Sample records for particulate matter sampling

  1. 40 CFR 60.285a - Test methods and procedures.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... performance test. (b) The owner or operator must determine compliance with the filterable particulate matter... used to determine the filterable particulate matter concentration. The sampling time and sample volume... repeat performance tests for filterable particulate matter at intervals no longer than 5 years following...

  2. Soil separator and sampler and method of sampling

    DOEpatents

    O'Brien, Barry H [Idaho Falls, ID; Ritter, Paul D [Idaho Falls, ID

    2010-02-16

    A soil sampler includes a fluidized bed for receiving a soil sample. The fluidized bed may be in communication with a vacuum for drawing air through the fluidized bed and suspending particulate matter of the soil sample in the air. In a method of sampling, the air may be drawn across a filter, separating the particulate matter. Optionally, a baffle or a cyclone may be included within the fluidized bed for disentrainment, or dedusting, so only the finest particulate matter, including asbestos, will be trapped on the filter. The filter may be removable, and may be tested to determine the content of asbestos and other hazardous particulate matter in the soil sample.

  3. Demonstration of Novel Sampling Techniques for Measurement of Turbine Engine Volatile and Non-Volatile Particulate Matter (PM) Emissions

    DTIC Science & Technology

    2015-12-30

    FINAL REPORT Demonstration of Novel Sampling Techniques for Measurement of Turbine Engine Volatile and Non-Volatile Particulate Matter (PM...Novel Sampling Techniques for Measurement of Turbine Engine Volatile and Non-Volatile Particulate Matter (PM) Emissions 6. AUTHOR(S) E. Corporan, M...report contains color. 14. ABSTRACT This project consists of demonstrating the performance and viability of two devices to condition aircraft turbine

  4. Ractopamine in particulate matter emitted from beef cattle feedyards and playa wetlands in the Central Plains.

    PubMed

    Wooten, Kimberly J; Sandoz, Melissa A; Smith, Philip N

    2018-04-01

    Beef cattle in the United States are routinely administered ractopamine, a β-adrenergic receptor agonist, to enhance growth. The present study is the first to quantify ractopamine in feedyard-emitted particulate matter and playa wetlands near feedyards. Ractopamine was present in 92% of particulate matter samples, 16% of playa sediment samples, and 3% of playa water samples, at maximum concentrations of 4.7 μg/g, 5.2 ng/g (dry wt), and 271 ng/L, respectively. These data suggest that aerial transmission and deposition of particulate matter is a transport mechanism for ractopamine between feedyards and aquatic systems in the region. Environ Toxicol Chem 2018;37:970-974. © 2017 SETAC. © 2017 SETAC.

  5. 40 CFR 60.285 - Test methods and procedures.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... determine compliance with the particulate matter standards in § 60.282(a) (1) and (3) as follows: (1) Method 5 shall be used to determine the particulate matter concentration. The sampling time and sample... opacity. (c) The owner or operator shall determine compliance with the particular matter standard in § 60...

  6. 40 CFR 60.285 - Test methods and procedures.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... determine compliance with the particulate matter standards in § 60.282(a) (1) and (3) as follows: (1) Method 5 shall be used to determine the particulate matter concentration. The sampling time and sample... opacity. (c) The owner or operator shall determine compliance with the particular matter standard in § 60...

  7. 40 CFR 60.285 - Test methods and procedures.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... determine compliance with the particulate matter standards in § 60.282(a) (1) and (3) as follows: (1) Method 5 shall be used to determine the particulate matter concentration. The sampling time and sample... opacity. (c) The owner or operator shall determine compliance with the particular matter standard in § 60...

  8. 40 CFR 60.285 - Test methods and procedures.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... determine compliance with the particulate matter standards in § 60.282(a) (1) and (3) as follows: (1) Method 5 shall be used to determine the particulate matter concentration. The sampling time and sample... opacity. (c) The owner or operator shall determine compliance with the particular matter standard in § 60...

  9. Demonstration of Novel Sampling Techniques for Measurement of Turbine Engine Volatile and Non-Volatile Particulate Matter (PM) Emissions

    DTIC Science & Technology

    2017-03-06

    WP-201317) Demonstration of Novel Sampling Techniques for Measurement of Turbine Engine Volatile and Non -volatile Particulate Matter (PM...Engine Volatile and Non -Volatile Particulate Matter (PM) Emissions 6. AUTHOR(S) E. Corporan, M. DeWitt, C. Klingshirn, M.D. Cheng, R. Miake-Lye, J. Peck...the performance and viability of two devices to condition aircraft turbine engine exhaust to allow the accurate measurement of total (volatile and non

  10. Do forests represent a long-term source of contaminated particulate matter in the Fukushima Prefecture?

    PubMed

    Laceby, J Patrick; Huon, Sylvain; Onda, Yuichi; Vaury, Veronique; Evrard, Olivier

    2016-12-01

    The Fukushima Daiichi Nuclear Power Plant (FDNPP) accident resulted in radiocesium fallout contaminating coastal catchments of the Fukushima Prefecture. As the decontamination effort progresses, the potential downstream migration of radiocesium contaminated particulate matter from forests, which cover over 65% of the most contaminated region, requires investigation. Carbon and nitrogen elemental concentrations and stable isotope ratios are thus used to model the relative contributions of forest, cultivated and subsoil sources to deposited particulate matter in three contaminated coastal catchments. Samples were taken from the main identified sources: cultivated (n = 28), forest (n = 46), and subsoils (n = 25). Deposited particulate matter (n = 82) was sampled during four fieldwork campaigns from November 2012 to November 2014. A distribution modelling approach quantified relative source contributions with multiple combinations of element parameters (carbon only, nitrogen only, and four parameters) for two particle size fractions (<63 μm and <2 mm). Although there was significant particle size enrichment for the particulate matter parameters, these differences only resulted in a 6% (SD 3%) mean difference in relative source contributions. Further, the three different modelling approaches only resulted in a 4% (SD 3%) difference between relative source contributions. For each particulate matter sample, six models (i.e. <63 μm and <2 mm from the three modelling approaches) were used to incorporate a broader definition of potential uncertainty into model results. Forest sources were modelled to contribute 17% (SD 10%) of particulate matter indicating they present a long term potential source of radiocesium contaminated material in fallout impacted catchments. Subsoils contributed 45% (SD 26%) of particulate matter and cultivated sources contributed 38% (SD 19%). The reservoir of radiocesium in forested landscapes in the Fukushima region represents a potential long-term source of particulate contaminated matter that will require diligent management for the foreseeable future. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. U.S.-MEXICO BORDER PROGRAM ARIZONA BORDER STUDY--QA ANALYTICAL RESULTS FOR PARTICULATE MATTER IN BLANK SAMPLES

    EPA Science Inventory

    The Particulate Matter in Blank Samples data set contains the analytical results for measurements of two particle sizes in 12 samples. Filters were pre-weighed, loaded into impactors, kept unexposed in the laboratory, unloaded and post-weighed. Positive weight gains for laborat...

  12. A Literature Review of Concentrations and Size Distributions of Ambient Airborne Pb-Containing Particulate Matter

    EPA Science Inventory

    The final 2008 lead (Pb) national ambient air quality standards (NAAQS) revision maintains Pb in total suspended particulate matter as the indicator. However, the final rule permits the use of low-volume PM10 (particulate matter sampled with a 50% cut-point of 10 μm) F...

  13. Ferruginous compounds in the airborne particulate matter of the metropolitan area of Belo Horizonte, Minas Gerais, Brazil.

    PubMed

    Tavares, Fernanda Vasconcelos Fonseca; Ardisson, José Domingos; Rodrigues, Paulo César Horta; Fabris, José Domingos; Fernandez-Outon, Luis Eugenio; Feliciano, Vanusa Maria Delage

    2017-08-01

    Samples of soil, iron ore, and airborne particulate matter (size <10 μm) were analyzed with the main goal of investigating the differentiating physicochemical properties of their ferruginous compounds. These data were used to identify whether the sources of airborne particulate matter in the metropolitan area of Belo Horizonte, Minas Gerais, Brazil, are either from natural origin, as, for instance, re-suspension of particles from soil, or due to anthropogenic activities, meaning that it would be originated from the many iron ore minings surrounding the metropolitan area. Numerical simulations were used to model the atmospheric dispersion of the airborne particulate matter emitted by iron mining located at the Iron Quadrangle geodomain, Minas Gerais. Results from these numerical simulations supported identifying the sites with the highest concentrations of airborne particulate matter in the metropolitan area. Samples of these suspended materials were collected at the selected sites by using high-volume air samplers. The physicochemical features of the solid materials were assessed by X-ray fluorescence, X-ray diffraction, magnetometry, and 57 Fe Mössbauer spectroscopy. The soil materials were found to be rich in quartz, aluminum, organic matter, and low contents of iron, mainly as low crystalline iron oxides. The samples of the iron ores, on the other hand, contain high concentration of iron, dominantly as relatively pure and crystalline hematite (α-Fe 2 O 3 ). The samples of the airborne particulate matter are rich in iron, mainly as hematite, but contained also quartz, aluminum, and calcium. Mössbauer spectroscopy was used to evaluate the hyperfine structure of 57 Fe of the hematite both from the iron ore and the soil samples. The structural characteristics of the hematite of these particulate materials were further explored. The direct influence of the iron ore mining on the composition of the airborne particulate matter was clearly evidenced based on the trace ability of hematite to its source of emission. Even the atmospheric air on regions relatively far away from the mining activities is also significantly influenced.

  14. Particulate carbon and nitrogen and suspended particulate matter in the Sacramento River at Rio Vista, California, January 3 - May 26, 1983 and October 31, 1983 - November 29, 1984

    USGS Publications Warehouse

    Hager, Stephen W.

    1994-01-01

    Particulate matter was collected at Rio Vista, California, in two study periods; the first, from January 3 to May 26, 1983; the second from October 31, 1983 to November 29, 1984. Concentrations of suspended particulate matter were measured gravimetrically on silver membrane filters. The pooled standard deviation on replicated samples was 1.4 mg/L, giving a coefficient of variation of 5.7 percent. Concentrations of particulate carbon and nitrogen were measured during a Perkin-Elmer model 240C elemental analyzer to combust material collected on glass fiber filters. Refrigeration of samples prior to filtration was shown to be a likely influence on precision of duplicate analyses. Median deviations between duplicates for carbon were 5.4 percent during the first study period and 8.9 percent during the second. For nitrogen, median deviations were 4.9 percent and 7.2 percent, respectively. This report presents the data for concentrations of suspended particulate material, the duplicate analyses for particulate carbon and nitrogen, and the volumes of sample filtered for the particulate carbon and nitrogen analyses for both studies. Not all samples collected during the second study have been analyzed for particulate carbon and nitrogen.

  15. STATISTICAL DISTRIBUTIONS OF PARTICULATE MATTER AND THE ERROR ASSOCIATED WITH SAMPLING FREQUENCY. (R828678C010)

    EPA Science Inventory

    The distribution of particulate matter (PM) concentrations has an impact on human health effects and the setting of PM regulations. Since PM is commonly sampled on less than daily schedules, the magnitude of sampling errors needs to be determined. Daily PM data from Spokane, W...

  16. Characterization of functional groups of airborne particulate matter

    NASA Astrophysics Data System (ADS)

    Baitimirova, M.; Katkevics, J.; Baumane, L.; Bakis, E.; Viksna, A.

    2013-12-01

    Particulate matter of organic combustibles burning consists of various hydrocarbons and radicals, which may cause harmful impact to human health. In this study solid particulate matter were collected on the filters from burning of various combustibles in a burning chamber and from atmosphere of city of Riga by dichotomous impactor. FTIR spectra were obtained before and after samples' treatment. Absorptions associated with aliphatic and aromatic hydrocarbons and alcohol functional groups were observed in the FTIR spectra. Free radicals of particulate matter were detected by electron paramagnetic resonance (EPR).

  17. Environmental studies in two communes of Santiago de Chile by the analysis of magnetic properties of particulate matter deposited on leaves of roadside trees

    NASA Astrophysics Data System (ADS)

    Muñoz, David; Aguilar, Bertha; Fuentealba, Raúl; Préndez, Margarita

    2017-03-01

    Emissions from motor vehicles are considered to be one of the main sources of airborne particulate matter in Santiago. International researchers have shown that particulate matter contains metal oxides and magnetic particles, both of which are emitted mainly from vehicles exhaust pipes. On the other hand, trees are effective in reducing such contamination, so that they act as passive collectors of particulate matter. This work presents the results obtained from the first magnetic study of the particulate matter collected in two areas of the city of Santiago de Chile. Magnetic susceptibility and Saturation Isothermic Remanent Magnetization (SIRM) were determined in leaves from abundant urban trees and from urban dust samples. Results indicate that most of the samples contain ferromagnetic minerals with magnetite (Fe3O4) as the main carrier. Values of magnetic susceptibility (SI ×10-6 m3/kg) in the range 0.04-0.24 for leaves and in the range 10-45 for urban dust were determinated. In one of the city areas studied, significant correlation between the particulate matter deposited on leaves of Platanus orientalis and measured traffic flows was obtained. In addition, it was possible to estimate that the species Platanus orientalis and Acer negundo have a better ability to capture particulate matter than the species Robinia pseudoacacia.

  18. Green Ocean Amazon 2014/15 High-Volume Filter Sampling: Atmospheric Particulate Matter of an Amazon Tropical City and its Relationship to Population Health Field Campaign Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Machado, C. M.; Santos, Erickson O.; Fernandes, Karenn S.

    Manaus, the capital of the Brazilian state of Amazonas, is developing very rapidly. Its pollution plume contains aerosols from fossil fuel combustion mainly due to vehicular emission, industrial activity, and a thermal power plant. Soil resuspension is probably a secondary source of atmospheric particles. The plume transports from Manaus to the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility ARM site at Manacapuru urban pollutants as well as pollutants from pottery factories along the route of the plume. Considering the effects of particulate matter on health, atmospheric particulate matter was evaluated at this site as partmore » of the ARM Facility’s Green Ocean Amazon 2014/15 (GoAmazon 2014/15) field campaign. Aerosol or particulate matter (PM) is typically defined by size, with the smaller particles having more health impact. Total suspended particulate (TSP) are particles smaller than 100 μm; particles smaller than 2.5 μm are called PM2.5. In this work, the PM2.5 levels were obtained from March to December of 2015, totaling 34 samples and TSP levels from October to December of 2015, totaling 17 samples. Sampling was conducted with PM2.5 and TSP high-volume samplers using quartz filters (Figure 1). Filters were stored during 24 hours in a room with temperature (21,1ºC) and humidity (44,3 %) control, in order to do gravimetric analyses by weighing before and after sampling. This procedure followed the recommendations of the Brazilian Association for Technical Standards local norm (NBR 9547:1997). Mass concentrations of particulate matter were obtained from the ratio between the weighted sample and the volume of air collected. Defining a relationship between particulate matter (PM2.5 and TSP) and respiratory diseases of the local population is an important goal of this project, since no information exists on that topic.« less

  19. Novel Sampling Techniques for Measurement of Turbine Engine Total Particulate Matter Emissions

    EPA Science Inventory

    This is the first progress report of a study to evaluate two different condensation devices for the measurement of the total (volatile + non-volatile) particulate matter (PM) emissions from aircraft turbine engines by direct sampling at the engine exit. The characteristics of th...

  20. Characterization of metals emitted from motor vehicles.

    PubMed

    Schauer, James J; Lough, Glynis C; Shafer, Martin M; Christensen, William F; Arndt, Michael F; DeMinter, Jeffrey T; Park, June-Soo

    2006-03-01

    A systematic approach was used to quantify the metals present in particulate matter emissions associated with on-road motor vehicles. Consistent sampling and chemical analysis techniques were used to determine the chemical composition of particulate matter less than 10 microm in aerodynamic diameter (PM10*) and particulate matter less than 2.5 microm in aerodynamic diameter (PM2.5), including analysis of trace metals by inductively coupled plasma mass spectrometry (ICP-MS). Four sources of metals were analyzed in emissions associated with motor vehicles: tailpipe emissions from gasoline- and diesel-powered vehicles, brake wear, tire wear, and resuspended road dust. Profiles for these sources were used in a chemical mass balance (CMB) model to quantify their relative contributions to the metal emissions measured in roadway tunnel tests in Milwaukee, Wisconsin. Roadway tunnel measurements were supplemented by parallel measurements of atmospheric particulate matter and associated metals at three urban locations: Milwaukee and Waukesha, Wisconsin, and Denver, Colorado. Ambient aerosol samples were collected every sixth day for one year and analyzed by the same chemical analysis techniques used for the source samples. The two Wisconsin sites were studied to assess the spatial differences, within one urban airshed, of trace metals present in atmospheric particulate matter. The measurements were evaluated to help understand source and seasonal trends in atmospheric concentrations of trace metals. ICP-MS methods have not been widely used in analyses of ambient aerosols for metals despite demonstrated advantages over traditional techniques. In a preliminary study, ICP-MS techniques were used to assess the leachability of trace metals present in atmospheric particulate matter samples and motor vehicle source samples in a synthetic lung fluid.

  1. Design and Calibration of a High Volume Cascade Impactor

    ERIC Educational Resources Information Center

    Gussman, R. A.; And Others

    1973-01-01

    This study was to develop an air sampling device capable of classifying large quantities of airborne particulate matter into discrete size fractions. Such fractionation will facilitate chemical analysis of the various particulate pollutants and thereby provide a more realistic assessment of the effects of particulate matter on human beings. (BL)

  2. Source Testing for Particulate Matter.

    ERIC Educational Resources Information Center

    DeVorkin, Howard

    Developed for presentation at the 12th Conference on Methods in Air Pollution and Industrial Hygiene Studies, University of Southern California, April, 1971, this outline covers procedures for the testing of particulate matter. These are: (1) basic requirements, (2) information required, (3) collection of samples, (4) processing of samples, (5)…

  3. Polycyclic aromatic hydrocarbons in the urban atmospheric particulate matter in the city of Naples (Italy)

    NASA Astrophysics Data System (ADS)

    Caricchia, Anna Maria; Chiavarini, Salvatore; Pezza, Massimo

    An investigation on PAH in the atmospheric particulate matter of the city of Naples has been carried out. Urban atmospheric particulate matter was sampled in three sampling sites (West, East and central areas of the city), whose characteristics were representative of the prevailing conditions. In each site, 24 h samplings for 7 consecutive days were performed during three sampling campaigns, in 1996-1997. The results were comparable with those reported in literature for similar investigations. Total PAH were in the range 2-130 ng m -3, with a seasonal variation (autumn/winter vs. summer) in the range 1.5-4.5. The relative contribution of diesel engines vs. gasoline fuelled engines was evidenced.

  4. Determination of Vanadium, Tin and Mercury in Atmospheric Particulate Matter and Cement Dust Samples by Direct Current Plasma Atomic Emission Spectrometry.

    ERIC Educational Resources Information Center

    Hindy, Kamal T.; And Others

    1992-01-01

    An atmospheric pollution study applies direct current plasma atomic emission spectrometry (DCP-AES) to samples of total suspended particulate matter collected in two industrial areas and one residential area, and cement dust collected near major cement factories. These samples were analyzed for vanadium, tin, and mercury. The results indicate the…

  5. Characterization of a humic acid-like brown substance in airborne particulate matter and tentative identification of its origin

    NASA Astrophysics Data System (ADS)

    Mukai, Hitoshi; Ambe, Yoshinari

    A brown substance having the solubility characteristics of humic acid was extracted from airborne particulate matter sampled in a rural area of Japan. This brown substance contributed 0.6-3% of the total carbon in airborne particulate matter. This fraction also contained pollen protein in samples collected during the pollen season. Patterns of elution from gel permeation chromatography suggested a molecular weight range from 500 to 10,000, with a still higher upper limit for one sample. The infrared spectra were compared with those of humic acid from the local soil, extracts from dead leaves, smoke from burning plant matter, and soot from automotive exhaust, all possible sources of the brown substance. The closest similarity was with the extract smoke. This identification is strengthened by lack of correlation of the brown substance with aluminum, a tracer for soil content, and a value of K/Fe ratio in the associated particulate matter higher than any plausible source other than combustion. It is probable that the primary source of this brown, high molecular weight acidic materials is agricultural burning.

  6. Determination of biomass burning tracers in air samples by GC/MS

    NASA Astrophysics Data System (ADS)

    Janoszka, Katarzyna

    2018-01-01

    Levoglucosan (LG) as a main cellulose burning product at 300°C is a biomass burning tracer. LG characterize by relatively high molar mass and it is sorbed by particulate matter. In the study of air pollution monitoring LG is mainly analyzed in particulate matter, PM1 and PM2,5. The tracer create relatively high O-H…O bond and weaker C-H…O bond. Due to the hydrogen bond, LG dissolves very well in water. Analytical procedure of LG determination include: extraction, derivatization and analysis by gas chromatography coupled with mass spectrometry detector. In water samples levoglucosan is determined by liquid chromatography. The paper presents a methodology for particulate matter samples determination their analysis by gas chromatography coupled with a mass spectrometry detector. Determination of LG content in particulate matter was performed according to an analytical method based on simultaneous pyridine extraction and derivatization using N,O-bis (trimethylsilyl) trifluoroacetamide and trimethylchlorosilane mixture (BSTFA: TMCS, 99: 1).

  7. Evaluation of Airborne Particulate Matter and Metals Data in Personal, Indoor and Outdoor Environments using ED-XRF and ICP-MS and Co-located Duplicate Samples

    EPA Science Inventory

    Factors and sources affecting measurement uncertainty in airborne particulate matter (PM) gravimetric measurements and elemental analyses were investigated as part of the Windsor Ontario Exposure Assessment Study (WOEAS). The assessment was made using co-located duplicate sample...

  8. Dirty breathing

    NASA Astrophysics Data System (ADS)

    Wisham, M.

    2017-12-01

    Breathing issues befall most asthmatics. However, the symptoms are not caused randomly. Particulate matter is a cause that has been collected and sampled at several bus stops. The following experiment provides the results of collected particulate matter in several locations around LSU.

  9. Composition of diesel exhaust with particular reference to particle bound organics including formation of artifacts.

    PubMed

    Lies, K H; Hartung, A; Postulka, A; Gring, H; Schulze, J

    1986-01-01

    For particulate emissions, standards were established by the US EPA in February 1980. Regulations limiting particulates from new light duty diesel vehicles are valid by model year 1982. The corresponding standards on a pure mass basis do not take into account any chemical character of the diesel particulate matter. Our investigation of the material composition shows that diesel particulates consist mainly of soot (up to 80% by weight) and adsorptively bound organics including polycyclic aromatic hydrocarbons (PAH). The qualitative and quantitative nature of hydrocarbon compounds associated with the particulates is dependent not only on the combustion parameters of the engine but also to an important degree on the sampling conditions when the particulates are collected (dilution ratio, temperature, filter material, sampling time etc.). Various methods for the analyses of PAH and their oxy- and nitro-derivatives are described including sampling, extraction, fractionation and chemical analysis. Quantitative comparison of PAH, nitro-PAH and oxy-PAH from different engines are given. For assessing mutagenicity of particulate matter, short-term biological tests are widely used. These biological tests often need a great amount of particulate matter requiring prolonged filter sampling times. Since it is well known that facile PAH oxidation can take place under the conditions used for sampling and analysis, the question rises if these PAH-derivates found in particle extracts partly or totally are produced during sampling (artifacts). Various results concerning nitro- and oxy-PAH are presented characterizing artifact formation as a minor problem under the conditions of the Federal Test Procedure. But results show that under other sampling conditions, e.g. electrostatic precipitation, higher NO2-concentrations and longer sampling times, artifact formation can become a bigger problem. The more stringent particulate standard of 0.2 g/mi for model years 1986 and 1987 respectively requires particulate trap technology. Preliminary investigations of the efficiency of ceramic filters used reveal that the reduction of the adsorptively bound organics is lower than the decrease of the solid carbonaceous fractions.

  10. Influence of Acidification on the Partitioning of Steroid Hormones among Filtrate, Filter Media, and Retained Particulate Matter.

    PubMed

    Havens, Sonya M; Hedman, Curtis J; Hemming, Jocelyn D C; Mieritz, Mark G; Shafer, Martin M; Schauer, James J

    2016-09-01

    Hormone contamination of aquatic systems has been shown to have deleterious effects on aquatic biota. However, the assessment of hormone contamination of aquatic environments requires a quantitative evaluation of the potential effects of sample preservation on hormone concentrations. This study investigated the influence of acidification (pH 2) of surface water samples on the partitioning of hormones among filtrate, filter media, and filter-retained particulate matter. Hormones were spiked into unpreserved and sulfuric acid-preserved ultrapure water and surface water runoff samples. The samples were filtered, and hormones were extracted from the filter and filtrate and analyzed by high-performance liquid chromatography. Acidification did not influence the partitioning of hormones onto the filter media. For the majority of the hormones investigated in this study, the partitioning of hormones to the filter-retained particulate matter was not influenced by acidification. Acidification increased the partitioning of progesterone and melengestrol acetate onto the retained particulate matter (about 25% for both analytes). Incorporation of an isotopically labeled internal standard (ISTD) for progesterone accounted for the loss of progesterone to the filter-retained particulates and resulted in accurate concentrations of progesterone in the filtrate. The incorporation of an ISTD for melengestrol acetate, however, was unable to account for the loss of melengestrol acetate to the retained particulates and resulted in underestimations of melengestrol acetate in the filtrate. Our results indicate that the analysis of melengestrol acetate in acid preserved surface runoff samples should be conducted on the filter-retained particulates as well as the filtrate. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  11. Representations of Fundamental Chemistry Concepts in Relation to the Particulate Nature of Matter

    ERIC Educational Resources Information Center

    Kirbulut, Zubeyde Demet; Beeth, Michael Edward

    2013-01-01

    This study investigated high school students' understanding of fundamental chemistry concepts - states of matter, melting, evaporation, condensation, boiling, and vapor pressure, in relation to their understanding of the particulate nature of matter. A sample of six students (four females and two males) enrolled in a second year chemistry course…

  12. Representations of Fundamental Chemistry Concepts in Relation to the Particulate Nature of Matter

    ERIC Educational Resources Information Center

    Kirbulut, Zübeyde Demet; Beeth, Michael Edward

    2013-01-01

    This study investigated high school students' understanding of fundamental chemistry concepts--states of matter, melting, evaporation, condensation, boiling, and vapor pressure, in relation to their understanding of the particulate nature of matter. A sample of six students (four females and two males) enrolled in a second year chemistry course at…

  13. Evolution and current understanding of physicochemical characterization of particulate matter from reactivity controlled compression ignition combustion on a multicylinder light-duty engine

    DOE PAGES

    Storey, John Morse; Curran, Scott J.; Lewis, Samuel A.; ...

    2016-08-04

    Low-temperature compression ignition combustion can result in nearly smokeless combustion, as indicated by a smoke meter or other forms of soot measurement that rely on absorbance due to elemental carbon content. Highly premixed low-temperature combustion modes do not form particulate matter in the traditional pathways seen with conventional diesel combustion. Previous research into reactivity controlled compression ignition particulate matter has shown, despite a near zero smoke number, significant mass can be collected on filter media used for particulate matter certification measurement. In addition, particulate matter size distributions reveal that a fraction of the particles survive heated double-dilution conditions. This papermore » summarizes research completed at Oak Ridge National Laboratory to date on characterizing the nature, chemistry and aftertreatment considerations of reactivity controlled compression ignition particulate matter and presents new research highlighting the importance of injection strategy and fuel composition on reactivity controlled compression ignition particulate matter formation. Particle size measurements and the transmission electron microscopy results do show the presence of soot particles; however, the elemental carbon fraction was, in many cases, within the uncertainty of the thermal–optical measurement. Particulate matter emitted during reactivity controlled compression ignition operation was also collected with a novel sampling technique and analyzed by thermal desorption or pyrolysis gas chromatography mass spectroscopy. Particulate matter speciation results indicated that the high boiling range of diesel hydrocarbons was likely responsible for the particulate matter mass captured on the filter media. Finally, to investigate potential fuel chemistry effects, either ethanol or biodiesel were incorporated to assess whether oxygenated fuels may enhance particle emission reduction.« less

  14. Evolution and current understanding of physicochemical characterization of particulate matter from reactivity controlled compression ignition combustion on a multicylinder light-duty engine

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Storey, John Morse; Curran, Scott J.; Lewis, Samuel A.

    Low-temperature compression ignition combustion can result in nearly smokeless combustion, as indicated by a smoke meter or other forms of soot measurement that rely on absorbance due to elemental carbon content. Highly premixed low-temperature combustion modes do not form particulate matter in the traditional pathways seen with conventional diesel combustion. Previous research into reactivity controlled compression ignition particulate matter has shown, despite a near zero smoke number, significant mass can be collected on filter media used for particulate matter certification measurement. In addition, particulate matter size distributions reveal that a fraction of the particles survive heated double-dilution conditions. This papermore » summarizes research completed at Oak Ridge National Laboratory to date on characterizing the nature, chemistry and aftertreatment considerations of reactivity controlled compression ignition particulate matter and presents new research highlighting the importance of injection strategy and fuel composition on reactivity controlled compression ignition particulate matter formation. Particle size measurements and the transmission electron microscopy results do show the presence of soot particles; however, the elemental carbon fraction was, in many cases, within the uncertainty of the thermal–optical measurement. Particulate matter emitted during reactivity controlled compression ignition operation was also collected with a novel sampling technique and analyzed by thermal desorption or pyrolysis gas chromatography mass spectroscopy. Particulate matter speciation results indicated that the high boiling range of diesel hydrocarbons was likely responsible for the particulate matter mass captured on the filter media. Finally, to investigate potential fuel chemistry effects, either ethanol or biodiesel were incorporated to assess whether oxygenated fuels may enhance particle emission reduction.« less

  15. Settling Efficiency of Urban Particulate Matter Transported by Stormwater Runoff.

    PubMed

    Carbone, Marco; Penna, Nadia; Piro, Patrizia

    2015-09-01

    The main purpose of control measures in urban areas is to retain particulate matter washed out by stormwater over impermeable surfaces. In stormwater control measures, particulate matter removal typically occurs via sedimentation. Settling column tests were performed to examine the settling efficiency of such units using monodisperse and heterodisperse particulate matter (for which the particle size distributions were measured and modelled by the cumulative gamma distribution). To investigate the dependence of settling efficiency from the particulate matter, a variant of the evolutionary polynomial regression (EPR), a Microsoft Excel function based on multi-objective EPR technique (EPR-MOGA), called EPR MOGA XL, was used as a data-mining strategy. The results from this study have shown that settling efficiency is a function of the initial total suspended solids (TSS) concentration and of the median diameter (d50 index), obtained from the particle size distributions (PSDs) of the samples.

  16. Genotoxic substances in the St. Lawrence system. 1: Industrial genotoxins sorbed to particulate matter in the St. Lawrence, St. Maurice, and Saguenay rivers, Canada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    White, P.A.; Rasmussen, J.B.; Blaise, C.

    1998-02-01

    Previous investigations of organic genotoxins in industrial effluents discharged into the St. Lawrence River system (Quebec, Canada) indicated that a substantial fraction of the genotoxicity is adsorbed to suspended particulate matter. This study used the SOS Chromotest to investigate the presence, potency, and behavior of particle-bound genotoxins in the downstream ecosystem. The results indicate that although extracts of both suspended and sedimented particulate matter are genotoxic, suspended particulate matter samples are more potent in the absence of S9 activation, with the reverse being true for bottom sediments. The results confirmed a positive relationship between the genotoxicity of bottom sediment extractsmore » and sediment organic matter content. A similar relationship between organic matter content and total polycyclic aromatic hydrocarbon (PAH) concentration indicates that putative genotoxins have physicochemical properties similar to the PAH class of contaminants. Conversion of PAH values to benzo[a]pyrene equivalents indicates that measured PAHs only account for a small fraction ({approximately}10%) of the observed SOS Chromotest response. Sites that receive discharges from foundries, aluminum refineries, and petroleum refineries yielded several of the most genotoxic samples. Further analyses revealed that the genotoxicity of suspended and sedimented particulate matter extracts is empirically related to the genotoxicity of industrial discharges. Comparisons of total genotoxicity levels in suspended particulates and bottom sediments suggest that direct-acting substances adsorbed to suspended matter are rapidly degraded and/or converted to more stable progenotoxins upon deposition. Further research is required to test this hypothesis and investigate effects on indigenous biota.« less

  17. SAMPLING ARTIFACT ESTIMATES FOR ALKANES, HOPANES, AND ALIPHATIC CARBOXYLIC ACIDS

    EPA Science Inventory

    Sampling artifacts for molecular markers from organic speciation of particulate matter were investigated by analyzing forty-one samples collected in Philadelphia as a part of the Northeast Oxidant and Particulate Study (NEOPS). Samples were collected using a high volume sampler ...

  18. Trueness, Precision, and Detectability for Sampling and Analysis of Organic Species in Airborne Particulate Matter

    EPA Science Inventory

    Recovery. precision, limits of detection and quantitation, blank levels, calibration linearity, and agreement with certified reference materials were determined for two classes of organic components of airborne particulate matter, polycyclic aromatic hydrocarbons and hopanes usin...

  19. HIGH VOLUME INJECTION FOR GCMS ANALYSIS OF PARTICULATE ORGANIC SPECIES IN AMBIENT AIR

    EPA Science Inventory

    Detection of organic species in ambient particulate matter typically requires large air sample volumes, frequently achieved by grouping samples into monthly composites. Decreasing the volume of air sample required would allow shorter collection times and more convenient sample c...

  20. QUANTIFYING HAZARDOUS SPECIES IN PARTICULATE MATTER DERIVED FROM FOSSIL-FUEL COMBUSTION

    EPA Science Inventory

    An analysis protocol that combines X-ray absorption near-edge structure spectroscopy with selective leaching has been developed to examine hazardous species in size- segregated particulate matter (PM) samples derived from the combustion of fossil fuels. The protocol has been used...

  1. An evaluation of indoor and outdoor biological particulate matter (BioPM)

    EPA Science Inventory

    Monitoring of indoor and ambient particulate matter (PM) and the characterization of the content for biological aerosol concentrations has not been extensively performed. Samples from urban and rural North Carolina, and Denver, CO, were collected and analyzed as the goal of this ...

  2. 75 FR 80117 - Methods for Measurement of Filterable PM10

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-21

    ...This action promulgates amendments to Methods 201A and 202. The final amendments to Method 201A add a particle-sizing device to allow for sampling of particulate matter with mean aerodynamic diameters less than or equal to 2.5 micrometers (PM2.5 or fine particulate matter). The final amendments to Method 202 revise the sample collection and recovery procedures of the method to reduce the formation of reaction artifacts that could lead to inaccurate measurements of condensable particulate matter. Additionally, the final amendments to Method 202 eliminate most of the hardware and analytical options in the existing method, thereby increasing the precision of the method and improving the consistency in the measurements obtained between source tests performed under different regulatory authorities. This action also announces that EPA is taking no action to affect the already established January 1, 2011 sunset date for the New Source Review (NSR) transition period, during which EPA is not requiring that State NSR programs address condensable particulate matter emissions.

  3. Kuwaiti oil fires—Particulate monitoring

    NASA Astrophysics Data System (ADS)

    Husain, Tahir; Amin, Mohamed B.

    The total suspended particulate (TSP) matters using a high-volume sampler and inhalable particulate matters using PM-10 samplers were collected at various locations in the Eastern Province of Saudi Arabia during and after the Kuwaiti oil fires. The collected samples were analysed for toxic metals and oil hydrocarbon concentrations including some carcinogenic organic compounds in addition to gravimetric analysis. The concentration values of particulate matters were determined on a daily basis at Dhahran. Abqaiq, Rahima, Tanajib and Jubail locations. The analyses of the filters show a high concentration of the inhalable particulate at various locations, especially when north or northwest winds were blowing. It was found that the inhalable particulate concentration exceeded the Meteorology and Environmental Protection Administration (MEPA) permissible limit of 340 μg m- 3 at most of these locations during May-October 1991. A trend between the total suspended particulate and inhalable particulate measured concurrently at the same locations was observed and a regression equation was developed to correlate PM-10 data with the total suspended particulate data.

  4. Determination of Methylamines and Trimethylamine-N-oxide in particulate matter by non-suppressed ion chromatography

    USDA-ARS?s Scientific Manuscript database

    An ion chromatography method with non-suppressed conductivity detection was developed for the simultaneous determination of methylamines (methylamine, dimethylamine, trimethylamine) and trimethylamine-N-oxide in particulate matter air samples. The analytes were well separated by means of cation-exch...

  5. SOURCE SAMPLING FINE PARTICULATE MATTER: WOOD-FIRED INDUSTRIAL BOILER

    EPA Science Inventory

    The report provides a profile for a wood-fired industrial boiler equipped with a multistage electrostatic precipitator control device. Along with the profile of emissions of fine particulate matter of aerodynamic diameter of 2.5 micrometers or less (PM-2.5), data are also provide...

  6. Chemical Characterization of Coarse Particulate Matter in the Desert Southwest - Pinal County Arizona, USA

    EPA Science Inventory

    The Desert Southwest Coarse Particulate Matter Study was undertaken of ambient concentrations and the composition of fine and coarse particles in rural, arid environments. Sampling was conducted in Pinal County, Arizona between February 2009 and February 2010. The goals of this ...

  7. Source identification of coarse particles in the Desert Southwest, USA using Positive Matrix Factorization

    EPA Science Inventory

    The Desert Southwest Coarse Particulate Matter Study was undertaken to further our understanding of the spatial and temporal variability and sources of fine and coarse particulate matter (PM) in rural, arid, desert environments. Sampling was conducted between February 2009 and Fe...

  8. RECOVERY OF SEMI-VOLATILE ORGANIC COMPOUNDS DURING SAMPLE PREPARATION: IMPLICATIONS FOR CHARACTERIZATION OF AIRBORNE PARTICULATE MATTER

    EPA Science Inventory

    Semi-volatile compounds present special analytical challenges not met by conventional methods for analysis of ambient particulate matter (PM). Accurate quantification of PM-associated organic compounds requires validation of the laboratory procedures for recovery over a wide v...

  9. INDIVIDUAL PARTICLE ANALYSIS OF PERSONAL SAMPLES FROM THE 1998 BALTIMORE PARTICULATE MATTER STUDY

    EPA Science Inventory

    The United States Environmental Protection Agency (U.S. EPA) recently conducted the 1998 Baltimore Particulate Matter (PM) Epidemiology-Exposure Study of the Elderly. The primary goal of that study was to establish the relationship between outdoor PM concentrations and actual h...

  10. A multiregional survey of nickel in outdoor air particulate matter in China: Implication for human exposure.

    PubMed

    Li, Han; Wan, Yanjian; Chen, Xiao; Cheng, Lu; Yang, Xueyu; Xia, Wei; Xu, Shunqing; Zhang, Hongling

    2018-05-01

    Nickel is a widespread environmental contaminant, and it is toxic to humans in certain forms at high doses. Despite this, nationwide data on nickel in outdoor air particulate matter and human exposure to nickel through inhalation in China are limited. In the present study, 662 outdoor air samples from seven representative provinces such as Shanghai, Hubei, Hunan, Hebei, Guangdong, Yunnan, and Shanxi were collected between March 2013 and February 2014 and analyzed by inductively coupled plasma mass spectrometry. The concentrations of nickel in the air were in the range of 2.1-80.9 ng/m 3 (geometric mean: 14.4 ng/m 3 ). In most areas, the concentrations of nickel were higher in winter and spring than those measured in summer and autumn. The daily intake (median) of nickel through inhalation of air particulate matter was estimated. Although the nickel concentrations in some air samples were high, inhalation of the air particulate matter accounted for a minor part of the total nickel intake; however, the adverse effects of human exposure to nickel through inhalation and its potential sources require more attention, particularly in Shanghai. This is a multiregional survey of nickel in outdoor air particulate matter in China. Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. Demonstration of Novel Sampling Techniques for Measurement of Turbine Engine Volatile and Non-Volatile Particulate Matter (PM) Emissions

    DTIC Science & Technology

    2016-09-01

    AFRL-RQ-WP-TR-2016-0131 DEMONSTRATION OF NOVEL SAMPLING TECHNIQUES FOR MEASUREMENT OF TURBINE ENGINE VOLATILE AND NON-VOLATILE PARTICULATE...MATTER (PM) EMISSIONS Edwin Corporan Fuels and Energy Branch Turbine Engine Division Matthew DeWitt and Chris Klingshirn University of...Energy Branch Turbine Engine Division Turbine Engine Division Aerospace Systems Directorate //Signature// CHARLES W. STEVENS Lead Engineer

  12. EXHAUST EMISSION PATTERNS FROM TWO LIGHT-DUTY DIESEL AUTOMOBILES

    EPA Science Inventory

    Particulate and gaseous emissions from two light-duty diesel automobiles were examined over six operating cycles. Particulate characterizations included mass emission rate, soluble organic content, and trace element content determinations. The particulate matter was sampled using...

  13. RECEPTOR MODELING OF AMBIENT AND PERSONAL EXPOSURE SAMPLES: 1998 BALTIMORE PARTICULATE MATTER EPIDEMIOLOGY-EXPOSURE STUDY

    EPA Science Inventory

    Sources of particulate matter exposure for an elderly population in a city north of Baltimore, MD were evaluated using advanced factor analysis models. Data collected with Versatile Air Pollutant Samplers (VAPS) positioned at a community site, outside and inside of an elderly ...

  14. & Source apportionment of particulate matter in the United States and associations with lung inflammatory Markers

    EPA Science Inventory

    Size-fractionated particulate matter (PM) samples were collected from six U.S. cities and chemically analyzed as part of the Multiple Air Pollutant Study. Particles were administered to cultured lung cells and the production of three different proinflammatory markers was measured...

  15. EVALUATION OF METHODS FOR THE DETERMINATION OF DIESEL-GENERATED FINE PARTICULATE MATTER: PHYSICAL CHARACTERIZATION OF RESULTS

    EPA Science Inventory

    A multi-phase instrument comparison study was conducted on two different diesel engines on a dynamometer to compare commonly used particulate matter (PM) measurement techniques while sampling the same diesel exhaust aerosol and to evaluate inter- and intra-method variability. In...

  16. Size-Differentiated Chemical Composition of Re-Suspended Soil Dust from the Desert Southwest United States

    EPA Science Inventory

    As part of the Desert Southwest Coarse Particulate Matter Study which characterized the composition of fine and coarse particulate matter in Pinal County, AZ, several source samples were collected from several different soil types to assist in source apportionment analysis of the...

  17. IDENTIFICATION OF POSSIBLE SOURCES OF PARTICULATE MATTER IN THE PERSONAL CLOUD USING SEM/EDX

    EPA Science Inventory

    The United States Environmental Protection Agency (U.S. EPA) conducted the Baltimore Particulate Matter (PM) Epidemiology-Exposure Study of the Elderly during the summer of 1998. The study design included PM2.5 samples obtained from elderly (65+ years of age) retirement facility ...

  18. An Automated Heart Rate Detection Platform in Wild-Type Zebrafish for Cardiotoxicity Screening of Fine Particulate Matter Air Pollution

    EPA Science Inventory

    Exposure to air pollution-derived particulate matter (PM) causes adverse cardiovascular health outcomes, with increasing evidence implicating soluble components of PM; however, the enormous number of unique PM samples from different air sheds far exceeds the capacity of conventio...

  19. Comparative In Vivo and Ex Vivo Toxicity Studies of Wildfire Particulate Matter

    EPA Science Inventory

    Inhalation of particulate matter (PM) generated from biomass burning is of concern particularly as the frequency and severity of wildfires have been increasing. Size-fractionated PM samples (ultrafine, <0.2 µm; fine, 0.2-2.5 µm; coarse, 2.5-10 µm) were colle...

  20. Spatial and Temporal Distribution of Current-Use Pesticides in Atmospheric Particulate Matter in Houston, Texas.

    PubMed

    Clark, Adelaide E; Yoon, Subin; Sheesley, Rebecca J; Usenko, Sascha

    2016-12-01

    The atmospheric concentrations of seven current-use pesticides in particulate matter were determined at four locations throughout the Houston metropolitan area in TSP and PM 2.5 samples from September 2013. Atmospheric concentrations in both TSP and PM 2.5 ranged from below method detection limits (MDLs) to nearly 1100 pg m -3 . The three compounds most frequently detected above MDLs were chlorothalonil, bifenthrin, and λ-cyhalothrin. Atmospheric chlorothalonil concentrations were above 800 pg m -3 in several TSP samples, but

  1. Determination of the Turkish Primary Students' Views about the Particulate Nature of Matter

    ERIC Educational Resources Information Center

    Ozmen, Haluk; Kenan, Osman

    2007-01-01

    This study was conducted to determine 4th, 5th, and 6th grade Turkish primary students' conceptions about the particulate nature of matter via a test. The test consists of 36 items related to the changes of microscopic properties of solid, liquid and gas matters during phase changing, cooling, heating and pressing of them. The sample of the study…

  2. NHEXAS PHASE I ARIZONA STUDY--STANDARD OPERATING PROCEDURE FOR FIELD USE OF THE PARTICULATE SAMPLER (UA-F-3.1)

    EPA Science Inventory

    The purpose of this SOP is to describe the in-field use of the particulate sampling system (pumping, control unit, and size selective inlet impactors) for collecting samples of particulate matter from the air during a predetermined time period during the Arizona NHEXAS project an...

  3. Effects of vibratory microscreening on proximate composition and recovery of poultry processing wastewater particulate matter.

    PubMed

    Kiepper, B H; Merka, W C; Fletcher, D L

    2008-12-01

    Experiments were conducted to compare the effects of tertiary microscreen gap size on the proximate composition and rate of recovery of particulate matter from poultry processing wastewater (PPW). A high-speed vibratory screen was installed within the wastewater treatment area of a southeast US broiler slaughter plant after the existing primary and secondary mechanical rotary screens. Microscreen panels with nominal gap size openings of 212, 106 and 45mum were investigated. The particulate matter samples recovered were subjected to proximate analysis to determine percent moisture, fat, protein, crude fiber and ash. The average percent wet weight moisture (%WW) content for all samples was 79.1. The average percent dry matter (%DM) fat, protein, crude fiber and ash were 63.5, 17.5, 4.8 and 1.5, respectively. The mean concentration of total solids (TS) recovered from all microscreen runs was 668mg/L, which represents a potential additional daily offal recovery rate of 12.1metric tons (MT) per 3.78 million L (1.0 million gallons US) of PPW. There was no significant difference in the performance of the three microscreen gap sizes with regard to proximate composition or mass of particulate matter recovered.

  4. The Effect of Composition, Size, and Solubility on Acute Pulmonary Injury in Rats Following Exposure to Mexico City Ambient Particulate Matter Samples

    EPA Science Inventory

    Particulate matter (PM) associated metals contribute to the adverse cardiopulmonary effects following exposure to air pollution. Here, we investigated how variation in the composition and size of ambient PM collected from two distinct regions in Mexico City relates to toxicity d...

  5. FINE PARTICULATE MATTER SOURCE ATTRIBUTION FOR SOUTHEAST TEXAS USING 14C/13C RATIOS

    EPA Science Inventory

    Radiocarbon analyses of fine particulate matter samples collected during the summer of 2000 in southeast Texas indicate that a substantial fraction of the aerosol carbon at an urban/suburban site (27% to 73%) and at a rural, forested site (44% to 77%) was modern carbon. Data fr...

  6. 77 FR 32632 - Ambient Air Monitoring Reference and Equivalent Methods: Designation of Three New Equivalent Methods

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-01

    ... Hydrogen Peroxide Filter Extraction'' In this method, total suspended particulate matter (TSP) is collected on glass fiber filters according to 40 CFR Appendix G to part 50, EPA Reference Method for the Determination of Lead in Suspended Particulate Matter Collected From Ambient Air. The filter samples are...

  7. A Review of Advancements in Particulate Matter Sampling and Analysis and its Application to Identifying Source Impacts at Receptor Locations

    EPA Science Inventory

    Time-integrated (typically 24-hr) filter-based methods (historical methods) form the underpinning of our understanding of the fate, impact of source emissions at receptor locations (source impacts), and potential health and welfare effects of particulate matter (PM) in air. Over...

  8. DETERMINING COARSE PARTICULATE MATTER CONCENTRATIONS: A PERFORMANCE EVALUATION OF CANDIDATE METHODOLOGIES UNDER WINTERTIME CONDITIONS

    EPA Science Inventory

    The main objective of this study is to evaluate the performance of sampling methods for potential use as a Federal Reference Method (FRM) capable of providing an estimate of coarse particle (PMc: particulate matter with an aerodynamic diameter between 2.5 um and 10 um) mass con...

  9. CHEMICAL AND PHYSICAL CHARACTERISTICS OF OUTDOOR, INDOOR, AND PERSONAL PARTICULATE AIR SAMPLES COLLECTED IN AND AROUND A RETIREMENT FACILITY

    EPA Science Inventory

    Residential, personal, indoor, and outdoor sampling of particulate matter was conducted at a retirement center in the Towson area of northern Baltimore County in 1998. Concurrent sampling was conducted at a central community site. Computer-controlled scanning electron microsco...

  10. Characterization of Dust on Solar Devices in Southern Nevada =

    NASA Astrophysics Data System (ADS)

    Sylva, Jason R.

    Dust can impact the efficiency of solar energy collection devices, and in some arid environments, dust can reduce solar energy efficiency up to 30%. Reducing the impact of dust is therefore critical in the expansion of solar technology throughout regions where solar energy is utilized. Characterization of suspended and settled particulate matter can assist in developing strategies for dust mitigation. With the characterization of suspended and settled particulate in remote, rural, and urban environments, more informed decisions can be made regarding the selection of coating material on solar panels as well as developing cleaning and maintenance procedures. Particulate matter that deposits on a solar surface can potentially interact with solar radiation, precipitation, or even directly with the surface material itself. These interactions could lead to the formation of coatings that reduce/block radiation and/or degrade the integrity of the surface. When you extrapolate these possibilities to a larger scale preliminary characterization of dust will play a vital role when planning the construction of a solar energy facility. A variety of sampling techniques were employed to obtain particulate matter for characterization. These included direct collection of particulates from solar surfaces: via vacuum and wipe sample collection on panels, tacky dot adhesive slides and plain slides that were exposed at different intervals, desert vugs that are natural particulate collectors, as well as high volume air sampling for collection of suspended particulates. High volume air sampling was performed using glass fiber filters and 2 micron stainless steel screens. Direct collection of settled particulates was performed by sampling from solar surfaces, vugs, and by collection on exposed glass surfaces. Collection onto glass surfaces was achieved by setting up a plain microscope slide, tacky dot slides, and panes of glass. The sampling methodology allowed for the collection of samples for analyses using various analytical methods that included Raman microspectroscopy, pyrolysis gas chromatography mass spectrometry, ion chromatography and inductively coupled plasma mass spectrometry. These various methods allow for identification of organic and inorganic components as well the mineral distribution of suspended and settled particulate material. None None None None None

  11. Seasonal variability in particulate matter source and composition to the depositional zone of Baltimore Canyon, U.S. Mid-Atlantic Bight

    USGS Publications Warehouse

    Prouty, Nancy G.; Mienis, Furu; Campbell, P.; Roark, E. Brendan; Davies, Andrew; Robertson, Craig M.; Duineveld, Gerard; Ross, Steve W.; Rhodes, M.; Demopoulos, Amanda W.J.

    2017-01-01

    Submarine canyons are often hotspots of biomass and productivity in the deep sea. However, the majority of deep-sea canyons remain poorly sampled. Using a multi-tracer approach, results from a detailed geochemical investigation from a year-long sediment trap deployment reveals details concerning the source, transport, and fate of particulate matter to the depositional zone (1318 m) of Baltimore Canyon on the US Mid-Atlantic Bight (MAB). Both organic biomarker composition (sterol and n-alkanes) and bulk characteristics (δ13C, Δ14C, Chl-a) suggest that on an annual basis particulate matter from marine and terrestrially-derived organic matter are equally important. However, elevated Chlorophyll-a and sterol concentrations during the spring sampling period highlight the seasonal influx of relatively fresh phytodetritus. In addition, the contemporaneous increase in the particle reactive elements cadmium (Cd) and molybdenum (Mo) in the spring suggest increased scavenging, aggregation, and sinking of biomass during seasonal blooms in response to enhanced surface production within the nutricline. While internal waves within the canyon resuspend sediment between 200 and 600 m, creating a nepheloid layer rich in lithogenic material, near-bed sediment remobilization in the canyon depositional zone is minimal. Instead, vertical transport and lateral transport across the continental margin are the dominant processes driving seasonal input of particulate matter. In turn, seasonal variability in deposited particulate organic matter may be linked to benthic faunal composition and ecosystem scale carbon cycling.

  12. Comparison and trend study on acidity and acidic buffering capacity of particulate matter in China

    NASA Astrophysics Data System (ADS)

    Ren, Lihong; Wang, Wei; Wang, Qingyue; Yang, XiaoYang; Tang, Dagang

    2011-12-01

    The acidity of about 2000 particulate matter samples from aircraft and ground-based monitoring is analyzed by the method similar to soil acidity determination. The ground-based samples were collected at about 50 urban or background sites in northern and southern China. Moreover, the acidic buffering capacity of those samples is also analyzed by the method of micro acid-base titration. Results indicate that the acidity level is lower in most northern areas than those in the south, and the acidic buffering capacity showed inverse tendency, correspondingly. This is the most important reason why the pollution of acidic-precipitation is much more serious in Southern China than that in Northern China. The acidity increases and the acidic buffering capacity drops with the decreasing of the particle sizes, indicating that fine particle is the main influencing factor of the acidification. The ionic results show that Ca salt is the main alkaline substance in particulate matter, whereas the acidification of particulate matter is due to the SO 2 and NO x emitted from the fossil fuel burning. And among of them, coal burning is the main contributor of SO 2, however the contribution of NO x that emitted from fuel burning of motor vehicles has increased in recent years. By comparison of the experimental results during the past 20 years, it can be concluded that the acid precipitation of particulate matter has not been well controlled, and it even shows an increasing tendency in China lately. The acid precipitation of particulate matter has begun to frequently attack in part of the northern areas. Multiple regression analysis indicates that coefficient value of the ions is the lowest at the urban sites and the highest at the regional sites, whereas the aircraft measurement results are intermediate between those two kinds of sites.

  13. Air quality during demolition and recovery activities in post-Katrina New Orleans.

    PubMed

    Ravikrishna, Raghunathan; Lee, Han-Woong; Mbuligwe, Stephen; Valsaraj, K T; Pardue, John H

    2010-07-01

    Air samples were collected during demolition and cleanup operations in the Lakeview district of New Orleans, Louisiana, USA, in late 2005 during the period immediately after Hurricane Katrina. Three different high-volume air samples were collected around waste collection areas that were created to temporarily hold the debris from the cleanup of residential properties in the area. Particulate concentrations were elevated and included crystalline fibers associated with asbestos. Metal concentrations on particulate matter resembled those measured in sediments deposited by floodwaters with the exception of Ba, which was elevated at all three locations. The highest organic contaminant concentration measured on particulates was the pesticide Ziram (Zinc, bis[diethylcarbamodithioato-S,S']-, [T-4]-) at 2,200 microg/g of particulate matter during sampling period 2. Ziram is used in latex paint, adhesives, caulking, and wallboard as a preservative. Fungal isolates developed from particulate air samples included species associated with disease including Aspergillus and Penicillium species. These data represent the most comprehensive assessment of demolition activities during the period immediately after Hurricane Katrina. Copyright (c) 2010 SETAC.

  14. Multi-faceted monitoring of estuarine turbidity and particulate matter provenance: Case study from Salem Harbor, USA.

    PubMed

    Hubeny, J Bradford; Kenney, Melanie; Warren, Barbara; Louisos, Jeremy

    2017-01-01

    Turbidity is a water quality parameter that is known to adversely affect aquatic systems, however the causes of turbid water are often elusive. We present results of a study designed to constrain the source of particulate matter in a coastal embayment that has suffered from increased turbidity over past decades. Our approach utilized monitoring buoys to quantify turbidity at high temporal resolution complemented by geochemical isotope analysis of suspended sediment samples and meteorological data. Results reveal a complex system in which multiple sources are associated with particulate matter. Weight of evidence demonstrates that phytoplankton productivity in the water column, however, is the dominant source of particulate matter associated with elevated turbidity in Salem Harbor, Massachusetts. Allochthonous matter from the watershed was observed to mix into the pool of suspended particulate matter near river mouths, especially in spring and summer. Resuspension of harbor surface sediments likely provides additional particulates in the regions of boat moorings, especially during summer when recreational boats are attached to moorings. Our approach allows us to constrain the causes of turbidity events in this embayment, is helping with conservation efforts of environmental quality in the region, and can be used as a template for other locations. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. Quantitative exposure matrix for asphalt fume, total particulate matter, and respirable crystalline silica among roofing and asphalt manufacturing workers.

    PubMed

    Fayerweather, William E; Trumbore, David C; Johnson, Kathleen A; Niebo, Ronald W; Maxim, L Daniel

    2011-09-01

    This paper summarizes available data on worker exposures to asphalt fume (soluble fraction), total particulate matter, and respirable crystalline silica (quartz) [hereinafter RCS] over a 30-year period in Owens Corning's asphalt production and roofing manufacturing plants. For the period 1977 through 2006, the air-monitoring database contains more than 1,400 personal samples for asphalt fume (soluble fraction), 2,400 personal samples for total particulate, and 1,300 personal samples for RCS. Unique process-job categories were identified for the asphalt production and roofing shingle manufacturing plants. Quantitative exposures were tabulated by agent, process-job, and calendar period to form an exposure matrix for use in subsequent epidemiologic studies of the respiratory health of these workers. Analysis of time trends in exposure data shows substantial and statistically significant exposure reductions for asphalt fume (soluble fraction), total particulate matter, and respirable crystalline silica at Owens Corning plants. Cumulative distribution plots for the most recent sampling period (2001-2006) show that 95% of the asphalt fume (soluble fraction) measurements were less than 0.25 mg/m3; 95% of the total particulate measurements were less than 2.2 mg/m3; and 95% of the RCS measurements were less than 0.05 mg/m3. Several recommendations are offered to improve the design of future monitoring efforts.

  16. Concept Learning versus Problem Solving: Evaluating a Threat to the Validity of a Particulate Gas Law Question

    ERIC Educational Resources Information Center

    Sanger, Michael J.; Vaughn, C. Kevin; Binkley, David A.

    2013-01-01

    Three different samples of students were asked to answer five multiple-choice questions concerning the properties of a sample of helium gas (particle speed, state of matter, sample volume, sample pressure, and particle distribution), including a particulate question first used by Nurrenbern and Pickering (particle distribution). In the first…

  17. Source apportionment with uncertainty estimates of fine particulate matter in Ostrava, Czech Republic using Positive Matrix Factorization

    EPA Science Inventory

    A 14-week investigation during a warm and cold seasons was conducted to improve understanding of air pollution sources that might be impacting air quality in Ostrava, the Czech Republic. Fine particulate matter (PM2.5) samples were collected in consecutive 12-h day and night incr...

  18. DISCUSSION AND EVALUATION OF THE VOLATILITY TEST FOR EQUIVALENCY OF OTHER METHODS TO THE FEDERAL REFERENCE METHOD FOR FINE PARTICULATE MATTER

    EPA Science Inventory

    In July 1997, EPA promulgated a new National Ambient Air Quality Standard (NAAQS) for fine particulate matter (PM2.5). This new standard was based on collection of an integrated mass sample on a filter. Field studies have demonstrated that the collection of semivolatile compoun...

  19. Source Apportionment of Ambient Fine Particulate Matter in Dearborn, Michigan, using Hourly Resolved PM Chemical Composition Data

    EPA Science Inventory

    High time-resolution aerosol sampling was conducted for one month during July–August 2007 in Dearborn, MI, a non-attainment area for fine particulate matter (PM2.5) National Ambient Air Quality Standards (NAAQS). Measurements of more than 30 PM2.5 species were made using a suite o...

  20. PRELIMINARY RESULTS OF EPA'S PERFORMANCE EVALUATION OF FEDERAL REFERENCE METHODS AND FEDERAL EQUIVALENT METHODS FOR COARSE PARTICULATE MATTER

    EPA Science Inventory

    The main objective of this study is to evaluate the performance of sampling methods for potential use as a Federal Reference Method (FRM) capable of providing an estimate of coarse particle (PMc: particulate matter with an aerodynamic diameter between 2.5 µm and 10 µm) ...

  1. DETERMINING COARSE PARTICULATE MATTER CONCENTRATIONS: A PERFORMANCE EVALUATION OF CANDIDATE METHODOLOGIES - STUDY DESIGN AND RESULTS FROM THE RTP EQUIPMENT SHAKEDOWN

    EPA Science Inventory

    The main objective of this study is to evaluate the performance of candidate sampling methods for potential use as a Federal Reference Method (FRM) capable of providing an estimate of coarse particle (PMc: particulate matter with an aerodynamic diameter between 2.5 um and 10 um...

  2. PARTICULATE ORGANIC CARBON MEASUREMENTS COLLECTED WITH LOW FLOW PERSONAL SAMPLERS

    EPA Science Inventory

    EPA's National Exposure Research Laboratory and the Research Triangle Institute (RTI) have conducted a particulate matter (PM) personal exposure study in Research Triangle Park, NC. Particulate carbon was sampled with pre-fired quartz filters using low flow PM2.5 samplers (2 L...

  3. Fractionation and characterization of organic matter in wastewater from a swine waste-retention basin

    USGS Publications Warehouse

    Leenheer, Jerry A.; Rostad, Colleen E.

    2004-01-01

    Organic matter in wastewater sampled from a swine waste-retention basin in Iowa was fractionated into 14 fractions on the basis of size (particulate, colloid, and dissolved); volatility; polarity (hydrophobic, transphilic, hydrophilic); acid, base, neutral characteristics; and precipitate or flocculates (floc) formation upon acidification. The compound-class composition of each of these fractions was determined by infrared and 13C-NMR spectral analyses. Volatile acids were the largest fraction with acetic acid being the major component of this fraction. The second most abundant fraction was fine particulate organic matter that consisted of bacterial cells that were subfractionated into extractable lipids consisting of straight chain fatty acids, peptidoglycans components of bacterial cell walls, and protein globulin components of cellular plasma. The large lipid content of the particulate fraction indicates that non-polar contaminants, such as certain pharmaceuticals added to swine feed, likely associate with the particulate fraction through partitioning interactions. Hydrocinnamic acid is a major component of the hydrophobic acid fraction, and its presence is an indication of anaerobic degradation of lignin originally present in swine feed. This is the first study to combine particulate organic matter with dissolved organic matter fractionation into a total organic matter fractionation and characterization.

  4. Association between ambient particulate matter and disorders of vestibular function.

    PubMed

    Han, Changwoo; Lim, Youn-Hee; Jung, Kweon; Hong, Yun-Chul

    2017-05-01

    Exposure to environmental chemicals has been suggested to alter the physiologic state of the inner and middle ear. However, it is unknown if particulate matter exposure is associated with acute vestibular dysfunction. To estimate the effects of particulate matter exposure on the number of hospital visits related to three major diseases of vestibular dysfunction, Meniere's disease (MD), benign paroxysmal positional vertigo (BPPV), and vestibular neuronitis (VN). Our study subject is from Korean National Health Insurance Service-National Sample Cohort, which is dynamic cohort consist of 1 million participants representing the Korean population. Among total cohort participants, we used the hospital visit data of 210,000 individuals who resided in Seoul from 2007 to 2010. Time series analysis using the Poisson generalized additive model and case-crossover analysis using conditional logistic regression were used to investigate the association between daily particulate matter levels (PM 2.5 , particulate matter <2.5μg/m 3 ; PM 10 , particulate matter <10μg/m 3 ; PM 10-2.5 , PM 10 - PM 2.5 ) and number of MD, BPPV, and VN hospital visits. Time series analysis showed that an interquartile range (IQR) increase in PM 10 and PM 10-2.5 on lag day 1 was associated with an increased risk of MD hospital visits [relative risk (RR), 95% confidence interval (CI), PM 10 : 1.09 (1.02-1.15); PM 10-2.5 : 1.06 (1.02-1.10)]. In addition, elderly individuals (≥60 years old) showed an increased risk of MD hospital visits after particulate matter exposure when compared to younger individuals. An IQR increase in particulate matter on lag day 1 was associated with a marginally significant increase in VN hospital visits [RR (95%CI), PM 2.5 : 1.11 (0.98-1.25); PM 10 : 1.07 (0.99-1.15); PM 10-2.5 : 1.04 (0.99-1.09)]. However, no association between particulate matter exposure and BPPV hospital visits was noted. Case-crossover analyses showed similar results to the time-series analysis across all three diseases. MD hospital visits were associated with ambient particulate matter exposure. Elderly individuals, in particular, were more susceptible to particulate matter exposure than younger individuals. Copyright © 2017 Elsevier Inc. All rights reserved.

  5. Determination of inorganic particulates: (cationic, anionic and heavy metals) in the atmosphere of some areas in Bahrain during the Gulf crisis in 1991

    NASA Astrophysics Data System (ADS)

    Ali-Mohamed, Ahmed Y.; Matter, Haifa A.

    Inorganic particulate matter was sampled weekly during the period March-May, 1991 at different sites at height of ˜6-9 m above the ground level. Deposited aerosols were chemically analyzed and a comparison was made between these sites. The percentage of tarry matter deposited on the airborne particulate matter was found to be 40% during the Gulf crisis compared to 5% prior to Gulf war (1985/86). Heavy metal analysis are also reported. The results were influenced differently by some atmospheric parameters such as temperature, humidity, rainfall, pressure and wind speed/direction.

  6. Comparison of PIXE and XRF analysis of airborne particulate matter samples collected on Teflon and quartz fibre filters

    NASA Astrophysics Data System (ADS)

    Chiari, M.; Yubero, E.; Calzolai, G.; Lucarelli, F.; Crespo, J.; Galindo, N.; Nicolás, J. F.; Giannoni, M.; Nava, S.

    2018-02-01

    Within the framework of research projects focusing on the sampling and analysis of airborne particulate matter, Particle Induced X-ray Emission (PIXE) and Energy Dispersive X-ray Fluorescence (ED-XRF) techniques are routinely used in many laboratories throughout the world to determine the elemental concentration of the particulate matter samples. In this work an inter-laboratory comparison of the results obtained from analysing several samples (collected on both Teflon and quartz fibre filters) using both techniques is presented. The samples were analysed by PIXE (in Florence, at the 3 MV Tandetron accelerator of INFN-LABEC laboratory) and by XRF (in Elche, using the ARL Quant'X EDXRF spectrometer with specific conditions optimized for specific groups of elements). The results from the two sets of measurements are in good agreement for all the analysed samples, thus validating the use of the ARL Quant'X EDXRF spectrometer and the selected measurement protocol for the analysis of aerosol samples. Moreover, thanks to the comparison of PIXE and XRF results on Teflon and quartz fibre filters, possible self-absorption effects due to the penetration of the aerosol particles inside the quartz fibre-filters were quantified.

  7. Analysis of atmospheric paniculate matter; application of optical and selected geochemical techniques

    USGS Publications Warehouse

    Mastalerz, Maria; Glikson, M.; Simpson, R.W.

    1999-01-01

    An increase in participate matter in the atmosphere has been shown to be linked to increased mortality but this relationship is poorly understood. Light microscopy, electron microscopy, electron microprobe, and micro-FTIR techniques have been applied to study atmospheric particulates in Brisbane, Australia as a part of a study on asthma. The particulate matter samples were collected daily from April to August 1992, and the sampling covered the autumn period which is typically a time of high asthma incidence in Brisbane. Volumetrically, most atmospheric particulate matter is less than 2 ??m in size. The microscopic analysis reveals that this material is composed mainly of combusted and incompletely burned hydrocarbons from motor vehicle exhaust emissions, quiescent spores of Mucorales, soil bacteria, and inorganic matter in the form of quartz and other silicates. Elemental and functional group analyses confirm microscope identification, documenting carbon-rich, aromatic exhaust material, more aliphatic pollen and spore material and inorganic matter. Fungal spores dominate bioaerosol and are very abundant from the end of April through May to mid-June. The cytoplasmic content of pollens or fungal spores is commonly regarded as allergenic. Particulates from the exhaust emissions and crustal material in a sub-micrometer size range may act as carriers or dispersive mechanisms for cytoplasmic material from fungal spores and pollens, perhaps causing periods of the highest exhaust emission to be the most allergenic. ?? 1998 Elsevier Science B.V. All rights reserved.

  8. Effect of PDEODE Teaching Strategy on Turkish Students' Conceptual Understanding: Particulate Nature of Matter

    ERIC Educational Resources Information Center

    Demircioglu, Hülya

    2017-01-01

    The aim of this study is to determine the effect of activities developed in accordance with PDEODE teaching strategy on students' understanding of the particulate nature of matter. The sample of the study consists of the first grade students who study in the Primary School Teacher Education Program. In order to determine the conceptual change on…

  9. SOURCE SAMPLING FINE PARTICULATE MATTER: A KRAFT PROCESS RECOVERY BOILER AT A PULP AND PAPER FACILITY, VOLUMES 1 AND 2

    EPA Science Inventory

    Fine particulate matter of aerodynamic diameter 2.5 m or less (PM-2.5) has been found harmful to human health, and a National Ambient Air Quality Standard for PM-2.5 was promulgated by the U.S. Environmental Protection Agency in July 1997. A national network of ambient monitorin...

  10. SOURCE SAMPLING FINE PARTICULATE MATTER: A KRAFT PROCESS HOGGED FUEL BOILER AT A PULP AND PAPER FACILITY, VOLUMES 1 AND 2

    EPA Science Inventory

    Fine particulate matter of aerodynamic diameter 2.5 m or less (PM-2.5) has been found harmful to human health, and a National Ambient Air Quality Standard for PM-2.5 was promulgated by the U.S. Environmental Protection Agency in July 1997. A national network of ambient monitorin...

  11. Teachers' Understanding of the Particulate Nature of Matter: The Case of Zambian Pre-Service Science Teachers

    ERIC Educational Resources Information Center

    Banda, Asiana; Mumba, Frackson; Chabalengula, Vivien M.; Mbewe, Simeon

    2011-01-01

    This study assessed Zambian Junior High School pre-service science teachers' understanding of the particulate nature of matter. A sample comprised 30 pre-service science teachers at a teacher training college. Data was collected through a questionnaire adopted from Ozmen and Kenan (2007). Results show that most teachers had correct views on the…

  12. Characterization of particulate matter sources in an urban environment.

    PubMed

    Mazzei, F; D'Alessandro, A; Lucarelli, F; Nava, S; Prati, P; Valli, G; Vecchi, R

    2008-08-15

    Daily time series measurements of elements or compounds are widely used to apportion the contribution of specific sources of particulate matter concentration in the atmosphere. We present results obtained for the urban area of Genoa (Italy) based on several hundred of PM10, PM2.5 and PM1 daily samples collected in sites with different geo-morphological and urbanization characteristics. Elemental concentrations of Na to Pb were obtained through Energy Dispersive X-Ray Fluorescence (ED-XRF), and the contributions of specific sources of particulate matter (PM) concentration were apportioned through Positive Matrix Factorization (PMF). By sampling at different sites we were able to obtain, in each PM fraction, the average and stable values for the tracers of specific sources, in particular traffic (Cu, Zn, Pb) and heavy oil combustion (V, Ni). We could also identify and quote the contamination of anthropogenic PM in "natural" sources (sea, soil dust). Sampling at several sites in the same urban area allowed us to resolve local characteristics as well as to quote average values.

  13. Markers of inflammation in alveolar cells exposed to fine particulate matter from prescribed fires and urban air.

    PubMed

    Myatt, Theodore A; Vincent, Michael S; Kobzik, Lester; Naeher, Luke P; MacIntosh, David L; Suh, Helen

    2011-10-01

    To assess the effect of fine particulate matter (PM(2.5)) from different particle sources on tumor necrosis factor- (TNF-) α, we measured TNF production from rat alveolar macrophages (AM) and human dendritic cells (DC) exposed to PM(2.5) from different sources. Fire-related PM(2.5) samples, rural ambient, and urban indoor and outdoor samples were collected in the Southeast United States. Tumor necrosis factor release was measured from rat AM and human DC following incubation with PM(2.5). Tumor necrosis factor release in AMs was greatest for fire-related PM(2.5) compared with other samples (TNF: P value = 0.005; mortality: P value = 0.005). Tumor necrosis factor releases from the DCs and AMs exposed to fire-associated PM(2.5) were strongly correlated (r = 0.87, P value < 0.0001). Particulate matter exposure produces TNF release consistent with pulmonary inflammation in rat AMs and human DCs, with the response in rat AMs differing by particle source.

  14. Fine Particulate Matter Concentrations in Urban Chinese Cities, 2005-2016: A Systematic Review.

    PubMed

    He, Mike Z; Zeng, Xiange; Zhang, Kaiyue; Kinney, Patrick L

    2017-02-14

    Background : Particulate matter pollution has become a growing health concern over the past few decades globally. The problem is especially evident in China, where particulate matter levels prior to 2013 are publically unavailable. We conducted a systematic review of scientific literature that reported fine particulate matter (PM 2.5 ) concentrations in different regions of China from 2005 to 2016. Methods : We searched for English articles in PubMed and Embase and for Chinese articles in the China National Knowledge Infrastructure (CNKI). We evaluated the studies overall and categorized the collected data into six geographical regions and three economic regions. Results : The mean (SD) PM 2.5 concentration, weighted by the number of sampling days, was 60.64 (33.27) μg/m³ for all geographic regions and 71.99 (30.20) μg/m³ for all economic regions. A one-way ANOVA shows statistically significant differences in PM 2.5 concentrations between the various geographic regions (F = 14.91, p < 0.0001) and the three economic regions (F = 4.55, p = 0.01). Conclusions: This review identifies quantifiable differences in fine particulate matter concentrations across regions of China. The highest levels of fine particulate matter were found in the northern and northwestern regions and especially Beijing. The high percentage of data points exceeding current federal regulation standards suggests that fine particulate matter pollution remains a huge problem for China. As pre-2013 emissions data remain largely unavailable, we hope that the data aggregated from this systematic review can be incorporated into current and future models for more accurate historical PM 2.5 estimates.

  15. Battery condenser system particulate emission factors for cotton gins: Particle size distribution characteristics

    USDA-ARS?s Scientific Manuscript database

    This report is part of a project to characterize cotton gin emissions from the standpoint of total particulate stack sampling and particle size analyses. In 2013, the Environmental Protection Agency (EPA) published a more stringent standard for particulate matter with nominal diameter less than or e...

  16. Direct Analysis of Low-Volatile Molecular Marker Extract from Airborne Particulate Matter Using Sensitivity Correction Method

    PubMed Central

    Irei, Satoshi

    2016-01-01

    Molecular marker analysis of environmental samples often requires time consuming preseparation steps. Here, analysis of low-volatile nonpolar molecular markers (5-6 ring polycyclic aromatic hydrocarbons or PAHs, hopanoids, and n-alkanes) without the preseparation procedure is presented. Analysis of artificial sample extracts was directly conducted by gas chromatography-mass spectrometry (GC-MS). After every sample injection, a standard mixture was also analyzed to make a correction on the variation of instrumental sensitivity caused by the unfavorable matrix contained in the extract. The method was further validated for the PAHs using the NIST standard reference materials (SRMs) and then applied to airborne particulate matter samples. Tests with the SRMs showed that overall our methodology was validated with the uncertainty of ~30%. The measurement results of airborne particulate matter (PM) filter samples showed a strong correlation between the PAHs, implying the contributions from the same emission source. Analysis of size-segregated PM filter samples showed that their size distributions were found to be in the PM smaller than 0.4 μm aerodynamic diameter. The observations were consistent with our expectation of their possible sources. Thus, the method was found to be useful for molecular marker studies. PMID:27127511

  17. Microbiota and Particulate Matter Assessment in Portuguese Optical Shops Providing Contact Lens Services

    PubMed Central

    Viegas, Carla; Faria, Tiago; Pacífico, Cátia; Dos Santos, Mateus; Monteiro, Ana; Lança, Carla; Carolino, Elisabete; Viegas, Susana; Cabo Verde, Sandra

    2017-01-01

    The aim of this work was to assess the microbiota (fungi and bacteria) and particulate matter in optical shops, contributing to a specific protocol to ensure a proper assessment. Air samples were collected through an impaction method. Surface and equipment swab samples were also collected side-by-side. Measurements of particulate matter were performed using portable direct-reading equipment. A walkthrough survey and checklist was also applied in each shop. Regarding air sampling, eight of the 13 shops analysed were above the legal requirement and 10 from the 26 surfaces samples were overloaded. In three out of the 13 shops fungal contamination in the analysed equipment was not detected. The bacteria air load was above the threshold in one of the 13 analysed shops. However, bacterial counts were detected in all sampled equipment. Fungi and bacteria air load suggested to be influencing all of the other surface and equipment samples. These results reinforce the need to improve air quality, not only to comply with the legal requirements, but also to ensure proper hygienic conditions. Public health intervention is needed to assure the quality and safety of the rooms and equipment in optical shops that perform health interventions in patients. PMID:28505144

  18. Carbonaceous aerosols in fine particulate matter of Santiago Metropolitan Area, Chile.

    PubMed

    Toro Araya, Richard; Flocchini, Robert; Morales Segura, Rául G E; Leiva Guzmán, Manuel A

    2014-01-01

    Measurements of carbonaceous aerosols in South American cities are limited, and most existing data are of short term and limited to only a few locations. For 6 years (2002-2007), concentrations of fine particulate matter and organic and elemental carbon were measured continuously in the capital of Chile. The contribution of carbonaceous aerosols to the primary and secondary fractions was estimated at three different sampling sites and in the warm and cool seasons. The results demonstrate that there are significant differences in the levels in both the cold (March to August) and warm (September to February) seasons at all sites studied. The percent contribution of total carbonaceous aerosol fine particulate matter was greater in the cool season (53 ± 41%) than in the warm season (44 ± 18%). On average, the secondary organic carbon in the city corresponded to 29% of the total organic carbon. In cold periods, this proportion may reach an average of 38%. A comparison of the results with the air quality standards for fine particulate matter indicates that the total carbonaceous fraction alone exceeds the World Health Organization standard (10 µg/m(3)) and the United States Environmental Protection Agency standard (15 µg/m(3)) for fine particulate matter.

  19. Aerodynamic size distribution of suspended particulate matter in the ambient air in the city of Cleveland, Ohio

    NASA Technical Reports Server (NTRS)

    Leibecki, H. F.; King, R. B.; Fordyce, J. S.

    1974-01-01

    The City of Cleveland Division of Air Pollution Control and NASA jointly investigated the chemical and physical characteristics of the suspended particulate matter in Cleveland, and as part of the program, measurements of the particle size distribution of ambient air samples at five urban locations during August and September 1972 were made using high-volume cascade impactions. The distributions were evaluated for lognormality, and the mass median diameters were compared between locations and as a function of resultant wind direction. Junge-type distributions were consistent with dirty continental aerosols. About two-thirds of the suspended particulate matter observed in Cleveland is less than 7 microns in diameter.

  20. Polarimetric discrimination of atmospheric particulate matter

    NASA Astrophysics Data System (ADS)

    Raman, Prashant; Fuller, Kirk; Gregory, Don

    2012-06-01

    A polarimeter capable of measuring the complete Mueller matrix of highly scattering samples in transmission and reflection from 300 to 1100 nm has been constructed and tested. Exploratory research has been conducted which may lead to the standoff detection of bio-aerosols in the atmosphere. The polarization properties of bsubtilis (surrogate for anthrax spore) have been compared to ambient particulate matter species such as pollen, dust and soot (all sampled onto microscope slides) and differentiating features have been identified. The application of this technique for the discrimination of bio-aerosol from background clutter has been demonstrated.

  1. [Contamination of urban air in a snowy district with 1-nitropyrene and particulate matter during the winter].

    PubMed

    Saitoh, N; Wada, Y; Koizumi, A; Kamiyama, S

    1990-10-01

    Nitroarenes, potent rodent carcinogens, have attracted much attention as environmental contaminants. Recently, simultaneous exposure to dust have been found to potentiate tumorigenicity of nitroarenes in rats (14). We hypothesized that inhabitants of northwestern Japan may be exposed to such substances in winter. First, we sought to develop a sensitive yet time saving method to determine nitroarene concentrations in airborne particulate matter. The method developed used a high-performance liquid chromatograph equipped with a fluorescence detector. By on-column catalytic reduction, using silica coated with platinum and rhodium, 1-nitropyrene (1-NP), 1,3-dinitropyrene, 1,6-dinitropyrene, and 1,8-dinitropyrene were effectively reduced to their amino derivatives which were easily detectable with the fluorescence detector. The lowest detectable limits found using the present method were on the order of picograms for individual compounds. Subsequently, we sought to determine the concentrations of nitroarenes using the new method on airborne particulate matter during the period from November to April. Samples were collected at sampling sites on road with high-volume air samplers for 24 hours or 72 hours in four different rural areas in Iwate Prefecture. At one location in the city of Morioka, samples were collected at the height of 25 m from the ground. Among the four nitropyrenes mentioned above, only 1-NP was detected in the samples. The concentrations of 1-NP and airborne particulates changed significantly in all examined areas in parallel with the rise and fall of the frequencies of studded tire use. The highest 1-NP and airborne particulate concentrations were 1.210 pg/m3 and 1,291 micrograms/m3, respectively, being recorded at the busiest road in Kitakami. In contrast, the lowest values were 38 to 66 pg/m3 for 1-NP and 54 to 94 micrograms/m3 for airborne particulates in Morioka, being recorded in November and April, respectively. The mutagenicities of extracts of airborne particulate matter showed similar trends. Thus, exposure situations with high concentrations of dust and 1-NP were confirmed to occur in Iwate. Finally, the risk posed by 1-NP in airborne particulate matter was estimated using the equation proposed by Cuddihy and McClellan (37) and was found to range from 3.12 x 10(-2) to 24.2 x 10(-2) lung cancer/year/10(6) people. Although the estimated risk due to 1-NP is relatively small, further surveillance is highly recommended in those areas since heavy dust exposure also occurs there.

  2. Hydrophilic Interaction Liquid Chromatography-Tandem Mass Spectrometry Analysis of Fosetyl-Aluminum in Airborne Particulate Matter

    PubMed Central

    Di Filippo, Patrizia; Riccardi, Carmela; Pomata, Donatella; Marsiglia, Riccardo; Console, Carla; Puri, Daniele

    2018-01-01

    Fosetyl-aluminum is a synthetic fungicide administered to plants especially to prevent diseases caused by the members of the Peronosporales and several Phytophthora species. Herein, we present a selective liquid chromatography-tandem mass spectrometry (LC-MS/MS) method to analyze residues of fosetyl-A1 in air particulate matter. This study was performed in perspective of an exposure assessment of this substance of health concern in environments where high levels of fosetly-Al, relatively to airborne particulate matter, can be found after spraying it. The cleanup procedure of the analyte, from sampled filters of atmospheric particulate matter, was optimized using a Strata X solid-phase extraction cartridge, after accelerated extraction by using water. The chromatographic separation was achieved using a polymeric column based on hydrophilic interaction in step elution with water/acetonitrile, whereas the mass spectrometric detection was performed in negative electrospray ionization. The proposed method resulted to be a simple, fast, and suitable method for confirmation purposes. PMID:29686933

  3. Monitoring of cotton dust and health risk assessment in small-scale weaving industry.

    PubMed

    Tahir, Muhammad Wajid; Mumtaz, Muhammad Waseem; Tauseef, Shanza; Sajjad, Muqadas; Nazeer, Awais; Farheen, Nazish; Iqbal, Muddsar

    2012-08-01

    The present study describes the estimation of particulate matter (cotton dust) with different sizes, i.e., PM(1.0), PM(2.5), PM(4.0), and PM(10.0 μm) in small-scale weaving industry (power looms) situated in district Hafizabad, Punjab, Pakistan, and the assessment of health problems of workers associated with these pollutants. A significant difference was found in PM(1.0), PM(2.5), PM(4.0), and PM(10.0) with reference to nine different sampling stations with p values <0.05. Multiple comparisons of particulate matter with respect to size, i.e. PM(1.0), PM(2.5), PM(4.0), and PM(10.0), depict that PM(1.0) differs significantly from PM(2.5), PM(4.0), and PM(10.0), with p values <0.05 and that PM(2.5) differs significantly from PM(1.0) and PM(10.0), with p values <0.05, whereas PM(2.5) differs non-significantly from PM(4.0), with a p value >0.05 in defined sampling stations on an average basis. Majority of the workers were facing several diseases due to interaction with particulate matter (cotton dust) during working hours. Flue, cough, eye, and skin infections were the most common diseases among workers caused by particulate matter (cotton dust).

  4. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOEpatents

    Gonze, Eugene V.; Brown, David B.

    2010-02-02

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  5. An Evaluation of Sharp Cut Cyclones for Sampling Diesel Particulate Matter Aerosol in the Presence of Respirable Dust

    PubMed Central

    Cauda, Emanuele; Sheehan, Maura; Gussman, Robert; Kenny, Lee; Volkwein, Jon

    2015-01-01

    Two prototype cyclones were the subjects of a comparative research campaign with a diesel particulate matter sampler (DPMS) that consists of a respirable cyclone combined with a downstream impactor. The DPMS is currently used in mining environments to separate dust from the diesel particulate matter and to avoid interferences in the analysis of integrated samples and direct-reading monitoring in occupational environments. The sampling characteristics of all three devices were compared using ammonium fluorescein, diesel, and coal dust aerosols. With solid spherical test aerosols at low particle loadings, the aerodynamic size-selection characteristics of all three devices were found to be similar, with 50% penetration efficiencies (d50) close to the design value of 0.8 µm, as required by the US Mine Safety and Health Administration for monitoring occupational exposure to diesel particulate matter in US mining operations. The prototype cyclones were shown to have ‘sharp cut’ size-selection characteristics that equaled or exceeded the sharpness of the DPMS. The penetration of diesel aerosols was optimal for all three samplers, while the results of the tests with coal dust induced the exclusion of one of the prototypes from subsequent testing. The sampling characteristics of the remaining prototype sharp cut cyclone (SCC) and the DPMS were tested with different loading of coal dust. While the characteristics of the SCC remained constant, the deposited respirable coal dust particles altered the size-selection performance of the currently used sampler. This study demonstrates that the SCC performed better overall than the DPMS. PMID:25060240

  6. Particle size distribution characteristics of cotton gin battery condenser system total particulate emissions

    USDA-ARS?s Scientific Manuscript database

    This report is part of a project to characterize cotton gin emissions from the standpoint of total particulate stack sampling and particle size analyses. In 2013, EPA published a more stringent standard for particulate matter with nominal diameter less than or equal to 2.5 µm (PM2.5). This created a...

  7. NHEXAS PHASE I ARIZONA STUDY--STANDARD OPERATING PROCEDURE FOR PREPARATION OF PM AND URG IMPACTORS AND IMPACTION PLATES (UA-L-8.1)

    EPA Science Inventory

    The purpose of this SOP is to describe the stages of preparation required for Harvard particulate matter (PM) sampler impactor: (1) prior to in-field use of the particulate sampling system, (2) in-field sampling, and (3) disassembly after field use. This procedure applies direct...

  8. PIXE analysis of airborne particulate matter from Monterrey, Mexico. A first survey

    NASA Astrophysics Data System (ADS)

    Aldape, F.; Flores M, J.; Díaz, R. V.; Hernández-Méndez, B.; Montoya Z, J. M.; Blanco, E. E.; Fuentes, A. F.; Torres-Martínez, L. M.

    1999-04-01

    A first survey of elemental contents in airborne particulate matter from Monterrey, Nuevo León, Mexico, was performed using PIXE. This second largest industrial city is located 715 km north of Mexico City, and counts with a population of nearly three million inhabitants in its conurbation. Air pollution in the place comes from a great variety of industries ranging from iron smelters to furniture manufacturing, as well as from fuel combustion in vehicles and industries. This study presents results of elemental contents in airborne particulate matter in two particle size fractions: PM 2.5 and PM 15. The samples were collected during five weeks on working days, Monday-Friday, from 9 December 1996 to 14 January 1997. Two samples a day were collected, 12 h each, night-time and day-time. These first results show local pollution as typical from a large urban area in conjunction with an active industry. Thirteen elements were consistently detected in most of the samples and some episodes due to both industrial and human activities were identified. A general discussion about the results obtained is presented.

  9. Oxidative potential (OP) and mineralogy of iron ore particulate matter at the Gol-E-Gohar Mining and Industrial Facility (Iran).

    PubMed

    Soltani, Naghmeh; Keshavarzi, Behnam; Sorooshian, Armin; Moore, Farid; Dunster, Christina; Dominguez, Ana Oliete; Kelly, Frank J; Dhakal, Prakash; Ahmadi, Mohamad Reza; Asadi, Sina

    2017-03-09

    Concentrations of total suspended particulate matter, particulate matter with aerodynamic diameter <2.5 μm (PM 2.5 ), particulate matter <10 μm (PM 10 ), and fallout dust were measured at the Iranian Gol-E-Gohar Mining and Industrial Facility. Samples were characterized in terms of mineralogy, morphology, and oxidative potential. Results show that indoor samples exceeded the 24-h PM 2.5 and PM 10 mass concentration limits (35 and 150 µg m -3 , respectively) set by the US National Ambient Air Quality Standards. Calcite, magnetite, tremolite, pyrite, talc, and clay minerals such as kaolinite, vermiculite, and illite are the major phases of the iron ore PM. Accessory minerals are quartz, dolomite, hematite, actinolite, biotite, albite, nimite, laumontite, diopside, and muscovite. The scanning electron microscope structure of fibrous-elongated minerals revealed individual fibers in the range of 1.5 nm to 71.65 µm in length and 0.2 nm to 3.7 µm in diameter. The presence of minerals related to respiratory diseases, such as talc, crystalline silica, and needle-shaped minerals like amphibole asbestos (tremolite and actinolite), strongly suggests the need for detailed health-based studies in the region. The particulate samples show low to medium oxidative potential per unit of mass, in relation to an urban road side control, being more reactive with ascorbate than with glutathione or urate. However, the PM oxidative potential per volume of air is exceptionally high, confirming that the workers are exposed to a considerable oxidative environment. PM released by iron ore mining and processing activities should be considered a potential health risk to the mine workers and nearby employees, and strategies to combat the issue are suggested.

  10. Characterizing mineral dusts and other aerosols from the Middle East--Part 1: ambient sampling.

    PubMed

    Engelbrecht, Johann P; McDonald, Eric V; Gillies, John A; Jayanty, R K M; Casuccio, Gary; Gertler, Alan W

    2009-02-01

    The purpose of the Enhanced Particulate Matter Surveillance Program was to provide scientifically founded information on the chemical and physical properties of dust collected over a period of approximately 1 year in Djibouti, Afghanistan (Bagram, Khowst), Qatar, United Arab Emirates, Iraq (Balad, Baghdad, Tallil, Tikrit, Taji, Al Asad), and Kuwait (northern, central, coastal, and southern regions). Three collocated low-volume particulate samplers, one each for the total suspended particulate matter, < 10 micro m in aerodynamic diameter (PM(10)) particulate matter, and < 2.5 micro m in aerodynamic diameter (PM(2.5)) particulate matter, were deployed at each of the 15 sites, operating on a '1 in 6' day sampling schedule. Trace-element analysis was performed to measure levels of potentially harmful metals, while major-element and ion-chemistry analyses provided an estimate of mineral components. Scanning electron microscopy with energy dispersive spectroscopy was used to analyze the chemical composition of small individual particles. Secondary electron images provided information on particle size and shape. This study shows the three main air pollutant types to be geological dust, smoke from burn pits, and heavy metal condensates (possibly from metals smelting and battery manufacturing facilities). Non-dust storm events resulted in elevated trace metal concentrations in Baghdad, Balad, and Taji in Iraq. Scanning-electron-microscopy secondary electron images of individual particles revealed no evidence of freshly fractured quartz grains. In all instances, quartz grains had rounded edges and mineral grains were generally coated by clay minerals and iron oxides.

  11. Concentration and movement of neonicotinoids as particulate matter downwind during agricultural practices using air samplers in southwestern Ontario, Canada.

    PubMed

    Forero, Luis Gabriel; Limay-Rios, Victor; Xue, Yingen; Schaafsma, Arthur

    2017-12-01

    Atmospheric emissions of neonicotinoid seed treatment insecticides as particulate matter in field crops occur mainly for two reasons: 1) due to abraded dust of treated seed generated during planting using vacuum planters, and 2) as a result of disturbances (tillage or wind events) in the surface of parental soils which release wind erodible soil-bound residues. In the present study, concentration and movement of neonicotinoids as particulate matter were quantified under real conditions using passive and active air samplers. Average neonicotinoid concentrations in Total Suspended Particulate (TSP) using passive samplers were 0.48 ng/cm 2 , trace, trace (LOD 0.80 and 0.04 ng/cm 2 for clothianidin and thiamethoxam, respectively), and using active samplers 16.22, 1.91 and 0.61 ng/m 3 during planting, tillage and wind events, respectively. There was a difference between events on total neonicotinoid concentration collected in particulate matter using either passive or active sampling. Distance of sampling from the source field during planting of treated seed had an effect on total neonicotinoid air concentration. However, during tillage distance did not present an effect on measured concentrations. Using hypothetical scenarios, values of contact exposure for a honey bee were estimated to be in the range from 1.1% to 36.4% of the reference contact LD 50 value of clothianidin of 44 ng/bee. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Direct ultrasonic agitation for rapid extraction of organic matter from airborne particulate.

    PubMed

    Lee, S C; Zou, S C; Ho, K F; Chan, L Y

    2001-01-02

    Direct ultrasonic extraction (DUE) is proposed as simple and rapid sample pretreatment method. This new approach is applied to the extraction of particulate organic matter (POM) from airborne particulate by using dichloromethane (DCM) or DCM/methanol (90/10, v/v) as extractant. The analytical determination was carried out by weighing the extractable POM on an electrobalance. Total recovery for POM could be obtained when the sample was extracted three times with 25-50 mL extractant each for about 5 min at 50 W ultrasonic power. In comparison with conventional Soxhlet extraction, less extraction time (total 15 min only) and solvent consumption (100 mL) were required by DUE. The efficiency of the DUE was similar or even higher than the routine Soxhlet method. Additionally, the new extractor is very simple and easy to use and can accelerate the extraction procedures of organic components from various solid samples.

  13. Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter

    NASA Astrophysics Data System (ADS)

    del Rosario Sienra, María; Rosazza, Nelson G.; Préndez, Margarita

    2005-06-01

    Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North-East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m -3, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m -3. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.

  14. Analysis of Particulate and Fiber Debris Samples Returned from the International Space Station

    NASA Technical Reports Server (NTRS)

    Perry, Jay L.; Coston, James E.

    2014-01-01

    During the period of International Space Station (ISS) Increments 30 and 31, crewmember reports cited differences in the cabin environment relating to particulate matter and fiber debris compared to earlier experience as well as allergic responses to the cabin environment. It was hypothesized that a change in the cabin atmosphere's suspended particulate matter load may be responsible for the reported situation. Samples were collected and returned to ground-based laboratories for assessment. Assessments included physical classification, optical microscopy and photographic analysis, and scanning electron microscopy (SEM) evaluation using energy dispersive X-ray spectrometry (EDS) methods. Particular points of interest for assessing the samples were for the presence of allergens, carbon dioxide removal assembly (CDRA) zeolite dust, and FGB panel fibers. The results from the physical classification, optical microscopy and photographic analysis, and SEM EDS analysis are presented and discussed.

  15. Characterisation of PM(10), PM(2.5) and benzene soluble organic fraction of particulate matter in an urban area of Kolkata, India.

    PubMed

    Gupta, A K; Nag, Subhankar; Mukhopadhyay, U K

    2006-04-01

    In this study, the relationship between inhalable particulate (PM(10)), fine particulate (PM(2.5)), coarse particles (PM(2.5 - 10)) and meteorological parameters such as temperature, relative humidity, solar radiation, wind speed were statistically analyzed and modelled for urban area of Kolkata during winter months of 2003-2004. Ambient air quality was monitored with a sampling frequency of twenty-four hours at three monitoring sites located near traffic intersections and in an industrial area. The monitoring sites were located 3-5 m above ground near highly trafficked and congested areas. The 24 h average PM(10) and PM(2.5) samples were collected using Thermo-Andersen high volume samplers and exposed filter papers were extracted and analysed for benzene soluble organic fraction. The ratios between PM(2.5) and PM(10) were found to be in the range of 0.6 to 0.92 and the highest ratio was found in the most polluted urban site. Statistical analysis has shown a strong positive correlation between PM(10) and PM(2.5) and inverse correlation was observed between particulate matter (PM(10) and PM(2.5)) and wind speed. Statistical analysis of air quality data shows that PM(10) and PM(2.5) are showing poor correlation with temperature, relative humidity and solar radiation. Regression equations for PM(10) and PM(2.5) and meteorological parameters were developed. The organic fraction of particulate matter soluble in benzene is an indication of poly aromatic hydrocarbon (PAH) concentration present in particulate matter. The relationship between the benzene soluble organic fraction (BSOF) of inhalable particulate (PM(10)) and fine particulate (PM(2.5)) were analysed for urban area of Kolkata. Significant positive correlation was observed between benzene soluble organic fraction of PM(10) (BSM10) and benzene soluble organic fraction of PM(2.5) (BSM2.5). Regression equations for BSM10 and BSM2.5 were developed.

  16. Measurements of particulate semi-volatile material

    NASA Astrophysics Data System (ADS)

    Pang, Yanbo

    2000-10-01

    A new innovative sampling system, PC-BOSS, was developed by the combination of particle concentrator and BOSS denuder techniques in response to the new EPA PM2.5 standard and to meet top research priorities for particulate matter that were identified by the National Research Council. The PC-BOSS (P_article C_oncentrator- B_righam Young University O_rganic S_ampling S_ystem) can accurately determine not only PM2.5 stable mass and species such as sulfate, but also particulate semi- volatile material. Several field comparison studies of the PC-BOSS with the EPA PM2.5 reference method and state-of-the-art fine particle measurement methods confirm the capability of the PC-BOSS to accurately determine particulate semi-volatile material, especially organic compounds. This is the first routine sampling system for the determination of both particulate semi-volatile inorganic and organic material. Two other denuder system samplers for the determination of PM2.5 total mass including semi-volatile material were also developed for PM2.5 research and exposure monitoring. Results of studies around the United States indicate that the EPA PM2.5 FRM (Federal Reference Method) under- measured PM2.5 mass by 20-30% compared to PC-BOSS results due to the loss of particulate nitrate and semi-volatile organic compounds during sampling. Organic material is mostly responsible for this under- measurement by the FRM. Using our new sampling system in epidemiological and exposure studies will be essential to providing answers to some top research priorities for particulate matter and promote a better PM2.5 standard for the protection of human health because some fractions of particulate semi-volatile organic compounds are toxic and are possibly responsible for health effects associated with exposure to particulate matter. The atmospheric chemistry of organic aerosols in the troposphere and stratosphere is still largely unknown because of the lack of detailed organic aerosol information. The importance of organic aerosols might also be underestimated because current data on organic aerosols in the troposphere and stratosphere were mostly obtained by traditional methods, like the FRM method. Using PC-BOSS to study organic aerosols in the troposphere and stratosphere will provide not only more but also more accurate information about organic aerosols, and significantly improve the understanding of the role of aerosols in global warming, ozone depletion, and atmospheric heterogenous chemistry.

  17. Particulate matter in exhaled breath condensate: A promising indicator of environmental conditions

    NASA Astrophysics Data System (ADS)

    Pinheiro, Teresa; Alexandra Barreiros, M.; Alves, Luis C.; Felix, Pedro M.; Franco, Cristiana; Sousa, Joana; Almeida, S. M.

    2011-10-01

    Assessing the retention of aerosol particles in the human lung, one of the most important pathways of absorption, is a demanding issue. At present, there is no direct biomarker of exposure for the respiratory system. The collection of exhaled breath condensate (EBC) constitutes a new non-invasive method for sampling from the lung. However, the heterogeneity of the sample due to particulate matter suspended in the condensed phase may influence the quality of analytical results in occupational assessments. The main objective of the study was to confirm the presence of particulate matter in the condensate, to investigate how large the particles in suspension could be and to determine their elemental contents relative to those of EBC matrix. This paper reports on preliminary nuclear microprobe data of particulate matter in EBC. The sizes and the elemental contents of particles suspended in EBC of workers of a lead processing industry and in EBC of non-exposed individuals were inspected. Results demonstrated that EBC of workers contain large aerosol particles, isolated and in agglomerates, contrasting with non-exposed individuals. The particles contained high concentrations of Cl, Ca, Zn and Pb that are elements associated to the production process. These elements were also present in the EBC matrix although in much lower levels, suggesting that a fraction of the inhaled particulate matter was solubilised or their size-ranges were below the nuclear microprobe resolution. Therefore, the morphological characterization of individual particles achieved with nuclear microprobe techniques helped describing EBC constituents in detail, to comprehend their origin and enabled to delineate methodological procedures that can be recommended in occupational assessments. These aspects are critical to the validation of EBC as a biomarker of exposure to metals for the respiratory system.

  18. Modeling particulate matter emissions during mineral loading process under weak wind simulation.

    PubMed

    Zhang, Xiaochun; Chen, Weiping; Ma, Chun; Zhan, Shuifen

    2013-04-01

    The quantification of particulate matter emissions from mineral handling is an important problem for the quantification of global emissions on industrial sites. Mineral particulate matter emissions could adversely impact environmental quality in mining regions, transport regions, and even on a global scale. Mineral loading is an important process contributing to mineral particulate matter emissions, especially under weak wind conditions. Mathematical models are effective ways to evaluate particulate matter emissions during the mineral loading process. The currently used empirical models based on the form of a power function do not predict particulate matter emissions accurately under weak wind conditions. At low particulate matter emissions, the models overestimated, and at high particulate matter emissions, the models underestimated emission factors. We conducted wind tunnel experiments to evaluate the particulate matter emission factors for the mineral loading process. A new approach based on the mathematical form of a logistical function was developed and tested. It provided a realistic depiction of the particulate matter emissions during the mineral loading process, accounting for fractions of fine mineral particles, dropping height, and wind velocity. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. Size distributions of ambient air particles and enrichment factor analyses of metallic elements at Taichung Harbor near the Taiwan Strait

    NASA Astrophysics Data System (ADS)

    Fang, Guor-Cheng; Wu, Yuh-Shen; Chang, Shih-Yu; Huang, Shih-Han; Rau, Jui-Yeh

    2006-10-01

    This work attempts to characterize metallic elements associated with atmospheric particulate matter on a dry deposition plate, a TE-PUF high-volume air sampler and a universal air sampler. Dry deposition fluxes of particulates and concentrations of total suspended particulate, fine (PM 2.5) and coarse (PM 2.5-10) particulate matters were collected at Taichung harbor sampling sites from August 2004 to January 2005. Chemical analyses of metallic elements were made using a flame atomic absorption spectrophotometer coupled with hollow cathode lamps. Concentrations of metal elements in the forms of coarse particles and fine particles as well as the coarse/fine particulate ratios were presented. Statistical methods such as correlation analysis, principal component analysis and enrichment factor analysis were performed to compare the chemical components and identify possible emission sources at the sampling sites. Metallic elements of Cu, Zn, Pb, Cr, Ni and Mg had higher EF crust ratios in winter and spring than in summer and autumn. Diurnal and nocturnal variations of metallic element concentrations in fine and coarse particles were also discussed.

  20. U.S.-MEXICO BORDER PROGRAM ARIZONA BORDER STUDY--STANDARD OPERATING PROCEDURE FOR PREPARATION OF PM AND URG IMPACTORS AND IMPACTION PLATES (UA-L-8.1)

    EPA Science Inventory

    The purpose of this SOP is to describe the stages of preparation required for Harvard particulate matter (PM) sampler impactor: (1) prior to in-field use of the particulate sampling system, (2) in-field sampling, and (3) disassembly after field use. This procedure applies direct...

  1. Application of particle size distributions to total particulate stack samples to estimate PM2.5 and PM10 emission factors for agricultural sources

    USDA-ARS?s Scientific Manuscript database

    Particle size distributions (PSD) have long been used to more accurately estimate the PM10 fraction of total particulate matter (PM) stack samples taken from agricultural sources. These PSD analyses were typically conducted using a Coulter Counter with 50 micrometer aperture tube. With recent increa...

  2. Particle-bound benzene from diesel engine exhaust.

    PubMed

    Muzyka, V; Veimer, S; Shmidt, N

    1998-12-01

    The large surface area of the carbon core of diesel exhaust particles may contribute to the adsorption or condensation of such volatile carcinogenic organic compounds as benzene. The attention of this study focused on determining the distribution of benzene between the gas and particulate phases in the breathing zone of bus garage workers. Benzene and suspended particulate matter were evaluated jointly in the air of a municipal bus garage. Personal passive monitors were used for benzene sampling in the breathing zone of the workers. Active samplers were used for sampling diesel exhaust particles and the benzene associated with them. The benzene levels were measured by gas chromatography. Diesel engine exhaust from buses was the main source of air pollution caused by benzene and particles in this study. The concentration of benzene in the gas and particulate phases showed a wide range of variation, depending on the distance of the workplace from the operating diesel engine. Benzene present in the breathing zone of the workers was distributed between the gas and particulate phases. The amounts of benzene associated with particles were significantly lower in summer than in winter. The particulate matter of diesel exhaust contains benzene in amounts comparable to the concentrations of carcinogenic polycyclic aromatic hydrocarbons (PAH) and the usually found nitro-PAH. The concentration of benzene in the gas phase and in the suspended particulate matter of air can serve as an additional indicator of exposure to diesel exhaust and its carcinogenicity.

  3. Source apportionment of ambient PM10 and PM2.5 in Haikou, China

    NASA Astrophysics Data System (ADS)

    Fang, Xiaozhen; Bi, Xiaohui; Xu, Hong; Wu, Jianhui; Zhang, Yufen; Feng, Yinchang

    2017-07-01

    In order to identify the sources of PM10 and PM2.5 in Haikou, 60 ambient air samples were collected in winter and spring, respectively. Fifteen elements (Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn and Pb), water-soluble ions (SO42 - and NO3-), and organic carbon (OC) and elemental carbon (EC) were analyzed. It was clear that the concentration of particulate matter was higher in winter than in spring. The value of PM2.5/PM10 was > 0.6. Moreover, the proportions of TC, ions, Na, Al, Si and Ca were more high in PM10 and PM2.5. The SOC concentration was estimated by the minimum OC/EC ratio method, and deducted from particulate matter compositions when running CMB model. According to the results of CMB model, the resuspended dust (17.5-35.0%), vehicle exhaust (14.9-23.6%) and secondary particulates (20.4-28.8%) were the major source categories of ambient particulate matter. Additionally, sea salt also had partial contribution (3-8%). And back trajectory analysis results showed that particulate matter was greatly affected by regional sources in winter, while less affected in spring. So particulate matter was not only affected by local sources, but also affected by sea salt and regional sources in coastal cities. Further research could focuses on establishing the actual secondary particles profiles and identifying the local and regional sources of PM at once by one model or analysis method.

  4. 77 FR 65107 - Implementation of the New Source Review (NSR) Program for Particulate Matter Less Than 2.5...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-25

    ...-AR30 Implementation of the New Source Review (NSR) Program for Particulate Matter Less Than 2.5... Particulate Matter AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule. SUMMARY: The EPA is... for particulate matter (PM) known as ``particulate matter emissions'' in the context of the PSD and...

  5. Wind-Mediated Spread of Low-Pathogenic Avian Influenza Virus into the Environment during Outbreaks at Commercial Poultry Farms.

    PubMed

    Jonges, Marcel; van Leuken, Jeroen; Wouters, Inge; Koch, Guus; Meijer, Adam; Koopmans, Marion

    2015-01-01

    Avian influenza virus-infected poultry can release a large amount of virus-contaminated droppings that serve as sources of infection for susceptible birds. Much research so far has focused on virus spread within flocks. However, as fecal material or manure is a major constituent of airborne poultry dust, virus-contaminated particulate matter from infected flocks may be dispersed into the environment. We collected samples of suspended particulate matter, or the inhalable dust fraction, inside, upwind and downwind of buildings holding poultry infected with low-pathogenic avian influenza virus, and tested them for the presence of endotoxins and influenza virus to characterize the potential impact of airborne influenza virus transmission during outbreaks at commercial poultry farms. Influenza viruses were detected by RT-PCR in filter-rinse fluids collected up to 60 meters downwind from the barns, but virus isolation did not yield any isolates. Viral loads in the air samples were low and beyond the limit of RT-PCR quantification except for one in-barn measurement showing a virus concentration of 8.48 x 10(4) genome copies/m(3). Air samples taken outside poultry barns had endotoxin concentrations of ~50 EU/m(3) that declined with increasing distance from the barn. Atmospheric dispersion modeling of particulate matter, using location-specific meteorological data for the sampling days, demonstrated a positive correlation between endotoxin measurements and modeled particulate matter concentrations, with an R(2) varying from 0.59 to 0.88. Our data suggest that areas at high risk for human or animal exposure to airborne influenza viruses can be modeled during an outbreak to allow directed interventions following targeted surveillance.

  6. Proximate composition of poultry processing wastewater particulate matter from broiler slaughter plants.

    PubMed

    Kiepper, B H; Merka, W C; Fletcher, D L

    2008-08-01

    An experiment was conducted to compare the proximate composition of particulate matter recovered from poultry processing wastewater (PPW) generated by broiler slaughter plants. Poultry processing wastewater is the cumulative wastewater stream generated during the processing of poultry following primary and secondary physical screening (typically to 500 mum) that removes gross offal. Composite samples of PPW from 3 broiler slaughter plants (southeast United States) were collected over 8 consecutive weeks. All 3 broiler slaughter plants process young chickens with an average live weight of 2.0 kg. At each plant, a single 72-L composite sample was collected using an automatic sampler programmed to collect 1 L of wastewater every 20 min for 24 h during one normal processing day each week. Each composite sample was thoroughly mixed, and 60 L was passed through a series of sieves (2.0 mm, 1.0 mm, 500 mum, and 53 mum). The amount of particulate solids collected on the 2.0 mm, 1.0 mm, and 500 mum sieves was insignificant. The solids recovered from the 53-mum sieve were subjected to proximate analysis to determine percent moisture, fat, protein, ash, and fiber. The average percentages of fat, protein, ash, and fiber for all samples on a dry-weight basis were 55.3, 27.1, 6.1, and 4.1, respectively. Fat made up over half of the dry-weight matter recovered, representing PPW particulate matter between 500 and 53 mum. Despite the variation in number of birds processed daily, further processing operations, and number and type of wastewater screens utilized, there were no significance differences in percentage of fat and fiber between the slaughter plants. There were significant differences in percent protein and ash between the slaughter plants.

  7. Recognition of iron ions by carbazole-desferrioxamine fluorescent sensor and its application in total iron detection in airbone particulate matter.

    PubMed

    Delattre, François; Cazier-Dennin, Francine; Leleu, Ludovic; Dewaele, Dorothée; Landy, David; Mallard, Isabelle; Danjou, Pierre-Edouard

    2015-11-01

    This work reports on an efficient microwave irradiation synthesis of a new fluorescent chemosensor based on desferrioxamine B (DFO-B) and carbazole moiety. Furthermore, this novel chemosensor was employed for a comparative study of real environmental samples of airbone particulate matter collected from Dunkirk (Northern of France). Among selected relevant metal cations present in its airbone particulate matter, such as Na(+), K(+), Mg(2+), Ca(2+), Al(3+), Cr(3+), Mn(2+) and Zn(2+), this molecular device proved to be outstandingly sensitive toward Fe(3+) with a limit of detection of 1.49 ppb (2.1×10(-8) M) in methanol allowing the estimation of total iron in atmospheric particles. Copyright © 2015 Elsevier B.V. All rights reserved.

  8. The Effect of Mississippi River Discharge on the Concentration and Composition of Particulate Matter along the Texas-Louisiana Shelf during Summers 2012 and 2013

    NASA Astrophysics Data System (ADS)

    Richardson, M. J.; Zuck, N.; Gardner, W. D.

    2016-02-01

    Flow from the Mississippi-Atchafalaya River System generally peaks during the spring freshet, discharging nutrient-rich fresh water and sediment into the northern Gulf of Mexico. The peak discharge varies year to year as a result of varying drought or flood conditions in the Mississippi watershed. When compared to an 8-year climatological average, summer 2012 is characterized by low discharge into the northern Gulf of Mexico, whereas summer 2013 is characterized by average discharge conditions. Water samples were collected during four cruises during June and August of 2012 and 2013 to assess the changes in concentration and composition of bulk particulate matter. While no consistent relationship between particulate matter composition and hypoxia was observed, there are several statistically significant seasonal and inter-annual changes in the concentration and composition of particulate matter associated with varying river discharge. There is also evidence that some sub-pycnocline turbidity and chlorophyll-a may be due to in situ primary productivity, rather than settled plankton containing chlorophyll-a.

  9. Barrow Black Carbon Source and Impact Study Final Campaign Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barrett, Tate

    2014-07-01

    The goal of the Barrow Black Carbon Source and Impact (BBCSI) Study was to characterize the concentration and isotopic composition of carbonaceous atmospheric particulate matter (PM) at the Atmospheric Radiation Measurement site in Barrow, AK. The carbonaceous component was characterized via measurement of the organic and black carbon (OC and BC) components of the total PM. To facilitate complete characterization of the particulate matter, filter-based collections were used, including a medium volume PM2.5 sampler and a high volume PM10 sampler. Thirty-eight fine (PM2.5) and 49 coarse (PM10) particulate matter fractions were collected at weekly and bi-monthly intervals. The PM2.5 samplermore » operated with minimal maintenance during the 12 month campaign. The PM10 sampler used for the BBCSI used standard Tisch hi-vol motors which have a known lifetime of ~1 month under constant use; this necessitated monthly maintenance and it is suggested that the motors be upgraded to industrial blowers for future deployment in the Arctic. The BBCSI sampling campaign successfully collected and archived 87 ambient atmospheric particulate matter samples from Barrow, AK from July 2012 to June 2013. Preliminary analysis of the organic and black carbon concentrations has been completed. This campaign confirmed known trends of high BC lasting from the winter through to spring haze periods and low BC concentrations in the summer.« less

  10. SEM-EDX analysis in the source apportionment of particulate matter on Hypogymnia physodes lichen transplants around the Cu smelter and former mining town of Karabash, South Urals, Russia.

    PubMed

    Williamson, B J; Mikhailova, I; Purvis, O W; Udachin, V

    2004-04-25

    Scanning electron microscopy with energy-dispersive X-ray analysis (SEM-EDX) of particulate matter on lichen transplant thalli (Hypogymnia physodes) was assessed as a complementary technique to wet chemical analysis for source apportionment of airborne contaminants. Transplants (2 month exposure) stationed in the Cu smelter and former mining town of Karabash were compared with those from a control site 30 km south. Particulate matter in Karabash samples (715 analyses) showed higher levels of S, Pb, Cu, Sn and Zn compared with the control (598 analyses). Complex element associations among the particles confounded detailed mineralogical identifications, and therefore a simplified particle classification scheme was devised for source apportionment. Karabash samples contained high levels of particles classified as mining-related (MRP), and these were also identified in control samples, indicating wide spatial dispersion from the smelter and highlighting the sensitivity of the method. It was noted that MRP <2.5-microm diameter were poorly represented on lichen surfaces suggesting this may limit the usefulness of Hypogymnia transplants as proxies when assessing human health impacts from airborne particulates. Analyses of the lichen thallus surface (away from surface particulates) revealed high levels of Cu, Zn, Fe and Pb associated with organics in the Karabash samples compared with the control, with a proportionate loss of K, interpreted as being due to a stress-related increase in cell membrane permeability. This type of analysis may provide a novel SEM-EDX-based method for assessing lichen vitality. The techniques developed are presented and further implications of the study are discussed.

  11. 40 CFR 60.422 - Standards for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for particulate matter. 60... Manufacture § 60.422 Standards for particulate matter. On or after the date on which the performance test... sulfate dryer, particulate matter at an emission rate exceeding 0.15 kilogram of particulate per megagram...

  12. 40 CFR 60.422 - Standards for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for particulate matter. 60... Manufacture § 60.422 Standards for particulate matter. On or after the date on which the performance test... sulfate dryer, particulate matter at an emission rate exceeding 0.15 kilogram of particulate per megagram...

  13. 40 CFR 60.422 - Standards for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for particulate matter. 60... Manufacture § 60.422 Standards for particulate matter. On or after the date on which the performance test... sulfate dryer, particulate matter at an emission rate exceeding 0.15 kilogram of particulate per megagram...

  14. 40 CFR 60.422 - Standards for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standards for particulate matter. 60... Manufacture § 60.422 Standards for particulate matter. On or after the date on which the performance test... sulfate dryer, particulate matter at an emission rate exceeding 0.15 kilogram of particulate per megagram...

  15. Real-Time Measurements and Characterization of Airborne Particulate Matter from a Primary Silicon Carbide Production Plant.

    PubMed

    Jørgensen, Rikke Bramming; Kero, Ida Teresia

    2017-12-20

    Airborne particulate matter in the silicon carbide (SiC) industry is a known health hazard. The aims of this study were to elucidate whether the particulate matter generated inside the Acheson furnace during active operation is representative of the overall particulate matter in the furnace hall, and whether the Acheson furnaces are the main sources of ultrafine particles (UFP) in primary SiC production. The number concentration of ultrafine particles was evaluated using an Electrical Low Pressure Impactor (ELPI TM , Dekati Ltd., Tampere, Finland), a Fast Mobility Particle Sizer (FMPS TM , TSI, Shoreview, MN, USA) and a Condensation Particle Counter (CPC, TSI, Shoreview, MN, USA). The results are discussed in terms of particle number concentration, particle size distribution and are also characterized by means of electron microscopy (TEM/SEM). Two locations were investigated; the industrial Acheson process furnace hall and a pilot furnace hall; both of which represent an active operating furnace. The geometric mean of the particle number concentration in the Acheson process furnace hall was 7.7 × 10⁴ particles/cm³ for the UFP fraction and 1.0 × 10⁵ particles/cm³ for the submicrometre fraction. Particulate matter collected at the two sites was analysed by electron microscopy. The PM from the Acheson process furnace hall is dominated by carbonaceous particles while the samples collected near the pilot furnace are primarily rich in silicon.

  16. Real-Time Measurements and Characterization of Airborne Particulate Matter from a Primary Silicon Carbide Production Plant

    PubMed Central

    2017-01-01

    Airborne particulate matter in the silicon carbide (SiC) industry is a known health hazard. The aims of this study were to elucidate whether the particulate matter generated inside the Acheson furnace during active operation is representative of the overall particulate matter in the furnace hall, and whether the Acheson furnaces are the main sources of ultrafine particles (UFP) in primary SiC production. The number concentration of ultrafine particles was evaluated using an Electrical Low Pressure Impactor (ELPITM, Dekati Ltd., Tampere, Finland), a Fast Mobility Particle Sizer (FMPSTM, TSI, Shoreview, MN, USA) and a Condensation Particle Counter (CPC, TSI, Shoreview, MN, USA). The results are discussed in terms of particle number concentration, particle size distribution and are also characterized by means of electron microscopy (TEM/SEM). Two locations were investigated; the industrial Acheson process furnace hall and a pilot furnace hall; both of which represent an active operating furnace. The geometric mean of the particle number concentration in the Acheson process furnace hall was 7.7 × 104 particles/cm3 for the UFP fraction and 1.0 × 105 particles/cm3 for the submicrometre fraction. Particulate matter collected at the two sites was analysed by electron microscopy. The PM from the Acheson process furnace hall is dominated by carbonaceous particles while the samples collected near the pilot furnace are primarily rich in silicon. PMID:29261158

  17. Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE): Emissions of particulate matter from wood and dung cooking fires, brick kilns, generators, trash and crop residue burning

    NASA Astrophysics Data System (ADS)

    Stone, Elizabeth; Jayarathne, Thilina; Stockwell, Chelsea; Christian, Ted; Bhave, Prakash; Siva Praveen, Puppala; Panday, Arnico; Adhikari, Sagar; Maharjan, Rashmi; Goetz, Doug; DeCarlo, Peter; Saikawa, Eri; Yokelson, Robert

    2016-04-01

    The Nepal Ambient Monitoring and Source Testing Experiment (NAMASTE) field campaign targeted the in situ characterization of widespread and under-sampled combustion sources. In Kathmandu and the Terai, southern Nepal's flat plains, samples of fine particulate matter (PM2.5) were collected from wood and dung cooking fires (n = 22), generators (n = 2), groundwater pumps (n = 2), clamp kilns (n = 3), zig-zag kilns (n = 3), trash burning (n = 4), one heating fire, and one crop residue fire. Co-located measurements of carbon dioxide, carbon monoxide, and volatile organic compounds allowed for the application of the carbon mass balance approach to estimate emission factors for PM2.5, elemental carbon, organic carbon, and water-soluble inorganic ions. Organic matter was chemically speciated using gas chromatography - mass spectrometry for polycyclic aromatic hydrocarbons, sterols, n-alkanes, hopanes, steranes, and levoglucosan, which accounted for 2-8% of the measured organic carbon. These data were used to develop molecular-marker based profiles for use in source apportionment modeling. This study provides quantitative emission factors for particulate matter and its constituents for many important combustion sources in Nepal and South Asia.

  18. Size-selective sampling performance of six low-volume “total” suspended particulate (TSP) inlets

    EPA Science Inventory

    Several low-volume inlets (flow rates ≤ 16.7 liters per minute (Lpm)) are commercially available as components of low-cost, portable ambient particulate matter samplers. Because the inlets themselves do not contain internal fractionators, they are often assumed to representati...

  19. PARTICULATE ORGANIC SOURCE MARKERS IN THE NEW YORK CITY METROPOLITAN AREA

    EPA Science Inventory

    A sampling network of four sites was established for the Speciation of Organics for Apportionment of PM2.5 (SOAP) project during 2002-2003 to investigate composition, seasonal and spatial variability, and source contributions to particulate organic matter in the New York City met...

  20. 30 CFR 57.5075 - Diesel particulate records.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Diesel particulate records. 57.5075 Section 57..., Radiation, Physical Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5075 Diesel particulate records. (a) The table entitled “Diesel Particulate Matter Recordkeeping...

  1. 30 CFR 57.5075 - Diesel particulate records.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Diesel particulate records. 57.5075 Section 57..., Radiation, Physical Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5075 Diesel particulate records. (a) The table entitled “Diesel Particulate Matter Recordkeeping...

  2. Emission characteristics and chemical components of size-segregated particulate matter in iron and steel industry

    NASA Astrophysics Data System (ADS)

    Jia, Jia; Cheng, Shuiyuan; Yao, Sen; Xu, Tiebing; Zhang, Tingting; Ma, Yuetao; Wang, Hongliang; Duan, Wenjiao

    2018-06-01

    As one of the highest energy consumption and pollution industries, the iron and steel industry is regarded as a most important source of particulate matter emission. In this study, chemical components of size-segregated particulate matters (PM) emitted from different manufacturing units in iron and steel industry were sampled by a comprehensive sampling system. Results showed that the average particle mass concentration was highest in sintering process, followed by puddling, steelmaking and then rolling processes. PM samples were divided into eight size fractions for testing the chemical components, SO42- and NH4+ distributed more into fine particles while most of the Ca2+ was concentrated in coarse particles, the size distribution of mineral elements depended on the raw materials applied. Moreover, local database with PM chemical source profiles of iron and steel industry were built and applied in CMAQ modeling for simulating SO42- and NO3- concentration, results showed that the accuracy of model simulation improved with local chemical source profiles compared to the SPECIATE database. The results gained from this study are expected to be helpful to understand the components of PM in iron and steel industry and contribute to the source apportionment researches.

  3. Composition and oxidation state of sulfur in atmospheric particulate matter

    NASA Astrophysics Data System (ADS)

    Longo, Amelia F.; Vine, David J.; King, Laura E.; Oakes, Michelle; Weber, Rodney J.; Huey, Lewis Gregory; Russell, Armistead G.; Ingall, Ellery D.

    2016-10-01

    The chemical and physical speciation of atmospheric sulfur was investigated in ambient aerosol samples using a combination of sulfur near-edge x-ray fluorescence spectroscopy (S-NEXFS) and X-ray fluorescence (XRF) microscopy. These techniques were used to determine the composition and oxidation state of sulfur in common primary emission sources and ambient particulate matter collected from the greater Atlanta area. Ambient particulate matter samples contained two oxidation states: S0 and S+VI. Ninety-five percent of the individual aerosol particles (> 1 µm) analyzed contain S0. Linear combination fitting revealed that S+VI in ambient aerosol was dominated by ammonium sulfate as well as metal sulfates. The finding of metal sulfates provides further evidence for acidic reactions that solubilize metals, such as iron, during atmospheric transport. Emission sources, including biomass burning, coal fly ash, gasoline, diesel, volcanic ash, and aerosolized Atlanta soil, and the commercially available bacterium Bacillus subtilis, contained only S+VI. A commercially available Azotobacter vinelandii sample contained approximately equal proportions of S0 and S+VI. S0 in individual aerosol particles most likely originates from primary emission sources, such as aerosolized bacteria or incomplete combustion.

  4. 75 FR 30710 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Particulate Matter...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-06-02

    ... Promulgation of Air Quality Implementation Plans; Wisconsin; Particulate Matter Standards; Withdrawal of Direct... were made to the particulate matter standards by adding fine particulate standards and revoking the..., Intergovernmental relations, Particulate matter. Authority: 42 U.S.C. 7401 et seq. Dated: May 14, 2010. Walter W...

  5. Chemical characterization of outdoor and subway fine (PM(2.5-1.0)) and coarse (PM(10-2.5)) particulate matter in Seoul (Korea) by computer-controlled scanning electron microscopy (CCSEM).

    PubMed

    Byeon, Sang-Hoon; Willis, Robert; Peters, Thomas M

    2015-02-13

    Outdoor and indoor (subway) samples were collected by passive sampling in urban Seoul (Korea) and analyzed with computer-controlled scanning electron microscopy coupled with energy dispersive x-ray spectroscopy (CCSEM-EDX). Soil/road dust particles accounted for 42%-60% (by weight) of fine particulate matter larger than 1 µm (PM(2.5-1.0)) in outdoor samples and 18% of PM2.5-1.0 in subway samples. Iron-containing particles accounted for only 3%-6% in outdoor samples but 69% in subway samples. Qualitatively similar results were found for coarse particulate matter (PM(10-2.5)) with soil/road dust particles dominating outdoor samples (66%-83%) and iron-containing particles contributing most to subway PM(10-2.5) (44%). As expected, soil/road dust particles comprised a greater mass fraction of PM(10-2.5) than PM(2.5-1.0). Also as expected, the mass fraction of iron-containing particles was substantially less in PM(10-2.5) than in PM(2.5-1.0). Results of this study are consistent with known emission sources in the area and with previous studies, which showed high concentrations of iron-containing particles in the subway compared to outdoor sites. Thus, passive sampling with CCSEM-EDX offers an inexpensive means to assess PM(2.5-1.0) and PM(10-2.5) simultaneously and by composition at multiple locations.

  6. Comparison of fine particle measurements from a direct-reading instrument and a gravimetric sampling method.

    PubMed

    Kim, Jee Young; Magari, Shannon R; Herrick, Robert F; Smith, Thomas J; Christiani, David C

    2004-11-01

    Particulate air pollution, specifically the fine particle fraction (PM2.5), has been associated with increased cardiopulmonary morbidity and mortality in general population studies. Occupational exposure to fine particulate matter can exceed ambient levels by a large factor. Due to increased interest in the health effects of particulate matter, many particle sampling methods have been developed In this study, two such measurement methods were used simultaneously and compared. PM2.5 was sampled using a filter-based gravimetric sampling method and a direct-reading instrument, the TSI Inc. model 8520 DUSTTRAK aerosol monitor. Both sampling methods were used to determine the PM2.5 exposure in a group of boilermakers exposed to welding fumes and residual fuel oil ash. The geometric mean PM2.5 concentration was 0.30 mg/m3 (GSD 3.25) and 0.31 mg/m3 (GSD 2.90)from the DUSTTRAK and gravimetric method, respectively. The Spearman rank correlation coefficient for the gravimetric and DUSTTRAK PM2.5 concentrations was 0.68. Linear regression models indicated that log, DUSTTRAK PM2.5 concentrations significantly predicted loge gravimetric PM2.5 concentrations (p < 0.01). The association between log(e) DUSTTRAK and log, gravimetric PM2.5 concentrations was found to be modified by surrogate measures for seasonal variation and type of aerosol. PM2.5 measurements from the DUSTTRAK are well correlated and highly predictive of measurements from the gravimetric sampling method for the aerosols in these work environments. However, results from this study suggest that aerosol particle characteristics may affect the relationship between the gravimetric and DUSTTRAK PM2.5 measurements. Recalibration of the DUSTTRAK for the specific aerosol, as recommended by the manufacturer, may be necessary to produce valid measures of airborne particulate matter.

  7. Particulate Matter Levels in Ambient Air Adjacent to Industrial Area

    NASA Astrophysics Data System (ADS)

    Mohamed, R. M. S. R.; Nizam, N. M. S.; Al-Gheethi, A. A.; Lajis, A.; Kassim, A. H. M.

    2016-07-01

    Air quality in the residential areas adjacent to the industrial regions is of great concern due to the association with human health risks. In this work, the concentrations of particulate matter (PM10) in the ambient air of UTHM campus was investigated tostudy the air qualityand their compliance to the Malaysian Ambient Air Quality Guidelines (AAQG). The PM10 samples were taken over 24 hours from the most significant area at UTHM including Stadium, KolejKediamanTunDr. Ismail (KKTDI) and MakmalBahan. The meteorological parameters; temperature, relative humidity, wind speed and wind direction as well as particulate matterwere estimated by using E-Sampler Particulate Matter (PM10) Collector. The highest concentrations of PM10 (55.56 µg/m3) was recorded at MakmalBahan during the working and weekend days. However, these concentrations are less than 150 pg/m3. It can be concluded that although UTHM is surrounded by the industrial area, the air quality in the campus still within the standards limits.

  8. Seasonal dynamics of particulate organic matter in the Changjiang Estuary and adjacent coastal waters illustrated by amino acid enantiomers

    NASA Astrophysics Data System (ADS)

    Wu, Ying; Liu, Zongguang; Hu, Jun; Zhu, Zhuoyi; Liu, Sumei; Zhang, Jing

    2016-02-01

    Total suspended matter (TSM) was collected in the Changjiang Estuary and adjacent areas of the East China Sea in July, August, and November 2011, to study the composition and fate of particulate organic nitrogen (PON) during an August typhoon event and bottom trawling activities. Concentrations of particulate organic carbon (POC), particulate nitrogen (PN), and hydrolyzable particulate amino acids (PAA, D- and L-enantiomers) were higher during July and August than during November; however, D-arginine and alanine levels were significantly higher in November. Seasonal trends in the composition of PAAs indicate that in situ production is a key factor in their temporal distribution. No significant increase in TSM or decrease in labile organic matter was observed during the transit period following a typhoon event in August. In contrast, higher primary production was observed at this time as a result of the penetration of Changjiang Diluted Water caused by the typhoon event. Trawling effects were studied by comparing the calm season (July) with the bottom-trawling period (November) at similar sampling sites. The effect of trawling on the composition of bottom organic matter was studied by comparing D-amino acids concentrations and C/N ratios in the calm season (July) with the bottom-trawling period (November). A substantial contribution of microbial organic matter during the November cruise was indicated by a decrease in glutamic acid, an increase in TSM and D-alanine, and a lower carbon/nitrogen (C/N) ratio. In shallow coastal regions, anthropogenic activities (bottom trawling) may enhance the transfer of low-nutritional-value particulate organic matter into the benthic food chain.

  9. Optical analyzer

    DOEpatents

    Hansen, A.D.

    1987-09-28

    An optical analyzer wherein a sample of particulate matter, and particularly of organic matter, which has been collected on a quartz fiber filter is placed in a combustion tube, and light from a light source is passed through the sample. The temperature of the sample is raised at a controlled rate and in a controlled atmosphere. The magnitude of the transmission of light through the sample is detected as the temperature is raised. A data processor, differentiator and a two pen recorder provide a chart of the optical transmission versus temperature and the rate of change of optical transmission versus temperature signatures (T and D) of the sample. These signatures provide information as to physical and chemical processes and a variety of quantitative and qualitative information about the sample. Additional information is obtained by repeating the run in different atmospheres and/or different rates or heating with other samples of the same particulate material collected on other filters. 7 figs.

  10. 40 CFR 52.2059 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Particulate matter... Control strategy: Particulate matter. (a) Pennsylvania has committed to undertake a comprehensive program... Investigating and Controlling Nontraditional Particulate Matter Emissions Task Completion date Scheduled tasks...

  11. 40 CFR 52.2059 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Particulate matter... Control strategy: Particulate matter. (a) Pennsylvania has committed to undertake a comprehensive program... Investigating and Controlling Nontraditional Particulate Matter Emissions Task Completion date Scheduled tasks...

  12. 40 CFR 52.2059 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter... Control strategy: Particulate matter. (a) Pennsylvania has committed to undertake a comprehensive program... Investigating and Controlling Nontraditional Particulate Matter Emissions Task Completion date Scheduled tasks...

  13. 40 CFR 52.2059 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter... Control strategy: Particulate matter. (a) Pennsylvania has committed to undertake a comprehensive program... Investigating and Controlling Nontraditional Particulate Matter Emissions Task Completion date Scheduled tasks...

  14. Concentrations of trace elements and compounds in the airborne suspended particulate matter in Cleveland, Ohio, from August 1971 to August 1972 and their dependence on wind direction: Complete data listing and concentration roses

    NASA Technical Reports Server (NTRS)

    King, R. B.; Neustadter, H. E.

    1976-01-01

    Concentrations of 75 chemical constituents in the airborne particulate matter were measured in Cleveland, Ohio during 1971 and 1972. Daily values, maxima, geometric means and their standard deviations covering a 1-year period (45 to 50 sampling days) at each of 16 sites are presented on microfiche for 60 elements, and for a lesser number of days for 10 polycyclic aromatic hydrocarbon compounds (PAH), the aliphatic hydrocarbon compounds (AH) as a group and carbon. In addition, concentration roses showing directional properties are presented for 39 elements, 10 PAH and the AH as a group. The elements (except carbon) are shown both in terms of concentration and percentage of the suspended particulate matter.

  15. Diversity and Composition of Airborne Fungal Community Associated with Particulate Matters in Beijing during Haze and Non-haze Days.

    PubMed

    Yan, Dong; Zhang, Tao; Su, Jing; Zhao, Li-Li; Wang, Hao; Fang, Xiao-Mei; Zhang, Yu-Qin; Liu, Hong-Yu; Yu, Li-Yan

    2016-01-01

    To assess the diversity and composition of airborne fungi associated with particulate matters (PMs) in Beijing, China, a total of 81 PM samples were collected, which were derived from PM2.5, PM10 fractions, and total suspended particles during haze and non-haze days. The airborne fungal community in these samples was analyzed using the Illumina Miseq platform with fungi-specific primers targeting the internal transcribed spacer 1 region of the large subunit rRNA gene. A total of 797,040 reads belonging to 1633 operational taxonomic units were observed. Of these, 1102 belonged to Ascomycota, 502 to Basidiomycota, 24 to Zygomycota, and 5 to Chytridiomycota. The dominant orders were Pleosporales (29.39%), Capnodiales (27.96%), Eurotiales (10.64%), and Hypocreales (9.01%). The dominant genera were Cladosporium, Alternaria, Fusarium, Penicillium, Sporisorium, and Aspergilus. Analysis of similarities revealed that both particulate matter sizes (R = 0.175, p = 0.001) and air quality levels (R = 0.076, p = 0.006) significantly affected the airborne fungal community composition. The relative abundance of many fungal genera was found to significantly differ among various PM types and air quality levels. Alternaria and Epicoccum were more abundant in total suspended particles samples, Aspergillus in heavy-haze days and PM2.5 samples, and Malassezia in PM2.5 samples and heavy-haze days. Canonical correspondence analysis and permutation tests showed that temperature (p < 0.01), NO2 (p < 0.01), PM10 (p < 0.01), SO2(p < 0.01), CO (p < 0.01), and relative humidity (p < 0.05) were significant factors that determine airborne fungal community composition. The results suggest that diverse airborne fungal communities are associated with particulate matters and may provide reliable data for studying the responses of human body to the increasing level of air pollution in Beijing.

  16. Diversity and Composition of Airborne Fungal Community Associated with Particulate Matters in Beijing during Haze and Non-haze Days

    PubMed Central

    Yan, Dong; Zhang, Tao; Su, Jing; Zhao, Li-Li; Wang, Hao; Fang, Xiao-Mei; Zhang, Yu-Qin; Liu, Hong-Yu; Yu, Li-Yan

    2016-01-01

    To assess the diversity and composition of airborne fungi associated with particulate matters (PMs) in Beijing, China, a total of 81 PM samples were collected, which were derived from PM2.5, PM10 fractions, and total suspended particles during haze and non-haze days. The airborne fungal community in these samples was analyzed using the Illumina Miseq platform with fungi-specific primers targeting the internal transcribed spacer 1 region of the large subunit rRNA gene. A total of 797,040 reads belonging to 1633 operational taxonomic units were observed. Of these, 1102 belonged to Ascomycota, 502 to Basidiomycota, 24 to Zygomycota, and 5 to Chytridiomycota. The dominant orders were Pleosporales (29.39%), Capnodiales (27.96%), Eurotiales (10.64%), and Hypocreales (9.01%). The dominant genera were Cladosporium, Alternaria, Fusarium, Penicillium, Sporisorium, and Aspergilus. Analysis of similarities revealed that both particulate matter sizes (R = 0.175, p = 0.001) and air quality levels (R = 0.076, p = 0.006) significantly affected the airborne fungal community composition. The relative abundance of many fungal genera was found to significantly differ among various PM types and air quality levels. Alternaria and Epicoccum were more abundant in total suspended particles samples, Aspergillus in heavy-haze days and PM2.5 samples, and Malassezia in PM2.5 samples and heavy-haze days. Canonical correspondence analysis and permutation tests showed that temperature (p < 0.01), NO2 (p < 0.01), PM10 (p < 0.01), SO2(p < 0.01), CO (p < 0.01), and relative humidity (p < 0.05) were significant factors that determine airborne fungal community composition. The results suggest that diverse airborne fungal communities are associated with particulate matters and may provide reliable data for studying the responses of human body to the increasing level of air pollution in Beijing. PMID:27148180

  17. A preliminary test method for masonry heater particulate matter and carbon monoxide emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stern, C.H.; Jaasma, D.R.; Shelton, J.W.

    1991-08-01

    A test method for determining carbon monoxide (CO) and particulate matter (PM) emissions from masonry heaters is described and results of tests on two masonry heaters are presented. The method specifies fueling protocol and laboratory measurement procedures for determination of both emission factors (g/kg) and rates (g/hr). The fuel load size and fueling intervals are dependent upon the firebox volume of the masonry heater. The test method starts with a room temperature masonry heater and involves five firings to achieve burn rates in two ranges, where the burn rate is defined as the dry mass of the fuel load dividedmore » by the time between loadings. Emission samples are extracted from a dilution tunnel with a set flow rate and configuration. Particulate matter sampling is similar to US EPA Method 5G for woodstoves, and Co concentration is measured by a nondispersive infrared (NDIR) gas analyzer. The emissions results for each firing are weighted according to EPA Method 28 to obtain the overall emission totals for the test.« less

  18. 40 CFR 52.228 - Regulations: Particulate matter, Southeast Desert Intrastate Region.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Regulations: Particulate matter... § 52.228 Regulations: Particulate matter, Southeast Desert Intrastate Region. (a) The following... particulate matter in the Southeast Desert Intrastate Region. (1) Imperial County Air Pollution Control...

  19. 40 CFR 52.228 - Regulations: Particulate matter, Southeast Desert Intrastate Region.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Regulations: Particulate matter... § 52.228 Regulations: Particulate matter, Southeast Desert Intrastate Region. (a) The following... particulate matter in the Southeast Desert Intrastate Region. (1) Imperial County Air Pollution Control...

  20. Use of constant wavelength synchronous spectrofluorimetry for identification of polycyclic aromatic hydrocarbons in air particulate samples

    NASA Astrophysics Data System (ADS)

    Sharma, Homdutt; Jain, V. K.; Khan, Zahid H.

    2013-05-01

    We have developed a simple, rapid, inexpensive method for the identification of fluoranthene (Flan), benz(a)anthracene (BaA), benzo(a)pyrene (BaP), benzo(k)fluoranthene (BkF), pyrene (Pyr), benz(ghi)perylene (BghiP) in suspended particulate matter in an urban environment of Delhi. Suspended particulate matter samples of 24 h duration were collected on glass fiber filter papers. Polycyclic aromatic hydrocarbons (PAHs) were extracted from the filter papers using dichloromethane (DCM) and hexane with ultrasonication method. Comparison of the characteristic emission of spectra of PAHs with standard spectra indicated the degree of condensation of aromatic compounds present in investigated mixtures. It was also possible to identify some individual compounds. However, this identification could be more effective with the use of the respective values of Δλ parameter for each particular component of the mixture.

  1. 40 CFR 52.776 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Particulate matter...: Particulate matter. Link to an amendment published at 78 FR 28507, May 15, 2013. (a) The requirements of... the secondary standards for particulate matter in the Metropolitan Indianapolis Intrastate Region. (b...

  2. 40 CFR 52.2276 - Control strategy and regulations: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: Particulate matter. 52.2276 Section 52.2276 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY....2276 Control strategy and regulations: Particulate matter. (a) Part D conditional approval. The Texas... of the fabric filters, Parker Brothers and Co., Inc., shall not emit particulate matter in excess of...

  3. 40 CFR 52.1678 - Control strategy and regulations: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: Particulate matter. 52.1678 Section 52.1678 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 52.1678 Control strategy and regulations: Particulate matter. (a)-(c) [Reserved] (d) Section 227.3(a... CFR Subpart G, Control strategy: Sulfur oxides and particulate matter. (e) Determination of Attainment...

  4. Particulate air pollution from bushfires: human exposure and possible health effects.

    PubMed

    Karthikeyan, Sathrugnan; Balasubramanian, Rajasekhar; Iouri, Kostetski

    2006-11-01

    Toxicological studies have implicated trace metals adsorbed onto airborne particles as possible contributors to respiratory and/or cardiovascular inflammation. In particular, the water-soluble metal content is considered to be a harmful component of airborne particulate matter. In this work, the trace metal characteristics of airborne particulate matter, PM2.5, collected in Singapore from February to March 2005 were investigated with specific reference to their bioavailability. PM2.5 mass concentrations varied between 20.9 mug/m3 and 46.3 microg/m3 with an average mass of 32.8 microg/m3. During the sampling period, there were several bushfires in Singapore that contributed to sporadic increases in the particulate air pollution, accompanied by an acrid smell and asthma-related allergies. The aerosol samples were subjected to analysis of trace elements for determining their total concentrations as well as their water soluble fractions. Our results showed an increase in concentration of several water-soluble trace metals during bushfires compared to their urban background levels in Singapore. In order to measure the human exposure to particulate air pollution, the daily respiratory uptake (DRU) of several trace metals was calculated and compared between haze and nonhaze periods. The DRU values were significantly higher for several metals, including Zn, Cu, and Fe, during bushfires. Electron paramagnetic resonance (EPR) measurements showed that the particulate samples collected during bush fires generate more toxic hydroxyl radicals (OH.) than those in the background air, due to the presence of more soluble iron ions.

  5. Particulate-matter content of 11 cephalosporin injections: conformance with USP limits.

    PubMed

    Parkins, D A; Taylor, A J

    1987-05-01

    The particulate-matter content of 11 dry-powder cephalosporin injections was determined using a modified version of the official United States Pharmacopeial Convention (USP) method for particulate matter in small-volume injections (SVIs). Ten vials of each cephalosporin product were each constituted with 10 mL of Water for Injections BP that had been filtered through a 0.22-micron membrane. The pooled contents of the 10 vials for each product were allowed to stand under reduced pressure to ensure removal of gas bubbles. Particulate-matter content was determined using a HIAC/Royco particle counter on six 10-mL samples obtained from the pooled solutions for each product. All solution preparation and particle counting was performed in a horizontal-laminar-airflow hood. Modifications of the USP method used in this study included the use of six rather than two samples from each pooled solution, the addition of diluent to the injections through the rubber closure with a needle instead of into the open container, and changes in the degassing method. Particle counts for all products examined were lower than USP limits for SVIs. All but two products contained less than 15% of USP limits for particles greater than or equal to 10 microns in effective diameter and particles greater than or equal to 25 microns in effective diameter. The standard USP method for degassing (standing for two minutes) was inadequate. Application of reduced pressure for up to 10 minutes was necessary for thorough degassing of products.(ABSTRACT TRUNCATED AT 250 WORDS)

  6. Particulate Matter Filtration Design Considerations for Crewed Spacecraft Life Support Systems

    NASA Technical Reports Server (NTRS)

    Agui, Juan H.; Vijayakumar, R.; Perry, Jay L.

    2016-01-01

    Particulate matter filtration is a key component of crewed spacecraft cabin ventilation and life support system (LSS) architectures. The basic particulate matter filtration functional requirements as they relate to an exploration vehicle LSS architecture are presented. Particulate matter filtration concepts are reviewed and design considerations are discussed. A concept for a particulate matter filtration architecture suitable for exploration missions is presented. The conceptual architecture considers the results from developmental work and incorporates best practice design considerations.

  7. Assessment of Population Exposure to Coarse and Fine Particulate Matter in the Urban Areas of Chennai, India.

    PubMed

    Prasannavenkatesh, Ramachandran; Andimuthu, Ramachandran; Kandasamy, Palanivelu; Rajadurai, Geetha; Kumar, Divya Subash; Radhapriya, Parthasarathy; Ponnusamy, Malini

    2015-01-01

    Research outcomes from the epidemiological studies have found that the course (PM10) and the fine particulate matter (PM2.5) are mainly responsible for various respiratory health effects for humans. The population-weighted exposure assessment is used as a vital decision-making tool to analyze the vulnerable areas where the population is exposed to critical concentrations of pollutants. Systemic sampling was carried out at strategic locations of Chennai to estimate the various concentration levels of particulate pollution during November 2013-January 2014. The concentration of the pollutants was classified based on the World Health Organization interim target (IT) guidelines. Using geospatial information systems the pollution and the high-resolution population data were interpolated to study the extent of the pollutants at the urban scale. The results show that approximately 28% of the population resides in vulnerable locations where the coarse particulate matter exceeds the prescribed standards. Alarmingly, the results of the analysis of fine particulates show that about 94% of the inhabitants live in critical areas where the concentration of the fine particulates exceeds the IT guidelines. Results based on human exposure analysis show the vulnerability is more towards the zones which are surrounded by prominent sources of pollution.

  8. Assessment of Population Exposure to Coarse and Fine Particulate Matter in the Urban Areas of Chennai, India

    PubMed Central

    Prasannavenkatesh, Ramachandran; Andimuthu, Ramachandran; Kandasamy, Palanivelu; Rajadurai, Geetha; Subash Kumar, Divya; Radhapriya, Parthasarathy; Ponnusamy, Malini

    2015-01-01

    Research outcomes from the epidemiological studies have found that the course (PM10) and the fine particulate matter (PM2.5) are mainly responsible for various respiratory health effects for humans. The population-weighted exposure assessment is used as a vital decision-making tool to analyze the vulnerable areas where the population is exposed to critical concentrations of pollutants. Systemic sampling was carried out at strategic locations of Chennai to estimate the various concentration levels of particulate pollution during November 2013–January 2014. The concentration of the pollutants was classified based on the World Health Organization interim target (IT) guidelines. Using geospatial information systems the pollution and the high-resolution population data were interpolated to study the extent of the pollutants at the urban scale. The results show that approximately 28% of the population resides in vulnerable locations where the coarse particulate matter exceeds the prescribed standards. Alarmingly, the results of the analysis of fine particulates show that about 94% of the inhabitants live in critical areas where the concentration of the fine particulates exceeds the IT guidelines. Results based on human exposure analysis show the vulnerability is more towards the zones which are surrounded by prominent sources of pollution. PMID:26258167

  9. 40 CFR 52.1476 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met since the plan does not provide for the attainment and maintenance of the national standards for particulate matter in...

  10. 40 CFR 60.172 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.172... Smelters § 60.172 Standard for particulate matter. (a) On and after the date on which the performance test... contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  11. 40 CFR 52.776 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Particulate matter...: Particulate matter. (a) The requirements of subpart G of this chapter are not met since the plan does not provide for attainment and maintenance of the secondary standards for particulate matter in the...

  12. 40 CFR 52.2584 - Control strategy; Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy; Particulate matter... Control strategy; Particulate matter. (a) Part D—Disapproval—USEPA disapproves Regulation NR 154.11(7)(b... control strategy to attain and maintain the standards for particulate matter, because it does not contain...

  13. 40 CFR 60.532 - Standards for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standards for particulate matter. 60... Wood Heaters § 60.532 Standards for particulate matter. Unless exempted under § 60.530, each affected..., 1992, shall comply with the following particulate matter emission limits as determined by the test...

  14. 40 CFR 60.172 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.172... Smelters § 60.172 Standard for particulate matter. (a) On and after the date on which the performance test... contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  15. 40 CFR 52.2584 - Control strategy; Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy; Particulate matter... Control strategy; Particulate matter. (a) Part D—Disapproval—USEPA disapproves Regulation NR 154.11(7)(b... control strategy to attain and maintain the standards for particulate matter, because it does not contain...

  16. 40 CFR 60.162 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.162... Smelters § 60.162 Standard for particulate matter. (a) On and after the date on which the performance test... particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  17. 75 FR 17894 - Approval and Promulgation of Air Quality Implementation Plans; Wisconsin; Particulate Matter...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-08

    ... Promulgation of Air Quality Implementation Plans; Wisconsin; Particulate Matter Standards AGENCY: Environmental... matter standards in October 2006 by strengthening the 24-hour fine particulate standard and revoking the... standards to match the current Federal standards for particulate matter. DATES: Comments must be received on...

  18. 40 CFR 52.776 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Particulate matter...: Particulate matter. (a) The requirements of subpart G of this chapter are not met since the plan does not provide for attainment and maintenance of the secondary standards for particulate matter in the...

  19. 40 CFR 52.1476 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met since the plan does not provide for the attainment and maintenance of the national standards for particulate matter in...

  20. 40 CFR 60.172 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.172... Smelters § 60.172 Standard for particulate matter. (a) On and after the date on which the performance test... contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  1. 40 CFR 60.162 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.162... Smelters § 60.162 Standard for particulate matter. (a) On and after the date on which the performance test... particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  2. 40 CFR 52.1476 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met since the plan does not provide for the attainment and maintenance of the national standards for particulate matter in...

  3. 40 CFR 60.532 - Standards for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for particulate matter. 60... Wood Heaters § 60.532 Standards for particulate matter. Unless exempted under § 60.530, each affected..., 1992, shall comply with the following particulate matter emission limits as determined by the test...

  4. 40 CFR 52.2584 - Control strategy; Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy; Particulate matter... Control strategy; Particulate matter. (a) Part D—Disapproval—USEPA disapproves Regulation NR 154.11(7)(b... control strategy to attain and maintain the standards for particulate matter, because it does not contain...

  5. 40 CFR 52.2584 - Control strategy; Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy; Particulate matter... Control strategy; Particulate matter. (a) Part D—Disapproval—USEPA disapproves Regulation NR 154.11(7)(b... control strategy to attain and maintain the standards for particulate matter, because it does not contain...

  6. 40 CFR 52.2584 - Control strategy; Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy; Particulate matter... Control strategy; Particulate matter. (a) Part D—Disapproval—USEPA disapproves Regulation NR 154.11(7)(b... control strategy to attain and maintain the standards for particulate matter, because it does not contain...

  7. 40 CFR 60.172 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.172... Smelters § 60.172 Standard for particulate matter. (a) On and after the date on which the performance test... contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  8. 40 CFR 60.162 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.162... Smelters § 60.162 Standard for particulate matter. (a) On and after the date on which the performance test... particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  9. 40 CFR 60.162 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.162... Smelters § 60.162 Standard for particulate matter. (a) On and after the date on which the performance test... particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  10. 40 CFR 60.162 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.162... Smelters § 60.162 Standard for particulate matter. (a) On and after the date on which the performance test... particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  11. 40 CFR 52.2059 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Particulate matter... Control strategy: Particulate matter. (a) [Reserved] (b) EPA approves the PM-10 attainment demonstration...-Wilmington, PA-NJ-DE fine particulate matter (PM2.5) nonattainment area has attained the 2006 24-hour PM2.5...

  12. 40 CFR 60.532 - Standards for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for particulate matter. 60... Wood Heaters § 60.532 Standards for particulate matter. Unless exempted under § 60.530, each affected..., 1992, shall comply with the following particulate matter emission limits as determined by the test...

  13. 40 CFR 60.532 - Standards for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for particulate matter. 60... Wood Heaters § 60.532 Standards for particulate matter. Unless exempted under § 60.530, each affected..., 1992, shall comply with the following particulate matter emission limits as determined by the test...

  14. 40 CFR 60.172 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.172... Smelters § 60.172 Standard for particulate matter. (a) On and after the date on which the performance test... contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). ...

  15. 40 CFR 52.1476 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met since the plan does not provide for the attainment and maintenance of the national standards for particulate matter in...

  16. 40 CFR 60.1325 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... flue gases at the inlet of my particulate matter control device? 60.1325 Section 60.1325 Protection of... the inlet of my particulate matter control device? You must install, calibrate, maintain, and operate... particulate matter control device. ...

  17. 40 CFR 60.1325 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... flue gases at the inlet of my particulate matter control device? 60.1325 Section 60.1325 Protection of... the inlet of my particulate matter control device? You must install, calibrate, maintain, and operate... particulate matter control device. ...

  18. 75 FR 65594 - Approval and Promulgation of Air Quality Implementation Plans; Ohio; Particulate Matter Standards

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-26

    ... Promulgation of Air Quality Implementation Plans; Ohio; Particulate Matter Standards AGENCY: Environmental... in Ohio Administrative Code (OAC) Chapter 3745-17, ``Particulate Matter Standards.'' The revisions were submitted by Ohio EPA to satisfy the State's 5-year review requirements. The particulate matter...

  19. 40 CFR 52.126 - Control strategy and regulations: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: Particulate matter. 52.126 Section 52.126 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... strategy and regulations: Particulate matter. (a) The requirements of subpart G and § 51.281 of this... the national standards for particulate matter in Gila, Maricopa, Pima, Pinal, and Santa Cruz Counties...

  20. 40 CFR 52.227 - Control strategy and regulations: Particulate matter, Metropolitan Los Angeles Intrastate Region.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...: Particulate matter, Metropolitan Los Angeles Intrastate Region. 52.227 Section 52.227 Protection of... IMPLEMENTATION PLANS California § 52.227 Control strategy and regulations: Particulate matter, Metropolitan Los... does not provide for attainment and maintenance of the secondary standards for particulate matter in...

  1. 40 CFR 49.126 - Rule for limiting fugitive particulate matter emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Rule for limiting fugitive particulate matter emissions. (a) What is the purpose of this section? This section limits the amount of fugitive particulate matter that may be emitted from certain air pollution... source of fugitive particulate matter emissions. (c) What is exempted from this section? This section...

  2. 40 CFR 63.1357 - Temporary, conditioned exemption from particulate matter and opacity standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... particulate matter and opacity standards. 63.1357 Section 63.1357 Protection of Environment ENVIRONMENTAL... Cement Manufacturing Industry Other § 63.1357 Temporary, conditioned exemption from particulate matter... methods) is exempt from: (1) Any particulate matter and opacity standards of part 60 or part 63 of this...

  3. 40 CFR 52.227 - Control strategy and regulations: Particulate matter, Metropolitan Los Angeles Intrastate Region.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: Particulate matter, Metropolitan Los Angeles Intrastate Region. 52.227 Section 52.227 Protection of... IMPLEMENTATION PLANS California § 52.227 Control strategy and regulations: Particulate matter, Metropolitan Los... does not provide for attainment and maintenance of the secondary standards for particulate matter in...

  4. Constraints on primary and secondary particulate carbon sources using chemical tracer and 14C methods during CalNex-Bakersfield

    EPA Science Inventory

    The present study investigates primary and secondary sources of organic carbon for Bakersfield, CA, USA as part of the 2010 CalNex study. The method used here involves integrated sampling that is designed to allow for detailed and specific chemical analysis of particulate matter ...

  5. Tire tread wear particles in ambient air--a previously unknown source of human exposure to the biocide 2-mercaptobenzothiazole.

    PubMed

    Avagyan, Rozanna; Sadiktsis, Ioannis; Bergvall, Christoffer; Westerholm, Roger

    2014-10-01

    Urban particulate matter (PM), asphalt, and tire samples were investigated for their content of benzothiazole and benzothiazole derivates. The purpose of this study was to examine whether wear particles, i.e., tire tread wear or road surface wear, could contribute to atmospheric concentrations of benzothiazole derivatives. Airborne particulate matter (PM10) sampled at a busy street in Stockholm, Sweden, contained on average 17 pg/m(3) benzothiazole and 64 pg/m(3) 2-mercaptobenzothiazole, and the total suspended particulate-associated benzothiazole and 2-mercaptobenzothiazole concentrations were 199 and 591 pg/m(3), respectively. This indicates that tire tread wear may be a major source of these benzothiazoles to urban air PM in Stockholm. Furthermore, 2-mercaptobenzothiazole was determined in urban air particulates for the first time in this study, and its presence in inhalable PM10 implies that the human exposure to this biocide is underestimated. This calls for a revision of the risk assessments of 2-mercaptobenzothiazole exposure to humans which currently is limited to occupational exposure.

  6. EMAT enhanced dispersion of particles in liquid

    DOEpatents

    Kisner, Roger A.; Rios, Orlando; Melin, Alexander M.; Ludtka, Gerard Michael; Ludtka, Gail Mackiewicz; Wilgen, John B.

    2016-11-29

    Particulate matter is dispersed in a fluid material. A sample including a first material in a fluid state and second material comprising particulate matter are placed into a chamber. The second material is spatially dispersed in the first material utilizing EMAT force. The dispersion process continues until spatial distribution of the second material enables the sample to meet a specified criterion. The chamber and/or the sample is electrically conductive. The EMAT force is generated by placing the chamber coaxially within an induction coil driven by an applied alternating current and placing the chamber and induction coil coaxially within a high field magnetic. The EMAT force is coupled to the sample without physical contact to the sample or to the chamber, by another physical object. Batch and continuous processing are utilized. The chamber may be folded within the bore of the magnet. Acoustic force frequency and/or temperature may be controlled.

  7. Woodstove smoke and CO emissions: comparison of reference methods with the VIP sampler.

    PubMed

    Jaasma, D R; Champion, M C; Shelton, J W

    1990-06-01

    A new field sampler has been developed for measuring the particulate matter (PM) and carbon monoxide emissions of woodburning stoves. Particulate matter is determined by carbon balance and the workup of a sample train which is similar to a room-temperature EPA Method 5G train. A steel tank, initially evacuated, serves as the motive force for sampling and also accumulates a gas sample for post-test analysis of time-averaged stack CO and CO2 concentrations. Workup procedures can be completed within 72 hours of sampler retrieval. The system has been compared to reference methods in two laboratory test series involving six different woodburning appliances and two independent laboratories. The correlation of field sampler emission rates and reference method rates is strong.

  8. Woodstove smoke and CO emissions: Comparison of reference methods with the VIP sampler

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jaasma, D.R.; Champion, M.C.; Shelton, J.W.

    1990-06-01

    A new field sampler has been developed for measuring the particulate matter (PM) and carbon monoxide emissions of woodburning stoves. Particulate matter is determined by carbon balance and the workup of a sample train which is similar to a room-temperature EPA Method 5G train. A steel tank, initially evacuated, serves as the motive force for sampling and also accumulates a gas sample for post-test analysis of time-averaged stack CO and CO{sub 2} concentrations. Workup procedures can be completed within 72 hours of sampler retrieval. The system has been compared to reference methods in two laboratory test series involving six differentmore » woodburning appliances and two independent laboratories. The correlation of field sampler emission rates and reference method rates is strong.« less

  9. Chemical Characterization of Outdoor and Subway Fine (PM2.5–1.0) and Coarse (PM10–2.5) Particulate Matter in Seoul (Korea) by Computer-Controlled Scanning Electron Microscopy (CCSEM)

    PubMed Central

    Byeon, Sang-Hoon; Willis, Robert; Peters, Thomas M.

    2015-01-01

    Outdoor and indoor (subway) samples were collected by passive sampling in urban Seoul (Korea) and analyzed with computer-controlled scanning electron microscopy coupled with energy dispersive x-ray spectroscopy (CCSEM-EDX). Soil/road dust particles accounted for 42%–60% (by weight) of fine particulate matter larger than 1 µm (PM2.5–1.0) in outdoor samples and 18% of PM2.5–1.0 in subway samples. Iron-containing particles accounted for only 3%–6% in outdoor samples but 69% in subway samples. Qualitatively similar results were found for coarse particulate matter (PM10–2.5) with soil/road dust particles dominating outdoor samples (66%–83%) and iron-containing particles contributing most to subway PM10–2.5 (44%). As expected, soil/road dust particles comprised a greater mass fraction of PM10–2.5 than PM2.5–1.0. Also as expected, the mass fraction of iron-containing particles was substantially less in PM10–2.5 than in PM2.5–1.0. Results of this study are consistent with known emission sources in the area and with previous studies, which showed high concentrations of iron-containing particles in the subway compared to outdoor sites. Thus, passive sampling with CCSEM-EDX offers an inexpensive means to assess PM2.5–1.0 and PM10-2.5 simultaneously and by composition at multiple locations. PMID:25689348

  10. Basics of Sterile Compounding: Particulate Matter.

    PubMed

    Akers, Michael J

    2017-01-01

    This article focuses on the requirements for particulate matter in sterile products. Topics include particles and quality, particulate matter standards (large- and small-volume injectables), development of the small-volume injectable test, electronic (light obscuration) and microscope testing, and special requirements for particulate matter in biopharmaceutical preparations. Copyright© by International Journal of Pharmaceutical Compounding, Inc.

  11. 40 CFR 60.732 - Standards for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for particulate matter. 60... Dryers in Mineral Industries § 60.732 Standards for particulate matter. Each owner or operator of any... particulate matter in excess of 0.092 gram per dry standard cubic meter (g/dscm) [0.040 grain per dry standard...

  12. 40 CFR 60.182 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.182... Smelters § 60.182 Standard for particulate matter. (a) On and after the date on which the performance test... furnace, or sintering machine discharge end any gases which contain particulate matter in excess of 50 mg...

  13. 40 CFR 60.132 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.132... and Bronze Production Plants § 60.132 Standard for particulate matter. (a) On and after the date on... reverberatory furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf...

  14. 40 CFR 60.262 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.262... Production Facilities § 60.262 Standard for particulate matter. (a) On and after the date on which the... furnace any gases which: (1) Exit from a control device and contain particulate matter in excess of 0.45...

  15. 40 CFR 60.342 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.342... Manufacturing Plants § 60.342 Standard for particulate matter. (a) On and after the date on which the... gases which: (1) Contain particulate matter in excess of 0.30 kilogram per megagram (0.60 lb/ton) of...

  16. 40 CFR 60.292 - Standards for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standards for particulate matter. 60... Manufacturing Plants § 60.292 Standards for particulate matter. (a) On and after the date on which the..., particulate matter at emission rates exceeding those specified in table CC-1, Column 2 and Column 3...

  17. 40 CFR 60.732 - Standards for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standards for particulate matter. 60... Dryers in Mineral Industries § 60.732 Standards for particulate matter. Each owner or operator of any... particulate matter in excess of 0.092 gram per dry standard cubic meter (g/dscm) [0.040 grain per dry standard...

  18. 40 CFR 60.132 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.132... and Bronze Production Plants § 60.132 Standard for particulate matter. (a) On and after the date on... reverberatory furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf...

  19. 40 CFR 60.472 - Standards for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for particulate matter. 60... Processing and Asphalt Roofing Manufacture § 60.472 Standards for particulate matter. (a) On and after the...) Particulate matter in excess of: (i) 0.04 kg/Mg (0.08 lb/ton) of asphalt shingle or mineral-surfaced roll...

  20. 40 CFR 60.262 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.262... Production Facilities § 60.262 Standard for particulate matter. (a) On and after the date on which the... furnace any gases which: (1) Exit from a control device and contain particulate matter in excess of 0.45...

  1. 40 CFR 60.52 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.52... § 60.52 Standard for particulate matter. (a) On and after the date on which the initial performance... atmosphere from any affected facility any gases which contain particulate matter in excess of 0.18 g/dscm (0...

  2. 40 CFR 60.182 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.182... Smelters § 60.182 Standard for particulate matter. (a) On and after the date on which the performance test... furnace, or sintering machine discharge end any gases which contain particulate matter in excess of 50 mg...

  3. 40 CFR 60.292 - Standards for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for particulate matter. 60... Manufacturing Plants § 60.292 Standards for particulate matter. (a) On and after the date on which the..., particulate matter at emission rates exceeding those specified in table CC-1, Column 2 and Column 3...

  4. 40 CFR 60.382 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.382... Processing Plants § 60.382 Standard for particulate matter. (a) On and after the date on which the... stack emissions that: (1) Contain particulate matter in excess of 0.05 grams per dry standard cubic...

  5. 40 CFR 60.302 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.302... § 60.302 Standard for particulate matter. (a) On and after the 60th day of achieving the maximum... a grain dryer any process emission which: (1) Contains particulate matter in excess of 0.023 g/dscm...

  6. 40 CFR 60.732 - Standards for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for particulate matter. 60... Dryers in Mineral Industries § 60.732 Standards for particulate matter. Each owner or operator of any... particulate matter in excess of 0.092 gram per dry standard cubic meter (g/dscm) [0.040 grain per dry standard...

  7. 40 CFR 60.52 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.52... § 60.52 Standard for particulate matter. (a) On and after the date on which the initial performance... atmosphere from any affected facility any gases which contain particulate matter in excess of 0.18 g/dscm (0...

  8. 40 CFR 52.427 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Particulate matter...: Particulate matter. (a) Determination of attainment. EPA has determined, as of May 16, 2012, that based on... fine particulate matter (PM2.5) nonattainment area has attained the 2006 24-hour PM2.5 national ambient...

  9. 40 CFR 60.302 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.302... § 60.302 Standard for particulate matter. (a) On and after the 60th day of achieving the maximum... a grain dryer any process emission which: (1) Contains particulate matter in excess of 0.023 g/dscm...

  10. 40 CFR 60.342 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.342... Manufacturing Plants § 60.342 Standard for particulate matter. (a) On and after the date on which the... gases which: (1) Contain particulate matter in excess of 0.30 kilogram per megagram (0.60 lb/ton) of...

  11. 40 CFR 60.382 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.382... Processing Plants § 60.382 Standard for particulate matter. (a) On and after the date on which the... stack emissions that: (1) Contain particulate matter in excess of 0.05 grams per dry standard cubic...

  12. 40 CFR 60.132 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.132... and Bronze Production Plants § 60.132 Standard for particulate matter. (a) On and after the date on... reverberatory furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf...

  13. 40 CFR 60.472 - Standards for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for particulate matter. 60... Processing and Asphalt Roofing Manufacture § 60.472 Standards for particulate matter. (a) On and after the...) Particulate matter in excess of: (i) 0.04 kg/Mg (0.08 lb/ton) of asphalt shingle or mineral-surfaced roll...

  14. 40 CFR 60.292 - Standards for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for particulate matter. 60... Manufacturing Plants § 60.292 Standards for particulate matter. (a) On and after the date on which the..., particulate matter at emission rates exceeding those specified in table CC-1, Column 2 and Column 3...

  15. 40 CFR 60.302 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.302... § 60.302 Standard for particulate matter. (a) On and after the 60th day of achieving the maximum... a grain dryer any process emission which: (1) Contains particulate matter in excess of 0.023 g/dscm...

  16. 40 CFR 60.52 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.52... § 60.52 Standard for particulate matter. (a) On and after the date on which the initial performance... atmosphere from any affected facility any gases which contain particulate matter in excess of 0.18 g/dscm (0...

  17. 40 CFR 60.382 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.382... Processing Plants § 60.382 Standard for particulate matter. (a) On and after the date on which the... stack emissions that: (1) Contain particulate matter in excess of 0.05 grams per dry standard cubic...

  18. 40 CFR 52.427 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Particulate matter...: Particulate matter. (a) Determination of attainment. EPA has determined, as of May 16, 2012, that based on... fine particulate matter (PM2.5) nonattainment area has attained the 2006 24-hour PM2.5 national ambient...

  19. 40 CFR 60.472 - Standards for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for particulate matter. 60... Processing and Asphalt Roofing Manufacture § 60.472 Standards for particulate matter. (a) On and after the...) Particulate matter in excess of: (i) 0.04 kg/Mg (0.08 lb/ton) of asphalt shingle or mineral-surfaced roll...

  20. 40 CFR 60.182 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.182... Smelters § 60.182 Standard for particulate matter. (a) On and after the date on which the performance test... furnace, or sintering machine discharge end any gases which contain particulate matter in excess of 50 mg...

  1. 40 CFR 60.302 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.302... § 60.302 Standard for particulate matter. (a) On and after the 60th day of achieving the maximum... a grain dryer any process emission which: (1) Contains particulate matter in excess of 0.023 g/dscm...

  2. 40 CFR 60.52 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.52... § 60.52 Standard for particulate matter. (a) On and after the date on which the initial performance... atmosphere from any affected facility any gases which contain particulate matter in excess of 0.18 g/dscm (0...

  3. 40 CFR 60.52 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.52... § 60.52 Standard for particulate matter. (a) On and after the date on which the initial performance... atmosphere from any affected facility any gases which contain particulate matter in excess of 0.18 g/dscm (0...

  4. 40 CFR 60.132 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.132... and Bronze Production Plants § 60.132 Standard for particulate matter. (a) On and after the date on... reverberatory furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf...

  5. 40 CFR 60.262 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.262... Production Facilities § 60.262 Standard for particulate matter. (a) On and after the date on which the... furnace any gases which: (1) Exit from a control device and contain particulate matter in excess of 0.45...

  6. 40 CFR 60.732 - Standards for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for particulate matter. 60... Dryers in Mineral Industries § 60.732 Standards for particulate matter. Each owner or operator of any... particulate matter in excess of 0.092 gram per dry standard cubic meter (g/dscm) [0.040 grain per dry standard...

  7. 40 CFR 60.182 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.182... Smelters § 60.182 Standard for particulate matter. (a) On and after the date on which the performance test... furnace, or sintering machine discharge end any gases which contain particulate matter in excess of 50 mg...

  8. 40 CFR 60.132 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.132... and Bronze Production Plants § 60.132 Standard for particulate matter. (a) On and after the date on... reverberatory furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf...

  9. 40 CFR 60.292 - Standards for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for particulate matter. 60... Manufacturing Plants § 60.292 Standards for particulate matter. (a) On and after the date on which the..., particulate matter at emission rates exceeding those specified in table CC-1, Column 2 and Column 3...

  10. 75 FR 4063 - Adequacy Status of the Cleveland/Akron, Ohio Submitted Annual Fine Particulate Matter Attainment...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-01-26

    ... Cleveland/Akron, Ohio Submitted Annual Fine Particulate Matter Attainment Demonstration for Transportation... (MVEBs) for fine particulate matter (PM 2.5 ) and oxides of nitrogen (NO X ) as a precursor to fine particulate matter in the Cleveland/Akron, Ohio area are adequate for use in transportation conformity...

  11. 40 CFR 60.292 - Standards for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standards for particulate matter. 60... Manufacturing Plants § 60.292 Standards for particulate matter. (a) On and after the date on which the..., particulate matter at emission rates exceeding those specified in table CC-1, Column 2 and Column 3...

  12. 40 CFR 60.342 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.342... Manufacturing Plants § 60.342 Standard for particulate matter. (a) On and after the date on which the... gases which: (1) Contain particulate matter in excess of 0.30 kilogram per megagram (0.60 lb/ton) of...

  13. 40 CFR 60.302 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.302... § 60.302 Standard for particulate matter. (a) On and after the 60th day of achieving the maximum... a grain dryer any process emission which: (1) Contains particulate matter in excess of 0.023 g/dscm...

  14. 40 CFR 60.182 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.182... Smelters § 60.182 Standard for particulate matter. (a) On and after the date on which the performance test... furnace, or sintering machine discharge end any gases which contain particulate matter in excess of 50 mg...

  15. 40 CFR 60.472 - Standards for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standards for particulate matter. 60... Processing and Asphalt Roofing Manufacture § 60.472 Standards for particulate matter. (a) On and after the...) Particulate matter in excess of: (i) 0.04 kg/Mg (0.08 lb/ton) of asphalt shingle or mineral-surfaced roll...

  16. 40 CFR 60.262 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.262... Production Facilities § 60.262 Standard for particulate matter. (a) On and after the date on which the... furnace any gases which: (1) Exit from a control device and contain particulate matter in excess of 0.45...

  17. 40 CFR 60.382 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.382... Processing Plants § 60.382 Standard for particulate matter. (a) On and after the date on which the... stack emissions that: (1) Contain particulate matter in excess of 0.05 grams per dry standard cubic...

  18. Urban tree effects on fine particulate matter and human health

    Treesearch

    David J. Nowak

    2014-01-01

    Overall, city trees reduce particulate matter and provide substantial health benefits; but under certain conditions, they can locally increase particulate matter concentrations. Urban foresters need to understand how trees affect particulate matter so they can select proper species and create appropriate designs to improve air quality. This article details trees'...

  19. Investigating the composition characteristics of dissolved and particulate/colloidal organic matter in effluent-dominated stream using fluorescence spectroscopy combined with multivariable analysis.

    PubMed

    Yu, Min-Da; He, Xiao-Song; Xi, Bei-Dou; Gao, Ru-Tai; Zhao, Xian-Wei; Zhang, Hui; Huang, Cai-Hong; Tan, Wenbing

    2018-03-01

    Fluorescence excitation-emission matrix (EEM) spectroscopy combined with principal component analysis (PCA) and parallel factor analysis (PARAFAC) were used to investigate the compositional characteristics of dissolved and particulate/colloidal organic matter and its correlations with nitrogen, phosphorus, and heavy metals in an effluent-dominated stream, Northern China. The results showed that dissolved organic matter (DOM) was comprised of fulvic-like, humic-like, and protein-like components in the water samples, and fulvic-like substances were the main fraction of DOM among them. Particulate/colloidal organic matter (PcOM) consisted of fulvic-like and protein-like matter. Fulvic-like substances existed in the larger molecular form in PcOM, and they comprised a large amount of nitrogen and polar functional groups. On the other hand, protein-like components in PcOM were low in benzene ring and bound to heavy metals. It could be concluded that nitrogen, phosphorus, and heavy metals in effluent had an effect on the compositional characteristics of natural DOM and PcOM, which may deepen our understanding about the environmental behaviors of organic matter in effluent.

  20. Speciation of antimony in airborne particulate matter using ultrasound probe fast extraction and analysis by HPLC-HG-AFS.

    PubMed

    Bellido-Martín, A; Gómez-Ariza, J L; Smichowsky, P; Sánchez-Rodas, D

    2009-09-07

    A fast extraction procedure has been developed for Sb(III) and Sb(V) oxoanions speciation in airborne particulate matter samples. Different extraction media (diammonium tartrate, hidroxilammonium clorhidrate, citric acid+ascorbic acid, phosphoric acid and citrate solutions) were tried, with assistance of an ultrasonic probe. The operation power and time of extraction were also optimized. The higher extraction recoveries were obtained with a 100 mmol L(-1) hidroxilammonium clorhidrate aqueous solution assisted by the ultrasound probe operated at 50 W during 3 min. The extracts were analyzed by HPLC-HG-AFS. The chromatographic separation of Sb(III) and Sb(V) was also optimized using diammonium tartrate and phthalic acid as mobile phases. The separation of both Sb species was performed in less than 3 min under isocratic conditions, using a 200 mmol L(-1) diammonium tartrate solution. The proposed extraction procedure and the HPLC-HG-AFS instrumental coupling have been successfully applied to airborne particulate matter samples, with high Sb content, collected in heavy traffic streets from Buenos Aires (Argentina). The results showed the presence of both Sb species at similar concentrations in the ng m(-3) level. The extraction yield was higher than 90% for all the analyzed samples.

  1. Assessment of Contribution of Contemporary Carbon Sources to Size-Fractionated Particulate Matter and Time-Resolved Bulk Particulate Matter Using the Measurement of Radiocarbon

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hwang, H M; Young, T M; Buchholz, B A

    2009-04-16

    This study was motivated by a desire to improve understanding of the sources contributing to the carbon that is an important component of airborne particulate matter (PM). The ultimate goal of this project was to lay a ground work for future tools that might be easily implemented with archived or routinely collected samples. A key feature of this study was application of radiocarbon measurement that can be interpreted to indicate the relative contributions from fossil and non-fossil carbon sources of atmospheric PM. Size-resolved PM and time-resolved PM{sub 10} collected from a site in Sacramento, CA in November 2007 (Phase I)more » and March 2008 (Phase II) were analyzed for radiocarbon and source markers such as levoglucosan, cholesterol, and elemental carbon. Radiocarbon data indicates that the contributions of non-fossil carbon sources were much greater than that from fossil carbon sources in all samples. Radiocarbon and source marker measurements confirm that a greater contribution of non-fossil carbon sources in Phase I samples was highly likely due to residential wood combustion. The present study proves that measurement of radiocarbon and source markers can be readily applied to archived or routinely collected samples for better characterization of PM sources. More accurate source apportionment will support ARB in developing more efficient control strategies.« less

  2. Occurrence and abundance of carbohydrates and amino compounds in sequentially extracted labile soil organic matter fractions.

    USDA-ARS?s Scientific Manuscript database

    This study aimed to investigate the content of carbohydrates and amino compounds in three labile fraction of soil organic matter (SOM). Soil samples were collected from two agricultural fields in southern Italy and the light fraction (LF), the 500–53-µm particulate organic matter (POM) and the mobil...

  3. 40 CFR 60.682 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.682... Insulation Manufacturing Plants § 60.682 Standard for particulate matter. On and after the date on which the... gases which contain particulate matter in excess of 5.5 kg/Mg (11.0 1b/ton) of glass pulled. ...

  4. 40 CFR 60.142a - Standards for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standards for particulate matter. 60... 20, 1983 § 60.142a Standards for particulate matter. (a) Except as provided under paragraphs (b) and...-blown BOPF and contain particulate matter in excess of 23 mg/dscm (0.010 gr/dscf). (3) Exit from a...

  5. 40 CFR 60.142a - Standards for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standards for particulate matter. 60... 20, 1983 § 60.142a Standards for particulate matter. (a) Except as provided under paragraphs (b) and...-blown BOPF and contain particulate matter in excess of 23 mg/dscm (0.010 gr/dscf). (3) Exit from a...

  6. 40 CFR 60.682 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.682... Insulation Manufacturing Plants § 60.682 Standard for particulate matter. On and after the date on which the... gases which contain particulate matter in excess of 5.5 kg/Mg (11.0 1b/ton) of glass pulled. ...

  7. 40 CFR 60.122 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.122... Smelters § 60.122 Standard for particulate matter. (a) On and after the date on which the performance test... furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). (2...

  8. 40 CFR 60.92 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.92... Facilities § 60.92 Standard for particulate matter. (a) On and after the date on which the performance test... which: (1) Contain particulate matter in excess of 90 mg/dscm (0.04 gr/dscf). (2) Exhibit 20 percent...

  9. 40 CFR 60.272a - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60... Standard for particulate matter. (a) On and after the date of which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf); (2) Exit from a...

  10. 40 CFR 60.92 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.92... Facilities § 60.92 Standard for particulate matter. (a) On and after the date on which the performance test... which: (1) Contain particulate matter in excess of 90 mg/dscm (0.04 gr/dscf). (2) Exhibit 20 percent...

  11. 40 CFR 60.122 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.122... Smelters § 60.122 Standard for particulate matter. (a) On and after the date on which the performance test... furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). (2...

  12. 40 CFR 60.682 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.682... Insulation Manufacturing Plants § 60.682 Standard for particulate matter. On and after the date on which the... gases which contain particulate matter in excess of 5.5 kg/Mg (11.0 1b/ton) of glass pulled. ...

  13. 40 CFR 60.272a - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60... Standard for particulate matter. (a) On and after the date of which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf); (2) Exit from a...

  14. 40 CFR 60.682 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.682... Insulation Manufacturing Plants § 60.682 Standard for particulate matter. On and after the date on which the... gases which contain particulate matter in excess of 5.5 kg/Mg (11.0 1b/ton) of glass pulled. ...

  15. 40 CFR 60.272 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.272... Standard for particulate matter. (a) On and after the date on which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf). (2) Exit from a...

  16. 40 CFR 60.92 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.92... Facilities § 60.92 Standard for particulate matter. (a) On and after the date on which the performance test... which: (1) Contain particulate matter in excess of 90 mg/dscm (0.04 gr/dscf). (2) Exhibit 20 percent...

  17. 40 CFR 60.122 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.122... Smelters § 60.122 Standard for particulate matter. (a) On and after the date on which the performance test... furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). (2...

  18. 40 CFR 60.152 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.152... Plants § 60.152 Standard for particulate matter. (a) On and after the date on which the performance test...: (1) Particulate matter at a rate in excess of 0.65 g/kg dry sludge input (1.30 lb/ton dry sludge...

  19. 40 CFR 60.142a - Standards for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for particulate matter. 60... 20, 1983 § 60.142a Standards for particulate matter. (a) Except as provided under paragraphs (b) and...-blown BOPF and contain particulate matter in excess of 23 mg/dscm (0.010 gr/dscf). (3) Exit from a...

  20. 40 CFR 60.152 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.152... Plants § 60.152 Standard for particulate matter. (a) On and after the date on which the performance test...: (1) Particulate matter at a rate in excess of 0.65 g/kg dry sludge input (1.30 lb/ton dry sludge...

  1. 40 CFR 60.92 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.92... Facilities § 60.92 Standard for particulate matter. (a) On and after the date on which the performance test... which: (1) Contain particulate matter in excess of 90 mg/dscm (0.04 gr/dscf). (2) Exhibit 20 percent...

  2. 40 CFR 60.272a - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60... Standard for particulate matter. (a) On and after the date of which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf); (2) Exit from a...

  3. 40 CFR 60.122 - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60.122... Smelters § 60.122 Standard for particulate matter. (a) On and after the date on which the performance test... furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). (2...

  4. 40 CFR 60.122 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.122... Smelters § 60.122 Standard for particulate matter. (a) On and after the date on which the performance test... furnace any gases which: (1) Contain particulate matter in excess of 50 mg/dscm (0.022 gr/dscf). (2...

  5. 40 CFR 60.142a - Standards for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standards for particulate matter. 60... 20, 1983 § 60.142a Standards for particulate matter. (a) Except as provided under paragraphs (b) and...-blown BOPF and contain particulate matter in excess of 23 mg/dscm (0.010 gr/dscf). (3) Exit from a...

  6. 40 CFR 60.272 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.272... Standard for particulate matter. (a) On and after the date on which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf). (2) Exit from a...

  7. 40 CFR 60.152 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.152... Plants § 60.152 Standard for particulate matter. (a) On and after the date on which the performance test...: (1) Particulate matter at a rate in excess of 0.65 g/kg dry sludge input (1.30 lb/ton dry sludge...

  8. 40 CFR 60.272a - Standard for particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for particulate matter. 60... Standard for particulate matter. (a) On and after the date of which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf); (2) Exit from a...

  9. 40 CFR 60.92 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.92... Facilities § 60.92 Standard for particulate matter. (a) On and after the date on which the performance test... which: (1) Contain particulate matter in excess of 90 mg/dscm (0.04 gr/dscf). (2) Exhibit 20 percent...

  10. 40 CFR 60.152 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.152... Plants § 60.152 Standard for particulate matter. (a) On and after the date on which the performance test...: (1) Particulate matter at a rate in excess of 0.65 g/kg dry sludge input (1.30 lb/ton dry sludge...

  11. 40 CFR 60.682 - Standard for particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Standard for particulate matter. 60.682... Insulation Manufacturing Plants § 60.682 Standard for particulate matter. On and after the date on which the... gases which contain particulate matter in excess of 5.5 kg/Mg (11.0 1b/ton) of glass pulled. ...

  12. 40 CFR 60.142a - Standards for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standards for particulate matter. 60... 20, 1983 § 60.142a Standards for particulate matter. (a) Except as provided under paragraphs (b) and...-blown BOPF and contain particulate matter in excess of 23 mg/dscm (0.010 gr/dscf). (3) Exit from a...

  13. 40 CFR 60.272 - Standard for particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Standard for particulate matter. 60.272... Standard for particulate matter. (a) On and after the date on which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf). (2) Exit from a...

  14. 40 CFR 60.152 - Standard for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 7 2012-07-01 2012-07-01 false Standard for particulate matter. 60.152... Plants § 60.152 Standard for particulate matter. (a) On and after the date on which the performance test...: (1) Particulate matter at a rate in excess of 0.65 g/kg dry sludge input (1.30 lb/ton dry sludge...

  15. 40 CFR Table 2 to Subpart Ddddd of... - Operating Limits for Boilers and Process Heaters With Particulate Matter Emission Limits

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Process Heaters With Particulate Matter Emission Limits 2 Table 2 to Subpart DDDDD of Part 63 Protection... Heaters With Particulate Matter Emission Limits As stated in § 63.7500, you must comply with the applicable operating limits: If you demonstrate compliance with applicable particulate matter emission limits...

  16. 40 CFR Table 2 to Subpart Ddddd of... - Operating Limits for Boilers and Process Heaters With Particulate Matter Emission Limits

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Process Heaters With Particulate Matter Emission Limits 2 Table 2 to Subpart DDDDD of Part 63 Protection... Heaters With Particulate Matter Emission Limits As stated in § 63.7500, you must comply with the applicable operating limits: If you demonstrate compliance with applicable particulate matter emission limits...

  17. 40 CFR 60.272a - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60... Standard for particulate matter. (a) On and after the date of which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf); (2) Exit from a...

  18. 40 CFR 60.272 - Standard for particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter. 60.272... Standard for particulate matter. (a) On and after the date on which the performance test required to be... control device and contain particulate matter in excess of 12 mg/dscm (0.0052 gr/dscf). (2) Exit from a...

  19. Composition of particulate organic matter sampled in the troposphere over Siberia

    NASA Astrophysics Data System (ADS)

    Belan, Boris D.; Voronetskaya, Natalya G.; Pevneva, Galina S.; Golovko, Anatoly K.; Kozlov, Alexander S.; Simonenkov, Denis V.; Tolmachev, Gennadii N.

    2015-04-01

    In this paper we present some results of the analysis of organic compounds contained in the particulate matter sampled in the Siberian air shed during monthly research flights in 2012-2013. Aerosol sampling was performed in the tropospheric layer from 500 to 7000 m over the Karakan pine forest located on the east bank of the Novosibirsk Reservoir (River Ob). The Optik TU-134 aircraft laboratory was used as a research platform for in-situ measurements of atmospheric trace gas species and aerosols, as well as a particulate matter collection on PTFE filters. Analysis of the particulate organic matter sampled in the Siberian air shed in 2012-2013 allowed us to draw the following conclusions: the total content of n-alkanes increases in the spring and decreases in the winter. the length of the n-alkane homologous series had no seasonal dependence. maximum in the molecular weight distribution of n-alkanes varies depending on the season; compounds with C17, C22 and C25 chains dominated in winter and spring 2012, whereas in summer - C17 ones; in 2013 compounds with C17 chains dominated in winter, C18-C20 - in spring, and C21 and C23 - in summer. Carbon preference index (CPI) value for a given chain length of the homologous series (on the average from C12 to C28) did not reflect the contribution of sources of n-alkanes in the atmosphere. This work was supported by Interdisciplinary integration projects of the Siberian Branch of the Russian Academy of Science No. 35, No. 70 and No. 131; the Branch of Geology, Geophysics and Mining Sciences of RAS (Program No. 5); State contracts of the Ministry of Education and Science of Russia No. 14.604.21.0100, (RFMTFIBBB210290) and No. 14.613.21.0013 (RFMEFI61314X0013); and Russian Foundation for Basic Research (grants No. 14-05-00526 and 14-05-00590).

  20. 30 CFR 57.5067 - Engines.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5067 Engines. (a... (2) Meet or exceed the applicable particulate matter emission requirements of the Environmental...

  1. Measurement and modeling of diameter distributions of particulate matter in terrestrial solutions

    NASA Astrophysics Data System (ADS)

    Levia, Delphis F.; Michalzik, Beate; Bischoff, Sebastian; NäThe, Kerstin; Legates, David R.; Gruselle, Marie-Cecile; Richter, Susanne

    2013-04-01

    Particulate matter (PM) plays an important role in biogeosciences, affecting biosphere-atmosphere interactions and ecosystem health. This is the first known study to quantify and model PM diameter distributions of bulk precipitation, throughfall, stemflow, and organic layer (Oa) solution. Solutions were collected from a European beech (Fagus sylvatica L.) forest during leafed and leafless periods. Following scanning electron microscopy and image analysis, PM distributions were quantified and then modeled with the Box-Cox transformation. Based on an analysis of 43,278 individual particulates, median PM diameter of all solutions was around 3.0 µm. All PM diameter frequency distributions were skewed significantly to the right. Optimal power transformations of PM diameter distributions were between -1.00 and -1.56. The utility of this model reconstruction would be that large samples having a similar probability density function can be developed for similar forests. Further work on the shape and chemical composition of particulates is warranted.

  2. Riverine and wet atmospheric inputs of materials to a North Africa coastal site (Annaba Bay, Algeria)

    NASA Astrophysics Data System (ADS)

    Ounissi, Makhlouf; Amira, Aicha Beya; Dulac, François

    2018-07-01

    This study simultaneously assesses for the first time the relative contributions of riverine and wet atmospheric inputs of materials into the Algerian Annaba Bay on the Mediterranean coast of North Africa. Surface water sampling and water discharge estimates were performed weekly in 2014 at the outlets of the Mafragh River (MR) and Seybouse River (SR). Riverine samples were analyzed for dissolved nutrients and particulate matter (suspended particulate matter: SPM; particulate organic carbon: POC; biogenic silica: BSi; chlorophyll a: Chl a; particulate organic nitrogen: PON and particulate organic phosphorus (POP). Rainwater samples were jointly collected at a close weather station on a daily basis and analyzed for dissolved nutrients. The rainwater from the Annaba region was characterized by high concentrations of phosphate (PO4) and silicic acid (Si(OH)4) that are several times the average Mediterranean values, and by strong deposition fluxes. Conversely, the levels of dissolved inorganic nitrogen (DIN) and dissolved organic nitrogen (DON) and associated fluxes were remarkably low. The dissolved nutrient fluxes for the two catchments were low following the lowering of the river flows, but those of particulate matter (POC, Chl a, BSi) displayed significant amounts, especially for the MR catchment. BSi and POP represented approximately a third of the total silicon and total phosphorus fluxes, respectively. The levels of dissolved N and P in the MR water were comparable to those in rainwater. MR appeared to be a nearly pristine ecosystem with low nutrient levels and almost balanced N:P and Si:N ratios. SR water had low Si(OH)4 levels but was highly charged with NH4 and PO4 and showed unbalanced N:P and Si:N ratios in almost all samples. These conditions have resulted in large phytoplankton biomasses, which may lead to eutrophication. More importantly, the rainwater was identified as a relevant source of fertilizers for marine waters and agricultural land in the Annaba area and can partially balance the loss of Si(OH)4 from rivers to the bay due to dam retention.

  3. Radioactively-hot particles detected in dusts and soils from Northern Japan by combination of gamma spectrometry, autoradiography, and SEM/EDS analysis and implications in radiation risk assessment.

    PubMed

    Kaltofen, Marco; Gundersen, Arnie

    2017-12-31

    After the March 11, 2011, nuclear reactor meltdowns at Fukushima Dai-ichi, 180 samples of Japanese particulate matter (dusts and surface soils) and 235 similar U.S. and Canadian samples were collected and analyzed sequentially by gamma spectrometry, autoradiography, and scanning electron microscopy with energy dispersive X-ray analysis. Samples were collected and analyzed over a five-year period, from 2011 to 2016. Detectable levels of 134 Cs and 137 Cs were found in 142 of 180 (80%) Japanese particulate matter samples. The median radio-cesium specific activity of Japanese particulate samples was 3.2kBqkg -1 ±1.8kBqkg -1 , and the mean was 25.7kBqkg -1 (σ=72kBqkg -1 ). The U.S. and Canadian mean and median radio‑cesium activity levels were <0.03kBqkg -1 . U.S. and Canadian samples had detectable 134 Cs and 137 Cs in one dust sample out of 32 collected, and four soils out of 74. The maximum US/Canada radio-cesium particulate matter activity was 0.30±0.10kBqkg -1 . The mean in Japan was skewed upward due to nine of the 180 (5%) samples with activities >250kBqkg -1 . This skewness was present in both the 2011 and 2016 sample sets. >300 individual radioactively-hot particles were identified in samples from Japan; composed of 1% or more of the elements cesium, americium, radium, polonium, thorium, tellurium, or strontium. Some particles reached specific activities in the MBqμg -1 level and higher. No cesium-containing hot particles were found in the U.S. sample set. Only naturally-occurring radionuclides were found in particles from the U.S. background samples. Some of the hot particles detected in this study could cause significant radiation exposures to individuals if inhaled. Exposure models ignoring these isolated hot particles would potentially understate human radiation dose. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. Optical analyzer

    DOEpatents

    Hansen, Anthony D.

    1989-02-07

    An optical analyzer (10) wherein a sample (19) of particulate matter, and particularly of organic matter, which has been collected on a quartz fiber filter (20) is placed in a combustion tube (11), and light from a light source (14) is passed through the sample (19). The temperature of the sample (19) is raised at a controlled rate and in a controlled atmosphere. The magnitude of the transmission of light through the sample (19) is detected (18) as the temperature is raised. A data processor (23), differentiator (28) and a two pen recorder (24) provide a chart of the optical transmission versus temperature and the rate of change of optical transmission versus temperature signatures (T and D) of the sample (19). These signatures provide information as to physical and chemical processes and a variety of quantitative and qualitative information about the sample (19). Additional information is obtained by repeating the run in different atmospheres and/or different rates of heating with other samples of the same particulate material collected on other filters.

  5. Optical analyzer

    DOEpatents

    Hansen, Anthony D.

    1989-01-01

    An optical analyzer (10) wherein a sample (19) of particulate matter, and particularly of organic matter, which has been collected on a quartz fiber filter (20) is placed in a combustion tube (11), and light from a light source (14) is passed through the sample (19). The temperature of the sample (19) is raised at a controlled rate and in a controlled atmosphere. The magnitude of the transmission of light through the sample (19) is detected (18) as the temperature is raised. A data processor (23), differentiator (28) and a two pen recorder (24) provide a chart of the optical transmission versus temperature and the rate of change of optical transmission versus temperature signatures (T and D) of the sample (19). These signatures provide information as to physical and chemical processes and a variety of quantitative and qualitative information about the sample (19). Additional information is obtained by repeating the run in different atmospheres and/or different rates of heating with other samples of the same particulate material collected on other filters.

  6. Effects of wind direction on coarse and fine particulate matter concentrations in southeast Kansas.

    PubMed

    Guerra, Sergio A; Lane, Dennis D; Marotz, Glen A; Carter, Ray E; Hohl, Carrie M; Baldauf, Richard W

    2006-11-01

    Field data for coarse particulate matter ([PM] PM10) and fine particulate matter (PM2.5) were collected at selected sites in Southeast Kansas from March 1999 to October 2000, using portable MiniVol particulate samplers. The purpose was to assess the influence on air quality of four industrial facilities that burn hazardous waste in the area located in the communities of Chanute, Independence, Fredonia, and Coffeyville. Both spatial and temporal variation were observed in the data. Variation because of sampling site was found to be statistically significant for PM10 but not for PM2.5. PM10 concentrations were typically slightly higher at sites located within the four study communities than at background sites. Sampling sites were located north and south of the four targeted sources to provide upwind and downwind monitoring pairs. No statistically significant differences were found between upwind and downwind samples for either PM10 or PM2.5, indicating that the targeted sources did not contribute significantly to PM concentrations. Wind direction can frequently contribute to temporal variation in air pollutant concentrations and was investigated in this study. Sampling days were divided into four classifications: predominantly south winds, predominantly north winds, calm/variable winds, and winds from other directions. The effect of wind direction was found to be statistically significant for both PM10 and PM2.5. For both size ranges, PM concentrations were typically highest on days with predominantly south winds; days with calm/variable winds generally produced higher concentrations than did those with predominantly north winds or those with winds from "other" directions. The significant effect of wind direction suggests that regional sources may exert a large influence on PM concentrations in the area.

  7. Correction Methods for Organic Carbon Artifacts when Using Quartz-Fiber Filters in Large Particulate Matter Monitoring Networks: The Regression Method and Other Options

    EPA Science Inventory

    Sampling and handling artifacts can bias filter-based measurements of particulate organic carbon (OC). Several measurement-based methods for OC artifact reduction and/or estimation are currently used in research-grade field studies. OC frequently is not artifact-corrected in larg...

  8. Sampling of suspended particulate matter using particle traps in the Rhône River: Relevance and representativeness for the monitoring of contaminants.

    PubMed

    Masson, M; Angot, H; Le Bescond, C; Launay, M; Dabrin, A; Miège, C; Le Coz, J; Coquery, M

    2018-05-10

    Monitoring hydrophobic contaminants in surface freshwaters requires measuring contaminant concentrations in the particulate fraction (sediment or suspended particulate matter, SPM) of the water column. Particle traps (PTs) have been recently developed to sample SPM as cost-efficient, easy to operate and time-integrative tools. But the representativeness of SPM collected with PTs is not fully understood, notably in terms of grain size distribution and particulate organic carbon (POC) content, which could both skew particulate contaminant concentrations. The aim of this study was to evaluate the representativeness of SPM characteristics (i.e. grain size distribution and POC content) and associated contaminants (i.e. polychlorinated biphenyls, PCBs; mercury, Hg) in samples collected in a large river using PTs for differing hydrological conditions. Samples collected using PTs (n = 74) were compared with samples collected during the same time period by continuous flow centrifugation (CFC). The grain size distribution of PT samples shifted with increasing water discharge: the proportion of very fine silts (2-6 μm) decreased while that of coarse silts (27-74 μm) increased. Regardless of water discharge, POC contents were different likely due to integration by PT of high POC-content phytoplankton blooms or low POC-content flood events. Differences in PCBs and Hg concentrations were usually within the range of analytical uncertainties and could not be related to grain size or POC content shifts. Occasional Hg-enriched inputs may have led to higher Hg concentrations in a few PT samples (n = 4) which highlights the time-integrative capacity of the PTs. The differences of annual Hg and PCB fluxes calculated either from PT samples or CFC samples were generally below 20%. Despite some inherent limitations (e.g. grain size distribution bias), our findings suggest that PT sampling is a valuable technique to assess reliable spatial and temporal trends of particulate contaminants such as PCBs and Hg within a river monitoring network. Copyright © 2018 Elsevier B.V. All rights reserved.

  9. 40 CFR 60.1815 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... flue gases at the inlet of my particulate matter control device? 60.1815 Section 60.1815 Protection of... I monitor the temperature of flue gases at the inlet of my particulate matter control device? You... flue gas stream at the inlet of each particulate matter control device. ...

  10. 40 CFR 60.1815 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... flue gases at the inlet of my particulate matter control device? 60.1815 Section 60.1815 Protection of... I monitor the temperature of flue gases at the inlet of my particulate matter control device? You... flue gas stream at the inlet of each particulate matter control device. ...

  11. 77 FR 31691 - Approval and Promulgation of Implementation Plans; State of Hawaii; Regional Haze Federal...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-29

    ... Subject to BART 3. BART Determination for Kanoelehua Hill a. BART for NO X and Particulate Matter (PM) b.... The initials PM mean or refer to particulate matter. xxiv. The initials PM2.5 mean or refer to particulate matter with an aerodynamic diameter of less than 2.5 micrometers (fine particulate matter). xxv...

  12. IRON-BINDING AND STORAGE PROTEINS IN SPUTUM

    EPA Science Inventory

    Induced sputum (IS) and bronchoalveolar lavage (BAL) sample different lung compartments, with IS obtaining secretions from the surfaces of the bronchial airways and BAL sampling secretions from the alveolar airspaces. Deposition of iron-containing particulate matter occurs prefer...

  13. Oxygen analyzer

    DOEpatents

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  14. Oxygen analyzer

    DOEpatents

    Benner, William H.

    1986-01-01

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  15. Labile, dissolved and particulate PAHs and trace metals in wastewater: passive sampling, occurrence, partitioning in treatment plants.

    PubMed

    Gourlay-Francé, C; Bressy, A; Uher, E; Lorgeoux, C

    2011-01-01

    The occurrence and the partitioning of polycyclic aromatic hydrocarbons (PAHs) and seven metals (Al, Cd, Cr, Cu, Ni, Pb and Zn) were investigated in activated sludge wastewater treatment plants by means of passive and active sampling. Concentrations total dissolved and particulate contaminants were determined in wastewater at several points across the treatment system by means of grab sampling. Truly dissolved PAHs were sampled by means of semipermeable membrane devices. Labile (inorganic and weakly complexed) dissolved metals were also sampled using the diffusive gradient in thin film technique. This study confirms the robustness and the validity of these two passive sampling techniques in wastewater. All contaminant concentrations decreased in wastewater along the treatment, although dissolved and labile concentrations sometimes increased for substances with less affinity with organic matter. Solid-liquid and dissolved organic matter/water partitioning constants were estimated. The high variability of both partitioning constants for a simple substance and the poor relation between K(D) and K(OW) shows that the binding capacities of particles and organic matter are not uniform within the treatment and that other process than equilibrium sorption affect contaminant repartition and fate in wastewater.

  16. Discharge-related trends in the composition of particulate organic matter exported by small mountainous rivers: results from Oregon and California (Invited)

    NASA Astrophysics Data System (ADS)

    Goni, M. A.; Hatten, J. A.; Wheatcroft, R. A.; Borgeld, J.; Williamson, A.; Padgett, J.; Pasternack, G. B.; Gray, A.; Watson, E. B.

    2009-12-01

    Small mountainous rivers display highly variable discharges on both seasonal and event scales. Previous work has shown marked differences in the composition of the particulate load of rivers collected at different stages of the hydrograph, but fewer studies have specifically investigated how the biogeochemical compositions of particulate organic matter change as a function of discharge and how this variation affects the characteristics of the materials reaching the ocean. We explore these issues using data from three rivers along the west coast of the U.S. (Umpqua, Eel and Salinas) with similar watershed size but contrasting climate, vegetation and land use. Coarse and fine particulate organic matter samples collected at different discharges, including several flood events, were analyzed for carbon and nitrogen content, stable carbon and nitrogen isotopic compositions, radiocarbon compositions and yields of different organic biomarkers (e.g. lignin phenols, cutin acids, amino acid products). This presentation will focus on comparing and contrasting the provenance, age, and biochemical make-up of materials transported by each of the rivers as a function of discharge. Seasonal and event-scale differences in organic matter concentrations and compositions will be the subject of an accompanying poster. We will discuss both the processes responsible for these contrasts and the impacts they have on the delivery and fate of terrigenous organic matter in the coastal ocean.

  17. Status of Suspended Particulate Matters Pollution at Traditional Markets in Makassar City

    NASA Astrophysics Data System (ADS)

    Suryani, Sri; Fahrunnisa

    2018-03-01

    Research on the status of suspended particulate matters pollution in four traditional markets located in Makassar city has been done. The purpose of this research is to know the air quality in the traditional market areas, especially caused by suspended particulate matters. The background of this research is because traders who trade in traditional markets generally peddle their goods along dusty roads and suspended particulate matters in dust can be inhaled when the vehicle passes. These suspended particulate matters pollutant can cause lung diseases. The results showed that the level of suspended particulate matters pollution fluctuates every year depending on the local wind speed, humidity, and temperature. Research results also showed the values were over the standard value according to the governor of South Sulawesi regulation.

  18. Distribution, origin and transformation of amino sugars and bacterial contribution to estuarine particulate organic matter

    NASA Astrophysics Data System (ADS)

    Khodse, Vishwas B.; Bhosle, Narayan B.

    2013-10-01

    Amino sugars including bacterial biomarker muramic acid (Mur) were investigated in suspended particulate matter (SPM) to understand their distribution, origin, and biogeochemical cycling and the contribution of bacteria to particulate organic matter (POM) of the Mandovi estuary. SPM was collected from 9 sampling stations in the Mandovi estuary during the pre-monsoon (March) and monsoon (August). Total particulate amino sugar (TPAS) concentrations and yields varied spatially and were 2 to 5 times higher during the monsoon than the pre-monsoon. Negative correlation between salinity and TPAS-C yields [TPAS-C/particulate organic carbon (POC)×100] indicates the influence of terrestrial organic matter on the transport of TPAS-carbon. Glucosamine (GlcN), galactosamine (GalN), and mannosamine (ManN) were abundant during the monsoon. Low GlcN/GalN ratios (<3) indicate bacteria as the major source of amino sugars. Higher amino sugar yields and lower GlcN/GalN ratios during the monsoon than the pre-monsoon indicate enhanced transformation and greater bacterial contribution to POM during the former season. Degradation trends observed with TPAS were well supported by those obtained with carbohydrates and amino acids. Based on Mur concentrations, bacteria accounted for 24% to 35% of the POC and 24% to 62% of the total particulate nitrogen (TPN). Intact bacterial cells, however accounted for a small proportion of POC (2.5% to 4%) and TPN (9% to 11%). Our study suggests that POM was subjected to extensive diagenetic transformation, and its composition was influenced by bacteria, especially during the monsoon.

  19. Size charge fractionation of metals in municipal solid waste landfill leachate.

    PubMed

    Oygard, Joar Karsten; Gjengedal, Elin; Røyset, Oddvar

    2007-01-01

    Municipal solid waste landfill leachates from 9 Norwegian sites were size charge fractionated in the field, to obtain three fractions: particulate and colloidal matter >0.45microm, free anions/non-labile complexes <0.45microm and free cations/labile complexes <0.45microm. The fractionation showed that Cd and Zn, and especially Cu and Pb, were present to a large degree (63-98%) as particulate and colloidal matter >0.45microm. Cr, Co and Ni were on the contrary present mostly as non-labile complexes (69-79%) <0.45microm. The major cations Ca, Mg, K, and Mn were present mainly as free cations/labile complexes <0.45microm, while As and Mo were present to a large degree (70-90%) as free anions/non-labile complexes <0.45microm. Aluminium was present mainly as particulate and colloidal matter >0.45microm. The particulate and colloidal matter >0.45microm was mainly inorganic; indicating that the metals present in this fraction were bound as inorganic compounds. The fractionation gives important information on the mobility and potential bioavailability of the metals investigated, in contrast to the total metal concentrations usually reported. To study possible changes in respective metal species in leachate in aerated sedimentation tanks, freshly sampled leachate was stored for 48h, and subsequently fractionated. This showed that the free heavy metals are partly immobilized during storage of leachate with oxygen available. The largest effects were found for Cd and Zn. The proportion of As and Cr present as particulate matter or colloids >0.45microm also increased.

  20. Ambient air levels and health risk assessment of benzo(a)pyrene in atmospheric particulate matter samples from low-polluted areas: application of an optimized microwave extraction and HPLC-FL methodology.

    PubMed

    de la Gala Morales, María; Holgado, Fernando Rueda; Marín, Ma Rosario Palomo; Blázquez, Lorenzo Calvo; Gil, Eduardo Pinilla

    2015-04-01

    A new methodology involving a simple and fast pretreatment of the samples by microwave-assisted extraction and concentration by N2 stream, followed by HPLC with fluorescence detection, was used for determining the concentration of benzo(a)pyrene (BaP) in atmospheric particulate matter (PM10 fraction). Obtained LOD, 1.0 × 10(-3) ng/m(3), was adequate for the analysis of benzo(a)pyrene in the samples, and BaP recovery from PAH in Fine Dust (PM10-like) certified reference material was nearly quantitative (86%). The validated procedure was applied for analyzing 115 PM10 samples collected at different sampling locations in the low-polluted area of Extremadura (Southwest Spain) during a monitoring campaign carried out in 2011-2012. BaP spatial variations and seasonal variability were investigated as well as the influence of meteorological conditions and different air pollutants concentrations. A normalized protocol for health risk assessment was applied to estimate lifetime cancer risk due to BaP inhalation in the sampling areas, finding that around eight inhabitants per million people may develop lung cancer due to the exposition to BaP in atmospheric particulates emitted by the investigated sources.

  1. 40 CFR 62.15270 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... flue gases at the inlet of my particulate matter control device? 62.15270 Section 62.15270 Protection....15270 How do I monitor the temperature of flue gases at the inlet of my particulate matter control... temperature of the flue gas stream at the inlet of each particulate matter control device. ...

  2. 40 CFR 62.15270 - How do I monitor the temperature of flue gases at the inlet of my particulate matter control device?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... flue gases at the inlet of my particulate matter control device? 62.15270 Section 62.15270 Protection....15270 How do I monitor the temperature of flue gases at the inlet of my particulate matter control... temperature of the flue gas stream at the inlet of each particulate matter control device. ...

  3. Characterization of particulate matter deposited on urban tree foliage: A landscape analysis approach

    NASA Astrophysics Data System (ADS)

    Lin, Lin; Yan, Jingli; Ma, Keming; Zhou, Weiqi; Chen, Guojian; Tang, Rongli; Zhang, Yuxin

    2017-12-01

    Plants can mitigate ambient particulate matter by cleaning the air, which is crucial to urban environments. A novel approach was presented to quantitatively characterize particulate matter deposited on urban tree foliage. This approach could accurately quantify the number, size, shape, and spatial distribution of particles with different diameters on leaves. Spatial distribution is represented by proximity, which measures the closeness of particles. We sampled three common broadleaf species and obtained images through field emission scanning electron microscopy. We conducted the object-based method to extract particles from images. We then used Fragstats to analyze the landscape characteristics of these particles in term of selected metrics. Results reveal that Salix matsudana is more efficient than Ailanthus altissima and Fraxinus chinensis in terms of the number and area of particles per unit area and the proportion of fine particulate matter. The shape complexity of the particles increases with their size. Among the three species, S. matsudana and A. altissima particles respectively yield the highest and lowest proximity. PM1 in A. altissima and PM10 in F. chinensis and S. matsudana show the highest proximity, which may influence subsequent particle retention. S. matsudana should be generally considered to collect additional small particles. Different species and particle sizes exhibit various proximities, which should be further examined to elucidate the underlying mechanism.

  4. 40 CFR 52.1476 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... National Ambient Air Quality Standards for particulate matter. (1) NAQR Article 7.2.7, Particulate Matter; Table 4.2, Emissions Inventory Summary for Particulates and Table 5.2, Summary of Control Strategy... 24, 1979. (2) Nevada Air Quality Regulations, Article 4, Rule 4.34, (Visible Emission from Stationary...

  5. Tiny is mighty: seagrass beds have a large role in the export of organic material in the tropical coastal zone.

    PubMed

    Gillis, Lucy G; Ziegler, Alan D; van Oevelen, Dick; Cathalot, Cecile; Herman, Peter M J; Wolters, Jan W; Bouma, Tjeerd J

    2014-01-01

    Ecosystems in the tropical coastal zone exchange particulate organic matter (POM) with adjacent systems, but differences in this function among ecosystems remain poorly quantified. Seagrass beds are often a relatively small section of this coastal zone, but have a potentially much larger ecological influence than suggested by their surface area. Using stable isotopes as tracers of oceanic, terrestrial, mangrove and seagrass sources, we investigated the origin of particulate organic matter in nine mangrove bays around the island of Phuket (Thailand). We used a linear mixing model based on bulk organic carbon, total nitrogen and δ13C and δ15N and found that oceanic sources dominated suspended particulate organic matter samples along the mangrove-seagrass-ocean gradient. Sediment trap samples showed contributions from four sources oceanic, mangrove forest/terrestrial and seagrass beds where oceanic had the strongest contribution and seagrass beds the smallest. Based on ecosystem area, however, the contribution of suspended particulate organic matter derived from seagrass beds was disproportionally high, relative to the entire area occupied by mangrove forests, the catchment area (terrestrial) and seagrass beds. The contribution from mangrove forests was approximately equal to their surface area, whereas terrestrial contributions to suspended organic matter under contributed compared to their relative catchment area. Interestingly, mangrove forest contribution at 0 m on the transects showed a positive relationship with the exposed frontal width of the mangrove, indicating that mangrove forest exposure to hydrodynamic energy may be a controlling factor in mangrove outwelling. However we found no relationship between seagrass bed contribution and any physical factors, which we measured. Our results indicate that although seagrass beds occupy a relatively small area of the coastal zone, their role in the export of organic matter is disproportional and should be considered in coastal management especially with respect to their importance as a nutrient source for other ecosystems and organisms.

  6. 40 CFR 89.404 - Test procedure overview.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... engine operating conditions to be conducted on an engine dynamometer. The exhaust gases, generated raw or... matter. For more information on particulate matter sampling see § 89.112(c). The test cycles consist of... (raw analysis), and the power output during each mode. The measured values are weighted and used to...

  7. Formation of particulate matter monitoring during combustion of wood pellete with additives

    NASA Astrophysics Data System (ADS)

    Palacka, Matej; Holubčík, Michal; Vician, Peter; Jandačka, Jozef

    2016-06-01

    Application additives into the material for the production of wood pellets achieve an improvement in some properties such as pellets ash flow temperature and abrasion resistance. Additives their properties influence the course of combustion, and have an impact on the results of issuance. The experiment were selected additives corn starch and dolomite. Wood pellets were produced in the pelleting press and pelletizing with the additives. Selected samples were tested for the production of particulate matter (PM) during their direct burn. The paper analyzing a process of producing wood pellets and his effect on the final properties.

  8. PCBs, PCDD/Fs and PAHs in dissolved, suspended and settling particulate matrixes from the Baltic Sea

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Naef, C.; Broman, D.; Zebuehr, Y.

    The occurrence and dynamics of polychlorinated biphenyls (PCBs), dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and polycyclic aromatic hydrocarbons (PAHs) are discussed on the basis of results from samples taken at pristine coastal and off shore locations in the Baltic Sea. The sampling techniques used were high volume cross flow filtration and sediment traps for suspended and settling particulate matter, respectively, and polyurethane foam adsorbents for the compounds associated with the apparently dissolved fractions. All samples were Soxhlet extracted with toluene and separated on a HPLC system followed by quantification on GS/MS. The importance of parameters such as concentrations of particulate lipids, particulatemore » organic carbon and dissolved organic carbon, etc. for the distribution of the compounds between the suspended and settling particulate matrixes and the dissolved phase in the water are discussed. In situ determined particulate organic carbon-water partition coefficients as well as predicted dissolved organic carbon-water partition coefficients and approximations of the average ``truly`` dissolved concentrations are presented. The particulate and dissolved concentrations in the mixed surface layer are discussed in perspective to the particulate flux of PCBs, PCDD/Fs and PAHs.« less

  9. Occurrence and Characterization of Steroid Growth Promoters Associated with Particulate Matter Originating from Beef Cattle Feedyards.

    PubMed

    Blackwell, Brett R; Wooten, Kimberly J; Buser, Michael D; Johnson, Bradley J; Cobb, George P; Smith, Philip N

    2015-07-21

    Studies of steroid growth promoters from beef cattle feedyards have previously focused on effluent or surface runoff as the primary route of transport from animal feeding operations. There is potential for steroid transport via fugitive airborne particulate matter (PM) from cattle feedyards; therefore, the objective of this study was to characterize the occurrence and concentration of steroid growth promoters in PM from feedyards. Air sampling was conducted at commercial feedyards (n = 5) across the Southern Great Plains from 2010 to 2012. Total suspended particulates (TSP), PM10, and PM2.5 were collected for particle size analysis and steroid growth promoter analysis. Particle size distributions were generated from TSP samples only, while steroid analysis was conducted on extracts of PM samples using liquid chromatography mass spectrometry. Of seven targeted steroids, 17α-estradiol and estrone were the most commonly detected, identified in over 94% of samples at median concentrations of 20.6 and 10.8 ng/g, respectively. Melengestrol acetate and 17α-trenbolone were detected in 31% and 39% of all PM samples at median concentrations of 1.3 and 1.9 ng/g, respectively. Results demonstrate PM is a viable route of steroid transportation and may be a significant contributor to environmental steroid hormone loading from cattle feedyards.

  10. 40 CFR 52.1880 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met because the... matter in the Greater Metropolitan Cleveland Intrastate Region and the Ohio portions of the Northwest...

  11. 40 CFR 52.1880 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met because the... matter in the Greater Metropolitan Cleveland Intrastate Region and the Ohio portions of the Northwest...

  12. 40 CFR 52.1880 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met because the... matter in the Greater Metropolitan Cleveland Intrastate Region and the Ohio portions of the Northwest...

  13. 40 CFR 52.1880 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Particulate matter... strategy: Particulate matter. (a) The requirements of subpart G of this chapter are not met because the... matter in the Greater Metropolitan Cleveland Intrastate Region and the Ohio portions of the Northwest...

  14. Effects of rainfalls variability and physical-chemical parameters on enteroviruses in sewage and lagoon in Yopougon, Côte d'Ivoire

    NASA Astrophysics Data System (ADS)

    Momou, Kouassi Julien; Akoua-Koffi, Chantal; Traoré, Karim Sory; Akré, Djako Sosthène; Dosso, Mireille

    2017-07-01

    The aim of this study was to assess the variability of the content of nutrients, oxidizable organic and particulate matters in raw sewage and the lagoon on the effect of rainfall. Then evaluate the impact of these changes in the concentration of enteroviruses (EVs) in waters. The sewage samples were collected at nine sampling points along the channel, which flows, into a tropical lagoon in Yopougon. Physical-chemical parameters (5-day Biochemical Oxygen Demand, Chemical Oxygen Demand, Suspended Particulate Matter, Total Phosphorus, Orthophosphate, Total Kjeldahl Nitrogen and Nitrate) as well as the concentration of EV in these waters were determined. The average numbers of EV isolated from the outlet of the channel were 9.06 × 104 PFU 100 ml-1. Consequently, EV was present in 55.55 and 33.33 % of the samples in the 2 brackish lagoon collection sites. The effect of rainfall on viral load at the both sewage and brackish lagoon environments is significant correlate (two-way ANOVA, P < 0.05). Furthermore, in lagoon environment, nutrients (Orthophosphate, Total Phosphorus), 5-day Biochemical Oxygen Demand, Chemical Oxygen Demand and Suspended Particulate Matter were significant correlated with EVs loads ( P < 0.05 by Pearson test). The overall results highlight the problem of sewage discharge into the lagoon and correlation between viral loads and water quality parameters in sewage and lagoon.

  15. DICARBOXYLIC ACID CONCENTRATION TRENDS AND SAMPLING ARTIFACTS

    EPA Science Inventory

    Dicarboxylic acids associated with airborne particulate matter were measured during a summer period in Philadelphia that included multiple air pollution episodes. Samples were collected for two ten hour periods each day using a high volume sampler with two quartz fiber filters in...

  16. PAH and PCB in the Baltic -- A budget approach including fluxes, occurrence and concentration variability in air, suspended and settling particulates in water, surface sediments and river water

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Broman, D.; Axelman, J.; Bandh, C.

    In order to study the fate and occurrence of two groups of hydrophobic compounds in the Baltic aquatic environment a large number of samples were collected from the southern Baltic proper to the northern Bothnian Bay for the analyses of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs). The following sample matrices were collected; bottom surface sediments (0--1 cm, collected with gravity corer), settling particulate matter (collected with sediment traps), open water samples and over water samples (suspended particulates and dissolved fraction sampled by filtration) and air samples (aerosols and vapor phase sampled by filtration). All samples (except over watermore » and air) were collected at open sea in the Baltic. The analyses results have been used to make a model approach on the whole Baltic and to elucidate different aspects of the behavior of PAHs and PCBs in the Baltic, such as the occurrence of the compounds in water and sediment, the total content as well as the concentration variabilities over such a large geographical area, Further, the data on settling particulate matter as well as the air concentration data were used to estimate the total fluxes of PAHs and PCBs to the bottoms of the Baltic and t o the total water area of the Baltic, respectively. Further, data on the PAH and PCB content in river water from four major rivers provides rough estimates of the riverine input to the Baltic. The dynamics of PAHs and PCBs within the water mass have also been studied in terms of settling velocities and residence times in the water mass for these type of compounds in the open Baltic.« less

  17. 77 FR 45956 - Approval and Promulgation of Implementation Plans; Kentucky; Louisville; Fine Particulate Matter...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-02

    ... Promulgation of Implementation Plans; Kentucky; Louisville; Fine Particulate Matter 2002 Base Year Emissions... action to approve the 1997 annual fine particulate matter (PM 2.5 ) 2002 base year emissions inventory... 45957

  18. Dynamics of coarse particulate matter in the turbidity maximum zone of the Gironde Estuary

    NASA Astrophysics Data System (ADS)

    Fuentes-Cid, Ana; Etcheber, Henri; Schmidt, Sabine; Abril, Gwenaël; De-Oliveira, Eric; Lepage, Mario; Sottolichio, Aldo

    2014-01-01

    There is a lack of studies devoted to coarse particulate matter (CPM) in estuaries, although this fraction can disturb activities that filter large volumes of water, such as industrial or fishery activities. In the macrotidal and highly-turbid Gironde Estuary, a monthly sampling of CPM was performed in 2011 and 2013 at two stations in the Turbidity Maximum Zone (TMZ) to understand its seasonal, tidal and hydrological dynamics. Regardless of the season and station, low quantities of CPM (few g m-3) were observed in comparison with suspended particulate matter (several 103 g m-3). The highest concentrations were consistently recorded in bottom waters and at the upstream station. Whereas there is no clear link between the CPM present in the column water and spring or neap tides, an increase in the CPM size has been identified at the two stations after a flood event, fact potentially critical regarding filtering functioning of estuarine activities.

  19. EXPOSURE ASSESSMENT OF OLDER ADULTS TO PARTICULATE MATTER

    EPA Science Inventory

    The factors that influence the amount of particulate matter that potentially susceptible elderly Americans are exposed to is an issue of concern. This presentation and abstract investigates these factors using data obtained from three longitudinal particulate matter panel studies...

  20. PM levels in urban area of Bejaia

    NASA Astrophysics Data System (ADS)

    Benaissa, Fatima; Maesano, Cara Nichole; Alkama, Rezak; Annesi-Maesano, Isabella

    2017-04-01

    Air pollution is not routinely measured in Bejaia City, Algeria, an urban area of around 200,000 inhabitants. We present first time measurements of particulate matter (PM) mass concentrations for this city (PM10, PM7, PM4, PM2.5 and PM1) over the course of one week, from July 8 to July 14, 2015. This study covered eight urban sampling sites and 169 measurements were obtained to determine mass concentration levels. Air pollution is not routinely measured in Bejaia City, Algeria, an urban area of around 200,000 inhabitants. We present first time measurements of particulate matter (PM) mass concentrations for this city (PM10, PM7, PM4, PM2.5 and PM1) over the course of one week, from July 8 to July 14, 2015. This study covered eight urban sampling sites and 169 measurements were obtained to determine mass concentration levels. The average city-wide PM10 and PM2.5 concentrations measured during this sampling were 87.8 ± 33.9 and 28.7 ± 10.6 µg/m3 respectively. These results show that particulate matter levels are high and exceed Algerian ambient air quality standards (maximum 80 µg/m3, without specifying the particle size). Further, PM10 and PM2.5 averages were well above the prescribed 24-hour average World Health Organization Air Quality Guidelines (WHO AQG) (50 µg/m3 for PM10 and 25 µg/m3 for PM2.5). The PM1, PM2,5, PM4 and PM7 fractions accounted for 15%, 32 %, 56% and 78% respectively of the PM10 measurements. Our analysis reveals that PM concentration variations in the study region were influenced primarily by traffic. In fact, lower PM10 concentrations (21.7 and 33.1 µg/m3) were recorded in residential sites while higher values (53.1, and 45.2 µg/m3) were registered in city centers. Keywords: Particulate matter, Urban area, vehicle fleet, Bejaia.

  1. Impact of fuel quality regulation and speed reductions on shipping emissions: implications for climate and air quality.

    PubMed

    Lack, Daniel A; Cappa, Christopher D; Langridge, Justin; Bahreini, Roya; Buffaloe, Gina; Brock, Charles; Cerully, Kate; Coffman, Derek; Hayden, Katherine; Holloway, John; Lerner, Brian; Massoli, Paola; Li, Shao-Meng; McLaren, Robert; Middlebrook, Ann M; Moore, Richard; Nenes, Athanasios; Nuaaman, Ibraheem; Onasch, Timothy B; Peischl, Jeff; Perring, Anne; Quinn, Patricia K; Ryerson, Tom; Schwartz, Joshua P; Spackman, Ryan; Wofsy, Steven C; Worsnop, Doug; Xiang, Bin; Williams, Eric

    2011-10-15

    Atmospheric emissions of gas and particulate matter from a large ocean-going container vessel were sampled as it slowed and switched from high-sulfur to low-sulfur fuel as it transited into regulated coastal waters of California. Reduction in emission factors (EFs) of sulfur dioxide (SO₂), particulate matter, particulate sulfate and cloud condensation nuclei were substantial (≥ 90%). EFs for particulate organic matter decreased by 70%. Black carbon (BC) EFs were reduced by 41%. When the measured emission reductions, brought about by compliance with the California fuel quality regulation and participation in the vessel speed reduction (VSR) program, are placed in a broader context, warming from reductions in the indirect effect of SO₄ would dominate any radiative changes due to the emissions changes. Within regulated waters absolute emission reductions exceed 88% for almost all measured gas and particle phase species. The analysis presented provides direct estimations of the emissions reductions that can be realized by California fuel quality regulation and VSR program, in addition to providing new information relevant to potential health and climate impact of reduced fuel sulfur content, fuel quality and vessel speed reductions.

  2. Characterization of chemical and particulate emissions from aircraft engines

    NASA Astrophysics Data System (ADS)

    Agrawal, Harshit; Sawant, Aniket A.; Jansen, Karel; Wayne Miller, J.; Cocker, David R.

    2008-06-01

    This paper presents a series of measurements from four on-wing, commercial aircraft engines, including two newer CFM56-7 engines and two earlier CFM56-3 engines. Samples were collected from each engine using a probe positioned behind the exhaust nozzle of the aircraft, chocked on a concrete testing pad. The emission factors for particulate matter mass, elemental and organic carbon, carbonyls, polycyclic aromatic hydrocarbons, n-alkanes, dioxins, metals and ions are reported for four different engine power setting modes. The emissions indices of particulate matter, elemental and organic carbon are highly power dependent for these engines. Particulate matter emission indices (g kg-1 fuel) are found to increase from 1.1E-02 to 2.05E-01 with increase in power from idle to 85%. The elemental carbon to organic carbon varies from 0.5 to 3.8 with change in power from idle to 85%. The carbonyl emissions are dominated by formaldehyde. The emission index of formaldehyde ranges from 2.3E-01 to 4.8E-01 g kg-1 fuel. The distribution of metals depends on the difference in the various engines. The dioxin emissions from the aircraft engines are observed to be below detection limit.

  3. MULTI-SITE PERFORMANCE EVALUATIONS OF CANDIDATE METHODOLOGIES FOR DETERMINING COARSE PARTICULATE MATTER (PMC) CONCENTRATIONS

    EPA Science Inventory

    Comprehensive field studies were conducted to evaluate the performance of sampling methods for measuring the coarse fraction of PM10 in ambient air. Five separate sampling approaches were evaluated at each of three sampling sites. As the primary basis of comparison, a discret...

  4. MULTI-SITE EVALUATIONS OF CANDIDATE METHODOLOGIES FOR DETERMINING COARSE PARTICULATE MATTER (PMC) CONCENTRATIONS

    EPA Science Inventory

    Comprehensive field studies were conducted to evaluate the performance of sampling methods for measuring the coarse fraction of PM10 in ambient air. Five separate sampling approaches were evaluated at each of three sampling sites. As the primary basis of comparison, a discret...

  5. MULTI-SITE EVALUATIONS OF CANDIDATE METHODOLOGIES FOR DETERMINING COARSE PARTICULATE MATTER (PMC) CONCENTRATIONS

    EPA Science Inventory

    Comprehensive field studies were conducted to evaluate the performance of sampling methods for measuring the coarse fraction of PM10 in ambient air. Five separate sampling approaches were evaluated at each of three sampling sites. As the primary basis of comparison, a discrete ...

  6. CHEMICAL AND PHYSICAL CHARACTERIZATION OF INDOOR, OUTDOOR, AND PERSONAL SAMPLES COLLECTED IN AND AROUND A RETIREMENT FACILITY

    EPA Science Inventory

    Residential, personal, indoor, and outdoor sampling of particulate matter was conducted at a retirement center in the Towson area of northern Baltimore County in 1998. Concurrent sampling was conducted at a central community site. Computer-controlled scanning electron microsco...

  7. Major and trace element partitioning between dissolved and particulate phases in Antarctic surface snow.

    PubMed

    Grotti, M; Soggia, F; Ardini, F; Magi, E

    2011-09-01

    In order to provide a new insight into the Antarctic snow chemistry, partitioning of major and trace elements between dissolved and particulate (i.e. insoluble particles, >0.45 μm) phases have been investigated in a number of coastal and inland snow samples, along with their total and acid-dissolvable (0.5% nitric acid) concentrations. Alkaline and alkaline-earth elements (Na, K, Ca, Mg, Sr) were mainly present in the dissolved phase, while Fe and Al were predominantly associated with the particulate matter, without any significant difference between inland and coastal samples. On the other hand, partitioning of trace elements depended on the sampling site position, showing a general decrease of the particulate fraction by moving from the coast to the plateau. Cd, Cu, Pb and Zn were for the most part in the dissolved phase, while Cr was mainly associated with the particulate fraction. Co, Mn and V were equally distributed between dissolved and particulate phases in the samples collected from the plateau and preferentially associated with the particulate in the coastal samples. The correlation between the elements and the inter-sample variability of their concentration significantly decreased for the plateau samples compared to the coastal ones, according to a change in the relative contribution of the metal sources and in good agreement with the estimated marine and crustal enrichment factors. In addition, samples from the plateau were characterised by higher enrichment factors of anthropogenic elements (Cd, Cr, Cu, Pb and Zn), compared to the coastal area. Finally, it was observed that the acid-dissolvable metal concentrations were generally lower than the total concentration values, showing that the acid treatment can dissolve only a given fraction of the metal associated with the particulate (<20% for iron and aluminium).

  8. Pressurized liquid extraction of diesel and air particulate standard reference materials: effect of extraction temperature and pressure.

    PubMed

    Schantz, Michele M; McGaw, Elizabeth; Wise, Stephen A

    2012-10-02

    Four particulate matter Standard Reference Materials (SRMs) available from the National Institute of Standards and Technology (NIST) were used to evaluate the effect of solvent, number of static cycles and static times, pressure, and temperature when using pressurized liquid extraction (PLE) for the extraction of polycyclic aromatic hydrocarbons (PAHs) and nitrated-PAHs. The four materials used in the study were SRM 1648a Urban Particulate Matter, SRM 1649b Urban Dust, SRM 1650b Diesel Particulate Matter, and SRM 2975 Diesel Particulate Matter (Industrial Forklift). The results from the study indicate that the choice of solvent, dichloromethane compared to toluene and toluene/methanol mixtures, had little effect on the extraction efficiency. With three to five extraction cycles, increasing the extraction time for each cycle from 5 to 30 min had no significant effect on the extraction efficiency. The differences in extraction efficiency were not significant (with over 95% of the differences being <10%) when the pressure was increased from 13.8 to 20.7 MPa. The largest increase in extraction efficiency occurred for selected PAHs when the temperature of extraction was increased from 100 to 200 °C. At 200 °C naphthalene, biphenyl, fluorene, dibenzothiophene, and anthracene show substantially higher mass fractions (>30%) than when extracted at 100 °C in all the SRMs studied. For SRM 2975, large increases (>100%) are also observed for some other PAHs including benz[a]anthracene, benzo[k]fluoranthene, benzo[e]pyrene, benzo[a]pyrene, benzo[ghi]perylene, and benzo[b]chrysene when extracted at the higher temperatures; however, similar trends were not observed for the other diesel particulate sample, SRM 1650b. The results are discussed in relation to the use of the SRMs for evaluating analytical methods.

  9. Analysis of Parent/Nitrated Polycyclic Aromatic Hydrocarbons in Particulate Matter 2.5 Based on Femtosecond Ionization Mass Spectrometry.

    PubMed

    Itouyama, Noboru; Matsui, Taiki; Yamamoto, Shigekazu; Imasaka, Tomoko; Imasaka, Totaro

    2016-02-01

    Particulate matter 2.5 (PM2.5), collected from ambient air in Fukuoka City, was analyzed by gas chromatography combined with multiphoton ionization mass spectrometry using an ultraviolet femtosecond laser (267 nm) as the ionization source. Numerous parent polycyclic aromatic hydrocarbons (PPAHs) were observed in a sample extracted from PM2.5, and their concentrations were determined to be in the range from 30 to 190 pg/m(3) for heavy PPAHs. Standard samples of nitrated polycyclic aromatic hydrocarbons (NPAHs) were examined, and the limits of detection were determined to be in the picogram range. The concentration of NPAH adsorbed on PM2.5 in the air was less than 900-1300 pg/m(3). Graphical Abstract ᅟ.

  10. Extensive 1-year survey of trace elements and compounds in the airborne suspended particulate matter in Cleveland, Ohio

    NASA Technical Reports Server (NTRS)

    King, R. B.; Fordyce, J. S.; Antoine, A. C.; Leibecki, H. F.; Neustadter, H. E.; Sidik, S. M.

    1976-01-01

    Concentrations of 75 chemical constituents in the airborne particulate matter were measured in Cleveland, Ohio, during 1971 and 1972. Values covering a 1-year period (45 to 50 sampling days) at each of 16 sites are presented for 60 elements. A lesser number of values is given for sulfate, nitrate, fluoride, acidity, 10 polynuclear aromatic hydrocarbon compounds, and the aliphatic hydrocarbon compounds as a group. Methods used included instrumental neutron activation, emission spectroscopy, gas chromatography, combustion techniques, and colorimetry. Uncertainties in the concentrations associated with the sampling procedures, the analysis methods, the use of several analytical facilities, and samples with concentrations below the detection limits are evaluated in detail. The data is discussed in relation to other studies and source origins. The trace constituent concentrations as a function of wind direction are used to suggest a practical method for air pollution source identification.

  11. Environmental test chamber

    NASA Astrophysics Data System (ADS)

    Qian, Li

    2016-04-01

    Increasing of particulates in the air in city became a serious problem , but in the Beijing area students rarely research such questions. The intelligent instrument of suspended particulate matter sampler which introduce from the institute of geology and geophysics, Chinese academy of sciences can be collected for all kinds of grain size of suspended matter in the air.We put them near schools,so the PM2.5 in the air near our shool can be collected. The method for analysis is the environmental magnetism, etc. Numerous studies have demonstrated rapid and non-destructive magnetic parameters measurement for rapid estimation of particulate sources of heavy metals and provides a very effective means. Environmental magnetism is a frontier science among earth science, environmental science and magnetism,which has been applied into many fields because it is capable of providing important information for studying the regional or global environmental changes and the impact of human activity on environment. Testing magnetic parameters of the particle can extract atmospheric particulate matter source, distribution, pollution level and dynamic change information. Measured the magnetic parameters of ARM, IRM, hysteresis loop , element composition, soil particle size of the soil, leaf, the river and dustfall samples and PM2.5 of the atmospheric dustfall samples on campus and the Beijing city.By means of environmental magnetism analysis of atmospheric pollutants category, amount, etc. Magnetic properties of pollutants may indicate the source of the pollutants, the nature of the analysis of pollutants, monitoring pollutant change over time.

  12. CHEMICAL CHARACTERIZATION OF AMBIENT PARTICULATE MATTER NEAR THE WORLD TRADE CENTER: ELEMENTAL CARBON, ORGANIC CARBON, AND MASS RECONSTRUCTION

    EPA Science Inventory

    Concentrations of elemental carbon (EC), organic carbon matter (OM), particulate matter less than 2.5 um (PM2.5), and reconstructed soil, trace element oxides, and sulfate are reported from four locations near the World Trade Center (WTC) complex for airborne particulate matter (...

  13. 77 FR 39205 - Public Hearings for Proposed Rules-National Ambient Air Quality Standards for Particulate Matter

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-02

    ... Matter AGENCY: Environmental Protection Agency (EPA). ACTION: Announcement of public hearings. SUMMARY... Standards for Particulate Matter,'' that is scheduled to be published in the Federal Register on June 29... standards (NAAQS) for particulate matter (PM) to provide requisite protection of public health and welfare...

  14. Atmospheric mercury and fine particulate matter in coastal New England: implications for mercury and trace element sources in the northeastern United States

    USGS Publications Warehouse

    Kolker, Allan; Engle, Mark A.; Peucker-Ehrenbrink, Bernhard; Geboy, Nicholas J.; Krabbenhotft, David P.; Bothner, Michael H.; Tate, Michael T.

    2013-01-01

    Intensive sampling of ambient atmospheric fine particulate matter was conducted at Woods Hole, Massachusetts over a four-month period from 3 April to 29 July, 2008, in conjunction with year-long deployment of the USGS Mobile Mercury Lab. Results were obtained for trace elements in fine particulate matter concurrently with determination of ambient atmospheric mercury speciation and concentrations of ancillary gasses (SO2, NOx, and O3). For particulate matter, trace element enrichment factors greater than 10 relative to crustal background values were found for As, Bi, Cd, Cu, Hg, Pb, Sb, V, and Zn, indicating contribution of these elements by anthropogenic sources. For other elements, enrichments are consistent with natural marine (Na, Ca, Mg, Sr) or crustal (Ba, Ce, Co, Cs, Fe, Ga, La, Rb, Sc, Th, Ti, U, Y) sources, respectively. Positive matrix factorization was used together with concentration weighted air-mass back trajectories to better define element sources and their locations. Our analysis, based on events exhibiting the 10% highest PM2.5 contributions for each source category, identifies coal-fired power stations concentrated in the U.S. Ohio Valley, metal smelting in eastern Canada, and marine and crustal sources showing surprisingly similar back trajectories, at times each sampling Atlantic coastal airsheds. This pattern is consistent with contribution of Saharan dust by a summer maximum at the latitude of Florida and northward transport up the Atlantic Coast by clockwise circulation of the summer Bermuda High. Results for mercury speciation show diurnal production of RGM by photochemical oxidation of Hg° in a marine environment, and periodic traverse of the study area by correlated RGM-SO2(NOx) plumes, indicative of coal combustion sources.

  15. Harmful impact of air pollution on severe acute exacerbation of chronic obstructive pulmonary disease: particulate matter is hazardous.

    PubMed

    Choi, Juwhan; Oh, Jee Youn; Lee, Young Seok; Min, Kyung Hoon; Hur, Gyu Young; Lee, Sung Yong; Kang, Kyung Ho; Shim, Jae Jeong

    2018-01-01

    Particulate matter and air pollution in Korea are becoming worse. There is a lack of research regarding the impact of particulate matter on patients with COPD. Therefore, the purpose of this study was to investigate the effects of various air pollution factors, including particulate matter, on the incidence rate of severe acute exacerbations of COPD (AECOPD) events. We analyzed the relationship between air pollutants and AECOPD events that required hospitalization at Guro Hospital in Korea from January 1, 2015 to May 31, 2017. We used general linear models with Poisson distribution and log-transformation to obtain adjusted relative risk (RR). We conducted further analysis through the Comprehensive Air-quality Index (CAI) that is used in Korea. Among various other air pollutants, particulate matter was identified as a major source of air pollution in Korea. When the CAI score was over 50, the incidence rate of severe AECOPD events was statistically significantly higher [RR 1.612, 95% CI, 1.065-2.440, P =0.024]. Additionally, the particulate matter levels 3 days before hospitalization were statistically significant [RR 1.003, 95% CI, 1.001-1.005, P =0.006]. Particulate matter and air pollution increase the incidence rate of severe AECOPD events. COPD patients should be cautioned against outdoor activities when particulate matter levels are high.

  16. Noise Pollution and How it Can Indirectly Affect the Amounts of Particulate Matter in the Environment

    NASA Astrophysics Data System (ADS)

    Swamy, S.; Power, J.; Pham, D.; Preston, K. B.; Iqbal, A.

    2007-12-01

    Human and animal activity that occurs on gravel and dirt roads tends to contribute to high levels of particulate matter in the atmosphere. Birds molt their feathers, automobiles emit unused residues, and humans and animals stir up debris on the ground. Not only do these activities generate particulate matter, but they also generate noise. The aim of our study was to determine if a direct correlation exists between the amount of particulate matter and the noise levels in select areas within the Lake Merritt Park region of downtown Oakland, California. In addition, our research was aimed at determining if the level of noise at various locations conforms to City of Oakland regulations. Over a four-week period we measured noise levels and particulate matter concentrations at 27 different sites within the Park region. Preliminary results indicate that at a construction site and a residential area near the lake a direct correlation between our two variables existed; high noise level accompanied high particulate matter while low noise level accompanied low particulate matter, respectively. However, at the majority of the areas around the lake either indirect or no correlation was observed. Based on our results thus far, we conclude that noise levels are not indicative of particulate matter levels and that noise levels around Lake Merritt do conform to the city's regulations.

  17. Distribution patterns of particulate trace metals in the water column and nepheloid layer of the Gulf of Riga.

    PubMed

    Poikāne, Rita; Carstensen, Jacob; Dahllöf, Ingela; Aigars, Juris

    2005-07-01

    The dynamics (fate) of trace metals in suspended particulate matter within the Gulf of Riga has not yet been adequately addressed in the scientific literature. Therefore, during a two year period (2001-2002) samples of suspended particulate matter and surface sediments for trace metal analysis were collected in the Gulf of Riga and the Daugava river, and these data were combined with background information from the national marine monitoring program in Latvia. This paper presents a descriptive study of solid phase trace metals (aluminium, iron, cadmium, chromium, copper, manganese, nickel, lead and zinc) dynamics and their spatial distribution within the Gulf of Riga based on Principal Component Analysis and Cluster analysis. Fluvial particulate matter and particulate Al, Fe, Cr and Ni were brought into the Gulf of Riga mainly during spring flood and thereafter quickly diluted by the water masses of the Gulf of Riga. Fine-grained suspended material and particulate Al and Fe were well mixed and evenly distributed through all deepwater basins of the Gulf of Riga. The increase of particulate Mn below the thermocline in August and a strong negative correlation with dissolved oxygen concentrations suggested that particulate Mn in the water column and the sediments were regulated mainly by changing oxic-anoxic conditions in the sediments of the Gulf of Riga. The observed correlation between Al and Fe in the water column is in contrast to that observed in the nepheloid layer where Fe correlated with Mn, obviously due to fast diagenetic processes on sediment surface. The observed negative correlation of Cd and Zn with total carbon and total nitrogen in the nepheloid layer might indicate different sedimentation mechanisms of these elements, however, this assumption is still inconclusive.

  18. Source apportionment of speciated PM2.5 and non-parametric regressions of PM2.5 and PM(coarse) mass concentrations from Denver and Greeley, Colorado, and construction and evaluation of dichotomous filter samplers

    NASA Astrophysics Data System (ADS)

    Piedrahita, Ricardo A.

    The Denver Aerosol Sources and Health study (DASH) was a long-term study of the relationship between the variability in fine particulate mass and chemical constituents (PM2.5, particulate matter less than 2.5mum) and adverse health effects such as cardio-respiratory illnesses and mortality. Daily filter samples were chemically analyzed for multiple species. We present findings based on 2.8 years of DASH data, from 2003 to 2005. Multilinear Engine 2 (ME-2), a receptor-based source apportionment model was applied to the data to estimate source contributions to PM2.5 mass concentrations. This study relied on two different ME-2 models: (1) a 2-way model that closely reflects PMF-2; and (2) an enhanced model with meteorological data that used additional temporal and meteorological factors. The Coarse Rural Urban Sources and Health study (CRUSH) is a long-term study of the relationship between the variability in coarse particulate mass (PMcoarse, particulate matter between 2.5 and 10mum) and adverse health effects such as cardio-respiratory illnesses, pre-term births, and mortality. Hourly mass concentrations of PMcoarse and fine particulate matter (PM2.5) are measured using tapered element oscillating microbalances (TEOMs) with Filter Dynamics Measurement Systems (FDMS), at two rural and two urban sites. We present findings based on nine months of mass concentration data, including temporal trends, and non-parametric regressions (NPR) results, which were used to characterize the wind speed and wind direction relationships that might point to sources. As part of CRUSH, 1-year coarse and fine mode particulate matter filter sampling network, will allow us to characterize the chemical composition of the particulate matter collected and perform spatial comparisons. This work describes the construction and validation testing of four dichotomous filter samplers for this purpose. The use of dichotomous splitters with an approximate 2.5mum cut point, coupled with a 10mum cut diameter inlet head allows us to collect the separated size fractions that the collocated TEOMs collect continuously. Chemical analysis of the filters will include inorganic ions, organic compounds, EC, OC, and biological analyses. Side by side testing showed the cut diameters were in agreement with each other, and with a well characterized virtual impactor lent to the group by the University of Southern California. Error propagation was performed and uncertainty results were similar to the observed standard deviations.

  19. Personal exposure assessment to particulate metals using a paper-based analytical device

    NASA Astrophysics Data System (ADS)

    Cate, David; Volckens, John; Henry, Charles

    2013-03-01

    The development of a paper-based analytical device (PAD) for assessing personal exposure to particulate metals will be presented. Human exposure to metal aerosols, such as those that occur in the mining, construction, and manufacturing industries, has a significant impact on the health of our workforce, costing an estimated $10B in the U.S and causing approximately 425,000 premature deaths world-wide each year. Occupational exposure to particulate metals affects millions of individuals in manufacturing, construction (welding, cutting, blasting), and transportation (combustion, utility maintenance, and repair services) industries. Despite these effects, individual workers are rarely assessed for their exposure to particulate metals, due mainly to the high cost and effort associated with personal exposure measurement. Current exposure assessment methods for particulate metals call for an 8-hour filter sample, after which time, the filter sample is transported to a laboratory and analyzed by inductively-coupled plasma (ICP). The time from sample collection to reporting is typically weeks and costs several hundred dollars per sample. To exacerbate the issue, method detection limits suffer because of sample dilution during digestion. The lack of sensitivity hampers task-based exposure assessment, for which sampling times may be tens of minutes. To address these problems, and as a first step towards using microfluidics for personal exposure assessment, we have developed PADs for measurement of Pb, Cd, Cr, Fe, Ni, and Cu in aerosolized particulate matter.

  20. FIELD EVALUATION OF A SAMPLING APPROACH FOR PM-COARSE AEROSOLS

    EPA Science Inventory

    Subsequent to a 1997 revision of the national ambient air quality standards (NAAQS) for particulate matter (PM), the US Environmental Protection Agency is investigating the development of sampling methodology for a possible new coarse particle standard. When developed, this me...

  1. MODELING ENVIRONMENTAL EXPOSURES TO PARTICULATE MATTER AND PESTICIDES

    EPA Science Inventory

    This presentation describes initial results from on-going research at EPA on modeling human exposures to particulate matter and residential pesticides. A first generation probabilistic population exposure model for Particulate Matter (PM), specifically for predicting PM1o and P...

  2. Distribution and geochemical composition of suspended particulate material in the shallow embayment of northern Thermaikos Gulf, Greece

    NASA Astrophysics Data System (ADS)

    Tsompanoglou, K.; Anagnostou, Ch.; Krasakopoulou, E.; Pagou, K.; Karageorgis, A. P.; Pavlidou, A.; Albanakis, K.; Tsirambides, A.

    2017-07-01

    The distribution and the chemical composition of Suspended Particulate Matter (SPM), in the northern Thermaikos Gulf, were studied during an annual experiment, carried out from June 2004 to June 2005. Water samples were collected at three depths (1 m below surface, 10 m depth, and 2 m above bottom) and filtered to obtain SPM, particulate organic carbon (POC), total particulate nitrogen (PNtot) and particulate phosphorus (PP) concentrations. SPM and POC concentrations exhibited strong spatial and temporal variations, related to the different environmental characteristics in the study area such as river network, biological productivity, anthropogenic interferences, wind regime, and resuspension of the bottom sediments. The highest SPM concentrations were recorded at the surface (mean = 1.45 ± 0.75 mg/l, maximum value = 11.60 mg/l) and close to the bottom (mean = 1.49 ± 0.67 mg/l, maximum value = 11.72 mg/l), creating surface and bottom nepheloid layers (SNL and BNL), respectively. The maximum values were recorded close to the river mouths; the rivers are identified as the major sources of SPM. The Axios and Aliakmon rivers supplied the gulf with particulate matter, during the entire sampling period. Chemical analysis has revealed the significant correlation among the elements Al, Si, Fe, Ti, K, V, Mg and Ba suggesting the presence of terrigenous aluminosilicate minerals. Silica and Ca have terrigenous origin, but also come from autochthonous biogenic fraction. Chromium, Ni and Co, are of natural origin and derived from mafic and ultramafic rocks of the Axios and Aliakmon watersheds. Copper and Zn are correlated with each other and their distributions follow that of POC; these two metals are derived from partially treated domestic and industrial effluents. The vertical distribution of organic matter implies increased primary production within the upper layer of the water column. Phosphorus is present mainly in an organic form. During the sampling period, the water column was well-oxygenated. Early diagenesis only affected the concentrations of Mn and to a lesser extent Fe in the recently deposited seabed sediment.

  3. Particulate organic matter predicts bacterial productivity in a river dominated estuary

    NASA Astrophysics Data System (ADS)

    Crump, B. C.

    2015-12-01

    Estuaries act as coastal filters for organic and inorganic fluvial materials in which microbial, biogeochemical, and ecological processes combine to transform organic matter and nutrients prior to export to the coastal ocean. The function of this estuarine 'bioreactor' is linked to the residence times of those materials and to rates of microbial heterotrophic activity. Our ability to forecast the impact of global change on estuarine bioreactor function requires an understanding of the basic controls on microbial community activity and diversity. In the Columbia River estuary, the microbial community undergoes a dramatic seasonal shift in species composition during which a spring bacterioplankton community, dominated by Flavobacteriaceae and Oceanospirillales, is replaced by a summer community, dominated by Rhodobacteraceae and several common marine taxa. This annual shift occurs in July, following the spring freshet, when river flow and river chlorophyll concentration decrease and when estuarine water residence time increases. Analysis of a large dataset from 17 research cruises (1990-2014) showed that the composition of particulate organic matter in the estuary changes after the freshet with decreasing organic carbon and nitrogen content, and increasing contribution of marine and autochthonous estuarine organic matter (based on PO13C and pigment ratios). Bacterial production rates (measured as leucine or thymidine incorporation rates) in the estuary respond to this change, and correlate strongly with labile particulate nitrogen concentration and temperature during individual sampling campaigns, and with the concentration of chlorophyll in the Columbia River across all seasons. Regression models suggest that the concentration of labile particulate nitrogen and the rate of bacterial production can be predicted from sensor measurements of turbidity, salinity, and temperature in the estuary and chlorophyll in the river. These results suggest that the quality of particulate organic matter supplied by the river influences the composition of estuarine bacterial communities and the degree to which the Columbia River estuary functions as a bioreactor for fluvial particulate material.

  4. [Exploration of a quantitative methodology to characterize the retention of PM2.5 and other atmospheric particulate matter by plant leaves: taking Populus tomentosa as an example].

    PubMed

    Zhang, Zhi-Dan; Xi, Ben-Ye; Cao, Zhi-Guo; Jia, Li-Ming

    2014-08-01

    Taking Populus tomentosa as an example, a methodology called elution-weighing-particle size-analysis (EWPA) was proposed to evaluate quantitatively the ability of retaining fine particulate matter (PM2.5, diameter d ≤ 2.5 μm) and atmospheric particulate matter by plant leaves using laser particle size analyzer and balance. This method achieved a direct, accurate measurement with superior operability about the quality and particle size distribution of atmospheric particulate matter retained by plant leaves. First, a pre-experiment was taken to test the stability of the method. After cleaning, centrifugation and drying, the particulate matter was collected and weighed, and then its particle size distribution was analyzed by laser particle size analyzer. Finally, the mass of particulate matter retained by unit area of leaf and stand was translated from the leaf area and leaf area index. This method was applied to a P. tomentosa stand which had not experienced rain for 27 days in Beijing Olympic Forest Park. The results showed that the average particle size of the atmospheric particulate matter retained by P. tomentosa was 17.8 μm, and the volume percentages of the retained PM2.5, inhalable particulate matter (PM10, d ≤ 10 μm) and total suspended particle (TSP, d ≤ 100 μm) were 13.7%, 47.2%, and 99.9%, respectively. The masses of PM2.5, PM10, TSP and total particulate matter were 8.88 x 10(-6), 30.6 x 10(-6), 64.7 x 10(-6) and 64.8 x 10(-6) g x cm(-2) respectively. The retention quantities of PM2.5, PM10, TSP and total particulate matter by the P. tomentosa stand were 0.963, 3.32, 7.01 and 7.02 kg x hm(-2), respectively.

  5. Impact of fugitive sources and meteorological parameters on vertical distribution of particulate matter over the industrial agglomeration.

    PubMed

    Štrbová, Kristína; Raclavská, Helena; Bílek, Jiří

    2017-12-01

    The aim of the study was to characterize vertical distribution of particulate matter, in an area well known by highest air pollution levels in Europe. A balloon filled with helium with measuring instrumentation was used for vertical observation of air pollution over the fugitive sources in Moravian-Silesian metropolitan area during spring and summer. Synchronously, selected meteorological parameters were recorded together with particulate matter for exploration its relationship with particulate matter. Concentrations of particulate matter in the vertical profile were significantly higher in the spring than in the summer. Significant effect of fugitive sources was observed up to the altitude ∼255 m (∼45 m above ground) in both seasons. The presence of inversion layer was observed at the altitude ∼350 m (120-135 m above ground) at locations with major source traffic load. Both particulate matter concentrations and number of particles for the selected particle sizes decreased with increasing height. Strong correlation of particulate matter with meteorological parameters was not observed. The study represents the first attempt to assess the vertical profile over the fugitive emission sources - old environmental burdens in industrial region. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Estimation of particulate matter from simulation and measurements

    NASA Astrophysics Data System (ADS)

    Nakata, Makiko; Nakano, Tomio; Okuhara, Takaaki; Sano, Itaru; Mukai, Sonoyo

    2011-11-01

    The particulate matter is a typical indicator of small particles in the atmosphere. In addition to providing impacts on climate and environment, these small particles can bring adverse effects on human health. Then an accurate estimation of particulate matter is an urgent subject. We set up SPM sampler attached to our AERONET (Aerosol Robotics Network) station in urban city of Higashi-Osaka in Japan. The SPM sampler provides particle information about the concentrations of various SPMs (e.g., PM10 and PM2.5) separately. The AEROENT program is world wide ground based sunphotometric observation networks by NASA and provides the spectral information about aerosol optical thickness (AOT) and Angstrom exponent (α). Simultaneous measurements show that a linear correlation definitely exists between AOT and PM2.5. These results indicate that particulate matter can be estimated from AOT. However AOT represents integrated values of column aerosol amount retrieved from optical property, while particulate matter concentration presents in-situ aerosol loading on the surface. Then simple way using linear correlation brings the discrepancy between observed and estimated particulate matter. In this work, we use cluster information about aerosol type to reduce the discrepancy. Our improved method will be useful for retrieving particulate matter from satellite measurements.

  7. Approximation of personal exposure to fine particulate matters (PM2.5) during cooking using solid biomass fuels in the kitchens of rural West Bengal, India.

    PubMed

    Nayek, Sukanta; Padhy, Pratap Kumar

    2018-06-01

    More than 85% of the rural Indian households use traditional solid biofuels (SBFs) for daily cooking. Burning of the easily available unprocessed solid fuels in inefficient earthen cooking stoves produce large quantities of particulate matters. Smaller particulates, especially with aerodynamic diameter of 2.5 μm or less (PM 2.5 ), largely generated during cooking, are considered to be health damaging in nature. In the present study, kitchen level exposure of women cooks to fine particulate matters during lunch preparation was assessed considering kitchen openness as surrogate to the ventilation condition. Two-way ANCOVA analysis considering meal quantity as a covariate revealed no significant interaction between the openness and the seasons explaining the variability of the personal exposure to the fine particulate matters in rural kitchen during cooking. Multiple linear regression analysis revealed the openness as the only significant predictor for personal exposure to the fine particulate matters. In the present study, the annual average fine particulate matter exposure concentration was found to be 974 μg m -3 .

  8. Measurement and analysis of ambient atmospheric particulate matter in urban and remote environments

    NASA Astrophysics Data System (ADS)

    Hagler, Gayle S. W.

    Atmospheric particulate matter pollution is a challenging environmental concern in both urban and remote locations worldwide. It is intrinsically difficult to control, given numerous anthropogenic and natural sources (e.g. fossil fuel combustion, biomass burning, dust, and seaspray) and atmospheric transport up to thousands of kilometers after production. In urban regions, fine particulate matter (particles with diameters under 2.5 mum) is of special concern for its ability to penetrate the human respiratory system and threaten cardiopulmonary health. A second major impact area is climate, with particulate matter altering Earth's radiative balance through scattering and absorbing solar radiation, modifying cloud properties, and reducing surface reflectivity after deposition in snow-covered regions. While atmospheric particulate matter has been generally well-characterized in populated areas of developed countries, particulate pollution in developing nations and remote regions is relatively unexplored. This thesis characterizes atmospheric particulate matter in locations that represent the extreme ends of the spectrum in terms of air pollution-the rapidly-developing and heavily populated Pearl River Delta Region of China, the pristine and climate-sensitive Greenland Ice Sheet, and a remote site in the Colorado Rocky Mountains. In China, fine particles were studied through a year-long field campaign at seven sites surrounding the Pearl River Delta. Fine particulate matter was analyzed for chemical composition, regional variation, and meteorological impacts. On the Greenland Ice Sheet and in the Colorado Rocky Mountains, the carbonaceous fraction (organic and elemental carbon) of particulate matter was studied in the atmosphere and snow pack. Analyses included quantifying particulate chemical and optical properties, assessing atmospheric transport, and evaluating post-depositional processing of carbonaceous species in snow.

  9. STATUS AND PROGRESS IN PARTICULATE MATTER FORECASTING: INITIAL APPLICATION OF THE ETA- CMAQ FORECAST MODEL

    EPA Science Inventory

    This presentation reviews the status and progress in forecasting particulate matter distributions. The shortcomings in representation of particulate matter formation in current atmospheric chemistry/transport models are presented based on analyses and detailed comparisons with me...

  10. CHARACTERIZATION OF PARTICULATE MATTER FROM PHOENIX, ARIZONA, USING RAY FLUORESCENCE AND COMPUTER-CONTROLLED SCANNING ELECTRON MICROSCOPY

    EPA Science Inventory

    Numerous epidemiological studies have found associations between airborne particulate matter measured at community monitors and increased mortality and morbidity. Chemical and physical characteristics of particulate matter (e.g., elemental composition, size) and source identifi...

  11. 40 CFR 52.2429 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.2429 Section 52.2429 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  12. 40 CFR 52.477 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.477 Section 52.477 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  13. 40 CFR 52.477 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.477 Section 52.477 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  14. 40 CFR 52.1081 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.1081 Section 52.1081 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Determination of Attainment. EPA has determined, as of January...

  15. 40 CFR 52.2429 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.2429 Section 52.2429 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  16. 40 CFR 52.1131 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.1131 Section 52.1131 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Revisions to the following regulations submitted on March 30...

  17. 40 CFR 52.1131 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.1131 Section 52.1131 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Revisions to the following regulations submitted on March 30...

  18. 40 CFR 52.477 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.477 Section 52.477 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  19. 40 CFR 52.1081 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.1081 Section 52.1081 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Determination of Attainment. EPA has determined, as of January...

  20. 40 CFR 52.2429 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.2429 Section 52.2429 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  1. 40 CFR 52.1131 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.1131 Section 52.1131 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Revisions to the following regulations submitted on March 30...

  2. 40 CFR 52.477 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.477 Section 52.477 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  3. 40 CFR 52.1081 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.1081 Section 52.1081 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Determination of Attainment. EPA has determined, as of January...

  4. 40 CFR 52.1081 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.1081 Section 52.1081 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Determination of Attainment. EPA has determined, as of January...

  5. 40 CFR 52.2429 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.2429 Section 52.2429 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  6. 40 CFR 52.1081 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.1081 Section 52.1081 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) Determination of Attainment. EPA has determined, as of January...

  7. 40 CFR 52.2429 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.2429 Section 52.2429 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  8. 40 CFR 52.477 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.477 Section 52.477 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. Determination of Attainment. EPA has determined, as of January 12...

  9. Damage of natural stone tablets exposed to exhaust gas under laboratory conditions

    NASA Astrophysics Data System (ADS)

    Farkas, Orsolya; Szabados, György; Török, Ákos

    2016-04-01

    Natural stone tablets were exposed to exhaust gas under laboratory conditions to assess urban stone damage. Cylindrical test specimens (3 cm in diameter) were made from travertine, non-porous limestone, porous limestone, rhyolite tuff, sandstone, andesite, granite and marble. The samples were exposed to exhaust gas that was generated from diesel engine combustion (engine type: RÁBA D10 UTSLL 160, EURO II). The operating condition of the internal combustion engine was: 1300 r/m (app 50%). The exhaust gas was diverted into a pipe system where the samples were placed perpendicular to main flow for 1, 2, 4, 8 and 10 hours, respectively. The exhaust emission was measured by using AVL particulate measurement technology; filter paper method (AVL 415). The stone samples were documented and selective parameters were measured prior to and after exhaust gas exposure. Density, volume, ultrasonic pulse velocity, mineral composition and penetration depth of emission related particulate matter were recorded. The first results indicate that after 10 hours of exposure significant amount of particulate matter deposited on the stone surface independently from the surface properties and porosity. The black soot particles uniformly covered all types of stones, making hard to differentiate the specimens.

  10. 40 CFR 60.282a - Standard for filterable particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... matter. 60.282a Section 60.282a Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... 23, 2013 § 60.282a Standard for filterable particulate matter. (a) On and after the date on which the... furnace any gases which: (i) Contain filterable particulate matter in excess of 0.10 gram per dry standard...

  11. A Comparison of Dissolved and Particulate Organic Material in Two Southwestern Desert River Systems

    NASA Astrophysics Data System (ADS)

    Haas, P. A.; Brooks, P.

    2001-12-01

    Desert river systems of the southwestern U.S. acquire a substantial fraction of their dissolved organic matter (DOM) from the terrestrial environment during episodic rain events. This DOM provides carbon for stream metabolism and nitrogen, which is limiting in lower order streams in this environment. The San Pedro and Rio Grande Rivers represent two endpoints of catchment scale, discharge, and land use in the southwest. The San Pedro is a protected riparian corridor (San Pedro Riparian National Conservation Area), while the middle Rio Grande is a large river with extensive agriculture, irrigation, and reservoirs. Relative abundance and spectral properties of fulvic acids isolated from filtered samples were used to determine the source of dissolved organic carbon (DOC). Total DOC and particulate organic carbon (POC) changes with respect to episodic flooding events were compared for the two river systems. The San Pedro River DOC concentrations remain low approximately 2.2 to 3.3 ppm unless a relatively large storm event occurs when concentrations may go above 5.5 ppm (1000cfs flow). In contrast typical concentrations for the Rio Grande were approximately 5 ppm during the monsoon season. Particulate organic matter (POM) appears to be a more significant source of organic matter to the San Pedro than DOM. The relative importance of terrestrial vs. aquatic and dissolved vs. particulate organic matter with respect to aquatic ecosystems will be discussed.

  12. Arsenic species in atmospheric particulate matter as tracer of the air quality of Doñana Natural Park (SW Spain).

    PubMed

    González-Castanedo, Y; Sanchez-Rodas, D; Sánchez de la Campa, A M; Pandolfi, M; Alastuey, A; Cachorro, V E; Querol, X; de la Rosa, J D

    2015-01-01

    Sampling and chemical analyses, including major compounds and trace elements, of atmospheric particulate matter (PM10 and PM2.5) have been performed during 2006-2007 in a regional background monitoring station located within the Doñana Natural Park (SW of Spain). This region is strategic for air quality and climate change studies, representing a meeting place of the European and African continents, and the Atlantic Ocean and Mediterranean Sea. The present study based on meteorological parameters demonstrated long-range transport and impact of industrial plumes on the Doñana Natural. Inorganic arsenic species (arsenate and arsenite) have been analyzed in particulate matter (PM) to characterize the impact of near Cu-smelter plumes and demonstrated the long-range transport of industrial pollutants. As(V) is the main specie of As and varies between 95% and 98% of total As in PM10 and 96-97% in PM2.5. The As(V)/As(III) ratio measured in emission plumes of a Cu-smelter are similar to the ratio found in the Doñana Natural Park. The application of Positive Matrix Factorization (PMF) to atmospheric particulate matter estimated the contributions and chemical profiles of natural and anthropogenic sources impacting the Natural Park, demonstrating the industrial origin of the As and other toxic elements in the air. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Fractal and spectroscopic analysis of soot from internal combustion engines

    NASA Astrophysics Data System (ADS)

    Swapna, M. S.; Saritha Devi, H. V.; Raj, Vimal; Sankararaman, S.

    2018-03-01

    Today diesel engines are used worldwide for various applications and very importantly in transportation. Hydrocarbons are the most widespread precursors among carbon sources employed in the production of carbon nanotubes (CNTs). The aging of internal combustion engine is an important parameter in deciding the carbon emission and particulate matter due to incomplete combustion of fuel. In the present work, an attempt has been made for the effective utilization of the aged engines for potential applicationapplications in fuel cells and nanoelectronics. To analyze the impact of aging, the particulate matter rich in carbon content areis collected from diesel engines of different ages. The soot with CNTs is purified by the liquid phase oxidation method and analyzed by Field Emission Scanning Electron Microscopy, High-Resolution Transmission Electron Microscopy, Energy Dispersive Spectroscopy, UV-Visible spectroscopy, Raman spectroscopy and Thermogravimetric analysis. The SEM image contains self-similar patterns probing fractal analysis. The fractal dimensions of the samples are determined by the box counting method. We could find a greater amount of single-walled carbon nanotubes (SWCNTs) in the particulate matter emitted by aged diesel engines and thereby giving information about the combustion efficiency of the engine. The SWCNT rich sample finds a wide range of applicationapplications in nanoelectronics and thereby pointing a potential use of these aged engines.

  14. [Methodical problems of monitoring of fine particulate matters in atmospheric air of residential areas].

    PubMed

    Karelin, A O; Lomtev, A Yu; Mozzhukhina, N A; Yeremin, G B; Nikonov, V A

    Inhalation of fine particulate matters (PM and PM ) poses a threat for the health of population. Purpose of the study the analysis of the monitoring of fine particulate matters in the atmospheric air of Saint-Petersburg and identification of the main problems of the monitoring. Research methods methods of scientific hypothetical deductive cognition, sanitary-statistical methods, general logical methods and approaches of researches: analysis, synthesis, abstracting, generalization, induction. Results. The article represents the analysis of the monitoring of fine particulate matters in the atmospheric air of Saint- Petersburg. Only 11 in automatic monitoring stations out of 22 there is carried out the control of fine particulate matters: in 7 - PM and PM, and in 4 - PM The average year concentrations were below MAC in all the stations. The maximum concentrations achieved 3 MAC, but the repeatance of cases of exceedence of concentrations more than MAC was very rare. On the average of the city concentrations of PM were decreased from 0,8 MAC in 2006 and 1,1 MAC in 2007 to 0,5 MAC in 2013-14. The executed analysis revealed main problems of the monitoring of fine particulate matters in the Russian Federation. They include the absence of the usage 1of the officially approved methods of controlling of PM and PM in the atmospheric air until March 1, 2016, lack of the modern equipment for measurement of fine particulate matters. Conclusions. Therefore, the state of the monitoring of fine particulate matters in the atmospheric air in the Russian Federation fails to be satisfactory. It is necessary to improve system of the monitoring, create modern Russian appliances, methods and means for measurement of fine particulate matters concentrations in the atmospheric air.

  15. Heavy metals in particulate and colloidal matter from atmospheric deposition of urban Guangzhou, South China.

    PubMed

    Huang, Wen; Duan, Dandan; Zhang, Yulong; Cheng, Hefa; Ran, Yong

    2014-08-30

    Suspended particulate matter (SPM) and colloidal matter (COM) in annual dry and wet deposition samples in urban Guangzhou were for the first time collected, and their trace metals were investigated by using inductively coupled plasma mass spectrometry (ICP-MS). The deposition flux of SPM and of metal elements varied largely among the investigated seasons, and reached the maximum in spring. The correlation analysis indicated that significant correlations existed among some of the metal elements in the deposition samples. The enrichment factors (EF) of metals in COM in the deposition ranging from 79.66 to 130,000 were much higher than those of SPM ranging from 1.65 to 286.48, indicating the important role of COM. The factor analysis showed that emissions from street dust, non-ferrous metal production, and heavy fuel oil were major sources of the trace metals. Positive matrix factorization (PMF) model was used to quantitatively estimate anthropogenic source. Copyright © 2013 Elsevier Ltd. All rights reserved.

  16. A Comprehensive Program for Measurement of Military Aircraft Emissions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cheng, Mengdawn

    2009-11-01

    Emissions of gases and particulate matter by military aircraft were characterized inplume by 'extractive' and 'optical remote-sensing (ORS)' technologies. Non-volatile particle size distribution, number and mass concentrations were measured with good precision and reproducibly. Time-integrated particulate filter samples were collected and analyzed for smoke number, elemental composition, carbon contents, and sulfate. Observed at EEP the geometric mean diameter (as measured by the mobility diameter) generally increased as the engine power setting increased, which is consistent with downstream observations. The modal diameters at the downstream locations are larger than that at EEP at the same engine power level. The results indicatemore » that engine particles were processed by condensation, for example, leading to particle growth in-plume. Elemental analysis indicated little metals were present in the exhaust, while most of the exhaust materials in the particulate phase were carbon and sulfate (in the JP-8 fuel). CO, CO{sub 2}, NO, NO{sub 2}, SO{sub 2}, HCHO, ethylene, acetylene, propylene, and alkanes were measured. The last five species were most noticeable under engine idle condition. The levels of hydrocarbons emitted at high engine power level were generally below the detection limits. ORS techniques yielded real-time gaseous measurement, but the same techniques could not be extended directly to ultrafine particles found in all engine exhausts. The results validated sampling methodology and measurement techniques used for non-volatile particulate aircraft emissions, which also highlighted the needs for further research on sampling and measurement for volatile particulate matter and semi-volatile species in the engine exhaust especially at the low engine power setting.« less

  17. Aerial sampling of emissions from biomass pile burns in Oregon

    EPA Science Inventory

    Emissions from burning piles of post-harvest timber slash in Grande Ronde, Oregon were sampled using an instrument platform lofted into the plume using a tether-controlled aerostat or balloon. Emissions of carbon monoxide, carbon dioxide, methane, particulate matter (PM2.5 µm), ...

  18. MULTI-SITE FIELD EVALUATION OF CANDIDATE SAMPLERS FOR MEASURING COARSE-MODE PM

    EPA Science Inventory

    In response to expected changes to the National Ambient Air Quality Standards for particulate matter, comprehensive field studies were conducted to evaluate the performance of sampling methods for measuring coarse mode aerosols (i.e. PMc). Five separate PMc sampling approaches w...

  19. Aerial Sampling of Emissions from Biomass Pile Burns in Oregon

    EPA Science Inventory

    Emissions from burning piles of post-harvest timber slash in Grande Ronde, Oregon were sampled using an instrument platform lofted into the plume using a tether-controlled aerostat or balloon. Emissions of carbon monoxide, carbon dioxide, methane, particulate matter (PM2.5 µm), ...

  20. 40 CFR 60.51b - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... gases, liquids, or solids through the heating of municipal solid waste, and the gases, liquids, or... diluent gas) for subsequent on-or off-site analysis; integrated sample(s) collected are representative of... arithmetic average flue gas temperature measured at the particulate matter control device inlet during four...

  1. 40 CFR 60.51b - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... gases, liquids, or solids through the heating of municipal solid waste, and the gases, liquids, or... diluent gas) for subsequent on-or off-site analysis; integrated sample(s) collected are representative of... arithmetic average flue gas temperature measured at the particulate matter control device inlet during four...

  2. 40 CFR 60.51b - Definitions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... gases, liquids, or solids through the heating of municipal solid waste, and the gases, liquids, or... diluent gas) for subsequent on-or off-site analysis; integrated sample(s) collected are representative of... arithmetic average flue gas temperature measured at the particulate matter control device inlet during four...

  3. FEDERAL REFERENCE AND EQUIVALENT METHODS FOR MEASURING FINE PARTICULATE MATTER

    EPA Science Inventory

    In the national ambient air quality standards specified by the U.S. Environmental Protection Agency in the Code of Federal Regulations, new standards were established for particulate matter on July 18, 1997. The new particulate matter standards specify mass concentration as the...

  4. The heart as an extravascular target of endothelin-1 in particulate matter-induced cardiac dysfunction

    EPA Science Inventory

    Exposure to particulate matter air pollution has been causally linked to cardiovascular disease in humans. Several broad and overlapping hypotheses describing the biological mechanisms by which particulate matter exposure leads to cardiovascular disease and cardiac dysfunction ha...

  5. Ambient particulate matter accelerates coagulation via an IL-6-dependent pathway

    EPA Science Inventory

    The mechanisms by which exposure to particulate matter increases the risk of cardiovascular events are not known. Recent human and animal data suggest that particulate matter may induce alterations in hemostatic factors. In this study we determined the mechanisms by which particu...

  6. EXPOSURE ASSESSMENT FROM THE NERL RESEARCH TRIANGLE PARK PARTICULATE MATTER PANEL STUDY

    EPA Science Inventory

    The U.S. Environmental Protection Agency performed a particulate matter (PM) exposure assessment based on data from the National Exposure Research Laboratory (NERL) Research Triangle Park (RTP) Particulate Matter (PM) Panel Study. This study was a one-year investigation of PM ...

  7. 40 CFR 52.2526 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.2526 Section 52.2526 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) EPA approves West Virginia's November 15, 1991 SIP submittal for...

  8. 40 CFR 52.1374 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.1374 Section 52.1374 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) On July 8, 1997, the Governor of Montana submitted minor...

  9. 40 CFR 52.1025 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.1025 Section 52.1025 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... strategy: Particulate matter. (a) The revisions to the control strategy resulting from the modification to...

  10. 40 CFR 52.1374 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.1374 Section 52.1374 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) On July 8, 1997, the Governor of Montana submitted minor...

  11. 40 CFR 52.1374 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.1374 Section 52.1374 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) On July 8, 1997, the Governor of Montana submitted minor...

  12. 40 CFR 52.1341 - Control strategy: particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: particulate matter. 52.1341 Section 52.1341 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: particulate matter. Determination of Attainment. EPA has determined, as of May 23, 2011...

  13. 40 CFR 52.2526 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.2526 Section 52.2526 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) EPA approves West Virginia's November 15, 1991 SIP submittal for...

  14. 40 CFR 52.1025 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.1025 Section 52.1025 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... strategy: Particulate matter. (a) The revisions to the control strategy resulting from the modification to...

  15. 40 CFR 52.2526 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.2526 Section 52.2526 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) EPA approves West Virginia's November 15, 1991 SIP submittal for...

  16. 40 CFR 52.2526 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.2526 Section 52.2526 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) EPA approves West Virginia's November 15, 1991 SIP submittal for...

  17. 40 CFR 52.1374 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.1374 Section 52.1374 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) On July 8, 1997, the Governor of Montana submitted minor...

  18. 40 CFR 52.1374 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.1374 Section 52.1374 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) On July 8, 1997, the Governor of Montana submitted minor...

  19. 40 CFR 52.1025 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.1025 Section 52.1025 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... strategy: Particulate matter. (a) The revisions to the control strategy resulting from the modification to...

  20. 40 CFR 52.1341 - Control strategy: particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: particulate matter. 52.1341 Section 52.1341 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: particulate matter. Determination of Attainment. EPA has determined, as of May 23, 2011...

  1. 40 CFR 52.1025 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.1025 Section 52.1025 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... strategy: Particulate matter. (a) The revisions to the control strategy resulting from the modification to...

  2. 40 CFR 52.2526 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.2526 Section 52.2526 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Control strategy: Particulate matter. (a) EPA approves West Virginia's November 15, 1991 SIP submittal for...

  3. Saharan dust particles in snow samples of Alps and Apennines during an exceptional event of transboundary air pollution.

    PubMed

    Telloli, Chiara; Chicca, Milvia; Pepi, Salvatore; Vaccaro, Carmela

    2017-12-21

    Southern European countries are often affected in summer by transboundary air pollution from Saharan dust. However, very few studies deal with Saharan dust pollution at high altitudes in winter. In Italy, the exceptional event occurred on February 19, 2014, colored in red the entire mountain range (Alps and Apennines) and allowed to characterize the particulate matter deposited on snow from a morphological and chemical point of view. Snow samples were collected after this event in four areas in the Alps and one in the Apennines. The particulate matter of the melted snow samples was analyzed by scanning electron microscopy with energy dispersive X-ray spectrometry (SEM-EDS) and by inductively coupled plasma mass spectrometry (ICP-MS). These analyses confirmed the presence of Saharan dust particle components in all areas with similar percentages, supported also by the positive correlations between Mg-Ca, Al-Ca, Al-Mg, and Al-K in all samples.

  4. Data on microscale atmospheric pollution of Bolshoy Kamen town (Primorsky region, Russia)

    NASA Astrophysics Data System (ADS)

    Kholodov, Aleksei; Ugay, Sergey; Drozd, Vladimir; Maiss, Natalia; Golokhvast, Kirill

    2017-10-01

    The paper discusses the study of atmospheric particulate matter of Bolshoy Kamen town by means of laser granulometry of snow water samples. Snow sampling points were selected close to major enterprises, along the main streets and roads of the town and in the residential area. The near-ground layer of atmospheric air of the town contains particulate matter of three main size classes: under 10 microns, 10-50 microns and over 700 microns. It is shown that the atmosphere of this town is lightly polluted with particles under 10 μm (PM10). Only in 5 sampling points out of 11 we found microparticles potentially hazardous to human health in significant quantities - from 16.2% to 34.6%. On the most territory of the town large particles (over 400 μm) dominate reaching 79.2%. We can conclude that judging by the particle size analysis of snow water samples Bolshoy Kamen town can be considered safe in terms of presence of particles under 10 μm (PM10) in the atmosphere.

  5. Speciation and Health Risks of Atmospheric Nanoparticulates

    NASA Astrophysics Data System (ADS)

    Nguyen, Kennedy

    Exposure to air pollution causes several adverse health effects such as asthma, respiratory disease, cardiovascular disease, cancer, and premature death; and the San Joaquin Valley is one of the most heavily polluted regions in the US. The mountains that surround the valley allow air pollution, including particulate matter, to remain stagnant, prolonging the exposure of valley populations to it. The primary sources of particulate matter for this region are aluminosilicate dust from agricultural activities, and soot emissions from diesel trucks and vehicular traffic. A substantial fraction of emitted material is nanoparticulate matter (<100 nm), which contains trace iron and polycyclic aromatic hydrocarbons that can traverse into human organs via the lungs, initiate inflammation, and lead to disease. The traditional approach of reducing the total mass of emitted material is beginning to reach its limit of effectiveness for mitigating the negative health impacts of particulate matter. There is a need for chemical speciation of particulate matter that will allow the identification of the chemical and physical properties of particulates by source, the creation of well-controlled proxy particles with those properties for testing in cell culture studies, and correlation of particulate properties and sources with their negative health impacts. These results can help identify the sources of air pollution to prioritize for mitigation for the greatest health benefit. In addition, further chemical speciation can help monitor the results of such mitigation efforts. Here, natural particulate matter samples from Merced and Fresno, two cities in the San Joaquin Valley, were analyzed. Ultrafine particles present were 40 to 50 nm in diameter and mostly composed of aluminum, silicon, oxygen, and iron hydroxide. XAS data confirmed the presence of the aluminosilicate as smectite clay and the iron hydroxide as ferrihydrite. Furthermore, a chemical speciation study investigated industrial emissions of air particulate matter. Samples were analyzed using electron microscopy for elemental composition and size distribution, and found to contain fine metal particulates (lead and iron) that can lead to lung inflammation. From characterization data, in order to create a simplified proxy particle system for cell culture studies, amorphous silica particles were synthesized using a modified Stober Synthesis and coated with iron hydroxide. A range of iron hydroxide concentrations (0.06 to 1.63 mmol of iron per gram of silica) were used to test the effect of iron contamination on THP-1 cells, and higher concentrations of iron with silica (0.43 and 1.63 mmol of iron per gram of silica) were found to increase production of pro-inflammatory mediators compared to silica alone. Iron alone did not induce an effect relative to the control, demonstrating a synergistic effect when iron is combined with silica at low doses. It was found that crystalline silica was more toxic than amorphous silica (70% vs 80% respectively at 100 mug/ml). In addition, mesoporous silica was found to be more toxic than solid silica (73% vs 82% respectively at 100 mug/ml), likely due to a higher surface area (60.2 m2/g for mesoporous external surface area without internal pores vs 1.72 m 2/g for solid 2 mum silica and 54.5 m2/g for 50 nm silica) and increased particle loading at the same dose. Finally, a preliminary investigation of Printex 90 as a proxy material for soot, with and without the addition of iron and quinones, was conducted.

  6. 30 CFR 57.5066 - Maintenance standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., Physical Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5066... manufacturer specifications; and (3) The operator must maintain any emission or particulate control device...

  7. 30 CFR 57.5066 - Maintenance standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., Physical Agents, and Diesel Particulate Matter Diesel Particulate Matter-Underground Only § 57.5066... manufacturer specifications; and (3) The operator must maintain any emission or particulate control device...

  8. Mass Fraction Spatiotemporal Geostatistics and its Application to Map Atmospheric Polycyclic Aromatic Hydrocarbons after 9/11

    EPA Science Inventory

    Extensive research has been conducted on effects resulting from exposure to ambient particulate matter. Particulate matter has been linked to cardiovascular diseases, respiratory problems, and reproductive effects. A large body of work on particulate matter focuses on atmospher...

  9. 40 CFR 60.2720 - May I conduct performance testing less often?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... least 3 years, and all performance tests for the pollutant (particulate matter, hydrogen chloride, or...) If your CISWI unit continues to meet the emission limitation for particulate matter, hydrogen... shows a deviation from an emission limitation for particulate matter, hydrogen chloride, or opacity, you...

  10. 40 CFR 52.427 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.427 Section 52.427 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...: Particulate matter. Determination of attainment. EPA has determined, as of May 16, 2012, that based on 2007 to...

  11. 40 CFR 52.332 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control strategy: Particulate matter. 52.332 Section 52.332 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...: Particulate matter. (a) On April 9, 1992, the Governor of Colorado submitted the moderate PM-10 nonattainment...

  12. 40 CFR 52.332 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control strategy: Particulate matter. 52.332 Section 52.332 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...: Particulate matter. (a) On April 9, 1992, the Governor of Colorado submitted the moderate PM-10 nonattainment...

  13. 40 CFR 52.332 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control strategy: Particulate matter. 52.332 Section 52.332 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...: Particulate matter. (a) On April 9, 1992, the Governor of Colorado submitted the moderate PM-10 nonattainment...

  14. 40 CFR 52.332 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control strategy: Particulate matter. 52.332 Section 52.332 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...: Particulate matter. (a) On April 9, 1992, the Governor of Colorado submitted the moderate PM-10 nonattainment...

  15. 77 FR 61276 - Approval and Promulgation of Implementation Plans; Mississippi; 110(a)(1) and (2) Infrastructure...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-09

    ... and 2006 Fine Particulate Matter National Ambient Air Quality Standards AGENCY: Environmental...-hour fine particulate matter (PM 2.5 ) national ambient air quality standards (NAAQS). Section 110(a..., Incorporation by reference, Intergovernmental relations, Nitrogen dioxide, Particulate matter, Reporting and...

  16. 40 CFR 52.332 - Control strategy: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: Particulate matter. 52.332 Section 52.332 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...: Particulate matter. (a) On April 9, 1992, the Governor of Colorado submitted the moderate PM-10 nonattainment...

  17. 40 CFR 52.2678 - Control strategy and regulations: Particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy and regulations: Particulate matter. 52.2678 Section 52.2678 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY....2678 Control strategy and regulations: Particulate matter. (a) The requirements of § 51.110(a) and...

  18. 77 FR 59755 - Approval and Promulgation of Implementation Plans; Alabama 110(a)(1) and (2) Infrastructure...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-10-01

    ... 2006 Fine Particulate Matter National Ambient Air Quality Standards AGENCY: Environmental Protection... 24-hour fine particulate matter (PM 2.5 ) national ambient air quality standards (NAAQS). Section 110..., Incorporation by reference, Intergovernmental relations, Nitrogen dioxide, Particulate matter, Reporting and...

  19. 40 CFR 52.2678 - Control strategy and regulations: Particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy and regulations: Particulate matter. 52.2678 Section 52.2678 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY....2678 Control strategy and regulations: Particulate matter. (a) The requirements of § 51.110(a) and...

  20. SUMMARY FINDINGS FROM THE U.S. EPA'S PARTICULATE MATTER PANEL STUDIES

    EPA Science Inventory

    The U.S. EPA's Particulate Matter Panel Studies were a series of longitudinal human exposure studies used to characterize personal exposures to particulate matter (PM) and related co-pollutants to that of pollutants of ambient origin. Participants were monitored over time (28 d...

  1. Aged Riverine Particulate Organic Carbon in Four UK Catchments

    NASA Astrophysics Data System (ADS)

    Adams, Jessica; Tipping, Edward; Bryant, Charlotte; Helliwell, Rachel; Toberman, Hannah; Quinton, John

    2016-04-01

    The riverine transport of particulate organic matter (POM) is a significant flux in the carbon cycle, and affects macronutrients and contaminants. We used radiocarbon to characterise POM at 9 riverine sites of four UK catchments (Avon, Conwy, Dee, Ribble) over a one-year period. High-discharge samples were collected on three or four occasions at each site. Suspended particulate matter (SPM) was obtained by centrifugation, and the samples were analysed for carbon isotopes. Concentrations of SPM and SPM organic carbon (OC) contents were also determined, and were found to have a significant negative correlation. For the 7 rivers draining predominantly rural catchments, PO14C values, expressed as percent modern carbon absolute (pMC), varied little among samplings at each site, and there was no significant difference in the average values among the sites. The overall average PO14C value for the 7 sites of 91.2 pMC corresponded to an average age of 680 14C years, but this value arises from the mixing of differently-aged components, and therefore significant amounts of organic matter older than the average value are present in the samples. Although topsoil erosion is probably the major source of the riverine POM, the average PO14C value is appreciably lower than topsoil values (which are typically 100 pMC). This is most likely explained by inputs of older subsoil OC from bank erosion, or the preferential loss of high-14C topsoil organic matter by mineralisation during riverine transport. The significantly lower average PO14C of samples from the River Calder (76.6 pMC), can be ascribed to components containing little or no radiocarbon, derived either from industrial sources or historical coal mining, and this effect is also seen in the River Ribble, downstream of its confluence with the Calder. At the global scale, the results significantly expand available information for PO14C in rivers draining catchments with low erosion rates.

  2. Particulate matter induces prothrombotic microparticle shedding by human mononuclear and endothelial cells.

    PubMed

    Neri, Tommaso; Pergoli, Laura; Petrini, Silvia; Gravendonk, Lotte; Balia, Cristina; Scalise, Valentina; Amoruso, Angela; Pedrinelli, Roberto; Paggiaro, Pierluigi; Bollati, Valentina; Celi, Alessandro

    2016-04-01

    Particulate airborne pollution is associated with increased cardiopulmonary morbidity. Microparticles are extracellular vesicles shed by cells upon activation or apoptosis involved in physiological processes such as coagulation and inflammation, including airway inflammation. We investigated the hypothesis that particulate matter causes the shedding of microparticles by human mononuclear and endothelial cells. Cells, isolated from the blood and the umbilical cords of normal donors, were cultured in the presence of particulate from a standard reference. Microparticles were assessed in the supernatant as phosphatidylserine concentration. Microparticle-associated tissue factor was assessed by an one-stage clotting assay. Nanosight technology was used to evaluate microparticle size distribution. Particulate matter induces a dose- and time- dependent, rapid (1h) increase in microparticle generation in both cells. These microparticles express functional tissue factor. Particulate matter increases intracellular calcium concentration and phospholipase C inhibition reduces microparticle generation. Nanosight analysis confirmed that upon exposure to particulate matter both cells express particles with a size range consistent with the definition of microparticles (50-1000 nm). Exposure of mononuclear and endothelial cells to particulate matter upregulates the generation of microparticles at least partially mediated by calcium mobilization. This observation might provide a further link between airborne pollution and cardiopulmonary morbidity. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Hyphenation of a carbon analyzer to photo-ionization mass spectrometry to unravel the organic composition of particulate matter on a molecular level.

    PubMed

    Grabowsky, Jana; Streibel, Thorsten; Sklorz, Martin; Chow, Judith C; Watson, John G; Mamakos, Athanasios; Zimmermann, Ralf

    2011-12-01

    The carbonaceous fraction of airborne particulate matter (PM) is of increasing interest due to the adverse health effects they are linked to. Its analytical ascertainment on a molecular level is still challenging. Hence, analysis of carbonaceous fractions is often carried out by determining bulk parameters such as the overall content of organic compounds (OC) and elemental carbon (EC) as well as the total carbon content, TC (sum of OC and EC), however, no information about the individual substances or substance classes, of which the single fractions consist can be obtained. In this work, a carbon analyzer and a photo-ionization time-of-flight mass spectrometer (PI-TOF-MS) were hyphenated to investigate individual compounds especially from the OC fractions. The carbon analyzer enables the stepwise heating of particle samples and provides the bulk parameters. With the PI-TOF-MS, it is possible to detect the organic compounds released during the single-temperature steps due to soft ionization and fast detection of the molecular ions. The hyphenation was designed, built up, characterized by standard substances, and applied to several kinds of samples, such as ambient aerosol, gasoline, and diesel emission as well as wood combustion emission samples. The ambient filter sample showed a strong impact of wood combustion markers. This was revealed by comparison to the product pattern of the similar analysis of pure cellulose and lignin and the wood combustion PM. At higher temperatures (450 °C), a shift to smaller molecules occurred due to the thermal decomposition of larger structures of oligomeric or polymeric nature comparable to lignocelluloses and similar oxygenated humic-like substances. Finally, particulate matter from gasoline and diesel containing 10% biodiesel vehicle exhaust has been analyzed. Gasoline-derived PM exhibited large polycyclic aromatic hydrocarbons, whereas diesel PM showed a much higher total organic content. The detected pattern revealed a strong influence of the biodiesel content on the nature of the particulate organic material.

  4. [Polycyclic aromatic hidrocarbons deposition in the Milazzo-Valle del Mela (Sicily Region, Southern Italy) high-risk area following an oil refinery fire].

    PubMed

    Grechi, Daniele; Biggeri, Annibale

    2016-01-01

    On September 2014, a fire began within an oil refinery involving a storage tank containing several hundreds of thousands cubic meters of virgin naphtha. Mayors of neighbouring municipalities asked the Epidemiology and Prevention Society "Giulio A. Maccacaro" to carry out an environmental survey in order to evaluate what was the nature and how dangerous was suspended dust deposited by the fumes. In the following days, after fire had been extinguished we conducted a sample survey on the presence of polycyclic aromatic hydrocarbons (PAH) and metals in particulate deposited on the soil on a radius of five kilometres from the refinery and we engaged the exposed population. The Milazzo-Valle del Mela (Sicily Region, Southern Italy) high-risk area includes several industrial plants; among them, an oil refinery and a fuel powered energy plant. As reference area we selected the Sarroch municipality (Sardinia Region, Southern Italy), in the coast of the Tyrrhenian Sea, which is geographically comparable, where a large oil refinery is located and where an environmental campaign with measurement of PAH and metals in particulate matter was ongoing. Qualitatively, metal composition of particulate matter resulted similar in the Sarroch and Milazzo samples. Instead, a large excess of PAH was documented in the Milazzo samples as compared to the Sarroch ones. In conclusion, the results of the analysis of the samples of particulate matter deposited in the Milazzo area in the days immediately following the oil refinery fire showed a high quantity of PAH, carcinogenic substances which pose major hazard to population health. The greater fall-out was registered in the proximity of the burnt storage tank and the West neighbourhood, and at lesser extent in the Southern neighbourhood. As a consequence, there was a population exposure to carcinogenic substances which could have reached the food chain.

  5. Characterization of the Particulate Emissions from the BP ...

    EPA Pesticide Factsheets

    Opportunistic particle samples were gathered from the sail of a tethered aerostat during at-sea plume sampling of the purposely-burned surface oil during the BP Deepwater Horizon disaster in the Gulf of Mexico. Particles were analyzed for polycyclic aromatic hydrocarbons (PAHs), organic carbon (OC), elemental carbon (EC), metals, and polychlorinated dibenzodioxins/dibenzofurans (PCDDs/PCDFs). Emission factors were calculated using previous sampling values of background-adjusted CO2 and particulate matter (PM)-bound C. The mean of five thermal-optical analyses indicated that the burned crude oil particulate matter was 93% carbon (w/w) with the predominance being refractory elemental carbon (82% w/w) on average. PAHs accounted for roughly 60 ug/g of the PM mass or 4.5 mg/kg oil burned, at least an order of magnitude less than earlier laboratory based studies. Microscopy indicates that the soot from the in situ oil burns is distinct from more common soot by its aggregate size, primary particle size, and nanostructure within the primary particles. The PCDD/PCDF concentration of the PM was 1.5 to 3.3 ng toxic equivalency (TEQ)/kg PM sampled, about 10-fold lower than from a previous dedicated gas/solid sample, indicating loss of small particle-bound and more volatile PCDD/PCDF congeners through the aerostat sail. This work presents an analysis of smoke particles opportunistically caught during the in situ surface oil burns during the 2010 BP Deepwater Horizon di

  6. 40 CFR Table 7 to Subpart Ddddd of... - Establishing Operating Limits

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    .... Particulate matter, mercury, or total selected metals a. Wet scrubber operating parameters i. Establish a site... drop and liquid flow rate monitors and the particulate matter, mercury, or total selected metals... from the pressure drop and liquid flow rate monitors and the particulate matter, mercury, or total...

  7. SENSITIVITY ANALYSIS AND EVALUATION OF MICROFACPM: A MICROSCALE MOTOR VEHICLE EMISSION FACTOR MODEL FOR PARTICULATE MATTER EMISSIONS

    EPA Science Inventory

    A microscale emission factor model (MicroFacPM) for predicting real-time site-specific motor vehicle particulate matter emissions was presented in the companion paper entitled "Development of a Microscale Emission Factor Model for Particulate Matter (MicroFacPM) for Predicting Re...

  8. 40 CFR 52.275 - Particulate matter control.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Particulate matter control. 52.275 Section 52.275 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.275 Particulate matter control. (a) The following rules or portions of rules...

  9. 40 CFR 52.275 - Particulate matter control.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Particulate matter control. 52.275 Section 52.275 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.275 Particulate matter control. (a) The following rules or portions of rules...

  10. 40 CFR 52.275 - Particulate matter control.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Particulate matter control. 52.275 Section 52.275 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.275 Particulate matter control. (a) The following rules or portions of rules...

  11. 40 CFR 52.275 - Particulate matter control.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Particulate matter control. 52.275 Section 52.275 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS California § 52.275 Particulate matter control. (a) The following rules or portions of rules...

  12. Evaluating the effectiveness of vegetative environmental buffers in mitigating particulate matter emissions from poultry houses

    USDA-ARS?s Scientific Manuscript database

    Particulate Matter (PM) emissions from animal operations have been identified as a major air pollutant source with health and environmental impacts. Nearly 600 million broilers are produced annually on the Delmarva Peninsula, making it a hot spot for particulate matter emissions from poultry houses....

  13. 40 CFR 60.472 - Standards for particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Asphalt Processing and Asphalt Roofing Manufacture § 60.472 Standards for particulate matter. (a) On and after the...) Particulate matter in excess of: (i) 0.04 kg/Mg (0.08 lb/ton) of asphalt shingle or mineral-surfaced roll...

  14. 40 CFR 60.43b - Standard for particulate matter (PM).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter (PM). 60.43b Section 60.43b Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Industrial-Commercial-Institutional Steam Generating Units § 60.43b Standard for particulate matter (PM). (a...

  15. 78 FR 20793 - Approval and Promulgation of Implementation Plans; Mississippi; 110(a)(2)(E)(ii) Infrastructure...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-08

    ... and 2006 Fine Particulate Matter National Ambient Air Quality Standards AGENCY: Environmental...) requirements for the 1997 annual and 2006 24-hour fine particulate matter (PM 2.5 ) National Ambient Air..., Incorporation by reference, Nitrogen dioxide, Particulate Matter, Reporting and recordkeeping requirements...

  16. 75 FR 16459 - Draft Document Related to the Review of the National Ambient Air Quality Standards for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-04-01

    ... Review of the National Ambient Air Quality Standards for Particulate Matter AGENCY: Environmental... Review of the Particulate Matter National Ambient Air Quality Standards--First External Review Draft (75... Particulate Matter National Ambient Air Quality Standards--First External Review Draft (March 2010), please...

  17. 40 CFR 52.634 - Particulate matter (PM-10) Group III SIP.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Particulate matter (PM-10) Group III SIP. 52.634 Section 52.634 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Hawaii § 52.634 Particulate matter...

  18. 40 CFR 52.146 - Particulate matter (PM-10) Group II SIP commitments.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Particulate matter (PM-10) Group II SIP commitments. 52.146 Section 52.146 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Arizona § 52.146 Particulate matter...

  19. 40 CFR 60.43c - Standard for particulate matter (PM).

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for particulate matter (PM). 60.43c Section 60.43c Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Industrial-Commercial-Institutional Steam Generating Units § 60.43c Standard for particulate matter (PM). (a...

  20. GENETIC INFLUENCES ON IN VTIRO PARTICULATE MATTER-INDUCED AIRWAY EPITHELIAL INJURY AND INFLAMMATORY MEDIATOR RELEASE

    EPA Science Inventory

    GENETIC INFLUENCES ON IN VITRO PARTICULATE MATTER-INDUCED AIRWAY EPITHELIAL INJURY AND INFLAMMATORY MEDIATOR RELEASE.
    JA Dye, JH Richards, DA Andrews, UP Kodavanti. US EPA, RTP, NC, USA.

    Particulate matter (PM) air pollution is capable of damaging the airway epitheli...

  1. PREFACE TO SPECIAL SECTION ON PARTICULATE MATTER: ATMOSPHERIC SCIENCES, EXPOSURE, AND THE FOURTH COLLOQUIUM ON PARTICULATE MATTER AND HUMAN HEALTH

    EPA Science Inventory

    In response to epidemiological studies published over twenty years ago, at least three research communities have been intensively studying airborne particulate matter (PM). These efforts have been coordinated by approaching the source - atmospheric accumulation/receptor - exposu...

  2. 40 CFR 52.2231 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2231 Section 52.2231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 52.2231 Control strategy: Sulfur oxides and particulate matter. (a) Part D conditional approval. The...

  3. 40 CFR 52.1278 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1278 Section 52.1278 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...) Mississippi § 52.1278 Control strategy: Sulfur oxides and particulate matter. In a letter dated January 30...

  4. 40 CFR 52.2231 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2231 Section 52.2231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 52.2231 Control strategy: Sulfur oxides and particulate matter. (a) Part D conditional approval. The...

  5. 40 CFR 52.2231 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2231 Section 52.2231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 52.2231 Control strategy: Sulfur oxides and particulate matter. (a) Part D conditional approval. The...

  6. 40 CFR 52.2130 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2130 Section 52.2130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.2130 Control strategy: Sulfur oxides and particulate matter. In letters dated May 7, and...

  7. 40 CFR 52.1278 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1278 Section 52.1278 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...) Mississippi § 52.1278 Control strategy: Sulfur oxides and particulate matter. In a letter dated January 30...

  8. 40 CFR 52.1278 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 4 2013-07-01 2013-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1278 Section 52.1278 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...) Mississippi § 52.1278 Control strategy: Sulfur oxides and particulate matter. (a) In a letter dated January 30...

  9. 40 CFR 52.2231 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 5 2013-07-01 2013-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2231 Section 52.2231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 52.2231 Control strategy: Sulfur oxides and particulate matter. (a) Part D conditional approval. The...

  10. 40 CFR 52.2130 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2130 Section 52.2130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.2130 Control strategy: Sulfur oxides and particulate matter. In letters dated May 7, and...

  11. 40 CFR 52.933 - Control Strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 3 2011-07-01 2011-07-01 false Control Strategy: Sulfur oxides and particulate matter. 52.933 Section 52.933 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Strategy: Sulfur oxides and particulate matter. (a) In a letter dated March 27, 1987, the Kentucky...

  12. 40 CFR 89.112 - Oxides of nitrogen, carbon monoxide, hydrocarbon, and particulate matter exhaust emission standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ..., hydrocarbon, and particulate matter exhaust emission standards. 89.112 Section 89.112 Protection of....112 Oxides of nitrogen, carbon monoxide, hydrocarbon, and particulate matter exhaust emission... emissions of oxides of nitrogen, carbon monoxide, hydrocarbon, and nonmethane hydrocarbon are measured using...

  13. 40 CFR 89.112 - Oxides of nitrogen, carbon monoxide, hydrocarbon, and particulate matter exhaust emission standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., hydrocarbon, and particulate matter exhaust emission standards. 89.112 Section 89.112 Protection of....112 Oxides of nitrogen, carbon monoxide, hydrocarbon, and particulate matter exhaust emission... emissions of oxides of nitrogen, carbon monoxide, hydrocarbon, and nonmethane hydrocarbon are measured using...

  14. 77 FR 31262 - Approval and Promulgation of Implementation Plans; Kentucky; Louisville; Fine Particulate Matter...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-25

    ... Promulgation of Implementation Plans; Kentucky; Louisville; Fine Particulate Matter 2002 Base Year Emissions... approve the fine particulate matter (PM 2.5 ) 2002 base year emissions inventory, portion of the State...), a reasonable further progress (RFP) plan, contingency measures, a 2002 base year emissions inventory...

  15. 40 CFR 52.1278 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 4 2012-07-01 2012-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1278 Section 52.1278 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...) Mississippi § 52.1278 Control strategy: Sulfur oxides and particulate matter. In a letter dated January 30...

  16. 40 CFR 52.2231 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2231 Section 52.2231 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... § 52.2231 Control strategy: Sulfur oxides and particulate matter. (a) Part D conditional approval. The...

  17. 40 CFR 52.1781 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 4 2011-07-01 2011-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1781 Section 52.1781 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.1781 Control strategy: Sulfur oxides and particulate matter. (a) The plan's control strategy...

  18. 40 CFR 52.1278 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 4 2014-07-01 2014-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1278 Section 52.1278 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...) Mississippi § 52.1278 Control strategy: Sulfur oxides and particulate matter. (a) In a letter dated January 30...

  19. 40 CFR 52.578 - Control Strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 3 2012-07-01 2012-07-01 false Control Strategy: Sulfur oxides and particulate matter. 52.578 Section 52.578 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Strategy: Sulfur oxides and particulate matter. In a letter dated March 26, 1987, the Georgia Department of...

  20. 40 CFR 52.2130 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2130 Section 52.2130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.2130 Control strategy: Sulfur oxides and particulate matter. In letters dated May 7, and...

  1. 40 CFR 52.578 - Control Strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control Strategy: Sulfur oxides and particulate matter. 52.578 Section 52.578 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Strategy: Sulfur oxides and particulate matter. In a letter dated March 26, 1987, the Georgia Department of...

  2. 40 CFR 52.578 - Control Strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 3 2013-07-01 2013-07-01 false Control Strategy: Sulfur oxides and particulate matter. 52.578 Section 52.578 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Strategy: Sulfur oxides and particulate matter. In a letter dated March 26, 1987, the Georgia Department of...

  3. 40 CFR 52.933 - Control Strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control Strategy: Sulfur oxides and particulate matter. 52.933 Section 52.933 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Strategy: Sulfur oxides and particulate matter. In a letter dated March 27, 1987, the Kentucky Department...

  4. 40 CFR 52.2130 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 5 2012-07-01 2012-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2130 Section 52.2130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.2130 Control strategy: Sulfur oxides and particulate matter. In letters dated May 7, and...

  5. 40 CFR 52.62 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.62 Section 52.62 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... strategy: Sulfur oxides and particulate matter. In a letter dated May 29, 1987, the Alabama Department of...

  6. 40 CFR 52.578 - Control Strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 3 2014-07-01 2014-07-01 false Control Strategy: Sulfur oxides and particulate matter. 52.578 Section 52.578 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Strategy: Sulfur oxides and particulate matter. In a letter dated March 26, 1987, the Georgia Department of...

  7. 40 CFR 52.2130 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 5 2014-07-01 2014-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.2130 Section 52.2130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.2130 Control strategy: Sulfur oxides and particulate matter. In letters dated May 7, and...

  8. 40 CFR 52.1781 - Control strategy: Sulfur oxides and particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 4 2010-07-01 2010-07-01 false Control strategy: Sulfur oxides and particulate matter. 52.1781 Section 52.1781 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Carolina § 52.1781 Control strategy: Sulfur oxides and particulate matter. (a) The plan's control strategy...

  9. 30 CFR 57.5060 - Limit on exposure to diesel particulate matter.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... diesel particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent... particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent full shift... mine must not exceed an average eight-hour equivalent full shift airborne concentration of 350...

  10. 30 CFR 57.5060 - Limit on exposure to diesel particulate matter.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... diesel particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent... particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent full shift... mine must not exceed an average eight-hour equivalent full shift airborne concentration of 350...

  11. 30 CFR 57.5060 - Limit on exposure to diesel particulate matter.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... diesel particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent... particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent full shift... mine must not exceed an average eight-hour equivalent full shift airborne concentration of 350...

  12. 30 CFR 57.5060 - Limit on exposure to diesel particulate matter.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... diesel particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent... particulate matter (DPM) in an underground mine must not exceed an average eight-hour equivalent full shift... mine must not exceed an average eight-hour equivalent full shift airborne concentration of 350...

  13. 78 FR 23524 - Approval and Promulgation of Air Quality Implementation Plans; Indiana; Particulate Matter...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-04-19

    ... Promulgation of Air Quality Implementation Plans; Indiana; Particulate Matter Ambient Air Quality Standards... revise the Indiana State Implementation Plan (SIP) for particulate matter under the Clean Air Act. This submission contains the 24-hour fine particle National Ambient Air Quality Standards (NAAQS) promulgated by...

  14. MEASUREMENT OF FINE PARTICULATE MATTER (NONVOLATILE AND SEMIVOLATILE FRACTIONS) IN FRESNO, CA

    EPA Science Inventory

    Semi-volatile material, including ammonium nitrate and semi-volatile organic material, is often not measured by traditionally used sampling methods including the FRM and the R&P TEOM Monitor. An intensive sampling campaign was performed at the EPA Fresno, CA Supersite during D...

  15. Structural Variation in the Bacterial Community Associated with Airborne Particulate Matter in Beijing, China, during Hazy and Nonhazy Days.

    PubMed

    Yan, Dong; Zhang, Tao; Su, Jing; Zhao, Li-Li; Wang, Hao; Fang, Xiao-Mei; Zhang, Yu-Qin; Liu, Hong-Yu; Yu, Li-Yan

    2018-05-01

    The structural variation of the bacterial community associated with particulate matter (PM) was assessed in an urban area of Beijing during hazy and nonhazy days. Sampling for different PM fractions (PM 2.5 [<2.5 μm], PM 10 [<10 μm], and total suspended particulate) was conducted using three portable air samplers from September 2014 to February 2015. The airborne bacterial community in these samples was analyzed using the Illumina MiSeq platform with bacterium-specific primers targeting the 16S rRNA gene. A total of 1,707,072 reads belonging to 6,009 operational taxonomic units were observed. The airborne bacterial community composition was significantly affected by PM fractions ( R = 0.157, P < 0.01). In addition, the relative abundances of several genera significantly differed between samples with various haze levels; for example, Methylobacillus , Tumebacillus , and Desulfurispora spp. increased in heavy-haze days. Canonical correspondence analysis and permutation tests showed that temperature, SO 2 concentration, relative humidity, PM 10 concentration, and CO concentration were significant factors that associated with airborne bacterial community composition. Only six genera increased across PM 10 samples ( Dokdonella , Caenimonas , Geminicoccus , and Sphingopyxis ) and PM 2.5 samples ( Cellulomonas and Rhizobacter ), while a large number of taxa significantly increased in total suspended particulate samples, such as Paracoccus , Kocuria , and Sphingomonas Network analysis indicated that Paracoccus , Rubellimicrobium , Kocuria , and Arthrobacter were the key genera in the airborne PM samples. Overall, the findings presented here suggest that diverse airborne bacterial communities are associated with PM and provide further understanding of bacterial community structure in the atmosphere during hazy and nonhazy days. IMPORTANCE The results presented here represent an analysis of the airborne bacterial community associated with particulate matter (PM) and advance our understanding of the structural variation of these communities. We observed a shift in bacterial community composition with PM fractions but no significant difference with haze levels. This may be because the bacterial differences are obscured by high bacterial diversity in the atmosphere. However, we also observed that a few genera (such as Methylobacillus , Tumebacillus , and Desulfurispora ) increased significantly on heavy-haze days. In addition, Paracoccus , Rubellimicrobium , Kocuria , and Arthrobacter were the key genera in the airborne PM samples. Accurate and real-time techniques, such as metagenomics and metatranscriptomics, should be developed for a future survey of the relationship of airborne bacteria and haze. Copyright © 2018 American Society for Microbiology.

  16. Tidal cycles of total particulate mercury in the Jade Bay, lower Saxonian Wadden Sea, southern North Sea.

    PubMed

    Jin, Huafang; Liebezeit, Gerd

    2013-01-01

    In this study, we evaluate the nature of the relationship between particulate matter and total mercury concentrations. For this purpose, we estimate both of the two values in water column over 12-h tidal cycles of the Jade Bay, southern North Sea. Total particulate mercury in 250 mL water samples was determined by oxygen combustion-gold amalgamation. Mercury contents varied from 63 to 259 ng/g suspended particulate matter (SPM) or 3.5-52.8 ng/L in surface waters. Total particulate mercury content (THg(p)) was positively correlated with (SPM), indicating that mercury in tidal waters is mostly associated with (SPM), and that tidal variations of total particulate mercury are mainly due to changes in (SPM) content throughout the tidal cycle. Maximum values for THg(p) were observed during mid-flood and mid-ebb, while the lowest values were determined at low tide and high tide. These data suggest that there are no mercury point sources in the Jade Bay. Moreover, the THg(p) content at low tide and high tide were significantly lower than the values recorded in the bottom sediment of the sampling site (>200 ng/g DW), while THg(p) content during the mid-flood and mid-ebb were comparable to the THg content in the surface bottom sediments. Therefore, changes in THg(p) content in the water column due to tidal forcing may have resulted from re-suspension of underlying surface sediments with relatively high mercury content.

  17. Suspended particulate matter determines physical speciation of Fe, Mn, and trace metals in surface waters of Loire watershed.

    PubMed

    Baalousha, Mohamed; Stoll, Serge; Motelica-Heino, Mikaël; Guigues, Nathalie; Braibant, Gilles; Huneau, Frédéric; Le Coustumer, Philippe

    2018-02-10

    This study investigates the spatiotemporal variability of major and trace elements, dissolved organic carbon (DOC), total dissolved solids (TDS), and suspended particulate matter (SPM) in surface waters of several hydrosystems of the Loire River watershed in France. In particular, this study aims to delineate the impact of the abovementioned water physicochemical parameters on natural iron and manganese physical speciation (homoaggregation/heteroaggregation) among fine colloidal and dissolved (< 10 nm), colloidal (10-450 nm) and particulate (> 450 nm) phases in Loire River watershed. Results show that the chemistry of the Loire River watershed is controlled by two end members: magmatic and metamorphic petrographic context on the upper part of the watershed; and sedimentary rocks for the middle and low part of the Loire. The percentage of particulate Fe and Mn increased downstream concurrent with the increase in SPM and major cations concentration, whereas the percentage of colloidal Fe and Mn decreased downstream. Transmission electron microscopy analyses of the colloidal and particulate fractions (from the non-filtered water sample) revealed that heteroaggregation of Fe and Mn rich natural nanoparticles and natural organic matter to the particulate phase is the dominant mechanism. The heteroaggregation controls the partitioning of Fe and Mn in the different fractions, potentially due to the increase in the ionic strength, and divalent cations concentration downstream, and SPM concentration. These findings imply that SPM concentration plays an important role in controlling the fate and behavior of Fe and Mn in various sized fractions. Graphical abstract Physical speciation by heteroaggregation of (Fe-Mn) compounds: high [SPM] → [Fe-Mn] particulate faction; low {SPM] → [Fe-Mn] colloid-dissolved fraction.

  18. Monitoring diesel particulate matter and calculating diesel particulate densities using Grimm model 1.109 real-time aerosol monitors in underground mines.

    PubMed

    Kimbal, Kyle C; Pahler, Leon; Larson, Rodney; VanDerslice, Jim

    2012-01-01

    Currently, there is no Mine Safety and Health Administration (MSHA)-approved sampling method that provides real-time results for ambient concentrations of diesel particulates. This study investigated whether a commercially available aerosol spectrometer, the Grimm Portable Aerosol Spectrometer Model 1.109, could be used during underground mine operations to provide accurate real-time diesel particulate data relative to MSHA-approved cassette-based sampling methods. A subset was to estimate size-specific diesel particle densities to potentially improve the diesel particulate concentration estimates using the aerosol monitor. Concurrent sampling was conducted during underground metal mine operations using six duplicate diesel particulate cassettes, according to the MSHA-approved method, and two identical Grimm Model 1.109 instruments. Linear regression was used to develop adjustment factors relating the Grimm results to the average of the cassette results. Statistical models using the Grimm data produced predicted diesel particulate concentrations that highly correlated with the time-weighted average cassette results (R(2) = 0.86, 0.88). Size-specific diesel particulate densities were not constant over the range of particle diameters observed. The variance of the calculated diesel particulate densities by particle diameter size supports the current understanding that diesel emissions are a mixture of particulate aerosols and a complex host of gases and vapors not limited to elemental and organic carbon. Finally, diesel particulate concentrations measured by the Grimm Model 1.109 can be adjusted to provide sufficiently accurate real-time air monitoring data for an underground mining environment.

  19. Generation rates and emission factors of particulate matter and particle-bound polycyclic aromatic hydrocarbons of incense sticks.

    PubMed

    Lung, Shih-Chun Candice; Hu, Shu-Chuan

    2003-02-01

    The generation rates and emission factors of particulate matter and associated polycyclic aromatic hydrocarbons (PAHs) from incense burning were assessed in a laboratory setting. The differences among different segments of the same stick, among different sticks of the same kind of incense, and between two kinds of manually made Chih-Chen incense sticks (A and B) were evaluated. Joss sticks were burned inside a 44 cm long elutriator; personal environmental monitors fitted into the top of the elutriator were used to take PM2.5 and PM10 samples of incense smoke. Samples were analyzed for PAHs by gas chromatography-flame ionization Detector. It was found that particle and associated PAHs were generated approximately at 561 microg/min (geometric standard deviation (GSD) = 1.1) and 0.56 microg/min (GSD = 1.1) from Incense A, and at 661 microg/min (GSD = 1.7) and 0.46 microg/min (GSD = 1.3) from Incense B, respectively. One gram of Incense A emitted about 19.8 mg (GSD = 1.1) particulate matter and 17.1 microg (GSD = 1.2) particulate-phase PAHs, while one gram of Incense B produced around 43.6 mg (GSD = 1.1) of particles and 25.2 microg (GSD = 1.2) of particle-bound PAHs. There were significant differences in emissions between Incenses A and B, although they belong to the same class of incense. A 10-20% variability in emissions was observed in the main part of the manually produced stick, and a larger variation was found at both tips of the combustible part.

  20. Electrically heated particulate filter propagation support methods and systems

    DOEpatents

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-06-07

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate combustion of particulate matter in the particulate filter. A propagation module estimates a propagation status of the combustion of the particulate matter based on a combustion temperature. A temperature adjustment module controls the combustion temperature by selectively increasing a temperature of exhaust that passes through the particulate filter.

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