Potential for temperature change during application of ultrasonic vibration to intra-radicular posts.

PubMed

Satterthwaite, Julian D; Stokes, Alastair N; Frankel, Nicholas T N

2003-06-01

The aim of this study was to assess the potential for heat production when intra-radicular posts were subjected to ultrasonic vibration. Thirty zirconium ceramic posts and thirty stainless steel posts were luted into canine roots. Ultrasonic vibration was applied to the top of each post for thirty minutes and temperature change on the root surface was measured. The mean peak temperature rise from baseline was 18.7 degrees C. Post type had no influence on peak temperature. Temperature increase on the external root surfaces increased as the thickness of dentine between post and root surface reduced.

Peak capacity, peak-capacity production rate, and boiling point resolution for temperature-programmed GC with very high programming rates

PubMed

Grall; Leonard; Sacks

2000-02-01

Recent advances in column heating technology have made possible very fast linear temperature programming for high-speed gas chromatography. A fused-silica capillary column is contained in a tubular metal jacket, which is resistively heated by a precision power supply. With very rapid column heating, the rate of peak-capacity production is significantly enhanced, but the total peak capacity and the boiling-point resolution (minimum boiling-point difference required for the separation of two nonpolar compounds on a nonpolar column) are reduced relative to more conventional heating rates used with convection-oven instruments. As temperature-programming rates increase, elution temperatures also increase with the result that retention may become insignificant prior to elution. This results in inefficient utilization of the down-stream end of the column and causes a loss in the rate of peak-capacity production. The rate of peak-capacity production is increased by the use of shorter columns and higher carrier gas velocities. With high programming rates (100-600 degrees C/min), column lengths of 6-12 m and average linear carrier gas velocities in the 100-150 cm/s range are satisfactory. In this study, the rate of peak-capacity production, the total peak capacity, and the boiling point resolution are determined for C10-C28 n-alkanes using 6-18 m long columns, 50-200 cm/s average carrier gas velocities, and 60-600 degrees C/min programming rates. It was found that with a 6-meter-long, 0.25-mm i.d. column programmed at a rate of 600 degrees C/min, a maximum peak-capacity production rate of 6.1 peaks/s was obtained. A total peak capacity of about 75 peaks was produced in a 37-s long separation spanning a boiling-point range from n-C10 (174 degrees C) to n-C28 (432 degrees C).

Comparative study of lesions created by high-intensity focused ultrasound using sequential discrete and continuous scanning strategies.

PubMed

Fan, Tingbo; Liu, Zhenbo; Zhang, Dong; Tang, Mengxing

2013-03-01

Lesion formation and temperature distribution induced by high-intensity focused ultrasound (HIFU) were investigated both numerically and experimentally via two energy-delivering strategies, i.e., sequential discrete and continuous scanning modes. Simulations were presented based on the combination of Khokhlov-Zabolotskaya-Kuznetsov (KZK) equation and bioheat equation. Measurements were performed on tissue-mimicking phantoms sonicated by a 1.12-MHz single-element focused transducer working at an acoustic power of 75 W. Both the simulated and experimental results show that, in the sequential discrete mode, obvious saw-tooth-like contours could be observed for the peak temperature distribution and the lesion boundaries, with the increasing interval space between two adjacent exposure points. In the continuous scanning mode, more uniform peak temperature distributions and lesion boundaries would be produced, and the peak temperature values would decrease significantly with the increasing scanning speed. In addition, compared to the sequential discrete mode, the continuous scanning mode could achieve higher treatment efficiency (lesion area generated per second) with a lower peak temperature. The present studies suggest that the peak temperature and tissue lesion resulting from the HIFU exposure could be controlled by adjusting the transducer scanning speed, which is important for improving the HIFU treatment efficiency.

Graphene Nanoplatelet Reinforced Tantalum Carbide

DTIC Science & Technology

2015-08-27

testing showed an increase in thermal conductivity in GNP reinforced composites resulting in a reduction of peak sample surface temperature. This study...showed an increase in thermal conductivity in GNP reinforced composites resulting in a reduction of peak sample surface temperature. This study resulted...Wetting angle measurements are conducted to demonstrate the effectiveness of the PLC coating . Mechanical properties of the GrF-PLC hybrid are

Atmospheric pressure-MOVPE growth of GaSb/GaAs quantum dots

NASA Astrophysics Data System (ADS)

Tile, Ngcali; Ahia, Chinedu C.; Olivier, Jaco; Botha, Johannes Reinhardt

2018-04-01

This study focuses on the growth of GaSb/GaAs quantum dots (QD) using an atmospheric pressure MOVPE system. For the best uncapped dots, the average dot height, base diameter and density are 5 nm, 45 nm and 4.5×1010 cm-2, respectively. Capping of GaSb QDs at high temperatures caused flattening and formation of thin inhomogeneous GaSb layer inside GaAs resulting in no obvious QD PL peak. Capping at low temperatures lead to the formation of dot-like features and a wetting layer (WL) with distinct PL peaks for QD and WL at 1097 nm and 983 nm respectively. Some of the dot-like features had voids. An increase in excitation power caused the QD and WL peaks to shift to higher energies. This is attributed to electrostatic band bending leading to triangular potential wells, typical of type-II alignment between GaAs and strained GaSb. Variable temperature PL measurements of the QD sample showed the decrease in the intensity of the WL peak to be faster than that of the QD peak as the temperature increased.

Management of plains cottonwood at Theodore Roosevelt National Park, North Dakota

USGS Publications Warehouse

Friedman, Jonathan M.; Griffin, Eleanor R.

2017-01-01

Warmer temperatures since 1976 have reduced flood peaks and the ice jamming that magnifies those peaks; as a result channel movement, cottonwood establishment and cottonwood growth have decreased. Increasing temperatures associated with global climate change could continue this trend.

Contribution For Arc Temperature Affected By Current Increment Ratio At Peak Current In Pulsed Arc

NASA Astrophysics Data System (ADS)

Kano, Ryota; Mitubori, Hironori; Iwao, Toru

2015-11-01

Tungsten Inert Gas (TIG) Welding is one of the high quality welding. However, parameters of the pulsed arc welding are many and complicated. if the welding parameters are not appropriate, the welding pool shape becomes wide and shallow.the convection of driving force contributes to the welding pool shape. However, in the case of changing current waveform as the pulse high frequency TIG welding, the arc temperature does not follow the change of the current. Other result of the calculation, in particular, the arc temperature at the reaching time of peak current is based on these considerations. Thus, the accurate measurement of the temperature at the time is required. Therefore, the objective of this research is the elucidation of contribution for arc temperature affected by current increment ratio at peak current in pulsed arc. It should obtain a detail knowledge of the welding model in pulsed arc. The temperature in the case of increment of the peak current from the base current is measured by using spectroscopy. As a result, when the arc current increases from 100 A to 150 A at 120 ms, the transient response of the temperature didn't occur during increasing current. Thus, during the current rise, it has been verified by measuring. Therefore, the contribution for arc temperature affected by current increment ratio at peak current in pulsed arc was elucidated in order to obtain more knowledge of welding model of pulsed arc.

Influence of the volumes of bis-acryl and poly(methyl methacrylate) resins on their exothermic behavior during polymerization.

PubMed

Ha, Jung-Yun; Kim, Sung-Hun; Kim, Kyo-Han; Kwon, Tae-Yub

2011-01-01

This study aimed to evaluate the influence of the volumes of a bis-acryl resin (Luxatemp) and a poly(methyl methacrylate) resin (Jet) on their exothermic behaviors during polymerization based on vinyl group conversion. The number of vinyl groups reacted and exotherm were determined based on weight percent of methacrylate groups using FTIR spectroscopy. Temperature changes during polymerization at 23°C were recorded for 20 minutes using a multiple cavity mold overlying a thermocouple. The number of vinyl groups reacted and exotherm of Luxatemp were consistently lower than those of Jet at each resin volume. Mean peak temperature rises of Luxatemp and Jet were in the range of 2.0-6.6°C and 4.2-11.6°C respectively, with Luxatemp and Jet taking 2 and 10 minutes respectively to reach their peak temperatures. As their resin volumes increased, their peak temperatures and total peak areas were also observed to increase significantly (p<0.01).

Low-temperature vibrational dynamics of fused silica and binary silicate glasses

NASA Astrophysics Data System (ADS)

Cai, Ling; Shi, Ying; Hrdina, Ken; Moore, Lisa; Wu, Jingshi; Daemen, Luke L.; Cheng, Yongqiang

2018-02-01

Inelastic neutron scattering was used to study the vibrational dynamics of fused silica and its mixed binary glasses that were doped with either TiO2 or K2O . The energy transfer was measured from zero to 180 meV where the so-called Boson peaks (BP) at low energy and molecular vibrations at high energy are included. Although most of the vibrational spectra at the high energy resemble those reported in earlier literature, a defect-mode-like peak is observed for the doped binary systems near 120 meV . At very low temperature, the BP intensity increases rapidly with temperature and then, at higher temperature, the peak intensity decreases. As a result, a maximum is observed in the temperature dependence of the BP intensity. This maximum was shown in all four samples, but the pure SiO2 sample shows the highest intensity peak and the lowest temperature for peak position. Broadband energy spectra reveal a shift of intensity from BP to the more localized modes at higher energy. Temperature evolution of BP and its relationship with heat conduction and thermal expansion are discussed.

Multiple current peaks in room-temperature atmospheric pressure homogenous dielectric barrier discharge plasma excited by high-voltage tunable nanosecond pulse in air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, De-Zheng; Wang, Wen-Chun; Zhang, Shuai

2013-05-13

Room temperature homogenous dielectric barrier discharge plasma with high instantaneous energy efficiency is acquired by using nanosecond pulse voltage with 20-200 ns tunable pulse width. Increasing the voltage pulse width can lead to the generation of regular and stable multiple current peaks in each discharge sequence. When the voltage pulse width is 200 ns, more than 5 organized current peaks can be observed under 26 kV peak voltage. Investigation also shows that the organized multiple current peaks only appear in homogenous discharge mode. When the discharge is filament mode, organized multiple current peaks are replaced by chaotic filament current peaks.

Thermoluminescence, ESR and x-ray diffraction studies of CaSO4 : Dy phosphor subjected to post preparation high temperature thermal treatment

NASA Astrophysics Data System (ADS)

Bakshi, A. K.; Patwe, S. J.; Bhide, M. K.; Sanyal, B.; Natarajan, V.; Tyagi, A. K.; Kher, R. K.

2008-01-01

Thermoluminescence (TL), electron spin resonance (ESR) and x ray diffraction studies of CaSO4 : Dy phosphor subjected to post preparation high temperature treatment were carried out. Analysis of the TL glow curve indicated that the dosimetric glow peak at 240 °C reduces, whereas the low temperature satellite peak increases with the increase in the annealing temperature in the range 650-1000 °C. The influence of the annealing atmosphere on the TL glow curve structure was also observed. Reduction of the photoluminescence intensity of the annealed phosphor indicated that the environment of Dy3+ ions might have undergone some change due to high temperature treatment. Reduction in the ESR signal intensity corresponding to O_{3}^{-} and SO_{3}^{-} radicals was observed initially with the increase in the annealing temperaure; subsequently their intensity increased with temperature. Signals due to the SO_{4}^{-} radical vanished, when the phosphor was annealed beyond 800 °C. A signal corresponding to SH2- radicals was also observed in the ESR spectra for samples subjected to annealing in the temperature regime 800-1000 °C. XRD of the in situ annealed phosphor showed a change in the unit cell parameters. An endothermic peak at 860 °C in the DTA spectrum was observed.

Reflective photoluminescence fiber temperature probe based on the CdSe/ZnS quantum dot thin film

NASA Astrophysics Data System (ADS)

Wang, Helin; Yang, Aijun; Chen, Zhongshi; Geng, Yan

2014-08-01

A reflective fiber temperature sensor based on the optical temperature dependent characteristics of a quantum dots (QDs) thin film is developed by depositing the CdSe/ZnS core/shell quantum dots on the SiO2 glass substrates. As the temperature is changed from 30 to 200°C, the peak wavelengths of PL spectra from the sensing head increase linearly with the temperature, while the peak intensity and the full width at half maximum (FWHM) of PL spectra vary exponentially according to the specific physical law. Using the obtained temperature-dependent peak-wavelength shift, the average resolution of the designed fiber temperature sensor can reach 0.12 nm/°C, while it reaches 0.056 nm/°C according to the FWHM of PL spectrum.

Rattler model of the boson peak at silica surfaces.

PubMed

Steurer, Wolfram; Tosatti, Erio

2012-10-28

Recent experiments unveiled two new aspects of the low-energy excitation spectrum of silica glass--commonly termed as the "boson peak" region. The first is that at low temperature the silica surface exhibits a different, softer boson peak than the bulk. The second is a giant thermal blueshift of the surface boson peak frequency causing it to cross and overcome the bulk peak with increasing temperature. Here we present a simple lattice model that reproduces this behavior in all its aspects. Each site consists of rigid tetrahedral units softly connected so as to be able to rotate anharmonically as "rattlers" in their cages. As shown by simulations, the model dynamics exhibits a boson-like peak, which has lower frequency at the surface where rattlers have a weaker restoring force. Upon heating however the larger angular freedom of surface units allows them to rattle more than in the bulk, leading to a steeper frequency increase similar to experiment.

Graphitic carbon nanospheres: A Raman spectroscopic investigation of thermal conductivity and morphological evolution by pulsed laser irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Agarwal, Radhe; Sahoo, Satyaprakash, E-mail: satya504@gmail.com, E-mail: rkatiyar@hpcf.upr.edu; Chitturi, Venkateswara Rao

2015-12-07

Graphitic carbon nanospheres (GCNSs) were prepared by a unique acidic treatment of multi-walled nanotubes. Spherical morphology with a narrow size distribution was confirmed by transmission electron microscopy studies. The room temperature Raman spectra showed a clear signature of D- and G-peaks at around 1350 and 1591 cm{sup −1}, respectively. Temperature dependent Raman scattering measurements were performed to understand the phonon dynamics and first order temperature coefficients related to the D- and G-peaks. The temperature dependent Raman spectra in a range of 83–473 K were analysed, where the D-peak was observed to show a red-shift with increasing temperature. The relative intensity ratio ofmore » D- to G-peaks also showed a significant rise with increasing temperature. Such a temperature dependent behaviour can be attributed to lengthening of the C-C bond due to thermal expansion in material. The estimated value of the thermal conductivity of GCNSs ∼0.97 W m{sup −1} K{sup −1} was calculated using Raman spectroscopy. In addition, the effect of pulsed laser treatment on the GCNSs was demonstrated by analyzing the Raman spectra of post irradiated samples.« less

Effects of helium concentration and radiation temperature on interaction of helium atoms with displacement cascades in bcc iron

NASA Astrophysics Data System (ADS)

Gao, Chan; Tian, Dongfeng; Li, Maosheng; Qian, Dazhi

2018-03-01

In fusion applications, helium, implanted or created by transmutation, plays an important role in the response of reduced-activation ferritic/martensitic steels to neutron radiation damage. The effects of helium concentration and radiation temperature on interaction of interstitial helium atoms with displacement cascades have been studied in Fe-He system using molecular dynamics with recently developed Fe-He potential. Results indicate that interstitial helium atoms produce no additional defects at peak time and promote recombination of Frenkel pairs at lower helium concentrations, but suppress recombination of Frenkel pairs at larger helium concentrations. Moreover, large helium concentrations promote the production of defects at the end of cascades. The number of substitutional helium atoms increases with helium concentration at peak time and the end of cascades, but the number of substitutional helium atoms at peak time is smaller than that at the end of displacement cascades. High radiation temperatures promote the production at peak time and the recombination of defects at the end of cascades. The number of substitutional helium atoms increases with radiation temperature, but that at peak time is smaller than that at the end of cascades.

Factors contributing to the temperature beneath plaster or fiberglass cast material

PubMed Central

Hutchinson, Michael J; Hutchinson, Mark R

2008-01-01

Background Most cast materials mature and harden via an exothermic reaction. Although rare, thermal injuries secondary to casting can occur. The purpose of this study was to evaluate factors that contribute to the elevated temperature beneath a cast and, more specifically, evaluate the differences of modern casting materials including fiberglass and prefabricated splints. Methods The temperature beneath various types (plaster, fiberglass, and fiberglass splints), brands, and thickness of cast material were measured after they were applied over thermometer which was on the surface of a single diameter and thickness PVC tube. A single layer of cotton stockinette with variable layers and types of cast padding were placed prior to application of the cast. Serial temperature measurements were made as the cast matured and reached peak temperature. Time to peak, duration of peak, and peak temperature were noted. Additional tests included varying the dip water temperature and assessing external insulating factors. Ambient temperature, ambient humidity and dip water freshness were controlled. Results Outcomes revealed that material type, cast thickness, and dip water temperature played key roles regarding the temperature beneath the cast. Faster setting plasters achieved peak temperature quicker and at a higher level than slower setting plasters. Thicker fiberglass and plaster casts led to greater peak temperature levels. Likewise increasing dip-water temperature led to elevated temperatures. The thickness and type of cast padding had less of an effect for all materials. With a definition of thermal injury risk of skin injury being greater than 49 degrees Celsius, we found that thick casts of extra fast setting plaster consistently approached dangerous levels (greater than 49 degrees for an extended period). Indeed a cast of extra-fast setting plaster, 20 layers thick, placed on a pillow during maturation maintained temperatures over 50 degrees of Celsius for over 20 minutes. Conclusion Clinicians should be cautious when applying thick casts with warm dip water. Fast setting plasters have increased risk of thermal injury while brand does not appear to play a significant role. Prefabricated fiberglass splints appear to be safer than circumferential casts. The greatest risk of thermal injury occurs when thick casts are allowed to mature while resting on pillow. PMID:18298851

Optical properties of self-assembled ZnTe quantum dots grown by molecular-beam epitaxy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, C.S.; Lai, Y.J.; Chou, W.C.

2005-02-01

The morphology and the size-dependent photoluminescence (PL) spectra of the type-II ZnTe quantum dots (QDs) grown in a ZnSe matrix were obtained. The coverage of ZnTe varied from 2.5 to 3.5 monolayers (MLs). The PL peak energy decreased as the dot size increased. Excitation power and temperature-dependent PL spectra are used to characterize the optical properties of the ZnTe quantum dots. For 2.5- and 3.0-ML samples, the PL peak energy decreased monotonically as the temperature increased. However, for the 3.5-ML sample, the PL peak energy was initially blueshifted and then redshifted as the temperature increased above 40 K. Carrier thermalizationmore » and carrier transfer between QDs are used to explain the experimental data. A model of temperature-dependent linewidth broadening is employed to fit the high-temperature data. The activation energy, which was found by the simple PL intensity quenching model, of the 2.5, 3.0, and 3.5 MLs were determined to be 6.35, 9.40, and 18.87 meV, respectively.« less

Warm water temperatures and shifts in seasonality increase trout recruitment but only moderately decrease adult size in western North American tailwaters

USGS Publications Warehouse

Dibble, Kimberly L.; Yackulic, Charles B.; Kennedy, Theodore A.

2018-01-01

Dams throughout western North America have altered thermal regimes in rivers, creating cold, clear “tailwaters” in which trout populations thrive. Ongoing drought in the region has led to highly publicized reductions in reservoir storage and raised concerns about potential reductions in downstream flows. Large changes in riverine thermal regimes may also occur as reservoir water levels drop, yet this potential impact has received far less attention. We analyzed historic water temperature and fish population data to anticipate how trout may respond to future changes in the magnitude and seasonality of river temperatures. We found that summer temperatures were inversely related to reservoir water level, with warm temperatures associated with reduced storage and with dams operated as run-of-river units. Variation in rainbow trout (Oncorhynchus mykiss) recruitment was linked to water temperature variation, with a 5-fold increase in recruitment occurring at peak summer temperatures (18 °C vs. 7 °C) and a 2.5-fold increase in recruitment when peak temperatures occurred in summer rather than fall. Conversely, adult trout size was only moderately related to temperature. Rainbow and brown trout (Salmo trutta) size decreased by ~24 mm and 20 mm, respectively, as mean annual and peak summer temperatures increased. Further, rainbow trout size decreased by ~29 mm with an earlier onset of cold winter temperatures. While increased recruitment may be the more likely outcome of a warmer and drier climate, density-dependent growth constraints could exacerbate temperature-dependent growth reductions. As such, managers may consider implementing flows to reduce recruitment or altering infrastructure to maintain coldwater reservoir releases.

Structural analysis of graphene and h-BN: A molecular dynamics approach

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thomas, Siby; Ajith, K. M., E-mail: ajith@nitk.ac.in; Valsakumar, M. C.

2016-05-06

Classical molecular dynamics simulation is employed to analyze pair correlations in graphene and h-BN at various temperatures to explore the integrity of their respective structures. As the temperature increases, the height fluctuations in the out-of-plane direction of both graphene and h-BN are found to increase. The positional spread of atoms also increases with temperature. Thus the amplitude of the peak positions in the radial distribution function (RDF) decreases with temperature. It is found that FWHM of peaks in the RDF of h-BN is smaller as compared to those of graphene which implies that the structure of h-BN is more robustmore » as compared to that of graphene with respect to their respective empirical potential.« less

Long-term patterns in fish phenology in the western Dutch Wadden Sea in relation to climate change

NASA Astrophysics Data System (ADS)

van Walraven, Lodewijk; Dapper, Rob; Nauw, Janine J.; Tulp, Ingrid; Witte, Johannes IJ.; van der Veer, Henk W.

2017-09-01

Long-term patterns in fish phenology in the western Dutch Wadden Sea were studied using a 53 year (1960-2013) high resolution time series of daily kom-fyke catches in spring and autumn. Trends in first appearance, last occurrence and peak abundance were analysed for the most common species in relation to mode of life (pelagic, demersal, benthopelagic) and biogeographic guild (northern or southern distribution). Climate change in the western Wadden Sea involved an increase in water temperature from 1980 onwards. The main pattern in first day of occurrence, peak occurrence and last day of occurrence was similar: a positive trend over time and a correlation with spring and summer water temperature. This is counterintuitive; with increasing temperature, an advanced immigration of fish species would be expected. An explanation might be that water temperatures have increased offshore as well and hence fish remain longer there, delaying their immigration to the Wadden Sea. The main trend towards later date of peak occurrence and last day of occurrence was in line with our expectations: a forward shift in immigration into the Wadden Sea implies also that peak abundance is delayed. As a consequence of the increased water temperature, autumn water temperature remains favourable longer than before. For most of the species present, the Wadden Sea is not near the edge of their distributional range. The most striking phenological shifts occurred in those individual species for which the Wadden Sea is near the southern or northern edge of their distribution.

The influence of loading frequency on the high-temperature fatigue behavior of a Nicalon-fabric-reinforced polymer-derived ceramic-matrix composite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vanswijgenhoven, E.; Holmes, J.; Wevers, M.

Fiber-reinforced ceramic-matrix composites are under development for high-temperature structural applications. These applications involve fatigue loading under a wide range of frequencies. To date, high-temperature fatigue experiments have typically been performed at loading frequencies of 10 Hz or lower. At higher frequencies, a strong effect of loading frequency on fatigue life has been demonstrated for certain CMC`s tested at room temperature. The fatigue life of CMC`s with weak fiber-matrix interfaces typically decreases as the loading frequency increases. This decrease is attributed to frictional heating and frequency dependent interface and fiber damage. More recently, it has been shown that the room temperaturemore » fatigue life of a Nicalon-fabric-reinforced composite with a strong interface (SYLRAMIC{trademark}) appears to be independent of loading frequency. The high-temperature low-frequency fatigue behavior of the SYLRAMIC composite has also been investigated. For a fatigue peak stress {sigma}{sub peak} above a proportional limit stress of 70 MPa, the number of cycles to failure N{sub f} decreased with an increase in {sigma}{sub peak}. The material endured more than 10{sup 6} cycles for {sigma}{sub peak} below 70 MPa. In this paper, the influence of loading frequency on the high-temperature fatigue behavior of the SYLRAMIC composite is reported. It will be shown that the fatigue limit is unaffected by the loading frequency, that the number of fatigue cycles to failure N{sub f} increases with an increase in frequency, and that the time to failure t{sub f} decreases with an increase in frequency.« less

Comparisons of Damage Evolution between 2D C/SiC and SiC/SiC Ceramic-Matrix Composites under Tension-Tension Cyclic Fatigue Loading at Room and Elevated Temperatures

PubMed Central

Li, Longbiao

2016-01-01

In this paper, comparisons of damage evolution between 2D C/SiC and SiC/SiC ceramic-matrix composites (CMCs) under tension–tension cyclic fatigue loading at room and elevated temperatures have been investigated. Fatigue hysteresis loops models considering multiple matrix cracking modes in 2D CMCs have been developed based on the damage mechanism of fiber sliding relative to the matrix in the interface debonded region. The relationships between the fatigue hysteresis loops, fatigue hysteresis dissipated energy, fatigue peak stress, matrix multiple cracking modes, and interface shear stress have been established. The effects of fiber volume fraction, fatigue peak stress and matrix cracking mode proportion on fatigue hysteresis dissipated energy and interface debonding and sliding have been analyzed. The experimental fatigue hysteresis dissipated energy of 2D C/SiC and SiC/SiC composites at room temperature, 550 °C, 800 °C, and 1100 °C in air, and 1200 °C in vacuum corresponding to different fatigue peak stresses and cycle numbers have been analyzed. The interface shear stress degradation rate has been obtained through comparing the experimental fatigue hysteresis dissipated energy with theoretical values. Fatigue damage evolution in C/SiC and SiC/SiC composites has been compared using damage parameters of fatigue hysteresis dissipated energy and interface shear stress degradation rate. It was found that the interface shear stress degradation rate increases at elevated temperature in air compared with that at room temperature, decreases with increasing loading frequency at room temperature, and increases with increasing fatigue peak stress at room and elevated temperatures. PMID:28773966

[Raman spectroscopic study of binary PbO-TeO2 glasses].

PubMed

Huang, Li; You, Jing-Lin; Chen, Hui; Jiang, Guo-Chang

2008-07-01

Raman spectra of lead tellurite glasses and their melts were measured. Results show that four coordinate tellurite units convert into three coordinate units with increasing the concentration of PbO, and the number of non-bridging oxygen bonds (NBO) increases accordingly in this system. Three spectral peaks in the high frequency range were assigned to stretching vibration of bridging oxygen in four coordinate tellurite units (Q(b)), stretching vibration of non-bridging oxygen in four coordinate tellurite units (Q(nb)) and in three coordinate tellurite units (T(nb)). The relative density of four coordinate structure units decreases and the three coordinate tellurite units considerably exist in tellurite glasses when the concentration of PbO > 50%. Besides, the Raman frequencies of the three species' peaks become blue-shifted because of the temperature induced crystallization at high temperature, and the peak intensities increase and the peaks sharpen. The peaks merge together and become much broader while the glass is heated above the melting point because of multiple microstructure units coexisting.

Performance of fuel system at different diesel temperature

NASA Astrophysics Data System (ADS)

Xu, Xiaoyong; Li, Xiaolu; Sun, Zai

2010-08-01

This paper presents the findings about performance of the fuel system of a diesel engine at different diesel temperature obtained through simulation and experiment. It can be seen from these findings that at the same rotational speed of fuel pump, the initial pressure in the fuel pipe remain unchanged as the fuel temperature increases, the peak pressure at the side of fuel pipe near the injector delays, and its largest value of pressure decreases. Meanwhile, at the same temperature, as the rotational speed increases, the initial pressure of fuel pipe is also essentially the same, the arrival of its peaks delays, and its largest value of pressure increases. The maximum fuel pressure at the side of fuel pipe near the injector has an increase of 28.9 %, 22.3%, and 13.9% respectively than the previous ones according to its conditions. At the same rotational speed, as the temperature increases, the injection quantity through the nozzle orifice decreases. At the same temperature, as the rotational speed increases, the injection quantity through the nozzle orifice increases. These experimental results are consistent with simulation results.

SU-E-T-354: Peak Temperature Ratio of TLD Glow Curves to Investigate the Spatial Dependence of LET in a Clinical Proton Beam

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reft, C; Pankuch, M; Ramirez, H

Purpose: Use the ratio of the two high temperature peaks (HTR) in TLD 700 glow curves to investigate spatial dependence of the linear energy transfer (LET) in proton beams. Studies show that the relative biological effectiveness (RBE) depends upon the physical dose as well as its spatial distribution. Although proton therapy uses a spatially invariant RBE of 1.1, studies suggest that the RBE increases in the distal edge of a spread out Bragg peak (SOBP) due to the increased LET. Methods: Glow curve studies in TLD 700 show that the 280 C temperature peak is more sensitive to LET radiationmore » than the 210 C temperature peak. Therefore, the areas under the individual temperature peaks for TLDs irradiated in a proton beam normalized to the peak ratio for 6 MV photons are used to determine the HTR to obtain information on its LET. TLD 700 chips with dimensions 0.31×0.31×0.038 cc are irradiated with 90 MeV protons at varying depths in a specially designed blue wax phantom to investigate LET spatial dependence. Results: Five TLDs were placed at five different depths of the percent depth dose curve (PDD) of range 16.2 cm: center of the SOPB and approximately at the 99% distal edge, 90%, 75% and 25% of the PDD, respectively. HTR was 1.3 at the center of the SOBP and varied from 2.2 to 3.9 which can be related to an LET variation from 0.5 to 18 KeV/μ via calibration with radiation beams of varying LET. Conclusion: HTR data show a spatially invariant LET slightly greater than the 6 MV radiations in the SOBP, but a rapidly increasing LET at the end of the proton range. These results indicate a spatial variation in RBE with potential treatment consequences when selecting treatment margins to minimize the uncertainties in proton RBE.« less

Temperature dependence of Coulomb oscillations in a few-layer two-dimensional WS2 quantum dot.

PubMed

Song, Xiang-Xiang; Zhang, Zhuo-Zhi; You, Jie; Liu, Di; Li, Hai-Ou; Cao, Gang; Xiao, Ming; Guo, Guo-Ping

2015-11-05

Standard semiconductor fabrication techniques are used to fabricate a quantum dot (QD) made of WS2, where Coulomb oscillations were found. The full-width-at-half-maximum of the Coulomb peaks increases linearly with temperature while the height of the peaks remains almost independent of temperature, which is consistent with standard semiconductor QD theory. Unlike graphene etched QDs, where Coulomb peaks belonging to the same QD can have different temperature dependences, these results indicate the absence of the disordered confining potential. This difference in the potential-forming mechanism between graphene etched QDs and WS2 QDs may be the reason for the larger potential fluctuation found in graphene QDs.

Temperature dependence of Coulomb oscillations in a few-layer two-dimensional WS2 quantum dot

PubMed Central

Song, Xiang-Xiang; Zhang, Zhuo-Zhi; You, Jie; Liu, Di; Li, Hai-Ou; Cao, Gang; Xiao, Ming; Guo, Guo-Ping

2015-01-01

Standard semiconductor fabrication techniques are used to fabricate a quantum dot (QD) made of WS2, where Coulomb oscillations were found. The full-width-at-half-maximum of the Coulomb peaks increases linearly with temperature while the height of the peaks remains almost independent of temperature, which is consistent with standard semiconductor QD theory. Unlike graphene etched QDs, where Coulomb peaks belonging to the same QD can have different temperature dependences, these results indicate the absence of the disordered confining potential. This difference in the potential-forming mechanism between graphene etched QDs and WS2 QDs may be the reason for the larger potential fluctuation found in graphene QDs. PMID:26538164

Peak Metamorphic Temperature Profile across Eastern Belt Franciscan, Northern California Coast Ranges

NASA Astrophysics Data System (ADS)

Schmidt, W. L.; Platt, J. P.

2017-12-01

Previous work done on metamorphic temperatures across the lawsonite-albite to blueschist facies rocks of the Eastern Belt of the Franciscan accretionary complex has relied on a combination of many methods, and suggests that temperature broadly increases from west to east. The Taliaferro Metamorphic Complex is an exception to this pattern and shows higher pressures, and possibly higher temperatures, than its surroundings. The exact location and nature of the faults separating accreted packets in the Eastern Belt is somewhat controversial. A recently calibrated low-temperature laser Raman geothermometer for use on carbonaceous material provides a uniform method of estimating peak metamorphic temperature across the eastern Franciscan and is here used to identify the position of major tectonic boundaries. Temperatures were obtained from exposures in Thomes Creek, Cottonwood Creek, Grindstone Creek, and the middle fork of the Eel River. Peak T in the South Fork Mountain Schist, the highest grade and easternmost unit in the Franciscan, is 310-375°C, whereas in immediately underlying lawsonite-albite facies rocks below the Log Springs thrust, peak T is 270 - 300°C. The Taliaferro Metamorphic Complex reached a peak temperature of 336°C, whereas the surrounding lawsonite-albite facies rocks yield peak temperatures as low as 232°C. Preliminary temperature profiles clearly allow the major faults bounding the Taliaferro Metamorphic Complex and the South Fork Mountain Schist to be located. Extension of the temperature profile has the potential to reveal further detail within these units and the lower grade rocks surrounding them.

Effects of high temperature after pollination on physicochemical properties of waxy maize flour during grain development.

PubMed

Lu, Dalei; Cai, Xuemei; Yan, Fabao; Sun, Xuli; Wang, Xin; Lu, Weiping

2014-05-01

Waxy maize is grown in South China, where high temperatures frequently prevail. The effect of high-temperature stress on grain development of waxy maize is not known. High temperature decreased the grain fresh weight and volume, and lowered the grain dry weight and water content after 22 days after pollination (DAP). Plants exposed to high temperature had low starch content, and high protein and soluble sugar contents at maturity. Starch iodine binding capacity and granule size were increased by heat stress at all grain-filling stages. The former parameter decreased, while the latter parameter increased gradually with grain development. High temperature increased the peak and breakdown viscosity before 30 DAP, but the value decreased at maturity. Pasting and gelatinization temperatures at different stages were increased by heat stress and gradually decreased with grain development under both high-temperature and control conditions. Gelatinization enthalpy increased initially but decreased after peaking at 22 DAP under both control and heat stress conditions. High temperature decreased gelatinization enthalpy after 10 DAP. Retrogradation percentage value increased with high temperature throughout grain development. High temperature after pollination changes the dynamics of grain filling of waxy maize, which may underlie the observed changes in its pasting and thermal properties. © 2013 Society of Chemical Industry.

The effect of temperature and body weight on the routine metabolic rate and postprandial metabolic response in mulloway, Argyrosomus japonicus.

PubMed

Pirozzi, Igor; Booth, Mark A

2009-09-01

Specific dynamic action (SDA) is the energy expended on the physiological processes associated with meal digestion and is strongly influenced by the characteristics of the meal and the body weight (BW) and temperature of the organism. This study assessed the effects of temperature and body weight on the routine metabolic rate (RMR) and postprandial metabolic response in mulloway, Argyrosomus japonicus. RMR and SDA were established at 3 temperatures (14, 20 and 26 degrees C). 5 size classes of mulloway ranging from 60 g to 1.14 kg were used to establish RMR with 3 of the 5 size classes (60, 120 and 240 g) used to establish SDA. The effect of body size on the mass-specific RMR (mg O(2) kg(-1) h(-1)) varied significantly depending on the temperature; there was a greater relative increase in the mass-specific RMR for smaller mulloway with increasing temperature. No statistical differences were found between the mass exponent (b) values at each temperature when tested against H(0): b=0.8. The gross RMR of mulloway (mg O(2) fish(-1) h(-1)) can be described as function of temperature (T; 14-26 degrees C) as: (0.0195T-0.0454)BW(g)(0.8) and the mass-specific RMR (mg O(2) kg(-1) h(-1)) can be described as: (21.042T-74.867)BW(g)(-0.2). Both SDA duration and time to peak SDA were influenced by temperature and body weight; SDA duration occurred within 41-89 h and peak time occurred within 17-38 h of feeding. The effect of body size on peak metabolic rate varied significantly depending on temperature, generally increasing with temperature and decreasing with increasing body size. Peak gross oxygen consumption (MO(2): mg O(2) fish(-1) h(-1)) scaled allometrically with BW. Temperature, but not body size, significantly affected SDA scope, although the difference was numerically small. There was a trend for MO(2) above RMR over the SDA period to increase with temperature; however, this was not statistically significant. The average proportion of energy expended over the SDA period (SDA coefficient) ranged from approximately 7-13% of the total DE intake while the proportion of total energy expended on SDA above RMR ranged from approximately 16-27%.

Method transfer from high-pressure liquid chromatography to ultra-high-pressure liquid chromatography. II. Temperature and pressure effects.

PubMed

Åsberg, Dennis; Samuelsson, Jörgen; Leśko, Marek; Cavazzini, Alberto; Kaczmarski, Krzysztof; Fornstedt, Torgny

2015-07-03

The importance of the generated temperature and pressure gradients in ultra-high-pressure liquid chromatography (UHPLC) are investigated and compared to high-pressure liquid chromatography (HPLC). The drug Omeprazole, together with three other model compounds (with different chemical characteristics, namely uncharged, positively and negatively charged) were used. Calculations of the complete temperature profile in the column at UHPLC conditions showed, in our experiments, a temperature difference between the inlet and outlet of 16 °C and a difference of 2 °C between the column center and the wall. Through van't Hoff plots, this information was used to single out the decrease in retention factor (k) solely due to the temperature gradient. The uncharged solute was least affected by temperature with a decrease in k of about 5% while for charged solutes the effect was more pronounced, with k decreases up to 14%. A pressure increase of 500 bar gave roughly 5% increase in k for the uncharged solute, while omeprazole and the other two charged solutes gave about 25, 20 and 15% increases in k, respectively. The stochastic model of chromatography was applied to estimate the dependence of the average number of adsorption/desorption events (n) and the average time spent by a molecule in the stationary phase (τs) on temperature and pressure on peak shape for the tailing, basic solute. Increasing the temperature yielded an increase in n and decrease in τs which resulted in less skew at high temperatures. With increasing pressure, the stochastic modeling gave interesting results for the basic solute showing that the skew of the peak increased with pressure. The conclusion is that pressure effects are more pronounced for both retention and peak shape than the temperature effects for the polar or charged compounds in our study. Copyright © 2015 Elsevier B.V. All rights reserved.

Effect of annealing temperature and dopant concentration on the thermoluminescence sensitivity in LiF:Mg,Cu,Ag material.

PubMed

Yahyaabadi, Akram; Torkzadeh, Falamarz; Rezaei Ochbelagh, Dariush; Hosseini Pooya, Seyed Mahdi

2018-04-24

LiF:Mg,Cu,Ag is a new dosimetry material that is similar to LiF:Mg,Cu,P in terms of dosimetric properties. The effect of the annealing temperature in the range of 200 to 350°C on the thermoluminescence (TL) sensitivity and the glow curve structure of this material at different concentrations of silver (Ag) was investigated. It has been demonstrated that the optimum values of the annealing temperature and the Ag concentration are 240°C and 0.1 mol% for better sensitivity, respectively. The TL intensity decreases at annealing temperatures lower than 240°C or higher than 240°C, reaching a minimum at 300°C and then again increases for various Ag concentrations. It was observed that the glow curve structure altered and the area under the low temperature peak as well as the area under the main dosimetric peak decreased with increasing annealing temperature. The position of the main dosimetric peak moved in the direction of higher temperatures, but at 320 and 350°C annealing temperatures, it shifted to lower temperatures. It was also observed that the TL sensitivity could partially be recovered by a combined annealing procedure. Copyright © 2018 John Wiley & Sons, Ltd.

[Acidity and temperature effect on the fluorescence characteristics of hydraulic oils and lubricants].

PubMed

Deng, Hu; Zhou, Xun; Shang, Li-ping; Zhang, Ze-lin; Wang, Shun-li

2014-12-01

By analyzing HyJet V phosphate ester hydraulic oil environmental impacts (oil, etc.) and confounding factors (pH, temperature, etc.), the feasibility was studied for the fluorescence detection of aircraft hydraulic oil leaks. By using the fluorescence spectrophotometer at various acidities and temperatures, the fluorescence properties of HyJet V phosphate ester hydraulic oil, Jet Oil II lubricant and 2197 lubricant were gained. The experimental results are shown as following: The fluorescence peaks of HyJet V phosphate ester hydraulic oil, Jet Oil II lubricant and 2197 lubricant are at 362, 405 and 456 nm, respectively. The impact of temperature on HyJet V phosphate ester hydraulic oil is less effective; Jet Oil II lubricant and 2197 lubricant fluorescence intensity decreases with increasing temperature. When acidity increases, the fluorescence peak of HyJet V phosphate ester hydraulic oil gradient shifts from 370 to 362 nm, and the fluorescence intensity decreases; the fluorescence peak of Jet Oil II lubricant is always 405 nm, while the fluorescence intensity decreases; the fluorescence peak of 2197 lubricant at 456 nm red shifts to 523 nm, and double fluorescence peaks appeare. The results are shown as following: under the influence of the environment and interference factors, the fluorescence characteristics of HyJet V phosphate ester hydraulic oil remain unchanged, and distinguish from Jet Oil II lubricant and 2197 lubricant. Therefore, the experiments indicate that the detection of HyJet V phosphate ester hydraulic oil leak is feasible by using fluorescence method.

Impulsive excitation of mechanoluminescence in gamma-irradiated CaSO4:Eu phosphors

NASA Astrophysics Data System (ADS)

Kher, R. S.; Dhoble, S. J.; Pandey, R. K.; Upadhyay, A. K.; Khokhar, M. S. K.

2011-01-01

The mechanoluminescence (ML) and thermoluminescence (TL) of γ-irradiated CaSO4:Eu phosphor have been studied. CaSO4 samples having different concentrations of Eu were prepared by dissolving CaSO4.2H2O in sulphuric acid and evaporating the excess acid around 300 °C. ML was excited impulsively by dropping a load onto the sample. Three distinct peaks have been observed in the ML intensity versus time curve. The ML intensity increases with the increasing concentration of the dopant. The effect of temperature on the shape and peak of ML intensity was also recorded. Growth, saturation and broadening in an ML peak were observed. TL glow curves of CaSO4:Eu phosphors at different concentrations contain two TL peaks: the first peak was observed at around 110 °C and the other at 210 °C. Experimental results suggest that the ML excitation is related to the movement of dislocation with defect centres, the increase in ML with temperature is due to the enhancement in dislocation capture probability, and the reduction is due to the thermal bleaching of defect centres.

Improved measurement of carbonaceous aerosol in Beijing, China: intercomparison of sampling and thermal-optical analysis methods

NASA Astrophysics Data System (ADS)

Cheng, Y.; He, K. B.; Duan, F. K.; Zheng, M.; Ma, Y. L.; Tan, J. H.; Du, Z. Y.

2010-06-01

The sampling artifacts (both positive and negative) and the influence of thermal-optical methods (both charring correction method and the peak inert mode temperature) on the split of organic carbon (OC) and elemental carbon (EC) were evaluated in Beijing. The positive sampling artifact constituted 10% and 23% of OC concentration determined by the bare quartz filter during winter and summer, respectively. For summer samples, the adsorbed gaseous organics were found to continuously evolve off the filter during the whole inert mode when analyzed by the IMPROVE-A temperature protocol. This may be due to the oxidation of the adsorbed organics during sampling (reaction artifact) which would increase their thermal stability. The backup quartz approach was evaluated by a denuder-based method for assessing the positive artifact. The quartz-quartz (QBQ) in series method was demonstrated to be reliable, since all of the OC collected by QBQ was from originally gaseous organics. Negative artifact that could be adsorbed by quartz filter was negligible. When the activated carbon impregnated glass fiber (CIG) filter was used as the denuded backup filter, the denuder efficiency for removing gaseous organics that could be adsorbed by the CIG filter was only about 30%. EC values were found to differ by a factor of about two depending on the charring correction method. Influence of the peak inert mode temperature was evaluated based on the summer samples. The EC value was found to continuously decrease with the peak inert mode temperature. Premature evolution of light absorbing carbon began when the peak inert mode temperature was increased from 580 to 650 °C; when further increased to 800 °C, the OC and EC split frequently occurred in the He mode, and the last OC peak was characterized by the overlapping of two separate peaks. The discrepancy between EC values defined by different temperature protocols was larger for Beijing carbonaceous aerosol compared with North America and Europe, perhaps due to the higher concentration of brown carbon in Beijing aerosol.

Pulsed Nd:YAG laser welding of cardiac pacemaker batteries with reduced heat input

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuerschbach, P.W.; Hinkley, D.A.

1997-03-01

The effects of Nd:YAG laser beam welding process parameters on the resulting heat input in 304L stainless steel cardiac pacemaker batteries have been studied. By careful selection of process parameters, the results can be used to reduce temperatures near glass-to-metal seals and assure hermeticity in laser beam welding of high reliability components. Three designed response surface experiments were used to compare welding performance with lenses of varying focal lengths. The measured peak temperatures at the glass-to-metal seals varied from 65 to 140 C (149 to 284 F) and depended strongly on the levels of the experimental factors. It was foundmore » that welds of equivalent size can be made with significantly reduced temperatures. The reduction in battery temperatures has been attributed to an increase in the melting efficiency. This increase is thought to be due primarily to increased travel speeds, which were facilitated by high peak powers and low pulse energies. For longer focal length lenses, weld fusion zone widths were found to be greater even without a corresponding increase in the size of the weld. It was also found that increases in laser beam irradiance either by higher peak powers or smaller spot sizes created deeper and larger welds. These gains were attributed to an increase in the laser energy transfer efficiency.« less

Enhanced Raman Scattering from InSb Nanodots; Temperature and Laser-Power Dependent Studies

NASA Astrophysics Data System (ADS)

Wada, Noboru; Takayama, Haruki; Morohashi, Satoshi

2010-03-01

InSb nanodots were uniquely fabricated by vapor-transport on a Si substrate which had previously been bombarded by FBI Ga ions. The InSb nanodots were then examined by spatially-resolved Raman scattering using an Ar-ion laser (λ= 514.5 and 488 nm with P=1˜15 mW) with an optical microscope and CCD detector. In addition to the TO and LO peaks of InSb observed at ˜180 and 191 cm-1 respectively, two peaks were observed at ˜110 and 150 cm-1. Those Raman peaks were tentatively attributed to the 2TA and TO-TA second-order Raman processes. Those two peak intensities appeared to grow at the expense of the TO and LO Raman peak intensities with increasing the sample temperature from 10 K to 450 K. Also, the two-phonon peak intensities increased non-linearly with the probing laser power used. Hot carriers and their interactions with phonons in the restricted regions will be discussed together with Raman scattering results obtained from single-crystal InSb.

Effect of annealing temperature on the structural and optical properties of CeO{sub 2}:Ni thin films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Murugan, R.; Vijayaprasath, G.; Sakthivel, P.

2016-05-06

High quality Ni-doped CeO{sub 2} (CeO{sub 2}:Ni) thin films were deposited on glass substrates at room temperature by using radio frequency magnetron sputtering. The effect of annealing temperature on structural and optical properties of the CeO{sub 2}:Ni films was investigated. The structural, optical and vibrational properties of the films were determined using X-ray diffraction (XRD), photoluminescence spectrometer (PL) and Raman spectrometer. It was found that the as-deposited film has a fluorite cubic structure. By increasing annealing temperature from 100°C to 300°C, the crystalline quality of the thin films could be improved. The UV and visible band emissions were observed inmore » the photoluminescence spectra, due to exciton, defect related emissions respectively. The micro-Raman results show the characteristic peak of CeO{sub 2} F{sub 2g} at 465 cm{sup −1} and 2L0 at 1142 cm{sup −1}. Defect peaks like D and 0 bands were observed at 641 cm{sup −1} and 548 cm{sup −1} respectively. It is found from the spectra that the peak intensity of the films increased with increase of annealing temperature.« less

The Cooling History and Structure of the Ordinary Chondrite Parent Bodies

NASA Technical Reports Server (NTRS)

Benoit, P. H.; Sears, D. W. G.

1996-01-01

Most major meteorite classes exhibit significant ranges of metamorphism. The effects of metamorphism have been extensively characterized, but the heat source(s) and the metamorphic environment are unknown. Proposed beat sources include Al-26, Fe-60, electromagnetic induction, and impact. It is typically assumed that metamorphism occurred in parent bodies of some sort, but it uncertain whether these bodies were highly structured ("onion skins") or were chaotic mixes of material ("rubble piles"). The lack of simple trends of metallographic cooling rates with petrologic type has been considered supportive of both concepts. In this study, we use induced thermoluminescence (TL) as an indicator of thermal history. The TL of ordinary chondrites is produced by sodic feldspar, and the induced TL peak temperature is related to its crystallographic order/disorder. Ordered feldspar has TL peak temperatures of approx. 120 C, and disordered feldspar has TL peak temperatures of approx. 220 C. While ordered feldspar can be easily disordered in the laboratory by heating above 650 C and is easily quenched in the disordered form, producing ordered feldspar requires cooling at geologic cooling rates. We have measured the induced TL properties of 101 equilibrated ordinary chondrites, including 49 H, 29 L, and 23 LL chondrites. For the H chondrites there is an apparent trend of decreasing induced TL peak temperature with increasing petrologic type. H4 chondrites exhibit a tight range of TL peak temperatures, 190 C - 200 C, while H6 chondrites exhibit TL peak temperatures between 180 C and 190 C. H5 chondrites cover the range between H4 and H6, and also extend up to 210 C. Similar results are obtained for LL chondfiles and most L6 chondrites have lower induced TL peak temperatures than L5 chondrites.

Effect of daily fluctuations in ambient temperature on reproductive failure traits of Landrace and Yorkshire sows under Thai tropical environmental conditions.

PubMed

Jaichansukkit, Teerapong; Suwanasopee, Thanathip; Koonawootrittriron, Skorn; Tummaruk, Padet; Elzo, Mauricio A

2017-03-01

The aim of this study was to determine the effects of daily ranges and maximum ambient temperatures, and other risk factors on reproductive failure of Landrace (L) and Yorkshire (Y) sows under an open-house system in Thailand. Daily ambient temperatures were added to information on 35,579 litters from 5929 L sows and 1057 Y sows from three commercial herds. The average daily temperature ranges (ADT) and the average daily maximum temperatures (PEAK) in three gestation periods from the 35th day of gestation to parturition were classified. The considered reproductive failure traits were the occurrences of mummified fetuses (MM), stillborn piglets (STB), and piglet death losses (PDL) and an indicator trait for number of piglets born alive below the population mean (LBA). A multiple logistic regression model included farrowing herd-year-season (HYS), breed group of sow (BG), parity group (PAR), number of total piglets born (NTB), ADT1, ADT2, ADT3, PEAK1, PEAK2, and PEAK3 as fixed effects, while random effects were animal, repeated observations, and residual. Yorkshire sows had a higher occurrence of LBA than L sows (P = 0.01). The second to fifth parities sows had lower reproductive failures than other parities. The NTB regression coefficients of log-odds were positive (P < 0.01) for all traits. Narrower ranges of ADT3 increased the occurrence of MM, STB, and PDL (P < 0.01), while higher PEAK3 increased the occurrence of MM, STB, PDL, and LBA (P < 0.001). To reduce the risk of reproductive failures, particularly late in gestation, producers would need to closely monitor their temperature management strategies.

Effects of an advanced temperature cycle on smolt development and endocrinology indicate that temperature is not a zeitgeber for smolting in Atlantic salmon

USGS Publications Warehouse

McCormick, S.D.; Shrimpton, J.M.; Moriyama, S.; Bjornsson, Bjorn Thrandur

2002-01-01

Atlantic salmon (Salmo salar) juveniles were reared under simulated conditions of normal photoperiod (LDN) or short days (LD 9:15) and ambient temperature (AMB: normal temperature increases in April) or an advanced temperature cycle (ADV: temperature increases in February). Under both photoperiod conditions, the timing of increased and peak levels of gill Na+,K+-ATPase activity were not altered by temperature, although the rate of increase was initially greater under ADV. ADV/LD 9:15 resulted in peak gill Na+,K+-ATPase activity that was half of that seen under normal photoperiod and temperature conditions. Plasma growth hormone (GH) levels increased threefold in late March under ADV/LDN, but not under ADV/LD 9:15, indicating that there is a photoperiod-dependent effect of temperature on levels of this hormone. Plasma insulin-like growth factor I (IGF-I) increased in spring in all groups, with increases occurring significantly earlier in the ADV/LDN group. In each photoperiod condition, the advanced temperature cycle resulted in large decreases in plasma thyroxine (T4) levels in March, which subsequently recovered, whereas plasma 3,5,3???-triiodo-L-thyronine (T3) levels were not substantially affected by either photoperiod or temperature. There was no consistent pattern of change in plasma cortisol levels. The results do not provide support for the role of temperature as a zeitgeber, but do indicate that temperature has a role in the timing of smolting by affecting the rate of development and interacting with the photoperiod.

The temperature dependent amide I band of crystalline acetanilide

NASA Astrophysics Data System (ADS)

Cruzeiro, Leonor; Freedman, Holly

2013-10-01

The temperature dependent anomalous peak in the amide I band of crystalline acetanilide is thought to be due to self-trapped states. On the contrary, according to the present model, the anomalous peak comes from the fraction of ACN molecules strongly hydrogen-bonded to a neighboring ACN molecule, and its intensity decreases because, on average, this fraction decreases as temperature increases. This model provides, for the first time, an integrated and theoretically consistent view of the temperature dependence of the full amide I band and a qualitative explanation of some of the features of nonlinear pump-probe experiments.

Thermoluminescence solid-state nanodosimetry—the peak 5A/5 dosemeter

PubMed Central

Fuks, E.; Horowitz, Y. S.; Horowitz, A.; Oster, L.; Marino, S.; Rainer, M.; Rosenfeld, A.; Datz, H.

2011-01-01

The shape of composite peak 5 in the glow curve of LiF:Mg,Ti (TLD-100) following 90Sr/90Y beta irradiation, previously demonstrated to be dependent on the cooling rate used in the 400°C pre-irradiation anneal, is shown to be dependent on ionisation density in both naturally cooled and slow-cooled samples. Following heavy-charged particle high-ionisation density (HID) irradiation, the temperature of composite peak 5 decreases by ∼5°C and the peak becomes broader. This behaviour is attributed to an increase in the relative intensity of peak 5a (a low-temperature satellite of peak 5). The relative intensity of peak 5a is estimated using a computerised glow curve deconvolution code based on first-order kinetics. The analysis uses kinetic parameters for peaks 4 and 5 determined from ancillary measurements resulting in nearly ‘single-glow peak’ curves for both the peaks. In the slow-cooled samples, owing to the increased relative intensity of peak 5a compared with the naturally cooled samples, the precision of the measurement of the 5a/5 intensity ratio is found to be ∼15 % (1 SD) compared with ∼25 % for the naturally cooled samples. The ratio of peak 5a/5 in the slow-cooled samples is found to increase systematically and gradually through a variety of radiation fields from a minimum value of 0.13±0.02 for 90Sr/90Y low-ionisation density irradiations to a maximum value of ∼0.8 for 20 MeV Cu and I ion HID irradiations. Irradiation by low-energy electrons of energy 0.1–1.5 keV results in values between 1.27 and 0.95, respectively. The increasing values of the ratio of peak 5a/5 with increasing ionisation density demonstrate the viability of the concept of the peak 5a/5 nanodosemeter and its potential in the measurement of average ionisation density in a ‘nanoscopic’ mass containing the trapping centre/luminescent centre spatially correlated molecule giving rise to composite peak 5. PMID:21149323

Fiber-optic thermometry using thermal radiation from Tm end doped SiO{sub 2} fiber sensor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Morita, Kentaro; Katsumata, Toru; Komuro, Shuji

2014-04-15

Fiber-optic thermometry based on temperature dependence of thermal radiation from Tm{sup 3+} ions was studied using Tm end doped SiO{sub 2} fiber sensor. Visible light radiation peaks due to f-f transition of Tm{sup 3+} ion were clearly observed at λ = 690 and 790 nm from Tm end doped SiO{sub 2} fibers sensor at the temperature above 600 °C. Thermal radiation peaks are assigned with f-f transition of Tm{sup 3+} ion, {sup 1}D{sub 2}-{sup 3}H{sub 6}, and {sup 1}G{sub 4}-{sup 3}H{sub 6}. Peak intensity of thermal radiation from Tm{sup 3+} ion increases with temperature. Intensity ratio of thermal radiation peaks atmore » λ = 690 nm against that at λ = 790 nm, I{sub 790/690}, is suitable for the temperature measurement above 750 °C. Two-dimensional temperature distribution in a flame is successfully evaluated by Tm end doped SiO{sub 2} fiber sensor.« less

Fingerprinting malathion vapor: a simulant for VX nerve agent

NASA Astrophysics Data System (ADS)

Song, Renbo; Ding, Yujie J.; Zotova, Ioulia B.

2008-04-01

Being motivated by the possibility of fingerprinting and detecting VX nerve agent, we have investigated its stimulant, i.e. malathion vapor, which is less toxic and commercially available, in the far-infrared/THz transition region and THz frequency range. Such a spectroscopic study was carried out by using Fourier transform infrared spectroscopy (FTIR). Our intention is to obtain a specific spectroscopic signature of VX nerve agent as a chemical warfare agent. Following our experimental result, we have successfully observed eleven new absorption peaks from malathion vapor in the spectral ranges from 15 cm -1 to 68 cm -1 and from 75 cm -1 to 640 cm -1. Specifically, in the far-infrared/THz transition region, we have observed eight peaks and whereas in the THz region we have identified three relatively weak transition peaks. In addition, we have investigated the dependence of the absorption spectra on temperature in the range from room temperature to 60°C. In both of the frequency ranges, we have found that absorption coefficients significantly increase with increasing temperature. By comparing the transition peaks in the two frequency ranges, we have concluded that the frequency range of 400-640cm -1 is an optimal range for fingerprinting this chemical specie. We have designated two peaks for effectively and accurately identifying the VX nerve agents and one peak for differentiating between malathion and VX nerve agent.

Changes in divertor conditions in response to changing core density with RMPs

DOE PAGES

Briesemeister, Alexis R.; Ahn, Joon -Wook; Canik, John M.; ...

2017-06-07

The effects of changes in core density on divertor electron temperature, density and heat flux when resonant magnetic perturbations (RMPs) are applied are presented, notably a reduction in RMP induced secondary radial peaks in the electron temperature profile at the target plate is observed when the core density is increased, which is consistent with modeling. RMPs is used here to indicated non-axisymmetric magnetic field perturbations, created using in-vessel control coils, which have components which has at least one but typically many resonances with the rotational transform of the plasma. RMPs are found to alter inter-ELM heat flux to the divertormore » by modifying the core plasma density. It is shown that applying RMPs reduces the core density and increases the inter-ELM heat flux to both the inner and outer targets. Using gas puffing to return the core density to the pre-RMP levels more than eliminates the increase in inter-ELM heat flux, but a broadening of the heat flux to the outer target remains. These measurements were made at a single toroidal location, but the peak in the heat flux profile was found near the outer strike point where simulations indicate little toroidal variation should exist and tangentially viewing diagnostics showed no evidence of strong asymmetries. In experiments where divertor Thomson scattering measurements were available it is shown that, local secondary peaks in the divertor electron temperature profile near the target plate are reduced as the core density is increased, while peaks in the divertor electron density profile near the target are increased. Furthermore, these trends observed in the divertor electron temperature and density are qualitatively reproduced by scanning the upstream density in EMC3-Eirene modeling. Measurements are presented showing that higher densities are needed to induce detachment of the outer strike point in a case where an increase in electron temperature, likely due to a change in MHD activity, is seen after RMPs are applied.« less

Changes in divertor conditions in response to changing core density with RMPs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Briesemeister, Alexis R.; Ahn, Joon -Wook; Canik, John M.

The effects of changes in core density on divertor electron temperature, density and heat flux when resonant magnetic perturbations (RMPs) are applied are presented, notably a reduction in RMP induced secondary radial peaks in the electron temperature profile at the target plate is observed when the core density is increased, which is consistent with modeling. RMPs is used here to indicated non-axisymmetric magnetic field perturbations, created using in-vessel control coils, which have components which has at least one but typically many resonances with the rotational transform of the plasma. RMPs are found to alter inter-ELM heat flux to the divertormore » by modifying the core plasma density. It is shown that applying RMPs reduces the core density and increases the inter-ELM heat flux to both the inner and outer targets. Using gas puffing to return the core density to the pre-RMP levels more than eliminates the increase in inter-ELM heat flux, but a broadening of the heat flux to the outer target remains. These measurements were made at a single toroidal location, but the peak in the heat flux profile was found near the outer strike point where simulations indicate little toroidal variation should exist and tangentially viewing diagnostics showed no evidence of strong asymmetries. In experiments where divertor Thomson scattering measurements were available it is shown that, local secondary peaks in the divertor electron temperature profile near the target plate are reduced as the core density is increased, while peaks in the divertor electron density profile near the target are increased. Furthermore, these trends observed in the divertor electron temperature and density are qualitatively reproduced by scanning the upstream density in EMC3-Eirene modeling. Measurements are presented showing that higher densities are needed to induce detachment of the outer strike point in a case where an increase in electron temperature, likely due to a change in MHD activity, is seen after RMPs are applied.« less

Theoretical study of thermoelectric properties of few-layer MoS2 and WSe2.

PubMed

Huang, Wen; Luo, Xin; Gan, Chee Kwan; Quek, Su Ying; Liang, Gengchiau

2014-06-14

Molybdenum disulfide (MoS2) and tungsten diselenide (WSe2) are prototypical layered two-dimensional transition metal dichalcogenide materials, with each layer consisting of three atomic planes. We refer to each layer as a trilayer (TL). We study the thermoelectric properties of 1-4TL MoS2 and WSe2 using a ballistic transport approach based on the electronic band structures and phonon dispersions obtained from first-principles calculations. Our results show that the thickness dependence of the thermoelectric properties is different under n-type and p-type doping conditions. Defining ZT1st peak as the first peak in the thermoelectric figure of merit ZT as doping levels increase from zero at 300 K, we found that ZT1st peak decreases as the number of layers increases for MoS2, with the exception of 2TL in n-type doping, which has a slightly higher value than 1TL. However, for WSe2, 2TL has the largest ZT1st peak in both n-type and p-type doping, with a ZT1st peak value larger than 1 for n-type WSe2. At high temperatures (T > 300 K), ZT1st peak dramatically increases when the temperature increases, especially for n-type doping. The ZT1st peak of n-type 1TL-MoS2 and 2TL-WSe2 can reach 1.6 and 2.1, respectively.

On-sun testing of an advanced falling particle receiver system

NASA Astrophysics Data System (ADS)

Ho, Clifford K.; Christian, Joshua M.; Yellowhair, Julius; Siegel, Nathan; Jeter, Sheldon; Golob, Matthew; Abdel-Khalik, Said I.; Nguyen, Clayton; Al-Ansary, Hany

2016-05-01

A 1 MWth high-temperature falling particle receiver was constructed and tested at the National Solar Thermal Test Facility at Sandia National Laboratories. The continuously recirculating system included a particle elevator, top and bottom hoppers, and a cavity receiver that comprised a staggered array of porous chevron-shaped mesh structures that slowed the particle flow through the concentrated solar flux. Initial tests were performed with a peak irradiance of ~300 kW/m2 and a particle mass flow rate of 3.3 kg/s. Peak particle temperatures reached over 700 °C near the center of the receiver, but the particle temperature increase near the sides was lower due to a non-uniform irradiance distribution. At a particle inlet temperature of ~440 °C, the particle temperature increase was 27 °C per meter of drop length, and the thermal efficiency was ~60% for an average irradiance of 110 kW/m2. At an average irradiance of 211 kW/m2, the particle temperature increase was 57.1 °C per meter of drop length, and the thermal efficiency was ~65%. Tests with higher irradiances are being performed and are expected to yield greater particle temperature increases and efficiencies.

Association between temperature and death in residential populations in Shanghai

NASA Astrophysics Data System (ADS)

Hsia, L. B.; Lu, J. K.

1988-03-01

The study is focused on patterns of daily deaths in Shanghai for the period from 1 May 1979 to 30 April 1980. From May to September the deaths in all age groups are lower, but increase gradually from October and reach to a peak in February. This confirms results found in other countries, namely the death rate is increased in winter. The peak for the population aged over 70 is the highest of the three different age groups. Correlation analyses were carried out on three temperature parameters (daily minimum, maximum and mean temperatures) and six categories of death (heart disease, coronary heart disease, cerebrovascular disease, cancer, respiratory disease and total deaths). The results reveal that the average daily temperature is very significant for the six categories of death. There are three correlations: straight line relationship, parabolic relationship and exponential relationship. These different types arise from the different morbidity rates. Death from the different disease is also increased during days when the daily maximum temperature is over 35° C or the daily minimum temperature is below 0°C. This shows, in general, that days of extreme temperature lead to an increase in the death rate.

[Study of the effect of heat source separation distance on plasma physical properties in laser-pulsed GMAW hybrid welding based on spectral diagnosis technique].

PubMed

Liao, Wei; Hua, Xue-Ming; Zhang, Wang; Li, Fang

2014-05-01

In the present paper, the authors calculated the plasma's peak electron temperatures under different heat source separation distance in laser- pulse GMAW hybrid welding based on Boltzmann spectrometry. Plasma's peak electron densities under the corresponding conditions were also calculated by using the Stark width of the plasma spectrum. Combined with high-speed photography, the effect of heat source separation distance on electron temperature and electron density was studied. The results show that with the increase in heat source separation distance, the electron temperatures and electron densities of laser plasma did not changed significantly. However, the electron temperatures of are plasma decreased, and the electron densities of are plasma first increased and then decreased.

Climate change is projected to have severe impacts on the frequency and intensity of peak electricity demand across the United States.

PubMed

Auffhammer, Maximilian; Baylis, Patrick; Hausman, Catherine H

2017-02-21

It has been suggested that climate change impacts on the electric sector will account for the majority of global economic damages by the end of the current century and beyond [Rose S, et al. (2014) Understanding the Social Cost of Carbon: A Technical Assessment ]. The empirical literature has shown significant increases in climate-driven impacts on overall consumption, yet has not focused on the cost implications of the increased intensity and frequency of extreme events driving peak demand, which is the highest load observed in a period. We use comprehensive, high-frequency data at the level of load balancing authorities to parameterize the relationship between average or peak electricity demand and temperature for a major economy. Using statistical models, we analyze multiyear data from 166 load balancing authorities in the United States. We couple the estimated temperature response functions for total daily consumption and daily peak load with 18 downscaled global climate models (GCMs) to simulate climate change-driven impacts on both outcomes. We show moderate and heterogeneous changes in consumption, with an average increase of 2.8% by end of century. The results of our peak load simulations, however, suggest significant increases in the intensity and frequency of peak events throughout the United States, assuming today's technology and electricity market fundamentals. As the electricity grid is built to endure maximum load, our findings have significant implications for the construction of costly peak generating capacity, suggesting additional peak capacity costs of up to 180 billion dollars by the end of the century under business-as-usual.

Evaluation of centrifugal compressor performance with water injection

NASA Technical Reports Server (NTRS)

Beede, William L; Hamrick, Joseph T; Withee, Joseph R , Jr

1951-01-01

The effects of water injection on a compressor are presented. To determine the effects of varying water-air ratio, the compressor was operated at a constant equivalent impeller speed over a range of water-air ratios and weight flows. Operation over a range of weight flows at one water-air ratio and two inlet air temperatures was carried out to obtain an indication of the effects of varying inlet air temperature. Beyond a water-air ratio of 0.03 there was no increase in maximum air-weight flow, a negligible rise in peak total-pressure ratio, and a decrease in peak adiabatic efficiency. An increase in inlet air temperature resulted in an increase in the magnitude of evaporation. An analysis of data indicated that the magnitude of evaporation within the compressor impeller was small.

QCD phase transition with chiral quarks and physical quark masses.

PubMed

Bhattacharya, Tanmoy; Buchoff, Michael I; Christ, Norman H; Ding, H-T; Gupta, Rajan; Jung, Chulwoo; Karsch, F; Lin, Zhongjie; Mawhinney, R D; McGlynn, Greg; Mukherjee, Swagato; Murphy, David; Petreczky, P; Renfrew, Dwight; Schroeder, Chris; Soltz, R A; Vranas, P M; Yin, Hantao

2014-08-22

We report on the first lattice calculation of the QCD phase transition using chiral fermions with physical quark masses. This calculation uses 2+1 quark flavors, spatial volumes between (4 fm)(3) and (11 fm)(3) and temperatures between 139 and 196 MeV. Each temperature is calculated at a single lattice spacing corresponding to a temporal Euclidean extent of N(t) = 8. The disconnected chiral susceptibility, χ(disc) shows a pronounced peak whose position and height depend sensitively on the quark mass. We find no metastability near the peak and a peak height which does not change when a 5 fm spatial extent is increased to 10 fm. Each result is strong evidence that the QCD "phase transition" is not first order but a continuous crossover for m(π) = 135 MeV. The peak location determines a pseudocritical temperature T(c) = 155(1)(8) MeV, in agreement with earlier staggered fermion results. However, the peak height is 50% greater than that suggested by previous staggered results. Chiral SU(2)(L) × SU(2)(R) symmetry is fully restored above 164 MeV, but anomalous U(1)(A) symmetry breaking is nonzero above T(c) and vanishes as T is increased to 196 MeV.

Protein synthesis and specific dynamic action in crustaceans: effects of temperature.

PubMed

Whiteley, N M; Robertson, R F; Meagor, J; El Haj, A J; Taylor, E W

2001-03-01

Temperature influences the specific dynamic action (SDA), or rise in oxygen uptake rate after feeding, in eurythermal and stenothermal crustaceans by changing the timing and the magnitude of the response. Intra-specific studies on the eurythermal crab, Carcinus maenas, show that a reduction in acclimation temperature is associated with a decrease in SDA magnitude, resulting from an increase in SDA duration but a decrease in peak factorial scope (the factorial rise in peak SDA over prefeeding values). Inter-specific feeding studies on stenothermal polar isopods revealed marked differences in SDA response between the Antarctic species, Glyptonotus antarcticus and the Arctic species, Saduria entomon. Compared to S. entomon held at 4 and 13 degrees C, the SDA response in G. antarcticus held at 1 degrees C was characterised by a lower absolute oxygen uptake rate at peak SDA and an extended SDA duration. At peak SDA, whole animal rates of protein synthesis increased in proportion to the postprandial increase in oxygen uptake rate in the Antarctic and the Arctic species. Rates of oxygen uptake plotted against whole animal rates of protein synthesis gave similar relationships in both isopod species, indicating similar costs of protein synthesis after a meal, despite their differences in SDA response and thermal habitat.

Effects of Cryogenic Temperatures on LEDs and Optical Fiber

NASA Technical Reports Server (NTRS)

Pantel, Erica R.

2005-01-01

Light Emitting Diodes (LEDs) may provide a simple, low powered light source for future space missions. However, the effects of cryogenic temperatures on LEDs and optical fibers are largely unknown. Tests were performed on a selection of commercially-available LEDs, with wavelengths varying from 468 nm to 950 nm, as well as "white" LEDs. Dry ice and liquid nitrogen (LN2) were used to bring the LEDs to the desired temperatures. The optical fibers were tested using a specially-machined brass cylinder that would allow the fibers to be cooled slowly and evenly in an LN2 dewer. An optical fiber coupled to a spectrometer was used to acquired spectra of a calibration light source (wavelength range 253-922 nm) at various temperatures. Examination of the LED spectra has shown several different effects, depending on the LED in question. Those with wavelengths above 590 nm tend to show a "blue shift" in their peak wavelength and an increase in intensity. Other LEDs developed secondary or tertiary peaks, or showed no peak shift at all, although all LEDs did show an increase in observed intensity. The optical fiber showed a slight non-uniform decrease in transmission as the temperature cooled to -195 C.

Implications for organic maturation studies of evidence of a geologically rapid increase and stabilization of vitrinite reflectance at peak temperature: Cerro Prieto geothermal system, Mexico

USGS Publications Warehouse

Barker, C.E.

1991-01-01

A short-term rapid heating and cooling of the rock in well M-94 below 1300 m was caused by a pulse of hot water passing through the edge of the Cerro Prieto, Mexico, geothermal system. Below 1300 m, the peak paleotemperatures were about 225-250??C, but equilibrium well log temperatures indicate a decrease to 150-210??C at present. This hot water pulse sharply increased vitrinite reflectance to levels comparable to those measured in the central part of the system, even though studies of apatite fission-track annealing indicate that the duration of heating was only 100-101 yr in M-94, in contrast to 103-104 yr in the central part of the system. The quick change of the vitrinite reflectance geothermometer indicates that thermal maturation reactions can stabilize, after a geologically short period of heating, to a level consistent with peak temperature under moderate to high-temperature diagenesis in open, fluid-rich, geothermal systems. -from Author

Study of P3HT/ PCBM morphology using Raman spectroscopy

NASA Astrophysics Data System (ADS)

Kumar, Sunil; Kumar, Manoj; Rathi, Sonika; Yadav, Anjali; Upadhyaya, Aditi; Gupta, Saral K.; Singh, Amarjeet

2018-05-01

In the present work we have deposited PEDOT: PSS (poly3,4-ethylene dioxythiophene -poly (styrenesulfonate)) then Pristine P3HT (Poly-3 hexylthiophene-2,5-diyl), PCBM (6,6- PhenylC61 butyric acid methyl ester) and its blend composite (P3HT:PCBM) thin films on ITO substrate via spin coating technique. Pristine P3HT, pristine PCBM and blend thin film samples were annealed at different temperatures (50°C, 80°C and 110°C) for 1 hr. Raman spectra was measured for each thin film samples as prepared (at room temperature or 25°C) and annealed at different temperatures (50°C, 80°C, 110°C). Then we calculated area under Raman peaks which is representation of Raman Intensity and observed that area under Raman peak varies with annealing temperatures. The increase in peak intensity appears due to increased crystallinity in annealed thin films. The mixing of PCBM hinders the crystallization of P3HT in blend. Mixed amorphous phase plays major role in charge transportation in electronic devices.

Forcing of the Coupled Ionosphere-Thermosphere (IT) System During Magnetic Storms

NASA Technical Reports Server (NTRS)

Huang, Cheryl; Huang, Yanshi; Su, Yi-Jiun; Sutton, Eric; Hairston, Marc; Coley, W. Robin; Doornbos, Eelco; Zhang, Yongliang

2014-01-01

Poynting flux shows peaks around auroral zone AND inside polar cap. Energy enters IT system at all local times in polar cap. Track-integrated flux at DMSP often peaks at polar latitudes- probably due to increased area of polar cap during storm main phases. center dot lon temperatures at DMSP show large increases in polar region at all local times; cusp and auroral zones do not show distinctively high Ti. center dot I on temperatures in the polar cap are higher than in the auroral zones during quiet times. center dot Neutral densities at GRACE and GOCE show maxima at polar latitudes without clear auroral signatures. Response is fast, minutes from onset to density peaks. center dot GUVI observations of O/N2 ratio during storms show similar response as direct measurements of ion and neutral densities, i.e. high temperatures in polar cap during prestorm quiet period, heating proceeding from polar cap to lower latitudes during storm main phase. center dot Discrepancy between maps of Poynting flux and of ion temperatures/neutral densities suggests that connection between Poynting flux and Joule heating is not simple.

TGA/FTIR study of the pyrolysis of sodium citrate and its effect on the pyrolysis of tobacco and tobacco/SBA-15 mixtures under N2 and air atmospheres.

PubMed

Marcilla, A; Gómez-Siurana, A; Beltrán, M; Martínez-Castellanos, I; Blasco, I; Berenguer, D

2018-05-08

In this work, the effect of sodium citrate mixed with tobacco, in presence and absence of SBA-15 material, was studied by TGA/FTIR under N 2 and air atmospheres. Depending on the atmosphere used, the decomposition of sodium citrate changes considerably at high temperatures, mainly due to the oxidation of the residue. The analysis of the experimental and calculated DTG data of the sodium citrate/SBA-15 mixtures allows the observation of marked widening of the peaks appearing at lower temperatures, due to the presence of SBA-15, while the expected peak at high temperatures in air completely disappears. The presence of sodium citrate in tobacco and tobacco/SBA-15 mixtures produces changes, especially in air atmosphere, where the main peaks increase their intensity, whereas decreasing that of the oxidation of the residue at around 450 °C and an important peak appears at 630 °C. In N 2 atmosphere, all decomposition processes of tobacco proceed at lower temperatures and with higher intensities. The peak due to the citrate at temperatures around 200 °C completely disappears in all samples. This article is protected by copyright. All rights reserved.

Experimental investigation of the glass transition of polystyrene thin films in a broad frequency range

NASA Astrophysics Data System (ADS)

Inoue, Rintaro; Kanaya, Toshiji; Yamada, Takeshi; Shibata, Kaoru; Fukao, Koji

2018-01-01

In this study, we investigate the α process of a polystyrene thin film using inelastic neutron scattering (INS), dielectric relaxation spectroscopy (DRS), and thermal expansion spectroscopy (TES). The DRS and TES measurements exhibited a decrease in glass transition temperature (Tg) with film thickness. On the other hand, an increase in Tg was observed in INS studies. In order to interpret this contradiction, we investigated the temperature dependence of the peak frequency (fm) of the α process probed by DRS and TES. The experiments revealed an increase in the peak frequency (fm) with decreasing film thickness in the frequency region. This observation is consistent with the observed decrease in Tg with thickness. Interestingly, the increase in Tg with film thickness was confirmed by fitting the temperature dependence measurements of the peak frequency with the Vogel-Fulcher-Tammann equation, within the frequency region probed by INS. The discrepancy between INS and DRS or TES descriptions of the α process is likely to be attributed to a decrease in the apparent activation energy with film thickness and reduced mobility, due to the impenetrable wall effect.

Effect of Vaccinium bracteatum Thunb. leaf pigment on the thermal, pasting, and textural properties and microstructure characterization of rice starch.

PubMed

Xu, Yuan; Fan, Mingcong; Zhou, Sumei; Wang, Li; Qian, Haifeng; Zhang, Hui; Qi, Xiguang

2017-08-01

In this study, the thermal, pasting and gel textural properties of japonica rice starch (JRS) and glutinous rice starch (GRS) fortified with Vaccinium bracteatum Thunb. leaf pigment (VBTLP) were investigated. The results showed that VBTLP facilitated the gelatinization of JRS and GRS with earlier onsets of onset temperature (T o ), peak temperature (T p ), conclusion temperature (T c ), and lower values of gelatinization enthalpy (ΔH g ), and retrogradation enthalpy (ΔH r ), as the VBTLP level increased. For JRS, VBTLP increased the peak viscosity and breakdown, reduced the final viscosity and setback, but for GRS it increased the peak viscosity, final viscosity, breakdown and setback. VBTLP also reduced the hardness and adhesiveness of the JRS gel. The values of lightness (L ∗ ) for JRS and GRS with VBTLP decreased by 47.60 and 49.56%, respectively. Scanning electron microscopy (SEM) revealed that VBTLP caused looser matrices in dried JRS and GRS gels which had lower crystallinities compared with the control. Copyright © 2017 Elsevier Ltd. All rights reserved.

Communication: Nanoscale structure of tetradecyltrihexylphosphonium based ionic liquids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hettige, Jeevapani J.; Araque, Juan C.; Margulis, Claudio J., E-mail: claudio-margulis@uiowa.edu

In a recent communication [J. J. Hettige et al., J. Chem. Phys. 140, 111102 (2014)], we investigated the anomalous temperature dependence of the X-ray first sharp diffraction peak (or prepeak) in the tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl)-amide ionic liquid. Contrary to what was expected and often observed, the first sharp diffraction peak in this system was shown to increase in intensity with increasing temperature. This implies higher intermediate-range periodicity at a higher temperature. Is this counter-intuitive behavior specific to the combination of cation and anion? The current work analyzes the structural behavior of the same cation coupled with six different anions ranging frommore » the small and spherically symmetric Cl{sup −} to the more structurally complex and charge-diffuse NTf{sub 2}{sup −}. In all cases, the same temperature behavior trend for the prepeak is observed independent of anionic nature. We will show that the intensity increase in the prepeak region is associated with the structural behavior of charged liquid subcomponents. Instead, upon a temperature increase, the apolar subcomponents contribute to what would be an expected decrease of prepeak intensity.« less

Higher fine particulate matter and temperature levels impair exercise capacity in cardiac patients.

PubMed

Giorgini, Paolo; Rubenfire, Melvyn; Das, Ritabrata; Gracik, Theresa; Wang, Lu; Morishita, Masako; Bard, Robert L; Jackson, Elizabeth A; Fitzner, Craig A; Ferri, Claudio; Brook, Robert D

2015-08-01

Fine particulate matter (PM2.5) air pollution and variations in ambient temperature have been linked to increased cardiovascular morbidity and mortality. However, no large-scale study has assessed their effects on directly measured aerobic functional capacity among high-risk patients. Using a cross-sectional observational design, we evaluated the effects of ambient PM2.5 and temperature levels over 7 days on cardiopulmonary exercise test results performed among 2078 patients enrolling into a cardiac rehabilitation programme at the University of Michigan (from January 2003 to August 2011) using multiple linear regression analyses (controlling for age, sex, body mass index). Peak exercise oxygen consumption was significantly decreased by approximately 14.9% per 10 μg/m(3) increase in ambient PM2.5 levels (median 10.7 μg/m(3), IQR 10.1 μg/m(3)) (lag days 6-7). Elevations in PM2.5 were also related to decreases in ventilatory threshold (lag days 5-7) and peak heart rate (lag days 2-3) and increases in peak systolic blood pressure (lag days 4-5). A 10°C increase in temperature (median 10.5°C, IQR 17.5°C) was associated with reductions in peak exercise oxygen consumption (20.6-27.3%) and ventilatory threshold (22.9-29.2%) during all 7 lag days. In models including both factors, the outcome associations with PM2.5 were attenuated whereas the effects of temperature remained significant. Short-term elevations in ambient PM2.5, even at low concentrations within current air quality standards, and/or higher temperatures were associated with detrimental changes in aerobic exercise capacity, which can be linked to a worse quality of life and cardiovascular prognosis among cardiac rehabilitation patients. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

The effects of transverse magnetic field and local electronic interaction on thermoelectric properties of monolayer graphene

NASA Astrophysics Data System (ADS)

Rezania, Hamed; Azizi, Farshad

2018-02-01

We study the effects of a transverse magnetic field and electron doping on the thermoelectric properties of monolayer graphene in the context of Hubbard model at the antiferromagnetic sector. In particular, the temperature dependence of thermal conductivity and Seebeck coefficient has been investigated. Mean field approximation has been employed in order to obtain the electronic spectrum of the system in the presence of local electron-electron interaction. Our results show the peak in thermal conductivity moves to higher temperatures with increase of both chemical potential and Hubbard parameter. Moreover the increase of magnetic field leads to shift of peak in temperature dependence of thermal conductivity to higher temperatures. Finally the behavior of Seebeck coefficient in terms of temperature has been studied and the effects of magnetic field and Hubbard parameter on this coefficient have been investigated in details.

Seasonal cues of Arctic grayling movement in a small Arctic stream: the importance of surface water connectivity

USGS Publications Warehouse

Heim, Kurt C.; Wipfli, Mark S.; Whitman, Matthew S.; Arp, Christopher D.; Adams, Jeff; Falke, Jeffrey A.

2015-01-01

In Arctic ecosystems, freshwater fish migrate seasonally between productive shallow water habitats that freeze in winter and deep overwinter refuge in rivers and lakes. How these movements relate to seasonal hydrology is not well understood. We used passive integrated transponder tags and stream wide antennae to track 1035 Arctic grayling in Crea Creek, a seasonally flowing beaded stream on the Arctic Coastal Plain, Alaska. Migration of juvenile and adult fish into Crea Creek peaked in June immediately after ice break-up in the stream. Fish that entered the stream during periods of high flow and cold stream temperature traveled farther upstream than those entering during periods of lower flow and warmer temperature. We used generalized linear models to relate migration of adult and juvenile fish out of Crea Creek to hydrology. Most adults migrated in late June – early July, and there was best support (Akaike weight = 0.46; w i ) for a model indicating that the rate of migration increased with decreasing discharge. Juvenile migration occurred in two peaks; the early peak consisted of larger juveniles and coincided with adult migration, while the later peak occurred shortly before freeze-up in September and included smaller juveniles. A model that included discharge, minimum stream temperature, year, season, and mean size of potential migrants was most strongly supported (w i  = 0.86). Juvenile migration rate increased sharply as daily minimum stream temperature decreased, suggesting fish respond to impending freeze-up. We found fish movements to be intimately tied to the strong seasonality of discharge and temperature, and demonstrate the importance of small stream connectivity for migratory Arctic grayling during the entire open-water period. The ongoing and anticipated effects of climate change and petroleum development on Arctic hydrology (e.g. reduced stream connectivity, earlier peak flows, increased evapotranspiration) have important implications for Arctic freshwater ecosystems.

Effect of temperature on excess post-exercise oxygen consumption in juvenile southern catfish (Silurus meridionalis Chen) following exhaustive exercise.

PubMed

Zeng, Ling-Qing; Zhang, Yao-Guang; Cao, Zhen-Dong; Fu, Shi-Jian

2010-12-01

The effects of temperature on resting oxygen consumption rate (MO2rest) and excess post-exercise oxygen consumption (EPOC) after exhaustive exercise (chasing) were measured in juvenile southern catfish (Silurus meridionalis) (8.40±0.30 g, n=40) to test whether temperature has a significant influence on MO2rest, maximum post-exercise oxygen consumption rate (MO2peak) and EPOC and to investigate how metabolic scope (MS: MO2peak - MO2rest) varies with acclimation temperature. The MO2rest increased from 64.7 (10°C) to 160.3 mg O2 h(-1) kg(-1) (25°C) (P<0.05) and reached a plateau between 25 and 30°C. The post-exercise MO2 in all temperature groups increased immediately to the peak values and then decreased slowly to a steady state that was higher than the pre-exercise MO2. The MO2peak did not significantly differ among the 20, 25 and 30°C groups, though these values were much higher than those of the lower temperature groups (10 and 15°C) (P<0.05). The duration of EPOC varied from 32.9 min at 10°C to 345 min at 20°C, depending on the acclimation temperatures. The MS values of the lower temperature groups (10 and 15°C) were significantly smaller than those of the higher temperature groups (20, 25 and 30°C) (P<0.05). The magnitude of EPOC varied ninefold among all of the temperature groups and was the largest for the 20°C temperature group (about 422.4 mg O2 kg(-1)). These results suggested that (1) the acclimation temperature had a significant effect on maintenance metabolism (as indicated by MO2rest) and the post-exercise metabolic recovery process (as indicated by MO2peak, duration and magnitude of EPOC), and (2) the change of the MS as a function of acclimation temperature in juvenile southern catfish might be related to their high degree of physiological flexibility, which allows them to adapt to changes in environmental conditions in their habitat in the Yangtze River and the Jialing River.

Influence of nanotube length and density on the plasmonic terahertz response of single-walled carbon nanotubes

NASA Astrophysics Data System (ADS)

Karlsen, P.; Shuba, M. V.; Beckerleg, C.; Yuko, D. I.; Kuzhir, P. P.; Maksimenko, S. A.; Ksenevich, V.; Viet, Ho; Nasibulin, A. G.; Tenne, R.; Hendry, E.

2018-01-01

We measure the conductivity spectra of thin films comprising bundled single-walled carbon nanotubes (CNTs) of different average lengths in the frequency range 0.3-1000 THz and temperature interval 10-530 K. The observed temperature-induced changes in the terahertz conductivity spectra are shown to depend strongly on the average CNT length, with a conductivity around 1 THz that increases/decreases as the temperature increases for short/long tubes. This behaviour originates from the temperature dependence of the electron scattering rate, which we obtain from Drude fits of the measured conductivity in the range 0.3-2 THz for 10 μm length CNTs. This increasing scattering rate with temperature results in a subsequent broadening of the observed THz conductivity peak at higher temperatures and a shift to lower frequencies for increasing CNT length. Finally, we show that the change in conductivity with temperature depends not only on tube length, but also varies with tube density. We record the effective conductivities of composite films comprising mixtures of WS2 nanotubes and CNTs versus CNT density for frequencies in the range 0.3-1 THz, finding that the conductivity increases/decreases for low/high density films as the temperature increases. This effect arises due to the density dependence of the effective length of conducting pathways in the composite films, which again leads to a shift and temperature dependent broadening of the THz conductivity peak.

Modeled future peak streamflows in four coastal Maine rivers

USGS Publications Warehouse

Hodgkins, Glenn A.; Dudley, Robert W.

2013-01-01

To safely and economically design bridges and culverts, it is necessary to compute the magnitude of peak streamflows that have specified annual exceedance probabilities (AEPs). These peak flows are also needed for effective floodplain management. Annual precipitation and air temperature in the northeastern United States are in general projected to increase during the 21st century (Hayhoe and other, 2007). It is therefore important for engineers and resource managers to understand how peak flows may change in the future. This Fact Sheet, prepared in cooperation with the Maine Department of Transportation, presents a summary of modeled changes in peak flows at four basins in coastal Maine on the basis of projected changes in air temperature and precipitation. The full Scientific Investigations Report (Hodgkins and Dudley, 2013) is available at http://pubs.usgs.gov/sir/2013/5080/.

Purification and autolysis of the ficin isoforms from fig (Ficus carica cv. Sabz) latex

PubMed Central

Zare, Hamid; Moosavi-Movahedi, Ali Akbar; Salami, Maryam; Mirzaei, Morteza; Saboury, Ali Akbar; Sheibani, Nader

2013-01-01

Ficin (EC 3.4.22.3), a cysteine endoproteolytic protease in fig trees’ latex, has multiple isoforms. Until now, no data on autolysis of individual ficins (ficin isoforms) are available. Following purification, ficins’ autolysis was determined by HPLC chromatogram changes and ultrafiltrations at different temperatures and storage times. These results showed that the number of HPLC peaks in latex proteins purification of Ficus carica cv. Sabz varied from previous fig varieties or cultivars. Proteolytic activity of ficins was inhibited by specific cysteine protease inhibitors, confirming the participation of the cysteine residue in the active site. The zeta potential of the first two eluted peaks (I and II) was negative, while that of other peaks were positive. All ficins were susceptible to autolysis when stored at high temperatures. In contrast, only the last two ficins (B, C) were prone to autolysis at cold temperature after long storage period. The rate of degradation of the ficins was significantly increased with the increased storage time. The ficin (A) related to peak (III) had the highest and the lowest surface hydrophobic patches and ratio of autolytic to proteolytic activity, respectively. PMID:23312458

Non-invasive treatment efficacy evaluation for high-intensity focused ultrasound therapy using magnetically induced magnetoacoustic measurement

NASA Astrophysics Data System (ADS)

Guo, Gepu; Wang, Jiawei; Ma, Qingyu; Tu, Juan; Zhang, Dong

2018-04-01

Although the application of high intensity focused ultrasound (HIFU) has been demonstrated to be a non-invasive treatment technology for tumor therapy, the real-time temperature monitoring is still a key issue in the practical application. Based on the temperature-impedance relation, a fixed-point magnetically induced magnetoacoustic measurement technology of treatment efficacy evaluation for tissue thermocoagulation during HIFU therapy is developed with a sensitive indicator of critical temperature monitoring in this study. With the acoustic excitation of a focused transducer in the magnetoacoustic tomography with the magnetic induction system, the distributions of acoustic pressure, temperature, electrical conductivity, and acoustic source strength in the focal region are simulated, and the treatment time dependences of the peak amplitude and the corresponding amplitude derivative under various acoustic powers are also achieved. It is proved that the strength peak of acoustic sources is generated by tissue thermocoagulation with a sharp conductivity variation. The peak amplitude of the transducer collected magnetoacoustic signal increases accordingly along with the increase in the treatment time under a fixed acoustic power. When the temperature in the range with the radial and axial widths of about ±0.46 mm and ±2.2 mm reaches 69 °C, an obvious peak of the amplitude derivative can be achieved and used as a sensitive indicator of the critical status of treatment efficacy. The favorable results prove the feasibility of real-time non-invasive temperature monitoring and treatment efficacy evaluation for HIFU ablation using the magnetically induced magnetoacoustic measurement, and might provide a new strategy for accurate dose control during HIFU therapy.

Raman scattering in single-crystal sapphire at elevated temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thapa, Juddha; Liu, Bo; Woodruff, Steven D.

Sapphire is a widely used high-temperature material and this work presents thorough characterization of all the measurable Raman scattering modes in sapphire and their temperature dependencies. Here, Raman scattering in bulk sapphire rods is measured from room temperature to 1081 °C and is illustrated as a method of noncontact temperature measurement. A single-line argon ion laser at 488 nm was used to excite the sapphire rods inside a cylindrical furnace. All the anti-Stokes peaks (or lines) were observable through the entire temperature range of interest, while Stokes peaks were observable until they were obscured by background thermal emission. Temperature measurementsmore » were found to be most reliable for A 1g and E g modes using the peaks at ±418, ±379, +578, +645, and, +750 cm -1 (+ and – are designated for Stokes and anti-Stokes peaks respectively). The 418 cm -1 peak was found to be the most intense peak. The temperature dependence of peak position, peak width, and peak area of the ±418 and ±379 peaks is presented. For +578, +645 and +750, the temperature dependence of peak position is presented. The peaks’ spectral positions provide the most precise temperature information within the experimental temperature range. Finally, the resultant temperature calibration curves are given, which indicate that sapphire can be used in high-temperature Raman thermometry with an accuracy of about 1.38°C average standard deviation over the entire >1000°C temperature range.« less

Raman scattering in single-crystal sapphire at elevated temperatures

DOE PAGES

Thapa, Juddha; Liu, Bo; Woodruff, Steven D.; ...

2017-10-25

Sapphire is a widely used high-temperature material and this work presents thorough characterization of all the measurable Raman scattering modes in sapphire and their temperature dependencies. Here, Raman scattering in bulk sapphire rods is measured from room temperature to 1081 °C and is illustrated as a method of noncontact temperature measurement. A single-line argon ion laser at 488 nm was used to excite the sapphire rods inside a cylindrical furnace. All the anti-Stokes peaks (or lines) were observable through the entire temperature range of interest, while Stokes peaks were observable until they were obscured by background thermal emission. Temperature measurementsmore » were found to be most reliable for A 1g and E g modes using the peaks at ±418, ±379, +578, +645, and, +750 cm -1 (+ and – are designated for Stokes and anti-Stokes peaks respectively). The 418 cm -1 peak was found to be the most intense peak. The temperature dependence of peak position, peak width, and peak area of the ±418 and ±379 peaks is presented. For +578, +645 and +750, the temperature dependence of peak position is presented. The peaks’ spectral positions provide the most precise temperature information within the experimental temperature range. Finally, the resultant temperature calibration curves are given, which indicate that sapphire can be used in high-temperature Raman thermometry with an accuracy of about 1.38°C average standard deviation over the entire >1000°C temperature range.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuang, Xingya; Shankar, T.J.; Bi, X.T.

Wood pellets emit CO, CO2, CH4 and other volatiles during storage. Increased concentration of these gases in a sealed storage causes depletion of concentration of oxygen. The storage environment becomes toxic to those who operate in and around these storages. The objective of this study was to investigate the effects of temperature, moisture and storage headspace on emissions from wood pellets in an enclosed space. Twelve 10-liter plastic containers were used to study the effects of headspace ratio (25%, 50%, and 75% of container volume) and temperatures (10-50oC). Another eight containers were set in uncontrolled storage relative humidity and temperature.more » Concentrations of CO2, CO and CH4 were measured by a gas chromatography (GC). The results showed that emissions of CO2, CO and CH4 from stored wood pellets are most sensitive to storage temperature. Higher peak emission factors are associated with higher temperatures. Increased headspace volume ratio increases peak off-gas emissions because of the availability of oxygen for pellet decomposition. Increased relative humidity in the enclosed container increases the rate of off-gas emissions of CO2, CO and CH4 and oxygen depletion.« less

Climate change is projected to have severe impacts on the frequency and intensity of peak electricity demand across the United States

PubMed Central

Auffhammer, Maximilian; Baylis, Patrick; Hausman, Catherine H.

2017-01-01

It has been suggested that climate change impacts on the electric sector will account for the majority of global economic damages by the end of the current century and beyond [Rose S, et al. (2014) Understanding the Social Cost of Carbon: A Technical Assessment]. The empirical literature has shown significant increases in climate-driven impacts on overall consumption, yet has not focused on the cost implications of the increased intensity and frequency of extreme events driving peak demand, which is the highest load observed in a period. We use comprehensive, high-frequency data at the level of load balancing authorities to parameterize the relationship between average or peak electricity demand and temperature for a major economy. Using statistical models, we analyze multiyear data from 166 load balancing authorities in the United States. We couple the estimated temperature response functions for total daily consumption and daily peak load with 18 downscaled global climate models (GCMs) to simulate climate change-driven impacts on both outcomes. We show moderate and heterogeneous changes in consumption, with an average increase of 2.8% by end of century. The results of our peak load simulations, however, suggest significant increases in the intensity and frequency of peak events throughout the United States, assuming today’s technology and electricity market fundamentals. As the electricity grid is built to endure maximum load, our findings have significant implications for the construction of costly peak generating capacity, suggesting additional peak capacity costs of up to 180 billion dollars by the end of the century under business-as-usual. PMID:28167756

Cathodoluminescence microscopy and spectroscopy of micro- and nanodiamonds: an implication for laboratory astrophysics.

PubMed

Gucsik, Arnold; Nishido, Hirotsugu; Ninagawa, Kiyotaka; Ott, Ulrich; Tsuchiyama, Akira; Kayama, Masahiro; Simonia, Irakli; Boudou, Jean-Paul

2012-12-01

Color centers in selected micro- and nanodiamond samples were investigated by cathodoluminescence (CL) microscopy and spectroscopy at 298 K [room temperature (RT)] and 77 K [liquid-nitrogen temperature (LNT)] to assess the value of the technique for astrophysics. Nanodiamonds from meteorites were compared with synthetic diamonds made with different processes involving distinct synthesis mechanisms (chemical vapor deposition, static high pressure high temperature, detonation). A CL emission peak centered at around 540 nm at 77 K was observed in almost all of the selected diamond samples and is assigned to the dislocation defect with nitrogen atoms. Additional peaks were identified at 387 and 452 nm, which are related to the vacancy defect. In general, peak intensity at LNT at the samples was increased in comparison to RT. The results indicate a clear temperature-dependence of the spectroscopic properties of diamond. This suggests the method is a useful tool in laboratory astrophysics.

Behavior of a PCM at Varying Heating Rates: Experimental and Theoretical Study with an Aim at Temperature Moderation in Radionuclide Concrete Encasements

NASA Astrophysics Data System (ADS)

Medved', Igor; Trník, Anton

2018-07-01

Phase-change materials (PCMs) can store/release thermal energy within a small temperature range. This is of interest in various industrial applications, for example, in civil engineering (heating/cooling of buildings) or cold storage applications. Another application may be the moderation of temperature increases in concrete encasements of radionuclides during their decay. The phase-change behavior of a material is determined by its heat capacity and the peak it exhibits near a phase change. We analyze the behavior of such peaks for a selected PCM at heating rates varying between 0.1°C\\cdot min^{-1} and 1°C\\cdot min^{-1}, corresponding in real situations to different decay rates of radionuclides. We show that experimentally measured peaks can be plausibly described by an equilibrium theory that enables us to calculate the latent heat and phase-change temperature from experimental data.

Optical and Structural Properties of Ion-implanted InGaZnO Thin Films Studied with Spectroscopic Ellipsometry and Transmission Electron Microscopy

NASA Astrophysics Data System (ADS)

Park, Jun Woo; Jeong, Pil Seong; Choi, Suk-Ho; Lee, Hosun; Kong, Bo Hyun; Koun Cho, Hyung

2009-11-01

Amorphous InGaZnO (IGZO) thin films were grown using RF sputtering deposition at room temperature and their corresponding dielectric functions were measured. In order to reduce defects and increase carrier concentrations, we examined the effect of forming gas annealing and ion implantation. The band gap energy increased with increasing forming gas annealing temperature. We implanted the IGZO thin films with F- ions in order to decrease oxygen vacancies. For comparison, we also implanted InO- ions. Transmission electron microscopy showed that the amorphous phase undergoes transformation to a nanocrystalline phase due to annealing. We also observed InGaZnO4 nanocrystals having an In-(Ga/Zn) superlattice structure. As the annealing temperature increased, the optical gap energy increased due to crystallization. After annealing, we observed an oxygen-vacancy-related 1.9 eV peak for both unimplanted and InO-implanted samples. However, F- ion implantation substantially reduced the amplitude of the 1.9 eV peak, which disappeared completely at a F fluence of 5×1015 cm-2. We observed other defect-related peaks at 3.6 and 4.2 eV after annealing, which also disappeared after F implantation.

Combustion Noise at Elevated Pressures in a Liquid-Fueled Premixed Combustor

NASA Technical Reports Server (NTRS)

Darling, Douglas; Radhakrishnan, Krishnan; Oyediran, Ayo

1997-01-01

Noise generated in gas turbine combustors can exist in several forms-broadband noise, sharp resonant peaks, and regular or intermittent nonlinear pulsing. In the present study, dynamic pressure measurements were made in several JP-5-fueled combustor configurations, at various mean pressures and temperatures. The fluctuating pressure was measured at mean pressures from 6 to 14 atm and inlet temperatures from 550 K to 850 K. The goal of the present work was to study the effect of changes in mean flow conditions on combustor noise: both broadband noise and sharp tones were considered. In general, the shape of the broadband noise spectrum was consistent from one configuration to another. The shape of the spectrum was influenced by the acoustic filtering of the combustion zone. This filtering ensured the basic consistency of the spectra. In general, the trends in broadband noise observed at low mean pressures were also seen at high mean pressures; that is, the total sound level decreased with both increasing equivalence ratio and increasing inlet temperature. The combustor configurations without a central pilot experienced higher broadband noise levels and were more susceptible to narrow peak resonances than configurations with a central pilot. The sharp peaks were more sensitive to the mean flow than was the broadband noise, and the effects were not always the same. In some situations, increasing the equivalence ratio made the sharp peaks grow, while at other conditions, increasing the equivalence ratio made the sharp peaks shrink. Thus, it was difficult to predict when resonances would occur; however, they were reproducible. Acoustic coupling between the upstream and downstream regions of the combustor may play a role in the sharp-peaked oscillations. Noise was also observed near lean blow out. As with other types of noise, lean blow out noise was affected by the combustion chamber acoustics, which apparently maintains the fluctuations at a uniform frequency. However, the actual conditions when this type of noise was experienced appeared to simply follow the lean blow out limit as it varied with mean temperature and pressure.

Experimental and simulation studies of neutron-induced single-event burnout in SiC power diodes

NASA Astrophysics Data System (ADS)

Shoji, Tomoyuki; Nishida, Shuichi; Hamada, Kimimori; Tadano, Hiroshi

2014-01-01

Neutron-induced single-event burnouts (SEBs) of silicon carbide (SiC) power diodes have been investigated by white neutron irradiation experiments and transient device simulations. It was confirmed that a rapid increase in lattice temperature leads to formation of crown-shaped aluminum and cracks inside the device owing to expansion stress when the maximum lattice temperature reaches the sublimation temperature. SEB device simulation indicated that the peak lattice temperature is located in the vicinity of the n-/n+ interface and anode contact, and that the positions correspond to a hammock-like electric field distribution caused by the space charge effect. Moreover, the locations of the simulated peak lattice temperature agree closely with the positions of the observed destruction traces. Furthermore, it was theoretically demonstrated that the period of temperature increase of a SiC power device is two orders of magnitude less than that of a Si power device, using a thermal diffusion equation.

Detection of the relationship between peak temperature and extreme precipitation

NASA Astrophysics Data System (ADS)

Yu, Y.; Liu, J.; Zhiyong, Y.

2017-12-01

Under the background of climate change and human activities, the characteristics and pattern of precipitation have changed significantly in many regions. As the political and cultural center of China, the structure and character of precipitation in Jingjinji District has varied dramatically in recent years. In this paper, the daily precipitation data throughout the period 1960-2013 are selected for analyzing the spatial-temporal variability of precipitation. The results indicate that the frequency and intensity of precipitation presents an increasing trend. Based on the precipitation data, the maximum, minimum and mean precipitation in different temporal and spatial scales is calculated respectively. The temporal and spatial variation of temperature is obtained by using statistical methods. The relationship between temperature and precipitation in different range is analyzed. The curve relates daily precipitation extremes with local temperatures has a peak structure, increasing at the low-medium range of temperature variations but decreasing at high temperatures. The relationship between extreme precipitation is stronger in downtown than that in suburbs.

Temperature and evaporative water loss of leaf-sitting frogs: the role of reflection spectra

PubMed Central

Blount, Chris; Dickinson, Mark

2016-01-01

ABSTRACT The near infrared reflection peak in some frogs has been speculated to be either for enhancing crypticity, or to help them with thermoregulation. The theoretical background for the thermoregulatory processes has been established before, but little consideration has been given to the contribution from the frogs' reflection spectra differences. In this investigation, the reflection spectra from a range of different species of frogs were taken and combined with precise surface area measurements of frogs and an approximation to the mass transfer coefficient of agar frog models. These were then used to simulate the temperature and water evaporation in anurans with and without the near infrared reflective peak. We have shown that the presence of the near infrared reflection peak can contribute significantly to the temperature and evaporative water loss of a frog. The significance of the steady-state temperature differences between frogs with and without the near infrared reflection peak is discussed in a realistic and an extreme scenario. Temperature differences of up to 3.2°C were found, and the rehydration period was increased by up to 16.7%, although this does not reduce the number of rehydration events between dawn and dusk. PMID:27793832

Synergistic Effects of Temperature, Oxidation and Stress Level on Fatigue Damage Evolution and Lifetime Prediction of Cross-Ply SiC/CAS Ceramic-Matrix Composites Through Hysteresis-Based Parameters

NASA Astrophysics Data System (ADS)

Li, Longbiao

2017-12-01

The damage development and cyclic fatigue lifetime of cross-ply SiC/CAS ceramic-matrix composites have been investigated at different testing temperatures in air atmosphere. The relationships between the fatigue hysteresis-based damage parameters, i.e., fatigue hysteresis dissipated energy, fatigue hysteresis modulus and fatigue peak strain and the damage mechanisms of matrix multicracking, fiber/matrix interface debonding, interface sliding and fibers failure, have been established. With the increase in the cycle number, the evolution of the fatigue hysteresis modulus, fatigue peak strain and fatigue hysteresis dissipated energy depends upon the fatigue peak stress levels, interface and fibers oxidation and testing temperature. The fatigue life S-N curves of cross-ply SiC/CAS composite at room and elevated temperatures have been predicted, and the fatigue limit stresses at room temperature, 750 and 850 °C, are 50, 36 and 30% of the tensile strength, respectively.

The Pulse Response of Electrets to Energetic Ions

DTIC Science & Technology

1988-09-01

reduction in the low temperature peak for the aged sample. This change is accompanied by a significant increase in the high temperature peak. Ion...density in electron-beam charged FEP does not change under normal conditions while the hole density falls rapidly with aging . Because hole traps are...power, S, and the aver- age energy required to produce a charge carrier pair, W, are constant. By Equation 4-1, the charge, Q, produced by an emission

The effects of feeding on the swimming performance and metabolic response of juvenile southern catfish, Silurus meridionalis, acclimated at different temperatures.

PubMed

Pang, Xu; Cao, Zhen-Dong; Peng, Jiang-Lan; Fu, Shi-Jian

2010-02-01

To test whether the effects of feeding on swimming performance vary with acclimation temperature in juvenile southern catfish (Silurus meridionalis), we investigated the specific dynamic action (SDA) and swimming performance of fasting and feeding fish at acclimation temperatures of 15, 21, 27, and 33 degrees C. Feeding had no effect on the critical swimming speeding (U(crit)) of fish acclimated at 15 degrees C (p=0.66), whereas it elicited a 12.04, 18.70, and 20.98% decrease in U(crit) for fish acclimated at 21, 27 and 33 degrees C, respectively (p<0.05). Both the maximal postprandial oxygen consumption rate (VO2peak) and the active metabolic rate (VO2active, maximal aerobic sustainable metabolic rate of fasting fish) increased significantly with temperature (p<0.05). The postprandial maximum oxygen consumption rates during swimming (VO2max) were higher than the VO2active of fasting fish at all temperature groups (p<0.05). The VO2max increased with increasing temperature, but the relative residual metabolic scope (VO2max-VO2peak) during swimming decreased with increasing in temperature. The present study showed that the impairment of postprandial swimming performance increased with increasing temperature due to the unparalleled changes in the catfish's central cardio-respiratory, peripheral digestive and locomotory capacities. The different metabolic strategies of juvenile southern catfish at different temperatures may relate to changes in oxygen demand, imbalances in ion fluxes and dissolved oxygen levels with changes in temperature. 2009 Elsevier Inc. All rights reserved.

[Preparation and Performance of Ultrafast γ-CuI Scintillation Conversion Screen].

PubMed

Xia, Ming; Gu, Mu; Liu, Xiao-lin; Liu, Bo; Huang, Shi-ming; Ni, Chen

2015-04-01

Micro-columnar structured γ-CuI scintillation conversion screen with columnar diameter in the micrometer and thickness about 17 µm were prepared by thermal evaporation method on quartz substrates with different temperatures. X-ray excited luminescence spectra of the screens show two peaks located at 430 nm and near 700 nm, which correspond to the fast and slow emission components, respectively. The fast one dominated. The intensity of 430 nm peak decreased as the substrate temperature rose from 170 °C to 210 °C. At the same time the intensity of 700 nm band increased. The changes may be attributed to the iodine loss from screen caused by the substrate temperature. The phenomenon of iodine loss was observed by the Rutherford backscattering experiment. The crystal structure of the screens presents (111) preferred orientation, which is independent of the substrate temperature. As the temperature rose to 210 °C, two weak additional peaks of (220) and (420) γ-CuI crystal planes in X-ray diffraction patterns appeared due to the increase in kinetic energy of CuI molecules. The scanning electron microscopy images of the screens showed that the columnar structure was improved when the substrate temperature increased from 170 °C to 190 °C, but it would be degenerated when the temperature continued to rise to 210 °C because of the surface and bulk diffusion effects of the depositing molecules. Finally, the spatial resolution of the γ-CuI scintillation screens was measured by knife-edge method, and they are 4.5, 7.2 and 5.6lp · mm(-1) for the screens prepared at the substrates temperatures of 170, 190 and 210 °C, respectively. The result shows that micro-column structure could improve the spatial resolution of γ-CuI scintillation screen.

The stabilization of tannery sludge and the character of humic acid-like during low temperature pyrolysis.

PubMed

Ma, Hongrui; Gao, Mao; Hua, Li; Chao, Hao; Xu, Jing

2015-11-01

Tannery sludge contained plenty of organic matter, and the organic substance stability had direct impact on its derived chars' utilization. In this paper, the stabilization of tannery sludge and the variation of humic acid-like (HAL) extracted by different methods were investigated in a magnetic stirring reactor under low temperature pyrolysis of 100-400 °C. Results showed that the aromatic structure of pyrolysis chars increased with the increase of temperature and time. The char contained highly aromatic structure and relatively small dissolved organic matters (DOM) at 300 °C. The similar behaviors appeared in two HAL series by different extraction methods. The N content, H/C value, and aliphatic structures of HAL decreased with the increase of pyrolysis temperature, while the C/N value and aromatic structures increased with the rise of pyrolysis temperature. The composition and functional groups of HAL were similar with the purchased humic acid (HA). The fluorescence spectra revealed that two main peaks were found at Ex/Em = 239/363-368 nm and 283/359-368 nm in each HAL series from raw and 100 °C pyrolysis tannery sludge, representing a protein-like matter. The new peak appeared at Ex/Em = 263-283/388 nm in each HAL series from 200 °C pyrolysis tannery sludge-represented humic acid-like matter. The fluorescence intensity increased strongly compared to the other two peak intensity. Therefore, the humification of organic matter was increased by pyrolyzing. Notably, the HAL from 200 °C pyrolysis tannery sludge contained simple molecular structure, and the polycondensation increased but with a relative lower humification degree compared to soil HAL and purchased HA. Therefore, the sludge needs further oxidation. The humic substance was negligible by direct extraction when the temperature was 300 and 400 °C.

Toward large-scale solar energy systems with peak concentrations of 20,000 suns

NASA Astrophysics Data System (ADS)

Kribus, Abraham

1997-10-01

The heliostat field plays a crucial role in defining the achievable limits for central receiver system efficiency and cost. Increasing system efficiency, thus reducing the reflective area and system cost, can be achieved by increasing the concentration and the receiver temperature. The concentration achievable in central receiver plants, however, is constrained by current heliostat technology and design practices. The factors affecting field performance are surface and tracking errors, astigmatism, shadowing, blocking and dilution. These are geometric factors that can be systematically treated and reduced. We present improvements in collection optics and technology that may boost concentration (up to 20,000 peak), achievable temperature (2,000 K), and efficiency in solar central receiver plants. The increased performance may significantly reduce the cost of solar energy in existing applications, and enable solar access to new ultra-high-temperature applications, such as: future gas turbines approaching 60% combined cycle efficiency; high-temperature thermo-chemical processes; and gas-dynamic processes.

Effects of chemical form of sodium on the product characteristics of alkali lignin pyrolysis.

PubMed

Guo, Da-liang; Yuan, Hong-you; Yin, Xiu-li; Wu, Chuang-zhi; Wu, Shu-bin; Zhou, Zhao-qiu

2014-01-01

The effects of Na as organic bound form or as inorganic salts form on the pyrolysis products characteristics of alkali lignin were investigated by using thermogravimetric analyzer coupled with Fourier transform infrared spectrometry (TG-FTIR), tube furnace and thermo-gravimetric analyzer (TGA). Results of TG-FTIR and tube furnace indicated that the two chemical forms Na reduced the releasing peak temperature of CO and phenols leading to the peak temperature of the maximum mass loss rate shifted to low temperature zone. Furthermore, organic bound Na obviously improved the elimination of alkyl substituent leading to the yields of phenol and guaiacol increased, while inorganic Na increased the elimination of phenolic hydroxyl groups promoting the formation of ethers. It was also found the two chemical forms Na had different effects on the gasification reactivity of chars. For inorganic Na, the char conversion decreased with increasing the char forming temperature, while organic bound Na was opposite. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

Numerical calculations of temperature dependence of dielectric constant for an ordered assembly of BaTiO3 nanocubes with small tilt angles

NASA Astrophysics Data System (ADS)

Yasui, Kyuichi; Mimura, Ken-ichi; Izu, Noriya; Kato, Kazumi

2018-03-01

The dielectric constant of an ordered assembly of BaTiO3 nanocubes is numerically calculated as a function of temperature assuming a distribution of tilt angles of attached nanocubes. As the phase transition temperature from the tetragonal crystal structure to the cubic crystal structure of a BaTiO3 nanocube decreases as the tilt angle increases, the temperature at the peak of the dielectric constant of an ordered assembly is considerably lower than the Curie temperature of a free-standing BaTiO3 crystal. The peak of the dielectric constant as a function of temperature for an ordered assembly becomes considerably broader than that for a single crystal owing to the contribution of nanocubes with various tilt angles.

Electrical Conduction of Ba(Ti0.99Fe0.01)O3-δ Ceramic at High Temperatures

NASA Astrophysics Data System (ADS)

Yu, Zi-De; Chen, Xiao-Ming

2018-03-01

BaTiO3 and Ba(Ti0.99Fe0.01)O3-δ ceramics with dense microstructure have been synthesized by a solid-state reaction method, and their electrical conduction investigated by broadband electrical impedance spectroscopy at frequencies from 0.05 Hz to 3 × 106 Hz and temperatures from 200°C to 400°C. Compared with BaTiO3, the real part of the permittivity and the phase-transition temperature of Ba(Ti0.99Fe0.01)O3-δ decreased. Relaxation peaks appeared in the curves of the imaginary part of the permittivity as a function of frequency. With increase in frequency, the peaks gradually shifted towards higher frequency and their height increased. Conductivity was closely related to frequency and temperature. Frequency-dependent conductivity was analyzed using the Jonscher double power law. Compared with BaTO3, Ba(Ti0.99Fe0.01)O3-δ exhibited high impedance at given frequency and temperature. Impedance Cole-Cole plots displayed two semicircles, which could be well fit using two parallel RC equivalent circuit models. The conductivity activation energy was found to be around 1 eV. For Ba(Ti0.99Fe0.01)O3-δ , the electrical modulus curve versus frequency displayed two peaks.

Electrical Conduction of Ba(Ti0.99Fe0.01)O3- δ Ceramic at High Temperatures

NASA Astrophysics Data System (ADS)

Yu, Zi-De; Chen, Xiao-Ming

2018-07-01

BaTiO3 and Ba(Ti0.99Fe0.01)O3- δ ceramics with dense microstructure have been synthesized by a solid-state reaction method, and their electrical conduction investigated by broadband electrical impedance spectroscopy at frequencies from 0.05 Hz to 3 × 106 Hz and temperatures from 200°C to 400°C. Compared with BaTiO3, the real part of the permittivity and the phase-transition temperature of Ba(Ti0.99Fe0.01)O3- δ decreased. Relaxation peaks appeared in the curves of the imaginary part of the permittivity as a function of frequency. With increase in frequency, the peaks gradually shifted towards higher frequency and their height increased. Conductivity was closely related to frequency and temperature. Frequency-dependent conductivity was analyzed using the Jonscher double power law. Compared with BaTO3, Ba(Ti0.99Fe0.01)O3- δ exhibited high impedance at given frequency and temperature. Impedance Cole-Cole plots displayed two semicircles, which could be well fit using two parallel RC equivalent circuit models. The conductivity activation energy was found to be around 1 eV. For Ba(Ti0.99Fe0.01)O3- δ , the electrical modulus curve versus frequency displayed two peaks.

N Vibrational Temperatures and OH Number Density Measurements in a NS Pulse Discharge Hydrogen-Air Plasmas

NASA Astrophysics Data System (ADS)

Hung, Yichen; Winters, Caroline; Jans, Elijah R.; Frederickson, Kraig; Adamovich, Igor V.

2017-06-01

This work presents time-resolved measurements of nitrogen vibrational temperature, translational-rotational temperature, and absolute OH number density in lean hydrogen-air mixtures excited in a diffuse filament nanosecond pulse discharge, at a pressure of 100 Torr and high specific energy loading. The main objective of these measurements is to study a possible effect of nitrogen vibrational excitation on low-temperature kinetics of HO2 and OH radicals. N2 vibrational temperature and gas temperature in the discharge and the afterglow are measured by ns broadband Coherent Anti-Stokes Scattering (CARS). Hydroxyl radical number density is measured by Laser Induced Fluorescence (LIF) calibrated by Rayleigh scattering. The results show that the discharge generates strong vibrational nonequilibrium in air and H2-air mixtures for delay times after the discharge pulse of up to 1 ms, with peak vibrational temperature of Tv ≈ 2000 K at T ≈ 500 K. Nitrogen vibrational temperature peaks ≈ 200 μs after the discharge pulse, before decreasing due to vibrational-translational relaxation by O atoms (on the time scale of a few hundred μs) and diffusion (on ms time scale). OH number density increases gradually after the discharge pulse, peaking at t 100-300 μs and decaying on a longer time scale, until t 1 ms. Both OH rise time and decay time decrease as H2 fraction in the mixture is increased from 1% to 5%. OH number density in a 1% H2-air mixture peaks at approximately the same time as vibrational temperature in air, suggesting that OH kinetics may be affected by N2 vibrational excitation. However, preliminary kinetic modeling calculations demonstrate that OH number density overshoot is controlled by known reactions of H and O radicals generated in the plasma, rather than by dissociation by HO2 radical in collisions with vibrationally excited N2 molecules, as has been suggested earlier. Additional measurements at higher specific energy loadings and kinetic modeling calculations are underway.

Key conclusions from AVOID Work Stream One

NASA Astrophysics Data System (ADS)

Warren, Rachel

2010-05-01

AVOID work stream (WS1)one has produced emission scenarios that simulate potential future global emission pathways for greenhouse gases during the 21st century. The study explored the influence of three key features of such pathways: (1) the year in which emissions peak globally, (2) the rate of emission reduction, and (3) the minimum level to which emissions are eventually reduced. It examined the resultant climate change, climate change impacts and economic implications using computer simulations. Avoided impacts, carbon taxes and GDP change increase throughout the 21st century in the models. AVOID-WS1 showed that in the absence of climate policy it is very likely that global mean temperatures would exceed 3 degrees and there are evens chances that the temperature would rise by 4 degrees relative to pre-industrial times. Scenarios that peak emissions in 2016 were more effective at constraining temperatures to below 3 degrees than those that peaked in 2030: one ‘2016' scenario achieved a probability of 45% of avoiding breaching of a 2 degree threshold. Scenarios peaking in 2030 were inconsistent with constraining temperatures to below 2 degrees. Correspondingly, scenarios that peak in 2030 are more effective at avoiding climate impacts than scenarios that peak in 2016, for all sectors that we studied. Hence the date at which emissions peak is more important than the rate of subsequent emissions reduction in determining the avoided impacts. Avoided impacts increase with time, being negligible in the 2030s, significant by the 2050s and large by the 2080s. Finally, the choice of GCM influences the magnitude of the avoided impacts strongly, so that the uncertainties in our estimates of avoided impacts for each scenario are larger than the difference between the scenarios. Our economic analysis is based on models which differ greatly in the assumptions that they make, but generally show that the date at which emissions peak is a stronger driver of induced GDP changes, and, with some exceptions, carbon taxes, than the rate at which emissions are subsequently reduced. In models which assume perfect rationality and foresight and/or assume the economy to be equilibrium with full employment, then mitigation could cause GDP to decrease. In models which do not make these assumptions, mitigation could cause GDP to increase. In either case the effects are small (a few % of GDP lost or gained in 2100) and insignificant when compared with the 600-1200% increase in global GDP forecast between 2000 and 2100 in the SRES A1B reference scenario used in this study. Estimates of carbon taxes required differ widely between models.

Resistance noise in epitaxial thin films of ferromagnetic topological insulators

NASA Astrophysics Data System (ADS)

Bhattacharyya, Semonti; Kandala, Abhinav; Richardella, Anthony; Islam, Saurav; Samarth, Nitin; Ghosh, Arindam

2016-02-01

We report detailed temperature and gate-voltage dependence of 1/f resistance noise in magnetically doped topological insulators (TI) Crx(Bi,Sb)2-xTe3. The noise is remarkably sensitive to the gate voltage, increasing rapidly as the chemical potential is moved towards the charge neutrality point. Unlike in identically prepared (Bi,Sb)2Te3 films, where mobility-fluctuations in the surface states is the dominant mechanism, the noise in the magnetic Crx(Bi,Sb)2-xTe3 originates from transport in the localized band tail of the bulk valence band. A strong increase in noise with decreasing temperature supports this scenario. At higher temperature (≥10 K), we observed large noise peaks at gate voltage-dependent characteristic temperature scales. In line with similar observations in other non-magnetic TI systems, we attribute these peaks to generation-recombination in the Cr-impurity band.

Transport Studies in Alcator C-Mod ITB Plasmas

NASA Astrophysics Data System (ADS)

Fiore, C. L.; Bonoli, P. T.; Ernst, D.; Greenwald, M. J.; Ince-Cushman, A.; Lin, L.; Marmar, E. S.; Porkolab, M.; Rice, J. E.; Wukitch, S.; Rowan, W.; Bespamyatnov, I.; Phillips, P.

2008-11-01

Internal transport barriers occur in C-Mod plasmas that have off-axis ICRF heating and also in Ohmic H-mode plasmas. These ITBs are marked by highly peaked density and pressure profiles, as they rely on a reduction of particle and thermal flux in the barrier region which allows the neoclassical pinch to peak the central density without reducing the central temperature. Enhancement of several core diagnostics has resulted in increased understanding of C-Mod ITBs. Ion temperature profile measurements have been obtained using an innovative design for x-ray crystal spectrometry and clearly show a barrier forming in the ion temperature profile. The phase contrast imaging (PCI) provides limited localization of the ITB related fluctuations that increase in strength as the central density increases. Simulation of triggering conditions, integrated simulations with fluctuation measurements, parametric studies, and transport implications of fully ionized boron impurity profiles in the plasma are under study. A summary of these results will be presented.

Calcination Conditions on the Properties of Porous TiO2 Film

NASA Astrophysics Data System (ADS)

Zhang, Wenjie; Pei, Xiaobei; Bai, Jiawei; He, Hongbo

2014-03-01

Porous TiO2 films were deposited on SiO2 precoated glass-slides by sol-gel method using PEG1000 as template. The strongest XRD diffraction peak at 2θ = 25.3° is attributed to [101] plane of anatase TiO2 in the film. The increases of calcination temperature and time lead to stronger diffraction peak intensity. High transmittance and blue shift of light absorption edge are the properties of the film prepared at high calcination temperature. The average pore size of the films increases with the increasing calcination temperature as the result of TiO2 crystalline particles growing up and aggregation, accompanied with higher specific surface area. Photocatalytic activity of porous TiO2 films increases with the increasing calcination temperature. The light absorption edge of the films slightly moves to longer wavelength region along with the increasing calcination time. The mesoporous film calcinated at 500 °C for 2 h has the highest transmittance, the maximum surface area, and the maximum total pore volume. Consequently, the optimum degradation activity is achieved on the porous TiO2 film calcinated at 500 °C for 2 h.

Competition between ionic adsorption and desorption on electrochemical double layer capacitor electrodes in acetonitrile solutions at different currents and temperatures

NASA Astrophysics Data System (ADS)

Park, Sieun; Kang, Seok-Won; Kim, Ketack

2017-12-01

The operation of electrochemical double layer capacitors at high currents and viscosities and at low temperatures is difficult. Under these conditions, ion transport is limited, and some of the electrode area is unavailable for adsorption, which results in a low capacitance. Increasing the temperature helps to increase the ionic movement, leading to enhanced adsorption and increased capacitance. In contrast, ion desorption (self-discharge) surpasses the capacitance improvement when ions gain a high amount of energy with increasing temperature. For example, temperatures as high as 70 °C cause a very high rate of ionic desorption in acetonitrile solutions in which the individual properties of the two electrolytes-tetraethylammonium tetrafluoroborate (TEA BF4) and ethylmethylimidazolium tetrafluoroborate (EMI BF4)-are not distinguishable. The capacitance improvement and self-discharge are balanced, resulting in a capacitance peak at mid-range temperatures, i.e., 35-45 °C, in the more viscous electrolyte, i.e., TEA BF4. The less viscous electrolyte, i.e., EMI BF4 has a wider capacitance peak from 25 to 45 °C and higher capacitance than that of TEA BF4. Because the maximum power is obtained in the mid-temperature range (35-45 °C), it is necessary to control the viscosity and temperature to obtain the maximum power in a given device.

Aging of Johari-Goldstein Relaxation in Structural Glasses

NASA Astrophysics Data System (ADS)

Yardimci, Hasan; Leheny, Robert L.

2006-03-01

Using frequency-dependent dielectric susceptibility measurements we characterize the aging in two supercooled liquids, sorbitol and xylitol, below their calorimetric glass transition temperatures, Tg. In addition to the alpha relaxation that tracks the structural dynamics, the susceptibilities of both liquids possess a secondary Johari-Goldstein relaxation at higher frequencies. Following a quench below Tg, the susceptibility slowly approaches equilibrium behavior. For both liquids, features of the Johari-Goldstein relaxation display a dependence on the time since the quench, or aging time, that is very similar to the age dependence of the alpha peak. However, one can not assign a single fictive temperature to both the alpha and Johari-Goldstein relaxations. For example, the peak frequency of the Johari-Goldstein relaxation remains constant during aging for sorbitol while it increases with age for xylitol, inconsistent with a decreasing fictive temperature. This behavior contrasts with that of the high frequency tail of the alpha peak whose shape and position track the aging of the main part of the peak.

Stabilization of kerogen thermal maturation: Evidence from geothermometry and burial history reconstruction, Niobrara Limestone, Berthoud oil field, western Denver Basin, Colorado

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barker, C.E.; Crysdale, B.L.

1990-05-01

The burial history of this fractured Niobrara Limestone reservoir and source rock offers a setting for studying the stabilization of thermal maturity because soon after peak temperature of approximately 100{degree}C was reached, exhumation lowered temperature to about 60-70{degree}C. Vitrinite reflectance (Rm = 0.6-0.7%) and published clay mineralogy data from the Niobrara Limestone indicate that peak paleotemperature was approximately 100{degree}C. Fluid inclusion data also indicate oil migration occurred at 100{degree}C. Burial history reconstruction indicates 100{degree}C was reached in the Niobrara Limestone only during minimum burial, which occurred at 70 Ma and 8000 ft depth. However, erosion beginning at 70 Ma andmore » continuing until 50 Ma removed over 3,000 ft of rock. This depth of erosion agrees with an Rm of 0.4% measured in surface samples of the Pierre Shale. The exhumation of the reservoir decreased temperature by about 30{degree}C to near the corrected bottom-hole temperature of 50-70{degree}C. Lopatin time-temperature index (TTI) analysis suggests the Niobrara Limestone as a source rock matured to the oil generation stage (TTI = 10) about 25 Ma, significantly later than maximum burial, and after exhumation caused cooling. The Lopatin TTI method in this case seems to overestimate the influence of heating time. If time is an important factor, thermal maturity should continue to increase after peak burial and temperature so that vitrinite reflectance will not be comparable to peak paleotemperatures estimated from geothermometers set at near-peak temperature and those estimated from burial history reconstruction. The agreement between geothermometry and the burial history reconstruction in Berthoud State 4 suggests that the influence of heating time must be small. The elapsed time available at near peak temperatures was sufficient to allow stabilization of thermal maturation in this case.« less

Do diurnal patterns of branch carbon uptake and transpiration recover after heat waves? Results from a Mediterranean-type ecosystem experiencing seasonal and exceptional drought

NASA Astrophysics Data System (ADS)

Pivovaroff, A. L.; Pesqueira, A.; Sun, W.; Seibt, U.

2016-12-01

Mediterranean-type ecosystems are biodiversity hotspots, but increasing temperature and changes in precipitation will have significant impacts on vegetation, as evidenced by the current die-back of many woody species in southern California, USA, due to exceptional drought conditions. We installed flow-through chambers on four native woody plant species at Stunt Ranch, a University of California Natural Reserve System site, in order to continuously monitor fluxes of carbon and water at the branch-scale from the growing season through the annual seasonal drought period. Study species included Heteromeles arbutifolia, Malosma laurina, Salvia leucophylla, and Quercus agrifolia. Here we present the results of diurnal flux patterns before, during, and after two extreme heat waves events, when daily maximum temperatures doubled. Under typical summer conditions, which include hot, sunny days, study species exhibited two peaks in carbon assimilation during a diurnal cycle: a peak in the morning and a smaller, secondary peak in the afternoon, separated by a midday depression. During heat wave events, which generally lasted 3 days, species exhibited a small morning peak and no afternoon peak at all. All study species returned to their pre-heat wave diurnal flux patterns, which included the second afternoon peak, when weather conditions returned to normal. Since soil moisture was not affected by the short-term heat wave events, we conclude that the pronounced changes in diurnal patterns, including disappearance of the secondary afternoon peak, are the result of stomatal regulation in response to atmospheric water demand rather than root responses to soil moisture deficits. Our results demonstrate that carbon uptake of native species may be impacted under ongoing climate change when increased temperatures and drought conditions may be sustained.

Changes in seasonality and timing of peak streamflow in snow and semi-arid climates of the north-central United States, 1910–2012

USGS Publications Warehouse

Ryberg, Karen R.; Akyüz, F. Adnan; Wiche, Gregg J.; Lin, Wei

2015-01-01

Changes in the seasonality and timing of annual peak streamflow in the north-central USA are likely because of changes in precipitation and temperature regimes. A source of long-term information about flood events across the study area is the U.S. Geological Survey peak streamflow database. However, one challenge of answering climate-related questions with this dataset is that even in snowmelt-dominated areas, it is a mixed population of snowmelt/spring rain generated peaks and summer/fall rain generated peaks. Therefore, a process was developed to divide the annual peaks into two populations, or seasons, snowmelt/spring, and summer/fall. The two series were then tested for the hypotheses that because of changes in precipitation regimes, the odds of summer/fall peaks have increased and, because of temperature changes, snowmelt/spring peaks happen earlier. Over climatologically and geographically similar regions in the north-central USA, logistic regression was used to model the odds of getting a summer/fall peak. When controlling for antecedent wet and dry conditions and geographical differences, the odds of summer/fall peaks occurring have increased across the study area. With respect to timing within the seasons, trend analysis showed that in northern portions of the study region, snowmelt/spring peaks are occurring earlier. The timing of snowmelt/spring peaks in three regions in the northern part of the study area is earlier by 8.7– 14.3 days. These changes have implications for water interests, such as potential changes in lead-time for flood forecasting or changes in the operation of flood-control dams.

Numerical Analysis of the Temperature Impact on Performance of GaN-Based 460-nm Light-Emitting Diode.

PubMed

Tawfik, Wael Z; Lee, June Key

2018-03-01

The influence of temperature on the characteristics of a GaN-based 460-nm light-emitting diode (LED) prepared on sapphire substrate was simulated using the SiLENSe and SpeCLED software programs. High temperatures impose negative effects on the performance of GaN-based LEDs. As the temperature increases, electrons acquire higher thermal energies, and therefore LEDs may suffer more from high-current loss mechanisms, which in turn causes a reduction in the radiative recombination rate in the active region. The internal quantum efficiency was reduced by about 24% at a current density of 35 A/cm2, and the electroluminescence spectral peak wavelength was redshifted. The LED operated at 260 K and exhibited its highest light output power of ~317.5 mW at a maximum injection current of 350 mA, compared to 212.2 mW for an LED operated at 400 K. However, increasing temperature does not cause a droop in efficiency under high injection conditions. The peak efficiency at 1 mA of injection current decreases more rapidly by ~15% with increasing temperature from 260 to 400 K than the efficiency at high injection current of 350 mA by ~11%.

Correlation between reflectance and photoluminescent properties of al-rich ZnO nano-structures

NASA Astrophysics Data System (ADS)

Khan, Firoz; Baek, Seong-Ho; Ahmad, Nafis; Lee, Gun Hee; Seo, Tae Hoon; Suh, Eun-kyung; Kim, Jae Hyun

2015-05-01

Al rich zinc oxide nano-structured films were synthesized using spin coating sol-gel technique. The films were annealed in oxygen ambient in the temperature range of 200-700 °C. The structural, optical, and photoluminescence (PL) properties of the films were studied at various annealing temperatures using X-ray diffraction spectroscopy, field emission scanning electron microscopy, photoluminescence emission spectra measurement, and Raman and UV-Vis spectroscopy. The optical band gap was found to decrease with the increase of the annealing temperature following the Gauss Amp function due to the confinement of the exciton. The PL peak intensity in the near band region (INBE) was found to increase with the increase of the annealing temperature up to 600 °C, then to decrease fast to a lower value for the annealing temperature of 700 °C due to crystalline quality. The Raman peak of E2 (low) was red shifted from 118 cm-1 to 126 cm-1 with the increase of the annealing temperature. The intensity of the second order phonon (TA+LO) at 674 cm-1 was found to decrease with the increase of the annealing temperature. The normalized values of the reflectance and the PL intensity in the NBE region were highest for the annealing temperature of 600 °C. A special correlation was found between the reflectance at λ = 1000 nm and the normalized PL intensity in the green region due to scattering due to presence of grains.

Effects of meal size, meal type, and body temperature on the specific dynamic action of anurans.

PubMed

Secor, Stephen M; Wooten, Jessica A; Cox, Christian L

2007-02-01

Specific dynamic action (SDA), the increase in metabolism stemming from meal digestion and assimilation, varies as a function of meal size, meal type, and body temperature. To test predictions of these three determinants of SDA, we quantified and compared the SDA responses of nine species of anurans, Bombina orientalis, Bufo cognatus, Ceratophrys ornata, Dyscophus antongilli, Hyla cinerea, Kassina maculata, Kassina senegalensis, Pyxicephalus adspersus, and Rana catesbeiana subjected to meal size, meal type, and body temperature treatments. Over a three to seven-fold increase in meal size, anurans experienced predicted increases in postprandial rates of oxygen consumption (VO(2)) the duration of elevated VO(2) and SDA. Meal type had a significant influence on the SDA response, as the digestion and assimilation of hard-bodied, chitinous crickets, mealworms, and superworms required 76% more energy than the digestion and assimilation of soft-bodied earthworms, waxworms, and neonate rodents. Body temperature largely effected the shape of the postprandial metabolic profile; peak VO(2) increased and the duration of the response decreased with an increase in body temperature. Variation in body temperature did not significantly alter SDA for four species, whereas both H. cinerea and R. catesbeiana experienced significant increases in SDA with body temperature. For 13 or 15 species of anurans ranging in mass from 2.4 to 270 g, SMR, postprandial peak VO(2) and SDA scaled with body mass (log-log) with mass exponents of 0.79, 0.93, and 1.05, respectively.

Melting of size-selected gallium clusters with 60-183 atoms.

PubMed

Pyfer, Katheryne L; Kafader, Jared O; Yalamanchali, Anirudh; Jarrold, Martin F

2014-07-10

Heat capacities have been measured as a function of temperature for size-selected gallium cluster cations with between 60 and 183 atoms. Almost all clusters studied show a single peak in the heat capacity that is attributed to a melting transition. The peaks can be fit by a two-state model incorporating only fully solid-like and fully liquid-like species, and hence no partially melted intermediates. The exceptions are Ga90(+), which does not show a peak, and Ga80(+) and Ga81(+), which show two peaks. For the clusters with two peaks, the lower temperature peak is attributed to a structural transition. The melting temperatures for clusters with less than 50 atoms have previously been shown to be hundreds of degrees above the bulk melting point. For clusters with more than 60 atoms the melting temperatures decrease, approaching the bulk value (303 K) at around 95 atoms, and then show several small upward excursions with increasing cluster size. A plot of the latent heat against the entropy change for melting reveals two groups of clusters: the latent heats and entropy changes for clusters with less than 94 atoms are distinct from those for clusters with more than 93 atoms. This observation suggests that a significant change in the nature of the bonding or the structure of the clusters occurs at 93-94 atoms. Even though the melting temperatures are close to the bulk value for the larger clusters studied here, the latent heats and entropies of melting are still far from the bulk values.

Single-backscattering and quasi-single-backscattering of low energy ions from a cold nickel surface: contribution to the ICISS method

NASA Astrophysics Data System (ADS)

Soszka, W.

1992-09-01

Energy spectra of 5 keV Ne+ and He+ ions backscattered from the cold (100) nickel surface for chosen values of the incidence angles were measured. It was found that the occurrence of the isotope structure of the so-called "single-scattering" peak as well as its position on the energy scale depend on the incidence angle and the target temperature. In comparison to the case of room temperature the "ICISS curve" (the intensity of the single-scattering peak versus the incidence angle) at low temperatures increases up to relatively large angles. The curve in its part shows some structure which is not observed at room temperatures. It has been shown [E.S. Parilis et al., Atomic Collisions in Gases and on Solid Surfaces (FAN, Tashkent, 1988) in Russian] that the doubly scattered ions can have the same energy and exit angle as the singly scattered ions and both components create the quasi-single-scattering peak. The double-scattering component depends in a complex manner on the incidence angle and the target temperature. It is shown that at low temperatures (below 80 K) the intensity of the single-scattering component decreases (a decrease of thermal cross section), and the intensity of the double-scattering component relatively increases. This determines the behaviour of the ICISS curve, which, for low temperatures and light projectiles cannot be treated as a real ICISS curve.

Distribution of invasive and native riparian woody plants across the western USA in relation to climate, river flow, floodplain geometry and patterns of introduction

USGS Publications Warehouse

Ryan McShane,; Daniel Auerbach,; Friedman, Jonathan M.; Auble, Gregor T.; Shafroth, Patrick B.; Michael Merigliano,; Scott, Michael L.; N. Leroy Poff,

2015-01-01

Management of riparian plant invasions across the landscape requires understanding the combined influence of climate, hydrology, geologic constraints and patterns of introduction. We measured abundance of nine riparian woody taxa at 456 stream gages across the western USA. We constructed conditional inference recursive binary partitioning models to discriminate the influence of eleven environmental variables on plant occurrence and abundance, focusing on the two most abundant non-native taxa, Tamarix spp. and Elaeagnus angustifolia, and their native competitor Populus deltoides. River reaches in this study were distributed along a composite gradient from cooler, wetter higher-elevation reaches with higher stream power and earlier snowmelt flood peaks to warmer, drier lower-elevation reaches with lower power and later peaks. Plant distributions were strongly related to climate, hydrologic and geomorphic factors, and introduction history. The strongest associations were with temperature and then precipitation. Among hydrologic and geomorphic variables, stream power, peak flow timing and 10-yr flood magnitude had stronger associations than did peak flow predictability, low-flow magnitude, mean annual flow and channel confinement. Nearby intentional planting of Elaeagnus was the best predictor of its occurrence, but planting of Tamarix was rare. Higher temperatures were associated with greater abundance of Tamarix relative to P. deltoides, and greater abundance of P. deltoides relative toElaeagnus. Populus deltoides abundance was more strongly related to peak flow timing than was that of Elaeagnus or Tamarix. Higher stream power and larger 10-yr floods were associated with greater abundance of P. deltoides and Tamarix relative to Elaeagnus. Therefore, increases in temperature could increase abundance of Tamarix and decrease that of Elaeagnus relative to P. deltoides, changes in peak flow timing caused by climate change or dam operations could increase abundance of both invasive taxa, and dam-induced reductions in flood peaks could increase abundance of Elaeagnus relative to Tamarix and P. deltoides.

The double peaks and symmetric path phenomena in the catalytic activity of Pd/Al2O3-TiO2 catalysts with different TiO2 contents

NASA Astrophysics Data System (ADS)

Zhang, Shen; Guo, Yuyu; Li, Xingying; Wu, Xu; Li, Zhe

2018-06-01

Physicochemical properties of Pd/Al2O3-TiO2 catalysts with different amounts of TiO2 contents were investigated by XRD, nitrogen adsorption-desorption, FTIR, NH3-TPD, H2-TPR and XPS techniques. Catalysts of different compositions were tested in the ethanol oxidation reaction to study the effects of TiO2 contents. Double peaks and symmetric path phenomena were observed at certain temperatures with the increase in TiO2 contents. The symmetric peak phenomena and the diverse activity fluctuations have been ascribed to the controlling factors such as temperature and compositions. With the increase in TiO2 content, the surface area, adsorbed oxygen contents and surface acid quantity decreased gradually. The large surface area and adsorbed oxygen contents were conducive to the performance, while increased acid amounts were not beneficial for ethanol oxidation. At 150 and 175 °C, Pd/AT(X1

On the meaning of peak temperature profiles in inverted metamorphic sequences

NASA Astrophysics Data System (ADS)

Duprat-Oualid, Sylvia; Yamato, Philippe

2017-07-01

Inverted metamorphic sequences (IMS) are common features of main thrust systems on Earth. They exhibit an upwards continuous increase in peak temperature conditions and thereby constitute evidence of the close relationship between the thermal field evolution and tectonic processes. Heat advection and shear heating are known to allow the formation of such metamorphic signatures. Heat diffusion also plays an important role in temperature distribution on both sides of the thrust. Other advection processes such as erosion or accretion may also cause a local peak temperature inversion. Each one of these processes therefore affects the thermal field around the thrust. However, despite the crucial importance of all these processes for the interpretation of the inverted peak temperature signatures, their respective influences have never been quantified and compared all together. To address this issue, we propose an innovative coupled approach. (i) We use two-dimensional numerical models that simulate various thrust systems, allowing for a wide diversity of setups. To illustrate this study, we focus on intracontinental thrust systems for which all processes listed are likely to play a key role in the thermal evolution. We perform a parametric study including kinematic settings (i.e. convergence, erosion and accretion), thermal properties, mechanical strength and heat sources. (ii) Dimensionless numbers based on parameters are used to quantify the relative contributions of each process to the thermal budget evolution. Hence, the three thermal processes (i.e. heat diffusion, heat advection and shear heating) are compared with each other via three dimensionless combinations of the Peclet and Brinkman numbers: RDif, RAdv and RPro, respectively. Erosion and accretion are compared separately, based on a fourth dimensionless number Rea. (iii) We analytically examine the inverted peak temperature recorded along profiles that are perpendicular to the thrust zone defined in our numerical experiments. Each peak temperature profile presenting an inversion can then be characterized by a function of approximation involving six meaningful parameters: the location μFF and width σFF of the maximum peak temperature inversion, the characteristic peak temperature Tcte and gradient GLB beneath the inversion zone, and the inversion-related contrasts in the peak temperature ΔT and gradient ΔG. This coupled approach, linking numerical modelling and analytical treatment, allows to quantitatively interpret IMS in terms of the processes involved. The application of our method to intracontinental thrust systems demonstrates that shear heating and erosion support significant inversions, but that the relative contributions of each process have meaningful consequences. Our results reveal that competition between shear heating and heat diffusion on the one hand, and between erosion and accretion on the other hand have a high impact. In particular, the variability in the rock's mechanical strength strongly influences the features of peak temperature inversions. Consequently, none of these processes can be ignored. Our results highlight the major importance of the rheology of rocks in the thermal evolution of shear zones. Finally, our methodology is not only restricted to the analysis of numerical data but also constitutes a way of broad interest to analyse peak temperature signatures around any shear zone.

Flow Stress and Processing Map of a PM 8009Al/SiC Particle Reinforced Composite During Hot Compression

NASA Astrophysics Data System (ADS)

Luo, Haibo; Teng, Jie; Chen, Shuang; Wang, Yu; Zhang, Hui

2017-10-01

Hot compression tests of 8009Al alloy reinforced with 15% SiC particles (8009Al/15%SiCp composites) prepared by powder metallurgy (direct hot extrusion methods) were performed on Gleeble-3500 system in the temperature range of 400-550 °C and strain rate range of 0.001-1 s-1. The processing map based on the dynamic material model was established to evaluate the flow instability regime and optimize processing parameters; the associated microstructural changes were studied by the observations of optical metallographic and scanning electron microscopy. The results showed that the flow stress increased initially and reached a plateau after peak stress value with increasing strain. The peak stress increased as the strain rate increased and deformation temperature decreased. The optimum parameters were identified to be deformation temperature range of 500-550 °C and strain rate range of 0.001-0.02 s-1 by combining the processing map with microstructural observation.

Association of Temperature and Historical Dynamics of Malaria in the Republic of Korea, Including Reemergence in 1993

NASA Technical Reports Server (NTRS)

Linthicum, Kenneth J.; Anyamba, Assaf; Killenbeck, Bradley; Lee, Won-Ja; Lee, Hee Choon S.; Klein, Terry A.; Kim, Heung-Chul; Pavlin, Julie A.; Britch, Seth C.; Small, Jennifer;

In situ temperature relationships of biochemical and stomatal controls of photosynthesis in four lowland tropical tree species.

PubMed

Slot, Martijn; Winter, Klaus

2017-12-01

Net photosynthetic carbon uptake of Panamanian lowland tropical forest species is typically optimal at 30-32 °C. The processes responsible for the decrease in photosynthesis at higher temperatures are not fully understood for tropical trees. We determined temperature responses of maximum rates of RuBP-carboxylation (V CMax ) and RuBP-regeneration (J Max ), stomatal conductance (G s ), and respiration in the light (R Light ) in situ for 4 lowland tropical tree species in Panama. G s had the lowest temperature optimum (T Opt ), similar to that of net photosynthesis, and photosynthesis became increasingly limited by stomatal conductance as temperature increased. J Max peaked at 34-37 °C and V CMax ~2 °C above that, except in the late-successional species Calophyllum longifolium, in which both peaked at ~33 °C. R Light significantly increased with increasing temperature, but simulations with a photosynthesis model indicated that this had only a small effect on net photosynthesis. We found no evidence for Rubisco-activase limitation of photosynthesis. T Opt of V CMax and J Max fell within the observed in situ leaf temperature range, but our study nonetheless suggests that net photosynthesis of tropical trees is more strongly influenced by the indirect effects of high temperature-for example, through elevated vapour pressure deficit and resulting decreases in stomatal conductance-than by direct temperature effects on photosynthetic biochemistry and respiration. © 2017 John Wiley & Sons Ltd.

Self-preservation and structural transition of gas hydrates during dissociation below the ice point: an in situ study using Raman spectroscopy

NASA Astrophysics Data System (ADS)

Zhong, Jin-Rong; Zeng, Xin-Yang; Zhou, Feng-He; Ran, Qi-Dong; Sun, Chang-Yu; Zhong, Rui-Qin; Yang, Lan-Ying; Chen, Guang-Jin; Koh, Carolyn A.

2016-12-01

The hydrate structure type and dissociation behavior for pure methane and methane-ethane hydrates at temperatures below the ice point and atmospheric pressure were investigated using in situ Raman spectroscopic analysis. The self-preservation effect of sI methane hydrate is significant at lower temperatures (268.15 to 270.15 K), as determined by the stable C-H region Raman peaks and AL/AS value (Ratio of total peak area corresponding to occupancies of guest molecules in large cavities to small cavities) being around 3.0. However, it was reduced at higher temperatures (271.15 K and 272.15 K), as shown from the dramatic change in Raman spectra and fluctuations in AL/AS values. The self-preservation effect for methane-ethane double hydrate is observed at temperatures lower than 271.15 K. The structure transition from sI to sII occurred during the methane-ethane hydrate decomposition process, which was clearly identified by the shift in peak positions and the change in relative peak intensities at temperatures from 269.15 K to 271.15 K. Further investigation shows that the selectivity for self-preservation of methane over ethane leads to the structure transition; this kind of selectivity increases with decreasing temperature. This work provides new insight into the kinetic behavior of hydrate dissociation below the ice point.

Timing of squid migration reflects North Atlantic climate variability.

PubMed

Sims, D W; Genner, M J; Southward, A J; Hawkins, S J

2001-12-22

The environmental and biotic conditions affecting fisheries for cephalopods are only partially understood. A problem central to this is how climate change may influence population movements by altering the availability of thermal resources. In this study we investigate the links between climate and sea-temperature changes and squid arrival time off southwestern England over a 20-year period. We show that veined squid (Loligo forbesi) migrate eastward in the English Channel earlier when water in the preceding months is warmer, and that higher temperatures and early arrival correspond with warm (positive) phases of the North Atlantic oscillation (NAO). The timing of squid peak abundance advanced by 120-150 days in the warmest years ('early' years) compared with the coldest ('late' years). Furthermore, sea-bottom temperature was closely linked to the extent of squid movement. Temperature increases over the five months prior to and during the month of peak squid abundance did not differ between early and late years, indicating squid responded to temperature changes independently of time of year. We conclude that the temporal variation in peak abundance of squid seen off Plymouth represents temperature-dependent movement, which is in turn mediated by climatic changes associated with the NAO. Such climate-mediated movement may be a widespread characteristic of cephalopod populations worldwide, and may have implications for future fisheries management because global warming may alter both the timing and location of peak population abundance.

Wide Temperature Magnetization Characteristics of Transverse Magnetically Annealed Amorphous Tapes for High Frequency Aerospace Magnetics

NASA Technical Reports Server (NTRS)

Niedra, Janis M.; Schwarze, Gene E.

1999-01-01

100 kHz magnetization properties of sample transverse magnetically annealed, cobalt-based amorphous and iron-based nanocrystalline tape wound magnetic cores are presented over the temperature range of -150 C to 150 C, at selected values of B(sub peak). Frequency resolved characteristics are given over the range of 50 kHz to 1 MHz, but at B(sub peak) = 0.1 T and 50 C only. Basic exciting winding current and induced voltage data were taken on bare toroidal cores, in a standard type measurement setup. A linear permeability model, which represents the core by a parallel L-R circuit, is used to interpret and present the magnetization characteristics and several figures of merit applicable to inductor materials are reviewed. The 100 kHz permeability thus derived decreases with increasing temperature for the Fe-based, nanocrystalline material, but increases roughly linearly with temperature for the two Co-based materials, as long as B(sub peak) is sufficiently low to avoid saturation effects. Due to the high permeabilities, rather low values of the 'quality factor' Q, from about 20 to below unity, were obtained over the frequency range of 50 kHz to 1 MHz (50 C, B(sub peak) = 0.1 T). Therefore these cores must be gapped in order to make up high Q or high current inductors. However, being rugged, low core loss materials with flat B-H loop characteristics, they may provide new solutions to specialty inductor applications.

Thermal Index Evaluation of Local SAR in MRI-Based Head Models of Adult and Children for Portable Telephones

NASA Astrophysics Data System (ADS)

Fujiwara, Osamu; Miyamoto, Kayoko; Wang, Jianqing

Biological hazards due to radio-frequency (RF) waves result mainly from the temperature rise in tissue. It should be, therefore, clarified to what extent the RF waves of portable telephones increase the temperature-rise in human brain that includes the central part governing the body-temperature regulation function. In this paper, we calculated both the specific absorption rate (SAR) and the resultant temperature-rise for 900 MHz and 2 GHz portable telephones using the finite-difference time-domain (FDTD) method for three typical use positions, i.e., the vertical position, cheek position and tilt position. As a result, we found that there was an increase for median and 1% value of the cumulative distribution of temperature-rise in children’s brains for any use positions of the portable telephones compared to that in the adult’s brain, and also that the increasing trend in children’s brains for temperature-rise is identical to the temperature-rise trend in children’s hypothalamus. In addition, we found that the ten-gram averaged peak SAR among the adult and children heads had the same trend as that of the 0.1% value of the relatively cumulative distribution of temperature-rise, which shows that the ten-gram averaged peak SAR reflects only the localized temperature-rise in the brain surface.

Magnetic Field-Dependent Magneto-Optical Kerr Effect in [(GeTe)2(Sb2Te3)1]8 Topological Superlattice

NASA Astrophysics Data System (ADS)

Bang, Do; Awano, Hiroyuki; Saito, Yuta; Tominaga, Junji

2016-05-01

We studied the magnetic field dependence of magneto-optical Kerr rotation of the [(GeTe)2/(Sb2Te3)1]8 topological superlattice at different temperatures (from 300 K to 440 K). At low temperatures (less than 360 K), the Kerr signal was within noise level. However, large Kerr rotation peaks with a mirror symmetric loop were at high temperatures (higher than 360 K). The temperature dependence of the observed Kerr signal can be attributed to the breaking of spatial inversion symmetry, which induces a narrow gap in surface state bands due to the Ge atomic layer movement-induced phase transition in the superlattice. We found that the resonant field of each Kerr peak gradually decreases with increasing temperature. On the other hand, the phase transition from a high temperature phase to a low temperature one could be controlled by external magnetic fields.

Enhanced phosphorescence in N contained Ba 2SiO 4:Eu 2+ for X-ray and cathode ray tubes

NASA Astrophysics Data System (ADS)

Wang, Meiyuan; Zhang, Xia; Hao, Zhendong; Ren, Xinguang; Luo, Yongshi; Wang, Xiaojun; Zhang, Jiahua

2010-07-01

A bluish-green color long-lasting phosphorescent phosphor of N contained Ba 2SiO 4:Eu 2+ for X-ray and cathode ray tubes are prepared with the chemical component formula Ba 2SiO 4:0.01Eu 2+ - xSi 3N 4 - 2BaCO 3 ( x = 0.1 to 1.0) by the conventional high-temperature solid-state method. The phosphorescence and fluorescence properties as a function of Si 3N 4 content and temperature are investigated. The emission spectra show a single broad band peaking at 505 nm, which are ascribed to the 4f 65d 1 → 4f 7 transition of Eu 2+. Thermoluminescence (TL) glow-curves show that Ba 2SiO 4:0.01Eu 2+ without N holds a high-temperature peak at 417 K. With increasing the content of Si 3N 4, the phosphorescence grows super-linearly and some new TL peaks appear at low temperatures of about 400, 355, 365, and 335 K. These peaks are ascribed to the formation of new traps related to N substitution for O.

Strong electroluminescence from direct band and defects in Ge n+/p shallow junctions at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Guangyang; Li, Cheng, E-mail: lich@xmu.edu.cn; Chen, Chaowen

2016-05-09

Strong room temperature electroluminescence with two emission peaks at around 0.786 eV and 0.747 eV from Ge n+/p shallow junctions was reported. The peak at around 0.786 eV comes from direct band luminescence (DBL) in n + Ge regions, while the peak fixing at 0.747 eV is resulted from defects induced by ion implantation. Heavy n-type doping in Ge renders realization of strong defect-related luminescence (DRL) feasible. The peak intensity ratio of DRL/DBL decreases with increase of injection current since more electrons are filled in Γ valley. Above all, the Ge n+/p shallow junction is fully compatible with the source and drain in Gemore » metal-oxide-semiconductor field effect transistors.« less

Effect of thermal annealing on the phase evolution of silver tungstate in Ag/WO₃ films.

PubMed

Bose, R Jolly; Sreedharan, R Sreeja; Krishnan, R Resmi; Reddy, V R; Gupta, Mukul; Ganesan, V; Sudheer, S K; Pillai, V P Mahadevan

2015-06-15

Silver/tungsten oxide multi-layer films are deposited over quartz substrates by RF magnetron sputtering technique and the films are annealed at temperatures 200, 400 and 600°C. The effect of thermal annealing on the phase evolution of silver tungstate phase in Ag/WO3 films is studied extensively using techniques like X-ray diffraction, micro-Raman analysis, atomic force microscopy and photoluminescence studies. The XRD pattern of the as-deposited film shows only the peaks of cubic phase of silver. The film annealed at 200°C shows the presence of XRD peaks corresponding to orthorhombic phase of Ag2WO4 and peaks corresponding to cubic phase of silver with reduced intensity. It is found that, as annealing temperature increases, the volume fraction of Ag decreases and that of Ag2WO4 phase increases and becomes highest at a temperature of 400°C. When the temperature increases beyond 400°C, the volume fraction of Ag2WO4 decreases, due to its decomposition into silver and oxygen deficient phase Ag2W4O13. The micro-Raman spectra of the annealed films show the characteristic bands of tungstate phase which is in agreement with XRD analysis. The surface morphology of the films studied by atomic force microscopy reveals that the particle size and r.m.s roughness are highest for the sample annealed at 400°C. In the photoluminescence study, the films with silver tungstate phase show an emission peak in blue region centered around the wavelength 441 nm (excitation wavelength 256 nm). Copyright © 2015 Elsevier B.V. All rights reserved.

Northwestern Pacific typhoon intensity controlled by changes in ocean temperatures.

PubMed

Mei, Wei; Xie, Shang-Ping; Primeau, François; McWilliams, James C; Pasquero, Claudia

2015-05-01

Dominant climatic factors controlling the lifetime peak intensity of typhoons are determined from six decades of Pacific typhoon data. We find that upper ocean temperatures in the low-latitude northwestern Pacific (LLNWP) and sea surface temperatures in the central equatorial Pacific control the seasonal average lifetime peak intensity by setting the rate and duration of typhoon intensification, respectively. An anomalously strong LLNWP upper ocean warming has favored increased intensification rates and led to unprecedentedly high average typhoon intensity during the recent global warming hiatus period, despite a reduction in intensification duration tied to the central equatorial Pacific surface cooling. Continued LLNWP upper ocean warming as predicted under a moderate [that is, Representative Concentration Pathway (RCP) 4.5] climate change scenario is expected to further increase the average typhoon intensity by an additional 14% by 2100.

Fast, comprehensive two-dimensional liquid chromatography

PubMed Central

Stoll, Dwight R.; Li, Xiaoping; Wang, Xiaoli; Carr, Peter W.; Porter, Sarah E. G.; Rutan, Sarah C.

2011-01-01

The absolute need to improve the separating power of liquid chromatography, especially for multi-constituent biological samples, is becoming increasingly evident. In response, over the past few years, there has been a great deal of interest in the development of two dimension liquid chromatography (2DLC). Just as 1DLC is preferred to 1DGC based on its compatibility with biological materials we believe that ultimately 2DLC will be preferred to the much more highly developed 2DGC for such samples. The huge advantage of 2D chromatographic techniques over 1D methods is inherent in the tremendous potential increase in peak capacity (resolving power). This is especially true of comprehensive 2D chromatography wherein it is possible, under ideal conditions, to obtain a total peak capacity equal to the product of the peak capacities of the first and second dimension separations. However, the very long timescale (typically several hours to tens of hours) of comprehensive 2DLC is clearly its chief drawback. Recent advances in the use of higher temperatures to speed up isocratic and gradient elution liquid chromatography have been used to decrease the time needed to do the second dimension LC separation of 2DLC to about 20 seconds for a full gradient elution run. Thus fast, high temperature LC is becoming a very promising technique. Peak capacities of over 2000 and rates of peak capacity production of nearly 1 peak/s have been achieved. In consequence, many real samples showing more than 200 peaks with signal to noise ratios of better than 10:1 have been run in total times of under 30 minutes. This report is not intended to be a comprehensive review of 2DLC, but is deliberately focused on the issues involved in doing fast 2DLC by means of elevating the column temperature; however, many issues of broader applicability will be discussed. PMID:17888443

Effects of asphalt rejuvenator on thermal and mechanical properties on oxidized hot mixed asphalt pavements

NASA Astrophysics Data System (ADS)

Farace, Nicholas A.; Buttlar, William G.; Reis, Henrique

2016-04-01

The utilization of asphalt rejuvenator, and its effectiveness for restoring thermal and mechanical properties was investigated via Disk-shaped Compact Tension (DC(T)) and acoustic emission (AE) testing for determining mechanical properties and embrittlement temperatures of the mixtures. During the DC(T) testing the fracture energies and peak loads were used to measure the resistance of the rejuvenated asphalt to low temperature cracking. The AE testing monitored the acoustic emission activity while the specimens were cooled from room temperature to -40 °C to estimate the temperature at which thermal cracking began (i.e. the embrittlement temperature). First, a baseline response was obtained by obtaining the mechanical and thermal response of virgin HMA samples and HMA samples that had been exposed to oxidative aging for 36 hours at 135°C. The results showed the virgin samples had much higher peak loads and fracture energies than the 36 hours aged samples. Acoustic Emission showed similar results with the virgin samples having embrittlement temperatures 10 °C cooler than the 36 hours aged specimens. Then, overaged for 36 hours specimens were treated different amounts of rejuvenator (10%, 15%, and 20% by weight of binder content) and left to dwell for increased amount of time periods varying from one to eight weeks. It was observed that the AE results showed an improvement of embrittlement temperature with increasing with the dwell times. The 8 weeks specimens had cooler embrittlement temperatures than the virgin specimens. Finally, the low temperature effects on fracture energy and peak load of the rejuvenated asphalt was investigated. Rejuvenator was applied (10% by weight of binder) to specimens aged 36 hours at 135 °C, and the dwell time was varied from 1 to 4 weeks. The results showed that the peak loads were restored to levels of the virgin specimens, and the fracture energies improved to levels beyond that of the virgin specimens. The results also showed a general trend of improvement for the AE testing of the embrittlement temperature.

Calculating the electron temperature in the lightning channel by continuous spectrum

NASA Astrophysics Data System (ADS)

Xiangcheng, DONG; Jianhong, CHEN; Xiufang, WEI; Ping, YUAN

2017-12-01

Based on the theory of plasma continuous radiation, the relationship between the emission intensity of bremsstrahlung and recombination radiation and the plasma electron temperature is obtained. During the development process of a return stroke of ground flash, the intensity of continuous radiation spectrum is separated on the basis of the spectrums with obviously different luminous intensity at two moments. The electron temperature of the lightning discharge channel is obtained through the curve fitting of the continuous spectrum intensity. It is found that electron temperature increases with the increase of wavelength and begins to reduce after the peak. The peak temperature of the two spectra is close to 25 000 K. To be compared with the result of discrete spectrum, the electron temperature is fitted by the O I line and N II line of the spectrum respectively. The comparison shows that the high temperature value is in good agreement with the temperature of the lightning core current channel obtained from the ion line information, and the low temperature at the high band closes to the calculation result of the atomic line, at a low band is lower than the calculation of the atomic line, which reflects the temperature of the luminous channel of the outer corona.

Shallow Carrier Trap Levels in GaAsN Investigated by Photoluminescence

NASA Astrophysics Data System (ADS)

Inagaki, Makoto; Suzuki, Hidetoshi; Suzuki, Akio; Mutaguchi, Kazumasa; Fukuyama, Atsuhiko; Kojima, Nobuaki; Ohshita, Yoshio; Yamagichi, Masafumi

2011-04-01

Shallow carrier trap levels in GaAs1-xNx (0.0010≤x≤0.0038) were investigated by photoluminescence (PL) and photoreflectance (PR) ranging from 4.2 to 300 K. The band gap energies of the GaAsN were clearly determined in the whole temperature range by the PR fitting analysis. It is clarified by peak decomposing that there were three emission peaks in the near-band-edge PL spectra of GaAsN. One of them was originated from band-to-band transition. The energies of two emission peaks were located at approximately 6 and 17 meV below the band edge. The existence of these peaks is evidence of carrier localization at the near-band-edge. The intensity ratio of the peak at the low energy side to other peaks increases with increasing N composition. This behavior is similar to the degradation of electrical properties.

Experimental study of effect of magnetic field on anode temperature distribution in an ATON-type Hall thruster

NASA Astrophysics Data System (ADS)

Liu, Jinwen; Li, Hong; Mao, Wei; Ding, Yongjie; Wei, Liqiu; Li, Jianzhi; Yu, Daren; Wang, Xiaogang

2018-05-01

The energy deposition caused by the absorption of electrons by the anode is an important cause of power loss in a Hall thruster. The resulting anode heating is dangerous, as it can potentially reduce the thruster lifetime. In this study, by considering the ring shape of the anode of an ATON-type Hall thruster, the effects of the magnetic field strength and gradient on the anode ring temperature distribution are studied via experimental measurement. The results show that the temperature distribution is not affected by changes in the magnetic field strength and that the position of the peak temperature is essentially unchanged; however, the overall temperature does not change monotonically with the increase of the magnetic field strength and is positively correlated with the change in the discharge current. Moreover, as the magnetic field gradient increases, the position of the peak temperature gradually moves toward the channel exit and the temperature tends to decrease as a whole, regardless of the discharge current magnitude; in any case, the position of the peak temperature corresponds exactly to the intersection of the magnetic field cusp with the anode ring. Further theoretical analysis shows that the electrons, coming from the ionization region, travel along two characteristic paths to reach the anode under the guidance of the cusped magnetic field configuration. The change of the magnetic field strength or gradient changes the transfer of momentum and energy of the electrons in these two paths, which is the main reason for the changes in the temperature and distribution. This study is instructive for matching the design of the ring-shaped anode and the cusp magnetic field of an ATON-type Hall thruster.

Historical channel-planform change of the Little Colorado River near Winslow, Arizona

USGS Publications Warehouse

Block, Debra L.

2014-01-01

This study evaluates channel-planform adjustment on an alluvial reach of the Little Colorado River and documents the geomorphic evolution of the channel through an analysis of aerial photographs and orthophotographs for the period 1936–2010. The Little Colorado River has adjusted to the effects of an extreme flood in 1923 and a subsequent decline in peak discharge and mean annual flow by channel narrowing: the channel width and area of the river have decreased by approximately 90 percent over the study period. Although deposition historically exceeds erosion, lateral migration exacerbates localized erosion, particularly near hydraulic controls. Despite repeated cutoff and avulsion, the Little Colorado River has steadily increased in length and sinuosity over a period of 74 years. Changes in temperature and precipitation are likely affecting the discharge of the Little Colorado River near and downstream of Winslow, Ariz. Nonparametric methods of trend detection determine whether the probability distribution of temperature, precipitation, and peak streamflow has changed over time. Time-series plots of temperature and precipitation show statistically significant trends at the 99-percent-confidence level when evaluated with a Mann-Kendall test. An increasing trend was indicated in mean daily minimum air temperature (Tmin), whereas decreasing trends were indicated in both annual precipitation (Pann) and monsoon-seasonal precipitation (Pjas), as well as in peak discharge.

Dynamic stiffness of chemically and physically ageing rubber vibration isolators in the audible frequency range: Part 2—waveguide solution

NASA Astrophysics Data System (ADS)

Kari, Leif

2017-09-01

The dynamic stiffness of a chemically and physically ageing rubber vibration isolator in the audible frequency range is modelled as a function of ageing temperature, ageing time, actual temperature, time, frequency and isolator dimension. In particular, the dynamic stiffness for an axially symmetric, homogeneously aged rubber vibration isolator is derived by waveguides where the eigenmodes given by the dispersion relation for an infinite cylinder satisfying traction free radial surface boundary condition are matched to satisfy the displacement boundary conditions at the lateral surface ends of the finite rubber cylinder. The constitutive equations are derived in a companion paper (Part 1). The dynamic stiffness is calculated over the whole audible frequency range 20-20,000 Hz at several physical ageing times for a temperature history starting at thermodynamic equilibrium at +25°C and exposed by a sudden temperature step down to -60°C and at several chemical ageing times at temperature +25°C with simultaneous molecular network scission and reformation. The dynamic stiffness results are displaying a strong frequency dependence at a short physical ageing time, showing stiffness magnitude peaks and troughs, and a strong physical ageing time dependence, showing a large stiffness magnitude increase with the increased physical ageing time, while the peaks and troughs are smoothed out. Likewise, stiffness magnitude peaks and troughs are frequency-shifted with increased chemical ageing time. The developed model is possible to apply for dynamic stiffness prediction of rubber vibration isolator over a broad audible frequency range under realistic environmental condition of chemical ageing, mainly attributed to oxygen exposure from outside and of physical ageing, primarily perceived at low-temperature steps.

Toward understanding the structural heterogeneity and ion pair stability in dicationic ionic liquids.

PubMed

Li, Song; Bañuelos, José Leobardo; Zhang, Pengfei; Feng, Guang; Dai, Sheng; Rother, Gernot; Cummings, Peter T

2014-12-07

The structural and dynamical properties of dicationic ionic liquids (DILs) [Cn(mim)2](Tf2N)2, that is, 3-methylimidazolium dications separated by an alkyl chain and with bis(trifluoromethylsulfonyl)amide as the anion, were investigated by molecular dynamics (MD) simulation in combination with small/wide-angle X-ray scattering (SWAXS) measurements. Enhanced spatial heterogeneity is observed as the DIL chain length is increased, characterized by the changes in the scattering and the increased heterogeneity order parameter (HOP). Temperature variation imposes only slight influences on the local structures of DILs compared to monocationic ionic liquids (MILs). The peaks at 0.9 Å(-1) and 1.4 Å(-1) of the structure function shift towards low Q as the temperature increases, in a similar manner to MILs, and changes in peak positions in response to temperature changes are reflected in HOP variations. However, the prepeak shift with increasing temperature is ∼3 times smaller in DILs compared to MILs, and both MD and SWAXS indicate a DIL-specific prepeak shifting. Furthermore, the high ion pair/ion cage stability in DILs is indicative of high thermal stability and relative insensitivity of structural heterogeneity to temperature variation, which might be caused by the stronger Coulombic interactions in DILs.

Raman studied of undoped amorphous carbon thin film deposited by bias assisted-CVD

NASA Astrophysics Data System (ADS)

Ishak, A.; Fadzilah, A. N.; Dayana, K.; Saurdi, I.; Malek, M. F.; Nurbaya, Z.; Shafura, A. K.; Rusop, M.

2018-05-01

The undoped amorphous carbon thin film carbon was deposited at 200°C-350°C by bias assisted-CVD using palm oil as a precursor material. The effect of different substrate deposition temperatures on structural and electrical properties of undoped doped amorphous carbon film was discussed. The structural of undoped amorphous carbon films were correlated with Raman analysis through the evolution of D and G bands, Fourier spectra, and conductivity measurement. The spectral evolution observed showed the increase of upward shift of D and G peaks as substrate deposition temperatures increased. The spectral evolution observed at different substrate deposition temperatures show progressive formation of crystallites. It was predicted that small number of hydrogen is terminated with carbon at surface of thin film as shown by FTIR spectra since palm oil has high number of hydrogen (C67H127O8). These structural changes were further correlated with conductivity and the results obtained are discussed and compared. The conductivity is found in the range of 10-8 Scm-1. The increase of conductivity is correlated by the change of structural properties as correlated with characteristic parameters of Raman spectra including the position of G peak, full width at half maximum of G peak, and ID/IG and FTIR result.

Boson peak of alkali and alkaline earth silicate glasses: influence of the nature and size of the network-modifying cation.

PubMed

Richet, Nicolas F

2012-01-21

The influence of the size of the alkaline earth cation on the boson peak of binary metasilicate glasses, MSiO(3) (M = Mg, Ca, Sr, Ba), has been investigated from vibrational densities of states determined by inversion of low-temperature heat capacities. As given both by C(p)/T(3) and g(ω)/ω(2), the intensity of the boson peak undergoes a 7-fold increase from Mg to Ba, whereas its temperature and frequency correlatively decrease from 18 to 10 K and from 100 to 20 cm(-1), respectively. The boson peak results from a combination of librations of SiO(4) tetrahedra and localized vibrations of network-modifying cations with non-bridging oxygens whose contribution increases markedly with the ionic radius of the alkaline earth. As a function of ionic radii, the intensity for Sr and Ba varies in the same way as previously found for alkali metasilicate glasses. The localized vibrations involving alkali and heavy alkaline earth cations appear to be insensitive to the overall glass structure. Although the new data are coherent with an almost linear relationship between the temperature of the boson peak and transverse sound velocity, pure SiO(2) and SiO(2)-rich glasses make marked exceptions to this trend because of the weak transverse character of SiO(4) librations. Finally, the universality of the calorimetric boson peak is again borne out because all data for silicate glasses collapse on the same master curve when plotted in a reduced form (C(P)∕/T(3))/(C(P)/T(3))(b) vs. T/T(b). © 2012 American Institute of Physics

Studies of oxidation and thermal reduction of the Cu(100) surface using low energy positrons

NASA Astrophysics Data System (ADS)

Fazleev, N. G.; Maddox, W. B.; Weiss, A. H.

2010-03-01

Changes in the surface of an oxidized Cu(100) single crystal resulting from vacuum annealing have been investigated using positron annihilation induced Auger electron spectroscopy (PAES). PAES measurements show a large increase in the intensity of the Cu M2,3VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300 C. The intensity then decreases monotonically as the annealing temperature is increased to ˜600 C. In contrast, the O KLL PAES intensity is the lowest at 300 C and it starts to increase again as the temperature is increased further. PAES results are analyzed by performing calculations of positron surface states and annihilation characteristics taking into account the charge redistribution at the surface, surface reconstructions, and changes of electronic properties of the surfaces with adsorbed oxygen. Possible explanation is proposed for the observed behavior of the intensity of positron annihilation induced Cu M2,3VV and O KLL Auger peaks and probabilities of annihilation of surface trapped positrons with Cu 3p and O 1s core-level electrons with changes of the annealing temperature.

Increasing Boiling Heat Transfer using Low Conductivity Materials

PubMed Central

Mahamudur Rahman, Md; Pollack, Jordan; McCarthy, Matthew

2015-01-01

We report the counterintuitive mechanism of increasing boiling heat transfer by incorporating low-conductivity materials at the interface between the surface and fluid. By embedding an array of non-conductive lines into a high-conductivity substrate, in-plane variations in the local surface temperature are created. During boiling the surface temperature varies spatially across the substrate, alternating between high and low values, and promotes the organization of distinct liquid and vapor flows. By systematically tuning the peak-to-peak wavelength of this spatial temperature variation, a resonance-like effect is seen at a value equal to the capillary length of the fluid. Replacing ~18% of the surface with a non-conductive epoxy results in a greater than 5x increase in heat transfer rate at a given superheat temperature. This drastic and counterintuitive increase is shown to be due to optimized bubble dynamics, where ordered pathways allow for efficient removal of vapor and the return of replenishing liquid. The use of engineered thermal gradients represents a potentially disruptive approach to create high-efficiency and high-heat-flux boiling surfaces which are naturally insensitive to fouling and degradation as compared to other approaches. PMID:26281890

Thermal characteristic of limonite ore upon calcination and reduction

NASA Astrophysics Data System (ADS)

Febriana, Eni; Manaf, Azwar; Prasetyo, A. B.; Mayangsari, W.

2018-05-01

Thermal characteristics of the limonite laterite ore types have been studied using TG / DTA. There are four endothermic peaks at 250, 646, 900, and 1023 °C with a total mass loss of 10.07wt%. These four peaks correspond to the XRD results on samples calcined at 600-1000 °C. Analysis of TG / DTA to the mixture of limonite and graphite showed two endothermic reaction peaks at 641 and 900 °C and an exothermic peak at 1180 °C. Reduction of the limonite-graphite mixture was done by heating at 800-1100 °C for 1 hour, and the reduced samples were analyzed using XRD. The results indicate that the reduction process proceed completely at higher temperatures, indicated by the increasing intensity of kamacite and Fe metal phase, and the decrease of peak intensity of carbon due to reaction with metal oxides. At 1100 °C, intensity of Fe-metal decreased due to sintering of Fe which may occur because the temperature was too high.

Experimental measurement of stationary SS 304, SS 316L and 8630 GTA weld pool surface temperatures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kraus, H.G.

1989-07-01

The optical spectral radiometric/laser reflectance experimental method, previously developed by the author, was extended to obtain high-resolution surface temperature maps of stationary GTA molten weld pools using thick-plate SS 304, SS316L, and 8630 steel. Increasing the welding current from 50 to 200 A resulted in peak pool surface temperatures from 1050{sup 0} to 2400{sup 0}C for the SS 304. At a constant welding current of 150 A, the SS 304 and various heats of SS 316L and 8630 resulted in peak weld pool temperatures from 2300{sup 0} to 2700{sup 0}C. Temperature contour plots of all the welds made are given.more » Surface temperature maps are classified into types that are believed to be indicative of the convective circulation patterns present in the weld pools.« less

Increasing synchrony of high temperature and low flow in western North American streams: Double trouble for coldwater biota?

Treesearch

Ivan Arismendi; Mohammad Safeeq; Sherri L. Johnson; Jason B Dunham; Roy Haggerty

2013-01-01

Flow and temperature are strongly linked environmental factors driving ecosystem processes in streams. Stream temperature maxima (Tmax_w) and stream flow minima (Qmin) can create periods of stress for aquatic organisms. In mountainous areas, such as western North America, recent shifts toward an earlier spring peak flow and...

ESTIMATING RISK TO CALIFORNIA ENERGY INFRASTRUCTURE FROM PROJECTED CLIMATE CHANGE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sathaye, Jayant; Dale, Larry; Larsen, Peter

2011-06-22

This report outlines the results of a study of the impact of climate change on the energy infrastructure of California and the San Francisco Bay region, including impacts on power plant generation; transmission line and substation capacity during heat spells; wildfires near transmission lines; sea level encroachment upon power plants, substations, and natural gas facilities; and peak electrical demand. Some end-of-century impacts were projected:Expected warming will decrease gas-fired generator efficiency. The maximum statewide coincident loss is projected at 10.3 gigawatts (with current power plant infrastructure and population), an increase of 6.2 percent over current temperature-induced losses. By the end ofmore » the century, electricity demand for almost all summer days is expected to exceed the current ninetieth percentile per-capita peak load. As much as 21 percent growth is expected in ninetieth percentile peak demand (per-capita, exclusive of population growth). When generator losses are included in the demand, the ninetieth percentile peaks may increase up to 25 percent. As the climate warms, California's peak supply capacity will need to grow faster than the population.Substation capacity is projected to decrease an average of 2.7 percent. A 5C (9F) air temperature increase (the average increase predicted for hot days in August) will diminish the capacity of a fully-loaded transmission line by an average of 7.5 percent.The potential exposure of transmission lines to wildfire is expected to increase with time. We have identified some lines whose probability of exposure to fire are expected to increase by as much as 40 percent. Up to 25 coastal power plants and 86 substations are at risk of flooding (or partial flooding) due to sea level rise.« less

Experimental Investigation of Local Oscillator Chains with GaAs Planar Diodes at Cryogenic Temperatures

NASA Technical Reports Server (NTRS)

Maestrini, A.; Pukala, D.; Schlecht, E.; Mehdi, I.; Erickson, N.

2001-01-01

This paper will describe a robust test-bed that has been built to measure multiplier performance over a wide range of temperatures and frequencies. In a 182-212 GRz designed balanced doubler the peak efficiency at 201 GHz improves from 22% to 28% upon cooling from 300 K to 120 K. This stage is then used to pump a 362-424 GRz balanced planar doubler. The peak chain efficiency increases from 3.4% to 6% when the two cascaded doublers are cooled from 300 K to 120 K. This enables the production of 10 mW of peak output power at 377 GHz, which ought to be sufficient for driving the next stage multiplier.

A simple technique to prolong molding time during application of a fiberglass cast: An in vitro study

PubMed Central

Ayzenberg, Mark; Narvaez, Michael; Raphael, James

2018-01-01

Casting is routinely used for acute and post-operative immobilization and remains a cornerstone in the non-operative management of fractures and deformities. The application of a properly fitted and wellmolded cast, especially for a trainee, can be challenging. We present a simple method of prolonging cure time of fiberglass cast — placing ice in the dip water. Eight-ply, fiveinch fiberglass cast was circumferentially applied to an aluminum-wrapped cardboard cylinder. An electronic, 2-channel temperature sensor (TR-71wf Temp Logger, T&D Corporation, Matsumoto, Japan), accurate to 0.1ºC and accurate to ±0.3ºC, was placed between the fourth and fifth layers of fiberglass. Thirty total casts were tested using 9±1ºC (cold), 22±1ºC (ambient), and 36±1ºC (warm) dip water. Room temperature was maintained at 24±1ºC. Cast temperatures were measured during the exothermic reaction generated by the cast curing. Peak temperatures and cure times were recorded. Cure time was defined as the point of downward deflection on the timetemperature curve immediately after peak. Cure and peak temperatures were compared among groups using analysis of variance. Mean cure time was 3.5±0.1 minutes for warm water, 5.0±0.4 minutes for ambient water and 7.0±0.5 minutes for cold water. Peak temperature, measured between layers 4 and 5 of the cast material, was 36.6±0.8ºC for warm water, 31.1±1.4ºC for ambient water and 25.2±0.5ºC for cold water. Cold afforded, on average, an additional 2 minutes (40% increase) in cure time compared to ambient water and an additional 3.5 minutes (100% increase) compared to warm water. Cure time differences were significant (P<0.001) for all groups, as were peak temperature differences (P<0.001). Temperatures concerning for development of burns were never reached. Utilizing iced dip water when casting is a simple and effective method to prolong the time available for cast application. Orthopedic residents and trainees may find this useful in learning to fabricate a high quality cast. For the experienced orthopedic surgeon, this method eliminates the need to bridge longlimb casts and facilitates the application of complex casts. PMID:29770174

Hot deformation constitutive equation and processing map of Alloy 690

NASA Astrophysics Data System (ADS)

Feng, Han; Zhang, Songchuang; Ma, Mingjuan; Song, Zhigang

The hot deformation behavior of alloy 690 was studied in the temperature range of 800-1300 C and strain rate range of 0.1-10 s-1 by hot compression tests in a Gleeble 1500+ thermal mechanical simulator. The results indicated that flow stress of alloy 690 is sensitive to deformation temperature and strain rate and peak stress increases with decreasing of temperature and increasing of strain rate. In addition, the hot deformation parameters of deformation activation were calculated and the apparent activation energy of this alloy is about 300 kJ/mol. The constitutive equation which can be used to relate peak stress to the absolute temperature and strain rate was obtained. It's further found that the processing maps exhibited two domains which are considered as the optimum windows for hot working. The microstructure observations of the specimens deformed in this domain showed the full dynamic recrystallization (DRX) structure. There was a flow instability domain in the processing map where hot working should be avoided.

Dehydration and crystallization kinetics of zirconia-yttria gels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ramanathan, S.; Muraleedharan, R.V.; Roy, S.K.

1995-02-01

Zirconia and zirconia-yttria gels containing 4 and 8 mol% yttria were obtained by coprecipitation and drying at 373 K. The dehydration and crystallization behavior of the dried gels was studied by DSC, TG, and XRD. The gels undergo elimination of water over a wide temperature range of 373--673 K. The peak temperature of the endotherm corresponding to dehydration and the kinetic constants for the process were not influenced by the yttria content of the gel. The enthalpy of dehydration observed was in good agreement with the heat of vaporization data. The dehydration was followed by a sharp exothermic crystallization process.more » The peak temperature of the exotherm and the activation energy of the process increased with an increase in yttria content, while the enthalpy of crystallization showed a decrease. The ``glow effect`` reduced with increasing yttria content. Pure zirconia crystallizes in the tetragonal form while the zirconia containing 4 and 8 mol% yttria appears to crystallize in the cubic form.« less

Minimization of material inter-diffusion for thermally stable quaternary-capped InAs quantum dot via strain modification

NASA Astrophysics Data System (ADS)

Ghadi, Hemant; Sehara, Navneet; Murkute, Punam; Chakrabarti, Subhananda

2017-05-01

In this study, a theoretical model is developed for investigating the effect of thermal annealing on a single-layer quaternary-capped (In0.21Al0.21Ga0.58As) InAs quantum dot heterostructure (sample A) and compared to a conventional GaAs-capped sample (sample B). Strain, an interfacial property, aids in dot formation; however, it hinders interdiffusion (up to 650 °C), rendering thermal stability to heterostructures. Three diffusing species In/Al/Ga intermix because of the concentration gradient and temperature variation, which is modeled by Fick's law of diffusion. Ground-state energy for both carriers (electron and holes) is calculated by the Schrodinger equation at different annealing temperatures, incorporating strain computed by the concentration-dependent model. Change in activation energy due to strain decreases particle movement, thereby resulting in thermally stable structures at low annealing temperatures. At low temperature, the conduction band near the dot edge slightly decreases, attributed to the comparatively high strain. Calculated results are consistent with the experimental blue-shift i.e. towards lower wavelength of photoluminescence peak on the same sample with increasing annealing temperatures. Cross-sectional transmission microscopy (TEM) images substantiate the existence of dot till 800 °C for sample (A). With increasing annealing temperature, interdiffusion and dot sublimation are observed in XTEM images of samples A and B. Strain calculated from high-resolution X-ray diffraction (HRXRD) peaks and its decline with increasing temperature are in agreement with that calculated by the model. For highlighting the benefits of quaternary capping, InAlGaAs capping is theoretically and experimentally compared to GaAs capping. Concentration-dependent strain energy is calculated at every point and is further used for computing material interdiffusion, band profiles, and photoluminescence peak wavelength, which can provide better insights into strain energy behavior with temperature and help in the better understanding of thermal annealing.

Diurnal and seasonal change in stem respiration of Larix principis-rupprechtii trees, northern China.

PubMed

Yang, Yan; Zhao, Miao; Xu, Xiangtao; Sun, Zhenzhong; Yin, Guodong; Piao, Shilong

2014-01-01

Stem respiration is a critical and uncertain component of ecosystem carbon cycle. Few studies reported diurnal change in stem respiration as well as its linkage with climate. In this study, we investigated the diurnal and seasonal change in stem respiration and its linkage with environmental factors, in larch plantations of northern China from 2010 to 2012. The stem respiration per unit surface area (RS) showed clear diurnal cycles, ranging from 1.65±0.10 to 2.69±0.15 µmol m(-2) s(-1), increased after 6∶00, peaked at 15∶00 and then decreased. Both stem temperature and air temperature show similar diurnal pattern, while the diurnal pattern of air relative humidity is just the opposite to Rs. Similar to the diurnal cycles, seasonal change in RS followed the pattern of stem temperature. RS increased from May (1.28±0.07 µmol m(-2) s(-1)) when the stem temperature was relatively low and peaked in July (3.02±0.10 µmol m(-2) s(-1)) when the stem temperature was also the highest. Further regression analyses show that RS exponentially increases with increasing temperature, and the Q10 of Rs at mid daytime (1.97±0.17 at 12∶00 and 1.96±0.10 at 15∶00) is significantly lower than that of mid nighttime (2.60±0.14 at 00∶00 and 2.71±0.25 at 03∶00) Q10. This result not only implies that Rs is more sensitive to night than day warming, but also highlights that temperature responses of Rs estimated by only daytime measurement can lead to underestimated stem respiration increase under global warming, especially considering that temperature increase is faster during nighttime.

Improving Photovoltaic Energy Production with Fiber-Optic Distributed Temperature Sensing

NASA Astrophysics Data System (ADS)

Hausner, M. B.; Berli, M.

2014-12-01

The efficiency of solar photovoltaic (PV) generators declines sharply with increased temperatures. Peak solar exposure often occurs at the same time as peak temperatures, but solar PV installations are typically designed based on solar angle. In temperate areas, the peak temperatures may not be high enough to induce significant efficiency losses. In some of the areas with the greatest potential for solar development, however, summer air temperatures regularly reach 45 °C and PV panel temperatures exceed the air temperatures. Here we present a preliminary model of a PV array intended to optimize solar production in a hot and arid environment. The model begins with the diurnal and seasonal cycles in the angle and elevation of the sun, but also includes a meteorology-driven energy balance to project the temperatures of the PV panels and supporting structure. The model will be calibrated and parameterized using a solar array at the Desert Research Institute's (DRI) Renewable Energy Deployment and Display (REDD) facility in Reno, Nevada, and validated with a similar array at DRI's Las Vegas campus. Optical fibers will be installed on the PV panels and structural supports and interrogated by a distributed temperature sensor (DTS) to record the spatial and temporal variations in temperature. Combining the simulated panel temperatures, the efficiency-temperature relationship for the panels, and the known solar cycles at a site will allow us to optimize the design of future PV collectors (i.e., the aspect and angle of panels) for given production goals.

New Scenario of Dynamical Heterogeneity in Supercooled Liquid and Glassy States of 2D Monatomic System.

PubMed

Van Hoang, Vo; Teboul, Victor; Odagaki, Takashi

2015-12-24

Via analysis of spatiotemporal arrangements of atoms based on their dynamics in supercooled liquid and glassy states of a 2D monatomic system with a double-well Lennard-Jones-Gauss (LJG) interaction potential, we find a new scenario of dynamical heterogeneity. Atoms with the same or very close mobility have a tendency to aggregate into clusters. The number of atoms with high mobility (and size of their clusters) increases with decreasing temperature passing over a maximum before decreasing down to zero. Position of the peak moves toward a lower temperature if mobility of atoms in clusters is lower together with an enhancement of height of the peak. In contrast, the number of atoms with very low mobility or solidlike atoms (and size of their clusters) has a tendency to increase with decreasing temperature and then it suddenly increases in the vicinity of the glass transition temperature leading to the formation of a glassy state. A sudden increase in the number of strongly correlated solidlike atoms in the vicinity of a glass transition temperature (Tg) may be an origin of a drastical increase in viscosity of the glass-forming systems approaching the glass transition. In fact, we find that the diffusion coefficient decays exponentially with a fraction of solidlike atoms exhibiting a sudden decrease in the vicinity of the glass transition region.

Studies of Oxidation of the Cu(100) Surface Using Low Energy Positrons

NASA Astrophysics Data System (ADS)

Fazleev, N. G.; Maddox, W. B.; Nadesalingam, M.; Rajeshwar, K.; Weiss, A. H.

2009-03-01

Changes in the surface of an oxidized Cu(100) single crystal resulting from vacuum annealing have been investigated using positron annihilation induced Auger electron spectroscopy (PAES). PAES measurements show a large increase in the intensity of the positron annihilation induced Cu M2,3VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300° C. The intensity then decreases monotonically as the annealing temperature is increased to ˜600° C. Experimental PAES results are analyzed by performing calculations of positron surface states and annihilation probabilities of surface-trapped positrons with relevant core electrons taking into account the charge redistribution at the surface, surface reconstructions, and electron-positron correlations effects. Possible explanation for the observed behavior of the intensity of positron annihilation induced Cu M2,3VV Auger peak with changes of the annealing temperature is proposed.

Studies of oxidation of the Cu(100) surface using low energy positrons.

NASA Astrophysics Data System (ADS)

Maddox, W. B.; Fazleev, N. G.; Weiss, A. H.

2009-03-01

Changes in the surface of an oxidized Cu(100) single crystal resulting from vacuum annealing have been investigated using positron annihilation induced Auger electron spectroscopy (PAES). PAES measurements show a large increase in the intensity of the positron annihilation induced Cu M2,3VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300^o C. The intensity then decreases monotonically as the annealing temperature is increased to ˜600^o C. Experimental PAES results are analyzed by performing calculations of positron surface states and annihilation probabilities of surface-trapped positrons with relevant core electrons taking into account the charge redistribution at the surface, surface reconstructions, and electron-positron correlations effects. Possible explanation for the observed behavior of the intensity of positron annihilation induced Cu M2,3VV Auger peak with changes of the annealing temperature is proposed.

Temperature dependence of deuterium retention mechanisms in tungsten

NASA Astrophysics Data System (ADS)

Roszell, J. P.; Davis, J. W.; Haasz, A. A.

2012-10-01

The retention of 500 eV D+ was measured as a function of implantation temperature in single- (SCW) and poly-crystalline (PCW) tungsten. The results show a decrease in retention of ˜2 orders of magnitude over the temperature range of 350-550 K in SCW and a decrease of an order of magnitude over the temperature range of 600-700 K in PCW. Inspection of the TDS spectra showed a shift in peak location from 600 to 800 K as temperature was increased above 350 K in SCW and above 450 K in PCW specimens. TMAP modeling showed that the change in peak location corresponds to a change in trapping energy from 1.3 eV for the 600 K peak to 2.1 eV for the 800 K peak. It is proposed that for implantations performed above 350 K in SCW and 450 K in PCW, deuterium-containing vacancies are able to diffuse and combine to create stable nano-bubbles within the crystal lattice. The formation of nano-bubbles due to the annihilation of deuterium-vacancy complexes results in a change in the trapping energy from 1.3 to 2.1 eV as well as a decrease in retention as some of the deuterium-vacancy complexes will be destroyed at surfaces or grain boundaries, decreasing the number of trapping sites available.

Self-preservation and structural transition of gas hydrates during dissociation below the ice point: an in situ study using Raman spectroscopy

PubMed Central

Zhong, Jin-Rong; Zeng, Xin-Yang; Zhou, Feng-He; Ran, Qi-Dong; Sun, Chang-Yu; Zhong, Rui-Qin; Yang, Lan-Ying; Chen, Guang-Jin; Koh, Carolyn A.

2016-01-01

The hydrate structure type and dissociation behavior for pure methane and methane-ethane hydrates at temperatures below the ice point and atmospheric pressure were investigated using in situ Raman spectroscopic analysis. The self-preservation effect of sI methane hydrate is significant at lower temperatures (268.15 to 270.15 K), as determined by the stable C-H region Raman peaks and AL/AS value (Ratio of total peak area corresponding to occupancies of guest molecules in large cavities to small cavities) being around 3.0. However, it was reduced at higher temperatures (271.15 K and 272.15 K), as shown from the dramatic change in Raman spectra and fluctuations in AL/AS values. The self-preservation effect for methane-ethane double hydrate is observed at temperatures lower than 271.15 K. The structure transition from sI to sII occurred during the methane-ethane hydrate decomposition process, which was clearly identified by the shift in peak positions and the change in relative peak intensities at temperatures from 269.15 K to 271.15 K. Further investigation shows that the selectivity for self-preservation of methane over ethane leads to the structure transition; this kind of selectivity increases with decreasing temperature. This work provides new insight into the kinetic behavior of hydrate dissociation below the ice point. PMID:27941857

Self-preservation and structural transition of gas hydrates during dissociation below the ice point: an in situ study using Raman spectroscopy.

PubMed

Zhong, Jin-Rong; Zeng, Xin-Yang; Zhou, Feng-He; Ran, Qi-Dong; Sun, Chang-Yu; Zhong, Rui-Qin; Yang, Lan-Ying; Chen, Guang-Jin; Koh, Carolyn A

2016-12-12

The hydrate structure type and dissociation behavior for pure methane and methane-ethane hydrates at temperatures below the ice point and atmospheric pressure were investigated using in situ Raman spectroscopic analysis. The self-preservation effect of sI methane hydrate is significant at lower temperatures (268.15 to 270.15 K), as determined by the stable C-H region Raman peaks and A L /A S value (Ratio of total peak area corresponding to occupancies of guest molecules in large cavities to small cavities) being around 3.0. However, it was reduced at higher temperatures (271.15 K and 272.15 K), as shown from the dramatic change in Raman spectra and fluctuations in A L /A S values. The self-preservation effect for methane-ethane double hydrate is observed at temperatures lower than 271.15 K. The structure transition from sI to sII occurred during the methane-ethane hydrate decomposition process, which was clearly identified by the shift in peak positions and the change in relative peak intensities at temperatures from 269.15 K to 271.15 K. Further investigation shows that the selectivity for self-preservation of methane over ethane leads to the structure transition; this kind of selectivity increases with decreasing temperature. This work provides new insight into the kinetic behavior of hydrate dissociation below the ice point.

Thermal desorption of CO and H2 from degassed 304 and 347 stainless steel

NASA Technical Reports Server (NTRS)

Rezaie-Serej, S.; Outlaw, R. A.

1994-01-01

Thermal desorption spectroscopy (TDS), along with Auger electron spectroscopy, was used to study the desorption of H2 and CO from baked 304 and 347 stainless-steel samples exposed only to residual gases. Both 347 and 304 samples gave identical TDS spectra. The spectra for CO contained a sharp leading peak centered in the temperature range 410-440C and an exponentially increasing part for temperatures higher than 500C, with a small peak around 600C appearing as a shoulder. The leading peak followed a second-order desorption behavior with an activation energy of 28+/-2 kcal/mol, suggesting that the rate-limiting step for this peak is most likely a surface reaction that produces the CO molecules in the surface layer. The amount of desorbed CO corresponding to this peak was approximately 0.5X10(exp 14) molecules/cm(exp 2) . The exponentially rising part of the CO spectrum appeared to originate from a bulk diffusion process. The TDS spectrum for H2 consisted of a main peak centered also in the temperature range 410-440C, with two small peaks appearing as shoulders at approximately 500 and 650C. The main peak in this case also displayed a second-order behavior with an activation energy of 14+/-2 kcal/mol. The amount of desorbed H2, approximately 1.9X 10(exp 15) molecules/cm(exp 2) , appeared to be independent of the concentration of hydrogen in the bulk, indicating that the majority of the desorbed H2 originated from the surface layer.

Variation and seasonal patterns of suicide mortality in Finland and Sweden since the 1750s.

PubMed

Holopainen, Jari; Helama, Samuli; Björkenstam, Charlotte; Partonen, Timo

2013-11-01

Suicide mortality varies in both the short and long term. Our study examines suicide mortality in Finland and Sweden from the 1750s until today. The aim of our study is to detect any seasonal peaks in suicide rates and examine their temporal evolution to suggest a mechanism that may explain such peaks. We acquired the study material from the Finnish and Swedish cause of death statistics (257,341 deaths by suicide) and the relevant population gender structure data. We then separately calculated the annual male and female suicide rates per 100,000 inhabitants. We analysed the suicide peaks, calculating factors of proportionality for the available data by dividing the suicide rates in the peak months (May and October) by the annual suicide rates. Suicide rates in Finland and Sweden peak twice a year. Both men and women in both countries most often commit suicide in May. There is another peak in October, with the exception of Finnish men. These suicide peaks coincide with a temperature increase in May and the biggest annual drop in temperature in October. We also observed a monotonic long-term change in the Swedish statistics, but not in the Finnish data. Our hypothesis is that seasonal variation in suicide rates may be caused by abrupt temperature changes twice a year that trigger the activity in brown adipose tissue and deepen depression. While the overall suicide mortality rates varied considerably, the monthly proportions in May did not. This finding suggests a routine factor underlying the spring peak in suicide mortality.

Temperature Dependence of Low-Frequency Spectra in Molten Bis(trifluoromethylsulfonyl)amide Salts of Imidazolium Cations Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy.

PubMed

Shirota, Hideaki; Kakinuma, Shohei

2015-07-30

In this study, the temperature dependence of the low-frequency spectra of liquid bis(trifluoromethylsulfonyl)amide salts of the monocations 1-methyl-3-propylimidazolium and 1-hexyl-3-methylimidazolium and the dications 1,6-bis(3-methylimidazolium-1-yl)hexane and 1,12-bis(3-methylimidazolium-1-yl)dodecane has been investigated by means of femtosecond optical heterodyne-detected Raman-induced Kerr effect spectroscopy. The intensity in the low-frequency region below 20 cm(-1) in the spectra of the four ionic liquids increases with rising temperature. From a line-shape analysis of the broadened low-frequency spectra of the ionic liquids, it is clear that the lowest-frequency component, which peaks at approximately 5 cm(-1), contributes to the temperature dependence of the spectra. This implies that the activity of the intermolecular translational vibrational motion is increasing with rising temperature. It is also possible that decoupling in the crossover process between intermolecular vibrational motion and structural relaxation occurs as a result of a deterioration of the non-Markovian feature or the loss of memory caused by the higher temperature. The peak of the highest-frequency component, which is due mainly to the imidazolium ring libration, shifts to lower frequency with increasing temperature. This is attributed to weaker interactions of the ionic liquids at higher temperatures. Temperature-dependent viscosities from 293 to 353 K of the four ionic liquids have also been characterized.

Association of temperature and historical dynamics of malaria in the Republic of Korea, including reemergence in 1993.

PubMed

Linthicum, Kenneth J; Anyamba, Assaf; Killenbeck, Bradley; Lee, Won-Ja; Lee, Hee Choon S; Klein, Terry A; Kim, Heung-Chul; Pavlin, Julie A; Britch, Seth C; Small, Jennifer; Tucker, Compton J; Gaydos, Joel C

2014-07-01

Plasmodium vivax malaria reemerged in the Republic of Korea in 1993 after it had been declared malaria free in 1979. Malaria rapidly increased and peaked in 2000 with 4,142 cases with lower but variable numbers of cases reported through 2011. We examined the association of regional climate trends over the Korean Peninsula relative to malaria cases in U.S. military and Republic of Korea soldiers, veterans, and civilians from 1950 to 2011. Temperatures and anomaly trends in air temperature associated with satellite remotely sensed outgoing long-wave radiation were used to observe temporal changes. These changes, particularly increasing air temperatures, in combination with moderate rains throughout the malaria season, and distribution of malaria vectors, likely supported the 1993 reemergence and peaks in malaria incidence that occurred through 2011 by accelerating the rate of parasite development in mosquitoes and increased numbers as a result of an expansion of larval habitat, thereby increasing the vectorial capacity of Anopheles vectors. High malaria rates associated with a favorable climate were similarly observed during the Korean War. These findings support the need for increased investigations into malaria predictive models using climate-related variables. Reprint & Copyright © 2014 Association of Military Surgeons of the U.S.

Vibrational dynamics and boson peak in a supercooled polydisperse liquid.

PubMed

Abraham, Sneha Elizabeth; Bagchi, Biman

2010-03-01

Vibrational density of states (VDOS) in a supercooled polydisperse liquid is computed by diagonalizing the Hessian matrix evaluated at the potential energy minima for systems with different values of polydispersity. An increase in polydispersity leads to an increase in the relative population of localized high-frequency modes. At low frequencies, the density of states shows an excess compared to the Debye squared-frequency law, which has been identified with the boson peak. The height of the boson peak increases with polydispersity and shows a rather narrow sensitivity to changes in temperature. While the modes comprising the boson peak appear to be largely delocalized, there is a sharp drop in the participation ratio of the modes that exist just below the boson peak indicative of the quasilocalized nature of the low-frequency vibrations. Study of the difference spectrum at two different polydispersity reveals that the increase in the height of boson peak is due to a population shift from modes with frequencies above the maximum in the VDOS to that below the maximum, indicating an increase in the fraction of the unstable modes in the system. The latter is further supported by the facilitation of the observed dynamics by polydispersity. Since the strength of the liquid increases with polydispersity, the present result provides an evidence that the intensity of boson peak correlates positively with the strength of the liquid, as observed earlier in many experimental systems.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kraus, A.; Garner, P.; Hanan, N.

Thermal-hydraulic simulations have been performed using computational fluid dynamics (CFD) for the highly-enriched uranium (HEU) design of the IVG.1M reactor at the Institute of Atomic Energy (IAE) at the National Nuclear Center (NNC) in the Republic of Kazakhstan. Steady-state simulations were performed for both types of fuel assembly (FA), i.e. the FA in rows 1 & 2 and the FA in row 3, as well as for single pins in those FA (600 mm and 800 mm pins). Both single pin calculations and bundle sectors have been simulated for the most conservative operating conditions corresponding to the 10 MW outputmore » power, which corresponds to a pin unit cell Reynolds number of only about 7500. Simulations were performed using the commercial code STAR-CCM+ for the actual twisted pin geometry as well as a straight-pin approximation. Various Reynolds-Averaged Navier-Stokes (RANS) turbulence models gave different results, and so some validation runs with a higher-fidelity Large Eddy Simulation (LES) code were performed given the lack of experimental data. These singled out the Realizable Two-Layer k-ε as the most accurate turbulence model for estimating surface temperature. Single-pin results for the twisted case, based on the average flow rate per pin and peak pin power, were conservative for peak clad surface temperature compared to the bundle results. Also the straight-pin calculations were conservative as compared to the twisted pin simulations, as expected, but the single-pin straight case was not always conservative with regard to the straight-pin bundle. This was due to the straight-pin temperature distribution being strongly influenced by the pin orientation, particularly near the outer boundary. The straight-pin case also predicted the peak temperature to be in a different location than the twisted-pin case. This is a limitation of the straight-pin approach. The peak temperature pin was in a different location from the peak power pin in every case simulated, and occurred at an inner pin just before the enrichment change. The 600 mm case demonstrated a peak clad surface temperature of 370.4 K, while the 800 mm case had a temperature of 391.6 K. These temperatures are well below the necessary temperatures for boiling to occur at the rated pressure. Fuel temperatures are also well below the melting point. Future bundle work will include simulations of the proposed low-enriched uranium (LEU) design. Two transient scenarios were also investigated for the single-pin geometries. Both were “model” problems that were focused on pure thermal-hydraulic behavior, and as such were simple power changes that did not incorporate neutron kinetics modeling. The first scenario was a high-power, ramp increase, while the second scenario was a low-power, step increase. A cylindrical RELAP model was also constructed to investigate its accuracy as compared to the higher-fidelity CFD. Comparisons between the two codes showed good agreement for peak temperatures in the fuel and at the cladding surface for both cases. In the step transient, temperatures at four axial levels were also computed. These showed greater but reasonable discrepancy, with RELAP outputting higher temperatures. These results provide some evidence that RELAP can be used with confidence in modeling transients for IVG.« less

Temperature peaking at beginning of breakdown in 2.45 GHz pulsed off-resonance electron cyclotron resonance ion source hydrogen plasma

NASA Astrophysics Data System (ADS)

Cortázar, O. D.; Megía-Macías, A.; Vizcaíno-de-Julián, A.

2012-10-01

An experimental study of temperature and density evolution during breakdown in off-resonance ECR hydrogen plasma is presented. Under square 2.45 GHz microwave excitation pulses with a frequency of 50 Hz and relative high microwave power, unexpected transient temperature peaks that reach 18 eV during 20 μs are reported at very beginning of plasma breakdown. Decays of such peaks reach final stable temperatures of 5 eV at flat top microwave excitation pulse. Evidence of interplay between incoming power and duty cycle giving different kind of plasma parameters evolutions engaged to microwave coupling times is observed. Under relative high power conditions where short microwave coupling times are recorded, high temperature peaks are measured. However, for lower incoming powers and longer coupling times, temperature evolves gradually to a higher final temperature without peaking. On the other hand, the early instant where temperature peaks are observed also suggest a possible connection with preglow processes during breakdown in ECRIS plasmas.

Investigation of long term stability in metal hydrides

NASA Technical Reports Server (NTRS)

Marmaro, Roger W.; Lynch, Franklin E.; Chandra, Dhanesh; Lambert, Steve; Sharma, Archana

1991-01-01

It is apparent from the literature and the results of this study that cyclic degradation of AB(5) type metal hydrides varies widely according to the details of how the specimens are cycled. The Rapid Cycle Apparatus (RCA) used produced less degradation in 5000 to 10000 cycles than earlier work with a Slow Cycle Apparatus (SCA) produced in 1500 cycles. Evidence is presented that the 453 K (356 F) Thermal Aging (TA) time spent in the saturated condition causes hydride degradation. But increasing the cooling (saturation) period in the RCA did not greatly increase the rate of degradation. It appears that TA type degradation is secondary at low temperatures to another degradation mechanism. If rapid cycles are less damaging than slow cycles when the saturation time is equal, the rate of hydriding/dehydriding may be an important factor. The peak temperatures in the RCA were about 30 C lower than the SCA. The difference in peak cycle temperatures (125 C in the SCA, 95 C in RCA) cannot explain the differences in degradation. TA type degradation is similar to cyclic degradation in that nickel peaks and line broadening are observed in X ray diffraction patterns after either form of degradation.

Effects of optical design modifications on thermal performance of a highly reflective HfO2/SiO2/TiO2 three material coating

NASA Astrophysics Data System (ADS)

Ocak, M.; Sert, C.; Okutucu-Özyurt, T.

2018-02-01

Effects of layer thickness modifications on laser induced temperature distribution inside three material, highly reflective thin film coatings are studied with numerical simulations. As a base design, a 21 layer coating composed of HfO2, SiO2 and TiO2 layers of quarter wave thickness is considered. First, the laser induced temperature distribution in this base design is obtained. Then the layer thicknesses of the base design are modified and the corresponding temperature distributions in four alternative non-quarter wave coatings are evaluated. The modified thicknesses are determined using an in-house code developed to shift the electric field intensity (EFI) peak from the first high/low layer interface towards the adjacent low index layer that has a higher thermal conductivity, hence, higher laser damage resistance. Meanwhile, the induced increase in the EFI peak is kept at a user defined upper limit. The laser endurance of the base and alternative designs are compared in terms of their estimated temperature distributions. The results indicated that both the peak temperature and the highest interface temperature are decreased by at least 32%, in non-dimensional form, when alternative designs are used instead of the base design. The total reflection of the base design is only decreased from 99.8% to at most 99.4% when alternative designs are used. The study is proved to be successful in improving the laser endurance of three material thin film coatings by lowering the peak and interface temperatures.

Magnetic property in the ferromagnetic superconductor UGe2 at pressures above the ferromagnetic critical pressure

NASA Astrophysics Data System (ADS)

Tateiwa, Naoyuki; Haga, Yoshinori; Matsuda, Tatsuma D.; Yamamoto, Etsuji; Ōnuki, Yoshichika; Fisk, Zachary

2013-08-01

We have studied the high-pressure magnetic property in UGe2 where ferromagnetic superconductivity appears under high pressure. In this study, we focus on the magnetic property at pressures above the ferromagnetic critical pressure P c =1.6 GPa. The temperature and magnetic field dependences of the dc-magnetization have been measured under high pressures up to 5.1 GPa by using a ceramic anvil high pressure cell. At pressures above P c , the magnetic susceptibility x shows a broad maximum around T χmax and the magnetization at 2.0 K shows an abrupt increase (metamagnetic transition) at H c . With increasing pressure, the peak structure in x becomes broader, and the peak position T χmax moves to the higher temperature region. The metamagnetic field H c increases rapidly with increasing pressure. At pressures above 4.1 GPa, x shows a simple temperature dependence, and the magnetization increases linearly with increasing field. These phenomena in UGe2 resemble to those in the intermetallic compounds of 3 d transition metals such as Co(S1- x Se x ) and YCo2. We discuss the experimental results by using the phenomenological spin-fluctuation theory.

Some rheological properties of sodium caseinate-starch gels.

PubMed

Bertolini, Andrea C; Creamer, Lawrence K; Eppink, Mieke; Boland, Mike

2005-03-23

The influence of sodium caseinate on the thermal and rheological properties of starch gels at different concentrations and from different botanical sources was evaluated. In sodium caseinate-starch gels, for all starches with the exception of potato starch, the sodium caseinate promoted an increase in the storage modulus and in the viscosity of the composite gel when compared with starch gels. The addition of sodium caseinate resulted in an increase in the onset temperature, the gelatinization temperature, and the end temperature, and there was a significant interaction between starch and sodium caseinate for the onset temperature, the peak temperature, and the end temperature. Microscopy results suggested that sodium caseinate promoted an increase in the homogeneity in the matrix of cereal starch gels.

Thermal desorption of hydrogen from Mg2Ni hydrogen storage materials.

PubMed

Hur, Tae Hong; Han, Jeong Seb; Kim, Jin Ho; Kim, Byung Kwan

2011-07-01

In order to investigate the influence of HCS on the hydrogen occupation site of Mg2Ni alloy, the thermal desorption technique has been applied to Mg2Ni hydride made by hydriding combustion synthesis (HCS). Mg2Ni was made under low temperature in a short time by the HCS compared to conventional melting process. At various initial hydride wt% from 0.91 to 3.52, the sample was heated to 623 K at a rate of 1.0 K/min. The starting temperature of the evolution of hydrogen goes higher as the initial hydride wt% increases. Only one peak is shown in the case of the small initial hydride wt%. But two peaks appeared with increasing initial hydride wt%. The activation energies obtained by the first and second peaks are 113.0 and 99.5 kJ/mol respectively. The two site occupation model by Darriet et al. was proved. The influence of HCS on the hydrogen occupation site of Mg2Ni alloy is nonexistent.

Melting-solidification transition of Zn nanoparticles embedded in SiO2: Observation by synchrotron x-ray and ultraviolet-visible-near-infrared light

NASA Astrophysics Data System (ADS)

Amekura, H.; Tanaka, M.; Katsuya, Y.; Yoshikawa, H.; Ohnuma, M.; Matsushita, Y.; Kobayashi, K.; Kishimoto, N.

2010-11-01

Melting-solidification transition of Zn nanoparticles (NPs) with the mean diameter of 11.5 nm, embedded in silica glass, was investigated by glancing incident x-ray diffraction (GIXRD) at high temperatures using synchrotron radiation (SR). With increasing temperature, 101Zn diffraction peak gradually decreases up to ˜360 °C and then steeply decreases. This is due to the melting of Zn NPs, which completes around 420 °C. With decreasing temperature, the solidification of the NPs begins around ˜310 °C. The temperature hysteresis with a width of ˜110 °C was observed. With temperature, the diffraction angle shows a shift without hysteresis, which is ascribed to thermal expansion of Zn NP lattice. Thermal expansion coefficient of Zn NPs was determined as 24.4×10-6 K-1 along the ⟨101⟩ direction. Optical absorption spectroscopy shows a broad ultraviolet (UV) peak which was observed at even higher temperatures than the melting temperature but shifts to the low-energy side with the melting. The energy shift in the UV peak also shows the temperature hysteresis which resembles with the melting-solidification hysteresis recorded by SR-GIXRD. The melting-solidification transition is also detectable by the optical absorption spectroscopy in the UV-visible-near-infrared region.

Microwave absorption properties of flake-shaped Co particles composites at elevated temperature (293-673 K) in X band

NASA Astrophysics Data System (ADS)

Wang, Guowu; Li, Xiling; Wang, Peng; Zhang, Junming; Wang, Dian; Qiao, Liang; Wang, Tao; Li, Fashen

2018-06-01

The complex permeability and permittivity of the easy-plane anisotropic Co/polyimide composite at high temperature (293-673 K) in X band were measured. The results show that both the complex permeability and permittivity increase with the increase of temperature in the measured temperature range. The calculated absorption properties display that the intensity of the reflection loss (RL) peak first increases and then decreases with the increase of temperature, and reaches the maximum (-52 dB) at 523 K. At each temperature, the composite can achieve the RL exceeding -10 dB in the whole X band. The composite can even work stably for more than 20 min with the excellent absorption performance under 673 K. In addition, the RL performance of the composite at high temperature is better than that at room temperature.

Effect of temperature on motility and chemotaxis of Escherichia coli.

PubMed Central

Maeda, K; Imae, Y; Shioi, J I; Oosawa, F

1976-01-01

The swimming velocity of Escherichia coli at various constant temperatures was found to increase with increasing temperature. The frequency of tumbling had a peak at 34 degrees C and was very low both at 20 and at 39 degrees C. The swimming tracks near the surface of a slide glass showed curves, and the curvature increased the temperature. When the temperature of a bacterial suspension was suddenly changed, a transient change of the tumbling frequency was observed. A temperature drop induced a temporary increase in the tumbling frequency, and a quick rise of temperature, on the other hand, resulted in a temporary suppression of the tumbling. These dynamic responses to sudden changes of temperature was not observed in the smoothly swimming nonchemotactic strains bearing the mutations cheA and cheC and also in a mutant with the metF mutation under a smooth swimming condition. Images PMID:783127

Investigations on the carbon contaminations on the alkali cells of DPAL with hydrocarbon buffer gas

NASA Astrophysics Data System (ADS)

Li, Zhiyong; Tan, Rongqing; Wang, Yujie; Ye, Qing; Bian, Jintian; Huang, Wei; Li, Hui; Han, Gaoce

2017-10-01

Diode pumped alkali laser (DPAL) with hydrocarbon buffer gases has the features of low threshold and high efficiency. The chemical reaction between alkali and hydrocarbon gases affects the life time of DPAL. In this paper, a method based on Fourier transform infrared spectroscopy and Lambert-Beer law is adopted to find a safe temperature at which DPAL runs for a long term. A theoretical model is established to figure out ways to reduce the peak temperature in the cell window. The results indicates that 170 °C is a safe temperature. Although the absorbance of the cell window to the pump light and alkali laser is lower, there is temperature increase. Small light-transmitting area and air blowing on the windows can reduce the peak temperature effectively. Cooling the cell window is essential and critical in a long-term running DPAL.

Synthesis and characterization of intercalated few-layer graphenes

NASA Astrophysics Data System (ADS)

Sato, Shogo; Ichikawa, Hiroaki; Iwata, Nobuyuki; Yamamoto, Hiroshi

2014-02-01

Toward achieving room-temperature superconductivity, FeCl3-intercalated few-layer graphenes (FeCl3-FLGs) and Ca-intercalated few-layer graphenes (Ca-FLGs) were synthesized. FeCl3-FLGs were synthesized by the two-zone method and Ca-FLGs were synthesized using Ca-Li alloy. The Raman spectra of the FeCl3-FLGs showed a lower-intensity peak at 1607 cm-1 than that of the corresponding bare G. The peak at 1607 cm-1 suggested that the sample was stage 4-5 FeCl3-FLGs. The room-temperature electrical resistivity of FeCl3-FLGs was 2.65 × 10-5 Ω·m, which linearly decreased with decreasing temperature with a marked change occurring at approximately 200 K. From a XRD pattern of Ca-FLGs, we concluded that Ca is intercalated in FLGs. The room-temperature resistivity of Ca-FLGs was 3.45 × 10-5 Ω·m, which increased with decreasing temperature.

ZT Optimization: An Application Focus

PubMed Central

Tuley, Richard; Simpson, Kevin

2017-01-01

Significant research has been performed on the challenge of improving thermoelectric materials, with maximum peak figure of merit, ZT, the most common target. We use an approximate thermoelectric material model, matched to real materials, to demonstrate that when an application is known, average ZT is a significantly better optimization target. We quantify this difference with some examples, with one scenario showing that changing the doping to increase peak ZT by 19% can lead to a performance drop of 16%. The importance of average ZT means that the temperature at which the ZT peak occurs should be given similar weight to the value of the peak. An ideal material for an application operates across the maximum peak ZT, otherwise maximum performance occurs when the peak value is reduced in order to improve the peak position. PMID:28772668

Photoluminescence nonuniformity from self-seeding nuclei in CVD-grown monolayer MoSe2.

PubMed

Tian, Xiangling; Wei, Rongfei; Liu, Shanshan; Zhang, Yeming; Qiu, Jianrong

2018-01-03

We present optical spectroscopy (photoluminescence and Raman spectrum) studies of monolayer transition metal dichalcogenide MoSe 2 , with spatial location, temperature and excitation power dependence. The investigated spectra show location-dependent behavior with an increase in photoluminescence and Raman intensity and a blue-shift in photoluminescence peak position in the inner region. The observed behaviors of a large shift in the photoluminescence peak position at the edge and biexciton emissions in the inner region confirm that the monolayer MoSe 2 crystals grow from nucleation centers during the CVD process. Temperature activated energy and dependence of the peak position are attributed to residual oxygen during the growth. Investigating this information provides a basis for precisely controlling the synthesis of TMDCs and their application in advanced optoelectronics.

Cold temperature increases winter fruit removal rate of a bird-dispersed shrub

Treesearch

Charles Kwit; Douglas J. Levey; Cathryn H. Greenberg; Scott F. Pearson; John P. McCarty; Sarah Sargent

2004-01-01

We tested the hypothesis that winter removal rates of fruits of wax myrtle, Myrica cerifera, are higher in colder winters. Over a 9-year period, we monitored M. cerifera fruit crops in 13 0.1-ha study plots in South Carolina, U.S.A. Peak ripeness occurred in November, whereas peak removal occurred in the coldest months, December...

Global mean sea-level rise in a world agreed upon in Paris

NASA Astrophysics Data System (ADS)

Bittermann, Klaus; Rahmstorf, Stefan; Kopp, Robert E.; Kemp, Andrew C.

2017-12-01

Although the 2015 Paris Agreement seeks to hold global average temperature to ‘well below 2 °C above pre-industrial levels and to pursue efforts to limit the temperature increase to 1.5 °C above pre-industrial levels’, projections of global mean sea-level (GMSL) rise commonly focus on scenarios in which there is a high probability that warming exceeds 1.5 °C. Using a semi-empirical model, we project GMSL changes between now and 2150 CE under a suite of temperature scenarios that satisfy the Paris Agreement temperature targets. The projected magnitude and rate of GMSL rise varies among these low emissions scenarios. Stabilizing temperature at 1.5 °C instead of 2 °C above preindustrial reduces GMSL in 2150 CE by 17 cm (90% credible interval: 14-21 cm) and reduces peak rates of rise by 1.9 mm yr-1 (90% credible interval: 1.4-2.6 mm yr-1). Delaying the year of peak temperature has little long-term influence on GMSL, but does reduce the maximum rate of rise. Stabilizing at 2 °C in 2080 CE rather than 2030 CE reduces the peak rate by 2.7 mm yr-1 (90% credible interval: 2.0-4.0 mm yr-1).

Resistant Starch Contents of Native and Heat-Moisture Treated Jackfruit Seed Starch

PubMed Central

Kittipongpatana, Ornanong S.

2015-01-01

Native jackfruit seed starch (JFS) contains 30% w/w type II resistant starch (RS2) and can potentially be developed as a new commercial source of RS for food and pharmaceutical application. Heat-moisture treatment (HMT) was explored as a mean to increase RS content of native JFS. The effect of the conditions was tested at varied moisture contents (MC), temperatures, and times. Moisture levels of 20–25%, together with temperatures 80–110°C, generally resulted in increases of RS amount. The highest amount of RS (52.2%) was achieved under treatment conditions of 25% MC and 80°C, for 16 h (JF-25-80-16). FT-IR peak ratio at 1047/1022 cm−1 suggested increases in ordered structure in several HMT-JFS samples with increased RS. SEM showed no significant change in the granule appearance, except at high moisture/temperature treatment. XRD revealed no significant change in peaks intensities, suggesting the crystallinity within the granule was mostly retained. DSC showed increases in T g and, in most cases, ΔT, as the MC was increased in the samples. Slight but significant decreases in ΔH were observed in samples with low RS, indicating that a combination of high moisture and temperature might cause partial gelatinization. HMT-JFS with higher RS exhibited less swelling, while the solubility remained mostly unchanged. PMID:25642454

Anaerobic digestion of solid slaughterhouse waste: study of biological stabilization by Fourier Transform infrared spectroscopy and thermogravimetry combined with mass spectrometry.

PubMed

Cuetos, María José; Gómez, Xiomar; Otero, Marta; Morán, Antonio

2010-07-01

In this paper, Fourier Transform infrared spectroscopy (FTIR) along with thermogravimetric analysis together with mass spectrometry (TG-MS analysis) were employed to study the organic matter transformation attained under anaerobic digestion of slaughterhouse waste and to establish the stability of the digestates obtained when compared with fresh wastes. Digestate samples studied were obtained from successful digestion and failed systems treating slaughterhouse waste and the organic fraction of municipal solid wastes. The FTIR spectra and TG profiles from well stabilized products (from successful digestion systems) showed an increase in the aromaticity degree and the reduction of volatile content and aliphatic structures as stabilization proceeded. On the other hand, the FTIR spectra of non-stable reactors showed a high aliphaticity degree and fat content. When comparing differential thermogravimetry (DTG) profiles of the feed and digestate samples obtained from all successful anaerobic systems, a reduction in the intensity of the low-temperature range (approximately 300 degrees C) peak was observed, while the weight loss experienced at high-temperature (450-550 degrees C) was variable for the different systems. Compared to the original waste, the intensity of the weight loss peak in the high-temperature range decreased in the reactors with higher hydraulic retention time (HRT) whereas its intensity increased and the peak was displaced to higher temperatures for the digesters with lower HRT.

Circulation and metabolic rates in a natural hibernator: an integrative physiological model

PubMed Central

Nelson, Bethany T.; Andrews, Matthew T.

2010-01-01

Small hibernating mammals show regular oscillations in their heart rate and body temperature throughout the winter. Long periods of torpor are abruptly interrupted by arousals with heart rates that rapidly increase from 5 beats/min to over 400 beats/min and body temperatures that increase by ∼30°C only to drop back into the hypothermic torpid state within hours. Surgically implanted transmitters were used to obtain high-resolution electrocardiogram and body temperature data from hibernating thirteen-lined ground squirrels (Spermophilus tridecemlineatus). These data were used to construct a model of the circulatory system to gain greater understanding of these rapid and extreme changes in physiology. Our model provides estimates of metabolic rates during the torpor-arousal cycles in different model compartments that would be difficult to measure directly. In the compartment that models the more metabolically active tissues and organs (heart, brain, liver, and brown adipose tissue) the peak metabolic rate occurs at a core body temperature of 19°C approximately midway through an arousal. The peak metabolic rate of the active tissues is nine times the normothermic rate after the arousal is complete. For the overall metabolic rate in all tissues, the peak-to-resting ratio is five. This value is high for a rodent, which provides evidence for the hypothesis that the arousal from torpor is limited by the capabilities of the cardiovascular system. PMID:20844258

Effects of temperature on the specific dynamic action of the southern catfish, Silurus meridionalis.

PubMed

Luo, Yiping; Xie, Xiaojun

2008-02-01

Specific dynamic action (SDA), the energy expended on all physiological processes that is associated with meal digestion and assimilation, is strongly affected by temperature. We assessed the effects of temperature on the postprandial metabolic response and calculated SDA of the southern catfish, Silurus meridionalis. The fish was fed with experimental diets at a meal size of 4% body mass, and by using an 8-chamber, continuous-flow respirometer the oxygen consumption rate was determined at a 2 h interval until the postprandial oxygen consumption rate returning to the preprandial level, at four different temperatures. The energy expended on SDA (SDA(E)) were 2.71, 3.07, 3.16, and 3.62 kJ, the SDA(coefficients) (energy expended on SDA quantified as a percentage of the digestible energy content of the meal) were 7.70, 9.44, 10.36, and 11.12%, and the peak metabolic rates (R(peak)) of SDA were 3.48, 4.31, 5.96, and 7.30 mg O2 h(-1), at 17.5, 22.5, 27.5, and 32.5 degrees C respectively. The relationships between those parameters and temperature were: SDA(E)=1.74+0.0559T (n=26, r(2)=0.676), SDA(coefficient)=4.10+0.223T (n=26, r(2)=0.726), and R(peak)=-1.34+0.264T (n=26, r(2)=0.896). The SDA durations showed a slow-fast-slow tendency of decrease with increasing temperature, and were 88.00, 85.71, 67.71, and 66.50 h at 17.5, 22.5, 27.5 and 32.5 degrees C respectively. Two separate peaks appeared during the SDA response at 17.5 degrees C, and it might be due to a rapid startup of the mechanical process with a lag of the biochemical process, which suggested that the peaks of "mechanical component" and "biochemical component" of SDA might be separated when temperature was low enough.

Thermal effects on shearing resistance of fractures in Tak granite

NASA Astrophysics Data System (ADS)

Khamrat, S.; Thongprapha, T.; Fuenkajorn, K.

2018-06-01

Triaxial shear tests have been performed on tension-induced fractures and smooth saw-cut surfaces in Tak granite under temperatures up to 773 K. The objective is to gain an understanding of the movement of shallow faults that cause seismic activities in the Tak batholith in the north of Thailand. The results indicate that the peak and residual shear strengths and fracture dilations notably decrease as the temperatures increase. The thermal effect is enhanced under higher confining pressures. The areas of the sheared-off asperities increase with temperature and confining pressure. A power equation can describe the increase of shear strengths with normal stress where the normal stress exponent is a linear function of the temperature. The strain energy principle is applied to incorporate the principal stresses and strains into a strength criterion. A linear relation between the distortional strain energy (Wd) and the mean strain energy (Wm) of the fractures is obtained. The Wd-Wm slope depends on the fracture roughness and strength of the asperities, which can be defined as a function of shear and mean strains and dilation of the fractures. This may allow predicting the peak strength of the shallow faults in the Tak batholith.

Internal Friction of Austenitic Fe-Mn-C-Al Alloys

NASA Astrophysics Data System (ADS)

Lee, Young-Kook; Jeong, Sohee; Kang, Jee-Hyun; Lee, Sang-Min

2017-12-01

The internal friction (IF) spectra of Fe-Mn-C-Al alloys with a face-centered-cubic (fcc) austenitic phase were measured at a wide range of temperature and frequency ( f) to understand the mechanisms of anelastic relaxations occurring particularly in Fe-Mn-C twinning-induced plasticity steels. Four IF peaks were observed at 346 K (73 °C) (P1), 389 K (116 °C) (P2), 511 K (238 °C) (P3), and 634 K (361 °C) (P4) when f was 0.1 Hz. However, when f increased to 100 Hz, whereas P1, P2, and P4 disappeared, only P3 remained without the change in peak height, but with the increased peak temperature. P3 matches well with the IF peak of Fe-high Mn-C alloys reported in the literature. The effects of chemical composition and vacancy (v) on the four IF peaks were also investigated using various alloys with different concentrations of C, Mn, Al, and vacancy. As a result, the defect pair responsible for each IF peak was found as follows: a v-v pair for P1, a C-v pair for P2, a C-C pair for P3, and a C-C-v complex (major effect) + a Mn-C pair (minor effect) for P4. These results showed that the IF peaks of Fe-Mn-C-Al alloys reported previously were caused by the reorientation of C in C-C pairs, not by the reorientation of C in Mn-C pairs.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mevada, A. D., E-mail: adwait.mevada@gmail.com; Mehsana Urban Institute of Sciences, Ganpat University, Mehsana-Gozaria Highway, Kherva 384 001, Gujarat; Pandya, N. Y., E-mail: nirav-physics85@yahoo.com

Mg{sub 70}Zn{sub 30} is simplest of metallic glasses having good mechanical properties, biocompatibility with human body and is biodegradable, so it is widely studied material in its class. We present in this paper first principle calculations showing the change in the structure of the system with temperature. The computations are performed using PWSCF tool of Quantum ESPRESSO package, which uses density functional theory for calculations of electronic ground state properties and dynamical structures. With increasing temperature the number of peaks in RDFs reduce in number leaving only a single peak,the system thus makes a transition from non-crystalline solid to liquidmore » state within the range of 300–1000K. First coordination number was found to decrease with rising temperature.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Osti, Naresh C.; Naguib, Michael; Tyagi, Madhusudan

Two-dimensional transition metal carbides and nitrides (MXenes) are one of the largest and fastest growing families of materials. The presence of molecular hydrogen at ambient conditions in a MXene (Ti 3C 2T x, where T x represents a surface terminating species, including O, OH, and F) material is revealed here by inelastic and elastic neutron scatterings. The inelastic neutron-scattering spectrum measured at 5 K shows a peak at 14.6 meV, presenting a clear indication of the presence of parahydrogen in the MXene synthesized using 48% hydrofluoric acid and annealed at 110°C in vacuum prior to the measurement. An increase inmore » the measurement temperature gradually reduces the peak intensity and increases the peak width due to the mobility of the molecular hydrogen in confinement. The presence of molecular hydrogen is confirmed further from the observed elastic intensity drop in a fixed energy-window scan of elastic intensity measurements in the temperature range of 10–35 K. Using milder etching conditions, ion intercalation, or an increase in the annealing temperature all result in the absence of the trapped hydrogen molecules in MXene. Here, the results of this paper can guide the development of MXene materials with desired properties and improve our understanding of the behavior of MXenes in applications ranging from supercapacitors to hydrogen evolution reaction catalysis and hydrogen storage.« less

Evidence of molecular hydrogen trapped in two-dimensional layered titanium carbide-based MXene

DOE PAGES

Osti, Naresh C.; Naguib, Michael; Tyagi, Madhusudan; ...

2017-07-17

Two-dimensional transition metal carbides and nitrides (MXenes) are one of the largest and fastest growing families of materials. The presence of molecular hydrogen at ambient conditions in a MXene (Ti 3C 2T x, where T x represents a surface terminating species, including O, OH, and F) material is revealed here by inelastic and elastic neutron scatterings. The inelastic neutron-scattering spectrum measured at 5 K shows a peak at 14.6 meV, presenting a clear indication of the presence of parahydrogen in the MXene synthesized using 48% hydrofluoric acid and annealed at 110°C in vacuum prior to the measurement. An increase inmore » the measurement temperature gradually reduces the peak intensity and increases the peak width due to the mobility of the molecular hydrogen in confinement. The presence of molecular hydrogen is confirmed further from the observed elastic intensity drop in a fixed energy-window scan of elastic intensity measurements in the temperature range of 10–35 K. Using milder etching conditions, ion intercalation, or an increase in the annealing temperature all result in the absence of the trapped hydrogen molecules in MXene. Here, the results of this paper can guide the development of MXene materials with desired properties and improve our understanding of the behavior of MXenes in applications ranging from supercapacitors to hydrogen evolution reaction catalysis and hydrogen storage.« less

Redshift and blueshift of GaNAs/GaAs multiple quantum wells induced by rapid thermal annealing

NASA Astrophysics Data System (ADS)

Sun, Yijun; Cheng, Zhiyuan; Zhou, Qiang; Sun, Ying; Sun, Jiabao; Liu, Yanhua; Wang, Meifang; Cao, Zhen; Ye, Zhi; Xu, Mingsheng; Ding, Yong; Chen, Peng; Heuken, Michael; Egawa, Takashi

2018-02-01

The effects of rapid thermal annealing (RTA) on the optical properties of GaNAs/GaAs multiple quantum wells (MQWs) grown by chemical beam epitaxy (CBE) are studied by photoluminescence (PL) at 77 K. The results show that the optical quality of the MQWs improves significantly after RTA. With increasing RTA temperature, PL peak energy of the MQWs redshifts below 1023 K, while it blueshifts above 1023 K. Two competitive processes which occur simultaneously during RTA result in redshift at low temperature and blueshift at high temperature. It is also found that PL peak energy shift can be explained neither by nitrogen diffusion out of quantum wells nor by nitrogen reorganization inside quantum wells. PL peak energy shift can be quantitatively explained by a modified recombination coupling model in which redshift nonradiative recombination and blueshift nonradiative recombination coexist. The results obtained have significant implication on the growth and RTA of GaNAs material for high performance optoelectronic device application.

Water-Quality Data from Upper Klamath and Agency Lakes, Oregon, 2007-08

USGS Publications Warehouse

Kannarr, Kristofor E.; Tanner, Dwight Q.; Lindenberg, Mary K.; Wood, Tamara M.

2010-01-01

Significant Findings The U.S. Geological Survey Upper Klamath Lake water-quality monitoring program collected data from multiparameter continuous water-quality monitors, weekly water-quality samples, and meteorological stations during May-November 2007 and 2008. The results of these measurements and sample analyses are presented in this report for 29 stations on Upper Klamath Lake and 2 stations on Agency Lake, as well as quality-assurance data for the water-quality samples. Some of the significant findings from 2007 and 2008 are listed below. In 2007-08, ammonia concentrations were at or near the detection limit at all stations during the second week in June, after which they began to increase, with peak concentrations occurring from July through November. The concentration of un-ionized ammonia, which can be toxic to aquatic life, first began to increase in mid-June and peaked in July or August at most sites. Concentrations of un-ionized ammonia measured in the Upper Klamath Lake in 2007-08 did not reach concentrations that would have been potentially lethal to suckers. Samples collected for the analysis of dissolved organic carbon (DOC) late in the 2007 season showed no evidence of an increase in DOC subsequent to the breaching of the Williamson River Delta levees on October 30. In 2007-08, the lakewide daily median of dissolved oxygen concentration began to increase in early June, and peaked in mid- to late June. The lakewide daily median pH began to increase from early June and peaked in late June (2007) or early July (2008). Lakewide daily median pH slowly decreased during the rest of both seasons. The 2007 lakewide daily median specific conductance values first peaked on July 1, coincident with a peak in dissolved oxygen concentration and pH, followed by a decrease through mid-July. Specific conductance then remained relatively stable until mid-October when a sharp increase began that continued until the end of the season. Lakewide specific conductance values for 2008 steadily increased through the season to a maximum in late September. Lakewide daily median temperatures in both years began to increase during the beginning of June and peaked in July. These temperatures persisted until late August to early September when a gradual decrease occurred. In 2007-08, water-quality conditions monitored at the Agency Lake northern and southern stations were similar to those in Klamath Lake.

Drivers of Daily Routines in an Ectothermic Marine Predator: Hunt Warm, Rest Warmer?

PubMed Central

Papastamatiou, Yannis P.; Watanabe, Yuuki Y.; Bradley, Darcy; Dee, Laura E.; Weng, Kevin; Lowe, Christopher G.; Caselle, Jennifer E.

2015-01-01

Animal daily routines represent a compromise between maximizing foraging success and optimizing physiological performance, while minimizing the risk of predation. For ectothermic predators, ambient temperature may also influence daily routines through its effects on physiological performance. Temperatures can fluctuate significantly over the diel cycle and ectotherms may synchronize behaviour to match thermal regimes in order to optimize fitness. We used bio-logging to quantify activity and body temperature of blacktip reef sharks (Carcharhinus melanopterus) at a tropical atoll. Behavioural observations were used to concurrently measure bite rates in herbivorous reef fishes, as an index of activity for potential diurnal prey. Sharks showed early evening peaks in activity, particularly during ebbing high tides, while body temperatures peaked several hours prior to the period of maximal activity. Herbivores also displayed peaks in activity several hours earlier than the peaks in shark activity. Sharks appeared to be least active while their body temperatures were highest and most active while temperatures were cooling, although we hypothesize that due to thermal inertia they were still warmer than their smaller prey during this period. Sharks may be most active during early evening periods as they have a sensory advantage under low light conditions and/or a thermal advantage over cooler prey. Sharks swam into shallow water during daytime low tide periods potentially to warm up and increase rates of digestion before the nocturnal activity period, which may be a strategy to maximize ingestion rates. “Hunt warm, rest warmer” may help explain the early evening activity seen in other ectothermic predators. PMID:26061229

Deconvolution of the relaxations associated with local and segmental motions in poly(methacrylate)s containing dichlorinated benzyl moieties in the ester residue.

PubMed

Dominguez-Espinosa, Gustavo; Díaz-Calleja, Ricardo; Riande, Evaristo; Gargallo, Ligia; Radic, Deodato

2005-09-15

The relaxation behavior of poly(2,3-dichlorobenzyl methacrylate) is studied by broadband dielectric spectroscopy in the frequency range of 10(-1)-10(9) Hz and temperature interval of 303-423 K. The isotherms representing the dielectric loss of the glassy polymer in the frequency domain present a single absorption, called beta process. At temperatures close to Tg, the dynamical alpha relaxation already overlaps with the beta process, the degree of overlapping increasing with temperature. The deconvolution of the alpha and beta relaxations is facilitated using the retardation spectra calculated from the isotherms utilizing linear programming regularization parameter techniques. The temperature dependence of the beta relaxation presents a crossover associated with a change in activation energy of the local processes. The distance between the alpha and beta peaks, expressed as log(fmax;beta/fmax;alpha) where fmax is the frequency at the peak maximum, follows Arrhenius behavior in the temperature range of 310-384 K. Above 384 K, the distance between the peaks remains nearly constant and, as a result, the a onset temperature exhibited for many polymers is not reached in this system. The fraction of relaxation carried out through the alpha process, without beta assistance, is larger than 60% in the temperature range of 310-384 K where the so-called Williams ansatz holds.

Infrared study of OH(-) defects in KTiOPO4 crystals

NASA Astrophysics Data System (ADS)

Morris, P. A.; Crawford, M. K.; Jones, B.

1992-12-01

Variations in the concentrations and distributions of the OH(-) defects present in flux and hydrothermal KTiOPO4 (KTP) crystals, measured by infrared spectroscopy of single crystals, are attributed to differences in the growth environments and other nonhydrogenic defects present in the crystals. The concentrations of OH(-) have been estimated from the infrared data to be approximately 400 ppma (parts per million atomic) (3.0 x 10 exp 19/cu cm) in the flux crystals, 1100-1500 ppma (0.74-1.1 x 10 exp 20/cu cm) in the high-temperature hydrothermal and 600 ppma (4.3 x 10 exp 19/cu cm) in the low-temperature hydrothermal crystals. A 3566/cm peak and a 3575/cm band are observed in all crystals. The integrated intensity of the OH(-) absorption band at 3566/cm increases at the expense of the 3575/cm band at higher temperatures in the high-temperature hydrothermal crystals. Several OH(-) peaks (3490, 3455, 3428, 3420, and 3333/cm), which have strongly temperature-dependent linewidths, are present in the hydrothermally grown KTP crystals. The temperature dependencies of their peak frequencies and widths are consistent with the presence of mobile protons in the lattice. The protons located in the 3490 and 3428/cm sites are believed to contribute to the ionic conductivity of the high-conductivity high-temperature hydrothermal crystals.

Role of DNA protection and repair in resistance of Bacillus subtilis spores to ultrahigh shock pressures simulating hypervelocity impacts.

PubMed

Moeller, Ralf; Horneck, Gerda; Rabbow, Elke; Reitz, Günther; Meyer, Cornelia; Hornemann, Ulrich; Stöffler, Dieter

2008-11-01

Impact-induced ejections of rocks from planetary surfaces are frequent events in the early history of the terrestrial planets and have been considered as a possible first step in the potential interplanetary transfer of microorganisms. Spores of Bacillus subtilis were used as a model system to study the effects of a simulated impact-caused ejection on rock-colonizing microorganisms using a high-explosive plane wave setup. Embedded in different types of rock material, spores were subjected to extremely high shock pressures (5 to 50 GPa) lasting for fractions of microseconds to seconds. Nearly exponential pressure response curves were obtained for spore survival and linear dependency for the induction of sporulation-defective mutants. Spores of strains defective in major small, acid-soluble spore proteins (SASP) (alpha/beta-type SASP) that largely protect the spore DNA and spores of strains deficient in nonhomologous-end-joining DNA repair were significantly more sensitive to the applied shock pressure than were wild-type spores. These results indicate that DNA may be the sensitive target of spores exposed to ultrahigh shock pressures. To assess the nature of the critical physical parameter responsible for spore inactivation by ultrahigh shock pressures, the resulting peak temperature was varied by lowering the preshock temperature, changing the rock composition and porosity, or increasing the water content of the samples. Increased peak temperatures led to increased spore inactivation and reduced mutation rates. The data suggested that besides the potential mechanical stress exerted by the shock pressure, the accompanying high peak temperatures were a critical stress parameter that spores had to cope with.

Structural Changes in PEO-PPO-PEO Gels Induced by Methylparaben and Dexamethasone Observed Using Time-Resolved SAXS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meznarich, Norman A.K.; Juggernauth, K Anne; Batzli, Kiersten M

2011-11-17

Aqueous solutions of polyoxyethylene-polyoxypropylene-polyoxyethylene (PEO-PPO-PEO) triblock copolymers (commercially available as Pluronic surfactants) micellize and structurally arrange into cubic quasicrystalline lattices as their temperature is raised. This structural evolution is seen macroscopically as a gelation, and the presence of these ordered phases can be controlled through both polymer concentration and temperature. The presence of added solutes within the dispersions can also affect the onset and kinetics of structure formation. Here we investigate the structures formed in Pluronic F127 solutions ranging from 20 to 30% with two pharmaceutical additives [methylparaben (MP) and dexamethasone (DX)] using small-angle X-ray scattering (SAXS). We observe bothmore » the progressive evolution and breakdown of these structures as the temperature is increased from 0 to 80 °C. Additionally, we conducted time-resolved SAXS measurements to elucidate the kinetics of the structural evolution. On the basis of the evolution of scattering peaks as the samples were being heated, we suggest that added MP changes the nucleation behavior of fcc phases within the sample from a heterogeneous process to a more homogeneous distribution of nucleated species. MP and DX also stabilize the micelle lattices, allowing them to persevere at higher temperatures. We observed the unusual result that the presence of DX caused the primary peaks of the structure factor to be suppressed, while preserving the higher order peaks. The primary peaks reappeared at the highest temperatures tested.« less

Local strain-induced band gap fluctuations and exciton localization in aged WS2 monolayers

NASA Astrophysics Data System (ADS)

Krustok, J.; Kaupmees, R.; Jaaniso, R.; Kiisk, V.; Sildos, I.; Li, B.; Gong, Y.

2017-06-01

Optical properties of aged WS2 monolayers grown by CVD method on Si/SiO2 substrates are studied using temperature dependent photoluminescence and reflectance contrast spectroscopy. Aged WS2 monolayers have a typical surface roughness about 0.5 nm and, in addition, a high density of nanoparticles (nanocaps) with the base diameter about 30 nm and average height of 7 nm. The A-exciton of aged monolayer has a peak position at 1.951 eV while in as-grown monolayer the peak is at about 24 meV higher energy at room temperature. This red-shift is explained using local tensile strain concept, where strain value of 2.1% was calculated for these nanocap regions. Strained nanocaps have lower band gap energy and excitons will funnel into these regions. At T=10K a double exciton and trion peaks were revealed. The separation between double peaks is about 20 meV and the origin of higher energy peaks is related to the optical band gap energy fluctuations caused by random distribution of local tensile strain due to increased surface roughness. In addition, a wide defect related exciton band XD was found at about 1.93 eV in all aged monolayers. It is shown that the theory of localized excitons describes well the temperature dependence of peak position and halfwidth of the A-exciton band. The possible origin of nanocaps is also discussed.

Mysteries of LiF TLD response following high ionisation density irradiation: nanodosimetry and track structure theory, dose response and glow curve shapes.

PubMed

Horowitz, Y; Fuks, E; Datz, H; Oster, L; Livingstone, J; Rosenfeld, A

2011-06-01

Three outstanding effects of ionisation density on the thermoluminescence (TL) mechanisms giving rise to the glow peaks of LiF:Mg,Ti (TLD-100) are currently under investigation: (1) the dependence of the heavy charged particle (HCP) relative efficiency with increasing ionisation density and the effectiveness of its modelling by track structure theory (TST), (2) the behaviour of the TL efficiency, f(D), as a function of photon energy and dose. These studies are intended to promote the development of a firm theoretical basis for the evaluation of relative TL efficiencies to assist in their application in mixed radiation fields. And (3) the shape of composite peak 5 in the glow curve for various HCP types and energies and following high-dose electron irradiation, i.e. the ratio of the intensity of peak 5a to peak 5. Peak 5a is a low-temperature satellite of peak 5 arising from electron-hole capture in a spatially correlated trapping centre/luminescent centre (TC/LC) complex that has been suggested to possess a potential as a solid-state nanodosemeter due to the preferential electron/hole population of the TC/LC at high ionisation density. It is concluded that (1) the predictions of TST are very strongly dependent on the choice of photon energy used in the determination of f(D); (2) modified TST employing calculated values of f(D) at 2 keV is in agreement with 5-MeV alpha particle experimental results for composite peak 5 but underestimates the 1.5-MeV proton relative efficiencies. Both the proton and alpha particle relative TL efficiencies of the high-temperature TL (HTTL) peaks 7 and 8 are underestimated by an order of magnitude suggesting that the HTTL efficiencies are affected by other factors in addition to radial electron dose; (3) the dose-response supralinearity of peaks 7 and 8 change rapidly with photon energy: this behaviour is explained in the framework of the unified interaction model as due to a very strong dependence on photon energy of the relative intensity of localised recombination and (4) the increased width and decrease in T(max) of composite peak 5 as a function of ionisation density is due to the greater relative intensity of peak 5a (a low-temperature component of peak 5 arising from two-energy transfer events, which leads to localised recombination).

Mysteries of LiF TLD response following high ionisation density irradiation: nanodosimetry and track structure theory, dose response and glow curve shapes

PubMed Central

Horowitz, Y.; Fuks, E.; Datz, H.; Oster, L.; Livingstone, J.; Rosenfeld, A.

2011-01-01

Three outstanding effects of ionisation density on the thermoluminescence (TL) mechanisms giving rise to the glow peaks of LiF:Mg,Ti (TLD-100) are currently under investigation: (1) the dependence of the heavy charged particle (HCP) relative efficiency with increasing ionisation density and the effectiveness of its modelling by track structure theory (TST), (2) the behaviour of the TL efficiency, f(D), as a function of photon energy and dose. These studies are intended to promote the development of a firm theoretical basis for the evaluation of relative TL efficiencies to assist in their application in mixed radiation fields. And (3) the shape of composite peak 5 in the glow curve for various HCP types and energies and following high-dose electron irradiation, i.e. the ratio of the intensity of peak 5a to peak 5. Peak 5a is a low-temperature satellite of peak 5 arising from electron-hole capture in a spatially correlated trapping centre/luminescent centre (TC/LC) complex that has been suggested to possess a potential as a solid-state nanodosemeter due to the preferential electron/hole population of the TC/LC at high ionisation density. It is concluded that (1) the predictions of TST are very strongly dependent on the choice of photon energy used in the determination of f(D); (2) modified TST employing calculated values of f(D) at 2 keV is in agreement with 5-MeV alpha particle experimental results for composite peak 5 but underestimates the 1.5-MeV proton relative efficiencies. Both the proton and alpha particle relative TL efficiencies of the high-temperature TL (HTTL) peaks 7 and 8 are underestimated by an order of magnitude suggesting that the HTTL efficiencies are affected by other factors in addition to radial electron dose; (3) the dose–response supralinearity of peaks 7 and 8 change rapidly with photon energy: this behaviour is explained in the framework of the unified interaction model as due to a very strong dependence on photon energy of the relative intensity of localised recombination and (4) the increased width and decrease in Tmax of composite peak 5 as a function of ionisation density is due to the greater relative intensity of peak 5a (a low-temperature component of peak 5 arising from two-energy transfer events, which leads to localised recombination). PMID:21106636

The effects of γ-ray on charging behaviour using polyimide

NASA Astrophysics Data System (ADS)

Qin, Sichen; Tu, Youping; Tan, Tian; Wang, Shaohe; Yuan, Zhikang; Wang, Cong; Li, Laifeng; Wu, Zhixiong

2018-06-01

Insulation material is a key component of electrical equipment in satellites; its electrical properties determine the reliability and lifetime of the whole satellite. High-energy radioactive rays in space affect the molecular structure of the polymeric insulating materials. Under the action of plasma, high energy particles, along with the magnetic fields experienced in orbits, electric charges get injected into and trapped by the insulating material creating distortions in the electric field and even electrostatic discharges. Polyimides have been widely used for insulation in spacecraft. Choosing Co-60 gamma ray with irradiation doses of 1 MGy and 5 MGy to simulate the radiation environment of space, we investigated the effect of radiation on charging behaviour. The thermal stimulated current (TSC) from a high electric field over a wide range of temperatures was measured from which the activation energy was calculated. These results for the two sources show that the percentage increase in total charge was 133.3% and 119.4%. The γ, β 3, and α charge peaks of specimens after an irradiation dose of 1 MGy rose. In comparison, the β 2 peak of the 5 MGy-dosed specimens was enhanced. Also, there is almost no change in the γ, β 3, and α peaks. To understand the mechanism behind the TSC changes, the resulting physicochemical characteristics of an irradiated specimen were observed employing various analyses of chemical characteristics (x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray diffraction). Compared with the non-dosed specimen, the relative content of C–N and the glass transition temperature of the 1 MGy sample decreased, and the crystallinity increased, thus increasing the γ and α peak intensities. Compared with the 1 MGy sample, only the glass transition temperature had risen, thereby enhancing the β peak intensity. With the foregoing, a theoretical base for the selection and modification of insulation materials for spacecraft is provided.

Utilizing Thermal Mass in Refrigerated Display Cases to Reduce Peak Demand

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fricke, Brian A; Kuruganti, Teja; Nutaro, James J

The potential to store energy within refrigerated food products presents convenience store and supermarket operators with an opportunity to participate in utility sponsored demand response programs, whereby electricity usage can be shifted or reduced during peak periods. To determine the feasibility of reducing peak demand by shifting the refrigeration load to off-peak times, experimental and analytical analyses were performed. Simulated product, consisting of one-pint containers filled with a 50% ethylene glycol and 50% water solution, were stored in a medium-temperature vertical open refrigerated display case. Product temperature rise as a function of time was determined by turning off the refrigerationmore » to the display case, while product temperature pull-down time was subsequently determined by turning on the refrigeration to the display case. It was found that the thermal mass of the product in a medium-temperature display case was such that during a 2.5 hour period with no refrigeration, the average product temperature increased by 5.5 C. In addition, it took approximately 3.5 hours for the product to recover to its initial temperature after the refrigeration was turned on. Transient heat conduction analyses for one-dimensional objects is in good agreement with the experimental results obtained in this study. From the analysis, it appears that the thermal mass of the stored product in refrigerated display cases is sufficient to allow product temperatures to safely drift for a significant time under reduced refrigeration system operation. Thus, strategies for shifting refrigeration system electrical demand can be developed. The use of an advanced refrigeration system controller that can respond to utility signals can enable demand shifting with minimal impact.« less

Quantifying Temperature Effects on Snow, Plant and Streamflow Dynamics in Headwater Catchments

NASA Astrophysics Data System (ADS)

Wainwright, H. M.; Sarah, T.; Siirila-Woodburn, E. R.; Newcomer, M. E.; Williams, K. H.; Hubbard, S. S.; Enquist, B. J.; Steltzer, H.; Carroll, R. W. H.

2017-12-01

Quantifying Temperature Effects on Snow, Plant and Streamflow Dynamics in Headwater Catchments Snow-dominated headwater catchments are critical for water resource throughout the world; particularly in Western US. Under climate change, temperature increases are expected to be amplified in mountainous regions. We use a data-driven approach to better understand the coupling among inter-annual variability in temperature, snow and plant community dynamics and stream discharge. We apply data mining methods (e.g., principal component analysis, random forest) to historical spatiotemporal datasets, including the SNOTEL data, Landsat-based normalized difference vegetation index (NDVI) and airborne LiDAR-based snow distribution. Although both snow distribution and NDVI are extremely heterogeneous spatially, the inter-annual variability and temporal responses are spatially consistent, providing an opportunity to quantify the effect of temperature in the catchment-scale. We demonstrate our approach in the East River Watershed of the Upper Colorado River Basin, including Rocky Mountain Biological Laboratory, where the changes in plant communities and their dynamics have been extensively documented. Results indicate that temperature - particularly spring temperature - has a significant control not only on the timing of snowmelt, plant NDVI and peak flow but also on the magnitude of peak NDVI, peak flow and annual discharge. Monthly temperature in spring explains the variability of snowmelt by the equivalent standard deviation of 3.4-4.4 days, and total discharge by 10-11%. In addition, the high correlation among June temperature, peak NDVI and annual discharge suggests a primary role of spring evapotranspiration on plant community phenology, productivity, and streamflow volume. On the other hand, summer monsoon precipitation does not contribute significantly to annual discharge, further emphasizing the importance of snowmelt. This approach is mostly based on a set of datasets typically available throughout the US, providing a powerful approach to link remote sensing techniques with long-term monitoring of temperature, snowfall, plant, and streamflow dynamics.

Formation of silicon nanocrystals in sapphire by ion implantation and the origin of visible photoluminescence

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yerci, S.; Serincan, U.; Dogan, I.

2006-10-01

Silicon nanocrystals, average sizes ranging between 3 and 7 nm, were formed in sapphire matrix by ion implantation and subsequent annealing. Evolution of the nanocrystals was detected by Raman spectroscopy and x-ray diffraction (XRD). Raman spectra display that clusters in the matrix start to form nanocrystalline structures at annealing temperatures as low as 800 deg. C in samples with high dose Si implantation. The onset temperature of crystallization increases with decreasing dose. Raman spectroscopy and XRD reveal gradual transformation of Si clusters into crystalline form. Visible photoluminescence band appears following implantation and its intensity increases with subsequent annealing process. Whilemore » the center of the peak does not shift, the intensity of the peak decreases with increasing dose. The origin of the observed photoluminescence is discussed in terms of radiation induced defects in the sapphire matrix.« less

Studies of the oxidized Cu(100) surface using positron annihilation induced Auger electron spectroscopy

NASA Astrophysics Data System (ADS)

Maddox, W.; Fazleev, N. G.; Nadesalingam, M. P.; Weiss, A. H.

2008-03-01

We discuss recent progress in studies of an oxidized Cu(100) single crystal subjected to vacuum annealing over a temperature range from 293K to 1073K using positron annihilation induced Auger electron spectroscopy (PAES). The PAES measurements show a large monotonic increase in the intensity of the positron annihilation induced Cu M2,3 VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 573 K. The intensity then decreases monotonically as the annealing temperature is increased to 873 K. Experimental PAES results are analyzed by performing calculations of positron surface states and annihilation probabilities of surface-trapped positrons with relevant core electrons taking into account the charge redistribution at the surface, surface reconstructions, and electron-positron correlations effects. The effects of oxygen adsorption and surface reconstruction on localization of positron surface state wave functions and annihilation characteristics are analyzed. Possible explanations are provided for the observed behavior of the intensity of positron annihilation induced Cu M2,3VV Auger peak with changes of the annealing temperature.

Probing critical behavior of 2D Ising ferromagnet with diluted bonds using Wang-Landau algorithm

NASA Astrophysics Data System (ADS)

Ridha, N. A.; Mustamin, M. F.; Surungan, T.

2018-03-01

Randomness is an important subject in the study of phase transition as defect and impurity may present in any real material. The pre-existing ordered phase of a pure system can be affected or even ruined by the presence of randomness. Here we study ferromagnetic Ising model on a square lattice with a presence of randomness in the form of bond dilution. The pure system of this model is known to experience second order phase transition, separating between the high temperature paramagnetic and low-temperature ferromagnetic phase. We used Wang-Landau algorithm of Monte Carlo method to obtain the density of states from which we extract the ensemble average of energy and the specific heat. We observed the signature of phase transition indicated by the diverging peak of the specific heat as system sizes increase. These peaks shift to the lower temperature side as the dilution increases. The lower temperature ordered phase preserves up to certain concentration of dilution and is totally ruined when the bonds no longer percolates.

Dynamics of low- and high-Z metal ions emitted during nanosecond laser-produced plasmas

NASA Astrophysics Data System (ADS)

Elsied, Ahmed M.; Diwakar, Prasoon K.; Polek, Mathew; Hassanein, Ahmed

2016-11-01

Dynamics of metal ions during laser-produced plasmas was studied. A 1064 nm, Nd: YAG laser pulse was used to ablate pure Al, Fe, Co, Mo, and Sn samples. Ion flux and velocity were measured using Faraday cup ion collector. Time-of-flight measurements showed decreasing ion flux and ion velocity with increasing atomic weight, and heavy metal ion flux profile exhibited multiple peaks that was not observed in lighter metals. Slow peak was found to follow shifted Maxwell Boltzmann distribution, while the fast peak was found to follow Gaussian distribution. Ion flux angular distribution that was carried out on Mo and Al using fixed laser intensity 2.5 × 1010 W/cm2 revealed that the slow ion flux peaks at small angles, that is, close to normal to the target ˜0° independent of target's atomic weight, and fast ion flux for Mo peaks at large angles ˜40° measured from the target normal, while it completely absents for Al. This difference in spatial and temporal distribution reveals that the emission mechanism of the fast and slow ions is different. From the slow ion flux angular distribution, the measured plume expansion ratio (plume forward peaking) was 1.90 and 2.10 for Al and Mo, respectively. Moreover, the effect of incident laser intensity on the ion flux emission as well as the emitted ion velocity were investigated using laser intensities varying from 2.5 × 1010 W/cm2 to 1.0 × 1011 W/cm2. Linear increase of fast ion flux and velocity, and quadratic increase of slow ion flux and velocity were observed. For further understanding of plume dynamics, laser optical emission spectroscopy was used to characterize Sn plasma by measuring the temporal and spatial evolution of plasma electron density Ne and electron temperature Te. At 3.5 mm away from the target, plasma density showed slow decrease with time, however electron temperature was observed to decrease dramatically. The maximum plasma density and temperature occurred at 0.5 mm away from target and were measured to be 8.0 × 1017 cm-3 and 1.3 eV, respectively.

Effects of finite beam and plasma temperature on the growth rate of a two-stream free electron laser with background plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mahdizadeh, N.; Aghamir, F. M.

2013-02-28

A fluid theory is used to derive the dispersion relation of two-stream free electron laser (TSFEL) with a magnetic planar wiggler pump in the presence of background plasma (BP). The effect of finite beams and plasma temperature on the growth rate of a TSFEL has been verified. The twelve order dispersion equation has been solved numerically. Three instabilities, FEL along with the TS and TS-FEL instabilities occur simultaneously. The analysis in the case of cold BP shows that when the effect of the beam temperature is taken into account, both instable bands of wave-number and peak growth rate in themore » TS instability increase, but peak growth of the FEL and TS-FEL instabilities decreases. Thermal motion of the BP causes to diminish the TS instability and it causes to decrease the FEL and TS-FEL instabilities. By increasing the beam densities and lowering initial velocities (in the collective Raman regime), growth rate of instabilities increases; however, it has opposite behavior in the Campton regime.« less

Silicon Carbide Diodes Characterization at High Temperature and Comparison With Silicon Devices

NASA Technical Reports Server (NTRS)

Lebron-Velilla, Ramon C.; Schwarze, Gene E.; Gardner, Brent G.; Adams, Jerry D., Jr.

2004-01-01

Commercially available silicon carbide (SiC) Schottky diodes from different manufacturers rated at 200, 300, 600, and 1200 V, were electrically tested and characterized as a function of temperature up to 300 C. Electrical tests included both steady state and dynamic tests. Steady state tests produced forward and reverse I-V characteristic curves. Transient tests evaluated the switching performance of the diodes in either a hard-switched DC to DC buck converter or a half-bridge boost converter. For evaluation and comparison purposes, the same tests were performed with current state-of-the-art ultra fast silicon (Si) pn-junction diodes of similar ratings and also a Si Schottky diode. The comparisons made were forward voltage drop at rated current, reverse current at rated voltage, and turn-off peak reverse recovery current and reverse recovery time. In addition, efficiency measurements were taken for the buck DC to DC converter using both the SiC Schottky diodes and the Si pn-junction diodes at different temperatures and frequencies. The test results showed that at high temperature, the forward voltage drop for SiC Schottky diodes is higher than the forward drop of the ultra fast Si pn-junction diodes. As the temperature increased, the forward voltage drop of the SiC Schottky increased while for the ultra fast Si pn-junction diodes, the forward voltage drop decreased as temperature increased. For the elevated temperature steady state reverse voltage tests, the SiC Schottky diodes showed low leakage current at their rated voltage. Likewise, for the transient tests, the SiC Schottky diodes displayed low reverse recovery currents over the range of temperatures tested. Conversely, the Si pn-junction diodes showed increasing peak reverse current values and reverse recovery times with increasing temperature. Efficiency measurements in the DC to DC buck converter showed the advantage of the SiC Schottky diodes over the ultra fast Si pn-junction diodes, especially at the higher temperatures and higher frequencies.

Climatic change on the Gulf of Fonseca (Central America) using two-step statistical downscaling of CMIP5 model outputs

NASA Astrophysics Data System (ADS)

Ribalaygua, Jaime; Gaitán, Emma; Pórtoles, Javier; Monjo, Robert

2018-05-01

A two-step statistical downscaling method has been reviewed and adapted to simulate twenty-first-century climate projections for the Gulf of Fonseca (Central America, Pacific Coast) using Coupled Model Intercomparison Project (CMIP5) climate models. The downscaling methodology is adjusted after looking for good predictor fields for this area (where the geostrophic approximation fails and the real wind fields are the most applicable). The method's performance for daily precipitation and maximum and minimum temperature is analysed and revealed suitable results for all variables. For instance, the method is able to simulate the characteristic cycle of the wet season for this area, which includes a mid-summer drought between two peaks. Future projections show a gradual temperature increase throughout the twenty-first century and a change in the features of the wet season (the first peak and mid-summer rainfall being reduced relative to the second peak, earlier onset of the wet season and a broader second peak).

Influence of deposition substrate temperature on the morphology and molecular orientation of chloroaluminum phthalocyanine films as well the performance of organic photovoltaic cells.

PubMed

Zheng, Yan-Qiong; Zhang, Jing; Yang, Fang; Komino, Takeshi; Wei, Bin; Zhang, Jianhua; Wang, Zixing; Pu, Wenhong; Yang, Changzhu; Adachi, Chihaya

2015-10-09

The dependence of the morphology of neat chloroaluminum phthalocyanine (ClAlPc) films on substrate temperature (Tsub) during deposition is investigated by variable angle spectroscopic ellipsometry (VASE), x-ray diffraction (XRD), and atomic force microscopy (AFM) to obtain detailed information about the molecular orientation, phase separation, and crystallinity. AFM images indicate that both grain size and root mean square (RMS) roughness noticeably increase with Tsub both in neat and blend films. Increasing Tsub from room temperature to 420 K increases the horizontal orientation of the ClAlPc molecules with an increase of the mean molecular tilt angle from 60.13° (300 K) to 65.86° (420 K). The UV-vis absorption band of the corresponding films increases and the peak wavelength slightly red shifts with the Tsub increase. XRD patterns show a clear diffraction peak at Tsub over 390 K, implying the π-stacking of interconnected ClAlPc molecules at high Tsub. Planar and bulk heterojunction (BHJ) photovoltaic cells containing pristine ClAlPc films and ClAlPc:C60 blend films fabricated at Tsub of 390 K show increases in the power conversion efficiency (ηPCE) of 28% (ηPCE = 3.12%) and 36% (ηPCE = 3.58%), respectively, relative to devices as-deposited at room temperature. The maximum short circuit current in BHJs is obtained at 390 K in the Tsub range from 300 K to 450 K.

Dependence of Tritium Release from Stainless Steel on Temperature and Water Vapor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shmayda, W. T.; Sharpe, M.; Boyce, A. M.

The impact of water vapor and temperature on the release of tritium from stainless steel was studied. Degreased stainless steel samples loaded with tritium at room temperature following a 24-h degassing in vacuum at room temperature were subjected to increasing temperatures or humidity. In general, increasing either the sample temperature or the humidity causes an increased quantity of tritium to be removed. Increasing the temperature to 300°C in a dry gas stream results in a significant release of tritium and is therefore an effective means for reducing the tritium inventory in steel. For humid purges at 30°C, a sixfold increasemore » in humidity results in a tenfold increase in the peak outgassing rate. Increasing the humidity from 4 parts per million (ppm) to 1000 ppm when the sample temperature is 100°C causes a significant increase in the tritium outgassing rate. Finally, a simple calculation shows that only 15% of the activity present in the sample was removed in these experiments, suggesting that the surface layer of adsorbed water participates in regulating tritium desorption from the surface.« less

Dependence of Tritium Release from Stainless Steel on Temperature and Water Vapor

DOE PAGES

Shmayda, W. T.; Sharpe, M.; Boyce, A. M.; ...

2015-09-15

The impact of water vapor and temperature on the release of tritium from stainless steel was studied. Degreased stainless steel samples loaded with tritium at room temperature following a 24-h degassing in vacuum at room temperature were subjected to increasing temperatures or humidity. In general, increasing either the sample temperature or the humidity causes an increased quantity of tritium to be removed. Increasing the temperature to 300°C in a dry gas stream results in a significant release of tritium and is therefore an effective means for reducing the tritium inventory in steel. For humid purges at 30°C, a sixfold increasemore » in humidity results in a tenfold increase in the peak outgassing rate. Increasing the humidity from 4 parts per million (ppm) to 1000 ppm when the sample temperature is 100°C causes a significant increase in the tritium outgassing rate. Finally, a simple calculation shows that only 15% of the activity present in the sample was removed in these experiments, suggesting that the surface layer of adsorbed water participates in regulating tritium desorption from the surface.« less

Glasslike dynamical behavior of the plastocyanin hydration water

NASA Astrophysics Data System (ADS)

Bizzarri, Anna Rita; Paciaroni, Alessandro; Cannistraro, Salvatore

2000-09-01

The dynamical behavior of water around plastocyanin has been investigated in a wide temperature range by molecular dynamics simulation. The mean square displacements of water oxygen atoms show, at long times, a tα trend for all temperatures. Below 150 K, α is constant and equal to 1; at higher temperatures it drops to a value significantly smaller than 1, and thereafter decreases with increasing temperature. The occurrence of such an anomalous diffusion matches the onset of the dynamical transition observed in the protein. The intermediate scattering function of water is characterized, at high temperature, by a stretched exponential decay evolving, at low temperature, toward a two step relaxation behavior, which becomes more evident on increasing the exchanged wave vector q. Both the mean square displacements and the intermediate scattering functions show, beyond the ballistic regime, a plateau, which progressively extends for longer times as long as the temperature is lowered, such behavior reflecting trapping of water molecules within a cage formed by the nearest neighbors. At low temperature, a low frequency broad inelastic peak is observed in the dynamical structure factor of hydration water; such an excess of vibrational modes being reminiscent of the boson peak, characteristic of disordered, amorphous systems. All these features, which are typical of complex systems, can be traced back to the glassy character of the hydration water and suggest a dynamical coupling occurring at the macromolecule-solvent interface.

Comparative analysis of thermal behavior, isothermal crystallization kinetics and polymorphism of palm oil fractions.

PubMed

Zhang, Xia; Li, Lin; Xie, He; Liang, Zhili; Su, Jianyu; Liu, Guoqin; Li, Bing

2013-01-15

Thermal behavior of palm stearin (PS) and palm olein (PO) was explored by monitoring peak temperature transitions by differential scanning calorimetry (DSC). The fatty acid composition (FAC), isothermal crystallization kinetics studied by pulsed Nuclear Magnetic Resonance (pNMR) and isothermal microstructure were also compared. The results indicated that the fatty acid composition had an important influence on the crystallization process. PS and PO both exhibited more multiple endotherms than exotherms which showed irregular peak shapes. An increasing in cooling rate, generally, was associated with an increase in peak size. Application of the Avaimi equation to isothermal crystallization of PS and PO revealed different nucleation and growth mechanisms based on the Avrami exponents. PS quickly reached the end of crystallization because of more saturated triacylglycerol (TAG). The Avrami index of PS were the same as PO under the same isothermal condition at lower temperatrue, indicating that the crystallization mechanism of the two samples based on super-cooling state were the same. According to the polarized light microscope (PLM) images, crystal morphology of PS and PO was different. With the temperature increased, the structure of crystal network of both PS and PO gradually loosened.

Effect of heating rate on thermoluminescence output of LiF: Mg, Ti (TLD-100) in dosimetric applications

NASA Astrophysics Data System (ADS)

Singh, Ranjit; Kainth, Harpreet Singh

2018-07-01

The luminiscence characteristics of thermoluminscence dosimeter LiF: Mg, Ti (TLD-100) irradiated to X-rays from 6 MV linac have been studied for wide range of 2-50 K/s readout linear heating rates. The reproducibility of glow curves for TLDs is found to be better at lower heating rates and depreciate at higher heating rates. The glow curve spectra were analysed using deconvolution procedure based on general-order kinetics. Shift in the peak maximum temperature per unit rise in heating rate for various peaks were found to decrease with heating rate. The TLDs irradiated with same dose exhibit decreasing TL counts with increase in the heating rate, which indicate the thermal quenching effect in TLD-100. The value of activation energy for each peak within the glow curve increases with heating rate. Calibration curves plotted for the dose range 0.4-1020 cGy exhibit decreasing slope with increasing readout heating rate. Corrections for temperature lag between the heating element and the dosimeter, and the effective heating rate (βeff) across the sample estimated using formulation proposed by Kitis and Tuyn and are found to be fairly applicable.

Humid Heat Waves at different warming levels

NASA Astrophysics Data System (ADS)

Russo, S.; Sillmann, J.; Sterl, A.

2017-12-01

The co-occurrence of consecutive hot and humid days during a heat wave can strongly affect human health. Here, we quantify humid heat wave hazard in the recent past and at different levels of global warming.We find that the magnitude and apparent temperature peak of heat waves, such as the ones observed in Chicago in 1995 and China in 2003, have been strongly amplified by humidity. Climate model projections suggest that the percentage of area where heat wave magnitude and peak are amplified by humidity increases with increasing warming levels. Considering the effect of humidity at 1.5o and 2o global warming, highly populated regions, such as the Eastern US and China, could experience heat waves with magnitude greater than the one in Russia in 2010 (the most severe of the present era).The apparent temperature peak during such humid-heat waves can be greater than 55o. According to the US Weather Service, at this temperature humans are very likely to suffer from heat strokes. Humid-heat waves with these conditions were never exceeded in the present climate, but are expected to occur every other year at 4o global warming. This calls for respective adaptation measures in some key regions of the world along with international climate change mitigation efforts.

Effect of 50 MeV Li3 + irradiation on structural and electrical properties of Mn-doped ZnO

NASA Astrophysics Data System (ADS)

Neogi, S. K.; Chattopadhyay, S.; Banerjee, Aritra; Bandyopadhyay, S.; Sarkar, A.; Kumar, Ravi

2011-05-01

The present work aims to study the effect of ion irradiation on structural and electrical properties and their correlation with the defects in the Zn1 - xMnxO-type system. Zn1 - xMnxO (x = 0.02, 0.04) samples have been synthesized by the solid-state reaction method and have been irradiated with 50 MeV Li3 + ions. The concomitant changes have been probed by x-ray diffraction (XRD), temperature-dependent electrical resistivity and positron annihilation lifetime (PAL) spectroscopy. The XRD result shows a single-phase wurtzite structure for Zn0.98Mn0.02O, whereas for the Zn0.96Mn0.04O sample an impurity phase has been found, apart from the usual peaks of ZnO. Ion irradiation removes this impurity peak. The grain size of the samples is found to be uniform. For Zn0.98Mn0.02O, the observed sharp decrease in room temperature resistivity (ρRT) with irradiation is consistent with the lowering of the full width at half maximum of the XRD peaks. However, for Zn0.96Mn0.04O, ρRT decreases for the initial fluence but increases for a further increase in fluence. All the irradiated Zn0.98Mn0.02O samples show a metal-semiconductor transition in temperature-dependent resistivity measurements at low temperature. But all the irradiated Zn0.96Mn0.04O samples show a semiconducting nature in the whole range of temperatures. Results of room temperature resistivity, XRD and PAL measurements are consistent with each other.

Effect of 50 MeV Li3+ irradiation on structural and electrical properties of Mn-doped ZnO.

PubMed

Neogi, S K; Chattopadhyay, S; Banerjee, Aritra; Bandyopadhyay, S; Sarkar, A; Kumar, Ravi

2011-05-25

The present work aims to study the effect of ion irradiation on structural and electrical properties and their correlation with the defects in the Zn(1 - x)Mn(x)O-type system. Zn(1 - x)Mn(x)O (x = 0.02, 0.04) samples have been synthesized by the solid-state reaction method and have been irradiated with 50 MeV Li(3+) ions. The concomitant changes have been probed by x-ray diffraction (XRD), temperature-dependent electrical resistivity and positron annihilation lifetime (PAL) spectroscopy. The XRD result shows a single-phase wurtzite structure for Zn(0.98)Mn(0.02)O, whereas for the Zn(0.96)Mn(0.04)O sample an impurity phase has been found, apart from the usual peaks of ZnO. Ion irradiation removes this impurity peak. The grain size of the samples is found to be uniform. For Zn(0.98)Mn(0.02)O, the observed sharp decrease in room temperature resistivity (ρ(RT)) with irradiation is consistent with the lowering of the full width at half maximum of the XRD peaks. However, for Zn(0.96)Mn(0.04)O, ρ(RT) decreases for the initial fluence but increases for a further increase in fluence. All the irradiated Zn(0.98)Mn(0.02)O samples show a metal-semiconductor transition in temperature-dependent resistivity measurements at low temperature. But all the irradiated Zn(0.96)Mn(0.04)O samples show a semiconducting nature in the whole range of temperatures. Results of room temperature resistivity, XRD and PAL measurements are consistent with each other.

Onset temperature for Si nanostructure growth on Si substrate during high vacuum electron beam annealing.

PubMed

Fang, F; Markwitz, A

2009-05-01

Silicon nanostructures, called Si nanowhiskers, are successfully synthesized on Si(100) substrate by high vacuum electron beam annealing. The onset temperature and duration needed for the Si nanowhiskers to grow was investigated. It was found that the onset and growth morphology of Si nanowhiskers strongly depend on the annealing temperature and duration applied in the annealing cycle. The onset temperature for nanowhisker growth was determined as 680 degrees C using an annealing duration of 90 min and temperature ramps of +5 degrees C s(-1) for heating and -100 degrees C s(-1) for cooling. Decreasing the annealing time at peak temperature to 5 min required an increase in peak temperature to 800 degrees C to initiate the nanowhisker growth. At 900 degrees C the duration for annealing at peak temperature can be set to 0 s to grow silicon nanowhiskers. A correlation was found between the variation in annealing temperature and duration and the nanowhisker height and density. Annealing at 900 degrees C for 0 s, only 2-3 nanowhiskers (average height 2.4 nm) grow on a surface area of 5 x 5 microm, whereas more than 500 nanowhiskers with an important average height of 4.6 nm for field emission applications grow on the same surface area for a sample annealed at 970 degrees C for 0 s. Selected results are presented showing the possibility of controlling the density and height of Si nanowhisker growth for field emission applications by applying different annealing temperature and duration.

Profiles of Ionospheric Storm-enhanced Density during the 17 March 2015 Great Storm

NASA Astrophysics Data System (ADS)

Liu, J.; Wang, W.; Burns, A. G.; Yue, X.; Zhang, S.; Zhang, Y.

2015-12-01

Ionospheric F2 region peak densities (NmF2) are expected to show a positive phase correlation with total electron content (TEC), and electron density is expected to have an anti-correlation with electron temperature near the ionospheric F2 peak. However, we show that, during the 17 March 2015 great storm, TEC and F2 region electron density peak height (hmF2) over Millstone Hill increased, but the F2 region electron density peak (NmF2) decreased significantly during the storm-enhanced density (SED) phase of the storm compared with the quiet-time ionosphere. This SED occurred where there was a negative ionospheric storm near the F2 peak and below it. The weak ionosphere below the F2 peak resulted in much reduced downward heat conduction for the electrons, trapping the heat in the topside. This, in turn, increased the topside scale height, so that, even though electron densities at the F2 peak were depleted, TEC increased in the SED. The depletion in NmF2 was probably caused by an increase in the density of the molecular neutrals, resulting in enhanced recombination. In addition, the storm-time topside ionospheric electron density profile was much closer to diffusive equilibrium than non-storm time profile because of less daytime plasma flow from the ionosphere to the plasmasphere.

Spin Multiphoton Antiresonance at Finite Temperatures

NASA Astrophysics Data System (ADS)

Hicke, Christian; Dykman, Mark

2007-03-01

Weakly anisotropic S>1 spin systems display multiphoton antiresonance. It occurs when an Nth overtone of the radiation frequency coincides with the distance between the ground and the Nth excited energy level (divided by ). The coherent response of the spin displays a sharp minimum or maximum as a function of frequency, depending on which state was initially occupied. We find the spectral shape of the response dips/peaks. We also study the stationary response for zero and finite temperatures. The response changes dramatically with increasing temperature, when excited states become occupied even in the absence of radiation. The change is due primarily to the increasing role of single-photon resonances between excited states, which occur at the same frequencies as multiphoton resonances. Single-photon resonances are broad, because the single-photon Rabi frequencies largely exceed the multi-photon ones. This allows us to separate different resonances and to study their spectral shape. We also study the change of the spectrum due to relaxational broadening of the peaks, with account taken of both decay and phase modulation.

Studies of Oxidation of the Cu(100) Surface Using Low Energy Positrons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fazleev, N. G.; Kazan State University, Kazan 420008; Maddox, W. B.

2009-03-10

Changes in the surface of an oxidized Cu(100) single crystal resulting from vacuum annealing have been investigated using positron annihilation induced Auger electron spectroscopy (PAES). PAES measurements show a large increase in the intensity of the positron annihilation induced Cu M{sub 2,3}VV Auger peak as the sample is subjected to a series of isochronal anneals in vacuum up to annealing temperature 300 deg. C. The intensity then decreases monotonically as the annealing temperature is increased to {approx}600 deg. C. Experimental PAES results are analyzed by performing calculations of positron surface states and annihilation probabilities of surface-trapped positrons with relevant coremore » electrons taking into account the charge redistribution at the surface, surface reconstructions, and electron-positron correlations effects. Possible explanation for the observed behavior of the intensity of positron annihilation induced Cu M{sub 2,3}VV Auger peak with changes of the annealing temperature is proposed.« less

Temporal pattern of questing tick Ixodes ricinus density at differing elevations in the coastal region of western Norway

PubMed Central

2014-01-01

Background Climate change can affect the activity and distribution of species, including pathogens and parasites. The densities and distribution range of the sheep tick (Ixodes ricinus) and it’s transmitted pathogens appears to be increasing. Thus, a better understanding of questing tick densities in relation to climate and weather conditions is urgently needed. The aim of this study was to test predictions regarding the temporal pattern of questing tick densities at two different elevations in Norway. We predict that questing tick densities will decrease with increasing elevations and increase with increasing temperatures, but predict that humidity levels will rarely affect ticks in this northern, coastal climate with high humidity. Methods We described the temporal pattern of questing tick densities at ~100 and ~400 m a.s.l. along twelve transects in the coastal region of Norway. We used the cloth lure method at 14-day intervals during the snow-free season to count ticks in two consecutive years in 20 m2 plots. We linked the temporal pattern of questing tick densities to local measurements of the prevailing weather. Results The questing tick densities were much higher and the season was longer at ~100 compared to at ~400 m a.s.l. There was a prominent spring peak in both years and a smaller autumn peak in one year at ~100 m a.s.l.; but no marked peak at ~400 m a.s.l. Tick densities correlated positively with temperature, from low densities <5°C, then increasing and levelling off >15-17°C. We found no evidence for reduced questing densities during the driest conditions measured. Conclusions Tick questing densities differed even locally linked to elevation (on the same hillside, a few kilometers apart). The tick densities were strongly hampered by low temperatures that limited the duration of the questing seasons, whereas the humidity appeared not to be a limiting factor under the humid conditions at our study site. We expect rising global temperatures to increase tick densities and lead to a transition from a short questing season with low densities in the current cold and sub-optimal tick habitats, to longer questing seasons with overall higher densities and a marked spring peak. PMID:24725997

Surface-potential decay of biased-probe contact-charged amorphous polymer films

NASA Astrophysics Data System (ADS)

Knorr, Nikolaus; Rosselli, Silvia; Nelles, Gabriele

2010-03-01

We have investigated the decay of scanning Kelvin probe force microscopy (KPFM) and electric force microscopy (EFM) signals from biased-probe contact-charged films of three different amorphous polymers representing wide-ranging water absorption capabilities. The surface-potential decay (SPD) has been measured by repeatedly scanning the charge pattern as a function of dissipation time t while varying the relative humidity (RH), the film thickness d, the temperature, the charging voltage, and the load on the scanning probe. Whereas increases in KPFM and EFM peak widths are appreciable only in the long run, the decay in the peak heights is rapid at the beginning and then strongly slowing down with time. Peak heights can be approximated for t <1 hour by power laws of negative exponents (-β), with 0<β<0.5 in dry conditions. β increases for thinner films and when scanning with higher probe loads. Raising the humidity or heating to temperatures well below the glass transition temperature of the polymer considerably increases β, with much stronger impacts for polymers with a higher water uptake capability. From the findings, we conclude that ionic charge carriers are trapped by the charge injection process in the volume of the polymers at low depths. A main contribution to SPD is by drift of the ions in their own space-charge field, mutually repelling each other and being attracted by their mirror charge in the grounded back electrode. Lateral drifts for small t are not resolved, increases in peak widths for t ≫1 h are predominantly due to increased probe—charge carrier distances. We interpret the power law approximation in terms of dispersive transport theory. We approximate trap-controlled apparent mobilities μ from isothermal KPFM peak height data, taken within a few minutes after charging, by a linear and a hyperbolic SPD model. Both models yield μ ≈10-14 cm2/(V s) for thin films (d ≈50 nm) in dry conditions. For mobilities derived similarly from isohumid measurements series, we find an exponential increase as a function of RH%. We furthermore suggest that two more mechanisms contributing to SPD are: first, by potential shielding of charge carriers by water dipoles, and second, in an indirect manner, by diffusion of injected water.

Modelling the seasonality of Lyme disease risk and the potential impacts of a warming climate within the heterogeneous landscapes of Scotland.

PubMed

Li, Sen; Gilbert, Lucy; Harrison, Paula A; Rounsevell, Mark D A

2016-03-01

Lyme disease is the most prevalent vector-borne disease in the temperate Northern Hemisphere. The abundance of infected nymphal ticks is commonly used as a Lyme disease risk indicator. Temperature can influence the dynamics of disease by shaping the activity and development of ticks and, hence, altering the contact pattern and pathogen transmission between ticks and their host animals. A mechanistic, agent-based model was developed to study the temperature-driven seasonality of Ixodes ricinus ticks and transmission of Borrelia burgdorferi sensu lato across mainland Scotland. Based on 12-year averaged temperature surfaces, our model predicted that Lyme disease risk currently peaks in autumn, approximately six weeks after the temperature peak. The risk was predicted to decrease with increasing altitude. Increases in temperature were predicted to prolong the duration of the tick questing season and expand the risk area to higher altitudinal and latitudinal regions. These predicted impacts on tick population ecology may be expected to lead to greater tick-host contacts under climate warming and, hence, greater risks of pathogen transmission. The model is useful in improving understanding of the spatial determinants and system mechanisms of Lyme disease pathogen transmission and its sensitivity to temperature changes. © 2016 The Author(s).

Modelling the seasonality of Lyme disease risk and the potential impacts of a warming climate within the heterogeneous landscapes of Scotland

PubMed Central

Gilbert, Lucy; Harrison, Paula A.; Rounsevell, Mark D. A.

2016-01-01

Lyme disease is the most prevalent vector-borne disease in the temperate Northern Hemisphere. The abundance of infected nymphal ticks is commonly used as a Lyme disease risk indicator. Temperature can influence the dynamics of disease by shaping the activity and development of ticks and, hence, altering the contact pattern and pathogen transmission between ticks and their host animals. A mechanistic, agent-based model was developed to study the temperature-driven seasonality of Ixodes ricinus ticks and transmission of Borrelia burgdorferi sensu lato across mainland Scotland. Based on 12-year averaged temperature surfaces, our model predicted that Lyme disease risk currently peaks in autumn, approximately six weeks after the temperature peak. The risk was predicted to decrease with increasing altitude. Increases in temperature were predicted to prolong the duration of the tick questing season and expand the risk area to higher altitudinal and latitudinal regions. These predicted impacts on tick population ecology may be expected to lead to greater tick–host contacts under climate warming and, hence, greater risks of pathogen transmission. The model is useful in improving understanding of the spatial determinants and system mechanisms of Lyme disease pathogen transmission and its sensitivity to temperature changes. PMID:27030039

Near-isothermal conditions in the middle and lower crust induced by melt migration.

PubMed

Depine, Gabriela V; Andronicos, Christopher L; Phipps-Morgan, Jason

2008-03-06

The thermal structure of the crust strongly influences deformation, metamorphism and plutonism. Models for the geothermal gradient in stable crust predict a steady increase of temperature with depth. This thermal structure, however, is incompatible with observations from high-temperature metamorphic terranes exhumed in orogens. Global compilations of peak conditions in high-temperature metamorphic terranes define relatively narrow ranges of peak temperatures over a wide range in pressure, for both isothermal decompression and isobaric cooling paths. Here we develop simple one-dimensional thermal models that include the effects of melt migration. These models show that long-lived plutonism results in a quasi-steady-state geotherm with a rapid temperature increase in the upper crust and nearly isothermal conditions in the middle and lower crust. The models also predict that the upward advection of heat by melt generates granulite facies metamorphism, and widespread andalusite-sillimanite metamorphism in the upper crust. Once the quasi-steady-state thermal profile is reached, the middle and lower crust are greatly weakened due to high temperatures and anatectic conditions, thus setting the stage for gravitational collapse, exhumation and isothermal decompression after the onset of plutonism. Near-isothermal conditions in the middle and lower crust result from the thermal buffering effect of dehydration melting reactions that, in part, control the shape of the geotherm.

Zero bias conductance peak in InAs nanowire coupled to superconducting electrodes

NASA Astrophysics Data System (ADS)

Kim, Nam-Hee; Shin, Yun-Sok; Kim, Hong-Seok; Song, Jin-Dong; Doh, Yong-Joo

2018-04-01

We report the occurrence of the zero-bias conductance peak (ZBCP) in an InAs nanowire coupled to PbIn superconductors with varying temperature, bias voltage, and magnetic field. The ZBCP is suppressed with increasing temperature and bias voltage above the Thouless energy of the nanowire. Applying a magnetic field also diminishes the ZBCP when the resultant magnetic flux reaches the magnetic flux quantum h/2e. Our observations are consistent with theoretical expectations of reflectionless tunneling, in which the phase coherence between an electron and its Andreev-reflected hole induces the ZBCP as long as time-reversal symmetry is preserved.

Heat generation during removal of an abutment screw fragment from dental implants.

PubMed

Arias, Sergio R; Rueggeberg, Frederick A; Mettenburg, Donald; Sharawy, Mohamed; Looney, Stephen; Elsayed, Ranya; Elsalanty, Mohammed E

2018-04-01

Little information is available on the effect of drilling speed on surrounding bone during the removal of an abutment screw fragment. The purpose of this in vitro study was to compare, in vitro, the peak temperature increase during the removal of fractured abutment screws from implants placed in a porcine mandible, using drilling speeds of 600 or 2000 rpm. Twenty 4.3×13-mm dental implants were placed in 10 dissected porcine mandibles: 2 implants per mandible, 1 on each side. Localized defects were created in 20 surface-treated abutment screws, which were then tightened into each implant until a reproducible fracture occurred in each screw. The fractured screws were removed with a handpiece removal kit and irrigated with room-temperature water at either 600 or 2000 rpm. The temperature rise at the implant surface was measured at 3 levels with 3 type-K thermocouples. Repeated measure ANOVA was performed with the Tukey-Kramer post hoc test for mean pair-wise comparisons (α=.05 for all tests). Mean peak temperatures were significantly higher at 2000 rpm than at 600 rpm in the mid-body (P<.001) and crestal (P=.003) regions but not in the apical (P=.225) implant locations. No significant differences in mean peak temperatures were found among the 3 locations using 600 rpm (P=.179). In the 2000-rpm group, mean peak temperature in the mid-body area was consistently higher than that in the apical (P<.001) area, and more instances of temperature rise above 56°C and 60°C were observed. In 1 implant from this group, the estimated peak temperature exceeded the bone damage threshold value (50°C for 30 seconds). A drilling speed of 2000 rpm during the removal of abutment screw fragments caused overheating of the outer surface of the implant which may damage the surrounding bone; a speed of 600 rpm appears to be safe. Copyright © 2017 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

Annealing effect on the structural and dielectric properties of hematite nanoparticles

NASA Astrophysics Data System (ADS)

Kumar, Vijay; Chahal, Surjeet; Singh, Dharamvir; Kumar, Ashok; Kumar, Parmod; Asokan, K.

2018-05-01

In the present work, we have synthesized hematite (α-Fe2O3) nanoparticles by sol-gel method and sintered them at different temperatures (200 °C, 400 °C and 800 °C for six hours). The samples were then characterized using versatile characterization techniques such as X-ray diffraction (XRD), dielectric measurement and temperature dependent resistivity (RT) for their structural, dielectric and electrical properties. XRD measurements infer that intensity of peak increases with an increase in temperature resulting an increase in crystallite size. Temperature dependent resistivity also shows decrease in the resistivity of the samples. Furthermore, the dielectric measurements correspond to the increase in the dielectric constant. Based on these observations, it can be inferred that sintering temperature plays an important role in tailoring the various physical properties of hematite nanoparticles.

PDF as a coupling mediator between the light-entrainable and temperature-entrainable clocks in Drosophila melanogaster.

PubMed

Tomioka, K; Miyasako, Y; Umezaki, Y

2008-01-01

Drosophila shows bimodal circadian locomotor rhythms with peaks around light-on (morning peak) and before light-off (evening peak). The rhythm synchronizes to light and temperature cycles and the synchronization is achieved by two sets of clocks: one entrains to light cycles and the other to temperature cycles. The light-entrainable clock consists of the clock neurons located in the lateral protocerebrum (LNs) and the temperature-entrainable clock involves those located in the dorsal protocerebrum (DNs) and the cells located in the posterior lateral protocerebrum (LPNs). To understand the interaction between the light-entrainable and the temperature-entrainable clock neurons, locomotor rhythms of the mutant flies lacking PDF or PDF-positive clock neurons were examined. Under the light cycles, they showed altered phase of the evening peak. When exposed to temperature cycles of lower temperature levels, the onset of evening peak showed larger advance in contrast to those of wild-type flies. The termination of the peak also advanced while that of wild-type flies remained almost at the same phase as in the constant temperature. These results support our hypothesis that the PDF-positive light entrainable cells regulate the phase of the temperature entrainable cells to be synchronized to their own phase using PDF as a coupling mediator.

Dynamic void behavior in polymerizing polymethyl methacrylate cement.

PubMed

Muller, Scott D; McCaskie, Andrew W

2006-02-01

Cement mantle voids remain controversial with respect to survival of total hip arthroplasty. Void evolution is poorly understood, and attempts at void manipulation can only be empirical. We induced voids in a cement model simulating the constraints of the proximal femur. Intravoid pressure and temperature were recorded throughout polymerization, and the initial and final void volumes were measured. Temperature-dependent peak intravoid pressures and void volume increases were observed. After solidification, subatmospheric intravoid pressures were observed. The magnitude of these observations could not be explained by the ideal gas law. Partial pressures of the void gas at peak pressures demonstrated a dominant effect of gaseous monomer, thereby suggesting that void growth is a pressure-driven phenomenon resulting from temperature-dependent evaporation of monomer into existing trapped air voids.

Magnetism of Ho 1-xTb xAl₂ alloys: Critical dependence of a first-order transition on Tb concentration

DOE PAGES

Khan, Mahmud; Mudryk, Ya.; Gschneidner, K. A.; ...

2011-12-27

HoAl₂ exhibits a first-order spin reorientation transition at 20 K, which is manifested as a sharp peak in the heat capacity. When Ho is partially replaced by only 5% of Tb, the sharp heat-capacity peak in Ho 1-xTb xAl₂ (x = 0.05) disappears, and then reappears again for x ≥ 0.07. For x = 0.05, the anomaly corresponding to the spin reorientation transition is barely seen in the heat capacity, but as x exceeds 0.07 the weak anomaly transforms to a sharp peak. The spin reorientation transition temperature increases to 29 K for x = 0.05, and as x increasesmore » further the transition shifts to lower temperature and returns to ~20 K for x = 0.25. The transition is no longer observed when x exceeds 0.60. Temperature-dependent x-ray powder-diffraction data confirm the first-order nature of the spin reorientation transition for the alloy with x = 0.40, and indicate that the compound retains the room-temperature cubic structure within the sensitivity of the technique. Experimental observations are discussed considering the easy magnetization directions of HoAl₂ and TbAl₂.« less

Temperature-assisted solute focusing with sequential trap/release zones in isocratic and gradient capillary liquid chromatography: Simulation and experiment

PubMed Central

Groskreutz, Stephen R.; Weber, Stephen G.

2016-01-01

In this work we characterize the development of a method to enhance temperature-assisted on-column solute focusing (TASF) called two-stage TASF. A new instrument was built to implement two-stage TASF consisting of a linear array of three independent, electronically controlled Peltier devices (thermoelectric coolers, TECs). Samples are loaded onto the chromatographic column with the first two TECs, TEC A and TEC B, cold. In the two-stage TASF approach TECs A and B are cooled during injection. TEC A is heated following sample loading. At some time following TEC A’s temperature rise, TEC B’s temperature is increased from the focusing temperature to a temperature matching that of TEC A. Injection bands are focused twice on-column, first on the initial TEC, e.g. single-stage TASF, then refocused on the second, cold TEC. Our goal is to understand the two-stage TASF approach in detail. We have developed a simple yet powerful digital simulation procedure to model the effect of changing temperature in the two focusing zones on retention, band shape and band spreading. The simulation can predict experimental chromatograms resulting from spatial and temporal temperature programs in combination with isocratic and solvent gradient elution. To assess the two-stage TASF method and the accuracy of the simulation well characterized solutes are needed. Thus, retention factors were measured at six temperatures (25–75 °C) at each of twelve mobile phases compositions (0.05–0.60 acetonitrile/water) for homologs of n-alkyl hydroxylbenzoate esters and n-alkyl p-hydroxyphenones. Simulations accurately reflect experimental results in showing that the two-stage approach improves separation quality. For example, two-stage TASF increased sensitivity for a low retention solute by a factor of 2.2 relative to single-stage TASF and 8.8 relative to isothermal conditions using isocratic elution. Gradient elution results for two-stage TASF were more encouraging. Application of two-stage TASF increased peak height for the least retained solute in the test mixture by a factor of 3.2 relative to single-stage TASF and 22.3 compared to isothermal conditions for an injection four-times the column volume. TASF improved resolution and increased peak capacity; for a 12-minute separation peak capacity increased from 75 under isothermal conditions to 146 using single-stage TASF, and 185 for two-stage TASF. PMID:27836226

Temperature-assisted solute focusing with sequential trap/release zones in isocratic and gradient capillary liquid chromatography: Simulation and experiment.

PubMed

Groskreutz, Stephen R; Weber, Stephen G

2016-11-25

In this work we characterize the development of a method to enhance temperature-assisted on-column solute focusing (TASF) called two-stage TASF. A new instrument was built to implement two-stage TASF consisting of a linear array of three independent, electronically controlled Peltier devices (thermoelectric coolers, TECs). Samples are loaded onto the chromatographic column with the first two TECs, TEC A and TEC B, cold. In the two-stage TASF approach TECs A and B are cooled during injection. TEC A is heated following sample loading. At some time following TEC A's temperature rise, TEC B's temperature is increased from the focusing temperature to a temperature matching that of TEC A. Injection bands are focused twice on-column, first on the initial TEC, e.g. single-stage TASF, then refocused on the second, cold TEC. Our goal is to understand the two-stage TASF approach in detail. We have developed a simple yet powerful digital simulation procedure to model the effect of changing temperature in the two focusing zones on retention, band shape and band spreading. The simulation can predict experimental chromatograms resulting from spatial and temporal temperature programs in combination with isocratic and solvent gradient elution. To assess the two-stage TASF method and the accuracy of the simulation well characterized solutes are needed. Thus, retention factors were measured at six temperatures (25-75°C) at each of twelve mobile phases compositions (0.05-0.60 acetonitrile/water) for homologs of n-alkyl hydroxylbenzoate esters and n-alkyl p-hydroxyphenones. Simulations accurately reflect experimental results in showing that the two-stage approach improves separation quality. For example, two-stage TASF increased sensitivity for a low retention solute by a factor of 2.2 relative to single-stage TASF and 8.8 relative to isothermal conditions using isocratic elution. Gradient elution results for two-stage TASF were more encouraging. Application of two-stage TASF increased peak height for the least retained solute in the test mixture by a factor of 3.2 relative to single-stage TASF and 22.3 compared to isothermal conditions for an injection four-times the column volume. TASF improved resolution and increased peak capacity; for a 12-min separation peak capacity increased from 75 under isothermal conditions to 146 using single-stage TASF, and 185 for two-stage TASF. Copyright © 2016 Elsevier B.V. All rights reserved.

Dislocation-mediated trapping of deuterium in tungsten under high-flux high-temperature exposures

NASA Astrophysics Data System (ADS)

Bakaeva, A.; Terentyev, D.; De Temmerman, G.; Lambrinou, K.; Morgan, T. W.; Dubinko, A.; Grigorev, P.; Verbeken, K.; Noterdaeme, J. M.

2016-10-01

The effect of severe plastic deformation on the deuterium retention in tungsten exposed to high-flux low-energy plasma (flux ∼1024 m-2 s-1, energy ∼50 eV and fluence up to 5 × 1025 D/m2) was studied experimentally in a wide temperature range (460-1000 K) relevant for application in ITER. The desorption spectra in both reference and plastically-deformed samples were deconvoluted into three contributions associated with the detrapping from dislocations, deuterium-vacancy clusters and pores. As the exposure temperature increases, the positions of the release peaks in the plastically-deformed material remain in the same temperature range but the peak amplitudes are altered as compared to the reference material. The desorption peak attributed to the release from pores (i.e. cavities and bubbles) was suppressed in the plastically deformed samples for the low-temperature exposures, but became dominant for exposures above 700 K. The observed strong modulation of the deuterium storage in "shallow" and "deep" traps, as well as the reduction of the integral retention above 700 K, suggest that the dislocation network changes its role from "trapping sites" to "diffusion channels" above a certain temperature. The major experimental observations of the present work are in line with recent computational assessment based on atomistic and mean field theory calculations available in literature.

Temperature Dependence in the Terahertz Spectrum of Nicotinamide: Anharmonicity and Hydrogen-Bonded Network.

PubMed

Takahashi, Masae; Okamura, Nubuyuki; Fan, Xinyi; Shirakawa, Hitoshi; Minamide, Hiroaki

2017-04-06

We have investigated the terahertz-spectral property of nicotinamide focusing on the temperature dependence in the range of 14-300 K. We observed that almost all peaks in the terahertz spectrum of the nicotinamide crystal showed a remarkable shift with temperature, whereas the lowest-frequency peak at 34.8 cm -1 showed a negligible shift with temperature. By analyzing the terahertz spectrum with the dispersion-corrected density functional theory calculations, we found that the difference in the temperature dependence of the peak shift is well understood in terms of the presence/absence of stretching vibration of the intermolecular hydrogen bond in the mode and the change of cell parameters. The anharmonicity in the dissociation potential energy of very weak intermolecular hydrogen bonding causes the remarkable peak shift with temperature in the terahertz spectrum of nicotinamide. This finding suggests that the assignment and identification of peaks in the terahertz spectrum are systematically enabled by temperature-dependent measurements.

Morphology dependent amplified spontaneous emission in π-conjugated polymer

NASA Astrophysics Data System (ADS)

Wang, Yuchen; Yang, Xiao; Wang, Ruizhi; Li, Li; Li, Heng

2015-08-01

The amplified spontaneous emission (ASE) spectra of a π-conjugated polymer Poly [2-methoxy-5-(2‧-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) are studied in as-cast film, annealed film, 1 mg/ml solution and 2.5 mg/ml solution, respectively, using a 10 ns pulsed laser as an excitation source. We found that for annealed film (420 K), the ASE is hardly achieved compared to the as-cast film, which is consistent with the formation of the aggregation; whereas the film's temperature had much less effect on its ASE threshold. In solution, the ASE spectra show both 0-0 peak and 0-1 peak in 1 mg/ml solution, but only 0-1 peak in 2.5 mg/ml one. When the temperature of solution increases slightly from 300 K to 330 K, the ASE threshold increases dramatically in 1 mg/ml solution but slightly in 2.5 mg/ml one. Our results show the important role the morphology played in the ASE spectra in both film and solution. Therefore, controlling the interchain interaction in PCPs may be the key factor for performance of the organic lasers.

Influence of stress, temperature, and strain on calcite twins constrained by deformation experiments

NASA Astrophysics Data System (ADS)

Rybacki, E.; Evans, B.; Janssen, C.; Wirth, R.; Dresen, G.

2013-08-01

A series of low-strain triaxial compression and high-strain torsion experiments were performed on marble and limestone samples to examine the influence of stress, temperature, and strain on the evolution of twin density, the percentage of grains with 1, 2, or 3 twin sets, and the twin width—all parameters that have been suggested as either paleopiezometers or paleothermometers. Cylindrical and dog-bone-shaped samples were deformed in the semibrittle regime between 20 °C and 350 °C, under confining pressures of 50-400 MPa, and at strain rates of 10- 4-10- 6 s- 1. The samples sustained shear stresses, τ, up to 280 MPa, failing when deformed to shear strains γ > 1. The mean width of calcite twins increased with both temperature and strain, and thus, measurement of twin width provides only a rough estimation of peak temperature, unless additional constraints on deformation are known. In Carrara marble, the twin density, NL (no of twins/mm), increased as the rock hardened with strain and was approximately related to the peak differential stress, σ (MPa), by the relation σ=19.5±9.8√{N}. Dislocation tangles occurred along twin boundaries, resulting in a complicated cell structure, which also evolved with stress. As previously established, the square root of dislocation density, observed after quench, also correlated with peak stress. Apparently, both twin density and dislocation cell structure are important state variables for describing the strength of these rocks.

Reductions in labour capacity from heat stress under climate warming

NASA Astrophysics Data System (ADS)

Dunne, John P.; Stouffer, Ronald J.; John, Jasmin G.

2013-06-01

A fundamental aspect of greenhouse-gas-induced warming is a global-scale increase in absolute humidity. Under continued warming, this response has been shown to pose increasingly severe limitations on human activity in tropical and mid-latitudes during peak months of heat stress. One heat-stress metric with broad occupational health applications is wet-bulb globe temperature. We combine wet-bulb globe temperatures from global climate historical reanalysis and Earth System Model (ESM2M) projections with industrial and military guidelines for an acclimated individual's occupational capacity to safely perform sustained labour under environmental heat stress (labour capacity)--here defined as a global population-weighted metric temporally fixed at the 2010 distribution. We estimate that environmental heat stress has reduced labour capacity to 90% in peak months over the past few decades. ESM2M projects labour capacity reduction to 80% in peak months by 2050. Under the highest scenario considered (Representative Concentration Pathway 8.5), ESM2M projects labour capacity reduction to less than 40% by 2200 in peak months, with most tropical and mid-latitudes experiencing extreme climatological heat stress. Uncertainties and caveats associated with these projections include climate sensitivity, climate warming patterns, CO2 emissions, future population distributions, and technological and societal change.

Source attribution of aerosol size distributions and model evaluation using Whistler Mountain measurements and GEOS-Chem-TOMAS simulations

NASA Astrophysics Data System (ADS)

D'Andrea, S. D.; Ng, J. Y.; Kodros, J. K.; Atwood, S. A.; Wheeler, M. J.; Macdonald, A. M.; Leaitch, W. R.; Pierce, J. R.

2016-01-01

Remote and free-tropospheric aerosols represent a large fraction of the climatic influence of aerosols; however, aerosol in these regions is less characterized than those polluted boundary layers. We evaluate aerosol size distributions predicted by the GEOS-Chem-TOMAS global chemical transport model with online aerosol microphysics using measurements from the peak of Whistler Mountain, British Columbia, Canada (2182 m a.s.l., hereafter referred to as Whistler Peak). We evaluate the model for predictions of aerosol number, size, and composition during periods of free-tropospheric (FT) and boundary-layer (BL) influence at "coarse" 4° × 5° and "nested" 0.5° × 0.667° resolutions by developing simple FT/BL filtering techniques. We find that using temperature as a proxy for upslope flow (BL influence) improved the model-measurement comparisons. The best threshold temperature was around 2 °C for the coarse simulations and around 6 °C for the nested simulations, with temperatures warmer than the threshold indicating boundary-layer air. Additionally, the site was increasingly likely to be in cloud when the measured relative humidity (RH) was above 90 %, so we do not compare the modeled and measured size distributions during these periods. With the inclusion of these temperature and RH filtering techniques, the model-measurement comparisons improved significantly. The slope of the regression for N80 (the total number of particles with particle diameter, Dp, > 80 nm) in the nested simulations increased from 0.09 to 0.65, R2 increased from 0.04 to 0.46, and log-mean bias improved from 0.95 to 0.07. We also perform simulations at the nested resolution without Asian anthropogenic emissions and without biomass-burning emissions to quantify the contribution of these sources to aerosols at Whistler Peak (through comparison with simulations with these emissions on). The long-range transport of Asian anthropogenic aerosol was found to be significant throughout all particle number concentrations, and increased N80 by more than 50 %, while decreasing the number of smaller particles because of suppression of new-particle formation and enhanced coagulation sink. Similarly, biomass burning influenced Whistler Peak during summer months, with an increase in N80 exceeding 5000 cm-3. Occasionally, Whistler Peak experienced N80 > 1000 cm-3 without significant influence from Asian anthropogenic or biomass-burning aerosol. Air masses were advected at low elevations through forested valleys during times when temperature and downwelling insolation were high, ideal conditions for formation of large sources of low-volatility biogenic secondary organic aerosol (SOA). This condensable material increased particle growth and hence N80. The low-cost filtering techniques and source apportionment used in this study can be used in other global models to give insight into the sources and processes that shape the aerosol at mountain sites, leading to a better understanding of mountain meteorology and chemistry.

Inexistence of permafrost at the top of the Veleta peak (Sierra Nevada)

NASA Astrophysics Data System (ADS)

Gómez-Ortiz, Antonio; Salvador-Franch, Ferran; Salvà-Catarineu, Montserrat; Oliva, Marc; Palacios, David; Tanarro, Luis Miguel; Schulte, Lothar

2014-05-01

Several deep drillings wew carried out along a latitudinal transect from Svalbard (78°N) to Sierra Nevada (37°N, Spain) within the project Permafrost and Climate Change in Europe (PACE). In this abstract we discuss the data corresponding to the drilling existing at the top of the Veleta peak, at an altitude of 3380 m. This drilling reach a depth of 114.5 m depth, although we analyze here the data of the first 60 m depth. UTL-1 loggers were installed at depths of 0.2, 0.6, 1.2, 2.6, 4, 7, 10, 13, 15, 20 and 60 m. The observation period spans from 2002 to 2013 with data being taken every 2 h. The most surficial loggersrecorded the largest annual temperature oscillations, reaching 22.6°C at 20 cm. Down to 10 m depth the annual temperature amplitude is still remarkable and seasonal temperature changes are even observed at depths of 15 to 20 m. Below this level the temperature remains constant. The logger installed at 60 m depth recorded small temperature changes between 2006 and 2009, oscillating between 2.38 and 2.61ºC. Since January 2010 the temperatures stabilized at 2.61°C. However, this slight temperature increase must be framed within the margin of instrumentation error of the devices. Data shows evidence of the inexistence ofpermanent negative temperatures at depth. In contrast to what happens in the nearby Veleta cirque floor (3100 m), where marginal permafrost conditions have been recorded, in the Veleta peak (3380 m) data points to the absence of a permafrost regime. This may be due to several factors: a) The existence of permafrost in the Veletacirque is directly related to the presence of fossil glacier ice corresponding to a glacier that existed there during the Little Ice Age. b ) The early melting of snow cover in the Veleta peak due to wind effect and incidence of solar radiation condition the absence of permafrost conditions at the summitin contrast to the Veleta cirquefloor, where the longer persistence of snow favours the presence of continuous negative temperatures. c) The topographical setting of the Veleta peak favours a major incidence of radiation through therock walls,conditioning higher temperatures.

[The negative temperature effect of UV absorbance on C60 in different solvents].

PubMed

Yang, Tao; Zeng, Fan-qin; Ge, Qi; Xiong, Qian; Guo, Feng; Zhang, Xun-gao

2004-02-01

Ultraviolet Absorption Spectrum of Difference in Temperature (UVSDT) of C60 was studied in different solvents by UV-240 ultraviolet-visible spectrophotometer. Two samples were tested, one of which acted as reference sample and the other as ready test sample. During the period of the experiment, the temperature of the reference sample remained constant, while that of the ready test sample was changed to obtain difference in temperature. The two samples were scanned in succession by UV-240 ultraviolet-visible spectrophotometer using a certain range of wavelength. By changing the temperature of the ready test sample, we can get the ultraviolet absorption spectrum changing curve with temperature differential. In addition, the curve was studied by putting C60 in different solvents (alcohol, cyclohexane, n-hexane and 2-propanol). The curve indicates that the intensity of the absorption peak wavelength of C60 decreased with increasing the temperature of the sample, and a negative peak was observed in UVSDT. And the greater the difference in temperature, the higher the intensity of the negative peak. The result reflects that the structure of C60 depends strongly on its temperature, and the dependent relationship is closely related to the type of pi-pi electron transition. So it's valuable to test the absorption rate of C60 and obtain the changing curve in real time. It'll help us to separate, purify, analyze, and characterize C60. And it'll also help to do research on the mechanism of the chemical reactions, which take place in solvents, as well as to improve veracity.

Temperature dependence of pre-edge features in Ti K-edge XANES spectra for ATiO₃ (A = Ca and Sr), A₂TiO₄ (A = Mg and Fe), TiO₂ rutile and TiO₂ anatase.

PubMed

Hiratoko, Tatsuya; Yoshiasa, Akira; Nakatani, Tomotaka; Okube, Maki; Nakatsuka, Akihiko; Sugiyama, Kazumasa

2013-07-01

XANES (X-ray absorption near-edge structure) spectra of the Ti K-edges of ATiO3 (A = Ca and Sr), A2TiO4 (A = Mg and Fe), TiO2 rutile and TiO2 anatase were measured in the temperature range 20-900 K. Ti atoms for all samples were located in TiO6 octahedral sites. The absorption intensity invariant point (AIIP) was found to be between the pre-edge and post-edge. After the AIIP, amplitudes damped due to Debye-Waller factor effects with temperature. Amplitudes in the pre-edge region increased with temperature normally by thermal vibration. Use of the AIIP peak intensity as a standard point enables a quantitative comparison of the intensity of the pre-edge peaks in various titanium compounds over a wide temperature range.

Development of septum-free injector for gas chromatography and its application to the samples with a high boiling point.

PubMed

Ito, Hiroshi; Hayakawa, Kazuichi; Yamamoto, Atsushi; Murase, Atsushi; Hayakawa, Kazumi; Kuno, Minoru; Inoue, Yoshinori

2006-11-03

A novel apparatus with a simple structure has been developed for introducing samples into the vaporizing chamber of a gas chromatograph. It requires no septum due to the gas sealing structure over the carrier gas supply line. The septum-free injector made it possible to use injection port temperatures as high as 450 degrees C. Repetitive injection of samples with boiling points below 300 degrees C resulted in peak areas with relative standard deviations between 1.25 and 3.28% (n=5) and good linearity (r(2)>0.9942) for the calibration curve. In the analysis of polycyclic aromatic hydrocarbons and a base oil, the peak areas of components with high boiling points increased as the injection port temperature was increased to 450 degrees C.

Pyrolysis characteristics of typical biomass thermoplastic composites

NASA Astrophysics Data System (ADS)

Cai, Hongzhen; Ba, Ziyu; Yang, Keyan; Zhang, Qingfa; Zhao, Kunpeng; Gu, Shiyan

The biomass thermoplastic composites were prepared by extrusion molding method with poplar flour, rice husk, cotton stalk and corn stalk. The thermo gravimetric analyzer (TGA) has also been used for evaluating the pyrolysis process of the composites. The results showed that the pyrolysis process mainly consists of two stages: biomass pyrolysis and the plastic pyrolysis. The increase of biomass content in the composite raised the first stage pyrolysis peak temperature. However, the carbon residue was reduced and the pyrolysis efficiency was better because of synergistic effect of biomass and plastic. The composite with different kinds of biomass have similar pyrolysis process, and the pyrolysis efficiency of the composite with corn stalk was best. The calcium carbonate could inhibit pyrolysis process and increase the first stage pyrolysis peak temperature and carbon residue as a filling material of the composite.

Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan.

PubMed

Shibata, Mitsuhiro; Enjoji, Motohiro; Sakazume, Katsumi; Ifuku, Shinsuke

2016-06-25

Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. Copyright © 2016 Elsevier Ltd. All rights reserved.

Physicochemical and Thermal Properties of Extruded Instant Functional Rice Porridge Powder as Affected by the Addition of Soybean or Mung Bean.

PubMed

Mayachiew, Pornpimon; Charunuch, Chulaluck; Devahastin, Sakamon

2015-12-01

Legumes contain protein, micronutrients, and bioactive compounds, which provide various health benefits. In this study, soybean or mung bean was mixed in rice flour to produce by extrusion instant functional legume-rice porridge powder. The effects of the type and percentage (10%, 20%, or 30%, w/w) of legumes on the expansion ratio of the extrudates were first evaluated. Amino acid composition, color, and selected physicochemical (bulk density, water absorption index, and water solubility index), thermal (onset temperature, peak temperature, and transition enthalpy), and pasting (peak viscosity, trough viscosity, and final viscosity) properties of the powder were determined. The crystalline structure and formation of amylose-lipid complexes and the total phenolics content (TPC) and antioxidant activity of the powder were also measured. Soybean-blended porridge powder exhibited higher TPC, 2,2-diphenyl-1-picrylhydrazyl radical scavenging capacity, ferric reducing antioxidant power, amino acid, and fat contents than the mung bean-blended porridge powder. Incorporating either legume affected the product properties by decreasing the lightness and bulk density, while increasing the greenness and yellowness and the peak temperature and transition enthalpy. Expansion capacity of the extrudates increased with percentage of mung bean in the mixture but decreased as the percentage of soybean increased. Amylose-lipid complexes formation was confirmed by X-ray diffraction analysis results. Addition of soybean or mung bean resulted in significant pasting property changes of the porridge powder. © 2015 Institute of Food Technologists®

Sensitivity of potential evapotranspiration and simulated flow to varying meteorological inputs, Salt Creek watershed, DuPage County, Illinois

USGS Publications Warehouse

Whitbeck, David E.

2006-01-01

The Lamoreux Potential Evapotranspiration (LXPET) Program computes potential evapotranspiration (PET) using inputs from four different meteorological sources: temperature, dewpoint, wind speed, and solar radiation. PET and the same four meteorological inputs are used with precipitation data in the Hydrological Simulation Program-Fortran (HSPF) to simulate streamflow in the Salt Creek watershed, DuPage County, Illinois. Streamflows from HSPF are routed with the Full Equations (FEQ) model to determine water-surface elevations. Consequently, variations in meteorological inputs have potential to propagate through many calculations. Sensitivity of PET to variation was simulated by increasing the meteorological input values by 20, 40, and 60 percent and evaluating the change in the calculated PET. Increases in temperatures produced the greatest percent changes, followed by increases in solar radiation, dewpoint, and then wind speed. Additional sensitivity of PET was considered for shifts in input temperatures and dewpoints by absolute differences of ?10, ?20, and ?30 degrees Fahrenheit (degF). Again, changes in input temperatures produced the greatest differences in PET. Sensitivity of streamflow simulated by HSPF was evaluated for 20-percent increases in meteorological inputs. These simulations showed that increases in temperature produced the greatest change in flow. Finally, peak water-surface elevations for nine storm events were compared among unmodified meteorological inputs and inputs with values predicted 6, 24, and 48 hours preceding the simulated peak. Results of this study can be applied to determine how errors specific to a hydrologic system will affect computations of system streamflow and water-surface elevations.

Individual birds advance offspring hatching in response to increased temperature after the start of laying.

PubMed

Vedder, Oscar

2012-11-01

In seasonally reproducing organisms, timing reproduction to match food availability is key to individual fitness. Ambient temperature functions as an important cue for the timing of the food peak in temperate-zone birds. After laying start, individual birds may still improve synchrony between offspring hatching and food availability by adjusting the onset of incubation to most up-to-date cues about the development of the food source. However, it is unknown whether individuals respond to changes in temperature after the onset of laying, and whether individuals adjust incubation onset independent of clutch size. Here, I show in free-living blue tits (Cyanistes caeruleus) that experimental heating of nestboxes in the laying phase resulted in increased duration of nocturnal incubation bouts prior to clutch completion, leading to earlier hatching of eggs and increased hatching asynchrony. Experimental heating did not affect the number of laying gaps, egg volume and clutch size, nor were any carry-over effects on offspring detected. These results are best explained as a response to increased temperature acting as a cue for an advanced food-peak, rather than a relief of energetic constraints, because improved energetic conditions would not favour more hatching asynchrony. Other benefits cannot be excluded, since increased laying-phase incubation under warmer conditions may also help maintain egg viability. This study is the first to show that temperature has a causal effect on the time between clutch completion and hatching of the first offspring, indicating that behavioural adjustment to climate change can continue after laying start.

Magnetic and transport properties of amorphous Ce-Al alloy

NASA Astrophysics Data System (ADS)

Amakai, Yusuke; Murayama, Shigeyuki; Momono, Naoki; Takano, Hideaki; Kuwai, Tomohiko

2018-05-01

Amorphous (a-)Ce50Al50 has been prepared by DC high-rate sputter method. The structure of the obtained sample has been confirmed to have an amorphous structure because there are no Bragg peaks in the X-ray diffraction measurement and have a clear exothermic peak by the differential scanning calorimetry measurement. We have measured the resistivity ρ, magnetic susceptibility χ, specific heat Cp and thermoelectric power S for a-Ce50Al50. The temperature dependence of ρ exhibits a small temperature dependence less than 10% in the whole temperature region. χ follows a Curie-Weiss behavior in the high-temperature region of T>90 K. The effective paramagnetic moment peff, estimated from C is 2.18 μB/Ce-atom. The low-temperature Cp/T increases rapidly with decreasing temperature and tends to a saturation. S(T) exhibits negative values in a wide temperature region. A minimum of S appear at around 60 K, and S decreases linearly with decreasing temperature down to 10 K. The low-temperature S is almost 0 μV/K down to 2 K. From these results, we have pointed out that present a-Ce50Al50 would be an incoherent Kondo material.

The stress relaxation of cement clinkers under high temperature

NASA Astrophysics Data System (ADS)

Wang, Xiufang; Bao, Yiwang; Liu, Xiaogen; Qiu, Yan

2015-12-01

The energy consumption of crushing is directly affected by the mechanical properties of cement materials. This research provides a theoretical proof for the mechanism of the stress relaxation of cement clinkers under high temperature. Compression stress relaxation under various high temperatures is discussed using a specially developed load cell, which can measure stress and displacement under high temperatures inside an autoclave. The cell shows that stress relaxation dramatically increases and that the remaining stress rapidly decreases with an increase in temperature. Mechanical experiments are conducted under various temperatures during the cooling process to study the changes in the grinding resistance of the cement clinker with temperature. The effects of high temperature on the load-displacement curve, compressive strength, and elastic modulus of cement clinkers are systematically studied. Results show that the hardening phenomenon of the clinker becomes apparent with a decrease in temperature and that post-peak behaviors manifest characteristics of the transformation from plasticity to brittleness. The elastic modulus and compressive strength of cement clinkers increase with a decrease in temperature. The elastic modulus increases greatly when the temperature is lower than 1000 °C. The compressive strength of clinkers increases by 73.4% when the temperature drops from 1100 to 800 °C.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryota Ochiai; M. Azhar Uddin; Eiji Sasaoka

The effect of the presence of HCl and SO{sub 2} in the simulated coal combustion flue gas on the Hg{sup 0} removal by a commercial activated carbon (coconut shell AC) was investigated in a laboratory-scale fixed-bed reactor in a temperature range of 80-200{sup o}C. The characteristics (thermal stability) of the mercury species formed on the sorbents under various adsorption conditions were investigated by the temperature-programmed decomposition desorption (TPDD) technique. It was found that the presence of HCl and SO{sub 2} in the flue gas affected the mercury removal efficiency of the sorbents as well as the characteristics of the mercurymore » adsorption species. The mercury removal rate of AC increased with the HCl concentration in the flue gas. In the presence of HCl and the absence of SO{sub 2} during Hg{sup 0} adsorption by AC, a single Hg{sup 0} desorption peak at around 300{sup o}C was observed in the TPDD spectra and intensity of this peak increased with the HCl concentration during mercury adsorption. The peak at around 300{sup o}C may be derived from the decomposition and desorption of mercury chloride species. The presence of SO{sub 2} during mercury adsorption had an adverse effect on the mercury removal by AC in the presence of HCl. In the presence of both HCl and SO{sub 2} during Hg{sup 0} adsorption by AC, the major TPDD peak temperatures changed drastically depending upon the concentration of HCl and SO{sub 2} in flue gas during Hg{sup 0} adsorption. 16 refs., 7 figs.« less

Taking the temperature of Earth's hottest crust

NASA Astrophysics Data System (ADS)

Korhonen, F. J.; Clark, C.; Brown, M.; Taylor, R. J. M.

2014-12-01

The limitations of conventional thermobarometry and petrogenetic grids for determining the peak P- T conditions of granulites are well known. These limitations have been overcome during the past decade with the calibration of single mineral thermometers, particularly Al-in-orthopyroxene, Zr-in-rutile and Ti-in-zircon, and the increased use of P- T pseudosection thermobarometry. Most recent studies of ultrahigh temperature (UHT) granulites (those formed at >900 °C) have used one or other of these methods to argue for peak metamorphic temperatures up to or beyond 1000 °C. Since models for the thermal evolution of orogens generally do not predict such extreme temperatures it is important to confirm their veracity. Here we combine in a single study single mineral thermometry with P- T pseudosection thermobarometry to provide a robust determination of peak temperature and tight constraints on the retrograde P- T path for one UHT granulite locality in the Eastern Ghats Province. This is the first study to apply the most recent update of the internally consistent thermodynamic dataset of Holland and Powell (2011) and the re-parameterized a- x models of White et al. (2014) and Wheller and Powell (2014) to UHT granulites. For two samples, we report Zr-in-rutile temperatures of >1000 °C and Ti-in-zircon temperatures of ∼900 °C, supported by Al-in-orthopyroxene temperatures of ∼900 °C, that correspond closely to those estimated using P- T pseudosections for conditions at the thermal peak and at the solidus on the retrograde P- T path, respectively. The P- T path is counter-clockwise in common with other UHT granulite localities in the Eastern Ghats Province. By demonstrating that UHT metamorphism at T > 1000 °C is real we provide a robust constraint that must be met by geodynamic models for the development of ultrahot orogens.

Thermal Peak Management Using Organic Phase Change Materials for Latent Heat Storage in Electronic Applications

PubMed Central

Maxa, Jacob; Novikov, Andrej; Nowottnick, Mathias

2017-01-01

Modern high power electronics devices consists of a large amount of integrated circuits for switching and supply applications. Beside the benefits, the technology exhibits the problem of an ever increasing power density. Nowadays, heat sinks that are directly mounted on a device, are used to reduce the on-chip temperature and dissipate the thermal energy to the environment. This paper presents a concept of a composite coating for electronic components on printed circuit boards or electronic assemblies that is able to buffer a certain amount of thermal energy, dissipated from a device. The idea is to suppress temperature peaks in electronic components during load peaks or electronic shorts, which otherwise could damage or destroy the device, by using a phase change material to buffer the thermal energy. The phase change material coating could be directly applied on the chip package or the PCB using different mechanical retaining jigs.

Annealing Temperature Dependent Structural and Optical Properties of RF Sputtered ZnO Thin Films.

PubMed

Sharma, Shashikant; Varma, Tarun; Asokan, K; Periasamy, C; Boolchandani, Dharmendar

2017-01-01

This work investigates the effect of annealing temperature on structural and optical properties of ZnO thin films grown over Si 100 and glass substrates using RF sputtering technique. Annealing temperature has been varied from 300 °C to 600 °C in steps of 100, and different microstructural parameters such as grain size, dislocation density, lattice constant, stress and strain have been evaluated. The structural and surface morphological characterization has been done using X-ray Diffraction (XRD) and Scanning Electron Microscope (SEM). XRD analysis reveals that the peak intensity of 002 crystallographic orientation increases with increased annealing temperature. Optical characterization of deposited films have been done using UV-Vis-NIR spectroscopy and photoluminescence spectrometer. An increase in optical bandgap of deposited ZnO thin films with increasing annealing temperature has been observed. The average optical transmittance was found to be more than 85% for all deposited films. Photoluminiscense spectra (PL) suggest that the crystalline quality of deposited film has increased at higher annealing temperature.

Distinguishing magnetic blocking and surface spin-glass freezing in nickel ferrite nanoparticles

NASA Astrophysics Data System (ADS)

Nadeem, K.; Krenn, H.; Traussing, T.; Letofsky-Papst, I.

2011-01-01

Nickel ferrite nanoparticles dispersed in SiO2 matrix have been synthesized by sol-gel method. Structural analysis has been performed by using x-ray diffraction and transmission electron microscopy. Magnetic properties have been investigated by using superconducting quantum interference device magnetometry. In addition to the average blocking temperature peak at TB=120 K measured by a zero field cooled temperature scan of the dc susceptibility, an additional hump near 15 K is observed. Temperature dependent out-of-phase ac susceptibility shows the same features: one broad peak at high temperature and a second narrow peak at low temperature. The high temperature peak corresponds to magnetic blocking of individual nanoparticles, while the low temperature peak is attributed to surface spin-glass freezing which becomes dominant for decreasing particle diameter. To prove the dynamics of the spin (dis)order in both regimes of freezing and blocking, the frequency dependent ac susceptibility is investigated under a biasing dc field. The frequency shift in the "frozen" low-temperature ac susceptibility peak is fitted to a dynamic scaling law with a critical exponent zv=7.5, which indicates a spin-glass phase. Exchange bias is turned on at low temperature which signifies the existence of a strong core-shell interaction. Aging and memory effects are further unique fingerprints of a spin-glass freezing on the surface of isolated magnetic nanoparticles.

Evolution of ionosphere-thermosphere (IT) parameters in the cusp region related to ion upflow events

NASA Astrophysics Data System (ADS)

Kervalishvili, Guram; Lühr, Hermann

2017-04-01

In this study we investigate the relationships of various IT parameters with the intensity of vertical ion flow. Our study area is the ionospheric cusp region in the northern hemisphere. The approach uses superposed epoch analysis (SEA) method, centered alternately on peaks of the three different variables: neutral density enhancement, vertical plasma flow, and electron temperature. Further parameters included are large-scale field-aligned currents (LSFACs) and thermospheric zonal wind velocity profiles over magnetic latitude (MLat), which are centered at the event time and location. The dependence on the interplanetary magnetic field (IMF) By component orientation and the local (Lloyd) season is of particular interest. Our investigations are based on CHAMP and DMSP (F13 and F15) satellite observations and the OMNI online database collected during the years 2002-2007. The three Lloyd seasons of 130 days each are defined as follows: local winter (1 January ± 65 days), combined equinoxes (1 April and 1 October ± 32 days), and local summer (1 July ± 65 days). A period of 130 days corresponds to the time needed by CHAMP to sample all local times. The SEA MLat profiles with respect to neutral density enhancement and vertical plasma flow peaks show no significant but only slight (decreasing towards local summer) seasonal variations for both IMF By orientations. The latitude profiles of median LSFACs show a clear dependence on the IMF By orientation. As expected, the maximum and minimum values of LSFAC amplitudes are increasing towards local summer for both IMF By signs. With respect to zero epoch latitude, FAC peaks appear equatorward (negative MLat) related to Region 1 (R1) and poleward (positive MLat) to Region 0 (R0) FACs. However, there is an imbalance between the amplitudes of LSFACs, depending on the current latitude. R1 currents are systematically stronger than R0 FACs. A somewhat different distribution of density enhancements and large-scale FACs emerges when the SEA is centered on electron temperature peaks. As expected, the background electron temperature increases towards summer and shows no dependence on the IMF By orientation. In contrast to the previous sorting the mass density enhancement shows a dependence on the IMF By sign and increases towards local summer in case of IMF By<0. As before LSFAC peak values are increasing towards local summer, but there is no clear latitudinal profile of upward and downward FACs. We think that intense precipitation of soft electrons (<100 eV) cause the electron temperature enhancement in the cusp region. But there is no direct dependence on the FAC intensity. But for neutral density enhancement and vertical plasma flow the combination of Joule heating and soft electron precipitation, causing electron temperature and conductivity enhancements, are required.

Strong photoluminescence characteristics of sulforhodamine B attached on photonic crystal

NASA Astrophysics Data System (ADS)

Kim, Byoung-Ju; Kang, Kwang-Sun

2014-10-01

The optical properties of sulforhodamine B (SRH) impregnated in photonic crystal by two step synthetic processes including a urethane bond formation between a 3-isocyanatopropyl triethoxysilane (ICPTES, -N=C=O) and a SRH with elevated temperature in pyridine and hydrolysis-condensation reactions between synthesized ICPTES/SRH (ICPSRH) and tetraethoxyorthosilicate (TEOS) in NH4OH. The monodisperse silica spheres impregnated the ICPSRH (ICPSRHS) are fabricated. The reduction of the absorption peak at 2270 cm-1 representing asymmetric stretching vibration of -N=C=O indicates the progress of the reaction and new absorption peak at 1712 cm-1 characterizing -C=O stretching vibration indicates the formation of urethane bond. The UV-visible absorption spectra show the broadened spectral line width by intermolecular interaction. The photoluminescence (PL) peak of the SRH in methanol shows a hypsochromic shift with the increase the excitation wavelength. However, the PL peak for the ICPSRH exhibits a bathochromic shift as the excitation wavelength increases. The PL peak for the ICPSRH shows no hypsochromic or bathochromic shift. The PL peaks for SRH in methanol, ICPSRH and ICPSRHS are at 568, 598 and 572 nm, respectively. The main cause of the PL peak shift is due to the intermolecular interaction.

Resonant tunneling with high peak to valley current ratio in SiO{sub 2}/nc-Si/SiO{sub 2} multi-layers at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, D. Y., E-mail: cdy7659@126.com; Nanjing University of posts and Telecommunications, Nanjing 210046; Sun, Y.

We have investigated carrier transport in SiO{sub 2}/nc-Si/SiO{sub 2} multi-layers by room temperature current-voltage measurements. Resonant tunneling signatures accompanied by current peaks are observed. Carrier transport in the multi-layers were analyzed by plots of ln(I/V{sup 2}) as a function of 1/V and ln(I) as a function of V{sup 1/2}. Results suggest that besides films quality, nc-Si and barrier sub-layer thicknesses are important parameters that restrict carrier transport. When thicknesses are both small, direct tunneling dominates carrier transport, resonant tunneling occurs only at certain voltages and multi-resonant tunneling related current peaks can be observed but with peak to valley current ratiomore » (PVCR) values smaller than 1.5. When barrier thickness is increased, trap-related and even high field related tunneling is excited, causing that multi-current peaks cannot be observed clearly, only one current peak with higher PVCR value of 7.7 can be observed. While if the thickness of nc-Si is large enough, quantum confinement is not so strong, a broad current peak with PVCR value as high as 60 can be measured, which may be due to small energy difference between the splitting energy levels in the quantum dots of nc-Si. Size distribution in a wide range may cause un-controllability of the peak voltages.« less

Effect of potassium perfluorooctanesulfonate, perfluorooctanoate and octanesulfonate on the phase transition of dipalmitoylphosphatidylcholine (DPPC) bilayers

PubMed Central

Xie, W.; Kania-Korwel, I.; Bummer, P. M.; Lehmler, H.-J.

2007-01-01

Summary Perfluorooctanesulfonic acid (PFOS) is a persistent environmental pollutant that may cause adverse effects by inhibiting pulmonary surfactant. To gain further insights in this potential mechanism of toxicity, we investigated the interaction of PFOS potassium salt with dipalmitoylphosphatidylcholine (DPPC) – the major component of pulmonary surfactant – using steady-state fluorescence anisotropy spectroscopy and DSC (differential scanning calorimetry). In addition, we investigated the interactions of two structurally related compounds, perfluorooctanoic acid (PFOA) and octanesulfonic acid (OS) potassium salt, with DPPC. In the fluorescence experiments a linear depression of the main phase transition temperature of DPPC (Tm) and an increased peak width was observed with increasing concentration of all three compounds, both using 1,6-diphenyl-1,3,5-hexatriene (DPH) and 1-(4-trimethylammoniumphenyl)-6-phenyl-1,3,5-hexatriene p-toluenesulfonate (TMA-DPH) as fluorescent probes. PFOS caused an effect on Tm and peak width at much lower concentrations because of its increased tendency to partition onto DPPC bilayers, i.e., the partition coefficients decrease in the K(PFOS) > K(PFOA) ≫ K(OS). Similar to the fluorescence anisotropy measurements, all three compounds caused a linear depression in the onset of the main phase transition temperature and a significant peak broadening in the DSC experiments, with PFOS having the most pronounced effect of the peak width. The effect of PFOS and other fluorinated surfactants on DPPC in both mono- and bilayers may be one mechanism by which these compounds causes adverse biological effects. PMID:17349969

DOE Office of Scientific and Technical Information (OSTI.GOV)

Friedmann, T.A.; Tallant, D.R.; Barbour, J.C.

Carbon Nitride (CN{sub x}) films have been grown by ion-assisted pulsed-laser deposition (IAPLD). Graphite targets were laser ablated while bombarding the substrate with ions from a broad-beam Kaufman-type ion source. Ion voltage, current density, substrate temperature, and feed gas composition (N{sub 2} in Ar) were varied. Resultant films were characterized by Raman. Fourier transform infrared (FTIR), and Rutherford back scattering (RBS) spectroscopy. Samples with {approximately} 30% N/C ratio have been fabricated. The corresponding Raman and FTIR spectra indicate that nitrogen is incorporated into the samples by insertion into sp{sup 2}-bonded structures. A low level of C{identical_to}N triple bonds is alsomore » found. As the ion current and voltage are increased with a pure Ar ion beam, Raman peaks associated with nanocrystalline graphite appear in the spectra. Adding low levels of nitrogen to the ion beam first reduces the Raman intensity in the vicinity of the graphite disorder peak without adding detectable amounts of nitrogen to the films (as measured by RBS). At higher nitrogen levels in the ion beam, significant amounts of nitrogen are incorporated into the samples, and the magnitude of the ``disorder`` peak increases. By increasing the temperature of the substrate during deposition, the broad peak due mainly to sp{sup 2}-bonded C-N in the FTIR spectra is shifted to lower wavenumber. This could be interpreted as evidence of single-bonded C-N; however, it is more likely that the character of the sp{sup 2} bonding is changing.« less

Thermo-Mechanical Effect on Poly Crystalline Boron Nitride Tool Life During Friction Stir Welding (Dwell Period)

NASA Astrophysics Data System (ADS)

Almoussawi, M.; Smith, A. J.

2018-05-01

Poly Crystalline Boron Nitride (PCBN) tool wear during the friction stir welding of high melting alloys is an obstacle to commercialize the process. This work simulates the friction stir welding process and tool wear during the plunge/dwell period of 14.8 mm EH46 thick plate steel. The Computational Fluid Dynamic (CFD) model was used for simulation and the wear of the tool is estimated from temperatures and shear stress profile on the tool surface. Two sets of tool rotational speeds were applied including 120 and 200 RPM. Seven plunge/dwell samples were prepared using PCBN FSW tool, six thermocouples were also embedded around each plunge/dwell case in order to record the temperatures during the welding process. Infinite focus microscopy technique was used to create macrographs for each case. The CFD result has been shown that a shear layer around the tool shoulder and probe-side denoted as thermo-mechanical affected zone (TMAZ) was formed and its size increase with tool rotational speed increase. Maximum peak temperature was also found to increase with tool rotational speed increase. PCBN tool wear under shoulder was found to increase with tool rotational speed increase as a result of tool's binder softening after reaching to a peak temperature exceeds 1250 °C. Tool wear also found to increase at probe-side bottom as a result of high shear stress associated with the decrease in the tool rotational speed. The amount of BN particles revealed by SEM in the TMAZ were compared with the CFD model.

Modelling of peak temperature during friction stir processing of magnesium alloy AZ91

NASA Astrophysics Data System (ADS)

Vaira Vignesh, R.; Padmanaban, R.

2018-02-01

Friction stir processing (FSP) is a solid state processing technique with potential to modify the properties of the material through microstructural modification. The study of heat transfer in FSP aids in the identification of defects like flash, inadequate heat input, poor material flow and mixing etc. In this paper, transient temperature distribution during FSP of magnesium alloy AZ91 was simulated using finite element modelling. The numerical model results were validated using the experimental results from the published literature. The model was used to predict the peak temperature obtained during FSP for various process parameter combinations. The simulated peak temperature results were used to develop a statistical model. The effect of process parameters namely tool rotation speed, tool traverse speed and shoulder diameter of the tool on the peak temperature was investigated using the developed statistical model. It was found that peak temperature was directly proportional to tool rotation speed and shoulder diameter and inversely proportional to tool traverse speed.

Cathodoluminescence of InP

NASA Technical Reports Server (NTRS)

Gatos, C. H.; Vaughan, J. J.; Lagowski, J.; Gatos, H. C.

1981-01-01

Cathodoluminescence studies were carried out on p-type InP having carrier concentrations ranging from 7.2 x 10 to the 16th to 7.4 x 10 to the 18th per cu cm in the temperature range of 80-580 K. It was found that low-temperature spectra exhibited peaks at 1.41 and 1.38 eV. These peaks were attributed to band-to-band and band-acceptor transitions, respectively. The dependence of the band-to-band peak on temperature was used to extend knowledge of the temperature dependence of the energy gap of InP to 550 K. It was shown that the half-width of the cathodoluminescence peak can be used for the determination of carrier concentration and carrier-concentration inhomogeneities in the material. The variations of the cathodoluminescence peak height with temperature indicated the possibility of Auger recombination for high carrier concentrations (7.4 x 10 to the 18th per cu cm) at temperatures above 450 K.

Flux-lattice melting, anisotropy, and the role of interlayer coupling in Bi-Sr-Ca-Cu-O single crystals

NASA Astrophysics Data System (ADS)

Duran, C.; Yazyi, J.; de La Cruz, F.; Bishop, D. J.; Mitzi, D. B.; Kapitulnik, A.

1991-10-01

We have used the high-Q mechanical-oscillator technique to probe the vortex-lattice structure in high-quality Bi-Sr-Ca-Cu-O single crystals over a wide range of magnetic fields (200 Oe to 40 kOe), and relative orientations θ between the magnetic field and the crystalline c^ axis. In addition to the large softening and dissipation peak previously observed and interpreted as due to flux-lattice melting, another distinctly different peak at higher temperatures is seen. The temperatures where the dissipation peaks take place are solely defined by the parallel component of the field cosθ, while the restoring force on the oscillator is due to both field components. We suggest that the two peaks are due to the softening of interplanar coupling at the low-temperature peak, and melting or depinning of the two-dimensional pancake vortices at the higher-temperature peak.

The effect of temperature on amount and structure of motor variability during 2-minute maximum voluntary contraction.

PubMed

Brazaitis, Marius; Skurvydas, Albertas; Pukėnas, Kazimieras; Daniuseviciūtė, Laura; Mickevicienė, Dalia; Solianik, Rima

2012-11-01

In this study, we questioned whether local cooling of muscle or heating involving core and muscle temperatures are the main indicators for force variability. Ten volunteers performed a 2-min maximum voluntary contraction (MVC) of the knee extensors under control (CON) conditions after passive heating (HT) and cooling (CL) of the lower body. HT increased muscle and rectal temperatures, whereas CL lowered muscle temperature but did not affect rectal temperature. During 2-min MVC, peak force decreased to a lower level in HT compared with CON and CL experiments. Greater central fatigue was found in the HT experiment, and there was less in the CL experiment than in the CON experiment. Increased core and muscle temperature increased physiological tremor and the amount and structural complexity of force variability of the exercising muscles, whereas local muscle cooling decreased all force variability variables measured. Copyright © 2012 Wiley Periodicals, Inc.

Effect of annealing on structural, optical, and electrical properties of nickel (Ni)/indium tin oxide (ITO) nanostructures prepared by RF magnetron sputtering

NASA Astrophysics Data System (ADS)

Sobri, M.; Shuhaimi, A.; Hakim, K. M.; Ganesh, V.; Mamat, M. H.; Mazwan, M.; Najwa, S.; Ameera, N.; Yusnizam, Y.; Rusop, M.

2014-06-01

Nickel (Ni)/indium tin oxide (ITO) nanostructures were deposited on glass and silicon (1 1 1) substrates by RF magnetron sputtering using nickel and ITO (In-Sn, 90-10%) targets. The post-deposition annealing has been performed for Ni/ITO films in air. The effect of annealing temperature on the electrical, optical and structural properties of ITO films was studied. We found the appearance of (6 2 2) peak in addition to (4 0 0) and (2 2 2) major peaks, which indicates an enhancement of the film crystallinity at high temperature annealing of 650 °C. The samples show higher transmittance of more than 90% at 470 nm after annealing which is suitable for blue light emitting diode (LED) application. The optical energy bandgap is shifted from 3.51 to 3.65 eV for the Ni/ITO film after annealing at 650 °C. In addition, increasing the annealing temperature improves the film electrical properties. The resistivity value decreases from 3.77 × 10-5 Ω cm to 1.09 × 10-6 Ω cm upon increasing annealing temperature.

Anomalous luminescence phenomena of indium-doped ZnO nanostructures grown on Si substrates by the hydrothermal method

PubMed Central

2012-01-01

In recent years, zinc oxide (ZnO) has become one of the most popular research materials due to its unique properties and various applications. ZnO is an intrinsic semiconductor, with a wide bandgap (3.37 eV) and large exciton binding energy (60 meV) making it suitable for many optical applications. In this experiment, the simple hydrothermal method is used to grow indium-doped ZnO nanostructures on a silicon wafer, which are then annealed at different temperatures (400°C to 1,000°C) in an abundant oxygen atmosphere. This study discusses the surface structure and optical characteristic of ZnO nanomaterials. The structure of the ZnO nanostructures is analyzed by X-ray diffraction, the superficial state by scanning electron microscopy, and the optical measurements which are carried out using the temperature-dependent photoluminescence (PL) spectra. In this study, we discuss the broad peak energy of the yellow-orange emission which shows tendency towards a blueshift with the temperature increase in the PL spectra. This differs from other common semiconductors which have an increase in their peak energy of deep-level emission along with measurement temperature. PMID:22647253

Increasing synchrony of high temperature and low flow in western North American streams: double trouble for coldwater biota?

USGS Publications Warehouse

Arismendi, Ivan; Safeeq, Mohammad; Johnson, Sherri L.; Dunham, Jason B.; Haggerty, Roy

2013-01-01

Flow and temperature are strongly linked environmental factors driving ecosystem processes in streams. Stream temperature maxima (Tmax_w) and stream flow minima (Qmin) can create periods of stress for aquatic organisms. In mountainous areas, such as western North America, recent shifts toward an earlier spring peak flow and decreases in low flow during summer/fall have been reported. We hypothesized that an earlier peak flow could be shifting the timing of low flow and leading to a decrease in the interval between Tmax_w and Qmin. We also examined if years with extreme low Qmin were associated with years of extreme high Tmax_w. We tested these hypotheses using long32 term data from 22 minimally human-influenced streams for the period 1950-2010. We found trends toward a shorter time lag between Tmax_w and Qmin over time and a strong negative association between their magnitudes. Our findings show that aquatic biota may be increasingly experiencing narrower time windows to recover or adapt between these extreme events of low flow and high temperature. This study highlights the importance of evaluating multiple environmental drivers to better gauge the effects of the recent climate variability in freshwaters.

Isomers in the excited state of electron-transferring flavoprotein from Megasphaera elsdenii: spectral resolution from the time-resolved fluorescence spectra.

PubMed

Sato, Kyosuke; Nishina, Yasuzo; Shiga, Kiyoshi; Tanaka, Fumio

2008-02-27

Electron-transferring flavoprotein (Holo-ETF) from Megasphaera elsdenii contains two FAD's, one of which easily dissociates to form Iso-ETF (contains one FAD). Time-resolved fluorescence of FAD in Iso-ETF, and Holo-ETF were measured at 5 degrees C and 25 degrees C. Wavelength-dependent fluorescence decays of the both ETF at 5 degrees C and 25 degrees C were analyzed to resolve them into two independent spectra. It was found that Iso-ETF displayed two spectra with lifetime of 0.605 ns (emission peak, 508 nm) and with lifetime of 1.70 ns (emission peak, 540 nm) at 5 degrees C, and with lifetime of 0.693 ns (emission peak, 508 nm) and with lifetime of 2.75 ns (emission peak, 540 nm) at 25 degrees C. Holo-ETF displayed two spectra with lifetime of 0.739 ns (emission peak, 508 nm) and with lifetime of 2.06 ns (emission peak, 545 nm) at 5 degrees C, and with lifetime of 0.711 ns (emission peak, 527 nm) and with lifetime of 3.08 ns (emission peak, 540 nm) at 25 degrees C. Thus fluorescence lifetimes of every spectrum increased upon elevating temperature. Emission peaks Iso-ETF did not change much upon elevating temperature. Activation enthalpy changes, activation entropy changes and activation Gibbs energy changes of quenching rates all displayed negative. Two emission species in the both ETF may be hydrogen-bonding isomers, because isoalloxazine ring of FAD contains four hydrogen acceptors and one donor.

Magnetic and thermodynamic properties of Nd3NiGe2

NASA Astrophysics Data System (ADS)

Matsumoto, Keisuke T.; Hiraoka, Koichi

2018-05-01

We here report the magnetization, M, and specific heat, C, of Nd3NiGe2 , which crystallizes in the orthorhombic Gd3NiSi2 -type structure. Nd ions occupy three nonequivalent sites in a unit cell. Upon cooling, magnetization divided by magnetic field, M / B , increased sharply at the Curie temperature, TC, of 87 K and below 40 K. The former result indicates that the increase in M / B observed at TC is due to the long-range ferromagnetic order. The increase below 40 K is derived from a short-range correlation because of the absence of clear anomaly in C (T) . At 10 K and 2 K, the values of M undergo metamagnetic transitions. The value of magnetic specific heat divided by temperature shows a shoulder-like anomaly at around 20 K, which is attributed to antiferromagnetic behavior. Furthermore, two peaks in C (T) were observed at 4.5 K and 3.8 K, and these peaks occurred at lower temperatures in the presence of a magnetic field. This behavior is typical of materials with antiferromagnetic order. These observations are attributed to the competition between ferromagnetic and antiferromagnetic interactions, which is a result of the three nonequivalent Nd sites.

Biogenic Methane Generation Potential in the Eastern Nankai Trough, Japan: Effect of Reaction Temperature and Total Organic Carbon

NASA Astrophysics Data System (ADS)

Aung, T. T.; Fujii, T.; Amo, M.; Suzuki, K.

2017-12-01

Understanding potential of methane flux from the Pleistocene fore-arc basin filled turbiditic sedimentary formation along the eastern Nankai Trough is important in the quantitative assessment of gas hydrate resources. We considered generated methane could exist in sedimentary basin in the forms of three major components, and those are methane in methane hydrate, free gas and methane dissolved in water. Generation of biomethane strongly depends on microbe activity and microbes in turn survive in diverse range of temperature, salinity and pH. This study aims to understand effect of reaction temperature and total organic carbon on generation of biomethane and its components. Biomarker analysis and cultural experiment results of the core samples from the eastern Nankai Trough reveal that methane generation rate gets peak at various temperature ranging12.5°to 35°. Simulation study of biomethane generation was made using commercial basin scale simulator, PetroMod, with different reaction temperature and total organic carbon to predict how these effect on generation of biomethane. Reaction model is set by Gaussian distribution with constant hydrogen index and standard deviation of 1. Series of simulation cases with peak reaction temperature ranging 12.5°to 35° and total organic carbon of 0.6% to 3% were conducted and analyzed. Simulation results show that linear decrease in generation potential while increasing reaction temperature. But decreasing amount becomes larger in the model with higher total organic carbon. At higher reaction temperatures, >30°, extremely low generation potential was found. This is due to the fact that the source formation modeled is less than 1 km in thickness and most of formation do not reach temperature more than 30°. In terms of the components, methane in methane hydrate and free methane increase with increasing TOC. Drastic increase in free methane was observed in the model with 3% of TOC. Methane amount dissolved in water shows almost same for all models.

MAVEN observations of dayside peak electron densities in the ionosphere of Mars

NASA Astrophysics Data System (ADS)

Vogt, Marissa F.; Withers, Paul; Fallows, Kathryn; Andersson, Laila; Girazian, Zachary; Mahaffy, Paul R.; Benna, Mehdi; Elrod, Meredith K.; Connerney, John E. P.; Espley, Jared R.; Eparvier, Frank G.; Jakosky, Bruce M.

2017-01-01

The peak electron density in the dayside Martian ionosphere is a valuable diagnostic of the state of the ionosphere. Its dependence on factors like the solar zenith angle, ionizing solar irradiance, neutral scale height, and electron temperature has been well studied. The Mars Atmosphere and Volatile EvolutioN spacecraft's September 2015 "deep dip" orbits, in which the orbital periapsis was lowered to 125 km, provided the first opportunity since Viking to sample in situ a complete dayside electron density profile including the main peak. Here we present peak electron density measurements from 37 deep dip orbits and describe conditions at the altitude of the main peak, including the electron temperature and composition of the ionosphere and neutral atmosphere. We find that the dependence of the peak electron density and the altitude of the main peak on solar zenith angle are well described by analytical photochemical theory. Additionally, we find that the electron temperatures at the main peak display a dependence on solar zenith angle that is consistent with the observed variability in the peak electron density. Several peak density measurements were made in regions of large crustal magnetic field, but there is no clear evidence that the crustal magnetic field strength influences the peak electron density, peak altitude, or electron temperature. Finally, we find that the fractional abundance of O2+ and CO2+ at the peak altitude is variable but that the two species together consistently represent 95% of the total ion density.

Characterizing Climate Controls on Vegetation Seasonality in the North American Southwest

NASA Astrophysics Data System (ADS)

Fish, M. A.; Cook, B.; Smerdon, J. E.; Seager, R.; Williams, P.

2014-12-01

The North American Southwest, which extends from Colorado to southern Mexico and California to eastern Texas, encompasses a diversity of climates, elevations, and ecosystems. This region is expected to experience significant climatic change, and associated impacts, in the coming decades. To better understand the spatiotemporal variability of vegetation in the Southwest and the expected climatic controls on timing and spatial extend of vegetation growth, we compared GIMMS normalized difference vegetation index (NDVI, 1981-2011) against temperature and precipitation data. Spatial variations in vegetation seasonality and the timing of peak NDVI are linked to spatial variability in the precipitation regimes across the Southwest. Regions with spring NDVI peaks are dominated by winter precipitation, while late summer and fall peaks are in regions with significant summer precipitation driven by the North American Monsoon. Inter-annual variability in peak NDVI is positively correlated with precipitation and negatively correlated with temperature, with the largest correlation coefficients at one-month lags. The only significant long-term trends in NDVI are for northern Mexico, where agricultural productivity has been increasing over the last 30 years.

Temperature acclimation rate of aerobic scope and feeding metabolism in fishes: implications in a thermally extreme future

PubMed Central

Sandblom, Erik; Gräns, Albin; Axelsson, Michael; Seth, Henrik

2014-01-01

Temperature acclimation may offset the increased energy expenditure (standard metabolic rate, SMR) and reduced scope for activity (aerobic scope, AS) predicted to occur with local and global warming in fishes and other ectotherms. Yet, the time course and mechanisms of this process is little understood. Acclimation dynamics of SMR, maximum metabolic rate, AS and the specific dynamic action of feeding (SDA) were determined in shorthorn sculpin (Myoxocephalus scorpius) after transfer from 10°C to 16°C. SMR increased in the first week by 82% reducing AS to 55% of initial values, while peak postprandial metabolism was initially greater. This meant that the estimated AS during peak SDA approached zero, constraining digestion and leaving little room for additional aerobic processes. After eight weeks at 16°C, SMR was restored, while AS and the estimated AS during peak SDA recovered partly. Collectively, this demonstrated a considerable capacity for metabolic thermal compensation, which should be better incorporated into future models on organismal responses to climate change. A mathematical model based on the empirical data suggested that phenotypes with fast acclimation rates may be favoured by natural selection as the accumulated energetic cost of a slow acclimation rate increases in a warmer future with exacerbated thermal variations. PMID:25232133

Modeling Cyclic Fatigue Hysteresis Loops of 2D Woven Ceramic Matrix Composites at Elevated Temperatures in Steam

PubMed Central

Li, Longbiao

2016-01-01

In this paper, the cyclic fatigue hysteresis loops of 2D woven SiC/SiC ceramic matrix composites (CMCs) at elevated temperatures in steam have been investigated. The interface slip between fibers and the matrix existing in matrix cracking modes 3 and 5, in which matrix cracking and interface debonding occurred in longitudinal yarns, is considered as the major reason for hysteresis loops of 2D woven CMCs. The hysteresis loops of 2D SiC/SiC composites corresponding to different peak stresses, test conditions, and loading frequencies have been predicted using the present analysis. The damage parameter, i.e., the proportion of matrix cracking mode 3 in the entire matrix cracking modes of the composite, and the hysteresis dissipated energy increase with increasing fatigue peak stress. With increasing cycle number, the interface shear stress in the longitudinal yarns decreases, leading to transition of interface slip types of matrix cracking modes 3 and 5. PMID:28773544

The Evolution of Structural Order as a Measure of Thermal History of Coke in the Blast Furnace

NASA Astrophysics Data System (ADS)

Lundgren, Maria; Khanna, Rita; Ökvist, Lena Sundqvist; Sahajwalla, Veena; Björkman, Bo

2014-04-01

Investigations were carried out on cokes heat treated in the laboratory and on cokes extracted from the experimental blast furnace (EBF) raceway and hearth. X-ray diffraction (XRD) measurements were performed to investigate changes in structural order ( L c), chemical transformations in coke ash along with comparative thermodynamic equilibrium studies and the influence of melt. Three data processing approaches were used to compute L c values as a function of temperature and time and linear correlations were established between L c and heat treatment temperatures during laboratory investigations. These were used to estimate temperatures experienced by coke in various regions of EBF and estimated raceway temperatures were seen to follow the profile of combustion peak. The MgAl2O4 spinel was observed in coke submerged in slag during laboratory studies and in cokes found further into the raceway. Coke in contact with hot metal showed XRD peaks corresponding to presence of Fe3Si. The intensity of SiO2 peak in coke ash was seen to decrease with increasing temperature and disappeared at around 1770 K (1500 °C) due to the formation of SiC. This study has shown that the evolution of structural order and chemical transformations in coke could be used to estimate its thermal history in blast furnaces.

Hantavirus disease (nephropathia epidemica) in Belgium: effects of tree seed production and climate.

PubMed

Tersago, K; Verhagen, R; Servais, A; Heyman, P; Ducoffre, G; Leirs, H

2009-02-01

Recently, human cases of nephropathia epidemica (NE) due to Puumala virus infection in Europe have increased. Following the hypothesis that high reservoir host abundance induces higher transmission rates to humans, explanations for this altered epidemiology must be sought in factors that cause bank vole (Myodes glareolus) abundance peaks. In Western Europe, these abundance peaks are often related to high tree seed production, which is supposedly triggered by specific weather conditions. We evaluated the relationship between tree seed production, climate and NE incidence in Belgium and show that NE epidemics are indeed preceded by abundant tree seed production. Moreover, a direct link between climate and NE incidence is found. High summer and autumn temperatures, 2 years and 1 year respectively before NE occurrence, relate to high NE incidence. This enables early forecasting of NE outbreaks. Since future climate change scenarios predict higher temperatures in Europe, we should regard Puumala virus as an increasing health threat.

Coral mass spawning predicted by rapid seasonal rise in ocean temperature

PubMed Central

Maynard, Jeffrey A.; Edwards, Alasdair J.; Guest, James R.; Rahbek, Carsten

2016-01-01

Coral spawning times have been linked to multiple environmental factors; however, to what extent these factors act as generalized cues across multiple species and large spatial scales is unknown. We used a unique dataset of coral spawning from 34 reefs in the Indian and Pacific Oceans to test if month of spawning and peak spawning month in assemblages of Acropora spp. can be predicted by sea surface temperature (SST), photosynthetically available radiation, wind speed, current speed, rainfall or sunset time. Contrary to the classic view that high mean SST initiates coral spawning, we found rapid increases in SST to be the best predictor in both cases (month of spawning: R2 = 0.73, peak: R2 = 0.62). Our findings suggest that a rapid increase in SST provides the dominant proximate cue for coral mass spawning over large geographical scales. We hypothesize that coral spawning is ultimately timed to ensure optimal fertilization success. PMID:27170709

Temperature influence on the development and loss of seawater tolerance in two fast-growing strains of Atlantic salmon

USGS Publications Warehouse

Handeland, S.O.; Wilkinson, E.; Sveinsbo, B.; McCormick, S.D.; Stefansson, S.O.

2004-01-01

Development of hypo-osmoregulatory ability, gill Na+,K +-ATPase activity, condition factor and growth in Atlantic salmon during parr-smolt transformation was studied in a 2??3 factorial design with three temperatures (12.0, 8.9??C and ambient, 2.4-11.9??C, mean: 6.0??C) and two farmed strains of smolts (Mowi and AquaGen). The development of hypo-osmoregulatory ability and gill Na+,K+-ATPase activity were significantly influenced by freshwater temperature. In smolts raised at 12.0??C, maximum gill Na+,K+-ATPase activity was reached in late April, compared with late May and mid-June in the 8.9??C and ambient groups, respectively. In all groups, peak gill Na+,K +-ATPase activity was seen 350 degree days (d??C) after the onset of the smolt-related increase in enzyme activity (30 March) The period of high enzyme activity (>90% of maximum) lasted approximately 250 d??C. No distinct peak level in gill Na+,K+-ATPase activity was seen in the AquaGen strain at ambient temperature. Elevated temperatures also accelerated the loss of hypo-osmoregulatory capacity. In all groups, gill Na+,K+-ATPase activity reached pre-smolt levels approximately 500 d??C after the calculated peak level. Growth rate in freshwater was influenced by strain, temperature and their interaction, with the Mowi strain showing a higher growth rate than the AquaGen strain at 8.9??C and ambient temperatures. Following transfer to seawater, a higher growth rate was recorded in smolts from the Mowi strain than the AquaGen strain from the ambient temperature regime. Temperature influences the development and loss of smolt characteristics in both strains, and has long-term effects on post-smolt performance in seawater. ?? 2004 Elsevier B.V. All rights reserved.

Effects of extrusion variables on the properties of waxy hulless barley extrudates.

PubMed

Köksel, Hamit; Ryu, Gy-Hyung; Başman, Arzu; Demiralp, Hande; Ng, Perry K W

2004-02-01

The objective of this research was to investigate the extrudability of waxy hulless barley flour under various extrusion conditions. Waxy hulless barley flour was processed in a laboratory-scale corotating twin-screw extruder with different levels of feed moisture content (22.3, 26.8, and 30.7%) and die temperature (130, 150, and 170 degrees C) to develop a snack food with high beta-glucan content. The effects of extrusion condition variables (screw configuration, moisture, and temperature) on the system variables (pressure and specific mechanical energy), the extrudate physical properties (sectional expansion index, bulk density), starch gelatinization, pasting properties (cold peak viscosity, trough viscosity, and final viscosity), and beta-glucan contents were determined. Results were evaluated by using response surface methodology. Increased extrusion temperature and feed moisture content resulted in decreases in exit die pressure and specific mechanical energy values. For extrudates extruded under low shear screw configuration (LS), increased barrel temperature decreased sectional expansion index (SEI) values at both low and high moisture contents. The feed moisture seems to have an inverse relationship with SEI over the range studied. Bulk density was higher at higher moisture contents, for both low and high barrel temperatures, for samples extruded under high shear screw configuration (HS) and LS. Cold peak viscosities (CV) were observed in all samples. The CV increased with the increase in extrusion temperature and feed moisture content. Although beta-glucan contents of the LS extrudates were comparable to that of barley flour sample, HS samples had generally lower beta-glucan contents. The extrusion cooking technique seems to be promising for the production of snack foods with high beta-glucan content, especially using LS conditions.

Raman spectra boron doped amorphous carbon thin film deposited by bias assisted-CVD

NASA Astrophysics Data System (ADS)

Ishak, A.; Fadzilah, A. N.; Dayana, K.; Saurdi, I.; Malek, M. F.; Nurbaya, Z.; Shafura, A. K.; Rusop, M.

2018-05-01

Boron doped amorphous carbon thin film carbon was deposited at 200°C-350°C by bias assisted-CVD using palm oil as a precursor material. The structural boron doped amorphous carbon films were discussed by Raman analysis through the evolution of D and G bands. The spectral evolution observed showed the increase of upward shift of D and G peaks as substrate deposition temperatures increased. These structural changes were further correlated with optical gap and the results obtained are discussed and compared. The estimated optical band gap is found to be 1.9 to 2.05 eV and conductivity is to be in the range of 10-5 Scm-1 to 10-4 Scm-1. The decrease of optical band gap is associated to conductivity increased which change the characteristic parameters of Raman spectra including the position of G peak, full width at half maximum of G peak, and ID/IG.

TL and OSL properties of beta irradiated Y2O3 nanocrystal

NASA Astrophysics Data System (ADS)

Shivaramu, N. J.; Lakshminarasappa, B. N.; Nagabhushana, K. R.; Tatumi, S. H.; Rocca, R. R.; Singh, Fouran

2017-05-01

Nanocrystalline yttrium oxide (Y2O3) is synthesized by low temperature sol-gel technique and synthesized material is annealed at 900°C. The annealed β-rayed Y2O3 two TL glows with prominent peak at 407 K and weak glow peak at 643 K were observed in all irradiated samples. It is found that TL glow peaks intensity linearly increases with increase in β-dose from 0.813 - 40.625 Gy. The TL kinetic parameters are calculated using glow curve deconvoluted (GCD) method. The TL glows exhibits general order kinetics. Intense optical stimulated luminescence (OSL) is observed in the Y2O3 sample. These material exhibits linearity and reproducibility and hence, it suggests that this material may be used as dosimetric applications.

Temperature profiles of patient-applied eyelid warming therapies.

PubMed

Wang, Michael T M; Gokul, Akilesh; Craig, Jennifer P

2015-12-01

To compare temperature profile characteristics (on and off eye) of two patient-applied heat therapies for meibomian gland dysfunction (MGD): an eye mask containing disposable warming units (EyeGiene(®)) and a microwave-heated flaxseed eye bag(®) (MGDRx EyeBag(®)). In vitro evaluation: surface temperature profiles of activated eye masks and heated eye bags(®) (both n=10), were tracked every 10s until return to ambient temperature. Heat-transfer assessment: outer and inner eyelid temperature profiles throughout the eye mask and eye bag(®) treatment application period (10min) were investigated in triplicate. The devices were applied for 12 different time intervals in a randomised order, with a cool-down period in between to ensure ocular temperatures returned to baseline. Temperature measurements were taken before and immediately after each application. In vitro evaluation: on profile, the eye bag(®) surface temperature peaked earlier (0±0 s vs. 100±20 s, p<0.001), cooled more slowly and displayed less variability than the eye mask (all p<0.05). Heat-transfer assessment: the eye bag(®) effected higher peak inner eyelid temperatures (38.1±0.4°C vs. 37.4±0.2°C, p=0.04), as well as larger inner eyelid temperature increases over the first 2 min, and between 9 and 10 min (all p<0.05). The eye bag(®) surface temperature profile displayed greater uniformity and slower cooling than the eye mask, and was demonstrated to be significantly more effective in raising ocular temperatures than the eye mask, both statistically and clinically. This has implications for MGD treatment, where the melting points of meibomian secretions are likely to be higher with increasing disease severity. Copyright © 2015 Elsevier Ltd. All rights reserved.

Metamorphism and aqueous alteration in low petrographic type ordinary chondrites

NASA Technical Reports Server (NTRS)

Xie, T.; Lipschutz, M. E.; Sears, D. W. G.; Guimon, R. K.; Jie, Lu; Benoit, P. H.; O'D. Alexander, C. M.; Wright, Ian; Pillinger, C.; Morse, A. D.;

Comparison of the photothermal effects of 808nm gold nanorod and indocyanine green solutions using an 805nm diode laser

NASA Astrophysics Data System (ADS)

Hasanjee, Aamr M.; Zhou, Feifan; West, Connor; Silk, Kegan; Doughty, Austin; Bahavar, Cody F.; Chen, Wei R.

2016-03-01

Non-invasive laser immunotherapy (NLIT) is a treatment method for metastatic cancer which combines noninvasive laser irradiation with immunologically modified nanostructures to ablate a primary tumor and induce a systemic anti-tumor response. To further expand the development of NLIT, two different photosensitizing agents were compared: gold nanorods (GNR) with an optical absorption peak of 808 nm and indocyanine green (ICG) with an optical absorption peak of ~800 nm. Various concentrations of GNR and ICG solutions were irradiated at different power densities using an 805 nm diode laser, and the temperature of the solutions was monitored during irradiation using a thermal camera. For comparison, dye balls made up of a 1:1 volume ratio of gel solution to GNR or ICG solution were placed in phantom gels and were then irradiated using the 805 nm diode laser to imitate the effect of laser irradiation on in vivo tumors. Non-invasive laser irradiation of GNR solution for 2 minutes resulted in a maximum increase in temperature by 31.8 °C. Additionally, similar irradiation of GNR solution dye ball within phantom gel for 10 minutes resulted in a maximum temperature increase of 8.2 °C. Comparatively, non-invasive laser irradiation of ICG solution for 2 minutes resulted in a maximum increase in temperature by 28.0 °C. Similar irradiation of ICG solution dye ball within phantom gel for 10 minutes yielded a maximum temperature increase of only 3.4 °C. Qualitatively, these studies showed that GNR solutions are more effective photosensitizing agents than ICG solution.

Precipitate Evolution and Strengthening in Supersaturated Rapidly Solidified Al-Sc-Zr Alloys

NASA Astrophysics Data System (ADS)

Deane, Kyle; Kampe, S. L.; Swenson, Douglas; Sanders, P. G.

2017-04-01

Because of the low diffusivities of scandium and zirconium in aluminum, trialuminide precipitates containing these elements have been reported to possess excellent thermal stability at temperatures of 573 K (300 °C) and higher. However, the relatively low equilibrium solubilities of these elements in aluminum limit the achievable phase fraction and, in turn, strengthening contributions from these precipitates. One method of circumventing this limitation involves the use of rapid solidification techniques to suppress the initial formation of precipitates in alloys containing higher solute compositions. This work specifically discusses the fabrication of supersaturated Al-Sc, Al-Zr, and Al-Sc-Zr alloys via melt spinning, in which supersaturations of at least 0.55 at. pct Zr and 0.8 at. pct Sc are shown to be attainable through XRD analysis. The resulting ribbons were subjected to a multistep aging heat treatment in order to encourage a core-shell precipitate morphology, the precipitate evolution behavior was monitored with XRD and TEM, and the aging behavior was observed. While aging in these alloys is shown to follow similar trends to conventionally processed materials reported in literature, with phase fraction increasing until higher aging temperatures causing a competing dissolution effect, the onset of precipitation begins at lower temperatures than previously observed and the peak hardnesses occurred at higher temperature steps due to an increased aging time associated with increased solute concentration. Peaking in strength at a higher temperature doesn't necessarily mean an increase in thermal stability, but rather emphasizes the need for intelligently designed heat treatments to take full advantage of the potential strengthening of supersaturated Al-Sc-Zr alloys.

Seasonal and Interannual Variations of Ice Sheet Surface Elevation at the Summit of Greenland: Observed and Modeled

NASA Technical Reports Server (NTRS)

Zwally, H. Jay; Jun, Li; Koblinsky, Chester J. (Technical Monitor)

2001-01-01

Observed seasonal and interannual variations in the surface elevation over the summit of the Greenland ice sheet are modeled using a new temperature-dependent formulation of firn-densification and observed accumulation variations. The observed elevation variations are derived from ERS (European Remote Sensing)-1 and ERS-2 radar altimeter data for the period between April 1992 and April 1999. A multivariate linear/sine function is fitted to an elevation time series constructed from elevation differences measured by radar altimetry at orbital crossovers. The amplitude of the seasonal elevation cycle is 0.25 m peak-to-peak, with a maximum in winter and a minimum in summer. Inter-annually, the elevation decreases to a minimum in 1995, followed by an increase to 1999, with an overall average increase of 4.2 cm a(exp -1) for 1992 to 1999. Our densification formulation uses an initial field-density profile, the AWS (automatic weather station) surface temperature record, and a temperature-dependent constitutive relation for the densification that is based on laboratory measurements of crystal growth rates. The rate constant and the activation energy commonly used in the Arrhenius-type constitutive relation for firn densification are also temperature dependent, giving a stronger temperature and seasonal amplitudes about 10 times greater than previous densification formulations. Summer temperatures are most important, because of the strong non-linear dependence on temperature. Much of firn densification and consequent surface lowering occurs within about three months of the summer season, followed by a surface build-up from snow accumulation until spring. Modeled interannual changes of the surface elevation, using the AWS measurements of surface temperature and accumulation and results of atmospheric modeling of precipitation variations, are in good agreement with the altimeter observations. In the model, the surface elevation decreases about 20 cm over the seven years due to more compaction driven by increasing summer temperatures. The minimum elevation in 1995 is driven mainly by a temporary accumulation decrease and secondarily by warmer temperatures. However, the overall elevation increase over the seven years is dominated by the accumulation increase in the later years.

Shearing at the end of summer affects body temperature of free-living Angora goats ( Capra aegagrus) more than does shearing at the end of winter.

PubMed

Hetem, R S; de Witt, B A; Fick, L G; Fuller, A; Kerley, G I H; Maloney, S K; Meyer, L C R; Mitchell, D

2009-07-01

Angora goats are known to be vulnerable to cold stress, especially after shearing, but their thermoregulatory responses to shearing have not been measured. We recorded activity, and abdominal and subcutaneous temperatures, for 10 days pre-shearing and post-shearing, in 10 Angora goats inhabiting the succulent thicket of the Eastern Cape, South Africa, in both March (late summer) and September (late winter). Within each season, environmental conditions were similar pre-shearing and post-shearing, but September was an average 5°C colder than March. Shearing resulted in a decreased mean (P < 0.0001), minimum (P < 0.0001) and maximum daily abdominal temperature (P < 0.0001). Paradoxically, the decrease in daily mean (P = 0.03) and maximum (P = 0.01) abdominal temperatures, from pre-shearing to post-shearing, was greater in March than in September. Daily amplitude of body temperature rhythm (P < 0.0001) and the maximum rate of abdominal temperature rise (P < 0.0001) increased from pre-shearing to post-shearing, resulting in an earlier diurnal peak in abdominal temperature (P = 0.001) post-shearing. These changes in amplitude, rate of abdominal temperature rise and time of diurnal peak in abdominal temperature suggest that the goats' thermoregulatory system was more labile after shearing. Mean daily subcutaneous temperatures also decreased post-shearing (P < 0.0001), despite our index goat selecting more stable microclimates after shearing in March (P = 0.03). Following shearing, there was an increased difference between abdominal and subcutaneous temperatures (P < 0.0001) at night, suggesting that the goats used peripheral vasoconstriction to limit heat loss. In addition to these temperature changes, mean daily activity increased nearly two-fold after March shearing, but not September shearing. This increased activity after March shearing was likely the result of an increased foraging time, food intake and metabolic rate, as suggested by the increased water influx (P = 0.0008). Thus, Angora goats entered a heat conservation mode after shearing in both March and September. That the transition from the fleeced to the shorn state had greater thermoregulatory consequences in March than in September may provide a mechanistic explanation for Angora goats' vulnerability to cold in summer.

The shape of CMB temperature and polarization peaks on the sphere

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marcos-Caballero, A.; Fernández-Cobos, R.; Martínez-González, E.

2016-04-01

We present a theoretical study of CMB temperature peaks, including its effect over the polarization field, and allowing nonzero eccentricity. The formalism is developed in harmonic space and using the covariant derivative on the sphere, which guarantees that the expressions obtained are completely valid at large scales (i.e., no flat approximation). The expected patterns induced by the peak, either in temperature or polarization, are calculated, as well as their covariances. It is found that the eccentricity introduces a quadrupolar dependence in the peak shape, which is proportional to a complex bias parameter b {sub ε}, characterizing the peak asymmetry andmore » orientation. In addition, the one-point statistics of the variables defining the peak on the sphere is reviewed, finding some differences with respect to the flat case for large peaks. Finally, we present a mechanism to simulate constrained CMB maps with a particular peak on the field, which is an interesting tool for analysing the statistical properties of the peaks present in the data.« less

Experimental study on the coalescence process of SiO2 supported colloidal Au nanoparticles

NASA Astrophysics Data System (ADS)

Ruffino, F.; Torrisi, V.; Grimaldi, M. G.

2015-11-01

We report on an experimental study of the coalescence-driven grow process of colloidal Au nanoparticles on SiO2 surface. Nanoparticles with 30, 50, 80, 100 nm nominal diameters on a SiO2 substrate were deposited, from solutions, by the drop-casting method. Then, annealing processes, in the 573-1173 K temperature range and 900-3600 s time range, were performed. Using scanning electron microscopy analyses, the temporal evolution of the nanoparticles sizes has been studied. In particular, for all classes of nanoparticles, the experimental-obtained diameters distributions evidenced double-peak shapes (i. e. bimodal distributions): a first peak centered (and unchanged changing the annealing temperature and/or time) at the nominal diameter of the as-deposited nanoparticles, , and a second peak shifting at higher mean diameters, , increasing the annealing temperature and/or time. This observation suggested us a coalescence-driven growth process of a nanoparticles sub-population. As a consequence, the temporal evolution of (for each class of nanoparticles and each annealing temperature), within the well-established particles coalescence theoretical framework, has been analyzed. In particular, by the analyses of the experimental data using relations as prescribed by the theoretical model, a characteristic size-dependent activation energy for the Au nanoparticles coalescence process has been evaluated.

Non-Contact Acousto-Thermal Signatures of Plastic Deformation in TI-6AL-4V

NASA Astrophysics Data System (ADS)

Welter, J. T.; Malott, G.; Schehl, N.; Sathish, S.; Jata, K. V.; Blodgett, M. P.

2010-02-01

Plastic deformation introduces changes in a material which include increases in: dislocations, strains, residual stress, and yield stress. However, these changes have a very small impact on the material properties such as elastic modulus, conductivity and ultrasonic wave speed. This is due to the fact that interatomic forces govern these properties, and they are not affected by plastic deformation to any large degree. This is evident from the fact that the changes in electrical resistance and ultrasonic velocity in plastically deformed and virgin samples are very small and can only be determined by highly controlled experiments. Except for X-ray diffraction, there are no direct nondestructive methods for measuring strain and the residual stress. This paper presents an application of the non-contact acousto-thermal signature (NCATS) NDE methodology to detect plastic deformation in flat dog bone Ti-6Al-4V samples. Results of the NCATS measurements on samples subjected to incremental amounts of plastic deformation are presented. The maximum temperature attained by the sample due to acoustic excitation is found to be sensitive to the amount of plastic strain. It is observed that the temperature induced by acoustic excitation increases to a peak followed by a decrease to failure. The maximum temperature peak occurs at plastic strains of 12-14%. It is observed that there is a correlation between the peak in maximum temperature rise and the strain at the experimentally determined ultimate tensile strength. A microstructural based explanation for this will be presented. The results are discussed in reference to utilizing this technique for detection and evaluation of plastic deformation.

GaInNAs Structures Grown by MBE for High-Efficiency Solar Cells: Final Report; 25 June 1999--24 August 2002

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tu, C. W.

The focus of this work is to improve the quality of GaInNAs by advanced thin-film growth techniques, such as digital-alloy growth techniques and migration-enhanced epitaxy (MEE). The other focus is to further investigate the properties of such materials, which are potentially beneficial for high-efficiency, multijunction solar cells. 400-nm-thick strain-compensated Ga0.92In0.08As/GaN0.03As0.97 short-period superlattices (SPSLs) are grown lattice-matched to GaAs substrates. The photoluminescence (PL) intensity of digital alloys is 3 times higher than that of random alloys at room temperature, and the improvement is even greater at low temperature, by a factor of about 12. The room-temperature PL intensity of the GaInNAsmore » quantum well grown by the strained InAs/GaN0.023As SPSL growth mode is higher by a factor 5 as compare to the continuous growth mode. The SPSL growth method allows for independent adjustment of the In-to-Ga ratio without group III competition. MEE reduces the low-energy tail of PL, and PL peaks become more intense and sharper. The twin peaks photoluminescence of GaNAs grown on GaAs was observed at room temperature. The peaks splitting increase with increase in nitrogen alloy content. The strain-induced splitting of light-hole and heavy-hole bands of tensile-strained GaNAs is proposed as an explanation of such behavior.« less

Effect of dopant on electrical properties of PVA doped NaF polymer electrolyte films

NASA Astrophysics Data System (ADS)

Irfan, Mohammed; Razikha Banu, S.; Manjunath, A.; Mahesh, S. S.

2018-05-01

Polymer electrolyte films of Poly (vinyl alcohol) (PVA) doped with Sodium fluoride (NaF) of different weight ratios (6, 8 and 10 wt %) were prepared by solution casting method. We observed that AC conductivity was found to increase with rise in temperature and frequency with slope S ranging from 0.7 to 0.9. The Correlated Barrier Hopping (CBH) model is used because the value of S is temperature dependent and its value decreases by increasing temperature. The dielectric constant has high values in the low frequency region; this is due to the existence of various types of polarization mechanisms. The X-ray diffraction (XRD) diagram of pure PVA shows a characteristic peak at 2θ=19.490 indicating its semi-crystalline nature. On the incorporation of NaF salt into the polymer, the intensity of peak decreases gradually, suggesting a decrease in the degree of crystallinity of the complex. The CBH model is used to calculate the polaron binding energy (WM), the Hoping distance (R), the minimum hoping distance (Rmin) and the activation energy (Ea) results are discussed.

In-situ cyclic pulse annealing of InN on AlN/Si during IR-lamp-heated MBE growth

NASA Astrophysics Data System (ADS)

Suzuki, Akira; Bungi, Yu; Araki, Tsutomu; Nanishi, Yasushi; Mori, Yasuaki; Yamamoto, Hiroaki; Harima, Hiroshi

2009-05-01

To improve crystal quality of InN, an in-situ cyclic rapid pulse annealing during growth was carried out using infrared-lamp-heated molecular beam epitaxy. A cycle of 4 min growth of InN at 400 °C and 3 s pulse annealing at a higher temperature was repeated 15 times on AlN on Si substrate. Annealing temperatures were 550, 590, 620, and 660 °C. The back of Si was directly heated by lamp irradiation through a quartz rod. A total InN film thickness was about 200 nm. With increasing annealing temperature up to 620 °C, crystal grain size by scanning electron microscope showed a tendency to increase, while widths of X-ray diffraction rocking curve of (0 0 0 2) reflection and E 2 (high) mode peak of Raman scattering spectra decreased. A peak of In (1 0 1) appeared in X-ray diffraction by annealing higher than 590 °C, and In droplets were found on the surface by annealing at 660 °C.

Multiphonon contribution to the polaron formation in cuprates with strong electron correlations and strong electron-phonon interaction

NASA Astrophysics Data System (ADS)

Ovchinnikov, Sergey G.; Makarov, Ilya A.; Kozlov, Peter A.

2017-03-01

In this work dependences of the electron band structure and spectral function in the HTSC cuprates on magnitude of electron-phonon interaction (EPI) and temperature are investigated. We use three-band p-d model with diagonal and offdiagonal EPI with breathing and buckling phonon mode in the frameworks of polaronic version of the generalized tight binding (GTB) method. The polaronic quasiparticle excitation in the system with EPI within this approach is formed by a hybridization of the local multiphonon Franck-Condon excitations with lower and upper Hubbard bands. Increasing EPI leads to transfer of spectral weight to high-energy multiphonon excitations and broadening of the spectral function. Temperature effects are taken into account by occupation numbers of local excited polaronic states and variations in the magnitude of spin-spin correlation functions. Increasing the temperature results in band structure reconstruction, spectral weight redistribution, broadening of the spectral function peak at the top of the valence band and the decreasing of the peak intensity. The effect of EPI with two phonon modes on the polaron spectral function is discussed.

Miscibility of amorphous ZrO2-Al2O3 binary alloy

NASA Astrophysics Data System (ADS)

Zhao, C.; Richard, O.; Bender, H.; Caymax, M.; De Gendt, S.; Heyns, M.; Young, E.; Roebben, G.; Van Der Biest, O.; Haukka, S.

2002-04-01

Miscibility is a key factor for maintaining the homogeneity of the amorphous structure in a ZrO2-Al2O3 binary alloy high-k dielectric layer. In the present work, a ZrO2/Al2O3 laminate thin layer has been prepared by atomic layer chemical vapor deposition on a Si (100) wafer. This layer, with artificially induced inhomogeneity (lamination), enables one to study the change in homogeneity of the amorphous phase in the ZrO2/Al2O3 system during annealing. High temperature grazing incidence x-ray diffraction (HT-XRD) was used to investigate the change in intensity of the constructive interference peak of the x-ray beams which are reflected from the interfaces of ZrO2/Al2O3 laminae. The HT-XRD spectra show that the intensity of the peak decreases with an increase in the anneal temperature, and at 800 °C, the peak disappears. The same samples were annealed by a rapid thermal process (RTP) at temperatures between 700 and 1000 °C for 60 s. Room temperature XRD of the RTP annealed samples shows a similar decrease in peak intensity. Transmission electronic microscope images confirm that the laminate structure is destroyed by RTP anneals and, just below the crystallization onset temperature, a homogeneous amorphous ZrAlxOy phase forms. The results demonstrate that the two artificially separated phases, ZrO2 and Al2O3 laminae, tend to mix into a homogeneous amorphous phase before crystallization. This observation indicates that the thermal stability of ZrO2-Al2O3 amorphous phase is suitable for high-k applications.

Temperature dependent surface and spectral modifications of nano V2O5 films

NASA Astrophysics Data System (ADS)

Manthrammel, M. Aslam; Fatehmulla, A.; Al-Dhafiri, A. M.; Alshammari, A. S.; Khan, Aslam

2017-03-01

Nanocrystalline V2O5 films have been deposited on glass substrates at 300°C substrate temperature using thermal evaporation technique and were subjected to thermal annealing at different temperatures 350, 400, and 550°C. X-ray diffraction (XRD) spectra exhibit sharper and broader characteristic peaks respectively indicating the rearrangement of nanocrystallite phases with annealing temperatures. Other phases of vanadium oxides started emerging with the rise in annealing temperature and the sample converted completely to VO2 (B) phase at 550°C annealing. FESEM images showed an increase in crystallite size with 350 and 400°C annealing temperatures followed by a decrease in crystallite size for the sample annealed at 550°C. Transmission spectra showed an initial redshift of the fundamental band edge with 350 and 400°C while a blue shift for the sample annealed at 550°C, which was in agreement with XRD and SEM results. The films exhibited smart window properties as well as nanorod growth at specific annealing temperatures. Apart from showing the PL and defect related peaks, PL studies also supported the observations made in the transmission spectra.

Global conditions in the solar corona from 2010 to 2017

PubMed Central

Morgan, Huw; Taroyan, Youra

2017-01-01

Through reduction of a huge data set spanning 2010–2017, we compare mean global changes in temperature, emission measure (EM), and underlying photospheric magnetic field of the solar corona over most of the last activity cycle. The quiet coronal mean temperature rises from 1.4 to 1.8 MK, whereas EM increases by almost a factor of 50% from solar minimum to maximum. An increased high-temperature component near 3 MK at solar maximum drives the increase in quiet coronal mean temperature, whereas the bulk of the plasma remains near 1.6 MK throughout the cycle. The mean, spatially smoothed magnitude of the quiet Sun magnetic field rises from 1.6 G in 2011 to peak at 2.0 G in 2015. Active region conditions are highly variable, but their mean remains approximately constant over the cycle, although there is a consistent decrease in active region high-temperature emission (near 3 MK) between the peak of solar maximum and present. Active region mean temperature, EM, and magnetic field magnitude are highly correlated. Correlation between sunspot/active region area and quiet coronal conditions shows the important influence of decaying sunspots in driving global changes, although we find no appreciable delay between changes in active region area and quiet Sun magnetic field strength. The hot coronal contribution to extreme ultraviolet (EUV) irradiance is dominated by the quiet corona throughout most of the cycle, whereas the high variability is driven by active regions. Solar EUV irradiance cannot be predicted accurately by sunspot index alone, highlighting the need for continued measurements. PMID:28740861

Determination of sulfonamides and trimethoprim using high temperature HPLC with simultaneous temperature and solvent gradient.

PubMed

Giegold, Sascha; Teutenberg, Thorsten; Tuerk, Jochen; Kiffmeyer, Thekla; Wenclawiak, Bernd

2008-10-01

A fast HPLC method for the analysis of eight selected sulfonamides (SA) and trimethoprim has been developed with the use of high temperature HPLC. The separation could be achieved in less than 1.5 min on a 50 mm sub 2 microm column with simultaneous solvent and temperature gradient programming. Due to the lower viscosity of the mobile phase and the increased mass transfer at higher temperatures, the separation could be performed on a conventional HPLC system obtaining peak widths at half height between 0.6 and 1.3 s.

Hydrophobicity of silica thin films: The deconvolution and interpretation by Fourier-transform infrared spectroscopy

NASA Astrophysics Data System (ADS)

Saputra, Riza Eka; Astuti, Yayuk; Darmawan, Adi

2018-06-01

This work investigated the synthesis of dimethoxydimethylsilane:tetraethoxysilane (DMDMS:TEOS) silica thin films as well as the effect of DMDMS:TEOS molar ratios and calcination temperature on hydrophobic properties of silica thin films and its correlation with the FTIR spectra behaviour. The silica thin films were synthesized by sol-gel method using combination of DMDMS and TEOS as silica precursors, ethanol as solvent and ammonia as catalyst, with DMDMS and TEOS molar ratio of 10:90, 25:75, 50:50, 75:25 and 90:10. The results showed that DMDMS:TEOS molar ratio had significant impact on the hydrophobic properties of silica thin films coated on a glass surface. Furthermore, the correlation between water contact angle (WCA) and DMDMS:TEOS molar ratio was found to be in a parabolic shape. Concurrently, the maximum apex of the parabola obtained was observed on the DMDMS:TEOS molar ratio of 50:50 for all calcination temperature. It was clearly observed that the silica xerogel exhibiting notable change in relative peak intensities showed FTIR peak splitting of υasymmetric Si-O-Si. To uncover what happened at the FTIR peak, the deconvolution was conducted in Gaussian approach. It was established that the changes in the Gaussian peak component were related to DMDMS:TEOS molar ratios and the calcination temperature that allowed us to tailor the DMDMS:TEOS silica polymer structure model based on the peak intensity ratios. With the increase of DMDMS:TEOS molar ratio, the ratio of (cyclic Si-O-Si)/(linear Si-O-Si) decreased, whilst the ratio of (C-H)/(linear Si-O-Si) increased. Both ratios intersected at DMDMS:TEOS molar ratio of 50:50 with contribution factor ratio of 1:16 and 1:50 for silica xerogel calcined at 300 °C and 500 °C respectively. The importance of this research is the DMDMS:TEOS molar ratio plays an important role in determining the hydrophobic properties of thin films.

The effects of temperature and aeration on the corrosion of A508III low alloy steel in boric acid solutions at 25-95 °C

NASA Astrophysics Data System (ADS)

Xiao, Qian; Lu, Zhanpeng; Chen, Junjie; Yao, Meiyi; Chen, Zhen; Ejaz, Ahsan

2016-11-01

The effects of temperature, solution composition and dissolved oxygen on the corrosion rate and electrochemical behavior of an A508III low alloy steel in boric acid solution with lithium hydroxide at 25-95 °C are investigated. In aerated solutions, increasing the boric acid concentration increases the corrosion rate and the anodic current density. The corrosion rate in deaerated solutions increases with increasing temperature. A corrosion rate peak value is found at approximately 75 °C in aerated solutions. Increasing temperature increases the oxygen diffusion coefficient, decreases the dissolved oxygen concentration, accelerates the hydrogen evolution reaction, and accelerates both the active dissolution and the film forming reactions. Increasing dissolved oxygen concentration does not significantly affect the corrosion rate at 50 and 60 °C, increases the corrosion rate at 70 and 80 °C, and decreases the corrosion rate at 87.5 and 95 °C in a high concentration boric acid solution with lithium hydroxide.

Skin temperature modifies the impact of hypohydration on aerobic performance.

PubMed

Kenefick, R W; Cheuvront, S N; Palombo, L J; Ely, B R; Sawka, M N

2010-07-01

This study determined the effects of hypohydration on aerobic performance in compensable [evaporative cooling requirement (E(req)) < maximal evaporative cooling (E(max))] conditions of 10 degrees C [7 degrees C wet bulb globe temperature (WBGT)], 20 degrees C (16 degrees C WBGT), 30 degrees C (22 degrees C WBGT), and 40 degrees C (27 degrees C WBGT) ambient temperature (T(a)). Our hypothesis was that 4% hypohydration would impair aerobic performance to a greater extent with increasing heat stress. Thirty-two men [22 +/- 4 yr old, 45 +/- 8 ml.kg(-1).min(-1) peak O(2) uptake (Vo(2 peak))] were divided into four matched cohorts (n = 8) and tested at one of four T(a) in euhydrated (EU) and hypohydrated (HYPO, -4% body mass) conditions. Subjects completed 30 min of preload exercise (cycle ergometer, 50% Vo(2 peak)) followed by a 15 min self-paced time trial. Time-trial performance (total work, change from EU) was -3% (P = 0.1), -5% (P = 0.06), -12% (P < 0.05), and -23% (P < 0.05) in 10 degrees C, 20 degrees C, 30 degrees C, and 40 degrees C T(a), respectively. During preload exercise, skin temperature (T(sk)) increased by approximately 4 degrees C per 10 degrees C T(a), while core (rectal) temperature (T(re)) values were similar within EU and HYPO conditions across all T(a). A significant relationship (P < 0.05, r = 0.61) was found between T(sk) and the percent decrement in time-trial performance. During preload exercise, hypohydration generally blunted the increases in cardiac output and blood pressure while reducing blood volume over time in 30 degrees C and 40 degrees C T(a). Our conclusions are as follows: 1) hypohydration degrades aerobic performance to a greater extent with increasing heat stress; 2) when T(sk) is >29 degrees C, 4% hypohydration degrades aerobic performance by approximately 1.6% for each additional 1 degrees C T(sk); and 3) cardiovascular strain from high skin blood flow requirements combined with blood volume reductions induced by hypohydration is an important contributor to impaired performance.

Synthesis of cobalt stearate as oxidant additive for oxo-biodegradable polyethylene

NASA Astrophysics Data System (ADS)

Asriza, Ristika O.; Arcana, I. Made

2015-09-01

Cobalt stearate is an oxidant additives that can initiate a process of degradation in high density polyethylene (HDPE). To determine the effect of cobalt stearate in HDPE, oxo-biodegradable polyethylene film was given an irradiation with UV light or heating at various temperature. After given a heating, the FTIR spectra showed a new absorption peak at wave number 1712 cm-1 indicating the presence of carbonyl groups in polymers, whereas after irradiation with UV light is not visible the presence of this absorption peak. The increase concentration of cobalt stearate added in HDPE and the higher heating temperature, the intensity of the absorption peak of the carbonyl group increased. The increasing intensity of the carbonyl group absorption is caused the presence of damage in the film surface after heating, and this result is supported by analysis the surface properties of the film with using SEM. Biodegradation tests were performed on oxo-biodegradable polyethylene film which has been given heating or UV light with using activated sludge under optimal conditions the growth of microorganisms. After biodegradation, the maximum weight decreased by 23% in the oxo-biodegradable polyethylene film with a cobalt stearate concentration of 0.2% and after heating at a temperature of 75 °C for 10 days, and only 0.69% in the same film after irradiation UV light for 10 days. Based on the results above, cobalt stearate additive is more effective to initiate the oxidative degradation of HDPE when it is initiated by heating compared to irradiation with UV light.

Synthesis of cobalt stearate as oxidant additive for oxo-biodegradable polyethylene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Asriza, Ristika O.; Arcana, I Made, E-mail: arcana@chem.itb.ac.id

Cobalt stearate is an oxidant additives that can initiate a process of degradation in high density polyethylene (HDPE). To determine the effect of cobalt stearate in HDPE, oxo-biodegradable polyethylene film was given an irradiation with UV light or heating at various temperature. After given a heating, the FTIR spectra showed a new absorption peak at wave number 1712 cm{sup −1} indicating the presence of carbonyl groups in polymers, whereas after irradiation with UV light is not visible the presence of this absorption peak. The increase concentration of cobalt stearate added in HDPE and the higher heating temperature, the intensity of themore » absorption peak of the carbonyl group increased. The increasing intensity of the carbonyl group absorption is caused the presence of damage in the film surface after heating, and this result is supported by analysis the surface properties of the film with using SEM. Biodegradation tests were performed on oxo-biodegradable polyethylene film which has been given heating or UV light with using activated sludge under optimal conditions the growth of microorganisms. After biodegradation, the maximum weight decreased by 23% in the oxo-biodegradable polyethylene film with a cobalt stearate concentration of 0.2% and after heating at a temperature of 75 °C for 10 days, and only 0.69% in the same film after irradiation UV light for 10 days. Based on the results above, cobalt stearate additive is more effective to initiate the oxidative degradation of HDPE when it is initiated by heating compared to irradiation with UV light.« less

Temperature-dependent dielectric and energy-storage properties of Pb(Zr,Sn,Ti)O3 antiferroelectric bulk ceramics

NASA Astrophysics Data System (ADS)

Chen, Xuefeng; Liu, Zhen; Xu, Chenhong; Cao, Fei; Wang, Genshui; Dong, Xianlin

2016-05-01

The dielectric and energy-storage properties of Pb0.99Nb0.02[(Zr0.60Sn0.40)0.95Ti0.05]0.98O3 (PNZST) bulk ceramics near the antiferroelectric (AFE)-ferroelectric (FE) phase boundary are investigated as a function of temperature. Three characteristic temperatures T0, TC, T2 are obtained from the dielectric temperature spectrum. At different temperature regions (below T0, between T0 and TC, and above TC), three types of hysteresis loops are observed as square double loop, slim loop and linear loop, respectively. The switching fields and recoverable energy density all first increase and then decrease with increasing temperature, and reach their peak values at ˜T0. These results provide a convenient method to optimize the working temperature of antiferroelectric electronic devices through testing the temperature dependent dielectric properties of antiferroelectric ceramics.

γ-rays irradiation effects on dielectric properties of Ti/Au/GaAsN Schottky diodes with 1.2%N

NASA Astrophysics Data System (ADS)

Teffahi, A.; Hamri, D.; Djeghlouf, A.; Abboun Abid, M.; Saidane, A.; Al Saqri, N.; Felix, J. F.; Henini, M.

2018-06-01

Dielectric properties of As grown and irradiated Ti /Au/GaAsN Schottky diodes with 1.2%N are investigated using capacitance/conductance-voltage measurements in 90-290 K temperature range and 50-2000 kHz frequency range. Extracted parameters are interface state density, series resistance, dielectric constant, dielectric loss, tangent loss and ac conductivity. It is shown that exposure to γ-rays irradiation leads to reduction in effective trap density believed to result from radiation-induced traps annulations. An increase in series resistance is attributed to a net doping reduction. Dielectric constant (ε') shows usual step-like transitions with corresponding relaxation peaks in dielectric loss. These peaks shift towards lower temperature as frequency decrease. Temperature dependant ac conductivity followed an Arrhenius relation with activation energy of 153 meV in the 200-290 K temperature range witch correspond to As vacancy. The results indicate that γ-rays irradiation improves the dielectric and electrical properties of the diode due to the defect annealing effect.

Thermal effect on structure organizations in cobalt-fullerene nanocomposition.

PubMed

Lavrentiev, Vasily; Vacik, Jiri; Naramoto, Hiroshi; Sakai, Seiji

2010-04-01

Effect of deposition temperature (Ts) on structure of Co-C60 nanocomposite (NC) prepared by simultaneous deposition of cobalt and fullerene on sapphire is presented. The NC structure variations with Ts increasing from room temperature (RT) to 400 degrees C have been analyzed using scanning electron microscopy (SEM), atomic force microscopy (AFM) and Raman spectroscopy. AFM and SEM show granule-like structure of the Co-C60 film. The mixture film deposited at RT includes the hills on the surface suggesting accumulation of internal stress during phase separation. Raman spectra show 25 cm(-1) downshift of Ag(2) C60 peak suggesting -Co-C60- polymerization in C60-based matrix of the NC film. Analysis of Raman spectra has revealed existence of amorphous carbon (a-C) in the NC matrix that argues C60 decomposition. The Ts increase to 200 degrees C causes the surface hills smoothing. In parallel, downshift of the Ag(2) peak decreases to 16 cm(-1) that implies more pronounced phase separation and lower -Co-C60- polymerization efficiency. Also, amount of a-C content slightly increases. Further Ts increasing to 400 degrees C changes the NC structure dramatically. AFM shows evident enlargement of the granules. According to Raman spectra the high Ts deposition yields pronounced C60 decomposition increasing the a-C content. Features of a-C Raman peak imply nucleation of graphitic islands at the NC interfaces. Abundant decomposition of C60 in the mixture film deposited at 400 degrees C is referred to cobalt catalytic effect.

Structural characterization of ZnCl2 modified tellurite based glasses

NASA Astrophysics Data System (ADS)

Dhankhar, Sunil; Kundu, R. S.; Punia, R.; Sunita, Parmar, R.; Sanjay, Kishore, N.

2016-05-01

Glass composition 70 TeO2-(30-x) BaO - x ZnCl2; x = 5, 10, 15, 20 and 25 have been prepared by rapid melt quenching technique under controlled atmospheric conditions. Amorphous nature of the samples was confirmed by x-ray diffractogram. The glass transition temperature (Tg) has been determined using differential scanning calorimetry (DSC) and its value is observed to decrease with increase in ZnCl2 content. The peaks in the Raman and FTIR spectra have been estimated by deconvolutation of the spectra and each of deconvoluted spectra exhibits several peaks. IR and Raman spectra of the present glass system indicate that TeO2 exists as TeO3 trigonal pyramidal (tp), TeO4 trigonal bipyramidal (tbp) and TeO6 polyhedra structural units. With increase in zinc halide content, transformation of some of TeO4 structural units into TeO3 structural units is observed Increase in TeO3 structural units shows that non-bridging oxygen contribution increases which confirms the decrease in glass transition temperature.

OH radical kinetics in hydrogen-air mixtures at the conditions of strong vibrational nonequilibrium

NASA Astrophysics Data System (ADS)

Winters, Caroline; Hung, Yi-Chen; Jans, Elijah; Eckert, Zak; Frederickson, Kraig; Adamovich, Igor V.; Popov, Nikolay

2017-12-01

This work presents results of time-resolved, absolute measurements of OH number density, nitrogen vibrational temperature, and translational-rotational temperature in air and lean hydrogen-air mixtures excited by a diffuse filament nanosecond pulse discharge, at a pressure of 100 Torr and high specific energy loading. The main objective of these measurements is to study kinetics of OH radicals at the conditions of strong vibrational excitation of nitrogen, below autoignition temperature. N2 vibrational temperature and gas temperature in the discharge and the afterglow are measured by ns broadband coherent anti-Stokes Raman scattering. Hydroxyl radical number density is measured by laser induced fluorescence, calibrated by Rayleigh scattering. The results show that the discharge generates strong vibrational nonequilibrium in air and H2-air mixtures for delay times after the discharge pulse of up to ~1 ms, with a peak vibrational temperature of T v  ≈  1900 K at T  ≈  500 K. Nitrogen vibrational temperature peaks at 100-200 µs after the discharge pulse, before decreasing due to vibrational-translational relaxation by O atoms (on the time scale of several hundred µs) and diffusion (on ms time scale). OH number density increases gradually after the discharge pulse, peaking at t ~ 100-300 µs and decaying on a longer time scale, until t ~ 1 ms. Both OH rise time and decay time decrease as H2 fraction in the mixture is increased from 1% to 5%. Comparison of the experimental data with kinetic modeling predictions shows that OH kinetics is controlled primarily by reactions of H2 and O2 with O and H atoms generated during the discharge. At the present conditions, OH number density is not affected by N2 vibrational excitation directly, i.e. via vibrational energy transfer to HO2. The effect of a reaction between vibrationally excited H2 and O atoms on OH kinetics is also shown to be insignificant. As the discharge pulse coupled energy is increased, the model predicts transient OH number density overshoot due to the temperature rise caused by N2 vibrational relaxation by O atoms, which may well be a dominant effect in discharges with specific energy loading.

Body temperature changes during simulated bacterial infection in a songbird: fever at night and hypothermia during the day.

PubMed

Sköld-Chiriac, Sandra; Nord, Andreas; Tobler, Michael; Nilsson, Jan-Åke; Hasselquist, Dennis

2015-09-01

Although fever (a closely regulated increase in body temperature in response to infection) typically is beneficial, it is energetically costly and may induce detrimentally high body temperatures. This can increase the susceptibility to energetic bottlenecks and risks of overheating in some organisms. Accordingly, it could be particularly interesting to study fever in small birds, which have comparatively high metabolic rates and high, variable body temperatures. We therefore investigated two aspects of fever and other sickness behaviours (circadian variation, dose dependence) in a small songbird, the zebra finch. We injected lipopolysaccharide (LPS) at the beginning of either the day or the night, and subsequently monitored body temperature, body mass change and food intake for the duration of the response. We found pronounced circadian variation in the body temperature response to LPS injection, manifested by (dose-dependent) hypothermia during the day but fever at night. This resulted in body temperature during the peak response being relatively similar during the day and night. Day-to-night differences might be explained in the context of circadian variation in body temperature: songbirds have a high daytime body temperature that is augmented by substantial heat production peaks during activity. This might require a trade-off between the benefit of fever and the risk of overheating. In contrast, at night, when body temperature is typically lower and less variable, fever can be used to mitigate infection. We suggest that the change in body temperature during infection in small songbirds is context dependent and regulated to promote survival according to individual demands at the time of infection. © 2015. Published by The Company of Biologists Ltd.

Temperature-dependent toxicities of four common chemical pollutants to the marine medaka fish, copepod and rotifer.

PubMed

Li, Adela J; Leung, Priscilla T Y; Bao, Vivien W W; Yi, Andy X L; Leung, Kenneth M Y

2014-10-01

We hypothesize that chemical toxicity to marine ectotherms is the lowest at an optimum temperature (OT) and it exacerbates with increasing or decreasing temperature from the OT. This study aimed to verify this hypothetical temperature-dependent chemical toxicity (TDCT) model through laboratory experiments. Acute toxicity over a range of temperatures was tested on four commonly used chemicals to three marine ectotherms. Our results confirmed that toxicities, in terms of 96-h LC50 (median lethal concentration; for the marine medaka fish Oryzias melastigma and the copepod Tigriopus japonicus) and 24-h LC50 (for the rotifer Brachionus koreanus), were highly temperature-dependent, and varied between test species and between study chemicals. The LC50 value of the fish peaked at 20 °C for copper (II) sulphate pentahydrate and triphenyltin chloride, and at 25 °C for dichlorophenyltrichloroethane and copper pyrithione, and decreased with temperature increase or decrease from the peak (i.e., OT). However, LC50 values of the copepod and the rotifer generally showed a negative relationship with temperature across all test chemicals. Both copepod and rotifer entered dormancy at the lowest temperature of 4 °C. Such metabolic depression responses in these zooplanktons could reduce their uptake of the chemical and hence minimize the chemical toxicity at low temperatures. Our TDCT model is supported by the fish data only, whereas a simple linear model fits better to the zooplankton data. Such species-specific TDCT patterns may be jointly ascribed to temperature-mediated changes in (1) the physiological response and susceptibility of the marine ectotherms to the chemical, (2) speciation and bioavailability of the chemical, and (3) toxicokinetics of the chemical in the organisms.

Nernst and Seebeck effects in HgTe/CdTe topological insulator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yuan; Song, Juntao; Li, Yu-Xian, E-mail: yxli@mail.hebtu.edu.cn

2015-03-28

The Seebeck and Nernst effects in HgTe/CdTe quantum wells are studied using the tight-binding Hamiltonian and the nonequilibrium Green's function method. The Seebeck coefficient, S{sub c}, and the Nernst coefficient, N{sub c}, oscillate as a function of E{sub F}, where E{sub F} is the Fermi energy. The Seebeck coefficient shows peaks when the Fermi energy crosses the discrete transverse channels, and the height of the nth peak of the S{sub c} is [ln2/(1/2 +|n|)] for E{sub F} > 0. For the case E{sub F} < 0, the values of the peaks are negative, but the absolute values of the first five peaks are themore » same as those for E{sub F} > 0. The 6th peak of S{sub c} reaches the value [ln2/1.35] due to a higher density of states. When a magnetic field is applied, the Nernst coefficient appears. However, the values of the peaks for N{sub c} are all positive. For a weak magnetic field, the temperature suppresses the oscillation of the Seebeck and Nernst coefficients but increases their magnitude. For a large magnetic field, because of the highly degenerate Landau levels, the peaks of the Seebeck coefficient at position E{sub F}=−12, 10, 28meV, and Nernst coefficient at E{sub F}=−7, 10meV are robust against the temperature.« less

Synthesis and Thermoluminescence of ZnS:Mn2+ Nanoparticles

NASA Astrophysics Data System (ADS)

Zahedifar, M.; Taghavinia, N.; Aminpour, M.

2007-08-01

The controlled chemical method has been used for synthesis of Mn doped ZnS nanoparticles. Optical absorption studies showed that increasing of surfactant density, from 0.0001 to 0.5 mol/lit., causes the size of nanoparticles to decrease from 4.8 nm to about 3 nm and the band gap width to increase from 4.15 to 4.50 eV. Also increasing the temperature during the synthesis process caused the nanoparticle size to be increased. As a new result we observed a thermoluminescence (TL) glow peak at about 475 K, with its intensity depending on concentration of the Mn dopant. Activation energy of this glow peak was obtained to be about 0.6eV. A discussion of the obtained results is also presented.

DYNAMIC MECHANICAL STUDIES OF IRRADIATED POLYPROPYLENE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sauer, J.A.; Merrill, L.J.; Woodward, A.E.

1962-04-01

The internal friction and the dynamic modulus of isotactic polypropylene samples subject to varying degrees of pile irradiation were studied at low audio frequencies and over the temperature range from 100 to over 400 deg K. The radiation dosages used varied from 5.4 x lO/sup 17/ to 14 x lO/sup 18/ nvt. For irradiation doses up to about 3 x lO/sup 18/ nvt, one observed change is a decrease in the temperature at which the final upswing in damping and drop in modulus occurs, presumably as a result of defects produced in the crystallites by the irradiation. As the irradiationmore » dose increases above 3 x lO/sup 18/ nvt, all evidence of crystallinity is lost, and the internal friction peak which occurs in the neighborhood of 300 deg K and which is associated with the glass transition of the amorphous regions moves to higher temperatures as a result of the increasing chain-stiffening effect due to crosslinking. The secondary loss peak at 250 deg K attributed to the motion of a small number of segraents in the amorphous regions is found to increase in magnitude with increasing dose. The results of density determinations raade before and after irradiation and also after subsequent exposure of the irradiated samples to melting temperatures and of solvent extraction studies of the irradiated samples confirm the simultaneous occurrence of crosslinking and of crystalline degradation upon pile irradiation of polypropylene samples. (auth)« less

Yield and protein quality of thermophilic Bacillus spp. biomass related to thermophilic aerobic digestion of agricultural wastes for animal feed supplementation.

PubMed

Ugwuanyi, J Obeta

2008-05-01

Bacillus spp. responsible for thermophilic aerobic digestion (TAD) of agricultural wastes were studied for their growth rate, yield and protein quality (amino acid profile) under conditions that approximate full-scale waste digestion as pointers to the capacity of TAD to achieve protein enrichment of wastes for reuse in animal feeding. Specific growth rates of the thermophiles varied with temperature and aeration rates. For Bacillus coagulans, the highest specific growth rate was 1.98 muh(-1); for Bacillus licheniformis 2.56 muh(-1) and for Bacillus stearothermophilus 2.63 muh(-1). Molar yield of B. stearothermophilus on glucose increased with temperature to a peak of 0.404 g g(-1) at 50 degrees C before declining. Peak concentration of overflow metabolite (acetate) increased from 10 mmol at 45 degrees C to 34 mmol at 65 degrees C before declining. Accumulation of biomass in all three isolates decreased with increase in temperature while protein content of biomass increased. Highest biomass protein (79%) was obtained in B. stearothermophilus at 70 degrees C. Content of most essential amino acids of the biomass improved with temperature. Amino acid profile of the biomass was comparable to or superior to the FAO standard for SCP intended for use in animal feeding. Culture condition (waste digestion condition) may be manipulated to optimize protein yield and quality of waste digested by TAD for recycling in animal feed.

The dichotomous response of flood and storm extremes to rising global temperatures

NASA Astrophysics Data System (ADS)

Sharma, A.; Wasko, C.

2017-12-01

Rising temperature have resulted in increases in short-duration rainfall extremes across the world. Additionally it has been shown (doi:10.1038/ngeo2456) that storms will intensify, causing derived flood peaks to rise even more. This leads us to speculate that flood peaks will increase as a result, complying with the storyline presented in past IPCC reports. This talk, however, shows that changes in flood extremes are much more complex. Using global data on extreme flow events, the study conclusively shows that while the very extreme floods may be rising as a result of storm intensification, the more frequent flood events are decreasing in magnitude. The study argues that changes in the magnitude of floods are a function of changes in storm patterns and as well as pre-storm or antecedent conditions. It goes on to show that while changes in storms dominate for the most extreme events and over smaller, more urbanised catchments, changes in pre-storm conditions are the driving factor in modulating flood peaks in large rural catchments. The study concludes by providing recommendations on how future flood design should proceed, arguing that current practices (or using a design storm to estimate floods) are flawed and need changing.

Investigation of post-thermal annealing on material properties of Cu-In-Zn-Se thin films

NASA Astrophysics Data System (ADS)

Güllü, H. H.; Parlak, M.

2017-12-01

The Cu-In-Zn-Se thin film was synthesized by changing the contribution of In in chalcopyrite CuInSe2 with Zn. The XRD spectra of the films showed the characteristic diffraction peaks in a good agreement with the quaternary Cu-In-Zn-Se compound. They were in the polycrystalline nature without any post-thermal process, and the main orientation was found to be in the (112) direction with tetragonal crystalline structure. With increasing annealing temperature, the peak intensities in preferred orientation became more pronounced and grain sizes were in increasing behavior from 6.0 to 25.0 nm. The samples had almost the same atomic composition of Cu0.5In0.5ZnSe2. However, EDS results of the deposited films indicated that there was Se re-evaporation and/or segregation with the annealing in the structure of the film. According to the optical analysis, the transmittance values of the films increased with the annealing temperature. The absorption coefficient of the films was calculated as around 105 cm-1 in the visible region. Moreover, optical band gap values were found to be changing in between 2.12 and 2.28 eV depending on annealing temperature. The temperature-dependent dark- and photo-conductivity measurements were carried out to investigate the electrical characteristics of the films.

Physiological plasticity of metabolic rates in the invasive honey bee and an endemic Australian bee species.

PubMed

Tomlinson, Sean; Dixon, Kingsley W; Didham, Raphael K; Bradshaw, S Don

2015-12-01

Seasonal variation in metabolic rate and evaporative water loss as a function of ambient temperature were compared in two species of bees. The endemic blue-banded bee, Amegilla chlorocyanea, is a solitary species that is an important pollinator in the south-west Australian biodiversity hotspot. Responses were compared with the European honeybee, Apis mellifera, naturalised in Western Australia almost 200 years ago. Metabolic rate increased exponentially with temperature to a peak in both species, and then declined rapidly, with unique scaling exponents and peaks for all species-by-season comparisons. Early in the austral summer, Apis was less thermally tolerant than Amegilla, but the positions reversed later in the foraging season. There were also significant exponential increases in evaporative water loss with increasing temperature, and both season and species contributed to significantly different responses. Apis maintained relatively consistent thermal performance of metabolic rate between seasons, but at the expense of increased rates of evaporative water loss later in summer. In contrast, Amegilla had dramatically increased metabolic requirements later in summer, but maintained consistent thermal performance of evaporative water loss. Although both species acclimated to higher thermal tolerance, the physiological strategies underpinning the acclimation differed. These findings may have important implications for understanding the responses of these and other pollinators to changing environments and for their conservation management.

[Effects of PASP-KT-NAA on the grain-filling of maize in different accumulated temperature zones of Hilongjiang Province, Norheast China].

PubMed

Xu, Tian-Jun; Dong, Zhi-Qiang; Gao, Jiao; Chen, Chuan-Xiao; Jiao, Liu; Xie, Zhen-Xing

2013-02-01

Taking the two maize varieties Zhengdan 958 and Fengdan 3 grown on the three accumulated temperature zones (I, II and III) in Heilongjiang Provice as test materials, a field investigation was made in 2010 and 2011 to study the effects of PASP-KT-NAA (PKN), a compound of exogenous plant growth regulators, on the grain filling and yield of the varieties under different environmental temperatures. From zone I to III, the air temperature at the grain filling stage had a decreasing trend, with the average minimum temperature being 12.16, 11.40, and 9.56, respectively. The effective accumulated temperature at the mid-ate amt sae stage of grain filling was too low to be sufficient for grain filling, which severely affected the grain filling process. Applying N, P and K promoted the dry matter accumulation of maize grain and the grain filling rate in the three zones, delayed the peak time (Tmax) of the grain filling rate of Fengdan 3 but advanced that of Zhengdan 958, promoted the growth capacity at peak time of grain filling rate and the maximum grain filling rate of the two varieties, and shortened their active grain filling period. Applying N, P, and K increased the grain yield of the two varieties in the three zones obviously, and, as compared with those in zones I and II , the grain yields of Zhengdan 958 and Fengdan 3 in zone III were increased by 8.2% and 5.1% , and 3.4% and 0.8% , respectively. Therefore, applying N, P and K could help maize utilizing the limited accumulation temperature, improve the grain filling rate, decrease the grain water content, and ultimately, increase the maize yield.

Associations between seasonal meteorological conditions and the daily step count of adults in Yokohama, Japan: Results of year-round pedometer measurements in a large population.

PubMed

Hino, Kimihiro; Lee, Jung Su; Asami, Yasushi

2017-12-01

People's year-round interpersonal step count variations according to meteorological conditions are not fully understood, because complete year-round data from a sufficient sample of the general population are difficult to acquire. This study examined the associations between meteorological conditions and objectively measured step counts using year-round data collected from a large cohort ( N  = 24,625) in Yokohama, Japan from April 2015 to March 2016. Two-piece linear regression analysis was used to examine the associations between the monthly median daily step count and three meteorological indices (mean values of temperature, temperature-humidity index (THI), and net effective temperature (NET)). The number of steps per day peaked at temperatures between 19.4 and 20.7 °C. At lower temperatures, the increase in steps per day was between 46.4 and 52.5 steps per 1 °C increase. At temperatures higher than those at which step counts peaked, the decrease in steps per day was between 98.0 and 187.9 per 1 °C increase. Furthermore, these effects were more obvious in elderly than non-elderly persons in both sexes. A similar tendency was seen when using THI and NET instead of temperature. Among the three meteorological indices, the highest R 2 value with step counts was observed with THI in all four groups. Both high and low meteorological indices discourage people from walking and higher values of the indices adversely affect step count more than lower values, particularly among the elderly. Among the three indices assessed, THI best explains the seasonal fluctuations in step counts.

Raman spectra of Nd/Sn cosubstituted Ba6-3xSm8+2xTi18O54 microwave dielectric ceramics

NASA Astrophysics Data System (ADS)

Wu, S. Y.; Li, Y.; Chen, X. M.

2004-11-01

The Raman spectra and dielectric properties of Nd /Sn cosubstituted Ba6-3xSm8+2xTi18O54 (x =2/3) microwave dielectric ceramics were discussed as the functions of composition and sintering time. The peaks in 753cm-1 were caused by the second order scatter. The peaks in 425 and 403cm-1 became sharper with prolonging sintering time, and this reflected the increased lattice defects. The shoulder peak near 292cm-1 was caused by the octahedral tilt when A site is Nd3+. The Raman shifts in 590, 520, 280, and 232cm-1 indicated no obvious change in position, but all peaks became sharper with prolonging sintering time. This indicated the increased ordering degree of A-site cations. With prolonging sintering time, the Qf factor (Q is the inverse of dielectric loss, tan δ, and f is the resonant frequency) increased, and the temperature coefficient of resonant frequency significantly decreased or became more negative, while the dielectric constant indicated no significant variation.

Wildland Fire Induced Heating of Dome 375 Perma-Con®

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flores, Eugene Michael

AET-1 was tasked by ADEM with determining the temperature rise in the drum contents of drums stored in the Dome 375 Perma-Con® at TA-54 given a wildland fire. The wildland fire causes radiative and convective heating on the Perma-Con® exterior. The wildland fire time histories for the radiative and convective heating environment were provided to AET-1 by EES-16. If the calculated temperature rise results in a drum content temperature over 40 °C, then ADEM desires a design solution to ensure the peak temperature remains below 40 °C. An axi-symmetric FE simulation was completed to determine the peak temperature of themore » contents of a drum stored in the Dome 375 Perma-Con® during a wildland fire event. Three wildland fire time histories for the radiative and convective heat transfer were provided by EES-16 and were inputs for the FE simulation. The maximum drum content temperature reached was found to be 110 °C while using inputs from the SiteG_2ms_4ign_wind_from_west.xlsx time history input and not including the SWB in the model. Including the SWB in the results in a peak drum content temperature of 61 °C for the SiteG_2ms_4ign_wind_from_west.xlsx inputs. EES-16 decided that by using fuel mitigation efforts, such as mowing the grass and shrubs near the Perma-Con® they could reduce the shrub/grass fuel loading near the Perma-Con® from 1.46 kg/m 2 to 0.146 kg/m 2 and by using a less conservative fuel loading for the debris field inside the Dome 375 perimeter, reducing it from 0.58 kg/m2 to 0.058 kg/m 2 in their model. They also greatly increased the resolution of their radiation model and increased the accuracy of their model’s required convergence value. Using this refined input the maximum drum content temperature was found to be 28 °C with no SWB present in the model. Additionally, this refined input model was modified to include worst case emissivity values for the concrete, drum and Perma-Con® interior, along with adding a 91 second long residual radiative heat flux of 2,000 W/m2 to the end of the refined wildland fire input. For this case the maximum drum content temperature was found to be 32 °C. For Rev. 2 of this calculation and additional simulation was run that included a cable fire heat flux on the exterior of the Perma-Con® that was calculated by FP-DO. Including the cable fire heat flux in the model without the SWB resulted in a peak drum content temperature over time of 43 °C. Including the SWB in the simulation with the cable fire heat flux resulted in a peak drum content temperature over time of 35 °C.« less

Supercritical carbon dioxide treatment as a method for polymorph preparation of deoxycholic acid.

PubMed

Tozuka, Yuichi; Kawada, Dai; Oguchi, Toshio; Yamamoto, Keiji

2003-09-16

A new polymorph of deoxycholic acid (DCA) was formed by using a supercritical carbon dioxide treatment. Deoxycholic acid crystals were stored in a pressure vessel purged with carbon dioxide at 12MPa, 60 degrees C for definite intervals. After storage for 1h in supercritical carbon dioxide (SC-CO2), new X-ray diffraction (XRD) peaks, not found in the bulk DCA crystal, were observed at 2theta = 7.4 degrees, 9.7 degrees and 14.0 degrees. The intensities of the new diffraction peaks increased with an increase in storage time, whereas the intensities of the diffraction peaks due to bulk DCA crystal decreased. On the DSC curves, the crystals obtained showed an exothermic peak at around 155 degrees C followed by the melting peak of bulk DCA crystal at 175 degrees C. By the temperature-controlled powder XRD measurement, the crystals obtained were found to be a metastable form of DCA. The polymorphs of DCA have not been reported; therefore, the SC-CO2 treatment would be a peculiar method to obtain a DCA polymorph.

Temperature Evolution of Excitonic Absorptions in Cd(1-x)Zn(x)Te Materials

NASA Technical Reports Server (NTRS)

Quijada, Manuel A.; Henry, Ross

2007-01-01

The studies consist of measuring the frequency dependent transmittance (T) and reflectance (R) above and below the optical band-gap in the UV/Visible and infrared frequency ranges for Cd(l-x),Zn(x),Te materials for x=0 and x=0.04. Measurements were also done in the temperature range from 5 to 300 K. The results show that the optical gap near 1.49 eV at 300 K increases to 1.62 eV at 5 K. Finally, we observe sharp absorption peaks near this gap energy at low temperatures. The close proximity of these peaks to the optical transition threshold suggests that they originate from the creation of bound electron-hole pairs or excitons. The decay of these excitonic absorptions may contribute to a photoluminescence and transient background response of these back-illuminated HgCdTe CCD detectors.

The thermostimulated luminescence of radiation defects in KCl, KBr and KI crystals at elastic and plastic deformation

NASA Astrophysics Data System (ADS)

Shunkeyev, K.; Myasnikova, L.; Barmina, A.; Zhanturina, N.; Sagimbaeva, Sh; Aimaganbetova, Z.; Sergeyev, D.

2017-05-01

The efficiency of radiation defects formation in alkali halide crystals (AHC) was studied by the method of absorption spectroscopy. However, it is not possible to study the deformation-stimulated processes in detail by the absorption spectrum of radiation defects due to the limited sensitivity compared with luminescent spectroscopy. In this regard, thermally stimulated luminescence (TSL) of radiation defects at elastic and plastic deformation was applied in AHC. In the absence of deformation, the dominant peaks in TSL are ≤ft( {X_3^ - } \\right)aca^0-centers. After elastic deformation, low temperature peaks of TSL corresponding to F‧-, VK- and VF-centers became dominant. After plastic deformation, the peaks of TSL corresponding to ≤ft( {X_3^ - } \\right)aca^0-centers became dominant. The elastic deformation contributes to the increase in concentration of low-temperature F‧-, VK- and VF-centers, and the plastic one contributes to that of high temperature ≤ft( {X_3^ - } \\right)aca^0-centers (peaks of TSL in KCl at 360K, in KBr at 365K, in KI at 340K), composed by divacancies created by plastic deformation. At elastic deformation, unrelaxed interstitial halogen atoms are converted into VK- and VF-centers, and due to this fact the long-range interaction is absent, the result of which are the X_3^ - -centers.

Anomalous magnetic behavior of Sm0.8Ca0.2MnO3 nanoparticles.

PubMed

Mogilyansky, D; Fita, I; Wisniewski, A; Markovich, V; Puzniak, R; Gorodetsky, G

2012-11-01

Magnetic properties of compacted Sm0.8Ca0.2MnO3 (SCMO) particles with average particle size of 23-100 nm, prepared by the glycine-nitrate method, have been investigated. It was found that the relative volume of the ferromagnetic phase decreases with decreasing particle size. Curves of field cooled and zero filed cooled magnetization (M(ZFC)) exhibit a bifurcation just below the Curie temperature (T(c) approximately 55-64 K) for all particles studied. The field dependence of M(ZFC) peak follows de Almeida-Thouless line. Both features are characteristic of spin-glasses (SG). Measurements of ac-susceptibility in the temperature range 5-300 K and the frequency range f = 10 Hz-10 kHz show a sharp peak for both real and imaginary components in the vicinity of T(c), apparently attributed to the Hopkinson effect. A second small peak is seemingly associated with antiferromagnetic or ferrimagnetic ordering. Though, for smaller particles both peaks depend on frequency, no shift to higher temperatures with increasing f, characteristic for SG systems, was observed. The dissimilarity in magnetic properties and dynamic characteristics observed for SCMO and for La0.8Ca0.2MnO3 nanoparticles is discussed, taking into account a difference in the width of the band and the strength of double exchange and interparticle interactions.

Disease features in horses with induced equine monocytic ehrlichiosis (Potomac horse fever).

PubMed

Dutta, S K; Penney, B E; Myrup, A C; Robl, M G; Rice, R M

1988-10-01

Fifty-five horses were inoculated IV and/or SC with materials containing Ehrlichia risticii, ie, infected whole blood, buffy coat cells, or cell culture, to study clinical and hematologic features of equine monocytic ehrlichiosis (Potomac horse fever). Major clinical and hematologic features of induced E risticii infection were biphasic increase in rectal temperature with peak increases of 38.9 C and 39.3 C on postinoculation days (PID) 5 and 12, respectively; depression; anorexia; decreased WBC count (maximal decrease of 47% on PID 12); and diarrhea from PID 14 to PID 18. Increased WBC count was an inconsistent feature, with a maximal increase of 51.5% on PID 20. During times of decreased and increased WBC counts, lymphocyte/neutrophil ratios remained fairly constant. However, not all horses had all clinical and hematologic features, and these features were present in different degrees among horses. Increased rectal temperature, depression, anorexia, and decreased WBC count were more consistent features, whereas diarrhea developed in 73% of the horses. Of 55 horses, 39 (71%) had all clinical and hematologic features of the disease (classic disease), whereas 16 (29%) horses did not have greater than or equal to 1 of these features (nonclassic disease). The E risticii titer in the blood (ehrlichemia) was maximum during the peak increase in rectal temperature. In 55 horses, mortality was 9%. Significant differences (P greater than 0.5) in clinical and hematologic features were not detected between horses that survived and those that died of E risticii infection.

Temperature driven structural-memory-effects in carbon nanotubes filled with Fe3C nano crystals

NASA Astrophysics Data System (ADS)

Boi, Filippo S.; Zhang, Xiaotian; Corrias, Anna

2018-02-01

We report the observation of novel temperature-driven structural-memory-effects in carbon nanotubes (CNTs) filled with Fe3C nano-crystals. These structural-transitions were measured by means of temperature (T) dependent x-ray diffraction (XRD) in the T-range from 298 K to 12 K. A clear reversible 2θ-shift in the 002-peak of the graphitic-CNTs-walls is found with the decrease of the temperature. As determined by Rietveld refinement, such 2θ-shift translates in a not previously reported decrease in the value of the CNT graphitic c-axis with the decrease of the temperature (from 298 K to 12 K). Also, a clear reversible 2θ-shift in the 031 and 131 diffraction-peaks of Fe3C is observed within the same T-range. Rietveld refinements confirm the existence of such memory-effect and also reveal a gradual decrease of the 010-axis of Fe3C with the decrease of the temperature. These observations imply that the observed structural-memory-effect is a characteristic of CNTs when Fe3C is the encapsulated ferromagnet. The generality of such memory-effects was further confirmed by additional measurements performed on other types of CNTs characterized by continuous Fe3C-filling. XRD measurements in the T-range from 298 K to 673 K revealed also an unusual reversible decrease of the Fe3C-peak intensities with the increase of the temperature. These observations can have important implications on the magnetic data recording applications of these nanostructures by helping in better understanding the unusual temperature-dependent magnetic instabilities of iron-based nano-crystals which have been recently reported in literature.

Simulating natural light and temperature cycles in the laboratory reveals differential effects on activity/rest rhythm of four Drosophilids.

PubMed

Prabhakaran, Priya M; Sheeba, Vasu

2014-10-01

Recent studies under semi-natural conditions have revealed various unique features of activity/rest rhythms in Drosophilids that differ from those under standard laboratory conditions. An additional afternoon peak (A-peak) has been reported for Drosophila melanogaster and another species D. malerkotliana while D. ananassae exhibited mostly unimodal diurnal activity. To tease apart the role of light and temperature in mediating these species-specific behaviours of four Drosophilid species D. melanogaster, D. malerkotliana, D. ananassae, and Zaprionus indianus we simulated gradual natural light and/or temperature cycles conditions in laboratory. The pattern observed under semi-natural conditions could be reproduced in the laboratory for all the species under a variety of simulated conditions. D. melanogaster and D. malerkotliana showed similar patterns where as D. ananassae consistently exhibited predominant morning activity under almost all regimes. Z. indianus showed clearly rhythmic activity mostly when temperature cycles were provided. We find that gradually changing light intensities reaching a sufficiently high peak value can elicit A-peak in D. melanogaster, D. malerkotliana, and D. ananassae even at mild ambient temperature. Furthermore, we show that high mid-day temperature could induce A-peak in all species even under constant light conditions suggesting that this A-peak is likely to be a stress response.

Core-temperature sensor ingestion timing and measurement variability.

PubMed

Domitrovich, Joseph W; Cuddy, John S; Ruby, Brent C

2010-01-01

Telemetric core-temperature monitoring is becoming more widely used as a noninvasive means of monitoring core temperature during athletic events. To determine the effects of sensor ingestion timing on serial measures of core temperature during continuous exercise. Crossover study. Outdoor dirt track at an average ambient temperature of 4.4°C ± 4.1°C and relative humidity of 74.1% ± 11.0%. Seven healthy, active participants (3 men, 4 women; age  =  27.0 ± 7.5 years, height  =  172.9 ± 6.8 cm, body mass  =  67.5 ± 6.1 kg, percentage body fat  =  12.7% ± 6.9%, peak oxygen uptake [Vo(2peak)]  =  54.4 ± 6.9 mL•kg⁻¹•min⁻¹) completed the study. Participants completed a 45-minute exercise trial at approximately 70% Vo(2peak). They consumed core-temperature sensors at 24 hours (P1) and 40 minutes (P2) before exercise. Core temperature was recorded continuously (1-minute intervals) using a wireless data logger worn by the participants. All data were analyzed using a 2-way repeated-measures analysis of variance (trial × time), Pearson product moment correlation, and Bland-Altman plot. Fifteen comparisons were made between P1 and P2. The main effect of time indicated an increase in core temperature compared with the initial temperature. However, we did not find a main effect for trial or a trial × time interaction, indicating no differences in core temperature between the sensors (P1  =  38.3°C ± 0.2°C, P2  =  38.3°C ± 0.4°C). We found no differences in the temperature recordings between the 2 sensors. These results suggest that assumed sensor location (upper or lower gastrointestinal tract) does not appreciably alter the transmission of reliable and repeatable measures of core temperature during continuous running in the cold.

High-temperature thermoluminescence of anion-deficient alumina and possibilities of its application in high-dose dosimetry

NASA Astrophysics Data System (ADS)

Surdo, A. I.; Milman, I. I.; Abashev, R. M.; Vlasov, M. I.

2014-12-01

Results of studies of the thermoluminescence (TL) of anion-deficient alumina (α-Al2O3 - δ) single crystals and based on them TLD-500 detectors exposed to pulsed X-ray and electron radiation in a wide range of doses D, pulsed dose rates P p , and temperatures are described. The TL responses of α-Al2O3 - δ for continuous and pulsed X-ray irradiation at D = 0.05-150 Gy are compared. Unlike continuous irradiation, in the case of pulsed irradiation at P p ≥ 6 × 106 Gy/s, a linear increase in the TL response as a function of D is registered in the main and "chromium" peaks at 450 and 580 K, respectively, with a decrease in the slope of the dose dependence at D > 2 Gy for the peak at 450 K. It is found that high-dose irradiation (>60 Gy) leads to the formation of a new TL peak at 830 K and the preferential redistribution of the stored light sums into this peak. The dose dependence for the TL peak at 830 K is studied. It is established that it is linear in a super-high dose range of 104 to 6 × 106 Gy at P p = 2.6 × 1011 Gy/s.

Optical properties of metals: Infrared emissivity in the anomalous skin effect spectral region

DOE Office of Scientific and Technical Information (OSTI.GOV)

Echániz, T.; Pérez-Sáez, R. B., E-mail: raul.perez@ehu.es; Tello, M. J.

When the penetration depth of an electromagnetic wave in a metal is similar to the mean free path of the conduction electrons, the Drude classical theory is no longer satisfied and the skin effect becomes anomalous. Physical parameters of this theory for twelve metals were calculated and analyzed. The theory predicts an emissivity peak ε{sub peak} at room temperature in the mid-infrared for smooth surface metals that moves towards larger wavelengths as temperature decreases. Furthermore, the theory states that ε{sub peak} increases with the emission angle but its position, λ{sub peak}, is constant. Copper directional emissivity measurements as well asmore » emissivity obtained using optical constants data confirm the predictions of the theory. Considering the relationship between the specularity parameter p and the sample roughness, it is concluded that p is not the simple parameter it is usually assumed to be. Quantitative comparison between experimental data and theoretical predictions shows that the specularity parameter can be equal to one for roughness values larger than those predicted. An exhaustive analysis of the experimental optical parameters shows signs of a reflectance broad peak in Cu, Al, Au, and Mo around the wavelength predicted by the theory for p = 1.« less

Device and method for determining freezing points

NASA Technical Reports Server (NTRS)

Mathiprakasam, Balakrishnan (Inventor)

1986-01-01

A freezing point method and device (10) are disclosed. The method and device pertain to an inflection point technique for determining the freezing points of mixtures. In both the method and device (10), the mixture is cooled to a point below its anticipated freezing point and then warmed at a substantially linear rate. During the warming process, the rate of increase of temperature of the mixture is monitored by, for example, thermocouple (28) with the thermocouple output signal being amplified and differentiated by a differentiator (42). The rate of increase of temperature data are analyzed and a peak rate of increase of temperature is identified. In the preferred device (10) a computer (22) is utilized to analyze the rate of increase of temperature data following the warming process. Once the maximum rate of increase of temperature is identified, the corresponding temperature of the mixture is located and earmarked as being substantially equal to the freezing point of the mixture. In a preferred device (10), the computer (22), in addition to collecting the temperature and rate of change of temperature data, controls a programmable power supply (14) to provide a predetermined amount of cooling and warming current to thermoelectric modules (56).

The second peak effect and vortex pinning mechanisms in Ba(Fe,Ni)2As2 superconductors

NASA Astrophysics Data System (ADS)

Ghorbani, S. R.; Arabi, H.; Wang, X. L.

2017-09-01

Vortex pinning mechanisms have been studied systematically in BaFe1.9Ni0.1As2 single crystal as a function of temperature and magnetic field. The obtained shielding current density, Js, showed a second peak in the intermediate magnetic field range at high temperatures. The temperature dependence of the shielding current density, Js(T), was analysed within the collective pinning model at different magnetic fields. It was found that the second peak reflects the coexistence of both δl pinning, reflecting spatial variation in the mean free path (l), and δTc pinning, reflecting spatial variation in the superconducting critical temperature (Tc) at low temperature and low magnetic fields in BaFe1.9Ni0.1As2 single crystal. The results clearly show that pinning mechanism effects are strongly temperature and magnetic field dependent, and the second peak effect is more powerful at higher temperatures and magnetic fields. It was also found that the magnetic field mainly controls the pinning mechanism effect.

Mortality of Eggs and Newly Hatched Larvae of Lobesia botrana (Lepidoptera: Tortricidae) Exposed to High Temperatures in the Laboratory.

PubMed

Kiaeian Moosavi, F; Cargnus, E; Pavan, F; Zandigiacomo, P

2017-06-01

The hypothesis that bunch-zone leaf removal reduces infestations of the European grapevine moth, Lobesia botrana (Denis & Schiffermüller) (Lepidoptera: Tortricidae), by increasing egg and larval mortality owing to sunlight exposure was evaluated in the laboratory by subjecting different egg stages (white, red-eyes, and black-head) and newly hatched larvae to high temperatures. Based on temperatures recorded in a northern Italian vineyard on sun-exposed berries belonging to south-west facing bunches, eggs were subjected to constant temperatures of 40 °C and 37 °C for one or two periods of 3 or 6 h, and to 24-h temperature cycle with peak of 40 °C. Larvae were exposed to 24-h high-temperature cycles with peaks of 35, 37, and 40 °C. The results showed partial egg mortality at 40 °C, increasing with exposure hours and periods, and as eggs matured. Egg mortality was not affected by exposure to 37 °C. Larval survival already decreased significantly at 37 °C and was even lower at 40 °C. These laboratory data are in agreement with the hypothesis that temperatures reached by berries exposed to sunlight cause egg and larval mortality. Data on egg and larval susceptibility to high temperatures have also implications for species distribution and effects of climate change. © The Authors 2017. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Ion and Electron Heating Characteristics of Magnetic Re- Connection in Mast Tokamak Merging Experiment

NASA Astrophysics Data System (ADS)

Tanabe, Hiroshi; Inomoto, Michiaki; Ono, Yasushi; Yamada, Takuma; Imazawa, Ryota; Cheng, Chio-Zong

2016-07-01

We present results of recent studies of high power heating of magnetic reconnection, the fundamental process of several astrophysical events such as solar flare, in the Mega Amp Spherical Tokamak (MAST) - the world largest merging experiment. In addition to the previously reported significant reconnection heating up to ˜1keV [1], detailed local profiles of electron and ion temperature have been measured using a ultra-fine 300 channel Ruby- and a 130 channel YAG-Thomson scattering and a new 32 channel ion Doppler tomography diagnostics [2]. 2D profile measurement of electron temperature revealed highly localized heating structure at the X point with the characteristic scale length of 0.02-0.05m0.3T), a thick layer of closed flux surface surrounding the current sheet sustains the temperature profile for longer time than the electron and ion energy relaxation time ˜4-10ms, finally forming triple peak structures of ion and electron temperatures at the X point and in the downstream. While the peak electron temperature at the X point increases with toroidal field, the bulk electron temperature and the ion temperature in the downstream are unaffected. [1] Y. Ono et.al., Plasma Phys. Control. Fusion 54, 124039 (2012) [2] H. Tanabe et. al., Nucl. Fusion 53, 093027 (2013). [3] H. Tanabe et.al., Phys. Rev. Lett. 115, 215004 (2015)

Greater deciduous shrub abundance extends tundra peak season and increases modeled net CO2 uptake.

PubMed

Sweet, Shannan K; Griffin, Kevin L; Steltzer, Heidi; Gough, Laura; Boelman, Natalie T

2015-06-01

Satellite studies of the terrestrial Arctic report increased summer greening and longer overall growing and peak seasons since the 1980s, which increases productivity and the period of carbon uptake. These trends are attributed to increasing air temperatures and reduced snow cover duration in spring and fall. Concurrently, deciduous shrubs are becoming increasingly abundant in tundra landscapes, which may also impact canopy phenology and productivity. Our aim was to determine the influence of greater deciduous shrub abundance on tundra canopy phenology and subsequent impacts on net ecosystem carbon exchange (NEE) during the growing and peak seasons in the arctic foothills region of Alaska. We compared deciduous shrub-dominated and evergreen/graminoid-dominated community-level canopy phenology throughout the growing season using the normalized difference vegetation index (NDVI). We used a tundra plant-community-specific leaf area index (LAI) model to estimate LAI throughout the green season and a tundra-specific NEE model to estimate the impact of greater deciduous shrub abundance and associated shifts in both leaf area and canopy phenology on tundra carbon flux. We found that deciduous shrub canopies reached the onset of peak greenness 13 days earlier and the onset of senescence 3 days earlier compared to evergreen/graminoid canopies, resulting in a 10-day extension of the peak season. The combined effect of the longer peak season and greater leaf area of deciduous shrub canopies almost tripled the modeled net carbon uptake of deciduous shrub communities compared to evergreen/graminoid communities, while the longer peak season alone resulted in 84% greater carbon uptake in deciduous shrub communities. These results suggest that greater deciduous shrub abundance increases carbon uptake not only due to greater leaf area, but also due to an extension of the period of peak greenness, which extends the period of maximum carbon uptake. © 2015 John Wiley & Sons Ltd.

Phase behavior of mixtures of DPPC and POPG.

PubMed

Wiedmann, T; Salmon, A; Wong, V

1993-04-07

The phase relation of dipalmitoylphosphatidylcholine (DPPC) and 1-palmitoyl-2-oleoyl-phosphatidylglycerol (POPG) has been determined by measurement of the endothermic transitions of mixtures of DPPC and POPG in 100 mM NaCl, 50 mM PIPES (pH 7.0). With the use of differential scanning calorimetry, the gel-liquid crystalline phase transitions of pure POPG and DPPC were estimated to be 274 K and 315.8 K, respectively. With mixtures, there was considerable broadening of the endotherms, but there was no evidence of immiscibility. At high and low mole fractions of DPPC, the observed transition regions are not different from that calculated assuming ideal behavior. However in the central region of the phase diagram, there were deviations from both the ideal liquidus and solidus curves. The chemical shift anisotropy of the 13C-labelled carbonyl carbon of pure DPPC was determined as a function of temperature. At 298 K, a broad peak characteristic of axially symmetric motional averaging of the shielding tensor was observed. At a temperature of 300 K, a narrow peak at 173 ppm was superimposed upon the broad peak. The magnitude of the narrow resonance increased with temperature over the range of 300 to 315 K with the spectrum obtained at the latter point almost completely devoid of any broad features. Spectra obtained with a 9:1 mole ratio of DPPC/POPG was very similar to that obtained with pure DPPC. However, with increasing amounts of POPG, both the temperature at which the narrow resonance appeared and the temperature at which only a narrow resonance was observed were reduced. Over the range of 0 to 50 mol % POPG, there was no major change in the width or shape of the spectra which contained only a broad or narrow resonance. Also for mol % of POPG of 20% and less, there was agreement between the temperature at which only the narrow component was observed and the completion of the main phase transition based on the DSC scans. However, at the two higher mol % of 33 and 50%, the temperature at which only the narrow component was observed was lower than the temperature established for the completion of the main phase transition.

North–south polarization of European electricity consumption under future warming

PubMed Central

Wenz, Leonie; Levermann, Anders; Auffhammer, Maximilian

2017-01-01

There is growing empirical evidence that anthropogenic climate change will substantially affect the electric sector. Impacts will stem both from the supply side—through the mitigation of greenhouse gases—and from the demand side—through adaptive responses to a changing environment. Here we provide evidence of a polarization of both peak load and overall electricity consumption under future warming for the world’s third-largest electricity market—the 35 countries of Europe. We statistically estimate country-level dose–response functions between daily peak/total electricity load and ambient temperature for the period 2006–2012. After removing the impact of nontemperature confounders and normalizing the residual load data for each country, we estimate a common dose–response function, which we use to compute national electricity loads for temperatures that lie outside each country’s currently observed temperature range. To this end, we impose end-of-century climate on today’s European economies following three different greenhouse-gas concentration trajectories, ranging from ambitious climate-change mitigation—in line with the Paris agreement—to unabated climate change. We find significant increases in average daily peak load and overall electricity consumption in southern and western Europe (∼3 to ∼7% for Portugal and Spain) and significant decreases in northern Europe (∼−6 to ∼−2% for Sweden and Norway). While the projected effect on European total consumption is nearly zero, the significant polarization and seasonal shifts in peak demand and consumption have important ramifications for the location of costly peak-generating capacity, transmission infrastructure, and the design of energy-efficiency policy and storage capacity. PMID:28847939

North-south polarization of European electricity consumption under future warming.

PubMed

Wenz, Leonie; Levermann, Anders; Auffhammer, Maximilian

2017-09-19

There is growing empirical evidence that anthropogenic climate change will substantially affect the electric sector. Impacts will stem both from the supply side-through the mitigation of greenhouse gases-and from the demand side-through adaptive responses to a changing environment. Here we provide evidence of a polarization of both peak load and overall electricity consumption under future warming for the world's third-largest electricity market-the 35 countries of Europe. We statistically estimate country-level dose-response functions between daily peak/total electricity load and ambient temperature for the period 2006-2012. After removing the impact of nontemperature confounders and normalizing the residual load data for each country, we estimate a common dose-response function, which we use to compute national electricity loads for temperatures that lie outside each country's currently observed temperature range. To this end, we impose end-of-century climate on today's European economies following three different greenhouse-gas concentration trajectories, ranging from ambitious climate-change mitigation-in line with the Paris agreement-to unabated climate change. We find significant increases in average daily peak load and overall electricity consumption in southern and western Europe (∼3 to ∼7% for Portugal and Spain) and significant decreases in northern Europe (∼-6 to ∼-2% for Sweden and Norway). While the projected effect on European total consumption is nearly zero, the significant polarization and seasonal shifts in peak demand and consumption have important ramifications for the location of costly peak-generating capacity, transmission infrastructure, and the design of energy-efficiency policy and storage capacity.

Thermodynamic Properties of a Double Ring-Shaped Quantum Dot at Low and High Temperatures

NASA Astrophysics Data System (ADS)

Khordad, R.; Sedehi, H. R. Rastegar

2018-02-01

In this work, we study thermodynamic properties of a GaAs double ring-shaped quantum dot under external magnetic and electric fields. To this end, we first solve the Schrödinger equation and obtain the energy levels and wave functions, analytically. Then, we calculate the entropy, heat capacity, average energy and magnetic susceptibility of the quantum dot in the presence of a magnetic field using the canonical ensemble approach. According to the results, it is found that the entropy is an increasing function of temperature. At low temperatures, the entropy increases monotonically with raising the temperature for all values of the magnetic fields and it is independent of the magnetic field. But, the entropy depends on the magnetic field at high temperatures. The entropy also decreases with increasing the magnetic field. The heat capacity and magnetic susceptibility show a peak structure. The heat capacity reduces with increasing the magnetic field at low temperatures. The magnetic susceptibility shows a transition between diamagnetic and paramagnetic below for T<4 K. The transition temperature depends on the magnetic field.

Temperature-Dependent Dielectric Properties of Al/Epoxy Nanocomposites

NASA Astrophysics Data System (ADS)

Wang, Zijun; Zhou, Wenying; Sui, Xuezhen; Dong, Lina; Cai, Huiwu; Zuo, Jing; Chen, Qingguo

2016-06-01

Broadband dielectric spectroscopy was carried out to study the transition in electrical properties of Al/epoxy nanocomposites over the frequency range of 1-107 Hz and the temperature range of -20°C to 200°C. The dielectric permittivity, dissipation factor, and electrical conductivity of the nanocomposites increased with temperature and showed an abrupt increase around the glass transition temperature ( T g). The results clearly reveal an interesting transition of the electrical properties with increasing temperature: insulator below 70°C, conductor at about 70°C. The behavior of the transition in electrical properties of the nanocomposites was explored at different temperatures. The presence of relaxation peaks in the loss tangent and electric modulus spectra of the nanocomposites confirms that the chain segmental dynamics of the polymer is accompanied by the absorption of energy given to the system. It is suggested that the temperature-dependent transition of the electric properties in the nanocomposite is closely associated with the α-relaxation. The large increase in the dissipation factor and electric conductivity depends on the direct current conduction of thermally activated charge carriers resulting from the epoxy matrix above T g.

Microstructure Evolution and Mechanical Properties of 2219 Al Alloy During Aging Treatment

NASA Astrophysics Data System (ADS)

Wang, Huimin; Yi, Youping; Huang, Shiquan

2017-04-01

Hardness and tensile properties of 2219 Al alloys were tested at various temperature (150, 165, 175 °C) and subjected to T6 temper heat treatment to identify the peak aging time at various temperature. Microstructure evolution and precipitate behavior were analyzed with transmission electron microscope (TEM), differential scanning calorimetry (DSC) and x-ray diffraction (XRD). It is found that the peak aging time is 24 h at 150 °C and does not vary down to 165 °C. When the aging temperature rise to 175 °C, the peak aging time down to 12 h. Considering the strength and elongation, the optimum aging treatment is at 165 °C for 24 h after the solution treatment at 535 °C for 1.5 h. Compared with that of only water-quenched sample, after aged at 165 °C for 24 h, the tensile strength of the 2219 Al alloy increases from 324.5 to 411.8 MPa, yield strength from 168 to 310.8 MPa, respectively. The improvement in the mechanical performance is mainly attributed to the precipitation strengthening of the GP zones, θ″ and θ' phases.

Results for the Aboveground Configuration of the Boiling Water Reactor Dry Cask Simulator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Durbin, Samuel G.; Lindgren, Eric Richard

The thermal performance of commercial nuclear spent fuel dry storage casks are evaluated through detailed numerical analysis. These modeling efforts are completed by the vendor to demonstrate performance and regulatory compliance. The calculations are then independently verified by the Nuclear Regulatory Commission (NRC). Carefully measured data sets generated from testing of full sized casks or smaller cask analogs are widely recognized as vital for validating these models. Recent advances in dry storage cask designs have significantly increased the maximum thermal load allowed in a cask in part by increasing the efficiency of internal conduction pathways and also by increasing themore » internal convection through greater canister helium pressure. These same canistered cask systems rely on ventilation between the canister and the overpack to convect heat away from the canister to the environment for both above and belowground configurations. While several testing programs have been previously conducted, these earlier validation attempts did not capture the effects of elevated helium pressures or accurately portray the external convection of aboveground and belowground canistered dry cask systems. The purpose of the current investigation was to produce data sets that can be used to test the validity of the assumptions associated with the calculations used to determine steady-state cladding temperatures in modern dry casks that utilize elevated helium pressure in the sealed canister in an aboveground configuration. An existing electrically heated but otherwise prototypic BWR Incoloy-clad test assembly was deployed inside of a representative storage basket and cylindrical pressure vessel that represents a vertical canister system. The symmetric single assembly geometry with well-controlled boundary conditions simplifies interpretation of results. The arrangement of ducting was used to mimic conditions for an aboveground storage configuration in a vertical, dry cask systems with canisters. Transverse and axial temperature profiles were measured for a wide range of decay power and helium cask pressures. Of particular interest was the evaluation of the effect of increased helium pressure on peak cladding temperatures (PCTs) for identical thermal loads. All steady state peak temperatures and induced flow rates increased with increasing assembly power. Peak cladding temperatures decreased with increasing internal helium pressure for a given assembly power, indicating increased internal convection. In addition, the location of the PCT moved from near the top of the assembly to ~1/3 the height of the assembly for the highest (8 bar absolute) to the lowest (0 bar absolute) pressure studied, respectively. This shift in PCT location is consistent with the varying contribution of convective heat transfer proportional with of internal helium pressure.« less

Impact of dry heating on physicochemical properties of corn starch and lysine mixture.

PubMed

Ji, Ying; Yu, Jicheng; Xu, Yongbin; Zhang, Yinghui

2016-10-01

Corn starch was modified with lysine by dry heat treatment and to investigate how they can affect the pasting and structural properties of the treated starches. Dry heating with lysine reduced the pasting temperature and resulting in viscosity increase. The particle size of heated starch-lysine mixture increased, suggesting that starch granules were cross-linked to lysine. After dry heating, the onset temperature, peak temperature and conclusion temperature of corn starch-lysine mixture were lower than those of other starches. The degree of crystallinity decreased for the starch after dry heat treatment while these heated starch samples still have the same X-ray diffraction types as the original starch. Copyright © 2016 Elsevier B.V. All rights reserved.

Electrical characteristics and density of states of thin-film transistors based on sol-gel derived ZnO channel layers with different annealing temperatures

NASA Astrophysics Data System (ADS)

Wang, S.; Mirkhani, V.; Yapabandara, K.; Cheng, R.; Hernandez, G.; Khanal, M. P.; Sultan, M. S.; Uprety, S.; Shen, L.; Zou, S.; Xu, P.; Ellis, C. D.; Sellers, J. A.; Hamilton, M. C.; Niu, G.; Sk, M. H.; Park, M.

2018-04-01

We report on the fabrication and electrical characterization of bottom gate thin-film transistors (TFTs) based on a sol-gel derived ZnO channel layer. The effect of annealing of ZnO active channel layers on the electrical characteristics of the ZnO TFTs was systematically investigated. Photoluminescence (PL) spectra indicate that the crystal quality of the ZnO improves with increasing annealing temperature. Both the device turn-on voltage (Von) and threshold voltage (VT) shift to a positive voltage with increasing annealing temperature. As the annealing temperature is increased, both the subthreshold slope and the interfacial defect density (Dit) decrease. The field effect mobility (μFET) increases with annealing temperature, peaking at 800 °C and decreases upon further temperature increase. An improvement in transfer and output characteristics was observed with increasing annealing temperature. However, when the annealing temperature reaches 900 °C, the TFTs demonstrate a large degradation in both transfer and output characteristics, which is possibly produced by non-continuous coverage of the film. By using the temperature-dependent field effect measurements, the localized sub-gap density of states (DOSs) for ZnO TFTs with different annealing temperatures were determined. The DOSs for the subthreshold regime decrease with increasing annealing temperature from 600 °C to 800 °C and no substantial change was observed with further temperature increase to 900 °C.

Thermo-responsive plasmonic nanohybrids with tunable optical properties

NASA Astrophysics Data System (ADS)

Zhang, Lingyu; Song, Gang

2017-10-01

In this paper, we study the temperature-dependent optical properties of gold-silver core-shell (Au@Ag) nanorods coated by a thermo-responsive polymer poly (N-isopropylacrylamide) (PNIPAM). The wavelength of the plasmonic resonant absorption of the nanohybrids changes with temperature due to the combination effects of the plasmon resonance of the core and the thermal response of the shell. Using effective medium theory, we find that with increase of temperature, the absorption peak red-shifts due to the competition effects from the changes of the thickness and the effective refractive index of the polymer shell. The working wavelength can be tuned by the aspect ratio of nanorods. Moreover, the temperature sensitivity of plasmon resonance increases with the increase of the aspect ratio. Our studies provide a proof-of-concept design of thermal responsive plasmonic smart material.

Degradation mechanisms of optoelectric properties of GaN via highly-charged 209Bi33+ ions irradiation

NASA Astrophysics Data System (ADS)

Zhang, L. Q.; Zhang, C. H.; Xian, Y. Q.; Liu, J.; Ding, Z. N.; Yan, T. X.; Chen, Y. G.; Su, C. H.; Li, J. Y.; Liu, H. P.

2018-05-01

N-type gallium nitride (GaN) epitaxial layers were subjected to 990-keV Bi33+ ions irradiation to various fluences. Optoelectric properties of the irradiated-GaN specimens were studied by means of Raman scattering and variable temperature photoluminescence (PL) spectroscopy. Raman spectra reveal that both the free-carrier concentration and its mobility generally decrease with a successive increase in ion fluence. Electro-optic mechanisms dominated the electrical transport to a fluence of 1.061 × 1012 Bi33+/cm2. Above this fluence, electrical properties were governed by the deformation potential. The appearance of vacancy-type defects results in an abrupt degradation in electrical transports. Varying temperature photoluminescence (PL) spectra display that all emission lines of 1.061 × 1012 Bi33+/cm2-irradiated specimen present a general remarkable thermal redshift, quenching, and broadening, including donor-bound-exciton peak, yellow luminescence band, and LO-phonon replicas. Moreover, as the temperature rises, a transformation from excitons (donor-acceptor pairs' luminescence) to band-to-band transitions (donor-acceptor combinations) was found, and the shrinkage effect of the band gap dominated the shift of the peak position gradually, especially the temperature increases above 150 K. In contrast to the un-irradiated specimen, a sensitive temperature dependence of all photoluminescence (PL) lines' intensity obtained from 1.061 × 1012 Bi33+/cm2-irradiated specimen was found. Mechanisms underlying were discussed.

The Effects of Annealing Temperatures on Composition and Strain in SixGe1−x Obtained by Melting Growth of Electrodeposited Ge on Si (100)

PubMed Central

Abidin, Mastura Shafinaz Zainal; Morshed, Tahsin; Chikita, Hironori; Kinoshita, Yuki; Muta, Shunpei; Anisuzzaman, Mohammad; Park, Jong-Hyeok; Matsumura, Ryo; Mahmood, Mohamad Rusop; Sadoh, Taizoh; Hashim, Abdul Manaf

2014-01-01

The effects of annealing temperatures on composition and strain in SixGe1−x, obtained by rapid melting growth of electrodeposited Ge on Si (100) substrate were investigated. Here, a rapid melting process was performed at temperatures of 1000, 1050 and 1100°C for 1 s. All annealed samples show single crystalline structure in (100) orientation. A significant appearance of Si-Ge vibration mode peak at ~00 cm−1 confirms the existence of Si-Ge intermixing due to out-diffusion of Si into Ge region. On a rapid melting process, Ge melts and reaches the thermal equilibrium in short time. Si at Ge/Si interface begins to dissolve once in contact with the molten Ge to produce Si-Ge intermixing. The Si fraction in Si-Ge intermixing was calculated by taking into account the intensity ratio of Ge-Ge and Si-Ge vibration mode peaks and was found to increase with the annealing temperatures. It is found that the strain turns from tensile to compressive as the annealing temperature increases. The Si fraction dependent thermal expansion coefficient of SixGe1−x is a possible cause to generate such strain behavior. The understanding of compositional and strain characteristics is important in Ge/Si heterostructure as these properties seem to give significant effects in device performance. PMID:28788521

The Effects of Annealing Temperatures on Composition and Strain in Si x Ge1-x Obtained by Melting Growth of Electrodeposited Ge on Si (100).

PubMed

Abidin, Mastura Shafinaz Zainal; Morshed, Tahsin; Chikita, Hironori; Kinoshita, Yuki; Muta, Shunpei; Anisuzzaman, Mohammad; Park, Jong-Hyeok; Matsumura, Ryo; Mahmood, Mohamad Rusop; Sadoh, Taizoh; Hashim, Abdul Manaf

2014-02-24

The effects of annealing temperatures on composition and strain in Si x Ge 1- x , obtained by rapid melting growth of electrodeposited Ge on Si (100) substrate were investigated. Here, a rapid melting process was performed at temperatures of 1000, 1050 and 1100 °C for 1 s. All annealed samples show single crystalline structure in (100) orientation. A significant appearance of Si-Ge vibration mode peak at ~400 cm -1 confirms the existence of Si-Ge intermixing due to out-diffusion of Si into Ge region. On a rapid melting process, Ge melts and reaches the thermal equilibrium in short time. Si at Ge/Si interface begins to dissolve once in contact with the molten Ge to produce Si-Ge intermixing. The Si fraction in Si-Ge intermixing was calculated by taking into account the intensity ratio of Ge-Ge and Si-Ge vibration mode peaks and was found to increase with the annealing temperatures. It is found that the strain turns from tensile to compressive as the annealing temperature increases. The Si fraction dependent thermal expansion coefficient of Si x Ge 1- x is a possible cause to generate such strain behavior. The understanding of compositional and strain characteristics is important in Ge/Si heterostructure as these properties seem to give significant effects in device performance.

Extreme Events in Urban Streams Leading to Extreme Temperatures in Birmingham, UK

NASA Astrophysics Data System (ADS)

Rangecroft, S.; Croghan, D.; Van Loon, A.; Sadler, J. P.; Hannah, D. M.

2016-12-01

Extreme flows and high water temperature events act as critical stressors on the ecological health of rivers. Urban headwater streams are considered particularly vulnerable to the effects of these extreme events. Despite this, such catchments remain poorly characterised and the effect of differences in land use is rarely quantified, especially in relation to water temperature. Thus a key research gap has emerged in understanding the patterns of water temperature during extreme events within contrasting urban, headwater catchments. We studied the headwaters of two bordering urban catchments of contrasting land use within Birmingham, UK. To characterise response to extreme events, precipitation and flow were analysed for the period of 1970-2016. To analyse the effects of extreme events on water temperature, 10 temperature loggers recording at 15 minute intervals were placed within each catchment covering a range of land use for the period May 2016 - present. During peak over threshold flood events higher average peaks were observed in the less urbanised catchment; however highest maximum flow peaks took place in the more densely urbanised catchment. Very similar average drought durations were observed between the two catchments with average flow drought durations of 27 days in the most urbanised catchment, and 29 in the less urbanised catchment. Flashier water temperature regimes were observed within the more urbanised catchment and increases of up to 5 degrees were apparent within 30 minutes during certain storms at the most upstream sites. Only in the most extreme events did the more densely urban stream appear more susceptible to both extreme high flows and extreme water temperature events, possibly resultant from overland flow emerging as the dominant flow pathway during intense precipitation events. Water temperature surges tended to be highly spatially variable indicating the importance of local land use. During smaller events, water temperature was less changeable and spatially variable, suggesting that overland flow may not the dominant flow pathway in such events. During drought events, the effect of catchment land use on water temperature was less apparent.

Potassium acceptor doping of ZnO crystals

NASA Astrophysics Data System (ADS)

Parmar, Narendra S.; Corolewski, Caleb D.; McCluskey, Matthew D.; Lynn, K. G.

2015-05-01

ZnO bulk single crystals were doped with potassium by diffusion at 950°C. Positron annihilation spectroscopy confirms the filling of zinc vacancies and a different trapping center for positrons. Secondary ion mass spectroscopy measurements show the diffusion of potassium up to 10 μm with concentration ˜1 × 1016 cm-3. IR measurements show a local vibrational mode (LVM) at 3226 cm-1, at a temperature of 9 K, in a potassium doped sample that was subsequently hydrogenated. The LVM is attributed to an O-H bond-stretching mode adjacent to a potassium acceptor. When deuterium substitutes for hydrogen, a peak is observed at 2378 cm-1. The O-H peak is much broader than the O-D peak, perhaps due to an unusually low vibrational lifetime. The isotopic frequency ratio is similar to values found in other hydrogen complexes. Potassium doping increases the resistivity up to 3 orders of magnitude at room temperature. The doped sample has a donor level at 0.30 eV.

Temperature Rise and Allowable Carbon Emissions for the RCP2.6 Scenario

NASA Astrophysics Data System (ADS)

Tachiiri, K.; Hargreaves, J. C.; Annan, J. D.; Huntingford, C.; Kawamiya, M.

2012-12-01

Climate research centres are running Earth System Models (ESMs) forced by Representative Concentration Pathway (RCP) scenarios. While these GCM studies increase process based knowledge, the number of simulations is small, making it difficult to interpret the resulting distribution of responses in a probabilistic way. We use a probabilistic framework to estimate the range of future temperature change and allowable emissions for a low mitigation CO2 concentration pathway RCP 2.6. Uncertainty is initially estimated by allowing modelled equilibrium climate sensitivity, aerosol forcing and intrinsic physical and biogeochemical processes to vary within widely accepted ranges. Results are then further constrained by extensive use of contemporary measurements. Despite this, the resulting range of temperatures for RCP 2.6 remains large. The predicted peak global temperature increase, reached around 2100, from pre-industrial is 0.8 - 1.9 K and 1.0 - 1.9 K (95% range) for the unconstrained and the constrained cases, respectively. Allowable emissions at the time of peak emission period is projected as 6.0 - 10.8 PgC yr-1 and 7.4 - 10.2 PgC yr-1 for each case. After year 2100, negative net emissions are required with a probability of some 84 %, and related uncertainty in cumulative emissions is large.

Low temperature specific heat of frustrated antiferromagnet HoInCu4

NASA Astrophysics Data System (ADS)

Weickert, Franziska; Fritsch, Veronika; Bambaugh, Ryan; Sarrao, John; Thompson, Joe D.; Movshovich, Roman

2014-03-01

We present low temperature specific heat measurements of single crystal HoInCu4, down to 35 mK and in magnetic field up to 12 Tesla. Ho atoms are arranged in an FCC lattice of the edge-sharing tetrahedra, and undergo an antiferromagnetic ordering at TN = 0.76 K, with the frustration parameter f = -ΘCW /TN of 14.3. Magnetic AF order is suppressed in field H0 ~ 4 T. The low temperature Schottky anomaly due to Ho evolves smoothly as a function of field through H0 and TN. The peak value of the anomaly remains roughly constant from 0 T to 12 T. The temperature of the anomaly's peak remains constant at TSch ~ 170 mK for H

Effect of annealing temperature on optical properties of binary zinc tin oxide nano-composite prepared by sol-gel route using simple precursors: structural and optical studies by DRS, FT-IR, XRD, FESEM investigations.

PubMed

Habibi, Mohammad Hossein; Mardani, Maryam

2015-02-25

Binary zinc tin oxide nano-composite was synthesized by a facile sol-gel method using simple precursors from the solutions consisting of zinc acetate, tin(IV) chloride and ethanol. Effect of annealing temperature on optical and structural properties was investigated using X-ray diffraction (XRD), diffuse reflectance spectra (DRS), field emission scanning electron microscopy (FESEM) and Fourier transform infrared spectroscopy (FTIR). XRD results revealed the existence of the ZnO and SnO2 phases. FESEM results showed that binary zinc tin oxide nano-composites ranges from 56 to 60 nm in diameter at 400°C and 500°C annealing temperatures respectively. The optical band gap was increased from 2.72 eV to 3.11 eV with the increasing of the annealing temperature. FTIR results confirmed the presence of zinc oxide and tin oxide and the broad absorption peaks at 3426 and 1602 cm(-1) can be ascribed to the vibration of absorptive water, and the absorption peaks at 546, 1038 and 1410 cm(-1) are due to the vibration of Zn-O or Sn-O groups in binary zinc tin oxide. Copyright © 2014 Elsevier B.V. All rights reserved.

Dynamics of bound water molecules in fullerenol at different hydration levels

NASA Astrophysics Data System (ADS)

Wang, Yilin; Robey, Steven; Reutt-Robey, Janice

Fullerenols, polyhydroxylated fullerenes, are of great interest as promising materials in medical application because of their high water solubility and biocompatibility. Fullerenols are highly responsive to their environment, for example, they readily undergo hydration under ambient conditions. Understanding the dynamics of water molecules bound to fullerenols, and the interplay between water molecules and fullerenols is important in realizing biological function. Here, broadband dielectric spectroscopy (BDS), was performed on a fullerenol with 44 hydroxyl groups, C60(OH)44, between 300 K and 340 K. At room temperature and under ambient conditions, C60(OH)44 is hydrated, releasing bound water molecules with increasing temperature, as quantified by thermal gravimetric analysis (TGA) measurements. At room temperature, a dielectric band due to collective bulk-like dynamics of the bound water molecules is observed. The relaxation peak of the water molecules shifts to higher frequency with increasing of temperature, reflecting the dynamics of bound water. Upon loss of water molecules, either thermally induced or vacuum induced, the relaxation peak shifts to lower frequency. The stoichiometric relationship between the dielectric properties of the hydrated fullerenol and the interplay between the bound water molecules and C60(OH)44 will be discussed. This work was supported by the National Science Foundation (NSF) under Award Number 1310380.

Observations of electron vortex magnetic holes and related wave-particle interactions in the turbulent magnetosheath

NASA Astrophysics Data System (ADS)

Huang, S.; Sahraoui, F.; Yuan, Z.; He, J.; Zhao, J.; Du, J.; Le Contel, O.; Wang, X.; Deng, X.; Fu, H.; Zhou, M.; Shi, Q.; Breuillard, H.; Pang, Y.; Yu, X.; Wang, D.

2017-12-01

Magnetic hole is characterized by a magnetic depression, a density peak, a total electron temperature increase (with a parallel temperature decrease but a perpendicular temperature increase), and strong currents carried by the electrons. The current has a dip in the core region of the magnetic hole and a peak in the outer region of the magnetic hole. There is an enhancement in the perpendicular electron fluxes at 90° pitch angles inside the magnetic hole, implying that the electrons are trapped within it. The variations of the electron velocity components Vem and Ven suggest that an electron vortex is formed by trapping electrons inside the magnetic hole in the circular cross-section. These observations demonstrate the existence of a new type of coherent structures behaving as an electron vortex magnetic hole in turbulent space plasmas as predicted by recent kinetic simulations. We perform a statistically study using high time solution data from the MMS mission. The magnetic holes with short duration (i.e., < 0.5 s) have their cross section smaller than the ion gyro-radius. Superposed epoch analysis of all events reveals that an increase in the electron density and total temperature, significantly increase (resp. decrease) the electron perpendicular (resp. parallel) temperature, and an electron vortex inside the holes. Electron fluxes at 90° pitch angles with selective energies increase in the KSMHs, are trapped inside KSMHs and form the electron vortex due to their collective motion. All these features are consistent with the electron vortex magnetic holes obtained in 2D and 3D particle-in-cell simulations, indicating that the observed the magnetic holes seem to be best explained as electron vortex magnetic holes. It is furthermore shown that the magnetic holes are likely to heat and accelerate the electrons. We also investigate the coupling between whistler waves and electron vortex magnetic holes. These whistler waves can be locally generated inside electron vortex magnetic holes by electron temperature anisotropic instability.

Programmable selectivity for GC with series-coupled columns using pulsed heating of the second column.

PubMed

Whiting, Joshua; Sacks, Richard

2003-05-15

A series-coupled ensemble of a nonpolar dimethyl polysiloxane column and a polar trifluoropropylmethyl polysiloxane column with independent at-column heating is used to obtain pulsed heating of the second column. For mixture component bands that are separated by the first column but coelute from the column ensemble, a temperature pulse is initiated after the first of the two components has crossed the column junction point and is in the second column, while the other component is still in the first column. This accelerates the band for the first component. If the second column cools sufficiently prior to the second component band crossing the junction, the second band experiences less acceleration, and increased separation is observed for the corresponding peaks in the ensemble chromatogram. High-speed at-column heating is obtained by wrapping the fused-silica capillary column with resistance heater wire and sensor wire. Rapid heating for a temperature pulse is obtained with a short-duration linear heating ramp of 1000 degrees C/min. During a pulse, the second-column temperature increases by 20-100 degrees C in a few seconds. Using a cold gas environment, cooling to a quiescent temperature of 30 degrees C can be obtained in approximately 25 s. The effects of temperature pulse initiation time and amplitude on ensemble peak separation and resolution are described. A series of appropriately timed temperature pulses is used to separate three coeluting pairs of components in a 13-component mixture.

Intercomparison of thermal-optical method with different temperature protocols: Implications from source samples and solvent extraction

NASA Astrophysics Data System (ADS)

Cheng, Yuan; Duan, Feng-kui; He, Ke-bin; Du, Zhen-yu; Zheng, Mei; Ma, Yong-liang

2012-12-01

Three temperature protocols with different peak inert mode temperature (Tpeak-inert) were compared based on source and ambient samples (both untreated and extracted using a mixture of hexane, methylene chloride, and acetone) collected in Beijing, China. The ratio of EC580 (elemental carbon measured by the protocol with a Tpeak-inert of 580 °C; similar hereinafter) to EC850 could be as high as 4.8 for biomass smoke samples whereas the ratio was about 1.0 for diesel and gasoline exhaust samples. The EC580 to EC850 ratio averaged 1.95 ± 0.89 and 1.13 ± 0.20 for the untreated and extracted ambient samples, whereas the EC580 to EC650 ratio of ambient samples was 1.22 ± 0.10 and 1.20 ± 0.12 before and after extraction. It was suggested that there are two competing mechanisms for the effects of Tpeak-inert on the EC results such that when Tpeak-inert is increased, one mechanism tends to decrease EC by increasing the amount of charring whereas the other tends to increase EC through promoting more charring to evolve before native EC. Results from this study showed that EC does not always decrease when increasing the peak inert mode temperature. Moreover, reducing the charring amount could improve the protocols agreement on EC measurements, whereas temperature protocol would not influence the EC results if no charring is formed. This study also demonstrated the benefits of allowing for the OC and EC split occurring in the inert mode when a high Tpeak-inert is used (e.g., 850 °C).

Temperature dynamics of stormwater runoff in Australia and the USA.

PubMed

Hathaway, J M; Winston, R J; Brown, R A; Hunt, W F; McCarthy, D T

2016-07-15

Thermal pollution of surface waters by urban stormwater runoff is an often overlooked by-product of urbanization. Elevated stream temperatures due to an influx of stormwater runoff can be detrimental to stream biota, in particular for cold water systems. However, few studies have examined temperature trends throughout storm events to determine how these thermal inputs are temporally distributed. In this study, six diverse catchments in two continents are evaluated for thermal dynamics. Summary statistics from the data showed larger catchments have lower maximum runoff temperatures, minimum runoff temperatures, and temperature variability. This reinforces the understanding that subsurface drainage infrastructure in urban catchments acts to moderate runoff temperatures. The catchments were also evaluated for the presence of a thermal first flush using two methodologies. Results showed the lack of a first flush under traditional assessment methodologies across all six catchments, supporting the results from a limited number of studies in literature. However, the time to peak temperature was not always coincident with the time to peak flow, highlighting the variability of thermal load over time. When a new first flush methodology was applied, significant differences in temperature were noted with increasing runoff depth for five of the six sites. This study is the first to identify a runoff temperature first flush, and highlights the need to carefully consider the appropriate methodology for such analyses. Copyright © 2016 Elsevier B.V. All rights reserved.

Models for coupled fluid flow, mineral reaction, and isotopic alteration during contact metamorphism: The Notch Peak aureole, Utah

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferry, J.M.; Dipple, G.M.

Three different models were developed to simulate the effect of contact metamorphism and fluid-rock interaction on the prograde mineralogical and O isotopic evolution of calcareous argillites from the Notch Peak aureole, Utah. All models assume local mineral-fluid equilibrium, a steady-state temperature profile corresponding to peak metamorphic values, and the thermodynamic data for minerals and fluid of Berman (1988). The preferred model, metamorphism with flow of a time-integrated fluid flux of 2 {plus minus} 0.5 {center dot} 10{sup 4} mol/cm{sup 2} in the direction of increasing temperature, successfully reproduces the principal petrologic and isotopic features of the aureole: (1) occurrence andmore » positions (in map view) of diopside-in, tremolite-out, grossular-in, wollastonite-in, and quartz-out isograds; (2) stable coexistence of tremolite + calcite + quartz + diopside over an {approx}1 km distance between the diopside-in and tremolite-out isograds; (3) variable whole-rock {sup 18}O depletions of {approx}6-9{per thousand} adjacent to the contact; and (4) a gradual and irregular increase in {delta}{sup 18}O with increasing distance from the pluton. Results demonstrate how isotopic and petrologic data for contact aureoles can be integrated to provide quantitative constraints on the magnitude and geometry of metamorphic fluid flow.« less

Temperature acclimation rate of aerobic scope and feeding metabolism in fishes: implications in a thermally extreme future.

PubMed

Sandblom, Erik; Gräns, Albin; Axelsson, Michael; Seth, Henrik

2014-11-07

Temperature acclimation may offset the increased energy expenditure (standard metabolic rate, SMR) and reduced scope for activity (aerobic scope, AS) predicted to occur with local and global warming in fishes and other ectotherms. Yet, the time course and mechanisms of this process is little understood. Acclimation dynamics of SMR, maximum metabolic rate, AS and the specific dynamic action of feeding (SDA) were determined in shorthorn sculpin (Myoxocephalus scorpius) after transfer from 10°C to 16°C. SMR increased in the first week by 82% reducing AS to 55% of initial values, while peak postprandial metabolism was initially greater. This meant that the estimated AS during peak SDA approached zero, constraining digestion and leaving little room for additional aerobic processes. After eight weeks at 16°C, SMR was restored, while AS and the estimated AS during peak SDA recovered partly. Collectively, this demonstrated a considerable capacity for metabolic thermal compensation, which should be better incorporated into future models on organismal responses to climate change. A mathematical model based on the empirical data suggested that phenotypes with fast acclimation rates may be favoured by natural selection as the accumulated energetic cost of a slow acclimation rate increases in a warmer future with exacerbated thermal variations. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

A uniform laminar air plasma plume with large volume excited by an alternating current voltage

NASA Astrophysics Data System (ADS)

Li, Xuechen; Bao, Wenting; Chu, Jingdi; Zhang, Panpan; Jia, Pengying

2015-12-01

Using a plasma jet composed of two needle electrodes, a laminar plasma plume with large volume is generated in air through an alternating current voltage excitation. Based on high-speed photography, a train of filaments is observed to propagate periodically away from their birth place along the gas flow. The laminar plume is in fact a temporal superposition of the arched filament train. The filament consists of a negative glow near the real time cathode, a positive column near the real time anode, and a Faraday dark space between them. It has been found that the propagation velocity of the filament increases with increasing the gas flow rate. Furthermore, the filament lifetime tends to follow a normal distribution (Gaussian distribution). The most probable lifetime decreases with increasing the gas flow rate or decreasing the averaged peak voltage. Results also indicate that the real time peak current decreases and the real time peak voltage increases with the propagation of the filament along the gas flow. The voltage-current curve indicates that, in every discharge cycle, the filament evolves from a Townsend discharge to a glow one and then the discharge quenches. Characteristic regions including a negative glow, a Faraday dark space, and a positive column can be discerned from the discharge filament. Furthermore, the plasma parameters such as the electron density, the vibrational temperature and the gas temperature are investigated based on the optical spectrum emitted from the laminar plume.

Tunneling spin polarization in planar tunnel junctions: measurements using NbN superconducting electrodes and evidence for Kondo-assisted tunneling

NASA Astrophysics Data System (ADS)

Yang, Hyunsoo

2006-03-01

The fundamental origin of tunneling magnetoresistance in magnetic tunnel junctions (MTJs) is the spin-polarized tunneling current, which can be measured directly using superconducting tunneling spectroscopy (STS). The STS technique was first developed by Meservey and Tedrow using aluminum superconducting electrodes. Al has been widely used because of its low spin orbit scattering. However, measurements must be made at low temperatures (<0.4 K) because of the low superconducting transition temperature of Al. Here, we demonstrate that superconducting electrodes formed from NbN can be used to measure tunneling spin polarization (TSP) at higher temperatures up to ˜1.2K. The tunneling magnetoresistance and polarization of the tunneling current in MTJs is highly sensitive to the detailed structure of the tunneling barrier. Using MgO tunnel barriers we find TSP values as high as 90% at 0.25K. The TMR is, however, depressed by insertion of ultra thin layers of both non-magnetic and magnetic metals in the middle of the MgO barrier. For ultra-thin, discontinuous magnetic layers of CoFe, we find evidence of Kondo assisted tunneling, from increased conductance at low temperatures (<50K) and bias voltage (<20 mV). Over the same temperature and bias voltage regimes the tunneling magnetoresistance is strongly depressed. We present other evidence of Kondo resonance including the logarithmic temperature dependence of the zero bias conductance peak. We infer the Kondo temperature from both the spectra width of this conductance peak as well as the temperature dependence of the TMR depression. The Kondo temperature is sensitive to the thickness of the inserted CoFe layer and decreases with increased CoFe thickness. * performed in collaboration with S-H. Yang, C. Kaiser, and S. Parkin.

Modelling the Peak Elongation of Nylon6 and Fe Powder Based Composite Wire for FDM Feedstock Filament

NASA Astrophysics Data System (ADS)

Garg, Harish Kumar; Singh, Rupinder

2017-10-01

In the present work, to increase the application domain of fused deposition modelling (FDM) process, Nylon6-Fe powder based composite wire has been prepared as feed stock filament. Further for smooth functioning of feed stock filament without any change in the hardware and software of the commercial FDM setup, the mechanical properties of the newly prepared composite wire must be comparable/at par to the existing material i.e. ABS, P-430. So, keeping this in consideration; an effort has been made to model the peak elongation of in house developed feedstock filament comprising of Nylon6 and Fe powder (prepared on single screw extrusion process) for commercial FDM setup. The input parameters of single screw extruder (namely: barrel temperature, temperature of the die, speed of the screw, speed of the winding machine) and rheological property of material (melt flow index) has been modelled with peak elongation as the output by using response surface methodology. For validation of model the result of peak elongation obtained from the model equation the comparison was made with the results of actual experimentation which shows the variation of ±1 % only.

Assessment of Retained Austenite in AISI D2 Tool Steel Using Magnetic Hysteresis and Barkhausen Noise Parameters

NASA Astrophysics Data System (ADS)

Kahrobaee, Saeed; Kashefi, Mehrdad

2015-03-01

Inaccurate heat treatment process could result in excessive amount of retained austenite, which degrades the mechanical properties, like strength, wear resistance, and hardness of cold work tool steel parts. Thus, to control the mechanical properties, quantitative measurement of the retained austenite is a critical step in optimizing the heat-treating parameters. X-ray diffraction method is the most frequently used technique for this purpose. This technique is, however, destructive and time consuming. Furthermore, it is not applicable to 100% quality inspection of industrial parts. In the present paper, the influence of austenitizing temperature on the retained austenite content and hardness of AISI D2 tool steel has been studied. Additionally, nondestructive magnetic hysteresis parameters of the samples including coercivity, magnetic saturation, and maximum differential permeability as well as their magnetic Barkhausen noise features (RMS peak voltage and peak position) have been investigated. The results revealed direct relations between magnetic saturation, differential permeability, and MBN peak amplitude with increasing austenitizing temperature due to the retained austenite formation. Besides, both parameters of coercivity and peak position had an inverse correlation with the retained austenite fraction.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kong Lingmin; Feng Zhechuan; Wu Zhengyun

Four types of self-assembled InAs/GaAs quantum dots (QDs) were grown by molecular beam epitaxy and studied via temperature-dependent and time-resolved photoluminescence (PL) spectroscopy measurements. A thin InGaAs stain reducing layer (SRL) is adopted which extends the emission wavelength to 1.3 mum and the influence of strain on QDs is investigated. The SRL releases the strain between the wetting layer and QDs, and enlarges the size of QDs, as shown by atomic force microscopy measurements. As the thickness of InAs layer decreases to 1.7 ML, the QDs with the SRL are chained to strings and the density of QDs increases significantly,more » which leads to an abnormal redshift of 1.3 mum PL peak at room temperature. PL peaks of InAs QDs with the SRL show redshift compared with the QDs directly deposited on GaAs matrix. The dependences of PL lifetime on the QD size, density and temperature (T) are systematically studied. It is observed that the PL lifetime of QDs is insensitive to T below 50 K. Beyond 50 K, increases and then drops at higher temperature, with a peak at T{sub C}, which was determined by the SRL and the thickness of InAs. We have also observed an obvious PL spectral redshift of the QDs with 1.7 ML InAs coverage on SRL at low T as the measuring time delays. The PL lifetime of QDs with the SRL is smaller than that of QDs without the SRL. The QDs with different densities have different PL lifetime dependence on the QDs size. These observations can be explained by the competition between the carrier redistribution and thermal emission.« less

Temperature-Dependent Electrical and Micromechanical Properties of Lanthanum Titanate with Additions of Yttria

NASA Technical Reports Server (NTRS)

Goldsby, Jon C.

2010-01-01

Temperature-dependent elastic properties were determined by establishing continuous flexural vibrations in the material at its lowest resonance frequency of 31tHz. The imaginary part of the complex impedance plotted as a function of frequency and temperature reveals a thermally activated peak, which decreases in magnitude as the temperature increases. Additions of yttria do not degrade the electromechanical in particularly the elastic and anelastic properties of lanthanum titanate. Y2O3/La2Ti2O7 exhibits extremely low internal friction and hence may be more mechanical fatigue-resistant at low strains.

A dual-parameter tilted fiber Bragg grating-based sensor for liquid level and temperature monitoring

NASA Astrophysics Data System (ADS)

Osuch, Tomasz; Jurek, Tomasz; Markowski, Konrad; Jedrzejewski, Kazimierz

2016-09-01

In this paper, the concept and experimental characterization of tilted fiber Bragg grating (TFBG) based sensor for temperature and liquid level measurement are presented. It is shown that, when liquid level increases the peak amplitudes of cladding modes linearly decreases (in dB). In turn, changes in temperature causes a shift of the TFBG transmission spectrum, which can be accurately measured by monitoring the Bragg wavelength corresponding to the liquid level independent core mode. The main advantages of proposed sensor are simple design as well as linear responses to liquid level and temperature.

Controls of Methane Dynamics and Emissions in an Arctic Warming Experiment

NASA Astrophysics Data System (ADS)

Nielsen, C. S.; Elberling, B.; Michelsen, A.; Strobel, B. W.; Wulff, K.; Banyasz, I.

2015-12-01

Climatic changes have resulted in increasing air temperatures across the Arctic. This may increase anaerobic decomposition of soil organic matter to methane (CH4) in wetlands and increase plant growth and thereby production of substrate. Little is known about how seasonal variations in dissolved CH4 in soil water, substrate availability, and the effect of warming affect arctic wetland dynamics of CH4 production and emission. In 2013 we established two experiments in a fen at Disko Island, W Greenland; one with year round warming by open-top chambers and removal of shrubs, and one with removal of the aerenchymatous sedge Carex aquatilis ssp. stans. Throughout the growing season 2014 we measured how the treatments affected CH4 emissions, dissolved CH4 in the soil water, and substrate availability. Ecosystem CH4 emissions peaked at August 5th 2014 (7.5 μmol m-2 h-1) without coinciding with time of highest concentrations of dissolved CH4 or acetate indicating a decoupling between production and emission of CH4. The peak in dissolved CH4 concentration, at ten cm depth (1368 ppm, September 18th 2014), followed the peak in concentration of acetate in the same depth (0.30 ppm, August 30th 2014) highlighting the importance of this substance as a substrate for methanogenesis. C. aquatilis ssp. stans accounted for 60% and 77% of the ecosystem CH4 emissions in areas of the fen with water table above and below soil surface showing the importance of the presence of this species to serve as a pipe for CH4 emission which is bypassing the upper soil zone and potential methane oxidation. Throughout the season, warming increased the air temperature at soil surface by on average 0.89°C and occasionally warming and shrub removal increased soil temperature in 2 and 5 cm depth, but there was no effect of the treatments on the CH4 emissions indicating that this wetland is quite resilient towards future climate change.

In vivo temperature rise in anesthetized human pulp during exposure to a polywave LED light curing unit.

PubMed

Runnacles, Patrício; Arrais, Cesar Augusto Galvão; Pochapski, Marcia Thais; Dos Santos, Fábio André; Coelho, Ulisses; Gomes, João Carlos; De Goes, Mário Fernando; Gomes, Osnara Maria Mongruel; Rueggeberg, Frederick Allen

2015-05-01

This in vivo study evaluated pulp temperature (PT) rise in human premolars during exposure to a light curing unit (LCU) using selected exposure modes (EMs). After local Ethics Committee approval, intact first upper premolars, requiring extraction for orthodontic reasons, from 8 volunteers, received infiltrative and intraligamental anesthesia. The teeth (n=15) were isolated using rubber dam and a minute pulp exposure was attained. A sterile probe from a wireless, NIST-traceable, temperature acquisition system was inserted directly into the coronal pulp chamber, and real time PT (°C) was continuously monitored while the buccal surface was exposed to polywave light from a LED LCU (Bluephase 20i, Ivoclar Vivadent) using selected EMs allowing a 7-min span between each exposure: 10-s either in low (10-s/L) or high (10-s/H); 5-s-turbo (5-s/T); and 60-s-high (60-s/H) intensities. Peak PT values and PT increases from baseline (ΔT) after exposure were subjected to one-way, repeated measures ANOVAs, and Bonferroni's post hoc tests (α=0.05). Linear regression analysis was performed to establish the relationship between applied radiant exposure and ΔT. All EMs produced higher peak PT than the baseline temperature (p<0.001). The 60-s/H mode generated the highest peak PT and ΔT (p<0.001), with some teeth exhibiting ΔT higher than 5.5°C. A significant, positive relationship between applied radiant exposure and ΔT (r(2)=0.916; p<0.001) was noted. Exposing intact, in vivo anesthetized human upper premolars to a polywave LED LCU increases PT, and depending on EM and the tooth, PT increase can be higher than the critical ΔT, thought to be associated with pulpal necrosis. Copyright © 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

Modelling of electric characteristics of 150-watt peak solar panel using Boltzmann sigmoid function under various temperature and irradiance

NASA Astrophysics Data System (ADS)

Sapteka, A. A. N. G.; Narottama, A. A. N. M.; Winarta, A.; Amerta Yasa, K.; Priambodo, P. S.; Putra, N.

2018-01-01

Solar energy utilized with solar panel is a renewable energy that needs to be studied further. The site nearest to the equator, it is not surprising, receives the highest solar energy. In this paper, a modelling of electrical characteristics of 150-Watt peak solar panels using Boltzmann sigmoid function under various temperature and irradiance is reported. Current, voltage, temperature and irradiance data in Denpasar, a city located at just south of equator, was collected. Solar power meter is used to measure irradiance level, meanwhile digital thermometer is used to measure temperature of front and back panels. Short circuit current and open circuit voltage data was also collected at different temperature and irradiance level. Statistically, the electrical characteristics of 150-Watt peak solar panel can be modelled using Boltzmann sigmoid function with good fit. Therefore, it can be concluded that Boltzmann sigmoid function might be used to determine current and voltage characteristics of 150-Watt peak solar panel under various temperature and irradiance.

Internal friction of hydrated soda-lime-silicate glasses.

PubMed

Reinsch, S; Müller, R; Deubener, J; Behrens, H

2013-11-07

The internal friction of hydrated soda-lime-silica glasses with total water content (C(W)) up to 1.9 wt. % was studied by dynamic mechanical analysis (DMA) using temperature-frequency sweeps from 723 K to 273 K and from 1 s(-1) to 50 s(-1). Total water content and concentrations of H2O molecules (C(H2O)) and OH groups (C(OH)) in the DMA specimens were determined by infrared spectroscopy. For low water contents (C(W) ≈ C(OH) < 0.25 wt. %) two discrete internal friction peaks below the glass transition (α relaxation) were assigned to the low-temperature motion of alkali ions (γ relaxation) and cooperative movements of dissimilar mobile species under participation of OH at higher temperature (β(OH) relaxation). For large water contents (C(W) > 1 wt. %), where significant amounts of molecular water are evident (C(H2O) > 0.15 wt. %), however, internal friction spectra change unexpectedly: the β(OH) peak heights saturate and a low temperature shoulder appears on the β-relaxation peak. This emerging relaxation mode (β(H2O) relaxation) was assigned to the motions of H2O molecules. β(H2O) relaxation was found to be faster than β(OH) but slower than γ relaxation. Activation energy of the different relaxation modes increased in the order γ < β(H2O) < β(OH) < α.

Effect of Bath Temperature on Cooling Performance of Molten Eutectic NaNO3-KNO3 Quench Medium for Martempering of Steels

NASA Astrophysics Data System (ADS)

Pranesh Rao, K. M.; Narayan Prabhu, K.

2017-10-01

Martempering is an industrial heat treatment process that requires a quench bath that can operate without undergoing degradation in the temperature range of 423 K to 873 K (150 °C to 600 °C). The quench bath is expected to cool the steel part from the austenizing temperature to quench bath temperature rapidly and uniformly. Molten eutectic NaNO3-KNO3 mixture has been widely used in industry to martemper steel parts. In the present work, the effect of quench bath temperature on the cooling performance of a molten eutectic NaNO3-KNO3 mixture has been studied. An Inconel ASTM D-6200 probe was heated to 1133 K (860 °C) and subsequently quenched in the quench bath maintained at different temperatures. Spatially dependent transient heat flux at the metal-quenchant interface for each bath temperature was calculated using inverse heat conduction technique. Heat transfer occurred only in two stages, namely, nucleate boiling and convective cooling. The mean peak heat flux ( q max) decreased with increase in quench bath temperature, whereas the mean surface temperature corresponding to q max and mean surface temperature at the start of convective cooling stage increased with increase in quench bath temperature. The variation in normalized cooling parameter t 85 along the length of the probe increased with increase in quench bath temperature.

Preparation of high-strength Al-Mg-Si-Cu-Fe alloy via heat treatment and rolling

NASA Astrophysics Data System (ADS)

Liu, Chong-yu; Yu, Peng-fei; Wang, Xiao-ying; Ma, Ming-zhen; Liu, Ri-ping

2014-07-01

An Al-Mg-Si-Cu-Fe alloy was solid-solution treated at 560°C for 3 h and then cooled by water quenching or furnace cooling. The alloy samples which underwent cooling by these two methods were rolled at different temperatures. The microstructure and mechanical properties of the rolled alloys were investigated by optical microscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, and tensile testing. For the water-quenched alloys, the peak tensile strength and elongation occurred at a rolling temperature of 180°C. For the furnace-cooled alloys, the tensile strength decreased initially, until the rolling temperature of 420°C, and then increased; the elongation increased consistently with increasing rolling temperature. The effects of grain boundary hardening and dislocation hardening on the mechanical properties of these rolled alloys decreased with increases in rolling temperature. The mechanical properties of the 180°C rolling water-quenched alloy were also improved by the presence of β″ phase. Above 420°C, the effect of solid-solution hardening on the mechanical properties of the rolled alloys increased with increases in rolling temperature.

“Glass-like” thermal conductivity gradually induced in thermoelectric Sr{sub 8}Ga{sub 16}Ge{sub 30} clathrate by off-centered guest atoms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Christensen, Sebastian; Schmøkel, Mette Stokkebro; Borup, Kasper Andersen

The origin of the “glass-like” plateau in thermal conductivity of inorganic type I clathrates has been debated for more than a decade. Here, it is demonstrated that the low temperature thermal conductivity of Sr{sub 8}Ga{sub 16}Ge{sub 30} can be controlled by the synthesis method: A flux-grown sample has a “glass-like” plateau in thermal conductivity at low temperature, while a zone-melted sample instead has a crystalline peak. A combination of flux-growth and zone-melting produces an intermediate thermal conductivity. In a comprehensive study of three single crystal samples, it is shown by neutron diffraction that the transition from crystalline peak to “glass-like”more » plateau is related to an increase in Sr guest atom off-centering distance from 0.24 Å to 0.43 Å. By modifying ab initio calculated force constants for the guest atom to an isotropic model, we reproduce both measured heat capacity and inelastic neutron scattering data. The transition from peak to plateau in the thermal conductivity can be modeled by a combined increase of Rayleigh and disorder scattering. Measurement of heat capacity refutes simple models for tunneling of Sr between off-center sites. Furthermore, the electronic properties of the same samples are characterized by Hall carrier density, Seebeck coefficient, and resistivity. The present comprehensive analysis excludes tunneling and charge carrier scattering as dominant contributors to the “glass-like” plateau. The increased guest atom off-centering distance controlled by synthesis provides a possible microscopic mechanism for reducing the low temperature thermal conductivity of clathrates.« less

Novel voltage signal at proximity-induced superconducting transition temperature in gold nanowires

NASA Astrophysics Data System (ADS)

Wang, Jian; Tang, JunXiong; Wang, ZiQiao; Sun, Yi; Sun, QingFeng; Chan, Moses H. W.

2018-08-01

We observed a novel voltage peak in the proximity-induced superconducting gold (Au) nanowire while cooling the sample through the superconducting transition temperature. The voltage peak turned dip during warming. The voltage peak or dip was found to originate respectively from the emergence or vanishing of the proximity-induced superconductivity in the Au nanowire. The amplitude of the voltage signal depends on the temperature scanning rate, and it cannot be detected when the temperature is changed slower than 0.03 K/min. This transient feature suggests the non-equilibrium property of the effect. Ginzburg-Landau model clarified the voltage peak by considering the emergence of Cooper pairs of relatively lower free energy in superconducting W contact and the non-equilibrium diffusion of Cooper pairs and quasiparticles.

Thermoluminescence and optically stimulated luminescence disadvantages of α-Al2O3:C crystal grown by the temperature gradient technique

NASA Astrophysics Data System (ADS)

Yang, Xin-Bo; Xu, Jun; Li, Hong-Jun; Bi, Qun-Yu; Cheng, Yan; Su, Liang-Bi; Tang, Qiang

2010-04-01

Recently, α-Al2O3:C crystal with highly sensitive thermoluminescence (TL) and optically stimulated luminescence (OSL) has been successfully grown by the temperature gradient technique. This paper investigates the heating rate dependence of TL sensitivity, light-induced fading of TL signals and thermal stability of OSL of α-Al2O3:C crystals. As the heating rate increases, the integral TL response decreases and the dosimetric glow peak shifts to higher temperatures in α-Al2O3:C crystals. Light-induced fading of TL increases with the irradiation dose, and TL response decreases as the exposure time increases, especially in the first 15 minutes. With the increasing intensity of the exposure light, the TL fading of α-Al2O3:C crystal increases sharply. The OSL response of as-grown α-Al2O3:C crystal is quite stable below 373 K and decreases sharply for higher temperatures.

Thermal sterilization of heat-sensitive products using high-temperature short-time sterilization.

PubMed

Mann, A; Kiefer, M; Leuenberger, H

2001-03-01

High-temperature short-time (HTST) sterilization with a continuous-flow sterilizer, developed for this study, was evaluated. The evaluation was performed with respect to (a) the chemical degradation of two heat-sensitive drugs in HTST range (140-160 degrees C) and (b) the microbiological effect of HTST sterilization. Degradation kinetics of two heat-sensitive drugs showed that a high peak temperature sterilization process resulted in less chemical degradation for the same microbiological effect than a low peak temperature process. Both drugs investigated could be sterilized with acceptable degradation at HTST conditions. For the evaluation of the microbiological effect, Bacillus stearothermophilus ATCC 7953 spores were used as indicator bacteria. Indicator spore kinetics (D(T), z value, k, and E(a)), were determined in the HTST range. A comparison between the Bigelow model (z value concept) and the Arrhenius model, used to describe the temperature coefficient of the microbial inactivation, demonstrated that the Bigelow model is more accurate in prediction of D(T) values in the HTST range. The temperature coefficient decreased with increasing temperature. The influence of Ca(2+) ions and pH value on the heat resistance of the indicator spores, which is known under typical sterilization conditions, did not change under HTST conditions.

Seventy-five years of masting and rodent population peaks in Norway: Why do wood mice not follow the rules?

PubMed

Selås, Vidar

2016-09-01

Wood mouse (Apodemus sylvaticus) populations are expected to show a peak in autumn in the year after a mast year of sessile oak (Quercus petraea), because stored acorns increase winter survival. In Aust-Agder, South Norway, only 16 of 34 mast years from 1939-2014 were followed by a year with a peak in the wood mouse population. For many of the remaining instances, there rather was a minor peak 2 or 3 years after the mast. In multiple logistic regression models, the probability of a wood mouse population peak after a mast year of sessile oak was positively related to a snow-corrected temperature index of the previous winter and negatively to a small rodent population index of the previous autumn. The present study thus supports the hypothesis that longer periods with snow-free ground and subzero temperatures negatively affect wood mouse winter survival. Because it may be difficult for wood mice to survive on a diet consisting of acorns alone, the negative relationship with the rodent population index of the previous year is most likely caused by an over-exploitation of necessary alternative food resources, such as other plant seeds and arthropods. Stored acorns not utilized during one winter are assumed to benefit wood mice in a succeeding winter, giving a delayed population peak relative to the mast year. © 2016 International Society of Zoological Sciences, Institute of Zoology/Chinese Academy of Sciences and John Wiley & Sons Australia, Ltd.

Composition-dependent damping and relaxation dynamics in miscible polymer blends above glass transition temperature by anelastic spectroscopy

NASA Astrophysics Data System (ADS)

Wu, Xuebang; Shang, Shuying; Xu, Qiaoling; Liu, Changsong; Zhu, Zhengang; Zhang, Guangzhao

2008-07-01

Anelastic spectroscopy is used to study the composition dependence of the damping and molecular relaxation dynamics in miscible poly(ethylene oxide) (PEO)/poly(methyl methacrylate) (PMMA) blends above the glass transition temperature. The ultrahigh damping peak of the relaxation type is shown to be associated with the liquid-liquid transition of PMMA. A higher PEO concentration leads to a higher damping performance and a lower transition temperature. The decreasing activation energy with increasing PEO concentration indicates a drastic increase in molecular mobility. Moreover, the relaxation time reveals a transition from the Vogel-Fulcher-Tamman behavior to the Arrhenius behavior due to the intermolecular guest-host interactions.

Source attribution of aerosol size distributions and model evaluation using Whistler Mountain measurements and GEOS-Chem-TOMAS simulations

NASA Astrophysics Data System (ADS)

D'Andrea, S. D.; Ng, J. Y.; Kodros, J. K.; Atwood, S. A.; Wheeler, M. J.; Macdonald, A. M.; Leaitch, W. R.; Pierce, J. R.

2015-09-01

Remote and free tropospheric aerosols represent a large fraction of the climatic influence of aerosols; however, aerosol in these regions is less characterized than those polluted boundary layers. We evaluate aerosol size distributions predicted by the GEOS-Chem-TOMAS global chemical transport model with online aerosol microphysics using measurements from the peak of Whistler Mountain, BC, Canada (2182 m a.s.l.). We evaluate the model for predictions of aerosol number, size and composition during periods of free tropospheric (FT) and boundary-layer (BL) influence at "coarse" 4° × 5° and "nested" 0.5° × 0.667° resolutions by developing simple FT/BL filtering techniques. We find that using temperature as a proxy for upslope flow (BL influence) improved the model measurement comparisons. The best threshold temperature was around 2 °C for the coarse simulations and around 6 °C for the nested simulations, with temperatures warmer than the threshold indicating boundary-layer air. Additionally, the site was increasingly likely to be in-cloud when the measured RH was above 90 %, so we do not compare the modeled and measured size distributions during these periods. With the inclusion of these temperature and RH filtering techniques, the model-measurement comparisons improved significantly. The slope of the regression for N80 (the total number of particles with particle diameter, Dp > 80 nm) in the nested simulations increased from 0.09 to 0.65, R2 increased from 0.04 to 0.46, and log-mean bias improved from 0.95 to 0.07. We also perform simulations at the nested resolution without Asian anthropogenic (AA) emissions and without biomass-burning (BB) emissions to quantify the contribution of these sources to aerosols at Whistler Peak (through comparison with simulations with these emissions on). The long-range transport of AA aerosol was found to be significant throughout all particle number concentrations, and increased the number of particles larger than 80 nm (N80) by more than 50 %, while decreasing the number of smaller particles because of suppression of new-particle formation and enhanced coagulation sink. Similarly, BB influenced Whistler Peak during summer months, with an increase in N80 exceeding 5000 cm-3. Occasionally, Whistler Peak experienced N80 > 1000 cm-3 without significant influence from AA or BB aerosol. Air masses were advected at low elevations through forested valleys during times when temperature and downwelling insolation were high, ideal conditions for formation of large sources of low-volatility biogenic secondary organic aerosol (SOA). This condensable material increased particle growth and hence N80. The low-cost filtering techniques and source apportionment used in this study can be used in other global models to give insight into the sources and processes that shape the aerosol at mountain sites, leading to a better understanding of mountain meteorology and chemistry.

Dielectric spectroscopy in benzophenone: the beta relaxation and its relation to the mode-coupling Cole-Cole peak.

PubMed

Pardo, L C; Lunkenheimer, P; Loidl, A

2007-09-01

We report a thorough characterization of the glassy dynamics of benzophenone by broadband dielectric spectroscopy. We detect a well-pronounced beta relaxation peak developing into an excess wing with increasing temperature. A previous analysis of results from Optical-Kerr-effect measurements of this material within the mode-coupling theory revealed a high-frequency Cole-Cole peak. We address the question if this phenomenon also may explain the Johari-Goldstein beta relaxation, a so-far unexplained spectral feature inherent to glass-forming matter, mainly observed in dielectric spectra. Our results demonstrate that according to the present status of theory, both spectral features seem not to be directly related.

Surface phonons on Bi2Sr2CaCu2O8+δ

NASA Astrophysics Data System (ADS)

Phelps, R. B.; Akavoor, P.; Kesmodel, L. L.; Demuth, J. E.; Mitzi, D. B.

1993-11-01

We report measurements of surface optical phonons on Bi2Sr2CaCu2O8+δ with high-resolution electron-energy-loss spectroscopy (HREELS). In addition to peaks near 50 and 80 meV (403 and 645 cm-1), which have been previously observed, our loss spectra exhibit a peak at 26 meV (210 cm-1). Loss spectra were measured at temperatures from 45 to 146 K, and the temperature dependence of the peaks was found to be weak. The 50 and 80 meV peaks shift to lower frequency by ~1.5 meV over this temperature range. All three peaks are attributed to surface optical phonons. The identification of particular bulk modes corresponding to the surface modes observed with HREELS is discussed.

Low cell pH depresses peak power in rat skeletal muscle fibres at both 30 degrees C and 15 degrees C: implications for muscle fatigue.

PubMed

Knuth, S T; Dave, H; Peters, J R; Fitts, R H

2006-09-15

Historically, an increase in intracellular H(+) (decrease in cell pH) was thought to contribute to muscle fatigue by direct inhibition of the cross-bridge leading to a reduction in velocity and force. More recently, due to the observation that the effects were less at temperatures closer to those observed in vivo, the importance of H(+) as a fatigue agent has been questioned. The purpose of this work was to re-evaluate the role of H(+) in muscle fatigue by studying the effect of low pH (6.2) on force, velocity and peak power in rat fast- and slow-twitch muscle fibres at 15 degrees C and 30 degrees C. Skinned fast type IIa and slow type I fibres were prepared from the gastrocnemius and soleus, respectively, mounted between a force transducer and position motor, and studied at 15 degrees C and 30 degrees C and pH 7.0 and 6.2, and fibre force (P(0)), unloaded shortening velocity (V(0)), force-velocity, and force-power relationships determined. Consistent with previous observations, low pH depressed the P(0) of both fast and slow fibres, less at 30 degrees C (4-12%) than at 15 degrees C (30%). However, the low pH-induced depressions in slow type I fibre V(0) and peak power were both significantly greater at 30 degrees C (25% versus 9% for V(0) and 34% versus 17% for peak power). For the fast type IIa fibre type, the inhibitory effect of low pH on V(0) was unaltered by temperature, while for peak power the inhibition was reduced at 30 degrees C (37% versus 18%). The curvature of the force-velocity relationship was temperature sensitive, and showed a higher a/P(0) ratio (less curvature) at 30 degrees C. Importantly, at 30 degrees C low pH significantly depressed the ratio of the slow type I fibre, leading to less force and velocity at peak power. These data demonstrate that the direct effect of low pH on peak power in both slow- and fast-twitch fibres at near-in vivo temperatures (30 degrees C) is greater than would be predicted based on changes in P(0), and that the fatigue-inducing effects of low pH on cross-bridge function are still substantial and important at temperatures approaching those observed in vivo.

Comparison of SPI and SPEI indices for Drought Characterization under Climate Change Scenario in India

NASA Astrophysics Data System (ADS)

Gupta, V.; Jain, M. K.

2017-12-01

Many drought indices are available for quantifying and characterizing the drought events. Selection of a particular drought index could influence the outcome of the study. In this study, we compared two drought indices namely, Standardized precipitation index (SPI) and Standardized Precipitation-Evapotranspiration Index (SPEI) under climate change condition. Data from 7 RCM models namely, CCCma-CanESM2, CERFACS-CNRM-CM5, GFDL-ESM2M, MOHC-HadGEM2, MIROC-MIROC5, MPI-ESM-LR and MPI-ESM-MR for RCP 4.5 scenario have been used to calculate 12 month SPI and SPEI values. L-moments which provides robust distribution parameter estimation, have been used to identify best fit distribution for projected data at each grid point for each month. Mann-Kendall and Sen's slope test have been used to detect trends in drought severity, duration, peak, and interval between drought events. Results of this study reveal that SPI shows decreasing trends in drought severity, duration and peak with negative Sen's slope, however, the SPEI shows increasing trends of severity, duration and peak with a positive Sen's slope for almost all over India. The analysis reveals that projected percentage of drought affected area based on SPI in the first half of the 21st century is higher compared to those obtained using SPEI, however for the second half of the 21st century, the projected drought affected computed using SPEI is higher compared to the corresponding area obtained using SPI. Decrease in droughts severity, duration and peaks in SPI analysis could be attributed to projected increase in monsoon rainfall in Indian Subcontinent during second half of 21st century however, SPI was found incapable to account the increase in temperature thus neglecting the drying due to increased evapotranspiration whereas SPEI shows significant drying in Indian subcontinent on account of increasing trend in temperature observed in projected future RCM scenarios.

Improved semi-conductor laser device, operating, at room temperature, with an array of three lasers in the spatially coherent, free running mode

NASA Technical Reports Server (NTRS)

Rutz, E. M.

1975-01-01

The peak pulse power was increased by operating an array of three homostructure Ga As lasers in the laser device. A spatial filter in the laser device selects the spatially coherent, free running, mode. The optical peak power is 5 watts, which is three times the peak power of a single laser in the array. The far-field distribution of the three laser array is a single Gaussian beam of spatial coherence without sidelobes or grating lobes. The length of the optical pulses of spatial coherence was increased to 200 ns by improved heat transfer from the p-n junctions of the lasers to the metal housing of the pulse transformer, and by doubling the core area and increasing the turns of the primary windings of the pulse transformer. The mechanical stability of the laser device was improved and the transition from mechanical alignment to electro-mechanical alignment control, was facilitated.

Influence of Sn doping in BaSnxTi1-xO3 ceramics on microstructural and dielectric properties

NASA Astrophysics Data System (ADS)

Ansari, Mohd. Azaj; Sreenivas, K.

2018-05-01

BaSnxTi1-x O3 solid solutions with varying Sn content (x = 0.00, 0.05, 0.15, 0.25) prepared by solid state reaction method have been studied for their structural and dielectric properties. X-ray diffraction and Raman spectroscopic analysis show composition induced modifications in the crystallographic structure, and with increasing Sn content the structure changes from tetragonal to cubic structure. The tetragonal distortion decreases with increasing Sn, and the structure becomes purely cubic for x =0.25. Changes in the structure are reflected in the temperature dependent dielectric properties. For increasing Sn content the peak dielectric constant is found to increase and the phase transition temperature (Tc) decreases to lower temperature. The purely cubic structure with x=0.25 shows a diffused phased transition.

Effect of Vacuum-Sintering Temperature on Magnetic and Mechanical Properties of TiC-TiN-Ni-Mo-C Cermets

NASA Astrophysics Data System (ADS)

Zhang, Man; Yang, Qingqing; Xiong, Weihao; Zhou, Shiquan; Wang, Shengqing; Luo, Haifeng; Ruan, Linji

2018-05-01

The effect of vacuum-sintering temperature (T vs ), ranging from 1390 °C to 1470 °C, on magnetic and mechanical properties of TiC-10TiN-30Ni-6Mo-4C (mol pct) cermet was investigated in the present article. Room-temperature (RT) magnetization and maximum susceptibility decreased with increasing T vs up to 1450 °C, and then increased. This was mainly attributed to the fact that Ti content in the Ni-based binder phase increased with increasing T vs up to 1450 °C, suppressing ferromagnetism of the Ni matrix. RT ferromagnetism disappeared at T vs ≥ 1430 °C. Transverse rupture strength (TRS) reached a peak value at T vs = 1430 °C, and hardness did not significantly vary with T vs .

Temperature characterization of dielectric permittivity and AC conductivity of nano copper oxide-doped polyaniline composite

NASA Astrophysics Data System (ADS)

Shubha, L. N.; Madhusudana Rao, P.

2016-06-01

The polyaniline/copper oxide (PANI/CuO) nanocomposite was prepared by mixing solutions of polyaniline and copper oxide nanoparticles in dimethyl sulfoxide (DMSO). The synthesized polymer nanocomposites were characterized by X-ray powder diffraction (XRD), scanning electron microscope (SEM) and UV-visible spectroscopy. The characteristic peaks in XRD and UV-visible spectra confirmed the presence of CuO in the polymer structure. SEM images indicated morphological changes in the composite matrix as compared to the pristine PANI. The DC conductivity measurements were performed using two-probe method for various temperatures. AC conductivity and dielectric response of the composites were investigated in the frequency range of 102-106Hz using LCR meter. Dielectric permittivity ɛ‧(w) and dielectric loss factor ɛ‧‧(w) were investigated. It was observed that ɛ‧(w) and ɛ‧‧(w) decrease with increase in frequency at all temperatures. At a particular frequency it is observed that both ɛ‧(w) and ɛ‧‧(w) increase with increase in temperature. It was also observed that AC conductivity increased with increase in frequency and temperature.

Thermoluminescent response of LiF:Mg,Ti to 20 keV electrons.

PubMed

Mercado-Uribe, H; Brandan, M E

2002-01-01

The thermoluminescence response of LiF:Mg,Ti (TLD-100) to 20 keV electrons from a scanning electron microscope has been measured. Radiochromic dye films previously calibrated were used to determine the fluence incident on TLD-100 chips. The procedure for irradiation and glow curve deconvolution was adhered to the protocols previously determined in our laboratory for gamma rays and heavy charged particles. The response at electron fluences higher than 4 x 10(10) cm(-2) is supralinear, due to the increasingly relevant contribution of the high temperature peaks. The relative contribution of the high temperature peaks to the TL signal is abnormally small, about half that observed in gamma irradiation and four times smaller than what has been measured in low-energy X ray exposure.

Early events in 2,4,6-trinitrotoluene (TNT) degradation by porphyrins: binding of TNT to porphyrin by hydrophobic and hydrogen bonds.

PubMed

Hikal, Walid M; Harmon, H James

2008-06-15

The interaction of meso-tri(4-sulfonatophenyl)mono(4-carboxyphenyl) porphyrin (C1TPP) with 2,4,6-trinitrotoluene (TNT) has been explored by UV-vis and fluorescence spectroscopy. The influence of temperature on the interaction has also been studied. C1TPP binds to TNT at pH 7.0 at room temperature via 1.94 kcal/mole hydrogen bonds with absorbance loss at 412-413 nm and the appearance of a new peak at 422-424 nm. The hydrogen binding of TNT to C1TPP was confirmed by the dissolution of the complex upon the addition of urea. Increasing the temperature results in the appearance of a new absorbance peak at 540 nm and absorbance loss at 515 nm with activation energy of 29.7 kcal/mole in the range of the hydrophobic bond energy. This suggests the hydrophobic bonding of TNT with the pyrrole nitrogens in the porphyrin. Increasing the concentration of the TNT in the solution quenches the fluorescence of the porphyrin following the Stern-Volmer equation. The association constants calculated from absorbance and fluorescence are expectedly similar.

Cold-induced ependymin expression in zebrafish and carp brain: implications for cold acclimation.

PubMed

Tang, S J; Sun, K H; Sun, G H; Lin, G; Lin, W W; Chuang, M J

1999-10-01

Cold acclimation has been suggested to be mediated by alternations in the gene expression pattern in the cold-adapted fish. To investigate the mechanism of cold acclimation in fish brain at the molecular level, relevant subsets of differentially expressed genes of interest were identified and cloned by the PCR-based subtraction suppression hybridization. Characterization of the selected cold-induced cDNA clones revealed one encoding ependymin. This gene was shown to be brain-specific. The expression of ependymin was induced by a temperature shift from 25 degrees C to 6 degrees C in Cyprinus carpio or 12 degrees C in Danio rerio. Activation of ependymin was detected 2 h after cold exposure and peaked at more than 10-fold at 12 h. This peak level remains unchanged until the temperature returns to 25 degrees C. Although the amount of soluble ependymin protein in brain was not changed by cold treatment, its level in the fibrous insoluble polymers increased 2-fold after exposure to low temperature. These findings indicate that the increase in ependymin expression is an early event that may play an important role in the cold acclimation of fish.

Thermal behaviour of chrome shavings and of sludges recovered after digestion of tanned solid wastes with calcium hydroxide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tahiri, S.; Albizane, A.; Messaoudi, A.

2007-07-01

The thermal behaviour of chrome shavings and of sludges recovered after digestion of tanned wastes with Ca(OH){sub 2} was studied. Ashes obtained after incineration of wastes at various temperatures were analysed by X-ray diffraction and EDX method. The main crystallized phases present in the ash obtained at 600 deg. C are Cr{sub 2}O{sub 3} and NaCl. The diffractograms revealed an increase in the intensities of the chromium oxide peaks and a very notable decrease of the amount of sodium chloride at 1100 deg. C. EDX analysis revealed a total disappearance of the chlorine peak at this temperature. Scanning electron micrographsmore » show that the waste lost its fibrous aspect when the temperature increases. Formation of aggregates was noted after 550 deg. C. Combustion of organic matters and decarbonation phenomenon are the main stages observed on GTA and DTA curves of sludges. These phenomena are, respectively, exothermic and endothermic. The diffractogram of sludges recorded at 550 deg. C, in the presence of a constant oxygen surplus, revealed the presence of CaCrO{sub 4} and CaCO{sub 3}.« less

Efficiency enhancement of blue light emitting diodes by eliminating V-defects from InGaN/GaN multiple quantum well structures through GaN capping layer control

NASA Astrophysics Data System (ADS)

Tsai, Sheng-Chieh; Li, Ming-Jui; Fang, Hsin-Chiao; Tu, Chia-Hao; Liu, Chuan-Pu

2018-05-01

A facile method for fabricating blue light-emitting diodes (B-LEDs) with small embedded quantum dots (QDs) and enhanced light emission is demonstrated by tuning the temperature of the growing GaN capping layer to eliminate V-defects. As the growth temperature increases from 770 °C to 840 °C, not only does the density of the V-defects reduce from 4.12 ∗ 108 #/cm2 nm to zero on a smooth surface, but the QDs also get smaller. Therefore, the growth mechanism of smaller QDs assisted by elimination of V-defects is discussed. Photoluminescence and electroluminescence results show that smaller embedded QDs can improve recombination efficiency, and thus achieve higher peak intensity with smaller peak broadening. Accordingly, the external quantum efficiency of the B-LEDs with smaller QDs is enhanced, leading to a 6.8% increase in light output power in lamp-form package LEDs.

DSC of human hair: a tool for claim support or incorrect data analysis?

PubMed

Popescu, C; Gummer, C

2016-10-01

Differential scanning calorimetry (DSC) data are increasingly used to substantiate product claims of hair repair. Decreasing peak temperatures may indicate structural changes and chemical damage. Increasing the DSC, wet peak temperature is, therefore, often considered as proof of hair repair. A detailed understanding of the technique and hair structure indicates that this may not be a sound approach. Surveying the rich literature on the use of dynamic thermal analysis (DTA) and differential scanning calorimetry (DSC) for the analyses of human hair and the effect of cosmetic treatments, we underline some of the problems of hair structure and data interpretation. To overcome some of the difficulties of data interpretation, we advise that DSC acquired data should be supported by other techniques when used for claim substantiation. In this way, one can provide meaningful interpretation of the hair science and robust data for product claims support. © 2016 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

Study on the laser irradiation characteristics of NEPE propellant in different oxygen concentrations

NASA Astrophysics Data System (ADS)

Xiang, Hengsheng; Chen, Xiong; Zhou, Changsheng

2016-01-01

The ignition and combustion characteristics of nitrate ester plasticized polyether (NEPE) propellant in different oxygen concentrations ambient gases were studied by the application of CO2 laser, infrared thermometer and high speed camera. The flame intensity data of the propellant was collected by the photodiode; propellant flame temperature was measured by infrared thermometer. The experimental results show that the time which NEPE propellant spend to be stable combustion will get shorter with the increase of oxygen concentration; the flame peak temperature measured by infrared thermometer increases with the increase of oxygen concentration when the oxygen concentration is less than 30% by volume, then decreases with the increase of oxygen concentration.

Characterisation of the thermally stimulated conductivity and thermoluminescence of natural topaz.

PubMed

Yukihara, E G; McKeever, S W S; Okuno, E; Yoshimura, E M

2002-01-01

Thermally stimulated conductivity (TSC) and thermoluminescence (TL) measurements were conducted to investigate the mechanisms of charge transfer and luminescence emission in natural samples of Brazilian topaz irradiated with beta particles from a 90Sr/90Y source or with a 1.75 MeV Van de Graaff electron beam. The luminescence and conductivity were simultaneously monitored during the heating of the samples, allowing direct comparison of the TL and TSC peaks. The results show that the three main TL peaks are accompanied by corresponding TSC peaks, usually shifted to higher temperatures. Comparison of the relative TL/TSC intensities of peaks 2 and 3 indicates that the process of thermal quenching of the luminescence is probably active, which is also supported by TL/TSC measurements at different heating rates. Results on the dose response of TL/TSC peaks also reveal an interesting feature: the TL intensity shows a monotonic increase with dose in the range of study (50 Gy-3 kGy) comprising a linear-supralinear-saturation characteristic, while the TSC peaks exhibit an increase from 50 Gy to 1 kGy, followed by a small decrease for doses greater than 1 kGy. This result is interpreted in terms of a model involving multiple traps and one recombination centre.

The phase differences of the interdecadal variabilities of tropical cyclone activity in the peak and late seasons over the western North Pacific

NASA Astrophysics Data System (ADS)

Fan, Tingting; Xu, Shibin; Huang, Fei; Zhao, Jinping

2018-04-01

This study compares the interdecadal variations in tropical cyclone (TC) activities over the western North Pacific (WNP) basin during the peak season (July-September) and late season (October-December) of 1955-2014 and explores the possible physical mechanisms behind the variations. Both the peak- and late-season tropical storm (TS) days show distinct interdecadal variations, while the late-season TS days lead the peak-season TS days by approximately 4 years on an interdecadal time scale. The late-season TC activity is related to the east-west sea surface temperature (SST) gradient across the equatorial Pacific. The westerly winds induced by the SST gradient can reduce the vertical wind shear and increase the low-level vorticity, which favors TC genesis over the TC genesis region. The peak-season TC activity appears to relate to the SST gradient between the Indian Ocean and the Central Pacific. The westerly wind induced by the SST gradient can reduce the vertical wind shear and increase the mid-level relative humidity, thereby enhancing the TC activity. The full picture of the interdecadal variation in the WNP TC activity during the peak and late seasons revealed in this study provides a new perspective on the seasonal TC forecasts and future projections.

Deglacial Warming and Wetting of Northern Alaska

NASA Astrophysics Data System (ADS)

Daniels, W.; Russell, J. M.; Longo, W. M.; Giblin, A. E.; Holland-Stergar, P.; Morrill, C.; Huang, Y.

2015-12-01

Aeolian sand dunes swept across northern Alaska during the last glacial maximum. Today, summer temperatures are moderate and soils can remain waterlogged all summer long. How did the transition from a cold and dry glacial to a warm and wet interglacial take place? To answer this question we reconstructed temperature and precipitation changes during the last deglaciation using biomarker hydrogen isotopes from a new 28,000 year-long sediment core from Lake E5, located in the central Brooks Range of Alaska. We use terrestrial leaf waxes (dDterr, C28-acid), informed by dD measurements of modern vegetation, to infer dD of precipitation, an indicator of relative temperature change. Biomarkers from aquatic organisms (dDaq, C18-acid) are used as a proxy for lake water isotopes. The offset between the two (eterr-aq) is used to infer relative changes in evaporative enrichment of lake water, and by extension, moisture balance. dDterr during the last glacial period was -282‰ compared to -258‰ during the Holocene, suggesting a 5.6 ± 2.7 °C increase in summer temperature using the modern local temperature-dD relationship. Gradual warming began at ~18.5 ka, and temperature increased abruptly at 11.5 ka, at the end of the Younger Dryas. Warming peaked in the early Holocene from 11.5 to 9.1 ka, indicating a Holocene thermal maximum associated with peak summer insolation. The eterr-aq supports a dry LGM and moist Holocene. Other sediment proxies (TIC, TOC, redox-sensitive elements) support the eterr-aq, and reveal a shift to more positive P-E beginning around 17 ka, suggesting rising temperature led increases in precipitation during the last deglaciation. Moreover, differing patterns of dDterr and eterr-aq during the deglaciation suggest that the relationship between temperature and precipitation changed through time. Such decoupling, likely due to regional atmospheric reorganization as the Laurentide ice sheet waned, illustrates the importance of atmospheric dynamics in controlling Alaskan climate.

Thermal controls of Yellowstone cutthroat trout and invasive fishes under climate change

USGS Publications Warehouse

Al-Chokhachy, Robert K.; Alder, Jay R.; Hostetler, Steven W.; Gresswell, Robert E.; Shepard, Bradley

2013-01-01

We combine large observed data sets and dynamically downscaled climate data to explore historic and future (2050–2069) stream temperature changes over the topographically diverse Greater Yellowstone Ecosystem (elevation range = 824–4017 m). We link future stream temperatures with fish growth models to investigate how changing thermal regimes could influence the future distribution and persistence of native Yellowstone cutthroat trout (YCT) and competing invasive species. We find that stream temperatures during the recent decade (2000–2009) surpass the anomalously warm period of the 1930s. Climate simulations indicate air temperatures will warm by 1 °C to >3 °C over the Greater Yellowstone by mid-21st century, resulting in concomitant increases in 2050–2069 peak stream temperatures and protracted periods of warming from May to September (MJJAS). Projected changes in thermal regimes during the MJJAS growing season modify the trajectories of daily growth rates at all elevations with pronounced growth during early and late summer. For high-elevation populations, we find considerable increases in fish body mass attributable both to warming of cold-water temperatures and to extended growing seasons. During peak July to August warming, mid-21st century temperatures will cause periods of increased thermal stress, rendering some low-elevation streams less suitable for YCT. The majority (80%) of sites currently inhabited by YCT, however, display minimal loss (<10%) or positive changes in total body mass by midcentury; we attribute this response to the fact that many low-elevation populations of YCT have already been extirpated by historical changes in land use and invasions of non-native species. Our results further suggest that benefits to YCT populations due to warmer stream temperatures at currently cold sites could be offset by the interspecific effects of corresponding growth of sympatric, non-native species, underscoring the importance of developing climate adaptation strategies that reduce limiting factors such as non-native species and habitat degradation.

Anomalous and non-Gaussian diffusion in Hertzian spheres

NASA Astrophysics Data System (ADS)

Ouyang, Wenze; Sun, Bin; Sun, Zhiwei; Xu, Shenghua

2018-09-01

By means of molecular dynamics simulations, we study the non-Gaussian diffusion in the fluid of Hertzian spheres. The time dependent non-Gaussian parameter, as an indicator of the dynamic heterogeneity, is increased with the increasing of temperature. When the temperature is high enough, the dynamic heterogeneity becomes very significant, and it seems counterintuitive that the maximum of non-Gaussian parameter and the position of its peak decrease monotonically with the increasing of density. By fitting the curves of self intermediate scattering function, we find that the character relaxation time τα is surprisingly not coupled with the time τmax where the non-Gaussian parameter reaches to a maximum. The intriguing features of non-Gaussian diffusion at high enough temperatures can be associated with the weakly correlated mean-field behavior of Hertzian spheres. Especially the time τmax is nearly inversely proportional to the density at extremely high temperatures.

DOE Office of Scientific and Technical Information (OSTI.GOV)

K. L. Davis; J. L. Rempe; D. L. Knudson

Silicon carbide (SiC) temperature monitors 05R4-02-A KG1403 (300 LO) and 05R4-01-A KG1415 (400 LO B) were evaluated at the High Temperature Test Lab (HTTL) to determine their peak irradiation temperatures. HTTL measurements indicate that the peak irradiation temperature for the 300 LO monitor was 295 {+-} 20 C and the peak irradiation temperature for the 400 LO B monitor was 294 {+-} 25 C. Two silicon carbide (SiC) temperature monitors irradiated in the Advanced Test Reactor (ATR) were evaluated at the High Temperature Test Lab (HTTL) to determine their peak temperature during irradiation. These monitors were irradiated as part ofmore » the University of Wisconsin Pilot Project with a target dose of 3 dpa. Temperature monitors were fabricated from high density (3.203 g/cm3) SiC manufactured by Rohm Haas with a nominal size of 12.5 mm x 1.0 mm x 0.75 mm (see Attachment A). Table 1 provides identification for each monitor with an expected peak irradiation temperature range based on preliminary thermal analysis (see Attachment B). Post irradiation calculations are planned to reduce uncertainties in these calculated temperatures. Since the early 1960s, SiC has been used as a post-irradiation temperature monitor. As noted in Reference 2, several researchers have observed that neutron irradiation induced lattice expansion of SiC annealed out when the post-irradiation annealing temperature exceeds the peak irradiation temperature. As noted in Reference 3, INL uses resistivity measurements to infer peak irradiation temperature from SiC monitors. Figure 1 depicts the equipment at the HTTL used to evaluate the SiC monitors. The SiC monitors are heated in the annealing furnace using isochronal temperature steps that, depending on customer needs, can range from 50 to 800 C. This furnace is located under a ventilation hood within the stainless steel enclosure. The ventilation system is activated during heating so that any released vapors are vented through this system. Annealing temperatures are recorded using a National Institute of Standards and Technology (NIST) traceable thermocouple inserted into an alumina tube in the furnace. After each isochronal annealing, the specimens are placed in a specialized fixture located in the constant temperature chamber (maintained at 30 C) for a minimum of 30 minutes. After the 30 minute wait time, each specimen's resistance is measured using the specialized fixture and a calibrated DC power analyzer. This report discusses the evaluation of the SiC monitors and presents the results. Testing was conducted in accordance with Reference 3. Sections 2 and 3 present the data collected for each monitor and provide interpretation of the data. Section 4 presents the evaluated temperature results.« less

Bio-heat transfer model of electroconvulsive therapy: Effect of biological properties on induced temperature variation.

PubMed

de Oliveira, Marilia M; Wen, Paul; Ahfock, Tony

2016-08-01

A realistic human head model consisting of six tissue layers was modelled to investigate the behavior of temperature profile and magnitude when applying electroconvulsive therapy stimulation and different biological properties. The thermo-electrical model was constructed with the use of bio-heat transfer equation and Laplace equation. Three different electrode montages were analyzed as well as the influence of blood perfusion, metabolic heat and electric and thermal conductivity in the scalp. Also, the effect of including the fat layer was investigated. The results showed that temperature increase is inversely proportional to electrical and thermal conductivity increase. Furthermore, the inclusion of blood perfusion slightly drops the peak temperature. Finally, the inclusion of fat is highly recommended in order to acquire more realistic results from the thermo-electrical models.

Controlled growth of heteroepitaxial zinc oxide nanostructures on gallium nitride.

PubMed

Kong, Bo Hyun; Kim, Dong Chan; Mohanta, Sanjay Kumar; Han, Won Suk; Cho, Hyung Koun; Hong, Chang-Hee; Kim, Hyung Gu

2009-07-01

ZnO epitaxial layers were grown on GaN underlying films by metalorganic chemical vapor deposition at various temperatures. An increase in growth temperature led to morphological changes from a smooth film with hexagonal-shaped surface pits to honeycomb-like nanostructures with deep hollow, and additionally resulted in a decrease in dislocation density in the interfacial layers. The reduced dislocation density at the higher growth temperature was attributed to an increase in the size of the critical nucleus and the low nucleation density at the initial stage. The shifts in the peak positions in the X-ray diffraction and photoluminescence were also observed in the samples grown at different temperatures, and were caused by the variation of residual strains after the complete coalescence of the nuclei.

Primary radiation damage characterization of α-iron under irradiation temperature for various PKA energies

NASA Astrophysics Data System (ADS)

Sahi, Qurat-ul-ain; Kim, Yong-Soo

2018-04-01

The understanding of radiation-induced microstructural defects in body-centered cubic (BCC) iron is of major interest to those using advanced steel under extreme conditions in nuclear reactors. In this study, molecular dynamics (MD) simulations were implemented to examine the primary radiation damage in BCC iron with displacement cascades of energy 1, 5, 10, 20, and 30 keV at temperatures ranging from 100 to 1000 K. Statistical analysis of eight MD simulations of collision cascades were carried out along each [110], [112], [111] and a high index [135] direction and the temperature dependence of the surviving number of point defects and the in-cascade clustering of vacancies and interstitials were studied. The peak time and the corresponding number of defects increase with increasing irradiation temperature and primary knock-on atom (PKA) energy. However, the final number of surviving point defects decreases with increasing lattice temperature. This is associated with the increase of thermal spike at high PKA energy and its long timespan at higher temperatures. Defect production efficiency (i.e., surviving MD defects, per Norgett-Robinson-Torrens displacements) also showed a continuous decrease with the increasing irradiation temperature and PKA energy. The number of interstitial clusters increases with both irradiation temperature and PKA energy. However, the increase in the number of vacancy clusters with PKA energy is minimal-to-constant and decreases as the irradiation temperature increases. Similarly, the probability and cluster size distribution for larger interstitials increase with temperature, whereas only smaller size vacancy clusters were observed at higher temperatures.

Mössbauer analysis of the firing process of the sky-green glaze of the imitative ancient Chinese Ru porcelain

NASA Astrophysics Data System (ADS)

Songhua, Chen; Zhengyao, Gao; Guoju, Hu; Xiande, Chen

1994-12-01

The variation of the Mössbauer parameters of the imitative ancient Ru porcelain skygreen glaze with the firing conditions is studied in detail in the present paper. The Mössbauer spectra show that the sky-green glaze contains three kinds of iron minerals, i.e. the structural iron (Fe2+ and Fe3+); Fe2O3 and Fe3O4. The relative intensity of the paramagnetic peak Fe2+ increases and the magnetic ratio of the magnetic peak decreases with increasing temperature. Based on the variation of the quadrupole splitting ( QS) of the paramagnetic peak Fe2+, the phase transformation characteristics of the sky-green glaze in the firing process is discussed. The coloring mechanism of the sky-green glaze and the variation of its magnetism in the firing process are also investigated in the present paper.

Optical and Transport Properties of Energetic Materials

NASA Astrophysics Data System (ADS)

Choi, Chang Sun

1990-01-01

The densities of Hydroxyl ammonium nitrate (HAN) based fast reacting liquids were measured as a function of pressure (up to 4.83 kbars) at several temperatures and the results of density measurements were fit to the Tait equation. Also the shear viscosities of this liquid were measured as a function of both pressure and temperature. The free volume model was applied to explain behavior of the shear viscosity with the assumption that only the reference temperature (T_0) in the Fulcher (1925), WLF (Williams, Landel, and Ferry) and Angell equations depends on pressure. The general relation to predict viscosity of this liquid at any temperature and pressure was derived and the difference between expected and measured values are about 5%. The phase diagrams of the HAN solution, Triethanol ammonium nitrate (TEAN) solution and LP-1845 were obtained through Differential Scanning Calorimetry (DSC) measurements. The TEAN solution has a eutectic temperature in the vicinity of 260^circK. The measured phase diagrams are in good agreement with the calculated phase diagrams. The TEAN solutions show a large supercooling effect. Some phase separation was observed in the TEAN solutions and this separation was believed to be due to eutectic composition of the TEAN solution. The expected freezing temperature of LP-1845 was almost the same with the calculated T_0 from the viscosity data. Raman spectra from the HAN solution, TEAN solution and LP-1845 were measured. Every peak in the spectra was assigned. These solutions show various interactions, such as ion-ion pairing and ion-water interaction. The strongest peak was a NO_3^- symmetric stretch mode at 1050 cm^{-1}. The time correlation functions were calculated from the Raman spectra of the 1050 cm^{-1} peak. The correlation time, which can be calculated from the linewidth, become shorter with decreasing temperatures and with increasing concentrations. The Kubo's stochastic theory explains the correlation functions very well if the solution is relatively dilute. The pressure dependence of the reaction rate was estimated by using the density data and Raman peak shift data.

Temperature effects on snapping performance in the common snapper Chelydra serpentina (Reptilia, Testudines).

PubMed

Vervust, Bart; Brecko, Jonathan; Herrel, Anthony

2011-01-01

Studies on the effect of temperature on whole-animal performance traits other than locomotion are rare. Here we investigate the effects of temperature on the performance of the turtle feeding apparatus in a defensive context. We measured bite force and the kinematics of snapping in the Common Snapping Turtle (Chelydra serpentina) over a wide range of body temperatures. Bite force performance was thermally insensitive over the broad range of temperatures typically experienced by these turtles in nature. In contrast, neck extension (velocity, acceleration, and deceleration) and jaw movements (velocity, acceleration, and deceleration) showed clear temperature dependence with peak acceleration and deceleration capacity increasing with increasing temperatures. Our results regarding the temperature dependence of defensive behavior are reflected by the ecology and overall behavior of this species. These data illustrate the necessity for carefully controlling T(b) when carrying out behavioral and functional studies on turtles as temperature affects the velocity, acceleration, and deceleration of jaw and neck extension movements. More generally, these data add to the limited but increasing number of studies showing that temperature may have important effects on feeding and defensive performance in ectotherms. © 2010 Wiley-Liss, Inc.

The influence of the time of day on core temperature and lower body power output in elite rugby union sevens players.

PubMed

West, Daniel J; Cook, Christian J; Beaven, Martyn C; Kilduff, Liam P

2014-06-01

Core temperature typically displays a low circadian in the morning before peaking later in the day, and these changes occur within small physiological ranges. Body temperature plays an important role in physical performance, and some athletes may be required to train and compete in both the morning and evening. However, the influence of the circadian change in body temperature and its influence on physical performance in elite athletes are unclear. This study examined the effects of the time of day on core temperature and lower body power output in elite rugby union sevens players. Sixteen elite rugby union sevens players completed morning (in AM) countermovement jump and core temperature (Tcore) measurement, which were then repeated later the same day (in PM). Countermovement jump was processed for peak power output (PPO). Data were analyzed using paired samples t-test and Pearson's product moment correlation and are presented in mean ± SD. Tcore significantly increased from AM to PM (AM, 36.92 ± 0.23 vs. PM, 37.18 ± 0.18° C; P < 0.001) with PPO significantly increasing from AM to PM in all 16 players (AM, 5248 ± 366 vs. PM, 5413 ± 361 W; P < 0.001). The delta change in Tcore (0.26 ± 0.13° C) and PPO (164 ± 78 W) was significantly related (r = 0.781; P < 0.001). In conclusion, small circadian changes in core temperature can influence physical performance in elite athletes. Coaches should seek to use strategies, which may raise morning body temperature to offset the circadian low in the morning.

Effect of spin-orbit coupling on excitonic levels in layered chalcogenide-fluorides

NASA Astrophysics Data System (ADS)

Zakutayev, Andriy; Kykyneshi, Robert; Kinney, Joseph; McIntyre, David H.; Schneider, Guenter; Tate, Janet

2008-03-01

BaCuChF (Ch=S,Se,Te) comprise a family of wide-bandgap p-type semiconductors. Due to their high transparency and conductivity, they have potential applications as components of transparent thin-film transistors, solar cells and light-emitting devices. Thin films of BaCuChF have been deposited on MgO by pulsed laser deposition (PLD). Solid solutions BaCuS1-xSexTeF and BaCuSe1-xTex have been prepared by PLD of alternating thin BaCuChF layers. All films were deposited at elevated substrate temperatures. They are preferentially c-axis oriented, conductive and transparent in the visible part of the spectrum. Double excitonic peaks have been observed in the absorption spectrum of these films in the temperature range from 80 to 300K. The separation between the peaks in the doublet increases with the increase of atomic mass of the chalcogen. It also increases with the increase of the heavy chalcogen component x in the solid solutions. This separation most likely is caused by the effect of spin-orbit coupling in the chalcogen atoms on excitonic levels in BaCuChF.

Microstructure-mechanical property relationships for Al-Cu-Li-Zr alloys with minor additions of cadmium, indium or tin

NASA Technical Reports Server (NTRS)

Blackburn, L. B.; Starke, E. A., Jr.

1989-01-01

Minor amounts of cadmium, indium or tin were added to a baseline alloy with the nominal composition of Al-2.4Cu-2.4Li-0.15Zr. These elements were added in an attempt to increase the age-hardening response of the material such that high strengths could be achieved through heat-treatment alone, without the need for intermediate mechanical working. The alloy variant containing indium achieved a higher peak hardness in comparison to the other alloy variations, including the baseline material, when aged at temperatures ranging from 160 C to 190 C. Tensile tests on specimens peak-aged at 160 indicated the yield strength of the indium-bearing alloy increased by approximately 15 percent compared to that of the peak-aged baseline alloy. In addition, the yield strength obtained in the indium-bearing alloy was comparable to that reported for similar baseline material subjected to a 6 percent stretch prior to peak-aging at 190 C. The higher strength levels obtaied for the indium-bearing alloy are attributed to increased number densities and homogeneity of both the T1 and theta-prime phases, as determined by TEM studies.

Thermoluminescence and the shock and reheating history of meteorites. III - The shergottites

NASA Technical Reports Server (NTRS)

Hasan, F. A.; Haq, M.; Sears, D. W. G.

1986-01-01

Thermoluminescence (TL) measurements on Shergotty, ALHA 77005, Zagami, and EETA 79001 (lithology A) have been used to obtain further information on the shock history of these meteorites. The level of TL sensitivity in the shergottites varied by a factor of 10, but was always low, probably reflecting the amount of crystalline material in the maskelynite. There are trends in the TL peak temperature, peak width, and TL sensitivity which are believed to be associated with different proportions of feldspar in high- and low-temperature forms. This interpretation is consistent with the observed changes induced in the TL properties by annealing shergottites at 400-900 C. It is suggested that the observed trends were produced during postshock crystallization at a variety of cooling rates, the increasing order of cooling rate being EETA 79001, Zagami, ALHA 77005, and Shergotty, and that there is high-temperature feldspar present in all the samples. This implies a postshock temperature above 600 C, and a small (less than 10 m) size of the ejecta. Current theories are well able to explain how objects of this size could have been ejected from Mars.

Correlation between optical properties surface morphology of porous silicon electrodeposited by Fe3+ ion

NASA Astrophysics Data System (ADS)

Mabrouk, Asma; Lorrain, N.; Haji, M. L.; Oueslati, Meherzi

2015-01-01

In this paper, we analyze the photoluminescence spectra (PL) of porous silicon (PS) layer which is elaborated by electrochemical etching and passivated by Fe3+ ions (PSF) via current density, electro-deposition and temperature measurements. We observe unusual surface morphology of PSF surface and anomalous emission behavior. The PSF surface shows regular distribution of cracks, leaving isolated regions or ;platelets; of nearly uniform thickness. These cracks become more pronounced for high current densities. The temperature dependence of the PL peak energy (EPL) presents anomalous behaviors, i.e., the PL peak energy shows a successive red/blue/redshift (S-shaped behavior) with increasing temperature that we attribute to the existence of strong potential fluctuations induced by the electrochemical etching of PS layers. A competition process between localized and delocalized excitons is used to discuss these PL properties. In this case, the potential confinement plays a key role on the enhancement of PL intensity in PSF. To explain the temperature dependence of the PL intensity, we have proposed a recombination model based on the tunneling and dissociation of excitons.

Modulating optical rectification, second and third harmonic generation of doped quantum dots: Interplay between hydrostatic pressure, temperature and noise

NASA Astrophysics Data System (ADS)

Ganguly, Jayanta; Saha, Surajit; Bera, Aindrila; Ghosh, Manas

2016-10-01

We examine the profiles of optical rectification (OR), second harmonic generation (SHG) and third harmonic generation (THG) of impurity doped QDs under the combined influence of hydrostatic pressure (HP) and temperature (T) in presence and absence of Gaussian white noise. Noise has been incorporated to the system additively and multiplicatively. In order to study the above nonlinear optical (NLO) properties the doped dot has been subjected to a polarized monochromatic electromagnetic field. Effect of application of noise is nicely reflected through alteration of peak shift (blue/red) and variation of peak height (increase/decrease) of above NLO properties as temperature and pressure are varied. All such changes again sensitively depends on mode of application (additive/multiplicative) of noise. The remarkable influence of interplay between noise strength and its mode of application on the said profiles has also been addressed. The findings illuminate fascinating role played by noise in tuning above NLO properties of doped QD system under the active presence of both hydrostatic pressure and temperature.

Ion mobility spectrometric analysis of vaporous chemical warfare agents by the instrument with corona discharge ionization ammonia dopant ambient temperature operation.

PubMed

Satoh, Takafumi; Kishi, Shintaro; Nagashima, Hisayuki; Tachikawa, Masumi; Kanamori-Kataoka, Mieko; Nakagawa, Takao; Kitagawa, Nobuyoshi; Tokita, Kenichi; Yamamoto, Soichiro; Seto, Yasuo

2015-03-20

The ion mobility behavior of nineteen chemical warfare agents (7 nerve gases, 5 blister agents, 2 lachrymators, 2 blood agents, 3 choking agents) and related compounds including simulants (8 agents) and organic solvents (39) was comparably investigated by the ion mobility spectrometry instrument utilizing weak electric field linear drift tube with corona discharge ionization, ammonia doping, purified inner air drift flow circulation operated at ambient temperature and pressure. Three alkyl methylphosphonofluoridates, tabun, and four organophosphorus simulants gave the intense characteristic positive monomer-derived ion peaks and small dimer-derived ion peaks, and the later ion peaks were increased with the vapor concentrations. VX, RVX and tabun gave both characteristic positive monomer-derived ions and degradation product ions. Nitrogen mustards gave the intense characteristic positive ion peaks, and in addition distinctive negative ion peak appeared from HN3. Mustard gas, lewisite 1, o-chlorobenzylidenemalononitrile and 2-mercaptoethanol gave the characteristic negative ion peaks. Methylphosphonyl difluoride, 2-chloroacetophenone and 1,4-thioxane gave the characteristic ion peaks both in the positive and negative ion mode. 2-Chloroethylethylsulfide and allylisothiocyanate gave weak ion peaks. The marker ion peaks derived from two blood agents and three choking agents were very close to the reactant ion peak in negative ion mode and the respective reduced ion mobility was fluctuated. The reduced ion mobility of the CWA monomer-derived peaks were positively correlated with molecular masses among structurally similar agents such as G-type nerve gases and organophosphorus simulants; V-type nerve gases and nitrogen mustards. The slope values of the calibration plots of the peak heights of the characteristic marker ions versus the vapor concentrations are related to the detection sensitivity, and within chemical warfare agents examined the slope values for sarin, soman, tabun and nitrogen mustards were higher. Some CWA simulants and organic solvents gave the ion peaks eluting at the similar positions of the CWAs, resulting in false positive alarms. Copyright © 2015 Elsevier B.V. All rights reserved.

Temperature-dependent photoluminescence study of InP/ZnS quantum dots

NASA Astrophysics Data System (ADS)

Thuy Pham, Thi; Tran, Thi Kim Chi; Liem Nguyen, Quang

2011-06-01

This paper reports on the temperature-dependent photoluminescence of InP/ZnS quantum dots under 532 nm excitation, which is above the InP transition energy but well below that of ZnS. The overall photoluminescence spectra show two spectral components. The higher-energy one (named X) is assigned to originate from the excitonic transition; while the low-energy spectral component (named I) is normally interpreted as resulting from lattice imperfections in the crystalline structure of InP/ZnS quantum dots (QDs). Peak positions of both the X and I emissions vary similarly with increasing temperature and the same as the InP bandgap narrowing with temperature. In the temperature range from 15 to 80 K, the ratio of the integrated intensity from the X and the I emissions decreases gradually and then this ratio increases fast at temperatures higher than 80 K. This could result from a population of charge carriers in the lattice imperfection states at a temperature below 80 K to increase the I emission but then with these charge carriers being released to contribute to the X emission.

The Pasting and Gel Textural Properties of Corn Starch in Glucose, Fructose and Maltose Syrup

PubMed Central

Sun, Qingjie; Xing, Yan; Qiu, Chao; Xiong, Liu

2014-01-01

The pasting and gel textural properties of corn starch in syrup at different concentrations were investigated by Rapid Visco Analyzer (RVA) and Texture profile analysis (TPA) tests. The results showed that the pasting temperatures of corn starch greatly increased, especially at higher sugar concentration. Increasing concentration of syrup caused an increase in peak, trough and final viscosity of corn starch. Peak viscosity and the disintegration rate of starch increased in the following order: fructose syrup> maltose syrup> glucose syrup. Increasing syrup concentration to 13%, 25% and 50% resulted in a lower retrogradation rate than the control. When the maltose syrup concentration increased to 50%, the retrogradation rate decreased to 14.30% from 33.38%. The highest hardness was observed when the syrup concentration was 25%. There was a particular low hardness when the concentration of syrup was 50%. The springiness of starch gels in syrup was similar at different concentrations. PMID:24755772

The pasting and gel textural properties of corn starch in glucose, fructose and maltose syrup.

PubMed

Sun, Qingjie; Xing, Yan; Qiu, Chao; Xiong, Liu

2014-01-01

The pasting and gel textural properties of corn starch in syrup at different concentrations were investigated by Rapid Visco Analyzer (RVA) and Texture profile analysis (TPA) tests. The results showed that the pasting temperatures of corn starch greatly increased, especially at higher sugar concentration. Increasing concentration of syrup caused an increase in peak, trough and final viscosity of corn starch. Peak viscosity and the disintegration rate of starch increased in the following order: fructose syrup> maltose syrup> glucose syrup. Increasing syrup concentration to 13%, 25% and 50% resulted in a lower retrogradation rate than the control. When the maltose syrup concentration increased to 50%, the retrogradation rate decreased to 14.30% from 33.38%. The highest hardness was observed when the syrup concentration was 25%. There was a particular low hardness when the concentration of syrup was 50%. The springiness of starch gels in syrup was similar at different concentrations.

Photoluminescence study of ZnS and ZnS:Pb nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Virpal,, E-mail: virpalsharma.sharma@gmail.com; Hastir, Anita; Kaur, Jasmeet

2015-05-15

Photoluminescence (PL) study of pure and 5wt. % lead doped ZnS prepared by co-precipitation method was conducted at room temperature. The prepared nanoparticles were characterized by X-ray Diffraction (XRD), UV-Visible (UV-Vis) spectrophotometer, Photoluminescence (PL) and Raman spectroscopy. XRD patterns confirm cubic structure of ZnS and PbS in doped sample. The band gap energy value increased in case of Pb doped ZnS nanoparticles. The PL spectrum of pure ZnS was de-convoluted into two peaks centered at 399nm and 441nm which were attributed to defect states of ZnS. In doped sample, a shoulder peak at 389nm and a broad peak centered atmore » 505nm were observed. This broad green emission peak originated due to Pb activated ZnS states.« less

On use of CO{sub 2} chemiluminescence for combustion metrics in natural gas fired reciprocating engines.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gupta, S. B.; Bihari, B.; Biruduganti, M.

Flame chemiluminescence is widely acknowledged to be an indicator of heat release rate in premixed turbulent flames that are representative of gas turbine combustion. Though heat release rate is an important metric for evaluating combustion strategies in reciprocating engine systems, its correlation with flame chemiluminescence is not well studied. To address this gap an experimental study was carried out in a single-cylinder natural gas fired reciprocating engine that could simulate turbocharged conditions with exhaust gas recirculation. Crank angle resolved spectra (266-795 nm) of flame luminosity were measured for various operational conditions by varying the ignition timing for MBT conditions andmore » by holding the speed at 1800 rpm and Brake Mean effective Pressure (BMEP) at 12 bar. The effect of dilution on CO*{sub 2}chemiluminescence intensities was studied, by varying the global equivalence ratio (0.6-1.0) and by varying the exhaust gas recirculation rate. It was attempted to relate the measured chemiluminescence intensities to thermodynamic metrics of importance to engine research -- in-cylinder bulk gas temperature and heat release rate (HRR) calculated from measured cylinder pressure signals. The peak of the measured CO*{sub 2} chemiluminescence intensities coincided with peak pressures within {+-}2 CAD for all test conditions. For each combustion cycle, the peaks of heat release rate, spectral intensity and temperature occurred in that sequence, well separated temporally. The peak heat release rates preceded the peak chemiluminescent emissions by 3.8-9.5 CAD, whereas the peak temperatures trailed by 5.8-15.6 CAD. Such a temporal separation precludes correlations on a crank-angle resolved basis. However, the peak cycle heat release rates and to a lesser extent the peak cycle temperatures correlated well with the chemiluminescent emission from CO*{sub 2}. Such observations point towards the potential use of flame chemiluminescence to monitor peak bulk gas temperatures as well as peak heat release rates in natural gas fired reciprocating engines.« less

Effect of Co doping concentration on structural properties and optical parameters of Co-doped ZnO thin films by sol-gel dip-coating method.

PubMed

Nam, Giwoong; Yoon, Hyunsik; Kim, Byunggu; Lee, Dong-Yul; Kim, Jong Su; Leem, Jae-Young

2014-11-01

The structural and optical properties of Co-doped ZnO thin films prepared by a sol-gel dip-coating method were investigated. X-ray diffraction analysis showed that the thin films were grown with a c-axis preferred orientation. The position of the (002) peak was almost the same in all samples, irrespective of the Co concentration. It is thus clear that Co doping had little effect on the position of the (002) peak. To confirm that Co2+ was substituted for Zn2+ in the wurtzite structure, optical measurements were conducted at room temperature by a UV-visible spectrometer. Three absorption peaks are apparent in the Co-doped ZnO thin films that do not appear for the undoped ZnO thin film. As the Co concentration was increased, absorption related to characteristic Co2+ transitions increased because three absorption band intensities and the area underneath the absorption wells between 500 and 700 nm increased with increasing Co concentration. The optical band gap and static dielectric constant decreased and the Urbach energy and extinction coefficient increased with increasing Co concentration.

Raman and infrared studies of nucleosides at high pressures: II. Cytidine.

PubMed

Li, J; Lee, S A; Pinnick, D A; Anderson, A; Smith, W; Griffey, R H; Mohan, V

2002-06-01

Raman and mid-infrared (MIR) spectra have been recorded for crystalline cytidine at pressures up to 10 GPa at room temperature. Broadening and positive wavenumber shifts are observed for most of the Raman and MIR peaks with increasing pressure. However, some of the MIR peaks associated with hydrogen-stretching modes display a negative wavenumber shift as a result of charge transfer effects. Evidence of a phase transition near 4 GPa is presented and attributed to a change in the conformation of the five membered sugar ring.

Temperature dependent viscosity of cobalt ferrite / ethylene glycol ferrofluids

NASA Astrophysics Data System (ADS)

Kharat, Prashant B.; Somvanshi, Sandeep B.; Kounsalye, Jitendra S.; Deshmukh, Suraj S.; Khirade, Pankaj P.; Jadhav, K. M.

2018-04-01

In the present work, cobalt ferrite / ethylene glycol ferrofluid is prepared in 0 to 1 (in the step of 0.2) volume fraction of cobalt ferrite nanoparticles synthesized by co-precipitation method. The XRD results confirmed the formation of single phase spinel structure. The Raman spectra have been deconvoluted into individual Lorentzian peaks. Cobalt ferrite has cubic spinel structure with Fd3m space group. FT-IR spectra consist of two major absorption bands, first at about 586 cm-1 (υ1) and second at about 392 cm-1 (υ2). These absorption bands confirm the formation of spinel-structured cobalt ferrite. Brookfield DV-III viscometer and programmable temperature-controlled bath was used to study the relationship between viscosity and temperature. Viscosity behavior with respect to temperature has been studied and it is revealed that the viscosity of cobalt ferrite / ethylene glycol ferrofluids increases with an increase in volume fraction of cobalt ferrite. The viscosity of the present ferrofluid was found to decrease with increase in temperature.

Electronic structure and thermoelectric transport properties of the golden Th{sub 2}S{sub 3}-type Ti{sub 2}O{sub 3} under pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Bin, E-mail: hnsqxubin@163.com; Gao, Changzheng; Zhang, Jing

2016-05-15

A lot of physical properties of Th{sub 2}S{sub 3}-type Ti{sub 2}O{sub 3} have investigated experimentally, hence, we calculated electronic structure and thermoelectric transport properties by the first-principles calculation under pressure. The increase of the band gaps is very fast from 30 GPa to 35 GPa, which is mainly because of the rapid change of the lattice constants. The total density of states becomes smaller with increasing pressure, which shows that Seebeck coefficient gradually decreases. Two main peaks of Seebeck coefficients always decrease and shift to the high doping area with increasing temperature under pressure. The electrical conductivities always decrease withmore » increasing temperature under pressure. The electrical conductivity can be improved by increasing pressure. Electronic thermal conductivity increases with increasing pressure. It is noted that the thermoelectric properties is reduced with increasing temperature.« less

Solid State Reduction of MoO3 with Carbon via Mechanical Alloying to Synthesize Nano-Crystaline MoO2

NASA Astrophysics Data System (ADS)

Saghafi, M.; Ataie, A.; Heshmati-Manesh, S.

In this research, effect of milling time on solid state reduction of MoO3 with carbon has been investigated. It was found that mechanical activation of a mixture of MoO3 and carbon at ambient temperature by high energy ball milling was not able to reduce MoO3 to metallic molybdenum. MoO3 was converted to MoO2 at the first stage of reduction and peaks of the latter phase in X-ray diffraction patterns were detected when the milling time exceeded from 50 hours. The main effect of increased milling time at this stage was decreasing of MoO3 peak intensities and significant peak broadening due to decrease in size of crystallites. After prolonged milling, MoO3 was fully reduced to nano-crystalline MoO2 and its mean crystallite size was calculated using Williamson-Hall technique and found to be 17.5 nm. Thermodynamic investigations also confirm the possibility of reduction of MoO3 to MoO2 during the milling operation at room temperature. But, further reduction to metallic molybdenum requires thermal activation at higher temperature near 1100 K. XRD and SEM techniques were employed to evaluate the powder particles characteristics.

Study of thermoluminescence response of purple to violet amethyst quartz from Balikesir, Turkey

NASA Astrophysics Data System (ADS)

Nur, N.; Yeğingil, Z.; Topaksu, M.; Kurt, K.; Doğan, T.; Sarıgül, N.; Yüksel, M.; Altunal, V.; Özdemir, A.; Güçkan, V.; Günay, I.

2015-09-01

In thermoluminescence (TL) dosimetry, the phosphor amethyst quartz as a thermoluminescent, appears to be one of the materials arousing the highest interest. In this study the dosimetric characteristics of natural amethyst quartz crystals collected from Balikesir-Dursunbey (Turkey) were investigated for the purpose of determination of the general properties that phosphors should have in order to be useful for thermoluminescence dosimetry. The natural thermoluminescence was drained by annealing the powder samples at 450 °C for 1.5 h. The effects of high temperature annealing, dose response curves, glow curves after a postirradiation annealing, reusability of the samples and storage of trapped electrons in dark at room temperature were clarified through irradiating the samples with the desired exposures by 90Sr/90Y beta particles. Isothermal annealing before and after irradiation was found to have a definite effect upon the TL glow curve of amethyst crystal powder. The same sample varied in sensitivity depending upon its previous thermal and radiation history. The peak heights of the glow peaks were examined with respect to dose response at dose levels between 1 Gy and 5 kGy. The intermediate temperature (IT) and high temperature (HT) peaks of 230 °C and 300 °C, respectively, exhibit dose-response curves as superlinear when dose is on the logarithmic scale except the dose response of 300 °C peak for the dose values of 1 < D < 20 Gy in which linear dose response was acquired. At the end of the storage time between exposure and readout which was about one month at room temperature, the emitted light reduction was 14% comparing to the initial state. Repeating the measurements of the same sample, exposed with 0.1, 0.5, 0.8 and 1 kGy beta exposures, resulted in between 4% and 11% increase in the TL sensitivity of the material.

Association between weather conditions and the number of patients at the emergency room in an Argentine hospital

NASA Astrophysics Data System (ADS)

Rusticucci, Matilde; Bettolli, Laura M.; de los Angeles Harris, M.

2002-02-01

The aim of this paper is to study the relationships between hospital emergencies and weather conditions by analysing summer and winter cases of patients requiring attention at the emergency room of a hospital in the city of Buenos Aires, Argentina. Hospital data have been sorted into seven different diagnostic groups as follows: (1) respiratory, cardiovascular and chest-pain complaints; (2) digestive, genitourinary and abdominal complaints; (3) neurological and psychopathological disorders; (4) infections; (5) contusion and crushing, bone and muscle complaints; (6) skin and allergies and (7) miscellaneous complaints. In general, there is an increase of 16.7% in winter while, for group 2 and group 6, there are more patients in summer, 54% and 75% respectively. In summer, the total number of patients for group 6 shows a significant positive correlation with temperature and dew-point temperature, and a negative correlation with the sea-level pressure for the same day. In winter, the same relationship exists, however its correlation is not as strong. The lags observed between these three variables: maximum dew-point temperature, maximum temperature, minimum air pressure and the peaks in admissions are 1, 2 and 4 days respectively. In winter, increases in temperature and dew point and decreases in pressure are followed by a peak in admissions for group 2. In winter, there are significantly more cases in group 5 on warm, dry days and on warm, wet days in the summer.

Hidden amorphous phase and reentrant supercooled liquid in Pd-Ni-P metallic glasses

DOE PAGES

Lan, S.; Ren, Y.; Wei, X. Y.; ...

2017-03-17

An anomaly in differential scanning calorimetry has been reported in a number of metallic glass materials in which a broad exothermal peak was observed between the glass and crystallization temperatures. The mystery surrounding this calorimetric anomaly is epitomized by four decades long studies of Pd-Ni-P metallic glasses, arguably the best glass-forming alloys. Here we show, using a suite of in-situ experimental techniques, that Pd-Ni-P alloys have a hidden amorphous phase in the supercooled liquid region. The anomalous exothermal peak is the consequence of a polyamorphous phase transition between two supercooled liquids, involving a change in the packing of atomic clustersmore » over medium-range length scales as large as 18 Å. With further temperature increase, the alloy reenters the supercooled liquid phase which forms the room-temperature glass phase upon quenching. Finally, the outcome of this study raises a possibility to manipulate the structure and hence the stability of metallic glasses through heat-treatment.« less

Measurement of curvature and temperature using multimode interference devices

NASA Astrophysics Data System (ADS)

Guzman-Sepulveda, J. R.; Aguilar-Soto, J. G.; Torres-Cisneros, M.; Ibarra-Manzano, O. G.; May-Arrioja, D. A.

2011-09-01

In this paper we propose the fabrication, implementation, and testing of a novel fiber optic sensor based on Multimode Interference (MMI) effects for independent measurement of curvature and temperature. The development of fiber based MMI devices is relatively new and since they exhibit a band-pass filter response they can be used in different applications. The operating mechanism of our sensor is based on the self-imaging phenomena that occur in multimode fibers (MMF), which is related to the interference of the propagating modes and their accumulated phase. We demonstrate that the peak wavelength shifts with temperature variations as a result of changes in the accumulated phase through thermo-optics effects, while the intensity of the peak wavelength is reduced as the curvature increases since we start to loss higher order modes. In this way both measurements are obtained independently with a single fiber device. Compared to other fiber-optic sensors, our sensor features an extremely simple structure and fabrication process, and hence cost effectiveness.

Heat acclimation attenuates physiological strain and the HSP72, but not HSP90α, mRNA response to acute normobaric hypoxia.

PubMed

Gibson, Oliver R; Turner, Gareth; Tuttle, James A; Taylor, Lee; Watt, Peter W; Maxwell, Neil S

2015-10-15

Heat acclimation (HA) attenuates physiological strain in hot conditions via phenotypic and cellular adaptation. The aim of this study was to determine whether HA reduced physiological strain, and heat shock protein (HSP) 72 and HSP90α mRNA responses in acute normobaric hypoxia. Sixteen male participants completed ten 90-min sessions of isothermic HA (40°C/40% relative humidity) or exercise training [control (CON); 20°C/40% relative humidity]. HA or CON were preceded (HYP1) and proceeded (HYP2) by a 30-min normobaric hypoxic exposure [inspired O2 fraction = 0.12; 10-min rest, 10-min cycling at 40% peak O2 uptake (V̇O2 peak), 10-min cycling at 65% V̇O2 peak]. HA induced greater rectal temperatures, sweat rate, and heart rates (HR) than CON during the training sessions. HA, but not CON, reduced resting rectal temperatures and resting HR and increased sweat rate and plasma volume. Hemoglobin mass did not change following HA nor CON. HSP72 and HSP90α mRNA increased in response to each HA session, but did not change with CON. HR during HYP2 was lower and O2 saturation higher at 65% V̇O2 peak following HA, but not CON. O2 uptake/HR was greater at rest and 65% V̇O2 peak in HYP2 following HA, but was unchanged after CON. At rest, the respiratory exchange ratio was reduced during HYP2 following HA, but not CON. The increase in HSP72 mRNA during HYP1 did not occur in HYP2 following HA. In CON, HSP72 mRNA expression was unchanged during HYP1 and HYP2. In HA and CON, increases in HSP90α mRNA during HYP1 were maintained in HYP2. HA reduces physiological strain, and the transcription of HSP72, but not HSP90α mRNA in acute normobaric hypoxia. Copyright © 2015 the American Physiological Society.

Effects of dormancy progression and low-temperature response on changes in the sorbitol concentration in xylem sap of Japanese pear during winter season.

PubMed

Ito, Akiko; Sugiura, Toshihiko; Sakamoto, Daisuke; Moriguchi, Takaya

2013-04-01

In order to elucidate which physiological event(s) are involved in the seasonal changes of carbohydrate dynamics during winter, we examined the effects of different low temperatures on the carbohydrate concentrations of Japanese pear (Pyrus pyrifolia (Burm.) Nakai). For four winter seasons, large increases in the sorbitol concentration of shoot xylem sap occurred during mid- to late December, possibly due to the endodormancy completion and low-temperature responses. When trees were kept at 15 °C from 3 November to 3 December in order to postpone the initiation and completion of chilling accumulation that would break endodormancy, sorbitol accumulation in xylem sap was always higher from trees with sufficient chilling accumulation than from trees that received insufficient chilling. However, an additional increase in xylem sap sorbitol occurred around late December in trees regardless of whether their chilling accumulation naturally progressed or was postponed. To examine different temperature effects more closely, we compared the carbohydrate concentrations of trees subjected to either 6 or 0 °C treatment. The sorbitol concentration in xylem sap tremendously increased at 0 °C treatment compared with 6 °C treatment. However, an additional increase in xylem sap sorbitol occurred at both the temperatures when sufficient chilling accumulated with a peak coinciding with the peak expression in shoots of the sorbitol transporter gene (PpSOT2). Interestingly, the total carbohydrate concentration of shoots tremendously increased with exposure to 0 °C compared with exposure to 6 °C, but was not affected by the amount of accumulated chilling. Instead, as chilling accumulated the ratio of sorbitol to total soluble sugars in shoots increased. We presumed that carbohydrates in the shoot tissues may be converted to sorbitol and loaded into the xylem sap so that the sorbitol accumulation patterns were synchronized with the progression of dormancy, whereas the total carbohydrate transported into shoots from other storage organs may be related to freezing tolerance acquisition independent of dormancy progression. We thus propose that there are different effects of dormancy progression and low-temperature responses on carbohydrate dynamics in Japanese pear.

Body temperature - a marker of infarct size in the era of early reperfusion.

PubMed

Ben-Dor, Itsik; Haim, Moti; Rechavia, Eldad; Murininkas, Daniel; Nahon, Merav; Harell, Daniella; Porter, Avital; Iakobishvili, Zaza; Scapa, Erez; Battler, Alexander; Hasdai, David

2005-01-01

We measured body temperature in 40 consecutive patients treated for a first ST elevation acute myocardial infarction (AMI) with primary percutaneous coronary interventions. Left ventricular function was assessed by echocardiography, and blood samples were drawn for highly sensitive C-reactive protein (hs-CRP), white blood cell (WBC) count, fibrinogen, creatine kinase (CK), and cardiac troponin I levels (cTnI). The median (25th, 75th quartiles) peak 24-hour temperature was 37.4 degrees C (36.9 degrees C, 37.6 degrees C). Variables significantly associated with peak 24-hour temperature were CK (p = 0.01, r = 0.42), wall motion index (p = 0.01, r = 0.41), hs-CRP (p = 0.01, r = 0.41), and cTnI (p = 0.03, r = 0.35). There was no significant correlation between peak 24-hour temperature and WBC count (p = 0.39, r = 0.14) and fibrinogen (p = 0.12, r = 0.21). Thus, peak 24-hour body temperature after ST elevation AMI probably reflects infarct size rather than a nonspecific inflammatory response. Copyright 2005 S. Karger AG, Basel.

Malleable Curie Temperatures of Natural Titanomagnetites: Occurrences, Modes, and Mechanisms

NASA Astrophysics Data System (ADS)

Jackson, Mike; Bowles, Julie

2018-02-01

Intermediate-composition titanomagnetites have Curie temperatures (Tc) that depend not only on composition but also on thermal history, with increases of 100°C or more in Tc produced by moderate-temperature (300-400°C) annealing in the laboratory or in slow natural cooling and comparable decreases produced by more rapid cooling ("quenching") from higher temperatures. New samples spanning a range of titanomagnetite compositions exhibit reversible changes in Tc comparable to those previously documented for pyroclastic samples from Mt. St. Helens and Novarupta. Additional high- and low-temperature measurements help to shed light on the nanoscale mechanisms responsible for the observed changes in Tc. High-T hysteresis measurements exhibit a peak in high-field slope khf(T) at the Curie temperature, and the peak magnitude decreases as Tc increases with annealing. Sharp changes in low-T magnetic behavior are also strongly affected by prior annealing or quenching, suggesting that these treatments affect the intrasite cation distributions. We have examined the effects of oxidation state and nonstoichiometry on the magnitude of Tc changes produced by quenching/annealing in different atmospheres. Treatments in air generally cause large changes (ΔTc > 100°). In an inert atmosphere, the changes are similar in many samples but strongly diminished in others. When the samples are embedded in a reducing material, ΔTc becomes insignificant. These results strongly suggest that cation vacancies play an essential role in the cation rearrangements responsible for the observed changes in Tc. Some form of octahedral-site chemical clustering or short-range ordering appears to be the best way to explain the large observed changes in Tc.

Ion irradiation studies on the void swelling behavior of a titanium modified D9 alloy

NASA Astrophysics Data System (ADS)

Balaji, S.; Mohan, Sruthi; Amirthapandian, S.; Chinnathambi, S.; David, C.; Panigrahi, B. K.

2015-12-01

The sensitivity of Positron Annihilation Spectroscopy (PAS) for probing vacancy defects and their environment is well known. Its applicability in determination of swelling and the peak swelling temperature was put to test in our earlier work on ion irradiated D9 alloys [1]. Upon comparison with the peak swelling temperature determined by conventional step height measurements it was found that the peak swelling temperature determined using PAS was 50 K higher. It was conjectured that the positrons trapping in the irradiation induced TiC precipitation could have caused the shift. In the present work, D9 alloys have been implanted with 100 appm helium ions and subsequently implanted with 2.5 MeV Ni ions up to peak damage of 100 dpa. The nickel implantations have been carried out through a range of temperatures between 450 °C and 650 °C. The evolution of cavities and TiC precipitates at various temperatures has been followed by TEM and this report provides an experimental verification of the conjecture.

Quantifying impacts of heat waves on power grid operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ke, Xinda; Wu, Di; Rice, Jennie S.

Climate change is projected to cause an increase in the severity and frequency of extreme weather events such as heat waves and droughts. Such changes present planning and operating challenges and risks to many economic sectors. In the electricity sector, statistics of extreme events in the past have been used to help plan for future peak loads, determine associated infrastructure requirements, and evaluate operational risks, but industry-standard planning tools have yet to be coupled with or informed by temperature models to explore the impacts of the "new normal" on planning studies. For example, high ambient temperatures during heat waves reducemore » the output capacity and efficiency of gas fired combustion turbines just when they are needed most to meet peak demands. This paper describes the development and application of a production cost and unit commitment model coupled to high resolution, hourly temperature data and a temperature dependent load model. The coupled system has the ability to represent the impacts of hourly temperatures on load conditions and available capacity and efficiency of combustion turbines, and therefore capture the potential impacts on system reliability and production cost. Ongoing work expands this capability to address the impacts of water availability and temperature on power grid operation.« less

Discharge mode transition and temporal-spatial evolution of an air-water plasma jet generated by pulsating DC power

NASA Astrophysics Data System (ADS)

Lei, J.; Geng, Y.; Liu, K.; Zhu, W.; Zheng, Z.; Hu, H.

2017-12-01

In this paper, pulsating direct current air-water plasma jet, which can increase the production of •OH and decrease the temperature, is studied. The results show that the discharge mode changes in one cycle from corona discharge with steep Trichel current pulse to glow-like discharge. It is unknown whether the different discharge modes and water ratio have an effect on the transient process of the excited O and •OH production and the mechanism of plasma propagation. So, a series of experiments are done in this paper. The results show that the changing rules of both the excited state O and the discharge current reach their two peak values synchronously. And its maximum appears at the time of the first peak current value in corona mode. However, the change of the excited state •OH is different. It increases to its maximum at the time of the second peak current value in glow-like mode. Besides, the intensified charge coupled device photographs show that the luminous intensity of the discharge zone at the first peak current value in corona mode is stronger than the second peak current value in glow-like mode. At the same time, the discharge area of the former is larger than the latter. Nevertheless, with the increase in water ratio, the discharge area change reversed. Additionally, the air plasma plume propagation depends on the gas flow. The initial propagation velocity decreases with the increase in water ratio.

Juxtaposition of the changes in intracellular calcium and force during staircase potentiation at 30 and 37°C

PubMed Central

Vandenboom, Rene

2014-01-01

Ca2+ entry during the action potential stimulates muscle contraction. During repetitive low frequency stimulation, skeletal muscle undergoes staircase potentiation (SP), a progressive increase in the peak twitch force induced by each successive stimulus. Multiple mechanisms, including myosin regulatory light chain phosphorylation, likely contribute to SP, a temperature-dependent process. Here, we used the Ca2+-sensitive fluorescence indicators acetoxymethyl (AM)-furaptra and AM-fura-2 to examine the intracellular Ca2+ transient (ICT) and the baseline Ca2+ level at the onset of each ICT during SP at 30 and 37°C in mouse lumbrical muscle. The stimulation protocol, 8 Hz for 8 s, resulted in a 27 ± 3% increase in twitch force at 37°C and a 7 ± 2% decrease in twitch force at 30°C (P < 0.05). Regardless of temperature, the peak rate of force production (+df/dt) was higher in all twitches relative to the first twitch (P < 0.05). Consistent with the differential effects of stimulation on twitch force at the two temperatures, raw ICT amplitude decreased during repetitive stimulation at 30°C (P < 0.05) but not at 37°C. Cytosolic Ca2+ accumulated during SP such that baseline Ca2+ at the onset of ICTs occurring late in the train was higher (P < 0.05) than that of those occurring early in the train. ICT duration increased progressively at both temperatures. This effect was not entirely proportional to the changes in twitch duration, as twitch duration characteristically decreased before increasing late in the protocol. This is the first study identifying a changing ICT as an important, and temperature-sensitive, modulator of muscle force during repetitive stimulation. Moreover, we extend previous observations by demonstrating that contraction-induced increases in baseline Ca2+ coincide with greater +df/dt but not necessarily with higher twitch force. PMID:25422504

Fermionic spectral functions in backreacting p-wave superconductors at finite temperature

NASA Astrophysics Data System (ADS)

Giordano, G. L.; Grandi, N. E.; Lugo, A. R.

2017-04-01

We investigate the spectral function of fermions in a p-wave superconducting state, at finite both temperature and gravitational coupling, using the AdS/CF T correspondence and extending previous research. We found that, for any coupling below a critical value, the system behaves as its zero temperature limit. By increasing the coupling, the "peak-dip-hump" structure that characterizes the spectral function at fixed momenta disappears. In the region where the normal/superconductor phase transition is first order, the presence of a non-zero order parameter is reflected in the absence of rotational symmetry in the fermionic spectral function at the critical temperature.

Temporal variation in the dispersion patterns of metazoan parasites of a coastal fish species from the Gulf of Mexico.

PubMed

Vidal-Martínez, V M; Pal, P; Aguirre-Macedo, M L; May-Tec, A L; Lewis, J W

2014-03-01

Global climate change (GCC) is expected to affect key environmental variables such as temperature and rainfall, which in turn influence the infection dynamics of metazoan parasites in tropical aquatic hosts. Thus, our aim was to determine how temporal patterns of temperature and rainfall influence the mean abundance and aggregation of three parasite species of the fish Cichlasoma urophthalmus from Yucatán, México. We calculated mean abundance and the aggregation parameter of the negative binomial distribution k for the larval digeneans Oligogonotylus manteri and Ascocotyle (Phagicola) nana and the ectoparasite Argulus yucatanus monthly from April 2005 to December 2010. Fourier analysis of time series and cross-correlations were used to determine potential associations between mean abundance and k for the three parasite species with water temperature and rainfall. Both O. manteri and A. (Ph.) nana exhibited their highest frequency peaks in mean abundance at 6 and 12 months, respectively, while their peak in k occurred every 24 months. For A. yucatanus the frequency peaks in mean abundance and k occurred every 12 months. We suggest that the level of aggregation at 24 months of O. manteri increases the likelihood of fish mortality. Such a scenario is less likely for A. (Ph.) nana and A. yucatanus, due to their low infection levels. Our findings suggest that under the conditions of GCC it would be reasonable to expect higher levels of parasite aggregation in tropical aquatic hosts, in turn leading to a potential increase in parasite-induced host mortality.

Investigation of thermoluminescence and kinetic parameters of CaMgB{sub 2}O{sub 5}: Dy{sup 3+} nanophosphor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Manhas, M.; Kumar, Vinay, E-mail: vinaykumar@smvdu.ac.in; Department of Physics, University of the Free State, P.O. Box 339, Bloemfontein ZA9300

2016-05-06

In this paper, thermoluminescence (TL) properties of Dy{sup 3+} (1.5 mol %) doped CaMgB{sub 2}O{sub 5} nanophosphor after being exposed to ultraviolet (UV) radiations (λ=254nm) were investigated. In UV exposed samples, the thermoluminescence glow curve consists of a broad glow peak located at 380 K with a small shoulder at 507 K. A shift in glow peak temperature from 367 K to 380 K after the UV exposure for 80 min was observed, which clearly shows that glow peaks follow the second order kinetics. The TL intensity of the peaks increases with an increase in the exposure time of UV rays (10-180 min). The TL Anal programmore » was used to analyze the glow curve. The kinetic parameters such as activation energy (E), the frequency factor (s) and the order of kinetics (b) were calculated for CaMgB{sub 2}O{sub 5}: Dy{sup 3+} nanophosphors.« less

Extreme temperature robust optical sensor designs and fault-tolerant signal processing

DOEpatents

Riza, Nabeel Agha [Oviedo, FL; Perez, Frank [Tujunga, CA

2012-01-17

Silicon Carbide (SiC) probe designs for extreme temperature and pressure sensing uses a single crystal SiC optical chip encased in a sintered SiC material probe. The SiC chip may be protected for high temperature only use or exposed for both temperature and pressure sensing. Hybrid signal processing techniques allow fault-tolerant extreme temperature sensing. Wavelength peak-to-peak (or null-to-null) collective spectrum spread measurement to detect wavelength peak/null shift measurement forms a coarse-fine temperature measurement using broadband spectrum monitoring. The SiC probe frontend acts as a stable emissivity Black-body radiator and monitoring the shift in radiation spectrum enables a pyrometer. This application combines all-SiC pyrometry with thick SiC etalon laser interferometry within a free-spectral range to form a coarse-fine temperature measurement sensor. RF notch filtering techniques improve the sensitivity of the temperature measurement where fine spectral shift or spectrum measurements are needed to deduce temperature.

Detectivity enhancement in quantum well infrared photodetectors utilizing a photonic crystal slab resonator.

PubMed

Kalchmair, S; Gansch, R; Ahn, S I; Andrews, A M; Detz, H; Zederbauer, T; Mujagić, E; Reininger, P; Lasser, G; Schrenk, W; Strasser, G

2012-02-27

We characterize the performance of a quantum well infrared photodetector (QWIP), which is fabricated as a photonic crystal slab (PCS) resonator. The strongest resonance of the PCS is designed to coincide with the absorption peak frequency at 7.6 µm of the QWIP. To accurately characterize the detector performance, it is illuminated by using single mode mid-infrared lasers. The strong resonant absorption enhancement yields a detectivity increase of up to 20 times. This enhancement is a combined effect of increased responsivity and noise current reduction. With increasing temperature, we observe a red shift of the PCS-QWIP resonance peak of -0.055 cm(-1)/K. We attribute this effect to a refractive index change and present a model based on the revised plane wave method.

Reversing and nonreversing heat capacity of poly(lactic acid) in the glass transition region by TMDSC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pyda, Marek; Wunderlich, Bernhard

2005-11-01

A study of the glass transition of an amorphous and a semicrystalline poly(lactic acid) (PLA) is performed with adiabatic calorimetry, differential scanning calorimetry (DSC), and temperature-modulated DSC (TMDSC). The reversing, total, and nonreversing apparent heat capacities of samples with different contents of L- and D-lactic acid and with various thermal histories were evaluated. Different modes of TMDSC analyses of amorphous and semicrystalline PLA were compared to the total heat capacity from standard DSC. The enthalpy relaxation and the cold crystallization in the glass transition region are largely irreversible. The melting is largely irreversible, but a 100% reversing fraction is observedmore » at low temperatures from 375 to 420 K, which becomes small inside the major melting peak at about 440 K. From the TMDSC of amorphous PLA, the combined information on endothermic and exothermic enthalpy relaxation and glass transition were deconvoluted into the reversing and nonreversing components. The glass transition temperature from the reversing heat capacity and the enthalpy relaxation peaks from the nonreversing component shift to higher temperature for increasingly annealed PLA. The relaxation times for aging decrease on cooling until the glass transition is reached and then increase. This behavior is linked to cooperativity. All quantitative thermal analyses are based on the heat capacity of the solid and liquid, evaluated earlier with the advanced thermal analysis system (ATHAS).« less

Temperature rise and parasitic infection interact to increase the impact of an invasive species.

PubMed

Laverty, Ciaran; Brenner, David; McIlwaine, Christopher; Lennon, Jack J; Dick, Jaimie T A; Lucy, Frances E; Christian, Keith A

2017-04-01

Invasive species often detrimentally impact native biota, e.g. through predation, but predicting such impacts is difficult due to multiple and perhaps interacting abiotic and biotic context dependencies. Higher mean and peak temperatures, together with parasites, might influence the impact of predatory invasive host species additively, synergistically or antagonistically. Here, we apply the comparative functional response methodology (relationship between resource consumption rate and resource supply) in one experiment and conduct a second scaled-up mesocosm experiment to assess any differential predatory impacts of the freshwater invasive amphipod Gammarus pulex, when uninfected and infected with the acanthocephalan Echinorhynchus truttae, at three temperatures representative of current and future climate. Individual G. pulex showed Type II predatory functional responses. In both experiments, infection was associated with higher maximum feeding rates, which also increased with increasing temperatures. Additionally, infection interacted with higher temperatures to synergistically elevate functional responses and feeding rates. Parasitic infection also generally increased Q 10 values. We thus suggest that the differential metabolic responses of the host and parasite to increasing temperatures drives the synergy between infection and temperature, elevating feeding rates and thus enhancing the ecological impact of the invader. Copyright © 2017 Australian Society for Parasitology. Published by Elsevier Ltd. All rights reserved.

Incubation behavior adjustments, driven by ambient temperature variation, improve synchrony between hatch dates and caterpillar peak in a wild bird population.

PubMed

Simmonds, Emily G; Sheldon, Ben C; Coulson, Tim; Cole, Ella F

2017-11-01

For organisms living in seasonal environments, synchronizing the peak energetic demands of reproduction with peak food availability is a key challenge. Understanding the extent to which animals can adjust behavior to optimize reproductive timing, and the cues they use to do this, is essential for predicting how they will respond to future climate change. In birds, the timing of peak energetic demand is largely determined by the timing of clutch initiation; however, considerable alterations can still occur once egg laying has begun. Here, we use a wild population of great tits ( Parus major ) to quantify individual variation in different aspects of incubation behavior (onset, duration, and daily intensity) and conduct a comprehensive assessment of the causes and consequences of this variation. Using a 54-year dataset, we demonstrate that timing of hatching relative to peak prey abundance (synchrony) is a better predictor of reproductive success than clutch initiation or clutch completion timing, suggesting adjustments to reproductive timing via incubation are adaptive in this species. Using detailed in-nest temperature recordings, we found that postlaying, birds improved their synchrony with the food peak primarily by varying the onset of incubation, with duration changes playing a lesser role. We then used a sliding time window approach to explore which spring temperature cues best predict variance in each aspect of incubation behavior. Variation in the onset of incubation correlated with mean temperatures just prior to laying; however, incubation duration could not be explained by any of our temperature variables. Daily incubation intensity varied in response to daily maximum temperatures throughout incubation, suggesting female great tits respond to temperature cues even in late stages of incubation. Our results suggest that multiple aspects of the breeding cycle influence the final timing of peak energetic demand. Such adjustments could compensate, in part, for poor initial timing, which has significant fitness impacts.

An allowable cladding peak temperature for spent nuclear fuels in interim dry storage

NASA Astrophysics Data System (ADS)

Cha, Hyun-Jin; Jang, Ki-Nam; Kim, Kyu-Tae

2018-01-01

Allowable cladding peak temperatures for spent fuel cladding integrity in interim dry storage were investigated, considering hydride reorientation and mechanical property degradation behaviors of unirradiated and neutron irradiated Zr-Nb cladding tubes. Cladding tube specimens were heated up to various temperatures and then cooled down under tensile hoop stresses. Cool-down specimens indicate that higher heat-up temperature and larger tensile hoop stress generated larger radial hydride precipitation and smaller tensile strength and plastic hoop strain. Unirradiated specimens generated relatively larger radial hydride precipitation and plastic strain than did neutron irradiated specimens. Assuming a minimum plastic strain requirement of 5% for cladding integrity maintenance in interim dry storage, it is proposed that a cladding peak temperature during the interim dry storage is to keep below 250 °C if cladding tubes are cooled down to room temperature.

High-Performance Spray-Deposited Indium Doped ZnO Thin Film: Structural, Morphological, Electrical, Optical, and Photoluminescence Study

NASA Astrophysics Data System (ADS)

Asl, Hassan Zare; Rozati, Seyed Mohammad

2018-03-01

In this study, high-quality indium doped zinc oxide thin films were deposited using the spray pyrolysis technique, and the substrate temperature varied from 450°C to 550°C with steps of 25°C with the aim of investigating the effect of substrate temperature. It was found that as the temperature increased, the resistivity of the films decreased to the extent that it was as low as 5.34 × 10-3 Ω cm for the one deposited at 500°C; however, it slightly increased for the resulting film at 550°C. Although the carrier concentration mostly increased with temperature, it appeared that the carrier mobility was the parameter mainly governing the conductivity variation. In addition, the average transparency of the deposited films at 500°C, 525°C and 550°C was around 87% (400-800 nm), which makes them outstanding transparent conductive oxide films. Moreover, the crystallite size and strain of the resulting films were estimated via the Williamson-Hall method. The results revealed a considerable reduction in the crystallite size and strain up to 500°C followed by a rise at higher substrate temperature. Based on both the surface and cross-section field emission scanning electron microscope images, the film resulting at 500°C was highly compacted and crack free, which can explain the enlargement of the carrier mobility (10.9 cm2 V-1 s-1) in this film. Finally, a detailed photoluminescence study revealed several peaks in the spectrum and the variation of the two major peaks appeared to have correlation with the carrier concentration.

Effective model with strong Kitaev interactions for α -RuCl3

NASA Astrophysics Data System (ADS)

Suzuki, Takafumi; Suga, Sei-ichiro

2018-04-01

We use an exact numerical diagonalization method to calculate the dynamical spin structure factors of three ab initio models and one ab initio guided model for a honeycomb-lattice magnet α -RuCl3 . We also use thermal pure quantum states to calculate the temperature dependence of the heat capacity, the nearest-neighbor spin-spin correlation function, and the static spin structure factor. From the results obtained from these four effective models, we find that, even when the magnetic order is stabilized at low temperature, the intensity at the Γ point in the dynamical spin structure factors increases with increasing nearest-neighbor spin correlation. In addition, we find that the four models fail to explain heat-capacity measurements whereas two of the four models succeed in explaining inelastic-neutron-scattering experiments. In the four models, when temperature decreases, the heat capacity shows a prominent peak at a high temperature where the nearest-neighbor spin-spin correlation function increases. However, the peak temperature in heat capacity is too low in comparison with that observed experimentally. To address these discrepancies, we propose an effective model that includes strong ferromagnetic Kitaev coupling, and we show that this model quantitatively reproduces both inelastic-neutron-scattering experiments and heat-capacity measurements. To further examine the adequacy of the proposed model, we calculate the field dependence of the polarized terahertz spectra, which reproduces the experimental results: the spin-gapped excitation survives up to an onset field where the magnetic order disappears and the response in the high-field region is almost linear. Based on these numerical results, we argue that the low-energy magnetic excitation in α -RuCl3 is mainly characterized by interactions such as off-diagonal interactions and weak Heisenberg interactions between nearest-neighbor pairs, rather than by the strong Kitaev interactions.

Climate impacts of geoengineering in a delayed mitigation scenario

NASA Astrophysics Data System (ADS)

Tilmes, S.; Sanderson, B. M.; O'Neill, B. C.

2016-08-01

Decarbonization in the immediate future is required to limit global mean temperature (GMT) increase to 2°C relative to preindustrial conditions, if geoengineering is not considered. Here we use the Community Earth System Model (CESM) to investigate climate outcomes if no mitigation is undertaken until GMT has reached 2°C. We find that late decarbonization in CESM without applying stratospheric sulfur injection (SSI) leads to a peak temperature increase of 3°C and GMT remains above 2° for 160 years. An additional gradual increase and then decrease of SSI over this period reaching about 1.5 times the aerosol burden resulting from the Mount Pinatubo eruption in 1992 would limit the increase in GMT to 2.0° for the specific pathway and model. SSI produces mean and extreme temperatures in CESM comparable to an early decarbonization pathway, but aridity is not mitigated to the same extent.

Climate Impacts of Geoengineering in a Delayed Mitigation Scenario

NASA Astrophysics Data System (ADS)

Tilmes, S.; Sanderson, B. M.; O'Neill, B. C.

2016-12-01

Decarbonization in the immediate future is required to limit global mean temperature (GMT) increase to 2 degrees C relative to pre-industrial conditions, if geoengineering is not considered. Here we use the Community Earth System Model (CESM) to investigate climate outcomes if no mitigation is undertaken until GMT has reached 2 degree C. We find that late decarbonization (LD) in CESM without applying stratospheric sulfur injection (SSI) leads to a peak temperature increase of 3 degree C and GMT remains above 2 degrees for 160 years. An additional gradual increase and then decrease of SSI over this period reaching about 1.5 times the aerosol burden resulting from the Mt Pinatubo eruption in 1992 would limit the increase in GMT to 2.0 degrees for the specific pathway and model. SSI produces mean and extreme temperatures in CESM comparable to an early decarbonization pathway, but aridity is not mitigated to the same extent.

Microstructure evolution and dynamic recrystallization behavior of a powder metallurgy Ti-22Al-25Nb alloy during hot compression

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia, Jianbo

The flow behavior of a powder metallurgy (P/M) Ti-22Al-25Nb alloy during hot compression tests has been investigated at a strain rate of 0.01 s{sup −1} and a temperature range of 980–1100 °C up to various true strains from 0.1 to 0.9. The effects of deformation temperature and strain on microstructure characterization and nucleation mechanisms of dynamic recrystallization (DRX) were assessed by means of Optical microscope (OM), electron backscatter diffraction (EBSD) and transmission electron microscope (TEM) techniques, respectively. The results indicated that the process of DRX was promoted by increasing deformation temperature and strain. By regression analysis, a power exponent relationshipmore » between peak stresses and sizes of stable DRX grains was developed. In addition, it is suggested that the discontinuous dynamic recrystallization (DDRX) and continuous dynamic recrystallization (CDRX) controlled nucleation mechanisms for DRX grains operated simultaneously during the whole hot process, and which played the leading role varied with hot process parameters of temperature and strain. It was further demonstrated that the CDRX featured by progressive subgrain rotation was weakened by elevating deformation temperatures. - Highlights: •Flow behavior of a P/M Ti-22Al-25Nb is studied by hot compression tests. •Microstructure evolution of alloy is affected by deformation temperature and strain. •The relationship between peak stress and stable DRX grain size was developed. •The process of DRX was promoted by increasing deformation temperature and strain. •Nucleation mechanisms of DRX were identified by EBSD analysis and TEM observation.« less

40 CFR 63.11440 - What are the monitoring requirements for new and existing sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Clay Ceramics Manufacturing Area Sources Standards, Compliance, and Monitoring Requirements § 63.11440... ceramic ware, you must conduct a daily check of the peak firing temperature. If the peak temperature...

Magnetic and dielectric properties of Ca-substituted BiFeO3 nanoferrites by the sol-gel method.

PubMed

Lin, Jinpei; Guo, Zeping; Li, Mei; Lin, Qing; Huang, Kangling; He, Yun

2018-01-01

A multiferroic material can simultaneously show two or more basic magnetic properties, including ferromagnetism, antiferromagnetism, and ferroelectricity. BiFeO 3 is a multiferroic material with a rhombohedral distorted perovskite structure. Doping can reduce the volatility of Bi and greatly improve the magnetoelectric properties of BiFeO 3 . To investigate the influence of the doping content we used the following analytical methods: X-ray powder diffraction (XRD), scanning electron microscopy (SEM), microwave network analysis (PNA-N5244A), and the Superconducting Quantum Interference Device (Quantum Design MPMS) test. With the increase of Ca 2+ concentration in the solution, the grain size of Bi 1- x Ca x FeO 3 becomes smaller, showing the role of Ca 2+ ions as the dopant for fine grains. The calcination temperatures are the major causes for the saturated magnetization. The residual magnetization ( M r ) and the coercive force ( H c ) decrease linearly with the increase of x value, and due to the effect of Ca 2+ substitution at Bi 3+ sites, which causes the valence change of Fe and/or the oxygen vacancies. The XRD result indicates that the diffraction peak emerges with the increase of Ca 2+ and the main diffraction peak achieves a high angle. The best calcining temperature is 600 °C, and the morphology is very dependent on the calcining temperature.

186 K Operation of Terahertz Quantum-Cascade Lasers Based on a Diagonal Design

NASA Technical Reports Server (NTRS)

Kumar, Sushil; Hu, Qing; Reno, John L.

2009-01-01

Resonant-phonon terahertz quantum-cascade lasers operating up to a heat-sink temperature of 186 K are demonstrated. This record temperature performance is achieved based on a diagonal design, with the objective to increase the upper-state lifetime and therefore the gain at elevated temperatures. The increased diagonality also lowers the operating current densities by limiting the flow of parasitic leakage current. Quantitatively, the diagonality is characterized by a radiative oscillator strength that is smaller by a factor of two from the least of any previously published designs. At the lasing frequency of 3.9 THz, 63 mW of peak optical power was measured at 5 K, and approximately 5 mW could still be detected at 180 K.

An origin of orange (2 eV) photoluminescence in SiO{sub 2} films implanted with high Si{sup +}-ion doses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tyschenko, I. E., E-mail: tys@isp.nsc.ru

2015-09-15

The photoluminescence and photoluminescence excitation spectra of SiO{sub 2} films implanted with high (3 at %) Si{sup +}-ion doses are studied in relation to the temperature of postimplantation annealing. It is shown that two photoluminescence bands with peaks at 2.7 and 2 eV are dominant in the spectra. As the annealing temperature is increased, the relation between the intensities of the 2.7 and 2 eV bands changes in favor of the former one. Both of the photoluminescence bands have their main excitation peak at the energy 5.1 eV. The excitation spectrum of the ∼2-eV band exhibits also peaks at 3.8more » and 4.6 eV. It is concluded that, in the implanted SiO{sub 2} films, the orange photoluminescence band originates from radiative transitions between levels of centers associated with a deficiency of oxygen (≡Si–Si≡ or =Si:) and the levels of nonbridging oxygen (≡Si–O•)« less

Adsorption, Desorption, and Displacement Kinetics of H2O and CO2 on TiO2(110)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Smith, R. Scott; Li, Zhenjun; Chen, Long

The adsorption, desorption, and displacement kinetics of H2O and CO2 on TiO2(110) are investigated using temperature programmed desorption (TPD) and molecular beam techniques. The TPD spectra for both H2O and CO2 have well-resolved peaks corresponding to desorption from bridge-bonded oxygen (BBO), Ti, and oxygen vacancies (VO) sites in order of increasing peak temperature. Analysis of the saturated monolayer peak for both species reveals that the corresponding adsorption energies on all sites are greater for H2O and for CO2. Sequential dosing of H2O and CO2 reveals that, independent of the dose order, H2O molecules will displace CO2 in order to occupymore » the highest energy binding sites available. Isothermal experiments show that the displacement of CO2 by H2O occurs between 75 and 80 K. Further analysis shows that a ratio of 4 H2O to 3 CO2 molecules is needed to displace CO2 from the TiO2(110) surface.« less

Potassium acceptor doping of ZnO crystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parmar, Narendra S., E-mail: nparmar@wsu.edu; Lynn, K. G.; Department of Physics and Astronomy, Washington State University, Pullman, Washington 99164-2814

2015-05-15

ZnO bulk single crystals were doped with potassium by diffusion at 950°C. Positron annihilation spectroscopy confirms the filling of zinc vacancies and a different trapping center for positrons. Secondary ion mass spectroscopy measurements show the diffusion of potassium up to 10 μm with concentration ∼1 × 10{sup 16} cm{sup −3}. IR measurements show a local vibrational mode (LVM) at 3226 cm{sup −1}, at a temperature of 9 K, in a potassium doped sample that was subsequently hydrogenated. The LVM is attributed to an O–H bond-stretching mode adjacent to a potassium acceptor. When deuterium substitutes for hydrogen, a peak is observedmore » at 2378 cm{sup −1}. The O-H peak is much broader than the O-D peak, perhaps due to an unusually low vibrational lifetime. The isotopic frequency ratio is similar to values found in other hydrogen complexes. Potassium doping increases the resistivity up to 3 orders of magnitude at room temperature. The doped sample has a donor level at 0.30 eV.« less

Ceramic automotive Stirling engine program

NASA Technical Reports Server (NTRS)

1986-01-01

The Ceramic Automotive Stirling Engine Program evaluated the application of advanced ceramic materials to an automotive Stirling engine. The objective of the program was to evaluate the technical feasibility of utilizing advanced ceramics to increase peak engine operating temperature, and to evaluate the performance benefits of such an increase. Manufacturing cost estimates were also developed for various ceramic engine components and compared with conventional metallic engine component costs.

Effect of Rapid Thermal Processing on Light-Induced Degradation of Carrier Lifetime in Czochralski p-Type Silicon Bare Wafers

NASA Astrophysics Data System (ADS)

Kouhlane, Y.; Bouhafs, D.; Khelifati, N.; Belhousse, S.; Menari, H.; Guenda, A.; Khelfane, A.

2016-11-01

The electrical properties of Czochralski silicon (Cz-Si) p-type boron-doped bare wafers have been investigated after rapid thermal processing (RTP) with different peak temperatures. Treated wafers were exposed to light for various illumination times, and the effective carrier lifetime ( τ eff) measured using the quasi-steady-state photoconductance (QSSPC) technique. τ eff values dropped after prolonged illumination exposure due to light-induced degradation (LID) related to electrical activation of boron-oxygen (BO) complexes, except in the sample treated with peak temperature of 785°C, for which the τ eff degradation was less pronounced. Also, a reduction was observed when using the 830°C peak temperature, an effect that was enhanced by alteration of the wafer morphology (roughness). Furthermore, the electrical resistivity presented good stability under light exposure as a function of temperature compared with reference wafers. Additionally, the optical absorption edge shifted to higher wavelength, leading to increased free-carrier absorption by treated wafers. Moreover, a theoretical model is used to understand the lifetime degradation and regeneration behavior as a function of illumination time. We conclude that RTP plays an important role in carrier lifetime regeneration for Cz-Si wafers via modification of optoelectronic and structural properties. The balance between an optimized RTP cycle and the rest of the solar cell elaboration process can overcome the negative effect of LID and contribute to achievement of higher solar cell efficiency and module performance.

Origin of unusual bandgap shift and dual emission in organic-inorganic lead halide perovskites

PubMed Central

Dar, M. Ibrahim; Jacopin, Gwénolé; Meloni, Simone; Mattoni, Alessandro; Arora, Neha; Boziki, Ariadni; Zakeeruddin, Shaik Mohammed; Rothlisberger, Ursula; Grätzel, Michael

2016-01-01

Emission characteristics of metal halide perovskites play a key role in the current widespread investigations into their potential uses in optoelectronics and photonics. However, a fundamental understanding of the molecular origin of the unusual blueshift of the bandgap and dual emission in perovskites is still lacking. In this direction, we investigated the extraordinary photoluminescence behavior of three representatives of this important class of photonic materials, that is, CH3NH3PbI3, CH3NH3PbBr3, and CH(NH2)2PbBr3, which emerged from our thorough studies of the effects of temperature on their bandgap and emission decay dynamics using time-integrated and time-resolved photoluminescence spectroscopy. The low-temperature (<100 K) photoluminescence of CH3NH3PbI3 and CH3NH3PbBr3 reveals two distinct emission peaks, whereas that of CH(NH2)2PbBr3 shows a single emission peak. Furthermore, irrespective of perovskite composition, the bandgap exhibits an unusual blueshift by raising the temperature from 15 to 300 K. Density functional theory and classical molecular dynamics simulations allow for assigning the additional photoluminescence peak to the presence of molecularly disordered orthorhombic domains and also rationalize that the unusual blueshift of the bandgap with increasing temperature is due to the stabilization of the valence band maximum. Our findings provide new insights into the salient emission properties of perovskite materials, which define their performance in solar cells and light-emitting devices. PMID:27819049

Origin of unusual bandgap shift and dual emission in organic-inorganic lead halide perovskites.

PubMed

Dar, M Ibrahim; Jacopin, Gwénolé; Meloni, Simone; Mattoni, Alessandro; Arora, Neha; Boziki, Ariadni; Zakeeruddin, Shaik Mohammed; Rothlisberger, Ursula; Grätzel, Michael

2016-10-01

Emission characteristics of metal halide perovskites play a key role in the current widespread investigations into their potential uses in optoelectronics and photonics. However, a fundamental understanding of the molecular origin of the unusual blueshift of the bandgap and dual emission in perovskites is still lacking. In this direction, we investigated the extraordinary photoluminescence behavior of three representatives of this important class of photonic materials, that is, CH 3 NH 3 PbI 3 , CH 3 NH 3 PbBr 3 , and CH(NH 2 ) 2 PbBr 3 , which emerged from our thorough studies of the effects of temperature on their bandgap and emission decay dynamics using time-integrated and time-resolved photoluminescence spectroscopy. The low-temperature (<100 K) photoluminescence of CH 3 NH 3 PbI 3 and CH 3 NH 3 PbBr 3 reveals two distinct emission peaks, whereas that of CH(NH 2 ) 2 PbBr 3 shows a single emission peak. Furthermore, irrespective of perovskite composition, the bandgap exhibits an unusual blueshift by raising the temperature from 15 to 300 K. Density functional theory and classical molecular dynamics simulations allow for assigning the additional photoluminescence peak to the presence of molecularly disordered orthorhombic domains and also rationalize that the unusual blueshift of the bandgap with increasing temperature is due to the stabilization of the valence band maximum. Our findings provide new insights into the salient emission properties of perovskite materials, which define their performance in solar cells and light-emitting devices.

Optical spectroscopy of the bladder washout fluid to optimize fluorescence cystoscopy with Hexvix®.

PubMed

Martoccia, Carla; Zellweger, Matthieu; Lovisa, Blaise; Jichlinski, Patrice; van den Bergh, Hubert; Wagnières, Georges

2014-09-01

Fluorescence cystoscopy enhances detection of early bladder cancer. Water used to inflate thebladder during the procedure rapidly contains urine, which may contain fluorochromes. This frequently degradesfluorescence images. Samples of bladder washout fluid (BWF) or urine were collected (15 subjects). We studiedtheir fluorescence properties and assessed changes induced by pH (4 to 9) and temperature (15°C to 41°C).A typical fluorescence spectrum of BWF features a main peak (excitation/emission: 320∕420 nm, FWHM =50∕100 nm) and a weaker (5% to 20% of main peak intensity), secondary peak (excitation/emission: 455∕525 nm, FWHM = 80∕50 nm). Interpatient fluctuations of fluorescence intensity are observed. Fluorescence intensity decreases when temperature increases (max 30%) or pH values vary (max 25%). Neither approach is compatible with clinical settings. Fluorescence lifetime measurements suggest that 4-pyridoxic acid/riboflavin is the most likely molecule responsible for urine’s main/secondary fluorescence peak. Our measurements give an insight into the spectroscopy of the detrimental background fluorescence. This should be included in the optical design of fluorescence cystoscopes. We estimate that restricting the excitation range from 370–430 nm to 395–415 nm would reduce the BWF background by a factor 2.

Temperature peaks affect fire-induced soil water repellency, infiltration and erosion risk of Mediterranean shrublands. Implications for water and sediment connectivity

NASA Astrophysics Data System (ADS)

Jordán, Antonio; Zavala, Lorena M.; Gordillo-Rivero, Ángel J.; Miriam, Miriam; Keesstra, Saskia; Cerdà, Artemi

2017-04-01

We know that the impact of fire on soil water repellency varies largely with the availability of water and physical and chemical soil properties, as well as the intensity of pre-existing hydrophobicity. However, there are few studies that relate the intensity of post-fire soil hydrophobicity and its persistence to the intensity and duration of thermal peaks occurring during fire. Fundamentally, this is due to the difficulty of quantifying these factors in situ, so that experimental fires are an extremely useful tool. The objective of this work was to study the impact of the intensity and duration of the thermal peaks observed during an experimental fire in the hydrophobicity of previously wet or slightly hydrophobic soils and the consequences of these changes on infiltration, runoff and soil loss (through rainfall simulation) in the immediate (30 days) and medium-term (1 year) post-fire period. In general, soil water repellency increased in all cases, although high temperatures and residence times of moderate thermal peaks caused the greatest impact. Although infiltration rates determined by mini-disk infiltrometer with water generally declined, no significant changes were observed in the same measurement with ethanol (which negates the effect of hydrophobicity).

Size tunability and optical properties of CdSe quantum dots for various growth conditions

NASA Astrophysics Data System (ADS)

Ko, Eun Yee; Lee, Joo In; Jeon, Ju-Won; Lee, In Hwan; Shin, Yong Hyeon; Han, Il Ki

2013-01-01

We report the optical properties of CdSe quantum dots (QDs) synthesized under various growth conditions, such as growth temperature, growth time, ligand ratio, and Cd:Se ratio of the precursors. As the growth temperature and time was increased, the peaks of the photoluminescence (PL) spectra were a red shifted, indicating that the size of QDs increased. Different ligand ratios and Cd:Se ratios of the precursors played important roles in determining the QDs size. From the PL spectra and the transmission electron microscopy image, the size distribution, as well as the size of CdSe QDs, could be controlled by using the growth conditions. The temperature-dependent PL of CdSe QDs dropped and dried on Si substrates was measured at temperatures from 15 K to 290 K. With increasing temperature, the red shift of the QDs was about 35 meV, which is noticeably smaller than that of bulk CdSe (˜100 meV). The influence of the temperature on the optical properties of colloidal CdSe QDs is important for an application to various devices.

Climate mediates the effects of disturbance on ant assemblage structure

PubMed Central

Gibb, Heloise; Sanders, Nathan J.; Dunn, Robert R.; Watson, Simon; Photakis, Manoli; Abril, Silvia; Andersen, Alan N.; Angulo, Elena; Armbrecht, Inge; Arnan, Xavier; Baccaro, Fabricio B.; Bishop, Tom R.; Boulay, Raphael; Castracani, Cristina; Del Toro, Israel; Delsinne, Thibaut; Diaz, Mireia; Donoso, David A.; Enríquez, Martha L.; Fayle, Tom M.; Feener, Donald H.; Fitzpatrick, Matthew C.; Gómez, Crisanto; Grasso, Donato A.; Groc, Sarah; Heterick, Brian; Hoffmann, Benjamin D.; Lach, Lori; Lattke, John; Leponce, Maurice; Lessard, Jean-Philippe; Longino, John; Lucky, Andrea; Majer, Jonathan; Menke, Sean B.; Mezger, Dirk; Mori, Alessandra; Munyai, Thinandavha C.; Paknia, Omid; Pearce-Duvet, Jessica; Pfeiffer, Martin; Philpott, Stacy M.; de Souza, Jorge L. P.; Tista, Melanie; Vasconcelos, Heraldo L.; Vonshak, Merav; Parr, Catherine L.

2015-01-01

Many studies have focused on the impacts of climate change on biological assemblages, yet little is known about how climate interacts with other major anthropogenic influences on biodiversity, such as habitat disturbance. Using a unique global database of 1128 local ant assemblages, we examined whether climate mediates the effects of habitat disturbance on assemblage structure at a global scale. Species richness and evenness were associated positively with temperature, and negatively with disturbance. However, the interaction among temperature, precipitation and disturbance shaped species richness and evenness. The effect was manifested through a failure of species richness to increase substantially with temperature in transformed habitats at low precipitation. At low precipitation levels, evenness increased with temperature in undisturbed sites, peaked at medium temperatures in disturbed sites and remained low in transformed sites. In warmer climates with lower rainfall, the effects of increasing disturbance on species richness and evenness were akin to decreases in temperature of up to 9°C. Anthropogenic disturbance and ongoing climate change may interact in complicated ways to shape the structure of assemblages, with hot, arid environments likely to be at greatest risk. PMID:25994675

Effect of time varying phosphorus implantation on optoelectronics properties of RF sputtered ZnO thin-films

NASA Astrophysics Data System (ADS)

Murkute, Punam; Ghadi, Hemant; Saha, Shantanu; Chavan, Vinayak; Chakrabarti, Subhananda

2018-03-01

ZnO has potential application in the field of short wavelength devices like LED's, laser diodes, UV detectors etc, because of its wide band gap (3.34 eV) and high exciton binding energy (60 meV). ZnO possess N-type conductivity due to presence of defects arising from oxygen and zinc interstitial vacancies. In order to achieve P-type or intrinsic carrier concentration an implantation study is preferred. In this report, we have varied phosphorous implantation time and studied its effect on optical as well structural properties of RF sputtered ZnO thin-films. Implantation was carried out using Plasma Immersion ion implantation technique for 10 and 20 s. These films were further annealed at 900°C for 10 s in oxygen ambient to activate phosphorous dopants. Low temperature photoluminescence (PL) spectra measured two distinct peaks at 3.32 and 3.199 eV for 20 s implanted sample annealed at 900°C. Temperature dependent PL measurement shows slightly blue shift in peak position from 18 K to 300 K. 3.199 eV peak can be attributed to donoracceptor pair (DAP) emission and 3.32 eV peak corresponds to conduction-band-to-acceptor (eA0) transition. High resolution x-ray diffraction revels dominant (002) peak from all samples. Increasing implantation time resulted in low peak intensity suggesting a formation of implantation related defects. Compression in C-axis with implantation time indicates incorporation of phosphorus in the formed film. Improvement in surface quality was observed from 20 s implanted sample which annealed at 900°C.

Optical and dielectric properties of NiFe2O4 nanoparticles under different synthesized temperature

NASA Astrophysics Data System (ADS)

Parishani, Marziye; Nadafan, Marzieh; Dehghani, Zahra; Malekfar, Rasoul; Khorrami, G. H. H.

In this research, NiFe2O4 nanoparticles was prepared via the simple sol-gel route, using different sintering temperature. This nanoparticle was characterized via X-ray diffraction (XRD) pattern, scanning electron microscopy (SEM), and FTIR spectra. The XRD patterns show by increasing the synthesized temperature, the intensity, and broadening of peaks are decreased so the results are more crystallization and raising the size of nanoparticles. The size distribution in the histogram of the NiFe2O4 nanoparticles is 42, 96, and 315 nm at 750 °C, 850 °C, and 950 °C, respectively. The FTIR spectra were evaluated using Kramers-Kronig method. Results approved the existing of certain relations between sintering temperatures and grain size of nanoparticles. By raising the temperature from 750 °C to 950 °C, the grain size was increased from 70 nm to 300 nm and the optical constants of nanoparticles were strongly related to synthesizing temperature as well. Since by increasing temperature, both real/imaginary parts of the refractive index and dielectric function were decreased. Consequently, the transversal (TO) and longitudinal (LO) phonon frequencies are detected. The TO and LO frequencies have shifted to red frequencies by increasing reaction temperature.

Investigation on Structural and Optical Properties of Copper Telluride Thin Films with Different Annealing Temperature

NASA Astrophysics Data System (ADS)

Nishanthini, R.; Muthu Menaka, M.; Pandi, P.; Bahavan Palani, P.; Neyvasagam, K.

The copper telluride (Cu2Te) thin film of thickness 240nm was coated on a microscopic glass substrate by thermal evaporation technique. The prepared films were annealed at 150∘C and 250∘C for 1h. The annealing effect on Cu2Te thin films was examined with different characterization methods like X-ray Diffraction Spectroscopy (XRD), Scanning Electron Microscopy (SEM), Ultra Violet-Visible Spectroscopy (UV-VIS) and Photoluminescence (PL) Spectroscopy. The peak intensities of XRD spectra were increased while increasing annealing temperature from 150∘C to 250∘C. The improved crystallinity of the thin films was revealed. However, the prepared films are exposed complex structure with better compatibility. Moreover, the shift in band gap energy towards higher energies (blue shift) with increasing annealing temperature is observed from the optical studies.

Two-Photon Pumped Synchronously Mode-Locked Bulk GaAs Laser

NASA Astrophysics Data System (ADS)

Cao, W. L.; Vaucher, A. M.; Ling, J. D.; Lee, C. H.

1982-04-01

Pulses 7 picoseconds or less in duration have been generated from a bulk GaAs crystal by a synchronous mode-locking technique. The GaAs crystal was optically pumped by two-photon absorption of the emission from a mode-locked Nd:glass laser. Two-photon absorption as the means of excitation increases the volume of the gain medium by increasing the pene-tration depth of the pump intensity, enabling generation of intra-cavity pulses with peak power in the megawatt range. Tuning of the wavelength of the GaAs emission is achieved by varying the temperature. A tuning range covering 840 nm to 885 nm has been observed over a temperature range from 97°K to 260°K. The intensity of the GaAs emission has also been observed to decrease as the temperature of the crystal is increased.

Effect of pressure on the α relaxation in glycerol and xylitol

NASA Astrophysics Data System (ADS)

Paluch, M.; Casalini, R.; Hensel-Bielowka, S.; Roland, C. M.

2002-06-01

The effect of pressure on the dielectric relaxation of two polyhydroxy alcohols is examined by analysis of existing data on glycerol, together with new measurements on xylitol. The fragility, or Tg-normalized temperature dependence, changes with pressure for low pressures, but becomes invariant above 1 GPa. When compared at temperatures for which the α-relaxation times are equal, there is no effect of pressure (<1 GPa) on the shape of the α dispersion at higher temperatures. However, nearer Tg, pressure broadens the α peak, consistent with the expected correlation of fragility with the breadth of the relaxation function. We also observe that the α-relaxation peaks for both glycerol and xylitol show an excess intensity at higher frequencies. For xylitol, unlike for glycerol, at lower temperatures this wing disjoins to form a separate peak. For both glass formers, elevated pressure causes the excess wing to become more separated from the peak maximum; that is, the properties of the primary and excess intensities are not correlated. This implies that the excess wing in glycerol is also a distinct secondary process, although it cannot be resolved from the primary peak.

Cooling System to Treat Exercise-Induced Hyperthermia

DTIC Science & Technology

2016-06-01

temperatures . Additionally, individual variations in sweat rates, ventilation rates, fitness levels, and oxygen consumption were not...gastrointestinal MHR maximum heart rate NASA National Aeronautics and Space Administration Tc core temperature UCHS uncompensated heat stress VO2peak peak oxygen consumption ...the effectiveness of a cooling pump based patient thermal management system supplied by Aspen Systems on lowering core body temperature

Phase-shift detection in a Fourier-transform method for temperature sensing using a tapered fiber microknot resonator.

PubMed

Larocque, Hugo; Lu, Ping; Bao, Xiaoyi

2016-04-01

Phase-shift detection in a fast-Fourier-transform (FFT)-based spectrum analysis technique for temperature sensing using a tapered fiber microknot resonator is proposed and demonstrated. Multiple transmission peaks in the FFT spectrum of the device were identified as optical modes having completed different amounts of round trips within the ring structure. Temperature variation induced phase shifts for each set of peaks were characterized, and experimental results show that different peaks have distinct temperature sensitivities reaching values up to -0.542  rad/°C, which is about 10 times greater than that of a regular adiabatic taper Mach-Zehnder interferometer when using similar phase-tracking schemes.

Dysprosium electrodeposition from a hexaalkylguanidinium-based ionic liquid

NASA Astrophysics Data System (ADS)

Berger, Claudia A.; Arkhipova, Maria; Maas, Gerhard; Jacob, Timo

2016-07-01

The rare-earth element dysprosium (Dy) is an important additive that increases the magnetocrystalline anisotropy of neodymium magnets and additionally prevents from demagnetizing at high temperatures. Therefore, it is one of the most important elements for high-tech industries and is mainly used in permanent magnetic applications, for example in electric vehicles, industrial motors and direct-drive wind turbines. In an effort to develop a more efficient electrochemical technique for depositing Dy on Nd-magnets in contrast to commonly used costly physical vapor deposition, we investigated the electrochemical behavior of dysprosium(iii) trifluoromethanesulfonate in a custom-made guanidinium-based room-temperature ionic liquid (RTIL). We first examined the electrodeposition of Dy on an Au(111) model electrode. The investigation was carried out by means of cyclic voltammetry (CV) and X-ray photoelectron spectroscopy (XPS). The initial stages of metal deposition were followed by in situ scanning tunneling microscopy (STM). CV measurements revealed a large cathodic reduction peak, which corresponds to the growth of monoatomic high islands, based on STM images taken during the initial stages of deposition. XPS identified these deposited islands as dysprosium. A similar reduction peak was also observed on an Nd-Fe-B substrate, and positively identified as deposited Dy using XPS. Finally, we varied the concentration of the Dy precursor, electrolyte flow and temperature during Dy deposition and demonstrated that each of these parameters could be used to increase the thickness of the Dy deposit, suggesting that these parameters could be tuned simultaneously in a temperature-controlled flow cell to enhance the thickness of the Dy layer.The rare-earth element dysprosium (Dy) is an important additive that increases the magnetocrystalline anisotropy of neodymium magnets and additionally prevents from demagnetizing at high temperatures. Therefore, it is one of the most important elements for high-tech industries and is mainly used in permanent magnetic applications, for example in electric vehicles, industrial motors and direct-drive wind turbines. In an effort to develop a more efficient electrochemical technique for depositing Dy on Nd-magnets in contrast to commonly used costly physical vapor deposition, we investigated the electrochemical behavior of dysprosium(iii) trifluoromethanesulfonate in a custom-made guanidinium-based room-temperature ionic liquid (RTIL). We first examined the electrodeposition of Dy on an Au(111) model electrode. The investigation was carried out by means of cyclic voltammetry (CV) and X-ray photoelectron spectroscopy (XPS). The initial stages of metal deposition were followed by in situ scanning tunneling microscopy (STM). CV measurements revealed a large cathodic reduction peak, which corresponds to the growth of monoatomic high islands, based on STM images taken during the initial stages of deposition. XPS identified these deposited islands as dysprosium. A similar reduction peak was also observed on an Nd-Fe-B substrate, and positively identified as deposited Dy using XPS. Finally, we varied the concentration of the Dy precursor, electrolyte flow and temperature during Dy deposition and demonstrated that each of these parameters could be used to increase the thickness of the Dy deposit, suggesting that these parameters could be tuned simultaneously in a temperature-controlled flow cell to enhance the thickness of the Dy layer. Electronic supplementary information (ESI) available. See DOI: 10.1039/C6NR01351A

In vitro infrared thermography assessment of temperature peaks during the intra-oral welding of titanium abutments

NASA Astrophysics Data System (ADS)

Degidi, Marco; Nardi, Diego; Sighinolfi, Gianluca; Merla, Arcangelo; Piattelli, Adriano

2012-07-01

Control of heat dissipation and transmission to the peri-implant area during intra-oral welding is very important to limit potential damage to the surrounding tissue. The aim of this in vitro study was to assess, by means of thermal infrared imaging, the tissue temperature peaks associated with the thermal propagation pathway through the implants, the abutments and the walls of the slot of the scaffold, generated during the welding process, in three different implant systems. An in vitro polyurethane mandible model was prepared with a 7.0 mm v-shape slot. Effects on the maximum temperature by a single welding procedure were studied using different power supplies and abutments. A total of 36 welding procedures were tested on three different implant systems. The lowest peak temperature along the walls of the 7.0 mm v-shaped groove (31.6 ± 2 °C) was assessed in the specimens irrigated with sterile saline solution. The highest peak temperature (42.8 ± 2 °C) was assessed in the samples with a contemporaneous power overflow and premature pincers removal. The results of our study suggest that the procedures used until now appear to be effective to avoid thermal bone injuries. The peak tissue temperature of the in vitro model did not surpass the threshold limits above which tissue injury could occur.

Kinetics of the subtransition in dipalmitoylphosphatidylcholine.

PubMed

Tristram-Nagle, S; Wiener, M C; Yang, C P; Nagle, J F

1987-07-14

The kinetics of the interconversions of the subgel and gel phases in dipalmitoylphosphatidylcholine have been studied by using differential dilatometry, differential scanning calorimetry (DSC), and neutral buoyancy centrifugation as a function of incubation temperature and deuteriation of the solvent. As seen by others, DSC scans show two peaks in the subgel transition region for incubation temperatures below 1 degree C. After incubation at 0.1 degree C, the DSC peak that occurs at the lower scanning temperature appears with an incubation half-time of 0.5 day and eventually converts into a peak at higher scanning temperature with an incubation half-time of 18 days. By varying the scanning rate, we show that these two peaks merge into one at slow scanning rates with a common equilibrium transition temperature of 13.8 degrees C, in agreement with equilibrium calorimetry and dilatometry (delta V = 0.017 +/- 0.001 mL/g). For incubation temperatures above 4.6 degrees C, only one peak appears in both scanning dilatometry and calorimetry. While the initial rate of subgel conversion is smaller at the higher incubation temperatures, after 300 h a higher percentage of the sample has converted to subgel than at the lower incubation temperatures. We suggest that higher incubation temperatures (near 5 degrees C) are preferable for forming the stable subgel phase, and we present a colliding domain picture that indicates why this may be so. Our results in D2O and the similarity of the kinetics of volume decrease with the kinetics of wide-angle diffraction lines also support the suggestion that the partial loss of interlamellar water plays a kinetic role in subgel formation.

Climatic controls on the snowmelt hydrology of the northern Rocky Mountains

USGS Publications Warehouse

Pederson, G.T.; Gray, S.T.; Ault, T.; Marsh, W.; Fagre, D.B.; Bunn, A.G.; Woodhouse, C.A.; Graumlich, L.J.

2011-01-01

The northern Rocky Mountains (NRMs) are a critical headwaters region with the majority of water resources originating from mountain snowpack. Observations showing declines in western U.S. snowpack have implications for water resources and biophysical processes in high-mountain environments. This study investigates oceanic and atmospheric controls underlying changes in timing, variability, and trends documented across the entire hydroclimatic-monitoring system within critical NRM watersheds. Analyses were conducted using records from 25 snow telemetry (SNOTEL) stations, 148 1 April snow course records, stream gauge records from 14 relatively unimpaired rivers, and 37 valley meteorological stations. Over the past four decades, midelevation SNOTEL records show a tendency toward decreased snowpack with peak snow water equivalent (SWE) arriving and melting out earlier. Temperature records show significant seasonal and annual decreases in the number of frost days (days ???0??C) and changes in spring minimum temperatures that correspond with atmospheric circulation changes and surface-albedo feedbacks in March and April. Warmer spring temperatures coupled with increases in mean and variance of spring precipitation correspond strongly to earlier snowmeltout, an increased number of snow-free days, and observed changes in streamflow timing and discharge. The majority of the variability in peak and total annual snowpack and streamflow, however, is explained by season-dependent interannual-to-interdecadal changes in atmospheric circulation associated with Pacific Ocean sea surface temperatures. Over recent decades, increased spring precipitation appears to be buffering NRM total annual streamflow from what would otherwise be greater snow-related declines in hydrologic yield. Results have important implications for ecosystems, water resources, and long-lead-forecasting capabilities. ?? 2011 American Meteorological Society.

Effect of organic matter application on CP-MAS-13C-NMR spectra of humic acids from a brown soil

NASA Astrophysics Data System (ADS)

Dou, S.

2009-04-01

The humified SOM or humic substances (HS) composed of humic acid (HA), fulvic acid (FA) and humin (HM) represent the most microbially recalcitrant and stable reservoir of organic carbon in soil (Piccolo et al., 2004). OM applications can influence the amount and structural characteristics of HS(Dou et al., 2008). During the past few decades, there has been much research on HS, but their chemical structure is still not fully understood (Dong, 2006).CP-MAS-13C-NMR spectroscopy was considered as an effective method to study structures of HS without dissolving problem compared with liquid 13C-NMR (Conte et al., 1997; Dou et al., 2008). It can directly measure the carbon framework and reflect the nature of HS transformation after OM application (Spaccini et al., 2000). For that reason, this method was applied in this study. The objective of this paper was to clarify the effect of long term OM application on the changes of structural characteristics in HAs, which provided new information for improving soil fertility by OM application. The experiment was carried out on a brown soil (Paleudalf in USDA Soil Taxonomy) at Shenyang Agricultural University, Liaoning province, China (N41°48'-E123°25'). The experiment included 3 treatments: zero-treatment (CKbr), and two pig manure (PM) treatments (O1 and O2) at the rates of 0.9 t ha-1 and 1.8 t ha-1 of organic carbon, respectively. The samples of the HA fraction were extracted, separated and purified according to the method described by Dou et al. (1991). Elemental composition, Differential thermal analysis (DTA), -lgK value, FT-IR and CP-MAS- 13C-NMR of HAs were performed. Effects on the contents of orgaic carbon and its composition. The contents of TOC were from 8.77 g kg-1 to 12.25 g kg-1. The relative contents in TOC for WSS, HA, and FA were 6.87%, 14.2% and 19.8%. Comparing the CKbr, the contents of WSS, HA and FA for O1 and O2 increased, but relative contents of WSS and FA decreased. The content of the HA increased after OM application, which was consistent with other studies (Wang et al., 2001). The content of the WSS increased after the OM application indicating that the increase of labile organic carbon. The C/H mole ratio of the HS could reflect the degree of condensation (Dou et al., 1995). Effects on HA chemical and optical properties. The chemical and optical properties of HA were listed. The C/H ratios decreased after OM application, from 0.830 (CKbr) to 0.754 (O2). While △lgK increased, from 0.623 (CKbr) to 0.658 (O2). The HA structure tended to become simpler. The C/H ratio of the HA decreased after OM application. This indicates that OM application decreased the degree of condensation. The △lgK values can be used as the index of HA molecule complexity in the soil. If △lgK increased, the molecular structure becomes simpler. After OM application, △lgK increased indicating that the molecular structure became simpler. Effects on HA thermal properties. It could be seen that HA had exothermic peaks in moderate and high temperature regions. After OM application, heat (H2) of exothermic peak increased in moderate temperature region, while heat (H3) of exothermic peak decreased in high temperature region. The the heat ratio of exothermic peaks in high temperature region to moderate (H3/H2) decreased. From CKbr to O2, H3/H2 decreased from 4.31 to0.86. The HA had moderate and high temperature exothermic peaks. The heat of exothermic peaks in the moderate temperature region might show that aliphatic compounds decomposed and peripheral functional groups decarboxylated. The heat of the exothermic peaks in the high temperature region might show that the HA was oxidized completely and inter-aromatic structures in the molecule decomposed. The heat ratio of the high to moderate temperature exothermic regions (H3/H2) decreased significantly after PM application, indicating that the proportion of aromatic structure decreased and the HA molecular structure simplified. Effects on CP-MAS-13C-NMR spectrum of HA. The CP-MAS- 13C-NMR spectra of the HA were quite similar to each other. These spectra exhibited signals for alkyl (0~50 ppm), O-alkyl (50~110 ppm), aromatic (110~160 ppm) and carbonyl (160~200 ppm) regions. The signals in carbonyl C region concentrated between 172 ppm and 173 ppm, and with a small signal occurred in the region of 190~200 ppm, indicating that there was carbonyl C of carboxylic acid, ester and amide, but a little amount carbonyl C of ketonic compounds. In the region of aromatic C, the most obvious peaks were the absorption at 131~133 ppm and 114~117 ppm. The former was mainly the aromatic C substituted by -COOH or -COOMe and the unsubstituted aromatic meta to carbons bearing an oxygen or nitrogen atom; the latter was mainly the unsubstituted aromatic C ortho and para to carbons bearing an oxygen and nitrogen atom. There was a small peak at 152-154ppm, which was the signal of phenolic OH. The signal at 55~56 ppm was methoxyl C. The signals at 71~73 ppm were due to the -CH(OH)- in carbohydrate. The peak at 102~103 ppm was generally assigned to double oxygen-C in polysaccharide (possibly acetal). The maximum absorption at 30 ppm was the contribution of the polymethylene chain -(CH2)n- in saturated hydrocarbons (Wilson, 1981). After OM application, the contents of alkyl C and O-alkyl C increased and the contents of aromatic C and carbonxyl C except to 1986 decreased. Compared with 1986, the contents of O-alkyl C increased and the contents of alkyl C decreased for the same treatment CKbr and O2. Aromaticity decreased significantly in OM treatments, indicating that the OM decreased the content of aromatic C and was simplified the molecular structure. The relative content of O-alkyl C increased indicating that OM application increased the content of methoxyl C and -CH(OH)- in carbohydrate. Alkyl C was probably derived from compounds of plants with high resistance to degradation, such as cutin and suberin (Baldock et al., 1992; Preston, 1996), or from newly synthesized products from soil micro-organisms , which are likely to represent the most persistent fraction of stable OM (Baldock et al., 1990; Lichtfouse et al., 1998; Piccolo, 2002). The alkyl C increased after the OM applications, indicated by the increase of hydrophobic components content and aliphatic character. Compared with 1986, the contents of O-alkyl C increased and the contents of alkyl C decreased for the same treatment CKbr and O2, indcating that a simplification trend took place in the aliphatic fraction of HA molecular with cultivation time in the tested soil. Conclusions.We have found that:1) The contents of HAs increased after OM application;2) OM application increased the contents of alkyl C and O-alkyl C, and decreased the C/H ratio, aromaticity, and the H3/H2 ratio of the HA, which indicated that the HA structure tended to become simpler and more aliphatic. 3) The results obtained by CP-MAS- 13C-NMR spectroscopy were mainly corresponding with those obtained by chemical analysis, thermal analysis, optical properties and IR spectroscopy, which indicated that 13C-NMR spectroscopy had a potential in characterizing the structural changes of HA after long-term OM application into soils.

Seasonal variations in the major chemical species of snow at the South East Dome in Greenland

NASA Astrophysics Data System (ADS)

Oyabu, Ikumi; Matoba, Sumito; Yamasaki, Tetsuhide; Kadota, Moe; Iizuka, Yoshinori

2016-03-01

We analyze snow-pit samples collected in May 2015 at the South East Dome (SE Dome) on the Greenland ice sheet. The analysis includes high-resolution records of δD and δ18O, as well as the major ions, CH3SO3-, Cl-, NO3-, SO42-, Na+, NH4+, K+, Ma2+, and Ca2+. We find that the 3.55-m snow pit recorded temperature and aerosol proxies back to summer or autumn of 2014. This indicates a higher accumulation rate than those at other major drilling sites in Greenland. Due to this high accumulation rate, ion concentrations except Na+ are lower than those typical of the central Greenland ice sheet. Concerning seasonal variability, the Na+, Cl-, Ca2+, Mg2+, and NO3- vary similarly to other sites in Greenland, with the Na+ and Cl- peaking in winter to early spring, Ca2+ peaking in spring, Mg2+ peaking in winter to spring, and NO3- towards a peak in summer while showing smaller peaks in winter to spring. The NH4+ increased in spring, and SO42- increased in autumn to winter at SE Dome. On the other hand, the seasonal trend in the Cl-/Na+ ratio differs from those in the inland region. As we did not fully recover one seasonal cycle, some seasonal peaks may have been missed.

Annual variation in the reproductive hormone and behavior rhythm in a population of the Asian short-toed lark: Can spring temperature influence activation of the HPG axis of wild birds?

PubMed

Zhang, Shuping; Xu, Xianglong; Wang, Weiwei; Zhao, Lidan; Gao, Lijun; Yang, Wenyu

2017-09-01

Although a number of studies have demonstrated a correlation between ambient temperature and the timing of reproductive behavior in many bird species, the relationships between temperature, activation of the hypothalamus-pituitary-gonad (HPG) axis, laying, and hatching in free-living birds, remain unclear. We investigated the relationships between spring temperature, reproductive hormones, and behavior, in a population of the Asian short-toed lark (Calandrella cheleensis) on the Inner Mongolian Grasslands in 2014, 2015 and 2016. LH and T levels peaked earliest in the year with the highest April temperature (2014) and latest in the year with the lowest April temperature (2016), and rose faster in 2014 than in 2015 or 2016. Laying and hatching occurred earliest in 2014 and latest in 2016. E2 also peaked earlier in 2014 than in the other two years but there was no significant difference in peak E2 levels among the three years. The peak of hatching only coincided with the peak in grasshopper nymph (the main food of nestlings) abundance in 2015 and the nestling fledging rate in 2015 was significantly higher than that in 2014 and 2016. We also conducted a controlled experiment on the effect of temperature on plasma LH, T and E2 levels in wild-caught larks, which shows that mean plasma LH, T and E2 levels in the 16°C group all peaked 4days earlier than in the 13°C group. All these results suggest that activation of HPG endocrine axis in the Asia short-toed lark population is closely related to ambient temperature, and that this subsequently influences the timing of laying and hatching. The HPG axis' endocrine function is a physiological factor that mediates effects of ambient temperature on the timing of breeding. Temperature induced annual variation in the timing of hatching was, however, insufficient to synchronize the nestling period with the annual peak in grasshopper nymph abundance. Unusually warm, or cold, spring temperatures advanced, or delayed, grasshopper nymph development to an extent that exceeded the Asian short-toed lark's capacity to advance or delay the onset of breeding and reproductive success was lower in the two years of the study in which the nestling period was asynchronous with the peak of grasshopper nymph abundance. Long-term research on the relationship between the timing of reproduction and population demographics of the Asian short-toed lark is required to understand the effects of climate change on this species and on temperate birds in general. Copyright © 2017 Elsevier Inc. All rights reserved.

Physiochemical and functional properties of chum salmon (Oncorhynchus keta) skin gelatin extracted at different temperatures.

PubMed

Liu, Yang; Xia, Lining; Jia, Hui; Li, Qi; Jin, Wengang; Dong, Xiuping; Pan, Jinfeng

2017-12-01

Aquatic source gelatins are gaining more attention due to the advantages in safety and religion acceptability compared with mammalian sources. For understanding the effects of extracting temperature on gelatins from chum salmon (Oncorhynchus keta) skins (GCSS), gelatins were extracted at temperatures from 40 to 90°C and the physiochemical properties of GCSS were investigated. GCSS yield increased while imino acids content declined as the increase of temperature. GCSS40, 50 and 60 showed strong β-, α1- and α2-chains but the three faded in GCSS70, 80 and 90, with the presence of low molecular weight fragments. Amides A, I and III were shifted to higher wavenumber in GCSS70, 80 and 90 compared with that of GCSS40, 50 and 60. X-ray diffraction showed lower intensity of peak at 7° in GCSS80 and 90 than in the other GCSS. Gel strength declined while a*, b* and ΔE* value increased as temperature increased. Foam expansion and stability of GCSS40, 50 and 60 were lower than those of GCSS70, 80 and 90. Emulsion activity and stability decreased as temperature increased. Extracting temperature greatly affected yield, molecular composition and functionalities of GCSS. A temperature lower than 50°C is recommended for GCSS extraction. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Correlation of Toughness between H-Plate and Charpy Impact Tests

DTIC Science & Technology

1959-09-01

thermal cycles having peak temperatures in or near the range of critical transformation temperatures. Notch sensitivity in these regions has been...21- In their recent work the transition temperatures of heat-affected-zone struc- tures produced by thermal cycles having peak temperatures in the...gradient of thermal cycles associated with welding is too complex to have been included in the scope of this report. The superior toughness of the Ni

Polyolefin nanocomposites

DOEpatents

Chaiko, David J.

2007-01-02

The present invention relates to methods for the preparation of clay/polymer nanocomposites. The methods include combining an organophilic clay and a polymer to form a nanocomposite, wherein the organophilic clay and the polymer each have a peak recrystallization temperature, and wherein the organophilic clay peak recrystallization temperature sufficiently matches the polymer peak recrystallization temperature such that the nanocomposite formed has less permeability to a gas than the polymer. Such nanocomposites exhibit 2, 5, 10, or even 100 fold or greater reductions in permeability to, e.g., oxygen, carbon dioxide, or both compared to the polymer. The invention also provides a method of preparing a nanocomposite that includes combining an amorphous organophilic clay and an amorphous polymer, each having a glass transition temperature, wherein the organophilic clay glass transition temperature sufficiently matches the polymer glass transition temperature such that the nanocomposite formed has less permeability to a gas than the polymer.

Thermo-Mechanical Fatigue Crack Growth of RR1000

PubMed Central

Pretty, Christopher John; Whitaker, Mark Thomas; Williams, Steve John

2017-01-01

Non-isothermal conditions during flight cycles have long led to the requirement for thermo-mechanical fatigue (TMF) evaluation of aerospace materials. However, the increased temperatures within the gas turbine engine have meant that the requirements for TMF testing now extend to disc alloys along with blade materials. As such, fatigue crack growth rates are required to be evaluated under non-isothermal conditions along with the development of a detailed understanding of related failure mechanisms. In the current work, a TMF crack growth testing method has been developed utilising induction heating and direct current potential drop techniques for polycrystalline nickel-based superalloys, such as RR1000. Results have shown that in-phase (IP) testing produces accelerated crack growth rates compared with out-of-phase (OOP) due to increased temperature at peak stress and therefore increased time dependent crack growth. The ordering of the crack growth rates is supported by detailed fractographic analysis which shows intergranular crack growth in IP test specimens, and transgranular crack growth in 90° OOP and 180° OOP tests. Isothermal tests have also been carried out for comparison of crack growth rates at the point of peak stress in the TMF cycles. PMID:28772394

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Li-Fang; Ou, Chin-Ching; Striebel, Kathryn A.

The goal of this research was to measure Mn dissolution from a thin porous spinel LiMn{sub 2}O{sub 4} electrode by rotating ring-disk collection experiments. The amount of Mn dissolution from the spinel LiMn{sub 2}O{sub 4} electrode under various conditions was detected by potential step chronoamperometry. The concentration of dissolved Mn was found to increase with increasing cycle numbers and elevated temperature. The dissolved Mn was not dependent on disk rotation speed, which indicated that the Mn dissolution from the disk was under reaction control. The in situ monitoring of Mn dissolution from the spinel was carried out under various conditions.more » The ring currents exhibited maxima corresponding to the end-of-charge (EOC) and end-of-discharge (EOD), with the largest peak at EOC. The results suggest that the dissolution of Mn from spinel LiMn{sub 2}O{sub 4} occurs during charge/discharge cycling, especially in a charged state (at >4.1 V) and in a discharged state (at <3.1 V). The largest peak at EOC demonstrated that Mn dissolution took place mainly at the top of charge. At elevated temperatures, the ring cathodic currents were larger due to the increase of Mn dissolution rate.« less

Effect of sintering temperature of Ce3+-doped Lu3Al5O12 phosphors on light emission and properties of crystal structure for white-light-emitting diodes

NASA Astrophysics Data System (ADS)

Koizumi, Hiroshi; Watabe, Junya; Sugiyama, Shin; Hirabayashi, Hideaki; Homma, Tetsuya

2018-06-01

The effect of the sintering temperature of Ce3+-doped Lu3Al5O12 (Ce-LuAG) phosphors on the emission and properties of the crystal structure was studied. A cathodoluminescence peak at 317 nm, which was assigned to lattice defects, was exhibited in addition to emission peaks at 508 and 540 nm for the Ce-LuAG phosphors. The intensities of the 317 nm emission peak for the phosphors with mean particle diameters of 5.0 and 10.0 µm formed at a low sintering temperature of 1430 °C were higher than those for the phosphors with mean particle diameters of 18.0 and 20.5 µm formed at a high sintering temperature of 1550 °C. In contrast, the electroluminescence spectra for fabricated white-light-emitting diodes (LEDs) using the phosphors revealed that the intensity of the peak at 540 nm was strong for the mean particle diameters of 18.0 and 20.5 µm. The intensity of the 540 nm peak, which is attributed to the 4f→5d transition of the Ce3+ activator, showed a dependence on the sintering temperature. The relationship between the optical properties and the lattice defects is discussed.