyzed ozonation (GAC-O 3 ) for removal of humic acid from an aqueous solution. The results were evaluated by the removal of DOC that specifies organic matter, UV 254 absorbance, SUVA (Specific Ultraviolet Absorbance at 254 nm) and absorbance at 436 nm. When ozonation was used alone, DOC removal was 21.4% at an ozone concentration of 10 mg/L, pH 6.50 and oxidation time of 60 min. The results showed that the use of ICZ or GAC as a catalyst increased the decomposition of humic acid compared to ozonation alone. DOC removal efficiencies were 62% and 48.1% at pH 6.5, at a catalyst loading of 0.75 g/L, and oxidation time of 60 min for ICZ and GAC, respectively. The oxidation experiments were also carried out using <100 kDa and <50 kDa molecular size fractions of humic acid in the presence of ICZ or GAC. Catalytic ozonation also yielded better DOC and UV 254 reduction in both <50 kDa and <100 kDa fractions of HA compared to ozonation. Copyright © 2017 Elsevier Ltd. All rights reserved.

Ozonation of Canadian Athabasca asphaltene

NASA Astrophysics Data System (ADS)

Cha, Zhixiong

Application of ozonation in the petrochemical industry for heavy hydrocarbon upgrading has not been sufficiently explored. Among heavy hydrocarbons, asphaltenes are the heaviest and the most difficult fractions for analysis and treatment. Therefore, ozonation of asphaltenes presents an interesting application in the petrochemical industry. Commercial application of ozonation in the petrochemical industry has three obstacles: availability of an ozone-resistant and environmentally friendly solvent, the precipitation of ozonation intermediates during reaction, and recovery of the solvent and separation of the ozonation products. Preliminary ozonation of Athabasca oil sands asphaltene in nonparticipating solvents encountered serious precipitation of the ozonation intermediates. The precipitated intermediates could be polymeric ozonides and intermolecular ozonides or polymeric peroxides. Because the inhomogeneous reaction medium caused low ozone efficiency, various participating solvents such as methanol and acetic acid were added to form more soluble hydroperoxides. The mass balance results showed that on average, one asphaltene molecule reacted with 12 ozone molecules through the electrophilic reaction and the subsequent decomposition of ozonation intermediates generated acetone extractable products. GC/MS analysis of these compounds indicated that the free radical reactions could be important for generation of volatile products. The extensively ozonated asphaltene in the presence of participating solvents were refluxed with methanol to generate more volatile products. GC/MS analysis of the methanol-esterified ozonation products indicated that most volatile products were aliphatic carboxylic acid esters generated through cleavage of substituents. Reaction kinetics study showed that asphaltene ozonation was initially a diffusion rate-controlled reaction and later developed to a chemical reaction rate-controlled reaction after depletion of the reactive aromatic sites

Proceedings of the 13th Annual International Conference on Outdoor Recreation & Education (Jackson Hole, Wyoming, November 1-6, 1999).

ERIC Educational Resources Information Center

Harwell, Rick, Ed.; Emmons, Karin, Ed.

This proceedings contains papers, abstracts of papers, and descriptions of professional development workshops at the 1999 International Conference of the Association for Outdoor Recreation and Education (AORE). Following conference schedules and session information, substantive entries include: "The 1999 National Outdoor Book Awards";…

A revised linear ozone photochemistry parameterization for use in transport and general circulation models: multi-annual simulations

NASA Astrophysics Data System (ADS)