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Sample records for partially melted zone

  1. ``Partial Melting'' Of Fault Zones: A Mechanism Of Seismic Slip Termination

    NASA Astrophysics Data System (ADS)

    Otsuki, K.; Koizumi, Y.

    2004-12-01

    ), Te is calculated at 27 μ s, close to the observation of 17 μ s. Assuming V=1 m/s and σ =275 MPa for seismic slips, Te=7.5 ms (7.5 mm slip), but it will be much larger when the slip is diffused in the fault zone with a finite width. 3) Full melting region: small μ (ca. 0.4-0.1) and W at large V. When the barrier of the partial melting is overcome, fault slip will run away.

  2. Migmatites in the Ivrea Zone (NW Italy): Constraints on partial melting and melt loss in metasedimentary rocks from Val Strona di Omegna

    NASA Astrophysics Data System (ADS)

    Redler, Charlotte; White, Richard W.; Johnson, Tim E.

    2013-08-01

    The mid to lower crustal metamorphic field gradient through amphibolite and granulite facies rocks in the Ivrea Zone offers the potential to study partial melting and melt loss in the crust. Metapelitic rocks in Val Strona di Omegna show a progressive evolution in migmatite structures from metatexites with rare isolated leucosome veins in the amphibolite facies rocks to stromatic migmatites and diatexites in granulite facies rocks. Little field or petrographic evidence for melting can be seen on crossing the position of the modelled wet solidus, consistent with the small amounts of melt predicted to occur by H2O-saturated melting. The first field evidence for partial melting, in the form of narrow discontinuous leucosomes, coincides with the fluid-absent breakdown of muscovite and the prograde appearance of K-feldspar. The consumption of biotite, which is modelled to occur over a 50-100 °C wide field of coexisting garnet-sillimanite-biotite, led to more pronounced melting and the formation of abundant garnet-bearing leucosomes. At the highest grades, metagreywacke compositions contain leucosomes that are spatially focussed on orthopyroxene porphyroblasts. Calculated P-T pseudosections show that the metapelitic rocks could have produced up to 40 mol% melt and the metagreywackes up to 25% melt at peak metamorphic conditions of around 11 kbar, 900 °C. Modelling of granulite facies samples shows elevated solidi suggesting significant melt loss prior to cooling, consistent with depletion in SiO2, Na2O and K2O and enrichment in FeO, MgO and TiO2 relative to amphibolite facies samples. Zones of diatexite in the highest grade rocks indicate that, at least locally, melt loss was inefficient and/or accumulation of melt occurred. Zones of apparent accumulation of melt are common at the boundaries between metatexitic metagreywacke and diatexitic metapelite, and may indicate that the metagreywacke formed a low-permeability barrier that restricted melt flow.

  3. Experimental Hydrous Partial Melting of Natural Pristine and Altered MORB Beneath Subduction Zones

    NASA Astrophysics Data System (ADS)

    Carter, L. B.; Skora, S. E.; Blundy, J.

    2012-12-01

    ). Textural evidence further suggests that the K-composition of the starting material likely contributes to the location of the elusive second critical endpoint. Textural evidence implies the presence of 2 immiscible fluids at 850°C in the pristine MORB sample (in agreement with the location of the second critical endpoint of Kessel et al. 2005, using K-free MORB). This is in contrast to AOC which appears to have had only a single fluid phase (in agreement with the conclusion of Klimm et al. 2008, simulating a synthetic AOC composition). Accessory phases, apart from rutile, were not yet positively identified in our run products. Instead, we will use trace element data combined with a mass balance approach and fractionation of key trace element ratios (e.g. U/Th; La/Th, etc.) to evaluate whether accessory phases are present or not. Our study suggests that subducted MORB may behave heterogeneously during partial melting in subduction zone environments, owing to significant chemical variations in the K2O content of pristine versus altered oceanic crust. Geochemical analysis of the resulting mineralogy and melt composition of this study will further assist in the understanding of element transfer from the subducted slab to the overriding mantle wedge.

  4. Microstructure formation in partially melted zone during gas tungsten arc welding of AZ91 Mg cast alloy

    SciTech Connect

    Zhu Tianping Chen, Zhan W.; Gao Wei

    2008-11-15

    During gas tungsten arc (GTA) welding of AZ91 Mg cast alloy, constitutional liquid forms locally in the original interdendritic regions in the partially melted zone (PMZ). The PMZ re-solidification behaviour has not been well understood. In this study, the gradual change of the re-solidification microstructure within PMZ from base metal side to weld metal side was characterised. High cooling rate experiments using Gleeble thermal simulator were also conducted to understand the morphological change of the {alpha}-Mg/{beta}-Mg{sub 17}Al{sub 12} phase interface formed during re-solidification after partial melting. It was found that the original partially divorced eutectic structure has become a more regular eutectic phase in most of the PMZ, although close to the fusion boundary the re-solidified eutectic is again a divorced one. Proceeding the eutectic re-solidification, if the degree of partial melting is sufficiently high, {alpha}-Mg re-solidified with a cellular growth, resulting in a serrated interface between {alpha}-Mg and {alpha}-Mg/{beta}-Mg{sub 17}Al{sub 12} in the weld sample and between {alpha}-Mg and {beta}-Mg{sub 17}Al{sub 12} (fully divorced eutectic) in Gleeble samples. The morphological changes affected by the peak temperature and cooling rate are also explained.

  5. Microstructures and crystallographic fabric evolution during melt-present and melt-absent conditions in the partially molten middle crust: the Patos shear zone (Borborema Province, NE Brazil)

    NASA Astrophysics Data System (ADS)

    Ferreira Viegas, Luís Gustavo; Archanjo, Carlos; Vauchez, Alain

    2013-04-01

    The Patos shear zone is an exposed segment of the partially molten middle crust characterized by a 600 km long, E-trending transcurrent structure that deforms the Precambrian rocks of the Borborema Province. High-temperature (HT) mylonites with low melt fractions (~ 5%) constitute most of the shear belt, while a narrow strip of highly strained mylonites to ultramylonites outlines its southern margin. Migmatites and "transitional" mylonites occur sandwiched between these tectonites. A progressive microfabric development is recorded from melt-bearing mylonites to high-strain ultramylonites. A microstructural study was carried out to understand the fabric evolution from melt-assisted to melt-absent deformation. Fabrics were investigated by optical and scanning electron microscopy (SEM), and crystallographic preferred orientations were measured by Electron Backscatter Diffraction (EBSD). Melt-bearing HT-mylonites display solid-state microstructures with coarse quartz ribbons and sutured grain boundaries. K-feldspar clasts are often fractured and show peripheral myrmekite. Towards the contact with anatexites the microfabric becomes typically magmatic with abundant interstitial quartz. Transitional mylonites, located immediately south of the migmatites, are marked by progressive grain size reduction of recrystallized felsic phases. High-strain mylonites have a fine-grained quartz-feldspar matrix with relics of quartz ribbons and fractured K-feldspar. Melt-bearing mylonites display quartz [0001] axes forming maxima mainly on Y, while quartz fabrics in the anatexite are weaker and diffuse, suggesting deformation in the magmatic state. In transitional and high-strain mylonites the measured quartz CPOs show [0001] concentrations between Z and Y. K-feldspar and plagioclase fabrics record mainly the activity of (010)[001] and (010)[100] slip systems in all rock types, with local activity of the (100)[010] slip system in the transitional mylonites. These data suggest that the

  6. CO2 Solubility in Natural Rhyolitic Melts at High Pressures - Implications for Carbon Flux in Subduction Zones by Sediment Partial Melts

    NASA Astrophysics Data System (ADS)

    Duncan, M. S.; Dasgupta, R.

    2011-12-01

    Partial melts of subducting sediments is thought to be a critical agent in carrying trace elements and water to arc basalt source regions. For subduction zones that contain significant amount of carbonates in ocean-floor sediments, sediment melts likely also act as a carrier of CO2. However, the CO2 carrying capacity of natural rhyolitic melts at sub-arc depths remains unconstrained. We conducted experiments on a synthetic composition, similar to average, low-degree experimental partial melt of pelitic sediments. The composition was constructed with reagent grade oxides and carbonates, the source of excess CO2. Experiments were conducted between 1 and 3 GPa at 1200 °C in Au80Pd20 capsules using a piston cylinder apparatus with a half-inch BaCO3 assembly at Rice University. Quench products showed glasses with bubbles, the latter suggesting saturation of the melt with a CO2-rich vapor phase. Oxygen fugacity during the experiments was not strictly controlled but the presence of CO2 bubbles and absence of graphite indicates fO2 above the CCO buffer. Major element concentrations of glasses were measured using EPMA. The CO2 and H2O contents of experimental doubly polished (50-110 μm), bubble-free portions of the glass chips were determined using a Thermo Nicolet Fourier Transform Infrared Spectrometer. Spectra were recorded with a resolution of 4 cm-1, 512 scans, from 650 to 4000 cm-1, under a nitrogen purge to eliminate atmospheric gases. Dissolved volatile concentrations were quantified using the Beer-Lambert law and linear molar absorption coefficients from previous studies [1, 2]. Total dissolved carbon dioxide of experimental glasses was determined from the intensity of the ν3 antisymmetric stretch bands of CO32- at 1430 cm-1 and CO2mol at 2348 cm-1. Dissolved water content of experimental glasses was determined from the intensity of O-H stretching at 3520 cm-1. Estimated total CO2 concentrations at 3 GPa are in the range of 1-2 wt%, for melts with H2O contents

  7. CO2 solubility and speciation in rhyolitic sediment partial melts at 1.5-3.0 GPa - Implications for carbon flux in subduction zones

    NASA Astrophysics Data System (ADS)

    Duncan, Megan S.; Dasgupta, Rajdeep

    2014-01-01

    much as 2.6-5.5 wt.% CO2 to the sub-arc mantle source regions. At saturation, 1.6-3.3 wt.% sediment partial melt relative to the mantle wedge is therefore sufficient to bring up the carbon budget of the mantle wedge to produce primary arc basalts with 0.3 wt.% CO2. Sediment plumes in mantle wedge: Sediment plumes or diapirs may form from the downgoing slab because the sediment layer atop the slab is buoyant relative to the overlying, hanging wall mantle (Currie et al., 2007; Behn et al., 2011). Via this process, sediment layers with carbonates would carry CO2 to the arc source region. Owing to the higher temperature in the mantle wedge, carbonate can breakdown. Behn et al. (2011) suggested that sediment layers as thin as 100 m, appropriate for modern arcs, could form sediment diapirs. They predicted that diapirs would form from the slab in the sub-arc region for most subduction zones today without requiring hydrous melting. H2O-rich fluid driven carbonate breakdown: Hydrous fluid flushing of the slab owing to the breakdown of hydrous minerals could drive carbonate breakdown (Kerrick and Connolly, 2001b; Grove et al., 2002; Gorman et al., 2006). The addition of water would cause decarbonation creating an H2O-CO2-rich fluid that would then flux through the overlying sediment layer, lower the solidus temperature, and trigger melting. Recent geochemical (Cooper et al., 2012) and geodynamic (van Keken, 2003; Syracuse et al., 2010) constraints suggest that the sub-arc slab top temperatures are above the hydrous fluid-present sediment solidus, thus in the presence of excess fluid, both infiltration induced decarbonation and sediment melting may occur. Hot subduction: This is relevant for subduction zones such as Cascadia and Mexico, where slab-surface temperatures are estimated to be higher (Syracuse et al., 2010). A higher temperature could cause carbonate breakdown and sediment partial melting without requiring a hydrous fluid flux. In this case a relatively dry silicate

  8. Reaction between Metapelite-derived Hydrous Partial Melt and Subsolidus Fertile Peridotite at 2-3 GPa - Generation of High-K Magmas in Subduction Zones

    NASA Astrophysics Data System (ADS)

    Nelson, J. M.; Mallik, A.; Dasgupta, R.

    2013-12-01

    Trace compositions of arc magmas display signatures of recycled sediments [1] and thermal and geodynamic models of subduction zones suggest that sediment contribution to sub-arc mantle occurs in the form of hydrous melts generated at the slab-mantle interface by fluid-present melting [2, 3] or in the mantle wedge by diapiric rise of downgoing sediments [4]. Partial melts of hydrous pelitic sediments are rhyolitic in P-T conditions of the mantle wedge and are out of equilibrium with the surrounding peridotite, which implies inevitable reaction between such melt and overlying peridotite. However, partial melting in the mantle wedge with slab input has mostly been studied in peridotite+H2O systems [e.g. 5] and experimental constraints on sediment-peridotite hybrid remain limited [6]. In this study, we explore the phase equilibria of a sediment melt-fluxed fertile peridotite with the aim of understanding genesis of high-K arc magmas. Experiments were performed in AuPd capsules using a piston cylinder, on a 1:3 mixture of rhyolitic melt with 7.3 wt.% H2O [3] and fertile peridotite from 1150-1350 °C at 2-3 GPa. Interstitial melt/fluid is present at 1150 °C, 2 GPa and 1150-1200 °C, 3 GPa. While residual opx+cpx+biotite are present at both pressures, olivine is present from 1200-1300 °C, 2 GPa and garnet from 1150-1300 °C, 3 GPa. Cpx and biotite disappear at 1200-1250 °C, 2 GPa and 1350 °C, 3 GPa. At 2 GPa, from 1200-1300 °C, the melt composition (on a volatile-free basis), shows an increase in SiO2 (50-51 wt.%), MgO (10-14 wt.%) and decrease in Al2O3 (16-14 wt.%), CaO (10-7 wt.%), Na2O (3-2 wt.%) and H2O (13-8 wt.%.). K2O increases from 5 to 7 wt.% till 1250 °C followed by a decrease to 5 wt.%, at 1300 °C. FeO* varies between 6 and 5 wt.%. At 3 GPa, from 1225-1350 °C, the reacted melt displays an increase in SiO2 (47-49 wt.%), FeO* (4.2-5.4 wt.%), MgO (11-14 wt.%), and decrease in Al2O3 (15-14 wt.%), CaO (12-7 wt.%), Na2O (4-3 wt.%) and H2O (16-11 wt.%). K2O

  9. Melt migration modeling in partially molten upper mantle

    NASA Astrophysics Data System (ADS)

    Ghods, Abdolreza

    The objective of this thesis is to investigate the importance of melt migration in shaping major characteristics of geological features associated with the partial melting of the upper mantle, such as sea-floor spreading, continental flood basalts and rifting. The partial melting produces permeable partially molten rocks and a buoyant low viscosity melt. Melt migrates through the partially molten rocks, and transfers mass and heat. Due to its much faster velocity and appreciable buoyancy, melt migration has the potential to modify dynamics of the upwelling partially molten plumes. I develop a 2-D, two-phase flow model and apply it to investigate effects of melt migration on the dynamics and melt generation of upwelling mantle plumes and focusing of melt migration beneath mid-ocean ridges. Melt migration changes distribution of the melt-retention buoyancy force and therefore affects the dynamics of the upwelling plume. This is investigated by modeling a plume with a constant initial melt of 10% where no further melting is considered. Melt migration polarizes melt-retention buoyancy force into high and low melt fraction regions at the top and bottom portions of the plume and therefore results in formation of a more slender and faster upwelling plume. Allowing the plume to melt as it ascends through the upper mantle also produces a slender and faster plume. It is shown that melt produced by decompressional melting of the plume migrates to the upper horizons of the plume, increases the upwelling velocity and thus, the volume of melt generated by the plume. Melt migration produces a plume which lacks the mushroom shape observed for the plume models without melt migration. Melt migration forms a high melt fraction layer beneath the sloping base of the impermeable oceanic lithosphere. Using realistic conditions of melting, freezing and melt extraction, I examine whether the high melt fraction layer is able to focus melt from a wide partial melting zone to a narrow region

  10. Fabrics of migmatites and relationships between partial melting and deformation in high-grade transpressional shear zones: the Patos anatexite (Borborema Province, NE Brazil)

    NASA Astrophysics Data System (ADS)

    Viegas, L. G. F.; Archanjo, C. J.; Vauchez, A.

    2012-04-01

    Migmatites are heterogeneous rocks that record flow processes in the middle crust of actively deforming orogens. The Patos anatexite is located within a transpressional, high-temperature shear zone in which mylonites are associated with partial melting at different scales. The relationships between melting and deformation inside continental ductile shear zones can be hindered due to the apparent structural complexity of migmatites, which encompass shear zone-parallel syntectonic leucosome veins, randomly-oriented nebulites and isotropic leucogranite accumulations of various sizes. A comprehensive petrostructural study was carried out in these rocks in order to test the compatibility of field, magnetic and crystallographic fabrics with the kinematics of melt deformation within high-grade shear zones. Magnetic fabrics of partially molten rocks were investigated using the anisotropy of magnetic susceptibility (AMS) and anisotropy of anhysteretic remanence (AAR). Crystallographic preferred orientations (CPOs) were measured using Electron Backscatter Diffraction (EBSD). Bulk AMS results indicate that ferromagnetic minerals dominate the overall susceptibility of the Patos anatexite, while a subset of samples shows composite ferro- and paramagnetic susceptibilities. AAR in the paramagnetic subfabrics reveals coaxiality between ferro- and paramagnetic fabric ellipsoids, suggesting formation of the magnetic fabric in the Patos anatexite as resulting from a single viscous flow process. AMS lineations display a well-oriented pattern in which magnetic foliations rotate consistently with a dextral simple shear sense, while AAR subfabrics are broadly parallel to the main AMS axes. The CPO of biotite crystals shows a good correlation of <001> axes with the k3 direction of the magnetic susceptibility ellipsoid in samples displaying orientations consistent with the shear-zone fabric and dominantly ferromagnetic behavior. In sites where the nebulitic fabric displays complex patterns

  11. Partial melting of carbonated pelite at 3-7 GPa and deep cycling of CO2 and H2O in subduction zones

    NASA Astrophysics Data System (ADS)

    Tsuno, K.; Dasgupta, R.; Danielson, L. R.; Righter, K.

    2011-12-01

    The exchange of water and carbon dioxide between the Earth's crustal rocks and the interior is important for understanding geochemical and geophysical evolution of the planet on geologic timescale. Subduction of pelitic sediments is a key mechanism for volatile introduction to the mantle but the high-pressure behavior of H2O+ CO2 bearing sediments is only constrained for alumina-rich, low-Mg# bulk compositions [1, 2]. However, the ocean-floor sediments for many subduction zones that contain both water and CO2 are alumina-poor and have higher Mg#. To constrain the melting behavior of a model alumina poor carbonated pelite, we performed new experiments. Piston cylinder (3 GPa) and multianvil (5 and 7 GPa) experiments were conducted between 800 and 1150 °C, using a model sediment composition containing 1 wt.% H2O and 5 wt.% CO2 (trace vapor-present at subsolidus conditions). The choice of the bulk composition was aimed to model the loss of siliceous hydrous fluid during the shallow part of subduction. We determined the solidus temperatures between 800 and 850 °C at 3 GPa, 900 and 950 °C at 5 GPa, and <1000 °C at 7 GPa. The subsolidus phases include cpx, garnet, coesite, rutile, phengite, and calcitess at 3 GPa, and kyanite comes in at 5 GPa. Hydrous rhyolitic silicate melt was observed at 3 GPa and up to 1150 °C. The near-solidus melt at 5-7 GPa was K-rich and calcio-carbonatitic, in contrast to the previous experimental results in alumina-rich and low Mg# bulk composition [1, 2], which showed the stability of Al-rich trachyitic silicate melt at near-solidus temperatures up to 5 GPa, and replaced by carbonate melt only at ≥5.5 GPa. Carbonate-silicate melt immiscibility was observed at 5 GPa, 1100 °C in our study. The phengite-out boundary is located between 850 and 900 °C at 3 GPa, between 1000 and 1100 °C at 5 GPa, and <1000 °C at 7 GPa. The crystalline carbonate-out boundary is between 950 and 1000 °C at 3 and 5 GPa, and <1000 °C at 7 GPa. Comparison of

  12. Floating zone melting of cadmium telluride

    NASA Technical Reports Server (NTRS)

    Chang, Wen-Ming; Regel, L. L.; Wilcox, W. R.

    1992-01-01

    To produce superior crystals of cadmium telluride, floating zone melting in space has been proposed. Techniques required for floating zone melting of cadmium telluride are being developed. We have successfully float-zoned cadmium telluride on earth using square rods. A resistance heater was constructed for forming the molten zone. Evaporation of the molten zone was controlled by adding excess cadmium to the growth ampoule combined with heating of the entire ampoule. An effective method to hold the feed rod was developed. Slow rotation of the growth ampoule was proven experimentally to be necessary to achieve a complete symmetric molten zone. Most of the resultant cylindrical rods were single crystals with twins. Still needed is a suitable automatic method to control the zone length. We tried a fiber optical technique to control the zone length, but experiments showed that application of this technique to automate zone length control is unlikely to be successful.

  13. Experimental evidence supports mantle partial melting in the asthenosphere.

    PubMed

    Chantel, Julien; Manthilake, Geeth; Andrault, Denis; Novella, Davide; Yu, Tony; Wang, Yanbin

    2016-05-01

    The low-velocity zone (LVZ) is a persistent seismic feature in a broad range of geological contexts. It coincides in depth with the asthenosphere, a mantle region of lowered viscosity that may be essential to enabling plate motions. The LVZ has been proposed to originate from either partial melting or a change in the rheological properties of solid mantle minerals. The two scenarios imply drastically distinct physical and geochemical states, leading to fundamentally different conclusions on the dynamics of plate tectonics. We report in situ ultrasonic velocity measurements on a series of partially molten samples, composed of mixtures of olivine plus 0.1 to 4.0 volume % of basalt, under conditions relevant to the LVZ. Our measurements provide direct compressional (V P) and shear (V S) wave velocities and constrain attenuation as a function of melt fraction. Mantle partial melting appears to be a viable origin for the LVZ, for melt fractions as low as ~0.2%. In contrast, the presence of volatile elements appears necessary to explaining the extremely high V P/V S values observed in some local areas. The presence of melt in LVZ could play a major role in the dynamics of plate tectonics, favoring the decoupling of the plate relative to the asthenosphere. PMID:27386548

  14. Experimental evidence supports mantle partial melting in the asthenosphere.

    PubMed

    Chantel, Julien; Manthilake, Geeth; Andrault, Denis; Novella, Davide; Yu, Tony; Wang, Yanbin

    2016-05-01

    The low-velocity zone (LVZ) is a persistent seismic feature in a broad range of geological contexts. It coincides in depth with the asthenosphere, a mantle region of lowered viscosity that may be essential to enabling plate motions. The LVZ has been proposed to originate from either partial melting or a change in the rheological properties of solid mantle minerals. The two scenarios imply drastically distinct physical and geochemical states, leading to fundamentally different conclusions on the dynamics of plate tectonics. We report in situ ultrasonic velocity measurements on a series of partially molten samples, composed of mixtures of olivine plus 0.1 to 4.0 volume % of basalt, under conditions relevant to the LVZ. Our measurements provide direct compressional (V P) and shear (V S) wave velocities and constrain attenuation as a function of melt fraction. Mantle partial melting appears to be a viable origin for the LVZ, for melt fractions as low as ~0.2%. In contrast, the presence of volatile elements appears necessary to explaining the extremely high V P/V S values observed in some local areas. The presence of melt in LVZ could play a major role in the dynamics of plate tectonics, favoring the decoupling of the plate relative to the asthenosphere.

  15. Experimental evidence supports mantle partial melting in the asthenosphere

    PubMed Central

    Chantel, Julien; Manthilake, Geeth; Andrault, Denis; Novella, Davide; Yu, Tony; Wang, Yanbin

    2016-01-01

    The low-velocity zone (LVZ) is a persistent seismic feature in a broad range of geological contexts. It coincides in depth with the asthenosphere, a mantle region of lowered viscosity that may be essential to enabling plate motions. The LVZ has been proposed to originate from either partial melting or a change in the rheological properties of solid mantle minerals. The two scenarios imply drastically distinct physical and geochemical states, leading to fundamentally different conclusions on the dynamics of plate tectonics. We report in situ ultrasonic velocity measurements on a series of partially molten samples, composed of mixtures of olivine plus 0.1 to 4.0 volume % of basalt, under conditions relevant to the LVZ. Our measurements provide direct compressional (VP) and shear (VS) wave velocities and constrain attenuation as a function of melt fraction. Mantle partial melting appears to be a viable origin for the LVZ, for melt fractions as low as ~0.2%. In contrast, the presence of volatile elements appears necessary to explaining the extremely high VP/VS values observed in some local areas. The presence of melt in LVZ could play a major role in the dynamics of plate tectonics, favoring the decoupling of the plate relative to the asthenosphere. PMID:27386548

  16. The Impact of Partial Melting in the Orogenic Cycle

    NASA Astrophysics Data System (ADS)

    Rey, P. F.; Teyssier, C.; Whitney, D. L.

    2010-12-01

    Open source, community driven numerical codes available at geodynamics.org allow geologists to model orogenic processes including partial melting and its consequences during orogenic cycles. Here we explore the role of partial melting during continental subduction and its impact on the evolution of orogenic plateaux and that of migmatite-cored metamorphic core complexes. Continental subduction and orogenic plateaux: Numerical experiments show that when continental slabs buried into the mantle meet their solidus, crustal melt is confined to the slab during its ascent and ponds at the Moho (Fig. 1a). The displaced overlying crust is extruded horizontally into the weak lower crust of the continent, resulting in Earth’s surface uplift to form an orogenic plateau, and Moho downward motion to accommodate the influx of material into the lower crust. This model suggests a link between continental subduction, melting and the build up of orogenic plateaux, and show that partial melting may be a significant process in exhumation of ultrahigh-pressure (UHP) rocks. Model results are consistent with the common association of UHP rocks and migmatite. Growth and destruction of orogenic plateaux: The lateral growth of orogenic plateaux is often attributed to the flow of the plateau weak partially melted lower crust into its foreland in some cases over a distance > 1500 km in 15 myr. Using pre-thickening temperatures compatible with Tibet’s uplift history, we show that mass redistribution processes are dynamically coupled, and that CFE velocities are limited to less than 1 cm.yr-1 (~150 km in 15 myr) by cooling and crystallization of the melted channel in the foreland and by any upward deviation into metamorphic domes of the melted channel by extension in the plateau (Fig. 1b). Gravitational collapse and metamorphic core complexes: Localization of extension in the upper crust triggers convergent flow in the partially molten deep crust channel. This convergent flow leads to the

  17. A Disequilibrium Melting Spectrum: Partially Melted Crustal Xenoliths from the Wudalianchi Volcanic Field, NE China.

    NASA Astrophysics Data System (ADS)

    McLeod, C. L.; McGee, L. E.

    2015-12-01

    Disequilibrium melting has been established as a common process occurring during crustal anatexis and thus demonstrates that crustal assimilation by ascending mantle-derived magmas is likley not a closed system. Observations of extreme compositional heterogeneity within partial melts derived from crustal xenoliths have been documented in several recent examples, however, the retention or transfer of elements to and from residues and glasses, and their relative contributions to potential crustal contaminants warrants further investigation. Sampled lavas from the Huoshaoshan volcano in the Holocene Wudalianchi volcanic field of Northeast China contain crustal xenoliths which preserve a spectrum of partial melting both petrographically and geochemically, thus providing an excellent, natural example of crustal anatexis. Correlations exist between the volume of silicic glass preserved within the xenoliths and bulk rock SiO2 (70-83 wt%), Al2O3 (16-8 wt%), glass 87Sr/86Sr (0.715-0.908), abundances of elements common in feldspars and micas (Sr, Ba, Rb) and elements common in accessory minerals (Y, Zr, Nb). These correlations are likely associated with the consumption of feldspars and micas and the varying retention of accessory phases during partial melting. The xenoliths which contain the greater volumes of silicic glass and residual quartz (interpreted as being the most melted) were found within pahoehoe lava, whilst the least melted xenoliths were found within scoria of the summit cone of Huoshaoshan; thus it is interpreted that the extent of melting is linked to the immersion time in the lava. Small-scale (mm) mingling and transfer of material from the enclosing lava to the xenolith is observed, however, modelling of potential contaminant compositions is inconsistent with crustal contamination during lava petrogenesis. It is inferred that crustal contamination in sampled lavas is localized within the open magmatic system and most likely occurs at the contact zone

  18. Partial melting on the acapulcoite-lodranite meteorite parent body

    NASA Astrophysics Data System (ADS)

    McCoy, Timothy James

    1994-01-01

    Many asteroids experienced partial melting and incomplete differentiation. Our knowledge of the detailed of these processes are incomplete, owing to the paucity of partially melted meteorites. 1 studied two groups of meteorites which originated on a common parent body and are residues of a wide range of partial melting acapulcoites and lodranites. These meteorites formed from a chemically and isotopically heterogeneous precursor chondrite. Heating and cooling occurred early in the history of the solar system, as evidenced by the approximately 4.51 Ga 39 Ar40Ar age of acapulcoites and the approximately 4.48 Ga39Ar40Ar age of the lodranite Gibson. The heating was probably caused by non-collisional heat sources. Acapulcoites (Acapulco, Monument Draw, Yamato 74063, ALH A77081, ALH A81261, ALH A81315, ALH 78230, ALH A81187 and ALH 84190) formed by low degrees of partial melting (e.g., Fe, Ni-FeS eutectic melting, but not silicate partial melting). Fe, Ni-FeS partial melts concentrated into micron- to centimeter-sized veins, but migration distances were short. In contrast, lodranites (Lodran, Gibson, Yamato 791491, Yamato 791493, Yamato 74357, Yamato 8002, Yamato 75274, MAC 88177, LEW 88280, EET 84302 and FRO 90011) experienced higher degrees of partial melting, including silicate partial melting. The higher degree of partial melting allowed efficient melt migration, depleting the residues in plagioclase and troilite. Volatiles played a major role in melt migration, driving partial melts to the surface where they were erupted at greater than the escape velocity and lost into space, Thus, basaltic partial melts are not sampled as discrete meteorites. In one meteorite (LEW 86220), these basaltic, Fe, Ni, FeS-rich partial melts from a lodranite source region were injected into a cooler, acapulcoite region. The acapulcoite-lodranite parent body experienced a range of partial melting and melt migration. Cooling of this body may have been complex, with slow cooling at high

  19. Partial melting as the Cause of the Aesthenosphere - Lithosphere Seismic Discontinuity

    NASA Astrophysics Data System (ADS)

    Weidner, D. J.; Li, L.

    2012-12-01

    The classical view of how partial melts affects seismic velocity models the system as a mechanical aggregate of solid mineral phases with pockets of liquid with zero shear moduli. Such a system has a slow decrease in seismic velocity as the amount of partial melt increases, giving no opportunity for a seismic discontinuity. We assert that a much stronger effect of partial melting results from the dynamic interaction of a solid and liquid that are in thermodynamic equilibrium. Dynamic melting in response to the stress field of the seismic wave will dramatically soften the sound velocities. The salient properties are the volume change on melting, the productivity of melt with pressure, and the characteristic time of melting. In this context, the seismic wave perturbs the equilibrium between the solid and the liquid forcing the increase of one at the expense of the other. In this system, the velocity decrease is independent of the magnitude of the stress field of the seismic wave and the effect is much greater than that of the mechanical mixture of solid and melt. Here we present data on natural samples. KLB1, undergoing partial melting at LVZ conditions. Effective elastic moduli are derived from sinusoidal stress variations at seismic frequencies. The results support the dynamic melting model outline above. These data are successfully modeled by the thermodynamic program MELTS. With this program several scenarios are considered. We find that a mantle peridotite that has been partially melted to 1% and then the melt removed by compaction will display a velocity discontinuity, decreasing the velocity, as the solidus is crossed from solid to partial melt. The total amount of melt required for generating the low velocity zone may well be less than 1% in such a system.

  20. The role of subgrain boundaries in partial melting

    NASA Astrophysics Data System (ADS)

    Levine, Jamie S. F.; Mosher, Sharon; Rahl, Jeffrey M.

    2016-08-01

    Evidence for partial melting along subgrain boundaries in quartz and plagioclase is documented for rocks from the Lost Creek Gneiss of the Llano Uplift, central Texas, the Wet Mountains of central Colorado, and the Albany-Fraser Orogen, southwestern Australia. Domains of quartz or plagioclase crystals along subgrain boundaries are preferentially involved in partial melting over unstrained domains of these minerals. Material along subgrain boundaries in quartz and plagioclase has the same morphology as melt pseudomorphs present along grain boundaries and is commonly laterally continuous with this former grain boundary melt, indicating the material along subgrain boundaries can also be categorized as a melt pseudomorph. Subgrain boundaries consist of arrays of dislocations within a crystal lattice, and unlike fractures would not act as conduits for melt migration. Instead, the presence of former melt along subgrain boundaries requires that partial melting occurred in these locations because it is kinetically more favorable for melting reactions to occur there. Preferential melting in high strain locations may be attributed to strain energy, which provides a minor energetic contribution to the reaction and leads to preferential melting in locations with weakened bonds, and/or the presence of small quantities of water associated with dislocations, which may enhance diffusion rates or locally lower the temperature needed for partial melting.

  1. Geophysical constraints on partial melt in the upper mantle

    SciTech Connect

    Shankland, T.J.; O'Connell, R.J.; Waff, H.S.

    1981-08-01

    This paper adresses the conditions under which partial melt can exist in the mantle in order to be observed as a geophysical 'anomaly'. Typical observed anomalies are high electrical conductivity of the order of 0.1 S/m or greater, velocity decreases of 7--10%, seismic Q values less than 100, and a frequency band for seismic effects in the region mear 1 Hz. Existing theories of electrical conduction in partial melts and of frequency-dependent seismic properties together with recent measurements of melt electrical conductivity, viscosity, and partial melt texture can be used to establish requirements for melt to be observed by geophysical methods. From electrical anomalies, mainly sensitive to melt volume and its interconnection, one can require a minimum melt fraction of several percent at temperatures close to the solidus (1150/sup 0/--1300/sup 0/C). However, seismic models demand only a small volume in very flattened shapes (aspect ratio approx. =0.001, melt fraction approx.0.1%). Further, if melt configuration permits seismic dissipation in bulk, that is, there exist flattened voids intersecting more or less equant voids, then it is possible to infer melt fractions for elastic anomalies that are consistent with the several percent required for electrical anomalies. Observed equilibrium textures of partly melted peridotite together with inferred melt-solid surface energies suggest that melt on a grain size scale in a gravitational field segregates into a strongly anisotropic pattern. Thus if partial melt causes mantle geophysical anomalies, it should exist in a variety of void shapes and probably of sizes. While the association of electrical and elastic anomalies with indications of reduced density, volcanism, and high heat flow makes the hypothesis of partial melting an attractive explanation, the minimum physical requirement is for existence of relatively high temperature.

  2. Partial Melting of the Indarch (EH4) Meteorite : A Textural, Chemical and Phase Relations View of Melting and Melt Migration

    NASA Technical Reports Server (NTRS)

    McCoy, Timothy J.; Dickinson, Tamara L.; Lofgren, Gary E.

    2000-01-01

    To Test whether Aubrites can be formed by melting of enstatite Chondrites and to understand igneous processes at very low oxygen fugacities, we have conducted partial melting experiments on the Indarch (EH4) chondrite at 1000-1500 C. Silicate melting begins at 1000 C. Substantial melt migration occurs at 1300-1400 C and metal migrates out of the silicate change at 1450 C and approx. 50% silicate partial melting. As a group, our experiments contain three immiscible metallic melts 9Si-, and C-rich), two immiscible sulfide melts(Fe-and FeMgMnCa-rich) and Silicate melt. Our partial melting experiments on the Indarch (EH4) enstatite Chondrite suggest that igneous processes at low fO2 exhibit serveral unique features. The complete melting of sulfides at 1000 C suggest that aubritic sulfides are not relicts. Aubritic oldhamite may have crystallized from Ca and S complexed in the silicate melt. Significant metal-sulfide melt migration might occur at relatively low degrees of silicate partial melting. Substantial elemental exchange occurred between different melts (e.g., between sulfide and silicate, Si between silicate and metal), a feature not observed during experiments at higher fO2. This exchange may help explain the formation of aubrites from known enstatite chondrites.

  3. Hydrous Partial Melting Within the Deep Oceanic Crust

    NASA Astrophysics Data System (ADS)

    Koepke, J.; Feig, S. T.; Snow, J.

    2003-12-01

    Our knowledge on the structure, composition, and mineralogy of the in-situ lower oceanic crust (layer 3) and the mechanism how it is formed is poor. Petrological models for its generation, seismic and thermal models require an effective cooling of the deep oceanic crust. The current model implies a conductive mechanism for the cooling, and hydrothermal circulation is regarded to play a small role in transport of heat and masses in the deep oceanic crust (Wilcock, 2003). Here we demonstrate that hydrothermal circulation within the gabbroic layer starts at much higher temperatures (900° - 1000° C) as up to now believed. Water-rich fluids causes hydrous partial melting in a large scale, which is manifested by characteristic microtextures visible within many investigated rocks of all reference locations for oceanic gabbros (sampled by the Ocean Drilling Program (ODP Legs 147, 153, 176) and from the Oman ophiolite). The observed process has the potential for significant transfer of heat and masses between the upper and lower oceanic crust. The interpretation of the observed microstructures as products of hydrous partial melting is based on experimental work. Water-saturated melting experiments on a variety of natural gabbros between 900 and 1000° C at 200 MPa produced silicic melts similar in composition to oceanic plagiogranites (Koepke et al., 2003 in press). The newly formed minerals form a characteristic paragenesis consisting of plagioclase, orthopyroxene and pargasitic amphibole. In all experiments the An content of the new plagioclases is higher compared to that of the protolith, even at the lowest investigated temperature. It can be observed that olivine and clinopyroxene of the protolith react to orthopyroxene and pargasite. Very similar features can be observed in the natural gabbros. The most striking feature are zones within the plagioclase grains showing a strong enrichment in An component, often with An contents which are 20 to 25 mol% higher than those

  4. Wholesale, massive partial melting and melt separation in granite host rock, McMurdo Dry Valleys, Antarctica

    NASA Astrophysics Data System (ADS)

    Currier, R. M.; Marsh, B. D.

    2009-12-01

    During Gondwana breakup, over 104 km3 of basaltic magma was erupted and emplaced through a deep-seated magmatic mush column forming the Ferrar Igneous Complex (FIC) of the McMurdo Dry Valleys. The FIC consists of a 3.5 km interconnected stack of four thick (~350 m) and extensive (~100 km) sills capped by a series of flood basalts. The lowermost sill (Basement Sill) is floored and hosted by a complex of granitic plutons, which generally has undergone no melting at sill contacts. In the vicinity of the newly discovered central feeder vent in central Bull Pass, however, the granitc wall rock is extensively and thoroughly melted for over 40 m above the dolerite contact. The transition from essentially fully melted to un-melted rock is 100% exposed over many kms along the contact, delineating a huge block of crust, perhaps the foot of a massive caldera block, that evidently floated in the sill. Moreover, mafic dikes in the country rock vanish in the melt zone, indicating that the sliding block produced enough shear to stretch, thin, and erase the dikes. The degree and extent of melting clearly reflects the feeding locus for the establishment of the FIC. Besides the loss of dikes, it is the full loss of the coarse granitic texture and the bulk chemical profile that are most distinctive. The partial melt zone thus basically consists of two essential features: post melting residuum granite and granophyric segregations, reflecting locally separated melt. The residuum granite consists of varying amounts of unmelted feldspars and large (5-10 mm) distinctive globular clusters of quartz grains, thermally rounded by partial melting and tightly rimmed with biotite and iron oxides that fade away into unmelted granite. With distance from the contact the style and abundance of the granophyre segregations change in response to the degree of melting. Near the contact, they form irregular, bulbous masses up to several meters across, sometimes containing xenoliths of residuum granite

  5. Partitioning REE between minerals and coexisting melts during partial melting of a garnet lherzolite

    NASA Technical Reports Server (NTRS)

    Harrison, W. J.

    1981-01-01

    Partition coefficients for Ce, Sm, and Tm between garnet, clinopyroxene, orthopyroxene, olivine, and melt are determined at 35 kbar for 2.3, 8, 20, and 37.7% melting of a garnet lherzolite nodule with chondritic REE abundances. Partition coefficients are found to increase as the degree of partial melting increases. From 2.3 to 8% melting, this increase is for the most part a consequence of non-Henry's law behavior of REE in minerals.

  6. An observational and thermodynamic investigation of carbonate partial melting

    NASA Astrophysics Data System (ADS)

    Floess, David; Baumgartner, Lukas P.; Vonlanthen, Pierre

    2015-01-01

    Melting experiments available in the literature show that carbonates and pelites melt at similar conditions in the crust. While partial melting of pelitic rocks is common and well-documented, reports of partial melting in carbonates are rare and ambiguous, mainly because of intensive recrystallization and the resulting lack of criteria for unequivocal identification of melting. Here we present microstructural, textural, and geochemical evidence for partial melting of calcareous dolomite marbles in the contact aureole of the Tertiary Adamello Batholith. Petrographic observations and X-ray micro-computed tomography (X-ray μCT) show that calcite crystallized either in cm- to dm-scale melt pockets, or as an interstitial phase forming an interconnected network between dolomite grains. Calcite-dolomite thermometry yields a temperature of at least 670 °C, which is well above the minimum melting temperature of ∼600 °C reported for the CaO-MgO-CO2-H2O system. Rare-earth element (REE) partition coefficients (KDcc/do) range between 9-35 for adjacent calcite-dolomite pairs. These KD values are 3-10 times higher than equilibrium values between dolomite and calcite reported in the literature. They suggest partitioning of incompatible elements into a melt phase. The δ18O and δ13C isotopic values of calcite and dolomite support this interpretation. Crystallographic orientations measured by electron backscattered diffraction (EBSD) show a clustering of c-axes for dolomite and interstitial calcite normal to the foliation plane, a typical feature for compressional deformation, whereas calcite crystallized in pockets shows a strong clustering of c-axes parallel to the pocket walls, suggesting that it crystallized after deformation had stopped. All this together suggests the formation of partial melts in these carbonates. A Schreinemaker analysis of the experimental data for a CO2-H2O fluid-saturated system indeed predicts formation of calcite-rich melt between 650-880 °C, in

  7. Dynamics of melt and water circulation in the mantle transition zone

    NASA Astrophysics Data System (ADS)

    Bercovici, David

    2010-05-01

    The presence of melt above the mantle transition zone has been predicted by several groups, and its formation has been attributed - according to the 'water filter model" (Bercovici & Karato 2003) - with causing whole mantle convection to appear geochemically layered. In recent years, various seismological studies (e.g., most recently Jasbinsek and Dueker, 2007) have collectively inferred an extensive low velocity region at 410km depth, suggestive of the predicted melt zone. The leading mechanism proposed for generating this melt zone is by dehydration melting, which is supported by modest transition-zone water concentrations inferred by electromagnetic sounding (Huang, Xu, Karato, 2005). In this mechanism, warm upwelling 'damp" transition-zone material (wadsleyite) crosses the 410km boundary, and arrives above the solidus water limit in the upper-mantle (olivine) partial melt stability field. The fate of the subsequently produced melt is important for inferring the structure, observability and stability of this melt region. The most recent models of a wet melt layer spreading along the 410km boundary and reacting with a background mantle flow predict that the layer will be several 10s of kilometers thick, and that the melt's material will be entrained into the lower mantle well before it reaches any slabs (Leahy & Bercovici, 2010). At these pressures the melt is possibly more dense than the solid, although the density cross-over point is not likely to be far above the 410km boundary. However, unless the density cross-over actually intersects the melt zone, the melt is stable to any Rayleigh-Taylor instability (Youngs & Bercovici, 2009). Finally, continued re-hydration of the transition zone is required to supply the melt layer in the presence of background mantle flow. Slabs foundering and flowing horizontally across the transition zone provide one of the best means for transporting water across the transition zone. Slabs at the bottom of the transition zone

  8. Impact of textural anisotropy on syn-kinematic partial melting of natural gneisses: an experimental approach.

    NASA Astrophysics Data System (ADS)

    Ganzhorn, Anne-Céline; Trap, Pierre; Arbaret, Laurent; Champallier, Rémi; Fauconnier, Julien; Labrousse, Loic; Prouteau, Gaëlle

    2015-04-01

    C experiments NOP1 was previously hydrated at room pressure and temperature. According to melt fraction, deformation of partially molten gneiss induced different strain patterns. For low melt fraction, at 750°C, deformation within the initially isotropic gneiss NOP1 is localized along large scales shear-zones oriented at about 60° from main stress component σ1. In these zones quartz grains are broken and micas are sheared. Melt is present as thin film (≥20 µm) at muscovite-quartz grain boundaries and intrudes quartz aggregates as injections parallel to σ1. For higher melt fraction, at 850°C, deformation is homogeneously distributed. In the layered gneiss PX28, deformation is partitioned between mica-rich and quartz-rich layers. For low melt fraction, at 850°C, numerous conjugate shear-bands crosscut mica-rich layers. Melt is present around muscovite grains and intrudes quartz grains in the favor of fractures. For high melt fractions, at 900°C, melt assisted creep within mica-rich layers is responsible for boudinage of the quartz-feldspar rich layers. Melt-induced veining assists the transport of melt toward inter-boudin zones. Finite strain pattern and melt distribution after deformation of PX28 attest for appearance of strong pressure gradients leading to efficient melt flow. The subsequent melt redistribution strongly enhance strain partitioning and strength weakening, as shown by differential stress vs. strain graphs. Our experiments have successfully reproduced microstructures commonly observed in migmatitic gneisses like boudinage of less fertile layers. Comparison between non-layered and layered gneisses attest for strong influence of compositional anisotropies inherited from the protolith upon melt distribution and migmatite strength.

  9. Evidence From a Crystal-Poor, Zoned (Rhyolite-Andesite) Pyroclastic Deposit From Volcan Tepetiltic, Western Mexico for Rapid Generation of Silicic Melt by Partial Melting of Granitoid and not by Segregation From a Long-Lived Crystal-Rich Mush

    NASA Astrophysics Data System (ADS)

    Lange, R. A.; Frey, H.; Hall, C.; Delgado-Granados, H.

    2007-12-01

    %), intermediate (56-66 wt% SiO2), hornblende- free lavas of V. Tepetiltic and the explosive, caldera-forming eruption that produced the crystal-poor (0-3 vol%), zoned (60-75 wt% SiO2), hornblende-bearing pyroclastic deposit. Most models for the formation of high- silica rhyolite, especially when part of an eruption that zones to andesite/dacite, is that it forms by melt segregation from the andesite/dacite crystalline mush. In the case of the erupted products from V. Tepetiltic, however, this oft-cited model is not viable. The crystal-poor andesite cannot be the parent for the rhyolite as too few crystals have formed. Instead, the most plausible scenario is that the magma chamber that fed construction of the main edifice of V. Tepetiltic solidified below its solidus by ~350 ka. Then, at ~214 ± 64 ka, a pulse of basaltic andesite magma was emplaced into the upper crust, which drove partial melting of granitoid beneath V. Tepetiltic, by the transfer of heat and volatiles. The partial melt (ranging from voluminous rhyolite to minor andesite) segregated, ascended, and erupted quickly (at ~190 ka) before extensive degassing- induced crystallization could occur. This model for the formation of rhyolite (by partial melting of granitoid) may be more widespread than currently recognized.

  10. Partial melt and seismic properties: A case study from the Seiland Igneous Province

    NASA Astrophysics Data System (ADS)

    Lee, Amicia; Walker, Andrew; Lloyd, Geoff; Torvela, Taija

    2016-04-01

    The geological evolution of orogenies is partly controlled by partial melting in the middle and/or lower crust. However, seismic methods cannot reliably quantify the amount of melting at depth in tectonically active mountain belts. We have developed a numerical modelling method to assess the impact of melt on seismic properties and applied this to samples from a transect across a migmatitic shear zone in the Seiland Igneous Province, Northern Norway. These rocks represent an analogue to lower crustal shear zones undergoing orogenic collapse. Compressional and shear waves reduce when melt is introduced but the effect on seismic anisotropy is unclear and recent evidence suggests the melt-seismic property relationship is not simple. We have measured crystallographic preferred orientations in sheared migmatites using EBSD and use this data as input for multiple numerical models designed to quantify the variation of seismic properties with melt volume. Three 'end member' models have been developed: a reference 'isotropic model' consisting of a rock matrix comprising randomly oriented grains with distributed spherical melt pockets, the 'shape fabric model' an isotropic matrix with ellipsoidal melt inclusions, and the 'CPO model' consisting of a textured mineralogical matrix with randomly distributed spherical melt pockets. The isotropic and matrix dominated models give end member seismic properties for the isotropic and anisotropic dominated regimes. Importantly, these models do not consider the shape of the melt fractions, and instead the melt is averaged over the whole rock. The shape fabric model calculates the seismic properties of an isotropic inclusion within an isotropic matrix. The results of this modelling show that an oblate ellipsoid has the greatest effect on seismic properties. It is also the most likely shape for melt pockets as it is an analogue shape for extensional melting during orogenic collapse; a large oblate ellipsoid produces a high S

  11. Fault Zone Drainage, Heating and Melting During Earthquake Slip

    NASA Astrophysics Data System (ADS)

    Rempel, A. W.; Rice, J. R.; Jacques, L. M.

    2003-12-01

    The expansion of pore water caused by frictional heating during large crustal events provides a powerful weakening mechanism (Sibson, 1973; Lachenbruch, 1980). It may explain the magnitude of seismically inferred fracture energy and aspects of its variation with increased slip (Abercrombie and Rice, 2003; Rice et al., 2003; Rice, this section, 2003). The weakening is mediated by the effects of fluid transport, which are sensitive to the permeability structure of the fault zone and its modification by damage induced by the passing rupture front (Poliakov et al., 2002), as well as by the increase in pore pressure itself. Higher permeabilities allow partial drainage to occur, so that enough strength remains for the heat generated to cause partial melting of the fault gouge at large enough slip. We use recent field and laboratory data for fluid transport through pressurized fault gouge (e.g. Lockner et al., 2000; Wibberley and Shimamoto, 2003) to motivate models for drainage and melting during earthquake slip. A dramatic illustration of the role of drainage is provided by an idealized model in which we assume that a freshly damaged, highly permeable region extends right up to a localized shear zone of thickness ho=5 mm, with fixed porosity n and much lower permeability k. At 7 km depth, for n=0.02 and k=10-19 m2, the slip distance required to reach the onset of melting at 750oC is approximately 0.4 m for a constant friction coefficient of f=0.6. At 14 km depth, for n=0.01 and k=10-20 m2, the same temperature is reached after only 0.1 m of slip. Yet more efficient drainage might occur due to the permeability increases that accompany reductions in the effective stress, so that even more rapid temperature increases would be predicted. For example, with ten times higher k, melting begins after 0.1 m slip at 7 km depth and just 0.05 m at 14 km. At onset of melting the high melt viscosity impedes further drainage and, with increasing melt fraction, inter-particle contact is

  12. Melt-melt immiscibility as result of synchronous melting of metapelites and impure marbles at crustal depth in the Moldanubian Zone, Bohemian Massif.

    NASA Astrophysics Data System (ADS)

    Ferrero, Silvio; O´Brien, Patrick J.; Ziemann, Martin A.; Wunder, Bernd; Hecht, Lutz; Wälle, Markus

    2016-04-01

    Investigation of melt and fluid inclusions in migmatites grants access to the unadultered products of crustal melting, shedding light on the processes driving crustal differentiation. Stromatic migmatites from the Oberpfalz (Moldanubian Zone, Bohemain Massif) present a unique occurrence of calcite-rich inclusions (CRI), crystallized inclusions of anatectic melt (nanogranites) and CO2-rich inclusions, all hosted in peritectic garnet. Their distribution as clusters in the host suggests a primary nature, i.e. that they formed during garnet growth, thus testifying for the coexistence of different melts and fluid during partial melting in the middle-lower crust. CRI are generally small (≤10 μm in diameter) and, from a microstructural point of view, strikingly resemble the coexistent nanogranites, i.e. they show a well-developed negative crystal shape and have a cryptocrystalline nature. Their phase assemblage, identified via Raman spectroscopy and EDS mapping, consists of calcite, white mica and chlorite, with quartz as accessory mineral. Moreover, calcite crystals locally develop euhedral faces, further supporting the hypothesis that this phase crystallized from an originally homogeneous calcite-rich melt. Piston-cylinder re-homogenization experiments achieved nanogranites re-melting at pressure-temperature conditions consistent with geothermobarometric estimates, 800-850°C and 0.7-0.9 GPa. After having been re-heated at these conditions, the coexistent calcite-rich inclusions appear modified, with formation of internal porosity and re-crystallization of calcite in microcrystalline aggregates, suggesting that during the experimental run calcite melting was achieved. LA-ICPMS analyses show that CRIs are generally highly enriched in LILE (particularly Sr, Ba) and LREE (up to LaN ≈500, with moderate to low fractionation among LREE, La/Sm=1-9) with respect both to the host garnet and the coexistent nanogranites. The higher abundance of LREE in CRIs is consistent with

  13. Magnetotelluric imaging of upper crustal partial melt at Tendaho graben in Afar, Ethiopia

    NASA Astrophysics Data System (ADS)

    Didana, Yohannes Lemma; Thiel, Stephan; Heinson, Graham

    2014-05-01

    We report on a recent magnetotelluric (MT) survey across the Manda Hararo magmatic segment (MHMS) within the Tendaho graben in the Afar Depression in northeastern Ethiopia. Twenty-two broadband MT sites with ˜1 km station spacing were deployed along a profile with the recorded data covering a period range from 0.003 s to 1000 s. A two-dimensional (2-D) resistivity model reveals an upper crustal fracture zone (fault) and partial melt with resistivity of 1-10Ωm at a depth of >1 km. The partial melt has a maximum horizontal width of 15 km and extends to a depth of 15 km within the Afar Stratoid Series basalts. We estimate a melt fraction of about 13% based on geochemical and borehole data, and bulk resistivity from the 2-D MT inversion model. The interpreted upper crustal partial melt may have been formed by either a magma intrusion from mantle sources or a large volume of continental crust that has been fluxed by a small amount of mantle melt and heat. Within the MHMS and Tendaho graben, a magma intrusion is a plausible explanation for the upper crustal conductor. The inferred presence of a conductive fracture zone or fault with hydrothermal fluid and shallow heat sourcing magma reservoir also makes the Tendaho graben a promising prospect for the development of conventional hydrothermal geothermal energy.

  14. Partial melting of amphibolite to trondhjemite near Ykutat, Alaska

    NASA Technical Reports Server (NTRS)

    Barker, F.

    1986-01-01

    At Nunatak Fiord, 55 km NE of Yakutat, Alaska, a uniform layer of Cretaceous metabasalt approximately 3 km thick was metamorphosed to amphibolite facies and locally partially melted to trondhjemite pegmatite. Results of the rare earth element analysis performed on the amphibolite and the trondhjemite pegmatite are discussed.

  15. Partial Melting of Massive Sulfide Ore Bodies During Metamorphism

    NASA Astrophysics Data System (ADS)

    Frost, B. R.

    2004-05-01

    Sulfide systems with the major metals Cu, Ni, Fe, Pb, and Zn show only limited field for melt at temperatures typical of most regional metamorphism (T<700oC). However, the presence of minor metals such as As, Hg, Sb, Tl, Se, and Te may flux melting down to much lower T. For example at one bar the eutectic between realgar and orpiment lies at 281oC. This means that numerous sulfosalt assemblages may melt at conditions well within those of regional metamorphism. Most massive sulfide ore bodies metamorphosed at greenschist or lower amphibolite facies contain rather simple assemblages of pyrite, pyrrhotite, chalcopyrite, sphalerite ± galena. In contrast, sulfide ore deposits metamorphosed at higher grades contain the same minerals along with a complex assortment of minor phases, including sulfosalts, native metals, and alloys, many of which are enriched in Au and Ag. We contend that these complex assemblages, which are enriched in low-melting metals, were formed during crystallization of a polymetallic melt. For the assemblages commonly found in massive sulfide deposits the most likely melt-forming reaction is arsenopyrite + pyrite = pyrrhotite + melt. At 1 bar this reaction takes place at 491oC; melting temperature increases by 17oC/kilobar. In our model the melt is initially rich in As and S (and perhaps Hg, Sb, Tl, Se, and Te). Au and Ag will also be fractionated into the melt. With increasing temperature the polymetallic melt will accommodate increasing amounts of Pb, Cu, and then Fe and Zn. The ore bodies from highest metamorphic terranes are commonly associated with rims of Mn- and Ca-pyroxenoids, suggesting that at the highest grades of metamorphism polymetallic melts may accommodate considerable amounts of these normally lithophile elements. We have identified more than 25 ore deposits from around the world where the ore partially melted during metamorphism. These include Cu-Fe-Zn deposits (mostly VMS), Pb-Zn deposits (both MVT and SEDEX), and disseminated Au

  16. Melt segregation from partially molten source regions - The importance of melt density and source region size

    NASA Technical Reports Server (NTRS)

    Stolper, E.; Hager, B. H.; Walker, D.; Hays, J. F.

    1981-01-01

    An investigation is conducted regarding the changes expected in the density contrast between basic melts and peridotites with increasing pressure using the limited data available on the compressibilities of silicate melts and data on the densities of mantle minerals. It is concluded that since compressibilities of silicate melts are about an order of magnitude greater than those of mantle minerals, the density contrast between basic melts and mantle minerals must diminish significantly with increasing pressure. An earlier analysis regarding the migration of liquid in partially molten source regions conducted by Walker et al. (1978) is extended, giving particular attention to the influence of the diminished density contrast between melt and residual crystals with increasing source region depth and to the influence of source region size. This analysis leads to several generalizations concerning the factors influencing the depths at which magmas will segregate from their source regions and the degrees of partial melting that can be achieved in these source regions before melt segregation occurs.

  17. Extensive partial melting and melt extraction in pelitic metasediments: An example from the Chiwaukum schist (Washington Cascades)

    NASA Astrophysics Data System (ADS)

    Austin, N.; Kelemen, P.

    2006-12-01

    Partial melting of crustal sediments plays an important role in both the production of anatectic granites (eg. Brown, 1994; Harris et al., 1995; Johnson et al., 2003), and modification of mantle derived melts via assimiation (eg. McBirney et al., 1987; Grove et al., 1982). These processes rely heavily on segregation of anatectic melts from their sedimentary source (Brown, 1994; Sawyer, 1994; Brown et al., 1995). Here, we investigate the extent of melting and melt extraction in the pelitic Chiwaukum schist (central Washington St.), within the contact aureole of the Big Jim intrusive complex. The Big Jim complex, part of the regionally extensive Mt. Stuart Batholith, intruded the pelitic Chiwaukum schist at ~96 Ma (Tabor et al., 1982, 1987; Matzel, 2004). It is concentrically zoned, with an ultramafic core and intermediate to felsic rim (Kelemen & Ghiorso, 1986). Peak metamorphic grades in the schist reach pyroxene hornfels, and textures indicative of partial melting of the schist are apparent; the pelitic schists, and their migmatized counterparts form a continuum from un-migmatized metasediments to structureless, biotite free hornfels, containing leucosome lenses. With increasing grade, there is a continuous decrease in Th and light REE's, elements that are mobile in melts and are largely immobile in hydrothermal fluids; REE and trace element patterns show no evidence of contamination of the partially molten schist by the intruding pluton. There is a sharp decrease in K2O in the schist with increasing grade, which correlates with the breakdown of biotite, while there is a sharp concomitant increase in CaO content. By assuming that CaO is immobile, minimum melt losses are estimated to be between 0 and 80%. Samples that have experienced greater melt loss are characterized by a decrease in Th, K#, and alumina saturation index, while they show increased Ca# and Mg#. This probably results from removal of a peraluminuos, K rich melt, with Na2O>>CaO and Fe

  18. Thermocapillary convection in zone-melting crystal growth - An open-boat physical simulation

    NASA Technical Reports Server (NTRS)

    Kim, Y. J.; Kou, Sindo

    1989-01-01

    Thermocapillary convection in a molten zone of NaNO3 contained in a boat with a free horizontal surface, that is heated from above by a centered wire heater, was studied to simulate flow in zone-melting crystal growth. Using a laser-light-cut technique and fine SiO powder as a tracer, convection in the melt zone was visualized in two different cases. In the first case, the entire melt surface was free, while in the second the melt surface was free only in the immediate vicinity of one vertical wall and was covered elsewhere, this wall being to simulate the melt/crystal interface during crystal growth. It was observed that thermocapillary convection near this wall prevailed in the first case, but was reduced significantly in the second. Since thermocapillary rather than natural convection dominated in the melt, the effect of the partial covering of the melt surface on thermocapillary convection in the melt observed in this study is expected to be similar under microgravity.

  19. Growth of early continental crust controlled by melting of amphibolite in subduction zones.

    PubMed

    Foley, Stephen; Tiepolo, Massimo; Vannucci, Riccardo

    2002-06-20

    It is thought that the first continental crust formed by melting of either eclogite or amphibolite, either at subduction zones or on the underside of thick oceanic crust. However, the observed compositions of early crustal rocks and experimental studies have been unable to distinguish between these possibilities. Here we show a clear contrast in trace-element ratios of melts derived from amphibolites and those from eclogites. Partial melting of low-magnesium amphibolite can explain the low niobium/tantalum and high zirconium/samarium ratios in melts, as required for the early continental crust, whereas the melting of eclogite cannot. This indicates that the earliest continental crust formed by melting of amphibolites in subduction-zone environments and not by the melting of eclogite or magnesium-rich amphibolites in the lower part of thick oceanic crust. Moreover, the low niobium/tantalum ratio seen in subduction-zone igneous rocks of all ages is evidence that the melting of rutile-eclogite has never been a volumetrically important process.

  20. Age and geochemical constraints for partial melting of granulites in Estonia

    NASA Astrophysics Data System (ADS)

    Soesoo, A.; Košler, J.; Kuldkepp, R.

    2006-03-01

    The rocks of the crystalline basement of the East European Craton in southern Estonia show effects of partial melting under granulite facies conditions. Zircons extracted from partial melting products (tonalite from the Tapa Zone 1824 ± 26, tonalite from the South Estonian Zone 1788 ± 16 Ma and charnockite from the Tapa Zone 1761 ± 11 Ma) yield U Pb crystallisation ages that span over approximately 80 Ma, suggesting a prolonged high-grade metamorphism or several separate events. U Pb zircon age of one sample of charnockite is concordant with the Nd model age of partial melting of its host mafic granulite facies gneiss (intercept at 1.76 Ga). Linear geochemical trends and similar initial Nd isotopic compositions of mafic granulites and charnockites suggest their possible genetic relationship. From our new and previously published data it follows that the peak granulite metamorphic conditions and formation of tonalites and charnockites (850 °C and 6 kbar) in the Estonian basement occurred at 1788 1778 Ma. Then, the rocks cooled down, passing through the garnet closure temperature of approximately 650 700 °C at 1728 ± 24 Ma. The age of metamorphism of the Estonian granulites is lower than the metamorphic ages known from southern Finland, but it is similar to the age of metamorphism reported from the Belarus-Baltic Granulite Belt in Latvia.

  1. Evidence for Partial Melting in Reflectance Spectra of 433 Eros

    NASA Technical Reports Server (NTRS)

    McFadden, L. A.; Goldman, Noah; Gaffey, M. J.; Izenberg, N. R.

    2005-01-01

    The NEAR Shoemaker spacecraft returned near-IR spectra of asteroid 433 Eros at spatial resolutions ranging from 2.5 to 100's km during its year-long orbital mission in 2000. Assuming modified Gaussian absorption bands represent the reflectance spectrum between 0.8-2.5 m we fit the average of all geometrically corrected spectra acquired by the near-IR spectrometer (NIS) with seven absorption bands. Interpretation of the absorption bands in terms of olivine and pyroxene minerals indicates that the surface of Eros contains olivine and two pyroxenes with compositions that are indicative of a partially melted assemblage. This partial melting must have occurred when the asteroid was part of a larger minor planet, prior to break up into its current elongated and irregular shape.

  2. Can slabs melt beneath forearcs in hot subduction zones?

    NASA Astrophysics Data System (ADS)

    Ribeiro, J.; Maury, R.; Gregoire, M.

    2015-12-01

    At subduction zones, thermal modeling predict that the shallow part of the downgoing oceanic crust (< 80 - 100 km depth to the slab) is usually too cold to cross the water-rich solidus and melts beneath the forearc. Yet, the occasional occurrence of adakites, commonly considered as slab melts, in the forearc region challenges our understanding of the shallow subduction processes. Adakites are unusual felsic rocks commonly associated with asthenospheric slab window opening or fast subduction of young (< 25 Ma) oceanic plate that enable slab melting at shallow depths; but their genesis has remained controversial. Here, we present a new approach that provides new constraints on adakite petrogenesis in hot subduction zones (the Philippines) and above an asthenospheric window (Baja California, Mexico). We use amphibole compositions to estimate the magma storage depths and the composition of the parental melts to test the hypothesis that adakites are pristine slab melts. We find that adakites from Baja California and Philippines formed by two distinct petrogenetic scenarios. In Baja California, hydrous mantle melts mixed/mingled with high-pressure (HP) adakite-type, slab melts within a lower crustal (~30 km depth) magma storage region before stalling into the upper arc crust (~7-15 km depth). In contrast, in the Philippines, primitive mantle melts stalled and crystallized within lower and upper crustal magma storage regions to produce silica-rich melts with an adakitic signature. Thereby, slab melting is not required to produce an adakitic geochemical fingerprint in hot subduction zones. However, our results also suggest that the downgoing crust potentially melted beneath Baja California.

  3. Growth of early continental crust by partial melting of eclogite.

    PubMed

    Rapp, Robert P; Shimizu, Nobumichi; Norman, Marc D

    2003-10-01

    The tectonic setting in which the first continental crust formed, and the extent to which modern processes of arc magmatism at convergent plate margins were operative on the early Earth, are matters of debate. Geochemical studies have shown that felsic rocks in both Archaean high-grade metamorphic ('grey gneiss') and low-grade granite-greenstone terranes are comprised dominantly of sodium-rich granitoids of the tonalite-trondhjemite-granodiorite (TTG) suite of rocks. Here we present direct experimental evidence showing that partial melting of hydrous basalt in the eclogite facies produces granitoid liquids with major- and trace-element compositions equivalent to Archaean TTG, including the low Nb/Ta and high Zr/Sm ratios of 'average' Archaean TTG, but from a source with initially subchondritic Nb/Ta. In modern environments, basalts with low Nb/Ta form by partial melting of subduction-modified depleted mantle, notably in intraoceanic arc settings in the forearc and back-arc regimes. These observations suggest that TTG magmatism may have taken place beneath granite-greenstone complexes developing along Archaean intraoceanic island arcs by imbricate thrust-stacking and tectonic accretion of a diversity of subduction-related terranes. Partial melting accompanying dehydration of these generally basaltic source materials at the base of thickened, 'arc-like' crust would produce compositionally appropriate TTG granitoids in equilibrium with eclogite residues.

  4. Highly refractory peridotites in Songshugou, Qinling orogen: Insights into partial melting and melt/fluid-rock reactions in forearc mantle

    NASA Astrophysics Data System (ADS)

    Cao, Yi; Song, Shuguang; Su, Li; Jung, Haemyeong; Niu, Yaoling

    2016-05-01

    The Songshugou ultramafic massif is located in the eastern segment of the Qinling orogenic belt, central China. It is a large spinel peridotite body dominated by coarse-grained, porphyroclastic, and fine-grained dunite with minor harzburgite, olivine clinopyroxenite, and banded/podiform chromitite. The compositions of the bulk-rock dunite and harzburgite, and the constituent olivine and spinel, together with the textures and chemical characteristics of multiphase mineral inclusions, point to the highly refractory nature of these rocks with complex histories of high-temperature boninite melt generation and boninitic melt-rock reaction, probably in a young, warm, and volatile-rich forearc lithospheric mantle setting. Additionally, a subsequent low-temperature fluid-rock reaction is also recorded by TiO2-rich spinel with Ti solubility/mobility enhanced by chloride- or fluoride-rich subduction-zone fluids as advocated by Rapp et al. (2010). The olivine clinopyroxenite, on the other hand, was likely crystallized from a residual boninitic melt that had reacted with harzburgitic residues. The ubiquitous occurrences of hydrous minerals, such as anthophyllite, tremolite, Cr-chlorite, and serpentine (stable at lower P-T crustal conditions) in the matrix, suggest that further low-temperature fluid-rock reaction (or retrograde metamorphism) has affected the original volatile-poor peridotites either in a mature and cool subduction zone, or in a continental crust during their exhumation into the Qinling collisional orogeny at early Paleozoic era, or both. The prolonged and intense ductile/brittle deformation can decrease the mineral grain size through dynamic recrystallization and fracturing, and thus aid the fluid-rock reaction or retrograde metamorphism and mineral chemical re-equilibration processes. Therefore, the Songshugou peridotites present a good example for understanding the petrogenesis and evolution of the mantle wedge, with the emphasis on the complex partial

  5. Physics of deep plume melting: komatiitic melt accumulation and segregation in the transition zone

    NASA Astrophysics Data System (ADS)

    Schmeling, Harro; Arndt, Nick; Kohl, Svenja

    2014-05-01

    Komatiites are assumed to be produced in very hot mantle upwellings or plumes. Under such conditions, melting will take place deep within the upper mantle or even within or below the mantle transition zone. Due to its compressibility at such pressures, melt has a higher density than olivine. Whether it would remain buoyant with respect to a peridotitic mantle both above and below the olivine-wadsleyite phase boundary because of the presence of denser garnet remains an open issue, particularly in view of recent X-ray refraction data on molten basalts by Sanloup et al. (2013). We studied the physics of melting and melt segregation within hot upwelling mantle passing through the transition zone, with particular emphasis on the effect of depth-dependent density contrasts between melt and the ambient mantle. Assuming a 1D plume, we solved the two-phase flow equations of the melt-matrix system accounting for matrix compaction and porosity-dependent shear and bulk viscosity. We assumed a constant ascent velocity leading to a constant rate of melt generation. In a first model series, the level of neutral buoyancy zneutral is assumed to lie above the depth of onset of melting, i.e. there exists a region where dense melt may lag behind the solid phases within the rising plume. Depending on two non-dimensional numbers (accumulation number Ac, compaction resistance number Cr) we find four regimes: 1) time-dependent melt accumulation in standing and broadening porosity waves that scale with the compaction length, 2) steady-state weak melt accumulation near zneutral, 3) no melt accumulation due to small density contrast, 4) no melt accumulation due to high matrix viscosity. In regime 4 the high mantle viscosity prevents the opening of pore space and the accumulation of melt. In a second series, the rising mantle crosses the olivine-wadsleyite phase boundary, which imposes a jump in density contrast between melt and ambient mantle. In this case, a sharp melt fraction contrast

  6. Volatile-rich partial melts at the oceanic lithosphere-asthenosphere boundary

    NASA Astrophysics Data System (ADS)

    Hirschmann, M. M.; Ardia, P.

    2011-12-01

    New seismic observations reinforce interpretations that the seismic low velocity zone beneath oceans, and particularly directly below the lithosphere-asthenosphere boundary, contain small amounts of melt. Experimental and theoretical studies agree that volatile-rich partial melt can be stable in the LVZ, but disagree sharply as to the volatile component- H2O vs. CO2 - chiefly responsible. Hirschmann et al. (2009) argued that hydrous partial melting does not occur in the LVZ for mantle with typical suboceanic H2O concentrations, but Green et al. (2010) argued on the basis of experiments with hydrous peridotite that the mantle in the LVZ with modest (>180 ppm) H2O can be in equilibrium with H2O-saturated partial melts having ~30 wt.% H2O. These observations conflict with experimentally-determined partition coefficients which suggest that near-solidus partial melts of nominally anhydrous peridotite with 200 ppm H2O can have no more than 5 wt% H2O, too little to stabilize hydrous melt along the mantle geotherm. New H2O storage capacity experiments determined for olivine equilibrated with peridotite and hydrous melt at 1400-1500 °C and 5-8 GPa confirm the validity of the Hirschmann et al. (2009) predictions. Consequently, we argue that H2O is not sufficient to stabilize partial melt in the LVZ. However, CO2 and/or CO2 in combination with H2O unavoidably stabilizes small amounts of carbonatite or hydrous carbonated melt at LVZ conditions. The strongest observational evidence for melting in the LVZ is at its shallowest portions, where the so-called G discontinuity indicates a sharp boundary between the LVZ and the overlying lithospheric lid. Recent studies by Kumar and Kawakatsu (2011) and Rychert and Shearer (2011) indicate that the boundary becomes deeper with plate age, consistent with the hypothesis that the boundary represents a volatile-present solidus and inconsistent with chemical boundary layer hypotheses. The seismic observations suggest that the boundary

  7. Partial melting of metagreywackes, Part II. Compositions of minerals and melts

    NASA Astrophysics Data System (ADS)

    Montel, Jean-Marc; Vielzeuf, Daniel

    C at 800MPa. The position of the isotects is interpreted in terms of both the solubility of water in the melt and the nature of the reactions involved in the melting process. A comparison with other partial melting experiments suggests that pelites are the most fertile source rocks above 800MPa. The difference in fertility between pelites and greywackes decreases with decreasing pressure. A review of the glass compositions obtained in experimental studies demonstrates that partial melting of fertile rock types in the crust (greywackes, pelites, or orthogneisses) produces only peraluminous leucogranites. More mafic granitic compositions such as the various types of calk-alkaline rocks, or mafic S-type rocks, have never been obtained during partial melting experiments. Thus, only peraluminous leucogranites may correspond to liquids directly formed by partial melting of metasediments. Other types of granites involve other components or processes, such as restite unmixing from the source region, and/or interaction with mafic mantle-derived materials.

  8. Ascent Dynamics of Low Degree Mantle Partial Melts, Constrained from CO2 Solubility Experiments.

    NASA Astrophysics Data System (ADS)

    Moussallam, Y.; Morizet, Y.; Massuyeau, M.; Gaillard, F.

    2014-12-01

    Low degree partial melting of carbonated mantle peridotite generates strongly silica-undersaturated melts containing substantial amount of carbon dioxide (several tens of wt%). Kimberlite melts are one of these volatile-rich mantle product and are believed to ascent through the upper mantle and crust at great speed (~5 to 50 ms-1). The role of volatiles in propelling this ascent has remained poorly quantified due to experimental difficulties in quenching such compositions to a glass. In this study, we used a range of melt compositions in the Si-C-Al-Ca-Mg-Fe-Na-K-O system addressing the chemical complexity needed to closely mimic kimberlitic to carbonatitic characteristics. These melts can, furthermore, be quenched fast enough to produce a glass and be used to determine the CO2 solubility as a function of composition and pressure. Our results suggest that the solubility of CO2 decreases steadily with increasing amount of network forming cations from ~30 wt% CO2 at 12 wt% SiO2 down to ~3 wt% CO2 at 40 wt% SiO2 and that pressure has limited effect on the solubility of CO2 up until very shallow depth (~ last 3 km). This peculiar pressure-solubility relation in kimberlite melt can explain the highly explosive nature of kimberlite magma and characteristic geo-morphological features of their root zone. We present a general CO2 solubility model based on thermodynamic formalism covering a large range of melt composition from 11 to 53 wt% SiO2 spanning the transition from carbonatitic to basaltic melts at pressures up to 1500 MPa.

  9. Consequences and Resolution of Lunar Lower Mantle Partial Melt

    NASA Astrophysics Data System (ADS)

    Fuqua, H.; Bremner, P. M.; Diamond, M. R.; Garapic, G.; Lock, S. J.; Mallik, A.; Nishikawa, Y.; Panovska, S.; Shahar, A.; Lognonne, P. H.; Panero, W. R.; Faul, U.; Panning, M. P.; Jimenez-Perez, H.; Schmerr, N. C.; Williams, Q. C.

    2014-12-01

    Existence of a partially molten layer at depth has been proposed to explain the lack of observed farside deep moonquakes, the observation of reflected phases from deep moonquakes, and the dissipation of tidal energy within the lunar interior. However, subsequent models explore the possibility that dissipation due to elevated temperatures alone can explain the observed dissipation factor (Q) and tidal love numbers. We have explored the hypothesis that high titanium melt compositions associated with lunar mantle overturn may sink to the base of the mantle, locally or regionally. We have performed forward calculations varying composition and thickness of layers to evaluate if a partially molten layer at the base of the mantle is well constrained by the observational data. Self-consistent physical parameters are calculated for each compositional model that are then compared against the observed data to determine a subset of permissible models. The data constraints considered by this study include bulk density, moment of inertia, real and imaginary parts of the Love numbers, seismic travel times, and electrical conductivity. Dynamic calculations using ASPECT have also been considered to determine the implications of early lunar mantle convection for the survivability of the partially molten layer. Finally, and as a perspective for a future NASA New Frontiers Geophysical Network, we present 1D synthetic seismograms calculated for each proposed structure of the Moon to investigate the future seismological resolution of these deep lunar structure features. This work was initiated at the CIDER 2014 program.

  10. Metamorphism and partial melting of ordinary chondrites: Calculated phase equilibria

    NASA Astrophysics Data System (ADS)

    Johnson, T. E.; Benedix, G. K.; Bland, P. A.

    2016-01-01

    Constraining the metamorphic pressures (P) and temperatures (T) recorded by meteorites is key to understanding the size and thermal history of their asteroid parent bodies. New thermodynamic models calibrated to very low P for minerals and melt in terrestrial mantle peridotite permit quantitative investigation of high-T metamorphism in ordinary chondrites using phase equilibria modelling. Isochemical P-T phase diagrams based on the average composition of H, L and LL chondrite falls and contoured for the composition and abundance of olivine, ortho- and clinopyroxene, plagioclase and chromite provide a good match with values measured in so-called equilibrated (petrologic type 4-6) samples. Some compositional variables, in particular Al in orthopyroxene and Na in clinopyroxene, exhibit a strong pressure dependence when considered over a range of several kilobars, providing a means of recognising meteorites derived from the cores of asteroids with radii of several hundred kilometres, if such bodies existed at that time. At the low pressures (<1 kbar) that typify thermal metamorphism, several compositional variables are good thermometers. Although those based on Fe-Mg exchange are likely to have been reset during slow cooling, those based on coupled substitution, in particular Ca and Al in orthopyroxene and Na in clinopyroxene, are less susceptible to retrograde diffusion and are potentially more faithful recorders of peak conditions. The intersection of isopleths of these variables may allow pressures to be quantified, even at low P, permitting constraints on the minimum size of parent asteroid bodies. The phase diagrams predict the onset of partial melting at 1050-1100 °C by incongruent reactions consuming plagioclase, clinopyroxene and orthopyroxene, whose compositions change abruptly as melting proceeds. These predictions match natural observations well and support the view that type 7 chondrites represent a suprasolidus continuation of the established petrologic

  11. Stannern-Trend Eucrite Petrogenesis: An Assessment of Partial Melt Contamination Models via Experimental Petrology

    NASA Astrophysics Data System (ADS)

    Crossley, S. D.; Mayne, R. G.; Lunning, N. G.; McCoy, T. J.; Greenwood, R. C.; Franchi, I. A.

    2016-08-01

    Melting experiments were performed on the eucrite, NWA 8562, in order to test the partial melt assimilation model of Stannern-trend petrogenesis. Major and trace element data will be applied to the model, and preliminary results appear to fit.

  12. Imaging the ascent path of fluids and partial melts at convergent plate boundaries by geophysical characteristics

    NASA Astrophysics Data System (ADS)

    Luehr, B. G.; Koulakov, I.; Kopp, H.; Rabbel, W.; Zschau, J.

    2011-12-01

    During the last decades many investigations were carried out at active continental margins to understand the link between the subduction of the fluid saturated oceanic plate and the process of ascent of fluids and partial melts forming a magmatic system that leads to volcanism at the earth surface. For this purpose structural information are needed about the slap itself, the part above it, the ascent paths as well as the storage of fluids and partial melts in the mantle and the crust above the down going slap up to the volcanoes on the surface. If we consider statistically the distance between the trench and the volcanic chain as well as the inclination angle of the down going plate, then the mean value of the depth distance down to the Wadati Benioff zone results of approximately 100 kilometers. Surprisingly, this depth range shows pronounced seismicity at most of all subduction zones. Additionally, mineralogical investigations in the lab have shown that the diving plate is maximal dehydrated around 100 km depth because of temperature and pressure conditions at this depth range. However, assuming a vertical fluid ascent there are exceptions. For instance at the Sunda Arc beneath Central Java the vertical distance results in approximately 150 km. But, in this case seismic investigations have shown that the fluids do not ascend vertically, but inclined even from a source area at around the 100 km depth. The ascent of the fluids and the appearance of partial melts as well as the distribution of these materials in the crust can be proved by seismic and seismological methods. With the seismic tomography these areas are imaged by lowered seismic velocities, high Vp/Vs ratios, as well as increased attenuation of seismic shear waves. But, to explore plate boundaries large and complex amphibious experiments are required, in which active and passive seismic investigations should be combined. They have to recover a range from before the trench to far behind the volcanic

  13. Lithium and magnesium isotopes fractionation by zone melting

    NASA Astrophysics Data System (ADS)

    Akimov, D. V.; Egorov, N. B.; Dyachenko, A. N.; Pustovalova, M. P.; Podoinikov, I. R.

    2016-06-01

    The process of changing isotopic composition of the lithium and magnesium salts was studied by using the process of zone melting. It was founded in the paper that the process of separation of the lithium isotopes is more effective than for magnesium isotopes when the conditions of process were the same. The coefficients of isotopes separation were calculated and have the next value: α = 1.006 for 26Mg isotope and α = 1.0022 for 6Li isotope.

  14. Tape casting and partial melting of Bi-2212 thick films

    NASA Technical Reports Server (NTRS)

    Buhl, D.; Lang, TH.; Heeb, B.; Gauckler, L. J.

    1995-01-01

    To produce Bi-2212 thick films with high critical current densities tape casting and partial melting is a promising fabrication method. Bi-2212 powder and organic additives were mixed into a slurry and tape casted onto glass by the doctor blade tape casting process. The films were cut from the green tape and partially molten on Ag foils during heat treatment. We obtained almost single-phase and well-textured films over the whole thickness of 20 microns. The orientation of the (a,b)-plane of the grains was parallel to the substrate with a misalignment of less than 6 deg. At 77 K/0T a critical current density of 15, 000 A/sq cm was reached in films of the dimension 1 cm x 2 cm x 20 microns (1 micron V/cm criterion, resistively measured). At 4 K/0T the highest value was 350,000 A/sq cm (1 nV/cm criterion, magnetically measured).

  15. Tape casting and partial melting of Bi-2212 thick films

    SciTech Connect

    Buhl, D.; Lang, T.; Heeb, B.

    1994-12-31

    To produce Bi-2212 thick films with high critical current densities tape casting and partial melting is a promising fabrication method. Bi-2212 powder and organic additives were mixed into a slurry and tape casted onto glass by the doctor blade tape casting process. The films were cut from the green tape and partially molten on Ag foils during heat treatment. We obtained almost single-phase and well-textured films over the whole thickness of 20 {mu}m. The orientation of the (a,b)-plane of the grains were parallel to the substrate with a misalignment of less than 6{degrees}. At 77K/OT a critical current density of 15`000 A/cm{sup 2} was reached in films of the dimension 1cm x 2cm x 20{mu}m (1{mu}V/cm criterion, resistively measured). At 4K/OT the highest value was 350`000 A/cm{sup 2} (1nV/cm criterion, magnetically measured).

  16. Microstructure and magnetization of Y-Ba-Cu-O prepared by melt quenching, partial melting and doping

    NASA Technical Reports Server (NTRS)

    Hojaji, Hamid; Hu, Shouxiang; Michael, Karen A.; Barkatt, Aaron; Thorpe, Arthur N.; Alterescu, Sidney

    1991-01-01

    Y-Ba-Cu-O samples prepared by means of a variety of melt-based techniques exhibit high values for their magnetic properties compared with those of samples prepared by solid state sintering. These techniques include single-stage partial melting as well as melt quenching followed by a second heat treatment stage, and they have been applied to the stoichiometric 123 composition as well as to formulations containing excess yttrium or other dopants. The structure of these melt-based samples is highly aligned, and the magnetization readings exhibit large anisotropy. At 77 K and magnetic field intensities of about 2 kOe, diamagnetic susceptibilities as high as -14 x 10(exp -3) emu/g were obtained in the cases of melt-quenched samples and remanent magnetization values as high as 10 emu/g for samples prepared by partial melting.

  17. Melt Inclusions as Windows on Subduction Zone Processes - A Retrospective

    NASA Astrophysics Data System (ADS)

    Sisson, T. W.

    2002-12-01

    A.T. (Fred) Anderson, in a series of papers in the interval 1972-1984, presented evidence from melt inclusions for high dissolved water and Cl concentrations in many subduction zone basalts through andesites. His observations, subsequently shown to be correct, were not widely accepted because (1) phase equilibrium experiments on Paricutin and Mount Hood andesites indicated moderate water concentrations, and some workers reasoned that potentially parental basalts would have been drier still, (2) common basalts lack hydrous phenocrysts, and (3) water content estimates were indirect (water-by-difference) or involved difficult, unfamiliar measurements (single inclusion manometry) and thus were discounted. Subsequent development of techniques for the direct and precise measurement of water and CO2 in melt inclusions (SIMS, FTIR), new hydrous phase-equilibrium studies on arc basalts through rhyolites, and wider appreciation of the diversity of arc magmatic suites changed this situation. Melt inclusion evidence shows that subduction zone basalts can have pre-eruptive dissolved water concentrations as high as ~6 wt% (Sisson and Layne 1993 EPSL; Roggensack et al. 1997 Science), confirming predictions from phase-equilibrium experiments (Sisson and Grove 1993a,b CMP), and supporting the now standard model of water-fluxed melting to drive arc magmatism. An important discovery, presaged in the original Anderson data, is that there is a wide range of pre-eruptive water contents in arc basalts, with some as dry as MORB (Sisson and Bronto 1998 Nature). Nearly dry arc basalts can erupt at the volcanic front (Galunggung, Java) and sporadically along the arc axis over distances of hundreds of km (Cascades, USA), in some cases in proximity to demonstrably water-rich magmatic centers (Mt. Shasta, Crater Lake). To produce dry primitive basalts requires upwelling and pressure-release melting of peridotite in the mantle wedge at temperatures (~1300° C) well above those predicted by

  18. The effect of H2O on partial melting of garnet peridotite at 3.5 GPa

    NASA Astrophysics Data System (ADS)

    Tenner, Travis J.; Hirschmann, Marc M.; Humayun, Munir

    2012-03-01

    We present experimental determinations of the influence of H2O on partial melting of garnet peridotite (+1.5, 2.5, and 5 wt. % added H2O) at 3.5 GPa and 1200-1450°C. Experiments produced complex polyphase regions of quenched melt and equilibrium partial melt compositions were reconstructed by combined EMP and LA-ICP-MS analyses. Mass balance-derived melt fractions (F) range from 0.18 to 0.33 and dissolved water contents range from 4.5 to 23.5 wt. %. One exceptional experiment quenched glass, allowing independent verification of H2O concentration by FTIR. The influence of H2O on melt production is quantified by the temperature difference required to achieve a given F under dry and wet conditions, ΔT, which is controlled by the H2O concentration in partial melts. Melts with 1.5, 5, 10, and 15 wt. % H2O yield ΔT values of 50, 150, 250, and 320°C, respectively, consistent with a cryoscopic parameterization that assumes 3 oxygens per mole of silicate melt. Based on this parameterization, we calculate that beneath oceanic ridges, peridotite H2O storage capacity increases from 0 to 240 ppm from 66 to 110 km depth. For H2O to be solely responsible for melting in the oceanic low velocity zone (LVZ) at least 5.7 wt. % H2O must be dissolved in the melt at 110 km, and considerably more (e.g., 15 wt.% at 220 km) is required for melting throughout the entire observed interval. The addition of H2O results in 3.5 GPa partial melts of garnet peridotite (normalized anhydrous) that are SiO2 and Al2O3 poor (43-50 and 9-11.5 wt. %, respectively), and MgO and CaO rich (18-27 and 7-12 wt. %, respectively) when compared to anhydrous analogues. These effects become highly pronounced deep in the upper mantle, and are opposite to the effect of H2O on melt compositions in the spinel stability field, potentially owing in part to OH-association with network modifying cations in high pressure, depolymerized melts and in part to low-temperature stabilization of garnet, which enhances CaO/Al2O

  19. Lithologic melt partitioning and transport properties of partially molten harzburgite

    NASA Astrophysics Data System (ADS)

    Miller, K. J.; Zhu, W.; Montesi, L.; Gaetani, G. A.; Le Roux, V.; Xiao, X.

    2015-12-01

    Quantitative constraints on melt transport in upper mantle are critical to understanding various dynamic processes at ocean ridges. In this study, we propose that thermodynamic gradients, resulting from spatial variations in mineralogy, can unevenly partition melt between olivine and orthopyroxene (opx), the two most abundant minerals in the upper mantle. The lithologic melt partitioning leads to higher melt fraction in olivine-rich regions compared to opx-rich regions, which may have important implications for melt transport. Lithologic partitioning has been experimentally confirmed in analogue systems, such as quartz/fluorite-H2O (Watson, 1999), but has never been observed in olivine/opx-melt samples. We synthesized olivine/opx-melt (harzburgite) samples by isostatically pressing oxide-high alumina basalt mixtures at 1350 °C and 1.5 GPa in a piston-cylinder apparatus. Nominal melt fractions of 0.02 to 0.20 and a constant 3 to 2 (olivine to opx) volume ratio were tested. Experimental charges were quenched, cored, and imaged using synchrotron X-ray microtomography. The resulting 3-D images constitute digital rock samples on which local melt fraction distributions, permeabilities, and electrical conductivities were numerically quantified. Our results are strong evidence for melt partitioning between olivine and opx: local melt fractions are 10 to 50% higher around olivine than opx grains. At the same melt fraction, permeabilities of whole harzburgite samples are lower compared to monomineralic olivine-melt samples (Miller et al., 2014). However, the presence of opx negligibly affects the permeability-porosity relation unless the abundance of opx is more than 40 vol. %. In contrast, electrical conductivities of harzburgites are systematically lower than those of olivine-melt samples. Lithological melt partitioning could be another mechanism responsible for forming high-porosity melt pathways in addition to reaction infiltration instability and deformation melt bands.

  20. Microtomography of partially molten rocks: three-dimensional melt distribution in mantle peridotite.

    PubMed

    Zhu, Wenlu; Gaetani, Glenn A; Fusseis, Florian; Montési, Laurent G J; De Carlo, Francesco

    2011-04-01

    The permeability of the upper mantle controls melt segregation beneath spreading centers. Reconciling contradictory geochemical and geophysical observations at ocean ridges requires a better understanding of transport properties in partially molten rocks. Using x-ray synchrotron microtomography, we obtained three-dimensional data on melt distribution for mantle peridotite with various melt fractions. At melt fractions as low as 0.02, triple junctions along grain edges dominated the melt network; there was no evidence of an abrupt change in the fundamental character of melt extraction as melt fraction increased to 0.2. The porosity of the partially molten region beneath ocean ridges is therefore controlled by a balance between viscous compaction and melting rate, not by a change in melt topology. PMID:21454786

  1. Microtomography of partially molten rocks: three-dimensional melt distribution in mantle peridotite.

    PubMed

    Zhu, Wenlu; Gaetani, Glenn A; Fusseis, Florian; Montési, Laurent G J; De Carlo, Francesco

    2011-04-01

    The permeability of the upper mantle controls melt segregation beneath spreading centers. Reconciling contradictory geochemical and geophysical observations at ocean ridges requires a better understanding of transport properties in partially molten rocks. Using x-ray synchrotron microtomography, we obtained three-dimensional data on melt distribution for mantle peridotite with various melt fractions. At melt fractions as low as 0.02, triple junctions along grain edges dominated the melt network; there was no evidence of an abrupt change in the fundamental character of melt extraction as melt fraction increased to 0.2. The porosity of the partially molten region beneath ocean ridges is therefore controlled by a balance between viscous compaction and melting rate, not by a change in melt topology.

  2. Microtomography of partially molten rocks : three-dimensional melt distribution in mantle peridotite.

    SciTech Connect

    Zhu, W.; Gaetani, G.; Fusseis, F.; Montesi, L.; De Carlo, F.

    2011-04-01

    The permeability of the upper mantle controls melt segregation beneath spreading centers. Reconciling contradictory geochemical and geophysical observations at ocean ridges requires a better understanding of transport properties in partially molten rocks. Using x-ray synchrotron microtomography, we obtained three-dimensional data on melt distribution for mantle peridotite with various melt fractions. At melt fractions as low as 0.02, triple junctions along grain edges dominated the melt network; there was no evidence of an abrupt change in the fundamental character of melt extraction as melt fraction increased to 0.2. The porosity of the partially molten region beneath ocean ridges is therefore controlled by a balance between viscous compaction and melting rate, not by a change in melt topology.

  3. Deformation mechanisms in granodiorite at effective pressures to 100 MPa and temperatures to partial melting

    SciTech Connect

    Friedman, M.; Handin, J.; Bauer, S.J.

    1981-01-01

    Deformation mechanisms in room-dry and water-saturated specimens of Charcoal Granodiorite, shortened at 10/sup -4/s/sup -1/, at effective pressures (Pe) to 100 MPa and temperatures to partial melting (less than or equal to 1050/sup 0/C) are documented with a view toward providing criteria to recognize and characterize the deformation for geological and engienering applications. Above 800/sup 0/C strength decreases dramatically at effective pressures greater than or equal to 50 MPa and water-weakening reduces strength an additional 30 to 40% at Pe = 100 MPa. Strains at failure are only 0.1 to 2.2% with macroscopic ductility (within this range) increasing as the effective pressures are increased and in wet versus dry tests. Shattering (multiple faulting) gives way to faulting along a single zone to failure without macroscopic faulting as ductility increases. Microscopically, cataclasis (extension microfracturing and thermal cracking with rigid-body motions) predominates at all conditions. Dislocation gliding contributes little to the strain. Precursive extension microfractures coalesce to produce the throughgoing faults with gouge zones exhibiting possible Riedel shears. Incipient melting, particularly in wet tests, produces a distinctive texture along feldspar grain boundaries that suggests a grain-boundary-softening effect contributes to the weakening. In addition, it is demonstrated that the presence of water does not lead to more microfractures, but to a reduction in the stresses required to initiate and propagate them.

  4. Storage of fluids and melts at subduction zones detectable by seismic tomography

    NASA Astrophysics Data System (ADS)

    Luehr, B. G.; Koulakov, I.; Rabbel, W.; Brotopuspito, K. S.; Surono, S.

    2015-12-01

    During the last decades investigations at active continental margins discovered the link between the subduction of fluid saturated oceanic plates and the process of ascent of these fluids and partial melts forming a magmatic system that leads to volcanism at the earth surface. For this purpose the geophysical structure of the mantle and crustal range above the down going slap has been imaged. Information is required about the slap, the ascent paths, as well as the reservoires of fluids and partial melts in the mantle and the crust up to the volcanoes at the surface. Statistically the distance between the volcanoes of volcanic arcs down to their Wadati Benioff zone results of approximately 100 kilometers in mean value. Surprisingly, this depth range shows pronounced seismicity at most of all subduction zones. Additionally, mineralogical laboratory investigations have shown that dehydration of the diving plate has a maximum at temperature and pressure conditions we find at around 100 km depth. The ascent of the fluids and the appearance of partial melts as well as the distribution of these materials in the crust can be resolved by seismic tomographic methods using records of local natural seismicity. With these methods these areas are corresponding to lowered seismic velocities, high Vp/Vs ratios, as well as increased attenuation of seismic shear waves. The anomalies and their time dependence are controlled by the fluids. The seismic velocity anomalies detected so far are within a range of a few per cent to more than 30% reduction. But, to explore plate boundaries large and complex amphibious experiments are required, in which active and passive seismic investigations should be combined to achieve best results. The seismic station distribution should cover an area from before the trench up to far behind the volcanic chain, to provide under favorable conditions information down to 150 km depth. Findings of different subduction zones will be compared and discussed.

  5. Recrystallization and zone melting of charged colloids by thermally induced crystallization.

    PubMed

    Shinohara, Mariko; Toyotama, Akiko; Suzuki, Misaki; Sugao, Yukihiro; Okuzono, Tohru; Uchida, Fumio; Yamanaka, Junpei

    2013-08-01

    We examined the application of recrystallization and zone-melting crystallization methods, which have been used widely to fabricate large, high-purity crystals of atomic and molecular systems, to charged colloidal crystals. Our samples were aqueous dispersions of colloidal silica (with particle diameters of d = 108 or 121 nm and particle volume fractions of ϕ = 0.035-0.05) containing the weak base pyridine. The samples crystallized upon heating because of increases in the particle charge numbers, and they melted reversibly on cooling. During the recrystallization experiments, the polycrystalline colloids were partially melted in a Peltier cooling device and then were crystallized by stopping the cooling and allowing the system to return to ambient temperature. The zone-melting crystallization was carried out by melting a narrow zone (millimeter-sized in width) of the polycrystalline colloid samples and then moving the sample slowly over a cooling device to recrystallize the molten region. Using both methods, we fabricated a few centimeter-sized crystals, starting from millimeter-sized original polycrystals when the crystallization rates were sufficiently slow (33 μm/s). Furthermore, the optical quality of the colloidal crystals, such as the half-band widths of the diffraction peaks, was significantly improved. These methods were also useful for refining. Small amounts of impurity particles (fluorescent polystyrene particles, d = 333 nm, ϕ = 5 × 10(-5)), added to the colloidal crystals, were excluded from the crystals when the crystallization rates were sufficiently slow (∼0.1 μm/s). We expect that the present findings will be useful for fabricating large, high-purity colloidal crystals.

  6. Effect of water on the composition of partial melts of greenstone and amphibolite

    NASA Technical Reports Server (NTRS)

    Beard, James S.; Lofgren, Gary E.

    1989-01-01

    Closed-system partial melts of hydrated, metamorphosed arc basalts and andesites (greenstones and amphibolites), where only water structurally bound in metamorphic minerals is available for melting (dehydration melting), are generally water-undersaturated, coexist with plagioclase-rich, anhydrous restites, and have compositions like island arc tonalites. In contrast, water-saturated melting at water pressures of 3 kilobars yields strongly peraluminous, low iron melts that coexist with an amphibole-bearing, plagioclase-poor restite. These melt compositions are unlike those of most natural silicic rocks. Thus, dehydration melting over a range of pressures in the crust of island arcs is a plausible mechanism for the petrogenesis of islands arc tonalite, whereas water-saturated melting at pressure of 3 kilobars and above is not.

  7. Slab melting versus slab dehydration in subduction-zone magmatism

    PubMed Central

    Mibe, Kenji; Kawamoto, Tatsuhiko; Matsukage, Kyoko N.; Fei, Yingwei; Ono, Shigeaki

    2011-01-01

    The second critical endpoint in the basalt-H2O system was directly determined by a high-pressure and high-temperature X-ray radiography technique. We found that the second critical endpoint occurs at around 3.4 GPa and 770 °C (corresponding to a depth of approximately 100 km in a subducting slab), which is much shallower than the previously estimated conditions. Our results indicate that the melting temperature of the subducting oceanic crust can no longer be defined beyond this critical condition and that the fluid released from subducting oceanic crust at depths greater than 100 km under volcanic arcs is supercritical fluid rather than aqueous fluid and/or hydrous melts. The position of the second critical endpoint explains why there is a limitation to the slab depth at which adakitic magmas are produced, as well as the origin of across-arc geochemical variations of trace elements in volcanic rocks in subduction zones. PMID:21536910

  8. Partial melting of amphibolite to trondhjemite at Nunatak Fiord, St. Elias Mountains, Alaska

    SciTech Connect

    Barker, F.; McLellan, E.L.; Plafker, G.

    1985-01-01

    At Nunatak Fiord, 55km NE of Yakutat, Alaska, a uniform layer of Cretaceous basalt ca. 3km thick was metamorphosed ca. 67 million years ago to amphibolite and locally partially melted to pegmatitic trondhjemite. Segregations of plagioclase-quartz+/-biotite rock, leucosomes in amphibolite matrix, range from stringers 5-10mm thick to blunt pods as thick as 6m. They tend to be parallel to foliation of the amphibolite, but crosscutting is common. The assemblage aluminous hornblende-plagioclase-epidote-sphene-quartz gave a hydrous melt that crystallized to plagioclase-quartz+/-biotite pegmatitic trondhjemite. 5-10% of the rock melted. Eu at 2x chondrites is positively anomalous. REE partitioning in melt/residum was controlled largely by hornblende and sphene. Though the mineralogical variability precludes quantitative modeling, partial melting of garnet-free amphibolite to heavy-REE-depleted trondhjemitic melt is a viable process.

  9. Production of ferroan andesites by the experimental partial melting of an LL chondrite

    NASA Technical Reports Server (NTRS)

    Mcguire, J. C.; Jurewicz, A. J. G.; Jones, J. H.

    1994-01-01

    A partial melting experiment on the St. Severin (LL) chondrite produced a melt that was andesitic, having 54-60 wt% silica, at 1200 C and an oxygen fugacity of IW+2, two log units above the iron-wustite (IW) buffer. Under these same conditions, CV, CM, and L chondrites produced low-silica melts resembling angrites. This experimental study attempts to reproduce and explain this unusual result.

  10. Melting Temperature and Partial Melt Chemistry of H2O-Saturated Mantle Peridotite to 11 Gigapascals

    PubMed

    Kawamoto; Holloway

    1997-04-11

    The H2O-saturated solidus of a model mantle composition (Kilborne Hole peridotite nodule, KLB-1) was determined to be just above 1000°C from 5 to 11 gigapascals. Given reasonable H2O abundances in Earth's mantle, an H2O-rich fluid could exist only in a region defined by the wet solidus and thermal stability limits of hydrous minerals, at depths between 90 and 330 kilometers. The experimental partial melts monotonously became more mafic with increasing pressure from andesitic composition at 1 gigapascal to more mafic than the starting peridotite at 10 gigapascals. Because the chemistry of the experimental partial melts is similar to that of kimberlites, it is suggested that kimberlites may be derived by low-temperature melting of an H2O-rich mantle at depths of 150 to 300 kilometers. PMID:9092469

  11. Melting Temperature and Partial Melt Chemistry of H2O-Saturated Mantle Peridotite to 11 Gigapascals

    PubMed

    Kawamoto; Holloway

    1997-04-11

    The H2O-saturated solidus of a model mantle composition (Kilborne Hole peridotite nodule, KLB-1) was determined to be just above 1000°C from 5 to 11 gigapascals. Given reasonable H2O abundances in Earth's mantle, an H2O-rich fluid could exist only in a region defined by the wet solidus and thermal stability limits of hydrous minerals, at depths between 90 and 330 kilometers. The experimental partial melts monotonously became more mafic with increasing pressure from andesitic composition at 1 gigapascal to more mafic than the starting peridotite at 10 gigapascals. Because the chemistry of the experimental partial melts is similar to that of kimberlites, it is suggested that kimberlites may be derived by low-temperature melting of an H2O-rich mantle at depths of 150 to 300 kilometers.

  12. Redistribution of Core-forming Melt During Shear Deformation of Partially Molten Peridotite

    NASA Technical Reports Server (NTRS)

    Hustoft, J. W.; Kohlstedt, D. L.

    2002-01-01

    To investigate the role of deformation on the distribution of core-forming melt in a partially molten peridotite, samples of olivine-basalt-iron sulfide were sheared to large strains. Dramatic redistribution of sulfide and silicate melts occur during deformation. Additional information is contained in the original extended abstract.

  13. Melting Behaviour of Carbonated MORB: the transition zone carbon filter

    NASA Astrophysics Data System (ADS)

    Thomson, A. R.; Walter, M. J.; Kohn, S. C.

    2014-12-01

    The convecting mantle represents Earth's largest reservoir for volatile storage on geological timescales. Continuous outgassing in volcanic settings worldwide indicates that volatile recycling during subduction of oceanic crust is critical for the maintenance of mantle volatile contents. Subducting basaltic crust initially contains a cocktail of volatiles, but it loses effectively its entire water cargo as hydrous fluids between 70 and 300 km depending on slab temperature [1], which may leave a residual anhydrous carbonated MORB assemblage. The fate of this carbon during subduction to greater depths is important geologically due to its potential role in causing mantle melting and metasomatism. Large discrepancies exist among studies of carbonated eclogite, and results are scarce beyond 10 GPa. Here we present results of experiments on MORB containing 2.5 wt.% CO2between 3 and 21 GPa. We observe a subsolidus phase assemblage dominated by garnet, clinopyroxene and SiO2 at all pressures. At pressures lower than 7 GPa CO2 is the stable carbon phase in all runs due to the reaction dol + 2coes = cpx + CO2 [2]. Solid dolomite, magnesite and/or Na2(Ca,Mg,Fe)4(CO3)5 are observed in subsolidus experiments at higher pressure. Near-solidus melts above 7 GPa are carbonatites, with Ca# > 0.5 and alkali contents that increase with pressure. The solidus temperature of 1200 °C at 3 GPa rises to 1375 °C at 13 GPa. At higher pressure the melting temperature drops sharply by > 200 °C to ~ 1150 °C. This creates a ledge in the solidus at 13 - 15 GPa, just above or within the uppermost transition zone, which coincides with the appearance of Na2(Ca,Mg,Fe)4(CO3)5. Temperature paths for the majority of worldwide slabs [3] intersect this ledge and produce carbonatite melt that will metasomatise the overlying mantle, potentially causing a region of increased diamond formation. Only material in the coldest slabs will pass beneath the ledge and carry carbon deeper into the Earth. Thus, this

  14. Trace element behavior and P-T-t evolution during partial melting of exhumed eclogite in the North Qaidam UHPM belt (NW China): Implications for adakite genesis

    NASA Astrophysics Data System (ADS)

    Zhang, Guibin; Niu, Yaoling; Song, Shuguang; Zhang, Lifei; Tian, Zuolin; Christy, Andrew G.; Han, Lei

    2015-06-01

    We have studied trace element behavior and timing of decompression melting of UHP rocks during exhumation recorded in the magmatic products, i.e., the melt phase (leucosomes), cumulate (garnetite) and residue (amphibolitized eclogite) from a single outcrop in the south Dulan area, North Qaidam UHPM belt, NW China. Two distinct episodes of partial melting are recognized. First, Grt-free tonalitic-trondhjemitic leucosome melts with higher silica crystallized at 424.0 ± 2.7 Ma. Garnets grew in the leucosome melt but fractionated out to form garnetite cumulates along with Ti-rich phases (rutile and titanite), strengthening the adakitic signature of the leucosome. Later Grt-bearing leucosome melts with an age of 412.4 ± 2.9 Ma cross-cut boudins and layers of amphibolitized eclogite. Geochemical investigation of bulk-rocks and in situ minerals verifies the genetic relationship between the amphibolitized eclogite and the tonalitic-trondhjemitic melts. Zircons from the amphibolitized eclogite have older (> 700 Ma) protolith ages, with subsequent eclogite-facies metamorphism, retrograde granulite-facies overprinting and partial melting. Phase modeling and Zr-in-rutile thermometry calculations in combination with zircon geochronology reveal the evolution P-T-t path for the exhumation and the partial melting of the deeply subducted continental crust at the North Qaidam subduction zone in the Early Paleozoic.

  15. Bulk YBa2Cu3O(x) superconductors through pressurized partial melt growth processing

    NASA Technical Reports Server (NTRS)

    Hu, S.; Hojaji, H.; Barkatt, A.; Boroomand, M.; Hung, M.; Buechele, A. C.; Thorpe, A. N.; Davis, D. D.; Alterescu, S.

    1992-01-01

    A novel pressurized partial melt growth process has been developed for producing large pieces of bulk Y-Ba-Cu-O superconductors. During long-time partial melt growth stage, an additional driving force for solidification is obtained by using pressurized oxygen gas. The microstructure and superconducting properties of the resulting samples were investigated. It was found that this new technique can eliminate porosity and inhomogeneity, promote large-scale grain-texturing, and improve interdomain coupling as well.

  16. Multi-stage barites in partially melted UHP eclogite: implications for fluid/melt activities during deep continental subduction in the Sulu orogenic belt

    NASA Astrophysics Data System (ADS)

    Wang, Songjie; Wang, Lu

    2015-04-01

    . Zr-in-rutile thermometry shows their formation temperature to be 586-664 oC at 1.5-2.5 GPa. Barite-bearing MS inclusions with Ba-bearing K-feldspar (type-II) connected by Kfs+Pl+Bt veinlets of in-situ phengite breakdown and thin barite veinlets along grain boundaries (type-III) are products of phengite breakdown and induced fluid flow during exhumation. These barites have witnessed the gradational separation process of melt/ fluid from miscibility on/above the second critical endpoint during UHP metamorphism, to immiscibility along the exhumation path of the subducted slab. Associated reactions from pyrite to hematite and goethite with the type-III barite ring surrounding the pyrite provide evidence for a local high oxygen fugacity environment during eclogite partial melting and subsequent melt/fluid crystallization processes. Moreover, large grain barite aggregations (type-IV) modified by amphibole+albite symplectite are most likely formed by release of molecular and hydroxyl water from anhydrous minerals of eclogite during high-grade amphibolite-facies retrogression. The growth of multi-stage barites in UHP eclogite further advances our understanding of fluid/melt transfer, crystallization processes along the subduction-exhumation path of the partially melted eclogite, broadening our knowledge of melt/fluid evolution within subduction-collision zones worldwide. REFERENCES Chen Y.X., et al., 2014, Lithos, 200, 1-21. Liu J.B., et al., 2000, Acta Petrologica Sinica 16(4), 482-484. Zeng L.S., et al., 2007, Chinese Science Bulletin, 52(21), 2995-3001. Gao X.Y., et al., 2012, Journal of Metamorphic Geology, 30(2), 193-212.

  17. H2O-fluid-saturated melting of subducted continental crust facilitates exhumation of ultrahigh-pressure rocks in continental subduction zones

    NASA Astrophysics Data System (ADS)

    Labrousse, L.; Duretz, T.; Gerya, T.

    2015-10-01

    We present two-dimensional numerical models of plate subduction and collision inspired by the Scandinavian Caledonian orogeny to investigate the possible impact of continental crust partial melting on the exhumation of ultra-high pressure metamorphic rocks. Three possible reactions were tested: low temperature solidus representing H2O-fluid-saturated partial melting, and two end-member reaction curves for dehydration melting. Thermo-mechanical effects of partial melting were implemented as (1) a viscosity decrease as a determined rheologically critical melt percentage was reached (here 0.1), (2) a change in effective heat capacity and adiabatic heating/cooling accounting for a latent heat term in the heat equation. Among the 3 tested reactions, only H2O-fluid-saturated partial melting drastically modifies the collision dynamics from the non-melting reference model holding all other parameters constant. A substantially low general viscosity truncation (here 1017 Pa s) is needed to properly resolve the effect of partial melting on deep collision processes. Low temperature melting indeed induces the development of a low viscosity buoyant plume prior to slab detachment, where migmatites exhume from UHP conditions at rates and with pressure-temperature paths similar to the natural values acknowledged for the Norwegian Caledonides. High temperature melting has no drastic influence on early collision dynamics. While positive buoyancy remains the first order driver for the exhumation of buried continental rocks, exhumation initiates in these cases with eduction subsequent to slab detachment. Melting and formation of a migmatite plume can later occur along decompression path while continental crust undergoes thermal reequilibration at temperatures above 900 °C. Some of the partially molten material can also relaminate in the overriding plate rather than exhume within the collision zone. Even if minor in terms of amount of magma produced, H2O-fluid-saturated partial melting

  18. Implications for Melt Differentiation Processes in the Central Mexican Volcanic Belt from 'Zoned' Monogenetic Volcanoes

    NASA Astrophysics Data System (ADS)

    Straub, S. M.; Gomez-Tuena, A.; Goldstein, S. L.; Cai, Y. M.; Martin-Del Pozzo, A.

    2007-05-01

    ' towards lower FeO* and TiO2 with decreasing Mg#. These 'differentiation trends' are preserved fully or partially within individual monogenetic centers. Our preliminary trace element and isotope data suggest that these 'differentiation trends' can neither by explained simply by fractional crystallization nor by crustal assimiliation but require more complex petrogenesis that may involve serial addition of slab components to mantle sources. These competing models are testable by comprehensive trace elements and isotope studies in combination with mineral and melt inclusions work on zoned monogenetic centers.

  19. Partial melting of apatite-bearing charnockite, granulite, and diorite: Melt compositions, restite mineralogy, and petrologic implications

    NASA Technical Reports Server (NTRS)

    Beard, James S.; Lofgren, Gary E.; Sinha, A. Krishna; Tollo, Richard P.

    1994-01-01

    Melting experiments (P = 6.9 kbar, T = 850-950 deg C, NNO is less than fO2 is less than HM) were done on mafic to felsic charnockites, a dioritic gneiss, and a felsic garnet granulite, all common rock types in the Grenville basement of eastern North America. A graphite-bearing granulite gneiss did not melt. Water (H2O(+) = 0.60 to 2.0 wt %) is bound in low-grade, retrograde metamorphic minerals and is consumed during the earliest stages of melting. Most melts are water-undersaturated. Melt compositions range from metaluminous, silicic granodiorite (diorite starting composition) to peraluminous or weakly metaluminous granites (all others). In general, liquids become more feldspathic, less silicic, and less peraluminous and are enriched in FeO, MgO, and TiO2 with increasing temperature. Residual feldspar mineralogy controls the CaO, K2O, and Na2O contents of the partial melts and the behavior of these elements can be used, particularly if the degree of source melting can be ascertained, to infer some aspects of the feldspar mineralogy of the source. K-feldspar, a common restite phase in the charnockite and granulite (but not the diorite) should control the behavior of Ba and, possibly, Eu in these systems and yield signatures of these elements that can distinguish source regions and, in some cases, bulk versus melt assimilation. Apatite, a common restite phase, is enriched in rare earth elements (REE), especially middle REE. Retention of apatite in the restite will result in steep, light REE-enriched patterns for melts derived from the diorite and charnockites.

  20. Partially Melted UHP Eclogite in the Sulu Orogenic Belt, China and its rheological significance to deep continental subduction: Micro- to Macro-scale Evidence

    NASA Astrophysics Data System (ADS)

    Wang, Lu; Kusky, Timothy; Polat, Ali; Wang, Songjie; Jiang, Xingfu; Zong, Keqing; Wang, Junpeng; Deng, Hao; Fu, Jianmin

    2015-04-01

    . Whole-rock trace element analyses show that the leucocratic rocks, residue and peak metamorphic stage eclogite (no decompression partial melting) show well matched mass balance relationships. Melts derived from eclogite partial melting lubricated the subducted eclogite slices and facilitated their buoyant rise from mantle depths to crustal levels. Partial melting of deeply subducted eclogite is an important process in determining the rheological structure and mechanical behavior of subducted lithosphere and its rapid exhumation, controlling flow of deep lithospheric material, and for generation of melts from the upper mantle, potentially contributing to arc magmatism and growth of continental crust. Deeply subducted, partially melted eclogite from General's Hill show that eclogites can develop regularly spaced melt channels, a meter or two thick, that would act as significant seismic anomalies5. This may provide direct evidence for the nature of enigmatic 'bright zones' presented in some deep-crustal seismic reflection profiles which have been interpreted to represent areas of melt, high fluid content or unusual rock compositions6. Hermann, J. & Green, D. H. (2001). Earth Planet. Sci. Lett. 188, 149-168. Song, S.G., et al. (2014). Geochim. Cosmochim. Acta 130 42-62. Zhang, G.B., et al. (2014). Lithos, doi: 10.1016/j.lithos.2014.12.009 Gao, X. Y., et al. (2012). J. Metamorph. Geol. 30, 193-212. Wang, L., et al. (2014). Nature Communications. 5:5604 doi: 10.1038/ncomms6604. Brown, L. et al. (1996). Science 274, 1688-1690.

  1. Partial Melting of the Aliende (CV3) Meteorite: Implications for Origins of Basaltic Meteorites.

    PubMed

    Jurewicz, A J; Mittlefehldt, D W; Jones, J H

    1991-05-01

    Eucrites and angrites are distinct types of basaltic meteorites whose origins are poorly known. Experiments in which samples of the Allende (CV3) carbonaceous chondrite were partially melted indicate that partial melts can resemble either eucrites or angrites, depending only on the oxygen fugacity (fo(2)). Melts are eucritic if thefo(2) is below that of the iron-wüstite buffer or angritic if above the fo(2) of that buffer. With changing pressure, the graphite-oxygen redox reaction can produce oxygen fugacities that are above or below those of the iron-wüstite buffer. Therefore, a single, homogeneous, carbonaceous planetoid >110 kilometers in radius could produce melts of drastically different composition, depending on the depth of melting.

  2. Electrical conductivity of partially-molten olivine aggregate and melt interconnectivity in the oceanic upper mantle

    NASA Astrophysics Data System (ADS)

    Laumonier, Mickael; Frost, Dan; Farla, Robert; Katsura, Tomoo; Marquardt, Katharina

    2016-04-01

    A consistent explanation for mantle geophysical anomalies such as the Lithosphere-Astenosphere Boundary (LAB) relies on the existence of little amount of melt trapped in the solid peridotite. Mathematical models have been used to assess the melt fraction possibly lying at mantle depths, but they have not been experimentally checked at low melt fraction (< 2 vol. %). To fill this gap, we performed in situ electrical conductivity (EC) measurement on a partially-molten olivine aggregate (Fo92-olivine from a natural peridotite of Lanzarote, Canary Islands, Spain) containing various amount of basaltic (MORB-like composition) melt (0 to 100%) at upper mantle conditions. We used the MAVO 6-ram press (BGI) combined with a Solartron gain phase analyser to acquire the electrical resistance of the sample at pressure of 1.5 GPa and temperature up to 1400°C. The results show the increase of the electrical conductivity with the temperature following an Arrhenius law, and with the melt fraction, but the effect of pressure between 1.5 and 3.0 GPa was found negligible at a melt fraction of 0.5 vol.%. The conductivity of a partially molten aggregate fits the modified Archie's law from 0.5 to 100 vol.%. At melt fractions of 0.25, 0.15 and 0.0 vol.%, the EC value deviates from the trend previously defined, suggesting that the melt is no longer fully interconnected through the sample, also supported by chemical mapping. Our results extend the previous results obtained on mixed system between 1 and 10% of melt. Since the melt appears fully interconnected down to very low melt fraction (0.5 vol.%), we conclude that (i) only 0.5 to 1 vol.% of melt is enough to explain the LAB EC anomaly, lower than previously determined; and (ii) deformation is not mandatory to enhance electrical conductivity of melt-bearing mantle rocks.

  3. Morphology of melt-rich channels formed during reaction infiltration experiments on partially molten mantle rocks

    NASA Astrophysics Data System (ADS)

    Pec, Matej; Holtzman, Benjamin; Zimmerman, Mark; Kohlstedt, David

    2016-04-01

    Geochemical, geophysical and geological observations suggest that melt extraction from the partially molten mantle occurs by some sort of channelized flow. Melt-solid reactions can lead to melt channelization due to a positive feedback between melt flow and reaction. If a melt-solid reaction increases local permeability, subsequent flow is increased as well and promotes further reaction. This process can lead to the development of high-permeability channels which emerge from background flow. In nature, anastomozing tabular dunite bodies within peridotitic massifs are thought to represent fossilized channels that formed by reactive flow. The conditions under which such channels can emerge are treated by the reaction infiltration instability (RII) theory (e.g. Szymczak and Ladd 2014). In this contribution, we report the results of a series of Darcy type experiments designed to study the development of channels due to RII in mantle lithologies (Pec et al. 2015). We sandwiched a partially molten rock between a melt source and a porous sink and annealed it at high-pressures (P = 300 MPa) and high-temperatures (T = 1200° or 1250° C) under a controlled pressure gradient (∇P = 0-100 MPa/mm) for up to 5 hours. The partially molten rock is formed by 50:50 mixtures of San Carlos olivine (Ol, Fo ˜ 88) and clinopyroxene (Cpx) with either 4, 10 or 20 vol% of alkali basalt added. The source and sink are disks of alkali basalt and porous alumina, respectively. During the experiments, silica undersaturated melt from the melt source dissolves Cpx and precipitates an iron rich Ol (Fo ˜ 82) thereby forming a Cpx-free reaction layer at the melt source - partially molten rock interface. The melt fraction in the reaction layer increases significantly (40% melt) compared to the protolith, confirming that the reaction increases the permeability of the partially molten rock. In experiments annealed under a low pressure gradient (and hence slow melt flow velocity) the reaction layer is

  4. Grain-scale alignment of melt in sheared partially molten rocks: implications for viscous anisotropy

    NASA Astrophysics Data System (ADS)

    Pec, Matej; Quintanilla-Terminel, Alejandra; Holtzman, Benjamin; Zimmerman, Mark; Kohlstedt, David

    2016-04-01

    Presence of melt significantly influences rheological properties of partially molten rocks by providing fast diffusional pathways. Under stress, melt aligns at the grain scale and this alignment induces viscous anisotropy in the deforming aggregate. One of the consequences of viscous anisotropy is melt segregation into melt-rich sheets oriented at low angle to the shear plane on much larger scales than the grain scale. The magnitude and orientation of viscous anisotropy with respect to the applied stress are important parameters for constitutive models (Takei and Holtzman 2009) that must be constrained by experimental studies. In this contribution, we analyze the shape preferred orientation (SPO) of individual grain-scale melt pockets in deformed partially molten mantle rocks. The starting materials were obtained by isostatically hot-pressing olivine + basalt and olivine + chromite + basalt powders. These partially molten rocks were deformed in general shear or torsion at a confining pressure, Pc = 300 MPa, temperature, T = 1200° - 1250° C, and strain rates of 10-3 - 10-5 s-1to finite shear strains, γ, of 0.5 - 5. After the experiment, high resolution backscattered electron images were obtained using a SEM equipped with a field emission gun. Individual melt pockets were segmented and their SPO analyzed using the paror and surfor methods and Fourier transforms (Heilbronner and Barret 2014). Melt segregation into melt-rich sheets inclined at 15° -20° antithetic with respect to the shear plane occurs in three-phase system (olivine + chromite + basalt) and in two-phase systems (olivine + basalt) twisted to high strain. The SPO of individual melt pockets within the melt-rich bands is moderately strong (b/a ≈ 0.8) and is always steeper (20° -40°) than the average melt-rich band orientation. In the two-phase system (olivine + basalt) sheared to lower strains, no distinct melt-rich sheets are observed. Individual grain-scale melt pockets are oriented at 45° -55

  5. Global Cycling of Carbon Constrained by Partial Melting Experiments of Carbonated Mantle Peridotite and Eclogite

    NASA Astrophysics Data System (ADS)

    Dasgupta, R.; Hirschmann, M. M.; Withers, A. C.

    2005-12-01

    The mass of carbon stored in the mantle exceeds that in all other Earth's reservoirs combined1 and large fluxes of carbon are cycled into and out of the mantle via subduction and volcanic emission. Outgassing of CO2 from the mantle has a critical influence on Earth's climate for time scales of 108-109 yr1. The residence time for carbon in the mantle is thought to exceed the age of the Earth1,2, but it could be significantly less owing to pervasive deep melting beneath oceanic ridges. The chief flux of subducted carbon is via carbonate in altered ocean-floor basalts, which survives dehydration during subduction. Because solidi of carbonated eclogite remain hotter than average subduction geotherms at least up to transition zone3, significant subducted C is delivered to the deep Earth. In upwelling mantle, however, partial melting of carbonated eclogite releases calcio-dolomitic carbonatite melt at depths near ~400 km and metasomatically implants carbonate to surrounding peridotite. Thus, volcanic release of CO2 to basalt source regions is controlled by the solidus of carbonated peridotite. We conducted experiments with nominally anhydrous, carbonated garnet lherzolite (PERC: MixKLB-1+2.5 wt.% CO2) using Pt/C capsules in piston cylinder (3 GPa) and Walker-style multi-anvil presses (4 to 10 GPa) and between 1075-1500 °C. The stable near-solidus crystalline carbonate is dolomitess at 3 GPa and magnesitess from 4 to 10 GPa. Carbonate melt is stabilized at the solidus and crystalline carbonate disappears within 20-60°. The solidus increases from ≥1075 °C at 3 GPa to 1110-1140 °C at 4.1 GPa as the stable carbonate transforms from dolomitess to magnesitess. From 4.1 GPa, the solidus of PERC magnesite lherzolite increases to ~1500 °C at 10 GPa. In upwelling mantle the solidus of carbonated lherzolite is ~100-200 km shallower than that of eclogite+CO2, but beneath oceanic ridges, initial melting occurs as deep as 300-330 km. For peridotite with ~120-1200 ppm CO2, this

  6. Earth's Deep Carbon Cycle Constrained by Partial Melting of Mantle Peridotite and Eclogite

    NASA Astrophysics Data System (ADS)

    Dasgupta, R.; Hirschmann, M. M.; Withers, A. C.

    2006-05-01

    The mass of carbon in the mantle is thought to exceed that in all Earth's other reservoirs combined1 and large fluxes of carbon are cycled into and out of the mantle via subduction and volcanic emission. Devolatilization is known to release water in the mantle wedge, but release of carbon could be delayed if the relevant decarbonation reactions or solidi of oceanic crust are not encountered along P-T path of subduction. Outgassing of CO2 from the mantle also has a critical influence on Earth's climate for time scales of 108-109 yr1. The residence time for carbon in the mantle is thought to exceed the age of the Earth1,2, but it could be significantly shorter owing to pervasive deep melting beneath oceanic ridges. The dominant influx of carbon is via carbonate in altered ocean-floor basalts, which survives decarbonation during subduction. Our experiments demonstrate that solidi of carbonated eclogite remain hotter than average subduction geotherms at least as deep as transition zone3, and thus significant subducted C is delivered to the deep Earth, rather than liberated in the shallow mantle by melting. Flux of CO2 into the mantle, assuming average estimate of carbon in altered ocean crust of 0.21 wt. % CO24, can amount to 0.15 × 1015 g/yr. In upwelling mantle, however, partial melting of carbonated eclogite releases calcio-dolomitic carbonatite melt at depths near ~400 km and metasomatically implants carbonate to surrounding peridotite. Thus, volcanic release of CO2 to basalt source regions is likely controlled by the solidus of carbonated peridotite. Our recent experiments with nominally anhydrous, carbonate-bearing garnet lherzolite indicate that the solidus of peridotite with a trace amount of CO2 is ~500 °C lower than that of volatile-free peridotite at 10 GPa5. In upwelling mantle the solidus of carbonated lherzolite is ~100-200 km shallower than that of eclogite+CO2, but beneath oceanic ridges, initial melting occurs as deep as 300-330 km. For peridotite

  7. Receiver function constraints on crustal seismic velocities and partial melting beneath the Red Sea rift and adjacent regions, Afar Depression

    NASA Astrophysics Data System (ADS)

    Reed, Cory A.; Almadani, Sattam; Gao, Stephen S.; Elsheikh, Ahmed A.; Cherie, Solomon; Abdelsalam, Mohamed G.; Thurmond, Allison K.; Liu, Kelly H.

    2014-03-01

    The Afar Depression is an ideal locale for the investigation of crustal processes involved in the transition from continental rifting to oceanic spreading. To provide relatively high resolution images of the crust beneath the Red Sea rift (RSR) represented by the Tendaho graben in the Afar Depression, we deployed an array of 18 broadband seismic stations in 2010 and 2011. Stacking of about 2300 receiver functions from the 18 and several nearby stations along the ~200 km long array reveals an average crustal thickness of 22±4 km, ranging from ~17 km near the RSR axis to 30 km within the overlap zone between the Red Sea and Gulf of Aden rifts. The resulting anomalously high Vp/Vs ratios decrease from 2.40 in the southwest to 1.85 within the overlap zone. We utilize theoretical Vp and melt fraction relationships to obtain an overall highly reduced average crustal Vp of ~5.1 km/s. The melt percentage is about 10% beneath the RSR while the overlap zone contains minor quantities of partial melt. The observed high Vp/Vs values beneath most of the study area indicate widespread partial melting beneath the southwest half of the profile, probably as a result of gradual eastward migration of the RSR axis. Our results also suggest that the current extensional strain in the lower crust beneath the region is diffuse, while the strain field in the upper crust is localized along narrow volcanic segments. These disparate styles of deformation imply a high degree of decoupling between the upper and lower crust.

  8. Partial melting of deeply subducted eclogite from the Sulu orogen in China.

    PubMed

    Wang, Lu; Kusky, Timothy M; Polat, Ali; Wang, Songjie; Jiang, Xingfu; Zong, Keqing; Wang, Junpeng; Deng, Hao; Fu, Jianmin

    2014-12-17

    We report partial melting of an ultrahigh pressure eclogite in the Mesozoic Sulu orogen, China. Eclogitic migmatite shows successive stages of initial intragranular and grain boundary melt droplets, which grow into a three-dimensional interconnected intergranular network, then segregate and accumulate in pressure shadow areas and then merge to form melt channels and dikes that transport magma to higher in the lithosphere. Here we show, using zircon U-Pb dating and petrological analyses, that partial melting occurred at 228-219 Myr ago, shortly after peak metamorphism at 230 Myr ago. The melts and residues are complimentarily enriched and depleted in light rare earth element (LREE) compared with the original rock. Partial melting of deeply subducted eclogite is an important process in determining the rheological structure and mechanical behaviour of subducted lithosphere and its rapid exhumation, controlling the flow of deep lithospheric material, and for generation of melts from the upper mantle, potentially contributing to arc magmatism and growth of continental crust.

  9. Partial melting of deeply subducted eclogite from the Sulu orogen in China.

    PubMed

    Wang, Lu; Kusky, Timothy M; Polat, Ali; Wang, Songjie; Jiang, Xingfu; Zong, Keqing; Wang, Junpeng; Deng, Hao; Fu, Jianmin

    2014-01-01

    We report partial melting of an ultrahigh pressure eclogite in the Mesozoic Sulu orogen, China. Eclogitic migmatite shows successive stages of initial intragranular and grain boundary melt droplets, which grow into a three-dimensional interconnected intergranular network, then segregate and accumulate in pressure shadow areas and then merge to form melt channels and dikes that transport magma to higher in the lithosphere. Here we show, using zircon U-Pb dating and petrological analyses, that partial melting occurred at 228-219 Myr ago, shortly after peak metamorphism at 230 Myr ago. The melts and residues are complimentarily enriched and depleted in light rare earth element (LREE) compared with the original rock. Partial melting of deeply subducted eclogite is an important process in determining the rheological structure and mechanical behaviour of subducted lithosphere and its rapid exhumation, controlling the flow of deep lithospheric material, and for generation of melts from the upper mantle, potentially contributing to arc magmatism and growth of continental crust. PMID:25517619

  10. Partial melting of deeply subducted eclogite from the Sulu orogen in China

    PubMed Central

    Wang, Lu; Kusky, Timothy M.; Polat, Ali; Wang, Songjie; Jiang, Xingfu; Zong, Keqing; Wang, Junpeng; Deng, Hao; Fu, Jianmin

    2014-01-01

    We report partial melting of an ultrahigh pressure eclogite in the Mesozoic Sulu orogen, China. Eclogitic migmatite shows successive stages of initial intragranular and grain boundary melt droplets, which grow into a three-dimensional interconnected intergranular network, then segregate and accumulate in pressure shadow areas and then merge to form melt channels and dikes that transport magma to higher in the lithosphere. Here we show, using zircon U–Pb dating and petrological analyses, that partial melting occurred at 228–219 Myr ago, shortly after peak metamorphism at 230 Myr ago. The melts and residues are complimentarily enriched and depleted in light rare earth element (LREE) compared with the original rock. Partial melting of deeply subducted eclogite is an important process in determining the rheological structure and mechanical behaviour of subducted lithosphere and its rapid exhumation, controlling the flow of deep lithospheric material, and for generation of melts from the upper mantle, potentially contributing to arc magmatism and growth of continental crust. PMID:25517619

  11. Dihedral angle of carbonatite melts in mantle residue near the upper mantle and transition zone

    NASA Astrophysics Data System (ADS)

    Ghosh, S. K.; Rohrbach, A.; Schmidt, M. W.

    2015-12-01

    Carbonate melts are thought to be ideal metasomatic agents in the deep upper mantle (Green & Wallace, 1988) and these melts are low in viscosities (10-1-10-3 Pa·s) compared to primitive basalt (101-102 Pa·s), furthermore the ability to form an interconnected grain-edge melt network at low melt fractions (< 1%) make carbonate melts extremely mobile. They are molten at relatively low temperatures and have solidus temperatures hundreds of degrees lower than silicate melts at >3 GPa (Dasgupta et al. 2006, Ghosh et al., 2009), dissolve a number of geochemically incompatible elements much better than silicate melts (Blundy and Dalton, 2000). Previous studies of carbonate melt dihedral angles in olivine-dominated matrices yielded 25-30oat 1-3 GPa, relatively independent of melt composition (Watson et al., 1990) and temperature (Hunter and McKenzie, 1989). Dihedral angles of carbonate melts in contact with deep mantle silicate phases (e.g. garnet, wadsleyite, and ringwoodite) which constitute more than 70 % of the deep upper mantle and transition zone have not been studied yet. We have performed multi-anvil experiments on carbonate-bearing peridotites with 5.0 wt% CO2 from 13.5 to 20 GPa 1550 oC to investigate the dihedral angle of magnesio-carbonatite melts in equilibrium with garnet, olivine (and its high-pressure polymorphs), and clinoenstatite. The dihedral angle of carbonate melts in the deep upper mantle and transition zone is ~30° for majorite garnet and olivine (and its polymorphs) dominated matrices. It does not change with increasing pressure in the range 13.5-20 GPa. Our results suggest that very low melt fractions of carbonatite melt forming in the deep upper mantle and transition zone are interconnected at melt fractions less than 0.01. Consistent with geophysical observations, this could possibly explain low velocity regions in the deep mantle and transition zone.

  12. Petrology and Wavespeeds in Central Tibet Indicate a Partially Melted Mica-Bearing Crust

    NASA Astrophysics Data System (ADS)

    Hacker, B. R.; Ritzwoller, M. H.; Xie, J.

    2013-12-01

    S-wave speeds and Vp/Vs ratios in the middle to deep crust of Tibet are best explained by a partially melted, mica-bearing middle to lower crust with a subhorizontal to gently dipping foliation. Surface-wave tomography [e.g., Yang et al., 2012; Xie et al., 2013] shows that the central Tibetan Plateau (the Qiangtang block) is characterized by i) slow S-wave speeds of 3.3-3.5 km/s at depths from 20-25 km to 45-50 km, ii) S-wave radial anisotropy of at least 4% (Vsh > Vsv) with stronger anisotropy in the west than the east [Duret et al., 2010], and iii) whole-crust Vp/Vs ratios in the range of 1.73-1.78 [Xu et al., 2013]. The depth of the Curie temperature for magnetite inferred from satellite magnetic measurements [Alsdorf and Nelson, 1999], the depth of the α-β quartz transition inferred from Vp/Vs ratios [Mechie et al., 2004], and the equilibration pressures and temperatures of xenoliths erupted from the mid-deep crust [Hacker et al., 2000] indicate that the thermal gradient in Qiangtang is steep, reaching 1000°C at 30-40 km depth. This thermal gradient crosses the dehydration-melting solidi for crustal rocks at 20-30 km depth, implying the presence or former presence of melt in the mid-deep crust. These temperatures do not require the wholesale breakdown of mica at these depths, because F and Ti can stabilize mica to at least 1300°C [Dooley and Patino Douce, 1996]. Petrology suggests, then, that the Qiangtang middle to deep crust consists of a mica-bearing residue from which melt has been extracted or is being extracted. Wavespeeds calculated for mica-bearing rocks with a subhorizontal to gently dipping foliation and minor silicate melt are the best match to the wavespeeds and anisotropy observed by seismology. Alsdorf, D., and D. Nelson, The Tibetan satellite magnetic low: Evidence for widespread melt in the Tibetan crust?, Geology, 27, 943-946, 1999. Dooley, D.F., and A.F. Patino Douce, Fluid-absent melting of F-rich phlogopite + rutile +quartz, American

  13. Evidence for melt partitioning between olivine and orthopyroxene in partially molten harzburgite

    NASA Astrophysics Data System (ADS)

    Miller, K.; Zhu, W.; Montesi, L. G.; Le Roux, V.; Gaetani, G. A.

    2013-12-01

    During melting at mid-ocean ridges, melt is driven into an equilibrium, minimum-energy configuration by surface energy gradients between solid-solid and solid-liquid phase boundaries. Such a configuration, where melt is mostly restricted to three and four-grain junctions, acts as a porous medium through which melt can percolate to the surface. For a monomineralic system, melt is distributed evenly among all grains. However, in mineralogical heterogeneous systems, melt partitions unevenly between the various solid phases to minimize the total energy of the system. In a ocean ridge melting environment, where olivine is often juxtaposed against orthopyroxene (opx), lithologic partitioning is expected to turn olivine-rich regions into high-permeability conduits, through which melt can be quickly extracted, drastically increasing the permeability of the mantle [Zhu and Hirth, 2003]. Lithologic partitioning has been demonstrated in experiments using analogue systems [Watson, 1999]; however, to date, no experiment has confirmed its existence in partially molten mantle systems. We present experimental results that determine the degree of melt partitioning between olivine and opx in partially molten harzburgites. Samples were prepared from a powdered mixture of oxides and carbonates and then hot-pressed in a solid-media piston-cylinder apparatus at 1350°C and 1.5GPa [Zhu et al., 2011] to achieve an 82/18 vol. % ratio of olivine to opx. Prior to hot-pressing, basalt was added to the powdered mixtures in various proportions to test for lithologic partitioning across a range of melt fractions. Three-dimensional, 700nm-resolution images of our samples were obtained using synchrotron X-ray microtomography on the 2BM station of the Advanced Photon Source at Argonne National Labs. Image data were filtered using an anisotropic diffusion filter to enhance phase contrast and then segmented to produce binary representations of each phase. In order to quantitatively demonstrate

  14. Melting curve of CaCO3 with implications for the presence of melt in the transition zone

    NASA Astrophysics Data System (ADS)

    Li, Z.; Li, J.

    2014-12-01

    Carbonates are important carriers for carbon exchange between the surface and interior of the Earth and therefore their melting behavior bears directly on the deep carbon cycle. Previous studies showed that the solidus temperature of carbonated silicate spans a wide range of temperature due to composition variations in the starting materials. In order to provide fundamental data for thermodynamic calculations, the melting curve of pure CaCO3 was measured up to 22 GPa using an in-situ electrical method in this study. The measurement was realized by monitoring abrupt changes in electrical conductivity upon melting. The results showed that the melting temperature of CaCO3 increases rapidly from 2 to 8 GPa, consistent with the existing data (Irving and Wyllie, 1975; Suito et al., 2001). Our new data at high pressures reveal that the CaCO3 melting curve flattens around 8GPa, starts to decrease until 15 GPa, and then increases again from 15 to 22 GPa. The changes in the melting slope reflect the evolution of the melt compressibility with pressure and the sub-solidus structural phase transformations. The inferred CaCO3 melt density from melting curve slope is slightly smaller than basaltic melt at same pressureand temperature. The unusual negative slope melting curve between 8 and 15 GPa likely indicates the presence of melt around 400-500 Km depth, which may explain some of observed low-velocity zones in the transition zone (Vinnik & Farra, 2006). Reference: Irving AJ, Wyllie PJ (1975) Subsolidus and melting relationshipsfor calcite, magnesite and the join CaCO3-MgCO3 to 36 kb. GeochimCosmochimActa 39: 35-53. Suito K, Namba J, Horikawa T, Taniguchi Y, Sakurai N, Kobayashi M, Onodera A, Shimomura O, Kikegawa T (2001) Phase relations of CaCO3 at high pressure and high temperature. Am Mineral 86(9):997-1002. Vinnik L. & Farra V. (2006) S velocity reversal in the mantle Transition Zone. Geophysical Research Letters 33, L18316.

  15. Lunar highland meteorite Dhofar 026 and Apollo sample 15418: Two strongly shocked, partially melted, granulitic breccias

    USGS Publications Warehouse

    Cohen, B. A.; James, O.B.; Taylor, L.A.; Nazarov, M.A.; Barsukova, L.D.

    2004-01-01

    Studies of lunar meteorite Dhofar 026, and comparison to Apollo sample 15418, indicate that Dhofar 026 is a strongly shocked granulitic breccia (or a fragmental breccia consisting almost entirely of granulitic breccia clasts) that experienced considerable post-shock heating, probably as a result of diffusion of heat into the rock from an external, hotter source. The shock converted plagioclase to maskelynite, indicating that the shock pressure was between 30 and 45 GPa. The post-shock heating raised the rock's temperature to about 1200 ??C; as a result, the maskelynite devitrified, and extensive partial melting took place. The melting was concentrated in pyroxene-rich areas; all pyroxene melted. As the rock cooled, the partial melts crystallized with fine-grained, subophitic-poikilitic textures. Sample 15418 is a strongly shocked granulitic breccia that had a similar history, but evidence for this history is better preserved than in Dhofar 026. The fact that Dhofar 026 was previously interpreted as an impact melt breccia underscores the importance of detailed petrographic study in interpretation of lunar rocks that have complex textures. The name "impact melt" has, in past studies, been applied only to rocks in which the melt fraction formed by shock-induced total fusion. Recently, however, this name has also been applied to rocks containing melt formed by heating of the rocks by conductive heat transfer, assuming that impact is the ultimate source of the heat. We urge that the name "impact melt" be restricted to rocks in which the bulk of the melt formed by shock-induced fusion to avoid confusion engendered by applying the same name to rocks melted by different processes. ?? Meteoritical Society, 2004.

  16. Partial melting of a Pb-Sn mushy layer due to heating from above, and implications for regional melting of Earth's directionally solidified inner core

    NASA Astrophysics Data System (ADS)

    Yu, James; Bergman, Michael I.; Huguet, Ludovic; Alboussiere, Thierry

    2015-09-01

    Superimposed on the radial solidification of Earth's inner core may be hemispherical and/or regional patches of melting at the inner-outer core boundary. Little work has been carried out on partial melting of a dendritic mushy layer due to heating from above. Here we study directional solidification, annealing, and partial melting from above of Pb-rich Sn alloy ingots. We find that partial melting from above results in convection in the mushy layer, with dense, melted Pb sinking and resolidifying at a lower height, yielding a different density profile than for those ingots that are just directionally solidified, irrespective of annealing. Partial melting from above causes a greater density deeper down and a corresponding steeper density decrease nearer the top. There is also a change in microstructure. These observations may be in accordance with inferences of east-west and perhaps smaller-scale variations in seismic properties near the top of the inner core.

  17. Separation of supercritical slab-fluids to form aqueous fluid and melt components in subduction zone magmatism.

    PubMed

    Kawamoto, Tatsuhiko; Kanzaki, Masami; Mibe, Kenji; Matsukage, Kyoko N; Ono, Shigeaki

    2012-11-13

    Subduction-zone magmatism is triggered by the addition of H(2)O-rich slab-derived components: aqueous fluid, hydrous partial melts, or supercritical fluids from the subducting slab. Geochemical analyses of island arc basalts suggest two slab-derived signatures of a melt and a fluid. These two liquids unite to a supercritical fluid under pressure and temperature conditions beyond a critical endpoint. We ascertain critical endpoints between aqueous fluids and sediment or high-Mg andesite (HMA) melts located, respectively, at 83-km and 92-km depths by using an in situ observation technique. These depths are within the mantle wedge underlying volcanic fronts, which are formed 90 to 200 km above subducting slabs. These data suggest that sediment-derived supercritical fluids, which are fed to the mantle wedge from the subducting slab, react with mantle peridotite to form HMA supercritical fluids. Such HMA supercritical fluids separate into aqueous fluids and HMA melts at 92 km depth during ascent. The aqueous fluids are fluxed into the asthenospheric mantle to form arc basalts, which are locally associated with HMAs in hot subduction zones. The separated HMA melts retain their composition in limited equilibrium with the surrounding mantle. Alternatively, they equilibrate with the surrounding mantle and change the major element chemistry to basaltic composition. However, trace element signatures of sediment-derived supercritical fluids remain more in the melt-derived magma than in the fluid-induced magma, which inherits only fluid-mobile elements from the sediment-derived supercritical fluids. Separation of slab-derived supercritical fluids into melts and aqueous fluids can elucidate the two slab-derived components observed in subduction zone magma chemistry. PMID:23112158

  18. Separation of supercritical slab-fluids to form aqueous fluid and melt components in subduction zone magmatism.

    PubMed

    Kawamoto, Tatsuhiko; Kanzaki, Masami; Mibe, Kenji; Matsukage, Kyoko N; Ono, Shigeaki

    2012-11-13

    Subduction-zone magmatism is triggered by the addition of H(2)O-rich slab-derived components: aqueous fluid, hydrous partial melts, or supercritical fluids from the subducting slab. Geochemical analyses of island arc basalts suggest two slab-derived signatures of a melt and a fluid. These two liquids unite to a supercritical fluid under pressure and temperature conditions beyond a critical endpoint. We ascertain critical endpoints between aqueous fluids and sediment or high-Mg andesite (HMA) melts located, respectively, at 83-km and 92-km depths by using an in situ observation technique. These depths are within the mantle wedge underlying volcanic fronts, which are formed 90 to 200 km above subducting slabs. These data suggest that sediment-derived supercritical fluids, which are fed to the mantle wedge from the subducting slab, react with mantle peridotite to form HMA supercritical fluids. Such HMA supercritical fluids separate into aqueous fluids and HMA melts at 92 km depth during ascent. The aqueous fluids are fluxed into the asthenospheric mantle to form arc basalts, which are locally associated with HMAs in hot subduction zones. The separated HMA melts retain their composition in limited equilibrium with the surrounding mantle. Alternatively, they equilibrate with the surrounding mantle and change the major element chemistry to basaltic composition. However, trace element signatures of sediment-derived supercritical fluids remain more in the melt-derived magma than in the fluid-induced magma, which inherits only fluid-mobile elements from the sediment-derived supercritical fluids. Separation of slab-derived supercritical fluids into melts and aqueous fluids can elucidate the two slab-derived components observed in subduction zone magma chemistry.

  19. Separation of supercritical slab-fluids to form aqueous fluid and melt components in subduction zone magmatism

    PubMed Central

    Kawamoto, Tatsuhiko; Kanzaki, Masami; Mibe, Kenji; Ono, Shigeaki

    2012-01-01

    Subduction-zone magmatism is triggered by the addition of H2O-rich slab-derived components: aqueous fluid, hydrous partial melts, or supercritical fluids from the subducting slab. Geochemical analyses of island arc basalts suggest two slab-derived signatures of a melt and a fluid. These two liquids unite to a supercritical fluid under pressure and temperature conditions beyond a critical endpoint. We ascertain critical endpoints between aqueous fluids and sediment or high-Mg andesite (HMA) melts located, respectively, at 83-km and 92-km depths by using an in situ observation technique. These depths are within the mantle wedge underlying volcanic fronts, which are formed 90 to 200 km above subducting slabs. These data suggest that sediment-derived supercritical fluids, which are fed to the mantle wedge from the subducting slab, react with mantle peridotite to form HMA supercritical fluids. Such HMA supercritical fluids separate into aqueous fluids and HMA melts at 92 km depth during ascent. The aqueous fluids are fluxed into the asthenospheric mantle to form arc basalts, which are locally associated with HMAs in hot subduction zones. The separated HMA melts retain their composition in limited equilibrium with the surrounding mantle. Alternatively, they equilibrate with the surrounding mantle and change the major element chemistry to basaltic composition. However, trace element signatures of sediment-derived supercritical fluids remain more in the melt-derived magma than in the fluid-induced magma, which inherits only fluid-mobile elements from the sediment-derived supercritical fluids. Separation of slab-derived supercritical fluids into melts and aqueous fluids can elucidate the two slab-derived components observed in subduction zone magma chemistry. PMID:23112158

  20. Partial melting of UHP calc-gneiss from the Dabie Mountains

    NASA Astrophysics Data System (ADS)

    Liu, Penglei; Wu, Yao; Liu, Qiang; Zhang, Junfeng; Zhang, Li; Jin, Zhenmin

    2014-04-01

    Exhumation melting has been proposed for the ultra-high pressure (UHP) metamorphic rocks in the Dabie Mountains based on melting experiments. We document here the first petrological and mineralogical evidence demonstrating that the UHP calc-gneisses from the Ganjialing area in the Dabie Mountains experienced partial melting during early exhumation. The assemblage of garnet, phengite (Si = 3.65 pfu), coesite, rutile and carbonate preserved in the calc-gneisses indicates a peak metamorphic condition of 692-757 °C and 4.0-4.8 GPa. Partial melting is indicated by several lines of evidence: the melting textures of phengite, the feldspar-dominated films, bands, branches, blebs and veins, the euhedral K-feldspars, the intergrowth film of plagioclase and K-feldspar, the plagioclase + biotite intergrowth after garnet and the epidote poikiloblasts. Polyphase inclusions in garnet are characterized with wedge-like offshoots and serrate outlines whereas those in epidote display negative crystal shapes, which can be best interpreted by entrapment of former melts. We propose a wet melting reaction of Phn + Q ± Na-Cpx + H2O = Bt + Pl + Grt + felsic melts, which likely took place at ca.650-800 °C and ca.1.0-2.0 GPa, to interpret the melting event in the calc-gneisses. Chemical exchanges between garnet and melts produced new garnet domains with higher almandine, spessartine, MREE, HREE and Y but lower grossular, pyrope, P, Sc, Ti, V and Zr contents. Zr-in-rutile thermometer reveals a low temperature of 620-643 °C at 5 GPa, indicating a later reset for Zr in rutile. Healed fractures are suggested to be responsible for the formation of some polyphase inclusions in garnet.

  1. Partial melting of ordinary chondrites: Lost City (H) and St. Severin (LL)

    NASA Technical Reports Server (NTRS)

    Jurewicz, Amy J. G.; Jones, John H.; Weber, Egon T.; Mittlefehldt, David W.

    1993-01-01

    Eucrites and diogenites are examples of asteroidal basalts and orthopyroxenites, respectively. As they are found intermingled in howardites, which are inferred to be regolith breccias, eucrites and diogenites are thought to be genetically related. But the details of this relationship and of their individual origins remain controversial. Work by Jurewicz et al. showed that 1170-1180 C partial melts of the (anhydrous) Murchison (CM) chondrite have major element compositions extremely similar to primitive eucrites, such as Sioux County. However, the MnO contents of these melts were about half that of Sioux County, a problem for the simple partial melting model. In addition, partial melting of Murchison could not produce diogenites, because residual pyroxenes in the Murchison experiments were too Fe- and Ca-rich and were minor phases at all but the lowest temperatures. A parent magma for diogenites needs an expanded low-calcium pyroxene field. In their partial melting study of an L6 chondrite, Kushiro and Mysen found that ordinary chondrites did have an expanded low-Ca pyroxene field over that of CV chondrites (i.e., Allende), probably because ordinary chondrites have lower Mg/Si ratios. This study expands that of both Kushiro and Mysen and Jurewicz et al. to the Lost City (H) and St. Severin (LL) chondrites at temperatures ranging from 1170 to 1325 C, at an fO2 of one log unit below the iron-wuestite buffer (IW-1).

  2. Partial melting of garnet lherzolite with water and carbon dioxide at 3 GPa using a new melt extraction technique: implications for intraplate magmatism

    NASA Astrophysics Data System (ADS)

    Baasner, Amrei; Médard, Etienne; Laporte, Didier; Hoffer, Géraldine

    2016-05-01

    The origin and source rocks of alkali-rich and SiO2-undersatured magmas in the Earth's upper mantle are still under debate. The garnet signature in rare earth element patterns of such magmas suggests a garnet-bearing source rock, which could be garnet lherzolite or garnet pyroxenite. Partial melting experiments were performed at 2.8 GPa and 1345-1445 °C in a piston-cylinder using mixtures of natural lherzolite with either 0.4 wt% H2O and 0.4 wt% CO2 or 0.7 wt% H2O and 0.7 wt% CO2. Different designs of AuPd capsules were used for melt extraction. The most successful design included a pentagonally shaped disc placed in the top part of the capsule for sufficient melt extraction. The degrees of partial melting range from 0.2 to 0.04 and decrease with decreasing temperature and volatile content. All samples contain olivine and orthopyroxene. The amounts of garnet and clinopyroxene decrease with increasing degree of partial melting until both minerals disappear from the residue. Depending on the capsule design, the melts quenched to a mixture of quench crystals and residual glass or to glass, allowing measurement of the volatile concentrations by Raman spectroscopy. The compositions of the partial melts range from basalts through picrobasalts to foidites. Compared to literature data for melting of dry lherzolites, the presence of H2O and CO2 reduces the SiO2 concentration and increases the MgO concentration of partial melts, but it has no observable effect on the enrichment of Na2O in the partial melts. The partial melts have compositions similar to natural melilitites from intraplate settings, which shows that SiO2-undersaturated intraplate magmas can be generated by melting of garnet lherzolite in the Earth's upper mantle in the presence of H2O and CO2.

  3. Partial melting of the South Qinling orogenic crust, China: Evidence from Triassic migmatites and diorites of the Foping dome

    NASA Astrophysics Data System (ADS)

    Zhang, He; Ye, Ri-Sheng; Liu, Bing-Xiang; Wang, Yan; Zhang, Yuan-Shuo; Siebel, Wolfgang; Chen, Fukun

    2016-09-01

    The Qinling orogen was ultimately formed by suturing of the South Qinling and Yangtze blocks, but the exact timing of the final amalgamation of the two blocks has not been well established so far. Partial melting of the Qinling orogenic continental crust resulted in the generation of migmatites, and such rocks may help to decipher the chronology of such event. In this paper, we report U-Pb ages, trace element, and Hf isotopic compositions of zircons from migmatites and diorite gneisses of the Foping dome, South Qinling. Zircons from migmatites form anhedral grains of variable sizes that are characterized by complex trace element compositions. Based on zircon U-Pb ages, the migmatites can be subdivided into two groups: Group 1 migmatites mainly retain Triassic zircons with U-Pb ages of 214-211 Ma and Hf model ages of ~ 1.46 Ga in core and rim domains; zircons from Group 2 migmatites record both Triassic (~ 210 Ma) and Neoproterozoic U-Pb ages, analogous to igneous rocks of the Wudang and Yaolinghe Groups exposed in South Qinling. Zircons from the diorite gneisses yield U-Pb ages of 216-210 Ma with Hf isotopic composition (TDM2 ages of ~ 1.46 Ga) similar to the migmatites. Evidence from whole-rock Nd isotopic analyses also points to a similar genesis between migmatites and diorite gneisses. It is proposed that Group 1 migmatites were derived by melting of Triassic diorites, while Group 2 migmatites were derived from Neoproterozoic igneous rocks, a major basement lithology of South Qinling. Partial melting of the orogenic crust took place at ~ 214-210 Ma, approximately consistent with the retrograde metamorphism of granulites exposed along the suture zone between the South Qinling and Yangtze blocks. We suggest that the collision of these two blocks occurred prior to ~ 215 Ma and that the Foping dome resulted from rapid collapse of an overthickened crust followed by partial melting enhanced by asthenospheric influx.

  4. The behavior of Fe3+/∑Fe during partial melting of spinel lherzolite

    NASA Astrophysics Data System (ADS)

    Gaetani, Glenn A.

    2016-07-01

    This study presents an internally consistent model for the behavior of Fe3+/∑Fe during partial melting of spinel lherzolite. The Fe3+/∑Fe ratio for olivine is calculated on the basis of point defect thermodynamics, and the oxidation states of iron in the other solid phases are calculated using Fe3+/Fe2+ distribution between olivine and orthopyroxene, clinopyroxene, or spinel. Conservation of mass is used to relate the Fe3+/Fe2+ ratio of partial melt to the concentrations of Fe3+ and Fe2+ in the initial and residual solids as a function of pressure, temperature, and oxygen fugacity. Results from isobaric batch melting calculations demonstrate that the Fe3+/∑Fe ratio of the partial melt decreases with increasing melt fraction. Conversely, the Fe3+/∑Fe ratio of the partial melt increases with increasing melt fraction during decompression batch melting. The relative oxygen fugacity of the upper mantle depends on both the oxidation state of iron and mantle potential temperature. Results from incremental decompression melting calculations in which 1% melt is produced for each 100 MPa of decompression and then removed from the residual solid indicate that relative oxygen fugacity calculated from the oxidation state of iron in basaltic glass does not represent a unique value for the oceanic upper mantle but, rather, reflects conditions in the lower portion of the melting regime. A 100 °C change in mantle potential temperature produces a change in relative oxygen fugacity of ∼0.8 log units, similar to the global range inferred from mid-ocean ridge basalt glasses. It is necessary, therefore, to compare relative oxygen fugacity calculated from basaltic glass with proxies for potential temperature before drawing conclusions on heterogeneity of the oxidation state of iron in the oceanic upper mantle. Results from model calculations also suggest that the sub-arc mantle is intrinsically more oxidizing than the oceanic mantle because it is cooler. The global correlation

  5. Are seismic wave velocities and anisotropies reliable proxies for partial melts?

    NASA Astrophysics Data System (ADS)

    Lee, Amicia; Torvela, Taija; Lloyd, Geoffrey; Walker, Andrew

    2015-04-01

    Partial melts and their segregation weaken mineral crystallographic alignment, resulting in a decrease in seismic anisotropy (AV). Furthermore, introduction of melt induces a drop in seismic wave velocities, especially for shear (Vs) but also compressional (Vp) waves, although some solid-state processes can also lead to velocity drops. Thus, decreases in AV and/or V are often used to infer the presence and even the amount of melt in both the crust and mantle, for example via the Vp/Vs ratio. However, evidence is accumulating that the relationship between melt fraction and seismic properties is not straight-forward. We consider how varying melt fraction (f) might affect crustal seismic properties. Our modelling approach is based on electron backscattered diffraction (EBSD) analysis of crystallographic preferred orientation (CPO) patterns from granulite facies sheared migmatites. The CPO data are used to model the seismic properties of rocks with different solid/melt proportions. Subsequently, melt was simulated via an isotropic elastic stiffness matrix and combined mathematically with the CPO-derived seismic properties, and seismic properties then recalculated to take into account the presence of melt. These melt models, therefore, predict changes in seismic properties at different f. The models show that low (c. f < 0.15) and high (0.7 < f < 1) values affect seismic properties much more than the 'crystal mush' part (0.1 < f < 0.7): velocities (V) and anisotropies (AV) for both low and high f drop rapidly but 'plateau' at intermediate f. Our results imply that V and, especially, AV may not be reliable proxies for the amount of crustal melt present. Seismic wave behaviour in crystal-supported (0.1 < f < 0.7) material may be controlled by the solid rather than the melt phase.

  6. High Pressure Experimental Investigation of the Interaction between Partial Melts of Eclogite and Mantle Peridotite during Upwelling

    NASA Astrophysics Data System (ADS)

    Pinter, Z.; Rosenthal, A.; Frost, D. J.; McCammon, C. A.; Höfer, H. E.; Yaxley, G. M.; Berry, A.; Woodland, A. B.; Vasilyev, P.; Pearson, G. D.

    2015-12-01

    Many mantle-derived magmas may originate through partial melting of complex, mixed mantle rocks including not only peridotite, but also oceanic crust recycled into the mantle [1,2]. There is, however, little detailed knowledge concerning how such material is produced, how it melts, the types of liquids produced and how they are extracted from the mantle. We have conducted a series of peridotite/basalt layered experiments using an average altered mid-ocean ridge basalt GA2 [3] and fertile peridotite HZ1 [4] doped with Ir to act as a redox sensor [5,6]. Experiments were performed at 3-10 GPa, 1235-1660°C, using a multi anvil apparatus. The compositions of minerals and melts were analysed using an electron microprobe. Fourier-transform infrared and Mössbauer spectroscopy were also employed to determine the concentrations of small amounts of volatiles and the Fe3+/ΣFe ratio, respectively. Experiments yielded well-crystallised heterogeneous mantle assemblages. Similar to previous studies [3,7], 'dry' eclogite starts to melt at higher depths than ambient 'dry' mantle along adiabatic paths. Highly siliceous melts produced through near-adiabatic ascent freeze into ambient peridotite, forming distinct orthopyroxene-rich reaction zones [8]. We demonstrate that impregnating partial melts of eclogite in an upwelling mantle differ in their metasomatic effects depending on the particular adiabatic path, as suggested previously [7]. Thus, melt compositions formed by subsequent re-melting of such metasomatic assemblages strongly depend on potential temperature of the adiabat [7]. [1] Hofmann et al. Treatise Geochem 2, 2.03, 61-101 (2003) [2] Sobolev et al. Science 316, 412-417 (2007) [3] Spandler et al. J Petrol 49, 771-795 (2008) [4] Green et al. Nature 467, 448-451 (2010) [5] Stagno et al. Nature 493, 84-88 (2013) [6] Stagno et al. Contrib Mineral Petrol 169:16 (2015) [7] Rosenthal et al. Sci Rep 4, 6099 (2014) [8] Yaxley & Green Schweiz Mineral Petrogr Mitt 78, 243-255 (1998)

  7. Syn-exhumation partial melting and melt segregation in the Sulu UHP terrane: Evidences from leucosome and pegmatitic vein of migmatite

    NASA Astrophysics Data System (ADS)

    Song, Yanru; Xu, Haijin; Zhang, Junfeng; Wang, Deyuan; Liu, Endong

    2014-08-01

    In order to investigate partial melting and melt evolution during exhumation of deeply subducted continental crust, we carried out a combined study on layered leucosomes and pegmatitic veins from the Weihai-Rongcheng migmatites in the Sulu ultra-high pressure (UHP) metamorphic terrane, eastern China. The leucosomes are millimetric to centimetric in thickness and mainly consists of K-feldspar + quartz + plagioclase. The pegmatitic veins emplace along the compositional layers or crosscut them and are mainly composed of K-feldspar + quartz. CL images show that most zircon grains of the leucosomes have a core-rim zoning structure, whereas zircons of the pegmatitic veins are mostly new growth grains with rarely preserved relict domains. The inherited zircon domains (ca. 750 Ma) are of a magmatic origin with zircon εHf(t) values between - 5.7 and 5.3 (mean = - 0.8 ± 1.5), suggesting that the protolith rock is a Mid-Neoproterozoic juvenile crust. The zircon overgrowth rims (223 ± 3 Ma) of the leucosomes and the new zircon grains (217 ± 2 Ma) of the pegmatitic veins formed in equilibrium with melt and are similar to magmatic zircons in terms of their CL images and trace element compositions, e.g., heavy-enriched REE patterns (i.e., very low (Gd/Lu)N ratios) with positive Ce and variably negative Eu anomalies, high Y contents and low Hf/Y ratios. Compared with the inherited protolith zircon domains, the Triassic zircon domains of the leucosomes and the pegmatitic veins have obviously high U but low Th contents, resulting in very low Th/U ratios (< 0.09). The low Th/U ratios (< 0.1) of zircons suggest that Th/U ratio cannot be used to discriminate igneous/metamorphic zircons. The zircons of the pegmatitic veins have remarkably lower Th/U ratios (0.00008-0.01, mostly < 0.006) than those of zircon rims of the leucosomes (0.006-0.09), suggesting that the melt segregation process can also result in low Th/U ratios of zircons. Calculated growth temperature for the zircon

  8. Experimental derivation of nepheline syenite and phonolite liquids by partial melting of upper mantle peridotites

    NASA Astrophysics Data System (ADS)

    Laporte, Didier; Lambart, Sarah; Schiano, Pierre; Ottolini, Luisa

    2014-10-01

    Piston-cylinder experiments were performed to characterize the composition of liquids formed at very low degrees of melting of two fertile lherzolite compositions with 430 ppm and 910 ppm K2O at 1 and 1.3 GPa. We used the microdike technique (Laporte et al., 2004) to extract the liquid phase from the partially molten peridotite, allowing us to analyze liquid compositions at degrees of melting F down to 0.9%. At 1.3 GPa, the liquid is in equilibrium with olivine + orthopyroxene + clinopyroxene + spinel in all the experiments; at 1 GPa, plagioclase is present in addition to these four mineral phases up to about 5% of melting (T≈1240 °C). Important variations of liquid compositions are observed with decreasing temperature, including strong increases in SiO2, Na2O, K2O, and Al2O3 concentrations, and decreases in MgO, FeO, and CaO concentrations. The most extreme liquid compositions are phonolites with 57% SiO2, 20-22% Al2O3, Na2O + K2O up to 14%, and concentrations of MgO, FeO, and CaO as low as 2-3%. Reversal experiments confirm that low-degree melts of a fertile lherzolite have phonolitic compositions, and pMELTS calculations show that the amount of phonolite liquid generated at 1.2 GPa increases from 0.3% in a source with 100 ppm K2O to 3% in a source with 2000 ppm K2O. The enrichment in silica and alkalis with decreasing melt fraction is coupled with an increase of the degree of melt polymerization, which has important consequences for the partitioning of minor and trace elements. Thus Ti4+ in our experiments and, by analogy with Ti4+, other highly charged cations, and rare earth elements become less incompatible near the peridotite solidus. Our study brings a strong support to the hypothesis that phonolitic lavas or their plutonic equivalents (nepheline syenites) may be produced directly by partial melting of upper mantle rock-types at moderate pressures (1-1.5 GPa), especially where large domains of the subcontinental lithospheric mantle has been enriched in

  9. Experimental partial melting of the Allende (CV) and Murchison (CM) chondrites and the origin of asteroidal basalt

    NASA Technical Reports Server (NTRS)

    Jurewicz, A. J. G.; Mittlefehldt, D. W.; Jones, J. H.

    1993-01-01

    Following the investigation of Jurewicz et al. (1991) on the composition of partial melts of eucrites and angrites, this study investigates partial melts of the Allende and Murchison chondrites and details the anhydrous phase relations of both chondrites at 1 atm, under temperatures and oxygen fugacities plausigle for the formation of basaltic meteorites. It was found that, in general, ambient oxygen fugacity exerts a strong influence on the compositions of partial melts of chondrites by controlling the amount of FeO available to the silicate system. At high f(O2), angritic magmas are produced, whereas eucritic melts are produced at low levels of f(O2).

  10. Receiver function constraints on crustal seismic velocities and partial melting in the Red Sea Rift, Central Afar

    NASA Astrophysics Data System (ADS)

    Reed, C. A.; Almadani, S.; Gao, S. S.; Elsheikh, A. A.; Cherie, S.; Thurmond, A. K.; Liu, K. H.

    2013-12-01

    The Afar Depression is currently a unique locale for the investigation of crustal and mantle processes involved in the transition from continental to oceanic rifting. To provide high-quality images of the crust and upper mantle beneath the Red Sea Rift in Central Afar, we deployed an array of 18 broadband seismic stations in 2010 and 2011. Here we report receiver function stacking results to investigate crustal properties of this presumably incipient oceanic rift. Stacking of approximately 2200 radial receiver functions along the ~200 km long array reveals an average crustal thickness of 22 km, ranging from nearly 18 km within the Red Sea Rift axis to approximately 30 km within the overlap zone between the Red Sea and Gulf of Aden rift axes. The resulting anomalously high Vp/Vs ratios systematically decrease toward the northeast, ranging from 2.40 southwest of the Tendaho Graben to 1.85 within the overlap zone. We utilize theoretical Vp and melt fraction relationships to constrain a highly reduced average crustal P-velocity of 5.0 km/s within the rift axis, which is characterized by a melt percentage of ~11% confined primarily to the lower crust while the overlap zone contains relatively minor quantities of partial melt. An observed asymmetric distribution of high Vp/Vs values within the Tendaho Graben, as well as regionally maximum values on the southwestern rift flank, suggest crustal magmas either delivered from off-axis subcrustal magma chambers or as material present as residuum from the Red Sea Rift axis migration. Comparisons of these crustal properties beneath the Red Sea Rift and those found beneath mature mid-ocean ridges suggest the locus of extensional strain within the Central Afar is currently diffuse and in the process of localizing toward the Tendaho Graben accompanying the northeastward migration of the Afar Triple Junction.

  11. Formation of layered and schlieren migmatites by partial melting at Aspen Basin, New Mexico

    SciTech Connect

    Metcalf, R.V.

    1985-01-01

    Although several recent studies of layered migmatites have suggested that they originated by subsolidus differentiation, both layered and schlieren-type migmatites at Aspen Basin formed by partial melting. Proterozoic supracrustal rocks at Aspen Basin were intruded by a suite of calc-alkalic diorite, tonalite and granite, intensely deformed, then intruded by younger aplite and granite. The supra-crustal rocks consist of migmatitic, sillimanite-grade metagreywacke, felsic gneiss and amphibolite. Within the metagreywackes, concordant coarse-grained neosomes (leucosomes + melanosomes) are interlayered with fine-grained grey gneiss. These layered migmatites grade toward schlieren-type migamtites at deeper levels, where the proportions of leucocratic material and degree of discordance increase. Two pieces of evidence demonstrate that leucosomes crystallized from melts. Partial melting is favored over injection on the basis of major and trace element chemical analyses. None of the plutonic units have appropriate composition to serve as the migmatite source, and the chemical and mineralogical compositions of leucosomes and leucogranites correlate to their metamorphic host rock, implying local derivation. The transition from layered to schlieren migmatites is marked by an increase in Rb, Rb/Sr, and K/sub 2/O/Na/sub 2/O within the leucosomes and leucogranites, and apparently represents an increase in the degree of partial melting.

  12. Effect of partial melting on small scale convection atop a mantle plume

    NASA Astrophysics Data System (ADS)

    Agrusta, R.; Arcay, D.; Tommasi, A.; Gonzalez, A.

    2014-12-01

    A lithospheric plate passing atop a mantle plume is likely to be thermally thinned or "rejuvenated". Geophysical data on the lithosphere-asthenosphere boundary (LAB) depth beneath active hotspots partly validate this prediction, but there is a large variation of the LAB upwelling estimated from different methods. Numerical simulations of plume-lithosphere interactions show that the development of small-scale convection (SSC) in the plume pancake spreading out along the base of the lithosphere is a mechanism able to rejuvenate the lithosphere, even for a fast-moving plate. The triggering of SSC has been shown to depend on the rheological behaviour of the unstable layer underlying the stagnant upper part of the thermal boundary layer (TBL), but the stability of the this layer may also be affected by partial melting.We analyze, using a 2D petrological-thermo-mechanical numerical model, the influence of partial melting on the dynamics of time-dependent SSC instabilities and the resulting rejuvenation of a lithosphere passing atop a mantle plume. These models show a complex behavior, with either an acceleration, no change or a slight decceleration of the SSC onset, due to the competing effects of the latent heat of melting, which cools the plume material, and of the buoyancy increase associated with melting, among which the dominant effect is the depletion in heavy elements of the solid fraction. The viscosity reduction, though significant (up to 2 orders of magnitude) is too localized to affect the SSC dynamics. Despite the presence of partial melting, the mechanical lithosphere erosion in not enhanced significantly relatively to melt-free models.

  13. Evidence of melting, melt percolation and deformation in a supra-subduction zone (Marum ophiolite complex, Papua New Guinea)

    NASA Astrophysics Data System (ADS)

    Kaczmarek, Mary-Alix; Jonda, Leo; Davies, Hugh L.

    2015-08-01

    New geochemical and microstructural data are presented for a suite of ultramafic rocks from the Marum ophiolite in Papua New Guinea. Our results describe a piece of most depleted mantle made essentially of dunite and harzburgite showing compositions of supra-subduction zone peridotite. Strong olivine crystallographic preferred orientations (CPOs) in dunite and harzburgite inferred the activation of both (001)[100] and (010)[100] slip systems, which are activated at high-temperature and low-stress conditions. Clinopyroxene and orthopyroxene CPOs inferred the activation of (100)[001] and (010)[001] slip systems, which are common for pyroxenes deformed at high temperature. This plastic deformation is interpreted to have developed during the formation of the Marum ophiolite, prior to melt percolation. The orientation of the foliation and olivine [100] slip directions sub-parallel to the subduction zone indicates that mantle flow was parallel to the trench pointing a fast polarisation direction parallel to the arc. This provides new evidence that fast polarisation direction parallel to the arc could be caused by anisotropic peridotite and not by olivine [001] slip. After its formation, Marum ophiolite has been fertilised by diffuse crystallisation of a low proportion of clinopyroxene (1-2 %) (P1) and formation of cm-scale ol-clinopyroxenite and ol-websterite veins cross-cutting the foliation (P2). This percolating melt shows silica-rich magnesian affinities (boninite-like) related to supra-subduction zone in a young fore-arc environment. The peridotite has also been percolated by a melt with more tholeiite affinities precipitating plagioclase-rich wehrlite and thin gabbroic veins (P3); these are interpreted to form after the boninitic event. The small proportion of newly crystallised pyroxene in the dunite shows similar orientation of crystallographic axes to the host dunite (<100>ol parallel to <001>cpx-opx). In contrast, the pyroxenes in ol-clinopyroxenite, ol

  14. The effect of water on the partial melting of peridotite at 3 GPa.

    NASA Astrophysics Data System (ADS)

    Tenner, T. J.; Hirschmann, M. M.

    2008-12-01

    We have investigated the influence of water on partial melting of fertile garnet peridotite by performing experiments with a hydrated synthetic peridotite at 3 GPa. The starting material consists of a synthetic KLB-1 peridotite analog mixed in varying ratios with a synthetic hydrous olivine composition (Mg# of 83 + 10% H2O) to produce starting materials with 1, 1.5, and 2.5 wt.% H2O. Experiments were performed in a Walker-style multianvil apparatus in AuPd and Fe-presaturated AuPd capsules at 1250-1475 °C. Resulting charges consist of liquid+ol+opx±cpx±gt and all phase compositions were analyzed by electron microprobe. Though liquids quench to glass in some experiments, they are more commonly preserved as 20×20 to 100×300 micron pools of heterogeneous quench crystals. For these, extensive analyses are required to reconstruct partial melt compositions. Consequently, we perform ~150 individual microprobe analyses on the quench for each experiment and accept only those analyses (typically 10 to 40 analyses) that yield olivine-liquid Fe-Mg KD values between 0.30 and 0.35. Inferred equilibrium liquid compositions range from basaltic at high temperature to nephelinitic at low temperature. Melt fractions, F, are calculated by mass balance and range from 0.12 to 0.31. As an index of the influence of H2O on melting, we calculate ΔT, which is the difference between the temperature of the experiment and that required to generate that melt fraction under dry conditions, which are inferred from the experiments of Walter (1998) and from those of Davis and Hirschmann (in prep). For experiments in AuPd capsules, small corrections for iron loss are also required. Calculated values of ΔT as a function of dissolved H2O concentration are inferred by mass balance, and conservation of H2O during experiments can be investigated by FTIR on glassy quench products. The ΔT vs. H2O in the melt trend shows excellent agreement with previous determinations at lower pressure. This simple

  15. Experimental Measurement of Frozen and Partially Melted Water Droplet Impact Dynamics

    NASA Technical Reports Server (NTRS)

    Palacios, Jose; Yan, Sihong; Tan, Jason; Kreeger, Richard E.

    2014-01-01

    High-speed video of single frozen water droplets impacting a surface was acquired. The droplets diameter ranged from 0.4 mm to 0.9 mm and impacted at velocities ranging from 140 m/sec to 309 m/sec. The techniques used to freeze the droplets and launch the particles against the surfaces is described in this paper. High-speed video was used to quantify the ice accretion area to the surface for varying impact angles (30 deg, 45 deg, 60 deg), impacting velocities, and break-up angles. An oxygen /acetylene cross-flow flame used to ensure partial melting of the traveling frozen droplets is also discussed. A linear relationship between impact angle and ice accretion is identified for fully frozen particles. The slope of the relationship is affected by impact speed. Perpendicular impacts, i.e. 30 deg, exhibited small differences in ice accretion for varying velocities, while an increase of 60% in velocity from 161 m/sec to 259 m/sec, provided an increase on ice accretion area of 96% at an impact angle of 60 deg. The increase accretion area highlights the importance of impact angle and velocity on the ice accretion process of ice crystals. It was experimentally observed that partial melting was not required for ice accretion at the tested velocities when high impact angles were used (45 and 60 deg). Partially melted droplets doubled the ice accretion areas on the impacting surface when 0.0023 Joules were applied to the particle. The partially melted state of the droplets and a method to quantify the percentage increase in ice accretion area is also described in the paper.

  16. Electrical conductivity during incipient melting in the oceanic low-velocity zone.

    PubMed

    Sifré, David; Gardés, Emmanuel; Massuyeau, Malcolm; Hashim, Leila; Hier-Majumder, Saswata; Gaillard, Fabrice

    2014-05-01

    The low-viscosity layer in the upper mantle, the asthenosphere, is a requirement for plate tectonics. The seismic low velocities and the high electrical conductivities of the asthenosphere are attributed either to subsolidus, water-related defects in olivine minerals or to a few volume per cent of partial melt, but these two interpretations have two shortcomings. First, the amount of water stored in olivine is not expected to be higher than 50 parts per million owing to partitioning with other mantle phases (including pargasite amphibole at moderate temperatures) and partial melting at high temperatures. Second, elevated melt volume fractions are impeded by the temperatures prevailing in the asthenosphere, which are too low, and by the melt mobility, which is high and can lead to gravitational segregation. Here we determine the electrical conductivity of carbon-dioxide-rich and water-rich melts, typically produced at the onset of mantle melting. Electrical conductivity increases modestly with moderate amounts of water and carbon dioxide, but it increases drastically once the carbon dioxide content exceeds six weight per cent in the melt. Incipient melts, long-expected to prevail in the asthenosphere, can therefore produce high electrical conductivities there. Taking into account variable degrees of depletion of the mantle in water and carbon dioxide, and their effect on the petrology of incipient melting, we calculated conductivity profiles across the asthenosphere for various tectonic plate ages. Several electrical discontinuities are predicted and match geophysical observations in a consistent petrological and geochemical framework. In moderately aged plates (more than five million years old), incipient melts probably trigger both the seismic low velocities and the high electrical conductivities in the upper part of the asthenosphere, whereas in young plates, where seamount volcanism occurs, a higher degree of melting is expected.

  17. Electrical conductivity during incipient melting in the oceanic low-velocity zone.

    PubMed

    Sifré, David; Gardés, Emmanuel; Massuyeau, Malcolm; Hashim, Leila; Hier-Majumder, Saswata; Gaillard, Fabrice

    2014-05-01

    The low-viscosity layer in the upper mantle, the asthenosphere, is a requirement for plate tectonics. The seismic low velocities and the high electrical conductivities of the asthenosphere are attributed either to subsolidus, water-related defects in olivine minerals or to a few volume per cent of partial melt, but these two interpretations have two shortcomings. First, the amount of water stored in olivine is not expected to be higher than 50 parts per million owing to partitioning with other mantle phases (including pargasite amphibole at moderate temperatures) and partial melting at high temperatures. Second, elevated melt volume fractions are impeded by the temperatures prevailing in the asthenosphere, which are too low, and by the melt mobility, which is high and can lead to gravitational segregation. Here we determine the electrical conductivity of carbon-dioxide-rich and water-rich melts, typically produced at the onset of mantle melting. Electrical conductivity increases modestly with moderate amounts of water and carbon dioxide, but it increases drastically once the carbon dioxide content exceeds six weight per cent in the melt. Incipient melts, long-expected to prevail in the asthenosphere, can therefore produce high electrical conductivities there. Taking into account variable degrees of depletion of the mantle in water and carbon dioxide, and their effect on the petrology of incipient melting, we calculated conductivity profiles across the asthenosphere for various tectonic plate ages. Several electrical discontinuities are predicted and match geophysical observations in a consistent petrological and geochemical framework. In moderately aged plates (more than five million years old), incipient melts probably trigger both the seismic low velocities and the high electrical conductivities in the upper part of the asthenosphere, whereas in young plates, where seamount volcanism occurs, a higher degree of melting is expected. PMID:24784219

  18. The electrical conductivity during incipient melting in the oceanic low velocity zone

    PubMed Central

    Sifré, David; Gardés, Emmanuel; Massuyeau, Malcolm; Hashim, Leila; Hier-Majumder, Saswata; Gaillard, Fabrice

    2014-01-01

    A low viscosity layer in the upper mantle, the Asthenosphere, is a requirement for plate tectonics1. The seismic low velocities and the high electrical conductivities of the Asthenosphere are attributed either to sub-solidus water-related defects in olivine minerals2-4 or to a few volume percents of partial melt5-8 but these two interpretations have shortcomings: (1) The amount of H2O stored in olivine is not expected to be higher than 50 ppm due to partitioning with other mantle phases9, including pargasite amphibole at moderate temperatures10, and partial melting at high temperatures9; (2) elevated melt volume fractions are impeded by the too cold temperatures prevailing in the Asthenosphere and by the high melt mobility that can lead to gravitational segregation11,12. Here we determined the electrical conductivity of CO2-H2O-rich melts, typically produced at the onset of mantle melting. Electrical conductivity modestly increases with moderate amounts of H2O and CO2 but it dramatically increases as CO2 content exceeds 6 wt% in the melt. Incipient melts, long-expected to prevail in the asthenosphere10,13-15, can therefore trigger its high electrical conductivities. Considering depleted and enriched mantle abundances in H2O and CO2 and their effect on the petrology of incipient melting, we calculated conductivity profiles across the Asthenosphere for various plate ages. Several electrical discontinuities are predicted and match geophysical observations in a consistent petrological and geochemical framework. In moderately aged plates (>5Ma), incipient melts most likely trigger both the seismic low velocities and the high electrical conductivities in the upper part of the asthenosphere, whereas for young plates4, where seamount volcanism occurs6, higher degree of melting is expected. PMID:24784219

  19. Evidence of melting, melt percolation and deformation in a supra-subduction zone (Marum ophiolite complex - Papua New Guinea)

    NASA Astrophysics Data System (ADS)

    Kaczmarek, M. A.; Jonda, L.; Davies, H. L.

    2015-12-01

    New geochemical and microstructural data from the Marum ophiolite in Papua New Guinea describe a piece of most depleted mantle made essentially of dunite and harzburgite showing compositions of supra-subduction zone (SSZ) peridotite. Strong olivine crystallographic preferred orientations (CPO) in dunite and harzburgite inferred the activation of both (001)[100] and (010)[100] slip systems. Clinopyroxene and orthopyroxene CPOs inferred the activation of (100)[001] and (010)[001] slip systems. This plastic deformation is interpreted to have developed at high temperature during the formation of the Marum ophiolite, prior to melt percolation. The orientation of the foliation and olivine [100] slip directions sub-parallel to the subduction zone indicates that mantle flow was parallel to the trench pointing a fast polarization direction parallel to the arc. Marum depleted mantle has been fertilised by diffuse crystallisation of a low proportion of clinopyroxene (1-2%) in the dunite and formation of cm-scale ol-clinopyroxenite and ol-websterite veins cross-cutting the foliation. This percolating melt shows silica-rich magnesian affinities (boninite-like) related to supra-subduction zone in a young fore-arc environment. The peridotite has also been percolated by a melt with more tholeiite affinities precipitating plagioclase-rich wehrlite and thin gabbroic veins; these are interpreted to form after the boninitic event. The small proportion of newly crystallized pyroxene distributed in the dunite shows similar orientation of crystallographic axes to the host dunite (<100>ol parallel to <001>cpx-opx). In contrast, the pyroxenes in ol-clinopyroxenite, ol-websterite and the thin gabbroic veins in the wehrlite, record their own orientation with <001> axes at 45 to 60˚ to olivine <100> axes. For low melt proportion, such as crystallization of pyroxenes in the dunite, the crystallization is governed by epitaxial growth, and when the proportion of melt is higher the newly formed

  20. Partial melting and the efficiency of mantle outgasing in one-plate planets

    NASA Astrophysics Data System (ADS)

    Plesa, Ana-Catalina; Breuer, Doris

    2013-04-01

    The generation of partial melting can have a major impact on the thermo-chemical evolution of a terrestrial body by the depletion of the mantle material in incompatible elements such as radioactive elements and volatiles, crust formation and volcanic outgassing. During some period in the thermal history of a terrestrial planet, the temperature in regions of the upper mantle, either below tectonic plates or a stagnant lid, rises above the solidus - the temperature at which the mineral with the lowest melting temperature among those that form the silicate mantle mixture starts to melt. The melt than rises toward the surface, forms the crust, and releases volatiles into the atmosphere. In case of one-plate (stagnant lid) planets the thickness of the present-day crust can 'tell' us already about the efficiency of mantle melting and mantle degassing - the thicker the crust the more mantle material experienced melting and thus the more efficient can be the outgassing. However, it has been shown with parameterized convection models [1] but also 2-3D convection models [2] that crustal delamination is a common process in one-plate planets. Crustal delamination allows that possibly much more crust is produced during the entire evolution (and thus more mantle material experienced differentiation) than what is observed today, implying also more efficient outgassing than expected. Crustal delamination is therefore a process that may help to generate a substantial planetary atmosphere. In the present work we investigate the influence of partial melt on mantle dynamics and the volcanic outgassing of one-plate planets using the mantle convection code GAIA [3] in a 2D cylindrical geometry. We consider the depletion of the mantle, redistribution of radioactive heat sources between mantle and crust, as well as mantle dehydration and volcanic outgassing [4]. When melt is extracted to form the crust, the mantle material left behind is more buoyant than its parent material and depleted

  1. Partial melting in one-plate planets: Implications for thermo-chemical and atmospheric evolution

    NASA Astrophysics Data System (ADS)

    Plesa, A.-C.; Breuer, D.

    2014-08-01

    In the present work, we investigate the influence of partial melting on mantle dynamics, crustal formation, and volcanic outgassing of a one-plate planet using a 2D mantle convection code. When melt is extracted to form crust, the mantle material left behind is more buoyant than its parent material and depleted in radioactive heat sources. The extracted heat-producing elements are then enriched in the crust, which also has an insulating effect due to its lower thermal conductivity compared to the mantle. In addition, partial melting can influence the mantle rheology through the dehydration (water depletion) of the mantle material by volcanic outgassing. As a consequence, the viscosity of water-depleted regions increases more than two orders of magnitude compared to water-saturated rocks resulting in slower cooling rates. The most important parameter influencing the thermo-chemical evolution is the assumed density difference between the primitive and the depleted mantle material (i.e., between peridotite and harzburgite). With small or negligible values of compositional buoyancy, crustal formation including crustal delamination is very efficient, also resulting in efficient processing and degassing of the mantle. The convecting mantle below the stagnant lid depletes continuously with time. In contrast, with increasing compositional buoyancy, crustal formation and mantle degassing are strongly suppressed although partial melting is substantially prolonged in the thermal evolution. The crust shows strong lateral variations in thickness, and crustal delamination is reduced and occurs only locally. Furthermore, two to four different mantle reservoirs can form depending on the initial temperature distribution. Two of these reservoirs can be sustained during the entire evolution - a scenario possibly valid for Mars as it may explain the isotope characteristic of the Martian meteorites.

  2. Hydrous partial melting in the lower crust of the Oman ophiolite

    NASA Astrophysics Data System (ADS)

    Boudier, F. I.; Koepke, J.; Nicolas, A. J.

    2004-12-01

    Series of water-saturated melting experiments have been performed on natural gabbros between 900° and 1000°C, at crustal pressure up to 200MPa (Koepke et al., 2004), that put new constraints on the composition of melt and residual crystals at increasing temperature and melt fraction produced. In the gabbro section of the Oman ophiolite, the development of high-T secondary parageneses is ubiquist, represented by orthopyroxene+pargasite rims within contact between olivine and plagioclase, while clinopyroxene is replaced by pargasite. The reference to the experimental results, and isotopic tracing (Bosch et al., 2004) lead to interpret these reactions as representing initiation of hydrous partial melting by fluids circulating at grain boundaries. The inferred mechanism allowing supercritical water to penetrate the deep gabbro section is a strong anisotropy of thermal compression inducing microcracking in the cooling lower gabbros (Nicolas et al., 2003). In the Oman gabbros, another important petrologic feature is the local occurrence, in the deeper section, of large amounts of orthopyroxene bearing gabbros either interlayered with olivine gabbros or intrusive as pegmatitic patches, in association with wehrlites, or mixed with pargasitic gabbros. The corresponding upper levels are rich in dioritic or trondjemitic dikes. These occurrences are restricted to localized areas that coincide with tips and segments limits as deduced from the detailed mapping along the NW-SE paleospreading axis. The origin of these parageneses as products of hydrous melting of the gabbros, at various melt fraction, is explored by reference to the experimental data. Koepke, J., Feig, S.T., Snow, J., Freise, M., 2004. Contrib. Mineral. Petrol. 146, 414-432. Bosch, D.et al., 2004, J. Petrology, 45, 1181-1208. Nicolas, A., Mainprice, D., Boudier, F., 2003, J. Geophys. Res. 108 (B8) 2371.

  3. Breeding bird response to partially harvested riparian management zones

    USGS Publications Warehouse

    Chizinski, Christopher J.; Peterson, Anna; Hanowski, JoAnn; Blinn, Charles R.; Vondracek, Bruce C.; Niemi, Gerald

    2011-01-01

    We compared avian communities among three timber harvesting treatments in 45-m wide even-age riparian management zones (RMZs) placed between upland clearcuts and along one side of first- or second-order streams in northern Minnesota, USA. The RMZs had three treatments: (1) unharvested, (2) intermediate residual basal area (RBA) (targeted goal 11.5 m2/ha, realized 16.0 m2/ha), and (3) low RBA (targeted goal 5.7 m2/ha, realized 8.7 m2/ha). Surveys were conducted one year pre-harvest and three consecutive years post-harvest. There was no change in species richness, diversity, or total abundance associated with harvest but there were shifts in the types of birds within the community. In particular, White-throated Sparrows (Zonotrichia albicollis) and Chestnut-sided Warblers (Dendroica pensylvanica) increased while Ovenbirds (Seiurus aurocapilla) and Red-eyed Vireos (Vireo olivaceus) decreased. The decline of avian species associated with mature forest in the partially harvested treatments relative to controls indicates that maintaining an unharvested RMZ adjacent to an upland harvest may aid in maintaining avian species associated mature forest in Minnesota for at least three years post-harvest. However, our observations do not reflect reproductive success, which is an area for future research.

  4. Contrasting Ti Zoning Patterns in Quartz Phenocrysts from the Bishop and Fish Canyon Tuffs: An Expression of Volatile Composition in Recharge Melts

    NASA Astrophysics Data System (ADS)

    Wark, D. A.; Bachmann, O.

    2005-12-01

    Mafic recharge is increasingly recognized as playing an important role in the thermal and chemical evolution of silicic magma systems. Even in the absence of direct interaction between mafic and silicic magmas, volatiles released from recharge melts may be effective agents of heat exchange ("gas sparging" of Bachmann and Bergantz, 2003). These volatiles will also variably affect - depending on their abundance and composition - phase relations and physical properties of the overlying silicic magma. Addition of H2O to rhyolite melt should decrease solidus temperatures and melt viscosity; addition of CO2-rich bubbles (into which H2O will migrate from the melt) will have the opposite effects. We interpret differences in quartz zoning patterns from the Bishop and Fish Canyon Tuffs - each of which has a near-eutectic, rhyolitic melt composition - to reflect differences in the composition of volatiles added by recharge melts. Late-erupted Bishop Tuff contains phenocrysts of quartz that are reversely zoned with respect to Ti content: low-Ti cores (~40-50 ppm) are separated from high-Ti rims (80-100 ppm) by a sharp boundary that appears to be a dissolution feature. This pattern is best explained by recharge involving CO2-rich basalts typical of the region. Quartz that originally grew at 740°C partially dissolved due to heating and was later reprecipitated at the higher temperatures (780-800°C) of the CO2-elevated solidus. In contrast, Fish Canyon quartz is strongly resorbed, with variable Ti contents (90-120 ppm) but no systematic zoning. Partial dissolution of quartz without growth of high-Ti rims can be explained by the addition of heat and H2O-rich volatiles (which lowered the solidus temperature) released from recharge melts like those extruded after Fish Canyon eruption (the Huerto Andesite).

  5. Equivalence of equations describing trace element distribution during equilibrium partial melting

    NASA Technical Reports Server (NTRS)

    Consolmagno, G. J.; Drake, M. J.

    1976-01-01

    It is shown that four equations used for calculating the evolution of trace-element abundances during equilibrium partial melting are mathematically equivalent. The equations include those of Hertogen and Gijbels (1976), Shaw (1970), Schilling (1971), and O'Nions and Clarke (1972). The general form to which all these equations reduce is presented, and an analysis is performed to demonstrate their mathematical equivalence. It is noted that the utility of the general equation flows from the nature of equilibrium (i.e., the final state is independent of the path by which that state is attained).

  6. Trace Elements in Basalts From the Siqueiros Fracture Zone: Implications for Melt Migration Models

    NASA Astrophysics Data System (ADS)

    Pickle, R. C.; Forsyth, D. W.; Saal, A. E.; Nagle, A. N.; Perfit, M. R.

    2008-12-01

    Incompatible trace element (ITE) ratios in MORB from a variety of locations may provide insights into the melt migration process by constraining aggregated melt compositions predicted by mantle melting and flow models. By using actual plate geometries to create a 3-D thermodynamic mantle model, melt volumes and compositions at all depths and locations may be calculated and binned into cubes using the pHMELTS algorithm [Asimow et al., 2004]. These melts can be traced from each cube to the surface assuming several migration models, including a simplified pressure gradient model and one in which melt is guided upwards by a low permeability compacted layer. The ITE ratios of all melts arriving at the surface are summed, averaged, and compared to those of the actual sample compositions from the various MOR locales. The Siqueiros fracture zone at 8° 20' N on the East Pacific Rise (EPR) comprises 4 intra-transform spreading centers (ITSCs) across 140 km of offset between two longer spreading ridges, and is an excellent study region for several reasons. First, an abundance of MORB data is readily available, and the samples retrieved from ITSCs are unlikely to be aggregated in a long-lived magma chamber or affected by along-axis transport, so they represent melts extracted locally from the mantle. Additionally, samples at Siqueiros span a compositional range from depleted to normal MORB within the fracture zone yet have similar isotopic compositions to samples collected from the 9-10° EPR. This minimizes the effect of assuming a uniform source composition in our melting model despite a heterogeneous mantle, allowing us to consistently compare the actual lava composition with that predicted by our model. Finally, it has been demonstrated with preliminary migration models that incipient melts generated directly below an ITSC may not necessarily erupt at that ITSC but migrate laterally towards a nearby ridge due to enhanced pressure gradients. The close proximity of the

  7. Probing the atomic structure of basaltic melts generated by partial melting of upper mantle peridotite (KLB-1): Insights from high-resolution solid-state NMR study

    NASA Astrophysics Data System (ADS)

    Park, S. Y.; Lee, S. K.

    2015-12-01

    Probing the structural disorder in multi-component silicate glasses and melts with varying composition is essential to reveal the change of macroscopic properties in natural silicate melts. While a number of NMR studies for the structure of multi-component silicate glasses and melts including basaltic and andesitic glasses have been reported (e.g., Park and Lee, Geochim. Cosmochim. Acta, 2012, 80, 125; Park and Lee, Geochim. Cosmochim. Acta, 2014, 26, 42), many challenges still remain. The composition of multi-component basaltic melts vary with temperature, pressure, and melt fraction (Kushiro, Annu. Rev. Earth Planet. Sci., 2001, 71, 107). Especially, the eutectic point (the composition of first melt) of nepheline-forsterite-quartz (the simplest model of basaltic melts) moves with pressure from silica-saturated to highly undersaturated and alkaline melts. The composition of basaltic melts generated by partial melting of upper mantle peridotite (KLB-1, the xenolith from Kilbourne Hole) also vary with pressure. In this study we report experimental results for the effects of composition on the atomic structure of Na2O-MgO-Al2O3-SiO2 (NMAS) glasses in nepheline (NaAlSiO4)-forsterite (Mg2SiO4)-quartz (SiO2) eutectic composition and basaltic glasses generated by partial melting of upper mantle peridotite (KLB-1) using high-resolution multi-nuclear solid-state NMR. The Al-27 3QMAS (triple quantum magic angle spinning) NMR spectra of NMAS glasses in nepheline-forsterite-quartz eutectic composition show only [4]Al. The Al-27 3QMAS NMR spectra of KLB-1 basaltic glasses show mostly [4]Al and a non-negligible fraction of [5]Al. The fraction of [5]Al, the degree of configurational disorder, increases from 0 at XMgO [MgO/(MgO+Al2O3)]=0.55 to ~3% at XMgO=0.79 in KLB-1 basaltic glasses while only [4]Al are observed in nepheline-forsterite-quartz eutectic composition. The current experimental results provide that the fraction of [5]Al abruptly increases by the effect of

  8. Experimental Spinel Standards for Ferric Iron (Fe3+) Determination During Peridotite Partial Melting

    NASA Astrophysics Data System (ADS)

    Wenz, M. D.; Sorbadere, F.; Rosenthal, A.; Frost, D. J.; McCammon, C. A.

    2014-12-01

    The presence of ferric iron (Fe3+) in the mantle plays a significant role in the oxygen fugacity (fO2) of the Earth's interior. This has a wide range of implications for Earth related processes ranging from the composition of the atmosphere to magmatic phase relations during melting and crystallization processes [1]. A major source of Earth's mantle magmas is spinel peridotite. Despite its low abundance, spinel (Fe3+/ƩFe = 15-34%, [2]) is the main contributor of Fe3+to the melt upon partial melting. Analyses of Fe3+ on small areas of spinel and melt are required to study the Fe3+ behavior during partial melting of spinel peridotite. Fe K-edge X-ray Absorption Near Edge Structure (XANES) combines both high precision and small beam size, but requires standards with a wide range of Fe3+ content to obtain good calibration. Glasses with varying Fe3+ content are easily synthesized [3, 4]. Spinel, however, presents a challenge for experimental standards due to the low diffusion of Cr and Al preventing compositional homogeneity. Natural spinel standards are often used, but only cover a narrow Fe3+ range. Thus, there is a need for better experimental spinel standards over a wider range of fO2. Our study involves making experimental mantle spinels with variable Fe3+ content. We used a sol-gel auto-combustion method to synthesize our starting material [5]. FMQ-2, FMQ+0, and air fO2 conditions were established using a gas mixing furnace. Piston cylinder experiments were performed at 1.5GPa, and 1310 -1370°C to obtain solid material for XANES. To maintain distinct oxidizing conditions, three capsules were used: graphite for reduced, Re for intermediate and AuPd for oxidized conditions. The spinels were analyzed by Mössbauer spectroscopy. Fe3+/ƩFe ranged from 0.3 to 0.6. These values are consistent with the Fe edge position obtained using XANES analyses, between 7130 and 7132 eV, respectively. Our spinels are thus suitable standards for Fe3+ measurements in peridotite

  9. To the origin of Icelandic rhyolites: insights from partially melted leucocratic xenoliths

    NASA Astrophysics Data System (ADS)

    Gurenko, Andrey A.; Bindeman, Ilya N.; Sigurdsson, Ingvar A.

    2015-05-01

    We have studied glass-bearing leucocratic (granitic to Qz-monzonitic) crustal xenoliths from the Tindfjöll Pleistocene volcanic complex, SW Iceland. The xenoliths consist of strongly resorbed relicts of anorthitic plagioclase, K-rich feldspar and rounded quartz in colorless through pale to dark-brown interstitial glass. Spongy clinopyroxene and/or rounded or elongated crystals of orthopyroxene are in subordinate amount. Magnetite, ilmenite, zircon, apatite, allanite and/or chevkinite are accessory minerals. The xenoliths more likely are relicts of earlier-formed, partially melted Si-rich rocks or quartz-feldspar-rich crystal segregations, which suffered latter interaction with hotter and more primitive magma(s). Icelandic lavas are typically low in δ 18O compared to mantle-derived, "MORB"-like rocks (~5.6 ± 0.2 ‰), likely due to their interaction with, or contamination by, the upper-crustal rocks affected by rain and glacial melt waters. Surprisingly, many quartz and feldspar crystals and associated colorless to light-colored interstitial glasses of the studied xenoliths are not low but high in δ 18O (5.1-7.2 ‰, excluding three dark-brown glasses of 4-5 ‰). The xenoliths contain abundant, low- to high- δ 18O (2.4-6.3 ‰) young zircons (U-Pb age 0.2-0.27 ± 0.03 Ma; U-Th age 0.16 ± 0.07 Ma), most of them in oxygen isotope equilibrium with interstitial glasses. The δ 18O values >5.6 ‰ recorded in the coexisting zircon, quartz, feldspar and colorless interstitial glass suggest crystallization from melts produced by fusion of crustal rocks altered by seawater, also reflecting multiple melting and crystallization events. This suggests that "normal"- δ 18O silicic magmas may not be ultimately produced by crystallization of mafic, basaltic magmas. Instead, our new single-crystal laser fluorination and ion microprobe O-isotope data suggest addition of diverse partial crustal melts, probably originated from variously altered and preconditioned crust.

  10. Origins of ultralow velocity zones through slab-derived metallic melt

    NASA Astrophysics Data System (ADS)

    Liu, Jiachao; Li, Jie; Hrubiak, Rostislav; Smith, Jesse S.

    2016-05-01

    Understanding the ultralow velocity zones (ULVZs) places constraints on the chemical composition and thermal structure of deep Earth and provides critical information on the dynamics of large-scale mantle convection, but their origin has remained enigmatic for decades. Recent studies suggest that metallic iron and carbon are produced in subducted slabs when they sink beyond a depth of 250 km. Here we show that the eutectic melting curve of the iron-carbon system crosses the current geotherm near Earth’s core-mantle boundary, suggesting that dense metallic melt may form in the lowermost mantle. If concentrated into isolated patches, such melt could produce the seismically observed density and velocity features of ULVZs. Depending on the wetting behavior of the metallic melt, the resultant ULVZs may be short-lived domains that are replenished or regenerated through subduction, or long-lasting regions containing both metallic and silicate melts. Slab-derived metallic melt may produce another type of ULVZ that escapes core sequestration by reacting with the mantle to form iron-rich postbridgmanite or ferropericlase. The hypotheses connect peculiar features near Earth's core-mantle boundary to subduction of the oceanic lithosphere through the deep carbon cycle.

  11. Origins of ultralow velocity zones through slab-derived metallic melt.

    PubMed

    Liu, Jiachao; Li, Jie; Hrubiak, Rostislav; Smith, Jesse S

    2016-05-17

    Understanding the ultralow velocity zones (ULVZs) places constraints on the chemical composition and thermal structure of deep Earth and provides critical information on the dynamics of large-scale mantle convection, but their origin has remained enigmatic for decades. Recent studies suggest that metallic iron and carbon are produced in subducted slabs when they sink beyond a depth of 250 km. Here we show that the eutectic melting curve of the iron-carbon system crosses the current geotherm near Earth's core-mantle boundary, suggesting that dense metallic melt may form in the lowermost mantle. If concentrated into isolated patches, such melt could produce the seismically observed density and velocity features of ULVZs. Depending on the wetting behavior of the metallic melt, the resultant ULVZs may be short-lived domains that are replenished or regenerated through subduction, or long-lasting regions containing both metallic and silicate melts. Slab-derived metallic melt may produce another type of ULVZ that escapes core sequestration by reacting with the mantle to form iron-rich postbridgmanite or ferropericlase. The hypotheses connect peculiar features near Earth's core-mantle boundary to subduction of the oceanic lithosphere through the deep carbon cycle.

  12. Origins of ultralow velocity zones through slab-derived metallic melt

    DOE PAGES

    Liu, Jiachao; Li, Jie; Hrubiak, Rostislav; Smith, Jesse S.

    2016-05-03

    Understanding the ultralow velocity zones (ULVZs) places constraints on the chemical composition and thermal structure of deep Earth and provides critical information on the dynamics of large-scale mantle convection, but their origin has remained enigmatic for decades. Recent studies suggest that metallic iron and carbon are produced in subducted slabs when they sink beyond a depth of 250 km. Here we show that the eutectic melting curve of the iron-carbon system crosses the current geotherm near Earth’s core-mantle boundary, suggesting that dense metallic melt may form in the lowermost mantle. If concentrated into isolated patches, such melt could produce themore » seismically observed density and velocity features of ULVZs. Depending on the wetting behavior of the metallic melt, the resultant ULVZs may be short-lived domains that are replenished or regenerated through subduction, or long-lasting regions containing both metallic and silicate melts. Slab-derived metallic melt may produce another type of ULVZ that escapes core sequestration by reacting with the mantle to form iron-rich post-bridgmanite or ferropericlase. The hypotheses connect peculiar features near Earth’s core-mantle boundary to subduction of the oceanic lithosphere through the deep carbon cycle.« less

  13. Partially confined configuration for the growth of semiconductor crystals from the melt in zero-gravity environment

    NASA Technical Reports Server (NTRS)

    Lagowski, J.; Gatos, H. C.; Dabkowski, F. P.

    1985-01-01

    A novel partially confined configuration is proposed for the crystal growth of semiconductors from the melt, including those with volatile constituents. A triangular prism is employed to contain the growth melt. Due to surface tension, the melt will acquire a cylindrical-like shape and thus contact the prism along three parallel lines. The three empty spaces between the cylindrical melt and the edges of the prism will accommodate the expansion of the solidifying semiconductor, and in the case of semiconductor compounds with a volatile constituent, will permit the presence of the desired vapor phase in contact with the melt for controlling the melt stoichiometry. Theoretical and experimental evidence in support of this new type of confinement is presented.

  14. Partial melting on iron(II) oxide-rich asteroids: Insights to the first stage of planetary differentiation

    NASA Astrophysics Data System (ADS)

    Gardner-Vandy, Kathryn Gail

    2012-05-01

    The melting of planetesimals was a widespread geologic phenomenon taking place in the early inner solar system. Petrologic and geochemical evidence shows that this melting frequently resulted in full differentiation of planetary bodies into a core, mantle, and crust. The extent of this early planetary melting is evidenced in the breadth of achondrite meteorites. In the achondrite meteorite group, there exist meteorites that experienced low degrees of melting, such that the parent body underwent partial melting and did not fully differentiate. These meteorites, called the primitive achondrites, are a window to the first stage of melting in the early solar system. The primitive achondrites with FeO-poor silicate compositions have been well-studied, but little is known about the formation conditions and history of the FeO-rich primitive achondrites, which includes the brachinites and several ungrouped meteorites. The brachinites are olivine-dominated meteorites with a recrystallized texture that show evidence of partial melting and melt removal on their parent body. The ungrouped primitive achondrites are also olivine-dominated meteorites with a recrystallized texture, but they exhibit a larger range in mineralogy with most being essentially chondritic and containing relict chondrules. In this dissertation, I present a study of the petrology, geochemistry and formation conditions of the FeO-rich primitive achondrites. I analyze the petrology and bulk composition of the meteorites, and I conduct thermodynamic modelling of the mineral assemblages to determine oxidation conditions during their formation. Finally, I attempt to simulate the formation of the brachinite meteorites through 1-atmosphere, gas-mixing partial melting experiments of an FeO-rich chondritic meteorite. These meteorites represent a continuum of partial melting, akin to that seen in the acapulcoite-lodranite clan of primitive achondrites. Mineral compositions and oxygen fugacity formation conditions

  15. Subduction zone mantle enrichment by fluids and Zr-Hf-depleted crustal melts as indicated by backarc basalts of the Southern Volcanic Zone, Argentina

    NASA Astrophysics Data System (ADS)

    Holm, Paul M.; Søager, Nina; Alfastsen, Mads; Bertotto, Gustavo W.

    2016-10-01

    We aim to identify the components metasomatizing the mantle above the subducting Nazca plate under part of the Andean Southern Volcanic Zone (SVZ). We present new major and ICP-MS trace element and Sr, Nd and high-precision Pb isotope analyses of primitive olivine-phyric alkali basalts from the Northern Segment Volcanic Field, part of the Payenia province in the backarc of the Transitional SVZ. One new 40Ar-39Ar age determination confirms the Late Pleistocene age of this most northerly part of the province. All analysed rocks have typical subduction zone type incompatible element enrichment, and the rocks of the Northern Segment, together with the neighbouring Nevado Volcanic Field, have isotopic compositions intermediate between adjacent Transitional SVZ arc rocks and southern Payenia OIB-type basaltic rocks. Modelling the Ba-Th-Sm variation we demonstrate that fluids as well as 1-2% melts of upper continental crust (UCC) enriched their mantle sources, and La-Nb-Sm variations additionally indicate that the pre-metasomatic sources ranged from strongly depleted to undepleted mantle. Low Eu/Eu* and Sr/Nd also show evidence for a UCC component in the source. The contribution of Chile Trench sediments to the magmas seems insignificant. The Zr/Sm and Hf/Sm ratios are relatively low in many of the Northern Segment rocks, ranging down to 17 and 0.45, respectively, which, together with relatively high Th/U, is argued to indicate that the metasomatizing crustal melts were derived by partial melting of subducted UCC that had residual zircon, in contrast to the UCC melts added to Transitional SVZ arc magmas. Mixing between depleted and undepleted mantle, enriched by UCC and fluids, is suggested by Sr, Nd and Pb isotopes of the Northern Segment and Nevado magmas. The metasomatized undepleted mantle south of the Northern Segment is suggested to be part of upwelling OIB-type mantle, whereas the pre-metasomatically depleted mantle also can be found as a component in some arc

  16. Subduction of Fracture Zones control mantle melting and geochemical signature above slabs

    NASA Astrophysics Data System (ADS)

    Constantin Manea, Vlad; Leeman, William; Gerya, Taras; Manea, Marina; Zhu, Guizhi

    2014-05-01

    The geochemistry of arc volcanics proximal to oceanic fracture zones (FZs) is consistent with higher than normal fluid inputs to arc magma sources. Here, enrichment of boron (B/Zr) in volcanic arc lavas is used to evaluate relative along-strike inputs of slab-derived fluids in the Aleutian, Andean, Cascades, and Trans-Mexican arcs. Significant B/Zr spikes coincide with subduction of prominent FZs in the relatively cool Aleutian and Andean subduction zones, but not in the relatively warm Cascadia and Mexican subduction zones, suggesting that FZ subduction locally enhances fluid introduction beneath volcanic arcs, and retention of fluids to sub-arc depths diminishes with subduction zone thermal gradient. Geodynamic treatments of lateral inhomogeneities in subducting plates have not previously considered how FZs may influence the melt and fluid distribution above the slab. Using high-resolution three-dimensional coupled petrological-thermomechanical numerical simulations of subduction, we show that fluids, including melts and water, concentrate in areas where fracture zones are subducted, resulting in along-arc variability in magma source compositions and processes.

  17. Melt zones beneath five volcanic complexes in California: an assessment of shallow magma occurrences

    SciTech Connect

    Goldstein, N.E.; Flexser, S.

    1984-12-01

    Recent geological and geophysical data for five magma-hydrothermal systems were studied for the purpose of developing estimates for the depth, volume and location of magma beneath each area. The areas studied were: (1) Salton Trough, (2) The Geysers-Clear Lake, (3) Long Valley caldera, (4) Coso volcanic field, and (5) Medicine Lake volcano, all located in California and all selected on the basis of recent volcanic activity and published indications of crustal melt zones. 23 figs.

  18. Partial Melting of Garnet Lherzolite with H2o and CO2 at 3 GPa: Implications for Intraplate Magmatism.

    NASA Astrophysics Data System (ADS)

    Baasner, A.; Medard, E.; Laporte, D.

    2014-12-01

    The origin and source rock of alkali-rich and SiO2-undersatured magmas in the Earth`s upper mantle have been under debate for a long time. The garnet signature in rare earth element patterns of such magmas suggest a garnet-bearing source rock, which could be garnet lherzolite or garnet pyroxenite. Partial melting experiments were performed at 3 GPa and 1345-1445 °C in a piston-cylinder apparatus using mixtures of natural lherzolite with 0.4-0.7 wt% H2O and 0.4-0.7 wt% CO2 as starting materials. Different designs of AuPd capsules were used for melt extraction. Mineral and melt phases were analysed with electron microprobe and laser ablation inductively coupled plasma mass spectrometry. The degree of partial melting in the experiments ranges from ~20% to ~4% and decreases with decreasing temperature and decreasing volatile content in the starting material. All samples contain olivine and orthopyroxene. Garnet is present in experiments performed below 1420 °C. The amount of clinopyroxene decreases with increasing degree of partial melting and volatile concentration in the starting material. Depending on the capsule design the melts quenched to glasses or to a mixture of quench crystals and residual glass. The composition of the partial melts ranges from basalts through picrobasalts to foidites. The alkali concentration increases and the SiO2 concentration decreases with decreasing degree of partial melting and increasing volatile concentration in the starting material. The partial melts are similar in many aspects to alkali intraplate magmas (basanites to melilitites), although they are richer in MgO. Compositions closer to natural basanites could be obtained either at lower degree of melting (and lower volatile contents) or through olivine fractionation. Our results strongly suggests that. SiO2-undersaturated intraplate magmas can be generated by mantle melting of garnet-lherzolite in the presence of H2O and CO2 in the Earth`s upper mantle at 3 GPa (~100 km depth).

  19. H2O storage capacity of olivine at 5-8 GPa and consequences for dehydration partial melting of the upper mantle

    NASA Astrophysics Data System (ADS)

    Ardia, P.; Hirschmann, M. M.; Withers, A. C.; Tenner, T. J.

    2012-09-01

    The H2O storage capacities of peridotitic minerals place crucial constraints on the onset of hydrous partial melting in the mantle. The storage capacities of minerals in equilibrium with a peridotite mineral assemblage (“peridotite-saturated” minerals) are lower than when the minerals coexist only with fluid because hydrous partial melt is stabilized at a lower activity of H2O. Here, we determine peridotite-saturated olivine H2O storage capacities from 5 to 8 GPa and 1400-1500 °C in layered experiments designed to grow large (∼100-150 μm) olivine crystals in equilibrium with the full hydrous peridotite assemblage (melt+ol+opx+gar+cpx). The peridotite-saturated H2O storage capacity of olivine at 1450 °C rises from 57±26 ppm (by wt.) at 5 GPa to 254±60 ppm at 8 GPa. Combining these with results of a parallel study at 10-13 GPa (Tenner et al., 2011, CMP) yields a linear relation applicable from 5 to 13 GPa for peridotite-saturated H2O storage capacity of olivine at 1450 °C, CH2Oolivine(ppm)=57.6(±16)×P(GPa)-169(±18). Storage capacity diminishes with increasing temperature, but is unaffected by variable total H2O concentration between 0.47 and 1.0 wt%. Both of these are as predicted for the condition in which the water activity in the melt is governed principally by the cryoscopic requirement of melt stability for a given temperature below the dry solidus. Measured olivine storage capacities are in agreement or slightly greater than those predicted by a model that combines data from experimental freezing point depression and olivine/melt partition coefficients of H2O (Hirschmann et al., 2009). Considering the temperature along the mantle geotherm, as well as available constraints on garnet/olivine and pyroxene/olivine partitioning of H2O (DH2Ogar/ol,DH2Opx/ol), we estimate the peridotite H2O storage capacity in the low velocity zone. The CH2O required to initiate melting between 150 and 250 km depth is between 270 and 855 ppm. We conclude that hydrous

  20. Magma transport and olivine crystallization depths in Kīlauea's east rift zone inferred from experimentally rehomogenized melt inclusions

    NASA Astrophysics Data System (ADS)

    Tuohy, Robin M.; Wallace, Paul J.; Loewen, Matthew W.; Swanson, Donald A.; Kent, Adam J. R.

    2016-07-01

    Concentrations of H2O and CO2 in olivine-hosted melt inclusions can be used to estimate crystallization depths for the olivine host. However, the original dissolved CO2 concentration of melt inclusions at the time of trapping can be difficult to measure directly because in many cases substantial CO2 is transferred to shrinkage bubbles that form during post-entrapment cooling and crystallization. To investigate this problem, we heated olivine from the 1959 Kīlauea Iki and 1960 Kapoho (Hawai'i) eruptions in a 1-atm furnace to temperatures above the melt inclusion trapping temperature to redissolve the CO2 in shrinkage bubbles. The measured CO2 concentrations of the experimentally rehomogenized inclusions (⩽590 ppm for Kīlauea Iki [n = 10]; ⩽880 ppm for Kapoho, with one inclusion at 1863 ppm [n = 38]) overlap with values for naturally quenched inclusions from the same samples, but experimentally rehomogenized inclusions have higher within-sample median CO2 values than naturally quenched inclusions, indicating at least partial dissolution of CO2 from the vapor bubble during heating. Comparison of our data with predictions from modeling of vapor bubble formation and published Raman data on the density of CO2 in the vapor bubbles suggests that 55-85% of the dissolved CO2 in the melt inclusions at the time of trapping was lost to post-entrapment shrinkage bubbles. Our results combined with the Raman data demonstrate that olivine from the early part of the Kīlauea Iki eruption crystallized at <6 km depth, with the majority of olivine in the 1-3 km depth range. These depths are consistent with the interpretation that the Kīlauea Iki magma was supplied from Kīlauea's summit magma reservoir (∼2-5 km depth). In contrast, olivine from Kapoho, which was the rift zone extension of the Kīlauea Iki eruption, crystallized over a much wider range of depths (∼1-16 km). The wider depth range requires magma transport during the Kapoho eruption from deep beneath the summit

  1. Magma transport and olivine crystallization depths in Kīlauea’s East Rift Zone inferred from experimentally rehomogenized melt inclusions

    USGS Publications Warehouse

    Tuohy, Robin M; Wallace, Paul J.; Loewen, Matthew W; Swanson, Don; Kent, Adam J R

    2016-01-01

    Concentrations of H2O and CO2 in olivine-hosted melt inclusions can be used to estimate crystallization depths for the olivine host. However, the original dissolved CO2concentration of melt inclusions at the time of trapping can be difficult to measure directly because in many cases substantial CO2 is transferred to shrinkage bubbles that form during post-entrapment cooling and crystallization. To investigate this problem, we heated olivine from the 1959 Kīlauea Iki and 1960 Kapoho (Hawai‘i) eruptions in a 1-atm furnace to temperatures above the melt inclusion trapping temperature to redissolve the CO2 in shrinkage bubbles. The measured CO2 concentrations of the experimentally rehomogenized inclusions (⩽590 ppm for Kīlauea Iki [n=10]; ⩽880 ppm for Kapoho, with one inclusion at 1863 ppm [n=38]) overlap with values for naturally quenched inclusions from the same samples, but experimentally rehomogenized inclusions have higher within-sample median CO2 values than naturally quenched inclusions, indicating at least partial dissolution of CO2 from the vapor bubble during heating. Comparison of our data with predictions from modeling of vapor bubble formation and published Raman data on the density of CO2 in the vapor bubbles suggests that 55-85% of the dissolved CO2 in the melt inclusions at the time of trapping was lost to post-entrapment shrinkage bubbles. Our results combined with the Raman data demonstrate that olivine from the early part of the Kīlauea Iki eruption crystallized at <6 km depth, with the majority of olivine in the 1-3 km depth range. These depths are consistent with the interpretation that the Kīlauea Iki magma was supplied from Kīlauea’s summit magma reservoir (∼2-5 km depth). In contrast, olivine from Kapoho, which was the rift zone extension of the Kīlauea Iki eruption, crystallized over a much wider range of depths (∼1-16 km). The wider depth range requires magma transport during the Kapoho eruption from deep beneath the

  2. Laser powder-bed fusion additive manufacturing: Physics of complex melt flow and formation mechanisms of pores, spatter, and denudation zones

    DOE PAGES

    Khairallah, Saad A.; Anderson, Andrew T.; Rubenchik, Alexander; King, Wayne E.

    2016-02-23

    Our study demonstrates the significant effect of the recoil pressure and Marangoni convection in laser powder bed fusion (L-PBF) of 316L stainless steel. A three-dimensional high fidelity powder-scale model reveals how the strong dynamical melt flow generates pore defects, material spattering (sparking), and denudation zones. The melt track is divided into three sections: a topological depression, a transition and a tail region, each being the location of specific physical effects. The inclusion of laser ray-tracing energy deposition in the powder-scale model improves over traditional volumetric energy deposition. It enables partial particle melting, which impacts pore defects in the denudation zone.more » Different pore formation mechanisms are observed at the edge of a scan track, at the melt pool bottom (during collapse of the pool depression), and at the end of the melt track (during laser power ramp down). Finally, we discuss remedies to these undesirable pores are discussed. The results are validated against the experiments and the sensitivity to laser absorptivity.« less

  3. Growth of GaAs crystals from the melt in a partially confined configuration

    NASA Technical Reports Server (NTRS)

    Gatos, Harry C.; Lagowski, Jacek

    1988-01-01

    The experimental approach was directed along two main goals: (1) the implementation of an approach to melt growth in a partially confined configuration; and (2) the investigation of point defect interaction and electronic characteristics as related to thermal treatment following solidification and stoichiometry. Significant progress was made along both fronts. Crystal growth of GaAs in triangular ampuls was already carried out successfully and consistent with the model. In fact, pronounced surface tension phenomena which cannot be observed in ordinary confinement system were identified and should premit the assessment of Maragoni effects prior to space processing. Regarding thermal treatment, it was discovered that the rate of cooling from elevated temperatures is primarily responsible for a whole class of defect interactions affecting the electronic characteristics of GaAs and that stoichiometry plays a critical role in the quality of GaAs.

  4. Thermal Convection, Tidal Heating And Shallow Partial Melting Within Galilean Icy Satellites

    NASA Astrophysics Data System (ADS)

    Sotin, C.; Head, J.; Tobie, G.

    This study describes how hot plumes form in the outer ice I layer when one takes into account the fact that ice viscosity depends very strongly on temperature. It investigates a large range of parameters to describe the distribution and amount of tidal heatin. In the range of ice viscosity inferred from laboratory experiments, it is shown that tidal forces can heat up rising diapirs on Europa. Partial melt produced in the rising diapirs is predicted to create disruption of near-surface materials and formation of lenticulae and chaos, even if the average ice layer thickness overlying an ocean is larger than 20 km. Models for Callisto and Ganymede are carried out in order to investigate the effect of tidal heating using the same viscosity laws.

  5. Origin and Constraints on Ilmenite-rich Partial Melt in the Lunar Lower Mantle

    NASA Astrophysics Data System (ADS)

    Mallik, A.; Fuqua, H.; Bremner, P. M.; Panovska, S.; Diamond, M. R.; Lock, S. J.; Nishikawa, Y.; Jiménez-Pérez, H.; Shahar, A.; Panero, W. R.; Lognonne, P. H.; Faul, U.

    2015-12-01

    Existence of a partially molten layer at the lunar core-mantle boundary has been proposed to explain the lack of observed far-side deep moonquakes, the observation of reflected seismic phases from deep moonquakes, and the dissipation of tidal energy within the lunar interior [1,2]. However, subsequent models explored the possibility that dissipation due to elevated temperatures alone can explain the observed dissipation factor (Q) and tidal love numbers [3]. Using thermo-chemical and dynamic modeling (including models of the early lunar mantle convection), we explore the hypothesis that an ilmenite-rich layer forms below crustal anorthosite during lunar magma ocean crystallization and may sink to the base of the mantle to create a partial melt layer at the lunar core-mantle boundary. Self-consistent physical parameters (including gravity, pressure, density, VP and Vs) are forward calculated for a well-mixed mantle with uniform bulk composition versus a mantle with preserved mineralogical stratigraphy from lunar magma ocean crystallization. These parameters are compared against observed mass, moment of inertia, real and imaginary parts of the Love numbers, and seismic travel times to further limit the acceptable models for the Moon. We have performed a multi-step grid search with over twenty thousand forward calculations varying thicknesses of chemically/mineralogically distinct layers within the Moon to evaluate if a partially molten layer at the base of the lunar mantle is well-constrained by the observed data. Furthermore, dynamic mantle modeling was employed on the best-fit model versions to determine the survivability of a partially molten layer at the core-mantle boundary. This work was originally initiated at the CIDER 2014 program. [1] Weber et al. (2011). Science 331(6015), 309-12. [2] Khan et al. (2014). JGR 119. [3] Nimmo et al. (2012). JGR 117, 1-11.

  6. Experimental evidence for melt partitioning between olivine and orthopyroxene in partially molten harzburgite

    NASA Astrophysics Data System (ADS)

    Miller, Kevin J.; Zhu, Wen-lu; Montési, Laurent G. J.; Gaetani, Glenn A.; Le Roux, Véronique; Xiao, Xianghui

    2016-08-01

    Observations of dunite channels in ophiolites and uranium series disequilibria in mid-ocean ridge basalt suggest that melt transport in the upper mantle beneath mid-ocean ridges is strongly channelized. We present experimental evidence that spatial variations in mineralogy can also focus melt on the grain scale. This lithologic melt partitioning, which results from differences in the interfacial energies associated with olivine-melt and orthopyroxene-melt boundaries, may complement other melt focusing mechanisms in the upper mantle such as mechanical shear and pyroxene dissolution. We document here lithologic melt partitioning in olivine-/orthopyroxene-basaltic melt samples containing nominal olivine to orthopyroxene ratio of 3 to 2 and melt fractions of 0.02 to 0.20. Experimental samples were imaged using synchrotron-based X-ray microcomputed tomography at a resolution of 700 nm per voxel. By analyzing the local melt fraction distributions associated with olivine and orthopyroxene grains in each sample, we found that the melt partitioning coefficient, i.e., the ratio of melt fraction around olivine to that around orthopyroxene grains, varies between 1.1 and 1.6. The permeability and electrical conductivity of our digital samples were estimated using numerical models and compared to those of samples containing only olivine and basaltic melt. Our results suggest that lithologic melt partitioning and preferential localization of melt around olivine grains might play a role in melt focusing, potentially enhancing average melt ascent velocities.

  7. Lithosphere and Asthenosphere Properties beneath Oceans and Continents and their Relationship with Domains of Partial Melt Stability in the Mantle

    NASA Astrophysics Data System (ADS)

    Dasgupta, R.

    2014-12-01

    The depth of the lithosphere-asthenosphere boundary (LAB) and the change in properties across the lithosphere, asthenosphere, and LAB in various tectonic settings are captured in a variety of geophysical data, including seismic velocities and electrical conductivity. A sharp drop in shear wave velocity and increase in electrical conductivity can potentially be caused by the appearance of partial melt at or below the LAB but the chemical and dynamic stability of partial melt across lithosphere and at LAB remain debated. Here I apply the recent models of mantle melting in the presence of water and carbon [1, 2] to evaluate the domains of stability of partial melt both beneath continents and oceans. The model allows prediction of the possible presence, the fraction, and composition of partial melt as a function of depth, bulk C and H2O content, and fO2 [3] in various geologic/tectonic settings. The results show that while a hydrous, carbonated melt is stable only beneath LAB and in the asthenospheric mantle beneath oceans, continental mantle can contain a carbonate-rich melt within the lithosphere. For geotherms corresponding to surface heat flux (SHF) of 40-50 mW m-2, which also match P-T estimates beneath cratons based on thermo-barometry of peridotite xenoliths [4], the solidus of fertile peridotite with trace amount of CO2 and H2O is crossed at depths as shallow as 80-120 km [5]. If elevated geotherms of the Proterozoic and Phanerozoic terrains are applied, carbonatitic melt becomes stable somewhat shallower. These depths are similar to those argued for a mid-lithospheric discontinuity (MLD) where a negative velocity gradient has been detected much shallower than the proposed depth of LAB in many places. With a drop in oxygen fugacity with depth, a freezing of carbonatitic melt may be expected at intermediate depths (~150-200 km). At 200-250 km a hydrous, carbonated silicate melt may reappear owing to the interplay of fO2 and freezing point depression effect of CO

  8. A modified iterative sandwich method for determination of near-solidus partial melt compositions. II. Application to determination of near-solidus melt compositions of carbonated peridotite

    NASA Astrophysics Data System (ADS)

    Dasgupta, Rajdeep; Hirschmann, Marc M.

    2007-12-01

    We performed modified iterative sandwich experiments (MISE) to determine the composition of carbonatitic melt generated near the solidus of natural, fertile peridotite + CO2 at 1,200 1,245°C and 6.6 GPa. Six iterations were performed with natural peridotite (MixKLB-1: Mg# = 89.7) and ˜10 wt% added carbonate to achieve the equilibrium carbonatite composition. Compositions of melts and coexisting minerals converged to a constant composition after the fourth iteration, with the silicate mineral compositions matching those expected at the solidus of carbonated peridotite at 6.6 GPa and 1,230°C, as determined from a sub-solidus experiment with MixKLB-1 peridotite. Partial melts expected from a carbonated lherzolite at a melt fraction of 0.01 0.05% at 6.6 GPa have the composition of sodic iron-bearing dolomitic carbonatite, with molar Ca/(Ca + Mg) of 0.413 ± 0.001, Ca# [100 × molar Ca/(Ca + Mg + Fe*)] of 37.1 ± 0.1, and Mg# of 83.7 ± 0.6. SiO2, TiO2 and Al2O3 concentrations are 4.1 ± 0.1, 1.0 ± 0.1, and 0.30 ± 0.02 wt%, whereas the Na2O concentration is 4.0 ± 0.2 wt%. Comparison of our results with other iterative sandwich experiments at lower pressures indicate that near-solidus carbonatite derived from mantle lherzolite become less calcic with increasing pressure. Thus carbonatitic melt percolating through the deep mantle must dissolve cpx from surrounding peridotite and precipitate opx. Significant FeO* and Na2O concentrations in near solidus carbonatitic partial melt likely account for the ˜150°C lower solidus temperature of natural carbonated peridotite compared to the solidus of synthetic peridotite in the system CMAS + CO2. The experiments demonstrate that the MISE method can determine the composition of partial melts at very low melt fraction after a small number of iterations.

  9. Imaging melt and thermal structure in subduction zones: what does seismic attenuation tell us?

    NASA Astrophysics Data System (ADS)

    Abers, G. A.; Fischer, K. M.; Hirth, G.; Holtzman, B. K.; McCarthy, C.; Plank, T. A.; Wiens, D. A.

    2013-12-01

    Subduction zones provide opportunities for observation of the mantle melting region not easily available elsewhere. Earthquakes within subducting plates can be recorded in the overlying plate. These paths sample the volumes where melting occurs with high resolution and short ray paths, and produce simple signals with much higher frequency content than available elsewhere. Also, arc volcanoes provide a direct sample of mantle melting products, and magmas record H2O concentrations, temperature, and pressure in their geochemical compositions. Beneath both volcanic arcs and back-arc basins, seismic waves exhibit very high attenuation (1/Q) for both P and S waves. Several recent field experiments have shown that the region of high 1/Q is localized and more than an order of magnitude more attenuating than adjacent regions in the forearc or slab. We have systematically re-analyzed data from two sets of these experiments, from Central America and the Marianas, where 1/Q anomalies are well defined and where arc or backarc lavas provide independent constraints on mantle properties. These analyses show strong attenuation anomalies, with Qs at 1 Hz no lower than 60-80 beneath Costa Rica but lower beneath other arcs and back-arc basins, to Qs<40. The systematic decrease in Qs (increase in attenuation) correlates well with temperature from geothermometers based on major-element chemistry. However, these Qs values are a factor of 2-4 lower than predicted from temperature by current laboratory-based calibrations in olivine-dominated rocks, at relevant conditions. We refine the Qs predictions using a grain size evolution model and estimates of mantle water content from olivine-hosted melt inclusions, effects which decrease but do not eliminate the discrepancy. We conclude that melt must have a significant impact on Q, bigger than predicted by models of grain-boundary dissipation with equilibrium grain geometries. One possibility is that in these very high 1/Q regions additional

  10. Uranium and minor-element partitioning in Fe-Ti oxides and zircon from partially melted granodiorite, Crater Lake, Oregon

    SciTech Connect

    La Tourrette, T.Z.; Burnett, D.S. ); Bacon C.R. )

    1991-02-01

    Crystal-liquid partitioning in Fe-Ti oxides and zircon was studied in partially melted granodiorite blocks ejected during the climactic eruption of Mt. Mazama (Crater Lake), Oregon. The blocks, which contain up to 33% rhyolite glass (75 wt% SiO{sub 2}), are interpreted to be portions of the magma chamber walls that were torn off during eruption. The glass is clear and well homogenized for all measured elements except Zr. Results for Fe-Ti oxides give D{sub U}{sup oxide/liq} {approx} 0.1. Partitioning of Mg, Mn, Al, Si, V, and Cr in Fe-Ti oxides indicates that grains surrounded by glass are modestly well equilibrated with the melt for many of the minor elements, while those that are inclusions in relict plagioclase are not. Uranium and ytterbium inhomogeneities in zircons indicate that the zircons have only partially equilibrated with the melt and that uranium appears to have been diffusing out of the zircons have only partially equilibrated with the melt and that uranium appears to have been diffusing out of the zircons faster that the zircons were dissolving. Based on the authors measurements and given their low abundances in most rocks, Fe-Ti oxides probably do not play a major role in U-Th fractional during partial melting. The partial melts were undersaturated with zircon and apatite, but both phases are present in the authors samples. This demonstrates an actual case of nonequilibrium source retention of accessory phases, which in general could be an important trace element fractionation mechanism. Their results do not support the hypothesis that liquid structure is the dominant factor controlling trace-element partitioning in high-silica rhyolites.

  11. Experimental and geochemical evidence for derivation of the El Capitan Granite, California, by partial melting of hydrous gabbroic lower crust

    USGS Publications Warehouse

    Ratajeski, K.; Sisson, T.W.; Glazner, A.F.

    2005-01-01

    Partial melting of mafic intrusions recently emplaced into the lower crust can produce voluminous silicic magmas with isotopic ratios similar to their mafic sources. Low-temperature (825 and 850??C) partial melts synthesized at 700 MPa in biotite-hornblende gabbros from the central Sierra Nevada batholith (Sisson et al. in Contrib Mineral Petrol 148:635-661, 2005) have major-element and modeled trace-element (REE, Rb, Ba, Sr, Th, U) compositions matching those of the Cretaceous El Capitan Granite, a prominent granite and silicic granodiorite pluton in the central part of the Sierra Nevada batholith (Yosemite, CA, USA) locally mingled with coeval, isotopically similar quartz diorite through gabbro intrusions (Ratajeski et al. in Geol Soc Am Bull 113:1486-1502, 2001). These results are evidence that the El Capitan Granite, and perhaps similar intrusions in the Sierra Nevada batholith with lithospheric-mantle-like isotopic values, were extracted from LILE-enriched, hydrous (hornblende-bearing) gabbroic rocks in the Sierran lower crust. Granitic partial melts derived by this process may also be silicic end members for mixing events leading to large-volume intermediate composition Sierran plutons such as the Cretaceous Lamarck Granodiorite. Voluminous gabbroic residues of partial melting may be lost to the mantle by their conversion to garnet-pyroxene assemblages during batholithic magmatic crustal thickening. ?? Springer-Verlag 2005.

  12. Petrological mapping of a Low Velocity Zone (LVZ) induced by CO2-H2O-bearing incipient melts

    NASA Astrophysics Data System (ADS)

    Massuyeau, M.; Gardés, E.; Morizet, Y.; Le Trong, E.; Gaillard, F.

    2014-12-01

    The link between volatiles and mantle melting has so far been illuminated by experiments, revealing that ppm concentration levels of carbon and other volatiles in the Earth's mantle induce partial melting. Pressure-temperature conditions of incipient melting for CO2-H2O-peridotite [1] match fairly well with the upper part of the LVZ, as the redox melting [2] with the lower part. Recent experimental studies about the Earth mantle conductivity have shown the importance of small amounts of hydrated CO2-rich melts in the geophysical signature of the LVZ [3]. Although such melts are stable under the P-T-fO2 conditions of the LVZ [1-2, 4-6], the variability of these parameters complicates the definition of their chemical composition. Using Margules' formalisms, we established a multi-component model describing the Gibbs free energy of melt produced by mantle melting in presence of CO2-H2O, that are carbonatite-carbonated melt-nephilinite-basanite and basalt with increasing degree of partial melting. This parameterization is calibrated on crystal-liquid, redox, fluid-liquid and liquid-liquid equilibria obtained by experimental studies in the P-T range 1-10 GPa and 900-1800°C. We propose a calculation of the composition of melts produced in the oceanic LVZ as a function of ages (temperature) and chemical heterogeneities (water, alkalis). At about 80 km depth, we show that the composition of the melts is > 30 wt% SiO2 for ages < 30 Ma, and comes closer to the carbonatitic terms for older lithosphere. Besides lateral chemical variations, our model calculates the melt composition along an oceanic ridge adiabat, predicting an abrupt compositional transition between a H2O-rich carbonatitic melt and a carbonated silicate melt, between 130 km and 100 km. We propose a chemical mapping of the melt composition (and of the degree of partial melting) as a function of the distance to the ridge and of the depth. Our model represents an innovating attempt to connect the chemical

  13. Low HFSE Rhyolites from Oregon: Smoking Gun for an Origin Through Partial Melting of the Crust

    NASA Astrophysics Data System (ADS)

    Streck, M. J.; Steiner, A. R.; Jenkins, E. N.; Large, A.

    2014-12-01

    Rhyolites are a significant component of continental magmatism of Oregon for the last 40 million years. Rhyolites of all time slices are compositionally diverse ranging from low to high-silica rhyolites, from less fractionated rhyolites with high Ba concentrations (≥1300 ppm Ba) and weak Eu anomalies (>0.4 Eu/Eu*) to strongly fractionated rhyolites with very low Ba contents (≤100 ppm) but strong Eu anomalies (≤0.2 Eu/Eu*), and rhyolites range from Fe-rich, A-type rhyolites to calc-alkaline varieties. In this study, we focus on one compositional end member of rhyolites that is characterized by very low concentrations of high field strength elements (HFSE) designated here as low HFSE rhyolites. Such low HFSE rhyolites contain Nb and Ta contents of 8-13 ppm and 0.8-1.1 ppm, respectively, and Zr and Hf concentrations of 60-150 ppm and 2.5-4 ppm, respectively. The significance of these low HFSE concentrations is that they are consistent with partial melting of observed crustal rocks but not with fractionation of observed mafic magmas. Compilation of chemical data of Cenozoic mafic magmas across Oregon indicate that the vast majority of basaltic rocks contain Nb and Zr contents in excess of 5 and 100 ppm, respectively. Only the most primitive high-Al olivine basalts have concentrations as low as 1 and 40 ppm. Basaltic magmas generate rhyolitic liquids after ~90-95% crystallization (e.g., as seen in lava lakes). After such high amounts of crystallization using basaltic magmas from Oregon, Nb and Zr contents would be far in excess of what is observed in these low HFSE rhyolites as both elements will behave incompatibly (strongly to moderately) during fractionation to rhyolites. Also, there are chemical and petrographic arguments that neither late titanite nor zircon fractionation in rhyolites caused low HFSE contents. Although lesser amounts of fractionation would be needed starting with an andesitic composition, HFSE contents of most andesites are already on levels

  14. High-quality Silicon Films Prepared by Zone-melting Recrystallization

    NASA Technical Reports Server (NTRS)

    Chen, C. K.; Geis, M. W.; Tsaur, B. Y.; Fan, J. C. C.

    1984-01-01

    The graphite strip heater zone melting recrystallization (ZMR) technique is described. The material properties of the ZMR films, and SOI device results are reviewed. Although our ZMR work is primarily motivated by integrated circuit applications, this work evolved in part from earlier research on laser crystallization of thick amorphous GaAs and Si films, which was undertaken with the goal of producing low cost photovoltaic materials. The ZMR growth process and its effect on the properties of the recrystallized films may contribute some insight to a general understanding of the rapid recrystallization of Si for solar cells. Adaptation of ZMR for solar cell fabrication is considered.

  15. The role of partial melting and syn-orogenic deformation in the pre-concentration of uranium and thorium. The example of the CAGE District (Northern Quebec).

    NASA Astrophysics Data System (ADS)

    Trap, Pierre; Goncalves, Philippe; Durand, Cyril; Marquer, Didier; Feybesse, Jean-Louis; Richard, Yoann; Lacroix, Brice; Caillet, Yoann; Paquette, Jean-Louis

    2015-04-01

    This contribution aims to discuss the relationships between metamorphism, deformation and U-Th mineralization within the orogenic crust, from millimeter to kilometer scale and during the whole P-T-t evolution. The study area is the CAGE district along the paleoproterozoic Torngat orogen (Northern Quebec) made of 2.1 Ga metasedimentary rocks, marbles and paragneisses, deposited upon a 2.5 Ga orthogneissic basement. Several types of U-Th mineralizations have been reported within the middle crust highly metamorphosed and deformed during the Torgnat orogeny (1.9-1.8 Ga). An integrated study with field, geophysical, structural, petrological, geochemical and thermochronological analyses enable a reconstitution of the tectono-metamorphic setting of these U-Th mineralizations and of the mechanism responsible for their pre-concentration into the orogenic crust. The petrological analysis allows us to build a clockwise P-T-t-D evolution with peak pressure conditions at 7.5 - 10 kbar and 725 - 750 ° C and peak temperature conditions at 5-6 kbar and 800-850°C. This high grade metamorphism and widespread partial melting developed within a single dextral transpressive regime. The structural analysis suggests strain partitioning responsible for a S-C-C' like architecture observed at all scales. Aeromagnetic, radiometric and field observations revealed that U-Th mineralizations are mainly focused along the kilometer scale C and C'-type shear zones. The age of crustal partial melting was constrained by U-Pb LA-ICP-MS analyses on zircon and monazite within migmatitic paragneiss and orthogneiss between 1841 ± 5 and 1828 ± 7 Ma. Younger U-Pb ages at around 1810-1750 Ma have been reported on monazite and titanites within the crustal scale shear bands (C and C' like). Results obtained on mylonitic metacarbonaceous and metapelites within kilometer scale shear zones suggest that late shearing formed during retrograde evolution at decreasing temperature after peak metamorphism. The δ13

  16. Uranium and minor-element partitioning in Fe-Ti oxides and zircon from partially melted granodiorite, Crater Lake, Oregon

    USGS Publications Warehouse

    Tourrette, T.Z.L.; Burnett, D.S.; Bacon, C.R.

    1991-01-01

    Crystal-liquid partitioning in Fe-Ti oxides and zircon was studied in partially melted granodiorite blocks ejected during the climactic eruption of Mt. Mazama (Crater Lake), Oregon. The blocks, which contain up to 33% rhyolite glass (75 wt% SiO2), are interpreted to be portions of the magma chamber walls that were torn off during eruption. The glass is clear and well homogenized for all measured elements except Zr. Results for Fe-Ti oxides give DUoxide/liq ??? 0.1. Partitioning of Mg, Mn, Al, Si, V, and Cr in Fe-Ti oxides indicates that grains surrounded by glass are moderately well equilibrated with the melt for many of the minor elements, while those that are inclusions in relict plagioclase are not. Uranium and ytterbium inhomogeneities in zircons indicate that the zircons have only partially equilibrated with the melt and that uranium appears to have been diffusing out of the zircons faster than the zircons were dissolving. Minimum U, Y, and P concentrations in zircons give maximum DUzrc/liq = 13,DYzrc/liq = 23, and DPzrc/liq = 1, but these are considerably lower than reported by other workers for U and Y. Based on our measurements and given their low abundances in most rocks, Fe-Ti oxides probably do not play a major role in U-Th fractionation during partial melting. The partial melts were undersaturated with zircon and apatite, but both phases are present in our samples. This demonstrates an actual case of non-equilibrium source retention of accessory phases, which in general could be an important trace-element fractionation mechanism. Our results do not support the hypothesis that liquid structure is the dominant factor controlling trace-element partitioning in high-silica rhyolites. Rough calculations based on Zr gradients in the glass indicate that the samples could have been partially molten for 800 to 8000 years. ?? 1991.

  17. CO2 Solubility in Rhyolitic Melts as a Function of P, T, and fO2 - Implications for Carbon Flux in Subduction Zones

    NASA Astrophysics Data System (ADS)

    Duncan, M. S.; Dasgupta, R.

    2013-12-01

    Understanding the balance between subduction inputs vs. arc output of carbon is critical for constraining the global carbon cycle. However, the agent of carbon transfer from slab to sub-arc mantle is not constrained [1]. Partial melt of ocean-floor sediments is thought to be a key agent of mass transfer in subduction zones, accounting for the trace element characteristics of arc magmas [2]. Yet the carbon carrying capacity of rhyolitic partial melts of sediments remains unknown at sub-arc depths. In our previous work [3], we constrained CO2 solubility of natural rhyolite from 1.5-3.0 GPa, 1300 °C and logfO2 at FMQ×1.0. However, the effects of T and fO2 on CO2 solubility remain unconstrained. In particular, for sediments with organic carbon, graphite stability is expected and the fO2 of C-dissolution can be lower, which may affect the solubility. Thus it is critical to constrain the CO2 solubility of sediment partial melts under graphite-saturated conditions. We determined CO2 solubility of a model rhyolite composition, similar to partial melt composition of natural metapelite [4], at graphite saturation, using Pt/Gr capsules and a piston cylinder device. Experiments were conducted at 1.5-3.0 GPa and 1100-1400 °C. FTIR was employed to measure the concentrations of CO2 and H2O in doubly polished experimental glasses. Raman and SIMS were used to determine the presence of reduced carbon species and total carbon, respectively. FTIR spectra reveal that CO2 is dissolved as both molecular CO2 (CO2mol.) and carbonates (CO32-). For graphite-saturated, hydrous melts with measured H2O ~2.0 wt.%, CO2tot. (CO2mol.+CO32-) values increase with increasing P from ~0.6 to 1.2 wt.% from 1.5 to 3.0 GPa at 1300 °C. These values are lower than more oxidized melts with the same water content, which were 0.85 to 1.99 wt.% CO2 as P increased. At 3 GPa, graphite-saturated experiments from 1100 to 1300 °C yield CO2tot. value of 1.18-1.20 wt.%, suggesting minor effect of temperature in

  18. Melt ponds and marginal ice zone from new algorithm of sea ice concentration retrieval

    NASA Astrophysics Data System (ADS)

    Repina, Irina; Tikhonov, Vasiliy; Komarova, Nataliia; Raev, Mikhail; Sharkov, Evgeniy

    2016-04-01

    Studies of spatial and temporal properties of sea ice distribution in polar regions help to monitor global environmental changes and reveal their natural and anthropogenic factors, as well as make forecasts of weather, marine transportation and fishing conditions, assess perspectives of mineral mining on the continental shelf, etc. Contact methods of observation are often insufficient to meet the goals, very complicated technically and organizationally and not always safe for people involved. Remote sensing techniques are believed to be the best alternative. Its include monitoring of polar regions by means of passive microwave sensing with the aim to determine spatial distribution, types, thickness and snow cover of ice. However, the algorithms employed today to retrieve sea ice characteristics from passive microwave sensing data for different reasons give significant errors, especially in summer period and also near ice edges and in cases of open ice. A new algorithm of sea ice concentration retrieval in polar regions from satellite microwave radiometry data is discussed. Beside estimating sea ice concentration, the algorithm makes it possible to indicate ice areas with melting snow and melt ponds. Melt ponds are an important element of the Arctic climate system. Covering up to 50% of the surface of drifting ice in summer, they are characterized by low albedo values and absorb several times more incident shortwave radiation than the rest of the snow and ice cover. The change of melt ponds area in summer period 1987-2015 is investigated. The marginal ice zone (MIZ) is defined as the area where open ocean processes, including specifically ocean waves, alter significantly the dynamical properties of the sea ice cover. Ocean wave fields comprise short waves generated locally and swell propagating from the large ocean basins. Depending on factors like wind direction and ocean currents, it may consist of anything from isolated, small and large ice floes drifting over a

  19. Study of the permeability in melting zone of South China Sea based on percolation theory

    NASA Astrophysics Data System (ADS)

    Wan, Ju-ying; Xu, He-hua; Li, Yan-zhen; Shu, Wei-bing

    2015-09-01

    Oceanic crust is formed at mid-ocean ridges. The melting zone extends up to several hundreds of km laterally, the upwelling area at the spreading axis is confined to a narrow belt of only 2-3 km width. Whereas the parameter of permeability that magma ascending from the mantle beneath mid-ocean ridges is still poorly understood, despite the important role of the process for the formation of crust. Based on continuum percolation, we build the random fracture network as magma migration channels of South China Sea; with momentum equation, we deduced the dynamic pressure distribution with passive corner flow. After which, the permeability of melting zone is calculated with finite element method. Numerical simulation results indicate that there exists a power law relationship between the permeability and magma migration channels. The simulated result is consistent with that calculated by fractal method. The discovery of the ruler provides sound theoretical basis for the formation and evolution of oceanic crust, and may help us better understanding the formation and evolution of South China Sea.

  20. The low magnetic field properties of superconducting bulk yttrium barium copper oxide - Sintered versus partially melted material

    NASA Technical Reports Server (NTRS)

    Hein, R. A.; Hojaji, H.; Barkatt, A.; Shafii, H.; Michael, K. A.; Thorpe, A. N.; Ware, M. F.; Alterescu, S.

    1989-01-01

    A comparison of the low magnetic field properties of sintered (990 C) and partially melted samples (1050 C) has been performed. Changes in the microstructure produced by recrystallization from the melt result in a significant increase in flux pinning at 77 K. Low-frequency (10-100 Hz), low-ac magnetic-field (0.01-9.0 Oe) ac susceptibility data show that gross changes in the loss component accompany the observed changes in microstructure. The effects of applied dc magnetic fields (10-220 Oe) on the ac responses of these microstructures have also been probed.

  1. Partial melting of subducted paleo-Pacific plate during the early Cretaceous: Constraint from adakitic rocks in the Shaxi porphyry Cu-Au deposit, Lower Yangtze River Belt

    NASA Astrophysics Data System (ADS)

    Deng, Jianghong; Yang, Xiaoyong; Li, Shuang; Gu, Huangling; Mastoi, Abdul Shakoor; Sun, Weidong

    2016-10-01

    A large porphyry Cu-Au deposit associated with early Cretaceous intrusive rocks has been discovered and explored in the Shaxi area, Lower Yangtze River Belt (LYRB), eastern China. We studied two types of intrusive rocks in the Shaxi area: Cu-Au mineralization related diorites and quartz-diorites (adakitic rocks), and newly found high Sr/Y ratio biotite-gabbros. They were formed almost simultaneously with crystallization ages of ca. 130 to 129 Ma, younger than the early stage shoshonitic rocks (Longmenyuan, Zhuanqiao and Shuangmiao Fm.) in the Luzong volcanic basin, ~ 10 km south of the Shaxi area. These intrusive rocks show similar distribution patterns of trace elements (enriched in LILEs and depleted in HFSEs) and REEs (enriched in LREEs and depleted in HREEs, no Eu negative anomaly, flat HREE patterns). The diorites and quartz-diorites are adakitic rocks with calc-alkaline affinity, distinguished from other adakitic rocks in the LYRB which are high-K calc-alkaline series. The biotite-gabbros are not adakitic rocks, although they are characterized by high Sr/Y ratios. Shaxi adakitic rocks show positive zircon εHf(t) values, which may be attributed to the contribution of subducted oceanic crust, while the εHf(t) values of the biotite-gabbros are mostly negative, indicating the involvement of old crustal materials. Although Sr-Nd-Pb isotopes of Shaxi adakitic rocks are more depleted than those of other adakitic rocks in the LYRB, they are still slightly enriched, similar to continental arc adakites in the Andean Austral Volcanic Zone. The Shaxi adakitic rocks are characterized by high Sr contents and Sr/Y ratios, medium (La/Yb)N, MgO contents and Mg#, and low K2O/Na2O ratios, decoupling of Sr/Y and (La/Yb)N, low Th/U values, exhibiting characteristics of slab-derived adakitic rocks. They were not produced by fractional crystallization of basaltic magmas like adakitic rocks in Edong-Jiurui and Tongling but originally generated from partial melting of subducted

  2. Generation of trondhjemite from partial melting of dacite under granulite facies conditions: an example from the New Jersey Highlands, USA

    USGS Publications Warehouse

    Puffer, J.H.; Volkert, R.A.

    1991-01-01

    New field and geochemical data place the Losee Metamorphic Suite (a tonalite/trondhjemite complex) of northern New Jersey into the context of a major Proterozoic continental are represented by a discontinuous belt of northern Appalachian metadacite. Samples of Losee rock range from extremely leucocratic trondhjemite locally associated with amphibolite, to banded biotite, hornblende, pyroxene, and garnet-bearing tonalites. The major element and REE composition of the tonalite closely resembles dacite from continental are settings and model melts extracted from an eclogite residue by partial melting at 15 kbar. The REE composition of most Losee trondhjemite is enriched in REE, particularly HREE, compared with Losee tonalite, and is interpreted as the product of local anatectic melting of Losee tonalite (metadacite) that occurred in a granulite facies environment during the Grenville orogeny. ?? 1991.

  3. A petrologic, thermodynamic and experimental study of brachinites: Partial melt residues of an R chondrite-like precursor

    NASA Astrophysics Data System (ADS)

    Gardner-Vandy, Kathryn G.; Lauretta, Dante S.; McCoy, Timothy J.

    2013-12-01

    The primitive achondrites provide a window into the initial melting of asteroids in the early solar system. The brachinites are olivine-dominated meteorites with a recrystallized texture that we and others interpret as evidence of partial melting and melt removal on the brachinite parent body. We present a petrologic, thermodynamic and experimental study of the brachinites to evaluate the conditions under which they formed and test our hypothesis that the precursor material to the brachinites was FeO-rich compared to the precursors of other primitive achondrites. Petrologic analysis of six brachinites (Brachina, Allan Hills (ALH) 84025, Hughes 026, Elephant Moraine (EET) 99402, Northwest Africa (NWA) 3151, and NWA 4969) and one brachinite-like achondrite (NWA 5400) shows that they are meteorites with recrystallized texture that are enriched in olivine (⩾80 vol.%) and depleted in other minerals with respect to a chondritic mineralogy. Silicates in the brachinites are FeO-rich (Fa32-36). Brachinite-like achondrite Northwest Africa 5400 is similar in mineralogy and texture to the brachinites but with a slightly lower FeO-content (Fa30). Thermodynamic calculations yield equilibration temperatures above the Fe,Ni-FeS cotectic temperature (∼950 °C) for all meteorites studied here and temperatures above the silicate eutectic (∼1050 °C) for all but two. Brachina formed at an fO2 of ∼IW, and the other brachinites and NWA 5400 formed at ∼IW - 1. All the meteorites show great evidence of formation by partial melting having approximately chondritic to depleted chondritic mineralogies, equilibrated mineral compositions, and recrystallized textures, and having reached temperatures above that required for melt generation. In an attempt to simulate the formation of the brachinite meteorites, we performed one-atmosphere, gas-mixing partial melting experiments of R4 chondrite LaPaz Ice Field 03639. Experiments at 1250 °C and an oxygen fugacity of IW - 1 produce residual

  4. Partial melting and refertilization of mantle peridotites in the Xigaze ophiolite: constraints from whole-rock and mineral geochemistry

    NASA Astrophysics Data System (ADS)

    Zhang, Chang; Liu, Chuan-Zhou; Wu, Fu-Yuan

    2016-04-01

    Ophiolites along the E-W trending Yarlung-Tsangpo Suture (YTS), which separates the Indian plate from the Eurasian plate, have been regarded as relics of the Neo-Tethyan Ocean. The Xigaze ophiolite in the central YTS has been extensively studied. One of the most intact crust-mantle sequences is preserved in the Luqu (or Beimarang) ophiolite. Mantle peridotites of the Luqu ophiolite are dominated by harzburgites, with 55-65% olivine, 30-40% orthopyroxene, 1-5% clinopyroxene and 1-3% spinel. Minor lherzolites and dunites are also outcropped, and the mode contents of clinopyroxene in lherzolite can be locally up to 10%. This contribution presented whole-rock major element and mineral chemistry including EMPA (Electronic MicroProbe Analysis) and clinopyroxene in situ trace elements. Whole rock Al2O3 (0.23-2.05%) and CaO (0.41-1.7%) contents are very low but show obviously inverse correlation with MgO (39.7-47.0%), indicating that the Luqu peridotites are residues of variable degrees of partial melting. This is supported by the Cr# (=molar Cr/(Cr+Al)) values of spinels which vary from 0.36 to 0.69. Meanwhile, the high Cr# values of spinels and homogenously high Mg# (= molar Mg/(Mg+Fe2+)) values of olivines, clustering at 0.91, indicate high degrees of partial melting. The low REE (rare earth elements) concentrations and chondrite-normalized distribution partterns of clinopyroxenes reflect ultra-depleted natures, with most showing LREE (light REEs) and MREE (medium REEs) depleted patterns and strong fractionations between MREEs and HREE (heavy REEs) ((Sm/Yb)N: 0.021-0.184). Based on the observations and analyses, a model of two-stage melting process was proposed that the primitive mantle underwent 2-8% melting in garnet stability field which was followed by 10-15% melting in spinel stability field. The clinopyroxenes in some peridotites exhibit obvious enrichment of somestrongly incompatible elements (such as sodium and LREE) that reveal later refertilization process for

  5. Partial melting in the iron-sulfur system at high pressure: A synchrotron X-ray diffraction study

    SciTech Connect

    Campbell, A J; Seagle, C T; Heinz, D L; Shen, G; Prakapenka, V

    2008-09-18

    Partial melting in the Fe-S system was investigated at high pressures because of its importance to understanding the formation, composition, and thermal structure of the Earth's core. Earlier studies at very high pressure (>25 GPa) took place before the discovery of Fe{sub 3}, which compromised the interpretation of those results. Furthermore, they relied on textural criteria for melting that are difficult to apply at high pressure. In this study synchrotron X-ray diffraction was used to monitor coexisting metal and sulfide at high pressures and temperatures, during laser heating in a diamond anvil cell. The criterion for melting was the disappearance of one of the two coexisting phases, and reappearance upon quench. Temperatures of eutectic melting between Fe and Fe{sub 3}S were bracketed in this way up to 60 GPa, and a lower bound was established at 80 GPa. The accuracy of the melting point measured in these studies was improved through modelling of the axial temperature distribution through the thickness of the sample; this indicated an {approx}6% correction to the spectroradiometrically determined temperature. The Fe-Fe{sub 3}S eutectic composition remains close to 15 wt% S up to 60 GPa.

  6. Vegetative growth and cluster development in Shiraz grapevines subjected to partial root-zone cooling.

    PubMed

    Rogiers, Suzy Y; Clarke, Simon J

    2013-01-01

    Heterogeneity in root-zone temperature both vertically and horizontally may contribute to the uneven vegetative and reproductive growth often observed across vineyards. An experiment was designed to assess whether the warmed half of a grapevine root zone could compensate for the cooled half in terms of vegetative growth and reproductive development. We divided the root system of potted Shiraz grapevines bilaterally and applied either a cool or a warm treatment to each half from budburst to fruit set. Shoot growth and inflorescence development were monitored over the season. Simultaneous cooling and warming of parts of the root system decreased shoot elongation, leaf emergence and leaf expansion below that of plants with a fully warmed root zone, but not to the same extent as those with a fully cooled root zone. Inflorescence rachis length, flower number and berry number after fertilization were smaller only in those vines exposed to fully cooled root zones. After terminating the treatments, berry enlargement and the onset of veraison were slowed in those vines that had been exposed to complete or partial root-zone cooling. Grapevines exposed to partial root-zone cooling were thus delayed in vegetative and reproductive development, but the inhibition was greater in those plants whose entire root system had been cooled.

  7. Partial crystallization of picritic melt and its applications for the genesis of high-Ti and low-Ti basalts

    NASA Astrophysics Data System (ADS)

    Yang, J.; WANG, C.; Jin, Z.; Jin, S.; Yan, S.

    2015-12-01

    Geochemical and petrological studies have revealed the existence of high-Ti and low-Ti basalts in large igneous provinces (LIPs). However the originate of these high-Ti and low-Ti magmas are still under debate. Several different mechanisms have been proposed: (1) the high-Ti basalts are formed by the melting of mantle plume containing recycled oceanic crust (Spandler et al., 2008) while low-Ti basalts are formed by the melting of subcontinental lithospheric mantle (Xiao et al., 2004); (2) both high-Ti and low-Ti basalts are from mantle plume source, but the production of high-Ti basalts are associated with the thick lithosphere while the low-Ti basalts are controlled by the thin lithosphere (Arndt et al., 1993); (3) they are derived from the different degrees of melting, with high-Ti basalts representing low degree of partial melting of mantle plume (Xu et al., 2004). The low Mg# (below 0.7) of high-Ti and low-Ti basalts provides that they are far away from direct melting of mantle peridotite. In addition, seismic data indicate unusually high seismic velocities bodies beneath the LIPs which explained by the fractionated cumulates from picritic magmas (Farnetani et al., 1996). Therefore, we believed that the crystallization differentiation process might play a more significant role in the genesis of high-Ti and low-Ti basalts.In order to investigate the generation of high-Ti and low-Ti basalts, a series of high pressure and high temperature partial crystallization experiments were performed at pressures of 1.5, 3.0 and 5.0 GPa and a temperature range of 1200-1700℃. The starting material is picrate glass with relative high TiO2 (2.7 wt %), which is synthesized according to the chemical composition of primary magmas of Emeishan LIP (Xu et al., 2001). The experimental results show that: (1) At a given pressure, the TiO2 content is decreased with increasing melt fraction; (2) At a given melt fraction, the TiO2 content of melts is increased with increasing pressure. On

  8. Migmatites formed by water-fluxed partial melting of a leucogranodiorite protolith: Microstructures in the residual rocks and source of the fluid

    NASA Astrophysics Data System (ADS)

    Sawyer, E. W.

    2010-05-01

    The Opatica Subprovince in the Canadian Shield is a late Archaean (2761-2702 Ma) plutonic arc formed above a north-dipping subduction zone. Anatexis (2690-2677 Ma) of leucogranodiorite and leucotonalite orthogneisses in the Opatica generated migmatites in an area of north-vergent back thrusts visible at the surface and in L ITHOPROBE seismic profile 48. Schollen diatexite migmatites occur in the thrusts and metatexite migmatites between them. The modal mineralogy, microstructure, and whole rock major, trace and oxygen isotope compositions of the protolith and migmatites were investigated to; 1) determine the melting reaction, 2) find microstructural criteria for identifying residual rocks in leucocratic systems where there is no melanosome, and 3) to determine the source of the fluid involved in anatexis. Partial melting of the protolith did not change the mineral assemblage, but the abundance of quartz and microcline both declined and plagioclase and biotite increased in the residual rocks. Quartz, plagioclase and microcline show evidence for dissolution and biotite does not. Thus, water-fluxed melting of quartz + plagioclase + microcline occurred. A mass balance indicates 25-30% partial melting. The melting reaction consumed the microcline and created essentially monomineralic domains of plagioclase. Extraction of 80-90% of the melt left a thin film of melt on the grain boundaries, and crystallization of these in the plagioclase domains created diagnostic microstructures. Microcline fills the last remaining pore space and forms high-aspect ratio crystals between plagioclases or triangular crystals at grain junctions. Quartz shows a range of morphologies, from high-aspect ratio films through the "string of beads" to isolated rounded grains, as the microstructure progressively equilibrated after crystallisation. Most accessory phases, including zircon, remained in the residuum. However, almost all the schollen migmatites have high contents of Th, U, Nb, Ta and REE

  9. Melt Extraction Zones in Shallow Arc Plutons: Insights from Fisher Lake Orbicules and Comb Layers, Northern Sierra Nevada

    NASA Astrophysics Data System (ADS)

    McCarthy, A. J.; Muntener, O.

    2015-12-01

    Identifying the processes behind magma flow structures and complex sheeted zones within otherwise near-homogeneous shallow plutons is fundamental in order to understand the mechanisms of melt transport, magma differentiation, crustal recycling and growth of mid-upper crustal plutons. The Cretaceous gabbro-diorite pluton of Fisher Lake, Northern Sierra Nevada (USA), contains multiple m-sized orbicule and magma-breccia bodies as well as orbicule- and comb layer-bearing dikes. Olivine-bearing norites, hornblende diorites and gabbros which have crystallized at low pressure (2kbar) from hydrous basaltic-andesite melts form texturally diverse orbicule cores which act as nuclei for comb layers. Rising hydrous mafic melts remobilizing low pressure cumulates and/or crystal mushes are injected at the contact between cooling plutons prior to the initiation of comb layer growth. Multiple generations of melt injections are attested by the presence of magma-breccia bodies which incorporate fractured, disaggregated fragments of pre-existing orbicule and comb layer bodies. The cumulate signature of the orbicule-bearing matrix indicates that interstitial melt was extracted towards shallower depth. Though orbicule and comb layer bodies have been variously ascribed to melt migration within cooling plutons, magma mixing or fluid flow, we propose an alternative interpretation where these m-scale features represent localized subvertical channels formed during the extraction of multiple batches of hydrous melts within a volcanic plumbing system or shallow plutonic feeder zone. These features thus preserve unique evidence of upper-crustal melt migration processes during the transfer of hydrous mafic melts towards shallower depth. Geochemical gradients between decompressing liquids and crystallizing cumulates are the main driving force for crystallization. We will illustrate examples of this process on the basis of field observations, textural data, whole rock and mineral geochemistry.

  10. A petrologic and isotopic study of lodranites: Evidence for early formation as partial melt residues from heterogeneous precursors

    NASA Astrophysics Data System (ADS)

    McCoy, T. J.; Keil, K.; Clayton, R. N.; Mayeda, T. K.; Bogard, D. D.; Garrison, D. H.; Wieler, R.

    1997-02-01

    We have conducted petrologic, chemical, and isotopic studies of lodranites in an attempt to constrain their genesis. Lodran, Gibson, Y-791491, Y-791493, Y-74357, Y-8002, Y-75274, MAC 88177, LEW 88280, EET 84302, FRO 90011, and QUE 93148 are classified as lodranites. Lodranites and acapulcoites are indistinguishable on the basis of oxygen isotopic compositions but are distinct in average grain sizes of their mafic silicates, with lodranites being significantly coarser-grained. Lodranites exhibit a diverse range of petrologic and mineralogic features: they range widely in mafic silicate compositions (Fa 3-13), plagioclase (0-11.4 vol%), Fe,Ni metal (0.5-20 vol%), and troilite (0.2-5.3 vol%) contents; and shock levels (S1-S4) . They appear to have experienced high peak temperatures and rapid cooling in the temperature range recorded by metallographic cooling rates (i.e., 700-350°C). The only dated lodranite, Gibson, cooled to Ar closure temperatures at 4.49 ± 0.01 Ga. Lodranites formed from chemically and isotopically heterogeneous precursors in which the mineral and oxygen isotopic compositions were correlated. Heating of their parent body to temperatures between ˜ 1050-1200°C resulted in formation of Fe,NiFeS and basaltic partial melts. Depletions of troilite and/ or plagioclase in most lodranites testify to the removal of some of these partial melts, although melt migration was complex. Lodranites appear to have experienced a complex cooling history of slow cooling at high temperatures, followed by rapid cooling at intermediate temperatures, possibly related to breakup of the parent body. Lodranites were liberated from their parent body during 1-3 impact events, with most having cosmic ray exposure ages of 5.5-7 Ma. The acapulcoites are samples from the same parent body but were heated to lower temperatures and, thus, experienced lower degrees of partial melting.

  11. Fluid-Melt-Crust Interactions Beneath The Andean Arc: Textures, Crystal Zoning and CO2- Inclusions In Gabbroic Xenoliths From San Pedro Volcano (SVZ)

    NASA Astrophysics Data System (ADS)

    Ginibre, C.; Dungan, M. A.

    2006-12-01

    Crustal sections beneath active continental arcs are `percolation columns' in which the crust is continuously under modification by pluton emplacement, circulating fluids, and interactions with ascending magmas. Amphibole- and phlogopite-bearing gabbroic xenoliths from a Holocene dacite of V. San Pedro have been interpreted as formed by the reaction of a hydrous silicic melt with a partly solidified cumulate pile (Costa et al. 2001). Optical microscopy and back-scattered electron images reveal complex textures including partial melt zones, numerous arrays of secondary fluid inclusions, and, in some samples, melt inclusions, mainly in olivine. Three main stages are identified. (1) Metasomatism of original gabbroic cumulates leads to the formation of poikilitic hornblende, micas, orthopyroxene and sodic plagioclase by reaction of olivine, plagioclase and possibly clinopyroxene with hydrous melt. (2) Fluid infiltration along cracks, now preserved as fluid-bearing healed microfractures affects olivine, most orthopyroxene, clinopyroxene, plagioclase and first stage amphibole. (3) Destabilization and melting, mainly of the hydrous minerals, occur during the remobilization in the host lava, associated with new mineral growth. Amphibole, orthopyroxene, olivine, and sodic feldspar produced in stage (3) resemble those from stage (1) but lack fluid inclusions. Fracture and melt migration at this stage is observed as veinlets cross-cutting various minerals. Inclusions analysed by Raman spectroscopy and microthermometry contain CO2 fluids with a small amount of N2. Their low density, below the critical density, implies equilibration at pressures lower than 2 kbar. Variations between inclusion arrays suggests several generations of fluids under variable conditions. LA ICPMS data of inclusions in olivine show low trace element contents in early, dense inclusions and more trace elements (Th, Sr, Pb) in late, very low-density fluids suggesting possibly aqueous fluid (although not

  12. A New Approach for Studying Softening and Melting Behavior of Particles in a Blast Furnace Cohesive Zone

    NASA Astrophysics Data System (ADS)

    Yang, Wenjing; Zhou, Zongyan; Pinson, David; Yu, Aibing

    2015-04-01

    The cohesive zone where ferrous burden materials soften and melt plays a critical role in determining the performance and stability of a blast furnace. The softening and melting behavior of ore particles significantly affects the layer permeability and structure, and subsequently changes the gas/liquid distribution and heat transfer in the cohesive zone. Wax balls are often used in physical experiments to study the ore softening and melting behavior because of their low melting temperature. In this work, a new approach on the basis of discrete element method is established. The relationship between Young's modulus ( E) and temperature ( T) of wax balls is first proposed based on the experimental data, and then implemented into a DEM model. The particle deformation, temperature, coordination number, and gas pressure drop under conditions relevant to blast furnace operations are then examined. The results show that the proposed approach can capture the main features of softening and melting behavior of particles. On this basis, the effects of a few variables are investigated. The approach and results should be useful to the establishment of a comprehensive picture about softening and melting behavior, and its effect on blast furnace operations.

  13. Partial melting of the St. Severin (LL) and Lost City (H) ordinary chondrites: One step backwards and two steps forward

    NASA Technical Reports Server (NTRS)

    Jurewicz, A. J. G.; Jones, J. H.; Mittlefehldt, D. W.

    1994-01-01

    This study looks at partial melting in H and LL chondrites at nearly one atmosphere of total pressure as part of a continuing study of the origins of basaltic achondrites. Previously, melting experiments on anhydrous CM and CV chondrites showed that, near its solidus, the CM chondrite produced melts having major element chemistries similar to the Sioux County eucrite; but, the pyroxenes in the residuum were too iron-rich to form diogenites. Our preliminary results from melting experiments on ordinary (H, LL) chondrites suggested that, although the melts did not look like any known eucrites, pyroxenes from these charges bracketed the compositional range of pyroxenes found in diogenites. We had used the Fe/Mg exchange coefficients calculated for olivine, pyroxene, and melt in these charges to evaluate the approach to equilibrium, which appeared to be excellent. Unfortunately, mass balance calculations later indicated to us that, unlike our CM and CV charges, the LL and H experimental charges had lost significant amounts of iron to their (Pt or PtRh) supports. Apparently, pyroxene stability in chondritic systems is quite sensitive to the amount of FeO, and it was this unrecognized change in the bulk iron content which had stabilized the high temperature, highly magnesian pyroxenes. Accordingly, this work reinvestigates the phase equilibria of ordinary chondrites, eliminating iron and nickel loss, and reports significant differences. It also looks closely at how the iron and sodium in the bulk charge affect the stability of pyroxene, and it comments on how these new results apply to the problems of diogenite and eucrite petrogenesis.

  14. Snow distribution, melt and surface water inputs to the soil in the mountain rain-snow transition zone

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The timing, magnitude, and spatial distribution of snow cover and the resulting surface water inputs (SWI) are quantified for a catchment in the rain-snow transition zone. Although the timing of melt events are similar across the basin, southwest facing slopes receive smaller and more frequent SWI ...

  15. Low-Degree Partial Melting Experiments of CR and H Chondrite Compositions: Implications for Asteroidal Magmatism Recorded in GRA 06128 and GRA 06129 T

    NASA Technical Reports Server (NTRS)

    Usui, T.; Jones, John H.; Mittlefehldt, D. W.

    2010-01-01

    Studies of differentiated meteorites have revealed a diversity of differentiation processes on their parental asteroids; these differentiation mechanisms range from whole-scale melting to partial melting without the core formation [e.g., 1]. Recently discovered paired achondrites GRA 06128 and GRA 06129 (hereafter referred to as GRA) represent unique asteroidal magmatic processes. These meteorites are characterized by high abundances of sodic plagioclase and alkali-rich whole-rock compositions, implying that they could originate from a low-degree partial melt from a volatile-rich oxidized asteroid [e.g., 2, 3, 4]. These conditions are consistent with the high abundances of highly siderophile elements, suggesting that their parent asteroid did not segregate a metallic core [2]. In this study, we test the hypothesis that low-degree partial melts of chondritic precursors under oxidizing conditions can explain the whole-rock and mineral chemistry of GRA based on melting experiments of synthesized CR- and H-chondrite compositions.

  16. The dynamics of melt and shear localization in partially molten aggregates.

    PubMed

    Katz, Richard F; Spiegelman, Marc; Holtzman, Benjamin

    2006-08-10

    The volcanoes that lie along the Earth's tectonic boundaries are fed by melt generated in the mantle. How this melt is extracted and focused to the volcanoes, however, remains an unresolved question. Here we present new theoretical results with implications for melt focusing beneath mid-ocean ridges. By modelling laboratory experiments, we test a formulation for magma dynamics and provide an explanation for localized bands of high-porosity and concentrated shear deformation observed in experiments. These bands emerge and persist at 15 degrees-25 degrees to the plane of shear. Past theoretical work on this system predicted the emergence of melt bands but at an angle inconsistent with experiments. Our results suggest that the observed band angle results from a balance of porosity-weakening and strain-rate-weakening deformation mechanisms. Lower band angles are predicted for greater strain-rate weakening. From these lower band angles, we estimate the orientation of melt bands beneath mid-ocean ridges and show that they may enhance magma focusing toward the ridge axis.

  17. Iron isotope fractionation during sulfide-rich felsic partial melting in early planetesimals

    NASA Astrophysics Data System (ADS)

    Wang, Kun; Day, James M. D.; Korotev, Randy L.; Zeigler, Ryan A.; Moynier, Frédéric

    2014-04-01

    New Fe isotope data of feldspar-rich meteorites Graves Nunataks 06128 and 06129 (GRA 06128/9) reveal that they are the only known examples of crustal materials with isotopically light Fe isotope compositions (δFe56=-0.08±0.06‰; δ56Fe is defined as the per mille deviation of a sample's 56Fe/54Fe ratio from the IRMM-014 standard) in the Solar System. In contrast, associated brachinites, as well as brachinite-like achondrites, have Fe isotope compositions (δFe56=+0.01±0.02‰) that are isotopically similar to carbonaceous chondrites and the bulk terrestrial mantle. In order to understand the cause of Fe isotope variations in the GRA 06128/9 and brachinite parent body, we also report the Fe isotope compositions of metal, silicate and sulfide fractions from three ordinary chondrites (Semarkona, Kernouve, Saint-Séverin). Metals from ordinary chondrites are enriched in the heavier isotopes of Fe (average δFe56=0.15‰), sulfide fractions are enriched in the lighter isotopes of Fe (average δFe56=-0.14‰), and the δ56Fe values of the silicates are coincident with that of the bulk rock (average δFe56=0.03‰). The enrichment of light isotopes of Fe isotopes in GRA 06128/9 is consistent with preferential melting of sulfides in precursor chondritic source materials leading to the formation of Fe-S-rich felsic melts. Conceptual models show that melt generation to form a GRA 06128/9 parental melt occurred prior to the onset of higher-temperature basaltic melting (<1200 °C) in a volatile-rich precursor and led to the generation of buoyant felsic melt with a strong Fe-S signature. These models not only reveal the origin of enrichment in light isotopes of Fe for GRA 06128/9, but are also consistent with petrological and geochemical observations, experimental studies for the origin of Fe-S-rich felsic melts, and for the cessation of early melting on some asteroidal parent bodies because of the effective removal of the major radioactive heat-source, 26Al. The mode of

  18. Geochemical characterization of migmatized orthogneiss from Porto Ottiolu (NE Sardinia, Italy) and its inferences on partial melting process

    NASA Astrophysics Data System (ADS)

    Cruciani, Gabriele; Fancello, Dario; Franceschelli, Marcello; Columbu, Stefano

    2015-04-01

    by the occurrence of myrmekitic miscrostructures between quartz and feldspar, quartz films at the feldspar interface and by albite rims around plagioclase. Some selected samples were analysed for major, minor and trace element content. The leucosomes are characterized by the following major elements content: SiO2: 72.9-76.2; Al2O3: 14.7-15.4; Fe2O3tot: 0.1-0.7; MgO: 0.1-0.3; CaO: 0.5-3.2; Na2O: 2.4-3.5; K2O: 4.0-8.6 wt%. The noticeable wide range in CaO and K2O is related to the high variability of the plagioclase/K-feldspar ratio. Most leucosomes have granitic composition, except for those occurring along shear zones that have tonalitic composition. Mesosomes major elements contents are SiO2 ca. 70; Al2O3: 14.4-15.1; Fe2O3tot: 2.1-3.4; MgO ca. 1.0; CaO ca. 3.0; Na2O ca. 3.5; K2O ca. 2.6 wt.%. They have granodioritic compositions. All leucosome and mesosome samples are corundum normative. Chondrite-normalized REE patterns of leucosomes are characterized by a marked positive Eu anomaly and by LREE enrichment. Mesosomes are characterized by marked negative Eu anomalies, as well as by LREE and HREE enrichment. ∑REE is higher in mesosomes (153 ppm) than in leucosomes (20-63 ppm). Field relationships, microstructural and geochemical data support the hypothesis that migmatization was generated by partial melting of a probaby Ordovician granitoid. The origin of the various types of leucosome has been discussed.

  19. Growth of GaAs from a free surface melt under controlled arsenic pressure in a partially confined configuration

    NASA Technical Reports Server (NTRS)

    Gatos, H. C.; Lagowski, J.; Wu, Y.

    1988-01-01

    A partially confined configuration for the growth of GaAs from melt in space was developed, consisting of a triangular prism containing the seed crystal and source material in the form of a rod. It is suggested that the configuration overcomes two obstacles in the growth of GaAs in space: total confinement in a quartz crucible and lack of arsenic pressure control. Ground tests of the configuration show that it is capable of crystal growth in space and is useful for studying the growth of GaAs from a free-surface melt on earth. The resulting chemical composition, electrical property variations, and phenomenological models to account for the results are presented.

  20. Trace element evidence for anatexis at oceanic magma chamber roofs and the role of partial melts for contamination of fresh MORB

    NASA Astrophysics Data System (ADS)

    Fischer, Lennart A.; Erdmann, Martin; France, Lydéric; Wolff, Paul E.; Deloule, Etienne; Zhang, Chao; Godard, Marguerite; Koepke, Jürgen

    2016-09-01

    At oceanic spreading centers, interactions between magma and hydrothermal convecting systems trigger major physical, thermal, and chemical exchanges. The two-pyroxene hornfels recovered from the base of the sheeted dike sequence at Integrated Ocean Drilling Program (IODP) Site 1256 (equatorial Eastern Pacific) are interpreted as a conducting boundary layer between the underlying axial melt lens and the hydrothermally cooled sheeted dikes. They are cut by numerous small, felsic veins, which were recently interpreted as a product of hydrous partial melting of sheeted dikes. Here, we present trace element compositions of products (melts and residues) of hydrous partial melting experiments using basalts and hornfels from IODP Site 1256 as starting material. The experimental products generated between 910 °C and 970 °C match the natural lithologies from Site 1256 in terms of major and trace element compositions. The compositions of the anatectic melts correspond to the compositions of the felsic veins, while the residual minerals match the compositions of the two-pyroxene hornfels, evidencing that hydrous partial melting is an important magmatic process in the gabbro/dike transition of fast-spreading mid-oceanic ridges. Our results complement previous experimental studies on anatectic processes occurring at the roof of the magma chambers from fast-spreading mid-ocean ridges. Moreover, calculations of mixing and assimilation fractional crystallization using the experimental partial melts as contaminant/assimilant showed that anatectic melts can only be a minor contributor to the contamination process.

  1. Controlled alternate partial root-zone irrigation: its physiological consequences and impact on water use efficiency.

    PubMed

    Kang, Shaozhong; Zhang, Jianhua

    2004-11-01

    Controlled alternate partial root-zone irrigation (CAPRI), also called partial root-zone drying (PRD) in other literature, is a new irrigation technique and may improve the water use efficiency of crop production without significant yield reduction. It involves part of the root system being exposed to drying soil while the remaining part is irrigated normally. The wetted and dried sides of the root system are alternated with a frequency according to soil drying rate and crop water requirement. The irrigation system is developed on the basis of two theoretical backgrounds. (i) Fully irrigated plants usually have widely opened stomata. A small narrowing of the stomatal opening may reduce water loss substantially with little effect on photosynthesis. (ii) Part of the root system in drying soil can respond to the drying by sending a root-sourced signal to the shoots where stomata may be inhibited so that water loss is reduced. In the field, however, the prediction that reduced stomatal opening may reduce water consumption may not materialize because stomatal control only constitutes part of the total transpirational resistance. The boundary resistance from the leaf surface to the outside of the canopy may be so substantial that reduction in stomatal conductance is small and may be partially compensated by the increase in leaf temperature. It is likely that densely populated field crops, such as wheat and maize, may have a different stomatal control over transpiration from that of fruit trees which are more sparsely separated. It was discussed how long the stomata can keep 'partially' closed when a prolonged and repeated 'partial' soil drying is applied and what role the rewatering-stimulated new root growth may play in sensing the repeated soil drying. The physiological and morphological alternation of plants under partial root-zone irrigation may bring more benefits to crops than improved water use efficiency where carbon redistribution among organs is crucial to the

  2. Field and Geochronological Evidence of Partial Melting, Melt Mobilisation and - in a 2.7 GA Metatexite-Diatexite Complex in Troms, Northern Norway

    NASA Astrophysics Data System (ADS)

    Slagstad, T.

    2013-12-01

    diatexite host, and suggest that the latter had a melt-dominated rheology. Abundant pegmatite collected in the spaces between and around the blocks demonstrating that copious melt was available in the system and that ongoing deformation led to pressure differences facilitating melt mobility. The granites are heterogeneous, displaying a diffusely to sharply defined compositional, dm-thick layering. The darker layers can locally be identified as metatexite, and where strain is relatively low, several-dm-long, biotite-rich schlieren are observed. In one place, two enclaves of amphibolite are connected by a 3-4 m-long irregular string of amphibolite. Although field relationships do not exist to demonstrate a genetic relationship between meta-/diatexite and the granitic gneisses, these relationships along with the geochronological data suggest that such a link is likely. Ongoing work aims to demonstrate and characterise the link between partial melting and granite formation in this Neoarchean, Fennoscandian terrain.

  3. Seismic Evidence of Localized Distribution of Fluids or Melts in the Mantle Transition Zone

    NASA Astrophysics Data System (ADS)

    Tajima, F.; Nakagawa, T.

    2009-04-01

    waveforms did not show such anomaly. The waveform modeling was carried out up to 1 Hz using a finite difference code. Results indicate that a highly localized LVA zone (about -10% anomaly) is responsible for broadening the P waveforms. The LVA zones may indicate fluids dehydrated from hydrous mineral compositions or melts through the phase transformation at the bottom of the MTZ. A number of studies propose that a certain amount of water can be transported through the subduction process, and stored in the MTZ as the lower mantle minerals may not include much water (e.g., Ohtani et al., 2004). However, the distribution or fate of "water" dehydrated from minerals which are descending further into the lower mantle has been known little. On the other hand a recent study suggests that the MTZ may be dry based on the electrical conductivity modeling (Yoshino et al., 2008). We suggest that if the distribution of transported water is very localized in the MTZ, then the debates do not have to be contradictory to each other.

  4. Partially-overlapped viewing zone based integral imaging system with super wide viewing angle.

    PubMed

    Xiong, Zhao-Long; Wang, Qiong-Hua; Li, Shu-Li; Deng, Huan; Ji, Chao-Chao

    2014-09-22

    In this paper, we analyze the relationship between viewer and viewing zones of integral imaging (II) system and present a partially-overlapped viewing zone (POVZ) based integral imaging system with a super wide viewing angle. In the proposed system, the viewing angle can be wider than the viewing angle of the conventional tracking based II system. In addition, the POVZ can eliminate the flipping and time delay of the 3D scene as well. The proposed II system has a super wide viewing angle of 120° without flipping effect about twice as wide as the conventional one.

  5. From partial melting to retrogression in the Pointe Geologie migmatitic complex: a history of heterogeneous distribution of fluids

    NASA Astrophysics Data System (ADS)

    Pelletier, Anne; Guiraud, Michel; Menot, René-Pierre

    2005-04-01

    In the Pointe Géologie area (66°40 S; 140°00 E; Terre Adélie, East Antarctica), the Paleoproterozoic basement consists in a migmatitic complex of metasedimentary origin. Metasediments underwent a thermal event, leading to the high-grade amphibolite facies assemblages biotite-cordierite-sillimanite and to dehydration melting reactions at 4-6 kbar and 700±50 °C, followed by retrogression in greenschist facies. In most of the archipelago, K-feldspar gneisses (KFG) are characterized by a Sil+Crd+Kfs+Bt assemblage and many K-feldspar-rich leucosomes. Locally, a spectacular rock type occurs as North dipping bands of about 10 m thick and consists in nodular gneisses (NG) that display less abundant, K-feldspar-poor leucosomes. Commonly, the retrograde imprint facies is quite weak in KFG and only expressed by sporadic Bt-Ms±And equilibrium assemblage, whereas it developed more extensively in NG. A pseudosection calculated at constant P=4 kbar shows that the differences between NG and KFG assemblages can be considered to be mainly driven by difference in H 2O proportions and much less by differences in FeO/MgO or K 2O/MgO ratios. The hydrated assemblage (Bt-Ms nodules) in NG requires at least 10-20% more H 2O than the Crd+Kfs+Sil/And assemblage does in KFG. Parageneses and mineral compositions indicate that this difference in H 2O occurred early in the history, at least as early as the anatectic stage. Therefore, differences between NG and KFG are related to the variation in partial melting features (water distribution, proportion of melt extraction), which appears to be spatially controlled by cryptic tectonic structures. The particular shape and orientation of NG bands are interpreted as a complex history of melt extraction in the Pointe Géologie area which could involve a two stage melting process.

  6. The effect of bulk composition on the solidus of carbonated eclogite from partial melting experiments at 3 GPa

    NASA Astrophysics Data System (ADS)

    Dasgupta, Rajdeep; Hirschmann, Marc M.; Dellas, Nikki

    2005-05-01

    To explore the effect of bulk composition on the solidus of carbonated eclogite, we determined near-solidus phase relations at 3 GPa for four different nominally anhydrous, carbonated eclogites. Starting materials (SLEC1, SLEC2, SLEC3, and SLEC4) were prepared by adding variable proportions and compositions of carbonate to a natural eclogite xenolith (66039B) from Salt Lake crater, Hawaii. Near-solidus partial melts for all bulk compositions are Fe Na calcio-dolomitic and coexist with garnet + clinopyroxene + ilmenite ± calcio-dolomitic solid solution. The solidus for SLEC1 (Ca#=100 × molar Ca/(Ca + Mg + FeT)=32, 1.63 wt% Na2O, and 5 wt% CO2) is bracketed between 1,050°C and 1,075°C (Dasgupta et al. in Earth Planet Sci Lett 227:73 85, 2004), whereas initial melting for SLEC3 (Ca# 41, 1.4 wt% Na2O, and 4.4 wt% CO2) is between 1,175°C and 1,200°C. The solidus for SLEC2 (Ca# 33, 1.75 wt% Na2O, and 15 wt% CO2) is estimated to be near 1,100°C and the solidus for SLEC3 (Ca# 37, 1.47 wt% Na2O, and 2.2 wt% CO2) is between 1,100°C and 1,125°C. Solidus temperatures increase with increasing Ca# of the bulk, owing to the strong influence of the calcite magnesite binary solidus-minimum on the solidus of carbonate bearing eclogite. Bulk compositions that produce near-solidus crystalline carbonate closer in composition to the minimum along the CaCO3-MgCO3 join have lower solidus temperatures. Variations in total CO2 have significant effect on the solidus if CO2 is added as CaCO3, but not if CO2 is added as a complex mixture that maintains the cationic ratios of the bulk-rock. Thus, as partial melting experiments necessarily have more CO2 than that likely to be found in natural carbonated eclogites, care must be taken to assure that the compositional shifts associated with excess CO2 do not unduly influence melting behavior. Near-solidus dolomite and calcite solid solutions have higher Ca/(Ca + Mg) than bulk eclogite compositions, owing to Ca Mg exchange equilibrium

  7. Transport Property Measurements in Doped Bi2Te3 Single Crystals Obtained via Zone Melting Method

    NASA Astrophysics Data System (ADS)

    Jariwala, Bhakti; Shah, Dimple; Ravindra, N. M.

    2015-06-01

    Single crystals of Se- and Fe-doped Bi2Te3 have been synthesized via the zone melting method. Energy-dispersive x-ray and x-ray powder diffraction analyses have been carried out to identify the constituent elements and determine the lattice parameters of the grown crystals. Surface topological features of the as-grown single crystals have been studied. The transport properties of doped stoichiometric Bi2Te3 single crystals have been studied by measuring the thermoelectric power and electrical conductivity in the temperature range from 303 K to 473 K. The thermoelectric power, S, effective mass, scattering parameter, and Fermi energy have been calculated from thermoelectric power measurements. The temperature dependence of the electrical conductivity, σ, shows that the dopants in the crystals are thermally activated. All the crystals exhibit semiconducting behavior as confirmed by the temperature dependence of σ and S. The effective mass of electrons and the effective density of states have been determined and are reported for Bi2Te3- x Se x (0 ≤ x ≤ 0.3) and Bi2- y Fe y Te3 (0 ≤ y ≤ 0.3).

  8. Coupled thermodynamic and two-phase flow modelling of partially melting crust

    NASA Astrophysics Data System (ADS)

    Riel, Nicolas; Bouilhol, Pierre; Magni, Valentina; van Hunen, Jeroen; Velic, Mirko

    2016-04-01

    How magmas are formed, transferred and interact in the lower crust to form mid-crust plutonic belts remain a fundamental question to understand the chemical and mechanical evolution of continents. To assess this question we developed a 2-D two-phase flow code using finite volume method. Our formulation takes into account: (i) an extended Darcy's law for fluid flow with first order temperature- and fluid-content dependency for the host-rock viscosity and silica-dependent viscosity for the fluid, (ii) the heat equation assuming thermal equilibrium for both solid and liquid and temperature-dependent diffusivity, (iii) thermodynamic modelling of stable phases via a dynamic coupling with Perple_X, and (iv) chemical advection of both the solid and liquid composition. To model chemical interactions with the host rock during magma transport, the melt is assumed to be either in thermodynamic equilibrium or in thermodynamic disequilibrium, or as function of these two endmembers. We applied our modelling approach to investigate the behaviour and composition of magma during lower crust melting. Our goal is to better understand the formation of felsic crust through melting, segregation and assimilation of lower crustal lithologies, applied to Archaean systems. Our preliminary results show the ascend of silica-rich magmas is slow, occurring on the timescale of millions of years, and is highly controlled by (i) the melting curve of the protolith and (ii) by its chemical degree of interaction with the host rock. The resulting transferred magmas are in good accordance with observed composition forming the grey gneisses of Archean terranes (i.e SiO2-rich > 62%, Mg# = 40-50, Na2O ~6%, MgO = 0.5-1%).

  9. Geochemistry, Metamorphism, and Partial Melting of Hydrothermally Altered Rocks in the Sherridon Complex, Trans Hudson Orogen, Manitoba

    NASA Astrophysics Data System (ADS)

    Tinkham, D. K.

    2009-05-01

    Lithogeochemistry and field investigations of regionally metamorphosed rocks in the central portion of the Sherridon Complex of the Trans-Hudson orogen indicates high-grade gneisses are dominantly derived from protoliths with rhyodacite and basaltic compositions that subsequently experienced pre-metamorphic seafloor- related hydrothermal alteration. Immobile trace element geochemistry results indicate the voluminous rhyodacite composition rocks formed in a volcanic arc environment, and associated VMS deposits and less voluminous basaltic composition rocks suggest a bimodal-felsic VMS environment. Felsic lithologies are interpreted to have experienced local pre-metamorphic sericite, chlorite, carbonate, and possible silica alteration, with an extensive zone of carbonate alteration associated with more basaltic-composition protoliths. Upper amphibolite facies metamorphism of hydrothermally altered felsic lithologies resulted in a variety of quartz-rich rocks containing combinations of gahnite, garnet, cordierite, sillimanite, orthoamphibole, biotite, and feldspar bearing assemblages. An extensive garnet-cordierite-sillimanite-biotite ± orthoamphibole quartz-rich gneiss unit (GCSB) grades into a stromatic migmatite with a modal decrease in garnet and sillimanite in the host gneiss. Cordierite commonly overgrows and locally completely replaces sillimanite. Increased amounts of melting results in very local diatexite and locally mobilized melt crystallizing to a massive biotite clotted granitoid. The biotite-rich clots in the granitoid are interpreted to have resulted from replacement of garnet ± cordierite within the melt based on their shape, small remnants of garnet, and local sillimanite. Phase equilibria modelling of a suite of GCSB rocks (average Mg# = 0.55) in the MnNCKFMASHT chemical system utilizing program Domino predicts pressures in excess of 5.5 kilobars for sillimanite stability, and is most compatible with pressures between 6.5-7.0 kilobars based on

  10. Partial re-equilibration of highly siderophile elements and the chalcogens in the mantle: A case study on the Baldissero and Balmuccia peridotite massifs (Ivrea Zone, Italian Alps)

    NASA Astrophysics Data System (ADS)

    Wang, Zaicong; Becker, Harry; Gawronski, Timo

    2013-05-01

    The conditions at which melt percolation and reactive infiltration of depleted mantle peridotites fractionate highly siderophile elements (HSE) and cause re-equilibration of 187Os/188Os in mantle rocks are still poorly constrained. In a comparative study of the Paleozoic Balmuccia (BM) and Baldissero (BD) peridotite tectonites (Ivrea-Verbano Zone, Northern Italy), the influence of partial melting and melt infiltration on abundances of HSE, chalcogens (S, Se and Te) and 187Os/188Os have been studied. At BM, Re depletion ages (TRD) of lherzolites and replacive dunites display a uniform distribution with a maximum near 400-500 Ma. BD peridotites also display a Paleozoic distribution peak but a significant number of samples yielded Proterozoic TRD. The predominance of Paleozoic Re depletion ages in both bodies is consistent with Sm-Nd ages and the late Paleozoic magmatic and geodynamic evolution of the Ivrea-Verbano Zone. The different extents of preservation of ancient 187Os/188Os in BM and BD peridotites are interpreted to reflect different degrees of isotopic homogenization and chemical re-equilibration with incompatible element-depleted infiltrating melt during the Paleozoic. The differences between the two bodies are also reflected by differences in HSE and chalcogen abundances, with BD displaying large scatter among HSE patterns, slight re-enrichment of Re relative to Au, and linear trends of Pd, Se and Te with Al2O3. The differences in distributions of model ages and heterogeneity in HSE abundances support the view that the lithophile element, HSE and chalcogen variations of different suites of lherzolites likely reflect different extents of reactive melt infiltration in mantle peridotites, with partial re-equilibration and melt extraction in open system environments. However, the variable re-equilibration of BM and BD lherzolites apparently did not produce significant differences in HSE ratios such as Os/Ir, Ru/Ir, Rh/Ir, and Pd/Pt, which are in the range of

  11. Reductions in contaminant mass discharge following partial mass removal from DNAPL source zones.

    PubMed

    Suchomel, Eric J; Pennell, Kurt D

    2006-10-01

    Although in situ remediation technologies have been used to aggressively treat dense nonaqueous phase liquid (DNAPL) source zones, complete contaminant removal or destruction is rarely achieved. To evaluate the effects of partial source zone mass removal on dissolved-phase contaminant flux, four experiments were conducted in a two-dimensional aquifer cell that contained a tetrachloroethene (PCE) source zone and down-gradient plume region. Initial source zone PCE saturation distributions, quantified using a light transmission system, were expressed in terms of a ganglia-to-pool ratio (GTP), which ranged from 0.16 (13.8% ganglia) to 1.6 (61.5% ganglia). The cells were flushed sequentially with a 4% (wt.) Tween 80 surfactant solution to achieve incremental PCE mass removal, followed by water flooding until steady-state mass discharge and plume concentrations were established. In all cases, the GTP ratio decreased with increasing mass removal, consistent with the observed preferential dissolution of PCE ganglia and persistence of high-saturation pools. In the ganglia-dominated system (GTP = 1.6), greater than 70% mass removal was required before measurable reductions in plume concentrations and mass discharge were observed. For pool-dominated source zones (GTP < 0.3), substantial reductions (>50%) in mass discharge were realized after only 50% mass removal.

  12. A partial melting study of an ordinary (H) chondrite composition with application to the unique achondrite Graves Nunataks 06128 and 06129

    NASA Astrophysics Data System (ADS)

    Usui, Tomohiro; Jones, John H.; Mittlefehldt, David W.

    2015-04-01

    Melting experiments of a synthesized, alkali-bearing, H-chondrite composition were conducted at ambient pressure with three distinct oxygen fugacity conditions (IW-1, IW, and IW+2). Oxygen fugacity conditions significantly influence the compositions of partial melts. Partial melts at IW-1 are distinctly enriched in SiO2 relative to those of IW and IW+2 melts. The silica-enriched, reduced (IW-1) melts are characterized by high alkali contents and have silica-oversaturated compositions. In contrast, the silica-depleted, oxidized (≥IW) melts, which are also enriched in alkali contents, have distinctly silica-undersaturated compositions. These experimental results suggest that alkali-rich, felsic, asteroidal crusts as represented by paired achondrites Graves Nunataks 06128 and 06129 should originate from a low-degree, relatively reduced partial melt from a parent body having near-chondritic compositions. Based on recent chronological constraints and numerical considerations as well as our experimental results, we propose that such felsic magmatism should have occurred in a parent body that is smaller in size and commenced accreting later than those highly differentiated asteroids having basaltic crusts and metallic cores.

  13. Multiple episodes of partial melting, depletion, metasomatism and enrichment processes recorded in the heterogeneous upper mantle sequence of the Neotethyan Eldivan ophiolite, Turkey

    NASA Astrophysics Data System (ADS)

    Uysal, Ibrahim; Ersoy, E. Yalçın; Dilek, Yildirim; Kapsiotis, Argyrios; Sarıfakıoğlu, Ender

    2016-03-01

    The Eldivan ophiolite along the Izmir-Ankara-Erzincan suture zone in north-central Anatolia represents a remnant of the Neotethyan oceanic lithosphere. Its upper mantle peridotites include three lithologically and compositionally distinct units: clinopyroxene (cpx)-harzburgite and lherzolite (Group-1), depleted harzburgite (Group-2), and dunite (Group-3). Relics of primary olivine and pyroxene occur in the less refractory harzburgites, and fresh chromian spinel (Cr-spinel) is ubiquitous in all peridotites. The Eldivan peridotites reflect a petrogenetic history evolving from relatively fertile (lherzolite and cpx-harzburgite) toward more depleted (dunite) compositions through time, as indicated by (i) a progressive decrease in the modal cpx distribution, (ii) a progressive increase in the Cr#s [Cr / (Cr + Al)] of Cr-spinel (0.15-0.78), and (iii) an increased depletion in the whole-rock abundances of some magmaphile major oxides (Al2O3, CaO, SiO2 and TiO2) and incompatible trace elements (Zn, Sc, V and Y). The primitive mantle-normalized REE patterns of the Group-1 and some of the Group-2 peridotites display LREE depletions. Higher YbN and lower SmN/YbN ratios of these rocks are compatible with their formation after relatively low degrees (9-25%) of open-system dynamic melting (OSDM) of a Depleted Mid-ocean ridge Mantle (DMM) source, which was then fluxed with small volumes of oceanic mantle-derived melt [fluxing ratio (β): 0.7-1.2%]. Accessory Cr-spinel compositions (Cr# = 015-0.53) of these rocks are consistent with their origin as residual peridotites beneath a mid-ocean ridge axis. Part of the Group-2 harzburgites exhibit lower YbN and higher SmN/YbN ratios, LREE-enriched REE patterns, and higher Cr-spinel Cr#s ranging between 0.54 and 0.61. Trace element compositions of these peridotites can be modeled by approximately 15% OSDM of a previously 17% depleted DMM, which was then fluxed (β: 0.4%) with subduction-influenced melt. The Group-3 dunite samples contain

  14. Carbon dioxide partial pressure and 13C content of north temperate and boreal lakes at spring ice melt

    USGS Publications Warehouse

    Striegl, R.G.; Kortelainen, Pirkko; Chanton, J.P.; Wickland, K.P.; Bugna, G.C.; Rantakari, M.

    2001-01-01

    Carbon dioxide (CO2) accumulates under lake ice in winter and degasses to the atmosphere after ice melt. This large springtime CO2 pulse is not typically considered in surface-atmosphere flux estimates, because most field studies have not sampled through ice during late winter. Measured CO2 partial pressure (pCO2) of lake surface water ranged from 8.6 to 4,290 Pa (85-4,230 ??atm) in 234 north temperate and boreal lakes prior to ice melt during 1998 and 1999. Only four lakes had surface pCO2 less than or equal to atmospheric pCO2, whereas 75% had pCO2 >5 times atmospheric. The ??13CDIC (DIC = ??CO2) of 142 of the lakes ranged from -26.28??? to +0.95.???. Lakes with the greatest pCO2 also had the lightest ??13CDIC, which indicates respiration as their primary CO2 source. Finnish lakes that received large amounts of dissolved organic carbon from surrounding peatlands had the greatest pCO2. Lakes set in noncarbonate till and bedrock in Minnesota and Wisconsin had the smallest pCO2 and the heaviest ??13CDIC, which indicates atmospheric and/or mineral sources of C for those lakes. Potential emissions for the period after ice melt were 2.36 ?? 1.44 mol CO2 m-2 for lakes with average pCO2 values and were as large as 13.7 ?? 8.4 mol CO2 m-2 for lakes with high pCO2 values.

  15. Evidence for partial melt in the crust beneath Mt. Paektu (Changbaishan), Democratic People's Republic of Korea and China.

    PubMed

    Kyong-Song, Ri; Hammond, James O S; Chol-Nam, Ko; Hyok, Kim; Yong-Gun, Yun; Gil-Jong, Pak; Chong-Song, Ri; Oppenheimer, Clive; Liu, Kosima W; Iacovino, Kayla; Kum-Ran, Ryu

    2016-04-01

    Mt. Paektu (also known as Changbaishan) is an enigmatic volcano on the border between the Democratic People's Republic of Korea (DPRK) and China. Despite being responsible for one of the largest eruptions in history, comparatively little is known about its magmatic evolution, geochronology, or underlying structure. We present receiver function results from an unprecedented seismic deployment in the DPRK. These are the first estimates of the crustal structure on the DPRK side of the volcano and, indeed, for anywhere beneath the DPRK. The crust 60 km from the volcano has a thickness of 35 km and a bulk V P/V S of 1.76, similar to that of the Sino-Korean craton. The V P/V S ratio increases ~20 km from the volcano, rising to >1.87 directly beneath the volcano. This shows that a large region of the crust has been modified by magmatism associated with the volcanism. Such high values of V P/V S suggest that partial melt is present in the crust beneath Mt. Paektu. This region of melt represents a potential source for magmas erupted in the last few thousand years and may be associated with an episode of volcanic unrest observed between 2002 and 2005. PMID:27152343

  16. Evidence for partial melt in the crust beneath Mt. Paektu (Changbaishan), Democratic People’s Republic of Korea and China

    PubMed Central

    Kyong-Song, Ri; Hammond, James O. S.; Chol-Nam, Ko; Hyok, Kim; Yong-Gun, Yun; Gil-Jong, Pak; Chong-Song, Ri; Oppenheimer, Clive; Liu, Kosima W.; Iacovino, Kayla; Kum-Ran, Ryu

    2016-01-01

    Mt. Paektu (also known as Changbaishan) is an enigmatic volcano on the border between the Democratic People’s Republic of Korea (DPRK) and China. Despite being responsible for one of the largest eruptions in history, comparatively little is known about its magmatic evolution, geochronology, or underlying structure. We present receiver function results from an unprecedented seismic deployment in the DPRK. These are the first estimates of the crustal structure on the DPRK side of the volcano and, indeed, for anywhere beneath the DPRK. The crust 60 km from the volcano has a thickness of 35 km and a bulk VP/VS of 1.76, similar to that of the Sino-Korean craton. The VP/VS ratio increases ~20 km from the volcano, rising to >1.87 directly beneath the volcano. This shows that a large region of the crust has been modified by magmatism associated with the volcanism. Such high values of VP/VS suggest that partial melt is present in the crust beneath Mt. Paektu. This region of melt represents a potential source for magmas erupted in the last few thousand years and may be associated with an episode of volcanic unrest observed between 2002 and 2005. PMID:27152343

  17. Evidence for partial melt in the crust beneath Mt. Paektu (Changbaishan), Democratic People's Republic of Korea and China.

    PubMed

    Kyong-Song, Ri; Hammond, James O S; Chol-Nam, Ko; Hyok, Kim; Yong-Gun, Yun; Gil-Jong, Pak; Chong-Song, Ri; Oppenheimer, Clive; Liu, Kosima W; Iacovino, Kayla; Kum-Ran, Ryu

    2016-04-01

    Mt. Paektu (also known as Changbaishan) is an enigmatic volcano on the border between the Democratic People's Republic of Korea (DPRK) and China. Despite being responsible for one of the largest eruptions in history, comparatively little is known about its magmatic evolution, geochronology, or underlying structure. We present receiver function results from an unprecedented seismic deployment in the DPRK. These are the first estimates of the crustal structure on the DPRK side of the volcano and, indeed, for anywhere beneath the DPRK. The crust 60 km from the volcano has a thickness of 35 km and a bulk V P/V S of 1.76, similar to that of the Sino-Korean craton. The V P/V S ratio increases ~20 km from the volcano, rising to >1.87 directly beneath the volcano. This shows that a large region of the crust has been modified by magmatism associated with the volcanism. Such high values of V P/V S suggest that partial melt is present in the crust beneath Mt. Paektu. This region of melt represents a potential source for magmas erupted in the last few thousand years and may be associated with an episode of volcanic unrest observed between 2002 and 2005.

  18. The partial molar sound speed of TiO2 in sodium silicate melts: Evidence for an exceptionally compressible component

    NASA Astrophysics Data System (ADS)

    Liu, Q.; Ai, Y.; Lange, R. A.

    2005-12-01

    Longitudinal acoustic velocities were measured at one bar by an ultrasonic frequency sweep acoustic interferometer for ten Na2O-TiO2-SiO2 (NTS) liquids for which previous density and thermal expansion measurements were made (Liu and Lange, 2001). This previous study showed that the partial molar volume of the TiO2 component varied systematically with composition and reflected changes in the average coordination of Ti4+ from values of ~4.6 to ~5.4. Sound speed data were collected at frequencies of 4.5, 5, and 6 MHz between 1233 and 1896 K; in all cases, the sound speeds decrease with increasing temperature. Six of the liquids share a similar (~25 mol%) TiO2 concentration, so that the effect of varying Na:Si ratio on the partial molar sound speed of the TiO2 component can be evaluated. The results for these ten NTS liquids were combined with sound speed data on Na2O-SiO2 liquids from the literature to derive the partial molar sound speed of the TiO2 component in these liquids. The results show that, at 1573 K, it is inversely correlated with SiO2 concentration, from values as low as 571±56 m/s to those as high as 1235±54 m/s, a variation of more than 100%. Fitted values for the partial molar sound speeds of the SiO2 and Na2O components at 1573 K are constants at 2538±52 and 2713±52 m/s, respectively. When the sound speed data are combined with density data to calculate melt compressibility, the results show that the TiO2 component is 3-15 more compressible than either the Na2O or SiO2 component. The partial molar compressibility of the TiO2 component is also strongly correlated to its partial molar thermal expansivity. It is shown that the TiO2 component is most compressible and most expansive when the average Ti4+ coordination in these sodium silicate liquids is near five, which strongly suggests that the abundance of five-coordinated Ti4+ enhances topological mechanisms of both compression and thermal expansion.

  19. Geochemistry and petrology of spinel lherzolite xenoliths from Xalapasco de La Joya, San Luis Potosi, Mexico: Partial melting and mantle metasomatism

    NASA Astrophysics Data System (ADS)

    Liang, Yan; Elthon, Don

    1990-09-01

    Spinel Iherzolite xenoliths from Xalapasco de La Joya, San Luis Potosi, Mexico, are divided into two distinct groups according to their major element and trace element characteristics. Group Ia xenoliths are characterized by light rare earth element (LREE) depletion ((La/Lu)N = 0.10-0.77 in clinopyroxene) and linear major and compatible trace element relationships. Group Ib xenoliths are characterized by FeO and Na2O enrichment and higher (La/Lu)N ratios (0.80-4.1 in clinopyroxene) and complex major element relationships. These samples, which have a range of equilibrium temperatures of 910°-1070°C, exhibit protogranular textures and typical orthopyroxene+clinopyroxene+spinel clusters. Modal abundances and chemical compositions of the group Ia xenoliths vary from primitive (15.2% clinopyroxene, 38.5% MgO, 1824 ppm Ni) to moderately depleted (6.4-8.7% clinopyroxene, 43.8-44.1% MgO, 2192 ppm Ni). Systematic variations of major elements and compatible trace elements in the group Ia xenoliths are interpreted to result from various degrees (<25%) of partial melting and melt extraction, followed by subsolidus equilibration and annealing. The extracted melts have a range of compositions similar to picritic basalts. Abundances of moderately incompatible trace elements, Sc and Cr, in the group Ia minerals have been substantially redistributed during subsolidus equilibration. In a few of these xenoliths there appears to be vestiges of incipient metasomatism, but metasomatism has not substantially influenced the group as a whole. Group Ib xenoliths have been substantially influenced by metasomatic processes. The ∑FeO and Na2O contents of the cores of clinopyroxenes in group Ib xenoliths are higher than clinopyroxenes in group Ia samples. The higher La contents and La/Lu ratios in group Ib clinopyroxenes (compared to group Ia), together with this FeO and Na2O enrichment, suggest that equilibration of basanites with residual mantle has been a major process in the evolution

  20. Melt extraction in mush zones: The case of crystal-rich enclaves at the Sabatini Volcanic District (central Italy)

    NASA Astrophysics Data System (ADS)

    Masotta, M.; Mollo, S.; Gaeta, M.; Freda, C.

    2016-04-01

    A peculiar feature of the Sabatini Volcanic District (SVD, central Italy) is the occurrence of crystal-poor pumices and crystal-rich enclaves within the same eruptive host-deposit. The stratigraphic sequence of pumices and enclaves indicates the tapping of a stratified magma chamber, where a crystal-poor phonolitic magma lay on top of a more primitive crystal-rich magma. The crystal-rich enclaves are genetically related to the pumices and record the evolution of a solidification front, in which a more differentiated melt was produced, extracted and eventually erupted. We collected and analyzed crystal-rich enclaves from one of the largest phonolitic eruptions at the SVD and used their petrological and geochemical features to reconstruct magma differentiation and crystal-melt separation in the solidification front. On this basis, three groups of enclaves have been identified: porphyritic enclaves, holocrystalline enclaves and sanidinites. The mineralogical variability faithfully reproduces the spatial and temporal evolution expected of a solidification front, from early-to-intermediate crystallization conditions (porphyritic and holocrystalline type) to the late stage of solidification (sanidinites), in which the percolation of a more differentiated melt through the crystal mush triggered the instability of the solidification front. Results from numerical models indicate that gravitational instability is the most efficient mechanism to explain melt extraction in mush zones of medium-sized (~ 10 km3), short-lived (~ 104 years) magma chambers.

  1. Experimental investigation of gabbro partial melting in the presence of NaCl-rich fluid - implications for the genesis of oceanic plagiogranites

    NASA Astrophysics Data System (ADS)

    Almeev, R. R.; Koepke, J.; Silantyev, S. A.; Portnyagin, M.; Garbe-Schoenberg, C.; Botcharnikov, R. E.

    2013-12-01

    We present results of the experimental study designed to assess the role of NaCl-rich hydrous fluids (modeled seawater-derived fluid) on partial melting of gabbroic rocks. Three contrasting compositions, i.e., olivine-bearing gabbro, gabbro-norite and Fe-Ti-gabbro, were investigated experimentally in the presence of the hydrous fluids with and without an excess of NaCl. The experiments were conducted in the range of pressures (100-200 MPa), temperatures (800-1040°C) and redox conditions (FMQ - FMQ+3). Partial melting in the presence of single aqueous fluid of low salinity (< 20 wt %NaCl) does not show any significant differences from the partial melting in the presence of salt-free aqueous fluid. In contrast, the presence of large amounts of NaCl (20-50 wt % in the fluid) and formation of saline-rich liquid (brine) causes the dramatic decrease in silica concentration of the partial melts and thus is not a premise to produce natural plagiogranites at investigated conditions. However the presence of NaCl may have played an important role at lower temperatures above the hydrous (only H2O-bearing fluid) solidus of the system in the presence of more complex fluids (saline and with low aH2O). Recently, J.Brophy proposed to use SiO2-REE diagrams for natural systems to decode the consequences of ideal fractionation of the basaltic melt and batch melting of the gabbro in application to the genesis of plagiogranites in mid-ocean ridge environments (e.g. Brophy, 2009). He argued that, for liquids with SiO2 greater than ~62 wt. %, hydrous melting of gabbroic cumulate should yield a negative correlation between REE abundances and increasing SiO2, while fractional crystallization of mid-ocean ridge basalt should produce a positive correlation. Our new experiments and trace element determinations in runs with large melt pools can be used to test this model. We observed the depletion of HREE (Yb) with increasing SiO2 (> 62 wt%) well predicted by the model of Brophy. In contrast

  2. H2O storage capacity of olivine and low-Ca pyroxene from 10 to 13 GPa: consequences for dehydration melting above the transition zone

    NASA Astrophysics Data System (ADS)

    Tenner, Travis J.; Hirschmann, Marc M.; Withers, Anthony C.; Ardia, Paola

    2012-02-01

    The onset of hydrous partial melting in the mantle above the transition zone is dictated by the H2O storage capacity of peridotite, which is defined as the maximum concentration that the solid assemblage can store at P and T without stabilizing a hydrous fluid or melt. H2O storage capacities of minerals in simple systems do not adequately constrain the peridotite water storage capacity because simpler systems do not account for enhanced hydrous melt stability and reduced H2O activity facilitated by the additional components of multiply saturated peridotite. In this study, we determine peridotite-saturated olivine and pyroxene water storage capacities at 10-13 GPa and 1,350-1,450°C by employing layered experiments, in which the bottom 2/3 of the capsule consists of hydrated KLB-1 oxide analog peridotite and the top 1/3 of the capsule is a nearly monomineralic layer of hydrated Mg# 89.6 olivine. This method facilitates the growth of 200-μm olivine crystals, as well as accessory low-Ca pyroxenes up to 50 μm in diameter. The presence of small amounts of hydrous melt ensures that crystalline phases have maximal H2O contents possible, while in equilibrium with the full peridotite assemblage (melt + ol + pyx + gt). At 12 GPa, olivine and pyroxene water storage capacities decrease from 1,000 to 650 ppm, and 1,400 to 1,100 ppm, respectively, as temperature increases from 1,350 to 1,450°C. Combining our results with those from a companion study at 5-8 GPa (Ardia et al., in prep.) at 1,450°C, the olivine water storage capacity increases linearly with increasing pressure and is defined by the relation C_{{{{H}}2 {{O}}}}^{{olivine}} ( {{ppm}} ) = 57.6( { ± 16} ) × P( {{GPa}} ) - 169( { ± 18} ). Adjustment of this trend for small increases in temperature along the mantle geotherm, combined with experimental determinations of D_{{{{H}}2 {{O}}}}^{{pyx/olivine}} from this study and estimates of D_{{{{H}}2 {{O}}}}^{{{{gt}}/{{olivine}}}} , allows for estimation of peridotite

  3. Pseudotachylyte in the Bench Canyon Shear Zone, central Sierra Nevada, California: Frictional melting in the brittle and semi-brittle fields

    SciTech Connect

    McNulty, B.A. )

    1993-04-01

    Many aspects of pseudotachylyte are controversial, particularly whether it is the product of intense comminution (e.g. ultracataclasite'') or frictional melting. Ubiquitous exposures of pseudotachylyte in the Bench Canyon shear Zone (BCSZ), central Sierra Nevada, California, provide an excellent opportunity for further study. Scanning electron microscopy (SEM) reveals vesicles, amygdules, crystallites and embayments of microxenocrysts, textures which are supportive of a melt origin for pseudotachylyte in the BCAZ. EDS and microprobe analyses indicate strong compositional contrasts between pseudotachylyte and granodiorite host; one explanation for this is preferential melting in order of individual mineral melting points.

  4. Ca(Ti,Si)O3 Diamond Inclusions Crystallized From Carbonate Melts in the Transition Zone: Experimental Constraints

    NASA Astrophysics Data System (ADS)

    Armstrong, L. S.; Walter, M. J.; Keshav, S.; Bulanova, G.; Pickles, J.; Lord, O. T.; Lennie, A.

    2007-12-01

    Composite diamond inclusions consisting of coexisting endmember CaSiO3 and CaTiO3 are rare but occur in diamond populations from Juina, Brazil1-2. Phase relations show that above ~9 GPa (at 1500 K) a perovskite-structured solid solution exists between these endmembers, while at lower pressures intermediate compositions produce coexisting CaTiO3-perovskite and CaSiO3 in the walstromite structure3. Inclusions with `perovskite' stoichiometry are commonly interpreted as fragments of solid mantle from the transition zone or lower mantle4-6. Here we report on two composite diamond inclusions from Juina kimberlite, and can effectively eliminate a subsolidus origin on the basis of experimental mineral phase relations. Instead, based on new melting experiments we find that the inclusions most likely crystallized directly from Ca-rich carbonate melts. Like other workers1-2 we interpret the composite inclusions as exsolution products of a high-pressure Ca(Ti,Si)O3 perovskite stable in the transition zone. Our bulk inclusion compositions are estimated to contain 50- 65 mol% CaTiO3, and are remarkably low in MgSiO3 component at less than 0.2 mol%. Experiments have shown that in peridotite or eclogite lithologies, Ca-rich perovskite in equilibrium with an MgSiO3-phase (majorite or Mg-perovskite) have about 3 to 7 mol% MgSiO37-8. Here we report on new subsolidus laser-heated diamond anvil cell experiments at 20-50 GPa in the ternary system CaSiO3-CaTiO3-MgSiO3 that bracket the CaTi-rich limb of the solvus between Ca- and Mg-rich perovskites. All experiments were made at 2000 (±200) K for 45-75 min, and were analysed using synchrotron micro-focus X-ray diffraction. We find that the solubility of MgSiO3 in CaTi-perovskite solid solutions increases significantly with increasing CaTiO3 component. Thus, Ti-rich calcium perovskite in peridotite or eclogite lithologies should have very high, not exceptionally low, MgSiO3 component. Accordingly, a subsolidus paragenesis is unlikely for

  5. Low-Velocity Zone of the Earth's Mantle: Incipient Melting Caused by Water.

    PubMed

    Lambert, I B; Wyllie, P J

    1970-08-21

    Experimental phase diagrams for the systems gabbro-water and peridotite-water indicate that, if there is any water in the upper mantle, then traces of hydrous interstitial silicate magma will be produced at depths corresponding to the beginning of the low-velocity zone. This explanation for the zone is more satisfactory than others proposed. PMID:17820306

  6. Low-Velocity Zone of the Earth's Mantle: Incipient Melting Caused by Water.

    PubMed

    Lambert, I B; Wyllie, P J

    1970-08-21

    Experimental phase diagrams for the systems gabbro-water and peridotite-water indicate that, if there is any water in the upper mantle, then traces of hydrous interstitial silicate magma will be produced at depths corresponding to the beginning of the low-velocity zone. This explanation for the zone is more satisfactory than others proposed.

  7. The petrogenesis of felsic calc-alkaline magmas from the southernmost Cascades, California: origin by partial melting of basaltic lower crust

    USGS Publications Warehouse

    Borg, L.E.; Clynne, M.A.

    1998-01-01

    The majority offelsic rocks from composite centers in teh southernmost Cascades have geochemical and Sr, Nd and Pb isotopic ratios that suggest derivation by partial melting of lower crust that is compositionally similar to cale-alkaline basalts observed in the region. Only a few felsic rocks have ???18O and Pb isotopic compositions that indicate interaction with the upper crust. Mineralogical and geochemical differences among the felsic magmas results primarily from melting under variable f(H2O) and lower temperature conditions leaves an amphibole-rich residuum, and produced magmas that have amphibole ?? biotite phenocrysts, relatively high silica contents, and pronounced middle rare earch element depletions. These conclusions are consistent with published thermal models that suggest that reasonable volumes of basaltic magma emplaced beneath large composite centers in the southernmost Cascades can serve as the eat source for melting of the lower crust. Melting of the lower crust under varible f(H2O contents of these basaltic magmas.

  8. 49 CFR 222.42 - How does this rule affect Intermediate Quiet Zones and Intermediate Partial Quiet Zones?

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... LOCOMOTIVE HORNS AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.42 How does this rule affect Intermediate Quiet Zones...

  9. 49 CFR 222.42 - How does this rule affect Intermediate Quiet Zones and Intermediate Partial Quiet Zones?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... LOCOMOTIVE HORNS AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.42 How does this rule affect Intermediate Quiet Zones...

  10. 49 CFR 222.42 - How does this rule affect Intermediate Quiet Zones and Intermediate Partial Quiet Zones?

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... LOCOMOTIVE HORNS AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.42 How does this rule affect Intermediate Quiet Zones...

  11. 49 CFR 222.42 - How does this rule affect Intermediate Quiet Zones and Intermediate Partial Quiet Zones?

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... LOCOMOTIVE HORNS AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.42 How does this rule affect Intermediate Quiet Zones...

  12. 49 CFR 222.42 - How does this rule affect Intermediate Quiet Zones and Intermediate Partial Quiet Zones?

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... LOCOMOTIVE HORNS AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.42 How does this rule affect Intermediate Quiet Zones...

  13. Drastic shift in lava geochemistry in the volcanic-front to rear-arc region of the Southern Kamchatkan subduction zone: Evidence for the transition from slab surface dehydration to sediment melting

    NASA Astrophysics Data System (ADS)

    Duggen, Svend; Portnyagin, Maxim; Baker, Joel; Ulfbeck, David; Hoernle, Kaj; Garbe-Schönberg, Dieter; Grassineau, Nathalie

    2007-01-01

    The shift of lava geochemistry between volcanic front to rear-arc volcanoes in active subduction zones is a widespread phenomenon. It is somehow linked to an increase of the slab surface depth of the subducting oceanic lithosphere and increasing thickness of the mantle wedge and new constraints for its causes may improve our understanding of magma generation and element recycling in subduction zones in general. As a case study, this paper focuses on the geochemical composition of lavas from two adjacent volcanic centres from the volcanic front (VF) to rear-arc (RA) transition of the Southern Kamchatkan subduction zone, with the aim to examine whether the shift in lava geochemistry is associated with processes in the mantle wedge or in the subducted oceanic lithosphere or both. The trace element and O-Sr-Nd-Hf-Pb (double-spike)-isotopic composition of the mafic Mutnovsky (VF) and Gorely (RA) lavas in conjunction with geochemical modelling provides constraints for the degree of partial melting in the mantle wedge and the nature of their slab components. Degrees of partial melting are inferred to be significantly higher beneath Mutnovsky (˜18%) than Gorely (˜10%). The Mutnovsky (VF) slab component is dominated by hydrous fluids, derived from subducted sediments and altered oceanic crust, eventually containing minor but variable amounts of sediment melts. The composition of the Gorely slab component strongly points to a hydrous silicate melt, most likely mainly stemming from subducted sediments, although additional fluid-contribution from the underlying altered oceanic crust (AOC) is likely. Moreover, the Hf-Nd-isotope data combined with geochemical modelling suggest progressive break-down of accessory zircon in the melting metasediments. Therefore, the drastic VF to RA shift in basalt chemistry mainly arises from the transition of the nature of the slab component (from hydrous fluid to melt) in conjunction with decreasing degrees of partial melting within ˜15 km

  14. Viscosity determinations of some frictionally generated silicate melts: Implications for slip zone rheology during impact-induced faulting

    NASA Technical Reports Server (NTRS)

    Spray, John G.

    1992-01-01

    Analytical scanning electron microscopy, using combined energy dispersive and wavelength dispersive spectrometry, was used to determine the major-element compositions of some natural and artificial glasses and their crystalline equivalents derived by the frictional melting of acid to intermediate protoliths. The major-element compositions are used to calculate the viscosities of their melt precursors using the model of Shaw at temperatures of 800-1400 C, with Fe(2+)/Fe(tot) = 0.5 and for 1-3 wt percent H2O. These results are then modified to account for suspension effects in order to determine viscosities. The results have implications for the generation of pseudotachylitic breccias as seen in the basement lithologies of the Sudbury and Vredefort structures and possibly certain dimict lunar breccias. Many of these breccias show similarities with the more commonly developed pseudotachylite fault and injection veins seen in endogenic fault zones that typically occur in thicknesses of a few centimeters or less. The main difference is one of scale: Impact-induced pseudotachylite breccias can attain several meters in thickness. This would suggest that they were generated under exceptionally high slip rates and hence high strain rates and that the friction melts generated possessed extremely low viscosities.

  15. Experimental determination of dissolved CO2 content in nominally anhydrous andesitic melts at graphite/diamond saturation - Remobilization of deeply subducted reduced carbon via partial melts of MORB-like eclogite

    NASA Astrophysics Data System (ADS)

    Eguchi, J.; Dasgupta, R.

    2015-12-01

    Experimental phase relations of carbonated lithologies [1] and geochemistry of deep diamonds [2] suggest that deep recycling of carbon has likely been efficient for a significant portion of Earth's history. Both carbonates and organic carbon subduct into the mantle, but with gradual decrease of fO2 with depth [3] most carbon in deep mantle rocks including eclogite could be diamond/graphite [4]. Previous studies investigated the transfer of CO2 from subducted eclogite to the ambient mantle by partial melting in the presence of carbonates, i.e., by generation of carbonate-rich melts [5]. However, the transfer of carbon from subducted eclogite to the mantle can also happen, perhaps more commonly, by extraction of silicate partial melt in the presence of reduced carbon; yet, CO2 solubility in eclogite-derived andesitic melt at graphite/diamond saturation remains unconstrained. CO2content of eclogite melts is also critical as geochemistry of many ocean island basalts suggest the presence of C and eclogite in their source regions [6]. In the present study we determine CO2 concentration in a model andesitic melt [7] at graphite/diamond saturation at conditions relevant for partial melting of eclogite in the convecting upper mantle. Piston cylinder and multi anvil experiments were conducted at 1-6 GPa and 1375-1550 °C using Pt/Gr double capsules. Oxygen fugacity was monitored with Pt-Fe sensors in the starting mix. Completed experiments at 1-3 GPa show that CO2 concentration increases with increasing P, T, and fO2 up to ~0.3 wt%. Results were used to develop empirical and thermodynamic models to predict CO2 concentration in partial melts of graphite saturated eclogite. This allowed us to quantify the extent to which CO2 can mobilize from eclogitic heterogeneities at graphite/diamond saturated conditions. With estimates of eclogite contribution to erupted basaltic lavas, the models developed here allow us to put constraints on the flux of CO2 to mantle source regions

  16. Occurrence and characterization of carbon nanoparticles below the soot laden zone of a partially premixed flame

    SciTech Connect

    Paul, Bireswar; Datta, Amitava; Datta, Aparna; Saha, Abhijit

    2009-12-15

    An experimental study has been performed to detect the occurrence of nanosized carbon particulates below the soot laden zone of a co-flowing partially premixed flame. Samples have been extracted from different points across the flame and passed through DI water. Absorption and fluorescence spectroscopies have been performed with the collected water suspensions. The occurrence of carbon nanoparticles is evident across the inner flame front. In addition, evidence of naphthalene has also been found inside the inner rich premixed flame. The concentration of naphthalene decreases while that of the carbon nanoparticles increases as the inner flame front is reached. The stability of the nanoparticles in the sample has been ensured by observing that the change in fluorescence quantum yield from the sample over a long duration is small. The band gap energy has been evaluated using the absorption data to characterize the likely structures of the particles in the collected suspension. Two kinds of particles having different zones of band gap energy are found in the flame. Dynamic light scattering measurements show that the particle size grows with the increase in height in the lower part of the flame. While, at 3 and 6 mm elevations the particles are observed to be below 2.5 nm in diameter, the particles at 10 mm elevation are found in the size range of 2.5-5.5 nm. (author)

  17. Frictional melting experiments investigate coseismic behaviour of pseudotachylyte-bearing faults in the Outer Hebrides Fault Zone, UK.

    NASA Astrophysics Data System (ADS)

    Campbell, L.; De Paola, N.; Nielsen, S. B.; Holdsworth, R.; Lloyd, G. E. E.; Phillips, R. J.; Walcott, R.

    2015-12-01

    Recent experimental studies, performed at seismic slip rates (≥ 1 m/s), suggest that the friction coefficient of seismic faults is significantly lower than at sub-seismic (< 1 mm/s) speeds. Microstructural observations, integrated with theoretical studies, suggest that the weakening of seismic faults could be due to a range of thermally-activated mechanisms (e.g. gel, nanopowder and melt lubrication, thermal pressurization, viscous flow), triggered by frictional heating in the slip zone. The presence of pseudotachylyte within both exhumed fault zones and experimental slip zones in crystalline rocks suggests that lubrication plays a key role in controlling dynamic weakening during rupture propagation. The Outer Hebrides Fault Zone (OHFZ), UK contains abundant pseudotachylyte along faults cutting varying gneissic lithologies. Our field observations suggest that the mineralogy of the protolith determines volume, composition and viscosity of the frictional melt, which then affects the coseismic weakening behaviour of the fault and has important implications for the magnitudes and distribution of stress drops during slip episodes. High velocity friction experiments at 18 MPa axial load, 1.3 ms-1 and up to 10 m slip were run on quartzo-feldspathic, metabasic and mylonitic samples, taken from the OHFZ in an attempt to replicate its coseismic frictional behaviour. These were configured in cores of a single lithology, or in mixed cores with two rock types juxtaposed. All lithologies produce a general trend of frictional evolution, where an initial peak followed by transient weakening precedes a second peak which then decays to a steady state. Metabasic and felsic single-lithology samples both produce sharper frictional peaks, at values of μ = 0.19 and μ= 0.37 respectively, than the broader and smaller (μ= 0.15) peak produced by a mixed basic-felsic sample. In addition, both single-lithology peaks occur within 0.2 m slip, whereas the combined-lithology sample displays a

  18. A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites.

    PubMed

    Reubi, Olivier; Blundy, Jon

    2009-10-29

    Andesites represent a large proportion of the magmas erupted at continental arc volcanoes and are regarded as a major component in the formation of continental crust. Andesite petrogenesis is therefore fundamental in terms of both volcanic hazard and differentiation of the Earth. Andesites typically contain a significant proportion of crystals showing disequilibrium petrographic characteristics indicative of mixing or mingling between silicic and mafic magmas, which fuels a long-standing debate regarding the significance of these processes in andesite petrogenesis and ultimately questions the abundance of true liquids with andesitic composition. Central to this debate is the distinction between liquids (or melts) and magmas, mixtures of liquids with crystals, which may or may not be co-genetic. With this distinction comes the realization that bulk-rock chemical analyses of petrologically complex andesites can lead to a blurred picture of the fundamental processes behind arc magmatism. Here we present an alternative view of andesite petrogenesis, based on a review of quenched glassy melt inclusions trapped in phenocrysts, whole-rock chemistry, and high-pressure and high-temperature experiments. We argue that true liquids of intermediate composition (59 to 66 wt% SiO(2)) are far less common in the sub-volcanic reservoirs of arc volcanoes than is suggested by the abundance of erupted magma within this compositional range. Effective mingling within upper crustal magmatic reservoirs obscures a compositional bimodality of melts ascending from the lower crust, and masks the fundamental role of silicic melts (>/=66 wt% SiO(2)) beneath intermediate arc volcanoes. This alternative view resolves several puzzling aspects of arc volcanism and provides important clues to the integration of plutonic and volcanic records.

  19. A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites.

    PubMed

    Reubi, Olivier; Blundy, Jon

    2009-10-29

    Andesites represent a large proportion of the magmas erupted at continental arc volcanoes and are regarded as a major component in the formation of continental crust. Andesite petrogenesis is therefore fundamental in terms of both volcanic hazard and differentiation of the Earth. Andesites typically contain a significant proportion of crystals showing disequilibrium petrographic characteristics indicative of mixing or mingling between silicic and mafic magmas, which fuels a long-standing debate regarding the significance of these processes in andesite petrogenesis and ultimately questions the abundance of true liquids with andesitic composition. Central to this debate is the distinction between liquids (or melts) and magmas, mixtures of liquids with crystals, which may or may not be co-genetic. With this distinction comes the realization that bulk-rock chemical analyses of petrologically complex andesites can lead to a blurred picture of the fundamental processes behind arc magmatism. Here we present an alternative view of andesite petrogenesis, based on a review of quenched glassy melt inclusions trapped in phenocrysts, whole-rock chemistry, and high-pressure and high-temperature experiments. We argue that true liquids of intermediate composition (59 to 66 wt% SiO(2)) are far less common in the sub-volcanic reservoirs of arc volcanoes than is suggested by the abundance of erupted magma within this compositional range. Effective mingling within upper crustal magmatic reservoirs obscures a compositional bimodality of melts ascending from the lower crust, and masks the fundamental role of silicic melts (>/=66 wt% SiO(2)) beneath intermediate arc volcanoes. This alternative view resolves several puzzling aspects of arc volcanism and provides important clues to the integration of plutonic and volcanic records. PMID:19865169

  20. Three-dimensional electrical conductivity structure beneath Australia from inversion of geomagnetic observatory data: evidence for lateral variations in transition-zone temperature, water content and melt

    NASA Astrophysics Data System (ADS)

    Koyama, Takao; Khan, Amir; Kuvshinov, Alexey

    2014-03-01

    In this paper, we report the 3-D electrical conductivity distribution beneath the Australian continent in the depth range 410-1600 km, which we have imaged by inverting C-response estimates from a regional network of geomagnetic observatories. The inversion scheme is based on a quasi-Newton optimization method while the forward algorithm relies on an integral-equation approach. To properly account for the ocean effect in responses at coastal observatories we included a high-resolution (1° × 1°) fixed thin laterally varying surface conductance layer. As starting model in the inversion we considered a laboratory-based 3-D conductivity model of the region obtained from seismic surface wave data and thermodynamic modelling. This model provides a good fit to observed C-response estimates supporting its choice as initial model. The most striking feature of the obtained 3-D model is a high-conductivity anomaly in the lower part of the mantle transition zone (MTZ; 520-660 km depth) beneath southeastern Australia implying considerable lateral as radial heterogeneity in the conductivity structure. The high-conductivity region appears to be 0.5-1 log units more conductive than previous global and other regionalized 1-D models. Further analysis using laboratory-based conductivity models combined with thermochemical phase equilibrium computations shows that the strong conductivity anomaly implies water contents of around 0.1 wt per cent in the upper part and >0.4 wt per cent in the lower part of the MTZ. This implies a large MTZ water reservoir that likely totals one to three times that which currently resides in the oceans. The amount of water in the lower MTZ appears to exceed the experimentally determined water storage capacity of the main lower MTZ mineral ringwoodite, which, as a result, undergoes dehydration-induced partial melting. Including contributions to conductivity from a thin melt layer (20 km thick) located in the mid-MTZ increases conductivity locally in the

  1. Geochemical signatures of metasedimentary rocks of high-pressure granulite facies and their relation with partial melting: Carvalhos Klippe, Southern Brasília Belt, Brazil

    NASA Astrophysics Data System (ADS)

    Cioffi, Caue Rodrigues; Campos Neto, Mario da Costa; da Rocha, Brenda Chung; Moraes, Renato; Henrique-Pinto, Renato

    2012-12-01

    High-grade metasedimentary rocks can preserve geochemical signatures of their sedimentary protolith if significant melt extraction did not occur. Retrograde reaction textures provide the main evidence for trapped melt in the rock fabrics. Carvalhos Klippe rocks in Southern Brasília Orogen, Brazil, present a typical high-pressure granulite assemblage with evidence of mica breakdown partial melting (Ky + Grt + Kfs ± Bt ± Rt). The metamorphic peak temperatures obtained by Zr-in-Rt and ternary feldspar geothermometers are between 850 °C and 900 °C. The GASP baric peak pressure obtained using grossular rich garnet core is 16 kbar. Retrograde reaction textures in which the garnet crystals are partially to totally replaced by Bt + Qtz ± Fsp intergrowths are very common in the Carvalhos Klippe rocks. These reactions are interpreted as a result of interactions between residual phases and trapped melt during the retrograde path. In the present study the geochemical signatures of three groups of Carvalhos Klippe metasedimentary rocks are analysed. Despite the high metamorphic grade these three groups show well-defined geochemical features and their REE patterns are similar to average compositions of post-Archean sedimentary rocks (PAAS, NASC). The high-pressure granulite facies Grt-Bt-Pl gneisses with immature arenite (wacke, arkose or lithic-arenite) geochemical signatures present in the Carvalhos Klippe are compared to similar rocks in amphibolite facies from the same tectonic framework (Andrelândia Nappe System). The similar geochemical signatures between Grt-Bt-Pl gneisses metamorphosed in high-pressure granulite facies and Grt-Bt-Pl-Qtz schists from the Andrelândia and Liberdade Nappes, with minimal to absent melting conditions, are suggestive of low rates of melt extraction in these high-grade rocks. The rocks with pelitic compositions most likely had higher melt extraction and even under such circumstances nevertheless tend to show REE patterns similar to

  2. Subduction of fracture zones

    NASA Astrophysics Data System (ADS)

    Constantin Manea, Vlad; Gerya, Taras; Manea, Marina; Zhu, Guizhi; Leeman, William

    2013-04-01

    Since Wilson proposed in 1965 the existence of a new class of faults on the ocean floor, namely transform faults, the geodynamic effects and importance of fracture zone subduction is still little studied. It is known that oceanic plates are characterized by numerous fracture zones, and some of them have the potential to transport into subduction zones large volumes of water-rich serpentinite, providing a fertile water source for magma generated in subduction-related arc volcanoes. In most previous geodynamic studies, subducting plates are considered to be homogeneous, and there is no clear indication how the subduction of a fracture zone influences the melting pattern in the mantle wedge and the slab-derived fluids distribution in the subarc mantle. Here we show that subduction of serpentinized fracture zones plays a significant role in distribution of melt and fluids in the mantle wedge above the slab. Using high-resolution tree-dimensional coupled petrological-termomechanical simulations of subduction, we show that fluids, including melts and water, vary dramatically in the region where a serpentinized fracture zone enters into subduction. Our models show that substantial hydration and partial melting tend to concentrate where fracture zones are being subducted, creating favorable conditions for partially molten hydrous plumes to develop. These results are consistent with the along-arc variability in magma source compositions and processes in several regions, as the Aleutian Arc, the Cascades, the Southern Mexican Volcanic Arc, and the Andean Southern Volcanic Zone.

  3. The Growth of Melt Inclusion- and Water-Rich Zones in Clinopyroxene Phenocrysts of the Powai Ankaramite Flow, Deccan Traps, India: Rapid Closed System Oscillatory Mineral Growth

    NASA Astrophysics Data System (ADS)

    Seaman, S. J.

    2015-12-01

    Water concentrations were measured and mapped using FTIR spectroscopy in clinopyroxene phenocrysts of the Powai ankaramite flow, located near Mumbai, west of the Western Ghats escarpment of the Deccan province, India. Samples were provided by Dr. Hetu Sheth of the Indian Institute of Technology, Mumbai. Chatterjee and Sheth (2015) showed that phenocrysts in the flow were part of a cumulate layer intruded by high-temperature basaltic melt at ~ 6 kb and ~1230oC. Cpx phenocrysts are euhedral and have concentric bands (100 to 200 microns thick) of fine (10-20 micron diameter) melt inclusions. Cpx bands that host melt inclusions have higher concentrations of water than inclusion-free bands. Water concentrations of cpx and ol were used to calculate water concentrations in the melt from which the crystals formed. Water concentrations in the parent magma were between 4.35 and 8.26 wt. % based on water concentrations in cpx, and between 8.24 and 9.41 wt. % based on those in ol. Both Mg and Fe are relatively depleted in the water- and melt inclusion-rich zones in cpx, and Ca is enriched in these zones. We suggest that oscillatory zoning in cpx is a result of repeated growth of cpx in water-richer and water-poorer boundary layers in which water lowered melt viscosity and enhanced diffusion and crystal growth rates. Water-enhanced growth rates may have resulted in preferential capture of melt inclusions preserved in water-rich cpx zones. Mg was preferentially incorporated into the cpx, causing Ca and water to build up in the boundary layer, and Mg and Fe to become relatively depleted in the boundary layer, as discussed for oscillatorially-zoned minerals by Wang and Merino (1993). Application of the equations for growth of oscillatory zones in crystals given by Wang and Merino (1993) to the growth of cpx crystals in the Powai ankaramite indicate that crystal growth occurred relatively quickly, on the order of days, although the width of the boundary zone, which is uncertain

  4. Concept of the exhumed partial annealing (retention) zone in thermochronology: An appraisal

    NASA Astrophysics Data System (ADS)

    Fitzgerald, P. G.

    2013-12-01

    The concept of an exhumed partial annealing zone (PAZ) in fission track (FT) thermochronology has been a widely used and successful interpretative tool since the 1980s. This 1D-interpretative approach is typically applied to samples collected over significant relief, with best results if the sampling is undertaken in steep short-wavelength topography and samples collected parallel to topography (perpendicular to curved isotherms), and for samples following a vertical exhumation path. While annealing of fission tracks occurs even at low ambient temperatures the PAZ is defined as the zone between where tracks are annealed 'geologically' instantaneously and where the rate of annealing slows dramatically; between ~60 and ~110°C for tracks in apatite depending on composition. The shape and average slope of a PAZ varies depending on the paleogeothermal gradient and its stability, and the length of time over which a PAZ forms. PAZs and partial retention zones (PRZ) are now known for different minerals for various techniques. Single grain age dispersion can be significantly magnified in a PAZ/PRZ depending on composition, grain size, [eU], radiation damage and zoning for the FT and (U-Th)/He methods. An exhumed PAZ/PRZ may be revealed in an age-elevation ('vertical') profile when, following a period of uplift/exhumation, the form of the PAZ/PRZ is retained with a 'sharp' convex inflexion (the 'break in slope') marking the base of the exhumed PAZ/PRZ with reset samples structurally beneath. The break in slope represents a minimal age for the transition from 'relative thermal stability' to rapid cooling, as the rock column has to cool through the PAZ/PRZ, with the underestimate greater if the change in cooling rate is not significant. The base of an exhumed PAZ/PRZ is a curve, but we approximate it with straight lines, with less precision with fewer samples. The break in slope may not be distinguishable if the cooling/exhumation was long ago and/or of low magnitude. The

  5. [Effects of controlled alternate partial root-zone drip irrigation on apple seedling morphological characteristics and root hydraulic conductivity].

    PubMed

    Yang, Qi-Liang; Zhang, Fu-Cang; Liu, Xiao-Gang; Ge, Zhen-Yang

    2012-05-01

    To investigate the effects of alternate partial root-zone drip irrigation (ADI) on the morphological characteristics and root hydraulic conductivity of apple seedlings, three irrigation modes, i.e., fixed partial root-zone drip irrigation (FDI, fixed watering on one side of the seedling root zone), controlled alternate partial root-zone drip irrigation (ADI, alternate watering on both sides of the seedling root zone), and conventional drip irrigation (CDI, watering cling to the seedling base), and three irrigation quotas, i. e., each irrigation amount of FDI and ADI was 10, 20 and 30 mm, and that of CDI was 20, 30 and 40 mm, respectively, were designed. In treatment ADI, the soil moisture content on the both sides of the root zone appeared a repeated alternation of dry and wet process; while in treatment CDI, the soil moisture content had less difference. At the same irrigation quotas, the soil moisture content at the watering sides had no significant difference under the three drip irrigation modes. At irrigation quota 30 mm, the root-shoot ratio, healthy index of seedlings, and root hydraulic conductivity in treatment ADI increased by 31.6% and 47.1%, 34.2% and 53.6%, and 9.0% and 11.0%, respectively, as compared with those in treatments CDI and FDI. The root dry mass and leaf area had a positive linear correlation with root hydraulic conductivity. It was suggested that controlled alternate partial root-zone drip irrigation had obvious compensatory effects on the root hydraulic conductivity of apple seedlings, improved the soil water use by the roots, benefited the equilibrated dry matter allocation in seedling organs, and markedly enhanced the root-shoot ratio and healthy index of the seedlings.

  6. [Effects of controlled alternate partial root-zone drip irrigation on apple seedling morphological characteristics and root hydraulic conductivity].

    PubMed

    Yang, Qi-Liang; Zhang, Fu-Cang; Liu, Xiao-Gang; Ge, Zhen-Yang

    2012-05-01

    To investigate the effects of alternate partial root-zone drip irrigation (ADI) on the morphological characteristics and root hydraulic conductivity of apple seedlings, three irrigation modes, i.e., fixed partial root-zone drip irrigation (FDI, fixed watering on one side of the seedling root zone), controlled alternate partial root-zone drip irrigation (ADI, alternate watering on both sides of the seedling root zone), and conventional drip irrigation (CDI, watering cling to the seedling base), and three irrigation quotas, i. e., each irrigation amount of FDI and ADI was 10, 20 and 30 mm, and that of CDI was 20, 30 and 40 mm, respectively, were designed. In treatment ADI, the soil moisture content on the both sides of the root zone appeared a repeated alternation of dry and wet process; while in treatment CDI, the soil moisture content had less difference. At the same irrigation quotas, the soil moisture content at the watering sides had no significant difference under the three drip irrigation modes. At irrigation quota 30 mm, the root-shoot ratio, healthy index of seedlings, and root hydraulic conductivity in treatment ADI increased by 31.6% and 47.1%, 34.2% and 53.6%, and 9.0% and 11.0%, respectively, as compared with those in treatments CDI and FDI. The root dry mass and leaf area had a positive linear correlation with root hydraulic conductivity. It was suggested that controlled alternate partial root-zone drip irrigation had obvious compensatory effects on the root hydraulic conductivity of apple seedlings, improved the soil water use by the roots, benefited the equilibrated dry matter allocation in seedling organs, and markedly enhanced the root-shoot ratio and healthy index of the seedlings. PMID:22919832

  7. Effects of partial root-zone irrigation on hydraulic conductivity in the soil-root system of maize plants.

    PubMed

    Hu, Tiantian; Kang, Shaozhong; Li, Fusheng; Zhang, Jianhua

    2011-08-01

    Effects of partial root-zone irrigation (PRI) on the hydraulic conductivity in the soil-root system (L(sr)) in different root zones were investigated using a pot experiment. Maize plants were raised in split-root containers and irrigated on both halves of the container (conventional irrigation, CI), on one side only (fixed PRI, FPRI), or alternately on one of two sides (alternate PRI, APRI). Results show that crop water consumption was significantly correlated with L(sr) in both the whole and irrigated root zones for all three irrigation methods but not with L(sr) in the non-irrigated root zone of FPRI. The total L(sr) in the irrigated root zone of two PRIs was increased by 49.0-92.0% compared with that in a half root zone of CI, suggesting that PRI has a significant compensatory effect of root water uptake. For CI, the contribution of L(sr) in a half root zone to L(sr) in the whole root zone was ∼50%. For FPRI, the L(sr) in the irrigated root zone was close to that of the whole root zone. As for APRI, the L(sr) in the irrigated root zone was greater than that of the non-irrigated root zone. In comparison, the L(sr) in the non-irrigated root zone of APRI was much higher than that in the dried zone of FPRI. The L(sr) in both the whole and irrigated root zones was linearly correlated with soil moisture in the irrigated root zone for all three irrigation methods. For the two PRI treatments, total water uptake by plants was largely determined by the soil water in the irrigated root zone. Nevertheless, the non-irrigated root zone under APRI also contributed to part of the total crop water uptake, but the continuously non-irrigated root zone under FPRI gradually ceased to contribute to crop water uptake, suggesting that it is the APRI that can make use of all the root system for water uptake, resulting in higher water use efficiency.

  8. Effects of partial root-zone irrigation on hydraulic conductivity in the soil–root system of maize plants

    PubMed Central

    Hu, Tiantian; Kang, Shaozhong; Li, Fusheng; Zhang, Jianhua

    2011-01-01

    Effects of partial root-zone irrigation (PRI) on the hydraulic conductivity in the soil–root system (Lsr) in different root zones were investigated using a pot experiment. Maize plants were raised in split-root containers and irrigated on both halves of the container (conventional irrigation, CI), on one side only (fixed PRI, FPRI), or alternately on one of two sides (alternate PRI, APRI). Results show that crop water consumption was significantly correlated with Lsr in both the whole and irrigated root zones for all three irrigation methods but not with Lsr in the non-irrigated root zone of FPRI. The total Lsr in the irrigated root zone of two PRIs was increased by 49.0–92.0% compared with that in a half root zone of CI, suggesting that PRI has a significant compensatory effect of root water uptake. For CI, the contribution of Lsr in a half root zone to Lsr in the whole root zone was ∼50%. For FPRI, the Lsr in the irrigated root zone was close to that of the whole root zone. As for APRI, the Lsr in the irrigated root zone was greater than that of the non-irrigated root zone. In comparison, the Lsr in the non-irrigated root zone of APRI was much higher than that in the dried zone of FPRI. The Lsr in both the whole and irrigated root zones was linearly correlated with soil moisture in the irrigated root zone for all three irrigation methods. For the two PRI treatments, total water uptake by plants was largely determined by the soil water in the irrigated root zone. Nevertheless, the non-irrigated root zone under APRI also contributed to part of the total crop water uptake, but the continuously non-irrigated root zone under FPRI gradually ceased to contribute to crop water uptake, suggesting that it is the APRI that can make use of all the root system for water uptake, resulting in higher water use efficiency. PMID:21527627

  9. Experimentally determined distribution of fluorine and chlorine upon hydrous slab melting, and implications for F-Cl cycling through subduction zones

    NASA Astrophysics Data System (ADS)

    Van den Bleeken, Greg; Koga, Kenneth T.

    2015-12-01

    Fluorine and chlorine are volatile elements known to be enriched in primitive arc magmas, and variations of F/Cl ratios can carry information about slab devolatilization processes. Recent experiments on the fractionations of these elements suggest that aqueous fluid has limited capacity to enrich the magma source region in F. Hence, it is difficult to explain observations of primitive arc magmas particularly rich in F. To complement previous experimental studies, we examined the fractionation of fluorine and chlorine during hydrous partial melting of subducting slab. Element-doped phase equilibria experiments were carried out in a complex chemical system at conditions equivalent to potential slab melting temperatures (750-1000 °C) across the amphibolite to eclogite facies transition (1.3-3 GPa). Partition coefficients of F and Cl between hydrous silicic melts and minerals were determined by electron microprobe and/or ion probe. Fluorine is compatible in amphibole (DFamp/glass = 1.18-1.85), and incompatible in garnet (0.034-0.140), clinopyroxene (0.059-0.505), and allanite (0.205-0.504). Hence, amphibole is an important F host, and can retain significant quantities of F in the solid residue of partial melting. On the contrary, Cl is incompatible, with DClmineral/glass generally decreasing from amphibole (0.079-0.625; one outlier at 1.87) to allanite (0.163), clinopyroxene (0.066-0.158), and garnet (0.031-0.153; outlier at 0.492). As a result, Cl is easily mobilized during partial melting. Fluorine and chlorine release during slab melting have been quantified by applying our partition coefficients to a non-modal batch melting model. The model shows that amphibole plays a key role in F/Cl fractionation during partial melting, while F/Cl is close to that of source for the melting of amphibole free eclogite. Moreover, the results from a flux-melting model employing several source compositions are compared to F and Cl abundances in primitive arc magmas. The observed

  10. Effect of Bulk Water Concentration on Mantle Wedge Hybridization by Rhyolitic Sediment Melt - Implications for Generation of K-rich Basalts to Andesites in Subduction Zones

    NASA Astrophysics Data System (ADS)

    Mallik, A.; Dasgupta, R.; Nelson, J. M.; Tsuno, K.

    2014-12-01

    Similarities in trace element geochemistry between ocean-floor sediments and arc lavas suggest the involvement of subducted sediments in the mantle source of arc volcanoes. Siliciclastic sediments produce rhyo-dacitic, hydrous partial melts at sub-arc depths, which must react with wedge peridotite during their ascent. In addition to fluids, these sediment melts can be a major carrier of water to the arc source. Here we investigate the effects of bulk water concentration on the phase equilibria of reaction between sediment partial melt and peridotite. Piston-cylinder experiments were performed using Au-Pd capsules, at 2 and 3 GPa, 1050 - 1350 °C with mixtures of 25% rhyolite + 75% lherzolite, bearing bulk water content of 2 (low-water) and 4 wt.% (high-water). Melting degree is higher in high-water experiments at both 2 and 3 GPa with a sharp increase in melt mode from 31 to 53 wt.% at 1250-1300 °C, 2 GPa and 21 to 49 wt.% at 1225-1250 °C, 3 GPa. This sharp increase in melt mode is accompanied by a corresponding abrupt increase in residual olivine to opx ratio at both pressures (0.11 to 0.53 at 1250-1300 °C, 2 GPa and 0 to 0.71 at 1225-1250 °C, 3 GPa). The stability field of phlogopite, clinopyroxene, and garnet are reduced in high-water experiments due to higher degrees of partial melting. Low-water experiments produce basalts with SiO2, on a volatile-free basis, increasing from 49 to 51 wt.% at 2 GPa and 46 to 48 wt.% at 3 GPa. For high-water experiments, melt SiO2 contents at 2 GPa are slightly higher than those in low-water experiments for a given temperature, varying from 51 to 52 wt.%, and, at 3 GPa, the melts trend towards andesitic compositions with SiO2 ~54 wt.%. These compositional characteristics of the melts can be attributed to the effect of increased olivine to opx ratios in the residue as a function of increasing bulk water concentration. Our study shows that a spectrum of ultra-potassic, high-Mg arc lavas (MgO varying from 10-16 wt.%) from

  11. Zircon U-Pb ages and Hf-O isotopic composition of migmatites from the Zanjan-Takab complex, NW Iran: Constraints on partial melting of metasediments

    NASA Astrophysics Data System (ADS)

    Moghadam, Hadi Shafaii; Li, Xian-Hua; Stern, Robert J.; Ghorbani, Ghasem; Bakhshizad, Farzaneh

    2016-01-01

    We study migmatites and other metamorphic rocks in the Zanjan-Takab region of NW Iran and use these results to report the first evidence of Oligocene core complex formation in Iran. Four samples of migmatites associated with paragneisses, including leucosomes and associated para-amphibolite melanosomes were selected for U-Pb dating and Hf-O isotopic analysis. Zircon cores - interpreted as originally detrital zircons - have variable ages that peak at ca. 100-110 Ma, but their sedimentation age - indicated by the youngest 206Pb/238U ages - is ca. 35-40 Ma. New zircons associated with incipient melting occur as overgrowths around zircon cores and/or as newly grown grains. Morphologies and internal structures suggest that rim growth and formation of new zircons were associated with partial melting. All four samples contain zircons with rims that yield 206Pb/238U ages of 28-25 Ma, indicating that partial melting occurred in Late Oligocene time. δ18O values for zircon rims vary between 8.2 and 12.3‰, significantly higher than expected for mantle inputs (δ18O ~ 6‰) and consistent with equilibrium with surface materials. Zircon rims yield εHf(t) between 2.2 and 12.4 and two-stage Hf model ages of ~ 448-562 Ma, indicating that the region is underlain by Cadomian-Caledonian crust. According to the Hf-O isotopic values, the main mechanism forming zircon rims was dissolution of pre-existing detrital zircons with reprecipitation of new zircon shortly thereafter. Oligocene ages indicate that partial melting accompanied core complex formation in the Zanjan-Takab region. Extension, melting, and core complex formation in south-central Iran are Eocene in age, but younger ages of Oligocene-Miocene in NW Iran and Turkey indicate that extension was distributed throughout the region during Cenozoic time.

  12. Purification of Cu by hydrogen plasma-arc zone melting and characterization of trace impurities by secondary ion mass spectrometry

    SciTech Connect

    Lalev, G.M.; Lim, J.-W. Munirathnam, N.R. Choi, G.-S.; Uchikoshi, M.; Mimura, K.; Isshiki, M.

    2009-01-15

    Purification of 4N (99.99%) and 6N (99.9999%) purity Cu rods by hydrogen plasma-arc zone melting was carried out. Weight loss in the 4N and 6N Cu rods as a function of number of zone refined passes revealed a higher rate of impurity removal by vaporization in 4N Cu when compared to 6N Cu. Purification effect was studied by analyzing major impurities like Mg, Si, Ca, Ti, Cr, Ni and Fe by O{sub 2}{sup +} ions and C, O, As, Cl, P and S by Cs{sup +} ion sources using secondary ion mass spectrometry. A remarkable decrease of Si, Ti and Fe impurity concentrations in Cu at x/L = 0.03 after 10 zone passes was observed, but no similar purification effect along the remaining length of the zone refined copper rod was observed. Mg, Se and Ca in the Cu rods were reduced faster by a high evaporation effect due to P{sub i}/P{sub Cu} > 10{sup 2}. On the other hand, removal of O, C, S and Se was expectedly dominated by vaporization in the form of H{sub 2}O, CH{sub 4,} H{sub 2}S, and H{sub 2}Se through thermodynamically favored reactions. The overall segregation rate of the individual impurity elements was decreased with an increase in the purity from 4N to 6N of Cu rods. SIMS analysis of trace impurities was successfully carried out on HPZM Cu for quantitative estimation.

  13. Partial melting of granitoids under eclogite-facies conditions: nanogranites from felsic granulites from Orlica-Śnieżnik Dome (Bohemian Massif)

    NASA Astrophysics Data System (ADS)

    Ferrero, Silvio; O'Brien, Patrick; Walczak, Katarzyna; Wunder, Bernd; Hecht, Lutz

    2014-05-01

    Melt inclusions (MI) study in migmatites is a powerful tool to retrieve the original composition of the anatectic melt, both as major elements (Ferrero et al., 2012) and fluid contents (Bartoli et al., 2013). Crystallized MI, or "nanogranites" (Cesare et al., 2009), were identified within HP felsic granulites from Orlica-Śnieżnik Dome, NE Bohemian Massif (Walczak, 2011). The investigated samples are Grt+Ky leucogranulites originated from a granitic protolith, with assemblage Qtz+Pl+Kfs+Grt+Ky+Ttn+Rt+Ilm. Nanogranites occur in garnet as primary inclusions, and consist of Qtz+Ab+Bt+Kfs±Ep±Ap. Such assemblage results from the crystallization of a melt generated during a partial melting reaction; the same reaction is also responsible for the production of the host garnet, interpreted therefore as a peritectic phase. Besides nanogranites, former presence of melt is supported by the occurrence of tiny pseudomorphs of melt-filled pores (Holness & Sawyer, 2008) and euhedral faces in garnet. Garnet composition, with Grs =0.28-0.31, phase assemblage (kyanite, ternary feldspar) and classic thermobarometry suggest that partial melting took place at T≥875°C and P~2.2-2.6 GPa, under eclogite-facies conditions. Although other authors reported palisade quartz after coesite in this area (see e.g. Bakun-Czubarow, 1992), no clear evidence of UHP conditions have been identified during this study. Piston cylinder re-homogenization experiments were performed on MI-bearing garnet chips to obtain the composition of the pristine anatectic melt. The first data from experiments in the range 850-950°C and 2-2.2 GPa show that nanogranites can be re-melted at T≥875°. However, homogenization has not been reached yet since new Grt, with lower CaO and higher MgO, crystallizes on the walls of the inclusion. As P increases, the modal amount of new phase decreases, while its composition evolves closer to those of the host garnet. Further experiments at higher pressure are in underway, with

  14. Partial melting of fertile peridotite fluxed by hydrous rhyolitic melt at 2-3 GPa: implications for mantle wedge hybridization by sediment melt and generation of ultrapotassic magmas in convergent margins

    NASA Astrophysics Data System (ADS)

    Mallik, Ananya; Nelson, Jared; Dasgupta, Rajdeep

    2015-05-01

    We investigated the melting behavior of peridotite fluxed with 25 wt% of H2O-bearing rhyolitic sediment melt (1.8 wt% bulk H2O), by performing experiments from 1100 to 1300 °C at 2 GPa and 1050-1350 °C at 3 GPa. The apparent solidus of our bulk composition lies between 1100 and 1150 °C at both pressures, which is at a higher temperature than the vapor-saturated solidus and close to the pargasite dehydration solidus of peridotite. With increasing temperature, reacted melt fraction increases from 20 to 36 wt% from 1200 to 1300 °C at 2 GPa and 7 to 24 wt% from 1225 to 1350 °C at 3 GPa. Orthopyroxene is present as a residual phase in all the experiments, while olivine is present as a residual phase in all the experiments at 2 GPa only. Amphibole is absent above 1100 °C at both pressures, clinopyroxene disappears above 1200 and 1300 °C at 2 and 3 GPa, respectively, and garnet (only present at 3 GPa) melts out above 1300 °C. Upon reaction with the mantle wedge and subsequent melting of the hybrid rock, subducted sediment-derived rhyolites evolve in composition to a nepheline-normative ultrapotassic leucitite, similar in major element composition to ultrapotassic lavas from active arcs such as Sunda and inactive arcs such as in the Roman Magmatic Province. Fluxing peridotite with H2O versus H2O-bearing sediment melt at similar pressures does not appear to have an effect on isobaric melt productivity, but does have significant effect on melting reactions and resultant melt composition, with influx of sediment melt adding K2O to the system, thereby stabilizing phlogopite, which in turn buffers the reacted melt to ultrapotassic compositions. Previous experimental studies, along with this study, find that phlogopite can be stable near the hotter core of the mantle wedge and, hence, is likely to be subducted to deeper mantle, thereby influencing deeper cycling of volatiles and large ion lithophile elements. Also, because D {Rb/phl/melt} ≫ D {Sr/phl/melt} and D {Nd/phl/melt

  15. Critical porosity of melt segregation during crustal melting: Constraints from zonation of peritectic garnets in a dacite volcano

    NASA Astrophysics Data System (ADS)

    Yu, Xun; Lee, Cin-Ty A.

    2016-09-01

    The presence of leucogranitic dikes in orogenic belts suggests that partial melting may be an important process in the lower crust of active orogenies. Low seismic velocity and low electrical resistivity zones have been observed in the lower crust of active mountain belts and have been argued to reflect the presence of partial melt in the deep crust, but volcanoes are rare or absent above many of these inferred melt zones. Understanding whether these low velocity zones are melt-bearing, and if so, why they do not commonly erupt, is essential for understanding the thermal and rheologic structure of the crust and its dynamic evolution. Central to this problem is an understanding of how much melt can be stored before it can escape from the crust via compaction and eventually erupt. Experimental and theoretical studies predict trapped melt fractions anywhere from <5% to >30%. Here, we examine Mn growth-zoning in peritectic garnets in a Miocene dacite volcano from the ongoing Betic-Rif orogeny in southern Spain to estimate the melt fraction at the time of large-scale melt extraction that subsequently led to eruption. We show that the melt fraction at segregation, corresponding approximately to the critical melt porosity, was ∼30%, implying significant amounts of melt can be stored in the lower crust without draining or erupting. However, seismic velocities in the lower crust beneath active orogenic belts (southern Spain and Tibet) as well as beneath active magmatic zones (e.g., Yellowstone hotspot) correspond to average melt porosities of <10%, suggesting that melt porosities approaching critical values are short-lived or that high melt porosity regions are localized into heterogeneously distributed sills or dikes, which individually cannot be resolved by seismic studies.

  16. Partial Melt Systems in Plate-Driven Corner Flow: Evaluating the Formation of Porosity Bands as a Mechanism for Magma Focusing at Mid-Ocean Ridges

    NASA Astrophysics Data System (ADS)

    Gebhardt, D.; Butler, S. L.

    2015-12-01

    The imposition of an external shear on a system of partial melt will result in compaction of the solid matrix and concentration of the interstitial liquid melt leading to the formation of regions of contrasting high and low porosity. In experiments, direct and torsional shear geometries have demonstrated that these regions of varying porosity form in bands orientated at low angles relative to the shear plane. A variety of numerical models have been employed to recreate these experimental results. Simple shear, pure shear and torsional shear geometries have been used in both linear and nonlinear numerical settings to model the formation of the porosity bands. In this contribution the numerical models utilize a shear geometry derived from the velocity field of the plate-driven corner flow of a mid-ocean ridge. Motivation for using the velocity field of a mid-ocean ridge comes from evidence that suggests the existence of lateral melt channeling from either side of the ridge axis. Imposing the shear from a mid-ocean ridge corner flow allows for the evaluation of the resulting porosity bands in terms of suitability for channeling melt laterally toward the ridge axis. This is done using both slow and fast spreading ridge geometries. The degree of similarity between previous numerical and experimental results has been found to be greatly influenced by the imposed viscosity law of the solid matrix phase. In order to keep this in mind, the numerical models in this contribution use three different matrix viscosity laws: strain-rate independent, strain-rate dependent and anisotropic. Of these rheologies, strain-rate independence results in the poorest orientation for channeling melt directly to the ridge axis. The strain-rate dependent and anisotropic viscosities present more favorable direct-channeling orientations for the fastest growing porosity bands, but in both cases the background flow will rotate bands to less ideal orientations over time. However, these less

  17. A numerical treatment of melt/solid segregation - Size of the eucrite parent body and stability of the terrestrial low-velocity zone

    NASA Technical Reports Server (NTRS)

    Walker, D.; Stolper, E. M.; Hays, J. F.

    1978-01-01

    Crystal sinking to form cumulates and melt percolation toward segregation in magma pools can be treated with modifications of Stokes' and Darcy's laws, respectively. The velocity of crystals and melt depends, among other things, on the force of gravity (g) driving the separations and the cooling time of the environment. The increase of g promotes more efficient differentiation, whereas the increase of cooling rate limits the extent to which crystals and liquid can separate. The rate at which separation occurs is strongly dependent on the proportion of liquid that is present. The observation of cumulates and segregated melts among the eucrite meteorites is used as a basis for calculating the g (and planet size) required to perform these differentiations. The eucrite parent body was probably at least 10-100 km in radius. The earth's low velocity zone (LVZ) is shown to be unstable with respect to draining itself of excess melt if the melt forms an interconnecting network. A geologically persistent LVZ with a homogeneous distribution of melt can be maintained with melt fractions only on the order of 0.1% or less.

  18. The effect of the melt thermal gradient on the size of the constitutionally supercooled zone

    NASA Astrophysics Data System (ADS)

    Prasad, A.; Yuan, L.; Lee, P. D.; Easton, M.; StJohn, D.

    2016-03-01

    Recent verification of the analytical Interdependence model by a numerical solidification model (µMatIC) confirmed the critical role of constitutional supercooling (CS) in achieving sufficient undercooling to trigger successful nucleation events. The location of the maximum amount of CS (ΔTCSmax) is some distance from the interface of the previously growing grain and this distance contributes to the final as-cast grain size. The effect of the thermal gradient, G, on the size of the CS zone (CSZ) was neglected in that work. However, G is expected to affect the size of the CSZ (i.e. the length of the CSZ, x’ CSZ , and the location of ΔTCSmax, x’ CSmax ). This investigation assesses the effect of G on x’csz and x' CSmax . A range of G values is introduced into both the analytical and the numerical models to obtain a correlation between the value of G and the dimensions of the CSZ. The result of a test case from the analytical model shows that x’ CSmax initially decreases rapidly and then decreases gradually approaching zero at very high values of G. Independent of the analytical model, the results from the numerical model replicate the trend obtained from the analytical model.

  19. Decrease in water activity due to fluid absent partial melting monitored with water content in biotite in the Western Adamello contact aureole (Italy)

    NASA Astrophysics Data System (ADS)

    Siron, Guillaume; Baumgartner, Lukas; Bouvier, Anne-Sophie; Vennemann, Torsten

    2016-04-01

    The fluorine and chlorine exchange on the hydroxyl site in micas is used to monitor changes in fluid composition (Munoz 1984). Most studies assume that the OH-site does not contain vaccancies, since the vast majority of studies use analytical techniques that does not allow to directly measure the OH- content of the mica. Nevertheless, studies have shown that significant amounts of O2- are present, and its concentration increases with temperature and titanium content. This feature was intrepreted as the consequence of a Ti-oxygen exchange in amphibolite and granulite facies rocks (Dyar et al. 1993, Cesare et al. 2008). Here, we present OH, F, Cl data for biotite from contact aureoles from biotite-schist to partially molten sillimanite-cordierite schists. OH-F-Cl content of biotites were analyzed using Secondary Ion Mass Spectrometry (SIMS), and major elements were analyzed by EMP. Samples were collected in the mid-crustal Western Adamello contact aureole (Italian Alps, Floess and Baumgartner, 2013). For that purpose we used biotite standards with water content constrained by Thermal Conversion Elemental Analyzer (TC/EA) see Bauer and Vennemann 2014, at a level of precision of 0.1-0.2 wt% (2SD). SIMS measurements typically have a precision of 0.1wt% (2SD), corresponding to the homogeneity of the internal standard at the SwissSIMS laboratory. OH- content decreases in samples with increasing peak temperature and Ti content (Ti range for biotites of 0.15-0.42 p.f.u for all samples). Nevertheless, within each individual sample, OH- is not a function of Ti. Ti variations are about 0.4 p.f.u., which is ten times the analytical uncertainty of the EMP analysis (0.004 p.f.u., 1SD). Water content is constant within analytical precision for each sample. The mean of OH- measurements is 3.41 p.f.u. in biotite and garnet grade samples, whereas those of samples in the partially molten zone have values of 3.27 p.f.u. We do not see any correlation with XMg or F and Cl. Hence, we

  20. Influence of gravitational and vibrational convection on the heat- and mass transfer in the melt during crystal growing by Bridgman and floating zone methods

    NASA Astrophysics Data System (ADS)

    Fedorov, Oleg

    2016-07-01

    Space materials science is one of the priorities of different national and international space programs. The physical processes of heat and mass transfer in microgravity (including effect of g-jitter) is far from complete clarity, especially for important practical technology for producing crystals from the melt. The idea of the impact on crystallizing melt by low frequency vibration includes not only the possibility to suppress unwanted microaccelerations, but also to actively influence the structure of the crystallization front. This approach is one of the most effective ways to influence the quality of materials produced in flight conditions. The subject of this work is the effect of vibrations on the thermal and hydrodynamic processes during crystal growth using Bridgman and floating zone techniques, which have the greatest prospect of practical application in space. In the present approach we consider the gravitational convection, Marangoni convection, as well as the effect of vibration on the melt for some special cases. The results of simulation were compared with some experimental data obtained by the authors using a transparent model substance - succinonitrile (Bridgman method), and silicon (floating zone method). Substances used, process parameters and characteristics of the experimental units correspond the equipment developed for onboard research and serve as a basis for selecting optimum conditions vibration exposure as a factor affecting the solidification pattern. The direction of imposing vibrations coincides with the axis of the crystal, the frequency is presented by the harmonic law, and the force of gravity was varied by changing its absolute value. Mathematical model considered axisymmetric approximation of joint convective-conductive energy transfer in the system crystal - melt. Upon application of low-frequency oscillations of small amplitude along the axis of growing it was found the suppression of the secondary vortex flows near the

  1. Responses of canopy transpiration and canopy conductance of peach (Prunus persica) trees to alternate partial root zone drip irrigation

    NASA Astrophysics Data System (ADS)

    Gong, Daozhi; Kang, Shaozhong; Zhang, Jianhua

    2005-08-01

    We investigated canopy transpiration and canopy conductance of peach trees under three irrigation patterns: fixed 1/2 partial root zone drip irrigation (FPRDI), alternate 1/2 partial root zone drip irrigation (APRDI) and full root zone drip irrigation (FDI). Canopy transpiration was measured using heat pulse sensors, and canopy conductance was calculated using the Jarvis model and the inversion of the Penman-Monteith equation. Results showed that the transpiration rate and canopy conductance in FPRDI and APRDI were smaller than those in FDI. More significantly, the total irrigation amount was greatly reduced, by 34.7% and 39.6%, respectively for APRDI and FPRDI in the PRDI (partial root zone drip irrigation) treatment period. The daily transpiration was linearly related to the reference evapotranspiration in the three treatments, but daily transpiration of FDI is more than that of APRDI and FPRDI under the same evaporation demand, suggesting a restriction of transpiration water loss in the APRDI and FPRDI trees. FDI needed a higher soil water content to carry the same amount of transpiration as the APRDI and FPRDI trees, suggesting the hydraulic conductance of roots of APRDI and FPRDI trees was enhanced, and the roots had a greater water uptake than in FDI when the average soil water content in the root zone was the same. By a comparison between the transpiration rates predicted by the Penman-Monteith equation and the measured canopy transpiration rates for 60 days during the experimental period, an excellent correlation along the 1:1 line was found for all the treatments (R2 > 0.80), proving the reliability of the methodology.

  2. Melt densities in the CaO-FeO-Fe 2O 3-SiO 2 system and the compositional dependence of the partial molar volume of ferric iron in silicate melts

    NASA Astrophysics Data System (ADS)

    Dingwell, Donald B.; Brearley, Mark

    1988-12-01

    The densities of 10 melts in the CaO-FeO-Fe 2O 3-SiO 2 system were determined in equilibrium with air, in the temperature range of 1200 to 1550°C, using the double-bob Archimedean technique. Melt compositions range from 6 to 58 wt% SiO 2, 14 to 76 wt% Fe 2O 3 and 10 to 46 wt% CaO. The ferric-ferrous ratios of glasses drop-quenched from loop fusion equilibration experiments were determined by 57Fe Mössbauer spectroscopy. Melt densities range from 2.689 to 3.618 gm/cm 3 with a mean standard deviation from replicate experiments of 0.15%. Least-squares regressions of molar volume versus molar composition have been performed and the root mean squared deviation shows that a linear combination of partial molar volumes for the oxide components (CaO, FeO, Fe 2O 3 and SiO 2) cannot describe the data set within experimental error. Instead, the inclusion of excess terms in CaFe 3+ and CaSi (product terms using the oxides) is required to yield a fit that describes the experimental data within error. The nonlinear compositional-dependence of the molar volumes of melts in this system can be explained by structural considerations of the roles of Ca and Fe 3+. The volume behavior of melts in this system is significantly different from that in the Na 2O-FeO-Fe 2O 3-SiO 2 system, consistent with the proposal that a proportion of Fe 3+ in melts in the CaO-FeO-Fe 2O 3-SiO 2 system is not tetrahedrally-coordinated by oxygen, which is supported by differences in 57Fe Mössbauer spectra of glasses. Specifically, this study confirms that the 57Fe Mössbauer spectra exhibit an area asymmetry and higher values of isomer shift of the ferric doublet that vary systematically with composition and temperature (this study; Dingwell and Virgo, 1987, 1988). These observations are consistent with a number of other lines of evidence ( e.g., homogeneous redox equilibria, Dickenson and Hess, 1986; viscosity, Dingwell and Virgo, 1987,1988). Two species of ferric iron, varying in proportions with

  3. Effect of subduction components on production of basalts from Tateshina volcano, central Japan: geochemical calculation of dehydration of subducting oceanic crust and partial melting of overlying sediments, and subsequent fluid-mantle interaction

    NASA Astrophysics Data System (ADS)

    Katoh, Masayasu; Shuto, Kenji

    Effect of subduction components on production of basalts from Tateshina volcano, central Japan: geochemical calculation of dehydration of subducting oceanic crust and partial melting of overlying sediments, and subsequent fluid-mantle interaction

  4. Effect of partial melting on Vp and Vs in crustal enclaves from Mazarrón (SE Spain)

    NASA Astrophysics Data System (ADS)

    Ferri, Fabio; Burlini, Luigi; Cesare, Bernardo

    2016-03-01

    The combination of compressional and shear wave velocity is an important tool in discriminating rock types and identifying residing melts within the continental crust. Here we report the laboratory measurements for Vp and Vs obtained in varying conditions up to those exceeding the beginning of melting (950 °C at 500 MPa confining pressure) on two residual garnet-biotite-sillimanite-cordierite-spinel metapelitic enclaves recovered from the Neogene dacites of Mazarrón (SE Spain). The enclaves preserve widespread interstitial rhyolitic glass as evidence of primary melt extraction. At 500 MPa, the experimental Vp ranges from 7.21 ÷ 7.46 km s- 1 at room temperature to 5.44 km/s at 950 °C. The mean Vs is 4.5 km/s at room temperature with shear-wave splitting of 0.25 ÷ 0.3 km/s, measured along three mutually orthogonal directions. When temperature increases, the Vs evidences a reversible slope change at about 650 °C, and the shear-wave splitting reduces to zero (isotropic material) at 850-950 °C, where the sample Vs is ~ 3.0 km/s. The Vp anisotropy is 7-10% up to 700 °C increasing to ~ 20% at 950 °C, while the Vs anisotropy continuously decreases with temperature from 5% to 7% at room temperature to zero at 950 °C. No mineral reactions are observed up to 650-700 °C; however, microstructure equilibrates due to the relaxation of the primary glass at the glass transition temperature. Between 850 °C and 950 °C, a new melting reaction is observed producing biotite + spinel + ilmenite + plagioclase + melt. At melting, the rock becomes isotropic for Vs, and Poisson's ratio increases to 0.30. Our seismic data show that the seismic signature of high grade metapelitic rocks is similar to that of mafic materials. The evolution of Vp and Vs at melting conditions is compatible with the geophysical data of the area, supporting the hypothesis of the current existence of anatectic melts at intermediate depths of the Alborán domain.

  5. Do melt-rich shear zones lubricate rift flanks? 3-D spatial gradients in anisotropy beneath the East African Rift in Ethiopia

    NASA Astrophysics Data System (ADS)

    Holtzman, B. K.; Gaherty, J. B.; Kendall, J.; Stuart, G.

    2006-12-01

    Melt-enhanced weakening of the mantle may be essential for a continent to break apart and rift. A primary means of understanding this aspect of the dynamics of rifting (and other geodynamic settings) is the interpretation of seismic anisotropy in terms of melt distribution and/or mantle flow direction. In recent rock- deformation experiments, the relationships between flow direction and seismic fast direction are complicated by the presence of water (e.g. Katayama et al., 2004) and segregated melt (Holtzman et al. 2003). In the latter, deviatoric stress drives melt to organize into networks of melt-rich shear zones. Scaling from laboratory to upper mantle conditions predicts characteristic network spacings of <1 km, less than wavelengths of measured seismic waves; thus they should cause significant seismic anisotropy. Measurable gradients in anisotropy may be diagnostic indicators of gradients in melt segregation. Because melt-rich shear zones will weaken the mantle on a large scale, the presence of such anisotropy gradients would map to gradients in viscosity. To map melt distribution beneath the rift and test for the presence or absence of this process, we combine measurements of seismic velocities beneath the East African Rift in Ethiopia with modeling of elastic properties of aligned, segregated melt and olivine fabric. Analysis of SKS phases has shown that fast directions parallel magmatic centers in the rift and splitting magnitudes are largest near the rift flanks, consistent with the hypothesis above (e.g. Kendall et al., 2006). Preliminary analysis of Love-Rayleigh differential times across the rift are consistent with a vertical fast axis, suggesting the presence of a vertically aligned, rift parallel melt phase down to the solidus (Pilidou et al., 2005). We expand on these results by applying a cross-correlation procedure to precisely estimate relative amplitude and phase of surface waves traversing the rift. Data are derived from the EAGLE and Ethiopia

  6. Tularosa Basin Play Fairway Analysis: Partial Basin and Range Heat and Zones of Critical Stress Maps

    SciTech Connect

    Adam Brandt

    2015-11-15

    Interpolated maps of heat flow, temperature gradient, and quartz geothermometers are included as TIF files. Zones of critical stress map is also included as a TIF file. The zones are given a 5km diameter buffer. The study area is only a part of the Basin and Range, but it does includes the Tularosa Basin.

  7. [Determination of N-nitrosodimethylamine in beer by frozen zone melting liquid-liquid extraction/gas chromatography].

    PubMed

    Peng, Qiaorong; Tang, Tao; Yu, Shuxin; Sun, Yuanshe; Lei, Wu; Wang, Fengyun; Zhang, Weibing; Li, Tong

    2014-04-01

    A simple and effective sample enrichment method of frozen zone melting liquid-liquid extraction was optimized and validated for the analysis of trace N-nitrosodimethylamine (NDMA) in beer samples. The method was based on high pressure liquid-liquid extraction with a low temperature frozen step. The 90 mL beer was placed in a container with 10 mL dichloromethane. After agitation, the sample was kept in a freezer for 16 h at -19 degrees C. The organic extract was analyzed by gas chromatography with a flame ionization detector (GC-FID). The accuracy, precision, detection and quantification limits and linearity of the method were evaluated. The results showed that the calibration curve of NDMA was linear in the range of 5-200 mg/L with a good correlation coefficient (r2) of 0.999 6. The recoveries at the spiked levels of 5, 10 and 20 mg/L were 84.94%, 83.24%, 85.14% with the relative standard deviations (n = 7) of 3.06%, 3.19%, 2.63%, respectively. The ordinary extraction method of N-nitrosodimethylamine in beer includes the four steps of low-temperature distillation, liquid-liquid extraction, rotary evaporation and nitrogen blowing concentration. With the extremely low volume of solvent used, the proposed extraction method proved to be easy and simple, and adequate for high-throughput analysis at low cost. PMID:25069335

  8. [Determination of N-nitrosodimethylamine in beer by frozen zone melting liquid-liquid extraction/gas chromatography].

    PubMed

    Peng, Qiaorong; Tang, Tao; Yu, Shuxin; Sun, Yuanshe; Lei, Wu; Wang, Fengyun; Zhang, Weibing; Li, Tong

    2014-04-01

    A simple and effective sample enrichment method of frozen zone melting liquid-liquid extraction was optimized and validated for the analysis of trace N-nitrosodimethylamine (NDMA) in beer samples. The method was based on high pressure liquid-liquid extraction with a low temperature frozen step. The 90 mL beer was placed in a container with 10 mL dichloromethane. After agitation, the sample was kept in a freezer for 16 h at -19 degrees C. The organic extract was analyzed by gas chromatography with a flame ionization detector (GC-FID). The accuracy, precision, detection and quantification limits and linearity of the method were evaluated. The results showed that the calibration curve of NDMA was linear in the range of 5-200 mg/L with a good correlation coefficient (r2) of 0.999 6. The recoveries at the spiked levels of 5, 10 and 20 mg/L were 84.94%, 83.24%, 85.14% with the relative standard deviations (n = 7) of 3.06%, 3.19%, 2.63%, respectively. The ordinary extraction method of N-nitrosodimethylamine in beer includes the four steps of low-temperature distillation, liquid-liquid extraction, rotary evaporation and nitrogen blowing concentration. With the extremely low volume of solvent used, the proposed extraction method proved to be easy and simple, and adequate for high-throughput analysis at low cost.

  9. Subpixel variability of MODIS albedo retrievals and its importance for ice sheet surface melting in southwestern Greenland's ablation zone

    NASA Astrophysics Data System (ADS)

    Moustafa, S.; Rennermalm, A. K.; Roman, M. O.; Koenig, L.; Smith, L. C.; Schaaf, C.; Wang, Z.; Mioduszewski, J.

    2013-12-01

    On the Greenland ice sheet, albedo declined across 70% of its surface since 2000, with the greatest reduction in the lower 600 m of the southwestern ablation zone. Because albedo plays a prominent role in the ice sheet surface energy balance, its decline has resulted in near doubling of meltwater production. To characterize ice sheet albedo, Moderate Imaging Spectrometer (MODIS) surface albedo products are typically used. However, it is unclear how the spatial variability of albedo within a MODIS pixel influences surface melting and whether it can be considered a linear function of albedo. In this study, high spatiotemporal resolution measurements of spectral albedo and ice sheet surface ablation were collected along a ~ 1.3 km transect during June 2013 within the Akuliarusiarsuup Kuua (AK) River watershed in southwest Greenland. Spectral measurements were made at 325-1075 nm using a Analytical Spectral Devices (ASD) spectroradiometer, fitted with a Remote Cosine Receptor (RCR). In situ albedo measurements are compared with the daily MODIS albedo product (MCD43A) to analyze how space, time, surface heterogeneity, atmospheric conditions, and solar zenith angle geometry govern albedo at different scales. Finally, analysis of sub-pixel albedo and ablation reveal its importance on meltwater production in the lower parts of the ice sheet margin.

  10. Origin of felsic achondrites Graves Nunataks 06128 and 06129, and ultramafic brachinites and brachinite-like achondrites by partial melting of volatile-rich primitive parent bodies

    NASA Astrophysics Data System (ADS)

    Day, James M. D.; Walker, Richard J.; Ash, Richard D.; Liu, Yang; Rumble, Douglas; Irving, Anthony J.; Goodrich, Cyrena A.; Tait, Kimberly; McDonough, William F.; Taylor, Lawrence A.

    2012-03-01

    New major- and trace-element abundances, highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, Re) abundances, and oxygen and rhenium-osmium isotope data are reported for oligoclase-rich meteorites Graves Nunataks 06128 and 06129 (GRA 06128/9), six brachinites (Brachina; Elephant Morraine 99402/7; Northwest Africa (NWA) 1500; NWA 3151; NWA 4872; NWA 4882) and three olivine-rich achondrites, which are referred to here as brachinite-like achondrites (NWA 5400; NWA 6077; Zag (b)). GRA 06128/9 represent examples of felsic and highly-sodic melt products from an asteroid that may provide a differentiation complement to brachinites and/or brachinite-like achondrites. The new data, together with our petrological observations, are consistent with derivation of GRA 06128/9, brachinites and the three brachinite-like achondrites from nominally volatile-rich and oxidised 'chondritic' precursor sources within their respective parent bodies. Furthermore, the range of Δ17O values (˜0‰ to -0.3‰) among the meteorites indicates generation from isotopically heterogeneous sources that never completely melted, or isotopically homogenised. It is possible to generate major- and trace-element compositions similar to brachinites and the three studied brachinite-like achondrites as residues of moderate degrees (13-30%) of partial melting of primitive chondritic sources. This process was coupled with inefficient removal of silica-saturated, high Fe/Mg felsic melts with compositions similar to GRA 06128/9. Melting of the parent bodies of GRA 06128/9, brachinites and brachinite-like achondrites halted well before extensive differentiation, possibly due to the exhaustion of the short-lived radionuclide 26Al by felsic melt segregation. This mechanism provides a potential explanation for the cessation of run-away melting in asteroids to preserve achondrites such as GRA 06128/9, brachinites, brachinite-like achondrites, acapulcoite-lodranites, ureilites and aubrites. Moderate degrees of

  11. Zr complexation in high pressure fluids and silicate melts and implications for the mobilization of HFSE in subduction zones

    NASA Astrophysics Data System (ADS)

    Louvel, Marion; Sanchez-Valle, Carmen; Malfait, Wim J.; Testemale, Denis; Hazemann, Jean-Louis

    2013-03-01

    Field observations and solubility experiments show evidence for the efficient mobilization of nominally insoluble HFSE (i.e., Ti, Zr, Nb and Hf) by high pressure fluids, probably via complexation with polymerized alkali-silica dissolved species and halogens (F and Cl). Here we investigate the complexation of Zr in subduction-related fluids (aqueous fluids and hydrous haplogranite melts) up to 800 °C and 2.4 GPa using X-ray absorption spectroscopy (XANES and EXAFS) in a hydrothermal diamond anvil cell and provide evidence for the formation of Zr-O-Si/Na polymeric species in alkali-(alumino)silicate fluids at high pressure. Zr4+ speciation in dilute fluids (2.5 wt% HCl) is dominated by 8-fold-coordinated [Zr(H2O)8]4+ hydrated complexes at room conditions and no evidence for extensive Zr-Cl complexation in the fluid was found up to 420 °C, as confirmed by ab initio XANES calculations of various ZrO8-xClx clusters. The addition of Na and Si dissolved species (from 35 to 60 wt% dissolved Na2Si2O5, NS2) into the fluid favors the formation of alkali-zirconosilicate clusters Zr-O-Si/Na similar to those found in vlasovite (Na2ZrSi4O11), with Zr4+ in octahedral coordination with oxygen (Zr-O distance = 2.09 ± 0.04 Å) and ˜6 Si (Na) second neighbors (Zr-Si/Na distance = 3.66 ± 0.06 Å). This coordination environment also dominates Zr speciation in F-free and F-bearing NS2 and haplogranite glasses and high pressure hydrous haplogranite melts (15.5-33 wt% dissolved H2O) in the investigated pressure-temperature range. The XAS analyses, assisted by ab initio XANES calculations, are not conclusive concerning the extent of Zr-F complexation in hydrous granitic melts. Alkali-zirconosilicate Zr-O-Si/Na clusters such as those identified in this study may explain the enhanced solubility of zircon ZrSiO4 (and other HFSE-bearing minerals) in alkali-aluminosilicate-bearing aqueous fluids produced by dehydration and melting of the slab and provide a favorable mechanism for the

  12. Melting in super-earths.

    PubMed

    Stixrude, Lars

    2014-04-28

    We examine the possible extent of melting in rock-iron super-earths, focusing on those in the habitable zone. We consider the energetics of accretion and core formation, the timescale of cooling and its dependence on viscosity and partial melting, thermal regulation via the temperature dependence of viscosity, and the melting curves of rock and iron components at the ultra-high pressures characteristic of super-earths. We find that the efficiency of kinetic energy deposition during accretion increases with planetary mass; considering the likely role of giant impacts and core formation, we find that super-earths probably complete their accretionary phase in an entirely molten state. Considerations of thermal regulation lead us to propose model temperature profiles of super-earths that are controlled by silicate melting. We estimate melting curves of iron and rock components up to the extreme pressures characteristic of super-earth interiors based on existing experimental and ab initio results and scaling laws. We construct super-earth thermal models by solving the equations of mass conservation and hydrostatic equilibrium, together with equations of state of rock and iron components. We set the potential temperature at the core-mantle boundary and at the surface to the local silicate melting temperature. We find that ancient (∼4 Gyr) super-earths may be partially molten at the top and bottom of their mantles, and that mantle convection is sufficiently vigorous to sustain dynamo action over the whole range of super-earth masses.

  13. Partial melting and upwelling rates beneath the Azores from a U-series isotope perspective [rapid communication

    NASA Astrophysics Data System (ADS)

    Bourdon, Bernard; Turner, Simon P.; Ribe, Neil M.

    2005-10-01

    We report U-series systematics ( 238U- 230Th- 231Pa- 226Ra) for basalts from the Azores islands and the nearby mid-Atlantic ridge with the aim of constraining melting processes in this region of plume-ridge interaction. Both 230Th and 231Pa excess show rough negative trends with indices of source enrichment (Sr, Nd and Pb isotopes) which cannot be explained by melting of a source variably enriched by mafic components (e.g. pyroxenite). However, there is evidence for a distinct source component, possibly sediment, beneath Sao Miguel which may give rise to these trends. 231Pa excess and Sm-Nd fractionation are positively and negatively correlated (respectively) with distance from the centre of the plume, while 230Th excesses show no clear trend. This suggests that mantle upwelling velocity exerts a strong control on U-Pa fractionation and that melting is initiated deeper in the centre of the plume. These observations are used to infer melting conditions beneath the mid-Atlantic ridge and Azores islands. The mantle upwelling velocity is constrained to be 3-4 cm/a which is smaller than that inferred for Hawaii or Iceland. Predicted 226Ra-excesses are similar to, or lower than those measured, suggesting high velocity melt ascent in channels and rapid differentiation prior to eruption. The effect of the presence of volatiles in the source is also investigated and we show that the presence of water could explain the 230Th and 231Pa trends as a function of distance across the plume. A 3-D model for the Azores plume can reproduce the U-series isotope observations.

  14. Maine Pseudotachylyte Localities and the Role of Host Rock Anisotropy in Fault Zone Development and Frictional Melting

    NASA Astrophysics Data System (ADS)

    Swanson, M. T.

    2004-12-01

    Three brittle strike-slip fault localities in coastal Maine have developed pseudotachylyte fault veins, injection veins and other reservoir structures in a variety of host rocks where the pre-existing layering can serve as a controlling fabric for brittle strike-slip reactivation. Host rocks with a poorly-oriented planar anisotropy at high angles to the shear direction will favor the development of R-shears in initial en echelon arrays as seen in the Two Lights and Richmond Island Fault Zones of Cape Elizabeth that cut gently-dipping phyllitic quartzites. These en echelon R-shears grow to through-going faults with the development of P-shear linkages across the dominantly contractional stepovers in the initial arrays. Pseudotachylyte on these faults is very localized, typically up to 1-2 mm in thickness and is restricted to through-going fault segments, P-shear linkages and some sidewall ripouts. Overall melt production is limited by the complex geometry of the multi-fault array. Host rocks with a favorably-oriented planar anisotropy for reactivation in brittle shear, however, preferentially develop a multitude of longer, non-coplanar layer-parallel fault segments. Pseudotachylyte in the newly-discovered Harbor Island Fault Zone in Muscongus Bay is developed within vertical bedding on regional upright folds with over 50 individual layer-parallel single-slip fault veins, some of which can be traced for over 40 meters along strike. Many faults show clear crosscuts of pre-existing quartz veins that indicate a range of coseismic displacements of 0.23-0.53 meters yielding fault vein widths of a few mm and dilatant reservoirs up to 2 cm thick. Both vertical and rare horizontal lateral injection veins can be found in the adjoining wall rock up to 0.7 cm thick and 80 cm in length. The structure of these faults is simple with minor development of splay faults, sidewall ripouts and strike-slip duplexes. The prominent vertical flow layering within the mylonite gneisses of

  15. Experimental determination of electrical conductivity during deformation of melt-bearing olivine aggregates: Implications for electrical anisotropy in the oceanic low velocity zone

    NASA Astrophysics Data System (ADS)

    Caricchi, Luca; Gaillard, Fabrice; Mecklenburgh, Julian; Le Trong, Emmanuel

    2011-02-01

    A novel experimental setup was used to measure in-situ variations of electrical conductivity (EC) during deformation in torsion (simple shear) at 300 MPa confining pressure and temperatures between 873 and 1473 K. This setup is designed to test if deformation of partially molten systems can produce electrical anisotropy. The motivation for this study comes from the observation that the Lithosphere-Asthenosphere Boundary (LAB) at mid-ocean ridges and in particular at the East Pacific Rise is strongly electrically anisotropic. In an initial set of calibration experiments, the variation of EC with temperature (873-1473 K) was determined for Carrara marble, Åheim dunite and basalt-bearing olivine aggregates. EC was then monitored during deformation experiments at 1473 K and measured in the frequency range between 6 MHz and 1 Hz. The electrical response of the different materials tested as a function of frequency, changes significantly depending on the presence, absence, proportion and distribution of melt contained in the specimen. Melt-free samples show a single conduction mechanism whereas melt-bearing samples display two conduction mechanisms linked in series, reflecting the contribution of isolated and connected melt. Impedance was measured along the sample radius, in a direction parallel to the shear gradient inherent in torsion experiments. During the tests, increasing values of the impedance measured suggest that the long range melt connectivity decreases radially, and melt drains from low to high shear stress regions. The conductivity, calculated from impedance measurements, is low and comparable to values measured along mid-ocean ridges. We suggest that electrical anisotropy of the LAB reflects an alternation of melt-enriched and melt-depleted channels elongated in the spreading direction possibly induced by spreading velocity gradients along the ridge. This implies that the observed electrical anisotropy reveals larger scale processes than strain

  16. Dependence of the Tidal Response on the Internal Structure of the Moon: Geodetic Implication to the Partial Melt Layer at the Lower-Most Part of the Lunar Mantle

    NASA Astrophysics Data System (ADS)

    Harada, Y.; Goossens, S. J.; Matsumoto, K.; Yan, J.; Ping, J.; Noda, H.

    2012-12-01

    viscosity in this part is probably lower than that in the upper portion because the knowledge of seismology also indicates the presence of a high attenuation zone. On the other hand, the viscosity of the upper portion is regarded to be uniform in here, and fixed to the maximum value of the above parameter range. As a result, it is clarified that the viscosity solution consistent with geodetic observations of both rotation and gravity field exists if the interior structure includes the specific low viscosity zone. There is just one narrow range of allowable viscosity with the observed Q, which can only be explained by this low viscosity zone. This viscosity range determines a numerical k2 which is consistent with the observed values. As a conclusion, the strong seismic attenuation zone inside the lunar interior is probably equivalent to the low viscosity zone. Particularly, it is the remarkable point that the value of the viscosity inferred here is too low considering solid rock whereas it is too high considering complete melt. Therefore, as has formerly been pointed out, the partial melting would occur in this lower-most part like that of the ultra-low velocity zone on the Earth. Moreover, this zone is expected to include the fluid phase with a ratio corresponding to the rheologically critical melt fraction.

  17. Melt- versus fluid-induced metasomatism in spinel to garnet wedge peridotites (Ulten Zone, Eastern Italian Alps): clues from trace element and Li abundances

    NASA Astrophysics Data System (ADS)

    Scambelluri, M.; Hermann, J.; Morten, L.; Rampone, E.

    2006-04-01

    The peridotite bodies of the Ulten Zone (Upper Austroalpine, Italian Eastern Alps) are enclosed in Variscan migmatites and derive from a mantle wedge environment. They display the progressive transformation of porphyroclastic spinel peridotites ( T=1,200°C; P=1.5 GPa) into fine-grained garnet-amphibole peridotites ( T=850°C; P=3 GPa). Detailed bulk-rock and mineral trace element analyses of a sample suite documenting the entire metamorphic evolution of the peridotites revealed several stages of metasomatism. The spinel peridotites derive from a depleted mantle that became enriched in some large ion lithophile element (LILE) and light rare earth elements (LREE). The same signature pertains to clinopyroxene and orthopyroxene, indicating that this metasomatic signature was acquired at the recorded temperature of 1,200°C. Such a temperature is considerably above the wet peridotite solidus and hence the metasomatic agent must have been a hydrous melt. Moreover, the Li-enrichment of the spinel-facies pyroxenes (up to 24 ppm Li) reflects disequilibrium distribution after exchange with a presumably mafic melt. cpx/opx D Li=3-7 and cpx/ol D Li=2.7-8 indicate that the spinel-facies clinopyroxene hosts higher Li amounts than the coexisting minerals. LREE fractionation, variable LREE enrichment, LILE enrichment with respect to HFSE (average clinopyroxene Pb N /Nb N =16-90) in spinel lherzolites can be related to chromatographic effects of porous melt flow. The significant enrichment of pyroxenes from the spinel lherzolites in Pb, U and Li indicates that the metasomatic melt was subduction-related. All these features suggest that the spinel lherzolites formed a mantle wedge layer percolated by melts carrying recycled crustal components and rising from a deeper source of subduction magmas. The garnet + amphibole peridotites equilibrated at temperatures well below the wet solidus in the presence of an aqueous fluid. Bulk-rock trace element patterns display pronounced positive

  18. Magnetocaloric effect in a dual-phase coupled LaFe11Si2 crystal prepared by a modified high-pressure zone-melting technique

    NASA Astrophysics Data System (ADS)

    Feng, Shutong; Fang, Yue; Zhai, Qijie; Luo, Zhiping; Zheng, Hongxing

    2016-10-01

    A modified high-pressure optical zone-melting technique was adopted to grow a rare-earth-based LaFe11Si2 crystal in the present work. Dual-phase coupled microstructure was obtained where aligned α(Fe) phase distributed in the La(Fe,Si)13 matrix. Magnetic measurements showed that the produced crystal underwent a second-order magnetic transition in the vicinity of 250 K. Under a magnetic field change of 30 kOe, the refrigeration capacity (RC) of the produced crystal reached up to 162 J/kg. It was confirmed that zone-melting crystal growth technique is an effective approach to strikingly enhance the magnetocaloric effect of La-Fe-Si refrigeration materials.

  19. The limited depth range of a metallic-Fe-bearing layer in the lower mantle and its implications for partial melting

    NASA Astrophysics Data System (ADS)

    Girard, J.; Karato, S. I.

    2014-12-01

    Partial melting in (most of) the lower mantle occurs only by the presence of volatile elements such as hydrogen (and/or carbon). The experimental studies by [Kawamoto, 2004] showed that partial melting is possible even at temperature of 1673 K in the shallow lower mantle if there is sufficient water. However, if metallic Fe is present in the lower mantle as suggested by [Frost et al., 2004]). most of hydrogen will be dissolved in metallic Fe, and thus melting will be prevented, making it difficult to explain a seismic velocity drop in the shallow lower mantle [Schmandt et al., 2014]. In this study we conducted high pressure experiments using the Rotational Drickamer Apparatus (RDA), on bridgmanite (Mg,Fe)SiO3 + (Mg,Fe)O mixture at pressure up to 23-29 GPa and temperature of about 2000-2200K. Using the advantage of the new RDA cell design which provide a larger pressure gradient (~6 GPa across the sample), we report experimental observations showing that metallic Fe is formed only in the low pressure conditions, 24-26.5 GPa (corresponding to the depth range of 660-730 km), leaving the shallow lower mantle minerals "dry". Our results are also consistent with the published results by [Irifune et al., 2010; Sinmyo and Hirose, 2013] where they did not find any metallic Fe above 27 GPa. Therefore we conclude that metallic Fe is present only in the narrow depth range in the lower mantle. In such a case partial melt would be impossible and only occur at depth greater than 730 km. Our results explain why a velocity drop is observed at ~730 km not at 660 km [Schmandt et al., 2014]. The present results also have important implications for other geochemical issues including the behaviors of siderohpile elements during core formation. Frost, D. J., et al., (2004), Nature, 428, 409-412. Irifune, T., et al., (2010), Science, 327, 193-195. Kawamoto, T. (2004), Physics of Earth and Planetary Interiors, 143/144, 387-395. Schmandt, B., et al., (2014), Science, 344(6189), 1265

  20. Petrogenesis of adakite and high-Nb basalt association in the SW of Sabzevar Zone, NE of Iran: Evidence for slab melt-mantle interaction

    NASA Astrophysics Data System (ADS)

    Mazhari, Seyed Ali

    2016-04-01

    Adakitic rocks appear in close association with high Nb basaltic (HNB) rocks in the SW of Sabzevar ophiolitic belt. Adakites are calc-alkaline and include trachy-andesite, teachy-dacite and dacite. These rocks are rich in Na2O, Al2O3 and Sr and show depletion in MgO, Y and Yb. Adakitic samples are defined by high Sr/Y (88-128) and La/Yb (20-45) ratios; as well as a lack of Eu anomaly (Eu/Eu∗ = 0.92-0.99) in REE patterns. Geochemical composition indicates that adakites were generated from slab melting in a high pressure-high heat flow subducting setting. Different adakitic rocks have been formed by various slab partial melting degrees and reaction of adakitic magma with heterogeneous mantle wedge rocks. HNB rocks are alkaline, nepheline normative and sodic (Na2O/K2O = 2.7-3.4) with high concentration of Al2O3, TiO2, MgO, P2O5, LILE and HFSE, especially Nb (30-56 ppm). These basalts show fractionated REE patterns with elevated LREE/HREE (LaN/YbN = 20-25) and trace elements contents suggest their generation by low partial melting degrees (<2%) from garnet-peridotite origin which have already metasomatized by adakitic melts.

  1. Negligible sulfur isotope fractionation during partial melting: Evidence from Garrett transform fault basalts, implications for the late-veneer and the hadean matte

    NASA Astrophysics Data System (ADS)

    Labidi, J.; Cartigny, P.

    2016-10-01

    We report the quadruple sulfur isotope compositions, sulfur contents and speciation major and trace elements (including copper and chlorine abundances) of eleven basalts collected in the Garrett transform fault. We combine these data to discuss the absence of S isotopic fractionation along both partial melting and low-pressure fractional crystallization. The variations of K2O/TiO2 and La/SmN-ratios (respectively between 0.017 and 0.067, and between 0.31 and 0.59) suggest a range of depletion in Garrett lavas that includes ultra depleted samples (K2O/TiO2 < 0.03). The remarkable level of incompatible element depletion is consistent with re-melting of a depleted source. Contrasting with incompatible element depletion, all samples display similar S and Cu abundance (at a given major-element composition) to mid-ocean ridge basalts (MORB). This indicates that Garrett Intra Transform Lavas (ITL) are sulfide saturated as MORB are. Copper content for Garrett parental melts (MgO >8%) are ∼80 ppm, indistinguishable from MORBs. This requires their mantle sources, variably depleted in incompatible element, to host residual sulfide buffering the Cu content of all erupted melts. We calculate a minimum S content for the source of ultra-depleted Garrett lavas of 100 ± 40ppmS, i.e. roughly a factor of 2 below the MORB mantle source. After exclusion of a single sample with Cl/K ratio >0.1 that likely experienced hydrothermal sulfide assimilation, Garrett ITLs display homogeneous δ34 S, Δ33 S and Δ36 S values with averages of - 0.68 ± 0.08 ‰, + 0.010 ± 0.005 ‰ and - 0.04 ± 0.04 ‰, respectively (all 1σ, n = 10). The δ34 S values display no relationship with either K2O/TiO2 variations or extent sulfide fractionation. From these observations, we derive a 34S/32S fractionation factor between exsolved sulfides and sulfide dissolved in silicate melts of 1.0000 ± 0.0003. The S isotopic fractionation during partial melting can thus be considered as negligible, and both

  2. Andesitic crustal growth via mélange partial melting: Evidence from Early Cretaceous arc dioritic/andesitic rocks in southern Qiangtang, central Tibet

    NASA Astrophysics Data System (ADS)

    Hao, Lu-Lu; Wang, Qiang; Wyman, Derek A.; Ou, Quan; Dan, Wei; Jiang, Zi-Qi; Yang, Jin-Hui; Li, Jie; Long, Xiao-Ping

    2016-05-01

    Deciphering the petrogenesis of andesitic/dioritic rocks is fundamental to understanding the formation of the continental crust. Here we present detailed petrology, geochronology, major and trace element, Sr-Nd-Hf-O isotope data for the Early Cretaceous (˜122 Ma) dioritic rocks in the Bizha area in southern Qiangtang, Tibet. The dioritic rocks are characterized by large ion lithophile elements, Pb, and light rare earth elements but depletion of high field strength elements with slightly enriched and variable ɛNd(t) values of -0.01 to -3.31 and initial 87Sr/86Sr isotopic ratios of 0.7053-0.7062. They also have variable magmatic zircon Hf-O isotope compositions (ɛHf(t) = -5.3 to +3.6 and δ18O = +7.3 to +9.5 ‰). Combined with contemporary andesitic lavas in southern Qiangtang, we suggest that the intermediate magmatic rocks in this area were most probably derived by partial melting of a subduction mélange, which is a mixture of mid-oceanic ridge basalts (MORBs), sediments, and mantle wedge peridotites, formed along the interface between the subducted slab and the overlying mantle wedge in a subduction channel before ˜124 Ma. The mélange diapir melting was triggered by the asthenospheric upwelling and hot corner flow caused by roll-back of the northward subducted Bangong-Nujiang oceanic slab during the Early Cretaceous. The Early Cretaceous intermediate magmatic rocks in southern Qiangtang have an overall continental crust-like andesitic composition. Therefore, partial melting of mélange provides an important support for the generation of andesitic magmas in continental arcs and the "andesite model" for crustal growth.

  3. ANALYTICAL ASSESSMENT OF THE IMPACTS OF PARTIAL MASS DEPLETION IN DNAPL SOURCE ZONES (SAN FRANCISCO, CA)

    EPA Science Inventory

    Analytical solutions describing the time-dependent DNAPL source-zone mass and contaminant discharge rate are used as a flux-boundary condition in a semi-analytical contaminant transport model. These analytical solutions assume a power relationship between the flow-averaged sourc...

  4. Partial Root-Zone Drying of Olive (Olea europaea var. 'Chetoui') Induces Reduced Yield under Field Conditions.

    PubMed

    Dbara, Soumaya; Haworth, Matthew; Emiliani, Giovani; Ben Mimoun, Mehdi; Gómez-Cadenas, Aurelio; Centritto, Mauro

    2016-01-01

    The productivity of olive trees in arid and semi-arid environments is closely linked to irrigation. It is necessary to improve the efficiency of irrigation techniques to optimise the amount of olive fruit produced in relation to the volume of water used. Partial root-zone drying (PRD) is a water saving irrigation technique that theoretically allows the production of a root-to-shoot signal that modifies the physiology of the above-ground parts of the plant; specifically reducing stomatal conductance (gs) and improving water use efficiency (WUE). Partial root-zone drying has been successfully applied under field conditions to woody and non-woody crops; yet the few previous trials with olive trees have produced contrasting results. Thirty year-old olive trees (Olea europaea 'var. Chetoui') in a Tunisian grove were exposed to four treatments from May to October for three-years: 'control' plants received 100% of the potential evapotranspirative demand (ETc) applied to the whole root-zone; 'PRD100' were supplied with an identical volume of water to the control plants alternated between halves of the root-zone every ten-days; 'PRD50' were given 50% of ETc to half of the root-system, and; 'rain-fed' plants received no supplementary irrigation. Allowing part of the root-zone to dry resulted in reduced vegetative growth and lower yield: PRD100 decreased yield by ~47% during productive years. During the less productive years of the alternate bearing cycle, irrigation had no effect on yield; this suggests that withholding of water during 'off-years' may enhance the effectiveness of irrigation over a two-year cycle. The amount and quality of oil within the olive fruit was unaffected by the irrigation treatment. Photosynthesis declined in the PRD50 and rain-fed trees due to greater diffusive limitations and reduced biochemical uptake of CO2. Stomatal conductance and the foliar concentration of abscisic acid (ABA) were not altered by PRD100 irrigation, which may indicate the

  5. Partial Root-Zone Drying of Olive (Olea europaea var. 'Chetoui') Induces Reduced Yield under Field Conditions.

    PubMed

    Dbara, Soumaya; Haworth, Matthew; Emiliani, Giovani; Ben Mimoun, Mehdi; Gómez-Cadenas, Aurelio; Centritto, Mauro

    2016-01-01

    The productivity of olive trees in arid and semi-arid environments is closely linked to irrigation. It is necessary to improve the efficiency of irrigation techniques to optimise the amount of olive fruit produced in relation to the volume of water used. Partial root-zone drying (PRD) is a water saving irrigation technique that theoretically allows the production of a root-to-shoot signal that modifies the physiology of the above-ground parts of the plant; specifically reducing stomatal conductance (gs) and improving water use efficiency (WUE). Partial root-zone drying has been successfully applied under field conditions to woody and non-woody crops; yet the few previous trials with olive trees have produced contrasting results. Thirty year-old olive trees (Olea europaea 'var. Chetoui') in a Tunisian grove were exposed to four treatments from May to October for three-years: 'control' plants received 100% of the potential evapotranspirative demand (ETc) applied to the whole root-zone; 'PRD100' were supplied with an identical volume of water to the control plants alternated between halves of the root-zone every ten-days; 'PRD50' were given 50% of ETc to half of the root-system, and; 'rain-fed' plants received no supplementary irrigation. Allowing part of the root-zone to dry resulted in reduced vegetative growth and lower yield: PRD100 decreased yield by ~47% during productive years. During the less productive years of the alternate bearing cycle, irrigation had no effect on yield; this suggests that withholding of water during 'off-years' may enhance the effectiveness of irrigation over a two-year cycle. The amount and quality of oil within the olive fruit was unaffected by the irrigation treatment. Photosynthesis declined in the PRD50 and rain-fed trees due to greater diffusive limitations and reduced biochemical uptake of CO2. Stomatal conductance and the foliar concentration of abscisic acid (ABA) were not altered by PRD100 irrigation, which may indicate the

  6. Trace element compositions of apatite from the middle zone of the Panzhihua layered intrusion, SW China: Insights into the differentiation of a P- and Si-rich melt

    NASA Astrophysics Data System (ADS)

    Xing, Chang-Ming; Wang, Christina Yan; Li, Congying

    2014-09-01

    The Panzhihua layered intrusion in the ~ 260 Ma Emeishan large igneous province is composed of melagabbro and Fe-Ti oxide ore bodies in the lower zone (LZ) and the lower part of the middle zone (MZa), and Fe-Ti oxide-poor leucogabbro in the upper part of the middle zone (MZb) and upper zone (UZ). Cumulus apatite grains occur in the ~ 500- to 600-m-thick MZb, which makes up 25-30% of the ~ 2-km-thick intrusion. Apatite grains from the MZb show two compositional reversals in the composition of Sr, which divide the MZb into three sub-units from the base upwards, MZb1, MZb2 and MZb3. There is 1-3 vol.% apatite in the MZb1 and MZb2 and 2-5 vol.% apatite in the MZb3. Both apatite and plagioclase have an overall trend of decreasing Sr in each sub-unit. Most apatite grains from the MZb1 and MZb2 have negative Eu anomalies (Eu/Eu* = 0.70-0.98) on chondrite-normalized REE plots and some at the top of the MZb2 have positive Eu anomalies (Eu/Eu* = 1.09-1.18), whereas all grains from the MZb3 have positive Eu anomalies (Eu/Eu* = 1.11-1.25). We consider that the Panzhihua intrusion formed due to immiscibility of ferrobasaltic magmas in a large convection cell at high temperatures. The immiscible Fe-rich melt tended to move towards the base of the chamber, whereas the Si-rich melt moved upwards due to density differences. Crystallization of Fe-Ti oxides from the Fe-rich melt at high temperatures may result in the enrichment of P in the residual magmas. The upward moving residual P-rich magmas may have mixed with Si-rich melt to form a P- and Si-rich melt in the upper part of the chamber, from which the MZb formed. Double-diffusive convection circulated in the P- and Si-rich melt to form stratified magma layers. Magma mixing between the stratified magma layers resulted in the compositional reversals of apatite along the boundaries. Negative Eu anomaly of apatite in the MZb1 and MZb2 is attributed to prior crystallization of plagioclase, whereas replenishment of a syenitic magma to

  7. Partial melting and rapid exhumation of a Pliocene UHP terrane: CA-TIMS zircon results from Normanby Island, Papau New Guinea

    NASA Astrophysics Data System (ADS)

    DesOrmeau, J. W.; Gordon, S. M.; Little, T. A.; Bowring, S. A.

    2012-12-01

    Some ultra-high pressure (UHP) terranes contain eclogite embedded within migmatitic gneisses that preserve evidence for multiple episodes of partial melting. Understanding the mechanisms by which crustal rocks are subducted to mantle depths and subsequently exhumed requires understanding the timing of metamorphism and the timing and role of partial melting. The D'Entrecasteaux Islands of southeastern Papua New Guinea (PNG) expose Pliocene UHP eclogites contained within migmatitic host gneisses. Garnet-whole rock Lu-Hf geochronology suggests UHP metamorphism may have begun by ca. 7 Ma, and Ar-Ar thermochronology indicates that the rocks were exhumed to the surface by ca. 2 Ma; the history between 7 and 2 Ma is crucial for tectonic models of PNG. We have applied U-Pb chemical-abrasion thermal-ionization mass spectrometry (CA-TIMS) geochronology to zircons separated from granitoid intrusions within the host gneisses to better understand the timing and role of melting in the exhumation of the PNG UHP rocks. Three granodiorite intrusions were collected from Normanby Island as it has received far less study in previous investigations than the other D'Entrecasteaux Islands (Goodenough and Fergusson) and exposes the contact of the UHP-HP rocks against the structurally overlying, weakly metamorphosed rocks of the Papuan ultramafic belt (PUB). From the west side of Normanby dome in contact with the PUB, zircons from a foliated protomylonitic granodiorite sill yielded 206Pb/238U dates of ca. 4.1 Ma. In comparison, on the eastern side of Normanby dome, zircons from a weakly foliated, discordant pegmatitic dike yielded a complex array of zircon analyses and the youngest dates are ca. 4.1 Ma. The zircons extracted from these deformed intrusions are interpreted to date melt emplacement, crystallization, and zircon growth, which may be coeval with amphibolite facies (570-730 °C and ~7-12 Kbar) metamorphism recorded from Goodenough and Fergusson Islands. Zircons from a non

  8. Melting Phase Relation of Nominally Anhydrous, Carbonated Pelite at Sub-arc Depths and Cycling of Sedimentary Carbon in Subduction Zones

    NASA Astrophysics Data System (ADS)

    Tsuno, K.; Dasgupta, R.

    2009-12-01

    An important mass transfer process for subduction zone magmatism is the cycling of C-O-H volatiles from subducting slab to arc volcanoes. However, CO2 is known to remain stable in subducting lithologies in the form crystalline carbonates. Mass balance of chemical tracers between slab input and arc output1 and stable isotopic compositions of arc fluids2, on the other hand, suggest that subducting sediments contribute to arc volcanism and arc-flux of CO2 derives primarily from subducting sediments. Therefore, it is important to explore the possible link between sediment contributions to arc volcanism and CO2 release from subducting sediments to mantle wedge. We have investigated, using an end-loaded piston cylinder device, melting relation of a carbonate-bearing, nominally anhydrous pelagic sediment composition at a single pressure of 3 GPa and at temperatures of 900-1350 °C. The starting material (HPLC1) has ~5 wt.% CO2 and corresponds (in H2O-free basis) to a mixture of 10 wt.% pelagic carbonate unit and 90 wt.% overlying hemipelagic mud unit that enter the Central American trench3. The subsolidus assemblage at 900 °C consists of garnet+cpx+K-feldspar+coesite+rutile+ankeritess, whereas just above the solidus (900-1000 °C), carbonatitic melt appears and ankeritess disappears (1000-1100 °C). The appearance of CO2-bearing silicate melt at 1100 °C coincides with the disappearance of K-feldspar and rutile, and the melt coexists with garnet+cpx+coesite/quartz from 1100 to 1300 °C. The liquidus is located >1350 °C, and the sole liquidus phase is quartz. Silicate melt composition evolves systematically from 1100 to 1350 °C with a decrease in SiO2 (65.7 to 59.1 wt.%), Al2O3 (13.5 to 12.4 wt.%), K2O (~5.5 to 2.1 wt.%), and CO2 (~8.5 to 5.2 wt.%), whereas MgO, FeO*, and CaO contents of the melt increase from 0.4 to 2.6 wt.%, 1.5 to 6.7 wt.%, and 2.4 to 8.7 wt.%, respectively. The Na2O content increases from 2.3 to 3.6 wt.% between 1100 and 1200 °C and decreases to 2

  9. The density, compressibility and seismic velocity of hydrous melts at crustal and upper mantle conditions

    NASA Astrophysics Data System (ADS)

    Ueki, K.; Iwamori, H.

    2015-12-01

    Various processes of subduction zone magmatism, such as upward migration of partial melts and fractional crystallization depend on the density of the hydrous silicate melt. The density and the compressibility of the hydrous melt are key factors for the thermodynamic calculation of phase relation of the hydrous melt, and the geophysical inversion to predict physicochemical conditions of the melting region based on the seismic velocity. This study presents a new model for the calculations of the density of the hydrous silicate melts as a function of T, P, H2O content and melt composition. The Birch-Murnaghan equation is used for the equation of state. We compile the experimentally determined densities of various hydrous melts, and optimize the partial molar volume, compressibility, thermal expansibility and its pressure derivative, and K' of the H2O component in the silicate melt. P-T ranges of the calibration database are 0.48-4.29 GPa and 1033-2073 K. As such, this model covers the P-T ranges of the entire melting region of the subduction zone. Parameter set provided by Lange and Carmichael [1990] is used for the partial molar volume and KT value of the anhydrous silicate melt. K' of anhydrous melt is newly parameterized as a function of SiO2 content. The new model accurately reproduces the experimentally determined density variations of various hydrous melts from basalt to rhyolite. Our result shows that the hydrous melt is more compressive and less dense than the anhydrous melt; with the 5 wt% of H2O in melt, density and KT decrease by ~10% and ~30% from those of the anhydrous melt, respectively. For the application of the model, we calculated the P-wave velocity of the hydrous melt. With the 5 wt% of H2O, P-wave velocity of the silicate melt decreases by >10%. Based on the melt P-wave velocity, we demonstrate the effect of the melt H2O content on the seismic velocity of the partially molten zone of the subduction zone.

  10. Multi-zone modelling of partially premixed low-temperature combustion in pilot-ignited natural-gas engines

    SciTech Connect

    Krishnan, S. R.; inivasan, K. K.

    2010-09-14

    Detailed results from a multi-zone phenomenological simulation of partially premixed advanced-injection low-pilot-ignited natural-gas low-temperature combustion are presented with a focus on early injection timings (the beginning of (pilot) injection (BOI)) and very small diesel quantities (2-3 per cent of total fuel energy). Combining several aspects of diesel and spark ignition engine combustion models, the closed-cycle simulation accounted for diesel autoignition, diesel spray combustion, and natural-gas combustion by premixed turbulent flame propagation. The cylinder contents were divided into an unburned zone, several pilot fuel zones (or 'packets') that modelled diesel evaporation and ignition, a flame zone for natural-gas combustion, and a burned zone. The simulation predicted the onset of ignition, cylinder pressures, and heat release rate profiles satisfactorily over a wide range of BOIs (20-60° before top dead centre (before TDC)) but especially well at early BOIs. Strong coupling was observed between pilot spray combustion in the packets and premixed turbulent combustion in the flame zone and, therefore, the number of ignition centres (packets) profoundly affected flame combustion. The highest local peak temperatures (greater than 2000 K) were observed in the packets, while the flame zone was much cooler (about 1650 K), indicating that pilot diesel spray combustion is probably the dominant source of engine-out emissions of nitrogen oxide (NOx). Further, the 60° before TDC BOI yielded the lowest average peak packet temperatures (about 1720 K) compared with the 20° before TDC BOI (about 2480 K) and 40° before TDC BOI (about 2700 K). These trends support experimental NOx trends, which showed the lowest NOx emissions for the 60°, 20°, and 40° before TDC BOIs in that order. Parametric studies showed that increasing the intake charge temperature, pilot quantity, and natural-gas equivalence ratio all led to higher peak

  11. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPA and temperatures to partial melting

    SciTech Connect

    Bauer, S.J.; Friedman, M.; Handin, J.

    1981-01-01

    The short-term failure strengths and strains at failure of room-dry and water-saturated, cylindrical specimens (2 by 4 cm) of Charcoal Granodiorite (CG), Mt. Hood Andesite (MHA), and Cuerbio Basalt (CB) at a strain rate of 10/sup -4/s/sup -1/, at effective confining pressures of 0, 50, and 100 MPa and at temperatures to partial melting were investigated. Data from water-saturated specimens of the granodiorite and andesite, compared to room-dry counterparts, indicate (1) the pore pressures are essentially communicated throughout each test specimen so that they are fully effective; (2) at P/sub e/ = 0 and 50 MPa the granodiorite does not water-weaken; (3) at these same effective pressures the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (4) at P/sub e/ = 0 and 870 to 900/sup 0/C the andesite's strength averages 20 MPa while the strength of dry specimens at the same P and T exhibit a strength of 100 MPa; (5) at P/sub e/ = 50 MPa compared to 160 MPa dry; (6) the basalt at P/sub e/ = 0, appears to be water-weakened at 800/sup 0/C; (7) water saturated specimens deformed at temperatures less than that of melting exhibit ultimate strengths at less than 2% shortening and then work-soften along faults; (8) again as do the dry counterparts, the wet specimens deform primarily by microscopic fracturing that coalesces into one or more macroscopic faults; and (9) the temperature for incipient melting of the andesite is decreased >150/sup 0/C in the water-saturated tests.

  12. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPa and temperatures to partial melting

    SciTech Connect

    Bauer, S.J.; Friedman, M.; Handin, J.

    1981-01-01

    Instantaneous-failure strengths and ductilities of water-saturated cylindrical specimens of Charcoal Granodiorite, Mount Hood Andesite, and Cuerbio Basalt are determined at a strain rate of 10{sup -4}s{sup -1} and at effective confining pressures (Pe) of 0 and 50 MPa and at temperatures to partial melting. The data indicate: (1) at Pe = 0 and 50 MPa (Pc and Pp of 50 MPa and of 100 and 50 MPa, respectively) the granodiorite does not water-weaken; (2) at these same Pe the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (3) at Pe = 0 and 870-900{sup 0}C the andesite's wet strength averages 20 MPa compared to 100 MPa, dry; (4) at Pe = 50 MPa and 920{sup 0}C its wet strength is 45 MPa compared to 160 MPa dry; (5) at Pe = 0, the basalt appears to be water-weakened above 800{sup 0}C; (6) water-saturated specimens deformed at temperatures less than T{sub m} exhibit ultimate strengths at less than 2 percent shortening and then work-soften along faults; and (7) both dry and wet specimens deform primarily by brittle fracture. Extrapolations indicate: (1) crystalline rocks should be drillable because they remain brittle until partial melting occurs, and penetration rates should increase with temperature because there is a corresponding decrease in brittle fracture strength; (2) boreholes in ''water-filled'' holes will be stable to >10 km at temperatures 10 km; and (4) open boreholes in the andesite are apt to be much less stable, and at similar temperatures would fail at 2 to 5-km depth.

  13. Thermal Conductive Heat Transfer and Partial Melting of Volatiles in Icy Moons, Asteroids, and Kuiper Belt Objects (Invited)

    NASA Astrophysics Data System (ADS)

    Kargel, J. S.; Furfaro, R.

    2013-12-01

    Thermal gradients within conductive layers of icy satellite and asteroids depend partly on heat flow, which is related to the secular decay of radioactive isotopes, to heat released by chemical phase changes, by conversion of gravitational potential energy to heat during differentiation, tidal energy dissipation, and to release of heat stored from prior periods. Thermal gradients are also dependent on the thermal conductivity of materials, which in turn depends on their composition, crystallinity, porosity, crystal fabric anisotropy, and details of their mixture with other materials. Small impurities can produce lattice defects and changes in polymerization, and thereby have a huge influence on thermal conductivity, as can cage-inclusion (clathrate) compounds. Heat flow and thermal gradients can be affected by fluid phase advection of mass and heat (in oceans or sublimating upper crusts), by refraction related to heterogeneities of thermal conductivity due to lateral variations and composition or porosity. Thermal profiles depend also on the surface temperature controlled by albedo and climate, surface relief, and latitude, orbital obliquity and surface insolation, solid state greenhouses, and endogenic heating of the surface. The thermal state of icy moon interiors and thermal gradients can be limited at depth by fluid phase advection of heat (e.g., percolating meteoric methane or gas emission), by the latent heat of phase transitions (melting, solid-state transitions, and sublimation), by solid-state convective or diapiric heat transfer, and by foundering. Rapid burial of thick volatile deposits can also affect thermal gradients. For geologically inactive or simple icy objects, most of these controls on heat flow and thermal gradients are irrelevant, but for many other icy objects they can be important, in some cases causing large lateral and depth variations in thermal gradients, large variations in heat flow, and dynamically evolving thermal states. Many of

  14. [Effects of alternate partial root-zone subsurface drip irrigation on potato yield and water use efficiency].

    PubMed

    Huang, Zhong-Dong; Qi, Xue-Bin; Fan, Xiang-Yang; Hu, Chao; Zhu, Dong-Hai; Li, Ping; Qiao, Dong-Mei

    2010-01-01

    Field experiment was conducted to investigate the effects of alternate partial root-zone subsurface drip irrigation (APRSDI) on the physiological responses, yield, and water use efficiency of potato. Compared with conventional drip irrigation (CDI), APRSDI had less negative effects on the potato leaf photosynthesis rate (P(n)), but decreased the transpiration rate and stomatal conductance significantly. The slightly higher P(n) under CDI was at the expense of consuming more water. No significant difference was observed in the potato yield under APRSDI and CDI, but APRSDI saved the irrigation amount by 25.8% and increased the irrigation water use efficiency and total water use efficiency by 27.5% and 15.3%, respectively, suggesting that APRSDI would be a feasible water-saving irrigation technique for the planting of potato.

  15. Alteration of chaotic advection in blood flow around partial blockage zone: Role of hematocrit concentration

    NASA Astrophysics Data System (ADS)

    Maiti, Soumyabrata; Chaudhury, Kaustav; DasGupta, Debabrata; Chakraborty, Suman

    2013-01-01

    Spatial distributions of particles carried by blood exhibit complex filamentary pattern under the combined effects of geometrical irregularities of the blood vessels and pulsating pumping by the heart. This signifies the existence of so called chaotic advection. In the present article, we argue that the understanding of such pathologically triggered chaotic advection is incomplete without giving due consideration to a major constituent of blood: abundant presence of red blood cells quantified by the hematocrit (HCT) concentration. We show that the hematocrit concentration in blood cells can alter the filamentary structures of the spatial distribution of advected particles in an intriguing manner. Our results reveal that there primarily are two major impacts of HCT concentrations towards dictating the chaotic dynamics of blood flow: changing the zone of influence of chaotic mixing and determining the enhancement of residence time of the advected particles away from the wall. This, in turn, may alter the extent of activation of platelets or other reactive biological entities, bearing immense consequence towards dictating the biophysical mechanisms behind possible life-threatening diseases originating in the circulatory system.

  16. Partial Root-Zone Drying of Olive (Olea europaea var. 'Chetoui') Induces Reduced Yield under Field Conditions

    PubMed Central

    Dbara, Soumaya; Haworth, Matthew; Emiliani, Giovani; Ben Mimoun, Mehdi; Gómez-Cadenas, Aurelio; Centritto, Mauro

    2016-01-01

    The productivity of olive trees in arid and semi-arid environments is closely linked to irrigation. It is necessary to improve the efficiency of irrigation techniques to optimise the amount of olive fruit produced in relation to the volume of water used. Partial root-zone drying (PRD) is a water saving irrigation technique that theoretically allows the production of a root-to-shoot signal that modifies the physiology of the above-ground parts of the plant; specifically reducing stomatal conductance (gs) and improving water use efficiency (WUE). Partial root-zone drying has been successfully applied under field conditions to woody and non-woody crops; yet the few previous trials with olive trees have produced contrasting results. Thirty year-old olive trees (Olea europaea ‘var. Chetoui’) in a Tunisian grove were exposed to four treatments from May to October for three-years: ‘control’ plants received 100% of the potential evapotranspirative demand (ETc) applied to the whole root-zone; ‘PRD100’ were supplied with an identical volume of water to the control plants alternated between halves of the root-zone every ten-days; ‘PRD50’ were given 50% of ETc to half of the root-system, and; ‘rain-fed’ plants received no supplementary irrigation. Allowing part of the root-zone to dry resulted in reduced vegetative growth and lower yield: PRD100 decreased yield by ~47% during productive years. During the less productive years of the alternate bearing cycle, irrigation had no effect on yield; this suggests that withholding of water during ‘off-years’ may enhance the effectiveness of irrigation over a two-year cycle. The amount and quality of oil within the olive fruit was unaffected by the irrigation treatment. Photosynthesis declined in the PRD50 and rain-fed trees due to greater diffusive limitations and reduced biochemical uptake of CO2. Stomatal conductance and the foliar concentration of abscisic acid (ABA) were not altered by PRD100 irrigation

  17. Direct Observations of Rapid Basal Melting and Bed Topography in the Grounding Zones of the Dotson and Crosson Ice Shelves, West Antarctica

    NASA Astrophysics Data System (ADS)

    Khazendar, A.; Rignot, E. J.; Schroeder, D. M.; Seroussi, H. L.; Schodlok, M.; Scheuchl, B.; Sutterley, T. C.; Velicogna, I.

    2015-12-01

    Glaciological changes of the Dotson and Crosson ice shelves and their tributary glaciers of Smith, Pope and Kohler are among the most noticeable in the Amundsen Sea Embayment region of West Antarctica. Here, we present sounding radar and laser altimetry observations of two aspects that are indispensable for understanding those changes: basal melting and bedrock topography in the grounding zones. We find that Smith Glacier in particular thinned by a remarkably fast 300-490 m between the years 2002 and 2009. Its grounding line has retreated far enough to be now at 2000 m below sea level in a previously identified trench. All three glacier grounding lines have already retreated down steeper parts of their bedrocks to flatter terrains, plausibly contributing to the reported slowing down in the acceleration of their ice volume discharges. The wider implications of the work emphasize the unprecedented perspectives that direct observation can offer of diverse grounding zone structures and evolution scenarios.

  18. Constraints on the dynamics of melt migration, flow and emplacement across the continental crust

    NASA Astrophysics Data System (ADS)

    Cavalcante, Carolina; Viegas, Gustavo

    2015-04-01

    The presence of partial melting during deformation produces a drastic change in the rheological behavior of the continental crust. The rock strength decreases with melt fractions as low as ~0.7 %. At pressure/temperature conditions typical of the middle crust, melt-bearing systems may play a critical role in the processes of strain localization and in the overall strength of the continental lithosphere. In eastern Brazil, Neoproterozoic tectonics are often associated with wide partial melting and shear zone development, that promote the exhumation of mid- to lower crustal layers where compositionally heterogeneous anatexites with variable melt fractions and leucosome structures are exposed. The leucosomes usually form interconnected networks of magma that reflect the high melt content present during deformation. In this contribution we address two case studies encompassing the dynamics of melt flow at magma chambers, represented by the Carlos Chagas anatexite, and the mechanisms of melt migration and channeling through shear zones, in which the Patos shear zone serves as an analogue. Through detailed petrostructural studies of anatexites exposed at these settings, we aim to demonstrate the way melt deforms and localizes strain, the different patterns of melt flow pathways across the crust, and the implications for the mechanical behaviour of the Earth's lithosphere during orogenic deformation.

  19. Quantifying melting and mobilistaion of interstitial melts in crystal mushes

    NASA Astrophysics Data System (ADS)

    Veksler, Ilya; Dobson, Katherine; Hess, Kai-Uwe; Ertel-Ingrisch, Werner; Humphreys, Madeleine

    2015-04-01

    The deformation of crystals mushes and separation of melts and crystals in is critical to understanding the development of physical and chemical heterogeneity in magma chambers and has been invoked as an eruption trigger mechanism. Here we investigate the behaviour of the melt in the well characterised, classic crystal mush system of the Skaergaard intrusion by combining experimental petrology and the non-destructive 3D imaging methods. Starting materials for partial melting experiments were four samples from the upper Middle Zone of the Layered Series. Cylinders, 15 mm in diameter and 20 mm in length, were drilled out of the rock samples, placed in alumina crucibles and held for 5 days in electric furnaces at atmospheric pressure and 1050-1100 °C. Redox conditions set by the CO-CO2 gas mixture were kept close to those of the FMQ buffer. We then use spatially registered 3D x-ray computed tomography images, collected before and after the experiment, to determine the volume and distribution of the crystal framework and interstitial phases, and the volume, distribution and connectivity the interstitial phases that undergo melting and extraction while at elevated temperature. Image analysis has allowed us to quantify these physical changes with high spatial resolution. Our work is a first step towards quantitative understanding of the melt mobilisation and migration processes operating in notionally locked crystal rich magmatic systems.

  20. San Andreas Fault dip, Peninsular Ranges mafic lower crust and partial melt in the Salton Trough, Southern California, from ambient-noise tomography

    NASA Astrophysics Data System (ADS)

    Barak, Shahar; Klemperer, Simon L.; Lawrence, Jesse F.

    2015-11-01

    We use ambient-noise tomography to improve CVM-H11.9, a community velocity model of southern California. Our new 3-D shear-velocity model with 0.05° x 0.05° lateral and 1 km vertical blocks reveals new structure beneath the San Andreas Fault (SAF), Peninsular Ranges batholith (PRB), southern Sierra Nevada batholith (SNB), and the Salton Trough (ST). We use 4 years of data recorded on 849 broadband stations, vastly more than previous studies and including our own broadband Salton Seismic Imaging Project, a 40 station transect across the ST, as well as other campaign stations in both Mexico and the United States. Mean lower crust and upper mantle wave speeds (3.6 km/s at 20 km, 4.2 km/s at 40 km) are low by global standards. Across the SAF, southeast of San Gorgonio Pass, we observe vertical to steeply dipping lateral velocity contrasts that extend beneath the Moho. Beneath the western PRB and westernmost southern SNB, we observe relatively high shear velocities (≥3.8 km/s) in the lower crust that we interpret as the mafic roots of the overlying arc. Relatively high-velocity upper mantle (up to ˜4.5 km/s) may be part of the intact arc, or possibly a remnant of the Farallon plate. Beneath the ST, we observe zones of low shear-velocity in the lower crust and upper mantle which permit up to ˜4.5% melt in the lower crust and up to ˜6% melt in the upper mantle, depending on the assumed composition and pore geometry. Our results preclude the existence of older continental crust beneath the ST and support the creation of new crust beneath the ST.

  1. Alpine-type sensu strictu(ophiolitic) peridotites: Refractory residues from partial melting or igneous sediments? A contribution to the discussion of the paper: "The origin of ultramafic and ultrabasic rocks" by P.J. Wyllie

    USGS Publications Warehouse

    Thayer, T.P.

    1969-01-01

    Although Alpine peridotites and basaltic lavas are widely associated in eugeosynclines and oceanic areas, their genetic ties are obscure. Three major characteristics of olivine-rich Alpine peridotite and dunite-relict cumulus textures, aggregated masses of chromitite, and intimate association with magnesium-rich gabbro - cannot be explained by partial melting of garnet peridotite to form tholeiite. Association of magnesium-rich gabbro with the chromite-bearing and so-called high-temperature Alpine peridotites is believed to present problems that have not been considered by advocates of the partial-melting hypothesis. The chromite-bearing Alpine peridotites and related feldspathic rocks are believed to have formed near the top of the mantle by gravitational differentiation processes which are largely independent of the melting processes that produce basaltic magma at depths of 50 km or more. ?? 1969.

  2. Early Cretaceous low-Mg# adakitic rocks in the southern margin of the central North China Craton: Partial melting of thickened lower continental crust and tectonic implications

    NASA Astrophysics Data System (ADS)

    Yang, D.

    2015-12-01

    This paper reports new whole-rock geochemical, Sr-Nd-Pb isotopic, and zircon U-Pb and Hf isotopic data for Early Cretaceous intrusive rocks in the Sanmenxia-Houma area of central China, and uses these data to constrain the petrogenesis of low-Mg adakitic rocks (LMAR) and the spatial extent of the influence of the deeply subducted Yangtze slab during the Triassic evolution of this region. New zircon LA-ICP-MS U-Pb data indicate that the early- and late-stage southern Quli, Qiligou, and Gaomiao porphyritic quartz diorites, the Canfang granodiorite, and the northern Wangmao porphyritic quartz monzodiorite were emplaced during the Early Cretaceous (~130 Ma) and the late Early Cretaceous (116 Ma). These rocks are characterized by high Na2O/K2O, Sr/Y, and (La/Yb)n ratios as well as high Sr concentrations, low Mg# values, and low heavy rare earth element and Y concentrations, all of which indicate an LMAR affinity. The samples have relatively high initial 87Sr/86Sr ratios (0.7054-0.7095), and low eNd(t) (-11.90 to -22.20) and eHf(t) (-16.7 to -32.7) values, indicative of a lower continental crust origin. The presence of Neoproterozoic (754-542 Ma) and inherited Late Triassic (220 Ma) metamorphic zircons within the late Early Cretaceous LMAR and the relatively high 206Pb/204Pb ratios of these rocks suggest that they formed from primary magmas derived from partial melting of Yangtze Craton (YC) basement material that had undergone ultrahigh-pressure metamorphism. In contrast, the presence of Paleoproterozoic and Archean inherited zircons within early Early Cretaceous LMAR in this area and the relatively low 206Pb/204Pb ratios of these rocks are indicative of derivation from primary magmas generated by partial melting of the thickened lower continental crust of the North China Craton (NCC). These rocks may have formed in an extensional environment associated with the upwelling of asthenospheric mantle material. The presence of YC basement material within the NCC in the

  3. Partial melting a key agent in exhumation of the world's youngest eclogite-facies (and UHP) rocks in the D'Entrecasteaux Islands, Papua New Guinea

    NASA Astrophysics Data System (ADS)

    Little, T. A.; Hacker, B. R.; Gordon, S. M.; Baldwin, S.; Fitzgerald, P. G.

    2010-12-01

    The D'Entrecasteaux Islands of SE Papua New Guinea host the world's youngest (2-8 Ma) eclogite-facies rocks and represent the only place where (U)HP rocks are actively exhuming. Structural, geochronological,and thermobarometric data indicate that the strongly deformed (U)HP terrane was exhumed within the Woodlark Rift at mean rates of >2 cm/yr. Exhumation was accompanied by partial melting of the gneissic terrane. During the Eocene Papuan arc-continent collision a large (>25 km-thick, based on simple thermal calculations) nappe of Australian Plate-derived continental rocks was most likely subducted to (U)HP depths. There the crustal material remained lodged metastably for up to 30 m.y. until the Late Miocene-Pliocene when the onset of asthenospheric circulation ahead of the west-propagating Woodlark spreading ridge introduced heat and fluids into the nappe. These processes caused the crustal material to weaken and break away within the paleo-subduction channel, to recrystallize in the eclogite-facies, and to rise as one or more Rayleigh-Taylor instabilities. As these diapirs ascended isothermally, they underwent partial melting and were intruded by abundant syntectonic granodiorites, lowering their viscosity and increasing buoyancy. The migmatitic (U)HP body ponded near the Moho at ~3-5 Ma, where it acquired a flat-lying LS tectonite fabric and was subject to pervasive amphibolite-facies retrogression. Quartz LPO's associated with the tectonite fabric were measured using EBSD and commonly record activity of the high temperature prism-[c] slip system. However, the fabrics are extremely weak (J fabric strength parameter generally less than 2), a result which we attribute to deformation in the presence of a connected intergranular melt phase. This gravitationally unstable welt of weak continental crustal material was extended parallel (E-W) to the rift margin, thinning ductilely by <1/3. This lower crustal flow, dominated by pure shear (Wk <0.4), was mechanically

  4. Technical Note: Approximate solution of transient drawdown for constant-flux pumping at a partially penetrating well in a radial two-zone confined aquifer

    NASA Astrophysics Data System (ADS)

    Huang, C.-S.; Yang, S.-Y.; Yeh, H.-D.

    2015-06-01

    An aquifer consisting of a skin zone and a formation zone is considered as a two-zone aquifer. Existing solutions for the problem of constant-flux pumping in a two-zone confined aquifer involve laborious calculation. This study develops a new approximate solution for the problem based on a mathematical model describing steady-state radial and vertical flows in a two-zone aquifer. Hydraulic parameters in these two zones can be different but are assumed homogeneous in each zone. A partially penetrating well may be treated as the Neumann condition with a known flux along the screened part and zero flux along the unscreened part. The aquifer domain is finite with an outer circle boundary treated as the Dirichlet condition. The steady-state drawdown solution of the model is derived by the finite Fourier cosine transform. Then, an approximate transient solution is developed by replacing the radius of the aquifer domain in the steady-state solution with an analytical expression for a dimensionless time-dependent radius of influence. The approximate solution is capable of predicting good temporal drawdown distributions over the whole pumping period except at the early stage. A quantitative criterion for the validity of neglecting the vertical flow due to a partially penetrating well is also provided. Conventional models considering radial flow without the vertical component for the constant-flux pumping have good accuracy if satisfying the criterion.

  5. Petrogenesis of magmatic albite granites associated to cogenetic A-type granites: Na-rich residual melt extraction from a partially crystallized A-type granite mush

    NASA Astrophysics Data System (ADS)

    Barboni, Mélanie; Bussy, François

    2013-09-01

    from the pure melting of an immature biotite-bearing quartz-feldspathic crustal protolith induced by early mafic injections at low crustal levels. Strong field evidences coupled to mineral chemistry and elemental geochemistry strongly support a magmatic origin for the albite granite. Sr, Nd, Hf zircon isotope data, U-Pb zircon ages, as well as data on petrography, mineral chemistry and elemental geochemistry attest that A-type and albite granites are closely related. Our preferred petrogenetic model is to consider the albite granite magma as a compositionally extreme melt that was extracted from a partially crystallized A-type granite mush at a late stage of crystallization. Alternatively, albite granites could form by melting of plagioclase-rich layers formed during A-type granite differentiation.

  6. 49 CFR 222.41 - How does this rule affect Pre-Rule Quiet Zones and Pre-Rule Partial Quiet Zones?

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.41 How does this rule affect Pre-Rule Quiet Zones and Pre-Rule... public highway-rail grade crossing within the quiet zone one or more SSMs identified in appendix A...

  7. 49 CFR 222.41 - How does this rule affect Pre-Rule Quiet Zones and Pre-Rule Partial Quiet Zones?

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.41 How does this rule affect Pre-Rule Quiet Zones and Pre-Rule... public highway-rail grade crossing within the quiet zone one or more SSMs identified in appendix A...

  8. 49 CFR 222.41 - How does this rule affect Pre-Rule Quiet Zones and Pre-Rule Partial Quiet Zones?

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.41 How does this rule affect Pre-Rule Quiet Zones and Pre-Rule... public highway-rail grade crossing within the quiet zone one or more SSMs identified in appendix A...

  9. 49 CFR 222.41 - How does this rule affect Pre-Rule Quiet Zones and Pre-Rule Partial Quiet Zones?

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.41 How does this rule affect Pre-Rule Quiet Zones and Pre-Rule... public highway-rail grade crossing within the quiet zone one or more SSMs identified in appendix A...

  10. 49 CFR 222.41 - How does this rule affect Pre-Rule Quiet Zones and Pre-Rule Partial Quiet Zones?

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... AT PUBLIC HIGHWAY-RAIL GRADE CROSSINGS Exceptions to the Use of the Locomotive Horn Silenced Horns at Groups of Crossings-Quiet Zones § 222.41 How does this rule affect Pre-Rule Quiet Zones and Pre-Rule... public highway-rail grade crossing within the quiet zone one or more SSMs identified in appendix A...

  11. Melting of Transition Metals

    SciTech Connect

    Ross, M; Japel, S; Boehler, R

    2005-04-11

    We review the transition melting studies carried out at Mainz, and describe a recently developed model used to explain that the relatively low melting slopes are due to the partially filled d-bands, and the persistence of the pressure induced s-d transition. The basic tenets of the model have now been reconfirmed by new measurements for Cu and Ni. The measurements show that Cu which has a filled 3d-band, has a melt slope that is about 2.5 greater than its neighbor Ni. In the case of Mo, the apparent discrepancy of DAC melting measurements with shock melting can be explained by accounting for the change in melt slope due to the bcc-cp transition observed in the shock studies. The Fe melt curve is revisited. The possible relevance of the Jahn-Teller effect and recently observed transition metal melts with Icosahedral Short-Range Order (ISRO) is discussed.

  12. Mantle migration of K-LILE-enriched melts/fluids in supra-subduction settings: evidence from the Finero Complex (Ivrea-Verbano Zone, Southern Alps)

    NASA Astrophysics Data System (ADS)

    Zanetti, A.; Mazzucchelli, M.; Giovanardi, T.; Tiepolo, M.; Vannucci, R.

    2011-12-01

    The Finero Complex is located in the northern sector of the Ivrea-Verbano Zone (Southern Alps). It is placed in contact with the Austro-Alpine terrains of the Sesia-Lanzo Zone by the Insubric line and consists of a dunitic-harzburgitic mantle unit, surrounded by a layered mafic-ultramafic intrusion. Unlike the central and southern sectors of the Ivrea-Verbano Zone, recent geochronological data suggest that metasomatic events of the Finero mantle unit, as well as the emplacement of the layered intrusion, occurred over a time span covering Middle Triassic to Lower Jurassic. A number of different geodynamic scenarios, among which aborted rifting processes and/or mantle plume activity, have been proposed to account for Lower Mesozoic melt-related events. However, the trace element and isotopic evidence points to the occurrence of large amount of crustal component in melts migrating through the mantle unit, which, consistently with regional structural features, has been proposed to be related to the development of roll-back subduction(s) during the early Mesozoic. New field, petrochemical and geochronological work has allowed to place further constraints on the geochemical affinity and evolution of the metasomatic melts/fluids affecting the mantle unit. Particular emphasis has been placed on the reconstruction of different migration stages recorded by decameter-wide dunites. In these bodies, an early migration stage produced dm-wide chromitite layers formed by chromite and orthopyroxene (Opx), with subordinate clinopyroxene (Cpx) and accessory amounts of amphibole (Amph), zircon and zirconolite. Successive migration events produced a lithologic series formed by, in order of crystallization: i) straight, cm-large websterites formed by Cpx-Opx-Amph-Phlogopite (Phl); ii) cm- to dm-wide bands with curved strike, characterized by segregation of Cpx-Phl-Amph-Opx; iii) dm-scale pockets filled by pegmatoidal Amph and Phlog; iv) finally, mm-thick veins with random strike and

  13. Earth's interior. Dehydration melting at the top of the lower mantle.

    PubMed

    Schmandt, Brandon; Jacobsen, Steven D; Becker, Thorsten W; Liu, Zhenxian; Dueker, Kenneth G

    2014-06-13

    The high water storage capacity of minerals in Earth's mantle transition zone (410- to 660-kilometer depth) implies the possibility of a deep H2O reservoir, which could cause dehydration melting of vertically flowing mantle. We examined the effects of downwelling from the transition zone into the lower mantle with high-pressure laboratory experiments, numerical modeling, and seismic P-to-S conversions recorded by a dense seismic array in North America. In experiments, the transition of hydrous ringwoodite to perovskite and (Mg,Fe)O produces intergranular melt. Detections of abrupt decreases in seismic velocity where downwelling mantle is inferred are consistent with partial melt below 660 kilometers. These results suggest hydration of a large region of the transition zone and that dehydration melting may act to trap H2O in the transition zone.

  14. Primary carbonatite melt from deeply subducted oceanic crust.

    PubMed

    Walter, M J; Bulanova, G P; Armstrong, L S; Keshav, S; Blundy, J D; Gudfinnsson, G; Lord, O T; Lennie, A R; Clark, S M; Smith, C B; Gobbo, L

    2008-07-31

    Partial melting in the Earth's mantle plays an important part in generating the geochemical and isotopic diversity observed in volcanic rocks at the surface. Identifying the composition of these primary melts in the mantle is crucial for establishing links between mantle geochemical 'reservoirs' and fundamental geodynamic processes. Mineral inclusions in natural diamonds have provided a unique window into such deep mantle processes. Here we provide experimental and geochemical evidence that silicate mineral inclusions in diamonds from Juina, Brazil, crystallized from primary and evolved carbonatite melts in the mantle transition zone and deep upper mantle. The incompatible trace element abundances calculated for a melt coexisting with a calcium-titanium-silicate perovskite inclusion indicate deep melting of carbonated oceanic crust, probably at transition-zone depths. Further to perovskite, calcic-majorite garnet inclusions record crystallization in the deep upper mantle from an evolved melt that closely resembles estimates of primitive carbonatite on the basis of volcanic rocks. Small-degree melts of subducted crust can be viewed as agents of chemical mass-transfer in the upper mantle and transition zone, leaving a chemical imprint of ocean crust that can possibly endure for billions of years. PMID:18668105

  15. Primary carbonatite melt from deeply subducted oceanic crust

    SciTech Connect

    Walter, M.J.; Bulanova, G.P.; Armstrong, L.S.; Keshav, S.; Blundy, J.D.; Gudfinnesson, G.; Lord, O.T.; Lennie, A.R.; Clark, S.M.; Smith, C.B.; Gobbo, L.

    2008-07-01

    Partial melting in the Earth's mantle plays an important part in generating the geochemical and isotopic diversity observed in volcanic rocks at the surface. Identifying the composition of these primary melts in the mantle is crucial for establishing links between mantle geochemical 'reservoirs' and fundamental geodynamic processes. Mineral inclusions in natural diamonds have provided a unique window into such deep mantle processes. Here they provide exper8imental and geochemical evidence that silicate mineral inclusions in diamonds from Juina, Brazil, crystallized from primary and evolved carbonatite melts in the mantle transition zone and deep upper mantle. The incompatible trace element abundances calculated for a melt coexisting with a calcium-titanium-silicate perovskite inclusion indicate deep melting of carbonated oceanic crust, probably at transition-zone depths. Further to perovskite, calcic-majorite garnet inclusions record crystallization in the deep upper mantle from an evolved melt that closely resembles estimates of primitive carbonatite on the basis of volcanic rocks. Small-degree melts of subducted crust can be viewed as agents of chemical mass-transfer in the upper mantle and transition zone, leaving a chemical imprint of ocean crust that can possibly endure for billions of years.

  16. Fluid processes in subduction zones.

    PubMed

    Peacock, S A

    1990-04-20

    Fluids play a critical role in subduction zones and arc magmatism. At shallow levels in subduction zones (<40 kilometers depth), expulsion of large volumes of pore waters and CH(4)-H(2)O fluids produced by diagenetic and low-grade metamorphic reactions affect the thermal and rheological evolution of the accretionary prism and provide nutrients for deep-sea biological communities. At greater depths, H(2)O and CO(2) released by metamorphic reactions in the subducting oceanic crust may alter the bulk composition in the overlying mantle wedge and trigger partial melting reactions. The location and conse-quences of fluid production in subduction zones can be constrained by consideration of phase diagrams for relevant bulk compositions in conjunction with fluid and rock pressure-temperature-time paths predicted by numerical heat-transfer models. Partial melting of subducting, amphibole-bearing oceanic crust is predicted only within several tens of million years of the initiation of subduction in young oceanic lithosphere. In cooler subduction zones, partial melting appears to occur primarily in the overlying mantle wedge as a result of fluid infiltration. PMID:17784486

  17. Fluid processes in subduction zones.

    PubMed

    Peacock, S A

    1990-04-20

    Fluids play a critical role in subduction zones and arc magmatism. At shallow levels in subduction zones (<40 kilometers depth), expulsion of large volumes of pore waters and CH(4)-H(2)O fluids produced by diagenetic and low-grade metamorphic reactions affect the thermal and rheological evolution of the accretionary prism and provide nutrients for deep-sea biological communities. At greater depths, H(2)O and CO(2) released by metamorphic reactions in the subducting oceanic crust may alter the bulk composition in the overlying mantle wedge and trigger partial melting reactions. The location and conse-quences of fluid production in subduction zones can be constrained by consideration of phase diagrams for relevant bulk compositions in conjunction with fluid and rock pressure-temperature-time paths predicted by numerical heat-transfer models. Partial melting of subducting, amphibole-bearing oceanic crust is predicted only within several tens of million years of the initiation of subduction in young oceanic lithosphere. In cooler subduction zones, partial melting appears to occur primarily in the overlying mantle wedge as a result of fluid infiltration.

  18. A melt-focusing zone in the lithospheric mantle preserved in the Santa Elena Ophiolite, Costa Rica

    NASA Astrophysics Data System (ADS)

    Madrigal, Pilar; Gazel, Esteban; Denyer, Percy; Smith, Ian; Jicha, Brian; Flores, Kennet E.; Coleman, Drew; Snow, Jonathan

    2015-08-01

    The Santa Elena Ophiolite in Costa Rica is composed of a well-preserved fragment of the lithospheric mantle that formed along a paleo-spreading center. Within its exposed architecture, this ophiolite records a deep section of the melt transport system of a slow/ultra-slow spreading environment, featuring a well-developed melt-focusing system of coalescent diabase dikes that intrude the peridotite in a sub-vertical and sub-parallel arrangement. Here we present an integrated analysis of new structural data, 40Ar/39Ar geochronology, major and trace element geochemistry and radiogenic isotope data from the diabase dikes in order to elucidate the tectonic setting of the Santa Elena Ophiolite. The dikes are basaltic and tholeiitic in composition. Petrological models of fractional crystallization suggest deep pressures of crystallization of > 0.4 GPa for most of the samples, which is in good agreement with similar calculations from slow/ultra-slow spreading ridges and require a relatively hydrated (~ 0.5 wt.% H2O) MORB-like source composition. The diabase dikes share geochemical and isotope signatures with both slow/ultra-slow spreading ridges and back-arc basins and indicate mixing of a DMM source and an enriched mantle end-member like EMII. The 40Ar/39Ar geochronology yielded an age of ~ 131 Ma for a previous pegmatitic gabbroic magmatic event that intruded the peridotite when it was hot and plastic and an age of ~ 121 Ma for the diabase intrusions, constraining the cooling from near asthenospheric conditions to lithospheric mantle conditions to ~ 10 Ma. Our findings suggest a complex interplay between oceanic basin and back-arc extension environments during the Santa Elena Ophiolite formation. We propose an alternative hypothesis for the origin of Santa Elena as an obducted fragment of an oceanic core complex (OCC).

  19. The basalt-high magnesium andesite association formed by multi-stage partial melting of a heterogeneous source mantle: Evidence from Hirado-Seto, Northwest Kyushu, Southwest Japan

    NASA Astrophysics Data System (ADS)

    Mashima, Hidehisa

    2009-10-01

    An association of basalts and high magnesium andesites (HMAs), erupted at 7 Ma after the opening of the Sea of Japan, exposed at Hirado-Seto in northwest Kyushu, southwest Japan. The rocks are aphyric and are characterized by enrichments in incompatible trace elements similar to those seen for oceanic island basalts, although the HMAs show a weak negative Nb anomaly. High MgO, Ni and low FeO*/MgO indicate that the Hirado-Seto rocks were originally primitive magmas. They do not show a positive correlation between K 2O/La and SiO 2, or between Pb/La and SiO 2, indicating that hydrous components derived from a subducting slab did not play a significant role in the genesis of the Hirado-Seto basalt-HMA magmas. Alternatively, the normative olivine-quartz-[Jd + CaTs] compositions indicate that the Hirado-Seto basalt-HMA magmas were formed by multi-stage partial melting of the source mantle at pressures ranging from 1 to 0.5 GPa along the 1300 °C mantle adiabat, assuming anhydrous conditions. Basalt magmas separated from the source mantle at 1 GPa. HMA magmas separated at 0.5 GPa. A weak negative anomaly for Nb in HMAs can be explained by precipitation of Ti-P oxides during their ascent under high fO 2 condition. Thinning of the Hirado-Seto lithosphere caused by transtensional strain during the opening of the Sea of Japan would have enabled separation of HMA magmas at unusually low pressures.

  20. Late Carboniferous adakitic granodiorites in the Qiongkusitai area, western Tianshan, NW China: Implications for partial melting of lower crust in the southern Central Asian Orogenic Belt

    NASA Astrophysics Data System (ADS)

    Yin, Jiyuan; Chen, Wen; Xiao, Wenjiao; Yuan, Chao; Long, Xiaoping; Cai, Keda; Zhang, Bin

    2016-07-01

    Carboniferous granitic rocks are wide spread in the western Tianshan, but their tectonic contexts remain controversial. We present zircon U-Pb age, major element, trace element, and in situ zircon Hf isotopic data for the Qiongkusitai granodiorites from the southern part of the Yili block in the western Tianshan. The granodiorites were emplaced in the Late Carboniferous (ca. 314 Ma) and are characterized by high SiO2 (62.1-65.7 wt.%), high Sr (376-485 ppm), low Y (13.7-17.7 ppm) and low Yb (1.34-1.81 ppm) with Sr/Y ratios of 23-34. Such characteristics imply adakitic affinities. Their low concentrations of Cr (3.85-6.75 ppm), Co (7.63-10.7 ppm) and Ni (2.94-6.80 ppm) suggest little, if any, interaction with a mantle source. Compared to the thickened lower crustal-derived adakitic rocks, the relatively low Nb/Ta ratios of the Qiongkusitai adakitic granodiorites indicate that they were probably generated by partial melting of amphibolite facies rocks, but not eclogite facies rocks. The Qiongkusitai adakitic granodiorites have positive zircon εHf(t) values of +0.7 to +5.1 and TDM2 of 1.28-1.68 Ga, and they are interpreted as being derived from remelting of amphibolite facies Mesoproterozoic basement with an input of juvenile material. Late Carboniferous magmatism in the western Tianshan was possibly triggered by asthenospheric upwelling as a result of the roll-back of the subducted southern Tianshan oceanic lithosphere.

  1. [Effects of nitrogen forms on the growth, yield and fruit quality of tomato under controlled alternate partial root zone irrigation].

    PubMed

    Zhang Qiang; Xu, Fei; Wang, Rong-fu; Shu, Liang-zuo; Liu, Rui; Zhang, De-yu

    2014-12-01

    The effects of nitrogen (N) forms (ammonium-N and nitrate-N) on the growth, yield and fruit quality of tomato plants (cv. Zhongyan 988) under controlled alternate partial root zone irrigation (APRI) were examined in a split-root experiment. Under the same irrigation mode and/or controlled soil water limitation treatment, ammonium-N promoted plant growth at the early stage, while nitrate-N improved plant growth and development at the later stage leading to higher biomass accumulation and fruit yield at harvest. Under APRI and the same soil water conditions, plants of the nitrate-N treatment improved the content of vitamin C and the ratio of soluble sugar to organic acid and thus facilitated fruit quality when compared with those of the ammonium-N treatment. Plant height and leaf area under APRI treatment were lower compared with conventional irrigation (CK) under the same N form, but the stem diameter under APRI treatment with 60% theta(f) (field water capacity, theta(f)) soil moisture showed a slight increase at the late growth stage. Under the same N form, fruit yield was significantly lower in APRI treatment than that of the CK. Compared with the CK, fruit yield decreased by 22.4%-26.3% under the APRI treatment with 40% theta(f) soil moisture. Under 60% theta(f) soil moisture, the APRI treatment significantly improved fruit quality and water-use efficiency compared with the CK regardless small reduction (5.3%-5.4%) in fruit yield. The experimental results suggested that the APRI treatment with the lower limitation of soil moisture controlled at 60% theta(f), and nitrate-N supply would be the optimal option in terms of sustainable use of water resource and fertilizer.

  2. [Effects of nitrogen forms on the growth, yield and fruit quality of tomato under controlled alternate partial root zone irrigation].

    PubMed

    Zhang Qiang; Xu, Fei; Wang, Rong-fu; Shu, Liang-zuo; Liu, Rui; Zhang, De-yu

    2014-12-01

    The effects of nitrogen (N) forms (ammonium-N and nitrate-N) on the growth, yield and fruit quality of tomato plants (cv. Zhongyan 988) under controlled alternate partial root zone irrigation (APRI) were examined in a split-root experiment. Under the same irrigation mode and/or controlled soil water limitation treatment, ammonium-N promoted plant growth at the early stage, while nitrate-N improved plant growth and development at the later stage leading to higher biomass accumulation and fruit yield at harvest. Under APRI and the same soil water conditions, plants of the nitrate-N treatment improved the content of vitamin C and the ratio of soluble sugar to organic acid and thus facilitated fruit quality when compared with those of the ammonium-N treatment. Plant height and leaf area under APRI treatment were lower compared with conventional irrigation (CK) under the same N form, but the stem diameter under APRI treatment with 60% theta(f) (field water capacity, theta(f)) soil moisture showed a slight increase at the late growth stage. Under the same N form, fruit yield was significantly lower in APRI treatment than that of the CK. Compared with the CK, fruit yield decreased by 22.4%-26.3% under the APRI treatment with 40% theta(f) soil moisture. Under 60% theta(f) soil moisture, the APRI treatment significantly improved fruit quality and water-use efficiency compared with the CK regardless small reduction (5.3%-5.4%) in fruit yield. The experimental results suggested that the APRI treatment with the lower limitation of soil moisture controlled at 60% theta(f), and nitrate-N supply would be the optimal option in terms of sustainable use of water resource and fertilizer. PMID:25876407

  3. Fluid mechanics and mass transfer in melt crystal growth: Analysis of the floating zone and vertical Bridgman processes

    NASA Technical Reports Server (NTRS)

    Brown, R. A.

    1986-01-01

    This research program focuses on analysis of the transport mechanisms in solidification processes, especially one of interest to the Microgravity Sciences and Applications Program of NASA. Research during the last year has focused on analysis of the dynamics of the floating zone process for growth of small-scale crystals, on studies of the effect of applied magnetic fields on convection and solute segregation in directional solidification, and on the dynamics of microscopic cell formation in two-dimensional solidification of binary alloys. Significant findings are given.

  4. Modeling study of the small-scale mantle convection in the subduction zone mantle wedge including the melting mechanism of mantle rocks

    NASA Astrophysics Data System (ADS)

    Yamamoto, M.; Tamura, Y.

    2014-12-01

    It is observed that subduction zone mantle wedge is not uniform even in the direction along the overlying island-arc that is perpendicular to the subducting direction. The hot fingers model is a hypothetical model specifying the three dimensional structural variation within the mangle wedge; it assumes that there is a fingers-like stripe pattern of mechanical and thermodynamical properties within the wedge. Those non-uniformity appears over the arc crust as nonuniform distribution of volcanic eruptions. Indeed, quaternary volcanoes in the NE Japan arc could be grouped into ten volcano clusters striking transverse to the arc. These have an average width of ∼50 km, and are separated by parallel gaps 30-75 km wide. Moreover, the structure of the mantle wedge and arc crust beneath the NE Japan arc and the Izu-Bonin-Mariana arc, respectively, suggest that the third dimension, lying along the strike of the arc, is necessary to understand the actual production of magmas in subduction zones. To explore the physical and mathematical mechanism of formation of the hot-fingers pattern, we develop a model of mantle convection in the mantle wedge. Our model incorporates the melting mechanism of the mantle rocks, which affect temperature and velocity of mantle. Our model produces a spatiotemporal pattern in those variables. The obtained results are compared with the spatiotemporal patterns observed in the NE Japan arc.

  5. Technical Note: Approximate solution of transient drawdown for constant-flux pumping at a partially penetrating well in a radial two-zone confined aquifer

    NASA Astrophysics Data System (ADS)

    Huang, C.-S.; Yang, S.-Y.; Yeh, H.-D.

    2015-03-01

    An aquifer consisting of a skin zone and a formation zone is considered as a two-zone aquifer. Existing solutions for the problem of constant-flux pumping (CFP) in a two-zone confined aquifer involve laborious calculation. This study develops a new approximate solution for the problem based on a mathematical model including two steady-state flow equations with different hydraulic parameters for the skin and formation zones. A partially penetrating well may be treated as the Neumann condition with a known flux along the screened part and zero flux along the unscreened part. The aquifer domain is finite with an outer circle boundary treated as the Dirichlet condition. The steady-state drawdown solution of the model is derived by the finite Fourier cosine transform. Then, an approximate transient solution is developed by replacing the radius of the boundary in the steady-state solution with an analytical expression for a dimensionless time-dependent radius of influence. The approximate solution is capable of predicting good temporal drawdown distributions over the whole pumping period except at the early stage. A quantitative criterion for the validity of neglecting the vertical flow component due to a partially penetrating well is also provided. Conventional models considering radial flow without the vertical component for the CFP have good accuracy if satisfying the criterion.

  6. Experimental study of local dehydration and partial melting of biotite-amphibole gneiss with participation of the H2O-CO2-(K, Na)Cl fluids at the middle-crustal conditions

    NASA Astrophysics Data System (ADS)

    Safonov, O.; Kozhukhantseva, S.

    2012-04-01

    Activity of aqueous chloride-rich brines coexisting with CO2-rich fluids is identified in many amphibolite and granulite terrains suggesting that this type of fluid is an important agent of high-grade metamorphism in the lower to middle crust (see reviews in Touret, 2009; Newton, Manning, 2010). Although thermodynamic and transport properties of these fluids is well constrained both theoretically and experimentally, their affect on complex natural assemblages is poorly understood and demands systematic experimental study. We report here results of the experiments on interaction of the biotite-amphibole gneiss from the Sand River formation (Limpopo Complex, South Africa) with the fluids H2O-CO2-(K, Na)Cl at 5.5 kbar, 750 and 800 C, the chloride/(H2O+CO2) varying from 0 0.1, and molar CO2/(CO2+H2O) = 0.5. No any reaction textures were identified in the sample interacted with the chloride-free CO2-H2O fluid at 750 C. At this temperature, addition of KCl into the fluid resulted in formation of spectacular reaction textures around biotite (Bt), amphibole (Amp), plagioclase (Pl) and quartz (Qtz) in the starting gneiss. These textures are intergrowths of low-Al clinopyroxene (Cpx) and K-feldspar (Kfs) (sporadically accompanied by ilmenite, sphene and Ti-bearing low-Al mica) corresponding to a progress of the following reactions: Phl + 3An + 18Qtz + 3(K2O in fluid) = 3Di + 7Kfs + (H2O in fluid) and Prg + Ed + 7(K2O in fluid) + 37Qtz + 5An = 9Di + 14Kfs + (2H2O + Na2O in fluid). Local partial melting of the gneiss interacted with KCl-bearing fluids at 750OC was observed only in the run at KCl/(CO2+H2O) = 1/30 and could be caused by local variation of water activity in the sample. Nevertheless, at 800 OC, granitic (>70 wt. % of SiO2) K2O-rich and Cl-bearing melt appears along the grain boundaries in all run samples. This melt produces K-feldspar and clinopyroxene, which are found as euhedral crystals in the glass. Melt films are usually accompanied by K-feldspar microveins

  7. Late Cretaceous dacitic dykes swarm from Central Iran, a trace for amphibolite melting in a subduction zone

    NASA Astrophysics Data System (ADS)

    Nosouhian, N.; Torabi, G.; Arai, S.

    2016-05-01

    Late Cretaceous Bayazeh dyke swarm is situated in the western part of the Central-East Iranian Microcontinent (CEIM). These dykes with a dominant northeast-southwest trend occur in the Eastern margin of the Yazd block. They cross cut the Lower Cretaceous sedimentary rocks. The length of the Bayazeh dykes occasionally reaches up to the 2 km. Rock forming minerals of these dykes are plagioclase (andesine and oligoclase), amphibole (magnesio-hastingsitic hornblende, magnesio-hornblende and tschermakitic hornblende), quartz, K-feldspar (orthoclase), zircon and apatite. Secondary minerals are chlorite (pycnochlorite), albite, magnetite and calcite. The main textures are porphyritic, glomeroporphyritic and poikilitic. The felsic character of the Bayazeh dacitic dykes is shown by their high SiO2 (62.70 to 64.60 wt %) and low [Fe2O3* + MgO + MnO + TiO2] (average 4.64 wt %) contents. These dykes represent the peraluminous to metaluminous nature and their Na2O and K2O values are 5.20-7.14 and 1.51-2.59 wt %, respectively, which reveal their sodic chemistry. The trace element characteristics are the LREE enrichment relative to HREE, [La/Yb]CN = 13.27-22.99, and slightly negative or positive Eu anomaly. These geochemical characteristics associated with low Nb/La (0.16-0.25), Yb/Nd (0.04-0.05) and high Zr/Sm (37.60-58.25) ratios indicate that the melting of a metamorphosed subducted oceanic crust is occurred where the residual mineral assemblage is dominated by garnet amphibolite. The chemical compositions of the Bayazeh dykes resemble those of slab-derived tonalite-trondhjemite-granodiorite (TTG) series. They were formed by subduction of Mesozoic Neo-Tethys -related Nain and Ashin oceanic crusts.

  8. The Effect of Temperature and Carbon to Hematite Ratio on the Formation of Cementite During the Couple of STMA and Partial Melting Processes

    NASA Astrophysics Data System (ADS)

    Soleymani, Amir Peyman; Panjepour, Masoud; Meratian, Mahmood

    2016-04-01

    In this research, the role of the couple of simultaneous thermal-mechanical activation (STMA) and partial melting (PM) processes in the carbothermic reduction of hematite and cementite formation was studied. For this purpose, the STMA process was performed for 6 hours at 1073 K (800 °C) on the mixture of hematite and graphite with stoichiometry ratio (22 wt pct C) in argon atmosphere in the first stage, and then this process was coupled to the PM process at 1453 K (1180 °C) for 25 minutes. The results obtained showed that the percentage of cementite phase in the product of the STMA process was only about 24 wt pct and after carrying out the PM process, this value reached 77 wt pct in the final product. In the second stage, the effect of the ratio of the parameters of carbon to hematite on the initial mixture (1:1, 1:25, and 1:5 times the stoichiometry ratio) and STMA process temperature [1073 K, 1123 K, and 1173 K (800 °C, 850 °C, and 900 °C)] was studied. The results were indicative of the fact that by an increase in the ratio of carbon to hematite and at STMA temperature, the percentage of cementite in the final product obtained from the PM process significantly increased. In fact, the specimens obtained from the couple of the STMA and PM processes with a carbon to hematite ratio of 1.5:1 at 1073 K (800 °C) and that of 1.25:1 at 1173 K (900 °C) showed the greatest percentage of cementite. The mechanism regarding the processes showed that by controlling the amount and manner of free carbon distribution in the STMA product based on the parameters of the ratio of carbon to hematite and temperature, it was possible to obtain pure cementite. Therefore, the couple of STMA and PM processes can also be brought up as a new method in the production of pure cementite.

  9. A multi-disciplinary investigation into the distribution of melt along the Taupo Volcanic Zone, New Zealand

    NASA Astrophysics Data System (ADS)

    Hamling, I. J.; Hreinsdottir, S.; Kilgour, G.; Bertrand, E. A.

    2015-12-01

    The 300 km long Taupo Volcanic Zone (TVZ) formed as a result of back-arc rifting associated with subduction of the Pacific Plate beneath the Australian Plate. The TVZ is home to two of the most active rhyolitic calderas in the world, Taupo and Okataina, and is thought to have erupted more than 10,000 km3 of predominately rhyolitic magma, with ~640 km3 of material over the past 61 ka from Taupo and Okataina alone. Using GPS and interferometric synthetic aperture radar (InSAR) data, collected by the European (ESA) and Japanese (JAXA) space agencies, we present ground deformation observations from 2003 to 2011 and show widespread subsidence across the central TVZ at rates of up to 20 mm/yr. Using simple elastic dislocation models to represent the contraction of a sill like body, we predict an annual volume change of up to 0.016 km3 beneath the central TVZ and suggest that the majority of the observed subsidence is a result of the cooling and subsequent contraction of magma within the shallow crust. Furthermore, with New Zealand volcanoes now added to the GEO's Geohazard Supersites and Natural Laboratories initiative, we will detail our attempts at integrating geodetic, magnetotelluric and petrological datasets to image the plumbing system beneath the TVZ.

  10. Partial port-closing strategy for obtaining high throughput or high purities in a four-zone simulated moving bed chromatography for binary separation.

    PubMed

    Mun, Sungyong

    2010-10-15

    The "partial port-closing" operation strategy for a four-zone simulated moving bed (SMB) chromatographic process for binary separation was developed to improve the SMB performance. This strategy included the partial extract-closing (PEC) and the partial raffinate-closing (PRC) operations. In case of the PEC operation, the extract port is made to be closed during the first-half stage of a switching period. During the latter-half stage, the extract port is made to be open. In case of the PRC operation, the raffinate port is made to be open during the first-half stage of a switching period. During the latter-half stage, the raffinate port is made to be closed. If the operating conditions are chosen properly in each operation using a highly efficient optimization tool, the product stream can be collected during only the period that the product is almost separated from impurity. During the other period that the product is contaminated with impurity, the collection of the product stream can be stopped by closing the product port. The uncollected product stream is then allowed to keep migrating through the adjacent zone within the SMB process. Such a partial port-closing operation including PEC and PRC was found to surpass a conventional SMB operation remarkably in throughput and product purity. PMID:20837353

  11. New geochemical and isotopic constraints on the genesis of the Oliveira Azeméis granitoid melts (Porto-Tomar Shear Zone, Iberian Variscan Chain, Central-Western Portugal)

    NASA Astrophysics Data System (ADS)

    Santos, J. F.; Mendes, M. H.; Gonçalves, A. C.; Moita, P.

    2012-04-01

    The Porto-Tomar Shear Zone (PTSZ) is a very important tectonic structure that separates, in central-western Portugal, two of the major tectonic units of the Iberian Variscan Chain: the Ossa-Morena Zone, to the west, and the Central Iberian Zone, to the east. The Oliveira de Azeméis area lies in the northern sector of the PTZC and it is characterized by the occurrence of strongly deformed granitoids. Country rocks are dominantly pelitic metasediments which, according to recent geological mapping (Pereira et al., 2007), belong to the Precambrian Lourosa Formation and the Ordovician São João de Ver Formation. Using Rb-Sr whole-rock isotopic data, Pinto (1979) proposed an age of 379±12 Ma for the Oliveira de Azeméis granitoids. In this work, new results were obtained on these granitoids in the area between the villages of Travanca and Curval, especially in the Sacramento quarry. In this critical outcrop, strongly deformed two-mica granite (displaying S-C structures, with dextral NNW-SSE shear planes) pass into diatexites and metatexites with garnet, cordierite and sillimanite-bearing melanosomes. Leucosomes seem to have mainly granitic s.s. compositions, but cm-thick bands of leucotonalite were also found. Major element geochemistry of granite samples shows the following ranges: 71.4% ≤ SiO2 ≤ 74.2%; 0.74% ≤Fe2O3t ≤ 2.48%; 0.35% ≤ MgO ≤ 0.60%; 0.49% ≤ CaO ≤ 1.32%; 2.90% ≤ Na2O ≤ 3.11%; 4.70% ≤ K2O ≤ 5.47%; 1.17 ≤ ASI ≤ 1.36. Trace element data reveal a strong fractionation between highly incompatible LILE and less incompatible HFSE (248 ≤ PM normalized Rb/Y ≤ 671) and between LREE and HREE (18.6 ≤ PM normalized La/Lu ≤ 54.7). These features, in particular the peraluminous composition, the high K contents and the distinct rare-earth fractionation suggest that the Oliveira de Azeméis granites are mostly the result of partial melting of metasediments with a large pelitic component and that garnet is a likely residual phase

  12. Seismic Constraints on Water and Melt Pathways and Fluxes Through Island Arc System

    NASA Astrophysics Data System (ADS)

    Wiens, D.; Wei, S. S.; Cai, C.; Eimer, M. O.; Adams, A. N.

    2015-12-01

    Seismological studies using land and ocean bottom seismographs can image velocity anomalies resulting from the presence of melt, fluids, and hydrated minerals in arc and backarc systems. The largest uncertainty in subduction zone water inputs derives from the lack of constraints on hydration of the incoming oceanic mantle. Results from several subduction zones show reduced mantle seismic velocities associated with extensional faulting as the incoming plate bends, suggesting up to 30% uppermost mantle serpentinization associated with water flow through faults. Extensional earthquakes occur to depths of about 15 km below the Moho at most subduction zones, suggesting the water storage capacity of the subducting uppermost mantle may be much larger than previously thought. Island arc systems with active backarc spreading centers offer an opportunity to image mantle wedge processes and compare with geochemical and petrological outputs. In Mariana, mantle seismic anomalies associated with arc and backarc melting are separated by a high velocity, low attenuation region at shallow depths (< 80 km), implying distinct arc and backarc melting regions, with the anomalies coalescing at greater depths. The maximum anomaly in the backarc is shallower (~ 30 km) than in the arc (~ 60 km), consistent with final equilibrium depths estimated from basalt thermobarometry. In the Lau basin the slow anomaly beneath the spreading center is displaced westward with greater depths, suggesting that partial melting occurs along an upwelling limb of mantle flow originating west of the backarc. The observed Lau backarc anomalies are roughly inversely proportional to inferred mantle water content, suggesting that water reduces the melt porosity. Water may increase the efficiency of melt transport and reduce porosity by lowering the melt viscosity, increasing grain size through faster grain growth, or by causing a different topology of melt within the mantle rock. A lower melt porosity for aqueous

  13. The relationship between the age of the lithosphere and the composition of oceanic magmas: Constraints on partial melting, mantle sources and the thermal structure of the plates

    NASA Astrophysics Data System (ADS)

    Haase, Karsten M.

    1996-10-01

    On the basis of different proportions and chemical compositions of shield and post-shield magmas, three types of oceanic intraplate volcanism appear to exist. The average SiO 2 contents of primitive melts of most Pacific and Atlantic intraplate lavas show a regular decrease with increasing age of the lithosphere up to 70 Ma. The average pressures of melting of most magmas lie beneath the thermal boundary layer defined by the 1300°C isotherm, in accordance with geophysical models. The average melting pressures of shield tholeiites erupting at the largest hotspots on Earth suggest that erosion of the plate is restricted to strong plumes. Increasing average ratios of (Ce/Yb) N(=chondrite-normalized) and (Tb/Yb) N with increasing age of the lithosphere imply that residual garnet has an increasing influence on the melting of most magmas. An influence of MORB material in intraplate magmas is observed in volcanoes erupting on lithosphere younger than 15 Ma. Correlations between SiO 2 and the rare earth element ratios suggest that the rare earth elements are more strongly influenced by the pressure of melting than by differences in source composition. Lavas with extremely low 143Nd/ 144Nd (e.g. Gough-Tristan da Cunha) have high (Nd/Sm) N for a given SiO 2, in accordance with a long-term enriched mantle source. After a correction for the fractionation occurring at high melting pressures (a recalculation of all averages to 50% SiO 2) the (Nd/Sm) N of most lavas can be modeled by 3-15% melting of depleted mantle sources.

  14. Dynamic and static equilibrium sea level effects of Greenland Ice Sheet melt: An assessment of partially-coupled idealized water hosing experiments (Invited)

    NASA Astrophysics Data System (ADS)

    Kopp, R. E.; Mitrovica, J. X.; Griffies, S. M.; Yin, J.; Hay, C. C.; Stouffer, R. J.

    2010-12-01

    Regional sea level can deviate from mean global sea level because of both dynamic sea level (DSL) effects, resulting from oceanic and atmospheric circulation and temperature and salinity distributions, and changes in the static equilibrium (SE) sea level configuration, produced by the gravitational, elastic, and rotational effects of mass redistribution. Both effects will contribute to future sea level change, but because they are studied by two different subdisciplines -- climate modeling and glacial rebound modeling -- projections that attempt to combine both have to date been scarce. To compare their magnitude, we simulated the effects of Greenland Ice Sheet (GIS) melt by conducting idealized North Atlantic "water-hosing" experiments in a climate model unidirectionally coupled to a SE sea level model. At current rates of GIS melt, freshwater hosing experiments in fully coupled atmosphere-ocean general circulation models (AOGCMs) do not yield clear DSL trends but do generate DSL variability; comparing that variability to expected static equilibrium "fingerprints" suggests that at least about 40 years of observations are needed to detect the "fingerprints" of ice sheet melt at current Greenland melt rates of about 0.3 mm equivalent sea level (esl)/year. Accelerated melt rates of about 2--6 mm esl/y, as may occur later in the century, should be detectable above background DSL variability within less than a decade of their onset. At these higher melt rates, AOGCMs do yield clear DSL trends. In the GFDL CM 2.1 model, DSL trends are strongest in the western North Atlantic, while SE effects come to dominate in most of the ocean when melt exceeds about 20 cm esl.

  15. Rapid Ascent of Aphyric Mantle Melts through the Overriding Crust in Subduction Zones: Evidence from Variable Uranium-Series Disequilibria, Amorphous Hydrous Alteration Microtextures in Crystal Rims, and Two-Pyroxene Pseudo-Decompression Paths

    NASA Astrophysics Data System (ADS)

    Zellmer, G. F.; Freymuth, H.; Hsieh, H. H.; Hwang, S. L.; Iizuka, Y.; Miller, C. A.; Rubin, K. H.; Sakamoto, N.; Yurimoto, H.

    2014-12-01

    Volcanic hazard mitigation at subduction zones critically depends on knowledge of magma generation and ascent processes and timescales. Two diametrically opposite scenarios are presently debated: One paradigm is the generation of low-silica (basaltic) melts in the mantle wedge, followed by protracted sub-liquidus magma ascent and evolution through crystal growth and fractionation in crustal reservoirs, which are tapped during volcanic eruptions. In contrast, a diametrically opposite model favours the generation of higher silica melts in the mantle or in a lower crustal hot zone, followed by rapid decompression to the surface under super-liquidus conditions. In the latter case, crystals are picked up during magma ascent, and are in the process of dissolving. We present multiple lines of evidence that point to crystal uptake as the principal processes by which arc melts acquire their crystal cargo: (i) variable 234U-238U disequilibria in mineral separates; (ii) hydrous mineral rims with amorphous alteration textures; and (iii) two-pyroxene pseudo-decompression paths; cf. Zellmer et al. (2014a,b,c), doi: 10.1144/SP385.3 and 10.1144/SP385.9 and 10.1144/SP410.1. These observations point to a scarcity of true phenocrysts in many arc magmas, and thus to decompression of aphyric melts that take up their crystal cargo during ascent. The data imply that many hydrous wedge melts are more silica-rich than basalts and achieve super-liquidus conditions during rapid ascent from great depth.

  16. The Asthenosphere Melting Regimes Alteration due to Changing Conditions of Upper Mantle

    NASA Astrophysics Data System (ADS)

    Perepechko, Y. V.; Sharapov, V. N.; Sorokin, K., Jr.

    2014-12-01

    Analyzed in the article are different asthenosphere magma generation regimes above the upper mantle hot spots as thermodynamic and geometric parameters of the upper mantle and the conditions on its boundaries vary. The two-layer mantle model is applied to consider the formation of decompression melting areas. The thickness of metasomatically altered lithospheric mantle is determined by the mantle substance rheology and the location of the upper boundary of asthenosphere. We also take into consideration the principal solid state phase transitions by using the mantle substance state equation. The sizes and distribution of hot spots as well as their maximal temperature were defined by the thermodynamic conditions of the perovskite transition existence. The numerical analysis results demonstrate the manifestation of three main mantle dynamics modes; the conditions necessary to form the partial melting zones are not reached; some melting areas with the 30 to 65 Ma existence time do occur; the melting areas that are formed exist permanently. The permanently existing asthenosphere zones are marked by quasiperiodical variation in thickness and the degree of melting. The typical temperatures of a hot spot sharing these modes are the 1740°С and 2020°С correspondingly. The originally presupposed heating degree and the temperature ratio of the upper mantle do influence the decompression melting degree substantially and - to a lesser extent - they influence the size of melting zones. The primary evolution of the second mode is described by the development of a complex system of asthenosphere zones that lead to the occurrence of additional convectional cells dividing the partial melting zone. The variation in the rheological properties of the mantle substance also contributes to the manifestation of the complex structure of asthenosphere zone. The work was made with support of the Russian Foundation for Basic Research grant #12-05-00625.

  17. Hydrogen permeation in stationary arc-melted nickel 200

    NASA Astrophysics Data System (ADS)

    Li, H.; North, T. H.; Sommerville, I. D.; McLean, A.

    1990-06-01

    A combination of hydrogen permeation experiments and computer simulation was used to evaluate the distributions of temperature and of the hydrogen transfer flux in a stationary arcmelted Nickel 200 disc over the entire hydrogen permeation zone. The results indicate that the markedly nonuniform temperature distribution in the hydrogen permeation zone involves widely varying hydrogen fluxes and even transfer of hydrogen in different directions. At steady state, the hydrogen distribution is determined by a thermally produced dynamic equilibrium. Hydrogen supersaturation occurs in solid nickel at the solid/liquid interface in the arc-melted pool. An increase in hydrogen partial pressure in the shielding gas increases the heat input to the melt and decreases the stability of the arc melting process.

  18. Testing How Depletion, Dehydration and Melt Affect Seismic Expressions of the Asthenosphere

    NASA Astrophysics Data System (ADS)

    Armitage, J. J.; Goes, S. D. B.; Hammond, J. O. S.

    2015-12-01

    Seismic images of the upper mantle beneath mid-ocean ridges and rift zones typically show discontinuities in wave speed that are often attributed to the presence of partial melt. To understand how lithosphere and asthenosphere differ in temperature, composition and melt content, it is necessary to test plausible dynamic scenarios against a wide range of observables. Here we take a first step at comparing seismic constraints with the seismic structure predicted for (1) a simple oceanic lithosphere-asthenosphere system, formed by melt extraction and dehydration at the ridge and half-space cooling as the lithosphere away from it and (2) continental break-up where there is significant partial melting. We have developed a relatively simple 2-D geodynamic model of decompression melting during extension that incorporates melt retention and dehydration. This model can explain the seismic structure below the East Pacific Rise as imaged by surface and body waves, including a double low velocity zone, with triangular anomaly above 50-60 km depth due to dry melting and low velocity layer between 60 and ~200km depth mainly resulting from solid-state anelasticity in hydrated mantle. We only require a minor contribution below the ridge of deep hydrous melt. Below Afar, in the East African Rift, S receiver functions have found a discontinuity in shear wave speeds at ~75km depth, consistent with the depth of the onset of dry melting. Yet, from the same forward model, no aspect of the melt zone leads to sufficiently sharp impedance contrast in isotropic velocity to explain the receiver-function signals. This suggests that something else is required to explain the seismic observations. We speculate that this may be a change in seismic anisotropy caused by a change in melt segregation characteristics.

  19. Porosity of the melting zone and variations in the solid mantle upwelling rate beneath Hawaii: Inferences from {sup 238}U-{sup 230}Th-{sup 226}Ra and {sup 235}U-{sup 231}Pa disequilibria

    SciTech Connect

    Sims, K.W.W.; DePaolo, D.J.; Murrell, M.T.; Baldridge, W.S.; Goldstein, S.; Clague, D.; Jull, M.

    1999-12-01

    Measurements of {sup 238}U-{sup 230}Th-{sup 226}Ra and {sup 235}U-{sup 231}Pa disequilibria in a suite of tholeiitic-to-basanitic lavas provide estimates of porosity, solid mantle upwelling rate and melt transport times beneath Hawaii. The observation that ({sup 230}Th/{sup 238}U) {gt} 1 indicates that garnet is required as a residual phase in the magma sources for all of the lavas. Both chromatographic porous flow and dynamic melting of a garnet peridotite source can adequately explain the combined U-Th-Ra and U-Pa data for these Hawaiian basalts. For chromatographic porous flow, the calculated maximum porosity in the melting zone ranges from 0.3--3% for tholeiites and 0.1--1% for alkali basalts and basanites, and solid mantle upwelling rates range from 40 to 100 cm/yr for tholeiites and from 1 to 3 cm/yr for basanites. For dynamic melting, the escape or threshold porosity is 0.5--2% for tholeiites and 0.1--0.8% for alkali basalts and basanites, and solid mantle upwelling rates range from 10 to 30 cm/yr for tholeiites and from 0.1 to 1 cm/yr for basanites. Assuming a constant melt productivity, calculated total melt fractions range from 15% for the tholeiitic basalts to 3% for alkali basalts and basanites.

  20. Slab melting and magma generation beneath the southern Cascade Arc

    NASA Astrophysics Data System (ADS)

    Walowski, K. J.; Wallace, P. J.; Clynne, M. A.

    2014-12-01

    Magma formation in subduction zones is interpreted to be caused by flux melting of the mantle wedge by fluids derived from dehydration of the downgoing oceanic lithosphere. In the Cascade Arc and other hot-slab subduction zones, however, most dehydration reactions occur beneath the forearc, necessitating a closer investigation of magma generation processes in this setting. Recent work combining 2-D steady state thermal models and the hydrogen isotope composition of olivine-hosted melt inclusions from the Lassen segment of the Cascades (Walowski et al., 2014; in review) has shown that partial melting of the subducted basaltic crust may be a key part of the subduction component in hot arcs. In this model, fluids from the slab interior (hydrated upper mantle) rise through the slab and cause flux-melting of the already dehydrated MORB volcanics in the upper oceanic crust. In the Shasta and Lassen segments of the southern Cascades, support for this interpretation comes from primitive magmas that have MORB-like Sr isotope compositions that correlate with subduction component tracers (H2O/Ce, Sr/P) (Grove et al. 2002, Borg et al. 2002). In addition, mass balance calculations of the composition of subduction components show ratios of trace elements to H2O that are at the high end of the global arc array (Ruscitto et al. 2012), consistent with the role of a slab-derived melt. Melting of the subducted basaltic crust should contribute a hydrous dacitic or rhyolitic melt (e.g. Jego and Dasgupta, 2013) to the mantle wedge rather than an H2O-rich aqueous fluid. We are using pHMELTS and pMELTS to model the reaction of hydrous slab melts with mantle peridotite as the melts rise through the inverted thermal gradient in the mantle wedge. The results of the modeling will be useful for understanding magma generation processes in arcs that are associated with subduction of relatively young oceanic lithosphere.

  1. Melt-rock reaction an melt impregnation in oceanic peridotites: insights from the Ligurian-Piemontese ophiolites

    NASA Astrophysics Data System (ADS)

    Piccardo, G. B.

    2011-12-01

    Mantle peridotites from Alpine-Apennine ophiolites, deriving from the Jurassic Ligurian Tethys, record signatures of the complex petrogenetic evolution, other than partial melting, that the lithospheric mantle suffered during pre-oceanic extension and melt percolation, melt-rock interaction and refertilization of early melts from decompression melting of the almost adiabatically upwelling asthenosphere (Piccardo et al., 2008). Lithosphere extension by far field tectonic forces lead to thinning of the lithospheric mantle and its progressive exhumation. Field and petrographic-structural data indicate that lithosphere extension was driven by extensional shear zones during the whole evolution of the mantle lithosphere, from garnet- to plagioclase-facies conditions. The pristine sub-continental lithospheric mantle is still preserved in ophiolites deriving from the passive margins (ocean-continent transition zones) of the basin, whereas melt-reacted and refertilized peridotites are dominant in more internal oceanic domains. OCT peridotites maintain structural-paragenetic features indicating their provenance from the deep lithosphere (P > 2.5 GPa) (Piccardo et al., 2009). Km-scale extensional shear zones in spinel peridotites (e.g., Vissers et al., 1991; Hoogerduijn Strating et al., 1993) have been dated to 220 Ma (Lu-Hf age) (Montanini et al., 2006) and 225 Ma (40Ar/39Ar amphibole age) (Müntener & Hermann, 2001) indicating that significant lithosphere extension and mantle exhumation was already active during Triassic times. Passive upwelling asthenosphere underwent fractional melting under spinel-facies conditions forming MORB-type depleted single melt increments that were injected into the lithospheric spinel-facies shear zones. Porous flow percolation of the silica-undersaturated melt fractions and melt-peridotite interaction (pyroxene dissolution and olivine precipitation) formed reactive spinel harzburgites and dunites. Melt-peridotite interaction led to silica

  2. Partial root-zone drying and conventional deficit irrigation applied during the whole berry growth maintain yield and berry quality in 'Crimson Seedless' table grapes

    NASA Astrophysics Data System (ADS)

    Pérez-Pastor, Alejandro; Domingo, Rafael; De la Rosa, Jose M.°; Rosario Conesa Saura, M.°

    2016-04-01

    To compare the effects of partial root-zone drying and conventional deficit irrigation applied during post-veraison and the whole berry growth on water relations, yield and berry quality, one experiment was conducted in a commercial vineyard of 'Crimson Seedless' table grapes. Five irrigation treatments were imposed: (i) Control (CTL) irrigated to 110% of crop evapotranspiration (ETc), (ii) regulated deficit irrigation (RDI) irrigated at 50% of CTL during the non- critical period of post-verasion, (iii) continuous deficit irrigation (DIc), irrigated at 50% of CTL throughout the whole berry growing season, (iv) partial root-zone drying (PRD), irrigated similar to RDI, but alternating the irrigation applied in the dry side every 10-14 days; and (v) continuous partial root-zone drying (PRDc), irrigated as DIc but alternating the irrigation in the dry side every 10-14 days. RDI and PRD received 24% and 28% less water than CTL, respectively. These reductions were higher in DIc and PRDc (65% and 53%, respectively). Total yield was not affected by any DI strategy. Only significantly lower values were observed in the weight and height's berries in respect to CTL. However, the colour parameters evaluated increased in all DI treatments, being slightly higher in DIc and PRDc compared with RDI and PRD. In addition, total soluble solids (TSS) were significantly higher in DIc, compared to other irrigated counterparts. Our findings showed that the application of water deficit during the whole berry growth through the use of DIc and PRDc, can be considered for irrigation scheduling in 'Crimson Seedless' table grapes. Acknowledgements This work has been funded by the European Union LIFE+ project IRRIMAN (LIFE13 ENV/ES/000539).

  3. Application of zone-melting technique to metal chelate systems-XI Refining of tetrakis(di-n-propionylmethanato)zirconium(IV) from hafnium and trace amounts of some other metals.

    PubMed

    Yoshida, I; Kobayashi, H; Ueno, K

    1977-01-01

    The zone-melting method was applied to purification of tetrakis(di-n-propionylmethanato)zirconium(IV) which contained copper(II), nickel(II), cobalt(II and III), iron(III) and hafnium(IV) in the forms of their chelates with the common ligand. All minor components having effective distribution coefficients < 1 in the zirconium(IV) chelate were concentrated toward the terminal end of the refining column. When an aqueous solution of zirconium(IV) containing zinC(II) and manganese(II) in addition to the metal contaminants above was treated with di-n-propionylmethane to precipitate the chelate complexes, only zinc, iron and hafnium were found in the precipitated zirconium chelate. The first two were ettectively removed by zone-melting. Though the separation of hafnium was poorer, the technique was efficient enough for practical purposes. PMID:18962026

  4. The value of magnetoencephalography for seizure-onset zone localization in magnetic resonance imaging-negative partial epilepsy

    PubMed Central

    Bouet, Romain; Delpuech, Claude; Ryvlin, Philippe; Isnard, Jean; Guenot, Marc; Bertrand, Olivier; Hammers, Alexander; Mauguière, François

    2013-01-01

    Surgical treatment of epilepsy is a challenge for patients with non-contributive brain magnetic resonance imaging. However, surgery is feasible if the seizure-onset zone is precisely delineated through intracranial electroencephalography recording. We recently described a method, volumetric imaging of epileptic spikes, to delineate the spiking volume of patients with focal epilepsy using magnetoencephalography. We postulated that the extent of the spiking volume delineated with volumetric imaging of epileptic spikes could predict the localizability of the seizure-onset zone by intracranial electroencephalography investigation and outcome of surgical treatment. Twenty-one patients with non-contributive magnetic resonance imaging findings were included. All patients underwent intracerebral electroencephalography investigation through stereotactically implanted depth electrodes (stereo-electroencephalography) and magnetoencephalography with delineation of the spiking volume using volumetric imaging of epileptic spikes. We evaluated the spatial congruence between the spiking volume determined by magnetoencephalography and the localization of the seizure-onset zone determined by stereo-electroencephalography. We also evaluated the outcome of stereo-electroencephalography and surgical treatment according to the extent of the spiking volume (focal, lateralized but non-focal or non-lateralized). For all patients, we found a spatial overlap between the seizure-onset zone and the spiking volume. For patients with a focal spiking volume, the seizure-onset zone defined by stereo-electroencephalography was clearly localized in all cases and most patients (6/7, 86%) had a good surgical outcome. Conversely, stereo-electroencephalography failed to delineate a seizure-onset zone in 57% of patients with a lateralized spiking volume, and in the two patients with bilateral spiking volume. Four of the 12 patients with non-focal spiking volumes were operated upon, none became seizure

  5. The value of magnetoencephalography for seizure-onset zone localization in magnetic resonance imaging-negative partial epilepsy.

    PubMed

    Jung, Julien; Bouet, Romain; Delpuech, Claude; Ryvlin, Philippe; Isnard, Jean; Guenot, Marc; Bertrand, Olivier; Hammers, Alexander; Mauguière, François

    2013-10-01

    Surgical treatment of epilepsy is a challenge for patients with non-contributive brain magnetic resonance imaging. However, surgery is feasible if the seizure-onset zone is precisely delineated through intracranial electroencephalography recording. We recently described a method, volumetric imaging of epileptic spikes, to delineate the spiking volume of patients with focal epilepsy using magnetoencephalography. We postulated that the extent of the spiking volume delineated with volumetric imaging of epileptic spikes could predict the localizability of the seizure-onset zone by intracranial electroencephalography investigation and outcome of surgical treatment. Twenty-one patients with non-contributive magnetic resonance imaging findings were included. All patients underwent intracerebral electroencephalography investigation through stereotactically implanted depth electrodes (stereo-electroencephalography) and magnetoencephalography with delineation of the spiking volume using volumetric imaging of epileptic spikes. We evaluated the spatial congruence between the spiking volume determined by magnetoencephalography and the localization of the seizure-onset zone determined by stereo-electroencephalography. We also evaluated the outcome of stereo-electroencephalography and surgical treatment according to the extent of the spiking volume (focal, lateralized but non-focal or non-lateralized). For all patients, we found a spatial overlap between the seizure-onset zone and the spiking volume. For patients with a focal spiking volume, the seizure-onset zone defined by stereo-electroencephalography was clearly localized in all cases and most patients (6/7, 86%) had a good surgical outcome. Conversely, stereo-electroencephalography failed to delineate a seizure-onset zone in 57% of patients with a lateralized spiking volume, and in the two patients with bilateral spiking volume. Four of the 12 patients with non-focal spiking volumes were operated upon, none became seizure

  6. Formation of harzburgite by pervasive melt/rock reaction in the upper mantle

    USGS Publications Warehouse

    Kelemen, P.B.; Dick, H.J.B.; Quick, J.E.

    1992-01-01

    Many mantle peridotite samples are too rich in SiO2 (in the form of orthopyroxene) and have ratios of light to heavy rare earth elements that are too high to be consistent with an origin as the residuum of partial melting of the primitive mantle. Trace element studies of melt/rock reaction zones in the Trinity peridotite provide evidence for reaction of the mantle lithosphere with ascending melts, which dissolved calcium-pyroxene and precipitated orthopyroxene as magma mass decreased. This process can account for the observed major and trace element compositions of lithospheric mantle samples, and may accordingly be prevalent in the upper mantle.

  7. The evolution and storage of primitive melts in the Eastern Volcanic Zone of Iceland: the 10 ka Grímsvötn tephra series (i.e. the Saksunarvatn ash)

    NASA Astrophysics Data System (ADS)

    Neave, David A.; Maclennan, John; Thordarson, Thorvaldur; Hartley, Margaret E.

    2015-08-01

    Major, trace and volatile elements were measured in a suite of primitive macrocrysts and melt inclusions from the thickest layer of the 10 ka Grímsvötn tephra series (i.e. Saksunarvatn ash) at Lake Hvítárvatn in central Iceland. In the absence of primitive tholeiitic eruptions (MgO > 7 wt%) within the Eastern Volcanic Zone (EVZ) of Iceland, these crystal and inclusion compositions provide an important insight into magmatic processes in this volcanically productive region. Matrix glass compositions show strong similarities with glass compositions from the AD 1783-1784 Laki eruption, confirming the affinity of the tephra series with the Grímsvötn volcanic system. Macrocrysts can be divided into a primitive assemblage of zoned macrocryst cores (An78-An92, Mg#cpx = 82-87, Fo79.5-Fo87) and an evolved assemblage consisting of unzoned macrocrysts and the rims of zoned macrocrysts (An60-An68, Mg#cpx = 71-78, Fo70-Fo76). Although the evolved assemblage is close to being in equilibrium with the matrix glass, trace element disequilibrium between primitive and evolved assemblages indicates that they were derived from different distributions of mantle melt compositions. Juxtaposition of disequilibrium assemblages probably occurred during disaggregation of incompatible trace element-depleted mushes (mean La/Ybmelt = 2.1) into aphyric and incompatible trace element-enriched liquids (La/Ybmelt = 3.6) shortly before the growth of the evolved macrocryst assemblage. Post-entrapment modification of plagioclase-hosted melt inclusions has been minimal and high-Mg# inclusions record differentiation and mixing of compositionally variable mantle melts that are amongst the most primitive liquids known from the EVZ. Coupled high-field strength element (HFSE) depletion and incompatible trace element enrichment in a subset of primitive plagioclase-hosted melt inclusions can be accounted for by inclusion formation following plagioclase dissolution driven by interaction with plagioclase

  8. Granodiorites of the South Mountain Batholith (Nova Scotia, Canada) derived by partial melting of Avalonia granulite rocks beneath the Meguma terrane: Implications for the heat source of the Late Devonian granites of the Northern Appalachians

    NASA Astrophysics Data System (ADS)

    Shellnutt, J. Gregory; Dostal, Jaroslav

    2015-08-01

    The Late Devonian South Mountain Batholith (SMB) of Nova Scotia is the largest batholith of the northern Appalachians. The peraluminous granitic rocks range from biotite granodiorite to leucogranite. Samples collected from a drill core of the Scrag Lake granodioritic pluton of the western SMB are chemically homogeneous from the surface to a depth of ~ 1425 m. The homogeneous composition implies that the granodiorite was derived from a relatively homogeneous source and that country rock assimilation was not an important source for the parental magma. Equilibrium partial melt modeling of underlying sub-Meguma granulite rocks indicates that they are the primary source rocks of the granodiorites. We suggest that mantle-derived magmas intruded the lower crust and induce large-scale melting of the granulite basement rocks to produce the granodiorites. Fractional crystallization of the granodiorites plus assimilation of Meguma Supergroup metasediments likely produces the silica-rich rocks of the SMB. The cause of mantle melting is uncertain however it may be related to the transitioning of the northern Appalachians from a position above the deep mantle Pacific large low shear velocity province (LLSVP) to a higher shear velocity region of the mantle.

  9. Partial melting of the mélange for the growth of andesitic crust indicated by the Early Cretaceous arc dioritic/andesitic rocks in southern Qiangtang, central Tibet

    NASA Astrophysics Data System (ADS)

    Hao, LuLu; Wang, Qiang; Wyman, Derek; Ou, Quan; Dan, Wei; Jiang, ZiQi; Yang, JinHui; Long, XiaoPing; Li, Jie

    2016-04-01

    Deciphering the petrogenesis of andesitic/dioritic rocks is fundamental to understanding the formation of the continental crust. Here we present the detailed petrology, geochronology, major and trace element, Sr-Nd-Hf-O isotope data for the Early Cretaceous (ca. 122 Ma) dioritic rocks in the Bizha area in southern Qiangtang, Tibet. The dioritic rocks are characterized by large ion lithophile elements, Pb and light rare earth elements but depletion of high field strength elements with slightly enriched and variable ɛNd(t) values of -0.01 to -3.31 and initial 87Sr/86Sr isotopic ratios of 0.7053 to 0.7062. They also have variable magmatic zircon Hf-O isotope compositions (ɛHf(t) = -5.3 to +3.6 and δ18O = 7.3 to 9.5 ‰). Combined with contemporary andesitic lavas in southern Qiangtang, we suggest that the intermediate magmatic rocks in this area were most probably derived by partial melting of the mélange, which is a mixture of the middle oceanic ridge basalts (MORBs), sediments and mantle wedge peridotites, formed along the interface between the subducted slab and the overlying mantle wedge in a subduction channel before ~ 124 Ma. The mélange diapir melting was triggered by the asthenospheric upwelling and hot corner flow caused by roll-back of the northward subducted Bangong-Nujiang oceanic slab during the Early Cretaceous. The Early Cretaceous intermediate magmatic rocks in southern Qiangtang have an overall continental crust-like andesitic composition. Therefore, partial melting of the mélange provides an important support for the generation of andesitic magmas in continental arcs and the "andesite model" for crustal growth.

  10. Pliocene-Quaternary crustal melting in central and northern Tibet and insights into crustal flow.

    PubMed

    Wang, Qiang; Hawkesworth, Chris J; Wyman, Derek; Chung, Sun-Lin; Wu, Fu-Yuan; Li, Xian-Hua; Li, Zheng-Xiang; Gou, Guo-Ning; Zhang, Xiu-Zheng; Tang, Gong-Jian; Dan, Wei; Ma, Lin; Dong, Yan-Hui

    2016-01-01

    There is considerable controversy over the nature of geophysically recognized low-velocity-high-conductivity zones (LV-HCZs) within the Tibetan crust, and their role in models for the development of the Tibetan Plateau. Here we report petrological and geochemical data on magmas erupted 4.7-0.3 Myr ago in central and northern Tibet, demonstrating that they were generated by partial melting of crustal rocks at temperatures of 700-1,050 °C and pressures of 0.5-1.5 GPa. Thus Pliocene-Quaternary melting of crustal rocks occurred at depths of 15-50 km in areas where the LV-HCZs have been recognized. This provides new petrological evidence that the LV-HCZs are sources of partial melt. It is inferred that crustal melting played a key role in triggering crustal weakening and outward crustal flow in the expansion of the Tibetan Plateau. PMID:27307135

  11. Contrasting physiological effects of partial root zone drying in field-grown grapevine (Vitis vinifera L. cv. Monastrell) according to total soil water availability.

    PubMed

    Romero, Pascual; Dodd, Ian C; Martinez-Cutillas, Adrian

    2012-06-01

    Different spatial distributions of soil moisture were imposed on field-grown grapevines by applying the same irrigation volumes to the entire (DI; deficit irrigation) or part of the (PRD; partial root zone drying) root zone. Five treatments were applied: controls irrigated at 60% ETc (crop evapotranspiration) for the whole season (308 mm year(-1)); DI-1 and PRD-1 that received the same irrigation as controls before fruit set, 30% ETc from fruit set to harvest and 45% ETc post-harvest (192 mm year(-1)); and DI-2 and PRD-2 that were the same, except that 15% ETc was applied from fruit set to harvest (142 mm year(-1)). Compared with DI-1, PRD-1 maintained higher leaf area post-veraison and increased root water uptake, whole-plant hydraulic conductance, leaf transpiration, stomatal conductance, and photosynthesis, but decreased intrinsic gas exchange efficiency without causing differences in leaf xylem abscisic acid (ABA) concentration. Compared with DI-2, PRD-2 increased leaf xylem ABA concentration and decreased root water uptake, whole-plant hydraulic conductance, leaf transpiration, stomatal conductance, and photosynthesis, mainly at the beginning of PRD cycles. Distinctive PRD effects (e.g. greater stomatal closure) depended on the volumetric soil water content of the wet root zone, as predicted from a model of root-to-shoot ABA signalling. PMID:22451721

  12. Density and seismic velocity of hydrous melts under crustal and upper mantle conditions

    NASA Astrophysics Data System (ADS)

    Ueki, Kenta; Iwamori, Hikaru

    2016-05-01

    We present a new model for calculating the density of hydrous silicate melts as a function of P, T, H2O concentration, and melt composition. We optimize VPr,Tr, ∂V/∂T, ∂V/∂P, ∂V2/∂T∂P, and K' of H2O end-member components in hydrous silicate melts, as well as K' of anhydrous silicate melts, using previously reported experimental results. The parameter set for H2O end-member component in silicate melt optimized in this study is internally consistent with the parameter values for the properties of anhydrous silicate melt reported by Lange and Carmichael (1987, 1990). The model calculation developed in this study reproduces the experimentally determined densities of various hydrous melts, and can be used to calculate the relationships between pressures, temperatures, and H2O concentrations of various hydrous melts from ultramafic to felsic compositions at pressures of 0-4.29 GPa. Using the new parameter set, we investigate the effects of H2O content on the seismic velocity of hydrous melts, as well as seismic velocities in partially molten regions of subduction zones. The results show that water content in silicate melt plays a key role in determining seismic velocity structure, and therefore must be taken into account when interpreting seismic tomography.

  13. Strain partitioning into dry and wet zones and the formation of Ca-rich myrmekite in syntectonic syenites: A case for melt-assisted dissolution-replacement creep under granulite facies conditions

    NASA Astrophysics Data System (ADS)

    De Toni, G. B.; Bitencourt, M. F.; Nardi, L. V. S.

    2016-10-01

    The formation of Ca-rich myrmekites is described in syntectonic syenites crystallized and progressively deformed under granulite facies conditions. The syenites are found in high- and low-strain zones where microstructure and mineral composition are compared. Heterogeneously distributed water-rich, late-magmatic liquids were responsible for strain partitioning into dry and wet high-strain zones at outcrop scale, where contrasting deformation mechanisms are reported. In dry high-strain zones K-feldspar and clinopyroxene are recrystallized under high-T conditions. In wet high-strain zones, the de-stabilization of clinopyroxene and pervasive replacement of relatively undeformed K-feldspar porphyroclasts by myrmekite and subordinate micrographic intergrowths indicate dissolution-replacement creep as the main deformation mechanism. The reworking of these intergrowths is observed and is considered to contribute significantly to the development of the mylonitic foliation and banding. A model is proposed for strain partitioning relating a positive feedback between myrmekite-forming reaction, continuous inflow of late-magmatic liquids and dissolution-replacement creep in the wet zone at the expenses of original mineralogy preserved in the dry zones. Melt-assisted dissolution-replacement creep in syntectonic environments under granulite-facies conditions may extend the field of operation of dissolution-replacement creep, changing significantly the rheology of the lower continental crust.

  14. Seismic evidence of effects of water on melt transport in the Lau back-arc mantle.

    PubMed

    Wei, S Shawn; Wiens, Douglas A; Zha, Yang; Plank, Terry; Webb, Spahr C; Blackman, Donna K; Dunn, Robert A; Conder, James A

    2015-02-19

    Processes of melt generation and transport beneath back-arc spreading centres are controlled by two endmember mechanisms: decompression melting similar to that at mid-ocean ridges and flux melting resembling that beneath arcs. The Lau Basin, with an abundance of spreading ridges at different distances from the subduction zone, provides an opportunity to distinguish the effects of these two different melting processes on magma production and crust formation. Here we present constraints on the three-dimensional distribution of partial melt inferred from seismic velocities obtained from Rayleigh wave tomography using land and ocean-bottom seismographs. Low seismic velocities beneath the Central Lau Spreading Centre and the northern Eastern Lau Spreading Centre extend deeper and westwards into the back-arc, suggesting that these spreading centres are fed by melting along upwelling zones from the west, and helping to explain geochemical differences with the Valu Fa Ridge to the south, which has no distinct deep low-seismic-velocity anomalies. A region of low S-wave velocity, interpreted as resulting from high melt content, is imaged in the mantle wedge beneath the Central Lau Spreading Centre and the northeastern Lau Basin, even where no active spreading centre currently exists. This low-seismic-velocity anomaly becomes weaker with distance southward along the Eastern Lau Spreading Centre and the Valu Fa Ridge, in contrast to the inferred increase in magmatic productivity. We propose that the anomaly variations result from changes in the efficiency of melt extraction, with the decrease in melt to the south correlating with increased fractional melting and higher water content in the magma. Water released from the slab may greatly reduce the melt viscosity or increase grain size, or both, thereby facilitating melt transport.

  15. Carbonate Stability and Melt Composition in Peridotite-CO2 System to 20 GPa

    NASA Astrophysics Data System (ADS)

    Ghosh, S.; Ohtani, E.; Litasov, K. D.; Suzuki, A.; Terasaki, H.

    2005-12-01

    Carbon dioxide and water are the most important volatile constituents in the Earth and they produce drastic changes in the melting phase relations and partial melt compositions of the mantle peridotite. Study of the peridotite-CO2 system is closely related to petrogenesis of kimberlite and diamond. There are a few high pressure mineral inclusions (i.e. majorite garnet and Ca and Mg perovskite) in diamond which suggest that kimberlites may be originated from the transition zone and lower mantle. The phase relations and melt compositions in the CO2-bearing peridotite at high pressures are poorly constrained, however the kimberlite and basalt-CO2 systems have been studied intensively. Simplified peridotite-CO2 system (like CMS or CMAS) has been studied at pressures up to 12 GPa (Canil and Scarfe, 1990), whereas complex peridotite-CO2 systems have been investigated only at lower pressures (up to 4 GPa, e.g. Wendlandt and Mysen, 1980). In this work we report the preliminary results on the phase relations and melt compositions of a model peridotite-CO2 system determined at 10-20 GPa and temperature range from 1200 to 2100oC. Our results show that solidus of carbonated peridotite is consistent with low-pressure data for CMAS-CO2 system. Liquidus phase at 10-20 GPa is majorite garnet. At 10-15 GPa, crystallization sequence with decreasing temperature is garnet, olivine and clinoenstatite. Magnesite is the most important CO2-rich phase stable in peridotite up to 1600oC at 20 GPa. The partial melt formed by 10-25% melting at 10-20 GPa has high MgO (26-34 wt.%) and FeO (7.0-10.4 wt.%) and low SiO2 (18-36 wt.%) and Al2O3 (0.5-1.3 wt.%) contents. It also contains 6-12 wt.% CaO, 0.6-2.0 wt.% Na2O and 0.1-0.3 wt.% K2O. The CO2 contents in the melts are 14-32 wt.%. The SiO2-poor nature of the partial melts is different from the results for melting of anhydrous or water-bearing peridotite. Partial melting of hydrous peridotite produces the melts enriched in SiO2, which can be

  16. Existence of a stable resonance zone with nearly unchanging vibration characteristics for a near-field scanning optical microscope probe dipped partially into a liquid

    NASA Astrophysics Data System (ADS)

    Lee, Wonjun; Kim, Seyoung; Kim, Dae-Chan; O, Beom-Hoan; Park, Se-Geun; Lee, Seung Gol

    2014-02-01

    The vibration characteristics of a near-field scanning optical microscope (NSOM) probe, whose vibration was controlled by two-nodal-wedge method and tip was partially dipped into a liquid, were investigated theoretically and experimentally. The resonant frequency and the Q value of the NSOM probe were found to remain nearly unchanged irrespective of the dipping depth of the probe, if the probe was kept within a dipping depth range of 0.4˜1.0 mm. With the achievement of a high Q value, the existence of this stable resonance zone implies that bio-samples immersed in a liquid can be accurately and stably measured using a NSOM controlled by using two-nodal-wedge method.

  17. The jumbo squid, Dosidicus gigas (Ommastrephidae), living in oxygen minimum zones I: Oxygen consumption rates and critical oxygen partial pressures

    NASA Astrophysics Data System (ADS)

    Trueblood, Lloyd A.; Seibel, Brad A.

    2013-10-01

    Dosidicus gigas is a large, metabolically active, epipelagic squid known to undertake diel vertical migrations across a large temperature and oxygen gradient in the Eastern Pacific. Hypoxia is known to cause metabolic suppression in D. gigas. However, the precise oxygen level at which metabolic suppression sets in is unknown. Here we describe a novel ship-board swim tunnel respirometer that was used to measure metabolic rates and critical oxygen partial pressures (Pcrit) for adult squids (2-7kg). Metabolic rate measurements were validated by comparison to the activity of the Krebs cycle enzyme, citrate synthase, in mantle muscle tissue (2-17kg). We recorded a mean routine metabolic rate of 5.91μmolg-1h-1 at 10°C and 12.62μmolg-1h-1 at 20°C. A temperature coefficient, Q10, of 2.1 was calculated. D. gigas had Pcrits of 1.6 and 3.8kPa at 10 and 20°C, respectively. Oxygen consumption rate (MO2) varied with body mass (M) according to MO2=11.57M-0.12±0.03 at 10°C. Citrate synthase activity varied with body mass according to Y=9.32M-0.19±0.02.

  18. Melting of subducted basalt at the core-mantle boundary.

    PubMed

    Andrault, Denis; Pesce, Giacomo; Bouhifd, Mohamed Ali; Bolfan-Casanova, Nathalie; Hénot, Jean-Marc; Mezouar, Mohamed

    2014-05-23

    The geological materials in Earth's lowermost mantle control the characteristics and interpretation of seismic ultra-low velocity zones at the base of the core-mantle boundary. Partial melting of the bulk lower mantle is often advocated as the cause, but this does not explain the nonubiquitous character of these regional seismic features. We explored the melting properties of mid-oceanic ridge basalt (MORB), which can reach the lowermost mantle after subduction of oceanic crust. At a pressure representative of the core-mantle boundary (135 gigapascals), the onset of melting occurs at ~3800 kelvin, which is ~350 kelvin below the mantle solidus. The SiO2-rich liquid generated either remains trapped in the MORB material or solidifies after reacting with the surrounding MgO-rich mantle, remixing subducted MORB with the lowermost mantle.

  19. Serpentinization, element transfer, and the progressive development of zoning in veins: evidence from a partially serpentinized harzburgite

    NASA Astrophysics Data System (ADS)

    Schwarzenbach, Esther M.; Caddick, Mark J.; Beard, James S.; Bodnar, Robert J.

    2016-01-01

    Serpentinization is an important geochemical process that affects the chemistry and petrophysical properties of the oceanic lithosphere and supports life through abiogenic formation of hydrogen. Here, we document through detailed mineralogical evidence and equilibrium thermodynamic models the importance of water (H2O) and silica (SiO2) activities on mineral assemblages produced during progressive serpentinization of a harzburgite. We describe a harzburgite from the Santa Elena Ophiolite in Costa Rica that is ~30 % serpentinized. Serpentine + brucite ± magnetite veins occur in olivine, Al-rich serpentine + talc veins occur in orthopyroxene, and Al-rich serpentine ± talc ± brucite veins occur at the boundary of orthopyroxene and olivine. Bulk vein chemistry and element distribution maps demonstrate distinct chemical zonations within veins and chemical gradients between orthopyroxene- and olivine-dominated areas. Specifically, the sample records (1) varying brucite composition depending on whether or not it is associated with magnetite, (2) formation of magnetite from Fe-rich brucite (±Fe-rich serpentine) during olivine hydration, where magnetite coexists with brucite Mg#96 and serpentine Mg#99, (3) chemical gradients in Si, Al, Cr, and Ca within and between orthopyroxene- and olivine-hosted veins, and 4) local (different) equilibrium assemblages within different zones of veins. The studied sample preserves rarely observed textures documenting continuous replacement of olivine, rather than individual vein generations and overprinting that is typically observed in more intensely serpentinized peridotites. Furthermore, the presence of a discrete sequence of vein textures and mineralogy allows direct comparison between mineral textures and equilibrium thermodynamic models and permits new insights into mineral reactions during serpentinization.

  20. Genesis of adakitic granitoids by partial melting of thickened lower crust and its implications for early crustal growth: A case study from the Huichizi pluton, Qinling orogen, central China

    NASA Astrophysics Data System (ADS)

    Qin, Zhengwei; Wu, Yuanbao; Siebel, Wolfgang; Gao, Shan; Wang, Hao; Abdallsamed, Mohammed. I. M.; Zhang, Wenxiang; Yang, Saihong

    2015-12-01

    Adakitic rocks are often considered as a key to deciphering the genesis of Archean TTGs and the early crustal growth. Granites from the Huichizi pluton in the North Qinling (NQ) unit have high Sr/Y and (La/Yb)N ratios similar to adakites. Their relatively high SiO2, K2O, and Na2O and very low MgO, Cr, and Ni contents are in the range of high-SiO2 adakites and early Archean TTGs and are compositionally similar to experimental melts derived from metabasalt sources. New SIMS zircon U-Pb dating constrains the emplacement age of the Huichizi pluton at 422 ± 5 Ma. Rock samples from the Huichizi pluton have εNd(t) and zircon εHf(t) values similar to the Neoproterozoic metabasalts in the NQ unit. In combination with their normal mantle-like δ18Ozir values, these adakites are best explained by partial melting of the Neoproterozoic mafic crustal root due to subduction of the Shangdan ocean. Regional geological data suggest that the crust was probably thickened by a ca. 490 Ma arc-collision process prior to the emplacement of the Huichizi pluton. Our results confirm that underplating of mafic magma and its subsequent fusion triggered by slab subduction under high pressure conditions could be an important mechanism for the formation of early continental crust.

  1. Comparative effects of deficit irrigation and alternate partial root-zone irrigation on xylem pH, ABA and ionic concentrations in tomatoes.

    PubMed

    Wang, Yaosheng; Liu, Fulai; Jensen, Christian Richardt

    2012-03-01

    Comparative effects of partial root-zone irrigation (PRI) and deficit irrigation (DI) on xylem pH, ABA, and ionic concentrations of tomato (Lycopersicon esculentum L.) plants were investigated in two split-root pot experiments. Results showed that PRI plants had similar or significantly higher xylem pH, which was increased by 0.2 units relative to DI plants. Nitrate and total ionic concentrations (cations+anions), and the proportion of cations influenced xylem pH such that xylem pH increases as nitrate and total ionic concentrations decrease, and the proportion of cations increases. In most cases, the xylem ABA concentration was similar for PRI and DI plants, and a clear association between increases in xylem pH with increasing xylem ABA concentration was only found when the soil water content was relatively low. The concentrations of anions, cations, and the sum of anions and cations in PRI were higher than in the DI treatment when soil water content was relatively high in the wetted soil compartment. However, when water content in both soil compartments of the PRI pots were very low before the next irrigation, the acquisition of nutrients by roots was reduced, resulting in lower concentrations of anions and cations in the PRI than in the DI treatment. It is therefore essential that the soil water content in the wet zone should be maintained relatively high while that in the drying soil zone should not be very low, both conditions are crucial to maintain high soil and plant water status while sustaining ABA signalling of the plants.

  2. Comparative effects of deficit irrigation and alternate partial root-zone irrigation on xylem pH, ABA and ionic concentrations in tomatoes.

    PubMed

    Wang, Yaosheng; Liu, Fulai; Jensen, Christian Richardt

    2012-03-01

    Comparative effects of partial root-zone irrigation (PRI) and deficit irrigation (DI) on xylem pH, ABA, and ionic concentrations of tomato (Lycopersicon esculentum L.) plants were investigated in two split-root pot experiments. Results showed that PRI plants had similar or significantly higher xylem pH, which was increased by 0.2 units relative to DI plants. Nitrate and total ionic concentrations (cations+anions), and the proportion of cations influenced xylem pH such that xylem pH increases as nitrate and total ionic concentrations decrease, and the proportion of cations increases. In most cases, the xylem ABA concentration was similar for PRI and DI plants, and a clear association between increases in xylem pH with increasing xylem ABA concentration was only found when the soil water content was relatively low. The concentrations of anions, cations, and the sum of anions and cations in PRI were higher than in the DI treatment when soil water content was relatively high in the wetted soil compartment. However, when water content in both soil compartments of the PRI pots were very low before the next irrigation, the acquisition of nutrients by roots was reduced, resulting in lower concentrations of anions and cations in the PRI than in the DI treatment. It is therefore essential that the soil water content in the wet zone should be maintained relatively high while that in the drying soil zone should not be very low, both conditions are crucial to maintain high soil and plant water status while sustaining ABA signalling of the plants. PMID:22162869

  3. The influence of partial timber harvest in riparian management zones on macroinvertebrate and fish communities on first- and second-order streams in northern Minnesota

    USGS Publications Warehouse

    Chizinski, Christopher J.; Vondracek, Bruce C.; Blinn, Charles R.; Newman, Raymond M.; Atuke, Dickson M.; Fredricks, Keith; Hemstad, Nathaniel A.; Merten, Eric; Schlesser, Nicholas

    2010-01-01

    Relatively few evaluations of aquatic macroinvertebrate and fish communities have been published in peer-reviewed literature detailing the effect of varying residual basal area (RBA) after timber harvesting in riparian buffers. Our analysis investigated the effects of partial harvesting within riparian buffers on aquatic macroinvertebrate and fish communities in small streams from two experiments in northern Minnesota northern hardwood-aspen forests. Each experiment evaluated partial harvesting within riparian buffers. In both experiments, benthic macroinvertebrates and fish were collected 1 year prior to harvest and in each of 3 years after harvest. We observed interannual variation for the macroinvertebrate abundance, diversity and taxon richness in the single-basin study and abundance and diversity in the multiple-basin study, but few effects related to harvest treatments in either study. However, interannual variation was not evident in the fish communities and we detected no significant changes in the stream fish communities associated with partially harvested riparian buffers in either study. This would suggest that timber harvesting in riparian management zones along reaches ≤200 m in length on both sides of the stream that retains RBA ≥ 12.4 ± 1.3 m2 ha−1 or on a single side of the stream that retains RBA ≥ 8.7 ± 1.6 m2 ha−1 may be adequate to protect macroinvertebrate and fish communities in our Minnesota study systems given these specific timber harvesting techniques.

  4. Partial root zone drying: regulation of photosynthetic limitations and antioxidant enzymatic activities in young olive (Olea europaea) saplings.

    PubMed

    Aganchich, Badia; Wahbi, Said; Loreto, Francesco; Centritto, Mauro

    2009-05-01

    The effect of partial root drying (PRD) irrigation on split-root olive (Olea europaea L. cv Picholine marocaine) saplings was investigated. An irrigated control and two PRD regimes were applied (control: irrigation applied on both sides of the root system to keep the soil water content close to field capacity; PRD(50): irrigation applied at 50% of the control amount on one side of the root system and irrigation withheld from the other side, with irrigation regimes switched between the sides of the root system every 2 weeks; and PRD(100): irrigation applied at 100% of the control amount on one side and irrigation withheld on the other side, with irrigation regimes switched between the sides of the root system every 2 weeks. Only saplings in the PRD(50) regime were subjected to water-deficit irrigation. The PRD treatments significantly affected water relations and vegetative growth throughout the growing season. Predawn leaf water potential and relative water content differed significantly between the PRD(50) and PRD(100) saplings, leading to reduced stomatal conductance, carbon assimilation, shoot length and leaf number in PRD(50) saplings. However, the PRD(50) water-deficit treatment did not affect the capacity of the saplings to assimilate CO(2). Activities of superoxide dismutase, soluble and insoluble peroxidase (POX) and polyphenol oxidase were up-regulated by the PRD(50) and PRD(100) treatments compared with control values. The higher activities of both soluble and insoluble POX observed in PRD(50) saplings may reflect the greater inhibitory effect of this treatment on vegetative growth. Up-regulation of the detoxifying systems in the PRD(100) and PRD(50) saplings may have provided protection mechanisms against irreversible damage to the photosynthetic machinery, thereby allowing the photosynthetic apparatus to function and preventing the development of severe water stress. We also measured CO(2) assimilation rate/internal leaf CO(2) concentration (A

  5. Melt electrospinning.

    PubMed

    Hutmacher, Dietmar W; Dalton, Paul D

    2011-01-01

    Melt electrospinning is relatively under-investigated compared to solution electrospinning but provides opportunities in numerous areas, in which solvent accumulation or toxicity are a concern. These applications are diverse, and provide a broad set of challenges to researchers involved in electrospinning. In this context, melt electrospinning provides an alternative approach that bypasses some challenges to solution electrospinning, while bringing new issues to the forefront, such as the thermal stability of polymers. This Focus Review describes the literature on melt electrospinning, as well as highlighting areas where both melt and solution are combined, and potentially merge together in the future.

  6. Effect of Mantle Wedge Hybridization by Sediment Melt on Geochemistry of Arc Magma and Arc Mantle Source - Insights from Laboratory Experiments at High Pressures and Temperatures

    NASA Astrophysics Data System (ADS)

    Mallik, A.; Dasgupta, R.; Tsuno, K.; Nelson, J. M.

    2015-12-01

    Generation of arc magmas involves metasomatism of the mantle wedge by slab-derived H2O-rich fluids and/or melts and subsequent melting of the modified source. The chemistry of arc magmas and the residual mantle wedge are not only regulated by the chemistry of the slab input, but also by the phase relations of metasomatism or hybridization process in the wedge. The sediment-derived silica-rich fluids and hydrous partial melts create orthopyroxene-rich zones in the mantle wedge, due to reaction of mantle olivine with silica in the fluid/melt [1,2]. Geochemical evidence for such a reaction comes from pyroxenitic lithologies coexisting with peridotite in supra-subduction zones. In this study, we have simulated the partial melting of a parcel of mantle wedge modified by bulk addition of sediment-derived melt with variable H2O contents to investigate the major and trace element chemistry of the magmas and the residues formed by this process. Experiments at 2-3 GPa and 1150-1300 °C were conducted on mixtures of 25% sediment-derived melt and 75% lherzolite, with bulk H2O contents varying from 2 to 6 wt.%. Partial reactive crystallization of the rhyolitic slab-derived melt and partial melting of the mixed source produced a range of melt compositions from ultra-K basanites to basaltic andesites, in equilibrium with an orthopyroxene ± phlogopite ± clinopyroxene ± garnet bearing residue, depending on P and bulk H2O content. Model calculations using partition coefficients (from literature) of trace elements between experimental minerals and silicate melt suggest that the geochemical signatures of the slab-derived melt, such as low Ce/Pb and depletion in Nb and Ta (characteristic slab signatures) are not erased from the resulting melt owing to reactive crystallization. The residual mineral assemblage is also found to be similar to the supra-subduction zone lithologies, such as those found in Dabie Shan (China) and Sanbagawa Belt (Japan). In this presentation, we will also

  7. Seismic evidence for silicate melt atop the 410-km mantle discontinuity

    USGS Publications Warehouse

    Revenaugh, Justin; Sipkin, S.A.

    1994-01-01

    LABORATORY results demonstrating that basic to ultrabasic melts become denser than olivine-rich mantle at pressures above 6 GPa (refs 1-3) have important implications for basalt petrogenesis, mantle differentiation and the storage of volatiles deep in the Earth. A density cross-over between melt and solid in the extensively molten Archaean mantle has been inferred from komatiitic volcanism and major-element mass balances, but present-day evidence of dense melt below the seismic low-velocity zone is lacking. Here we present mantle shear-wave impedance profiles obtained from multiple-ScS reverberation mapping for corridors connecting western Pacific subduction zone earthquakes with digital seismograph stations in eastern China, imaging a ~5.8% impedance decrease roughly 330 km beneath the Sea of Japan, Yellow Sea and easternmost Asia. We propose that this represents the upper surface of a layer of negatively buoyant melt lying on top of the olivine ??? ??- phase transition (the 410-km seismic discontinuity). Volatile-rich fluids expelled from the partial melt zone as it freezes may migrate upwards, acting as metasomatic agents and perhaps as the deep 'proto-source' of kimberlites. The remaining, dense, crystalline fraction would then concentrate above 410 km, producing a garnet-rich layer that may flush into the transition zone.

  8. Seismological detection of "730-km" discontinuity beneath Japan subduction zone

    NASA Astrophysics Data System (ADS)

    Liu, Z.; Park, J. J.; Karato, S. I.

    2015-12-01

    Because the mantle transition zone likely contains a large amount of water (Karato, 2011; Pearson et al., 2014), vertical material transport across the transition would cause partial melting that may produce seismic signals above and/or below the transition zone. Schmandt et al. (2014) observed a seismic low-velocity zone (LVZ) at the top of the lower mantle (~730 km) beneath the southwestern US, arguing for dehydration melting due to downward flow across the 670-km discontinuity (670) from the transition zone. These authors further proposed a correlation between seismic velocity reductions and the direction of water transport, in which LVZ at ~730 km indicates materials moving downward from the transition zone, while the lack of LVZ at this depth would suggest an upward flow of mantle materials. Other regions also need to be investigated to confirm the correlation between this seismic feature and mantle water transport. We test their model by detecting "730-km" discontinuity beneath the Japan subduction zone using frequency-dependent receiver functions. In addition, water transport above the 410-km discontinuity (410) also plays an important role in global water circulation (Bercovici and Karato, 2003). Seismological studies (e.g. Courtier and Revenaugh, 2007; Schaeffer and Bostock, 2010) have observed LVZs above the 410, which might be caused by dehydration melting due to the upwelling of hydrated materials across the 410-km discontinuity from the transition zone. In this study, we also detect potential LVZs above 410 to establish a correlation between seismic velocity drop and flow direction. Around the Japan subduction zone, our preliminary results show evidence of low velocity zones below 670 in regions where stagnant slab is present for a substantial amount of time but not in other regions suggesting a variety of vertical mass transport in this region. Key words: transition zone, water transport, subduction zone, melting, receiver functions

  9. Comparative effect of partial root-zone drying and deficit irrigation on incidence of blossom-end rot in tomato under varied calcium rates.

    PubMed

    Sun, Yanqi; Feng, Hao; Liu, Fulai

    2013-04-01

    This study investigated the comparative effects of reduced irrigation regimes--partial root-zone drying (PRD) and conventional deficit irrigation (DI)--on the incidence of blossom-end rot (BER) in tomato (Solanum lycopersicum L.) under three Ca-fertilization rates: 0, 100, and 200mg Ca kg(-1) soil (denoted Ca0, Ca1, and Ca2, respectively). The plants were grown in split-root pots in a climate-controlled glasshouse and treated with PRD and DI during early flowering to the fruit maturity stage. The results showed that, in comparison with DI treatment, PRD significantly reduced BER incidence. A greater xylem sap abscisic acid concentration, lower stomatal conductance, and higher plant water status in the PRD in relation to the DI plants might have contributed to the increased fruit Ca uptake, and could have reduced BER development in tomato fruits. Therefore, under conditions with limited freshwater resources, application of PRD irrigation could be a promising approach for saving water and for preventing BER development in tomatoes.

  10. Comparative effect of partial root-zone drying and deficit irrigation on incidence of blossom-end rot in tomato under varied calcium rates.

    PubMed

    Sun, Yanqi; Feng, Hao; Liu, Fulai

    2013-04-01

    This study investigated the comparative effects of reduced irrigation regimes--partial root-zone drying (PRD) and conventional deficit irrigation (DI)--on the incidence of blossom-end rot (BER) in tomato (Solanum lycopersicum L.) under three Ca-fertilization rates: 0, 100, and 200mg Ca kg(-1) soil (denoted Ca0, Ca1, and Ca2, respectively). The plants were grown in split-root pots in a climate-controlled glasshouse and treated with PRD and DI during early flowering to the fruit maturity stage. The results showed that, in comparison with DI treatment, PRD significantly reduced BER incidence. A greater xylem sap abscisic acid concentration, lower stomatal conductance, and higher plant water status in the PRD in relation to the DI plants might have contributed to the increased fruit Ca uptake, and could have reduced BER development in tomato fruits. Therefore, under conditions with limited freshwater resources, application of PRD irrigation could be a promising approach for saving water and for preventing BER development in tomatoes. PMID:23530128

  11. Melt processing of Yb-123 tapes

    SciTech Connect

    Athur, S. P.; Balachandran, U.; Salama, K.

    2000-02-17

    The innovation of a simple, scalable process for manufacturing long-length conductors of HTS is essential to potential commercial applications such as power cables, magnets, and transformers. In this paper the authors demonstrate that melt processing of Yb-123 tapes made by the PIT route is an alternative to the coated conductor and Bi-2223 PIT tape fabrication techniques. Ag-clad Yb-123 tapes were fabricated by groove rolling and subsequently, melt processed in different oxygen partial pressures in a zone-melting furnace with a gradient of 140 C/cm. The transition temperatures measured were found to be around 81 K undermost processing conditions. EPMA of the tapes processed under different conditions show the 123 phase to be Ba deficient and Cu and Yb rich. Critical current was measured at various temperatures from 77 K to 4.2 K. The J{sub c} increased with decrease in pO{sub 2}. The highest I{sub c} obtained was 52 A at 4.2 K.

  12. Quantifying global melt flux and degassing rate from global mantle convection models with plate motion history

    NASA Astrophysics Data System (ADS)

    Li, M.; Black, B. A.; Zhong, S.; Manga, M.; Rudolph, M. L.; Olson, P.

    2015-12-01

    How does the Earth's deep mantle convection affect surface climate change? Volcanism in various geological settings, including mid-ocean ridges, volcanic arcs, rift zones and sites with intraplate volcanism, releases volatiles to Earth's surface. The amount and composition of these volatiles influence the evolution Earth's ocean, crust and atmosphere, which in turn control the evolution of the biosphere. While there are constraints of Earth's degassing from the geochemistry of samples in some localized regions, a quantification of the time evolution of degassing on a global scale remains largely unknown.In this study, we run geodynamical calculations with a full 3D spherical geometry to explore the amount of partial melting in the shallow part of Earth's mantle and implied degassing at a global scale. The plate motion history for the last 200 Ma or longer is employed as time-dependent velocity boundary condition for mantle flow. Using the temperature, pressure and composition in mantle convection models, we calculate the degree of partial melting in different geological settings. We show that the melt flux at mid-ocean ridges generally increases linearly with the speed of plates, with some perturbations due to changes of length of mid-ocean ridges. Generally, this melt flux is about 2-3 times in the past 200 million years than that of the present-day Earth. The present-day melt flux is ~20 km3/year, but this value reaches ~40 km3/year at about 80Ma, and ~60 km3/year at about 120-160Ma. Given estimates of volatile content in the source regions where partial melting occurs and the melt flux we calculate, we quantify the evolution of degassing rate (of CO2) at mid-ocean ridges, hotspots, large igneous provinces, and subduction zones.

  13. Distribution of melt beneath Mount St Helens and Mount Adams inferred from magnetotelluric data

    USGS Publications Warehouse

    Hill, G.J.; Caldwell, T.G.; Heise, W.; Chertkoff, D.G.; Bibby, H.M.; Burgess, M.K.; Cull, J.P.; Cas, Ray A.F.

    2009-01-01

    Three prominent volcanoes that form part of the Cascade mountain range in Washington State (USA)Mounts StHelens, Adams and Rainierare located on the margins of a mid-crustal zone of high electrical conductivity1,5. Interconnected melt can increase the bulk conductivity of the region containing the melt6,7, which leads us to propose that the anomalous conductivity in this region is due to partial melt associated with the volcanism. Here we test this hypothesis by using magnetotelluric data recorded at a network of 85 locations in the area of the high-conductivity anomaly. Our data reveal that a localized zone of high conductivity beneath thisvolcano extends downwards to join the mid-crustal conductor. As our measurements were made during the recent period of lava extrusion at Mount St Helens, we infer that the conductivity anomaly associated with the localized zone, and by extension with the mid-crustal conductor, is caused by the presence of partial melt. Our interpretation is consistent with the crustal origin of silicic magmas erupting from Mount St Helens8, and explains the distribution of seismicity observed at the time of the catastrophic eruption in 1980 (refs9, 10). ?? 2009 Macmillan Publishers Limited. All rights reserved.

  14. Constraints on the Nature of Terrestrial Core-Forming Melts: Ultra-High Pressure Transport Property Measurements and X-Ray Computed Tomography Final Report

    SciTech Connect

    Roberts, J J; Kinney, J H; Ryerson, F J

    2006-01-20

    A key issue in models of planetary core formation is the interconnectness and potential percolation of iron-sulfide melts in contact with silicates at high temperature and pressure. To address this issue an integrated study of the electrical conductivity-texture-permeability relationships of olivine-sulfide partial-melt samples was performed. This work has application to the interpretation of high conductivity zones in the Earth as revealed by electromagnetic studies and to the origin and development of the Earth's core. The project consisted of three main tasks. (1) Synthesis and characterization of olivine-sulfide partial-melts. (2) Electrical conductivity measurements of the partial-melt and the individual melt and crystalline phases. (3) X-ray microtomographic determination of the 3-D structure and interconnectedness of the melt phase. The results are used to determine a model of permeability of a partially molten solid that incorporates the melt distribution, a goal that has never before been achieved. Material synthesis was accomplished in the piston cylinder apparatus and electrical conductivity measurements were performed at one atmosphere. X-ray computed tomography was performed on recovered samples at the ALS. This work makes use of and further enhances LLNL's strengths in high-pressure material properties, x-ray micro- and nanoscale imaging and development of transport theory.

  15. Crustal growth in subduction zones

    NASA Astrophysics Data System (ADS)

    Vogt, Katharina; Castro, Antonio; Gerya, Taras

    2015-04-01

    There is a broad interest in understanding the physical principles leading to arc magmatisim at active continental margins and different mechanisms have been proposed to account for the composition and evolution of the continental crust. It is widely accepted that water released from the subducting plate lowers the melting temperature of the overlying mantle allowing for "flux melting" of the hydrated mantle. However, relamination of subducted crustal material to the base of the continental crust has been recently suggested to account for the growth and composition of the continental crust. We use petrological-thermo-mechanical models of active subduction zones to demonstrate that subduction of crustal material to sublithospheric depth may result in the formation of a tectonic rock mélange composed of basalt, sediment and hydrated /serpentinized mantle. This rock mélange may evolve into a partially molten diapir at asthenospheric depth and rise through the mantle because of its intrinsic buoyancy prior to emplacement at crustal levels (relamination). This process can be episodic and long-lived, forming successive diapirs that represent multiple magma pulses. Recent laboratory experiments of Castro et al. (2013) have demonstrated that reactions between these crustal components (i.e. basalt and sediment) produce andesitic melt typical for rocks of the continental crust. However, melt derived from a composite diapir will inherit the geochemical characteristics of its source and show distinct temporal variations of radiogenic isotopes based on the proportions of basalt and sediment in the source (Vogt et al., 2013). Hence, partial melting of a composite diapir is expected to produce melt with a constant major element composition, but substantial changes in terms of radiogenic isotopes. However, crustal growth at active continental margins may also involve accretionary processes by which new material is added to the continental crust. Oceanic plateaus and other

  16. Zone Refining by Laser

    NASA Technical Reports Server (NTRS)

    Griner, D. B.

    1986-01-01

    System developed for studying use of laser beam for zone-refining semiconductors and metals. Specimen scanned with focused CO2 laser beam in such way that thin zone of molten material moves along specimen sweeps impurities with it. Zone-melting system comprises microcomputer, laser, electromechanical and optical components for beam control, vacuum chamber that holds specimen, and sensor for determining specimen temperature.

  17. On the occurrence and implications of Jurassic primary continental boninite-like melts in the Zagros orogen

    NASA Astrophysics Data System (ADS)

    Esna-Ashari, A.; Tiepolo, M.; Hassanzadeh, J.

    2016-08-01

    Ultramafic rocks, ranging from pyroxenites to hornblendites, are associated with granitoids of the Aligoodarz intrusive complex in the central Sanandaj-Sirjan Zone, representing the Mesozoic continental arc segment of the Zagros orogen. As inferred from the ultramafic whole rock composition and the most primitive clinopyroxene composition in pyroxenites, the geochemical signature of primary melt is significantly different from that of the continental arc basalts. In particular, primary melt is characterized by extremely low concentrations of incompatible elements and high concentrations of Mg and refractory elements typical of boninites. Amphibole is a late crystallizing mineral in these rocks and is in textural and chemical disequilibrium with olivine + orthopyroxene + clinopyroxene. Amphibole crystallized from a liquid underwent differentiation through a process of melt-rock reaction. In particular, early differentiated boninitic cumulates reacted with later melts with a strong crustal signature similar to Aligoodarz granodiorite. Usbnd Pb zircon geochronology from ultramafic rocks and surrounding quartz-diorite yield similar ages and indicate that they are coeval with Aligoodarz granitoids (ca. 165-170 Ma). However, the occurrence of a marked negative Eu anomaly in zircon from the ultramafic rocks, which is absent in the boninitic primary melt, indicates that zircons crystallized from the infiltrating melt and in turn date the timing of melt infiltration. The interaction between ultramafic cumulates and infiltrated melt has generated a new liquid compositionally similar to high-Mg andesites and to the quartz-diorites hosting the ultramafic cumulates. The scenario that better account for the genesis of boninitic melts in the Sanandaj-Sirjan Zone is partial melting of a depleted mantle wedge in response to the onset of NeoTethys subduction. According to this hypothesis, middle Jurassic calc-alkaline magmatism in the Sanandaj-Sirjan Zone represents the mature stage

  18. Re-Os isotope studies of Mindanao adakites: Implications for sources of metals and melts

    NASA Astrophysics Data System (ADS)

    Dreher, Scott T.; MacPherson, Colin G.; Pearson, D. Graham; Davidson, Jon P.

    2005-12-01

    Whether the downgoing slab in modern subduction zones is able to melt is an important unresolved aspect of plate tectonics. Rare arc lavas with high Sr/Y ratios and low Y and heavy rare earth element concentrations, called adakites, are often attributed to melting of young subducted crust in subduction zones. Osmium isotopic data obtained for 13 adakite samples from Mindanao, Philippines, conflict with the slab-melting model. Ten of the samples have unradiogenic 187Os/188Os ratios inconsistent with partial melting of the ca. 50 Ma Philippine Sea lithosphere subducting beneath Mindanao. The Os isotope signatures are similar to those of young mid-oceanic-ridge basalts and normal arc rocks, consistent with a mantle source. In addition to implications for mass transfer in subduction zones, the apparent association of adakites with Cu-Au deposits makes understanding their origin, and that of the associated metals, economically interesting. This study suggests that a reevaluation is required of the slab-melting hypothesis in general, and that the metals associated with the Mindanao adakites come from the mantle.

  19. Melting processes under microgravity conditions

    NASA Astrophysics Data System (ADS)

    Glicksman, M.; Lupulescu, A.; Koss, M.

    The Rensselaer Isothermal Dendritic Growth Experiment (RIDGE) uses the large data archive amassed through a series of three NASA-supported microgravity experiments (IDGE/USMP-2, -3, and -4), all of which flew aboard the space shuttle Columbia. The IDGE instruments aboard USMP-2 and -3 provided in-flight CCD images, and 35-mm films (postflight). USMP-4 also allowed streaming of near-real-time video. Using 30 fps video data, it became possible for the first time to study both freezing and melting sequences for high-purity pivalic acid (PVA). We report on the melting process observed for PVA crystal fragments, observed under nearly ideal convection-free conditions. Conduction-limited melting processes are of importance in orbital melting of materials, meteoritic genesis, mushy-zone evolution, and in fusion weld pools where length scales for thermal buoyancy are restricted. Microgravity video show clearly that PVA dendrites melt into fragments that shrink at accelerating rates to extinction. The melting paths of individual fragments follow characteristic time dependences derived from theory. The theoretical melting kinetics against which the experimental observations are carefully compared is based on conduction-limited quasi-static melting under shape-preserving conditions. Good agreement between theory and experiment is found for the stable melting of needle-shaped prolate spheroidal PVA crystal fragments with aspect ratios near C /A = 12.

  20. Alternate partial root-zone irrigation reduces bundle-sheath cell leakage to CO2 and enhances photosynthetic capacity in maize leaves.

    PubMed

    Wang, Zhenchang; Kang, Shaozhong; Jensen, Christian R; Liu, Fulai

    2012-02-01

    The physiological basis for the advantage of alternate partial root-zone irrigation (PRI) over common deficit irrigation (DI) in improving crop water use efficiency (WUE) remains largely elusive. Here leaf gas exchange characteristics and photosynthetic CO(2)-response and light-response curves for maize (Zea mays L.) leaves exposed to PRI and DI were analysed under three N-fertilization rates, namely 75, 150, and 300 mg N kg(-1) soil. Measurements of net photosynthetic rate (A(n)) and stomatal conductance (g(s)) showed that, across the three N-fertilization rates, the intrinsic WUE was significantly higher in PRI than in DI leaves. Analysis of the CO(2)-response curve revealed that both carboxylation efficiency (CE) and the CO(2)-saturated photosynthetic rate (A(sat)) were significantly higher in PRI than in DI leaves across the three N-fertilization rates; whereas the N-fertilization rates did not influence the shape of the curves. The enhanced CE and A(sat) in the PRI leaves was accompanied by significant decreases in carbon isotope discrimination (Δ(13)C) and bundle-sheath cell leakiness to CO(2) (Φ). Analysis of the light-response curve indicated that, across the three N-fertilization rates, the quantum yield (α) and light-saturated gross photosynthetic rate (A(max)) were identical for the two irrigation treatments; whilst the convexity (κ) of the curve was significantly greater in PRI than in DI leaves, which coincided with the greater CE and A(sat) derived from the CO(2)-response curve at a photosynthetic photon flux density of 1500 μmol m(-2) s(-1). Collectively, the results suggest that, in comparison with the DI treatment, PRI improves photosynthetic capacity parameters CE, A(sat), and κ of maize leaves and that contributes to the greater intrinsic WUE in those plants.

  1. Physiological responses of potato (Solanum tuberosum L.) to partial root-zone drying: ABA signalling, leaf gas exchange, and water use efficiency.

    PubMed

    Liu, Fulai; Shahnazari, Ali; Andersen, Mathias N; Jacobsen, Sven-Erik; Jensen, Christian R

    2006-01-01

    The physiological responses of potato (Solanum tuberosum L. cv. Folva) to partial root-zone drying (PRD) were investigated in potted plants in a greenhouse (GH) and in plants grown in the field under an automatic rain-out-shelter. In the GH, irrigation was applied daily to the whole root system (FI), or to one-half of the root system while the other half was dried, for 9 d. In the field, the plants were drip irrigated either to the whole root system near field capacity (FI) or using 70% water of FI to one side of the roots, and shifted to the other side every 5-10 d (PRD). PRD plants had a similar midday leaf water potential to that of FI, whereas in the GH their root water potential (Psi(r)) was significantly lowered after 5 d. Stomatal conductance (g(s)) was more sensitive to PRD than photosynthesis (A) particularly in the field, leading to greater intrinsic water use efficiency (WUE) (i.e. A/g(s)) in PRD than in FI plants on several days. In PRD, the xylem sap abscisic acid concentration ([ABA](xylem)) increased exponentially with decreasing Psi(r); and the relative [ABA](xylem) (PRD/FI) increased exponentially as the fraction of transpirable soil water (FTSW) in the drying side decreased. In the field, the leaf area index was slightly less in PRD than in FI treatment, while tuber biomass was similar for the two treatments. Compared with FI, PRD treatment saved 30% water and increased crop water use efficiency (WUE) by 59%. Restrictions on leaf area expansion and g(s) by PRD-induced ABA signals might have contributed to reduced water use and increased WUE.

  2. Melting in migmatites associated with sub-grain boundaries in quartz

    NASA Astrophysics Data System (ADS)

    Levine, J.; Mosher, S.

    2010-12-01

    Migmatites from three diverse locations and rock types contain pseudomorphs of melt along sub-grain and grain boundaries, particularly in quartz. This relationship suggests melting preferentially occurs in more strained areas of a crystal lattice, consistent with observations from metallurgy and material science. In metals, ceramics and colloids, it has been demonstrated that melting preferentially occurs on grain boundaries, areas of high dislocation density, and that melting begins in areas that are more highly strained. Molecular dynamics simulations and experiments on colloids show that melting will also occur along sub-grain boundaries if there are no true grain boundaries present. A process known as SIMA (strain-induced melt activation) has been used on Al alloys to create a spherical grain shape, utilizing the fact that melt will preferentially form in high-strain areas, including both grain and sub-grain boundaries. In migmatites, previous work indicates that melt travels along grain boundaries as well as fractures within grains. Experimental work and identification of remnant blebs or pseudomorphs of melt along grain boundaries in natural rocks provides evidence for such transport. Our study of deformed rocks from three areas provides new evidence for melting as well as transport along sub-grain boundaries, particularly in quartz. Granitic gneiss samples from the Llano Uplift, central Texas, are from small-scale shear zones and surrounding country rock. The quartz/K-feldspar grain boundaries commonly have cuspate/serrate edges that are associated with sub-grain boundaries in quartz, and blebs of K-feldspar are found along sub-grain boundaries within quartz grains. The K-feldspar most likely represents pseudomorphs of melt that have migrated into and melted the quartz grain along quartz sub-grain boundaries, creating space for the crystallizing melt. Metapelites from the Wet Mountains of south-central Colorado have undergone partial melting via biotite

  3. Compositional zoning in high-silica rhyolite tuffs

    NASA Astrophysics Data System (ADS)

    Wolff, J. A.; Ramos, F. C.; Olin, P. H.

    2012-12-01

    The mush model for silicic magma systems predicts the development of a supernatant crystal-poor melt lens overlying rheologically static crystal mush following roughly 50% crystallization of an initially well-stirred magma body. It does not immediately explain the origin of strong chemical zonation in large bodies of crystal-poor high-silica rhyolite magma exemplified by the Bishop Tuff and Bandelier Tuff. Concentrations of incompatible trace elements in pumice clasts from the first-erupted portion of the 1.60 Ma Otowi Member of the Bandelier Tuff, Valles Caldera, NM, are up 4 times those in late-erupted pumice, seemingly requiring 75% crystallization. Early/late element enrichments and depletions in the Otowi are indeed predicted by fractionation of the observed phenocryst assemblage. However, the Otowi Member also exhibits a strong gradient in Sr isotopes and, in late-erupted pumices, reverse zoning of sanidine and feldspar phenocrysts and micro-scale variations in glass chemistry that lie off the trend for the whole tuff. Zoning is not simply the result of recharge and mixing with more mafic magma because Sr concentrations are typically very low (<5 ppm) throughout the the zoned sequence and not all element pairs exhibit linear co-variation. These apparently conflicting observations are reconciled by a model in which the static mush layer beneath the crystal-poor melt lens is repeatedly partially melted by recharging magma. The regenerated melt is indistinguishable in major element composition from the intial melt lens but is depleted in incompatible trace elements. It is also more dense than the original melt lens because it has been produced by melting of anhydrous phases (sanidine + quartz). Consequently, the new melt pools at the interface of the non-eruptible mush pile and the original melt lens to produce an eruptible, compositionally zoned crystal-poor rhyolitic liquid. The whole compositional range of original melt + remelted crystal residue duplicates

  4. Mineralogy, Petrology, Chemistry, and Ar-39 - Ar-40 and Ages of the Caddo County IAB Iron: Evidence for Early Partial Melt Segregation of a Gabbro Area Rich in Plagioclase-Diopside

    NASA Technical Reports Server (NTRS)

    Takeda, Hiroshi; Bogard, Donald D.; Mittlefehldt, David W.; Garrison, Daniel H.

    2000-01-01

    We found coarse-grained gabbroic material rich in plagioclase and diopside in the Caddo County IAB iron meteorite. The polished thin sections studied were made from areas rich in Al and Ca detected by a micro-focus X-ray fluorescence (XRF) mapping technique. The gabbro is not a clast within a breccia, but rather this area is located mainly at silicate-metal boundaries only a few cm away from an area with fine-grained, ultramafic silicate similar to winonaites. Medium-grained orthopyroxene and olivine are found in transitional areas showing no disturbance of their crystalline textures. A vein-like region, starting at the area rich in fine-grained mafic silicate, extends towards the gabbroic area with a gradual increase in abundance of plagioclase and diopside. This texture and our accumulated knowledge of the formation mechanism of IAB/winonaltes meteorites, suggest that the gabbroic materials were formed by inhomogeneous segregation of partial melts of chondritic source materials. Compositional data on two mineralogically distinct samples of the gabbro-rich portion of the inclusion were obtained by INAA. Compared to an average of LAB silicate inclusions or winonaites, the Caddo County gabbro is enriched in the incompatible lithophile elements Na, Ca, Sc, REE and Hf, which is consistent with a melt origin for the gabbro. The cosmogenic space exposure age of Caddo County (511 Ma) is significantly younger than exposure ages of some other IAB meteorites, An 39Ar-40Ar age determination of the gabbroic material indicates a series of upward steps in age from 4.516 Ga to 4.523 Ga, with a few high temperature ages up to 4.54 Ga. The older age could approximate the primary recrystallization age of silicates. The stepped Ar age spectrum may indicate differences in Ar closure temperatures during slow cooling of -2-20'C/Myr in the parent body. Alternatively, the younger Ar-Ar ages may date a shock event which occurred while Caddo County was hot and which also created textures

  5. Evaluating the effects of stress-driven segregation, strain and reaction history, and intrinsic rock properties on melt transport and rock rheology in the naturally deformed lithosphere

    NASA Astrophysics Data System (ADS)

    Kruckenberg, S. C.; Tikoff, B.

    2012-12-01

    geometries that differ from patterns predicted by numerical and experimental studies of stress-driven melt segregation. Dunite melt bands in low strain regions of the Twin Sisters complex typically form high angle conjugate geometries, but in highly deformed portions of the host peridotites their geometries systematically become more subparallel. Structural and textural observations suggest that melt flow was contemporaneous with deformation and therefore the organization of the reactive melt flow network was dynamically linked to the magnitude of viscous strain and localization phenomena in the host peridotites. These observations underscore the importance of field, microstructural, and textural studies in tectonic systems that experienced the sequential or coeval effects of melt extraction, migration or accumulation (e.g., migmatite-granite complexes). The permeability of melt flow networks, the distribution of melt and melt connectivity in the orogenic crust, and the timing of partial melting relative to deformation, all affect the efficiency of melt transfer in the lithosphere. The rheological evolution of partially molten rocks further significantly affects the ability of the melt-rich crust to mobilize into zones of active deformation, such as during the formation of migmatite domes (e.g., the Naxos dome, Greece).

  6. Composition and origin of rhyolite melt intersected by drilling in the Krafla geothermal field, Iceland

    USGS Publications Warehouse

    Zierenberg, R.A.; Schiffman, P.; Barfod, G.H.; Lesher, C.E.; Marks, N.E.; Lowenstern, Jacob B.; Mortensen, A.K.; Pope, E.C.; Bird, D.K.; Reed, M.H.; Friðleifsson, G.O.; Elders, W.A.

    2013-01-01

    The Iceland Deep Drilling Project Well 1 was designed as a 4- to 5-km-deep exploration well with the goal of intercepting supercritical hydrothermal fluids in the Krafla geothermal field, Iceland. The well unexpectedly drilled into a high-silica (76.5 % SiO2) rhyolite melt at approximately 2.1 km. Some of the melt vesiculated while extruding into the drill hole, but most of the recovered cuttings are quenched sparsely phyric, vesicle-poor glass. The phenocryst assemblage is comprised of titanomagnetite, plagioclase, augite, and pigeonite. Compositional zoning in plagioclase and exsolution lamellae in augite and pigeonite record changing crystallization conditions as the melt migrated to its present depth of emplacement. The in situ temperature of the melt is estimated to be between 850 and 920 °C based on two-pyroxene geothermometry and modeling of the crystallization sequence. Volatile content of the glass indicated partial degassing at an in situ pressure that is above hydrostatic (~16 MPa) and below lithostatic (~55 MPa). The major element and minor element composition of the melt are consistent with an origin by partial melting of hydrothermally altered basaltic crust at depth, similar to rhyolite erupted within the Krafla Caldera. Chondrite-normalized REE concentrations show strong light REE enrichment and relative flat patterns with negative Eu anomaly. Strontium isotope values (0.70328) are consistent with mantle-derived melt, but oxygen and hydrogen isotope values are depleted (3.1 and −118 ‰, respectively) relative to mantle values. The hydrogen isotope values overlap those of hydrothermal epidote from rocks altered by the meteoric-water-recharged Krafla geothermal system. The rhyolite melt was emplaced into and has reacted with a felsic intrusive suite that has nearly identical composition. The felsite is composed of quartz, alkali feldspar, plagioclase, titanomagnetite, and augite. Emplacement of the rhyolite magma has resulted in partial melting of

  7. Growth of Si Bulk Crystals with Large Diameter Ratio Using Small Crucibles by Creating a Large Low-Temperature Region Inside a Si Melt Contained in an NOC Furnace Developed Using Two Zone Heaters

    NASA Astrophysics Data System (ADS)

    Nakajima, Kazuo; Ono, Satoshi; Murai, Ryota; Kaneko, Yuzuru

    2016-06-01

    Three zone heaters were generally used for a noncontact crucible (NOC) furnace. For practical reasons a simpler NOC furnace was developed with two zone heaters, which had a carbon heat holder to cover the three roles of each heater. Large low-temperature regions were obtained, and silicon ingots were grown in small crucibles with a large diameter and diameter ratio. Here, the diameter ratio is the ratio of the ingot diameter to the crucible diameter and can be as large as 0.90. The diameter ratio was controlled mainly by the temperature reduction of the first heater. Power changes of the second heater did not have a significant impact on the ingot diameter. Using this NOC furnace, maximum ingot diameters of 28.0, 33.5, and 45.0 cm were obtained using crucibles of 33, 40, and 50 cm in diameter, respectively. The oxygen concentration of the ingots did not strongly depend on the diameter ratio and were always low because convection in the Si melt was markedly suppressed by the carbon heat holder. Moreover, the oxygen concentration of the ingots has a tendency to become lower as the crucible diameter becomes larger.

  8. Rapid hydrothermal cooling above the axial melt lens at fast-spreading mid-ocean ridge

    PubMed Central

    Zhang, Chao; Koepke, Juergen; Kirchner, Clemens; Götze, Niko; Behrens, Harald

    2014-01-01

    Axial melt lenses sandwiched between the lower oceanic crust and the sheeted dike sequences at fast-spreading mid-ocean ridges are assumed to be the major magma source of oceanic crust accretion. According to the widely discussed “gabbro glacier” model, the formation of the lower oceanic crust requires efficient cooling of the axial melt lens, leading to partial crystallization and crystal-melt mush subsiding down to lower crust. These processes are believed to be controlled by periodical magma replenishment and hydrothermal circulation above the melt lens. Here we quantify the cooling rate above melt lens using chemical zoning of plagioclase from hornfelsic recrystallized sheeted dikes drilled from the East Pacific at the Integrated Ocean Drilling Program Hole 1256D. We estimate the cooling rate using a forward modelling approach based on CaAl-NaSi interdiffusion in plagioclase. The results show that cooling from the peak thermal overprint at 1000–1050°C to 600°C are yielded within about 10–30 years as a result of hydrothermal circulation above melt lens during magma starvation. The estimated rapid hydrothermal cooling explains how the effective heat extraction from melt lens is achieved at fast-spreading mid-ocean ridges. PMID:25209311

  9. Rapid hydrothermal cooling above the axial melt lens at fast-spreading mid-ocean ridge.

    PubMed

    Zhang, Chao; Koepke, Juergen; Kirchner, Clemens; Götze, Niko; Behrens, Harald

    2014-09-11

    Axial melt lenses sandwiched between the lower oceanic crust and the sheeted dike sequences at fast-spreading mid-ocean ridges are assumed to be the major magma source of oceanic crust accretion. According to the widely discussed "gabbro glacier" model, the formation of the lower oceanic crust requires efficient cooling of the axial melt lens, leading to partial crystallization and crystal-melt mush subsiding down to lower crust. These processes are believed to be controlled by periodical magma replenishment and hydrothermal circulation above the melt lens. Here we quantify the cooling rate above melt lens using chemical zoning of plagioclase from hornfelsic recrystallized sheeted dikes drilled from the East Pacific at the Integrated Ocean Drilling Program Hole 1256D. We estimate the cooling rate using a forward modelling approach based on CaAl-NaSi interdiffusion in plagioclase. The results show that cooling from the peak thermal overprint at 1000-1050°C to 600°C are yielded within about 10-30 years as a result of hydrothermal circulation above melt lens during magma starvation. The estimated rapid hydrothermal cooling explains how the effective heat extraction from melt lens is achieved at fast-spreading mid-ocean ridges.

  10. Rapid hydrothermal cooling above the axial melt lens at fast-spreading mid-ocean ridge.

    PubMed

    Zhang, Chao; Koepke, Juergen; Kirchner, Clemens; Götze, Niko; Behrens, Harald

    2014-01-01

    Axial melt lenses sandwiched between the lower oceanic crust and the sheeted dike sequences at fast-spreading mid-ocean ridges are assumed to be the major magma source of oceanic crust accretion. According to the widely discussed "gabbro glacier" model, the formation of the lower oceanic crust requires efficient cooling of the axial melt lens, leading to partial crystallization and crystal-melt mush subsiding down to lower crust. These processes are believed to be controlled by periodical magma replenishment and hydrothermal circulation above the melt lens. Here we quantify the cooling rate above melt lens using chemical zoning of plagioclase from hornfelsic recrystallized sheeted dikes drilled from the East Pacific at the Integrated Ocean Drilling Program Hole 1256D. We estimate the cooling rate using a forward modelling approach based on CaAl-NaSi interdiffusion in plagioclase. The results show that cooling from the peak thermal overprint at 1000-1050°C to 600°C are yielded within about 10-30 years as a result of hydrothermal circulation above melt lens during magma starvation. The estimated rapid hydrothermal cooling explains how the effective heat extraction from melt lens is achieved at fast-spreading mid-ocean ridges. PMID:25209311

  11. Chemical Composition of Impact Glass and Suevite-Type Partial Melts of the Rab and Krk Islands and Their Relation with the Proposed Krk Impact Structure in Northern Adriatic, Croatia

    NASA Astrophysics Data System (ADS)

    Čalogović, M.; Marjanac, T.; Fazinić, S.; Strmić-Palinkaš, S.; Tomša, A. M.; Marjanac, L.

    2015-09-01

    Chemical composition of Krk impact structure ejecta represented by incomplete melts and glasses indicate affinity with Pleistocene loess as target lithology, and suggests Pleistocene age of the impact.

  12. Generation of Palaeoproterozoic tonalites and associated high-K granites in southwestern Tanzania by partial melting of underplated mafic crust in an intracontinental setting: Constraints from geochemical and isotopic data

    NASA Astrophysics Data System (ADS)

    Manya, Shukrani; Maboko, Makenya A. H.

    2016-09-01

    The southwestern part of the 2.0-1.8 Ga Palaeoproterozoic Usagaran Belt in the Njombe area of SW Tanzania is intruded by two types of synchronous granitic rocks with different chemical and petrological characteristics. The first type consists of hornblende-rich tonalites that have major element compositions similar to those of Archaean TTG but differ significantly in their trace element composition. The tonalites are spatially and closely associated with felsic, high-K, I-type granites, some of which are gneissic and/or aplitic. U-Pb zircon geochronology shows that the emplacement of tonalites at 1887 ± 11 Ma was largely contemporaneous with emplacement of high-K granitic gneisses at 1877 ± 15 Ma and aplitic granites at 1857 ± 19 Ma. The data also reveal the presence of Archaean crust of 2648 ± 25 Ma in the zircon cores of some samples in the otherwise Palaeoproterozoic terrane. The tonalites are characterized by MgO contents of 1.60-4.11 wt.% at a SiO2 range of 58.1-67.9 wt.%, the Mg# of 34-55, lower Sr contents (220-462 ppm) and less fractionated REE patterns (La/YbCN = 3.55-12.9) compared to Archaean TTG (Sr > 500 ppm, La/YbCN > 20). These features, coupled with the εNd (1887 Ma) values of + 0.37 to - 0.66 as well as the associated mafic enclaves are suggestive of derivation of the tonalites by low pressure (below the garnet stability) partial melting of a mantle-derived mafic underplate that was subsequently contaminated with small amounts of pre-existing igneous crustal rocks. The evolved nature of the high-K granites (MgO = 0.20-1.30 wt.%, SiO2 = 65.5-73.9 wt.%, Mg# = 25-42, εNd = - 3.20 to - 4.75) coupled with old TDM ages which are 200-1000 Ma older than their emplacement age requires a higher degree of assimilation of older crustal material by the magma derived from partial melting of the underplated mafic crust which was subsequently followed by crystal fractionation involving plagioclase, pyroxene and amphibole. The close spatial and temporal

  13. Enhanced performance of a three-zone simulated moving bed chromatography for separation of succinic acid and lactic acid by simultaneous use of port-location rearrangement and partial-feeding.

    PubMed

    Mun, Sungyong

    2014-07-11

    The performance of a three-zone simulated moving bed (SMB) chromatographic process for separation of succinic acid and lactic acid has been improved to a certain extent in previous researches by applying either a partial-feeding (PF) or a port-location rearrangement (PR) to its operation. To make a further improvement, the strategy of applying both PF and PR simultaneously to the three-zone SMB operation was proposed in this study. The results from both equilibrium-theory analysis and detailed simulation proved that the proposed strategy, which was called PF-PR in this article, had the benefit of a synergy between the individual merits of PF and PR in the three-zone SMB performance. As a consequence, the PF-PR mode could surpass the PF and the PR modes by a wide margin and the classical mode by a dramatic margin in the aspects of separation performance and throughput.

  14. Carbonatitic and granitic melts produced under conditions of primary immiscibility during anatexis in the lower crust

    NASA Astrophysics Data System (ADS)

    Ferrero, Silvio; Wunder, Bernd; Ziemann, Martin A.; Wälle, Markus; O'Brien, Patrick J.

    2016-11-01

    Carbonatites are peculiar magmatic rocks with mantle-related genesis, commonly interpreted as the products of melting of CO2-bearing peridotites, or resulting from the chemical evolution of mantle-derived magmas, either through extreme differentiation or secondary immiscibility. Here we report the first finding of anatectic carbonatites of crustal origin, preserved as calcite-rich polycrystalline inclusions in garnet from low-to-medium pressure migmatites of the Oberpfalz area, SW Bohemian Massif (Central Europe). These inclusions originally trapped a melt of calciocarbonatitic composition with a characteristic enrichment in Ba, Sr and LREE. This interpretation is supported by the results of a detailed microstructural and microchemical investigation, as well as re-melting experiments using a piston cylinder apparatus. Carbonatitic inclusions coexist in the same cluster with crystallized silicate melt inclusions (nanogranites) and COH fluid inclusions, suggesting conditions of primary immiscibility between two melts and a fluid during anatexis. The production of both carbonatitic and granitic melts during the same anatectic event requires a suitable heterogeneous protolith. This may be represented by a sedimentary sequence containing marble lenses of limited extension, similar to the one still visible in the adjacent central Moldanubian Zone. The presence of CO2-rich fluid inclusions suggests furthermore that high CO2 activity during anatexis may be required to stabilize a carbonate-rich melt in a silica-dominated system. This natural occurrence displays a remarkable similarity with experiments on carbonate-silicate melt immiscibility, where CO2 saturation is a condition commonly imposed. In conclusion, this study shows how the investigation of partial melting through melt inclusion studies may unveil unexpected processes whose evidence, while preserved in stiff minerals such as garnet, is completely obliterated in the rest of the rock due to metamorphic re

  15. Reactive transport in a partially molten system with binary solid solution

    NASA Astrophysics Data System (ADS)

    Jordan, Jacob S.; Hesse, Marc A.

    2015-12-01

    Melt extraction from the Earth's mantle through high-porosity channels is required to explain the composition of the oceanic crust. Feedbacks from reactive melt transport are thought to localize melt into a network of high-porosity channels. Recent studies invoke lithological heterogeneities in the Earth's mantle to seed the localization of partial melts. Therefore, it is necessary to understand the reaction fronts that form as melt flows across the lithological interface between the heterogeneity and the ambient mantle. Here we present a chromatographic analysis of reactive melt transport across lithological boundaries, using the theory of hyperbolic conservation laws. This is an extension of linear trace element chromatography to the coupling of major elements and energy transport. Our analysis allows the prediction of the nonlinear feedbacks that arise in reactive melt transport due to changes in porosity. This study considers the special case of a partially molten porous medium with binary solid solution. As melt traverses a lithological contact, binary solid solution leads to the formation of a reacted zone between an advancing reaction front and the initial contact. The analysis also shows that the behavior of a fertile heterogeneity depends on its absolute concentration, in addition to compositional differences between itself and the refractory background. We present a regime diagram that predicts if melt emanating from a fertile heterogeneity localizes into high-porosity channels or develops a zero porosity shell. The theoretical framework presented here provides a useful tool for understanding nonlinear feedbacks in reactive melt transport, because it can be extended to more complex and realistic phase behaviors.

  16. Electrical conductivity measurements on silicate melts using the loop technique

    NASA Technical Reports Server (NTRS)

    Waff, H. S.

    1976-01-01

    A new method is described for measurement of the electrical conductivity of silicate melts under controlled oxygen partial pressure at temperatures to 1550 C. The melt samples are suspended as droplets on platinum-rhodium loops, minimizing iron loss from the melt due to alloying with platinum, and providing maximum surface exposure of the melt to the oxygen-buffering gas atmosphere. The latter provides extremely rapid equilibration of the melt with the imposed oxygen partial pressure. The loop technique involves a minimum of setup time and cost, provides reproducible results to within + or - 5% and is well suited to electrical conductivity studies on silicate melts containing redox cations.

  17. Experimental deformation of partially molten granite and implications for strain localization

    NASA Astrophysics Data System (ADS)

    Goncalves, L.; Hirth, G.; Alkmim, F.; Pedrosa-Soares, A.; Goncalves, C.

    2011-12-01

    To improve our understanding of partially molten systems we conducted a set of hydrostatic, general shear and axial compression experiments on sintered aggregates composed of equal amounts by weight of quartz, albite and microcline (grain size of 37-53μm). All experiments were conducted using a Griggs solid medium apparatus at T=900°C, P=1.5GPa and strain rates from 10-4/s to 10-6/s. Previous hydrostatic and axial compression experiments conducted on partial molten granitic rocks have shown that the initial grain size, amount of melt and strain rate are important parameters for the development of distinct microstructures, LPO, and melt distribution. In addition, some of these studies demonstrated that the strength of granite and aplite decrease significantly for melt contents up to 15%, when compared to similar melt-free rocks. The rock's strength deep within the Earth decreases owing to partial melting which brings up some questions: would strain localization take place when partial melt affects rheology? Would brittle and/or ductile shear zones act as potential regions for concentration of partial melt? Is there a critical fraction of melt responsible for strain localization? How is melt distribution influenced by deformation? How does the kinematics of deformation (i.e., axial compression versus general shear) affect melt distribution? The purpose of our experiments is to investigate the role of melting on the rheological properties of crustal rocks. In addition, we seek to provide new constraints on the grain scale processes that control the properties of partially molten rocks and the importance of these processes in understanding shear localization in the lithosphere. Samples were made from crushed Amelia albite (Ab97Or2An1), Hugo Microcline (Or90) and Black Hills quartzite, which have all been used in previous experimental deformation studies. The albite is essentially pure; the microcline contains ~ 1% of muscovite. The Black Hills quartzite contains < 1

  18. Numerical models of mantle lithosphere weakening, erosion and delamination induced by melt extraction and emplacement

    NASA Astrophysics Data System (ADS)

    Wallner, Herbert; Schmeling, Harro

    2016-09-01

    Continental rifting caused by extension and heating from below affects the lithosphere or cratons in various ways. Volcanism and melt intrusions often occur along with thinning, weakening and even breaking lithosphere. Although mechanical necking models of the lithosphere are often applied, the aspects of melting and the implications due to melt transport and emplacement at shallower depths are not well understood. A two-phase flow approach employing melt extraction and shallow emplacement associated with thermal weakening is developed and compared with observations. The results of this comparison indicate the importance of partial melts and an asthenospheric magma source for increasing the rising rate of the lithosphere-asthenosphere boundary during extension. Thermo-mechanical physics of visco-plastic flow is approximated using the Finite Difference method with Eulerian formulation in 2D. The conservation of mass, momentum and energy equations are solved for a multi-component (crust-mantle) and two-phase (melt-matrix) system. Rheology is temperature- and stress-dependent. In consideration of depletion and enrichment melting and solidification are controlled by a simplified linear binary solid solution model. Melt is extracted and emplaced in predefined depth regions (emplacement zones) in the lithospheric mantle and crust. The Compaction Boussinesq Approximation was applied; its validity was tested against the Full Compaction formulation and found fully satisfactory for the case of sublithospheric melting models. A simple model guided by the geodynamic situation of the Rwenzori region typically results in updoming asthenosphere with melt-assisted erosion of the lithosphere's base. Even with a conservative approach for a temperature anomaly melting alone doubles the lithospheric erosion rate in comparison with a model without melting. With melt extraction and intrusion lithospheric erosion and upwelling of the lithosphere-asthenosphere boundary speeds up by a

  19. Conduction-limited crystallite melting

    NASA Astrophysics Data System (ADS)

    Lupulescu, A.; Glicksman, M. E.; Koss, M. B.

    2005-04-01

    High-purity pivalic acid (PVA) dendrites were observed growing under convection-free conditions during the isothermal dendritic growth experiment (IDGE) flown on NASA's space shuttle Columbia on STS-87. The IDGE was part of the complement of primary scientific experiments designated as the United States Microgravity Payload Mission (USMP4) launched late in 1997. The IDGE video data show that PVA dendrites may be melted without exhibiting any detectable relative motion with respect to the surrounding quiescent melt phase. Thus, melting occurs by heat conduction alone. When a small fixed superheating is imposed on pre-existing dendritic fragments, they melt steadily toward extinction. Individual fragments steadily decrease in size according to a square-root of time dependence predicted using quasi-static conduction-limited theory. Agreement between analytic melting theory and microgravity experiments was found originally if the melting process occurs under the restriction of shape-preserving conditions, where needle-like crystal fragments may be approximated as ellipsoids with a constant axial ratio. Among the new results reported here is the influence of capillarity effects on melting in needle-like crystallites, observed as a dramatic change in their axial ratio, when the size scale of a crystallite decreases below a critical value. In microgravity melting experiments, the axial ratio of individual crystallites does not remain constant, because of interactions with neighboring fragments within the mushy zone. The kinetic data were then "sectorized" to divide the total melting process into a series of short intervals. Each melting sector for a crystallite could then be approximated by a constant average value of the axial ratio. Sectorization also allows accurate prediction of melting kinetics by applying quasi-static heat conduction theory, despite the suspected presence of capillarity and the occurrence of fragmentation. These additional processes that accompany

  20. Microscale effects of melt infiltration into the lithospheric mantle: Peridotite xenoliths from Xilong, South China

    NASA Astrophysics Data System (ADS)

    Lu, Jianggu; Zheng, Jianping; Griffin, William L.; O'Reilly, Suzanne Y.; Pearson, Norman J.

    2015-09-01

    Melting and reactions between minerals and melts are important processes in the evolution of the lithospheric mantle, and are usually inferred from their geochemical fingerprints in mantle samples. However, a suite of mantle-derived peridotite xenoliths from the Xilong area, South China, records the reaction of successive silicate melts of different compositions with mineral assemblages in the mantle, preserved by quenching during entrainment. These xenoliths form two groups and record a compositionally layered mantle. Group 1 has olivine Mg# ~ 91, (and is thus relatively refractory), is derived from depths of ~ 50-65 km, and shows the trace-element geochemical signature of "old" carbonatitic metasomatism. Group 2 is more fertile with olivine Mg# mainly ~ 89-90, is derived from ~ 40 to 55 km and has ubiquitous modal spinel. Xenoliths of both groups then show sequential infiltration by two compositionally distinct melts (Na-rich and K-rich) not long before eruption. The Na-rich melts are enclosed in spongy clinopyroxene and spinel rims and are inferred to have triggered the reactions that formed the spongy rims, which have lower Al2O3, Na2O and Mg#, but higher FeO, TiO2 and Cr# than the primary phases. The undersaturated Na-rich mafic melts were probably formed in the asthenosphere by low-degree melting. The K-rich melts occur mainly in reaction zones around orthopyroxene and in reaction patches containing fine-grained secondary olivine, clinopyroxene and minor spinel. The melts have high contents of SiO2, K2O (mean 14.3 wt.%), Rb, Ba, and LREE but very low Na2O/K2O (0.01-0.29), positive anomalies in Eu and Sr, and variable HFSE anomalies. These compositional characteristics are consistent with an origin as low-degree partial melts of pre-existing phlogopite-bearing rocks. The K-rich melts also react with primary olivine, and the spongy-textured secondary clinopyroxene and spinel inferred to have formed by reaction with the Na-rich melts, yielding secondary olivine

  1. Melting in the FeOsbnd SiO2 system to deep lower-mantle pressures: Implications for subducted Banded Iron Formations

    NASA Astrophysics Data System (ADS)

    Kato, Chie; Hirose, Kei; Nomura, Ryuichi; Ballmer, Maxim D.; Miyake, Akira; Ohishi, Yasuo

    2016-04-01

    Banded iron formations (BIFs), consisting of layers of iron oxide and silica, are far denser than normal mantle material and should have been subducted and sunk into the deep lower mantle. We performed melting experiments on Fe2SiO4 from 26 to 131 GPa in a laser-heated diamond-anvil cell (DAC). The textural and chemical characterization of a sample recovered from the DAC revealed that SiO2 is the liquidus phase for the whole pressure range examined in this study. The chemical compositions of partial melts are very rich in FeO, indicating that the eutectic melt compositions in the FeOsbnd SiO2 binary system are very close to the FeO end-member. The eutectic temperature is estimated to be 3540 ± 150 K at the core-mantle boundary (CMB), which is likely to be lower than the temperature at the top of the core at least in the Archean and Paleoproterozoic eons, suggesting that subducted BIFs underwent partial melting in a thermal boundary layer above the CMB. The FeO-rich melts formed by partial melting of the BIFs were exceedingly dense and therefore migrated downward. We infer that such partial melts have caused iron enrichment in the bottom part of the mantle, which may have contributed to the formation of ultralow velocity zones (ULVZs) observed today. On the other hand, solid residues left after the segregation of the FeO-rich partial melts have been almost pure SiO2, and therefore buoyant in the deep lower mantle to be entrained in mantle upwellings. They have likely been stretched and folded repeatedly by mantle flow, forming SiO2 streaks within the mantle "marble cake". Mantle packages enhanced by SiO2 streaks may be the origin of seismic scatterers in the mid-lower mantle.

  2. Silicate melts density, buoyancy relations and the dynamics of magmatic processes in the upper mantle

    NASA Astrophysics Data System (ADS)

    Sanchez-Valle, Carmen; Malfait, Wim J.

    2016-04-01

    Although silicate melts comprise only a minor volume fraction of the present day Earth, they play a critical role on the Earth's geochemical and geodynamical evolution. Their physical properties, namely the density, are a key control on many magmatic processes, including magma chamber dynamics and volcanic eruptions, melt extraction from residual rocks during partial melting, as well as crystal settling and melt migration. However, the quantitative modeling of these processes has been long limited by the scarcity of data on the density and compressibility of volatile-bearing silicate melts at relevant pressure and temperature conditions. In the last decade, new experimental designs namely combining large volume presses and synchrotron-based techniques have opened the possibility for determining in situ the density of a wide range of dry and volatile-bearing (H2O and CO2) silicate melt compositions at high pressure-high temperature conditions. In this contribution we will illustrate some of these progresses with focus on recent results on the density of dry and hydrous felsic and intermediate melt compositions (rhyolite, phonolite and andesite melts) at crustal and upper mantle conditions (up to 4 GPa and 2000 K). The new data on felsic-intermediate melts has been combined with in situ data on (ultra)mafic systems and ambient pressure dilatometry and sound velocity data to calibrate a continuous, predictive density model for hydrous and CO2-bearing silicate melts with applications to magmatic processes down to the conditions of the mantle transition zone (up to 2773 K and 22 GPa). The calibration dataset consist of more than 370 density measurements on high-pressure and/or water-and CO2-bearing melts and it is formulated in terms of the partial molar properties of the oxide components. The model predicts the density of volatile-bearing liquids to within 42 kg/m3 in the calibration interval and the model extrapolations up to 3000 K and 100 GPa are in good agreement

  3. Vitrification of waste with conitnuous filling and sequential melting

    SciTech Connect

    Powell, James R.; Reich, Morris

    2001-09-04

    A method of filling a canister with vitrified waste starting with a waste, such as high-level radioactive waste, that is cooler than its melting point. Waste is added incrementally to a canister forming a column of waste capable of being separated into an upper zone and a lower zone. The minimum height of the column is defined such that the waste in the lower zone can be dried and melted while maintaining the waste in the upper zone below its melting point. The maximum height of the column is such that the upper zone remains porous enough to permit evolved gases from the lower zone to flow through the upper zone and out of the canister. Heat is applied to the waste in the lower zone to first dry then to raise and maintain its temperature to a target temperature above the melting point of the waste. Then the heat is applied to a new lower zone above the melted waste and the process of adding, drying and melting the waste continues upward in the canister until the entire canister is filled and the entire contents are melted and maintained at the target temperature for the desired period. Cooling of the melted waste takes place incrementally from the bottom of the canister to the top, or across the entire canister surface area, forming a vitrified product.

  4. 'Melt welt' mechanism of extreme weakening of gabbro at seismic slip rates.

    PubMed

    Brown, Kevin M; Fialko, Yuri

    2012-08-30

    Laboratory studies of frictional properties of rocks at slip velocities approaching the seismic range (∼0.1-1 m s(-1)), and at moderate normal stresses (1-10 MPa), have revealed a complex evolution of the dynamic shear strength, with at least two phases of weakening separated by strengthening at the onset of wholesale melting. The second post-melting weakening phase is governed by viscous properties of the melt layer and is reasonably well understood. The initial phase of extreme weakening, however, remains a subject of much debate. Here we show that the initial weakening of gabbro is associated with the formation of hotspots and macroscopic streaks of melt ('melt welts'), which partially unload the rest of the slip interface. Melt welts begin to form when the average rate of frictional heating exceeds 0.1-0.4 MW m(-2), while the average temperature of the shear zone is well below the solidus (250-450 °C). Similar heterogeneities in stress and temperature are likely to occur on natural fault surfaces during rapid slip, and to be important for earthquake rupture dynamics.

  5. 'Melt welt' mechanism of extreme weakening of gabbro at seismic slip rates.

    PubMed

    Brown, Kevin M; Fialko, Yuri

    2012-08-30

    Laboratory studies of frictional properties of rocks at slip velocities approaching the seismic range (∼0.1-1 m s(-1)), and at moderate normal stresses (1-10 MPa), have revealed a complex evolution of the dynamic shear strength, with at least two phases of weakening separated by strengthening at the onset of wholesale melting. The second post-melting weakening phase is governed by viscous properties of the melt layer and is reasonably well understood. The initial phase of extreme weakening, however, remains a subject of much debate. Here we show that the initial weakening of gabbro is associated with the formation of hotspots and macroscopic streaks of melt ('melt welts'), which partially unload the rest of the slip interface. Melt welts begin to form when the average rate of frictional heating exceeds 0.1-0.4 MW m(-2), while the average temperature of the shear zone is well below the solidus (250-450 °C). Similar heterogeneities in stress and temperature are likely to occur on natural fault surfaces during rapid slip, and to be important for earthquake rupture dynamics. PMID:22932388

  6. A benchmark initiative on mantle convection with melting and melt segregation

    NASA Astrophysics Data System (ADS)

    Schmeling, Harro; Dannberg, Juliane; Dohmen, Janik; Kalousova, Klara; Maurice, Maxim; Noack, Lena; Plesa, Ana; Soucek, Ondrej; Spiegelman, Marc; Thieulot, Cedric; Tosi, Nicola; Wallner, Herbert

    2016-04-01

    In recent years a number of mantle convection models have been developed which include partial melting within the asthenosphere, estimation of melt volumes, as well as melt extraction with and without redistribution at the surface or within the lithosphere. All these approaches use various simplifying modelling assumptions whose effects on the dynamics of convection including the feedback on melting have not been explored in sufficient detail. To better assess the significance of such assumptions and to provide test cases for the modelling community we carry out a benchmark comparison. The reference model is taken from the mantle convection benchmark, cases 1a to 1c (Blankenbach et al., 1989), assuming a square box with free slip boundary conditions, the Boussinesq approximation, constant viscosity and Rayleigh numbers of 104 to 10^6. Melting is modelled using a simplified binary solid solution with linearly depth dependent solidus and liquidus temperatures, as well as a solidus temperature depending linearly on depletion. Starting from a plume free initial temperature condition (to avoid melting at the onset time) five cases are investigated: Case 1 includes melting, but without thermal or dynamic feedback on the convection flow. This case provides a total melt generation rate (qm) in a steady state. Case 2 is identical to case 1 except that latent heat is switched on. Case 3 includes batch melting, melt buoyancy (melt Rayleigh number Rm) and depletion buoyancy, but no melt percolation. Output quantities are the Nusselt number (Nu), root mean square velocity (vrms), the maximum and the total melt volume and qm approaching a statistical steady state. Case 4 includes two-phase flow, i.e. melt percolation, assuming a constant shear and bulk viscosity of the matrix and various melt retention numbers (Rt). These cases are carried out using the Compaction Boussinseq Approximation (Schmeling, 2000) or the full compaction formulation. For cases 1 - 3 very good agreement

  7. Occurrence of silicate melt, carbonate-rich melt and fluid during medium pressure anatexis of metapelitic gneisses (Oberpfalz, Bavaria) revealed by melt and fluid inclusions study

    NASA Astrophysics Data System (ADS)

    Ferrero, Silvio; O'Brien, Patrick; Hecht, Lutz; Wunder, Bernd

    2014-05-01

    In the last decades our understanding of partial melting processes in the lower crust profited from the investigation of fluid inclusions (Touret et al., 2009) and more recently of anatectic melt inclusions (Cesare et al., 2011) within enclaves and high-grade terranes. The latter finding allowed us to directly analyse the original anatectic melt (Ferrero et al., 2012; Bartoli et al., 2013) preserved within peritectic phases, i.e. mainly garnet, but also ilmenite and spinel, before fractionation, mixing and contamination processes took place. Furthermore, the occurrence of primary fluid inclusions (FI) and anatectic melt inclusions (MI) within enclaves allowed the characterization of the COH fluid present during anatexis under fluid+melt immiscibility conditions (Ferrero et al., 2014). Primary crystallized MI, or "nanogranites", and FI have been identified to occur as clusters in garnet from stromatic migmatites (Zeilengneise) from Oberpfalz, Eastern Bavaria (Moldanubian Zone). During the late Carboniferous, these Grt+Bt+Sill+Crd+Spl metapelitic gneisses underwent HT/MP metamorphism, followed by a HT/LP event (Tanner & Behrmann, 1995). Nanogranites, ≤20 µm in size, consist of Qtz+Bt+Wm+Ab±Ap, and show abundant nanoporosity, localized in the quartz. Fluid inclusions are smaller, generally ≤10 µm, and contain CO2+N2+CH4 plus siderite, pyrophillite and cristobalite, mineral phases not observed in the surrounding rock or as mineral inclusion in garnet. Polycrystalline inclusions containing Cc+Wm+Opx±Qz, commonly ≤10 µm in diameter, occur in the same cluster with MI and FI. Microstructural features, negative-crystal shape and the well-developed crystalline faces of calcite within inclusions suggest that they may result from the crystallization of a carbonate-rich melt. The lack of arrays of carbonate-bearing MI, verified by cathodoluminiscence investigation, supports their primary nature, i.e. they formed during garnet growth. This would suggest the occurrence

  8. Melting Relations of Multicomponent Carbonate System MgCO3 - FeCO3- CaCO3- Na2CO3 at 12-23 GPa

    NASA Astrophysics Data System (ADS)

    Spivak, Anna; Solopova, Natalia; Litvin, Yuriy; Dubrovinsky, Leonid; Zakharchenko, Egor

    2014-05-01

    Considerable attention is focused on high-pressure high-temperature experimental study of melting phase relations of carbonates which were involved into a 'super-deep' diamond genesis. High-pressure stability of carbonate melts and their role in 'ultra-deep' diamonds genesis are most essential. Experimental study of melting relations of multicomponent carbonate system was carried out using multi-anvil press at the pressures 12 - 23 GPa and temperatures 800 to 1650 oC. Chemical compositions of starting carbonate system used for melting experiment were prepared by mixing: FeCO3 - 26,00; MgCO3- 26,00; CaCO3 - 25,00; Na2CO3 - 23,00 wt %. A region of partial melting for the system is experimentally determined. The partial melting field is arranged between low-temperature boundary of eutectics melting (solidus line) of the multicomponent carbonate and the boundary of complete melting (liquidus line) at higher temperature. From experimental observations, a Mg-Fe carbonate solid solution is the liquidus phase. At temperature lowering, the assemblage (Mg,Fe)CO3 + (Ca,Na2,Fe)CO3 + L (liquid) is formed. Then, the invariant eutectic assemblage (Mg,Fe)CO3 + (Ca,Na2,Fe)CO3 + Na2(Ca,Fe)(CO3)2+ L (liquid) which is determining for subsolidus assemblage (Mg,Fe)CO3 + (Ca,Na2,Fe)CO3 + Na2(Ca,Fe)(CO3)2 is formed. Next to liquidus line is one-phase field of completely miscible multicomponent carbonate melt. On the whole, the results demonstrate phase relations of solid carbonates and multicomponent carbonate liquid in the immediate vicinity to the low-temperature melting boundary. The early melting of the multicomponent carbonate system is compatible with the lower mantle geothermal conditions because the primary melting temperatures are noticeably below than the geothermal values. It is significant that multicomponent carbonate melts are stable and completely miscible under conditions as partial so complete melting. Thus, high-pressure high-temperature experimental data demonstrate

  9. Slab melting as a barrier to deep carbon subduction.

    PubMed

    Thomson, Andrew R; Walter, Michael J; Kohn, Simon C; Brooker, Richard A

    2016-01-01

    Interactions between crustal and mantle reservoirs dominate the surface inventory of volatile elements over geological time, moderating atmospheric composition and maintaining a life-supporting planet. While volcanoes expel volatile components into surface reservoirs, subduction of oceanic crust is responsible for replenishment of mantle reservoirs. Many natural, 'superdeep' diamonds originating in the deep upper mantle and transition zone host mineral inclusions, indicating an affinity to subducted oceanic crust. Here we show that the majority of slab geotherms will intersect a deep depression along the melting curve of carbonated oceanic crust at depths of approximately 300 to 700 kilometres, creating a barrier to direct carbonate recycling into the deep mantle. Low-degree partial melts are alkaline carbonatites that are highly reactive with reduced ambient mantle, producing diamond. Many inclusions in superdeep diamonds are best explained by carbonate melt-peridotite reaction. A deep carbon barrier may dominate the recycling of carbon in the mantle and contribute to chemical and isotopic heterogeneity of the mantle reservoir. PMID:26738593

  10. Slab melting as a barrier to deep carbon subduction

    NASA Astrophysics Data System (ADS)

    Thomson, Andrew R.; Walter, Michael J.; Kohn, Simon C.; Brooker, Richard A.

    2016-01-01

    Interactions between crustal and mantle reservoirs dominate the surface inventory of volatile elements over geological time, moderating atmospheric composition and maintaining a life-supporting planet. While volcanoes expel volatile components into surface reservoirs, subduction of oceanic crust is responsible for replenishment of mantle reservoirs. Many natural, ‘superdeep’ diamonds originating in the deep upper mantle and transition zone host mineral inclusions, indicating an affinity to subducted oceanic crust. Here we show that the majority of slab geotherms will intersect a deep depression along the melting curve of carbonated oceanic crust at depths of approximately 300 to 700 kilometres, creating a barrier to direct carbonate recycling into the deep mantle. Low-degree partial melts are alkaline carbonatites that are highly reactive with reduced ambient mantle, producing diamond. Many inclusions in superdeep diamonds are best explained by carbonate melt-peridotite reaction. A deep carbon barrier may dominate the recycling of carbon in the mantle and contribute to chemical and isotopic heterogeneity of the mantle reservoir.

  11. Slab melting as a barrier to deep carbon subduction.

    PubMed

    Thomson, Andrew R; Walter, Michael J; Kohn, Simon C; Brooker, Richard A

    2016-01-01

    Interactions between crustal and mantle reservoirs dominate the surface inventory of volatile elements over geological time, moderating atmospheric composition and maintaining a life-supporting planet. While volcanoes expel volatile components into surface reservoirs, subduction of oceanic crust is responsible for replenishment of mantle reservoirs. Many natural, 'superdeep' diamonds originating in the deep upper mantle and transition zone host mineral inclusions, indicating an affinity to subducted oceanic crust. Here we show that the majority of slab geotherms will intersect a deep depression along the melting curve of carbonated oceanic crust at depths of approximately 300 to 700 kilometres, creating a barrier to direct carbonate recycling into the deep mantle. Low-degree partial melts are alkaline carbonatites that are highly reactive with reduced ambient mantle, producing diamond. Many inclusions in superdeep diamonds are best explained by carbonate melt-peridotite reaction. A deep carbon barrier may dominate the recycling of carbon in the mantle and contribute to chemical and isotopic heterogeneity of the mantle reservoir.

  12. Pliocene-Quaternary crustal melting in central and northern Tibet and insights into crustal flow

    PubMed Central

    Wang, Qiang; Hawkesworth, Chris J.; Wyman, Derek; Chung, Sun-Lin; Wu, Fu-Yuan; Li, Xian-Hua; Li, Zheng-Xiang; Gou, Guo-Ning; Zhang, Xiu-Zheng; Tang, Gong-Jian; Dan, Wei; Ma, Lin; Dong, Yan-Hui

    2016-01-01

    There is considerable controversy over the nature of geophysically recognized low-velocity–high-conductivity zones (LV–HCZs) within the Tibetan crust, and their role in models for the development of the Tibetan Plateau. Here we report petrological and geochemical data on magmas erupted 4.7–0.3 Myr ago in central and northern Tibet, demonstrating that they were generated by partial melting of crustal rocks at temperatures of 700–1,050 °C and pressures of 0.5–1.5 GPa. Thus Pliocene-Quaternary melting of crustal rocks occurred at depths of 15–50 km in areas where the LV–HCZs have been recognized. This provides new petrological evidence that the LV–HCZs are sources of partial melt. It is inferred that crustal melting played a key role in triggering crustal weakening and outward crustal flow in the expansion of the Tibetan Plateau. PMID:27307135

  13. Distribution of REE, LILE, and HFSE between biotite, feldspar, and the melt in the granulite facies migmatite, nimnyr block, Aldan shield

    NASA Astrophysics Data System (ADS)

    Glebovitskii, V. A.; Sedova, I. S.

    2016-02-01

    The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element's partition coefficients between minerals and the melt D i min/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE D i are a little below 1, while those of LREE, especially D i for Ce, are 1-3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the D i of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.

  14. U-238 - Th-230 - Ra-226 disequilibria in volcanics: A new insight into melting conditions

    NASA Astrophysics Data System (ADS)

    Chabaux, Francois; Allegre, Claude J.

    1994-08-01

    Using new mass spectrometry techniques developed for the analysis of Ra isotopes, we present U-238 - Th-230 - Ra-226 disequilibria data from a variety of volcanic settings, and compare them with previously published data. Two correlations are observed with alkali volcanic data, one between (Th-230/U-238) and (Th-230/Ra-226) and another between the intensity of the disequilibria and the buoyancy flux of the underlying plume. These two correlations prove that partial melting is the major cause of U-Th-Ra fractionations in this volcanic context. The U-238 - Th-230 - Ra-226 disequilibria then place new constraints on some parameters of the classical melting models (batch melting and dynamic melting). The comparison of U-238 - Th-230 - Ra-226 disequilibria in alkali volcanics, carbonatites and subduction zones shows a clear parallel between the disequilibria value and the type of volcanic context. Such a parallel reflects the diversity of the conditions of magma generation, and shows that the U-238 - Th-230 - Ra-226 disequilibria systematics are very dependent on the chemical composition of liquids produced during magmatic processes. A systematic difference is observed between disequilibria in MORB and in alkali volcanics, which could indicate that the melting processes in these two volcanic contexts are very different.

  15. Multi-sensor geophysical constraints on crustal melt in the central Andes: the PLUTONS project

    NASA Astrophysics Data System (ADS)

    Pritchard, M. E.; Comeau, M. J.; West, M. E.; Christensen, D. H.; Mcfarlin, H. L.; Farrell, A. K.; Del Potro, R.; Gottsmann, J.; McNutt, S. R.; Michelfelder, G.; Diez, M.; Elliott, J.; Henderson, S. T.; Keyson, L.; Delgado, F.; Unsworth, M. J.

    2015-12-01

    The central Andes is a key global location to quantify storage, transport, and volumes of magma in the Earth's crust as it is home to the world's largest zone of partial melt (the Altiplano-Puna Magma or Mush Body, APMB) as well as the more recently documented Southern Puna Magma Body (SPMB). We describe results from the recently completed international PLUTONS project that focused inter-disciplinary study on two sites of large-scale surface uplift that presumably represent ongoing magmatic intrusions in the mid to upper crust - Uturuncu, Bolivia (in the center of the APMB) and Lazufre on the Chile-Argentina border (on the edge of the SPMB). In particular, a suite of geophysical techniques (seismology, gravity, surface deformation, and electro-magnetic methods) have been used to infer the current subsurface distribution and quantity of partial melts in combination with geochemical and lab studies on samples from the area. Both Uturuncu and Lazufre show separate geophysical anomalies in the upper and mid/lower crust (e.g., low seismic velocity, low resistivity, etc.) indicating multiple distinct reservoirs of magma and/or hydrothermal fluids with different properties. The characteristics of the geophysical anomalies differ somewhat depending on the technique used - reflecting the different sensitivity of each method to subsurface melt of different compositions, connectivity, and volatile content. For example, the depth to the top of the APMB is shallower in a joint ambient noise tomography and receiver function analysis compared to a 3D magnetotelluric inversion. One possibility is that the seismic methods are detecting brines above the APMB that do not have a large electromagnetic signature. Comparison of the geophysical measurements with laboratory experiments at the APMB indicate a minimum of 4-25% melt averaged over the region is needed -- higher melt volumes are permitted by the gravity and MT data and may exist in small regions. However, bulk melt values above

  16. The Edinburgh-Cape Blue Object Survey - V. The end: Partial Zones 4-6; Galactic latitudes -50° > b > -90°

    NASA Astrophysics Data System (ADS)

    Kilkenny, D.; Worters, H. L.; O'Donoghue, D.; Koen, C.; Koen, T.; Hambly, N.; MacGillivray, H.; Stobie, R. S.

    2016-07-01

    Results for the remaining zones of the Edinburgh-Cape (EC) Blue Object survey are presented. These are incomplete, but lie in that part of the South Galactic Cap between 50° and 90° from the Galactic plane and south of about -12.3° of declination. This part of the survey comprises 79 UK Schmidt Telescope fields covering about 2150 deg2, in which we find 536 blue objects - including hot subdwarfs (˜33 per cent), white dwarfs (˜30 per cent), binaries (˜12 per cent), cataclysmic variables (˜1.5 per cent) and some `star-like' galaxies (˜12 per cent). A further 254 stars observed in the survey, mainly low-metallicity F- and G-type stars, are also listed. Low-dispersion spectroscopic classification is given for all the hot objects and UBV photometry for most of them. Either spectroscopy or photometry is listed for the cooler types.

  17. Melt retention and segregation beneath mid-ocean ridges.

    PubMed

    Faul, U H

    2001-04-19

    Geochemical models of melting at mid-ocean ridges-particularly those based on trace elements and uranium-decay-series isotopes-predict that melt segregates from the matrix at very low porosities, of order 0.1%. Some of these models also require that the melt ascends rapidly. But these predictions appear to conflict with seismic data obtained by the mantle electromagnetic and tomography (MELT) experiment. These data reveal, beneath the East Pacific Rise (at 17 degrees S), a region of low velocities several hundred kilometres wide, which is best explained by the presence of 1-2% melt, distributed on a grain scale in disk-shaped geometries. Here I show that these apparently contradictory constraints can be reconciled by taking into account the geometry and resulting permeability of the intergranular network of melt, together with the changing character of the melt as it ascends. A deep, volatile-rich melt with low viscosity and density is mobile at 0.1% porosity, but basaltic melt only becomes mobile at a porosity above 1%. While the volumetric contribution of the volatile-rich melt to the erupted basalts is small, the isotopic disequilibria (except for radium) generated by porous flow of this melt are preserved if melt transport is rapid at the onset of high-productivity melting. Also, because of incomplete extraction, some melt is retained in a broad zone, consistent with the MELT observations.

  18. Studying the structure of a zone in which the single-phase flow moving in an annular channel with partially blocked cross section becomes spatially disturbed

    NASA Astrophysics Data System (ADS)

    Kashinskii, O. N.; Lobanov, P. D.; Kurdyumov, A. S.; Pribaturin, N. A.

    2013-05-01

    The flow of liquid in an annular channel with a partially shaded flow section is experimentally studied using the electrodiffusion method. The effect on the flow structure produced by a shutter closing one-quarter of the channel cross section is shown. An obstacle installed in the channel causes the flow to attain a 3D structure. The flow pattern in such channel differs significantly from that observed in undisturbed flow moving in an annular channel. It is revealed that the friction stress values measured on the channel's inner wall depend essentially on the azimuth angle over the channel height. With distance away from the obstacle, the influence it has on the hydrodynamic flow structure tends to decrease, but the disturbance produced by it does not die out completely even at a distance of more than 600 mm from the obstacle. Data quantitatively characterizing the disturbance of flow structure in the studied channel are presented.

  19. Disequilibrium melt distributions during static recrystallisation

    NASA Astrophysics Data System (ADS)

    Walte, N. P.; Bons, P. D.; Passchier, C. W.; Koehn, D.; Arnold, J.

    2003-04-01

    DISEQUILIBRIUM MELT DISTRIBUTIONS DURING STATIC RECRYSTALLISATION N.P. Walte (1), P.D. Bons (2), C.W. Passchier (1), D. Koehn (1), J. Arnold (1) (1) Institute for Earth Sciences, Johannes Gutenberg-University, Mainz, Germany, (2) Institute for Earth Sciences, Eberhard Karls University, Tübingen, Germany (walte@mail.uni-mainz.de) The geometry of melt-filled pores in a partially molten rock strongly controls the permeability, rheology and initial segregation of melt. Current theory for monomineralic aggregates, using only the wetting angle and melt fraction as parameters, predicts a perfectly regular melt framework or equally shaped melt inclusions on grain boundary junctions. However, published melt-present high-temperature experiments with rock forming minerals such as quartz or olivine show considerable deviations from this predicted regular equilibrium melt geometry. Disequilibrium features, such as fully wetted grain boundaries, melt lenses, and large melt patches have been described, and were attributed to surface energy anisotropy of the minerals. This study used static analogue experiments with norcamphor plus ethanol liquid, that allow continuous in-situ observation of the evolving distribution of melt during static recrystallisation. The liquid-crystal surface energy of norcamphor is effectively isotropic. For the experiments an approximately 0.1 mm thin sample of norcamphor plus ethanole was placed between two glass plates and observed with a miroscope. Ethanol was used as a melt analogue because it allows to run experiments at room temperature, avoiding any temperature gradients. The wetting angle is approximately 15°, which is well below 60° and within the range reported for quartz and olivine plus melt experiments. The experiments show that all described disequilibrium features can form during fluid-enhanced static recrystallisation, especially where surrounding grains consume small, few-sided grains. These features are unstable and transient: a

  20. Detached and Floating-Zone Growth of Semiconductor Crystals on the ISS

    NASA Technical Reports Server (NTRS)

    Dold, P.; Kaiser, N.; Benz, K. W.; Croell, A.; Szofran, F. R.; Cobb, S.; Volz, M.; Schweizer, M.; Rose, M. Franklin (Technical Monitor)

    2000-01-01

    Understanding the mechanism of detached Bridgman growth and establishing the growth of large scale germanium-silicon crystals by the float-zone technique are the key points of the project "RDGS - Reduction of Defects in Germanium-Silicon". The contact angle of the melt and the growth angle of the crystal are essential parameters which allow a controlled use of detached growth. The contact angle was determined for a variety of different substrates and melt compositions; pBN showed the highest value for pure germanium as well as for germanium-rich GeSi melts. The growth angle of Ge(sub 0.95) Si(sub 0.05) was measured to be 8.5-10.5 degrees which concurs with the values of pure germanium and silicon, respectively. The temperature dependence and the concentration dependence of the surface tension were determined for concentrations up to 10at% silicon (partial derivative (gamma)/partial derivative T=-0.08 (raised dot) 10(exp -3)N/m (raised dot) K, partial derivative (gamma)/partial derivative (C)=2.2 (raised dot) 10(exp -3)N/m (raised dot) at%). Using these values, the critical Marangoni number indicating the transition to time-dependent thermocapillary flow will be exceeded for the growth of large scale float-zone crystals onboard the ISS. Therefore, suitable tools for flow control are required.

  1. LILE, REE, and HFSE partition coefficients between crystal and melt in migmatites of granulite facies of the Nimnyr block, Aldan shield

    NASA Astrophysics Data System (ADS)

    Glebovitskii, V. A.; Sedova, I. S.

    2015-05-01

    The behavior of Rb, Sr, Ba, Cr, V, Nb, Zr, REEs, and Y is studied in migmatites of granulite facies and the transitional zone to amphibolite facies in the western part of the Aldan granulite area. Our data allowed estimation of the partition coefficients of these elements in the crystal-melt system ( D i ) for orthopyroxene, garnet, clinopyroxene, and hornblende. The leucosomes of anatectic migmatites and diatectites (high-K charnockites and granites) were accepted as a melt, and the metapelites or previously granitized rocks (nebulites) and early leucosomes relative to late leucosome were the primary rocks and restite. The dependence of D i on the REE ionic radius is close to parabolic [7]. Our data allow identification of a qualitative link between the D {/i Grt/melt} and the thermodynamic conditions of high-grade metamorphism and the accompanying partial melting, which leads to formation of a series of ultrametamorphic granitic rocks: lower temperature rocks (conditions of amphibolite facies) are characterized by higher D REE values relative to the zone of granulite facies. The late granitic rocks formed after diatectic charnockites are also characterized by higher D REE values relative to the preceding charnockites. For the conditions of granulite facies, the material belongs to rocks similar in the formation conditions; however, the series are strongly distinct in K content. The influence of the composition of the anatectic melt and acidity-alkalinity conditions on the partition coefficients of the studied elements is so strong that it eliminates the effect of temperature and pressure. The LREEs, Rb, Sr, and Ba will mostly accumulate in the garnet-orthopyroxene assemblage in the zone of melt origination, whereas HREEs will remain in restite along with Cr and V. Niobium and Zr may enrich the granitic melts. In contrast, the stability of amphibole in restite causes the depletion of melts in all REEs, Y, and Nb and enrichment in Rb, Sr, Ba, and, to a lesser

  2. A benchmark initiative on mantle convection with melting and melt segregation

    NASA Astrophysics Data System (ADS)

    Schmeling, Harro; Dohmen, Janik; Wallner, Herbert; Noack, Lena; Tosi, Nicola; Plesa, Ana-Catalina; Maurice, Maxime

    2015-04-01

    In recent years a number of mantle convection models have been developed which include partial melting within the asthenosphere, estimation of melt volumes, as well as melt extraction with and without redistribution at the surface or within the lithosphere. All these approaches use various simplifying modelling assumptions whose effects on the dynamics of convection including the feedback on melting have not been explored in sufficient detail. To better assess the significance of such assumptions and to provide test cases for the modelling community we initiate a benchmark comparison. In the initial phase of this endeavor we focus on the usefulness of the definitions of the test cases keeping the physics as sound as possible. The reference model is taken from the mantle convection benchmark, case 1b (Blanckenbach et al., 1989), assuming a square box with free slip boundary conditions, the Boussinesq approximation, constant viscosity and a Rayleigh number of 1e5. Melting is modelled assuming a simplified binary solid solution with linearly depth dependent solidus and liquidus temperatures, as well as a solidus temperature depending linearly on depletion. Starting from a plume free initial temperature condition (to avoid melting at the onset time) three cases are investigated: Case 1 includes melting, but without thermal or dynamic feedback on the convection flow. This case provides a total melt generation rate (qm) in a steady state. Case 2 includes batch melting, melt buoyancy (melt Rayleigh number Rm), depletion buoyancy and latent heat, but no melt percolation. Output quantities are the Nusselt number (Nu), root mean square velocity (vrms) and qm approaching a statistical steady state. Case 3 includes two-phase flow, i.e. melt percolation, assuming a constant shear and bulk viscosity of the matrix and various melt retention numbers (Rt). These cases should be carried out using the Compaction Boussinseq Approximation (Schmeling, 2000) or the full compaction

  3. Alternative hypothese for the origin of the ultra-low velocity zones

    NASA Astrophysics Data System (ADS)

    Li, J.; Liu, J.; Hrubiak, R.; Smith, J.

    2015-12-01

    Decades ago seismic tomography revealed peculiar patches known as the ultra-low-velocity zones (ULVZ), located just above the Earth's core-mantle boundary. Typically 5 to 40 km in height, and 100 km in lateral extent, the ULVZs are denser than the surrounding mantle by about 10%, and slower in shear and compressional wave velocities by roughly 30% and 10%, respectively. Elucidating the origin of ULVZs is a key issue in understanding mantle heterogeneity and unraveling the history of chemical differentiation in deep Earth. Existing models invoking partial melting of silicate lithology require specific solidus temperatures to produce isolated melt regions, and they may not be able to account for the large density excess.The scenarios involving iron-rich post-bridgmanite or ferropericlase have been questioned by recent theoretical results showing that iron enrichment in crystalline phases cannot simultaneously explain the observed density and velocity anomalies. Thus the nature of the ULVZs has remained enigmatic. Here we show that the eutectic melting curve of the iron-carbon binary system intersects with the present-day geotherm near the base of the Earth's mantle, suggesting the presence of metallic melt in the D" layer. Using an established model for solid-liquid compositions and approximate values of density and elastic parameters, we found that introducing a suitable fraction of metallic melt could match all the seismic observations, and the fraction depends on the wetting behavior of the melt. We propose a number of alternative hypotheses for the origin of the ultra-low velocity zones, including short-lived ULVZs with metallic melt that are supplied by subducted slabs, long-lasting ULVZs involving both metallic and silicate melts, and ULVZs containing iron-rich solids and residual metallic melt. These hypotheses can be tested by future studies on surface tension, element partitioning, elastic properties, and dynamic modeling.

  4. Melting of CaO and CaSiO3 at Deep Mantle Condition Using First Principles Simulations

    NASA Astrophysics Data System (ADS)

    Bajgain, S. K.; Ghosh, D. B.; Karki, B. B.

    2015-12-01

    Accurate prediction of melting temperatures of major mantle minerals at high pressures is important to understand the Hadean Earth as well as to explain the observed seismic anomalies at ultra-low velocity zone (ULVZ). To further investigate the geophysical implications of our recent first principles study of molten CaO and CaSiO­3, we calculated the melting temperatures of the corresponding solid phases by integrating the Clausius-Clapeyron equation. The melting behavior of their high-pressure phases can constrain the lower mantle solidus. Our calculations show melting temperature of 5700 ± 500 kelvins for CaSiO3 and 7800 ± 600 kelvins for CaO at the base of the lower mantle (136 GPa). The bulk sound velocities of CaO and CaSiO3 liquids at the core-mantle boundary are found to be 40 % lower than P-wave seismic velocity and 22 % lower than that of MgSiO3 liquid. With substantial decrease of melting temperature by freezing point depression and iron partitioning, the partial melting of multi-component silicate and its gravitational buoyancy at ULVZ cannot be ruled out.

  5. Elastic properties of silicate melts at high pressure and implications for low velocity anomalies in the crust and mantle

    NASA Astrophysics Data System (ADS)

    Clark, A. N.; Lesher, C. E.

    2015-12-01

    Regions of low seismic velocities in the mantle and crust are commonly attributed to the presence of silicate melt or aqueous fluid. The elastic properties of silicate melts are typically modeled at high pressure using equations of state developed for crystalline materials. However, amorphous silicates spanning a wide range of composition and structure, i.e. SiO2 to MgSiO3, and including naturally occurring basalt compositions, exhibit a weak dependence of P-wave velocity on density in clear violation of Birch's law, which governs the behavior of crystalline materials. This anomalous behavior is attributed to the high degree of flexibility of the silicate network on loading that may be a general property of naturally occurring silicate melts at crustal and upper mantle conditions. If this is the case, P-wave velocities for silicate melts will be significantly less pressure dependent than previously assumed, which in turn will enhance the effects of melt fraction on lowering aggregate mantle seismic velocities. Here we present VP calculated for partially molten mantle up to 20 GPa showing that melt fractions purported to explain VP reductions associated with the lithosphere-asthenosphere boundary may be overestimated by 15%, while those reported for the transition zone may be overestimated to an even greater extent. Moreover, we predict that d lnVS/d lnVP (RSP) should vary little across low velocities regions within the upper mantle due solely to the presence of melt, but will be strongly influenced by how melt is distributed, consistent the work of [1]. Finally, RSP is found to be relatively insensitive to type of fluid present, contrary to conventional wisdom, and thus caution is warranted in attributing changes in RSP to either silicate melt or aqueous fluids. The implications of these findings for interpreting low velocity anomalies beneath hotspots and arcs (e.g. Iceland and Japan) will be discussed. [1] Takei, Y. (2002) JGR vol. 107

  6. The system Na2CO3-CaCO3-MgCO3 at 6 GPa and 900-1250°C and its relation to the partial melting of carbonated mantle

    NASA Astrophysics Data System (ADS)

    Shatskiy, Anton; Litasov, Konstantin D.; Sharygin, Igor S.; Egonin, Ilya A.; Mironov, Aleksandr M.; Palyanov, Yuri N.; Ohtani, Eiji

    2016-01-01

    In order to constrain the Na2CO3-CaCO3-MgCO3 T-X diagram at 6 GPa in addition to the binary and pseudo-binary systems we conducted experiments along the Na2CO3-Ca0.5Mg0.5CO3 join. At 900-1000°C, melting does not occur and isothermal sections are presented by one-, two- and three-phase regions containing Ca-bearing magnesite, aragonite, Na2CO3 (Na2) and Na2(Ca1-0.9Mg0-0.1)3-4(CO3)4-5 (Na2Ca3-4), Na4(Ca1-0.6Mg0-0.4)(CO3)3 (Na4Ca), Na2(Ca0-0.08Mg1-0.92)(CO3)2 (Na2Mg) phases with intermediate compositions. The minimum melting point locates between 1000°C and 1100°C. This point would resemble that of three eutectics: Mgs-Na2Ca3-Na2Mg, Na2Mg-Na2Ca3-Na4Ca or Na2Mg-Na4Ca-Na2, in the compositional interval of [45Na2CO3.55(Ca0.6Mg0.4)CO3]-[60Na2CO3.40Ca0.6Mg0.4CO3]. The liquidus projection has seven primary solidification phase regions for Mgs, Dol, Arg, Na2Ca3, Na4Ca, Na2 and Na2Mg. The results suggest that extraction of Na and Ca from silicate to carbonate components has to decrease minimum melting temperature of carbonated mantle rocks to 1000-1100°C at 6 GPa and yields Na-rich dolomitic melt with a Na# (Na2O/(Na2O + CaO + MgO)) ≥ 28 mol%.

  7. Evidence for hydrous melting along high-temperature veins within a gabbro from SWIR (ODP Leg 176)

    NASA Astrophysics Data System (ADS)

    Feig, S. T.; Koepke, J.; Bremer, C.; Snow, J. E.

    2003-04-01

    The 1053 m long drilled gabbroic section of the Leg 176 from the Southwest Indian Ridge (SWIR) contains numerous high-temperature veins composed of orthopyroxene (opx), pargasite (par), clinopyroxene (cpx), and plagioclase (plag). According to Maeda et al. (2002) these veins were formed by a water-rich fluid at temperatures up to 1000°C. New partial melting experiments using oceanic gabbros from the Leg 176 as starting material revealed, that at such conditions gabbros should melt (Feig et al., this volume). By carefully checking high-temperature veins with backscattered electron imaging, we actually found in one gabbro (R6a) from the Leg microstructures which are evident for hydrous partial melting. Plag in contact with a vein shows a few tens of microns thick, irregular zone significantly enriched in An (An76), while cpx along veins react to idiomorphic opx (Mg# = 75) and par (Na+K on A = 0.73; Mg# = 74). An-rich plag, opx, and par are regarded as restitic crystals of a partial melting reaction, while micron-sized "pools" of hornblende between cpx and par are probably related to former melt pockets. Striking is the compositional agreement with corresponding phases of those hydrous partial melting experiments using as starting material a gabbro (61a) showing a composition (olivine - Fo71, plag - An55, cpx - Mg# = 78), which matches well that of R6a (olivine - Fo71, plag - An55, cpx - Mg# = 80). That run performed at 940°C (P = 200 MPa, NNO oxygen buffer, water-saturated) shows as crystal phases opx (Mg# = 75), par (Na+K on A = 0.68; Mg# = 74), and plag (~ An75; extrapolated from a run performed at 980°C with An79, since the plag of the 940°C-run was too tiny for microprobe analysis). Cpx was not stable in that run at 940°C. The coexisting melt of this run is dioritc with a SiO2 content of 60.9 wt%. Our experiments imply melting temperatures of ~940°C under water-saturated conditions for the formation of the high-temperature vein minerals. The melt, once

  8. Spade: An H Chondrite Impact-melt Breccia that Experienced Post-shock Annealing

    NASA Technical Reports Server (NTRS)

    Rubin, Alan E.; Jones, Rhian H.

    2006-01-01

    The low modal abundances of relict chondrules (1.8 Vol%) and of coarse (i.e. >= 2200 micron-size) isolated mafic silicate grains (1.8 Vol%) in Spade relative to mean H6 chondrites (11.4 and 9.8 vol%, respectively) show Spade to be a rock that has experienced a significant degree of melting. Various petrographic features (e.g., chromite-plagioclase assemblages, chromite veinlets, silicate darkening) indicate that melting was caused by shock. Plagioclase was melted during the shock event and flowed so that it partially to completely surrounded nearby mafic silicate grains. During crystallization, plagioclase developed igneous zoning. Low-Ca pyroxene that crystallized from the melt (or equilibrated with the melt at high temperatures) acquired relatively high amounts of CaO. Metallic Fe-Ni cooled rapidly below the Fe-Ni solws and transformed into martensite. Subsequent reheating of the rock caused transformation of martensite into abundant duplex plessite. Ambiguities exist in the shock stage assignment of Spade. The extensive silicate darkening, the occurrence of chromite-plagioclase assemblages, and the impact-melted characteristics of Spade are consistent with shock stage S6. Low shock (stage S2) is indicated by the undulose extinction and lack of planar fractures in olivine. This suggests that Spade reached a maximum prior shock level equivalent to stage S6 and then experienced post-shock annealing (probably to stage Sl). These events were followed by a less intense impact that produced the undulose extinction in the olivine, characteristic of shock stage S2. Annealing could have occurred if Spade were emplaced near impact melts beneath the crater floor or deposited in close proximity to hot debris within an ejecta blanket. Spade firmly establishes the case for post-shock annealing. This may have been a common process on ordinary chondrites (OC) asteroids.

  9. Cracks preserve kimberlite melt composition

    NASA Astrophysics Data System (ADS)

    Brett, R. C.; Vigouroux-Caillibot, N.; Donovan, J. J.; Russell, K.

    2009-12-01

    The chemical composition of kimberlite melts has previously been estimated by measuring aphanitic intrusive rocks (deposit composition) or by partial melting experiments on carbonated lherzolites (source composition). Pervasively altered, degassed and contaminated material preclude the determination of the primitive melt composition. Here we present data on melt compositions trapped in unaltered olivine cracks that have been healed and overgrown prior to shallow level emplacement. During the ascent of kimberlite magma the prograding crack tip samples mantle peridotite xenoliths. Xenoliths rapidly disaggregate over the first few kilometers of transport producing a population of olivine xenocrysts that are released to the fluid-rich melt. Rapid ascent of the kimberlite magma causes depressurization and creates internal elastic stresses in the olivine crystals that can only be alleviated by volumetric expansion or brittle failure. On the time scales operative during kimberlite ascent volume expansion is negligible and brittle failure occurs. Small wetting angles between the fluid-rich melt and olivine allow infiltration of the melt into the crack. These very thin cracks (<5 µm) heal rapidly and preserve primary kimberlitic material en route to the surface. We use the electron microprobe with a focused beam (interaction volume less than 2 µm) to analyze the small volumes of material found in the healed cracks of the olivine. We analyzed for 18 elements including oxygen, which we obtained by utilizing a non-linear time dependent intensity acquisition and empirically determined mass absorption coefficients. By accurately knowing the amount of oxygen in a sample, we assign oxygen molecules to all other analyzed elements (e.g. MgO, Al2O3) and the remaining oxygen is assigned to hydrogen and carbon. The analysis total is used as a constraint on the proportion of each species. Mg/Ca ratios of the cracks vary from 0.6-5 indicating a compositional continuum between alkali

  10. Water-Fluxed Fractional Melting: a new, Efficient Mechanism of Garnet Enrichment During Mid- and Lower-Crustal Anatexis

    NASA Astrophysics Data System (ADS)

    Luffi, P. I.; Saleeby, J. B.; Asimow, P. D.

    2005-12-01

    Garnet porphyroblasts of impressive size and/or abundance spatially associated with trondhjemitic leucosomes are known from a variety of migmatites worldwide [e.g. 1-4], and have frequently been interpreted as peritectic products of dehydration melting due to P-T variations controlled by regional-scale tectonothermal processes. However, to produce the observed abundance of garnet isochemically, such melting mechanisms would require significant overstepping of the solidus. They cannot, therefore, satisfactorily explain why partial melting often is triggered only locally and generates leucosome + abundant garnet in well delimited veins, pods and patches, leaving large volumes of paleosome essentially unaltered and garnet-free. Indeed, textural evidence suggests in many cases that partial melting proceeded in an open system, implying channelized volatile and/or melt influx and, possibly, simultaneous melt removal. To test this alternative mechanism for producing leucosome + garnet assemblages, we used the program Adiabat_1ph [5], a flexible front-end to the MELTS thermodynamic model [6] that facilitates such open-system calculations. We simulated the influx of water into a series of originally vapor-free model tonalites and diorites and tracked the effect of melt fractionation on the abundance of formed garnet. Calculations ran at constant P-T conditions close to the original solidus of the system by progressive addition of small amounts of water and continuous removal of generated melts. Our results show that water-fluxed fractional melting generates mainly trondhjemitic liquids and produces 3-5 times more garnet than melting in closed systems in the presence of similar amounts of water. This reaction may be written in a general form as Plg + Amph + Water ± Qtz ± Bt ± Cpx → Grt + Melt ± Cpx. Simulated water-fluxed fractional melting produces nearly homogeneous garnets in diorites, whereas garnets formed in tonalites are zoned due to larger compositional changes

  11. Oceanic slab melting and mantle metasomatism.

    PubMed

    Scaillet, B; Prouteau, G

    2001-01-01

    Modern plate tectonic brings down oceanic crust along subduction zones where it either dehydrates or melts. Those hydrous fluids or melts migrate into the overlying mantle wedge trigerring its melting which produces arc magmas and thus additional continental crust. Nowadays, melting seems to be restricted to cases of young (< 50 Ma) subducted plates. Slab melts are silicic and strongly sodic (trondhjemitic). They are produced at low temperatures (< 1000 degrees C) and under water excess conditions. Their interaction with mantle peridotite produces hydrous metasomatic phases such as amphibole and phlogopite that can be more or less sodium rich. Upon interaction the slab melt becomes less silicic (dacitic to andesitic), and Mg, Ni and Cr richer. Virtually all exposed slab melts display geochemical evidence of ingestion of mantle material. Modern slab melts are thus unlike Archean Trondhjemite-Tonalite-Granodiorite rocks (TTG), which suggests that both types of magmas were generated via different petrogenetic pathways which may imply an Archean tectonic model of crust production different from that of the present-day, subduction-related, one. PMID:11838241

  12. Oceanic slab melting and mantle metasomatism.

    PubMed

    Scaillet, B; Prouteau, G

    2001-01-01

    Modern plate tectonic brings down oceanic crust along subduction zones where it either dehydrates or melts. Those hydrous fluids or melts migrate into the overlying mantle wedge trigerring its melting which produces arc magmas and thus additional continental crust. Nowadays, melting seems to be restricted to cases of young (< 50 Ma) subducted plates. Slab melts are silicic and strongly sodic (trondhjemitic). They are produced at low temperatures (< 1000 degrees C) and under water excess conditions. Their interaction with mantle peridotite produces hydrous metasomatic phases such as amphibole and phlogopite that can be more or less sodium rich. Upon interaction the slab melt becomes less silicic (dacitic to andesitic), and Mg, Ni and Cr richer. Virtually all exposed slab melts display geochemical evidence of ingestion of mantle material. Modern slab melts are thus unlike Archean Trondhjemite-Tonalite-Granodiorite rocks (TTG), which suggests that both types of magmas were generated via different petrogenetic pathways which may imply an Archean tectonic model of crust production different from that of the present-day, subduction-related, one.

  13. Melt and Chemical Transport in the Mantle: Insights from Deglaciation-Induced Melting Perturbations in Iceland

    NASA Astrophysics Data System (ADS)

    Eason, D. E.; Ito, G.; Sinton, J. M.

    2011-12-01

    Eruptive products represent a time-averaged view of the melting region and melt migration processes, making numerous fundamental parameters of the melt system difficult to constrain. Temporal and spatial variations in melting provide potential windows into this obscure region of the Earth by preferentially sampling melts from different regions of the mantle or mixing melts over different length-scales. We present a newly extended geochemical time series from the Western Volcanic Zone (WVZ) of Iceland, which experienced a short-lived melting perturbation due to glacial unloading during the last major deglaciation (~15-10 ka). Glacial unloading during this period led to increased degrees of melting particularly in the shallow mantle, which is manifest as an observed increase in volcanic production up to 30 times the steady-state value, decreased levels of highly to moderately incompatible element ratios (e.g., a 35-50% decrease in Nb/Y, with the greatest change occurring in the northernmost WVZ), and elevated SiO2 and CaO concentrations (~0.8 wt. % and ~1.9 wt. % increase in average oxide concentrations respectively) during and immediately following deglaciation. Although eruptive productivity returns to steady-state values within ~3000 yr following deglaciation, the incompatible element concentrations in erupted lavas gradually increase throughout the post-glacial period. We exploit this short-lived melting perturbation to examine and constrain knowledge of fundamental characteristics of melt generation and transport, including mantle permeability, melt ascent rates, depth-dependent melting functions (dF/dP), and the nature of chemical transport and melt mixing in the system. Using conservation equations describing the generation and porous flow of melt in a viscous matrix, we model melt migration in the mantle during and after ice sheet removal, as well as trace element transport for both equilibrium and disequilibrium transport end members. The predicted

  14. Gravimetric imaging of partially molten bodies beneath the Bolivian Altiplano

    NASA Astrophysics Data System (ADS)

    del Potro, R.; Diez, M.; Gottsmann, J.; Camacho, A. J.; Sunagua, M.

    2011-12-01

    The presence of partial melt in the Earth's crust causes a decrease in density, and hence a density contrast, that generates a potential field anomaly. Gravimetric techniques can quantify such an anomaly and invert its signature to produce a subsurface density distribution model, from which images of anomalous density bodies can be isolated. Here, we present a 3D gravimetric image of four deep-rooted negative density bodies in the Central Volcanic Zone of the Andes in southern Bolivia, which we interpret to contain partial melt. The underlying gravimetric data were obtained by the combination of 143 new with 60 existing observation from previous regional surveys. The survey covers an area of ~5000 km2 that comprises the Central Andean Bouguer anomaly minima of about -450 μGal. After standard data reduction, the local residual gravity signal was inverted using a priori determined plausible density contrasts (±50 to ±300 kg m-3). The inversion routine builds a subsurface model (defined by the 3D aggregation of parallel-piped cells) based on a controlled 'growth' process of anomalous density bodies by means of an exploratory approach. Non-uniqueness is addressed by favouring solutions that balance minimum residuals and minimum number of anomalous bodies with minimum anomalous mass. Within the range of assumed density contrasts, all inversion models show the presence of the deep-rooted low-density bodies, providing a significant confidence level to the inversion results. Our favoured 3D model of the anomalous bodies is obtained from a negative density contrast of 150 kg m-3 that corresponds to <30 vol% partial melt of dacitic composition. These partially molten bodies appear to connect the Altiplano-Puna Magma Body (AMPB) at ~20 km depth, to shallower (~5 km) pre-eruption levels beneath the Altiplano-Puna Volcanic Complex (APVC). One of the bodies is located beneath a large on-going ground uplift centred at Uturuncu volcano and the modelled ground deformation source

  15. Esthetic removable partial dentures.

    PubMed

    Ancowitz, Stephen

    2004-01-01

    This article provides information regarding the many ways that removable partial dentures (RPDs) may be used to solve restorative problems in the esthetic zone without displaying metal components or conspicuous acrylic resin flanges. The esthetic zone is defined and described, as are methods for recording it. Six dental categories are presented that assist the dentist in choosing a variety of RPD design concepts that may be used to avoid metal display while still satisfying basic principles of RPDs. New materials that may be utilized for optimal esthetics are presented and techniques for contouring acrylic resin bases and tinting denture bases are described.

  16. Melt production beneath Mt. Shasta from boron data in primitive melt inclusions.

    PubMed

    Rose, E F; Shimizu, N; Layne, G D; Grove, T L

    2001-07-13

    Most arc magmas are thought to be generated by partial melting of the mantle wedge induced by infiltration of slab-derived fluids. However, partial melting of subducting oceanic crust has also been proposed to contribute to the melt generation process, especially when young and hot lithosphere is being subducted. The isotopic composition of boron measured in situ in olivine-hosted primitive melt inclusions in a basaltic andesite from Mt. Shasta, California, is characterized by large negative values that are also highly variable (delta(11)B = -21.3 to -0.9 per mil). The boron concentrations, from 0.7 to 1.6 parts per million, are lower than in most other arc lavas. The relation between concentration and isotopic composition of boron observed here supports a hypothesis that materials left after dehydration of the subducting slab may have contributed to the generation of basaltic andesite lavas at Mt. Shasta.

  17. Melt production beneath Mt. Shasta from boron data in primitive melt inclusions.

    PubMed

    Rose, E F; Shimizu, N; Layne, G D; Grove, T L

    2001-07-13

    Most arc magmas are thought to be generated by partial melting of the mantle wedge induced by infiltration of slab-derived fluids. However, partial melting of subducting oceanic crust has also been proposed to contribute to the melt generation process, especially when young and hot lithosphere is being subducted. The isotopic composition of boron measured in situ in olivine-hosted primitive melt inclusions in a basaltic andesite from Mt. Shasta, California, is characterized by large negative values that are also highly variable (delta(11)B = -21.3 to -0.9 per mil). The boron concentrations, from 0.7 to 1.6 parts per million, are lower than in most other arc lavas. The relation between concentration and isotopic composition of boron observed here supports a hypothesis that materials left after dehydration of the subducting slab may have contributed to the generation of basaltic andesite lavas at Mt. Shasta. PMID:11452119

  18. Tectonic and source controls on granite melt chemistry

    NASA Astrophysics Data System (ADS)

    Brown, M.

    2012-12-01

    boundaries, so equilibrium is possible for elements concentrated in minerals located along these boundaries or sequestered close to the edges of the hydrate, whereas in fluid present melting, melt pockets form at Qtz-Flds grain junctions, which may limit the opportunity for equilibration with trace elements in accessory minerals associated with or sequestered in hydrate phases. Syn-anatectic deformation is important; diffusion accommodated grain-boundary sliding allows melt migration along grain boundaries, which enables better interaction between mineral grains and melt, whereas diffusion creep by dissolution-precipitation favors equilibration of grain surface compositions with melt. Deformation also assists rapid melt migration, which may inhibit equilibration between melt and residue. Commonly, leucosomes exhibit either strong positive Eu anomalies with low Zr, recording early crystallization of Flds and Qtz, or compositions with strong negative Eu anomalies and high Zr, representing fractionated melt. This contrast is generated as melt passes through crust that is cooler than the liquidus, causing crystallization on channel walls. There is a continuous process of crystallization/fractionation during migration until evolved melt crosses the solidus at a melt extraction point, after which if the volume is sufficient it ascends rapidly to the upper crust. Thus, residual source rocks were both zones of melt generation and zones of melt transfer from the deeper crust.

  19. Reaction Infiltration Instabilities in Partially Molten Rocks

    NASA Astrophysics Data System (ADS)

    Pec, M.; Holtzman, B. K.; Zimmerman, M. E.; Kohlstedt, D. L.

    2015-12-01

    Tabular dunites in ophiolites are thought to form high-permeability, melt channels due to a positive feedback between melt flow and melt-solid reaction in the upper mantle. Reaction-infiltration instability (RII) theory predicts whether or not channels emerge from background flow. To test the applicability of RII theory to mantle rocks, we sandwiched a partially molten rock between a melt reservoir and a porous sink. Hot-pressed 50:50 mixtures of olivine (Ol) and clinopyroxene (Cpx) with either 4, 10 or 20 vol% alkali basalt formed ~4 mm long cylinders of partially molten rock. Source and sink are disks of alkali basalt and porous alumina. We annealed the melt-rock-sink triplets for up to 5 h at a confining pressure of Pc=300 MPa with effective pressure Pe=0 to 299.9 MPa at T=1200° or 1250°C. The melt fraction in the partially molten rock influences the permeability, which, together with the applied pressure gradient, controls the melt migration velocity. The temperature influences the reaction rate. Melt velocity and reaction rate are fundamental parameters in RII theory. In experiments, two distinct features form due to melt migration, 1) a planar reaction layer (RL) and 2) finger-shaped channels. Both the RL and the channels contain Ol+melt with no Cpx, indicating that the reaction melt1+Cpx→melt2+Ol occurs. The channels develop only if the melt velocity is >5µm/s. Once a channel reaches the porous sink, a large increase in the effective permeability is detected. The morphology and spacing of the channels depends on the initial melt fraction. With 20 vol% melt, multiple, voluminous channels with a spacing of 1.8±0.5 mm develop. At lower melt contents, fewer, thinner channels with a spacing of ~3 mm develop. The channel spacing predicted by theory is about a factor 2-4 smaller than observed. Our results indicate that RII theory provides a solid framework for investigating melt migration in experiments and potentially a basis for extrapolation to mantle

  20. Optically induced melting of colloidal crystals and their recrystallization.

    PubMed

    Harada, Masashi; Ishii, Masahiko; Nakamura, Hiroshi

    2007-04-15

    Colloidal crystals melt by applying focused light of optical tweezers and recrystallize after removing it. The disturbed zone by the light grows radially from the focus point and the ordering starts from the interface with the crystal. Although the larger disturbed zone is observed for the higher power optical tweezers, a master curve is extracted by normalization of the disturbed zone. The temporal changes of the normalized disturbed zone are well described with exponential functions, indicating that the melting and recrystallization process is governed by a simple relaxation mechanism.

  1. Melting phase relation of nominally anhydrous, carbonated pelitic-eclogite at 2.5-3.0 GPa and deep cycling of sedimentary carbon

    NASA Astrophysics Data System (ADS)

    Tsuno, Kyusei; Dasgupta, Rajdeep

    2011-05-01

    We have experimentally investigated melting phase relation of a nominally anhydrous, carbonated pelitic eclogite (HPLC1) at 2.5 and 3.0 GPa at 900-1,350°C in order to constrain the cycling of sedimentary carbon in subduction zones. The starting composition HPLC1 (with 5 wt% bulk CO2) is a model composition, on a water-free basis, and is aimed to represent a mixture of 10 wt% pelagic carbonate unit and 90 wt% hemipelagic mud unit that enter the Central American trench. Sub-solidus assemblage comprises clinopyroxene + garnet + K-feldspar + quartz/coesite + rutile + calcio-ankerite/ankeritess. Solidus temperature is at 900-950°C at 2.5 GPa and at 900-1,000°C at 3.0 GPa, and the near-solidus melt is K-rich granitic. Crystalline carbonates persist only 50-100°C above the solidus and at temperatures above carbonate breakdown, carbon exists in the form of dissolved CO2 in silica-rich melts and as a vapor phase. The rhyodacitic to dacitic partial melt evolves from a K-rich composition at near-solidus condition to K-poor, and Na- and Ca-rich composition with increasing temperature. The low breakdown temperatures of crystalline carbonate in our study compared to those of recent studies on carbonated basaltic eclogite and peridotite owes to Fe-enrichment of carbonates in pelitic lithologies. However, the conditions of carbonate release in our study still remain higher than the modern depth-temperature trajectories of slab-mantle interface at sub-arc depths, suggesting that the release of sedimentary carbonates is unlikely in modern subduction zones. One possible scenario of carbonate release in modern subduction zones is the detachment and advection of sedimentary piles to hotter mantle wedge and consequent dissolution of carbonate in rhyodacitic partial melt. In the Paleo-NeoProterozoic Earth, on the other hand, the hotter slab-surface temperatures at subduction zones likely caused efficient liberation of carbon from subducting sedimentary carbonates. Deeply subducted

  2. Shocked Feldspar in L Chondrites: Deformation, Transformation and Local Melting

    NASA Astrophysics Data System (ADS)

    Fudge, C.; Sharp, T. G.

    2016-08-01

    We present textures and compositional profiles of