40 CFR 52.350 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.350 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Colorado § 52.350 Control strategy: Ozone. (a) Revisions to the Colorado State Implementation Plan, 1-hour ozone NAAQS Redesignation Request and Maintenance...

75 FR 64675 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-20

... approve a request from the State of Texas to redesignate the Beaumont/Port Arthur (BPA) Texas ozone... making a final determination that the BPA nonattainment area has attained the 1997 8- hour ozone NAAQS... BPA State Implementation Plan (SIP), a 1997 8-hour ozone maintenance plan that includes a 2021 Motor...

77 FR 29540 - Approval and Promulgation of Implementation Plans; Portion of York County, SC Within Charlotte...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-18

... 1997 8-Hour Ozone Nonattainment Area; Ozone 2002 Base Year Emissions Inventory AGENCY: Environmental... ozone 2002 base year emissions inventory portion of the state implementation plan (SIP) revision.... The emissions inventory is included in the ozone attainment demonstration that was submitted for the...

78 FR 52893 - Implementation of the 2008 National Ambient Air Quality Standards for Ozone: State Implementation...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-27

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Parts 50, 51, 70 and 71 [EPA-HQ-OAR-2010-0885, FRL-9810-3] RIN 2060-AR34 Implementation of the 2008 National Ambient Air Quality Standards for Ozone: State Implementation Plan Requirements Correction In proposed rule document 2013-13233 appearing on pages 34178 through...

78 FR 34903 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-11

... Promulgation of Air Quality Implementation Plans; Ohio; 1997 8-Hour Ozone Maintenance Plan Revision; Motor... request by Ohio to revise the 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP) to... area with budgets developed using EPA's Motor Vehicle Emissions Simulator (MOVES) emissions model. Ohio...

40 CFR 52.2585 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.2585... strategy: Ozone. (a) Disapproval—On November 6, 1986, the Wisconsin Department of Natural Resources submitted as a proposed revision to the State's ozone State Implementation Plan a site-specific reasonably...

40 CFR 52.2585 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.2585... strategy: Ozone. (a) Disapproval—On November 6, 1986, the Wisconsin Department of Natural Resources submitted as a proposed revision to the State's ozone State Implementation Plan a site-specific reasonably...

40 CFR 52.2585 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.2585... strategy: Ozone. (a) Disapproval—On November 6, 1986, the Wisconsin Department of Natural Resources submitted as a proposed revision to the State's ozone State Implementation Plan a site-specific reasonably...

40 CFR 52.2585 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.2585... strategy: Ozone. (a) Disapproval—On November 6, 1986, the Wisconsin Department of Natural Resources submitted as a proposed revision to the State's ozone State Implementation Plan a site-specific reasonably...

75 FR 9373 - Approval and Promulgation of Implementation Plans; New York State Implementation Plan Revision

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-02

... for State Implementation Plan (SIP) Submissions? In 1997, EPA revised the health-based national... that ozone causes adverse health effects at lower ozone concentrations and over longer periods of time... standard would be more protective of human health, especially with regard to children and adults who are...

78 FR 34965 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Lima 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-11

... Promulgation of Air Quality Implementation Plans; Ohio; Lima 1997 8-Hour Ozone Maintenance Plan Revision; Motor... 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP) to replace the previously... Simulator (MOVES) emissions model. Ohio submitted the SIP revision request to EPA on January 11, 2013. DATES...

78 FR 34965 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-11

... Promulgation of Air Quality Implementation Plans; Ohio; 1997 8-Hour Ozone Maintenance Plan Revision; Motor... request by Ohio to revise the 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP...) emissions model. Ohio submitted the SIP revision request to EPA on December 7, 2012. DATES: Comments must be...

78 FR 34906 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Lima 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-11

... Promulgation of Air Quality Implementation Plans; Ohio; Lima 1997 8-Hour Ozone Maintenance Plan Revision to... Lima, Ohio 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP) to replace motor... (MOVES) emissions model. Ohio submitted the SIP revision request to EPA on January 11, 2013. DATES: This...

78 FR 21867 - Approval and Promulgation of Implementation Plans; Revision to the New York State Implementation...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-12

.... It is important to note, aside from ozone, the NYMA is attaining the NAAQS for all of the other..., the area was redesignated to attainment in 2002 and is currently a maintenance area. For ozone, the... has attained the 1-hour ozone standard and has attained the 1997 8-hour ozone standard by its required...

2008 Ozone National Ambient Air Quality Standards (NAAQS) Findings of Failure to Submit

EPA Pesticide Factsheets

This final action finds that 15 states and the District of Columbia have failed to submit specific state implementation plan (SIP) elements to satisfy certain nonattainment area, and/or Ozone Transport Region (OTR), planning requirements for the 2008 ozone

76 FR 5078 - Approval and Promulgation of Air Quality Implementation Plans: Tennessee; Approval of Section 110...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-28

...) Maintenance Plan for the 1997 8-Hour Ozone Standards for the Nashville, TN, Area AGENCY: Environmental... Tennessee State Implementation Plan (SIP) concerning the maintenance plan addressing the 1997 8-hour ozone standards for the Nashville, Tennessee 1997 8-hour ozone maintenance area, which is comprised of Davidson...

77 FR 21913 - Approval and Promulgation of State Implementation Plans; Hawaii; Infrastructure Requirements for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-12

... Promulgation of State Implementation Plans; Hawaii; Infrastructure Requirements for the 1997 8-Hour Ozone and... requirements of Section 110(a)(1) and (2) of the Clean Air Act (CAA) for the 1997 8-hour ozone national ambient...): Air quality modeling and submission of modeling data. Section 110(a)(2)(L): Permitting fees. Section...

77 FR 60661 - Approval and Promulgation of Air Quality Implementation Plans; Indiana; South Bend-Elkhart...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-04

... Promulgation of Air Quality Implementation Plans; Indiana; South Bend-Elkhart, Indiana Ozone Maintenance Plan..., Indiana 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP) by replacing the... Vehicle Emissions Simulator (MOVES) 2010a emissions model. Indiana submitted this request to EPA for...

78 FR 6741 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-31

... Quality Standard (NAAQS); a State Implementation Plan (SIP) revision containing a 10-year ozone... emissions budgets (MVEBs) for the years 2008 and 2022 that are contained in the 10-year ozone maintenance... forth how the area will maintain attainment of the 1997 8-hour ozone NAAQS for the next 10 years in...

40 CFR 52.1534 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.1534... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the New Hampshire Department... revisions are for the purpose of satisfying the one-hour ozone attainment demonstration requirements of...

40 CFR 52.1129 - Control strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Ozone. 52.1129... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Massachusetts Department...) and 182(c)(2)(B) of the Clean Air Act for the Springfield, Massachusetts serious ozone nonattainment...

40 CFR 52.1129 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.1129... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Massachusetts Department...) and 182(c)(2)(B) of the Clean Air Act for the Springfield, Massachusetts serious ozone nonattainment...

40 CFR 52.1534 - Control strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Ozone. 52.1534... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the New Hampshire Department... revisions are for the purpose of satisfying the one-hour ozone attainment demonstration requirements of...

40 CFR 52.1129 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.1129... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Massachusetts Department...) and 182(c)(2)(B) of the Clean Air Act for the Springfield, Massachusetts serious ozone nonattainment...

40 CFR 52.1129 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.1129... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Massachusetts Department...) and 182(c)(2)(B) of the Clean Air Act for the Springfield, Massachusetts serious ozone nonattainment...

40 CFR 52.1129 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.1129... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Massachusetts Department...) and 182(c)(2)(B) of the Clean Air Act for the Springfield, Massachusetts serious ozone nonattainment...

40 CFR 52.1534 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.1534... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the New Hampshire Department... revisions are for the purpose of satisfying the one-hour ozone attainment demonstration requirements of...

40 CFR 52.1534 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.1534... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the New Hampshire Department... revisions are for the purpose of satisfying the one-hour ozone attainment demonstration requirements of...

40 CFR 52.1534 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.1534... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the New Hampshire Department... revisions are for the purpose of satisfying the one-hour ozone attainment demonstration requirements of...

40 CFR 96.386 - Withdrawal from CAIR NOX Ozone Season Trading Program.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Withdrawal from CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.386 Withdrawal from CAIR NOX Ozone Season Trading Program. Except as provided under paragraph (g) of this section, a CAIR NOX Ozone Season...

40 CFR 96.386 - Withdrawal from CAIR NOX Ozone Season Trading Program.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Withdrawal from CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.386 Withdrawal from CAIR NOX Ozone Season Trading Program. Except as provided under paragraph (g) of this section, a CAIR NOX Ozone Season...

40 CFR 96.386 - Withdrawal from CAIR NOX Ozone Season Trading Program.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Withdrawal from CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.386 Withdrawal from CAIR NOX Ozone Season Trading Program. Except as provided under paragraph (g) of this section, a CAIR NOX Ozone Season...

40 CFR 96.386 - Withdrawal from CAIR NOX Ozone Season Trading Program.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Withdrawal from CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.386 Withdrawal from CAIR NOX Ozone Season Trading Program. Except as provided under paragraph (g) of this section, a CAIR NOX Ozone Season...

40 CFR 96.386 - Withdrawal from CAIR NOX Ozone Season Trading Program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Withdrawal from CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.386 Withdrawal from CAIR NOX Ozone Season Trading Program. Except as provided under paragraph (g) of this section, a CAIR NOX Ozone Season...

78 FR 28747 - Approval and Promulgation of Implementation Plans; North Carolina; State Implementation Plan...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-16

... standards for ozone, lead, and particulate matter found in the Code of Federal Regulations. DATES: This..., submission amending the State's NAAQS table for ozone, lead and particulate matter that are found at 15A NCAC... Carolina's SIP. b. Lead On November 12, 2008, EPA revised the lead NAAQS from 1.5 micrograms per cubic...

40 CFR 52.66 - Control Strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control Strategy: Ozone. 52.66 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Alabama § 52.66 Control Strategy: Ozone. (a) The redesignation request submitted by the State of Alabama, on March 16, 1995 for the Birmingham marginal ozone...

40 CFR 52.66 - Control Strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control Strategy: Ozone. 52.66 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Alabama § 52.66 Control Strategy: Ozone. (a) The redesignation request submitted by the State of Alabama, on March 16, 1995 for the Birmingham marginal ozone...

40 CFR 52.2088 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.2088... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Rhode Island Department of...) of the Clean Air Act, for the Providence serious ozone nonattainment area. (b) Approval—Revisions to...

40 CFR 52.66 - Control Strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control Strategy: Ozone. 52.66 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Alabama § 52.66 Control Strategy: Ozone. (a) The redesignation request submitted by the State of Alabama, on March 16, 1995 for the Birmingham marginal ozone...

40 CFR 52.2088 - Control strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Ozone. 52.2088... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Rhode Island Department of...) of the Clean Air Act, for the Providence serious ozone nonattainment area. (b) Approval—Revisions to...

40 CFR 52.66 - Control Strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control Strategy: Ozone. 52.66 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Alabama § 52.66 Control Strategy: Ozone. (a) The redesignation request submitted by the State of Alabama, on March 16, 1995 for the Birmingham marginal ozone...

40 CFR 52.2088 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.2088... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Rhode Island Department of...) of the Clean Air Act, for the Providence serious ozone nonattainment area. (b) Approval—Revisions to...

40 CFR 52.2088 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.2088... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Rhode Island Department of...) of the Clean Air Act, for the Providence serious ozone nonattainment area. (b) Approval—Revisions to...

40 CFR 52.2088 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.2088... strategy: Ozone. (a) Revisions to the State Implementation Plan submitted by the Rhode Island Department of...) of the Clean Air Act, for the Providence serious ozone nonattainment area. (b) Approval—Revisions to...

40 CFR 52.1683 - Control strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS (CONTINUED) New York § 52.1683 Control strategy: Ozone. (a) The State of New York has certified to the satisfaction of the EPA that no sources are... ozone nonattainment areas in New York listed below have attained the 1-hour ozone standard on the date...

78 FR 28497 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Canton-Massillon 1997 8-Hour...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-15

... Promulgation of Air Quality Implementation Plans; Ohio; Canton-Massillon 1997 8-Hour Ozone Maintenance Plan... the Canton-Massillon, Ohio 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP... using EPA's Motor Vehicle Emissions Simulator (MOVES) emissions model. Ohio submitted the SIP revision...

78 FR 28551 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Canton-Massillon 1997 8-Hour...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-15

... Promulgation of Air Quality Implementation Plans; Ohio; Canton-Massillon 1997 8-Hour Ozone Maintenance Plan..., Ohio, 1997 8-hour ozone maintenance air quality State Implementation Plan (SIP) under the Clean Air Act... Motor Vehicle Emissions Simulator (MOVES) emissions model. Ohio submitted the SIP revision request to...

76 FR 57013 - Approval and Promulgation of Air Quality Implementation Plans; West Virginia; Revised Motor...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-15

... Promulgation of Air Quality Implementation Plans; West Virginia; Revised Motor Vehicle Emission Budgets for the... Implementation Plan (SIP) revision submitted by the State of West Virginia for the purpose of amending the 8-hour ozone maintenance plan for the Charleston, Huntington, Parkersburg, Weirton, and Wheeling 8-hour ozone...

California Baseline Ozone Transport Study (CABOTS): Ozonesonde Measurements

NASA Astrophysics Data System (ADS)

Eiserloh, A. J., Jr.; Chiao, S.; Spitze, J.; Cauley, S.; Clark, J.; Roberts, M.

2016-12-01

Because the EPA recently lowered the ambient air quality standard for the 8-hr average of ozone (O3) to70 ppbv, California must continue to achieve significant reductions in ozone precursor emissions and prepare for new State Implementation Plans (SIP) to demonstrate how ground-level ambient ozone will be reduced below the new health-based standard. Prior studies suggest that background levels of ozone traveling across the Pacific Ocean can significantly influence surface ozone throughout California, particularly during the spring. Evidence has been presented indicating that background levels of ozone continue to increase in the western United States over the recent few decades, implying more ozone exceedances in the future. To better understand the contributions of the external natural and anthropogenic pollution sources as well as atmospheric processes for surface ozone concentrations in California during the spring and summer months, the California Baseline Ozone Transport Study (CABOTS) has been established. One major goal of CABOTS is to implement near daily ozonesonde measurements along the California Coast to quantify background ozone aloft before entering the State during high ozone season. CABOTS has been ongoing from May through August of 2016 launching ozonesondes from Bodega Bay and Half Moon Bay, California. The temporal progression of ozonesonde measurements and subsequent analysis of the data will be discussed with a focus on the contribution of background ozone to surface ozone sites inland as well as likely origins of layers aloft. Comparisons of current ozonesondes versus prior ozonesonde studies of California will also be performed. A few selected cases of high ozone layers moving onshore from different sources will be discussed as well.

40 CFR 96.388 - CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units. 96.388 Section 96.388 Protection of Environment... SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.388 CAIR...

40 CFR 96.388 - CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units. 96.388 Section 96.388 Protection of Environment... SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.388 CAIR...

40 CFR 96.388 - CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units. 96.388 Section 96.388 Protection of Environment... SO 2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.388 CAIR...

40 CFR 96.388 - CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units. 96.388 Section 96.388 Protection of Environment... SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.388 CAIR...

40 CFR 96.388 - CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false CAIR NOX Ozone Season allowance allocations to CAIR NOX Ozone Season opt-in units. 96.388 Section 96.388 Protection of Environment... SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Opt-in Units § 96.388 CAIR...

40 CFR 96.360 - Submission of CAIR NOX Ozone Season allowance transfers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Submission of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Transfers § 96.360 Submission of CAIR NOX Ozone Season allowance transfers. A CAIR authorized account representative seeking recordation of a CAIR...

40 CFR 96.360 - Submission of CAIR NOX Ozone Season allowance transfers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Submission of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Transfers § 96.360 Submission of CAIR NOX Ozone Season allowance transfers. A CAIR authorized account representative seeking recordation of a CAIR...

40 CFR 96.341 - Timing requirements for CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Timing requirements for CAIR NOX Ozone... PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.341 Timing requirements for CAIR NOX Ozone Season allowance allocations. (a) By October 31, 2006, the permitting authority...

40 CFR 96.360 - Submission of CAIR NOX Ozone Season allowance transfers.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Submission of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Transfers § 96.360 Submission of CAIR NOX Ozone Season allowance transfers. A CAIR authorized account representative seeking recordation of a CAIR...

40 CFR 96.341 - Timing requirements for CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Timing requirements for CAIR NOX Ozone... PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.341 Timing requirements for CAIR NOX Ozone Season allowance allocations. (a) By October 31, 2006, the permitting authority...

40 CFR 96.341 - Timing requirements for CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Timing requirements for CAIR NOX Ozone... PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.341 Timing requirements for CAIR NOX Ozone Season allowance allocations. (a) By October 31, 2006, the permitting authority...

40 CFR 96.360 - Submission of CAIR NOX Ozone Season allowance transfers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Submission of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Transfers § 96.360 Submission of CAIR NOX Ozone Season allowance transfers. A CAIR authorized account representative seeking recordation of a CAIR...

40 CFR 96.341 - Timing requirements for CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Timing requirements for CAIR NOX Ozone... PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.341 Timing requirements for CAIR NOX Ozone Season allowance allocations. (a) By October 31, 2006, the permitting authority...

40 CFR 96.353 - Recordation of CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false Recordation of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.353 Recordation of CAIR NOX Ozone Season allowance allocations. (a) By September 30, 2007, the Administrator will record in...

40 CFR 96.353 - Recordation of CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false Recordation of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.353 Recordation of CAIR NOX Ozone Season allowance allocations. (a) By September 30, 2007, the Administrator will record in...

40 CFR 96.341 - Timing requirements for CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Timing requirements for CAIR NOX Ozone... PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.341 Timing requirements for CAIR NOX Ozone Season allowance allocations. (a) By October 31, 2006, the permitting authority...

40 CFR 96.353 - Recordation of CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Recordation of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.353 Recordation of CAIR NOX Ozone Season allowance allocations. (a) By September 30, 2007, the Administrator will record in...

40 CFR 96.353 - Recordation of CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Recordation of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.353 Recordation of CAIR NOX Ozone Season allowance allocations. (a) By September 30, 2007, the Administrator will record in...

40 CFR 96.360 - Submission of CAIR NOX Ozone Season allowance transfers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false Submission of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Transfers § 96.360 Submission of CAIR NOX Ozone Season allowance transfers. A CAIR authorized account representative seeking recordation of a CAIR...

40 CFR 96.353 - Recordation of CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false Recordation of CAIR NOX Ozone Season... STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Tracking System § 96.353 Recordation of CAIR NOX Ozone Season allowance allocations. (a) By September 30, 2007, the Administrator will record in...

77 FR 6016 - Approval and Promulgation of Implementation Plans; State of Tennessee: Prevention of Significant...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-07

..., and extreme nonattainment (NAA) classifications) and significant emission rates for the 8-hour ozone..., serious, severe, and extreme ozone NAA. \\4\\ On July 18, 1997, EPA promulgated a revised 8-hour ozone NAAQS...

77 FR 35862 - Approval and Promulgation of Implementation Plans; State of Florida: New Source; Review...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-15

... Resource Management, to EPA in two separate SIP revisions on October 19, 2007, and July 1, 2011. These SIP...) Implementation Rule NSR Update Phase II (hereafter referred to as the ``Ozone Implementation NSR Update'' or ``Phase II Rule'') recognizing nitrogen oxide (NO X ) as an ozone precursor, among other requirements. In...

76 FR 28195 - Approval and Promulgation of Air Quality Implementation Plans; New Mexico; Sunland Park 1-Hour...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-16

... Promulgation of Air Quality Implementation Plans; New Mexico; Sunland Park 1-Hour Ozone Maintenance Plan AGENCY... the New Mexico State Implementation Plan (SIP). The revision consists of a maintenance plan for Sunland Park, New Mexico developed to ensure continued attainment of the 8-hour ozone National Ambient Air...

Air Emissions Inventory Guidance for Implementation of Ozone and Particulate Matter NAAQS and Regional Haze Regulations

EPA Pesticide Factsheets

Guidance document on how to develop emission inventories to meet State Implementation Plan requirements for complying with the 8-hour ozone national ambient air quality standards (NAAQS), the revised particulate matter (PM) NAAQS, and the regional haze reg

Using Source Apportionment to Evaluate the Cross State Transport of Ozone in the Eastern United States

NASA Astrophysics Data System (ADS)

Goldberg, D. L.; Canty, T. P.; Hembeck, L.; Vinciguerra, T.; Carpenter, S. F.; Anderson, D. C.; Salawitch, R. J.; Dickerson, R. R.

2014-12-01

The amount of air pollution crossing state lines has great policy implications. Using the ozone source apportionment tool (OSAT) in the Comprehensive Air-Quality Model with Extensions (CAMx) version 6.10, we can quantify how much ozone is generated locally versus transported from upwind locations. Initial results show that up to 70% of the surface ozone in Maryland during poor air quality days in the summer of July 2011 can be attributed to pollution from outside of the state's borders. Modifications to the CB05 gas-phase chemistry mechanism, supported by literature recommendations and improve agreement with NASA's DISCOVER-AQ Maryland aircraft campaign, can further increase this percentage. Additionally, we show the role of upwind sources and background ozone has become increasingly important as local emissions of ozone precursors continue to drop, starting with the steep reductions imposed in 2002 in response to Maryland's State Implementation Plan submitted to EPA. This study suggests future efforts to control surface ozone must include a meaningful strategy for dealing with cross-state transport of ozone precursors.

40 CFR 96.320 - General CAIR NOX Ozone Season Trading Program permit requirements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false General CAIR NOX Ozone Season Trading... PROGRAMS FOR STATE IMPLEMENTATION PLANS Permits § 96.320 General CAIR NOX Ozone Season Trading Program permit requirements. (a) For each CAIR NOX Ozone Season source required to have a title V operating...

40 CFR 96.320 - General CAIR NOX Ozone Season Trading Program permit requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false General CAIR NOX Ozone Season Trading... PROGRAMS FOR STATE IMPLEMENTATION PLANS Permits § 96.320 General CAIR NOX Ozone Season Trading Program permit requirements. (a) For each CAIR NOX Ozone Season source required to have a title V operating...

40 CFR 96.320 - General CAIR NOX Ozone Season Trading Program permit requirements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false General CAIR NOX Ozone Season Trading... PROGRAMS FOR STATE IMPLEMENTATION PLANS Permits § 96.320 General CAIR NOX Ozone Season Trading Program permit requirements. (a) For each CAIR NOX Ozone Season source required to have a title V operating...

40 CFR 96.320 - General CAIR NOX Ozone Season Trading Program permit requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false General CAIR NOX Ozone Season Trading... PROGRAMS FOR STATE IMPLEMENTATION PLANS Permits § 96.320 General CAIR NOX Ozone Season Trading Program permit requirements. (a) For each CAIR NOX Ozone Season source required to have a title V operating...

40 CFR 96.320 - General CAIR NOX Ozone Season Trading Program permit requirements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false General CAIR NOX Ozone Season Trading... PROGRAMS FOR STATE IMPLEMENTATION PLANS Permits § 96.320 General CAIR NOX Ozone Season Trading Program permit requirements. (a) For each CAIR NOX Ozone Season source required to have a title V operating...

"OZONE SOURCE APPORTIONMENT IN CMAQ' | Science ...

EPA Pesticide Factsheets

Ozone source attribution has been used to support various policy purposes including interstate transport (Cross State Air Pollution Rule) by U.S. EPA and ozone nonattainment area designations by State agencies. Common scientific applications include tracking intercontinental transport of ozone and ozone precursors and delineating anthropogenic and non-anthropogenic contribution to ozone in North America. As in the public release due in September 2013, CMAQ’s Integrated Source Apportionment Method (ISAM) attributes PM EC/OC, sulfate, nitrate, ammonium, ozone and its precursors NOx and VOC, to sectors/regions of users’ interest. Although the peroxide-to-nitric acid productions ratio has been the most common indicator to distinguish NOx-limited ozone production from VOC-limited one, other indicators are implemented in addition to allowing for an ensemble decision based on a total of 9 available indicator ratios. Moreover, an alternative approach of ozone attribution based on the idea of chemical sensitivity in a linearized system that has formed the basis of chemical treatment in forward DDM/backward adjoint tools has been implemented in CMAQ. This method does not require categorization into either ozone regime. In this study, ISAM will simulate the 2010 North America ozone using all of the above gas-phase attribution methods. The results are to be compared with zero-out difference out of those sectors in the host model runs. In addition, ozone contribution wil

SBAR Panel: Phase I Federal Implementation Plans (FIPs) To Reduce the Regional Transport of Ozone in the Eastern United States

EPA Pesticide Factsheets

SBAR panel on regional reductions of nitrogen oxides, with focus on the windborne transport of ozone smog and nitrogen oxides from NOx-producing sources in 22 eastern states and the District of Columbia

75 FR 48582 - Approval and Promulgation of Implementation Plans and Operating Permits Program; State of Nebraska

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-11

... the basis that these compounds make a negligible contribution to tropospheric ozone formation. These... has a negligible contribution to tropospheric ozone formation, and need not be considered in..., Incorporation by reference, Intergovernmental relations, Nitrogen dioxide, Ozone, Particulate matter, Reporting...

76 FR 41100 - Approval and Promulgation of Implementation Plans; Alabama; 110(a)(1) and (2) Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-13

...EPA is taking final action to approve the December 10, 2007, submission by the State of Alabama, through the Alabama Department of Environmental Management (ADEM) as demonstrating that the State meets the state implementation plan (SIP) requirements of sections 110(a)(1) and (2) of the Clean Air Act (CAA or the Act) for the 1997 8-hour ozone national ambient air quality standards (NAAQS). Section 110(a) of the CAA requires that each state adopt and submit a SIP for the implementation, maintenance, and enforcement of each NAAQS promulgated by the EPA, which is commonly referred to as an ``infrastructure'' SIP. Alabama certified that the Alabama SIP contains provisions that ensure the 1997 8-hour ozone NAAQS is implemented, enforced, and maintained in Alabama (hereafter referred to as ``infrastructure submission''). Alabama's infrastructure submission, provided to EPA on December 10, 2007, addressed all the required infrastructure elements for the 1997 8-hour ozone NAAQS. Additionally, EPA is responding to adverse comments received on EPA's March 17, 2011, proposed approval of Alabama's December 10, 2007, infrastructure submission.

Documents for SBAR Panel: Phase I Federal Implementation Plans (FIPs) To Reduce the Regional Transport of Ozone in the Eastern United States

EPA Pesticide Factsheets

SBAR panel on regional reductions of nitrogen oxides, with focus on the windborne transport of ozone smog and nitrogen oxides from NOx-producing sources in 22 eastern states and the District of Columbia

77 FR 6727 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-09

... for Redesignation of Ozone and Carbon Monoxide Nonattainment Areas,'' Memorandum from G.T. Helms... Carbon Monoxide (CO) Redesignations,'' Memorandum from G.T. Helms, Chief, Ozone/Carbon Monoxide Programs...,'' Memorandum from G.T. Helms, Chief, Ozone/Carbon Monoxide Programs Branch, August 17, 1993; ``State...

77 FR 47530 - Approval and Promulgation of State Implementation Plans; Hawaii; Infrastructure Requirements for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-09

... Promulgation of State Implementation Plans; Hawaii; Infrastructure Requirements for the 1997 8-Hour Ozone and... State Implementation Plan (SIP) revision submitted by the state of Hawaii pursuant to the requirements... FURTHER INFORMATION CONTACT: Dawn Richmond, Air Planning Office (AIR-2), U.S. Environmental Protection...

75 FR 61369 - Revisions to the California State Implementation Plan; Sacramento Metropolitan Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-05

... the California State Implementation Plan; Sacramento Metropolitan Air Quality Management District... approve a revision to the Sacramento Metropolitan Air Quality Management District's portion of the... Metropolitan Air Quality Management District (SMAQMD) adopted the ``Ozone State Implementation Plan Revision...

Federal Implementation Plans for Iowa, Kansas, Michigan, Missouri, Oklahoma, and Wisconsin To Reduce Interstate Transport of Ozone (76 FR 40662)

EPA Pesticide Factsheets

EPA provides an opportunity for public comment on our conclusion that emissions from six states significantly contribute to downwind nonattainment or interfere with maintenance of the 1997 ozone National Ambient Air Quality Standards in other states.

Memorandum: Status of 110(a)(2)(D)(i)(I) SIPs for the 2008 Ozone NAAQS

EPA Pesticide Factsheets

This document describes the status of each Clean Air Act (CAA) section 110(a)(2)(D)(i)(I) state implementation plan (SIP) for the 2008 ozone NAAQS for the eastern states and the District of Columbia that are the focus of the final rule.

Ozone Control Strategies | Ground-level Ozone | New ...

EPA Pesticide Factsheets

2017-09-05

The Air Quality Planning Unit's primary goal is to protect your right to breathe clean air. Guided by the Clean Air Act, we work collaboratively with states, communities, and businesses to develop and implement strategies to reduce air pollution from a variety of sources that contribute to the ground-level ozone or smog problem.

76 FR 17801 - Approval and Promulgation of Implementation Plans; New York Reasonable Further Progress Plans...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-31

... the State's Attainment Demonstration SIP In 1997, EPA revised the health-based NAAQS for ozone... scientific evidence demonstrating that ozone causes adverse health effects at lower ozone concentrations and.... EPA determined that the 8-hour standard would be more protective of human health, especially with...

Finding of Failure to Submit State Implementation Plans for the 2008 Ozone National Ambient Air Quality Standard (NAAQS)

EPA Pesticide Factsheets

On November 29, 2017 the U.S. Environmental Protection Agency (EPA) found that three states failed to submit timely state implementation plan (SIP) revisions necessary to satisfy certain Clean Air Act (CAA) and EPA requirements for implementing the 2008 oz

Ozone: Stage Two Vapor Recovery Rule and Guidance

EPA Pesticide Factsheets

This page includes the guidance document, fact sheet, memorandum, and final rule on removing Stage II Gasoline Vapor Control Programs from State Implementation Plans (SIP) for the Ozone National Ambient Air Quality Standards (NAAQS)

LINKING CHANGES IN UTILITY NO X EMISSIONS TO CHANGE IN OZONE AIR QUALITY

EPA Science Inventory

The NO_x State Implementation Plan (SIP) Call was designed to reduce Northeastern U.S. NO_x emissions from utilities. With these reductions, it was anticipated that the amount of ozone attributed to transport from other states would in turn be reduced. In th...

76 FR 41123 - Approval and Promulgation of Implementation Plans; Mississippi; 110(a)(1) and (2) Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-13

...EPA is taking final action to approve the December 7, 2007, submission by the State of Mississippi, through the Mississippi Department of Environmental Quality (MDEQ) as demonstrating that the State meets the implementation plan (SIP) requirements of sections 110(a)(1) and (2) of the Clean Air Act (CAA or the Act) for the 1997 8- hour ozone national ambient air quality standards (NAAQS). Section 110(a) of the CAA requires that each state adopt and submit a SIP for the implementation, maintenance, and enforcement of each NAAQS promulgated by the EPA, which is commonly referred to as an ``infrastructure'' SIP. Mississippi certified that the Mississippi SIP contains provisions that ensure the 1997 8-hour ozone NAAQS is implemented, enforced, and maintained in Mississippi (hereafter referred to as ``infrastructure submission''). Mississippi's infrastructure submission, provided to EPA on December 7, 2007, addressed all the required infrastructure elements for the 1997 8-hour ozone NAAQS. Additionally, EPA is responding to adverse comments received on EPA's March 17, 2011, proposed approval of Mississippi's December 7, 2007, infrastructure submission.

76 FR 41111 - Approval and Promulgation of Implementation Plans; South Carolina; 110(a)(1) and (2...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-13

...EPA is taking final action to approve the December 13, 2007, submission submitted by the State of South Carolina, through the South Carolina Department of Health and Environmental Control (SC DHEC) as demonstrating that the State meets the state implementation plan (SIP) requirements of sections 110(a)(1) and (2) of the Clean Air Act (CAA or the Act) for the 1997 8-hour ozone national ambient air quality standards (NAAQS). Section 110(a) of the CAA requires that each state adopt and submit a SIP for the implementation, maintenance, and enforcement of each NAAQS promulgated by the EPA, which is commonly referred to as an ``infrastructure'' SIP. South Carolina certified that the South Carolina SIP contains provisions that ensure the 1997 8-hour ozone NAAQS is implemented, enforced, and maintained in South Carolina (hereafter referred to as ``infrastructure submission''). South Carolina's infrastructure submission, provided to EPA on December 13, 2007, addressed all the required infrastructure elements for the 1997 8-hour ozone NAAQS. Additionally, EPA is correcting an inadvertent error and responding to adverse comments received on EPA's March 17, 2011, proposed approval of South Carolina's December 13, 2007, infrastructure submission.

77 FR 50021 - Revisions to the California State Implementation Plan, San Joaquin Valley Unified Air Pollution...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-20

..., such as owners of mobile sources that also contribute to ozone formation. EPA also believes that... percent of the ozone precursor emissions, while mobile sources are responsible for approximately 80...

Zone trends for three metropolitan statistical areas in North Carolina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oommen, R.G.; Aneja, V.P.; Riordan, A.J.

1996-12-31

As part of an effort by the state of North Carolina to develop a State Implementation Plan (SIP) for ozone control, a network of ozone stations was established to monitor ozone concentrations across the state. Approximately twenty-five ozone stations made continuous measurements surrounding the three major Metropolitan Statistical Areas (MSAs) between 1993-1995: Raleigh/Durham (RDU), Charlotte/Mecklenburg (CLT), and Greensboro/Winston-Salem/High Point (GSO). Statistical Averages on the ozone data were performed at each MSA to study trends and/or relationships on high ozone days. It was found that the three MSAs were not significantly different to each other, indicating they fall under the samemore » synoptic weather patterns, Transport and local production of biogenic sources of VOCs and NO{sub x} appear to play an important role for high ozone downwind at RDU, while mobile sources of these precursor gases contribute to the high ozone downwind of CLT and GSO. A {delta}(O{sub 3}) analysis (difference between the O{sub 3} measured at an upwind and downwind site) suggested that long-range transport of the precursors was a significant contribution for ozone problems at the three MSAs. 15 refs., 2 figs., 2 tabs.« less

76 FR 11190 - Approval and Promulgation of Implementation Plans; State of Missouri

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-01

... the state of Missouri to add two new rules which implement restrictions on the idling of heavy duty diesel vehicles in the Kansas City Metropolitan Area and in the St. Louis Ozone Nonattainment Area. EPA...

Modeling Analyses of the Effects of Changes in Nitrogen Oxides Emission from the Electric Power Sector on Ozone Levels in the Eastern United States

EPA Science Inventory

This modeling study tests a hypothetical scenario to see what air quality might have looked like if no emission controls had been placed on electric generating units, as required by the NOx State Implementation Plan (SIP) Call required in 2004. Results showed that ozone levels w...

Ozone Implementation Regulatory Actions

EPA Pesticide Factsheets

Training courses, presentations, and other resources to help state and local air professionals learn more about NAAQS implementation, air pollution control and emissions reduction, SIP development, and public participation.

78 FR 37757 - Revisions to the California State Implementation Plan, South Coast Air Quality Management District

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-24

... the California State Implementation Plan, South Coast Air Quality Management District AGENCY... the South Coast Air Quality Management District (SCAQMD) portion of the California State... Quality Index rather than on 1-hour ozone forecasted values; (b) forecast criteria for allowing a...

75 FR 56928 - Approval and Promulgation of State Implementation Plan Revisions; State of North Dakota...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-17

... typical movement of weather systems. Thus, geography, topography and meteorology of the region that... obstacles to ozone transport from North Dakota to California. Thus, geography and topography reduce the... proposing partial approval of the State Implementation Plan (SIP) revisions called ``Interstate Transport of...

76 FR 41088 - Approval and Promulgation of Implementation Plans; Kentucky; 110(a)(1) and (2) Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-13

...EPA is taking final action to approve the December 13, 2007, submission by the Commonwealth of Kentucky, through the Kentucky Division of Air Quality (KDAQ) as demonstrating that the Commonwealth meets the state implementation plan (SIP) requirements of sections 110(a)(1) and (2) of the Clean Air Act (CAA or the Act) for the 1997 8- hour ozone national ambient air quality standards (NAAQS). Section 110(a) of the CAA requires that each state adopt and submit a SIP for the implementation, maintenance, and enforcement of each NAAQS promulgated by the EPA, which is commonly referred to as an ``infrastructure'' SIP. Kentucky certified that the Kentucky SIP contains provisions that ensure the 1997 8-hour ozone NAAQS is implemented, enforced, and maintained in Kentucky (hereafter referred to as ``infrastructure submission''). Kentucky's infrastructure submission, provided to EPA on December 13, 2007, addressed all the required infrastructure elements for the 1997 8-hour ozone NAAQS. Additionally, EPA is responding to adverse comments received on EPA's March 17, 2011, proposed approval of Kentucky's December 13, 2007, infrastructure submission.

State Implementation Plan (SIP) Checklist Guide

EPA Pesticide Factsheets

Guidance documents and examples to assist air quality agencies of non-attainment areas in developing plans to implement national ambient air quality standards (NAAQS), including the ground-level ozone standard.

Federal Implementation Plans: Interstate Transport of Fine Particulate Matter and Ozone and Correction of SIP Approvals (76 FR 48208)

EPA Pesticide Factsheets

In this action, EPA limits the interstate transport of emissions of nitrogen oxides (NOX) and sulfur dioxide (SO2) that contribute to harmful levels of fine particle matter (PM2.5) and ozone in downwind states.

75 FR 24944 - Adequacy Status of the Milwaukee-Racine, Door County, Manitowoc County, and Sheboygan County...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-06

... a State Implementation Plan (SIP) means that transportation activities will not produce new air... Ozone Redesignation and Maintenance Plans for Transportation Conformity Purposes AGENCY: Environmental... Sheboygan County, Wisconsin ozone nonattainment areas are adequate for use in transportation conformity...

Federal Implementation Plans for Iowa, Michigan, Missouri, Oklahoma, and Wisconsin and Determination for Kansas Regarding Interstate Transport of Ozone (76 FR 80760)

EPA Pesticide Factsheets

EPA concludes that emissions from Iowa, Kansas, Michigan, Missouri, Oklahoma, and Wisconsin significantly contribute to downwind nonattainment or interfere with maintenance of the 1997 ozone National Ambient Air Quality Standards (NAAQS) in other states.

Report: Differences in Processing Practices Could Decrease the Reliability of Ozone Data Used for Assessing Air Quality to Protect Public Health

EPA Pesticide Factsheets

Report #18-P-0105, February 28, 2018. There is a risk that the state, local and tribal agencies that monitor ambient air quality are not always implementing the EPA’s recommended QA practices for validating ozone data.

75 FR 45082 - Revisions to the California State Implementation Plan, Santa Barbara County Air Pollution Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-02

... the California State Implementation Plan, Santa Barbara County Air Pollution Control District AGENCY... limited disapproval of revisions to the Santa Barbara County Air Pollution Control District (SBCAPCD... Environmental protection, Air pollution control, Intergovernmental relations, Nitrogen dioxide, Ozone, Reporting...

77 FR 5709 - Revisions to the California State Implementation Plan, San Joaquin Valley Unified Air Pollution...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-06

... the California State Implementation Plan, San Joaquin Valley Unified Air Pollution Control District... revisions to the San Joaquin Valley Unified Air Pollution Control District (SJVUAPCD) portion of the... pollution control, Incorporation by reference, Intergovernmental relations, Nitrogen dioxide, Ozone...

76 FR 33181 - Revisions to the California State Implementation Plan, San Joaquin Valley Unified Air Pollution...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-08

... the California State Implementation Plan, San Joaquin Valley Unified Air Pollution Control District... approve a revision to the San Joaquin Valley Unified Air Pollution Control District (SJVUAPCD) portion of..., Air pollution control, Intergovernmental relations, Ozone, Reporting and recordkeeping requirements...

Status of Clean Air Act (CAA) 110(a)(2)(D)(i)(I) SIPs Final Rule TSD

EPA Pesticide Factsheets

This document describes, for each state subject to a Federal implementation plan (FIP) with respect to ozone and/or PM2.5 NAAQS under the Transport Rule, the status of each Clean Air Act state implementation plan (SIP) for the relevant NAAQS.

78 FR 34177 - Implementation of the 2008 National Ambient Air Quality Standards for Ozone: State Implementation...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-06

... evaluating control strategies. This better understanding allows for more strategic approaches in which public..., we lay out our proposed approaches, but here are a few examples: 1. Federal control measures: States...), reasonably available control technology (RACT), reasonably available control measures (RACM), new source...

76 FR 17585 - Approval and Promulgation of Implementation Plans; State of Missouri

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-30

... 1997 revisions to the National Ambient Air Quality Standards (NAAQS) for ozone. Section 110(a)(1... modeling to assure attainment and maintenance of the applicable standards. By statute, SIPs meeting the... ozone and PM 2.5 NAAQS.\\1\\ EPA will address these elements below under the following headings: (A...

Estimating North American background ozone in U.S. surface air with two independent global models: Variability, uncertainties, and recommendations

EPA Science Inventory

Accurate estimates for North American background (NAB) ozone (O3) in surface air over the United States are needed for setting and implementing an attainable national O3 standard. These estimates rely on simulations with atmospheric chemistry-transport models that set North Amer...

77 FR 28423 - Final Rule To Implement the 1997 8-Hour Ozone National Ambient Air Quality Standard...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-14

...The EPA is revising the rules for implementing the 1997 8-hour ozone national ambient air quality standards (NAAQS) to address certain limited portions of the rules vacated by the U.S. Court of Appeals for the District of Columbia Circuit. This final rule assigns Clean Air Act (CAA or Act) classifications and associated state planning and control requirements to selected ozone nonattainment areas. This final rule also addresses three vacated provisions of the 1997 8-hour NAAQS--Phase 1 Implementation Rule (April 30, 2004) that provided exemptions from the anti-backsliding requirements relating to nonattainment area New Source Review (NSR), CAA section 185 penalty fees, and contingency measures, as these three requirements applied for the 1-hour standard. This rule also reinstates the 1-hour contingency measures as applicable requirements that must be retained until the area attains the 1997 8- hour ozone standard. Finally, this rule deletes an obsolete provision that stayed the EPA's authority to revoke the 1-hour ozone standard pending the Agency's issuance of a final rule that revises or reinstates its revocation authority and considers and addresses certain other issues. That rule has now been issued.

78 FR 28744 - Approval and Promulgation of Implementation Plans; Georgia; State Implementation Plan...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-16

... update the Georgia SIP to reflect EPA's current national ambient air quality standards (NAAQS) for sulfur...'s rules identifying the current NAAQS table for sulfur dioxide, nitrogen dioxide, ozone, lead and... separate action. II. Analysis of the State's Submittal a. Sulfur Dioxide On June 22, 2010, EPA revised the...

The Use of Regulatory Air Quality Models to Develop Successful Ozone Attainment Strategies

NASA Astrophysics Data System (ADS)

Canty, T. P.; Salawitch, R. J.; Dickerson, R. R.; Ring, A.; Goldberg, D. L.; He, H.; Anderson, D. C.; Vinciguerra, T.

2015-12-01

The Environmental Protection Agency (EPA) recently proposed lowering the 8-hr ozone standard to between 65-70 ppb. Not all regions of the U.S. are in attainment of the current 75 ppb standard and it is expected that many regions currently in attainment will not meet the future, lower surface ozone standard. Ozone production is a nonlinear function of emissions, biological processes, and weather. Federal and state agencies rely on regulatory air quality models such as the Community Multi-Scale Air Quality (CMAQ) model and Comprehensive Air Quality Model with Extensions (CAMx) to test ozone precursor emission reduction strategies that will bring states into compliance with the National Ambient Air Quality Standards (NAAQS). We will describe various model scenarios that simulate how future limits on emission of ozone precursors (i.e. NOx and VOCs) from sources such as power plants and vehicles will affect air quality. These scenarios are currently being developed by states required to submit a State Implementation Plan to the EPA. Projections from these future case scenarios suggest that strategies intended to control local ozone may also bring upwind states into attainment of the new NAAQS. Ground based, aircraft, and satellite observations are used to ensure that air quality models accurately represent photochemical processes within the troposphere. We will highlight some of the improvements made to the CMAQ and CAMx model framework based on our analysis of NASA observations obtained by the OMI instrument on the Aura satellite and by the DISCOVER-AQ field campaign.

California State Implementation Plan; Final Approval of Revision; Yolo-Solano Air Quality Management District; Reasonably Available Control Technology Requirements for 1997 8-hour Ozone NAAQS

EPA Pesticide Factsheets

EPA is taking final action to approve a revision to the Yolo-Solano Air Quality Management District (YSAQMD) portion of the California SIP concerning YSAQMD regarding RACT)requirements the 1997 8-hour ozone NAAQS and approve negative declarations into SIP.

77 FR 35287 - Approval and Promulgation of Air Quality Implementation Plans; Virginia; Regional Haze State...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-13

... meeting the infrastructure requirements relating to visibility protection for the 1997 8-hour ozone...)(i)(II) and 110 (a)(2)(J), relating to visibility protection for the 1997 8-hour ozone NAAQS and the... Regional Haze SIP cannot lawfully discharge or restart the clock on a FIP obligation because EPA is already...

76 FR 43898 - Approval and Promulgation of State Implementation Plan Revisions; Infrastructure Requirements for...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-22

...: The commenter supported EPA's efforts to require ozone monitoring in Utah's Uinta Basin. However, the... air quality in the basin is not in compliance with the ozone standard,'' to designate the Uinta Basin... commenter refers to. For a discussion of other monitoring data in the Uinta Basin, see the response to...

75 FR 72695 - Approval and Promulgation of Implementation Plans; Oklahoma; State Implementation Plan Revisions...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-26

... chemical reactions in the atmosphere. The level of impact a new source can have on ozone levels is... condensing outside the stack or through chemical reactions with pollutants already in the atmosphere...

77 FR 59356 - Approval and Promulgation of Implementation Plans; North Carolina: Approval of Rocky Mount...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-27

... Promulgation of Implementation Plans; North Carolina: Approval of Rocky Mount Supplemental Motor Vehicle... is proposing to approve a revision to the North Carolina State Implementation Plan (SIP), submitted... supplements the original redesignation request and maintenance plan for Rocky Mount 1997 8-hour ozone area...

75 FR 72954 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Ohio Portion of the...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-29

... maintenance plan revision on July 6, 2010. The submittal contained revisions to 2015 and 2020 NO X point... (SIP), the States' plans for maintaining the 8-hour ozone NAAQS through 2020 in the area. The Ohio and Indiana plans demonstrated maintenance of the 8-hour ozone standard through 2020 by showing that current...

75 FR 71029 - Approval and Promulgation of State Implementation Plans; State of Colorado; Interstate Transport...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-22

... variability in emissions and/ or meteorology), may have difficulty maintaining the standard. As explained in... year with particularly severe meteorology (weather that is conducive to ozone and/or particulate...

Region 9: California Adequate / Inadequate Letter Attachment (5/30/2008)

EPA Pesticide Factsheets

This is a document that states that it has been found adequate for transportation conformitypurposes certain 8-hour ozone and PM2.5 motor vehicleemissions budgets in the 2007 South Coast StateImplementation Plan.

77 FR 6711 - Approval and Promulgation of Implementation Plans; Arkansas; Infrastructure Requirements for the...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-09

...EPA is proposing to partially approve and partially disapprove submittals from the state of Arkansas pursuant to the Clean Air Act (CAA or Act) that address the infrastructure elements specified in the CAA section 110(a)(2), necessary to implement, maintain, and enforce the 1997 8-hour ozone and the 1997 and 2006 fine particulate matter (PM2.5) national ambient air quality standards (NAAQS or standards). We are proposing to find that the current Arkansas State Implementation Plan (SIP) meets the following infrastructure elements for the 1997 8-hour ozone NAAQS and the 1997 and 2006 PM2.5 NAAQS: 110(a)(2)(A), (B), (E), (F), (G), (H), (K), (L), (M), and portions of (C), (D)(ii) and (J). We are proposing to find that the current Arkansas SIP does not meet the infrastructure requirements for the 1997 8-hour ozone NAAQS and the 1997 and 2006 PM2.5 NAAQS at 110(a)(2) for portions of (C), (D)(ii), and (J) because the EPA-approved SIP prevention of significant deterioration (PSD) program does not apply to greenhouse gas (GHG) emitting sources. We also are proposing to find that the current Arkansas SIP does not meet the infrastructure requirements for the 1997 and 2006 PM2.5 NAAQS at 110(a)(2) for portions of (C), (D)(ii), and (J) because Arkansas has not submitted the PSD SIP revision required by EPA's Implementation of the New Source Review (NSR) Program for Particulate Matter Less Than 2.5 Micrometers (73 FR 28321, May 16, 2008). Further, we are proposing to partially approve and partially disapprove the provisions of SIP submissions that emissions from sources in Arkansas do not interfere with measures required in the SIP of any other state under part C of the CAA to prevent significant deterioration of air quality, with regard to the 1997 8-hour ozone NAAQS and the 2006 PM2.5 NAAQS. The partial disapprovals herein are because Arkansas cannot issue permits for GHG emissions and because the State did not submit the required PM2.5 PSD SIP revision. Finally, for purposes of the 1997 8-hour ozone NAAQS, EPA is proposing to approve SIP revisions that modify the Arkansas PSD SIP to include nitrogen oxides (NOX) as an ozone precursor. This action is being taken under section 110 and part C of the Act. Finally, EPA is also proposing to make a correction to the attainment status table in 40 CFR 81.304 to accurately reflect the redesignation date of Crittenden County, Arkansas to attainment for the 1997 8-hour ozone standard.

76 FR 8736 - Status of Motor Vehicle Budgets in Submitted State Implementation Plan for Transportation...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-15

...EPA is notifying the public that EPA has withdrawn its previous adequacy finding on the 2012 motor vehicle emission budgets (MVEBs) for Connecticut's two 8-hour ozone nonattainment areas. EPA has withdrawn the adequacy finding because Connecticut Department of Environmental Protection (CT DEP) withdrew its 2012 motor vehicle emission budgets from its eight-hour ozone attainment demonstration SIP for both ozone nonattainment areas. As a result of our finding, Connecticut can not use these 2012 motor vehicle emission budgets for future conformity determinations.

40 CFR 96.340 - State trading budgets.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false State trading budgets. 96.340 Section...) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.340 State trading budgets. (a) Except as provided in...

40 CFR 96.340 - State trading budgets.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false State trading budgets. 96.340 Section...) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.340 State trading budgets. (a) Except as provided in...

40 CFR 96.340 - State trading budgets.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false State trading budgets. 96.340 Section...) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO 2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.340 State trading budgets. (a) Except as provided in...

40 CFR 96.340 - State trading budgets.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false State trading budgets. 96.340 Section...) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.340 State trading budgets. (a) Except as provided in...

40 CFR 96.340 - State trading budgets.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false State trading budgets. 96.340 Section...) NOX BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS FOR STATE IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.340 State trading budgets. (a) Except as provided in...

76 FR 19292 - Approval and Promulgation of Implementation Plans; Oregon; Interstate Transport of Pollution...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-07

...EPA is proposing to approve a portion of the State Implementation Plan (SIP) revision submitted by the State of Oregon for the purpose of addressing the interstate transport provisions of Clean Air Act (CAA) section 110(a)(2)(D)(i)(I) for the 1997 8-hour ozone National Ambient Air Quality Standards (NAAQS or standards) and the 1997 fine particulate matter (PM2.5) NAAQS. Section 110(a)(2)(D)(i) of the CAA requires that each State have adequate provisions to prohibit air emissions from adversely affecting air quality in other States through interstate transport. EPA is proposing to approve Oregon's SIP revision for the 1997 8-hour ozone and 1997 PM2.5 NAAQS as meeting the requirements of CAA section 110(a)(2)(D)(i)(I) to prohibit emissions that will contribute significantly to nonattainment of the these standards in any other State and to prohibit emissions that will interfere with maintenance of these standards by any other State.

78 FR 16826 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Cleveland-Akron-Lorain and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-19

...-9790-1] Approval and Promulgation of Air Quality Implementation Plans; Ohio; Cleveland-Akron-Lorain and Columbus 1997 8-Hour Ozone Maintenance Plan Revisions to Approved Motor Vehicle Emissions Budgets AGENCY... quality State Implementation Plans (SIPs) under the Clean Air Act to replace the previously approved motor...

75 FR 48894 - Approval and Promulgation of Air Quality Implementation Plans; New Mexico; Revisions to Emissions...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-12

... Promulgation of Air Quality Implementation Plans; New Mexico; Revisions to Emissions Inventory Reporting.... SUMMARY: The EPA is proposing to approve revisions to the New Mexico State Implementation Plan (SIP... Quality Standards that EPA has established for criteria pollutants such as ozone, particulate matter, and...

76 FR 24372 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Update to Materials...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-02

... Emissions From Industrial Process Operations New Castle County.'' 12. Regulation 1112 ``Control of Nitrogen... the State Implementation Plans.'' 25. Regulation 1139 ``Nitrogen Oxides (NO X ) Budget Trading Program... by reference, Intergovernmental relations, Lead, Nitrogen dioxide, Ozone, Particulate matter...

Rulemaking to Affirm Interim Amendments to Dates in Federal Implementation Plans Addressing Interstate Transport of Ozone and Fine Particulate Matter (81 FR 13275)

EPA Pesticide Factsheets

This rulemaking affirms and makes permanent certain amendments previously made on an interim basis to the Code of Federal Regulations (CFR) provisions implementing the Cross-State Air Pollution Rule (CSAPR).

78 FR 21302 - Approval and Promulgation of Implementation Plans; New York State Ozone Implementation Plan Revision

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-10

... in Subpart 212.1, ``A burner designed to reduce flame turbulence by the mixing of fuel and air and by... Pavement and Asphalt Based Surface Coating,'' (see 77 FR 13974). Specifically, New York made amendments to...

State Implementation Plans: Related Resources

EPA Pesticide Factsheets

Guidance, strategies and links are offered for reducing vehicle air pollution, including ozone or smog-forming pollutants, particulate matter and other emissions that pose public health and air quality concerns.

Parameterizing the impacts of ozone-vegetation coupling and feedbacks on ozone air quality in a chemical transport model

NASA Astrophysics Data System (ADS)

Zhou, S.; Tai, A. P. K.; Lombardozzi, D.

2016-12-01

Apart from being an important greenhouse gas, tropospheric ozone is a significant air pollutant that is shown to have harmful effects both on human health and vegetation. Ozone damages vegetation mainly through reducing plant photosynthesis and stomatal conductance. Meanwhile, ozone is also strongly dependent on vegetation via various biogeochemical and physical processes. These interdependences between ozone and vegetation would constitute feedback mechanisms that can potentially alter ozone concentration itself, and should be considered in future climate and air quality projections. In this study, we first implement an empirical scheme for ozone damage on vegetation in the Community Land Model (CLM), and simulate the relative changes in leaf area indices (LAI) and stomatal conductance for three plant groups (consolidated from 15 plant functional types) at various prescribed ozone levels (from 0 ppb to 100 ppb). We find that all plant groups suffer the greatest decreases in LAI and stomatal conductance in regions with their greatest abundance, and grasses and crops show the most severe damage from ozone exposure compared with broadleaf and needleleaf groups, with an LAI reduction of as much as 50% in some areas even at an ozone level of 30 ppb. Using the CLM-simulated results, we develop a semi-empirical parameterization scheme to link prescribed ozone levels to the spatially varying simulated relative changes in LAI and stomatal conductance at model steady state. We implement the scheme in the GEOS-Chem chemical transport model so that ozone-vegetation chemical coupling via ozone dry deposition and biogenic volatile organic compound (VOC) emissions can be simulated online. Model simulations indicate that ozone effect on stomatal conductance (which modifies dry deposition) appears to be the dominant feedback pathway influencing surface ozone, whereas ozone-mediated LAI changes (which affects biogenic VOC emissions) appear to play a lesser role. This work is the first attempt to account for online ozone-vegetation coupling in a chemical transport model, with important ramifications for more realistic assessment of ozone air quality under a constantly evolving climate and land cover.

75 FR 48566 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Administrative and Non...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-11

...''; Regulation 12 ``Control of Nitrogen Oxide Emissions''; Regulation 1113* ``Open Burning''; Regulation 14... of General Federal Actions to the State Implementation Plans''; Regulation 39 ``Nitrogen Oxides (NO X..., Intergovernmental relations, Nitrogen dioxide, Ozone, Particulate matter, Reporting and recordkeeping requirements...

78 FR 41846 - Approval and Promulgation of Implementation Plans; New York State Ozone Implementation Plan Revision

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-12

... production plants. These control requirements will be specifically aimed at reducing NO X emissions resulting... Environmental protection, Air pollution control, Hydrocarbons, Incorporation by reference, Intergovernmental..., ``Portland Cement Plants and Glass Plants,'' and Subpart 227-2, ``Reasonably Available Control Technology...

40 CFR 52.352 - Interstate transport.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Interstate transport. 52.352 Section 52...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Colorado § 52.352 Interstate transport. Addition to the Colorado State Implementation Plan of the Colorado Interstate Transport SIP regarding the 1997 8-Hour Ozone...

40 CFR 52.352 - Interstate transport.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Interstate transport. 52.352 Section 52...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Colorado § 52.352 Interstate transport. Addition to the Colorado State Implementation Plan of the Colorado Interstate Transport SIP regarding the 1997 8-Hour Ozone...

78 FR 53709 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-30

...] Approval and Promulgation of Air Quality Implementation Plans; Delaware; Infrastructure Requirements for the 2008 Ozone National Ambient Air Quality Standards AGENCY: Environmental Protection Agency (EPA... ambient air quality standards (NAAQS) are promulgated, the CAA requires states to submit a plan for the...

Regulatory ozone modeling: status, directions, and research needs.

PubMed Central

Georgopoulos, P G

1995-01-01

The Clean Air Act Amendments (CAAA) of 1990 have established selected comprehensive, three-dimensional, Photochemical Air Quality Simulation Models (PAQSMs) as the required regulatory tools for analyzing the urban and regional problem of high ambient ozone levels across the United States. These models are currently applied to study and establish strategies for meeting the National Ambient Air Quality Standard (NAAQS) for ozone in nonattainment areas; State Implementation Plans (SIPs) resulting from these efforts must be submitted to the U.S. Environmental Protection Agency (U.S. EPA) in November 1994. The following presentation provides an overview and discussion of the regulatory ozone modeling process and its implications. First, the PAQSM-based ozone attainment demonstration process is summarized in the framework of the 1994 SIPs. Then, following a brief overview of the representation of physical and chemical processes in PAQSMs, the essential attributes of standard modeling systems currently in regulatory use are presented in a nonmathematical, self-contained format, intended to provide a basic understanding of both model capabilities and limitations. The types of air quality, emission, and meteorological data needed for applying and evaluating PAQSMs are discussed, as well as the sources, availability, and limitations of existing databases. The issue of evaluating a model's performance in order to accept it as a tool for policy making is discussed, and various methodologies for implementing this objective are summarized. Selected interim results from diagnostic analyses, which are performed as a component of the regulatory ozone modeling process for the Philadelphia-New Jersey region, are also presented to provide some specific examples related to the general issues discussed in this work. Finally, research needs related to a) the evaluation and refinement of regulatory ozone modeling, b) the characterization of uncertainty in photochemical modeling, and c) the improvement of the model-based ozone-attainment demonstration process are presented to identify future directions in this area. Images Figure 7. Figure 7. Figure 7. Figure 8. Figure 9. PMID:7614934

OZONE MONITORING, MAPPING, AND PUBLIC OUTREACH ...

EPA Pesticide Factsheets

The U.S. EPA had developed a handbook to help state and local government officials implement ozone monitoring, mapping, and outreach programs. The handbook, called Ozone Monitoring, Mapping, and Public Outreach: Delivering Real-Time Ozone Information to Your Community, provides step-by-step instructions on how to: Design, site, operate, and maintain an ozone monitoring network. Install, configure, and operate the Automatic Data Transfer System Use MapGen software to create still-frame and animated ozone maps. Develop and outreach plan to communicate information about real-time ozone levels and their health effects to the public.This handbook was developed by EPA's EMPACT program. The program takes advantage of new technologies that make it possible to provide environmental information to the public in near real time. EMPACT is working with the 86 largest metropolitan areas of the country to help communities in these areas: Collect, manage and distribute time-relevant environmental information. Provide their residents with easy-to-understand information they can use in making informed, day-to-day decisions. Information

75 FR 57220 - Rule To Implement the 1997 8-Hour Ozone National Ambient Air Quality Standard: New Source Review...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-20

... Rule To Implement the 1997 8-Hour Ozone National Ambient Air Quality Standard: New Source Review Anti-Backsliding Provisions for Former 1-Hour Ozone Standard--Public Hearing Notice AGENCY: Environmental... be held for the proposed ``Rule to Implement the 1997 8-Hour Ozone National Ambient Air Quality...

76 FR 2066 - Approval and Promulgation of Implementation Plans; Indiana; Removal of Vehicle Inspection and...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-12

... ozone maintenance plans. The Indiana Department of Environmental Management (IDEM) submitted this... Promulgation of Implementation Plans; Indiana; Removal of Vehicle Inspection and Maintenance Programs for Clark... to allow the State to discontinue the vehicle inspection and maintenance (I/M) program in Clark and...

Interpreting Predictions from the SAPRC07 Mechanism Based on Regional and Continental Simulations

EPA Science Inventory

The SAPRC07T mechanism is implemented and evaluated in the CMAQ air quality model. The implementation is described and tested with simulations over the United States for two periods. The evaluation compares results against observations for ozone and particulate matter as well as ...

78 FR 47253 - Approval and Promulgation of Air Quality Implementation Plans; Maine; Oxides of Nitrogen...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-05

...-hour ozone standard in any area in the OTR. The State's submittals include detailed technical analyses... areas in the OTR. The State's technical analyses rely on several different techniques used to analyze... Maine's requests? Based on the ME DEP's technical analyses discussed above, EPA believes that the State...

76 FR 48207 - Federal Implementation Plans: Interstate Transport of Fine Particulate Matter and Ozone and...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-08

... Problems and NAAQS Addressed 1. Air Quality Problems and NAAQS Addressed 2. FIP Authority for Each State... resolve nonattainment or maintenance problems at downwind state receptors. Downwind states also have... are fossil fuel-fired boilers and turbines producing electricity for sale, as detailed in section VII...

76 FR 75845 - Approval and Promulgation of Implementation Plans; State of Tennessee: Prevention of Significant...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-05

... major stationary thresholds (marginal, moderate, serious, severe, and extreme NAA classifications) and... offset ratios for marginal, moderate, serious, severe, and extreme ozone NAA. EPA finalized regulations...

Determination of State Budgets for the Final Ozone Supplemental of the Transport Rule TSD

EPA Pesticide Factsheets

In this final rulemaking, EPA finalizes Federal Implementation Plans (FIPs) to address significant contribution to nonattainment and interference with maintenance in Iowa, Michigan, Missouri, Oklahoma, and Wisconsin.

75 FR 76332 - Approval and Promulgation of Air Quality Implementation Plans; Illinois

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-08

... Promulgation of Air Quality Implementation Plans; Illinois AGENCY: Environmental Protection Agency (EPA... attaining the 1997 8-hour ozone National Ambient Air Quality Standard (NAAQS). The State's NO X RACT waiver... classification of an area. The air quality planning and control requirements for the reduction of NO X emissions...

Evaluation of the new EMAC-SWIFT chemistry climate model

NASA Astrophysics Data System (ADS)

Scheffler, Janice; Langematz, Ulrike; Wohltmann, Ingo; Rex, Markus

2016-04-01

It is well known that the representation of atmospheric ozone chemistry in weather and climate models is essential for a realistic simulation of the atmospheric state. Including atmospheric ozone chemistry into climate simulations is usually done by prescribing a climatological ozone field, by including a fast linear ozone scheme into the model or by using a climate model with complex interactive chemistry. While prescribed climatological ozone fields are often not aligned with the modelled dynamics, a linear ozone scheme may not be applicable for a wide range of climatological conditions. Although interactive chemistry provides a realistic representation of atmospheric chemistry such model simulations are computationally very expensive and hence not suitable for ensemble simulations or simulations with multiple climate change scenarios. A new approach to represent atmospheric chemistry in climate models which can cope with non-linearities in ozone chemistry and is applicable to a wide range of climatic states is the Semi-empirical Weighted Iterative Fit Technique (SWIFT) that is driven by reanalysis data and has been validated against observational satellite data and runs of a full Chemistry and Transport Model. SWIFT has recently been implemented into the ECHAM/MESSy (EMAC) chemistry climate model that uses a modular approach to climate modelling where individual model components can be switched on and off. Here, we show first results of EMAC-SWIFT simulations and validate these against EMAC simulations using the complex interactive chemistry scheme MECCA, and against observations.

77 FR 24440 - Approval and Promulgation of Implementation Plans; Georgia; Atlanta; Ozone 2002 Base Year...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-24

... Promulgation of Implementation Plans; Georgia; Atlanta; Ozone 2002 Base Year Emissions Inventory AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed rule. SUMMARY: EPA is proposing to approve the ozone... (hereafter referred to as ``the Atlanta Area'' or ``Area''), ozone attainment demonstration that was...

77 FR 8197 - Implementation of the 2008 National Ambient Air Quality Standards for Ozone: Nonattainment Area...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-14

...-AR32 Implementation of the 2008 National Ambient Air Quality Standards for Ozone: Nonattainment Area Classifications Approach, Attainment Deadlines and Revocation of the 1997 Ozone Standards for Transportation... proposing thresholds for classifying nonattainment areas for the 2008 ozone National Ambient Air Quality...

77 FR 30160 - Implementation of the 2008 National Ambient Air Quality Standards for Ozone: Nonattainment Area...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-21

...-AR32 Implementation of the 2008 National Ambient Air Quality Standards for Ozone: Nonattainment Area Classifications Approach, Attainment Deadlines and Revocation of the 1997 Ozone Standards for Transportation... all nonattainment areas for the 2008 ozone national ambient air quality standards (NAAQS) (the ``2008...

77 FR 62159 - Approval and Promulgation of Implementation Plans; North Carolina Portion of the Charlotte...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-12

... standards (NAAQS) for the North Carolina portion of the bi-state Charlotte-Gastonia-Rock Hill 1997 8-hour... ozone nonattainment area (hereafter referred to as the ``bi-state Charlotte Area'') is comprised of... Townships) Counties in North Carolina (hereafter referred to as the ``North Carolina portion of the bi-state...

76 FR 21835 - Approval and Promulgation of State Implementation Plans; State of Colorado; Interstate Transport...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-19

... another state's air quality through interstate transport. In this action, EPA is proposing to approve the Colorado Interstate Transport SIP provisions that address the requirement of section 110(a)(2)(D)(i) that... Interstate Transport SIP revision for the 1997 8-hour ozone and 1997 PM 2.5 NAAQS. This revision was...

The geographic distribution and economic value of climate change-related ozone health impacts in the United States in 2030.

PubMed

Fann, Neal; Nolte, Christopher G; Dolwick, Patrick; Spero, Tanya L; Brown, Amanda Curry; Phillips, Sharon; Anenberg, Susan

2015-05-01

In this United States-focused analysis we use outputs from two general circulation models (GCMs) driven by different greenhouse gas forcing scenarios as inputs to regional climate and chemical transport models to investigate potential changes in near-term U.S. air quality due to climate change. We conduct multiyear simulations to account for interannual variability and characterize the near-term influence of a changing climate on tropospheric ozone-related health impacts near the year 2030, which is a policy-relevant time frame that is subject to fewer uncertainties than other approaches employed in the literature. We adopt a 2030 emissions inventory that accounts for fully implementing anthropogenic emissions controls required by federal, state, and/or local policies, which is projected to strongly influence future ozone levels. We quantify a comprehensive suite of ozone-related mortality and morbidity impacts including emergency department visits, hospital admissions, acute respiratory symptoms, and lost school days, and estimate the economic value of these impacts. Both GCMs project average daily maximum temperature to increase by 1-4°C and 1-5 ppb increases in daily 8-hr maximum ozone at 2030, though each climate scenario produces ozone levels that vary greatly over space and time. We estimate tens to thousands of additional ozone-related premature deaths and illnesses per year for these two scenarios and calculate an economic burden of these health outcomes of hundreds of millions to tens of billions of U.S. dollars (2010$). Near-term changes to the climate have the potential to greatly affect ground-level ozone. Using a 2030 emission inventory with regional climate fields downscaled from two general circulation models, we project mean temperature increases of 1 to 4°C and climate-driven mean daily 8-hr maximum ozone increases of 1-5 ppb, though each climate scenario produces ozone levels that vary significantly over space and time. These increased ozone levels are estimated to result in tens to thousands of ozone-related premature deaths and illnesses per year and an economic burden of hundreds of millions to tens of billions of U.S. dollars (2010$).

Region 6: Texas Adequate Letter (4/7/2008)

EPA Pesticide Factsheets

This is a letter from Carl Edlund, Director, to Susana Hildebrand regarding the MVEB's for Dallas/Fort Worth 8-hour Ozone State Implementation Plan (SIP) and the Houston / Galveston / Brazoria Reasonable Further Progress (RFP) plan.

Region 6: Texas Adequate Letter (6/21/17)

EPA Pesticide Factsheets

Letter from EPA approves Motor Vehicle Emissions Budgets contained in latest revisions to Houston/Galveston/Brazoria (HGB) 2008 8-hour Ozone State Implementation Plan, adequate for transportation conformity purposes and announced in the Federal Register.

78 FR 65590 - Approval and Promulgation of Air Quality Implementation Plans; Indiana; Indiana PM2.5

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-01

...EPA is proposing to approve revisions to Indiana's state implementation plan as requested by the Indiana Department of Environmental Management (IDEM) to EPA on July 12, 2012, and December 12, 2012. The revisions to Indiana's state implementation plan (SIP) implement certain EPA regulations for particulate matter smaller than 2.5 micrometers (PM2.5) by establishing definitions related to PM2.5, defining PM2.5 increment levels, and setting PM2.5 class 1 variances. The revisions also incorporate definitions and regulations that recognize nitrogen oxides (NOX) as an ozone precursor.

Implementation of marine halogen chemistry into the Community Multiscale Air Quality (CMAQ) model

NASA Astrophysics Data System (ADS)

Gantt, B.; Sarwar, G.

2017-12-01

In two recent studies (Sarwar et al, 2015 and Gantt et al., 2017), the impact of marine halogen (bromine and iodine) chemistry on air quality has been evaluated using the Community Multiscale Air Quality (CMAQ) model. We found that marine halogen chemistry not only has the expected effect of reducing marine boundary layer ozone concentrations, but also reduces ozone in the free troposphere and inland from the coast. In Sarwar et al. (2015), the impact of the halogen chemistry without and with photochemical reactions of higher iodine oxides over the Northern Hemisphere was examined using the coarse horizontal grids of a hemispheric domain. Halogen chemistry without and with the photochemical reactions of higher iodine oxides reduces ozone over seawater by 15% and 48%, respectively. Using the results of the chemistry without the photochemical reactions of higher iodine oxides, we developed a simple first order ozone loss rate and implemented it into the public version of CMAQv52. In Gantt et al. (2017), the impact of the simple first order loss rate as well as the full halogen chemistry without photochemical reactions of higher iodine oxides over the continental United States was examined using finer horizontal grids of the regional domain and boundary conditions from the hemispheric domain with and without marine halogen chemistry. The boundary conditions obtained with the halogen chemistry as well as the simple halogen chemistry reduces ozone along the coast where CMAQ typically overpredicts the concentrations. Development of halogen chemistry in CMAQ has continued with the implementation of several heterogeneous reactions of bromine and iodine species, revised reactions of higher iodine oxides, and a refined marine halogen emissions inventory. Our latest version of halogen chemistry with photochemical reactions of higher iodine oxides reduces ozone by 23% over the seawater. This presentation will discuss the previous and ongoing implementation of revised halogen chemistry in CMAQ and its impacts on air quality.

75 FR 45075 - Federal Implementation Plans To Reduce Interstate Transport of Fine Particulate Matter and Ozone

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-02

... Matter and Ozone AGENCY: Environmental Protection Agency (EPA). ACTION: Notice of public hearings... Implementation Plans to Reduce Interstate Transport of Fine Particulate Matter and Ozone'' (Transport Rule) which... matter (PM 2.5 ) national ambient air quality standards (NAAQS) and the 1997 ozone NAAQS. Public hearing...

77 FR 20582 - Approval and Promulgation of Implementation Plans; State of Florida: New Source Review Prevention...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-05

... Management to EPA in two separate SIP revisions on October 19, 2007, and July 1, 2011. These SIP revisions... Rule NSR Update Phase II (hereafter referred to as the ``Ozone Implementation NSR Update'' or ``Phase..., Air, Pesticides and Toxics Management Division, U.S. Environmental Protection Agency, Region 4, 61...

76 FR 77178 - Approval and Promulgation of Implementation Plans; New York State Ozone Implementation Plan Revision

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-12

... Pavement and Asphalt Based Surface Coating.'' The intended effect of this action is to approve control..., ``Asphalt Pavement and Asphalt Based Surface Coating?'' A. Background B. What are the requirements of Part 241, ``Asphalt Pavement and Asphalt Based Surface Coating?'' C. What is EPA's evaluation? VI. What is...

78 FR 68367 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Ohio NOX

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-14

... Clean Air Act, which allows for Ohio's Clean Air Interstate Rule (CAIR) NO X Ozone Season Trading Program rules to supersede Ohio's nitrogen oxides (NO X ) State Implementation Plan (SIP) Call Budget Trading Program rules, but leave other requirements of the NO X SIP Call in place for units not covered by...

77 FR 57029 - Approval and Promulgation of State Implementation Plan Revisions; Infrastructure Requirements for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-17

... either electronically through www.regulations.gov or in hard copy at the Air Program, Environmental... 4 p.m., excluding Federal holidays. FOR FURTHER INFORMATION CONTACT: Kathy Ayala, Air Program, U.S... 1997 ozone NAAQS, states typically have met the basic program elements required in section 110(a)(2...

78 FR 11804 - Approval and Promulgation of Implementation Plans; State of Kansas; Idle Reduction of Heavy-Duty...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-20

...EPA is proposing to approve the State Implementation Plan (SIP) submitted by the State of Kansas on July 27, 2010, to add two new rules which implement restrictions on the idling of heavy duty diesel vehicles and reduce nitrogen oxide (NOX) emissions at stationary sources in the Kansas portion of the Kansas City Maintenance Area for ozone. EPA is approving this revision because the standards and requirements set by the rules will strengthen the Kansas SIP. EPA's approval of this SIP revision is being done in accordance with the requirements of the Clean Air Act (CAA).

78 FR 57501 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Amendments to Vehicle...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-19

...EPA is approving a state implementation plan (SIP) revision submitted by the Wisconsin Department of Natural Resources on June 7, 2012, concerning the state's vehicle inspection and maintenance (I/M) program in southeast Wisconsin. The revision amends I/M program requirements in the active control measures portion of the ozone SIP to reflect changes that have been implemented at the state level since EPA fully approved the I/M program on August 16, 2001. The submittal also includes a demonstration under section 110(l) of the Clean Air Act (CAA) addressing lost emission reductions associated with the program changes.

Region 6: Texas Adequate Letter (6/16/2005)

EPA Pesticide Factsheets

This is a letter from Carl E. Edlund, Director, to Candice Garrett regarding motor vehicle emissions budgets (MVEB) contained in the 5 Increment of Progress 8-hour Ozone StateImplementation Plan (SIP) for the Dallas-Fort Worth nonattainment area.

Region 6: Texas Austin Adequate Letter (11/23/2016)

EPA Pesticide Factsheets

EPA letter approves the Motor Vehicle Emissions Budgets contained in the latest revision to Dallas/Fort Worth 2008 8-hour Ozone State Implementation Plan, finding them adequate for transportation conformity purposes to be announced in the Federal Register.

40 CFR 51.916 - What are the requirements for an Ozone Transport Region under the 8-hour NAAQS?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 2 2011-07-01 2011-07-01 false What are the requirements for an Ozone... IMPLEMENTATION PLANS Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.916 What are the requirements for an Ozone Transport Region under the 8-hour NAAQS? (a) In General...

40 CFR 51.916 - What are the requirements for an Ozone Transport Region under the 8-hour NAAQS?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 2 2012-07-01 2012-07-01 false What are the requirements for an Ozone... IMPLEMENTATION PLANS Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.916 What are the requirements for an Ozone Transport Region under the 8-hour NAAQS? (a) In General...

40 CFR 51.916 - What are the requirements for an Ozone Transport Region under the 8-hour NAAQS?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 2 2013-07-01 2013-07-01 false What are the requirements for an Ozone... IMPLEMENTATION PLANS Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.916 What are the requirements for an Ozone Transport Region under the 8-hour NAAQS? (a) In General...

40 CFR 51.916 - What are the requirements for an Ozone Transport Region under the 8-hour NAAQS?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 2 2010-07-01 2010-07-01 false What are the requirements for an Ozone... IMPLEMENTATION PLANS Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.916 What are the requirements for an Ozone Transport Region under the 8-hour NAAQS? (a) In General...

40 CFR 51.916 - What are the requirements for an Ozone Transport Region under the 8-hour NAAQS?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 2 2014-07-01 2014-07-01 false What are the requirements for an Ozone... IMPLEMENTATION PLANS Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.916 What are the requirements for an Ozone Transport Region under the 8-hour NAAQS? (a) In General...

77 FR 35285 - Approval of Air Quality Implementation Plan; Arizona; Attainment Plan for 1997 8-Hour Ozone Standard

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-13

... Quality Implementation Plan; Arizona; Attainment Plan for 1997 8-Hour Ozone Standard AGENCY: U.S... 1997 8-hour ozone national ambient air quality standards (NAAQS) in the Phoenix-Mesa nonattainment area... required for ozone nonattainment areas under title I, part D, subpart 1 of the Clean Air Act (CAA) for the...

77 FR 6743 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-09

...EPA is proposing to approve a request from Illinois to redesignate the Illinois portion of the Chicago-Gary-Lake County, Illinois-Indiana (IL-IN) ozone nonattainment area (the Greater Chicago area) to attainment of the 1997 8-hour ozone National Ambient Air Quality Standard (NAAQS or standard) because the request meets the statutory requirements for redesignation under the Clean Air Act (CAA). The Illinois portion of the Greater Chicago area includes Cook, DuPage, Kane, Lake, McHenry, and Will Counties and portions of Grundy (Aux Sable and Goose Lake Townships) and Kendall (Oswego Township) Counties. The Illinois Environmental Protection Agency (IEPA) submitted this request on July 23, 2009, and supplemented its request in a submittal on September 16, 2011. EPA is proposing to approve, as a revision of the Illinois State Implementation Plan (SIP), the State's plan for maintaining the 1997 8-hour ozone standard through 2025 in the Illinois portion of the Greater Chicago area. EPA is proposing to approve 2002 Volatile Organic Compound (VOC) and Nitrogen Oxides (NOX) emission inventories for the Illinois portion of the Greater Chicago area as a revision of the Illinois SIP because the emission inventories meet the requirements of section 182(a) of the CAA. Finally, EPA proposes to approve the State's 2008 and 2025 VOC and NOX Motor Vehicle Emission Budgets (MVEBs) for the Illinois portion of the Greater Chicago area.

ATMOSPHERIC MODEL DEVELOPMENT

EPA Science Inventory

This task provides credible state of the art air quality models and guidance for use in implementation of National Ambient Air Quality Standards for ozone and PM. This research effort is to develop and improve air quality models, such as the Community Multiscale Air Quality (CMA...

Trans-Pacific Air Pollution and NAAQS Attainment: Domestic and International Policy Options

NASA Astrophysics Data System (ADS)

Dolsak, N.; Jaegle, L.

2002-12-01

Observational data and models of global air pollution increasingly indicate that Asian air pollution caused by fossil fuel burning is transported across the Pacific, thereby affecting local air quality in the United States. This may have policy ramifications for a number of counties in the U.S. struggling to meet the NAAQS. This problem will be exacerbated as the EPA tightens the standards for Ozone and PM. As the new 8-hour, 80 ppb ozone standard and the new PM2.5 standards are implemented, the number of counties considered to be in non-attainment is estimated to double (for ozone) and quadruple (for PM2.5), respectively. State Implementation Plans that rely only on local emission reductions may not be enough to meet the new NAAQS if a considerable proportion of the background concentrations come from Asia or other distant sources. Further, reducing emissions locally may not be the most cost-effective way of meeting the new EPA standards. This presentation will draw on observational data in the western U.S. and global models, such as GEOS-CHEM, to examine the significance of trans-pacific pollution (background pollution as well as episodic impacts) to air quality in the Western United States in their attempts to meet the new NAAQS for Ozone and Particulate Matter. The size of Asian economies, their reliance on fossil fuels, and their rapid industrialization suggests that the importance of trans-pacific air pollution will increase. This presentation will examine policy implications of Asian emissions under three of the IPCC future emission scenarios. We will also identify an array of domestic policies that States and counties in non-attainment areas may consider to reduce the concentrations of ozone and PM. Further, we will examine the potential for reducing local concentrations by devising policy instruments for reducing emissions where they can be reduced at a lower cost. For this work, we will draw on policy experience from regional air pollution in the European Union and evaluate options for devising policy instruments within the institutional framework of the Asia Pacific Economic Cooperation.

78 FR 44890 - Approval and Promulgation of Implementation Plans; North Carolina; Control Techniques Guidelines...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-25

... for the 1997 8- hour ozone NAAQS includes six full counties and one partial county in North Carolina; and one partial county in South Carolina. The North Carolina portion of the bi-state Charlotte Area... one full county and six partial counties in the bi-state Charlotte area as a marginal nonattainment...

Radiative effects due to North American anthropogenic and lightning emissions: Global and regional modeling

NASA Astrophysics Data System (ADS)

Martini, Matus Novak

We analyze the contribution of North American (NA) lightning and anthropogenic emissions to summertime ozone concentrations, radiative forcing, and exports from North America using the global University of Maryland chemistry transport model (UMD-CTM) and the regional scale Weather Research and Forecasting model with chemistry (WRF-Chem). Lightning NO contributes by 15--20 ppbv to upper tropospheric ozone concentrations over the United States with the effects of NA lightning on ozone seen as far east as North Africa and Europe. Using the UMD-CTM, we compare changes in surface and column ozone amounts due to the NOx State Implementation Plan (SIP) Call with the natural variability in ozone due to changes in meteorology and lightning. Comparing early summer 2004 with 2002, surface ozone decreased by up to 5 ppbv due to the NO x SIP Call while changes in meteorology and lightning resulted in a 0.3--1.4 ppbv increase in surface ozone. Ozone column variability was driven primarily by changes in lightning NO emissions, especially over the North Atlantic. As part of our WRF-Chem analysis, we modify the radiation schemes to use model-calculated ozone (interactive ozone) instead of climatological ozone profiles and conduct multiple 4-day simulations of July 2007. We found that interactive ozone increased the outgoing longwave radiation (OLR) by 3 W m-2 decreasing the bias with respect to remotely sensed OLR. The improvement is due to a high bias in the climatological ozone profiles. The interactive ozone had a small impact on mean upper troposphere temperature (-0.15°C). The UMD-CTM simulations indicate that NA anthropogenic emissions are responsible for more ozone export but less ozone radiative forcing than lightning NO emissions. Over the North Atlantic, NA anthropogenic emissions contributed 0.15--0.30 W m-2 to the net downward radiative flux at the tropopause while NA lightning contributed 0.30--0.50 W m-2. The ozone export from anthropogenic emissions was almost twice as large as that from lightning emissions. The WRF-Chem simulations show that the export of reactive nitrogen was 23%--28% of the boundary layer emissions and 26%--38% of the total emissions including lightning NO.

Photochemical modeling of emissions trading of highly reactive volatile organic compounds in Houston, Texas. 1. Reactivity based trading and potential for ozone hot spot formation.

PubMed

Wang, Linlin; Thompson, Tammy; McDonald-Buller, Elena C; Webb, Alba; Allen, David T

2007-04-01

As part of the State Implementation Plan for attaining the National Ambient Air Quality Standard for ozone, the Texas Commission of Environmental Quality has created a Highly Reactive Volatile Organic Compounds (HRVOC) Emissions Cap and Trade Program for industrial point sources in the Houston/Galveston/Brazoria area. This program has a number of unique features, including its focus on a limited group of ozone precursors and its provisions for trading emissions based on atmospheric reactivity. This series of papers examines the potential air quality impacts of this new emission trading program through photochemical modeling of potential trading scenarios; this first paper in the series describes the air quality modeling methods used to assess potential trades, the potential for localized increases in ozone concentrations (ozone "hot spots") due to HRVOC emission trading, and the use of reactivity scales in the trading. When HRVOC emissions are traded on a mass basis, the simulations indicate that trading of HRVOC allowances between facilities resulted in less than 0.15 ppb (<0.13%) and 0.06 ppb (<0.06%) increases in predicted maximum, area-wide 1-h averaged and 8-h averaged ozone concentrations, respectively. Maximum decreases in ozone concentrations associated with trading, as opposed to across-the-board reductions, were larger than the increases. All of these changes are small compared to the maximum changes in ozone concentrations due to the VOC emissions from these sources (up to 5-10 ppb for 8 h averages; up to 30 ppb for 1-h averages). When emissions of HRVOCs are traded for other, less reactive emissions, on a reactivity weighted basis, air quality simulations indicate that daily maximum ozone concentrations increased by less than 0.3%. Because these relatively small changes (< 1%) are for unlikely trading scenarios designed to produce a maximum change in ozone concentrations (all emissions traded into localized regions), the simulations indicate that the implementation of the trading program, as currently configured and possibly expanded, is unlikely to cause localized increases in ozone concentrations ("hot spots").

Homogenized total ozone data records from the European sensors GOME/ERS-2, SCIAMACHY/Envisat, and GOME-2/MetOp-A

NASA Astrophysics Data System (ADS)

Lerot, C.; Van Roozendael, M.; Spurr, R.; Loyola, D.; Coldewey-Egbers, M.; Kochenova, S.; van Gent, J.; Koukouli, M.; Balis, D.; Lambert, J.-C.; Granville, J.; Zehner, C.

2014-02-01

Within the European Space Agency's Climate Change Initiative, total ozone column records from GOME (Global Ozone Monitoring Experiment), SCIAMACHY (SCanning Imaging Absorption SpectroMeter for Atmospheric CartograpHY), and GOME-2 have been reprocessed with GODFIT version 3 (GOME-type Direct FITting). This algorithm is based on the direct fitting of reflectances simulated in the Huggins bands to the observations. We report on new developments in the algorithm from the version implemented in the operational GOME Data Processor v5. The a priori ozone profile database TOMSv8 is now combined with a recently compiled OMI/MLS tropospheric ozone climatology to improve the representativeness of a priori information. The Ring procedure that corrects simulated radiances for the rotational Raman inelastic scattering signature has been improved using a revised semi-empirical expression. Correction factors are also applied to the simulated spectra to account for atmospheric polarization. In addition, the computational performance has been significantly enhanced through the implementation of new radiative transfer tools based on principal component analysis of the optical properties. Furthermore, a soft-calibration scheme for measured reflectances and based on selected Brewer measurements has been developed in order to reduce the impact of level-1 errors. This soft-calibration corrects not only for possible biases in backscattered reflectances, but also for artificial spectral features interfering with the ozone signature. Intersensor comparisons and ground-based validation indicate that these ozone data sets are of unprecedented quality, with stability better than 1% per decade, a precision of 1.7%, and systematic uncertainties less than 3.6% over a wide range of atmospheric states.

78 FR 11751 - Approval and Promulgation of Implementation Plans; State of Kansas; Idle Reduction of Heavy-Duty...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-20

...EPA is taking direct final action to approve revisions to the Kansas State Implementation Plan (SIP) submitted by the State of Kansas on July 27, 2010. The revision includes two new rules which implement restrictions on the idling of heavy duty diesel vehicles and reduce nitrogen oxide (NOX) emissions at stationary sources in the Kansas portion of the Kansas City Maintenance Area for ozone. EPA is approving this revision because the standards and requirements set by the rules will strengthen the Kansas SIP. EPA's approval of this SIP revision is being done in accordance with the requirements of the Clean Air Act (CAA).

Proposed Approval of Kentucky 2008 Transport SIP Submission

EPA Pesticide Factsheets

The Environmental Protection Agency (EPA) is proposing to approve Kentucky’s February 28, 2018, draft State Implementation Plan (SIP) submission pertaining to the “good neighbor” provision of the Clean Air Act (CAA or Act) for the 2008 8-hour ozone Nationa

76 FR 31263 - Approval and Promulgation of Implementation Plans; State of California; Interstate Transport of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-31

...EPA is proposing a limited approval and limited disapproval of a State Implementation Plan (``SIP'') revision submitted by the State of California on November 17, 2007, for the purpose of addressing the ``transport SIP'' provisions of Clean Air Act (``CAA'') section 110(a)(2)(D)(i) for the 1997 8-hour ozone National Ambient Air Quality Standards (NAAQS or standards) and the 1997 fine particulate matter (``PM2.5'') NAAQS. Section 110(a)(2)(D)(i) of the CAA requires that each SIP contain adequate provisions to prohibit emissions that adversely affect air quality in other States through interstate transport. EPA is proposing a limited approval and limited disapproval of California's SIP revision for the 1997 8-hour ozone and 1997 PM2.5 NAAQS with respect to the requirement in CAA section 110(a)(2)(D)(i)(II) that each SIP contain adequate measures prohibiting emissions of air pollutants in amounts which will interfere with other States' measures required under title I, part C of the CAA to prevent significant deterioration of air quality. Specifically, EPA is proposing to approve California's SIP revision with respect to those Districts in California that implement SIP-approved permit programs meeting the approval criteria under CAA section 110(a)(2)(D)(i), as discussed in this proposal. EPA is simultaneously proposing to disapprove California's SIP revision with respect to those Districts in California that do not implement SIP-approved permit programs meeting these approval criteria. For any District for which we finalize a disapproval, EPA intends to simultaneously promulgate a limited Federal Implementation Plan (``FIP''), as discussed in this proposal, unless the relevant area is already subject to a FIP.

High winter ozone pollution from carbonyl photolysis in an oil and gas basin.

PubMed

Edwards, Peter M; Brown, Steven S; Roberts, James M; Ahmadov, Ravan; Banta, Robert M; deGouw, Joost A; Dubé, William P; Field, Robert A; Flynn, James H; Gilman, Jessica B; Graus, Martin; Helmig, Detlev; Koss, Abigail; Langford, Andrew O; Lefer, Barry L; Lerner, Brian M; Li, Rui; Li, Shao-Meng; McKeen, Stuart A; Murphy, Shane M; Parrish, David D; Senff, Christoph J; Soltis, Jeffrey; Stutz, Jochen; Sweeney, Colm; Thompson, Chelsea R; Trainer, Michael K; Tsai, Catalina; Veres, Patrick R; Washenfelder, Rebecca A; Warneke, Carsten; Wild, Robert J; Young, Cora J; Yuan, Bin; Zamora, Robert

2014-10-16

The United States is now experiencing the most rapid expansion in oil and gas production in four decades, owing in large part to implementation of new extraction technologies such as horizontal drilling combined with hydraulic fracturing. The environmental impacts of this development, from its effect on water quality to the influence of increased methane leakage on climate, have been a matter of intense debate. Air quality impacts are associated with emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs), whose photochemistry leads to production of ozone, a secondary pollutant with negative health effects. Recent observations in oil- and gas-producing basins in the western United States have identified ozone mixing ratios well in excess of present air quality standards, but only during winter. Understanding winter ozone production in these regions is scientifically challenging. It occurs during cold periods of snow cover when meteorological inversions concentrate air pollutants from oil and gas activities, but when solar irradiance and absolute humidity, which are both required to initiate conventional photochemistry essential for ozone production, are at a minimum. Here, using data from a remote location in the oil and gas basin of northeastern Utah and a box model, we provide a quantitative assessment of the photochemistry that leads to these extreme winter ozone pollution events, and identify key factors that control ozone production in this unique environment. We find that ozone production occurs at lower NOx and much larger VOC concentrations than does its summertime urban counterpart, leading to carbonyl (oxygenated VOCs with a C = O moiety) photolysis as a dominant oxidant source. Extreme VOC concentrations optimize the ozone production efficiency of NOx. There is considerable potential for global growth in oil and gas extraction from shale. This analysis could help inform strategies to monitor and mitigate air quality impacts and provide broader insight into the response of winter ozone to primary pollutants.

High winter ozone pollution from carbonyl photolysis in an oil and gas basin

NASA Astrophysics Data System (ADS)

Edwards, Peter M.; Brown, Steven S.; Roberts, James M.; Ahmadov, Ravan; Banta, Robert M.; Degouw, Joost A.; Dubé, William P.; Field, Robert A.; Flynn, James H.; Gilman, Jessica B.; Graus, Martin; Helmig, Detlev; Koss, Abigail; Langford, Andrew O.; Lefer, Barry L.; Lerner, Brian M.; Li, Rui; Li, Shao-Meng; McKeen, Stuart A.; Murphy, Shane M.; Parrish, David D.; Senff, Christoph J.; Soltis, Jeffrey; Stutz, Jochen; Sweeney, Colm; Thompson, Chelsea R.; Trainer, Michael K.; Tsai, Catalina; Veres, Patrick R.; Washenfelder, Rebecca A.; Warneke, Carsten; Wild, Robert J.; Young, Cora J.; Yuan, Bin; Zamora, Robert

2014-10-01

The United States is now experiencing the most rapid expansion in oil and gas production in four decades, owing in large part to implementation of new extraction technologies such as horizontal drilling combined with hydraulic fracturing. The environmental impacts of this development, from its effect on water quality to the influence of increased methane leakage on climate, have been a matter of intense debate. Air quality impacts are associated with emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs), whose photochemistry leads to production of ozone, a secondary pollutant with negative health effects. Recent observations in oil- and gas-producing basins in the western United States have identified ozone mixing ratios well in excess of present air quality standards, but only during winter. Understanding winter ozone production in these regions is scientifically challenging. It occurs during cold periods of snow cover when meteorological inversions concentrate air pollutants from oil and gas activities, but when solar irradiance and absolute humidity, which are both required to initiate conventional photochemistry essential for ozone production, are at a minimum. Here, using data from a remote location in the oil and gas basin of northeastern Utah and a box model, we provide a quantitative assessment of the photochemistry that leads to these extreme winter ozone pollution events, and identify key factors that control ozone production in this unique environment. We find that ozone production occurs at lower NOx and much larger VOC concentrations than does its summertime urban counterpart, leading to carbonyl (oxygenated VOCs with a C = O moiety) photolysis as a dominant oxidant source. Extreme VOC concentrations optimize the ozone production efficiency of NOx. There is considerable potential for global growth in oil and gas extraction from shale. This analysis could help inform strategies to monitor and mitigate air quality impacts and provide broader insight into the response of winter ozone to primary pollutants.

Quantification of source region influences on the ozone burden

NASA Astrophysics Data System (ADS)

Treffeisen, Renate; Grunow, Katja; Möller, Detlev; Hainsch, Andreas

A project was performed to quantify different influences on the ozone burden. It could be shown that large-scale meteorological influences determine a very large percentage of the ozone concentration. Local measures intended to reduce peak ozone concentrations in summer turn out to be not very effective as a result. The aim of this paper is to quantify regional emission influences on the ozone burden. The investigation of these influences is possible by comparison of the ozone (O 3) and oxidant (O x=O 3+NO 2) concentrations at high-elevation sites downwind and upwind of a source region by using back trajectories. It has been shown that a separation between large-scale influenced meteorological and regional ozone burdens at these sites is possible. This method is applied for an important emission area in Germany—the Ruhrgebiet. On average, no significant ozone contribution of this area to the regional ozone concentration could be found. A large part of the ozone concentration is highly correlated with synoptic weather systems, which exhibit a dominant influence on the local ozone concentrations. Significant contributions of related photochemical ozone formation of the source area of 13-15% have been found only during favourable meteorological situations, identified by the hourly maximum day temperature being above 25°C. This is important with respect to the EU daughter directive to EU 96/62/EC (Official Journal L296 (1996) 55) because Member States should explore the possibilities of local measures to avoid the exceedance of threshold values and, if effective local measures exist, to implement them.

76 FR 47443 - Approval and Promulgation of State Implementation Plans; State of Colorado; Attainment...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-05

... ozone concentrations is less than or equal to 0.08 ppm. Forty CFR part 50, Appendix I, section 2.3... at both locations. This is 0.2 ppb lower than Colorado's 2008 modeling projected using incorrect..., section 2.1, page 15; section 3.0, pages 20-28; section 4.2, page 40.) Colorado followed this procedure in...

75 FR 31290 - Approval and Promulgation of State Implementation Plan Revisions; State of North Dakota; Air...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-03

... Interstate Transport of Pollution for the 1997 PM 2.5 and 8-Hour Ozone NAAQS: ``Significant Contribution to... Transport of Air Pollution'' addressing the requirements of Clean Air Act section 110(a)(2)(D)(i) for the... to as the Interstate Transport of Air Pollution SIP, address the requirements of Clean Air Act...

76 FR 34608 - Approval and Promulgation of Air Quality Implementation Plans; State of California; Interstate...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-14

... other states' measures to protect visibility for the 1997 8-hour ozone and 1997 particulate matter (PM 2... precursors react in the atmosphere to form fine particulate matter that impairs visibility by scattering and... greatest distance, in kilometers or miles, at which a dark object can be viewed against the sky. B. The CAA...

MODEL DEVELOPMENT FOR FY08 CMAQ RELEASE

EPA Science Inventory

This task provides credible state of the art air quality models and guidance for use in implementation of National Ambient Air Quality Standards for ozone and PM. This research effort is to develop and improve air quality models, such as the Community Multiscale Air Quality (CMA...

Impacts of interstate transport of pollutants on high ozone events over the Mid-Atlantic United States

NASA Astrophysics Data System (ADS)

Liao, Kuo-Jen; Hou, Xiangting; Baker, Debra Ratterman

2014-02-01

The impacts of interstate transport of anthropogenic nitrogen oxides (NOx) and volatile organic compound (VOC) emissions on peak ozone formation in four nonattainment areas (i.e., Baltimore, Philadelphia-Wilmington-Atlantic City, Pittsburgh-Beaver Valley and Washington, DC) in the Mid-Atlantic U.S. were quantified in this study. Regional air quality and sensitivities of ground-level ozone to emissions from four regions in the eastern U.S. were simulated for three summer months (June, July and August) in 2007 using the U.S. EPA's Community Multiscale Air Quality model with the decoupled direct method 3D. The emissions inventory used in this study was the 2007 Mid-Atlantic Regional Air Management Association Level 2 inventory, developed for State Implementation Plan screening modeling for the Ozone Transport Commission region. The modeling results show that responses of peak ozone levels at specific locations to emissions from EGU (i.e., electric generating unit) and non-EGU sources could be different. Therefore, emissions from EGU and non-EGU sources should be considered as two different control categories when developing regional air pollution mitigation strategies. Based on the emission inventories used in this study, reductions in anthropogenic NOx emissions (including those from EGU and non-EGU sources) from the Great Lake region as well as northeastern and southeastern U.S. would be effective for decreasing area-mean peak ozone concentrations during the summer of 2007 in the Mid-Atlantic ozone air quality nonattainment areas. The results also show that reductions in anthropogenic VOC emissions from the northeastern U.S. would also be effective for decreasing area-mean peak ozone concentrations over the Mid-Atlantic U.S. In some cases, reductions in anthropogenic NOx emissions from the Great Lake and northeastern U.S. could slightly increase area-mean peak ozone concentrations at some ozone monitors in the Pittsburgh-Beaver Valley and Washington, DC areas. However, the disbenefit of the slight increase in ozone concentrations attributed to the NOx emission controls was far outweighed by the overall ozone air quality benefits over the Mid-Atlantic region.

77 FR 28785 - Revisions to Federal Implementation Plans To Reduce Interstate Transport of Fine Particulate...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-16

... Ozone AGENCY: Environmental Protection Agency (EPA). ACTION: Withdrawal of direct final rule. SUMMARY... Particulate Matter and Ozone'' as a direct final rule on February 21, 2012. Because the EPA received adverse... Implementation Plans To Reduce Interstate Transport of Fine Particulate Matter and Ozone'' as a direct final rule...

75 FR 54778 - Approval and Promulgation of Air Quality Implementation Plans; Louisiana; Baton Rouge 8-Hour...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-09

... Promulgation of Air Quality Implementation Plans; Louisiana; Baton Rouge 8-Hour Ozone Nonattainment Area; Determination of Attainment of the 8-Hour Ozone Standard AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: The EPA has determined that the Baton Rouge (BR) moderate 8- hour ozone...

40 CFR 52.930 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.930 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Kentucky § 52.930 Control strategy: Ozone. (a) The VOC..., Campbell and Kenton Counties) ozone nonattainment area. The demonstration of attainment of the ozone...

40 CFR 52.930 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.930 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Kentucky § 52.930 Control strategy: Ozone. (a) The VOC..., Campbell and Kenton Counties) ozone nonattainment area. The demonstration of attainment of the ozone...

40 CFR 52.930 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.930 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Kentucky § 52.930 Control strategy: Ozone. (a) The VOC..., Campbell and Kenton Counties) ozone nonattainment area. The demonstration of attainment of the ozone...

40 CFR 52.930 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.930 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Kentucky § 52.930 Control strategy: Ozone. (a) The VOC..., Campbell and Kenton Counties) ozone nonattainment area. The demonstration of attainment of the ozone...

40 CFR 52.930 - Control strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: Ozone. 52.930 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Kentucky § 52.930 Control strategy: Ozone. (a) The VOC..., Campbell and Kenton Counties) ozone nonattainment area. The demonstration of attainment of the ozone...

77 FR 16785 - Approval and Promulgation of Implementation Plans; Alaska: Infrastructure Requirements for the...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-22

... Promulgation of Implementation Plans; Alaska: Infrastructure Requirements for the 1997 8-Hour Ozone National... the National Ambient Air Quality Standard (NAAQS) promulgated for ozone on July 18, 1997. EPA is...-hour ozone NAAQS: (A), (B), (C), (D)(ii), (E), (F), (G), (H), (J), (K), (L), and (M). EPA is proposing...

Impact of Ozone Radiative Feedbacks on Global Weather Forecasting

NASA Astrophysics Data System (ADS)

Ivanova, I.; de Grandpré, J.; Rochon, Y. J.; Sitwell, M.

2017-12-01

A coupled Chemical Data Assimilation system for ozone is being developed at Environment and Climate Change Canada (ECCC) with the goals to improve the forecasting of UV index and the forecasting of air quality with the Global Environmental Multi-scale (GEM) Model for Air quality and Chemistry (MACH). Furthermore, this system provides an opportunity to evaluate the benefit of ozone assimilation for improving weather forecasting with the ECCC Global Deterministic Prediction System (GDPS) for Numerical Weather Prediction (NWP). The present UV index forecasting system uses a statistical approach for evaluating the impact of ozone in clear-sky and cloudy conditions, and the use of real-time ozone analysis and ozone forecasts is highly desirable. Improving air quality forecasting with GEM-MACH further necessitates the development of integrated dynamical-chemical assimilation system. Upon its completion, real-time ozone analysis and ozone forecasts will also be available for piloting the regional air quality system, and for the computation of ozone heating rates, in replacement of the monthly mean ozone distribution currently used in the GDPS. Experiments with ozone radiative feedbacks were run with the GDPS at 25km resolution and 84 levels with a lid at 0.1 hPa and were initialized with ozone analysis that has assimilated total ozone column from OMI, OMPS, and GOME satellite instruments. The results show that the use of prognostic ozone for the computation of the heating/cooling rates has a significant impact on the temperature distribution throughout the stratosphere and upper troposphere regions. The impact of ozone assimilation is especially significant in the tropopause region, where ozone heating in the infrared wavelengths is important and ozone lifetime is relatively long. The implementation of the ozone radiative feedback in the GDPS requires addressing various issues related to model biases (temperature and humidity) and biases in equilibrium state (ozone mixing ratio, air temperature and overhead column ozone) used for the calculation of the linearized photochemical production and loss of ozone. Furthermore the radiative budget in the tropopause region is strongly affected by water vapor cooling, which impact requires further evaluation for the use in chemically coupled operational NWP systems.

78 FR 32613 - Disapproval of State Implementation Plan; Infrastructure Requirements for the 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-31

... 12866. I. National Technology Transfer and Advancement Act Section 12 of the National Technology... information claimed to be Confidential Business Information (CBI) or other information whose disclosure is... requirements of [section 128].'' \\2\\ We find that this legislative history indicates that Congress intended...

Examining the Impact of Regional-Scale Air Quality Regulations on Human Health Outcomes

EPA Science Inventory

The NOx State Implementation Plan Call was issued by the U.S. Environmental Protection Agency to reduce the emissions of nitrogen oxides from the electric power sector to curtail the regional transport of the secondarily-formed pollutant, ozone. As emission control actions often...

78 FR 47572 - Disapproval of State Implementation Plan; Infrastructure Requirements for the 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-06

... docket. You may view the hard copy of the docket Monday through Friday, 8:00 a.m. to 4:00 p.m., excluding...: July 24, 2013. Shaun L. McGrath, Regional Administrator, Region 8. [FR Doc. 2013-18842 Filed 8-5-13; 8...

40 CFR 52.1470 - Identification of plan.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Highway 50 Corridor Study, June 1979 (Appendix C); (D) Reference from Transportation and Traffic... submitted on May 5, 1983 by the State: (i) “Stateline, Nevada, 1983 Carbon Monoxide Study”—a traffic... Implementation Plan, Post 1982 Update for Ozone adopted on October 16, 1984 (including section 33 (Chlorine in...

40 CFR 52.1470 - Identification of plan.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Highway 50 Corridor Study, June 1979 (Appendix C); (D) Reference from Transportation and Traffic... submitted on May 5, 1983 by the State: (i) “Stateline, Nevada, 1983 Carbon Monoxide Study”—a traffic... Implementation Plan, Post 1982 Update for Ozone adopted on October 16, 1984 (including section 33 (Chlorine in...

78 FR 4800 - Approval and Promulgation of Air Quality Implementation Plans; Connecticut; Reasonably Available...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-23

... from cutback asphalt paving and solvent cleaning (metal degreasing). The original version of the state's cutback asphalt rule allowed use of cutback asphalt, with some restrictions, during the ozone season and provided exemptions for penetrating prime coat products and for long-term storage of asphalt...

75 FR 72705 - Approval and Promulgation of Implementation Plans; Idaho

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-26

... other states, WG relied on an additional study entitled the ``Uinta Basin Air Quality Study (UBAQS... of a modeling analysis to assess ozone impacts prior to authorizing oil and gas development projects... Agencies on assessing impacts of oil and gas development projects.\\18\\ WG questioned why EPA's...

40 CFR 96.342 - CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false CAIR NOX Ozone Season allowance... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.342 CAIR NOX Ozone Season allowance allocations. (a)(1) The baseline heat input (in mmBtu) used with respect to CAIR NOX Ozone Season allowance...

40 CFR 96.342 - CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false CAIR NOX Ozone Season allowance... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.342 CAIR NOX Ozone Season allowance allocations. (a)(1) The baseline heat input (in mmBtu) used with respect to CAIR NOX Ozone Season allowance...

40 CFR 96.342 - CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false CAIR NOX Ozone Season allowance... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.342 CAIR NOX Ozone Season allowance allocations. (a)(1) The baseline heat input (in mmBtu) used with respect to CAIR NOX Ozone Season allowance...

40 CFR 96.342 - CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false CAIR NOX Ozone Season allowance... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.342 CAIR NOX Ozone Season allowance allocations. (a)(1) The baseline heat input (in mmBtu) used with respect to CAIR NOX Ozone Season allowance...

40 CFR 96.342 - CAIR NOX Ozone Season allowance allocations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 21 2011-07-01 2011-07-01 false CAIR NOX Ozone Season allowance... IMPLEMENTATION PLANS CAIR NOX Ozone Season Allowance Allocations § 96.342 CAIR NOX Ozone Season allowance allocations. (a)(1) The baseline heat input (in mmBtu) used with respect to CAIR NOX Ozone Season allowance...

Inquiry Based Projects Using Student Ozone Measurements and the Status of Using Plants as Bio-Indicators

NASA Astrophysics Data System (ADS)

Ladd, I. H.; Fishman, J.; Pippin, M.; Sachs, S.; Skelly, J.; Chappelka, A.; Neufeld, H.; Burkey, K.

2006-05-01

Students around the world work cooperatively with their teachers and the scientific research community measuring local surface ozone levels using a hand-held optical scanner and ozone sensitive chemical strips. Through the GLOBE (Global Learning and Observations to Benefit the Environment) Program, students measuring local ozone levels are connected with the chemistry of the air they breathe and how human activity impacts air quality. Educational tools have been developed and correlated with the National Science and Mathematics Standards to facilitate integrating the study of surface ozone with core curriculum. Ozone air pollution has been identified as the major pollutant causing foliar injury to plants when they are exposed to concentrations of surface ozone. The inclusion of native and agricultural plants with measuring surface ozone provides an Earth system approach to understanding surface ozone. An implementation guide for investigating ozone induced foliar injury has been developed and field tested. The guide, Using Sensitive Plants as Bio-Indicators of Ozone Pollution, provides: the background information and protocol for implementing an "Ozone Garden" with native and agricultural plants; and, a unique opportunity to involve students in a project that will develop and increase their awareness of surface ozone air pollution and its impact on plants.

The Utility of the OMI HCHO and NO2 Data Products in Air Quality Decision- Making Activities

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.

2010-01-01

We will present three related air quality applications of the OMI HCHO (formaldehyde) and NO2 (nitrogen dioxide) data products, which we us to support mission planning of an OMI-like instrument for the proposed GEO-CAPE satellite that has as one of its objectives to study air quality from space. First, we will discuss a novel and practical application of the data products to the "weight of evidence" in the air quality decision-making process (e.g., State Implementation Plan (SIP)) for a city, region, or state to demonstrate that it is making progress toward attainment of the National Ambient Air Quality Standard (NAAQS) for ozone. Any trend, or lack thereof, in the observed OMI HCHO/NO2, which we use as an air quality indicator, may support that an emission control strategy implemented to reduce ozone is or is not occurring for a metropolitan area. Second, we will discuss how we use variations in the OMI HCHO product as a proxy for variability in the biogenic hydrocarbon, isoprene, which is an important player for the formation of high levels of ozone and the dominant source of HCHO in the eastern U.S. Third, we will discuss the variability of NO2 in the U.S. as indicated by the OMI NO2 product. In addition, we will show the impact of the 2005 hurricanes on pollutant emissions, including those associated with the intensive oil extraction and refining activities, in the Gulf of Mexico region using the OMI NO2 product. The variability of HCHO and NO2 as indicated by OMI helps us to understand changes in the OMI HCHO/NO2 and the implications for ozone formation.

76 FR 14805 - Approval and Promulgation of Air Quality Implementation Plans; New Hampshire; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-18

... Implementation Plans (SIPs) related to attainment of the 1997 8-hour ozone NAAQS for so long as the area... related to attainment of the 1997 8-hour ozone NAAQS for this area, for so long as the area continues to... moderate 1997 8-hour ozone nonattainment area has attained the 1997 8-hour National Ambient Air Quality...

In-situ Measurements of Ozone Production Rates and Comparisons to Model-derived Production Rates During the Houston, TX and Denver, CO DISCOVER-AQ Campaigns

NASA Astrophysics Data System (ADS)

Baier, B. C.; Brune, W. H.; Miller, D. O.; Lefer, B. L.

2015-12-01

Tropospheric ozone (O3) is a secondary pollutant that has harmful effects on human and plant life. The climate and urban emissions in Houston, TX and Denver, CO can be conducive for significant ozone production and thus, high ozone events. Tighter government strategies for ozone mitigation have been proposed, which involve reducing the current EPA eight-hour ozone standard from 75 ppb to 65-70 ppb. These strategies rely on the reduction of ozone precursors in order to decrease the ozone production rate, P(O3). The changes in the ozone concentration at a certain location are dependent upon P(O3), so decreasing P(O3) can decrease ozone levels provided that it has not been transported from other areas. Air quality models test reduction strategies before they are implemented, locate ozone sources, and predict ozone episodes. Traditionally, P(O3) has been calculated by models. However, large uncertainties in model emissions inventories, chemical mechanisms, and meteorology can reduce confidence in this approach. A new instrument, the Measurement of Ozone Production Sensor (MOPS) directly measures P(O3) and can provide an alternate approach to determining P(O3). An updated version of the Penn State MOPS (MOPSv2.0) was deployed to Houston, TX and Denver, CO as a part of NASA's DISCOVER-AQ field campaign in the summers of 2013 and 2014, respectively. We present MOPS directly-measured P(O3) rates from these areas, as well as comparisons to zero-dimensional and three-dimensional modeled P(O3) using the RACM2 and MCMv2.2 mechanisms. These comparisons demonstrate the potential of the MOPS to test and evaluate model-derived P(O3), to advance the understanding of model chemical mechanisms, and to improve predictions of high ozone events.

78 FR 17161 - Approval and Promulgation of Air Quality Implementation Plans; District of Columbia, Maryland and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-20

... 1997 ozone NAAQS which revised the health-based NAAQS for ozone by setting the NAAQS at 0.08 parts per... evidence demonstrating that ozone causes adverse health effects at lower ozone concentrations and over... determined that the 1997 ozone NAAQS would be more protective of human health, especially for children and...

77 FR 71129 - Revisions to the California State Implementation Plan, San Joaquin Valley United Air Pollution...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-29

... Register on June 21, 2012 and concerns volatile organic compound (VOC) emissions from chipping and grinding... Organic Material 8/18/11 11/18/11 Composting Operations. We proposed to approve these rules because we... ozone forming volatile organic compound (VOC) emissions from greenwaste composting that contains food...

77 FR 44560 - Revisions to the Nevada State Implementation Plan, Washoe County Air Quality District

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-30

... emissions of criteria pollutants such as volatile organic compounds (VOC), oxides of nitrogen (NO X ), and... to, mass balance types of analysis, be made by the operator. Section 030.970A, Part 70 Permit... relations, Nitrogen dioxide, Ozone, Particulate matter, Reporting and recordkeeping requirements, Volatile...

75 FR 45209 - Federal Implementation Plans To Reduce Interstate Transport of Fine Particulate Matter and Ozone

Federal Register 2010, 2011, 2012, 2013, 2014

2010-08-02

... 1. What is the source of EPA's authority for this action? 2. What air quality problems does this... non-attainment or maintenance problems, the remaining exceedances occur almost entirely in the winter... to which this wintertime problem is caused by emissions transported from upwind states. Further study...

75 FR 55711 - Federal Implementation Plans To Reduce Interstate Transport of Fine Particulate Matter and Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-14

... Matter and Ozone; Correction AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed rule..., Nitrogen oxides, Ozone, Particulate matter, Regional haze, Reporting and recordkeeping requirements, Sulfur...

40 CFR 52.582 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.582 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Georgia § 52.582 Control strategy: Ozone. (a) Approval... area has attaining data for the 1997 8-hour ozone NAAQS. This determination, in accordance with 40 CFR...

40 CFR 52.476 - Control strategy: ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: ozone. 52.476 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS District of Columbia § 52.476 Control strategy: ozone. (a... of Progress Plan for the District of Columbia's portion of the Metropolitan Washington, D.C. ozone...

40 CFR 52.476 - Control strategy: ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: ozone. 52.476 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS District of Columbia § 52.476 Control strategy: ozone. (a... of Progress Plan for the District of Columbia's portion of the Metropolitan Washington, D.C. ozone...

40 CFR 52.582 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.582 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Georgia> § 52.582 Control strategy: Ozone. Link to an... of the user, the added text is set forth as follows: § 52.582 Control strategy: Ozone. (d...

40 CFR 52.523 - Control strategy: Ozone

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Ozone 52.523 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Florida § 52.523 Control strategy: Ozone (a) Disapproval. EPA is disapproving portions of Florida's infrastructure SIP for the 1997 8-hour ozone NAAQS regarding...

40 CFR 52.476 - Control strategy: ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: ozone. 52.476 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS District of Columbia § 52.476 Control strategy: ozone. (a... of Progress Plan for the District of Columbia's portion of the Metropolitan Washington, D.C. ozone...

40 CFR 52.523 - Control strategy: Ozone

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Ozone 52.523 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Florida § 52.523 Control strategy: Ozone (a) Disapproval. EPA is disapproving portions of Florida's infrastructure SIP for the 1997 8-hour ozone NAAQS regarding...

40 CFR 52.377 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.377 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Connecticut § 52.377 Control strategy: Ozone. Link to an... Air Act, for the Greater Hartford serious ozone nonattainment area, and the Connecticut portion of the...

40 CFR 52.476 - Control strategy: ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: ozone. 52.476 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS District of Columbia § 52.476 Control strategy: ozone. (a... of Progress Plan for the District of Columbia's portion of the Metropolitan Washington, D.C. ozone...

40 CFR 52.476 - Control strategy: ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy: ozone. 52.476 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS District of Columbia § 52.476 Control strategy: ozone. (a... of Progress Plan for the District of Columbia's portion of the Metropolitan Washington, D.C. ozone...

40 CFR 52.582 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.582 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Georgia § 52.582 Control strategy: Ozone. (a) Approval... area has attaining data for the 1997 8-hour ozone NAAQS. This determination, in accordance with 40 CFR...

40 CFR 52.582 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.582 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Georgia § 52.582 Control strategy: Ozone. (a) Approval... area has attaining data for the 1997 8-hour ozone NAAQS. This determination, in accordance with 40 CFR...

40 CFR 52.377 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.377 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Connecticut § 52.377 Control strategy: Ozone. Link to an... the Greater Hartford serious ozone nonattainment area, and the Connecticut portion of the NY-NJ-CT...

Effects of different representations of transport in the new EMAC-SWIFT chemistry climate model

NASA Astrophysics Data System (ADS)

Scheffler, Janice; Langematz, Ulrike; Wohltmann, Ingo; Kreyling, Daniel; Rex, Markus

2017-04-01

It is well known that the representation of atmospheric ozone chemistry in weather and climate models is essential for a realistic simulation of the atmospheric state. Interactively coupled chemistry climate models (CCMs) provide a means to realistically simulate the interaction between atmospheric chemistry and dynamics. The calculation of chemistry in CCMs, however, is computationally expensive which renders the use of complex chemistry models not suitable for ensemble simulations or simulations with multiple climate change scenarios. In these simulations ozone is therefore usually prescribed as a climatological field or included by incorporating a fast linear ozone scheme into the model. While prescribed climatological ozone fields are often not aligned with the modelled dynamics, a linear ozone scheme may not be applicable for a wide range of climatological conditions. An alternative approach to represent atmospheric chemistry in climate models which can cope with non-linearities in ozone chemistry and is applicable to a wide range of climatic states is the Semi-empirical Weighted Iterative Fit Technique (SWIFT) that is driven by reanalysis data and has been validated against observational satellite data and runs of a full Chemistry and Transport Model. SWIFT has been implemented into the ECHAM/MESSy (EMAC) chemistry climate model that uses a modular approach to climate modelling where individual model components can be switched on and off. When using SWIFT in EMAC, there are several possibilities to represent the effect of transport inside the polar vortex: the semi-Lagrangian transport scheme of EMAC and a transport parameterisation that can be useful when using SWIFT in models not having transport of their own. Here, we present results of equivalent simulations with different handling of transport, compare with EMAC simulations with full interactive chemistry and evaluate the results with observations.

Transport and deposition of nitrogen oxides and ozone in the atmospheric surface layer

NASA Astrophysics Data System (ADS)

Li, Yongxian

Tropospheric ozone is an important photochemical air pollutant, which increases respiratory-related diseases, decreases crop yields, and causes other environmental problems. This research has focused on the measurement of soil biogenic emissions of nitric oxide (NO), one of the precursors for ozone formation, from intensively managed soils in the Southeast US, and examined the transport and deposition of NOx (NO + NO2) and ozone in the atmospheric surface layer, and the effects of NO emissions and its chemical reactions on ozone flux and deposition to the earth's surface. Emissions of nitric oxide were measured from an intensively managed agricultural soil, in the lower coastal plain of North Carolina (near Plymouth, NC), using a dynamic chamber technique. Measurements of soil NO emissions in several crop canopies were conducted at four different sites in North Carolina during late spring and summer of 1994-1996. The turbulent fluxes of NO2 and O3 at 5 m and 10 m above the ground were measured using the eddy-correlation technique near Plymouth, NC during late spring of 1995 and summer of 1996, concurrent with measurements of soil NO emissions using the dynamic chamber system. Soil NO emission from within the corn field was high averaging approximately 35 ng N/m2/s during the measurement period of 1995. In another study, vertical measurements of ozone were made on a 610 m tall tower located 15 km Southeast of Raleigh, NC during the summers of 1993-1997, as part of an effort by the State of North Carolina to develop a State Implementation Plan (SIP) for ozone control in the Raleigh Metropolitan Statistical Area. A strong correlation was observed between the nighttime and early morning ozone concentrations in the residual layer (CR) above the NBL and the maximum ground level concentration (C o max) the following afternoon. Based on this correlation, an empirical regression equation (Co max = 27.67*exp(0.016 CR)) was developed for predicting maximum ground level ozone concentrations during the summer months. (Abstract shortened by UMI.)

40 CFR 52.377 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.377 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Connecticut § 52.377 Control strategy: Ozone. (a... requirements of sections 172(c)(9) and 182(c)(9) of the Clean Air Act, for the Greater Hartford serious ozone...

40 CFR 52.377 - Control strategy: Ozone.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: Ozone. 52.377 Section...) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Connecticut § 52.377 Control strategy: Ozone. (a... requirements of sections 172(c)(9) and 182(c)(9) of the Clean Air Act, for the Greater Hartford serious ozone...

77 FR 14712 - Approval and Promulgation of Air Quality Implementation Plans; Massachusetts; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-03-13

... Massachusetts Department of Environmental Protection performed a missing data analysis for each site with low... Massachusetts missing data analysis used a combination of meteorology and air quality data for ozone monitors... with missing ozone data, the ozone levels, if captured, would have been below the 1997 8-hour ozone...

78 FR 68377 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Ohio NOX

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-14

...On November 15, 2010, Ohio EPA submitted to EPA revisions to Ohio OAC 3745-14. EPA is proposing to approve these revisions under the Clean Air Act, which allows for Ohio's Clean Air Interstate Rule (CAIR) NOX Ozone Season Trading Program rules to supersede Ohio's nitrogen oxides (NOX) State Implementation Plan (SIP) Call Budget Trading Program rules, but leave other requirements of the NOX SIP Call in place for units not covered by CAIR.

77 FR 2677 - EPA Responses to State and Tribal 2008 Ozone Designation Recommendations; Extension of Public...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-19

... State and Tribal 2008 Ozone Designation Recommendations; Extension of Public Comment Period AGENCY... and tribal ozone designation recommendations for the 2008 Ozone National Ambient Air Quality Standards... designation determinations for the 2008 ozone standards in spring 2012. DATES: Comments must be received on or...

77 FR 42997 - Approval and Promulgation of Implementation Plans; Tennessee; 110(a)(1) and (2) Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-23

...-Hour Ozone National Ambient Air Quality Standards AGENCY: Environmental Protection Agency (EPA). ACTION... ambient air quality standards (NAAQS). Section 110(a) of the CAA requires that each state adopt and submit... National Ambient Air Quality Standards.'' \\1\\ Two elements identified in section 110(a)(2) are not governed...

77 FR 58032 - Approval and Promulgation of Implementation Plans; New Mexico; Albuquerque/Bernalillo County...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-19

... prevention of significant deterioration (PSD) measures required in the SIP of any other state, with regard to... modify the PSD SIP to include nitrogen oxides (NO X ) as an ozone precursor. EPA is approving revisions to the Albuquerque/Bernalillo County PSD SIP that identify the PM 2.5 precursors and establish...

76 FR 27973 - Approval and Promulgation of Air Quality Implementation Plans; State of Delaware; Regional Haze...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-13

... Ozone National Ambient Air Quality Standard (NAAQS) and the 1997 and 2006 fine particulate matter (PM 2... particle precursors react in the atmosphere to form fine particulate matter, which impairs visibility by... distance, in kilometers or miles, at which a dark object can be viewed against the sky. B. Background...

Dynamic evaluation of CMAQ part I: Separating the effects of ...

EPA Pesticide Factsheets

A dynamic evaluation of the Community Multiscale Air Quality (CMAQ) modeling system version 5.0.1 was conducted to evaluate the model's ability to predict changes in ozone levels between 2002 and 2005, a time period characterized by emission reductions associated with the EPA's Nitrogen Oxides State Implementation Plan as well as significant reductions in mobile source emissions. Model results for the summers of 2002 and 2005 were compared to simulations from a previous version of CMAQ to assess the impact of model updates on predicted pollutant response. Changes to the model treatment of emissions, meteorology and chemistry had substantial impacts on the simulated ozone concentrations. While the median bias for high summertime ozone decreased in both years compared to previous simulations, the observed decrease in ozone from 2002 to 2005 in the eastern US continued to be underestimated by the model. Additional “cross” simulations were used to decompose the model predicted change in ozone into the change due to emissions, the change due to meteorology and any remaining change not explained individually by these two components. The decomposition showed that the emission controls led to a decrease in modeled high summertime ozone close to twice as large as the decrease attributable to changes in meteorology alone. Quantifying the impact of retrospective emission controls by removing the impacts of meteorology during the control period can be a valuable approac

75 FR 27514 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-17

... vehicular traffic are also subject to increased ozone levels because wind carries ozone and its precursors... ozone triggers a variety of health problems including aggravated asthma, reduced lung capacity, and... is called the design value (DV). The DV indicates the severity of the ozone problem in an area; it is...

77 FR 50966 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Attainment Demonstration...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-23

... moderate 8-hour ozone nonattainment area? In 1997, EPA revised the health-based NAAQS for ozone, setting it... standard based on scientific evidence demonstrating that ozone causes adverse health effects at lower ozone... was set. EPA determined that the 1997 8-hour standard would be more protective of human health...

75 FR 36316 - Approval and Promulgation of Air Quality Implementation Plans; Louisiana; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-25

... the 1997 8-hour ozone NAAQS would be suspended for so long as the area continues to attain the ozone... proposing to determine that the Baton Rouge, Louisiana moderate 1997 8-hour ozone nonattainment area has attained the 1997 8-hour National Ambient Air Quality Standard (NAAQS) for ozone. This proposed...

Health Benefits of Decreases in PM2.5 and Ozone in the United States from 1998 to 2016

NASA Astrophysics Data System (ADS)

Nawaz, O.; Zhang, Y.; Tong, D.; van Donkelaar, A.; Martin, R.; West, J. J.

2017-12-01

Between 1990 and 2015 the US average concentration of PM2.5 decreased by 37% and ozone decreased by 22%, driven by environmental regulations and technological advances. These decreases in pollutants are expected to have brought substantial benefits for public health in the US. Here we assess the effects of this decrease by estimating the total burden of PM2.5 and ozone on premature mortality, each year between 1998-2016. Two data sets of ambient concentration were implemented in the health impact analysis that included different subsets of the time period. First, we use data from the North American Chemical Reanalysis project, which uses OMI NO2 and MODIS AOD observations for data assimilation to constrain ozone and PM2.5 between 2009-2016. Second, we use satellite-derived estimates of ground-level PM2.5 using AOD retrievals from NASA satellites combined with the GEOS-Chem chemical transport model between 1998-2015; these estimates are calibrated to ground-based observations using a geographically weighted regression. Using yearly data on population and baseline mortality provided by the Centers for Disease Control (CDC), we assess how air pollution-related mortality has changed annually within the continental United States, and analyze trends to determine how effectively the health burden has been reduced by environmental regulations and other factors.

Present state of knowledge of the upper atmosphere: An assessment report

NASA Technical Reports Server (NTRS)

1984-01-01

A program of research, technology, and monitoring of the phenomena of the upper atmosphere, to provide for an understanding of and to maintain the chemical and physical integrity of the Earth's upper atmosphere was developed. NASA implemented a long-range upper atmospheric science program aimed at developing an organized, solid body of knowledge of upper atmospheric processes while providing, in the near term, assessments of potential effects of human activities on the atmosphere. The effects of chlorofluorocarbon (CFC) releases on stratospheric ozone were reported. Issues relating the current understanding of ozone predictions and trends and highlights recent and future anticipated developments that will improve our understanding of the system are summarized.

40 CFR 97.510 - State NOX Ozone Season trading budgets, new unit set-asides, Indian country new unit set-aside...

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 22 2012-07-01 2012-07-01 false State NOX Ozone Season trading budgets... BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS TR NOX Ozone Season Trading Program § 97.510 State NOX Ozone Season trading budgets, new unit set-asides, Indian country new unit set-aside, and...

40 CFR 97.510 - State NOX Ozone Season trading budgets, new unit set-asides, Indian country new unit set-aside...

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 22 2013-07-01 2013-07-01 false State NOX Ozone Season trading budgets... BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS TR NOX Ozone Season Trading Program § 97.510 State NOX Ozone Season trading budgets, new unit set-asides, Indian country new unit set-aside, and...

40 CFR 97.510 - State NOX Ozone Season trading budgets, new unit set-asides, Indian country new unit set-aside...

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 21 2014-07-01 2014-07-01 false State NOX Ozone Season trading budgets... BUDGET TRADING PROGRAM AND CAIR NOX AND SO2 TRADING PROGRAMS TR NOX Ozone Season Trading Program § 97.510 State NOX Ozone Season trading budgets, new unit set-asides, Indian country new unit set-aside, and...

77 FR 28338 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Reasonably Available...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-14

... Promulgation of Air Quality Implementation Plans; Maryland; Reasonably Available Control Technology for the 1997 8-Hour Ozone National Ambient Air Quality Standard AGENCY: Environmental Protection Agency (EPA... available control technology (RACT) for the 1997 8-hour ozone national ambient air quality standard (NAAQS...

77 FR 65488 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; Attainment Demonstration...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-29

... national ambient air quality standard (NAAQS) for the Philadelphia-Wilmington-Atlantic City, PA-NJ-MD-DE..., Air pollution control, Incorporation by reference, Nitrogen dioxide, Ozone, Reporting and... Promulgation of Air Quality Implementation Plans; Maryland; Attainment Demonstration for the 1997 8-Hour Ozone...

National trends in ozone injury to forest plants: 16 years of biomonitoring

Treesearch

Gretchen Smith

2013-01-01

The ozone indicator, an important research component of the Forest Health Monitoring (FHM) Program of the Forest Service, U.S. Department of Agriculture, was developed and implemented to address specific concerns about the negative effects of ground-level ozone pollution on forest health and productivity. Ozone is a highly toxic air contaminant that has been shown...

78 FR 7672 - Approval and Promulgation of Implementation Plans; Texas; Beaumont/Port Arthur Ozone Maintenance...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-04

.... SUMMARY: EPA is approving a revision to the Beaumont/Port Arthur (BPA) 1997 8-hour ozone maintenance air... emissions model. The BPA 1997 8-hour ozone maintenance area consists of Hardin, Jefferson, and Orange... proposed to approve a revision to the BPA 1997 8-hour ozone maintenance air quality SIP by replacing the...

Ozone Research with Advanced Cooperative Lidar Experiment (ORACLE) Implementation Study

NASA Technical Reports Server (NTRS)

Stadler, John H.; Browell, Edward V.; Ismail, Syed; Dudelzak, Alexander E.; Ball, Donald J.

1998-01-01

New technological advances have made possible new active remote sensing capabilities from space. Utilizing these technologies, the Ozone Research with Advanced Cooperative Lidar Experiment (ORACLE) will provide high spatial resolution measurements of ozone, clouds and aerosols in the stratosphere and lower troposphere. Simultaneous measurements of ozone, clouds and aerosols will assist in the understanding of global change, atmospheric chemistry and meteorology.

The Observed Response of Ozone Monitoring Instrument (OMI) NO2 Columns to NOx Emission Controls on Power Plants in the United States: 2005-2011

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; deFoy, Benjamin; Lamsal, Lok N.; Streets, David G.; Lu, Zifeng; Pickering, Kenneth E.; Krotkov, Nickolay A.

2013-01-01

We show that Aura Ozone Monitoring Instrument (OMI) nitrogen dioxide (NO2) tropospheric column data may be used to assess changes of the emissions of nitrogen oxides (NOx) from power plants in the United States, though careful interpretation of the data is necessary. There is a clear response for OMI NO2 data to NOx emission reductions from power plants associated with the implementation of mandated emission control devices (ECDs) over the OMI record (2005e2011). This response is scalar for all intents and purposes, whether the reduction is rapid or incremental over several years. However, it is variable among the power plants, even for those with the greatest absolute decrease in emissions. We document the primary causes of this variability, presenting case examples for specific power plants.

76 FR 56975 - Approval and Promulgation of Air Quality Implementation Plans; West Virginia; Revised Motor...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-15

... Wheeling 8-hour ozone maintenance areas. This revision amends the maintenance plans' 2009 and 2018 motor... Revision and EPA's Review III. Final Action IV. Statutory and Executive Order Reviews I. Background On July... Review On March 14, 2011, the State of West Virginia submitted to EPA a formal revision to its SIP. The...

76 FR 11083 - Approval and Promulgation of Implementation Plans; State of Missouri

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-01

... approval into the SIP two new rules, 10 CSR 10-2.385 Control of Heavy Duty Diesel Vehicle Idling Emissions for the Kansas City Ozone Maintenance Area and 10 CSR 10-5.385 Control of Heavy Duty Diesel Vehicle.... II. Why is EPA approving Missouri's SIP revision? The rule 10 CSR 10-2.385 Control of Heavy Duty...

75 FR 42018 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-20

...,'' Memorandum from G. T. Helms, Chief, Ozone/Carbon Monoxide Programs Branch, April 30, 1992; ``Contingency Measures for Ozone and Carbon Monoxide (CO) Redesignations,'' Memorandum from G. T. Helms, Chief, Ozone...,'' Memorandum from G. T. Helms, [[Page 42022

Source apportionment of emissions from light-duty gasoline vehicles and other sources in the United States for ozone and particulate matter.

PubMed

Vijayaraghavan, Krish; Lindhjem, Chris; Koo, Bonyoung; DenBleyker, Allison; Tai, Edward; Shah, Tejas; Alvarez, Yesica; Yarwood, Greg

2016-02-01

Federal Tier 3 motor vehicle emission and fuel sulfur standards have been promulgated in the United States to help attain air quality standards for ozone and PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm). The authors modeled a standard similar to Tier 3 (a hypothetical nationwide implementation of the California Low Emission Vehicle [LEV] III standards) and prior Tier 2 standards for on-road gasoline-fueled light-duty vehicles (gLDVs) to assess incremental air quality benefits in the United States (U.S.) and the relative contributions of gLDVs and other major source categories to ozone and PM2.5 in 2030. Strengthening Tier 2 to a Tier 3-like (LEV III) standard reduces the summertime monthly mean of daily maximum 8-hr average (MDA8) ozone in the eastern U.S. by up to 1.5 ppb (or 2%) and the maximum MDA8 ozone by up to 3.4 ppb (or 3%). Reducing gasoline sulfur content from 30 to 10 ppm is responsible for up to 0.3 ppb of the improvement in the monthly mean ozone and up to 0.8 ppb of the improvement in maximum ozone. Across four major urban areas-Atlanta, Detroit, Philadelphia, and St. Louis-gLDV contributions range from 5% to 9% and 3% to 6% of the summertime mean MDA8 ozone under Tier 2 and Tier 3, respectively, and from 7% to 11% and 3% to 7% of the maximum MDA8 ozone under Tier 2 and Tier 3, respectively. Monthly mean 24-hr PM2.5 decreases by up to 0.5 μg/m(3) (or 3%) in the eastern U.S. from Tier 2 to Tier 3, with about 0.1 μg/m(3) of the reduction due to the lower gasoline sulfur content. At the four urban areas under the Tier 3 program, gLDV emissions contribute 3.4-5.0% and 1.7-2.4% of the winter and summer mean 24-hr PM2.5, respectively, and 3.8-4.6% and 1.5-2.0% of the mean 24-hr PM2.5 on days with elevated PM2.5 in winter and summer, respectively. Following U.S. Tier 3 emissions and fuel sulfur standards for gasoline-fueled passenger cars and light trucks, these vehicles are expected to contribute less than 6% of the summertime mean daily maximum 8-hr ozone and less than 7% and 4% of the winter and summer mean 24-hr PM2.5 in the eastern U.S. in 2030. On days with elevated ozone or PM2.5 at four major urban areas, these vehicles contribute less than 7% of ozone and less than 5% of PM2.5, with sources outside North America and U.S. area source emissions constituting some of the main contributors to ozone and PM2.5, respectively.

40 CFR 82.1 - Purpose and scope.

Code of Federal Regulations, 2011 CFR

2011-07-01

... STRATOSPHERIC OZONE Production and Consumption Controls § 82.1 Purpose and scope. (a) The purpose of the regulations in this subpart is to implement the Montreal Protocol on Substances that Deplete the Ozone Layer... ozone-depleting substances, according to specified schedules. The Protocol also requires each nation...

40 CFR 82.1 - Purpose and scope.

Code of Federal Regulations, 2010 CFR

2010-07-01

... STRATOSPHERIC OZONE Production and Consumption Controls § 82.1 Purpose and scope. (a) The purpose of the regulations in this subpart is to implement the Montreal Protocol on Substances that Deplete the Ozone Layer... ozone-depleting substances, according to specified schedules. The Protocol also requires each nation...

40 CFR 82.1 - Purpose and scope.

Code of Federal Regulations, 2013 CFR

2013-07-01

... STRATOSPHERIC OZONE Production and Consumption Controls § 82.1 Purpose and scope. (a) The purpose of the regulations in this subpart is to implement the Montreal Protocol on Substances that Deplete the Ozone Layer... ozone-depleting substances, according to specified schedules. The Protocol also requires each nation...

40 CFR 82.1 - Purpose and scope.

Code of Federal Regulations, 2014 CFR

2014-07-01

... STRATOSPHERIC OZONE Production and Consumption Controls § 82.1 Purpose and scope. (a) The purpose of the regulations in this subpart is to implement the Montreal Protocol on Substances that Deplete the Ozone Layer... ozone-depleting substances, according to specified schedules. The Protocol also requires each nation...

40 CFR 82.1 - Purpose and scope.

Code of Federal Regulations, 2012 CFR

2012-07-01

... STRATOSPHERIC OZONE Production and Consumption Controls § 82.1 Purpose and scope. (a) The purpose of the regulations in this subpart is to implement the Montreal Protocol on Substances that Deplete the Ozone Layer... ozone-depleting substances, according to specified schedules. The Protocol also requires each nation...

78 FR 6035 - Approval and Promulgation of Air Quality Implementation Plans; Ohio and Indiana; Cincinnati...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-29

... MOBILE6.2 emissions model. The ozone maintenance plan established 2015 and 2020 budgets for the Ohio and...-9773-5] Approval and Promulgation of Air Quality Implementation Plans; Ohio and Indiana; Cincinnati-Hamilton, OH; Ohio and Indiana 1997 8-Hour Ozone Maintenance Plan Revisions to Approved Motor Vehicle...

The study of international and interstate transport of ozone in Yuma, Arizona

NASA Astrophysics Data System (ADS)

Li, Y.; Sonenberg, M.; Wood, J. L.; Pearson, C. R.; Colson, H.; Malloy, J. W.; Pace, M.; Mao, F.; Paul, J.; Busby, B. R.; Parkey, B.; Drago, L.; Franquist, T. S.

2017-12-01

In October 2015, EPA reduced the National Ambient Air Quality Standards (NAAQS) for ozone from 75 parts per billion (ppb) to 70 ppb. Meeting the new standard may be extremely challenging for some areas, including rural Yuma County in the State of Arizona. Yuma County faces unique air quality challenges, since it borders the Mexican states of Baja California and Sonora, and the State of California. The present study investigates the contribution of international and interstate transport of ozone and ozone precursors to episodes of elevated ozone concentrations in Yuma. The Arizona Department of Environmental Quality (ADEQ) merged HYSPLIT modeling outputs with two years of hourly ground ozone monitor data to investigate the potential area contributions to ozone concentrations in Yuma County. This analysis found that elevated ozone concentrations in Yuma in 2014 and 2015 frequently coincided with back-trajectories over both California and Mexico, typically favoring Mexico during the spring. In May 2017, ADEQ installed a new ozone monitor in San Luis Rio Colorado, Sonora, Mexico (Latitude: 32.4665, Longitude: -114.7688), which is 29 km south of ozone site in Yuma County. We will present the first simultaneous observations of ozone seasons in Sonora, Mexico, eastern California, and Yuma.

76 FR 48002 - Approval and Promulgation of Air Quality Implementation Plans; State of California; Interstate...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-08

...EPA is finalizing a limited approval and limited disapproval of a state implementation plan (SIP) revision submitted by the State of California on November 17, 2007, to address the ``transport SIP'' provisions of Clean Air Act (CAA) section 110(a)(2)(D)(i) for the 1997 8-hour ozone National Ambient Air Quality Standards (NAAQS or standards) and the 1997 fine particulate matter (PM2.5) NAAQS. Section 110(a)(2)(D)(i) of the CAA requires that each SIP contain, among other things, adequate measures prohibiting emissions of air pollutants in amounts which will interfere with any other State's measures required under title I, part C of the CAA to prevent significant deterioration of air quality. EPA is approving California's SIP revision with respect to those Districts that implement SIP- approved permit programs meeting the approval criteria and simultaneously disapproving California's SIP revision with respect to those Districts that do not implement SIP-approved permit programs meeting the approval criteria, as discussed in our May 31, 2011 proposed rule (76 FR 31263).

77 FR 64425 - Approval and Promulgation of Implementation Plans; Alaska: Infrastructure Requirements for the...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-22

... Ambient Air Quality Standard AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY... the National Ambient Air Quality Standards (NAAQS) promulgated for ozone on July 18, 1997. EPA finds... measuring and monitoring ozone in ambient air, a general definition of ozone, federal Prevention of...

"OZONE SOURCE APPORTIONMENT IN CMAQ'

EPA Science Inventory

Ozone source attribution has been used to support various policy purposes including interstate transport (Cross State Air Pollution Rule) by U.S. EPA and ozone nonattainment area designations by State agencies. Common scientific applications include tracking intercontinental tran...

Climate variability modulates western US ozone air quality in spring via deep stratospheric intrusions

PubMed Central

Lin, Meiyun; Fiore, Arlene M.; Horowitz, Larry W.; Langford, Andrew O.; Oltmans, Samuel J.; Tarasick, David; Rieder, Harald E.

2015-01-01

Evidence suggests deep stratospheric intrusions can elevate western US surface ozone to unhealthy levels during spring. These intrusions can be classified as ‘exceptional events', which are not counted towards non-attainment determinations. Understanding the factors driving the year-to-year variability of these intrusions is thus relevant for effective implementation of the US ozone air quality standard. Here we use observations and model simulations to link these events to modes of climate variability. We show more frequent late spring stratospheric intrusions when the polar jet meanders towards the western United States, such as occurs following strong La Niña winters (Niño3.4<−1.0 °C). While El Niño leads to enhancements of upper tropospheric ozone, we find this influence does not reach surface air. Fewer and weaker intrusion events follow in the two springs after the 1991 volcanic eruption of Mt. Pinatubo. The linkage between La Niña and western US stratospheric intrusions can be exploited to provide a few months of lead time during which preparations could be made to deploy targeted measurements aimed at identifying these exceptional events. PMID:25964012

78 FR 21296 - Approval and Promulgation of Implementation Plans; New Jersey; Infrastructure SIP for the 1997 8...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-10

... some circumstances, it could prohibit the disclosure of emission data to the public. See 40 CFR 52.1575... to revoke 40 CFR 52.1575. G. Emergency power: Section 110(a)(2)(G) requires states to provide for... 40 CFR 52.1575. EPA is proposing to disapprove New Jersey's submittals for the 1997 8-hour ozone and...

By-passing acidification limitations during the biofiltration of high formaldehyde loads via the application of ozone pulses.

PubMed

García-Pérez, Teresa; Aizpuru, Aitor; Arriaga, Sonia

2013-11-15

A formaldehyde airstream was treated in a biofilter for an extended period of time. During the first 133 days, the reactor was operated without ozone, whereas over the following 82 days ozone was intermittently implemented. The maximum stable elimination capacity obtained without ozone was around 57 g m(-3) h(-1). A greater load could not be treated under these conditions, and no significant formaldehyde removal was maintained for inlet loads greater than 65 g m(-3) h(-1); the activity of microorganisms was then inhibited by the presence of acidic byproducts, and the media acidified (pH<4). The implementation of ozone pulses allowed a stable elimination capacity to be obtained, even at greater loads (74 g m(-3) h(-1)). The effect of ozone on the extra cellular polymeric substances detachment from the biofilm could not be confirmed due to the too low biofilter biomass content. Thus, the results suggest that ozone acted as an in situ pH regulator, preventing acidic byproducts accumulation, and allowing the treatment of high loads of formaldehyde. Copyright © 2013 Elsevier B.V. All rights reserved.

76 FR 36873 - Approval and Promulgation of Implementation Plans and Designations of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-23

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 52 [EPA-R04-OAR-2010-1036-201138; FRL-9322-4] Approval and Promulgation of Implementation Plans and Designations of Areas for Air Quality Planning Purposes... Atlanta, Georgia 1997 8-hour ozone nonattainment area has attained the 1997 8- hour ozone national ambient...

78 FR 19599 - Approval and Promulgation of Implementation Plans; Texas; Reasonably Available Control Technology...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-02

... Promulgation of Implementation Plans; Texas; Reasonably Available Control Technology for the 1997 8-Hour Ozone... (SIP) for the Houston/Galveston/ Brazoria (HGB) 1997 8-Hour ozone nonattainment Area (Area). The HGB... Room between the hours of 8:30am and 4:30 p.m. weekdays except for legal holidays. Contact the person...

Historical Analysis and Charaterization of Ground Level Ozone for Canada and United State

NASA Astrophysics Data System (ADS)

Lin, H.; Li, H.; Auld, H.

2003-12-01

Ground-level ozone has long been recognized as an important health and ecosystem-related air quality concern in Canada and the United States. In this work we seek to understand the characteristics of ground level ozone conditions for Canada and United States to support the Ozone Annex under the Canada-U.S. Air Quality Agreement. Our analyses are based upon the data collected by Canadian National Air Pollution Surveillance (NAPS, the NAPS database has also been expanded to include U.S. EPA ground level ozone data) network. Historical ozone data from 1974 to 2002 at a total of 538 stations (253 Canadian stations and 285 U.S. stations) were statistically analyzed using several methodologies including the Canada Wide Standard (CWS). A more detailed analysis including hourly, daily, monthly, seasonally and yearly ozone concentration distributions and trends was undertaken for 54 stations.

Air quality impacts of distributed power generation in the South Coast Air Basin of California 1: Scenario development and modeling analysis

NASA Astrophysics Data System (ADS)

Rodriguez, M. A.; Carreras-Sospedra, M.; Medrano, M.; Brouwer, J.; Samuelsen, G. S.; Dabdub, D.

Distributed generation (DG) is generally defined as the operation of many small stationary power generators throughout an urban air basin. Although DG has the potential to supply a significant portion of the increased power demands in California and the rest of the United States, it may lead to increased levels of in-basin pollutants and adversely impact urban air quality. This study focuses on two main objectives: (1) the systematic characterization of DG installation in urban air basins, and (2) the simulation of potential air quality impacts using a state-of-the-art three-dimensional computational model. A general and systematic approach is devised to construct five realistic and 21 spanning scenarios of DG implementation in the South Coast Air Basin (SoCAB) of California. Realistic scenarios reflect an anticipated level of DG deployment in the SoCAB by the year 2010. Spanning scenarios are developed to determine the potential impacts of unexpected outcomes. Realistic implementations of DG in the SoCAB result in small differences in ozone and particulate matter concentrations in the basin compared to the baseline simulations. The baseline accounts for population increase, but does not consider any future emissions control measures. Model results for spanning implementations with extra high DG market penetration show that domain-wide ozone peak concentrations increase significantly. Also, air quality impacts of spanning implementations when DG operate during a 6-h period are larger than when the same amount of emissions are introduced during a 24-h period.

77 FR 10350 - Revisions to Federal Implementation Plans To Reduce Interstate Transport of Fine Particulate...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-21

... Matter and Ozone AGENCY: Environmental Protection Agency (EPA). ACTION: Proposed rule. SUMMARY: EPA is...: Interstate Transport of Fine Particulate Matter and Ozone and Correction of SIP Approvals, published August 8... ) and sulfur dioxide (SO 2 ) that contribute harmful levels of fine particle matter and ozone in...

75 FR 62470 - Approval and Promulgation of Implementation Plans and Designations of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-10-12

... Purposes; Tennessee: Knoxville; Determination of Attaining Data for the 1997 8-Hour Ozone Standards AGENCY... make a determination that the Knoxville, Tennessee nonattainment area for the 1997 8-hour ozone..., quality controlled monitoring data from 2007 through 2009. The Knoxville 1997 8-hour ozone nonattainment...

78 FR 17902 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-25

... health (``primary'' NAAQS) and welfare (``secondary'' NAAQS). In 1978, EPA designated the San Diego Air... on scientific evidence demonstrating that ozone causes adverse health effects at lower ozone... was set. EPA determined that the 1997 ozone standard would be more protective of human health...

Can artificial neural networks be used to predict the origin of ozone episodes?

PubMed

Fontes, T; Silva, L M; Silva, M P; Barros, N; Carvalho, A C

2014-08-01

Tropospheric ozone is a secondary pollutant having a negative impact on health and environment. To control and minimize such impact the European Community established regulations to promote a clean air all over Europe. However, when an episode is related with natural mechanisms as Stratosphere-Troposphere Exchanges (STE), the benefits of an action plan to minimize precursor emissions are inefficient. Therefore, this work aims to develop a tool to identify the sources of ozone episodes in order to minimize misclassification and thus avoid the implementation of inappropriate air quality plans. For this purpose, an artificial neural network model - the Multilayer Perceptron - is used as a binary classifier of the source of an ozone episode. Long data series, between 2001 and 2010, considering the ozone precursors, (7)Be activity and meteorological conditions were used. With this model, 2-7% of a mean error was achieved, which is considered as a good generalization. Accuracy measures for imbalanced data are also discussed. The MCC values show a good performance of the model (0.65-0.92). Precision and F1-measure indicate that the model specifies a little better the rare class. Thus, the results demonstrate that such a tool can be used to help authorities in the management of ozone, namely when its thresholds are exceeded due natural causes, as the above mentioned STE. Therefore, the resources used to implement an action plan to minimize ozone precursors could be better managed avoiding the implementation of inappropriate measures. Copyright © 2014 Elsevier B.V. All rights reserved.

Ultraviolet and solar photocatalytic ozonation of municipal wastewater: Catalyst reuse, energy requirements and toxicity assessment.

PubMed

Mecha, Achisa C; Onyango, Maurice S; Ochieng, Aoyi; Momba, Maggy N B

2017-11-01

The present study evaluated the treatment of municipal wastewater containing phenol using solar and ultraviolet (UV) light photocatalytic ozonation processes to explore comparative performance. Important aspects such as catalyst reuse, mineralization of pollutants, energy requirements, and toxicity of treated wastewater which are crucial for practical implementation of the processes were explored. The activity of the photocatalysts did not change significantly even after three consecutive uses despite approximately 2% of the initial quantity of catalyst being lost in each run. Analysis of the change in average oxidation state (AOS) demonstrated the formation of more oxidized degradation products (ΔAOS values of 1.0-1.7) due to mineralization. The energy requirements were determined in terms of electrical energy per order (E EO ) and the collector area per order (A CO ). The E EO (kWh m -3  Order -1 ) values were 26.2 for ozonation, 38-47 for UV photocatalysis and 7-22 for UV photocatalytic ozonation processes. On the other hand, A CO (m 2  m -3  order -1 ) values were 31-69 for solar photocatalysis and 8-13 for solar photocatalytic ozonation. Thus photocatalytic ozonation processes required less energy input compared to the individual processes. The cytotoxicity of the wastewater was analysed using the 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) assay with Vero cells. The cell viability increased from 28.7% in untreated wastewater to 80% in treated wastewater; thus showing that the treated wastewater was less toxic. The effectiveness of photocatalytic ozonation, recovery and reusability of the photocatalysts, as well as detoxification of the wastewater make this low energy consumption process attractive for wastewater remediation. Copyright © 2017 Elsevier Ltd. All rights reserved.

75 FR 75656 - Approval and Promulgation of Air Quality Implementation Plans; New Hampshire; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-06

... 51.902(a)), EPA is proposing to determine that this area has attained the 1997 ozone NAAQS by its... implementation rule (see 40 CFR 51.902(a)), EPA is proposing to determine that this area has attained the 1997... 1997 8-hour ozone nonattainment area continues to attain the 1997 8-hour National Ambient Air Quality...

77 FR 75383 - Approval and Promulgation of Air Quality Implementation Plans; Illinois; Infrastructure SIP...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-20

... Requirements for the 2006 PM 2.5 NAAQS; Revisions to FIPs To Reduce Interstate Transport of PM 2.5 and Ozone..., 2011, and February 21, 2012, actions pertain to Federal Implementation Plans (FIPs) to reduce... August 8, 2011, (76 FR 48208), EPA published FIPs to reduce interstate transport of PM 2.5 and ozone. It...

Ozone trends over the United States at different times of day

NASA Astrophysics Data System (ADS)

Yan, Yingying; Lin, Jintai; He, Cenlin

2018-01-01

In the United States, the decline of summertime daytime peak ozone in the last 20 years has been clearly connected to reductions in anthropogenic emissions. However, questions remain about how and through what mechanisms ozone at other times of day have changed over recent decades. Here we analyze the interannual variability and trends of ozone at different hours of day, using observations from about 1000 US sites during 1990-2014. We find a clear diurnal cycle both in the magnitude of ozone trends and in the relative importance of climate variability versus anthropogenic emissions to ozone changes. Interannual climate variability has mainly been associated with the detrended fluctuation in the US annual daytime ozone over 1990-2014, with a much smaller effect on the nighttime ozone. Reductions in anthropogenic emissions of nitrogen oxides have led to substantial growth in the US annual average nighttime ozone due to reduced ozone titration, while the summertime daytime ozone has declined. Environmental policymaking might consider further improvements to reduce ozone levels at night and other non-peak hours.

Ozone trends over the United States at different times of day

NASA Astrophysics Data System (ADS)

Lin, J.; Yan, Y.

2017-12-01

In the United States, the decline of summertime daytime peak ozone in the last 20 years has been clearly connected to reductions in anthropogenic emissions. Yet questions remain on how and through what mechanisms ozone at other times of day have changed over the recent decades. Here we analyze the interannual variability and trends of ozone at different hours of day, using observations from about 1000 US sites during 1990-2014. We find a clear diurnal cycle both in the magnitude of ozone trends and in the relative importance of climate variability versus anthropogenic emissions to ozone changes. Interannual climate variability has mainly been associated with the de-trended fluctuation in the US annual daytime ozone over 1990-2014, with a much smaller effect on the nighttime ozone. Reductions in anthropogenic emissions of nitrogen oxides have led to substantial growth in the US annual average nighttime ozone due to reduced ozone titration, while the summertime daytime ozone has declined. Environmental policymaking might consider further improvements to reduce ozone levels at night and other non-peak hours.

76 FR 70940 - Approval and Promulgation of Air Quality Implementation Plans; Oklahoma; Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-16

... for the 1997 8-hour ozone NAAQS and the 1997 and 2006 PM 2.5 NAAQS: 110(a)(2)(A), (B), (C), (D)(ii... in Oklahoma do not interfere with measures required in the SIP of any other state under part C of the... action is being taken under section 110 and part C of the Act. DATES: Comments must be received on or...

The Utility of the OMI HCHO/NO2 in Air Quality Decision-Making Activities

NASA Technical Reports Server (NTRS)

Duncan, Bryan

2010-01-01

I will discuss a novel and practical application of the OMI HCHU and NO2 data products to the "weight of evidence" in the air quality decision-making process (e.g., State Implementation Plan (SIP)) for a city, region, or state to demonstrate that it is making progress toward attainment of the National Ambient Air Quality Standard (NAAQS) for ozone. Any trend, or lack thereof, in the observed OMI HCHO/NO2 may support that an emission control strategy implemented to reduce ozone is or is not occurring for a metropolitan area. In addition, the observed OMI HCHO/NO2 may be used to define new emission control strategies as the photochemical environments of urban areas evolve over time. I will demonstrate the utility of the OMI HCHO/NO2 over the U.S. for air quality applications with support from simulations with both a regional model and a photochemical box model. These results support mission planning of an OMI-like instrument for the proposed GEO-CAPE satellite that has as one of its objectives to study air quality from space. However, I'm attending the meeting as the Aura Deputy Project Scientist, so I don't technically need to present anything to justify the travel.

76 FR 14626 - Approval and Promulgation of Implementation Plans; Kentucky; 110(a)(1) and (2) Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-17

... provide relevant data for the purpose of predicting the effect on ambient air quality of the 8-hour ozone... the 1997 8-Hour Ozone National Ambient Air Quality Standards AGENCY: Environmental Protection Agency... Act) for the 1997 8-hour ozone national ambient air quality standards (NAAQS). Section 110(a) of the...

76 FR 63251 - Revisions to Federal Implementation Plans To Reduce Interstate Transport of Fine Particulate...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-10-12

... Matter and Ozone AGENCY: Environmental Protection Agency (EPA). ACTION: Announcement of public hearing... Ozone'', which was signed on October 6, 2011 and posted on EPA's website on October 6, 2011. The hearing... Particulate Matter and Ozone and Correction of SIP Approvals). EPA is proposing to amend the assurance penalty...

77 FR 66398 - Partial Approval and Disapproval of Air Quality Implementation Plans; Arizona; Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-05

... Ozone and Fine Particulate Matter AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule...- hour ozone national ambient air quality standards (NAAQS) and the 1997 and 2006 NAAQS for fine..., 1997, EPA issued a revised NAAQS for ozone \\1\\ and a new NAAQS for fine particulate matter (PM 2.5 ).\\2...

75 FR 958 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; 2002 Base Year Emission...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-07

... standard would be more protective of human health, especially children and adults who are active outdoors... 1997, EPA revised the health-based NAAQS for ozone, setting it at 0.08 parts per million (ppm) averaged... that ozone causes adverse health effects at lower ozone concentrations and over longer periods of time...

78 FR 55029 - Approval and Promulgation of Implementation; Texas; Houston: Reasonable Further Progress Plan...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-09

... 1997 (62 FR 38856), the EPA revised the health-based NAAQS for ozone, setting it at 0.08 parts per... scientific evidence demonstrating that ozone causes adverse health effects at lower ozone concentrations and.... The EPA determined that the 8-hour standard would be more protective of human health, especially...

78 FR 29032 - Approval and Promulgation of Implementation Plans Tennessee: Revisions to Volatile Organic...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-17

... tropospheric ozone formation. The compounds were added by EPA through a rulemaking action which provided for... consistent with federal law. Tropospheric ozone, commonly known as smog, occurs when VOC and nitrogen oxide (NO X ) react in the atmosphere. Because of the harmful health effects of ozone, EPA limits the amount...

75 FR 29671 - Approval and Promulgation of Air Quality Implementation Plans: Florida; Approval of Section 110(a...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-05-27

... how each area will continue attainment of the 1997 8-hour ozone NAAQS, and provide contingency... one of these areas is found to violate the 1997 ozone standards, the contingency plan section of each... returns to maintenance of the 1997 ozone standards. Please see section (d) Contingency Plan, below, for...

75 FR 2091 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-14

... computed 3-year average ozone concentration of 0.085 ppm is the smallest value that is greater than 0.08..., April 30, 1992; 3. ``Contingency Measures for Ozone and Carbon Monoxide (CO) Redesignations... includes contingency measures to remedy future violations of the 1997 8-hour ozone NAAQS. The maintenance...

Cogeneration and beyond: The need and opportunity for high efficiency, renewable community energy systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gleason, T.C.J.

1992-06-01

The justification, strategies, and technology options for implementing advanced district heating and cooling systems in the United States are presented. The need for such systems is discussed in terms of global warming, ozone depletion, and the need for a sustainable energy policy. Strategies for implementation are presented in the context of the Public Utilities Regulatory Policies Act and proposed new institutional arrangements. Technology opportunities are highlighted in the areas of advanced block-scale cogeneration, CFC-free chiller technologies, and renewable sources of heating and cooling that are particularly applicable to district systems.

Using Ozone Lidar to Investigate Sources of High Ozone Concentrations in the Western United States

NASA Astrophysics Data System (ADS)

Senff, C. J.; Langford, A. O.; Alvarez, R. J.; Brewer, Wm. A.; Banta, R. M.; Marchbanks, R. D.; Sandberg, S. P.; Weickmann, A. M.; Holloway, J. S.; Williams, E. J.

2016-06-01

We have used NOAA's Tunable Optical Profiler for Aerosol and oZone (TOPAZ) ozone lidar to investigate the sources of high surface ozone concentrations in two different regions of the western United States (US): the Uintah Basin in northeast Utah and Clark County in southern Nevada, which includes the city of Las Vegas. The Uintah Basin is a booming oil and gas producing region that often suffers from very high wintertime ozone concentrations. Clark County experiences violations of the US ozone standard primarily in spring and early summer despite a lack of any major local pollution sources. TOPAZ lidar observations, in conjunction with surface in situ measurements and model results, provided strong evidence that the high wintertime ozone concentrations in the Uintah Basin are primarily driven by local emissions associated with oil and gas exploration, whereas the Clark County ozone exceedances are often caused by ozone-rich air that is transported from the lower stratosphere all the way down to the earth's surface.

Effects of El Niño on Summertime Ozone Air Quality in the Eastern United States

NASA Astrophysics Data System (ADS)

Shen, Lu; Mickley, Loretta J.

2017-12-01

We investigate the effect of El Niño on maximum daily 8 h average surface ozone over the eastern United States in summer during 1980-2016. El Niño can influence the extratropical climate through the propagation of stationary waves, leading to (1) reduced transport of moist, clean air into the middle and southern Atlantic states and greater subsidence, reduced precipitation, and increased surface solar radiation in this region, as well as (2) intensified southerly flow into the south central states, which here enhances flux of moist and clean air. As a result, each standard deviation increase in the Niño 1 + 2 index is associated with an increase of 1-2 ppbv ozone in the Atlantic states and a decrease of 0.5-2 ppbv ozone in the south central states. These influences can be predicted 4 months in advance. We show that U.S. summertime ozone responds differently to eastern-type El Niño events compared to central-type events.

77 FR 66422 - Approval and Promulgation of Implementation Plans; Arizona; Motor Vehicle Inspection and...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-05

... requirement'' for the Phoenix area under our final rule implementing the 8-hour ozone NAAQS (see 40 CFR 51.900(f) and 51.905(a)(1)) based on the designation of that area as a nonattainment area for the 8-hour... and, for the Phoenix area with respect to ozone, the enhanced performance standard in 40 CFR 51.351...

The reservoir of ozone in the boundary layer of the eastern United States and its potential impact on the global tropospheric ozone budget

NASA Technical Reports Server (NTRS)

Vukovich, F. M.; Fishman, J.; Browell, E. V.

1985-01-01

An analysis of available ozone data in the eastern two-thirds of the United States indicates that a substantial reservoir of ozone is present in the summertime. Five-year mean concentrations range from 40 to 65 ppbv. The reservoir covered an area of several million square kilometers and extends vertically from the surface to 1 to 2 km. The vertical distribution of ozone in the reservoir during midday supports a transport of additional ozone from the boundary layer to the free troposphere. Data are presented demonstrating the potential effect of transport by convective clouds and by the sea breeze circulation - mechanisms by which ozone may be transported out of the boundary layer into the free troposphere. The potential impact of this reservoir on the tropospheric ozone budget is discussed. It is shown that if less than half of the ozone mass in this reservoir is transported to the free troposphere, then the amount of ozone transported out of the boundary layer approximates the amount of ozone transported downward during a tropopause fold event.

Increasing Anthropogenic Emissions in China Offset Air Quality Policy Efforts in Western United States: A Satellite and Modelling Perspective

NASA Astrophysics Data System (ADS)

Boersma, F. F.; Verstraeten, W. W.; Williams, J. E.; Neu, J. L.; Bowman, K. W.; Worden, J.

2014-12-01

Tropospheric ozone is an important greenhouse gas and a global air pollutant originating from photo-chemical oxidation of ozone precursors in the presence of NOX. Eastern Asia has the fastest growing anthropogenic emissions in the world, possibly affecting both the pollution in the local troposphere as well as in the trans-Pacific region. Local measurements over Asia show that tropospheric ozone has increased by 1 to 3% per year since the start of the millennium. This increase is often invoked to explain positive ozone trends observed in western United States, but to date there is no unambiguous evidence showing that enhanced Asian pollution is responsible for these trends. Here we interpret satellite measurements of tropospheric ozone and its precursor nitrate dioxide from the Aura Tropospheric Emission Spectrometer (TES) and Ozone Monitoring Instrument (OMI) using the TM5 global chemistry-transport model to directly show that tropospheric ozone over China has increased by ~10% from 2005-2010 in response to both a ~15% rise in Chinese emissions and an increased downward ozone transport from the stratosphere. What is more, we demonstrate that Chinese export of ozone and its precursors have offset one-third of the reduction in free tropospheric ozone over the western United States that should have occurred during 2005-2010 via emissions reductions associated with air quality policies in the United States. The issue of export and long-range transport of pollution from other countries indicates that global efforts may be required to address both the global as well as the regional air quality and climate change.

77 FR 5706 - Approval and Promulgation of Implementation Plans; Georgia; 110(a)(1) and (2) Infrastructure...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-06

... the 1997 8-Hour Ozone National Ambient Air Quality Standards AGENCY: Environmental Protection Agency... the 1997 8-hour ozone national ambient air quality standards (NAAQS). Section 110(a) of the CAA... 110(a)(1) and (2) for the 1997 8-Hour Ozone and PM 2.5 National Ambient Air Quality Standards.'' \\1...

40 CFR 51.910 - What requirements for reasonable further progress (RFP) under sections 172(c)(2) and 182 apply...

Code of Federal Regulations, 2010 CFR

2010-07-01

...-hour ozone NAAQS? 51.910 Section 51.910 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.910 What... nonattainment for the 8-hour ozone NAAQS? (a) What are the general requirements for RFP for an area classified...

40 CFR 51.910 - What requirements for reasonable further progress (RFP) under sections 172(c)(2) and 182 apply...

Code of Federal Regulations, 2011 CFR

2011-07-01

...-hour ozone NAAQS? 51.910 Section 51.910 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.910 What... nonattainment for the 8-hour ozone NAAQS? (a) What are the general requirements for RFP for an area classified...

40 CFR 51.910 - What requirements for reasonable further progress (RFP) under sections 172(c)(2) and 182 apply...

Code of Federal Regulations, 2013 CFR

2013-07-01

...-hour ozone NAAQS? 51.910 Section 51.910 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.910 What... nonattainment for the 8-hour ozone NAAQS? (a) What are the general requirements for RFP for an area classified...

40 CFR 51.910 - What requirements for reasonable further progress (RFP) under sections 172(c)(2) and 182 apply...

Code of Federal Regulations, 2012 CFR

2012-07-01

...-hour ozone NAAQS? 51.910 Section 51.910 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.910 What... nonattainment for the 8-hour ozone NAAQS? (a) What are the general requirements for RFP for an area classified...

40 CFR 51.910 - What requirements for reasonable further progress (RFP) under sections 172(c)(2) and 182 apply...

Code of Federal Regulations, 2014 CFR

2014-07-01

...-hour ozone NAAQS? 51.910 Section 51.910 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Provisions for Implementation of 8-hour Ozone National Ambient Air Quality Standard § 51.910 What... nonattainment for the 8-hour ozone NAAQS? (a) What are the general requirements for RFP for an area classified...

78 FR 11583 - Approval and Promulgation of Implementation Plans Tennessee: Revisions to Volatile Organic...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-19

... exclusion list for VOC on the basis that they have a negligible effect on tropospheric ozone formation. Tropospheric ozone, commonly known as smog, occurs when VOC and nitrogen oxide (NO X ) react in the atmosphere. Because of the harmful health effects of ozone, EPA limits the amount of VOC and NO X that can be released...

75 FR 8871 - Approval and Promulgation of Implementation Plans and Designation of Areas for Air Quality...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-26

... quality monitoring data for the 2007-2009 ozone seasons that demonstrate that the 8-hour ozone NAAQS has... technical information and/or data that you used. 5. If you estimate potential costs or burdens, explain how... FR 23857), EPA published a final rule designating and classifying areas under the 8-hour ozone NAAQS...

78 FR 68378 - Approval and Promulgation of Air Quality Implementation Plans; Illinois; Amendments to Vehicle...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-14

... inspection and maintenance (I/M) program in the Chicago and Metro-East St. Louis ozone nonattainment areas in.... Louis ozone nonattainment areas since February 1999. The program is presently operating in Cook, DuPage... nonattainment area and in portions of Madison, St. Clair and Monroe Counties in the Metro-East St. Louis ozone...

75 FR 78164 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; The Milwaukee-Racine...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-15

... suspended for as long as the areas continue to attain the 1997 8-hour ozone standard. These determinations... obligations remain suspended for each area for so long as it continues to attain the 1997 8-hour ozone NAAQS...; Determination of Attainment of the 1997 8-hour Ozone Standard AGENCY: Environmental Protection Agency (EPA...

Climate-driven ground-level ozone extreme in the fall over the Southeast United States

PubMed Central

Wang, Yuhang

2016-01-01

Ground-level ozone is adverse to human and vegetation health. High ground-level ozone concentrations usually occur over the United States in the summer, often referred to as the ozone season. However, observed monthly mean ozone concentrations in the southeastern United States were higher in October than July in 2010. The October ozone average in 2010 reached that of July in the past three decades (1980–2010). Our analysis shows that this extreme October ozone in 2010 over the Southeast is due in part to a dry and warm weather condition, which enhances photochemical production, air stagnation, and fire emissions. Observational evidence and modeling analysis also indicate that another significant contributor is enhanced emissions of biogenic isoprene, a major ozone precursor, from water-stressed plants under a dry and warm condition. The latter finding is corroborated by recent laboratory and field studies. This climate-induced biogenic control also explains the puzzling fact that the two extremes of high October ozone both occurred in the 2000s when anthropogenic emissions were lower than the 1980s and 1990s, in contrast to the observed decreasing trend of July ozone in the region. The occurrences of a drying and warming fall, projected by climate models, will likely lead to more active photochemistry, enhanced biogenic isoprene and fire emissions, an extension of the ozone season from summer to fall, and an increase of secondary organic aerosols in the Southeast, posing challenges to regional air quality management. PMID:27551089

Climate-driven ground-level ozone extreme in the fall over the Southeast United States.

PubMed

Zhang, Yuzhong; Wang, Yuhang

2016-09-06

Ground-level ozone is adverse to human and vegetation health. High ground-level ozone concentrations usually occur over the United States in the summer, often referred to as the ozone season. However, observed monthly mean ozone concentrations in the southeastern United States were higher in October than July in 2010. The October ozone average in 2010 reached that of July in the past three decades (1980-2010). Our analysis shows that this extreme October ozone in 2010 over the Southeast is due in part to a dry and warm weather condition, which enhances photochemical production, air stagnation, and fire emissions. Observational evidence and modeling analysis also indicate that another significant contributor is enhanced emissions of biogenic isoprene, a major ozone precursor, from water-stressed plants under a dry and warm condition. The latter finding is corroborated by recent laboratory and field studies. This climate-induced biogenic control also explains the puzzling fact that the two extremes of high October ozone both occurred in the 2000s when anthropogenic emissions were lower than the 1980s and 1990s, in contrast to the observed decreasing trend of July ozone in the region. The occurrences of a drying and warming fall, projected by climate models, will likely lead to more active photochemistry, enhanced biogenic isoprene and fire emissions, an extension of the ozone season from summer to fall, and an increase of secondary organic aerosols in the Southeast, posing challenges to regional air quality management.

Impacts and mitigation of excess diesel-related NOx emissions in 11 major vehicle markets

NASA Astrophysics Data System (ADS)

Anenberg, Susan C.; Miller, Joshua; Minjares, Ray; Du, Li; Henze, Daven K.; Lacey, Forrest; Malley, Christopher S.; Emberson, Lisa; Franco, Vicente; Klimont, Zbigniew; Heyes, Chris

2017-05-01

Vehicle emissions contribute to fine particulate matter (PM2.5) and tropospheric ozone air pollution, affecting human health, crop yields and climate worldwide. On-road diesel vehicles produce approximately 20 per cent of global anthropogenic emissions of nitrogen oxides (NOx), which are key PM2.5 and ozone precursors. Regulated NOx emission limits in leading markets have been progressively tightened, but current diesel vehicles emit far more NOx under real-world operating conditions than during laboratory certification testing. Here we show that across 11 markets, representing approximately 80 per cent of global diesel vehicle sales, nearly one-third of on-road heavy-duty diesel vehicle emissions and over half of on-road light-duty diesel vehicle emissions are in excess of certification limits. These excess emissions (totalling 4.6 million tons) are associated with about 38,000 PM2.5- and ozone-related premature deaths globally in 2015, including about 10 per cent of all ozone-related premature deaths in the 28 European Union member states. Heavy-duty vehicles are the dominant contributor to excess diesel NOx emissions and associated health impacts in almost all regions. Adopting and enforcing next-generation standards (more stringent than Euro 6/VI) could nearly eliminate real-world diesel-related NOx emissions in these markets, avoiding approximately 174,000 global PM2.5- and ozone-related premature deaths in 2040. Most of these benefits can be achieved by implementing Euro VI standards where they have not yet been adopted for heavy-duty vehicles.

The increasing threat to stratospheric ozone from dichloromethane.

PubMed

Hossaini, Ryan; Chipperfield, Martyn P; Montzka, Stephen A; Leeson, Amber A; Dhomse, Sandip S; Pyle, John A

2017-06-27

It is well established that anthropogenic chlorine-containing chemicals contribute to ozone layer depletion. The successful implementation of the Montreal Protocol has led to reductions in the atmospheric concentration of many ozone-depleting gases, such as chlorofluorocarbons. As a consequence, stratospheric chlorine levels are declining and ozone is projected to return to levels observed pre-1980 later this century. However, recent observations show the atmospheric concentration of dichloromethane-an ozone-depleting gas not controlled by the Montreal Protocol-is increasing rapidly. Using atmospheric model simulations, we show that although currently modest, the impact of dichloromethane on ozone has increased markedly in recent years and if these increases continue into the future, the return of Antarctic ozone to pre-1980 levels could be substantially delayed. Sustained growth in dichloromethane would therefore offset some of the gains achieved by the Montreal Protocol, further delaying recovery of Earth's ozone layer.

The increasing threat to stratospheric ozone from dichloromethane

NASA Astrophysics Data System (ADS)

Hossaini, Ryan; Chipperfield, Martyn P.; Montzka, Stephen A.; Leeson, Amber A.; Dhomse, Sandip S.; Pyle, John A.

2017-06-01

It is well established that anthropogenic chlorine-containing chemicals contribute to ozone layer depletion. The successful implementation of the Montreal Protocol has led to reductions in the atmospheric concentration of many ozone-depleting gases, such as chlorofluorocarbons. As a consequence, stratospheric chlorine levels are declining and ozone is projected to return to levels observed pre-1980 later this century. However, recent observations show the atmospheric concentration of dichloromethane--an ozone-depleting gas not controlled by the Montreal Protocol--is increasing rapidly. Using atmospheric model simulations, we show that although currently modest, the impact of dichloromethane on ozone has increased markedly in recent years and if these increases continue into the future, the return of Antarctic ozone to pre-1980 levels could be substantially delayed. Sustained growth in dichloromethane would therefore offset some of the gains achieved by the Montreal Protocol, further delaying recovery of Earth's ozone layer.

40 CFR 52.1683 - Control strategy: Ozone.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Ozone. 52.1683...: Ozone. (a) The State of New York has certified to the satisfaction of the EPA that no sources are... ozone nonattainment areas in New York listed below have attained the 1-hour ozone standard on the date...

40 CFR 52.1683 - Control strategy: Ozone.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Ozone. 52.1683...: Ozone. (a) The State of New York has certified to the satisfaction of the EPA that no sources are... ozone nonattainment areas in New York listed below have attained the 1-hour ozone standard on the date...

40 CFR 52.1683 - Control strategy: Ozone.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Ozone. 52.1683...: Ozone. (a) The State of New York has certified to the satisfaction of the EPA that no sources are... that the 1-hour ozone nonattainment areas in New York listed below have attained the 1-hour ozone...

40 CFR 52.1683 - Control strategy: Ozone.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Ozone. 52.1683...: Ozone. (a) The State of New York has certified to the satisfaction of the EPA that no sources are... ozone nonattainment areas in New York listed below have attained the 1-hour ozone standard on the date...

Effects of El Niño on summertime ozone air quality in the eastern United States

NASA Astrophysics Data System (ADS)

Shen, L.; Mickley, L. J.

2017-12-01

We investigate the effect of El Nino on maximum daily 8-hour average (MDA8) surface ozone over the eastern United States in summer (June-August, JJA) from 1980 to 2016. El Nino can influence the extra-tropical climate through the propagation of stationary waves, leading to (1) a low-pressure anomaly in the western Atlantic, which reduces transport of moist, clean air from the ocean into the mid- and southern Atlantic states, and (2) intensified southerly flow in the South Central states, which conversely enhances flux of moist, clean air into this region. El Nino can also trigger greater subsidence, reduced precipitation, and increased surface solar radiation in the mid- and southern Atlantic States. As a result, every standard deviation increase in the Nino 1+2 index is associated with an increase of 1-2 ppbv ozone in the Atlantic States and a decrease of 0.5-2 ppbv ozone in the South Central states. On average, models participating in the Atmospheric Model Intercomparison Project have difficulties capturing the El Nino influence on summertime weather in the eastern United States, implying that the freely running chemistry-climate models also cannot simulate the ozone variability related to El Nino.

Ozone Trends Across the United States over a Period of Decreasing NOx and VOC Emissions

EPA Science Inventory

In this work, we evaluate ambient ozone trends at urban, suburban, and rural monitoring sites across the United States over a period of decreasing NOx and VOC emissions (1998–2013). We find that decreasing ozone trends generally occur in the summer, in less urbanized areas,...

Dynamic Evaluation of Two Decades of WRF-CMAQ Ozone Simulations over the Contiguous United States (2017 MAC-MAQ Conference Presentation)

EPA Science Inventory

Dynamic evaluation of two decades of ozone simulations performed with the fully coupled Weather Research and Forecasting (WRF)–Community Multi-scale Air Quality (CMAQ) model over the contiguous United States is conducted to assess how well the changes in observed ozone air ...

76 FR 43598 - Approval and Promulgation of Air Quality Plans: State of Missouri

Federal Register 2010, 2011, 2012, 2013, 2014

2011-07-21

... Promulgation of Air Quality Plans: State of Missouri AGENCY: Environmental Protection Agency (EPA). ACTION... Control Technology (RACT) for purposes of attaining the 1997 8-hour ozone National Ambient Air Quality...-assured ozone air quality data for 2008-2010, which demonstrate that the 1997 8-hour ozone NAAQS has been...

78 FR 4796 - Approval and Promulgation of Implementation Plans; South Carolina: New Source Review-Prevention...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-01-23

... on the basis that they have a negligible contribution to tropospheric formation of ozone.\\17\\ EPA has... changes. \\17\\ Tropospheric ozone, commonly known as smog, occurs when VOC and nitrogen oxide (NO X ) react... for PM 2.5, PM 10 , ozone and lead that are found at Regulation 61.62-5, Standard No. 2. The four SIP...

77 FR 3720 - Determination of Failure To Attain the One-Hour Ozone Standard by 2007, Determination of Current...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-25

... the area is currently attaining the eight-hour standard is finalized, 40 CFR 51.918 \\1\\ of EPA's ozone... CFR 51.905(e)(2)(i)(B). EPA's proposed determination that the area failed to attain the one-hour ozone... standard. For areas that attain the standard, section 51.918 of the implementation rule provides that, upon...

Effects of El Niño on Summertime Ozone Air Quality in the Eastern United States

PubMed Central

Mickley, Loretta J.

2017-01-01

Abstract We investigate the effect of El Niño on maximum daily 8 h average surface ozone over the eastern United States in summer during 1980–2016. El Niño can influence the extratropical climate through the propagation of stationary waves, leading to (1) reduced transport of moist, clean air into the middle and southern Atlantic states and greater subsidence, reduced precipitation, and increased surface solar radiation in this region, as well as (2) intensified southerly flow into the south central states, which here enhances flux of moist and clean air. As a result, each standard deviation increase in the Niño 1 + 2 index is associated with an increase of 1–2 ppbv ozone in the Atlantic states and a decrease of 0.5–2 ppbv ozone in the south central states. These influences can be predicted 4 months in advance. We show that U.S. summertime ozone responds differently to eastern‐type El Niño events compared to central‐type events. PMID:29622852

Monitoring of Observation Errors in the Assimilation of Satellite Ozone Data

NASA Technical Reports Server (NTRS)

Stajner, Ivanka; Winslow, Nathan; Rood, Richard B.; Pawson, Steven

2003-01-01

The stratospheric ozone layer protects life on Earth from the harmful effects of solar ultravioiet radiation. The ozone layer is currently in a fragile state because of depletion caused by man-made chemicals, especially chlorofluorocarbons. The state of the ozone layer is being monitored and evaluated by scientific experts around the world, in order to help policy makers assess the impacts of international protocols that control the production and release of ozone depleting chemicals. Scientists use a variety ozone measurements and models in order to form a comprehensive picture about the current state of the ozone layer, and to predict the future behavior (expected to be a recovery, as the abundance of the depleting chemicals decreases). Among the data sets used, those from satellite-borne instruments have the advantage of providing a wealth of information about the ozone distribution over most of the globe. Several instruments onboard American and international satellites make measurements of the properties of the atmosphere, from which atmospheric ozone amounts are estimated; long-term measurement programs enable monitoring of trends in ozone. However, the characteristics of satellite instruments change in time. For example, the instrument lenses through which measurements are made may deteriorate over time, or the satellite orbit may drift so that measurements over each location are made later and later in the day. These changes may increase the errors in the retrieved ozone amounts, and degrade the quality of estimated ozone amounts and of their variability. Our work focuses on combining the satellite ozone data with global models that capture atmospheric motion and ozone chemistry, using advanced statistical techniques: this is known as data assimilation. Our method provides a three-dimensional global ozone distribution that is consistent with both the satellite measurements and with our understanding of processes (described in the models) that control ozone distribution. Through the monitoring of statistical properties of the agreement between the data and the model, this approach also enables us to detect changes in the quality of ozone data retrieved from satellite-borne instrument measurements. This paper demonstrates that calculations of the changes in satellite data quality, and the impact these changes on the estimates of the global ozone distribution, can assist in maintaining the uniform quality of the satellite ozone data throughout the lifetime of these instruments, thus contributing to our understanding of long-term ozone change.

Chronic Exposure to Ambient Ozone and Asthma Hospital Admissions among Children

PubMed Central

Lin, Shao; Liu, Xiu; Le, Linh H.; Hwang, Syni-An

2008-01-01

Background The association between chronic exposure to air pollution and adverse health outcomes has not been well studied. Objective This project investigated the impact of chronic exposure to high ozone levels on childhood asthma admissions in New York State. Methods We followed a birth cohort born in New York State during 1995–1999 to first asthma admission or until 31 December 2000. We identified births and asthma admissions through the New York State Integrated Child Health Information System and linked these data with ambient ozone data (8-hr maximum) from the New York State Department of Environmental Conservation. We defined chronic ozone exposure using three indicators: mean concentration during the follow-up period, mean concentration during the ozone season, and proportion of follow-up days with ozone levels > 70 ppb. We performed logistic regression analysis to adjust for child’s age, sex, birth weight, and gestational age; maternal race/ethnicity, age, education, insurance status, smoking during pregnancy, and poverty level; and geographic region, temperature, and copollutants. Results Asthma admissions were significantly associated with increased ozone levels for all chronic exposure indicators (odds ratios, 1.16–1.68), with a positive dose–response relationship. We found stronger associations among younger children, low sociodemographic groups, and New York City residents as effect modifiers. Conclusion Chronic exposure to ambient ozone may increase the risk of asthma admissions among children. Younger children and those in low socioeconomic groups have a greater risk of asthma than do other children at the same ozone level. PMID:19079727

Nonattainment and Ozone Transport Region (OTR) SIP Requirements

EPA Pesticide Factsheets

The Clean Air Act (CAA) requires a group of northeast states, which make up the Ozone Transport Region (OTR), to submit a SIP and install a certain level of controls for the pollutants that form ozone, even if they meet ozone standards.

The Stratospheric Aerosol and Gas Experiment III/International Space Station Mission: Science Objectives and Mission Status

NASA Astrophysics Data System (ADS)

Eckman, R.; Zawodny, J. M.; Cisewski, M. S.; Flittner, D. E.; McCormick, M. P.; Gasbarre, J. F.; Damadeo, R. P.; Hill, C. A.

2015-12-01

The Stratospheric Aerosol and Gas Experiment III/International Space Station (SAGE III/ISS) is a strategic climate continuity mission which was included in NASA's 2010 plan, "Responding to the Challenge of Climate and Environmental Change: NASA's Plan for a Climate-Centric Architecture for Earth Observations and Applications from Space." SAGE III/ISS continues the long-term, global measurements of trace gases and aerosols begun in 1979 by SAGE I and continued by SAGE II and SAGE III on Meteor 3M. Using a well characterized occultation technique, the SAGE III instrument's spectrometer will measure vertical profiles of ozone, aerosols, water vapor, nitrogen dioxide, and other trace gases relevant to ozone chemistry. The mission will launch in 2016 aboard a Falcon 9 spacecraft.The primary objective of SAGE III/ISS is to monitor the vertical distribution of aerosols, ozone, and other trace gases in the Earth's stratosphere and troposphere to enhance our understanding of ozone recovery and climate change processes in the stratosphere and upper troposphere. SAGE III/ISS will provide data necessary to assess the state of the recovery in the distribution of ozone, extend the SAGE III aerosol measurement record that is needed by both climate models and ozone models, and gain further insight into key processes contributing to ozone and aerosol variability. The multi-decadal SAGE ozone and aerosol data sets have undergone intense community scrutiny for accuracy and stability. SAGE ozone data have been used to monitor the effectiveness of the Montreal Protocol.The ISS inclined orbit of 51.6 degrees is ideal for SAGE III measurements because the orbit permits solar occultation measurement coverage to approximately +/- 70 degrees of latitude. SAGE III/ISS will make measurements using the solar occultation measurement technique, lunar occultation measurement technique, and the limb scattering measurement technique. In this presentation, we describe the SAGE III/ISS mission, its implementation, the current status of the instrument, and the testing that took place this past summer. We will focus principally on the science to be conducted by the mission.

Use market forces to reduce auto pollution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrington, W.; Walls, M.A.; McConnell, V.

1995-05-01

When the serious health threat posed by breathing ozone was recognized, Congress took aggressive action by writing emissions standards for new cars into the 1970 Clean Air Act. Because automobile emissions are the major source of the chemicals that react to form ozone, it was hoped that this measure would be enough to lower ozone concentrations to safe levels throughout the country. However, by the late 1980s nearly 100 urban areas still did not meet the desired ozone limits. Frustrated, and determined to ``clean up`` these cities, Congress wrote even tighter regulations into the 1990 Clean Air Act amendments. Asmore » a result, the Environmental Protection Agency (EPA) and state air quality agencies have begun to implement a series of new regulations, many of which may be very costly and cumbersome. Before the nation incurs the costs of this efforts, one should reexamination the wisdom behind it. Does it make sense to mandate reduced emissions rates for new cars? Sticker prices will rise noticeably, but only minimal improvement in air quality can be expected because so much progress already has been made in reducing emissions from new cars. How much faith can the authors put in new approaches such as EPA`s Enhanced Inspection and Maintenance program, which may be useful in some areas but has yet to provide its value? What is to be gained by establishing rigid deadlines when emerging technologies potentially can reduce ozone levels much more cost-effectively? Furthermore, recent scientific data indicates that there may not be an urgent need to meet those deadlines. The paper discusses the use of financial incentives to lower ozone concentrations.« less

The Impact of Iodide-Mediated Ozone Deposition and Halogen Chemistry on Surface Ozone Concentrations Across the Continental United States

EPA Science Inventory

The air quality of many large coastal areas in the United States is affected by the confluence of polluted urban and relatively clean marine airmasses, each with distinct atmospheric chemistry. In this context, the role of iodide-mediated ozone (O3) deposition over seawater and m...

An Estimation of the Climatic Effects of Stratospheric Ozone Losses during the 1980s. Appendix K

NASA Technical Reports Server (NTRS)

MacKay, Robert M.; Ko, Malcolm K. W.; Shia, Run-Lie; Yang, Yajaing; Zhou, Shuntai; Molnar, Gyula

1997-01-01

In order to study the potential climatic effects of the ozone hole more directly and to assess the validity of previous lower resolution model results, the latest high spatial resolution version of the Atmospheric and Environmental Research, Inc., seasonal radiative dynamical climate model is used to simulate the climatic effects of ozone changes relative to the other greenhouse gases. The steady-state climatic effect of a sustained decrease in lower stratospheric ozone, similar in magnitude to the observed 1979-90 decrease, is estimated by comparing three steady-state climate simulations: 1) 1979 greenhouse gas concentrations and 1979 ozone, II) 1990 greenhouse gas concentrations with 1979 ozone, and III) 1990 greenhouse gas concentrations with 1990 ozone. The simulated increase in surface air temperature resulting from nonozone greenhouse gases is 0.272 K. When changes in lower stratospheric ozone are included, the greenhouse warming is 0.165 K, which is approximately 39% lower than when ozone is fixed at the 1979 concentrations. Ozone perturbations at high latitudes result in a cooling of the surface-troposphere system that is greater (by a factor of 2.8) than that estimated from the change in radiative forcing resulting from ozone depiction and the model's 2 x CO, climate sensitivity. The results suggest that changes in meridional heat transport from low to high latitudes combined with the decrease in the infrared opacity of the lower stratosphere are very important in determining the steady-state response to high latitude ozone losses. The 39% compensation in greenhouse warming resulting from lower stratospheric ozone losses is also larger than the 28% compensation simulated previously by the lower resolution model. The higher resolution model is able to resolve the high latitude features of the assumed ozone perturbation, which are important in determining the overall climate sensitivity to these perturbations.

Variability and changes in tropospheric ozone over the western United States (1980-2010): Exploring the roles of stratosphere-to-troposphere transport and El Niño-Southern Oscillation

NASA Astrophysics Data System (ADS)

Lin, M.; Fiore, A. M.; Horowitz, L. W.; Naik, V.; Oltmans, S. J.; Levy, H.; Cooper, O. R.; Johnson, B. J.

2011-12-01

Understanding the drivers of inter-annual variability and long-term changes of tropospheric ozone is crucial for designing appropriate control policies. Advancing this knowledge will also enable process-oriented assessments of chemistry-climate models, which are needed to build confidence in their utility for projecting tropospheric ozone under future climate scenarios. We examine here the response of North American background ozone over the past 30 years (1980-2010) to changes in atmospheric circulation and chemistry, both in the stratosphere and in the troposphere, through an integrated analysis of observational records from satellite, ozonesonde and ground-based networks with the GFDL AM3 global chemistry-climate model (nudged to reanalysis winds to allow for exact space-time comparisons with the observational datasets). Comparing the model simulation with ~30 years of ozone measurements at Mauna Loa ground station (~3397 m a.s.l.) and Hilo sonde (550-450 hPa) in Hawaii, we find that mid-tropospheric ozone in the eastern Pacific extratropics is enhanced by ~5-10 ppbv (~10-20% deviations from the climatological mean) during strong El Niño events (i.e. 1982-1983, 1997-1998, 2009-2010), presumably reflecting stronger transport from the stratosphere and Asia due to the eastward extension of the Pacific storm tracks and amplified subtropical jet. The La Niña condition typically manifests in the opposite sign, with ozone decreasing north of Hawaii. Over the western U.S., however, both cyclonic and anticyclonic circulation following strong El Niño and La Niña winters, respectively, may enhance deep stratosphere-to-troposphere transport in spring. Both ozonesonde and model results sampled at Trinidad Head, California, indicate ~25% positive deviations in UT/LS ozone during the El Niño winters of 1997-1998 and 2009-2010. We find that this ENSO-related UT/LS ozone variability is also captured in satellite-derived total column ozone from TOMS and AIRS over the Northwest U.S. in May. In contrast, enhanced lower tropospheric ozone over the western U.S. during strong La Niña years (e.g. 1999) mostly reflect changes in atmospheric dynamics rather than lower stratospheric ozone. The model indicates a 0.2 ppb/yr increase in mid-tropospheric ozone over the past 25 years. We are implementing a stratospheric ozone tracer in the model to quantify the springtime stratospheric enhancement to the high tail of daily maximum 8-hour surface ozone frequency during both phases of ENSO. We expect that the associated variability should provide insights regarding potential responses to climate shifts as well as inform air quality planning and control strategies to attain the national standard.

Ozone bioindicators and forest health: a guide to the evaluation, analysis, and interpretation of the ozone injury data in the Forest Inventory and Analysis Program

Treesearch

Gretchen C. Smith; John W. Coulston; Barbara M. O' Connell

2008-01-01

In 1994, the Forest Inventory and Analysis (FIA) and Forest Health Monitoring programs of the U.S. Forest Service implemented a national ozone (O3) biomonitoring program designed to address specific questions about the area and percent of forest land subject to levels of O3 pollution that may negatively affect the forest...

78 FR 19994 - Approval and Promulgation of Implementation Plans; South Carolina: New Source Review-Prevention...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-03

... on the basis that they have a negligible contribution to tropospheric formation of ozone to be... table at Regulation 61-62.5, Standard No. 2 to (1) add the 2008 8-hour ozone NAAQS of 75 parts per billion, (2) amend the lead \\11\\ NAAQS to 0.15 [micro]g/m\\3\\ and (3) remove the 1-hour ozone NAAQS, which...

Survey of Rural Areas in the Western United States with the Potential to form Winter Ozone

NASA Astrophysics Data System (ADS)

Hall, C. F.; Mansfield, M. L.

2012-12-01

Both the Uinta Basin of Eastern Utah and the Upper Green River Basin of Western Wyoming are prone to winter ozone events. Ozone in both basins is believed to require a specific set of meteorological phenomena, namely, snow cover and persistent thermal inversions. It is also believed that the primary source of ozone precursors in both basins is the production of oil and/or natural gas. We have conducted a survey of many basins and valleys in the West United States in order to identify regions having meteorology similar to either the Uinta or the Upper Green River Basins, but also having dissimilar industrial activity. Ozone monitoring in such regions may help us better understand the role of oil and gas emissions in the winter ozone phenomenon.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

NASA Astrophysics Data System (ADS)

Fernandez, Rafael Pedro; Kinnison, Douglas E.; Lamarque, Jean-Francois; Tilmes, Simone; Saiz-Lopez, Alfonso

2017-04-01

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSLBr) enhances stratospheric ozone depletion. Based on a dual set of 1960-2100 coupled chemistry-climate simulations (i.e. with and without VSLBr), we show that the maximum Antarctic ozone hole depletion increases by up to 14% when natural VSLBr are considered, in better agreement with ozone observations. The impact of the additional 5 pptv VSLBr on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of 5 million km2, which is equivalent in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSLBr in CAM-Chem does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affect the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by year 2070, and indicates that natural VSLBr chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. This work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.

CO-OCCURRENCE OF OZONE AND ACIDIC CLOUD WATER IN HIGH-ELEVATION FORESTS

EPA Science Inventory

A chemical climatology for high-elevation forests was estimated from ozone and cloudwater acidity data collected in the eastern United States. esides frequent ozone-only and pH-only single-pollutant episodes, both simultaneous and sequential co-occurrence of ozone and acidic clou...

Ozone loss in the lower stratosphere over the United States in 1992-1993: Evidence for heterogeneous chemistry on the Pinatubo aerosol

NASA Technical Reports Server (NTRS)

Hofmann, D. J.; Oltmans, S. J.; Komhyr, W. D.; Harris, J. M.; Lathrop, J. A.; Langford, A. O.; Deshler, T.; Johnson, B. J.; Torres, A.; Matthews, W. A.

1994-01-01

Ozone profiles obtained at Boulder, Colorado and Wallops Island, Virginia indicate that ozone was about 25% below normal during the winter and spring of 1992-93 in the 12-22 km region. This large ozone reduction in the lower stratosphere, though sometimes partially compensated by higher than normal ozone above 24 km, was responsible for the low total column ozone values observed across the United States during this period. Normal temperatures throughout the low ozone region suggest that transport-related effects are probably not the most important cause of the ozone deficits. This region of low ozone at Boulder corresponds closely with the location of the enhanced H2SO4/H2O aerosol from the Pinatubo eruption of 1991 as measured near Boulder and at Laramie, Wyoming. Trajectory analyses suggest that except at low altitudes in spring, air parcels on the days of the ozone measurements generally arrived at Boulder from higher latitude, although seldom higher than 60 deg N, and hence may have been subjected to heterogeneous chemical processing on the surface of Pinatubo aerosol droplets resulting in chlorine-catalyzed ozone destruction, a process which is believed to be more effective under the lower winter temperatures and sunlight levels of higher latitudes.

Multi-Model Comparison of Lateral Boundary Contributions to Surface Ozone Over the United States

EPA Science Inventory

As the National Ambient Air Quality Standards (NAAQS) for ozone become more stringent, there has been growing attention on characterizing the contributions and the uncertainties in ozone from outside the US to the ozone concentrations within the US. The third phase of the Air Qua...

Multi-model Comparison of Lateral Boundary Contributions to Ozone Concentrations over the United States

EPA Science Inventory

As the National Ambient Air Quality Standards (NAAQS) for ozone become more stringent, there has been growing attention on characterizing the contributions and the uncertainties in ozone from outside the US to the ozone concentrations within the US. The third phase of the Air Qua...

Attribution of Trends and Variability in Surface Ozone over the United States

NASA Technical Reports Server (NTRS)

Strode, Sarah; Cooper, Owen; Damo, Megan; Logan, Jennifer; Rodriquez, Jose; Strahan, Susan; Witte, Jacquie

2013-01-01

Concentrations of tropospheric ozone, a greenhouse gas and air pollutant, are impacted by changes in precursor emissions as well meteorology and influx from the stratosphere. Observations show a decreasing trend in summertime surface ozone at rural stations in the eastern United States, while some western stations show increasing trends, particularly in springtime. We use the Global Modeling Initiative (GMI) global chemical transport model to investigate the roles of precursor emission changes, meteorological variability, and stratosphere-troposphere exchange (STE) in explaining observed trends in surface ozone from rural sites in the United States from 1991-2010. The model's interannual variability shows significant correlations with observations from many of the surface sites. We also compare the simulated ozone to ozonesonde data for several locations with sufficiently long records. We compare a simulation with time-dependent precursor emissions, including emission reductions over the United States and Europe and increases over Asia, to a simulation with fixed emissions to quantify the impact of changing emissions on the surface trends. The simulation with varying emissions reproduces much of the east-west difference in summertime ozone over the U.S., although it generally underestimates the negative trend in the East. In contrast, the fixed-emission simulation shows increasing ozone at both eastern and western sites. We will discuss possible causes of this behavior, including long-range transport and STE.

76 FR 70929 - Approval and Promulgation of Air Quality Implementation Plans; District of Columbia; Regional...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-16

...EPA is proposing to approve a revision to the District of Columbia State Implementation Plan (SIP) submitted by the District of Columbia through the District Department of the Environment (DDOE) on October 27, 2011 that addresses regional haze for the first implementation period. This revision addresses the requirements of the Clean Air Act (CAA) and EPA's rules that require states to prevent any future, and remedy any existing, anthropogenic impairment of visibility in mandatory Class I areas caused by emissions of air pollutants from numerous sources located over a wide geographic area (also referred to as the ``regional haze program''). States are required to assure reasonable progress toward the national goal of achieving natural visibility conditions in Class I areas. EPA is proposing to determine that the Regional Haze plan submitted by the District of Columbia satisfies these requirements of the CAA. EPA is also proposing to approve this revision as meeting the infrastructure requirements relating to visibility protection for the 1997 8-Hour Ozone National Ambient Air Quality Standard (NAAQS) and the 1997 and 2006 fine particulate matter (PM2.5) NAAQS.

Impacts and mitigation of excess diesel-related NOx emissions in 11 major vehicle markets.

PubMed

Anenberg, Susan C; Miller, Joshua; Minjares, Ray; Du, Li; Henze, Daven K; Lacey, Forrest; Malley, Christopher S; Emberson, Lisa; Franco, Vicente; Klimont, Zbigniew; Heyes, Chris

2017-05-25

Vehicle emissions contribute to fine particulate matter (PM 2.5 ) and tropospheric ozone air pollution, affecting human health, crop yields and climate worldwide. On-road diesel vehicles produce approximately 20 per cent of global anthropogenic emissions of nitrogen oxides (NO x ), which are key PM 2.5 and ozone precursors. Regulated NO x emission limits in leading markets have been progressively tightened, but current diesel vehicles emit far more NO x under real-world operating conditions than during laboratory certification testing. Here we show that across 11 markets, representing approximately 80 per cent of global diesel vehicle sales, nearly one-third of on-road heavy-duty diesel vehicle emissions and over half of on-road light-duty diesel vehicle emissions are in excess of certification limits. These excess emissions (totalling 4.6 million tons) are associated with about 38,000 PM 2.5 - and ozone-related premature deaths globally in 2015, including about 10 per cent of all ozone-related premature deaths in the 28 European Union member states. Heavy-duty vehicles are the dominant contributor to excess diesel NO x emissions and associated health impacts in almost all regions. Adopting and enforcing next-generation standards (more stringent than Euro 6/VI) could nearly eliminate real-world diesel-related NO x emissions in these markets, avoiding approximately 174,000 global PM 2.5 - and ozone-related premature deaths in 2040. Most of these benefits can be achieved by implementing Euro VI standards where they have not yet been adopted for heavy-duty vehicles.

Effects of stratospheric ozone recovery on photochemistry and ozone air quality in the troposphere

NASA Astrophysics Data System (ADS)

Zhang, H.; Wu, S.; Huang, Y.; Wang, Y.

2014-04-01

There has been significant stratospheric ozone depletion since the late 1970s due to ozone-depleting substances (ODSs). With the implementation of the Montreal Protocol and its amendments and adjustments, stratospheric ozone is expected to recover towards its pre-1980 level in the coming decades. In this study, we examine the implications of stratospheric ozone recovery for the tropospheric chemistry and ozone air quality with a global chemical transport model (GEOS-Chem). With a full recovery of the stratospheric ozone, the projected increases in ozone column range from 1% over the low latitudes to more than 10% over the polar regions. The sensitivity factor of troposphere ozone photolysis rate, defined as the percentage changes in surface ozone photolysis rate for 1% increase in stratospheric ozone column, shows significant seasonal variation but is always negative with absolute value larger than one. The expected stratospheric ozone recovery is found to affect the tropospheric ozone destruction rates much more than the ozone production rates. Significant decreases in surface ozone photolysis rates due to stratospheric ozone recovery are simulated. The global average tropospheric OH decreases by 1.7%, and the global average lifetime of tropospheric ozone increases by 1.5%. The perturbations to tropospheric ozone and surface ozone show large seasonal and spatial variations. General increases in surface ozone are calculated for each season, with increases by up to 0.8 ppbv in the remote areas. Increases in ozone lifetime by up to 13% are found in the troposphere. The increased lifetimes of tropospheric ozone in response to stratospheric ozone recovery enhance the intercontinental transport of ozone and global pollution, in particular for the summertime. The global background ozone attributable to Asian emissions is calculated to increase by up to 15% or 0.3 ppbv in the Northern Hemisphere in response to the projected stratospheric ozone recovery.

Characterization of ozone in the lower troposphere during the 2016 G20 conference in Hangzhou.

PubMed

Su, Wenjing; Liu, Cheng; Hu, Qihou; Fan, Guangqiang; Xie, Zhouqing; Huang, Xin; Zhang, Tianshu; Chen, Zhenyi; Dong, Yunsheng; Ji, Xiangguang; Liu, Haoran; Wang, Zhuang; Liu, Jianguo

2017-12-12

Recently, atmospheric ozone pollution has demonstrated an aggravating tendency in China. To date, most research about atmospheric ozone has been confined near the surface, and an understanding of the vertical ozone structure is limited. During the 2016 G20 conference, strict emission control measures were implemented in Hangzhou, a megacity in the Yangtze River Delta, and its surrounding regions. Here, we monitored the vertical profiles of ozone concentration and aerosol extinction coefficients in the lower troposphere using an ozone lidar, in addition to the vertical column densities (VCDs) of ozone and its precursors in the troposphere through satellite-based remote sensing. The ozone concentrations reached a peak near the top of the boundary layer. During the control period, the aerosol extinction coefficients in the lower lidar layer decreased significantly; however, the ozone concentration fluctuated frequently with two pollution episodes and one clean episode. The sensitivity of ozone production was mostly within VOC-limited or transition regimes, but entered a NOx-limited regime due to a substantial decline of NOx during the clean episode. Temporary measures took no immediate effect on ozone pollution in the boundary layer; instead, meteorological conditions like air mass sources and solar radiation intensities dominated the variations in the ozone concentration.

Detailed Performance Calculations: Wayne State University and Ford Motor Company, Appendix C

NASA Technical Reports Server (NTRS)

1984-01-01

The laser-generated OH through ozone dissociation is defined in equations. Using these equations, the ozone interference levels corresponding to various humidity and ozone concentrations can be calculated readily.

Detailed performance calculations: Wayne State University and Ford Motor Company, appendix C

NASA Astrophysics Data System (ADS)

1984-12-01

The laser-generated OH through ozone dissociation is defined in equations. Using these equations, the ozone interference levels corresponding to various humidity and ozone concentrations can be calculated readily.

Present state of knowledge of the upper atmosphere: An assessment report; processes that control ozone and other climatically important trace gases

NASA Technical Reports Server (NTRS)

Watson, R. T.; Geller, M. A.; Stolarski, R. S.; Hampson, R. F.

1986-01-01

The state of knowledge of the upper atmosphere was assessed as of January 1986. The physical, chemical, and radiative processes which control the spatial and temporal distribution of ozone in the atmosphere; the predicted magnitude of ozone perturbations and climate changes for a variety of trace gas scenarios; and the ozone and temperature data used to detect the presence or absence of a long term trend were discussed. This assessment report was written by a small group of NASA scientists, was peer reviewed, and is based primarily on the comprehensive international assessment document entitled Atmospheric Ozone 1985: Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change, to be published as the World Meteorological Organization Global Ozone Research and Monitoring Project Report No. 16.

77 FR 73387 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Determinations of...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-10

... Ozone Standard for the Pittsburgh-Beaver Valley Moderate Nonattainment Area AGENCY: Environmental... independent determinations regarding the Pittsburgh-Beaver Valley 1997 8-hour ozone nonattainment area (the.... Among those nonattainment areas is the Pittsburgh Area, which includes Allegheny, Armstrong, Beaver...

Formation of Ozonic Compound and Used as Therapeutic Agent in Medicine

NASA Astrophysics Data System (ADS)

Zhu, Lei; Ye, Chunyong; Min, Xinmin

2018-03-01

It has some encouraging results to use ozone in medicine. However, as ozone is usually in gas state, unstable and strong oxidability, it is difficult to be stored and used commonly. Ozone, ethylene, acrylic acid and the ozonic compounds were calculated to study the interaction between ozone and carrier material to form ozonide. The stability of the ozonide, or the bond strength between ozone and ions of carrier are controlled felicitously to release ozone from the ozonide with proper velocity. Ozone antimicrobial has been composed on the above principle. It can be used conveniently, especially for common families. There are some characteristics of ozone antimicrobial or ozone, such as universal applicability, efficiency and rapidity, security, strong penetrability, no drug resistance and sterilization and treatment simultaneity.

Application of CFD modelling at a full-scale ozonation plant for the removal of micropollutants from secondary effluent.

PubMed

Launer, M; Lyko, S; Fahlenkamp, H; Jagemann, P; Ehrhard, P

2013-01-01

Since November 2009, Germany's first full-scale ozonation plant for tertiary treatment of secondary effluent is in continuous operation. A kinetic model was developed and combined with the commercial computational fluid dynamics (CFD) software ANSYS(®) CFX(®) to simulate the removal of micropollutants from secondary effluents. Input data like reaction rate constants and initial concentrations of bulk components of the effluent organic matter (EfOM) were derived from experimental batch tests. Additionally, well-known correlations for the mass transfer were implemented into the simulation model. The CFD model was calibrated and validated by full-scale process data and by analytical measurements for micropollutants. The results show a good consistency of simulated values and measured data. Therewith, the validated CFD model described in this study proved to be suited for the application of secondary effluent ozonation. By implementing site-specific ozone exposition and the given reactor geometry the described CFD model can be easily adopted for similar applications.

The Nevada Rural Ozone Initiative: Field measurements of surface ozone in rural settings

NASA Astrophysics Data System (ADS)

Fine, R.; Gustin, M. S.; Weiss-Penzias, P. S.; Jaffe, D. A.; Peterson, C.

2011-12-01

The Nevada Rural Ozone Initiative (NVROI) focuses on measuring ozone and other parameters at rural sites across Nevada. The project was prompted by observations of elevated ozone concentrations at Great Basin National Park (GBNP), a remote location at the eastern boundary of the state. Past CASTNET data collected at GBNP demonstrated that the area will be out of attainment if the new ozone NAAQS are established at any values between 60 and 70 ppb. To examine the ozone sources we have augmented the CASTNET data at GBNP with measurements at additional sites. NVROI field sites are situated between 1390 and 2080 meters above sea level along transects consistent with the prevailing wind directions across the state. Data collection began in July 2011. Measurements indicate significant variability in the diel pattern of ozone concentrations between field sites suggesting that site specific physicochemical characteristics, free tropospheric inputs, and regional transport of air pollutants all influence observed values at these background sites. Ancillary gas, particulate matter, and meteorological parameters will be coupled with trajectory analyses to investigate the influence of local, regional, and long range sources on background ozone concentrations.

40 CFR 52.136 - Control strategy for ozone: Oxides of nitrogen.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy for ozone: Oxides of... for ozone: Oxides of nitrogen. EPA is approving an exemption request submitted by the State of Arizona on April 13, 1994 for the Maricopa County ozone nonattainment area from the NOX RACT requirements...

40 CFR 52.136 - Control strategy for ozone: Oxides of nitrogen.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy for ozone: Oxides of... for ozone: Oxides of nitrogen. EPA is approving an exemption request submitted by the State of Arizona on April 13, 1994 for the Maricopa County ozone nonattainment area from the NOX RACT requirements...

40 CFR 52.136 - Control strategy for ozone: Oxides of nitrogen.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy for ozone: Oxides of... for ozone: Oxides of nitrogen. EPA is approving an exemption request submitted by the State of Arizona on April 13, 1994 for the Maricopa County ozone nonattainment area from the NOX RACT requirements...

40 CFR 52.136 - Control strategy for ozone: Oxides of nitrogen.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy for ozone: Oxides of... for ozone: Oxides of nitrogen. EPA is approving an exemption request submitted by the State of Arizona on April 13, 1994 for the Maricopa County ozone nonattainment area from the NOX RACT requirements...

40 CFR 52.136 - Control strategy for ozone: Oxides of nitrogen.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy for ozone: Oxides of... for ozone: Oxides of nitrogen. EPA is approving an exemption request submitted by the State of Arizona on April 13, 1994 for the Maricopa County ozone nonattainment area from the NOX RACT requirements...

Ozone bioindicator

Treesearch

John W. Coulston; Mark J. Ambrose

2007-01-01

Why Is Ozone Important? Ground-level ozone occurs at phytotoxic levels in the United States (Lefohn and Pinkerton 1988). Elevated levels of ozone can cause foliar injury to several tree species, may cause growth loss, and can make trees more susceptible to insects and pathogens (Chappelka and Samuelson 1998). However, tree species have varying degrees of sensitivity to...

Multi-model Comparison of Lateral Boundary Contributions to Ozone Concentrations over the United States (CM

EPA Science Inventory

As the National Ambient Air Quality Standards (NAAQS) for ozone become more stringent, there has been growing attention on characterizing the contributions and the uncertainties in ozone from outside the US to the ozone concentrations within the US. The third phase of the Air Qua...

Using CMAQ to provide probabilistic assessment of emission control scenarios in meeting the ozone standard

EPA Science Inventory

In the United States, regional-scale air quality models are being used to identify emissions reductions needed to comply with the ozone National Ambient Air Quality Standard. Previous work has demonstrated that ozone extreme values (i.e., 4th highest ozone or Design Value) are c...

Ozone bioindicator sampling and estimation

Treesearch

Gretchen C, Smith; William D. Smith; John W. Coulston

2007-01-01

Ozone is an important forest stressor that has been measured at known phytotoxic levels at forest locations across the United States. The percent forest exhibiting negative impacts from ozone air pollution is one of the Montreal Process indicators of forest health and vitality. The ozone bioindicator data of the U.S. Forest Service Forest Inventory and Analysis Program...

Multi-model Comparison of Lateral Boundary Contributions to Ozone Concentrations over the United States (CMAS Presentation)

EPA Science Inventory

As the National Ambient Air Quality Standards (NAAQS) for ozone become more stringent, there has been growing attention on characterizing the contributions and the uncertainties in ozone from outside the US to the ozone concentrations within the US. The third phase of the Air Qua...

Impact of increasing heat waves on U.S. ozone episodes in the 2050s: Results from a multimodel analysis using extreme value theory

NASA Astrophysics Data System (ADS)

Shen, L.; Mickley, L. J.; Gilleland, E.

2016-04-01

We develop a statistical model using extreme value theory to estimate the 2000-2050 changes in ozone episodes across the United States. We model the relationships between daily maximum temperature (Tmax) and maximum daily 8 h average (MDA8) ozone in May-September over 2003-2012 using a Point Process (PP) model. At ~20% of the sites, a marked decrease in the ozone-temperature slope occurs at high temperatures, defined as ozone suppression. The PP model sometimes fails to capture ozone-Tmax relationships, so we refit the ozone-Tmax slope using logistic regression and a generalized Pareto distribution model. We then apply the resulting hybrid-extreme value theory model to projections of Tmax from an ensemble of downscaled climate models. Assuming constant anthropogenic emissions at the present level, we find an average increase of 2.3 d a-1 in ozone episodes (>75 ppbv) across the United States by the 2050s, with a change of +3-9 d a-1 at many sites.

Evaluation of the Community Multiscale Air Quality (CMAQ) ...

EPA Pesticide Factsheets

The Community Multiscale Air Quality (CMAQ) model is a state-of-the-science air quality model that simulates the emission, transport and fate of numerous air pollutants, including ozone and particulate matter. The Computational Exposure Division (CED) of the U.S. Environmental Protection Agency develops the CMAQ model and periodically releases new versions of the model that include bug fixes and various other improvements to the modeling system. In the fall of 2016, CMAQ version 5.1.1 will be released. This new version of CMAQ will contain important bug fixes to several issues that were identified in CMAQv5.1 (the current public release version of the CMAQ model), and additionally include updates to other portions of the code. Some specific model updates include a new implementation of the wind-blown dust calculation in CMAQv5.1.1 which fixes several bugs that were identified in the current implementation of wind-blown dust in CMAQv5.1. Several other major updates to the model include an update to the calculation of aerosols; implementation of full halogen chemistry (CMAQv5.1 contains a partial implementation of halogen chemistry), which is particularly important for hemispheric applications of the CMAQ model, as halogen chemistry is need to accurately simulation the destruction of ozone over the ocean; and the new carbon bond 6 (CB6) chemical mechanism. Several annual, and numerous episodic, CMAQv5.1.1 simulations will be performed to assess the impact of these

New analytical model for the ozone electronic ground state potential surface and accurate ab initio vibrational predictions at high energy range.

PubMed

Tyuterev, Vladimir G; Kochanov, Roman V; Tashkun, Sergey A; Holka, Filip; Szalay, Péter G

2013-10-07

An accurate description of the complicated shape of the potential energy surface (PES) and that of the highly excited vibration states is of crucial importance for various unsolved issues in the spectroscopy and dynamics of ozone and remains a challenge for the theory. In this work a new analytical representation is proposed for the PES of the ground electronic state of the ozone molecule in the range covering the main potential well and the transition state towards the dissociation. This model accounts for particular features specific to the ozone PES for large variations of nuclear displacements along the minimum energy path. The impact of the shape of the PES near the transition state (existence of the "reef structure") on vibration energy levels was studied for the first time. The major purpose of this work was to provide accurate theoretical predictions for ozone vibrational band centres at the energy range near the dissociation threshold, which would be helpful for understanding the very complicated high-resolution spectra and its analyses currently in progress. Extended ab initio electronic structure calculations were carried out enabling the determination of the parameters of a minimum energy path PES model resulting in a new set of theoretical vibrational levels of ozone. A comparison with recent high-resolution spectroscopic data on the vibrational levels gives the root-mean-square deviations below 1 cm(-1) for ozone band centres up to 90% of the dissociation energy. New ab initio vibrational predictions represent a significant improvement with respect to all previously available calculations.

Ozone exposures and implications for vegetation in rural areas of the central Appalachian Mountains, U.S.A.

Treesearch

Pamela Edwards; Cindy Huber; Frederica Wood

2004-01-01

The United States is making the transition from the 1979 1 hr maximum ozone standard to the newly adopted 8 hr ozone standard (3 yr average of the 4th highest maximum 8 hr ozone concentration). Consequently, we analyzed and compared ozone concentrations under both standards from a variety of monitoring sites throughout the central Appalachian region of Kentucky (KY),...

76 FR 81727 - Approval and Promulgation of Implementation Plans; Oklahoma; Federal Implementation Plan for...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-28

...EPA is partially approving and partially disapproving a revision to the Oklahoma State Implementation Plan (SIP) submitted by the State of Oklahoma through the Oklahoma Department of Environmental Quality on February 19, 2010, intended to address the regional haze requirements of the Clean Air Act (CAA). In addition, EPA is partially approving and partially disapproving a portion of a revision to the Oklahoma SIP submitted by the State of Oklahoma on May 10, 2007 and supplemented on December 10, 2007 to address the requirements of CAA section 110(a)(2)(D)(i)(II) as it applies to visibility for the 1997 8- hour ozone and 1997 fine particulate matter National Ambient Air Quality Standards. This CAA requirement is intended to prevent emissions from one state from interfering with the visibility programs in another state. EPA is approving certain core elements of the SIP including Oklahoma's: determination of baseline and natural visibility conditions; coordinating regional haze and reasonably attributable visibility impairment; monitoring strategy and other implementation requirements; coordination with states and Federal Land Managers; and a number of NOX, SO2, and PM BART determinations. EPA is finding that Oklahoma's regional haze SIP did not address the sulfur dioxide Best Available Retrofit Technology requirements for six units in Oklahoma in accordance with the Regional Haze requirements, or the requirement to prevent interference with other states' visibility programs. EPA is promulgating a Federal Implementation Plan to address these deficiencies by requiring emissions to be reduced at these six units. This action is being taken under section 110 and part C of the CAA.

Examining the impact of nitryl chloride chemistry on summertime air quality

NASA Astrophysics Data System (ADS)

Sarwar, G.; Simon, H. A.; Bhave, P.; Hutzell, W. T.

2011-12-01

Results of recent field campaigns suggest that heterogeneous reactions can form nitryl chloride (ClNO2) at night. ClNO2 photodissociates into nitrogen dioxide and chlorine radicals during the day. Subsequent photolysis of nitrogen dioxide and reactions of chlorine radicals with volatile organic compounds increase ozone production. Thus, the presence of ClNO2 in the atmosphere can enhance ozone. In this study, the impact of the heterogeneous production of ClNO2 on summertime air quality in the United States is examined by using the Community Multiscale Air Quality (CMAQ) model. Laboratory chamber experimental studies have parameterized the yield of ClNO2 and the heterogeneous uptake of dinitrogen pentoxide on aerosols. We implement these parameterizations into the CMAQ model. In addition to the typical emissions, the model also includes emissions of sea-salt, anthropogenic particulate chloride, anthropogenic hydrochloric acid and molecular chlorine from the National Emissions Inventory. Model simulations are conducted without and with the heterogeneous ClNO2 formation reaction for September 1-10, 2006. The results of the study suggest that the heterogeneous reaction produces ClNO2 in many coastal areas as well as inland locations in the United States. The ClNO2 increase in coastal areas is caused by chloride emissions from sea-salt and in inland-areas by chloride emissions from fire and anthropogenic sources. Predicted ClNO2 levels reach nighttime peaks of up to 4.0 ppb in the Los Angeles area and up to 1.2 ppb near Houston, similar to the measured values reported in the literature. The ClNO2 chemistry decreases nitric acid as well as particulate nitrate by a large margin; consequently it changes composition of NOz. It increases hourly and daily maximum 8-hr ozone by up to 9 ppbv and 6 ppbv, respectively. It increases aerosol sulfate while decreasing aerosol nitrate and ammonium. The accompanying presentation identifies predicted spatial patterns of ClNO2 concentrations across the United States and describes the detailed impact of the ClNO2 chemistry on ozone, nitric acid, sulfate, particulate nitrate, ammonium, and particulate chloride. To evaluate the impact of the ClNO2 chemistry on an ozone control strategy, two additional model simulations were conducted with reduced NOx emissions. Relative response factors were determined without and with the ClNO2 chemistry; the accompanying presentation discusses the impact on ozone control strategy.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

NASA Astrophysics Data System (ADS)

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean-Francois; Tilmes, Simone; Saiz-Lopez, Alfonso

2017-02-01

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSLBr) enhances stratospheric ozone depletion. Based on a dual set of 1960-2100 coupled chemistry-climate simulations (i.e. with and without VSLBr), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSLBr are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSLBr on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ˜ 5 million km2, which is equivalent in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSLBr in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSLBr chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. This work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.

Use of AIRS, OMI, MLS, and TES Data in Assessing Forest Ecosystem Exposure to Ozone

NASA Technical Reports Server (NTRS)

Spruce, Joseph P.

2007-01-01

Ground-level ozone at high levels poses health threats to exposed flora and fauna, including negative impacts to human health. While concern is common regarding depletion of ozone in the stratosphere, portions of the urban and rural United States periodically have high ambient levels of tropospheric ozone on the ground. Ozone pollution can cause a variety of impacts to susceptible vegetation (e.g., Ponderosa and Jeffrey pine species in the southwestern United States), such as stunted growth, alteration of growth form, needle or leaf chlorosis, and impaired ability to withstand drought-induced water stress. In addition, Southern Californian forests with high ozone exposures have been recently subject to multiyear droughts that have led to extensive forest overstory mortality from insect outbreaks and increased incidence of wildfires. Residual forests in these impacted areas may be more vulnerable to high ozone exposures and to other forest threats than ever before. NASA sensors collect a wealth of atmospheric data that have been used recently for mapping and monitoring regional tropospheric ozone levels. AIRS (Atmospheric Infrared Sounder), OMI (Ozone Monitoring Instrument), MLS (Microwave Limb Sounder), and TES (Tropospheric Emission Spectrometer) data could be used to assess forest ecosystem exposure to ozone. Such NASA data hold promise for providing better or at least complementary synoptic information on ground-level ozone levels that Federal agency partners can use to assess forest health trends and to mitigate the threats as needed in compliance with Federal laws and mandates. NASA data products on ozone concentrations may be able to aid applications of DSTs (decision support tools) adopted by the USDA FS (U.S. Department of Agriculture Forest Service) and by the NPS (National Park Service), such as the Ozone Calculator, in which ground ozone estimates are employed to assess ozone impacts to forested vegetation.

Advanced pumped storage hydroelectric power may reduce NO{sub x} and VOC emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

As a severe ozone nonattainment area, the New York/New Jersey metropolitan area faces the difficult challange of reducing emissions of nitrogen oxides (NO{sub x}) and volatile organic compounds (VOCs), the primary precursors of ground-level ozone. An ambitious,more » $$2.4 billion undertaking, known as the Mt. Hope project, may help the metropolitan area - and the entire Mid-Atlantic Ozone Transport Region (OTR) - attain ozone compliance. The project includes a new 2,000-MW electricity storage facility, which would allow thermal power plants in the region to run more efficiently and reduce NO{sub x} and VOC emissions, especially at times of critical ozone levels. The Mt. Hope project is the subject of a recent study that analyzed, potential reductions in ozone precursors from project implementation. According to the study, NO{sub x} emissions could be reduced by up to 50 tons per day and $$91 million per year could potentially be saved if the project is implemented. Advanced pumped storage (APS) improves significantly on the conventional method. The Mt. Hope project, for example, is expected to consume only 22% more electricity than it generates. APS facilities are designed to switch from power-receiving to power-generating modes frequently in response to demand - up to 20 times a day in the Mt. Hope design. 1 ref., 1 fig.« less

Impacts of Lowered Urban Air Temperatures on Precursor Emission and Ozone Air Quality.

PubMed

Taha, Haider; Konopacki, Steven; Akbari, Hashem

1998-09-01

Meteorological, photochemical, building-energy, and power plant simulations were performed to assess the possible precursor emission and ozone air quality impacts of decreased air temperatures that could result from implementing the "cool communities" concept in California's South Coast Air Basin (SoCAB). Two pathways are considered. In the direct pathway, a reduction in cooling energy use translates into reduced demand for generation capacity and, thus, reduced precursor emissions from electric utility power plants. In the indirect pathway, reduced air temperatures can slow the atmospheric production of ozone as well as precursor emission from anthropogenic and biogenic sources. The simulations suggest small impacts on emissions following implementation of cool communities in the SoCAB. In summer, for example, there can be reductions of up to 3% in NO x emissions from in-basin power plants. The photochemical simulations suggest that the air quality impacts of these direct emission reductions are small. However, the indirect atmospheric effects of cool communities can be significant. For example, ozone peak concentrations can decrease by up to 11% in summer and population-weighted exceedance exposure to ozone above the California and National Ambient Air Quality Standards can decrease by up to 11 and 17%, respectively. The modeling suggests that if these strategies are combined with others, such as mobile-source emission control, the improvements in ozone air quality can be substantial.

Extent of ozone injury to trees in the western United States

Treesearch

Paul R. Miller

1996-01-01

The widespread nature of ozone air pollution in California and the suspected potential for ozone damage to forests near cities in other Western States led to field surveys and establishment of monitoring plots beginning in the mid–1960’s. The surveys and plot results were divided into three categories depending on the evidence of injury that was documented, including (...

Impacts of Ozone-vegetation Interactions and Biogeochemical Feedbacks on Atmospheric Composition and Air Quality Under Climate Change

NASA Astrophysics Data System (ADS)

Sadeke, M.; Tai, A. P. K.; Lombardozzi, D.; Val Martin, M.

2015-12-01

Surface ozone pollution is one of the major environmental concerns due to its damaging effects on human and vegetation. One of the largest uncertainties of future surface ozone prediction comes from its interaction with vegetation under a changing climate. Ozone can be modulated by vegetation through, e.g., biogenic emissions, dry deposition and transpiration. These processes are in turn affected by chronic exposure to ozone via lowered photosynthesis rate and stomatal conductance. Both ozone and vegetation growth are expected to be altered by climate change. To better understand these climate-ozone-vegetation interactions and possible feedbacks on ozone itself via vegetation, we implement an online ozone-vegetation scheme [Lombardozzi et al., 2015] into the Community Earth System Model (CESM) with active atmospheric chemistry, climate and land surface components. Previous overestimation of surface ozone in eastern US, Canada and Europe is shown to be reduced by >8 ppb, reflecting improved model-observation comparison. Simulated surface ozone is lower by 3.7 ppb on average globally. Such reductions (and improvements) in simulated ozone are caused mainly by lower isoprene emission arising from reduced leaf area index in response to chronic ozone exposure. Effects via transpiration are also potentially significant but require better characterization. Such findings suggest that ozone-vegetation interaction may substantially alter future ozone simulations, especially under changing climate and ambient CO2 levels, which would further modulate ozone-vegetation interactions. Inclusion of such interactions in Earth system models is thus necessary to give more realistic estimation and prediction of surface ozone. This is crucial for better policy formulation regarding air quality, land use and climate change mitigation. Reference list: Lombardozzi, D., et al. "The Influence of Chronic Ozone Exposure on Global Carbon and Water Cycles." Journal of Climate 28.1 (2015): 292-305.

Regional Assessment of Ozone Sensitive Tree Species Using Bioindicator Plants

Treesearch

John W. Coulston; Gretchen C. Smith; William D. Smith

2003-01-01

Tropospheric ozone occurs at phytotoxic levels in the northeastern and mid-Atlantic regions of the United States. Quantifying possible regional-scale impacts of ambient ozone on forest tree species is difficult and is confounded by other factors, such as moisture and light, which influence the uptake of ozone by plants. Biomonitoring provides an approach to document...

Modeling ozone bioindicator injury with microscale and landscape-scale explanatory variables: A logistic regression approach

Treesearch

John W. Coulston

2011-01-01

Tropospheric ozone occurs at phytotoxic levels in the United States (Lefohn and Pinkerton 1988). Several plant species, including commercially important timber species, are sensitive to elevated ozone levels. Exposure to elevated ozone can cause growth reduction and foliar injury and make trees more susceptible to secondary stressors such as insects and pathogens (...

76 FR 33647 - Approval and Promulgation of Determination of Attainment for the 1997 8-Hour Ozone Standard...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-09

... Promulgation of Determination of Attainment for the 1997 8-Hour Ozone Standard: States of Missouri and Illinois... area has attained the 1997 8-hour National Ambient Air Quality Standard (NAAQS) for ozone. The St... with other requirements related to the attainment of the 1997 8-hour ozone standard are suspended...

Co-benefits of air quality and climate change policies on air quality of the Mediterranean

NASA Astrophysics Data System (ADS)

Pozzoli, Luca; Mert Gokturk, Ozan; Unal, Alper; Kindap, Tayfun; Janssens-Maenhout, Greet

2015-04-01

The Mediterranean basin is one of the regions of the world where significant impacts due to climate changes are predicted to occur in the future. Observations and model simulations are used to provide to the policy makers scientifically based estimates of the necessity to adjust national emission reductions needed to achieve air quality objectives in the context of a changing climate, which is not only driven by GHGs, but also by short lived climate pollutants, such as tropospheric ozone and aerosols. There is an increasing interest and need to design cost-benefit emission reduction strategies, which could improve both regional air quality and global climate change. In this study we used the WRF-CMAQ air quality modelling system to quantify the contribution of anthropogenic emissions to ozone and particulate matter concentrations in Europe and the Eastern Mediterranean and to understand how this contribution could change in different future scenarios. We have investigated four different future scenarios for year 2050 defined during the European Project CIRCE: a "business as usual" scenario (BAU) where no or just actual measures are taken into account; an "air quality" scenario (BAP) which implements the National Emission Ceiling directive 2001/81/EC member states of the European Union (EU-27); a "climate change" scenario (CC) which implements global climate policies decoupled from air pollution policies; and an "integrated air quality and climate policy" scenario (CAP) which explores the co-benefit of global climate and EU-27 air pollution policies. The BAP scenario largely decreases summer ozone concentrations over almost the entire continent, while the CC and CAP scenarios similarly determine lower decreases in summer ozone but extending all over the Mediterranean, the Middle East countries and Russia. Similar patterns are found for winter PM concentrations; BAP scenario improves pollution levels only in the Western EU countries, and the CAP scenario determines the largest PM reductions over the entire continent and the Mediterranean basin.

Seasonal prediction of US summertime ozone using statistical analysis of large scale climate patterns.

PubMed

Shen, Lu; Mickley, Loretta J

2017-03-07

We develop a statistical model to predict June-July-August (JJA) daily maximum 8-h average (MDA8) ozone concentrations in the eastern United States based on large-scale climate patterns during the previous spring. We find that anomalously high JJA ozone in the East is correlated with these springtime patterns: warm tropical Atlantic and cold northeast Pacific sea surface temperatures (SSTs), as well as positive sea level pressure (SLP) anomalies over Hawaii and negative SLP anomalies over the Atlantic and North America. We then develop a linear regression model to predict JJA MDA8 ozone from 1980 to 2013, using the identified SST and SLP patterns from the previous spring. The model explains ∼45% of the variability in JJA MDA8 ozone concentrations and ∼30% variability in the number of JJA ozone episodes (>70 ppbv) when averaged over the eastern United States. This seasonal predictability results from large-scale ocean-atmosphere interactions. Warm tropical Atlantic SSTs can trigger diabatic heating in the atmosphere and influence the extratropical climate through stationary wave propagation, leading to greater subsidence, less precipitation, and higher temperatures in the East, which increases surface ozone concentrations there. Cooler SSTs in the northeast Pacific are also associated with more summertime heatwaves and high ozone in the East. On average, models participating in the Atmospheric Model Intercomparison Project fail to capture the influence of this ocean-atmosphere interaction on temperatures in the eastern United States, implying that such models would have difficulty simulating the interannual variability of surface ozone in this region.

Seasonal prediction of US summertime ozone using statistical analysis of large scale climate patterns

PubMed Central

Mickley, Loretta J.

2017-01-01

We develop a statistical model to predict June–July–August (JJA) daily maximum 8-h average (MDA8) ozone concentrations in the eastern United States based on large-scale climate patterns during the previous spring. We find that anomalously high JJA ozone in the East is correlated with these springtime patterns: warm tropical Atlantic and cold northeast Pacific sea surface temperatures (SSTs), as well as positive sea level pressure (SLP) anomalies over Hawaii and negative SLP anomalies over the Atlantic and North America. We then develop a linear regression model to predict JJA MDA8 ozone from 1980 to 2013, using the identified SST and SLP patterns from the previous spring. The model explains ∼45% of the variability in JJA MDA8 ozone concentrations and ∼30% variability in the number of JJA ozone episodes (>70 ppbv) when averaged over the eastern United States. This seasonal predictability results from large-scale ocean–atmosphere interactions. Warm tropical Atlantic SSTs can trigger diabatic heating in the atmosphere and influence the extratropical climate through stationary wave propagation, leading to greater subsidence, less precipitation, and higher temperatures in the East, which increases surface ozone concentrations there. Cooler SSTs in the northeast Pacific are also associated with more summertime heatwaves and high ozone in the East. On average, models participating in the Atmospheric Model Intercomparison Project fail to capture the influence of this ocean–atmosphere interaction on temperatures in the eastern United States, implying that such models would have difficulty simulating the interannual variability of surface ozone in this region. PMID:28223483

TECHNICAL CHALLENGES INVOLVED IN IMPLEMENTATION OF VOC REACTIVITY-BASED CONTROL OF OZONE

EPA Science Inventory

The control of VOC emissions based on their individual contribution to ozone formation has been the subject of intensive discussion and research in the past five years, and has gained a large degree of acceptance in the air pollution regulatory community for certain industrial op...

76 FR 31237 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-31

...-Beaver Valley 8-Hour Ozone Nonattainment Area AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: EPA is making a final determination that the Pittsburgh-Beaver Valley 8-hour ozone..., Beaver, Butler, Fayette, Washington, and Westmoreland Counties in Pennsylvania. EPA's determination is...

78 FR 65877 - Approval and Promulgation of Implementation Plans; Atlanta, Georgia 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-11-04

... Subjects in 40 CFR Part 52 Environmental protection, Air pollution control, Incorporation by reference...-hour ozone national ambient air quality standards (NAAQS) nonattainment area (hereafter referred to as... Section, Air Planning Branch, Air, Pesticides and Toxics Management Division, U.S. Environmental...

78 FR 20244 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Determinations of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-04

... CFR 51.918), a final determination of attainment suspends the CAA requirements for the Pittsburgh Area... Ozone Standard for the Pittsburgh-Beaver Valley Moderate Nonattainment Area AGENCY: Environmental... determinations regarding the Pittsburgh-Beaver Valley 1997 8-hour ozone nonattainment area (the Pittsburgh Area...

MARs Color Imager (MARCI) Daily Global Ozone Column Mapping from the Mars Reconnaissance Orbiter (MRO): A Survey of 2006-2010 Results

NASA Astrophysics Data System (ADS)

Clancy, R. T.; Wolff, M. J.; Malin, M. C.; Cantor, B. A.

2010-12-01

MARCI UV band imaging photometry within (260nm) and outside (320nm) the Hartley ozone band absorption supports daily global mapping of Mars ozone column abundances. Key retrieval issues include accurate UV radiometric calibrations, detailed specifications of surface and atmospheric background reflectance (surface albedo, atmospheric Raleigh and dust scattering/absorption), and simultaneous cloud retrievals. The implementation of accurate radiative transfer (RT) treatments of these processes has been accomplished (Wolff et al., 2010) such that daily global mapping retrievals for Mars ozone columns have been completed for the 2006-2010 period of MARCI global imaging. Ozone retrievals are most accurate for high column abundances associated with mid-to-high latitude regions during fall, winter, and spring seasons. We present a survey of these MARCI ozone column retrievals versus season, latitude, longitude, and year.

State Fiscal Year 1997-2000 State Transportation Improvement Program (STIP) Cleveland/Akron/Lorain Moderate Ozone Nonattainment Area Air Quality Conformity Documentation

DOT National Transportation Integrated Search

1996-06-01

This document, which is a portion of the Ohio 1997-2000 State Transportation Improvement Program (STIP), describes the conformity determination for the former eight county Cleveland/Akron/Lorain (CAL) Moderate Ozone Nonattainment Area, which includes...

Ozone injury across the Southern United States, 2002–06

Treesearch

Anita K. Rose; John W. Coulston

2009-01-01

In the Eastern United States, hourly concentrations of ozone typically range from 30 to 50 parts per billion(ppb), with events that may exceed 100 ppb. Typical exposure levels can cause visible foliar injury to

Expected ozone benefits of reducing nitrogen oxide (NOx) emissions from coal-fired electricity generating units in the eastern United States.

PubMed

Vinciguerra, Timothy; Bull, Emily; Canty, Timothy; He, Hao; Zalewsky, Eric; Woodman, Michael; Aburn, George; Ehrman, Sheryl; Dickerson, Russell R

2017-03-01

On hot summer days in the eastern United States, electricity demand rises, mainly because of increased use of air conditioning. Power plants must provide this additional energy, emitting additional pollutants when meteorological conditions are primed for poor air quality. To evaluate the impact of summertime NO x emissions from coal-fired electricity generating units (EGUs) on surface ozone formation, we performed a series of sensitivity modeling forecast scenarios utilizing EPA 2018 version 6.0 emissions (2011 base year) and CMAQ v5.0.2. Coal-fired EGU NO x emissions were adjusted to match the lowest NO x rates observed during the ozone seasons (April 1-October 31) of 2005-2012 (Scenario A), where ozone decreased by 3-4 ppb in affected areas. When compared to the highest emissions rates during the same time period (Scenario B), ozone increased ∼4-7 ppb. NO x emission rates adjusted to match the observed rates from 2011 (Scenario C) increased ozone by ∼4-5 ppb. Finally in Scenario D, the impact of additional NO x reductions was determined by assuming installation of selective catalytic reduction (SCR) controls on all units lacking postcombustion controls; this decreased ozone by an additional 2-4 ppb relative to Scenario A. Following the announcement of a stricter 8-hour ozone standard, this analysis outlines a strategy that would help bring coastal areas in the mid-Atlantic region closer to attainment, and would also provide profound benefits for upwind states where most of the regional EGU NO x originates, even if additional capital investments are not made (Scenario A). With the 8-hr maximum ozone National Ambient Air Quality Standard (NAAQS) decreasing from 75 to 70 ppb, modeling results indicate that use of postcombustion controls on coal-fired power plants in 2018 could help keep regions in attainment. By operating already existing nitrogen oxide (NO x ) removal devices to their full potential, ozone could be significantly curtailed, achieving ozone reductions by up to 5 ppb in areas around the source of emission and immediately downwind. Ozone improvements are also significant (1-2 ppb) for areas affected by cross-state transport, especially Mid-Atlantic coast regions that had struggled to meet the 75 ppb standard.

A survey of valleys and basins of the western United States for the capacity to produce winter ozone.

PubMed

Mansfield, Marc L; Hall, Courtney F

2018-04-18

High winter ozone in the Uintah Basin, Utah, and the Upper Green River Basin, Wyoming, occurs because of the confluence of three separate factors: (1) extensive oil or natural gas production, (2) topography conducive to strong multiple-day thermal inversions, and (3) snow cover. We surveyed 13 basins and valleys in the western United States for the existence and magnitude of these factors. Seven of the basins, because winter ozone measurements were available, were assigned to four different behavioral classes. Based on similarities among the basins, the remaining six were also given a tentative assignment. Two classes (1 and 2) correspond to basins with high ozone because all three factors just listed are present at sufficient magnitude. Class 3 corresponds to rural basins with ozone at background levels, and occurs because at least one of the three factors is weak or absent. Class 4 corresponds to ozone below background levels, and occurs, for example, in urban basins where emissions scavenge ozone. All three factors are present in the Wind River Basin, Wyoming, but compared to the Uintah or the Upper Green Basins, it has only moderate oil and gas production and is assigned to class 3. We predict that the Wind River Basin, as well as other class 3 basins that have inversions and snow cover, would transition from background (class 3) to high ozone behavior (class 1 or 2) if oil or gas production were to intensify, or to class 4 (low winter ozone) if they were to become urban. High ozone concentrations in winter only occur in basins or valleys that have an active oil and natural gas production industry, multiple-day thermal inversions, and snow cover, and have only been documented in two basins worldwide. We have examined a number of other candidate basins in the western United States and conclude that these factors are either absent or too weak to produce high winter ozone. This study illustrates how strong each factor needs to be before winter ozone can be expected, and can be used by planners and regulators to foresee the development of winter ozone problems.

Climate Change and Air Pollution-Related Health Impacts in the United States: Assessment of Current Findings

NASA Astrophysics Data System (ADS)

Kinney, P.; Fann, N.

2016-12-01

Ambient air pollution can be affected by climate in a variety of ways, which in turn have important implications for human health. Observed and projected changes in climate lead to modified weather pat­terns and biogenic emissions, which influence the levels and geographic patterns of outdoor air pollutants of health concern, including ground-level ozone (O3) and fine particulate matter (PM2.5). The USGCRP scientific assessment of the human health impacts of climate change concluded with high confidence that climate change will make it harder for any given regulatory approach to reduce ground-level ozone pollution in the future as meteorological conditions become increasingly conducive to forming ozone over most of the United States. Unless offset by additional emissions reductions of ozone precursors, these climate-driven increases in ozone will cause premature deaths, hospital visits, lost school days, and acute respiratory symptoms. The evidence for climate impacts on PM2.5 is less robust than that for ozone. However, one mechanism through which climate change is likely to affect PM2.5 as well as O3 in the United States is via impacts on wildfires. Wildfires emit precursors of both fine particles and O3, which increase the risk of premature death and adverse chronic and acute cardiovascular and respiratory health outcomes. Climate change is projected to increase the number and severity of naturally occurring wildfires in parts of the United States, increasing emissions of particulate matter and ozone precursors and resulting in additional adverse health outcomes. We present the key results and conclusions from a nationwide assessment of O3 health impacts in 2030, as well as new evidence for respiratory health effects of wildfires in the western United States.

Godiva, a European Project for Ozone and Trace Gas Measurements from GOME

NASA Astrophysics Data System (ADS)

Goede, A. P. H.; Tanzi, C. P.; Aben, I.; Burrows, J. P.; Weber, M.; Perner, D.; Monks, P. S.; Llewellyn-Jones, D.; Corlett, G. K.; Arlander, D. W.; Platt, U.; Wagner, T.; Pfeilsticker, K.; Taalas, P.; Kelder, H.; Piters, A.

GODIVA (GOME Data Interpretation, Validation and Application) is a European Commission project aimed at the improvement of GOME (Global Ozone Monitoring Experiment) data products. Existing data products include global ozone, NO2 columns and (ir)radiances. Advanced data products include O3 profiles, BrO, HCHO and OCIO columns. These data are validated by ground-based and balloon borne instruments. Calibration issues are investigated by in-flight monitoring using several complementary calibration sources, as well as an on-ground replica of the GOME instrument. The results will lead to specification of operational processing of the EUMETSAT ozone Satellite Application Facility as well as implementation of the improved and new GOME data products in the NILU database for use in the European THESEO (Third European Stratospheric Experiment on Ozone) campaign of 1999

Ozone, ozone production rates and NO observations on the outskirts of Quito, Ecuador

NASA Astrophysics Data System (ADS)

Cazorla, M.

2014-12-01

Air quality measurements of ambient ozone, ozone production rates and nitrogen oxides, in addition to baseline meterology observations, are being taken at a recently built roof-top facility on the campus of Universidad San Francisco de Quito, in Ecuador. The measurement site is located in Cumbayá, a densely populated valley adjacent to the city of Quito. Time series of ozone and NO are being obtained with commercial air quality monitors. Rush-hour peaks of NO, above 100 ppb, have been observed, while daytime ozone levels are low. In addition, ozone production rates are being measured with the Ecuadorian version of the MOPS, Measurement of Ozone Production Sensor, originally built at Penn State University in 2010. NO and ozone observations and test results of measured ozone production rates will be presented.

Alternative Fuels Data Center: Texas Puts a New Spin on Mowing

Science.gov Websites

halt on Ozone Action Days, and petroleum use is reduced by about 100,000 gallons per year. " On -level ozone pollution, prompting the state to declare Ozone Action Days. On these days, residents and produce much lower emissions than gasoline mowers do, and they can be used on Ozone Action Days. CTCC

Current and future climate- and air pollution-mediated impacts on human health.

PubMed

Doherty, Ruth M; Heal, Mathew R; Wilkinson, Paul; Pattenden, Sam; Vieno, Massimo; Armstrong, Ben; Atkinson, Richard; Chalabi, Zaid; Kovats, Sari; Milojevic, Ai; Stevenson, David S

2009-12-21

We describe a project to quantify the burden of heat and ozone on mortality in the UK, both for the present-day and under future emission scenarios. Mortality burdens attributable to heat and ozone exposure are estimated by combination of climate-chemistry modelling and epidemiological risk assessment. Weather forecasting models (WRF) are used to simulate the driving meteorology for the EMEP4UK chemistry transport model at 5 km by 5 km horizontal resolution across the UK; the coupled WRF-EMEP4UK model is used to simulate daily surface temperature and ozone concentrations for the years 2003, 2005 and 2006, and for future emission scenarios. The outputs of these models are combined with evidence on the ozone-mortality and heat-mortality relationships derived from epidemiological analyses (time series regressions) of daily mortality in 15 UK conurbations, 1993-2003, to quantify present-day health burdens. During the August 2003 heatwave period, elevated ozone concentrations > 200 microg m-3 were measured at sites in London and elsewhere. This and other ozone photochemical episodes cause breaches of the UK air quality objective for ozone. Simulations performed with WRF-EMEP4UK reproduce the August 2003 heatwave temperatures and ozone concentrations. There remains day-to-day variability in the high ozone concentrations during the heatwave period, which on some days may be explained by ozone import from the European continent.Preliminary calculations using extended time series of spatially-resolved WRF-EMEP4UK model output suggest that in the summers (May to September) of 2003, 2005 & 2006 over 6000 deaths were attributable to ozone and around 5000 to heat in England and Wales. The regional variation in these deaths appears greater for heat-related than for ozone-related burdens.Changes in UK health burdens due to a range of future emission scenarios will be quantified. These future emissions scenarios span a range of possible futures from assuming current air quality legislation is fully implemented, to a more optimistic case with maximum feasible reductions, through to a more pessimistic case with continued strong economic growth and minimal implementation of air quality legislation. Elevated surface ozone concentrations during the 2003 heatwave period led to exceedences of the current UK air quality objective standards. A coupled climate-chemistry model is able to reproduce these temperature and ozone extremes. By combining model simulations of surface temperature and ozone with ozone-heat-mortality relationships derived from an epidemiological regression model, we estimate present-day and future health burdens across the UK. Future air quality legislation may need to consider the risk of increases in future heatwaves.

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean -Francois

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSL Br) enhances stratospheric ozone depletion. Based on a dual set of 1960–2100 coupled chemistry–climate simulations (i.e. with and without VSL Br), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSL Br are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSL Br on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ~5 million km 2, which is equivalentmore » in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSL Br in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSL Br chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. As a result, this work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.« less

Impact of biogenic very short-lived bromine on the Antarctic ozone hole during the 21st century

DOE PAGES

Fernandez, Rafael P.; Kinnison, Douglas E.; Lamarque, Jean -Francois; ...

2017-02-03

Active bromine released from the photochemical decomposition of biogenic very short-lived bromocarbons (VSL Br) enhances stratospheric ozone depletion. Based on a dual set of 1960–2100 coupled chemistry–climate simulations (i.e. with and without VSL Br), we show that the maximum Antarctic ozone hole depletion increases by up to 14 % when natural VSL Br are considered, which is in better agreement with ozone observations. The impact of the additional 5 pptv VSL Br on Antarctic ozone is most evident in the periphery of the ozone hole, producing an expansion of the ozone hole area of ~5 million km 2, which is equivalentmore » in magnitude to the recently estimated Antarctic ozone healing due to the implementation of the Montreal Protocol. We find that the inclusion of VSL Br in CAM-Chem (Community Atmosphere Model with Chemistry, version 4.0) does not introduce a significant delay of the modelled ozone return date to 1980 October levels, but instead affects the depth and duration of the simulated ozone hole. Our analysis further shows that total bromine-catalysed ozone destruction in the lower stratosphere surpasses that of chlorine by the year 2070 and indicates that natural VSL Br chemistry would dominate Antarctic ozone seasonality before the end of the 21st century. As a result, this work suggests a large influence of biogenic bromine on the future Antarctic ozone layer.« less

Impact of parameterization choices on the restitution of ozone deposition over vegetation

NASA Astrophysics Data System (ADS)

Le Morvan-Quéméner, Aurélie; Coll, Isabelle; Kammer, Julien; Lamaud, Eric; Loubet, Benjamin; Personne, Erwan; Stella, Patrick

2018-04-01

Ozone is a potentially phyto-toxic air pollutant, which can cause leaf damage and drastically alter crop yields, causing serious economic losses around the world. The VULNOZ (VULNerability to OZone in Anthropised Ecosystems) project is a biology and modeling project that aims to understand how plants respond to the stress of high ozone concentrations, then use a set of models to (i) predict the impact of ozone on plant growth, (ii) represent ozone deposition fluxes to vegetation, and finally (iii) estimate the economic consequences of an increasing ozone background the future. In this work, as part of the VULNOZ project, an innovative representation of ozone deposition to vegetation was developed and implemented in the CHIMERE regional chemistry-transport model. This type of model calculates the average amount of ozone deposited on a parcel each hour, as well as the integrated amount of ozone deposited to the surface at the regional or country level. Our new approach was based on a refinement of the representation of crop types in the model and the use of empirical parameters specific to each crop category. The results obtained were compared with a conventional ozone deposition modeling approach, and evaluated against observations from several agricultural areas in France. They showed that a better representation of the distribution between stomatal and non-stomatal ozone fluxes was obtained in the empirical approach, and they allowed us to produce a new estimate of the total amount of ozone deposited on the subtypes of vegetation at the national level.

Effects of ozone-vegetation coupling on surface ozone air quality via biogeochemical and meteorological feedbacks

NASA Astrophysics Data System (ADS)

Sadiq, Mehliyar; Tai, Amos P. K.; Lombardozzi, Danica; Martin, Maria Val

2017-02-01

Tropospheric ozone is one of the most hazardous air pollutants as it harms both human health and plant productivity. Foliage uptake of ozone via dry deposition damages photosynthesis and causes stomatal closure. These foliage changes could lead to a cascade of biogeochemical and biogeophysical effects that not only modulate the carbon cycle, regional hydrometeorology and climate, but also cause feedbacks onto surface ozone concentration itself. In this study, we implement a semi-empirical parameterization of ozone damage on vegetation in the Community Earth System Model to enable online ozone-vegetation coupling, so that for the first time ecosystem structure and ozone concentration can coevolve in fully coupled land-atmosphere simulations. With ozone-vegetation coupling, present-day surface ozone is simulated to be higher by up to 4-6 ppbv over Europe, North America and China. Reduced dry deposition velocity following ozone damage contributes to ˜ 40-100 % of those increases, constituting a significant positive biogeochemical feedback on ozone air quality. Enhanced biogenic isoprene emission is found to contribute to most of the remaining increases, and is driven mainly by higher vegetation temperature that results from lower transpiration rate. This isoprene-driven pathway represents an indirect, positive meteorological feedback. The reduction in both dry deposition and transpiration is mostly associated with reduced stomatal conductance following ozone damage, whereas the modification of photosynthesis and further changes in ecosystem productivity are found to play a smaller role in contributing to the ozone-vegetation feedbacks. Our results highlight the need to consider two-way ozone-vegetation coupling in Earth system models to derive a more complete understanding and yield more reliable future predictions of ozone air quality.

40 CFR 52.1620 - Identification of plan.

Code of Federal Regulations, 2014 CFR

2014-07-01

... prohibit interference with maintenance and PSD measures in any other state. Interstate transport for the... interference with maintenance and PSD measures in any other state. Sunland Park 1997 8-Hour Ozone Maintenance... other states' programs for PSD for the 1997 and 2008 Ozone and the 1997 and 2006 PM2.5 NAAQS Bernalillo...

75 FR 4745 - Approval and Promulgation of Implementation Plans, State of California, San Joaquin Valley...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-29

...Under section 110(k)(6) of the Clean Air Act, EPA is proposing to correct our May 2004 final approval of revisions to the San Joaquin Valley Unified Air Pollution Control District portion of the California State Implementation Plan. EPA is also proposing to take action on three amended District rules, one of which was submitted on March 7, 2008 and the other two of which were submitted on March 17, 2009. Two of the submitted rules reflect revisions to approved District rules that provide for review of new and modified stationary sources (``new source review'' or NSR) within the District, and the third reflects revisions to an approved District rule that provides a mechanism by which existing stationary sources may be exempt from the requirement to secure a Federally-mandated operating permit. The NSR rule revisions relate to exemptions from permitting and from offsets for certain agricultural operations, to the establishment of NSR applicability and offset thresholds consistent with a classification of ``extreme'' nonattainment for the ozone standard, and to the implementation of EPA's NSR Reform Rules. With respect to the revised District NSR rules, EPA is proposing a limited approval and limited disapproval because, although the changes would strengthen the SIP, there are deficiencies in enforceability that prevent full approval. With respect to the operating permit rule, EPA is proposing a full approval. Lastly, EPA is proposing to rescind certain obsolete permitting requirements from the District portion of the California plan. If EPA were to finalize the limited approval and limited disapproval action, as proposed, then a sanctions clock, and EPA's obligation to promulgate a Federal implementation plan, would be triggered because certain revisions to the District rules that are the subject of this action are required under anti-backsliding principles established for the transition from the 1-hour to the 8-hour ozone standard.

EXPERIMENTAL AND THEORETICAL EVALUATIONS OF OBSERVATIONAL-BASED TECHNIQUES

EPA Science Inventory

Observational Based Methods (OBMs) can be used by EPA and the States to develop reliable ozone controls approaches. OBMs use actual measured concentrations of ozone, its precursors, and other indicators to determine the most appropriate strategy for ozone control. The usual app...

AIR QUALITY OVER THE EASTERN UNITED STATES

EPA Science Inventory

Atmospheric concentrations of ozone and fine particulate matter continue to exceed their standards in many parts of the eastern United States. However, the peak concentration levels and number of ozone exceedances have decreased substantially in recent years due, in part, to the...

Air Quality Modeling Technical Support Document for the 2008 Ozone NAAQS Cross-State Air Pollution Rule Proposal

EPA Pesticide Factsheets

In this technical support document (TSD) we describe the air quality modeling performed to support the proposed Cross-State Air Pollution Rule for the 2008 ozone National Ambient Air Quality Standards (NAAQS)

Overview of the SHARP campaign: Motivation, design, and major outcomes

NASA Astrophysics Data System (ADS)

Olaguer, Eduardo P.; Kolb, Charles E.; Lefer, Barry; Rappenglück, Bernhard; Zhang, Renyi; Pinto, Joseph P.

2014-03-01

The Study of Houston Atmospheric Radical Precursors (SHARP) was a field campaign developed by the Houston Advanced Research Center on behalf of the Texas Environmental Research Consortium. SHARP capitalized on previous research associated with the Second Texas Air Quality Study and the development of the State Implementation Plan (SIP) for the Houston-Galveston-Brazoria (HGB) ozone nonattainment area. These earlier studies pointed to an apparent deficit in ozone production in the SIP attainment demonstration model despite the enhancement of simulated emissions of highly reactive volatile organic compounds in accordance with the findings of the original Texas Air Quality Study in 2000. The scientific hypothesis underlying the SHARP campaign was that there are significant undercounted primary and secondary sources of the radical precursors, formaldehyde, and nitrous acid, in both heavily industrialized and more typical urban areas of Houston. These sources, if properly taken into account, could increase the production of ozone in the SIP model and the simulated efficacy of control strategies designed to bring the HGB area into ozone attainment. This overview summarizes the precursor studies and motivations behind SHARP, as well as the overall experimental design and major findings of the 2009 field campaign. These findings include significant combustion sources of formaldehyde at levels greater than accounted for in current point source emission inventories; the underestimation of formaldehyde and nitrous acid emissions, as well as CO/NOx and NO2/NOx ratios, by mobile source models; and the enhancement of nitrous acid by atmospheric organic aerosol.

Hearing Schedule and List of Speakers for the Public Hearing on Revisions to FIPs to Reduce Interstate Transport of Fine Particulate Matter and Ozone – October 28, 2011, Washington, D.C.

EPA Pesticide Factsheets

List of Speakers and Hearing Schedule for the October 28 Public Hearing on the proposed Revisions to the Federal Implementation Plans to Reduce Interstate Transport of Fine Particulate Matter and Ozone.

75 FR 10420 - Approval and Promulgation of Implementation Plans: 1-Hour Ozone Extreme Area Plan for San Joaquin...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-03-08

... rulemaking. A. Emissions Inventory Comment: Earthjustice comments on the importance of emission inventories..., accurate, current inventory of actual emissions from all sources of the relevant pollutant or pollutants in such area.'' It also comments that ARB submitted to EPA new emissions inventories for ozone precursors...

77 FR 66715 - Approval and Promulgation of Implementation Plans; California; Determinations of Attainment for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-11-07

... ENVIRONMENTAL PROTECTION AGENCY 40 CFR Part 52 [EPA-R09-OAR-2011-0492; FRL- 9749-4] Approval and... that makes several determinations relating to certain 1997 8-hour ozone nonattainment areas in...), direct final rule that makes several determinations relating to 1997 8-hour ozone nonattainment areas in...

75 FR 43062 - Approval and Promulgation of Air Quality Implementation Plans; Texas; Revisions to Emissions...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-23

... ozone precursor gases during the winter and summer months, respectively. The revisions also allow for... dioxide, ozone, lead (Pb), particulate matter (PM), and sulfur dioxide (SO 2 ). A SIP is a set of air... supporting information such as emissions inventories, monitoring networks, and modeling demonstrations. Each...

77 FR 58955 - Approval and Promulgation of Air Quality Implementation Plans; Commonwealth of Pennsylvania...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-25

...) Infrastructure Requirements for the 1997 8-Hour Ozone and the 1997 and 2006 Fine Particulate Matter National..., modeling, legal authority, and adequate resources necessary to assure attainment and maintenance of the... addressing the infrastructure requirements for the 1997 8-hour ozone and fine particulate matter (PM 2.5...

75 FR 953 - Approval and Promulgation of Air Quality Implementation Plans; Maryland; 2002 Base Year Emission...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-07

... human health, especially children and adults who are active outdoors, and individuals with a pre... EPA's regulations. II. What Is the Background for This Action? In 1997, EPA revised the health-based... the 8-hour ozone standard based on scientific evidence demonstrating that ozone causes adverse health...

75 FR 68251 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; 2002 Base Year...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-05

... human health, especially children and adults who are active outdoors, and individuals with a pre... EPA's regulations. II. What is the background for this action? In 1997, EPA revised the health-based... the 8-hour ozone standard based on scientific evidence demonstrating that ozone causes adverse health...

76 FR 38334 - Approval and Promulgation of Air Quality Implementation Plans; District of Columbia, Maryland...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-30

... health, especially children and adults who are active outdoors, and individuals with a pre-existing... Order Reviews I. What is the background of this action? In 1997, EPA revised the health-based NAAQS for... ozone standard based on scientific evidence demonstrating that ozone causes adverse health effects at...

76 FR 57871 - Approval of Air Quality Implementation Plans; California; South Coast; Attainment Plan for 1997 8...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-16

... indicates that adverse public health effects occur following exposure to ozone, particularly in children and... be active outdoors, which increases their exposure. See ``Fact Sheet, Proposal To Revise the National... evidence demonstrating that ozone causes adverse health effects at lower concentrations and over longer...

75 FR 57390 - Approval and Promulgation of Implementation Plans; Alabama: Volatile Organic Compounds

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-21

... Tropospheric ozone, commonly known as smog, occurs when VOCs and nitrogen oxides (NO X ) react in the... contribution to tropospheric ozone formation. EPA is approving revisions to the Alabama SIP submitted on March... the VOC definition on the basis that these compounds make a negligible contribution to tropospheric...

76 FR 28696 - Approval and Promulgation of Air Quality Implementation Plans; California; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-18

... based on complete, quality-assured and certified ambient air quality monitoring data for 2007-2009... certain air quality monitoring data because they meet the criteria for ozone exceptional events that are... certified monitoring data. A violation occurs when the ambient ozone air quality monitoring data show...

Ozone time scale decomposition and trend assessment from surface observations in National Parks of the United States

NASA Astrophysics Data System (ADS)

Mao, H.; McGlynn, D. F.; Wu, Z.; Sive, B. C.

2017-12-01

A time scale decomposition technique, the Ensemble Empirical Mode Decomposition (EEMD), has been employed to decompose the time scales in long-term ozone measurement data at 24 US National Park Service sites. Time scales of interest include the annual cycle, variability by large scale climate oscillations, and the long-term trend. The implementation of policy regulations was found to have had a greater effect on sites nearest to urban regions. Ozone daily mean values increased until around the late 1990s followed by decreasing trends during the ensuing decades for sites in the East, southern California, and northwestern Washington. Sites in the Midwest did not experience a reversal of trends from positive to negative until the mid- to late 2000s. The magnitude of the annual amplitude decreased for nine sites and increased for three sites. Stronger decreases in the annual amplitude occurred in the East, with more sites in the East experiencing decreases in annual amplitude than in the West. The date of annual ozone peaks and minimums has changed for 12 sites in total, but those with a shift in peak date did not necessarily have a shift in the trough date. There appeared to be a link between peak dates occurring earlier and a decrease in the annual amplitude. This is likely related to a decrease in ozone titration due to NOx emission reductions. Furthermore, it was found that the shift in the Pacific Decadal Oscillation (PDO) regime from positive to negative in 1998-1999 resulting in an increase in occurrences of La Niña-like conditions had the effect of directing more polluted air masses from East Asia to higher latitudes over North America. This change in PDO regime was likely one main factor causing the increase in ozone concentrations on all time scales at an Alaskan site DENA-HQ.

Direct Measurements of the Ozone Production Rate: Methods, Measurements, and Implications for Air Quality Monitoring

NASA Astrophysics Data System (ADS)

Brune, W. H.; Baier, B.; Miller, D. O.; Apel, E. C.; Wisthaler, A.; Fried, A.; Cantrell, C. A.; Blake, D. R.; Brown, S. S.; McDuffie, E. E.; Kaser, L.; Long, R.; Weinheimer, A. J.

2017-12-01

Ground level ozone pollution remains a health hazard in the United States despite dramatic reductions due to regulatory actions over the past three decades. The key to understanding the link between the ozone precursor gases, nitrogen oxides (NOx) and volatile organic compounds (VOCs), and ozone pollution is the ozone production rate. However, in air quality models, uncertainties in emissions and meteorology hide the true sensitivity of modeled ozone to the chemistry of the ozone production rate. A better way to understand the ozone production rate is to measure it directly. We devised a method for measuring the ozone production rate directly and have deployed it in a few field studies. In this presentation, we will discuss some fairly recent observations, the strengths and weaknesses of the current method, and a path toward routine monitoring of the ozone production rate.

Ozone injury to forests across the northeast and north central United States, 1994 - 2010

Treesearch

Gretchen C. Smith; Randall S. Morin; George L. McCaskill

2012-01-01

Ozone is a highly toxic air contaminant that has been shown to decrease tree growth and cause significant disturbance to forested ecosystems. Ozone also causes distinct foliar injury symptoms to certain species (bioindicator plants) that can be used to detect and monitor ozone stress (biomonitoring) in the forest environment. In the early 1990s, the U.S. Forest Service...

What would have happened to the ozone layer if chlorofluorocarbons (CFCs) had not been regulated?

NASA Astrophysics Data System (ADS)

Newman, P. A.; Oman, L. D.; Douglass, A. R.; Fleming, E. L.; Frith, S. M.; Hurwitz, M. M.; Kawa, S. R.; Jackman, C. H.; Krotkov, N. A.; Nash, E. R.; Nielsen, J. E.; Pawson, S.; Stolarski, R. S.; Velders, G. J.

2008-12-01

Ozone depletion by chlorofluorocarbons (CFCs) was first proposed by Molina and Rowland in their 1974 Nature paper. Since that time, the scientific connection between ozone losses and CFCs and other ozone depleting substances (ODSs) has been firmly established with laboratory measurements, atmospheric observations, and modeling research. The nations of the world implemented the Montreal Protocol (and amendments) which stopped ODS production in 1992. In this presentation we use a fully coupled radiation- chemical-dynamical model to simulate a future world where ODSs were never regulated and ODS production grew at an annual rate of 3%. In this "world avoided" simulation, 17% of the globally average column ozone is destroyed by 2020, and 67% is destroyed by 2065 in comparison to 1980. Large ozone depletions in the polar region become year-round rather than just seasonal as is currently observed in the Antarctic ozone hole. Very large temperature decreases are observed in response to circulation changes and decreased shortwave radiation absorption by ozone. Ozone levels in the tropical lower stratosphere remain constant until about 2053 and then collapse to near zero by 2058 as a result of heterogeneous chemical processes (as currently observed in the Antarctic ozone hole). The tropical cooling that triggers the ozone collapse is caused by an increase of the tropical upwelling. In response to ozone changes, ultraviolet (UV) radiation increases, tripling the erythemal (sunburn) radiation in the northern summer mid-latitudes by 2065.

Ozone damage detection in cantaloupe plants

NASA Technical Reports Server (NTRS)

Gausman, H. W.; Escobar, D. E.; Rodriguez, R. R.; Thomas, C. E.; Bowen, R. L.

1978-01-01

Ozone causes up to 90 percent of air pollution injury to vegetation in the United States; excess ozone affects plant growth and development and can cause undetected decrease in yields. Laboratory and field reflectance measurements showed that ozone-damaged cantaloupe (Cucumis melo L.) leaves had lower water contents and higher reflectance than did nondamaged leaves. Cantaloupe plants which were lightly, severely, and very severely ozone-damaged were distinguishable from nondamaged plants by reflectance measurements in the 1.35- to 2.5 micron near-infrared water absorption waveband. Ozone-damaged leaf areas were detected photographically 16 h before the damage was visible. Sensors are available for use with aircraft and spacecraft that possibly could be used routinely to detect ozone-damaged crops.

Tropospheric Ozone Near-Nadir-Viewing IR Spectral Sensitivity and Ozone Measurements from NAST-I

NASA Technical Reports Server (NTRS)

Zhou, Daniel K.; Smith, William L.; Larar, Allen M.

2001-01-01

Infrared ozone spectra from near nadir observations have provided atmospheric ozone information from the sensor to the Earth's surface. Simulations of the NPOESS Airborne Sounder Testbed-Interferometer (NAST-I) from the NASA ER-2 aircraft (approximately 20 km altitude) with a spectral resolution of 0.25/cm were used for sensitivity analysis. The spectral sensitivity of ozone retrievals to uncertainties in atmospheric temperature and water vapor is assessed in order to understand the relationship between the IR emissions and the atmospheric state. In addition, ozone spectral radiance sensitivity to its ozone layer densities and radiance weighting functions reveals the limit of the ozone profile retrieval accuracy from NAST-I measurements. Statistical retrievals of ozone with temperature and moisture retrievals from NAST-I spectra have been investigated and the preliminary results from NAST-I field campaigns are presented.

THE EFFECT OF CHLORINE EMISSIONS ON TROPOSPHERIC OZONE IN THE UNITED STATES

EPA Science Inventory

The effect of chlorine emissions on atmospheric ozone in the continental United States was evaluated. Atmospheric chlorine chemistry was combined with the carbon bond mechanism and incorporated into the Community Multiscale Air Quality model. Sources of chlorine included anthrop...

Analysis of ozone precursor data from Baton Rouge, Houston, El Paso, and Dallas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sather, M.E.; Kemp, M.G.

1998-12-31

Ongoing analyses of ozone precursor data continue to be performed for Baton Rouge, Louisiana, and Houston, El Paso, and Dallas, Texas. All four areas have collected ambient monitoring data for ozone, nitrogen oxides (NO{sub x}), and over 50 volatile organic compound (VOC) species in accordance with the Photochemical Assessment Monitoring Stations (PAMS) requirements. The PAMS program was initiated to provide more detailed VOC, NO{sub x}, and meteorological data for scientists, modelers, and managers working toward eliminating violations of the ozone National Ambient Air Quality Standards (NAAQS). This paper will focus on several useful analyses of PAMS data for the fourmore » study areas including: (1) a trends analysis of Total Non-Methane Organic Compounds (TNMOC), NO{sub x}, and ozone data from two Baton Rouge sites, (2) results of TNMOC/NO{sub x} ratio analyses for the three Baton Rouge PAMS sites which can provide a starting point for evaluating specific site sensitivity to changes in VOC or NO{sub x} ambient concentrations, (3) results of benzene/toluene ratio analyses which supply information on aged/fresh air masses, and (4) results of ethylene/acetylene ratio analyses which are useful in determining the impacts of catalytic/noncatalytic vehicles. This paper will also discuss the continuing maturation of the PAMS program in Baton Rouge, Houston, and El Paso. The Dallas area is expected to formally begin implementing a PAMS program in 1998 after the area is reclassified to a serious status for ozone pollution. In addition, the Beaumont, Texas area is currently scheduled to be reclassified to a serious status for ozone pollution in the 1998/1999 time period, and thus would also need to begin implementing a PAMS program.« less

A Hybrid Model for Spatially and Temporally Resolved Ozone Exposures in the Continental United States

PubMed Central

Di, Qian; Rowland, Sebastian; Koutrakis, Petros; Schwartz, Joel

2017-01-01

Ground-level ozone is an important atmospheric oxidant, which exhibits considerable spatial and temporal variability in its concentration level. Existing modeling approaches for ground-level ozone include chemical transport models, land-use regression, Kriging, and data fusion of chemical transport models with monitoring data. Each of these methods has both strengths and weaknesses. Combining those complementary approaches could improve model performance. Meanwhile, satellite-based total column ozone, combined with ozone vertical profile, is another potential input. We propose a hybrid model that integrates the above variables to achieve spatially and temporally resolved exposure assessments for ground-level ozone. We used a neural network for its capacity to model interactions and nonlinearity. Convolutional layers, which use convolution kernels to aggregate nearby information, were added to the neural network to account for spatial and temporal autocorrelation. We trained the model with AQS 8-hour daily maximum ozone in the continental United States from 2000 to 2012 and tested it with left out monitoring sites. Cross-validated R2 on the left out monitoring sites ranged from 0.74 to 0.80 (mean 0.76) for predictions on 1 km×1 km grid cells, which indicates good model performance. Model performance remains good even at low ozone concentrations. The prediction results facilitate epidemiological studies to assess the health effect of ozone in the long term and the short term. PMID:27332675

The predicted impact of VOCs from Marijuana cultivation operations on ozone concentrations in great Denver, CO.

NASA Astrophysics Data System (ADS)

Wang, C. T.; Vizuete, W.; Wiedinmyer, C.; Ashworth, K.

2016-12-01

Colorado is the first the marijuana legal states in the United States since 2014. As a result, thousands of legal Marijuana cultivation operations are at great Denver area now. Those Marijuana cultivation operations could be the potential to release a lot of biogenic VOCs, such as monoterpene(C10H16), alpha-pinene, and D-limonene. Those alkene species could rapidly increase the peroxy radicals and chemical reactions in the atmosphere, especially in the urban area which belong to VOC-limited ozone regime. These emissions will increase the ozone in Denver city, where is ozone non-attainment area. Some previous research explained the marijuana smoke and indoor air quality (Martyny, Serrano, Schaeffer, & Van Dyke, 2013) and the smell of marijuana chemical compounds(Rice & Koziel, 2015). However, there have been no studies discuss on identifying and assessing emission rate from marijuana and how those species impact on atmospheric chemistry and ozone concentration, and the marijuana emissions have been not considered in the national emission inventory, either. This research will use air quality model to identify the possibility of ozone impact by marijuana cultivation emission. The Comprehensive Air Quality Model with Extensions, CAMx, are applied for this research to identify the impact of ozone concentration. This model is government regulatory model based on the Three-State Air Quality Modeling Study (3SAQS), which developed by UNC-Chapel Hill and ENVIRON in 2012. This model is used for evaluation and regulate the ozone impact in ozone non-attainment area, Denver city. The details of the 3SAQS model setup and protocol can be found in the 3SAQS report(UNC-IE, 2013). For the marijuana emission study scenarios, we assumed the monoterpene (C10H16) is the only emission species in air quality model and identify the ozone change in the model by the different quantity of emission rate from marijuana cultivation operations.

AN APPROACH FOR CHARACTERIZING TROPOSPHERIC OZONE RISK TO FOREST

EPA Science Inventory

The risk tropospheric ozone poses to forests in the United States is dependent on the variation in ozone exposure across the distribution of the forests in question and the various environmental and climate factors predominant in the region. All these factors have a spatial natur...

Highlights of TOMS Version 9 Total Ozone Algorithm

NASA Technical Reports Server (NTRS)

Bhartia, Pawan; Haffner, David

2012-01-01

The fundamental basis of TOMS total ozone algorithm was developed some 45 years ago by Dave and Mateer. It was designed to estimate total ozone from satellite measurements of the backscattered UV radiances at few discrete wavelengths in the Huggins ozone absorption band (310-340 nm). Over the years, as the need for higher accuracy in measuring total ozone from space has increased, several improvements to the basic algorithms have been made. They include: better correction for the effects of aerosols and clouds, an improved method to account for the variation in shape of ozone profiles with season, latitude, and total ozone, and a multi-wavelength correction for remaining profile shape errors. These improvements have made it possible to retrieve total ozone with just 3 spectral channels of moderate spectral resolution (approx. 1 nm) with accuracy comparable to state-of-the-art spectral fitting algorithms like DOAS that require high spectral resolution measurements at large number of wavelengths. One of the deficiencies of the TOMS algorithm has been that it doesn't provide an error estimate. This is a particular problem in high latitudes when the profile shape errors become significant and vary with latitude, season, total ozone, and instrument viewing geometry. The primary objective of the TOMS V9 algorithm is to account for these effects in estimating the error bars. This is done by a straightforward implementation of the Rodgers optimum estimation method using a priori ozone profiles and their error covariances matrices constructed using Aura MLS and ozonesonde data. The algorithm produces a vertical ozone profile that contains 1-2.5 pieces of information (degrees of freedom of signal) depending upon solar zenith angle (SZA). The profile is integrated to obtain the total column. We provide information that shows the altitude range in which the profile is best determined by the measurements. One can use this information in data assimilation and analysis. A side benefit of this algorithm is that it is considerably simpler than the present algorithm that uses a database of 1512 profiles to retrieve total ozone. These profiles are tedious to construct and modify. Though conceptually similar to the SBUV V8 algorithm that was developed about a decade ago, the SBUV and TOMS V9 algorithms differ in detail. The TOMS algorithm uses 3 wavelengths to retrieve the profile while the SBUV algorithm uses 6-9 wavelengths, so TOMS provides less profile information. However both algorithms have comparable total ozone information and TOMS V9 can be easily adapted to use additional wavelengths from instruments like GOME, OMI and OMPS to provide better profile information at smaller SZAs. The other significant difference between the two algorithms is that while the SBUV algorithm has been optimized for deriving monthly zonal means by making an appropriate choice of the a priori error covariance matrix, the TOMS algorithm has been optimized for tracking short-term variability using month and latitude dependent covariance matrices.

Reynolds and Westvaco Plant Proposed Ozone (O3) State Implementation Plan (SIP) Revisions

EPA Pesticide Factsheets

This document may be of assistance in applying the New Source Review (NSR) air permitting regulations including the Prevention of Significant Deterioration (PSD) requirements. This document is part of the NSR Policy and Guidance Database. Some documents in the database are a scanned or retyped version of a paper photocopy of the original. Although we have taken considerable effort to quality assure the documents, some may contain typographical errors. Contact the office that issued the document if you need a copy of the original.

40 CFR 52.387 - Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS.

Code of Federal Regulations, 2012 CFR

2012-07-01

...-hour ozone and PM2.5 NAAQS. 52.387 Section 52.387 Protection of Environment ENVIRONMENTAL PROTECTION... § 52.387 Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS. On March 13, 2007, the State...)(D)(i) interstate transport requirements of the Clean Air Act for the 1997 8-hour ozone and PM2.5...

40 CFR 52.387 - Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS.

Code of Federal Regulations, 2010 CFR

2010-07-01

...-hour ozone and PM2.5 NAAQS. 52.387 Section 52.387 Protection of Environment ENVIRONMENTAL PROTECTION... § 52.387 Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS. On March 13, 2007, the State...)(D)(i) interstate transport requirements of the Clean Air Act for the 1997 8-hour ozone and PM2.5...

40 CFR 52.387 - Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS.

Code of Federal Regulations, 2011 CFR

2011-07-01

...-hour ozone and PM2.5 NAAQS. 52.387 Section 52.387 Protection of Environment ENVIRONMENTAL PROTECTION... § 52.387 Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS. On March 13, 2007, the State...)(D)(i) interstate transport requirements of the Clean Air Act for the 1997 8-hour ozone and PM2.5...

40 CFR 52.387 - Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS.

Code of Federal Regulations, 2014 CFR

2014-07-01

...-hour ozone and PM2.5 NAAQS. 52.387 Section 52.387 Protection of Environment ENVIRONMENTAL PROTECTION... § 52.387 Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS. On March 13, 2007, the State...)(D)(i) interstate transport requirements of the Clean Air Act for the 1997 8-hour ozone and PM2.5...

40 CFR 52.387 - Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS.

Code of Federal Regulations, 2013 CFR

2013-07-01

...-hour ozone and PM2.5 NAAQS. 52.387 Section 52.387 Protection of Environment ENVIRONMENTAL PROTECTION... § 52.387 Interstate Transport for the 1997 8-hour ozone and PM2.5 NAAQS. On March 13, 2007, the State...)(D)(i) interstate transport requirements of the Clean Air Act for the 1997 8-hour ozone and PM2.5...

76 FR 37272 - Approval and Promulgation of Air Quality Implementation Plans; Illinois; Royal Fiberglass Pools...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-27

...EPA is approving into the Illinois State Implementation Plan (SIP) an adjusted standard for Royal Fiberglass Pools (``Royal'') at its Dix, Illinois facility. On November 8, 2010, the Illinois Environmental Protection Agency (IEPA) submitted to EPA for approval an adjustment to the general rule, Use of Organic Material Rule, commonly known as the eight pound per hour (8 lb/hr) rule, as it applies to emissions of volatile organic matter (VOM) from Royal's pool manufacturing facility. The adjusted standard relieves Royal from being subject to the general rule for VOM emissions from its Dix facility. EPA is approving this SIP revision because it will not interfere with attainment or maintenance of the ozone National Ambient Air Quality Standard (NAAQS).

The impact of the observation nudging and nesting on the simulated meteorology and ozone concentrations from WRF-SMOKE-CMAQ during DISCOVER-AQ 2013 Texas campaign

NASA Astrophysics Data System (ADS)

Choi, Y.; Li, X.; Czader, B.

2014-12-01

Three WRF simulations for the DISCOVER-AQ 2013 Texas campaign period (30 days in September) are performed to characterize uncertainties in the simulated meteorological and chemical conditions. These simulations differ in domain setup, and in performing observation nudging in WRF runs. There are around 7% index of agreement (IOA) gain in temperature and 9-12% boost in U-WIND and V-WIND when the observational nudging is employed in the simulation. Further performance gain from nested domains over single domain is marginal. The CMAQ simulations based on above WRF setups showed that the ozone performance slightly improved in the simulation for which objective analysis (OA) is carried out. Further IOA gain, though quite limited, is achieved with nested domains. This study shows that the high ozone episodes during the analyzed time periods were associated with the uncertainties of the simulated cold front passage, chemical boundary condition and small-scale temporal wind fields. All runs missed the observed high ozone values which reached above 150 ppb in La Porte on September 25, the only day with hourly ozone over 120 ppb. The failure is likely due to model's inability to catch small-scale wind shifts in the industrial zone, despite better wind directions in the simulations with nudging and nested domains. This study also shows that overestimated background ozone from the southerly chemical boundary is a critical source for the model's general overpredictions of the ozone concentrations from CMAQ during September of 2013. These results of this study shed a light on the necessity of (1) capturing the small-scale winds such as the onsets of bay-breeze or sea-breeze and (2) implementing more accurate chemical boundary conditions to reduce the simulated high-biased ozone concentrations. One promising remedy for (1) is implementing hourly observation nudging instead of the standard one which is done every three hours.

Ozone-induced dissociation on a traveling wave high-resolution mass spectrometer for determination of double-bond position in lipids.

PubMed

Vu, Ngoc; Brown, Jeffery; Giles, Kevin; Zhang, Qibin

2017-09-15

The position of C=C within fatty acyl chains affects the biological function of lipids. Ozone-induced dissociation mass spectrometry (OzID-MS) has great potential in determination of lipid double-bond position, but has generally been implemented on low-resolution ion trap mass spectrometers. In addition, most of the OzID-MS experiments carried out so far were focused on the sodiated adducts of lipids; fragmentation of the most commonly observed protonated ions generated in LC/MS-based lipidomics workflow has been less explored. Ozone generated in line from an ozone generator was connected to the trap and transfer gas supply line of a Synapt G2 high-resolution mass spectrometer. Protonated ions of different phosphatidylcholines (PC) were generated by electrospray ionization through direct infusion. Different parameters, including traveling wave height and velocity, trap entrance and DC potential, were adjusted to maximize the OzID efficiency. sn-positional isomers and cis/trans isomers of lipids were compared for their reactivity with ozone. Traveling wave height and velocity were tuned to prolong the encounter time between lipid ions and ozone, and resulted in improved OzID efficiency, as did increasing trapping region DC and entrance potential. Under optimized settings, at least 1000 times enhancement in OzID efficiency was achieved compared to that under default settings for monounsaturated PC standards. Monounsaturated C=C in the sn-2 PC isomer reacted faster with ozone than the sn-1 isomer. Similarly, the C=C in trans PC reacted faster than in cis PC. This is the first implementation of OzID in the trap and transfer region of a traveling wave enabled high-resolution mass spectrometer. The OzID reaction efficiency is significantly improved by slowing down ions in the trap region for their prolonged interaction with ozone. This will facilitate application of high-resolution OzID-MS in lipidomics. Copyright © 2017 John Wiley & Sons, Ltd.

77 FR 74355 - Approval of Air Quality Implementation Plans; California; San Joaquin Valley; Attainment Plan for...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-14

... update the air quality modeling in the San Joaquin Valley 8-Hour Ozone SIP by December 31, 2014. DATES... modeling in the San Joaquin Valley 8-Hour Ozone SIP to reflect emissions inventory improvements and any...) * * * (396) * * * (ii) * * * (A) * * * (2) * * * (ii) Commitment to update the air quality modeling in the...

76 FR 48754 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Reasonably Available Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-08-09

... 8-hour ozone standard, which is the case for the former Cleveland-Akron-Lorain moderate ozone... included in the public docket without change and may be made available online at http://www.regulations.gov... public docket and made available on the Internet. If you submit an electronic comment, EPA recommends...

77 FR 46990 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Attainment Demonstration...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-08-07

... protective of human health, especially for children and adults who are active outdoors, and individuals with... CAA requirements for a moderate 8-hour ozone nonattainment area? In 1997, EPA revised the health-based... health effects at lower ozone concentrations and over longer periods of time than was understood when the...

78 FR 36716 - Approval and Promulgation of Air Quality Implementation Plans; Pennsylvania; Philadelphia County...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-06-19

... or otherwise protected through www.regulations.gov or email. The www.regulations.gov Web site is an.... Although listed in the index, some information is not publicly available, i.e., CBI or other information... Philadelphia County addressing the requirements of RACT under the 1997 8-hour ozone NAAQS. I. Background Ozone...

77 FR 36404 - Approval and Promulgation of Air Quality Implementation Plans; Massachusetts; Determination of...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-06-19

... Environmental Protection recently performed a missing data analysis for this site in accordance with the regulatory requirements of 40 CFR Part 50, Appendix I, for both 2010 and 2011. The Massachusetts missing data... the missing days to decisively conclude that on the days with missing ozone data, the ozone levels, if...

78 FR 32135 - Approval and Promulgation of Implementation Plans; Atlanta, Georgia 1997 8-Hour Ozone...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-29

... allowed by 40 CFR 51.918 for the Atlanta Area.\\5\\ Subsequently, EPA approved Georgia's SIP revisions... CFR 51.910. Specifically, in ozone nonattainment areas with air quality classified as ``moderate'' or... CFR 51.910(b)(2). For an area like Atlanta, the RFP SIP revision must provide for a 15 percent...

75 FR 21169 - Approval and Promulgation of Air Quality Implementation Plans; New Mexico; Revisions to New...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-23

... maintenance for carbon monoxide; and Removing the provision that allowed 8-hour ozone areas to use other tests..., 1999); Is not an economically significant regulatory action based on health or safety risks subject to...--Analysis in Serious, Severe, and Extreme Ozone Nonattainment Areas and Serious Carbon Monoxide Areas. 20.2...

Modeling coupled interactions of carbon, water, and ozone exchange between terrestrial ecosystems and the atmosphere

Treesearch

Ned Nikolova; Karl F. Zeller

2003-01-01

A new biophysical model (FORFLUX) is presented to study the simultaneous exchange of ozone, carbon dioxide, and water vapor between terrestrial ecosystems and the atmosphere. The model mechanistically couples all major processes controlling ecosystem flows trace gases and water implementing recent concepts in plant eco-physiology, micrometeorology, and soil hydrology....

76 FR 10249 - Approval and Promulgation of Air Quality Implementation Plans; Texas; Revisions To Control...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-02-24

... Container rule as an ozone control strategy from the Texas SIP for the Control of Ozone Air Pollution. In the submittal, Texas demonstrates that Federal portable fuel container standards promulgated by EPA in... Portable Fuel Container Regulations IV. What is the effect of this action? V. Final Action VI. Statutory...

77 FR 21690 - Approval and Promulgation of Air Quality Implementation Plan for 1997 8-Hour Ozone Standard; Arizona

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-11

... and emissions input data preparation, model performance evaluation, interpreting modeling results, and... standard based on ambient ozone monitoring data for the 2006- 2008 period. EPA has not yet acted on this... ppm) and years thereafter were at or below the standard. See EPA Air Quality System (AQS) data...

Long-term performance of passive materials for removal of ozone from indoor air.

PubMed

Cros, C J; Morrison, G C; Siegel, J A; Corsi, R L

2012-02-01

The health effects associated with exposure to ozone range from respiratory irritation to increased mortality. In this paper, we explore the use of three green building materials and an activated carbon (AC) mat that remove ozone from indoor air. We studied the effects of long-term exposure of these materials to real environments on ozone removal capability and pre- and post-ozonation emissions. A field study was completed over a 6-month period, and laboratory testing was intermittently conducted on material samples retrieved from the field. The results show sustained ozone removal for all materials except recycled carpet, with greatest ozone deposition velocity for AC mat (2.5-3.8 m/h) and perlite-based ceiling tile (2.2-3.2 m/h). Carbonyl emission rates were low for AC across all field sites. Painted gypsum wallboard and perlite-based ceiling tile had similar overall emission rates over the 6-month period, while carpet had large initial emission rates of undesirable by-products that decayed rapidly but remained high compared with other materials. This study confirms that AC mats and perlite-based ceiling tile are viable surfaces for inclusion in buildings to remove ozone without generating undesirable by-products. PRACTICAL IMPLICATIONS The use of passive removal materials for ozone control could decrease the need for, or even render unnecessary, active but energy consuming control solutions. In buildings where ozone should be controlled (high outdoor ozone concentrations, sensitive populations), materials specifically designed or selected for removing ozone could be implemented, as long as ozone removal is not associated with large emissions of harmful by-products. We find that activated carbon mats and perlite-based ceiling tiles can provide substantial, long-lasting, ozone control. © 2011 John Wiley & Sons A/S.

Ozone processing of foods and beverages

USDA-ARS?s Scientific Manuscript database

Ozone has a long history of use as a disinfectant in food and beverage processing. In the United States, the application of ozone to disinfect bottled water was approved as Generally Recognized As Safe (GRAS) in 1982. Later it was approved as a sanitizing agent for bottled water treatment lines. Ozo...

INTERANNUAL VARIATION IN METEOROLOGICALLY ADJUSTED OZONE LEVELS IN THE EASTERN UNITED STATES: A COMPARISON OF TWO APPROACHED

EPA Science Inventory

Assessing the influence of abatement efforts and other human activities on ozone levels is complicated by the atmosphere's changeable nature. Two statistical methods, the dynamic linear model(DLM) and the generalized additive model (GAM), are used to estimate ozone trends in the...

Ozone in Sequoia National Park: Linking Ozone Production in the San Joaquin Valley to Trends in Vegetative Impacts in Sequoia National Park from 2000-2016

NASA Astrophysics Data System (ADS)

Buysse, C. E.; Pusede, S.; Kotsakis, A.

2016-12-01

Sequoia National Park (SNP) has the worst ozone air pollution of any National Park in the United States. Ozone pollution levels in SNP are high enough to exert damaging impacts on humans, animals, and vegetation. The major source of ozone to SNP is chemical production within the nearby and ozone-polluted San Joaquin Valley (SJV), which is then transported out of the valley into the park. Emission controls to reduce ozone in the SJV have been in place for the last two decades and these controls should have had the effect of altering ozone levels within SNP. This work has two aims. First, we investigate the chemistry driving trends in ozone in SNP and link these changes to trends in ozone in the SJV. Second, we consider both the metrics and time frames that best capture ozone trends contributing to vegetative damage, as these are not well represented in assessments of human health-based ambient air quality standards over an entire ozone season.

Effects of ozonated sewage effluent on reproduction and behavioral endpoints in zebrafish (Danio rerio).

PubMed

Pohl, Johannes; Björlenius, Berndt; Brodin, Tomas; Carlsson, Gunnar; Fick, Jerker; Larsson, D G Joakim; Norrgren, Leif; Örn, Stefan

2018-04-25

Pharmaceutical residues and other micro-contaminants may enter aquatic environments through effluent from sewage treatment plants (STPs) and could cause adverse effects in wild fish. One strategy to alleviate this situation is to improve wastewater treatment by ozonation. To test the effectiveness of full-scale wastewater effluent ozonation at a Swedish municipal STP, the added removal efficiency was measured for 105 pharmaceuticals. In addition, gene expression, reproductive and behavioral endpoints were analyzed in zebrafish (Danio rerio) exposed on-site over 21 days to ozonated or non-ozonated effluents as well as to tap water. Ozone treatment (7 g O 3 /m 3 ) removed pharmaceuticals by an average efficiency of 77% in addition to the conventional treatment, leaving 11 screened pharmaceuticals above detection limits. Differences in biological responses of the exposure treatments were recorded in gene expression, reproduction and behavior. Hepatic vitellogenin gene expression was higher in male zebrafish exposed to the ozonated effluent compared to the non-ozonated effluent and tap water treatments. The reproductive success was higher in fish exposed to ozonated effluent compared to non-ozonated effluent and to tap water. The behavioral measurements showed that fish exposed to the ozonated STP effluent were less active in swimming the first minute after placed in a novel vessel. Ozonation is a capable method for removing pharmaceuticals in effluents. However, its implementation should be thoroughly evaluated for any potential biological impact. Future research is needed for uncovering the factors which produced the in vivo responses in fish. Copyright © 2018 Elsevier B.V. All rights reserved.

What Would Have Happened to the Ozone Layer if Chlorofluorocarbons (CFCs) had not been Regulated?

NASA Technical Reports Server (NTRS)

Newman, Paul A.; Oman, L. D.; Douglass, A. R.; Fleming, E. L.; Frith, S. M.; Hurwitz, M. M.; Kawa, S. R.; Jackman, C. H.; Krotkov, N. A.; Nash, E. R.;

A photosynthesis-based two-leaf canopy stomatal ...

EPA Pesticide Factsheets

A coupled photosynthesis-stomatal conductance model with single-layer sunlit and shaded leaf canopy scaling is implemented and evaluated in a diagnostic box model with the Pleim-Xiu land surface model (PX LSM) and ozone deposition model components taken directly from the meteorology and air quality modeling system—WRF/CMAQ (Weather Research and Forecast model and Community Multiscale Air Quality model). The photosynthesis-based model for PX LSM (PX PSN) is evaluated at a FLUXNET site for implementation against different parameterizations and the current PX LSM approach with a simple Jarvis function (PX Jarvis). Latent heat flux (LH) from PX PSN is further evaluated at five FLUXNET sites with different vegetation types and landscape characteristics. Simulated ozone deposition and flux from PX PSN are evaluated at one of the sites with ozone flux measurements. Overall, the PX PSN simulates LH as well as the PX Jarvis approach. The PX PSN, however, shows distinct advantages over the PX Jarvis approach for grassland that likely result from its treatment of C3 and C4 plants for CO2 assimilation. Simulations using Moderate Resolution Imaging Spectroradiometer (MODIS) leaf area index (LAI) rather than LAI measured at each site assess how the model would perform with grid averaged data used in WRF/CMAQ. MODIS LAI estimates degrade model performance at all sites but one site having exceptionally old and tall trees. Ozone deposition velocity and ozone flux along with LH

Intense Electrochemical Oxidation on Graphitized Carbon Electrodes in the Presence of Ozone

NASA Astrophysics Data System (ADS)

Klochikhin, V. L.; Potapova, G. F.; Putilov, A. V.

2018-06-01

A new intense oxidation process for water treatment in which oxidation with ozone is coupled to electrochemical processes is described, and the results from its application to water purification are presented along with the discussion of its practical implementation. The use of graphitized carbon materials for this process is explained and tested experimentally. The use of glassy carbon for the anode enables us to achieve very high (up to 25 vol %) concentrations of ozone in the generated ozone-oxygen mixture. The material used for the cathode—graphitized carbon cloth (GCC) reinforced with Ni allows different electrocatalytic processes to proceed on its developed surface, and combines the high sorption capacity of this cathode and potentialcontrolled selectivity of cathodic electrochemical processes.

The Sensitivity of U.S. Surface Ozone Formation to NOx, and VOCs as Viewed from Space

NASA Technical Reports Server (NTRS)

Duncan, Bryan N.; Yoshida, Yasuko; Sillman, Sanford; Retscher, Christian; Pickering, Kenneth E.; Martin, Randall V.; Celarier, Edward A.

2009-01-01

We investigated variations in the sensitivity of surface ozone formation in summer to precursor species concentrations of volatile organic compounds (VOCs) and nitrogen oxides (NO(x)) as inferred from the ratio of tropospheric columns of formaldehyde and nitrogen dioxide from the Aura Ozone Monitoring Instrument (OMI). The data indicate that ozone formation became: 1. more sensitive to NO(x) over most of the U.S, from 2005 to 2007 because of substantial decreases in NO(x) emissions primarily from stationary sources, and 2. more sensitive to NO(x) with increasing temperature, in part because emissions of highly reactive, biogenic isoprene increase with temperature, thus increasing the total VOC reactivity. Based on our interpretation of the data, current strategies implemented to reduce unhealthy levels of surface ozone should focus more on reducing NO(x) emissions, except in some downtown areas which have historically benefited from reductions in VOC emissions.

Developing a predictive tropospheric ozone model for Tabriz

NASA Astrophysics Data System (ADS)

Khatibi, Rahman; Naghipour, Leila; Ghorbani, Mohammad A.; Smith, Michael S.; Karimi, Vahid; Farhoudi, Reza; Delafrouz, Hadi; Arvanaghi, Hadi

2013-04-01

Predictive ozone models are becoming indispensable tools by providing a capability for pollution alerts to serve people who are vulnerable to the risks. We have developed a tropospheric ozone prediction capability for Tabriz, Iran, by using the following five modeling strategies: three regression-type methods: Multiple Linear Regression (MLR), Artificial Neural Networks (ANNs), and Gene Expression Programming (GEP); and two auto-regression-type models: Nonlinear Local Prediction (NLP) to implement chaos theory and Auto-Regressive Integrated Moving Average (ARIMA) models. The regression-type modeling strategies explain the data in terms of: temperature, solar radiation, dew point temperature, and wind speed, by regressing present ozone values to their past values. The ozone time series are available at various time intervals, including hourly intervals, from August 2010 to March 2011. The results for MLR, ANN and GEP models are not overly good but those produced by NLP and ARIMA are promising for the establishing a forecasting capability.

Comparison of Wintertime Ozone Production Associated With Oil and Gas Extraction Activity in Wyoming and Utah

NASA Astrophysics Data System (ADS)

Oltmans, S. J.; Schnell, R. C.; Mefford, T. K.; Neely, R. R., III

2012-12-01

The wintertime cold, reduced sunlight conditions of the mid-latitudes of continental interior locations are normally not considered to be conducive to significant ozone production. Recent observations have shattered this expectation with hourly ozone mixing ratios regularly exceeding 100 ppb measured in January, February and March in the states of Wyoming and Utah in the United States. Maximum daily eight hour average ozone mixing ratios have exceeded 100 ppb, far exceeding the U.S. threshold of 75 ppb. Conditions under which this dramatic ozone production takes place include a mix of high levels of ozone precursors (NOx and VOCs), a very stable and shallow boundary layer, snow cover providing enhanced UV radiation, and air confining terrain features. The high levels of precursors have been tied to oil and gas extraction activities in the affected regions. Under the requisite meteorological conditions where high pressure, low winds, and snow-covered ground are present extremely stable and shallow (~50-200 m) boundary layers persist. The highly reflective snow cover provides enhanced photolysis rates that in February can exceed those in June. For several winters in Utah and Wyoming with large ozone enhancements, the time series of various meteorological (wind, temperature, solar radiation, snow cover) and chemical parameters (ozone and NOx) show a somewhat different progression of high ozone events between the two locations. In the Unitah Basin of Utah high ozone formation conditions are more persistent throughout the winter than in the Pinedale Anticline region of Wyoming. This is likely a function of the differing topography of the two areas. However, for individual events the two sites show a similar progression of rapid ozone formation each day. Sites in both Utah and Wyoming just outside the oil and gas extraction activity areas show little or no enhanced ozone. Winters without the requisite meteorological conditions also do not experience high ozone events.

76 FR 59090 - Approval and Promulgation of Implementation Plans; Oregon: New Source Review/Prevention of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-09-23

...EPA is proposing to approve a portion of the State Implementation Plan (SIP) revision submitted by the State of Oregon for the purpose of addressing the third element of the interstate transport provisions of Clean Air Act (CAA or the Act) section 110(a)(2)(D)(i)(II) for the 1997 8-hour ozone National Ambient Air Quality Standards (NAAQS or standards) and the 1997 and 2006 fine particulate matter (PM2.5) NAAQS. The third element of CAA section 110(a)(2)(D)(i)(II) requires that a State not interfere with any other State's required measures to prevent significant deterioration (PSD) of its air quality. EPA is also proposing to approve numerous revisions to the Oregon SIP that were submitted to EPA by the State of Oregon on October 8, 2008; October 10, 2008; March 17, 2009; June 23, 2010; December 22, 2010 and May 5, 2011. The revisions include updating Oregon's new source review (NSR) rules to be consistent with current Federal regulations and streamlining Oregon's air quality rules by clarifying requirements, removing duplicative rules, and correcting errors. The revisions were submitted in accordance with the requirements of section 110 and part D of the Act).

Dynamic evaluation of two decades of WRF-CMAQ ozone simulations over the contiguous United States

EPA Science Inventory

Dynamic evaluation of the fully coupled Weather Research and Forecasting (WRF)– Community Multi-scale Air Quality (CMAQ) model ozone simulations over the contiguous United States (CONUS) using two decades of simulations covering the period from 1990 to 2010 is conducted to ...

Dynamic evaluation of two decades of WRF-CMAQ ozone simulations over the contiguous United States

EPA Science Inventory

Dynamic evaluation of the fully coupled Weather Research and Forecasting (WRF)– Community Multi-scale Air Quality (CMAQ) model ozone simulations over the contiguous United States (CONUS) using two decades of simulations covering the period from 1990 to 2010 is conducted to assess...

ASSESSING OZONE EFFECTS ON PLANTS NATIVE TO THE SOUTHEASTERN UNITED STATES

EPA Science Inventory

For the last six years, the U.S. National Park Service, U.S. Environmental Protection Agency, and University researchers have been documenting the effects of ozone on a large number of woody and herbaceous species native to the southeastern United States. n Great Smoky Mountains ...

Uncertainties in Episodic Ozone Modeling Stemming from Uncertainties in the Meteorological Fields.

NASA Astrophysics Data System (ADS)

Biswas, Jhumoor; Trivikrama Rao, S.

2001-02-01

This paper examines the uncertainty associated with photochemical modeling using the Variable-Grid Urban Airshed Model (UAM-V) with two different prognostic meteorological models. The meteorological fields for ozone episodes that occurred during 17-20 June, 12-15 July, and 30 July-2 August in the summer of 1995 were derived from two meteorological models, the Regional Atmospheric Modeling System (RAMS) and the Fifth-Generation Pennsylvania State University-National Center for Atmospheric Research Mesoscale Model (MM5). The simulated ozone concentrations from the two photochemical modeling systems, namely, RAMS/UAM-V and MM5/UAM-V, are compared with each other and with ozone observations from several monitoring sites in the eastern United States. The overall results indicate that neither modeling system performs significantly better than the other in reproducing the observed ozone concentrations. The results reveal that there is a significant variability, about 20% at the 95% level of confidence, in the modeled 1-h ozone concentration maxima from one modeling system to the other for a given episode. The model-to-model variability in the simulated ozone levels is for most part attributable to the unsystematic type of errors. The directionality for emission controls (i.e., NOx versus VOC sensitivity) is also evaluated with UAM-V using hypothetical emission reductions. The results reveal that not only the improvement in ozone but also the VOC-sensitive and NOx-sensitive regimes are influenced by the differences in the meteorological fields. Both modeling systems indicate that a large portion of the eastern United States is NOx limited, but there are model-to-model and episode-to-episode differences at individual grid cells regarding the efficacy of emission reductions.

Ozonation and ultrafiltration for the treatment of olive mill wastewaters: effect of key operating conditions and integration schemes.

PubMed

Martins, Rui C; Ferreira, Ana M; Gando-Ferreira, Licínio M; Quinta-Ferreira, Rosa M

2015-10-01

With the objective of reaching suitable techniques for olive mill wastewater treatment, ozonation and ultrafiltration were studied individually and combined. A continuous reactor was run for the treatment of a phenolic mixture mimicking an actual olive mill wastewater (OMW) by ozonation. The effect of the main operating parameters was analysed (pH, liquid flow rate and ozone inlet concentration). The increase of pH and ozone dose improved ozonation efficiency. As expected, the highest residence time led to higher steady-state degradation (35 % of chemical oxygen demand (COD) abatement). Even if the rise on ozone inlet gas concentration was able to remove COD in a higher extent, it should be taken into consideration that with the lowest oxidant load (15 g O3/m(3)), the maximum steady-state biochemical oxygen demand (BOD5)/COD ratio was reached which would reduce the process costs. These operating conditions (pH 9, 1 mL/min of liquid flow rate and 15 g O3/m(3)) were applied to an actual OMW leading to 80 % of phenolic content abatement and 12 % of COD removal at the steady state. Regarding ultrafiltration, it was concluded that the best total phenolic content (TPh) and COD abatement results (55 and 15 %) are attained for pH 9 and using a transmembrane pressure drop of 1 bar. Among the integration schemes that were tested, ultrafiltration followed by ozonation was able to reach 93 and 20 % of TPh and COD depletion, respectively. Moreover, this sequence led to an effluent with a BOD5/COD ratio of about 0.55 which means that it likely can be posteriorly refined in a municipal wastewater treatment plant.